WorldWideScience

Sample records for chemistry archaeology mechanisms

  1. Biocorrosion of Archaeological Glass

    OpenAIRE

    Shelley, William L.

    2016-01-01

    This research investigates the physical manifestation and chemical mechanisms andprocesses of biologically-induced corrosion of archaeological glass. Archaeological glasssamples from Greece and Cyprus suspected to have undergone biocorrosion wereanalyzed to characterize the composition and surface topography and to determine thedifference in the chemistry and microstructure between the glass surface and the bulk.Microscopic and analytical techniques employed include digital microscopy, polari...

  2. Quantum mechanics in chemistry

    CERN Document Server

    Schatz, George C

    2002-01-01

    Intended for graduate and advanced undergraduate students, this text explores quantum mechanical techniques from the viewpoint of chemistry and materials science. Dynamics, symmetry, and formalism are emphasized. An initial review of basic concepts from introductory quantum mechanics is followed by chapters examining symmetry, rotations, and angular momentum addition. Chapter 4 introduces the basic formalism of time-dependent quantum mechanics, emphasizing time-dependent perturbation theory and Fermi's golden rule. Chapter 5 sees this formalism applied to the interaction of radiation and matt

  3. "Interred with their bones" - linking soil micromorphology and chemistry to unlock the hidden archive of archaeological human burials

    Science.gov (United States)

    Brothwell, Don; Usai, Maria-Raimonda; Keely, Brendan; Pickering, Matt; Wilson, Clare

    2010-05-01

    "Interred with their bones" Acronym: InterArChive - an ERC-funded project *** " Friends, Romans, countrymen, lend me your ears; " I come to bury Caesar, not to praise him. " The evil that men do lives after them; " The good is oft 'interred with their bones'; " So let it be with Caesar. William Shakespeare, Julius Caesar, Act III, Scene 2. *** Background The state of decay within soils in archaeological graves is often such that degradable objects are not preserved in a condition that can be visually recognised. However, microscopic soil features, inorganic element distributions and organic residues can be measured. Thus, archaeological burial soils have the potential to reveal signatures of decay; pre-burial treatment; presence and nature of associated clothing and perishable artefacts; diet of the individual; cause of death; evidence of morbidity and drug-use. Aims • To develop and test a multidisciplinary approach linking soil micromorphology and chemistry to recover environmental and cultural information; • Revealing the hidden archaeological archive within the burial soil • Developing soil sampling and analysis recommendations for archaeological human burials Methods 1: Sampling and soil field description from archaeological sites contrasting in soil, geology, age, and culture and from experimental piglet burials 2: Microscopic/micromorphological analysis (micro-scale observations) of remains and features in burial soils. We will establish the order of occurrence, spatial patterns, displacement, mode of formation and decay of micromorphological features including exotic components, parasites, hair and remnants of footwear and clothing [cf. pilot study of soils from Yemen]; microfabrics and textural pedofeatures, also to facilitate resolution of body decay products from other accumulations. 3: Microprobe analysis (nano-scale) will generate elemental maps of soil thin sections, allowing identification of features with distinct chemical signatures

  4. Fast Chemistry Mechanisms for Climate Applications

    Science.gov (United States)

    Cameron-Smith, P. J.; Connell, P. S.; Bergmann, D. J.; Chuang, C. C.; Prather, M. J.; Lamarque, J.; Hess, P.; Vitt, F.

    2008-12-01

    When atmospheric chemistry is included in long climate and Earth system simulations, the completeness of the chemical mechanism must be balanced with the computational cost, and the scientific interests of the atmospheric chemist must be tempered by the chemical needs of other components of the climate model (e.g, greenhouse gas concentrations for radiative heating, and deposition rates for biosphere interactions). We have implemented two chemical mechanisms for use in long climate simulations. One uses 28 species to calculate ozone, OH, methane, N2O, and sulfate throughout troposphere and stratosphere. The other uses just 15 species to calculate ozone, OH, and sulfate, with the OH providing the means to back-out the lifetime of methane and other species of interest. We have compared the sensitivity of both mechanisms to emission perturbations against the response of a state-of-the-art full chemistry mechanism that uses 90 species. Both fast mechanisms compare well. Prepared by LLNL under Contract DE-AC52-07NA27344.

  5. Physical Chemistry Chemical Kinetics and Reaction Mechanism

    CERN Document Server

    Trimm, Harold H

    2011-01-01

    Physical chemistry covers diverse topics, from biochemistry to materials properties to the development of quantum computers. Physical chemistry applies physics and math to problems that interest chemists, biologists, and engineers. Physical chemists use theoretical constructs and mathematical computations to understand chemical properties and describe the behavior of molecular and condensed matter. Their work involves manipulations of data as well as materials. Physical chemistry entails extensive work with sophisticated instrumentation and equipment as well as state-of-the-art computers. This

  6. The Archaeology of Archaeology

    Science.gov (United States)

    de Smet, T. S.; Holcomb, J. A.

    2013-12-01

    Context and chronology are of critical importance in archaeological research. Unfortunately, however, many previously excavated sites lack adequate detail in these aspects. As such, archaeologists are increasingly returning to previously investigated sites in order to reassess the integrity of prior excavations and answer new research questions. Near-surface geophysics can be used to locate and map the extent of prior excavations at these sites. Here, we present two case studies of the use of geophysics to find previously excavated archaeological trenches. At Copper's Ferry (10IH73), in western Idaho, magnetic gradiometry was used to locate a trench excavated by Idaho State University in 1961. This trench yielded cultural materials associated with the Western Stemmed Tradition that potentially date to the Pleistocene. At Goat Springs Pueblo (LA285), New Mexico, electromagnetic induction was used to find UCLA's 1960 excavation trench within a central kiva. Ground-truthing at both sites proved the efficacy of these methods, and allowed for a reexamination of the context and chronology at both sites.

  7. Extending Saiph to simulate fluid mechanics and chemistry problems

    OpenAIRE

    Macià Sorrosal, Sandra

    2016-01-01

    Saiph is a domain specific language for solving partial differential equations in high performance computing systems, developed at the Barcelona Computing Center. The aim of this project is to extend this language to support fluid mechanics and chemistry problems.

  8. The chemistry induced by mechanical load

    CERN Document Server

    Frank, Irmgard

    2016-01-01

    Results in the field of mechanochemistry are summarized. For example under mechanical load often a solvolysis is observed instead of a simple homolytic bond rupture. Also a mechanically induced redox reaction was reported experimentally and could be modelled theoretically. With CPMD simulations it is possible to understand multi-step mechanisms in full detail.

  9. Examining the life history of an individual from Solcor 3, San Pedro de Atacama: Combining bioarchaeology and archaeological chemistry

    International Nuclear Information System (INIS)

    Detailed life history information using multiple lines of evidence including the identification of geographic origins, health, and body use indicators, can be used to elucidate the complex process of acculturation in the San Pedro de Atacama oases of northern Chile during the Middle Horizon. This paper presents the results of bioarchaeological and archaeological chemical analyses of the skeletal remains of an adult male (tomb 50, catalog number 1948) from the cemetery of Solcor 3 (ca. AD 500-900). Strontium isotope ratios in human tooth enamel reveal information about where a person lived during their childhood, when enamel was being formed. Individual 1948 showed strontium isotope ratios decidedly outside the range of the local San Pedro de Atacama strontium isotope signature. Given these data implying that individual 1948 was originally from elsewhere, an examination of his health status, social role, and mortuary context provides insight into the treatment of foreigners in San Pedro de Atacama. Our data support the argument that individual 1948's foreign birth did not hinder his later assimilation into Atacameno society. He was buried in a local cemetery with a typical mortuary assemblage for a male of this time and no strong evidence of possible foreign origin. Skeletal indicators of diet and activity patterns do not distinguish individual 1948 from the local population, suggesting that his lifestyle was similar to that of other Atacamenos. Therefore, our analyses suggest that individual 1948's acculturation into Atacameno society during his adult life was nearly complete and he retained little to no indication of his probable foreign birth

  10. Long term alteration of glass/iron systems in anoxic conditions: contribution of archaeological analogues to the study of mechanisms

    International Nuclear Information System (INIS)

    The knowledge of glass alteration mechanisms arouses a great interest over the last decades, particularly in the nuclear field, since vitrification is used to stabilize high-level radioactive wastes in many countries. In the French concept, these nuclear glasses would be stored in geological repositories. This multi-barrier system (glass matrix, stainless steel container, low carbon steel over-container, geological barrier) must ensure the durable confinement of radionuclides. But laboratory experiments do not permit to predict directly the behaviour of these materials over typically a million-year timescale and the extrapolation of short-term laboratory data to long time periods remains problematic. Part of the validation of the predictive models relies on natural and archaeological analogues. Here, the analogues considered are vitreous slags produced as wastes by a blast furnace working during the 16. century in the iron making site of Glinet (Normandy, France). The choice of these specific artefacts is due to the presence of particular interface between corrosion products and glass matrix inside the blocks. Thus, they can help us to understand the influence of iron corrosion products from the steel containers on the glass alteration mechanisms and kinetics. A first part of this work concerns the characterization of the archaeological artefacts especially the interfacial area between glass and corrosion products inside cracks using micro and nano-beam techniques ( Raman spectroscopy, FEG-SEM, TEM, STXM...). This study has enabled to suggest an alteration process with different geochemical steps that leads to alteration profile observed. One of these steps is the precipitation of an iron silicate phase. In a second time, leaching experiments were set up on a synthetic glass of similar composition than the archaeological one to understand the first stages of alteration with and without iron. Two phenomena can be observed: silicon sorption and precipitation of iron

  11. Quantum mechanics a comprehensive text for chemistry

    CERN Document Server

    Arora, Kishor

    2010-01-01

    This book contains 14 chapters. The text includes the inadequacy of classical mechanics and covers basic and fundamental concepts of quantum mechanics including concepts of transitional, vibration rotation and electronic energies, introduction to concepts of angular momenta, approximatemethods and their application concepts related to electron spin, symmetery concepts and quantum mechanics and ultimately the book features the theories of chemical bonding and use of softwares in quantum mechanics. the text of the book is presented in a lucid manner with ample examples and illustrations wherever

  12. New Interference Mechanism Controls Ultracold Chemistry

    Science.gov (United States)

    Kendrick, Brian K.; Hazra, Jisha; Balakrishnan, N.

    2016-05-01

    A newly discovered interference mechanism has been shown to control the outcome of ultracold chemical reactions. The mechanism originates from the unique properties associated with ultracold collisions, namely: (1) isotropic (s-wave) scattering and (2) an effective quantization of the scattering phase shift (which originates from the bound state structure of the molecule). These two properties can lead to maximum constructive or destructive interference between two interfering reaction pathways (such as exchange and non-exchange in systems with two or more identical nuclei). If the molecular system exhibits a conical intersection, then the associated geometric phase is shown to act as a ``quantum switch'' which can turn the reactivity on or off. Reaction rate coefficients for the O + OH --> H + O2 and H + H2, reactions are presented which explicitly demonstrate the effect. Experimentalists might exploit this new mechanism to control ultracold reactions by the application of external electric or magnetic fields or by the selection of a particular nuclear spin state. This work was supported in part by the LDRD program (Grant No. 20140309ER) at LANL (B.K.) and by NSF Grant PHY-1505557 (N.B.) and ARO MURI Grant No. W911NF-12-1-0476 (N.B.).

  13. Ferrous archaeological analogues for the understanding of the multi-secular corrosion mechanisms in an anoxic environment

    International Nuclear Information System (INIS)

    Understanding the long term corrosion mechanisms of iron in an anoxic environment is essential in the field of the radioactive waste storage. In France, it is planned to store high level nuclear wastes in a multi-barrier system containing a glassy matrix surrounded by a stainless steel container, embedded in a low-carbon steel over-container. This system would be placed in a deep geological repository, which would impose anoxic conditions. As it must be efficient for a period of several thousands of years, one should understand the alteration mechanisms that are expected to occur in such a long time. To this purpose, a specific approach is developed on ferrous archaeological analogues with thick corrosion layer formed in natural conditions. In this study, the corrosion mechanisms have been assessed by examining nails aged of 400 years coming from the archaeological site of Glinet, selected as a reference site. The first point was a fine characterisation of the entire corrosion system metal / corrosion products / medium, through the use of coupled multi-scale analytical tools. The first results showed that the samples were corroded in an anoxic calco-carbonated environment. Moreover, the coupling of X-ray micro-diffraction, Raman microspectroscopy and dispersive energy spectroscopy has enabled to identify three corrosion systems composed of iron carbonates, siderite and chukanovite, and magnetite. Depending on the phase's layout in the system, the electronic resistance of the corrosion layers has been established, from resistive to conductive. In a second stage, re-corroding experiments in laboratory were performed. Firstly, the electrochemical behaviour of the corrosion system has shown that water reduction at the metallic interface is negligible. Furthermore, reaction tracing with copper and deuterium has allowed identifying the electron consumptions sites mainly localised on the external part, and the precipitation sites on the internal part of the corrosion

  14. Archaeological Bonanza

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    China’s construction boom unearths many important ancient sites China’s top 10 archaeological discoveries in 2008 were released by the State Administration of Cultural Heritage (SACH) on March 31. The 10 winners, which were chosen from 25 nominees, include a Bronze-Age graveyard in

  15. Concepts and methods in modern theoretical chemistry statistical mechanics

    CERN Document Server

    Ghosh, Swapan Kumar

    2013-01-01

    Concepts and Methods in Modern Theoretical Chemistry: Statistical Mechanics, the second book in a two-volume set, focuses on the dynamics of systems and phenomena. A new addition to the series Atoms, Molecules, and Clusters, this book offers chapters written by experts in their fields. It enables readers to learn how concepts from ab initio quantum chemistry and density functional theory (DFT) can be used to describe, understand, and predict chemical dynamics. This book covers a wide range of subjects, including discussions on the following topics: Time-dependent DFT Quantum fluid dynamics (QF

  16. Epoxide Chemistry: Guided Inquiry Experiment Emphasizing Structure Determination and Mechanism

    Science.gov (United States)

    Krishnamurty, H. G.; Jain, Niveta; Samby, Kiran

    2000-04-01

    This paper presents an operationally simple three-step synthesis of an a-hydroxy acid based on epoxide chemistry. The focus of the experiment is on the preparation of the chalcone epoxide and its reaction with hot alcoholic alkali. The experiment leads to an unpredicted reaction product. Its structure is established as 2-benzyl-2-phenylglycollic acid by chemical and spectroscopic analysis. The hydroxyacid is a good example to bring home an important NMR principle: the nonequivalence of hydrogens adjacent to a stereogenic center. The formation of the alpha-hydroxy acid is a mechanistic puzzle. A stepwise mechanism can be developed applying lecture-based organic chemistry concepts. On the other hand, acid-catalyzed (H2SO4, BF3) reaction of the chalcone epoxide gives benzoylphenylacetaldehyde. The exercise can be used as a multistep organic chemistry experiment. It also gives students a research-type experience.

  17. Long term corrosion of iron in concrete and in atmospheric conditions: a contribution of archaeological analogues to mechanism comprehension

    International Nuclear Information System (INIS)

    Full text of publication follows: The prediction of iron (or low alloy steel) corrosion on very long term period is necessary in two different purposes: (i) the preservation and conservation of cultural heritage and (ii) the French storage and repository concept for the radioactive wastes. In order to determine the evolution of corrosion processes for very long period, mechanistic models have been developed. In these models that are based on a phenomenological approach to evaluate the average corrosion rates, two different environments are considered: concrete (steel reinforcements) and atmospheric. The study of archaeological analogues is a very pertinent tool for the validation of these models. First, physico-chemical analysis on old corrosion layers lead to a precise localisation and identification of the phases present in the corrosion system. Moreover, experimental reinduced corrosions of ancient samples under controlled parameters (temperature, relative humidity) bring new insight on the mechanisms involved. In particular, one crucial question related to the wet-dry cycle is the localisation of oxygen reduction sites in the rust layer. For this purpose, specific experiments have been set up to re-corrode the ancient samples in marked medium (using 18O2). Samples were exposed to cycling between high and low relative humidity, produced by saline saturated solutions. Then cross-sections of samples obtained were investigated by nuclear reaction analysis (NRA) 18O(p,α)15N on the Pierre Sue Laboratory nuclear microprobe. In this presentation the 18O distribution profiles are discussed and interpreted in order to bring new insight on corrosion mechanisms. A comparative interpretation is made for each medium (concrete and atmosphere)

  18. UNESCO, URI, and Archaeology in the Deep Blue Sea: Archaeological Ethics and Archaeological Oceanography

    Science.gov (United States)

    Krieger, William H.; Buxton, Bridget

    2012-12-01

    Multiple groups have interests that intersect within the field of deep submergence (beyond the 50 meter range of SCUBA) archaeology. These groups' differing priorities present challenges for interdisciplinary collaboration, particularly as there are no established guidelines for best practices in such scenarios. Associating the term `archaeology' with projects directed at underwater cultural heritage that are guided by archaeologists poses a real risk to that heritage. Recognizing that the relevant professional organizations, local laws, and conventions currently have little ability to protect pieces of cultural heritage across disciplines and international boundaries, the authors propose institution-specific mechanisms, called Archaeology Review Boards, guided by local and international laws and conventions concerning cultural heritage, as the best means to provide oversight for academically centered archaeological activities at the local level.

  19. Contract archaeology and news archaeological contracts

    Directory of Open Access Journals (Sweden)

    Wilhelm Londoño

    2016-09-01

    Full Text Available This paper addresses two topics related to the current situation of archaeology in Latin America and Colombia. The first section of the paper deals with the impact of contract archaeology in Colombia. The fact that programs of contract or preventive archaeology have rocketed in recent years is well known. Less known, however, are the broad tendencies and dimensions of this phenomenon. The second issue discussed here is the relationship between global tourism politics and processes of local recovery and enhancement of heritage assets, which will be explored through the analysis of two archaeological sites. The recovery and touristification of an archaeological site is used as starting point to reflect about the differences between a new tendency in archaeological contract opposed to the dominant tendency in the field.

  20. Molecular Mechanism of Acrylamide Neurotoxicity: Lessons Learned from Organic Chemistry

    Science.gov (United States)

    Gavin, Terrence

    2012-01-01

    Background: Acrylamide (ACR) produces cumulative neurotoxicity in exposed humans and laboratory animals through a direct inhibitory effect on presynaptic function. Objectives: In this review, we delineate how knowledge of chemistry provided an unprecedented understanding of the ACR neurotoxic mechanism. We also show how application of the hard and soft, acids and bases (HSAB) theory led to the recognition that the α,β-unsaturated carbonyl structure of ACR is a soft electrophile that preferentially forms covalent bonds with soft nucleophiles. Methods: In vivo proteomic and in chemico studies demonstrated that ACR formed covalent adducts with highly nucleophilic cysteine thiolate groups located within active sites of presynaptic proteins. Additional research showed that resulting protein inactivation disrupted nerve terminal processes and impaired neurotransmission. Discussion: ACR is a type-2 alkene, a chemical class that includes structurally related electrophilic environmental pollutants (e.g., acrolein) and endogenous mediators of cellular oxidative stress (e.g., 4-hydroxy-2-nonenal). Members of this chemical family produce toxicity via a common molecular mechanism. Although individual environmental concentrations might not be toxicologically relevant, exposure to an ambient mixture of type-2 alkene pollutants could pose a significant risk to human health. Furthermore, environmentally derived type-2 alkenes might act synergistically with endogenously generated unsaturated aldehydes to amplify cellular damage and thereby accelerate human disease/injury processes that involve oxidative stress. Conclusions: These possibilities have substantial implications for environmental risk assessment and were realized through an understanding of ACR adduct chemistry. The approach delineated here can be broadly applied because many toxicants of different chemical classes are electrophiles that produce toxicity by interacting with cellular proteins. PMID:23060388

  1. Ash chemistry and sintering, verification of the mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Skrifvars, B.J. [Aabo Akademi, Turku (Finland)

    1996-12-01

    In this project four sintering mechanisms have been studied, i.e., partial melting with a viscous liquid, partial melting with a non-viscous liquid, chemical reaction sintering and solid state sintering. The work has aimed at improving the understanding of ash sintering mechanisms and quantifying their role in combustion and gasification. The work has been oriented in particular on the understanding of biomass ash behavior. The work has not directly focused on any specific technical application. However, results can also be applied on other fuels such as brown coal, petroleum coke, black liquor and different types of wastes (PDF, RDF, MSW). In one part of study the melting behavior was calculated for ten biomass ashes and compared with lab measurements of sintering tendencies. The comparison showed that the T{sub 15} temperatures, i.e. those temperatures at which the ashes contained 15 % molten phase, correlated fairly well with the temperature at which the sintering measurements detected sintering. This suggests that partial melting can be predicted fairly accurate for some ashes already with the today existing thermodynamic calculation routines. In some cases, however the melting calculations did not correlate with the detected sintering temperatures. In a second part detailed measurements on ash behavior was conducted both in a semi full scale CFB and a lab scale FBC. Ashes and deposits were collected and analyzed in several different ways. These analyses show that the ash chemistry shifts radically when the fuel is shifted. Fuels with silicate based ashes behaved totally different than those with an oxide or salt based ash. The chemistry was also affected by fuel blending. The ultimate goal has been to be able to predict the ash thermal behavior during biomass thermal conversion, using the fuel and ash elemental analyses and a few operational key parameters as the only input data. This goal has not yet today been achieved. (author)

  2. Organic Chemistry Students' Ideas about Nucleophiles and Electrophiles: The Role of Charges and Mechanisms

    Science.gov (United States)

    Anzovino, Mary E.; Bretz, Stacey Lowery

    2015-01-01

    Organic chemistry students struggle with reaction mechanisms and the electron-pushing formalism (EPF) used by practicing organic chemists. Faculty have identified an understanding of nucleophiles and electrophiles as one conceptual prerequisite to mastery of the EPF, but little is known about organic chemistry students' knowledge of nucleophiles…

  3. Tephra, tephrochronology and archaeology

    DEFF Research Database (Denmark)

    Riede, Felix; Thastrup, Mads

    2013-01-01

    instantaneous from a geological, archaeological, and evolutionary perspective. Often these volcanic products can be identified by various chemical and non-chemical means and if the eruption date is known, the occurrence of tephra from a given eruption in stratigraphic sequences provides a powerful means......, and to make a case for better linking tephra research to archaeology, all from a primarily Scandinavian perspective. We argue that the identification of tephra in archaeological sediments should, in due time, become as routine as other types of geo-archaeological analyses, especially given that tephra cannot...

  4. A comparison of atmospheric composition using the Carbon Bond and Regional Atmospheric Chemistry Mechanisms

    OpenAIRE

    Sarwar, G.; J. Godowitch; B. H. Henderson; K. Fahey; Pouliot, G.; W. T. Hutzell; Mathur, R.; Kang, D.; Goliff, W. S.; Stockwell, W. R.

    2013-01-01

    We incorporate the recently developed Regional Atmospheric Chemistry Mechanism (version 2, RACM2) into the Community Multiscale Air Quality modeling system for comparison with the existing 2005 Carbon Bond mechanism with updated toluene chemistry (CB05TU). Compared to CB05TU, RACM2 enhances the domain-wide monthly mean hydroxyl radical concentrations by 46% and nitric acid by 26%. However, it reduces hydrogen peroxide by 2%, peroxyacetic acid by 94%, methyl hydrogen peroxide by 19%, peroxyace...

  5. A comparison of atmospheric composition using the Carbon Bond and Regional Atmospheric Chemistry Mechanisms

    OpenAIRE

    Sarwar, G.; J. Godowitch; Henderson, B.; K. Fahey; Pouliot, G.; W. T. Hutzell; Mathur, R.; Kang, D.; Goliff, W. S.; Stockwell, W. R.

    2013-01-01

    We incorporate the recently developed Regional Atmospheric Chemistry Mechanism (version 2, RACM2) into the Community Multiscale Air Quality modeling system for comparison with the existing 2005 Carbon Bond mechanism with updated toluene chemistry (CB05TU). Compared to CB05TU, RACM2 enhances the domain-wide monthly mean hydroxyl radical concentrations by 46% and nitric acid by 26%. However, it reduces hydrogen peroxide by 2%, peroxyacetic acid by 94%, methyl hydrogen peroxide by 19%, pe...

  6. Teaching Archaeology. ERIC Digest.

    Science.gov (United States)

    Brown, Gail William

    How could handchipped stones, ancient ruins, old broken dishes, and antiquated garbage help students learn about the world and themselves? Within archaeology, these seemingly irrelevant items can enlighten students about the world around them through science, culture, and history. When teaching archaeology in the classroom, educators can lead…

  7. Radiocarbon and Indian archaeology

    International Nuclear Information System (INIS)

    The increasing use of radiocarbon (C14) dating techniques in Indian archaeology has been described in detail. Work done in Microlithic cultures, Neolithic period, Indus civilization and Iron age cultures have been reported. C14 dates of various archaeological sites are listed. (K.B.)

  8. Chemistry

    International Nuclear Information System (INIS)

    The chemical research and development efforts related to the design and ultimate operation of molten-salt breeder reactor systems are concentrated on fuel- and coolant-salt chemistry, including the development of analytical methods for use in these systems. The chemistry of tellurium in fuel salt is being studied to help elucidate the role of this element in the intergranular cracking of Hastelloy N. Studies were continued of the effect of oxygen-containing species on the equilibrium between dissolved UF3 and dissolved UF4, and, in some cases, between the dissolved uranium fluorides and graphite, and the UC2. Several aspects of coolant-salt chemistry are under investigation. Hydroxy and oxy compounds that could be formed in molten NaBF4 are being synthesized and characterized. Studies of the chemistry of chromium (III) compounds in fluoroborate melts were continued as part of a systematic investigation of the corrosion of structural alloys by coolant salt. An in-line voltammetric method for determining U4+/U3+ ratios in fuel salt was tested in a forced-convection loop over a six-month period. (LK)

  9. Mechanical work makes important contributions to surface chemistry at steps

    OpenAIRE

    Francis, M. F.; Curtin, W. A.

    2015-01-01

    The effect of mechanical strain on the binding energy of adsorbates to late transition metals is believed to be entirely controlled by electronic factors, with tensile stress inducing stronger binding. Here we show, via computation, that mechanical strain of late transition metals can modify binding at stepped surfaces opposite to well-established trends on flat surfaces. The mechanism driving the trend is mechanical, arising from the relaxation of stored mechanical energy. The mechanical ene...

  10. OK computer? Digital community archaeologies in practice (Internet Archaeology 40

    Directory of Open Access Journals (Sweden)

    Seren Griffiths

    2015-12-01

    Full Text Available The articles in this section of Internet Archaeology came out of a Theoretical Archaeology Group session at Manchester University in 2014. The session was motivated to explore issues associated with 'digital public archaeology' (DPA. The articles presented here deal with a number of themes which arise when doing digital public archaeology.

  11. Archaeology and Photography: A Pragmatology

    DEFF Research Database (Denmark)

    Svabo, Connie; Shanks, Michael

    2013-01-01

    This chapter is an exploration of meta-archaeology. We consider some of the premises, dispositions, infrastructures of archaeological practices, where the archaeological is no longer a substantive, but adjectival, an aspect of things and doings, where archaeology is part of the trans...

  12. History of Historical Archaeology

    Directory of Open Access Journals (Sweden)

    Robert L. Schuyler

    1998-11-01

    Full Text Available On Sunday April 19, 1998 Jean Carl Harrington (known to the profession as J.C. or "Pinky" Harrington passed away at his home in Richmond, Virginia. At 96 Harrington's life almost spanned the 20th century and did encompass the rise and establishment of professional Historical Archaeology in North America. Many consider Harrington to be the founder or "father" of Americanist Historical Archaeology. In 1936 he took over the newly created NPS-CCC project at Jamestown, Virginia and that event is arguably the inception of Historical Archaeology as an organized, scholarly discipline.

  13. New approaches to chemical reaction mechanisms by means of radiation chemistry

    International Nuclear Information System (INIS)

    Since active species generated during radiolysis can be used as oxidative or reductive regents of various organic and inorganic compounds, radiation chemistry has been applied to wide range of research fields. We have studied charge-delocalization process in molecular systems, properties of intermediates in the excited states, mechanism of light emitting device, photo-catalyst for degradation of toxic compounds and so on by means of radiation chemistry. In the present paper, we summarize our recent research results. (author)

  14. Chemistry

    International Nuclear Information System (INIS)

    Research progress is reported in programs on fuel-salt chemistry, properties of compounds in the Li--Te system, Te spectroscopy UF4--H equilibria, porous electrode studies of molten salts, fuel salt-coolant salt reactions, thermodynamic properties of transition-metal fluorides, and properties of sodium fluoroborate. Developmental work on analytical methods is summarized including in-line analysis of molten MSBR fuel, analysis of coolant-salts for tritium, analysis of molten LiF--BeF2--ThF4 for Fe and analysis of LiF--BeF--ThF4 for Te

  15. Iowa Intensive Archaeological Survey

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — This shape file contains intensive level archaeological survey areas for the state of Iowa. All intensive Phase I surveys that are submitted to the State Historic...

  16. Mineralogy and chemistry of archaeological ceramic fragments from archaeological Dark Earth site in Colombian Amazon Mineralogia e química de fragmentos cerâmicos arqueológicos em sítio com Terra Preta da Amazônia Colombiana

    OpenAIRE

    Marcondes Lima da Costa; Gaspar Morcote Rios; Mônia Maria Carvalho da Silva; Glayce Jholy da Silva; Uliana Molano-Valdes

    2011-01-01

    Several Archaeological Dark Earth (ADE) sites have been already found in the Colombian Amazon forest showing high content of archaeological ceramic fragments similarly to those in the Brazilian Amazon represented by Quebrada Tacana site. Their fragments are yellow to grey colour, display a burned clayey matrix which involves fragments of cariapé and coal and ash particles, besides grains of quartz and micas. The clay matrix is made of metakaolinite, quartz, and some mica flakes, chlorite and ...

  17. Ash chemistry and sintering, verification of the mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Skrifvars, B.J.; Backman, R.; Lauren, T.; Uusikartano, T.; Malm, H.; Stenstroem, P.; Vesterkvist, M. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    In this project four sintering mechanisms have been studied, i.e., partial melting with a viscous liquid, partial melting with a non-viscous liquid, chemical reaction sintering and solid state sintering. The work has aimed at improving the understanding of ash sintering mechanisms and quantifying their role in combustion and gasification. The work has been oriented in particular on the understanding of biomass ash behavior. The work has not directly focused on any specific technical application. However, results can also be applied on other fuels such as brown coal, petroleum coke, black liquor and different types of wastes (PDF, RDF, MSW). During 1996 the work has focused on identifying bed agglomeration mechanisms and analysing bed agglomerates in both full scale and lab scale FB reactors, as well as comparing how well the compression strength based sintering test can predict bed agglomeration in an FB furnace. (orig.)

  18. Comprehensive mechanisms for combustion chemistry: Experiment, modeling, and sensitivity analysis

    Energy Technology Data Exchange (ETDEWEB)

    Dryer, F.L.; Yetter, R.A. [Princeton Univ., NJ (United States)

    1993-12-01

    This research program is an integrated experimental/numerical effort to study pyrolysis and oxidation reactions and mechanisms for small-molecule hydrocarbon structures under conditions representative of combustion environments. The experimental aspects of the work are conducted in large diameter flow reactors, at pressures from one to twenty atmospheres, temperatures from 550 K to 1200 K, and with observed reaction times from 10{sup {minus}2} to 5 seconds. Gas sampling of stable reactant, intermediate, and product species concentrations provides not only substantial definition of the phenomenology of reaction mechanisms, but a significantly constrained set of kinetic information with negligible diffusive coupling. Analytical techniques used for detecting hydrocarbons and carbon oxides include gas chromatography (GC), and gas infrared (NDIR) and FTIR methods are utilized for continuous on-line sample detection of light absorption measurements of OH have also been performed in an atmospheric pressure flow reactor (APFR), and a variable pressure flow (VPFR) reactor is presently being instrumented to perform optical measurements of radicals and highly reactive molecular intermediates. The numerical aspects of the work utilize zero and one-dimensional pre-mixed, detailed kinetic studies, including path, elemental gradient sensitivity, and feature sensitivity analyses. The program emphasizes the use of hierarchical mechanistic construction to understand and develop detailed kinetic mechanisms. Numerical studies are utilized for guiding experimental parameter selections, for interpreting observations, for extending the predictive range of mechanism constructs, and to study the effects of diffusive transport coupling on reaction behavior in flames. Modeling using well defined and validated mechanisms for the CO/H{sub 2}/oxidant systems.

  19. The Super-Fast Chemistry Mechanism for IPCC AR5 Simulations with CCSM

    Science.gov (United States)

    Cameron-Smith, P. J.; Prather, M. J.; Lamarque, J.; Hess, P. G.; Connell, P. S.; Bergmann, D. J.; Vitt, F. M.

    2009-12-01

    When atmospheric chemistry is included in long climate and Earth system simulations, the completeness of the chemical mechanism must be balanced with the computational cost, and the scientific interests of the atmospheric chemist must be tempered by the chemical needs of other components of the climate model (e.g, greenhouse gas concentrations for radiative heating, and deposition rates for biosphere interactions). We have implemented a super-fast chemical mechanism for use in IPCC AR5 simulations with the CCSM climate model. The mechanism uses just 17 species to calculate ozone, OH, and sulfate, with the OH providing the means to back-out the lifetime of methane and other species of interest. The recent addition of isoprene offers significant improvements to the sensitivity of the super-fast mechanism to emission perturbations when compared to our state-of-the-art full chemistry mechanism that uses 90 species. An analysis of the impact of different tropopause definitions will also be presented.

  20. Photographs and Archaeological Knowledge

    Directory of Open Access Journals (Sweden)

    Sudeshna Guha

    2013-11-01

    Full Text Available This article explores some of the ways in which photographs and their archives establish archaeological knowledge. It draws upon histories of photography and archaeology within South Asia to create focus upon archaeology’s evidentiary regimes. The aims are to: a demonstrate the importance of engaging with photographs and their archives as objects for reckoning archaeology’s evidentiary terrains, b draw attention to multiple social biographies a photograph or photographic archive acquires, c highlight the visual as a force of archaeology’s historiography, and d impress upon the necessity of attending to historiographical issues. The aims allow us in seeing some of the ways in which field sciences create their evidentiary frames, and have a special resonance within the context of South Asian archaeology where professional and amateur archaeologists continue to promote the belief that archaeological facts exist out there, and that archaeological research produces better and more robust sources for the past than scholarship based on texts. Visual histories also highlight the mutation of the so-called ‘colonialist’ historiography within the post-colonial histories of archaeology’s developments, and encourage us to go beyond the hackneyed formulations of colonial legacies and the hagiographic literature of individual practitioners.

  1. Chemistry

    International Nuclear Information System (INIS)

    Research and development activities dealing with the chemical problems related to design and ultimate operation of molten-salt reactor systems are described. An experimental test stand was constructed to expose metallurgical test specimens to Te2 vapor at defined temperatures and deposition rates. To better define the chemistry of fluoroborate coolant, several aspects are being investigated. The behavior of hydroxy and oxy compounds in molten NaBF4 is being investigated to define reactions and compounds that may be involved in corrosion and/or could be involved in methods for trapping tritium. Two corrosion products of Hastelloy N, Na3CrF6 and Na5Cr3F14, were identified from fluoroborate systems. The evaluation of fluoroborate and alternate coolants continued. Research on the behavior of hydrogen and its isotopes is summarized. The solubilities of hydrogen, deuterium, and helium in Li2BeF4 are very low. The sorption of tritium on graphite was found to be significant (a few milligrams of tritium per kilogram of graphite), possibly providing a means of sequestering a portion of the tritium produced. Development of analytical methods continued with emphasis on voltammetric and spectrophotometric techniques for the in-line analysis of corrosion products such as Fe2+ and Cr3+ and the determination of the U3+/U4+ ratio in MSBR fuel salt. Similar studies were conducted with the NaBF4--NaF coolant salt. Information developed during the previous operation of the CSTF has been assessed and used to formulate plans for evaluation of in-line analytical methods in future CSTF operations. Electroanalytical and spectrophotometric research suggests that an electroactive protonic species is present in molten NaBF4--NaF, and that this species rapidly equilibrates with a volatile proton-containing species. Data obtained from the CSTF indicated that tritium was concentrated in the volatile species. (JGB)

  2. Using Scanning Electron Microscopy with Energy Dispersive X-Ray Spectroscopy to Analyze Archaeological Materials

    Science.gov (United States)

    Hill, Adam D.; Lehman, Ann H.; Parr, Maria L.

    2007-01-01

    A course linking chemistry and archaeology was designed to introduce scientific principles and applications to students with little or no science background. The course could provide students an opportunity to explore the role of the sciences in archaeology and to discover the relationship between materials and the culture that produce them.

  3. Resource Letter TTSM-1: Teaching thermodynamics and statistical mechanics in introductory physics, chemistry, and biology

    OpenAIRE

    Dreyfus, Benjamin W.; Geller, Benjamin D.; Meltzer, David E.; Sawtelle, Vashti

    2014-01-01

    This Resource Letter draws on discipline-based education research from physics, chemistry, and biology to collect literature on the teaching of thermodynamics and statistical mechanics in the three disciplines. While the overlap among the disciplinary literatures is limited at present, we hope this Resource Letter will spark more interdisciplinary interaction.

  4. An Introductory Organic Chemistry Review Homework Exercise: Deriving Potential Mechanisms for Glucose Ring Opening in Mutarotation

    Science.gov (United States)

    Murdock, Margaret; Holman, R. W.; Slade, Tyler; Clark, Shelley L. D.; Rodnick, Kenneth J.

    2014-01-01

    A unique homework assignment has been designed as a review exercise to be implemented near the end of the one-year undergraduate organic chemistry sequence. Within the framework of the exercise, students derive potential mechanisms for glucose ring opening in the aqueous mutarotation process. In this endeavor, 21 general review principles are…

  5. 30 Years of Archaeological Research

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    China’s archaeology has achieved remarkable outcomes during the 30 years after the carrying out of the reform and opening up policy. In theoretical research, various archaeological theories and genres have been introduced to China, which have influenced the development of the archaeology of China.

  6. Chemistry and Heritage

    Science.gov (United States)

    Vittoria Barbarulo, Maria

    2014-05-01

    Chemistry is the central science, as it touches every aspect of the society we live in and it is intertwined with many aspects of our culture; in particular, the strong link between Chemistry and Archaeology and Art History is being explored, offering a penetrating insight into an area of growing interest from an educational point of view. A series of vital and vibrant examples (i.e., ancient bronzes composition, colour changes due to natural pigment decomposition, marble degradation) has been proposed, on one hand, to improve student understanding of the relationship between cultural and scientific issues arising from the examination, the conservation, and the maintenance of cultural Heritage, on the other, to illustrate the role of the underlying Chemistry. In some case studies, a survey of the most relevant atmospheric factors, which are involved in the deterioration mechanisms, has also been presented to the students. First-hand laboratory experiences have been providing an invaluable means of discovering the full and varied world of Chemistry. Furthermore, the promotion of an interdisciplinary investigation of a famous painting or fresco, involving the study of its nature and significance, the definition of its historical context, any related literature, the chemical knowledge of the materials used, may be an excellent occasion to experiment the Content and Language Integrated Learning (CLIL). The aim of this approach is to convey the important message that everyone has the responsibility to care for and preserve Heritage for the benefit of present and future generations.

  7. Building Sustainability in Community Archaeology: the Hendon School Archaeology Project

    Directory of Open Access Journals (Sweden)

    Gabriel Moshenska

    2011-10-01

    Full Text Available The Hendon School Archaeology Project is a collaboration between Hendon School, the Hendon and District Archaeological Society (HADAS and the UCL Institute of Archaeology. It aims to provide students at the school with an experience and understanding of archaeological fieldwork, while investigating an important multi-period site. This paper outlines the results of the first five years of the project: both the archaeological findings, and as an innovative collaborative form of community archaeology. The principal focus of research is the 16th-century residence of John Norden, cartographer to Elizabeth I; however, the most significant discovery to date is a substantial ceramic assemblage of 12th to 14th-century date. As community archaeology, an important aspect is the sustainability of the project, based on cost and resource sharing between the project partners, which we believe may offer a useful model for other such initiatives.

  8. Galactic Archaeology: Current Surveys

    CERN Document Server

    Wyse, Rosemary F G

    2016-01-01

    I present an overview of the science goals and achievements of ongoing spectroscopic surveys of individual stars in the nearby Universe. I include a brief discussion of the development of the field of Galactic Archaeology - using the fossil record in old stars nearby to infer how our Galaxy evolved and place the Milky Way in cosmological context.

  9. Archaeological Discoveries in Liaoning

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    LIAONING Province, in northeastern China, has been inhabited by many ethnic groups since ancient times. It is one of the sites of China’s earliest civilization. Since the 1950s many archaeological discoveries from periods beginning with the Paleolithic of 200,000 years ago, and through all the following historic periods, have been made in the province.

  10. Islamic Archaeology in Qatar

    DEFF Research Database (Denmark)

    Walmsley, Alan

    2014-01-01

    Three years of archaeological research at Al Zubarah on the northwest coast of the Qatar peninsula has produced detailed information on social, cultural, and economic structures of a major trading town of the Gulf in the 18th and 19th centuries CE. Detailed investigations, undertaken in partnership...

  11. Archaeology in Social Studies: An Integrated Approach. Theme: Archaeology in the Classroom.

    Science.gov (United States)

    Devine, Heather

    1989-01-01

    Provides a rationale for integrating archaeology into the social studies classroom, suggesting archaeology topics that satisfy knowledge goals in the curriculum. Describes field trip, excavation, and experimental archaeology activities. Includes lists of archaeological agencies and teacher references. (LS)

  12. Archaeology, landscape and aesthetics

    Directory of Open Access Journals (Sweden)

    David E. Cooper

    2015-12-01

    Full Text Available This paper examines the role, if any, of aesthetic reflections in the discipline of landscape archaeology. It begins by rejecting the charge that archaeologists should set aside their own aesthetic sensibility when studying landscapes. The bulk of the paper, however, is concerned with arguing that attention to the aesthetic sensibilities of the peoples who made the landscapes studied is essential to the kind of understanding and reconstruction of ways of life that landscape archaeology aims to provide. Two important themes that are developed during the course of this argument are: (1 a distinction (ignored by some archaeologists who are critical of appeals to aesthetic enjoyment between aesthetic appreciation and a dilettante “aestheticism” and (2 the aesthetic satisfactions that must be taken in work, such as farming, if this is to flourish.

  13. Additive archaeology: an alternative framework for recontextualising archaeological entities

    OpenAIRE

    Reilly Paul

    2015-01-01

    Additive manufacturing poses a number of challenges to conventional understandings of materiality, including the so-called archaeological record. In particular, concepts such as real, virtual, and authentic are becoming increasingly unstable, as archaeological artefacts and assemblages can be digitalised, reiterated, extended and distributed through time and space as 3D printable entities. This paper argues that additive manufacturing represents a ‘grand disciplinary challenge’ to archaeologi...

  14. Drones in Archaeology

    KAUST Repository

    Smith, Neil

    2014-09-01

    In late 2013, a joint archaeological and computer vision project was initiated to digitally capture the archaeological remains in the al-Ula valley, Saudi Arabia. The goal of our team of archeologists and computer scientists is to integrate 3D scanning technologies to produce 3D reconstructions of archaeological sites. Unmanned Aerial Vehicles (UAVs) serve as the vehicle which makes this scanning possible. UAVs allow the acquisition of 3D data as easily from the air as from the ground. This project focuses on the recent excavations carried out in ancient Dedan by King Saud University and the country\\'s conservation of the Lihyanite "lion tombs" carved into the ancient city\\'s cliff faces. Over the next several years this site will be used as a test bed to validate the potential of this emerging technology for rapid cultural heritage documentation. We additionally scanned several areas in Mada\\'in Saleh, an ancient Nabatean city filled with monumental carved sandstone tomb facades, rivaled only by the capital of the Nabatean empire: Petra.

  15. Future archaeologies : method and story.

    OpenAIRE

    Watts, Laura

    2009-01-01

    This will be an account of an ongoing experiment called 'future archaeology'. Despite it’s name it's not strictly an archaeological experiment, since I’m not an archaeologist. Nor is it strictly scientific, since I’m not a natural scientist. However, it is an empirical experiment: it draws on evidence, it draws on artefacts, it has a method, and is theoretically grounded in critical social sciences, science studies, anthropology, and archaeological theory.

  16. History of marine archaeological research in India

    Digital Repository Service at National Institute of Oceanography (India)

    Tripati, S.

    archaeology we study the past activities of human from maritime finds, usually from shipwrecks, sunken ports and settlements. Nautical archaeology is studied and explained as maritime archaeology, specialising in maritime activities and technology of ships...

  17. Internet Archaeology News

    Directory of Open Access Journals (Sweden)

    Cèsar Carreras Monfort

    1999-05-01

    Full Text Available La revista Internet Archaeology News s'adreça a un públic restringit, especialitzat en arqueologia i sobretot en aplicacions de caràcter informàtic i noves metodologies de treball. El fet que la revista neixi amb la voluntat d'ésser innovadora en el seu camp i molt especialitzada no treu que el nivell de les col·laboracions sigui de força qualitat gràcies a la política del equip editorial.

  18. A comparison of atmospheric composition using the Carbon Bond and Regional Atmospheric Chemistry Mechanisms

    Directory of Open Access Journals (Sweden)

    G. Sarwar

    2013-10-01

    Full Text Available We incorporate the recently developed Regional Atmospheric Chemistry Mechanism (version 2, RACM2 into the Community Multiscale Air Quality modeling system for comparison with the existing 2005 Carbon Bond mechanism with updated toluene chemistry (CB05TU. Compared to CB05TU, RACM2 enhances the domain-wide monthly mean hydroxyl radical concentrations by 46% and nitric acid by 26%. However, it reduces hydrogen peroxide by 2%, peroxyacetic acid by 94%, methyl hydrogen peroxide by 19%, peroxyacetyl nitrate by 40%, and organic nitrate by 41%. RACM2 enhances ozone compared to CB05TU at all ambient levels. Although it exhibited greater overestimates at lower observed concentrations, it displayed an improved performance at higher observed concentrations. The RACM2 ozone predictions are also supported by increased ozone production efficiency that agrees better with observations. Compared to CB05TU, RACM2 enhances the domain-wide monthly mean sulfate by 10%, nitrate by 6%, ammonium by 10%, anthropogenic secondary organic aerosols by 42%, biogenic secondary organic aerosols by 5%, and in-cloud secondary organic aerosols by 7%. Increased inorganic and organic aerosols with RACM2 agree better with observed data. Any air pollution control strategies developed using the two mechanisms do not differ appreciably.

  19. A comparison of atmospheric composition using the Carbon Bond and Regional Atmospheric Chemistry Mechanisms

    Directory of Open Access Journals (Sweden)

    G. Sarwar

    2013-03-01

    Full Text Available We incorporate the recently developed Regional Atmospheric Chemistry Mechanism (version 2, RACM2 into the Community Multiscale Air Quality modeling system for comparison with the existing 2005 Carbon Bond mechanism with updated toluene chemistry (CB05TU. Compared to CB05TU, RACM2 enhances the domain-wide monthly mean hydroxyl radical concentrations by 46% and nitric acid by 26%. However, it reduces hydrogen peroxide by 2%, peroxyacetic acid by 94%, methyl hydrogen peroxide by 19%, peroxyacetyl nitrate by 40%, and organic nitrate by 41%. RACM2 predictions generally agree better with the observed data than the CB05TU predictions. RACM2 enhances ozone for all ambient levels leading to higher bias at low (70 ppbv concentrations. The RACM2 ozone predictions are also supported by increased ozone production efficiency that agrees better with observations. Compared to CB05TU, RACM2 enhances the domain-wide monthly mean sulfate by 10%, nitrate by 6%, ammonium by 10%, anthropogenic secondary organic aerosols by 42%, biogenic secondary organic aerosols by 5%, and in-cloud secondary organic aerosols by 7%. Increased inorganic and organic aerosols with RACM2 agree better with observed data. While RACM2 enhances ozone and secondary aerosols by relatively large margins, control strategies developed for ozone or fine particles using the two mechanisms do not differ appreciably.

  20. Indigenous Archaeology as Decolonizing Practice

    Science.gov (United States)

    Atalay, Sonya

    2006-01-01

    Archaeological methods of analysis, research directions, and theoretical approaches have changed dramatically since the early days of the discipline, and today archaeological research topics relate to various aspects of cultural heritage, representation, and identity that overlap with fields such as ethnic studies, cultural anthropology, art and…

  1. Kant and the nature of matter: Mechanics, chemistry, and the life sciences.

    Science.gov (United States)

    Gaukroger, Stephen

    2016-08-01

    Kant believed that the ultimate processes that regulate the behavior of material bodies can be characterized exclusively in terms of mechanics. In 1790, turning his attention to the life sciences, he raised a potential problem for his mechanically-based account, namely that many of the operations described in the life sciences seemed to operate teleologically. He argued that the life sciences do indeed require us to think in teleological terms, but that this is a fact about us, not about the processes themselves. Nevertheless, even were we to concede his account of the life sciences, this would not secure the credentials of mechanics as a general theory of matter. Hardly any material properties studied in the second half of the eighteenth century were, or could have been, conceived in mechanical terms. Kant's concern with teleology is tangential to the problems facing a general matter theory grounded in mechanics, for the most pressing issues have nothing to do with teleology. They derive rather from a lack of any connection between mechanical forces and material properties. This is evident in chemistry, which Kant dismisses as being unscientific on the grounds that it cannot be formulated in mechanical terms.

  2. Kant and the nature of matter: Mechanics, chemistry, and the life sciences.

    Science.gov (United States)

    Gaukroger, Stephen

    2016-08-01

    Kant believed that the ultimate processes that regulate the behavior of material bodies can be characterized exclusively in terms of mechanics. In 1790, turning his attention to the life sciences, he raised a potential problem for his mechanically-based account, namely that many of the operations described in the life sciences seemed to operate teleologically. He argued that the life sciences do indeed require us to think in teleological terms, but that this is a fact about us, not about the processes themselves. Nevertheless, even were we to concede his account of the life sciences, this would not secure the credentials of mechanics as a general theory of matter. Hardly any material properties studied in the second half of the eighteenth century were, or could have been, conceived in mechanical terms. Kant's concern with teleology is tangential to the problems facing a general matter theory grounded in mechanics, for the most pressing issues have nothing to do with teleology. They derive rather from a lack of any connection between mechanical forces and material properties. This is evident in chemistry, which Kant dismisses as being unscientific on the grounds that it cannot be formulated in mechanical terms. PMID:27474191

  3. Effect of Surface Chemistry on the Mechanisms and Governing Laws of Friction and Wear.

    Science.gov (United States)

    Dai, Ling; Sorkin, Viacheslav; Zhang, Yong-Wei

    2016-04-01

    Recent studies have shown that interface chemistry, that is, the formation and breaking of chemical bonds across contacting interfaces, is closely related to the wear and friction behavior at the nanoscale. In reality, the dangling bond density (DBD) at contacting surfaces can vary greatly. Currently, it remains unclear how friction and wear mechanisms depend on DBDs and whether the Archard's law for wear and Amonton's law for friction are still applicable for contacting surfaces with different DBDs. In this work, we address these issues by studying the wear and friction behavior between two sliding diamond-like carbon surfaces by controlling DBDs via hydrogenation using molecular dynamics simulations. It is found that the chemical bond breaking and remaking across the contacting interface play the key role in determining the friction and wear behavior. During the sliding, a higher DBD leads to more chemical bond formations across the interface, causing stronger wear via either atom or cluster detachments. With the same DBD, a mechanism transition from an atom-by-atom to cluster detachments is observed by increasing the normal load. Remarkably, a fully saturated surface can exhibit a wearless friction. We further show that after necessary modifications, the Archard's law for wear and the Amonton's law for friction may be applicable at the nanoscale. The present work reveals insights into the effect of interface chemistry on the friction and wear, and it provides guidelines for effective antiwear design. PMID:27004415

  4. An Exercise in Theoretical Archaeology: Do Archaeological Cultures Exist?

    Directory of Open Access Journals (Sweden)

    Marko Porčić

    2016-02-01

    Full Text Available Archaeological culture still persists as a basic analytical and interpretative concept in Serbian archaeology despite criticism. This paper presents a formal view of archaeological cultures and explores the epistemological implications of this formalization. Formal analysis of archaeological culture is achieved through logical and quantitative explication of the traditional definition of archaeological cultures. The main result of the formal analysis is that there are real patterns of formal variability of material culture that may or may not correspond to traditional archaeological cultures. These patterns are real only in the analytical sense – they are real for given input data and scale of analysis. Unlike the traditional approach where this patterns are equated with archaeological cultures which are furthered interpreted in essentialist terms or as quasi- organic entities such as ethnic groups, it is claimed here that discovered patterns are only the starting point – the empirical situation that needs to be accounted for in anthropological an historical terms. This paper shows how patterns that are traditionally identified as archaeological cultures can arise as a consequence of an entire range of processes – different social and historical realities. The main conclusion is that the traditional concept of archaeological culture is not useful neither as analytical or interpretative tools for two reasons: 1 traditional cultures are subjectively defined entities with no theoretical justification for the criteria used in their definition and 2 the empirical pattern cannot be an explanation in itself because it is the thing that needs to be explained. Cultural evolutionary (transmission theory is proposed as a general framework for defining and interpreting patterns of formal variability of material culture in time and space.

  5. The 2015 Nobel Prize in Chemistry The Discovery of Essential Mechanisms that Repair DNA Damage.

    Science.gov (United States)

    Lindahl, Tomas; Modrich, Paul; Sancar, Aziz

    2016-01-01

    The Royal Swedish Academy awarded the Nobel Prize in Chemistry for 2015 to Tomas Lindahl, Paul Modrich and Aziz Sancar for their discoveries in fundamental mechanisms of DNA repair. This pioneering research described three different essential pathways that correct DNA damage, safeguard the integrity of the genetic code to ensure its accurate replication through generations, and allow proper cell division. Working independently of each other, Tomas Lindahl, Paul Modrich and Aziz Sancar delineated the mechanisms of base excision repair, mismatch repair and nucleotide excision repair, respectively. These breakthroughs challenged and dismissed the early view that the DNA molecule was very stable, paving the way for the discovery of human hereditary diseases associated with distinct DNA repair deficiencies and a susceptibility to cancer. It also brought a deeper understanding of cancer as well as neurodegenerative or neurological diseases, and let to novel strategies to treat cancer.

  6. The 2015 Nobel Prize in Chemistry The Discovery of Essential Mechanisms that Repair DNA Damage.

    Science.gov (United States)

    Lindahl, Tomas; Modrich, Paul; Sancar, Aziz

    2016-01-01

    The Royal Swedish Academy awarded the Nobel Prize in Chemistry for 2015 to Tomas Lindahl, Paul Modrich and Aziz Sancar for their discoveries in fundamental mechanisms of DNA repair. This pioneering research described three different essential pathways that correct DNA damage, safeguard the integrity of the genetic code to ensure its accurate replication through generations, and allow proper cell division. Working independently of each other, Tomas Lindahl, Paul Modrich and Aziz Sancar delineated the mechanisms of base excision repair, mismatch repair and nucleotide excision repair, respectively. These breakthroughs challenged and dismissed the early view that the DNA molecule was very stable, paving the way for the discovery of human hereditary diseases associated with distinct DNA repair deficiencies and a susceptibility to cancer. It also brought a deeper understanding of cancer as well as neurodegenerative or neurological diseases, and let to novel strategies to treat cancer. PMID:27183258

  7. Potassium sorbate as an inhibitor in copper chemical mechanical planarization slurry. Part I. Elucidating slurry chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Nagar, Magi; Starosvetsky, David [Department of Materials Engineering, Technion Israel Institute of Technology, Haifa 32000 (Israel); Vaes, Jan [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Ein-Eli, Yair, E-mail: eineli@tx.technion.ac.i [Department of Materials Engineering, Technion Israel Institute of Technology, Haifa 32000 (Israel)

    2010-04-01

    The integration of an advanced inhibitor, potassium sorbate (K[CH{sub 3}(CH){sub 4}CO{sub 2}]), in a copper CMP slurry based on hydrogen peroxide and glycine is reported. The first part of the study discusses the slurry chemistry by qualitatively describing the processes involved and proposes a mechanism for a hydrogen peroxide-glycine based slurry having sorbate anion as an inhibitor. For this purpose, the specific role of each chemical constituent in the slurry was elucidated at a fundamental level by electrochemical studies, X-ray photon spectroscopy (XPS) and contact angle measurements, all linked to the CMP performance on blanket wafers. Once the polishing mechanism was resolved the influence of the inhibitor was evaluated by CMP processing of patterned wafers.

  8. Computational organic chemistry: bridging theory and experiment in establishing the mechanisms of chemical reactions.

    Science.gov (United States)

    Cheng, Gui-Juan; Zhang, Xinhao; Chung, Lung Wa; Xu, Liping; Wu, Yun-Dong

    2015-02-11

    Understanding the mechanisms of chemical reactions, especially catalysis, has been an important and active area of computational organic chemistry, and close collaborations between experimentalists and theorists represent a growing trend. This Perspective provides examples of such productive collaborations. The understanding of various reaction mechanisms and the insight gained from these studies are emphasized. The applications of various experimental techniques in elucidation of reaction details as well as the development of various computational techniques to meet the demand of emerging synthetic methods, e.g., C-H activation, organocatalysis, and single electron transfer, are presented along with some conventional developments of mechanistic aspects. Examples of applications are selected to demonstrate the advantages and limitations of these techniques. Some challenges in the mechanistic studies and predictions of reactions are also analyzed.

  9. Biomarker in archaeological soils

    Science.gov (United States)

    Wiedner, Katja; Glaser, Bruno; Schneeweiß, Jens

    2015-04-01

    The use of biomarkers in an archaeological context allow deeper insights into the understanding of anthropogenic (dark) earth formation and from an archaeological point of view, a completely new perspective on cultivation practices in the historic past. During an archaeological excavation of a Slavic settlement (10th/11th C. A.D.) in Brünkendorf (Wendland region in Northern Germany), a thick black soil (Nordic Dark Earth) was discovered that resembled the famous terra preta phenomenon. For the humid tropics, terra preta could act as model for sustainable agricultural practices and as example for long-term CO2-sequestration into terrestrial ecosystems. The question was whether this Nordic Dark Earth had similar properties and genesis as the famous Amazonian Dark Earth in order to find a model for sustainable agricultural practices and long term CO2-sequestration in temperate zones. For this purpose, a multi-analytical approach was used to characterize the sandy-textured Nordic Dark Earth in comparison to less anthropogenically influenced soils in the adjacent area in respect of ecological conditions (e.g. amino sugar), input materials (faeces) and the presence of stable soil organic matter (black carbon). Amino sugar analyses showed that Nordic Dark Earth contained higher amounts of microbial residues being dominated by soil fungi. Faecal biomarkers such as stanols and bile acids indicated animal manure from omnivores and herbivores but also human excrements. Black carbon content of about 30 Mg ha-1 in the Nordic Dark Earth was about four times higher compared to the adjacent soil and in the same order of magnitude compared to terra preta. Our data strongly suggest parallels to anthropogenic soil formation in Amazonia and in Europe by input of organic wastes, faecal material and charred organic matter. An obvious difference was that in terra preta input of human-derived faecal material dominated while in NDE human-derived faecal material played only a minor role

  10. THE EFFECT OF CHEMISTRY AND NETWORK STRUCTURE ON MORPHOLOGICAL AND MECHANICAL PROPERTIES OF DIEPOXIDE PRECURSORS AND POLY(HYDROXYETHERS)

    OpenAIRE

    Bump, Maggie Bobbitt

    2001-01-01

    This dissertation research addresses the interrelationships between chemistry and network structure in epoxy networks as well as how mechanical properties of the resulting networks are affected by these relationships. The effects of chemistry and network structure on interphase morphology and performance in vinyl ester/carbon fiber composites have also been investigated on both a macro and nanoscale. Thermosets were prepared with blends of bisphenol-A and novel phosphine oxide based die...

  11. Archaeology in Indiana: The Science Today.

    Science.gov (United States)

    Jones, James R., III, Ed.; Johnson, Amy, Ed.; Bennett, Pamela J., Ed.

    1999-01-01

    This issue continues the Indiana Historical Bureau's collaboration with the Division of Historic Preservation and Archaeology, Indiana Department of Natural Resources. The articles include "The Science of Archaeology," chronicling the remarkable transformation of the science of archaeology to date; "Archaeology in Indiana," providing a brief…

  12. Indigenous archaeology as complement to, not separate from, scientific archaeology

    Directory of Open Access Journals (Sweden)

    Joe Watkins

    2013-10-01

    Full Text Available Defining Indigenous Archaeology is as difficult as defining “Indigenous”. In some areas the term “Indigenous” is applied to people who existed in an area prior to colonization (“Geography”; in other areas it is applied to people who are to those people whose ancestors created the culture being (“Descendancy”; in others it is applied to the community of people who live in the area where the archaeology is being conducted (“Proximity”. This paper recognizes that Archaeology, however defined, has characteristics that add to the scientific study of the human past; that Indigenous Archaeology is not meant to supplant scientific archaeology but to add to archaeology’s powers. In this paper I will provide an overview of Indigenous Archaeology, examine some of the in trying to discuss its many facets as a single disciplinary approach to the of the past, and then close with an examination of the in the generalized approach to the study of the past by partnering with communities and organizations.

  13. Marine archaeological research in India

    Digital Repository Service at National Institute of Oceanography (India)

    Tripati, S.; Sundaresh; Vora, K.H.; Bandodkar, S.N.

    of this activity. All the developed countries have made tremendous progress in this field and substantial progress has been made in India in marine archaeology. Over the years the National Institute of Oceanography in collaboration with other Government agencies...

  14. The Archaeology of Egyptian Monasticism

    DEFF Research Database (Denmark)

    Blanke, Louise

    The study of Egyptian monasticism has traditionally relied heavily on the rich corpus of textual sources, while the archaeological remains have been secondary to our understanding of monastic life. This imbalance has resulted in a situation where questions pertinent to the physical remains...... of monasteries ha ve largely remained unanswered. Based on first - hand archaeological material from the White Monastery federation and comparative material obtained through archaeological reports, the thesis addresses Egypt ian Monasticism in the transition from Late Antiquity to the Early Islamic period......, by examining three main themes through seven chapters. These themes are: 1. the relationship between the archaeological and textual sources pertinent to the White Monastery; 2. the diachronic development of the White Monastery and the process es that caused its abandonment; 3. the economy of the White...

  15. Bioadhesion of mussels and geckos: Molecular mechanics, surface chemistry, and nanoadhesives

    Science.gov (United States)

    Lee, Haeshin

    The adhesive strategies of living creatures are diverse, ranging from temporary to permanent adhesions with various functions such as locomotion, self-defense, communication, colony formation, and so on. The classic example of temporary adhesion is the gecko, which is known for its ability to walk along vertical and even inverted surfaces; this remarkable adhesion arises from the interfacial weak interactions of van der Waals and capillary forces. In contrast, a celerbrated example of permanent adhesion is found in marine mussels which secrete protein adhesives that function in aqueous environments without mechanical failure against turbulent conditions on the seashore. In addition, mussel adhesives stick to virtually all inorganic and organic surfaces. However, most commonly used man-made adhesives lack such unique adhesion properties compared to their natural counterparts. For example, many commercial adhesives quickly lose their adhesive strength when exposed to solvents, particularly water. The first part of this thesis focused on adhesion mechanics of mussels at a single-molecule level, in which the adhesive molecule showed surprisingly strong yet reversible adhesion on inorganic surfaces but exhibited irreversible covalent bond formation on organic surfaces. Strong and reversible adhesion on mucin surfaces was found, indicating potential application for drug delivery via mucus layers. Next, inspired by the mussel's versatile adhesion on a wide variety of material surfaces, a material-independent surface modification chemistry called 'polydopamine coating' is described. This concept was subsequently adapted to develop a surface-independent polymeric primer for layer-by-layer assembly of multifunctional coatings. Finally, a new bio-hybrid adhesive 'geckel' was developed by the functional combination of adhesion strategies of geckos and mussels. The new bio-inspired adhesive and material-independent surface chemistry can revolutionize the research areas such as

  16. Ferrous archaeological analogues for the understanding of the multi-secular corrosion mechanisms in an anoxic environment; Les analogues archeologiques ferreux pour la comprehension des mecanismes de corrosion multiseculaire en milieu anoxique

    Energy Technology Data Exchange (ETDEWEB)

    Saheb-Djahromi, M.

    2009-12-15

    Understanding the long term corrosion mechanisms of iron in an anoxic environment is essential in the field of the radioactive waste storage. In France, it is planned to store high level nuclear wastes in a multi-barrier system containing a glassy matrix surrounded by a stainless steel container, embedded in a low-carbon steel over-container. This system would be placed in a deep geological repository, which would impose anoxic conditions. As it must be efficient for a period of several thousands of years, one should understand the alteration mechanisms that are expected to occur in such a long time. To this purpose, a specific approach is developed on ferrous archaeological analogues with thick corrosion layer formed in natural conditions. In this study, the corrosion mechanisms have been assessed by examining nails aged of 400 years coming from the archaeological site of Glinet, selected as a reference site. The first point was a fine characterisation of the entire corrosion system metal / corrosion products / medium, through the use of coupled multi-scale analytical tools. The first results showed that the samples were corroded in an anoxic calco-carbonated environment. Moreover, the coupling of X-ray micro-diffraction, Raman microspectroscopy and dispersive energy spectroscopy has enabled to identify three corrosion systems composed of iron carbonates, siderite and chukanovite, and magnetite. Depending on the phase's layout in the system, the electronic resistance of the corrosion layers has been established, from resistive to conductive. In a second stage, re-corroding experiments in laboratory were performed. Firstly, the electrochemical behaviour of the corrosion system has shown that water reduction at the metallic interface is negligible. Furthermore, reaction tracing with copper and deuterium has allowed identifying the electron consumptions sites mainly localised on the external part, and the precipitation sites on the internal part of the corrosion

  17. Galactic Archaeology and Minimum Spanning Trees

    CERN Document Server

    Macfarlane, B A; Flynn, C M L

    2015-01-01

    Chemical tagging of stellar debris from disrupted open clusters and associations underpins the science cases for next-generation multi-object spectroscopic surveys. As part of the Galactic Archaeology project TraCD (Tracking Cluster Debris), a preliminary attempt at reconstructing the birth clouds of now phase-mixed thin disk debris is undertaken using a parametric minimum spanning tree (MST) approach. Empirically-motivated chemical abundance pattern uncertainties (for a 10-dimensional chemistry-space) are applied to NBODY6-realised stellar associations dissolved into a background sea of field stars, all evolving in a Milky Way potential. We demonstrate that significant population reconstruction degeneracies appear when the abundance uncertainties approach 0.1 dex and the parameterised MST approach is employed; more sophisticated methodologies will be required to ameliorate these degeneracies.

  18. Investigating Differences in Isoprene Oxidation Chemistry Between Gas-Phase Mechanisms Using a Constrained Chemical Box Model

    Science.gov (United States)

    Marvin, M. R.; Wolfe, G. M.; Salawitch, R. J.; Canty, T. P.; Hanisco, T. F.; Kaiser, J.; Keutsch, F. N.; Graus, M.; Warneke, C.; De Gouw, J. A.; Gilman, J.; Lerner, B. M.; Peischl, J.; Veres, P. R.; Min, K. E.; Holloway, J. S.; Aikin, K. C.; Ryerson, T. B.; Roberts, J. M.; Brown, S. S.; Pollack, I. B.; Hatch, C. D.; Lee, B. H.; Lopez-Hilfiker, F.; Thornton, J. A.; Diskin, G. S.; Sachse, G. W.; Huey, L. G.; Liu, X.; Wisthaler, A.; Mikoviny, T.; Wennberg, P. O.; St Clair, J.; Crounse, J.; Teng, A.

    2015-12-01

    Oxidation of isoprene by OH can significantly influence concentrations of important atmospheric pollutants such as ozone and secondary organic aerosols, but the chemistry that describes the relationships between these species is complex and not fully understood. Debate on the topic has led to differences in the isoprene oxidation schemes of several gas-phase chemical mechanisms currently applied in air chemistry models. We use the University of Washington Chemical Model (UWCMv3) to evaluate these mechanisms with respect to isoprene chemistry based on observations from the SENEX and SEAC4RS aircraft campaigns. The campaigns provide constraints on compounds measured over the Southeast United States, where isoprene concentrations are high and other conditions (e.g., NOx levels) vary widely. The payloads for both missions include observations of a wide range of isoprene oxidation products, which can provide insight into specific oxidation pathways. Analysis will focus on the characterization and comparison of isoprene oxidation chemistry for established gas-phase mechanisms that are prevalent in atmospheric modeling today, including the Carbon Bond mechanism (CB05 and CB6r2) and the Master Chemical Mechanism (versions 3.2 and 3.3).

  19. Mass spectrometry. Environment, biology, oenology, medicine, geology, chemistry, archaeology, mechanisms; Spectrometrie de masse. Environnement, biologie, oenologie, medecine, geologie, chimie, archeologie, mecanismes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    This document provides the papers (communications and posters) presented at the 16. French days of mass spectrometry, held September 6-9, 1999 in Nancy, France. 5 papers are interesting for the INIS database and are analyzed separately. (O.M.)

  20. Mass spectrometry. Environment, biology, oenology, medicine, geology, chemistry, archaeology, mechanisms; Spectrometrie de masse. Environnement, biologie, oenologie, medecine, geologie, chimie, archeologie, mecanismes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    This document provides the papers (communications and posters) presented at the 16. French days of mass spectrometry, held September 6-9, 1999 in Nancy, France. 7 papers are interesting for the ETDE database and are analyzed separately. (O.M.)

  1. Mechanisms before Reactions: A Mechanistic Approach to the Organic Chemistry Curriculum Based on Patterns of Electron Flow

    Science.gov (United States)

    Flynn, Alison B.; Ogilvie, William W.

    2015-01-01

    A significant redesign of the introductory organic chemistry curriculum at the authors' institution is described. There are two aspects that differ greatly from a typical functional group approach. First, organic reaction mechanisms and the electron-pushing formalism are taught before students have learned a single reaction. The conservation of…

  2. Archaeology on Screen: Representing Archaeology on Film in Serbia

    Directory of Open Access Journals (Sweden)

    Aleksandar Bandović

    2016-02-01

    Full Text Available Reading the popular culture may contribute to the reflexive view on a discipline such as archaeology. Film, as a part of popular culture, frequently unveils the hidden messages, which may be an echo of a discipline or its distorted image in the mirror. Film and archaeology share not only the common origins in the modernity, but also the imaginary spaces where the past and the present meet and intertwine. The subjects treated in films, the contexts in which archaeology appears, speak of the place the discipline holds in the society, reminding us at the same time of all the elements encompassed by the archaeological discourse. On the other hand, if we compare the portraits of the imaginary archaeologists (such as Professor Mihajlo Pavlović, Vera Zarić, with the witnesses of archaeology in Serbia over the 20th century (Nikola Vulić, Dragoslav Srejović, Milutin Garašanin, we shall approach the meeting point between academic and general public, science and the audience, theory and practice. Extraordinary individuals, unemployed dreamers living at the borders of the worlds, charming connoisseurs of the underworlds – these are but some of the qualities ascribed to the discipline by the films. However, these stereotypes do not generate out of the void, they are the consequence of the self-representation. This mystification of the discipline leads us back to the debate on the responsibility and ethics of the social scientists inside the society they live in. Of course, the suggested reading is one of the many possibilities, one of the archaeological interpretations.

  3. Introduction: Critical Blogging in Archaeology

    Directory of Open Access Journals (Sweden)

    Colleen Morgan

    2015-05-01

    Full Text Available This special volume of Internet Archaeology collects the leading voices of blogging in archaeology to provide a critical examination of informal, online self-publication. This collection of articles is one result of over a decade of digital communication; the confluence of a conversation that grew from a few lonely voices to a tumultuous cacophony. Even so, blogging has had very little scrutiny in wider archaeological publication (but see Caraher 2008; Kansa and Deblauwe 2011. The first movement toward this volume was the Blogging Archaeology session at the 2011 Society for American Archaeology meetings, accompanied by a "Blog Carnival," a groundbreaking effort to foment reflexive discussion prior to the conference. Several participants of this original session and blog carnival have contributed to this volume; these articles are intermingled with perspectives from contributors who have started blogging in the intervening time, and with peer review comments from archaeologists who have blogged for a long time, and from those who do not blog at all.

  4. Mineralogy and chemistry of archaeological ceramic fragments from archaeological Dark Earth site in Colombian Amazon Mineralogia e química de fragmentos cerâmicos arqueológicos em sítio com Terra Preta da Amazônia Colombiana

    Directory of Open Access Journals (Sweden)

    Marcondes Lima da Costa

    2011-03-01

    Full Text Available Several Archaeological Dark Earth (ADE sites have been already found in the Colombian Amazon forest showing high content of archaeological ceramic fragments similarly to those in the Brazilian Amazon represented by Quebrada Tacana site. Their fragments are yellow to grey colour, display a burned clayey matrix which involves fragments of cariapé and coal and ash particles, besides grains of quartz and micas. The clay matrix is made of metakaolinite, quartz, and some mica flakes, chlorite and sepiolite. Cariapé and cauixi spicules are constituted of cristobalite, which is also the main mineral component of the coal and ashes. Although not detected by X-ray diffraction, the phosphate minerals should be present, since the contents of phosphor reach up to 2.90 Wt.% P2O5. Possibly it occurs as aluminium-phosphate, since Ca contents fall below 0.1 Wt.%. These mineralogical and chemical characteristics allow to correlate these ceramic fragments with those found in the ADE in Brazil and reinforce phosphor as an important chemical component, which indicates human activity by the daily use of pottery all over the Amazon region.Vários sítios arqueológicos de Terra Preta Arqueológica (TPA encontrados na floresta Amazônica Colombiana também contêm alto conteúdo de fragmentos cerâmicos semelhantes aqueles da Amazônia Brasileira, como mostra o sítio Quebrada Tacana. Seus fragmentos cerâmicos são amarelo a cinza, exibem matriz argilosa calcinada envolvendo fragmentos de cariapé, carvão e partículas de cinza, grãos de quartzo e micas. A matriz é composta de metacaulinita a material amorfo, quartzo, folhas de micas, clorita e sepiolita. Cariapé e cauixi são constituídos de cristobalita, da mesma forma o carvão e as cinzas. Embora não detectados pela difração de raios x, os fosfatos devem estar presentes, pois foram detectados teores de P2O5 de até 2,90 %, possivelmente como fosfatos de alumínio, já que o conteúdo de Ca está abaixo 0

  5. Digital fruition of archaeological finds. The experience at the Archaeological Museum of Bologna

    Directory of Open Access Journals (Sweden)

    Anna Maria Manferdini

    2011-12-01

    Full Text Available This contribution presents a series of investigations undertaken thanks to the collaboration between the Department of Architecture and Territorial Planning of the University of Bologna and the Archaeological Museum of Bologna , aimed at finding a procedure for the 3d digital survey and exploration of archaeological finds. In particular, this paper shows how users can benefit from the use of digital technologies for the fruition of historical-artistic heritage. As a matter of fact, digital communication tools stimulate multisensory perception mechanisms and therefore allow to actively involve users in the exploration of contents presented through collections. Immersive visualizations, augmented reality and both tactile and visual exploration of findings can ease the establishment of a more immediate and direct communication channel with users that generally communicate and access information using digital technologies and mediums.

  6. North European Symposium for Archaeological Textiles X

    DEFF Research Database (Denmark)

    Proceedings of the Tenth North European Symposium for Archaeological Textiles, held in Copenhagen, 14-17 May 2008......Proceedings of the Tenth North European Symposium for Archaeological Textiles, held in Copenhagen, 14-17 May 2008...

  7. Qatar Islamic Archaeology and Heritage Project

    DEFF Research Database (Denmark)

    Report on the archaeological fieldwork at Al Zubarah and environs for the Qatar Museums Authority......Report on the archaeological fieldwork at Al Zubarah and environs for the Qatar Museums Authority...

  8. A Simple Assignment that Enhances Students' Ability to Solve Organic Chemistry Synthesis Problems and Understand Mechanisms

    Science.gov (United States)

    Teixeira, Jennifer; Holman, R. W.

    2008-01-01

    Organic chemistry students typically struggle with the retrosynthetic approach to solving synthesis problems because most textbooks present the chemistry grouped by "reactions of the functional group". In contrast, the retrosynthetic approach requires the student to envision "reactions that yield the functional group". A second challenge is the…

  9. Six Impossible Mechanisms before Breakfast: Arrow Pushing as an Instructional Device in Inorganic Chemistry

    Science.gov (United States)

    Berg, Steffen; Ghosh, Abhik

    2013-01-01

    In a recent article by the authors, the suggestion was made that arrow pushing, a widely used tool in organic chemistry, could also be profitably employed in the teaching of introductory inorganic chemistry. A number of relatively simple reactions were used to illustrate this thesis, raising the question whether the same approach might rationalize…

  10. Methodology of Parameterization of Molecular Mechanics Force Field From Quantum Chemistry Calculations using Genetic Algorithm: A case study of methanol

    CERN Document Server

    Li, Ying; Chan, Maria K Y; Sankaranarayanan, Subramanian; Rouxb, Benoît

    2016-01-01

    In molecular dynamics (MD) simulation, force field determines the capability of an individual model in capturing physical and chemistry properties. The method for generating proper parameters of the force field form is the key component for computational research in chemistry, biochemistry, and condensed-phase physics. Our study showed that the feasibility to predict experimental condensed phase properties (i.e., density and heat of vaporization) of methanol through problem specific force field from only quantum chemistry information. To acquire the satisfying parameter sets of the force field, the genetic algorithm (GA) is the main optimization method. For electrostatic potential energy, we optimized both the electrostatic parameters of methanol using the GA method, which leads to low deviations of between the quantum mechanics (QM) calculations and the GA optimized parameters. We optimized the van der Waals (vdW) parameters both using GA and guided GA methods by calibrating interaction energy of various met...

  11. Teaching the Philosophical Interpretations of Quantum Mechanics and Quantum Chemistry Through Controversies

    Science.gov (United States)

    Garritz, Andoni

    2013-07-01

    This study has the key premise of teaching history and philosophy of physical sciences to illustrate how controversies and rivalries among scientists play a key role in the progress of science and why scientific development is not only founded on the accumulation of experimental data. The author is a defender of teachers who consider philosophical, historical and socio-scientific issues. In particular, the disputes can be used in science teaching to promote students awareness of the "historicity" of science and to facilitate the understanding of scientific progress beyond that of inductive generalizations. The establishment of a theory is accompanied with philosophical interpretations all the way. The author will try to show that it gives excellent results in teaching and learning to bring to the foreground the complexity that surrounds the development of ideas in science, illustrating how controversies, presuppositions, contradictions and inconsistencies find a place in the work of scientists and philosophers alike. In this sense, the case of quantum mechanics and quantum chemistry is very solid because it is historically full of controversies among their heads: Einstein, Bohr, De Broglie, Heisenberg, Schrödinger, Born, Lewis, Langmuir, Bader, Hoffmann and Pauling, at least.

  12. Archaeology as a social science.

    Science.gov (United States)

    Smith, Michael E; Feinman, Gary M; Drennan, Robert D; Earle, Timothy; Morris, Ian

    2012-05-15

    Because of advances in methods and theory, archaeology now addresses issues central to debates in the social sciences in a far more sophisticated manner than ever before. Coupled with methodological innovations, multiscalar archaeological studies around the world have produced a wealth of new data that provide a unique perspective on long-term changes in human societies, as they document variation in human behavior and institutions before the modern era. We illustrate these points with three examples: changes in human settlements, the roles of markets and states in deep history, and changes in standards of living. Alternative pathways toward complexity suggest how common processes may operate under contrasting ecologies, populations, and economic integration.

  13. Archaeology and global information systems

    Directory of Open Access Journals (Sweden)

    Ian Hodder

    1999-03-01

    Full Text Available In this paper I wish to reinforce the view that there is a potential in the use of the Internet by archaeology for an important change in the organisation and institutionalisation of archaeological knowledge. As many have argued, this change involves a shift from hierarchy to networks and flows. But there are dangers that the Internet will simply translate old forms of elite knowledge into new forms, increasingly excluding the un-networked. Care needs to be taken to provide different modes of access for different groups and to find ways round the exclusive tendencies associated with the dispersal of any new technology.

  14. Extracting physical chemistry from mechanics: a new approach to investigate DNA interactions with drugs and proteins in single molecule experiments

    CERN Document Server

    Rocha, M S

    2015-01-01

    In this review we focus on the idea of establishing connections between the mechanical properties of DNAligand complexes and the physical chemistry of DNA-ligand interactions. This type of connection is interesting because it opens the possibility of performing a robust characterization of such interactions by using only one experimental technique: single molecule stretching. Furthermore, it also opens new possibilities in comparing results obtained by very different approaches, in special when comparing single molecule techniques to ensemble-averaging techniques. We start the manuscript reviewing important concepts of the DNA mechanics, from the basic mechanical properties to the Worm-Like Chain model. Next we review the basic concepts of the physical chemistry of DNA-ligand interactions, revisiting the most important models used to analyze the binding data and discussing their binding isotherms. Then, we discuss the basic features of the single molecule techniques most used to stretch the DNA-ligand complex...

  15. On the use of SPM to probe the interplay between polymer surface chemistry and polymer surface mechanics

    Science.gov (United States)

    Brogly, Maurice; Noel, Olivier; Awada, Houssein; Castelein, Gilles

    2007-03-01

    Adhesive properties of a polymer surface results from the complex contribution of surface chemistry and activation of sliding and dissipating mechanisms within the polymer surface layer. The purpose of this study is to dissociate the different contributions (chemical and mechanical) included in an AFM force-distance curve in order to establish relationships between the surface viscoelastic properties of the polymer, the surface chemistry of functionalized polymer surfaces and the adhesive forces, as determined by C-AFM experiments. Indeed we are interested in the measurements of local attractive or adhesive forces in AFM contact mode, of controlled chemical and mechanical model substrates. In order to investigate the interplay between mechanical or viscoelastic mechanisms and surface chemistry during the tip - polymer contact, we achieved force measurements on model PDMS polymer networks, whose surfaces are chemically controlled with the same functional groups as before (silicon substrates). On the basis of AFM nano-indentation experiments, surface Young moduli have been determined. The results show that the viscoelastic contribution is dominating in the adhesion force measurement. We propose an original model, which express the local adhesion force to the energy dissipated within the contact and the surface properties of the material (thermodynamic work of adhesion). Moreover we show that the dissipation function is related to Mc, the mass between crosslinks of the network.

  16. How stress and temperature conditions affect rock-fluid chemistry and mechanical deformation

    Science.gov (United States)

    Nermoen, Anders; Korsnes, Reidar; Aursjø, Olav; Madland, Merete; Kjørslevik, Trygve Alexander; Østensen, Geir

    2016-02-01

    We report the results from a series of chalk flow-through-compaction experiments performed at three effective stresses (0.5 MPa, 3.5 MPa and 12.3 MPa) and two temperatures (92° and and 130°). The results show that both stress and temperature are important to both chemical alteration and mechanical deformation. The experiments were conducted on cores drilled from the same block of outcrop chalks from the Obourg quarry within the Saint Vast formation (Mons, Belgium). The pore pressure was kept at 0.7 MPa for all experiments with a continuous flow of 0.219 M MgCl2 brine at a constant flow rate; 1 original pore volume (PV) per day. The experiments have been performed in tri-axial cells with independent control of the external stress (hydraulic pressure in the confining oil), pore pressure, temperature, and the injected flow rate. Each experiment consists of two phases; a loading phase where stress-strain dependencies are investigated (approx. 2 days), and a creep phase that lasts for more than 150-160 days. During creep, the axial deformation was logged, and the effluent samples were collected for ion chromatography analyses. Any difference between the injected and produced water chemistry gives insight into the rock-fluid interactions that occur during flow through of the core. The observed effluent concentration shows a reduction in Mg2+, while the Ca2+ concentration is increased. This, together with SEM-EDS analysis, indicates that magnesium-bearing mineral phases are precipitated leading to dissolution of calcite, an observation . This is in-line with other flow-through experiments reported earlier. The observed dissolution and precipitation are sensitive to the effective stress and test temperature. Typically. H, higher stress and temperature lead to increased concentration differences of Mg2+ and Ca2+ concentration changes.. The observed strain can be partitioned additively into a mechanical and chemical driven component.

  17. How stress and temperature conditions affect rock-fluid chemistry and mechanical deformation

    Directory of Open Access Journals (Sweden)

    Anders eNermoen

    2016-02-01

    Full Text Available We report the results from a series of chalk flow-through-compaction experiments performed at three effective stresses (0.5 MPa, 3.5 MPa and 12.3 MPa and two temperatures (92℃ and and 130℃. The results show that both stress and temperature are important to both chemical alteration and mechanical deformation. The experiments were conducted on cores drilled from the same block of outcrop chalks from the Obourg quarry within the Saint Vast formation (Mons, Belgium. The pore pressure was kept at 0.7 MPa for all experiments with a continuous flow of 0.219 M MgCl2 brine at a constant flow rate; 1 original pore volume (PV per day. The experiments have been performed in tri-axial cells with independent control of the external stress (hydraulic pressure in the confining oil, pore pressure, temperature, and the injected flow rate. Each experiment consists of two phases; a loading phase where stress-strain dependencies are investigated (approx. 2 days, and a creep phase that lasts for more than 150-160 days. During creep, the axial deformation was logged, and the effluent samples were collected for ion chromatography analyses. Any difference between the injected and produced water chemistry gives insight into the rock-fluid interactions that occur during flow through of the core. The observed effluent concentration shows a reduction in Mg2+, while the Ca2+ concentration is increased. This, together with SEM-EDS analysis, indicates that magnesium-bearing mineral phases are precipitated leading to dissolution of calcite, an observation . This is in-line with other flow-through experiments reported earlier. The observed dissolution and precipitation are sensitive to the effective stress and test temperature. Typically. H, higher stress and temperature lead to increased concentration differences of Mg2+ and Ca2+ concentration changes.. The observed strain can be partitioned additively into a mechanical and chemical driven component.

  18. The Times of Archaeology and Archaeologies of Time

    Directory of Open Access Journals (Sweden)

    Andrew Gardner

    2001-11-01

    Full Text Available The subject matter of archaeology as a discipline is explicitly structured by time, and ‘timetravel’ is a common feature of popular discourses about the study of the past. Yet archaeology is also the discipline which, amongst its other theoretical shortcomings, has singularly failed to develop any theory 'of 'time. Chronology is ever-present as a measuring tool, but only in rare cases has there been any consideration of this as but one, culturally-specific kind of temporality among many others experienced by people in their daily lives. In this paper, I will discuss various perspectives on archaeological times, including more sophisticated approaches developed since the later 1980s, and argue for an abandoning of the dualism between ‘measured’ and ‘experienced’ times which has emerged in some of these more critical attempts to grapple with the issue. Time is fundamental to archaeology, but not just because we ‘use’ dates. Rather, archaeologists should be able to contribute to wider discussions of time from their understandings of the materialized temporalities of past human agents, and to develop perspectives on the importance of these to the very nature of human social agency as a form of engagement with the world.

  19. Archaeology Excavation Simulation: Correcting the Emphasis

    Science.gov (United States)

    Thistle, Paul C.

    2012-01-01

    Museums offering archaeological programs often attempt to use the "sandbox approach" to simulate archaeological excavation work. However, in light of the definition of simulation, and given the realities of actual professional practice in archaeological excavation, the author argues that the activity of troweling for artifacts in loose sand places…

  20. Plasma Discharges in Gas Bubbles in Liquid Water: Breakdown Mechanisms and Resultant Chemistry

    Science.gov (United States)

    Gucker, Sarah M. N.

    is created either through flowing gas around the high voltage electrode in the discharge tube or self-generated by the plasma as in the steam discharge. This second method allows for large scale processing of contaminated water and for bulk chemical and optical analysis. Breakdown mechanisms of attached and unattached gas bubbles in liquid water were investigated using the first device. The breakdown scaling relation between breakdown voltage, pressure and dimensions of the discharge was studied. A Paschen-like voltage dependence for air bubbles in liquid water was discovered. The results of high-speed photography suggest the physical charging of the bubble due to a high voltage pulse; this charging can be significant enough to produce rapid kinetic motion of the bubble about the electrode region as the applied electric field changes over a voltage pulse. Physical deformation of the bubble is observed. This charging can also prevent breakdown from occurring, necessitating higher applied voltages to overcome the phenomenon. This dissertation also examines the resulting chemistry from plasma interacting with the bubble-liquid system. Through the use of optical emission spectroscopy, plasma parameters such as electron density, gas temperature, and molecular species production and intensity are found to have a time-dependence over the ac voltage cycle. This dependence is also source gas type dependent. These dependencies afford effective control over plasma-driven decomposition. The effect of plasma-produced radicals on various wastewater simulants is studied. Various organic dyes, halogenated compounds, and algae water are decomposed and assessed. Toxicology studies with melanoma cells exposed to plasma-treated dye solutions are completed, demonstrating the non-cytotoxic quality of the decomposition process. Thirdly, this dissertation examines the steam plasma system, developed through this research to circumvent the acidification associated with gas-feed discharges

  1. Art and Chemistry

    OpenAIRE

    Walter, Philippe

    2015-01-01

    Philippe Walter’s teaching, which he delivered as holder of the Liliane Bettencourt Annual Chair of Technological Innovation, was completed with two lectures on “practical work” to deal with a real case. The conditions and challenges of interdisciplinary research combining analytical chemistry, art history and archaeology were thus discussed in relation to specific works. The Holy Family, Constantin Abraham (1785-1855) by Raphaël (aka), Sanzio Raffaello (1483-1520), hard porcelain, Sèvres, C...

  2. Electron spin interactions in chemistry and biology fundamentals, methods, reactions mechanisms, magnetic phenomena, structure investigation

    CERN Document Server

    Likhtenshtein, Gertz

    2016-01-01

    This book presents the versatile and pivotal role of electron spin interactions in nature. It provides the background, methodologies and tools for basic areas related to spin interactions, such as spin chemistry and biology, electron transfer, light energy conversion, photochemistry, radical reactions, magneto-chemistry and magneto-biology. The book also includes an overview of designing advanced magnetic materials, optical and spintronic devices and photo catalysts. This monograph appeals to scientists and graduate students working in the areas related to spin interactions physics, biophysics, chemistry and chemical engineering.

  3. Physics and archaeology

    CERN Document Server

    Aitken, M J

    1995-01-01

    After a general survey of the way in which physics,and indeed chemistry, has opened new vistas archeology these lectures will focus on age determination.Here physics has played a crucial role in providing a timescale prior to recorded history , the latter beginnig about 5000 years ago with the First Dynasty of Egypt and the earliest pyramid. The physics-based timescale was initially provided by radiocarbon dating and this showed the early phases of Neolithic civilisation, e.g.,the earliest Jericho, to have been substiantially more ancient than had been conjectured. Further back in time than the 50000-year limit of that technique other radioisotope methods have been used, as well as electron spin resonance and luminescence; these have been espacially important in dating early human development, notably in throwing light on the relationship of anatomically-modern humans of the Neanderthals. In particular luminescence dating (both thermoluminescence and optically-stimulated luminescence) will be discussed, not o...

  4. Review: Role of Chemistry, Mechanics, and Transport on Well Integrity in CO2 Storage Environments

    Energy Technology Data Exchange (ETDEWEB)

    Carroll, Susan A.; Carey, William J.; Dzombak, David; Huerta, Nicolas J.; Li, Li; Richard, Tom; Um, Wooyong; Walsh, Stuart D.; ZHANG, LIWEI

    2016-01-11

    Among the various risks associated with CO2 storage in deep geologic formations, wells are important potential pathways for fluid leaks and groundwater contamination. Injection of CO2 will perturb the storage reservoir and any wells that penetrate the CO2 or pressure footprints are potential pathways for leakage of CO2 and/or reservoir brine. Well leakage is of particular concern for regions with a long history of oil and gas exploration because they are top candidates for geologic CO2 storage sites. This review explores in detail the ability of wells to retain their integrity against leakage with careful examination of the coupled physical and chemical processes involved. Understanding time-dependent leakage is complicated by the changes in fluid flow, solute transport, chemical reactions, and mechanical stresses over decade or longer time frames for site operations and monitoring. Almost all studies of the potential for well leakage have been laboratory based, as there are limited data on field-scale leakage. When leakage occurs by diffusion only, laboratory experiments show that while CO2 and CO2-saturated brine react with cement and casing, the rate of degradation is transport-limited and alteration of cement and casing properties is low. When a leakage path is already present due to cement shrinkage or fracturing, gaps along interfaces (e.g. casing/cement or cement/rock), or casing failures, chemical and mechanical alteration have the potential to decrease or increase leakage risks. Laboratory experiments and numerical simulations have shown that mineral precipitation or closure of strain-induced fractures can seal a leak pathway over time or conversely open pathways depending on flow-rate, chemistry, and the stress state. Experiments with steel/cement and cement/rock interfaces have indicated that protective mechanisms such as metal passivation, chemical alteration, mechanical deformation, and pore clogging can also help mitigate leakage. The specific rate

  5. Archaeology for the Seventh Generation

    Science.gov (United States)

    Gonzalez, Sara L.; Modzelewski, Darren; Panich, Lee M.; Schneider, Tsim D.

    2006-01-01

    This article describes the 2004 summer field program, the Kashaya Pomo Interpretive Trail Project (KPITP), which is an extension of the Fort Ross Archaeological Project (FRAP). Both are collaborative projects involving UC Berkeley, the California Department of Parks and Recreation, and the Kashaya Pomo tribe. The project attempts to integrate the…

  6. The Archaeology of Old Nuulliit

    DEFF Research Database (Denmark)

    Sørensen, Mikkel

    ¬aeo-Eskimo culture groups in Alaska. Knuth never published his findings in detail, which be¬came a mystery in Arctic archaeology circles. New investigations by the author of the material shows that the site was settled repeatedly by the first immigrants between 2500 BC and 1900 BC, and in addition that a total...

  7. Oscar Montelius and Chinese Archaeology

    Directory of Open Access Journals (Sweden)

    Xingcan Chen

    2014-05-01

    Full Text Available This paper demonstrates that Oscar Montelius (1843–1921, the world-famous Swedish archaeologist, had a key role in the development of modern scientific Chinese archaeology and the discovery of China’s prehistory. We know that one of his major works, Die Methode, the first volume of his Älteren kulturperioden im Orient und in Europa, translated into Chinese in the 1930s, had considerable influence on generations of Chinese archaeologists and art historians. What has previously remained unknown, is that Montelius personally promoted the research undertaken in China by Johan Gunnar Andersson (1874–1960, whose discoveries of Neolithic cultures in the 1920s constituted the breakthrough and starting point for the development of prehistoric archaeology in China. In this paper, we reproduce, translate and discuss a long forgotten memorandum written by Montelius in 1920 in support of Andersson’s research. In this Montelius indicated his belief in the potential of prehistoric Chinese archaeology as well as his predictions regarding the discoveries about to be made. It is therefore an important document for the study of the history of Chinese archaeology as a whole.

  8. Why History of Archaeology Matters?

    Directory of Open Access Journals (Sweden)

    Staša Babić

    2016-03-01

    Full Text Available Over the last decades, in the framework of the wider critical reassessments of archaeological theory and practice, especially in the English-speaking literature, a number of writings have been published, pointing to the origins and theoretical background in which some of the basic concepts of the discipline were developed. The very essence of archaeology has thus been situated into the cultural, political and ideological context of Western Europe at the end of the 18th and beginning of the 19th century. On the other hand, by the end of the 19th century this strategy of study into the past has become a part of the academic life in other contexts (such as Serbia, where the general circumstances were utterly different. However, the basic concepts were transferred from their original setting, inevitably undergone transformations, and then applied with long-lasting consequences. Therefore, the importance of the study of the history of archaeology in various local settings surpasses local concerns, but contributes to deeper understanding of the social role and importance of archaeological research in general.

  9. A manufactured past: virtual reality in archaeology

    Directory of Open Access Journals (Sweden)

    Glyn Goodrick

    2004-01-01

    Full Text Available Virtual reality and visualisation technologies developed over the past thirty years have been readily accessible to the archaeological community since the mid 1990s. Despite the high profile of virtual archaeology (Reilly 1991 both within the media and professional archaeology it has not been taken on board as a generally useful and standard technique by archaeologists. In this article we wish to discuss the technical and other issues which have resulted in a reluctance to adopt virtual archaeology and, more importantly, discuss ways forward that can enable us routinely to benefit from this technology in the diversity of archaeological practice.

  10. Art, auto-mechanics, and supramolecular chemistry. A merging of hobbies and career

    OpenAIRE

    Eric V. Anslyn

    2016-01-01

    While the strict definition of supramolecular chemistry is “chemistry beyond the molecule”, meaning having a focus on non-covalent interactions, the field is primarily associated with the creation of synthetic receptors and self-assembly. For synthetic ease, the receptors and assemblies routinely possess a high degree of symmetry, which lends them an aspect of aesthetic beauty. Pictures of electron orbitals similarly can be seen as akin to works of art. This similarity was an early draw for m...

  11. The Novel ''Controlled Intermediate Nuclear Fusion'' and its Possible Industrial Realization as Predicted by Hadronic Mechanics and Chemistry

    CERN Document Server

    Santilli, R M

    2006-01-01

    In this note, we propose, apparently for the first time, a new type of controlled nuclear fusion called "intermediate" because occurring at energies intermediate between those of the ''cold'' and ''hot'' fusions, and propose a specific industrial realization. For this purpose: 1) We show that known limitations of quantum mechanics, quantum chemistry and special relativity cause excessive departures from the conditions occurring for all controlled fusions; 2) We outline the covering hadronic mechanics, hadronic chemistry and isorelativity specifically conceived, constructed and verified during the past two decades for new cleans energies and fuels; 3) We identify seven physical laws predicted by the latter disciplines that have to be verified by all controlled nuclear fusions to occur; 4) We review the industrial research conducted to date in the selection of the most promising engineering realization as well as optimization of said seven laws; and 5) We propose with construction details a specific {\\it hadron...

  12. Theoretical chemistry periodicities in chemistry and biology

    CERN Document Server

    Eyring, Henry

    1978-01-01

    Theoretical Chemistry: Periodicities in Chemistry and Biology, Volume 4 covers the aspects of theoretical chemistry. The book discusses the stably rotating patterns of reaction and diffusion; the chemistry of inorganic systems exhibiting nonmonotonic behavior; and population cycles. The text also describes the mathematical modeling of excitable media in neurobiology and chemistry; oscillating enzyme reactions; and oscillatory properties and excitability of the heart cell membrane. Selected topics from the theory of physico-chemical instabilities are also encompassed. Chemists, mechanical engin

  13. Computerized Archaeology – 3D Tools for Investigating Archaeological Artifacts

    International Nuclear Information System (INIS)

    The computerized revolution poses challenges and creates new opportunities in archaeological research. The Computerized Archaeology Laboratory at the Hebrew University integrates techniques and ideas from computer science (e.g., computer graphics, machine learning) in the archaeological research methodologies. We operate optical scanners which provide the three dimensional (3D) digital models that are then analyzed with the computer programs developed in our laboratory. These programs address research issues and needs which could not be addressed without the availability of digital 3D models. Beyond ‘capturing’ and visualizing data, I will focus on the process of analysis and provide novel ways of interpretation. For example, recently we developed new ways for determining the degree of similarity between flakes from various Middle Paleolithic lithic assemblages in the Southern Levant. Preliminary results are promising since the methodology applied distinguished between assemblages not using the traditional techno-typological criteria. This may provide a novel method for clustering and separation of prehistoric assemblages, new means to check the validity of the traditional classification. (author)

  14. Plasma Discharges in Gas Bubbles in Liquid Water: Breakdown Mechanisms and Resultant Chemistry

    Science.gov (United States)

    Gucker, Sarah M. N.

    is created either through flowing gas around the high voltage electrode in the discharge tube or self-generated by the plasma as in the steam discharge. This second method allows for large scale processing of contaminated water and for bulk chemical and optical analysis. Breakdown mechanisms of attached and unattached gas bubbles in liquid water were investigated using the first device. The breakdown scaling relation between breakdown voltage, pressure and dimensions of the discharge was studied. A Paschen-like voltage dependence for air bubbles in liquid water was discovered. The results of high-speed photography suggest the physical charging of the bubble due to a high voltage pulse; this charging can be significant enough to produce rapid kinetic motion of the bubble about the electrode region as the applied electric field changes over a voltage pulse. Physical deformation of the bubble is observed. This charging can also prevent breakdown from occurring, necessitating higher applied voltages to overcome the phenomenon. This dissertation also examines the resulting chemistry from plasma interacting with the bubble-liquid system. Through the use of optical emission spectroscopy, plasma parameters such as electron density, gas temperature, and molecular species production and intensity are found to have a time-dependence over the ac voltage cycle. This dependence is also source gas type dependent. These dependencies afford effective control over plasma-driven decomposition. The effect of plasma-produced radicals on various wastewater simulants is studied. Various organic dyes, halogenated compounds, and algae water are decomposed and assessed. Toxicology studies with melanoma cells exposed to plasma-treated dye solutions are completed, demonstrating the non-cytotoxic quality of the decomposition process. Thirdly, this dissertation examines the steam plasma system, developed through this research to circumvent the acidification associated with gas-feed discharges

  15. Nigeria’s Archaeological Heritage

    Directory of Open Access Journals (Sweden)

    Emeka E. Okonkwo

    2016-06-01

    Full Text Available People have exploited mineral resources for several reasons ranging from the production of metal and ceramic objects to stone and wooden tools. Indigenous extraction and use of mineral resources for production of general goods among others have continued unabated. In this article, archaeological and ethnographic data were used to identify extraction methods for some of these raw materials in the past, and thus, examine how failure to manage such resources has adversely affected technological and resource development in Nigeria

  16. Modern analytic methods applied to the art and archaeology

    International Nuclear Information System (INIS)

    The interaction of diverse areas as the analytic chemistry, the history of the art and the archaeology has allowed the development of a variety of techniques used in archaeology, in conservation and restoration. These methods have been used to date objects, to determine the origin of the old materials and to reconstruct their use and to identify the degradation processes that affect the integrity of the art works. The objective of this chapter is to offer a general vision on the researches that have been realized in the Instituto Nacional de Investigaciones Nucleares (ININ) in the field of cultural goods. A series of researches carried out in collaboration with national investigators and of the foreigner is described shortly, as well as with the great support of degree students and master in archaeology of the National School of Anthropology and History, since one of the goals that have is to diffuse the knowledge of the existence of these techniques among the young archaeologists, so that they have a wider vision of what they could use in an in mediate future and they can check hypothesis with scientific methods. (Author)

  17. LANDSCAPE ARCHAEOLOGY ALONG LIMES TRANSALUTANUS

    Directory of Open Access Journals (Sweden)

    Eugen S. Teodor

    2014-09-01

    Full Text Available The project addresses the historical monuments comprised in the longest Roman ‘linear defence’ structure present on the Romanian territory.Despite it being the longest, this historic structure is the least protected and the least known in its technical details. Was indeed Limes Transalutanus an incomplete limes (lacking civilian settlements, for example, an odd construction (a vallum without fossa, an early-alarm line rather than a proper defensive line? Taking on these historical and archaeological challenges, the team attempts to develop an investigation technology applicable to large scale archaeological landscapes - a full evaluation chain, involving aerial survey, surface survey, geophysical investigation, multispectral images analysis, statistic evaluation and archaeological diggings. This technological chain will be systematically applied on the whole length of the objective, that is, on a 155 km distance. The attempt to find answers to issues related to the earth works’ functionality, layout, structure, chronology and relation with adjacent sites will be grounded on exploring the relations of the monument with the surrounding environment, by focussing on finding methods to reconstruct the features of the ancient landscapes, like systematic drilling, palynological tests and toponymical studies.

  18. A Writing and Ethics Component for a Quantum Mechanics, Physical Chemistry Course

    Science.gov (United States)

    Reilly, John T.; Strickland, Michael

    2010-01-01

    A writing-across-the-curriculum and ethics component is presented for a second-semester, physical chemistry course. The activity involves introducing ethical issues pertinent to scientists. Students are asked to read additional material, participate in discussions, and write essays and a paper on an ethical issue. The writing and discussion…

  19. Analytical chemistry

    International Nuclear Information System (INIS)

    This book is comprised of nineteen chapters, which describes introduction of analytical chemistry, experimental error and statistics, chemistry equilibrium and solubility, gravimetric analysis with mechanism of precipitation, range and calculation of the result, volume analysis on general principle, sedimentation method on types and titration curve, acid base balance, acid base titration curve, complex and firing reaction, introduction of chemical electro analysis, acid-base titration curve, electrode and potentiometry, electrolysis and conductometry, voltammetry and polarographic spectrophotometry, atomic spectrometry, solvent extraction, chromatograph and experiments.

  20. Understanding Archaeological Authority in a Digital Context

    Directory of Open Access Journals (Sweden)

    Lorna-Jane Richardson

    2014-12-01

    Full Text Available "…with the increasing spread of social media and mobile communication, the social networks of knowledge construction are becoming not only vastly bigger and quicker and less limited by space and time constraints than they have been before, but also more of a threat to established authorities." (Hofheinz 2011, 1426 This article considers the issues of archaeological authority, expertise and organisational reputation in the UK from an online perspective, and questions whether the participatory promise of social media technologies can, and should, challenge archaeological authority. It explores how these issues are approached and mediated online, the issues of digital literacy for audience reception, and the approaches used by archaeological organisations to address the challenges of undertaking digital public archaeology projects whilst maintaining archaeological rigour and the visible performance of expertise. It discusses how the concepts of archaeological authority and expertise are demonstrated and practised online, using data from my doctoral research, undertaken from 2011 to 2013. This article questions if the presence of websites dedicated to the promulgation of alternative archaeologies on the Internet can present challenges for the performance of archaeological expertise online, and how organisations monitor and respond to alternative archaeological interpretations and news stories.

  1. New insights into the fouling mechanism of dissolved organic matter applying nanofiltration membranes with a variety of surface chemistries.

    Science.gov (United States)

    Mustafa, Ghulam; Wyns, Kenny; Buekenhoudt, Anita; Meynen, Vera

    2016-04-15

    Nanofiltration (NF) membrane fouling by DOM remains a major and poorly understood issue. To acquire a better insight we studied the fouling of the DOM fractions humic acids (HAs) and fulvic acids (FAs), with and without Ca(2+), on native and grafted ceramic NF membranes. Grafting with two methods and three different grafting groups allowed to create a range of membranes with a variety of surface chemistries, and a wide range of surface polarity, much broader than ever used in previous studies. A typical polymer (polyamide) NF membrane was included for comparison. All obtained results reveal that membrane fouling is not determined by membrane hydrophilicity/hydrophobicity as a general and sole criterion, but rather on the whole of the surface chemistry determining the amount and strength of the possible foulant-membrane interactions. As a consequence the effect of inorganic ions on the fouling is also dependent on the surface chemistry. Important new insight in the DOM fouling mechanism was acquired, shedding new light on the state-of-the-art knowledge. PMID:26905798

  2. Chemistry and Mechanism of Alizarin Red S and Methylene Blue Biosorption onto Olive Stone: Equilibrium and Kinetic

    OpenAIRE

    Albadarin, Ahmad B.; Mangwandi, Chirangano

    2015-01-01

    The biosorption process of anionic dye Alizarin Red S (ARS) and cationic dye methylene blue (MB) as a function of solution pH, initial concentration and contact time onto olive stone (OS) biomass has been investigated. The main objectives of the current study are to: (i) study the chemistry and the mechanism of ARS and MB biosorption onto olive stone and the type of OS–ARS, MB interactions occurring, (ii) study the biosorption equilibrium and kinetic experimental data required for the design ...

  3. Investigation of causes of differences in student performance on the topics of stereochemistry and reaction mechanisms in an undergraduate organic chemistry course

    Science.gov (United States)

    Krylova, Irina

    Students have a great deal of difficulty in understanding the concepts of chemistry, including organic chemistry. which results in high failure and repeat rates. The purpose of this study was to determine possible reasons for student failure in an undergraduate organic chemistry course. In particular, the study dealt with student difficulties in two concepts of undergraduate organic chemistry--stereochemistry and reaction mechanisms. Such possible reasons for student failure. as lack of logical or spatial abilities, lack of knowledge of general chemistry, lack of studying efforts and misconceptions, were under investigation. The study involved a combination of both a quantitative approach--statistical analysis of student performance, and a qualitative approach--analysis of student think-aloud interviews. A group of students at the Catholic University of America (22 students), Prince George's Community College (23 students) and Montgomery Community College (13 students) enrolled in an undergraduate organic chemistry course were participants in the study. Catholic University and community college students were treated as two separate groups. At the beginning of the study, student logical and spatial abilities, and knowledge of general chemistry were ascertained. After each of the stereochemistry and reaction mechanisms concepts were taught, students were given two separate achievement tests on these concepts. Statistical correlation between independent variables (logical and spatial abilities, knowledge of general chemistry, and studying efforts) and dependent variables (achievement in stereochemistry and reaction mechanisms) was investigated using regression analysis. A group of students was interviewed to ascertain their knowledge of the organic chemistry concepts, ways of reasoning and misconceptions. The results of the study showed that knowledge of general chemistry is the most important variable in both Catholic University and community college student

  4. Microstructural, compositional and mechanical properties of the archaeological indigenous ceramics of Caninhas, Sao Paulo,Brazil; Analise microestrutural, composicional e propriedades mecanicas das ceramicas indigenas do sitio arqueologico Caninhas, Sao Paulo, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Nakano, F.P.; Taguchi, S.P., E-mail: japaum@alunos.eel.usp.b [Universidade de Sao Paulo (DEMAR/EEL/USP), Lorena, SP (Brazil). Escola de Engenharia de Lorena. Dept. de Engenharia de Materiais; Ribeiro, R.B.; Rosa, S.J.L. [Faculdades Integradas Teresa D' Avila (FATEA), Lorena, SP (Brazil). Rede Salesianas. Dept. de Desenho Industrial; Bornal, W.G.; Queiroz, C.M. [Fundacao Cultural de Jacarehy, Jacarei, SP (Brazil). Nucleo de Arqueologia do Vale do Paraiba

    2009-07-01

    Archaeological ceramics contain infinity of data about social and cultural indigenous site Caninhas/SP. The ceramics present a gradient of color (ochre to dark gray), when from the surface to the center of the piece, indicating compositional variability caused by inefficient sintering carried out by indigenous peoples. It was analyzed the composition phases by X-rays diffraction (XRD) and mapping by EDS, identifying the illite, quartz and lutecite phases (ochre region) and illite, quartz, hydrated alumina and lutecite phases (dark gray region). The results of EDS confirmed the stages identified by X-rays diffraction and suggesting the presence of roots and scrap of ceramics sintered in the composition of indigenous ceramics, when compared by optical microscope and scanning electron microscope. Vickers hardness identified as fragile and heterogeneous are archaeological ceramics, reaching approximately 203 HV in the grains of silica and 16 HV in the ceramic matrix. (author)

  5. Analysis of archaeological pieces with nuclear techniques

    International Nuclear Information System (INIS)

    In this work nuclear techniques such as Neutron Activation Analysis, PIXE, X-ray fluorescence analysis, Metallography, Uranium series, Rutherford Backscattering for using in analysis of archaeological specimens and materials are described. Also some published works and thesis about analysis of different Mexican and Meso american archaeological sites are referred. (Author)

  6. Maritime Archaeology and Climate Change: An Invitation

    Science.gov (United States)

    Wright, Jeneva

    2016-08-01

    Maritime archaeology has a tremendous capacity to engage with climate change science. The field is uniquely positioned to support climate change research and the understanding of past human adaptations to climate change. Maritime archaeological data can inform on environmental shifts and submerged sites can serve as an important avenue for public outreach by mobilizing public interest and action towards understanding the impacts of climate change. Despite these opportunities, maritime archaeologists have not fully developed a role within climate change science and policy. Moreover, submerged site vulnerabilities stemming from climate change impacts are not yet well understood. This article discusses potential climate change threats to maritime archaeological resources, the challenges confronting cultural resource managers, and the contributions maritime archaeology can offer to climate change science. Maritime archaeology's ability to both support and benefit from climate change science argues its relevant and valuable place in the global climate change dialogue, but also reveals the necessity for our heightened engagement.

  7. The application of lithic raw material mechanical analysis in Paleolithic archaeology%石料力学性能分析在旧石器考古学研究中的应用

    Institute of Scientific and Technical Information of China (English)

    周振宇; 郇勇; 刘薇; 董杰

    2016-01-01

    nucleation of cracks that can be reflected on strain vs.stress curves.To investigate the mechanical properties of raw material,compression tests were performed using a MTS 810 material testing machine.Specimen cubes were cut out of pebbles from Paleolithic site for the tests.Force is measured by the load cell,and the deformation of the specimen is measured by a COD displacement sensor fixed between two compression plates.This deformation vs.force relationship was then transformed to a strain vs.stress curve.Six kinds of raw material,dolomite,chert,obsidian,quartz,quartzite,and granite,were involved in the compression test.In Shuidonggou site,dolomite shows higher ductility and brittleness than quartz and quartzite.This result implies that dolomite appears better flaking properties than quartz and quartzite in Shuidonggou.Archaeology remains The quartz from Beitaishanmiao site,Hubei and Xujiacheng site,Gansu present the similar lithology mechanical properties,which might be taken as one explanation for that both two sites shows similar raw material utilization and lithic assemblage.In the chert (Daerwo site,Guanyindong site,Guizhou) and obsidian (Japan) specimens we examined,since of the microfissure,both the dispersion of maximum stress and maximum strain is bigger than dolomite,quartz,sand quartzite,and granite.This suggests that,in some case,the macro-crystal rock maybe appears better flaking properties than microcrystal rock,such as chert,flint,and obsidian.In this study,mechanical properties analysis has been proved quite objective method for raw material utilization analysis.We suggest that knapping experiment should be correlated with mechanical tests.Moreover,more mechanical tests with different raw materials from different sites are necessary for the comparative examination and also significant for building a raw material mechanical properties database.

  8. Understanding fossil phytolith preservation: the role of partial dissolution in paleoecology and archaeology.

    Science.gov (United States)

    Cabanes, Dan; Shahack-Gross, Ruth

    2015-01-01

    Opaline phytoliths are important microfossils used for paleoecological and archaeological reconstructions that are primarily based on relative ratios of specific morphotypes. Recent studies have shown that phytolith assemblages are prone to post-depositional alteration involving partial dissolution, however, the manner in which partial dissolution affects morphotype composition is poorly understood. Here we show that morphotype assemblages from four different plant species subjected to controlled partial dissolution are significantly different from the original assemblages, indicating that the stability of various morphotypes differs, mainly depending on their surface area to bulk ratios. This underlying mechanism produces distorted morphotype compositions in partially dissolved phytolith assemblages, bearing vast implications for morphotype-based paleoecological and archaeological interpretation. Together with analyses of phytolith assemblages from a variety of archaeological sites, our results establish criteria by which well-preserved phytolith assemblages can be selected for accurate paleoecological and archaeological reconstructions.

  9. Snapshots of lignin oxidation and depolymerization in archaeological wood: an EGA-MS study.

    Science.gov (United States)

    Tamburini, Diego; Łucejko, Jeannette Jacqueline; Ribechini, Erika; Colombini, Maria Perla

    2015-10-01

    Evolved gas analysis-mass spectrometry (EGA-MS) was used for the first time to study archaeological wood, in order to investigate its chemical degradation. The archaeological wood was from an oak pile from a stilt house found in the Neolithic 'La Marmotta' village (Lake Bracciano, Rome, Italy). The sampling was performed from the external to the internal part of the pile, following the annual growth rings in groups of five. In addition, sound oak wood and isolated wood components (holocellulose and cellulose) were also analyzed, and the results were used to highlight differences because of degradation. Our study demonstrated that EGA-MS provides information on the thermo-chemistry of archaeological wood along with in-depth compositional data thanks to the use of MS. Our investigations not only highlighted wood degradation in terms of differences between carbohydrates and lignin content, but also showed that lignin oxidation and depolymerization took place in the archaeological wood. Mass spectral data revealed differences among the archaeological samples from the internal to the external part of the pile. An increase in the formation of wood pyrolysis products bearing a carbonyl group at the benzylic position and a decrease in the amount of lignin dimers were observed. These were related to oxidation and depolymerization reactions, respectively. PMID:26456777

  10. Two-electron reduction of ethylene carbonate: a quantum chemistry re-examination of mechanisms

    CERN Document Server

    Leung, Kevin

    2013-01-01

    Passivating solid-electrolyte interphase (SEI) films arising from electrolyte decomposition on low-voltage lithium ion battery anode surfaces are critical for battery operations. We review the recent theoretical literature on electrolyte decomposition and emphasize the modeling work on two-electron reduction of ethylene carbonate (EC, a key battery organic solvent). One of the two-electron pathways, which releases CO gas, is re-examined using simple quantum chemistry calculations. Excess electrons are shown to preferentially attack EC in the order (broken EC^-) > (intact EC^-) > EC. This confirms the viability of two electron processes and emphasizes that they need to be considered when interpreting SEI experiments. An estimate of the crossover between one- and two-electron regimes under a homogeneous reaction zone approximation is proposed.

  11. Investigation of silicate surface chemistry and reaction mechanisms associated with mass transport in geologic media

    International Nuclear Information System (INIS)

    The concentration and rate of transport of radionuclides through geologic media can be strongly influenced by the extent of sorption on aquifer surfaces. Over time intervals relevant to such transport processes, rock and mineral surfaces cannot be considered as inert, unreactive substrates but rather as groundwater/solidphase interfaces which are commonly in a state of natural or artificially induced disequilibrium. The goal of the present research is to define experimentally the type of water/rock interactions that will influence surface chemistry and hence sorption characteristics and capacities of natural aquifers. As wide a range of silicate minerals as possible was selected for study to represent rock-forming minerals in basalt, tuff, and granite. The minerals include K-feldspar, plagioclase feldspar, olivine, hornblende, biotite, and volcanic glass

  12. Reaction Mechanisms for the Limited Reversibility of Li-O2 Chemistry in Organic Carbonate Electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Wu; Xu, Kang; Viswanathan, Vilayanur V.; Towne, Silas A.; Hardy, John S.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Wang, Deyu; Zhang, Jiguang

    2011-11-15

    The Li-O2 chemistry in nonaqueous carbonate electrolytes and the underneath reason of its limited reversibility was exhaustively investigated. The discharge products collected from the air cathode in a Li-O2 battery at different depth of discharge (DOD) were systematically analyzed with X-ray diffraction. It is revealed that, independent of the discharge depth, lithium alkylcarbonate (either lithium propylenedicarbonate - LPDC, or lithium ethylenedicarbonate - LEDC, with other related derivatives) and lithium carbonate (Li2CO3) are always the main products, obviously originated from the electrolyte solvents propylene carbonate (PC) and ethylene carbonate (EC). These lithium alkylcarbonates are obviously generated from the single-electron reductive decomposition of the corresponding carbonate solvents initiated by the attack of superoxide radical anions. On the other hand, neither lithium peroxide (Li2O2) nor lithium oxide (Li2O) is detected. More significantly, from in situ gas chromatography/mass spectroscopy it is found that Li2CO3 and Li2O cannot be oxidized even when charged up to 4.6 V vs. Li/Li+, while LPDC, LEDC and Li2O2 are readily able to, with CO2 and CO released with the re-oxidation of LPDC and LEDC. It is therefore concluded that the quasi-reversibility of Li-O2 chemistry observed hitherto in an organic carbonate-based electrolyte is actually reliant on the formation of lithium alkylcarbonates through the reductive decomposition of carbonate solvents during discharge process and the subsequent oxidation of these same alkylcarbonates during charge process. It is the poor oxidizability of these alkylcarbonate species that constitutes the obstruction to an ideal rechargeable Li-O2 battery.

  13. Grid for Meso american Archaeology

    Energy Technology Data Exchange (ETDEWEB)

    Lucet, G.

    2007-07-01

    Meso american archaeology works with large amounts of disperse and diverse information, thus the importance of including new methods that optimise the acquisition, conservation, retrieval, and analysis of data to generate knowledge more efficiently and create a better understanding of history. Further, this information --which includes texts, coordinates, raster graphs, and vector graphs-- comes from a considerable geographical area --parts of Mexico, Nicaragua, Honduras and Costa Rica as well as Guatemala, El Salvador and Belize-- is constantly expanding. This information includes elements like shards, buildings, mural paintings, high and low reliefs, topography, maps, and information about the fauna and soil. Grid computing offers a solution to handle all this information: it respects researchers' need for independence while supplying a platform to share, process and compare the data obtained. Additionally, the Grid can enhance space-time analyses with remote visualisation techniques that can, in turn, incorporate geographical information systems and virtual reality. (Author)

  14. Critical Reflections on Digital Public Archaeology

    Directory of Open Access Journals (Sweden)

    Chiara Bonacchi

    2015-12-01

    Full Text Available This article presents critiques and analyses of recent work in digital public archaeology (DPA in the United Kingdom. It first locates different strands of DPA within the wider field of public archaeology, and begins to map out the diverse forms, aims and sources of DPA. Next it critically examines the models of 'communication' that are present in DPA, suggesting that greater attention should be paid to audiences in particular, and monitoring and evaluation in general. Finally the article considers the democratising effects of digital media on archaeological knowledge economies, highlighting some current and potential future areas of interest.

  15. LIDAR, Point Clouds, and their Archaeological Applications

    Energy Technology Data Exchange (ETDEWEB)

    White, Devin A [ORNL

    2013-01-01

    It is common in contemporary archaeological literature, in papers at archaeological conferences, and in grant proposals to see heritage professionals use the term LIDAR to refer to high spatial resolution digital elevation models and the technology used to produce them. The goal of this chapter is to break that association and introduce archaeologists to the world of point clouds, in which LIDAR is only one member of a larger family of techniques to obtain, visualize, and analyze three-dimensional measurements of archaeological features. After describing how point clouds are constructed, there is a brief discussion on the currently available software and analytical techniques designed to make sense of them.

  16. Magnetometry and archaeological prospection in Mexico

    Science.gov (United States)

    Barba Pingarron, L.; Laboratorio de Prospeccion Arqueologica

    2013-05-01

    Luis Barba Laboratorio de Prospección Arqueológica Instituto de Investigaciones Antropológicas Universidad Nacional Autonoma de México The first magnetic survey in archaeological prospection was published in 1958 in the first number of Archaeometry, in Oxford. That article marked the beginning of this applications to archaeology. After that, magnetic field measurements have become one of the most important and popular prospection tools. Its most outstanding characteristic is the speed of survey that allows to cover large areas in short time. As a consequence, it is usually the first approach to study a buried archaeological site. The first attempts in Mexico were carried out in 196. Castillo and Urrutia, among other geophysical techniques, used a magnetometer to study the northern part of the main plaza, zocalo, in Mexico City to locate some stone Aztec sculptures. About the same time Morrison et al. in La Venta pyramid used a magnetometer to measure total magnetic field trying to find a substructure. Some years later Brainer and Coe made a magnetic survey to locate large stone Olmec heads in San Lorenzo Tenochtitlan, Veracruz. Technology development has provided everyday more portable and accurate instruments to measure the magnetic field. The first total magnetic field proton magnetometers were followed by differential magnetometers and more recently gradiometers. Presently, multiple sensor magnetometers are widely used in European archaeology. The trend has been to remove the environmental and modern interference and to make more sensitive the instruments to the superficial anomalies related to most of the archaeological sites. There is a close relationship between the geology of the region and the way magnetometry works in archaeological sites. Archaeological prospection in Europe usually needs very sensitive instruments to detect slight magnetic contrast of ditches in old sediments. In contrast, volcanic conditions in Mexico produce large magnetic contrast

  17. Free Radical Chemistry of Disinfection Byproducts. 3. Degradation Mechanisms of Chloronitromethane, Bromonitromethane and Dichloronitromethane

    Energy Technology Data Exchange (ETDEWEB)

    Bruce J. Mincher; Stephen P. Mezyk; William J. Cooper; S. Kirkham Cole; Robert V. Fox; Piero R. Gardinali

    2010-01-01

    Halonitromethanes (HNMs) are byproducts formed through ozonation and chlorine/ chloramine disinfection processes in drinking waters that contain dissolved organic matter and bromide ions. These species occur at low concentration, but have been determined to have high cytotoxicity and mutagenicity and therefore may represent a human health hazard. In this study, we have investigated the chemistry involved in the mineralization of HNMs to non-hazardous inorganic products through the application of advanced oxidation and reduction processes. We have combined measured absolute reaction rate constants for the reactions of chloronitromethane, bromonitromethane and dichloronitromethane with the hydroxyl radical and the hydrated electron with a kinetic computer model in an attempt to elucidate the reaction pathways of these HNMs. The results are compared to measurements of stable products resulting from steady-state 60Co y-irradiations of the same compounds. The model predicted the decomposition of the parent compounds and ingrowth of chloride and bromide ions with excellent accuracy, but the prediction of the total nitrate ion concentration was slightly in error, reflecting the complexity of nitrogen oxide species reactions in irradiated solution.

  18. High-energy chemistry of formamide: a unified mechanism of nucleobase formation.

    Science.gov (United States)

    Ferus, Martin; Nesvorný, David; Šponer, Jiří; Kubelík, Petr; Michalčíková, Regina; Shestivská, Violetta; Šponer, Judit E; Civiš, Svatopluk

    2015-01-20

    The coincidence of the Late Heavy Bombardment (LHB) period and the emergence of terrestrial life about 4 billion years ago suggest that extraterrestrial impacts could contribute to the synthesis of the building blocks of the first life-giving molecules. We simulated the high-energy synthesis of nucleobases from formamide during the impact of an extraterrestrial body. A high-power laser has been used to induce the dielectric breakdown of the plasma produced by the impact. The results demonstrate that the initial dissociation of the formamide molecule could produce a large amount of highly reactive CN and NH radicals, which could further react with formamide to produce adenine, guanine, cytosine, and uracil. Based on GC-MS, high-resolution FTIR spectroscopic results, as well as theoretical calculations, we present a comprehensive mechanistic model, which accounts for all steps taking place in the studied impact chemistry. Our findings thus demonstrate that extraterrestrial impacts, which were one order of magnitude more abundant during the LHB period than before and after, could not only destroy the existing ancient life forms, but could also contribute to the creation of biogenic molecules. PMID:25489115

  19. The chemistry of simple alkene molecules on Si(100)c(4 × 2): The mechanism of cycloaddition and their selectivities

    Science.gov (United States)

    Akagi, Kazuto; Yoshinobu, Jun

    2016-10-01

    The chemistry of simple alkene molecules on the Si(100) surface is reviewed with the newly-produced visual presentation by theoretical calculations. The early pioneering studies by the Kyoto Group and Pittsburgh group reported the di-σ bond formation and the precursor-mediated chemisorption for acetylene and ethylene on Si(100), respectively. Thereafter, these studies have been stimulating various studies of organic molecules on Si surfaces. Our recent studies have observed the precursor states for alkene chemisorption and elucidated the microscopic mechanisms of the di-σ bond formation (cycloaddition) with the help of theoretical calculations; the site-, stereo- and regio-selective chemisorption of simple alkene molecules on Si(100)c(4 × 2) has been established.

  20. The ceramic artifacts in archaeological black earth (terra preta) from Lower Amazon Region, Brazil: chemistry and geochemical evolution Artefatos cerâmicos em sítios arqueológicos com terra preta na região do baixo Amazonas, Brasil: composição química e evolução geoquímica

    OpenAIRE

    Marcondes Lima da Costa; Dirse Clara Kern; Alice Helena Eleotério Pinto; Jorge Raimundo da Trindade Souza

    2004-01-01

    This paper carried out a chemical investigation of archaeological ceramic artifacts found in archaeological sites with Black Earth (ABE) in the Lower Amazon Region at Cachoeira-Porteira, State of Pará, Brazil. The ceramic artifacts, mostly of daily use, belong to Konduri culture (from 900 to 400 years BP). They are constituted of SiO2, Al2O3, Fe2O3, Na2O and P2O5; SiO2 and Al2O3 together add up to 80 % and indicate influence of acid rocks, transformed into clay minerals basically kaolinite. T...

  1. Objects or Narratives. Archaeological Exhibitions in Serbia: Foundations of Museum Archaeology

    OpenAIRE

    Tatjana Cvjetićanin

    2016-01-01

    Although every local museum or parts of national museums keep archaeological finds, museums in general play a very limited role on the archaeological scene, often being passive and marginalized. Well-grounded investigation into the archaeological objects kept in museum collections and, above all, the public domain of museums, the nature of collections and exhibitions, both permanent and occasional, have not been adequately recognized, discussed or considered. In spite of the fact that museum ...

  2. The e-Depot for Dutch Archaeology. Archiving and publication of archaeological data

    OpenAIRE

    Hollander, H.S.

    2014-01-01

    In the Netherlands, the archiving and publication of archaeological research data has led to the establishment of the e-Depot for Dutch Archaeology (EDNA) accommodated at DANS. EDNA is a collaboration between DANS and the Cultural Heritage Agency (RCE). DANS is an institute of the Royal Netherlands Academy of Arts and Sciences (KNAW) and the Netherlands Organisation for Scientific Research (NWO). The slogan "Digital archaeology requires a digital memory" was used in 2007 to bring care for dig...

  3. Advancing Theory? Landscape Archaeology and Geographical Information Systems

    Directory of Open Access Journals (Sweden)

    Di Hu

    2012-05-01

    Full Text Available This paper will focus on how Geographical Information Systems (GIS have been applied in Landscape Archaeology from the late 1980s to the present. GIS, a tool for organising and analysing spatial information, has exploded in popularity, but we still lack a systematic overview of how it has contributed to archaeological theory, specifically Landscape Archaeology. This paper will examine whether and how GIS has advanced archaeological theory through a historical review of its application in archaeology.

  4. Chemistry and anticarcinogenic mechanisms of glycoalkaloids produced by eggplants, potatoes, and tomatoes.

    Science.gov (United States)

    Friedman, Mendel

    2015-04-01

    Inhibition of cancer can occur via apoptosis, a genetically directed process of cell self-destruction that involves numerous biomarkers and signaling pathways. Glycoalkaloids are nitrogen-containing secondary plant metabolites found in numerous Solanaceous plants including eggplants, potatoes, and tomatoes. Exposure of cancer cells to glycoalkaloids produced by eggplants (α-solamargine and α-solasonine), potatoes (α-chaconine and α-solanine), and tomatoes (α-tomatine) or their hydrolysis products (mono-, di-, and trisaccharide derivatives and the aglycones solasodine, solanidine, and tomatidine) inhibits the growth of the cells in culture (in vitro) as well as tumor growth in vivo. This overview comprehensively surveys and consolidates worldwide efforts to define the following aspects of these natural compounds: (a) their prevalence in the three foods; (b) their chemistry and structure-activity relationships; (c) the reported factors (biomarkers, signaling pathways) associated with apoptosis of bone, breast, cervical, colon, gastric, glioblastoma, leukemia, liver, lung, lymphoma, melanoma, pancreas, prostate, and squamous cell carcinoma cell lines in vitro and the in vivo inhibition of tumor formation and growth in fish and mice and in human skin cancers; and (d) future research needs. The described results may make it possible to better relate the structures of the active compounds to their health-promoting function, individually, in combination, and in food, and allow the consumer to select glycoalkaloid-containing food with the optimal content of nontoxic beneficial compounds. The described findings are expected to be a valuable record and resource for further investigation of the health benefits of food-related natural compounds.

  5. Maritime archaeology and shipwrecks off Goa

    Digital Repository Service at National Institute of Oceanography (India)

    Tripati, S.; Gaur, A.S.; Sundaresh

    . It is hoped that this book will be an invaluable guide for students; teachers and scholars of Archaeology, History and allied disciplines besides general public. The book is well illustrated and comprehensively presented to be of use to everybody interested...

  6. Application of Spaceborne Remote Sensing to Archaeology

    Science.gov (United States)

    Crippen, Robert E.

    1997-01-01

    Spaceborne remote sensing data have been underutilized in archaeology for a variety of seasons that are slowly but surely being overcome. Difficulties have included cost/availability of data, inadequate resolution, and data processing issues.

  7. Evaluating Mechanisms of Dihydroxylation by Thin-Layer Chromatography: A Microscale Experiment for Organic Chemistry

    Science.gov (United States)

    Burlingham, Benjamin T.; Rettig, Joseph C.

    2008-01-01

    A microscale experiment is presented in which cyclohexene is dihydroxylated under three sets of conditions: epoxidation-hydrolysis, permanganate oxidation, and the Woodward dihydroxylation. The products of the reactions are determined by the use of thin-layer chromatography. Teams of students are presented with proposed mechanisms for each…

  8. The Chemistry of Cold: Mechanisms of Torpor Regulation in the Siberian Hamster.

    Science.gov (United States)

    Cubuk, Ceyda; Bank, Jonathan H H; Herwig, Annika

    2016-01-01

    Siberian hamsters use spontaneous daily torpor, a state of hypometabolism and hypothermia, to save energy during winter. Multiple neuroendocrine signals set the scene for spontaneous torpor to occur, and several brain areas have been identified as potential sites for torpor regulation. Here, we summarize the known mechanisms of a fascinating physiological state in the Siberian hamster.

  9. Palaeolithic research at the Institute of Archaeology

    OpenAIRE

    Andrew Garrard; Norah Moloney; Dietrich Stout; Ignacio de la Torre

    2005-01-01

    Since its foundation in 1937, the Institute of Archaeology has been an important centre of research on Pleistocene environments and Palaeolithic archaeology. Frederick Zeuner (loA: 1937-1963) was greatly respected for his teaching and research on the subject, including his 1945 publication The Pleistocene period and John Waechter (loA: 1954-1978) for his Palaeolithic excavations at Gorham's Cave in Gibraltar and Swanscombe in the Thames Valley. Mark Newcomer (loA: 1973-1989) inspired many of...

  10. Archaeologically Sustainable Development in an Urban Context

    OpenAIRE

    Barrett, John C

    2013-01-01

    Archaeological deposits pose a financial risk for developers resulting from the planning constraints that are imposed by the premise that a public interest exists in those deposits and in the consequent impact that any development might have upon them. In England and Wales, those planning constraints arise from the principles now established by the National Planning Policy Framework. Here archaeological deposits are identified as being among the heritage assets that go to make up the heritage...

  11. The study of archaeology in Malta

    OpenAIRE

    Bonanno, Anthony

    1996-01-01

    The University of Malta has made a late entry in the field of archaeology. The first graduate courses started only in 1987. One recalls with satisfaction, however, that Professor Temi Zammit, the distinguished Maltese archaeologist, was Rector of the Royal University of Malta between 1920 and 1926, and that for a short period, in the years 1938-1939, John Ward Perkins, then at the beginning of his brilliant and influential career, was appointed Professor of Archaeology...

  12. Developing technologies for the management of the Archaeological Heritage: towards a model of Evaluation of the Archaeological Impact

    OpenAIRE

    Barreiro Martínez, David; Villoch Vázquez, Victoria; Criado Boado, Felipe

    1999-01-01

    This paper proposes to establish criteria and procedures of archaeological practice to solve the problems and demands posed by the Management of the Archaeological Heritage. Our Research Unit is developing the CLAAR Programme, to define criteria and conventions for Landscape Archaeology and Archaeological Heritage. The main aim of this programme is to contribute to the development of systems and methodologies to manage and evaluate the Archaeological Heritage. In a practica...

  13. ADAPTATION OF N-HEPTANE AUTOIGNITION TABULATION FOR COMPLEX CHEMISTRY MECHANISMS

    Directory of Open Access Journals (Sweden)

    Neven Duić

    2011-01-01

    Full Text Available The adaptation of auto-ignition tabulation for effective use of complex chemical mechanisms will be presented in this paper. Taking cool flame ignition phenomenon into account could improve numerical simulations of combustion in compression ignition engines. Current approaches of successful simulation of this phenomenon are based on the extraction of ignition delay times, heat releases and also reaction rates from tabulated data dependant on four parameters: temperature, pressure, equivalence ratio and exhaust gasses mass fraction. The methods described here were used to create lookup tables including cool flame using a comprehensive chemical mechanism without including reaction rates data (as used by other authors. The method proved to be stable for creating tables and these results will be shown, as well as initial implementation results using the tables in computational fluid dynamics software.

  14. Comprehensive Mechanisms for Combustion Chemistry: An Experimental and Numerical Study with Emphasis on Applied Sensitivity Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Dryer, Frederick L.

    2009-04-10

    This project was an integrated experimental/numerical effort to study pyrolysis and oxidation reactions and mechanisms for small-molecule hydrocarbon structures under conditions representative of combustion environments. The experimental aspects of the work were conducted in large-diameter flow reactors, at 0.3 to 18 atm pressure, 500 to 1100 K temperature, and 10-2 to 2 seconds reaction time. Experiments were also conducted to determine reference laminar flame speeds using a premixed laminar stagnation flame experiment and particle image velocimetry, as well as pressurized bomb experiments. Flow reactor data for oxidation experiments include: (1)adiabatic/isothermal species time-histories of a reaction under fixed initial pressure, temperature, and composition; to determine the species present after a fixed reaction time, initial pressure; (2)species distributions with varying initial reaction temperature; (3)perturbations of a well-defined reaction systems (e.g. CO/H2/O2 or H2/O2)by the addition of small amounts of an additive species. Radical scavenging techniques are applied to determine unimolecular decomposition rates from pyrolysis experiments. Laminar flame speed measurements are determined as a function of equivalence ratio, dilution, and unburned gas temperature at 1 atm pressure. Hierarchical, comprehensive mechanistic construction methods were applied to develop detailed kinetic mechanisms which describe the measurements and literature kinetic data. Modeling using well-defined and validated mechanisms for the CO/H2/Oxidant systems and perturbations of oxidation experiments by small amounts of additives were also used to derive absolute reaction rates and to investigate the compatibility of published elementary kinetic and thermochemical information. Numerical tools were developed and applied to assess the importance of individual elementary reactions to the predictive performance of the

  15. Effect of direct quenching on the microstructure and mechanical properties of the lean-chemistry HSLA-100 steel plates

    International Nuclear Information System (INIS)

    Highlights: → Direct-quenched and tempered (DQT) steels gives better mechanical properties. → Fine Cu and Nb (C, N) precipitates enhance matrix strengthening and tempering resistance. → Boron promotes hardenability, but low temperature Charpy impact toughness gets affected. → Mechanical properties equivalent to HSLA-100 steel is achieved by directly quenched leaner chemistry alloys. - Abstract: The influence of direct quenching on structure-property behavior of lean chemistry HSLA-100 steels was studied. Two laboratory heats, one containing Cu and Nb (C:0.052, Mn:0.99, Cu:1.08, Nb:0.043, Cr:0.57, Ni:1.76, Mo:0.55 pct) and the other containing Cu, Nb and B (C:0.04, Mn:1.02, Cu:1.06, Nb:0.036, Cr:0.87, Ni:1.32, Mo:0.41, B:0.002 percent) were hot-rolled into 25 and 12.5 mm thick plates by varying finish-rolling temperatures. The plates were heat-treated by conventional reheat quenching and tempering (RQT), as well as by direct quenching and tempering (DQT) techniques. In general, direct-quench and tempered plates of Nb-Cu heat exhibited good strength (yield strength ∼ 900 MPa) and low-temperature impact toughness (average: 74 J at -85 deg. C); the Charpy V-notch impact energies were marginally lower than conventional HSLA-100 steel. In Nb-Cu-B heat, impact toughness at low-temperature was inferior owing to boron segregation at grain boundaries. Transmission electron microscopy (TEM) and scanning auger microprobe (SAM) analysis confirmed existence of borocarbides at grain boundaries in this steel. In general, for both the steels, the mechanical properties of the direct-quench and tempered plates were found to be superior to reheat quench and tempered plates. A detailed transmission electron microscopy study revealed presence of fine Cu and Nb (C, N) precipitates in these steels. It was also observed that smaller martensite inter-lath spacing, finer grains and precipitates in direct-quench and tempered plates compared to the reheat quench and tempered plates

  16. Effect of direct quenching on the microstructure and mechanical properties of the lean-chemistry HSLA-100 steel plates

    Energy Technology Data Exchange (ETDEWEB)

    Dhua, S.K., E-mail: skdhua@yahoo.com [R and D Centre for Iron and Steel, Steel Authority of India Limited, Doranda, Ranchi 834002 (India); Sen, S.K., E-mail: sksen@sail-rdcis.com [R and D Centre for Iron and Steel, Steel Authority of India Limited, Doranda, Ranchi 834002 (India)

    2011-08-15

    Highlights: {yields} Direct-quenched and tempered (DQT) steels gives better mechanical properties. {yields} Fine Cu and Nb (C, N) precipitates enhance matrix strengthening and tempering resistance. {yields} Boron promotes hardenability, but low temperature Charpy impact toughness gets affected. {yields} Mechanical properties equivalent to HSLA-100 steel is achieved by directly quenched leaner chemistry alloys. - Abstract: The influence of direct quenching on structure-property behavior of lean chemistry HSLA-100 steels was studied. Two laboratory heats, one containing Cu and Nb (C:0.052, Mn:0.99, Cu:1.08, Nb:0.043, Cr:0.57, Ni:1.76, Mo:0.55 pct) and the other containing Cu, Nb and B (C:0.04, Mn:1.02, Cu:1.06, Nb:0.036, Cr:0.87, Ni:1.32, Mo:0.41, B:0.002 percent) were hot-rolled into 25 and 12.5 mm thick plates by varying finish-rolling temperatures. The plates were heat-treated by conventional reheat quenching and tempering (RQT), as well as by direct quenching and tempering (DQT) techniques. In general, direct-quench and tempered plates of Nb-Cu heat exhibited good strength (yield strength {approx} 900 MPa) and low-temperature impact toughness (average: 74 J at -85 deg. C); the Charpy V-notch impact energies were marginally lower than conventional HSLA-100 steel. In Nb-Cu-B heat, impact toughness at low-temperature was inferior owing to boron segregation at grain boundaries. Transmission electron microscopy (TEM) and scanning auger microprobe (SAM) analysis confirmed existence of borocarbides at grain boundaries in this steel. In general, for both the steels, the mechanical properties of the direct-quench and tempered plates were found to be superior to reheat quench and tempered plates. A detailed transmission electron microscopy study revealed presence of fine Cu and Nb (C, N) precipitates in these steels. It was also observed that smaller martensite inter-lath spacing, finer grains and precipitates in direct-quench and tempered plates compared to the reheat

  17. A Potential Mechanism for Perchlorate Formation on Mars: Surface-Radiolysis-Initiated Atmospheric Chemistry

    Science.gov (United States)

    Wilson, Eric; Atreya, Sushil K.; Kaiser, Ralf-Ingo; Mahaffy, Paul

    2016-10-01

    Perchlorate (ClO4–) is prevalent on Earth, and with observations of perchlorate on lunar samples and chondrite meteorites, along with recent observations indicating the presence of perchlorate (ClO4–) in the Martian surface by the Phoenix lander and the Sample Analysis at Mars (SAM) on the Mars Science Laboratory (MSL) rover, it appears that the existence of perchlorate is widespread throughout the solar system. However, the abundance and isotopic composition of Martian perchlorate suggest that the perchlorate formation mechanism on Mars may involve a different path than perchlorate found elsewhere in the solar system. Motivated by this, we employ a one-dimensional chemical model to investigate the viability of perchlorate formation in the atmosphere of Mars, instigated by the radiolysis of the Martian surface by galactic cosmic rays. The surface-atmosphere interaction to produce Martian perchlorate involves the sublimation of chlorine oxides into the atmosphere, through surface radiolysis, and their subsequent synthesis to form perchloric acid (HClO4), followed by surface deposition and mineralization to form surface perchlorates. Considering the chlorine oxide, OClO, we find an OClO surface flux as low as 3.2x107 molecules cm–2 s–1, sublimated into the atmosphere from the surface could produce sufficient HClO4 to explain the perchlorate concentration on Mars, assuming an accumulation depth of 30 cm and integrated over the Amazonian period. Radiolysis provides an efficient pathway for the oxidation of chlorine, bypassing the efficient Cl/HCl recycling mechanism that characterizes HClO4 formation mechanisms proposed for the Earth but not Mars.

  18. Development and application of a chemistry mechanism for mesoscale simulations of the troposphere and lower stratosphere

    Energy Technology Data Exchange (ETDEWEB)

    Lippert, E.; Hendricks, J.; Petry, H. [Cologne Univ. (Germany). Inst. for Geophysics and Meteorology

    1997-12-31

    A new chemical mechanism is applied for mesoscale simulations of the impact of aircraft exhausts on the atmospheric composition. The temporal and spatial variation of the tropopause height is associated with a change of the trace gas composition in these heights. Box and three dimensional mesoscale model studies show that the conversion of aircraft exhausts depends strongly on the cruise heights as well as on the location of release in relation to the tropopause. The impact of aircraft emissions on ozone is strongly dependent on the individual meteorological situation. A rising of the tropopause height within a few days results in a strong increase of ozone caused by aircraft emissions. (author) 12 refs.

  19. Uptake of Reactive Black 5 by pumice and walnut activated carbon: Chemistry and adsorption mechanisms

    OpenAIRE

    Heibati, B.; Rodriguez-Couto, S.; Amrane, A; M. Rafatullah; Hawari, A.; Al-Ghouti, M. A.

    2014-01-01

    The potential of using pumice and walnut wood activated carbon as low-cost adsorbents for the removal of the diazo dye Reactive Black 5 (RB5) from aqueous solutions was investigated. The Langmuir isotherm fit to the data specified the presence of two different natures of adsorption sites with different binding energies on the AC-W surface. Kinetic modelling showed that the adsorption behaviour and mechanism of RB5 for both adsorbents is believed to happen via surface adsorption followed by di...

  20. Ultrasonic and mechanical behavior of green and partially sintered alumina: Effects of slurry consolidation chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Schilling, C.H.; Garcia, V.J.; Smith, R.M. [Ames Lab., IA (United States)]|[Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering; Roberts, R.A. [Iowa State Univ., Ames, IA (United States)

    1998-10-01

    Green and partially sintered compacts of {alpha}-Al{sub 2}O{sub 3} powder were made by filtration of aqueous suspensions under three conditions: (i) electrostatic stabilization without any organic additive, (ii) strong flocculation near the isoelectric point without any organic additive, and (iii) weak flocculation by the use of maltodextrin or oxalic acid additives. The authors evaluated relationships between the macroscopic and interparticle mechanical behavior of these compacts using model correlations with measurements of diametral compression, ultrasonic velocity, and ultrasonic attenuation. Although type iii green specimens were less dense than type i, type iii exhibited significant increases in velocity, macroscopic Young`s modulus, interparticle-contact stiffness, and diametral compressive strength, suggesting that the mechanism of stiffening/strengthening entailed interparticle bridging of maltodextrin or oxalic acid. These properties were significantly reduced upon heating type iii specimens to 500 C, suggesting that pyrolysis of surface-adsorbed maltodextrin and oxalic acid may have reduced the interparticle stiffness and strength. In contrast, negligible changes in these properties occurred upon heating type i specimens to the same temperature. Despite small increases in packing density, significant decreases in attenuation and significant increases in velocity, interparticle-contact stiffness, and Young`s modulus occurred upon heating all specimens to {ge}700 C, suggesting the formation of interparticle necks by solid-state sintering.

  1. Alkali-activated fly ash. Relationship between mechanical strength gains and initial ash chemistry

    Directory of Open Access Journals (Sweden)

    Palomo, A.

    2008-09-01

    Full Text Available Alkali-activated fly ash is the primary component of a new generation of high-strength, durable binders with excellent mechanical properties and durability (on occasion bettering traditional Portland cement performance. Moreover, development of these cements may contribute to mitigating CO2 emissions, since the base material is an industrial by-product. The present study was conducted to determine the effect of the composition of the initial materials (SiO2/Al2O3 and Na2O/Al2O3 ratios on the mechanical properties, nature and composition of the reaction products. The results obtained indicate that there is no linear relationship between these ratios and mechanical strength, but rather a series of optimal values above and below which strength declines. In the specific case of the ratios studied in the present paper, these values were: SiO2/Al2O3= 4.0 and Na2O/Al2O3= 1.0 (molar ratios.Las cenizas volantes activadas alcalinamente constituyen la base de una nueva generación de cementos con muy interesantes propiedades mecánicas, adherentes y durables (a veces incluso mejores que las de los cementos Portland tradicionales. Adicionalmente el desarrollo de estos cementos podría contribuir a mitigar las emisiones de CO2 a la atmósfera, ya que el material base de los mismos puede estar formado por subproductos industriales. En la presente investigación se realizó un estudio para determinar la influencia de la composición de los materiales iniciales (ratios SiO2/Al2O3 y Na2O/Al2O3 en las propiedades mecánicas y en la naturaleza y composición de los productos de reacción. Los resultados obtenidos indican que no existe una relación lineal de dichas ratios con las resistencias mecánicas, sino que existen unos valores óptimos, por encima y debajo de los cuales las resistencias mecánicas disminuyen. En el caso concreto de las ratios estudiadas en el presente trabajo estos valores serian: SiO2/Al2O3= 4,0 y Na2O/Al2O3= 1,0 (relaciones molares

  2. Spectral methods in chemistry and physics applications to kinetic theory and quantum mechanics

    CERN Document Server

    Shizgal, Bernard

    2015-01-01

    This book is a pedagogical presentation of the application of spectral and pseudospectral methods to kinetic theory and quantum mechanics. There are additional applications to astrophysics, engineering, biology and many other fields. The main objective of this book is to provide the basic concepts to enable the use of spectral and pseudospectral methods to solve problems in diverse fields of interest and to a wide audience. While spectral methods are generally based on Fourier Series or Chebychev polynomials, non-classical polynomials and associated quadratures are used for many of the applications presented in the book. Fourier series methods are summarized with a discussion of the resolution of the Gibbs phenomenon. Classical and non-classical quadratures are used for the evaluation of integrals in reaction dynamics including nuclear fusion, radial integrals in density functional theory, in elastic scattering theory and other applications. The subject matter includes the calculation of transport coefficient...

  3. Mechanisms for Midlatitude Ozone Loss: Heterogeneous Chemistry in the Lowermost Stratosphere?

    Science.gov (United States)

    Smith, Jessica B.; Hintsa, Eric J.; Allen, Norton T.; Stimpfle, Richard M.; Anderson, James G.

    2001-01-01

    The question of midlatitude ozone erosion by chlorine free radical catalysis is examined. We present and analyze simultaneous, high-resolution observations of ClO, H2O, tropopause height, particle reactive surface area, and ice saturation occurrence frequency obtained from the NASA ER-2 aircraft. The objective is to test the hypothesis that the existence of cirrus clouds or cold aerosols in the first few kilometers above the tropopause at midlatitudes is responsible for increasing the ratio of chlorine free radicals to total inorganic chlorine, thus amplifying the rate of catalytic ozone destruction. The observations reveal a sharp decrease in ice saturation frequency at the tropopause, a marked degree of undersaturation just above the tropopause, a corresponding sharp gradient in the product of cold aerosol reactive surface area and reaction probability, gamma-S(sub a), and, finally, the consistent absence of enhanced concentrations of ClO immediately above the tropopause. These results suggest that midlatitude ozone loss is not controlled in situ by the mechanism of cirrus cloud and/or cold aerosol enhancement of chlorine radicals in the vicinity of the tropopause.

  4. Marx, Production, Society and Archaeology

    Directory of Open Access Journals (Sweden)

    Lull, Vicente

    2005-06-01

    Full Text Available Social life is produced. Social life takes place before the fact of thinking about it. Drawing upon elements coming from utopian Socialism. British economy and, especially, Hegel’s philosophy, Marx proposed a set of dialectic categories addressed to thinking and to explaining how social life is produced, including in these dynamics the production of ourselves. In this paper, the guidelines of Marx’ thoughts are shown starting from the reading and analysis of his own texts. Also, the pertinence of the relationship between Marx and the research of society is argued through the material objects which make any society real: the archaeological research.

    La vida social se produce. La vida social es anterior al hecho de pensarla. Basándose en elementos procedentes del socialismo utópico, la economía británica y, sobre todo, la filosofía de Hegel, Marx propuso categorías dialécticas para pensar y explicar cómo se produce la vida social, y nosotros en ella. En este artículo se exponen las líneas básicas del pensamiento de Marx a partir de una lectura y análisis de sus propios textos, y se argumenta la pertinencia de la relación entre dicho pensamiento y la investigación de la sociedad a partir de los objetos materiales que la hicieron posible: la investigación arqueológica.

  5. Making space for an archaeology of place

    Directory of Open Access Journals (Sweden)

    David Wheatley

    2004-01-01

    Full Text Available Rather than attempt to write a balanced or complete overview of the application of GIS to archaeology (which would inevitably end up being didactic and uncritical this article sets out to present a discursive and contentious position with the deliberate aim of stimulating further debate about the future role of GIS within our discipline. To this end, existing applications of GIS to archaeology are reviewed, concentrating on two areas of application, predictive modelling and visibility analyses, and on their wider disciplinary context. It is argued that GIS cannot be simplistically held to have been a 'good thing' or a 'bad thing' for archaeology, but rather that these different application areas may be analysed separately and found to have quite different qualities. Although they are in no sense alternatives to one another, the areas of predictive modelling and visibility analysis can be seen to represent quite different agendas for the development of an archaeology of space and/or place. The development of correlative predictive models is considered first, both from the perspective of explanation and of cultural resource management. The arguments against predictive modelling as a means of explanation are rehearsed and it is found to be over-generalising, deterministic and de-humanised. As a consequence, it is argued that predictive modelling is now essentially detached from contemporary theoretical archaeological concerns. Moreover, it is argued to be an area with significant unresolved methodological problems and, far more seriously, that it presents very real dangers for the future representativity of archaeological records. Second, the development of GIS-based visibility analysis is reviewed. This is also found to be methodologically problematic and incomplete. However, it is argued that visibility studies — in direct contrast to predictive modelling — have remained firmly situated within contemporary theoretical debates, notably about

  6. Archaeological Narratives and Other Ways of Telling.

    Science.gov (United States)

    Pluciennik

    1999-12-01

    With a few exceptions, archaeologists have been far less concerned with the form of their texts or problems of authorship than have ethnographers. Typically, archaeologies are presented in the form of narratives understood as sequential stories. Approaches to narrative analysis drawn from literary theory, philosophy, and sociology and definitions of characters, events, and plots are examined, together with particular problems these may pose for the discipline of archaeology. It is suggested that neither literary analysis nor the tendency to write and evaluate archaeological and historical narratives in terms of explanatory value takes sufficient account of the often hybrid nature and aims of these texts and the contexts in which they were produced. This argument is illustrated with particular reference to stories of the Mesolithic-Neolithic transition in Europe. It is argued that reconsidering archaeology's positioning across the 19th-century science-humanities divide suggests a broader approach to the idea of what constitutes a narrative which can offer fresh opportunities for useful reflexivity and experimentation in presentation. Further roles and possibilities of narrative and non-narrative ways of writing archaeologies are also considered. PMID:10539944

  7. Archaeological Evidence for Resilience of Pacific Northwest Salmon Populations and the Socioecological System over the last ~7,500 years

    OpenAIRE

    Sarah K. Campbell; Butler, Virginia L.

    2010-01-01

    Archaeological data on the long history of interaction between indigenous people and salmon have rarely been applied to conservation management. When joined with ethnohistoric records, archaeology provides an alternative conceptual view of the potential for sustainable harvests and can suggest possible social mechanisms for managing human behavior. Review of the ~7,500-year-long fish bone record from two subregions of the Pacific Northwest shows remarkable stability in salmon use. As maj...

  8. Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China

    Directory of Open Access Journals (Sweden)

    B. Zheng

    2014-06-01

    Full Text Available Severe regional haze pollution events occurred in eastern and central China in January 2013, which had adverse effects on the environment and public health. Extremely high levels of particulate matter with aerodynamic diameter of 2.5 μm or less (PM2.5 with dominant components of sulfate and nitrate are responsible for the haze pollution. Although heterogeneous chemistry is thought to play an important role in the production of sulfate and nitrate during haze episodes, few studies have comprehensively evaluated the effect of heterogeneous chemistry on haze formation in China by using the 3-D models due to of a lack of treatments for heterogeneous reactions in most climate and chemical transport models. In this work, the offline-coupled WRF-CMAQ model with newly added heterogeneous reactions is applied to East Asia to evaluate the impacts of heterogeneous chemistry and the meteorological anomaly during January 2013 on regional haze formation. The revised CMAQ with heterogeneous chemistry not only captures the magnitude and temporal variation of sulfate and nitrate, but also reproduces the enhancement of relative contribution of sulfate and nitrate to PM2.5 mass from clean days to polluted haze days. These results indicate the significant role of heterogeneous chemistry in regional haze formation and improve the understanding of the haze formation mechanisms during the January 2013 episode.

  9. 40 years of medieval archaeology at Aarhus University

    DEFF Research Database (Denmark)

    Roesdahl, Else

    2015-01-01

    The history of medieval archaeology as a university discipline in Denmark (at Aarhus University), 1971-2012......The history of medieval archaeology as a university discipline in Denmark (at Aarhus University), 1971-2012...

  10. “Neutron metallography” of archaeological bronzes

    Science.gov (United States)

    Siano, S.; Bartoli, L.; Kockelmann, W.; Zoppi, M.; Miccio, M.

    2004-07-01

    Following a first demonstration on the potentials of time-of-flight neutron diffraction in the microstructural characterisation of archaeological bronzes, we present here the results of a further systematic study on the topic. The experiments were performed on standardised specimens and original archaeological bronze findings at the powder diffractometer ROTAX. The possibility to achieve various metallographic data concerning alloy composition, homogeneity, dendritic structure, metal and mineral phases, as well as the effects of hardening, annealing, and re-crystallisation processes was successfully demonstrated. Furthermore, we also report a texture analysis on a Roman coin, which provided a clear striking fingerprint thus demonstrating a powerful authentication method.

  11. The Archaeology of Late Antique Sudan

    DEFF Research Database (Denmark)

    Dann, Rachael Jane

    , and despite the spectacular nature of the finds, the sites have received remarkably little scholarly attention. This book offers the first interpretation of social life at these key sites, and proposes a series of innovative, theoretically informed frames for exploring the significance of the material remains...... a series of archaeologically unique monumental tumuli and multi-chambered tomb structures containing evidence of human and animal sacrifice, as well as a highly sophisticated material culture. The interpretations presented here draw on the emergent field of sensory archaeology to address the key issue...... of material culture and the human relationship to the sensory nature of the sensory world....

  12. Pajarito Plateau archaeological surveys and excavations. II

    Energy Technology Data Exchange (ETDEWEB)

    Steen, C R

    1982-04-01

    Los Alamos National Laboratory continues its archaeological program of data gathering and salvage excavations. Sites recently added to the archaeological survey are described, as well as the results of five excavations. Among the more interesting and important discoveries are (1) the apparently well-established local use of anhydrous lime, and (2) a late pre-Columbian use of earlier house sites and middens for garden plots. Evidence indicated that the local puebloan population was the result of an expansion of upper Rio Grande peoples, not an influx of migrants.

  13. Teaching Experimental Archaeology at the University of Copenhagen

    DEFF Research Database (Denmark)

    Lyngstrøm, Henriette Syrach

    2011-01-01

    For more than ten years the Faculty of Humanities at the University of Copenhagen has offered the course Experimental Archaeology, Ethno-archaeology and Simple Technology to all students at BA level.......For more than ten years the Faculty of Humanities at the University of Copenhagen has offered the course Experimental Archaeology, Ethno-archaeology and Simple Technology to all students at BA level....

  14. Maturing Gracefully? Curriculum Standards for History and Archaeology.

    Science.gov (United States)

    Black, Mary S.

    2001-01-01

    Explores the similarities and differences between the disciplines of history and archaeology. Examines the standards and principles recently proposed for teaching history and archaeology to determine the areas of difference and commonality. Addresses the issues of historical and archaeological thinking describing each in detail. (CMK)

  15. Transformations of the Past: Teachers' Knowledge of North American Archaeology.

    Science.gov (United States)

    Black, Mary S.

    1999-01-01

    Argues that archaeology education should be included within the social studies curriculum and addresses various reasons why archaeology has been ignored within the classroom. Presents the findings from a survey that investigated preservice and experienced teachers' knowledge of archaeology. Concludes that there is a need for teacher preparation on…

  16. Archaeology for Dance: An Approach to Dance Education

    Science.gov (United States)

    Lopez y. Royo, Alessandra

    2002-01-01

    The paper proposes that existing methodologies for dance studies can be extended through consideration of recently developing methodologies from social archaeology. It is first argued that an archaeological perspective on dance is enriching for archaeology, whose recent interest in dance as a focus of investigation can be seen as an attempt to…

  17. Chemical Processing in a Polluted Forest Canopy: a Model Comparison of the Regional Atmospheric Chemistry Mechanism, Version 2 and SAPRC07

    Science.gov (United States)

    Goliff, W.; Stockwell, W. R.; Fuentes, J. D.

    2007-12-01

    In this study, we present a comparison of modeled chemical processing in polluted forest canopies using the Regional Atmospheric Chemistry Mechanism, Version 2 and SAPRC07. The comparison involves a number of field studies, one, for example, was conducted at a forested site near Oak Ridge, TN during the summer of 1999. The sites were under the influence of nitrogen oxide and hydrocarbon emissions from suburban automobile traffic. Air chemistry measurements (e.g., ozone, NOx and VOC) and meteorological measurements were collected within and above the forest canopies. A comparison of the degree of chemical processing by HO and NO3 radicals and O3 for biogenic compounds, and the amount of HOx formation between the two mechanisms is presented.

  18. Crowd-sourcing archaeological research: HeritageTogether digital public archaeology in practice

    Directory of Open Access Journals (Sweden)

    Seren Griffiths

    2015-12-01

    Full Text Available Archaeologists are increasingly working with crowd-sourced digital data. Using evidence from other disciplines about the nature of crowd-sourcing in academic research, we suggest that archaeological projects using donated data can usefully be differentiated between generative projects (which rely on data collected by citizen scientists, and analytical projects (which make use of volunteers to classify, or otherwise analyse data that are provided by the project. We conclude that projects which privilege hyper-local research (such as surveying specific sites might experience tension if the audience they are appealing to are 'cyber local'. In turn, for more 'traditional' archaeological audiences (when the primary motivating interests may be the tangible, physical nature of portable material culture or the archaeological site itself, then intangible, digital simulacra may not provide an effective medium through which to undertake digital public archaeology.

  19. PHOTOGRAMMETRIC TECHNIQUES FOR PROMOTION OF ARCHAEOLOGICAL HERITAGE: THE ARCHAEOLOGICAL MUSEUM OF PARMA (ITALY)

    OpenAIRE

    E. Dall’Asta; Bruno, N.; Bigliardi, G.; Zerbi, A.; R. Roncella

    2016-01-01

    In a context rich in history and cultural heritage, such as the Italian one, promotion and enhancement of historical evidences are crucial. The paper describes the case study of the Archaeological Museum of Parma, which, for the main part, conserves evidences found in the roman archaeological site of Veleia (Piacenza, Italy). To enhance the comprehension of the past, the project aims to promote the exhibits through new digital contents, in particular 3D models and AR applications, to improve ...

  20. Objects or Narratives. Archaeological Exhibitions in Serbia: Foundations of Museum Archaeology

    Directory of Open Access Journals (Sweden)

    Tatjana Cvjetićanin

    2016-02-01

    Full Text Available Although every local museum or parts of national museums keep archaeological finds, museums in general play a very limited role on the archaeological scene, often being passive and marginalized. Well-grounded investigation into the archaeological objects kept in museum collections and, above all, the public domain of museums, the nature of collections and exhibitions, both permanent and occasional, have not been adequately recognized, discussed or considered. In spite of the fact that museum exhibitions legitimize the dominant social and political norms of the present, museums remain marginalized, separated from the currents of various pertinent disciplines, and not prepared for the necessary changes. Archaeological theory, shaping the archaeological practice of museums as well, is not understood as its constituent part, and the interpretive context in which exhibitions are created, contents and nature of interpretation are not considered. The analysis of the exhibitions of the National Museum in Belgrade, being the paradigm of museum archaeology in Serbia up to the middle of the 20th century, has shown that the culture-historical approach, the idea of continuity and dynamic artistic presentations of alienated past have marked this public presence of museums. The Museum has developed from the storage space and knowledge presentation, over exhibition space to an ideal museum, dominated by estheticized expositions, establishing various official representations of the past. The changes in the theory of museology, somewhat coinciding with the changes in archaeological theory, have posed a new challenge to museum archaeology, that may be defined in short as the need for the new interpretation of the past.

  1. Moessbauer Studies in Chinese Archaeology: A Review

    Energy Technology Data Exchange (ETDEWEB)

    Hsia Yuanfu; Huang Hongbo [Nanjing University, Department of Physics (China)

    2003-09-15

    The Moessbauer effect has been applied to a wide variety of objects related to Chinese archaeology. Besides ceramic artifacts, materials like porcelain, glazes, bronzes, ancient coins, ancient mineral drugs, and even fossils were studied. This article reviews these applications with particular emphasis on the study of the famous terracotta warriors and horses of the Qin Dynasty.

  2. Archaeometric studies on the Hatahara archaeological site

    International Nuclear Information System (INIS)

    The reconstruction of the past and the understanding of historical and cultural aspects of societies that developed at archaeological sites have been enabled by archaeometric studies undertaken on ceramics located at these areas. This study aims to be a contribution to the elucidation of these aspects with the application of three physical methods of analysis: neutron activation analysis (NAA), thermoluminescence dating (TL) an electronic paramagnetic resonance (EPR) to ceramic fragments from the Hatahara archaeological site, located at central Amazon. The elemental concentrations obtained by NAA for 120 ceramic fragments were interpreted by means of cluster analysis and discriminant analysis. The results showed the existence of five distinct ceramic groups. This information, supported by archaeological interpretation, confirm the existence of four distinct occupation Phases at Hatahara site. In order to establish a chronology for the occupations, the ages of three ceramic fragments were determined by TL. The dating of two fragments did not confirm the archaeological interpretation about their occupation Phases. However, the dating of the third fragment allowed the confirmation that it belongs to the Manacapuru Phase. The determination of the burning temperatures of four ceramic fragments was performed by EPR. It was observed that although the analyzed ceramic samples belong to three distinct groups, there was no significant variation on their burning temperatures. (author)

  3. Educational Reconstruction through the Lens of Archaeology

    Science.gov (United States)

    Milewski, Patrice

    2010-01-01

    This article examines the educational reconstruction that was undertaken by the Department of Education in Ontario during the first years of the twentieth century. It draws on Foucault's method of archaeology to identify how schooling reforms comprised a discontinuity in pedagogic knowledge. This mutation created the conditions of possibility for…

  4. EIS Field Investigation in an Archaeological Site

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2000-01-01

    Nydam Mose is an area rich in archaeological artefacts from the Iron Age. Excavations have been conducted in this area since 1859. Environmental changes and probably disturbances caused by excavating the area are now expected to have lead to an accelerated rate of deterioration of both wood and m...

  5. Studying at the UCL Institute of Archaeology

    Directory of Open Access Journals (Sweden)

    Bill Sillar

    2013-10-01

    Full Text Available Ranked 1st in 'The Guardian' (2013 league table for studying archaeology Ranked 2nd in 'The Times' (2013 ‘Good University Guide’ 100% of Institute undergraduate finalists expressed satisfaction with our teaching and support in the UK National Student Surveys 2010 and 2011 Students at the UCL Institute of Archaeology discover the rich diversity of the human past, exploring societies from two million years ago to the present day, and asking questions of relevance to our shared global future. To address these questions students integrate the humanities and the sciences; using a wide range of approaches to collect, evaluate and interpret relevant evidence. At UCL and during survey and excavation projects students make life-long friends while developing teamwork, management and leadership skills. Studying archaeology demands energy and enthusiasm, it challenges expectations while developing the problem-solving and transferable skills which all employers are looking for. Graduates from the Institute go on to make wide-ranging contributions to society, including business, academia and archaeology.

  6. Interactions In Space For Archaeological Models

    CERN Document Server

    Evans, T S; Knappett, C

    2011-01-01

    In this article we examine a variety of quantitative models for describing archaeological networks, with particular emphasis on the maritime networks of the Aegean Middle Bronze Age. In particular, we discriminate between those gravitational networks that are most likely (maximum entropy) and most efficient (best cost/benefit outcomes).

  7. The fifth issue of Archaeology International

    OpenAIRE

    Harris, David R.

    2001-01-01

    With the appearance of this issue, Archaeology International (AI) reaches its fifth birthday. Since it was launched, as a successor to the former Bulletin and Annual Reports of the Institute, my aim each year has been to feature short articles on current research by Institute staff and research students, and to supplement them with summary information about other research-related matters.

  8. Palaeolithic research at the Institute of Archaeology

    Directory of Open Access Journals (Sweden)

    Andrew Garrard

    2005-08-01

    Full Text Available Since its foundation in 1937, the Institute of Archaeology has been an important centre of research on Pleistocene environments and Palaeolithic archaeology. Frederick Zeuner (loA: 1937-1963 was greatly respected for his teaching and research on the subject, including his 1945 publication The Pleistocene period and John Waechter (loA: 1954-1978 for his Palaeolithic excavations at Gorham's Cave in Gibraltar and Swanscombe in the Thames Valley. Mark Newcomer (loA: 1973-1989 inspired many of the students with his experimental research on prehistoric bone and flint technology and for his innovative work on the microwear analysis of flint tools. In 1982, Mark Roberts began his excavations at the Lower Palaeolithic site of Boxgrove in Sussex and more recently Matthew Pope has been involved in an extensive survey of the Middle Pleistocene raised beaches along the south Sussex coast. Simon Parfitt has been undertaking groundbreaking research into the Lower Palaeolithic of East Anglia. Andrew Garrard and Norah Moloney joined the staff of the Institute of Archaeology in 1990 and 1994 respectively, and Dietrich Stout and Ignacio de la Torre in 2005. Each are involved in research relating to human developments through the Pleistocene and this is outlined in the four sections that follow. Several other staff also undertake research in related fields, including Ole Gron, Simon Hills on, Richard Macphail, Marcello Mannino, Tim Schadla-Hall, James Steele and Ken Thomas. The work of several of these has featured in recent issues of Archaeology International.

  9. Particle accelerators unravel Art and Archaeology issues

    Science.gov (United States)

    Calligaro, Thomas

    2008-10-01

    Many analytical techniques are applied to get a better insight on art works and archaeological artefacts and to contribute to their conservation and restoration. Because of the precious and sometimes unique character of these items, non-destructive and non-sampling techniques are preferred. From this standpoint, the analysis with ion beams produced by accelerators (IBA), featuring good analytical performance and non-destructiveness, constitutes one of the best choices. Ion beams analysis techniques (IBA) introduced in 1957 have been constantly adapted to address art and archaeology questions; today the performances obtained directly on the object placed in the atmosphere rival with those achieved in vacuum. Since 20 years, AGLAE, the IBA facility of the Centre for Research and Restoration of the Museums of France located in the Louvre museum has contributed to this progress. The cornerstone of this development is a versatile external nuclear microprobe implementing PIXE, PIGE, RBS, NRA and ERDA methods for rapid expertises of art works and more extensive research works in art history, archaeology and conservation science. After an introduction of the physical principles of IBA, a virtual tour of this unique facility will be provided. The benefit of its use will be illustrated through two case studies, the first one dealing with the determination by PIXE of the provenance of painted works of the Spanish master Murillo and the second one with the authentication study using NRA of a mysterious archaeological rock crystal skull.

  10. Archaeology for the Science Teacher: Interdisciplinary Applications.

    Science.gov (United States)

    Anslinger, C. Michael; Thiel, Daniel P.

    1984-01-01

    Provides an example of how archaeologists might conduct a hypothetical research program to illustrate how specific types of data are generated and then used to interpret prehistoric culture systems. A brief review of the historical development of American archaeology is also provided. (JN)

  11. Archaeological and Geological dating by means of thermoluminescence

    International Nuclear Information System (INIS)

    In this thesis an specific method for dating local archaeological and geological samples based on the phenomenon of thermoluminescence (TL) using the fine grain and quartz inclusion techniques is developed. Taking into account that this work is interesting for professionals working in the fields of Physics, Chemistry, Archaeology, Anthropology and related sciences, some basic concepts are described to have a better comprehension. Chapter 1 describes the concept of radioactivity, remarking the importance of the different decay types as well as the main radioactive series and the energy liberated in the process. The causes of radioactive desequilibrium are also considered in the case for radon. Another important aspect taken into account in this chapter is the radioisotope production and its relationship with the neutron activation analysis used for the determination of the Uranium and Thorium concentrations in the samples. The TL phenomenon is described in Chapter 2, emphasizing the importance of the process of thermally stimulated luminescence best known as TL and its application for dating minerals of different origin. Chapter 3 shows some important antecedents remarking some aspects of the techniques commonly used for dating purposes. Chapter 4 shows the different methods used for the sample preparation. The techniques used for the 40 K, 238 U and 232 Th determination as well as for the cosmic radiation measurement using locally made TLD are also described. The methods used for the determination of the paleodosis as a function of the TL intensity of each sample are described: special emphasis is taken on the moisture effects as well as in the error limits in the age estimation. Results and conclusions of this study are presented in Chapter 5. These results gave an age of 980 ± 90 years for the Edzna ceramic and 1520 ± 90 years for the Calixtlahuaca ceramics. The age of the Teotihuacan ceramics was not estimated due to the lack of a stable region of the traps

  12. Bad chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    General chemistry courses haven't changed significantly in forty years. Because most basic chemistry students are premedical students, medical schools have enormous influence and could help us start all over again to create undergraduate chemistry education that works.

  13. Male strategies and Plio-Pleistocene archaeology.

    Science.gov (United States)

    O'Connell, J F; Hawkes, K; Lupo, K D; Blurton Jones, N G

    2002-12-01

    Archaeological data are frequently cited in support of the idea that big game hunting drove the evolution of early Homo, mainly through its role in offspring provisioning. This argument has been disputed on two grounds: (1) ethnographic observations on modern foragers show that although hunting may contribute a large fraction of the overall diet, it is an unreliable day-to-day food source, pursued more for status than subsistence; (2) archaeological evidence from the Plio-Pleistocene, coincident with the emergence of Homo can be read to reflect low-yield scavenging, not hunting. Our review of the archaeology yields results consistent with these critiques: (1) early humans acquired large-bodied ungulates primarily by aggressive scavenging, not hunting; (2) meat was consumed at or near the point of acquisition, not at home bases, as the hunting hypothesis requires; (3) carcasses were taken at highly variable rates and in varying degrees of completeness, making meat from big game an even less reliable food source than it is among modern foragers. Collectively, Plio-Pleistocene site location and assemblage composition are consistent with the hypothesis that large carcasses were taken not for purposes of provisioning, but in the context of competitive male displays. Even if meat were acquired more reliably than the archaeology indicates, its consumption cannot account for the significant changes in life history now seen to distinguish early humans from ancestral australopiths. The coincidence between the earliest dates for Homo ergaster and an increase in the archaeological visibility of meat eating that many find so provocative instead reflects: (1) changes in the structure of the environment that concentrated scavenging opportunities in space, making evidence of their pursuit more obvious to archaeologists; (2) H. ergaster's larger body size (itself a consequence of other factors), which improved its ability at interference competition. PMID:12473486

  14. Fantastic Archaeology: The Wild Side of North American Archaeology, by Stephen Williams. University of Pennsylvania Press, Philadelphia, 1991

    Directory of Open Access Journals (Sweden)

    Bruce G. Trigger

    1993-05-01

    Full Text Available For many years Stephen Williams has taught a course at Harvard University dealing with those aspects of Americanist archaeology that the finds to be based on fantasy rather than on carefully recovered archaeological evidence. He has now published a book based on this course, which provides a history of this archaeology. Much of the strength of this book is derived from Williams' recognition that fantastic archaeology has been an integral part of American archaeology from its earliest days, that the border between the fantastic and the scientific is problematical, and that weird ideas often fill real social needs.

  15. Probing Nucleobase Interactions and Predicting Mechanisms of Synthetic Interest Using Computational Chemistry, and Furthering the Development of BVI Education in Chemistry

    Science.gov (United States)

    Harrison, Jason Gordon

    2013-01-01

    Quantum mechanical (QM) and molecular docking methods are used to probe systems of biological and synthetic interest. Probing interactions of nucleobases within proteins, and properly modeling said interactions toward novel nucleobase development, is extremely difficult, and of great utility in RNA interference (RNAi) therapeutics. The issues in…

  16. The Breath of Chemistry

    DEFF Research Database (Denmark)

    Josephsen, Jens

    The present preliminary text is a short thematic presentation in biological inorganic chemistry meant to illustrate general and inorganic (especially coordination) chemistry in biochemistry. The emphasis is on molecular models to explain features of the complicated mechanisms essential to breathing...

  17. Archaeological analogous and industrials for deep storage: study of the archaeological metallic piece

    International Nuclear Information System (INIS)

    The aim of present research is to obtain information about archaeological analogous of iron and steel, useful for the model of deep geological repository (AGP). The analogous examined have remained buried between 1400 and 2400 years, in very assorted geochemical environments. The extraction of the archaeological pieces has been accomplished according to normalised protocols, trying to carry to the laboratory so the piece as its burial environment, avoiding all possible pollution. Trying to the archaeological analogous could provide valuable information to the AGP model, the study has been directed to related the physical-chemical characteristics of the terrain respect to the deterioration of the archaeological metallic piece. The geology of the surrounding terrain to the archaeological deposit, the geomorphological study of the terrain and data from the analysis of ground: pH, wetness, porosity, organic matter contents, bacteria presence, sulphates, carbonates, chlorides, etc., have allowed to explain the physical-chemical phenomena suffered by the archaeological iron and steel pieces. Also, an exhaustive study of the archaeological piece has been accomplished, concerning the microstructure of the corrosion layer and of the not deteriorated metallic rest. Obtained information concerns different items, such as corrosion velocity and formations of oxide layers, diffusion of chemical elements from the corrosion layer to the metal and viceversa, and structural changes in oxide layers and in the metallic remains by structural ageing. Obtained data have allowed to develop a mathematical model for calculation of corrosion velocity in buried iron and steels, based on physical-chemical variables of grounds, chemical composition and thermomechanical treatment given to the metal during its manufacture. (Author)

  18. Iron deposition in modern and archaeological teeth

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.-M.M., E-mail: AnneMarie.Williams@utas.edu.au [School of Medicine, Private Bag 34, University of Tasmania, Hobart 7001 (Australia); Siegele, R. [Australian Nuclear Science and Technology Organisation, PMB 1, Menai, NSW 2234 (Australia)

    2014-09-15

    Iron surface concentrations and profile maps were measured on the enamel of archaeological and modern teeth to determine how iron is deposited in tooth enamel and if it was affected by the post-mortem environment. Teeth from Australian children who died in the second half of the 19th century were compared with contemporary teeth extracted for orthodontic purposes. Surface analysis of the teeth was performed using the 3 MV Van Der Graff Accelerator at The Australian Nuclear Science and Technology Organisation (ANSTO), Sydney, Australia. A small sample of teeth were then cut in the mid sagittal plane and analysed using ANSTO High Energy Heavy Ion Microprobe. Maps and linear profiles were produced showing the distribution of iron across the enamel. Results show that both the levels and distribution of iron in archaeological teeth is quite different to contemporary teeth, raising the suggestion that iron has been significantly altered by the post-mortem environment.

  19. A Faceted Query Engine Applied to Archaeology

    Directory of Open Access Journals (Sweden)

    Kenneth A. Ross

    2007-04-01

    Full Text Available In this article we present the Faceted Query Engine, a system developed at Columbia University under the aegis of the inter-disciplinary project Computational Tools for Modeling, Visualizing and Analyzing Historic and Archaeological Sites. Our system is based on novel Database Systems research that has been published in Computer Science venues (Ross and Janevski, 2004 and Ross et al., 2005. The goal of this article is to introduce our system to the target user audience - the archaeology community. We demonstrate the use of the Faceted Query Engine on a previously unpublished dataset: the Thulamela (South Africa collection. This dataset is comprised of iron-age finds from the Thulamela site at the Kruger National Park. Our project is the first to systematically compile and classify this dataset. We also use a larger dataset, a collection of ancient Egyptian artifacts from the Memphis site (Giddy,1999, to demonstrate some of the features of our system.

  20. WATER AND ARCHAEOLOGY FOR SUSTAINABLE TOURISM

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    NICHOLAS KATHIJOTES

    2016-03-01

    Full Text Available Water is undoubtedly the most precious resource of the planet and the accessibility to water resources marked the history of mankind since the dawn of times. Water has been indeed very central to archaeology and anthropology, that studied the ways in which water was provisioned, tanked, distributed, worshipped, exploited for agricultural irrigation or to power machines like water-mills, used for leisure, hygiene and healing, or abused to confer power on particular groups ,and how it played a central role in political and economic strategies. More than any other factor, waterways marked cultural and economic developments in history. This paper outlines examples of water resources management throughout the ages, in Cyprus and the Hellenic Civilization on different aspects of the use and management of water, investigates technical issues and gives suggestions, thus promoting a new approach to archaeological heritage and sustainable tourism.

  1. Quantitative paleoparasitology applied to archaeological sediments

    Directory of Open Access Journals (Sweden)

    Martín H Fugassa

    2006-12-01

    Full Text Available Three techniques to extract parasite remains from archaeological sediments were tested. The aim was to improve the sensibility of recommended paleoparasitological techniques applied in archaeological remains. Sediment collected from the pelvic girdle of a human body found in Cabo Vírgenes, Santa Cruz, Argentina, associated to a Spanish settlement founded in 1584 known as Nombre de Jesús, was used to search for parasites. Sediment close to the skull was used as control. The techniques recommended by Jones, Reinhard, and Dittmar and Teejen were used and compared with the modified technique presented here, developed to improve the sensibility to detect parasite remains. Positive results were obtained only with the modified technique, resulting in the finding of Trichuris trichiura eggs in the sediment.

  2. Mathematical Chemistry

    OpenAIRE

    Trinajstić, Nenad; Gutman, Ivan

    2002-01-01

    A brief description is given of the historical development of mathematics and chemistry. A path leading to the meeting of these two sciences is described. An attempt is made to define mathematical chemistry, and journals containing the term mathematical chemistry in their titles are noted. In conclusion, the statement is made that although chemistry is an experimental science aimed at preparing new compounds and materials, mathematics is very useful in chemistry, among other things, to produc...

  3. Basic Issues in Harappan Archaeology: Some Thoughts

    Directory of Open Access Journals (Sweden)

    Vasant Shinde

    2006-12-01

    Full Text Available The identification of the Harappan Civilization in the early twentieth century was considered to be the most significant archaeological discovery in the Indian Subcontinent as it pushed the beginning of settled life by 2000 years. Contemporary to the Mesopotamian and Egyptian Civilizations it was unique in its town planning. Spread over major parts of the western and north-western subcontinent, its influence is seen to the Tajikistan border in the north and the Gulf region in the west with over two thousand sites found till date. The past eight decades of research have brought to light many important details of the culture including the cultural process involving its origin, maturity and decline but certain aspects such as the terminology, climatic influence, regional variations, script etc are still very flimsy. To gain more information the focus of research will have to shift from Mega Site Archaeology to Small Site Archaeology with large multidisciplinary research projects to acquire a more holistic picture of the Harappan culture.

  4. Contextualising Archaeological Information Through Interactive Maps

    Directory of Open Access Journals (Sweden)

    Ian Johnson

    2002-09-01

    Full Text Available Many web sites use maps delivered as non-interactive images. With the development of web-enabled mapping, new methods of presenting and contextualising archaeological and historical data are becoming available. However, most current examples are static views of contemporary framework data or specific time slices, and do not provide interactivity relating to the time dimension, which is so important to archaeology and related disciplines. In this article I look at some of the advantages of time-enabled interactive mapping and map animation in providing educational experiences to museum visitors and the web-browsing public. These will be illustrated through three example applications of the TimeMap methodology developed at the University of Sydney Archaeological Computing Laboratory: 1. the Sydney TimeMap kiosk at the Museum of Sydney; 2. an embedded Java mapping applet developed for MacquarieNet, a major Australian online educational encyclopaedia; and 3. the metadata clearinghouse mapping applet developed for the Electronic Cultural Atlas Initiative, Berkeley. In each of these examples, a wide range of resources are delivered through a time-enabled map interface which accesses live database data rather than pre-structured curated presentations of data. This flexibility brings its own challenges in providing intuitive pathways and appropriate levels of detail in response to free-ranging user enquiries. The paper outlines some of the approaches I have adopted to resolve these issues.

  5. When Archaeology Begins: The Cultural and Political Context of Chinese Archaeological Thought

    Directory of Open Access Journals (Sweden)

    Xinyi Liu

    2008-05-01

    Full Text Available Since the beginning of the 19th century, the construction of world history has been dominated by Western Europe. In Jack Goody’s recent work, The Theft of History (2007, he demonstrates that the interpretation of the past is conceptualized and presented according to what happened in Europe, and more often in Western Europe. Chinese archaeology, under the control of Western imperialism in the early 20th century, believed that it had to destroy Confucianism and come up with a new philosophy. However, with the arrival of many different kinds of western ideas, such as evolution and diffusion, Chinese archaeology was reformulated many times. Such issues have been discussed in several publications (Chen 1997; Liu and Chen 1999; Falkenhausen 1993. In this paper, we reexamine some of the key concepts of Chinese archaeological thought.

  6. Skyscape Archaeology: an emerging interdiscipline for archaeoastronomers and archaeologists

    Science.gov (United States)

    Henty, Liz

    2016-02-01

    For historical reasons archaeoastronomy and archaeology differ in their approach to prehistoric monuments and this has created a divide between the disciplines which adopt seemingly incompatible methodologies. The reasons behind the impasse will be explored to show how these different approaches gave rise to their respective methods. Archaeology investigations tend to concentrate on single site analysis whereas archaeoastronomical surveys tend to be data driven from the examination of a large number of similar sets. A comparison will be made between traditional archaeoastronomical data gathering and an emerging methodology which looks at sites on a small scale and combines archaeology and astronomy. Silva's recent research in Portugal and this author's survey in Scotland have explored this methodology and termed it skyscape archaeology. This paper argues that this type of phenomenological skyscape archaeology offers an alternative to large scale statistical studies which analyse astronomical data obtained from a large number of superficially similar archaeological sites.

  7. From Web to Grid, a new perspective for archaeology

    CERN Document Server

    Pelfer, Pier Giovanni

    2004-01-01

    It is well known that in Archaeology large use is done of digital technologies and computer applications for data acquisition, storage, analysis and visualisation. In the last years the amount of information coming from remote sensing. from precise and fast acquisition of 3-D artefacts images by scanners laser, from GPS precise reference of geographical points and from other human and natural sciences are increasing at a large extent the amount of data that it need to be stored and made available for analysis. Moreover the use of Virtual Archaeology as a new approach to the narration and visualisation in Archaeology, is expanding rapidly, not only in the museum and archaeology professions, but also in the broadcast media, tourism and heritage industries. From another side recent natural and social disasters (wars) created enormous damages to the archaeological heritage and in many case destroyed definitively any information about ancient civilisations. It is urgent a longterm project for saving archaeological...

  8. The Effect of a Rapid Heating Rate, Mechanical Vibration and Surfactant Chemistry on the Structure–Property Relationships of Epoxy/Clay Nanocomposites

    Directory of Open Access Journals (Sweden)

    Kevin Magniez

    2013-08-01

    Full Text Available The role of processing conditions and intercalant chemistry in montmorillonite clays on the dispersion, morphology and mechanical properties of two epoxy/clay nanocomposite systems was investigated in this paper. This work highlights the importance of employing complementary techniques (X-ray diffraction, small angle X-ray scattering, optical microscopy and transmission electron microscopy to correlate nanomorphology to macroscale properties. Materials were prepared using an out of autoclave manufacturing process equipped to generate rapid heating rates and mechanical vibration. The results suggested that the quaternary ammonium surfactant on C30B clay reacted with the epoxy during cure, while the primary ammonium surfactant (I.30E catalysed the polymerisation reaction. These effects led to important differences in nanocomposite clay morphologies. The use of mechanical vibration at 4 Hz prior to matrix gelation was found to facilitate clay dispersion and to reduce the area fraction of I.30E clay agglomerates in addition to increasing flexural strength by over 40%.

  9. Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

    DEFF Research Database (Denmark)

    Hashikawa, Y; Kawasaki, M; Andersen, Mads Peter Sulbæk;

    2004-01-01

    FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100-700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 +/- 0.05 and 0.47 +/- 0.05, respectively. Results are discussed with...... respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a. (C) 2004 Elsevier B.V. All rights reserved....

  10. Design, synthesis and bioactivity of novel ALS enzyme inhibitors (II)——Molecular mechanics, quantum chemistry and structure-activity relationship studies on the herbicidal heterocyclic sulfonamide

    Institute of Scientific and Technical Information of China (English)

    陆荣健; 杨华铮; 尚贞锋; 汪惟为; 潘荫明; 赵学庄

    1996-01-01

    In view of quantum pharmacology, the structure-activity relationships of different kinds of fused heterocydic sulfonamides with the same mode of action were first investigated using molecular mechanics, quantum chemistry and discriminatory analysis. It has been found that the process of the interaction of the fused heterocydic sulfonamide with ALS enzyme involves the electropositive region of the sulfonyl bridge chain and the electronegative region of the heterocydic moiety. The herbicidal activity is related to the potency of electric charge translocation of the related regions.

  11. Training and Maritime Archaeology in a University Context

    Science.gov (United States)

    Parham, David; Palma, Paola

    2008-12-01

    This paper draws on experience gained by Bournemouth University to consider undergraduate education in maritime archaeology. At Bournemouth maritime archaeology is taught firmly in the context of a broader archaeological education. Archaeological programmes vary with the institutions within which they are taught, each programme thus having an individual character that separates it from that of other institutions and further enriches the subject through the breadth of this education. At Bournemouth the value of teaching archaeology with a high component of practical experience has been long understood. This does not mean that archaeology is taught as a purely practical subject but as one within which experience in the field is seen as a worthwhile focus. Bournemouth’s programme therefore recognises the value of field research projects as learning environments for undergraduates studying maritime archaeology. The programme is subject to a number of constraints, notably the size of the archaeological employment market, levels of pay within that market, questions of ongoing professional development after graduation, and the requirements of other employment markets into which archaeological graduates enter. This paper argues that research project-based learning, and in particular, involvement with amateur groups, provides a way to balance these constraints and supports development of both technical and transferable ‘soft’ skills.

  12. Geodetic surveying as part of archaeological research in Sudan

    Directory of Open Access Journals (Sweden)

    Jan Pacina

    2015-06-01

    Full Text Available Surveying is an important part of any archaeological research. In this paper we focus on the archaeological research in north Sudan (6th Nile cataract and the surveying methods applicable under the local conditions. Surveying in the Third World countries is affected by the political situation (limited import of surveying tools, local conditions (lack of fixed points, GNSS correction signal, inaccessible basemaps and fixed point network. This article describes the methods and results obtained during the three archaeological seasons (2011-2014. The classical surveying methods were combined with KAP (Kite Aerial Photography to obtain the desired results in form of archaeological maps, detailed orthophoto images and other analyses results.

  13. 77 FR 59660 - Notice of Inventory Completion: Stanford University Archaeology Center, Stanford, CA

    Science.gov (United States)

    2012-09-28

    ... National Park Service Notice of Inventory Completion: Stanford University Archaeology Center, Stanford, CA AGENCY: National Park Service, Interior. ACTION: Notice. SUMMARY: The Stanford University Archaeology... Stanford University Archaeology Center. Repatriation of the human remains to the Indian tribes stated...

  14. 77 FR 34987 - Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology & Anthropology...

    Science.gov (United States)

    2012-06-12

    ... National Park Service Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology...: Notice. SUMMARY: The University of Pennsylvania Museum of Archaeology & Anthropology has completed an...: Dr. Richard Hodges, Director, University of Pennsylvania Museum of Archaeology &...

  15. Chemistry Notes

    Science.gov (United States)

    School Science Review, 1976

    1976-01-01

    Described are eight chemistry experiments and demonstrations applicable to introductory chemistry courses. Activities include: measure of lattice enthalpy, Le Chatelier's principle, decarboxylation of soap, use of pocket calculators in pH measurement, and making nylon. (SL)

  16. Colour Chemistry

    Science.gov (United States)

    Griffiths, J.; Rattee, I. D.

    1973-01-01

    Discusses the course offerings in pure color chemistry at two universities and the three main aspects of study: dyestuff chemistry, color measurement, and color application. Indicates that there exists a constant challenge to ingenuity in the subject discipline. (CC)

  17. Positronium chemistry

    CERN Document Server

    Green, James

    1964-01-01

    Positronium Chemistry focuses on the methodologies, reactions, processes, and transformations involved in positronium chemistry. The publication first offers information on positrons and positronium and experimental methods, including mesonic atoms, angular correlation measurements, annihilation spectra, and statistical errors in delayed coincidence measurements. The text then ponders on positrons in gases and solids. The manuscript takes a look at the theoretical chemistry of positronium and positronium chemistry in gases. Topics include quenching, annihilation spectrum, delayed coincidence

  18. Combinatorial chemistry

    DEFF Research Database (Denmark)

    Nielsen, John

    1994-01-01

    An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds.......An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds....

  19. Geometric documentation of underwater archaeological sites

    Directory of Open Access Journals (Sweden)

    Eleni Diamanti

    2013-12-01

    Full Text Available Photogrammetry has often been the most preferable method for the geometric documentation of monuments, especially in cases of highly complex objects, of high accuracy and quality requirements and, of course, budget, time or accessibility limitations. Such limitations, requirements and complexities are undoubtedly features of the highly challenging task of surveying an underwater archaeological site. This paper is focused on the case of a Hellenistic shipwreck found in Greece at the Southern Euboean gulf, 40-47 meters below the sea surface. Underwater photogrammetry was chosen as the ideal solution for the detailed and accurate mapping of a shipwreck located in an environment with limited accessibility. There are time limitations when diving at these depths so it is essential that the data collection time is kept as short as possible. This makes custom surveying techniques rather impossible to apply. However, with the growing use of consumer cameras and photogrammetric software, this application is becoming easier, thus benefiting a wide variety of underwater sites. Utilizing cameras for underwater photogrammetry though, poses some crucial modeling problems, due to the refraction effect and further additional parameters which have to be co-estimated [1]. The applied method involved an underwater calibration of the camera as well as conventional field survey measurements in order to establish a reference frame. The application of a three-dimensional trilateration using common tape measures was chosen for this reason. Among the software that was used for surveying and photogrammetry processing, were Site Recorder SE, Eos Systems Photomodeler, ZI’s SSK and Rhinoceros. The underwater archaeological research at the Southern Euboean gulf is a continuing project carried out by the Hellenic Institute for Marine Archaeology (H.I.M.A. in collaboration with the Greek Ephorate of Underwater Antiquities, under the direction of the archaeologist G

  20. Archaeological program for the Yucca Mountain Site

    International Nuclear Information System (INIS)

    Archaeological surveys, limited surface collections and selected test excavations in the Yucca Mountain Project Area have revealed four distinct aboriginal hunting and gathering adaptive strategies and a separate historic Euroamerican occupation. The four aboriginal adaptations are marked by gradual shifts in settlement locations that reflect changing resource procurement strategies. Whereas the earliest hunters and gatherers focused their activities around the exploitation of toolstone along ephemeral drainages and the hunting of game animals in the uplands, the latest aboriginal settlements reflect intensive procurement of early spring plant resources in specific upland environments. The final Euroamerican occupation in the area is marked by limited prospecting activities and travel through the area by early immigrants

  1. The Petrie Museum of Egyptian Archaeology, UCL

    Directory of Open Access Journals (Sweden)

    Jan Picton

    2013-10-01

    Full Text Available University College London houses one of the world’s most important collections of ancient Egyptian material, the majority excavated by Flinders Petrie, his students and his successors in the late 19th and early 20th centuries. It is a museum of archaeology that helps to explain the development of a discipline that was in its infancy when Petrie worked in Egypt over a century ago. It is a teaching collection, its densely packed cases entrancing, and sometimes intimidating, visitors who rave about its old-fashioned feel, but it is anything but frozen in time.

  2. Teaching Archaeology in the Twenty-First Century.

    Science.gov (United States)

    Bender, Susan J., Ed.; Smith, George S., Ed.

    This book was written to offer ideas on how to open archeological education to more students, not just those seeking a Ph.D. Individuals in archaeology provide background and offer suggestions for a movement to provide greater access to the field. The book ponders 21st century archaeology, its possible directions and strategies, and call on those…

  3. Geohistorical Archaeology: A Perspective for Considering the Historic Past

    Science.gov (United States)

    McGregor, John R.

    2002-01-01

    The term geohistorical archaeology was adopted to describe the combination of the techniques and concepts of historical geography, historical archaeology, and history. It is suggested that the field offers the potential of enhanced research and instruction as it pertains to the early historical settlement of an area. Particular emphasis is placed…

  4. Synchrotron radiation in art and archaeology SRA 2005

    Energy Technology Data Exchange (ETDEWEB)

    Pollard, A.M.; Janssens, K.; Artioli, G.; Young, M.L.; Casadio, F.; Schnepp, S.; Marvin, J.; Dunand, D.C.; Almer, J.; Fezzaa, K.; Lee, W.K.; Haeffner, D.R.; Reguer, S.; Dillmann, Ph.; Mirambet, F.; Susini, J.; Lagarde, P.; Pradell, T.; Molera, J.; Brunetti, B.; D' acapito, F.; Maurizio, C.; Mazzoldi, P.; Padovani, S.; Sgamellotti, A.; Garges, F.; Etcheverry, M.P.; Flank, A.M.; Lagarde, P.; Marcus, M.A.; Scheidegger, A.M.; Grolimund, D.; Pallot-Frossard, I.; Smith, A.D.; Jones, M.; Gliozzo, E.; Memmi-Turbanti, I.; Molera, J.; Vendrell, M.; Mcconachie, G.; Skinner, T.; Kirkman, I.W.; Pantos, E.; Wallert, A.; Kanngiesser, B.; Hahn, O.; Wilke, M.; NekaT, B.; Malzer, W.; Erko, A.; Chalmin, E.; Vignaud, C.; Farges, F.; Susini, J.; Menu, M.; Sandstrom, M.; Cotte, M.; Kennedy, C.J.; Wess, T.J.; Muller, M.; Murphy, B.; Roberts, M.A.; Burghammer, M.; Riekel, C.; Gunneweg, J.; Pantos, E.; Dik, J.; Tafforeau, P.; Boistel, R.; Boller, E.; Bravin, A.; Brunet, M.; Chaimanee, Y.; Cloetens, P.; Feist, M.; Hoszowska, J.; Jaeger, J.J.; Kay, R.F.; Lazzari, V.; Marivaux, L.; Nel, A.; Nemoz, C.; Thibault, X.; Vignaud, P.; Zabler, S.; Sciau, P.; Goudeau, P.; Tamura, N.; Doormee, E.; Kockelmann, W.; Adriaens, A.; Ryck, I. de; Leyssens, K.; Hochleitner, B.; Schreiner, M.; Drakopoulos, M.; Snigireva, I.; Snigirev, A.; Sanchez Del Rio, M.; Martinetto, P.; Dooryhee, E.; Suarez, M.; Sodo, A.; Reyes-Valerio, C.; Haro Poniatowski, E.; Picquart, M.; Lima, E.; Reguera, E.; Gunneweg, J.; Reiche, I.; Berger, A.; Bevers, H.; Duval, A

    2005-07-01

    Materials - bones, artifacts, artwork,.... - lie at the heart of both archaeology and art conservation. Synchrotron radiation techniques provide powerful ways to interrogate these records of our physical and cultural past. In this workshop we will discuss and explore the current and potential applications of synchrotron radiation science to problems in archaeology and art conservation. This document gathers the abstracts of the presentations.

  5. Environmental archaeology at the Institute: the early years

    Directory of Open Access Journals (Sweden)

    Joan Sheldon

    2001-10-01

    Full Text Available In the 1998/99 issue of Archaeology International, Geoffrey Dimbleby reflected on the period, from 1964 to 1979, when he was head of the Institute's former Department of Human Environment. Here Joan Sheldon (Fig. 1, who joined the Institute in 1948 as assistant to Frederick Zeuner, recalls how environmental archaeology developed during her 35 years on the staff.

  6. Synchrotron radiation in art and archaeology SRA 2005

    International Nuclear Information System (INIS)

    Materials - bones, artifacts, artwork,.... - lie at the heart of both archaeology and art conservation. Synchrotron radiation techniques provide powerful ways to interrogate these records of our physical and cultural past. In this workshop we will discuss and explore the current and potential applications of synchrotron radiation science to problems in archaeology and art conservation. This document gathers the abstracts of the presentations

  7. Mexican Underwater Archaeology and Some of its Challenges and Solutions

    Directory of Open Access Journals (Sweden)

    Pilar Luna Erreguerena

    2013-10-01

    Full Text Available In response to Carver’s lead article, I’d like to highlight an easily overlooked aspect of archaeology: underwater archaeology. I will offer some examples and experiences from Mexico, which will perhaps resonate in other cities and nations around the world with a rich underwater cultural heritage.

  8. Surface chemistry and interfacial charge-transfer mechanisms in photoinduced oxygen exchange at O2-TiO2 interfaces.

    Science.gov (United States)

    Montoya, Juan Felipe; Peral, José; Salvador, Pedro

    2011-04-01

    Experimental results obtained over the last three decades on photoinduced oxygen isotopic exchange (POIE) of TiO₂ oxygen atoms with those of adsorbed water molecules and gaseous O₂ are analyzed in the light of recent information from the literature on the interaction of water and O₂ species with the TiO₂ surface (obtained by application of surface spectroscopy techniques in combination with high-resolution scanning tunnelling microscopy). The analysis emphasizes the singular role that bridging oxygen ions and bridging oxygen vacancies play in TiO₂ surface chemistry and interfacial electron transfer at the gas phase-TiO₂ interface in the absence and presence of water. The observed competition between POIE and the photo-oxidation (PO) of organic compounds is analyzed in terms of the recently developed direct-indirect (D-I) kinetic model for heterogeneous photocatalysis (D. Monllor-Satoca et al., Catal. Today, 2007, 129, 247, and references therein). PMID:21442702

  9. Starry Messages: Searching for Signatures of Interstellar Archaeology

    CERN Document Server

    Carrigan, Richard A

    2010-01-01

    Searching for signatures of cosmic-scale archaeological artifacts such as Dyson spheres or Kardashev civilizations is an interesting alternative to conventional SETI. Uncovering such an artifact does not require the intentional transmission of a signal on the part of the original civilization. This type of search is called interstellar archaeology or sometimes cosmic archaeology. The detection of intelligence elsewhere in the Universe with interstellar archaeology or SETI would have broad implications for science. For example, the constraints of the anthropic principle would have to be loosened if a different type of intelligence was discovered elsewhere. A variety of interstellar archaeology signatures are discussed including non-natural planetary atmospheric constituents, stellar doping with isotopes of nuclear wastes, Dyson spheres, as well as signatures of stellar and galactic-scale engineering. The concept of a Fermi bubble due to interstellar migration is introduced in the discussion of galactic signatu...

  10. Palazzo Valentini: Archaeological discoveries and redevelopment projects

    Directory of Open Access Journals (Sweden)

    Luisa Napoli

    2015-06-01

    Full Text Available Palazzo Valentini, a historical site of Rome׳s Provincial Administration, is located at the heart of the city. The building was purchased in 1827 by Vincenzo Valentini, a banker and consul general of the Prussian Crown. In 1939, with the outbreak of World War II, a fully self-contained, air-raid shelter was built under the courtyard, with an exit tunnel heading onto the Trajan׳s Forum. Archaeological investigations started in 2005 in view of a simple rehabilitation work of the underground level. As work progressed, the sample-plots brought to light new archaeological findings: relics of a huge temple and what remained of two residential houses with thermal baths. We therefore designed an exhibition space with glass surfaces to allow visitors to appreciate the findings while following a path through historical ages: from the 16th-century courtyard to the underground Roman domus (the sumptuous houses of senators and dignitaries of the Roman Empire, with private baths, to the remains of a Roman temple, and all the way to the Trajan׳s Column pedestal by way of the air-raid shelter. Virtual reconstructions, graphic effects, and movies are the means used to revive the hypothetical original appearance of the environments and the daily life of that epoch in order to help us build a prototype of an on-site museum of the third millennium.

  11. Classification of archaeologically stratified pumice by INAA

    International Nuclear Information System (INIS)

    In the framework of the research program 'Synchronization of Civilization in the Eastern Mediterranean Region in the 2nd Millenium B.C.' instrumental neutron activation analysis (INAA) was used to determine 30 elements in pumice from archaeological excavations to reveal their specific volcanic origin. The widespread pumiceous products of several eruptions in the Aegean region were used as abrasive tools and were therefore popular trade objects. A remarkable quantity of pumice and pumiceous tephra (several km3) was produced by the 'Minoan eruption' of Thera (Santorini), which is assumed to have happened between 1450 and 1650 B.C. Thus the discovery of the primary fallout of 'Minoan' tephra in archaeologically stratified locations can be used as a relative time mark. Additionally, pumice lumps used as abrasive can serve for dating by first appearance. Essential to an identification of the primary volcanic source is the knowledge that pumices from the Aegean region can easily be distinguished by their trace element distribution patterns, as previous work has shown. The elements Al, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, Ti, U, V, Yb, Zn and Zr were determined in 16 samples of pumice lumps from excavations in Tell-el-Dab'a and Tell-el-Herr (Egypt). Two irradiation cycles and five measurement runs were applied. A reliable identification of the samples is achieved by comparing these results to the database compiled in previous studies. (author)

  12. Radiology in archaeological studies of incas mummies

    International Nuclear Information System (INIS)

    Purpose: The purpose of this paper was to determine the imaging findings in three 500-year-old Inca mummies and how modern radiology can be used in other sciences such as archaeology. Material and Method: Three naturally mummified children were studied using conventional radiography, dental radiography, CT and puncture biopsies. Working sessions were limited to 20 minutes to prevent thawing of the corpses and radiological techniques were adjusted to their particular anatomic position. Results: CT images showed shrinkaged internal organs due to dehydration. The fatty tissue of the bodies was visibly white because of the transformation of it into adipocere, favoring white matter/gray matter differentiation at the central nervous system. The lungs were expanded in the three corpses and right lung and maxillary sinus pathologies were determined in the older girl. Chronological ages of the three children at the time of their deaths were established. DNA studies determined no family links among them. The spleen was not seen in any case. Conclusions: Modern radiology is an excellent tool in archaeological research. Nutritional state, ages and pathologies of the three mummies were evaluated. (author)

  13. Review of Ramsey Abbey - An Archaeological Survey

    Directory of Open Access Journals (Sweden)

    Chris Gaffney

    2002-11-01

    Full Text Available The CD is designed to be read using most standard web browsers and is compatible with both Windows and Mac operating systems. Occasionally in order to view a diagram you are transported into Adobe Acrobat, a copy of which is on the CD. The CD is the culmination of a community based project based on the medieval abbey at Ramsey in Cambridgeshire, England. According to the sleeve of the CD the project was paid for by a Royal Society and British Association Millennium Award, which was funded by the Millennium Commission to 'encourage people's understanding of science, engineering and technology in the community'. The science in question largely involves the small-scale, perhaps even surgical, use of resistance, magnetic and ground penetrating radar (GPR. The project, however, had a more interesting agenda, one that involves the testing of an archaeological problem. In short, the Archaeological Field Unit (AFU of Cambridgeshire County Council found that there were competing hypotheses concerning the location of the former church on the now-ruined abbey site. The CD pieces together the evidence for the church, collected with the help of the children at the school that now occupies the site. The CD can be seen as part of the remit to reach the wider community that also involved open days, seminars and a web site.

  14. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

  15. Fundamentals of quantum chemistry

    CERN Document Server

    House, J E

    2004-01-01

    An introduction to the principles of quantum mechanics needed in physical chemistry. Mathematical tools are presented and developed as needed and only basic calculus, chemistry, and physics is assumed. Applications include atomic and molecular structure, spectroscopy, alpha decay, tunneling, and superconductivity. New edition includes sections on perturbation theory, orbital symmetry of diatomic molecules, the Huckel MO method and Woodward/Hoffman rules as well as a new chapter on SCF and Hartree-Fock methods. * This revised text clearly presents basic q

  16. Politics and the World Archaeological Congress [-3

    Directory of Open Access Journals (Sweden)

    Rao, Nandini

    1995-06-01

    Full Text Available The recognition in the West that every discipline is influenced by its socio-political context led to the demand for reflexive archaeology and to the formation in 1986, by the 'politically aware', of the World Archaeological Congress (WAC. WAC explicitly recognises the socio-political context of archaeological practice, and archaelogy's political, social and academic responsibilities. The Congress, which meets every four years, met in India in December 1994. Indian archaeologists have largely denied the influence of socio-political contexts on academics. But this has not prevented some from (misusing archaeological evidence to further political ends with catastrophic results. No discussion on the issue was permitted at the Congress so that eight years after it was formed. the WAC compromised and suppressed free debate on a vital matter. This essay outlines the genesis of WAC and the reasons why it was formed, before analysing the Indian context of the third meeting of the Congress. It also examines the response of Indian archaeologists at WAC to the protest against such political abuse of archaeology and calls for a reflection on whether WAC has achieved its objective of becoming a relevant world organisation.

    El reconocimiento en Occidente de que cada disciplina está influida por su contexto socio-político llevó a la reivindicación de una arqueología reflexiva y a la formación en 1986, por los arqueólogos ”políticamente conscientes”, del Congreso Arqueológico Mundial (WAC. El WAC reconoce explícitamente el contexto sociopolítico de la práctica arqueológica y las responsabilidades políticas, sociales y académicas de la arqueología. El Congreso, que se celebra cada cuatro años, tuvo lugar en India en diciembre de 1994. Los arqueólogos indios han negado durante mucho tiempo la influencia de los contextos socio-políticos sobre los investigadores. Pero ello no ha impedido que algunos de ellos hayan utilizado de

  17. The Application of SCC-DV-Xα Computational Method of Quantum Chemistry in Cement Chemistry

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    It has been explored why quantum chemistry is applied to the research field of cement chemistry. The fundamental theory of SCC-DV-Xα computational method of quantum chemistry is synopsized. The results obtained by computational quantum chemistry method in recent years of valence-bond structures and hydration activity of some cement clinker minerals, mechanical strength and stabilization of some hydrates are summarized and evaluated. Finally the prospects of the future application of quantum chemistry to cement chemistry are depicted.

  18. The Scandinavian Connection: The Roots of Darwinian Archaeology in 19th-Century Scandinavian Archaeology

    Directory of Open Access Journals (Sweden)

    Felix Riede

    2006-05-01

    Full Text Available ‘Evolution’ is without doubt one of archaeology’s favourite, most used and perhaps most overused words. However, ‘evolution’ comes in many guises and it is only really in the last ten years that an explicitly Darwinian approach to the archaeological record has begun to emerge. Today, the number of papers using Darwinian Theory grows almost exponentially, reflecting perhaps the current popularity of applying Darwinian Theory to human behaviour, including culture, in more general terms (Aunger 2000; Barrett et al. 2002; Laland andamp; Brown 2002; Mesoudi et al. 2004; Ziman 2000. The field has developed its own technical jargon (Hart andamp; Terrell 2002 and enjoys increasing public funding. Here is not the place to list, let alone discuss the entire corpus of works (but see http://cladistics.coas.missouri.edu/pubs.html and http://www.ceacb.ucl.ac.uk/resources. Instead this brief papers attempts to address some historical aspects of Darwinian thinking in archaeology. Although there is considerable diversity within this Darwinian or Evolutionary Archaeology (EA, this paper will focus primarily on its two most vocal American proponents: Michael J. O’Brien and Richard Lee Lyman. In a long series of publications they have not only put forward a “radically empiricist” (Shennan 2002a: 255, yet eminently workable Darwinian approach to artefact analysis, but they have also traced the intellectual ancestry of EA back to a number of key figures in early 20th century Americanist archaeology (Lyman et al. 1997b; Lyman andamp; O’Brien 1997, 1999, 2000a, 2001, 2003, 2004; Lyman et al. 1997a, 1997b; Lyman et al. 1998; O’Brien et al. 2005. Despite the impressive amount of scholarship that has gone into these works and the exemplary publication strategy, which has been instrumental in promoting this particular approach, their version of the history of archaeology can be criticised as the writing of “partial histories” (Murray 2002a: 234. As

  19. Detection of 'archaeological features' among reflectance spectra of natural soils and archaeological soils using principal component analysis (PCA)

    Science.gov (United States)

    Choi, Yoon Jung; Lampel, Johannes; Jordan, David; Fiedler, Sabine; Wagner, Thomas

    2016-04-01

    Archaeological terminology 'soil-mark' refers to buried archaeological features being visible on the ground surface. Soil-marks have been identified by archaeologists based on their personal experience and knowledge. This study suggests a quantitative spectral analysis method to detect such archaeological features. This study identifies 'archaeological spectra' (reflectance spectra from surfaces containing archaeological materials) among various soil spectra using PCA (principal component analysis). Based on the results of the PCA, a difference (D) between the original spectrum and modified spectrum, which represents the principal component (PC) values of natural soils, can be determined. If the difference D between the two spectra is small, then the spectrum is similar to the spectral features of natural soils. If not, it identifies that the spectrum is more likely to be non-natural soil, probably an archaeological material. The method is applied on soil spectra from a prehistoric settlement site in Calabria, Italy. For the spectral range between 400 to 700nm, the difference value D for archaeological material ranges from 0.11 to 0.73 (the value varies depending on the number of PCs used). For natural soil, D ranges only from 0.04 to 0.09. The results shows D value is significantly larger for archaeological spectra, which indicates that the method can be applied to identify archaeological material among an unknown group of soil spectra, if a set of samples of natural soils exists. The study will present results of applying this method to various wavelength ranges and spectra from different sites. The major aim is to find optimised settings of the PCA method which can be applied in a universal way for identifying archaeological spectra.

  20. The ceramic artifacts in archaeological black earth (terra preta from Lower Amazon Region, Brazil: chemistry and geochemical evolution Artefatos cerâmicos em sítios arqueológicos com terra preta na região do baixo Amazonas, Brasil: composição química e evolução geoquímica

    Directory of Open Access Journals (Sweden)

    Marcondes Lima da Costa

    2004-09-01

    Full Text Available This paper carried out a chemical investigation of archaeological ceramic artifacts found in archaeological sites with Black Earth (ABE in the Lower Amazon Region at Cachoeira-Porteira, State of Pará, Brazil. The ceramic artifacts, mostly of daily use, belong to Konduri culture (from 900 to 400 years BP. They are constituted of SiO2, Al2O3, Fe2O3, Na2O and P2O5; SiO2 and Al2O3 together add up to 80 % and indicate influence of acid rocks, transformed into clay minerals basically kaolinite. The relative high contents of P2O5 (2.37 % in average come out as (Al,Fe-phosphate, an uncommon fact in primitive red ceramics, but found in some roman and egyptian archaeological sites. The contents of the trace elements are similar or below the Earth's crust average. This chemical composition (except P2O5 detaches saprolite material derived acid igneous rocks or sedimentary ones as the main raw material of the ceramics. The contents of K, Na and Ca represent the feldspars and rock fragments possibly introduced into saprolitic groundmass, indicated by mineralogical studies. The presence of cauixi and cariapé as well as quartz sand was confirmed by optical microscope, SEM analyses and by the high silica contents of ceramic fragments. Phosphorus was possibly incorporated into groundmass during cooking of foods, and ABE soil profile formation developed on yellow Latosols. The raw materials and its tempers (cauixi, or cariapé, feldspar, crushed rocks, old ceramic artifacts and quartz fragments are found close to the sites and therefore and certainly came from them.Neste trabalho realizou-se a caracterização química de fragmentos de artefatos cerâmicos encontrados em sítios arqueológicos com terra preta no Baixo Amazonas (Cachoeira-Porteira, Pará, Brasil, representativos da cultura Konduri (de 900 a 400 anos AP. Esses fragmentos são constituídos de SiO2, Al2O3, Fe2O3, Na2O e P2O5, sendo que SiO2 e Al2O3, juntos, perfazem mais de 80 % em peso. Os teores

  1. Bioinorganic Chemistry

    OpenAIRE

    Bertini, Ivano; Gray, Harry B.; Lippard, Stephen J.; Valentine, Joan Selverstone

    1994-01-01

    This book covers material that could be included in a one-quarter or one-semester course in bioinorganic chemistry for graduate students and advanced undergraduate students in chemistry or biochemistry. We believe that such a course should provide students with the background required to follow the research literature in the field. The topics were chosen to represent those areas of bioinorganic chemistry that are mature enough for textbook presentation. Although each chapter presents material...

  2. Organic chemistry

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-08-15

    This book with sixteen chapter explains organic chemistry on linkage isomerism such as alkane, cycloalkane, alkene, aromatic compounds, stereo selective isomerization, aromatic compounds, stereo selective isomerization, organic compounds, stereo selective isomerization, organic halogen compound, alcohol, ether, aldehyde and ketone, carboxylic acid, dicarboxylic acid, fat and detergent, amino, carbohydrate, amino acid and protein, nucleotide and nucleic acid and spectroscopy, a polymer and medical chemistry. Each chapter has introduction structure and characteristic and using of organic chemistry.

  3. Social Chemistry

    OpenAIRE

    Lichtfouse, Eric; Schwarzbauer, Jan; Robert, Didier

    2012-01-01

    International audience This article is both an essay to propose social chemistry as a new scientific discipline, and a preface of the book Environmental Chemistry for a Sustainable World. Environmental chemistry is a fast emerging discipline aiming at the understanding the fate of pollutants in ecosystems and at designing novel processes that are safe for ecosystems. Past pollution should be cleaned, future pollution should be predicted and avoided (Lichtfouse et al., 2005a). Such advices ...

  4. Computational chemistry

    OpenAIRE

    Truhlar, Donald G.; McKoy, Vincent

    2000-01-01

    Computational chemistry has come of age. With significant strides in computer hardware and software over the last few decades, computational chemistry has achieved full partnership with theory and experiment as a tool for understanding and predicting the behavior of a broad range of chemical, physical, and biological phenomena. The Nobel Prize award to John Pople and Walter Kohn in 1998 highlighted the importance of these advances in computational chemistry. With massively parallel computers ...

  5. The physical basis of chemistry

    CERN Document Server

    Warren, Warren S

    2000-01-01

    If the text you're using for general chemistry seems to lack sufficient mathematics and physics in its presentation of classical mechanics, molecular structure, and statistics, this complementary science series title may be just what you're looking for. Written for the advanced lower-division undergraduate chemistry course, The Physical Basis of Chemistry, Second Edition, offers students an opportunity to understand and enrich the understanding of physical chemistry with some quantum mechanics, the Boltzmann distribution, and spectroscopy. Posed and answered are questions concerning eve

  6. Mechanism of Magnetostructural Transitions in Copper-Nitroxide-Based Switchable Molecular Magnets: Insights from ab Initio Quantum Chemistry Calculations.

    Science.gov (United States)

    Jung, Julie; Guennic, Boris Le; Fedin, Matvey V; Ovcharenko, Victor I; Calzado, Carmen J

    2015-07-20

    The gradual magnetostructural transition in breathing crystals based on copper(II) and pyrazolyl-substituted nitronyl nitroxides has been analyzed by means of DDCI quantum chemistry calculations. The magnetic coupling constants (J) within the spin triads of Cu(hfac)2L(Bu)·0.5C8H18 have been evaluated for the X-ray structures reported at different temperatures. The coupling is strongly antiferromagnetic at low temperature and becomes ferromagnetic when the temperature increases. The intercluster magnetic coupling (J') is antiferromagnetic and shows a marked dependence on temperature. The magnetostructural transition can be reproduced using the calculated J values for each structure in the simulation of the magnetic susceptibility. However, the μ(T) curve can be improved nicely by considering the coexistence of two phases in the transition region, whose ratio varies with temperature corresponding to both the weakly and strongly coupled spin states. These results complement a recent VT-FTIR study on the parent Cu(hfac)2L(Pr) compound with a gradual magnetostructural transition.

  7. Surface chemistry in the interstellar medium - I - H2 formation by Langmuir-Hinshelwood and Eley-Rideal mechanisms

    CERN Document Server

    Bourlot, Jacques Le; Pinto, Cecilia; Roueff, Evelyne; Roy, Fabrice

    2012-01-01

    H2 formation remains a major issue for the understanding of interstellar physics. We investigate H2 formation in the interstellar medium at the light of the most recent experimental and theoretical data. We implemented detailed H2 formation mechanisms on grains surface in the Meudon PDR code : i) Langmuir-Hinshelwood mechanism taking into account the contribution of the different sizes of dust grains in the diffusion processes and ii) the Eley-Rideal mechanism. We show that, thanks to these processes, H2 can be formed even in regions where dust temperature is larger than 25 K. We also show that formation by Eley-Rideal mechanism can be a significant source of heating of the gas. We derive line intensities for various astrophysical conditions. Such an approach results in an enhanced H2 formation rate compared to the standard formation determined by observations in absorption in the UV. We derive some H2 line intensities for isobaric and isochoric models.

  8. The ectomycorrhizal fungus Paxillus involutus converts organic matter in plant litter using a trimmed brown-rot mechanism involving Fenton chemistry

    DEFF Research Database (Denmark)

    Rineau, Francois; Roth, Doris; Shah, Firoz;

    2012-01-01

    chemistry similar to that of brown-rot fungi. The set of enzymes expressed by Pa. involutus during the degradation of the organic matter was similar to the set of enzymes involved in the oxidative degradation of wood by brown-rot fungi. However, Pa. involutus lacked transcripts encoding extracellular...... the mycorrhizal fungi. To capture the nitrogen, the fungi must at least partly disrupt the recalcitrant organic matterprotein complexes within which the nitrogen is embedded. This disruption process is poorly characterized. We used spectroscopic analyses and transcriptome profiling to examine the mechanism...... by which the ectomycorrhizal fungus Paxillus involutus degrades organic matter when acquiring nitrogen from plant litter. The fungus partially degraded polysaccharides and modified the structure of polyphenols. The observed chemical changes were consistent with a hydroxyl radical attack, involving Fenton...

  9. Massive Open Online Archaeology, Massive Open Online Opportunity: Toward a Worldwide Community of Archaeological Practice

    OpenAIRE

    Emanuel, Jeffrey Paul

    2014-01-01

    While the World Wide Web has provided the public at large with heretofore-unimagined access to information, the egalitarian – and frequently anonymous – nature of online content creation has also provided an unprecedented opportunity for the spread of misinformation and misinterpretation alike. Archaeology is no exception to the double-edged sword that is the 21st century web, as the opening of museum collections, the ability to conduct armchair “surveys” via tools like Google Earth, unfetter...

  10. Starry messages: Searching for signatures of interstellar archaeology

    International Nuclear Information System (INIS)

    Searching for signatures of cosmic-scale archaeological artifacts such as Dyson spheres or Kardashev civilizations is an interesting alternative to conventional SETI. Uncovering such an artifact does not require the intentional transmission of a signal on the part of the original civilization. This type of search is called interstellar archaeology or sometimes cosmic archaeology. The detection of intelligence elsewhere in the Universe with interstellar archaeology or SETI would have broad implications for science. For example, the constraints of the anthropic principle would have to be loosened if a different type of intelligence was discovered elsewhere. A variety of interstellar archaeology signatures are discussed including non-natural planetary atmospheric constituents, stellar doping with isotopes of nuclear wastes, Dyson spheres, as well as signatures of stellar and galactic-scale engineering. The concept of a Fermi bubble due to interstellar migration is introduced in the discussion of galactic signatures. These potential interstellar archaeological signatures are classified using the Kardashev scale. A modified Drake equation is used to evaluate the relative challenges of finding various sources. With few exceptions interstellar archaeological signatures are clouded and beyond current technological capabilities. However SETI for so-called cultural transmissions and planetary atmosphere signatures are within reach.

  11. Starry messages: Searching for signatures of interstellar archaeology

    Energy Technology Data Exchange (ETDEWEB)

    Carrigan, Richard A., Jr.; /Fermilab

    2009-12-01

    Searching for signatures of cosmic-scale archaeological artifacts such as Dyson spheres or Kardashev civilizations is an interesting alternative to conventional SETI. Uncovering such an artifact does not require the intentional transmission of a signal on the part of the original civilization. This type of search is called interstellar archaeology or sometimes cosmic archaeology. The detection of intelligence elsewhere in the Universe with interstellar archaeology or SETI would have broad implications for science. For example, the constraints of the anthropic principle would have to be loosened if a different type of intelligence was discovered elsewhere. A variety of interstellar archaeology signatures are discussed including non-natural planetary atmospheric constituents, stellar doping with isotopes of nuclear wastes, Dyson spheres, as well as signatures of stellar and galactic-scale engineering. The concept of a Fermi bubble due to interstellar migration is introduced in the discussion of galactic signatures. These potential interstellar archaeological signatures are classified using the Kardashev scale. A modified Drake equation is used to evaluate the relative challenges of finding various sources. With few exceptions interstellar archaeological signatures are clouded and beyond current technological capabilities. However SETI for so-called cultural transmissions and planetary atmosphere signatures are within reach.

  12. Archaeological Documentation of a Defunct Iraqi Town

    Science.gov (United States)

    Šedina, J.; Pavelka, K.; Housarová, E.

    2016-06-01

    The subject of this article is the possibilities of the documentation of a defunct town from the Pre-Islamic period to Early Islamic period. This town is located near the town Makhmur in Iraq. The Czech archaeological mission has worked at this dig site. This Cultural Heritage site is threatened by war because in the vicinity are positions of ISIS. For security reasons, the applicability of Pleiades satellite data has been tested. Moreover, this area is a no-fly zone. However, the DTM created from stereo-images was insufficient for the desired application in archeology. The subject of this paper is the testing of the usability of RPAS technology and terrestrial photogrammetry for documentation of the remains of buildings. RPAS is a very fast growing technology that combines the advantages of aerial photogrammetry and terrestrial photogrammetry. A probably defunct church is a sample object.

  13. ARCHAEOLOGICAL DOCUMENTATION OF A DEFUNCT IRAQI TOWN

    Directory of Open Access Journals (Sweden)

    J. Šedina

    2016-06-01

    Full Text Available The subject of this article is the possibilities of the documentation of a defunct town from the Pre-Islamic period to Early Islamic period. This town is located near the town Makhmur in Iraq. The Czech archaeological mission has worked at this dig site. This Cultural Heritage site is threatened by war because in the vicinity are positions of ISIS. For security reasons, the applicability of Pleiades satellite data has been tested. Moreover, this area is a no-fly zone. However, the DTM created from stereo-images was insufficient for the desired application in archeology. The subject of this paper is the testing of the usability of RPAS technology and terrestrial photogrammetry for documentation of the remains of buildings. RPAS is a very fast growing technology that combines the advantages of aerial photogrammetry and terrestrial photogrammetry. A probably defunct church is a sample object.

  14. Studies of technology in prehistoric archaeology

    Directory of Open Access Journals (Sweden)

    Vitezović Selena

    2011-01-01

    Full Text Available Technology studies have always been the most important focus of archaeology, as a science which analyzes human past through the study of material culture. To say that something is technological in archaeology, means to put the concept of technology in the centre of theoretical studies, and to study not only the form of the object, but also the entire sequence of technological factors, from raw material choice, mode of use, up to the reasons for abandonment. The concept of technology in anthropology and archaeology is based on the original meaning of the word τεχνη in ancient Greek, meaning the skill, i. e., to study how something is being done. Such a concept of technology as a skill or mode of doing something was for the first time outlined by the French anthropologist Marcel Mauss, whose starting point was that every technological statement was at the same time social or cultural statement and that technological choices have social foundations. Pierre Lemonnier further developed the anthropology of technology, focusing on the question of technological choices, as well as numerous other anthropologists. In archaeology, the most important contribution to the study of technology was the work of André Leroi-Gourhan, who created the concept of chaîne opératoire, as an analytical tool for studying the mode of creating, using and discarding an artefact, starting with raw material acquisition, mode of manufacture, final form, use (including caching, breaking and repairing up to the final discarding. It is not only about reconstructing the algorithmic sequence of operations in creating one object, but it is a complex analysis of operational chain within one society which includes the analysis of technological choices. The analyses of technologies today include a variety of different approaches, most of them with emphasis on the cultural and social aspects of technology. The analysis of bone industry in the Early and Middle Neolithic in central

  15. Public Engagement at Archaeology South-East

    Directory of Open Access Journals (Sweden)

    Hilary Orange

    2013-10-01

    Full Text Available Business skills are a recognised skill shortage within the archaeological profession (Aitchison and Edwards, 2008: 106. Conversely, many small and medium-sized enterprises could benefit from the specialist knowledge that recently graduated PhD students could bring to their business. Recognising this, UCL Advances (the centre for entrepreneurship and business at UCL manages a Knowledge Exchange Associate (KEA scheme whereby exiting PhD students are hosted by businesses. Each KEA acts as a conduit for the transfer of knowledge from UCL to industry, with projects tailored to meet the needs of each business. In return KEA’s are provided with challenging and creative project management experience and formal business training (UCL Advances, 2013.

  16. Online Resistance to Precarious Archaeological Labour

    Directory of Open Access Journals (Sweden)

    Sam Hardy

    2015-05-01

    Full Text Available The international cultural heritage economy has long been underpinned by a reserve army of unemployed/underemployed labour. The entry-level workforce is being further undermined and unpaid/underpaid labour is additionally being consolidated through the crisis and austerity measures. Independently and under different pressures, archaeologists across Europe have begun to use blogging, micro-blogging and other social media in concerted national efforts to document, analyse and resist exploitative and exclusive employment practices. This article focuses on the development of movements against unpaid labour (free archaeology in the UK, against unpaid and underpaid internship (volontariato and stage in Italy, and for employment (istihdam in Turkey. Using insights gained through observing and participating in these movements, and through running a research blog on precarious labour in the cultural heritage industry, this article examines the benefits and limits of blogging/micro-blogging as a tool for debate within the profession, communication with the public, and activism.

  17. Distant Neighbours: Different Visions about Mexican Archaeology

    Directory of Open Access Journals (Sweden)

    Luis Gómez Gastélum

    2014-05-01

    Full Text Available In 1972, Mexican archaeology experienced a major transformation due to the enactment of a Federal Law about archaeological, artistic, and historical monuments and zones, which changed the Mexican Government’s administration of Mexican archaeological heritage. In 1972, in West Mexico, an active group of archaeologists from the U.S.A. was working. They came from several universities and were also members of an academic association, the West Mexican Society for Advanced Study, that was based in Ajijic, Mexico, and comprised both U.S. and Mexican archaeologists. This group wrote to the government about their views of the new laws, and the government department concerned with their implementation, the Mexican National Institute of Anthropology and History (INAH – Instituto Nacional de Antropología e Historia, then responded with the Mexican Government’s official standpoint. In this paper, we analyze the positions of the West Mexican Society for Advanced Study, and INAH. We observe the sociopolitical and academic contexts from both U.S. and Mexican perspectives, and we offer explanations about their opposing views. We consider this episode to be a manifestation of the ideas circulating between U.S. and Mexican archaeologies.En 1972 la arqueología mexicana tuvo un cambio radical. En ese año fue promulgada la Ley Federal de Monumentos y Zonas Arqueológicos, Artísticos e Históricos. Esta ley cambió la manera en que el gobierno mexicano administraba el patrimonio arqueológico nacional. En dicho año, en el occidente de México, estuvo trabajando un grupo muy activo de arqueólogos estadounidenses, que si bien procedían de diversas universidades, también fueron miembros de una institución académica. La Sociedad de Estudios Avanzados del Occidente de México, con sede en Ajijic, México, reunió tanto a arquéologos estadounidenses como mexicanos. Los primeros escribieron un documento que contenía sus opiniones sobre la nueva ley y lo

  18. PRINCELY HALYCH: INTRIGUING PROSPECTS FOR ARCHAEOLOGICAL RESEARCH

    Directory of Open Access Journals (Sweden)

    Ihor Koval

    2015-05-01

    Full Text Available According to statistical data, permanent and local archaeological researches have covered only about ten per cent of the territory of Princely Halych, which opens up endless possibilities for research at the site of the ancient city. The chapter highlights the importance of the scientific and popular works by Antin Petrushevych, Lev Lavretskyi and Izydor Sharanevych, who in 1882 initiated the archaeological research on the mighty Principality of Halych (Galicia and its capital, and the excavation of the first Christian church in Halych – the Church of the Holy Saviour mentioned in the Kyivan Chronicle. The little-known works of these scientists, which were published in Lviv newspapers in the 1880s, clearly show that Lavretskyi and Sharanevych’s findings received international acclaim and were a significant factor in rousing national consciousness and stimulating social activity of the Galician Ukrainians. It is difficult to explain the lack of interest in carrying out excavations outside the perimeter of the foundations of the Church, which could have enhanced the social, historical, topographical analysis of the monument and its surroundings. A particular fact that proves the importance of such research is the discovery of pendant seals, which modern sphragistics attributes to Prince Volodymyrko Volodarevych (1141-1153.  This conclusion is in good agreement with the Kyivan Chronicle and the findings of the archaeologists who excavated the Church of the Holy Saviour. All these facts provide grounds for the hypothesis concerning the location of the State Chancellery and the mysterious Palace of the 12th century Lords of Galicia.

  19. Contribution of archaeological analogs to the estimation of average corrosion rates and long term corrosion mechanisms of low carbon steel in soil; Apport des analogues archeologiques a l'estimation des vitesses moyennes et a l'etude des mecanismes de corrosion a tres long terme des aciers non allies dans les sols

    Energy Technology Data Exchange (ETDEWEB)

    Neff, D

    2003-11-15

    In the context of the French nuclear waste storage, a multi-barriers disposal is envisaged. Wastes could be put in metallic overpacks disposed in a clay soil. As these overpacks could be made of low carbon steel, it is important to understand the corrosion behaviour of this material in soil during period of several centuries. Indeed, it is necessary to consolidate the empirical data by a phenomenological approach. This includes laboratory experiments and modelling of the phenomenon which have to be validated and completed by the study of archaeological artefacts. This was the aim of this PhD-work. To this purpose, an analytical protocol has been elaborated: about forty archaeological artefacts coming from five dated sites (2. to 16. centuries) have been studied on cross section in order to observe on the same sample all the constituents of the system: metallic substrate/corrosion products/environment. The corrosion products are divided into two zones: the Dense Product Layer (DPL) in contact with the metal, and the Transformed Medium (TM) which are the corrosion products formed around soil minerals (quartz grains). The metallic substrate has been studied by the classical methods of materials science (optical and scanning electron microscope, energy and wavelength dispersive spectroscopies). It has been verified that despite their heterogeneity of structure and composition, they are all hypo-eutectoids steels that can contain phosphorous until 0.5 wt%. The corrosion products have been analysed by local structural analytical methods as micro-diffraction under synchrotron radiation ({mu}XRD) and Raman micro-spectroscopy. These two complementary techniques and also the elemental composition analysis conducted to the characterisation of the corrosion forms. On the majority of the samples coming from four sites, the DPL are constituted by goethite including marbles of magnetite/maghemite. On the artefacts from the fifth site, a particular corrosion form has been

  20. River archaeology - a new tool for historical hydrology

    Energy Technology Data Exchange (ETDEWEB)

    Toth, Attila J [National Office of Cultural Heritage, Budapest (Hungary)], E-mail: attila.toth@koh.hu

    2008-11-01

    River archaeology consists of underwater research on the rivers themselves. It is also concerned with the archaeology of the valleys/floodplains with special attention to human-environmental interactions (reconstructing landscape, the environment, economy and society from material culture and traces of human impact on their surroundings). As historical hydrology is concerned with similar questions, from the hydrologist's point of view, the combination of different approaches offers the possibilities for fruitful cooperation for both disciplines. The intent of this paper is to present the type, nature and limitations of this part of the archaeological record through recent work in the Drava River basin.

  1. Assessing chemistry schemes and constraints in air quality models used to predict ozone in London against the detailed Master Chemical Mechanism.

    Science.gov (United States)

    Malkin, Tamsin L; Heard, Dwayne E; Hood, Christina; Stocker, Jenny; Carruthers, David; MacKenzie, Ian A; Doherty, Ruth M; Vieno, Massimo; Lee, James; Kleffmann, Jörg; Laufs, Sebastian; Whalley, Lisa K

    2016-07-18

    Air pollution is the environmental factor with the greatest impact on human health in Europe. Understanding the key processes driving air quality across the relevant spatial scales, especially during pollution exceedances and episodes, is essential to provide effective predictions for both policymakers and the public. It is particularly important for policy regulators to understand the drivers of local air quality that can be regulated by national policies versus the contribution from regional pollution transported from mainland Europe or elsewhere. One of the main objectives of the Coupled Urban and Regional processes: Effects on AIR quality (CUREAIR) project is to determine local and regional contributions to ozone events. A detailed zero-dimensional (0-D) box model run with the Master Chemical Mechanism (MCMv3.2) is used as the benchmark model against which the less explicit chemistry mechanisms of the Generic Reaction Set (GRS) and the Common Representative Intermediates (CRIv2-R5) schemes are evaluated. GRS and CRI are used by the Atmospheric Dispersion Modelling System (ADMS-Urban) and the regional chemistry transport model EMEP4UK, respectively. The MCM model uses a near-explicit chemical scheme for the oxidation of volatile organic compounds (VOCs) and is constrained to observations of VOCs, NOx, CO, HONO (nitrous acid), photolysis frequencies and meteorological parameters measured during the ClearfLo (Clean Air for London) campaign. The sensitivity of the less explicit chemistry schemes to different model inputs has been investigated: Constraining GRS to the total VOC observed during ClearfLo as opposed to VOC derived from ADMS-Urban dispersion calculations, including emissions and background concentrations, led to a significant increase (674% during winter) in modelled ozone. The inclusion of HONO chemistry in this mechanism, particularly during wintertime when other radical sources are limited, led to substantial increases in the ozone levels predicted

  2. Assessing chemistry schemes and constraints in air quality models used to predict ozone in London against the detailed Master Chemical Mechanism.

    Science.gov (United States)

    Malkin, Tamsin L; Heard, Dwayne E; Hood, Christina; Stocker, Jenny; Carruthers, David; MacKenzie, Ian A; Doherty, Ruth M; Vieno, Massimo; Lee, James; Kleffmann, Jörg; Laufs, Sebastian; Whalley, Lisa K

    2016-07-18

    Air pollution is the environmental factor with the greatest impact on human health in Europe. Understanding the key processes driving air quality across the relevant spatial scales, especially during pollution exceedances and episodes, is essential to provide effective predictions for both policymakers and the public. It is particularly important for policy regulators to understand the drivers of local air quality that can be regulated by national policies versus the contribution from regional pollution transported from mainland Europe or elsewhere. One of the main objectives of the Coupled Urban and Regional processes: Effects on AIR quality (CUREAIR) project is to determine local and regional contributions to ozone events. A detailed zero-dimensional (0-D) box model run with the Master Chemical Mechanism (MCMv3.2) is used as the benchmark model against which the less explicit chemistry mechanisms of the Generic Reaction Set (GRS) and the Common Representative Intermediates (CRIv2-R5) schemes are evaluated. GRS and CRI are used by the Atmospheric Dispersion Modelling System (ADMS-Urban) and the regional chemistry transport model EMEP4UK, respectively. The MCM model uses a near-explicit chemical scheme for the oxidation of volatile organic compounds (VOCs) and is constrained to observations of VOCs, NOx, CO, HONO (nitrous acid), photolysis frequencies and meteorological parameters measured during the ClearfLo (Clean Air for London) campaign. The sensitivity of the less explicit chemistry schemes to different model inputs has been investigated: Constraining GRS to the total VOC observed during ClearfLo as opposed to VOC derived from ADMS-Urban dispersion calculations, including emissions and background concentrations, led to a significant increase (674% during winter) in modelled ozone. The inclusion of HONO chemistry in this mechanism, particularly during wintertime when other radical sources are limited, led to substantial increases in the ozone levels predicted

  3. Resin Systems and Chemistry-Degradation Mechanisms and Durability in Long-Term Durability of Polymeric Matrix Composites. Chapter 1

    Science.gov (United States)

    Hinkley, Jeffrey A.; Connell, John W.

    2012-01-01

    In choosing a polymer-matrix composite material for a particular application, a number of factors need to be weighed. Among these are mechanical requirements, fabrication method (e.g. press-molding, resin infusion, filament winding, tape layup), and use conditions. Primary among the environmental exposures encountered in aerospace structures are moisture and elevated temperatures, but certain applications may require resistance to other fluids and solvents, alkaline agents, thermal cycling, radiation, or rapid, localized heating (for example, lightning strike). In this chapter, the main classes of polymer resin systems found in aerospace composites will be discussed. Within each class, their responses to environmental factors and the associated degradation mechanisms will be reviewed.

  4. Good chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    The subject matter in chemistry courses reflects almost nothing of the issues that chemists are interested in. It is important to formulate a set of topics - and a Medical College Admissions Test reflecting them - that would leave chemistry departments no choice but to change their teaching.

  5. Cambridge Illustrated History of Archaeology, edited by Paul G. Bahn, Cambridge University Press, New York, 1996

    OpenAIRE

    Douglas R. Givens

    1997-01-01

    The Cambridge Illustrated History of Archaeology is another in a series of volumes devoted to the history of archaeology that have appeared in recent time. Paul Bahn, the editor of the volume, has broken down his coverage of the history of worldwide archaeology into the following arrangement 'The Archaeology of Archaeology", "Old Worlds and New, 1500-1760", "Antiquarians and Explorers, 1760-1820", "Science and Romantic...

  6. Shipwreck archaeology of the Lakshadweep Islands, west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Tripati, S.; Gudigar, P.

    Archaeological investigations in the Lakshadweep Islands have brought to light the presence of a large number of shipwrecks and the archival records have the details of some of these wrecks. Northern islands and reefs of Minicoy were the locations...

  7. Ancient Dwarka: Study based on recent underwater archaeological investigations

    Digital Repository Service at National Institute of Oceanography (India)

    Gaur, A.S.; Sundaresh; Tripati, S.

    , the Lord Krishna founded the holy city of Dwarka, which subsequently got submerged under sea. Marine archaeological explorations off Dwarka have brought to light a large number of stone structures, which are semicircular, rectangular and square in shape...

  8. Position fixing and surveying techniques for marine archaeological studies

    Digital Repository Service at National Institute of Oceanography (India)

    Ganesan, P.

    tools available for major and small archaeological studies. Various suggessions are being given in this report in measuring distances underwater of artifact, measurement of depth and a method to get the azimuth of the baseline control network, so...

  9. Application of acoustic, magnetic and electromagnetic systems in marine archaeology

    Digital Repository Service at National Institute of Oceanography (India)

    SubbaRaju, L.V.

    The importance of integrated geoscientific studies is reiterated for underwater archaeological exploration. Geophysical systems applied for the detection of artefacts, ancient places and underwater sites/objects are explained and detailed...

  10. Biomimetic hydroxyapatite as a new consolidating agent for archaeological bone

    Science.gov (United States)

    North, Alexis E.

    Recent studies on calcareous stone and plaster consolidation have demonstrated considerable potential by bio-mimicking the growth of hydroxyapatite (HAP), the main mineralogical constituent of teeth and bone matrix. These initial conservation applications, together with significant fundamental research on the precipitation of HAP for bioengineering and biomedical applications, offer great promise in the use of HAP as a consolidating agent for archaeological bone and other similar materials such as archaeological teeth, ivory, and antler. Experimental research via the controlled application of diammonium phosphate (DAP) precursors to bone flour, modern bone samples, and archaeological bones, indicated the in situ formation of HAP with a simultaneous increase in the cohesiveness of friable bone material, while preserving the bone's physiochemical properties. These preliminary results point towards a promising new method in archaeological conservation.

  11. Alchemy or Science? Compromising Archaeology in the Deep Sea

    Science.gov (United States)

    Adams, Jonathan

    2007-06-01

    In the torrid debate between archaeology and treasure hunting, compromise is often suggested as the pragmatic solution, especially for archaeology carried out either in deep water or beyond the constraints that commonly regulate such activities in territorial seas. Both the wisdom and the need for such compromise have even been advocated by some archaeologists, particularly in forums such as the internet and conferences. This paper argues that such a compromise is impossible, not in order to fuel confrontation but simply because of the nature of any academic discipline. We can define what archaeology is in terms of its aims, theories, methods and ethics, so combining it with an activity founded on opposing principles must transform it into something else. The way forward for archaeology in the deep sea does not lie in a contradictory realignment of archaeology’s goals but in collaborative research designed to mesh with emerging national and regional research and management plans.

  12. The active Nea Anchialos Fault System (Central Greece: comparison of geological, morphotectonic, archaeological and seismological data

    Directory of Open Access Journals (Sweden)

    R. Caputo

    1996-06-01

    Full Text Available The Nea Anchialos Fault System has been studied integrating geological, morphological, structural, archaeological and seismic data. This fault system forms the northern boundary of the Almyros Basin which is one of the Neogene-Quaternary tectonic basins of Thessaly. Specific structural and geomorphological mapping were carried out and fault-slip data analysis allowed the Late Quaternary palaeo-stress field to be estimated. The resulting N-S trending purely extensional regime is consistent with the direction of the T-axes computed from the focal mechanisms of the summer 1980, Volos seismic sequence and the April 30, 1985 Almyros earthquake. A minor set of structural data indicates a WNW-ESE extension which has been interpreted as due to a local and second order stress field occurring during the N-S regional extension. Furthermore, new archaeological data, discovered by the author, have improved morphology and tectonics of the area also allowing a tentative estimate of the historic (III-IV century AD. to Present fault slip rate. Several topographic profiles across the major E- W topographic escarpment as well as along the streams, have emphasised scarps and knick-points, further supporting the occurrence of very recent morphogenic activity. In the last section, the structural, morphological and archaeological data are compared with the already existing seismological data and their integrated analysis indicates that the Nea Anchialos Fault System has been active since Lower(?-Middle Pleistocene.

  13. Nuclear analytical technique for the study of ancient pottery from a Ghanaian archaeological site

    International Nuclear Information System (INIS)

    Instrumental Neutron Activation Analysis (INAA) was utilized to determine the elemental concentrations of the archaeological pottery samples from Jenini slave camp in the Brong Ahafo Region, Ghana, employing the 30kW tank-in-pool Miniature Neutron Source Reactor (MNSR) at the Ghana Atomic Energy Commission (GAEC). Jenini was a slave camp of Samory Toure during the indigenous slavery and the Trans-Atlantic slave trade. The samples were obtained during the excavations of the tombs of the slaves who died at the camp. The accuracy of the INAA method was evaluated using IAEA Soil-7 reference material. The precision was calculated as relative standard deviation and was found to be within ±10%. Thirty-two (32) ceramic fragment samples from the archaeological site were analyzed to determine the concentration of 20 elements: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, La, Mn, Na, Sc, Sm,Th, U, and V. Two multivariate statistical methods, cluster and factor analyses, were performed on the data set in order to determine similarities and correlations between the various samples. The results of the cluster and factor analyses indicate a considerable overlap in the chemistry of the pottery shards from the three sampling points (i.e. Trench 1, Trench 2 and Pit 1) indicating that the pot shards were made from a single type of clay or clays of similar geochemical signatures. (au)

  14. Archaeological obsidian from La Sierra Gorda Mexico, by PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Juarez-Cossio, D.; Terreros, E.; Quiroz-Moreno, J.; Romero-Sanchez, S. [Instituto Nacional de Antropologia e Historia, Mexico. Seminario 8, Col. Centro. 06060 Mexico, DF (Mexico); Calligaro, T.F. [Centre de Recherche et de Restauration des Musees de France, UMR 171, Palais du Louvre-Porte des Lions, 14, Quai Francois Mitterrand, 75001 Paris (France); Tenorio, D. [Instituto Nacional de Investigaciones Nucleares, Apdo. Postal 18-1027, 11801 Mexico, DF (Mexico)], E-mail: dolores.tenorio@inin.gob.mx; Jimenez-Reyes, M. [Instituto Nacional de Investigaciones Nucleares, Apdo. Postal 18-1027, 11801 Mexico, DF (Mexico); Los Rios, M. de [Instituto Nacional de Antropologia e Historia, Mexico. Seminario 8, Col. Centro. 06060 Mexico, DF (Mexico)

    2009-04-15

    The chemical compositions of 42 obsidian pre-Hispanic artifacts from Tancama and Purisima, both archaeological sites of La Sierra Gorda Valleys, Mexico, were analyzed by PIXE technique. These obsidians came from four sources: Sierra de Pachuca Hidalgo, Paraiso Queretaro, Ucareo Michoacan and mainly from Zacualtipan/Metzquititlan Hidalgo. According to archaeological evidences, La Sierra Gorda valleys participated in commercial exchange with other regional sites, from Classic to Post-classic periods (A.D. 300-1500)

  15. Archaeological maps: methods and techniques for territorial analysis

    OpenAIRE

    Rocha, Leonor; Branco, Gertrudes

    2011-01-01

    Archaeological maps are, by definition, a tool for the management of the cultural heritage, planning and urban development, and are drawn up on the basis of existing studies and recent fieldwork, covering all the latest data. In Portugal, the idea of creating a national archaeological map was developed, for the first time, in the 1970s. However, several attempts to organize such amount of information have been offset by two major problems: the difficulty of mapping such a large area, and the ...

  16. Asphalt in carbon-14-dated archaeological samples from Terqa, Syria

    International Nuclear Information System (INIS)

    The results are reported of an organic geochemical study to verify contamination in 14C dated archaeological samples, which could account for much older apparent ages than expected. The data indicate that ancient asphalt must be the source of contamination, showing that caution should be exercised, in interpreting 14C dates of archaeological samples from areas containing asphalt or other fossil fuel deposits. (U.K.)

  17. A Review of 'The Oxford Handbook of Mesoamerican Archaeology'

    Directory of Open Access Journals (Sweden)

    Agathe Dupeyron

    2013-10-01

    Full Text Available 'The Oxford Handbook of Mesoamerican Archaeology' is intended to be a showcase of the discipline’s recent developments and provide a comprehensive - but non-exhaustive - overview of early 21st century work in the region. It is probably one of the most ambitious such projects since the sixteen volume series 'Handbook of Middle American Indians' published in the 1960s. It is primarily intended for professionals and students of Mesoamerican archaeology.

  18. UAV Systems for Photogrammetric Data Acquisition of Archaeological Sites

    OpenAIRE

    Lo Brutto, M.; Borruso, A.; D'Argenio, A.

    2012-01-01

    The use of UAV systems for surveying archaeological sites is becoming progressively more common due to the considerable potential in terms of rapidity of survey, costs and accuracy. The paper presents the first results of the photogrammetric survey of the archaeological site of Himera in Sicily (Italy) using by UAV systems. A complete documentation of the site through the production of a DSM and an ortho image were carried out. The research further evaluated two different image processing wor...

  19. Introductory quantum chemistry

    International Nuclear Information System (INIS)

    This book on quantum chemistry is primarily intended for university students at the senior undergraduate level. It serves as an aid to the basic understanding of the important concepts of quantum mechanics introduced in the field of chemistry. Various chapters of the book are devoted to the following : (i) Waves and quanta, (ii) Operator concept in quantum chemistry, (iii) Wave mechanics of some simple systems, (iv) Perturbation theory, (v) Many-electron atoms and angular momenta (vi) Molecular orbital theory and its application to the electronic structure of diatomic molecules, (vii) Chemical bonding in polyatomic molecules and (viii) Chemical applications of Hellmann-Feynman theorem. At the end of each chapter, a set of problems is given and the answers to these problems are given at the end of the book. (A.K.)

  20. Incorporating a Product Archaeology Paradigm across the Mechanical Engineering Curriculum

    Science.gov (United States)

    Moore-Russo, Deborah; Cormier, Phillip; Lewis, Kemper; Devendorf, Erich

    2013-01-01

    Historically, the teaching of design theory in an engineering curriculum has been relegated to a senior capstone design experience. Presently, however, engineering design concepts and courses can be found through the entirety of most engineering programs. Educators have recognized that engineering design provides a foundational platform that can…

  1. Quantum chemistry

    CERN Document Server

    Lowe, John P

    1993-01-01

    Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom,

  2. ArchaeoGRID, the Archaeology on the e-Infrastructures

    Energy Technology Data Exchange (ETDEWEB)

    Pelfer, G.; Cechini, R.; Pelfer, P. G.; Politi, A.

    2007-07-01

    It is well known that in archaeology large use is done of digital technologies and computer applications for data acquisition, storage, analysis and visualization. The approach of modern archaeology to the study of the evolution of ancient human societies is based on the acquisition and analysis of many types of data. The amount of information coming from the archaeology and the other connected sciences and human ties that need to be stored and made available for analysis are increasing at a very large extent. Such data must, however, be analyzed if they are to become valuable information and knowledge. The data analysis use advanced methods developed in mathematics, informatics, physics, geology, biology, ecology, anthropology and in other natural and human sciences. The inevitable result of this is an exponential increase of the amount and complexity of information that must be acquired, transferred, stored, processed and analyzed. From another, side natural disasters, wars and terrorism created enormous damages to the archaeological heritage and in many case destroyed definitively all information about ancient civilizations. It is urgent a long term project for acquiring, storing and preserving at least the archaeological information. The paper presents the EGEE- II ArchaeoGRID project that, using GRID technologies developed at CERN and in other laboratories, is developing a grid able to fit the very challenging requests of contemporary archaeology. (Author)

  3. A History of NASA Remote Sensing Contributions to Archaeology

    Science.gov (United States)

    Giardino, Marco J.

    2010-01-01

    During its long history of developing and deploying remote sensing instruments, NASA has provided a scientific data that have benefitted a variety of scientific applications among them archaeology. Multispectral and hyperspectral instrument mounted on orbiting and suborbital platforms have provided new and important information for the discovery, delineation and analysis of archaeological sites worldwide. Since the early 1970s, several of the ten NASA centers have collaborated with archaeologists to refine and validate the use of active and passive remote sensing for archeological use. The Stennis Space Center (SSC), located in Mississippi USA has been the NASA leader in archeological research. Together with colleagues from Goddard Space Flight Center (GSFC), Marshall Space Flight Center (MSFC), and the Jet Propulsion Laboratory (JPL), SSC scientists have provided the archaeological community with useful images and sophisticated processing that have pushed the technological frontiers of archaeological research and applications. Successful projects include identifying prehistoric roads in Chaco canyon, identifying sites from the Lewis and Clark Corps of Discovery exploration and assessing prehistoric settlement patterns in southeast Louisiana. The Scientific Data Purchase (SDP) stimulated commercial companies to collect archaeological data. At present, NASA formally solicits "space archaeology" proposals through its Earth Science Directorate and continues to assist archaeologists and cultural resource managers in doing their work more efficiently and effectively. This paper focuses on passive remote sensing and does not consider the significant contributions made by NASA active sensors. Hyperspectral data offers new opportunities for future archeological discoveries.

  4. Rethinking Undergraduate Physical Chemistry Curricula

    Science.gov (United States)

    Miller, Stephen R.

    2016-01-01

    A summary of fundamental changes made to the undergraduate physical chemistry curriculum in the Chemistry Department at Gustavus Adolphus College (beginning in the 2013-2014 academic year) is presented. The yearlong sequence now consists of an introductory semester covering both quantum mechanics and thermodynamics/kinetics, followed by a second…

  5. Influence of nanometer scale film structure of ZDDP tribofilm on Its mechanical properties: A computational chemistry study

    Energy Technology Data Exchange (ETDEWEB)

    Onodera, Tasuku; Kuriaki, Takanori; Morita, Yusuke [Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Suzuki, Ai [New Industry Creation Hatchery Center, Tohoku University, 6-6-10 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Koyama, Michihisa [Department of Chemical Engineering, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Tsuboi, Hideyuki; Hatakeyama, Nozomu; Endou, Akira [Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Takaba, Hiromitsu [Department of Chemical Engineering, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Del Carpio, Carlos A. [Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Kubo, Momoji [Fracture and Reliability Research Institute, Graduate School of Engineering, Tohoku University, 6-6-11-701 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Minfray, Clotilde; Martin, Jean-Michel [Laboratory of Tribology and Dynamical Systems, Ecole Centrale de Lyon, 36, avenue Guy de Collongue 69134, ECULLY Cedex (France); Miyamoto, Akira, E-mail: miyamoto@aki.che.tohoku.ac.jp [Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); New Industry Creation Hatchery Center, Tohoku University, 6-6-10 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Department of Chemical Engineering, Graduate School of Engineering, Tohoku University, 6-6-11-1302 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan)

    2009-11-30

    We investigated the influence of a nanometer scale film structure of a tribofilm generated from zinc dialkyldithiophosphate (ZDDP) anti-wear additive on its mechanical properties using a combined molecular dynamics (MD) and finite element (FE) method. The frictional behavior of an interface between a native iron oxide layer on steel surface and zinc metaphosphate - regarded as a model material of ZDDP tribofilm - was firstly studied using the MD method. The results showed that the iron atoms in the oxide layer diffused into the phosphate layer during the friction process. The zinc atoms in the phosphate layer also diffused into the oxide layer. Significant interdiffusion of iron and zinc atoms was observed with increasing simulation time. Thus, metallic phosphate with a gradient composition of iron and zinc atoms was formed on the phosphate/oxide interface. We then constructed an axisymmetric nanoindentation simulation model from the MD-derived structures at a certain simulation time and carried out a FE calculation. As a result, we found that the rubbed ZDDP tribofilm, including the phosphate with the gradient composition of metallic atoms, showed larger contact stiffness and hardness. The combined MD/FE simulation indicates that the tribofilm becomes stiffer and harder due to the interdiffusion of iron and zinc atoms on the tribofilm/oxide interface. We have found that the gradient composition formation in ZDDP tribofilm during friction process influences on its mechanical properties.

  6. Influence of nanometer scale film structure of ZDDP tribofilm on Its mechanical properties: A computational chemistry study

    International Nuclear Information System (INIS)

    We investigated the influence of a nanometer scale film structure of a tribofilm generated from zinc dialkyldithiophosphate (ZDDP) anti-wear additive on its mechanical properties using a combined molecular dynamics (MD) and finite element (FE) method. The frictional behavior of an interface between a native iron oxide layer on steel surface and zinc metaphosphate - regarded as a model material of ZDDP tribofilm - was firstly studied using the MD method. The results showed that the iron atoms in the oxide layer diffused into the phosphate layer during the friction process. The zinc atoms in the phosphate layer also diffused into the oxide layer. Significant interdiffusion of iron and zinc atoms was observed with increasing simulation time. Thus, metallic phosphate with a gradient composition of iron and zinc atoms was formed on the phosphate/oxide interface. We then constructed an axisymmetric nanoindentation simulation model from the MD-derived structures at a certain simulation time and carried out a FE calculation. As a result, we found that the rubbed ZDDP tribofilm, including the phosphate with the gradient composition of metallic atoms, showed larger contact stiffness and hardness. The combined MD/FE simulation indicates that the tribofilm becomes stiffer and harder due to the interdiffusion of iron and zinc atoms on the tribofilm/oxide interface. We have found that the gradient composition formation in ZDDP tribofilm during friction process influences on its mechanical properties.

  7. Trace Chemistry

    Science.gov (United States)

    Radhakrishnan, Krishnan; Whitefield, Philip

    1999-01-01

    , in addition, of the pressure, temperature, and velocity. A near term goal of the experimental program should be to confirm the nonlinear effects of sulfur speciation, and if present, to provide an explanation for them. It is also desirable to examine if the particulate matter retains any sulfur. The recommendation is to examine the effects on SOx production of variations in fuel-bound sulfur and aromatic content (which may affect the amount of particulates formed). These experiments should help us to understand if there is a coupling between particulate formation and SO, concentration. Similarly, any coupling with NOx can be examined either by introducing NOx into the combustion air or by using fuel-bound nitrogen. Also of immediate urgency is the need to establish and validate a detailed mechanism for sulfur oxidation/aerosol formation, whose chemistry is concluded to be homogeneous, because there is not enough surface area for heterogeneous effects. It is envisaged that this work will involve both experimental and theoretical programs. The experimental work will require, in addition to the measurements described above, fundamental studies in devices such as flow reactors and shock tubes. Complementing this effort should be modeling and theoretical activities. One impediment to the successful modeling of sulfur oxidation is the lack of reliable data for thermodynamic and transport properties for several species, such as aqueous nitric acid, sulfur oxides, and sulfuric acid. Quantum mechanical calculations are recommended as a convenient means of deriving values for these properties. Such calculations would also help establish rate constants for several important reactions for which experimental measurements are inherently fraught with uncertainty. Efforts to implement sufficiently detailed chemistry into computational fluid dynamic codes should be continued. Zero- and one-dimensional flow models are also useful vehicles for elucidating the minimal set of species and

  8. Modern analytic methods applied to the art and archaeology; Metodos analiticos modernos aplicados al arte y la arqueologia

    Energy Technology Data Exchange (ETDEWEB)

    Tenorio C, M. D.; Longoria G, L. C., E-mail: dolores.tenorio@inin.gob.m [ININ, Departamento de Quimica, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2010-07-01

    The interaction of diverse areas as the analytic chemistry, the history of the art and the archaeology has allowed the development of a variety of techniques used in archaeology, in conservation and restoration. These methods have been used to date objects, to determine the origin of the old materials and to reconstruct their use and to identify the degradation processes that affect the integrity of the art works. The objective of this chapter is to offer a general vision on the researches that have been realized in the Instituto Nacional de Investigaciones Nucleares (ININ) in the field of cultural goods. A series of researches carried out in collaboration with national investigators and of the foreigner is described shortly, as well as with the great support of degree students and master in archaeology of the National School of Anthropology and History, since one of the goals that have is to diffuse the knowledge of the existence of these techniques among the young archaeologists, so that they have a wider vision of what they could use in an in mediate future and they can check hypothesis with scientific methods. (Author)

  9. NASA Remote Sensing Applications for Archaeology and Cultural Resources Management

    Science.gov (United States)

    Giardino, Marco J.

    2008-01-01

    NASA's Earth Science Mission Directorate recently completed the deployment of the Earth Observation System (EOS) which is a coordinated series of polar-orbiting and low inclination satellites for long-term global observations of the land surface, biosphere, solid Earth, atmosphere, and oceans. One of the many applications derived from EOS is the advancement of archaeological research and applications. Using satellites, manned and unmanned airborne platform, NASA scientists and their partners have conducted archaeological research using both active and passive sensors. The NASA Stennis Space Center (SSC) located in south Mississippi, near New Orleans, has been a leader in space archaeology since the mid-1970s. Remote sensing is useful in a wide range of archaeological research applications from landscape classification and predictive modeling to site discovery and mapping. Remote sensing technology and image analysis are currently undergoing a profound shift in emphasis from broad classification to detection, identification and condition of specific materials, both organic and inorganic. In the last few years, remote sensing platforms have grown increasingly capable and sophisticated. Sensors currently in use, including commercial instruments, offer significantly improved spatial and spectral resolutions. Paired with new techniques of image analysis, this technology provides for the direct detection of archaeological sites. As in all archaeological research, the application of remote sensing to archaeology requires a priori development of specific research designs and objectives. Initially targeted at broad archaeological issues, NASA space archaeology has progressed toward developing practical applications for cultural resources management (CRM). These efforts culminated with the Biloxi Workshop held by NASA and the University of Mississippi in 2002. The workshop and resulting publication specifically address the requirements of cultural resource managers through

  10. Constraining the primordial initial mass function with stellar archaeology

    CERN Document Server

    Hartwig, Tilman; Klessen, Ralf S; Glover, Simon C O

    2014-01-01

    We present a new near-field cosmological probe of the initial mass function (IMF) of the first stars. Specifically, we constrain the lower-mass limit of the Population III (Pop III) IMF with the total number of stars in large, unbiased surveys of the Milky Way bulge and halo. We model the early star formation history in a Milky-Way like halo with a semi-analytic approach, based on Monte-Carlo sampling of dark matter merger trees, combined with a treatment of the most important feedback mechanisms, such as stellar radiation and metal enrichment. Assuming a logarithmically flat Pop III IMF and varying its low mass limit, we derive the number of expected survivors of these first stars, using them to estimate the probability to detect any such Pop III fossil in stellar archaeological surveys. Our model parameters are calibrated with existing empirical constraints, such as the optical depth to Thomson scattering. Following our analysis, the most promising region to find possible Pop III survivors is the stellar ha...

  11. Special report: a century of chemistry. History of sciences: Max Planck and the birth of quantum mechanics

    International Nuclear Information System (INIS)

    In 1892 Lord Kelvin said 'that the fundamental concepts of physics had been established'. However, quantum mechanics in 1900, and relativity in 1905 were going to profoundly upset this science. Jean-Claude Boudenot allows us to relive the essential discoveries, which have given rise to the majority of the technologies of the 20. century through the life of Max Planck (1858-1947). The first scientific hit of M.Planck was to solve the problem of the black body at the turn of last century, he postulated that the exchange of energy between radiation and the walls of the cavity had the form of a flow of very small and indivisible quantities of energy called energy quantum. This discovery allowed him to receive the Nobel prize of physics in 1918

  12. Effect of Y220C mutation on p53 and its rescue mechanism: a computer chemistry approach.

    Science.gov (United States)

    Rauf, Shah Md Abdur; Endou, Akira; Takaba, Hiromitsu; Miyamoto, Akira

    2013-01-01

    Mutation causes inactivation of 'p53' tumor suppressor protein in almost fifty percent of cancers in humans. Outside the DNA-binding surface of p53, Y220C is the most common cancerous mutation. Previous studies have shown that a surface cavity is created by this mutation which destabilizes p53. PhiKan083, a carbazole derivative capable of binding with that cavity, and slows down its thermal denaturation rate. We investigated, theoretically, on mechanisms of structural stability loss due to Y220C mutation and mechanisms of stability restoration by PhiKan083 at the atomic level. From this study it is found that in Tp53C, Tyr220 has five electrostatic interactions with residues Val 147, Prol51, Pro153 and Pro223 located on S3/S4 loop and S7/S8 loop. The S7/S8 loop is stabilized by these electrostatic interactions. Due to the Y220C mutation all these electrostatic interactions are lost. As a result the structural fluctuation occurs at S7/S8 loop, and the loop is displaced from its original position after 6 ns MD simulation. When PhiKan083 is present (inserted) at the mutation site it provides five electrostatic interactions with Pro155, Glu221 and Thr230, and two hydrogen bonds with Leu145 and Asp228, respectively. These interactions provided by Pkikan083 stabilized the S7/S8 loop, and as a result it couldn't be displaced. Our results showed that due to Y220C mutation p53 became destabilized through structural fluctuations surrounding the mutation site. When PhiKan083 is present at the Y220C mutation site (in 2vuk), it provides electrostatic and hydrogen bonding interactions among residue-220, its neighboring residues and PhiKan08. These interactions give additional stability to Y220C mutant p53, thus Y220C mutant p53 doesn't destabilize.

  13. Archaeological culture, please meet yoghurt culture: towards a relational archaeology of milk

    Directory of Open Access Journals (Sweden)

    Dimitrij Mlekuž

    2015-12-01

    Full Text Available Taking milk as a point of departure, we set out on a journey to explore the ‘mutual becomings’ of different bodies, species, and things. We argue that milk should be understood as a component in an assemblage that connects animals, humans, hormones, enzymes, bacteria, food, genes, technologies and material culture. These complex entanglements produced new, unexpected results and effects. Since they form part of this assemblage, all its components are profoundly changed. Focusing on this diversity of relations between humans, other creatures, things and substances is a key to an archaeology that does not radically separate humans and nonhumans.

  14. Materials Chemistry

    CERN Document Server

    Fahlman, Bradley D

    2011-01-01

    The 2nd edition of Materials Chemistry builds on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field. The 2nd edition continues to offer innovative coverage and practical perspective throughout. After briefly defining materials chemistry and its history, seven chapters discuss solid-state chemistry, metals, semiconducting materials, organic "soft" materials, nanomaterials, and materials characterization. All chapters have been thoroughly updated and expanded with, for example, new sections on ‘soft lithographic’ patterning, ‘click chemistry’ polymerization, nanotoxicity, graphene, as well as many biomaterials applications. The polymer and ‘soft’ materials chapter represents the largest expansion for the 2nd edition. Each ch...

  15. Introductory Chemistry

    OpenAIRE

    Baron, Mark; Gonzalez-Rodriguez, Jose; Stevens, Gary; Gray, Nathan; Atherton, Thomas; Winn, Joss

    2010-01-01

    Teaching and Learning resources for the 1st Year Introductory Chemistry course (Forensic Science). 30 credits. These are Open Educational Resources (OER), made available for re-use under a Creative Commons license.

  16. Nobel Prize in Chemistry

    Science.gov (United States)

    2000-01-01

    The Royal Swedish Academy has awarded the 1999 Nobel Prize in Chemistry to Ahmed H. Zewail (California Institute of Technology, Pasadena, CA) "for his studies of the transition states of chemical reactions using femtosecond spectroscopy". Zewail's work has taken the study of the rates and mechanisms of chemical reactions to the ultimate degree of detail - the time scale of bond making and bond breaking.

  17. Green Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Collison, Melanie

    2011-05-15

    Green chemistry is the science of chemistry used in a way that will not use or create hazardous substances. Dr. Rui Resendes is working in this field at GreenCentre Canada, an offshoot of PARTEQ Innovations in Kingston, Ontario. GreenCentre's preliminary findings suggest their licensed product {sup S}witchable Solutions{sup ,} featuring 3 classes of solvents and a surfactant, may be useful in bitumen oil sands extraction.

  18. Cluster Chemistry

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    @@ Cansisting of eight scientists from the State Key Laboratory of Physical Chemistry of Solid Surfaces and Xiamen University, this creative research group is devoted to the research of cluster chemistry and creation of nanomaterials.After three-year hard work, the group scored a series of encouraging progresses in synthesis of clusters with special structures, including novel fullerenes, fullerene-like metal cluster compounds as well as other related nanomaterials, and their properties study.

  19. The Institute of Archaeology Conference Competition

    Directory of Open Access Journals (Sweden)

    Ruth D Whitehouse

    2014-10-01

    Full Text Available One of the most creative innovations of Stephen Shennan’s directorship is the annual Institute of Archaeology Conference Competition. This scheme is now in its seventh year (with the result of the eighth competition just announced and it seems a good time to document and celebrate its success. The competition takes place in the spring of each year, with the winning conference being held in the following academic year. In the present format, applicants are asked to outline and justify the conference topic, list the proposed speakers and present a rough budget, with an indication of where the rest of the funds will be obtained if the conference costs are likely to exceed the £2000 of the award. There is no restriction as to the subject of the conference or its scale, though it is stipulated that the award must make a significant difference to the viability of the conference and that the conference fee for Institute attendees should be minimal, with a maximum of £10 for students.

  20. The industrial archaeology of deep time.

    Science.gov (United States)

    Bulstrode, Jenny

    2016-03-01

    For geologists and antiquaries of the late 1850s debates over ancient stone tools were frustrated by a lack of accepted criteria. The artefacts were hard to interpret. It was not self-evident how to judge whether they were ancient or modern, natural or man-made; or indeed whether stone tools could pre-date the use of metal tools at all. Antiquary and papermaker John Evans provided a system that offered to resolve these issues. His criteria and his use of re-enactment, making his own stone implements, gained acceptance among flint experts across fluid disciplinary boundaries and enabled authoritative interpretations of the underdetermined objects. This paper explores how Evans drew on the concerns of his industrial culture to make sense of prehistoric artefacts and support his claim to access the past through his own actions. Situated industrial concerns provided the resources for his flint work: from a patent dispute with astronomer and fellow industrialist Warren de la Rue, through his role in the Victorian arms trade, to the struggle to displace skilled manual labour in his factories. Evans is remembered for pioneering the techniques and classificatory system of modern Palaeolithic archaeology and as one of the founders of the re-enactment science of experimental flint knapping. His work played a significant role in helping reconceive the antiquity of man, yet the system of proof for this grand claim was deeply situated in his industrial culture. This paper explores how the industrial resources of a Victorian papermaker made human history.

  1. VIRTUAL EXHIBITION AND FRUITION OF ARCHAEOLOGICAL FINDS

    Directory of Open Access Journals (Sweden)

    A. M. Manferdini

    2012-09-01

    Full Text Available During the last two decades, since digital technologies have become more sophisticated in acquiring real data and building faithful copies of them, their improvements have suggested interesting applications in the field of valorisation of Historical, Cultural and Artistic Heritage, with significant consequences in the share and widespread of knowledge. But although several technologies and methodologies for 3d digitization have recently been developed and improved, the lack of a standard procedure and the costs connected to their use still doesn't encourage the systematic digital acquisition of wide collections and heritage. The aim of this paper is to show the state of the art of a project whose aim is to provide a methodology and a procedure to create digital reproductions of artefacts for Institutions called to preserve, manage and enhance the fruition of archaeological finds inside museums or through digital exhibitions. Our project’s aim is to find the most suitable procedure to digitally acquire archaeo logical artefacts that usually have small dimensions and have very complex and detailed surfaces. Within our methodology, particular attention has been paid to the use of widely shared and open-source visualization systems that enhance the involvement of the user by emphasizing three-dimensional characteristics of artefacts through virtual reality.

  2. Ceramic compositional analysis in archaeological perspective

    Energy Technology Data Exchange (ETDEWEB)

    Bishop, R.L.; Rands, R.L.; Holley, G.R.

    1980-01-01

    The primary significance of compositional analysis in archaeology lies on the spatial dimension, in distinguishing products made by locally or regionally-based groups. If compositional analysis is to be carried beyond the descriptive recording of similarities and differences, the resource procurement zone (and its geographical relationship to inferred places of manufacture) is a basic operational concept (Rands and Bishop 1980). A zonal concept is clearly indicated in the case of pottery, which frequently is derived from raw materials, clay and temper, that do not necessarily coincide in their place of procurement. Moreover, depending on geomorphological and geochemical variables, these materials may show considerable homogeneity over a fairly extended area. On the other hand, unless there is strong, selective patterning in the exploitation of resources, great heterogeneity within a restricted region may result in fragmented procurement zones that are difficult to equate with the products of specific manufacturing centers. Under favorable circumstances, however, it appears that methods of compositional analysis are approaching the point at which microzones of limited geographical extent can be recognized and assigned heuristically useful boundaries.

  3. EDXRS Compositional Classification of Archaeological Pottery

    International Nuclear Information System (INIS)

    The work carried out within this project was focused on the implementation of reliable EDXRF analytical procedures allowing the quantitative analysis and compositional classification of archaeological pottery, followed by its application to different cases of study. The development in CEADEN of a very compact polarized secondary target excitation set-up allowed maximizing x-ray production and detection. The use of proper materials for shielding served to eliminate the spectral interferences arising due to the excitation of construction materials. Together with this improvement in x-ray production, the installation of a digital signal processor (DSP) based spectrometer allowed to improve the instrumental sensitivity by a factor of 10, thus achieving better counting statistics, a significant reduction in measuring time and lowering the uncertainty of the determination. During the last years of the project, the work was aimed into the analysis of both Cuban pre-Columbian pottery and colonial exponents, in an effort to reveal compositional groups and the criteria for their differentiation. In addition a compositional analysis of Taino pottery from the Eastern region of Cuba was carried out. (author)

  4. DECENTRALIZATION OF ARCHAEOLOGICAL HERITAGE MANAGEMENT IN THE YUCATECAN LIVING TOWNS. INDICATORS PARTICIPATION AND COORDINATION OF THE PUBLIC AND SOCIAL STAKEHOLDERS

    Directory of Open Access Journals (Sweden)

    Josep Ligorred Perramon

    2014-10-01

    Full Text Available This research was developed against a background of debate arising since the 1990s regarding decentralization processes in archaeological heritage management in Mexico. Therefore this research focuses on the study of management processes in sites in Yucatan: particularly through observation of archaeological sites that make and what they do, and don’t, the different social actors to promote the conservation of this Our main hypothesis is that the lack of strategies for an activation of archaeological heritage in urban areas which is sustained over time and aimed at and/or alliance among the different government levels, and between government and various sectors of society, prohibits the and revaluing of this heritage for sustainable social use. We studied the archaeological situation prevailing in the Yucatecan cities of Mérida, Izamal, Acanceh and Dzilam González. The results us to demonstrate the need for a new management plan of heritage in living towns. Finally, we a series of indicators for measuring the participation, actions and coordination of those involved, with a view to collaborating in the development of mechanisms and strategies for evaluating advances in decentralization processes

  5. Dynamics and mechanisms of hot chemistry stimulated by recoil methods. Progress report, March 1, 1978--February 28, 1979

    International Nuclear Information System (INIS)

    The nuclear recoil chemical activation process in cyclobutane-t and subsequent inter- and intra-molecular energy transfer in recoil tritium and recoil chlorine hot reaction systems are analyzed. A stepladder model for intermolecular energy transfer from cyclobutane-t on collision shows average quanta of energy transferred range from 0.5 to 10 kcal/collision in He, N2, CO2 and cyclobutane bath gases. The recoil energy spectrum of hot chlorine atoms generated via the 37Cl(n,γ)38Cl reaction is also reported. The average recoil energy is found to be 294 eV and the maximum is 528 eV. Average reaction energy is calculated to be relatively independent of composition over the range from 0 to 99% moderation with noble gases in well scavenged systems of moderate reactivity. Geometrical isomerization accompanying the gas phase chlorine atom replacement reaction in 2,3 dichlorohexafluoro-2-butene as a function of moderation has been further investigated. A thermal or near thermal reaction path having a trans/cis product ratio of 1.3 and a high energy process which preferentially forms trans product from both cis and trans reactant are found. Dynamical features associated with the observed high energy inverse isotope effect in the reaction of chlorine atoms with H2 and D2 have been investigated through a non-Boltzmann rate constant analysis. The origin of this kinetic isotope effect is attributed to the secondary reactive process of collisional dissociation of translationally, vibrationally, and rotationally excited hydrogen chloride product molecules. Investigation of the kinetics and mechanisms of photochemical reactions between sulfur dioxide and aliphatic hydrocarbons has been initiated

  6. PHOTOGRAMMETRIC TECHNIQUES FOR PROMOTION OF ARCHAEOLOGICAL HERITAGE: THE ARCHAEOLOGICAL MUSEUM OF PARMA (ITALY

    Directory of Open Access Journals (Sweden)

    E. Dall’Asta

    2016-06-01

    Full Text Available In a context rich in history and cultural heritage, such as the Italian one, promotion and enhancement of historical evidences are crucial. The paper describes the case study of the Archaeological Museum of Parma, which, for the main part, conserves evidences found in the roman archaeological site of Veleia (Piacenza, Italy. To enhance the comprehension of the past, the project aims to promote the exhibits through new digital contents, in particular 3D models and AR applications, to improve their usability by the public. Projects like this pose some difficulties especially in data acquisition and restitution due to complexity of the objects and their dimension and position that are not always adequate for an easy survey. Furthermore, in this case, it was necessary to find a solution that takes into account, on one hand, the necessity of a high degree of detail to ensure high metric quality and, on the other hand, the need of producing small files, in order to easy load and consult them on the web or smartphone applications. For all these reasons, close-range photogrammetry was considered the most adequate technique to produce the major part of the models. In this paper, particular attention will be dedicated to the description of the survey campaign and data processing, underlining difficulties and adopted solutions, in order to provide a methodological summary of the actions performed.

  7. Archaeological remote sensing application pre-post war situation of Babylon archaeological site—Iraq

    Science.gov (United States)

    Jahjah, Munzer; Ulivieri, Carlo; Invernizzi, Antonio; Parapetti, Roberto

    2007-06-01

    The first basic step in obtaining a correct geographical knowledge and initiative for archaeological cartography analysis is an adequately geo-localized representation of natural and semi-natural resources and human activities, present and past. In this context, the correct and contextual evaluation of the resources through the use of integrated techniques of aerial photos, remote sensing and geographic information system (GIS) supply the synoptic instrument to the real knowledge of the land geography and for the operational management of any research and project. We will describe, at a synthetic level, the maturity of the land systematic study of Babylon archaeological site using different change detection analysis. Topographic maps of 1920 and 1980 were used, 18 aerial photos (1986) were mosaicked and georeferenced, vector information was digitized and inserted in a GIS system, DTM was build. Object oriented image analysis activity is being carried on and initial results are available through a WebGIS. The use of remote sensing (Quickbird and Ikonos) data allows us to capture the integral mutations due to human interventions. Earth observation data and GIS system were an optimal starting point for generating and updating the cartography. This results will be indispensable for the Iraqi authority and scientific community who care about the future of the territory.

  8. Photogrammetric Techniques for Promotion of Archaeological Heritage: the Archaeological Museum of Parma (italy)

    Science.gov (United States)

    Dall'Asta, E.; Bruno, N.; Bigliardi, G.; Zerbi, A.; Roncella, R.

    2016-06-01

    In a context rich in history and cultural heritage, such as the Italian one, promotion and enhancement of historical evidences are crucial. The paper describes the case study of the Archaeological Museum of Parma, which, for the main part, conserves evidences found in the roman archaeological site of Veleia (Piacenza, Italy). To enhance the comprehension of the past, the project aims to promote the exhibits through new digital contents, in particular 3D models and AR applications, to improve their usability by the public. Projects like this pose some difficulties especially in data acquisition and restitution due to complexity of the objects and their dimension and position that are not always adequate for an easy survey. Furthermore, in this case, it was necessary to find a solution that takes into account, on one hand, the necessity of a high degree of detail to ensure high metric quality and, on the other hand, the need of producing small files, in order to easy load and consult them on the web or smartphone applications. For all these reasons, close-range photogrammetry was considered the most adequate technique to produce the major part of the models. In this paper, particular attention will be dedicated to the description of the survey campaign and data processing, underlining difficulties and adopted solutions, in order to provide a methodological summary of the actions performed.

  9. Spatiotemporal conceptual platform for querying archaeological information systems

    Science.gov (United States)

    Partsinevelos, Panagiotis; Sartzetaki, Mary; Sarris, Apostolos

    2015-04-01

    Spatial and temporal distribution of archaeological sites has been shown to associate with several attributes including marine, water, mineral and food resources, climate conditions, geomorphological features, etc. In this study, archeological settlement attributes are evaluated under various associations in order to provide a specialized query platform in a geographic information system (GIS). Towards this end, a spatial database is designed to include a series of archaeological findings for a secluded geographic area of Crete in Greece. The key categories of the geodatabase include the archaeological type (palace, burial site, village, etc.), temporal information of the habitation/usage period (pre Minoan, Minoan, Byzantine, etc.), and the extracted geographical attributes of the sites (distance to sea, altitude, resources, etc.). Most of the related spatial attributes are extracted with readily available GIS tools. Additionally, a series of conceptual data attributes are estimated, including: Temporal relation of an era to a future one in terms of alteration of the archaeological type, topologic relations of various types and attributes, spatial proximity relations between various types. These complex spatiotemporal relational measures reveal new attributes towards better understanding of site selection for prehistoric and/or historic cultures, yet their potential combinations can become numerous. Therefore, after the quantification of the above mentioned attributes, they are classified as of their importance for archaeological site location modeling. Under this new classification scheme, the user may select a geographic area of interest and extract only the important attributes for a specific archaeological type. These extracted attributes may then be queried against the entire spatial database and provide a location map of possible new archaeological sites. This novel type of querying is robust since the user does not have to type a standard SQL query but

  10. Solvent effects in chemistry

    CERN Document Server

    Buncel, Erwin

    2015-01-01

    This book introduces the concepts, theory and experimental knowledge concerning solvent effects on the rate and equilibrium of chemical reactions of all kinds.  It begins with basic thermodynamics and kinetics, building on this foundation to demonstrate how a more detailed understanding of these effects may be used to aid in determination of reaction mechanisms, and to aid in planning syntheses. Consideration is given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to statistical methods (chemometrics), and to modern day concerns such as ""green"" chemistry, where ut

  11. Spins in chemistry

    CERN Document Server

    McWeeny, Roy

    2004-01-01

    Originally delivered as a series of lectures, this volume systematically traces the evolution of the ""spin"" concept from its role in quantum mechanics to its assimilation into the field of chemistry. Author Roy McWeeny presents an in-depth illustration of the deductive methods of quantum theory and their application to spins in chemistry, following the path from the earliest concepts to the sophisticated physical methods employed in the investigation of molecular structure and properties. Starting with the origin and development of the spin concept, the text advances to an examination of sp

  12. Chemistry in microelectronics

    CERN Document Server

    Le Tiec, Yannick

    2013-01-01

    Microelectronics is a complex world where many sciences need to collaborate to create nano-objects: we need expertise in electronics, microelectronics, physics, optics and mechanics also crossing into chemistry, electrochemistry, as well as biology, biochemistry and medicine. Chemistry is involved in many fields from materials, chemicals, gases, liquids or salts, the basics of reactions and equilibrium, to the optimized cleaning of surfaces and selective etching of specific layers. In addition, over recent decades, the size of the transistors has been drastically reduced while the functionalit

  13. Martian Chlorine Chemistry: A Study of Perchlorate on the Martian Surface, Evidence of an Ongoing Formation Mechanism and Implications of a Complex Chlorine Cycle

    Science.gov (United States)

    Carrier, Brandi L.

    2015-10-01

    The research presented herein addresses the detection of perchlorate on Mars, evidence of perchlorate in Mars meteorite EETA 79001, determination of the perchlorate parent salts at the Phoenix landing site, and the ongoing formation of perchlorate from chloride minerals as well as from other oxychlorine species. The detection of perchlorate in three samples by the Phoenix Wet Chemistry Laboratory and the implication of these results are discussed. The further detection of perchlorate in Mars meteorite EETA 79001 by ion chromatography and the determination of the parent salts of the perchlorate detected at the Phoenix landing site by electrochemical analyses and ion chromatography are detailed and the implications of the identity of the parent salts are discussed. The possible formation pathways for martian perchlorate are then explored and a possible mechanism for ongoing perchlorate formation on the martian surface is detailed. Perchlorate is shown to be formed upon exposure of chloride minerals, as well as of chlorite and chlorate salts, to current Mars relevant conditions including temperature, pressure, ultraviolet radiation and atmospheric composition. The implications of this ongoing perchlorate formation for the survival and detection of organics, the oxidizing nature of the soil, formation of liquid brines and recurring slope lineae are discussed. Further preliminary experiments have been conducted to investigate the effects of perchlorate formation on the survival and degradation of organic compounds.

  14. Digital Media, Power and (InEquality in Archaeology and Heritage

    Directory of Open Access Journals (Sweden)

    Sara Perry

    2015-01-01

    Full Text Available Decades of Internet study have arguably done little to shed light on the nature and implications of web-based communications in archaeology. Since the late 1990s, the online world has been lauded by archaeologists for its capacities to engender dialogue, participation, intellectual change and even democratic revolution. Yet the dangers associated with its use have barely been probed. Threats to privacy, equality, access, security of data, and personal safety and well-being are seemingly characteristic of all communication technologies. However, the naive zeal with which many archaeological and heritage organisations are employing online platforms for dissemination, profile-building, 'impact' and public accountability is fraught with risk and deserving of interrogation. This article explores the effects of digital culture on the professional identities and careers of archaeologists, heritage specialists and museum workers. Through a multi-disciplinary survey of over 400 individuals, nearly one-third of whom self-identified as archaeological or related heritage practitioners (working both inside and outside of the academic sector, we consider the various ways in which online technologies are used to express, promote, facilitate, strengthen and undermine both professionals themselves and professional practices in archaeology. Situating ourselves in the intersectional and feminist literature, we argue that web-based harassment and lack of adequate e-safety mechanisms are rife in the discipline, putting it in jeopardy of fuelling structural inequalities. Our findings suggest that close to one-third of practitioners report victimisation via online communication; the majority know their abusers offline; and, although the prevalence of such abuse is roughly equal among men and women, its nature is split along gender lines. Of especial concern, most practitioners choose to ignore their abuse, a decision that may be motivated by the non-existent or victim

  15. Evaluation of 1,3,5 trimethylbenzene degradation in the detailed tropospheric chemistry mechanism, MCMv3.1, using environmental chamber data

    Directory of Open Access Journals (Sweden)

    A. Metzger

    2008-11-01

    Full Text Available The degradation mechanism of 1,3,5-trimethyl- benzene (TMB as implemented in the Master Chemical Mechanism version 3.1 (MCM was evaluated using data from the environmental chamber at the Paul Scherrer Institute. The results show that the MCM provides a consistent description of the photo-oxidation of TMB/NOx mixtures for a range of conditions. In all cases the agreement between the measurement and the simulation decreases with decreasing VOC-NOx ratio and in addition with increasing precursor concentration. A significant underestimation of the decay rate of TMB and thus underestimation of reactivity in the system, consistent with results from previous appraisals of the MCM, was observed.

    Much higher nitrous acid (HONO concentrations compared to simulations and expected from chamber characterization experiments were measured during these smog chamber experiments. A light induced NO2 to HONO conversion at the chamber walls is suggested to occur. This photo-enhanced NO2 to HONO conversion with subsequent HONO photolysis enhances the reactivity of the system. After the implementation of this reaction in the model it describes the decay of TMB properly. Nevertheless, the model still over-predicts ozone at a later stage of the experiment. This can be attributed to a too slow removal of NO2. It is also shown that this photo-enhanced HONO formation is not restricted to TMB photo-oxidation but also occurs in other chemical systems (e.g. α-pinene. However, the influence of HONO as a source of OH radicals is less important in these more reactive systems and therefore the importance of the HONO chemistry is less obvious.

  16. Examining the impacts of ethanol (E85) versus gasoline photochemical production of smog in a fog using near-explicit gas- and aqueous-chemistry mechanisms

    Science.gov (United States)

    Ginnebaugh, Diana L.; Jacobson, Mark Z.

    2012-12-01

    This study investigates the air quality impacts of using a high-blend ethanol fuel (E85) instead of gasoline in vehicles in an urban setting when a morning fog is present under summer and winter conditions. The model couples the near-explicit gas-phase Master Chemical Mechanism (MCM v. 3.1) with the extensive aqueous-phase Chemical Aqueous Phase Radical Mechanism (CAPRAM 3.0i) in SMVGEAR II, a fast and accurate ordinary differential equation solver. Summer and winter scenarios are investigated during a two day period in the South Coast Air Basin (SCAB) with all gasoline vehicles replaced by flex-fuel vehicles running on E85 in 2020. We find that E85 slightly increases ozone compared with gasoline in the presence or absence of a fog under summer conditions but increases ozone significantly relative to gasoline during winter conditions, although winter ozone is always lower than summer ozone. A new finding here is that a fog during summer may increase ozone after the fog disappears, due to chemistry alone. Temperatures were high enough in the summer to increase peroxy radical (RO2) production with the morning fog, which led to the higher ozone after fog dissipation. A fog on a winter day decreases ozone after the fog. Within a fog, ozone is always lower than if no fog occurs. The sensitivity of the results to fog parameters like droplet size, liquid water content, fog duration and photolysis are investigated and discussed. The results support previous work suggesting that E85 and gasoline both enhance pollution with E85 enhancing pollution significantly more at low temperatures. Thus, neither E85 nor gasoline is a ‘clean-burning’ fuel.

  17. Examining the impacts of ethanol (E85) versus gasoline photochemical production of smog in a fog using near-explicit gas- and aqueous-chemistry mechanisms

    International Nuclear Information System (INIS)

    This study investigates the air quality impacts of using a high-blend ethanol fuel (E85) instead of gasoline in vehicles in an urban setting when a morning fog is present under summer and winter conditions. The model couples the near-explicit gas-phase Master Chemical Mechanism (MCM v. 3.1) with the extensive aqueous-phase Chemical Aqueous Phase Radical Mechanism (CAPRAM 3.0i) in SMVGEAR II, a fast and accurate ordinary differential equation solver. Summer and winter scenarios are investigated during a two day period in the South Coast Air Basin (SCAB) with all gasoline vehicles replaced by flex-fuel vehicles running on E85 in 2020. We find that E85 slightly increases ozone compared with gasoline in the presence or absence of a fog under summer conditions but increases ozone significantly relative to gasoline during winter conditions, although winter ozone is always lower than summer ozone. A new finding here is that a fog during summer may increase ozone after the fog disappears, due to chemistry alone. Temperatures were high enough in the summer to increase peroxy radical (RO2) production with the morning fog, which led to the higher ozone after fog dissipation. A fog on a winter day decreases ozone after the fog. Within a fog, ozone is always lower than if no fog occurs. The sensitivity of the results to fog parameters like droplet size, liquid water content, fog duration and photolysis are investigated and discussed. The results support previous work suggesting that E85 and gasoline both enhance pollution with E85 enhancing pollution significantly more at low temperatures. Thus, neither E85 nor gasoline is a ‘clean-burning’ fuel. (letter)

  18. Electrospun meshes possessing region-wise differences in fiber orientation, diameter, chemistry and mechanical properties for engineering bone-ligament-bone tissues.

    Science.gov (United States)

    Samavedi, Satyavrata; Vaidya, Prasad; Gaddam, Prudhvidhar; Whittington, Abby R; Goldstein, Aaron S

    2014-12-01

    Although bone-patellar tendon-bone (B-PT-B) autografts are the gold standard for repair of anterior cruciate ligament ruptures, they suffer from drawbacks such as donor site morbidity and limited supply. Engineered tissues modeled after B-PT-B autografts are promising alternatives because they have the potential to regenerate connective tissue and facilitate osseointegration. Towards the long-term goal of regenerating ligaments and their bony insertions, the objective of this study was to construct 2D meshes and 3D cylindrical composite scaffolds - possessing simultaneous region-wise differences in fiber orientation, diameter, chemistry and mechanical properties - by electrospinning two different polymers from off-set spinnerets. Using a dual drum collector, 2D meshes consisting of an aligned polycaprolactone (PCL) fiber region, randomly oriented poly(lactide-co-glycolide) (PLGA) fiber region and a transition region (comprised of both PCL and PLGA fibers) were prepared, and region-wise differences were confirmed by microscopy and tensile testing. Bone marrow stromal cells (BMSCs) cultured on these meshes exhibited random orientations and low aspect ratios on the random PLGA regions, and high aspect ratios and alignment on the aligned PCL regions. Next, meshes containing an aligned PCL region flanked by two transition regions and two randomly oriented PLGA regions were prepared and processed into 3D cylindrical composite scaffolds using an interpenetrating photo-crosslinkable polyethylene glycol diacrylate hydrogel to recapitulate the shape of B-PT-B autografts. Tensile testing indicated that cylindrical composites were mechanically robust, and eventually failed due to stress concentration in the aligned PCL region. In summary, this study demonstrates a process to fabricate electrospun meshes possessing region-wise differences in properties that can elicit region-dependent cell responses, and be readily processed into scaffolds with the shape of B-PT-B autografts.

  19. Radiation Chemistry

    Science.gov (United States)

    Wojnárovits, L.

    Ionizing radiation causes chemical changes in the molecules of the interacting medium. The initial molecules change to new molecules, resulting in changes of the physical, chemical, and eventually biological properties of the material. For instance, water decomposes to its elements H2 and O2. In polymers, degradation and crosslinking take place. In biopolymers, e.g., DNS strand breaks and other alterations occur. Such changes are to be avoided in some cases (radiation protection), however, in other cases they are used for technological purposes (radiation processing). This chapter introduces radiation chemistry by discussing the sources of ionizing radiation (radionuclide sources, machine sources), absorption of radiation energy, techniques used in radiation chemistry research, and methods of absorbed energy (absorbed dose) measurements. Radiation chemistry of different classes of inorganic (water and aqueous solutions, inorganic solids, ionic liquids (ILs)) and organic substances (hydrocarbons, halogenated compounds, polymers, and biomolecules) is discussed in concise form together with theoretical and experimental backgrounds. An essential part of the chapter is the introduction of radiation processing technologies in the fields of polymer chemistry, food processing, and sterilization. The application of radiation chemistry to nuclear technology and to protection of environment (flue gas treatment, wastewater treatment) is also discussed.

  20. Archaeological research in the Eurasian steppes

    Directory of Open Access Journals (Sweden)

    Parzinger, Hermann

    1998-06-01

    Full Text Available This paper presents the activities of the 'Eurasien-Abteilung' of the German Archaeological Institute in different countries of former USSR. Many of these projects have just begun; consequently the paper does not discuss the results of these investigations, but details their scientific purposes. The investigations cover an area which extends from the Black Sea to northeastern China. The principal objects of these investigations include: the transition from the Late Bronze to the Early Iron Age in the Pontic area north of the Black Sea and the Greek colonization of that area; the activities of the Scythians and the Sassanians in Transcaucasia, urbanism and metallurgy in the Bronze Age of Central Asia; and, finally, cultural developments from the Early Bronze Age to the periods of the Scythians and the Huns period in southern Siberia.

    Este artículo presenta las actividades de la 'Eurasien-Abteilung', del Instituto Arqueológico Alemán, en los distintos países de la ex-URSS. Como muchos de estos proyectos han empezado hace poco tiempo, no pretendemos adelantar resultados, sino planteamientos científicos. El área que abarcan se extiende desde el Mar Negro hasta el Noreste de China. Sus principales temas de investigación son: el cambio del Bronce Final a la primera Edad del Hierro en el norte del Mar Negro, la colonización griega en esta zona, las actividades de los Escitas y de los Sasánidas en Transcaucasia, el urbanismo y la metalurgia de la Edad del Bronce en Asia Central y, finalmente, el desarrollo cultural desde el Bronce Antiguo hasta la época de los Escitas y Hunos en el sur de Siberia.

  1. Advancing archaeological geophysics: Interpreting the archaeological landscape, ground-penetrating radar data processing, and multi-sensor fusion

    Science.gov (United States)

    Ernenwein, Eileen G.

    The human past has been the subject of scientific inquiry for centuries, and has long been approached by the study of material remains from traditional archaeological excavations. In recent decades the advancing fields of geophysics and geographic information systems have greatly improved the archaeological toolkit, and research to improve these methods is ongoing. This dissertation focuses on important aspects of geophysical survey as an approach to landscape-scale archaeology, each presented as stand-alone scientific papers that utilize a 1.2 hectare four-dimensional (ground-penetrating radar, magnetometry, magnetic susceptibility, and conductivity) dataset collected at Pueblo Escondido, a large prehistoric village of the Mogollon culture in southern New Mexico. Chapter 2 presents a case study showing the benefits of multidimensional geophysical surveys over large areas at archaeological sites. When paired with traditional archaeological excavations, it is possible to interpret the archaeological landscape on a much broader scale than is possible using excavations alone. At Pueblo Escondido, this approach led to a revised understanding of the architectural remains with broad regional significance. Chapter 3 describes new problems related to GPR surveys over large areas or extended periods of time, including issues related to correcting trace misalignments, edge discontinuities, and striping. Data processing solutions are offered. Chapter 4 presents an exploration of image classification methods for integrating multiple geophysical datasets. Unsupervised classification utilizing K-means cluster analysis and supervised classification using Mahalanobis Distance are described. The latter yielded a predictive model of archaeological features and identified some features that were not easily identified in the original datasets.

  2. Feasibility study of archaeological structures scanning by muon tomography

    Science.gov (United States)

    Gómez, H.; Carloganu, C.; Gibert, D.; Marteau, J.; Niess, V.; Katsanevas, S.; Tonazzo, A.

    2015-08-01

    One of the main concerns in archaeology is to find of a method to study precisely archaeological structures in the least invasive way possible to avoid damage. The requirement of preserving the structures integrity prevents, in the case of pyramids or tumuli, the study of any internal structure (halls or tombs) which are not reachable by existing corridors. One non-invasive method is the muon tomography. By placing a detector which allows to register the muon direction after the structure, it is possible to have an idea of its composition based on the attenuation of the muon flux, which depends on the material length and density that muons have crossed. This technique, alone or together with other exploration techniques as seismic tomography or electrical resistivity tomography, can provide useful information about the internal structure of the archaeological form that can not be obtained by conventional archaeological methods. In this work, the time measurement necessary to obtain a significant result about the composition of an archaeological structure is estimated. To do that, a Monte Carlo simulation framework based on the MUSIC software, properly tuned for this study, has been developed. The particular case of the Kastas Amfipoli Macedonian tumulus has been considered to perform the simulations.

  3. The development of a GIS for New Deal Archaeology

    Directory of Open Access Journals (Sweden)

    Bernard K. Means

    2011-05-01

    Full Text Available I have recently launched an effort to create a GIS of all New Deal-funded archaeological investigations conducted in the 48 states that comprised the USA during the Great Depression (Means 2011. This effort was inspired by the persistent notion that New Deal archaeology was largely limited to the southeastern United States, where the generally warmer climate was seen as conducive to the lengthy field seasons that ensured continuous work for the unemployed (Lyon 1996. The large mound sites that dotted the southeastern USA also ensured that there would be sufficient work for the large relief crews seen as ideal from the perspective of federal officials. While it may prove true that the majority of New Deal archaeology was conducted in the southeast, it is also demonstrably true that the various ‘Alphabet Soup’ work relief programs – notably the Civilian Conservation Corps (CCC and the Works Progress Administration/Work Projects Administration (WPA – supported archaeological investigations throughout the USA. In my preliminary efforts to create a GIS for New Deal archaeology, I have determined that at least 75 percent of the 48 states that comprised the USA during the Great Depression had some form of federally funded work relief survey or excavation.

  4. NASA Remote Sensing Research as Applied to Archaeology

    Science.gov (United States)

    Giardino, Marco J.; Thomas, Michael R.

    2002-01-01

    The use of remotely sensed images is not new to archaeology. Ever since balloons and airplanes first flew cameras over archaeological sites, researchers have taken advantage of the elevated observation platforms to understand sites better. When viewed from above, crop marks, soil anomalies and buried features revealed new information that was not readily visible from ground level. Since 1974 and initially under the leadership of Dr. Tom Sever, NASA's Stennis Space Center, located on the Mississippi Gulf Coast, pioneered and expanded the application of remote sensing to archaeological topics, including cultural resource management. Building on remote sensing activities initiated by the National Park Service, archaeologists increasingly used this technology to study the past in greater depth. By the early 1980s, there were sufficient accomplishments in the application of remote sensing to anthropology and archaeology that a chapter on the subject was included in fundamental remote sensing references. Remote sensing technology and image analysis are currently undergoing a profound shift in emphasis from broad classification to detection, identification and condition of specific materials, both organic and inorganic. In the last few years, remote sensing platforms have grown increasingly capable and sophisticated. Sensors currently in use, or nearing deployment, offer significantly finer spatial and spectral resolutions than were previously available. Paired with new techniques of image analysis, this technology may make the direct detection of archaeological sites a realistic goal.

  5. Archaeological Investigations at the Upper Chapel, Norfolk Street, Sheffield, UK

    Directory of Open Access Journals (Sweden)

    Katherine Baker

    2011-02-01

    Full Text Available Sheffield, in the north of England, grew rapidly in the 19th century and gained an international reputation for its cutlery, tableware, and steel products. The material legacy of this age of industrialisation is extensive, and archaeological work in the modern city over the last 20 years has, for the most part, focused on the above and below ground industrial archaeology relating to metals trades' production sites spanning the 19th and 20th centuries. This article describes recent archaeological work around the Upper Chapel, a Unitarian Meeting House in the city centre where archaeological work recovered a possible buried medieval soil deposit, which contained an assemblage of medieval pottery dating from the 12th to 15th centuries. The presence of waster sherds and fragments of kiln furniture within this assemblage suggests that pottery production may have taken place on or near the site, making this the first putative evidence for pottery production in medieval Sheffield. The archaeological investigations also recovered four human burials from the 18th- to 19th-century burial ground associated with the Upper Chapel. The Upper Chapel burial ground differs from other recently excavated cemeteries in Sheffield as it potentially contained graves of high-status individuals, with at least a proportion of the skeletons and coffins well-preserved owing to waterlogged ground conditions. Detailed studies of the human remains, coffins, and incorporated material, including brass shroud pins are also discussed.

  6. Feasibility study of archaeological structures scanning by muon tomography

    Energy Technology Data Exchange (ETDEWEB)

    Gómez, H.; Katsanevas, S.; Tonazzo, A. [Laboratoire Astroparticule et Cosmologie (APC) - Université Paris 7. Paris (France); Carloganu, C.; Niess, V. [Laboratoire de Physique Corpusculaire (LPC) - Université Blaise Pascal. Clermont - Ferrand (France); Gibert, D. [Géosciences Rennes - Université de Rennes 1. Rennes (France); Marteau, J. [Institute de Physique Nucléaire de Lyon (IPNL) - Université de Lyon (UCBL). Lyon (France)

    2015-08-17

    One of the main concerns in archaeology is to find of a method to study precisely archaeological structures in the least invasive way possible to avoid damage. The requirement of preserving the structures integrity prevents, in the case of pyramids or tumuli, the study of any internal structure (halls or tombs) which are not reachable by existing corridors. One non-invasive method is the muon tomography. By placing a detector which allows to register the muon direction after the structure, it is possible to have an idea of its composition based on the attenuation of the muon flux, which depends on the material length and density that muons have crossed. This technique, alone or together with other exploration techniques as seismic tomography or electrical resistivity tomography, can provide useful information about the internal structure of the archaeological form that can not be obtained by conventional archaeological methods. In this work, the time measurement necessary to obtain a significant result about the composition of an archaeological structure is estimated. To do that, a Monte Carlo simulation framework based on the MUSIC software, properly tuned for this study, has been developed. The particular case of the Kastas Amfipoli Macedonian tumulus has been considered to perform the simulations.

  7. Feasibility study of archaeological structures scanning by muon tomography

    International Nuclear Information System (INIS)

    One of the main concerns in archaeology is to find of a method to study precisely archaeological structures in the least invasive way possible to avoid damage. The requirement of preserving the structures integrity prevents, in the case of pyramids or tumuli, the study of any internal structure (halls or tombs) which are not reachable by existing corridors. One non-invasive method is the muon tomography. By placing a detector which allows to register the muon direction after the structure, it is possible to have an idea of its composition based on the attenuation of the muon flux, which depends on the material length and density that muons have crossed. This technique, alone or together with other exploration techniques as seismic tomography or electrical resistivity tomography, can provide useful information about the internal structure of the archaeological form that can not be obtained by conventional archaeological methods. In this work, the time measurement necessary to obtain a significant result about the composition of an archaeological structure is estimated. To do that, a Monte Carlo simulation framework based on the MUSIC software, properly tuned for this study, has been developed. The particular case of the Kastas Amfipoli Macedonian tumulus has been considered to perform the simulations

  8. Hyperspectral MIVIS data to investigate the Lilybaeum (Marsala) Archaeological Park

    Science.gov (United States)

    Merola, P.; Allegrini, A.; Bajocco, S.

    2005-10-01

    In the last 20 years air photograph and remote sensing, both from airplane and satellite, allowed to gain, from the analysis of the superficial land unit characteristics, useful information for the location of buried archaeological structures. For this kind of investigation, hyperspectral MIVIS (Multispectral Infrared and Visible Imaging Spectrometer) data revealed to be very useful, for example, since 1994, for the purpose CNR-LARA research project, many archaeological studies have been supported by MIVIS data on several italian archaeological sites: Selinunte, Arpi (Foggia), Villa Adriana (Tivoli) and Marsala. Marsala town, the ancient Lilybaeum, lies on the western coastline of Sicily, at about 30 km south of Trapani. Founded by the Phoenicians, it intensely lived during the Punic, Roman, Arab and Norman periods, whose dominations left many important remains. This archaeological area was investigated by means of several techniques, such as excavations, topographic studies based on airborne campaigns, etc. On this site the main archaeological information were provided by the analysis of the VIS-NIR spectral bands and by Thermal Capacity image.

  9. Polymer Chemistry

    Science.gov (United States)

    Williams, Martha; Roberson, Luke; Caraccio, Anne

    2010-01-01

    This viewgraph presentation describes new technologies in polymer and material chemistry that benefits NASA programs and missions. The topics include: 1) What are Polymers?; 2) History of Polymer Chemistry; 3) Composites/Materials Development at KSC; 4) Why Wiring; 5) Next Generation Wiring Materials; 6) Wire System Materials and Integration; 7) Self-Healing Wire Repair; 8) Smart Wiring Summary; 9) Fire and Polymers; 10) Aerogel Technology; 11) Aerogel Composites; 12) Aerogels for Oil Remediation; 13) KSC's Solution; 14) Chemochromic Hydrogen Sensors; 15) STS-130 and 131 Operations; 16) HyperPigment; 17) Antimicrobial Materials; 18) Conductive Inks Formulations for Multiple Applications; and 19) Testing and Processing Equipment.

  10. Quantum chemistry

    CERN Document Server

    Lowe, John P

    2006-01-01

    Lowe's new edition assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry. It can serve as a primary text in quantum chemistry courses, and enables students and researchers to comprehend the current literature. This third edition has been thoroughly updated and includes numerous new exercises to facilitate self-study and solutions to selected exercises.* Assumes little initial mathematical or physical sophistication, developing insights and abilities in the context of actual problems* Provides thorough treatment

  11. Images of Miloje M. Vasić in Serbian Archaeology

    Directory of Open Access Journals (Sweden)

    Aleksandar Palavestra

    2016-02-01

    Full Text Available Miloje M. Vasić, "the first academically educated archaeologist in Serbia", has a strange destiny in the Serbian archaeology. On the one hand, he has been elevated to the post of the "founding father" of the discipline, with almost semidivine status and iconic importance, while on the other hand, his works have been largely unread and neglected. This paradoxical split is the consequence of the fact that Vasić has been postulated as the universal benchmark of the archaeological practice in Serbia, regardless of his interpretation of the past on the grounds of the archaeological record – the essence of archaeology. Strangely, the life and work of Vasić have not been the subject of much writing, apart from several obituaries, two short appropriate texts (Srejović, Cermanović, and rare articles in catalogues and collections dedicated to the research of Vinča (Garašanin, Srejović, Tasić, Nikolić and Vuković. The critical analysis of his whole interpretive constellation, with "The Ionian colony Vinča" being its brightest star, was limited before the World War II to the rare attempts to rectify the chronology and identify the Neolithic of the Danube valley (Fewkes, Grbić, Holste. After the war, by the middle of the 20th century, the interpretation of Vasić has been put to severe criticism of his students (Garašanin, Milojčić, Benac, which led to the significant paradigm shift, the recognition of the importance of the Balkan Neolithic, and the establishment of the culture-historical approach in the Serbian archaeology. However, from this moment on, the reception of Vasić in the Serbian archaeology has taken a strange route: Vasić as a person gains in importance, but his works are neglected, though referred to, but almost in a cultic fashion, without reading or interpreting them. Rare is a paper on the Neolithic of the Central Balkans that does not call upon the name of Vasić and his four- volume "Vinča", in which Neolithic is not

  12. The GALAH Survey and Galactic Archaeology in the next decade

    CERN Document Server

    Martell, Sarah L

    2015-01-01

    The field of Galactic Archaeology aims to understand the origins and evolution of the stellar populations in the Milky Way, as a way to understand galaxy formation and evolution in general. The GALAH (Galactic Archaeology with HERMES) Survey is an ambitious Australian-led project to explore the Galactic history of star formation, chemical evolution, minor mergers and stellar migration. GALAH is using the HERMES spectrograph, a novel, highly multiplexed, four-channel high-resolution optical spectrograph, to collect high-quality R ~ 28,000 spectra for one million stars in the Milky Way. From these data we will determine stellar parameters, radial velocities and abundances for up to 29 elements per star, and carry out a thorough chemical tagging study of the nearby Galaxy. There are clear complementarities between GALAH and other ongoing and planned Galactic Archaeology surveys, and also with ancillary stellar data collected by of major cosmological surveys. Combined, these data sets will provide a revolutionary...

  13. Impact of roots and rhizomes on wetland archaeology

    DEFF Research Database (Denmark)

    Tjelldén, Anna Katarina Ejgreen; Kristiansen, Søren Munch; Matthiesen, Henning;

    2015-01-01

    species that can damage site stratigraphy and artefacts. However, reviews on the types and degree of damage caused by vegetation to archaeological remains preserved in situ in wetlands have hitherto only been sporadically treated in the literature. Thus, this paper provides an overview of the adverse...... demonstrate that cultural heritage site management may unintentionally introduce deep-rooted or exudate aggressive plants by invoking change in hydrological conditions. Moreover, the implementation of biomass energy utilization and agricultural root depth optimization on a worldwide basis stresses the need...... for more research within root and rhizome impact on archaeological remains in wetlands. In conclusion, the worst-case scenario may be in situ deterioration instead of preservation, and one essential threat to archaeological wetland sites is the impact of wetland vegetation....

  14. Island Archaeology: In Search of a New Horizon

    Directory of Open Access Journals (Sweden)

    Arie Boomert

    2007-05-01

    Full Text Available This paper charts the academic development of “island archaeology” from its roots in Darwinist and anthropological island studies through island biogeography to processual and post-processual archaeology. It is argued that the rarely made explicit yet fundamental premise of island archaeology that insular human societies show intrinsic characteristics essentially dissimilar from those on mainlands is false. The persistence of this misconception is due in part to the emphasis on islands as ideal units of analysis. It is suggested that island societies should be studied at the level of the archipelago and/or mainland coastal setting within their maritime cultural framework, ultimately leading up to an archaeology of maritime identity.

  15. Augmented Reality System for the musealization of archaeological sites

    Directory of Open Access Journals (Sweden)

    Javier Esclapés

    2013-11-01

    Full Text Available In this paper we are presenting a multi-marker and semi-immersive system for augmented reality to visualize and interact with archaeological sites, specifically those located in inaccessible or complex environments, such as caves or underwater locations. The use of this system in museum exhibitions helps visitors to come closer to archaeological heritage. As an example for the implementation of this system, an archaeological site has been used. It is the “Cova del Barranc del Migdia”, located in the “Sierra del Montgó”, Xàbia (Spain. The product obtained has been exhibited in various museums nationwide.

  16. Geophysical Investigations of Archaeological Resources in Southern Idaho

    Energy Technology Data Exchange (ETDEWEB)

    Brenda Ringe Pace; Gail Heath; Clark Scott; Carlan McDaniel

    2005-10-01

    At the Idaho National Laboratory and other locations across southern Idaho, geophysical tools are being used to discover, map, and evaluate archaeological sites. A variety of settings are being explored to expand the library of geophysical signatures relevant to archaeology in the region. Current targets of interest include: prehistoric archaeological features in open areas as well as lava tube caves, historical structures and activity areas, and emigrant travel paths. We draw from a comprehensive, state of the art geophysical instrumentation pool to support this work. Equipment and facilities include ground penetrating radar, electromagnetic and magnetic sensors, multiple resistivity instruments, advanced positioning instrumentation, state of the art processing and data analysis software, and laboratory facilities for controlled experiments.

  17. The Invisible Hunger: Is Famine Identifiable from the Archaeological Record?

    Directory of Open Access Journals (Sweden)

    Johanna Morgan

    2013-06-01

    Full Text Available Famine, as defined by an acute (short-term or chronic (long-term or cyclical period of starvation, is identifiable in the historical period from written records and potentially with archaeological corroboration, but in prehistory other approaches must be employed. Several of these are discussed including studies of diet and nutrition, paleodemography, environmental catalysts, and funerary ritual. Despite a multifactorial analysis integrating palynology, dendrochronology, stable isotope analyses, osteoarchaeology, and social archaeology, difficulties in contemporizing paleodemographic events them with osteological assemblages are substantial enough that the detection of a famine is not possible solely from the archaeological record. More significant is the conclusion that all apparent indicators for acute or chronic starvation are also representative of epidemic disease. Because of this uncertainty, it is not possible to identify famine in prehistory.

  18. Compass & Vernier Type Models in Indo Archaeology: Engineering Heritage

    Science.gov (United States)

    Bhattacharya, Deepak

    2015-09-01

    Two extant, dated, verifiable archaeological members are adduced to have radial type compass features, having scope for fractionation of angles (θ operators) in a constant manner with lookout facilities. The Archaeological Survey of India celebrates their apex achievements in the domain of engineering/survey devices of erstwhile societies. Possible correlation has been drawn between the representatives of the elusive Gola yantra and the Vikhyana yantra (circular instrument & looking device) as referred in Indian history and culture. Dadhi nauti (curd level) has been explained for the first time. Now, all of these are accessible to everyone. This work is the first time report, which relates to historical archaeology of lower date c. 600 AD.

  19. 77 FR 59661 - Notice of Inventory Completion: Stanford University Archaeology Center, Stanford, CA

    Science.gov (United States)

    2012-09-28

    ... National Park Service Notice of Inventory Completion: Stanford University Archaeology Center, Stanford, CA AGENCY: National Park Service, Interior. ACTION: Notice. SUMMARY: The Stanford University Archaeology... to be culturally affiliated with the human remains may contact the Stanford University...

  20. Identifying military impacts to archaeological resources based on differences in vertical stratification of soil properties

    Science.gov (United States)

    The National Historic Preservation Act requires land-managing agencies to identify and account for their impacts on archaeological resources. Regulatory agencies that oversee compliance with historic preservation legislation frequently assume military training adversely affects archaeological resou...

  1. Organic chemistry

    International Nuclear Information System (INIS)

    The activities of the mycotoxin research group are discussed. This includes the isolation and structure determination of mycotoxins, plant products, the biosyntheris of mycotoxins, the synthesis and characteristics of steroids, the synthesis and mechanistic aspects of heterocyclic chemistry and the functionality of steroids over long distances. Nmr spectra and mass spectroscopy are some of the techniques used

  2. Reinventing Chemistry

    OpenAIRE

    Whitesides, George McClelland

    2015-01-01

    Chemistry is in a period of change, from an era focused on molecules and reactions, to one in which manipulations of systems of molecules and reactions will be essential parts of controlling larger systems. This Essay traces paths from the past to possible futures.

  3. Analysis of archaeological precious stones from Slovenia

    Energy Technology Data Exchange (ETDEWEB)

    Šmit, Ž. [Facully of Mathematics and Physics, University of Ljubljana (Slovenia); Fajfar, H. [Jožef Stefan Institute, Ljubljana (Slovenia); Jeršsek, M. [Slovenian Museum of Natural History, Ljubljana (Slovenia); Knific, T. [National Museum of Slovenia, Ljubljana (Slovenia); Kržic, A. [Higher Vocational Centre, Sezana (Slovenia); Lux, J. [Institute for the Protection of Cultural Heritage of Slovenia, Ljubljana (Slovenia)

    2013-07-01

    Full text: Precious stones have been attractive pieces of jewelry since ancient times. However, due to the limited sources of origin, the quality of applied items mainly depended on long-range commercial relations, but also on fashion. In Antiquity and Late Antiquity, stones much used and sought for were emeralds and garnets. In Slovenia, emeralds are typically related to the early Roman period and are incorporated in the finds of gold jewelry from the graves. Emerald is generally beryl colored by admixture of chromium, though green colors can also be due to admixtures of iron or vanadium. Garnets were increasingly used by various nations of the People Migration period, and mounted in gilded silver or gold objects by 'cloisonne' or 'en cabochon' techniques. In Slovenia, numerous jewelry items containing garnets were found in the graves and in post-Roman fortified settlements. Geologically, according to the admixtures of metal ions, the garnets are divided into several species, while the most common among archaeological finds are almandines and pyropes and their intermediate types. It is also common to divide garnets into five groups, the first two originating from India, the third from Ceylon and the fifth from Czech Republic. The measurements involved presumed emeralds from Roman jewelry finds in Slovenia and comparative samples of beryl from Siberia and Habachtal in Austria. The analysis determined the coloring ions and showed relations between particular stones. For garnets, ten samples from brooches, earrings and rings were selected for the analysis on the basis of previous micro Raman examination. The analysis was performed by a combined PIXE-PIGE technique using proton beam in air. The light elements of Na, Mg, AI were determined according to the emitted gamma rays, while X-rays were used for the elements heavier than silicon. Two X-ray spectra were measured in each measuring point, soft and hard X-ray; the latter was obtained using an

  4. Principles of quantum chemistry

    CERN Document Server

    George, David V

    2013-01-01

    Principles of Quantum Chemistry focuses on the application of quantum mechanics in physical models and experiments of chemical systems.This book describes chemical bonding and its two specific problems - bonding in complexes and in conjugated organic molecules. The very basic theory of spectroscopy is also considered. Other topics include the early development of quantum theory; particle-in-a-box; general formulation of the theory of quantum mechanics; and treatment of angular momentum in quantum mechanics. The examples of solutions of Schroedinger equations; approximation methods in quantum c

  5. Quantum chemistry an introduction

    CERN Document Server

    Kauzmann, Walter

    2013-01-01

    Quantum Chemistry: An Introduction provides information pertinent to the fundamental aspects of quantum mechanics. This book presents the theory of partial differentiation equations by using the classical theory of vibrations as a means of developing physical insight into this essential branch of mathematics.Organized into five parts encompassing 16 chapters, this book begins with an overview of how quantum mechanical deductions are made. This text then describes the achievements and limitations of the application of quantum mechanics to chemical problems. Other chapters provide a brief survey

  6. The ectomycorrhizal fungus Paxillus involutus converts organic matter in plant litter using a trimmed brown-rot mechanism involving Fenton chemistry

    Science.gov (United States)

    Rineau, Francois; Roth, Doris; Shah, Firoz; Smits, Mark; Johansson, Tomas; Canbäck, Björn; Olsen, Peter Bjarke; Persson, Per; Grell, Morten Nedergaard; Lindquist, Erika; Grigoriev, Igor V; Lange, Lene; Tunlid, Anders

    2012-01-01

    Soils in boreal forests contain large stocks of carbon. Plants are the main source of this carbon through tissue residues and root exudates. A major part of the exudates are allocated to symbiotic ectomycorrhizal fungi. In return, the plant receives nutrients, in particular nitrogen from the mycorrhizal fungi. To capture the nitrogen, the fungi must at least partly disrupt the recalcitrant organic matter–protein complexes within which the nitrogen is embedded. This disruption process is poorly characterized. We used spectroscopic analyses and transcriptome profiling to examine the mechanism by which the ectomycorrhizal fungus Paxillus involutus degrades organic matter when acquiring nitrogen from plant litter. The fungus partially degraded polysaccharides and modified the structure of polyphenols. The observed chemical changes were consistent with a hydroxyl radical attack, involving Fenton chemistry similar to that of brown-rot fungi. The set of enzymes expressed by Pa. involutus during the degradation of the organic matter was similar to the set of enzymes involved in the oxidative degradation of wood by brown-rot fungi. However, Pa. involutus lacked transcripts encoding extracellular enzymes needed for metabolizing the released carbon. The saprotrophic activity has been reduced to a radical-based biodegradation system that can efficiently disrupt the organic matter–protein complexes and thereby mobilize the entrapped nutrients. We suggest that the released carbon then becomes available for further degradation and assimilation by commensal microbes, and that these activities have been lost in ectomycorrhizal fungi as an adaptation to symbiotic growth on host photosynthate. The interdependence of ectomycorrhizal symbionts and saprophytic microbes would provide a key link in the turnover of nutrients and carbon in forest ecosystems. PMID:22469289

  7. Megaliths, myths and men an introduction to astro-archaeology

    CERN Document Server

    Brown, Peter Lancaster

    2000-01-01

    As commonly used, the term ""megaliths"" refers to huge, free-standing, neolithic stones whose origin and meaning have long been debated by archaeologists and students of prehistory. Perhaps the most famous neolithic site is Stonehenge, the great circle of giant stones on Salisbury Plain in England. Twentieth-century studies of Stonehenge and other megalithic monuments have given rise to the science of astra-archaeology, i.e, the study of early astronomical knowledge through the interpretation of ancient monuments and other archaeological data.The present volume, by a noted British astronomer

  8. The Sustainability of Dental Calculus for Archaeological Research

    DEFF Research Database (Denmark)

    Mackie, Meaghan Emma; Radini, Anita; Speller, Camilla

    Dental calculus is a mineralized plaque biofilm formed by microbiota of the oral microbiome. Until recently, the information potential of dental calculus for archaeological study was not fully realised and it was often discarded. However, it is now recognized that dental calculus entombs and pres......Dental calculus is a mineralized plaque biofilm formed by microbiota of the oral microbiome. Until recently, the information potential of dental calculus for archaeological study was not fully realised and it was often discarded. However, it is now recognized that dental calculus entombs...... and preserve biomolecules related to diet, health and disease....

  9. Geophysical survey of the Burnum archaeological site (Croatia)

    Science.gov (United States)

    Boschi, Federica; Campedelli, Alessandro; Giorgi, Enrico; Lepore, Giuseppe; de Maria, Sandro

    2010-05-01

    A multidisciplinary geophysical investigation has been carried out at the site of Burnum (Krka Valley, Croatia) by the University of Bologna, in the context of an international agreement between the University of Zadar, the Civic Museum of Drniš, and the Centre for the Study of the Adriatic Sea Archaeology (Ravenna). The Burnum Project aims at improving our knowledge and preserve the important roman castrum, transformed in a municipium at the beginning of the 2nd century AD. Since 2005, different geophysical techniques have been applied to the site, such as magnetometry, electrical resistivity studies and ground penetrating radar, making the investigated area an interesting case history of a multidisciplinary approach applied to archaeology. After different field works, the geophysical mapping of the southern part of the castrum is almost complete, whereas the northern one will be completed during next planned campaigns. Magnetic data have been collected with the gradient technique, using an Overhauser system and an optically-pumped Potassium magnetometer-gradiometer, configured with a vertical sensor distance of 1.50 m. The resistivity method has been applied using the ARP© (Automatic Resistivity Profiling) and the OhM Mapper systems. GPR surveys have been carried out testing different systems and antennas. During 2009, a special emphasis was given to the acquisition, processing and interpretation of the optically-pumped Potassium magnetometer-gradiometer data. As a result, a clear image of the settlement configuration was obtained, improving our knowledge of the forum-basilica complex and possibly discovering a second auxiliary castrum. Direct exploration by archaeological excavations of selected areas has correctly confirmed the geophysical results and the archaeological interpretation proposed. The features of the building materials, brought to the light and analysed after the excavations, were coherent with the instrumental responses of all the applied

  10. Marine archaeological explorations on the southwestern coast of Saurashtra, India

    Digital Repository Service at National Institute of Oceanography (India)

    Gaur, A.S.; Tripati, S.

    to those reported from Rangpur (Rao 1962-63), Bet Dwarka (Gaur and Sundaresh 2003) and Rojdi (Possehl 1989). 82 | JOURNAL OF INDIAN OCEAN ARCHAEOLOGY No.3, 2006 Stone Anchors Different types of 5 stone anchors have been noticed at Miyani, Srinagar... 1: 133-140 Rao, S.R. 1962-63. Excavations at Rangpur and other explorations in Gujarat, Ancient India 18-19:5-207 Rao, S R. 1979 Lothal-A Harappan Port Town Part I. New Delhi: Archaeological Survey of India. Rao, S.R 1990. Excavations...

  11. MUSEUMS: A STRATEGY TO PRESERVE ARCHAEOLOGICAL SITES IN CAMPECHE, MEXICO

    Directory of Open Access Journals (Sweden)

    Marisol Ordaz Tamayo

    2015-03-01

    Full Text Available Mexico’s long history and rich cultural diversity translates into an equally rich offer of national patrimony. That offer, both national and international in scope, adopts diverse formats, such as and/ or archaeological parks. Several Maya archaeological sites in the state of have been exposed without previous planning for their conservation, management, and further research. This leads to and, consequently, their devaluation as a priceless patrimonial heritage. This study explores the prospect and of a community and museum-based strategy as a key to integrate the value of said sites as educational, cultural, economic, and tourist assets and contributing factors to the region’s sustainable

  12. The ARROWS project: adapting and developing robotics technologies for underwater archaeology

    OpenAIRE

    Allotta,Benedetto; Costanzi, Riccardo; Ridolfi, Alessandro; Colombo, Carlo; Bellavia, Fabio; Fanfani, Marco; Pazzaglia, Fabio; Salvetti, Ovidio; Moroni, Davide; Pascali, Maria Antonietta; Reggiannini, Marco; Kruusmaa, Maarja; Salumae, Taavi; Frost, Gordon; Tsiogkas, Nikolaos

    2015-01-01

    ARchaeological RObot systems for the World's Seas (ARROWS) EU Project proposes to adapt and develop low-cost Autonomous Underwater Vehicle (AUV) Technologies to significantly reduce the cost of archaeological operations, covering the full extent of archaeological campaign. ARROWS methodology is to identify the archaeologists requirements in all phases of the campaign and to propose related technological solutions. Starting from the necessities identified by archaeological project partners in ...

  13. Comet Halley and interstellar chemistry

    International Nuclear Information System (INIS)

    How complex is the chemistry of the interstellar medium? How far does it evolve and how has it interacted with the chemistry of the solar system? Are the galactic chemical processes destroyed, preserved, or even enhanced in comets? Are biogenic molecules formed in space and have the formation mechanisms interacted in any way with prebiotic organic chemical processes on the early earth? Radio molecular studies of comets are important for probing deep into the coma and nuclear region and thus may help answer these questions. Comets are believed to be pristine samples of the debris left from the formation of the solar system and may have been the carrier between interstellar and terrestrial prebiotic chemistries. Recent observations of Comet Halley and subsequent comets have given the author an excellent opportunity to study the relationship between interstellar molecular chemistry and cometary chemistry

  14. 76 FR 28072 - Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology and Anthropology...

    Science.gov (United States)

    2011-05-13

    ... National Park Service Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology and... Archaeology and Anthropology, Philadelphia, PA. The human remains were removed from St. Mary Parish (formerly... assessment of the human remains was made by University of Pennsylvania Museum of Archaeology and...

  15. 78 FR 19301 - Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology and Anthropology...

    Science.gov (United States)

    2013-03-29

    ... National Park Service Notice of Inventory Completion: University of Pennsylvania Museum of Archaeology and... of Pennsylvania Museum of Archaeology and Anthropology has completed an inventory of human remains... Pennsylvania Museum of Archaeology and Anthropology. Repatriation of the human remains to the Indian...

  16. 75 FR 28648 - Notice of Inventory Completion: Peabody Museum of Archaeology and Ethnology, Harvard University...

    Science.gov (United States)

    2010-05-21

    ... National Park Service Notice of Inventory Completion: Peabody Museum of Archaeology and Ethnology, Harvard... completion of an inventory of human remains in the possession of the Peabody Museum of Archaeology and... remains was made by the Peabody Museum of Archaeology and Ethnology professional staff in...

  17. 76 FR 14047 - Notice of Intent To Repatriate Cultural Items: Peabody Museum of Archaeology and Ethnology...

    Science.gov (United States)

    2011-03-15

    ... National Park Service Notice of Intent To Repatriate Cultural Items: Peabody Museum of Archaeology and... Archaeology and Ethnology, Harvard University, Cambridge, MA, that meet the definition of unassociated... ornaments was donated to the Peabody Museum of Archaeology and Ethnology by Mary S. Felton and Dr....

  18. 77 FR 59968 - Notice of Intent To Repatriate Cultural Items: Stanford University Archaeology Center, Stanford, CA

    Science.gov (United States)

    2012-10-01

    ... National Park Service Notice of Intent To Repatriate Cultural Items: Stanford University Archaeology Center... Archaeology Center, in consultation with the appropriate Indian tribes, has determined that the cultural items... affiliated with the cultural items may contact the Stanford University Archaeology Center....

  19. The sixth Nordic conference on the application of scientific methods in archaeology

    International Nuclear Information System (INIS)

    The Sixth Nordic Conference on the Application of Scientific Methods in Archaeology with 73 participants was convened in Esbjerg (Denmark), 19-23 September 1993. Isotope dating of archaeological, paleoecological and geochronological objects, neutron activation and XRF analytical methods, magnetometry, thermoluminescence etc. have been discussed. The program included excursions to archaeological sites and a poster session with 12 posters. (EG)

  20. Testing Corrosion Inhibitors for the Conservation of Archaeological Copper and Copper Alloys

    Directory of Open Access Journals (Sweden)

    Robert B. Faltermeier

    1997-11-01

    Full Text Available This is a synopsis of the Ph.D. research undertaken at the Institute of Archaeology, University College London. The aim was to evaluate corrosion inhibitors for use in the conservation of copper and copper alloy archaeological artefacts. The objective of this work was to acquire an insight into the performance of copper corrosion inhibitors, when applied to archaeological copper.

  1. A Brief Discussion of New Archaeology%新考古学论纲

    Institute of Scientific and Technical Information of China (English)

    沈颂金

    2001-01-01

    Neoarchaeology in America began in the 1950s, which challenged the traditional archaeology. Neoarchaeologists focused their attention on cultural ecology, used advanced scientific techniques such as computer and 14C dating, and applied new theory and method in the study of archaeological data. This approach was a revolution in the history of archaeology.

  2. Pioneers, publishers and the dissemination of archaeological knowledge: A study of publishing in British archaeology 1816-1851

    Directory of Open Access Journals (Sweden)

    Sarah Scott

    2013-08-01

    Full Text Available The first half of the nineteenth century was a formative period in the development of archaeology as a discipline and archaeological publishing played a key role in this. Libraries were an essential marker of social and intellectual status and there now exists a considerable body of scholarship on the most impressive publications of the day and on the factors influencing their presentation; for example, in relation to the publication of Mediterranean classical antiquities. The crucial role which publishers played in the selection and dissemination of scholarship has been addressed in recent studies of the history of the book, and there is a growing literature on the role of publishers in the dissemination of scientific knowledge, but there has to date been very limited evaluation of the role of publishers in the selection and dissemination of archaeological knowledge in Britain in this period. This study will investigate the extent to which the publication and dissemination of archaeological knowledge, and hence the discipline itself, was shaped by the intellectual and/or commercial concerns of publishers, with a view to providing a more nuanced understanding of the ways in which knowledge was filtered and the impact that this had. Key trends in archaeological publishing in the period 1816-51 will be identified, based on the London Catalogue of Books, and will show how and why this kind of study should be seen as an essential component of any research which considers the history of the discipline. Selected case studies will show the immense, and previously unacknowledged, importance of decisions made during the publication process on the development of archaeology in Britain, and directions for further study will be identified.

  3. Archaeological Geophysics in Israel: Past, Present and Future

    Science.gov (United States)

    Eppelbaum, L. V.

    2009-04-01

    Israel is a country with diverse and rapidly changeable environments where is localized a giant number of archaeological objects of various age, origin and size. The archaeological remains occur in a complex (multi-layered and variable) geological-archaeological media. It is obvious that direct archaeological excavations cannot be employed at all localized and supposed sites taking into account the financial, organizational, ecological and other reasons. Therefore, for delineation of buried archaeological objects, determination their physical-geometrical characteristics and classification, different geophysical methods are widely applied. The number of employed geophysical methodologies is constantly increasing and now Israeli territory may be considered as a peculiar polygon for various geophysical methods testing. The geophysical investigations at archaeological sites in Israel could be tentatively divided on three stages: (1) past [- 1990] (e.g., Batey, 1987; Ben-Menahem, 1979; Dolphin, 1981; Ginzburg and Levanon, 1977; Karcz et al., 1977; Karcz and Kafri, 1978; Tanzi et al., 1983; Shalem, 1949; Willis, 1928), (2) present [1991 - 2008] (e.g., Bauman et al., 2005; Ben-Dor et al., 1999; Ben-Yosef et al., 2008; Berkovitch et al., 2000; Borradaile, 2003; Boyce et al., 2004; Bruins et al., 2003; Daniels et al., 2003; Ellenblum et al., 1998; Eppelbaum, 1999, 2000a, 2000b, 2005, 2007a, 2007b, 2008b; Eppelbaum and Ben-Avraham, 2002; Eppelbaum and Itkis, 2000, 2001; 2003, 2009; Eppelbaum et al., 2000a, 2000b, 2001a, 2001b, 2003a, 2003b, 2004a, 2004b; 2005, 2006a, 2006b, 2006c, 2006d, 2007, 2009a, 2009b; Ezersky et al., 2000; Frumkin et al., 2003; Itkis and Eppelbaum, 1998; Itkis, 2003; Itkis et al., 2002, 2003, 2008; Jol et al., 2003, 2008; Kamai and Hatzor, 2007; Khesin et al., 1996; Korjenkov and Mazor, 1999; Laukin et al., 2001; McDermott et al., 1993; Marco, 2008; Marco et al., 2003; Nahas et al., 2006; Neishtadt et al., 2006; Nur and Ron, 1997; Paparo, 1991; Porat

  4. Organometallic chemistry

    OpenAIRE

    Bashkin, James K.; M.L.H. Green; Dr. M. L. H. Green

    1982-01-01

    Transition metal organometallic chemistry is a rapidly expanding field, which has an important relationship to industrial problems of petrochemical catalysis. This thesis describes studies of fundamental organometallic reaction processes, such as C-H and C-C bond formation and cleavage, and investigations of the structure and bonding of organometallic compounds. A number of techniques were used to pursue these studies, including synthesis, X-ray crystallography, and semi-em...

  5. Disk Chemistry*

    OpenAIRE

    Thi Wing-Fai

    2015-01-01

    The chemical species in protoplanetary disks react with each other. The chemical species control part of the thermal balance in those disks. How the chemistry proceeds in the varied conditions encountered in disks relies on detailed microscopic understanding of the reactions through experiments or theoretical studies. This chapter strives to summarize and explain in simple terms the different types of chemical reactions that can lead to complex species. The first part of the chapter deals wit...

  6. Interstellar chemistry

    OpenAIRE

    Klemperer, William

    2006-01-01

    In the past half century, radioastronomy has changed our perception and understanding of the universe. In this issue of PNAS, the molecular chemistry directly observed within the galaxy is discussed. For the most part, the description of the molecular transformations requires specific kinetic schemes rather than chemical thermodynamics. Ionization of the very abundant molecular hydrogen and atomic helium followed by their secondary reactions is discussed. The rich variety of organic species o...

  7. Modeling group size and scalar stress by logistic regression from an archaeological perspective.

    Directory of Open Access Journals (Sweden)

    Gianmarco Alberti

    Full Text Available Johnson's scalar stress theory, describing the mechanics of (and the remedies to the increase in in-group conflictuality that parallels the increase in groups' size, provides scholars with a useful theoretical framework for the understanding of different aspects of the material culture of past communities (i.e., social organization, communal food consumption, ceramic style, architecture and settlement layout. Due to its relevance in archaeology and anthropology, the article aims at proposing a predictive model of critical level of scalar stress on the basis of community size. Drawing upon Johnson's theory and on Dunbar's findings on the cognitive constrains to human group size, a model is built by means of Logistic Regression on the basis of the data on colony fissioning among the Hutterites of North America. On the grounds of the theoretical framework sketched in the first part of the article, the absence or presence of colony fissioning is considered expression of not critical vs. critical level of scalar stress for the sake of the model building. The model, which is also tested against a sample of archaeological and ethnographic cases: a confirms the existence of a significant relationship between critical scalar stress and group size, setting the issue on firmer statistical grounds; b allows calculating the intercept and slope of the logistic regression model, which can be used in any time to estimate the probability that a community experienced a critical level of scalar stress; c allows locating a critical scalar stress threshold at community size 127 (95% CI: 122-132, while the maximum probability of critical scale stress is predicted at size 158 (95% CI: 147-170. The model ultimately provides grounds to assess, for the sake of any further archaeological/anthropological interpretation, the probability that a group reached a hot spot of size development critical for its internal cohesion.

  8. Computational chemistry

    Science.gov (United States)

    Arnold, J. O.

    1987-01-01

    With the advent of supercomputers, modern computational chemistry algorithms and codes, a powerful tool was created to help fill NASA's continuing need for information on the properties of matter in hostile or unusual environments. Computational resources provided under the National Aerodynamics Simulator (NAS) program were a cornerstone for recent advancements in this field. Properties of gases, materials, and their interactions can be determined from solutions of the governing equations. In the case of gases, for example, radiative transition probabilites per particle, bond-dissociation energies, and rates of simple chemical reactions can be determined computationally as reliably as from experiment. The data are proving to be quite valuable in providing inputs to real-gas flow simulation codes used to compute aerothermodynamic loads on NASA's aeroassist orbital transfer vehicles and a host of problems related to the National Aerospace Plane Program. Although more approximate, similar solutions can be obtained for ensembles of atoms simulating small particles of materials with and without the presence of gases. Computational chemistry has application in studying catalysis, properties of polymers, all of interest to various NASA missions, including those previously mentioned. In addition to discussing these applications of computational chemistry within NASA, the governing equations and the need for supercomputers for their solution is outlined.

  9. Finding Folk Religion: An Archaeology of ‘Strange’ Behaviour

    Directory of Open Access Journals (Sweden)

    Sonja Hukantaival

    2013-12-01

    Full Text Available Archaeology is not only about describing things; we also seek to understand what we find. Sometimes a find can seem puzzling, unexpected in the context in question. It is argued here that evidence of non-Christian elements of religiosity in a historical context can constitute such surprising finds. These finds become less confusing in the light of other sources, such as folklore accounts and historical records. Still, archaeology can offer something not accessible to other disciplines. This paper discusses the phenomenon of folk religion, and the ways that we can take to find the meanings behind the material remains of practices, which may perhaps seem odd to us. A multidisciplinary approach is favoured, and the contribution of archaeology is crucial in gaining information about past practices. The paper also offers a short survey of some archaeological approaches to questions of folk religion. Another issue addressed is why we might be surprised to find evidence of ‘strange’ practices in historical contexts. It is suggested here that historical constructs about the ‘civilising’ effects of Christianity, Reformation, and Enlightenment, respectively, have affected the way that religiosity has been seen in the context of historical Europe.

  10. Teaching the Impact of Globalization through Historical Archaeology.

    Science.gov (United States)

    Stewart, Marilyn C.

    Historical archaeology has evolved from an early preoccupation with famous houses and forts to a study of capitalism around the world. Archaeologists study the cultures and interrelationships of the colonizers and the colonized as they negotiated their places in an ever-expanding world system. Recent studies in South Africa, Latin America, and the…

  11. Galactic Archaeology with the Subaru Prime Focus Spectrograph

    Science.gov (United States)

    Chiba, Masashi; Cohen, Judith; Wyse, Rosemary F. G.

    2016-08-01

    We present an overview of our Galactic Archaeology (GA) survey program with the Prime Focus Spectrograph (PFS) for Subaru. Following successful design reviews, the instrument is now under construction with first light anticipated in 2018. Main characteristics of PFS and the science goals in our PFS/GA program are described.

  12. The Archaeology Education Handbook: Sharing the Past with Kids.

    Science.gov (United States)

    Smardz, Karolyn, Ed.; Smith, Shelley J., Ed.

    This guidebook outlines the culture and structure of schools and shows how archaeologists can work with teachers, curriculum developers, museum professionals, and park rangers to develop useful programs in archaeological education both in the classroom and in informal settings. The essays strive to provide multiple examples of exemplary…

  13. Applying Foucault's "Archaeology" to the Education of School Counselors

    Science.gov (United States)

    Shenker, Susan S.

    2008-01-01

    Counselor educators can utilize the ideas of philosopher Michel Foucault in preparing preservice school counselors for their work with K-12 students in public schools. The Foucaultian ideas of "governmentality," "technologies of domination," "received truths," "power/knowledge," "discontinuity," and "archaeology" can contribute to students'…

  14. Moessbauer, XRD, NAA and XRF study of archaeological slag

    International Nuclear Information System (INIS)

    In 1960, remains of four furnaces from Early Medieval Age were excavated in Nitra. Because a lot of glass-like findings were found on this site the function of furnaces was considered as being used for production of glass even though no analytical tests were performed. These dig-outs were divided into two groups: The first group contains dark glass-like archaeological fragments which were interpreted as a waste (slag) of a glass production. The second group consists of archaeological artefacts which were thought to be a slag from iron production. The main aim of this work is to investigate these two types of archaeological artefacts. Employing standard transmission geometry Moessbauer effect experiments, iron crystallographic sites are identified and compared. In all samples, Fe2+ and Fe3+ structural positions were revealed. In addition, some of the archaeological artefacts that are presumably coming from glass production show traces of metallic iron. On the other hand, slag from iron production exhibit minute contribution of iron oxides in several instances. Additional information about the composition of slag is obtained from X-ray diffraction (XRD), neutron activation analysis (NAA), and X-ray fluorescence (XRF) measurements. (authors)

  15. Saxon Obsequies: the Early Medieval Archaeology of Richard Cornwallis Neville

    Directory of Open Access Journals (Sweden)

    Howard Williams

    2013-04-01

    Full Text Available This paper investigates the origins of British Anglo-Saxon archaeology by focusing on the work of one early Victorian archaeologist: Richard Cornwallis Neville. The seemingly descriptive and parochial nature of Neville’s archaeological pursuits, together with the attention he afforded to Romano-British remains, has impeded due recognition, and critical scrutiny, of his contributions to the development of early Medieval burial archaeology. Using his archaeological publications as source material, I will show how Neville’s interpretations of Saxon graves were a form of memory work, defining his personal, familial and martial identity in relation to the landscape and locality of his aristocratic home at Audley End, near Saffron Walden, Essex. Subsequently, I argue that Neville’s prehistoric and Romano-British discoveries reveal his repeated concern with the end of Roman Britain and its barbarian successors. Finally, embodied within Neville’s descriptions of early Medieval graves and their location we can identify a pervasive Anglo-Saxonism. Together these strands of argument combine to reveal how, for Neville, Saxon graves constituted a hitherto unwritten first chapter of English history that could be elucidated through material culture and landscape.

  16. Ethnographic Households and Archaeological Interpretations: A Case from Iranian Kurdistan.

    Science.gov (United States)

    Kramer, Carol

    1982-01-01

    Shows how archaeological interpretation based strictly on the evidence of architectural remains may lead to inaccurate conclusions about social patterns in extinct societies. An ethnographic study of an Iranian Kurdish village is used to illustrate the possible variations of residential social relationships within buildings with similar…

  17. A Survey of Archaeological Samples Dated in 1984

    DEFF Research Database (Denmark)

    Mejdahl, Vagn

    A survey is given of archaeological samples dated in 1984 at the Nordic Laboratory for Thermoluminescence Dating. A total of 79 samples were dated, 49 of which were burnt stones. All results were corrected for fading as measured for samples stored for four weeks at room temperature. The alpha dose...

  18. Texture Attribute Analysis of GPR Data for Archaeological Prospection

    Science.gov (United States)

    Zhao, Wenke; Forte, Emanuele; Pipan, Michele

    2016-08-01

    We evaluate the applicability and the effectiveness of texture attribute analysis of 2-D and 3-D GPR datasets obtained in different archaeological environments. Textural attributes are successfully used in seismic stratigraphic studies for hydrocarbon exploration to improve the interpretation of complex subsurface structures. We use a gray-level co-occurrence matrix (GLCM) algorithm to compute second-order statistical measures of textural characteristics, such as contrast, energy, entropy, and homogeneity. Textural attributes provide specific information about the data, and can highlight characteristics as uniformity or complexity, which complement the interpretation of amplitude data and integrate the features extracted from conventional attributes. The results from three archaeological case studies demonstrate that the proposed texture analysis can enhance understanding of GPR data by providing clearer images of distribution, volume, and shape of potential archaeological targets and related stratigraphic units, particularly in combination with the conventional GPR attributes. Such strategy improves the interpretability of GPR data, and can be very helpful for archaeological excavation planning and, more generally, for buried cultural heritage assessment.

  19. Putting papyri into archaeological context: new insights from Tebtunis, Egypt

    Directory of Open Access Journals (Sweden)

    Andrew Monson

    2001-10-01

    Full Text Available For more than a century, scholars have studied the ancient Egyptian texts written on rolls of papyrus that have been found in tombs, temples and cemeteries. But it is only recently that systematic attempts have been made, as at the site of Tebtunis in the Fayum oasis, to relate such texts to the archaeological contexts from which they came.

  20. Strategies for Teaching Maritime Archaeology in the Twenty First Century

    Science.gov (United States)

    Staniforth, Mark

    2008-12-01

    Maritime archaeology is a multi-faceted discipline that requires both theoretical learning and practical skills training. In the past most universities have approached the teaching of maritime archaeology as a full-time on-campus activity designed for ‘traditional’ graduate students; primarily those in their early twenties who have recently come from full-time undergraduate study and who are able to study on-campus. The needs of mature-age and other students who work and live in different places (or countries) and therefore cannot attend lectures on a regular basis (or at all) have largely been ignored. This paper provides a case study in the teaching of maritime archaeology from Australia that, in addition to ‘traditional’ on-campus teaching, includes four main components: (1) learning field methods through field schools; (2) skills training through the AIMA/NAS avocational training program; (3) distance learning topics available through CD-ROM and using the Internet; and (4) practicums, internships and fellowships. The author argues that programs to teach maritime archaeology in the twenty first century need to be flexible and to address the diverse needs of students who do not fit the ‘traditional’ model. This involves collaborative partnerships with other universities as well as government underwater cultural heritage management agencies and museums, primarily through field schools, practicums and internships.

  1. Out of the archaeologist's desk drawer: communicating archaeological data online

    Science.gov (United States)

    Abate, D.; David, M.

    2015-08-01

    During archaeological field work a huge amount of data is collected, processed and elaborated for further studies and scientific publications. However, access and communication of linked data; associated tools for interrogation, analysis and sharing are often limited at the first stage of the archaeological research, mainly due to issues related to IPR. Information is often released months if not years after the fieldwork. Nowadays great deal of archaeological data is `born digital' in the field or lab. This means databases, pictures and 3D models of finds and excavation contexts could be available for public communication and sharing. Researchers usually restrict access to their data to a small group of people. It follows that data sharing is not so widespread among archaeologists, and dissemination of research is still mostly based on traditional pre-digital means like scientific papers, journal articles and books. This project has implemented a web approach for sharing and communication purposes, exploiting mainly open source technologies which allow a high level of interactivity. The case study presented is the newly Mithraeum excavated in Ostia Antica archaeological site in the framework of the Ostia Marina Project.

  2. Archaeological analogs and corrosion; Analogues archeologiques et corrosion

    Energy Technology Data Exchange (ETDEWEB)

    David, D

    2008-07-01

    In the framework of the high level and long life radioactive wastes disposal deep underground, the ANDRA built a research program on the material corrosion. In particular they aim to design containers for a very long time storage. Laboratory experiments are in progress and can be completed by the analysis of metallic archaeological objects and their corrosion after hundred years. (A.L.B.)

  3. Trace element analysis of archaeological artefacts from Pella, Jordan

    International Nuclear Information System (INIS)

    A brief history of the site at Pella, Jordan is presented, as a prelude to an analysis of the element composition of 82 pottery sherds. Statistical results from this data support the archaeological evidence for occupation during the Late Bronze and Early Iron Age

  4. Archaeological and Geological dating by means of thermoluminescence; Fechamiento geologico y arqueologico por termoluminiscencia

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez M, P.R

    1999-07-01

    In this thesis an specific method for dating local archaeological and geological samples based on the phenomenon of thermoluminescence (TL) using the fine grain and quartz inclusion techniques is developed. Taking into account that this work is interesting for professionals working in the fields of Physics, Chemistry, Archaeology, Anthropology and related sciences, some basic concepts are described to have a better comprehension. Chapter 1 describes the concept of radioactivity, remarking the importance of the different decay types as well as the main radioactive series and the energy liberated in the process. The causes of radioactive desequilibrium are also considered in the case for radon. Another important aspect taken into account in this chapter is the radioisotope production and its relationship with the neutron activation analysis used for the determination of the Uranium and Thorium concentrations in the samples. The TL phenomenon is described in Chapter 2, emphasizing the importance of the process of thermally stimulated luminescence best known as TL and its application for dating minerals of different origin. Chapter 3 shows some important antecedents remarking some aspects of the techniques commonly used for dating purposes. Chapter 4 shows the different methods used for the sample preparation. The techniques used for the {sup 40} K, {sup 238} U and {sup 232} Th determination as well as for the cosmic radiation measurement using locally made TLD are also described. The methods used for the determination of the paleodosis as a function of the TL intensity of each sample are described: special emphasis is taken on the moisture effects as well as in the error limits in the age estimation. Results and conclusions of this study are presented in Chapter 5. These results gave an age of 980 {+-} 90 years for the Edzna ceramic and 1520 {+-} 90 years for the Calixtlahuaca ceramics. The age of the Teotihuacan ceramics was not estimated due to the lack of a stable

  5. Book Review: Interdisciplinary Archaeological Research Programme Maasvlakte 2

    Science.gov (United States)

    Innes, J. B.

    2015-10-01

    Archaeological investigation in wetland environments has long been recognised as a specialised aspect of the discipline, where the levels of preservation of organic materials and sediments can be so high that cultural horizons and excavated artefacts can be placed into detailed palaeo-environmental, biological and landscape contexts, in contrast to the more limited information of this kind that is available from dryland archaeological sites. Inevitably, the recovery, integration and understanding of these vital additional data require an interdisciplinary approach and an investment in specialist equipment and scientific analyses if their full potential for reconstructing human occupation and site use within their landscape setting is to be fully realised. The mobilisation and integration of such a team of environmental specialists can require major financial resources, meticulous planning and close co-operation between the various disciplines involved. The most extreme example of wetland archaeology is probably integrated excavation and environmental archaeological research in subtidal locations, but modern development of major coastal infrastructure is increasingly making sites available for study from the early to mid-Holocene or even earlier that have been overwhelmed by sea-level rise and which would otherwise be beyond the reach of archaeological investigation. Such very large scale subtidal interdisciplinary research projects are major, expensive and long-term undertakings and are still rare enough to be publication highlights in the discipline of environmental archaeology. Important recent examples of subtidal work in north-west Europe include Pedersen et al. (1997) and elements of Fischer (1995) in south Scandinavia, and investigations off southern England (Allen and Gardiner, 2000; Momber et al., 2011; Sturt et al., 2014). Research on submerged palaeoenvironments and palaeolandscapes has also seen significant advances (Griffiths et al., 2015), with the

  6. Qualitative and Quantitative Data on the Use of the Internet for Archaeological Information

    Directory of Open Access Journals (Sweden)

    Lorna-Jane Richardson

    2015-04-01

    Full Text Available These survey results are from an online survey of 577 UK-based archaeological volunteers, professional archaeologists and archaeological organisations. These data cover a variety of topics related to how and why people access the Internet for information about archaeology, including demographic information, activity relating to accessing information on archaeological topics, archaeological sharing and networking and the use of mobile phone apps and QR codes for public engagement. There is wide scope for further qualitative and quantitative analysis of these data.

  7. Modelling Vague Knowledge for Decision Support in Planning Archaeological Prospections

    Science.gov (United States)

    Boos, S.; Hornung, S.; Müller, H.

    2012-07-01

    Most archaeological predictive models lack significance because fuzziness of data and uncertainty in knowledge about human behaviour and natural processes are hardly ever considered. One possibility to cope with such uncertainties is utilization of probability based approaches like Bayes Theorem or Dempster-Shafer-Theory. We analyzed an area of 50 km2 in Rhineland Palatinate (Germany) near a Celtic oppidum by use of Dempster-Shafer's theory of evidence for predicting spatial probability distribution of archaeological sites. This technique incorporates uncertainty by assigning various weights of evidence to defined variables, in that way estimating the probability for supporting a specific hypothesis (in our case the hypothesis presence or absence of a site). Selection of variables for our model relied both on assumptions about settlement patterns and on statistically tested relationships between known archaeological sites and environmental factors. The modelling process was conducted in a Geographic Information System (GIS) by generating raster-based likelihood surfaces. The corresponding likelihood surfaces were aggregated to a final weight of evidence surface, which resulted in a likelihood value for every single cell of being a site or a non-site. Finally the result was tested against a database of known archaeological sites for evaluating the gain of the model. For the purpose of enhancing the gain of our model and sharpening our criteria we used a two-step approach to improve the modelling of former settlement strategies in our study area. Applying the developed model finally yielded a 100 percent success rate of known archaeological sites located in predicted high potential areas.

  8. Formation of Carbon Nanotube Based Gears: Quantum Chemistry and Molecular Mechanics Study of the Electrophilic Addition of o-Benzyne to Fullerenes, Graphene, and Nanotubes

    Science.gov (United States)

    Jaffe, Richard; Han, Jie; Globus, Al; Chancellor, Marisa K. (Technical Monitor)

    1997-01-01

    Considerable progress has been made in recent years in chemical functionalization of fullerene molecules. In some cases, the predominant reaction products are different from those obtained (using the same reactants) from polycyclic aromatic hydrocarbons (PAHs). One such example is the cycloaddition of o-benzyne to C60. It is well established that benzyne adds across one of the rings in naphthalene, anthracene and other PAHs forming the [2+4] cycloaddition product (benzobicyclo[2.2.2.]-octatriene with naphthalene and triptycene with anthracene). However, Hoke et al demonstrated that the only reaction path for o-benzyne with C60 leads to the [2+2] cycloaddition product in which benzyne adds across one of the interpentagonal bonds (forming a cyclobutene ring in the process). Either reaction product results in a loss of aromaticity and distortion of the PAH or fullerene substrate, and in a loss of strain in the benzyne. It is not clear, however, why different products are preferred in these cases. In the current paper, we consider the stability of benzyne-nanotube adducts and the ability of Brenner's potential energy model to describe the structure and stability of these adducts. The Brenner potential has been widely used for describing diamondoid and graphitic carbon. Recently it has also been used for molecular mechanics and molecular dynamics simulations of fullerenes and nanotubes. However, it has not been tested for the case of functionalized fullerenes (especially with highly strained geometries). We use the Brenner potential for our companion nanogear simulations and believe that it should be calibrated to insure that those simulations are physically reasonable. In the present work, Density Functional theory (DFT) calculations are used to determine the preferred geometric structures and energetics for this calibration. The DFT method is a kind of ab initio quantum chemistry method for determining the electronic structure of molecules. For a given basis set

  9. Exhibition Season: Annual Archaeological Exhibitions in London, 1880s-1930s

    Directory of Open Access Journals (Sweden)

    Amara Thornton

    2015-03-01

    Full Text Available Annual archaeological exhibitions were a visible symbol of archaeological research. Held mainly in London, the displays encapsulated a network of archaeologists, artists, architects and curators, and showcased the work of the first generations of trained archaeologists. The exhibition catalogues and published reviews of the displays provide a unique method for exploring the reception and sponsorship of archaeological work overseas and its promotion to a fascinated, well connected and well moneyed public. The exhibitions were a space in which conversation and networking were as important as educational enrichment. This paper analyses the social history of the “annual exhibition” in archaeology, highlighting the development and maintenance of the networks behind archaeological research, the geography of London as a way to examine influence in archaeology, and the utility of exhibitions for archaeological publicity during this period of exploration.

  10. Domain-Specific Formal Ontology of Archaeology and Its Application in Knowledge Acquisition and Analysis

    Institute of Scientific and Technical Information of China (English)

    Chun-Xia Zhang; Cun-Gen Cao; Fang Gu; Jin-Xin Si

    2004-01-01

    Inherent heterogeneity and distribution of knowledge strongly prevent knowledge from sharing and reusing among different agents and software entities, and a formal ontology has been viewed as a promising means to tackle this problem. In this paper, a domain-specific formal ontology of archaeology is presented. The ontology mainly consists of three parts: archaeological categories, their relationships and axioms. The ontology not only captures the semantics of archaeological knowledge, but also provides archaeology with an explicit and formal specification of a shared conceptualization, thus making archaeological knowledge shareable and reusable across humans and machines in a structured fashion. Further, we propose a method to verify ontology correctness based on the individuals of categories. As applications of the ontology, we have developed an ontology-driven approach to knowledge acquisition from archaeological text and a question answering system for archaeological knowledge.

  11. Large-scale high-resolution non-invasive geophysical archaeological prospection for the investigation of entire archaeological landscapes

    Science.gov (United States)

    Trinks, Immo; Neubauer, Wolfgang; Hinterleitner, Alois; Kucera, Matthias; Löcker, Klaus; Nau, Erich; Wallner, Mario; Gabler, Manuel; Zitz, Thomas

    2014-05-01

    Over the past three years the 2010 in Vienna founded Ludwig Boltzmann Institute for Archaeological Prospection and Virtual Archaeology (http://archpro.lbg.ac.at), in collaboration with its ten European partner organizations, has made considerable progress in the development and application of near-surface geophysical survey technology and methodology mapping square kilometres rather than hectares in unprecedented spatial resolution. The use of multiple novel motorized multichannel GPR and magnetometer systems (both Förster/Fluxgate and Cesium type) in combination with advanced and centimetre precise positioning systems (robotic totalstations and Realtime Kinematic GPS) permitting efficient navigation in open fields have resulted in comprehensive blanket coverage archaeological prospection surveys of important cultural heritage sites, such as the landscape surrounding Stonehenge in the framework of the Stonehenge Hidden Landscape Project, the mapping of the World Cultural Heritage site Birka-Hovgården in Sweden, or the detailed investigation of the Roman urban landscape of Carnuntum near Vienna. Efficient state-of-the-art archaeological prospection survey solutions require adequate fieldwork methodologies and appropriate data processing tools for timely quality control of the data in the field and large-scale data visualisations after arrival back in the office. The processed and optimized visualisations of the geophysical measurement data provide the basis for subsequent archaeological interpretation. Integration of the high-resolution geophysical prospection data with remote sensing data acquired through aerial photography, airborne laser- and hyperspectral-scanning, terrestrial laser-scanning or detailed digital terrain models derived through photogrammetric methods permits improved understanding and spatial analysis as well as the preparation of comprehensible presentations for the stakeholders (scientific community, cultural heritage managers, public). Of

  12. Stellar Archaeology: New Science with Old Stars

    Science.gov (United States)

    Frebel, Anna

    2011-01-01

    The early chemical evolution of the Galaxy and the Universe is vital to our understanding of a host of astrophysical phenomena. Since the most metal-poor Galactic stars are relics from the high-redshift Universe, they probe the chemical and dynamical conditions as the Milky Way began to form, the origin and evolution of the elements, and the physics of nucleosynthesis. They also provide constraints on the nature of the first stars, their associated supernovae and initial mass function, and early star and galaxy formation. I will present exemplary metal-poor stars with which these different topics can be addressed. Those are the most metal-poor stars in the Galaxy ([Fe/H] thorium, which can be used to radioactively date the stars to be 13 Gyr old. I will then transition to recent discoveries of metal-poor ([Fe/H] -3.0) stars in the least luminous dwarf satellites orbiting the Milky Way. Their stellar chemical signatures support the concept that small systems, analogous to the surviving dwarf galaxies, were the building blocks of the Milky Way's low-metallicity halo. This opens a new window for studying galaxy formation through stellar chemistry.

  13. Surface chemistry

    CERN Document Server

    Desai, KR

    2008-01-01

    The surface Chemistry of a material as a whole is crucially dependent upon the Nature and type of surfaces exposed on crystallites. It is therefore vitally important to independently Study different, well - defined surfaces through surface analytical techniques. In addition to composition and structure of surface, the subject also provides information on dynamic light scattering, micro emulsions, colloid Stability control and nanostructures. The present book endeavour to bring before the reader that the understanding and exploitation of Solid state phenomena depended largely on the ability to

  14. Heterogeneous atmospheric chemistry

    Science.gov (United States)

    Schryer, D. R.

    1982-01-01

    The present conference on heterogeneous atmospheric chemistry considers such topics concerning clusters, particles and microparticles as common problems in nucleation and growth, chemical kinetics, and catalysis, chemical reactions with aerosols, electron beam studies of natural and anthropogenic microparticles, and structural studies employing molecular beam techniques, as well as such gas-solid interaction topics as photoassisted reactions, catalyzed photolysis, and heterogeneous catalysis. Also discussed are sulfur dioxide absorption, oxidation, and oxidation inhibition in falling drops, sulfur dioxide/water equilibria, the evidence for heterogeneous catalysis in the atmosphere, the importance of heterogeneous processes to tropospheric chemistry, soot-catalyzed atmospheric reactions, and the concentrations and mechanisms of formation of sulfate in the atmospheric boundary layer.

  15. Bubble and foam chemistry

    CERN Document Server

    Pugh, Robert J

    2016-01-01

    This indispensable guide will equip the reader with a thorough understanding of the field of foaming chemistry. Assuming only basic theoretical background knowledge, the book provides a straightforward introduction to the principles and properties of foams and foaming surfactants. It discusses the key ideas that underpin why foaming occurs, how it can be avoided and how different degrees of antifoaming can be achieved, and covers the latest test methods, including laboratory and industrial developed techniques. Detailing a variety of different kinds of foams, from wet detergents and food foams, to polymeric, material and metal foams, it connects theory to real-world applications and recent developments in foam research. Combining academic and industrial viewpoints, this book is the definitive stand-alone resource for researchers, students and industrialists working on foam technology, colloidal systems in the field of chemical engineering, fluid mechanics, physical chemistry, and applied physics.

  16. Assessment of Commonly Used Cleaning Methods on the Anatomical Structure of Archaeological Wood

    Directory of Open Access Journals (Sweden)

    Safa Abdelkader Mohamed HAMED

    2013-06-01

    Full Text Available This study was conducted to diagnose and evaluate the effect of commonly used cleaning methods in Egypt on the anatomical structure of archaeological wood samples. Beech wood samples, which were taken from anonymous mashrabia, have been cleaned mechanically and chemically, then a scanning electron microscope (SEM study was undertaken, to monitor any significant structural changes in wood samples due to cleaning processes. SEM data, however, show that cleaning procedures, both mechanical and chemical, affect the anatomical structure of wood, and do not achieve the best result. The main problem is that the effect of reagents cannot be easily removed from the wood structure. Ethyl alcohol proved to have the minimal effect on the wood structure in this study.

  17. Integrating Computational Chemistry into a Course in Classical Thermodynamics

    Science.gov (United States)

    Martini, Sheridan R.; Hartzell, Cynthia J.

    2015-01-01

    Computational chemistry is commonly addressed in the quantum mechanics course of undergraduate physical chemistry curricula. Since quantum mechanics traditionally follows the thermodynamics course, there is a lack of curricula relating computational chemistry to thermodynamics. A method integrating molecular modeling software into a semester long…

  18. Connecting Archaeological Data and Grey Literature via Semantic Cross Search

    Directory of Open Access Journals (Sweden)

    Douglas Tudhope

    2011-07-01

    Full Text Available Differing terminology and database structure hinders meaningful cross search of excavation datasets. Matching free text grey literature reports with datasets poses yet more challenges. Conventional search techniques are unable to cross search between archaeological datasets and Web-based grey literature. Results are reported from two AHRC funded research projects that investigated the use of semantic techniques to link digital archive databases, vocabularies and associated grey literature. STAR (Semantic Technologies for Archaeological Resources was a collaboration between the University of Glamorgan, Hypermedia Research Unit and English Heritage (EH. The main outcome is a research Demonstrator (available online, which cross searches over excavation datasets from different database schemas, including Raunds Roman, Raunds Prehistoric, Museum of London, Silchester Roman and Stanwick sampling. The system additionally cross searches over an extract of excavation reports from the OASIS index of grey literature, operated by the Archaeology Data Service (ADS. A conceptual framework provided by the CIDOC Conceptual Reference Model (CRM integrates the different database structures and the metadata automatically generated from the OASIS reports by natural language processing techniques. The methods employed for extracting semantic RDF representations from the datasets and the information extraction from grey literature are described. The STELLAR project provides freely available tools to reduce the costs of mapping and extracting data to semantic search systems such as the Demonstrator and to linked data representation generally. Detailed use scenarios (and a screen capture video provide a basis for a discussion of key issues, including cost-benefits, ontology modelling, mapping, terminology control, semantic implementation and information extraction issues. The scenarios show that semantic interoperability can be achieved by mapping and extracting

  19. Automatic archaeological feature extraction from satellite VHR images

    Science.gov (United States)

    Jahjah, Munzer; Ulivieri, Carlo

    2010-05-01

    Archaeological applications need a methodological approach on a variable scale able to satisfy the intra-site (excavation) and the inter-site (survey, environmental research). The increased availability of high resolution and micro-scale data has substantially favoured archaeological applications and the consequent use of GIS platforms for reconstruction of archaeological landscapes based on remotely sensed data. Feature extraction of multispectral remotely sensing image is an important task before any further processing. High resolution remote sensing data, especially panchromatic, is an important input for the analysis of various types of image characteristics; it plays an important role in the visual systems for recognition and interpretation of given data. The methods proposed rely on an object-oriented approach based on a theory for the analysis of spatial structures called mathematical morphology. The term "morphology" stems from the fact that it aims at analysing object shapes and forms. It is mathematical in the sense that the analysis is based on the set theory, integral geometry, and lattice algebra. Mathematical morphology has proven to be a powerful image analysis technique; two-dimensional grey tone images are seen as three-dimensional sets by associating each image pixel with an elevation proportional to its intensity level. An object of known shape and size, called the structuring element, is then used to investigate the morphology of the input set. This is achieved by positioning the origin of the structuring element to every possible position of the space and testing, for each position, whether the structuring element either is included or has a nonempty intersection with the studied set. The shape and size of the structuring element must be selected according to the morphology of the searched image structures. Other two feature extraction techniques were used, eCognition and ENVI module SW, in order to compare the results. These techniques were

  20. New trends and developments in radiation chemistry

    International Nuclear Information System (INIS)

    Radiation chemistry is a branch of chemistry that studies chemical transformations in materials exposed to high-energy radiations. It uses radiation as the initiator of chemical reactions. Practical applications of radiation chemistry today extend to many fields, including health care, food and agriculture, manufacturing, industrial pollution abatement, biotechnology and telecommunications. The important advantage of radiation chemistry lies in its ability to be used to produce, and study, almost any reactive atomic and molecular species playing a part in chemical reactions, synthesis, industrial processes, or in biological systems. The techniques are applicable to gaseous, liquid, solid, and heterogeneous systems. By combining different techniques of radiation chemistry with analytical chemistry, the reaction mechanism and kinetics of chemical reactions are studied. In November 1988 in Bologna, Italy, the IAEA convened an advisory group meeting to assess new trends and developments in radiation chemistry. The present publication includes most of the contributions presented at the meeting. Refs, figs and tabs

  1. Novel Process for Laser Stain Removal from Archaeological Oil Paintings

    Science.gov (United States)

    El-Nadi, Lotfia; El-Feky, Osama; Abdellatif, Galila; Darwish, Sawsan

    2013-03-01

    Some samples of oil paintings (5 × 5 cm) were prepared on wooden panel with four types of fungi commonly encountered on oil paintings were selected for this study. Each of the fungi is associated with different colored stains. Fungus Alternaria tenuis is associated by a dense black stain, Chetomium globosum by a brownish gray stain, Aspergillus flavus by a yellowish stain, and Fusaruim oxysporum by a pinkish stain. Fungi growing on oil paintings affect the surface characteristics by forming a variety of colored patches typically composed of many complex chemical substances that are produced during metabolic processes. These colored stains may be encrusted in spores, present in mycelium or secreted to a substance such as oil paintings surfaces. While the fungal stains can sometimes be extracted with appropriate solvents, there are some stains that resist solvent extraction entirely. Developing new solvent system that might attack the paint structure, and is time consuming and requires a great deal of trial and error. Mechanical stain removal is also problematic in that it often produces abrasion of the surface, markedly deteriorating the artwork, and is extra ordinarily fine and tedious. For these reasons, we decided to examine an alternative physical technique as a new approach to deal with stain removal. Since the stains are due to the existence of fungi, we thought it a good idea to remove them by singlet oxygen. We applied the photo dynamic process through which the fungi stains were covered with organic dye derivatives in solution under controlled illumination in the lab. The samples were then irradiated by low power Laser light from a He-Ne laser, the dye will be photodecomposed and produce singlet oxygen. We report in this work the results obtained as a function of: - The concentration and types of the organic dye in solution, - The presence of certain amounts of liquids added to the solution, - The scanning speed of the laser beam on the sample surface

  2. Cambridge Illustrated History of Archaeology, edited by Paul G. Bahn, Cambridge University Press, New York, 1996

    Directory of Open Access Journals (Sweden)

    Douglas R. Givens

    1997-11-01

    Full Text Available The Cambridge Illustrated History of Archaeology is another in a series of volumes devoted to the history of archaeology that have appeared in recent time. Paul Bahn, the editor of the volume, has broken down his coverage of the history of worldwide archaeology into the following arrangement 'The Archaeology of Archaeology", "Old Worlds and New, 1500-1760", "Antiquarians and Explorers, 1760-1820", "Science and Romanticism, 1820-1860", "The Search for Human Origins, 1860-1920", "Archaeology Comes of Age, 1920-1960", "New Techniques and Competing Philosophies, 1960-1990",and "Current Controversies and Future Trends". Bahn's volume explores many of the major developments in archaeological practice from both in the classical world and was as from the practice of archaeology in the Americas. The volume even gives the reader a glimpse into the origins and growth of archaeology in New Zealand. Of particular interest is coverage of the history of early archaeological efforts having to do with early studies of human origins.

  3. Developing technologies for the management of the Archaeological Heritage: towards a model of Evaluation of the Archaeological Impact

    Directory of Open Access Journals (Sweden)

    Barreiro Martínez, David

    1999-06-01

    Full Text Available This paper proposes to establish criteria and procedures of archaeological practice to solve the problems and demands posed by the Management of the Archaeological Heritage. Our Research Unit is developing the CLAAR Programme, to define criteria and conventions for Landscape Archaeology and Archaeological Heritage. The main aim of this programme is to contribute to the development of systems and methodologies to manage and evaluate the Archaeological Heritage. In a practical sense, it tries to compose a Handbook of Practice to apply to research and commercial projects. As an example, this paper deals with the Evaluation of Archaeological Impact, proposing a methodological scheme to be applied to this new practice, which is an important part of the Evaluation of Environmental Impact.

    Este texto plantea la necesidad de establecer procedimientos y convenciones de práctica arqueológica para resolver los problemas y demandas en la gestión actual del Patrimonio Arqueológico. En concreto se presenta el programa CAPA (criterios y convenciones en Arqueología del Paisaje y Patrimonio Arqueológico en vía de realización por nuestro Grupo de Investigación. El objetivo de este programa es contribuir al desarrollo de sistemas y metodologías de gestión y evaluación del Patrimonio Arqueológico y llegar a componer un Manual de Usos Internos que nuestro grupo aplicaría en los diferentes proyectos de investigación y de asistencia técnica. Como ejemplo de estos desarrollos, se considera la Evaluación de Impacto Arqueológico y se propone un esquema metodológico para la realización de este nuevo tipo de práctica arqueológica, que forma parte importante de la Evaluación de Impacto Ambiental.

  4. [Archaeology and criminology--Strengths and weaknesses of interdisciplinary cooperation].

    Science.gov (United States)

    Bachhiesl, Christian

    2015-01-01

    Interdisciplinary cooperation of archaeology and criminology is often focussed on the scientific methods applied in both fields of knowledge. In combination with the humanistic methods traditionally used in archaeology, the finding of facts can be enormously increased and the subsequent hermeneutic deduction of human behaviour in the past can take place on a more solid basis. Thus, interdisciplinary cooperation offers direct and indirect advantages. But it can also cause epistemological problems, if the weaknesses and limits of one method are to be corrected by applying methods used in other disciplines. This may result in the application of methods unsuitable for the problem to be investigated so that, in a way, the methodological and epistemological weaknesses of two disciplines potentiate each other. An example of this effect is the quantification of qualia. These epistemological reflections are compared with the interdisciplinary approach using the concrete case of the "Eulau Crime Scene".

  5. Ground-penetrating radar techniques for archaeological investigations

    Science.gov (United States)

    Conyers, L.

    2013-12-01

    The ground-penetrating radar (GPR) technique has borrowed many of its methods from seismic exploration. Many have direct applications for archaeological exploration and interpretation. While most GPR data are essentially 'single fold' reflection data, they can still be processed into images much like seismic profiles. Many closely spaced profiles in a grid are analogous to 3-D seismic, and reflections can be migrated, filtered and topographically corrected much like standard seismic methods. In addition forward-modeling can be used as predictive methods to help with understanding the complexity of radar energy transmission, reflection, refraction and attenuation in the ground. When GPR is employed using these three-dimensional methods, archaeological sites that are deeply buried or stratigraphically complex, can be interpreted in ways not possible using other shallow geophysical techniques.

  6. Species identification of archaeological skin objects from Danish bogs

    DEFF Research Database (Denmark)

    Brandt, Luise Ørsted; Schmidt, Anne Lisbeth; Mannering, Ulla;

    2014-01-01

    species used for the production of skin garments. Until recently, species identification of archaeological skin was primarily performed by light and scanning electron microscopy or the analysis of ancient DNA. However, the efficacy of these methods can be limited due to the harsh, mostly acidic...... environment of peat bogs leading to morphological and molecular degradation within the samples. We compared species assignment results of twelve archaeological skin samples from Danish bogs using Mass Spectrometry (MS)-based peptide sequencing, against results obtained using light and scanning electron...... microscopy. While it was difficult to obtain reliable results using microscopy, MS enabled the identification of several species-diagnostic peptides, mostly from collagen and keratins, allowing confident species discrimination even among taxonomically close organisms, such as sheep and goat. Unlike previous...

  7. From Information to Message: Archaeology and Media in Serbia

    Directory of Open Access Journals (Sweden)

    Jasna Vuković

    2016-02-01

    Full Text Available The paper discusses the image of archaeology and archaeologists created in the public by various media. On the grounds of analysis of the texts in which the subject of archaeology figures in newspapers and on social networks, it is demonstrated that archaeologists are mainly perceived in the public as inert “concealers” of the real truth of the past. The reason behind this is equally in the insufficient knowledge of the media, but as well in the reluctance of professional archaeologists to communicate. The paper offers an outline of long-term strategy to bridge the existing gap and inform the public about the mission and social relevance of the discipline.

  8. [Ancient teeth: research on teeth and jaws from archaeological sites].

    Science.gov (United States)

    Jelsma, J

    2016-05-01

    Archaeology aims to enhance our understanding of the human past. An archaeologist devotes him- or herself to material remains, most often from the earth. The best sources of information about human behaviour and the earlier conditions of life for human beings are gravesites. In addition to being a source of cultural information, well-preserved skeletons offer vast possibilities for biochemical and genetic research. Teeth in particular can provide a treasure trove of information about the lives of our ancestors. With DNA analysis, gender and genetic relationships can be determined, however, the surface of the teeth also provides information about gender, age and genetic relationships and, of course, about the use of the teeth. New discoveries are being made and new (bio-)archaeological analyses are being carried out all the time. PMID:27166454

  9. Terahertz and Cultural Heritage Science: Examination of Art and Archaeology

    Directory of Open Access Journals (Sweden)

    Antonino Cosentino

    2016-02-01

    Full Text Available Cultural Heritage scientists need methodologies to examine Art and Archaeology in order to understand artistic materials and techniques and devise better conservation procedures. This review discusses the most successful and promising applications of Terahertz (THz technology in Cultural Heritage Science. THz is used in homeland security and for plenty of other industrial sectors and it presents a number of valuable features specifically for the investigation of Art and Archaeology: No radiation risk, low power, non-contact and reflection mode. Recent technical advancements are also making its application fast, mobile and relatively affordable creating a potential for its diffused implementation in museums. While THz is most promising for the investigation of multilayered art, such as paintings, it has been tested on a very large range of artifacts, from manuscripts to mummies and lacquered historical furniture.

  10. The Development of the Scientific Aesthetic in Archaeological Site Photography?

    Directory of Open Access Journals (Sweden)

    Charlotte Carter

    2015-05-01

    Full Text Available In this article, I shall introduce some core ideas from my research on the character of photographic representations published in archaeological journals during the mid-twentieth century. The aim of this study is to show the connection between the employment of certain scientific visual aesthetics in site photography at a time when the discipline of archaeology wanted to be seen as more scientific. Using the rod scale as a key visual metaphor for the identity of the discipline, I will argue that the increasing presence of the rod scale in published site photographs played a key part in the development of a specific scientific visual vocabulary which was driven by the contemporary culture-historical context.

  11. Cyclodextrin chemistry

    International Nuclear Information System (INIS)

    The chemistry of cyclodextrins was studied. This study included synthesising some cyclodextrin derivatives, preparing selected inclusion complexes with cyclodextrin and investigating the effects of gamma irradiation on cyclodextrins and certain linear oligosaccharides. This report presents a brief review of the structure and properties of cyclodextrins, the synthesis of cyclodextrin derivatives, their complexation and applications. This is followed by a description of the synthesis of some cyclodextrin derivatives and the preparation of inclusion complexes of cyclodextrin with some organic compounds. Finally, the effects of gamma irradiation on cyclodextrins, some of their derivatives and certain structurally related carbohydrates are discussed. The gamma irradiation studies were carried out for two reasons: to study the effects of gamma irradiation on cyclodextrins and their derivatives; and to investigate selectivity during the gamma irradiation of cyclodextrin derivatives

  12. Combustion chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  13. In Praise of Vagueness: Uncertainty, ambiguity and archaeological methodology

    DEFF Research Database (Denmark)

    Sørensen, Tim Flohr

    2016-01-01

    This article stipulates that vagueness is a socially important yet academically largely overlooked aspect of human interaction with the world. Vagueness and vague experiences can structure material categorisations of the world; it can contribute to the shaping of social relations and nurture the....... Finally, it is argued that the idealisation of certitude in archaeological analysis needs to be complemented by an interpretative framework making it possible to recognise vagueness as a social phenomenon....

  14. Botany meets archaeology: people and plants in the past.

    Science.gov (United States)

    Day, Jo

    2013-12-01

    This paper explores the close links between botany and archaeology, using case studies from the ancient Mediterranean. It explains the kinds of palaeobotanical remains that archaeologists can recover and the methods used to analyse them. The importance of iconographic and textual evidence is also underlined. Examples of key research areas that focus on ancient plants are discussed: diet and palaeoeconomy; medicines, poisons, and psychotropics; perfumes, cosmetics, and dyes; and prestige.

  15. Archaeological and chemical analysis of Tell el Yahudiyeh ware

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, M F; Harbottle, G; Sayre, E V

    1978-01-01

    Typological and geographic analyses indicate that Tell el Yahudiyeh ware (found in Cyprus, Egypt, Nubia, and the Levant during the Middle Bronze period, c. 1750-1550 B.C.) were probably manufactured in two areas, the Nile Valley and the Levant. Activation analysis was carried out and correlated with the archaeological analyses. Results confirm the two ''families'' of the ware, one Egyptian and one Levantine. Speculations are offered on the social interaction of the period. 11 figures, 2 tables. (DLC)

  16. A Note Concerning the Archaeology of Annadel State Park

    OpenAIRE

    Parkman, Edward Breck

    1983-01-01

    The recent DPR investigations have been directed toward a better understanding of the Annadel prehistoric archaeological record. One goal of this work has been to delineate the boundaries of the park's primary obsidian source (i.e., the "Annadel" source). Special attention has also been given to x-ray fluorescence spectrography and obsidian hydration studies. These studies have helped to better illustrate the chemical variability of the local obsidian, and to better define the local chronolog...

  17. The development of Spanish archaeology in the 20th century

    OpenAIRE

    Martínez Navarrete, María Isabel

    1997-01-01

    The long history of state unity and archaeology’s strong dependence on the state explain how archaeological practice became institutionalized in Spain. The intellectual currents that marked Spanish archaeology’s development – antiquarianism, Enlightenment interest in human antiquity, the definition of national identity – are analogous to those in other European countries: foreign models always were influential. Largely due to traditional, institutionalized links to German and French archaeolo...

  18. Botany meets archaeology: people and plants in the past.

    Science.gov (United States)

    Day, Jo

    2013-12-01

    This paper explores the close links between botany and archaeology, using case studies from the ancient Mediterranean. It explains the kinds of palaeobotanical remains that archaeologists can recover and the methods used to analyse them. The importance of iconographic and textual evidence is also underlined. Examples of key research areas that focus on ancient plants are discussed: diet and palaeoeconomy; medicines, poisons, and psychotropics; perfumes, cosmetics, and dyes; and prestige. PMID:23669575

  19. Biomimetic hydroxyapatite as a new consolidating agent for archaeological bone

    OpenAIRE

    North, Alexis

    2014-01-01

    Recent studies on calcareous stone and plaster consolidation have demonstrated considerable potential by bio-mimicking the growth of hydroxyapatite (HAP), the main mineralogical constituent of teeth and bone matrix. These initial conservation applications, together with significant fundamental research on the precipitation of HAP for bioengineering and biomedical applications, offer great promise in the use of HAP as a consolidating agent for archaeological bone and other similar materials su...

  20. Earliest evidence of pollution by heavy metals in archaeological sites

    OpenAIRE

    Guadalupe Monge; Jimenez-Espejo, Francisco J.; Antonio García-Alix; Francisca Martínez-Ruiz; Nadine Mattielli; Clive Finlayson; Naohiko Ohkouchi; Miguel Cortés Sánchez; Jose María Bermúdez de Castro; Ruth Blasco; Jordi Rosell; José Carrión; Joaquín Rodríguez-Vidal; Geraldine Finlayson

    2015-01-01

    Homo species were exposed to a new biogeochemical environment when they began to occupy caves. Here we report the first evidence of palaeopollution through geochemical analyses of heavy metals in four renowned archaeological caves of the Iberian Peninsula spanning the last million years of human evolution. Heavy metal contents reached high values due to natural (guano deposition) and anthropogenic factors (e.g. combustion) in restricted cave environments. The earliest anthropogenic pollution ...

  1. Voices carry: An archaeology of the Hervormd approach

    OpenAIRE

    Johann Beukes

    2008-01-01

    From the investigative premise of a Foucauldian archaeology of knowledge, this article attempts to unearth the layers of ideas which constituted the Hervormd approach to doing theology over the past century. Digging into seemingly disassociated bodies of theological precedents, the article anatomizes four layers of ideas in a series of diverse orientations towards theology, namely the (1) ethical, (2) confessional and (3) dialectical orientations, and stemming from a Kantian orientation in pa...

  2. Reverse engineering and the archaeology of the modern world

    OpenAIRE

    Moshenska, G.

    2016-01-01

    This paper explores the practical and conceptual connections between the archaeology of post-industrial societies and the process of reverse engineering. It explores common themes such as industrial decline, the loss of technical expertise, and the growing problem of obsolescence both in technological infrastructure and in the management of digital data. To illuminate the connections between the two fields it considers several examples. These include the implicit applications of r...

  3. Computer vision, archaeological classification and China's terracotta warriors

    OpenAIRE

    Bevan, A.; Li, X; Martinón-Torres, M.; Green, S; Rehren, T.; Xia, Y.(Hunan University, Changsha, 410082, People's Republic of China); Zhao, K.; Zhao, Z.; Ma, S.; Cao, W.

    2014-01-01

    Structure-from-motion and multiview-stereo together offer a computer vision technique for reconstructing detailed 3D models from overlapping images of anything from large landscapes to microscopic features. Because such models can be generated from ordinary photographs taken with standard cameras in ordinary lighting conditions, these techniques are revolutionising digital recording and analysis in archaeology and related subjects such as palaeontology, museum studies and art history. However...

  4. Archaeological investigations in Palanda, Santa Ana-La Florida (Ecuador)

    OpenAIRE

    Valdez, Francisco

    2014-01-01

    International audience; Recent archaeological research carried out in Zamora Chinchipe (Ecuador) have shown the presence of a previously unknown prehispanic culture, that was present throughout the Mayo Chinchipe-Marañón hydraulic basin; thus it was designated with the same name. Archaeologial work in the Santa Ana-La Florida site (Palanda) has given a precise chronological dimension and has produced evidence on the ideology, architecture, funerary customs and the material culture in general ...

  5. Archaeological and chemical analysis of Tell el Yahudiyeh ware

    International Nuclear Information System (INIS)

    Typological and geographic analyses indicate that Tell el Yahudiyeh ware (found in Cyprus, Egypt, Nubia, and the Levant during the Middle Bronze period, c. 1750-1550 B.C.) were probably manufactured in two areas, the Nile Valley and the Levant. Activation analysis was carried out and correlated with the archaeological analyses. Results confirm the two ''families'' of the ware, one Egyptian and one Levantine. Speculations are offered on the social interaction of the period. 11 figures, 2 tables

  6. Innovation Technologies and Applications for Coastal Archaeological sites

    Science.gov (United States)

    Di Iorio, A.; Biliouris, D.; Guzinski, R.; Hansen, L. B.; Bagni, M.

    2015-04-01

    Innovation Technologies and Applications for Coastal Archaeological sites project (ITACA) aims to develop and test a management system for underwater archaeological sites in coastal regions. The discovering and monitoring service will use innovative satellite remote sensing techniques combined with image processing algorithms. The project will develop a set of applications integrated in a system pursuing the following objectives: - Search and location of ancient ship wrecks; - Monitoring of ship wrecks, ruins and historical artefacts that are now submerged; - Integration of resulting search and monitoring data with on-site data into a management tool for underwater sites; - Demonstration of the system's suitability for a service. High resolution synthetic aperture radar (TerraSAR-X, Cosmo-SkyMed) and multispectral satellite data (WorldView) will be combined to derive the relative bathymetry of the bottom of the sea up to the depth of 50 meters. The resulting data fusion will be processed using shape detection algorithms specific for archaeological items. The new algorithms, the physical modelling and the computational capabilities will be integrated into the Web-GIS, together with data recorded from surface (2D and 3D modelling) and from underwater surveys. Additional specific archaeological layers will be included into the WebGIS to facilitate the object identification through shape detection techniques and mapping. The system will be verified and validated through an extensive onground (sea) campaign carried out with both cutting edge technologies (side-scan sonar, multi beam echo sounder) and traditional means (professional scuba divers) in two test sites in Italy and Greece. The project is leaded by Planetek Hellas E.P.E. and include ALMA Sistemi sas for the "shape detection" and dissemination tasks, DHI-GRAS and Kell Srl for multispectral and SAR bathymetry. The complete consortium is composed by eleven partners and the project Kick-Off has been held in

  7. Manufacturing details by Neutron Radiography of Archaeological Pottery

    Energy Technology Data Exchange (ETDEWEB)

    Bernedo, Alfredo Victor Bellido; Latini, Rose Mary [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil); Souza, Maria Ines Silvani; Vinagre Filho, Ubirajara Maribondo [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Full text: The aim of the present work was to investigate manufacturing details of archaeological pot-sherds ceramics by Neutron Radiography. Pottery is perhaps the most important artefact found in excavation. Its archaeological importance relies on the fact that it can reveal cultural traditions and commercial influences in ancient communities. These pottery was recently discovered in archaeological earth circular structures sites in Acre state Brazil and the characteristics of clay used in their manufacture have been studied by modern scientific techniques such as Instrumental Neutron Activation Analysis (INAA), Thermoluminescence Dating and Moessbauer Spectroscopy. Different fragments of pottery were submitted to a neutron flux of the order of 10{sup 5}n.cm{sup -2}2:s{sup -1} for 3 minutes in the research reactor Argonauta at the Instituto de Engenharia Nuclear/CNEN. Digital processing techniques using imaging plate were applied to the image of the selected sample. The Neutrongraphy shows two different manufacturing details: palette and rollers. The fragment made by the technique of palette show a homogeneous mass and the neutrongraphy of ceramic fragments made by the technique of the rollers, pottery funeral, can be seen horizontal traces of the junction of rollers, overlapping, forming layers supported on each other. This technique allows you to create more stable structures. Thus, both the technique of the pallet as the roller can be characterized by Neutron Radiography. (author)

  8. archAR: an archaeological augmented reality experience

    Science.gov (United States)

    Wiley, Bridgette; Schulze, Jürgen P.

    2015-03-01

    We present an application for Android phones or tablets called "archAR" that uses augmented reality as an alternative, portable way of viewing archaeological information from UCSD's Levantine Archaeology Laboratory. archAR provides a unique experience of flying through an archaeological dig site in the Levantine area and exploring the artifacts uncovered there. Using a Google Nexus tablet and Qualcomm's Vuforia API, we use an image target as a map and overlay a three-dimensional model of the dig site onto it, augmenting reality such that we are able to interact with the plotted artifacts. The user can physically move the Android device around the image target and see the dig site model from any perspective. The user can also move the device closer to the model in order to "zoom" into the view of a particular section of the model and its associated artifacts. This is especially useful, as the dig site model and the collection of artifacts are very detailed. The artifacts are plotted as points, colored by type. The user can touch the virtual points to trigger a popup information window that contains details of the artifact, such as photographs, material descriptions, and more.

  9. The empirical case against the 'demographic turn' in Palaeolithic archaeology.

    Science.gov (United States)

    Collard, Mark; Vaesen, Krist; Cosgrove, Richard; Roebroeks, Wil

    2016-07-01

    Recently, it has become commonplace to interpret major transitions and other patterns in the Palaeolithic archaeological record in terms of population size. Increases in cultural complexity are claimed to result from increases in population size; decreases in cultural complexity are suggested to be due to decreases in population size; and periods of no change are attributed to low numbers or frequent extirpation. In this paper, we argue that this approach is not defensible. We show that the available empirical evidence does not support the idea that cultural complexity in hunter-gatherers is governed by population size. Instead, ethnographic and archaeological data suggest that hunter-gatherer cultural complexity is most strongly influenced by environmental factors. Because all hominins were hunter-gatherers until the Holocene, this means using population size to interpret patterns in the Palaeolithic archaeological record is problematic. In future, the population size hypothesis should be viewed as one of several competing hypotheses and its predictions formally tested alongside those of its competitors.This article is part of the themed issue 'Major transitions in human evolution'.

  10. Characterization of ceramic archaeological by high resolution X ray microtomography

    International Nuclear Information System (INIS)

    Characterization of ceramic fragments is a very important area of research in art and archeometry area because it enables a greater understanding of how ancient civilizations behave and what were their traditions and customs. Petrography and chemical analyses are commonly used, but these techniques are destructive, which is not interesting for this type of sample. Through the exchange of multidisciplinary scientific knowledge and new partnerships, high resolution X-ray microtomography has been introduced in archaeological area as a great possibility of 3D inspection in a non-destructive way. The goal of this work is to investigate the internal microstructures of four samples of archeological ceramic, from the Archaeological Site of Macacu - RJ. The X-ray microtomography were performed in a high resolution setup, and can be used to infer the nature of organic temper even with all plant remains completely burnt out during the firing process and also to ensure the homogeneity of samples envisaged for geochemical analyses, especially with respect to the distribution of chemically diverse fabric compounds. In this way this study intends to contribute to our understanding of the archaeological and historical formations of this region. (author)

  11. Raman spectroscopy characterization of colored pigments in archaeological materials

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    Archaeological artifacts and artworks with colors are being increasingly analyzed in these years. The pigment materials used for their creation are much studied after the development of modern non-destructive micro sampling analytical techniques. Art historians, museum conservators, and archaeolo......Archaeological artifacts and artworks with colors are being increasingly analyzed in these years. The pigment materials used for their creation are much studied after the development of modern non-destructive micro sampling analytical techniques. Art historians, museum conservators......, and archaeological scientists are now much aware of the importance of physicochemical characterization for the attribution of the historical period and genuineness of an item. Ancient technological methods used in the construction of the items may be characterized by spectroscopists with a minimal disturbance....... The use of Raman spectroscopy can be taken to illustrate this: It provides e.g. information of importance to art restorers and museum conservation scientists in preserving materials and the understanding of deterioration processes. It does so by identification of key components, as shown in Fig. 1. Prior...

  12. Geomorphic and archaeological -historical evidence for past ealihquakes in Greece

    Directory of Open Access Journals (Sweden)

    H. Maroukian

    1996-06-01

    Full Text Available Geomorphic observations focused on landforms of marine and fluvial origin such as notches, beachrocks, stream channel shifts, alluvial terraces and knickpoints, when combined with historical and archaeological information are able to date seismic events that took place in the past in some places of the Peloponnesus. At thc Eastern Gulf of Corinth, a seismically active area, all the geomorphic observations fit quite well with the deformation field induced by the action of an offshore fault. At Mycenae, a seismically inactive area with no historical evidence of earthquakes, the archaeological information is the only evidence for past earthquakes while geomorphic data indicate the most probable activated fault. At Sparta, an area of low seismicity but with historical evidence of destructive earthquakes, the geomorphic evidence helps to identify the most likely ruptured fault. At Eliki, a seismically active area with well documented historical activity, the geomorphic data serve to define the causative fault.This paper shows that although historical and archaeological data provide evidence far the occurrence of past earthquakes and often their date, geomorphic observations must be used to identify the causative fault.

  13. Archaeological soybean (Glycine max in East Asia: does size matter?

    Directory of Open Access Journals (Sweden)

    Gyoung-Ah Lee

    Full Text Available The recently acquired archaeological record for soybean from Japan, China and Korea is shedding light on the context in which this important economic plant became associated with people and was domesticated. This paper examines archaeological (charred soybean seed size variation to determine what insight can be gained from a comprehensive comparison of 949 specimens from 22 sites. Seed length alone appears to represent seed size change through time, although the length × width × thickness product has the potential to provide better size change resolution. A widespread early association of small seeded soybean is as old as 9000-8600 cal BP in northern China and 7000 cal BP in Japan. Direct AMS radiocarbon dates on charred soybean seeds indicate selection resulted in large seed sizes in Japan by 5000 cal BP (Middle Jomon and in Korea by 3000 cal BP (Early Mumun. Soybean seeds recovered in China from the Shang through Han periods are similar in length to the large Korean and Japanese specimens, but the overall size of the large Middle and Late Jomon, Early Mumun through Three Kingdom seeds is significantly larger than any of the Chinese specimens. The archaeological record appears to disconfirm the hypothesis of a single domestication of soybean and supports the view informed by recent phyologenetic research that soybean was domesticated in several locations in East Asia.

  14. Characterization of ceramic archaeological by high resolution X ray microtomography

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Alessandra C.; Freitas, Renato; Calza, Cristiane F.; Lopes, Ricardo T.; Lima, Inaya, E-mail: alecastro@lin.ufrj.br [Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Lab. de Instrumentacao Nuclear; Carvalho, Daniele D.; Gaspar, Maria D. [Museu Nacional (MN/UFRJ), RJ (Brazil). Centro de Tecnologia

    2013-07-01

    Characterization of ceramic fragments is a very important area of research in art and archeometry area because it enables a greater understanding of how ancient civilizations behave and what were their traditions and customs. Petrography and chemical analyses are commonly used, but these techniques are destructive, which is not interesting for this type of sample. Through the exchange of multidisciplinary scientific knowledge and new partnerships, high resolution X-ray microtomography has been introduced in archaeological area as a great possibility of 3D inspection in a non-destructive way. The goal of this work is to investigate the internal microstructures of four samples of archeological ceramic, from the Archaeological Site of Macacu - RJ. The X-ray microtomography were performed in a high resolution setup, and can be used to infer the nature of organic temper even with all plant remains completely burnt out during the firing process and also to ensure the homogeneity of samples envisaged for geochemical analyses, especially with respect to the distribution of chemically diverse fabric compounds. In this way this study intends to contribute to our understanding of the archaeological and historical formations of this region. (author)

  15. The survival of archaeology in the design of future cities?

    Directory of Open Access Journals (Sweden)

    Natalie Vinton

    2013-10-01

    Full Text Available Ironically, when given the opportunity to respond to J. J. Carver’s thought-provoking article ‘The Challenges and Opportunities for Mega-Infrastructure Projects and Archaeology’ and thinking I had plenty of time in which to do so, I was suddenly thrust back into two, all-consuming major Sydney infrastructure projects, which currently sit in the category of ‘confidential’, meaning not yet fit for public consumption and dare not breath a word of the detail. In short, what this means is that the timeframes are impossibly short, the budgets are even tighter, the crystal ball is working overtime and the select few staff signed to work on these projects are working around the clock to deliver succinct documents that are required to be pragmatic, avoid archaeological ‘speak’ and provide certainty about the archaeology, its extent, nature, significance, timeframes and budget estimates for managing the known and potential archaeological resource. Surely, such easy tasks to deliver on?

  16. Manufacturing details by Neutron Radiography of Archaeological Pottery

    International Nuclear Information System (INIS)

    Full text: The aim of the present work was to investigate manufacturing details of archaeological pot-sherds ceramics by Neutron Radiography. Pottery is perhaps the most important artefact found in excavation. Its archaeological importance relies on the fact that it can reveal cultural traditions and commercial influences in ancient communities. These pottery was recently discovered in archaeological earth circular structures sites in Acre state Brazil and the characteristics of clay used in their manufacture have been studied by modern scientific techniques such as Instrumental Neutron Activation Analysis (INAA), Thermoluminescence Dating and Moessbauer Spectroscopy. Different fragments of pottery were submitted to a neutron flux of the order of 105n.cm-22:s-1 for 3 minutes in the research reactor Argonauta at the Instituto de Engenharia Nuclear/CNEN. Digital processing techniques using imaging plate were applied to the image of the selected sample. The Neutrongraphy shows two different manufacturing details: palette and rollers. The fragment made by the technique of palette show a homogeneous mass and the neutrongraphy of ceramic fragments made by the technique of the rollers, pottery funeral, can be seen horizontal traces of the junction of rollers, overlapping, forming layers supported on each other. This technique allows you to create more stable structures. Thus, both the technique of the pallet as the roller can be characterized by Neutron Radiography. (author)

  17. Chemistry Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — Purpose: To conduct fundamental studies of highway materials aimed at understanding both failure mechanisms and superior performance. New standard test methods are...

  18. Public perception of chemistry

    OpenAIRE

    Stražar, Alenka

    2015-01-01

    The thesis deals with the perception of chemistry among the public, which reflects the stereotypes that people have about chemistry. It presents the existing classification of stereotypes about chemistry and their upgrade. An analysis of movies that reflect the existing perception of chemistry in the public is written. Literature on selected aspects of the application of chemistry in movies is collected and analyzed. A qualification of perception of chemistry in the movies is presented based ...

  19. Science Update: Inorganic Chemistry.

    Science.gov (United States)

    Rawls, Rebecca

    1981-01-01

    Describes areas of inorganic chemistry which have changed dramatically in the past year or two, including photochemistry, electrochemistry, organometallic complexes, inorganic reaction theory, and solid state chemistry. (DS)

  20. Enhancement, Presentation and Shelter Replacement of the Archaeological Site at Akrotiri, Thera

    OpenAIRE

    Nikos Fintikakis; Christos Doumas

    2014-01-01

    In this article Architect Nikos Fintikakis gives a detailed description of the implemented in 2012 the project of preservation of the archaeological site in Akrotiri (Greece) using a bioclimatic canopy (http://www.projectbaikal.com/index.php/pb/article/view/688/ 649). The problem of preservation of the archaeological heritage is urgent and also relevant to Irkutsk with it's Glazkovsky necropolis, a unique monument of the Neolithic (Baryshnikov V. Glazkovsky necropolis in Irkutsk: archaeologic...

  1. Archaeology of wings : Birds and people in the Baltic Sea region during the Stone Age

    OpenAIRE

    Mannermaa, Kristiina

    2008-01-01

    The prominent roles of birds, often mentioned in historical sources, are not well reflected in archaeological research. Absence or scarcity of bird bones in archaeological assemblages has been often seen as indication of a minor role of birds in the prehistoric economy or ideology, or explained by taphonomic loss. Few studies exist where birds form the basis for extensive archaeological interpretation. In this doctoral dissertation bird bone material from various Stone Age sites in the Baltic...

  2. The evaluation of corrosion inhibitors for application to copper and copper alloy archaeological artefacts

    OpenAIRE

    Faltermeier, R.

    1995-01-01

    This thesis concerns corrosion inhibiting compounds which slow the deterioration of archaeological copper artefacts. Benzotriazole (BTA) and 2-Amino- 5-mercapto-1,3,4-thiadiazole (AMT) have been applied as corrosion inhibitors in archaeological conservation. A search was conducted for similar compounds that could be applied in the conservation of copper and copper alloys. According to a list of requirements specific to archaeological conservation, six new inhibitors were tes...

  3. NEW USES OF TAJIN ARCHAEOLOGICAL HERITAGE THROUGH TOURISTIFICATION, COMMODITIZATION AND PERFORMANCE

    OpenAIRE

    Zúñiga, Federico; Posgrado en Antropología, Universidad Nacional Autónoma de México

    2014-01-01

    Nowadays, the archaeological heritage is faced with a wide range of processes that have gradually transformed it into a profitable resource. It is pointed out that the accelerated touristification, commodification and spectacle have driven the archaeological heritage to acquire new meanings and uses. In consideration of the above, the aim of this paper is to discuss, through ethnographic analysis, the new uses and meanings of the archaeological heritage of El Tajin, located in Papantla, Verac...

  4. Archaeology in Latin America, by Gustavo G. Politis and Benjamin Alberti, editors, 1999, Routledge, London

    OpenAIRE

    David L. Browman

    2001-01-01

    The two editors argue in their preface to the volume that the particular sociopolitical context of Latin America has led to a regionalism not seen in North America or Europe, resulting in a unique variety of archaeology. They particularly conceive "Latin American archaeology" in this case to he only that archaeology done by individuals who are citizens of the countries of the region, and they ex­clude from consideratio...

  5. Determination of gamma ray attenuation coefficient of archaeological ceramics from Parana State, Brazil

    International Nuclear Information System (INIS)

    This work demonstrates an alternative methodology for the linear attenuation coefficient determination (μρ) of irregular form samples. This methodology aims the study of indigenous archaeological ceramics from the region of Londrina, North of Parana State, Brazil. These ceramics are from Padre Carlos Weiss Historic Museum, Londrina University and belong to the Kaingaing tradition. Firstly, μρ determination by two mean method was performed by the gamma ray beam attenuation of the immersed ceramics, by using two different means with well-known linear attenuation coefficient. Beyond, the deduction of the equation for the μρ determination by the two-means methods, was also realized. By the other side, μρ theoretical value was determined with the XCOM computer program. This program uses the ceramics chemistry composition and provides an energy versus mass attenuation coefficient table. To verify the two-means method efficiency, five ceramics sample of thickness 1.15 cm and 1.87 cm were prepared with homogeneous clay. Theses ceramics, we used for the μρ determination using the attenuation method, and two-means method. The results and the μρ obtained deviation were compared for these samples, for the two methods. With the obtained results, it was concluded that the two-means method is applicable for the mass attenuation coefficient determination for the archaeometry studies. (author). 6 refs., 1 fig., 5 tabs

  6. Comparing Carbonyl Chemistry in Comprehensive Introductory Organic Chemistry Textbooks

    Science.gov (United States)

    Nelson, Donna J.; Kumar, Ravi; Ramasamy, Saravanan

    2015-01-01

    Learning the chemistry of compounds containing carbonyl groups is difficult for undergraduate students partly because of a convolution of multiple possible reaction sites, competitive reactions taking place at those sites, different criteria needed to discern between the mechanisms of these reactions, and no straightforward selection method…

  7. Integrating Computational Chemistry into the Physical Chemistry Curriculum

    Science.gov (United States)

    Johnson, Lewis E.; Engel, Thomas

    2011-01-01

    Relatively few undergraduate physical chemistry programs integrate molecular modeling into their quantum mechanics curriculum owing to concerns about limited access to computational facilities, the cost of software, and concerns about increasing the course material. However, modeling exercises can be integrated into an undergraduate course at a…

  8. Iron corrosion in an anoxic soil: Comparison between thermodynamic modelling and ferrous archaeological artefacts characterised along with the local in situ geochemical conditions

    Energy Technology Data Exchange (ETDEWEB)

    Saheb, M.; Neff, D.; Michelin, A.; Dillmann, P. [CEA Saclay, CNRS, LAPA SIS2M, UMR3299, 91 - Gif-sur-Yvette (France); Saheb, M. [ANDRA, F-92298 Chatenay Malabry (France); Descostes, M. [CEA Saclay, DEN DANS DPC SECR, Lab Radionuclides Migrat Measurements and Modelling, 91 - Gif-sur-Yvette (France); Descostes, M. [Univ Evry, CEA, CNRS, UMR 8587, Evry (France); Dillmann, P. [CNRS, Inst Rech Archeomat, UMR 5060, F-75700 Paris (France)

    2010-07-01

    This article is part of an ongoing study on the long-term corrosion behaviour of ferrous archaeological artefacts. The aim of this study is to correlate the corrosion products formed on ancient artefacts in an anoxic medium to the environmental data using thermodynamic modelling. For this purpose, measurement campaigns have been conducted on the archaeological site of Glinet (16. century, High Normandy (Seine-Maritime), France) where the evolution of the pore water chemistry has been recorded for a period of one year. Three evolution steps have been distinguished after the oxidizing perturbation which was induced by the piezometers installation. The first step was related to an oxidizing environment in which pore water was in equilibrium with a Fe(III) precipitated phase: ferri-hydrite (FeOOH center dot 0.4 H{sub 2}O). The second step was considered as an intermediate step and Fe speciation had evolved; equilibrium was achieved between ferri-hydrite and a Fe(II) carbonate phase: siderite (Fe(II)CO{sub 3}). The last step of the evolution was related to a reducing stage where pore water was in equilibrium with magnetite (Fe(II, III){sub 3}O{sub 4}) and with chukanovite (Fe(II){sub 2}(OH){sub 2}CO{sub 3}). As these phases were present in the corrosion layers formed on the archaeological samples, it is possible to conclude that the thermodynamic approach was helpful in developing a better understanding of the effect of geochemical conditions on the composition and mineralogy of the corrosion products formed on archaeological artefacts. This work could be used as a reference for further corrosion studies, especially on long-term corrosion processes applied to nuclear waste disposal. (authors)

  9. Microscopic and Spectroscopic Characterisation of Waterlogged Archaeological Softwood from Anoxic Environments

    DEFF Research Database (Denmark)

    Pedersen, Nanna Bjerregaard

    Confocal Raman imaging, UV-microspectrophotometry, light microscopy, transmission electron microscopy, compositional analysis, and ATR-FTIR spectroscopy has been applied to waterlogged archaeological Norway spruce [Picea abies (L.) Karst] and Scots pine [Pinus sylvestris L.] retrieved from anoxic...... waterlogged sites and solely decayed by erosion bacteria to refine the understanding of the residual wood structure left after degradation. This was done not only to improve the ability to develop suitable and cost effective conservations treatments but also to improve the understanding of anaerobic decay...... mechanisms acting on plant biomass in waterlogged anoxic environment.Morphological analyses showed typical erosion bacteria decay patterns in the residual wood structure. Decay resistance of some cell types and cell wall compartments in preference to others is most likely explained not only by elevated...

  10. Study of archaeological artefacts to refine the model of iron long-term indoor atmospheric corrosion

    Science.gov (United States)

    Monnier, J.; Legrand, L.; Bellot-Gurlet, L.; Foy, E.; Reguer, S.; Rocca, E.; Dillmann, P.; Neff, D.; Mirambet, F.; Perrin, S.; Guillot, I.

    2008-09-01

    The study of long-term indoor atmospheric corrosion is involved in the field of the interim storage of nuclear wastes. Indeed study of archaeological artefacts is one of the only mean to gather information on very long periods. Concerning ancient items, due to the complexity of the system, it is necessary to couple many analytical techniques from the macro to the microscopic scale. This enables to propose a description of the Amiens cathedral chain rust layers, made of a matrix of goethite, with lepidocrocite and akaganeite locally present and marbling of a poor crystallized phase associated to ferrihydrite. Electrochemical measurements permit to study the reduction capacity of the rust layer and to draw reduction mechanisms of the so-called active phases, by in situ experiments coupled with X-ray diffraction and X-ray absorption spectroscopy.

  11. Study of archaeological artefacts to refine the model of iron long-term indoor atmospheric corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Monnier, J. [Laboratoire Pierre Suee - UMR 9956 CEA-CNRS, bat 637 CEA Saclay, 91191 Gif-sur-Yvette (France); Institut de Chimie des Materiaux de Paris Est-equipe MCMC, UMR 7182 CNRS-Universite Paris 12, 2-8 rue Henry Dunant, 94320 Thiais (France)], E-mail: judith.monnier@cea.fr; Legrand, L. [Laboratoire Analyse et Modelisation pour la Biologie et l' Environnement, UMR 8587, Evry (France); Bellot-Gurlet, L. [Laboratoire de Dynamique, Interaction et Reactivite (LADIR), UMR 7075 CNRS and Universite Pierre et Marie Curie Paris 6, 2 rue Henry Dunant, 94320 Thiais (France); Foy, E. [Laboratoire Pierre Suee - UMR 9956 CEA-CNRS, bat 637 CEA Saclay, 91191 Gif-sur-Yvette (France); Reguer, S. [Synchrotron SOLEIL, Saint-Aubin BP 4891192 Gif-sur-Yvette (France); Rocca, E. [Laboratoire de Chimie du Solide Mineral, UMR 7555, Universite Henri Poincare-Nancy I (France); Dillmann, P. [Laboratoire Pierre Suee - UMR 9956 CEA-CNRS, bat 637 CEA Saclay, 91191 Gif-sur-Yvette (France); IRAMAT UMR 5060, IPSE - CEA Saclay, Gif-sur-Yvette (France); Neff, D. [Laboratoire Pierre Suee - UMR 9956 CEA-CNRS, bat 637 CEA Saclay, 91191 Gif-sur-Yvette (France); Mirambet, F. [Laboratoire de Recherche des Monuments Historiques, 29, rue de Paris, Champs-sur-Marne (France); Perrin, S. [Laboratoire d' Etude de la Corrosion Aqueuse, SCCME, bat 458 CEA Saclay, 91191 Gif-sur-Yvette (France); Guillot, I. [Institut de Chimie des Materiaux de Paris Est-equipe MCMC, UMR 7182 CNRS-Universite Paris 12, 2-8 rue Henry Dunant, 94320 Thiais (France)

    2008-09-30

    The study of long-term indoor atmospheric corrosion is involved in the field of the interim storage of nuclear wastes. Indeed study of archaeological artefacts is one of the only mean to gather information on very long periods. Concerning ancient items, due to the complexity of the system, it is necessary to couple many analytical techniques from the macro to the microscopic scale. This enables to propose a description of the Amiens cathedral chain rust layers, made of a matrix of goethite, with lepidocrocite and akaganeite locally present and marbling of a poor crystallized phase associated to ferrihydrite. Electrochemical measurements permit to study the reduction capacity of the rust layer and to draw reduction mechanisms of the so-called active phases, by in situ experiments coupled with X-ray diffraction and X-ray absorption spectroscopy.

  12. Study of archaeological artefacts to refine the model of iron long-term indoor atmospheric corrosion

    International Nuclear Information System (INIS)

    The study of long-term indoor atmospheric corrosion is involved in the field of the interim storage of nuclear wastes. Indeed study of archaeological artefacts is one of the only mean to gather information on very long periods. Concerning ancient items, due to the complexity of the system, it is necessary to couple many analytical techniques from the macro to the microscopic scale. This enables to propose a description of the Amiens cathedral chain rust layers, made of a matrix of goethite, with lepidocrocite and akaganeite locally present and marbling of a poor crystallized phase associated to ferrihydrite. Electrochemical measurements permit to study the reduction capacity of the rust layer and to draw reduction mechanisms of the so-called active phases, by in situ experiments coupled with X-ray diffraction and X-ray absorption spectroscopy

  13. Migration chemistry

    International Nuclear Information System (INIS)

    Migration chemistry, the influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour of pollutants in the environment, is an interplay between the actual natur of the pollutant and the characteristics of the environment, such as pH, redox conditions and organic matter content. The wide selection of possible pollutants in combination with varying geological media, as well as the operation of different chemical -, biochemical - and physico-chemical reactions compleactes the prediction of the influence of these processes on the mobility of pollutants. The report summarizes a wide range of potential pollutants in the terrestrial environment as well as a variety of chemical -, biochemical - and physico-chemical reactions, which can be expected to influence the migration behaviour, comprising diffusion, dispersion, convection, sorption/desorption, precipitation/dissolution, transformations/degradations, biochemical reactions and complex formation. The latter comprises the complexation of metal ions as well as non-polar organics to naturally occurring organic macromolecules. The influence of the single types of processes on the migration process is elucidated based on theoretical studies. The influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour is unambiguous, as the processes apparently control the transport of pollutants in the terrestrial environment. As the simple, conventional KD concept breaks down, it is suggested that the migration process should be described in terms of the alternative concepts chemical dispersion, average-elution-time and effective retention. (AB) (134 refs.)

  14. Substance and materiality? The archaeology of Talensi medicine shrines and medicinal practices.

    Science.gov (United States)

    Insoll, Timothy

    2011-08-01

    Talensi materia medica is varied, encompassing plant, mineral, and animal substances. Healing, medicines, and medicinal practices and knowledge can be shrine-based and linked with ritual practices. This is explored utilising ethnographic data and from an archaeological perspective with reference to future possibilities for research both on Talensi medicine and, by implication, more generally through considering the archaeology of Talensi medicine preparation, use, storage, spread, and disposal. It is suggested that configuring the archaeology of medicine shrines and practices more broadly in terms of health would increase archaeological visibility and research potential.

  15. Some advances in atmospheric chemistry

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In the recent decade, researches have been carried out by our group on some aspects of atmospheric chemistry through field observation, mechanism analysis and model simulation. Here some main results on greenhouse gas (CH4, N2O) emission from Chinese agricultural fields, aerosol, global carbon cycle and ozone variation in surface laver over China are briefly reported.

  16. Computational Chemistry of Adhesive Bonds

    Science.gov (United States)

    Phillips, Donald H.

    1999-01-01

    This investigation is intended to determine the electrical mechanical, and chemical properties of adhesive bonds at the molecular level. The initial determinations will be followed by investigations of the effects of environmental effects on the chemistry and properties of the bond layer.

  17. Towards a Socio-Political History of Archaeology in the Middle East: The Development of Archaeological Practice and Its Impacts on Local Communities in Syria

    Directory of Open Access Journals (Sweden)

    Laurence Gillot

    2010-05-01

    Full Text Available No longer is Archaeology regarded as a neutral or a purely scientific discipline, but as a process influenced by the aims of its practitioners, who are, in turn, deeply affected by contemporary intellectual, social and political agendas. As well, research undertaken on archaeological practice in non-western settings, that is closely related to colonial issues, has highlighted how archaeology could be a tool of scientific, cultural, political and socio-economic domination (e.g. Diaz-Andreu 2007; Kane 2003; Silberman 1989; Trigger 1984.

  18. EM techniques for archaeological laboratory experiments: preliminary results

    Science.gov (United States)

    Capozzoli, Luigi; De Martino, Gregory; Giampaolo, Valeria; Raffaele, Luongo; Perciante, Felice; Rizzo, Enzo

    2015-04-01

    The electromagnetic techniques (EM) are based on the investigation of subsoil geophysical parameters and in the archaeological framework they involve in studying contrasts between the buried cultural structures and the surrounding materials. Unfortunately, the geophysical contrast between archaeological features and surrounding soils sometimes are difficult to define due to problems of sensitivity and resolution both related on the characteristic of the subsoil and the geophysical methods. For this reason an experimental activity has been performed in the Hydrogeosite laboratory addressed on the assessment of the capability of geophysical techniques to detect archeological remains placed in the humid/saturated subsoil. At Hydrogeosite Laboratory of CNR-IMAA, a large scale sand-box is located, consisting on a pool shape structures of 230m3 where archaeological remains have been installed . The remains are relative to a living environment and burial of Roman times (walls, tombs, roads, harbour, etc.) covered by sediments. In order to simulate lacustrine and wetland condition and to simulate extreme events (for example underwater landslide, fast natural erosion coast, etc.) the phreatic level was varied and various acquisitions for the different scenarios were performed. In order to analyze the EM behavior of the buried small archaeological framework, ground penetrating radar (GPR) and electrical resistivity tomographies were performed. With GPR, analysis in time domain and frequency domain were performed and coupled to information obtained through resistivity analysis with the support of numerical simulations used to compare the real data with those modeled. A dense grid was adopted for 400 and 900 MHz e-m acquisitions in both the directions, the maximum depth of investigation was limited and less than 3 meters. The same approach was used for ERT acquisition where different array are employed, in particular 3D configuration was used to carry out a 3D resistivity

  19. The suitability of EDXRF for compositional classification of archaeological pottery

    International Nuclear Information System (INIS)

    Many investigations have been carried out trying to enlarge the information that can be gathered through the chemical analysis of archaeological findings. Chemical composition data sets, properly interpreted with multivariate analysis techniques, have been used extensively to supplement investigations involving provenance studies or more complex socio-economic aspects of the past communities. Correct inferences from the gathered compositional data are only possible if well documented background information about the studied samples is available, such as a correct interpretation of the archaeological contexts, knowledge about the nature of the used raw materials or procurement sources (geology of the territories), among others. The combined use of Instrumental Neutron Activation Analysis (INAA) and Scanning Electron Microscopy X-ray analysis (SEM-EDX) has been widely applied to the classification of archaeological pottery. However the need to remove at least a minimal part (invasion) of the sample and the time delay required for radioisotope decay and the high costs involved in INAA often restrict its use. Energy Dispersive x-ray Fluorescence spectrometry (EDXRF) is advantageous to perform a completely non-destructive analysis in a relatively fast way, but several problems have restricted its wider use in the past. The highly matrix-dependent attenuation of x-rays in the analysed sample hampers the use of the standard-less quantification procedures as an alternative when suitable certified reference materials are not at hand, and the relatively limited instrumental sensitivity of the conventional spectrometers has not allowed the determination of some trace elements that are relevant for compositional differentiation and provided a comparatively higher uncertainties. This contribution presents the results of several investigations aimed to achieving classification of archaeological pottery using reliable quantitative EDXRF procedures. The main factors affecting the

  20. Beryllium chemistry and processing

    CERN Document Server

    Walsh, Kenneth A

    2009-01-01

    This book introduces beryllium; its history, its chemical, mechanical, and physical properties including nuclear properties. The 29 chapters include the mineralogy of beryllium and the preferred global sources of ore bodies. The identification and specifics of the industrial metallurgical processes used to form oxide from the ore and then metal from the oxide are thoroughly described. The special features of beryllium chemistry are introduced, including analytical chemical practices. Beryllium compounds of industrial interest are identified and discussed. Alloying, casting, powder processing, forming, metal removal, joining and other manufacturing processes are covered. The effect of composition and process on the mechanical and physical properties of beryllium alloys assists the reader in material selection. The physical metallurgy chapter brings conformity between chemical and physical metallurgical processing of beryllium, metal, alloys, and compounds. The environmental degradation of beryllium and its all...

  1. Prebiotic chemistry in clouds

    Science.gov (United States)

    Oberbeck, Verne R.; Marshall, John; Shen, Thomas

    1991-01-01

    The chemical evolution hypothesis of Woese (1979), according to which prebiotic reactions occurred rapidly in droplets in giant atmospheric reflux columns was criticized by Scherer (1985). This paper proposes a mechanism for prebiotic chemistry in clouds that answers Scherer's concerns and supports Woese's hypothesis. According to this mechanism, rapid prebiotic chemical evolution was facilitated on the primordial earth by cycles of condensation and evaporation of cloud drops containing clay condensation nuclei and nonvolatile monomers. For example, amino acids supplied by, or synthesized during entry of meteorites, comets, and interplanetary dust, would have been scavenged by cloud drops containing clay condensation nuclei and would be polymerized within cloud systems during cycles of condensation, freezing, melting, and evaporation of cloud drops.

  2. Is the Truth Down There?: Cultural Heritage Conflict and the Politics of Archaeological Authority

    Directory of Open Access Journals (Sweden)

    Ian Barber

    2006-06-01

    Full Text Available The selective pressures and processes of cultural heritage management effectively disinherit some interest groups. Where this occurs in the context of postcolonial or nationalist conflict, the material archaeological record may be referenced to support or reject particular views. The disciplinary assumptions behind the archaeological evidence so produced are not usually contested in judicial contexts. A review of archaeology’s theoretical foundations suggests that this naivety itself may be problematic. A descriptive culture history approach dominated archaeology over the first half of the twentieth century with a strong political appeal to nationalist politics. Subsequently archaeology became concerned with processual explanation and the scientific identification of universal laws of culture, consistent with postwar technological optimism and conformity. A postprocessual archaeology movement from the 1970s has promoted relativism and challenged the singular authority of scientific explanation. Archaeologists caught within this debate disagree over the use of the archaeological record in situations of political conflict. Furthermore, the use of archaeology in the sectarian debate over the Ayodhya birthplace of Rama suggests that the material record of the past can become highly politicized and seemingly irresolvable. Archaeological research is also subject to other blatant and subtle political pressures throughout the world, affecting the nature and interpretation of the record. A system that privileges archaeological information values may be irrelevant also to communities who value and manage their ancestral heritage for customary purposes. Collectively this review of theory and applied knowledge suggests that it is unrealistic to expect that archaeology can authoritatively resolve strident claims and debates about the past. Instead, an important contemporary contribution of archaeology may be its potential to document cultural and

  3. Preparation of archaeological samples for its dating by thermoluminescence

    International Nuclear Information System (INIS)

    The present work shows the results of the preparation of archaeological samples for their dating by thermoluminescence (Tl) using the Fine grain technique established by Zimmerman but with the varying of such preparation was realized in normal daylight conditions, only the taking of the Tl readings were realized in dark room and red light. In the chapter 1 basic concepts are described about: matter constitution, radioactivity, units and radiation magnitudes, and thermoluminescence. In the chapter 2 some theoretical aspects on dating are showed. It is described how realizing the samples collection, the fine grain method, the determination of the accumulated dose through the years or paleodoses (P=Q+I) by mean of the increasing to obtain the dose equivalent dose (Q) and the signal regeneration method to obtain the correction factor by supra linearity (1), the determination of the annual dose rate to apply the age equation and the evaluation of the age uncertainty with the error limits. The development of experimental part with samples from the archaeological site named Edzna in Campeche, Mexico is described in the chapter 3. The results are presented in the chapter 4. It was obtained an age for the sample named CH7 it was obtained an age of 389 ± years. In conclusion the preparation of the archaeological samples for their dating by Tl in the conditions before mentioned is reliable, but they must be realized more studies with samples of well known age, preparing them in normal daylight conditions and simultaneously in dark room with red light. In order to observe how respond the minerals present in the sample at different dose rapidity, the same samples must be radiated with radiation sources with different dose rate. (Author)

  4. Quantitative Chemical Analysis of Archaeological Slag Material Using Handheld X-ray Fluorescence Spectrometry.

    Science.gov (United States)

    Scott, Rebecca B; Eekelers, Kim; Degryse, Patrick

    2016-01-01

    Handheld X-ray fluorescence spectrometry (XRF) has seen a dramatic increase in use for archaeological projects. The attraction of the technique is its portable and nondestructive nature. In many cases, the archaeological artefacts in question cannot be destructively sampled, or the piece itself cannot be sent to an analytical laboratory. One of the current research interests associated with the Sagalassos project is the study of the Roman iron industry. Previously exported iron slag and ore from the site and the surrounding area was subjected to laboratory chemical analyses. These indicated that different ores were being utilized in the production of iron in different periods. In order to further the project the slag material still in the site depot needed to be analyzed. However, recent legislative changes mean that materials can only be analyzed on-site. Since samples could not be taken and destructive chemical analysis was no longer feasible, a portable, nondestructive technique was required. Handheld XRF can easily provide qualitative data, but these data are only comparable to other handheld XRF qualitative data, from the same device. Quantitative data gathering is possible, but can be more problematic, particularly when the material in question is heterogeneous in nature. A calibration file was created using the manufacturer's software and "in-house" standards made from the pre-quantified samples of iron slag available in the laboratory. In order to make the calibration as robust as possible, the composition of the standards was analyzed statistically to determine which of these created bias and leverage for specific elements. These standards were then omitted from the calibration for that element. The calibration was tested in the laboratory using samples of iron slag previously analyzed with wet chemistry, and the results indicated that most sample analyses showed 30% error were found in samples which contained very low or very high quantities of the

  5. Medicinal electrochemistry: integration of electrochemistry, medicinal chemistry and computational chemistry.

    Science.gov (United States)

    Almeida, M O; Maltarollo, V G; de Toledo, R A; Shim, H; Santos, M C; Honorio, K M

    2014-01-01

    Over the last centuries, there were many important discoveries in medicine that were crucial for gaining a better understanding of several physiological processes. Molecular modelling techniques are powerful tools that have been successfully used to analyse and interface medicinal chemistry studies with electrochemical experimental results. This special combination can help to comprehend medicinal chemistry problems, such as predicting biological activity and understanding drug action mechanisms. Electrochemistry has provided better comprehension of biological reactions and, as a result of many technological improvements, the combination of electrochemical techniques and biosensors has become an appealing choice for pharmaceutical and biomedical analyses. Therefore, this review will briefly outline the present scope and future advances related to the integration of electrochemical and medicinal chemistry approaches based on various applications from recent studies. PMID:24533810

  6. An XML-based information model for archaeological pottery

    Institute of Scientific and Technical Information of China (English)

    LIU De-zhi; RAZDAN Anshuman; SIMON Arleyn; BAE Myungsoo

    2005-01-01

    An information model is defined to support sharing scientific information on Web for archaeological pottery. Apart from non-shape information, such as age, material, etc., the model also consists of shape information and shape feature information. Shape information is collected by Lasers Scanner and geometric modelling techniques. Feature information is generated from shape information via feature extracting techniques. The model is used in an integrated storage, archival, and sketch-based query and retrieval system for 3D objects, native American ceramic vessels. A novel aspect of the information model is that it is totally implemented with XML, and is designed for Web-based visual query and storage application.

  7. A Virtual Tomb for Kelvingrove: Virtual Reality, Archaeology and Education

    Directory of Open Access Journals (Sweden)

    Melissa M. Terras

    1999-11-01

    Full Text Available The use of computers as an educational resource in museums is becoming increasingly popular as more and more institutions realise that multimedia displays are very successful in imparting a broad variety of information. Although three-dimensional reconstructions of sites and structures have been used in archaeology for many years, the majority of museum computer installations have dealt with two-dimensional media because of the costs, equipment and labour involved in producing interactive 3D scenes. The birth of VRML (Virtual Reality Modeling Language has changed the way virtual reality is implemented and viewed. As an internet protocol, VRML can be used on most major platforms and implemented by anyone with a word-processing package, an internet browser, and the relevant plug-in. There is no reason why this new technology cannot be adopted by archaeologists and museums to produce virtual reality models of structures, sites and objects to aid the research of specialists and the education of the public. This project (undertaken at the Humanities Advanced Technology and Information Institute, University of Glasgow, Scotland, between May and October 1998 investigated the practicalities involved in using VRML to create a virtual reality model for use in a public space. A model of the Egyptian tomb of Sen-nedjem was developed for installation in the Egyptian Gallery of the Kelvingrove Museum and Art Gallery, Glasgow, in the hope that the introduction of this computer display would encourage the museum visitor's interest in the gallery's existing artefacts. Creation of the model would also investigate the possibility of using VRML to build accurate archaeological reconstructions cheaply and efficiently using publicly available software and existing archaeological resources. A fully functioning virtual reality model of the tomb of Sen-nedjem has been created, incorporating interactive elements, photorealistic representation, and animation, and this

  8. Magnetic mapping and interpretation of an archaeological site in Syria

    Science.gov (United States)

    khatib alkontar, Rozan AL; Munschy, Marc; Castel, Corinne; Quenet, Philippe

    2014-05-01

    Among the subsurface methods of exploration that have been developed to meet the new requirements of archaeological research, geophysical methods offer a very wide range of applications in the study of buried deposits. In their latest developments, the prospecting method based on the measurement of the magnetic field is particularly effective at very different types of sites, ranging from prehistoric times to the most recent. The measured magnetic field observed at a place and at a time, results from the vector sum of the main regional field, the effect of subsurface structures, local disturbances such as power lines, buildings, fences, and the diurnal variation (solar influence). The principle of the magnetic method is, from magnetic measurements on a flat plane above the prospected surface, to study the three-dimensional variations of magnetization producing the magnetic anomalies. The use of magnetic surveys for archaeological prospecting is a well-established and versatile technique, and wide ranges of data processing routines are often applied to further enhance acquired data or derive source parameters. The main purpose of this work was to acquire new magnetic data on the field and to propose quantitative interpretations of magnetic maps obtained on three archaeological sites of Bronze Age in Syria (Badiyah ANR program). More precisely, some results are presented concerning one of the three sites, the Tell Al-Rawda-site which corresponds to a circular city of Early Bronze Age with a radius of about 200 m. Several profiles are used to characterize magnetizations. A large portion of archaeological geophysical data are concerned primarily with identifying the location and spatial extent of buried remains, although the data collected are likely to contain further information relating to the depth and geometry of anomalous features. A simple magnetic model corresponding to rectangular structures uniformly magnetized associated to walls cannot explain the magnetic

  9. Prompt gamma-ray analysis of archaeological bronze

    International Nuclear Information System (INIS)

    Prompt γ-ray analysis using the internal monostandard method was applied to voluminous archaeological bronze mirrors produced in ancient China. Sn/Cu content ratios were determined nondestructively by this method. Furthermore, Au/Cu, As/Cu, and Sb/Cu content ratios were determined by means of measuring decay γ-rays emitted from radioactive nuclides produced within samples via (n,γ) reactions. It is clear that the Sn/Cu content ratios in bronze mirrors produced in the Sung era is smaller than in ones produced in between the Han and the Tung era. (author)

  10. A survey of archaeological samples dated in 1988

    International Nuclear Information System (INIS)

    A survey is given of archaeological samples dated in 1988 at the Nordic Laboratory for Thermoluminescence Dating. A total of 67 samples were dated. The results were corrected for short-term fading of feldspars as measured for samples stored at room temperature for four weeks or at 100 deg. C for two weeks. The beta dose from potassium and rubidium in feldspar, and the alpha dose from uranium and thorium in quartz and feldspar were included assuming alpha efficiency factors of 0.1 for quartz and 0.2 for feldspar. (author) 22 tabs., 1 ill., 14 refs

  11. Plant remains of archaeological site Casa Vieja, Callango (Ica

    Directory of Open Access Journals (Sweden)

    José Roque

    2013-06-01

    Full Text Available A paleoethnobotanical study was carried out at the Middle Horizon archaeological site of Casa Vieja, located in Callango within the Lower Ica Valley. A total of 23 species were identified, all determined to be of the Magnoliopyta Division, 78 % (or 18 species were Magnoliopsid and 22% (or 15 species Liliopsid. The Fabaceae are the best represented family with 6 species. Most of the analyzed samples correspond to seeds of Gossypium barbadense “cotton”. Seventy percent of the species were probably used as food; 48% for artifact-making and construction and 52% for medicinal and curative purposes.

  12. A Survey of Archaeological Samples Dated in 1985

    DEFF Research Database (Denmark)

    Mejdahl, Vagn

    1986-01-01

    A survey is given of archaeological samples received for dating in 1985 at the Nordic Laboratory for Thermoluminescence Dating. A total of 66 samples were dated, 42 of which were burnt stones. All results were corrected for short-term fading as measured for samples stored at room temperature for ...... for four weeks. The beta dose from potassium and rubidium in feldspar and the alpha dose from uranium and thorium in quartz and feldspar were included assuming alpha efficiency factors of 0.1 for quartz and 0.2 for feldspar....

  13. Crowd-sourced Archaeological Research: The MicroPasts Project

    Directory of Open Access Journals (Sweden)

    Chiara Bonacchi

    2014-10-01

    Full Text Available This paper offers a brief introduction to MicroPasts, a web-enabled crowd-sourcing and crowd-funding project whose overall goal is to promote the collection and use of high quality research data via institutional and community collaborations, both on- and off-line. In addition to introducing this initiative, the discussion below is a reflection of its lead author’s core contribution to the project and will dwell in more detail on one particular aspect of MicroPasts: its relevance to research and practice in public archaeology, cultural policy and heritage studies.

  14. Early Historic Shipwreck Archaeology of the Indian Subcontinent Region

    Digital Repository Service at National Institute of Oceanography (India)

    Gaur, A.S.

    .1:73–82. Tripati, S., Gaur, A. S., Sundaresh, and Bandodkar, S. N., 2001, Shipwreck exploration in Sunchi Reef in Goa waters, West Coast of India, World Archaeology 32.3:357–69. Warmington, E. H., 1928, The Commerce between Roman Empire and India. Cambridge... centuries of the Christian era. Warmington (1928) believed that in the first two centuries of the Christian era the Roman Empire witnessed the establishment and development of a profitable commerce between two great regions, the Mediterranean countries...

  15. Satellite SAR data assessment for Silk Road archaeological prospection

    Science.gov (United States)

    Chen, Fulong; Lasaponara, Rosa; Masini, Nicola; Yang, Ruixia

    2015-04-01

    The development of Synthetic Aperture Radar (SAR) in terms of multi-band, multi-polarization and high-resolution data, favored the application of this technology also in archaeology [1]. Different approaches based on both single and multitemporal data analysis, exploiting the backscattering and the penetration of radar data, have been used for a number of archaeological sites and landscapes [2-5]. Nevertheless, the capability of this technology in archaeological applications has so far not been fully assessed. It lacks a contribution aimed at evaluating the potential of SAR technology for the same study area by using different bands, spatial resolutions and data processing solutions. In the framework of the Chinese-Italian bilateral project "Smart management of cultural heritage sites in Italy and China: Earth Observation and pilot projects", we addressed some pioneering investigations to assess multi-mode (multi-band, temporal, resolution) satellite SAR data (including X-band TerraSAR, C-band Envisat and L-band ALOS PALSAR) in archaeological prospection of the Silk road [6]. The Silk Road, a series of trade and cultural transmission routes connecting China to Europe, is the witness of civilization and friendship between the East and West dated back to 2000 years ago, that left us various relics (e.g. lost cities) to be uncovered and investigated.. In particular, the assessment has been performed in the Xinjiang and Gansu section pf the Silk Road focusing on : i) the subsurface penetration capability of SAR data in the arid and semi-arid region ii) and sensitivity of SAR imaging geometry for the detection of relics As regards the point i) , apart from the soil moisture, the penetration is seriously restricted by the soil porosity. For instance, negligible penetration signs were detected in Yumen Frontier Pass either using X- or L-band SAR data due to the occurrence of Yardang landscape. As regards the point ii), the flight path of SAR images in parallel with the

  16. Galactic Archaeology. The dwarfs that survived and perished

    CERN Document Server

    Belokurov, Vasily

    2013-01-01

    From the archaeological point of view, the local dwarf galaxies are unique objects in which the imprint of the conditions that shaped the early structure formation can be studied today at high resolution. Over the last decade, this new window into the high redshift Universe has started to be exploited using deep wide-field imaging, high resolution spectroscopy and cutting edge N-body and hydro-dynamical simulations. We review the recent advances in the observational studies of the Milky Way dwarf galaxies, with the aim to understand the properties of the population as a whole and to assist an objective comparison between the models and the data.

  17. Industrial Chemistry and School Chemistry: Making Chemistry Studies More Relevant

    Science.gov (United States)

    Hofstein, Avi; Kesner, Miri

    2006-01-01

    In this paper, we present the development and implementation over the period of more than 15 years of learning materials focusing on industrial chemistry as the main theme. The work was conducted in the Department of Science Teaching at the Weizmann Institute of Science, Israel. The project's general goal was to teach chemistry concepts in the…

  18. Physical chemistry

    CERN Document Server

    Mortimer, Robert G

    2008-01-01

    In this third edition, core applications have been added along with more recent developments in the theories of chemical reaction kinetics and molecular quantum mechanics, as well as in the experimental study of extremely rapid chemical reactions.* Fully revised concise edition covering recent developments in the field* Supports student learning with step by step explanation of fundamental principles, an appropriate level of math rigor, and pedagogical tools to aid comprehension* Encourages readers to apply theory in practical situations

  19. Identifying military impacts on archaeology deposits based on differences in soil organic carbon and chemical elements at soil horizon interfaces

    Science.gov (United States)

    The National Historic Preservation Act requires land-managing agencies to identify and account for their impacts on archaeological resources. Regulatory agencies that oversee compliance with historic preservation legislation frequently assume military training adversely affects archaeological resou...

  20. From Matter to Life:Chemistry?Chemistry!

    Institute of Scientific and Technical Information of China (English)

    Jean-Marie; LEHN

    2007-01-01

    1 Results Animate as well as inanimate matter,living organisms as well as materials,are formed of molecules and of the organized entities resulting from the interaction of molecules with each other.Chemistry provides the bridge between the molecules of inanimate matter and the highly complex molecular architectures and systems which make up living organisms. Synthetic chemistry has developed a very powerful set of methods for constructing ever more complex molecules.Supramolecular chemistry seeks to con...

  1. Green chemistry: A tool in Pharmaceutical Chemistry

    OpenAIRE

    Smita Talaviya; Falguni Majumdar

    2012-01-01

    Green chemistry expresses an area of research developing from scientific discoveries about pollution awareness and it utilizes a set of principles that reduces or eliminates the use or generation of hazardous substances in all steps of particular synthesis or process. Chemists and medicinal scientists can greatly reduce the risk to human health and the environment by following all the valuable principles of green chemistry. The most simple and direct way to apply green chemistry in pharmaceut...

  2. Archaeology and Anthropology Sites, Villa Rica, Georgia Archaeology Sites Map, Published in 2006, 1:12000 (1in=1000ft) scale, Chattahoochee-Flint Regional Development.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Archaeology and Anthropology Sites dataset, published at 1:12000 (1in=1000ft) scale, was produced all or in part from Hardcopy Maps information as of 2006. It...

  3. 75 FR 58431 - Notice of Inventory Completion: Peabody Museum of Archaeology and Ethnology, Harvard University...

    Science.gov (United States)

    2010-09-24

    ... Inventory Completion published in the Federal Register (66 FR 51464, October 9, 2001) from four to seven... National Park Service Notice of Inventory Completion: Peabody Museum of Archaeology and Ethnology, Harvard... Peabody Museum of Archaeology and Ethnology, Harvard University, Cambridge, MA. The human remains...

  4. Archaeology, Ethics, and Character: Using Our Cultural Heritage to Teach Citizenship

    Science.gov (United States)

    Moe, Jeanne M.; Coleman, Carolee; Fink, Kristie; Krejs, Kirsti

    2002-01-01

    Archaeology is a highly interdisciplinary field. Its main goal is to construct culture histories, but it uses many scientific methods in the process. Ethical dilemmas inherent in archaeology make it a good vehicle for teaching ethics and character in the classroom (Moe 2000). The interdisciplinary nature of the field makes it possible to weave…

  5. 77 FR 48533 - Notice of Inventory Completion: The Robert S. Peabody Museum of Archaeology, Phillips Academy...

    Science.gov (United States)

    2012-08-14

    ... National Park Service Notice of Inventory Completion: The Robert S. Peabody Museum of Archaeology, Phillips.... Peabody Museum of Archaeology has completed an inventory of human remains, in consultation with the... culturally affiliated with the human remains may contact the Robert S. Peabody Museum of...

  6. Excavating the Nation: Archaeology and Control of the Past and Present in Republican Sichuan

    Science.gov (United States)

    Kyong-McClain, Jeffrey

    2009-01-01

    This dissertation considers whether or not archaeology was an effective tool for nation-building elites in Republican China (1912-1949), by looking at the discipline's fortunes in the off-center locale of Sichuan province. Through consideration of the multiplicity of agents and motives involved in archaeological enterprise in Republican Sichuan,…

  7. Digging holes abroad. An ethnography of Dutch archaeological research projects abroad

    NARCIS (Netherlands)

    Linde, Sjoerd Jaap van der

    2012-01-01

    Over the last few decades, western archaeology increasingly abandoned its ‘ivory tower’ in order to investigate, negotiate and develop its position and role in global society. The way in which we deal with other peoples views in the interpretation of archaeological materials, the way in which we int

  8. 文献考古方法论刍议%On the Methodology of Documentary Archaeology

    Institute of Scientific and Technical Information of China (English)

    何驽

    2002-01-01

    The application of historical literature in archaeological research has been lack of methodological formalization. This situation has retarden the establishment of epistemological consentience, leading to dispute about historical records among Chinese archaeologists. The article argues that the systematic correspondence between potential logic of historical literature and archaeological contexts could serve as the datum point for the utilization of ancient literature.

  9. Pattern to process : methodological investigations into the formation and interpretation of spatial patterns in archaeological landscapes

    NARCIS (Netherlands)

    Leusen, Pieter Martijn van

    2002-01-01

    My research has shown that the type of regional archaeological data analysis required by landscape archaeological approaches is an area where both theory and method are still in their infancy. High-level theories about the occurrence, scope, and effects of processes such as centralization, urbanizat

  10. Computer graphics and urban archaeology Bracara Augusta’s case study

    OpenAIRE

    Bernardes, P.; Martins, Manuela

    2004-01-01

    Computer graphics is undoubtedly an important tool, widely used for representing and manipulating enormous amounts of highly complex information. Usually, the archaeological information is highly complex, so its representation using computer graphics technology is a true and engaging challenge. Virtual reconstructions representing archaeological sites, as for example the roman town Bracara Augusta, should be considered a fundamental tool for research improvement carried out by ...

  11. Treasures from the Past: Using Archaeology in Upper-Elementary Social Studies.

    Science.gov (United States)

    Gardner, Cynthia C.

    1997-01-01

    Describes a fourth grade teacher's interdisciplinary efforts at imparting the joys of archaeology to her students. The students read fiction and non-fiction materials about the physical environments and participated in a series of hands-on learning activities. These involved simulated archaeological digs, personal artifacts, and realia. (MJP)

  12. The Oxford Handbook of the Archaeology and Anthropology of Hunter-Gatherers

    NARCIS (Netherlands)

    Cummings, Vicky; Jordan, Peter; Zvelebil, Marek

    2014-01-01

    For more than a century, the study of hunting and gathering societies has been central to the development of both archaeology and anthropology as academic disciplines, and has also generated widespread public interest and debate. The Oxford Handbook of the Archaeology and Anthropology of Hunter-Gath

  13. Grounding the past : the praxis of participatory archaeology in the Mixteca Alta, Oaxaca, Mexico

    NARCIS (Netherlands)

    Geurds, Alexander

    2007-01-01

    "Grounding the Past" addresses archaeological field praxis and its role in the political present of Santiago Tilantongo and Santiago Apoala, two communities in the Mixteca Alta region of Oaxaca, Mexico. Efforts to involve local stakeholder communities in archaeology have become an important issue wo

  14. Prehistoric Archaeology and Poetic Wisdom%史前考古学与诗性智慧

    Institute of Scientific and Technical Information of China (English)

    户晓辉

    2001-01-01

    Archaeological remains of the prehistoric times are the results of poetic wisdom of the prehistoric people. They are spiritual rather than material remains. Thus archaeological studies need not only giving explanations on the materials but also understanding them in a multidiscipline background.

  15. A Review of the International Academic Symposium on Tibetan Archaeology and Art

    Institute of Scientific and Technical Information of China (English)

    ZhangChanghong

    2004-01-01

    To date at least two aspects of Tibetan studies have become prominent. One is Tibetan archaeology which has grown from a base of ever-enriching fieldwork, and the other is Tibetan art studies which is dominated by Tibetan Buddhist art. In western humanity disciplines,archaeology and art history have always been regarded

  16. David Hurst Thomas and the Historical Archaeology of the Spanish Borderlands.

    Science.gov (United States)

    Snead, James E.

    2000-01-01

    Discusses David Hurst Thomas' archaeological work on the Spanish borderlands, which integrates field archaeology and documentary history. Focuses on locating and studying the Santa Catalina de Guale. Addresses his project on the Pueblo San Marcos that will further test his ideas about the Spanish mission period. (CMK)

  17. Listing of Education in Archaeological Programs: The LEAP Clearinghouse, 1989-1989 Summary Report.

    Science.gov (United States)

    Knoll, Patricia C., Ed.

    This catalog incorporates information gathered between 1987 and 1989 for inclusion into the National Park Service's Listing of Education in Archaeological Programs (LEAP) computerized database. This database is a listing of federal, state, local and private projects promoting positive public awareness of U.S. archaeology--prehistoric and historic,…

  18. Chemistry Rocks: Redox Chemistry as a Geologic Tool.

    Science.gov (United States)

    Burns, Mary Sue

    2001-01-01

    Applies chemistry to earth science, uses rocks in chemistry laboratories, and teaches about transition metal chemistry, oxidation states, and oxidation-reduction reactions from firsthand experiences. (YDS)

  19. Solid-State Chemistry as a Formation Mechanism for C 4N 2 Ice and Possibly the Haystack (220 cm -1 ice emission feature) in Titan's Stratosphere as Observed by Cassini CIRS

    Science.gov (United States)

    Anderson, Carrie; Samuelson, Robert E.; McLain, Jason L.; Nna Mvondo, Delphine; Romani, Paul; Flasar, F. Michael

    2016-10-01

    A profusion of organic ices containing hydrocarbons, nitriles, and combinations of their mixtures comprise Titan's complex stratospheric cloud systems, and are typically formed via vapor condensation. These ice particles are then distributed throughout the mid-to-lower stratosphere, with an increased abundance near the winter poles (see Anderson et al., 2016). The cold temperatures and the associated strong circumpolar winds that isolate polar air act in much the same way as on Earth, giving rise to compositional anomalies and stratospheric clouds that provide heterogeneous chemistry sites.Titan's C4N2 ice emission feature at 478 cm-1 and "the Haystack," a strong unidentified stratospheric ice emission feature centered at 220 cm-1, share a common characteristic. Even though both are distinctive ice emission features evident in Cassini Composite InfraRed (CIRS) far-IR spectra, no associated vapor emission features can be found in Titan's atmosphere. Without a vapor phase, solid-state chemistry provides an alternate mechanism beside vapor condensation for producing these observed stratospheric ices.Anderson et al., (2016) postulated that C4N2 ice formed in Titan's stratosphere via the solid-state photochemical reaction HCN + HC3N → C4N2 + H2 can occur within extant HCN-HC3N composite ice particles. Such a reaction, and potentially similar reactions that may produce the Haystack ice, are specific examples of solid-state chemistry in solar system atmospheres. This is in addition to the reaction HCl + ClONO2 → HNO3 + Cl2, which is known to produce HNO3 coatings on terrestrial water ice particles, a byproduct of the catalytic chlorine chemistry that produces ozone holes in Earth's polar stratosphere (see for example, Molina et al., 1987 Soloman, 1999).A combination of radiative transfer modeling of CIRS far-IR spectra, coupled with optical constants derived from thin film transmittance spectra of organic ice mixtures obtained in our Spectroscopy for Planetary ICes

  20. Surface modification of Fe{sub 2}O{sub 3} nanoparticles with 3-aminopropyltrimethoxysilane (APTMS): An attempt to investigate surface treatment on surface chemistry and mechanical properties of polyurethane/Fe{sub 2}O{sub 3} nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Palimi, M.J. [Institute for Color Science and Technology (ICST), PO 16765-654, Tehran (Iran, Islamic Republic of); Rostami, M., E-mail: rostami-m@icrc.ac.ir [Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology (ICST), PO 16765-654, Tehran (Iran, Islamic Republic of); Mahdavian, M.; Ramezanzadeh, B. [Department of Surface Coatings and Corrosion, Institute for Color Science and Technology (ICST), PO 16765-654, Tehran (Iran, Islamic Republic of)

    2014-11-30

    Highlights: • Surface treatment of Fe{sub 2}O{sub 3} with amino propyl tri methoxy silane. • The surface chemistry pigments were affected by the chemical treatment. • Surface treatment of the nanoparticles by silane resulted in the significant improvement of the mechanical properties of the polyurethane coating. • The improvement was most pronounced when the nanoparticles were modified with 3 gr silane/5 g nanoparticles. - Abstract: Fe{sub 2}O{sub 3} nanoparticles were modified with various amounts of 3-amino propyl trimethoxy silane (APTMS). Modified and unmodified nanoparticles were introduced into the polyurethane matrix at different concentrations. Fourier transform infrared radiation (FT-IR) and X-ray photoelectron spectrophotometer (XPS) were employed in order to investigate the APTMS grafting on the nanoparticles field emission-scanning electron microscope (FE-SEM) was utilized in order to investigate nanoparticles dispersion in the polyurethane coating matrix as well as the fracture behavior of the nanocomposites. The mechanical properties of the nanocomposites were investigated by dynamic mechanical thermal analysis (DMTA) and tensile test. The FTIR spectra and XPS analysis clearly showed that APTMS was grafted on the surface of nanoparticles successfully and formed chemical bonds with the surface. Also, surface treatment of the nanoparticles by silane resulted in the significant improvement of the mechanical properties of the polyurethane coating. The improvement was most pronounced when the nanoparticles were modified with 3 gr silane/5 g nanoparticles.