Pilot-scale investigation of the robustness and efficiency of a copper-based treated wood wastes recycling process

Energy Technology Data Exchange (ETDEWEB)

Coudert, Lucie [INRS-ETE (Canada); Blais, Jean-François, E-mail: blaisjf@ete.inrs.ca [INRS-ETE (Canada); Mercier, Guy [INRS-ETE (Canada); Cooper, Paul [University of Toronto (Canada); Gastonguay, Louis [IREQ (Canada); Morris, Paul [FPInnovations (Canada); Janin, Amélie; Reynier, Nicolas [INRS-ETE (Canada)

2013-10-15

Highlights: • A leaching process was studied for metals removal from CCA-treated wood wastes. • This decontamination process was studied at pilot scale (130-L reactor). • Removals up to 98% of As, 88% of Cr, and 96% of Cu were obtained from wood wastes. • The produced leachates can be treated by chemical precipitation. -- Abstract: The disposal of metal-bearing treated wood wastes is becoming an environmental challenge. An efficient recycling process based on sulfuric acid leaching has been developed to remove metals from copper-based treated wood chips (0 < x < 12 mm). The present study explored the performance and the robustness of this technology in removing metals from copper-based treated wood wastes at a pilot plant scale (130-L reactor tank). After 3× 2 h leaching steps followed by 3× 7 min rinsing steps, up to 97.5% of As, 87.9% of Cr, and 96.1% of Cu were removed from CCA-treated wood wastes with different initial metal loading (>7.3 kg m{sup −3}) and more than 94.5% of Cu was removed from ACQ-, CA- and MCQ-treated wood. The treatment of effluents by precipitation–coagulation was highly efficient; allowing removals more than 93% for the As, Cr, and Cu contained in the effluent. The economic analysis included operating costs, indirect costs and revenues related to remediated wood sales. The economic analysis concluded that CCA-treated wood wastes remediation can lead to a benefit of 53.7 US$ t{sup −1} or a cost of 35.5 US$ t{sup −1} and that ACQ-, CA- and MCQ-treated wood wastes recycling led to benefits ranging from 9.3 to 21.2 US$ t{sup −1}.

Chemical modification of wood

Science.gov (United States)

Roger M. Rowell

2007-01-01

After millions of years of evolution, wood was designed to perform in a wet environment, and nature is programmed to recycle it, in a timely way, back to the basic building blocks of carbon dioxide and water through biological, thermal, aqueous, photochemical, chemical, and mechanical degradation. The properties of wood are, for the most part, a result of the chemistry...

Formation of dioxins and furans during combustion of treated wood

Energy Technology Data Exchange (ETDEWEB)

Tame, Nigel W.; Dlugogorski, Bogdan Z.; Kennedy, Eric M. [Process Safety and Environment Protection Research Group, School of Engineering, The University of Newcastle, Callaghan, NSW 2308 (Australia)

2007-08-15

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F, dioxin) are produced in combustion of wood treated with copper-based preservatives. This review summarises and analyses the pertinent literature on the role of preservatives in the formation of dioxin in the low-temperature, vitiated environment that exists in the domestic combustion of wood, and in large-scale fires. Until recently, the role of preservatives was not thoroughly examined in the literature with respect to fires, as incineration attracted most of the research focus. However, latest studies have demonstrated that some current and emerging wood preservatives significantly increase dioxin formation during combustion in domestic stoves and in fires. The following pathways are identified: (i) copper, a common biocide that is chemically bound to the wood, is an important dioxin catalyst, (ii) preservative metals promote smouldering of wood char following cessation of flaming, providing the required temperature environment for dioxin formation, and (iii) chlorinated organics added as secondary preservative components yield dioxin precursors upon thermal decomposition. These conclusions indicate that it remains hazardous to dispose of preservative impregnated timber via domestic combustion even if arsenic is not present. (author)

Finishability of CCA pressure-treated wood

Science.gov (United States)

Alan Ross; Richard Carlson; William Feist; Steven Bussjaeger

2000-01-01

Thus, a need arose for the development of surface finishes for CCA-treated wood that could address the special requirements of this substrate and provide protection against the ravages of water, sunlight, mildew, and other aspects of weathering and wear. Initially, this need was not addressed, most wood preserving companies had little expertise in surface finishes and...

Studies on thermal degradation and termite resistant properties of chemically modified wood

Energy Technology Data Exchange (ETDEWEB)

Deka, M.; Saikia, C.N. [Council for Scientific and Industrial Research (CSIR), Regional Research Laboratory, Jorhat (India); Baruah, K.K. [Assam Agricultural University, Jorhat (India)

2002-09-01

A series of experiments were carried out to examine the resistant capacity of a chemically treated hard wood, Anthocephalus cadamba (Roxb) Miq. to thermal and termite degradation. The treatment with thermosetting resins viz. urea formaldehyde (UF), melamine formaldehyde (MF) and phenol formaldehyde (PF) at 31-33 levels of weight percent gain (WPG) increased the strength property i.e. modulus of rupture (MOR) by 7.50-21.02% and stiffness i.e. modulus of elasticity (MOE) by 9.50-12.18% over the untreated one with no remarkable effect on specific gravity. The treated samples were found resistant to termite attack, while the untreated one was badly damaged by termites on 12 months' exposure to a termite colony. The thermal degradations of untreated and treated wood samples were studied using thermogravimetric (TGA) and differential thermogravimetric (DTG) techniques at heating rates 20 and 30 {sup o}Cmin{sup -1} in temperature range 30-650{sup o}C. The treated wood was found to be thermally more stable than the untreated one. (author)

Effect of weathering on chromated copper arsenate (CCA) treated wood : leaching of metal salts and change in water repellency

Science.gov (United States)

R. Sam Williams; Stan Lebow; Patricia Lebow

2003-01-01

Wood pressure-treated with chromated copper arsenate (CCA) wood preservative is commonly used for outdoor construction. Oxides of arsenic, copper, and chromium are bound in the wood by a complex series of chemical reactions, but a small percentage of these compounds are gradually released by leaching and weathering. Recent studies suggest that the release of these...

Variability in evaluating environmental impacts of treated wood.

Science.gov (United States)

Stan T. Lebow; Paul Cooper; Patricia K. Lebow

2004-01-01

Preservative-treated wood contains components that may be toxic to non-target organisms if released into the environment in sufficient quantities. Numerous studies have been conducted to determine the rate of preservative release from treated wood and/or the extent of their subsequent accumulation in the environment. These studies have produced a wide range of results...

Modification of polypropylene with radiation-treated wood fiber

International Nuclear Information System (INIS)

Czvikovszky, T.; Tapolcai, I.

1983-01-01

The dispersed wood material is used not only as filler for thermosetting polymers but also as a new type of fibrous additive for thermoplastics e.g. polypropylene. Benefit of this additive (filler or reinforcement) is determined by the coupling between the wood and the synthetic resin. Fibrous, dispersed wood material was preirradiated in air, treated with vinyl monomer containing polyester resin and then mixed in polypropylene. Processability of such thermoplastic blends as well as reactivity of the mixed components were followed by measuring energy, absorbed during the kneading of the melt. The vinylmonomer vinylmonomer - polyester additive, activated at higher temperature by the radiation-formed peroxy groups on the wood fiber, results in good processability of the thermoplastic blend, and gives interesting mechanical properties. Calandering, extrusion, pressmoulding and mechanical testing demonstrated good workability and practical value of the polypropylene composite material containing radiation-treated wood fiber. (author)

Bond quality of phenol-based adhesives containing liquefied creosote-treated wood

Science.gov (United States)

Chung-Yun Hse; Feng Fu; Hui Pan

2009-01-01

Liquefaction of spent creosote-treated wood was studied to determine the technological practicability of its application in converting treated wood waste into resin adhesives. A total of 144 plywood panels were fabricated with experimental variables included 2 phenol to wood (P/W) ratios in liquefaction, 6 resin formulations (3 formaldehyde/liquefied wood (F/...

Influences of Thermo-Vacuum Treatment on Colors and Chemical Compositions of Alder Birch Wood

Directory of Open Access Journals (Sweden)

Yan Yang

2015-10-01

Full Text Available With high temperature-heat treatment, the dimensional stability and durability of wood is improved and wood color is darkened as well. In this paper, alder birch wood (Betula alnoides was treated by the Thermo-Vacuum Treatment (TVT. The changes of wood color parameters and the chemical composition were determined by the CIE1976 L*a*b* method and the chemical analysis method, respectively. The results were revealed as follows: (1 A lower value of lightness, L*, and a higher value of total color difference, △E*, were obtained at the higher heat-treatment temperatures and longer treatment time. (2 The higher the heat-treatment temperatures and the longer the heat-treatment times were, the lower the contents of hemicellulose and cellulose were and the higher the content of lignin was. Moreover, Fourier Transform infrared spectroscopy (FTIR analysis demonstrated that the characteristic absorption peaks of cellulose, hemicellulose, and lignin diminished. The acetylation reaction of hemicellulose and the degradation reaction of groups of lignin side chain occurred during TVT. (3 TVT degraded the chemical composition of cell walls, which resulted in further changes of the wood color. A significant correlation existed between the differences of color indices and the differences of the chemical composition after TVT.

Microdistribution of copper-carbonate and iron oxide nanoparticles in treated wood

Energy Technology Data Exchange (ETDEWEB)

Matsunaga, Hiroshi, E-mail: mhiroshi@ffpri.affrc.go.jp; Kiguchi, Makoto [Forestry and Forest Products Research Institute (Japan); Evans, Philip D. [University of British Columbia, Centre for Advanced Wood Processing (Canada)

2009-07-15

Aqueous dispersions of copper-carbonate nanoparticles and microparticles have just begun to be exploited commercially for the preservative treatment of wood. The success of the new systems will depend, in part, on the uniform distribution of the preservative in wood and the ability of copper to penetrate cell walls. We examined the distribution of copper in wood treated with a nano-Cu preservative. Copper particles are not uniformly distributed in treated wood, but they accumulate in voids that act as the flow paths for liquids in wood. Particles are deposited on, but not within cell walls. Nevertheless, elemental copper is present within cell walls, but at a lower level than that in wood treated with a conventional wood preservative. These findings suggest that nano-Cu preservatives are able to deliver bioactive components into wood cell walls even though the majority of copper particles are too large to penetrate the cell wall's nanocapillary network.

The fungal composition of natural biofinishes on oil-treated wood

NARCIS (Netherlands)

van Nieuwenhuijzen, Elke J.; Houbraken, Jos A. M. P.; Punt, Peter J; Roeselers, Guus; Adan, Olaf C G; Samson, Robert A.

2017-01-01

Biofinished wood is considered to be a decorative and protective material for outdoor constructions, showing advantages compared to traditional treated wood in terms of sustainability and self-repair. Natural dark wood staining fungi are essential to biofinish formation on wood. Although all sorts

The fungal composition of natural biofinishes on oil-treated wood

NARCIS (Netherlands)

van Nieuwenhuijzen, E.J.; Houbraken, J.A.M.P.; Punt, P.J.; Roeselers, G.; Adan, O.C.G.; Samson, R.A.

2017-01-01

Background Biofinished wood is considered to be a decorative and protective material for outdoor constructions, showing advantages compared to traditional treated wood in terms of sustainability and self-repair. Natural dark wood staining fungi are essential to biofinish formation on wood. Although

Weathering methods for preservative treated wood and their applicability for fire retarded wood

NARCIS (Netherlands)

Voss, A.

1999-01-01

preservative treated wood. The aim of the presentation is to inform you about current testing methods and to discuss their applicability to test fire retarded wood in outdoor use. Assuming that fire retardants will only be used in out of ground contact, only those methods are mentioned, which fit

FIELD-SCALE LEACHING OF ARSENIC, CHROMIUM AND COPPER FROM WEATHERED TREATED WOOD

Science.gov (United States)

Hasan, A. Rasem; Hu, Ligang; Solo-Gabriele, Helena M.; Fieber, Lynne; Cai, Yong; Townsend, Timothy G.

2010-01-01

Earlier studies documented the loss of wood preservatives from new wood. The objective of this study was to evaluate losses from weathered treated wood under field conditions by collecting rainfall leachate from 5 different wood types, all with a surface area of 0.21 m2. Wood samples included weathered chromate copper arsenate (CCA) treated wood at low (2.7 kg/m3), medium (4.8 kg/m3) and high (35.4 kg/m3) retention levels, new alkaline copper quat (ACQ) treated wood (1.1 kg/m3 as CuO) and new untreated wood. Arsenic was found to leach at a higher rate (100 mg in 1 year for low retention) than chromium and copper (leached at the highest rate from the ACQ sample (670 mg). Overall results suggest that metals’ leaching is a continuous process driven by rainfall, and that the mechanism of release from the wood matrix changes as wood weathers. PMID:20053493

A new material for chemical industry - wood polymer composites

International Nuclear Information System (INIS)

Majali, A.B.; Patil, N.D.

1979-01-01

The paper outlines the advantages of the radiation cured wood-polymer composites (WPC) for application in certain critical areas of chemical industry. The wood-polymer composite made filterpress frames and plates were tested in a chemical plant. The entire exercise is elaborated. The radiation cured wood exhibited a considerably extended useful life in alkaline and acidic solutions. Composites based on teak wood showed a remarkable improvement with a nominal polymer loading of 10%. The reports of accelerated aging test of WPC are also presented. (auth.)

Wood preservative testing

Science.gov (United States)

Rebecca Ibach; Stan T. Lebow

2012-01-01

Most wood species used in commercial and residential construction have little natural biological durability and will suffer from biodeterioration when exposed to moisture. Historically, this problem has been overcome by treating wood for outdoor use with toxic wood preservatives. As societal acceptance of chemical use changes, there is continual pressure to develop and...

Use of handheld X-ray fluorescence spectrometry units for identification of arsenic in treated wood

Energy Technology Data Exchange (ETDEWEB)

Block, Colleen N. [University of Miami, Department of Civil, Architectural, and Environmental Engineering, P.O. Box 248294, McArthur Building, Coral Gables, FL 33124-0630 (United States); Shibata, Tomoyuki [University of Miami, Department of Civil, Architectural, and Environmental Engineering, P.O. Box 248294, McArthur Building, Coral Gables, FL 33124-0630 (United States); Solo-Gabriele, Helena M. [University of Miami, Department of Civil, Architectural, and Environmental Engineering, P.O. Box 248294, McArthur Building, Coral Gables, FL 33124-0630 (United States)]. E-mail: hmsolo@miami.edu; Townsend, Timothy G. [University of Florida, Department of Environmental Engineering Sciences, Gainesville, FL 32611-6450 (United States)

2007-07-15

The objective of this study was to evaluate the performance of handheld XRF analyzers on wood that has been treated with a preservative containing arsenic. Experiments were designed to evaluate precision, detection limit, effective depth of analysis, and accuracy of the XRF arsenic readings. Results showed that the precision of the XRF improved with increased sample concentration and longer analysis times. Reported detection limits decreased with longer analysis times to values of less than 1 mg/kg or 18 mg/kg, depending on the model used. The effective depth of analysis was within the top 1.2 cm and 2.0 cm of sample for wood containing natural gradients of chemical preservative and concentration extremes, respectively. XRF results were found to be 1.5-2.3 times higher than measurements from traditional laboratory analysis. Equations can be developed to convert XRF values to results which are consistent with traditional laboratory testing. - Handheld XRF analyzers provided quantitative results for the amount of arsenic within preservative-treated wood.

A Survey of Wood Protection Chemicals, Tree Killers and Sprayers ...

African Journals Online (AJOL)

chemicals used in wood protection (preservation) within Makurdi metropolis. A purposive, non-random sampling was undertaken in Makurdi metropolis to identify wood protection chemicals/tree-killers available in agrochemical stores, ...

Aureobasidium melanogenum: a native of dark biofinishes on oil treated wood.

Science.gov (United States)

van Nieuwenhuijzen, Elke J; Houbraken, Jos A M P; Meijer, Martin; Adan, Olaf C G; Samson, Robert A

2016-05-01

The genus Aureobasidium, which is known as a wood staining mould, has been detected on oil treated woods in the specific stain formation called biofinish. This biofinish is used to develop a new protective, self-healing and decorative biotreatment for wood. In order to understand and control biofinish formation on oil treated wood, the occurrence of different Aureobasidium species on various wood surfaces was studied. Phenotypic variability within Aureobasidium strains presented limitations of morphological identification of Aureobasidium species. PCR amplification and Sanger sequencing of ITS and RPB2 were used to identify the culturable Aureobasidium species composition in mould stained wood surfaces with and without a biofinish. The analysed isolates showed that several Aureobasidium species were present and that Aureobasidium melanogenum was predominantly detected, regardless of the presence of a biofinish and the type of substrate. A. melanogenum was detected on wood samples exposed in the Netherlands, Cameroon, South Africa, Australia and Norway. ITS-specific PCR amplification, cloning and sequencing of DNA extracted from biofinish samples confirmed results of the culturing based method: A. melanogenum is predominant within the Aureobasidium population of biofinishes on pine sapwood treated with raw linseed oil and the outdoor placement in the Netherlands.

The use of new, aqueous chemical wood modifications to improve the durability of wood-plastic composites

Science.gov (United States)

Rebecca E. Ibach; Craig M. Clemons; George C. Chen

2017-01-01

The wood flour used in wood-plastic composites (WPCs) can biologically deteriorate and thus the overall mechanical performance of WPCs decrease when exposed to moisture and fungal decay. Protecting the wood flour by chemical modification can improve the durability of the wood in a nontoxic way so it is not harmful to the environment. WPCs were made with modified wood...

Technological and Thermal Properties of Thermoplastic Composites Filled with Heat-treated Alder Wood

Directory of Open Access Journals (Sweden)

Mürşit Tufan

2016-02-01

Full Text Available This study investigated the effect of heat-treated wood content on the water absorption, mechanical, and thermal properties of wood plastic composites (WPCs. The WPCs were produced from various loadings (30, 40, and 50 wt% of heat-treated and untreated alder wood flours (Alnus glutinosa L. using high-density polyethylene (HDPE with 3 wt% maleated polyethylene (MAPE coupling agent. All WPC formulations were compression molded into a hot press for 3 min at 170 ºC. The WPCs were evaluated using mechanical testing, Fourier transform infrared spectroscopy (FTIR, thermogravimetric analysis (TGA, and differential scanning calorimetry (DSC. The mechanical property values of the WPC specimens decreased with increasing amounts of the heat-treated wood flour, except for the tensile modulus values. The heat treatment of alder wood slightly increased the thermal stability of the WPCs compared with the reference WPCs. The crystallization degree (Xc and the enthalpy of crystallization of the WPCs slightly decreased with increasing content of the heat-treated wood flour. However, all WPCs containing the heat-treated alder wood flour showed a higher crystallinity degree than that of the virgin HDPE.

Quantities of arsenic-treated wood in demolition debris generated by Hurricane Katrina.

Science.gov (United States)

Dubey, Brajesh; Solo-Gabriele, Helena M; Townsendt, Timothy G

2007-03-01

The disaster debris from Hurricane Katrina is one of the largest in terms of volume and economic loss in American history. One of the major components of the demolition debris is wood waste of which a significant proportion is treated with preservatives, including preservatives containing arsenic. As a result of the large scale destruction of treated wood structures such as electrical poles, fences, decks, and homes a considerable amount of treated wood and consequently arsenic will be disposed as disaster debris. In this study an effort was made to estimate the quantity of arsenic disposed through demolition debris generated in the Louisiana and Mississippi area through Hurricane Katrina. Of the 72 million cubic meters of disaster debris generated, roughly 12 million cubic meters were in the form of construction and demolition wood resulting in an estimated 1740 metric tons of arsenic disposed. Management of disaster debris should consider the relatively large quantities of arsenic associated with pressure-treated wood.

WOOD STOVE EMISSIONS: PARTICLE SIZE AND CHEMICAL COMPOSITION

Science.gov (United States)

The report summarizes wood stove particle size and chemical composition data gathered to date. [NOTE: In 1995, EPA estimated that residential wood combustion (RWC), including fireplaces, accounted for a significant fraction of national particulate matter with aerodynamic diameter...

Carcinogenic risk of chromium, copper and arsenic in CCA-treated wood

International Nuclear Information System (INIS)

Ohgami, Nobutaka; Yamanoshita, Osamu; Thang, Nguyen Dinh; Yajima, Ichiro; Nakano, Chihiro; Wenting, Wu; Ohnuma, Shoko

2015-01-01

We showed that 2.1% of 233 pieces of lumber debris after the Great East Japan Earthquake was chromated copper arsenate (CCA)-treated wood. Since hexavalent chromium (Cr), copper (Cu) and pentavalent arsenic (As) in the debris may be diffused in the air via incineration, we exposed human lung normal (BEAS-2B) and carcinoma (A549) cells to Cr, Cu and As at the molar ratio in a representative CCA-treated wood. Co-exposure to 0.10 μM Cr and 0.06 μM As, which solely had no effect on colony formation, synergistically promoted colony formation in BEAS-2B cells, but not A549 cells, with activation of the PI3K/AKT pathway. Sole exposure and co-exposure to Cu showed limited effects. Since previous reports showed Cr and As concentrations to which human lungs might be exposed, our results suggest the importance to avoid diffusion of Cr and As in the air via incineration of debris including CCA-treated wood after the disaster. - Highlights: • CCA-treated wood was found in debris after the Great East Japan Earthquake in 2011. • Carcinogenic risk of CCA-treated woods was evaluated with human lung cell lines. • Co-exposure to Cr and As synergistically promoted colony formation. • Co-exposure to Cr and As synergistically activated the PI3/AKT pathway. • Effects of sole exposure and co-exposure to Cu on colony formation were limited. - Co-exposure to Cr and As, but not Cu, in CCA-treated wood debris from the Great East Japan Earthquake showed carcinogenicity in vitro.

Environmental impact of preservative-treated wood in a wetland boardwalk.

Science.gov (United States)

Stan T. Lebow; Patricia K. Lebow; Daniel O. Foster; Kenneth M. Brooks

Forest Service, Bureau of Land Management, and industry partners are cooperating in a study of the leaching and environmental effects of a wetland boardwalk. The construction project is considered bworst casec because the site has high rainfall and large volumes of treated wood were used. Separate boardwalk test sections were constructed using untreated wood or wood...

Environmental issues: New techniques for managing and using wood fuel ash

Energy Technology Data Exchange (ETDEWEB)

Fehrs, J.E.; Donovan, C.T. [C.T. Donovan Associates, Inc., Burlington, VT (United States)

1993-12-31

Continued research and development of environmentally-acceptable and cost-effective end uses for wood ash is having a significant affect on the ability to use wood and wood waste for fuel. This is particularly true for ash resulting from treated wood combustion. Concerns about the contents of ash from wood containing paint, stain, preservatives, or other chemicals is one of the largest regulatory barriers to its use as fuel. The purpose of this paper is to: (1) Identify the physical and chemical characteristics of ashes produced from the combustion of untreated and treated wood; (2) Explain the types of {open_quotes}clean, untreated{close_quotes} and {open_quotes}treated{close_quotes} wood that are likely to produce ash that can beneficially used; (3) Describe existing and potential products and end uses for untreated and treated wood ash.

REMOVAL COPPER, CHROMIUM, ARSENIC FROM OUT-OF- SERVICE CCA-TREATED WOOD MATERIALS

Directory of Open Access Journals (Sweden)

Engin Derya Gezer

2004-11-01

Full Text Available Remediation can be defined as removing copper, chromium and arsenic from out-of-service CCA treated wood products. There are some various remediation methods that can be applied to remove copper, chromium and arsenic from out-of service CCA treated wood products in order to re-use that wooden materials and minimize adverse impacts of those out-of service CCA treated wood to environment, human health, animals and other living organisms. In this study, those applied various remediation methods to remove copper, chromium and arsenic were summarized.

Chemical characterisation of the whole plant cell wall of archaeological wood: an integrated approach.

Science.gov (United States)

Zoia, Luca; Tamburini, Diego; Orlandi, Marco; Łucejko, Jeannette Jacqueline; Salanti, Anika; Tolppa, Eeva-Liisa; Modugno, Francesca; Colombini, Maria Perla

2017-07-01

Wood artefacts undergo complex alteration and degradation during ageing, and gaining information on the chemical composition of wood in archaeological artefacts is fundamental to plan conservation strategies. In this work, an integrated analytical approach based on innovative NMR spectroscopy procedures, gel permeation chromatography and analytical pyrolysis coupled with gas chromatography/mass spectrometry (Py-GC-MS) was applied for the first time on archaeological wood from the Oseberg collection (Norway), in order to evaluate the chemical state of preservation of the wood components, without separating them. We adopted ionic liquids (ILs) as non-derivatising solvents, thus obtaining an efficient dissolution of the wood, allowing us to overcome the difficulty of dissolving wood in its native form in conventional molecular solvents. Highly substituted lignocellulosic esters were therefore obtained under mild conditions by reacting the solubilised wood with either acetyl chloride or benzoyl chloride. A phosphytilation reaction was also performed using 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholan. As a result, the functionalised wood developed an enhanced solubility in molecular solvents, thus enabling information about modifications of lignin, depolymerisation of cellulose and structure of lignin-carbohydrate complexes to be obtained by means of spectroscopic (2D-HSQC-NMR and 31 P-NMR) and chromatographic (gel permeation chromatography) techniques. Py-GC-MS was used to investigate the degradation undergone by the lignocellulosic components on the basis of their pyrolysis products, without any pre-treatment of the samples. The application of all these combined techniques enabled a comprehensive characterisation of the whole cell wall of archaeological wood and the evaluation of its state of preservation. High depletion of carbohydrates and high extent of lignin oxidation were highlighted in the alum-treated objects, whereas a good preservation state was found

Creosote movement from treated wood immersed in fresh water

Science.gov (United States)

Sung-Mo Kang; Jeffrey J. Morrell; John Simonsen; Stan Lebow

2005-01-01

Creosote has a long history of successful use as a wood preservative, but polycyclic aromatic hydrocarbons in this preservative have raised environmental concerns, particularly when creosote-treated wood is used in aquatic environments. A number of models have been developed to predict the risk of creosote use in aquatic environments, but one limitation of these models...

Enhanced oil recovery chemicals from renewable wood resources

Energy Technology Data Exchange (ETDEWEB)

Grune, W.N.; Compere, A.L.; Griffith, W.L.; Crenshaw, J.M.

1979-04-01

Most of the wood pulp in the U.S. is produced by cooking, or digesting, wood chips in a chemical solution. These pulping processes have effluent streams which contain dissolved lignins, lignin breakdown products, and carbohydrates. There is a substantial economic incentive to use these materials as feedstocks for the production of high-valued micellar flood chemicals. The pulp and paper industries have practiced chemical recovery for almost a century. The largest chemical recycle processes are the internal recycle of inorganic salts for reuse in pulping. This is coupled with the use of waste organic compounds in the liquor as a fuel for directly-fired evaporation processes. Diversion of effluent and low valued streams for chemical recovery using fermentation, purification, or synthesis methods appears technically feasible in several cases. The use of new recovery processes could yield a variety of different wood-effluent based products. Some of the sugar acids in pulping liquors might be used as sequestering agents in reservoirs where there are large amounts of multivalent cations in flood brines. Fermentation production of high viscosity polymers, sequestering agents, and coagent alcohols appears worth further investigation. Tall oil acids and their derivatives can be used as surfactants in some reservoirs. Some waste constituents may adsorb preferentially on formations and thereby reduce loss of surfactants and other higher-valued chemicals.

Enhanced understanding of the relationship between chemical modification and mechanical properties of wood

Science.gov (United States)

Charles R. Frihart; Daniel J. Yelle; John Ralph; Robert J. Moon; Donald S. Stone; Joseph E. Jakes

2008-01-01

Chemical additions to wood often change its bulk properties, which can be determined using conventional macroscopic mechanical tests. However, the controlling interactions between chemicals and wood take place at and below the scale of individual cells and cell walls. To better understand the effects of chemical additions to wood, we have adapted and extended two...

Electrodialytic remediation of CCA treated waste wood in pilot scale

DEFF Research Database (Denmark)

Pedersen, Anne Juul; Christensen, Iben Vernegren; Ottosen, Lisbeth M.

2005-01-01

study the utility of the method Electrodialytic Remediation was demonstrated for handling of CCA treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low level DC current as the cleaning agent, combines elektrokinetic movement of ions in the wood matrix with the princi......-ples of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA treated wood using electrodialytic remediation in laboratory scale (Ribeiro et al., 2000; Kristensen et al., 2003), but until now, the method had not been studied in larger scale. The pilot scale plant used...... in this study was designed to contain up to 2 m3 wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to fi-nally 150 cm. The remediation time was varied between 11 and 21 days...

Limited oxygen index levels of impregnated Scots pine wood

International Nuclear Information System (INIS)

Tomak, Eylem Dizman; Cavdar, Ayfer Donmez

2013-01-01

Highlights: • Scots pine samples were treated with 4 wood preservatives with various concentrations. • Limited oxygen index level was evaluated both for leached and un-leached samples. • All treatments improved fire retardance of samples despite some chemicals leached out. • Samples treated with fireproof agent showed the best results. • LOI of samples treated with boron powder and silicon oil was not changed by leaching. - Abstract: In this study, effect of various concentrations of boron powder, mixture of boric acid and borax, fireproof agent based on liquid blend of limestone, and silicon oil on limited oxygen index levels (LOI) of S. pine wood was investigated. Wood samples were first vacuum treated with the preservatives, and then were subjected to leaching procedure. Samples treated with fireproof agent showed the best results for improving the fire retardancy of wood, furthermore, samples treated with 25%, 50% and 100% of the solution did not burn. Leaching did not considerably change the LOI of wood samples treated with boron powder and silicon oil; however, LOI levels of samples treated with the mixture of boric acid and borax and fireproof agent were affected by leaching procedure probably arising those preservatives did not chemically bond to main wood components. All treatments improved fire retardancy of samples despite some amount of preservatives leached out from wood

Limited oxygen index levels of impregnated Scots pine wood

Energy Technology Data Exchange (ETDEWEB)

Tomak, Eylem Dizman, E-mail: eylemdizman@yahoo.com [Forest Industry Engineering Department, Faculty of Forestry, Bursa Technical University, 16200 Bursa (Turkey); Cavdar, Ayfer Donmez [Interior Architecture Department, Faculty of Architecture, Karadeniz Technical University, 61080 Trabzon (Turkey)

2013-12-10

Highlights: • Scots pine samples were treated with 4 wood preservatives with various concentrations. • Limited oxygen index level was evaluated both for leached and un-leached samples. • All treatments improved fire retardance of samples despite some chemicals leached out. • Samples treated with fireproof agent showed the best results. • LOI of samples treated with boron powder and silicon oil was not changed by leaching. - Abstract: In this study, effect of various concentrations of boron powder, mixture of boric acid and borax, fireproof agent based on liquid blend of limestone, and silicon oil on limited oxygen index levels (LOI) of S. pine wood was investigated. Wood samples were first vacuum treated with the preservatives, and then were subjected to leaching procedure. Samples treated with fireproof agent showed the best results for improving the fire retardancy of wood, furthermore, samples treated with 25%, 50% and 100% of the solution did not burn. Leaching did not considerably change the LOI of wood samples treated with boron powder and silicon oil; however, LOI levels of samples treated with the mixture of boric acid and borax and fireproof agent were affected by leaching procedure probably arising those preservatives did not chemically bond to main wood components. All treatments improved fire retardancy of samples despite some amount of preservatives leached out from wood.

Effects of Heat-Treated Wood Particles on the Physico-Mechanical Properties and Extended Creep Behavior of Wood/Recycled-HDPE Composites Using the Time–Temperature Superposition Principle

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Teng-Chun Yang

2017-03-01

Full Text Available This study investigated the effectiveness of heat-treated wood particles for improving the physico-mechanical properties and creep performance of wood/recycled-HDPE composites. The results reveal that the composites with heat-treated wood particles had significantly decreased moisture content, water absorption, and thickness swelling, while no improvements of the flexural properties or the wood screw holding strength were observed, except for the internal bond strength. Additionally, creep tests were conducted at a series of elevated temperatures using the time–temperature superposition principle (TTSP, and the TTSP-predicted creep compliance curves fit well with the experimental data. The creep resistance values of composites with heat-treated wood particles were greater than those having untreated wood particles due to the hydrophobic character of the treated wood particles and improved interfacial compatibility between the wood particles and polymer matrix. At a reference temperature of 20 °C, the improvement of creep resistance (ICR of composites with heat-treated wood particles reached approximately 30% over a 30-year period, and it increased significantly with increasing reference temperature.

Effects of Heat-Treated Wood Particles on the Physico-Mechanical Properties and Extended Creep Behavior of Wood/Recycled-HDPE Composites Using the Time–Temperature Superposition Principle

Science.gov (United States)

Yang, Teng-Chun; Chien, Yi-Chi; Wu, Tung-Lin; Hung, Ke-Chang; Wu, Jyh-Horng

2017-01-01

This study investigated the effectiveness of heat-treated wood particles for improving the physico-mechanical properties and creep performance of wood/recycled-HDPE composites. The results reveal that the composites with heat-treated wood particles had significantly decreased moisture content, water absorption, and thickness swelling, while no improvements of the flexural properties or the wood screw holding strength were observed, except for the internal bond strength. Additionally, creep tests were conducted at a series of elevated temperatures using the time–temperature superposition principle (TTSP), and the TTSP-predicted creep compliance curves fit well with the experimental data. The creep resistance values of composites with heat-treated wood particles were greater than those having untreated wood particles due to the hydrophobic character of the treated wood particles and improved interfacial compatibility between the wood particles and polymer matrix. At a reference temperature of 20 °C, the improvement of creep resistance (ICR) of composites with heat-treated wood particles reached approximately 30% over a 30-year period, and it increased significantly with increasing reference temperature. PMID:28772726

Role of construction debris in release of copper, chromium, and arsenic from treated wood structures

Science.gov (United States)

Stan T. Lebow; Steven A. Halverson; Jeffrey J. Morrell; John. Simonsen

Recent research on the release of wood preservatives from treated wood used in sensitive environments has not considered the potential contribution from construction residues. This study sought to develop leaching rate data for small construction debris and compare those to the release rate from treated wood itself. Western hemlock boards were pressure treated with...

Exposure testing of fasteners in preservative treated wood : gravimetric corrosion rates and corrosion product analyses

Science.gov (United States)

Samuel L. Zelinka; Rebecca J. Sichel; Donald S. Stone

2010-01-01

Research was conducted to determine the corrosion rates of metals in preservative treated wood and also understand the mechanism of metal corrosion in treated wood. Steel and hot-dip galvanized steel fasteners were embedded in wood treated with one of six preservative treatments and exposed to 27oC at 100% relative humidity for 1 year. The...

Pretreatments for converting wood into paper and chemicals

Science.gov (United States)

William R. Kenealy; Carl J. Houtman; Jose Laplaza; Thomas W. Jeffries; Eric G. Horn

2007-01-01

Biorefining wood into paper and chemicals is not as easy as making a single traditional paper product. Paper is made from the cellulose- containing fractions of wood and processing may remove lignin and hemicellulose components. The yield and composition of the product depend upon the type of paper being produced. The paper process often alters the noncellulose...

Resistance of treated rubber wood ( Hevea brasiliensis ) to termite ...

African Journals Online (AJOL)

Spent rubber trees from a 25 year old plantation were cut, sawn and treated with Copper Chromium Arsenate (CCA) and Cashew Nut Shell Liquid (CNSL). Two sets of wood samples were treated with CCA and CNSL respectively while the third set was not treated to serve as control. The three sets were exposed to termite ...

Physical and mechanical properties of flakeboard produced from recycled CCA-treated wood

Science.gov (United States)

W. Li; T.F. Shupe; Chung-Yun Hse

2004-01-01

Chromated copper arsenate (CCA) treated wood has been most widely used in North America since the 1970s for many exterior applications such as decks, fences, playground equipment, utility poles, and others. A large volume of CCA-treated wood is currently coming out of service. Traditional disposal methods such as landfilling and incineration are not without adverse...

Mechanical and natural durability properties of wood treated with a novel organic preservative/consolidant product

International Nuclear Information System (INIS)

Lionetto, Francesca; Frigione, Mariaenrica

2009-01-01

An organic preservative/consolidant of new formulation was selected in order to evaluate its effect on the mechanical properties of worm-eaten walnut wood. Walnut wood is widely used for the realization of artistic handworks (e.g. statues, altars, etc.) furniture and flooring. The flexural strength and modulus of elasticity, the toughness and the hardness were determined on both treated and untreated samples. The experimental results showed that the product increased significantly the flexural strength while the other mechanical properties were not appreciably affected by the chemical treatment. The microstructure of the samples tested was observed using scanning electron microscopy. The preserving character against insects of the investigated product was assessed by both visual inspection and measurements of weight loss on the treated specimens after their exposure to living insects. The samples on which the product was applied, exposed to Oligomerus ptilinoides for one year, were more resistant to decay than the corresponding untreated samples.

Investigation of the Acoustic Properties of Chemically Impregnated Kayu Malam Wood Used for Musical Instrument

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Md. Faruk Hossen

2018-01-01

Full Text Available The chemical modification or impregnation through preparing the wood polymer composites (WPCs can effectively reduce the hygroscopicity as well as can improve the acoustic properties of wood. On the other hand, a small amount of nanoclay into the chemical mixture can further improve the different properties of the WPCs through the preparation of wood polymer nanocomposites (WPNCs. Kayu Malam wood species with styrene (St, vinyl acetate (VA, and montmorillonite (MMT nanoclay were used for the preparation of WPNCs. The acoustic properties such as specific dynamic Young’s modulus (Ed/γ, internal friction (Q−1, and acoustic conversion efficiency (ACE of wood were examined using free-free flexural vibration. It was observed that the chemically impregnated wood composite showed a higher value of Ed/γ than raw wood and the nanoclay-loaded wood nanocomposite showed the highest value. The reverse trend was observed in the case of Q−1. On the other hand, chemical impregnation has a minor effect on ACE of wood for musical instruments. The results suggested that the chemically impregnated Kayu Malam wood polymer nanocomposite (WPNC is suitable for making soundboards of violin and guitar instruments to be played longer without losing tone quality.

Electrochemical removal of CU, CR and AS from CCA-treated waste wood

Energy Technology Data Exchange (ETDEWEB)

Kristensen, I.V.; Ottosen, L.M.; Villumsen, A. [Dept. of Geology and Geotechnical Engineering, The Technical Univ. of Denmark, Lyngby (Denmark); Ribeiro, A.B. [Dept. of Geology and Geotechnical Engineering, The Technical Univ. of Denmark, Lyngby (Denmark)]|[Dept. de Ciencias e Engenharia do Ambiente, Faculdade de Ciencias e Tecnologia, Univ. Nova de Lisboa, Caparica (Portugal)

2001-07-01

CCA-treated waste wood poses a potential environmental problem due to the content of copper, chromium and arsenic. This paper presents the results obtained by electrodialytic remediation of CCA-treated waste wood. It is found that more than 90% Cu, and approximately 85% Cr and As was removed from the wood during the remediation. Thereby the concentration of copper in the wood is reduced from app. 426 ppm to app. 25 ppm, chromium is reduced from app. 837 ppm to app. 135 ppm and the arsenic content decreases from app. 589 ppm to app. 151 ppm. After remediation the removed metals are collected into liquids. The use of ion exchange membranes to separate the wood from the electrolytes result in a distribution of the metals after remediation that makes the collection of the metals easier, and reuse of the metals, for e.g. new CCA, may be possible. (orig.)

76 FR 13616 - Picayune Wood Treating Site Picayune, Pearl River County, MS; Notice of Settlement

Science.gov (United States)

2011-03-14

... ENVIRONMENTAL PROTECTION AGENCY [Docket EPA-RO4-SFUND-2011-0201, FRL-9280-3] Picayune Wood... entered into a settlement for reimbursement of past response costs concerning the Picayune Wood Treating... No. EPA-RO4- SFUND-2011-0201 or Site name Picayune Wood Treating Superfund Site by one of the...

Roughness study on homogeneous layer panels manufactured from treated wood waste

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Maria Fátima do Nascimento

2017-02-01

Full Text Available Natural resource exploration is growing, highlighting woods and joinery waste, wood industries and the like. This study presents homogeneous particleboard (PPH roughness characterization manufactured from treated wood waste. Normative document with values of Brazilian Technical Standard Association ABNT NBR 8404 (1984, was adopted as a reference. The results show that the manufactured PPH showed roughness class N 10, with roughness values (Ra of less than 12.5 microns.

A General Evaluation for Recycling Process of Impregnated Wood Removed From the Service

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Cihat Taşçıoğlu

2011-03-01

Full Text Available Wood presevatives such as creosote, pentaclorophenol (PCP and chromated copper arsenate (CCA have been widely used over the years in order to extend wood products’ service life. CCA was known as most widely used wood preservative chemical in residendial and commercial applications world wide until 2004 volanteered phase out of the chemical from residential use bye the major manufacturers. Over the years CCA treated wood acuumulated in service reaching millions of cubic meters. But there is growing concern about the environmental impacts and increasing difficulty in disposing of treated wood products in many countries. Since disposal of CCA treated wood material poses greater problems than the other treated wood products due to heavy and toxic metal componets of CCA such as chromium and arsenic Traditional disposal methods like landfillig or incineration, both have negative environmental consequences. For that reason the increasing volume of CCA-treated wood products coming out of service requires alternative disposal methods and recycling techniques never tried before. The main purpose of this study, except for traditional methods like landfilling and incineration, is to evaluate the current alternative disposal and recycling methods for CCA treated wood removed from service.

Corrosion of metals in treated wood examined by synchrotron based xanes and XFM

Science.gov (United States)

Samuel L. Zelinka; Joseph E. Jakes; Grant T. Kirker; Leandro Passarini; Barry Lai

2016-01-01

Copper based waterborne wood preservatives are frequently used to extend the service life of wood products used in outdoor environments. While these copper based treatments protect the wood from fungal decay and insect attack, they increase the corrosion of metals embedded or in contact with the treated wood. Over the past ten years, several studies have looked at the...

Pine Wood Treated with a Citric Acid and Glycerol Mixture: Biomaterial Performance Improved by a Bio-byproduct

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Gatien Geraud Essoua Essoua

2016-02-01

Full Text Available Wood material is a good reservoir for biogenic carbon storage. The use of wood material for outdoor products such as siding in the building construction sector presents limits. These limits are bound to the nature of wood material (hygroscopic property and anatomical structure. They are responsible for the dimensional variation associated with moisture content variations. Fungal attacks and coating layers adhesion on wood surface, are other problems. This research investigated the feasibility of impregnation with environmentally friendly chemicals, i.e., a citric acid-glycerol mixture (CA-G. The anti-swelling efficiency (ASE, hardness, biodegradation, and coating adhesion tests were performed on softwood specimens. ASE results were up to 53%. The equilibrium moisture content of the treated specimens was less than half of the untreated ones. FTIR spectroscopy showed bands at 1720 to 1750 cm-1, indicating the presence of ester bonds, and scanning electron microscopy images confirmed the polymerization and condensation of treatment solution inside the wood structure. Hardness and decay resistance were increased; however, treatment reduces coating adhesion. In conclusion, CA-G represents a promising eco-responsible solution for improving the technical performance of outdoor wood products.

Wood anatomical and chemical properties related to the pulpability ...

African Journals Online (AJOL)

Eucalyptus globulus is one of the most important hardwood species used by the pulp and paper industry due to its high pulp yield, high wood density, excellent fibre quality and good handsheet properties. However, the wood is a highly variable and complex material that has different chemical, physical and anatomical ...

Wood Chemical Composition in Species of Cactaceae: The Relationship between Lignification and Stem Morphology

Science.gov (United States)

Canché-Escamilla, Gonzalo; Soto-Hernández, Marcos

2015-01-01

In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs) and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content) in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous) with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35%) of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level. PMID:25880223

Wood chemical composition in species of Cactaceae: the relationship between lignification and stem morphology.

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Jorge Reyes-Rivera

Full Text Available In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35% of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level.

Wood chemical composition in species of Cactaceae: the relationship between lignification and stem morphology.

Science.gov (United States)

Reyes-Rivera, Jorge; Canché-Escamilla, Gonzalo; Soto-Hernández, Marcos; Terrazas, Teresa

2015-01-01

In Cactaceae, wood anatomy is related to stem morphology in terms of the conferred support. In species of cacti with dimorphic wood, a unique process occurs in which the cambium stops producing wide-band tracheids (WBTs) and produces fibers; this is associated with the aging of individuals and increases in size. Stem support and lignification have only been studied in fibrous tree-like species, and studies in species with WBTs or dimorphic wood are lacking. In this study, we approach this process with a chemical focus, emphasizing the role of wood lignification. We hypothesized that the degree of wood lignification in Cactaceae increases with height of the species and that its chemical composition varies with wood anatomy. To test this, we studied the chemical composition (cellulose, hemicellulose, and lignin content) in 13 species (2 WBTs wood, 3 dimorphic, and 8 fibrous) with contrasting growth forms. We also analyzed lignification in dimorphic and fibrous species to determine the chemical features of WBTs and fibers and their relationship with stem support. The lignin contents were characterized by Fourier transform infrared spectroscopy and high performance liquid chromatography. We found that 11 species have a higher percentage (>35%) of lignin in their wood than other angiosperms or gymnosperms. The lignin chemical composition in fibrous species is similar to that of other dicots, but it is markedly heterogeneous in non-fibrous species where WBTs are abundant. The lignification in WBTs is associated with the resistance to high water pressure within cells rather than the contribution to mechanical support. Dimorphic wood species are usually richer in syringyl lignin, and tree-like species with lignified rays have more guaiacyl lignin. The results suggest that wood anatomy and lignin distribution play an important role in the chemical composition of wood, and further research is needed at the cellular level.

Landfill disposal of CCA-treated wood with construction and demolition (C&D) debris: arsenic, chromium, and copper concentrations in leachate.

Science.gov (United States)

Jambeck, Jenna R; Townsend, Timothy G; Solo-Gabriele, Helena M

2008-08-01

Although phased out of many residential uses in the United States, the disposal of CCA-treated wood remains a concern because significant quantities have yet to be taken out of service, and it is commonly disposed in landfills. Catastrophic events have also led to the concentrated disposal of CCA-treated wood, often in unlined landfills. The goal of this research was to simulate the complex chemical and biological activity of a construction and demolition (C&D) debris landfill containing a realistic quantity of CCA-treated wood (10% by mass), produce leachate, and then evaluate the arsenic, copper, and chromium concentrations in the leachate as an indication of what may occur in a landfill setting. Copper concentrations were not significantly elevated in the control or experimental simulated landfill setting (alpha = 0.05). However, the concentrations of arsenic and chromium were significantly higher in the experimental simulated landfill leachate compared to the control simulated landfill leachate (alpha = 0.05, p debris can impact leachate quality which, in turn could affect leachate management practices or aquifers below unlined landfills.

Chemical investigation on wood tree species in a temperate forest, east-northern Romania

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Teaca, C. A.

2007-02-01

Full Text Available A quantitative evaluation of wood chemical components for some tree species in a forest area from east-northern Romania is presented here, through a comparative study from 1964 to 2000. Investigation upon the wood tree-rings in a Quercus robur L. tree species, as a dominant species, as regards its chemical composition and structure of the natural polymer constituents - cellulose and lignin - was also performed through chemical methods to separate the main wood components, FT-IR spectroscopy, and thermogravimetry. Having in view the impact of climate and external factors (such as pollutant depositions, some possible correlations between wood chemical composition and its further use can be made. The FT-IR spectra give evidence of differences in the frequency domains of 3400-2900 cm-1 and 1730-1640 cm-1, due to some interactions between the chemical groups (OH, C=O. The crystallinity index of cellulose presents variations in the oak wood tree-rings. Thermogravimetry analyses show different behaviour of cellulose at thermal decomposition, as a function of radial growth and tree’s height. A preliminary chemical investigation of oak wood sawdust shows a relatively high content of mineral elements (ash, compared with a previous study performed in 1964, fact that may indicate an intense drying process of the oak tree, a general phenomenon present in European forests for this species.

Effect of Different Heat Treatment Temperatures on the Chemical Composition and Structure of Chinese Fir Wood

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Shichao Cheng

2016-03-01

Full Text Available The properties of wood can be improved after heat-treatment. There have been many studies dealing with mechanical properties and chemical modifications of heat-treated wood. The purpose of this paper is to provide a new analysis method, to give better insights on the hemicelluloses, cellulose, and lignin contents of heat-treated wood by using Fourier transform infrared (FT-IR and two-dimensional infrared (2D-IR spectroscopies. The FT-IR spectra results showed progressive degradation in the carbonyl groups of the glucuronic acid units and degradation of the pyranose of hemicelluloses. These changes were measured as the percentage decrease of crystalline cellulose and the loss of C=O and C=C groups linking together the aromatic skeleton of lignin. The 2D-IR spectra showed the appearance of 5 × 5 peak clusters in the 1000 to 1200 cm-1 region, which could account for the hemicellulose degradation. In addition, changes in the degree of sensitivity at 1627 and 1509 cm-1 coincided with cross-linking reactions among the aromatic units in the lignin molecules.

Effects of Treated Wood Flour on Physico-Mechanical Properties of ...

African Journals Online (AJOL)

Wood flour was crushed in to particle size and given two surface treatments each with alkali and 3-chloro-2 hydroxylpropyltrimethylammoniumchloride. The raw, alkali-treated and bonding agent treated fibers were used as natural rubber composites. The samples were used to produce fiber-reinforced natural rubber ...

CCA retention and its effects on the bonding performance of decommissioned treated wood: a preliminary study

Science.gov (United States)

Cheng Piao; Todd F. Shupe; Mark Gibson; Chung Y. Hse

2009-01-01

Chromated copper arsenate (CCA) continues to be widely used as a wood preservative for industrial uses in the U.S. Disposal of treated wood is a potential long-term environmental liability. Current practices for disposing of decommissioned preservative-treated wood include landfilling and incineration, which are increasingly impractical due to environmental...

CHARACTERIZATION OF EMISSIONS OF THERMALLY MODIFIED WOOD AND THEIR REDUCTION BY CHEMICAL TREATMENT

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Jana Peters

2008-05-01

Full Text Available Thermal treatment is a suitable method for improving the quality of wood types like spruce, beech or poplar, and thus to open up new fields of application that used to be limited to tropical woods or woods treated with timber preservatives. These thermally treated woods are characterized by a typical odor caused by degradation products of miscellaneous wood components. The characterization and removal of those odorous substances were investigated using chromatographic and spectroscopic methods. Headspace gas chromatography (GC in combination with solid-phase microextraction (SPME was used for a qualitative analysis of volatile wood emissions, and the detectable volatiles were compared before and after solvent extraction. Wood solvent extractives were investigated by means of gas chromatography/mass spectrometry and then evaluated in terms of changes in composition caused by the thermal treatment process.

Comparative study on liquefaction of creosote and chromated copper arsenate (CCA)-treated wood and untreated southern pine wood: effects of acid catalyst content, liquefaction time, temperature, and phenol to wood ratio

Science.gov (United States)

Hui Pan; Chung-Yun Hse; Todd F. Shupe

2009-01-01

Creosote- and chromated copper arsenate (CCA)-treated wood waste and untreated southern pine wood were liquefied with phenol and sulfuric acid. The effects of sulfuric acid content, liquefaction time, liquefaction temperature, and phenol to wood ratio on liquefaction rate (i.e., wood residue content) were investigated and analyzed by analysis of variance (...

Leaching of CCA-treated wood: implications for waste disposal

International Nuclear Information System (INIS)

Townsend, Timothy; Tolaymat, Thabet; Solo-Gabriele, Helena; Dubey, Brajesh; Stook, Kristin; Wadanambi, Lakmini

2004-01-01

Leaching of arsenic, chromium, and copper from chromated copper arsenate (CCA)-treated wood poses possible environmental risk when disposed. Samples of un-weathered CCA-treated wood were tested using a variety of the US regulatory leaching procedures, including the toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), extraction procedure toxicity method (EPTOX), waste extraction test (WET), multiple extraction procedure (MEP), and modifications of these procedures which utilized actual MSW landfill leachates, a construction and demolition (C and D) debris leachate, and a concrete enhanced leachate. Additional experiments were conducted to assess factors affecting leaching, such as particle size, pH, and leaching contact time. Results from the regulatory leaching tests provided similar results with the exception of the WET, which extracted greater quantities of metals. Experiments conducted using actual MSW leachate, C and D debris leachate, and concrete enhanced leachate provided results that were within the same order of magnitude as results obtained from TCLP, SPLP, and EPTOX. Eleven of 13 samples of CCA-treated dimensional lumber exceeded the US EPA's toxicity characteristic (TC) threshold for arsenic (5 mg/L). If un-weathered arsenic-treated wood were not otherwise excluded from the definition of hazardous waste, it frequently would require management as such. When extracted with simulated rainwater (SPLP), 9 of the 13 samples leached arsenic at concentrations above 5 mg/L. Metal leachability tended to increase with decreasing particle size and at pH extremes. All three metals leached above the drinking water standards thus possibly posing a potential risk to groundwater. Arsenic is a major concern from a disposal point of view with respect to ground water quality

Hot water extracted wood fiber for production of wood plastic composites (WPCs)

Science.gov (United States)

Manuel Raul Pelaez-Samaniego; Vikram Yadama; Eini Lowell; Thomas E. Amidon; Timothy L. Chaffee

2013-01-01

Undebarked ponderosa pine chips were treated by hot water extraction to modify the chemical composition. In the treated pine (TP) , the mass was reduced by approximately 20%, and the extract was composed mainly of degradation products of hemicelluloses. Wood flour produced from TP and unextracted chips (untreated pine, UP) was blended with high-density polyethylene (...

Fractionation of heavy metals in liquefied chromated copper arsenate (CCA)-treated wood sludge using a modified BCR-sequential extraction procedure

Science.gov (United States)

Hui Pan; Chung-Yun Hse; Robert Gambrell; Todd F. Shupe

2009-01-01

Chromated copper arsenate (CCA)-treated wood was liquefied with polyethylene glycol/glycerin and sulfuric acid. After liquefaction, most CCA metals (98% As, 92% Cr, and 83% Cu) were removed from liquefied CCA-treated wood by precipitation with calcium hydroxide. The original CCA-treated wood and liquefied CCA-treated wood sludge were fractionated by a modified...

Leachability of boron from wood treated with natural and semi-synthetic polymers and calcium precipitating agent

Science.gov (United States)

S. N. Kartal; F. Green

2003-01-01

Several fixation systems to limit or decrease boron leachability from treated wood have been developed. Some attempts have relied on limiting of water penetration of treated wood using water repellents, monomer and polymer systems. On the other hand, non-toxic polymers such as proteins were tried to reduce amount of boron leached from wood (Thevenon et al. 1997, 1998...

Nondestructive chemical imaging of wood at the micro-scale: advanced technology to complement macro-scale evaluations

Science.gov (United States)

Barbara L. Illman; Julia Sedlmair; Miriam Unger; Carol Hirschmugl

2013-01-01

Chemical images help understanding of wood properties, durability, and cell wall deconstruction for conversion of lignocellulose to biofuels, nanocellulose and other value added chemicals in forest biorefineries. We describe here a new method for nondestructive chemical imaging of wood and wood-based materials at the micro-scale to complement macro-scale methods based...

Long-term soil accumulation of chromium, copper, and arsenic adjacent to preservative-treated wood.

Science.gov (United States)

S. Lebow; D. Foster; J. Evans

2004-01-01

Chromated copper arsenate (CCA) treated wood has been used extensively in outdoor applications. The Environmental Protection Agency (EPA) and CCA producers recently reached an agreement to limit future use of CCA for some types of applications. One area of concern is the long-term accumulation of leached CCA in soil adjacent to treated wood structures. Interpreting...

Exposure testing of fasteners in preservative treated wood: Gravimetric corrosion rates and corrosion product analyses

Energy Technology Data Exchange (ETDEWEB)

Zelinka, Samuel L., E-mail: szelinka@fs.fed.u [USDA Forest Products Laboratory, One Gifford Pinchot Drive, Madison, WI 53726 (United States); Sichel, Rebecca J. [College of Engineering, University of Wisconsin, Madison, WI 53706 (United States); Stone, Donald S. [Department of Materials Science and Engineering, College of Engineering, University of Wisconsin, Madison, WI 53706 (United States)

2010-12-15

Research highlights: {yields} The composition of the corrosion products was similar for the nail head and shank. {yields} Reduced copper was not detected on any of the fasteners. {yields} Measured corrosion rates were between 1 and 35 {mu}m year{sup -1}. - Abstract: Research was conducted to determine the corrosion rates of metals in preservative treated wood and also understand the mechanism of metal corrosion in treated wood. Steel and hot-dip galvanized steel fasteners were embedded in wood treated with one of six preservative treatments and exposed to 27 {sup o}C at 100% relative humidity for 1 year. The corrosion rate was determined gravimetrically and the corrosion products were analyzed with scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. Although the accepted mechanism of corrosion in treated wood involves the reduction of cupric ions from the wood preservative, no reduced copper was found on the corrosion surfaces. The galvanized corrosion products contained sulfates, whereas the steel corrosion products consisted of iron oxides and hydroxides. The possible implications and limitations of this research on fasteners used in building applications are discussed.

ASSESSING CHILDREN'S EXPOSURES TO THE WOOD PRESERVATIVE CCA (CHROMATED COPPER ARSENATE) ON TREATED PLAYSETS AND DECKS

Science.gov (United States)

Concerns have been raised regarding the safety of young children contacting arsenic and chromium residues while playing on and around Chromated Copper Arsenate (CCA) treated wood playground structures and decks. Although CCA registrants voluntarily canceled treated wood for re...

Chapter 14: Evaluating the Leaching of Biocides from Preservative-Treated Wood Products

Science.gov (United States)

Stan T. Lebow

2014-01-01

Leaching of biocides is an important consideration in the long term durability and any potential for environmental impact of treated wood products. This chapter discusses factors affecting biocide leaching, as well as methods of evaluating rate and quantity of biocide released. The extent of leaching is a function of preservative formulation, treatment methods, wood...

Guide for minimizing the effect of preservative-treated wood on sensitive environments

Science.gov (United States)

Stan T. Lebow; Michael Tippie

2001-01-01

Preservative-treated wood is often used for construction of highway and foot bridges, wetland boardwalks, and other structures in or over water or sensitive environments. In these applications it is important that release of preservative from the wood into the environment is minimized. This publication addresses this concern by describing the various types of pressure-...

Metal loss from treated wood products in contact with municipal solid waste landfill leachate

Energy Technology Data Exchange (ETDEWEB)

Dubey, Brajesh [Department of Environmental Health, PO Box 70682, East Tennessee State University, Johnson City, TN 37614 (United States); Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL 32611-6450 (United States); Townsend, Timothy, E-mail: ttown@ufl.edu [Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL 32611-6450 (United States); Solo-Gabriele, Helena [Department of Civil, Architectural and Environmental Engineering, University of Miami, Coral Gables, FL 33124-0630 (United States)

2010-03-15

The research presented in this paper evaluates the potential impact of municipal solid waste (MSW) landfill leachate quality on the loss of metals from discarded treated wood during disposal. The loss of arsenic (As), chromium (Cr), copper (Cu), and boron (B) from several types of pressure-treated wood (CCA: chromated copper arsenate, ACQ: alkaline copper quaternary, CBA: copper boron azole, and DOT: disodium octaborate tetrahydrate) using leachate collected from 26 MSW landfills in Florida was examined. The toxicity characteristic leaching procedure (TCLP), the synthetic precipitation leaching procedure (SPLP), and California's waste extraction test (WET) were also performed. The results suggested that loss of preservative components was influenced by leachate chemistry. Copper loss from CCA-, ACQ- and CBA-treated wood was similar in magnitude when in contact with landfill leachates compared to synthetic TCLP and SPLP solutions. Ammonia was found as one of the major parameters influencing the leaching of Cu from treated wood when leached with MSW landfill leachates. The results suggest that disposal of ACQ- and CBA-treated wood in substantial quantity in MSW landfills may elevate the Cu concentration in the leachate; this could be of potential concern, especially for a bioreactor MSW landfill in which relatively higher ammonia concentrations in leachate have been reported in recent literature. For the As, Cr and B the concentrations observed with the landfill leachate as the leaching solutions were over a range from some sample showing the concentrations below and some showing above the observed value from corresponding SPLP and TCLP tests. In general the WET test showed the highest concentrations.

Subterranean Termite Resistance of Polystyrene-Treated Wood from Three Tropical Wood Species

Directory of Open Access Journals (Sweden)

Yusuf Sudo Hadi

2016-07-01

Full Text Available The objective of this work was to investigate the resistance of three Indonesian wood species to termite attack. Samples from sengon (Falcataria moluccana, mangium (Acacia mangium, and pine (Pinus merkusii were treated with polystyrene at loading levels of 26.0%, 8.6%, and 7.7%, respectively. Treated and untreated samples were exposed to environmental conditions in the field for 3 months. Untreated specimens of sengon, mangium, and pine had resistance ratings of 3.0, 4.6, and 2.4, respectively, based on a 10-point scale from 0 (no resistance to 10 (complete or near-complete resistance. Corresponding resistance values of 7.8, 7.2, and 8.2 were determined for specimens treated with polystyrene. Overall weight loss values of 50.3%, 23.3%, and 66.4% were found for untreated sengon, mangium, and pine samples, respectively; for treated samples, the values were 7.6%, 14.4%, and 5.1%, respectively. Based on the findings in this study, overall resistance to termite attack was higher for treated samples compared to untreated samples.

Accelerated weathering of fire-retardant-treated wood for fire testing

Science.gov (United States)

Robert H. White

2009-01-01

Fire-retardant-treated products for exterior applications must be subjected to actual or accelerated weathering prior to fire testing. For fire-retardant-treated wood, the two accelerated weathering methods have been Method A and B of ASTM D 2898. The rain test is Method A of ASTM D 2898. Method B includes exposures to ultraviolet (UV) sunlamps in addition to water...

A non-destructive approach for assessing decay in preservative treated wood

NARCIS (Netherlands)

Machek, L.; Edlund, M.L.; Sierra-Alvarez, R.; Militz, H.

2004-01-01

This study investigated the suitability of the non-destructive vibration-impulse excitation technique to assess the attack of preservative-treated wood in contact with the ground. Small stakes (10×5×100 mm3) of treated and untreated Scots pine sapwood were exposed to decay in laboratory-scale

Arsenic, chromium, and copper leaching from CCA-treated wood and their potential impacts on landfill leachate in a tropical country.

Science.gov (United States)

Kamchanawong, S; Veerakajohnsak, C

2010-04-01

This study looks into the potential risks of arsenic, chromium, and copper leaching from disposed hardwoods treated with chromated copper arsenate (CCA) in a tropical climate. The Toxicity Characteristic Leaching Procedure (TCLP) and the Waste Extraction Test (WET) were employed to examine new CCA-treated Burseraceae and Keruing woods, weathered CCA-treated teak wood, and ash from new CCA-treated Burseraceae wood. In addition, a total of six lysimeters, measuring 2 m high and 203 mm in diameter were prepared to compare the leachate generated from the wood monofills, construction and demolition (C&D) debris landfills and municipal solid waste (MSW) landfills, containing CCA-treated Burseraceae wood. The TCLP and WET results showed that the CCA-treated Burseraceae wood leached higher metal concentrations (i.e. 9.19-17.70 mg/L, 1.14-5.89 mg/L and 4.83-23.89 mg/L for arsenic, chromium, and copper, respectively) than the CCA-treated Keruing wood (i.e. 1.74-11.34 mg/L, 0.26-3.57 mg/L and 0.82-13.64 mg/L for arsenic, chromium and copper, respectively). Ash from the CCA-treated Burseraceae wood leached significantly higher metal concentrations (i.e. 108.5-116.9 mg/L, 1522-3862 mg/L and 84.03-114.4 mg/L for arsenic, chromium and copper, respectively), making this type of ash of high concern. The lysimeter study results showed that the MSW lysimeter exhibited higher reducing conditions, more biological activities and more dissolved ions in their leachates than the wood monofill and C&D debris lysimeters. All leachates generated from the lysimeters containing the CCA-treated Burseraceae wood contained significantly higher concentrations of arsenic in comparison to those of the untreated wood: in the range of 0.53-15.7 mg/L. It can be concluded that the disposal of CCA-treated Burseraceae wood in an unlined C&D landfill or a MSW landfill has the potential to contaminate groundwater.

CCA-treated wood disposed in landfills and life-cycle trade-offs with waste-to-energy and MSW landfill disposal.

Science.gov (United States)

Jambeck, Jenna; Weitz, Keith; Solo-Gabriele, Helena; Townsend, Timothy; Thorneloe, Susan

2007-01-01

Chromated copper arsenate (CCA)-treated wood is a preservative treated wood construction product that grew in use in the 1970s for both residential and industrial applications. Although some countries have banned the use of the product for some applications, others have not, and the product continues to enter the waste stream from construction, demolition and remodeling projects. CCA-treated wood as a solid waste is managed in various ways throughout the world. In the US, CCA-treated wood is disposed primarily within landfills; however some of the wood is combusted in waste-to-energy (WTE) facilities. In other countries, the predominant disposal option for wood, sometimes including CCA-treated wood, is combustion for the production of energy. This paper presents an estimate of the quantity of CCA-treated wood entering the disposal stream in the US, as well as an examination of the trade-offs between landfilling and WTE combustion of CCA-treated wood through a life-cycle assessment and decision support tool (MSW DST). Based upon production statistics, the estimated life span and the phaseout of CCA-treated wood, recent disposal projections estimate the peak US disposal rate to occur in 2008, at 9.7 million m(3). CCA-treated wood, when disposed with construction and demolition (C&D) debris and municipal solid waste (MSW), has been found to increase arsenic and chromium concentrations in leachate. For this reason, and because MSW landfills are lined, MSW landfills have been recommended as a preferred disposal option over unlined C&D debris landfills. Between landfilling and WTE for the same mass of CCA-treated wood, WTE is more expensive (nearly twice the cost), but when operated in accordance with US Environmental Protection Agency (US EPA) regulations, it produces energy and does not emit fossil carbon emissions. If the wood is managed via WTE, less landfill area is required, which could be an influential trade-off in some countries. Although metals are concentrated

Mechanical and chemical properties of CCA-treated lumber removed from spent residential decks

Science.gov (United States)

Robert L. Smith; David Bailey; Philip A. Araman

2007-01-01

The amount of chromated copper arsenate (CCA)- treated wood being removed from spent residential decks is increasing at a tremendous rate. While most spent CCA-treated wood is being disposed in landfills, further useful and environmentally beneficial alternatives have to be met. If the volume of CCA-treated wood reaching landfills continues to rise, stricter disposal...

Changes in mechanical and chemical wood properties by electron beam irradiation

International Nuclear Information System (INIS)

Schnabel, Thomas; Huber, Hermann; Grünewald, Tilman A.; Petutschnigg, Alexander

2015-01-01

Highlights: • Changes in wood due to electron beam irradiations (EBI) were evaluated. • Wood components undergo different altering mechanisms due to the irradiation. • Chemical reactions in wood lead to better surface hardness of low irradiated wood. - Abstract: This study deals with the influence of various electron beam irradiation (EBI) dosages on the Brinell hardness of Norway spruce. The results of the hardness measurements and the FT-IR spectroscopic analysis show different effects of the EBI at dosages of 25, 50, 100 and 200 kGy. It was assumed that the lignin and carbohydrates undergo different altering mechanisms due to the EBI treatment. New cleavage products and condensation reactions of lignin and carbohydrates lead to better surface hardness of low irradiated wood samples. These results provide a useful basis for further investigations on the changes in wood chemistry and material properties due to electron beam irradiations

Changes in mechanical and chemical wood properties by electron beam irradiation

Energy Technology Data Exchange (ETDEWEB)

Schnabel, Thomas, E-mail: thomas.schnabel@fh-salzburg.ac.at [Salzburg University of Applied Sciences, Department of Forest Products Technology and Wood Constructions, Marktstraße 136a, 5431 Kuchl (Austria); Huber, Hermann [Salzburg University of Applied Sciences, Department of Forest Products Technology and Wood Constructions, Marktstraße 136a, 5431 Kuchl (Austria); Grünewald, Tilman A. [BOKU University of Natural Resources and Life Sciences, Institute of Physics and Materials Science, Peter Jordan Straße 82, 1190 Vienna (Austria); Petutschnigg, Alexander [Salzburg University of Applied Sciences, Department of Forest Products Technology and Wood Constructions, Marktstraße 136a, 5431 Kuchl (Austria); BOKU University of Natural Resources and Life Sciences, Konrad Lorenzstraße 24, 3430 Tulln (Austria)

2015-03-30

Highlights: • Changes in wood due to electron beam irradiations (EBI) were evaluated. • Wood components undergo different altering mechanisms due to the irradiation. • Chemical reactions in wood lead to better surface hardness of low irradiated wood. - Abstract: This study deals with the influence of various electron beam irradiation (EBI) dosages on the Brinell hardness of Norway spruce. The results of the hardness measurements and the FT-IR spectroscopic analysis show different effects of the EBI at dosages of 25, 50, 100 and 200 kGy. It was assumed that the lignin and carbohydrates undergo different altering mechanisms due to the EBI treatment. New cleavage products and condensation reactions of lignin and carbohydrates lead to better surface hardness of low irradiated wood samples. These results provide a useful basis for further investigations on the changes in wood chemistry and material properties due to electron beam irradiations.

Inventory of contaminants in waste wood; Inventering av foeroreningar i returtrae

Energy Technology Data Exchange (ETDEWEB)

Jermer, Joeran; Ekvall, Annika; Tullin, Claes [Swedish National Testing and Research Inst., Boraas (Sweden)

2001-03-01

Waste wood is increasingly used as fuel in Sweden. It is of Swedish origin as well as imported, mainly from Germany and the Netherlands. The waste wood is contaminated by e.g. paint and wood preservatives and objects of metal, glass, plastics etc. The contaminants may cause technical problems such as deposits and corrosion as well as plugging of air openings. The present study has focussed on potential contaminants in waste wood that could cause problems of technical as well as environmental nature. The major chemical contaminants are surface treatments (paints etc) and wood preservatives. The surface treatments contribute in particular to contaminants of zinc and lead. In some cases zinc has been found to cause severe deposits in the furnaces. Surface treatments also contribute to increased levels of sodium, chlorine, sulphur and nitrogen. Preservative-treated wood is the most important source of increased levels of copper, chromium and arsenic in the waste wood. Waste wood imported from Germany contains less arsenic but the same amount of copper and chromium as Swedish waste wood. The contents of mercury in German waste wood can be expected to be higher than in waste wood of Swedish origin. The fraction consisting of wood-based panels is comparably free from contaminants but as a result of the high contents of adhesives wood-based panels contribute to a higher proportion of nitrogen in waste wood than in forest residues. A great number of non-wood compounds (such as plastics and metals) do also contaminate waste wood. By careful and selective demolition and various sorting procedures most non-wood compounds will be separated from the waste wood. Waste sorting analyses carried out indicate that the waste wood contains approximately 1% non-wood compounds, mainly plastic and metal compounds, glass, dirt, concrete, bricks and gypsum. This may seem to be a small proportion, but if large amounts of waste wood are incinerated the non-wood compounds will inevitably cause

USE OF AMAZONIAN SPECIES FOR AGING DISTILLED BEVERAGES: PHYSICAL AND CHEMICAL WOOD ANALYSIS

Directory of Open Access Journals (Sweden)

Jonnys Paz Castro

2015-06-01

Full Text Available The process of storing liquor in wooden barrels is a practice that aims to improve the sensory characteristics, such as color, aroma and flavor, of the beverage. The quality of the liquor stored in these barrels depends on wood characteristics such as density, permeability, chemical composition, anatomy, besides the wood heat treatment used to fabricate the barrels. Brazil has a great diversity of forests, mainly in the north, in the Amazon. This region is home to thousands of tree species, but is limited to the use of only a few native species to store liquors. The objective of this study was to determine some of the physical and chemical characteristics for four Amazon wood species. The results obtained in this study will be compared with others from woods that are traditionally used for liquor storage. The species studied were angelim-pedra (Hymenolobium petraeum Ducke cumarurana (Dipteryx polyphylla (Huber Ducke, jatobá (Hymenaea courbaril L. and louro-vermelho (Nectandra rubra (Mez CK Allen. The trees were collected from Precious Woods Amazon Company forest management area, in Silves, Amazonas. Analyzes such as: concentration of extractives, lignin amount, percentage of minerals (ash and tannin content, density, elemental analysis (CHNS-O and thermal analysis were done. It was observed that the chemical composition (lignin, holocellulose and elemental analysis (percentage of C, H, N and O of the woods have significant differences. The jatobá wood presented higher tannin content, and in the thermal analysis, was that which had the lowest mass loss.

Wood preservatives and pressure-treated wood: considerations for historic-preservation projects

Science.gov (United States)

Ronald W. Anthony; Stan T. Lebow

2015-01-01

Wood, an abundant resource throughout most of the world, has been used as a building material for thousands of years. Many historic buildings have been built primarily of wood, and masonry and stone buildings generally have wood elements, both structural and architectural. As a biological material, wood is both remarkably complex and yet quite durable if well...

Rapid microwave-assisted acid extraction of metals from chromated copper arsenate (CCA)-treated southern pine wood

Science.gov (United States)

Bin Yu; Chung Y. Hse; Todd F. Shupe

2009-01-01

The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in...

Changes of wood cell walls in response to hygro-mechanical steam treatment.

Science.gov (United States)

Guo, Juan; Song, Kunlin; Salmén, Lennart; Yin, Yafang

2015-01-22

The effects of compression combined with steam treatment (CS-treatment), i.e. a hygro-mechanical steam treatment on Spruce wood were studied on a cell-structure level to understand the chemical and physical changes of the secondary cell wall occurring under such conditions. Specially, imaging FT-IR microscopy, nanoindentation and dynamic vapour absorption were used to track changes in the chemical structure, in micromechanical and hygroscopic properties. It was shown that CS-treatment resulted in different changes in morphological, chemical and physical properties of the cell wall, in comparison with those under pure steam treatment. After CS-treatment, the cellular structure displayed significant deformations, and the biopolymer components, e.g. hemicellulose and lignin, were degraded, resulting in decreased hygroscopicity and increased mechanical properties of the wood compared to both untreated and steam treated wood. Moreover, CS-treatment resulted in a higher degree of degradation especially in earlywood compared to a more uniform behaviour of wood treated only by steam. Copyright © 2014 Elsevier Ltd. All rights reserved.

Heat-induced chemical and color changes of extractive-free Black Locust (Rosinia Pseudoacacia) wood

Science.gov (United States)

Yao Chen; Jianmin Gao; Yongming Fan; Mandla A. Tshabalala; Nicole M. Stark

2012-01-01

To investigate chemical and color changes of the polymeric constituents of black locust (Robinia pseudoacacia) wood during heat treatment, extractive-free wood flour was conditioned to 30% initial moisture content (MC) and heated for 24 h at 120 °C in either an oxygen or nitrogen atmosphere. The color change was measured using the CIELAB color system. Chemical changes...

Mineral preservatives in the wood of Stradivari and Guarneri.

Directory of Open Access Journals (Sweden)

Joseph Nagyvary

Full Text Available Following the futile efforts of generations to reach the high standard of excellence achieved by the luthiers in Cremona, Italy, by variations of design and plate tuning, current interest is being focused on differences in material properties. The long-standing question whether the wood of Stradivari and Guarneri were treated with wood preservative materials could be answered only by the examination of wood specimens from the precious antique instruments. In a recent communication (Nature, 2006, we reported about the degradation of the wood polymers in instruments of Stradivari and Guarneri, which could be explained only by chemical manipulations, possibly by preservatives. The aim of the current work was to identify the minerals from the small samples of the maple wood which were available to us from the antique instruments. The ashes of wood from one violin and one cello by Stradivari, two violins by Guarneri, one viola by H. Jay, one violin by Gand-Bernardel were analyzed and compared with a variety of commercial tone woods. The methods of analysis were the following: back-scattered electron imaging, X-ray fluorescence maps for individual elements, wave-length dispersive spectroscopy, energy dispersive X-ray spectroscopy and quantitative microprobe analysis. All four Cremonese instruments showed the unmistakable signs of chemical treatments in the form of chemicals which are not present in natural woods, such as BaSO4, CaF2, borate, and ZrSiO4. In addition to these, there were also changes in the common wood minerals. Statistical evaluation of 12 minerals by discriminant analysis revealed: a. a difference among all four Cremona instruments, b. the difference of the Cremonese instruments from the French and English antiques, and c. only the Cremonese instruments differed from all commercial woods. These findings may provide the answer why all attempts to recreate the Stradivarius from natural wood have failed. There are many obvious

Electrodialytic remediation of CCA-treated waste wood in a 2 m3 pilot plant

DEFF Research Database (Denmark)

Christensen, Iben Vernegren; Pedersen, Anne Juul; Ottosen, Lisbeth M.

2006-01-01

Waste wood that has been treated with chromated-copper-arsenate (CCA) poses a potential environmental problem due to the content of copper, chromium and arsenic. A pilot plant for electrodialytic remediation of up to 2 m3 wood has been designed and tested and the results are presented here. Sever...

Understanding decay resistance, dimensional stability and strength changes in heat treated and acetylated wood

Science.gov (United States)

Roger M. Rowell; Rebecca E. Ibach; James McSweeny; Thomas Nilsson

2009-01-01

Reductions in hygroscopicity, increased dimensional stability and decay resistance of heat-treated wood depend on decomposition of a large portion of the hemicelluloses in the wood cell wall. In theory, these hemicelluloses are converted to small organic molecules, water and volatile furan-type intermediates that can polymerize in the cell wall. Reductions in...

Effect of coating systems on the vaporization of pentachlorophenol from treated wood

Science.gov (United States)

L. L. Ingram; G. D. McGinnis; P. M. Pope; W. C. Feist

1983-01-01

Specimens of southern pine treated with pentachlorophenol (penta) in mineral spirits (dip treatment), penta in P9 type A oil and penta in methylene chloride (pressure treatments) were used to evaluate the efficacy of different types of coatings in suppressing the vaporization of penta from treated wood. The clear film-forming coatings, such as polyurethane and alkyds,...

Mechanical properties of wood from Pinus sylvestris L. treated with Light Organic Solvent Preservative and with waterborne Copper Azole

Energy Technology Data Exchange (ETDEWEB)

Villasante, A.; Laina, R.; Rojas, J. A. M.; Rojas, I. M.; Vignote, S.

2013-07-01

Aim of study: To determine the effect on wood from Pinus sylvestris of treatment with preservatives on mechanical properties and to establish the relation between the penetration and compression strenght. Area of study: Spain. Material and methods: 40 samples of defect-free wood from Pinus sylvestris L. were treated with Light Organic Solvent Preservative (Vacsol Azure WR 2601) and 50 with waterborne Copper Azole (Tanalith E 3492). 40 control samples were not treated (water or preservative). Mechanical resistance to static bending, modulus of elasticity and compression strength parallel to the grain were compared with untreated wood. Regression analysis between the penetration and compression strength parallel was done with the samples treated with waterborne preservative. Main results: The results indicate that the treated wood (with either product) presents a statistically significant increase in mechanical resistance in all three mechanical characteristics. The results obtained differ from earlier studies carried out by other authors. There was no correlation between parallel compression strength and the degree of impregnation of the wood with waterborne Copper Azole. The most probable explanation for these results concerns changes in pressure during treatment. The use of untreated control samples instead of samples treated only with water is more likely to produce significant results in the mechanical resistance studies. Research highlights: Treated wood presents a statistically significant increase in MOE, modulus of rupture to static bending and parallel compression strength. There was no correlation between parallel compression strength and the degree of impregnation with waterborne preservative. (Author)

Statistical analysis of influence of soil source on leaching of arsenic and copper from CCA-C treated wood

Science.gov (United States)

Patricia Lebow; Richard Ziobro; Linda Sites; Tor Schultz; David Pettry; Darrel Nicholas; Stan Lebow; Pascal Kamdem; Roger Fox; Douglas Crawford

2006-01-01

Leaching of wood preservatives affects the long-term efficacy and environmental impact of treated wood. Soil properties and wood characteristicscan affectleaching of woad preservatives, but these effects are not well understood. This paper reports a statistical analysis of the effects of soil and wood properties on leaching of arsenic (As) and copper (Cu) from southern...

Mechanical properties of wood from Pinus sylvestris L. treated with Light Organic Solvent Preservative and with waterborne Copper Azole

Directory of Open Access Journals (Sweden)

A.M. Villasante

2013-12-01

Full Text Available Aim of study: To determine the effect on wood from Pinus sylvestris of treatment with preservatives on mechanical properties and to establish the relation between the penetration and compression strength.Area of study: SpainMaterial and Methods: 40 samples of defect-free wood from Pinus sylvestris L. were treated with Light Organic Solvent Preservative (Vacsol Azure WR 2601 and 50 with waterborne Copper Azole (Tanalith E 3492. 40 control samples were not treated (water or preservative. Mechanical resistance to static bending, modulus of elasticity and compression strength parallel to the grain were compared with untreated wood. Regression analysis between the penetration and compression strength parallel was done with the samples treated with waterborne preservative.Main results: The results indicate that the treated wood (with either product presents a statistically significant increase in mechanical resistance in all three mechanical characteristics. The results obtained differ from earlier studies carried out by other authors.There was no correlation between parallel compression strength and the degree of impregnation of the wood with waterborne Copper Azole . The most probable explanation for these results concerns changes in pressure during treatment.The use of untreated control samples instead of samples treated only with water is more likely to produce significant results in the mechanical resistance studies.Research highlights: Treated wood presents a statistically significant increase in MOE, modulus of rupture to static bending  and parallel compression strength.There was no correlation between parallel compression strength and the degree of impregnation with waterborne preservative.Keywords: Light Organic Solvent Preservative; MOE; parallel compression; static bending; waterborne Copper Azole; wood technology.

Assessment of the radiation field from radioactive elements in a wood-ash-treated coniferous forest in southwest Sweden

International Nuclear Information System (INIS)

Ravila, A.; Holm, E.

1996-01-01

The distribution of natural and antrophogenic radioactive elements in soil and wood was investigated in a 30-year-old forest stand of Norway spruce. Forest plots treated with a single dose of granulated wood ash in 1989 were compared with untreated control plots. It was observed that the retention of radiocesium and radiostrontium by the forest soil is rather strong in spite of the high annual precipitation (1100 mm a -1 ) and the relatively acidic conditions of the soil. Most of the deposited nuclear weapon fall-out of radiocesium and radiostrontium is still residing in the forest soil. Radiostrontium, but not radiocesium, was found in the intrasoil water collected with lysimeters at soil depths of 20 and 50 cm. Wood xylem radial distributions of radiostrontium indicated a decreased bioavailability with time after deposition of nuclear weapons fall-out, and no major differences could be observed on comparison of wood from ash-treated plots with wood from untreated plots. The activity concentration of radiocesium in tree rings formed prior to 1986 and grown at the ash-treated plot was about two to three times that found in wood from the untreated control plot. (author)

Effects of Treatment Materials on the Physical Properties of Eucalyptus (Eucalyptus camaldulensis Dehn. Wood

Directory of Open Access Journals (Sweden)

Selahattin Bardak

2011-04-01

Full Text Available This study was designed to determine effects on retention and shrink levels of Eucalyptus (Eucalyptus camaldulensis Dehn. which treated with some commercial preservative types, borates, polyethylene glycol, and water repellents. In this study, four type impregnation chemicals were chosen: 1. Commercial preservative types, [Ammonium sulphate, Vacsol-WR WR and Immersol-WR (WR], 2. Borates chemicals, [Boric acid, Borax, Boric acid+ Borax] 3. Polyethylene glycol such as Polyethylene glycol (PEG-400 4. Water repellents [Styrene, Methylmetacrylate.]. As a result, retention % and shrink levels of Eucalyptus wood was lower treated with commercial preservative types and borates preservatives compare to other treatment chemicals. However, retention % levels of Eucalyptus wood treated with WR chemicals were highly significant levels. According to their leachability period although PEG 400 showed antishrink effectiveness other treatments didnt showed antishrink efficiency.

Continuous Fixed-Bed Column Study and Adsorption Modeling: Removal of Lead Ion from Aqueous Solution by Charcoal Originated from Chemical Carbonization of Rubber Wood Sawdust

Directory of Open Access Journals (Sweden)

Swarup Biswas

2015-01-01

Full Text Available The efficiency of chemically carbonized rubber wood sawdust for the removal of lead ion from the aqueous stream was investigated by column process. Chemically carbonized rubber wood sawdust was prepared by treating the sawdust with H2SO4 and HNO3. Maximum removal of lead ion in column process was found as 38.56 mg/g. The effects of operating parameters such as flow rate, bed depth, concentration, and pH were studied in column mode. Experimental data confirmed that the adsorption capacity increased with the increasing inlet concentration and bed depth and decreased with increasing flow rate. Thomas, Yoon-Nelson, and Adams-Bohart models were used to analyze the column experimental data and the relationship between operating parameters. Chemically carbonized rubber wood sawdust was characterized by using Fourier transform infrared spectroscopy. Scanning electron microscope was also utilized for morphological analysis of the adsorbent. Furthermore X-ray fluorescence spectrum analysis and energy dispersive X-ray spectroscopy were also used for the confirmation of lead adsorption process.

ANATOMICAL CHARACTERISTICS AND CHEMICAL PROPERTIES OF THE BRANCH-WOOD OF Schizolobium amazonicum DUCKE SPECIES AND ITS POTENTIAL USES

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Yusup Amin

2013-10-01

Full Text Available The scale of forest degradation and deforestation in Indonesia has inspired the use of lesser-known wood species, which are potentially abundant and so far has not much been utilized. Utilization of these woods should be imposed not only of the stem wood but also of the branch-wood portions. Schizolobiumamazonicum Ducke treeis one of those lesser-known species, and growing fast with an MAIof3.68 cm/year.In Indonesia this species is only found in the Purwodadi Botanical Garden. A research was conducted to study the basic characteristics (anatomical aspects and chemical properties of the branch-wood portion of this species. The branch-wood materials were obtained from the Purwodadi Botanical Garden situated in Pasuruan (East Java. The specimens used were the first branch of the trunk (stem of nine-year old S. amazonicum tree (= 29.46 cm. The branch-wood samples were then examined for the anatomical aspects (macroscopic and microscopic characteristics and chemical properties (chemical composition. Results revealed that the anatomical properties of S.amazonicum branch-wood exhibited close similarities to those of sengon wood; it was light in appearance and white in color. Its fiber averaged about 1500 μm, and based on the fiber dimension's derived values the branch- wood fiber of this species was categorized into first-class quality for pulp and paper manufacture. Further, the chemical composition of this branch-wood compared favorably with that of sengon and mangium wood. The composition of extractive content thatsoluble in alcohol-benzene; lignin; holocellulose; and α-cellulose of this branch-wood were 2.46; 28.71; 80.64; and 50.47%, respectively. The overall assessment implied that the branch-wood portion of S.amazonicum tree affords favorable potential to be developed as raw material for pulp and paper manufacture. Also, considering that both sengon and mangium woods were already used in the pulp and paper industries as well as the trees are

Counter-current acid leaching process for copper azole treated wood waste.

Science.gov (United States)

Janin, Amélie; Riche, Pauline; Blais, Jean-François; Mercier, Guy; Cooper, Paul; Morris, Paul

2012-09-01

This study explores the performance of a counter-current leaching process (CCLP) for copper extraction from copper azole treated wood waste for recycling of wood and copper. The leaching process uses three acid leaching steps with 0.1 M H2SO4 at 75degrees C and 15% slurry density followed by three rinses with water. Copper is recovered from the leachate using electrodeposition at 5 amperes (A) for 75 min. Ten counter-current remediation cycles were completed achieving > or = 94% copper extraction from the wood during the 10 cycles; 80-90% of the copper was recovered from the extract solution by electrodeposition. The counter-current leaching process reduced acid consumption by 86% and effluent discharge volume was 12 times lower compared with the same process without use of counter-current leaching. However, the reuse of leachates from one leaching step to another released dissolved organic carbon and caused its build-up in the early cycles.

Effect of simulated rainfall and weathering on release of preservative elements from CCA treated wood

Science.gov (United States)

Stan Lebow; R. Sam Williams; Patricia Lebow

2003-01-01

The release of arsenic from wood pressure-treated with chromated copper arsenate (CCA) can be decreased by application of wood finishes, but little is known about the types of finishes that are best suited for this purpose. This study evaluated the effects of finish water repellent content and ultraviolet (UV) radiation on the release of arsenic, copper, and chromium...

Synchrotron based x-ray fluorescence microscopy confirms copper in the corrosion products of metals in contact with treated wood

Science.gov (United States)

Samuel L. Zelinka; Joseph E. Jakes; Grant T. Kirker; David Vine; Stefan Vogt

2017-01-01

Copper based waterborne wood preservatives are frequently used to extend the service life of wood products when subjected to frequent moisture exposure. While these copper based treatments protect the wood from fungal decay and insect attack, they increase the corrosion of metals embedded or in contact with the treated wood. Previous research has shown the most...

Anatomical and chemical properties and density of Coffea arabica L. wood

Directory of Open Access Journals (Sweden)

Marisa Aparecida Pereira

2014-09-01

Full Text Available The state of Minas Gerais is the largest producer of coffee in Brazil and the amount of residue in crops seems adequate to support production of solid wood products of Coffea arabica L., which is currently used for energy purposes or remains in the area. This activity adds insignificant value the coffee products and release CO2, which has harmful effects to the environment. This study was conducted with the aim of characterizing technologically Coffea arabica L. wood to enhance its use in furniture, to characterize its anatomical, chemical and wood basic density. The density showed an average of 0.608g.cm-3. The anatomical analysis showed distinct growth layers, semiporosos vessels with simple perforation plates. The axial parenchyma is apotracheal and diffuse in the aggregate with heterogeneous rays, not laminated and fiber libriformes not septate with bordered pits distinct. The chemical content of extract in hot and cold water were respectively 6.1% and 9.6%. The ash content was found to be 0.68%. Data were comparable to those of mahogany (Swietenia macrophylla and Piptadenia peregrina Benth, (angico-vermelho used for the production of furniture.

Chemical source characterization of residential wood combustion emissions in Denver, Colorado; Bakersfield, California; and Mammoth Lakes, California

International Nuclear Information System (INIS)

Houck, J.E.; Goulet, J.M.; Chow, J.C.; Watson, J.G.

1989-01-01

The chemical composition of residential wood combustion particulate emissions was determined for fireplaces and woodstoves. Burn rates, burn patterns, wood burning appliances, and cordwood types characteristic of Denver, Colorado; Bakersfield, California; and Mammoth Lakes, California, were used during sample collection. Samples were collected using a dilution/cooling system to ensure that condensible compounds were captured. Analyses for 44 chemical species were conducted. Source profiles for use in chemical mass balance (CMB) modeling were calculated from the analytical data. The principal chemical species comprising the profiles were organic compounds and elemental carbon. The minor chemical species were sulfur, chlorine, potassium, sodium, calcium, zinc, nitrate, and ammonium. Virtually all potassium was in a water-soluble form, and sulfur emissions between fireplaces and woodstoves were noted. Area-specific source profiles for fireplaces, woodstoves, and overall residential wood combustion are presented

EFFECT OF REMOVING OLEORESIN WITH VARIOUS CHEMICAL COMPOUNDS ON PHYSICAL AND MECHANICAL PROPERTIES OF KERUING WOOD (DIPTEROCARPUS SPP.

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Bambang Wiyono

2007-03-01

Full Text Available Keruing  (Dipterocarpus spp.  was  the  second  important  wood  export of   Indonesia. Unfortunately, this wood contains oleoresin that hinders its utilization. Currently, the method used to remove oleoresin from keruing is by soaking it into bollied sodium salt solution. Result of  this method is unsatisfactory because the residual heavy oleoresin might still appear on the wood surface. The study was conducted to determine suitable chemical compounds for removing oleoresin from keruing, and the effects on physical and mechanical properties of the wood. Four types of chemical compounds were tested, i.e. sodium chloride, oxalic acid, sulfuric acid, and nitric acid, each at the concentrations of  0.5 percent, 1.0 percent, and 1.5 percent. Wood samples were soaked in the boiling solution at different concentration level for seven hours. When the solution cooled down, the oleoresin exudated out of  the wood samples was separated. The oleoresin was weighed for recovery determination after air dried, and the wood samples were cut into smaller-sized specimens for the physical and mechanical testing (MOE, MOR, compression parallel to grain, hardness and density. Results showed that sulfuric acid was the best chemical compound for removing oleoresin, and the higher the concentration the greater the oleoresin recovery. The second best chemical compound was nitric acid at an optimum concentration of one percent. The soaking of keruing in sulfuric acid and oxalic acid solution resulted in paler wood color compare with the untreated wood sample. Nitric acid solutions caused the color of the wood surface to turn into yellow brownish. The physical and mechanical properties (MOE, MOR, compression parallel to grain, hardness and density of the oleoresin-removed keruing were slightly lower than the untreated (control samples.

Cellulose Nanocomposites by Melt Compounding of TEMPO-Treated Wood Fibers in Thermoplastic Starch Matrix

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Aline Cobut

2014-04-01

Full Text Available To facilitate melt compounding of cellulose nanofibrils (CNF based composites, wood pulp fibers were subjected to a chemical treatment whereby the fibers were oxidized using 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO. This treatment introduced negatively charged carboxylate groups to the fibers. TEMPO-treated fibers (TempoF were added to a mixture of amylopectin starch, glycerol, and water. Granules were prepared from this mixture and processed into CNF composites by extrusion. TempoF were easier to process into composites as compared with non-treated pulp fibers (PF. SEM revealed partial disintegration of TempoF during melt processing. Consequently, TempoF gave composites with much better mechanical properties than those of conventional composites prepared from pulp fibers and TPS. Particularly, at 20 wt% TempoF content in the composite, the modulus and strength were much improved. Such a continuous melt processing route, as an alternative to laboratory solvent casting techniques, may promote large-scale production of CNF-based composites as an environmentally friendly alternative to synthetic plastics/composites.

Elastic and Strength Properties of Heat-Treated Beech and Birch Wood

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Vlastimil Borůvka

2018-04-01

Full Text Available This paper deals with the impact of heat treatment on the elastic and strength properties of two diffuse porous hardwoods, namely Fagus sylvatica and Betula pendula. Two degrees of the heat treatment were used at temperatures of 165 °C and 210 °C. The dynamic and static elasticity modulus, bending strength, impact toughness, hardness, and density were tested. It is already known that an increase in treatment temperature decreases the mechanical properties and, on the other hand, leads to a better shape and dimensional stability. Higher temperatures of the heat treatment correlated with lower elastic and strength properties. In the case of higher temperature treatments, the decline of tested properties was noticeable as a result of serious changes in the chemical composition of wood. It was confirmed that at higher temperature stages of treatment, there was a more pronounced decrease in beech properties compared to those of the birch, which was the most evident in their bending strength and hardness. Our research confirmed that there is no reason to consider birch wood to be of a lesser quality, although it is regarded by foresters as an inferior tree species. After the heat treatment, the wood properties are almost the same as in the case of beech wood.

Copper Leaching from Copper-ethanolamine Treated Wood: Comparison of Field Test Studies and Laboratory Standard Procedures

OpenAIRE

Nejc Thaler; Miha Humar

2014-01-01

Copper-based compounds are some of the most important biocides for the protection of wood in heavy duty applications. In the past, copper was combined with chromium compounds to reduce copper leaching, but a recent generation of copper-based preservatives uses ethanolamine as a fixative. To elucidate the leaching of copper biocides from wood, Norway spruce (Picea abies) wood was treated with a commercial copper-ethanolamine solution with two different copper concentrations (cCu = 0.125% and 0...

Demonstration of the efficiency and robustness of an acid leaching process to remove metals from various CCA-treated wood samples.

Science.gov (United States)

Coudert, Lucie; Blais, Jean-François; Mercier, Guy; Cooper, Paul; Janin, Amélie; Gastonguay, Louis

2014-01-01

In recent years, an efficient and economically attractive leaching process has been developed to remove metals from copper-based treated wood wastes. This study explored the applicability of this leaching process using chromated copper arsenate (CCA) treated wood samples with different initial metal loading and elapsed time between wood preservation treatment and remediation. The sulfuric acid leaching process resulted in the solubilization of more than 87% of the As, 70% of the Cr, and 76% of the Cu from CCA-chips and in the solubilization of more than 96% of the As, 78% of the Cr and 91% of the Cu from CCA-sawdust. The results showed that the performance of this leaching process might be influenced by the initial metal loading of the treated wood wastes and the elapsed time between preservation treatment and remediation. The effluents generated during the leaching steps were treated by precipitation-coagulation to satisfy the regulations for effluent discharge in municipal sewers. Precipitation using ferric chloride and sodium hydroxide was highly efficient, removing more than 99% of the As, Cr, and Cu. It appears that this leaching process can be successfully applied to remove metals from different CCA-treated wood samples and then from the effluents. Copyright © 2013 Elsevier Ltd. All rights reserved.

THE EFFECT OF HEAT TREATMENT ON THE CHEMICAL AND COLOR CHANGE OF BLACK LOCUST (ROBINIA PSEUDOACACIA WOOD FLOUR

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Yao Chen,

2012-01-01

Full Text Available The aim of this study was to investigate the effects of oxygen and moisture content (MC on the chemical and color changes of black locust (Robinia pseudoacacia wood during heat treatment. The wood flour was conditioned to different initial MCs and heated for 24 h at a constant temperature of 120ºC in either oxygen or nitrogen atmosphere. The pH values and chromaticity indexes were examined. Diffuse reflectance UV-Vis (DRUV and Fourier transform infrared (FTIR spectra were used to characterize the changes of chromophores upon heating. The study demonstrated that the pH values decreased after heat treatment, and it was lower when the heat treated was in oxygen than in nitrogen. The L* decreased significantly, while a* and b* increased. The total color difference ΔE* increased with increasing initial MC until a plateau was reached after 30% MC. The color change was greater in oxygen than in nitrogen. The hydroxyl groups decreased after heat treatment. The releases of acid and formation of quinoid compounds and carboxylic groups during heat treatment were confirmed. Discoloration of wood is due mainly to the condensation and oxidation reactions, which are accelerated by oxygen. Higher MCs are required to obtain the greatest color change of wood in inert atmosphere.

Potassium methyl siliconate-treated pulp fibers and their effects on wood plastic composites: Water sorption and dimensional stability

Science.gov (United States)

Cheng Piao; Zhiyong Cai; Nicole M. Stark; Charles J. Monlezun

2013-01-01

Potassium methyl siliconate (PMS) was investigated as a new nano modifier of wood fiber and wood flour to improve the compatibility between the fiber/flour and the plastic matrix in fiber reinforced plastic composites. Before injection molding, bleached and brown pulp fibers and mixed species wood flour were pretreated in PMS solutions. The morphology of the treated...

In vitro bioaccessibility of copper azole following simulated dermal transfer from pressure-treated wood

Data.gov (United States)

U.S. Environmental Protection Agency — In vitro bioaccessibility of copper azole following simulated dermal transfer from pressure-treated wood. This dataset is associated with the following publication:...

Nondestructive methods of evaluating quality of wood in preservative-treated piles

Science.gov (United States)

Xiping. Wang; Robert J. Ross; John R. Erickson; John W. Forsman; Gary D. McGinnis; Rodney C. De Groot

2000-01-01

Stress-wave-based nondestructive evaluation methods were used to evaluate the potential quality and modulus of elasticity (MOE) of wood in used preservative-treated Douglas-fir and southern pine piles. Stress wave measurements were conducted on each pile section. Stress wave propagation speeds in the piles were then obtained to estimate their MOE. This was followed by...

Influence of corn steep liquor and glucose on colonization of control and CCB (Cu/Cr/B)-treated wood by brown rot fungi

International Nuclear Information System (INIS)

Humar, Miha; Amartey, Sam A.; Pohleven, Franc

2006-01-01

There are increasing problems with regard to the disposal of treated wood waste. Due to heavy metals or arsenic in impregnated wood waste, burning and landfill disposal options are not considered to be environmentally friendly solutions for dealing with this problem. Extraction of the heavy metals and recycling of the preservatives from the wood waste is a much more promising and environmentally friendly solution. In order to study the scale up of this process, copper/chromium/boron-treated wood specimens were exposed to copper tolerant (Antrodia vaillantii and Leucogyrophana pinastri) and copper sensitive wood decay fungi (Gloeophyllum trabeum and Poria monticola). Afterwards, the ability of fungal hyphae to penetrate and overgrow the wood specimens was investigated. The fungal growths were stimulated by immersing the specimens into aqueous solution of glucose or corn steep liquor prior to exposure to the fungi. The fastest colonization of the impregnated wood was by the copper tolerant A. vaillantii. Addition of glucose onto the surface of the wood specimens increased the fungi colonization of the specimens; however, immersion of the specimens into the solution of corn steep liquor did not have the same positive influence. These results are important in elucidating copper toxicity in wood decay fungi and for using these fungi for bioremediation of treated wood wastes

Soil quality in a cropland soil treated with wood ash containing charcoal

Science.gov (United States)

Omil, Beatriz; Balboa, Miguel A.; Fonturbel, M. Teresa; Gartzia-Bengoetxea, Nahia; Arias-González, Ander; Vega, Jose A.; Merino, Agustin

2014-05-01

The strategy of the European Union "Europe 2020" states that by 2020, 20% of final energy consumption must come from renewables. In this scenario, there is an increasing use of biomass utilization for energy production. Indeed, it is expected that the production of wood-ash will increase in coming years. Wood ash, a mixture of ash and charcoal, generated as a by-product of biomass combustion in power plants, can be applied to soil to improve the soil quality and crop production. Since the residue contains significant content of charcoal, the application of mixed wood ash may also improve the SOM content and soil quality in the long term, in soils degraded as a consequence of intensive management. The objective of this study was asses the changes in SOM quality and soil properties in a degraded soils treated with wood ash containing charcoal. The study was carried out in a field devoted to cereal crops during the last decades. The soil was acidic (pH 4.5) with a low SOC content (3 %) and fine texture. The experiment was based on a randomised block design with four replicates. Each block included the following four treatments: Control, 16 Mg fly wood ash ha-1, 16 Mg mixed wood ash ha-1 (16 Mg) and 32 Mg mixed wood ash ha-1 (32 Mg). The application was carried out once. The ash used in the study was obtained from a thermal power plant and was mainly derived from the combustion of Pinus radiata bark and branches. The wood ash is highly alkaline (pH= 10), contains 10 % of highly condensed black carbon (atomic H/C ratio solid state 13C CPMAS NMR and Differential Scanning Calorimetry (DSC). These techniques were applied in bulk samples and aggregates of different sizes. The changes in microbial activity were studied by analysis of microbial biomass C and basal respiration. The soil bacterial community was studied by the Biolog method. Several physical properties, such soil aggregate distribution, hydraulic conductivity and available water contente were also determined

Improving the two-step remediation process for CCA-treated wood. Part I, Evaluating oxalic acid extraction

Science.gov (United States)

Carol Clausen

2004-01-01

In this study, three possible improvements to a remediation process for chromated-copper-arsenate (CCA) treated wood were evaluated. The process involves two steps: oxalic acid extraction of wood fiber followed by bacterial culture with Bacillus licheniformis CC01. The three potential improvements to the oxalic acid extraction step were (1) reusing oxalic acid for...

Effect of precipitation pattern on leaching of preservative from treated wood and implications for accelerated testing

Science.gov (United States)

Stan Lebow

2014-01-01

There is a need to develop improved accelerated test methods for evaluating the leaching of wood preservatives from treated wood exposed to precipitation. In this study the effects of rate of rainfall and length of intervals between rainfall events on leaching was evaluated by exposing specimens to varying patterns of simulated rainfall under controlled laboratory...

Possible preparation of wood-plastic composites based on unsaturated polyester resins and styrene by radiation and chemical methods in combination

International Nuclear Information System (INIS)

Pesek, M.; Pultar, F.; Jarkovsky, J.; Andr, J.

1983-01-01

Using the radiation chemical method it is possible to prepare wood-plastic composites using doses of 1 to 2.5 kGy. The impregnation mixture in the wood gelatinates and subsequent curing using chemical initiators takes place without outflow of the mixture from the wood and without formation of incrustations. The basic components of the impregnation mixtures used were unsaturated polyester resins; styrene or methyl methacrylate was used as the thinner. The proven initiator of polymerization was 2,2'-azobisisobutyronitrile. The technology is described of wood impregnation and radiation or chemical curing. The effects were monitored of viscosity, temperature, radiation dose and the concentrations of the individual components of the impregnation mixtures and initiators of polymerization on the process of the preparation of wood-plastic composites. (M.D.)

Leaching of chromated copper arsenate (CCA)-treated wood in a simulated monofill and its potential impacts to landfill leachate

Energy Technology Data Exchange (ETDEWEB)

Jambeck, Jenna R. [Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL 32611-6450 (United States); Townsend, Timothy [Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL 32611-6450 (United States)]. E-mail: ttown@ufl.edu; Solo-Gabriele, Helena [Department of Civil, Architectural, and Environmental Engineering, University of Miami, Coral Gables, FL 33146-0630 (United States)

2006-07-31

The proper end-of-life management of chromated copper arsenate (CCA)-treated wood, which contains arsenic, copper, and chromium, is a concern to the solid waste management community. Landfills are often the final repository of this waste stream, and the impacts of CCA preservative metals on leachate quality are not well understood. Monofills are a type of landfill designed and operated to dispose a single waste type, such as ash, tires, mining waste, or wood. The feasibility of managing CCA-treated wood in monofills was examined using a simulated landfill (a leaching lysimeter) that contained a mix of new and weathered CCA-treated wood. The liquid to solid ratio (LS) reached in the experiment was 0.63:1. Arsenic, chromium, and copper leached from the lysimeter at average concentrations of 42 mg/L for arsenic, 9.4 mg/L for chromium, and 2.4 mg/L for copper. Complementary batch leaching studies using deionized water were performed on similar CCA-treated wood samples at LS of 5:1 and 10:1. When results from the lysimeter were compared to the batch test results, copper and chromium leachability appeared to be reduced in the lysimeter disposal environment. Of the three metals, arsenic leached to the greatest extent and was found to have the best correlation between the batch and the lysimeter experiments.

Online Sorting of Wood Treated with Chromated Copper Arsenate Using Laser Induced Breakdown Spectroscopy

National Research Council Canada - National Science Library

Moskal, Thomas

2001-01-01

.... While CCA treated wood has several benefits, with perhaps the most important being the saving of an estimated 225 million trees annually due to its longer service life, there are growing concerns...

CORROSION AND CHEMICAL WASTE IN SAWBLADES STEEL USED IN WOOD

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Paulo Fernando Trugilho

2002-01-01

Full Text Available The objective this work was to evaluate the chemical waste provoked by the wood on the sheets of steel used in the making of the mountains and cut tools. It was certain the correlationbetween the chemical waste and the extractive soluble in cold water, hot water and in the sequencetoluene and ethanol content. Two types of steel and twenty-seven species different from wood wereused. The corrosive agent, constituted of 50 g of fresh sawdust (moist mixed to 50 ml of distilledwater, it was prepared and placed inside of the plastic box, hermetically closed, on the samples ofsteel, which were totally immersed. The box was placed in a water bath pre-heated to 75°C, that themedium temperature of reaction is considered, that affects the sheet of the sawblade in operation. Thisgroup was operated to 80 rotations per minute (rpm. The time of reaction was of four hours. Afterthat time the corrosive agent was discarded and the samples were washed, dried and weighed. At theend, each sample was processed by a total period of forty hours. The chemical waste was evaluated by the weight difference suffered from beginning at the end of the experiment. For theresults it was observed that the Eucalyptus tradryphloia and the Eucalyptus phaeotricha the speciesthat provoked were, respectively, the largest and smaller chemical waste for the two types of steelappraised. Great variation exists in the chemical waste due to the effect of the species. The corrosionand chemical waste are especially related with the quality of the material solved in ethanol. The 1070steel were more attached than the 6170 steel.

Chemical evolution of Miocene wood: Example from the Belchatow brown coal deposit, central Poland

Science.gov (United States)

Drobniak, A.; Mastalerz, Maria

2006-01-01

Miocene conifer wood samples from the Belchatow brown coal deposit in Poland were studied in order to discuss a range of chemical variations that occur as a result of biochemical coalification. Petrographic analysis, ultimate analysis, electron microprobe technique, and FTIR spectroscopy were used in this study. Our data show several progressive trends in functional groups distribution that take place during the wood transformation from group 1 to group 4, such as an overall increase in aromaticity, an increase in lignin/cellulose ratio, and an increase in oxygen functionalities. Other observations include an increase in aliphatic stretching and bending functionalities from groups 1 to 3; followed by a decrease in the wood of group 4; appearance of aliphatic out-of-plane bands in group 3 and increase in group 4; an increase in CH2/CH3 in group 4 compared to the other groups; and decrease in O-H groups in group 4 compared to other groups. These observations, together with other chemical and petrological observations, indicate that the progressive elimination of cellulose and modification of lignin are dominant processes of the wood transformation. ?? 2005 Elsevier B.V. All rights reserved.

New Approach to Remove Metals from Chromated Copper Arsenate (CCA)-Treated Wood

Science.gov (United States)

Todd F. Shupe; Chung Y. Hse; Hui Pan

2012-01-01

Recovery of metals from chromated copper arsenate (CCA)-treated southern pine wood particles was investigated using binary acid solutions consisting of acetic, oxalic, and phosphoric acids in a microwave reactor. Formation of an insoluble copper oxalate complex in the binary solution containing oxalic acid was the major factor for low copper removal. Furthermore, the...

Fabrication of Hydrophobic Surface on Wood Veneer via Electroless Nickel Plating Combined with Chemical Corrosion

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Zhaojun Tang

2015-12-01

Full Text Available Birch veneers were coated with Ni-P films by a combined process of KBH4 activation and electroless plating. The plated veneers were further chemically corroded to obtain hydrophobic surfaces on wood. The effect of chemical corrosion on the contact angle of the veneers was investigated. The hydrophobic veneers were characterized by X-ray photo electron spectroscopy (XPS, scanning electron microscopy (SEM, and X-ray diffraction (XRD. The surface contact angle of birch veneer before and after it was plated with Ni-P alloy coating was 41º and 121º, respectively. The contact angle reached 136.7º when the nickel-coated veneers were corroded in CuSO4 aqueous solution for 30 min. XPS analysis showed that Cu0 cluster doped with little CuO formed on the corroded surface of Ni-P alloy film after chemical corrosion. SEM and XRD showed that rough copper clusters formed on the surface of the wood veneer and revealed the reason of the surface hydrophobicity. This study provides a new pathway for fabricating hydrophobic wood.

Corrosion rates of fasteners in treated wood exposed to 100% relative humidity

Science.gov (United States)

Samuel L. Zelinka; Douglas R. Rammer

2009-01-01

In the past, gravimetric corrosion data for fasteners exposed to treated wood has been reported as a percent weight loss. Although percent weight loss is a valid measure of corrosion for comparing identical fasteners, it can distort the corrosion performance of fasteners with different geometries and densities. This report reevaluates a key report on the corrosiveness...

An emissions audit of a biomass combustor burning treated wood waste

International Nuclear Information System (INIS)

Jackson, P.M.; Jones, H.H.; King, P.G.

1993-01-01

This report describes the Emissions Audit carried out on a Biomass Combustor burning treated wood waste at the premises of a furniture manufacturer. The Biomass Combustor was tested in two firing modes; continuous fire and modulating fire. Combustion chamber temperatures and gas residence times were not measured. Boiler efficiencies were very good at greater than 75% in both tests. However, analysis of the flue gases indicated that improved efficiencies are possible. The average concentrations of CO (512mgm -3 ) and THC (34mgm -3 ) for Test 1 were high, indicating that combustion was poor. The combustor clearly does not meet the requirements of the Guidance Note for the Combustion of Wood Waste. CO 2 and O 2 concentrations were quite variable showing that combustion conditions were fairly unstable. Improved control of combustion should lead to acceptable emission concentrations. (Author)

Chemical composition and sensory properties of non-wooded and wooded Shiraz (Vitis vinifera L.) wine as affected by vineyard row orientation and grape ripeness level.

Science.gov (United States)

Hunter, Jacobus J; Volschenk, Cornelis G

2018-05-01

The study aimed to unravel vineyard row orientation (NS, EW, NE-SW, NW-SE) and grape ripeness level (23, 25, 27 °Balling) implications for grape and wine composition and sensory properties/style (non-wooded/wooded wines) of Vitis vinifera L. cv. Shiraz (rootstock 101-14 Mgt). Soluble solid/titratable acidity ratios were lowest for EW, whereas warmer canopy sides (NW, N, NE) advanced grape ripening. Skin anthocyanins and phenolics generally decreased with ripening. NW-SE rows and S, SE, E and NE canopy sides showed highest skin total anthocyanins and phenolics. Wine total anthocyanins and phenolics increased with grape ripening; EW had lower values. Wine phenolic contents differed between canopy sides; N, NE, E and SE tended higher. Wine sensory profiles increased with grape ripening. For non-wooded wines, NW-SE and NE-SW row orientations generally resulted in highest scores, followed by NS. For EW rows, the N side presented better wines. Wood addition enhanced specific sensory descriptor perceptions. A large collection of wine styles surfaced in the same vineyard and terroir, increasing options to contribute positively to sustainable products. The study generated globally applicable, novel information vital for unlocking and valorising terroir/site potential for grape and wine chemical composition and wine sensory/style properties. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Online sorting of recovered wood waste by automated XRF-technology: part II. Sorting efficiencies.

Science.gov (United States)

Hasan, A Rasem; Solo-Gabriele, Helena; Townsend, Timothy

2011-04-01

Sorting of waste wood is an important process practiced at recycling facilities in order to detect and divert contaminants from recycled wood products. Contaminants of concern include arsenic, chromium and copper found in chemically preserved wood. The objective of this research was to evaluate the sorting efficiencies of both treated and untreated parts of the wood waste stream, and metal (As, Cr and Cu) mass recoveries by the use of automated X-ray fluorescence (XRF) systems. A full-scale system was used for experimentation. This unit consisted of an XRF-detection chamber mounted on the top of a conveyor and a pneumatic slide-way diverter which sorted wood into presumed treated and presumed untreated piles. A randomized block design was used to evaluate the operational conveyance parameters of the system, including wood feed rate and conveyor belt speed. Results indicated that online sorting efficiencies of waste wood by XRF technology were high based on number and weight of pieces (70-87% and 75-92% for treated wood and 66-97% and 68-96% for untreated wood, respectively). These sorting efficiencies achieved mass recovery for metals of 81-99% for As, 75-95% for Cu and 82-99% of Cr. The incorrect sorting of wood was attributed almost equally to deficiencies in the detection and conveyance/diversion systems. Even with its deficiencies, the system was capable of producing a recyclable portion that met residential soil quality levels established for Florida, for an infeed that contained 5% of treated wood. Copyright © 2010 Elsevier Ltd. All rights reserved.

Wood anatomy and physical and chemical properties of fast growing Athel tamarisk (Tamarix aphylla L.

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Reza oladi

2017-02-01

Full Text Available Athel tamarisk (Tamarix aphylla is a fast growing, evergreen tree succeeding in the most soils and can tolerate the saline conditions. Despite its ecological importance and wide distribution in central and southern parts of Iran, wood properties of this species has little been concerned. However, the potential of this species in cellulosic industries of Middle East dry countries has recently been focused. Hence, to study wood anatomy and physical and chemical properties of Athel tamarisk, 3 stands were selected and felled from the Zabol region (Sistan and Baluchestan province. Wood anatomical features of this species were studied and listed according to the list of microscopic features for hardwood identification by IAWA Committee. In addition, lignin distribution in xylem was studied using fluorescence microscopy. Calculating fiber biometry features assessed that although fiber quality is not perfect but meets the standards of paper production, comparing other commercially used hardwoods in this industry. According to chemical composition analysis, cellulose content of this wood is rather low (39% which could be a result of large amount of thin-walled paranchyma cells in xylem. Lignin content is a bit higher than average hardwoods and this component is concentrated in vessels and fibers. Physical properties of studied wood samples (specific gravity and shrinkage values were in the range of other light-weight and fast growing hardwoods and thus this wood is expected to have similar end-use quality.

Analysis of High Quality Agar wood Oil Chemical Compounds By Means Of SPME/ GC-MS and Z-Score Technique

International Nuclear Information System (INIS)

Nurlaila Ismail; Mohd Ali Nor Azah; Mailina Jamil; Saiful Nizam Tajuddin; Mohd Nasir Taib

2013-01-01

Currently, the grading of the agar wood oil to the high and low quality is done using manually such as human trained grader. It was performed based on the agar wood oil physical properties such as human experience and perception and the oil colour, odor and long lasting aroma. Several researchers found that chemical profiles of the oil should be utilized to overcome the problem facing by manual techniques for example human nose cannot tolerate with the many oils at the same time, so that accurate result can be obtained in grading the agar wood oil. The analysis involved of SPME/ GC-MS and Z-score techniques have been proposed in this study to analyze the chemical compounds especially from the high quality samples of agar wood oil (Aquilariamalaccensis) from Malaysia. Two SPME fibers were used such as divinylbenzene-carbogen-polydimethylsiloxane (DVB-CAR-PDMS) and polydimethylsiloxane (PDMS) in extracting the oils compound under three different sampling temperature conditions such as 40, 60 and 80 degree Celsius. The chemical compounds extracted by SPME/ GC-MS were analyzed. The chemical compounds as identified by Z-score as significant compounds were discussed before the conclusion is made. It was found that 10-epi-γ-eudesmol, aromadendrene, β-agar ofuran, α-agar ofuran and γ-eudesmol were highlighted as significant for high quality agar wood oil and can be used as a marker compounds in classifying the agar wood oil. (author)

Structural analysis of heat-treated birch (Betule papyrifera) surface during artificial weathering

International Nuclear Information System (INIS)

Huang Xianai; Kocaefe, Duygu; Kocaefe, Yasar; Boluk, Yaman; Krause, Cornélia

2013-01-01

Highlights: ► Investigate detailed structural changes of heat-treated wood due to weathering. ► Identify connection between physical structural changes and chemical degradation. ► Study effect of heat treatment conditions on weathering degradation process. - Abstract: Effect of artificial weathering on the surface structural changes of birch (Betule papyrifera) wood, heat-treated to different temperatures, was studied using the fluorescence microscopy and the scanning electron microscopy (SEM). Changes in the chemical structure of wood components were analyzed by FTIR in order to understand the mechanism of degradation taking place due to heat treatment and artificial weathering. The results are compared with those of the untreated (kiln-dried) birch. The SEM analysis results show that the effect of weathering on the cell wall of the untreated birch surface is more than that of heat-treated samples. The FTIR spectroscopy results indicate that lignin is the most sensitive component of heat-treated birch to the weathering degradation process. Elimination of the amorphous and highly crystallised cellulose is observed for both heat-treated and untreated wood during weathering. It is also observed that heat treatment increases the lignin and crystallised cellulose contents, which to some extent protects heat-treated birch against degradation due to weathering.

Chemical speciation of PM2.5 emissions from residential wood combustion and meat cooking

International Nuclear Information System (INIS)

McDonald, J.; Zielinska, B.; Fujita, E.; Chow, J.; Watson, J.; Sagebiel, J.; Sheetz, L.; Batie, S.

1998-01-01

Residential wood combustion and meat cooking emissions were each analyzed to develop a chemical emissions profile. Samples were collected using a DRI-constructed dilution stack sampler equipped with a 2.5 mm particle selective cyclone. Emissions were diluted 30-100 times, cooled to ambient temperature, and were allowed 80 seconds for condensation prior to collection. Fireplace and wood-stove emissions testing was conducted at the DRI facilities. Wood type, wood moisture, burn rate, and fuel load were varied for different experiments. Meat emissions testing was conducted at the CE-CERT stationary emissions lab in Riverside, California. Meat type, fat content, and the cooking appliance used were changed in different tests. Fine particle and semi-volatile organic compounds were collected on filter/PUF/XAD/PUF cartridges. Inorganic samples were collected on Teflon and quartz filters, which were analyzed for mass by gravimetry, elements by x-ray fluorescence, ammonium by automated colorimetry, organic and elemental carbon by thermal/optical reflectance, as well as chloride, nitrate, and sulfate by ion chromatography. Analysis of organic species was conducted by gas chromatography/mass spectrometry (GC/MS). These data have been utilized for constructing specific profiles for use in the Chemical Mass Balance model for apportionment of fine particle sources in the Denver, Colorado, region

MODELING AGGREGATE EXPOSURE AND DOSE OF CHILDREN TO A WOOD TREATMENT PRESERVATIVE FROM PLAYSETS AND HOME DECKS

Science.gov (United States)

Pressure- or non-pressure- treated lumber may pose a potential health hazard to children if the children contact certain chemicals in soils around leaching wood structures and/or in dislodgeable residues that may form on the wood surfaces of the structures. A physically-based,...

Elemental analysis of ash residue from combustion of CCA treated wood waste before and after electrodialytic extraction

DEFF Research Database (Denmark)

Pedersen, Anne Juul; Ottosen, Lisbeth M.

2006-01-01

Element distribution in a combined fly ash and bottom ash from combustion of copper chromate arsenate (CCA) treated wood waste was investigated by scanning electron microscopy (SEM/EDX) before and after electrodialytic extraction. The untreated ash contained various particles, including pieces...... of incompletely combusted wood rich in Cr and Ca, and irregular particles rich in Si, Al and K. Cr was also found incorporated in silica-based matrix particles. As was associated with Ca in porous (char) particles, indicating that Ca-arsenates had been formed during combustion. Cu was associated with Cr...... in the incompletely combusted wood pieces and was also found in almost pure form in a surface layer of some matrix particles – indicating surface condensation of volatile Cu species. In treated ash, Ca and As were no longer found together, indicating that Ca-arsenates had been dissolved due to the electrodialytic...

Arsenic levels in wipe samples collected from play structures constructed with CCA-treated wood: Impact on exposure estimates

Energy Technology Data Exchange (ETDEWEB)

Barraj, Leila M. [Chemical Regulation and Food Safety, Exponent, Inc., Suite 1100, 1150 Connecticut Ave., NW, Washington, DC 20036 (United States)], E-mail: lbarraj@exponent.com; Scrafford, Carolyn G. [Chemical Regulation and Food Safety, Exponent, Inc., Suite 1100, 1150 Connecticut Ave., NW, Washington, DC 20036 (United States); Eaton, W. Cary [RTI International, 3040 Cornwallis Road, Research Triangle Park, NC 27709 (United States); Rogers, Robert E.; Jeng, Chwen-Jyh [Toxcon Health Sciences Research Centre Inc., 9607 - 41 Avenue, Edmonton, Alberta, T6E 5X7 (Canada)

2009-04-01

Lumber treated with chromated copper arsenate (CCA) has been used in residential outdoor wood structures and playgrounds. The U.S. EPA has conducted a probabilistic assessment of children's exposure to arsenic from CCA-treated structures using the Stochastic Human Exposure and Dose Simulation model for the wood preservative scenario (SHEDS-Wood). The EPA assessment relied on data from an experimental study using adult volunteers and designed to measure arsenic in maximum hand and wipe loadings. Analyses using arsenic handloading data from a study of children playing on CCA-treated play structures in Edmonton, Canada, indicate that the maximum handloading values significantly overestimate the exposure that occurs during actual play. The objective of our paper is to assess whether the dislodgeable arsenic residues from structures in the Edmonton study are comparable to those observed in other studies and whether they support the conclusion that the values derived by EPA using modeled maximum loading values overestimate hand exposures. We compared dislodgeable arsenic residue data from structures in the playgrounds in the Edmonton study to levels observed in studies used in EPA's assessment. Our analysis showed that the dislodgeable arsenic levels in the Edmonton playground structures are similar to those in the studies used by EPA. Hence, the exposure estimates derived using the handloading data from children playing on CCA-treated structures are more representative of children's actual exposures than the overestimates derived by EPA using modeled maximum values. Handloading data from children playing on CCA-treated structures should be used to reduce the uncertainty of modeled estimates derived using the SHEDS-Wood model.

Effect of lime and wood ash on the nixtamalization of maize and tortilla chemical and nutritional characteristics.

Science.gov (United States)

Pappa, María Renée; de Palomo, Patricia Palacios; Bressani, Ricardo

2010-06-01

The objective of the study was to obtain information on the chemical composition, functional properties, sensory quality and protein value of tortillas made from the nixtamalization of maize using either lime or wood ashes. The Ca, K, Mg, Fe, and Zn content of lime and wood ashes showed lime to be high in Ca content while wood ash contained more K and about 71% of the Ca content of lime. Both contained relatively high levels of Mg, Fe and Zn, but more so in the wood ashes. The level of reagent for nixtamalization was set at 0.8% of the maize weight. All other processing conditions were kept constant. The pH of the cooking solution was 12.0 for lime and 10.9 for wood ash. The moisture content of maize at 60 min of cooking was 45.8% for both treatments, however after 12 h of soaking, moisture level was 51.0% for the lime treatment and only 46.8% for the ash treatment. Solids (2.4%) in the lime cooking liquor were higher than in the wood ash liquor (1.0%). Chemical composition changes were similar between treatments in masa and tortilla; however, both masa and tortillas absorbed relatively high levels of all minerals including Fe and Zn from the wood ash treatment. The different treatment influenced functional properties particularly hardness and color. Tortilla characteristics were also similar. Protein quality of both alkali cooked products was lower than that of raw corn, more so the product from the wood ash treatment. Although some differences were observed in the sensory studies, human subjects did not dislike the wood ash made tortillas.

Wood

DEFF Research Database (Denmark)

Unterrainer, Walter

2014-01-01

come from? How is it harvested? How is it manufactured and treated ? How are the buildings detailed and protected against weather during construction to keep them dry and make them long-life ? In a period of climate change, forests are the last lungs of the planet to sequestrate CO2. Their global size......Wood – a sustainable building material ? For thousands of years and all over the planet, wood has been used as a building material and exciting architecture has been created in wood. The fantastic structural, physical and aesthetic properties of the material as well as the fact that wood...

The Effect of Ultrasound Pretreatment on Poplar Wood Dimensional Stability

Directory of Open Access Journals (Sweden)

Shu Qiu

2016-08-01

Full Text Available Dimensional stability is a key property of wood that significantly affects its applications. The effect of an ultrasound pretreatment on poplar wood (Populous tomentosa dimensional stability was examined. During the pretreatments, wood samples were immersed in distilled water and treated ultrasonically under three different powers and frequencies. The samples were then analyzed by Fourier transform infrared spectroscopy (FTIR and X-ray diffraction (XRD. The chemical transformation of the cell-wall material was studied and then associated with the change of water absorption and the swelling coefficient. The results showed that the water absorption decreased after the ultrasonic pretreatment. The axial and radial swelling coefficients of the pretreated samples decreased, while the tangential swelling coefficients increased. The volumetric swelling coefficient of pretreated specimens fluctuated near 4.48% (the volumetric swelling coefficient of untreated wood. Ultrasonic pretreatment increased the number of hydrophilic groups, such as the hydroxyl, acetyl, and uronic ester groups. Meanwhile, the pretreatment also increased the degree of crystallinity and reduced the available polar groups. These two factors together caused the change of the moisture absorption and the swelling coefficient of the pretreated wood. These conclusions suggest that the ultrasonic pretreatment is a promising method for further chemical modification of wood.

Analysis of preservative-treated wood by multivariate analysis of laser-induced breakdown spectroscopy spectra

International Nuclear Information System (INIS)

Martin, Madhavi Z.; Labbe, Nicole; Rials, Timothy G.; Wullschleger, Stan D.

2005-01-01

In this work, multivariate statistical analysis (MVA) techniques are coupled with laser-induced breakdown spectroscopy (LIBS) to identify preservative types (chromated copper arsenate, ammoniacal copper zinc or alkaline copper quat), and to predict elemental content in preservative-treated wood. The elemental composition of the samples was measured with a standard laboratory method of digestion followed by atomic absorption spectroscopy analysis. The elemental composition was then correlated with the LIBS spectra using projection to latent structures (PLS) models. The correlations for the different elements introduced by different treatments were very strong, with the correlation coefficients generally above 0.9. Additionally, principal component analysis (PCA) was used to differentiate the samples treated with different preservative formulations. The research has focused not only on demonstrating the application of LIBS as a tool for use in the forest products industry, but also considered sampling errors, limits of detection, reproducibility, and accuracy of measurements as they relate to multivariate analysis of this complex wood substrate

Analysis of preservative-treated wood by multivariate analysis of laser-induced breakdown spectroscopy spectra

Energy Technology Data Exchange (ETDEWEB)

Martin, Madhavi Z. [Environmental Sciences Division Oak Ridge National Laboratory, P.O. Box 2008 MS 6422, Oak Ridge TN 37831-6422 (United States); Labbe, Nicole [Forest Products Center, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996-4570 (United States)]. E-mail: nlabbe@utk.edu; Rials, Timothy G. [Forest Products Center, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996-4570 (United States); Wullschleger, Stan D. [Environmental Sciences Division Oak Ridge National Laboratory, P.O. Box 2008 MS 6422, Oak Ridge TN 37831-6422 (United States)

2005-08-31

In this work, multivariate statistical analysis (MVA) techniques are coupled with laser-induced breakdown spectroscopy (LIBS) to identify preservative types (chromated copper arsenate, ammoniacal copper zinc or alkaline copper quat), and to predict elemental content in preservative-treated wood. The elemental composition of the samples was measured with a standard laboratory method of digestion followed by atomic absorption spectroscopy analysis. The elemental composition was then correlated with the LIBS spectra using projection to latent structures (PLS) models. The correlations for the different elements introduced by different treatments were very strong, with the correlation coefficients generally above 0.9. Additionally, principal component analysis (PCA) was used to differentiate the samples treated with different preservative formulations. The research has focused not only on demonstrating the application of LIBS as a tool for use in the forest products industry, but also considered sampling errors, limits of detection, reproducibility, and accuracy of measurements as they relate to multivariate analysis of this complex wood substrate.

Possible preparation of wood-plastic materials based on unsaturated polyester resins and methyl metacrylate, by radiation and chemical methods in combination

International Nuclear Information System (INIS)

Pesek, M.

1982-01-01

The preparation of wood-plastic combinations (WPC) using combined methods for curing intermediate products and final products is described. In the first step, impregnated wood was irradiated using doses of 1 to 10 kGy in the presence of chemical initiators of polymerization. Thereafter, curing of this partly cured impregnating mixture was accomplished in the wood at elevated temperatures with the aid of chemical initiators of polymerization. Impregnation mixtures based on unsaturated polyester resins and methyl methacrylate, and the wood species European Beech (Fagus silvatica) and Black Alder (Alnus glutinosa) were used. The results indicate that this method of preparing WPC allows substantially lower radiation doses to be used, i.e., doses in the range of 1 to 2.5 kGy. These doses gelatinate the impregnation mixture in the wood so that the subsequent curing by chemical polymerization initiators proceeds without the impregnation mixture flowing out of the wood, and without forming bosses and incrustations. Intermediate products and wood products needing no further finish may thus be prepared: in some cases regrinding or repolish is sufficient. The possibility of using impregnation mixtures based on various unsaturated polyester resins was investigated, and the influence on the curing process of temperature, polymerization initiator concentration, methyl methacrylate concentration, inhibitor concentration, and other factors affecting curing was evaluated. (author)

Use of near infared spectroscopy to measure the chemical and mechanical properties of solid wood

Science.gov (United States)

Stephen S. Kelley; Timothy G. Rials; Rebecca Snell; Leslie H. Groom; Amie Sluiter

2004-01-01

Near infrared (NIR) spectroscopy (500 nm-2400 nm), coupled with multivariate analytic (MVA) statistical techniques, have been used to predict the chemical and mechanical properties of solid loblolly pine wood. The samples were selected from different radial locations and heights of three loblolly pine trees grown in Arkansas. The chemical composition and mechanical...

Use of near infrared spectroscopy to measure the chemical and mechanical properties of solid wood

Science.gov (United States)

Stephen S. Kelley; Timothy G. Rials; Rebecca Snell; Leslie H. Groom; Amie Sluiter

2004-01-01

Near infrared (NIR) spectroscopy (500 nm-2400 nm), coupled with multivariate analytic (MVA) statistical techniques, have been used to predict the chemical and mechanical properties of solid loblolly pine wood. The samples were selected from different radial locations and heights of three loblolly pine trees grown in Arkansas. The chemical composition and mechanical...

Phosphate removal by refined aspen wood fiber treated with carboxymethyl cellulose and ferrous chloride

Science.gov (United States)

Thomas L. Eberhardt; Soo-Hong Min; James S. Han

2006-01-01

Biomass-based filtration media are of interest as an economical means to remove pollutants and nutrients found in stormwater runoff. Refined aspen wood fiber samples treated with iron salt solutions demonstrated limited capacities to remove (ortho)phosphate from test solutions. To provide additional sites for iron complex formation, and thereby impart a greater...

Assessment of local wood species used for the manufacture of cookware and the perception of chemical benefits and chemical hazards associated with their use in Kumasi, Ghana

Directory of Open Access Journals (Sweden)

Mensah John Kenneth

2012-12-01

Full Text Available Abstract Background Historical proven wood species have no reported adverse health effect associated with its past use. Different historical proven species have traditionally been used to manufacture different wooden food contact items. This study uses survey questionnaires to assess suppliers’, manufacturers’, retailers’ and consumers’ (end-users’ preferences for specific wood species, to examine the considerations that inform these preferences and to investigate the extent of awareness of the chemical benefits and chemical hazards associated with wooden food contact material use. Methods Through the combined use of a cross sectional approach and a case study design, 25 suppliers, 25 manufacturers, 25 retailers and 125 consumers (end-users of wooden food contact materials in four suburbs in Kumasi Metropolitan Area (Anloga junction, Ahinsan Bus Stop, Ahwia-Pankrono and Race Course and Ashanti Akyim Agogo in the Ashanti Akyim North District of the Ashanti Region were administered with closed ended questionnaires. The questionnaires were prepared in English, but local language, Twi, was used to translate and communicate the content of the questionnaire where necessary. Results Suppliers’, manufacturers’ and retailers’ preferences for specific wood species for most wooden cookware differed from that of consumers (end-users. But all respondent groups failed to indicate any awareness of chemical benefits or chemical hazards associated with either the choice of specific wood species for specific wooden cookware or with the general use of wooden food contact materials. The lack of appreciation of chemical benefits or hazards associated with active principles of wooden cookware led to heavy reliance of consumers (end-users on the wood density, price, attractive grain pattern and colour or on the judgement of retailers in their choice of specific species for a wooden cookware. Conclusion This study contributes some practical suggestions

A Tool for Estimating Variability in Wood Preservative Treatment Retention

Science.gov (United States)

Patricia K. Lebow; Adam M. Taylor; Timothy M. Young

2015-01-01

Composite sampling is standard practice for evaluation of preservative retention levels in preservative-treated wood. Current protocols provide an average retention value but no estimate of uncertainty. Here we describe a statistical method for calculating uncertainty estimates using the standard sampling regime with minimal additional chemical analysis. This tool can...

Combustion Characteristics of Impregnated and Surface-treated Chestnut (Castanea sativa Mill. Wood Left Outdoors for One Year

Directory of Open Access Journals (Sweden)

Muhammed Said Fidan

2016-01-01

Full Text Available Treating wood with impregnating materials in order to improve resistance to burning is a commonly employed safety measure. In this study, chestnut (Castanea sativa Mill. wood samples were impregnated using either Tanalith-E or Wolmanit-CB according to ASTM-D 1413-76 and surface-treated using water-based or synthetic varnish according to ASTM-D 3023. These samples were used to investigate the combustion characteristics of samples left outdoors for one year as detailed in ASTM-E 160-50. The combustion temperatures of the samples left outdoors were similar upon impregnation with either Tanalith-E or Wolmanit-CB. However, the combustion temperature of the samples treated with synthetic varnish was lower than those that were treated with water-based varnish. The time to collapse and the total duration of combustion of the samples left outdoors were shorter for those impregnated with Wolmanit-CB. Weight loss of the samples left outdoors was higher for those that were impregnated with Tanalith-E and treated with water-based varnish. Gas analysis of the samples that were left outdoors indicated that the O2 content of flue gas from samples that were impregnated with Wolmanit-CB and treated with synthetic varnish was high and the CO content of flue gas from the same samples was low.

Robust and Low-Cost Flame-Treated Wood for High-Performance Solar Steam Generation.

Science.gov (United States)

Xue, Guobin; Liu, Kang; Chen, Qian; Yang, Peihua; Li, Jia; Ding, Tianpeng; Duan, Jiangjiang; Qi, Bei; Zhou, Jun

2017-05-03

Solar-enabled steam generation has attracted increasing interest in recent years because of its potential applications in power generation, desalination, and wastewater treatment, among others. Recent studies have reported many strategies for promoting the efficiency of steam generation by employing absorbers based on carbon materials or plasmonic metal nanoparticles with well-defined pores. In this work, we report that natural wood can be utilized as an ideal solar absorber after a simple flame treatment. With ultrahigh solar absorbance (∼99%), low thermal conductivity (0.33 W m -1 K -1 ), and good hydrophilicity, the flame-treated wood can localize the solar heating at the evaporation surface and enable a solar-thermal efficiency of ∼72% under a solar intensity of 1 kW m -2 , and it thus represents a renewable, scalable, low-cost, and robust material for solar steam applications.

Influence of wood-derived biochar on the physico-mechanical and chemical characteristics of agricultural soils

Science.gov (United States)

Ahmed, Ahmed S. F.; Raghavan, Vijaya

2018-01-01

Amendment of soil with biochar has been shown to enhance fertility and increase crop productivity, but the specific influence of biochar on soil workability remains unclear. Select physico-mechanical and chemical properties of clay loam and sandy loam soils were measured after amendment with wood-derived biochar of two particle size ranges (0.5-425 and 425-850 µm) at five dosages ranging from 0.5 to 10% dry weight. Whereas the clay loam soil workability decreased when the finer wood-derived biochar was applied at rates of 6 or 10%, soil fertility was not enhanced. The sandy loam soil, due to Proctor compaction, significantly decreased in bulk density with 6 and 10% wood-derived biochar amendments indicating higher soil resistance to compaction.

Long term durability of wood-plastic composites made with chemically modified wood

Science.gov (United States)

Rebecca E. Ibach; Craig M. Clemons

2017-01-01

Wood-plastic composites (WPCs) have slower moisture sorption than solid wood, but over time moisture can impact the strength, stiffness, and decay of the composite. These changes will become increasingly important if WPCs are used in more challenging environments such as in ground-contact applications. There are several options for mitigating the moisture sorption of...

Penetration and Effectiveness of Micronized Copper in Refractory Wood Species.

Science.gov (United States)

Civardi, Chiara; Van den Bulcke, Jan; Schubert, Mark; Michel, Elisabeth; Butron, Maria Isabel; Boone, Matthieu N; Dierick, Manuel; Van Acker, Joris; Wick, Peter; Schwarze, Francis W M R

2016-01-01

The North American wood decking market mostly relies on easily treatable Southern yellow pine (SYP), which is being impregnated with micronized copper (MC) wood preservatives since 2006. These formulations are composed of copper (Cu) carbonate particles (CuCO3·Cu(OH)2), with sizes ranging from 1 nm to 250 μm, according to manufacturers. MC-treated SYP wood is protected against decay by solubilized Cu2+ ions and unreacted CuCO3·Cu(OH)2 particles that successively release Cu2+ ions (reservoir effect). The wood species used for the European wood decking market differ from the North American SYP. One of the most common species is Norway spruce wood, which is poorly treatable i.e. refractory due to the anatomical properties, like pore size and structure, and chemical composition, like pit membrane components or presence of wood extractives. Therefore, MC formulations may not suitable for refractory wood species common in the European market, despite their good performance in SYP. We evaluated the penetration effectiveness of MC azole (MCA) in easily treatable Scots pine and in refractory Norway spruce wood. We assessed the effectiveness against the Cu-tolerant wood-destroying fungus Rhodonia placenta. Our findings show that MCA cannot easily penetrate refractory wood species and could not confirm the presence of a reservoir effect.

Exposure assessment of residents living near a wood treatment plant

International Nuclear Information System (INIS)

Dahlgren, James; Warshaw, Raphael; Horsak, Randy D.; Parker, Frank M. III; Takhar, Harpreet

2003-01-01

We report the results of environmental sampling and modeling in a neighborhood adjacent to a wood processing plant. This plant used creosote and pentachlorophenol (PCP) to treat wood for over 70 years. Between 1999 and 2001, environmental samples were obtained to quantify the level of environmental contamination from the wood processing plant. Blood from 10 residents was measured for chlorinated dioxins and dibenzofurans. Soil sediment samples from drainage ditches and attic/dust samples from nearby residents' homes were tested for polychlorinated dioxins, furans, and polycyclic aromatic hydrocarbons (PAH). The dioxin congeners analysis of the 10 residents revealed elevated valued for octachlorodibenzo-p-dioxin and heptachlorodibenzo-p-dioxin compatible with PCP as the source. The levels of carcinogenic PAHs were higher than background levels and were similar to soil contamination on wood preserving sites. Wipe sampling in the kitchens of 11 homes revealed that 20 of the 33 samples were positive for octachlorinated dioxins with a mean value of 10.27 ng/m 2 . The soil, ditch samples, and positive wipe samples from the homes indicate a possible ongoing route of exposure to the contaminants in the homes of these residents. Modeled air exposure estimated for the wood processing waste chemicals indicate some air exposure to combustion products. The estimated air levels for benzo(a)pyrene and tetrachlorodibenzodiozin in this neighborhood exceeded the recommended levels for these compounds in some states. The quantitative data presented suggest a significant contamination of a neighborhood by wood processing waste chemicals. These findings suggest the need for more stringent regulations on waste discharges from wood treatment plants

Resistance of borax–copper treated wood in aboveground exposure to attack by Formosan subterranean termites

Science.gov (United States)

Stan Lebow; Bessie Woodward; Douglas Crawford; William Abbott

2005-01-01

The spread of Formosan subterranean termites (FSTs) in the southern United States has increased public interest in finding a preservative treatment to protect framing lumber from termite attack. This study evaluated the use of a borax-based preservative to protect wood from FST attack. Southern Pine and Douglas-fir specimens were pressure-treated with three...

Isolation and characterization of mold fungi and insects infecting sawmill wood, and their inhibition by gamma radiation

Science.gov (United States)

Kalawate, Aparna; Mehetre, Sayaji

2015-12-01

This article describes the isolation, identification, and characterization of wood-rotting fungi and insects, and their inhibition was studied using gamma radiation. Products manufactured from plantation timber species are deteriorated by wood-rotting fungi such as Hypocrea lixii, Fusarium proliferatum, and Aspergillus flavus, and insects such as powderpost beetles. Proper preservation methods are necessary for ensuring a long service life of wood products. In this study, wood samples were treated with 2.5% copper ethanolamine boron (CEB) (10% w/v) and subsequently irradiated with gamma rays (10 kGy). It was observed that CEB-treated and gamma-irradiated samples controlled fungi and powderpost beetles significantly. As wood is a dead organic material, penetration of chemicals into it is very difficult. Gamma rays easily pass through wooden objects with hidden eggs and dormant spores of insects and fungi, respectively. Gamma irradiation was proved very effective in reducing damage caused by both fungi and insects.

CREEP BEHAVIOR OF BORATE-TREATED STRANDBOARD: EFFECT OF ZINC BORATE RETENTION, WOOD SPECIES, AND LOAD LEVEL

OpenAIRE

Wu,Qinglin; Lee,Ong N; Cai,Zhiyong; Zhou,Dingguo

2009-01-01

Creep performance of zinc borate-treated strandboard from southern pine (Pinus taeda L.) and red oak (Quercus falcata) was investigated at 25(0)C temperature and 65% relative humidity. It was shown that the borate treatment had some significant effect on creep deflection of the test panels, and the effect varied with wood species. There was no significant effect of creep loading on residual bending properties of treated strandboard under the stress levels used. The four element spring-dashpot...

Adhesive interactions with wood

Science.gov (United States)

Charles R. Frihart

2004-01-01

While the chemistry for the polymerization of wood adhesives has been studied systematically and extensively, the critical aspects of the interaction of adhesives with wood are less clearly understood. General theories of bond formation need to be modified to take into account the porosity of wood and the ability of chemicals to be absorbed into the cell wall....

The Effect of Heat Treatment on the chemical and color change of Black Locust (Robinia Pseudoacacia) wood flour

Science.gov (United States)

Yao Chen; Yongming Fan; Jianmin Gao; Nicole M. Stark

2012-01-01

The aim of this study was to investigate the effects of oxygen and moisture content (MC) on the chemical and color changes of black locust (Robinia pseudoacacia) wood during heat treatment. The wood flour was conditioned to different initial MCs and heated for 24 h at a constant temperature of 120°C in either oxygen or nitrogen atmosphere. The pH values and...

The role of natural wood constituents on the anaerobic treatability of forest industry wastewaters

NARCIS (Netherlands)

Sierra - Alvarez, R.

1990-01-01

Anaerobic treatment has been shown to be an efficient and energy conserving method for treating various types of readily biodegradable non-inhibitory forest industry wastewaters. However, the high toxicity of paper mill effluents derived from chemical wood processing operations has hampered

Content of Chemical Elements in Wood-Destroying Fungi

Directory of Open Access Journals (Sweden)

Strapáč I.

2016-12-01

Full Text Available The aim of this study was to examine the content of chemical elements in the dried fruiting bodies of edible wood decaying fungi such as Honey mushrooms (Armillaria mellea, Shiitakes (Lentinus edodes and Oyster mushrooms (Pleurotus ostreatus. Powdered samples of fungi were mineralized in a microwave digestion. Twenty-one (21 chemical elements were detected in the plasma of the device ICP-MS AGILENT 7500c by accredited methods with the aid of calibration curves. The content of individual elements varied within a considerable range. The highest contents of K, Mn, Cu and Cd were found in the fruiting bodies of Honey mushrooms (Armillaria mellea. Shiitakes (Lentinus edodes had the highest content of B and Mo. Significant differences were found in the content of elements in the Oyster mushrooms (Pleurotus ostreatus from Slovakia, Hungary and China. The highest content of Al was found in the Oyster mushrooms (Pleurotus ostreatus from Hungary. The Chinese oysters had a maximum contents of Ca, Mg, Co, Pb, As and U. The Oyster mushrooms (Pleurotus ostreatus from Lemešany (Slovakia had the highest contents of Na, Zn, Fe, Se, Ag, Hg and Cr. The difference of chemical element content could be influenced by the genotype of the fungus and by the composition of substrate on which mushroom grow up.

Wood hydrolyzate treatments for improved fermentation of wood sugars to 2,3-butanediol

Energy Technology Data Exchange (ETDEWEB)

Frazer, F.R.; McCaskey, T.A.

1989-01-01

Acid-hydrolyzed hardwood contains compounds inhibitory to micro-organisms that convert wood sugars to fermentation products such as fuels and chemicals. Several methods of treating acid-hydrolyzed hardwood (hydrolyzate) to reduce the levels of potential microbial inhibitors (acetate, furfural, sulfate, and phenolics) were evaluated. The methods evaluated were precipitation with calcium hydroxide, extraction with organic solvents, treatment with ion-exchange resins, adsorption resins, and activated charcoal. Treatment of the hydrolyzate with an anion exchange resin (Amberlite IRA-400) was the most effective method for removing potential inhibitors. Non-treatment hydrolyzate adjusted to pH 6 inhibited growth of a 2,3-butanediol-producing culture of Klebsiella pneumoniae. However, hydrolyzate treated with Amberlite IRA-400 was not inhibitory and resulted in yields of 2,3-butanediol that were greater than 90% of theoretical. (author).

How to decrease the hydrophilicity of wood flour to process efficient composite materials

Energy Technology Data Exchange (ETDEWEB)

Pouzet, M.; Gautier, D.; Charlet, K. [Institut Pascal, UMR 6602 UBP/CNRS/IFMA, BP 265, Aubière 63175 (France); Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, Clermont-Ferrand 63000 (France); CNRS, UMR 6296, Institut de Chimie de Clermont-Ferrand, Aubière 63177 (France); Dubois, M., E-mail: Marc.DUBOIS@univ-bpclermont.fr [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, Clermont-Ferrand 63000 (France); CNRS, UMR 6296, Institut de Chimie de Clermont-Ferrand, Aubière 63177 (France); Béakou, A. [Institut Pascal, UMR 6602 UBP/CNRS/IFMA, BP 265, Aubière 63175 (France)

2015-10-30

Graphical abstract: Evolution of the contact angle of a water drop on sample (θ{sub c}) according to the fluorinated material. - Highlights: • Fluorination was applied to wood flour. • Covalent attachment of fluorine atoms onto wood surface decreases its hydrophilicity. • Fluorinated wood flour was added into composites with polyester. • Fluorination enhances the interface between wood flour and polymer matrix. - Abstract: Dynamic fluorination and static fluorination were applied to wood flour to decrease its hydrophilic character, aiming at processing wood-polymer composites with good properties. Fourier-Transform infrared spectra and {sup 19}F solid state NMR (Nuclear Magnetic Resonance) results proved the successful covalent bonding of fluorine atoms onto the wood's chemical structure. It revealed that static fluorination brings about a less damaged and less hydrophilic fluorinated wood than with dynamic fluorination. Composites manufactured from this fluorinated wood presented a hydrophobic character directly related to the hydrophicity of these wood reinforcements. A composite made with fluorinated wood and polyester exhibited a higher hydrophobicity than the neat polyester and than the composite made with non-treated wood. Moreover, the further fluorination of a composite made of fluorinated wood led to a contact angle comparable to that of some metals (steel, gold) due to the etching of the composite surface during fluorination.

Fast pyrolysis of creosote treated wood ties in a fluidized bed reactor and analytical characterization of product fractions

International Nuclear Information System (INIS)

Jung, Su-Hwa; Koo, Won-Mo; Kim, Joo-Sik

2013-01-01

A fraction of creosote treated wood ties was pyrolyzed in a pyrolysis plant equipped with a fluidized bed reactor and char-separation system at different temperatures. Analyses of each pyrolysis product, especially the oil, were carried out using a variety of analytical tools. The maximum oil yield was obtained at 458 °C with a value of 69.3 wt%. Oils obtained were easily separated into two phases, a creosote-derived fraction (CDF) and a wood-derived fraction (WDF). Major compounds of the WDF were acetic acid, furfural and levoglucosan, while the CDF was mainly composed of polycyclic aromatic hydrocarbons (PAHs), such as 1-methylnaphthalene, biphenyl, acenaphthene, dibenzofuran, fluorene, phenanthrene, anthracene, fluoranthene and pyrene. HPLC analysis showed that the concentration of PAHs of the CDF obtained at 458 °C constituted about 22.5 wt% of the oil. - Highlights: • Creosote treated wood ties was stably pyrolyzed in a fluidized bed reactor. • Pyrolysis oil contained extremely low metal content due to the char removal system. • Bio-oil components was quantitatively analyzed by relative response factor. • Creosote-derived pyrolysis oil fraction was composed of PHAs and has a high caloric value (39 MJ/kg)

Neutron Scattering Studies of Nano-Scale Wood-Water Interactions

Science.gov (United States)

Plaza Rodriguez, Nayomi Z.

modifications, namely, adhesive infiltration and acetylation, on the wood nanostructure as well as its moisture-induced swelling. Tangential-longitudinal latewood loblolly pine 0.5 mm thick sections were acetylated or treated with an adhesive (Phenol-formaldehyde (PF) or polymeric methylene diisocyanate (pMDI)) using deuterated or hydrogenated chemicals. Contrast variation experiments on wood modified with deuterated chemicals revealed that PF can infiltrate the regions between the elementary fibrils, while acetylation does not. The moisture-induced swelling of the chemically modified wood was studied, by studying the samples modified with hydrogenated chemicals using SANS and the previously built humidity chamber. These studies revealed that while both PF and pMDI can infiltrate the microfibrils, only PF reduced significantly the swelling at both the elementary fibril and bulk levels. In acetylated samples, the elementary fibril spacing was proportional to the moisture-content of the sample, which was reduced with increasing acetylation. This suggested that the acetylation treatment did not reduce the swelling at the elementary fibril but prevented water from entering the microfibril by modifying the regions surrounding the elementary fibrils. Using quasi-elastic neutron scattering (QENS) and a custom-built in situ relative humidity sample environment I measured experimentally the (5 - 400 ps) water dynamics inside wood cell walls for the first time and found that there are two types of bound water in the cell wall, namely, slow and fast water. The motion of both water types is well described by a jump-diffusion model, which corresponds to water molecules whose movement follows a stop and go process. Here, the slow water corresponds to water molecules that are highly associated to the wood polymers, whereas the fast water corresponds to water confined inside nanopores within the wood cell wall.

Iron Stain on Wood

Science.gov (United States)

Mark Knaebe

2013-01-01

Iron stain, an unsightly blue–black or gray discoloration, can occur on nearly all woods. Oak, redwood, cypress, and cedar are particularly prone to iron stain because these woods contain large amounts of tannin-like extractives. The discoloration is caused by a chemical reaction between extractives in the wood and iron in steel products, such as nails, screws, and...

Integrated control of wood destroying basidiomycetes combining Cu-based wood preservatives and Trichoderma spp.

Science.gov (United States)

Ribera, Javier; Fink, Siegfried; Bas, Maria Del Carmen; Schwarze, Francis W M R

2017-01-01

The production of new generation of wood preservatives (without addition of a co-biocide) in combination with an exchange of wood poles on identical sites with high fungal inoculum, has resulted in an increase of premature failures of wood utility poles in the last decades. Wood destroying basidiomycetes inhabiting sites where poles have been installed, have developed resistance against wood preservatives. The objective of the in vitro studies was to identify a Trichoderma spp. with a highly antagonistic potential against wood destroying basidiomycetes that is capable of colonizing Cu-rich environments. For this purpose, the activity of five Trichoderma spp. on Cu-rich medium was evaluated according to its growth and sporulation rates. The influence of the selected Trichoderma spp. on wood colonization and degradation by five wood destroying basidiomycetes was quantitatively analyzed by means of dry weight loss of wood specimens. Furthermore, the preventative effect of the selected Trichoderma spp. in combination with four Cu-based preservatives was also examined by mass loss and histological changes in the wood specimens. Trichoderma harzianum (T-720) was considered the biocontrol agent with higher antagonistic potential to colonize Cu-rich environments (up to 0.1% CuSO4 amended medium). T. harzianum demonstrated significant preventative effect on wood specimens against four wood destroying basidiomycetes. The combined effect of T. harzianum and Cu-based wood preservatives demonstrated that after 9 months incubation with two wood destroying basidiomycetes, wood specimens treated with 3.8 kg m-3 copper-chromium had weight losses between 55-65%, whereas containers previously treated with T. harzianum had significantly lower weight losses (0-25%). Histological studies on one of the wood destroying basidiomycetes revealed typical decomposition of wood cells by brown-rot fungi in Cu-impregnated samples, that were notably absent in wood specimens previously exposed to T

Integrated control of wood destroying basidiomycetes combining Cu-based wood preservatives and Trichoderma spp.

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Javier Ribera

Full Text Available The production of new generation of wood preservatives (without addition of a co-biocide in combination with an exchange of wood poles on identical sites with high fungal inoculum, has resulted in an increase of premature failures of wood utility poles in the last decades. Wood destroying basidiomycetes inhabiting sites where poles have been installed, have developed resistance against wood preservatives. The objective of the in vitro studies was to identify a Trichoderma spp. with a highly antagonistic potential against wood destroying basidiomycetes that is capable of colonizing Cu-rich environments. For this purpose, the activity of five Trichoderma spp. on Cu-rich medium was evaluated according to its growth and sporulation rates. The influence of the selected Trichoderma spp. on wood colonization and degradation by five wood destroying basidiomycetes was quantitatively analyzed by means of dry weight loss of wood specimens. Furthermore, the preventative effect of the selected Trichoderma spp. in combination with four Cu-based preservatives was also examined by mass loss and histological changes in the wood specimens. Trichoderma harzianum (T-720 was considered the biocontrol agent with higher antagonistic potential to colonize Cu-rich environments (up to 0.1% CuSO4 amended medium. T. harzianum demonstrated significant preventative effect on wood specimens against four wood destroying basidiomycetes. The combined effect of T. harzianum and Cu-based wood preservatives demonstrated that after 9 months incubation with two wood destroying basidiomycetes, wood specimens treated with 3.8 kg m-3 copper-chromium had weight losses between 55-65%, whereas containers previously treated with T. harzianum had significantly lower weight losses (0-25%. Histological studies on one of the wood destroying basidiomycetes revealed typical decomposition of wood cells by brown-rot fungi in Cu-impregnated samples, that were notably absent in wood specimens

Corrosão de parafusos fixados à madeira tratada com soluções de creosoto vegetal Corrosion of screws fixed into wood treated with wood tar creosote solutions

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Juarez Benigno Paes

2002-05-01

Full Text Available O objetivo desta pesquisa foi avaliar a corrosão de parafusos auto-rosqueáveis fixados à madeira tratada com soluções preservativas preparadas com creosoto vegetal, em condições de campo. Obteve-se o creosoto vegetal bruto por meio da destilação à temperatura de 110 - 255ºC do alcatrão vegetal. Uma fração dos destilados foi lavada com solução a 9% de bicarbonato de sódio, obtendo-se o creosoto vegetal purificado. Ambas as frações foram enriquecidas com 3% de naftenato de cobre; 3% de naftenato de zinco; 3% naftenato de cobalto; 2% de TBTO; 2% de tribromofenato de tubutil-estanho; 2% de pentaclorofenol; ou 0,4% de trióxido de arsênico. Foram preparadas 16 soluções, sendo 14 enriquecidas, além do creosoto vegetal bruto e do creosoto vegetal purificado. Estacas confeccionadas com madeira de alburno de Eucalyptus grandis foram tratadas pelo processo de célula- cheia (processo Bethell. Após o tratamento, parafusos auto-rosquéaveis de ferro zincado foram fixados às estacas. O ensaio foi instalado em três localidades da Zona da Mata de Minas Gerais (Viçosa, Ponte Nova e Leopoldina. A corrosividade das soluções de creosoto vegetal foi comparada à causada pelo creosoto mineral. As soluções preparadas com creosoto vegetal purificado foram menos corrosivas que suas similares preparadas com creosoto vegetal bruto, assemelhando-se ao creosoto mineral.The objective of this research was to evaluate the corrosion of screws fixed into wood treated with preservative solutions of wood tar creosote. The crude wood tar creosote was obtained through distillation of wood tar at 110 - 255ºC. A fraction of this product was washed with a solution of sodium bicarbonate at 9%, resulting in purified wood tar creosote. Both fractions were enriched with 3% of copper naphtenate, 3% of zinc naphtenate, 3% of cobalt naphtenate, 2% of TBTO, 2% of tributhyl-tin tribromophenate, 2% of pentachlorophenol, or with 0.4% of arsenic trioxide. A total

Chemical composition and speciation of particulate organic matter from modern residential small-scale wood combustion appliances.

Science.gov (United States)

Czech, Hendryk; Miersch, Toni; Orasche, Jürgen; Abbaszade, Gülcin; Sippula, Olli; Tissari, Jarkko; Michalke, Bernhard; Schnelle-Kreis, Jürgen; Streibel, Thorsten; Jokiniemi, Jorma; Zimmermann, Ralf

2018-01-15

Combustion technologies of small-scale wood combustion appliances are continuously developed decrease emissions of various pollutants and increase energy conversion. One strategy to reduce emissions is the implementation of air staging technology in secondary air supply, which became an established technique for modern wood combustion appliances. On that account, emissions from a modern masonry heater fuelled with three types of common logwood (beech, birch and spruce) and a modern pellet boiler fuelled with commercial softwood pellets were investigated, which refer to representative combustion appliances in northern Europe In particular, emphasis was put on the organic constituents of PM2.5, including polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs) and phenolic species, by targeted and non-targeted mass spectrometric analysis techniques. Compared to conventional wood stoves and pellet boilers, organic emissions from the modern appliances were reduced by at least one order of magnitude, but to a different extent for single species. Hence, characteristic ratios of emission constituents and emission profiles for wood combustion identification and speciation do not hold for this type of advanced combustion technology. Additionally, an overall substantial reduction of typical wood combustion markers, such as phenolic species and anhydrous sugars, were observed. Finally, it was found that slow ignition of log woods changes the distribution of characteristic resin acids and phytosterols as well as their thermal alteration products, which are used as markers for specific wood types. Our results should be considered for wood combustion identification in positive matrix factorisation or chemical mass balance in northern Europe. Copyright © 2017 Elsevier B.V. All rights reserved.

Effects of copper amine treatments on mechanical, biological and surface/interphase properties of poly (vinyl chloride)/wood composites

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Jiang, Haihong

2005-11-01

The copper ethanolamine (CuEA) complex was used as a wood surface modifier and a coupling agent for wood-PVC composites. Mechanical properties of composites, such as unnotched impact strength, flexural strength and flexural toughness, were significantly increased, and fungal decay weight loss was dramatically decreased by wood surface copper amine treatments. It is evident that copper amine was a very effective coupling agent and decay inhibitor for PVC/wood flour composites, especially in high wood flour loading level. A DSC study showed that the heat capacity differences (DeltaCp) of composites before and after PVC glass transition were reduced by adding wood particles. A DMA study revealed that the movements of PVC chain segments during glass transition were limited and obstructed by the presence of wood molecule chains. This restriction effect became stronger by increasing wood flour content and by using Cu-treated wood flour. Wood flour particles acted as "physical cross-linking points" inside the PVC matrix, resulting in the absence of the rubbery plateau of PVC and higher E', E'' above Tg, and smaller tan delta peaks. Enhanced mechanical performances were attributed to the improved wetting condition between PVC melts and wood surfaces, and the formation of a stronger interphase strengthened by chemical interactions between Cu-treated wood flour and the PVC matrix. Contact angles of PVC solution drops on Cu-treated wood surfaces were decreased dramatically compared to those on the untreated surfaces. Acid-base (polar), gammaAB, electron-acceptor (acid) (gamma +), electron-donor (base) (gamma-) surface energy components and the total surface energies increased after wood surface Cu-treatments, indicating a strong tendency toward acid-base or polar interactions. Improved interphase and interfacial adhesion were further confirmed by measuring interfacial shear strength between wood and the PVC matrix.

Formation of metal agglomerates during carbonisation of chromated copper arsenate (CCA) treated wood waste: Comparison between a lab scale and an industrial plant

Energy Technology Data Exchange (ETDEWEB)

Helsen, Lieve [Katholieke Universiteit Leuven, Department of Mechanical Engineering, Division of Applied Mechanics and Energy Conversion, Celestijnenlaan 300A, B-3001 Leuven (Heverlee) (Belgium)]. E-mail: lieve.helsen@mech.kuleuven.be; Hacala, Amelie [Company Thermya, 1 rue Nicolas Appert, 33140 Villenave d' Ornon (France)]. E-mail: hacala@thermya.com

2006-10-11

This paper compares the results obtained by scanning electron microscopy coupled to X-ray analysis (SEM-EDXA) of the solid product after carbonisation of treated wood waste in a lab scale and in an industrial installation. These setups (lab scale and industrial) are characterized by different operating conditions of the carbonisation process. Moreover, the wood waste input to the processes differs significantly. From this study, it is clear that some similarities but also some differences exist between the lab scale study and the study with the industrial Chartherm plant. In both reactors, a metal (and mineral) agglomeration process takes place, even in the case of untreated wood. The agglomerates initially present in the wood input may serve as a seed for the metal agglomeration process during 'chartherisation'. The industrial setup leads to a broader range of agglomerates' size (0.1-50 {mu}m) and composition (all possible combinations of Cu, Cr, As and wood minerals). Some agglomerates contain the three metals but the major part is a combination of wood minerals and one or two of the three preservative metals, while all agglomerates analysed in the lab scale product contain the three metals. The separate influence of wood input characteristics and process conditions cannot be derived from these experiments, but the observations suggest that the higher the CCA retention in the wood input is, the easier is the metal agglomeration process during chartherisation of CCA treated wood waste. From the analyses performed in this study it seems that copper behaves differently in the sense that it agglomerates easily, but the resulting particles are small (<1 {mu}m)

Formation of metal agglomerates during carbonisation of chromated copper arsenate (CCA) treated wood waste: Comparison between a lab scale and an industrial plant

International Nuclear Information System (INIS)

Helsen, Lieve; Hacala, Amelie

2006-01-01

This paper compares the results obtained by scanning electron microscopy coupled to X-ray analysis (SEM-EDXA) of the solid product after carbonisation of treated wood waste in a lab scale and in an industrial installation. These setups (lab scale and industrial) are characterized by different operating conditions of the carbonisation process. Moreover, the wood waste input to the processes differs significantly. From this study, it is clear that some similarities but also some differences exist between the lab scale study and the study with the industrial Chartherm plant. In both reactors, a metal (and mineral) agglomeration process takes place, even in the case of untreated wood. The agglomerates initially present in the wood input may serve as a seed for the metal agglomeration process during 'chartherisation'. The industrial setup leads to a broader range of agglomerates' size (0.1-50 μm) and composition (all possible combinations of Cu, Cr, As and wood minerals). Some agglomerates contain the three metals but the major part is a combination of wood minerals and one or two of the three preservative metals, while all agglomerates analysed in the lab scale product contain the three metals. The separate influence of wood input characteristics and process conditions cannot be derived from these experiments, but the observations suggest that the higher the CCA retention in the wood input is, the easier is the metal agglomeration process during chartherisation of CCA treated wood waste. From the analyses performed in this study it seems that copper behaves differently in the sense that it agglomerates easily, but the resulting particles are small (<1 μm)

A new shock wave assisted wood preservative injection system

Science.gov (United States)

Rao, K. S.; Ravikumar, G.; Lai, Ram; Jagadeesh, G.

Preservative treatment of many tropical hard woods and bamboo pose severe problem. A number of wood preservatives (chemical formulations toxic to wood decay/ destroying organisms like fungi, wood destroying termites, marine borers etc.) and wood impregnating techniques are currently in use for improving bio resistance of timber and bamboo and thereby enhancing service life for different end uses. How ever, some species of tropical hardwoods and many species of bamboo are difficult to treat, posing technical problems. In this paper we report preliminary results of treatment of bamboo with a novel Shockwave assisted injection treatment. Samples (30×2.5×1.00 cm) of an Indian species of bamboo Dendrocalamus strictus prepared from defect free culms of dry bamboo are placed in the driven section of a vertical shock tube filled with the 4Coppepr-Chrome-Arsenic(CCA) preservative solution.The bamboo samples are subjected to repeated shock wave loading (3 shots) with typical over pressures of 30 bar. The results from the study indicate excellent penetration and retention of CCA preservative in bamboo samples. The method itself is much faster compared to the conventional methods like pressure treatment or hot and cold process.

Competitive outcomes between wood-decaying fungi are altered in burnt wood.

Science.gov (United States)

Edman, Mattias; Eriksson, Anna-Maria

2016-06-01

Fire is an important disturbance agent in boreal forests where it creates a wide variety of charred and other types of heat-modified dead wood substrates, yet how these substrates affect fungal community structure and development within wood is poorly understood. We allowed six species of wood-decaying basidiomycetes to compete in pairs in wood-discs that were experimentally burnt before fungal inoculation. The outcomes of interactions in burnt wood differed from those in unburnt control wood for two species:Antrodia sinuosanever lost on burnt wood and won over its competitor in 67% of the trials compared to 40% losses and 20% wins on unburnt wood. In contrast, Ischnoderma benzoinumwon all interactions on unburnt wood compared to 33% on burnt wood. However, the responses differed depending on the identity of the competing species, suggesting an interaction between competitor and substrate type. The observed shift in competitive balance between fungal species probably results from chemical changes in burnt wood, but the underlying mechanism needs further investigation. Nevertheless, the results indicate that forest fires indirectly structure fungal communities by modifying dead wood, and highlight the importance of fire-affected dead wood substrates in boreal forests. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Wood ash to treat sewage sludge for agricultural use

Energy Technology Data Exchange (ETDEWEB)

White, R.K. [Clemson Univ., SC (United States)

1993-12-31

About 90% of the three million tons of wood ash generated in the United States from wood burning facilities is being landfilled. Many landfills are initiated tipping fees and/or restrictions on the disposal of special wastes such as ash. The purpose of this work was to evaluate (1) the feasibility of using wood ash to stabilize sewage sludge and (2) the fertilizer and liming value of the sludge/ash mixture on plant response and soil pH. Research showed that wood ash, when mixed with sludge, will produce a pH above 12.0, which meets US EPA criteria for pathogen reduction for land application on non-direct food chain crops. Different ratios of wood ash to sludge mixtures were tested and the 1:1 ratio (by weight) was found to be optimal. Five replications of wood ash from four sources were tested for moisture content, pH and fertilizer nutrients. The pH of the ash/sludge mixture (1:1) on day one ranged from 12.4 to 13.2. In most cases the pH remained the same over a 21 day test or only dropped 0.1 to 0.3 units. Analyses of the mixtures showed that heavy metal concentrations (As, B, Cd, Co, Cr, Cu, Mn, Mo, Ni, Pb, S, Se, Zn) were low. The 1:1 ash/sludge mixture had a calcium carbonate equivalency of 17%. Green house pot studies using tall fescue grass were loadings of 300 to 750 pounds per acre of TKN-N than for 500 lb/acre of 10-10-10 commercial fertilizer. Plant tissue analysis showed N, P, K, Ca, and Mg levels to be within the sufficiency range for tall fescue.

Not just lumber--Using wood in the sustainable future of materials, chemicals, and fuels

Science.gov (United States)

Joseph E. Jakes; Xavier Arzola; Richard Bergman; Peter Ciesielski; Christopher G. Hunt; Nima Rahbar; Mandla Tshabalala; Alex C. Wiedenhoeft; Samuel L. Zelinka

2016-01-01

Forest-derived biomaterials can play an integral role in a sustainable and renewable future. Research across a range of disciplines is required to develop the knowledge necessary to overcome the challenges of incorporating more renewable forest resources in materials, chemicals, and fuels. We focus on wood specifically because in our view, better characterization of...

EFFECTS OF SOME BORON COMPOUNDS ON THE LEACHABILITY OF EUCALYPTUS (Eucalyptus camaldulensis Dehn. WOOD

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Hüseyin Tan

2003-04-01

Full Text Available Wood preservation effectiveness of boron compounds against biological damagers and fire is well known. But these compounds are not widely used in preservation of wood because of their leachability from wood by rain water and making wood more hyroscopic than untreated wood in damp environments. Main aim of this study is; therefore, to improve the undesired leachability properties of some boron compounds by various water repellents (WRs. Aqueous solutions with polyethyleneglycole (PEG-400 of boric acid and sodium perborate were chosen as boron compounds. WRs were used as secondary treatment chemicals which were considered as dimensional stabilizer of wood and phsical bariers of boron retained at innerparts of treated wood. Results indicated that WRs were reduced leachability of boron from wood significantly (P<0.05. Boron salts applied with. PEG were more leachable than were of equeous solutions. WRs were not found effective on reducing the leachability of boron solved in PEG. Longer leaching time caused more leachant and reduction the phsical alleviation of WRs on boron leaching.

Weatherability and Leach Resistance of Wood Impregnated with Nano-Zinc Oxide

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Nami Kartal S

2010-01-01

Full Text Available Abstract Southern pine specimens vacuum-treated with nano-zinc oxide (nano-ZnO dispersions were evaluated for leach resistance and UV protection. Virtually, no leaching occurred in any of the nano-ZnO–treated specimens in a laboratory leach test, even at the highest retention of 13 kg/m3. However, specimens treated with high concentrations of nano-ZnO showed 58–65% chemical depletion after 12 months of outdoor exposure. Protection from UV damage after 12 months exposure is visibly obvious on both exposed and unexposed surfaces compared to untreated controls. Graying was markedly diminished, although checking occurred in all specimens. Nano-zinc oxide treatment at a concentration of 2.5% or greater provided substantial resistance to water absorption following 12 months of outdoor exposure compared to untreated and unweathered southern pine. We conclude that nano-zinc oxide can be utilized in new wood preservative formulations to impart resistance to leaching, water absorption and UV damage of wood.

Wood frame systems for wood homes

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Julio Cesar Molina

2010-12-01

Full Text Available The use of constructive systems that combine strength, speed, with competitive differential techniques and mainly, compromising with the environment, is becoming more popular in Brazil. The constructive system in wood frame for houses of up to five stories is very interesting, because it is a light system, structured in reforested treated wood which allows the combination of several materials, besides allowing speed in the construction and total control of the expenses already in the project phase for being industrialized. The structural behavior of the wood frame is superior to the structural masonry in strength, thermal and acoustic comfort. However, in Brazil, the wood frame is still little known and used, due to lack of technical knowledge about the system, prejudice associated the bad use of the wood as construction material, or still, in some cases, lack of normalization. The aim of this manuscript consists of presenting the main technical characteristics and advantages of the constructive system in wood frame homes, approaching the main stages of the constructive process through examples, showing the materials used in the construction, in addition the main international normative recommendations of the project. Thus, this manuscript also hopes to contribute to the popularization of the wood frame system in Brazil, since it is a competitive, fast and ecologically correct system. Moreover, nowadays, an enormous effort of the technical, commercial and industrial section has been accomplished for the development of this system in the country.

Construction of Hydrophobic Wood Surface and Mechanical Property of Wood Cell Wall on Nanoscale Modified by Dimethyldichlorosilane

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Yang, Rui; Wang, Siqun; Zhou, Dingguo; Zhang, Jie; Lan, Ping; Jia, Chong

2018-01-01

Dimethyldichlorosilane was used to improve the hydrophobicity of wood surface. The water contact angle of the treated wood surface increased from 85° to 143°, which indicated increased hydrophobicity. The nanomechanical properties of the wood cell wall were evaluated using a nanoindentation test to analyse the hydrophobic mechanism on the nano scale. The elastic modulus of the cell wall was significantly affected by the concentration but the influence of treatment time is insignificant. The hardness of the cell wall for treated samples was significantly affected by both treatment time and concentration. The interaction between treatment time and concentration was extremely significant for the elastic modulus of the wood cell wall.

STOCHASTIC HUMAN EXPOSURE AND DOSE SIMULATION MODEL FOR THE WOOD PRESERVATIVE SCENARIO (SHEDS-WOOD), VERSION 2 MODEL SAS CODE

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Concerns have been raised regarding the safety of young children contacting arsenic and chromium residues while playing on and around Chromated Copper Arsenate (CCA) treated wood playground structures and decks. Although CCA registrants voluntarily canceled treated wood for resi...

The effect of some wood preservatives on the thermal degradation of Scots pine

International Nuclear Information System (INIS)

Tomak, Eylem D.; Baysal, Ergun; Peker, Huseyin

2012-01-01

Highlights: ► Scots pine samples were impregnated with 10 commercial wood preservatives. ► Thermal degradation of wood was evaluated by TG, DTG and DTA. ► The thermal behavior of treated wood differed from that of untreated wood. ► Boron containing wood preservatives yielded more charcoal than other preservatives. ► Boric oxide and metal compounds in the formulations may affect char weight. - Abstract: Wood has been a structural material for many years; however, its ability to burn has limited its use in some applications. This study aims to evaluate the effect of commercial wood preservatives having concentration of 4% on the thermal behavior of Scots pine wood, and compare the fire retardant effectiveness of these preservatives with that of boron compounds. Thermal degradation of treated and untreated wood samples was evaluated by thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA). Thermal behavior of treated wood differed from thermal behavior of untreated wood in terms of a high char yield. Results showed that weight loss of wood reduced while char yield increased in the charring phase of the pyrolysis in the boron containing preservative treated wood accompanying with pyrolysis temperature lowered. The highest char yield was obtained from the samples treated with disodium octaborate tetrahydrate in the all treated groups.

Characterization of volatile constituents in commercial oak wood chips.

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Fernández de Simón, Brígida; Muiño, Iria; Cadahía, Estrella

2010-09-08

The volatile composition of the different oak wood pieces (chips of Quercus spp.) that can be found on the market to be used as alternatives to barrels for aging wines, as well as of chips of Quercus pyrenaica which are being introduced, was studied, evaluating the contents of volatile phenols, lactones, furanic compounds, pyranones, phenolic aldehydes, phenolic ketones, and others. In regard to the overall results, the volatile composition of these products varies widely and has not been clearly laid out according to either the oak species or the wood toasting intensity. Taking into account that the different characteristics of alternatives to barrel products are reflected in the wine treated with them and that an oenological profile based on these variables (origin and toasting level) cannot be defined, only an appropriate chemical analysis would reveal the quality of alternative-to-barrel products and allow us to attempt to foresee its effects on the chemical and organoleptic characteristics of the wines treated with them. On the other hand, the Q. pyrenaica alternative products are very similar to those of other species, with some aromatic particularities, such as their high levels of furanic compounds, eugenol, Furaneol, and cis-whiskylactone, and low levels of vanillin.

State-of-the-art of the European regulation on wood wastes and wood ashes valorization. Synthesis

International Nuclear Information System (INIS)

Mousseau, S.

2007-01-01

This study has the objective of comparing the regulations of 10 European countries with that of France, in relation to the classification and recycling of wood waste, in particular lightly treated wood, as well as recycling of wood ash. The first part relating to wood waste presents a detailed analysis by country as well as a summary, on the one hand, of the various sectors for recycling waste wood and, on the other, the emission limits for their energy recovery. Generally, there is a distinction between waste covered by the incineration directive, and the others, without any particular category for lightly treated wood. However, recommendations emerge from this that are based essentially on the regulations or guidelines observed in Germany, Austria and the United Kingdom. The second part relating to wood ash also a presents a detailed analysis by country as well as a summary of the various sectors of recycling and limit values for spreading. Ash is generally considered as waste, and is recycled on a case-by case basis. Only Germany and Austria have clearly integrated wood ash in their regulatory framework. Overall this study shows the need for uniform regulation at European level, establishing environment requirements for recycling wood waste and wood ash, in order to encourage development of the use of biomass

Advances in corrosion testing of metals in contact with treated wood

Science.gov (United States)

Samuel Zelinka; D.S. Stone

2010-01-01

A January 2004 change in the regulation of wood preservatives used in the U.S.has increased the use of newer wood preservatives, such as alkaline copper quaternary (ACQ) and copper azole (CuAz). These preservatives contain high amounts of cupric ions, which may be reduced to copper metal at the expense of less noble steel and galvanized fasteners in the wood....

The effect of some wood preservatives on the thermal degradation of Scots pine

Energy Technology Data Exchange (ETDEWEB)

Tomak, Eylem D., E-mail: eylemdizman@yahoo.com [Karadeniz Technical University, Faculty of Forestry, Forest Industrial Engineering Department, 61080 Trabzon (Turkey); Baysal, Ergun, E-mail: bergun@mu.edu.tr [Mugla University, Faculty of Technology, Department of Wood Science and Technology, Kotekli, 48000 Mugla (Turkey); Peker, Huseyin, E-mail: peker100@hotmail.com [Artvin Coruh University, Faculty of Forestry, Forest Industrial Engineering Department, 06100 Artvin (Turkey)

2012-11-10

Highlights: Black-Right-Pointing-Pointer Scots pine samples were impregnated with 10 commercial wood preservatives. Black-Right-Pointing-Pointer Thermal degradation of wood was evaluated by TG, DTG and DTA. Black-Right-Pointing-Pointer The thermal behavior of treated wood differed from that of untreated wood. Black-Right-Pointing-Pointer Boron containing wood preservatives yielded more charcoal than other preservatives. Black-Right-Pointing-Pointer Boric oxide and metal compounds in the formulations may affect char weight. - Abstract: Wood has been a structural material for many years; however, its ability to burn has limited its use in some applications. This study aims to evaluate the effect of commercial wood preservatives having concentration of 4% on the thermal behavior of Scots pine wood, and compare the fire retardant effectiveness of these preservatives with that of boron compounds. Thermal degradation of treated and untreated wood samples was evaluated by thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA). Thermal behavior of treated wood differed from thermal behavior of untreated wood in terms of a high char yield. Results showed that weight loss of wood reduced while char yield increased in the charring phase of the pyrolysis in the boron containing preservative treated wood accompanying with pyrolysis temperature lowered. The highest char yield was obtained from the samples treated with disodium octaborate tetrahydrate in the all treated groups.

Assessing the Extent of Sediment Contamination Around Creosote-treated Pilings Through Chemical and Biological Analyses

Science.gov (United States)

Stefansson, E. S.

2008-12-01

Creosote is a common wood preservative used to treat marine structures, such as docks and bulkheads. Treated dock pilings continually leach polycyclic aromatic hydrocarbons (PAHs) and other creosote compounds into the surrounding water and sediment. Over time, these compounds can accumulate in marine sediments, reaching much greater concentrations than those in seawater. The purpose of this study was to assess the extent of creosote contamination in sediments, at a series of distances from treated pilings. Three pilings were randomly selected from a railroad trestle in Fidalgo Bay, WA and sediment samples were collected at four distances from each: 0 meters, 0.5 meters, 1 meter, and 2 meters. Samples were used to conduct two bioassays: an amphipod bioassay (Rhepoxynius abronius) and a sand dollar embryo bioassay. Grain size and PAH content (using a fluorometric method) were also measured. Five samples in the amphipod bioassay showed significantly lower effective survival than the reference sediment. These consisted of samples closest to the piling at 0 and 0.5 meters. One 0 m sample in the sand dollar embryo bioassay also showed a significantly lower percentage of normal embryos than the reference sediment. Overall, results strongly suggest that creosote-contaminated sediments, particularly those closest to treated pilings, can negatively affect both amphipods and echinoderm embryos. Although chemical data were somewhat ambiguous, 0 m samples had the highest levels of PAHs, which corresponded to the lowest average survival in both bioassays. Relatively high levels of PAHs were found as far as 2 meters away from pilings. Therefore, we cannot say how far chemical contamination can spread from creosote-treated pilings, and at what distance this contamination can still affect marine organisms. These results, as well as future research, are essential to the success of proposed piling removal projects. In addition to creosote-treated pilings, contaminated sediments must

Environmental Degradation of Fiber-Reinforced Polymer Fasteners in Wood

Science.gov (United States)

Samuel L. Zelinka; Douglas R. Rammer

2013-01-01

This paper examines the durability of fiber-reinforced polymer (FRP) nails in treated wood. The FRP nails were exposed to four conditions: (1) accelerated weathering, consisting of exposure to ultraviolet light and condensation; (2) 100% relative humidity (RH); (3) being driven into untreated wood and exposed to 100% RH; and (4) being driven into wood treated with...

physico-chemical properties and energy potential of wood wastes

African Journals Online (AJOL)

user

were performed to assess the energy characteristics of the collected wood .... Methods. Wood processing activities were physically observed for. 6 days/wk at the sawmills for 15weeks. ..... [10] Oladeji, J T “Fuel characterization of briquettes.

Weathering properties of treated southern yellow pine wood examined by X-ray photoelectron spectroscopy, scanning electron microscopy and physical characterization

Energy Technology Data Exchange (ETDEWEB)

Salaita, Ghaleb N.; Ma, Frank M.S.; Parker, Trudy C. [Dow Chemical Company, Technical Center, 3200 Kanawha Turnpike, South Charleston, WV 25303 (United States); Hoflund, Gar B. [Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainesville, FL 32611 (United States)], E-mail: garho@hotmail.com

2008-04-30

In this study the weathering behavior of southern yellow pine (SYP) wood samples pretreated in different solutions has been examined using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and various types of physical characterization regarding material loss and discoloration. The treatment solutions include water as a control, a commercially available water repellent (WR) wood treating additive and polyethylene glycol (PEG) products including PEG PLUS{sup TM}, PEG 8000 solutions and Compound 20M in varying concentrations. All contained the wood preservative chromated copper arsenate (CCA). One sample was treated with a CCA solution only. The treatments were carried out at 20 deg. C and 150 psig for 1/2 h after exposure to vacuum (28 mmHg) for 15 min. Simulated weathering was achieved in an Atlas 65-W Weather-Ometer for 2000 h with both light and dark periods and rain. The temperature ranged from 23 deg. C during the dark cycle to 35 deg. C during the light cycle. With weathering the XPS O/C ratios increase due to oxidation of the surface. Exposure to UV light results in bond breakage and reaction with oxygen in the presence of air to form organic functional groups such as , , C=O and/or O-C-O. These oxidized products can protect the underlying wood from deterioration if they are insoluble in water and remain on the surface as a protective coating. If soluble, rain washes the compounds away and assists in the degradation. Correlated changes are observed in the XPS O/C ratios, the high-resolution XPS C 1s spectra, the SEM micrographs and physical measurements including thickness alteration, weight loss, and discoloration by yellowing or whitening of the weathered wood. The PEG treatments are effective in protecting wood with the 2% PEG PLUS treatment providing the best weathering behavior similar to that of the CCA treatment. The WR and water treatments yield the poorest weathering properties.

Weathering properties of treated southern yellow pine wood examined by X-ray photoelectron spectroscopy, scanning electron microscopy and physical characterization

International Nuclear Information System (INIS)

Salaita, Ghaleb N.; Ma, Frank M.S.; Parker, Trudy C.; Hoflund, Gar B.

2008-01-01

In this study the weathering behavior of southern yellow pine (SYP) wood samples pretreated in different solutions has been examined using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and various types of physical characterization regarding material loss and discoloration. The treatment solutions include water as a control, a commercially available water repellent (WR) wood treating additive and polyethylene glycol (PEG) products including PEG PLUS TM , PEG 8000 solutions and Compound 20M in varying concentrations. All contained the wood preservative chromated copper arsenate (CCA). One sample was treated with a CCA solution only. The treatments were carried out at 20 deg. C and 150 psig for 1/2 h after exposure to vacuum (28 mmHg) for 15 min. Simulated weathering was achieved in an Atlas 65-W Weather-Ometer for 2000 h with both light and dark periods and rain. The temperature ranged from 23 deg. C during the dark cycle to 35 deg. C during the light cycle. With weathering the XPS O/C ratios increase due to oxidation of the surface. Exposure to UV light results in bond breakage and reaction with oxygen in the presence of air to form organic functional groups such as , , C=O and/or O-C-O. These oxidized products can protect the underlying wood from deterioration if they are insoluble in water and remain on the surface as a protective coating. If soluble, rain washes the compounds away and assists in the degradation. Correlated changes are observed in the XPS O/C ratios, the high-resolution XPS C 1s spectra, the SEM micrographs and physical measurements including thickness alteration, weight loss, and discoloration by yellowing or whitening of the weathered wood. The PEG treatments are effective in protecting wood with the 2% PEG PLUS treatment providing the best weathering behavior similar to that of the CCA treatment. The WR and water treatments yield the poorest weathering properties

Wood preservation

Science.gov (United States)

Kevin Archer; Stan Lebow

2006-01-01

Wood preservation can be interpreted to mean protection from fire, chemical degradation, mechanical wear, weathering, as well as biological attack. In this chapter, the term preservation is applied more restrictively to protection from biological hazards.

Electron treatment of wood pulp for the viscose process

Science.gov (United States)

Stepanik, T. M.; Ewing, D. E.; Whitehouse, R.

2000-03-01

Electron processing is currently being evaluated by several viscose producers for integration into their process. The viscose industry converts dissolving wood pulp into products such as staple fibre, filament, cord, film, packaging, and non-edible sausage casings. These materials are used in the clothing, drapery, hygiene, automobile, food, and packaging industries. Viscose producers are facing increasingly high production costs and stringent environmental regulations that have forced some plants to close. Electron treatment of wood pulp can significantly reduce the amounts of chemicals used for producing viscose and the production of hazardous pollutants. Acsion Industries has worked with companies worldwide to demonstrate the benefits of using electron treated pulp for producing viscose (rayon). This paper describes the viscose process, the benefits of using electron treatment in the viscose process, and Acsion's efforts in developing this technology.

Electrochemical impedance spectroscopy (EIS) as a tool for measuring corrosion of polymer-coated fasteners used in treated wood

Science.gov (United States)

Samuel L. Zelinka; Lorraine Ortiz-Candelaria; Donald S. Stone; Douglas R. Rammer

2009-01-01

Currently, many of the polymer-coated fasteners on the market are designed for improved corrosion performance in treated wood; yet, there is no way to evaluate their corrosion performance. In this study, a common technique for measuring the corrosion performance of polymer-coated metals, electrochemical impedance spectroscopy (EIS), was used to evaluate commercial...

Corrosion of metals in wood : comparing the results of a rapid test method with long-term exposure tests across six wood treatments

Science.gov (United States)

Samuel L. Zelinka; Donald S. Stone

2011-01-01

This paper compares two methods of measuring the corrosion of steel and galvanized steel in wood: a long-term exposure test in solid wood and a rapid test method where fasteners are electrochemically polarized in extracts of wood treated with six different treatments. For traditional wood preservatives, the electrochemical extract method correlates with solid wood...

Acute wood or coal exposure with carbon monoxide intoxication induces sister chromatid exchange

Energy Technology Data Exchange (ETDEWEB)

Ozturk, S.; Vatansever, S.; Cefle, K.; Palanduz, S.; Guler, K.; Erten, N.; Erk, O.; Karan, M.A.; Tascioglu, C. [University of Istanbul, Istanbul (Turkey). Istanbul Faculty of Medicine

2002-07-01

The object of this study was to investigate the genotoxic effect of acute overexposure to combustion products originating from coal or wood stoves in patients presenting with acute carbon monoxide intoxication. The authors analyzed the frequency of sister chromatid exchange and the carboxyhemoglobin concentration in 20 consecutive patients without a history of smoking or drug use who had been treated in the Emergency Care Unit of Istanbul Medical Faculty due to acute carbon monoxide intoxication. All of these cases were domestic accidents due to dysfunctioning coal or wood stoves. The results were compared with a control group of 20 nonsmoking, nondrug-using healthy individuals matched for age, sex, and absence of other chemical exposure. It was concluded that acute exposure to combustion products of wood or coal is genotoxic to DNA. Potential causes of genotoxicity include known mutagenic compounds present in coal or wood smoke and ash, oxygen radicals formed during combustion, as well as hypoxic and reperfusion injury mechanisms initiated by carbon monoxide intoxication.

Anaerobic baffled reactor coupled with chemical precipitation for treatment and toxicity reduction of industrial wastewater.

Science.gov (United States)

Laohaprapanona, Sawanya; Marquesa, Marcia; Hogland, William

2014-01-01

This study describes the reduction of soluble chemical oxygen demand (CODs) and the removal of dissolved organic carbon (DOC), formaldehyde (FA) and nitrogen from highly polluted wastewater generated during cleaning procedures in wood floor manufacturing using a laboratory-scale biological anaerobic baffled reactor followed by chemical precipitation using MgCI2 .6H20 + Na2HPO4. By increasing the hydraulic retention time from 2.5 to 3.7 and 5 days, the reduction rates of FA, DOC and CODs of nearly 100%, 90% and 83%, respectively, were achieved. When the Mg:N:P molar ratio in the chemical treatment was changed from 1:1:1 to 1.3:1:1.3 at pH 8, the NH4+ removal rate increased from 80% to 98%. Biologically and chemically treated wastewater had no toxic effects on Vibrio fischeri and Artemia salina whereas chemically treated wastewater inhibited germination of Lactuca sativa owing to a high salt content. Regardless of the high conductivity of the treated wastewater, combined biological and chemical treatment was found to be effective for the removal of the organic load and nitrogen, and to be simple to operate and to maintain. A combined process such as that investigated could be useful for on-site treatment of low volumes of highly polluted wastewater generated by the wood floor and wood furniture industries, for which there is no suitable on-site treatment option available today.

Impact of chromated copper arsenate (CCA) in wood mulch.

Science.gov (United States)

Townsend, Timothy G; Solo-Gabriele, Helena; Tolaymat, Thabet; Stook, Kristin

2003-06-20

The production of landscape mulch is a major market for the recycling of yard trash and waste wood. When wood recovered from construction and demolition (C&D) debris is used as mulch, it sometimes contains chromated copper arsenate (CCA)-treated wood. The presence of CCA-treated wood may cause some potential environmental problems as a result of the chromium, copper, and arsenic present. Research was performed to examine the leachability of the three metals from a variety of processed wood mixtures in Florida. The mixtures tested included mixed wood from C&D debris recycling facilities and mulch purchased from retail outlets. The synthetic precipitation leaching procedure (SPLP) was performed to examine the leaching of chromium, copper and arsenic. Results were compared to Florida's groundwater cleanup target levels (GWCTLs). Eighteen of the 22 samples collected from C&D debris processing facilities leached arsenic at concentrations greater than Florida's GWCTL of 50 microg/l. The mean leachable arsenic concentration for the C&D debris samples was 153 microg/l with a maximum of 558 microg/l. One of the colored mulch samples purchased from a retail outlet leached arsenic above 50 microg/l, while purchased mulch samples derived from virgin materials did not leach detectable arsenic (<5 microg/l). A mass balance approach was used to compute the potential metal concentrations (mg/kg) that would result from CCA-treated wood being present in wood mulch. Less than 0.1% CCA-treated wood would cause a mulch to exceed Florida's residential clean soil guideline for arsenic (0.8 mg/kg).

Physiognomic and chemical characters in wood as palaeoclimate proxies

NARCIS (Netherlands)

Poole, I.J.; Bergen, P.F. van

2006-01-01

Fossil wood is both abundant and ubiquitous through geological time and space. During growth the parent plant was directly influenced by the biotic and abiotic (including climatic-) factors in the surrounding environment. The climate affects wood production in a number of ways and it is the

Turning wood residues into wood revenues

International Nuclear Information System (INIS)

Graham, R.G.; Kravetz, Don

1996-01-01

Ensyn is a profitable commercial company which derives its revenues from the conversion of wood residues into liquid biofuel and chemicals. The technology, Rapid Thermal Processing (RTP (TM) )is based on extremely fast ''cracking'' of biomass which results in light liquid yields exceeding 70% by weight, from wood. Whether producing chemicals or liquid biofuel, the RTP plant is configured identically and operated essentially in the same mode. Chemicals production simply allows economical production to occur at a lower plant capacity, as low as 2 tonnes/day, than is feasible for a dedicated fuel plant (typically greater than 100 tonnes/day). Ensyn has developed the commercialisation of RTP TM from bench to industrial scale in 10 years. A variety of crative funding initiatives in the early years allowed for capital to be raised for R and D without the loss of intellectual property (IP). The transition years of technology demonstration, prior to full commercialisation, were funded by a blend of revenues from venture capital and public sources, and by quickly tapping into a niche market for RTP TM . The utilisation of the technology at the niche market scale opened the doors to the larger fuel and commodity markets. Once, again, both IP and control of the company were maintained during these years. Flexibility, creativity and expertise are necessary to understand the significance of various financing options (private investments, commercial banking and bond issues) and to integrate these options with various renewable energy, recycling and tax incentives. Understanding these options with various renewable energy, recycling and tax incentives is necessary. Understanding both the core and peripheral needs of the customer are essential in successfully advancing a commercial wood energy venture. Ensyn's experience in these areas is the focus of the paper. (Author)

Wood chemistry symposium: from muka to lignin

Energy Technology Data Exchange (ETDEWEB)

MacLeod, M.

1979-01-01

The Canadian Wood Chemistry Symposium held during September, 1979, is reviewed. The chemical and physical explanations of delignification were debated. Problems of mechanical pulping include insufficient brightness, yellowing, and low strength relative to energy consumption. A session on chemicals, energy, and food from wood began with criteria for a viable project, which included adequate return on investment, modest capital investment requirements, identified pre-existing markets, and favorable thermodynamic balances. The pulp and paper industry should improve its methods of using bark and wood waste in direct combustion (by pre-drying wastes and improving furnace efficiency) rather than supporting oil-from-wood projects, since using a waste for fuel will free fossil fuels for uses in synthetic fibers and thermoplastics. In the area of food, there are modest successes with cellulose fiber additives to bread and snack food and single cell protein (which, though made from wastes, cannot compete with soy protein). However, making monomeric sugars from wood polysaccharides is not an efficient process, and muka, animal feed supplement from foliage, is successful only in Russia. In Canada it cannot compete with agricultural products. Alpha cellulose is a major wood chemical product. Promising uses include cellulose derived thermoplastics and lignosulphonates for secondary oil recovery. Instead of breaking wood polysaccharides and lignin into monomers and then repolymerizing them, it is possible to use the pre-built polymers; such an approach is illustrated by use of lignin in polyurethane foams, adhesives, and coatings.

Waste wood as bioenergy feedstock. Climate change impacts and related emission uncertainties from waste wood based energy systems in the UK.

Science.gov (United States)

Röder, Mirjam; Thornley, Patricia

2018-04-01

Considering the urgent need to shift to low carbon energy carriers, waste wood resources could provide an alternative energy feedstock and at the same time reduce emissions from landfill. This research examines the climate change impacts and related emission uncertainties of waste wood based energy. For this, different grades of waste wood and energy application have been investigated using lifecycle assessment. Sensitivity analysis has then been applied for supply chain processes and feedstock properties for the main emission contributing categories: transport, processing, pelletizing, urea resin fraction and related N 2 O formation. The results show, depending on the waste wood grade, the conversion option, scale and the related reference case, that emission reductions of up to 91% are possible for non-treated wood waste. Compared to this, energy from treated wood waste with low contamination can achieve up to 83% emission savings, similar to untreated waste wood pellets, but in some cases emissions from waste wood based energy can exceed the ones of the fossil fuel reference - in the worst case by 126%. Emission reductions from highly contaminated feedstocks are largest when replacing electricity from large-scale coal and landfill. The highest emission uncertainties are related to the wood's resin fraction and N 2 O formation during combustion and, pelletizing. Comparing wood processing with diesel and electricity powered equipment also generated high variations in the results, while emission variations related to transport are relatively small. Using treated waste wood as a bioenergy feedstock can be a valid option to reduce emissions from energy production but this is only realisable if coal and landfill gas are replaced. To achieve meaningful emission reduction in line with national and international climate change targets, pre-treatment of waste wood would be required to reduce components that form N 2 O during the energy conversion. Copyright © 2017

MILD ALKALINE TREATMENT ACTIVATES SPRUCE WOOD FOR ENZYMATIC PROCESSING: A POSSIBLE STAGE IN BIO-REFINERY PROCESSES

Directory of Open Access Journals (Sweden)

Yan Wang

2011-05-01

Full Text Available The structure of wood is so compact that enzymes are too large to penetrate into the structure and thereby attack the wood components for modifications that can be valuable for various purposes. Here we present a pretreatment method based on traditional kraft pulping, which opens the wood structure, so that enzymes are able to attack the wood components. To study this kind of chemical pretreatment, spruce wood samples were treated at similar conditions used in kraft cooking at varying intensities (H-factors. To verify if the structure was “opened” for enzymes, the pretreated wood samples were incubated with a cellulolytic culture filtrate, and the released reducing sugar concentration after the enzymatic hydrolysis was measured. The results indicated that un-pretreated wood fibers could not be attacked by the enzymes, but already relatively mild pretreatment was sufficient for letting the culture filtrate attack wood polysaccharides, and more intensive treatments opened the structure further. The mildest treatments did not cause any significant yield losses of lignin (Klason lignin. Some galactogluco-mannans were however lost during the pretreatments. The mechanisms behind the effect and the technical significance of the method are discussed.

Thermal Properties of Wood-Plastic Composites Prepared from Hemicellulose-extracted Wood Flour

Directory of Open Access Journals (Sweden)

A.A. Enayati

2013-01-01

Full Text Available Hemicellulose of Southern Yellow Pine wood spices was extracted by pressurized hot water at three different temperatures: 140°C, 155°C and 170°C. Compounding with PP (polypropylene was performed by extrusion after preparing wood flour and sieving to determine its mesh size. The ratio of wood to polymer was 50:50 based on oven-dry weight of wood flour. All extraction treatments and control samples were compounded under two sets of conditions, without and with 2% MAPP as coupling agent. Injection molding was used to make tensile test samples (dogbone from the pellets made by extrusion. Thermal properties of wood-plastic composites were studied by TGA and DSC while the thermal stability of pretreated wood flours, PP and MAPP were studied by TGA as well. The greater weight loss of wood materials was an indication that higher treatment temperature increases the extractability of hemicellulose. The removal of hemicellulose by extraction improves thermal stability of wood flour, especially for extraction at 170°C. Wood-plastic composites made from extracted fibers at 170°C showed the highest thermal stability. Coupling agent did not have a significant effect on thermal stability but it improved the degree of crystallinity of the composites.Surface roughness of wood fiber increased after treatment. Extraction of hemicellulose increased the degree of crystallinity but it was not significant except for samples from treated wood flour at 170°C and with MAPP.

Cytochemical localization of cellulases in decayed and nondecayed wood

Energy Technology Data Exchange (ETDEWEB)

Murmanis, L.; Highley, T.L.; Palmer, J.G.

1987-01-01

Sawdust from undecayed western hemlock wood and from wood previously decayed by the brown-rot fungus Poria placenta or by the white-rot fungus Ganoderma applanatum was incubated with commercial cellulase from Trichoderma viride. Samples were treated cytochemically to locate cellulase activity and examined by TEM. Results showed that cellulase degraded undecayed wood extensively, with the attack starting on the outer border of a cell wall and progressing inside. Wood decayed by P. placenta, with or without cellulase incubation, and treated by the cytochemical test showed uniform distribution of electron dense particles throughout the cell walls. In wood decayed by G. applanatum, cellulase degradation was similar to that in undecayed wood. From measurements of particle diameter it is suggested that electron dense particles are cellulase. It is concluded that brown-rot and white-rot fungi have different effects on the microstructure of wood. The brown-rot fungus appears to open the wood microstructure so that cellulase can diffuse throughout the degraded tracheid wall.

Source apportionment of PM2.5 at multiple Northwest U.S. sites: Assessing regional winter wood smoke impacts from residential wood combustion

Science.gov (United States)

Kotchenruther, Robert A.

2016-10-01

Wood smoke from residential wood combustion is a significant source of elevated PM2.5 in many communities across the Northwest U.S. Accurate representation of residential wood combustion in source-oriented regional scale air quality models is challenging because of multiple uncertainties. As an alternative to source-oriented source apportionment, this work provides, through receptor-oriented source apportionment, an assessment of winter residential wood combustion impacts at multiple Northwest U.S. locations. Source apportionment was performed on chemically speciated PM2.5 from 19 monitoring sites using the Positive Matrix Factorization (PMF) receptor model. Each site was modeled independently, but a common data preparation and modeling protocol was used so that results were as comparable as possible across sites. Model solutions had from 4 to 8 PMF factors, depending on the site. PMF factors at each site were associated with a source classification (e.g., primary wood smoke), a dominant chemical composition (e.g., ammonium nitrate), or were some mixture. 15 different sources or chemical compositions were identified as contributing to PM2.5 across the 19 sites. The 6 most common were; aged wood smoke and secondary organic carbon, motor vehicles, primary wood smoke, ammonium nitrate, ammonium sulfate, and fugitive dust. Wood smoke was identified at every site, with both aged and primary wood smoke identified at most sites. Wood smoke contributions to PM2.5 were averaged for the two winter months of December and January, the months when wood smoke in the Northwest U.S. is mainly from residential wood combustion. The total contribution of residential wood combustion, that from primary plus aged smoke, ranged from 11.4% to 92.7% of average December and January PM2.5 depending on the site, with the highest percent contributions occurring in smaller towns that have fewer expected sources of winter PM2.5. Receptor modeling at multiple sites, such as that conducted in this

Advances and challenges of wood polymer composites

Science.gov (United States)

Roger M. Rowell

2006-01-01

Wood flour and fiber have been blended with thermoplastic such as polyethylene, polypropylene, polylactic acid and polyvinyl chloride to form wood plastic composites (WPC). WPCs have seen a large growth in the United States in recent years mainly in the residential decking market with the removal of CCA treated wood decking from residential markets. While there are...

Changes in structural and chemical components of wood delignified by fungi

Energy Technology Data Exchange (ETDEWEB)

Blanchette, R.A.; Otjen, L.; Effland, M.J.; Eslyn, W.E.

1985-01-01

Cerrena unicolor, Ganoderma applanatum, Ischnoderma resinosum and Poria medulla-panis were associated with birch (Betula papyrifera) wood that had been selectively delignified in the forest. Preferential lignin degradation was not uniformly distributed throughout the decayed wood. A typical white rot causing a simultaneous removal of all cell wall components was also present. In the delignified wood, 95 to 98% of the lignin was removed as well as substantial amounts of hemicelluloses. Scanning and transmission electron microscopy were used to identify the micromorphological and ultrastructural changes that occurred in the cells during degradation. In delignified areas the compound middle lamella was extensively degraded causing a defibration of cells. The secondary wall, especially the S2 layer, remained relatively unaltered. In simultaneously white-rotted wood all cell wall layers were progressively removed from the lumen toward the middle lamella causing erosion troughs or holes to form. Large voids filled with fungal mycelia resulted from a coalition of degraded areas. Birch wood decayed in laboratory soil-block tests was also intermittently delignified, selective delignification, sparsely distributed throughout the wood, and a simultaneous rot resulting in the removal of all cell wall components were evident. SEM appears to be an appropriate technique for examining selectively delignified decayed wood. 30 references.

Superfund record of decision (EPA Region 3): Southern Maryland Wood Treating Site, Hollywood, MD, September 8, 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-09-01

The decision document presents the selected remedial action for the Southern Maryland Wood Treating Site (`the Site`), in Hollywood, Maryland. This is the second and final phase of remedial action for the Site. This phase addresses soil and sediment contamination and non-aqueous phase liquids (`NAPLs`) which are the principal threats remaining at the Site and are a source of contamination to the ground water and surface water.

CANONICAL CORRELATION OF PHYSICAL AND CHEMICAL CHARACTERISTICS OF THE WOOD OF Eucalyptus grandis AND Eucalyptus saligna CLONES

Directory of Open Access Journals (Sweden)

Paulo Fernando Trugilho

2003-01-01

Full Text Available The analysis of canonical correlation measures the existence and the intensity of the association between two groups of variables. The research objectified to evaluate thecanonical correlation between chemical and physical characteristics and fiber dimensional ofwood of Eucalyptus grandis and Eucalyptus saligna clones, verifying the interdependenceamong the groups of studied variables. The analysis indicated that the canonical correlationswere high and that in two cases the first and second pair were significant at the level of 1% ofprobability. The analysis of canonical correlation showed that the groups are notindependent. The intergroup associations indicated that the wood of high insoluble lignin contentand low ash content is associated with the high radial and tangential contraction and highbasic density wood.

Treatment of Copper Contaminated Municipal Wastewater by Using UASB Reactor and Sand-Chemically Carbonized Rubber Wood Sawdust Column

Directory of Open Access Journals (Sweden)

Swarup Biswas

2016-01-01

Full Text Available The performance of a laboratory scale upflow anaerobic sludge blanket (UASB reactor and its posttreatment unit of sand-chemically carbonized rubber wood sawdust (CCRWSD column system for the treatment of a metal contaminated municipal wastewater was investigated. Copper ion contaminated municipal wastewater was introduced to a laboratory scale UASB reactor and the effluent from UASB reactor was then followed by treatment with sand-CCRWSD column system. The laboratory scale UASB reactor and column system were observed for a period of 121 days. After the posttreatment column the average removal of monitoring parameters such as copper ion concentration (91.37%, biochemical oxygen demand (BODT (93.98%, chemical oxygen demand (COD (95.59%, total suspended solid (TSS (95.98%, ammonia (80.68%, nitrite (79.71%, nitrate (71.16%, phosphorous (44.77%, total coliform (TC (99.9%, and fecal coliform (FC (99.9% was measured. The characterization of the chemically carbonized rubber wood sawdust was done by scanning electron microscope (SEM, X-ray fluorescence spectrum (XRF, and Fourier transforms infrared spectroscopy (FTIR. Overall the system was found to be an efficient and economical process for the treatment of copper contaminated municipal wastewater.

Treatment of Copper Contaminated Municipal Wastewater by Using UASB Reactor and Sand-Chemically Carbonized Rubber Wood Sawdust Column.

Science.gov (United States)

Biswas, Swarup; Mishra, Umesh

2016-01-01

The performance of a laboratory scale upflow anaerobic sludge blanket (UASB) reactor and its posttreatment unit of sand-chemically carbonized rubber wood sawdust (CCRWSD) column system for the treatment of a metal contaminated municipal wastewater was investigated. Copper ion contaminated municipal wastewater was introduced to a laboratory scale UASB reactor and the effluent from UASB reactor was then followed by treatment with sand-CCRWSD column system. The laboratory scale UASB reactor and column system were observed for a period of 121 days. After the posttreatment column the average removal of monitoring parameters such as copper ion concentration (91.37%), biochemical oxygen demand (BODT) (93.98%), chemical oxygen demand (COD) (95.59%), total suspended solid (TSS) (95.98%), ammonia (80.68%), nitrite (79.71%), nitrate (71.16%), phosphorous (44.77%), total coliform (TC) (99.9%), and fecal coliform (FC) (99.9%) was measured. The characterization of the chemically carbonized rubber wood sawdust was done by scanning electron microscope (SEM), X-ray fluorescence spectrum (XRF), and Fourier transforms infrared spectroscopy (FTIR). Overall the system was found to be an efficient and economical process for the treatment of copper contaminated municipal wastewater.

QUALITY OF REACTION WOOD IN EucalyptusTREES TILTED BY WIND FOR PULP PRODUCTION

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Walter Torezani Neto Boschetti

2017-09-01

Full Text Available This study aims to evaluate the quality of normal, tension and opposite wood of eucalyptus trees lengthwise, in straight and inclined stems, affected by wind action. It also aims to explain the pulping parameters resultant from the quality of the wood. The trees were grouped into four tilt ranges, ranging from 0 to 50º, and the basic density, chemical composition of the wood, and performance in kraft pulping were assessed. Normal and tension wood had similar basic densities; while for opposite wood, the density was lower, being responsible for a decrease in reaction wood density. The chemical composition of the wood was influenced by the presence of reaction wood in the stem.Tension and opposite wood showed lower levels of extractives and lignin and higher holocellulose content when compared to normal wood, with favorable wood quality for pulping. The increase in holocellulose content and the reduction of lignin and extractives content contributed positively to a more delignified pulp and reduction of the Kappa number. However, after cooking the reaction wood under the same conditions as those of normal wood, reaction wood pulping tends to have a lower screen yields. Due to differences in basic density and chemical constituents between opposite and normal wood, it is recommended not to designate the opposite wood as normal wood.

Holistic approach to wood protection

Science.gov (United States)

Roger M. Rowell

2006-01-01

When untreated wood is exposed to adverse outdoor conditions, nature has a series of chemistries to degrade it to its original building blocks of carbon dioxide and water. Fungi, termites, heat, moisture, ultraviolet (UV) energy, and chemicals take their toll on the performance properties of wood. We tend to study each of these degradation chemistries as individual...

Selected mechanical properties of modified beech wood

Directory of Open Access Journals (Sweden)

Jiří Holan

2008-01-01

Full Text Available This thesis deals with an examination of mechanical properties of ammonia treated beach wood with a trademark Lignamon. For determination mechanical properties were used procedures especially based on ČSN. From the results is noticeable increased density of wood by 22% in comparison with untreated beach wood, which makes considerable increase of the most mechanical wood properties. Considering failure strength was raised by 32% and modulus of elasticity was raised at average about 46%.

Photodegradation of wood and depth profile analysis

International Nuclear Information System (INIS)

Kataoka, Y.

2008-01-01

Photochemical degradation is a key process of the weathering that occurs when wood is exposed outdoors. It is also a major cause of the discoloration of wood in indoor applications. The effects of sunlight on the chemical composition of wood are superficial in nature, but estimates of the depth at which photodegradation occurs in wood vary greatly from 80 microm to as much as 2540 mic rom. Better understanding of the photodegradation of wood through depth profile analysis is desirable because it would allow the development of more effective photo-protective treatments that target the surface layers of wood most susceptible to photodegradation. This paper briefly describes fundamental aspects of photodegradation of wood and reviews progress made in the field of depth profile study on the photodegradation of wood. (author)

Effect of wood filler treatment and EBAGMA compatibilizer on morphology and mechanical properties of low density polyethylene/olive husk flour composites

Directory of Open Access Journals (Sweden)

2007-07-01

Full Text Available This paper deals with plastic-wood composites based on low density polyethylene (LDPE and olive husk flour (OHF. The problem of incompatibility between the hydrophilic wood filler and the LDPE hydrophobic matrix was treated by two methods: a chemical modification of the olive husk flour with maleic anhydride to esterify the free hydroxyl groups of the wood components and the use of a compatibilizer agent, i.e. an ethylene-butyl acrylate-glycidyl methacrylate (EBAGMA terpolymer. The changes in the structure, the morphology, and the properties resulting from these treatments were followed by various techniques, especially FTIR spectroscopy, scanning electron microscopy (SEM, tensile measurements and water absorption. The experimental results indicated that both methods, i.e. the chemical treatment of the olive husk flour with maleic anhydride and the inclusion of EBAGMA terpolymer, improved the interactions between the two composite components and promoted better dispersion of the filler in the matrix. Moreover, ultimate tensile properties were also increased. However, the use of EBAGMA terpolymer as compatibilizer produced better enhancement of the properties of LDPE/OHF composites compared to those treated with maleic anhydride.

The effects of wood storage on the chemical composition and indigenous microflora of eucalyptus species used in the pulping industry

CSIR Research Space (South Africa)

Ramnath, L

2018-02-01

Full Text Available Lipophilic extractives naturally occurring in wood tend to coalesce during pulping to form pitch deposits, which have particularly undesirable effects on the pulping process and quality of pulp produced. A chemical characterization of different...

Comparative study of Nd:YAG laser-induced breakdown spectroscopy and transversely excited atmospheric CO2 laser-induced gas plasma spectroscopy on chromated copper arsenate preservative-treated wood.

Science.gov (United States)

Khumaeni, Ali; Lie, Zener Sukra; Niki, Hideaki; Lee, Yong Inn; Kurihara, Kazuyoshi; Wakasugi, Motoomi; Takahashi, Touru; Kagawa, Kiichiro

2012-03-01

Taking advantage of the specific characteristics of a transversely excited atmospheric (TEA) CO(2) laser, a sophisticated technique for the analysis of chromated copper arsenate (CCA) in wood samples has been developed. In this study, a CCA-treated wood sample with a dimension of 20 mm × 20 mm and a thickness of 2 mm was attached in contact to a nickel plate (20 mm × 20 mm × 0.15 mm), which functions as a subtarget. When the TEA CO(2) laser was successively irradiated onto the wood surface, a hole with a diameter of approximately 2.5 mm was produced inside the sample and the laser beam was directly impinged onto the metal subtarget. Strong and stable gas plasma with a very large diameter of approximately 10 mm was induced once the laser beam had directly struck the metal subtarget. This gas plasma then interacted with the fine particles of the sample inside the hole and finally the particles were effectively dissociated and excited in the gas plasma region. By using this technique, high precision and sensitive analysis of CCA-treated wood sample was realized. A linear calibration curve of Cr was successfully made using the CCA-treated wood sample. The detection limits of Cr, Cu, and As were estimated to be approximately 1, 2, and 15 mg/kg, respectively. In the case of standard LIBS using the Nd:YAG laser, the analytical intensities fluctuate and the detection limit was much lower at approximately one-tenth that of TEA CO(2) laser. © 2012 Optical Society of America

Chemical studies on oils derived from aspen poplar wood, cellulose, and an isolated aspen poplar lignin

Energy Technology Data Exchange (ETDEWEB)

Eager, R L; Pepper, J M; Roy, J C; Mathews, J F

1983-01-01

An initial study has been made of the chemical nature of the oil phase resulting from the conversion of aspen poplar wood, cellulose, and an isolated lignin from the aspen poplar as a result of their interactions with water and carbon monoxide in the presence of sodium carbonate at 360 degrees C. Gas chromatographic analysis of the sodium hydroxide soluble fractions from each substrate revealed similar spectra of alkyl-substituted phenols. The relative abundance of identified low molecular weight phenolic compounds decreased from lignin to wood to cellulose. This was in agreement with the known phenolic nature of lignin. As well, it confirmed the synthesis during reaction of such compounds from a carbohydrate substrate. Gas chromatographic analysis of the whole oils also revealed the presence in each case of several alkyl-substituted cyclopentanones whose relative abundance decreased from cellulose to wood to lignin. Silica gel column separation of the oils, after a charcoal treatment, followed by capillary gas chromatographic - mass spectrometric analyses of the resulting fraction indicated the presence of other higher molecular weight phenols, napthols, cycloalkanols, and polycyclic and long chain alkanes and alkenes.

Feasibility of biodegradation of pentachlorophenol in scrap wood

International Nuclear Information System (INIS)

Beaulieu, G.; Besner, A.; Gilbert, R.; Tetreault, P.; Beaudet, R.; Bisaillon, J. G.; Lepine, F.; Ottou, J. M.; Sansregret, J. L.; Lei, J.

1998-04-01

The feasibility of biological treatment of scrap wood impregnated in pentachlorophenol (PCP) was investigated using wood samples impregnated with PCP for biodegradation experiments by the Hydro-Quebec Research Institute (IREQ). IREQ identified the necessity of pre-treating the wood, first by shredding wood poles into wood shavings, followed by mechanical milling of the shavings to obtain wood dust. Biodegradation experiments under anaerobic conditions were performed by the Armand-Frappier Institute by isolating a consortium of bacteria from a mixture of PCP-contaminated soils and a municipal anaerobic sludge that was able to degrade PCP under anaerobic methanogenic conditions at 29 degrees C. A complementary source of carbon was found to be necessary for the bacterial consortium to degrade the PCP. The best PCP degradation results were obtained with an aerobic fixed-film reactor. Aerobic biodegradation tests were performed on liquor extracted from wood dust contaminated with PCP. The anaerobic fixed field reactor was able to completely degrade the PCP extracted from wood dust in less than one day. Aerobic biodegradation was also investigated using microorganisms and fungi. Over a four month experimental period only low concentrations of PCP were found in effluents treated with the aerobic cultures. 117 refs., 38 tabs., 31 figs

PROTECTIVE TREATMENT OF WOOD IMPREGNATING COMPOSITION OF PETROCHEMICAL WASTE

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T. V. Maslakova

2015-01-01

Full Text Available The paper presents results of experimental and theoretical studies aimed at expanding the applications of the copolymers on the basis of the waste styrene production. One of the areas is used as impregnating compositions of wood materials, selection of optimal conditions modification on samples of the most widely used in the industry of wood, such as birch, aspen and other. Studies were conducted to obtain and use an impregnating compositions based on copolymers synthesized from waste products of styrene and the cubic remainder rectification of ethylbenzene (CRRE for the protective treatment of birch wood. Identified physic-chemical characteristics of physical mixtures of copolymers «CORS», «STAM», CRRE at different ratios. Studied the process of modification birch using the method of experiment planning greco-latin square of the fourth order, and the influence of such factors as the temperature of the impregnating composition, the duration of the impregnation, the temperature and duration of thermal treatment on the performance moisture resistance of wood. Were established optimal conditions modification birch wood treated impregnating compositions on the basis of physical mixtures of copolymer «CORS» with CRRE and copolymer «STAM» with CRRE is the mixing ratio 2:1, the duration and temperature of the impregnation 7 h and 95 0C, time and temperature of heat treatment 7 h and 170 0C, respectively. A sealing composition containing CRRE with copolymer «STAM» 1:2 is more preferable, as in the structure of the copolymer «STAM» contains carboxyl and anhydrite group. Thus was justified use for the modification of natural wood impregnating compositions on the basis of physical mixtures of CRRE with copolymers «CORS» and «STAM», which improve the properties of wood, increase moisture and weather resistance more than twice.

Extant contents of chromium, copper and arsenic in waste CCA-treated timber

International Nuclear Information System (INIS)

Chiba, Keiko; Uchida, Shinpei; Honma, Yoshinori; Sera, Koichiro; Saitoh, Katsumi

2009-01-01

The segregation and disposal of chromated copper arsenate (CCA)-treated wood waste when recycling building waste materials is a serious issue. We examined the contents of CCA preserved cedar timber by PIXE analysis. CCA preserved timber contained large amounts of these metals both on the surface and core of the wood. The ratio of chromium, copper and arsenic contained on the surface was 1:2:1, and in contrast, the ratio in the core was 1:1:2. In other words, the arsenic content was highest in the core. Moreover, the chemical form of arsenic in both parts of the wood was only inorganic arsenic; the same form of arsenic in preservative components known as carcinogenic substances. These findings mean that the complete separation of waste CCA preserved timber from construction and demolition wood is needed. (author)

STRUCTURAL ANALYSIS OF WOOD-LEATHER PANELS BY RAMAN SPECTROSCOPY

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Tilman Grünewald,

2012-02-01

Full Text Available Besides other ligno-cellulosic materials such as straw, rice husks, or bagasse, wet blue particles from leather production are a promising new raw material stock for wood-based panels, as they offer not only a high availability, but increase the properties of the panel with regard to fire resistance or mechanical characteristics. A panel with a mixture of 42.5% wood fibers, 42.5% wet blue leather particles, and 15% lignin adhesive was produced, and an inhomogeneous sample was prepared. An area of 9 x 10 mm was rasterized and scanned by means of Raman Spectroscopy. Furthermore, the reference spectra of the constituents, i.e. wood fiber, wet blue leather particle, and lignin powder were recorded. The obtained data were treated and analyzed using chemometric methods (principal components analysis PCA and cluster analysis. An important finding was that the reference data were not directly represented in the panels’ spectra, and the correlation matrix of the PCA was not applicable to the panel data. This indicated that chemical changes might take place during the pressing. After processing the panel Raman spectra with the help of PCA and cluster analysis, three distinctive clusters were obtained, discriminating wood, leather, and mixed regions. With the assigned spectral information, it was possible to create a spectral image of the surface.

EFFECT OF ARTIFICIAL WEATHERING ON WOOD LAMINATES COLOR TREATED WITH TWO FINISHING PRODUCTS

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Thais Jacob Mendes

2016-03-01

Full Text Available Weathering is one of the main reasons for the degradation of wood, especially its color. The application of finishes minimizes these effects. This study aimed to monitor the effect of artificial weathering on wood veneer of the species cumaru (Dipteryx odorata and pau marfim (Balfourodendron riedelianum with two finishes, the marine varnish and Cetol, with monitoring using a spectrophotometer. The samples were subjected to cycles of exposure to weathering for 20, 40, 52, 76, 124, 226, 430, 838 and 960 hours. The colorimetric parameters (L*, a*, b*, C and h* were measured before treatment, after application of the products and during the weathering time intervals. The application of finishes darkened veneer of cumaru wood and pau marfim in nature. However, in higher weathering times, both species returned to a lighter color, and even became lighter than the natural wood. The use of Cetol was more efficient, giving greater stability in the conservation of wood color of the species studied.

Hexadecyl ammonium chloride amylose inclusion complex to emulsify cedarwood oil and treat wood against termites and wood-decay fungi

Science.gov (United States)

F.J. Eller; W.T. Hay; G.T. Kirker; M.E. Mankowski; G.W. Sellling

2018-01-01

Cedarwood oil (CWO) has a wide range of bioactivities, including insect repellency and toxicity, as well as conferring resistance against termites and wood-decay fungi. In previous work examining pressure treatment of wood, ethanol was used as the diluent/carrier for CWO. However, it is preferable to use a water-based carrier for environmental, safety and cost...

Harvested wood products : basis for future methodological development

Science.gov (United States)

Kenneth E. Skog

2003-01-01

The IPCC Guidelines (IPCC 1997) provide an outline of how harvested wood could be treated in national greenhouse gas (GHG) inventories. This section shows the relation of that outline to the approaches and estimation methods to be presented in this Appendix. Wood and paper products are referred to as harvested wood products (HWP). It does not include carbon in...

Chapter 23: Corrosion of Metals in Wood Products

Science.gov (United States)

Samuel L. Zelinka

2014-01-01

The corrosion of metals in contact with wood has been studied for over 80 years, and in most situations wood is not corrosive [1]. Recently, however, the durability of fasteners in preservative--treated wood has become a concern. Changes in legislation and certification in the United States, the European Union, and Australasia have restricted the use of chromated...

75 FR 44251 - Wood Oils and Gums, and Streptomyces

Science.gov (United States)

2010-07-28

... ENVIRONMENTAL PROTECTION AGENCY EPA-HQ-OPP-2010-0441; FRL-8829-8 Wood Oils and Gums, and... integrated use in tank mixes with chemical fungicides. The Wood Oils and Gums Registration Review Case no longer contains any other wood oils or gums with active ingredients with registered products except for...

Effective Remediation of Lead Ions from Aqueous Solution by Chemically Carbonized Rubber Wood Sawdust: Equilibrium, Kinetics, and Thermodynamic Study

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Swarup Biswas

2015-01-01

Full Text Available Rubber wood sawdust was carbonized into charcoal by chemical treatment which was used for removal of lead ion from aqueous solution. The work involves batch experiments to investigate the pH effect, initial concentration of adsorbate, contact time, and adsorbent dose. Experimental data confirmed that the adsorption capacities increased with increasing inlet concentration and bed height and decreased with increasing flow rate. Adsorption results showed a maximum adsorption capacity of 37 mg/g at 308 K. Langmuir, Freundlich, and Temkin model adsorption isotherm models were applied to analyze the process where Temkin was found as a best fitted model for present study. Simultaneously kinetics of adsorption like pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were investigated. Thermodynamic parameters were used to analyze the adsorption experiment. Fourier transform infrared spectroscopy, scanning electron microscope, and energy dispersive X-ray spectroscopy confirmed the batch adsorption of lead ion onto chemically carbonized rubber wood sawdust.

Composite structure of wood cells in petrified wood

International Nuclear Information System (INIS)

Nowak, Jakub; Florek, Marek; Kwiatek, Wojciech; Lekki, Janusz; Chevallier, Pierre; Zieba, Emil; Mestres, Narcis; Dutkiewicz, E.M.; Kuczumow, Andrzej

2005-01-01

Special kinds of petrified wood of complex structure were investigated. All the samples were composed of at least two different inorganic substances. The original cell structure was preserved in each case. The remnants of the original biological material were detected in some locations, especially in the cell walls. The complex inorganic structure was superimposed on the remnant organic network. The first inorganic component was located in the lumena (l.) of the cells while another one in the walls (w.) of the cells. The investigated arrangements were as follows: calcite (l.)-goethite-hematite (w.)-wood from Dunarobba, Italy; pyrite (l.)-calcite (w.)-wood from Lukow, Poland; goethite (l.)-silica (w.)-wood from Kwaczala, Poland. The inorganic composition was analysed and spatially located by the use of three spectral methods: electron microprobe, X-ray synchrotron-based microprobe, μ-PIXE microprobe. The accurate mappings presenting 2D distribution of the chemical species were presented for each case. Trace elements were detected and correlated with the distribution of the main elements. In addition, the identification of phases was done by the use of μ-Raman and μ-XRD techniques for selected and representative points. The possible mechanisms of the described arrangements are considered. The potential synthesis of similar structures and their possible applications are suggested

Composite structure of wood cells in petrified wood

Energy Technology Data Exchange (ETDEWEB)

Nowak, Jakub [Department of Chemistry, Catholic University of Lublin, 20-718 Lublin (Poland); Florek, Marek [Department of Chemistry, Catholic University of Lublin, 20-718 Lublin (Poland); Kwiatek, Wojciech [Institute of Nuclear Physics, Department of Nuclear Spectroscopy, 31-342 Cracow (Poland); Lekki, Janusz [Institute of Nuclear Physics, Department of Nuclear Spectroscopy, 31-342 Cracow (Poland); Chevallier, Pierre [LPS, CEN Saclay et LURE, Universite Paris-Sud, Bat 209D, F-91405 Orsay (France); Zieba, Emil [Department of Chemistry, Catholic University of Lublin, 20-718 Lublin (Poland); Mestres, Narcis [Institut de Ciencia de Materials de Barcelona (ICMAB), Campus de la UAB, E-08193-Bellaterra (Spain); Dutkiewicz, E.M. [Institute of Nuclear Physics, Department of Nuclear Spectroscopy, 31-342 Cracow (Poland); Kuczumow, Andrzej [Department of Chemistry, Catholic University of Lublin, 20-718 Lublin (Poland)

2005-04-28

Special kinds of petrified wood of complex structure were investigated. All the samples were composed of at least two different inorganic substances. The original cell structure was preserved in each case. The remnants of the original biological material were detected in some locations, especially in the cell walls. The complex inorganic structure was superimposed on the remnant organic network. The first inorganic component was located in the lumena (l.) of the cells while another one in the walls (w.) of the cells. The investigated arrangements were as follows: calcite (l.)-goethite-hematite (w.)-wood from Dunarobba, Italy; pyrite (l.)-calcite (w.)-wood from Lukow, Poland; goethite (l.)-silica (w.)-wood from Kwaczala, Poland. The inorganic composition was analysed and spatially located by the use of three spectral methods: electron microprobe, X-ray synchrotron-based microprobe, {mu}-PIXE microprobe. The accurate mappings presenting 2D distribution of the chemical species were presented for each case. Trace elements were detected and correlated with the distribution of the main elements. In addition, the identification of phases was done by the use of {mu}-Raman and {mu}-XRD techniques for selected and representative points. The possible mechanisms of the described arrangements are considered. The potential synthesis of similar structures and their possible applications are suggested.

Eucalyptus grandis AND Eucalyptus dunnii USE FOR WOOD-CEMENT PANELS MANUFACTURING

Directory of Open Access Journals (Sweden)

Setsuo Iwakiri

2008-03-01

Full Text Available This research evaluated the potential use of Eucalyptus grandis and Eucalyptus dunnii wood for wood-cement panelsmanufacturing. The boards were manufactured at the density of 1,20 g/cm³, using portland cement as mineral bonding and woodfurnish without treatment, treated in cold water and hot water. The wood furnish of Pinus taeda was used as control. The resultsindicated that it is not necessary to treat E. grandis and E. dunni wood for wood-cement board manufacturing. In relation to woodspecies, the board manufactured with E. dunnii showed lower values of mechanical properties. However, boards manufactured of E.grandis wood showed satisfactory results in comparison to boards of P. taeda and the referenced values of BISON process and otherproducts cited in the pertnent literature, indicating the high potential for wood-cement board manufacture of this tree species.

Chemical composition of particles from traditional burning of Pakistani wood species

Science.gov (United States)

Shahid, Imran; Kistler, Magdalena; Mukhtar, Azam; Ramirez-Santa Cruz, Carlos; Bauer, Heidi; Puxbaum, Hans

2015-11-01

Total particulate matter (TPM) emitted during burning of three types of Pakistani wood (eucalyptus camaldulensis, local name Safeeda; acacia nilotica, local name Kikar, Babul; dalbergia sissoo, Shisham, Tali) in a traditional brick stove were collected and analyzed for anhydrosugars, sugar alcohols, trace metals, soluble ions and carbonaceous species. This is a first study reporting anhydrosugars in wood smoke particles emitted during traditional burning of common wood types in Pakistan. Carbonaceous species showed the highest contribution to the particulate matter. Although the total carbon (TC) contribution was similar for all burnings (64.8-70.2%), the EC/OC ratio varied significantly, from 0.2 to 0.3 for Accacia and Dalbergia to 0.7-0.8 for Eucalyptus and Wood-mix. Among inorganic constituents potassium chloride and silicon were found at levels higher than 1%. The levoglucosan concentrations ranged from 3.0 to 6.6% (average 5.6%) with the highest value for Accacia and lowest value for the wood-mix. The high levoglucosan/mannosan ratios of 20-28 were typical for hardwood. The ratio between levoglucosan and galactosan varied stronger and was found to be around 13-20 for Accacia, Eucalyptus and Wood mix, and 43 for Dalbergia. The determined levoglucosan concentrations allowed assessing the conversion factor for calculation of biomass smoke contribution to ambient particulate matter levels in Pakistan.

Physical and chemical characterization of waste wood derived biochars.

Science.gov (United States)

Yargicoglu, Erin N; Sadasivam, Bala Yamini; Reddy, Krishna R; Spokas, Kurt

2015-02-01

Biochar, a solid byproduct generated during waste biomass pyrolysis or gasification in the absence (or near-absence) of oxygen, has recently garnered interest for both agricultural and environmental management purposes owing to its unique physicochemical properties. Favorable properties of biochar include its high surface area and porosity, and ability to adsorb a variety of compounds, including nutrients, organic contaminants, and some gases. Physical and chemical properties of biochars are dictated by the feedstock and production processes (pyrolysis or gasification temperature, conversion technology and pre- and post-treatment processes, if any), which vary widely across commercially produced biochars. In this study, several commercially available biochars derived from waste wood are characterized for physical and chemical properties that can signify their relevant environmental applications. Parameters characterized include: physical properties (particle size distribution, specific gravity, density, porosity, surface area), hydraulic properties (hydraulic conductivity and water holding capacity), and chemical and electrochemical properties (organic matter and organic carbon contents, pH, oxidation-reduction potential and electrical conductivity, zeta potential, carbon, nitrogen and hydrogen (CHN) elemental composition, polycyclic aromatic hydrocarbons (PAHs), heavy metals, and leachable PAHs and heavy metals). A wide range of fixed carbon (0-47.8%), volatile matter (28-74.1%), and ash contents (1.5-65.7%) were observed among tested biochars. A high variability in surface area (0.1-155.1g/m(2)) and PAH and heavy metal contents of the solid phase among commercially available biochars was also observed (0.7-83 mg kg(-1)), underscoring the importance of pre-screening biochars prior to application. Production conditions appear to dictate PAH content--with the highest PAHs observed in biochar produced via fast pyrolysis and lowest among the gasification

Innovations in Wood Protection in the age of Nanotechnology

Science.gov (United States)

Carol A. Clausen

2014-01-01

Advances in wood protection based on nanotechnology are being developed to improve resistance of wood products to biodeterioration, reduce environmental impacts from chemical leaching and resist UV degradation of in-service wood. A number of different approaches have been explored. First, the nanometals zinc oxide and copper oxide were evaluated as preservative...

Monitoring losses of copper based wood preservatives in the Thames estuary

International Nuclear Information System (INIS)

Hingston, J.A.; Murphy, R.J.; Lester, J.N.

2006-01-01

Field trials were conducted at two sites in the Thames estuary to monitor losses of copper, chromium and arsenic from wood preservative treated timbers of varying sizes and treatment regimes. Results indicated that leaching tests conducted under standard laboratory conditions might overestimate losses compared to losses resulting from real environmental exposures. Amine copper treated wood was noted to leach higher levels of copper compared to chromated copper arsenate treated wood, and was therefore considered an inappropriate replacement biocide for fresh and marine construction purposes on this basis. Increases in copper concentrations in the outer sections of amine copper treated posts may have represented re-distribution of this component in this timber. No accumulation of metals was found in sediments surrounding field trial posts. - Wood preservative field trials in the UK indicate that standard laboratory tests overestimate losses compared to those resulting from real environmental exposures

Monitoring losses of copper based wood preservatives in the Thames estuary

Energy Technology Data Exchange (ETDEWEB)

Hingston, J.A. [Environmental Processes and Water Technology Research Group, Department of Environmental Science and Technology, Faculty of Life Sciences, Imperial College, London SW7 2AZ (United Kingdom)]. E-mail: james.hingston@psd.defra.gsi.gov.uk; Murphy, R.J. [Department of Biology, Imperial College, London SW7 2AZ (United Kingdom); Lester, J.N. [School of Water Sciences, Cranfield University, Cranfield, Bedfordshire, MK43 0AL (United Kingdom)

2006-09-15

Field trials were conducted at two sites in the Thames estuary to monitor losses of copper, chromium and arsenic from wood preservative treated timbers of varying sizes and treatment regimes. Results indicated that leaching tests conducted under standard laboratory conditions might overestimate losses compared to losses resulting from real environmental exposures. Amine copper treated wood was noted to leach higher levels of copper compared to chromated copper arsenate treated wood, and was therefore considered an inappropriate replacement biocide for fresh and marine construction purposes on this basis. Increases in copper concentrations in the outer sections of amine copper treated posts may have represented re-distribution of this component in this timber. No accumulation of metals was found in sediments surrounding field trial posts. - Wood preservative field trials in the UK indicate that standard laboratory tests overestimate losses compared to those resulting from real environmental exposures.

Effects of compost and phosphate on plant arsenic accumulation from soils near pressure-treated wood

International Nuclear Information System (INIS)

Cao Xinde; Ma, Lena Q.

2004-01-01

Leaching of arsenic (As) from chromated copper arsenate (CCA)-treated wood may elevate soil arsenic levels. Thus, an environmental concern arises regarding accumulation of As in vegetables grown in these soils. In this study, a greenhouse experiment was conducted to evaluate As accumulation by vegetables from the soils adjacent to the CCA-treated utility poles and fences and examine the effects of soil amendments on plant As accumulation. Carrot (Daucus carota L.) and lettuce (Lactuca sativa L.) were grown for ten weeks in the soil with or without compost and phosphate amendments. As expected, elevated As concentrations were observed in the pole soil (43 mg kg -1 ) and in the fence soil (27 mg kg -1 ), resulting in enhanced As accumulation of 44 mg kg -1 in carrot and 32 mg kg -1 in lettuce. Addition of phosphate to soils increased As accumulation by 4.56-9.3 times for carrot and 2.45-10.1 for lettuce due to increased soil water-soluble As via replacement of arsenate by phosphate in soil. However, biosolid compost application significantly reduced plant As uptake by 79-86%, relative to the untreated soils. This suppression is possibly because of As adsorbed by biosolid organic mater, which reduced As phytoavailability. Fractionation analysis showed that biosolid decreased As in soil water-soluble, exchangeable, and carbonate fraction by 45%, whereas phosphate increased it up to 2.61 times, compared to the untreated soils. Our results indicate that growing vegetables in soils near CCA-treated wood may pose a risk of As exposure for humans. Compost amendment can reduce such a risk by reducing As accumulation by vegetables and can be an important strategy for remediating CCA-contaminated soils. Caution should be taken for phosphate application since it enhances As accumulation. - Capsule: Compost amendment can reduce As exposure risk for humans by reducing As accumulation by vegetables and can be an important strategy for remediating CCA-contaminated soils

Effects of compost and phosphate on plant arsenic accumulation from soils near pressure-treated wood

Energy Technology Data Exchange (ETDEWEB)

Cao Xinde [Soil and Water Science Department, University of Florida, Gainesville, FL (United States)]. E-mail: xcao@stevens.edu; Ma, Lena Q. [Soil and Water Science Department, University of Florida, Gainesville, FL (United States)

2004-12-01

Leaching of arsenic (As) from chromated copper arsenate (CCA)-treated wood may elevate soil arsenic levels. Thus, an environmental concern arises regarding accumulation of As in vegetables grown in these soils. In this study, a greenhouse experiment was conducted to evaluate As accumulation by vegetables from the soils adjacent to the CCA-treated utility poles and fences and examine the effects of soil amendments on plant As accumulation. Carrot (Daucus carota L.) and lettuce (Lactuca sativa L.) were grown for ten weeks in the soil with or without compost and phosphate amendments. As expected, elevated As concentrations were observed in the pole soil (43 mg kg{sup -1}) and in the fence soil (27 mg kg{sup -1}), resulting in enhanced As accumulation of 44 mg kg{sup -1} in carrot and 32 mg kg{sup -1} in lettuce. Addition of phosphate to soils increased As accumulation by 4.56-9.3 times for carrot and 2.45-10.1 for lettuce due to increased soil water-soluble As via replacement of arsenate by phosphate in soil. However, biosolid compost application significantly reduced plant As uptake by 79-86%, relative to the untreated soils. This suppression is possibly because of As adsorbed by biosolid organic mater, which reduced As phytoavailability. Fractionation analysis showed that biosolid decreased As in soil water-soluble, exchangeable, and carbonate fraction by 45%, whereas phosphate increased it up to 2.61 times, compared to the untreated soils. Our results indicate that growing vegetables in soils near CCA-treated wood may pose a risk of As exposure for humans. Compost amendment can reduce such a risk by reducing As accumulation by vegetables and can be an important strategy for remediating CCA-contaminated soils. Caution should be taken for phosphate application since it enhances As accumulation. - Capsule: Compost amendment can reduce As exposure risk for humans by reducing As accumulation by vegetables and can be an important strategy for remediating CCA

Differentiating Agar wood Oil Quality Using Artificial Neural Network

International Nuclear Information System (INIS)

Nurlaila Ismail; Nor Azah Mohd Ali; Mailina Jamil; Saiful Nizam Tajuddin; Mohd Nasir Taib

2013-01-01

Agar wood oil is well known as expensive oil extracted from the resinous of fragrant heartwood. The oil is getting high demand in the market especially from the Middle East countries, China and Japan because of its unique odor. As part of an on-going research in grading the agar wood oil quality, the application of Artificial Neural Network (ANN) is proposed in this study to analyze agar wood oil quality using its chemical profiles. The work involves of selected agar wood oil from low and high quality, the extraction of chemical compounds using GC-MS and Z-score to identify of the significant compounds as input to the network. The ANN programming algorithm was developed and computed automatically via Matlab software version R2010a. Back-propagation training algorithm and sigmoid transfer function were used to optimize the parameters in the training network. The result obtained showed the capability of ANN in analyzing the agar wood oil quality hence beneficial for the further application such as grading and classification for agar wood oil. (author)

Environmental education on wood preservatives and preservative ...

African Journals Online (AJOL)

The development and use of wood preservatives in Nigeria should address not only the cost and demand functions but also the potential hazards in environmental equations. Forest products specialists are often asked about the perceived risks and environmental costs of treated wood products. Evidently, the civil society is ...

Methods for Mitigating the Environmental Risks Associated with Wood Preservatives

Science.gov (United States)

Dennis Hayward; Stan T. Lebow; Kenneth M. Brooks

2011-01-01

As noted in earlier chapters, the treatment of wood is both art and science. Wood is a variable material; treatment results tend to vary with the preservative and wood species and even within boards of the same species. This means that treated wood often contains a range of preservative retentions. Some pieces will have less than the desired retention, while others may...

Understanding extractive bleed : wood extractives: distribution, properties, and classes

Science.gov (United States)

Edward Burke; Norm Slavik; Tony Bonura; Dennis Connelly; Tom Faris; Arnie Nebelsick; Brent Stuart; Sam Williams; Alex C. Wiedenhoeft

2010-01-01

Color, odor, and natural durability of heartwood are characteristics imparted by a class of chemicals in wood known collectively extractives. Wood is converted by the tree from sapwood to heartwood by the deposition of extractives, typically many years after the growth ring undergoing this change was formed by the tree. Extractives are thus not a part of the wood...

Bio-Based Adhesives and Evaluation for Wood Composites Application

Directory of Open Access Journals (Sweden)

Fatemeh Ferdosian

2017-02-01

Full Text Available There has been a rapid growth in research and innovation of bio-based adhesives in the engineered wood product industry. This article reviews the recent research published over the last few decades on the synthesis of bio-adhesives derived from such renewable resources as lignin, starch, and plant proteins. The chemical structure of these biopolymers is described and discussed to highlight the active functional groups that are used in the synthesis of bio-adhesives. The potentials and drawbacks of each biomass are then discussed in detail; some methods have been suggested to modify their chemical structures and to improve their properties including water resistance and bonding strength for their ultimate application as wood adhesives. Moreover, this article includes discussion of techniques commonly used for evaluating the petroleum-based wood adhesives in terms of mechanical properties and penetration behavior, which are expected to be more widely applied to bio-based wood adhesives to better evaluate their prospect for wood composites application.

Colour and chemical changes of the lime wood surface due to CO{sub 2} laser thermal modification

Energy Technology Data Exchange (ETDEWEB)

Kubovský, Ivan, E-mail: kubovsky@tuzvo.sk; Kačík, František

2014-12-01

Highlights: • Influences of CO{sub 2} laser on lime wood surface were studied. • With growth of the irradiation dose brightness decrease and increase of the total colour difference were observed. • Cellulose degradation and loss of hemicelluloses were observed. • Higher values at the input energy lead to accelerating the mutual reaction of the functional groups resulting in the subsequent condensation of lignin. • CO{sub 2} laser irradiation can be used as a new colouring method. - Abstract: We studied colour and main wood components changes of lime wood caused by CO{sub 2} laser beam irradiation. The dry surface of lime wood (Tilia vulgaris L.) was irradiated with the CO{sub 2} laser beam (wavelength of 10.6 μm) at different exposures (expressed as the irradiation dose). Colour changes were monitored by the spectrophotometer, chemical changes were observed by the ATR-FTIR spectroscopy and carbohydrates were analysed by the HPLC method. With the growth of the irradiation dose (from 8.1 to 28.7 J cm{sup −2}) lightness (ΔL{sup *}) decrease and increase of the total colour difference (ΔE{sup *}) were observed. Higher values of the input energy lead to accelerating the mutual reaction of the functional groups resulting in the subsequent condensation of lignin. The total decrease in saccharides at the highest irradiation dose reaches 27.39% of the initial amount of saccharides in the reference sample. We have observed degradation and loss of hemicelluloses.

Ionizing radiation and a wood-based biorefinery

International Nuclear Information System (INIS)

Driscoll, Mark S.; Stipanovic, Arthur J.; Cheng, Kun; Barber, Vincent A.; Manning, Mellony; Smith, Jennifer L.; Sundar, Smith

2014-01-01

Woody biomass is widely available around the world. Cellulose is the major structural component of woody biomass and is the most abundant polymer synthesized by nature, with hemicellulose and lignin being second and third. Despite this great abundance, woody biomass has seen limited application outside of the paper and lumber industries. Its use as a feedstock for fuels and chemicals has been limited because of its highly crystalline structure, inaccessible morphology, and limited solubility (recalcitrance). Any economic use of woody biomass for the production of fuels and chemicals requires a “pretreatment” process to enhance the accessibility of the biomass to enzymes and/or chemical reagents. Electron beams (EB), X-rays, and gamma rays produce ions in a material which can then initiate chemical reactions and cleavage of chemical bonds. Such ionizing radiation predominantly scissions and degrades or depolymerizes both cellulose and hemicelluloses, less is known about its effects on lignin. This paper discusses how ionizing radiation can be used to make a wood-based biorefinery more environmentally friendly and profitable for its operators. - Highlights: • Ionizing radiation reduces the crystallinity of cellulose. • Ionizing radiation reduces cellulose's degree of polymerization. • The amount and rate of enzymatic hydrolysis of lignocellulosic materials, including wood, are increased with increasing radiation dose. • Wood and other lignocellulosic materials have the potential to be a renewable material for the production of chemicals and fuels

Optimising hydrogen bonding in solid wood

DEFF Research Database (Denmark)

Engelund, Emil Tang

2009-01-01

The chemical bonds of wood are both covalent bonds within the wood polymers and hydrogen bonds within and between the polymers. Both types of bonds are responsible for the coherence, strength and stiffness of the material. The hydrogen bonds are more easily modified by changes in load, moisture...... and temperature distorting the internal bonding state. A problem arises when studying hydrogen bonding in wood since matched wood specimens of the same species will have very different internal bonding states. Thus, possible changes in the bonding state due to some applied treatment such as conditioning...... maintaining 100 % moisture content of the wood. The hypothesis was that this would enable a fast stress relaxation as a result of reorganization of bonds, since moisture plasticizes the material and temperature promotes faster kinetics. Hereby, all past bond distortions caused by various moisture, temperature...

Radiation processing of wood-plastic composites

International Nuclear Information System (INIS)

Czvikovszky, T.

1992-01-01

There are three main types of radiation-processed composite material derived from plastics and fibrous natural polymers. The first are the monomer-impregnated, radiation-treated wood-plastic composites (WPC). They became a commercial success in the early 1970s. More recently, work has focused on improving the WPCs by creating in them interpenetrating network (IPN) systems by the use of appropriate multifunctional oligomers and monomers. The main kinetic features of radiation-initiated chain polymerization remain applicable even in impregnated wood. The second type are the plastics filled or reinforced with dispersed wood fiber or other cellulosics (WFRP). In their case, radiation processing offers a new opportunity to apply radiation-reactive adhesion promoters between wood or cellulosic fibers and the thermoplastic matrices. The third type are the laminar composites made by electron beam coating of wood-based agglomerate sheets and boards. This chapter reviews the industrial applications and the radiation processing of the three types of the wood-plastic composites and indicates future trends. (orig.)

Characterization of residues from thermal treatment of treated wood and extraction of Cu, Cr, As and Zn

DEFF Research Database (Denmark)

Ottosen, Lisbeth M.; Pedersen, Anne Juul; Christensen, Iben Vernegren

2005-01-01

, that the charcoal contained a high concentration of Zn, probably from paint. Chemical extraction experiments in HNO were conducted with the charcoal and it was found that the order of extraction (in percentage) was Zn > Cu > As > Cr. A SEM/EDX investigation of the mixed ash from combustion showed the presence...... a matter to cope with when methods to avoid As emission are implemented: the residues with increased concentrations of Cu, Cr and As. In the present paper two different residues after thermal treatment are characterized: a mixed bottom and fly ash from combustion of CCA impregnated wood, and a charcoal...... form in a small layer on the surface of some matrix particles indicating condensation of volatile Cu species. Chemical extraction with inorganic acids showed the order of percentages mobilized as: As > Cu > Cr....

Preliminary studies of Brazilian wood using different radioisotopic sources

International Nuclear Information System (INIS)

Carvalho, Gilberto; Silva, Leonardo Gondim de Andrade e

2013-01-01

Due to availability and particular features, wood was one of the first materials used by mankind with a wide variety of applications. It can be used as raw material for paper and cellulose manufacturing; in industries such as chemical, naval, furniture, sports goods, toys, and musical instrument; in building construction and in the distribution of electric energy. Wood has been widely researched; therefore, wood researchers know that several aspects such as temperature, latitude, longitude, altitude, sunlight, soil, and rainfall index interfere with the growth of trees. This behavior explains why average physical-chemical properties are important when wood is studied. The majority of researchers consider density to be the most important wood property because of its straight relationship with the physical and mechanical properties of wood. There are three types of wood density: basic, apparent and green. The apparent density was used here at 12% of moisture content. In this study, four different types of wood were used: 'freijo', 'jequetiba', 'muiracatiara' and 'ipe'. For wood density determination by non-conventional method, Am-241, Ba-133 and Cs-137 radioisotopic sources; a NaI scintillation detector and a counter were used. The results demonstrated this technique to be quick and accurate. By considering the nuclear parameters obtained as half value layers and linear absorption coefficients, Cs-137 radioisotopic source demonstrated to be the best option to be used for inspection of the physical integrity of electric wooden poles and live trees for future works. (author)

Wood quality changes caused by mineral fertilization

Directory of Open Access Journals (Sweden)

Carlos Roberto Sette Jr

2014-06-01

Full Text Available The diverse and important use of wood from fast growth eucalyptus plantations requires the analysis of the effect of mineral fertilizers on wood quality. The objective of this study was to evaluate the anatomical characteristics and wood density from Eucalyptus grandis trees (3 m x 2 m spacing fertilized with potassium and sodium (at planting, 6 th and 12th month. Fifteen (15 6 years old eucalyptus trees were selected (5 trees/treatment, cut and wood samples at DBH (1,3 m were taken for anatomical characteristics (fiber and vessels and wood density analysis. Results showed that eucalyptus trees treated with mineral fertilizers did not show significant alteration in average wood density, with radial profile model common to all three treatments, characterized by a values increase in the region next to the pith, toward to bark. Mineral fertilization influenced wood anatomical characteristics: treatment with sodium was characterized by thinner walls and lumen larger diameter; in treatment with potassium, larger vessels were detected.

Enhancing durability of wood-based composites with nanotechnology

Science.gov (United States)

Carol Clausen

2012-01-01

Wood protection systems are needed for engineered composite products that are susceptible to moisture and biodeterioration. Protection systems using nano-materials are being developed to enhance the durability of wood-based composites through improved resistance to biodeterioration, reduced environmental impact from chemical leaching, and improved resistance to...

Fabrication of a superhydrophobic surface on a wood substrate

Science.gov (United States)

Wang, Shuliang; Shi, Junyou; Liu, Changyu; Xie, Cheng; Wang, Chengyu

2011-09-01

A layer of lamellar superhydrophobic coating was fabricated on a wood surface through a wet chemical process. The superhydrophobic property of the wood surface was measured by contact angle (CA) measurements. The microstructure and chemical composition of the superhydrophobic coating were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). An analytical characterization revealed that the microscale roughness of the lamellar particles was uniformly distributed on the wood surface and that a zinc stearate monolayer (with the hydrophobic groups oriented outward) formed on the ZnO surface as the result of the reaction between stearic acid and ZnO. This process transformed the wood surface from hydrophilic to superhydrophobic: the water contact angle of the surface was 151°, and the sliding angle was less than 5°.

Modification of the original color of the Eucalyptus grandis wood by heat treatments

Directory of Open Access Journals (Sweden)

Rosilei Aparecida Garcia

2014-09-01

Full Text Available The objective of this study was to determine the modification of original color of Eucalyptus grandis Hill ex. Maiden wood after heat-treatment. Wood samples were heat-treated under different temperatures (180, 200, 215 and 230ºC and time conditions (15 minutes, 2 and 4 hours. Color analysis were performed on the CIE L*a*b* system by using a Color Eye XTH-X-Rite 200d spectrophotometer. All heat treatments promoted an alteration of the original color of wood. Heat-treated woods presented lower L* (lightness values than untreated wood (control, characterizing the wood darkness, mainly for more severe conditions of temperature and time. Chromatic coordinates (a* and b* showed different behaviors depending on the temperature-time combination. The modification of the original color of the wood allowed the creation of new color patterns, which can add greater value to the studied wood.

Chemical Profiles of Wood Components of Poplar Clones for Their Energy Utilization

Directory of Open Access Journals (Sweden)

Danica Kačíková

2012-12-01

Full Text Available Selected and tested poplar clones are very suitable biomass resources for various applications such as biofuels, the pulp and paper industry as well as chemicals production. In this study, we determined the content of lignin, cellulose, holocellulose, and extractives, syringyl to guaiacyl (S/G ratio in lignin, and also calculated higher heating values (HHV among eight examined clones of Populus grown on three different experimental sites. The highest lignin content for all the examined sites was determined in ‘I-214’ and ‘Baka 5’ clones, whereas the highest content of extractives was found in ‘Villafranca’ and ‘Baka 5’ clones. The highest S/G ratio for all the examined sites was determined in ‘Villafranca’ and ‘Agathe F’ clones. The chemical profiles of main wood components, extractives, and the S/G ratio in lignin were also influenced by both the experimental site and the clone × site interaction. Higher heating values, derived from calculations based on the contents of lignin and extractives (or lignin only, were in close agreement with the previously published data. The highest heating values were found for ‘Baka 5’ and ‘I-214’ clones. The optimal method of poplar biomass utilization can be chosen on basis of the lignocellulosics chemical composition and the S/G ratio in lignin.

Physical, Chemical, and Biological Properties of Soil under Decaying Wood in a Tropical Wet Forest in Puerto Rico

Science.gov (United States)

Marcela Zalamea; Grizelle Gonzalez; D. Jean Lodge

2016-01-01

Decaying wood is related to nutrient cycling through its role as either a sink or source of nutrients. However, at micro scales, what is the effect of decaying logs on the physical, chemical,and biotic characteristics of the soil underneath? We took samples from a 0 to 5 cm depth under and a 50 cm distance away from decaying logs (Dacryodes excelsa and Swietenia...

Pretreatment Characteristics of Waste Oak Wood by Ammonia Percolation

Science.gov (United States)

Kim, Jun-Seok; Kim, Hyunjoon; Lee, Jin-Suk; Lee, Joon-Pyo; Park, Soon-Chul

A log of waste oak wood collected from a Korean mushroom farm has been tested for ammonia percolation pretreatment. The waste log has different physical characteristics from that of virgin oak wood. The density of the waste wood was 30% lower than that of virgin oak wood. However, there is little difference in the chemical compositions between the woods. Due to the difference in physical characteristics, the optimal pretreatment conditions were also quite different. While for waste oak the optimum temperature was determined to be 130°C, for virgin oak wood the optimum pretreatment was only achieved at 170°C. Presoaking for 12 h with ammonia solution before pretreatment was helpful to increase the delignification efficiency.

Studies on Solid Wood. II. The Influence of Chemical Modifications on Viscoelastic Properties

DEFF Research Database (Denmark)

Bjørkmann, Anders; Salmén, Lennart

2000-01-01

The relation between the properties of wood polymers and those of the composite material of wood is a subject that has been of interest for a long time. In order to increase oar knowledge in this matter, changes of wood properties have been studied on samples of spruce and birch, subjected to var...

Chemical compounds in teak

Directory of Open Access Journals (Sweden)

Fernanda Viana da Silva Leonardo

2015-09-01

Full Text Available Quinone compounds are largely generated at extractive fraction of the woods in a complex and variable biological system. The literature has indications for many segments from food industry to pharmaceutical industry. Within the field of industrial use of wood, they are less desirable since they are treated only as incidental substances in production strings of pulp, paper, charcoal, and sawmill. In spite of its small amount, compared to other chemical compounds called essential, these substances have received special attention from researchers revealing a diverse range of offerings to market products textiles, pharmaceuticals, colorants, and other polymers, for which are being tested and employed. Quinones are found in fungi, lichens, and mostly in higher plants. Tectona grandis, usually called teak, is able to biosynthesize anthraquinones, which is a quinone compound, byproduct of secondary metabolism. This species provides wood that is much prized in the furniture sector and can also be exploited for metabolites to supply the market in quinone compounds and commercial development of new technologies, adding value to the plantations of this species within our country.

Specifications in the application form for environmental assessment of wood preservatives

Energy Technology Data Exchange (ETDEWEB)

Lucks, U J [ed.

2000-09-01

In 1990 the former Federal Health Office (Bundesgesundheitsamt) and the Federal Environmental Agency (Umweltbundesamt) jointly elaborated a catalogue of test requirements necessary for assessing the impact of wood preservatives on man and environment. Based on several years of experience, a revision was deemed necessary. Complying with the provisions of the Directive 98/8/EC of the European Parliament and the Council of 16 February 1998 concerning the placing of biocidal products on the market, which have to be transposed into national laws, the regulatory bodies BAM, BgVV and UBA, in cooperation with industry and academia (IUCT), developed an amended application form for wood preservatives. The provisions laid down there include different sets of data for wood preservatives, depending on the intended uses/hazard classes, e.g. physico-chemical and ecotoxicological properties, data on exposure, fate and behaviour in the environment and on waste management. The tests should be conducted according to standardized test protocols. Next to the list of data requirements explanations and justifications are given on why the data are needed and how they contribute to the risk assessment. Furthermore, recommendations are given on which test guidelines should preferably be followed to generate the data. In addition, annex I includes a proposal for a test guideline on how to screen leachates from preservative-treated wood surfaces for their ecotoxic potential to aquatic organisms. (orig.)

Determination of Mn, Fe, and Cu in chemically-treated wood pulps by the XRF addition method

Energy Technology Data Exchange (ETDEWEB)

Raemoe, J.; Klasila, T.; Piepponen, S. [VTT Chemical Technology (Finland); Sillanpaeae, M. [Oulu Univ. (Finland)

2001-08-01

A rapid X-ray fluorescence addition method has been developed for quantification of the technically most important metals in wood pulp matrix (Mn, Fe, and Cu). Pretreatment consisted of just two steps: first, acid was added to the sample to achieve homogeneous distribution of the metals; the pulp was then pressed lightly on to Mylar film. Total analysis time was less than 10 min. The concentration range investigated was up to 15 mg kg{sup -1} for Mn and up to 5 mg kg{sup -1} for Fe and Cu. Metal concentrations in Scandinavian pulps are not expected to exceed these amounts. The quantification limit was 2 mg kg{sup -1} for all three metals. The reproducibilities and repeatabilities were concentration-dependent and varied between 3 and 19% and between 1 and 17%, respectively. The squares of the linear correlation coefficients between measured intensity and added metal concentration were 0.994, 0.950, and 0.932 for Mn, Fe, and Cu, respectively. (orig.)

Hydrophobic modification of wood via surface-initiated ARGET ATRP of MMA

Energy Technology Data Exchange (ETDEWEB)

Fu Yanchun; Li Gang [Material Science and Engineering College, Northeast Forestry University, Harbin 150040 (China); Yu Haipeng, E-mail: yuhaipeng20000@yahoo.com.cn [Key laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040 (China); Material Science and Engineering College, Northeast Forestry University, Harbin 150040 (China); Liu Yixing, E-mail: yxl200488@sina.com [Key laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040 (China); Material Science and Engineering College, Northeast Forestry University, Harbin 150040 (China)

2012-01-15

To convert the hydrophilic surface of wood into a hydrophobic surface, the present study investigated activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP) as a method of grafting methyl methacrylate (MMA) onto the wood surface. The wood treated with 2-bromoisobutyryl bromide and with the subsequently attached MMA via ARGET ATRP under different polymerization times (2 h, 4 h, 6 h, 8 h) were examined using scanning electron microscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. All the analyses confirmed that PMMA had been grafted onto the wood surface. Water contact angle measurement proved that the covering layer of PMMA on wood made the surface hydrophobic. Polymerization time had a positive influence on the contact angle value and higher contact angle can be produced with the prolongation of the polymerization time. When the reaction time was extended to 8 h, the contact angle of treated wood surface reached 130 Degree-Sign in the beginning, and remained at 116 Degree-Sign after 60 s. The ARGET ATRP method may raise an alteration on the wood surface modification.

An Investigation of Consolidants Penetration in Wood. Part 2: FTIR Spectroscopy

Directory of Open Access Journals (Sweden)

Maria Cristina TIMAR

2011-03-01

Full Text Available FTIR spectroscopy was used in this work for studying the penetration of some consolidants frequentlyused in old wood conservation into test pieces of sound spruce wood (Picea abies wood. Thin microsections(30-60 μm of control and treated wood were analysed in reflectance mode using an ATR system. Theconsolidation products investigated were Paraloid B72, bee wax, a mixture of bee wax / linseed oil and twotypes of paraffins. These products presented FTIR spectra with characteristic common and specific bands,allowing their identification in the treated wood with no impediments coming from their colour, transparencyor the percent of cell lumena filling. The treatment of wood with these products brought about alterations ofthe spectra aspect by the appearance or intensification of some characteristic bands and the modification ofthe ratio between the areas of some characteristic absorption bands so that a qualitative and semiquantitativeevaluation of the presence and penetration depth and distribution of these consolidationproducts in wood was possible, proving the adopted method as valuable and useful for further research inthis field.

Preliminary studies of Brazilian wood using different radioisotopic sources

Energy Technology Data Exchange (ETDEWEB)

Carvalho, Gilberto; Silva, Leonardo Gondim de Andrade e, E-mail: gcarval@ipen.br, E-mail: ftgasilva@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2013-07-01

Due to availability and particular features, wood was one of the first materials used by mankind with a wide variety of applications. It can be used as raw material for paper and cellulose manufacturing; in industries such as chemical, naval, furniture, sports goods, toys, and musical instrument; in building construction and in the distribution of electric energy. Wood has been widely researched; therefore, wood researchers know that several aspects such as temperature, latitude, longitude, altitude, sunlight, soil, and rainfall index interfere with the growth of trees. This behavior explains why average physical-chemical properties are important when wood is studied. The majority of researchers consider density to be the most important wood property because of its straight relationship with the physical and mechanical properties of wood. There are three types of wood density: basic, apparent and green. The apparent density was used here at 12% of moisture content. In this study, four different types of wood were used: 'freijo', 'jequetiba', 'muiracatiara' and 'ipe'. For wood density determination by non-conventional method, Am-241, Ba-133 and Cs-137 radioisotopic sources; a NaI scintillation detector and a counter were used. The results demonstrated this technique to be quick and accurate. By considering the nuclear parameters obtained as half value layers and linear absorption coefficients, Cs-137 radioisotopic source demonstrated to be the best option to be used for inspection of the physical integrity of electric wooden poles and live trees for future works. (author)

Possibilities of producing sundry wood-plastic articles by different methods

International Nuclear Information System (INIS)

Pesek, M.

1978-01-01

In making wood-plastic materials, i.e., the combination of wood and polymers, wood is impregnated by a polymerizable mixture; the incorporated mixture may be polymerized by ionizing radiation or by chemical initiation or by a combination of both. The advantages and drawbacks of the individual procedures are described. Examples are shown of the preparation of small wood-plastic articles, e.g., mosaic parquets, parts of music instruments, handles, etc., cured in a rotary curing container. (author)

Mechanical properties of moso bamboo treated with chemical agents

Science.gov (United States)

Benhua Fei; Zhijia Liu; Zehui Jiang; Zhiyong Cai

2013-01-01

Bamboo is a type of biomass material and has great potential as a bioenergy resource for the future in China. Surface chemical and thermal–mechanical behavior play an important role in the manufacturing process of bamboo composites and pellets. In this study, moso bamboo was treated by sodium hydrate solution and acetic acid solution. Surface chemical and dynamic...

A Study on the Effect of Plasma Treatment for Waste Wood Biocomposites

Directory of Open Access Journals (Sweden)

MiMi Kim

2013-01-01

Full Text Available The surface modification of wood powder by atmospheric pressure plasma treatment was investigated. The composites were manufactured using wood powder and polypropylene (wood powder: polypropylene = 55 wt% : 45 wt%. Atmospheric pressure plasma treatment was applied under the condition of 3 KV, 17±1 KHz, 2 g/min. Helium was used as the carrier gas and hexamethyl-disiloxane (HMDSO as the monomer to modify the surface property of the waste wood biocomposites by plasma polymerization. The tensile strengths of untreated waste wood powder (W3 and single species wood powder (S3 were about 18.5 MPa and 21.5 MPa while those of plasma treated waste wood powder (PW3 and plasma treated single species wood powder (PS3 were about 21.2 MPa and 23.4 MPa, respectively. Tensile strengths of W3 and S3 were improved by 14.6% and 8.8%, respectively. From the analyses of mechanical properties and morphology, we conclude that the interfacial bonding of polypropylene and wood powder can be improved by atmospheric pressure plasma treatment.

Properties of Eucalyptus benthamii wood for energy production

Directory of Open Access Journals (Sweden)

Dimas Agostinho Silva

2015-12-01

Full Text Available The objective of this study was to evaluate the energy potential of Eucalyptus benthamii Maiden et Cambage wood. The samples were collected in the municipality of Cerro Negro, Santa Catarina State, Brazil. Samples were collected from 5 trees at 0%, 25%, 50%, 75% and 100% of commercial height. It was determined basic density, high calorific value, elemental composition, immediate chemical analysis, lower calorific value, energy density, carbon storage and energy production. The physical and chemical variables studied and energy potential of wood did not present differences along the stem.

Assessment of chemical and material contamination in waste wood fuels--A case study ranging over nine years.

Science.gov (United States)

Edo, Mar; Björn, Erik; Persson, Per-Erik; Jansson, Stina

2016-03-01

The increased demand for waste wood (WW) as fuel in Swedish co-combustion facilities during the last years has increased the import of this material. Each country has different laws governing the use of chemicals and therefore the composition of the fuel will likely change when combining WW from different origins. To cope with this, enhanced knowledge is needed on WW composition and the performance of pre-treatment techniques for reduction of its contaminants. In this study, the chemical and physical characteristics of 500 WW samples collected at a co-combustion facility in Sweden between 2004 and 2013 were investigated to determine the variation of contaminant content over time. Multivariate data analysis was used for the interpretation of the data. The concentrations of all the studied contaminants varied widely between sampling occasions, demonstrating the highly variable composition of WW fuels. The efficiency of sieving as a pre-treatment measure to reduce the levels of contaminants was not sufficient, revealing that sieving should be used in combination with other pre-treatment methods. The results from this case study provide knowledge on waste wood composition that may benefit its management. This knowledge can be applied for selection of the most suitable pre-treatments to obtain high quality sustainable WW fuels. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Cooling tower wood sampling and analyses: A case study

International Nuclear Information System (INIS)

Haymore, J.L.

1985-01-01

Extensive wood sampling and analyses programs were initiated on crossflow and counterflow cooling towers that have been in service since 1951 and 1955, respectively. Wood samples were taken from all areas of the towers and were subjected to biological, chemical and physical tests. The tests and results for the analyses are discussed. The results indicate the degree of wood deterioration, and areas of the towers which experience the most advanced degree of degradation

NorWood: a gene expression resource for evo-devo studies of conifer wood development.

Science.gov (United States)

Jokipii-Lukkari, Soile; Sundell, David; Nilsson, Ove; Hvidsten, Torgeir R; Street, Nathaniel R; Tuominen, Hannele

2017-10-01

The secondary xylem of conifers is composed mainly of tracheids that differ anatomically and chemically from angiosperm xylem cells. There is currently no high-spatial-resolution data available profiling gene expression during wood formation for any coniferous species, which limits insight into tracheid development. RNA-sequencing data from replicated, high-spatial-resolution section series throughout the cambial and woody tissues of Picea abies were used to generate the NorWood.conGenIE.org web resource, which facilitates exploration of the associated gene expression profiles and co-expression networks. Integration within PlantGenIE.org enabled a comparative regulomics analysis, revealing divergent co-expression networks between P. abies and the two angiosperm species Arabidopsis thaliana and Populus tremula for the secondary cell wall (SCW) master regulator NAC Class IIB transcription factors. The SCW cellulose synthase genes (CesAs) were located in the neighbourhoods of the NAC factors in A. thaliana and P. tremula, but not in P. abies. The NorWood co-expression network enabled identification of potential SCW CesA regulators in P. abies. The NorWood web resource represents a powerful community tool for generating evo-devo insights into the divergence of wood formation between angiosperms and gymnosperms and for advancing understanding of the regulation of wood development in P. abies. © 2017 The Authors. New Phytologist © 2017 New Phytologist Trust.

EFFECTS OF LEACHING MEDIUM ON LEACHABILITY OF WOOD PRESERVING N'N-HYDROXYNAPTHALIMIDE (NHA)

OpenAIRE

Evren Terzi,; Dilek Dogu,; Feyza Kurt,; S. Nami Kartal,; Frederick Green

2012-01-01

Laboratory leaching test procedures usually call for the use of distilled or deionized water; however, treated wood is generally exposed to different types of water, soil, and weather conditions. Thus, factors such as salinity, hardness, pH, temperature etc. might be important in the release of different amounts of biocide compounds. This study evaluates the release of the sodium salt of the calcium precipitating and wood preserving agent N’N-hydroxynapthalimide (NHA) from treated wood specim...

The influence of irradiated wood filler on some properties of polypropylene - wood composites

Directory of Open Access Journals (Sweden)

Điporović-Momčilović Milanka

2007-01-01

Full Text Available The problem of compatibility between the wood filler and thermoplastic matrix is of essential importance in composite production. Numerous methods have been developed for increasing this compatibility, which is still representing a challenging objective of composite research throughout the world. The research into these methods is primarily directed towards their efficiency from the viewpoint of the composite performance and their economical acceptability. The latter is of particular importance for the composite production in the developing countries with respect to the shortage of the corresponding funds. With this respect, the utilization of ionizing radiation might have considerable advantages. In this research, the beech wood flour was irradiated by a dose of 10 kGy of 60Co gamma rays for purpose of provoking the changes by the ionizing effect. The effects of ionizing radiation upon the properties of wood particles have been examined by IR spectroscopy and by determination of contents of hydroxyl groups in wood by acetylating as an indirect method. All these methods have been expected to reveal the chemical effects of the applied radiation treatment. The irradiated and the control wood flour were used in order to produce the samples of composite with polypropylene. The polypropylene-wood flour (PP-WF composites were produced with 40% of wood particles having fraction size 0.3 mm. The melt-blended composites were modified with amido-acrylic acid (AMACA as a new coupling agent synthesized for this propose in amount of 6 wt.% (based on wood filler and successively with 0.05 wt.% (based on PP of organic peroxide during mixing step. The composites containing coupling agents showed superior mechanical properties, compared to the untreated one. The highest extent of improvement of tensile was achieved in PP-WFl composites modified with AMACA coupling agent.

Significance of wood extractives for wood bonding.

Science.gov (United States)

Roffael, Edmone

2016-02-01

Wood contains primary extractives, which are present in all woods, and secondary extractives, which are confined in certain wood species. Extractives in wood play a major role in wood-bonding processes, as they can contribute to or determine the bonding relevant properties of wood such as acidity and wettability. Therefore, extractives play an immanent role in bonding of wood chips and wood fibres with common synthetic adhesives such as urea-formaldehyde-resins (UF-resins) and phenol-formaldehyde-resins (PF-resins). Extractives of high acidity accelerate the curing of acid curing UF-resins and decelerate bonding with alkaline hardening PF-resins. Water-soluble extractives like free sugars are detrimental for bonding of wood with cement. Polyphenolic extractives (tannins) can be used as a binder in the wood-based industry. Additionally, extractives in wood can react with formaldehyde and reduce the formaldehyde emission of wood-based panels. Moreover, some wood extractives are volatile organic compounds (VOC) and insofar also relevant to the emission of VOC from wood and wood-based panels.

X-ray initiated polymerization of wood impregnants

Energy Technology Data Exchange (ETDEWEB)

Cleland, Marshall R.; Galloway, Richard A. [IBA Industrial, Inc., Edgewood, NY (United States); Berejka, Anthony J. [Ionicorp, Huntington, NY 11743 (United States)], E-mail: berejka@msn.com; Montoney, Daniel [Strathmore Products, Syracuse, NY (United States); Driscoll, Mark; Smith, Leonard; Scott Larsen, L. [State University of New York, SUNY-ESF, Syracuse, NY (United States)

2009-07-15

X-rays, derived from a high energy, high-current electron beam (EB), initiated in-situ polymerization of a unique class of monomers that were found to penetrate the cell walls of wood. X-rays initiated an auto-catalytic acrylic polymerization and penetrated through thick pieces of wood. The final cured product having the polymerizate, a polymer, both in the wood cell lumens and in the cell walls is called wood impregnated with a wood-polymer penetrant (WPP). The controlled lower dose rate of X-rays overcame disproportionation encountered when using higher dose-rate electron beam initiation. With X-rays, the in-situ polymerization took place in one exposure of modest dose. With EB, multiple passes were needed to avoid excessive heat build-up and monomer volatilization. Having entered the cell walls of the wood and then being polymerized within the cell walls, these radiation-cured unique monomers imparted outstanding dimensional stability upon exposure of the impregnated wood to humidity cycling. The preferred monomer system was also chemically modified prior to impregnation with agents that would remain in the wood and prevent the growth of fungi and other microbials. This technique differs from historic uses of monomers that merely filled the lumens of the wood (historic wood-polymer composites), which are only suitable for indoor use. The WPP impregnated wood that was either X-ray cured or EB cured demonstrated enhanced structural properties, dimensional stability, and decay resistance.

X-ray initiated polymerization of wood impregnants

International Nuclear Information System (INIS)

Cleland, Marshall R.; Galloway, Richard A.; Berejka, Anthony J.; Montoney, Daniel; Driscoll, Mark; Smith, Leonard; Scott Larsen, L.

2009-01-01

X-rays, derived from a high energy, high-current electron beam (EB), initiated in-situ polymerization of a unique class of monomers that were found to penetrate the cell walls of wood. X-rays initiated an auto-catalytic acrylic polymerization and penetrated through thick pieces of wood. The final cured product having the polymerizate, a polymer, both in the wood cell lumens and in the cell walls is called wood impregnated with a wood-polymer penetrant (WPP). The controlled lower dose rate of X-rays overcame disproportionation encountered when using higher dose-rate electron beam initiation. With X-rays, the in-situ polymerization took place in one exposure of modest dose. With EB, multiple passes were needed to avoid excessive heat build-up and monomer volatilization. Having entered the cell walls of the wood and then being polymerized within the cell walls, these radiation-cured unique monomers imparted outstanding dimensional stability upon exposure of the impregnated wood to humidity cycling. The preferred monomer system was also chemically modified prior to impregnation with agents that would remain in the wood and prevent the growth of fungi and other microbials. This technique differs from historic uses of monomers that merely filled the lumens of the wood (historic wood-polymer composites), which are only suitable for indoor use. The WPP impregnated wood that was either X-ray cured or EB cured demonstrated enhanced structural properties, dimensional stability, and decay resistance.

Preparation of coloured wood plastics

International Nuclear Information System (INIS)

Lebedev, V.T.; Filippova, T.G.; Rajchuk, F.Z.

1977-01-01

A study has been made into the possibility of using fat, as well as alcohol- and water-soluble dyes for radiation-chemical dying of polymers and plastics filled with wood. The use of fat-soluble azo and anthraquinone dyes permits obtaining intensely colored wood-plastic materials based on methyl methacrylate by way of gamma radiation with doses of up to 3 Mrad. At a dose above 5 Mrad, a marked tarnishing of the dye or a change in color and stains are observed. Dyes in styrene withstand higher radiation doses without any significant destruction

Nanoreinforced biocompatible hydrogels from wood hemicelluloses and cellulose whiskers

Science.gov (United States)

Muzaffer Ahmet Karaaslan; Mandla A. Tshabalala; Daniel J. Yelle; Gisela Buschle-Diller

2011-01-01

Nanoreinforced hydrogels with a unique network structure were prepared from wood cellulose whiskers coated with chemically modified wood hemicelluloses. The hemicelluloses were modified with 2-hydroxyethylmethacrylate prior to adsorption onto the cellulose whiskers in aqueous medium. Synthesis of the hydrogels was accomplished by in situ radical polymerization of the...

Wood-ash addition on a drained forest peatland in Southern Sweden - Effects on water chemistry; Tillfoersel av biobra ensleaska i tallskog paa en dikad torvmark i soedra Sverige - Effekter paa vattenkemin

Energy Technology Data Exchange (ETDEWEB)

Ring, Eva; Broemssen, Claudia von; Losjoe, Katarina; Sikstroem Ulf

2012-02-15

Wood ash can be used for forest fertilization on peatlands or for nutrient compensation following intensive harvesting. This project was performed in order to investigate effects on water chemistry of applying wood ash to a Scots pine stand on a drained peatland. Ditch-water chemistry was monitored before and after the application of wood ash. Furthermore, groundwater was collected and chemically analyzed both from the ash-treated peatland and from an adjacent untreated reference peatland. Both short term (a few months) and more long term effects (up to three years after application) were detected on water chemistry

Mechanical properties of chemically modified portuguese pinewood

OpenAIRE

Lopes, Duarte B; Mai, Carsten; Militz, Holger

2014-01-01

To turn wood into a construction material with enhanced properties, many methods of chemical modification have been developed in the last few decades. In this work, mechanical properties of pine wood were chemically modified, compared and evaluated. Maritime pine wood (Pinus pinaster) was modified with four chemical processes: 1,3-dimethylol-4,5- dihydroxyethyleneurea, N-methylol melamine formaldehyde, tetra-alkoxysilane and wax. The following mechanical properties were assessed experiment...

Cone calorimeter tests of wood-based decking materials

Science.gov (United States)

Robert H. White; Mark A. Dietenberger; Nicole M. Stark

2007-01-01

New technologies in building materials have resulted in the use of a wide variety of materials in decks. As part of our effort to address fire concerns in the wildland-urban interface, the Forest Products Laboratory has been examining the fire performance of decking products. In addition to preservative-treated wood, decking products include wood-plastic composites and...

Irradiation effects in wood and cellulose

International Nuclear Information System (INIS)

McLaren, K.G.

1976-01-01

For cellulosic materials the predominant effect of high energy radiation is depolymerisation and degradation by chain scission, although there is some evidence that crosslinking or cellulose stabilisation can occur under certain conditions. When the cellulose is in the form of a natural product such as wood, where it is intimately associated with other polysaccharides, lignins, resins and gums, the effects of radiation can be significantly modified. Examination of cellulose produced by chemical pulping treatment of wood which had been previously given small doses of radiation, showed significant differences in the extent of cellulose depolymerisation with different wood species. The relevance of this work to the paper pulp industry will also be discussed. (author)

PREPARATION AND CHARACTERIZATION OF COMPOSITES COMPRISING MODIFIED HARDWOOD AND WOOD POLYMERS/POLY(VINYL CHLORIDE

Directory of Open Access Journals (Sweden)

Ruxanda Bodîrlău

Full Text Available Chemical modification of hardwood sawdust from ash-tree species was carried out with a solution of maleic anhydride in acetone. Wood polymers, lignin, and cellulose were isolated from the wood sawdust and modified by the same method. Samples were characterized by Fourier transform infrared spectroscopy (FTIR, providing evidence that maleic anhydride esterifies the free hydroxyl groups of the wood polymer components. Composites comprising chemically modified wood sawdust and wood polymers (cellulose, lignin-as variable weight percentages-, and poly (vinyl chloride were obtained and further characterized by using FTIR spectroscopy and scanning electron microscopy (SEM. The thermal behavior of composites was investigated by using the thermogravimetric analysis (TGA. In all cases, thermal properties were affected by fillers addition.

Utilization of poplar wood sawdust for heavy metals removal from model solutions

Directory of Open Access Journals (Sweden)

Demcak Stefan

2017-06-01

Full Text Available Some kinds of natural organic materials have a potential for removal of heavy metal ions from wastewater. It is well known that cellulosic waste materials or by-products can be used as cheap adsorbents in chemical treatment process. In this paper, poplar wood sawdust were used for removal of Cu(II, Zn(II and Fe(II ions from model solutions with using the static and dynamic adsorption experiments. Infrared spectrometry of poplar wood sawdust confirmed the presence of the functional groups which correspond with hemicelluloses, cellulose and lignin. At static adsorption was achieved approximately of 80 % efficiency for all treated model solutions. Similar efficiency of the adsorption processes was reached after 5 min at dynamic condition. The highest efficiency of Cu(II removal (98 % was observed after 30 min of dynamic adsorption. Changes of pH values confirmed a mechanism of ion exchange on the beginning of the adsorption process.

Incorporation of treated straw and wood fly ash into clay building brick

DEFF Research Database (Denmark)

Chen, Wan; Ottosen, Lisbeth M.; Jensen, Pernille Erland

2016-01-01

High Cd content in straw and wood fly ash, generated from biomass-fired power plants, prohibits its recycling as fertilizer spreading on the landfilled. To improve and alter the current mainstream of fly ash treatment by landfilling, different approaches were tried for treatment of straw and wood...... fly ash, such as washing with water to quickly recover the highly soluble salts (mainly K and Cl), and treatment of the washed fly ash with elevated heavy metal content resulted from washing by electrodialytic remediation (EDR). The finding that SiO2 (quartz) accounted for a significant portion...

Evaluation of wood species and preservatives for WisDOT sign posts.

Science.gov (United States)

2013-10-01

The Wisconsin Department of Transportation (WisDOT) uses preservative-treated wood posts for much of the signage along state highways because wood is relatively inexpensive, easy to install, and has the necessary strength properties to tolerate typic...

Remarks on orthotropic elastic models applied to wood

Directory of Open Access Journals (Sweden)

Nilson Tadeu Mascia

2006-09-01

Full Text Available Wood is generally considered an anisotropic material. In terms of engineering elastic models, wood is usually treated as an orthotropic material. This paper presents an analysis of two principal anisotropic elastic models that are usually applied to wood. The first one, the linear orthotropic model, where the material axes L (Longitudinal, R( radial and T(tangential are coincident with the Cartesian axes (x, y, z, is more accepted as wood elastic model. The other one, the cylindrical orthotropic model is more adequate of the growth caracteristics of wood but more mathematically complex to be adopted in practical terms. Specifically due to its importance in wood elastic parameters, this paper deals with the fiber orientation influence in these models through adequate transformation of coordinates. As a final result, some examples of the linear model, which show the variation of elastic moduli, i.e., Young´s modulus and shear modulus, with fiber orientation are presented.

Identification of Four Wood Species by an Electronic Nose and by LIBS

Directory of Open Access Journals (Sweden)

Juliana R. Cordeiro

2012-01-01

Full Text Available This paper presents two complementary methods capable of identifying four wood species (Cedrela fissilis, Ocotea porosa, Hymenolobium petraeum, and Aspidosperma subincanum both by their volatile organic compounds and by the presence of 10 chemical elements: Al, B, Ca, Mg, Zn, Cu, Mn, Fe, Na, and Si. The volatile compounds were detected by an electronic nose formed by an array of three different conductive polymer gas sensors. The elemental determination was made by laser-induced breakdown spectrometry (LIBS. The emissions measured were treated by principal component analysis (PCA. Leave-one-out analysis showed a rate of hits of 100%.

Wood handbook : wood as an engineering material

Science.gov (United States)

Robert J. Ross; Forest Products Laboratory. USDA Forest Service.

2010-01-01

Summarizes information on wood as an engineering material. Presents properties of wood and wood-based products of particular concern to the architect and engineer. Includes discussion of designing with wood and wood-based products along with some pertinent uses.

Transformation and Release of Micronized Cu Used as a Wood Preservative in Treated Wood in Wetland Soil.

Science.gov (United States)

Micronized Cu (µ-Cu) is used as a wood preservative, replacing toxic Chromated Copper Arsenates. Micronized Cu is Malachite [Cu2CO3(OH)2] that has been milled to micron/submicron particles, many with diameters less than 100 nm, and then mixed with quat or azol biocides. I...

Protection of Wood from Microorganisms by Laccase-Catalyzed Iodination

Science.gov (United States)

Engel, J.; Thöny-Meyer, L.; Schwarze, F. W. M. R.; Ihssen, J.

2012-01-01

In the present work, Norway spruce wood (Picea abies L.) was reacted with a commercial Trametes versicolor laccase in the presence of potassium iodide salt or the phenolic compounds thymol and isoeugenol to impart an antimicrobial property to the wood surface. In order to assess the efficacy of the wood treatment, a leaching of the iodinated and polymerized wood and two biotests including bacteria, a yeast, blue stain fungi, and wood decay fungi were performed. After laccase-catalyzed oxidation of the phenols, the antimicrobial effect was significantly reduced. In contrast, the enzymatic oxidation of iodide (I−) to iodine (I2) in the presence of wood led to an enhanced resistance of the wood surface against all microorganisms, even after exposure to leaching. The efficiency of the enzymatic wood iodination was comparable to that of a chemical wood preservative, VP 7/260a. The modification of the lignocellulose by the laccase-catalyzed iodination was assessed by the Fourier transform infrared spectroscopy-attenuated total reflectance (FTIR-ATR) technique. The intensities of the selected lignin-associated bands and carbohydrate reference bands were analyzed, and the results indicated a structural change in the lignin matrix. The results suggest that the laccase-catalyzed iodination of the wood surface presents an efficient and ecofriendly method for wood protection. PMID:22865075

Health assessment for Southern Maryland Wood Treating (SMWT) National Priorities List (NPL) Site, Hollywood, St. Mary's County, Maryland, Region 3. CERCLIS No. MDD980704852. Final report

Energy Technology Data Exchange (ETDEWEB)

1989-04-10

The Southern Maryland Wood Treating National Priorities List site is located in Hollywood, St. Mary's County, Maryland. Approximately 12,000 gallons of dioxin-contaminated wastes and 2,000 gallons of wastes contaminated with volatile organic compounds or polynuclear aromatic hydrocarbons, or both, remain in on-site tanks used during wood treatment operations. Until remediation of the site is completed there is a potential public health concern from dermal absorption, ingestion, or inhalation of contaminants from groundwater, surface water, sediments, soil, and contaminated on-site structures.

Characterization of wood-based molding bonded with citric acid

OpenAIRE

Umemura, Kenji; Ueda, Tomohide; Kawai, Shuichi

2012-01-01

The wood-based moldings were fabricated by using only citric acid as an adhesive. The mechanical properties, water resistances, thermal properties and chemical structure were investigated. Wood powder obtained from Acacia mangium was mixed with citric acid under certain weight ratios (0-40 wt%), and each powder mixture was molded using two types of metal molds at 200 °C and 4MPa for 10 min. The modulus of rupture (MOR) and the modulus of elasticity (MOE) values of the wood-based molding conta...

Wood-thermoplastic composites manufactured using beetle-killed spruce from Alaska

Science.gov (United States)

V. Yadama; Eini Lowell; N. Petersen; D. Nicholls

2009-01-01

The primary objectives of the study were to characterize the critical properties of wood flour produced using highly deteriorated beetle-killed spruce for wood-plastic composite (WPC) production and evaluate important mechanical and physical properties of WPC extruded using an industry standard formulation. Chemical composition analysis indicated no significant...

WOOD PROPERTIES AND EFFECT OF WOOD PROPERTIES ON THE WOOD FINISHING

Directory of Open Access Journals (Sweden)

Abdulkadir Malkoçoğlu

2006-04-01

Full Text Available Wood is basic raw material for furniture and joinery industries with wood structures. Wood is a biological material that has widely different properties depending on species, geographic area where the tree grew, the growth condition, size of the tree at harvest, sawing, and other manufacturing processes. Wood properties have been characterized within two groups as natural and manufacturing factors that effects finishing performance. Grow rate, density, knots, moisture content, extractives and juvenile wood are natural characteristics. Grain orientation, texture, drying and performance expectations are manufacturing characteristics. In this review, the effects of natural and manufacturing characteristics are discussed on the surface finishing performance of wood.

Micronized copper wood preservatives: An efficiency and potential health risk assessment for copper-based nanoparticles

International Nuclear Information System (INIS)

Civardi, Chiara; Schwarze, Francis W.M.R.; Wick, Peter

2015-01-01

Copper (Cu) is an essential biocide for wood protection, but fails to protect wood against Cu-tolerant wood-destroying fungi. Recently Cu particles (size range: 1 nm–25 μm) were introduced to the wood preservation market. The new generation of preservatives with Cu-based nanoparticles (Cu-based NPs) is reputedly more efficient against wood-destroying fungi than conventional formulations. Therefore, it has the potential to become one of the largest end uses for wood products worldwide. However, during decomposition of treated wood Cu-based NPs and/or their derivate may accumulate in the mycelium of Cu-tolerant fungi and end up in their spores that are dispersed into the environment. Inhaled Cu-loaded spores can cause harm and could become a potential risk for human health. We collected evidence and discuss the implications of the release of Cu-based NPs by wood-destroying fungi and highlight the exposure pathways and subsequent magnitude of health impact. - Highlights: • We compared copper particulate wood preservatives with conventional ones. • We assessed the fungicidal activity of particulate copper wood preservatives. • We reviewed the Cu-tolerance mechanisms of some wood-destroying fungi. • Fungi colonizing wood treated with particulate copper may release Cu-loaded spores. - We assess the fungicidal activity of particulate copper wood preservatives and their possible release in the air by Cu-tolerant wood-destroying fungi

Thermo-Chemical Conversion of Microwave Activated Biomass Mixtures

Science.gov (United States)

Barmina, I.; Kolmickovs, A.; Valdmanis, R.; Vostrikovs, S.; Zake, M.

2018-05-01

Thermo-chemical conversion of microwave activated wheat straw mixtures with wood or peat pellets is studied experimentally with the aim to provide more effective application of wheat straw for heat energy production. Microwave pre-processing of straw pellets is used to provide a partial decomposition of the main constituents of straw and to activate the thermo-chemical conversion of wheat straw mixtures with wood or peat pellets. The experimental study includes complex measurements of the elemental composition of biomass pellets (wheat straw, wood, peat), DTG analysis of their thermal degradation, FTIR analysis of the composition of combustible volatiles entering the combustor, the flame temperature, the heat output of the device and composition of the products by comparing these characteristics for mixtures with unprocessed and mw pre-treated straw pellets. The results of experimental study confirm that mw pre-processing of straw activates the thermal decomposition of mixtures providing enhanced formation of combustible volatiles. This leads to improvement of the combustion conditions in the flame reaction zone, completing thus the combustion of volatiles, increasing the flame temperature, the heat output from the device, the produced heat energy per mass of burned mixture and decreasing at the same time the mass fraction of unburned volatiles in the products.

Mechanical Characteristics of Chemically Degraded Surface Layers of Wood

Czech Academy of Sciences Publication Activity Database

Frankl, Jiří; Kloiber, Michal; Drdácký, Miloš; Tippner, J.; Bryscejn, Jan

2012-01-01

Roč. 2, č. 11 (2012), s. 694-700 ISSN 2159-5275 R&D Projects: GA ČR(CZ) GPP105/11/P628 Institutional support: RVO:68378297 Keywords : wood * corrosion * defibering * mechanical properties Subject RIV: JN - Civil Engineering http://www.davidpublishing.com

Fabrication of superhydrophobic wood surfaces via a solution-immersion process

Science.gov (United States)

Liu, Changyu; Wang, Shuliang; Shi, Junyou; Wang, Chengyu

2011-11-01

Superhydrophobic wood surfaces were fabricated from potassium methyl siliconate (PMS) through a convenient solution-immersion method. The reaction involves a hydrogen bond assembly and a polycondensation process. The silanol was formed by reacting PMS aqueous solution with CO2, which was assembled on the wood surface via hydrogen bonds with the wood surface -OH groups. The polymethylsilsesquioxane coating was obtained through the polycondensation reaction of the hydroxyl between wood and silanol. The morphology of products were characterized using a scanning electron microscope (SEM), the surface chemical composition was determined using energy dispersive X-ray analysis (EDXA), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry (TGA) and contact angle measurement. Analytical results revealed that rough protuberances uniformly covered the wood surface, thus transforming the wood surface from hydrophilic to superhydrophobic. The water contact angle of the superhydrophobic wood surface was about 153° and a sliding angle was 4.6°.

GC-MS Characterizations of Termiticidal Heartwood Extractives from Wood Species Utilized in Pakistan

Science.gov (United States)

Mark Mankowski; Blossie Boyd; Barbar Hassan; Grant T. Kirker

2016-01-01

Wood species that exhibit innate tolerance to wood destroying organisms such as termites are considered to be naturally durable. This durability can, in part, be due to the complex chemical compounds in the heartwood of naturally durable wood species. We examined the effects of varying concentrations of heartwood extractives on the subterranean termite, ...

The international comparative wood treatment study WOAM Freemantle 1987 - Trondheim 2012

DEFF Research Database (Denmark)

Botfeldt, Knud Bo; Petersen, Maj Britt

2016-01-01

The project The international Comparative Wood Treatment Study was developed and launched under ICOM-WOAM by D. Grattan, Canadian Conservation Institute and F. Schweingruber, The Swiss Federal Forestry Institute. The project started in 1983 and at the Woam Conference in Freemantle in 1987 the many....... This paper evaluates and documents changes in the condition of the wood samples from the WOAM project in 1987, with focus on the PEG/water treated samples. In Trondheim, visual assessment and evaluation of the samples was performed, without removing the wood samples from the climate controlled storage...... PEG in the samples. With the exception of the samples treated with low molecular weight PEG (i.e. PEG 400), there are very few and very small changes in the samples 25 years (1987-2012) after treatment. Low molecular weight PEG has a good bulking effect on well-preserved wood, but has a negative...

Liquefaction of aspen poplar wood

Energy Technology Data Exchange (ETDEWEB)

Eager, R L; Mathews, J F; Pepper, J M

1982-01-01

Dried and green aspen poplar wood suspended in water containing alkali catalysts was converted completely to an oil, water-soluble chemical, and gases by heating for 1 hour in the presence of CO in a rocking batch reactor. Within the ranges of parameters studied: temperature of 593-633 K; nominal reaction times of less than or equal to 1 hour; water-to-wood ratio of 0.5:1-5:1; Na/sub 2/CO/sub 3/, K/sub 2/CO/sub 3/, and NaOH catalysts; amount of catalyst 7.0-12.5%; and initial H-CO ratios of 2:1-0:1, the water-to-wood ratio was most important. Oil yields of approximately 50% with a C plus H content of approximately 80% and representing a C recovery of approximately 66% were obtained. The higher heats of combustion were 32.2-36.0 MJ/kg.

Effects of wood chip ash fertilization on soil chemistry in a Norway spruce plantation on a nutrient-poor soil

DEFF Research Database (Denmark)

Ingerslev, Morten; Hansen, Mette; Pedersen, Lars Bo

2014-01-01

of wood chip ash application on soil chemistry in a 44-year-old Norway spruce (Picea abies) plantation on a nutrient-poor soil in Denmark and to investigate the effect of applying different ash types and doses. Soil samples were collected and analyzed 2.5years (3 growing seasons) after ash application....... This study shows that, regardless of ash formulation, preparation or dose, application of wood ash to forest soil has a liming effect in the O-horizon manifested as an increase in CECe, BS and pH. This effect was not seen in the mineral soil within the time frame of this study. At the same time, an increase...... in Cd was found in the O-horizon, corresponding to the amount added in the ashes. Generally, no other increase in soil contents of the heavy metals was seen. Hardening of the wood ash did not decrease the chemical impact on the soil chemistry as compared to non-treated ash whereas an increase in ash...

Use of wood ash in the treatment of high tannin sorghum for poultry ...

African Journals Online (AJOL)

A study was conducted to investigate the effects of wood ash treatment on the nutritional value of high tannin sorghum. High tannin sorghum was either soaked in wood ash slurry and then germinated for four days or soaked in wood ash extract and germinated for 28 hours or germinated after soaking in water. Chemical ...

Health evaluation of volatile organic compound (VOC) emission from exotic wood products

DEFF Research Database (Denmark)

Kirkeskov, L; Witterseh, T; Funch, L W

2009-01-01

The purpose of this study was to measure and evaluate the impact of the emissions of selected products of exotic wood on health. Ten products were screened for chemical compounds, and five of the most used products which emitted more than 800 microg/kg were selected for further quantitative...... analyses by climate chamber measurement (iroko, ramin, sheesham, merbau, and rubber tree). Samples of exotic wood (rubber tree and belalu) were further analyzed for emission of chemical compounds by migration into artificial saliva and for content of pesticides and allergenic natural rubber latex (NR latex......) (rubber tree). The toxicological effects of all substances identified were evaluated and the lowest concentrations of interest (LCI) assessed. An R-value was calculated for each wood product (R-value below 1 is considered to be unproblematic as regards health). Emission from the evaluated exotic wood only...

Wood : adhesives

Science.gov (United States)

A.H. Conner

2001-01-01

This chapter on wood adhesives includes: 1) Classification of wood adhesives 2) Thermosetting wood adhesives 3) Thermoplastic adhesives, 4) Wood adhesives based on natural sources 5) Nonconventional bonding of wood 6) Wood bonding.

Wood ethanol and synthetic natural gas pathways

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-11-30

This report provided details of updates to the wood ethanol pathway recently added to the GHGenius model, an analytical tool used to analyze emissions from conventional and alternative fuel combustion processes. The pathway contains data developed by the United States Department of Energy. A number of co-products were added to the wood and agricultural residue pathways, including furfural, xylitol, lignin, and glycerol. New chemical inputs included nitrogen gas, ammonia, enzymes and yeast. Biological ethanol pathways were reviewed, and separate inputs for wood, agricultural residues, corn ethanol, and wheat ethanol were added. The model was updated to reflect current research conducted on the gasification of wood and the upgrading of the gas to produce pipeline quality natural gas. New process developments in producing pipeline quality gas from coal were also added. The ability to model enzyme consumption was added to all ethanol pathways. 25 refs., 41 tabs., 8 figs.

Wood ethanol and synthetic natural gas pathways

International Nuclear Information System (INIS)

2006-01-01

This report provided details of updates to the wood ethanol pathway recently added to the GHGenius model, an analytical tool used to analyze emissions from conventional and alternative fuel combustion processes. The pathway contains data developed by the United States Department of Energy. A number of co-products were added to the wood and agricultural residue pathways, including furfural, xylitol, lignin, and glycerol. New chemical inputs included nitrogen gas, ammonia, enzymes and yeast. Biological ethanol pathways were reviewed, and separate inputs for wood, agricultural residues, corn ethanol, and wheat ethanol were added. The model was updated to reflect current research conducted on the gasification of wood and the upgrading of the gas to produce pipeline quality natural gas. New process developments in producing pipeline quality gas from coal were also added. The ability to model enzyme consumption was added to all ethanol pathways. 25 refs., 41 tabs., 8 figs

Modeling the Emission of CO from Wood Fires using Detailed Chemical Kinetics

DEFF Research Database (Denmark)

Dederichs, Anne

Carbon monoxide is treated as one of the most common and dangerous of gases evolving in fires. Modeling the formation of the toxic gas CO from in fire enclosures using detailed chemical kinetics is the topic of this manuscript. A semi-empirical model is developed to study the formation of CO from......, the model separately treats the process of pyrolysis and combustion. For under ventilated conditions and at high temperatures during pyrolysis it is found that the process of pyrolysation strongly influences the formation of CO in fire. CO2 follows the same trend....

Chemical characterisation of PM10 emissions from combustion in a closed stove of common woods grown in Portugal

Science.gov (United States)

Gonçalves, C.; Alves, C.; Pio, C.; Rzaca, M.; Schmidl, C.; Puxbaum, H.

2009-04-01

A series of source tests were conducted to determine the wood elemental composition, combustion gases and the chemical constitution of PM10 emissions from the closed stove combustion of four species of woods grown in Portugal: Eucalyptus globulos, Pinus pinaster, Quercus suber and Acacia longifolia. The burning tests were made in a closed stove with a dilution source sampler. To ascertain the combustion phase and conditions, continuous emission monitors measured O2, CO2, CO, NO, hydrocarbons, temperature and pressure, during each burning cycle. Woodsmoke samples have been collected and analysed to estimate the contribution of plant debris and biomass smoke to atmospheric aerosols. At this stage of work, cellulose, anhydrosugars and humic-like substances (HULIS) have been measured. Cellulose was determined photometrically after its conversion to D-Glucose. The determination of levoglucosan and other anhydrosugars, including mannosan and galactosan, was carried out by high performance liquid chromatography with electrochemical detection. HULIS determination was made with a total organic carbon analyser and an infrared non dispersive detector, after the isolation of substances. Cellulose was present in PM10 at mass fractions (w/w) of 0.13%, 0.13%, 0.05% and 0.08% for Eucalyptus globulos, Pinus pinaster, Quercus suber and Acacia longifolia, respectively. Levoglucosan was the major anhydrosugar present in the samples, representing mass fractions of 14.71%, 3.80%, 6.78% and 1.91%, concerning the above mentioned wood species, respectively. The levoglucosan-to-mannosan ratio, usually used to evaluate the proportion of hardwood or softwood smoke in PM10, gave average values of 34.9 (Eucalyptus globulos), 3.40 (Pinus pinaster), 24.8 (Quercus suber) and 10.4 (Acacia longifolia). HULIS were present at mass fractions of 2.35%, 2.99%, 1.52% and 1.72% for the four wood species listed in the same order as before.

Assessment of the potential quality of preservative-treated pilings removed from service : [abstract

Science.gov (United States)

Xiping Wang; John W. Forsman; John R. Erickson; Robert J. Ross; Douglas J. Gardner; Gary D. McGinnis; Rodney C. DeGroot

1999-01-01

Preservative-treated wood products are important construction materials. Preservative-treated wood pilings, after removal from service, constitute a major disposal problem for managers of waterfront facilities. For example, approximately 7,000 to 8,000 tons of mechanically or biologically deteriorated wood pilings are currently removed from U.S. naval facilities...

Environmentally friendly wood preservatives formulated with enzymatic-hydrolyzed okara, copper and/or boron salts

International Nuclear Information System (INIS)

Ahn, Sye Hee; Oh, Sei Chang; Choi, In-gyu; Han, Gyu-seong; Jeong, Han-seob; Kim, Ki-woo; Yoon, Young-ho; Yang, In

2010-01-01

Novel biocides, such as copper azole (CuAz) and ammoniacal copper quaternary (ACQ), are extensively used as substitutes for chromate copper arsenate (CCA) in wood preservation. However, the expense of these biocides has necessitated the development of cost-effective and environmentally friendly wood preservatives. This study was conducted to investigate the effectiveness against decaying fungi of the preservatives formulated with enzymatic-hydrolyzed okara (OK), which is an organic waste produced from the manufacture of tofu, CuCl 2 (CC) and/or Na 2 B 4 O 7 .10H 2 O (B). With the addition of NH 4 OH as a dissociating agent, the addition of OK facilitated the target retention of most of the OK/CC and OK/CC/B preservative formulations in wood blocks. The OK-based wood preservatives (OK-WPs) were stable against hot-water leaching. When compared with control and CC-treated wood blocks, the leached wood blocks treated with OK/CC and OK/CC/B formulations showed excellent decay resistance against both Postia placenta and Gloeophyllum trabeum, especially when OK was hydrolyzed by Celluclast at a loading level of 0.1 ml/g. Scanning electron microscopy (SEM) and SEM-energy dispersive X-ray (SEM-EDX) spectrometry analyses demonstrated that preservative complexes, such as OK-CC and OK-CC-B, existed in the wood blocks treated with OK/CC and OK/CC/B formulations. This study results support the potential application of OK-WPs as environmentally friendly wood preservatives capable of replacing CuAz and ACQ.

Environmentally friendly wood preservatives formulated with enzymatic-hydrolyzed okara, copper and/or boron salts

Energy Technology Data Exchange (ETDEWEB)

Ahn, Sye Hee; Oh, Sei Chang [Department of Forest Resources, Daegu University, Gyeongsan 712-714 (Korea, Republic of); Choi, In-gyu [Department of Forest Sciences, Seoul National University, Seoul 151-921 (Korea, Republic of); Han, Gyu-seong [Department of Wood and Paper Sciences, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Jeong, Han-seob [Department of Forest Sciences, Seoul National University, Seoul 151-921 (Korea, Republic of); Kim, Ki-woo [National Instrumentation Center for Environmental Management, Seoul National University, Seoul 151-921 (Korea, Republic of); Yoon, Young-ho [KCI Co. Ltd., Seosan, Chungcheongnam-do 356-874 (Korea, Republic of); Yang, In, E-mail: dahadad2000@yahoo.com [Research Institute for Agriculture and Life Sciences, Seoul National University, San 56-1 Sillim-Dong, Kwanak-gu, Seoul 151-921 (Korea, Republic of)

2010-06-15

Novel biocides, such as copper azole (CuAz) and ammoniacal copper quaternary (ACQ), are extensively used as substitutes for chromate copper arsenate (CCA) in wood preservation. However, the expense of these biocides has necessitated the development of cost-effective and environmentally friendly wood preservatives. This study was conducted to investigate the effectiveness against decaying fungi of the preservatives formulated with enzymatic-hydrolyzed okara (OK), which is an organic waste produced from the manufacture of tofu, CuCl{sub 2} (CC) and/or Na{sub 2}B{sub 4}O{sub 7}.10H{sub 2}O (B). With the addition of NH{sub 4}OH as a dissociating agent, the addition of OK facilitated the target retention of most of the OK/CC and OK/CC/B preservative formulations in wood blocks. The OK-based wood preservatives (OK-WPs) were stable against hot-water leaching. When compared with control and CC-treated wood blocks, the leached wood blocks treated with OK/CC and OK/CC/B formulations showed excellent decay resistance against both Postia placenta and Gloeophyllum trabeum, especially when OK was hydrolyzed by Celluclast at a loading level of 0.1 ml/g. Scanning electron microscopy (SEM) and SEM-energy dispersive X-ray (SEM-EDX) spectrometry analyses demonstrated that preservative complexes, such as OK-CC and OK-CC-B, existed in the wood blocks treated with OK/CC and OK/CC/B formulations. This study results support the potential application of OK-WPs as environmentally friendly wood preservatives capable of replacing CuAz and ACQ.

Preliminary investigation of biological resistance, water absorption and swelling of thermally compressed pine wood panels

Science.gov (United States)

Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel Arango; Carol A. Clausen; Frederick Green

2008-01-01

Wood can be modified by compressive, thermal and chemical treatments. Compression of wood under thermal conditions is resulted in densification of wood. This study evaluated decay and termite resistance of thermally compressed pine wood panels at either 5 or 7 MPa and at either 120 or 150°C for one hour. The process caused increases in density and decreases in...

Determination of Cr(VI) in wood specimen: A XANES study at the Cr K edge

International Nuclear Information System (INIS)

Strub, E.; Plarre, R.; Radtke, M.; Reinholz, U.; Riesemeier, H.; Schoknecht, U.; Urban, K.; Juengel, P.

2008-01-01

The content of chromium in different oxidation states in chromium-treated wood was studied with XANES (X-ray absorption near-edge structure) measurements at the Cr K absorption edge. It could be shown that wood samples treated with Cr(VI) (pine and beech) did still contain a measurable content of Cr(VI) after four weeks conditioning. If such wood samples were heat exposed for 2 h with 135 deg. C prior conditioning, Cr(VI) was no longer detected by XANES, indicating a complete reduction to chromium (III)

Effects of Chemical Curing Temperature and Time on the Properties of Liquefied Wood based As-cured Precursors and Carbon Fibers

Directory of Open Access Journals (Sweden)

Junbo Shang

2015-09-01

Full Text Available Liquefied wood based as-cured precursors and carbon fibers prepared by different chemical curing processes were carried out to investigate the effects of curing temperature and time on the thermostability and microstructure of liquefied wood based precursors, the tensile strength of carbon fibers as well. The primary fibers can be converted into precursors with high performance by directly heating at target curing temperature. With the temperature and duration increasing, the numbers of methylene bonds in precursors increased, resulting in the enhancement of cross-linkages among molecular chains and then the improvement of thermostability of precursors. Carbon fibers prepared from as-cured precursors (curing temperature 95 oC, curing time 3h had the minimum value of the average interlayer spacing (d002, it also showed the highest tensile strength, almost 800 MPa, which can be classified as fibers of general grade.

Study of UV curing in the wood industry

International Nuclear Information System (INIS)

Haider Osama Al-Mahdi

1999-01-01

Although mass production is the primary demand, the wood finishing must nevertheless conform to certain minimal standards. The surface should be protected and sealed against heat, dirt and abrasion, and insulated from the ingress and evaporation of moisture which would cause dimensional changes in the timber. The finish should be clear (unclouded) and smooth to enhance the natural beauty of the figure and the grain. The finish should also maintain its appearance, and adhesion, as well as protection given to the wood. The film should not seriously be degrading during the lifetime of the article. All the standards mentioned above are available in the 100% solid acrylic UV finishing system. A thorough study of the timber wood anatomy and of the physical and chemical properties of polymerized film is essential in order to match these properties with the wood substrate

Wood Pulp Digetster Wall Corrosion Investigation

Energy Technology Data Exchange (ETDEWEB)

Giles, GE

2003-09-18

The modeling of the flow in a wood pulp digester is but one component of the investigation of the corrosion of digesters. This report describes the development of a Near-Wall-Model (NWM) that is intended to couple with a CFD model that determines the flow, heat, and chemical species transport and reaction within the bulk flow of a digester. Lubrication theory approximations were chosen from which to develop a model that could determine the flow conditions within a thin layer near the vessel wall using information from the interior conditions provided by a CFD calculation of the complete digester. The other conditions will be determined by coupled solutions of the wood chip, heat, and chemical species transport and chemical reactions. The NWM was to couple with a digester performance code in an iterative fashion to provide more detailed information about the conditions within the NW region. Process Simulations, Ltd (PSL) is developing the digester performance code. This more detailed (and perhaps more accurate) information from the NWM was to provide an estimate of the conditions that could aggravate the corrosion at the wall. It is intended that this combined tool (NWM-PSL) could be used to understand conditions at/near the wall in order to develop methods to reduce the corrosion. However, development and testing of the NWM flow model took longer than anticipated and the other developments (energy and species transport, chemical reactions and linking with the PSL code) were not completed. The development and testing of the NWM are described in this report. In addition, the investigation of the potential effects of a clear layer (layer reduced in concentration of wood chips) near the wall is reported in Appendix D. The existence of a clear layer was found to enhance the flow near the wall.

Starch inclusion complex to emulsify cedarwood oil and pressure treat wood

Science.gov (United States)

Previously, we have demonstrated that CO2-derived cedarwood oil has a range of bioactivities, including insect repellency and toxicity as well as conferring resistance to both termites and wood-rot fungi. In the earlier pressure treatment work, ethanol was used as the diluent/carrier. However, it is...

A brief review of machine vision in the context of automated wood identification systems

Science.gov (United States)

John C. Hermanson; Alex C. Wiedenhoeft

2011-01-01

The need for accurate and rapid field identification of wood to combat illegal logging around the world is outpacing the ability to train personnel to perform this task. Despite increased interest in non-anatomical (DNA, spectroscopic, chemical) methods for wood identification, anatomical characteristics are the least labile data that can be extracted from solid wood...

Effects of permethrin treated wood on the subterranean termite Reticulitermes flavipes (Kollar) and comparison of solvent extraction for HPLC analysis of permethrin in wood

Science.gov (United States)

Mark Mankowski; Blossie Boyd; Geoffrey Webb

2016-01-01

Permethrin is a common insecticide used in wood preservation. It is an effective synthetic pyrethroid that is considered to be less toxic to higher organisms than organochlorine insecticides. In wood preservation, it can be used in combination with fungicides such as 3-iodo-2-propynyl butyl carbamate (IPBC). Permethrin has a dual mode of action as it is a repellent and...

Evaluation of wood species and preservatives for Wisconsin transportation sign posts : [research brief].

Science.gov (United States)

2013-12-01

The Wisconsin Department of Transportation (WisDOT) administers approximately 11,800 miles of state highways. It uses preservative-treated wood posts for much of the signage along these highways because wood is relatively inexpensive, easy to install...

Tolerance of Serpula lacrymans to copper-based wood preservatives

DEFF Research Database (Denmark)

Hastrup, Anne Christine Steenkjær; Green, Frederick; Clausen, Carol A.

2005-01-01

construction, but some decay fungi are known to be copper tolerant. In this study, soil-block tests were undertaken to clarify the effect of copper, copper citrate, and alkaline copper quaternary-type D (ACQ-D) on the decay capabilities of S. lacrymans compared with an alternative wood preservative......Serpula lacrymans, the dry rot fungus, is considered the most economically important wood decay fungus in certain temperate regions of the world, namely northern Europe, Japan, and Australia. Previously, copper-based wood preservatives were commonly used for pressure treatment of wood for building...... not containing copper. Twelve isolates of the dry rot fungus S. lacrymans and four other brown-rot species were evaluated for weight loss on wood treated with 1.2% copper citrate, 0.5% ACQ-D, and 0.5% naphthaloylhydroxylamine (NHA). Eleven out of 12 isolates of S. lacrymans were shown to be tolerant towards...

Gene Expression Analysis of Copper Tolerance and Wood Decay in the Brown Rot Fungus Fibroporia radiculosa

Science.gov (United States)

J. D. Tang; L. A. Parker; A. D. Perkins; T. S. Sonstegard; S. G. Schroeder; D. D. Nicholas; S. V. Diehl

2013-01-01

High-throughput transcriptomics was used to identify Fibroporia radiculosa genes that were differentially regulated during colonization of wood treated with a copper-based preservative. The transcriptome was profiled at two time points while the fungus was growing on wood treated with micronized copper quat (MCQ). A total of 917 transcripts were...

Characteristics of wood ash and influence on soil properties and nutrient uptake: an overview.

Science.gov (United States)

Demeyer, A; Voundi Nkana, J C; Verloo, M G

2001-05-01

Wood industries and power plants generate enormous quantities of wood ash. Disposal in landfills has been for long a common method for removal. New regulations for conserving the environment have raised the costs of landfill disposal and added to the difficulties for acquiring new sites for disposal. Over a few decades a number of studies have been carried out on the utilization of wood ashes in agriculture and forestry as an alternative method for disposal. Because of their properties and their influence on soil chemistry the utilization of wood ashes is particularly suited for the fertility management of tropical acid soils and forest soils. This review principally focuses on ash from the wood industry and power plants and considers its physical, chemical and mineralogical characteristics, its effect on soil properties, on the availability of nutrient elements and on the growth and chemical composition of crops and trees, as well as its impact on the environment.

From laboratory corrosion tests to a corrosion lifetime for wood fasteners : progress and challenges

Science.gov (United States)

Samuel L. Zelinka; Dominique Derome; Samuel V. Glass

2010-01-01

Determining a “corrosion-lifetime” for fasteners embedded in wood treated with recently adopted preservative systems depends upon successfully relating results of laboratory tests to in-service conditions. In contrast to laboratory tests where metal is embedded in wood at constant temperature and moisture content, the in-service temperature and moisture content of wood...

Wood-polymer composites obtained by gamma radiation

International Nuclear Information System (INIS)

Gago, Javier; Lopez, Alcides; Rodriguez, Juan; Universidad Nacional de Ingenieria, Lima; Acevedo, Moises; Santiago, Julio; Universidad Nacional Mayor de San Marcos, Lima

2006-01-01

It has been prepared composites materials by means of monomer penetration in pores of wood samples and later curing by means of gamma irradiation. The studied species were Hura crepitans L. (catahua), Aniba puchury-minor (C. Martinez) (mohena amarilla), and Calycophyllum spruceanum (Benth.) (capirona). These new materials exhibit smaller water absorption and better mechanical properties in comparison with native wood. The test tubes of catahua treated with the styrene-polyester mixture absorb only up to 10% humidity compared to the native species whereas its hardness is increased in a 100%. (author)

A solution-state NMR approach to elucidating pMDI-wood bonding mechanisms in loblolly pine

Science.gov (United States)

Daniel Joseph Yelle

2009-01-01

Solution-state NMR spectroscopy is a powerful tool for unambiguously determining the existence or absence of covalent chemical bonds between wood components and adhesives. Finely ground wood cell wall material dissolves in a solvent system containing DMSO-d6 and NMI-d6, keeping wood component polymers intact and in a near-...

Cord Wood Testing in a Non-Catalytic Wood Stove

Energy Technology Data Exchange (ETDEWEB)

Butcher, T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Trojanowski, R. [Brookhaven National Lab. (BNL), Upton, NY (United States); Wei, G. [Brookhaven National Lab. (BNL), Upton, NY (United States)

2014-06-30

EPA Method 28 and the current wood stove regulations have been in-place since 1988. Recently, EPA proposed an update to the existing NSPS for wood stove regulations which includes a plan to transition from the current crib wood fuel to cord wood fuel for certification testing. Cord wood is seen as generally more representative of field conditions while the crib wood is seen as more repeatable. In any change of certification test fuel, there are questions about the impact on measured results and the correlation between tests with the two different fuels. The purpose of the work reported here is to provide data on the performance of a noncatalytic stove with cord wood. The stove selected has previously been certified with crib wood which provides a basis for comparison with cord wood. Overall, particulate emissions were found to be considerably higher with cord wood.

Differential sensitivity to the antifouling chemical medetomidine between wood frog and American toad tadpoles with evidence for low-dose stimulation and high-dose inhibition of metamorphosis.

Science.gov (United States)

Fong, Peter P; Lambert, Olivia J; Hoagland, Margot L; Kurtz, Emily R

2018-05-05

Antifouling chemicals are legacy contaminants in aquatic ecosystems. Previous experiments have shown that a 14-day exposure to the antifouling chemical medetomidine delays metamorphosis and reduces body mass in wood frog tadpoles. In the present study, we exposed wood frog tadpoles to medetomidine for 3, 7, and 10 days at 100 nM, 1 μM, and 10 μM. We also exposed American toad tadpoles to medetomidine for 3 days at four concentrations (10 nM, 100 nM, 1 μM, and 10 μM) in static renewal experiments. In each experiment, we measured growth, frequency and time to metamorphosis, and mass at metamorphosis. In both species, medetomidine significantly slowed development as measured by the Gosner stage. After 34 days in culture, wood frog tadpoles exposed to 1 and 10 μM medetomidine for as few as 3 days were significantly less developed compared to controls. Toads exposed to 1 μM medetomidine for 3 days were also significantly less developed on day 27, but by day 34, there was no difference from controls. For wood frogs, medetomidine significantly affected time to metamorphosis with a trend for tadpoles at lower concentrations metamorphosing sooner than those at higher concentrations. While medetomidine affected time to metamorphosis in wood frogs, it did not affect fresh mass, dry mass, or mortality compared to controls. Wood frog tadpoles that did not metamorphose after over 90 days in culture were more frequent in high-concentration groups than in the control. In toads, 10 μM medetomidine was 100% lethal within 23 days, but at the same concentration and duration, no wood frog tadpoles died. Lower concentrations were also significantly lethal to toads compared to controls, but tadpoles that survived in 10 and 100 nM metamorphosed sooner than those in 1 μM. Fresh mass of toad tadpoles exposed to 1 μm was significantly smaller at metamorphosis compared to that of controls. Medetomidine also affected the behavior of tadpoles. In toads, medetomidine

In situ polymerization of polyaniline in wood veneers.

Science.gov (United States)

Trey, Stacy; Jafarzadeh, Shadi; Johansson, Mats

2012-03-01

The present study describes the possibility to polymerize aniline within wood veneers to obtain a semi-conducting material with solid wood acting as the base template. It was determined that it is possible to synthesize the intrinsically conductive polymer (ICP) polyaniline in situ within the wood structure of Southern yellow pine veneers, combining the strength of the natural wood structure with the conductivity of the impregnated polymer. It was found that polyaniline is uniformly dispersed within the wood structure by light microscopy and FT-IR imaging. A weight percent gain in the range of 3-12 wt % was obtained with a preferential formation in the wood structure and cell wall, rather than in the lumen. The modified wood was found to be less hydrophilic with the addition of phosphate doped polyaniline as observed by equilibrium water swelling studies. While wood itself is insulating, the modified veneers had conductivities of 1 × 10(-4) to 1 × 10(-9) S cm(-1), demonstrating the ability to tune the conductivity and allowing for materials with a wide range of applications, from anti-static to charge-dispersing materials. Furthermore, the modified veneers had lower total and peak heat releases, as determined by cone calorimetry, because of the char properties of the ICP. This is of interest if these materials are to be used in building and furniture applications where flame retardance is of importance. © 2012 American Chemical Society

The effects of early diagenesis on the chemical and stable carbon isotopic composition of wood

International Nuclear Information System (INIS)

Spiker, E.C.; Hatcher, P.G.

1987-01-01

Studies of modern and ancient buried wood show that there is a linear correlation between carbohydrate content and the stable carbon isotope composition as carbohydrates are preferentially degraded during early diagenesis. As the carbohydrate content decreases, the delta 13 C value of the degraded wood decreases 1 to 2 per mil, approaching the value of the residual lignin. These results indicate that carbohydrate degradation products are lost and not incorporated into the aromatic structure as lignin is selectively preserved during early diagenesis of wood. These results also indicate that attempts to quantify terrestrial inputs to modern sedimentary organic matter based on delta 13 C values should consider the possibility of a 1 to 2 per mil decrease in the delta 13 C value of degraded wood. (author)

Investigation Of The Color Changing Properties Of Wood Stain Derived From Pinar Leaves

Directory of Open Access Journals (Sweden)

Abdi Atılgan

2011-11-01

Full Text Available This study was designed to develop an environmentally friendly wood stain derived pinar (Quercus aucheri leaves and determine the color stability of this stain when exposed to UV light irradiation. Wood stains derived from pinar leaves were prepared from aqueous solution with %3 iron (FeSO4.7H2O , % 5 alum ((KAl(SO42.12H2O, and % 10 vinegar mordant mixtures. Scots pine (Pinus sylvestris L., Turkish oriental beech (Fagus orientalis Lipsky and oak (Quercus petraea L. wood specimens were used as staining substrates. After treatment with the stain, the wood panels were exposed to UV light irradiation for periods of 100, 200, and 300 hours and determinated the total color changes was according to ISO 2470 standards. Results showed that wood stain derived from pinar extract provided some color stability after UV irradiation. According to results, Scots pine specimens treated with the pinar extract + iron mixture provided the smallest total color changes. Meanwhile the highest total color change provided on the Scots pine treated with pinar extract+alum mixture.

Sorption of lipophilic organic compunds to wood and implications for their environmental fate

DEFF Research Database (Denmark)

Trapp, Stefan; Miglioranza, S.B.; Mosbæk, Hans

2001-01-01

The sorption from water to wood (KWood) of 10 organic chemicals (logKOW, 1.48-6.20) was experimentally determined for oak (Quercus robur) and basket willow (Salix viminalis). Linear regression yielded log KWood ) -0.27 (( 0.25) + 0.632 (( 0.063)log KOW for oak (r ) 0.90, n ) 27) and log KWood ) -...... time. If metabolism inside the stem occurs, wood can serve as a “safe sink” for environmental chemicals. This might be of use in phytoremediation....

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications.

Science.gov (United States)

Zhu, Hongli; Luo, Wei; Ciesielski, Peter N; Fang, Zhiqiang; Zhu, J Y; Henriksson, Gunnar; Himmel, Michael E; Hu, Liangbing

2016-08-24

With the arising of global climate change and resource shortage, in recent years, increased attention has been paid to environmentally friendly materials. Trees are sustainable and renewable materials, which give us shelter and oxygen and remove carbon dioxide from the atmosphere. Trees are a primary resource that human society depends upon every day, for example, homes, heating, furniture, and aircraft. Wood from trees gives us paper, cardboard, and medical supplies, thus impacting our homes, school, work, and play. All of the above-mentioned applications have been well developed over the past thousands of years. However, trees and wood have much more to offer us as advanced materials, impacting emerging high-tech fields, such as bioengineering, flexible electronics, and clean energy. Wood naturally has a hierarchical structure, composed of well-oriented microfibers and tracheids for water, ion, and oxygen transportation during metabolism. At higher magnification, the walls of fiber cells have an interesting morphology-a distinctly mesoporous structure. Moreover, the walls of fiber cells are composed of thousands of fibers (or macrofibrils) oriented in a similar angle. Nanofibrils and nanocrystals can be further liberated from macrofibrils by mechanical, chemical, and enzymatic methods. The obtained nanocellulose has unique optical, mechanical, and barrier properties and is an excellent candidate for chemical modification and reconfiguration. Wood is naturally a composite material, comprised of cellulose, hemicellulose, and lignin. Wood is sustainable, earth abundant, strong, biodegradable, biocompatible, and chemically accessible for modification; more importantly, multiscale natural fibers from wood have unique optical properties applicable to different kinds of optoelectronics and photonic devices. Today, the materials derived from wood are ready to be explored for applications in new technology areas, such as electronics, biomedical devices, and energy. The

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications

Energy Technology Data Exchange (ETDEWEB)

Zhu, Hongli; Luo, Wei; Ciesielski, Peter N.; Fang, Zhiqiang; Zhu, J. Y.; Henriksson, Gunnar; Himmel, Michael E.; Hu, Liangbing

2016-08-24

With the arising of global climate change and resource shortage, in recent years, increased attention has been paid to environmentally friendly materials. Trees are sustainable and renewable materials, which give us shelter and oxygen and remove carbon dioxide from the atmosphere. Trees are a primary resource that human society depends upon every day, for example, homes, heating, furniture, and aircraft. Wood from trees gives us paper, cardboard, and medical supplies, thus impacting our homes, school, work, and play. All of the above-mentioned applications have been well developed over the past thousands of years. However, trees and wood have much more to offer us as advanced materials, impacting emerging high-tech fields, such as bioengineering, flexible electronics, and clean energy. Wood naturally has a hierarchical structure, composed of well-oriented microfibers and tracheids for water, ion, and oxygen transportation during metabolism. At higher magnification, the walls of fiber cells have an interesting morphology--a distinctly mesoporous structure. Moreover, the walls of fiber cells are composed of thousands of fibers (or macrofibrils) oriented in a similar angle. Nanofibrils and nanocrystals can be further liberated from macrofibrils by mechanical, chemical, and enzymatic methods. The obtained nanocellulose has unique optical, mechanical, and barrier properties and is an excellent candidate for chemical modification and reconfiguration. Wood is naturally a composite material, comprised of cellulose, hemicellulose, and lignin. Wood is sustainable, earth abundant, strong, biodegradable, biocompatible, and chemically accessible for modification; more importantly, multiscale natural fibers from wood have unique optical properties applicable to different kinds of optoelectronics and photonic devices. Today, the materials derived from wood are ready to be explored for applications in new technology areas, such as electronics, biomedical devices, and energy. The

Consumer willingness to pay for a naturally decay-resistant wood product.

Science.gov (United States)

Geoffrey Donovan; Hayley. Hesseln

2004-01-01

Chromated copper arsenate (CCA) is the most widely used chemical wood preservative in the United States. Concerns about the safety of CCA led to an agreement between the Environmental Protection Agency and the wood treatment industry to withdraw CCA for nonindustrial uses by the end of 2003. In light of the publicity surrounding the withdrawal of CCA, this article...

Activated carbon from thermo-compressed wood and other lignocellulosic precursors

Directory of Open Access Journals (Sweden)

Capart, R.

2007-05-01

Full Text Available The effects of thermo-compression on the physical properties such as bulk density, mass yield, surface area, and also adsorption capacity of activated carbon were studied. The activated carbon samples were prepared from thermo-compressed and virgin fir-wood by two methods, a physical activation with CO2 and a chemical activation with KOH. A preliminary thermo-compression method seems an easy way to confer to a tender wood a bulk density almost three times larger than its initial density. Thermo-compression increased yield regardless of the mode of activation. The physical activation caused structural alteration, which enhanced the enlargement of micropores and even their degradation, leading to the formation of mesopores. Chemical activation conferred to activated carbon a heterogeneous and exclusively microporous nature. Moreover, when coupled to chemical activation, thermo-compression resulted in a satisfactory yield (23%, a high surface area (>1700 m2.g-1, and a good adsorption capacity for two model pollutants in aqueous solution: methylene blue and phenol. Activated carbon prepared from thermo-compressed wood exhibited a higher adsorption capacity for both the pollutants than did a commercial activated carbon.

Wood density variation in Gmelina arborea trees using X-ray densitometry

International Nuclear Information System (INIS)

Roque, Roger Moya; Tomazello, Mario

2005-01-01

The wood density constitutes the main wood quality parameter by its relationship with anatomical, physical and chemical properties and wood utilization. The modern and accurate methods - like X-ray densitometry - are applied to determine the density spatial distribution in wood sections and pith-bark direction. On the other hand, emphasis to wood utilization from fast growing plantations, like Gmelina arborea in Costa Rica, has been done. The objectives of this study were to determinate the influence of 2 climatic conditions of Costa Rica on radial wood density variation of gmelina trees form fast growing plantations using the X-ray densitometry method. Wood samples were cut at DBH of gmelina trees and transversal thin laths were selected at north-south direction and conditioned at 12% moisture content equilibrium and X-rayed. The radiographic films were revealed and scanned a 256 gray scale with 1000 dpi resolution and the intra tree-ring density were determined by CRAD and CERD software. The results demonstrated that the climatic and forest management affects the wood density variability and the distinctness of tree-ring boundaries of gmelina trees, as well as, the applicability of X-ray densitometry in wood quality analysis. (author)

Grafted wood pulp containing quaternary ammonium group and its application in the removal of different anions from aqueous solution

International Nuclear Information System (INIS)

Sokker, H.H.

2005-01-01

Network wood pulp based on acrylonitrile has been chemically modified through different reactions to obtain group capable of anion exchange. Graft copolymerization of acrylonitrile onto wood pulp was carried out by using gamma-radiation 60 Co. Factors affecting the grafting process e.g radiation dose and monomer concentration were investigated.The chemical modification of cyano groups were carried out by reaction with ethanol amine producing oxazoline group followed by quaternization of tertiary amine by reaction with benzyl chloride producing quaternary ammonium salt. The grafted and modified wood pulp were characterized by FTIR, SEM and TGA.Qualitative experiments of adsorption were conducted to evaluate the modified wood pulp on fixing sulfate, phosphate,nitrate and dichromate from aqueous solution using batch extractions. Based on the results obtained, it may be concluded that it is possible to modify chemically wood pulp containing cyano groups by different routes for its usage as anion exchanger

Wood nitrogen concentrations in tropical trees: phylogenetic patterns and ecological correlates.

Science.gov (United States)

Martin, Adam R; Erickson, David L; Kress, W John; Thomas, Sean C

2014-11-01

In tropical and temperate trees, wood chemical traits are hypothesized to covary with species' life-history strategy along a 'wood economics spectrum' (WES), but evidence supporting these expected patterns remains scarce. Due to its role in nutrient storage, we hypothesize that wood nitrogen (N) concentration will covary along the WES, being higher in slow-growing species with high wood density (WD), and lower in fast-growing species with low WD. In order to test this hypothesis we quantified wood N concentrations in 59 Panamanian hardwood species, and used this dataset to examine ecological correlates and phylogenetic patterns of wood N. Wood N varied > 14-fold among species between 0.04 and 0.59%; closely related species were more similar in wood N than expected by chance. Wood N was positively correlated with WD, and negatively correlated with log-transformed relative growth rates, although these relationships were relatively weak. We found evidence for co-evolution between wood N and both WD and log-transformed mortality rates. Our study provides evidence that wood N covaries with tree life-history parameters, and that these patterns consistently co-evolve in tropical hardwoods. These results provide some support for the hypothesized WES, and suggest that wood is an increasingly important N pool through tropical forest succession. © 2014 The Authors. New Phytologist © 2014 New Phytologist Trust.

Assessment of the wood waste resource and its position in the wood / wood-energy sector - Synthesis

International Nuclear Information System (INIS)

Guinard, Ludovic; Deroubaix, Gerard; Roux, Marie-Lise; Levet, Anne-Laure; Quint, Vincent

2015-04-01

The first objective of this study is to obtain a better knowledge of the 'wood wastes' issue, to propose a photography of the wood waste sector (productions, trades, consumptions), and then to elaborate different prospective scenarios on the use of wood waste volumes while taking into account possible evolutions on the medium or short term of the regulation and market of the wood/wood energy sector. The considered wastes come from industrial production, from the use of wood-based products, and from the end of life of products potentially containing wood. The authors present bibliographical sources and the adopted methodology, briefly describe the 'wood waste' system with its actors, and then report their assessment of wood wastes. They propose a global assessment as well as detailed assessments with respect to waste origins: wood trade and distribution, industries, craft, households and communities, building sector, public and private tertiary sector, packaging. They also address the collection and management of wood wastes by public services, and present the different types of valorisation (panel fabrication, energy, and others). They discuss exports, and then present different scenarios: a trend-based scenario, and two prospective scenarios with a priority to energetic valorisation or to material valorisation of wood wastes. These scenarios are compared

Cu,Cr and As determination in preserved woods (Eucalyptus ssp.) by X-ray fluorescence spectrometries

International Nuclear Information System (INIS)

Pereira Junior, Sergio Matias

2014-01-01

Brazil produces around 2.2 millions of cubic meters of treated wood to meet the annual demand of railway, electric, rural and construction sectors. The most used wood species are eucalyptus (Eucalyptus ssp.) and pine (Pinus ssp.).The treated woods used for poles, sleepers, fence posts and plywoods should be according to Brazilian norms requirements. The most usual wood preservative products used in Brazil are CCA (chromated copper arsenate) and CCB (copper chromium and boron salt). The analytical methods, such as flame atomic absorption spectrometry (FAAS), plasma inductively coupled optical emission spectrometry (ICPOES) and X-ray fluorescence spectrometry (XRFS) have been used for the analytical control of those treatment processes. In this work, the eucalyptus trees (Eucalyptus ssp) samples was obtained from Minas Gerais State, Brazil, cut plantation areas. Under pressure, eucalyptus wood samples were submitted to different concentration of CCA solution reaching 3.9, 6.7, 9.1, 12.4 and 14.0 kg of CCA by m-³ sapwood retentions. Samples in cylinders and sawdust forms were obtained from treated wood samples. Copper, chromium and arsenic determination was performed using the energy dispersive X-ray fluorescence spectrometry (EDXRFS), portable X-ray fluorescence spectrometry (PXRFS), flame atomic absorption spectrometry (FAAS) and instrumental neutron activation analysis. In this work, the method of analysis, sensitivity, precision and accuracy performances of the related techniques were outlined. (author)

RETENTION AND PENETRATION OF CCA IN WOOD OF FIRST AND SECOND ROTATION OF Eucalyptus urophylla S.T. Blake

Directory of Open Access Journals (Sweden)

Mara Lúcia Agostini Valle

2013-06-01

Full Text Available http://dx.doi.org/10.5902/198050989292This study aimed to evaluate the retention and penetration of copper chrome arsenate (CCA type C as well as some wood properties of two rotations of two natural hybrid of Eucalyptus urophylla S. T. Blake, aiming their use as treated wood. The study was conducted with material from commercial plantations, with 63 months of age. For the wood characterization, the relationship sapwood-heartwood, the basic density and the size of fibers and vessels were evaluated. For the evaluation of treated wood, the penetration and retention of copper chrome arsenate (CCA type C were determined. Four trees per rotation and genetic material were used, which subsequently were split into three logs, in a total of 12 logs for each treatment. The preservative treatment was performed using the full cell process in autoclave using CCA solution with 2% concentration of active ingredients. The treatment process used was effective under the conditions required by the NBR 9480, with retention values ​​higher than the minimum required by the standard, which is 6.5 kg/m3 of CCA per treated wood, and in addition, provided deep penetration and regular condom in sapwood of all timber treated. There are no restrictions on the use of wood from the first and second rotation for preservative treatment, based on the properties evaluated. There was no correlation between the type C CCA retention and wood properties evaluated.

Superhydrophobic coatings on wood substrate for self-cleaning and EMI shielding

Science.gov (United States)

Xing, Yingjie; Xue, Yaping; Song, Jinlong; Sun, Yankui; Huang, Liu; Liu, Xin; Sun, Jing

2018-04-01

A layer of superhydrophobic coating having good electromagnetic shielding and self-cleaning performance was fabricated on a wood surface through an electroless copper plated process. The superhydrophobic property of the wood surface was measured by contact angle (CA) and roll-off angle (RA) measurements. The microstructure and chemical composition of the superhydrophobic coating were analyzed by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD). The analysis revealed that the microscale particles were uniformly distributed on the wood surface and the main component of the coating is metallic copper. The as-prepared Cu coatings on wood substrate exhibit a good superhydrophobicity with water contact angle about 160° and rolling angle less than 5°.

Chapter 6: Wood energy and competing wood product markers

Science.gov (United States)

Kenneth E. Skog; Robert C. Abt; Karen Abt

2014-01-01

Understanding the effect of expanding wood energy markets is important to all wood-dependent industries and to policymakers debating the implementation of public programs to support the expansion of wood energy generation. A key factor in determining the feasibility of wood energy projects (e.g. wood boiler or pellet plant) is the long-term (i.e. 20-30year) supply...

Wood adhesives : vital for producing most wood products

Science.gov (United States)

Charles R. Frihart

2011-01-01

A main route for the efficient utilization of wood resources is to reduce wood to small pieces and then bond them together (Frihart and Hunt 2010). Although humankind has been bonding wood since early Egyptian civilizations, the quality and quantity of bonded wood products has increased dramatically over the past 100 years with the development of new adhesives and...

IN SITU BIOREMEDIATION STRATEGIES FOR ORGANIC WOOD PRESERVATIVES

Science.gov (United States)

Laboratory biotreatability studies evaluated the use of bioventing and biosparging plus groundwater circulation (UVB technology) for their potential abililty to treat soil and groundwater containing creosote and pentachlorophenol. Soils from two former wood-treatment facilities w...

Syringyl-Rich Lignin Renders Poplars More Resistant to Degradation by Wood Decay Fungi

Science.gov (United States)

Skyba, Oleksandr; Douglas, Carl J.

2013-01-01

In order to elucidate the effects of lignin composition on the resistance of wood to degradation by decay fungi, wood specimens from two transgenic poplar lines expressing an Arabidopsis gene encoding ferulate 5-hydroxylase (F5H) driven by the cinnimate-4-hydroxylase promoter (C4H::F5H) that increased syringyl/guaiacyl (S/G) monolignol ratios relative to those in the untransformed control wood were incubated with six different wood decay fungi. Alterations in wood weight and chemical composition were monitored over the incubation period. The results showed that transgenic poplar lines extremely rich in syringyl lignin exhibited a drastically improved resistance to degradation by all decay fungi evaluated. Lignin monomer composition and its distribution among cell types and within different cell layers were the sole wood chemistry parameters determining wood durability. Since transgenic poplars with exceedingly high syringyl contents were recalcitrant to degradation, where wood durability is a critical factor, these genotypes may offer improved performance. PMID:23396333

Effect of stacking sequence on mechanical properties neem wood veneer plastic composites

Science.gov (United States)

Nagamadhu, M.; Kumar, G. C. Mohan; Jeyaraj, P.

2018-04-01

This study investigates the effect of wood veneer stacking sequence on mechanical properties of neem wood polymer composite (WPC) experimentally. Wood laminated samples were fabricated by conventional hand layup technique in a mold and cured under pressure at room temperature and then post cured at elevated temperature. Initially, the tensile, flexural, and impact test were conducted to understand the effect of weight fraction of fiber on mechanical properties. The mechanical properties have increased with the weight fraction of fiber. Moreover the stacking sequence of neem wood plays an important role. As it has a significant impact on the mechanical properties. The results indicated that 0°/0° WPC shows highest mechanical properties as compared to other sequences (90°/90°, 0°/90°, 45°/90°, 45°/45°). The Fourier Transform Infrared Spectroscopy (FTIR) Analysis were carried out to identify chemical compounds both in raw neem wood and neem wood epoxy composite. The microstructure raw/neat neem wood and the interfacial bonding characteristics of neem wood composite investigated using Scanning electron microscopy images.

Health effects on nearby residents of a wood treatment plant

International Nuclear Information System (INIS)

Dahlgren, James; Warshaw, Raphael; Thornton, John; Anderson-Mahoney, P.M.; Takhar, Harpreet

2003-01-01

Objectives: The aim of the study was to evaluate the health status of nearby residents of a wood treatment plant who had sustained prolonged low-level environmental exposure to wood processing waste chemicals. Methods: A population of 1269 exposed residents who were plaintiffs or potential plaintiffs in a lawsuit against the wood treatment plant were evaluated by questionnaire for a health history and symptoms. A representative sample of 214 exposed subjects was included in the analysis. One hundred thirty-nine controls were selected from 479 unexposed volunteers and matched to the exposed subjects as closely as possible by gender and age. Subjects and controls completed additional questionnaires and were evaluated by a physician for medical history and physical examination, blood and urine testing, neurophysiological and neuropsychological studies, and respiratory testing. Environmental sampling for wood processing waste chemicals was carried out on soil and drainage ditch sediment in the exposed neighborhood. Results: The exposed subjects had significantly more cancer, respiratory, skin, and neurological health problems than the controls. The subjective responses on questionnaires and by physician histories revealed that the residents had a significantly greater prevalence of mucous membrane irritation, and skin and neurological symptoms, as well as cancer. (Exposed versus unexposed, cancer 10.0% versus 2.08%, bronchitis 17.8% versus 5.8%, and asthma by history 40.5% versus 11.0%) There were significantly more neurophysiologic abnormalities in adults of reaction time, trails A and B, and visual field defects. Conclusions: Adverse health effects were significantly more prevalent in long-term residents near a wood treatment plant than in controls. The results of this study suggest that plant emissions from wood treatment facilities should be reduced

EVALUATION OF CEMENT-BONDED PARTICLE BOARD PRODUCED FROM AFZELIA AFRICANA WOOD RESIDUES

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OLUFEMI A. SOTANNDE

2012-12-01

Full Text Available The study was design to evaluate the physical and mechanical properties of cement-bonded particleboards produced from Afzelia africana wood residues. The production variables investigated were three wood particle types (flakes, flake-sawdust mix and sawdust, three chemical accelerators (CaCl2, MgCl2 and AlCl3 and four wood-cement ratios (1:2.0, 1:2.5, 1:3.0 and 1:3.5. The accelerators were based on 2% by weight of cement used. The boards produced were subjected to physical tests such as density, percentage water absorption and thickness swelling. Mechanical properties evaluated were modulus of rupture, internal bonding strength and compressive strength. The results revealed that the type of particle used, wood-cement ratio and chemical additives had a marked influence on the physical and mechanical properties of the boards (p < 0.05. From quality view point, flake-sawdust composite ranked best while flake boards ranked least. Similarly, CaCl2 had the best influence on the setting of the boards followed by MgCl2 and AlCl3. Finally, it has been shown that particle boards that satisfied the BISON type HZ requirement and ISO 8335 can be produced from Afzelia africana particularly at wood-cement of 1:2.5 and above.

Thermal Pretreatment of Wood for Co-gasification/co-firing of Biomass and Coal

Energy Technology Data Exchange (ETDEWEB)

Wang, Ping [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Howard, Bret [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Hedges, Sheila [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Morreale, Bryan [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Van Essendelft, Dirk [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Berry, David [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

2013-10-29

Utilization of biomass as a co-feed in coal and biomass co-firing and co-gasification requires size reduction of the biomass. Reducing biomass to below 0.2 mm without pretreatment is difficult and costly because biomass is fibrous and compressible. Torrefaction is a promising thermal pretreatment process and has the advantages of increasing energy density, improving grindability, producing fuels with more homogenous compositions and hydrophobic behavior. Temperature is the most important factor for the torrefaction process. Biomass grindability is related to cell wall structure, thickness and composition. Thermal treatment such as torrefaction can cause chemical changes that significantly affect the strength of biomass. The objectives of this study are to understand the mechanism by which torrefaction improves the grindability of biomass and discuss suitable temperatures for thermal pretreatment for co-gasification/co-firing of biomass and coal. Wild cherry wood was selected as the model for this study. Samples were prepared by sawing a single tangential section from the heartwood and cutting it into eleven pieces. The samples were consecutively heated at 220, 260, 300, 350, 450 and 550⁰C for 0.5 hr under flowing nitrogen in a tube furnace. Untreated and treated samples were characterized for physical properties (color, dimensions and weight), microstructural changes by SEM, and cell wall composition changes and thermal behaviors by TGA and DSC. The morphology of the wood remained intact through the treatment range but the cell walls were thinner. Thermal treatments were observed to decompose the cell wall components. Hemicellulose decomposed over the range of ~200 to 300⁰C and resulted in weakening of the cell walls and subsequently improved grindability. Furthermore, wood samples treated above 300⁰C lost more than 39% in mass. Therefore, thermal pretreatment above the hemicelluloses decomposition temperature but below 300⁰C is probably sufficient to

The decay of wood in landfills in contrasting climates in Australia

Energy Technology Data Exchange (ETDEWEB)

Ximenes, Fabiano, E-mail: fabiano.ximenes@dpi.nsw.gov.au [Forest Science, Agriculture NSW, New South Wales Department of Primary Industries, Level 12, 10 Valentine Ave, Parramatta, NSW 2150 (Australia); Björdal, Charlotte [Department of Conservation, Gothenburg University, Guldhedsgatan 5A, Box 130, SE-405 30 Göteborg (Sweden); Cowie, Annette [NSW Department of Primary Industries, Beef Industry Centre, Trevenna Rd., University of New England, Armidale, NSW 2351 (Australia); Barlaz, Morton [Dept. of Civil, Construction, & Environmental Eng., North Carolina State University, Box 7908, Raleigh, NC 27695-7908 (United States)

2015-07-15

Highlights: • We examine decay in wood from landfills in contrasting environments in Australia. • Analysis is based on changes in chemical composition and microscopy. • Climate did not influence levels of decay observed. • Microscopy of retrieved samples revealed most of the decay was aerobic in nature. • Current default factors for wood decay in landfills overestimate methane emissions. - Abstract: Wood products in landfill are commonly assumed to decay within several decades, returning the carbon contained therein to the atmosphere, with about half the carbon released as methane. However, the rate and extent of decay is not well known, as very few studies have examined the decay of wood products in landfills. This study reports on the findings from landfill excavations conducted in the Australian cities of Sydney and Cairns located in temperate and tropical environments, respectively. The objective of this study was to determine whether burial of the wood in warmer, more tropical conditions in Cairns would result in greater levels of decay than occurs in the temperate environment of Sydney. Wood samples recovered after 16–44 years in landfill were examined through physical, chemical and microscopic analyses, and compared with control samples to determine the carbon loss. There was typically little or no decay in the wood samples analysed from the landfill in Sydney. Although there was significant decay in rainforest wood species excavated from Cairns, decay levels for wood types that were common to both Cairns and Sydney landfills were similar. The current Intergovernmental Panel on Climate Change (IPCC, 2006) default decay factor for organic materials in landfills is 50%. In contrast, the carbon loss determined for Pinus radiata recovered from Sydney and Cairns landfills was 7.9% and 4.4%, respectively, and 0% for Agathis sp. This suggests that climate did not influence decay, and that the more extensive levels of decay observed for some wood samples

The decay of wood in landfills in contrasting climates in Australia

International Nuclear Information System (INIS)

Ximenes, Fabiano; Björdal, Charlotte; Cowie, Annette; Barlaz, Morton

2015-01-01

Highlights: • We examine decay in wood from landfills in contrasting environments in Australia. • Analysis is based on changes in chemical composition and microscopy. • Climate did not influence levels of decay observed. • Microscopy of retrieved samples revealed most of the decay was aerobic in nature. • Current default factors for wood decay in landfills overestimate methane emissions. - Abstract: Wood products in landfill are commonly assumed to decay within several decades, returning the carbon contained therein to the atmosphere, with about half the carbon released as methane. However, the rate and extent of decay is not well known, as very few studies have examined the decay of wood products in landfills. This study reports on the findings from landfill excavations conducted in the Australian cities of Sydney and Cairns located in temperate and tropical environments, respectively. The objective of this study was to determine whether burial of the wood in warmer, more tropical conditions in Cairns would result in greater levels of decay than occurs in the temperate environment of Sydney. Wood samples recovered after 16–44 years in landfill were examined through physical, chemical and microscopic analyses, and compared with control samples to determine the carbon loss. There was typically little or no decay in the wood samples analysed from the landfill in Sydney. Although there was significant decay in rainforest wood species excavated from Cairns, decay levels for wood types that were common to both Cairns and Sydney landfills were similar. The current Intergovernmental Panel on Climate Change (IPCC, 2006) default decay factor for organic materials in landfills is 50%. In contrast, the carbon loss determined for Pinus radiata recovered from Sydney and Cairns landfills was 7.9% and 4.4%, respectively, and 0% for Agathis sp. This suggests that climate did not influence decay, and that the more extensive levels of decay observed for some wood samples

CHARACTERIZATION OF WOOD DECAY BY ROT FUNGI USING COLORIMETRY AND INFRARED SPECTROSCOPY

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Mírian de Almeida Costa

2011-09-01

Full Text Available Wood samples of marupá (Simarouba amara and andiroba (Carapa guianenis were submitted to Trametes versicolor (white rot and Gloeophylum trabeum (brown rot fungi attack. Colorimetry was used to determine the color of the wood before and after wood decaying fungi. To evaluate the changes in chemical compounds levels in the wood samples, the diffuse reflectance medium infrared spectroscopy was used. Both wood were non resistant against white rot fungus, while with brown rot attack andiroba was resistant and marupá was not. After Gloeophyllum trabeum attack both woods changed to a darken color, and after Trametes versicolor attack andiroba changed to a lighter color and marupá darkened slightly, The analysis showed a reduction in the peak intensity of cellulose, hemicellulose and lignin, for both species, after Trametes versicolor attack and a reduction in the peak intensity of cellulose after Gloeophyllum trabeum attack.

Effect of heat treatment of wood on the morphology, surface roughness and penetration of simulated and human blood.

Science.gov (United States)

Rekola, J; Lassila, L V J; Nganga, S; Ylä-Soininmäki, A; Fleming, G J P; Grenman, R; Aho, A J; Vallittu, P K

2014-01-01

Wood has been used as a model material for the development of novel fiber-reinforced composite bone substitute biomaterials. In previous studies heat treatment of wood was perceived to significantly increase the osteoconductivity of implanted wood material. The objective of this study was to examine some of the changing attributes of wood materials that may contribute to improved biological responses gained with heat treatment. Untreated and 140°C and 200°C heat-treated downy birch (Betula pubescens Ehrh.) were used as the wood materials. Surface roughness and the effect of pre-measurement grinding were measured with contact and non-contact profilometry. Liquid interaction was assessed with a dipping test using two manufactured liquids (simulated blood) as well as human blood. SEM was used to visualize possible heat treatment-induced changes in the hierarchical structure of wood. The surface roughness was observed to significantly decrease with heat treatment. Grinding methods had more influence on the surface contour and roughness than heat treatment. The penetration of the human blood in the 200°C heat-treated exceeded that in the untreated and 140°C heat-treated materials. SEM showed no significant change due to heat treatment in the dry-state morphology of the wood. The results of the liquid penetration test support previous findings in literature concerning the effects of heat treatment on the biological response to implanted wood. Heat-treatment has only a marginal effect on the surface contour of wood. The highly specialized liquid conveyance system of wood may serve as a biomimetic model for the further development of tailored fiber-composite materials.

Technological and chemical properties of heat-treated Anatolian ...

African Journals Online (AJOL)

STORAGESEVER

2009-06-03

Jun 3, 2009 ... heat treatment temperature and time justifies these re- sults. Cellulose ..... properties of light-irradiated wood with heat treatment: Part 1. Effect ... Norway spruce (Picea abies) and birch (Betula pubescens) subjected to heat ...

Polyphenolic profile as a useful tool to identify the wood used in wine aging.

Science.gov (United States)

Sanz, Miriam; Fernández de Simón, Brígida; Cadahía, Estrella; Esteruelas, Enrique; Muñoz, Angel Ma; Hernández, Ma Teresa; Estrella, Isabel

2012-06-30

Although oak wood is the main material used in cooperage, other species are being considered as possible sources of wood for the production of wines and their derived products. In this work we have compared the phenolic composition of acacia (Robinia pseudoacacia), chestnut (Castanea sativa), cherry (Prunus avium) and ash (Fraxinus excelsior and F. americana) heartwoods, by using HPLC-DAD/ESI-MS/MS (some of these data have been showed in previous paper), as well as the changes that toasting intensity at cooperage produce in each polyphenolic profile. Before toasting, each wood shows a different and specific polyphenolic profile, with both qualitative and quantitative differences among them. Toasting notably changed these profiles, in general, proportionally to toasting intensity and led to a minor differentiation among species in toasted woods, although we also found phenolic markers in toasted woods. Thus, methyl syringate, benzoic acid, methyl vanillate, p-hydroxybenzoic acid, 3,4,5-trimethylphenol and p-coumaric acid, condensed tannins of the procyanidin type, and the flavonoids naringenin, aromadendrin, isosakuranetin and taxifolin will be a good tool to identify cherry wood. In acacia wood the chemical markers will be the aldehydes gallic and β-resorcylic and two not fully identified hydroxycinnamic compounds, condensed tannins of the prorobinetin type, and when using untoasted wood, dihydrorobinetin, and in toasted acacia wood, robinetin. In untoasted ash wood, the presence of secoiridoids, phenylethanoid glycosides, or di and oligolignols will be a good tool, especially oleuropein, ligstroside and olivil, together verbascoside and isoverbascoside in F. excelsior, and oleoside in F. americana. In toasted ash wood, tyrosol, syringaresinol, cyclolovil, verbascoside and olivil, could be used to identify the botanical origin. In addition, in ash wood, seasoned and toasted, neither hydrolysable nor condensed tannins were detected. Lastly, in chestnut wood, gallic

Biomaterial based novel polyurethane adhesives for wood to wood and metal to metal bonding

Directory of Open Access Journals (Sweden)

Mitesh Ramanlal Patel

2009-01-01

Full Text Available Polyurethane adhesives made from synthetic chemicals are non-biodegradable, costly and difficult to find raw materials from local market. To avoid solid pollution problem, cost effectiveness and easy availability of raw materials, biomaterials based polyurethane adhesives are used in current industrial interest. Direct use of castor oil in polyurethane adhesive gives limited hardness. Modification on active sites of castor oil to utilize double bond of unsaturated fatty acid and carboxyl group yields new modified or activated polyols, which can be utilized for polyurethane adhesive formulation. In view of this, we have synthesized polyurethane adhesives from polyester polyols, castor oil based polyols and epoxy based polyols with Isocyanate adducts based on castor oil and trimethylolpropane. To study the effects of polyurethane adhesive strength (i.e. lap shear strength on wood-to-wood and metal-to-metal bonding through various types of polyols, cross-linking density, isocyanate adducts and also to compare adhesive strength between wood to wood and metal to metal surface. These polyols and polyurethanes were characterized through GPC, NMR and IR-spectroscopy, gel and surface drying time. Thermal stability of PU adhesives was determined under the effect of cross-linking density (NCO/OH ratio. The NCO/OH ratio (1.5 was optimized for adhesives as the higher NCO/OH ratio (2.0 increasing cross-linking density and decreases adhesion. Lower NCO/OH ratio (1.0 provideslow cross-linking density and low strength of adhesives.

Evaluation of potentical use of the wood of Schizolobium amazonicum “Paricá” and Cecropia hololeuca “Embaúba” for wood cement board manufacture

Directory of Open Access Journals (Sweden)

Vinicius Yurk da Rocha

2012-06-01

Full Text Available This research was developed to evaluate the potential use of Schizolobium amazonicum “Paricá” and Cecropia hololeuca “Embaúba” wood for wood cement board manufacture. Panels with the density of 1.200 kg/m³ were made, using cement CP V ARI as mineral bonding and wood particles without treatment and treated with immersion in cold water, hot water and sodium hydroxide. The panels were pressed at the pressure of 40 kgf/cm², room temperature and press / clipping time of 24 hours and maturation time of 28 days. The evaluation of the properties of water absorption, thickness swelling, internal bond, modulus of elasticity and modulus of rupture, showed that Schizolobium amazonicum “Paricá” and Cecropia hololeuca “Embaúba” wood are technically feasible for wood-cement board manufacture. It was also found that the panels of embaúba exhibit some properties superior to those of the paricá, and the particles do not necessarily need treatment.

Two new termite (Isoptera: Rhinotermitidae) feeding indexes for woods of varing palatability

Science.gov (United States)

Chris J. Peterson; P.D. Gerard

2009-01-01

In order for bait matrices, treated wood and resistant wood species to be properly evaluated in the laboratory for termite resistance or palatability, reliable tests that can distinguish between food choices must be developed; otherwise, inferior products may enter the marketplace. In the current study, a bioassay method is proposed that allows the calculation of two...

Wood burning

Energy Technology Data Exchange (ETDEWEB)

Winkelmann, H

1955-01-01

Discussed are the use of wood as a fuel, the technique of wood combustion and the operation of wood-burning stoves for cooking and heating. In addition, there is a section which reviews the use of wood stoves in various countries and lists manufacturers of stoves, central heating furnaces and in some cases sawdust burners.

Effects of mosquitofish (Gambusia affinis cues on wood frog (Lithobates sylvaticus tadpole activity

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Katherine F. Buttermore

2011-06-01

Full Text Available We examined the changes in activity of wood frog (Lithobates sylvaticus tadpoles exposed to combinations of visual, chemical, and mechanical cues of the invasive mosquitofish (Gambusia affinis. We also examined whether the responses of the tadpoles to the predator cues were influenced by the short-term accumulation of chemical cues in the experimental container. In our experiment, the activity of wood frog (L. sylvaticus tadpoles was not affected by the presence of various cues from mosquitofish. Our experiment demonstrated that the repeated use of trial water can influence the activity level of tadpoles, regardless of the predator cue treatment used. Tadpoles in the first trial tended to be less active than tadpoles in subsequent trials. This effect does not appear to be mediated by the accumulation of predator cues since there was no significant interaction term. Our results suggest that short-term accumulation of predator chemical cues do not affect the behavior of wood frog tadpoles: however, our results suggest that the repeated use of the same water in consecutive trials may affect tadpole behavior, perhaps through the accumulation of conspecific chemical cues.

Effect of Single and Double Stage Chemically Treated Kenaf Fibers on Mechanical Properties of Polyvinyl Alcohol Film

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Md Ershad Ali

2014-12-01

Full Text Available The physico-mechanical properties of lignocellulosic kenaf fiber reinforced polyvinyl alcohol (PVA biocomposite films were investigated. To improve the properties of the biocomposite, kenaf fibers were chemically treated separately in a single stage (with Cr2(SO4312(H2O and double stages (with CrSO4 and NaHCO3 to improve the adhesion and compatibility between the kenaf fiber and PVA matrix. PVA was reinforced with various compositions of chemically treated kenaf fiber by using a solution casting technique. Microstructural analyses and mechanical tests were subsequently conducted. Scanning electron microscopic analysis indicated that chemical treatment improved the uniformity distribution of kenaf fiber within the PVA matrix. FTIR and XRD analyses confirmed the presence of chromium on the fiber surface. The tensile strength of PVA reinforced with chemical treated kenaf fiber was found to be higher than those reinforced with untreated kenaf. The Young’s modulus, flexural strength, and flexural modulus increased with fiber loading for both untreated and treated kenaf fiber reinforced PVA films. The double stage treated kenaf fiber showed better mechanical properties and lower moisture uptake than the single stage treated kenaf fiber.

Chemical Changes in Nonthermal Plasma-Treated N-Acetylcysteine (NAC) Solution and Their Contribution to Bacterial Inactivation.

Science.gov (United States)

Ercan, Utku K; Smith, Josh; Ji, Hai-Feng; Brooks, Ari D; Joshi, Suresh G

2016-02-02

In continuation of our previous reports on the broad-spectrum antimicrobial activity of atmospheric non-thermal dielectric barrier discharge (DBD) plasma treated N-Acetylcysteine (NAC) solution against planktonic and biofilm forms of different multidrug resistant microorganisms, we present here the chemical changes that mediate inactivation of Escherichia coli. In this study, the mechanism and products of the chemical reactions in plasma-treated NAC solution are shown. UV-visible spectrometry, FT-IR, NMR, and colorimetric assays were utilized for chemical characterization of plasma treated NAC solution. The characterization results were correlated with the antimicrobial assays using determined chemical species in solution in order to confirm the major species that are responsible for antimicrobial inactivation. Our results have revealed that plasma treatment of NAC solution creates predominantly reactive nitrogen species versus reactive oxygen species, and the generated peroxynitrite is responsible for significant bacterial inactivation.

Congeners in sugar cane spirits aged in casks of different woods.

Science.gov (United States)

Bortoletto, Aline M; Alcarde, André R

2013-08-15

The profile of volatile compounds and aging markers in sugar cane spirits aged for 36 months in casks made of 10 types of wood were studied. The ethanol content, volatile acidity, aldehydes, esters, higher alcohols, and methanol were determined. In addition, gallic, vanilic and syringic acids, siringaldehyde, coniferaldehyde, sinapaldehyde, vanillin, 5-hydroxymethylfurfural and furfural were identified and quantified. The profile of volatile compounds characterised aging in each type of wood. The beverage aged in oak cask achieved the highest contents of maturation-related congeners. The Brazilian woods, similar to oak, were jequitibá rosa and cerejeira, which presented the highest contents of some maturation-related compounds, such as vanillin, vanilic acid, syringaldehyde and sinapaldehyde. Although oak wood conferred more chemical complexity to the beverage, Brazilian woods, singly or complementarily, present potential for spirit characterisation and for improving the quality of sugar cane spirits. Copyright © 2013 Elsevier Ltd. All rights reserved.

Manufacture of wood/plastic composites by radiation

International Nuclear Information System (INIS)

Iwamoto, Takeo

1976-01-01

The manufacture and use of wood/plastic composite (WPC) as an example of wood matrix and wood sawdust/plastic composites (SDP) as an example of plastic matrix are reviewed. The raw material for WPC are mostly vinyl monomers, particularly methyl methacrylate and styrene. The reaction in WPC polymerization is radical polymerization. Researches on the radiation sources mostly resulted in gamma-ray. Electron beam can be applied only to thin products. The future use of WPC may be for furnitures, sporting goods, decorative parts and the like. Vital study on the reduction of manufacturing costs is required, for example, the improvement of reaction and the adoption of continuous process must be considered. The raw materials for SDP are wood sawdust, vinyl monomer (mostly methyl methacrylate) and resins. Electron beam accelerators are the most preferable radiation source because of its high efficiency and safe operation. SDP shows good forming property. The most preferable use of SDP is as interior materials for prefabricated houses, for example, opening frames for bath rooms. Some combination of the technologies of wood engineering, chemical engineering and radiation engineering must be established to develop and maintain the demands. The present radiation sources are forced to grow to large scale industrially, but the establishment of radiation source technology which can be enlarged stepwise is important to keep pace with the development. (Iwakiri, K.)

Suitability of hardwood treated with phenoxy and pyridine herbicides for firewood use

Science.gov (United States)

P.B. Bush; D.G. Neary; Charles K. McMahon; J.W. Taylor

1987-01-01

Abstract. Potential exposure to pesticide residues resulting from burning wood treated with phenoxyand pyridine herbicides was assessed. Wood samples from trees treated with 2,4-D [2,4-dichlo-rophenoxy acetic acid], dicamba [3,6-dichloro-o-anisic acid], dichlorprop [2-(2,4-dichlorphenoxy) propionic acid], picloram [4-amino-3,5,dtrichloropico-linic...

Biological resistance of polyethylene composites made with chemically modified fiber or flour

Science.gov (United States)

Rebecca E. Ibach; Craig M. Clemons

2002-01-01

The role of moisture in the biological decay of wood-plastic composites was investigated. Southern pine wood fiber and ponderosa pine wood flour were chemically modified using either acetic anhydride (AA), butylene oxide (BO), or propylene oxide (PO). A 50:50 mixture of high density polyethylene and either chemically modified fiber or flour, or untreated fiber or flour...

Developments in undergraduate wood science education at Stellenbosch University, South Africa

OpenAIRE

Rypstra,Tim

2011-01-01

In South Africa, Stellenbosch University (SU) is the designated provider of Bachelor, Master and Doctorate level qualifications in Forestry and Wood Products Science. SU provides educational programs to both mechanical (sawmilling, preservation, composite products, furniture, etc.) and the chemical (pulp & paper) processing sectors. To ensure academic quality, SU regularly has her academic programs assessed externally. In 2000, several changes to the then existing 4 year B.Sc. Wood Scienc...

Environmental impact assessment of wood ash utilization in forest road construction and maintenance--A field study.

Science.gov (United States)

Oburger, Eva; Jäger, Anna; Pasch, Alexander; Dellantonio, Alex; Stampfer, Karl; Wenzel, Walter W

2016-02-15

The ever increasing use of wood material as fuel for green energy production requires innovative, environmentally safe strategies for recycling of the remaining wood ash. Utilizing wood ash in forest road construction and maintenance to improve mechanical stability has been suggested as a feasible recycling option. To investigate the environmental impact of wood ash application in forest road maintenance, a two-year field experiment was conducted at two Austrian forest sites (Kobernausserwald (KO) (soil pH 5.5) and Weyregg (WE) (pH 7.7)) differing in their soil chemical properties. Two different ashes, one produced by grate incineration (GA) and the other by fluidized bed incineration in a mixture with 15 vol% burnt lime (FBA), were incorporated in repeated road sections at a 15:85% (V/V) ash-to-soil rate. Leaching waters from the road body were collected and analyzed for 32 environmentally relevant parameters over two years. Upon termination of the experiment, sub-road soil samples were collected and analyzed for ash-related changes in soil chemistry. Even though a larger number of parameters was affected by the ash application at the alkaline site (WE), we observed the most pronounced initial increases of pH as well as Al, As, Fe, Mn, Ni, Co, Cu, Mo, and NO2(−) concentrations in leachates beneath GA-treated road bodies at Kobernausserwald due to the lower soil buffer capacity at this site. Despite the observed effects our results indicate that, when specific requirements are met (i.e. appropriate ash quality, sufficient soil buffer capacity below the road body, and single time-point ash incorporation within several decades), wood ash application in forest road construction is generally environmentally acceptable.

Removal of nano- and micronized-copper from treated wood by chelating agents

Science.gov (United States)

S. Nami Kartal; Evren Terzi; Bessie Woodward; Carol A. Clausen; Stan T. Lebow

2013-01-01

Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from...

Potential wood protection strategies using physiological requirements of wood degrading fungi

NARCIS (Netherlands)

Sailer, M.F.; Etten, B.D. van

2004-01-01

Due to the increasing restrictions in the use of wood preserving biocides a number of potential biocide free wood preserving alternatives are currently assessed. Wood degrading fungi require certain conditions in the wood in order to be able to use wood as a food source. This paper discusses the

Examination of lignocellulosic fibers for chemical, thermal, and separations properties: Addressing thermo-chemical stability issues

Science.gov (United States)

Johnson, Carter David

Natural fiber-plastic composites incorporate thermoplastic resins with fibrous plant-based materials, sometimes referred to as biomass. Pine wood mill waste has been the traditional source of natural fibrous feedstock. In anticipation of a waste wood shortage other fibrous biomass materials are being investigated as potential supplements or replacements. Perennial grasses, agricultural wastes, and woody biomass are among the potential source materials. As these feedstocks share the basic chemical building blocks; cellulose, hemicellulose, and lignin, they are collectively called lignocellulosics. Initial investigation of a number of lignocellulosic materials, applied to fiber-plastic composite processing and material testing, resulted in varied results, particularly response to processing conditions. Less thermally stable lignocellulosic filler materials were physically changed in observable ways: darkened color and odor. The effect of biomass materials' chemical composition on thermal stability was investigated an experiment involving determination of the chemical composition of seven lignocellulosics: corn hull, corn stover, fescue, pine, soy hull, soy stover, and switchgrass. These materials were also evaluated for thermal stability by thermogravimetric analysis. The results of these determinations indicated that both chemical composition and pretreatment of lignocellulosic materials can have an effect on their thermal stability. A second study was performed to investigate what effect different pretreatment systems have on hybrid poplar, pine, and switchgrass. These materials were treated with hot water, ethanol, and a 2:1 benzene/ethanol mixture for extraction times of: 1, 3, 6, 12, and 24 hours. This factorial experiment demonstrated that both extraction time and medium have an effect on the weight percent of extractives removed from all three material types. The extracted materials generated in the above study were then subjected to an evaluation of thermal

Use of residual wood in the cement manufacturing process

International Nuclear Information System (INIS)

Gue, R.

2005-01-01

This PowerPoint presentation discussed the use of wood residuals in the cement manufacturing process. An outline of the cement manufacturing process was presented. Raw materials are combined in exact proportions to create a chemically correct mix, which is then pulverized in a mill. The mix is then burned in a kiln. The end product is cooled to form the pellet sized material known as clinker, which is then milled to form cement. The combustion and destruction characteristics of a cement kiln were presented. Modern cement kilns require approximately 3.2 Gj of energy to produce one tonne of cement. It was noted that wood residuals do not contain halogens, sulfur or other materials detrimental to the cement manufacturing process. Possible injection points for kilns were presented. Various studies have shown that wood residuals can be safely used as a fuel in the manufacture of cement. Environmental benefits derived from using wood included the complete destruction of organic portions, and the fact that residual ash becomes an indistinguishable part of the final product. It was concluded that wood residual materials are a satisfactory alternative fuel for the cement industry. tabs., figs

Review of test methods used to determine the corrosion rate of metals in contact with treated wood

Science.gov (United States)

Samuel L. Zelinka; Douglas R. Rammer

2005-01-01

The purpose of this literature review is to give an overview of test methods previously used to evaluate the corrosion of metals in contact with wood. This article reviews the test methods used to evaluate the corrosion of metals in contact with wood by breaking the experiments into three groups: exposure tests, accelerated exposure tests, and electrochemical tests....

Creosote treated timber in the Alaskan marine environment : Volume I.

Science.gov (United States)

2010-02-01

ADOT&PF is responsible for many structures that incorporate wood pilings and other timber in Alaska waters. Most are treated with preservative to inhibit marine borers : that will quickly destroy unprotected wood. Creosote is generally the most econo...

Evaluation of leachate quality from pentachlorophenol, creosote and ACA [ammoniacal chromium arsenate] preserved wood products

International Nuclear Information System (INIS)

Whiticar, D.M.; Letourneau, L.; Konasewich, D.

1994-01-01

A field study was conducted to evaluate the leachability characteristics of pentachlorophenol (PCP), creosote, and ammoniacal chromium arsenate (ACA) wood preservatives from freshly treated wood products. Test products included PCP-treated utility poles, creosote-treated timbers and marine pilings, and ACA-treated utility poles. Bundles of test products were placed over collection trays to collect the leachate generated by natural rainfall and by sprinkling with tap water. The sampling schedule was based on accumulated rainfall with samples taken at about every 15 mm from 15 mm to 150 mm. Analyses included pH, oil and grease, total organic carbon, ammonia, metals, polynuclear aromatic hydrocarbons (PAH), chlorinated and nonchlorinated phenols, resin acids, and fish toxicity. The study indicated that leachates from wood products freshly treated with ACA, creosote, and PCP have potential for aquatic toxicity if released to the environment. A decreasing trend was noted in both the arsenic and copper releases as cumulative precipitation increased. PCP releases remained constant over the course of the study while PAH releases showed no significant trend. Phenanthrene was found to be the main component in the releases. 28 refs., 18 figs., 7 tabs

Preservation of beech and spruce wood by allyl alcohol-based copolymers

International Nuclear Information System (INIS)

Solpan, Dilek; Gueven, Olgun

1999-01-01

Allyl alcohol (AA), acrylonitrile (AN), methyl methacrylate (MMA), monomers and monomer mixtures AA+AN, AA+MMA were used to conserve and consolidate Beech and Spruce. After impregnation, copolymerisation and polymerisation were accomplished by gamma irradiation. The fine structure of wood+polymer(copolymer) composites was investigated by Scanning Electron Microscopy (SEM). It was observed that copolymer obtained from AA+MMA monomer mixture showed the optimum compatibility. The compressional strength and Brinell Hardness Numbers determined for untreated and treated wood samples indicated that the mechanical strength of wood+copolymer composites was increased. It was found that the mechanical strength of the wood samples containing the AA+MMA copolymer was higher than the others. In the presence of P(AA/MMA), at highest conversion, the compressive strength perpendicular to the fibres in Beech and Spruce increased approximately 100 times. The water uptake capacity of wood+copolymer composites was observed to decrease by more than 50% relative to the original samples, and biodegradation did not take place

Radiation-chemical conservation and evaluation of wood from the rampart installation of Stillfried

International Nuclear Information System (INIS)

Kies, A.; Reithmayr, P.; Schaudy, R.

1985-12-01

The conservation of wooden remnants from the rampart originating from the urn field period a t Stillfried/March, Lower Austria, by impregnation with methyl methacrylate and by subsequent curing with gamma radiation is as well described as the preparation of thin sections thereof, which were suitable for the determination of the wood species or genera. For the frame construction of the rampart from the period Ha B, oak, linden and elm were found as the mainly used wood genera. This demonstrates that in that period the main elements of the mixed oak forest were still important. The results are discussed. (G.Q.)

Engineering Characteristics of Chemically Treated Water-Repellent Kaolin

Directory of Open Access Journals (Sweden)

Youngmin Choi

2016-12-01

Full Text Available Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the surface of clay particle is modified with organosilanes in concentrations (CO ranging from 0.5% to 10% by weight. As the CO increases, the specific gravity of treated clay tends to decrease, whereas the total organic carbon content of the treated clay tends to increase. The soil-water contact angle increases with an increase in CO until CO = 2.5%, and then maintains an almost constant value (≈134.0°. Resistance to water infiltration is improved by organosilane treatment under low hydrostatic pressure. However, water infiltration resistance under high hydrostatic pressure is reduced or exacerbated to the level of untreated clay. The maximum compacted dry weight density decreases with increasing CO. As the CO increases, the small strain shear modulus increases, whereas the effect of organosilane treatment on the constrained modulus is minimal. The results indicate that water-repellent kaolin clay possesses excellent engineering characteristics for a landfill cover material.

Engineering Characteristics of Chemically Treated Water-Repellent Kaolin

Science.gov (United States)

Choi, Youngmin; Choo, Hyunwook; Yun, Tae Sup; Lee, Changho; Lee, Woojin

2016-01-01

Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the surface of clay particle is modified with organosilanes in concentrations (CO) ranging from 0.5% to 10% by weight. As the CO increases, the specific gravity of treated clay tends to decrease, whereas the total organic carbon content of the treated clay tends to increase. The soil-water contact angle increases with an increase in CO until CO = 2.5%, and then maintains an almost constant value (≈134.0°). Resistance to water infiltration is improved by organosilane treatment under low hydrostatic pressure. However, water infiltration resistance under high hydrostatic pressure is reduced or exacerbated to the level of untreated clay. The maximum compacted dry weight density decreases with increasing CO. As the CO increases, the small strain shear modulus increases, whereas the effect of organosilane treatment on the constrained modulus is minimal. The results indicate that water-repellent kaolin clay possesses excellent engineering characteristics for a landfill cover material. PMID:28774098

Antioxidant activity and chemical composition of Juniperus excelsa ssp. polycarpos wood extracts.

Science.gov (United States)

Hosseinihashemi, S K; Dadpour, A; Lashgari, A

2017-03-01

Extracts from the wood of Juniperus excelsa ssp. polycarpos were analysed for their antioxidant activity using the DPPH method and compared with ascorbic acid and butylated hydroxytoluene. The most active extracts were analysed for their chemical composition using gas chromatography-mass spectrometry. Acetone extract was found to be moderately active as an antioxidant agent at 58.38%, which was lower than the value of vitamin C (98.56%) at the concentration of 14.20 mg/mL. The major components identified in the acetone extract as trimethylsilyl (TMS) derivatives were pimaric acid TMS (24.56%), followed by α-d-glucopyranoside,1,3,4,6-tetrakis-O-(TMS)-β-d-fructofuranosyl 2,3,4,6-tetrakis-O-(TMS) (21.39%), triflouromethyl-bis-(TMS)methyl ketone (9.32%), and cedrol (0.72%). The dissolved water:methanol (1:1 v/v) partitioned from acetone extract afforded 12 fractions; among them, the F9 fraction was found to have good antioxidant activity (88.49%) at the concentration of 14.20 mg/mL. The major compounds identified in F9 fraction were α-d-glucopyranoside, 1,3,4,6-tetrakis-O-(TMS) (20.22%) and trifluoromethyl-bis-(TMS)methyl ketone (5.10%).

Processing bulk natural wood into a high-performance structural material

Science.gov (United States)

Song, Jianwei; Chen, Chaoji; Zhu, Shuze; Zhu, Mingwei; Dai, Jiaqi; Ray, Upamanyu; Li, Yiju; Kuang, Yudi; Li, Yongfeng; Quispe, Nelson; Yao, Yonggang; Gong, Amy; Leiste, Ulrich H.; Bruck, Hugh A.; Zhu, J. Y.; Vellore, Azhar; Li, Heng; Minus, Marilyn L.; Jia, Zheng; Martini, Ashlie; Li, Teng; Hu, Liangbing

2018-02-01

Synthetic structural materials with exceptional mechanical performance suffer from either large weight and adverse environmental impact (for example, steels and alloys) or complex manufacturing processes and thus high cost (for example, polymer-based and biomimetic composites). Natural wood is a low-cost and abundant material and has been used for millennia as a structural material for building and furniture construction. However, the mechanical performance of natural wood (its strength and toughness) is unsatisfactory for many advanced engineering structures and applications. Pre-treatment with steam, heat, ammonia or cold rolling followed by densification has led to the enhanced mechanical performance of natural wood. However, the existing methods result in incomplete densification and lack dimensional stability, particularly in response to humid environments, and wood treated in these ways can expand and weaken. Here we report a simple and effective strategy to transform bulk natural wood directly into a high-performance structural material with a more than tenfold increase in strength, toughness and ballistic resistance and with greater dimensional stability. Our two-step process involves the partial removal of lignin and hemicellulose from the natural wood via a boiling process in an aqueous mixture of NaOH and Na2SO3 followed by hot-pressing, leading to the total collapse of cell walls and the complete densification of the natural wood with highly aligned cellulose nanofibres. This strategy is shown to be universally effective for various species of wood. Our processed wood has a specific strength higher than that of most structural metals and alloys, making it a low-cost, high-performance, lightweight alternative.

Study on the Effect of Heat Treatment on Physical Properties of Poplar and Beech Woods Impregnated with Nano-Copper and Nano-Silver

Directory of Open Access Journals (Sweden)

Hassan Siahposht

2012-06-01

Full Text Available Present study conducted to review effects of heat treatment on weight loss, water adsorption, and thickness swelling of poplar (Populus nigra and beech (Fagus oreintalis woods impregnated with nano-copper and nano-silver. Specimens werepressur (2.5 bar impregnated with 400 PPM water-based solution of nano-copper and nano-silver particles in a pressure vessel. For heat treatment, nano-cupper,  nano-silver impregnated and control specimens, were heat treated at 145°C temperature for 24 hours. Water absorption and thickness swelling decreased in heat treated and nano-heat treated specimens and this decrease in specimens impregnated with nano-copper and nano-silver was more obvious than in heat treated control specimens. The reasons were the degradation in crystal sections of celluloses chains and the ink variation of wood polymers. On the other hand, a comparison between heat treated and nano- heat treated specimens has shown weight loss further in nano-heat treated specimens. This shows that retent nano-copper and nano-silver by impregnation facilitates heat transfer in wood; and it may increase the process of degradation and pyrolysis of wood structures in inner parts of specimens.

Adsorption of manganese(II) ions by EDTA-treated activated carbons

Energy Technology Data Exchange (ETDEWEB)

Khan, A.Y.; Mazyck, D.W. [Jones Edmunds & Associates, Gainesville, FL (United States)

2009-07-01

The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical properties of the sorbents relative to their untreated counterparts. Furthermore, the modified sorbents exhibited a heightened capacity towards the adsorption of Mn(II) ions from aqueous media. Manganese(II) ion removal increased from 0 to 6.5 mg/g for the lignite coal-based sorbent, from 3.5 to 14.7 mg/g for the wood-based sorbent and from 1.3 to 7.9 mg/g for the bituminous coal-based sorbent. The increased removal is attributed, in part, to the creation of Lewis base sites that participate in covalent interactions and hydrolysis reactions.

Sono-chemical synthesis of cellulose nanocrystals from wood sawdust using Acid hydrolysis.

Science.gov (United States)

Shaheen, Th I; Emam, Hossam E

2018-02-01

Cellulose nanocrystal (CNC) is a unique material obtained from naturally occurring cellulose fibers. Owing to their mechanical, optical, chemical, and rheological properties, CNC gained significant interest. Herein, we investigate the potential of commercially non-recyclable wood waste, in particular, sawdust as a new resource for CNC. Isolation of CNC from sawdust was conducted as per acid hydrolysis which induced by ultrasonication technique. Thus, sawdust after being alkali delignified prior sodium chlorite bleaching, was subjected to sulfuric acid with concentration of 65% (w/w) at 60 ° C for 60min. After complete reaction, CNC were collected by centrifugation followed by dialyzing against water and finally dried via using lyophilization technique. The CNC yield attained values of 15% from purified sawdust. Acid hydrolysis mechanism exactly referred that, the amorphous regions along with thinner as well as shorter crystallites spreaded throughout the cellulose structure are digested by the acid leaving CNC suspension. The latter was freeze-dried to produce CNC powder. A thorough investigation pertaining to nanostructural characteristics of CNC was performed. These characteristics were monitored using TEM, SEM, AFM, XRD and FTIR spectra for following the changes in functionality. Based on the results obtained, the combination of sonication and chemical treatment was great effective in extraction of CNC with the average dimensions (diameter×length) of 35.2±7.4nm×238.7±81.2nm as confirmed from TEM. Whilst, the XRD study confirmed the crystal structure of CNC is obeyed cellulose type I with crystallinity index ∼90%. Cellulose nanocrystals are nominated as the best candidate within the range studied in the area of reinforcement by virtue of their salient textural features. Copyright © 2017 Elsevier B.V. All rights reserved.

Transcriptome Sequencing of Chemically Induced Aquilaria sinensis to Identify Genes Related to Agarwood Formation.

Science.gov (United States)

Ye, Wei; Wu, Hongqing; He, Xin; Wang, Lei; Zhang, Weimin; Li, Haohua; Fan, Yunfei; Tan, Guohui; Liu, Taomei; Gao, Xiaoxia

2016-01-01

Agarwood is a traditional Chinese medicine used as a clinical sedative, carminative, and antiemetic drug. Agarwood is formed in Aquilaria sinensis when A. sinensis trees are threatened by external physical, chemical injury or endophytic fungal irritation. However, the mechanism of agarwood formation via chemical induction remains unclear. In this study, we characterized the transcriptome of different parts of a chemically induced A. sinensis trunk sample with agarwood. The Illumina sequencing platform was used to identify the genes involved in agarwood formation. A five-year-old Aquilaria sinensis treated by formic acid was selected. The white wood part (B1 sample), the transition part between agarwood and white wood (W2 sample), the agarwood part (J3 sample), and the rotten wood part (F5 sample) were collected for transcriptome sequencing. Accordingly, 54,685,634 clean reads, which were assembled into 83,467 unigenes, were obtained with a Q20 value of 97.5%. A total of 50,565 unigenes were annotated using the Nr, Nt, SWISS-PROT, KEGG, COG, and GO databases. In particular, 171,331,352 unigenes were annotated by various pathways, including the sesquiterpenoid (ko00909) and plant-pathogen interaction (ko03040) pathways. These pathways were related to sesquiterpenoid biosynthesis and defensive responses to chemical stimulation. The transcriptome data of the different parts of the chemically induced A. sinensis trunk provide a rich source of materials for discovering and identifying the genes involved in sesquiterpenoid production and in defensive responses to chemical stimulation. This study is the first to use de novo sequencing and transcriptome assembly for different parts of chemically induced A. sinensis. Results demonstrate that the sesquiterpenoid biosynthesis pathway and WRKY transcription factor play important roles in agarwood formation via chemical induction. The comparative analysis of the transcriptome data of agarwood and A. sinensis lays the foundation

Production of bio-oil with low contents of copper and chlorine by fast pyrolysis of alkaline copper quaternary-treated wood in a fluidized bed reactor

International Nuclear Information System (INIS)

Koo, Won-Mo; Jung, Su-Hwa; Kim, Joo-Sik

2014-01-01

Fast pyrolysis of ACQ (alkaline copper quaternary)-treated wood was carried out in a bench-scale pyrolysis plant equipped with a fluidized bed reactor and char separation system. This study focused on the production of a bio-oil with low copper and chlorine contents, especially by adopting the fractional condensation of bio-oil using water condensers, an impact separator and an electrostatic precipitator. In addition, various analytical tools were applied to investigate the physicochemical properties of the pyrolysis products and the behavior of the preservative during pyrolysis. The bio-oil yield was maximized at 63.7 wt% at a pyrolysis temperature of 411 °C. Highly water-soluble holocellulose-derived components such as acetic acid and hydroxyacetone were mainly collected by the condensers, while lignin-derived components and levoglucosan were mainly observed in the oils collected by the impact separator and electrostatic precipitator. All the bio-oils produced in the experiments were almost free of copper and chlorine. Most copper in ACQ was transferred into the char. - Highlights: • ACQ(alkaline copper quaternary)-treated wood was successfully pyrolyzed in a bench-scale fluidized bed. • Bio-oils separately collected were different in their characteristics. • Bio-oils were free of didecyldimethylammonium chloride. • Bio oils were almost free of copper and chlorine. • The concentration of levoglucosan in a bio-oil was 24–31 wt%

Wood Identification of 18th Century Furniture. Interpreting Wood Naming Inventoires

Directory of Open Access Journals (Sweden)

Rocio Astrid BERNAL

2011-09-01

Full Text Available The 18th century Portuguese church furniture represents an extraordinary richness recognised worldwide, which demands safeguarding and valorisation. The identification of the wood of furniture artworks is the most important component for its comprehension and preservation. In this work wood anatomical characters of an 18th century Portuguese decorative furniture set from the Colegiada de São Martinho de Cedofeita, in Porto, were analysed to identify the woods used for manufacturing and to clarify their common names. Furthermore, the objectives were to recognise some of the criteria for choice of wood as well as the source of each wood. The woods identified from 16 fragments belong to Apuleia sp., Acacia sp., Neolamarckia sp. and Castanea sativa. Apuleia sp. and Acacia sp. woods most likely arrived from Brazil, while the Neolamarckia sp. woods likely arrived from India and the C. sativa woods from Portugal. The results are in accordance with the known Portuguese colonial sea routes of the 15th -18th centuries. Interestingly the terms found in the inventories can refer to finishing methods instead to the name of the woods, as for instance “oil wood” can refer to “oiled wood” or “linseed oiled wood”. The species choice may be related to the mechanical properties of the wood as well as the original tree size. Two large planks of Acacia sp. were used for the top of the “Portuguese arcaz”, and Apuleia sp. was found on main structural elements of this set of furniture, suggesting that wood colour was also important. Woods from Neolamarckia sp. and C. sativa, were also identified, being Castanea wood present only in the most recent pieces of the furniture set.