WorldWideScience

Sample records for chemical waste landfill

  1. Results of Hazardous and Mixed Waste Excavation from the Chemical Waste Landfill

    Energy Technology Data Exchange (ETDEWEB)

    Young, S. G.; Schofield, D. P.; Kwiecinski, D.; Edgmon, C. L.; Methvin, R.

    2002-02-27

    This paper describes the results of the excavation of a 1.9-acre hazardous and mixed waste landfill operated for 23 years at Sandia National Laboratories, Albuquerque, New Mexico. Excavation of the landfill was completed in 2 1/2 years without a single serious accident or injury. Approximately 50,000 cubic yards of soil contaminated with volatile and semi-volatile organics, metals, polychlorinated biphenyl compounds, and radioactive constituents was removed. In addition, over 400 cubic yards of buried debris was removed, including bulk debris, unknown chemicals, compressed gas cylinders, thermal and chemical batteries, explosive and ordnance debris, pyrophoric materials and biohazardous waste. Removal of these wastes included negotiation of multiple regulations and guidances encompassed in the Resource Conservation and Recovery Act (RCRA), the Toxic Substances Control Act (TSCA), and risk assessment methodology. RCRA concepts that were addressed include the area of contamination, permit modification, emergency treatment provision, and listed waste designation. These regulatory decisions enabled the project to overcome logistical and programmatic needs such as increased operational area, the ability to implement process improvements while maintaining a record of decisions and approvals.

  2. Chemical Waste Landfill Annual Post-Closure Care Report Calendar Year 2014

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Michael Marquand [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Little, Bonnie Colleen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    The CWL is a 1.9-acre remediated interim status landfill located in the southeastern corner of SNL/NM Technical Area III (Figures 2-1 and 2-2) undergoing post-closure care in accordance with the PCCP (NMED October 2009 and subsequent revisions). From 1962 until 1981, the CWL was used for the disposal of chemical and solid waste generated by SNL/NM research activities. Additionally, a small amount of radioactive waste was disposed of during the operational years. Disposal of liquid waste in unlined pits and trenches ended in 1981, and after 1982 all liquid waste disposal was terminated. From 1982 through 1985, only solid waste was disposed of at the CWL, and after 1985 all waste disposal ended. The CWL was also used as a hazardous waste drum-storage facility from 1981 to 1989. A summary of the CWL disposal history is presented in the Closure Plan (SNL/NM December 1992) along with a waste inventory based upon available disposal records and information.

  3. Adaptive sampling strategy support for the unlined chromic acid pit, chemical waste landfill, Sandia National Laboratories, Albuquerque, New Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R.L.

    1993-11-01

    Adaptive sampling programs offer substantial savings in time and money when assessing hazardous waste sites. Key to some of these savings is the ability to adapt a sampling program to the real-time data generated by an adaptive sampling program. This paper presents a two-prong approach to supporting adaptive sampling programs: a specialized object-oriented database/geographical information system (SitePlanner{trademark} ) for data fusion, management, and display and combined Bayesian/geostatistical methods (PLUME) for contamination-extent estimation and sample location selection. This approach is applied in a retrospective study of a subsurface chromium plume at Sandia National Laboratories` chemical waste landfill. Retrospective analyses suggest the potential for characterization cost savings on the order of 60% through a reduction in the number of sampling programs, total number of soil boreholes, and number of samples analyzed from each borehole.

  4. Landfills - Municipal Waste Operations

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — A Municipal Waste Operation is a DEP primary facility type related to the Waste Management Municipal Waste Program. The sub-facility types related to Municipal Waste...

  5. ENGINEERING ASPECTS OF LANDFILLING MUNICIPAL SOLID WASTE

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Sanitary landfilling is the most important method of municipalsolid waste disposal in China. Landfill sites are always set up in mountain valley, on plain or beside seashore. A complete landfill consists of base system, cover system, and leachate collection and gas extraction system. This paper reviews the state-of-the-art landfilling technology in China and collection discusses research projects for engineers.

  6. Landfilling of waste incineration residues

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Astrup, Thomas; Cai, Zuansi

    2002-01-01

    Residues from waste incineration are bottom ashes and air-pollution-control (APC) residues including fly ashes. The leaching of heavy metals and salts from the ashes is substantial and a wide spectrum of leaching tests and corresponding criteria have been introduced to regulate the landfilling...

  7. Request for interim approval to operate Trench 94 of the 218-E-12B Burial Ground as a chemical waste landfill for disposal of polychlorinated biphenyl waste in submarine reactor compartments. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    Cummins, G.D.

    1994-06-01

    This request is submitted to seek interim approval to operate a Toxic Substances Control Act (TSCA) of 1976 chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) waste. Operation of a chemical waste landfill for disposal of PCB waste is subject to the TSCA regulations of 40 CFR 761. Interim approval is requested for a period not to exceed 5 years from the date of approval. This request covers only the disposal of small 10 quantities of solid PCB waste contained in decommissioned, defueled submarine reactor compartments (SRC). In addition, the request applies only to disposal 12 of this waste in Trench 94 of the 218-E-12B Burial Ground (Trench 94) in the 13 200 East Area of the US Department of Energy`s (DOE) Hanford Facility. Disposal of this waste will be conducted in accordance with the Compliance 15 Agreement (Appendix H) between the DOE Richland Operations Office (DOE-RL) and 16 the US Environmental Protection Agency (EPA), Region 10. During the 5-year interim approval period, the DOE-RL will submit an application seeking final 18 approval for operation of Trench 94 as a chemical waste landfill, including 19 any necessary waivers, and also will seek a final dangerous waste permit from 20 the Washington State Department of Ecology (Ecology) for disposal of lead 21 shielding contained in the SRCS.

  8. GEOTECHNICAL DESIGN OF SOLID WASTE LANDFILL SITES

    Directory of Open Access Journals (Sweden)

    Suat AKBULUT

    2003-02-01

    Full Text Available Solid waste landfills are important engineering structures for protection of wastes, decrease of environmental pollution, and especially prevention of soil and water pollution. Solid wastes should conveniently be maintained in landfill areas to control environmental pollution caused by waste disposals. Until the middle of this century clay liners were used for maintenance of waste disposal, but it was observed that these liner systems were insufficient. Today thinner and less permeable liner systems are constructed by using synthetic materials. In this study, by evaluating the waste landfills, site assessment of landfills and construction of natural and synthetic liner systems were summarized respectively, and especially the design properties of these systems were examined intensively. Also, leachate collection and removal facilities, landfill gas collection unites, and final cover unites were evaluated in a detailed way.

  9. Closure Alternatives for Municipal Waste Landfills.Study Case: Municipal Waste Landfill Medias,Sibiu County

    Directory of Open Access Journals (Sweden)

    MIHĂIESCU R.

    2010-12-01

    Full Text Available In the recent decades, the environmental impact produced by municipal solid wastes has received specialattention. All new EU countries are involved in the process of implementation of the European Council Directive31/99/EC on the landfill of waste in the European Union. As consequence National legislation, adapted to fit the EUrequirements, focuses on integrated waste management and environmental control of municipal solid waste landfills,from start-up to closure and assimilation into the environment. In Romania, by Government decision, HG 349/2005,was established the obligatoriness of closing unconform waste landfills located in urban areas starting at July 2009. Asconsequence the owner of municipal waste landfill Medias started the proceedings of closure for the landfill. The aim ofthis study is to compare, from an environmental point of view, different alternatives for the closure of the municipalsolid waste landfill Somard-Medias (Romania.

  10. Evaluation of copper, zinc, and chromium concentration in landfill soil and hospital waste ash of Shahrekord municipal solid waste landfill

    Directory of Open Access Journals (Sweden)

    M Hatami Manesh

    2015-08-01

    Conclusion: High concentrations of metals determined in the present study represents the high application of these metals in the structure of municipal and hospital solid wastes and also their inaccurate separation. Thus, awareness about physical and chemical characteristics of municipal and hospital wastes and also the landfill soil is necessary for evaluating their effects on the soil quality and surrounding environments.

  11. Product specific emissions from municipal solid waste landfills

    DEFF Research Database (Denmark)

    Nielsen, Per Henning; Exner, Stephan; Jørgensen, Anne-Mette;

    1998-01-01

    in different countries, composition of the product and physical/chemical/biological properties of waste product components) and output data (e.g. estimated emissions to atmosphere and water) are given for a fictive waste product made of representative types of components (toluene, cellulose, polyvinylchloride......This paper presents and verifies the computer tool LCA-LAND for estimation of emissions from specific waste products disposed in municipal solid waste landfills in European countries for use in the inventory analysis of LCA. Examples of input data (e.g. distribution of the waste product...... (PVC), copper and chloride). Since waste products from different processes in the product system may be disposed at different landfills where they are mixed with waste originating outside the product system, the estimated emissions from specific waste products cannot be compared with measured emissions...

  12. Modelling biogas production of solid waste: application of the BGP model to a synthetic landfill

    Science.gov (United States)

    Rodrigo-Ilarri, Javier; Segura-Sobrino, Francisco

    2013-04-01

    Production of biogas as a result of the decomposition of organic matter included on solid waste landfills is still an issue to be understood. Reports on this matter are rarely included on the engineering construction projects of solid waste landfills despite it can be an issue of critical importance while operating the landfill and after its closure. This paper presents an application of BGP (Bio-Gas-Production) model to a synthetic landfill. The evolution in time of the concentrations of the different chemical compounds of biogas is studied. Results obtained show the impact on the air quality of different management alternatives which are usually performed in real landfills.

  13. Landfills

    Data.gov (United States)

    Vermont Center for Geographic Information — This data set defines both current and historic landfills/waste disposal storage sites for the State of Vermont. Historic landfills were identified with the...

  14. Characterization of thermal properties of municipal solid waste landfills.

    Science.gov (United States)

    Faitli, József; Magyar, Tamás; Erdélyi, Attila; Murányi, Attila

    2015-02-01

    Municipal waste landfills represent not only a source of landfill gases, but a source of thermal energy as well. The heat in landfills is generated by physical, chemical and microbiological processes. The goal of our study was to characterize the thermal properties of municipal solid waste (MSW) samples of the given landfill. A new apparatus was designed and constructed to measure heat flow. A systematic test series of 17 discrete measurements was carried out with municipal waste samples of 1.0-1.7 m(3). The thermal conductivity, heat diffusivity and specific heat capacity of the samples were determined. Analysing the results of the sampling and our experiments it was realized that the theoretical fundaments should be clarified. Two theories were developed for the serial and for the parallel heat flow in three phase disperse systems. The serial and parallel models resulted in different theoretical estimations. The measured thermal conductivity and heat diffusivity were better characterized by the parallel heat flow estimations. The results show that heat can flow parallel in solid, liquid and gas phases. Characterization of thermal properties serves to establish the fundament of heat extraction from municipal waste landfills.

  15. A simple model for the distribution and fate of organic chemicals in a landfill: MOCLA

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Christensen, Thomas Højlund

    2001-01-01

    of degradation and transformation in the landfill. Local equilibrium is assumed for the distribution of the chemicals in the landfill as expressed by Henry’s Law for the leachate-gas interface, and by the linear partition coefficient based on the waste solid organic carbon content for the waste......A simple mathematical model (MOCLA: Model for Organic Chemicals in Landfills) is presented, describing the distribution of organic chemicals between leachate, gas and solid waste. The model also predicts the fate of the chemicals in terms of emissions with leachate and landfill gas and in terms......-leachate interface. Degradation of the chemicals is expressed as a first order reaction. Annual specific leachate and gas generation data in combination with data on landfill area and volume allow for prediction of main emission routes. Model simulations involving two landfill scenarios for a number of chemicals...

  16. Phytoremediation of Polychlorobiphenyls PCBs in Landfill E-Waste Leachate with Water Hyacinth E.Crassipes

    OpenAIRE

    E.A Omondi; P.K Ndiba and P.G Njuru

    2015-01-01

    Abstract The presence of e-waste in a landfill can release persistent organic pollutants POPs including polychlorinated biphenyls PCBs into the environment. PCBs are a family of more than 200 chemical compounds congeners each of which consists of two benzene rings and one to ten chlorine atoms. This study investigated use of water hyacinth Eichhornia crassipes for phytoremediation of landfill leachate waste containing PCB. Landfill leachate was simulated in the laboratory by spiking water sam...

  17. Analysis of the contaminants released from municipal solid waste landfill site: A case study.

    Science.gov (United States)

    Samadder, S R; Prabhakar, R; Khan, D; Kishan, D; Chauhan, M S

    2017-02-15

    Release and transport of leachate from municipal solid waste landfills pose a potential hazard to both surrounding ecosystems and human populations. In the present study, soil, groundwater, and surface water samples were collected from the periphery of a municipal solid waste landfill (located at Ranital of Jabalpur, Madhya Pradesh, India) for laboratory analysis to understand the release of contaminants. The landfill does not receive any solid wastes for dumping now as the same is under a landfill closure plan. Groundwater and soil samples were collected from the bore holes of 15m deep drilled along the periphery of the landfill and the surface water samples were collected from the existing surface water courses near the landfill. The landfill had neither any bottom liner nor any leachate collection and treatment system. Thus the leachate generated from the landfills finds paths into the groundwater and surrounding surface water courses. Concentrations of various physico-chemical parameters including some toxic metals (in collected groundwater, soil, and surface water samples) and microbiological parameters (in surface water samples) were determined. The analyzed data were integrated into ArcGIS environment and the spatial distribution of the metals and other physic- chemical parameter across the landfill was extrapolated to observe the distribution. The statistical analysis and spatial variations indicated the leaching of metals from the landfill to the groundwater aquifer system. The study will help the readers and the municipal engineers to understand the release of contaminants from landfills for better management of municipal solid wastes.

  18. Household hazardous waste in municipal landfills: contaminants in leachate.

    Science.gov (United States)

    Slack, R J; Gronow, J R; Voulvoulis, N

    2005-01-20

    Household hazardous waste (HHW) includes waste from a number of household products such as paint, garden pesticides, pharmaceuticals, photographic chemicals, certain detergents, personal care products, fluorescent tubes, waste oil, heavy metal-containing batteries, wood treated with dangerous substances, waste electronic and electrical equipment and discarded CFC-containing equipment. Data on the amounts of HHW discarded are very limited and are hampered by insufficient definitions of what constitutes HHW. Consequently, the risks associated with the disposal of HHW to landfill have not been fully elucidated. This work has focused on the assessment of data concerning the presence of hazardous chemicals in leachates as evidence of the disposal of HHW in municipal landfills. Evidence is sought from a number of sources on the occurrence in landfill leachates of hazardous components (heavy metals and xenobiotic organic compounds [XOC]) from household products and the possible disposal-to-emissions pathways occurring within landfills. This review demonstrates that a broad range of xenobiotic compounds occurring in leachate can be linked to HHW but further work is required to assess whether such compounds pose a risk to the environment and human health as a result of leakage/seepage or through treatment and discharge.

  19. Industrial Waste Landfill IV upgrade package

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-29

    The Y-12 Plant, K-25 Site, and ORNL are managed by DOE`s Operating Contractor (OC), Martin Marietta Energy Systems, Inc. (Energy Systems) for DOE. Operation associated with the facilities by the Operating Contractor and subcontractors, DOE contractors and the DOE Federal Building result in the generation of industrial solid wastes as well as construction/demolition wastes. Due to the waste streams mentioned, the Y-12 Industrial Waste Landfill IV (IWLF-IV) was developed for the disposal of solid industrial waste in accordance to Rule 1200-1-7, Regulations Governing Solid Waste Processing and Disposal in Tennessee. This revised operating document is a part of a request for modification to the existing Y-12 IWLF-IV to comply with revised regulation (Rule Chapters 1200-1-7-.01 through 1200-1-7-.08) in order to provide future disposal space for the ORR, Subcontractors, and the DOE Federal Building. This revised operating manual also reflects approved modifications that have been made over the years since the original landfill permit approval. The drawings referred to in this manual are included in Drawings section of the package. IWLF-IV is a Tennessee Department of Environmental and Conservation/Division of Solid Waste Management (TDEC/DSWM) Class 11 disposal unit.

  20. Product specific emissions from municipal solid waste landfills

    DEFF Research Database (Denmark)

    Nielsen, Per Henning; Hauschild, Michael Zwicky

    1998-01-01

    For the inventory analysis of environmental impacts associated with products in LCA there is a great need for estimates of emissions from waste products disposed at municipal solid waste landfills (product specific emissions). Since product specific emissions can not be calculated or measured...... directly at the landfills, they must be estimated by modelling of landfill processes. This paper presents a landfill model based on a large number of assumptions and approximations concerning landfill properties, waste product properties and characteristics of various kinds of environmental protection...... systems (e.g. landfill gas combustion units and leachate treatment units). The model is useful for estimation of emissions from waste products disposed in landfills and it has been made operational in the computer tool LCA-LAND presented in a following paper. In the model, waste products are subdivided...

  1. Paper waste - Recycling, incineration or landfilling?

    DEFF Research Database (Denmark)

    Villanueva, Alejandro; Wenzel, Henrik

    2007-01-01

    comparisons of different management options for waste paper. Despite claims of inconsistency, the LCAs reviewed illustrate the environmental benefits in recycling over incineration or landfill options, for paper and cardboard waste. This broad consensus was found despite differences in geographic location......A review of existing life cycle assessments (LCAs) on paper and cardboard waste has been undertaken. The objectives of the review were threefold. Firstly, to see whether a consistent message comes out of published LCA literature on optimum disposal or recycling solutions for this waste type....... Such message has implications for current policy formulation on material recycling and disposal in the EU. Secondly, to identify key methodological issues of paper waste management LCAs, and enlighten the influence of such issues on the conclusions of the LCA studies. Thirdly, in light of the analysis made...

  2. Removal of high concentrated ammonia nitrogen from landfill leachate by landfilled waste layer

    Institute of Scientific and Technical Information of China (English)

    GUO Hui-dong; HE Pin-jing; SHAO Li-ming; LI Guo-jian

    2004-01-01

    The landfill of municipal solid waste(MSW) could be regarded as denitrification reactor and used in ammonia nitrogen biological removal process. In this research, the process was applied to municipal solid waste(MSW) collected in Shanghai, China, which was characterized with high food waste content. The NH4+ removal efficiency in the system of SBR nitrifying reactor followed by fresh and matured landfilled waste layer in series was studied. In the nitrifying reactor, above 90% of NH4+ in leachate was oxidized to NO2- and NO3-. Then high concentrated NO2- and NO3- was removed in the way of denitrification process in fresh landfilled waste layer. At the same time, degradation of fresh landfilled waste was accelerated. Up to the day 120, 136.5 gC/(kg dry waste) and 17.9 gN/(kg dry waste) were produced from waste layer. It accounted for 50.15% and 86.89% of the total carbon and nitrogen content of preliminary fresh waste, which was 4.42 times and 5.17 times higher than that of reference column respectively. After filtering through matured landfilled waste, BOD5 concentration in leachate dropped to below 100 mg/L, which would not affect following nitrification adversely. Because the matured landfilled waste acted as a well methanogenic reactor, 23% of carbon produced accumulatively from fresh landfilled waste degradation was converted into CH4.

  3. Microbiological indication of municipal solid waste landfill non-stabilization

    Institute of Scientific and Technical Information of China (English)

    ZHOU Qi-xing; SYLVESTER Runyuzi; YU Ji-yu; ZHANG Qian-ru

    2004-01-01

    Accidental collapse resulted from unstable factors is an important technological problem to be solved in sanitary landfill. Microbiological degradation of organic matters in landfilled solid waste are an important unstable factor. A landfill reactor was thus manufactured and installed to examine quantitative and population dynamics of microorganisms during degradation of landfilled solid waste. It was showed that unstable landfill can be reflected and indicated by microbiological features such as rapidly decreased growth amount of microorganisms, no detection of fungi and actinomyces, and changing the dominant population into methanogenic bacteria and Acinotobacter.

  4. Research on Health Risk-Based Radioactive Acceptance Criteria of Municipal Solid Waste Landfill

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The article focuses on the topics of Health Risk-Based Radioactive Acceptance Criteria of Municipal Solid Waste Landfill (MSWL, including municipal refuse landfills or industrial solid waste landfills, MSWL). At first, health risk assessment

  5. Fate of chemical warfare agents and toxic indutrial chemicals in landfills

    DEFF Research Database (Denmark)

    Bartelt-Hunt, D.L.; Barlaz, M.A.; Knappe, D.R.U.

    2006-01-01

    One component of preparedness for a chemical attack is planning for the disposal of contaminated debris. To assess the feasibility of contaminated debris disposal in municipal solid waste (MSW) landfills, the fate of selected chemical warfare agents (CWAs) and toxic industrial chemicals (TICs......) in MSW landfills was predicted with a mathematical model. Five blister agents [sulfur mustard (HD), nitrogen mustard (HN-2), lewisite (L), ethyldichloroarsine (ED), and phosgene oxime (CX)], eight nerve agents [tabun (GA), sarin (GB), soman (GD), GE, GF, VX, VG, and VM], one riot-control agent [CS...

  6. Waste survey - landfill disposability of furniture industrial wastes from varnishing processes; Huonekaluteollisuuden maalaamokaappijaetteiden kaatopaikkakelpoisuus

    Energy Technology Data Exchange (ETDEWEB)

    Vaajasaari, K.; Kulovaara, M.; Joutti, A.; Schulz, E. [Pirkanmaan Ympaeristoekeskus, Tampere (Finland)

    2001-07-01

    The objective of this study was to screen the environmental hazard of eight different furniture industrial wastes in context of their landfill disposal. These wastes are resulting from the varnishing process of furniture manufacture. Four of these materials were collected from a dry varnishing processes and the other four residues from a wet varnishing processes. We wanted to classify these industrial wastes according to their leaching and ecotoxicological properties to evaluate if these kind of materials could be disposed off to a non-hazardous landfill. Leaching properties of residues were determined with European standard draft prEN 12457-2 method. The toxicity measurement of the leaching tests eluates from furniture industrial residues was carried out with a plant (the onion Allium cepa root elongation test), bacteria (the luminescent bacteria Vibrio fischeri assay) and enzyme inhibition (the reverse electron transport, RET, assay). Chemical concentrations of TOC, formaldehyde and solvents in solid wastes and their leaching test eluates were measured simultaneously. The results showed that dry residues contained high amount of formaldehyde which will leach out from the wastes a long time period if wastes are in contact with water at landfill conditions. Furthermore, the water leachable substances in dry residues resulted very high acute toxicity. Toxicity test results confirmed the conclusions drawn from the chemical data as well in wet residues. Two of the wet residues with the highest solvent concentrations were clearly toxic, while the other two wet residues had the smallest concentrations of the harmful substances and only slight acute toxicity. The biggest problems in context of landfill disposability are connected to a high liquid content of wet residues (over 70 %). (orig.)

  7. 40 CFR 60.752 - Standards for air emissions from municipal solid waste landfills.

    Science.gov (United States)

    2010-07-01

    ... municipal solid waste landfills. 60.752 Section 60.752 Protection of Environment ENVIRONMENTAL PROTECTION... of Performance for Municipal Solid Waste Landfills § 60.752 Standards for air emissions from municipal solid waste landfills. (a) Each owner or operator of an MSW landfill having a design capacity...

  8. BIOLEACH: Coupled modeling of leachate and biogas production on solid waste landfills

    Science.gov (United States)

    Rodrigo-Clavero, Maria-Elena; Rodrigo-Ilarri, Javier

    2015-04-01

    One of the most important factors to address when performing the environmental impact assessment of urban solid waste landfills is to evaluate the leachate production. Leachate management (collection and treatment) is also one of the most relevant economical aspects to take into account during the landfill life. Leachate is formed as a solution of biological and chemical components during operational and post-operational phases on urban solid waste landfills as a combination of different processes that involve water gains and looses inside the solid waste mass. Infiltration of external water coming from precipitation is the most important component on this water balance. However, anaerobic waste decomposition and biogas formation processes play also a role on the balance as water-consuming processes. The production of leachate one biogas is therefore a coupled process. Biogas production models usually consider optimal conditions of water content on the solid waste mass. However, real conditions during the operational phase of the landfill may greatly differ from these optimal conditions. In this work, the first results obtained to predict both the leachate and the biogas production as a single coupled phenomenon on real solid waste landfills are shown. The model is applied on a synthetic case considering typical climatological conditions of Mediterranean catchments.

  9. The degradability of biodegradable plastics in aerobic and anaerobic waste landfill model reactors.

    Science.gov (United States)

    Ishigaki, Tomonori; Sugano, Wataru; Nakanishi, Akane; Tateda, Masafumi; Ike, Michihiko; Fujita, Masanori

    2004-01-01

    Degradabilities of four kinds of commercial biodegradable plastics (BPs), polyhydroxybutyrate and hydroxyvalerate (PHBV) plastic, polycaprolactone plastic (PCL), blend of starch and polyvinyl alcohol (SPVA) plastic and cellulose acetate (CA) plastic were investigated in waste landfill model reactors that were operated as anaerobically and aerobically. The application of forced aeration to the landfill reactor for supplying aerobic condition could potentially stimulate polymer-degrading microorganisms. However, the individual degradation behavior of BPs under the aerobic condition was completely different. PCL, a chemically synthesized BP, showed film breakage under the both conditions, which may have contributed to a reduction in the waste volume regardless of aerobic or anaerobic conditions. Effective degradation of PHBV plastic was observed in the aerobic condition, though insufficient degradation was observed in the anaerobic condition. But the aeration did not contribute much to accelerate the volume reduction of SPVA plastic and CA plastic. It could be said that the recalcitrant portions of the plastics such as polyvinyl alcohol in SPVA plastic and the highly substituted CA in CA plastic prevented the BP from degradation. These results indicated existence of the great variations in the degradability of BPs in aerobic and anaerobic waste landfills, and suggest that suitable technologies for managing the waste landfill must be combined with utilization of BPs in order to enhance the reduction of waste volume in landfill sites.

  10. Quantifying capital goods for waste landfilling

    DEFF Research Database (Denmark)

    Brogaard, Line Kai-Sørensen; Stentsøe, Steen; Willumsen, Hans Christian

    2013-01-01

    Materials and energy used for construction of a hill-type landfill of 4 million m3 were quantified in detail. The landfill is engineered with a liner and leachate collections system, as well as a gas collection and control system. Gravel and clay were the most common materials used, amounting to ...

  11. Sensitivity analysis of the waste composition and water content parameters on the biogas production models on solid waste landfills

    Science.gov (United States)

    Rodrigo-Ilarri, Javier; Segura-Sobrino, Francisco; Rodrigo-Clavero, Maria-Elena

    2014-05-01

    Landfills are commonly used as the final deposit of urban solid waste. Despite the waste is previously processed on a treatment plant, the final amount of organic matter which reaches the landfill is large however. The biodegradation of this organic matter forms a mixture of greenhouse gases (essentially Methane and Carbon-Dioxide as well as Ammonia and Hydrogen Sulfide). From the environmental point of view, solid waste landfills are therefore considered to be one of the main greenhouse gas sources. Different mathematical models are usually applied to predict the amount of biogas produced on real landfills. The waste chemical composition and the availability of water in the solid waste appear to be the main parameters of these models. Results obtained when performing a sensitivity analysis over the biogas production model parameters under real conditions are shown. The importance of a proper characterizacion of the waste as well as the necessity of improving the understanding of the behaviour and development of the water on the unsaturated mass of waste are emphasized.

  12. An integrated approach combining chemical analysis and an in vivo bioassay to assess the estrogenic potency of a municipal solid waste landfill leachate in Qingdao.

    Directory of Open Access Journals (Sweden)

    Yufeng Gong

    Full Text Available Various adverse effects related to landfill leachate have made leachates an important issue in past decades, and it has been demonstrated that landfill leachate is an important source of environmental estrogens. In this study, we employed chemical analysis of some already evaluated estrogenic substances, in combination with a bioassay using several specific biomarkers (e.g., plasma vitellogenin and sex steroids, enzyme activity of gonad gamma-glutamyl transpeptidase, and gonadosomatic index to evaluate the estrogenic activities in outlets from different stages of the leachate treatment process. The results indicated that 5 environmental estrogens (4-t-octylphenol, bisphenol A, di-ethyl phthalate, di-n-butyl phthalate, and diethylhexyl phthalate were detected by a gas chromatography-mass spectrometry, and the concentrations in leachate samples were 6153 ng/L, 3642 ng/L, 2139 ng/L, 5900 ng/L, and 9422 ng/L, respectively. Leachate (1∶200 diluted induced the synthesis of plasma vitellogenin and led to decreased enzyme activity of gonad gamma-glutamyl transpeptidase and gonadosomatic index in male goldfish (Carassius auratus after a 28-day exposure, while increased circulating 17β-estradiol level was also observed in males exposed to treated effluent. Although the target EEs were partially removed with removal rates varying from 87.2% to 99.77% by the "membrane bioreactor+reverse osmosis+aeration zeolite biofilter" treatment process, the treated effluent is still estrogenic to fish. The method combined chemical techniques with the responses of test organisms allowing us to identify the group of estrogen-like chemicals so that we were able to evaluate the overall estrogenic effects of a complex mixture, avoiding false negative assessments.

  13. A Decision Making Tool for Hazardous Waste Landfill Site Selection

    Directory of Open Access Journals (Sweden)

    P. Pandiyan

    2011-01-01

    Full Text Available Problem statement: Continuous global environmental crisis and degradation has been a challenge for the sustainability of living on earth. This threat was posed by industrialization, high products need, urbanization and population growth activities. As a result, the hazardous waste generation has tremendously increased. Approach: Landfill was one of the positive approaches to handle hazardous waste generated in great quantity. The appropriate selection of landfill site played a major role to remediate the hazardous waste materials. Attributes to be considered for decision-making were selected based on literature, observations with weightage assigned to each attribute following the pair wise comparison method and sensitivity index on a scale of 0 to 1 based on attribute measurement. The attributes were then grouped and ranked following Delphi approach. Results: In environmental assessment, field based study of three landfill sites such as Melakottaiyur, Pachaiyankuppam and Gummidipoondi in Tamil Nadu, India were selected and the sites scored a Risk Index (RI of 298.75, 369.05 and 408.25 respectively. In economical assessment, economic viability related attributes were analyzed and the three landfill site such as Pachaiyankuppam, Melakottaiyur and Gummidipoondi scored a RI of 86.1, 94.3 and 131.5 respectively. Conclusion/Recommendations: In environmental assessment the landfill sites were shortlisted. In order to achieve economic sustainability of the landfill, economic viability related attributes has to be analyzed with high priority and weightage in economical assessment.

  14. Contribution of individual waste fractions to the environmental impacts from landfilling of municipal solid waste

    DEFF Research Database (Denmark)

    Manfredi, Simone; Tonini, Davide; Christensen, Thomas Højlund

    2010-01-01

    PE/tonne). These savings are mostly determined by the waste fractions characterized by a high content of biogenic carbon (paper, organics, other combustible waste). These savings are due to emissions from energy generation avoided by landfill gas utilization, and by the storage of biogenic carbon in the landfill due......A number of LCA-based studies have reported on the environmental performance of landfilling of mixed waste, but little is known about the relative contributions of individual waste fractions to the overall impact potentials estimated for the mixed waste. In this paper, an empirical model has been...... used to estimate the emissions to the environment from landfilling of individual waste fractions. By means of the LCA-model EASEWASTE, the emissions estimated have been used to quantify how much of the overall impact potential for each impact category is to be attributed to the individual waste...

  15. 75 FR 53268 - Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program

    Science.gov (United States)

    2010-08-31

    ... AGENCY 40 CFR Parts 239 and 258 Adequacy of New Hampshire Municipal Solid Waste Landfill Permit Program... approve New Hampshire's modification of its approved Municipal Solid Waste Landfill Program. On March 22... be issued to certain municipal solid waste landfills by approved states. On June 28, 2010...

  16. 78 FR 5350 - Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program

    Science.gov (United States)

    2013-01-25

    ... AGENCY 40 CFR Parts 239 and 258 Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program... approve Massachusetts's modification of its approved Municipal Solid Waste Landfill Program. On March 22... be issued to certain municipal solid waste landfills by approved states. On December 7,...

  17. Parametric Analysis of Leachate and Water Resources around Municipal Solid Waste Landfill area in Solan

    Directory of Open Access Journals (Sweden)

    Sharma Deepika

    2016-01-01

    Full Text Available Leachate is defined as the liquid that drains from the landfill. The paper presents the physico-chemical, bacteriological and heavy metal testing results carried out for leachate, surface and sub-surface water samples collected from municipal solid waste landfill and different water sources in Solan to find out the effect of leachate percolation on groundwater quality. Physico-chemical parameters analysed were, pH, Total Dissolve Solid (TDS, sulphate, turbidity, Electrical Conductivity (EC while biological parameters tested were Biological Oxygen Demand (BOD, Chemical Oxygen Demand (COD, Most Probable Number (MPN test and ammonical nitrogen. Testing for heavy metals (Pb, Zn, Cr, Ni, Fe were carried out and have been reported. The results reveal that the leachate from the unlined landfill may have a significant impact on the groundwater resource (often used as drinking source particularly because of the toxic nature of the leachate coupled with the soil characteristics which is permeable in nature.

  18. Landfilling of waste: accounting of greenhouse gases and global warming contributions

    DEFF Research Database (Denmark)

    Manfredi, Simone; Tonini, Davide; Christensen, Thomas Højlund

    2009-01-01

    Accounting of greenhouse gas (GHG) emissions from waste landfilling is summarized with the focus on processes and technical data for a number of different landfilling technologies: open dump (which was included as the worst-case-scenario), conventional landfills with flares and with energy recovery......, and landfills receiving low-organic-carbon waste. The results showed that direct emissions of GHG from the landfill systems (primarily dispersive release of methane) are the major contributions to the GHG accounting, up to about 1000 kg CO2-eq. tonne —1 for the open dump, 300 kg CO2-eq. tonne —1...... for conventional landfilling of mixed waste and 70 kg CO2-eq. tonne—1 for low-organic-carbon waste landfills. The load caused by indirect, upstream emissions from provision of energy and materials to the landfill was low, here estimated to be up to 16 kg CO2-eq. tonne—1. On the other hand, utilization of landfill...

  19. Methanogenesis acceleration of fresh landfilled waste by micro-aeration

    Institute of Scientific and Technical Information of China (English)

    SHAO Li-ming; HE Pin-jing; ZHANG Hua; YU Xiao-hua; LI Guo-jian

    2005-01-01

    When municipal solid waste(MSW) with high content of food waste is landfilled, the rapid hydrolysis of food waste results in the imbalance of anaerobic metabolism in the landfill layer, indicated by accumulation of volatile fatty acids(VFA) and decrease of pH value.This occurrence could lead to long lag time before the initiation of methanogenesis and to the production of strong leachate. Simulated landfill columns with forced aeration, with natural ventilation, and with no aeration, were monitored regarding their organics degradation rate with leachate recirculation. Hydrolysis reactions produced strong leachate in the column with no aeration. With forced aeration, the produced VFA could be effectively degraded, leading to the reduction in COD of the leachate effluent since the week 3. The CH4 in the frequency of twice/d, could amount to 40% (v/v) after only 20 weeks. This amount had increased up to 50% afterward even with no aeration. Most of COD in the recirculated leachate was removed. Using natural ventilation, CH4 could also be produced and the COD of the leachate effluent be reduced after 10 weeks of operation. However, the persistent existence of oxygen in the landfill layer yielded instability in methanogenesis process.

  20. Impact assessment of intermediate soil cover on landfill stabilization by characterizing landfilled municipal solid waste.

    Science.gov (United States)

    Qi, Guangxia; Yue, Dongbei; Liu, Jianguo; Li, Rui; Shi, Xiaochong; He, Liang; Guo, Jingting; Miao, Haomei; Nie, Yongfeng

    2013-10-15

    Waste samples at different depths of a covered municipal solid waste (MSW) landfill in Beijing, China, were excavated and characterized to investigate the impact of intermediate soil cover on waste stabilization. A comparatively high amount of unstable organic matter with 83.3 g kg(-1) dry weight (dw) total organic carbon was detected in the 6-year-old MSW, where toxic inorganic elements containing As, Cd, Cr, Cu, Mn, Ni, Pb, and Zn of 10.1, 0.98, 85.49, 259.7, 530.4, 30.5, 84.0, and 981.7 mg kg(-1) dw, respectively, largely accumulated because of the barrier effect of intermediate soil cover. This accumulation resulted in decreased microbial activities. The intermediate soil cover also caused significant reduction in moisture in MSW under the soil layer, which was as low as 25.9%, and led to inefficient biodegradation of 8- and 10-year-old MSW. Therefore, intermediate soil cover with low permeability seems to act as a barrier that divides a landfill into two landfill cells with different degradation processes by restraining water flow and hazardous matter.

  1. Assessment of microbiological and chemical properties in a municipal landfill area.

    Science.gov (United States)

    Frączek, Krzysztof J; Ropek, Dariusz R; Lenart-Boroń, Anna M

    2014-01-01

    This study aimed at determining the environmental hazards for soils posed by a large municipal landfilll. The concentrations of heavy metals and Policyclic Aromatic Hydrocarbons, as well as microbial composition (i.e., mesophilic bacteria, actinomycetes, molds, Salmonella, Staphylococcus, Clostridium perfringens) in four soils within and in the vicinity of the landfill were evaluated and compared to waste samples. Both chemical and microbiological analyses revealed only limited contamination of surrounding areas. Although the increased alkalinity of soils was detected, the concentrations of heavy metals and Polycyclic Aromatic Hydrocarbons (PAHs) did not exceed the admissible values. All examined microbial groups were abundant in soil and waste. The highest microbial cell numbers were observed in warm summer and spring months. Although the site south of the landfill shows no trace of microbial contamination, pathogenic bacteria were found north of the landfill. This may suggest that there are other, more effective, transmission routes of bacteria than groundwater flow.

  2. Landfill taxes and Enhanced Waste Management: Combining valuable practices with respect to future waste streams.

    Science.gov (United States)

    Hoogmartens, Rob; Eyckmans, Johan; Van Passel, Steven

    2016-09-01

    Both landfill taxes and Enhanced Waste Management (EWM) practices can mitigate the scarcity issue of landfill capacity by respectively reducing landfilled waste volumes and valorising future waste streams. However, high landfill taxes might erode incentives for EWM, even though EWM creates value by valorising waste. Concentrating on Flanders (Belgium), the paper applies dynamic optimisation modelling techniques to analyse how landfill taxation and EWM can reinforce each other and how taxation schemes can be adjusted in order to foster sustainable and welfare maximising ways of processing future waste streams. Based on the Flemish simulation results, insights are offered that are generally applicable in international waste and resource management policy. As shown, the optimal Flemish landfill tax that optimises welfare in the no EWM scenario is higher than the one in the EWM scenario (93 against €50/ton). This difference should create incentives for applying EWM and is driven by the positive external effects that are generated by EWM practices. In Flanders, as the current landfill tax is slightly lower than these optimal levels, the choice that can be made is to further increase taxation levels or show complete commitment to EWM. A first generally applicable insight that was found points to the fact that it is not necessarily the case that the higher the landfill tax, the more effective waste management improvements can be realised. Other insights are about providing sufficient incentives for applying EMW practices and formulating appropriate pleas in support of technological development. By these insights, this paper should provide relevant information that can assist in triggering the transition towards a resource-efficient, circular economy in Europe.

  3. The new Waste Law: Challenging opportunity for future landfill operation in Indonesia.

    Science.gov (United States)

    Meidiana, Christia; Gamse, Thomas

    2011-01-01

    The Waste Law No. 18/2008 Article 22 and 44 require the local governments to run environmentally sound landfill. Due to the widespread poor quality of waste management in Indonesia, this study aimed to identify the current situation by evaluating three selected landfills based on the ideal conditions of landfill practices, which are used to appraise the capability of local governments to adapt to the law. The results indicated that the local governments have problems of insufficient budget, inadequate equipment, uncollected waste and unplanned future landfill locations. All of the selected landfills were partially controlled landfills with open dumping practices predominating. In such inferior conditions the implementation of sanitary landfill is not necessarily appropriate. The controlled landfill is a more appropriate solution as it offers lower investment and operational costs, makes the selection of a new landfill site unnecessary and can operate with a minimum standard of infrastructure and equipment. The sustainability of future landfill capacity can be maintained by utilizing the old landfill as a profit-oriented landfill by implementing a landfill gas management or a clean development mechanism project. A collection fee system using the pay-as-you-throw principle could increase the waste income thereby financing municipal solid waste management.

  4. Environmental assessment of solid waste landfilling technologies by means of LCA-modeling.

    Science.gov (United States)

    Manfredi, Simone; Christensen, Thomas H

    2009-01-01

    By using life cycle assessment (LCA) modeling, this paper compares the environmental performance of six landfilling technologies (open dump, conventional landfill with flares, conventional landfill with energy recovery, standard bioreactor landfill, flushing bioreactor landfill and semi-aerobic landfill) and assesses the influence of the active operations practiced on these performances. The environmental assessments have been performed by means of the LCA-based tool EASEWASTE, whereby the functional unit utilized for the LCA is "landfilling of 1ton of wet household waste in a 10m deep landfill for 100 years". The assessment criteria include standard categories (global warming, nutrient enrichment, ozone depletion, photo-chemical ozone formation and acidification), toxicity-related categories (human toxicity and ecotoxicity) and impact on spoiled groundwater resources. Results demonstrate that it is crucially important to ensure the highest collection efficiency of landfill gas and leachate since a poor capture compromises the overall environmental performance. Once gas and leachate are collected and treated, the potential impacts in the standard environmental categories and on spoiled groundwater resources significantly decrease, although at the same time specific emissions from gas treatment lead to increased impact potentials in the toxicity-related categories. Gas utilization for energy recovery leads to saved emissions and avoided impact potentials in several environmental categories. Measures should be taken to prevent leachate infiltration to groundwater and it is essential to collect and treat the generated leachate. The bioreactor technologies recirculate the collected leachate to enhance the waste degradation process. This allows the gas collection period to be reduced from 40 to 15 years, although it does not lead to noticeable environmental benefits when considering a 100 years LCA-perspective. In order to more comprehensively understand the influence

  5. Fate of chemical warfare agents and toxic industrial chemicals in landfills.

    Science.gov (United States)

    Bartelt-Hunt, Shannon L; Barlaz, Morton A; Knappe, Detlef R U; Kjeldsen, Peter

    2006-07-01

    One component of preparedness for a chemical attack is planning for the disposal of contaminated debris. To assess the feasibility of contaminated debris disposal in municipal solid waste (MSW) landfills, the fate of selected chemical warfare agents (CWAs) and toxic industrial chemicals (TICs) in MSW landfills was predicted with a mathematical model. Five blister agents [sulfur mustard (HD), nitrogen mustard (HN-2), lewisite (L), ethyldichloroarsine (ED), and phosgene oxime (CX)], eight nerve agents [tabun (GA), sarin (GB), soman (GD), GE, GF, VX, VG, and VM], one riot-control agent [CS], and two TICs [furan and carbon disulfide] were studied. The effects of both infiltration (climate) and contaminant biodegradability on fate predictions were assessed. Model results showed that hydrolysis and gas-phase advection were the principal fate pathways for CWAs and TICs, respectively. Apart from CX and the TICs, none of the investigated compounds was predicted to persist in a landfill for more than 5 years. Climate had little impact on CWA/TIC fate, and biodegradability was only important for compounds with long hydrolysis half-lives. Monte Carlo simulations were performed to assess the influence of uncertainty in model input parameters on CWA/TIC fate predictions. Correlation analyses showed that uncertainty in hydrolysis rate constants was the primary contributor to variance of CWA fate predictions, while uncertainty in the Henry's Law constant and landfill gas-production rate accounted for most of the variance of TIC fate predictions. CWA hydrolysates were more persistent than the parent CWAs, but limited information is available on abiotic or biotic transformation rates for these chemicals.

  6. 40 CFR 62.14353 - Standards for municipal solid waste landfill emissions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Standards for municipal solid waste... POLLUTANTS Federal Plan Requirements for Municipal Solid Waste Landfills That Commenced Construction Prior to... municipal solid waste landfill emissions. (a) The owner or operator of a designated facility having a...

  7. 76 FR 303 - Alaska: Adequacy of Alaska's Municipal Solid Waste Landfill Permit Program

    Science.gov (United States)

    2011-01-04

    ... AGENCY 40 CFR Parts 239 and 258 Alaska: Adequacy of Alaska's Municipal Solid Waste Landfill Permit... proposes to approve Alaska's modification of its approved Municipal Solid Waste Landfill (MSWLF) permit... Domenic Calabro, Office of Air, Waste, and Toxics, U.S. EPA, Region 10, 1200 Sixth Avenue, Suite...

  8. 40 CFR 258.16 - Closure of existing municipal solid waste landfill units.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Closure of existing municipal solid waste landfill units. 258.16 Section 258.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Location Restrictions § 258.16...

  9. Landfills: Engineering Design for Waste Control

    Science.gov (United States)

    Deck, Anita; Grubbs, Michael E.

    2016-01-01

    It is becoming increasingly important to consider the waste humans produce and options for reducing the impact it has on the environment. Allowing students the opportunities to research potential solutions and present their ideas results in an educated citizenry that considers consequences of technological advances. Throughout the course of a…

  10. Waste management in the Irkutsk Region, Siberia, Russia: Environmental assessment of current practice focusing on landfilling

    DEFF Research Database (Denmark)

    Starostina, Vlada; Damgaard, Anders; Rechberger, Helmut

    2014-01-01

    The municipal waste management system of the region of Irkutsk is described and a life cycle assessment (LCA) performed to assess the environmental performance of the system. Annually about 500 000 tons of waste are managed. The waste originates from three sources: household waste (27%), commercial...... years, the LCA modelling showed that introduction of a new and modern landfill with gas and leachate collection could improve the performance of the waste management system significantly. Collection of landfill gas and utilization for 30 years for electricity production (gas turbine) would reduce...... waste (23%) and office & institutional waste (44%). Other waste of unknown composition constitutes 6%. Only 3% of the waste is recycled; 97% of the municipal waste is disposed of at the old Alexandrovsky landfill. The environmental impact from the current system is dominated by the landfill, which has...

  11. IJER@2014 Page 57 Disposal Criteria of Bhanpur Solid Waste Landfill Site: Investigation and Suggestions

    Directory of Open Access Journals (Sweden)

    Tapas Dasgpta

    2014-03-01

    Full Text Available The solid waste management and design assist waste management officials in developing and encouraging environmentally sound methods for the disposal of "nonhazardous" solid waste. Promulgated under the authority of municipal act, the Municipal Solid Waste Landfill (MSWLF regulation act establish a framework for planning and implementing municipal solid waste landfill programs at the state and local levels. This framework sets minimum standards for protecting human health and the environment, while allowing states to develop more flexible MSWLF criteria. Intension to mitigate or expeditiously remediate potential adverse environmental impacts resulting from municipal landfills. However, other regulations existed prior to the revised MSWLF standards discussed in this module. The promulgation Criteria for Classification of Solid Waste Disposal Facilities and Practices. The established regulatory standards to satisfy the minimum national performance criteria for sanitary landfills governs only those solid waste disposal facilities and practices that do not meet the definition of a MSWLF. Such facilities include waste piles, industrial nonhazardous waste landfills, surface impoundments, and land application units. Environmental Protect Authority (EPA modified address the fact that these non-municipal non-hazardous wastes landfills may receive Conditionally Exempt Small Quantity Generator (CESQG hazardous waste, further clarify that construction and demolition landfills may receive residential lead-based paint waste as Solid Waste Disposal Facilities without for MSWLFs as long as all conditions are met.

  12. Construction and operation of an industrial solid waste landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    The US Department of Energy (DOE), Office of Waste Management, proposes to construct and operate a solid waste landfill within the boundary of the Portsmouth Gaseous Diffusion Plant (PORTS), Piketon, Ohio. The purpose of the proposed action is to provide PORTS with additional landfill capacity for non-hazardous and asbestos wastes. The proposed action is needed to support continued operation of PORTS, which generates non-hazardous wastes on a daily basis and asbestos wastes intermittently. Three alternatives are evaluated in this environmental assessment (EA): the proposed action (construction and operation of the X-737 landfill), no-action, and offsite shipment of industrial solid wastes for disposal.

  13. Groundwater Monitoring Plan for the Solid Waste Landfill

    Energy Technology Data Exchange (ETDEWEB)

    JW Lindberg; CJ Chou

    2000-12-14

    The Solid Waste Landfill (SWL) is regulated by the Washington State Department of Ecology under WAC 173-304. Between 1973 and 1976, the landfill received primarily paper waste and construction debris, but it also received asbestos, sewage, and catch tank liquid waste. Groundwater monitoring results indicate the SWL has contaminated groundwater with volatile organic compounds and possibly metals at levels that exceed regulatory limits. DynCorp, Tri-Cities, Inc. operates the facility under an interim closure plan (final closure plan will be released shortly). Pacific Northwest National Laboratory (PNNL) monitors groundwater at the site. This monitoring plan includes well and constituent lists, and summarizes sampling, analytical, and quality control requirements. Changes from the previous monitoring plan include elimination of two radionuclides from the analyte list and some minor changes in the statistical analysis. Existing wells in the current monitoring network only monitor the uppermost portion of the upper-most aquifer. Therefore, two new downgradient wells and one existing upgradient well are proposed to determine whether groundwater waste constituents have reached the lower portion of the uppermost aquifer. The proposed well network includes three upgradient wells and ten downgradient wells. The wells will be sampled quarterly for 14 analytes required by WAC 173-304-490 plus volatile organic compounds and filtered arsenic as site-specific analytes.

  14. Geophysical study in waste landfill localized above fractured rocks

    Directory of Open Access Journals (Sweden)

    Ariveltom Cosme da Silva

    2011-08-01

    Full Text Available Geophysical survey is an important method for investigation of contaminated areas used in the characterization of contrasting physical properties in the presence of pollutants. This work applied the geophysical methods of Electrical Resistivity and Self Potential in waste landfill, located in Caçapava do Sul city, RS. The landfill is located over fractured metamorphic rocks. Eight lines of electrical profiling with 288 measures of self potential were done. In addition, 83 measurements of direction and dip of fractures were taken. The application of spontaneous potential method permitted to detect the direction of groundwater flow. The electrical resistivity measurements allowed the identification of low-intensity anomalies associated with the presence of leachate. There is a relationship between anomalous zones and the directions of fractures.

  15. Contribution of individual waste fractions to the environmental impacts from landfilling of municipal solid waste.

    Science.gov (United States)

    Manfredi, Simone; Tonini, Davide; Christensen, Thomas H

    2010-03-01

    A number of LCA-based studies have reported on the environmental performance of landfilling of mixed waste, but little is known about the relative contributions of individual waste fractions to the overall impact potentials estimated for the mixed waste. In this paper, an empirical model has been used to estimate the emissions to the environment from landfilling of individual waste fractions. By means of the LCA-model EASEWASTE, the emissions estimated have been used to quantify how much of the overall impact potential for each impact category is to be attributed to the individual waste fractions. Impact potentials are estimated for 1 tonne of mixed waste disposed off in a conventional landfill with bottom liner, leachate collection and treatment and gas collection and utilization for electricity generation. All the environmental aspects are accounted for 100 years after disposal and several impact categories have been considered, including standard categories, toxicity-related categories and groundwater contamination. Amongst the standard and toxicity-related categories, the highest potential impact is estimated for human toxicity via soil (HTs; 12 mPE/tonne). This is mostly caused by leaching of heavy metals from ashes (e.g. residues from roads cleaning and vacuum cleaning bags), batteries, paper and metals. On the other hand, substantial net environmental savings are estimated for the categories Global Warming (GW; -31 mPE/tonne) and Eco-Toxicity in water chronic (ETwc; -53 mPE/tonne). These savings are mostly determined by the waste fractions characterized by a high content of biogenic carbon (paper, organics, other combustible waste). These savings are due to emissions from energy generation avoided by landfill gas utilization, and by the storage of biogenic carbon in the landfill due to incomplete waste degradation.

  16. Physic-chemical evaluation of leach and water from the Borba Gato streamlet within the catchment area of the urban waste landfill of Maringá, Paraná State, Brazil - doi: 10.4025/actascitechnol.v34i1.6771

    Directory of Open Access Journals (Sweden)

    Marta Eliane Echeverria Borges

    2011-11-01

    Full Text Available The physic-chemical characteristics of leach deposited in the landfill waste pond and of water from the Borba Gato streamlet are evaluated. Twenty-six physic-chemical parameters were analyzed from three collection sites, or rather, two in the streamlet, one upstream (P-01 and one downstream (P-02 of the landfill waste pond, and one in the leach deposit pond (P-03. The streamlet area under analysis was impacted due to being in an agricultural area and for its urban waste deposits. Parameter concentrations of aluminum, iron and mercury were reported above the quality standard of freshwater, according to Conama 357/2005 resolution (class 2. Further, throughout the rainy period, the ammoniac nitrogen content was above the resolution quality standard for fresh water. Moreover, landfill leach was above standards of effluent discharge established by Conama 357/2005. An efficient treatment for the effluent generated in Maringá is required since there is evidence of leach pollution of the Borba Gato streamlet.

  17. Utilization of Agricultural Wastes in Stabilization of Landfill Soil

    Directory of Open Access Journals (Sweden)

    Nidzam Rahmat Mohamad

    2014-01-01

    Full Text Available Palm Oil Fuel Ash (POFA and Rice Husk Ash (RHA are local agricultural waste material from Palm Oil Industry and from Paddy Industry in Malaysia. Currently, the disposal of these ashes from a burning process is a problem to both industries, and hence leads to environmental pollution. The main aim of this research was to investigate the potential of utilizing POFA and RHA as sustainable stabilizer material as partial replacement of traditional one which is lime and Portland Cement (PC. Laboratory investigations were carried out to establish the potential utilization of Malaysian Agricultural wastes POFA and RHA in stabilizing Teluk Kapas Landfill soil. Landfill soil on its own and combination with laterite clay soil were stabilized using POFA or RHA either on its own or in combination with Lime or Portland Cement (PC. The traditional stabilizers of lime or Portland Cement (PC were used as controls. Compacted cylinder test specimens were made at typical stabilizer contents and moist cured for up to 60 days prior to testing for compressive and water absorption tests. The results obtained showed that landfill soil combined with laterite clay (50:50 stabilized with 20% RHA:PC (50:50and POFA: PC (50:50 recorded the highest values of compressive strength compared to the other compositions of stabilizers and soils. However, when the amount of POFA and RHA increased in the system the compressive strength values of the samples tends to increase. These results suggest technological, economic as well as environmental advantages of using POFA and RHA and similar industrial by-products to achieve sustainable infrastructure development with near zero industrial waste.

  18. DETERMINATIONS OF THE ENVIRONMENTAL TOXICITY CHARACTERISTICS OF HAZARDOUS INDUSTRIAL WASTE FROM LANDFILL LEACHATE (CASE STUDY

    Directory of Open Access Journals (Sweden)

    Daniela Dal Molin

    2010-04-01

    Full Text Available The aim of this study was to evaluate the environmental toxicity of hazardous industrial waste from landfill leachate of the one industrial solid waste center from the Rio Grande do Sul state, Brazil. The physical and chemical characteristics, as well as the ecotoxicity with Daphnia magna and toxicity and mutagenicity with Allium cepa were determined. The results of the row leachate sample indicated that the physical and chemical characteristics are compatible with the limit values imputed for treated wastewaters. Absence of acute ecotoxicity was also detected, however a significant (P<0.01 larger frequency of micronuclei was verified when compared with the results of the negative control, suggesting a genotóxico effect of this wast, although not significant alterations in the mitotic index and root growth was observed.

  19. Landfill gas generation and emission at danish waste disposal sites receiving waste with a low organic waste content

    DEFF Research Database (Denmark)

    Mou, Zishen; Scheutz, Charlotte; Kjeldsen, Peter

    2015-01-01

    two models are multi-phase models, which defines waste fractions into traditional MSW and low-organic waste categories, respectively. Both the LandGEM and the IPCC model estimated significantly larger methane (CH4) generation in comparison to the Afvalzorg model. The Afvalzorg model could better show...... the influence of not only the total disposed waste amount, but also various waste categories, and was found more suitable to estimate LFG generation from landfills receiving low-organic waste. Four major waste categories currently being disposed at Danish landfills (mixed bulky, shredder, dewatered sludge...... and street cleansing waste) and temporarily stored combustible waste were sampled and characterized in terms of TS, VS, TC, TOC, and biochemical methane potential (BMP). Decay rates (k values), were determined by conducting anaerobic degradation experiments and applying FOD equations to the experimental...

  20. Co-disposal of electronic waste with municipal solid waste in bioreactor landfills.

    Science.gov (United States)

    Visvanathan, C; Visvanthan, C; Yin, Nang Htay; Karthikeyan, Obuli P

    2010-12-01

    Three pilot scale lysimeters were adopted to evaluate the stability pattern and leaching potential of heavy metals from MSW landfills under the E-waste co-disposed condition. One lysimeter served as control and solely filled with MSW, whereas the other two lysimeters were provided with 10% and 25% of E-waste scraps (% by weight), respectively. The reactors were monitored over a period of 280 days at ambient settings with continuous leachate recirculation. Stabilization pattern of carbon appears to be more than 50% in all the three lysimeters with irrespective of their operating conditions. Iron and zinc concentrations were high in leachate during bioreactor landfill operation and correlating with the TCLP leachability test results. In contrast, Pb concentration was around waste was found to be amplified with the long term disposal or stabilization within landfills. The results showed that the TCLP test cannot be completely reliable tool for measuring long-term leachability of toxic substances under landfill condition; rather landfill lysimeter studies are necessary to get the real scenario.

  1. Landfilling of waste: accounting of greenhouse gases and global warming contributions.

    Science.gov (United States)

    Manfredi, Simone; Tonini, Davide; Christensen, Thomas H; Scharff, Heijo

    2009-11-01

    Accounting of greenhouse gas (GHG) emissions from waste landfilling is summarized with the focus on processes and technical data for a number of different landfilling technologies: open dump (which was included as the worst-case-scenario), conventional landfills with flares and with energy recovery, and landfills receiving low-organic-carbon waste. The results showed that direct emissions of GHG from the landfill systems (primarily dispersive release of methane) are the major contributions to the GHG accounting, up to about 1000 kg CO(2)-eq. tonne( -1) for the open dump, 300 kg CO(2)-eq. tonne( -1) for conventional landfilling of mixed waste and 70 kg CO(2)-eq. tonne(-1) for low-organic-carbon waste landfills. The load caused by indirect, upstream emissions from provision of energy and materials to the landfill was low, here estimated to be up to 16 kg CO(2)-eq. tonne(-1). On the other hand, utilization of landfill gas for electricity generation contributed to major savings, in most cases, corresponding to about half of the load caused by direct GHG emission from the landfill. However, this saving can vary significantly depending on what the generated electricity substitutes for. Significant amounts of biogenic carbon may still be stored within the landfill body after 100 years, which here is counted as a saved GHG emission. With respect to landfilling of mixed waste with energy recovery, the net, average GHG accounting ranged from about -70 to 30 kg CO(2)-eq. tonne(- 1), obtained by summing the direct and indirect (upstream and downstream) emissions and accounting for stored biogenic carbon as a saving. However, if binding of biogenic carbon was not accounted for, the overall GHG load would be in the range of 60 to 300 kg CO(2)-eq. tonne( -1). This paper clearly shows that electricity generation as well as accounting of stored biogenic carbon are crucial to the accounting of GHG of waste landfilling.

  2. 40 CFR 60.33c - Emission guidelines for municipal solid waste landfill emissions.

    Science.gov (United States)

    2010-07-01

    ... Guidelines and Compliance Times for Municipal Solid Waste Landfills § 60.33c Emission guidelines for municipal solid waste landfill emissions. (a) For approval, a State plan shall include control of MSW... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission guidelines for municipal...

  3. 76 FR 270 - Alaska: Adequacy of Alaska Municipal Solid Waste Landfill Permit Program

    Science.gov (United States)

    2011-01-04

    ... AGENCY 40 CFR Parts 239 and 258 Alaska: Adequacy of Alaska Municipal Solid Waste Landfill Permit Program... modification to Alaska's approved Municipal Solid Waste Landfill (MSWLF) permit program. The approved... 40 CFR 258.4. III. Statutory and Executive Order Reviews This action approves State solid...

  4. 78 FR 5288 - Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program

    Science.gov (United States)

    2013-01-25

    ... AGENCY 40 CFR Parts 239 and 258 Adequacy of Massachusetts Municipal Solid Waste Landfill Permit Program... modification to Massachusetts's approved municipal solid waste landfill (MSWLF) program. The approved... INFORMATION: A. Background On March 22, 2004, EPA issued a final rule amending the municipal solid...

  5. Application of tire chips to reduce the temperature of secondary geomembranes in municipal solid waste landfills.

    Science.gov (United States)

    Hoor, Azadeh; Rowe, R Kerry

    2012-05-01

    Heat generated by the biodegradation of waste and other chemical processes in a landfill can potentially affect the long-term performance of landfill liner system, in particular that of a high-density polyethylene geomembrane. In a double liner system, the difference in leachate exposure and temperature might improve the long-term performance of the secondary geomembrane compared to that of the primary geomembrane. However, in some cases, the temperature is likely to be high enough to substantially reduce the service-life of the secondary geomembrane. This study explores the possible effectiveness of using tire chips as thermal insulation between primary and secondary liners to reduce the temperature of secondary geomembranes as compared to traditional soil materials. Heat and contaminant migration analyses are performed for cases with no insulation and for cases in which a layer of soil or tire chips has been used as thermal insulation between the primary and secondary liners. The effect of insulation on prolonging the service-life of a secondary geomembrane and, consequently, on contaminant transport through a liner system is examined for the case of a volatile organic compound (dichloromethane) found in landfill leachate. The study suggests that the use of tire chips warrants consideration, however there are other practical issues that require consideration in the detailed design and construction of landfill liners. Issues such as finite service-life, low working temperature, excessive settlement, ability to generate internal heat, leaching of tire chips and limitations in performing electrical resistivity leak detection tests are identified.

  6. Solid waste management in Croatia in response to the European Landfill Directive.

    Science.gov (United States)

    Stanic-Maruna, Ira; Fellner, Johann

    2012-08-01

    The European Landfill Directive 99/31/EC represents the most influential piece of waste legislation on the management of municipal solid waste. In addition to technical standards regarding the design and location of landfills, it calls for a decrease in the amount of biodegradable waste landfilled. In order to meet the reduction targets set in the Landfill Directive, national solid waste strategies need to be changed. This article outlines the impact of the Landfill Directive on the Croatian waste management strategy and discusses the key challenges of its implementation. In addition, three scenarios of future waste management (mechanical biological pre-treatment, waste-to-energy and landfilling) have been investigated and evaluated regarding environmental impacts and affordability. The results of the analysis show that Croatia has transposed the said Directive into its own legislation in an exemplary way. The developed national waste management strategy foresees the set up of a separate collection of recyclables, waste pre-treatment of MSW, as well as the upgrading of existing disposal sites to sanitary landfills. However, the practical progress of carrying out provisions implemented on paper is lagging behind. Concerning the investigated scenarios the results of the evaluation indicate that mechanical biological pre-treatment in conjunction with separate collection of recyclables appears to be the most feasible option (in terms of economic and ecologic parameters). This result is in line with the proposed national waste management strategy.

  7. Evaluation Of Landfill Gas Decay Constant For Municipal Solid Waste Landfills Operated As Bioreactors

    Science.gov (United States)

    Prediction of the rate of gas production from bioreactor landfills is important to optimize energy recovery and to estimate greenhouse gas emissions. Landfill gas (LFG) composition and flow rate were monitored for four years for a conventional and two bioreactor landfill landfil...

  8. Chemical behavior of phthalates under abiotic conditions in landfills.

    Science.gov (United States)

    Huang, Jingyu; Nkrumah, Philip N; Li, Yi; Appiah-Sefah, Gloria

    2013-01-01

    The phthalates comprise a family of phthalic acid esters that are used primarily as plasticizers in polymeric materials to impart flexibility during the manufacturing process and to the end product. It is estimated that the annual worldwide production of phthalate esters exceeds five million tons. Plasticizers are one of the most prominent classes of chemicals, but unfortunately, they possess endocrine-disrupting chemical properties. As endocrine-disrupting chemicals, plasticizers have produced adverse developmental and reproductive effects in mammalian animal models.Phthalates are easily transported into the environment during manufacture, disposal,and leaching from plastic materials, because they are not covalently bound to the plastics of which they are a component. Because of their fugitive nature and widespread use, the phthalates are commonly detected in air, water, sediment/soil, and biota, including human tissue. Large amounts of phthalic acid esters are often leached from the plastics that are dumped at municipal landfills.Phthalate esters undergo chemical changes when released into the environment.The primary processes by which they are transformed include hydrolysis, photolysis,and biodegradation. It is noteworthy that all of these degradation processes are greatly influenced by the local physical and chemical conditions. Hence, in the present review, we have sought to ascertain from the literature how the phthalate esters undergo transformation when they are released into lower landfill layers.Within the upper landfill layers, biodegradation prevails as the major degradation mechanism by which the phthalates are dissipated. Generally, biodegradation pathways for the phthalates consist of primary biodegradation from phthalate diesters to phthalate monoesters, then to phthalic acid, and ultimately biodegradation of phthalic acid to form C02 and/or CH4• We have noted that the phthalate esters are also degraded through abiotic means,which proceeds via

  9. Risk-Based Prioritization Method for the Classification of Groundwater Pollution from Hazardous Waste Landfills

    Science.gov (United States)

    Yang, Yu; Jiang, Yong-Hai; lian, Xin-Ying; Xi, Bei-Dou; Ma, Zhi-fei; Xu, Xiang-Jian; An, Da

    2016-12-01

    Hazardous waste landfill sites are a significant source of groundwater pollution. To ensure that these landfills with a significantly high risk of groundwater contamination are properly managed, a risk-based ranking method related to groundwater contamination is needed. In this research, a risk-based prioritization method for the classification of groundwater pollution from hazardous waste landfills was established. The method encompasses five phases, including risk pre-screening, indicator selection, characterization, classification and, lastly, validation. In the risk ranking index system employed here, 14 indicators involving hazardous waste landfills and migration in the vadose zone as well as aquifer were selected. The boundary of each indicator was determined by K-means cluster analysis and the weight of each indicator was calculated by principal component analysis. These methods were applied to 37 hazardous waste landfills in China. The result showed that the risk for groundwater contamination from hazardous waste landfills could be ranked into three classes from low to high risk. In all, 62.2 % of the hazardous waste landfill sites were classified in the low and medium risk classes. The process simulation method and standardized anomalies were used to validate the result of risk ranking; the results were consistent with the simulated results related to the characteristics of contamination. The risk ranking method was feasible, valid and can provide reference data related to risk management for groundwater contamination at hazardous waste landfill sites.

  10. Estimation of Methane Emissions from Municipal Solid Waste Landfills in China Based on Point Emission Sources

    Institute of Scientific and Technical Information of China (English)

    CAI Bo-Feng; LIU Jian-Guo; GAO Qing-Xian; NIE Xiao-Qin; CAO Dong; LIU Lan-Cui; ZHOU Ying; ZHANG Zhan-Sheng

    2014-01-01

    The methane (CH4) emissions from municipal solid waste (MSW) landfills in China in 2007 were estimated based on database of the three-dimensional emission factors matrix and point sources, by an IPCC recommended FOD (first-order decay) model. The location, capacity and age of landfills constitute the three dimensions of the emission factors matrix, which were obtained by laboratory analysis and in situ investigation. Key parameters such as waste composition, degradable organic carbon ratio, CH4 correction factor, oxidation factor and recovery rate, were carefully analyzed in terms of these three dimensions. The point sources database consists of 2,107 MSW landfills in cities and towns of China in 2007. The results show that the CH4 emissions from MSW landfills were 1.186 Mt in 2007. Compared with the CH4 emissions of 2.20 Mt in 2005, the significant discrepancy mainly comes from statistical data of landfills, e.g., number of landfills and amount of waste disposed in landfills. CH4 emissions were lower than 700 t for most of the landfills, whereas there were 279 landfills with emissions larger than 1,000 t, and only 10 landfills with emissions larger than 10,000 t. Jiangsu province ranks the largest emitter with 98,700 t while Tibet is the smallest emitter with 2,100 t. In general, the emissions from eastern provinces, such as Jiangsu, Guangdong and Zhejiang, were larger than those from western provinces, such as Ningxia, Tibet and Qinghai.

  11. Assessment of two thermally treated drill mud wastes for landfill containment applications.

    Science.gov (United States)

    Carignan, Marie-Pierre; Lake, Craig B; Menzies, Todd

    2007-10-01

    Offshore oil and gas drilling operations generate significant amounts of drill mud waste, some of which is transported onshore for subsequent thermal treatment (i.e. via thermal remediation). This treatment process results in a mineral waste by-product (referred to as thermally treated drill mud waste; TTDMW). Bentonites are originally present in many of the drill mud products and it is hypothesized that TTDMW can be utilized in landfill containment applications (i.e. cover or base liner). The objective of this paper is to examine the feasibility of this application by performing various physical and chemical tests on two TTDMW samples. It is shown that the two TTDMW samples contained relatively small amounts of clay-sized minerals although hydraulic conductivity values are found to be less than 10(-8) m/s. Organic carbon contents of the samples were approximately 2%. Mineralogy characterization of the samples confirmed varying amounts of smectite, however, peak friction angles for a TTDMW sample was greater than 36 degrees. Chemical characterization of the TTDMW samples show potential leaching of barium and small amounts of other heavy metals. Discussion is provided in the paper on suggestions to assist in overcoming regulatory issues associated with utilization of TTDMW in landfill containment applications.

  12. Evaluation of the Oedometer Tests of Municipal Landfill Waste Material

    Directory of Open Access Journals (Sweden)

    Imre Emőke

    2014-07-01

    Full Text Available The aim of the ongoing research is (i to develop a new biodegradation landfill technique so that the landfill gas production could be controlled and the utilisation of the landfill gas could economically be optimized, (ii to plan the energy utilisation of the landfill including individual and combined solutions (solar, wind, geothermal energy, energy storage using methanol etc.. [1, 2, 3

  13. Indirect measurements of field-scale hydraulic conductivity of waste from two landfill sites.

    Science.gov (United States)

    Fleming, I R

    2011-12-01

    Management and prediction of the movement and distribution of fluids in large landfills is important for various reasons. Bioreactor landfill technology shows promise, but in arid or semi-arid regions, the natural content of landfilled waste may be low, thus requiring addition of significant volumes of water. In more humid locations, landfills can become saturated, flooding gas collection systems and causing sideslope leachate seeps or other undesirable occurrences. This paper compares results from two different approaches to monitoring water in waste. At the Brock West Landfill in eastern Canada, positive pore pressures were measured at various depths in saturated waste. The downward seepage flux through the waste is known, thus the vertical saturated hydraulic conductivity of the waste at this landfill was determined to be 3 × 10(-7)cm/s. By comparison, the Spadina Landfill in western Canada is predominantly unsaturated. The infiltration of moisture into the waste was measured using moisture sensors installed in boreholes which determined arrival time for moisture fronts resulting from major precipitation events as well as longer-term change in moisture content resulting from unsaturated drainage during winter when frozen ground prevented infiltration. The unsaturated hydraulic conductivity calculated from these data ranged from approximately 10(-6)cm/s for the slow winter drainage in the absence of significant recharge to 10(-2)cm/s or higher for shallow waste subject to high infiltration through apparent preferential pathways. These two very different approaches to field-scale measurements of vertical hydraulic conductivity provide insight into the nature of fluid movement in saturated and unsaturated waste masses. It is suggested that the principles of unsaturated seepage apply reasonably well for landfilled waste and that the hydraulic behavior of waste is profoundly influenced by the nature and size of voids and by the degree of saturation prevailing in the

  14. Contamination valuation of soil and groundwater source at anaerobic municipal solid waste landfill site.

    Science.gov (United States)

    Aziz, Shuokr Qarani; Maulood, Yousif Ismael

    2015-12-01

    The present work aimed to determine the risks that formed landfill leachate from anaerobic Erbil Landfill Site (ELS) poses on groundwater source and to observe the effects of disposed municipal solid waste (MSW) on soil properties. The study further aims to fill the gap in studies on the effects of disposed MSW and produced leachate on the groundwater characteristics and soil quality at ELS, Iraq. Soil, leachate, and groundwater samples were collected from ELS for use as samples in this study. Unpolluted groundwater samples were collected from an area outside of the landfill. Field and laboratory experiments for the soil samples were conducted. Chemical analyses for the soil samples such as organic matter, total salts, and SO4 (=) were also performed. Raw leachate and groundwater samples were analyzed using physical and chemical experiments. The yields for sorptivity, steady-state infiltration rate, and hydraulic conductivity of the soil samples were 0.0006 m/√s, 0.00004 m/s, and 2.17 × 10(-5) m/s, respectively. The soil at ELS was found to be light brown clayey gravel with sand and light brown gravely lean clay layers with low permeability. Unprocessed leachate analysis identified the leachate as stabilized. Findings showed that the soil and groundwater at the anaerobic ELS were contaminated.

  15. Analysis of a landfill gas to energy system at the municipal solid waste landfill in Gaziantep, Turkey.

    Science.gov (United States)

    Tercan, Safak Hengirmen; Cabalar, Ali Firat; Yaman, Gokhan

    2015-08-01

    This paper presents an analysis of the electricity generation from municipal solid waste (MSW), via landfill gas valorization technology, at the landfill of Gaziantep City, Turkey. Rapid increase in population, and industrial developments, throughout the world including Turkey results in larger amount of waste materials generated, increased need for energy, and adverse affects on the environment and human health. Turkey plans to produce 1/3 of its electricity demand using renewable energy sources by the year of 2023. It is recommended to use each year around 25 million tonnes of the MSW generated nationwide for a renewable energy supply. In this study, a concise summary of current status of electricity generation from a MSW landfill gas plant (via biogas harnessing) located in Gaziantep City was analyzed as a case study.

  16. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste

    Energy Technology Data Exchange (ETDEWEB)

    Danon-Schaffer, Monica N. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Tetra Tech, 800-555 West Hastings Street, Vancouver, Canada V6B 1M1 (Canada); Mahecha-Botero, Andrés, E-mail: andresm@chbe.ubc.ca [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Grace, John R. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Ikonomou, Michael [Institute of Ocean Sciences, P.O. Box 6000, 9860 West Saanich Road, Sidney, B.C., Canada V8L 4B2 (Canada)

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables. - Graphical abstract: Schematic of the various mass transfer (MT) and input/output steps for sub-systems in the landfill model. NeWS is defined as non-electronic waste solids, including sand and soil added as cover materials. Highlights: • A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs). • Landfill samples and laboratory results are used to estimate the model

  17. SEISMIC DISTRESS AND PROTECTION OF FLEXIBLE MEMBRANE LINERS OF SOLID WASTE LANDFILLS

    DEFF Research Database (Denmark)

    Zania, Varvara; Tsompanakis, Yiannis; Psarropoulos, Prodromos

    2011-01-01

    Seismic distress of solid waste landfills may result from any of the two consequences of a seismic event: (a) the transient ground deformation related to seismic wave propagation, (b) the permanent ground deformation caused by abrupt fault dislocation. Design provisions for solid waste landfills......-element analyses were performed, taking also into account the potential slip displacement development along the interfaces formulated on each side of the flexible membrane liner (FML). It is shown that base fault dislocation causes significant plastic strains at each one of the components of the waste landfill...

  18. Evaluation and modeling of biochemical methane potential (BMP) of landfilled solid waste: a pilot scale study

    DEFF Research Database (Denmark)

    Bilgili, M Sinan; Demir, Ahmet; Varank, Gamze

    2009-01-01

    The main goal of this study was to present a comparison of landfill performance with respect to solids decomposition. Biochemical methane potential (BMP) test was used to determine the initial and the remaining CH(4) potentials of solid wastes during 27 months of landfilling operation in two pilo...

  19. Application of Grey Situation Decision-Making Theory in Site Selection of a Waste Sanitary Landfill

    Institute of Scientific and Technical Information of China (English)

    CAO Li-wen; CHENG Yun-huan; ZHANG Jing; ZHOU Xiao-zhi; LIAN Cui-xia

    2006-01-01

    An application of an unequal-weighted multi-objective decision making method in site selection of a waste sanitary landfill is discussed. The eight factors, which affected possible options, were: size and capacity of the landfill, permeability of the stratum, the average difference in elevation between the groundwater level and the bottom of the landfill pit, quality and source of clay, the quality grade of the landfill site, the effect of landfill engineering on nearby residents, distance to the water supply and the water source as well as the cost of construction and waste transport. These are determined, given the conditions of the geological environment, the need for environmental protection and landfill site construction and transportation related to the design and operation of a sanitary landfill. The weights of the eight factors were further investigated based on the difference in their relevance. Combined with practical experience from Xuzhou city (Jiangsu province, China), the objectives, effects and weights of grey decision-making were determined and the process and outcome of the landfill site selection are stated in detail. The decision-making results have been proven to be acceptable and correct. As we show, unequal-weighted multi-objective grey situation decision-mak- ing is characterized by easy calculations and good maneuverability when used in landfill site selection. The number of factors (objectives) affecting the outcome and the quantitative method of qualitative indices can be adjusted on the basis of concrete conditions in landfill site selection. Therefore, unequal-weighted multi-objective grey situation decision making is a feasible method in selecting landfill sites which offers a reference method for landfill site selection elsewhere. It is a useful, rational and scientific exploration in the choice of a landfill site.

  20. Interim site characterization report and ground-water monitoring program for the Hanford site solid waste landfill

    Energy Technology Data Exchange (ETDEWEB)

    Fruland, R.M.; Hagan, R.A.; Cline, C.S.; Bates, D.J.; Evans, J.C.; Aaberg, R.L.

    1989-07-01

    Federal and state regulations governing the operation of landfills require utilization of ground-water monitoring systems to determine whether or not landfill operations impact ground water at the point of compliance (ground water beneath the perimeter of the facility). A detection-level ground-water monitoring system was designed, installed, and initiated at the Hanford Site Solid Waste Landfill (SWL). Chlorinated hydrocarbons were detected at the beginning of the ground-water monitoring program and continue to be detected more than 1 year later. The most probable source of the chlorinated hydrocarbons is washwater discharged to the SWL between 1985 and 1987. This is an interim report and includes data from the characterization work that was performed during well installation in 1987, such as field observations, sediment studies, and geophysical logging results, and data from analyses of ground-water samples collected in 1987 and 1988, such as field parameter measurements and chemical analyses. 38 refs., 27 figs., 8 tabs.

  1. Using MCDA and GIS for hazardous waste landfill siting considering land scarcity for waste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Feo, Giovanni De, E-mail: g.defeo@unisa.it [Department of Industrial Engineering, University of Salerno, via Giovanni Paolo II, 132, 84084 Fisciano, SA (Italy); Gisi, Sabino De [Italian National Agency for New Technologies, Energy and Sustainable Economic Development, ENEA, Water Resource Management Lab., via Martiri di Monte Sole 4, 40129 Bologna, BO (Italy)

    2014-11-15

    Highlights: • Wasting land for the siting of hazardous waste landfills must be avoided. • The siting procedure is based on a land use map of potentially suitable areas. • All the waste facilities of the management system are simultaneously considered. • A case study is developed considering two multi-criteria techniques. • An innovative criteria weighting tool (PSW) is used in combination with the AHP. - Abstract: The main aim of this study was to develop a procedure that minimizes the wasting of space for the siting of hazardous waste landfills as part of a solid waste management system. We wanted to tackle the shortage of land for waste disposal that is a serious and growing problem in most large urban regions. The procedure combines a multi-criteria decision analysis (MCDA) approach with a geographical information system (GIS). The GIS was utilised to obtain an initial screening in order to eliminate unsuitable areas, whereas the MCDA was developed to select the most suitable sites. The novelty of the proposed siting procedure is the introduction of a new screening phase before the macro-siting step aimed at producing a “land use map of potentially suitable areas” for the siting of solid waste facilities which simultaneously takes into consideration all plant types. The issue of obtaining sites evaluations of a specific facility was coupled with the issue of not wasting land appropriate to facilitate other types of waste management options. In the developed case study, the use of an innovative criteria weighting tool (the “Priority Scale”) in combination with the Analytic Hierarchy Process was useful to easier define the priorities of the evaluation criteria in comparison with other classic methods such as the Paired Comparison Technique in combination with the Simple Additive Weighting method.

  2. Estimation of the environmental risk posed by landfills using chemical, microbiological and ecotoxicological testing of leachates.

    Science.gov (United States)

    Matejczyk, Marek; Płaza, Grażyna A; Nałęcz-Jawecki, Grzegorz; Ulfig, Krzysztof; Markowska-Szczupak, Agata

    2011-02-01

    The leachates from 22 municipal solid waste (MSW) landfill sites in Southern Poland were characterized by evaluation of chemical, microbiological and ecotoxicological parameters. Chemical analyses were mainly focused on the identification of the priority hazardous substances according to Directive on Priority Substances, 2008/105/EC (a daughter directive of the WFD) in leachates. As showed, only five substances (Cd, Hg, hexachlorobutadiene, pentachlorobenzene and PAHs) were detected in the leachates. The compounds tested were absent or present at very low concentrations. Among them, only PAHs were found in all samples in the range from 0.057 to 77.2 μg L⁻¹. The leachates were contaminated with bacteria, including aerobic, psychrophilic and mesophilic bacteria, coliform and fecal coliforms, and spore-forming-bacteria, including Clostridium perfringens, and with filamentous fungi. From the analysis of specific microorganism groups (indicators of environmental pollution by pathogenic or opportunistic pathogenic organisms) it can be concluded that the landfill leachates showed sanitary and epidemiological hazard. In the ecotoxicological study, a battery of tests comprised of 5 bioassays, i.e. Microtox(®), Spirotox, Rotoxkit F™, Thamnotoxkit F™ and Daphtoxkit F™ magna was applied. The leachate samples were classified as toxic in 13.6%, highly toxic in 54.6% and very highly toxic in 31.8%. The Spirotox test was the most sensitive bioassay used. The percentage of class weight score was very high - above 60%; these samples could definitely be considered seriously hazardous and acutely toxic to the fauna and microflora. No correlations were found between the toxicity values and chemical parameters. The toxicity of leachate samples cannot be explained by low levels of the priority pollutants. It seems that other kinds of xenobiotics present in the samples at subacute levels gave the high aggregate toxic effect. The chemical, ecotoxicological and microbiological

  3. Application of landfill treatment approaches for stabilization of municipal solid waste.

    Science.gov (United States)

    Bolyard, Stephanie C; Reinhart, Debra R

    2016-09-01

    This research sought to compare the effectiveness of three landfill enhanced treatment approaches aimed at removing releasable carbon and nitrogen after anaerobic landfilling including flushing with clean water (FB 1), leachate recirculation with ex-situ treatment (FB 2), and leachate recirculation with ex-situ treatment and in-situ aeration (FB 3). After extensive treatment of the waste in the FB scenarios, the overall solids and biodegradable fraction were reduced relative to the mature anaerobically treated waste. In terms of the overall degradation, aeration did not provide any advantage over flushing and anaerobic treatment. Flushing was the most effective approach at removing biodegradable components (i.e. cellulose and hemicellulose). Leachate quality improved for all FBs but through different mechanisms. A significant reduction in ammonia-nitrogen occurred in FB 1 and 3 due to flushing and aeration, respectively. The reduction of chemical oxygen demand (COD) in FB 1 was primarily due to flushing. Conversely, the reduction in COD in FBs 2 and 3 was due to oxidation and precipitation during Fenton's Reagent treatment. A mass balance on carbon and nitrogen revealed that a significant fraction still remained in the waste despite the additional treatment provided. Carbon was primarily converted biologically to CH4 and CO2 in the FBs or removed during treatment using Fenton's Reagent. The nitrogen removal occurred through leaching or biological conversion. These results show that under extensive treatment the waste and leachate characteristics did meet published stability values. The minimum stability values achieved were through flushing although FB 2 and 3 were able to improve leachate quality and solid waste characteristics but not to the same extent as FB 1.

  4. Co-generation potentials of municipal solid waste landfills in Serbia

    Directory of Open Access Journals (Sweden)

    Bošković Goran B.

    2016-01-01

    Full Text Available Waste management in the Republic of Serbia is based on landfilling. As a result of such year-long practice, a huge number of municipal waste landfills has been created where landfill gas has been generated. Landfill gas, which is essentially methane (50-55% and carbon dioxide (40-45% (both GHGs, has a great environmental impact which can be reduced by using landfill gas in cogeneration plants to produce energy. The aim of this paper is to determine economic and environmental benefits from such energy production. For that purpose, the database of cogeneration potentials (CP of 51 landfills in the Republic of Serbia (RS was created. Amount of landfill gas generated at each municipal landfill was calculated by applying a first order decay equation which requires the data about solid waste production and composition and about some landfill characteristics. For all landfills, which have over 100,000 m3 each, a techno-economic analysis about building a CHP plant was conducted. The results have shown, that the total investment in 14 CHP plants with payback period of less than 7 years amounts € 11,721,288. The total nominal power of these plants is 7 MW of electrical power and 7.9 MW of thermal power, and an average payback period is about 61 months. In addition, using landfill biogas as energy source in proposed plants would reduce methane emission for 161,000 tons of CO2 equivalent per year. [Projekat Ministarstva nauke Republike Srbije, br. III 42013: Research of cogeneration potential of municipal and industrial energy power plant in Republic of Serbia and opportunities for rehabilitation of existing and construction of new cogeneration plants

  5. Stochastic modelling of landfill leachate and biogas production incorporating waste heterogeneity. Model formulation and uncertainty analysis.

    Science.gov (United States)

    Zacharof, A I; Butler, A P

    2004-01-01

    A mathematical model simulating the hydrological and biochemical processes occurring in landfilled waste is presented and demonstrated. The model combines biochemical and hydrological models into an integrated representation of the landfill environment. Waste decomposition is modelled using traditional biochemical waste decomposition pathways combined with a simplified methodology for representing the rate of decomposition. Water flow through the waste is represented using a statistical velocity model capable of representing the effects of waste heterogeneity on leachate flow through the waste. Given the limitations in data capture from landfill sites, significant emphasis is placed on improving parameter identification and reducing parameter requirements. A sensitivity analysis is performed, highlighting the model's response to changes in input variables. A model test run is also presented, demonstrating the model capabilities. A parameter perturbation model sensitivity analysis was also performed. This has been able to show that although the model is sensitive to certain key parameters, its overall intuitive response provides a good basis for making reasonable predictions of the future state of the landfill system. Finally, due to the high uncertainty associated with landfill data, a tool for handling input data uncertainty is incorporated in the model's structure. It is concluded that the model can be used as a reasonable tool for modelling landfill processes and that further work should be undertaken to assess the model's performance.

  6. Estimating methane emissions from landfills based on rainfall, ambient temperature, and waste composition: The CLEEN model.

    Science.gov (United States)

    Karanjekar, Richa V; Bhatt, Arpita; Altouqui, Said; Jangikhatoonabad, Neda; Durai, Vennila; Sattler, Melanie L; Hossain, M D Sahadat; Chen, Victoria

    2015-12-01

    Accurately estimating landfill methane emissions is important for quantifying a landfill's greenhouse gas emissions and power generation potential. Current models, including LandGEM and IPCC, often greatly simplify treatment of factors like rainfall and ambient temperature, which can substantially impact gas production. The newly developed Capturing Landfill Emissions for Energy Needs (CLEEN) model aims to improve landfill methane generation estimates, but still require inputs that are fairly easy to obtain: waste composition, annual rainfall, and ambient temperature. To develop the model, methane generation was measured from 27 laboratory scale landfill reactors, with varying waste compositions (ranging from 0% to 100%); average rainfall rates of 2, 6, and 12 mm/day; and temperatures of 20, 30, and 37°C, according to a statistical experimental design. Refuse components considered were the major biodegradable wastes, food, paper, yard/wood, and textile, as well as inert inorganic waste. Based on the data collected, a multiple linear regression equation (R(2)=0.75) was developed to predict first-order methane generation rate constant values k as functions of waste composition, annual rainfall, and temperature. Because, laboratory methane generation rates exceed field rates, a second scale-up regression equation for k was developed using actual gas-recovery data from 11 landfills in high-income countries with conventional operation. The Capturing Landfill Emissions for Energy Needs (CLEEN) model was developed by incorporating both regression equations into the first-order decay based model for estimating methane generation rates from landfills. CLEEN model values were compared to actual field data from 6 US landfills, and to estimates from LandGEM and IPCC. For 4 of the 6 cases, CLEEN model estimates were the closest to actual.

  7. Impact Of Aerobic Biostabilisation And Biodrying Process Of Municipal Solid Waste On Minimisation Of Waste Deposited In Landfills

    Directory of Open Access Journals (Sweden)

    Dziedzic Krzysztof

    2015-12-01

    Full Text Available The article discusses an innovative system used for aerobic biostabilisation and biological drying of solid municipal waste. A mechanical–biological process (MBT of municipal solid waste (MSW treatment were carried out and monitored in 5 bioreactors. A two-stage biological treatment process has been used in the investigation. In the first step an undersize fraction was subjected to the biological stabilisation for a period of 14 days as a result of which there was a decrease of loss on ignition, but not sufficient to fulfill the requirements of MBT technology. In the second stage of a biological treatment has been applied 7-days intensive bio-drying of MSW using sustained high temperatures in bioreactor. The article presents the results of the chemical composition analysis of the undersize fraction and waste after biological drying, and also the results of temperature changes, pH ratio, loss on ignition, moisture content, combustible and volatile matter content, heat of combustion and calorific value of wastes. The mass balance of the MBT of MSW with using the innovative aeration system showed that only 14.5% of waste need to be landfilled, 61.5% could be used for thermal treatment, and nearly 19% being lost in the process as CO2 and H2O.

  8. Metals and polybrominated diphenyl ethers leaching from electronic waste in simulated landfills

    Energy Technology Data Exchange (ETDEWEB)

    Kiddee, Peeranart [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Campus, Adelaide, 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Mawson Lakes Campus, Adelaide, 5095 (Australia); Naidu, Ravi, E-mail: ravi.naidu@crccare.com [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Campus, Adelaide, 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Mawson Lakes Campus, Adelaide, 5095 (Australia); Wong, Ming H. [Croucher Institute for Environmental Sciences, and Department of Biology, Hong Kong Baptist University, Kowloon Tong (China)

    2013-05-15

    Highlights: • Simulated landfill columns provided realistic results than lab based column study. • Column leachates showed significant seasonal effect on toxic substances. • Toxic substances in the landfill leachates pose environmental and health hazards. • A better management of e-waste is urgently needed. -- Abstract: Landfills established prior to the recognition of potential impacts from the leaching of heavy metals and toxic organic compounds often lack appropriate barriers and pose significant risks of contamination of groundwater. In this study, bioavailable metal(oids) and polybrominated diphenyl ethers (PBDEs) in leachates from landfill columns that contained intact or broken e-waste were studied under conditions that simulate landfills in terms of waste components and methods of disposal of e-wastes, and with realistic rainfall. Fourteen elements and PBDEs were analysed in leachates over a period of 21 months. The results demonstrate that the average concentrations of Al, Ba, Be, Cd, Co, Cr, Cu, Ni, Pb, Sb and V in leachates from the column that contained broken e-waste items were significantly higher than the column without e-waste. BDE-153 was the highest average PBDEs congener in all columns but the average of ∑PBDEs levels in columns that contained intact e-waste were (3.7 ng/l) and were not significantly higher than that in the leachates from the control column.

  9. Compositional and physicochemical changes in waste materials and biogas production across 7 landfill sites in UK.

    Science.gov (United States)

    Frank, R R; Cipullo, S; Garcia, J; Davies, S; Wagland, S T; Villa, R; Trois, C; Coulon, F

    2016-08-28

    The aim of this study was to evaluate the spatial distribution of the paper and fines across seven landfill sites (LFS) and assess the relationship between waste physicochemical properties and biogas production. Physicochemical analysis of the waste samples demonstrated that there were no clear trends in the spatial distribution of total solids (TS), moisture content (MC) and waste organic strength (VS) across all LFS. There was however noticeable difference between samples from the same landfill site. The effect of landfill age on waste physicochemical properties showed no clear relationship, thus, providing evidence that waste remains dormant and non-degraded for long periods of time. Landfill age was however directly correlated with the biochemical methane potential (BMP) of waste; with the highest BMP obtained from the most recent LFS. BMP was also correlated with depth as the average methane production decreased linearly with increasing depth. There was also a high degree of correlation between the Enzymatic Hydrolysis Test (EHT) and BMP test results, which motivates its potential use as an alternative to the BMP test method. Further to this, there were also positive correlations between MC and VS, VS and biogas volume and biogas volume and CH4 content. Outcomes of this work can be used to inform waste degradation and methane enhancement strategies for improving recovery of methane from landfills.

  10. Waste management and chemical inventories

    Energy Technology Data Exchange (ETDEWEB)

    Gleckler, B.P.

    1995-06-01

    This section of the 1994 Hanford Site Environmental Report summarizes the classification and handling of waste at the Hanford Site. Waste produced at the Hanford Site is classified as either radioactive, nonradioactive, or mixed waste. Radioactive wastes are further categorized as transuranic, high-level, and low-level. Mixed waste may contain both radioactive and hazardous nonradioactive substances. This section describes waste management practices and chemical inventories at the site.

  11. Heavy metal binding capacity (HMBC) of municipal solid waste landfill leachates.

    Science.gov (United States)

    Ward, Marnie L; Bitton, Gabriel; Townsend, Timothy

    2005-07-01

    This research describes the use of a toxicity assay for the identification of metal toxicity, bioavailability and heavy metal binding capacity (HMBC) of municipal solid waste (MSW) landfill leachates. MetPLATE, an assay specific for heavy metal toxicity, was used to determine the HMBC of MSW leachates collected from 14 sites in Florida, with a wide range of chemical and physical characteristics. The leachates displayed a low toxicity which was attributed to the site-specific parameters, including, high concentrations of both organic and inorganic ligands. The HMBC test was undertaken to measure the effect of these site-specific parameters on metal toxicity. The potential for MSW leachate to bind and, thus, detoxify heavy metals was investigated with copper, zinc, and mercury. The HMBC values obtained ranged from 3 to 115, 5 to 93 and 4 to 101 for HMBC-Cu+2, HMBC-Zn+2, and HMBC-Hg+2, respectively. Additionally, the high strength leachates displayed the highest binding capacities, although the landfills sampled represented a wide range of characteristics. For comparison, the HMBC values reported with local lake water, Lake Alice and Lake Beverly, and a wastewater treatment plant effluent were all below 3. A partial fractionation of MSW leachate samples from sites 1, 5 and 8, was conducted to further investigate the influence of selected site-specific physico-chemical parameters on metal binding. The fractionation revealed that the HMBC of the leachate samples was heavily influenced by the concentration of solids, organics and hardness.

  12. A review of groundwater contamination near municipal solid waste landfill sites in China.

    Science.gov (United States)

    Han, Zhiyong; Ma, Haining; Shi, Guozhong; He, Li; Wei, Luoyu; Shi, Qingqing

    2016-11-01

    Landfills are the most widely used method for municipal solid waste (MSW) disposal method in China. However, these facilities have caused serious groundwater contamination due to the leakage of leachate. This study, analyzed 32 scientific papers, a field survey and an environmental assessment report related to groundwater contamination caused by landfills in China. The groundwater quality in the vicinity of landfills was assessed as "very bad" by a comprehensive score (FI) of 7.85 by the Grading Method in China. Variety of pollutants consisting of 96 groundwater pollutants, 3 organic matter indicators, 2 visual pollutants and 6 aggregative pollutants had been detected in the various studies. Twenty-two kinds of pollutants were considered to be dominant. According to the Kruskal-Wallis test and the median test, groundwater contamination differed significantly between regions in China, but there were no significant differences between dry season and wet season measurements, except for some pollutants in a few landfill sites. Generally, the groundwater contamination appeared in the initial landfill stage after five years and peaked some years afterward. In this stage, the Nemerow Index (PI) of groundwater increased exponentially as landfill age increased at some sites, but afterwards decreased exponentially with increasing age at others. After 25years, the groundwater contamination was very low at selected landfills. The PI values of landfills decreased exponentially as the pollutant migration distance increased. Therefore, the groundwater contamination mainly appeared within 1000m of a landfill and most of serious groundwater contamination occurred within 200m. The results not only indicate that the groundwater contamination near MSW landfills should be a concern, but also are valuable to remediate the groundwater contamination near MSW landfills and to prevent the MSW landfill from secondary pollutions, especially for developing countries considering the similar

  13. Stable isotope signatures for characterising the biological stability of landfilled municipal solid waste.

    Science.gov (United States)

    Wimmer, Bernhard; Hrad, Marlies; Huber-Humer, Marion; Watzinger, Andrea; Wyhlidal, Stefan; Reichenauer, Thomas G

    2013-10-01

    Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of δ(13)C, δ(2)H and δ(18)O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration. We found significant differences in the δ(13)C-value of the dissolved inorganic carbon (δ(13)C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of δ(13)C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a δ(13)C-DIC of -20‰ to -25‰. The production of methane under anaerobic conditions caused an increase in δ(13)C-DIC up to values of +10‰ and higher depending on the actual reactivity of the MSW. During aeration of a landfill the aerobic degradation of the remaining organic matter caused a decrease to a δ(13)C-DIC of about -20‰. Therefore carbon isotope analysis in leachates and groundwater can be used for tracing the oxidation-reduction status of MSW landfills. Our results indicate that monitoring of stable isotopic signatures of landfill leachates over a longer time period (e.g. during in situ aeration) is a powerful and cost-effective tool for characterising the biodegradability and

  14. Comparison between controlled landfill reactor and conditioned landfill bioreactor

    Institute of Scientific and Technical Information of China (English)

    LUO Feng; CHEN Wan-zhi; SONG Fu-zhong; LI Xiao-peng; ZHANG Guo-qing

    2004-01-01

    Bioreactor landfills allow a more active landfill management that recognizes the biological, chemical and physical processes involved in a landfill environment. The results of laboratory-scale simulators of landfill reactors treating municipal solid wastes were studied, the effect of solid waste size, leachate recirculation, nutrient balance, pH value, moisture content and temperature on the rate of municipal solid waste(MSW) biodegradation were determined, and it indicated the optimum pH value, moisture content and temperature can used to decompose MSW. The results of waste biodegradation were compared with that of the simulators of the leachate-recirculated landfill and conservative sanitary landfill. In the control experiment the antitheses of a decreasing trend of the organic load, measured as biological oxygen demand and chemical oxygen demand, was shown, and heavy metals concentration was observed. An obvious enhancement of effective disposal from simulator of conservative sanitary landfill(CSL), to that of leachate-recirculated landfill(LRL) and to that of conditioned bioreactor landfill(CBL) would be noted, through displaying the compared results of solid waste settlement, heavy metal concentration in leachate, methane production rate, biogas composition, BOD and COD as well as their ratio.

  15. Using MCDA and GIS for hazardous waste landfill siting considering land scarcity for waste disposal.

    Science.gov (United States)

    De Feo, Giovanni; De Gisi, Sabino

    2014-11-01

    The main aim of this study was to develop a procedure that minimizes the wasting of space for the siting of hazardous waste landfills as part of a solid waste management system. We wanted to tackle the shortage of land for waste disposal that is a serious and growing problem in most large urban regions. The procedure combines a multi-criteria decision analysis (MCDA) approach with a geographical information system (GIS). The GIS was utilised to obtain an initial screening in order to eliminate unsuitable areas, whereas the MCDA was developed to select the most suitable sites. The novelty of the proposed siting procedure is the introduction of a new screening phase before the macro-siting step aimed at producing a "land use map of potentially suitable areas" for the siting of solid waste facilities which simultaneously takes into consideration all plant types. The issue of obtaining sites evaluations of a specific facility was coupled with the issue of not wasting land appropriate to facilitate other types of waste management options. In the developed case study, the use of an innovative criteria weighting tool (the "Priority Scale") in combination with the Analytic Hierarchy Process was useful to easier define the priorities of the evaluation criteria in comparison with other classic methods such as the Paired Comparison Technique in combination with the Simple Additive Weighting method.

  16. Mechanism of H2S removal during landfill stabilization in waste biocover soil, an alterative landfill cover.

    Science.gov (United States)

    He, Ruo; Xia, Fang-Fang; Bai, Yun; Wang, Jing; Shen, Dong-Sheng

    2012-05-30

    Hydrogen sulfide (H(2)S) is one of the primary contributors to odors at landfills. The mechanism of waste biocover soil (WBS) for H(2)S removal was investigated in simulated landfill systems with the contrast experiment of a landfill cover soil (LCS). The H(2)S removal efficiency was higher than 90% regardless of the WBS or LCS covers. The input of landfill gas (LFG) could stimulate the growth of aerobic heterotrophic bacteria, actinomycete, sulfate-reducing bacteria (SRB) and sulfur-oxidizing bacteria (SOB) in the WBS cover, while that caused a decrease of 1-2 orders of magnitude in the populations of actinomycete and fungi in the bottom layer of the LCS cover. As H(2)S inputted, the sulfide content in the WBS cover increased and reached the maximum on day 30. In the LCS cover, the highest soil sulfide content was exhibited in the bottom layer during the whole experiment. After exposure to LFG, the lower pH value and higher sulfate content were observed in the top layer of the WBS cover, while there was not a significant difference in different layers of the LCS cover. The results indicated a more rapid biotransformation between sulfide and sulfate occurred in the WBS cover compared to the LCS.

  17. Exergy analysis of biogas production from a municipal solid waste landfill

    DEFF Research Database (Denmark)

    Xydis, George; Nanaki, E.; Koroneos, C.

    2013-01-01

    In the energy area, intensive efforts are being made over the last years to bridge the supply area with renewable energy sources and the demand side with energy conservation. Energy recovery from municipal solid waste landfills can play a contributing role in the solution of problems of both wast...

  18. Methylated mercury species in municipal waste landfill gas sampled in Florida, USA

    Science.gov (United States)

    Lindberg, S. E.; Wallschläger, D.; Prestbo, E. M.; Bloom, N. S.; Price, J.; Reinhart, D.

    Mercury-bearing material has been placed in municipal landfills from a wide array of sources including fluorescent lights, batteries, electrical switches, thermometers, and general waste. Despite its known volatility, persistence, and toxicity in the environment, the fate of mercury in landfills has not been widely studied. The nature of landfills designed to reduce waste through generation of methane by anaerobic bacteria suggests the possibility that these systems might also serve as bioreactors for the production of methylated mercury compounds. The toxicity of such species mandates the need to determine if they are emitted in municipal landfill gas (LFG). In a previous study, we had measured levels of total gaseous mercury (TGM) in LFG in the μg/m 3 range in two Florida landfills, and elevated levels of monomethyl mercury (MMM) were identified in LFG condensate, suggesting the possible existence of gaseous organic Hg compounds in LFG. In the current study, we measured TGM, Hg 0, and methylated mercury compounds directly in LFG from another Florida landfill. Again, TGM was in the μg/m 3 range, MMM was found in condensate, and this time we positively identified dimethyl mercury (DMM) in the LGF in the ng/m 3 range. These results identify landfills as a possible anthropogenic source of DMM emissions to air, and may help explain the reports of MMM in continental rainfall.

  19. Bacterial community diversity in municipal waste landfill sites.

    Science.gov (United States)

    Song, Liyan; Wang, Yangqing; Tang, Wei; Lei, Yu

    2015-09-01

    Little is known about the bacterial diversity of landfills and how environmental factors impact the diversity. In this study, PCR-based 454 pyrosequencing was used to investigate the bacterial communities of ten landfill leachate samples from five landfill sites in China. A total of 137 K useable sequences from the V3-V6 regions of the 16S rRNA gene were retrieved from 205 K reads. These sequences revealed the presence of a large number of operational taxonomic units (OTUs) in the landfills (709-1599 OTUs per sample). The most predominant bacterial representatives in the landfills investigated, regardless of geographic area, included Gammaproteobacteria, Firmicutes, and Bacteroidetes. The phyla Fusobacteria and Tenericutes were also found for the first time to be predominant in the landfills. The phylum Fusobacteria predominated (51.5 and 48.8%) in two semi-arid landfills, and the phylum Tenericutes dominated (30.6%) at one humid, subtropical landfill. Further, a large number of Pseudomonas was detected in most samples, comprising the dominant group and accounting for 40.9 to 92.4% of the total abundance. Principal component analysis (PCA) and cluster analysis based on OTU abundance showed that the abundant taxa separated the bacterial community. Canonical correlation analysis (CCA) suggested that precipitation and landfilling age significantly impact on the bacterial community structure. The bacterial community function (e.g., cellulolytic bacteria, sulfate-reducing bacteria (SRB), sulfate-oxidizing bacteria, and xenobiotic organic compound (XOC)-degrading bacteria) was also diverse, but the pattern is unclear.

  20. Environmental assessment of low-organic waste landfill scenarios by means of life-cycle assessment modelling (EASEWASTE)

    DEFF Research Database (Denmark)

    Manfredi, Simone; Christensen, Thomas Højlund; Scharff, H.

    2010-01-01

    The environmental performance of two low-organic waste landfill scenarios ('low-organic-energy' and 'low-organic-flare') was developed and compared with two household waste landfill scenarios ('household-energy' and 'household-flare') by means of LCA-modelling. The LCA-modelling was made for 1...... tonne of wet waste landfilled and the environmental aspects were evaluated for a 100-year period after disposal. The data utilized in the LCA-calculations to model the first 10-20 years of landfilling of the two low-organic waste scenarios make extensive use of site-specific data from the Nauerna...... assessments show that the low-organic waste scenarios achieved better environmental performance than the household waste scenarios with regard to both ordinary and toxicity-related environmental impact categories. This indicates that the reduction of organic matter accepted at landfills (as prescribed...

  1. Impact of electronic waste disposal on lead concentrations in landfill leachate.

    Science.gov (United States)

    Spalvins, Erik; Dubey, Brajesh; Townsend, Timothy

    2008-10-01

    Lead is the element most likely to cause discarded electronic devices to be characterized as hazardous waste. To examine the fate of lead from discarded electronics in landfills, five columns were filled with synthetic municipal solid waste (MSW). A mix of electronic devices was added to three columns (6% by weight), while two columns served as controls. A sixth column contained waste excavated from an existing MSW landfill. Leachate quality was monitored for 440 days. In columns with the synthetic waste, leachate pH indicated that the simulated landfill environment was characteristic of the acid phase of waste decomposition; lead leachability should be greater in the acid phase of landfill degradation as compared to the methanogenic phase. Lead concentrations ranged from 7 to 66 microg/L in the columns containing electronic waste and ranged from electronic devices were greater than those in the controls, the difference was not found to be statistically significant when comparing the data sets over the entire monitoring period. Lead results from the excavated waste column suggest that lead concentrations in all columns will decrease as the pH increases toward more neutral methanogenic conditions.

  2. Geologic and hydrologic data for the municipal solid waste landfill facility, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso County, Texas

    Science.gov (United States)

    Abeyta, Cynthia G.; Frenzel, P.F.

    1999-01-01

    Geologic and hydrologic data for the Municipal Solid Waste Landfill Facility on the U.S. Army Air Defense Artillery Center and Fort Bliss in El Paso County, Texas, were collected by the U.S. Geological Survey in cooperation with the U.S. Department of the Army. The 106.03-acre landfill has been in operation since January 1974. The landfill contains household refuse, Post solid wastes, bulky items, grass and tree trimmings from family housing, refuse from litter cans, construction debris, classified waste (dry), dead animals, asbestos, and empty oil cans. The depth of the filled areas is about 30 feet and the cover, consisting of locally derived material, is 2 to 3 feet thick. Geologic and hydrologic data were collected at or adjacent to the landfill during (1) drilling of 10 30- to 31-foot boreholes that were completed with gas-monitoring probes, (2) drilling of a 59-foot borehole, (3) drilling of a 355-foot borehole that was completed as a ground-water monitoring well, and (4) in situ measurements made on the landfill cover. After completion, the gas- monitoring probes were monitored on a quarterly basis (1 year total) for gases generated by the landfill. Water samples were collected from the ground-water monitoring well for chemical analysis. Data collection is divided into two elements: geologic data and hydrologic data. Geologic data include lithologic descriptions of cores and cuttings, geophysical logs, soil- gas and ambient-air analyses, and chemical analyses of soil. Hydrologic data include physical properties, total organic carbon, and pH of soil and sediment samples; soil-water chloride and soil-moisture analyses; physical properties of the landfill cover; measurements of depth to ground water; and ground-water chemical analyses. Interpretation of data is not included in this report.

  3. Phytoremediation of Polychlorobiphenyls PCBs in Landfill E-Waste Leachate with Water Hyacinth E.Crassipes

    Directory of Open Access Journals (Sweden)

    E.A Omondi

    2015-05-01

    Full Text Available Abstract The presence of e-waste in a landfill can release persistent organic pollutants POPs including polychlorinated biphenyls PCBs into the environment. PCBs are a family of more than 200 chemical compounds congeners each of which consists of two benzene rings and one to ten chlorine atoms. This study investigated use of water hyacinth Eichhornia crassipes for phytoremediation of landfill leachate waste containing PCB. Landfill leachate was simulated in the laboratory by spiking water samples with PCB to obtain concentrations of 5 10 and 15 amp956gL which were in one to two orders of magnitude above the US Environmental Protection Agency EPA limit of 0.5 amp956gL or 0.5 ppb. Water hyacinth plants were grown in 2 L samples of the PCB spiked water for 15 days and evaluated for tolerance and bioaccumulation of PCB. Phytoremediation of PCB spiked water by the plants was evaluated by measuring the change in concentration of PCB. The plants tolerated PCB concentrations in the range of 5 to 15 amp956gL without depicting any serious adverse effect except for change in root color and an initial wilting of peripheral leaves. Water hyacinth reduced the concentration of PCBs in the leachate over 15 days from 15 to 0.42 amp956gL for the 15 amp956gL initial concentration sample and to below the GCMS detection limit of 0.142 amp956gL for the 10 and 5 ugL initial concentration samples. Bioaccumulation of PCB in the plant tissue was evaluated through solid phase extraction and testing of samples for PCB with GCMS. Bioaccumulation of PCBs at a concentration of 0.179 amp956gg was observed in the water hyacinth roots for the 15 amp956gL sample but none was detected for the lower initial PCB concentration and shoots. The study demonstrated potential of water hyacinth plants in phytoremediation of PCBs in e-waste leachate.

  4. Geophysical characterization in solid waste landfill for evaluation of geotechnical instability conditioners

    Directory of Open Access Journals (Sweden)

    Carolina Del Roveri

    2013-03-01

    Full Text Available The disposal of solid waste can create environmental problems, in addition to the potential risk of instability even in planned geotechnical works, such as provisions in stacks or high ends of the landfill, because they represent mere adjustments in civil engineering works. The Leme city, SP, generates about 35 t/day of municipal waste, that are deposited in a landfill located in the Barro Preto neighborhood. This work conducted a geophysical survey, based on geotechnical instability evidence in area, for analysis of the conditioners that cause on the sides leachate resurgence landfill and its relationship to mass movements and ravines installation in cover soil, with consequent waste exposure. The results indicate horizons of low resistivity connected with resurgence points generated by the organic matter decomposition contained in the waste. Such horizons result in leachate concentration in some places, which, in turn, may lead to loss of cohesion of the materials constituting the residues mass. The results are areas with mass flow by rotational movements, which, together with the surface flow of rainwater, evolves into ravines and exposed residues, preferably at the resurgence point. The leachate flow on the surface affects areas beyond the limits at landfill with direct impact on local agriculture and risk to pedestrians using the highway bordered by the landfill beyond the soil and the local aquifer.

  5. Identification of Cellulose Breaking Bacteria in Landfill Samples for Organic Waste Management

    Science.gov (United States)

    Chan, P. M.; Leung, F. C.

    2015-12-01

    According to the Hong Kong Environmental Protection Department, the citizens of Hong Kong disposes 13,500 tonnes of waste to the landfill everyday. Out of the 13,500 tonnes, 3600 tonnes consist of organic waste. Furthermore, due to the limited supply of land for landfills in Hong Kong, it is estimated that landfills will be full by about 2020. Currently, organic wastes at landfills undergo anaerobic respiration, where methane gas, one of the most harmful green house gases, will be released. The management of such waste is a pressing issue, as possible solutions must be presented in this crucial period of time. The Independent Schools Foundation Academy introduced their very own method to manage the waste produced by the students. With an approximate of 1500 students on campus, the school produces 27 metric tonnes of food waste each academic year. The installation of the rocket food composter provides an alternate method of disposable of organic waste the school produces, for the aerobic environment allows for different by-products to be produced, namely compost that can be used for organic farming by the primary school students and subsequently carbon dioxide, a less harmful greenhouse gas. This research is an extension on the current work, as another natural factor is considered. It evaluates the microorganism community present in leachate samples collected from the North East New Territories Landfill, for the bacteria in the area exhibits special characteristics in the process of decomposition. Through the sequencing and analysis of the genome of the bacteria, the identification of the bacteria might lead to a break through on the current issue. Some bacteria demonstrate the ability to degrade lignin cellulose, or assist in the production of methane gas in aerobic respirations. These characteristics can hopefully be utilized in the future in waste managements across the globe.

  6. INPP Landfill[Disposal of very low level radioactive waste at Ignalina NPP

    Energy Technology Data Exchange (ETDEWEB)

    Dahlberg, Jan; Bergstroem, Ulla

    2004-06-15

    The objective of this report is to propose the basic design for final disposal of Very Low Level Radioactive Waste (VLLW) produced at the Ignalina Nuclear Power Plant and at other small waste producers in Lithuania. Considering the safety for the environment, as well as the construction costs, it has been decided that the repository will be of a landfill type based on the same design principles as similar authorised facilities in other countries. It has also been decided that the location of the landfill shall be in the vicinity of the Ignalina Nuclear Power Plant (INPP)

  7. Quantification of regional leachate variance from municipal solid waste landfills in China.

    Science.gov (United States)

    Yang, Na; Damgaard, Anders; Kjeldsen, Peter; Shao, Li-Ming; He, Pin-Jing

    2015-12-01

    The quantity of leachate is crucial when assessing pollution emanating from municipal landfills. In most cases, existing leachate quantification measures only take into account one source - precipitation, which resulted in serious underestimation in China due to its waste properties: high moisture contents. To overcome this problem, a new estimation method was established considering two sources: (1) precipitation infiltrated throughout waste layers, which was simulated with the HELP model, (2) water squeezed out of the waste itself, which was theoretically calculated using actual data of Chinese waste. The two sources depended on climate conditions and waste characteristics, respectively, which both varied in different regions. In this study, 31 Chinese cities were investigated and classified into three geographic regions according to landfill leachate generation performance: northwestern China (China-NW) with semi-arid and temperate climate and waste moisture content of about 46.0%, northern China (China-N) with semi-humid and temperate climate and waste moisture content of about 58.2%, and southern China (China-S) with humid and sub-tropical/tropical climate and waste moisture content of about 58.2%. In China-NW, accumulated leachate amounts were very low and mainly the result of waste degradation, implying on-site spraying/irrigation or recirculation may be an economic approach to treatment. In China-N, water squeezed out of waste by compaction totaled 22-45% of overall leachate amounts in the first 40 years, so decreasing the initial moisture content of waste arriving at landfills could reduce leachate generation. In China-S, the leachate generated by infiltrated precipitation after HDPE geomembranes in top cover started failing, contributed more than 60% of the overall amounts over 100 years of landfilling. Therefore, the quality and placing of HDPE geomembranes in the top cover should be controlled strictly for the purpose of mitigation leachate generation.

  8. Stable isotope signatures for characterising the biological stability of landfilled municipal solid waste

    Energy Technology Data Exchange (ETDEWEB)

    Wimmer, Bernhard, E-mail: bernhard.wimmer@ait.ac.at [AIT Austrian Institute of Technology GmbH, Health and Environment Department, Environmental Resources and Technologies, Konrad-Lorenz-Strasse 24, 3430 Tulln (Austria); Hrad, Marlies; Huber-Humer, Marion [Institute of Waste Management, Department of Water-Atmosphere-Environment, University of Natural Resources and Life Sciences, Muthgasse 107, 1190 Vienna (Austria); Watzinger, Andrea; Wyhlidal, Stefan; Reichenauer, Thomas G. [AIT Austrian Institute of Technology GmbH, Health and Environment Department, Environmental Resources and Technologies, Konrad-Lorenz-Strasse 24, 3430 Tulln (Austria)

    2013-10-15

    Highlights: ► The isotopic signature of δ{sup 13}C-DIC of leachates is linked to the reactivity of MSW. ► Isotopic signatures of leachates depend on aerobic/anaerobic conditions in landfills. ► In situ aeration of landfills can be monitored by isotope analysis in leachate. ► The isotopic analysis of leachates can be used for assessing the stability of MSW. ► δ{sup 13}C-DIC of leachates helps to define the duration of landfill aftercare. - Abstract: Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of δ{sup 13}C, δ{sup 2}H and δ{sup 18}O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25 year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration. We found significant differences in the δ{sup 13}C-value of the dissolved inorganic carbon (δ{sup 13}C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of δ{sup 13}C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a δ{sup 13}C-DIC of −20‰ to −25‰. The production of methane under anaerobic conditions caused an increase in δ{sup 13}C-DIC up to values of +10‰ and higher depending on the actual reactivity of the MSW

  9. Adsorption and transport of methane in landfill cover soil amended with waste-wood biochars.

    Science.gov (United States)

    Sadasivam, Bala Yamini; Reddy, Krishna R

    2015-08-01

    The natural presence of methane oxidizing bacteria (MOB) in landfill soils can stimulate the bio-chemical oxidation of CH4 to CO2 and H2O under suitable environmental conditions. This mechanism can be enhanced by amending the landfill cover soil with organic materials such as biochars that are recalcitrant to biological degradation and are capable of adsorbing CH4 while facilitating the growth and activity of MOB within their porous structure. Several series of batch and small-scale column tests were conducted to quantify the CH4 sorption and transport properties of landfill cover soil amended with four types of waste hardwood biochars under different levels of amendment percentages (2, 5 and 10% by weight), exposed CH4 concentrations (0-1 kPa), moisture content (dry, 25% and 75% water holding capacity), and temperature (25, 35 and 45 °C). The linear forms of the pseudo second-order kinetic model and the Langmuir isotherm model were used to determine the kinetics and the maximum CH4 adsorption capacity of cover materials. The maximum CH4 sorption capacity of dry biochar-amended soils ranged from 1.03 × 10(-2) to 7.97 × 10(-2) mol kg(-1) and exhibited a ten-fold increase compared to that of soil with 1.9 × 10(-3) mol kg(-1). The isosteric heat of adsorption for soil was negative and ranged from -30 to -118 kJ/mol, while that of the biochar-amended soils was positive and ranged from 24 to 440 kJ/mol. The CH4 dispersion coefficients for biochar-amended soils obtained through predictive transport modeling indicated that amending the soil with biochar enhanced the methane transport rates by two orders of magnitude, thereby increasing their potential for enhanced exchange of gases within the cover system. Overall, the use of hardwood biochars as a cover soil amendment to reduce methane emissions from landfills appears to be a promising alternative to conventional soil covers.

  10. A framework for assessment and characterisation of municipal solid waste landfill leachate: an application to the Turbhe landfill, Navi Mumbai, India.

    Science.gov (United States)

    Mishra, Harshit; Rathod, Merwan; Karmakar, Subhankar; Kumar, Rakesh

    2016-06-01

    Rapid industrialisation, growing population and changing lifestyles are the root causes for the generation of huge amounts of solid waste in developing countries. In India, disposal of municipal solid waste (MSW) through open dumping is the most common waste disposal method. Unfortunately, leachate generation from landfill is high due to the prolonged and prominent monsoon season in India. As leachate generation rate is high in most of the tropical countries, long-term and extensive monitoring efforts are expected to evaluate actual environmental pollution potential due to leachate contamination. However, the leachate characterisation involves a comprehensive process, which has numerous shortcomings and uncertainties possibly due to the complex nature of landfilling process, heterogeneous waste characteristics, widely varying hydrologic conditions and selection of analytes. In order to develop a sustainable MSW management strategy for protecting the surface and ground water resources, particularly from MSW landfill leachate contamination, assessment and characterisation of leachate are necessary. Numerous studies have been conducted in the past to characterise leachate quality from various municipal landfills; unfortunately, none of these propose a framework or protocol. The present study proposes a generic framework for municipal landfill leachate assessment and characterisation. The proposed framework can be applied to design any type of landfill leachate quality monitoring programme and also to facilitate improved leachate treatment activities. A landfill site located at Turbhe, Navi Mumbai, India, which had not been investigated earlier, has been selected as a case study. The proposed framework has been demonstrated on the Turbhe landfill site which is a comparatively new and the only sanitary landfill in Navi Mumbai.

  11. Life cycle analysis of sanitary landfill and incineration of municipal solid waste

    Institute of Scientific and Technical Information of China (English)

    倪晋仁; 韦洪莲; 刘阳生; 赵智杰

    2002-01-01

    Environmental consequences from sanitary landfill as well as incineration with power generation were compared in terms of life cycle analysis (LCA) for Laohukeng Waste-disposal Plant that is under consideration in Shenzhen. A variety of differences will be resulted from the two technologies, from which the primary issue that affects the conclusion is if the compensatory phase in power generation can be properly considered in the boundary definition of LCA. Upon the compensatory phase is taken into account in the landfill system, the negative environmental consequences from the landfill will be more significant than those from the incineration with power generation, although the reversed results can be obtained as the compensatory phase is neglected. In addition, mitigation of environmental impacts through the pollutant treatment in the incineration process will be more effective than in the landfill process.

  12. Epiphytic lichens as indicators of environmental quality around a municipal solid waste landfill (C Italy).

    Science.gov (United States)

    Paoli, Luca; Grassi, Alice; Vannini, Andrea; Maslaňáková, Ivana; Bil'ová, Ivana; Bačkor, Martin; Corsini, Adelmo; Loppi, Stefano

    2015-08-01

    Epiphytic lichens have been used as indicators of environmental quality around a municipal solid waste landfill in C Italy. An integrated approach, using the diversity of epiphytic lichens, as well as element bioaccumulation and physiological parameters in the lichen Flavoparmelia caperata (L.) Hale was applied along a transect from the facility. The results highlighted the biological effects of air pollution around the landfill. The Index of Lichen Diversity (ILD) increased and the content of heavy metals (Cr, Cd, Cu, Fe, Ni and Zn) decreased with distance from the landfill. Clear stress signals were observed in lichens growing in front of the facility, i.e. discoloration, necrosis, membrane lipid peroxidation, lower ergosterol content, higher dehydrogenase activity. Decreased photosynthetic efficiency, altered chlorophyll integrity and production of secondary metabolites were also found. The results suggested that lichens can be profitably used as bioindicators of environmental quality around landfills.

  13. Evaluating the biochemical methane potential (BMP) of low-organic waste at Danish landfills

    DEFF Research Database (Denmark)

    Mou, Zishen; Scheutz, Charlotte; Kjeldsen, Peter

    2014-01-01

    The biochemical methane potential (BMP) is an essential parameter when using first order decay (FOD) landfill gas (LFG) generation models to estimate methane (CH4) generation from landfills. Different categories of waste (mixed, shredder and sludge waste) with a low-organic content and temporarily...... for more than 60 days, with continuous monitoring of the cumulative CH4 generation. Results showed that samples of mixed waste and shredder waste had similar BMP results, which was in the range of 5.4–9.1 kg CH4/ton waste (wet weight) on average. As a calculated consequence, their degradable organic carbon...... values of 51.8–69.6 and 106.6–117.3 kg CH4/ton waste on average, respectively, and DOCC values of 3.84–5.12% and 7.96–8.74% of total weight. The same category of waste from different Danish landfills did not show significant variation. This research studied the BMP of Danish low-organic waste...

  14. Mining the Midden: A Facility for Dynamic Waste Harvesting at the Cedar Hills Regional Landfill

    Science.gov (United States)

    Allan, Aaron

    Mining the Midden intends to re-frame the sanitary landfill as a new typology of public land containing an embodied energy of cultural and material value. By reconnecting the public with the landfill and seriously exposing its layers of history and then digesting both mined and new waste within an industrial facility of materials recovery and plasma gasification technology waste-to-energy plant. The sequence of experience for a public visitor begins where the waste is transformed to energy and flows in the opposite direction of the trash through the facility and then into the active landfill mining operation which is the large site component of the project. The mine is flanked by the visitor path, which is suspended from the soldier piles of the excavation system and allows the visitor to interpret along the 1/3 mile path their personal connection to the waste stream and the consumption patterns which drive our waste. Interpretation results from multi-sensory experience of the open mine and its connection to the processing structure as one hovers above, through moments of seeing through structural glass lagging directly into the sectional cut of the landfill, and through cultural artifacts harvested by landfill archaeologists which are displayed in rhythm with the structure and lagging. The culmination of the prescribed path is a narrow cut which frames the view of Mt. Rainier in the distance and opens up a visual connection with the remaining majority of the landfill which have up to this point been blocked by the small mountain of trash which they just walked up and through. This thesis intends that by confronting people with the juxtapositions of 2 potentially destructive mounds or mountains, and how we as a culture value and protect land while we simultaneously dump our rubbish on other lands, this experience will make the visitor more conscious of ones personal contribution to our culture of disposable commodities.

  15. Mixed waste landfill corrective measures study final report Sandia National Laboratories, Albuquerque, New Mexico.

    Energy Technology Data Exchange (ETDEWEB)

    Peace, Gerald (Jerry) L.; Goering, Timothy James (GRAM, Inc., Albuquerque, NM)

    2004-03-01

    The Mixed Waste Landfill occupies 2.6 acres in the north-central portion of Technical Area 3 at Sandia National Laboratories, Albuquerque, New Mexico. The landfill accepted low-level radioactive and mixed waste from March 1959 to December 1988. This report represents the Corrective Measures Study that has been conducted for the Mixed Waste Landfill. The purpose of the study was to identify, develop, and evaluate corrective measures alternatives and recommend the corrective measure(s) to be taken at the site. Based upon detailed evaluation and risk assessment using guidance provided by the U.S. Environmental Protection Agency and the New Mexico Environment Department, the U.S. Department of Energy and Sandia National Laboratories recommend that a vegetative soil cover be deployed as the preferred corrective measure for the Mixed Waste Landfill. The cover would be of sufficient thickness to store precipitation, minimize infiltration and deep percolation, support a healthy vegetative community, and perform with minimal maintenance by emulating the natural analogue ecosystem. There would be no intrusive remedial activities at the site and therefore no potential for exposure to the waste. This alternative poses minimal risk to site workers implementing institutional controls associated with long-term environmental monitoring as well as routine maintenance and surveillance of the site.

  16. Scenario analysis of the benefit of municipal organic-waste composting over landfill, Cambodia.

    Science.gov (United States)

    Seng, Bunrith; Hirayama, Kimiaki; Katayama-Hirayama, Keiko; Ochiai, Satoru; Kaneko, Hidehiro

    2013-01-15

    This paper presents insight into the benefits of organic waste recycling through composting over landfill, in terms of landfill life extension, compost product, and mitigation of greenhouse gases (GHGs). Future waste generation from 2003 to 2020 was forecast, and five scenarios of organic waste recycling in the municipality of Phnom Penh (MPP), Cambodia, were carried out. Organic waste-specifically food and garden waste-was used for composting, and the remaining waste was landfilled. The recycling scenarios were set based on organic waste generated from difference sources: households, restaurants, shops, markets, schools, hotels, offices, and street sweeping. Through the five scenarios, the minimum volume reductions of waste disposal were about 56, 123, and 219 m(3) d(-1) in 2003, 2012, and 2020, respectively, whereas the maximum volume reductions in these years were about 325, 643, and 1025 m(3) d(-1). These volume reductions reflect a landfill life extension of a minimum of half a year and a maximum of about four years. Compost product could be produced at a minimum of 14, 30, and 54 tons d(-1) in 2003, 2012, and 2020, respectively, and at a maximum in those years of about 80, 158, and 252 tons d(-1). At the same time benefit is gained in compost product, GHG emissions could be reduced by a minimum of 12.8% and a maximum of 65.0% from 2003 to 2020. This means about 3.23 (minimum) and 5.79 million tons CO(2)eq (maximum) contributed to GHG mitigation. In this regard, it is strongly recommended that MPP should try to initiate an organic-waste recycling strategy in a best fit scenario.

  17. Leachates draining from controlled municipal solid waste landfill: Detailed geochemical characterization and toxicity tests.

    Science.gov (United States)

    Mavakala, Bienvenu K; Le Faucheur, Séverine; Mulaji, Crispin K; Laffite, Amandine; Devarajan, Naresh; Biey, Emmanuel M; Giuliani, Gregory; Otamonga, Jean-Paul; Kabatusuila, Prosper; Mpiana, Pius T; Poté, John

    2016-09-01

    Management of municipal solid wastes in many countries consists of waste disposal into landfill without treatment or selective collection of solid waste fractions including plastics, paper, glass, metals, electronic waste, and organic fraction leading to the unsolved problem of contamination of numerous ecosystems such as air, soil, surface, and ground water. Knowledge of leachate composition is critical in risk assessment of long-term impact of landfills on human health and the environment as well as for prevention of negative outcomes. The research presented in this paper investigates the seasonal variation of draining leachate composition and resulting toxicity as well as the contamination status of soil/sediment from lagoon basins receiving leachates from landfill in Mpasa, a suburb of Kinshasa in the Democratic Republic of the Congo. Samples were collected during the dry and rainy seasons and analyzed for pH, electrical conductivity, dissolved oxygen, soluble ions, toxic metals, and were then subjected to toxicity tests. Results highlight the significant seasonal difference in leachate physicochemical composition. Affected soil/sediment showed higher values for toxic metals than leachates, indicating the possibility of using lagoon system for the purification of landfill leachates, especially for organic matter and heavy metal sedimentation. However, the ecotoxicity tests demonstrated that leachates are still a significant source of toxicity for terrestrial and benthic organisms. Therefore, landfill leachates should not be discarded into the environment (soil or surface water) without prior treatment. Interest in the use of macrophytes in lagoon system is growing and toxic metal retention in lagoon basin receiving systems needs to be fully investigated in the future. This study presents useful tools for evaluating landfill leachate quality and risk in lagoon systems which can be applied to similar environmental compartments.

  18. Estimation of Methane Emissions from Municipal Solid Waste Landfills in China Based on Point Emission Sources

    Directory of Open Access Journals (Sweden)

    Cai Bo-Feng

    2014-01-01

    Citation: Cai, B.-F., Liu, J.-G., Gao, Q.-X., et al., 2014. Estimation of methane emissions from municipal solid waste landfills in China based on point emission sources. Adv. Clim. Change Res. 5(2, doi: 10.3724/SP.J.1248.2014.081.

  19. Landfilling: Hydrology

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Beaven, R.

    2011-01-01

    Landfill hydrology deals with the presence and movement of water through a landfill. The main objective in landfill hydrology is usually to predict leachate generation, but the presence and movement of water in a landfill also affect the degradation of the waste, the leaching of pollutants...... and the geotechnical stability of the fill. Understanding landfill hydrology is thus important for many aspects of landfill, in particular siting, design and operation. The objective of this chapter is to give a basic understanding of the hydrology of landfills, and to present ways to estimate leachate quantities......-circuiting. In the final section different existing hydrological models for landfills are presented with a special focus on the HELP model. This model is the most widely used tool for the prediction of leachate quantities in landfills, and for the sizing of leachate control and management infrastructure....

  20. Adsorption of Lead Content in Leachate of Sukawinatan Landfill Using Solid Waste of Tofu

    Directory of Open Access Journals (Sweden)

    Sri Hartati

    2016-08-01

    Full Text Available A study on the adsorption of lead content in the leachate from the landfill by using solid waste of tofu. This study assed the effects of weight of the solid waste of tofu and the contact time on the efficiency of the Pb adsorption. The sample used in this study was artificial sample of a solution of Pb metal ion and the sample of the leachate of the landfill waste. The study was carried out with a batch system, with the variables of weight of waste of tofu of 0.5; 1.0; 1.5 g. While the variables of the contact time were 0, 30, 60, 90, 120 and 150 minutes. To determine the optimum conditions, the waste of tofu was dissolved in 50 mL of Pb metal ion solution with a concentration of 20.27 mg/L and stirred with a shaker for 30 minutes at a speed of 180 rpm. The same thing was done by varying the contact time. When the optimum condition was obtained, it was applied with varying concentrations of Pb metal ion solution and garbage landfill leachate. The initial and the final levels of the Pb metal ion solution were analyzed by using the Atomic Adsorption Spectroscopy (AAS. The initial and the final results of the heavy metals were analyzed for disclosing the adsorption efficiency. To reveal the effects of the weight of the waste of tofu and the contact time, the data were analyzed with graphs. The waste of tofu with a weight of 1.5 g and a contact time of 90 minutes, had an adsorption efficiency of 97.68% at a concentration of 20.27 mg / L for Pb ion solution and 28.57% for the leachate from the landfill waste in 100 mL of leachate.

  1. Final Disposal of Solid Waste in Sanitary Landfills and Human Health

    Directory of Open Access Journals (Sweden)

    Gustavo Silveira Graudenz

    2012-06-01

    Full Text Available This article presents a critical review of scientific literature on waste sanitary landfills and its effects on human health, with an approach to the adverse effects that are most commonly associated to living near waste landfills. The health variables included were low birth weight, congenital abnormalities, some types of neoplasms, allergies, asthma and other respiratory diseases using the MEDLINE, LILACS and CAPES’ thesis post graduation database for systematic review. In spite of the fact that some studies indicate positive asssociation between health risks and living close to landfills, the majority of the studies, mainly the most recent ones, do not demonstrate a significant health risk in this condition. Some common limitations and bias of the work in the field are discussed. The lack of direct quantification of exposure, lack of prospective approach and no comparaison of the different types and quality of management of the residues are common limitations to most studies. So far, there is weak evidence to support significant epidemiological health risks associated to landfills. More interdisciplinary research should improve the knoledge of the health risks related to living in the proximity to sanitary landfills.

  2. [Uncertainty analysis for evaluating methane emissions from municipal solid waste landfill in Beijing].

    Science.gov (United States)

    Chen, Cao-Cao; Liu, Chun-Lan; Li, Zheng; Wang, Hai-Hua; Zhang, Yan; Wang, Lu

    2012-01-01

    In order to improve the accurate evaluation of CH4 emissions from municipal solid waste landfill in Beijing, FOD-model and Monte Carlo method were conducted. Based on local data, national data and experts' experience, the uncertainty of FOD-model and parameters' sensitivity analysis were identified. And we quantified effect of various parameters on model output. The results showed that 95% probability distribution range of CH4 emission from landfill was (11.8-19.76) x 10(4) t x a(-1) in Beijing. The mean value was 15.58 x 10(4)t x a(-1) with uncertainty range of -24.26% - 26.83%. Among all the parameters MCF (after 2000) showed the greatest impact on landfill CH4 emission in 2008, and its contribution to the uncertainty of emission result was 41.4%. This research can improve the assessment accuracy and quality on CH4 emission from municipal solid waste landfill in Beijing, as providing scientific basis to improve the landfill greenhouse gas inventory and data collection.

  3. Landfill site selection for municipal solid wastes in mountainous areas with landslide susceptibility.

    Science.gov (United States)

    Eskandari, Mahnaz; Homaee, Mehdi; Falamaki, Amin

    2016-06-01

    Several cities across the world are located in mountainous and landslide prone areas. Any landfill siting without considering landslide susceptibility in such regions may impose additional environmental adversity. This study was aimed to propose a practical method for selecting waste disposal site that accounts for landslide exposure. The proposed method was applied to a city which is highly proneness to landslide due to its geology, morphology, and climatic conditions. First, information on the previously occurred landslides of the region was collected. Based on this information, proper landslide causative factors were selected and their thematic maps were prepared. Factors' classes were then standardized in 0-1 domain, and thematic layers were weighted by using analytical hierarchy process (AHP). The landslide susceptibility map was prepared afterwards. Unsuitable areas for landfill location were masked in GIS environment by Boolean method, retaining sufficient areas for further evaluation. Nine remaining alternatives were selected through comprehensive field visits and were ranked by using AHP. Consequently, 17 factors in three environmental, economical, and social perspectives were employed. Sensitivity analyses were performed to assess the stability of the alternatives ranking with respect to variations in criterion weights. Based on the obtained landslide susceptible map, nearly 36 % of the entire region is proneness to landslide. The prepared Boolean map indicates that potential areas for landfill construction cover 11 % of the whole region. The results further indicated that if landslide susceptible areas are not considered in landfill site selection, the potential landfill sites would become more than twice. It can be concluded that if any of these landslide prone sites are selected for landfilling, further environmental disaster would be terminated in the future. It can be further concluded that the proposed method could reasonably well be adjusted to

  4. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    Energy Technology Data Exchange (ETDEWEB)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  5. Environmental assessment of low-organic waste landfill scenarios by means of life-cycle assessment modelling (EASEWASTE).

    Science.gov (United States)

    Manfredi, Simone; Christensen, Thomas H; Scharff, Heijo; Jacobs, Joeri

    2010-02-01

    The environmental performance of two low-organic waste landfill scenarios ('low-organic-energy' and 'low-organic-flare') was developed and compared with two household waste landfill scenarios ('household-energy' and 'household-flare') by means of LCA-modelling. The LCA-modelling was made for 1 tonne of wet waste landfilled and the environmental aspects were evaluated for a 100-year period after disposal. The data utilized in the LCA-calculations to model the first 10-20 years of landfilling of the two low-organic waste scenarios make extensive use of site-specific data from the Nauerna Landfill (The Netherlands), but average data from other comparable, existing landfills were used too. As data from full-scale landfills do not cover more than 30-40 years of landfilling, data from laboratory simulations and accelerated tests of limited scale were also utilized. The life-cycle impact assessments show that the low-organic waste scenarios achieved better environmental performance than the household waste scenarios with regard to both ordinary and toxicity-related environmental impact categories. This indicates that the reduction of organic matter accepted at landfills (as prescribed by the European Union Landfill Directive: Council Directive 1999/31/EC, EU, Brussels, 1999) can be a successful approach to decrease the environmental loads in several impact categories in comparison with landfilling of waste with significant organic content. However, when utilization of landfill gas is accounted for in the life-cycle impact assessment calculation, the small gas generation in low-organic waste landfills reduced the actual potential for energy generation and therefore the environmental savings obtained were reduced proportionally. Groundwater pollution from input of leachate was also evaluated and the WHO (Guidelines for Drinking-water Quality; WHO, Geneva, 2006) guideline for drinking water quality was assumed as reference. The results show that low-organic waste landfills

  6. Quantification of parameters influencing methane generation due to biodegradation of municipal solid waste in landfills and laboratory experiments.

    Science.gov (United States)

    Fei, Xunchang; Zekkos, Dimitrios; Raskin, Lutgarde

    2016-09-01

    The energy conversion potential of municipal solid waste (MSW) disposed of in landfills remains largely untapped because of the slow and variable rate of biogas generation, delayed and inefficient biogas collection, leakage of biogas, and landfill practices and infrastructure that are not geared toward energy recovery. A database consisting of methane (CH4) generation data, the major constituent of biogas, from 49 laboratory experiments and field monitoring data from 57 landfills was developed. Three CH4 generation parameters, i.e., waste decay rate (k), CH4 generation potential (L0), and time until maximum CH4 generation rate (tmax), were calculated for each dataset using U.S. EPA's Landfill Gas Emission Model (LandGEM). Factors influencing the derived parameters in laboratory experiments and landfills were investigated using multi-linear regression analysis. Total weight of waste (W) was correlated with biodegradation conditions through a ranked classification scheme. k increased with increasing percentage of readily biodegradable waste (Br0 (%)) and waste temperature, and reduced with increasing W, an indicator of less favorable biodegradation conditions. The values of k obtained in the laboratory were commonly significantly higher than those in landfills and those recommended by LandGEM. The mean value of L0 was 98 and 88L CH4/kg waste for laboratory and field studies, respectively, but was significantly affected by waste composition with ranges from 10 to 300L CH4/kg. tmax increased with increasing percentage of biodegradable waste (B0) and W. The values of tmax in landfills were higher than those in laboratory experiments or those based on LandGEM's recommended parameters. Enhancing biodegradation conditions in landfill cells has a greater impact on improving k and tmax than increasing B0. Optimizing the B0 and Br0 values of landfilled waste increases L0 and reduces tmax.

  7. Quantification of landfill methane using modified Intergovernmental Panel on Climate Change's waste model and error function analysis.

    Science.gov (United States)

    Govindan, Siva Shangari; Agamuthu, P

    2014-10-01

    Waste management can be regarded as a cross-cutting environmental 'mega-issue'. Sound waste management practices support the provision of basic needs for general health, such as clean air, clean water and safe supply of food. In addition, climate change mitigation efforts can be achieved through reduction of greenhouse gas emissions from waste management operations, such as landfills. Landfills generate landfill gas, especially methane, as a result of anaerobic degradation of the degradable components of municipal solid waste. Evaluating the mode of generation and collection of landfill gas has posted a challenge over time. Scientifically, landfill gas generation rates are presently estimated using numerical models. In this study the Intergovernmental Panel on Climate Change's Waste Model is used to estimate the methane generated from a Malaysian sanitary landfill. Key parameters of the model, which are the decay rate and degradable organic carbon, are analysed in two different approaches; the bulk waste approach and waste composition approach. The model is later validated using error function analysis and optimum decay rate, and degradable organic carbon for both approaches were also obtained. The best fitting values for the bulk waste approach are a decay rate of 0.08 y(-1) and degradable organic carbon value of 0.12; and for the waste composition approach the decay rate was found to be 0.09 y(-1) and degradable organic carbon value of 0.08. From this validation exercise, the estimated error was reduced by 81% and 69% for the bulk waste and waste composition approach, respectively. In conclusion, this type of modelling could constitute a sensible starting point for landfills to introduce careful planning for efficient gas recovery in individual landfills.

  8. Size-resolved culturable airborne bacteria sampled in rice field, sanitary landfill, and waste incineration sites.

    Science.gov (United States)

    Heo, Yongju; Park, Jiyeon; Lim, Sung-Il; Hur, Hor-Gil; Kim, Daesung; Park, Kihong

    2010-08-01

    Size-resolved bacterial concentrations in atmospheric aerosols sampled by using a six stage viable impactor at rice field, sanitary landfill, and waste incinerator sites were determined. Culture-based and Polymerase Chain Reaction (PCR) methods were used to identify the airborne bacteria. The culturable bacteria concentration in total suspended particles (TSP) was found to be the highest (848 Colony Forming Unit (CFU)/m(3)) at the sanitary landfill sampling site, while the rice field sampling site has the lowest (125 CFU/m(3)). The closed landfill would be the main source of the observed bacteria concentration at the sanitary landfill. The rice field sampling site was fully covered by rice grain with wetted conditions before harvest and had no significant contribution to the airborne bacteria concentration. This might occur because the dry conditions favor suspension of soil particles and this area had limited personnel and vehicle flow. The respirable fraction calculated by particles less than 3.3 mum was highest (26%) at the sanitary landfill sampling site followed by waste incinerator (19%) and rice field (10%), which showed a lower level of respiratory fraction compared to previous literature values. We identified 58 species in 23 genera of culturable bacteria, and the Microbacterium, Staphylococcus, and Micrococcus were the most abundant genera at the sanitary landfill, waste incinerator, and rice field sites, respectively. An antibiotic resistant test for the above bacteria (Micrococcus sp., Microbacterium sp., and Staphylococcus sp.) showed that the Staphylococcus sp. had the strongest resistance to both antibiotics (25.0% resistance for 32 microg ml(-1) of Chloramphenicol and 62.5% resistance for 4 microg ml(-1) of Gentamicin).

  9. Evaluation of Landfill Cover Design Options for Waste Disposal Sites in the Coastal Regions of Ghana

    Directory of Open Access Journals (Sweden)

    Kodwo Beedu Keelson

    2015-01-01

    Full Text Available Uncontrolled leachate generation from operational and closed waste disposal sites is a major environmental concern in the coastal regions of Ghana which have abundant surface water and groundwater resources. The Ghana Landfill Guidelines requires the provision of a final cover or capping system as part of a final closure plan for waste disposal sites in the country as a means of minimizing the harmful environmental effects of these emissions. However, this technical manual does not provide explicit guidance on the material types or configuration for landfill covers that would be suitable for the different climatic conditions in the country. Four landfill cover options which are based on the USEPA RCRA-type and evapotranspirative landfill cover design specifications were evaluated with the aid of the HELP computer program to determine their suitability for waste disposal sites located in the Western, Central and Greater Accra regions. The RCRA Subtitle C cover which yielded flux rates of less than 0.001 mm/yr was found to be suitable for the specific climatic conditions. The RCRA Subtitle D cover was determined to be unsuitable due to the production of very large flux rates in excess of 200 mm/yr. The results for the anisotropic barrier and capillary barrier covers were inconclusive. Recommendations for further study include a longer simulation period as well the study of the combined effects of different topsoil vegetative conditions and evaporative zone depths on the landfill water balance. The use of other water balance models such as EPIC, HYDRUS-2D and UNSAT-H for the evaluation of the evapotranspirative landfill cover design options should also be considered.

  10. Innovative landfill bioreactor systems for municipal solid waste treatment in East Africa aimed at optimal energy recovery and minimal greenhouse gas emissions

    NARCIS (Netherlands)

    Salukele, F.M.

    2013-01-01

    Landfilling is currently the dominant disposal method for municipal solid waste (MSW) in developing countries. Approximately 50% of the MSW generated in East Africa is disposed in landfills. Low costs and availability of land have made landfilling the most common waste management option in East Afri

  11. N 2O emissions at municipal solid waste landfill sites: Effects of CH 4 emissions and cover soil

    Science.gov (United States)

    Zhang, Houhu; He, Pinjing; Shao, Liming

    Municipal solid waste landfills are the significant anthropogenic sources of N 2O due to the cooxidation of ammonia by methane-oxidizing bacteria in cover soils. Such bacteria could be developed through CH 4 fumigation, as evidenced by both laboratory incubation and field measurement. During a 10-day incubation with leachate addition, the average N 2O fluxes in the soil samples, collected from the three selected landfill covers, were multiplied by 1.75 ( p landfill sites, N 2O fluxes in two landfill sites were significantly correlated with the variations of the CH 4 emissions without landfill gas recovery ( p landfill gas recovery in another landfill site ( p > 0.05). The annual average N 2O flux was 176 ± 566 μg N 2O-N m -2 h -1 ( p landfill site, which was 72% ( p landfill sites, respectively. The magnitude order of N 2O emissions in three landfill sites was also coincident by the results of laboratory incubation, suggesting the sandy soil cover could mitigate landfill N 2O emissions.

  12. The Characteristics of Leachate and Groundwater Pollution at Municipal Solid Waste Landfill of Ibb City, Yemen

    Directory of Open Access Journals (Sweden)

    Esmail A. Sabahi

    2009-01-01

    Full Text Available Problem statement: Yemen one of the developing country suffering from water pollution. Landfill is one of the source of water pollution. There are several boreholes located close to Ibb landfill used for drinking water. A study of composition of landfill leachate and groundwater pollution was conducted at Ibb landfill, which is located at Al-Sahool area, north of Ibb City, Yemen. Approach: The leachate was sampled at three different locations of the landfill, at the landfill itself and 15 and 20 m downstream of this landfill. Groundwater samples collected from 5 boreholes to study possible impact of leachate percolation into groundwater. Leachate and groundwater samples were collected during dry season only, due to the excessive generation of leachate during this season. Objective of this study was significant to assess degree of groundwater pollution due to Ibb landfill leachate at Al-Sahool area. The leachate and groundwater were physically and chemically characterized by using spectrophotometer HACH, BOD Trak HACH, flame photometer (PFP 7 and Inductively Coupled Plasma of Optical Emission Spectrometry (ICP-OES model Vista MPX. Parameters measured were pH, temperature, Electrical Conductivity (EC, Total Dissolved Solids (TDS, Dissolved Oxygen (DO, Fluoride (F, Chloride (Cl, Sulphate (SO4, Nitrites (NO2, Nitrates (NO3, ammonia-N (NH3-N, heavy metals (Pb, Zn, Ni, Cr, Cd, Cu, major cations (Na, Mg, Ca, K, Fe and biological parameters (COD, BOD5 and coliform group bacteria. Results: The results showed that, leachate at landfill most likely in methanogenic phase, based on the alkaline pH value recorded (pH = 8.46. The results also showed that 4 out of 5 boreholes were contaminated, where concentration of physico-chemical parameters are above the standard acceptable levels which required for drinking water adapted by Yemen's ministry of water and environment and by word standard. Conclusion: Therefore, landfill is dangerous for environment so

  13. Long-term biological monitoring of environmental quality around a solid waste landfill assessed with lichens.

    Science.gov (United States)

    Paoli, L; Corsini, A; Bigagli, V; Vannini, J; Bruscoli, C; Loppi, S

    2012-02-01

    The diversity of epiphytic lichens and the accumulation of selected trace elements in the lichen Flavoparmelia caperata L. (Hale) were used as indicators of pollution around a landfill in central Italy along 14 years of waste management. Lichens revealed an increased deposition for some elements (i.e., Cd, Cr, Fe and Ni) and a decrease of the lichen diversity at sites facing the landfill after an enlargement of the dumping area. However, the results allowed to exclude a significant increase in heavy metal depositions in the surrounding area and suggested that successful waste management may be associated with environmental quality. It is concluded that lichen monitoring might provide essential information to enhance the implementation of ecological impact assessment, supporting industrial regulatory procedures, also when waste management is concerned.

  14. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    Energy Technology Data Exchange (ETDEWEB)

    Galowitz, Stephen

    2013-06-30

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control

  15. Mercury air-borne emissions from 5 municipal solid waste landfills in Guiyang and Wuhan, China

    Directory of Open Access Journals (Sweden)

    Z. G. Li

    2010-01-01

    Full Text Available A detailed study on atmospheric mercury emissions from municipal solid waste (MSW landfills in China is necessary to understand mercury behavior in this source category, simply because China disposes of bulk MSW by landfilling and a large quantity of mercury enters into landfills. Between 2003 and 2006, mercury airborne emissions through different pathways, as well as mercury speciation in landfill gas (LFG were measured at 5 MSW landfills in Guiyang and Wuhan, China. The results showed that mercury content in the substrate fundamentally affected the magnitude of mercury emissions, resulting in the highest emission rate (as high as 57 651 ng Hg m−2 h−1 at the working face and in un-covered waste areas, and the lowest measured at soil covers and vegetation areas (less than 20 ng Hg m−2 h−1. Meteorological parameters, especially solar radiation, influenced the diurnal pattern of mercury surface-air emissions. Total gaseous mercury (TGM in LFG varied from 2.0 to 1406.0 ng m−3, monomethyl mercury (MMHg and dimethyl mercury (DMHg in LFG averaged at 1.93 and 9.21 ng m−3, and accounted for 0.51% and 1.79% of the TGM in the LFG, respectively. Total mercury emitted from the five landfills ranged from 17 to 3285 g yr−1, with the highest from the working face, then soil covering, and finally the vent pipes.

  16. Chemical and mineralogical characterization of blast-furnace sludge from an abandoned landfill.

    Science.gov (United States)

    Mansfeldt, Tim; Dohrmann, Reiner

    2004-11-15

    Blast-furnace sludge is generated during the production of pig iron and is disposed of in the environment in large surface landfills. We investigated blast-furnace sludge samples of an abandoned landfill in order to determine its chemical and mineralogical nature and to evaluate some environmental hazards that may arise from this industrial waste. The mineralogical inventory, which was quantified by Rietveld refinement of XRD analyses using the fundamental-parameter approach, revealed that blast-furnace sludge is dominated by X-ray amorphous substances (with a mean of 590 g kg(-1)) including coke and (hydr)oxides of Fe, Si, Al, Zn, and Pb. Calcite (CaCO3) (136 g kg(-1)), dolomite (Ca,Mg[CO3]2) (14 g kg(-1)), quartz (SiO2) (55 g kg(-1)), kaolinite (Al2[OH]4Si2O5) (40 g kg(-1)), graphite (C) (27 g kg(-1)), and chemically not specified layered double hydroxides (28 g kg(-1)) were identified in almost all samples. Iron is present as magnetite (Fe3O4) (34 g kg(-1)), hematite (Fe2O3) (38 g kg(-1)), wuestite (FeO) (20 g kg(-1)) and alpha-iron (Fe0) (6 g kg(-1)). Chemically, blast-furnace sludge is dominated by C (190 g kg(-1)) and Fe (158 g kg(-1)) reflecting the process of pig-iron production. On the basis of total contents, environmentally problematic metals (including As) are Zn (32.6 g kg(-1)), Pb (10.3 g kg(-1)), Cd (81 mg kg(-1)), and As (129 mg kg(-1)). As the forested landfill is used by residents for leisure activities, the exposure assessment by pathway oral uptake of blast-furnace sludge particles by humans has to be critically evaluated, particularly as significant proportions of metals are acid-soluble. However, under the prevailing slightly alkaline pH values of the sludge (pH 7.6-9.2), the solubility of the metals is very low as indicated by low pore water concentrations. Currently, groundwater monitoring should be focused mainly on F- since the F- concentrations in the pore water of blast-furnace sludge are at high level (2.65-24.1 mg of F- L(-1)).

  17. Hazardous Waste Landfill Siting using GIS Technique and Analytical Hierarchy Process

    Directory of Open Access Journals (Sweden)

    Ozeair Abessi

    2010-07-01

    Full Text Available Disposal of large amount of generated hazardous waste in power plants, has always received communities' and authori¬ties attentions. In this paper using site screening method and Analytical Hierarchy Process (AHP a sophisticated approach for siting hazardous waste landfill in large areas is presented. This approach demonstrates how the evaluation criteria such as physical, socio-economical, technical, environmental and their regulatory sub criteria can be introduced into an over layer technique to screen some limited appropriate zones in the area. Then, in order to find the optimal site amongst the primary screened site utilizing a Multiple Criteria Decision Making (MCDM method for hierarchy computations of the process is recommended. Using the introduced method an accurate siting procedure for environmental planning of the landfills in an area would be enabled. In the study this approach was utilized for disposal of hazardous wastes of Shahid Rajaee thermal power plant located in Qazvin province west central part of Iran. As a result of this study 10 suitable zones were screened in the area at first, then using analytical hierarchy process a site near the power plant were chosen as the optimal site for landfilling of the hazardous wastes in Qazvin province.

  18. Characterizing the biotransformation of sulfur-containing wastes in simulated landfill reactors.

    Science.gov (United States)

    Sun, Wenjie; Sun, Mei; Barlaz, Morton A

    2016-07-01

    Landfills that accept municipal solid waste (MSW) in the U.S. may also accept a number of sulfur-containing wastes including residues from coal or MSW combustion, and construction and demolition (C&D) waste. Under anaerobic conditions that dominate landfills, microbially mediated processes can convert sulfate to hydrogen sulfide (H2S). The presence of H2S in landfill gas is problematic for several reasons including its low odor threshold, human toxicity, and corrosive nature. The objective of this study was to develop and demonstrate a laboratory-scale reactor method to measure the H2S production potential of a range of sulfur-containing wastes. The H2S production potential was measured in 8-L reactors that were filled with a mixture of the target waste, newsprint as a source of organic carbon required for microbial sulfate reduction, and leachate from decomposed residential MSW as an inoculum. Reactors were operated with and without N2 sparging through the reactors, which was designed to reduce H2S accumulation and toxicity. Both H2S and CH4 yields were consistently higher in reactors that were sparged with N2 although the magnitude of the effect varied. The laboratory-measured first order decay rate constants for H2S and CH4 production were used to estimate constants that were applicable in landfills. The estimated constants ranged from 0.11yr(-1) for C&D fines to 0.38yr(-1) for a mixed fly ash and bottom ash from MSW combustion.

  19. Minimizing N2O fluxes from full-scale municipal solid waste landfill with properly selected cover soil

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Municipal solid waste landfills emit nitrous oxide (N2O) gas. Assuming that the soil cover is the primary N2O source from landfills,this study tested, during a four-year project, the hypothesis that the proper use of chosen soils with fine texture minimizes N2O emissions. A full-scale sanitary landfill, a full-scale bioreactor landfill and a cell planted with Nerium indicum or Festuca arundinacea Schreb, at the Hangzhou Tianziling landfill in Hangzhou City were the test sites. The N2O emission rates from all test sites were considerably lower than those reported in the published reports. Specifically, the N2O emission rate was dependent on soil water content and nitrate concentrations in the cover soil. The effects of leachate recirculation and irrigation were minimal. Properly chosen cover soils applied to the landfills reduced N2O flux.

  20. Waste management without landfills. The goal set for 2020 - utopian or realistic?; Deponiefreie Siedlungsabfallwirtschaft. Zielstellung 2020: Utopie oder realistische Aufgabe?

    Energy Technology Data Exchange (ETDEWEB)

    Radde, C.-A. [Bundesministerium fuer Umwelt, Naturschutz und Reaktorsicherheit, Bonn (Germany)

    2005-07-01

    As early as August 1999, the then FEderal Government stated its goals until 2020: Landfilling of untreated biodegradable was to end on 1 June 2005; Technologically complex mechanical and biological treatment plants can be used for waste treatment parallel to incineration; Environmentally inacceptable landfills were to be closed down gradually; By 2020, full environment-friendly treatment of all domestic waste in Germany was to be ensured. The contribution attempts to find out if this is at all possible. (orig.)

  1. Control technology assessment of hazardous waste disposal operations in chemicals manufacturing: walk-through survey report of Chemical Waste Management, Inc. , Emelle, Alabama

    Energy Technology Data Exchange (ETDEWEB)

    Anastas, M.

    1982-08-01

    A walk through survey was conducted to assess hazardous waste disposal operations at Chemical Waste Management, Incorporated (SIC-4953), Emelle, Alabama in February 1982. Hazardous waste treatment and disposal operations included landfilling, fixation, solar evaporation, and incineration. The incinerator was a liquid injection unit used for combustible liquids containing up to 10 percent chlorine. Polychlorinated biphenyls and other chlorine containing wastes not treated on site were temporarily stored before shipment for at sea incineration. In-situ fixation was carried out on corrosive, acidic, and heavy metal containing liquids. Liquid wastes were removed and eventually pumped into a pit where they were mixed with cement kiln dust. Drum stored wastes intended for landfilling were transported by front end loaders to the site. Heavy equipment operators were protected from exposure to dust by environmental cabs. Air and medical monitoring were performed on landfill, laboratory, and maintenance shop workers. Hard hats, goggles, and safety shoes were required at the landfill. Respirators and other protective equipment and clothing were available. The author concludes that the company management is concerned about the health and safety of the employees. An in depth survey is recommended.

  2. Gravimetric water distribution assessment from geoelectrical methods (ERT and EMI) in municipal solid waste landfill.

    Science.gov (United States)

    Dumont, Gaël; Pilawski, Tamara; Dzaomuho-Lenieregue, Phidias; Hiligsmann, Serge; Delvigne, Frank; Thonart, Philippe; Robert, Tanguy; Nguyen, Frédéric; Hermans, Thomas

    2016-09-01

    The gravimetric water content of the waste material is a key parameter in waste biodegradation. Previous studies suggest a correlation between changes in water content and modification of electrical resistivity. This study, based on field work in Mont-Saint-Guibert landfill (Belgium), aimed, on one hand, at characterizing the relationship between gravimetric water content and electrical resistivity and on the other hand, at assessing geoelectrical methods as tools to characterize the gravimetric water distribution in a landfill. Using excavated waste samples obtained after drilling, we investigated the influences of the temperature, the liquid phase conductivity, the compaction and the water content on the electrical resistivity. Our results demonstrate that Archie's law and Campbell's law accurately describe these relationships in municipal solid waste (MSW). Next, we conducted a geophysical survey in situ using two techniques: borehole electromagnetics (EM) and electrical resistivity tomography (ERT). First, in order to validate the use of EM, EM values obtained in situ were compared to electrical resistivity of excavated waste samples from corresponding depths. The petrophysical laws were used to account for the change of environmental parameters (temperature and compaction). A rather good correlation was obtained between direct measurement on waste samples and borehole electromagnetic data. Second, ERT and EM were used to acquire a spatial distribution of the electrical resistivity. Then, using the petrophysical laws, this information was used to estimate the water content distribution. In summary, our results demonstrate that geoelectrical methods represent a pertinent approach to characterize spatial distribution of water content in municipal landfills when properly interpreted using ground truth data. These methods might therefore prove to be valuable tools in waste biodegradation optimization projects.

  3. A PRELIMINARY EXPERIMENT ON DENITRIFICATION OF WASTE LANDFILL LEACHATE

    Science.gov (United States)

    Wada, Nariaki; Nakamichi, Tamihiro; Yagi, Masahiro; Matsumoto, Toshihide; Kugimiya, Akikazu; Michioku, Kohji

    A laboratory experiment on denitrification was carried out in order to reduce nitrogen load from municipal landfill leachate. Nitrogen was efficiently removed by feeding sludge of the leachate pond into the tanks, which could activate denitrification bacteria. Although inorganic reducing agent such as iron powder was not able to make the whole water mass anoxic, denitrification took place by supplying organic matters such as methanol, hydrogen feeding agent, etc.. It is considered that small amount of anoxic water film produced on surfaces of container and carriers might contribute to denitrification, although the bulk water is kept aerobic. It is found that organic matters contained in the leachate is so insufficient that nitrification liquid circulation does not work well for denitrification.

  4. Paper waste - Recycling, incineration or landfilling? A review of existing life cycle assessments

    DEFF Research Database (Denmark)

    Villanueva, Alejandro; Wenzel, Henrik

    2007-01-01

    comparisons of different management options for waste paper.\\ Despite claims of inconsistency, the LCAs reviewed illustrate the environmental benefits in recycling over incineration or landfill options, for paper and cardboard waste. This broad consensus was found despite differences in geographic location......A review of existing life cycle assessments (LCAs) on paper and cardboard waste has been undertaken. The objectives of the review were threefold. Firstly, to see whether a consistent message comes out of published LCA literature on optimum disposal or recycling solutions for this waste type....... Such message has implications for current policy formulation on material recycling and disposal in the EU. Secondly, to identify key methodological issues of paper waste management LCAs, and enlighten the influence of such issues on the conclusions of the LCA studies. Thirdly, in light of the analysis made...

  5. Quantification of regional leachate variance from municipal solid waste landfills in China

    DEFF Research Database (Denmark)

    Yang, Na; Damgaard, Anders; Kjeldsen, Peter;

    2015-01-01

    contents. To overcome this problem, a new estimation method was established considering two sources: (1) precipitation infiltrated throughout waste layers, which was simulated with the HELP model, (2) water squeezed out of the waste itself, which was theoretically calculated using actual data of Chinese...... of about 58.2%. In China-NW, accumulated leachate amounts were very low and mainly the result of waste degradation, implying on-site spraying/irrigation or recirculation may be an economic approach to treatment. In China-N, water squeezed out of waste by compaction totaled 22-45% of overall leachate......The quantity of leachate is crucial when assessing pollution emanating from municipal landfills. In most cases, existing leachate quantification measures only take into account one source - precipitation, which resulted in serious underestimation in China due to its waste properties: high moisture...

  6. Landfills - MO 2006 Solid Waste Management Districts (SHP)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This data set contains boundaries and contact information for Missouri Solid Waste Management districts and regions. The districts were created by statute to foster...

  7. Aromatic compound emissions from municipal solid waste landfill: Emission factors and their impact on air pollution

    Science.gov (United States)

    Liu, Yanjun; Lu, Wenjing; Guo, Hanwen; Ming, Zhongyuan; Wang, Chi; Xu, Sai; Liu, Yanting; Wang, Hongtao

    2016-08-01

    Aromatic compounds (ACs) are major components of volatile organic compounds emitted from municipal solid waste (MSW) landfills. The ACs emissions from the working face of a landfill in Beijing were studied from 2014 to 2015 using a modified wind tunnel system. Emission factors (EFs) of fugitive ACs emissions from the working face of the landfill were proposed according to statistical analyses to cope with their uncertainty. And their impacts on air quality were assessed for the first time. Toluene was the dominant AC with an average emission rate of 38.8 ± 43.0 μg m-2 s-1 (at a sweeping velocity of 0.26 m s-1). An increasing trend in AC emission rates was observed from 12:00 to 18:00 and then peaked at 21:00 (314.3 μg m-2 s-1). The probability density functions (PDFs) of AC emission rates could be classified into three distributions: Gaussian, log-normal, and logistic. EFs of ACs from the working face of the landfill were proposed according to the 95th percentile cumulative emission rates and the wind effects on ACs emissions. The annual ozone formation and secondary organic aerosol formation potential caused by AC emissions from landfills in Beijing were estimated to be 8.86 × 105 kg year-1 and 3.46 × 104 kg year-1, respectively. Toluene, m + p-xylene, and 1,3,5-trimethylbenzene were the most significant contributors to air pollution. Although ACs pollutions from landfills accounts for less percentage (∼0.1%) compared with other anthropogenic sources, their fugitive emissions which cannot be controlled efficiently deserve more attention and further investigation.

  8. Morbidity and mortality of people who live close to municipal waste landfills: a multisite cohort study

    Science.gov (United States)

    Mataloni, Francesca; Badaloni, Chiara; Golini, Martina Nicole; Bolignano, Andrea; Bucci, Simone; Sozzi, Roberto; Forastiere, Francesco; Davoli, Marina; Ancona, Carla

    2016-01-01

    Background: The evidence on the health effects related to residing close to landfills is controversial. Nine landfills for municipal waste have been operating in the Lazio region (Central Italy) for several decades. We evaluated the potential health effects associated with contamination from landfills using the estimated concentration of hydrogen sulphide (H2S) as exposure. Methods: A cohort of residents within 5 km of landfills was enrolled (subjects resident on 1 January 1996 and those who subsequently moved into the areas until 2008) and followed for mortality and hospitalizations until 31 December 2012. Assessment of exposure to the landfill (H2S as a tracer) was performed for each subject at enrolment, using a Lagrangian dispersion model. Information on several confounders was available (gender, age, socioeconomic position, outdoor PM10 concentration, and distance from busy roads and industries). Cox regression analysis was performed [Hazard Ratios (HRs), 95% confidence intervals (CIs)]. Results: The cohort included 242 409 individuals. H2S exposure was associated with mortality from lung cancer and respiratory diseases (e.g. HR for increment of 1 ng/m3 H2S: 1.10, 95% CI 1.02–1.19; HR 1.09, 95% CI 1.00–1.19, respectively). There were also associations between H2S and hospitalization for respiratory diseases (HR = 1.02, 95% CI 1.00–1.03), especially acute respiratory infections among children (0–14 years) (HR = 1.06, 95% CI 1.02–1.11). Conclusions: Exposure to H2S, a tracer of airborne contamination from landfills, was associated with lung cancer mortality as well as with mortality and morbidity for respiratory diseases. The link with respiratory disease is plausible and coherent with previous studies, whereas the association with lung cancer deserves confirmation. PMID:27222499

  9. Assessment of landfill reclamation and the effects of age on the combustion of recovered municipal solid waste

    Energy Technology Data Exchange (ETDEWEB)

    Forster, G A [Lancaster Environmental Foundation, PA (United States)

    1995-01-01

    This report summarized the Lancaster county Solid Waste Management Authorities`s (LCSWMA)landfill reclamation activities, ongoing since 1991. All aspects have been analyzed from the manpower and equipment requirements at the landfill to the operational impacts felt at the LCSWMA Resource Recovery Facility (RRF) where the material is delivered for processing. Characteristics of the reclaimed refuse and soil recovered from trommeling operations are discussed as are results of air monitoring performed at the landfill excavation site and the RRF. The report also discusses the energy value of the reclaimed material and compares this value with those obtained for significantly older reclaimed waste streams. The effects of waste age on the air emissions and ash residue quality at the RRF are also provided. The report concludes by summarizing the project benefits and provides recommendations for other landfill reclamation operations and areas requiring further research.

  10. Comparison between landfill gas and waste incineration for power generation in Astana, Kazakhstan.

    Science.gov (United States)

    Inglezakis, Vassilis J; Rojas-Solórzano, Luis; Kim, Jong; Aitbekova, Aisulu; Ismailova, Aizada

    2015-05-01

    The city of Astana, the capital of Kazakhstan, which has a population of 804,474, and has been experiencing rapid growth over the last 15 years, generates approximately 1.39 kg capita(-1) day(-1) of municipal solid waste (MSW). Nearly 700 tonnes of MSW are collected daily, of which 97% is disposed of at landfills. The newest landfill was built using modern technologies, including a landfill gas (LFG) collection system.The rapid growth of Astana demands more energy on its path to development, and the viability analysis of MSW to generate electricity is imperative. This paper presents a technical-economic pre-feasibility study comparing landfill including LFG utilization and waste incineration (WI) to produce electricity. The performance of LFG with a reciprocating engine and WI with steam turbine power technologies were compared through corresponding greenhouse gases (GHG) reduction, cost of energy production (CEP), benefit-cost ratio (BCR), net present value (NPV) and internal rate of return (IRR) from the analyses. Results demonstrate that in the city of Astana, WI has the potential to reduce more than 200,000 tonnes of GHG per year, while LFG could reduce slightly less than 40,000 tonnes. LFG offers a CEP 5.7% larger than WI, while the latter presents a BCR two times higher than LFG. WI technology analysis depicts a NPV exceeding 280% of the equity, while for LFG, the NPV is less than the equity, which indicates an expected remarkable financial return for the WI technology and a marginal and risky scenario for the LFG technology. Only existing landfill facilities with a LFG collection system in place may turn LFG into a viable project.

  11. Design concept for the solid waste landfill site:a case study of Chuzhou City,China

    Institute of Scientific and Technical Information of China (English)

    Wu Wentao

    2006-01-01

    This paper introduces landfill site of Chuzhou domestic waste, to which the improved anaerobic hygienic burying technology is applied. Chuzhou City, situated between Yangtze River and Huai River, is a window city in the east of Anhui Province. A landfill site with a capacity of 400 ton per day is to be constructed according to the city development plan and the garbage amount. This paper summarizes the landfill location, landform, groundwater; surface water,landfill stratal configuration, dominant wind, and the major machinery equipment. The projects of anti-percolation,seepage collection, seepage disposal, rainwater discharge, biogas diversion are deeply studied. The advanced design principle of the landfills is summarized, which is environment-friendly, science-oriented and economy-based. Environ ment-friendly principle is implemented in the selection of landfill location, construction of all projects, sealing up project and perfecting environment monitoring system; science-oriented principle prescribes that the design, construction, and management should be science-oriented; the selection of landfill location, design, plan optimization, resource-saving measures and comprehensive utilization should be economy-based. Chuzhou domestic waste landfill site is qualified as a golden model in this paper.

  12. Solid waste landfills under the Resource Conservation and Recovery Act Subtitle D

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    This document provides guidance for meeting: (1) Guidelines for the Land Disposal of Solid Waste (40 CFR 241); (2) Criteria for Classification of Solid Waste Disposal Facilities and Practices (40 CFR 257); and (3) Criteria for Municipal Solid Waste Landfills (MSWLFs) (40 CFR Part 258). Revisions to 40 CFR 257 and a new Part 258 were published in the Federal Register (56 FR 50978, 10/9/91). The Guidelines for the Land Disposal of Solid Waste set requirements and recommended procedures to ensure that the design, construction, and operation of land disposal sites is done in a manner that will protect human health and the environment. These regulations are applicable to MSWLFs and non-MSWLFs (e.g., landfills used only for the disposal of demolition debris, commercial waste, and/or industrial waste). These guidelines are not applicable to the, land disposal of hazardous, agricultural, and/or mining wastes. These criteria are to be used under the Resource Conservation and Recovery Act (RCRA) in determining which solid waste disposal facilities pose a reasonable possibility of adversely affecting human health or the environment. Facilities failing to satisfy these criteria will be considered to be open dumps which are prohibited under Section 4005 of RCRA. The Criteria for MSWLFs are applicable only to MSWLFs, including those MSWLFs in which sewage sludge is co-disposed with household waste. Based on specific criteria, certain MSWLFs are exempt from some, or all, of the regulations of 40 CFR 258. MSWLFs that fail to satisfy the criteria specified in 40 CFR 258 are also considered open dumps for the purposes of Section 4005 of RCRA. Through the use of a series of interrelated flow diagrams, this guidance document directs the reader to each design, operation, maintenance, and closure activity that must be performed for MSWLFs and non-MSWLFs.

  13. Landfilling: Environmental Issues

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Manfredi, Simone; Kjeldsen, Peter

    2011-01-01

    , the extent and quality of the technical environmental protection measures introduced, the daily operation and the timescale. This chapter describes the main potential environmental impacts from landfills. The modern landfill is able to avoid most of these impacts. However, in the planning and design...... of landfills it is important to understand the potential environmental impacts, which must be avoided. The emissions of landfill gas and leachate causing most of the environmental risks are described in detail in the chapters addressing specific landfill types: Chapter 10.5 (mineral waste landfill), Chapter 10...... to air, soil and water caused by the processes stabilizing the waste in the landfill. The main factors controlling the actual environmental impacts from the landfilling are: the nature and amount of the waste landfilled, the geological and hydrological setting of the landfill, the landfill technology...

  14. Characterization of trichloroethylene adsorption onto waste biocover soil in the presence of landfill gas.

    Science.gov (United States)

    He, Ruo; Su, Yao; Kong, Jiaoyan

    2015-09-15

    Waste biocover soils (WBS) have been demonstrated to have great potential in mitigating trichloroethylene (TCE) emission from landfills, due to the relatively high TCE-degrading capacity. In this study, the characteristics of TCE adsorption on WBS in the presence of the major landfill gas components (i.e., CH4 and CO2) were investigated in soil microcosms. The adsorption isotherm of TCE onto WBS was fitted well with linear model within the TCE concentrations of 7000 ppmv. The adsorption capacity of TCE onto WBS was affected by temperature, soil moisture content and particle size, of which, temperature was the dominant factor. The adsorption capacity of TCE onto the experimental materials increased with the increasing organic matter content. A significantly positive correlation was observed between the adsorption capacity of TCE and the organic matter content of experimental materials that had relatively higher organic content (r = 0.988, P = 0.044). To better understand WBS application in practice, response surface methodology was developed to predict TCE adsorption capacity and emissions through WBS in different landfills in China. These results indicated that WBS had high adsorption capacity of TCE in LFG and temperature should be paid more attention to manipulate WBS to reduce TCE emissions from landfills.

  15. Bioreactor landfill

    Institute of Scientific and Technical Information of China (English)

    WANG Hao; XING Kai; Anthony Adzomani

    2004-01-01

    Following the population expansion, there is a growing threat brought by municipal solid waste (MSW) against environment and human health. Sanitary landfill is the most important method of MSW disposal in China. In contrast to the conventional landfill, this paper introduces a new technique named bioreactor landfill (BL). Mechanisms, operation conditions as well as the advantages and disadvantages of BL are also discussed in this paper.

  16. Enhanced stabilisation of municipal solid waste in bioreactor landfills

    NARCIS (Netherlands)

    Valencia Vázquez, R.

    2008-01-01

    The increasing development and urbanization of the society has led to an increase per-capita production of municipal solid waste (MSW) materials. These MSW materials are of organic and inorganic nature that can be of rapidly, moderately and slowly biodegradable or inert characteristics. With regard

  17. Small-scale simulation of waste degradation in landfills

    Energy Technology Data Exchange (ETDEWEB)

    Martin, D.J.; Potts, L.G.A.; Reeves, A. [Nottingham Univ., Chemical Engineering Dept., Nottingham (United Kingdom)

    1997-07-01

    Biogas production from a mixture of food and paper, with additions of inoculum, buffer and nutrient, began after 24 weeks and reached 0.8 vol/vol.day from Week 40 to 51, at 55-65% (v/v) methane. Methanogenesis from a simulated solid waste has not previously been reported. (Author)

  18. DOES COMPOSTING OF BIODEGRADABLE MUNICIPAL SOLID WASTE ON THE LANDFILL BODY MAKE SENSE?

    Directory of Open Access Journals (Sweden)

    Dana Adamcová

    2016-01-01

    Full Text Available In this study white mustard (Sinapis alba plants were allowed to grow in earthen pots, treated with municipal solid waste compost (MSWC to study the effect of MSWC on the plant biomass production. Twenty-one days from the establishment of the experiment sprouts and the number of growing plants occurring in the earthen pots were counted. Plants growing in the earthen pots with the compost samples exhibited an increasing plant biomass while no changes were observed in their appearance; retarded growth or necrotic changes were not recorded. The performed phytotoxicity tests show that the analyzed composts produced in the composting plant situated on the landfill surface achieved high percentages of the germinating capacity of white mustard (Sinapis alba seeds and can be therefore used in the subsequent reclamation of the concerned landfill.

  19. Treatment of leachates of sanitary landfills of urban solid wastes. Tratamiento de lixiviados de vertederos controlados de residuos solidos urbanos

    Energy Technology Data Exchange (ETDEWEB)

    Iza Lopez, J. (Departamento de Ingenieria Quimica y de Medio Ambiente, ETSII, Bilbao (Spain))

    1994-01-01

    The method more used for Urban Solid Wastes is the sanitary landfill. Its management is similar to the industrial process plant. The minimization techniques of wastes are applicated to reduce the environmental impact and to increase the degradation process in order to improve the biogas as alternative energy. This article analyzes the anaerobic digestion, the leachates characterization and treatment of leachates. (Author)

  20. A case-study of landfill minimization and material recovery via waste co-gasification in a new waste management scheme

    Energy Technology Data Exchange (ETDEWEB)

    Tanigaki, Nobuhiro, E-mail: tanigaki.nobuhiro@eng.nssmc.com [NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., (EUROPEAN OFFICE), Am Seestern 8, 40547 Dusseldorf (Germany); Ishida, Yoshihiro [NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., 46-59, Nakabaru, Tobata-ku, Kitakyushu, Fukuoka 804-8505 (Japan); Osada, Morihiro [NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., (Head Office), Osaki Center Building 1-5-1, Osaki, Shinagawa-ku, Tokyo 141-8604 (Japan)

    2015-03-15

    Highlights: • A new waste management scheme and the effects of co-gasification of MSW were assessed. • A co-gasification system was compared with other conventional systems. • The co-gasification system can produce slag and metal with high-quality. • The co-gasification system showed an economic advantage when bottom ash is landfilled. • The sensitive analyses indicate an economic advantage when the landfill cost is high. - Abstract: This study evaluates municipal solid waste co-gasification technology and a new solid waste management scheme, which can minimize final landfill amounts and maximize material recycled from waste. This new scheme is considered for a region where bottom ash and incombustibles are landfilled or not allowed to be recycled due to their toxic heavy metal concentration. Waste is processed with incombustible residues and an incineration bottom ash discharged from existent conventional incinerators, using a gasification and melting technology (the Direct Melting System). The inert materials, contained in municipal solid waste, incombustibles and bottom ash, are recycled as slag and metal in this process as well as energy recovery. Based on this new waste management scheme with a co-gasification system, a case study of municipal solid waste co-gasification was evaluated and compared with other technical solutions, such as conventional incineration, incineration with an ash melting facility under certain boundary conditions. From a technical point of view, co-gasification produced high quality slag with few harmful heavy metals, which was recycled completely without requiring any further post-treatment such as aging. As a consequence, the co-gasification system had an economical advantage over other systems because of its material recovery and minimization of the final landfill amount. Sensitivity analyses of landfill cost, power price and inert materials in waste were also conducted. The higher the landfill costs, the greater the

  1. Heavy element accumulation in Evernia prunastri lichen transplants around a municipal solid waste landfill in central Italy.

    Science.gov (United States)

    Nannoni, Francesco; Santolini, Riccardo; Protano, Giuseppe

    2015-09-01

    This paper presents the results of a biomonitoring study to evaluate the environmental impact of airborne emissions from a municipal solid waste landfill in central Italy. Concentrations of 11 heavy elements, as well as photosynthetic efficiency and cell membrane integrity were measured in Evernia prunastri lichens transplanted for 4months in 17 monitoring sites around the waste landfill. Heavy element contents were also determined in surface soils. Analytical data indicated that emissions from the landfill affected Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn concentrations in lichens transplanted within the landfill and along the fallout direction. In these sites moderate to severe accumulation of these heavy elements in lichens was coupled with an increase in cell membrane damage and decrease in photosynthetic efficiency. Nevertheless, results indicated that landfill emissions had no relevant impact on lichens, as heavy element accumulation and weak stress symptoms were detected only in lichen transplants from sites close to solid waste. The appropriate management of this landfill poses a low risk of environmental contamination by heavy elements.

  2. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste.

    Science.gov (United States)

    Danon-Schaffer, Monica N; Mahecha-Botero, Andrés; Grace, John R; Ikonomou, Michael

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables.

  3. Simulating the heat budget for waste as it is placed within a landfill operating in a northern climate.

    Science.gov (United States)

    Megalla, Dina; Van Geel, Paul J; Doyle, James T

    2016-09-01

    A landfill gas to energy (LFGTE) facility in Ste. Sophie, Quebec was instrumented with sensors which measure temperature, oxygen, moisture content, settlement, total earth pressure, electrical conductivity and mounding of leachate. These parameters were monitored during the operating phase of the landfill in order to better understand the biodegradation and waste stabilization processes occurring within a LFGTE facility. Conceptual and numerical models were created to describe the heat transfer processes which occur within five waste lifts placed over a two-year period. A finite element model was created to simulate the temperatures within the waste and estimate the heat budget over a four and a half year period. The calibrated model was able to simulate the temperatures measured to date within the instrumented waste profile at the site. The model was used to evaluate the overall heat budget for the waste profile. The model simulations and heat budget provide a better understanding of the heat transfer processes occurring within the landfill and the relative impact of the various heat source/sink and storage terms. Aerobic biodegradation appears to play an important role in the overall heat budget at this site generating 36% of the total heat generated within the waste profile during the waste placement stages of landfill operations.

  4. Removal of contaminants in leachate from landfill by waste steel scrap and converter slag.

    Science.gov (United States)

    Oh, Byung-Taek; Lee, Jai-Young; Yoon, Jeyong

    2007-08-01

    This study may be the first investigation to be performed into the potential benefits of recycling industrial waste in controlling contaminants in leachate. Batch reactors were used to evaluate the efficacy of waste steel scrap and converter slag to treat mixed contaminants using mimic leachate solution. The waste steel scrap was prepared through pre-treatment by an acid-washed step, which retained both zero-valent iron site and iron oxide site. Extensive trichloroethene (TCE) removal (95%) occurred by acid-washed steel scrap within 48 h. In addition, dehalogenation (Cl(-) production) was observed to be above 7.5% of the added TCE on a molar basis for 48 h. The waste steel scrap also removed tetrachloroethylene (PCE) through the dehalogenation process although to a lesser extent than TCE. Heavy metals (Cr, Mn, Cu, Zn, As, Cd, and Pb) were extensively removed by both acid-washed steel scrap and converter slag through the adsorption process. Among salt ions (NH (4)(+) , NO (3)(-) , and PO (4)(3-) ), PO (4)(3-) was removed by both waste steel scrap (100% within 8 h) and converter slag (100% within 20 min), whereas NO (3)(-) and NH (4)(+ ) were removed by waste steel scrap (100% within 7 days) and converter slag (up to 50% within 4 days) respectively. This work suggests that permeable reactive barriers (PRBs) with waste steel scrap and converter slag might be an effective approach to intercepting mixed contaminants in leachate from landfill.

  5. Recycling potential of urban solid waste destined for sanitary landfills: the case of Indaiatuba, SP, Brazil.

    Science.gov (United States)

    Mancini, Sandro Donnini; Nogueira, Alex Rodrigues; Kagohara, Dennis Akira; Schwartzman, Jonas Age Saide; de Mattos, Tânia

    2007-12-01

    The urban solid waste of the city of Indaiatuba (pop. 175 000), located in the state of São Paulo, was characterized, focusing on the recycling potential. For this purpose, collected waste was subdivided into 27 items, classified by mass and volume. About 90% of this waste was found to be potentially recyclable and only 10% requiring landfilling. The compostable organic matter, in the form of food and garden waste, both with high moisture content (51 and 41%, respectively), represents 54% in mass and 21% in volume. The most common type of plastic in this waste is high density polyethylene, whose estimated disposal is about 5000kgday(-1). A socio-economic analysis of the waste generation indicates that low-income neighbourhoods discard relatively less packaging and more food waste, shoes and construction debris than middle and high income ones, which may be due to low purchasing power and schooling. Our findings indicate that more aluminium and uncoloured polyethylene terephthalate is discarded in the warmest months of the year, probably due to a greater consumption of canned and bottled drinks.

  6. Urban construction and demolition waste and landfill failure in Shenzhen, China.

    Science.gov (United States)

    Yang, Hong; Xia, Junqiang; Thompson, Julian R; Flower, Roger J

    2017-01-30

    On December 20, 2015 at 11:40 am a landslide in one of China's most advanced cities, Shenzhen, killed 73 people and damaged 33 buildings. In the absence of heavy rainfall or earthquakes, the landslide was an unexpected and profound shock to many people. According to China's Ministry of Land and Resources, the landslide was triggered by the collapse of an enormous pile of construction and demolition waste (CDW). With China's rapid urbanization, an increasing amount of CDW is being generated, especially in major cities. In total, China produces some 30% of the world's municipal solid waste and of this about 40% is CDW. To prevent landslides associated with CDW, the volume of waste dumped in landfills should be regulated. More specifically 4-Rs (reduce, reuse, recycle and recover) policies should be implemented more widely and efficiently. Although landfill will continue to be an important disposal option, proper management and careful monitoring of CDW are urgently needed to satisfy pressing safety issues. International collaboration, sharing of knowledge, and use of the latest technologies are needed so that the similar landslides can be prevented in China and elsewhere.

  7. An attempt to perform water balance in a Brazilian municipal solid waste landfill.

    Science.gov (United States)

    São Mateus, Maria do Socorro Costa; Machado, Sandro Lemos; Barbosa, Maria Cláudia

    2012-03-01

    This paper presents an attempt to model the water balance in the metropolitan center landfill (MCL) in Salvador, Brazil. Aspects such as the municipal solid waste (MSW) initial water content, mass loss due to decomposition, MSW liquid expelling due to compression and those related to weather conditions, such as the amount of rainfall and evaporation are considered. Superficial flow and infiltration were modeled considering the waste and the hydraulic characteristics (permeability and soil-water retention curves) of the cover layer and simplified uni-dimensional empirical models. In order to validate the modeling procedure, data from one cell at the landfill were used. Monthly waste entry, volume of collected leachate and leachate level inside the cell were monitored. Water balance equations and the compressibility of the MSW were used to calculate the amount of leachate stored in the cell and the corresponding leachate level. Measured and calculated values of the leachate level inside the cell were similar and the model was able to capture the main trends of the water balance behavior during the cell operational period.

  8. PERFORMANCE OF NORTH AMERICAN BIOREACTOR LANDFILLS: II. CHEMICAL AND BIOLOGICAL CHARACTERISTICS

    Science.gov (United States)

    The objective of this research was to examine the performance of five North American bioreactor landfills. This paper represents the second of a two part series and addresses biological and chemical aspects of bioreactor performance including gas production and management, and l...

  9. Toxicity of organic chemical pollution in groundwater downgradient of a landfill (Grindsted, Denmark)

    DEFF Research Database (Denmark)

    Baun, Anders; Jensen, S. D.; Bjerg, Poul Løgstrup;

    2000-01-01

    The aim of the present study was to describe the occurrence and distribution of toxicity related to organic chemical contaminants in the leachate plume downgradient of the Grindsted Landfill (Denmark). A total of 27 groundwater samples were preconcentrated by solidphase extraction (SPE) using XAD-2...

  10. Absorption of phosphorus from wastewater by aged refuse excavated from municipal solid waste landfill

    Institute of Scientific and Technical Information of China (English)

    ZHAO You-cai; SHAO Fang

    2005-01-01

    Municipal solid waste(refuse) landfill stabilizes as the refuse degrades. After years of biodegradation, the refuse in the landfill becomes stabilized and aged, which may vary with the local climate, humidity, and composition of refuse placed. In this work, it is found that the refuse with an age of over 8 years at Shanghai Refuse Landfill has been significantly stabilized and sufficiently aged and is thus suitable for excavation. The 8-year old aged refuse is mechanically screened, and the fine fractions of refuse(aged refuse) with a diameter less than 2 cm are then used as a biological absorbent for removal of both inorganic and organic phosphorus in livestock wastewater and prepared aqueous solution. It is proved that the aged refuse is very effective for the quantitative removal of both types of phosphorus. The absorption mechanism is proposed. It is considered that phosphorus is firstly absorbed onto the surface of the aged refuse and then used as a substrate for the growth of microorganisms which ultimately leave the aged refuse as sludge.

  11. Telomere shortening in women resident close to waste landfill sites.

    Science.gov (United States)

    De Felice, Bruna; Nappi, Carmine; Zizolfi, Brunella; Guida, Marco; Di Spiezio Sardo, Attilio; Bifulco, Giuseppe; Guida, Maurizio

    2012-05-25

    Several studies demonstrate links between environmental stress and index of reduced health, including risk factors for cardiovascular disease, reduced immune function and cancer risks. We investigated the hypothesis that pollution, as an environmental stress, impacts health by modulating the rate of cellular aging in healthy pregnant women. Our research looked at the effects that illegal waste sites have on the localized population of pregnant women in Campania, Italy. As is often the case in illegal dumping, the effects on the population are often seen well before knowing what specific agents in the soil and water are responsible. Here we provide evidence that the pollution in this region is significantly associated with higher oxidative stress, shorter telomere length and lower telomerase activity, which are known determinants of cell senescence and aging-related meiotic dysfunction in women, in peripheral blood mononuclear cells from healthy pregnant women, subjected to therapeutic abortion in the second trimester of pregnancy. These findings may have implications for understanding how, at the cellular level, environmental stress may promote earlier onset of age-related diseases.

  12. Assessment of the disposal of radioactive petroleum industry waste in nonhazardous landfills using risk-based modeling.

    Science.gov (United States)

    Smith, Karen P; Arnish, John J; Williams, Gustavious P; Blunt, Deborah L

    2003-05-15

    Certain petroleum production activities cause naturally occurring radioactive materials (NORM) to accumulate in concentrations above natural background levels, making safe and cost-effective management of such technologically enhanced NORM (TENORM) a key issue for the petroleum industry. As a result, both industry and regulators are interested in identifying cost-effective disposal alternatives that provide adequate protection of human health and the environment One such alternative, currently allowed in Michigan with restrictions, is the disposal of TENORM wastes in nonhazardous waste landfills. The disposal of petroleum industry wastes containing radium-226 (Ra-226) in nonhazardous landfills was modeled to evaluate the potential radiological doses and health risks to workers and the public. Multiple scenarios were considered in evaluating the potential risks associated with landfill operations and the future use of the property. The scenarios were defined, in part, to evaluate the Michigan policy; sensitivity analyses were conducted to evaluate the impact of key parameters on potential risks. The results indicate that the disposal of petroleum industry TENORM wastes in nonhazardous landfills in accordance with the Michigan policy and existing landfill regulations presents a negligible risk to most of the potential receptors considered in this study.

  13. Measuring organic carbon, nutrients and heavy metals in rivers receiving leachate from controlled and uncontrolled municipal solid waste (MSW) landfills.

    Science.gov (United States)

    Yusof, N; Haraguchi, A; Hassan, M A; Othman, M R; Wakisaka, M; Shirai, Y

    2009-10-01

    Since landfilling is the common method of waste disposal in Malaysia, river water is greatly exposed to the risk of contamination from leachate unless proper leachate management is carried out. In this study, leachates from three different types of landfills, namely active uncontrolled, active controlled and closed controlled, were characterized, and their relationships with river water chemistry were examined monthly for a year. The influence of leachate on river water chemistry from each type of landfill depended on many factors, including the presence of a leachate control mechanism, leachate characteristics, precipitation, surface runoff and the applied treatment. The impact of leachate from an active uncontrolled landfill was the highest, as the organic content, NH(4)(+)-N, Cd and Mn levels appeared high in the river. At the same time, influences of leachate were also observed from both types of controlled landfills in the form of inorganic nitrogen (NH(4)(+)-N, NO(3)(-)-N and NO(2)(-)-N) and heavy metals (Fe, Cr, Ni and Mn). Improper treatment practice led to high levels of some contaminants in the stream near the closed controlled landfill. Meanwhile, the active controlled landfill, which was located near the coastline, was exposed to the risk of contamination resulting from the pyrite oxidation of the surrounding area.

  14. Environmental impact assessment of leachate recirculation in landfill of municipal solid waste by comparing with evaporation and discharge (EASEWASTE)

    DEFF Research Database (Denmark)

    Xing, Wei; Lu, Wenjing; Zhao, Yan

    2013-01-01

    in leachate and the depositional ammonia from biogas. Moreover, the direct discharge of leachate may also result in ecotoxicity and human toxicity via water contaminated by heavy metals in leachate, with 3.96 PE and 11.64 PE respectively. The results also show that landfill gas is the main contributor...... of contaminants derived from waste can be stored in the landfill for long periods, with 11.69 person equivalent (PE) for stored ecotoxicity in water and 29.62 PE for stored ecotoxicity in soil, considered as potential risks of releasing to the environment someday. Meanwhile, impacts to ecotoxicity and human...... scenarios were modeled using EASEWASTE, comparing the strategies of leachate recirculation (with or without gas management), evaporation and discharge. In the current situation (Scenario A), a total of 280t of waste was generated and then transported to a conventional landfill for disposal. A number...

  15. The Biogeochemistry of Contaminant Groundwater Plumes Arising from Waste Disposal Facilities

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup; Albrechtsen, Hans-Jørgen; Kjeldsen, Peter

    2014-01-01

    Landfills with solid waste are abundant sources of groundwater pollution all over the world. Old uncontrolled municipal landfills are often large, heterogeneous sources with demolition waste, minor fractions of commercial or industrial waste, and organic waste from households. Strongly anaerobic ...... at landfill sites. Finally, the potential chemical or ecological impact from landfills located in former wetlands or near surface water bodies may deserve attention in future studies....

  16. Variation of Coenzyme F420 Activity and Methane Yield in Landfill Simulation of Organic Waste

    Institute of Scientific and Technical Information of China (English)

    CHENG Yun-huan; SANG Shu-xun; HUANG Hua-zhou; LIU Xiao-juan; OUYANG Jin-bao

    2007-01-01

    A simulated landfill anaerobic bioreactor was used to characterize the anaerobic biodegradation and biogas generation of organic waste which was mainly composed of residuals of vegetables and foods. We investigated the dynamics of the coenzyme F420 activity and determined correlations between biogas yields, methane yields, methane concentration and coenzyme F420 activity. The experiment was carried out under different conditions from control without any treatment, addition of Fe3+, microorganism inoculation to a combination of Fe3+ addition and inoculation at a temperature of 36±2 ℃. The experiment was lasted 120 d and coenzyme F420 activity was analyzed using ultraviolet spectrophotometry. Experimental results indicated that activity of the coenzyme F420 treated by Fe3+ and microorganism inoculation increased substantially. The waste treated by inoculation had the greatest increase. When the waste was treated by Fe3+, inoculation and the combination of Fe3+ and inoculation, biogas yields increased by 46.9%, 132.6% and 153.1%, respectively; while the methane yields increased 4, 97 and 98 times. Methane concentration varied between 0 and 6% in the control reactor, from 0 to 14% for waste treated by the addition of Fe3+, from 0 to 59% for waste treated by inoculation and from 0 to 63% for waste treated by Fe3+ addition and inoculation. Correlations between coenzyme F420 activity and biogas production, methane production and methane concentration proved to be positively significant (p<0.05), except for the control. Consequently, coenzyme F420 activity could be used as an index for monitoring the ac-tivity of methanogens during anaerobic biodegradation of the organic fraction of municipal solid waste.

  17. Effect of increasing salinity on biogas production in waste landfills with leachate recirculation: A lab-scale model study.

    Science.gov (United States)

    Ogata, Yuka; Ishigaki, Tomonori; Nakagawa, Mikako; Yamada, Masato

    2016-06-01

    The effects of salinity on anaerobic waste degradation and microbial communities were investigated, in order to propose an appropriate leachate recirculation process in a waste landfill in a tropical region. A salt concentration of 21 mS cm(-1) of electrical conductivity (EC) did not affect waste degradation, but a salt concentration of 35 mS cm(-1) of EC inhibited CH4 generation. A higher salt concentration of 80 mS cm(-1) of EC inhibited not only CH4 and CO2 generation, but also degradation of organic compounds. The bacterial and archaeal community compositions were affected by high salinity. High salinity can exert selective pressure on bacterial communities, resulting in a change in bacterial community structure. Ammonium caused strong, dominant inhibition of biogas production in the salt concentration range of this study. Quality control, especially of ammonium levels, will be essential for the promotion of waste biodegradation in landfills with leachate recirculation.

  18. Degradation of municipal solid waste in simulated landfill bioreactors under aerobic conditions.

    Science.gov (United States)

    Slezak, Radoslaw; Krzystek, Liliana; Ledakowicz, Stanislaw

    2015-09-01

    In this study the municipal solid waste degradation processes in simulated landfill bioreactors under aerobic and anaerobic conditions is investigated. The effect of waste aeration on the dynamics of the aerobic degradation processes in lysimeters as well as during anaerobic processes after completion of aeration is presented. The results are compared with the anaerobic degradation process to determine the stabilization stage of waste in both experimental modes. The experiments in aerobic lysimeters were carried out at small aeration rate (4.41⋅10(-3)lmin(-1)kg(-1)) and for two recirculation rates (24.9 and 1.58lm(-3)d(-1)). The change of leachate and formed gases composition showed that the application of even a small aeration rate favored the degradation of organic matter. The amount of CO2 and CH4 released from anaerobic lysimeter was about 5 times lower than that from the aerobic lysimeters. Better stabilization of the waste was obtained in the aerobic lysimeter with small recirculation, from which the amount of CO2 produced was larger by about 19% in comparison with that from the aerobic lysimeter with large leachate recirculation.

  19. Coal combustion waste management at landfills and surface impoundments 1994-2004.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D.; Ranek, N. L.; Environmental Science Division

    2006-09-08

    On May 22, 2000, as required by Congress in its 1980 Amendments to the Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) issued a Regulatory Determination on Wastes from the Combustion of Fossil Fuels. On the basis of information contained in its 1999 Report to Congress: Wastes from the Combustion of Fossil Fuels, the EPA concluded that coal combustion wastes (CCWs), also known as coal combustion by-products (CCBs), did not warrant regulation under Subtitle C of RCRA, and it retained the existing hazardous waste exemption for these materials under RCRA Section 3001(b)(3)(C). However, the EPA also determined that national regulations under Subtitle D of RCRA were warranted for CCWs that are disposed of in landfills or surface impoundments. The EPA made this determination in part on the basis of its findings that 'present disposal practices are such that, in 1995, these wastes were being managed in 40 percent to 70 percent of landfills and surface impoundments without reasonable controls in place, particularly in the area of groundwater monitoring; and while there have been substantive improvements in state regulatory programs, we have also identified gaps in State oversight' (EPA 2000). The 1999 Report to Congress (RTC), however, may not have reflected the changes in CCW disposal practices that occurred since the cutoff date (1995) of its database and subsequent developments. The U.S. Department of Energy (DOE) and the EPA discussed this issue and decided to conduct a joint DOE/EPA study to collect new information on the recent CCW management practices by the power industry. It was agreed that such information would provide a perspective on the chronological adoption of control measures in CCW units based on State regulations. A team of experts from the EPA, industry, and DOE (with support from Argonne National Laboratory) was established to develop a mutually acceptable approach for collecting and analyzing data

  20. Effect of enzyme additions on methane production and lignin degradation of landfilled sample of municipal solid waste.

    Science.gov (United States)

    Jayasinghe, P A; Hettiaratchi, J P A; Mehrotra, A K; Kumar, Sunil

    2011-04-01

    Operation of waste cells as landfill bioreactors with leachate recirculation is known to accelerate waste degradation and landfill gas generation. However, waste degradation rates in landfill bioreactors decrease with time, with the accumulation of difficult to degrade materials, such as lignin-rich waste. Although, potential exists to modify the leachate quality to promote further degradation of such waste, very little information is available in literature. The objective of this study was to determine the viability of augmenting leachate with enzymes to increase the rate of degradation of lignin-rich waste materials. Among the enzymes evaluated MnP enzyme showed the best performance in terms of methane yield and substrate (lignin) utilization. Methane production of 200 mL CH(4)/g VS was observed for the MnP amended reactor as compared to 5.7 mL CH(4)/g VS for the control reactor. The lignin reduction in the MnP amended reactor and control reactor was 68.4% and 6.2%, respectively.

  1. Olefin Recovery from Chemical Industry Waste Streams

    Energy Technology Data Exchange (ETDEWEB)

    A.R. Da Costa; R. Daniels; A. Jariwala; Z. He; A. Morisato; I. Pinnau; J.G. Wijmans

    2003-11-21

    The objective of this project was to develop a membrane process to separate olefins from paraffins in waste gas streams as an alternative to flaring or distillation. Flaring these streams wastes their chemical feedstock value; distillation is energy and capital cost intensive, particularly for small waste streams.

  2. Carbon pools and flows during lab-scale degradation of old landfilled waste under different oxygen and water regimes

    Energy Technology Data Exchange (ETDEWEB)

    Brandstätter, Christian, E-mail: bran.chri@gmail.com; Laner, David, E-mail: david.laner@tuwien.ac.at; Fellner, Johann, E-mail: johann.fellner@tuwien.ac.at

    2015-06-15

    Graphical abstract: Display Omitted - Highlights: • 40 year old waste from an old MSW landfill was incubated in LSR experiments. • Carbon balances for anaerobic and aerobic waste degradation were established. • The transformation of carbon pools during waste degradation was investigated. • Waste aeration resulted in the formation of a new, stable organic carbon pool. • Water addition did not have a significant effect on aerobic waste degradation. - Abstract: Landfill aeration has been proven to accelerate the degradation of organic matter in landfills in comparison to anaerobic decomposition. The present study aims to evaluate pools of organic matter decomposing under aerobic and anaerobic conditions using landfill simulation reactors (LSR) filled with 40 year old waste from a former MSW landfill. The LSR were operated for 27 months, whereby the waste in one pair was kept under anaerobic conditions and the four other LSRs were aerated. Two of the aerated LSR were run with leachate recirculation and water addition and two without. The organic carbon in the solid waste was characterized at the beginning and at the end of the experiments and major carbon flows (e.g. TOC in leachate, gaseous CO{sub 2} and CH{sub 4}) were monitored during operation. After the termination of the experiments, the waste from the anaerobic LSRs exhibited a long-term gas production potential of more than 20 NL kg{sup −1} dry waste, which corresponded to the mineralization of around 12% of the initial TOC (67 g kg{sup −1} dry waste). Compared to that, aeration led to threefold decrease in TOC (32–36% of the initial TOC were mineralized), without apparent differences in carbon discharge between the aerobic set ups with and without water addition. Based on the investigation of the carbon pools it could be demonstrated that a bit more than 10% of the initially present organic carbon was transformed into more recalcitrant forms, presumably due to the formation of humic substances

  3. Effects of specimen size and mix ratio on the nickel migration behavior of landfill waste mixed mortar.

    Science.gov (United States)

    Haque, M Aminul

    2017-04-01

    Landfill solid waste management system poses the potential source of silent wide-spread heavy metals like nickel poisoning in the entire ecosystem of nearby environment. Nickel containing demolish solid wastes are disposed at landfill zones to a great extent from where nickel migrate into the food chain through the surface water body as well as groundwater. Consequently, nickel exposure may cause different environmental problems. From this sense, it may be an attractive proposal to recycle the waste as a sustainable product. Herein is presented a long-term feasibility study on potential leaching behavioral pattern of nickel from different sizes and mixes based solidified landfill waste mixed mortar block. The calculated results revealed the larger sizes block entrapped more nickel content than the smaller in relation to the available for leaching. Moreover, the specimen bearing the higher amount of waste resulted the significant nickel immobilization within the crystalline structure. The study observed the fixation results 97.72%-99.35%, 97.08%-99.11%, 96.19%-98.58% and 95.86%-91.6% under the stabilizing agent to fine aggregate mixing combination 1:1, 1:1.5, 1:2 and 1:2.5 respectively where 30% of the total volume of fine aggregate was replaced by landfill waste. Although, mechanical strength test of all surrogate waste forms was also conducted that showed acceptable performance for land disposal, the current research pointing out that constructed green products were non-hazardous except the specimens having mixture ratio 1:2.5 because nickel ion release mechanism was observed under this ratio by surface decay or physical erosion of the monolithic matrices. Furthermore, semi-empirical based dominant leaching mechanism models were justified against the goodness of fit statistical parameters for interpreting the experimental observations of nickel transport profile where the adopted models possessed strong potential for predicting Ni content with high accuracy.

  4. Parameter determination of a compression model for landfilled municipal solid waste: an experimental study.

    Science.gov (United States)

    Xu, Xiao Bing; Zhan, Tony Liang Tong; Chen, Yun Min; Guo, Qi Gang

    2015-02-01

    The methods to determine the parameters of a one-dimensional compression model for landfilled municipal solid waste were investigated. In order to test the methods for parameter determination, long-term laboratory compression experiments were carried out under different surcharge loads (i.e. 100, 200 and 400 kPa). Based on the measured compression strain and the reported creep index, the modified primary compression indexes, pre-consolidation pressure and ultimate biodegradation-induced secondary compression strain were determined using the proposed methods. It was found that the simulated compression could not capture the measured secondary compression behavior when using a constant value of biodegradation-induced compression rate coefficient. The variation of the rate coefficient with the change of decomposition rate should be considered during modeling. Accordingly, the biodegradation-induced secondary compression strain in the compression model should be expressed in an incremental form in order to consider the variation of the rate coefficient.

  5. Probabilistic performance-assessment modeling of the mixed waste landfill at Sandia National Laboratories.

    Energy Technology Data Exchange (ETDEWEB)

    Peace, Gerald (Jerry) L. (.); Goering, Timothy James (GRAM, Inc.); Miller, Mark Laverne; Ho, Clifford Kuofei

    2007-01-01

    A probabilistic performance assessment has been conducted to evaluate the fate and transport of radionuclides (americium-241, cesium-137, cobalt-60, plutonium-238, plutonium-239, radium-226, radon-222, strontium-90, thorium-232, tritium, uranium-238), heavy metals (lead and cadmium), and volatile organic compounds (VOCs) at the Mixed Waste Landfill (MWL). Probabilistic analyses were performed to quantify uncertainties inherent in the system and models for a 1,000-year period, and sensitivity analyses were performed to identify parameters and processes that were most important to the simulated performance metrics. Comparisons between simulated results and measured values at the MWL were made to gain confidence in the models and perform calibrations when data were available. In addition, long-term monitoring requirements and triggers were recommended based on the results of the quantified uncertainty and sensitivity analyses.

  6. Critical evaluation of factors required to terminate the postclosure monitoring period at solid waste landfills

    DEFF Research Database (Denmark)

    Barlaz, M.A.; Rooker, A.P.; Kjeldsen, Peter

    2002-01-01

    requirements and regulatory activity that might be required to prepare regulators for the large number of requests to terminate postclosure monitoring expected over the next 20 years. An approach in which the frequency and extent of postclosure monitoring is reduced as warranted by site-specific data......Regulations governing the disposal of solid waste in landfills specify that they must be monitored for 30 years after closure unless this period is extended by the governing regulatory authority. Given the wide range of conditions under which refuse is buried, technical criteria, rather than...... water or groundwater. The acceptability of gaseous releases should be evaluated against criteria for odors, the potential for subsurface migration, and greenhouse gas and ozone precursor emissions. The approach presented here must be tested on a site-specific basis to identify additional data...

  7. Reaction mechanisms and rate constants of waste degradation in landfill bioreactor systems with enzymatic-enhancement.

    Science.gov (United States)

    Jayasinghe, P A; Hettiaratchi, J P A; Mehrotra, A K; Kumar, S

    2014-06-01

    Augmenting leachate before recirculation with peroxidase enzymes is a novel method to increase the available carbon, and therefore the food supply to microorganisms at the declining phase of the anaerobic landfill bioreactor operation. In order to optimize the enzyme-catalyzed leachate recirculation process, it is necessary to identify the reaction mechanisms and determine rate constants. This paper presents a kinetic model developed to ascertain the reaction mechanisms and determine the rate constants for enzyme catalyzed anaerobic waste degradation. The maximum rate of reaction (Vmax) for MnP enzyme-catalyzed reactors was 0.076 g(TOC)/g(DS).day. The catalytic turnover number (k(cat)) of the MnP enzyme-catalyzed was 506.7 per day while the rate constant (k) of the un-catalyzed reaction was 0.012 per day.

  8. Use of disposed waste ash from landfills to replace Portland cement.

    Science.gov (United States)

    Rukzon, Sumrerng; Chindaprasirt, Prinya

    2009-09-01

    In this study, waste ash was utilized as a pozzolanic material in blended Portland cement in order to reduce negative environmental effects and landfill volume required to dispose of waste ash. The influence of waste ash, namely palm oil fuel ash, rice husk ash and fly ash on compressive strength and sulfate resistance in mortar were studied and evaluated by some accelerated short-term techniques in sodium sulfate solutions. Ordinary Portland cement (OPC) was partially replaced with ground palm oil fuel ash (POA), ground rice husk ash (RHA) and classified fly ash (FA). Single pozzolan and a blend of equal weight portions of POA, RHA and FA were also used. The resistance to sulfate attack of mortar improves substantially with partial replacement of OPC with POA, RHA and FA. The use of a blend of equal weight portions of FA and POA or RHA produced mixes with good strength and resistance to sulfate attack. POA, RHA and FA have a high potential to be used as a pozzolanic material.

  9. Management of Conventional Wastes (Non Radioactive) in Spanish Landfills; Gestion de Residuos Convencionales (No Radiactivos) en Vertederos de Espana

    Energy Technology Data Exchange (ETDEWEB)

    Carreras, N.; Pena, J. M.; Ramos, J. L.; Millan, R.

    2011-07-15

    This report is the result of a collaboration agreement between CIEMAT and ENRESA. The goal of the report is to analyze the existing legislation on solid conventional waste, according to the European Community, the Spanish State and its Autonomous Communities, focusing on the latest regulation applicable to the final management in controlled landfills. In addition, information about the legal frame, production, composition and characteristics of conventional waste (i.e. urban, inert, dangerous industrial and non dangerous industrial) is given. Also, the final management that is carried out nowadays in Spain for each of the waste is analyzed and evaluated. Finally, the fulfilment of the in force regulation by the different types of Spanish controlled landfills is evaluated. (Author) 52 refs.

  10. Use of the Geographic Information System and Analytic Hierarchy Process for Municipal Solid Waste Landfill Site Selection: A Case Study of Najafabad, Iran

    Directory of Open Access Journals (Sweden)

    A. Afzali

    2014-03-01

    Full Text Available Following technological advancements and integrated municipal solid waste management in recent decades, various methods such as recycling, biotreatment, thermal treatment, and sanitary landfills have been developed and employed. Creating sanitary landfills is a major strategy in the integrated solid waste management hierarchy. It is cheaper and thus more common than other disposal methods. Selecting a suitable solid waste landfill site can prevent adverse ecological and socioeconomic effects. Landfill site selection requires the analysis of spatial data, regulations, and accepted criteria. The present study aimed to use the geographic information system and the analytic hierarchy process to identify an appropriate landfill site for municipal solid wastes in Najafabad (Isfahan, Iran. Environmental and socioeconomic criteria were evaluated through different information layers in the Boolean and fuzzy logics. The analytical hierarchy process was applied for weighing the fuzzy information layers. Subsequently, two suitable sites were identified by superimposing the maps from the Boolean and fuzzy logics and considering the minimum required landfill area for 20 years. However, proximity of these two sites to Tiran (a nearby city made them undesirable landfill sites for Najafabad. Therefore, due to the existing restrictions in Najafabad, the possibility of creating landfill sites in common with adjacent cities should be further investigated.

  11. Application of continuous normal-lognormal bivariate density functions in a sensitivity analysis of municipal solid waste landfill.

    Science.gov (United States)

    Petrovic, Igor; Hip, Ivan; Fredlund, Murray D

    2016-09-01

    The variability of untreated municipal solid waste (MSW) shear strength parameters, namely cohesion and shear friction angle, with respect to waste stability problems, is of primary concern due to the strong heterogeneity of MSW. A large number of municipal solid waste (MSW) shear strength parameters (friction angle and cohesion) were collected from published literature and analyzed. The basic statistical analysis has shown that the central tendency of both shear strength parameters fits reasonably well within the ranges of recommended values proposed by different authors. In addition, it was established that the correlation between shear friction angle and cohesion is not strong but it still remained significant. Through use of a distribution fitting method it was found that the shear friction angle could be adjusted to a normal probability density function while cohesion follows the log-normal density function. The continuous normal-lognormal bivariate density function was therefore selected as an adequate model to ascertain rational boundary values ("confidence interval") for MSW shear strength parameters. It was concluded that a curve with a 70% confidence level generates a "confidence interval" within the reasonable limits. With respect to the decomposition stage of the waste material, three different ranges of appropriate shear strength parameters were indicated. Defined parameters were then used as input parameters for an Alternative Point Estimated Method (APEM) stability analysis on a real case scenario of the Jakusevec landfill. The Jakusevec landfill is the disposal site of the capital of Croatia - Zagreb. The analysis shows that in the case of a dry landfill the most significant factor influencing the safety factor was the shear friction angle of old, decomposed waste material, while in the case of a landfill with significant leachate level the most significant factor influencing the safety factor was the cohesion of old, decomposed waste material. The

  12. Estimating national landfill methane emissions: an application of the 2006 Intergovernmental Panel on Climate Change Waste Model in Panama.

    Science.gov (United States)

    Weitz, Melissa; Coburn, Jeffrey B; Salinas, Edgar

    2008-05-01

    This paper estimates national methane emissions from solid waste disposal sites in Panama over the time period 1990-2020 using both the 2006 Intergovernmental Panel on Climate Change (IPCC) Waste Model spreadsheet and the default emissions estimate approach presented in the 1996 IPCC Good Practice Guidelines. The IPCC Waste Model has the ability to calculate emissions from a variety of solid waste disposal site types, taking into account country- or region-specific waste composition and climate information, and can be used with a limited amount of data. Countries with detailed data can also run the model with country-specific values. The paper discusses methane emissions from solid waste disposal; explains the differences between the two methodologies in terms of data needs, assumptions, and results; describes solid waste disposal circumstances in Panama; and presents the results of this analysis. It also demonstrates the Waste Model's ability to incorporate landfill gas recovery data and to make projections. The former default method methane emissions estimates are 25 Gg in 1994, and range from 23.1 Gg in 1990 to a projected 37.5 Gg in 2020. The Waste Model estimates are 26.7 Gg in 1994, ranging from 24.6 Gg in 1990 to 41.6 Gg in 2020. Emissions estimates for Panama produced by the new model were, on average, 8% higher than estimates produced by the former default methodology. The increased estimate can be attributed to the inclusion of all solid waste disposal in Panama (as opposed to only disposal in managed landfills), but the increase was offset somewhat by the different default factors and regional waste values between the 1996 and 2006 IPCC guidelines, and the use of the first-order decay model with a time delay for waste degradation in the IPCC Waste Model.

  13. 简析生活垃圾卫生填埋场封场设计%Closure Design of Domestic Waste Sanitary Landfill Sites

    Institute of Scientific and Technical Information of China (English)

    吴健萍

    2011-01-01

    Functions of closure of domestic waste sanitary landfill sites were sketched. Main contents about closure design were analyzed, including landfill pile shaping, structure determining of closure cover system, collection and drainage of landfill gas, and collection and discharge of rainwater in landfill pile.%简述了生活垃圾卫生填埋场封场的作用,分析了封场设计中堆体整形、封场覆盖系统结构的确定、填埋气体的收集导排、垃圾堆体雨水的收集排放等主要内容.

  14. [Effect of operational modes on community structure of type I methanotroph in the cover soil of municipal solid waste landfill].

    Science.gov (United States)

    Yu, Ting; He, Pin-Jing; Lü, Fan; Shao, Li-Ming

    2008-10-01

    Type I methanotroph is crucial for methane oxidization and it responses fast to the changes in environment. In this study, 16S rDNA-based denaturing gradient gel electrophoresis (DGGE) gene fingerprint technology was applied to investigate the effect of operational modes, i. e. high-density polyethylene liner (HDPE) isolation or subsurface irrigation of landfill leachate and vegetation, on community structure and diversity of type I methanotroph in soils covering municipal solid waste landfill. 16S rDNA based phylogenetic analysis reveals type I methanotroph in all tested soils belongs to Methylobacter. According to Shannon-Wiener diversity index and principal component analysis, landfill leachate subsurface irrigation and vegetation have more impact on type I methanotroph community structure and diversity than HDPE liner isolation does, and they reduce type I methanotroph diversity. Leachate irrigation is supposed to inhibit the growth of Methylobacter population. Community structure of type I methanotroph in landfill cover soil isolated by HDPE, i.e. invaded by landfill gas, shifts during long-term gas interference. When cover age is 1.5 years old, Shannon-Wiener diversity index of type I methanotroph reaches its maximum.

  15. Field investigation of the quality of fresh and aged leachates from selected landfills receiving e-waste in an arid climate

    Energy Technology Data Exchange (ETDEWEB)

    Kiddee, Peeranart [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Campus, Adelaide 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Mawson Lakes Campus, Adelaide 5095 (Australia); Naidu, Ravi, E-mail: ravi.naidu@unisa.edu.au [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Campus, Adelaide 5095 (Australia); Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Mawson Lakes Campus, Adelaide 5095 (Australia); Wong, Ming H. [Croucher Institute for Environmental Sciences, Department of Biology, Hong Kong Baptist University, Kowloon Tong, Hong Kong (China); Hearn, Laurence; Muller, Jochen F. [National Research Centre for Environmental Toxicology, The University of Queensland (Australia)

    2014-11-15

    Highlights: • E-waste comprises approximately 6% of the waste mass going to landfill in South Australia. • Significant amounts of metal(loids)s and PBDEs are released from e-waste mixed with municipal solid in landfill leachates. • Significantly elevated concentrations of lead and PBDEs are detected in groundwater wells downgradient of landfills. • Significant temporal variation exists in electrical conductivity and in the concentrations of As, Cd and Pb in leachates. - Abstract: The management of electronic waste (e-waste) is a serious problem worldwide and much of it is landfilled. A survey of four selected landfills in an arid region of South Australia was conducted to determine the proportion of e-waste in municipal waste and the properties of each landfill site. Leachate and groundwater samples were collected upgradient and downgradient of the landfills for analysis of polybrominated diphenyl ethers (PBDEs) and 14 metals and metalloids, including Al, As, Ba, Be, Cd, Co, Cr, Cu, Fe, Ni, Pb, Sb, V and Zn. Our data demonstrate that the selected landfills in South Australia continue to receive municipal waste containing in excess of 6%, or 25,000 tonnes per year, of e-waste. The leachates and groundwater collected from the landfills contained significantly elevated concentrations of Pb with the highest concentration in groundwater of 38 μg/l, almost four times higher than the Australian drinking water guideline of 10 μg/l. The presence of PBDEs was detected in both leachate and groundwater samples. Total PBDEs values of 2.13–59.75 ng/l in leachate samples were 10 times higher than in groundwater samples, which recorded a range of 0.41–6.53 ng/l at all sites. Moreover, the concentrations of metals and metalloids in sampled groundwater contained elevated levels of Al, As, Fe, Ni and Pb that exceeded Australian drinking water guideline values. For these reasons potential leaching of these contaminants is of concern and while difficult to attribute

  16. Test methods to aid in the evaluation of the diversion of biodegradable municipal waste (BMW) from landfill.

    Science.gov (United States)

    Wagland, S T; Tyrrel, S F

    2010-05-01

    This response follows on from a recent discussion by Sánchez (2009) on test methods to aid in the evaluation of the diversion of biodegradable municipal waste (BMW) from landfill. Test methods to assess the biodegradability/biodegradable content of organic waste are of great interest across Europe for different purposes, such as landfill acceptance criteria, monitoring treatment facility performance and for monitoring the diversion of biodegradable municipal waste (BMW) from landfill. Many studies have recently attempted to correlate short-term test methods with long-term anaerobic test methods. This response discusses recent findings and conclusions made by Sánchez (2009) and describes recent work undertaken at Cranfield University to develop the enzymatic hydrolysis test (EHT) method. The EHT has previously shown potential as a short-term, non-biological, biodegradability assessment tool, however there is a requirement to further develop this test method. We conclude that aerobic and anaerobic biological test methods are not the only suitable methods of assessing waste treatment process performance; and that alternative methods such as EHT are feasible and potentially suitable.

  17. SITE SELECTION TO HAZARDOUS WASTE LANDFILL OF GILANEGHARB TOWNSHIP IN KERMANSHAH PROVINCE, WESTERN IRAN BY USING REMOTE SENSING AND GIS

    Directory of Open Access Journals (Sweden)

    MOSLEM HADIDI

    2013-03-01

    Full Text Available Each of them has different effects on site selection of hazardous waste landfill. Some factors cause limits to site selection such as; climatic, topographic, land use, edaphic, quakeable, regions under conservation of environment organization and so on. these factors may be cause unsustainable and move hazardous waste to surface and under ground water and also air pollution according to wind aspect, consequently different contaminations. This study was conducted in Gilanegharb town in Kermanshah province west of Iran in 2012 to find best area of landfill of hazardous wastes. Each of the factors valued and weighted based on experts opinions and then evaluated each of the preperated layers in RS and GIS softwares. In the first evaluation of 19 sites, 6 sites were investigated. The results show that asphalt factory site is the best region and then Shahrdary, Tan Kooshk sites are better to landfill of hazardous waste respectively. The reasons for selecting of this regions were far form surface and ground water resources and as a result avoiding to be defiled of ground water. On the other hand, there is no air pollution and malodorous of Ghilangharb town because of wind blow aspect in the region.

  18. 40 CFR 761.75 - Chemical waste landfills.

    Science.gov (United States)

    2010-07-01

    ... thickness, 4 feet or compacted soil liner thickness, 3 feet; (ii) Permeability (cm/sec), equal to or less... liner in order to provide at least a permeability equivalent to the soils in paragraph (b)(1) of this... underlining and soil cover shall be provided to prevent excessive stress on the liner and to prevent...

  19. Landfill Top Covers

    DEFF Research Database (Denmark)

    Scheutz, Charlotte; Kjeldsen, Peter

    2011-01-01

    is landscaped in order to fit into the surrounding area/environment or meet specific plans for the final use of the landfill. To fulfill the above listed requirements landfill covers are often multicomponent systems which are placed directly on top of the waste. The top cover may be placed immediately after...... the landfill section has been filled or several years later depending on the settlement patterns. Significant differential settlements may disturb the functioning of the top cover. The specific design of the cover system depends on the type of waste landfilled (municipal, hazardous, or inert waste...... however, top covers may be the only environmental protection measure. In some landfill regulations (for instance the Subtitle D landfills receiving municipal solid waste in the USA) it is required to minimize infiltration into the waste layers. Therefore top covers containing liner components...

  20. From waste disposal service to power supplier. A landfill is turned into a futuristic energy farm; Vom Entsorger zum Versorger. Eine Muellkippe wird zum futuristischen Energiepark

    Energy Technology Data Exchange (ETDEWEB)

    Boeckh, Martin

    2011-11-15

    On a landfill operated by the waste disposal utility of the Rhein-Neckar district, an energy farm is currently under construction. Apart from a PV system and landfill gas production, a biomass-fuelled heating power station was recently commissioned. Further plants will follow, i.e. pellets production, power generation by a Wankel engine, and a futuristic plant for pressureless oil production from waste plastics.

  1. Landfilling: Concepts and Challenges

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Scharff, H.; Hjelmar, O.

    2011-01-01

    Landfilling of waste historically has been the main management route for waste, and in many parts of the world it still is. Landfills have developed from open polluting dumps to modern highly engineered facilities with sophisticated control measures and monitoring routines. However, in spite of all...... new approaches and technological advancement the landfill still is a long lasting accumulation of waste in the environment. Much of current landfill design and technology has been introduced as a reaction to problems encountered at actual landfills. The solution was in many cases sought in isolation...... to understand the concepts, the processes and the long-term aspects of landfilling. This chapter describes the main conceptual aspects of landfilling. The historical development is presented and key issues of time frames, mass balances and technical approaches are discussed. The environmental issues...

  2. Physic-chemical evaluation of leach and water from the Borba Gato streamlet within the catchment area of the urban waste landfill of Maringá, Paraná State, Brazil=Avaliação físico-química do lixiviado e da água do ribeirão Borba Gato na área de influência do aterro de resíduos de Maringá, Estado do Paraná, Brasil

    Directory of Open Access Journals (Sweden)

    Carlos de Barros Júnior

    2012-01-01

    Full Text Available The physic-chemical characteristics of leach deposited in the landfill waste pond and of water from the Borba Gato streamlet are evaluated. Twenty-six physic-chemical parameters were analyzed from three collection sites, or rather, two in the streamlet, one upstream (P-01 and one downstream (P-02 of the landfill waste pond, and one in the leach deposit pond (P-03. The streamlet area under analysis was impacted due to being in an agricultural area and for its urban waste deposits. Parameter concentrations of aluminum, iron and mercury were reported above the quality standard of freshwater, according to Conama 357/2005 resolution (class 2. Further, throughout the rainy period, the ammoniac nitrogen content was above the resolution quality standard for fresh water. Moreover, landfill leach was above standards of effluent discharge established by Conama 357/2005. An efficient treatment for the effluent generated in Maringá is required since there is evidence of leach pollution of the Borba Gato streamlet.Este estudo teve como objetivo avaliar as características físico-químicas do lixiviado depositado na lagoa do aterro e da água do ribeirão Borba Gato. Foram analisados 26 parâmetros físico-químicos de três pontos de coletas, dois no ribeirão, a montante (P-01 e a jusante (P-02 do aterro de resíduos, e um na lagoa de depósito de percolado do aterro (P-03. A área do ribeirão estudada se apresentou impactada, por ser uma região agrícola e pela deposição dos resíduos de Maringá. Dentre os parâmetros estudados, registrou-se que, na maioria dos meses, concentrações de alumínio, ferro e mercúrio estavam acima do padrão de qualidade de água doce da resolução do Conama 357/2005 (Classe 2. Além disso, verificou-se que no período chuvoso, P-02 registrou teores de nitrogênio amoniacal acima do padrão de qualidade de água doce da resolução, assim como o lixiviado do aterro apresentou-se acima do padrão do lançamento de

  3. Characteristics of landfill leachates and bio-solids of municipal solid waste (MSW in Riyadh City, Saudi Arabia

    Directory of Open Access Journals (Sweden)

    M.I. Al-Wabel

    2011-06-01

    Full Text Available The liquid and bio-solids (landfill sediments product from landfills has many toxic substances, which may adversely affect on the environmental health. Thus in order to have a better management of characteristics of Riyadh landfill leachates, 80 representative landfill leachate samples were collected and analyzed from February to May 2008. The analysis of landfill leachates includes pH, ECw, concentrations of soluble ions, chemical oxygen demand (COD, total suspended solids (TSS, and heavy metals contents. The obtained results showed that the landfill leachates are characterized by high concentrations of COD (13,900–22,350 mg L−1, TSS of (2280–8912 mg L−1, ECw values of (42.5–58.3 dS m−1 but the pH values ranged 5.49–6.32. Moreover, the leachates had higher concentrations of soluble Na+, K+, Ca2+, Mg2+, Cl−, HCO3- and SO42-. In addition, the leachates contained Fe, Mn, As, Ni, Cr, Zn and Cu in concentrations equivalent to: 104, 11.0, 1.4, 0.6, 0.25, 0.2 and 0.14 mg L−1, respectively. While in the bio-solids (landfill sediments the average content of Cd, Cr, Cu, Fe, Mn, Mo, Ni and V reached to 10, 242, 234, 48,608, 190, 18, 166 and 24 mg kg−1. The relatively higher variations between the upper and lower limits (maximum and minimum values of the studying parameters lead to conclude that it is essential to conduct a long-term monitoring program to obtain representative information and this fluctuation should be considered when operating the leachate treatment plant.

  4. Landfills, Hazardous Waste - WASTE_INDUSTRIAL_IDEM_IN: Industrial Waste Sites in Indiana (Indiana Department of Environmental Management, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — WASTE_INDUSTRIAL_IDEM_IN is a point shapefile that contains industrial waste site locations in Indiana, provided by personnel of Indiana Department of Environmental...

  5. Leachates control in sanitary landfills of urban solid wastes in Gipuzkoa; Control de lixiviados en los vertederos de residuos solidos urbanos de Gipuzkoa

    Energy Technology Data Exchange (ETDEWEB)

    Gomez Martin, M.A.; Antiguedad Auzmendi, I.

    1998-12-01

    The physico-chemical characterization of the leachates from seven sanitary landfills in Gipuzkoa has been studied. Flow rate, temperature and electric conductivity were monitored on line in some cases too. HELP model and other classic methods were applicated to calculate exactly the water balance. The authors conclude suggesting that these studies are essentials to know if the landfills are really sanitary landfills. (Author) 14 refs.

  6. Coal combustion waste management at landfills and surface impoundments 1994-2004.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D.; Ranek, N. L.; Environmental Science Division

    2006-09-08

    On May 22, 2000, as required by Congress in its 1980 Amendments to the Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) issued a Regulatory Determination on Wastes from the Combustion of Fossil Fuels. On the basis of information contained in its 1999 Report to Congress: Wastes from the Combustion of Fossil Fuels, the EPA concluded that coal combustion wastes (CCWs), also known as coal combustion by-products (CCBs), did not warrant regulation under Subtitle C of RCRA, and it retained the existing hazardous waste exemption for these materials under RCRA Section 3001(b)(3)(C). However, the EPA also determined that national regulations under Subtitle D of RCRA were warranted for CCWs that are disposed of in landfills or surface impoundments. The EPA made this determination in part on the basis of its findings that 'present disposal practices are such that, in 1995, these wastes were being managed in 40 percent to 70 percent of landfills and surface impoundments without reasonable controls in place, particularly in the area of groundwater monitoring; and while there have been substantive improvements in state regulatory programs, we have also identified gaps in State oversight' (EPA 2000). The 1999 Report to Congress (RTC), however, may not have reflected the changes in CCW disposal practices that occurred since the cutoff date (1995) of its database and subsequent developments. The U.S. Department of Energy (DOE) and the EPA discussed this issue and decided to conduct a joint DOE/EPA study to collect new information on the recent CCW management practices by the power industry. It was agreed that such information would provide a perspective on the chronological adoption of control measures in CCW units based on State regulations. A team of experts from the EPA, industry, and DOE (with support from Argonne National Laboratory) was established to develop a mutually acceptable approach for collecting and analyzing data

  7. Utilisation of chemically stabilized arsenic-contaminated soil in a landfill cover.

    Science.gov (United States)

    Kumpiene, Jurate; Desogus, Paolo; Schulenburg, Sven; Arenella, Mariarita; Renella, Giancarlo; Brännvall, Evelina; Lagerkvist, Anders; Andreas, Lale; Sjöblom, Rolf

    2013-12-01

    The aim of the study was to determine if an As-contaminated soil, stabilized using zerovalent iron (Fe(0)) and its combination with gypsum waste, coal fly ash, peat, or sewage sludge, could be used as a construction material at the top layer of the landfill cover. A reproduction of 2 m thick protection/vegetation layer of a landfill cover using a column setup was used to determine the ability of the amendments to reduce As solubility and stimulate soil functionality along the soil profile. Soil amendment with Fe(0) was highly efficient in reducing As in soil porewater reaching 99 % reduction, but only at the soil surface. In the deeper soil layers (below 0.5 m), the Fe treatment had a reverse effect, As solubility increased dramatically exceeding that of the untreated soil or any other treatment by one to two orders of magnitude. A slight bioluminescence inhibition of Vibrio fischeri was detected in the Fe(0) treatment. Soil amendment with iron and peat showed no toxicity to bacteria and was the most efficient in reducing dissolved As in soil porewater throughout the 2 m soil profile followed by iron and gypsum treatment, most likely resulting from a low soil density and a good air diffusion to the soil. The least suitable combination of soil amendments for As immobilization was a mixture of iron with coal fly ash. An increase in all measured enzyme activities was observed in all treatments, particularly those receiving organic matter. For As to be stable in soil, a combination of amendments that can keep the soil porous and ensure the air diffusion through the entire soil layer of the landfill cover is required.

  8. Aerobic landfill bioreactor

    Science.gov (United States)

    Hudgins, Mark P; Bessette, Bernard J; March, John; McComb, Scott T.

    2000-01-01

    The present invention includes a method of decomposing municipal solid waste (MSW) within a landfill by converting the landfill to aerobic degradation in the following manner: (1) injecting air via the landfill leachate collection system (2) injecting air via vertical air injection wells installed within the waste mass; (3) applying leachate to the waste mass using a pressurized drip irrigation system; (4) allowing landfill gases to vent; and (5) adjusting air injection and recirculated leachate to achieve a 40% to 60% moisture level and a temperature between 120.degree. F. and 140.degree. F. in steady state.

  9. Migration of nitrate, nitrite, and ammonia through the municipal solid waste incinerator bottom ash layer in the simulated landfill.

    Science.gov (United States)

    Yao, Jun; Chen, Luxi; Zhu, Huayue; Shen, Dongsheng; Qiu, Zhanhong

    2017-03-09

    Simulated landfill was operated for 508 days to investigate the effect of municipal solid waste incinerator (MSWI) bottom ash layer on the migration of nitrate, nitrite, and ammonia when it was used as the intermediate layer in the landfill. The result suggested that the MSWI bottom ash layer could capture the nitrate, nitrite, and ammonia from the leachate. The adsorption of the nitrate, nitrite, and ammonia on the MSWI bottom ash layer was saturated at the days 396, 34, and 97, respectively. Afterwards, the nitrogen species were desorbed from the MSWI bottom ash layer. Finally, the adsorption and desorption could reach the equilibrium. The amounts of adsorbed nitrate and nitrite on the MSWI bottom ash layer were 1685.09 and 7.48 mg, respectively, and the amount of the adsorbed and transformed ammonia was 13,773.19 mg, which was much higher than the desorbed. The water leaching test and synthetic precipitation leaching procedure (SPLP) results showed that the leachable nitrate, nitrite, and ammonia in the MSWI bottom ash were greatly increased after the landfill operation, suggesting that the adsorbed nitrogen could be finally leached out. Besides, the results also showed that MSWI bottom ash layer could affect the release of nitrate and ammonia at the initial stage of the landfill. However, it had little effect on the release of nitrite.

  10. Affinity of titanium dioxide nanoparticles for sodium montmorillonite clay: Implications for disposal in municipal solid waste landfills

    Science.gov (United States)

    Harns, Carrie

    Manufactured nanomaterials are used in a diverse array of commercially available products. Like other consumer goods, a portion of manufactured nano-products will enter municipal solid waste (MSW) landfills. Currently there is little information on the behavior and fate of engineered nanomaterials in MSW landfills and thus we do not know if current landfill designs are suitable for engineered nanomaterials. Of great consequence is understanding how nanomaterials will interact with clays, as they are integral components of composite liner systems. The overall objectives were to determine the affinity of titanium dioxide (TiO2) nanomaterials for montmorillonite as a function of solution chemistry and evaluate the mobility of TiO2 nanomaterials across clay barriers. It was observed that under favorable electrostatic conditions, TiO2 will heteroaggregate with montmorillonite, and TiO2-montmorillonite suspensions will remain stable under unfavorable electrostatic conditions. Additionally, it was observed that under simplified landfill leachate conditions, the clay barrier retained TiO2.

  11. GIS-based multicriteria municipal solid waste landfill suitability analysis: a review of the methodologies performed and criteria implemented.

    Science.gov (United States)

    Demesouka, O E; Vavatsikos, A P; Anagnostopoulos, K P

    2014-04-01

    Multicriteria spatial decision support systems (MC-SDSS) have emerged as an integration of the geographical information systems (GIS) and multiple criteria decision analysis (MCDA) methods. GIS-based MCDA allows the incorporation of conflicting objectives and decision maker (DM) preferences into spatial decision models. During recent decades, a variety of research articles have been published regarding the implementation of methods and/or tools in a variety of real-world case studies. The article discusses, in detail, the criteria and methods that are implemented in GIS-based landfill siting suitability analysis and especially the exclusionary and non-exclusionary criteria that can be considered when selecting sites for municipal solid waste (MSW) landfills. This paper reviews 36 seminal articles in which the evaluation of candidate landfill sites is conducted using MCDA methods. After a brief description of the main components of a MC-SDSS and the applied decision rules, the review focuses on the criteria incorporated into the decision models. The review provides a comprehensive guide to the landfill siting analysis criteria, providing details regarding the utilization methods, their decision or exclusionary nature and their monotonicity.

  12. Cultural Resources Review for Closure of the nonradioactive Dangerous Waste Landfill and Solid Waste Landfill in the 600 Area, Hanford Site, Benton County, Washington, HCRC# 2010-600-018R

    Energy Technology Data Exchange (ETDEWEB)

    Gutzeit, Jennifer L.; Kennedy, Ellen P.; Bjornstad, Bruce N.; Sackschewsky, Michael R.; Sharpe, James J.; DeMaris, Ranae; Venno, M.; Christensen, James R.

    2011-02-02

    The U.S. Department of Energy Richland Operations Office is proposing to close the Nonradioactive Dangerous Waste Landfill (NRDWL) and Solid Waste Landfill (SWL) located in the 600 Area of the Hanford Site. The closure of the NRDWL/SWL entails the construction of an evapotranspiration cover over the landfill. This cover would consist of a 3-foot (1-meter) engineered layer of fine-grained soil, modified with 15 percent by weight pea gravel to form an erosion-resistant topsoil that will sustain native vegetation. The area targeted for silt-loam borrow soil sits in Area C, located in the northern central portion of the Fitzner/Eberhardt Arid Lands Ecology (ALE) Reserve Unit. The pea gravel used for the mixture will be obtained from both off-site commercial sources and an active gravel pit (Pit #6) located just west of the 300 Area of the Hanford Site. Materials for the cover will be transported along Army Loop Road, which runs from Beloit Avenue (near the Rattlesnake Barricade) east-northeast to the NRDWL/SWL, ending at State Route 4. Upgrades to Army Loop Road are necessary to facilitate safe bidirectional hauling traffic. This report documents a cultural resources review of the proposed activity, conducted according to Section 106 of the National Historic Preservation Act of 1966.

  13. Size charge fractionation of metals in municipal solid waste landfill leachate.

    Science.gov (United States)

    Oygard, Joar Karsten; Gjengedal, Elin; Røyset, Oddvar

    2007-01-01

    Municipal solid waste landfill leachates from 9 Norwegian sites were size charge fractionated in the field, to obtain three fractions: particulate and colloidal matter >0.45microm, free anions/non-labile complexes 0.45microm. Cr, Co and Ni were on the contrary present mostly as non-labile complexes (69-79%) 0.45microm. The particulate and colloidal matter >0.45microm was mainly inorganic; indicating that the metals present in this fraction were bound as inorganic compounds. The fractionation gives important information on the mobility and potential bioavailability of the metals investigated, in contrast to the total metal concentrations usually reported. To study possible changes in respective metal species in leachate in aerated sedimentation tanks, freshly sampled leachate was stored for 48h, and subsequently fractionated. This showed that the free heavy metals are partly immobilized during storage of leachate with oxygen available. The largest effects were found for Cd and Zn. The proportion of As and Cr present as particulate matter or colloids >0.45microm also increased.

  14. Greenhouse gas emissions from two-stage landfilling of municipal solid waste

    Science.gov (United States)

    Zhang, Yuanyuan; Yue, Dongbei; Nie, Yongfeng

    2012-08-01

    Simulations were conducted to investigate greenhouse gas emissions from aerobic pretreatment and subsequent landfilling. The flows in carbon balance, such as gas, leachate, and solid phases, were considered in the simulations. The total amount of CO2 eq. decreased as organic removal efficiency (ORE) increased. At ORE values of 0, 0.30, 0.41, and 0.54, the total amounts of CO2 eq. were 2614, 2326, 2075, and 1572 kg CO2 eq. per one ton dry matter, respectively; gas accounted for the main contribution to the total amount. The reduction in CO2 eq. from leachate was the primary positive contribution, accounting for 356%, 174%, and 100% of total reduction at ORE values of 0.30, 0.41, and 0.54, respectively. The CO2 eq. from energy consumption was the negative contribution to total reduction, but this contribution is considerably lower than that from gas. Aerobic pretreatment shortened the lag time of biogas production by 74.1-97.0%, and facilitated the transfer of organic carbon in solid waste from uncontrolled biogas and highly polluting leachate to aerobically generated CO2.

  15. Performance evaluation of an anaerobic/aerobic landfill-based digester using yard waste for energy and compost production.

    Science.gov (United States)

    Yazdani, Ramin; Barlaz, Morton A; Augenstein, Don; Kayhanian, Masoud; Tchobanoglous, George

    2012-05-01

    The objective of this study was to evaluate a new alternative for yard waste management by constructing, operating and monitoring a landfill-based two-stage batch digester (anaerobic/aerobic) with the recovery of energy and compost. The system was initially operated under anaerobic conditions for 366 days, after which the yard waste was aerated for an additional 191 days. Off gas generated from the aerobic stage was treated by biofilters. Net energy recovery was 84.3MWh, or 46kWh per million metric tons of wet waste (as received), and the biochemical methane potential of the treated waste decreased by 83% during the two-stage operation. The average removal efficiencies of volatile organic compounds and non-methane organic compounds in the biofilters were 96-99% and 68-99%, respectively.

  16. Chemical Stabilization of Hanford Tank Residual Waste

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  17. Chemical stabilization of Hanford tank residual waste

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, Kirk J., E-mail: kirk.cantrell@pnnl.gov [Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy [Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Lukens, Wayne W. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Buck, Edgar C.; Mausolf, Edward J. [Pacific Northwest National Laboratory, Richland, WA 99352 (United States)

    2014-03-15

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH){sub 2}], an in situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and Ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of uranium from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. All three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective Maximum Contaminant Levels (MCLs) for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  18. MICROBIAL POPULATIONS AND MOISTURE CONTENT IN A CONVENTIONALLY OPERATED MUNICIPAL SOLID WASTE LANDFILL

    Science.gov (United States)

    Landfills are not sterile environments. In fact it can be argued that they are the ultimate reactors for biodegradation as they contain nutrients, bacteria, and various redox conditions which, then, change over time. Enhancement of the landfill environment to optimize the rates o...

  19. EFFECT OF SEALED MUNICIPAL WASTE LANDFILL ON THE QUALITY OF UNDERGROUND WATER

    Directory of Open Access Journals (Sweden)

    Elżbieta Halina Grygorczuk-Petersons

    2016-01-01

    Full Text Available The aim of the study was to evaluate the impact of the landfill on the groundwater environment. The assessment of water status in the region of landfill sealed with a layer of clay with a thickness of 0.5 m, was based on the own research and monitoring received from the municipal office, and conducted in 2007–2010. Waters flowing out of the landfill revealed an increase in pollution indicators such as: total organic carbon (TOC, concentrations of PAHs and heavy metals including zinc, cadmium, and chromium. It was demonstrated that the landfill sealed with a clay layer does not reduce the outflow of leachate to groundwater, but also that the purity of these waters is influenced by increased agricultural activity in the areas adjacent to the landfill.

  20. Effect of increasing salinity on biogas production in waste landfills with leachate recirculation: A lab-scale model study

    Directory of Open Access Journals (Sweden)

    Yuka Ogata

    2016-06-01

    Full Text Available The effects of salinity on anaerobic waste degradation and microbial communities were investigated, in order to propose an appropriate leachate recirculation process in a waste landfill in a tropical region. A salt concentration of 21 mS cm−1 of electrical conductivity (EC did not affect waste degradation, but a salt concentration of 35 mS cm−1 of EC inhibited CH4 generation. A higher salt concentration of 80 mS cm−1 of EC inhibited not only CH4 and CO2 generation, but also degradation of organic compounds. The bacterial and archaeal community compositions were affected by high salinity. High salinity can exert selective pressure on bacterial communities, resulting in a change in bacterial community structure. Ammonium caused strong, dominant inhibition of biogas production in the salt concentration range of this study. Quality control, especially of ammonium levels, will be essential for the promotion of waste biodegradation in landfills with leachate recirculation.

  1. The health impact of nonhazardous solid waste disposal in a community: the case of the Mare Chicose landfill in mauritius.

    Science.gov (United States)

    Goorah, Smita Sulackshana Devi; Esmyot, Mary Libera Isabelle; Boojhawon, Ravindra

    2009-01-01

    The disposal of nonhazardous solid waste on the island of Mauritius is centered on the Mare Chicose landfill. Because of health concerns in the community, the authors conducted a health impact survey, took measurements of height and weight, and compared the results with a control locality. After adjusting for confounding factors, the authors observed that numerous complaints were significantly higher in the target population. After elimination of reporting bias, however, nausea and vomiting remained as the only significant self-reported outcomes. The mean body mass index (BMI) of target men was significantly lower when compared with the control. This result was not observed in the populations of women and children, and suggests a gender difference in the health impact of the landfill.

  2. Greenhouse gas accounting of the proposed landfill extension and advanced incineration facility for municipal solid waste management in Hong Kong

    Energy Technology Data Exchange (ETDEWEB)

    Woon, K.S.; Lo, Irene M.C., E-mail: cemclo@ust.hk

    2013-08-01

    The burgeoning of municipal solid waste (MSW) disposal issue and climate change have drawn massive attention from people. On the one hand, Hong Kong is facing a controversial debate over the implementation of proposed landfill extension (LFE) and advanced incineration facility (AIF) to curb the MSW disposal issue. On the other hand, the Hong Kong Special Administrative Region Government is taking concerted efforts to reduce the carbon intensity in this region. This paper discusses the greenhouse gas (GHG) emissions from four proposed waste disposal scenarios, covering the proposed LFE and AIF within a defined system boundary. On the basis of the data collected, assumptions made, and system boundary defined in this study, the results indicate that AIF releases less GHG emissions than LFE. The GHG emissions from LFE are highly contributed by the landfill methane (CH{sub 4}) emissions but offset by biogenic carbon storage, while the GHG emissions from AIF are mostly due to the stack discharge system but offset by the energy recovery system. Furthermore, parametric sensitivity analyses show that GHG emissions are strongly dependent on the landfill CH{sub 4} recovery rate, types of electricity displaced by energy recovery systems, and the heating value of MSW, altering the order of preferred waste disposal scenarios. This evaluation provides valuable insights into the applicability of a policy framework for MSW management practices in reducing GHG emissions. Highlights: • AIF is better than LFE with regard to GHG emissions in Hong Kong. • Major individual sub-processes of LFE and AIF for GHG emissions are investigated. • GHG emissions for LFE and AIF are strongly dependent on studied parametric sensitivity analyses. • Findings are valuable for sustainable MSW management and GHG reductions in waste sector.

  3. Chemical stabilization of Hanford tank residual waste

    Science.gov (United States)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and Ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of uranium from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. All three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective Maximum Contaminant Levels (MCLs) for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste.

  4. UV—Catalytic Treatment of Municipal Solid—Waste Landfill Leachate with Hydrogen Peroxide and Ozone Oxidation

    Institute of Scientific and Technical Information of China (English)

    TahirImranQURESHI; Hong-TaeKIM; 等

    2002-01-01

    Theperformance of UV/H2O2,UV/O3,and UV/H2O2/O3 oxidation systems for the treatment of municipal solid-waste landfill leachate was investigated. Main objective of the experiment was to remove total organic carbon(TOC),non-biodegradable organic compounds (NBDOC) and color.In UV/H2O2 oxidation experiment, with the increase of H2O2 dosage,removal efficiencies of TOC and color along with the ratio of biochemical oxygen demand(BOD) to chemical oxygen demand (COD) of the effluent were increased and a better performance was obtained than the system H2O2 alone. In UV/H2O2 oxidation,under the optimum condition H2O2(0.2time),removal efficiencies of TOC and color were 78.9% and 95.5%, respectively,and BOD/COD ratio was significantly increased from 0.112 to 0.366.In UV/O3 oxidation,with the increase of O3 dosage,removal efficiencies of TOC and color along with BOD/COD ratio of the effluent were increased and a beter performance was obtained than the system O3 alone.Under the optimum condition UV/O3(50mg·min-1),removal efficiencies of TOC and color were 61.0% and 87.2%,respectively,and BOD/COD ratio was significantly increased from 0.112 to 0.323. In UV/H2O2/O3 system,color removal and BOD/COD ratio were improved further and TOC removal efficiency was found to be 30.4% higher than the system UV/O3 without H2O2.

  5. Solid waste disposal in the soil: effects on the physical, chemical, and organic properties of soil

    Directory of Open Access Journals (Sweden)

    Vanessa Regina Lasaro Mangieri

    2015-04-01

    Full Text Available Currently, there is growing concern over the final destination of the solid waste generated by society. Landfills should not be considered the endpoint for substances contained or generated in solid waste. The sustainable use of natural resources, especially soil and water, has become relevant, given the increase in anthropogenic activities. Agricultural use is an alternative to solid waste (leachate, biosolid disposal, considering the hypothesis that the agricultural use of waste is promising for reducing waste treatment costs, promoting nutrient reuse and improving the physical and chemical conditions of soil. Thus, this literature review, based on previously published data, seeks to confirm or disprove the hypothesis regarding the promising use of solid waste in agriculture to decrease the environmental liability that challenges public administrators in the development of efficient management. The text below addresses the following subtopics after the introduction: current solid waste disposal and environmental issues, the use of solid waste in agriculture, and the effect on the physical and chemical properties of soil and on organic matter, ending with final considerations.

  6. A logistic model for the prediction of the influence of water on the solid waste methanization in landfills.

    Science.gov (United States)

    Pommier, S; Chenu, D; Quintard, M; Lefebvre, X

    2007-06-15

    This article deals with the impact of water content of solid waste on biogas production kinetics in landfills. This impact has been proved in the laboratory thanks to anaerobic biodegradation experiments on paper/cardboard waste samples. A strong dependence with the moisture level was observed for both kinetic rates and maximum methane production. In this article, a logistic model is proposed to simulate the biogas production rate. It is chosen as simple as possible in order to allow for a correct identification of the model parameters given the experimental data available. The moisture dependency is introduced through a linear weighing of the biomass specific growth rate and of the amount of accessible organic substrate. It is directly linked to physical properties of the waste: the holding capacity and the minimal moisture level allowing the presence of free water.

  7. Performance and completion assessment of an in-situ aerated municipal solid waste landfill - Final scientific documentation of an Austrian case study.

    Science.gov (United States)

    Hrad, Marlies; Huber-Humer, Marion

    2016-08-23

    By converting anaerobic landfills into a biologically stabilized state through accelerating aerobic organic matter degradation, the effort and duration necessary for post-closure procedures can be shortened. In Austria, the first full-scale application of in-situ landfill aeration by means of low pressure air injection with simultaneous off-gas collection and treatment was implemented on an old MSW-landfill and operated between 2007 and 2013. Besides complementary laboratory investigations, which included waste sampling from the landfill site prior to aeration start, a comprehensive field monitoring program was conducted to assess the influence of the aeration measure on the emission behavior of the landfilled waste during the aeration period as well as after aeration completion. Although the initial waste material was described as rather stable, the lab-scale aeration tests indicated a significant improvement of the leachate quality and even the biological solid waste stability. However, the aeration success was less pronounced for the application at the landfill site, mainly due to technical limitations in the full-scale operation. In this paper main performance data of the field investigation are compared to four other scientifically documented case studies along with stability indicators for solid waste and leachate characteristics in order to evaluate the success of aeration as well as the progress of a landfill towards completion and end of post-closure care. A number of quantitative benchmarks and relevant context information for the performance assessment of the five hitherto conducted international aeration projects are proposed aiming to support the systematization and harmonization of available results from diverse field studies and full-scale applications in future.

  8. Significance analysis of the leachate level in a solid waste landfill in a coastal zone using total water balance and slope stability alternatives

    Energy Technology Data Exchange (ETDEWEB)

    Koo, Ja-Kong; Do, Nam-Young [Korea Advanced Institute of Science & Technology, Taejon (Korea, Republic of)

    1996-12-31

    The K site near Seoul began landfilling in 1992. The landfilled wastes include municipal solid waste (66.4%), construction residues (20.4%), water and wastewater sludges (trace levels), and hazardous waste (trace levels). The water content of the municipal solid waste is very high (47.3%); as a result, the leachate level (average E.L.) of the landfill, the design value of which is 7.0 m, was measured at 10.3 m in January 1995 and is increasing. The increase of leachate level in the landfill site causes a problem with slope stability. The leachate level at each disposal stage divided by the intermediate cover layer was calculated with the HELP (Hydrologic Evaluation of Landfill Performance) model and calibrated with the data measured from February 1993 to June 1995. Also, the hydraulic conductivities of the waste layer and the intermediate cover layer in each stage were calibrated continuously with HELP model analysis. To verify these results, the total water balance in the landfill site was calculated using the infiltration rate calculated from HELP modeling. The leachate level was E.L. 10.0 m, which was close to the measured leachate level. To estimate the change of the leachate level in the future, the total water balances with different leachate discharge rates of 3,000, 3,500, and 5,000 m{sup 3}/day were analyzed. When the leachate discharge rate was 5,000 ton/day and the initial water content was decreased below 25%, the average leachate level was 10.8 m. This result satisfies the safety factor requirements (=1.3) for landfill slope stability. 4 refs., 8 figs., 1 tab.

  9. Landfill leachate treatment in assisted landfill bioreactor

    Institute of Scientific and Technical Information of China (English)

    HE Pin-jing; QU Xian; SHAO Li-ming; LEE Duu-jong

    2006-01-01

    Landfill is the major disposal route of municipal solid waste(MSW) in most Asian countries. Leachate from landfill presents a strong wastewater that needs intensive treatment before discharge. Direct recycling was proposed as an effective alternative for leachate treatment by taking the landfill as a bioreactor. This process was proved not only considerably reducing the pollution potential of leachate, but also enhancing organic degradation in the landfill. However, as this paper shows, although direct leachate recycling was effective in landfilled MSW with low food waste fraction (3.5%, w/w), it failed in MSW containing 54% food waste, as normally noted in Asian countries. The initial acid stuck would inhibit methanogenesis to build up, hence strong leachate was yielded from landfill to threaten the quality of receiving water body. We demonstrated the feasibility to use an assisted bioreactor landfill, with a well-decomposed refuse layer as ex-situ anaerobic digester to reducing COD loading in leachate. By doing so, the refuse in simulated landfill column (2.3 m high) could be stabilized in 30 weeks while the COD in leachate reduced by 95%(61000 mg/L to 3000 mg/L). Meanwhile, the biogas production was considerably enhanced, signaling by the much greater amount and much higher methane content in the biogas.

  10. Leachate and Pollution Levels of Heavy Metals in the Groundwater near Municipal Solid Waste Landfill Site of Mashhad, Iran

    Directory of Open Access Journals (Sweden)

    Borhan Mansouri

    2014-06-01

    Full Text Available Background: The purpose of this study is to investigate the concentration of metals (lead, cadmium, chromium, copper, and nickel in the landfill leachate and heavy metals in wells downstream of municipal solid waste landfill site in the city of Mashhad. Methods: In both winter and summer seasons in 2009 samples were collected from five wells that were in landfill downstream in Mashhad. Results: Among heavy metals, nickel concentration in summer and lead concentration in winter had the highest levels. The results showed that the mean concentration of heavy metals in the studied wells was below the national standards of drinking water of Iran, WHO, and the United States. Pearson correlation coefficients also indicated that there was a significant correlation among the studied metals in the wells. Conclusion: Cd and Cu concentrations in all of the wells (except Pb in winter and Ni in summer did not pose any significant water quality problems since these concentrations were below the standards acceptable levels of drinking water.

  11. SITE SELECTION OF MUNICIPAL SOLID WASTE LANDFILLS USING ANALYTICAL HIERARCHY PROCESS METHOD IN A GEOGRAPHICAL INFORMATION TECHNOLOGY ENVIRONMENT IN GIROFT

    Directory of Open Access Journals (Sweden)

    H. Javaheri, T. Nasrabadi, M. H. Jafarian, G. R. Rowshan, H. Khoshnam

    2006-07-01

    Full Text Available Municipal solid waste generation is among the most significant sources which threaten the global environmental health. As an ideal selection depends on considering several independent factors concerning land use, socio economy and hydrogeology, the use of a multi criteria evaluation method seems inevitable. Taking benefit of geographic information system as a tool in combination with geographical information technology, equips the spatial decision support systems in appropriate site selection of sanitary landfills. The present study involves a kind of multi criteria evaluation method under the name of weighted linear combination by using geographical information technology as a practical instrument to evaluate the suitability of the vicinity of Giroft city in Kerman province of Iran for landfill. Water permeability, slope, distance from rivers, depth of underground watertable, distance from residential areas, distance from generation centers, general environmental criterion and distance from roads are the criteria which have been taken in to consideration in the process of analyzing. Superposing all of the raster type layers including geomorphologic, hydrologic, humanistic and land use criteria in land suitability, the final zoning of appropriate, fairly appropriate and inappropriate districts have been identified. Considering relative priority of all criteria in comparison with others, a specific weight is designated to each criterion according to their total influence on the whole process of decision making. The results from the application of the presented methodology are zones for landfill with varying zonal land suitability. Finally the zones will be ranked in descending order to indicate the priority of different options in front of the eyes of decision makers. The results achieved by this study may help policy makers of Giroft city by a variety of options for being considered as sanitary landfill locations.

  12. Heat budget for a waste lift placed under freezing conditions at a landfill operated in a northern climate.

    Science.gov (United States)

    Bonany, James E; Van Geel, Paul J; Burak Gunay, H; Burkan Isgor, O

    2013-05-01

    A landfill operated in Ste. Sophie, Québec, Canada was instrumented to better understand the waste stabilization process in northern climates. Instrument bundles were placed within the waste to monitor temperature, settlement, oxygen, moisture content, total load, mounding of leachate and electrical conductivity. A finite element model was developed to simulate the heat budget for the first waste lift placed in the winter months and was calibrated using the first 10.5 months of collected temperature data. The calibrated model was then used to complete a sensitivity analysis for the various parameters that impact the heat budget. The results of the analysis indicated that the heat required for phase change to thaw the liquid fraction within frozen waste had a significant impact on the heat budget causing sections of waste to remain frozen throughout the simulation period. This was supported by the data collected to date at Ste. Sophie and by other researchers indicating that frozen waste placed during the winter months can remain frozen for periods in access of 1.5 years.

  13. Chemical hazards associated with treatment of waste electrical and electronic equipment.

    Science.gov (United States)

    Tsydenova, Oyuna; Bengtsson, Magnus

    2011-01-01

    This review paper summarizes the existing knowledge on the chemical hazards associated with recycling and other end-of-life treatment options of waste electrical and electronic equipment (e-waste). The hazards arise from the presence of heavy metals (e.g., mercury, cadmium, lead, etc.), flame retardants (e.g., pentabromophenol, polybrominated diphenyl ethers (PBDEs), tetrabromobisphenol-A (TBBPA), etc.) and other potentially harmful substances in e-waste. If improperly managed, the substances may pose significant human and environmental health risks. The review describes the potentially hazardous content of e-waste, examines the existing e-waste management practices and presents scientific data on human exposure to chemicals, workplace and environmental pollution associated with the three major e-waste management options, i.e., recycling, incineration and landfilling. The existing e-waste management practices and associated hazards are reviewed separately for developed and developing countries. Finally, based on this review, the paper identifies gaps in the existing knowledge and makes some recommendations for future research.

  14. Field investigation of the quality of fresh and aged leachates from selected landfills receiving e-waste in an arid climate.

    Science.gov (United States)

    Kiddee, Peeranart; Naidu, Ravi; Wong, Ming H; Hearn, Laurence; Muller, Jochen F

    2014-11-01

    The management of electronic waste (e-waste) is a serious problem worldwide and much of it is landfilled. A survey of four selected landfills in an arid region of South Australia was conducted to determine the proportion of e-waste in municipal waste and the properties of each landfill site. Leachate and groundwater samples were collected upgradient and downgradient of the landfills for analysis of polybrominated diphenyl ethers (PBDEs) and 14 metals and metalloids, including Al, As, Ba, Be, Cd, Co, Cr, Cu, Fe, Ni, Pb, Sb, V and Zn. Our data demonstrate that the selected landfills in South Australia continue to receive municipal waste containing in excess of 6%, or 25,000 tonnes per year, of e-waste. The leachates and groundwater collected from the landfills contained significantly elevated concentrations of Pb with the highest concentration in groundwater of 38 μg/l, almost four times higher than the Australian drinking water guideline of 10 μg/l. The presence of PBDEs was detected in both leachate and groundwater samples. Total PBDEs values of 2.13-59.75 ng/l in leachate samples were 10 times higher than in groundwater samples, which recorded a range of 0.41-6.53 ng/l at all sites. Moreover, the concentrations of metals and metalloids in sampled groundwater contained elevated levels of Al, As, Fe, Ni and Pb that exceeded Australian drinking water guideline values. For these reasons potential leaching of these contaminants is of concern and while difficult to attribute elevated contaminant levels to e-waste, we do not recommend continued disposal of e-waste in old landfills that were not originally designed to contain leachates. The survey also revealed temporal variation in the electrical conductivity and concentrations of As, Cd and Pb present in leachates of landfills in arid Mediterranean climates. These results are consistent with the marked variations in rainfall patterns observed for such climates. The solute concentration (EC and other ions including As

  15. Municipal Solid Waste Management: Recycling, Resource Recovery, and Landfills. LC Science Tracer Bullet.

    Science.gov (United States)

    Meikle, Teresa, Comp.

    Municipal solid waste refers to waste materials generated by residential, commercial, and institutional sources, and consists predominantly of paper, glass, metals, plastics, and food and yard waste. Within the definition of the Solid Waste Disposal Act, municipal solid waste does not include sewage sludge or hazardous waste. The three main…

  16. Vertical profiles of community abundance and diversity of anaerobic methanotrophic archaea (ANME) and bacteria in a simple waste landfill in north China.

    Science.gov (United States)

    Dong, Jun; Ding, Linjie; Wang, Xu; Chi, Zifang; Lei, Jiansen

    2015-03-01

    Anaerobic methane oxidation (AMO) is considered to be an important sink of CH4 in habitats as marine sediments. But, few studies focused on AMO in landfills which may be an important sink of CH4 derived from waste fermentation. To show evidence of AMO and to uncover function anaerobic methanotroph (ANME) community in landfill, different age waste samples were collected in Jinqianpu landfill located in north China. Through high-throughput sequencing, Methanomicrobiales and Methanosarcinales archaea associated with ANME and reverse methanogenic archaea of Methanosarcina and Methanobacterium were detected. Sulfate-reducing bacteria (SRB) (Desulfobulbus and Desulfococcus) which could couple with ANME-conducting AMO were also found. But, the community structure of ANME had no significant difference with depths. From the results of investigation, we can come to a conclusion that sulfate-dependent anaerobic methane oxidation (SR-DAMO) would be the dominant AMO process in the landfill, while iron-dependent anaerobic methane oxidation (M/IR-DAMO) process was weak though concentration of ferric iron was large in the landfill. Denitrification-dependent anaerobic methane oxidation (NR-DAMO) was negative because of lack of nitrate and relevant function microorganisms in the landfill. Results also indicate that CH4 mitigation would have higher potential by increasing electron acceptor contents and promoting the growth of relevant function microorganisms.

  17. Municipal solid waste landfill site selection with geographic information systems and analytical hierarchy process: a case study in Mahshahr County, Iran.

    Science.gov (United States)

    Alavi, Nadali; Goudarzi, Gholamreza; Babaei, Ali Akbar; Jaafarzadeh, Nemat; Hosseinzadeh, Mohsen

    2013-01-01

    Landfill siting is a complicated process because it must combine social, environmental and technical factors. In this study, in order to consider all factors and rating criteria, a combination of geographic information systems and analytical hierarchy process (AHP) was used to determine the best sites for disposal of municipal solid waste (MSW) in Mahshahr County, Iran. In order to the decision making for landfill siting a structural hierarchy formed and the most important criteria: surface water, sensitive ecosystems, land cover, urban and rural areas, land uses, distance to roads, slope and land type were chosen according to standards and regulations. Each criterion was evaluated by rating methods. In the next step the relative importance of criteria to each other was determined by AHP. Land suitability for landfill was evaluated by simple additive weighting method. According to the landfill suitability map, the study area classified to four categories: high, moderate, low and very low suitability areas, which represented 18.6%, 20.3%, 1.6 and 0.8% of the study area respectively. The other 58.7% of the study area was determined to be completely unsuitable for landfill. By considering the parameters, such as the required area for landfill, distance to MSW generation points, and political and management issues, and consulting with municipalities managers in the study area, six sites were chosen for site visiting. The result of field study showed that it is a supplementary, and necessary, step in finding the best candidate landfill site from land with high suitability.

  18. THE "CHEMICAL OXYGEN DEMAND / TOTAL VOLATILE ACIDS" RATIO AS AN ANAEROBIC TREATABILITY INDICATOR FOR LANDFILL LEACHATES

    OpenAIRE

    Contrera,R. C.; K. C. da Cruz Silva; G. H. Ribeiro Silva; D. M. Morita; Zaiat,M.; V. Schalch

    2015-01-01

    Abstract In some operational circumstances a fast evaluation of landfill leachate anaerobic treatability is necessary, and neither Biochemical Methane Potential nor BOD/COD ratio are fast enough. Looking for a fast indicator, this work evaluated the anaerobic treatability of landfill leachate from São Carlos-SP (Brazil) in a pilot scale Anaerobic Sequence Batch Biofilm Reactor (AnSBBR). The experiment was conducted at ambient temperature in the landfill area. After the acclimation, at a ...

  19. Emission model for landfills with mechanically-biologically pretreated waste, with the emphasis on modelling the gas balance; Emissionsprognosemodell fuer Deponien mit mechanisch-biologisch vorbehandelten Abfaellen - Schwerpunkt: Modellierung des Gashaushaltes

    Energy Technology Data Exchange (ETDEWEB)

    Danhamer, H.

    2001-07-01

    The objective of this work was to determine influence factors on processes going on in landfills with mechanically-biologically pretreated waste (MBP-landfills) in order to predict emissions. For this purpose a computer based model has been developed. The model allows to simulate the gas, water and heat balance as well as settlement processes and was called DESIM2005 (version MB). It is based on theoretical modeling approaches as well as data from lab and reactor experiments. The main focus of model application was to determine factors influencing the gas phase and the emissions of landfill gas and methane during operation and aftercare of MBP-landfills. By performing simulations the effects of changing parameters for the processes gas transport and biological degradation as well as the effects of different qualities in waste pretreatment and of varying landfill operation techniques were investigated. Possibilities for increasing the environmental sustainability of landfills containing mechanically-biologically pretreated waste were shown. (orig.)

  20. Comparison of different physico-chemical methods for the removal of toxicants from landfill leachate

    Energy Technology Data Exchange (ETDEWEB)

    Cotman, Magda, E-mail: magda.cotman@ki.si [National Institute of Chemistry, Hajdrihova 19, SI-1001 Ljubljana (Slovenia); Zgajnar Gotvajn, Andreja [University of Ljubljana, Faculty of Chemistry and Chemical Technology (Slovenia)

    2010-06-15

    Our work was focused on investigation of different treatment procedures for the removal of toxic fractions from a landfill leachate, because sometimes the existing treatment in biological sequencing batch reactor (SBR) is not efficient enough, leading to a hazardous environmental impact of the present persistent and toxic compounds. The efficiency of the procedures used was monitored by chemical analyses and two toxicity tests (activated sludge and Vibrio fischeri). The existing SBR (HRT = 1.9 days) removed 46-78% of COD and 96-73% of NH{sub 4}{sup +}-N. Experiments were conducted with three landfill leachate samples expressing significant difference in concentrations of pollutants and with low BOD{sub 5}/COD ratio (0.06/0.01/0.03). The applied methods were air stripping, adsorption to activated carbon and zeolite clinoptilolite and Fenton oxidation. Air stripping at pH 11 was a viable treatment option for the removal of ammonia nitrogen (up to 94%) and reduction of toxicity to microorganisms. In the adsorption experiments in batch system with different concentration of PAC the most effective was the highest addition (50.0 g L{sup -1}) where 63-92% of COD was removed followed by significant reduction in toxicity to V. fischeri. In the column experiments with clinoptilolite 45/93/100% of NH{sub 4}{sup +}-N as well as 25/32/39% of COD removal was attained. The removal efficiency for metals followed the sequence Cr > Zn > Cd > Ni. The procedure with zeolite was the second most efficient one regarding reduction of toxicity to both organisms. Fenton oxidation at molar ratio Fe{sup 2+}:H{sub 2}O{sub 2} = 1.0:10.0 assured 70-85% removal of COD but it only slightly reduced the toxicity.

  1. Technical potential of electricity production from municipal solid waste disposed in the biggest cities in Brazil: landfill gas, biogas and thermal treatment.

    Science.gov (United States)

    de Souza, Samuel Nm; Horttanainen, Mika; Antonelli, Jhonatas; Klaus, Otávia; Lindino, Cleber A; Nogueira, Carlos Ec

    2014-10-01

    This article presents an analysis of possibilities for electrical energy production by using municipal solid waste disposed in the biggest Brazilian cities. Currently, the municipal solid waste in Brazil is collected and disposed of at landfills, but there are also other technologies, which in addition to dealing with the garbage can also provide benefits in terms of energy provision. The following scenarios were studied in this work: electricity production from landfill gas (reference scenario); incineration of all municipal solid waste; anaerobic digestion of organic waste and incineration of refuse-derived fuel fractions after being separated in separation plants. According to this study, the biggest cities in Brazil generate about 18.9 million tonnes of municipal solid waste per year (2011), of which 51.5% is biogenic matter. The overall domestic consumption of electricity is 480,120 GWh y(-1) in Brazil and the municipal solid waste incineration in the 16 largest cities in the country could replace 1.8% of it using incinerators. The city of São Paulo could produce 637 GWh y(-1) with landfill gas, 2368 GWh y(-1) with incineration of municipal solid waste and 1177 GWh y(-1) with incineration of refuse-derived fuel. The latter two scenarios could replace 27% and 13.5% of the residential electrical energy consumption in the city. This shows that thermal treatment might be a viable option of waste-to-energy in Brazil.

  2. Influence of temperature on carbon and nitrogen dynamics during in situ aeration of aged waste in simulated landfill bioreactors.

    Science.gov (United States)

    Tong, Huanhuan; Yin, Ke; Giannis, Apostolos; Ge, Liya; Wang, Jing-Yuan

    2015-09-01

    The effect of temperature on carbon and nitrogen compounds during in situ aeration of aged waste was investigated in lab-scale simulated landfill bioreactors at 35, 45 and 55 °C, respectively. The bioreactor operated at 55 °C presented the highest carbon mineralization rate in the initial stage, suggesting accelerated biodegradation rates under thermophilic conditions. The nitrogen speciation study indicated that organic nitrogen was the dominant species of total N in aerobic bioreactors due to ammonia removal. Leachate organic nitrogen was further fractionated to elucidate the fate of individual constituent. Detailed investigation revealed the higher bioconversion rates of N-humic and N-fulvic compounds compared to hydrophilic compounds in thermophilic conditions. At the end, waste material in 55 °C bioreactor was richer in highly matured humic substances (HS) verifying the high bioconversion rates.

  3. State of the art design: A closure system for the largest hazardous waste landfill at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Bartlett, S.F.; Serrato, M.G.; McMullin, S.R.

    1992-12-31

    This paper discusses the cover system proposed for a 55-acre, hazardous waste closure of the sanitary landfill at the Savannah River Site, near Aiken, South Carolina. The proposed cover system has been designed to accommodate a significant amount of post-closure settlement while maintaining a permeability of 1 {times} 10{sup {minus}7} cm/s or less throughout its 30-year, regulatory lifetime. A composite cover consisting of a geomembrane (GM) underlain by a geosynthetic clay liner (GCL) was selected because of its extremely low permeability, ability to elongate without tearing, and capacity to ``self-heal`` if punctured. These characteristics will enable the cover system to accommodate differential settlement without cracking or tearing, this providing long-term protection with minimal maintenance. Also, to improve the ability of the cover system to span voids that may develop in the underlying waste, a geogrid has been included in the foundation layer. A gas vent layer has been included to allow for the safe collection and venting of landfill gases.

  4. State of the art design: A closure system for the largest hazardous waste landfill at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Bartlett, S.F.; Serrato, M.G.; McMullin, S.R.

    1992-01-01

    This paper discusses the cover system proposed for a 55-acre, hazardous waste closure of the sanitary landfill at the Savannah River Site, near Aiken, South Carolina. The proposed cover system has been designed to accommodate a significant amount of post-closure settlement while maintaining a permeability of 1 [times] 10[sup [minus]7] cm/s or less throughout its 30-year, regulatory lifetime. A composite cover consisting of a geomembrane (GM) underlain by a geosynthetic clay liner (GCL) was selected because of its extremely low permeability, ability to elongate without tearing, and capacity to self-heal'' if punctured. These characteristics will enable the cover system to accommodate differential settlement without cracking or tearing, this providing long-term protection with minimal maintenance. Also, to improve the ability of the cover system to span voids that may develop in the underlying waste, a geogrid has been included in the foundation layer. A gas vent layer has been included to allow for the safe collection and venting of landfill gases.

  5. A pluridisciplinary model to predict municipal landfill life

    OpenAIRE

    Hiligsmann, Serge; Rodriguez, C.; Lardinois, M.; Radu, Jean-Pol; Charlier, Robert; Destain, Jacqueline; Drion, R.; Thonart, Philippe

    2001-01-01

    Most degradation processes that occur within municipal wastes landfills result from different microbial activities interacting all along the landfill lifetime and that are influenced by several non-biological factors. These complex biological and chemical processes require a multidisciplinary pattern in order to assess and control their environmental impact. Thanks to Walloon Region support, we have developed a pattern or model combining the evolution of different key parameters. Such paramet...

  6. Public concerns about and perceptions of solid waste dump sites and selection of sanitary landfill sites in the West Bank, Palestinian territory.

    Science.gov (United States)

    Al-Khatib, Issam A; Abu Hammad, Ahmad; Sharkas, Othman A; Sato, Chikashi

    2015-04-01

    Palestinian inhabitants have disposed of their solid wastes at open dumpsites over the past 40 years without an adequate solid waste management (SWM) plans. Recently, the Palestinian Authority initiated SWM planning to establish controlled sanitary landfills, based on a participatory approach. The purpose of this study was to assess public concerns about existing solid waste dumpsites and public perceptions of sanitary landfill site selection. The study will also take into consideration the effect of diverse social, economic, and environmental related factors of the inhabitants on sitting suitable landfill sites in three Palestinian districts in the West Bank, namely, "Nablus," "Salfit," and "Ramallah and Al-Bireh." The results of this study showed that 64.9% of the sample population are aware of the problems and potential impacts associated with random dumpsites, and 41.6% think that they are suffering from the dumps. Among the environmental, socioeconomic, and political factors, the environmental factors, air pollution in particular, are thought be the most important consideration in selecting a landfill site. The "fairness in selecting a landfill site" was chosen to be one of the most important socioeconomic factors, possibly as a reaction to the Israeli occupation and subsequent land use restrictions in the West Bank, Palestinian territory.

  7. Subsurface imaging of an abandoned solid waste landfill site in Norman, Oklahoma

    Science.gov (United States)

    Zume, J.T.; Tarhule, A.; Christenson, S.

    2006-01-01

    Leachate plume emanating from an old unlined municipal landfill site near the city of Norman, Oklahoma, is discharging into the underlying alluvial aquifer. Subsurface imaging techniques, electrical resistivity tomography and electrical conductivity (EC) logging, were used on the site to detect and map the position of the leachate plume. Anomalous EC zones, delineated with the two methods, correlated with the occurrence of the plume detected by water chemistry analyses from multilevel monitoring wells. Specific conductance, a potential indicator of leachate contamination, ranged from 1861 to 7710 ??S/cm in contaminated zones and from 465 to 2180 ??S/cm in uncontaminated ground water. Results are in agreement with those from earlier studies that the leachate plume emerges from the landfill along preferential pathways. Additionally, there are indications that the leading edge of the plume has migrated, at least, 200 m away from the landfill in the direction of ground water flow. ?? 2006 National Ground Water Association.

  8. Landfill Mining of Shredder Residues

    DEFF Research Database (Denmark)

    Hansen, Jette Bjerre; Hyks, Jiri; Shabeer Ahmed, Nassera

    In Denmark, shredder residues (SR) are classified as hazardous waste and until January 2012 the all SR were landfilled. It is estimated that more than 1.8 million tons of SR have been landfilled in mono cells. This paper describes investigations conducted at two Danish landfills. SR were excavated...

  9. PERFORMANCE OF NORTH AMERICAN BIOREACTOR LANDFILLS: I. LEACHATE HYDROLOGY AND WASTE SETTLEMENT

    Science.gov (United States)

    An assessment of state-of-the-practice at five full-scale North American landfills operating as bioreactors is presented in this two-paper set. This paper focuses on effectiveness of liners and leachate collection systems, leachate generation rates, leachate recirculation practi...

  10. COMPARISON OF MICROBIAL POPULATIONS IN A CONVENTIONAL AND BIOREACTING MUNICIPAL SOLID WASTE LANDFILLS

    Science.gov (United States)

    Landfills are the ultimate reactors for biodegradation as they contain nutrients, bacteria, and various redox conditions which, then, change over time. Enhancement of the landill environment to optimize the rates of biodegradation and to ensure more rapid stabilization of the was...

  11. Emission Control and Utilization of Landfill Gas in Ningbo Waste Landfill Site%宁波市垃圾填埋场填埋气体排放控制及利用研究

    Institute of Scientific and Technical Information of China (English)

    王斌

    2013-01-01

    Taking Ningbo city as an example,the treatment measures of unorganized emission of odor landfill gas from domestic waste sanitary landfill site were discussed,for instance,ordered collection and incineration-power generation.It could treat greenhouse gases such as CH4 effectively to make the pollutions control,and use waste heat to produce electricity.Thus it would achieve energy-saving and emission-reduction.%以宁波市为例,探讨了生活垃圾卫生填埋场产生的无组织排放的异味填埋气体有序收集及焚烧发电的处理措施,既有效处理了CH4等温室气体,使污染排放得到有效控制,又利用余热发电,实现节能减排.

  12. Behaviour at landfills of waste having undergone mechanic-biological and thermal conditioning; Deponieverhalten mechanisch-biologisch und thermisch behandelten Restabfalls

    Energy Technology Data Exchange (ETDEWEB)

    Danhamer, H.; Dach, J.; Jager, J. [Institut WAR, Darmstadt (Germany). FG Abfalltechnik

    1998-12-31

    The work studies, in landfill test reactors, water, gas and heat transport as well as gas and leachate formation in waste having undergone mechanical-biological and thermal conditioning. (orig.) [Deutsch] Es wurde der Wasser-, Gas- und Waermetransport, sowie die Gasbildung- und Sickerwasserbelastung mechanisch-biologisch und thermisch vorbehandelter Abfaelle in Deponieversuchsreaktoren untersucht. (orig.)

  13. Concentration and sources of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in surface soil near a municipal solid waste (MSW) landfill.

    Science.gov (United States)

    Melnyk, A; Dettlaff, A; Kuklińska, K; Namieśnik, J; Wolska, L

    2015-10-15

    Due to a continuous demand of land for infrastructural and residential development there is a public concern about the condition of surface soil near municipal solid waste landfills. A total of 12 surface (0-20 cm) soil samples from a territory near a landfill were collected and the concentration of 16 PAHs and 7 PCB congeners were investigated in these samples. Limits of detection were in the range of 0.038-1.2 μg/kg for PAHs and 0.025-0.041 μg/kg for PCBs. The total concentration of ∑ PAHs ranged from 892 to 3514 μg/kg with a mean of 1974 μg/kg. The total concentration of ∑ PCBs ranged from 2.5 to 12 μg/kg with a mean of 4.5 μg/kg. Data analyses allowed to state that the PAHs in surface soils near a landfill were principally from pyrogenic sources. Due to air transport, PAHs forming at the landfill are transported outside the landfill. PCB origin is not connected with the landfill. Aroclor 1242 can be the source of PCBs in several samples.

  14. Interaction of organic contaminant with natural clay type geo sorbents: potential use as geologic barrier in urban landfill

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Jimenez, N.; Procopio, J. R.; Sevilla, T.; Cuevas, J.; Rodirguez, M.

    2009-07-01

    The great amount of municipal solid wastes generated by the cities can be processed in different ways such as incineration, derivation to composting plants or, simply, deposition in controlled landfills. One of the landfill characteristics is possess and adequate geological barrier for contaminant contention. The most important chemical processes an adequate geological battier for contaminant contention. (Author)

  15. Two-year performance by evapotranspiration covers for municipal solid waste landfills in northwest Ohio

    Energy Technology Data Exchange (ETDEWEB)

    Barnswell, Kristopher D., E-mail: kristopher.barnswell2@rockets.utoledo.edu [Department of Environmental Sciences, University of Toledo, Lake Erie Center, 6200 Bayshore Rd., Oregon, OH 43616 (United States); Dwyer, Daryl F., E-mail: daryl.dwyer@utoledo.edu [Department of Environmental Sciences, University of Toledo, 2801 W. Bancroft, Mail Stop 604, Toledo, OH 43606 (United States)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer All ET covers produced rates of percolation less than 32 cm yr{sup -1}, the maximum allowable rate by the Ohio EPA. Black-Right-Pointing-Pointer Dredged sediment provided sufficient water storage and promoted growth by native plant species. Black-Right-Pointing-Pointer Native plant mixtures attained acceptable rates of evapotranspiration throughout the growing season. - Abstract: Evapotranspiration (ET) covers have gained interest as an alternative to conventional covers for the closure of municipal solid waste (MSW) landfills because they are less costly to construct and are expected to have a longer service life. Whereas ET covers have gained acceptance in arid and semi-arid regions (defined by a precipitation (P) to potential evapotranspiration (PET) ratio less than 0.75) by meeting performance standards (e.g. rate of percolation), it remains unclear whether they are suitable for humid regions (P:PET greater than 0.75). The goal of this project is to extend their application to northwest Ohio (P:PET equals 1.29) by designing covers that produce a rate of percolation less than 32 cm yr{sup -1}, the maximum acceptable rate by the Ohio Environmental Protection Agency (OEPA). Test ET covers were constructed in drainage lysimeters (1.52 m diameter, 1.52 m depth) using dredged sediment amended with organic material and consisted of immature (I, plants seeded onto soil) or mature (M, plants transferred from a restored tall-grass prairie) plant mixtures. The water balance for the ET covers was monitored from June 2009 to June 2011, which included measured precipitation and percolation, and estimated soil water storage and evapotranspiration. Precipitation was applied at a rate of 94 cm yr{sup -1} in the first year and at rate of 69 cm yr{sup -1} in the second year. During the first year, covers with the M plant mixture produced noticeably less percolation (4 cm) than covers with the I plant mixture (17 cm). However, during the

  16. Probabilistic performance-assessment modeling of the mixed waste landfill at Sandia National Laboratories.

    Energy Technology Data Exchange (ETDEWEB)

    Peace, Gerald L.; Goering, Timothy James (GRAM, Inc.); Miller, Mark Laverne; Ho, Clifford Kuofei

    2005-11-01

    A probabilistic performance assessment has been conducted to evaluate the fate and transport of radionuclides (americium-241, cesium-137, cobalt-60, plutonium-238, plutonium-239, radium-226, radon-222, strontium-90, thorium-232, tritium, uranium-238), heavy metals (lead and cadmium), and volatile organic compounds (VOCs) at the Mixed Waste Landfill (MWL). Probabilistic analyses were performed to quantify uncertainties inherent in the system and models for a 1,000-year period, and sensitivity analyses were performed to identify parameters and processes that were most important to the simulated performance metrics. Comparisons between simulated results and measured values at the MWL were made to gain confidence in the models and perform calibrations when data were available. In addition, long-term monitoring requirements and triggers were recommended based on the results of the quantified uncertainty and sensitivity analyses. At least one-hundred realizations were simulated for each scenario defined in the performance assessment. Conservative values and assumptions were used to define values and distributions of uncertain input parameters when site data were not available. Results showed that exposure to tritium via the air pathway exceeded the regulatory metric of 10 mrem/year in about 2% of the simulated realizations when the receptor was located at the MWL (continuously exposed to the air directly above the MWL). Simulations showed that peak radon gas fluxes exceeded the design standard of 20 pCi/m{sup 2}/s in about 3% of the realizations if up to 1% of the containers of sealed radium-226 sources were assumed to completely degrade in the future. If up to 100% of the containers of radium-226 sources were assumed to completely degrade, 30% of the realizations yielded radon surface fluxes that exceeded the design standard. For the groundwater pathway, simulations showed that none of the radionuclides or heavy metals (lead and cadmium) reached the groundwater during

  17. Fuzzy-logic modeling of Fenton's strong chemical oxidation process treating three types of landfill leachates.

    Science.gov (United States)

    Sari, Hanife; Yetilmezsoy, Kaan; Ilhan, Fatih; Yazici, Senem; Kurt, Ugur; Apaydin, Omer

    2013-06-01

    Three multiple input and multiple output-type fuzzy-logic-based models were developed as an artificial intelligence-based approach to model a novel integrated process (UF-IER-EDBM-FO) consisted of ultrafiltration (UF), ion exchange resins (IER), electrodialysis with bipolar membrane (EDBM), and Fenton's oxidation (FO) units treating young, middle-aged, and stabilized landfill leachates. The FO unit was considered as the key process for implementation of the proposed modeling scheme. Four input components such as H(2)O(2)/chemical oxygen demand ratio, H(2)O(2)/Fe(2+) ratio, reaction pH, and reaction time were fuzzified in a Mamdani-type fuzzy inference system to predict the removal efficiencies of chemical oxygen demand, total organic carbon, color, and ammonia nitrogen. A total of 200 rules in the IF-THEN format were established within the framework of a graphical user interface for each fuzzy-logic model. The product (prod) and the center of gravity (centroid) methods were performed as the inference operator and defuzzification methods, respectively, for the proposed prognostic models. Fuzzy-logic predicted results were compared to the outputs of multiple regression models by means of various descriptive statistical indicators, and the proposed methodology was tested against the experimental data. The testing results clearly revealed that the proposed prognostic models showed a superior predictive performance with very high determination coefficients (R (2)) between 0.930 and 0.991. This study indicated a simple means of modeling and potential of a knowledge-based approach for capturing complicated inter-relationships in a highly non-linear problem. Clearly, it was shown that the proposed prognostic models provided a well-suited and cost-effective method to predict removal efficiencies of wastewater parameters prior to discharge to receiving streams.

  18. THE "CHEMICAL OXYGEN DEMAND / TOTAL VOLATILE ACIDS" RATIO AS AN ANAEROBIC TREATABILITY INDICATOR FOR LANDFILL LEACHATES

    Directory of Open Access Journals (Sweden)

    R. C. Contrera

    2015-03-01

    Full Text Available Abstract In some operational circumstances a fast evaluation of landfill leachate anaerobic treatability is necessary, and neither Biochemical Methane Potential nor BOD/COD ratio are fast enough. Looking for a fast indicator, this work evaluated the anaerobic treatability of landfill leachate from São Carlos-SP (Brazil in a pilot scale Anaerobic Sequence Batch Biofilm Reactor (AnSBBR. The experiment was conducted at ambient temperature in the landfill area. After the acclimation, at a second stage of operation, the AnSBBR presented efficiency above 70%, in terms of COD removal, utilizing landfill leachate without water dilution, with an inlet COD of about 11,000 mg.L-1, a TVA/COD ratio of approximately 0.6 and reaction time equal to 7 days. To evaluate the landfill leachate biodegradability variation over time, temporal profiles of concentration were performed in the AnSBBR. The landfill leachate anaerobic biodegradability was verified to have a direct and strong relationship to the TVA/COD ratio. For a TVA/CODTotal ratio lower than 0.20, the biodegradability was considered low, for ratios between 0.20 and 0.40 it was considered medium, and above 0.40 it was considered high.

  19. Chemical speciation and mobility of heavy metals in municipal solid waste incinerator fly ash

    Institute of Scientific and Technical Information of China (English)

    LIU Feng; LIU Jian-guo; YU Qian-feng; NIE Yong-feng

    2004-01-01

    Chemical speciation is a significant factor that governs the toxicity and mobility of heavy metals in municipal solid waste incinerator fly ash. Sequential extraction procedure is applied to fractionate heavy metals(Pb, Zn, Cd, Cu, and Cr) into five defined groups: exchangeable, carbonate, Fe-Mn oxide, organic, and residual fractions. The mobility of heavy metals is also investigated with the aid of toxicity characteristic leaching procedure. In the fly ash sample, Pb is primarily presented in the carbonate(51%) and exchangeable(20%) fractions; Cd and Zn mainly exist as the exchangeable(83% and 49% respectively); Cu is mostly contained in the last three fractions(totally 87%); and Cr is mainly contained in the residual fraction(62%). Pb, Zn and Cd showed the high mobility in the investigation, thus might be of risk to the natural environment when municipal solid waste incinerator fly ash is landfilled or reutilized.

  20. The effects of leachate recirculation with supplemental water addition on methane production and waste decomposition in a simulated tropical landfill.

    Science.gov (United States)

    Sanphoti, N; Towprayoon, S; Chaiprasert, P; Nopharatana, A

    2006-10-01

    In order to increase methane production efficiency, leachate recirculation is applied in landfills to increase moisture content and circulate organic matter back into the landfill cell. In the case of tropical landfills, where high temperature and evaporation occurs, leachate recirculation may not be enough to maintain the moisture content, therefore supplemental water addition into the cell is an option that could help stabilize moisture levels as well as stimulate biological activity. The objectives of this study were to determine the effects of leachate recirculation and supplemental water addition on municipal solid waste decomposition and methane production in three anaerobic digestion reactors. Anaerobic digestion with leachate recirculation and supplemental water addition showed the highest performance in terms of cumulative methane production and the stabilization period time required. It produced an accumulated methane production of 54.87 l/kg dry weight of MSW at an average rate of 0.58 l/kg dry weight/d and reached the stabilization phase on day 180. The leachate recirculation reactor provided 17.04 l/kg dry weight at a rate of 0.14l/kg dry weight/d and reached the stabilization phase on day 290. The control reactor provided 9.02 l/kg dry weight at a rate of 0.10 l/kg dry weight/d, and reached the stabilization phase on day 270. Increasing the organic loading rate (OLR) after the waste had reached the stabilization phase made it possible to increase the methane content of the gas, the methane production rate, and the COD removal. Comparison of the reactors' efficiencies at maximum OLR (5 kgCOD/m(3)/d) in terms of the methane production rate showed that the reactor using leachate recirculation with supplemental water addition still gave the highest performance (1.56 l/kg dry weight/d), whereas the leachate recirculation reactor and the control reactor provided 0.69 l/kg dry weight/d and 0.43 l/kg dry weight/d, respectively. However, when considering

  1. Effective solidification/stabilisation of mercury-contaminated wastes using zeolites and chemically bonded phosphate ceramics.

    Science.gov (United States)

    Zhang, Shaoqing; Zhang, Xinyan; Xiong, Ya; Wang, Guoping; Zheng, Na

    2015-02-01

    In this study, two kinds of zeolites materials (natural zeolite and thiol-functionalised zeolite) were added to the chemically bonded phosphate ceramic processes to treat mercury-contaminated wastes. Strong promotion effects of zeolites (natural zeolite and thiol-functionalised zeolite) on the stability of mercury in the wastes were obtained and these technologies showed promising advantages toward the traditional Portland cement process, i.e. using Portland cement as a solidification agent and natural or thiol-functionalised zeolite as a stabilisation agent. Not only is a high stabilisation efficiency (lowered the Toxicity Characteristic Leaching Procedure Hg by above 10%) obtained, but also a lower dosage of solidification (for thiol-functionalised zeolite as stabilisation agent, 0.5 g g(-1) and 0.7 g g(-1) for chemically bonded phosphate ceramic and Portland cement, respectively) and stabilisation agents (for natural zeolite as stabilisation agent, 0.35 g g(-1) and 0.4 g g(-1) for chemically bonded phosphate ceramic and Portland cement, respectively) were used compared with the Portland cement process. Treated by thiol-functionalised zeolite and chemically bonded phosphate ceramic under optimum parameters, the waste containing 1500 mg Hg kg(-1) passed the Toxicity Characteristic Leaching Procedure test. Moreover, stabilisation/solidification technology using natural zeolite and chemically bonded phosphate ceramic also passed the Toxicity Characteristic Leaching Procedure test (the mercury waste containing 625 mg Hg kg(-1)). Moreover, the presence of chloride and phosphate did not have a negative effect on the chemically bonded phosphate ceramic/thiol-functionalised zeolite treatment process; thus, showing potential for future application in treatment of 'difficult-to-manage' mercury-contaminated wastes or landfill disposal with high phosphate and chloride content.

  2. Imaging and characterization of heterogeneous landfills using geophysical methods

    NARCIS (Netherlands)

    Konstantaki, L.A.

    2016-01-01

    Nowadays many countries use landfilling for the management of their waste or for treating old landfills. Emissions from landfills can be harmful to the environment and to human health, making the stabilization of landfills a priority for the landfill communities. Estimation of the emission potential

  3. Landfill area estimation based on integrated waste disposal options and solid waste forecasting using modified ANFIS model.

    Science.gov (United States)

    Younes, Mohammad K; Nopiah, Z M; Basri, N E Ahmad; Basri, H; Abushammala, Mohammed F M; Younes, Mohammed Y

    2016-09-01

    Solid waste prediction is crucial for sustainable solid waste management. The collection of accurate waste data records is challenging in developing countries. Solid waste generation is usually correlated with economic, demographic and social factors. However, these factors are not constant due to population and economic growth. The objective of this research is to minimize the land requirements for solid waste disposal for implementation of the Malaysian vision of waste disposal options. This goal has been previously achieved by integrating the solid waste forecasting model, waste composition and the Malaysian vision. The modified adaptive neural fuzzy inference system (MANFIS) was employed to develop a solid waste prediction model and search for the optimum input factors. The performance of the model was evaluated using the root mean square error (RMSE) and the coefficient of determination (R(2)). The model validation results are as follows: RMSE for training=0.2678, RMSE for testing=3.9860 and R(2)=0.99. Implementation of the Malaysian vision for waste disposal options can minimize the land requirements for waste disposal by up to 43%.

  4. Utilization of sepiolite materials as a bottom liner material in solid waste landfills.

    Science.gov (United States)

    Guney, Yucel; Cetin, Bora; Aydilek, Ahmet H; Tanyu, Burak F; Koparal, Savas

    2014-01-01

    Landfill bottom liners are generally constructed with natural clay soils due to their high strength and low hydraulic conductivity characteristics. However, in recent years it is increasingly difficult to find locally available clay soils that satisfy the required engineering properties. Fine grained soils such as sepiolite and zeolite may be used as alternative materials in the constructions of landfill bottom liners. A study was conducted to investigate the feasibility of using natural clay rich in kaolinite, sepiolite, zeolite, and their mixtures as a bottom liner material. Unconfined compression tests, swell tests, hydraulic conductivity tests, batch and column adsorption tests were performed on each type of soil and sepiolite-zeolite mixtures. The results of the current study indicate that sepiolite is the dominant material that affects both the geomechanical and geoenvironmental properties of these alternative liners. An increase in sepiolite content in the sepiolite-zeolite mixtures increased the strength, swelling potential and metal adsorption capacities of the soil mixtures. Moreover, hydraulic conductivity of the mixtures decreased significantly with the addition of sepiolite. The utilization of sepiolite-zeolite materials as a bottom liner material allowed for thinner liners with some reduction in construction costs compared to use of a kaolinite-rich clay.

  5. Ground waters quality assessment near solid municipal wastes and hazardous landfills; Valutazione della qualita' delle acque profonde in prossimita' di impianti di discarica per rifiuti solidi urbani e per rifiuti pericolosi

    Energy Technology Data Exchange (ETDEWEB)

    Bellino, M.; Falleni, F.; Forte, T.; Musmeci, L. [Istituto Superiore di Sanita' , Rome (Italy). Lab. di Igiene Ambientale

    1999-07-01

    The report discusses the impact on ground waters quality in relation to municipal and similar waste landfills and hazardous waste landfills, examined in three landfills of first category and one landfill of second category type C. Analytical results from sampling of ground and leaching waters are reported; from these results it can be deduced that environmental impact is minimum or non-existent, where law criteria for construction and management of landfills are respected. [Italian] Il rapporto esamina l'impatto sulla qualita' delle acque profonde dovuto agli impianti di discarica per rifiuti solidi urbani e assimilabili e per rifiuti pericolosi, rispettivamente di tre discariche controllate di prima categoria ed una di seconda di tipo C. Vengono riportate le risultanze analitiche relative ai campionamenti per la costruzione e gestione delle discariche. L'impatto ambientale e' minimo se non assente.

  6. Assessment of methane production from shredder waste in landfills: The influence of temperature, moisture and metals

    DEFF Research Database (Denmark)

    Fathi Aghdam, Ehsan; Scheutz, Charlotte; Kjeldsen, Peter

    2017-01-01

    In this study, methane (CH4) production rates from shredder waste (SW) were determined by incubation of waste samples over a period of 230days under different operating conditions, and first-order decay kinetic constants (k-values) were calculated. SW and sterilized SW were incubated under...

  7. Citric waste saccharification under different chemical treatments

    Directory of Open Access Journals (Sweden)

    Carlos Eduardo de Farias Silva

    2015-10-01

    Full Text Available Second generation ethanol from lignocellulose materials has been used in applications for food processing wastes. Since Brazil has a leading position in orange juice exports, the influence of acid and alkali pretreatments on liquor saccharification, solubilization of solid fraction and mass yield was evaluated. Time and Cacid or Calkaline at different concentrations of solids (low to moderate, 1 to 9% and high catalyst concentrations were analyzed. A hydrothermal pretreatment was conducted under the same conditions of acid and alkaline treatments to investigate the relative selectivity increase in using the catalysts. The chemical analyses of wastes indicated a 70% total carbohydrate level denoting a promising raw material for bioethanol production. Pretreatment caused acid saccharifications between 25 and 65% in total reducing sugars (TRS and mass yields (MY between 30 and 40%. In alkaline pretreatment, these rates ranged between 2 and 22.5% and between 30 and 80, respectively. In hydrothermal pretreatment, solubilized TRS varied between 3 and 37%, whereas MY remained between 45 and 60%, respectively. Cbiomass strongly influenced the three variables; in the same way, time affected MY.

  8. Anaerobic co-digestion of food waste and landfill leachate in single-phase batch reactors

    Energy Technology Data Exchange (ETDEWEB)

    Liao, Xiaofeng; Zhu, Shuangyan; Zhong, Delai; Zhu, Jingping, E-mail: jpzhuhust@163.com; Liao, Li, E-mail: liaoli2003@126.com

    2014-11-15

    Highlights: • Anaerobic co-digestion strategy for food waste treatment at OLR 41.8 g VS/L. • A certain amount of raw leachate effectively relieved acidic inhibition. • The study showed that food waste was completely degraded. - Abstract: In order to investigate the effect of raw leachate on anaerobic digestion of food waste, co-digestions of food waste with raw leachate were carried out. A series of single-phase batch mesophilic (35 ± 1 °C) anaerobic digestions were performed at a food waste concentration of 41.8 g VS/L. The results showed that inhibition of biogas production by volatile fatty acids (VFA) occurred without raw leachate addition. A certain amount of raw leachate in the reactors effectively relieved acidic inhibition caused by VFA accumulation, and the system maintained stable with methane yield of 369–466 mL/g VS. Total ammonia nitrogen introduced into the digestion systems with initial 2000–3000 mgNH{sub 4}–N/L not only replenished nitrogen for bacterial growth, but also formed a buffer system with VFA to maintain a delicate biochemical balance between the acidogenic and methanogenic microorganisms. UV spectroscopy and fluorescence excitation–emission matrix spectroscopy data showed that food waste was completely degraded. We concluded that using raw leachate for supplement water addition and pH modifier on anaerobic digestion of food waste was effective. An appropriate fraction of leachate could stimulate methanogenic activity and enhance biogas production.

  9. An integrated approach to natural and geo synthetic clay barriers performance against the diffusion of a pollution plume from municipal solid waste (MSW) landfills

    Energy Technology Data Exchange (ETDEWEB)

    Cuevas, J.; Sevilla, M. T.; Procopio, J. R.; Ruiz, A. I.; Da silva, P.; Gismera, M. J.; Regadio, M.; Sanchez Jimenez, N.; Soto, I. S. de; Rodriguez, M.; Leguey, S.

    2009-07-01

    Technical requirements for the landfills of municipal wastes in the European Union (EU) are given in the Council Directive 1993/31/EC. A geological barrier of at least 1 m thickness with a hydraulic conductivity (HC) of 1x10{sup -}9 m/s is required. Where the geological barrier does not naturally present the above conditions, a geological barrier of at least 0.5 m thick must be artificially established. (Author)

  10. Application of Remote Sensing and GIS in Landfill (waste Disposal) Site Selection and Environmental Impacts Assessment around Mysore City, Karnataka, India

    Science.gov (United States)

    Basavarajappa, T. H.

    2012-07-01

    Landfill site selection is a complex process involving geological, hydrological, environmental and technical parameters as well as government regulations. As such, it requires the processing of a good amount of geospatial data. Landfill site selection techniques have been analyzed for identifying their suitability. Application of Geographic Information System (GIS) is suitable to find best locations for such installations which use multiple criteria analysis. The use of Artificial intelligence methods, such as expert systems, can also be very helpful in solid waste planning and management. The waste disposal and its pollution around major cities in Karnataka are important problems affecting the environment. The Mysore is one of the major cities in Karnataka. The landfill site selection is the best way to control of pollution from any region. The main aim is to develop geographic information system to study the Landuse/ Landcover, natural drainage system, water bodies, and extents of villages around Mysore city, transportation, topography, geomorphology, lithology, structures, vegetation and forest information for landfill site selection. GIS combines spatial data (maps, aerial photographs, and satellite images) with quantitative, qualitative, and descriptive information database, which can support a wide range of spatial queries. For the Site Selection of an industrial waste and normal daily urban waste of a city town or a village, combining GIS with Analytical Hierarchy Process (AHP) will be more appropriate. This method is innovative because it establishes general indices to quantify overall environmental impact as well as individual indices for specific environmental components (i.e. surface water, groundwater, atmosphere, soil and human health). Since this method requires processing large quantities of spatial data. To automate the processes of establishing composite evaluation criteria, performing multiple criteria analysis and carrying out spatial clustering

  11. Landfill gas management facilities design guidelines

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-03-15

    In British Columbia, municipal solid waste landfills generate over 1000 tonnes of methane per year; landfill gas management facilities are required to improve the environmental performance of solid waste landfills. The aim of this document, developed by the British Columbia Ministry of the Environment, is to provide guidance for the design, installation, and operation of landfill gas management facilities to address odor and pollutant emissions issues and also address health and safety issues. A review of technical experience and best practices in landfill gas management facilities was carried out, as was as a review of existing regulations related to landfill gas management all over the world. This paper provides useful information to landfill owners, operators, and other professionals for the design of landfill gas management facilities which meet the requirements of landfill gas management regulations.

  12. Performance of evaporators in high level radioactive chemical waste service

    Energy Technology Data Exchange (ETDEWEB)

    Jenkins, C.F.

    1997-12-01

    Chemical processing of nuclear fuels and targets at Savannah River Site resulted in generation of millions of gallons of liquid wastes. The wastes were further processed to reduce volume and allow for extended temporary storage of a more concentrated material. Waste evaporators have been a central point for waste reduction for many years. Currently, the transfer and processing of the concentrated wastes for permanent storage requires dilution and results in generation of significant quantities of additional liquid wastes. A new round of volume reduction is required to fit existing storage capacity and to allow for removal of older vessels from service. Evaporator design, performance and repairs are discussed in this report.

  13. Hong kong chemical waste treatment facilities: a technology overview

    Energy Technology Data Exchange (ETDEWEB)

    Siuwang, Chu [Enviropace Ltd., Hong Kong (Hong Kong)

    1993-12-31

    The effective management of chemical and industrial wastes represents one of the most pressing environmental problems confronting the Hong Kong community. In 1990, the Hong Kong government contracted Enviropace Limited for the design, construction and operation of a Chemical Waste Treatment Facility. The treatment and disposal processes, their integration and management are the subject of discussion in this paper

  14. Experimental and life cycle assessment analysis of gas emission from mechanically–biologically pretreated waste in a landfill with energy recovery

    Energy Technology Data Exchange (ETDEWEB)

    Di Maria, Francesco, E-mail: francesco.dimaria@unipg.it; Sordi, Alessio; Micale, Caterina

    2013-11-15

    Highlights: • Bio-methane landfill emissions from different period (0, 4, 8, 16 weeks) MTB waste have been evaluated. • Electrical energy recoverable from landfill gas ranges from 11 to about 90 kW h/tonne. • Correlation between oxygen uptake, energy recovery and anaerobic gas production shows R{sup 2} ranging from 0.78 to 0.98. • LCA demonstrate that global impact related to gaseous emissions achieve minimum for 4 week of MBT. - Abstract: The global gaseous emissions produced by landfilling the Mechanically Sorted Organic Fraction (MSOF) with different weeks of Mechanical Biological Treatment (MBT) was evaluated for an existing waste management system. One MBT facility and a landfill with internal combustion engines fuelled by the landfill gas for electrical energy production operate in the waste management system considered. An experimental apparatus was used to simulate 0, 4, 8 and 16 weeks of aerobic stabilization and the consequent biogas potential (Nl/kg) of a large sample of MSOF withdrawn from the full-scale MBT. Stabilization achieved by the waste was evaluated by dynamic oxygen uptake and fermentation tests. Good correlation coefficients (R{sup 2}), ranging from 0.7668 to 0.9772, were found between oxygen uptake, fermentation and anaerobic test values. On the basis of the results of several anaerobic tests, the methane production rate k (year{sup −1}) was evaluated. k ranged from 0.436 to 0.308 year{sup −1} and the bio-methane potential from 37 to 12 N m{sup 3}/tonne, respectively, for the MSOF with 0 and 16 weeks of treatment. Energy recovery from landfill gas ranged from about 11 to 90 kW h per tonne of disposed MSOF depending on the different scenario investigated. Life cycle analysis showed that the scenario with 0 weeks of pre-treatment has the highest weighted global impact even if opposite results were obtained with respect to the single impact criteria. MSOF pre-treatment periods longer than 4 weeks showed rather negligible variation

  15. Occurrence and Distribution of Pharmaceutical Organic Compounds in the Groundwater Downgradient of a Landfill (Grindsted, Denmark)

    DEFF Research Database (Denmark)

    Holm, John V.; Rügge, Kirsten; Bjerg, Poul Løgstrup;

    1995-01-01

    Usually landfill leachates contain specific organic compounds as BTEXs (benzene, toluene, ethylbenzene, and xylenes), chlorinated aliphatic hydrocarbons and chlorobenzenes originating from household chemicals and waste from small businesses (I). However, where industrial waste has been landfilled......, the leachate may contain many other organic compounds (2). Another paper of ours (3) described the distribution of commonly found organic compounds in the leachate plume downgradient of the Grindsted Landfill and discussed the fate of the organic compounds in view of the redox environments determined...... in the plume (4). In this paper, we describe the occurrence and distribution of organic compounds originating from waste from the pharmaceutical industry in the groundwater downgradient of the same landfill. According to our knowledge, this is the first report on pharmaceutical compounds in a leachate plume....

  16. Methane elimination methods on landfills

    OpenAIRE

    Ponikvar, Martin

    2008-01-01

    Increase in substance and energy exploitation from waste which reduces the greenhouse gas emissions are one of the main goals of environmental protection. Slovenian legislation defines that in case captured landfill gas cannot be used for energy acquisition, incineration on the landfill itself or some other equivalent procedure must be used to prevent gas emissions into the air. The graduation thesis is based on existing municipal landfill Volče where suitable gas elimination is yet to be arr...

  17. Targeted modification of organic components of municipal solid waste by short-term pre-aeration and its enhancement on anaerobic degradation in simulated landfill bioreactors.

    Science.gov (United States)

    Ni, Zhe; Liu, Jianguo; Girotto, Francesca; Cossu, Raffaello; Qi, Guangxia

    2016-09-01

    Pre-aeration is effective on regulating subsequent anaerobic degradation of municipal solid waste (MSW) with high organic fractions during landfilling. The strength of pre-aeration should be optimized to intentionally remove some easily biodegradable fractions while conserve bio-methane potential as much as possible. This study investigates the evolution of organic components in MSW during 2-14days pre-aeration process and its impacts on subsequent anaerobic degradation in simulated landfill bioreactors. Results showed that a 6-day pre-aeration enabled to develop a thermophilic stage, which significantly accelerated biodegradation of organics except lignocelluloses, with removal rates of 42.8%, 76.7% and 25.1% for proteins, carbohydrates and lipids, respectively. Particularly, ammonia from accelerated ammonification in the thermophilic stage neutralized VFAs generated from anaerobic landfilling. As a result, the MSW with 6-day pre-aeration obtained the highest methane yield 123.4NL/kg dry matter. Therefore, it is recommended to interrupt pre-aeration before its cooling stage to switch to anaerobic landfilling.

  18. Removal of Pb2+ and Cd2+ by adsorption on clay-solidified grouting curtain for waste landfills

    Institute of Scientific and Technical Information of China (English)

    CHEN Yong-gui; ZHANG Ke-neng; ZOU Yin-sheng; DENG Fei-yue

    2006-01-01

    Pb2+ and Cd2+ in leachate were adsorbed on clay-solidified grouting curtain for waste landfills with equilibrium experiment. The cation exchange capacity was determined with ammonium acetate. And the concentration of heavy metal cations in leachate was determined with atomic absorption spectrophotometer. Their equilibrium isotherms were measured, and the experimental isotherm data were analyzed by using Freundlich and Langmuir models. The results show that the adsorption capacities of the heavy metal cations are closely related to the compositions of clay-solidified grouting curtain, and the maximum adsorption appears at the ratio of cement to clay of 2: 4 in the experimental conditions. At their maximum adsorption and pH 5.0, the adsorption capacities of Pb2+ and Cd2+ are 16.19 mg/g and 1.21 mg/g. The competitive adsorption coefficients indicate that the adsorption of clay-solidified grouting curtain for Pb2+ is stronger than that for Cd2+. The adsorption process conforms to Freundlich's model with related coefficient higher than 0. 996.

  19. Deployment of an alternative cover and final closure of the Mixed Waste Landfill, Sandia National Laboratories, Albuquerque, New Mexico.

    Energy Technology Data Exchange (ETDEWEB)

    Peace, Gerald (Jerry) L.; Goering, Timothy James (GRAM, Inc., Albuquerque, NM); McVey, Michael David (GRAM, Inc., Albuquerque, NM); Borns, David James

    2003-06-01

    An alternative cover design consisting of a monolithic layer of native soil is proposed as the closure path for the Mixed Waste Landfill at Sandia National Laboratories, New Mexico. The proposed design would rely upon soil thickness and evapotranspiration to provide long-term performance and stability, and would be inexpensive to build and maintain. The proposed design is a 3-ft-thick, vegetated soil cover. The alternative cover meets the intent of RCRA Subtitle C regulations in that: (a) water migration through the cover is minimized; (b) maintenance is minimized by using a monolithic soil layer; (c) cover erosion is minimized by using erosion control measures; (d) subsidence is accommodated by using a ''soft'' design; and (e) the permeability of the cover is less than or equal to that of natural subsurface soil present. Performance of the proposed cover is integrated with natural site conditions, producing a ''system performance'' that will ensure that the cover is protective of human health and the environment. Natural site conditions that will produce a system performance include: (a) extremely low precipitation and high potential evapotranspiration; (b) negligible recharge to groundwater; (c) an extensive vadose zone; (d) groundwater approximately 500 ft below the surface; and (e) a versatile, native flora that will persist indefinitely as a climax ecological community with little or no maintenance.

  20. BIODEGRADATIVE ANALYSIS OF MUNICIPAL SOLID WASTE IN LABORATORY-SCALE LANDFILLS

    Science.gov (United States)

    The report gives results of research to characterize the anaerobic biodegradability of the major biodegradable components of municipal solid waste (MSW). Tests were conducted in quadruplicate in 2-L reactors operated to obtain maximum yields. Measured methane (CH4) yields for gra...

  1. Sustainable Practices for Landfill Design and Operation (Part of book series Waste Management Principles and Practice)

    Science.gov (United States)

    The management of municipal solid waste (MSW) in many countries throughout the world has changed significantly over the past fifty years, with a shift from uncontrolled dumping or burning to complex systems that integrate multiple processes to recover materials or energy and prov...

  2. Waste and resources management. Ordinance on Environmentally Compatible Storage of Waste from Human Settlements and on Biological Waste Treatment Facilities (Landfill Ordinance - AbfAblV) - one year on; Abfall- und Ressourcenwirtschaft. 1 Jahr Abfallablagerungsverordnung

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, K.; Bergs, C.G.; Kosak, G.; Wallmann, R.; Bidlingmaier, W. (eds.)

    2006-07-01

    As early as the beginning of 2005 there were signs of trouble ahead resulting from the new Landfill Ordinance - it was only the extent of the trouble that was somewhat underestimated. Suddenly and unexpected to everyone, the industrial wastes that were supposed to have been avoided or reutilised were there again. These ''returned wastes'', in most cases arisings that were not taken into account during plant design, are currently causing serious capacity problems both in waste incineration and in mechanical biological waste treatment plants. In not a few cases the originally planned supply rates are being exceeded by up to 35%, with dramatic consequences. Another source of problems is the lack of utilisation capacities for high-caloric waste fractions, especially for those from mechanical biological waste treatment. The underlying causes are manifold, ranging from market misjudgment, insufficient fuel processing capacities to supposed or factual quality problems with the generated secondary fuel. The only remedial option available at present - at least from the legal viewpoint - is interim storage. The changed framework conditions for biowaste and green waste utilisation brought about by the Renewable Energy Law offers new interesting perspectives. Numerous unresolved questions and quite as many solution proposals provide reason enough for making residual waste treatment and biowaste utilisation one of the focal topics of the congress. Many EU countries, but also developing and threshold countries, are on the verge of making decisions on waste utilisation and treatment. The experiences, positive and negative, that have been gained to date in Germany with the full-area implementation of residual waste treatment can serve these countries as a valuable guide. Another focal topic of the congress is climate and resource protection.

  3. Modelling of landfill gas adsorption with bottom ash for utilization of renewable energy

    Energy Technology Data Exchange (ETDEWEB)

    Miao, Chen

    2011-10-06

    Energy crisis, environment pollution and climate change are the serious challenges to people worldwide. In the 21st century, human being is trend to research new technology of renewable energy, so as to slow down global warming and develop society in an environmentally sustainable method. Landfill gas, produced by biodegradable municipal solid waste in landfill, is a renewable energy source. In this work, landfill gas utilization for energy generation is introduced. Landfill gas is able to produce hydrogen by steam reforming reactions. There is a steam reformer equipment in the fuel cells system. A sewage plant of Cologne in Germany has run the Phosphoric Acid Fuel Cells power station with biogas for more than 50,000 hours successfully. Landfill gas thus may be used as fuel for electricity generation via fuel cells system. For the purpose of explaining the possibility of landfill gas utilization via fuel cells, the thermodynamics of landfill gas steam reforming are discussed by simulations. In practice, the methane-riched gas can be obtained by landfill gas purification and upgrading. This work investigate a new method for upgrading-landfill gas adsorption with bottom ash experimentally. Bottom ash is a by-product of municipal solid waste incineration, some of its physical and chemical properties are analysed in this work. The landfill gas adsorption experimental data show bottom ash can be used as a potential adsorbent for landfill gas adsorption to remove CO{sub 2}. In addition, the alkalinity of bottom ash eluate can be reduced in these adsorption processes. Therefore, the interactions between landfill gas and bottom ash can be explained by series reactions accordingly. Furthermore, a conceptual model involving landfill gas adsorption with bottom ash is developed. In this thesis, the parameters of landfill gas adsorption equilibrium equations can be obtained by fitting experimental data. On the other hand, these functions can be deduced with theoretical approach

  4. Removal of ammonia nitrogen from leachate of Muribeca municipal solid waste landfill, Pernambuco, Brazil, using natural zeolite as part of a biochemical system.

    Science.gov (United States)

    Lins, Cecilia Maria M S; Alves, Maria Cristina M; Campos, Juacyara C; Silva, Fabrícia Maria S; Jucá, José Fernando T; Lins, Eduardo Antonio M

    2015-01-01

    The inadequate disposal of leachate is one of the key factors in the environmental impact of urban solid waste landfills in Brazil. Among the compounds present in the leachates from Brazilian landfills, ammonia nitrogen is notable for its high concentrations. The purpose of this study was to assess the efficiency of a permeable reactive barrier filled with a natural zeolite, which is part of a biochemical system for the tertiary treatment of the leachate from Muribeca Municipal Solid Waste Landfill in Pernambuco, Brazil, to reduce its ammonia nitrogen concentration. This investigation initially consisted of kinetic studies and batch equilibrium tests on the natural zeolite to construct the sorption isotherms, which showed a high sorption capacity, with an average of 12.4 mg NH4+.L(-1), a value close to the sorption rates found for the aqueous ammonium chloride solution. A permeable reactive barrier consisting of natural zeolite, as simulated by the column test, was efficient in removing the ammonia nitrogen present in the leachate pretreated with calcium hydroxide. Nevertheless, the regenerated zeolite did not satisfactorily maintain the sorption properties of the natural zeolite, and an analysis of their cation-exchange properties showed a reduced capacity of 54 meq per 100 g for the regenerated zeolite compared to 150 meq per 100 g for the natural zeolite.

  5. Environmental impact assessment on the construction and operation of municipal solid waste sanitary landfills in developing countries: China case study.

    Science.gov (United States)

    Yang, Na; Damgaard, Anders; Lü, Fan; Shao, Li-Ming; Brogaard, Line Kai-Sørensen; He, Pin-Jing

    2014-05-01

    An inventory of material and energy consumption during the construction and operation (C&O) of a typical sanitary landfill site in China was calculated based on Chinese industrial standards for landfill management and design reports. The environmental impacts of landfill C&O were evaluated through life cycle assessment (LCA). The amounts of materials and energy used during this type of undertaking in China are comparable to those in developed countries, except that the consumption of concrete and asphalt is significantly higher in China. A comparison of the normalized impact potential between landfill C&O and the total landfilling technology implies that the contribution of C&O to overall landfill emissions is not negligible. The non-toxic impacts induced by C&O can be attributed mainly to the consumption of diesel used for daily operation, while the toxic impacts are primarily due to the use of mineral materials. To test the influences of different landfill C&O approaches on environmental impacts, six baseline alternatives were assessed through sensitivity analysis. If geomembranes and geonets were utilized to replace daily and intermediate soil covers and gravel drainage systems, respectively, the environmental burdens of C&O could be mitigated by between 2% and 27%. During the LCA of landfill C&O, the research scope or system boundary has to be declared when referring to material consumption values taken from the literature; for example, the misapplication of data could lead to an underestimation of diesel consumption by 60-80%.

  6. Distribution of Organic Compounds from Municipal Solid Waste in the Groundwater Downgradient of a Landfill (Grindsted, Denmark)

    DEFF Research Database (Denmark)

    Rügge, Kirsten; Bjerg, Poul Løgstrup; Christensen, Thomas Højlund

    1995-01-01

    organic carbon, NVOC) were found. In a distance of 130 m downgradient of the landfill, the NVOC had decreased to background level, which is 1-3 mg of C L-l. More than 15 organic compounds were identified in the groundwater at the downgradient border of the landfill with benzene, toluene, ethylbenzene...

  7. ELECTRIC POWER GENERATION USING A PHOSPHORIC ACID FUEL CELL ON A MUNICIPAL SOLID WASTE LANDFILL GAS STREAM

    Science.gov (United States)

    The report gives results of tests to verify the performance of a landfill gas pretreatment unit (GPU) and a phorsphoric acid fuel cell system. The complete system removes contaminants from landfill gas and produces electricity for on-site use or connection to an electric grid. Th...

  8. Emerging contaminants at a closed and an operating landfill in Oklahoma

    Science.gov (United States)

    Andrews, William J.; Masoner, Jason R.; Cozzarelli, Isabelle M.

    2012-01-01

    Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty-eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.

  9. LANDFILL BIOREACTOR PERFORMANCE, SECOND INTERIM REPORT

    Science.gov (United States)

    A bioreactor landfill is a landfill that is operated in a manner that is expected to increase the rate and extent of waste decomposition, gas generation, and settlement compared to a traditional landfill. This Second Interim Report was prepared to provide an interpretation of fie...

  10. Estimation of product specific emissions from municipal solid waste landfills for the inventory phase in LCA

    DEFF Research Database (Denmark)

    Nielsen, Per Henning; Hauschild, Michael Zwicky

    1998-01-01

    disposed inlandfills and it has been made operational in the computer tool LCA-LAND. In the model, waste products are subdivided into fivegroups of components: general organic matter (e.g. paper), specific organic compounds (e.g. organic solvents), inert components(e.g. PVC), metals (e.g. cadmium......Life Cycle Assessment (LCA) is an environmental management tool used to examine and evaluate the environmental impactsassociated with the existence of products. The focus of LCA is on the entire life cycle of the product, i.e. from the extraction of theraw materials through the production...... of materials and components and the manufacture, transportation and use of the product to thefinal disposal and possible recycling of the product. Although LCA has developed significantly during recent years, product specific emissions from disposed waste have only got minorattention in the literature leaving...

  11. Life Cycle Assessment of Thermal Treatment Technologies. An environmental and financial systems analysis of gasification, incineration and landfilling of waste

    Energy Technology Data Exchange (ETDEWEB)

    Assefa, Getachew; Eriksson, Ola [Royal Inst. of Tech., Stockholm (Sweden). Industrial Ecology; Jaeraas, Sven; Kusar, Henrik [Royal Inst. of Tech., Stockholm (Sweden). Chemical Technology

    2003-05-01

    A technology which is currently developed by researchers at KTH is catalytic combustion. which is one component of a gasification system. Instead of performing the combustion in the gas turbine by a flame, a catalyst is used. When the development of a new technology (as catalytic combustion) reaches a certain step where it is possible to quantify material-, energy- and capital flows, the prerequisites for performing a systems analysis is at hand. The systems analysis can be used to expand the know-how about the potential advantages of the catalytic combustion technology by highlighting its function as a component of a larger system. In this way it may be possible to point out weak points which have to be investigated more, but also strong points to emphasise the importance of further development. The aim of this project was to assess the energy turnover as well as the potential environmental impacts and economic costs of thermal treatment technologies in general and catalytic combustion in particular. By using a holistic assessment of the advantages and disadvantages of catalytic combustion of waste it was possible to identify the strengths and weaknesses of the technology under different conditions. Following different treatment scenarios have been studied: (1) Gasification with catalytic combustion, (2) Gasification with flame combustion, (3) Incineration with energy recovery and (4) Landfilling with gas collection. In the study compensatory district heating is produced by combustion. of biofuel. The power used for running the processes in the scenarios is supplied by the waste-to-energy technologies themselves while compensatory power is assumed to be produced. from natural gas. The emissions from the system studied were classified and characterised using methodology from Life Cycle Assessment into the following environmental impact categories: Global Warming Potential, Acidification Potential, Eutrophication Potential and finally Formation of Photochemical

  12. Pressing Municipal Solid Waste Incineration Fly Ash Bricks for Landfill Volume Reduction%生活垃圾焚烧飞灰压制砌块与减容填埋技术

    Institute of Scientific and Technical Information of China (English)

    朱新才; 赵由才; 周雄; 张骏; 夏发发; 陈善平; 全学军

    2016-01-01

    The construction speed of municipal solid waste incineration (MSWI )is currently faster than that of hazardous waste landfill in China,so that the disposal of MSWI fly ash becomes a pressing problem of the day.In comparison with other technologies,the chemical stabilization is applied widely,while still consume plenty of chelating agent and landfill volume.Restriction from total volume and service life of hazardous waste landfill,it is urgent to find a novel,economical and efficient technology for quick disposal of MSWI fly ash.In this study,the fly ash was pressed at high hydraulic load to reduce considerably both the volume and the quantity of chelating agents so that remarkably extend the service life of landfill.It was shown that the volume can be reduced over 60 %and the heavy metals leaching concentration of MSWI bricks was down obviously after pressing,which indicated the usage of chelating agent can be reduced by 30% ~70%.A novel volume reduction landfill process was proposed,the investment and benefit were evaluated.The service life can be prolonged for more than one to two times.The direct cost for the disposal of fly ash could be decreased by 200 RMB/t (not including the investment of equipment).The MSWI fly ash bricks were of regular shape and tight texture,which can avoid the dust in conventional landfill,promote automation, improve management and efficiency.%目前我国生活垃圾焚烧厂的建设速度远远超过危险废物填埋场的建设速度,大量的飞灰亟待安全处置。相对于其他处置技术,化学稳定化填埋被广泛应用,但需耗费大量重金属螯合剂以及填埋场库容,且满足技术规范的危废填埋场的填埋能力和使用年限均受限制。针对以上问题,对生活垃圾焚烧飞灰砌块减容潜力、重金属降低浸出进行研究,分析了飞灰压制砌块-减容填埋的可行性,并进行工艺设计,初步确定了工艺投入和综合效益。结果表明:生活垃

  13. Chemical composition of material fractions in Danish household waste

    DEFF Research Database (Denmark)

    Riber, Christian; Petersen, Claus; Christensen, Thomas Højlund

    2009-01-01

    method, because of the larger quantities included and the more homogenous material to sample from. Differences between the direct and the direct methods led to corrections in the of heavy metal concentration of a few fractions. The majority of the energy content of the waste originates from organic waste......The chemical composition of Danish household waste was determined by two approaches: a direct method where the chemical composition (61 substances) of 48 material fractions was determined after hand sorting of about 20 tonnes of waste collected from 2200 households; and an indirect method where...... batches of 80-1200 tonnes of unsorted household waste was incinerated and the content of the waste determined from the content of the outputs from the incinerator. The indirect method is believed to better represent the small but highly contaminated material fractions (e,g., batteries) than the direct...

  14. Environmental assessment of solid waste landfilling technologies by means of LCA-modeling

    DEFF Research Database (Denmark)

    Manfredi, Simone; Christensen, Thomas Højlund

    2009-01-01

    for 100 years”. The assessment criteria include standard categories (global warming, nutrient enrichment, ozone depletion, photo-chemical ozone formation and acidification), toxicity-related categories (human toxicity and ecotoxicity) and impact on spoiled groundwater resources. Results demonstrate...

  15. Leachates treatment with oxygen in Sanitary landfills of urban solid waste; Depuracion de lixiviados con oxigeno en vertederos de RSU

    Energy Technology Data Exchange (ETDEWEB)

    Parra, P.

    1999-11-01

    The leachate of spillways of solid waste is a product of the rain and of the humidity contributed by the residuals that is deposited in it. When water is filtered through the residuals in decompositions, biological materials and chemical compounds are dragged and dilute, being many of them very polluting. For their treatment, one must keep in mind that the composition chemistry of the leachates varies a lot according to the technique of exploitation and the antiquity of the spillway. (Author)

  16. Landfills, Hazardous Waste - CONSTRUCTION_DEMOLITION_WASTE_IDEM_IN: Construction and Demoliton Waste Facilities in Indiana (Indiana Department of Environmental Management, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — CONSTRUCTION_DEMOLITION_WASTE_IDEM_IN is a point shapefile that contains construction and demolition waste facility locations in Indiana, provided by personnel of...

  17. Hydraulic conductivity study of compacted clay soils used as landfill liners for an acidic waste.

    Science.gov (United States)

    Hamdi, Noureddine; Srasra, Ezzeddine

    2013-01-01

    Three natural clayey soils from Tunisia were studied to assess their suitability for use as a liner for an acid waste disposal site. An investigation of the effect of the mineral composition and mechanical compaction on the hydraulic conductivity and fluoride and phosphate removal of three different soils is presented. The hydraulic conductivity of these three natural soils are 8.5 × 10(-10), 2.08 × 10(-9) and 6.8 × 10(-10)m/s for soil-1, soil-2 and soil-3, respectively. Soil specimens were compacted under various compaction strains in order to obtain three wet densities (1850, 1950 and 2050 kg/m(3)). In this condition, the hydraulic conductivity (k) was reduced with increasing density of sample for all soils. The test results of hydraulic conductivity at long-term (>200 days) using acidic waste solution (pH=2.7, charged with fluoride and phosphate ions) shows a decrease in k with time only for natural soil-1 and soil-2. However, the specimens of soil-2 compressed to the two highest densities (1950 and 2050 kg/m(3)) are cracked after 60 and 20 days, respectively, of hydraulic conductivity testing. This damage is the result of a continued increase in the internal stress due to the swelling and to the effect of aggressive wastewater. The analysis of anions shows that the retention of fluoride is higher compared to phosphate and soil-1 has the highest sorption capacity.

  18. Anaerobic digestion of municipal solid waste as a treatment prior to landfill

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, P.H.L.; Kuruparan, P.; Visvanathan, C. [Asian Institute of Technology, Pathumthani (Thailand). Environmental Engineering and Management Program

    2007-02-15

    Anaerobic digestion of organic fraction of municipal solid waste was conducted in pilot-scale reactor based on high-solid combined anaerobic digestion process. This study was performed in two runs. In Run1 and Run 2, pre-stage flushing and micro-aeration were conducted to determine their effect in terms of enhancing hydrolysis and acidification in ambient condition. In Run 2, after pre-stage, the methane phase (methanogenesis) was started-up after pH adjustment and inoculum addition in mesophilic condition. Acidified leachate produced in pre-stage was used for percolation during active methane phase. At the end of methane phase, air flushing was conducted before unloading the digesters. Hydrolysis an acidification yield of 140 g C/kg TS and 180 g VFA/kg TS were achieved, respectively in pre-stage. Micro-aeration exhibited an equivocal result in terms of enhancing hydrolysis/acidification; however it showed a positive effect in methane phase performance and this needed further investigation. Leachate percolation during methane phase showed an enhanced methanization when compared to the reactors without leachate percolation. After 60 days, 260 l CH{sub 4}/kg VS was obtained. Based on the waste methane potential, 75% biogas conversion and 61% VS degradation were achieved. (author)

  19. Chemical species of plutonium in Hanford radioactive tank waste

    Energy Technology Data Exchange (ETDEWEB)

    Barney, G.S.

    1997-10-22

    Large quantities of radioactive wastes have been generated at the Hanford Site over its operating life. The wastes with the highest activities are stored underground in 177 large (mostly one million gallon volume) concrete tanks with steel liners. The wastes contain processing chemicals, cladding chemicals, fission products, and actinides that were neutralized to a basic pH before addition to the tanks to prevent corrosion of the steel liners. Because the mission of the Hanford Site was to provide plutonium for defense purposes, the amount of plutonium lost to the wastes was relatively small. The best estimate of the amount of plutonium lost to all the waste tanks is about 500 kg. Given uncertainties in the measurements, some estimates are as high as 1,000 kg (Roetman et al. 1994). The wastes generally consist of (1) a sludge layer generated by precipitation of dissolved metals from aqueous wastes solutions during neutralization with sodium hydroxide, (2) a salt cake layer formed by crystallization of salts after evaporation of the supernate solution, and (3) an aqueous supernate solution that exists as a separate layer or as liquid contained in cavities between sludge or salt cake particles. The identity of chemical species of plutonium in these wastes will allow a better understanding of the behavior of the plutonium during storage in tanks, retrieval of the wastes, and processing of the wastes. Plutonium chemistry in the wastes is important to criticality and environmental concerns, and in processing the wastes for final disposal. Plutonium has been found to exist mainly in the sludge layers of the tanks along with other precipitated metal hydrous oxides. This is expected due to its low solubility in basic aqueous solutions. Tank supernate solutions do not contain high concentrations of plutonium even though some tanks contain high concentrations of complexing agents. The solutions also contain significant concentrations of hydroxide which competes with other

  20. Fluctuation of dissolved heavy metal concentrations in the leachate from anaerobic digestion of municipal solid waste in commercial scale landfill bioreactors: The effect of pH and associated mechanisms.

    Science.gov (United States)

    Xie, S; Ma, Y; Strong, P J; Clarke, W P

    2015-12-15

    Heavy metals present in landfill leachate have infrequently been related to complete anaerobic degradation municipal solid waste (MSW) due to discrete ages of deposited MSW layers and leachate channelling in landfills. In this study, anaerobic digestion of MSW was performed in two enclosed 1000 tonne bioreactors using a unique flood and drain process. Leachates were characterised in terms of pH, soluble chemical oxygen demand, volatile fatty acids (VFAs), ammonium nitrogen and heavy metals over the entire course of digestion. All parameters, including pH, fluctuated during acidogenesis, acetogenesis and methanogenesis, which strongly impacted on the dynamics of dissolved heavy metal concentrations. The simulation of dissolution and precipitation processes indicated that metal sulphide precipitation was not a factor as metal concentrations exceeded solubility limits. The correlation of pH and dissolved heavy metal concentrations indicated that other, mechanisms were involved in the homogenised conditions within the bioreactors. Beside dissolution and precipitation, the main processes most likely involved in metal distributions were adsorption (Zn, Cu, Ni, Pb and Cd), complexation (Cr) or combinations of both process (As and Co).

  1. Landfill aeration for emission control before and during landfill mining.

    Science.gov (United States)

    Raga, Roberto; Cossu, Raffaello; Heerenklage, Joern; Pivato, Alberto; Ritzkowski, Marco

    2015-12-01

    The landfill of Modena, in northern Italy, is now crossed by the new high velocity railway line connecting Milan and Bologna. Waste was completely removed from a part of the landfill and a trench for the train line was built. With the aim of facilitating excavation and further disposal of the material extracted, suitable measures were defined. In order to prevent undesired emissions into the excavation area, the aerobic in situ stabilisation by means of the Airflow technology took place before and during the Landfill Mining. Specific project features involved the pneumatic leachate extraction from the aeration wells (to keep the leachate table low inside the landfill and increase the volume of waste available for air migration) and the controlled moisture addition into a limited zone, for a preliminary evaluation of the effects on process enhancement. Waste and leachate were periodically sampled in the landfill during the aeration before the excavation, for quality assessment over time; the evolution of biogas composition in the landfill body and in the extraction system for different plant set-ups during the project was monitored, with specific focus on uncontrolled migration into the excavation area. Waste biological stability significantly increased during the aeration (waste respiration index dropped to 33% of the initial value after six months). Leachate head decreased from 4 to 1.5m; leachate recirculation tests proved the beneficial effects of moisture addition on temperature control, without hampering waste aerobization. Proper management of the aeration plant enabled the minimization of uncontrolled biogas emissions into the excavation area.

  2. Report: Maximizing recycling participation to reduce waste to landfill: a study of small to medium-sized enterprises in Hobart, Tasmania, Australia.

    Science.gov (United States)

    Parsons, Sam; Kriwoken, Lorne K

    2010-05-01

    Small to medium-sized enterprises (SMEs) in Hobart, Tasmania, Australia face many barriers to recycling participation. This study first investigated the volumes and types of waste produced by SMEs. Significant barriers were then identified and key motivators to recycle examined. Using the Australia New Zealand Standard of Industrial Classification, stratified sampling of SMEs (n = 436) was undertaken. Inadequate storage space, paucity of readily available information on recycling services and the lack of staff allocated to sort and recycle were identified as major barriers. Cardboard, paper and plastic waste were produced in large volumes with only a small percentage being recycled and these were identified as target areas for local government. Recommendations include the appointment of a dedicated recycling officer to maximize recycling participation for the reduction of waste to landfill and to undertake further research on minimizing recycling costs.

  3. Properties of Simple Waste Landfill in Beijing Area%北京地区简易垃圾填埋场特性

    Institute of Scientific and Technical Information of China (English)

    张志红; 孙保卫; 纪华; 曲波

    2013-01-01

    The internal properties of waste body on typical simple waste landfill were researched in Beijing area.The variable regularity of internal temperature with filled depth of waste body was measured in site.The variable regularities of waste component,rate of water content and organic content with filled depth of waste body were found indoors.Results show that the inner temperature in the waste will decrease with increasing of dumping depth for superficial landfill,yet the inner temperature in the waste will increase with increasing of dumping depth for deep landfill until reaching peak value,then the adverse results can be obtained.The quantity of organic matter will decrease with increasing of dumping depth,and the water content values measured have indicated to increase with increasing mass of organic matter.%为了研究北京地区典型简易垃圾填埋场垃圾体的内部特征,在现场测定了垃圾体内部温度随深度的变化规律,并在室内测定了垃圾体的成分、含水率和有机质含量随深度的变化.结果表明:对于填埋深度较浅的垃圾场,垃圾体内部温度随填埋深度增加而降低,填埋深度较深的垃圾场,垃圾体内部温度则随填埋深度的增加而提高,但达到某一峰值后又呈逐渐下降的趋势;有机质随填埋深度增加而减小;含水量随着有机质质量分数的增加表现出逐渐增大的趋势.

  4. Physico-chemical characterisation of material fractions in household waste

    DEFF Research Database (Denmark)

    Götze, Ramona; Boldrin, Alessio; Scheutz, Charlotte

    2016-01-01

    State-of-the-art environmental assessment of waste management systems rely on data for the physico-chemical composition of individual material fractions comprising the waste in question. To derive the necessary inventory data for different scopes and systems, literature data from different sources...... and backgrounds are consulted and combined. This study provides an overview of physico-chemical waste characterisation data for individual waste material fractions available in literature and thereby aims to support the selection of data fitting to a specific scope and the selection of uncertainty ranges related...... to the data selection from literature. Overall, 97 publications were reviewed with respect to employed characterisation method, regional origin of the waste, number of investigated parameters and material fractions and other qualitative aspects. Descriptive statistical analysis of the reported physico...

  5. Gas Production Potential in the Landfill of Tehran by Landfill Methane Outreach Program

    Directory of Open Access Journals (Sweden)

    Pazoki

    2015-10-01

    Full Text Available Background Landfilling is the most common way of municipal solid waste (MSW disposal in Iran. Many countries have targeted landfill methane recovery among greenhouse gas mitigation strategies, since methane is the second most important greenhouse gas after carbon dioxide. Major questions remain with respect to actual methane production rates in field settings as well as the relative mass of methane that is recovered, emitted, oxidized by methanotrophic bacteria, laterally migrated, or temporarily stored within the landfill volume. Landfill gas (LFG consists of 50% - 60 vol% methane and 30% - 40 vol% carbon dioxide as well as trace amounts of numerous chemical compounds such as aromatics, chlorinated organic compounds and sulfur compounds. Landfill methane outreach program (LMOP is a voluntary assistance program which helps reduce methane emissions from landfills by encouraging the recovery and the beneficial use of LFG as an energy resource. Objectives In this study, the volume of LFG of Tehran by landfill methane outreach program (LMOP software was calculated. In addition, the relationship between the time of gas collection system operation and the volume of LFG production was evaluated. Materials and Methods The LMOP software was used. The available information and some presumptions were used to operate the software. The composition of the solid waste collected from the landfill of Tehran had specific details. A large amount of it was organic materials, which was about 67.8%. These materials have a good potential to produce gas. In addition, LMOP Colombia model uses the first-order equations in all the analytical equations. Furthermore, it is assumed that the landfill operation time is 30 years and the process is considered in two conditions; first, the gas was recovered in 2000, and second, the process started in 2015. Results The modeling results showed that for the gas recovery starting in 2000 and 2015, the power generation would be 2

  6. Stochastic approach to municipal solid waste landfill life based on the contaminant transit time modeling using the Monte Carlo (MC) simulation.

    Science.gov (United States)

    Bieda, Bogusław

    2013-01-01

    The paper is concerned with application and benefits of MC simulation proposed for estimating the life of a modern municipal solid waste (MSW) landfill. The software Crystal Ball® (CB), simulation program that helps analyze the uncertainties associated with Microsoft® Excel models by MC simulation, was proposed to calculate the transit time contaminants in porous media. The transport of contaminants in soil is represented by the one-dimensional (1D) form of the advection-dispersion equation (ADE). The computer program CONTRANS written in MATLAB language is foundation to simulate and estimate the thickness of landfill compacted clay liner. In order to simplify the task of determining the uncertainty of parameters by the MC simulation, the parameters corresponding to the expression Z2 taken from this program were used for the study. The tested parameters are: hydraulic gradient (HG), hydraulic conductivity (HC), porosity (POROS), linear thickness (TH) and diffusion coefficient (EDC). The principal output report provided by CB and presented in the study consists of the frequency chart, percentiles summary and statistics summary. Additional CB options provide a sensitivity analysis with tornado diagrams. The data that was used include available published figures as well as data concerning the Mittal Steel Poland (MSP) S.A. in Kraków, Poland. This paper discusses the results and show that the presented approach is applicable for any MSW landfill compacted clay liner thickness design.

  7. [Nursing workers' perceptions regarding the handling of hazardous chemical waste].

    Science.gov (United States)

    Costa, Taiza Florêncio; Felli, Vanda Elisa Andres; Baptista, Patrícia Campos Pavan

    2012-12-01

    The objectives of this study were to identify the perceptions of nursing workers regarding the handling of hazardous chemical waste at the University of São Paulo University Hospital (HU-USP), and develop a proposal to improve safety measures. This study used a qualitative approach and a convenience sample consisting of eighteen nursing workers. Data collection was performed through focal groups. Thematic analysis revealed four categories that gave evidence of training deficiencies in terms of the stages of handling waste. Difficulties that emerged included a lack of knowledge regarding exposure and its impact, the utilization of personal protective equipment versus collective protection, and suggestions regarding measures to be taken by the institution and workers for the safe handling of hazardous chemical waste. The present data allowed for recommending proposals regarding the safe management of hazardous chemical waste by the nursing staff.

  8. Bioactives from fruit processing wastes: Green approaches to valuable chemicals.

    Science.gov (United States)

    Banerjee, Jhumur; Singh, Ramkrishna; Vijayaraghavan, R; MacFarlane, Douglas; Patti, Antonio F; Arora, Amit

    2017-06-15

    Fruit processing industries contribute more than 0.5billion tonnes of waste worldwide. The global availability of this feedstock and its untapped potential has encouraged researchers to perform detailed studies on value-addition potential of fruit processing waste (FPW). Compared to general food or other biomass derived waste, FPW are found to be selective and concentrated in nature. The peels, pomace and seed fractions of FPW could potentially be a good feedstock for recovery of bioactive compounds such as pectin, lipids, flavonoids, dietary fibres etc. A novel bio-refinery approach would aim to produce a wider range of valuable chemicals from FPW. The wastes from majority of the extraction processes may further be used as renewable sources for production of biofuels. The literature on value addition to fruit derived waste is diverse. This paper presents a review of fruit waste derived bioactives. The financial challenges encountered in existing methods are also discussed.

  9. Methane production in anaerobic digestion of organic waste from Recife (Brazil landfill: evaluation in refuse of diferent ages

    Directory of Open Access Journals (Sweden)

    W. N. Schirmer

    2014-06-01

    Full Text Available This work focuses on monitoring the generation of biogas by biochemical methane potential (BMP assays, commonly used to assess anaerobic biodegradability of solid and liquid wastes under controlled conditions. The experiment employed 5 g of substrate of both refuses (fresh and one-year-old wastes, digested with 250 mL of inoculum in 1 L flasks as bioreactors (all of them in triplicate, operating under batch conditions at ± 35 ºC. Despite the difference of age of both refuses evaluated, there was no significant differences in volume (near 1800 mL and composition (55% methane of biogas generated in 80 days of incubation under mesophilic conditions. The important parameters of both refuses (such as moisture content, volatile solids and chemical oxygen demand also showed very similar initial values.

  10. The Biogeochemistry of Contaminant Groundwater Plumes Arising from Waste Disposal Facilities

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup; Albrechtsen, Hans-Jørgen; Kjeldsen, Peter;

    2014-01-01

    Landfills with solid waste are abundant sources of groundwater pollution all over the world. Old uncontrolled municipal landfills are often large, heterogeneous sources with demolition waste, minor fractions of commercial or industrial waste, and organic waste from households. Strongly anaerobic...... leachate with a high content of dissolved organic carbon, salts, and ammonium, as well as specific organic compounds and metals is released from the waste for decades or centuries. Landfill leachate plume hosts a variety of biogeochemical processes, which is the key to understand the significant potential...... at landfill sites. Finally, the potential chemical or ecological impact from landfills located in former wetlands or near surface water bodies may deserve attention in future studies....

  11. DESIGN OF LANDFILL LEACHATE TREATMENT PLANT IN CHANGSHA SOLID WASTE LANDFILL SITE%长沙市固体废弃物处理场渗沥液处理工程

    Institute of Scientific and Technical Information of China (English)

    吴惠鹏; 周昭阳; 陈娟娟

    2012-01-01

    长沙市固体废弃物处理场渗沥液处理工程是目前国内达到垃圾填埋场污染物排放限制(GB 16889-2008)要求的大型渗沥液处理厂,于2010年6月建成,最大处理规模达到1500 t/d,采用(A/O)2-MBR+RO/NF处理工艺设计.经运行验证,处理系统稳定高效,出水水质良好达标.文中对工程概况、污水特点、工艺流程、单元设计及运行效果进行了说明,并对本项目设计经验进行了总结.%The leachate treatment plant in Changsha Solid Waste Landfill Site was a large-scale plant which final effluent can meet the requirements of GB 16889-2008: standard for pollution control on the landfill site of municipal solid waste. The plant was completed on June 2010, whose maximum handling capacity was 1 500 m3/d, which was designed by (A/O)2-MBR+RO/NF process. The practical running showed that the treatment system was reliable and efficient, the effluent water quality can meet the standard. This article introduced the treatment plant, influent water quality, treatment process and treatment effect, and summarized as well the experiences of the plant designing.

  12. Best Practices for Siting Solar Photovoltaics on Municipal Solid Waste Landfills. A Study Prepared in Partnership with the Environmental Protection Agency for the RE-Powering America's Land Initiative: Siting Renewable Energy on Potentially Contaminated Land and Mine Sites

    Energy Technology Data Exchange (ETDEWEB)

    Kiatreungwattana, K.; Mosey, G.; Jones-Johnson, S.; Dufficy, C.; Bourg, J.; Conroy, A.; Keenan, M.; Michaud, W.; Brown, K.

    2013-04-01

    The Environmental Protection Agency and the National Renewable Energy Laboratory developed this best practices document to address common technical challenges for siting solar photovoltaics (PV) on municipal solid waste (MSW) landfills. The purpose of this document is to promote the use of MSW landfills for solar energy systems. Closed landfills and portions of active landfills with closed cells represent thousands of acres of property that may be suitable for siting solar photovoltaics (PV). These closed landfills may be suitable for near-term construction, making these sites strong candidate to take advantage of the 30% Federal Business Energy Investment Tax Credit. It was prepared in response to the increasing interest in siting renewable energy on landfills from solar developers; landfill owners; and federal, state, and local governments. It contains examples of solar PV projects on landfills and technical considerations and best practices that were gathered from examining the implementation of several of these projects.

  13. Combined Chemical Activation and Fenton Degradation to Convert Waste Polyethylene into High-Value Fine Chemicals.

    Science.gov (United States)

    Chow, Cheuk-Fai; Wong, Wing-Leung; Ho, Keith Yat-Fung; Chan, Chung-Sum; Gong, Cheng-Bin

    2016-07-04

    Plastic waste is a valuable organic resource. However, proper technologies to recover usable materials from plastic are still very rare. Although the conversion/cracking/degradation of certain plastics into chemicals has drawn much attention, effective and selective cracking of the major waste plastic polyethylene is extremely difficult, with degradation of C-C/C-H bonds identified as the bottleneck. Pyrolysis, for example, is a nonselective degradation method used to crack plastics, but it requires a very high energy input. To solve the current plastic pollution crisis, more effective technologies are needed for converting plastic waste into useful substances that can be fed into the energy cycle or used to produce fine chemicals for industry. In this study, we demonstrate a new and effective chemical approach by using the Fenton reaction to convert polyethylene plastic waste into carboxylic acids under ambient conditions. Understanding the fundamentals of this new chemical process provides a possible protocol to solve global plastic-waste problems.

  14. Off-air treatment in waste treatment systems and landfills - consequences for practical operation. 62. information meeting of ANS e.V.; Abluftbehandlung bei MBA und Deponiebetrieb - Konsequenzen fuer die Praxis. 62. Informationsgespraech des ANS e.V.

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, K.; Burth, M.; Dichtl, N.; Wallmann, R. (eds.)

    2001-07-01

    The new German Landfill Ordinance of 1 March 2001 specifies the requirements on construction and operation of mechanical-biological waste treatment plants and landfills as well as the continued operation of existing landfills. The conference provided current information of R + D projects as well as practical experience in Austria and Germany, with particular regard to the issues of off-air emissions and landfilling. [German] Seit dem 1. Maerz 2001 ist die Artikelverordnung rechtswirksam. Sie enthaelt Anforderungen an den Bau und Betrieb von mechanisch-biologischen Restabfallbehandlungsanlagen und Deponien. Die Abfallablagerungsverordnung hat darueber hinaus weitreichende Konsequenzen fuer die Betriebsdauer bestehender Deponien. Ziel der Tagung ist es, aktuelle Informationen aus laufenden Forschungs- und Entwicklungsvorhaben sowie Erfahrungen bei der praktischen Umsetzung zu praesentieren, die insbesondere zu den Themenkomplexen Abluftemissionen und Deponierung zur Zeit in Oesterreich und Deutschland vorliegen. (orig.)

  15. Leachate from Municipal Waste Landfill and Its Natural Degradation-A Case Study of Zubří, Zlín Region.

    Science.gov (United States)

    Václavík, Vojtěch; Ondrašiková, Ivana; Dvorský, Tomáš; Černochová, Kateřina

    2016-09-01

    This work deals with the natural degradation of leachate from an old reclaimed landfill by means of a biological pond. Hamra is a municipal waste landfill with a limited formation of leachate, which has already been reclaimed. Leachate in this location is disposed of using natural biogeochemical method, and it is subsequently discharged into a surface stream. The main issue dealt with here is the long-term effectiveness of natural degradation of leachate and the limits of its use. The solutions of these fundamental questions took advantage of a database of analytical assessments collected during a long-term monitoring of the landfill site. The primary degradation trends and the long-term development have been revealed and described on the basis of these assessments. The main benefit of the biological pond is the dilution of the dominant contaminants, especially of inorganic character. In the case of ammonium ions, they show nitrification caused by their transition from the reduction into oxidizing environment. From a long term point of view, the disadvantage of natural degradation of leachate can be seen in the gradual reduction in efficiency due to the concentration of the substances or an undesired growth of water plants, which can be successfully eliminated, for example, by means of targeted aeration and by maintaining vegetation in the pond and its surroundings. The biological potential of the locality is very favorable and, despite its anthropogenic load, it creates a location with suitable living conditions for many water animals and plants. That is why it can be concluded that the efficiency of the natural biochemical cleaning elements can be considered as sufficient, taking into account the nature of the deposited waste, the quantity and quality of leachate, as well as the climate character of the locality.

  16. Leachate from Municipal Waste Landfill and Its Natural Degradation—A Case Study of Zubří, Zlín Region

    Science.gov (United States)

    Václavík, Vojtěch; Ondrašiková, Ivana; Dvorský, Tomáš; Černochová, Kateřina

    2016-01-01

    This work deals with the natural degradation of leachate from an old reclaimed landfill by means of a biological pond. Hamra is a municipal waste landfill with a limited formation of leachate, which has already been reclaimed. Leachate in this location is disposed of using natural biogeochemical method, and it is subsequently discharged into a surface stream. The main issue dealt with here is the long-term effectiveness of natural degradation of leachate and the limits of its use. The solutions of these fundamental questions took advantage of a database of analytical assessments collected during a long-term monitoring of the landfill site. The primary degradation trends and the long-term development have been revealed and described on the basis of these assessments. The main benefit of the biological pond is the dilution of the dominant contaminants, especially of inorganic character. In the case of ammonium ions, they show nitrification caused by their transition from the reduction into oxidizing environment. From a long term point of view, the disadvantage of natural degradation of leachate can be seen in the gradual reduction in efficiency due to the concentration of the substances or an undesired growth of water plants, which can be successfully eliminated, for example, by means of targeted aeration and by maintaining vegetation in the pond and its surroundings. The biological potential of the locality is very favorable and, despite its anthropogenic load, it creates a location with suitable living conditions for many water animals and plants. That is why it can be concluded that the efficiency of the natural biochemical cleaning elements can be considered as sufficient, taking into account the nature of the deposited waste, the quantity and quality of leachate, as well as the climate character of the locality. PMID:27598181

  17. Comparison of first-order-decay modeled and actual field measured municipal solid waste landfill methane data.

    Science.gov (United States)

    Amini, Hamid R; Reinhart, Debra R; Niskanen, Antti

    2013-12-01

    The first-order decay (FOD) model is widely used to estimate landfill gas generation for emissions inventories, life cycle assessments, and regulation. The FOD model has inherent uncertainty due to underlying uncertainty in model parameters and a lack of opportunities to validate it with complete field-scale landfill data sets. The objectives of this paper were to estimate methane generation, fugitive methane emissions, and aggregated collection efficiency for landfills through a mass balance approach using the FOD model for gas generation coupled with literature values for cover-specific collection efficiency and methane oxidation. This study is unique and valuable because actual field data were used in comparison with modeled data. The magnitude and variation of emissions were estimated for three landfills using site-specific model parameters and gas collection data, and compared to vertical radial plume mapping emissions measurements. For the three landfills, the modeling approach slightly under-predicted measured emissions and over-estimated aggregated collection efficiency, but the two approaches yielded statistically equivalent uncertainties expressed as coefficients of variation. Sources of uncertainty include challenges in large-scale field measurement of emissions and spatial and temporal fluctuations in methane flow balance components (generated, collected, oxidized, and emitted methane). Additional publication of sets of field-scale measurement data and methane flow balance components will reduce the uncertainty in future estimates of fugitive emissions.

  18. Physical and chemical evaluation of furniture waste briquettes.

    Science.gov (United States)

    Moreno, Ana Isabel; Font, Rafael; Conesa, Juan A

    2016-03-01

    Furniture waste is mainly composed of wood and upholstery foam (mostly polyurethane foam). Both of these have a high calorific value, therefore, energy recovery would be an appropriate process to manage these wastes. Nevertheless, the drawback is that the energy content of these wastes is limited due to their low density mainly that of upholstery foam. Densification of separate foam presents difficulties due to its elastic character. The significance of this work lies in obtaining densified material by co-densification of furniture wood waste and polyurethane foam waste. Densification of furniture wood and the co-densification of furniture wood waste with polyurethane foam have been studied. On the one hand, the parameters that have an effect on the quality of the furniture waste briquettes have been analysed, i.e., moisture content, compaction pressure, presence of lignin, etc. The maximum weight percentage of polyurethane foam that can be added with furniture wood waste to obtain durable briquettes and the optimal moisture were determined. On the other hand, some parameters were analysed in order to evaluate the possible effect on the combustion. The chemical composition of waste wood was compared with untreated wood biomass; the higher nitrogen content and the concentration of some metals were the most important differences, with a significant difference of Ti content.

  19. 垃圾焚烧厂渗滤液处理设施运行优化%Operation Optimization of Landfill Leachate Treatment Facilities in Waste Incineration Plant

    Institute of Scientific and Technical Information of China (English)

    陈广; 王诚; 裘湛; 汪喜生

    2015-01-01

    好氧膜生物反应器(MBR)工艺是垃圾焚烧厂处理渗滤液的常用工艺之一,使用中膜污染及膜通量下降是制约MBR系统处理能力的主要因素。该文分析了上海某垃圾焚烧厂渗滤液处理设施、处理效果及实际影响因素,对离心出水的可行性进行了理论分析和试验研究,并提出了切实可行的运行优化方案,有效缓解了膜污染及膜通量下降等问题对整个MBR系统处理能力的制约。%Aerobic membrane bioreactor (MBR ) process is one of conventional process of landfill leachate treatment in waste incineration plant. However,membrane fouling and membrane flux declining limit the capacity of MBR system during its operation. On the basis of the data from operation of landfill leachate treatment facility in a waste incineration plant in Shanghai and some special experiments about the centrifugal filtrate,combined centrifugation units and unltra-filter were suggested to used,which can alleviate membrane fouling and flux decline problem effectively,and has popularization value for operation optimization.

  20. Chemical Dewatering Technique of waste Polymer Drilling Fluid

    Institute of Scientific and Technical Information of China (English)

    Li Gang; Zhu Muo

    1997-01-01

    @@ On the basis of the compositional analysis of waste polymer drilling fluid, we adopt chemical dewatering technique and thoroughly break down the colloid system of the drilling fluid. Having changed the surface properties of the clay particles and made the waste mud flocculate, the floc lost mud making ability and the phemeonenon of the floc returning mud is completely dispelled when it is buried. The recovered water can be reused in the mud system.

  1. EMISSION ASSESSMENT AT THE ŠTĚPÁNOVICE MUNICIPAL SOLID WASTE LANDFILL FOCUSING ON CH4 EMISSIONS

    Directory of Open Access Journals (Sweden)

    Dana Adamcová

    2016-07-01

    Full Text Available The study was conducted to measure the emission from landfill in the years 2005–2011. The results are used to diagnose the emissions of CH4. The mean value of CH4 in vol. % in the collection wells ranged from 0 to 2.14 vol. % the mean concentration of CH4 in mg/m3 ranged from 0 to 25 251 mg/m3 the average concentration of CH4 in mg/Nm3 at the measuring and control points ranged from 2.2 to 24.1 mg/Nm3. CH4 emissions from the landfill do not exceed the reporting thresholds the landfill does not meet conditions for being included in the Integrated Register of Pollutants.

  2. MOLECULAR AND CULTURAL METHODOLOGIES FOR ENUMERATING BACTERIA IN LANDFILL LEACHATES

    Science.gov (United States)

    Landfill bioreactor technology has been under investigation in the field for its potential economic and waste treatment benefits over conventional landfill systems. A better understanding of biological influences on the stabilization process is needed for incorporation into the e...

  3. CORROSION AND CHEMICAL WASTE IN SAWBLADES STEEL USED IN WOOD

    Directory of Open Access Journals (Sweden)

    Paulo Fernando Trugilho

    2002-01-01

    Full Text Available The objective this work was to evaluate the chemical waste provoked by the wood on the sheets of steel used in the making of the mountains and cut tools. It was certain the correlationbetween the chemical waste and the extractive soluble in cold water, hot water and in the sequencetoluene and ethanol content. Two types of steel and twenty-seven species different from wood wereused. The corrosive agent, constituted of 50 g of fresh sawdust (moist mixed to 50 ml of distilledwater, it was prepared and placed inside of the plastic box, hermetically closed, on the samples ofsteel, which were totally immersed. The box was placed in a water bath pre-heated to 75°C, that themedium temperature of reaction is considered, that affects the sheet of the sawblade in operation. Thisgroup was operated to 80 rotations per minute (rpm. The time of reaction was of four hours. Afterthat time the corrosive agent was discarded and the samples were washed, dried and weighed. At theend, each sample was processed by a total period of forty hours. The chemical waste was evaluated by the weight difference suffered from beginning at the end of the experiment. For theresults it was observed that the Eucalyptus tradryphloia and the Eucalyptus phaeotricha the speciesthat provoked were, respectively, the largest and smaller chemical waste for the two types of steelappraised. Great variation exists in the chemical waste due to the effect of the species. The corrosionand chemical waste are especially related with the quality of the material solved in ethanol. The 1070steel were more attached than the 6170 steel.

  4. Hydrophobic organic chemicals (HOCs) removal from biologically treated landfill leachate by powder-activated carbon (PAC), granular-activated carbon (GAC) and biomimetic fat cell (BFC).

    Science.gov (United States)

    Liyan, Song; Youcai, Zhao; Weimin, Sun; Ziyang, Lou

    2009-04-30

    Biological pretreatment efficiently remove organic matter from landfill leachate, but further removal of refractory hydrophobic organic chemicals (HOCs) is hard even with advanced treatment. In this work, three-stage-aged refuse bioreactor (ARB) efficiently removed chemical oxygen demand (COD) and biochemical oxygen demand (BOD) of fresh leachate produced in Shanghai laogang landfill, from 8603 to 451 mg L(-1) and 1368 to 30 mg L(-1), respectively. In downstream treatment, 3 g L(-1) powder-activated carbon (PAC), granular-activated carbon (GAC) and biomimetic fat cell (BFC) removed 89.2, 73.4 and 81.1% HOCs, but only 24.6, 19.1 and 8.9% COD, respectively. Through the specific HOCs accumulation characteristics of BFC, about 11.2% HOCs with low molecular weight (effluent exhibited a wide molecular weight distribution (34-514,646 Da). These constitutes are derived from both autochthonous and allochthonous matters as well as biological activities.

  5. CORROSION AND CHEMICAL WASTE IN SAWBLADES STEEL USED IN WOOD

    OpenAIRE

    2002-01-01

    The objective this work was to evaluate the chemical waste provoked by the wood on the sheets of steel used in the making of the mountains and cut tools. It was certain the correlationbetween the chemical waste and the extractive soluble in cold water, hot water and in the sequencetoluene and ethanol content. Two types of steel and twenty-seven species different from wood wereused. The corrosive agent, constituted of 50 g of fresh sawdust (moist) mixed to 50 ml of distilledwater, it was prepa...

  6. Computer simulation for designing waste reduction in chemical processing

    Energy Technology Data Exchange (ETDEWEB)

    Mallick, S.K. [Oak Ridge Inst. for Science and Technology, TN (United States); Cabezas, H.; Bare, J.C. [Environmental Protection Agency, Cincinnati, OH (United States)

    1996-12-31

    A new methodology has been developed for implementing waste reduction in the design of chemical processes using computer simulation. The methodology is based on a generic pollution balance around a process. For steady state conditions, the pollution balance equation is used as the basis to define a pollution index with units of pounds of pollution per pound of products. The pollution balance has been modified by weighing the mass of each pollutant by a chemical ranking of environmental impact. The chemical ranking expresses the well known fact that all chemicals do not have the same environmental impact, e.g., all chemicals are not equally toxic. Adding the chemical ranking effectively converts the pollutant mass balance into a balance over environmental impact. A modified pollution index or impact index with units of environmental impact per mass of products is derived from the impact balance. The impact index is a measure of the environmental effects due to the waste generated by a process. It is extremely useful when comparing the effect of the pollution generated by alternative processes or process conditions in the manufacture of any given product. The following three different schemes for the chemical ranking have been considered: (i) no ranking, i.e., considering that all chemicals have the same environmental impact, (ii) a simple numerical ranking of wastes from 0 to 3 according to the authors judgement of the impact of each chemical, and (iii) ranking wastes according to a scientifically derived combined index of human health and environmental effects. Use of the methodology has been illustrated with an example of production of synthetic ammonia. 3 refs., 2 figs., 1 tab.

  7. Environmental impact assessment on the construction and operation of municipal solid waste sanitary landfills in developing countries: China case study

    DEFF Research Database (Denmark)

    Yang, Na; Damgaard, Anders; Lü, Fan

    2014-01-01

    of mineral materials. To test the influences of different landfill C&O approaches on environmental impacts, six baseline alternatives were assessed through sensitivity analysis. If geomembranes and geonets were utilized to replace daily and intermediate soil covers and gravel drainage systems, respectively...

  8. Selection and Evaluation of Chemical Indicators for Waste Stream Identification

    Science.gov (United States)

    DeVita, W. M.; Hall, J.

    2015-12-01

    Human and animal wastes pose a threat to the quality of groundwater, surface water and drinking water. This is especially of concern for private and public water supplies in agricultural areas of Wisconsin where land spreading of livestock waste occurs on thin soils overlaying fractured bedrock. Current microbial source tracking (MST) methods for source identification requires the use of polymerase chain reaction (PCR) techniques. Due to cost, these tests are often not an option for homeowners, municipalities or state agencies with limited resources. The Water and Environmental Analysis Laboratory sought to develop chemical methods to provide lower cost processes to determine sources of fecal waste using fecal sterols, pharmaceuticals (human and veterinary) and human care/use products in ground and surface waters using solid phase extraction combined with triple quadrupole mass spectrometry. The two separate techniques allow for the detection of fecal sterol and other chemical markers in the sub part per billion-range. Fecal sterol ratios from published sources were used to evaluate drinking water samples and wastewater from onsite waste treatment systems and municipal wastewater treatment plants. Pharmaceuticals and personal care products indicative of human waste included: acetaminophen, caffeine, carbamazepine, cotinine, paraxanthine, sulfamethoxazole, and the artificial sweeteners; acesulfame, saccharin, and sucralose. The bovine antibiotic sulfamethazine was also targeted. Well water samples with suspected fecal contamination were analyzed for fecal sterols and PPCPs. Results were compared to traditional MST results from the Wisconsin State Laboratory of Hygiene. Chemical indicators were found in 6 of 11 drinking water samples, and 5 of 11 were in support of MST results. Lack of detection of chemical indicators in samples contaminated with fecal waste supports the need for confirmatory methods and advancement of chemical indicator detection technologies.

  9. Chemical recycling of mixed waste plastics by selective pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Tatsumoto, K.; Meglen, R.; Evans, R. [National Renewable Energy Laboratory, Golden, CO (United States)

    1995-05-01

    The goal of this work is to use selective pyrolysis to produce high-value chemicals from waste plastics mixtures. Selectivity is achieved by exploiting differences in reaction rates, catalysis, and coreactants. Target wastes are molecular mixtures such as; blends or composites, or mixtures from manufactured products such as; carpets and post-consumer mixed-plastic wastes. The experimental approach has been to use small-scale experiments using molecular beam mass spectrometry (MBMS), which provides rapid analysis of reaction products and permits rapid screening of process parameters. Rapid screening experiments permit exploration of many potential waste stream applications for the selective pyrolysis process. After initial screening, small-scale, fixed-bed and fluidized-bed reactors are used to provide products for conventional chemical analysis, to determine material balances, and to test the concept under conditions that will be used at a larger scale. Computer assisted data interpretation and intelligent chemical processing are used to extract process-relevant information from these experiments. An important element of this project employs technoeconomic assessments and market analyses of durables, the availability of other wastes, and end-product uses to identify target applications that have the potential for economic success.

  10. Earth Construction and Landfill Disposal Options for Slaker Grits

    Directory of Open Access Journals (Sweden)

    Risto Pöykiö

    2010-12-01

    Full Text Available Slaker grits, an industrial residue originating from the chemical recovery process at sulfate (kraft pulp mills, are typically disposed of to landfill in Finland. However, due to the relatively low total heavy metal and low leachable heavy metal, chloride, fluoride, sulfate, Dissolved O rganic Carbon (DOC and Total Dissolved Solids (TDS concentrations, the residue is a potential earth construction material. This paper gives an overview of the relevant Finnish legislation on the use of industrial waste as an earth construction agent, the classification of waste into one of three classes: hazardous waste, non-hazardous waste and inert waste, as well as the broad waste policy goals under EU law that affects their management.

  11. Canonical correlations between chemical and energetic characteristics of lignocellulosic wastes

    Directory of Open Access Journals (Sweden)

    Thiago de Paula Protásio

    2012-09-01

    Full Text Available Canonical correlation analysis is a statistical multivariate procedure that allows analyzing linear correlation that may exist between two groups or sets of variables (X and Y. This paper aimed to provide canonical correlation analysis between a group comprised of lignin and total extractives contents and higher heating value (HHV with a group of elemental components (carbon, hydrogen, nitrogen and sulfur for lignocellulosic wastes. The following wastes were used: eucalyptus shavings; pine shavings; red cedar shavings; sugar cane bagasse; residual bamboo cellulose pulp; coffee husk and parchment; maize harvesting wastes; and rice husk. Only the first canonical function was significant, but it presented a low canonical R². High carbon, hydrogen and sulfur contents and low nitrogen contents seem to be related to high total extractives contents of the lignocellulosic wastes. The preliminary results found in this paper indicate that the canonical correlations were not efficient to explain the correlations between the chemical elemental components and lignin contents and higher heating values.

  12. What to do with your chemical waste ?

    CERN Multimedia

    Roland Magnier/SC

    2004-01-01

    For any type and quantity of chemical waste, please contact phone number 16 0879 or 16 3315 for the collection and safe elimination. The quality and the safety of our environment is our own responsibility. Let's do it. Roland Magnier/SC-GS

  13. Study on the Natural Soil Properties Endau Rompin National Park (PETA as Compacted Soil Liner for Sanitary Landfill

    Directory of Open Access Journals (Sweden)

    Zulkifli Ahmad

    2013-11-01

    Full Text Available Abstract: This paper reviews and extends an understanding of a study on potential suitability of the natural soil in Endau Rompin National Park (PETA as a compacted soil liner for sanitary landfill. Since the demand for landfill system becomes obvious so that concerning construction and operation of landfills are increasing. A number of studies have been conducted for the liner system of landfill. Hence, study is required to choose the suitable type of material as liner barrier for the landfill system in term to achieve optimum long term performance. The sanitary landfill plays an important role in the framework of solid waste disposal. The compacted soil liner is a part of a liner structure for landfill to restrict leachate migration from facility into the environment. So that, if the landfill system is not well manage it will contaminate the soil and ground water, thus presenting a risk to human and environmental health. This study, natural soil will be taken from Endau Rompin National Park (PETA, Johor as soil sample for testing. Natural soil is an economy material as a liner system, and it does not decay easily from time to time. So it is an ideal material as a sanitary landfill liner system. In short, the purpose of this study is to compile and organize available information on the use of laboratory testing, as well as providing some guidance on the use of natural soil as barrier layer of landfill and also it suitability of physical and chemical properties natural soil as barrier layer of landfill. Based on the laboratory testing were conducted, found that soil sample taken form Endau Rompin National Park (PETA is suitable as compacted soil liner for sanitary landfill.

  14. Chemical waste treatment and recovery laboratory: an alternative for industrial waste of southern Minas Gerais

    Directory of Open Access Journals (Sweden)

    Luciano Tavares da Costa

    2015-06-01

    Full Text Available This manuscript consisted to obtain data, such as costs, equipments and investments necessary for the implementation of a Waste Treatment and Recovery Laboratory at UNIFAL-MG, campus II in Alfenas. In order to give support for the implementation and operation of this laboratory, in a way to guarantee a sustainable investment from the economic point of view, the EVTE was applied. This work was performed following the steps: identification and quantification of the wastes, EVTE elaboration, draft of the physical laboratory architecture and the analysis of the potential financial resources. It was verified that the implementation and management of the Chemical Waste Treatment Laboratory get to support an initial waste volume of 372 L/month and 3.5 kg/month of inorganic salts, beyond other industrial wastes from the neighborhood region. The implementation and maintenance of this laboratory are economic viable depending on the treated, recovered and recycled waste volume as well as on the provided service for the industry client. It is necessary to highlight the environmental benefits, especially due to the chemical waste disposal reduction, the academic formation opportunity and the social awareness promoted by the action of the laboratory. It can be add on the principle related to the Sustainable Logistic Plan in the Federal Public Administration.JEL-Code | Q01; QR3; L65.

  15. Study of some characteristic Mediterranean vegetation species best suited for renaturalization of terminal-phase municipal solid waste (MSW) landfills in Puglia (Southern Italy)

    Science.gov (United States)

    De Mei, Massimiliano; Di Mauro, Mariaida

    2006-07-01

    Natural recovery of worked-out or closed municipal solid waste (MSW) landfills is a current topic, but knowledge about the adaptability of Mediterranean vegetation species to such stressful conditions is still quite poor. Autochthonous plants were selected to withstand the stresses such as hot climate and drought typical of Mediterranean areas; this characteristic potentially allows the plants an easier, efficient adaptation. Our aim was to provide information in order to obtain an adequate quality of environmental renewal of a landfill and a reduced management cost while ensuring rehabilitation to an acceptable naturalistic state. The investigation lasted 3 years; some Mediterranean scrub native plant species were selected and monitored in their morphological (total and relative height, basal diameter, number of inter-nodes) and physiological (photosynthetic rate and water potential) activity. In order to test dependence on CO 2 concentration, different meteorological parameters were also monitored. Ceratonia siliqua, Phillyrea latifolia, Olea europaea and Quercus ilex showed considerable adaptability, reacting positively to every improvement in environmental conditions, particularly those of a meteorological nature. Survival and growth was satisfactory in Hedysarum coronarium, Medicago sativa, Lotus corniculatus, Rosmarinus officinalis, Myrtus communis and Viburnum tinus. Fraxinus ornus and Acer campestre suffered stress during the summer dry period and recovered quickly when atmospheric conditions improved. A drop irrigation system to ensure a satisfactory soil moisture during summer dry periods was the fundamental element for survival.

  16. Quantification of methane emissions from danish landfills

    DEFF Research Database (Denmark)

    Scheutz, Charlotte; Mønster, Jacob; Kjeldsen, Peter

    2013-01-01

    Whole-landfill methane emission was quantified using a tracer technique that combines controlled tracer gas release from the landfill with time-resolved concentration measurements downwind of the landfill using a mobile high-resolution analytical instrument. Methane emissions from 13 Danish...... landfills varied between 2.6 and 60.8 kg CH4 h–1. The highest methane emission was measured at the largest (in terms of disposed waste amounts) of the 13 landfills, whereas the lowest methane emissions (2.6-6.1 kgCH4 h–1) were measured at the older and smaller landfills. At two of the sites, which had gas...... collection, emission measurements showed that the gas collection systems only collected between 30-50% of the methane produced (assuming that the produced methane equalled the sum of the emitted methane and the collected methane). Significant methane emissions were observed from disposed shredder waste...

  17. System dynamics of the competition of municipal solid waste to landfill, electricity, and liquid fuel in California

    Energy Technology Data Exchange (ETDEWEB)

    Westbrook, Jessica; Malczynski, Leonard A.; Manley, Dawn Kataoka

    2014-03-01

    A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

  18. Antibiotic resistance of Escherichia coli in leachates from municipal solid waste landfills: comparison between semi-aerobic and anaerobic operations.

    Science.gov (United States)

    Threedeach, Simanata; Chiemchaisri, Wilai; Watanabe, Toru; Chiemchaisri, Chart; Honda, Ryo; Yamamoto, Kazuo

    2012-06-01

    A bacterial susceptibility test to 31 antibiotics was conducted on the 80 isolated Escherichia coli from the leachates of the landfills in two different operations: semi-aerobic (SL) and anaerobic (AL) landfills. The average population of E. coli from SL and AL leachates were 2.2 × 10(4) and 9.4 × 10(3)CFU/100ml, respectively. Between 80.8% and 87.5% of the E. coli isolated from both leachates as resistant to the tested antibiotics and high resistances were found to doxycycline (53.8-68.8%), cephalothin (57.5-61.3%), tetracycline (51.3-67.5%) and minocycline (37.5-46.3%). The percentages of isolates resistant to most antibiotics were higher in the AL leachate. The exception was nitrofurantoin to which the isolates from the SL were highly resistant. E. coli from both sources showed similarly high susceptibilities (90-100%) to aminoglycosides, quinolones, chloramphenicol, sulfonamide and some new beta-lactams. The difference in available oxygen in landfills could affect E. coli susceptibility to antibiotics in leachates.

  19. Chemical recycle of plastics waste; Hai purasuchikku no kemikaru risaikuru

    Energy Technology Data Exchange (ETDEWEB)

    Miyake, A. [Sumitomo Chemical Co. Ltd., Osaka (Japan)

    1997-11-01

    Chemical recycling of the wasted plastics contains from regeneration to monomer as a constructing component in the case of single element polymer to conversion to fuel oil through thermal decomposition of the mixed wasted plastics and application to chemical raw material. Polymethyl methacrylate (PMMA) decomposes to methylmethacrylate (MMA) monomer with high selection rate at max temperature of 400{+-}50degC. The Mitsubishi Rayon Co., Ltd. Signed a cooperative development contract on the recycling technique of PMMA The ICI., Ltd., Great Britain. Depolymerization technique of Polyethylene terephthalate (PET) is already used actually on methanolysis with Coca-Cola Corp. (Hoechst-Celanese Corp.) and glycolysis with Pepsi-Cola Corp. (Goodyear Inc.). The chemical recycle due to thermal decomposition of the mixed wasted plastics is established as a technique of gasification of the mixed wasted plastics to generate methanol in Japan by the Mitsubishi Heavy Ind., Ltd., and is operated in a pilot plant of 2 ton/day. Here was summarized on these trends in and out of Japan. 29 refs., 5 figs., 4 tab.

  20. Endogenous mitigation of H2S inside of the landfills.

    Science.gov (United States)

    Fang, Yuan; Zhong, Zhong; Shen, Dongsheng; Du, Yao; Xu, Jing; Long, Yuyang

    2016-02-01

    Vast quantities of hydrogen sulfide (H2S) emitted from landfill sites require urgent disposal. The current study focused on source control and examined the migration and conversion behavior of sulfur compounds in two lab-scale simulated landfills with different operation modes. It aimed to explore the possible strategies and mechanisms for H2S endogenous mitigation inside of landfills during decomposition. It was found that the strength of H2S emissions from the landfill sites was dependent on the municipal solid waste (MSW) degradation speed and vertical distribution of sulfide. Leachate recirculation can shorten both the H2S influence period and pollution risk to the surrounding environment. H2S endogenous mitigation may be achieved by chemical oxidation, biological oxidation, adsorption, and/or precipitation in different stages. Migration and conversion mainly affected H2S release behavior during the initial stabilization phase in the landfill. Microbial activities related to sulfur, nitrogen, and iron can further promote H2S endogenous mitigation during the high reducing phase. Thus, H2S endogenous mitigation can be effectively enhanced via control of the aforementioned processes.

  1. 膨润土对垃圾填埋场天然土壤衬垫的改性研究%Modified Study on Liner of Natural Soil in Waste Landfill Sites Using Bentonite

    Institute of Scientific and Technical Information of China (English)

    邓寅生; 黄研; 李武斐; 刘少辉

    2011-01-01

    Through adding different proportional bentonite to natural soil in waste landfill sites, carrying out the osmosis test by varying hydraulic head after densifying the soil, the results showed that optimal proportion of modified soil of bentonite was 8%.The permeability coefficient of modified soil of bentonite after densification was less than 1.0×l0-7 cm/s, it conforms to Standard for Pollution Control on the Landfill Site of Municipal Solid Waste (GB 16889-2008), and it can be taken as landfill liner for waste landfill sites.%通过对垃圾填埋场天然土壤中添加不同比例的膨润土,击实后进行变水头渗透试验得出膨润土改性土样的最佳配比为8%.改性土样压实膨润土的渗透系数≤1.0×10-7 cm/s,符合GB 16889-2008生活垃圾填埋场污染控制标准,可作为填埋场防渗衬层.

  2. Chemical characterization of emissions from a municipal solid waste treatment plant.

    Science.gov (United States)

    Moreno, A I; Arnáiz, N; Font, R; Carratalá, A

    2014-11-01

    Gaseous emissions are an important problem in municipal solid waste (MSW) treatment plants. The sources points of emissions considered in the present work are: fresh compost, mature compost, landfill leaks and leachate ponds. Hydrogen sulphide, ammonia and volatile organic compounds (VOCs) were analysed in the emissions from these sources. Hydrogen sulphide and ammonia were important contributors to the total emission volume. Landfill leaks are significant source points of emissions of H2S; the average concentration of H2S in biogas from the landfill leaks is around 1700 ppmv. The fresh composting site was also an important contributor of H2S to the total emission volume; its concentration varied between 3.2 and 1.7 ppmv and a decrease with time was observed. The mature composting site showed a reduction of H2S concentration (<0.1 ppmv). Leachate pond showed a low concentration of H2S (in order of ppbv). Regarding NH3, composting sites and landfill leaks are notable source points of emissions (composting sites varied around 30-600 ppmv; biogas from landfill leaks varied from 160 to 640 ppmv). Regarding VOCs, the main compounds were: limonene, p-cymene, pinene, cyclohexane, reaching concentrations around 0.2-4.3 ppmv. H2S/NH3, limonene/p-cymene, limonene/cyclohexane ratios can be useful for analysing and identifying the emission sources.

  3. Application of Deuterium and Oxygen-18 to Trace Leachate Movement in Bantar Gebang Sanitary Landfill

    Directory of Open Access Journals (Sweden)

    E.R. Pujiindiyati

    2011-08-01

    Full Text Available Bantar Gebang landfill was constructed in 1986 with total area of 108 ha and approximately 6000 ton/day solid waste is disposed to this landfill. Mostly, the people living surrounding landfill get afraid of impact of the hazardous chemicals produced by waste disposal to their health. The purpose of this investigation was to study the migration of leachate to Cibitung River water and shallow groundwaters near to the river. It is possible to be done because chemical contents and isotopic characteristics of municipal landfill leachate are unique, relative to aqueous media in the most natural environments. Laser absorption method developed by the LGR (Los Gatos Research was used to measure absolute abundances of 2HHO, HH18O and HHO in a number of water samples. In-situ measurements were also conducted as an additional parameter besides their isotopes. The δ2H of the H2O in landfill leachate was significantly enriched, with values of - 22.6 ‰ to + 4.3 ‰. This deuterium enrichment was undoubtedly due to the extensive production of microbial methane within the limited reservoir of the landfill. However, the enriched deuterium value in leachate was not detected in the river which still had depleted values. It was probably caused by the amount of natural water in the river was comparatively large, with respect to limited leachate discarded to the river.The electrical conductivity of the leachate was higher (3200 to 7600 S and the decreasing values were still monitored in the river to approximately 12 km after streaming the landfills. The effect of the high electrical conductivity and enriched deuterium of leachate was not clearly indicated in the groundwater samples which still represented the local precipitation recharge, except a monitoring well located in Bantar Gebang landfill area which has an indication of leachate contamination.

  4. Potential for leaching of heavy metals in open-burning bottom ash and soil from a non-engineered solid waste landfill.

    Science.gov (United States)

    Gwenzi, Willis; Gora, Dorcas; Chaukura, Nhamo; Tauro, Tonny

    2016-03-01

    Bottom ash from open-burning of municipal waste practised in developing countries poses a risk of heavy metal leaching into groundwater. Compared to incineration ash, there is limited information on heavy metal leaching from open-burning ash and soil from non-engineered landfills. Batch and column experiments were conducted to address three specific objectives; (1) to determine aqua regia extractable concentrations of heavy metals in fresh ash, old ash and soil from beneath the landfill, (2) to determine the relationship between heavy metal leaching, initial and final pH of leaching solution, and aqua regia extractable concentrations, and (3) to determine the breakthrough curves of heavy metals in ashes and soil. Aqua regia extractable concentrations of Cd, Zn, Mn, Cu, Ni and Pb were significantly higher (p heavy metals were not correlated with aqua regia extractable concentrations. Final pH of leachate rebounded to close to original pH of the material, suggesting a putative high buffering capacity for all materials. Both batch and column leaching showed that concentrations of leached heavy metals were disproportionately lower (heavy metals was further evidenced by sigmoidal breakthrough curves. Heavy metal retention was attributed to precipitation, pH-dependent adsorption and formation of insoluble organo-metallic complexes at near-neutral to alkaline pH. Overall, the risk of heavy metal leaching from ash and soil from the waste dump into groundwater was low. The high pH and the presence of Zn, Fe, Mn and Cu make ash an ideal low-cost liming material and source of micronutrients particularly on acidic soils prevalent in sub-Saharan Africa.

  5. Features of soil microbial groups in the area Kilmezsky landfill dumping of toxic chemicals ( Kirov Region

    Directory of Open Access Journals (Sweden)

    Berezin Grigory Ivanovich

    2016-06-01

    Full Text Available Under the influence of pesticides a transformation of soil microbial complexes occurs. In the area of Kilmezsky dumping of toxic chemicals (Kirov Region the species composition of soil phototrophes and quantitative characteristics of soil algo-cyano-mycological complexes change as a result of chronic exposure to pesticides . The content of cyanobacteria in the structure of phototrophic systems and the degree of mikromycets populations melanization can be used as bioindicators of soil contamination complementing the set of indicators based on certified laboratory methods of biotesting.

  6. COMMERCIAL-SCALE AEROBIC-ANAEROBIC BIOREACTOR LANDFILL OPERATIONS

    Science.gov (United States)

    A sequential aerobic-anaerobic treatment system has been applied at a commercial scale (3,000 ton per day) municipal solid waste landfill in Kentucky, USA since 2001. In this system, the uppermost layer of landfilled waste is aerated and liquid waste including leachate, surface w...

  7. Characterization of Airborne Particles in an Electronic Waste Recycling Facility and Their Toxicity Assessment

    Science.gov (United States)

    Improper disposal of electronic waste (e-waste) can lead to release of toxic chemicals into the environment and also may pose health risks. Thus, recycling e-waste, instead of landfilling, is considered to be an effective way to reduce pollutant release and exposure. However, lit...

  8. 75 FR 8986 - Draft Supplemental Environmental Impact Statement for the Proposed Campo Regional Landfill...

    Science.gov (United States)

    2010-02-26

    ... constructing and operating a solid waste landfill, recycling facility, and composting facility. In 1989, the... be required to comply with 40 CFR part 258 (Criteria for Municipal Solid Waste Landfills). Because... 258. For municipal solid waste landfills in Indian Country, the EPA must makes...

  9. Hydrogeology and ground-water-quality conditions at the Emporia- Lyon County Landfill, eastern Kansas, 1988

    Science.gov (United States)

    Myers, N.C.; Bigsby, P.R.

    1990-01-01

    Hydrogeology and water-quality conditions at the Emporia-Lyon County Landfill, eastern Kansas, were investigated from April 1988 through April 1989. Potentiometric-surface maps indicated groundwater movement from the northeast and northwest towards the landfill and then south through the landfill to the Cottonwood River. The maps indicate that during periods of low groundwater levels, groundwater flows northward in the north-west part of the landfill, which may have been induced by water withdrawal from wells north of the landfill or by water ponded in waste lagoons south and west of the landfill. Chemical analysis of water samples from monitoring wells upgradient and downgradient of the landfill indicate calcium bicarbonate to be the dominant water type. No inorganic or organic chemical concentrations exceeded Kansas or Federal primary drinking-water standards. Kansas secondary drinking-water standards were equaled or exceeded, however, in water from some or all wells for total hardness, dissolved solids, iron, and manganese. Water from one upgradient well contained larger concentrations of dissolved oxygen and nitrate, and smaller concentrations of bicarbonate, alkalinity, ammonia, arsenic, iron, and manganese as compared to all other monitoring wells. Results of this investigation indicate that groundwater quality downgradient of well MW-2 has increased concentrations of some inorganic and organic compounds. Due to the industrial nature of the area and the changing directions of groundwater flow, it is not clear what the source of these compounds might be. Long-term monitoring, additional wells, and access to nearby waste lagoons and waste-lagoon monitoring wells would help define the sources of increased inorganic and organic compounds. (USGS)

  10. Method for fractional solid-waste sampling and chemical analysis

    DEFF Research Database (Denmark)

    Riber, Christian; Rodushkin, I.; Spliid, Henrik

    2007-01-01

    to repeated particle-size reduction, mixing, and mass reduction until a sufficiently small but representative sample was obtained for digestion prior to chemical analysis. The waste-fraction samples were digested according to their properties for maximum recognition of all the studied substances. By combining...... four subsampling methods and five digestion methods, paying attention to the heterogeneity and the material characteristics of the waste fractions, it was possible to determine 61 substances with low detection limits, reasonable variance, and high accuracy. For most of the substances of environmental...... concern, the waste-sample concentrations were above the detection limit (e.g. Cd gt; 0.001 mg kg-1, Cr gt; 0.01 mg kg-1, Hg gt; 0.002 mg kg-1, Pb gt; 0.005 mg kg-1). The variance was in the range of 5-100%, depending on material fraction and substance as documented by repeated sampling of two highly...

  11. Integrated modeling and up-scaling of landfill processes and heterogeneity using stochastic approach

    OpenAIRE

    Bun, A.; Heimovaara, T.J.; Baviskar, S.M.; Van Turnhout, A.G.; Konstantaki, L.A.

    2012-01-01

    Municipal solid waste landfills are a very complex and heterogeneous systems. The waste in a landfill body is a heterogeneous mixture of a wide range of materials containing high levels of organic matter, high amounts of salts and a wide range of different organic and inorganic substances, such as heavy metals and organic solvents. A range of processes of different nature occur within landfills. Bio-geochemical processes in a landfill body lead to the development of landfill gases, a mixture ...

  12. Chemical Disposition of Plutonium in Hanford Site Tank Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jones, Susan A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-05-07

    This report examines the chemical disposition of plutonium (Pu) in Hanford Site tank wastes, by itself and in its observed and potential interactions with the neutron absorbers aluminum (Al), cadmium (Cd), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and sodium (Na). Consideration also is given to the interactions of plutonium with uranium (U). No consideration of the disposition of uranium itself as an element with fissile isotopes is considered except tangentially with respect to its interaction as an absorber for plutonium. The report begins with a brief review of Hanford Site plutonium processes, examining the various means used to recover plutonium from irradiated fuel and from scrap, and also examines the intermediate processing of plutonium to prepare useful chemical forms. The paper provides an overview of Hanford tank defined-waste–type compositions and some calculations of the ratios of plutonium to absorber elements in these waste types and in individual waste analyses. These assessments are based on Hanford tank waste inventory data derived from separately published, expert assessments of tank disposal records, process flowsheets, and chemical/radiochemical analyses. This work also investigates the distribution and expected speciation of plutonium in tank waste solution and solid phases. For the solid phases, both pure plutonium compounds and plutonium interactions with absorber elements are considered. These assessments of plutonium chemistry are based largely on analyses of idealized or simulated tank waste or strongly alkaline systems. The very limited information available on plutonium behavior, disposition, and speciation in genuine tank waste also is discussed. The assessments show that plutonium coprecipitates strongly with chromium, iron, manganese and uranium absorbers. Plutonium’s chemical interactions with aluminum, nickel, and sodium are minimal to non-existent. Credit for neutronic interaction of plutonium with these absorbers

  13. MONITORING APPROACHES FOR BIOREACTOR LANDFILLS - Report

    Science.gov (United States)

    Experimental bioreactor landfill operations at operating Municipal Solid Waste (MSW) landfills can be approved under the research development and demonstration (RD&D) provisions of 30CFR 258.4. To provide a basis for consistent data collection for future decision-making in suppor...

  14. Proposal Of Landfill Site Model In The Particular Territory

    Directory of Open Access Journals (Sweden)

    Stopka Ondrej

    2015-12-01

    Full Text Available Nowadays, waste logistics is a relevant element within the worldwide logistics system. This paper is focused on the proposal of the appropriate model of landfill site for disposal of municipal waste. This issue refers to waste logistics in urban areas. In this regard, three different alternative models of landfill sites are considered. Landfill site model can significantly influence the waste management productivity and effectiveness of the enterprise. In the paper, one of the decision-making problem methods is utilized. This particular method enables to assess each model of landfill site in relation to each of the specified criterion and order the models according to the achieved results.

  15. Simultaneous efficient removal of high-strength ammonia nitrogen and chemical oxygen demand from landfill leachate by using an extremely high ammonia nitrogen-resistant strain.

    Science.gov (United States)

    Yu, Dahai; Yang, Jiyu; Fang, Xuexun; Ren, Hejun

    2015-01-01

    Bioaugmentation is a promising technology for pollutant elimination from stressed environments, and it would provide an efficient way to solve challenges in traditional biotreatment of wastewater with high strength of ammonia nitrogen (NH4(+)-N). A high NH4(+)-N-resistant bacteria strain, identified as Bacillus cereus (Jlu BC), was domesticated and isolated from the bacteria consortium in landfill leachate. Jlu BC could survive in 100 g/L NH4(+)-N environment, which indicated its extremely high NH4(+)-N tolerance than the stains found before. Jlu BC was employed in the bioaugmented system to remove high strength of NH4(+)-N from landfill leachate, and to increase the removal efficiency, response surface methodology (RSM) was used for optimizing bioaugmentation degradation conditions. At the optimum condition (initial pH 7.33, 4.14 days, initial chemical oxygen demand [COD] concentration [18,000 mg/L], 3.5 mL inoculated domesticated bacteria strain, 0.3 mg/mL phosphorus supplement, 30 °C, and 170 rpm), 94.74 ± 3.8% removal rate of NH4(+)-N was obtained, and the experiment data corresponded well with the predicted removal rate of the RSM models (95.50%). Furthermore, COD removal rate of 81.94 ± 1.4% was obtained simultaneously. The results presented are promising, and the screened strain would be of great practical importance in mature landfill leachate and other NH4(+)-N enrichment wastewater pollution control.

  16. State waste discharge permit application, 200-E chemical drain field

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect ground would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE 91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. This document presents the State Waste Discharge Permit (SWDP) application for the 200-E Chemical Drain Field. Waste water from the 272-E Building enters the process sewer line directly through a floor drain, while waste water from the 2703-E Building is collected in two floor drains, (north and south) that act as sumps and are discharged periodically. The 272-E and 2703-E Buildings constitute the only discharges to the process sewer line and the 200-E Chemical Drain Field.

  17. Method of waste stabilization with dewatered chemically bonded phosphate ceramics

    Science.gov (United States)

    Wagh, Arun; Maloney, Martin D.

    2010-06-29

    A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100.degree. C.-200.degree. C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry. Another aspect of the invention is a direct anyhydrous CBPC fabrication method wherein water is removed from the slurry by heating and mixing the slurry while allowing the slurry to cure. Additional aspects of the invention are ceramic matrix waste forms prepared by the methods disclosed above.

  18. Waste dumps rehabilitation measures based on physico-chemical analyses in Zăghid mining area (Sălaj County, Romania

    Directory of Open Access Journals (Sweden)

    Ildiko M. Varga

    2011-08-01

    Full Text Available The present study deals with an abandoned coal mine from Zăghid area, North-WesternTransylvanian Basin (Sălaj County. The mining activity was stopped in 2005, without any attempt ofecological rehabilitation of the mined area and especially of the waste dumps left behind. The proposedrehabilitation models are based on some physical-chemical analyses of soil and waste samples (e.g. pH,EC, Salinity, humidity, porosity, density, plasticity, organic substances, mineralogical composition, heavymetals. Erosion map has been drawn based on the determined mineralogical composition (accordingSTAS 1913/5-85 – using Galton curve of tailings and the soil type. The values obtained for moisture andplasticity have been used to determine the ideal general inclination angle of the landfill systems in thestudied perimeter. Through chemical analysis, heavy metals like Ni and Cu have been identified, as themain pollution factors for surface and underground water. Therefore, the concentration of heavy metalsin the waters from Zăghid area is high in the water bodies, which are formed on waste dumps, but alsoin the mine water. This analysis is useful in establishing the actual state of the waste dumps and theircontent and the negative effects, which exercise on the environment in order to select the rehabilitationmodel for the waste dumps from Zăghid mining area. The main measures consist in: waste dumpsleveling, soil remediation, perennial plants culture and acid mine water decontamination.

  19. The removal of COD and color by Fenton oxidation from leachate of Erzurum municipal solid waste landfill

    Science.gov (United States)

    Kocakaplan, Nihal; Ertugay, Neşe; Malkoç, Emine

    2016-04-01

    The optimal conditions for treatment of leachate were determined as pH = 2.5, Fe2+= 2 mg/L and H2O2= 100 mg/L. Under the optimal conditions, approximately 90% color (at 620 nm), 84% color (at 525 nm), 74% color (at 436 nm) and 47.8% COD removal efficiency from leachate were achieved after 20 min of reaction. Depending on the results obtained experiments, Fenton process has been used successfully in removal of COD and color in landfill leachate.

  20. Radiological, physical, and chemical characterization of transuranic wastes stored at the Idaho National Engineering Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Apel, M.L.; Becker, G.K.; Ragan, Z.K.; Frasure, J.; Raivo, B.D.; Gale, L.G.; Pace, D.P.

    1994-03-01

    This document provides radiological, physical and chemical characterization data for transuranic radioactive wastes and transuranic radioactive and hazardous (i.e., mixed) wastes stored at the Idaho National Engineering Laboratory and considered for treatment under the Private Sector Participation Initiative Program (PSPI). Waste characterization data are provided in the form of INEL Waste Profile Sheets. These documents provide, for each content code, information on waste identification, waste description, waste storage configuration, physical/chemical waste composition, radionuclide and associated alpha activity waste characterization data, and hazardous constituents present in the waste. Information is provided for 139 waste streams which represent an estimated total volume of 39,380{sup 3} corresponding to a total mass of approximately 19,000,000 kg. In addition, considerable information concerning alpha, beta, gamma, and neutron source term data specific to Rocky Flats Plant generated waste forms stored at the INEL are provided to assist in facility design specification.

  1. Landfill Barrier-Overview and Prospect

    Institute of Scientific and Technical Information of China (English)

    Zheng Liange; Zhao Yongsheng

    2000-01-01

    Landfill is the primary method of waste disposal. The increasing attention focused on the effect of landfill on environment prompts the development of environmental sound landfill system. As the key parts of landfill, the barrier system can provide impermeabilization of leachate and prevent biogas from escaping intotheenvironment. In recent years, the technology pertaining the barrier system developed rapidly. In this paper, new materials used in liners and new concept of barrier construction are reviewed; the mechanisms of leachate through clay liner and geomembrane, the calculation of leaks through liner and the effect of freezing/thaw on liner are discussed.

  2. Characterization and treatment of municipal landfill leachates

    Energy Technology Data Exchange (ETDEWEB)

    Welander, Ulrika

    1998-03-01

    The efficiency of different leachate treatment methods for the removal of refractory organic compounds and ammonium-nitrogen was investigated. The methods evaluated were nitrification, denitrification, adsorption onto activated carbon, precipitation by ferric chloride or aluminum sulphate and oxidation by ozone or Fenton`s reagent. Furthermore, analyses were performed on leachates from municipal landfills of different kinds (a biocell deposit, a conventional mixed landfill containing household and industrial waste, and an ash deposit) in order to study the leachate composition in regard to various hydrophobic organic compounds as a function of the type of waste deposited. The results suggested that, in order to achieve a satisfactory removal of both ammonium-nitrogen and organic substances, the treatment of methanogenic leachates should be performed through a process combining biological and physical or chemical stages. When the biological treatment was not combined with a physical or a chemical process a COD removal of only 20-30% was achieved, whereas the toxicity of the leachate was significantly reduced. In contrast, a combination of nitrification and either adsorption onto activated carbon or oxidation using Fenton`s reagent resulted in a COD removal of about 80%, although certain specific organic compounds, such as phthalates, were unaffected by the treatment. A combination of nitrification, precipitation by ferric chloride and adsorption onto activated carbon removed 96% of the TOC. The analyses of leachates from municipal landfills of different types showed the leachate from the ash deposit to contain more C4-substituted phenols than the other leachates and to likewise contain alkanes, which the others did not 154 refs, 12 figs, 4 tabs

  3. Consecutive anaerobic-aerobic treatment of the organic fraction of municipal solid waste and lignocellulosic materials in laboratory-scale landfill-bioreactors.

    Science.gov (United States)

    Pellera, Frantseska-Maria; Pasparakis, Emmanouil; Gidarakos, Evangelos

    2016-10-01

    The scope of this study is to evaluate the use of laboratory-scale landfill-bioreactors, operated consecutively under anaerobic and aerobic conditions, for the combined treatment of the organic fraction of municipal solid waste (OFMSW) with two different co-substrates of lignocellulosic nature, namely green waste (GW) and dried olive pomace (DOP). According to the results such a system would represent a promising option for eventual larger scale applications. Similar variation patterns among bioreactors indicate a relatively defined sequence of processes. Initially operating the systems under anaerobic conditions would allow energetic exploitation of the substrates, while the implementation of a leachate treatment system ultimately aiming at nutrient recovery, especially during the anaerobic phase, could be a profitable option for the whole system, due to the high organic load that characterizes this effluent. In order to improve the overall effectiveness of such a system, measures towards enhancing methane contents of produced biogas, such as substrate pretreatment, should be investigated. Moreover, the subsequent aerobic phase should have the goal of stabilizing the residual materials and finally obtain an end material eventually suitable for other purposes.

  4. Scaling of ammonia stripping towers in the treatment of groundwater polluted by municipal solid waste landfill leachate: study of the causes of scaling and its effects on stripping performance

    Directory of Open Access Journals (Sweden)

    Paolo Viotti

    2015-04-01

    Full Text Available This paper documents the causes of the scaling of stripping towers used for the treatment of groundwater polluted by the leachate from an old municipal solid waste (MSW landfill in northern Italy. The effects of the scaling on the stripping performance are also reported. The whole process consists of a coagulation-flocculation pre-treatment at pH > 11, followed by an ammonia stripping stage, after heating the water to 38°C in order to improve removal efficiency. The stripped ammonia is recovered by absorption with sulfuric acid, producing a 30% solution of ammonium sulfate (reused as a base fertilizer. The effluent air stream is recirculated to the stripping towers (closed loop systems in order to avoid an excessive temperature drop inside the packings, mainly in winter, with consequent loss of efficiency and risk of icing. The progressive scaling of the packing has resulted in a loss of ammonia removal efficiency from an initial value of 98% (clean packing down to 80% after six months of continuous operation, necessitating a chemical cleaning. Optimum conditions for design and operation of the stripping process are also documented.

  5. Landfills in the Western United States

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Locations of landfills and waste transfer stations in 11 western states. Data was obtained from state and federal agencies in GIS, tabular, and map format.

  6. Two Domain Flow Method for Leachate PredictionThrough Municipal Solid Waste Layers in Al–Amari Landfill Site

    Directory of Open Access Journals (Sweden)

    Hayder Mohammed Abdul–Hameed

    2008-01-01

    Full Text Available Existing leachate models over–or underestimates leachate generation by up to three orders of magnitude. Practical experiments show that channeled flow in waste leads to rapid discharge of large leachate volumes and heterogeneous moisture distribution. In order to more accurately predict leachate generation, leachate models must be improved. To predict moisture movement through waste, the two–domain PREFLO, are tested. Experimental waste and leachate flow values are compared with model predictions. When calibrated with experimental parameters, the PREFLO provides estimates of breakthrough time. In the short term, field capacity has to be reduced to 0.12 and effective storage and hydraulic conductivity of the waste must be increased to 0.12 and effective storage and hydraulic conductivity of the wasted must be increased to 0.2 and 2.2 cm/s respectively. In the long term, a new modeling approach must be developed to adequately describe the moisture movement mechanisms.

  7. ENHANCED CHEMICAL CLEANING: A NEW PROCESS FOR CHEMICALLY CLEANING SAVANNAH RIVER WASTE TANKS

    Energy Technology Data Exchange (ETDEWEB)

    Ketusky, E; Neil Davis, N; Renee Spires, R

    2008-01-17

    The Savannah River Site (SRS) has 49 high level waste (HLW) tanks that must be emptied, cleaned, and closed as required by the Federal Facilities Agreement. The current method of chemical cleaning uses several hundred thousand gallons per tank of 8 weight percent (wt%) oxalic acid to partially dissolve and suspend residual waste and corrosion products such that the waste can be pumped out of the tank. This adds a significant quantity of sodium oxalate to the tanks and, if multiple tanks are cleaned, renders the waste incompatible with the downstream processing. Tank space is also insufficient to store this stream given the large number of tanks to be cleaned. Therefore, a search for a new cleaning process was initiated utilizing the TRIZ literature search approach, and Chemical Oxidation Reduction Decontamination--Ultraviolet (CORD-UV), a mature technology currently used for decontamination and cleaning of commercial nuclear reactor primary cooling water loops, was identified. CORD-UV utilizes oxalic acid for sludge dissolution, but then decomposes the oxalic acid to carbon dioxide and water by UV treatment outside the system being treated. This allows reprecipitation and subsequent deposition of the sludge into a selected container without adding significant volume to that container, and without adding any new chemicals that would impact downstream treatment processes. Bench top and demonstration loop measurements on SRS tank sludge stimulant demonstrated the feasibility of applying CORD-UV for enhanced chemical cleaning of SRS HLW tanks.

  8. 封场垃圾填埋场的治理与城市土地可持续利用%Remediation of Closed Waste Landfill Sites and Sustainable Utilization of Urban Land

    Institute of Scientific and Technical Information of China (English)

    李玲; 王颋军; 唐跃刚; 王卓理

    2013-01-01

    The status and existing problems of closed waste landfill sites in China were introduced.The feasibility of its remediation was analyzed from policy support,technological level and economic level.Finally the main land reuse types of closed waste landfill sites and its main influencing factors were summarized.%介绍了我国封场填埋场现状和目前存在主要问题,从政策支持力度、技术水平及经济水平等方面分析了对其治理的可行性,总结填埋场封场治理后的主要土地利用类型及其主要影响因素.

  9. Impact to groundwater resources by landfill foundry industries waste in Tandil, Buenos Aires, Argentina. A preliminary study; Impacto al recurso hidrico subterraneo por vertedero de residuos de industrias de fundicion en Tandil, Buenos Aires, Argentina. Un estudio preliminar

    Energy Technology Data Exchange (ETDEWEB)

    Miguel, R. E.; Ruiz de Galarreta, V. A.; Banda Noriega, R. B.

    2009-07-01

    In Tandil city, in Buenos Aires province, Argentina, the foundry industry is one of the most important production lines. The waste generated by these industries has historically been disposed as fill material in pit quarries and brick works of the likelihood that some of his constituents leach contacting the underground water resources. The aim of this paper is to present the preliminaries results hydrochemical and hydrodynamic study conducted in a landfill of waste foundry industries. The work is around developing a disposal site with the measurement of groundwater levels and taking water samples along an annual hydrological cycle (November 2007 - November 2008). The hydrodynamic analysis shows that the groundwater flow is from the west from a rocky area where high variance across the study area. Hydrochemistry in relation to concentrations of nitrate and electrical conductivity vary significantly upstream and downstream of the landfill. (Author) 9 refs.

  10. Assessing the market opportunities of landfill mining

    NARCIS (Netherlands)

    van der Zee, D.J.; Achterkamp, M.C.; de Visser, B.J.

    2004-01-01

    Long-term estimates make clear that the amount of solid waste to be processed at landfills in the Netherlands will sharply decline in coming years. Major reasons can be found in the availability of improved technologies for waste recycling and government regulations aiming at waste reduction. Conseq

  11. Assessing the opportunities of landfill mining

    NARCIS (Netherlands)

    Zee, D.J. van der; Achterkamp, M.C.; Visser, B.J. de

    2003-01-01

    Long-term estimates make clear that the amount of solid waste to be processed at landfills in the Netherlands will sharply decline in coming years. Major reasons can be found in the availability of improved technologies for waste recycling and government regulations aiming at waste reduction. Conseq

  12. Chitosan on Reducing Chemical Oxygen Demands in Laundry Waste Water

    Directory of Open Access Journals (Sweden)

    Tri Joko

    2016-09-01

    Full Text Available Laundry liquid waste contains several chemical substances in detergent raw materials such as phosphate, surfactants, ammonia, and total suspended solids. The existence of detergent in high concentrations and exceeds the quality standards that have been estabilished in a body of water can lead to cases of enviromental pollution in the form of increased turbidity an Chemical Oxygen Demands (COD levels. Therefore in order to maintain and to ensure the availabillity of water in terms of quality, it requires coagulation-flocculation process to laundry liquid waste before discharging into water bodies. This study aims to determine the decrease of COD levels and turbidity level in laundry liquid waste using chitosan coagulant in “X” laundry, Tembalang District, Semarang. The research is a quasi experimental study with pretest-posttest with control group research design with 6 times replication. The total samples are 60 in wich 24 tested for the levels of turbidity and 6 controls. The test results of Kruskal-Wallis with significance p-value < 0,05 indicates that dosage variation (p=0,000 gives different levels of COD and dosage variation (p=0,000 provide 755,97 mg/l and the advantage levels of turbidity before treatment was 516,20 NTU. The optimum dosage of chitosan coagulant is on the dose of 200 mg/l with the effectiveness decrease of COD levels and turbidity levels on 72,67% an 98,67% respectively.

  13. Pyrochlore as nuclear waste form. Actinide uptake and chemical stability

    Energy Technology Data Exchange (ETDEWEB)

    Finkeldei, Sarah Charlotte

    2015-07-01

    Radioactive waste is generated by many different technical and scientific applications. For the past decades, different waste disposal strategies have been considered. Several questions on the waste disposal strategy remain unanswered, particularly regarding the long-term radiotoxicity of minor actinides (Am, Cm, Np), plutonium and uranium. These radionuclides mainly arise from high level nuclear waste (HLW), specific waste streams or dismantled nuclear weapons. Although many countries have opted for the direct disposal of spent fuel, from a scientific and technical point of view it is imperative to pursue alternative waste management strategies. Apart from the vitrification, especially for trivalent actinides and Pu, crystalline ceramic waste forms are considered. In contrast to glasses, crystalline waste forms, which are chemically and physically highly stable, allow the retention of radionuclides on well-defined lattice positions within the crystal structure. Besides polyphase ceramics such as SYNROC, single phase ceramics are considered as tailor made host phases to embed a specific radionuclide or a specific group. Among oxidic single phase ceramics pyrochlores are known to have a high potential for this application. This work examines ZrO{sub 2} based pyrochlores as potential nuclear waste forms, which are known to show a high aqueous stability and a high tolerance towards radiation damage. This work contributes to (1) understand the phase stability field of pyrochlore and consequences of non-stoichiometry which leads to pyrochlores with mixed cationic sites. Mixed cationic occupancies are likely to occur in actinide-bearing pyrochlores. (2) The structural uptake of radionuclides themselves was studied. (3) The chemical stability and the effect of phase transition from pyrochlore to defect fluorite were probed. This phase transition is important, as it is the result of radiation damage in ZrO{sub 2} based pyrochlores. ZrO{sub 2} - Nd{sub 2}O{sub 3} pellets

  14. The Use of Chemical Modification of Polymer Waste for Obtaining Polymer Flocculants

    Institute of Scientific and Technical Information of China (English)

    W.W.Sulkowski; K.Nowak; A.Sulkowska; A.Wolin; ska; S.Malanka; W.M.Baldur; D.Pentak

    2007-01-01

    1 Results Chemical modification of polymer plastic wastes to useful products can be one of the way of effective waste plastics management (chemical recycling). Chemical modification of polymers and polymer plastic wastes can yield products with suitable physical and chemical properties. In consequence they can be used as polyelectrolytes[1]. The variety of pollutants, universality of various water and sewage treatment technologies, introduction of new water quality improved technologies have caused a gr...

  15. Comparison Of Four Landfill Gas Models Using Data From Four Danish Landfills

    DEFF Research Database (Denmark)

    Mønster, Jacob G.; Mou, Zishen; Kjeldsen, Peter

    2011-01-01

    , and to compare the four Danish landfill sites. The results show that three of the models generally give similar methane generation output. Only the LandGem model seems to give a much higher methane generation for Danish waste data, most likely due to a low organic fraction. Interpretation of the waste data......Data about type and quantity of waste disposed in four Danish landfills was collected and used on four different landfill gas generation models. This was done to compare the output data in order to evaluate the performance of the four landfill gas models when used on Danish waste types...... and the categorization of the waste play an important role in the methane prediction and combining the model predictions with whole site methane measurements would therefore be advised....

  16. Countermeasures of Environmental Management for Large-scale Landfill Sites after Closure: The Case of Laogang Domestic Waste Landfill Site in Shanghai%大型填埋场封场后环境管理对策研究——以上海市老港生活垃圾填埋场为例

    Institute of Scientific and Technical Information of China (English)

    邰俊

    2012-01-01

    以上海市老港生活垃圾填埋场1~3期为例,以历年常规监测数据为基础,分析了填埋场2007-2009年的污染物排放和环境质量动态变化情况,识别填埋场的现状环境问题,提出填埋场封场后应重视建立环境管理机构、制定环境管理制度、开展例行检查、实施长期监测等环境管理措施.%Taking Laogang Domestic Waste Landfill Site (Phase Ⅰ—Ⅲ) in Shanghai as an example, according to routine monitoring data, the pollutant emission and dynamic variation of environmental quality in the landfill site from 2007 to 2009 were analyzed, and the environmental problems in the landfill site were identified. Some measures of environmental management for the landfill sites after closure were put forward, such as establishing organization of environmental management, formulating policies of environmental management, implementing routine inspection and long-term monitoring.

  17. Landfill stabilization focus area: Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    Landfills within the DOE Complex as of 1990 are estimated to contain 3 million cubic meters of buried waste. The DOE facilities where the waste is predominantly located are at Hanford, the Savannah River Site (SRS), the Idaho National Engineering Laboratory (INEL), the Los Alamos National Laboratory (LANL), the Oak Ridge Reservation (ORR), the Nevada Test Site (NTS), and the Rocky Flats Plant (RFP). Landfills include buried waste, whether on pads or in trenches, sumps, ponds, pits, cribs, heaps and piles, auger holes, caissons, and sanitary landfills. Approximately half of all DOE buried waste was disposed of before 1970. Disposal regulations at that time permitted the commingling of various types of waste (i.e., transuranic, low-level radioactive, hazardous). As a result, much of the buried waste throughout the DOE Complex is presently believed to be contaminated with both hazardous and radioactive materials. DOE buried waste typically includes transuranic-contaminated radioactive waste (TRU), low-level radioactive waste (LLW), hazardous waste per 40 CFR 26 1, greater-than-class-C waste per CFR 61 55 (GTCC), mixed TRU waste, and mixed LLW. The mission of the Landfill Stabilization Focus Area is to develop, demonstrate, and deliver safer,more cost-effective and efficient technologies which satisfy DOE site needs for the remediation and management of landfills. The LSFA is structured into five technology areas to meet the landfill remediation and management needs across the DOE complex. These technology areas are: assessment, retrieval, treatment, containment, and stabilization. Technical tasks in each of these areas are reviewed.

  18. Impact of landfill leachate on the groundwater quality: A case study in Egypt

    Directory of Open Access Journals (Sweden)

    Magda M. Abd El-Salam

    2015-07-01

    Full Text Available Alexandria Governorate contracted an international company in the field of municipal solid waste management for the collection, transport and disposal of municipal solid waste. Construction and operation of the sanitary landfill sites were also included in the contract for the safe final disposal of solid waste. To evaluate the environmental impacts associated with solid waste landfilling, leachate and groundwater quality near the landfills were analyzed. The results of physico-chemical analyses of leachate confirmed that its characteristics were highly variable with severe contamination of organics, salts and heavy metals. The BOD5/COD ratio (0.69 indicated that the leachate was biodegradable and un-stabilized. It was also found that groundwater in the vicinity of the landfills did not have severe contamination, although certain parameters exceeded the WHO and EPA limits. These parameters included conductivity, total dissolved solids, chlorides, sulfates, Mn and Fe. The results suggested the need for adjusting factors enhancing anaerobic biodegradation that lead to leachate stabilization in addition to continuous monitoring of the groundwater and leachate treatment processes.

  19. Supercritical Water Process for the Chemical Recycling of Waste Plastics

    Science.gov (United States)

    Goto, Motonobu

    2010-11-01

    The development of chemical recycling of waste plastics by decomposition reactions in sub- and supercritical water is reviewed. Decomposition reactions proceed rapidly and selectively using supercritical fluids compared to conventional processes. Condensation polymerization plastics such as PET, nylon, and polyurethane, are relatively easily depolymerized to their monomers in supercritical water. The monomer components are recovered in high yield. Addition polymerization plastics such as phenol resin, epoxy resin, and polyethylene, are also decomposed to monomer components with or without catalysts. Recycling process of fiber reinforced plastics has been studied. Pilot scale or commercial scale plants have been developed and are operating with sub- and supercritical fluids.

  20. [Biological, chemical, and radiation factors in the classification of medical waste].

    Science.gov (United States)

    Rusakov, N V; Korotkova, G I; Orlov, A Iu; Kadyrov, D E

    2011-01-01

    The current classification of medical waste does not consider the sanitary-and-chemical hazard of epidemiologically dangerous and extremely dangerous medical waste (classes B and C). According to the results of the studies performed, the authors propose the improved classification of medical waste, which makes it possible to take into account not only infectious, radiation, and toxicological, but also sanitary-and-chemical hazards (toxicity, carcinogenicity, mutagenicity, and biological activity) of medical waste.

  1. LEACHATE CLOGGING ASSESSMENT OF GEOTEXTILE AND SOIL LANDFILL FILTERS

    Science.gov (United States)

    The liquids management strategy for any municipal or hazardous waste landfill requires a knowledgeable design strategy for the leachate collection system located at the base of the waste mass. Such leachate collection systems generally consist of sumps, perforated pipes, drainag...

  2. Quantification of methane emissions from 15 Danish landfills using the mobile tracer dispersion method

    DEFF Research Database (Denmark)

    Mønster, Jacob; Samuelsson, Jerker; Kjeldsen, Peter

    2015-01-01

    biocover installed. Landfills with gas collection and recovery systems had a recovery efficiency of 41-81%. Landfills where shredder waste was deposited showed significant methane emissions, with the largest emission from newly deposited shredder waste. The average methane emission from the landfills...

  3. Application of urban waste water sludge in revegetation of sanitary landfills; Aplicacion de lodos de depuradora procedentes de aguas residuales urbanas en la revegetacion de vertederos de RSU (II)

    Energy Technology Data Exchange (ETDEWEB)

    Ingelmo Sanchez, F.; Garcia Camarero, J.; Morenilla Martinez, J. J.; Bernacer Bonora, I.; Herrero Chamorro, O.; Amores Blasco, S.

    2000-07-01

    The use of forest soil for re vegetating sealed urban landfills is a practice leading to economic and environmental problems. Recently, it has been demonstrated a suitable technique for minimizing soil needs in the re-vegetation of a closed urban landfill which, the layer of fertile soil usually added for plants to settle and develop in such degraded substrate is replaced by a layer of the degraded soil amended with urban anaerobic sewage sludges. In this work we expose the firsts results of a pilot project for the re-vegetation with this procedure of a closed landfill of municipal solid wastes managed by the company Gestion Integral de Residuos in a collaborative research among the Centro de Investigaciones sobre Desertificacion, the Entidad Publica de Saneamiento de Aguas Residuales de la Comunidad Valenciana and the company Depuracion de Aguas del Mediterraneo. The closed landfill has a surface of 2,6 ha and its re-vegetation will be carried out by introducing native plants (annuals, busch and trees) after incorporation into the degraded soil of the anaerobic sewage sludge at the single dose of 60 tn/ha. (Author) 3 refs.

  4. The use of sewage sludges from waste water treatment plants for re-vegetation of sanitary landfills; Aplicacion de lodos de depuradora procedentes de aguas residuales urbanas en la revegetacion de vertederos de RSU

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, F. I.; Camarero, J. G.; Morenilla Martinez, J. J.; Bernacer Bonora, I.; Herrero Chamorro, O.; Amores Blasco, S.; Fernandez, C.; Codoner, M. A.

    1999-08-01

    The use of forest soil for re vegetating sealed urban landfills is a practice leading to economic and environmental problems. Recently, it has been demonstrated a suitable technique for minimizing soil needs in re-vegetation of closed urban landfill in which, the layer of fertile soil usually added for plants to settle and develop in such degraded substrate is replaced by a layer of the degraded soil amended with anaerobic sewage sludge. In this work we expose the phases and the design for the implementation of a pilot project for the re-vegetation with this procedure of a closed landfill of municipal solid wastes managed by GIRSA, in a collaborative research between CIDE (CSIC-UVEG-GV), Entidad Publica de Saneamiento de Aguas Residuales de la Comunidad Valenciana and DAM, S.L. The closed landfill has a surface of 2,6 ha and its re-vegetation will be carried out by introducing native plants (annuals, bush and trees) after incorporation into the degrades soil of the anaerobic sewage sludge at the single dose of 60 tn/ha. Twelve plots of 20 m by 8 m will be employed to a quarterly research of the effects on the soil and on the introduced vegetation of three doses (0,60, 120 tn/ha) of the anaerobic sewage sludge. (Author) 17 refs.

  5. Estimation of the mass-balance of selected metals in four sanitary landfills in Western Norway, with emphasis on the heavy metal content of the deposited waste and the leachate.

    Science.gov (United States)

    Øygard, Joar Karsten; Måge, Amund; Gjengedal, Elin

    2004-07-01

    A worst-case simulation of the mass-balance for metals in the waste deposited during 1 year and the levels of cadmium (Cd), lead (Pb), mercury (Hg), chromium (Cr) and iron (Fe) in the leachate was calculated for four sanitary landfills in Western Norway. Estimates of the levels of metal content in mixed municipal solid waste (MSW) were found by using recent literature values calculated in a mass-balance study at a Norwegian waste incinerator plant. Leachate from the landfills were sampled and analyzed monthly during 1 year, and from these measurements the total annual discharge of the selected metals through the leachate was determined. The levels of the measured heavy metals in the leachate were low. For Cd less than 0.06%, for Pb less than 0.01% and for Hg less than 0.02% of the estimated year's deposited mass of metals were leached from the landfills during the year of investigation. The high retention of these metals are most likely due to sulfide precipitation, but also due to the immobile condition of the metals in their original deposited solid state (plastics, ceramics, etc.). The percentage of Cr leached was relatively higher, but less than 1.0% per year. The mass balance of Fe suggests that this element is more mobile under the prevailing conditions. The percentage of Fe leached varied and was estimated to be between 1.9% and 18%. The present study clearly supports the theory that MSW only to a small extent will lead to discharge of metals if deposited at well-constructed sanitary landfills with top layers.

  6. Full Scale Tests of Short-Term Municipal Solid Waste Incineration Bottom Ash Weathering Before Landfill Disposal

    Directory of Open Access Journals (Sweden)

    Franco Marchese

    2009-01-01

    Full Text Available Problem statement: Natural weathering is the most economic method of treatment in order to reduce the release of heavy metals present in the residue. Approach: The aim of the study was to optimize the minimum weathering times that were useful to reduce the lead release to within the Italian limits for landfill disposal. The mechanism of short-term weathering of MSWI bottom ash had been studied and its effect on the leaching of lead had been evaluated. Two bottom ash heaps had been realized for the experimental assessment: In one case an open-air situation was used, in the other, a heap placed under shelter was not exposed to rain. Results: The weathering course was monitored through the results of a leaching test that was carried out at different ageing times (EN 12457-2:2002. The total carbonates were also measured, at the same time, on the fine fraction of the weathered bottom ash (2 was fixed by air. The pH value was controlled by Portlandite dissolution only at the beginning, after the pH control seems to be due to aluminum hydroxides. Conclusion: The most significant changes in the bottom ash were found to occur in the first 60 days. It had been possible to verify the limited influence of washing phenomena while it was confirmed that carbonation was the most important process in short-term weathering and that it had an important rule on limiting lead release.

  7. Metal levels in sugar cane (Saccharum spp.) samples from an area under the influence of a municipal landfill and a medical waste treatment system in Brazil.

    Science.gov (United States)

    Segura-Muñoz, S I; da Silva Oliveira, A; Nikaido, M; Trevilato, T M B; Bocio, A; Takayanagui, A M M; Domingo, J L

    2006-01-01

    In July 2003, duplicated samples of roots, stems and leaves of sugar cane (Saccharum spp.) were collected in 25 points of an area under direct influence of the municipal landfill site (MLS) and medical waste treatment system (MWTS) of Ribeirao Preto, São Paulo, Brazil. Cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), manganese (Mn), lead (Pb) and zinc (Zn) were determined by atomic absorption spectrophotometry. The following concentrations (mg/kg) were found in roots: Cd, 0.22+/-0.12; Cr, 64.3+/-48.7; Cu, 140.6+/-27.7; Hg, 0.04+/-0.02; Mn, 561.6+/-283.3; Pb, 7.9+/-2.1 and Zn, 177.4+/-64.9. For some metals, these levels are higher than the concentrations previously reported for different plants, reaching, in some cases, values that might be considered toxic for vegetables. Metal levels in stems were 80-90% of those found in roots, while the concentrations detected in leaves were significantly lower than those in roots. The present results suggest that MLS and MWTS activities might have been increasing metal concentrations in edible tissues of sugar cane grown in the area under their influence. Moreover, the traditional agricultural practices in the production of sugar cane could be also another determinant factor to reach the current metal levels. The results of this study indicate that sugar cane is a crop that is able to grow in areas where metals in soils are accumulated.

  8. SRS: Site ranking system for hazardous chemical and radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Rechard, R.P.; Chu, M.S.Y.; Brown, S.L.

    1988-05-01

    This report describes the rationale and presents instructions for a site ranking system (SRS). SRS ranks hazardous chemical and radioactive waste sites by scoring important and readily available factors that influence risk to human health. Using SRS, sites can be ranked for purposes of detailed site investigations. SRS evaluates the relative risk as a combination of potentially exposed population, chemical toxicity, and potential exposure of release from a waste site; hence, SRS uses the same concepts found in a detailed assessment of health risk. Basing SRS on the concepts of risk assessment tends to reduce the distortion of results found in other ranking schemes. More importantly, a clear logic helps ensure the successful application of the ranking procedure and increases its versatility when modifications are necessary for unique situations. Although one can rank sites using a detailed risk assessment, it is potentially costly because of data and resources required. SRS is an efficient approach to provide an order-of-magnitude ranking, requiring only readily available data (often only descriptive) and hand calculations. Worksheets are included to make the system easier to understand and use. 88 refs., 19 figs., 58 tabs.

  9. Landfills as a biorefinery to produce biomass and capture biogas.

    Science.gov (United States)

    Bolan, N S; Thangarajan, R; Seshadri, B; Jena, U; Das, K C; Wang, H; Naidu, R

    2013-05-01

    While landfilling provides a simple and economic means of waste disposal, it causes environmental impacts including leachate generation and greenhouse gas (GHG) emissions. With the introduction of gas recovery systems, landfills provide a potential source of methane (CH4) as a fuel source. Increasingly revegetation is practiced on traditionally managed landfill sites to mitigate environmental degradation, which also provides a source of biomass for energy production. Combustion of landfill gas for energy production contributes to GHG emission reduction mainly by preventing the release of CH4 into the atmosphere. Biomass from landfill sites can be converted to bioenergy through various processes including pyrolysis, liquefaction and gasification. This review provides a comprehensive overview on the role of landfills as a biorefinery site by focusing on the potential volumes of CH4 and biomass produced from landfills, the various methods of biomass energy conversion, and the opportunities and limitations of energy capture from landfills.

  10. Influence of leachate recirculation on aerobic and anaerobic decomposition of solid wastes

    Energy Technology Data Exchange (ETDEWEB)

    Bilgili, M. Sinan [Yildiz Technical University, Environmental Engineering Department, 34349 Besiktas, Istanbul (Turkey)]. E-mail: mbilgili@yildiz.edu.tr; Demir, Ahmet [Yildiz Technical University, Environmental Engineering Department, 34349 Besiktas, Istanbul (Turkey)]. E-mail: ahmetd@yildiz.edu.tr; Ozkaya, Bestamin [Yildiz Technical University, Environmental Engineering Department, 34349 Besiktas, Istanbul (Turkey)]. E-mail: bozkaya@yildiz.edu.tr

    2007-05-08

    In this study, the effect of leachate recirculation on aerobic and anaerobic degradation of municipal solid wastes is determined by four laboratory-scale landfill reactors. The options studied and compared with the traditional anaerobic landfill are: leachate recirculation, landfill aeration, and aeration with leachate recirculation. Leachate quality is regularly monitored by the means of pH, alkalinity, total dissolved solids, conductivity, oxidation-reduction potential, chloride, chemical oxygen demand, ammonia, and total Kjeldahl nitrogen, in addition to generated leachate quantity. Aerobic leachate recirculated landfill appears to be the most effective option in the removal of organic matter and ammonia. The main difference between aerobic recirculated and non-recirculated landfill options is determined at leachate quantity. Recirculation is more effective on anaerobic degradation of solid waste than aerobic degradation. Further studies are going on to determine the optimum operational conditions for aeration and leachate recirculation rates, also with the operational costs of aeration and recirculation.

  11. LANDFILLS AS BIOREACTORS: RESEARH AT THE OUTER LOOP LANDFILL, LOUISVILLE, KENTUCKY; FIRST INTERIM REPORT

    Science.gov (United States)

    Interim report resulting from a cooperative research and development agreement (CRADA) between US EP A's Officeof Research and Development - National Risk Management Research Laboratory and a n ongoing field demonstrationof municipal waste landfills being operated as bioreact...

  12. Bioelectrochemical Integration of Waste Heat Recovery, Waste-to- Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes

    Energy Technology Data Exchange (ETDEWEB)

    Mac Dougall, James [Air Products and Chemicals, Inc., Allentown, PA (United States)

    2016-02-05

    Many U.S. manufacturing facilities generate unrecovered, low-grade waste heat, and also generate or are located near organic-content waste effluents. Bioelectrochemical systems, such as microbial fuel cells and microbial electrolysis cells, provide a means to convert organic-content effluents into electric power and useful chemical products. A novel biochemical electrical system for industrial manufacturing processes uniquely integrates both waste heat recovery and waste effluent conversion, thereby significantly reducing manufacturing energy requirements. This project will enable the further development of this technology so that it can be applied across a wide variety of US manufacturing segments, including the chemical, food, pharmaceutical, refinery, and pulp and paper industries. It is conservatively estimated that adoption of this technology could provide nearly 40 TBtu/yr of energy, or more than 1% of the U.S. total industrial electricity use, while reducing CO2 emissions by more than 6 million tons per year. Commercialization of this technology will make a significant contribution to DOE’s Industrial Technology Program goals for doubling energy efficiency and providing a more robust and competitive domestic manufacturing base.

  13. Inferred performance of surface hydraulic barriers from landfill operational data

    Energy Technology Data Exchange (ETDEWEB)

    Gross, B.A. [GeoSyntec Consultants, Austin, TX (United States); Bonaparte, R.; Othman, M.A. [GeoSyntec Consultants, Atlanta, GA (United States)

    1997-12-31

    There are few published data on the field performance of surface hydraulic barriers (SHBs) used in waste containment or remediation applications. In contrast, operational data for liner systems used beneath landfills are widely available. These data are frequently collected and reported as a facility permit condition. This paper uses leachate collection system (LCS) and leak detection system (LDS) liquid flow rate and chemical quality data collected from modem landfill double-liner systems to infer the likely hydraulic performance of SHBs. Operational data for over 200 waste management unit liner systems are currently being collected and evaluated by the authors as part of an ongoing research investigation for the United States Environmental Protection Agency (USEPA). The top liner of the double-liner system for the units is either a geomembrane (GMB) alone, geomembrane overlying a geosynthetic clay liner (GMB/GCL), or geomembrane overlying a compacted clay liner (GMB/CCL). In this paper, select data from the USEPA study are used to: (i) infer the likely efficiencies of SHBs incorporating GMBs and overlain by drainage layers; and (ii) evaluate the effectiveness of SHBs in reducing water infiltration into, and drainage from, the underlying waste (i.e., source control). SHB efficiencies are inferred from calculated landfill liner efficiencies and then used to estimate average water percolation rates through SHBs as a function of site average annual rainfall. The effectiveness of SHBs for source control is investigated by comparing LCS liquid flow rates for open and closed landfill cells. The LCS flow rates for closed cells are also compared to the estimated average water percolation rates through SHBs presented in the paper.

  14. Non-invasive methods applied to the case of Municipal Solid Waste landfills (MSW): analysis of long-term data

    Science.gov (United States)

    Scozzari, A.

    2008-11-01

    This work presents and discusses a methodology for modeling the behavior of a landfill system in terms of biogas release to the atmosphere, relating this quantity to local meteorological parameters. One of the most important goals in the study of MSW sites lies in the optimization of biogas collection, thus minimizing its release to the atmosphere. After an introductory part, that presents the context of non-invasive measurements for the assessment of biogas release, the concepts of survey mapping and automatic flux monitoring are introduced. Objective of this work is to make use of time series coming from long-term flux monitoring campaigns in order to assess the trend of gas release from the MSW site. A key aspect in processing such data is the modeling of the effect of meteorological parameters over such measurements; this is accomplished by modeling the system behavior with a set of Input/Output data to characterize it without prior knowledge (system identification). The system identification approach presented here is based on an adaptive simulation concept, where a set of Input/Output data help training a "black box" model, without necessarily a prior analytical knowledge. The adaptive concept is based on an Artificial Neural Network scheme, which is trained by real-world data coming from a long-term monitoring campaign; such data are also used to test the real forecasting capability of the model. In this particular framework, the technique presented in this paper appears to be very attractive for the evaluation of biogas releases on a long term basis, by simulating the effects of meteorological parameters over the flux measurement, thus enhancing the extraction of the useful information in terms of a gas "flux" quantity.

  15. Non-invasive methods applied to the case of Municipal Solid Waste landfills (MSW: analysis of long-term data

    Directory of Open Access Journals (Sweden)

    A. Scozzari

    2008-11-01

    Full Text Available This work presents and discusses a methodology for modeling the behavior of a landfill system in terms of biogas release to the atmosphere, relating this quantity to local meteorological parameters. One of the most important goals in the study of MSW sites lies in the optimization of biogas collection, thus minimizing its release to the atmosphere.

    After an introductory part, that presents the context of non-invasive measurements for the assessment of biogas release, the concepts of survey mapping and automatic flux monitoring are introduced.

    Objective of this work is to make use of time series coming from long-term flux monitoring campaigns in order to assess the trend of gas release from the MSW site. A key aspect in processing such data is the modeling of the effect of meteorological parameters over such measurements; this is accomplished by modeling the system behavior with a set of Input/Output data to characterize it without prior knowledge (system identification.

    The system identification approach presented here is based on an adaptive simulation concept, where a set of Input/Output data help training a "black box" model, without necessarily a prior analytical knowledge. The adaptive concept is based on an Artificial Neural Network scheme, which is trained by real-world data coming from a long-term monitoring campaign; such data are also used to test the real forecasting capability of the model.

    In this particular framework, the technique presented in this paper appears to be very attractive for the evaluation of biogas releases on a long term basis, by simulating the effects of meteorological parameters over the flux measurement, thus enhancing the extraction of the useful information in terms of a gas "flux" quantity.

  16. Guidelines for generators of hazardous chemical waste at LBL and guidelines for generators of radioactive and mixed waste at LBL

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    In part one of this document the Governing Documents and Definitions sections provide general guidelines and regulations applying to the handling of hazardous chemical wastes. The remaining sections provide details on how you can prepare your waste properly for transport and disposal. They are correlated with the steps you must take to properly prepare your waste for pickup. The purpose of the second part of this document is to provide the acceptance criteria for the transfer of radioactive and mixed waste to LBL's Hazardous Waste Handling Facility (HWHF). These guidelines describe how you, as a generator of radioactive or mixed waste, can meet LBL's acceptance criteria for radioactive and mixed waste.

  17. A COMPARISON OF MOLECULAR AND CULTURAL METHODOLOGIES FOR ENUMERATING BACTERIA IN LANDFILL LEACHATES

    Science.gov (United States)

    Landfill bioreactor technology has been under investigation in the field for its potential economic and waste treatment benefits over conventional landfill systems. A better understanding of biological influences on the stabilization process is needed for incorporation into the e...

  18. Methane Gas Utilization Project from Landfill at Ellery (NY)

    Energy Technology Data Exchange (ETDEWEB)

    Pantelis K. Panteli

    2012-01-10

    Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

  19. Low carbon fuel and chemical production from waste gases

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, S.; Liew, F.M.; Daniell, J.; Koepke, M. [LanzaTech, Ltd., Auckland (New Zealand)

    2012-07-01

    LanzaTech has developed a gas fermentation platform for the production of alter native transport fuels and commodity chemicals from carbon monoxide, hydrogen and carbon dioxide containing gases. LanzaTech technology uses these gases in place of sugars as the carbon and energy source for fermentation thereby allowing a broad spectrum of resources to be considered as an input for product synthesis. At the core of the Lanzatech process is a proprietary microbe capable of using gases as the only carbon and energy input for product synthesis. To harness this capability for the manufacture of a diverse range of commercially valuable products, the company has developed a robust synthetic biology platform to enable a variety of novel molecules to be synthesised via gas fermentation. LanzaTech initially focused on the fermentation of industrial waste gases for fuel ethanol production. The company has been operating pilot plant that uses direct feeds of steel making off gas for ethanol production for over 24 months. This platform technology has been further successfully demonstrated using a broad range of gas inputs including gasified biomass and reformed natural gas. LanzaTech has developed the fermentation, engineering and control systems necessary to efficiently convert gases to valuable products. A precommercial demonstration scale unit processing steel mill waste gases was commissioned in China during the 2{sup nd} quarter of 2012. Subsequent scale-up of this facility is projected for the 2013 and will represent the first world scale non-food based low carbon ethanol project. More recently LanzaTech has developed proprietary microbial catalysts capable of converting carbon dioxide in the presence of hydrogen directly to value added chemicals, where-in CO{sub 2} is the sole source of carbon for product synthesis. Integrating the LanzaTech technology into a number of industrial facilities, such as steel mills, oil refineries and other industries that emit Carbon bearing

  20. Environmental assessment of Ammässuo Landfill (Finland) by means of LCA-modelling (EASEWASTE).

    Science.gov (United States)

    Niskanen, Antti; Manfredi, Simone; Christensen, Thomas H; Anderson, Reetta

    2009-08-01

    The Old Ammässuo Landfill (Espoo, Finland) covers an area of 52 hectares and contains about 10 million tonnes of waste that was landfilled between 1987 and 2007. The majority of this waste was mixed, of which about 57% originated from households. This paper aims at describing the management of the Old Ammässuo Landfill throughout its operational lifetime (1987-2007), and at developing an environmental evaluation based on life-cycle assessment (LCA) using the EASEWASTE-model. The assessment criteria evaluate specific categories of impact, including standard impact categories, toxicity-related impact categories and an impact categorized as spoiled groundwater resources (SGR). With respect to standard and toxicity-related impact categories, the LCA results show that substantial impact potentials are estimated for global warming (GW), ozone depletion (OD), human toxicity via soil (HTs) and ecotoxicity in water chronic (ETwc). The largest impact potential was found for SGR and amounted to 57.6 person equivalent (PE) per tonne of landfilled waste. However, the SGR impact may not be viewed as a significant issue in Finland as the drinking water is mostly supplied from surface water bodies. Overall, the results demonstrate that gas management has great importance to the environmental performance of the Old Ammässuo Landfill. However, several chemicals related to gas composition (especially trace compounds) and specific emissions from on-site operations were not available or were not measured and were therefore taken from the literature. Measurement campaigns and field investigations should be undertaken in order to obtain a more robust and comprehensive dataset that can be used in the LCA-modelling, before major improvements regarding landfill management are finalized.

  1. Landfills, Landfills, Published in 2003, Taylor County.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Landfills dataset, was produced all or in part from Published Reports/Deeds information as of 2003. It is described as 'Landfills'. Data by this publisher are...

  2. Technology Evaluation Workshop Report for Tank Waste Chemical Characterization

    Energy Technology Data Exchange (ETDEWEB)

    Eberlein, S.J.

    1994-04-01

    A Tank Waste Chemical Characterization Technology Evaluation Workshop was held August 24--26, 1993. The workshop was intended to identify and evaluate technologies appropriate for the in situ and hot cell characterization of the chemical composition of Hanford waste tank materials. The participants were asked to identify technologies that show applicability to the needs and good prospects for deployment in the hot cell or tanks. They were also asked to identify the tasks required to pursue the development of specific technologies to deployment readiness. This report describes the findings of the workshop. Three focus areas were identified for detailed discussion: (1) elemental analysis, (2) molecular analysis, and (3) gas analysis. The technologies were restricted to those which do not require sample preparation. Attachment 1 contains the final workshop agenda and a complete list of attendees. An information package (Attachment 2) was provided to all participants in advance to provide information about the Hanford tank environment, needs, current characterization practices, potential deployment approaches, and the evaluation procedure. The participants also received a summary of potential technologies (Attachment 3). The workshop opened with a plenary session, describing the background and issues in more detail. Copies of these presentations are contained in Attachments 4, 5 and 6. This session was followed by breakout sessions in each of the three focus areas. The workshop closed with a plenary session where each focus group presented its findings. This report summarizes the findings of each of the focus groups. The evaluation criteria and information about specific technologies are tabulated at the end of each section in the report. The detailed notes from each focus group are contained in Attachments 7, 8 and 9.

  3. Guidelines for generators of hazardous chemical waste at LBL and guidelines for generators of radioactive and mixed waste at LBL. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-01

    The purpose of this document is to provide the acceptance criteria for the transfer of hazardous chemical waste to LBL`s Hazardous Waste Handling Facility (HWHF). Hazardous chemical waste is a necessary byproduct of LBL`s research and technical support activities. This waste must be handled properly if LBL is to operate safely and provide adequate protection to staff and the environment. These guidelines describe how you, as a generator of hazardous chemical waste, can meet LBL`s acceptance criteria for hazardous chemical waste.

  4. Combustible radioactive waste treatment by incineration and chemical digestion

    Energy Technology Data Exchange (ETDEWEB)

    Stretz, L.A.; Crippen, M.D.; Allen, C.R.

    1980-05-28

    A review is given of present and planned combustible radioactive waste treatment systems in the US. Advantages and disadvantages of various systems are considered. Design waste streams are discussed in relation to waste composition, radioactive contaminants by amount and type, and special operating problems caused by the waste.

  5. BIOREACTOR DESIGN - OUTER LOOP LANDFILL, LOUISVILLE, KY

    Science.gov (United States)

    Bioreactor field demonstration projects are underway at the Outer Loop Landfill in Louisville, KY, USA. The research effort is a cooperative research effort between US EPA and Waste Management Inc. Two primary kinds of municipal waste bioreactors are under study at this site. ...

  6. Designing systems for landfill gas migration control in Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    Cannon, J. [Camp, Dresser & McKee, Inc., St. Paul, MN (United States)

    1996-11-01

    Camp, Dresser & McKee (CDM) has designed or is in the process of designing several landfill gas migration control systems in Minnesota. The systems are for both active and closed municipal solid waste landfills. The sites have a variety of covers, including geomembranes, clay caps, and non-engineered soil covers. The control system types include small perimeter systems, full-site systems and phased systems for active sites. Figure 1 shows the locations of the systems CDM is working on in Minnesota. This paper focuses on four sites: Oak Grove Landfill, Hopkins Landfill, Washington County Landfill, and Elk River Landfill. Table 1 provides an outline of the individual site characteristics. The first three sites are closed landfills. The Oak Grove Landfill system was designed and constructed for a group of industries responsible for closure and remedial action. The Hopkins and Washington County landfills are under the control of the Minnesota Pollution Control Agency (MPCA). The MPCA enacted a remedial action program at closed landfills, taking over responsibility for long-term liability under the terms of legally binding agreements negotiated with the site owners. The Elk River Landfill is an active, privately-owned facility. The migration problems and solutions developed for these four landfills are generally descriptive of all the landfills CDM is working on in Minnesota. All landfills have unique characteristics requiring site-specific solutions. CDM, after designing a number of migration control systems in Minnesota, is able to provide a generalized description of design options for specific types of sites. This paper discussions design options used to address different cover types, aesthetic needs, and waste depths, and includes a discussion of design needs for cold climates. A brief case history of the Oak Grove Landfill is included.

  7. Chemically bonded phosphate ceramics for radioactive and mixed waste solidification and stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Wagh, A.S.; Cunnane, J.C.; Singh, D.; Reed, D.T.; Armstrong, S.; Subhan, W.; Chawla, N.

    1993-01-01

    Results of an initial investigation of low temperature setting chemically bonded magnesium ammonium phosphate (MAP) ceramics as waste form materials, for solidification and stabilization of radioactive and mixed waste, are reported. The suitability of MAP for solidifying and encapsulating waste materials was tested by encapsulating zeolites at loadings up to [approximately]50 wt%. The resulting composites exhibited very good compressive strength characteristics. Microstructure studies show that zeolite grains remain unreacted in the matrix. Potential uses for solidifying and stab wastes are discussed.

  8. Chemically bonded phosphate ceramics for radioactive and mixed waste solidification and stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Wagh, A.S.; Cunnane, J.C.; Singh, D.; Reed, D.T.; Armstrong, S.; Subhan, W.; Chawla, N.

    1993-01-01

    Results of an initial investigation of low temperature setting chemically bonded magnesium ammonium phosphate (MAP) ceramics as waste form materials, for solidification and stabilization of radioactive and mixed waste, are reported. The suitability of MAP for solidifying and encapsulating waste materials was tested by encapsulating zeolites at loadings up to {approximately}50 wt%. The resulting composites exhibited very good compressive strength characteristics. Microstructure studies show that zeolite grains remain unreacted in the matrix. Potential uses for solidifying and stab wastes are discussed.

  9. Final Hazard Categorization for the Remediation of the 116-C-3 Chemical Waste Tanks

    Energy Technology Data Exchange (ETDEWEB)

    T. M. Blakley; W. D. Schofield

    2007-09-10

    This final hazard categorization (FHC) document examines the hazards, identifies appropriate controls to manage the hazards, and documents the commitments for the 116-C-3 Chemical Waste Tanks Remediation Project. The remediation activities analyzed in this FHC are based on recommended treatment and disposal alternatives described in the Engineering Evaluation for the Remediation to the 116-C-3 Chemical Waste Tanks (BHI 2005e).

  10. Landfill is an important atmospheric mercury emission source

    Institute of Scientific and Technical Information of China (English)

    FENG Xinbin; TANG Shunlin; LI Zhonggen; WANG Shaofeng; LIANG Lian

    2004-01-01

    Since municipal wastes contain refuses with high mercury contents, incineration of municipal wastes becomes the major anthropogenic atmospheric mercury emission source. In China, landfills are however the main way to dispose of municipal wastes. Total gaseous mercury (TGM) concentrations in landfill gas of Gaoyan sanitary landfill located in suburb of Guiyang City were monitored using a high temporal resolved automated mercury analyzer, and mono-methylmercury (MMHg) and dimethylmercury (DMHg) concentrations in landfill gas were also measured using GC coupled with the cold vapor atomic fluorescence (CVAFS) method. Meanwhile, the TGM exchange fluxes between exposed waste and air and the soil surface of the landfill and air, were measured using low Hg blank quartz flux chamber coupled with high temporal resolved automated mercury analyzer technique. TGM concentrations in landfill gas from half year filling area averaged out at 665.52±291.25 ng/m3, which is comparable with TGM concentrations from flue gas of a small coal combustion boiler in Guiyang. The average MMHg and DMHg concentrations averaged out at 2.06±1.82 ng/m3 and 9.50±5.18 ng/m3, respectively. It is proven that mercury emission is the predominant process at the surfaces of both exposed wastes and soil of landfill. Landfills are not only TGM emission source, but also methylmercury emission source to the ambient air. There are two ways to emit mercury to the air from landfills, one is with the landfill gas through landfill gas duct, and the other through soil/air exchange. The Hg emission processes from landfills are controlled by meteorological parameters.

  11. Determination of physico-chemical properties of fine-grained waste from the cleaning of iron casting

    OpenAIRE

    2017-01-01

    In the European Union one of the most important activities is the recovery and recycling of waste including foundry waste. In the article waste arising from production of iron casting was presented. Selected physic-chemical properties of iron-bearing waste were defined. Opportunities of waste management are related to their chemical construction as well as some physical properties. On the basic the results of research the solutions of foundry waste management were proposed.

  12. Gaseous methyl- and inorganic mercury in landfill gas from landfills in Florida, Minnesota, Delaware, and California

    Science.gov (United States)

    Lindberg, S. E.; Southworth, G.; Prestbo, E. M.; Wallschläger, D.; Bogle, M. A.; Price, J.

    2005-01-01

    Municipal waste landfills contain numerous sources of mercury which could be emitted to the atmosphere. Their generation of methane by anaerobic bacteria suggests that landfills may act as bioreactors for methylated mercury compounds. Since our previous study at a single Florida landfill, gaseous inorganic and methylated mercury species have now been identified and quantified in landfill gas at nine additional municipal landfills in several regions of the US. Total gaseous mercury occurs at concentrations in the μg m-3 range, while methylated compounds occur at concentrations in the ng m-3 range at all but one of the landfill sites. Dimethylmercury is the predominant methylated species, at concentrations up to 100 ng m-3, while monomethyl mercury was generally lower. Limited measurements near sites where waste is exposed for processing (e.g. working face, transfer areas) suggest that dimethylmercury is released during these activities as well. Although increasing amounts of landfill gas generated in the US are flared (which should thermally decompose the organic mercury to inorganic mercury), unflared landfill gas is a potentially important anthropogenic source of methylated mercury emissions to the atmosphere.

  13. Dynamic Assessment on Environmental Impacts of Construction Waste Disposal by Landfill in Shenzhen%深圳市建筑废弃物填埋处置的环境影响动态评估

    Institute of Scientific and Technical Information of China (English)

    王婷; 王家远; 武冬

    2016-01-01

    The paper analyzes main factors of construction waste landfill that impact environment,combines with the system dynamic method and builds dynamic model of environmental impacts of construction waste disposal by landfill via Vensim. Then,takes Shenzhen city for an example,transfers the environmental impacts into quantified currency form with the conception of social willingness-to-pay(WTP),proposes suggestions for making policies for construction waste disposal with obtained results.%梳理建筑废弃物填埋对环境影响的主要因素,结合系统动力学方法,运用Vensim软件构建建筑废弃物填埋处置的环境影响动态模型。以深圳市为例,借助社会支付意愿的概念将环境影响转化为货币形式进行建筑垃圾填埋对环境影响的定量计算,结合模拟分析对制定建筑废弃物处置政策提出建议。

  14. 建筑垃圾受纳场雨污分流系统的措施探讨%Discussion on Separate System of Rainwater and Sewage in Construction Waste Landfill Site

    Institute of Scientific and Technical Information of China (English)

    林伯伟

    2011-01-01

    以深圳某建筑垃圾受纳场为例,对其雨污分流系统进行了论述.分别就场地平整、永久性截洪沟、排水系统等进行分类、探讨,并提出了解决方案.%Taking a construction waste landfill site in Shenzhen as a case, the separate system of rainwater and sewage is described. The area leveling, permanent flood intercepting trench and drainage system are classified and discussed, and some specific schemes are proposed.

  15. Assessing Emissions of Volatile Organic Componds from Landfills Gas

    Directory of Open Access Journals (Sweden)

    Fahime Khademi

    2016-01-01

    Full Text Available Background: Biogas is obtained by anaerobic decomposition of organic wastes buried materials used to produce electricity, heat and biofuels. Biogas is at the second place for power generation after hydropower and in 2000 about 6% of the world power generation was allocated to biogas. Biogas is composed of 40–45 vol% CO2, 55–65 vol% CH4, and about 1% non-methaneVOCs, and non-methane volatile organic compounds. Emission rates are used to evaluate the compliance with landfill gas emission regulations by the United States Environmental Protection Agency (USEPA. BTEX comounds affect the air quality and may be harmful to human health. Benzene, toluene, ethylbenzene and xylene isomers that are generally called BTEX compounds are the most abundant VOCs in biogas. Methods: Sampling of VOCs in biogas vents was operated passively or with Tedlar bags. 20 samples were collected from 40 wells of old and new biogas sites of Shiraz’ landfill. Immediately after sampling, the samples were transferred to the laboratory. Analysis of the samples was performed with GC-MS. Results: The results showed that in the collection of the old and new biogas sites, the highest concentration of VOCs was observed in toluene (0.85ppm followed by benzene (0.81ppm, ethylbenzene (0.13ppm and xylene (0.08ppm. Conclusion: The results of the study showed that in all samples, most available compounds in biogas vents were aromatic hydrocarbon compounds.These compounds’ constituents originate from household hazardous waste materials deposited in the landfill or from biological/chemical decomposition processes within the landfill.

  16. Chemical composition and methane potential of commercial food wastes.

    Science.gov (United States)

    Lopez, Victoria M; De la Cruz, Florentino B; Barlaz, Morton A

    2016-10-01

    There is increasing interest in anaerobic digestion in the U.S. However, there is little information on the characterization of commercial food waste sources as well as the effect of waste particle size on methane yield. The objective of this research was to characterize four commercial food waste sources: (1) university dining hall waste, (2) waste resulting from prepared foods and leftover produce at a grocery store, (3) food waste from a hotel and convention center, and (4) food preparation waste from a restaurant. Each sample was tested in triplicate 8L batch anaerobic digesters after shredding and after shredding plus grinding. Average methane yields for the university dining, grocery store, hotel, and restaurant wastes were 363, 427, 492, and 403mL/dry g, respectively. Starch exhibited the most complete consumption and particle size did not significantly affect methane yields for any of the tested substrates. Lipids represented 59-70% of the methane potential of the fresh substrates.

  17. Diffusion of inorganic chemical wastes in compacted clay

    Energy Technology Data Exchange (ETDEWEB)

    Shackelford, C.D.

    1988-01-01

    The factors that were investigated included the water content/dry unit weight, the method of compaction, the mineralogy of the soil, and the concentration of the ions. The effective diffusion coefficients (D{asterisk}) of three anions (Cl{sup {minus}}, Br{sup {minus}}, and I{sup {minus}}) and three cations (K{sup +}, Cd{sup 2+}, and Zn{sup 2+}) in a simulated waste leachate were measured. Two clay soils (kaolinite and Lufkin clay) and a sand were used in the study. The clay samples were compacted and pre-soaked to minimize hydraulic gradients due to negative pore pressures. Mass balance calculations were performed to indicate possible sinks/sources in the diffusion system. The results of the diffusion tests were analyzed using two analytical solutions to Fick's second law and a commercially available semi-analytical solution. The D{asterisk} values for tests using high-concentration (0.04 N) leachate generally fell in the narrow range of about 4.0 {times} 10{sup {minus}6} to 2.0 {times} 10{sup {minus}5} cm{sup 2}/s, and were relatively insensitive to compaction water content/dry unit weight and to compaction method. The variability in the results from the tests with low-concentration (0.013 N) leachate precluded any definite conclusions from these tests. The values of D{asterisk} measured in this study were compared to values from previous studies, and the D{asterisk} values from this study were found to be slightly conservative (i.e., high). However, the results of the tests may be affected by several chemical and physical factors, and care should be taken to ensure that the soils used in the tests are representative of those used in the application of the test results. Recommendations are made for estimating D{asterisk} values for use in the design of compacted clay barriers for the containment of inorganic chemical wastes.

  18. Application of Vadose Zone Monitoring Technology for Characterization of Leachate Generation in Landfills

    Science.gov (United States)

    aharoni, imri; dahan, ofer

    2016-04-01

    Ground water contamination due to landfill leachate percolation is considered the most severe environmental threat related to municipal solid waste landfills. Natural waste degradation processes in landfills normally produce contaminated leachates up to decades after the waste has been buried. Studies have shown that understanding the mechanisms which govern attenuation processes and the fate of pollutants in the waste and in the underlying unsaturated zone is crucial for evaluation of environmental risks and selection of a restoration strategy. This work focuses on a closed landfill in the coastal plain of Israel that was active until 2002 without any lining infrastructure. A vadose zone monitoring system (VMS) that was implemented at the site enables continuous measurements across the waste body (15 m thick) and underlying sandy vadose zone (16 m thick). Data collected by the VMS included continuous measurements of water content as well as chemical composition of the leachates across the entire waste and vadose zone cross section. Results indicated that winter rain percolated through the waste, generating wetting waves which were observed across the waste and unsaturated sediment from land surface until groundwater at 31 m bls. Quick percolation and high fluxes were observed in spite of the clay cover that was implemented at the site as part of the rehabilitation scheme. The results show that the flow pattern is controlled by a preferential mechanism within the waste body. Specific sections showed rapid fluxes in response to rain events, while other sections remained unaffected. In the underlying sandy vadose zone the flow pattern exhibited characteristics of matrix flow. Yet, some sections received higher fluxes due to the uneven discharge of leachates from the overlying waste body. Water samples collected from the waste layer indicate production of highly polluted leachates over 14 years after the landfill was closed. The chemical composition within the waste

  19. Ammonia release and conversion in bioreactor landfill simulators

    Energy Technology Data Exchange (ETDEWEB)

    Lubberding, H.; Valencia, R.; Salazar, R.; Lens, P.

    2009-07-01

    Bioreactor landfills are considered to be an improvements to normal sanitary landfills, because the Municipal Solid Waste is stabilised faster and the biogas is produced in a shorter period of time (Valencia et al 2008a, b). In spite of these advantages, it is still difficult to reach within 30 years a safe status of the landfill due to the elevated NH{sub 4}{sup +} levels (up to 3 g/L) in the leachate. (Author)

  20. Quantification of long term emission potential from landfills

    OpenAIRE

    Heimovaara, T.J.

    2011-01-01

    Novel approaches for the after-care of Municipal Solid Waste (MSW) landfills are based on technological measures to reduce the long term emission potential in a short time period. Biological degradation in landfills is a means to significantly reduce the long term emission potential. Leachate emission to the groundwater is considered to be one of the largest long-term impacts related to landfilling. Currently we are starting up a research program, partly subsidized by the Dutch Technology fou...

  1. Quality and Quantity of Leachate in Aerobic Pilot-Scale Landfills

    Science.gov (United States)

    Bilgili, Memmet Sinan; Demir, Ahmet; Özkaya, Bestamin

    2006-08-01

    In this study, two pilot-scale aerobic landfill reactors with (A1) and without (A2) leachate recirculation are used to obtain detailed information on the quantity and quality of leachate in aerobic landfills. The observed parameters of leachate quality are pH, chloride (Cl-), chemical oxygen demand (COD), biological oxygen demand (BOD), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), and nitrate (NO3 --N). pH values of the leachate increased to 7 after 50 days in reactor A1 and after 70 days in reactor A2. Cl- concentrations increased rapidly to 6100 (A1) and 6900 (A2) mg/L after 80 days, from initial values of 3000 and 2800 mg/L, respectively. COD and BOD values decreased rapidly in the A1 landfill reactor, indicating the rapid oxidation of organic matter. The BOD/COD ratio indicates that leachate recirculation slightly increases the degradation of solid waste in aerobic landfills. NH3-N concentrations decreased as a result of the nitrification process. Denitrification occurred in parts of the reactors as a result of intermittent aeration; this process causes a decrease in NO3 - concentrations. There is a marked difference between the A1 and A2 reactors in terms of leachate quantity. Recirculated leachate made up 53.3% of the leachate generated from the A1 reactor during the experiment, while leachate quantity decreased by 47.3% with recirculation when compared with the aerobic dry landfill reactor.

  2. Trends in sustainable landfilling in Malaysia, a developing country.

    Science.gov (United States)

    Fauziah, S H; Agamuthu, P

    2012-07-01

    In Malaysia, landfills are being filled up rapidly due to the current daily generation of approximately 30,000 tonnes of municipal solid waste. This situation creates the crucial need for improved landfilling practices, as sustainable landfilling technology is yet to be achieved here. The objective of this paper is to identify and evaluate the development and trends in landfilling practices in Malaysia. In 1970, the disposal sites in Malaysia were small and prevailing waste disposal practices was mere open-dumping. This network of relatively small dumps, typically located close to population centres, was considered acceptable for a relatively low population of 10 million in Malaysia. In the 1980s, a national programme was developed to manage municipal and industrial wastes more systematically and to reduce adverse environmental impacts. The early 1990s saw the privatization of waste management in many parts of Malaysia, and the establishment of the first sanitary landfills for MSW and an engineered landfill (called 'secure landfill' in Malaysia) for hazardous waste. A public uproar in 2007 due to contamination of a drinking water source from improper landfilling practices led to some significant changes in the government's policy regarding the country's waste management strategy. Parliament passed the Solid Waste and Public Cleansing Management (SWPCM) Act 2007 in August 2007. Even though the Act is yet to be implemented, the government has taken big steps to improve waste management system further. The future of the waste management in Malaysia seems somewhat brighter with a clear waste management policy in place. There is now a foundation upon which to build a sound and sustainble waste management and disposal system in Malaysia.

  3. 西部地区建筑废弃物填埋的法律规制%Overview of the Construction & Demolition Waste Landfilling Disposal Regulation in Western China

    Institute of Scientific and Technical Information of China (English)

    袁红平; 孙洪伟

    2015-01-01

    建筑废弃物填埋法规对促进废弃物减量化与资源化起着重要作用。然而,目前我国的建筑废弃物填埋法规不成系统且执行效果有待加强。基于此,系统综述了西部6省市的建筑废弃物填埋法规,重点就法规完善性、主管部门的职责及协同监管、填埋设施规划与管理、填埋收费标准,以及填埋行为管理等进行了评述,旨在甄别现行法规体系中的主要欠缺,为完善西部地区建筑废弃物填埋法规提供参考。%Regulations for construction & demolition waste landfilling disposal(RCDWLD)plays an important role in waste minimization. However,it is found that the current RCDWLD in China is ineffective and needs to be further improved. This paper reviewed the regulation of the six regions located in western China. The focus was to examine the completeness of the regulatory system,the responsibilities of government department involved,the planning and development of waste landfilling facilities,the waste disposal charging fee,and the waste dumping behavior. It is anticipated that the drawbacks of current regulations could be identified and the findings could be used to enhance the RCDWLD in western China.

  4. Landfill leachate treatment using bacto-algal co-culture: An integrated approach using chemical analyses and toxicological assessment.

    Science.gov (United States)

    Kumari, Moni; Ghosh, Pooja; Thakur, Indu Shekhar

    2016-06-01

    The present study aims to evaluate the feasibility of leachate treatment using a synergistic approach by microalgae and bacteria. Leachate from one of the landfill of Northern India showed the presence of various toxic organic contaminants like naphthalene, benzene, phenol and their derivatives, napthols, pesticides, epoxides, phthalates and halogenated organic compounds. ICP-AES analysis revealed high concentrations of Zn, Cr, Fe, Ni, and Pb beyond the maximum permissible limit of discharge. Bacto-algal co-culture was found to be the most efficient in removal of toxic organic contaminants and heavy metals. Further, detoxification efficiency of bacto-algal treatment was evaluated by Methyl tetrazolium (MTT) assay for cytotoxicity and alkaline comet assay for genotoxicity using hepatoma HepG2 cells. Reduction in toxicity was confirmed by an increase in LC50 by 1.9 fold and reduction in Olive Tail Moment by 40.6 fold after 10 days of treatment. Results of the study indicate bioremediation and detoxification potency of bacto-algal co-culture for leachate treatment.

  5. Quantification of chemical contaminants in the paper and board fractions of municipal solid waste.

    Science.gov (United States)

    Pivnenko, K; Olsson, M E; Götze, R; Eriksson, E; Astrup, T F

    2016-05-01

    Chemicals are used in materials as additives in order to improve the performance of the material or the production process itself. The presence of these chemicals in recyclable waste materials may potentially affect the recyclability of the materials. The addition of chemicals may vary depending on the production technology or the potential end-use of the material. Paper has been previously shown to potentially contain a large variety of chemicals. Quantitative data on the presence of chemicals in paper are necessary for appropriate waste paper management, including the recycling and re-processing of paper. However, a lack of quantitative data on the presence of chemicals in paper is evident in the literature. The aim of the present work is to quantify the presence of selected chemicals in waste paper derived from households. Samples of paper and board were collected from Danish households, including both residual and source-segregated materials, which were disposed of (e.g., through incineration) and recycled, respectively. The concentration of selected chemicals was quantified for all of the samples. The quantified chemicals included mineral oil hydrocarbons, phthalates, phenols, polychlorinated biphenyls, and selected toxic metals (Cd, Co, Cr, Cu, Ni, and Pb). The results suggest large variations in the concentration of chemicals depending on the waste paper fraction analysed. Research on the fate of chemicals in waste recycling and potential problem mitigation measures should be focused on in further studies.

  6. Grouting of fly ash in sanitary landfills; Injektering av flygaska i hushaallsavfallsdeponi

    Energy Technology Data Exchange (ETDEWEB)

    Wikman, Karin; Berg, Magnus [AaF-Energi och Miljoe AB, Stockhom (Sweden); Andreas, Lale; Lagerkvist, Anders [Luleaa Univ. of Technology (Sweden); Jannes, Sara; Tham, Gustav [Telge Aatervinning AB, Soedertaelje (Sweden); Sjoeblom, Rolf [Tekedo AB, Nykoeping (Sweden)

    2003-10-01

    The purpose of the study was to investigate the potential for stabilization of sanitary landfills by injecting fly ash. The method is supposed to prevent differential settlements in landfills and by that to counteract damages in the final cover. Injecting fly ash may also affect the chemical development in a positive way and prevent metal leaching. Pilot experiments at the Tveta waste recycling center (Tveta Aatervinningsanlaeggning) have been performed in order to estimate if the grouting technology is a suitable method for sanitary landfills. Fly ashes from the combustion of bio fuels were used in these tests. A literature study and laboratory experiments in order to prepare the field experiments were also part of the project. About 100 tons of ash slurry were injected during the pilot experiments. This corresponds to a filling degree of approximately 12-16 % of the available pores in the landfill body. As a result of the pilot test, the following conclusions can be drawn: Ash can be mixed with water to a pumpable slurry which can be injected without hardening inside the equipment. Neither the waste nor the grouting material caused a backpressure during the injection and nothing indicates that the injected ash deforms the landfilled waste. The ash-water-slurry flows through the voids in the waste easily. Thus, the ash may dispread quite far from the injection holes. Using a more powerful equipment backpressure and movements in the waste might occur. It was not possible to estimate the flow required for backpressure in this study. Large variations are possible but for safety reasons the maximal pressure should be limited with regard to the expected stability in the actual area. The grouted ash will harden within the landfill body within a couple of days. It accumulates in hard but brittle lumps, which may result in an increased stability of the landfill. Further studies are necessary in order to evaluate how the stability is affected and what amounts of ash are

  7. Sustainable treatment of landfill leachate

    Science.gov (United States)

    Kamaruddin, Mohamad Anuar; Yusoff, Mohd. Suffian; Aziz, Hamidi Abdul; Hung, Yung-Tse

    2015-06-01

    Landfill leachate is a complex liquid that contains excessive concentrations of biodegradable and non-biodegradable products including organic matter, phenols, ammonia nitrogen, phosphate, heavy metals, and sulfide. If not properly treated and safely disposed, landfill leachate could be an impending source to surface and ground water contamination as it may percolate throughout soils and subsoils, causing adverse impacts to receiving waters. Lately, various types of treatment methods have been proposed to alleviate the risks of untreated leachate. However, some of the available techniques remain complicated, expensive and generally require definite adaptation during process. In this article, a review of literature reported from 2008 to 2012 on sustainable landfill leachate treatment technologies is discussed which includes biological and physical-chemical techniques, respectively.

  8. Utilization of biocatalysts in cellulose waste minimization

    Energy Technology Data Exchange (ETDEWEB)

    Woodward, J.; Evans, B.R.

    1996-09-01

    Cellulose, a polymer of glucose, is the principal component of biomass and, therefore, a major source of waste that is either buried or burned. Examples of biomass waste include agricultural crop residues, forestry products, and municipal wastes. Recycling of this waste is important for energy conservation as well as waste minimization and there is some probability that in the future biomass could become a major energy source and replace fossil fuels that are currently used for fuels and chemicals production. It has been estimated that in the United States, between 100-450 million dry tons of agricultural waste are produced annually, approximately 6 million dry tons of animal waste, and of the 190 million tons of municipal solid waste (MSW) generated annually, approximately two-thirds is cellulosic in nature and over one-third is paper waste. Interestingly, more than 70% of MSW is landfilled or burned, however landfill space is becoming increasingly scarce. On a smaller scale, important cellulosic products such as cellulose acetate also present waste problems; an estimated 43 thousand tons of cellulose ester waste are generated annually in the United States. Biocatalysts could be used in cellulose waste minimization and this chapter describes their characteristics and potential in bioconversion and bioremediation processes.

  9. Characterization of automotive shredder residues before and five years after landfill disposal

    Directory of Open Access Journals (Sweden)

    Lucian Ionel Cioca

    2015-04-01

    Full Text Available The paper illustrates the results of an extensive analytical characterization study of automotive shredder residues (ASR, also known as "fluff”. The analyses concerned material fractions and their content, with special reference to heavy metals (e.g. Cd, Cr, Hg, Pb, Cu and arsenic. Elution tests on the original materials were also conducted. Moreover, chemical concentrations of ASR samples after about five years' landfill residence was assessed, in order to verify possible changes resulting from both in-situ leaching and organic matter degradation phenomena. Results show that lead seems to be the most critical element in view of possible ASR acceptance in non-hazardous waste landfills because of its high concentration in raw waste and, especially, of its proven leachability characteristics.

  10. APPLICATION OF THERMAL PLASMA FOR INERTIZATION OF SLUDGE PRODUCED DURING TREATMENT OF LANDFILL LEACHATE

    Directory of Open Access Journals (Sweden)

    Anelise Leal Vieira Cubas

    Full Text Available One of the outstanding issues of concern by governments and society in general relates to the final destination of solid waste, which can bring severe impacts on social, political, economic and environmental dimensions. The sustainable development of enterprises and industries goes for the care of the planet, thus ensuring the quality of life for future generations and the planet. The disposal of municipal waste in landfills is the technique most commonly employed for the remediation of solid residues. The residues undergo decomposition beneath the soil and in the presence of water this generates leachate, which percolates down to the bottom of the landfill through drainage. This drained liquid is collected from the landfill installations and subjected to treatment, which involves physico-chemical and biological processes. Landfill leachate commonly contains heavy metals due to the incorrect disposal of products such as fluorescent bulbs and batteries. In this context, a method for the treatment of sludge originating from the physicochemical remediation of leachate using thermal plasma is proposed in this paper. The efficiency of the method was verified by monitoring the total organic carbon content, water content and density of the sludge. The quantity of metals present in the samples was determined before and after pyrolysis by thermal plasma using flame atomic absorption spectroscopy (FAAS, scanning electron microscopy (SEM and X-ray fluorescence (XRF spectrometry techniques. The results show that the leachate treatment method used was efficient, presenting the best results for the samples of iron and zinc.

  11. Municipal Solid Waste Resources

    Energy Technology Data Exchange (ETDEWEB)

    None

    2016-06-01

    Municipal solid waste (MSW) is a source of biomass material that can be utilized for bioenergy production with minimal additional inputs. MSW resources include mixed commercial and residential garbage such as yard trimmings, paper and paperboard, plastics, rubber, leather, textiles, and food wastes. Waste resources such as landfill gas, mill residues, and waste grease are already being utilized for cost-effective renewable energy generation. MSW for bioenergy also represents an opportunity to divert greater volumes of residential and commercial waste from landfills.

  12. Characterization and toxicological evaluation of leachate from closed sanitary landfill.

    Science.gov (United States)

    Emenike, Chijioke U; Fauziah, Shahul H; Agamuthu, P

    2012-09-01

    Landfilling is a major option in waste management hierarchy in developing nations. It generates leachate, which has the potential of polluting watercourses. This study analysed the physico-chemical components of leachate from a closed sanitary landfill in Malaysia, in relation to evaluating the toxicological impact on fish species namely Pangasius sutchi S., 1878 and Clarias batrachus L., 1758. The leachate samples were taken from Air Hitam Sanitary Landfill (AHSL) and the static method of acute toxicity testing was experimented on both fish species at different leachate concentrations. Each fish had an average of 1.3 ± 0.2 g wet weight and length of 5.0 ± 0.1 cm. Histology of the fishes was examined by analysing the gills of the response (dead) group, using the Harris haemtoxylin and eosin (H&E) method. Finneys' Probit method was utilized as a statistical tool to evaluate the data from the fish test. The physico-chemical analysis of the leachate recorded pH 8.2 ± 0.3, biochemical oxygen demand 3500 ± 125 mg L(-1), COD 10 234 ± 175 mg L(-1), ammonical nitrogen of 880 ± 74 mg L(-1), benzene 0.22 ± 0.1 mg L(-1) and toluene 1.2 ± 0.4 mg L(-1). The 50% lethality concentration (LC(50)) values calculated after 96 h exposure were 3.2% (v/v) and 5.9% (v/v) of raw leachate on P. sutchi and C. batrachus, respectively. The H&E staining showed denaturation of the nucleus and cytoplasm of the gills of the response groups. Leachate from the sanitary landfill was toxic to both fish species. The P. sutchi and C. batrachus may be used as indicator organisms for leachate pollution in water.

  13. Quantification of chemical contaminants in the paper and board fractions of municipal solid waste

    DEFF Research Database (Denmark)

    Pivnenko, Kostyantyn; Olsson, Mikael Emil; Götze, Ramona

    2016-01-01

    on the production technology or the potential end-use of the material. Paper has been previously shown to potentially contain a large variety of chemicals. Quantitative data on the presence of chemicals in paper are necessary for appropriate waste paper management, including the recycling and re-processing of paper......Chemicals are used in materials as additives in order to improve the performance of the material or the production process itself. The presence of these chemicals in recyclable waste materials may potentially affect the recyclability of the materials. The addition of chemicals may vary depending....... However, a lack of quantitative data on the presence of chemicals in paper is evident in the literature. The aim of the present work is to quantify the presence of selected chemicals in waste paper derived from households. Samples of paper and board were collected from Danish households, including both...

  14. Quantification of long term emission potential from landfills

    NARCIS (Netherlands)

    Heimovaara, T.J.

    2011-01-01

    Novel approaches for the after-care of Municipal Solid Waste (MSW) landfills are based on technological measures to reduce the long term emission potential in a short time period. Biological degradation in landfills is a means to significantly reduce the long term emission potential. Leachate emissi

  15. Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco)

    Science.gov (United States)

    Chofqi, Amina; Younsi, Abedelkader; Lhadi, El Kbir; Mania, Jacky; Mudry, Jacques; Veron, Alain

    2004-06-01

    The El Jadida landfill is one among many uncontrolled dumping sites in Morocco with no bottom liner. About 150 tons/day of solid wastes from mixed urban and industrial origins are placed directly on the ground. At the site of this landfill, the groundwaters circulate deeply (10-15 m) in the Cenomanian rock (calcareous-marl), which is characterised by an important permeability from cracks. The soil is sand-clay characterized by a weak coefficient of retention. The phreatic water ascends to the bottom of three quarries, which are located within the landfill. These circumstances, along with the lack of a leachate collection system, worsen the risks for a potential deterioration of the aquifer. To evaluate groundwater pollution due to this urban landfill, piezometric level and geochemical analyses have been monitored since 1999 on 60 wells. The landfill leachate has been collected from the three quarries that are located within the landfill. The average results of geochemical analyses show an important polluant charge vehiculed by landfill leachate (chloride = 5680 mg l -1, chemical oxygen demand = 1000 mg l -1, iron = 23 000 μg l -1). They show also an important qualitative degradation of the groundwater, especially in the parts situated in the down gradient area and in direct proximity to the landfill. In these polluted zones, we have observed the following values: higher than 4.5 mS cm -1 in electric conductivity, 1620 and 1000 mg l -1 respectively in chlorides and sulfate ( SO42-), 15-25 μg l -1 in cadmium, and 60-100 μg l -1 in chromium. These concentrations widely exceed the standard values for potable water. Several determining factors in the evolution of groundwater contamination have been highlighted, such as (1) depth of the water table, (2) permeability of soil and unsaturated zone, (3) effective infiltration, (4) humidity and (5) absence of a system for leachate drainage. So, to reduce the pollution risks of the groundwater, it is necessary to set a

  16. Modelling of the flow in the interface of a composite liner at the bottom of a municipal waste landfill; Modelisation des ecoulements dans les interfaces des barrieres d'etancheite composites des installations de stockage de dechets

    Energy Technology Data Exchange (ETDEWEB)

    Cartaud, F

    2004-11-15

    Composite liner at the bottom of waste landfill is based, in France, on a geo-membrane overlapping a compacted clay liner. Defects exist in geo-membranes and leachates, provided by water percolation through the waste, then flow in the interface between the two components of the lining system. The present work consisted in analysis, quantification and modelling of the leakage process in the interface. The experimental study has been carried out on a one-meter scale device in laboratory and allowed to assess the role of normal stress on the flow rate in interface. The case where a geo-textile is present beneath the geo-membrane has been also studied. The modelling allows to take into account more accurately the geometry of the interface and ensures a better quantification of leachate flow rates than using existing methods. (author)

  17. ER Operations Installation of Three FLUTe Soil-Vapor Monitoring Wells (MWL-SV03 MWL-SV04 and MWL-SV05) at the Mixed Waste Landfill.

    Energy Technology Data Exchange (ETDEWEB)

    Copland, John Robin [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-09-01

    This installation report describes the May through July 2014 drilling activities performed for the installation of three multi-port soil-vapor monitoring wells (MWL-SV03, MWL-SV04, and MWL-SV05) at the Mixed Waste Landfill (MWL), which is located at Sandia National Laboratories, New Mexico (SNL/NM). SNL/NM is managed and operated by Sandia Corporation (Sandia), a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy (DOE)/National Nuclear Security Administration. The MWL is designated as Solid Waste Management Unit (SWMU) 76 and is located in Technical Area (TA) III (Figure 1-1). The locations of the three soil-vapor monitoring wells (MWL-SV03, MWL-SV04, and MWL-SV05) are shown in Figure 1-2

  18. International training seminar: high training on sanitary landfills design, Madrid 7-11, April 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    The seminar on design of sanitary landfills was articulated in 5 sessions: 1.- Design of sanitary landfills depending on the quality of wastes. 2.- Legal, techniques and administrative aspects of management. 3.- Geotechniques studies 4.- Biogas 5.- Environmental impact of sanitary landfills.

  19. Opportunity for high value-added chemicals from food supply chain wastes.

    Science.gov (United States)

    Matharu, Avtar S; de Melo, Eduardo M; Houghton, Joseph A

    2016-09-01

    With approximately 1.3 billion tonnes of food wasted per annum, food supply chain wastes (FSCWs) may be viewed as the contemporary Periodic Table of biobased feedstock chemicals (platform molecules) and functional materials. Herein, the global drivers and case for food waste valorisation within the context of global sustainability, sustainable development goals and the bioeconomy are discussed. The emerging potential of high value added chemicals from certain tropical FSCW is considered as these are grown in three major geographical areas: Brazil, India and China, and likely to increase in volume. FSCW in the context of biorefineries is discussed and two case studies are reported, namely: waste potato, and; orange peel waste. Interestingly, both waste feedstocks, like many others, produce proteins and with the global demand for vegetable proteins on the rise then proteins from FSCW may become a dominant area.

  20. Preliminary Study on Chemical Components and Uranium Content of Calcium Fluoride Waste

    Institute of Scientific and Technical Information of China (English)

    LIANG; Xiao-hu; YANG; Lei; YANG; Jin-ling; SONG; Zhi-jun

    2013-01-01

    In the uranium conversion process,UF4 reduction is needed using calcium as reduction regent,so a great deal of calcium fluoride are generated,in which a no negligible amount of uranium(about 5%alleged)can be left in the calcium fluoride wastes by the entrainment effect.It is meaningful to extract and purify the uranium from these wastes,but chemical components of these waste is needed primarily.

  1. Life in a landfill slum, children's health, and the Millennium Development Goals

    Energy Technology Data Exchange (ETDEWEB)

    Shibata, Tomoyuki, E-mail: tshibata@niu.edu [Public Health Program, Northern Illinois University, DeKalb, IL (United States); Institute of the Study for Environment, Sustainability, and Energy, Northern Illinois University, DeKalb, IL (United States); Faculty of Public Health, Hasanuddin University, Makassar, South Sulawesi (Indonesia); Wilson, James L. [Institute of the Study for Environment, Sustainability, and Energy, Northern Illinois University, DeKalb, IL (United States); Department of Geography, Northern Illinois University, DeKalb, IL (United States); Watson, Lindsey M.; Nikitin, Ivan V. [Public Health Program, Northern Illinois University, DeKalb, IL (United States); Ansariadi; La Ane, Ruslan; Maidin, Alimin [Faculty of Public Health, Hasanuddin University, Makassar, South Sulawesi (Indonesia)

    2015-12-01

    People living in slums can be considered left behind with regard to national successes in achieving Millennium Development Goals (MDGs). The objective of this study was to evaluate the living and working conditions of waste pickers and their children in a landfill slum located in the largest city in eastern Indonesia. A total of 113 people from the landfill slum and 1184 people from the general population participated in face-to-face interviews. Municipal solid waste (MSW) was analyzed for metals, metalloids and fecal indicator bacteria. Ambient air quality including particulate matter was measured in the landfill. Households in the landfill slum were 5.73 (p = 0.04) times more likely to be below the international poverty line (MDG 1: Poverty) and 15.6 times (p < 0.01) more likely to have no one in the household possessing a primary education (MDG 2: Universal Education), and 107 times (p < 0.01) more likely not to have improved sanitation facilities (MDG 7: Environmental Sustainability) when compared to the general population. Diarrhea is one of the leading causes of death in children under five in Indonesia. Young children living in the landfill slum were 2.87 times (p = 0.02) more likely to develop diarrhea than their general population counterparts. Other survey results and environmental measurements suggest that landfill slum children have additional adverse health effects (e.g. infections and poisoning). Poverty underlies several MDG issues that directly or indirectly affect child health. Therefore, eradicating extreme poverty will continue to be the most critical challenge for the MDGs beyond 2015. - Highlights: • Waste-pickers and the health and well-being of their children are examined • Landfill slum (LS) residents do not have a share in improving economies • LSs illustrate the interrelationship of Millennium Development Goals • LS mothers and children are exposed to toxic chemicals and pathogens • MDGs directly and indirectly addresses issues

  2. Metal concentrations of simulated aerobic and anaerobic pilot scale landfill reactors

    Energy Technology Data Exchange (ETDEWEB)

    Sinan Bilgili, M. [Yildiz Technical University, Environmental Engineering Department, 34349 Yildiz, Besiktas, Istanbul (Turkey)]. E-mail: mbilgili@yildiz.edu.tr; Demir, Ahmet [Yildiz Technical University, Environmental Engineering Department, 34349 Yildiz, Besiktas, Istanbul (Turkey)]. E-mail: ahmetd@yildiz.edu.tr; Ince, Mahir [Department of Environmental Engineering, Gebze Institute of Technology, 41400 Gebze (Turkey)]. E-mail: mahirince@gyte.edu.tr; Ozkaya, Bestamin [Yildiz Technical University, Environmental Engineering Department, 34349 Yildiz, Besiktas, Istanbul (Turkey)]. E-mail: bozkaya@yildiz.edu.tr

    2007-06-25

    Leachate and solid waste samples from aerobic and anaerobic simulated landfill reactors operated with and without leachate recirculation were characterized in terms of metals such as Fe, Ca, K, Na, Cd, Cr, Cu, Pb, Ni, and Zn. Metal concentrations of aerobic landfill reactor leachate samples are always below the regulation limits. The higher concentrations in anaerobic landfill leachate samples decreased to regulation limits after the landfill becomes methanogenic. The effect of leachate recirculation is determined in anaerobic landfills more clearly than aerobic landfills. Metal precipitation resulted in a decrease in leachate metal content and an increase in solid waste metal content as expected. Result of the study show that the metal content of landfill leachate samples is not a major concern for both aerobic and anaerobic landfills.

  3. Municipal landfill leachates: A significant source for new and emerging pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Eggen, Trine, E-mail: Trine.Eggen@bioforsk.no [Bioforsk, Vest Saerheim, Norwegian Institute for Agricultural and Environmental Research, Postveien 213, N-4353 Klepp st. (Norway); Moeder, Monika [Helmholtz Centre for Environmental Research UFZ, Department of Analytical Chemistry, Permoserstrasse 15, D-04318 Leipzig (Germany); Arukwe, Augustine [Department of Biology, Norwegian University of Science and Technology (NTNU), Hogskoleringen 5, 7491 Trondheim (Norway)

    2010-10-01

    Landfills have historically remained the most common methods of organized waste disposal and still remain so in many regions of the world. Thus, they may contain wastes resulting from several decades of disposal and decomposition with subsequent release of organic compounds that may have environmental, wildlife and human health consequences. Products containing different types of additives with unique beneficial improvement properties are in daily use. However, when these products are decomposed, additives are release into the environment, some of which have been shown to have negative environmental impacts, resulting in the ban or at least restricted application of some chemicals. New and emerging compounds are continuously discovered in the environment. Herein, we report qualitative and quantitative data on the occurrence of new and emerging compounds with increasing environmental and public health concern in water- and particle phase of landfill leachates. Under normal environmental conditions, several of these chemicals are persistent high-volume products. Identified chemicals in the leachates at nanogram (ng) or microgram ({mu}g) per liter levels include - chlorinated alkylphosphates such as tris(1-chloro-2-propyl) phosphate (TCPP), N-butyl benzensulfonamide (NBBS), the insect repellent diethyl toluamide (DEET) and personal care products such as the non-steroidal anti-inflammatory drug ibuprofen and polycyclic musk compounds. Among new and emerging contaminants, perfluorinated compounds (PFCs) were measured in the water phase at concentrations up to 6231 ng/L. Compared with the other chemicals, PFCs were primarily distributed in water phase. An effective removal method for PFCs and other polar and persistent compounds from landfill leachates has been a major challenge, since commonly used treatment technologies are based on aeration and sedimentation. Thus, the present study has shown that municipal landfill leachates may represent a significant source of

  4. GREENER CHEMICAL PROCESS DESIGN ALTERNATIVES ARE REVEALED USING THE WASTE REDUCTION DECISION SUPPORT SYSTEM (WAR DSS)

    Science.gov (United States)

    The Waste Reduction Decision Support System (WAR DSS) is a Java-based software product providing comprehensive modeling of potential adverse environmental impacts (PEI) predicted to result from newly designed or redesigned chemical manufacturing processes. The purpose of this so...

  5. EVALUATION OF CHEMICALLY BONDED PHOSPHATE CERAMICS FOR MERCURY STABILIZATION OF A MIXED SYNTHETIC WASTE

    Science.gov (United States)

    This experimental study was conducted to evaluate the stabilization and encapsulation technique developed by Argonne National Laboratory, called the Chemically Bonded Phosphate Ceramics technology for Hg- and HgCl2-contaminated synthetic waste materials. Leachability ...

  6. Case study: City of Industry landfill gas recovery operation

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-11-01

    Development of civic, recreation, and conservation facilities throughout a 150-acre site which had been used for waste disposal from 1951 to 1970 is described. The history of the landfill site, the geology of the site, and a test well program to assess the feasibility of recoverying landfill gas economically from the site are discussed. Based on results of the test well program, the City of Industry authorized the design and installation of a full-scale landfill gas recovery system. Design, construction, and operation of the system are described. The landfill gas system provides fuel for use in boilers to meet space heating and hot water demands for site development (MCW)

  7. Composition and production rate of pharmaceutical and chemical waste from Xanthi General Hospital in Greece.

    Science.gov (United States)

    Voudrias, Evangelos; Goudakou, Lambrini; Kermenidou, Marianthi; Softa, Aikaterini

    2012-07-01

    The objective of this work was to determine the composition and production rates of pharmaceutical and chemical waste produced by Xanthi General Hospital in Greece (XGH). This information is important to design and cost management systems for pharmaceutical and chemical waste, for safety and health considerations and for assessing environmental impact. A total of 233 kg pharmaceutical and 110 kg chemical waste was collected, manually separated and weighed over a period of five working weeks. The total production of pharmaceutical waste comprised 3.9% w/w of the total hazardous medical waste produced by the hospital. Total pharmaceutical waste was classified in three categories, vial waste comprising 51.1%, syringe waste with 11.4% and intravenous therapy (IV) waste with 37.5% w/w of the total. Vial pharmaceutical waste only was further classified in six major categories: antibiotics, digestive system drugs, analgesics, hormones, circulatory system drugs and "other". Production data below are presented as average (standard deviation in parenthesis). The unit production rates for total pharmaceutical waste for the hospital were 12.4 (3.90) g/patient/d and 24.6 (7.48) g/bed/d. The respective unit production rates were: (1) for vial waste 6.4 (1.6) g/patient/d and 13 (2.6) g/bed/d, (2) for syringe waste 1.4 (0.4) g/patient/d and 2.8 (0.8) g/bed/d and (3) for IV waste 4.6 (3.0) g/patient/d and 9.2 (5.9) g/bed/d. Total chemical waste was classified in four categories, chemical reagents comprising 18.2%, solvents with 52.3%, dyes and tracers with 18.2% and solid waste with 11.4% w/w of the total. The total production of chemical waste comprised 1.8% w/w of the total hazardous medical waste produced by the hospital. Thus, the sum of pharmaceutical and chemical waste was 5.7% w/w of the total hazardous medical waste produced by the hospital. The unit production rates for total chemical waste for the hospital were 5.8 (2.2) g/patient/d and 1.1 (0.4) g/exam/d. The respective

  8. Hanford enhanced waste glass characterization. Influence of composition on chemical durability

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-06-01

    This report provides a review of the complete high-level waste (HLW) and low-activity waste (LAW) data sets for the glasses recently fabricated at Pacific Northwest National Laboratory and characterized at Savannah River National Laboratory (SRNL). The review is from the perspective of relating the chemical durability performance to the compositions of these study glasses, since the characterization work at SRNL focused on chemical analysis and ASTM Product Consistency Test (PCT) performance.

  9. Physical-chemical and bacteriological aspects of the groundwater in the sanitary landfills in the metropolitan region of Londrina, Paraná, Brazil

    Directory of Open Access Journals (Sweden)

    Luiz Henrique Dall´Antonia

    2006-02-01

    Full Text Available A detailed study of the physical-chemical and bacteriological qualities of the subterranean water at sanitary landfills in the Metropolitan Region of Londrina (PR, was carried out. The field of twelve wells that reach the groundwater as well as the emergence of the watertable of the Periquitos River, were also monitored. The results of the analyses of 120 samples of the collected water were compared to the permissible maximum values for human consumption according to the Federal Legislation in Brazil. Total excrements were found around 3,1 NMP/100mL (Well 4 and 120330 NMP/100mL (Periquitos River and fecal matter between 0 and 4100 NMP/100mL (Periquitos River. Such values were associated to the contamination caused by the presence of animals from neighbor properties, feeding themselves in that region. The pH, turbidity, COD and BOD were among the values expected, except for the conductivity that showed to be altered.

  10. 添加垃圾渗滤液对厨余垃圾厌氧发酵产氢的影响%Influence of feedstock proportion on anaerobic fermentative hydrogen production of kitchen waste and landfill leachate

    Institute of Scientific and Technical Information of China (English)

    刘婉玉; 叶景清; 甄峰; 郭燕锋; 袁振宏; 孙永明; 李东

    2012-01-01

    Using kitchen waste and landfill leachate as anaerobic fermentation materials, influences of feedstock proportion on stability of anaerobic fermentation and performance of hydrogen production were investigated. Experimental results showed that low proportion of landfill leachate can reduce the delay time and have not influence on the stability of anaerobic fermentation.The ammonia inhibition was easy to form when the proportion of landfill leachate increase gradually. The 100 g landfill leachate was added to 40 g kitchen waste, the delay time was 6 hours, hydrogen contents was kept at 50%, the maximum hydrogen production rate was 4.8 mL/(h · g), the final hydrogen production was 48.37 mL/g. The higher proportion could not realize effective hydrogen production due to the inhibition of ammonia. The hydrogen production rates were lower than 2.5 mL/(h · g) and the final hydrogen productions were 16~30 mL/g.%以厨余垃圾和垃圾渗滤液为原料,考察了垃圾渗滤液的不同添加量对厌氧消化稳定性及产氢气性能的影响.结果表明,在厨余垃圾中添加少量的垃圾渗滤液能缩短厌氧消化的延滞期而不影响其消化及产气性能,垃圾渗滤液浓度越高则越容易形成氨抑制,严重影响厌氧消化作用的进行.在40 g厨余原料中添加100 g垃圾渗滤液,其厌氧消化延滞期为6h,氢气含量稳定在50%,最大产氢气速率为4.8 mL/(h·g),最终氢气产量为48.37 mL/g;添加200~500 g垃圾渗滤液均形成氨抑制,严重影响产气性能,产气速率均低于2.5 mL/(h·g),最终产气量为16~30 mL/g.

  11. Evaluating the ability of artificial neural network and PCA-M5P models in predicting leachate COD load in landfills.

    Science.gov (United States)

    Azadi, Sama; Amiri, Hamid; Rakhshandehroo, G Reza

    2016-09-01

    Waste burial in uncontrolled landfills can cause serious environmental damages and unpleasant consequences. Leachates produced in landfills have the potential to contaminate soil and groundwater resources. Leachate management is one of the major issues with respect to landfills environmental impacts. Improper design of landfills can lead to leachate spread in the environment, and hence, engineered landfills are required to have leachate monitoring programs. The high cost of such programs may be greatly reduced and cost efficiency of the program may be optimized if one can predict leachate contamination level and foresee management and treatment strategies. The aim of this study is to develop two expert systems consisting of Artificial Neural Network (ANN) and Principal Component Analysis-M5P (PCA-M5P) models to predict Chemical Oxygen Demand (COD) load in leachates produced in lab-scale landfills. Measured data from three landfill lysimeters, including rainfall depth, number of days after waste deposition, thickness of top and bottom Compacted Clay Liners (CCLs), and thickness of top cover over the lysimeter, were utilized to develop, train, validate, and test the expert systems and predict the leachate COD load. Statistical analysis of the prediction results showed that both models possess good prediction ability with a slight superiority for ANN over PCA-M5P. Based on test datasets, the mean absolute percentage error for ANN and PCA-M5P models were 4% and 12%, respectively, and the correlation coefficient for both models was greater than 0.98. Developed models may be used as a rough estimate for leachate COD load prediction in primary landfill designs, where the effect of a top and/or bottom liner is disputed.

  12. Quantification of methane emissions from 15 Danish landfills using the mobile tracer dispersion method

    Energy Technology Data Exchange (ETDEWEB)

    Mønster, Jacob [Department of Environmental Engineering, Technical University of Denmark, Miljøvej – Building 113, DK-2800 Lyngby (Denmark); Samuelsson, Jerker, E-mail: jerker.samuelsson@fluxsense.se [Chalmers University of Technology/FluxSense AB, SE-41296 Göteborg (Sweden); Kjeldsen, Peter [Department of Environmental Engineering, Technical University of Denmark, Miljøvej – Building 113, DK-2800 Lyngby (Denmark); Scheutz, Charlotte, E-mail: chas@env.dtu.dk [Department of Environmental Engineering, Technical University of Denmark, Miljøvej – Building 113, DK-2800 Lyngby (Denmark)

    2015-01-15

    Highlights: • Quantification of whole landfill site methane emission at 15 landfills. • Multiple on-site source identification and quantification. • Quantified methane emission from shredder waste and composting. • Large difference between measured and reported methane emissions. - Abstract: Whole-site methane emissions from 15 Danish landfills were assessed using a mobile tracer dispersion method with either Fourier transform infrared spectroscopy (FTIR), using nitrous oxide as a tracer gas, or cavity ring-down spectrometry (CRDS), using acetylene as a tracer gas. The landfills were chosen to represent the different stages of the lifetime of a landfill, including open, active, and closed covered landfills, as well as those with and without gas extraction for utilisation or flaring. Measurements also included landfills with biocover for oxidizing any fugitive methane. Methane emission rates ranged from 2.6 to 60.8 kg h{sup −1}, corresponding to 0.7–13.2 g m{sup −2} d{sup −1}, with the largest emission rates per area coming from landfills with malfunctioning gas extraction systems installed, and the smallest emission rates from landfills closed decades ago and landfills with an engineered biocover installed. Landfills with gas collection and recovery systems had a recovery efficiency of 41–81%. Landfills where shredder waste was deposited showed significant methane emissions, with the largest emission from newly deposited shredder waste. The average methane emission from the landfills was 154 tons y{sup −1}. This average was obtained from a few measurement campaigns conducted at each of the 15 landfills and extrapolating to annual emissions requires more measurements. Assuming that these landfills are representative of the average Danish landfill, the total emission from Danish landfills were calculated at 20,600 tons y{sup −1}, which is significantly lower than the 33,300 tons y{sup −1} estimated for the national greenhouse gas inventory for

  13. Challenges and issues in moving towards sustainable landfilling in a transitory country - Malaysia.

    Science.gov (United States)

    Agamuthu, P; Fauziah, S H

    2011-01-01

    Malaysia disposes of 28,500 tonnes of municipal solid waste directly into landfills daily. This fact alone necessitates sustainable landfills to avoid adverse impacts on the population and the environment. The aim of the present study was to elucidate the issues and challenges faced by waste managers in moving towards sustainable landfilling in Malaysia. Various factors influence the management of a landfill. Among them is the human factor, which includes attitude and public participation. Although Malaysia's economy is developing rapidly, public concern and awareness are not evolving in parallel and therefore participation towards sustainable waste management through the 'reduce, reuse and recycle' approach (3Rs) is severely lacking. Consequently, landfill space is exhausted earlier than scheduled and this is no longer sustainable in terms of security of disposal. Challenges also arise from the lack of funding and the increase in the price of land. Thus, most waste managers normally aim for 'just enough' to comply with the regulations. Investment for the establishment of landfills generally is minimized since landfilling operations are considered uneconomical after closure. Institutional factors also hamper the practice of sustainable landfilling in the country where 3Rs is not mandatory and waste separation is totally absent. Although there are huge obstacles to be dealt with in moving towards sustainable landfilling in Malaysia, recent developments in waste management policy and regulations have indicated that positive changes are possible in the near future. Consequently, with the issues solved and challenges tackled, landfills in Malaysia can then be managed effectively in a more sustainable manner.

  14. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    Energy Technology Data Exchange (ETDEWEB)

    Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

    2000-02-26

    Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with

  15. In situ containment and stabilization of buried waste

    Energy Technology Data Exchange (ETDEWEB)

    Allan, M.L.; Kukacka, L.E.; Heiser, J.H.

    1992-11-01

    The objective of the project was to develop, demonstrate and implement advanced grouting materials for the in-situ installation of impermeable, durable subsurface barriers and caps around waste sites and for the in-situ stabilization of contaminated soils. Specifically, the work was aimed at remediation of the Chemical Waste (CWL) and Mixed Waste Landfills (MWL) at Sandia National Laboratories (SNL) as part of the Mixed Waste Landfill Integrated Demonstration (MWLID). This report documents this project, which was conducted in two subtasks. These were (1) Capping and Barrier Grouts, and (2) In-situ Stabilization of Contaminated Soils. Subtask 1 examined materials and placement methods for in-situ containment of contaminated sites by subsurface barriers and surface caps. In Subtask 2 materials and techniques were evaluated for in-situ chemical stabilization of chromium in soil.

  16. Chemical analysis of simulated high level waste glasses to support stage III sulfate solubility modeling

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-03-17

    The U.S. Department of Energy (DOE), Office of Environmental Management (EM) is sponsoring an international, collaborative project to develop a fundamental model for sulfate solubility in nuclear waste glass. The solubility of sulfate has a significant impact on the achievable waste loading for nuclear waste forms within the DOE complex. These wastes can contain relatively high concentrations of sulfate, which has low solubility in borosilicate glass. This is a significant issue for low-activity waste (LAW) glass and is projected to have a major impact on the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Sulfate solubility has also been a limiting factor for recent high level waste (HLW) sludge processed at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). The low solubility of sulfate in glass, along with melter and off-gas corrosion constraints, dictate that the waste be blended with lower sulfate concentration waste sources or washed to remove sulfate prior to vitrification. The development of enhanced borosilicate glass compositions with improved sulfate solubility will allow for higher waste loadings and accelerate mission completion.The objective of the current scope being pursued by SHU is to mature the sulfate solubility model to the point where it can be used to guide glass composition development for DWPF and WTP, allowing for enhanced waste loadings and waste throughput at these facilities. A series of targeted glass compositions was selected to resolve data gaps in the model and is identified as Stage III. SHU fabricated these glasses and sent samples to SRNL for chemical composition analysis. SHU will use the resulting data to enhance the sulfate solubility model and resolve any deficiencies. In this report, SRNL provides chemical analyses for the Stage III, simulated HLW glasses fabricated by SHU in support of the sulfate solubility model development.

  17. Radiological, physical, and chemical characterization of low-level alpha contaminated wastes stored at the Idaho National Engineering Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Apel, M.L.; Becker, G.K.; Ragan, Z.K.; Frasure, J.; Raivo, B.D.; Gale, L.G.; Pace, D.P.

    1994-03-01

    This document provides radiological, physical, and chemical characterization data for low-level alpha-contaminated radioactive and low-level alpha-contaminated radioactive and hazardous (i.e., mixed) wastes stored at the Idaho National Engineering Laboratory and considered for treatment under the Private Sector Participation Initiative Program. Waste characterization data are provided in the form of INEL Waste Profile Sheets. These documents provide, for each content code, information on waste identification, waste description, waste storage configuration, physical/chemical waste composition, radionuclide and associated alpha activity waste characterization data, and hazardous constituents present in the waste. Information is provided for 97 waste streams which represent an estimated total volume of 25,450 m 3 corresponding to a total mass of approximately 12,000,000 kg. In addition, considerable information concerning alpha, beta, gamma, and neutron source term data specific to Rocky Flats-generated waste forms stored at the INEL are provided to assist in facility design specification.

  18. Enhanced Chemical Cleaning: A New Process for Chemically Cleaning Savannah River Waste Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Ketusky, Edward; Spires, Renee; Davis, Neil

    2009-02-11

    At the Savannah River Site (SRS) there are 49 High Level Waste (HLW) tanks that eventually must be emptied, cleaned, and closed. The current method of chemically cleaning SRS HLW tanks, commonly referred to as Bulk Oxalic Acid Cleaning (BOAC), requires about a half million liters (130,000 gallons) of 8 weight percent (wt%) oxalic acid to clean a single tank. During the cleaning, the oxalic acid acts as the solvent to digest sludge solids and insoluble salt solids, such that they can be suspended and pumped out of the tank. Because of the volume and concentration of acid used, a significant quantity of oxalate is added to the HLW process. This added oxalate significantly impacts downstream processing. In addition to the oxalate, the volume of liquid added competes for the limited available tank space. A search, therefore, was initiated for a new cleaning process. Using TRIZ (Teoriya Resheniya Izobretatelskikh Zadatch or roughly translated as the Theory of Inventive Problem Solving), Chemical Oxidation Reduction Decontamination with Ultraviolet Light (CORD-UV{reg_sign}), a mature technology used in the commercial nuclear power industry was identified as an alternate technology. Similar to BOAC, CORD-UV{reg_sign} also uses oxalic acid as the solvent to dissolve the metal (hydr)oxide solids. CORD-UV{reg_sign} is different, however, since it uses photo-oxidation (via peroxide/UV or ozone/UV to form hydroxyl radicals) to decompose the spent oxalate into carbon dioxide and water. Since the oxalate is decomposed and off-gassed, CORD-UV{reg_sign} would not have the negative downstream oxalate process impacts of BOAC. With the oxalate destruction occurring physically outside the HLW tank, re-precipitation and transfer of the solids, as well as regeneration of the cleaning solution can be performed without adding additional solids, or a significant volume of liquid to the process. With a draft of the pre-conceptual Enhanced Chemical Cleaning (ECC) flowsheet, taking full

  19. Biogas generation in landfills. Equilibria, rates and yields

    Energy Technology Data Exchange (ETDEWEB)

    Aakesson, M.

    1997-05-01

    Landfilling in `cells` has become more common in recent years. Different waste streams are guided to different cells, among which the biocell is a landfill designed for biogas production. In this thesis, the dependence of biogas generation on waste composition was investigated. Six 8,000 m{sup 3} test cells, with contents ranging from mainly commercial waste to pure domestic waste and equipped with gas extraction systems and bottom plastic liners, were monitored for seven years. Great emphasis was given to the characterization of conversion processes and governing mechanism in the topics of bio-energetics, kinetics and capacities. A thermodynamic model, in which the oxidations of volatile fatty acids (VFA) (2chemical oxygen demand, N, P and K were quantified. Biomass pools were estimated from methane yields, growth yield coefficients, and bacterial mineral contents. However, results from commercial waste test cells showed that the assimilation of P exceeded the refuse content, which suggests the turnover of microbial biomass and questions the notion of nutritional limitation. In sum, the results showed that the advantages of a reduced content of readily biodegradable material, achieved by guidance or pretreatment, encompass several aspects of the performance. 84 refs, 6 figs, 1 tab

  20. Indirect Determination of Chemical Composition and Fuel Characteristics of Solid Waste

    DEFF Research Database (Denmark)

    Riber, Christian; Christensen, Thomas Højlund

    Determination of chemical composition of solid waste can be performed directly or indirectly by analysis of combustion products. The indirect methodology instrumented by a full scale incinerator is the only method that can conclude on elements in trace concentrations. These elements are of great...... interest in evaluating waste management options by for example LCA modeling. A methodology description of indirect determination of chemical composition and fuel properties of waste is provided and validated by examples. Indirect analysis of different waste types shows that the chemical composition...... of toxic elements is shown exemplified by Hg. The average concentration is evaluated to be affected by three occurrences; background, rare items and very rare items (1/800 tonnes), that are all important to the Hg average concentration....

  1. Savannah River Site chemical, metal, and pesticide (CMP) waste vitrification treatability studies

    Energy Technology Data Exchange (ETDEWEB)

    Cicero, C.A.

    1997-01-13

    Numerous Department of Energy (DOE) facilities, as well as Department of Defense (DOD) and commercial facilities, have used earthen pits for disposal of chemicals, organic contaminants, and other waste materials. Although this was an acceptable means of disposal in the past, direct disposal into earthen pits without liners or barriers is no longer a standard practice. At the Savannah River Site (SRS), approximately three million pounds of such material was removed from seven chemical, metal, and pesticide disposal pits. This material is known as the Chemical, Metal, and Pesticide (CMP) Pit waste and carries several different listed waste codes depending on the contaminants in the respective storage container. The waste is not classified as a mixed waste because it is believed to be non-radioactive; however, in order to treat the material in a non-radioactive facility, the waste would first have to be screened for radioactivity. The Defense Waste Processing Technology (DWPT) Section of the Savannah River Technology Center (SRTC) was requested by the DOE-Savannah River (SR) office to determine the viability of vitrification of the CMP Pit wastes. Radioactive vitrification facilities exist which would be able to process this waste, so the material would not have to be analyzed for radioactive content. Bench-scale treatability studies were performed by the DWPT to determine whether a homogeneous and durable glass could be produced from the CMP Pit wastes. Homogeneous and durable glasses were produced from the six pits sampled. The optimum composition was determined to be 68.5 wt% CMP waste, 7.2 wt% Na{sub 2}O, 9 wt% CaO, 7.2 wt% Li{sub 2}O and 8.1 wt% Fe{sub 2}O{sub 3}. This glass melted at 1,150 C and represented a two fold volume reduction.

  2. Landfill monitoring using remote sensing: a case study of Glina, Romania.

    Science.gov (United States)

    Iacoboaea, Cristina; Petrescu, Florian

    2013-10-01

    Landfill monitoring is one of the most important components of waste management. This article presents a case study on landfill monitoring using remote sensing technology. The study area was the Glina landfill, one of the largest municipal waste disposal sites in Romania. The methodology consisted of monitoring the differences of temperature computed for several distinct waste disposal zones with respect to a ground reference area, all of them located within the landfill site. The remote sensing data used were Landsat satellite multi-temporal data. The differences of temperature were computed using Landsat thermal infrared data. The study confirmed the use of multi-temporal Landsat imagery as a complementary data source.

  3. Mineral and organic compounds in leachate from landfill with concentrate recirculation.

    Science.gov (United States)

    Talalaj, Izabela Anna

    2015-02-01

    The effect of a reverse osmosis concentrate recirculation on the mineral and organic compounds in a landfill leachate was investigated. Investigated was the quality of a leachate from two landfills operated for different periods (a 20-year-old Cell A and a 1-year-old Cell B), where the concentrate was recirculated. Examined were general parameters (conductivity, pH), organic compounds (biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic nitrogen, BOD/COD), and inorganic compounds (nitrogen ammonia, sulfite, sulfate, cyanide, boron, chloride, ferrous, zinc, chrome, copper). The findings from the first year of investigation showed that over the initial period of recirculation, the concentration of organic compounds (BOD, COD) increased, but after 6 months their values stabilized. It indicates that the concentrate recirculation accelerated organic decomposition, especially in the new landfill Cell. The analysis of inorganic parameters showed that recirculation landfills produce a leachate with a higher concentration of N-NH4, and Cl(-). In case of the old landfill Cell, an increase in B and Fe was also noticeable. These compounds are cyclically washed out from a waste dump and require an additional pretreatment in order to exclude them from recirculation cycle. The increased concentration of Cu, Zn, and Fe was noticed during the initial months of recirculation and in the season of intense atmospheric precipitation in the leachate from both Cells. Higher values of electro conductivity, Cl(-), N-NH4 (+), B, and Fe in the leachate from the old field indicate that the attenuation capacity of this landfill is close to exhaustion.

  4. Utilizing environmental management information systems to monitor chemical usage and facilitate waste minimization

    Energy Technology Data Exchange (ETDEWEB)

    Blazer, T.L.; Kinney, R.W. [Modern Technologies Corporation, Dayton, OH (United States)

    1996-10-01

    Waste minimization and pollution prevention activities have proven to be valuable to the chemical industry`s and the chemical user`s bottom line. Many companies have found that, with a modest initial capital investment and product modifications, mounds of bureaucratic liability can be removed and substantial cost savings can be realized.

  5. Chemical compatibility screening results of plastic packaging to mixed waste simulants

    Energy Technology Data Exchange (ETDEWEB)

    Nigrey, P.J.; Dickens, T.G.

    1995-12-01

    We have developed a chemical compatibility program for evaluating transportation packaging components for transporting mixed waste forms. We have performed the first phase of this experimental program to determine the effects of simulant mixed wastes on packaging materials. This effort involved the screening of 10 plastic materials in four liquid mixed waste simulants. The testing protocol involved exposing the respective materials to {approximately}3 kGy of gamma radiation followed by 14 day exposures to the waste simulants of 60 C. The seal materials or rubbers were tested using VTR (vapor transport rate) measurements while the liner materials were tested using specific gravity as a metric. For these tests, a screening criteria of {approximately}1 g/m{sup 2}/hr for VTR and a specific gravity change of 10% was used. It was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only VITON passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. It is anticipated that those materials with the lowest VTRs will be evaluated in the comprehensive phase of the program. For specific gravity testing of liner materials the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals.

  6. Evolution on qualities of leachate and landfill gas in the semi-aerobic landfill

    Institute of Scientific and Technical Information of China (English)

    HUANG Qifei; YANG Yufei; PANG Xiangrui; WANG Qi

    2008-01-01

    To study the characteristics of stabilization in semi-aerobic landfill, large-scale simulated landfill was constructed based on the semi-aerobic landfill theory. Consequently, the concentrations of chemical oxygen demand (COD), ammonia nitrogen, and nitrite nitrogen, and the pH value in leachate, as well as the component contents of landfill gas composition (methane, carbon dioxide, and oxygen) in landfill were regularly monitored for 52 weeks. The results showed that COD and ammonia concentrations declined rapidly and did not show the accumulating rule like anaerobic landfill, and remained at about 300 and 100 mg/L, respectively, after 48 weeks. Meanwhile, the descending rate reached 98.9% and 96.9%, respectively. Nitrate concentration increased rapidly after 24 weeks and fluctuated between 220-280 mg/L after 43 weeks. The pH values were below 7 during the first 8 weeks and after that leachates appeared to be alkaline. Carbon dioxide was the main composition in landfill gas and its concentration remained at a high level through the whole stabilization process. The average contents of carbon dioxide, oxygen, and methane varied between 19 vol.%-28 vol.%, 2 vol.%-8 vol.%, and 5 vol.%-13 vol.%, respectively. A relative equilibrium was reached after 48 weeks. The highest temperature in the landfill chamber could amount to 75.8 degrees centigrade.

  7. Landfill mining: Developing a comprehensive assessment method.

    Science.gov (United States)

    Hermann, Robert; Wolfsberger, Tanja; Pomberger, Roland; Sarc, Renato

    2016-11-01

    In Austria, the first basic technological and economic examinations of mass-waste landfills with the purpose to recover secondary raw materials have been carried out by the 'LAMIS - Landfill Mining Österreich' pilot project. A main focus of its research, and the subject of this article, is the first conceptual design of a comprehensive assessment method for landfill mining plans, including not only monetary factors (like costs and proceeds) but also non-monetary ones, such as the concerns of adjoining owners or the environmental impact. Detailed reviews of references, the identification of influences and system boundaries to be included in planning landfill mining, several expert workshops and talks with landfill operators have been performed followed by a division of the whole assessment method into preliminary and main assessment. Preliminary assessment is carried out with a questionnaire to rate juridical feasibility, the risk and the expenditure of a landfill mining project. The results of this questionnaire are compiled in a portfolio chart that is used to recommend, or not, further assessment. If a detailed main assessment is recommended, defined economic criteria are rated by net present value calculations, while ecological and socio-economic criteria are examined in a utility analysis and then transferred into a utility-net present value chart. If this chart does not support making a definite statement on the feasibility of the project, the results must be further examined in a cost-effectiveness analysis. Here, the benefit of the particular landfill mining project per capital unit (utility-net present value ratio) is determined to make a final distinct statement on the general benefit of a landfill mining project.

  8. Integrated modeling and up-scaling of landfill processes and heterogeneity using stochastic approach

    NARCIS (Netherlands)

    Bun, A.; Heimovaara, T.J.; Baviskar, S.M.; van Turnhout, A.G.; Konstantaki, L.A.

    2012-01-01

    Municipal solid waste landfills are a very complex and heterogeneous systems. The waste in a landfill body is a heterogeneous mixture of a wide range of materials containing high levels of organic matter, high amounts of salts and a wide range of different organic and inorganic substances, such as h

  9. Attenuation of Landfill Leachate In Unsaturated Sandstone

    Science.gov (United States)

    Butler, A. P.; Brook, C.; Godley, A.; Lewin, K.; Young, C. P.

    Landfill leachate emanating from old "dilute and disperse" sites represents a potential (and in many cases actual) threat to the integrity of groundwater. Indeed, this concern has been included in EU legislation (80/86/EEC), where key contaminants (e.g. ammonia, various toxic organic compounds and heavy metals) are explicitly highlighted in terms of their impact on groundwater. In the UK, whilst there are a substantial number of unlined landfills sited on major aquifers, many of these are in locations where there is a substantial unsaturated zone. Thus, there exists the opportunity for the modification and attenuation of contaminants prior to it encountering the water table. An understanding of likely changes in leachate content and concentrations at such sites will enable a more comprehensive assessment of the potential risks and liabilities posed by such sites to be evaluated. The Burntstump landfill, situated 8 km north of Nottingham (UK), is sited on an outcrop of Sherwood sandstone. The fine friable sand has been quarried since the 1960s and the excavated volume used to store municipal waste. Filling at the site commenced in the mid 1970s and originally was unlined. In 1978 the first of what was to become a series of boreholes was installed within an area of roughly 5 m radius over one of the original waste cells. Cores of the waste and underlying sandstone were extracted and analysed for a range of physical and chemical parameters. The most recent set of analyses were obtained in 2000. The series of investigations therefore provide an important record of leachate migration and modification through the unsaturated zone for over twenty years. The progression of the leachate front is clearly delineated by the chloride concentration profile with an average velocity of around 1.6 m.yr-1. Combining this value with an average (and reasonably uniform) measured moisture content of about 7% gives a mean inter-granular specific discharge of 110 mm.yr-1. An interesting

  10. Treatment of landfill leachates by waste iron-scraps coupling with aged-refuse-based reactor%废铁屑耦合矿化垃圾反应床处理填埋场渗滤液研究

    Institute of Scientific and Technical Information of China (English)

    安晓英; 何岩; 陶锐锋; 李真; 郭翠香; 王力刚

    2011-01-01

    为了构建合理的废铁屑耦合矿化垃圾反应床工艺,分别进行了停留时间对铁屑处理填埋场渗滤液和矿化垃圾反应床出水的影响对比分析.并据此研究了前置铁屑固定床耦合矿化垃圾反应床处理填埋场渗滤液的效能.结果表明,在不进行pH调节的条件下,前置铁屑固定床和间歇曝气沉淀具有明显强化反应床体系去除COD和氨氮的能力,出水COD和氨氮分别小于150 mg/L和5 mg/L.随着铁屑内电解反应器的不断完善,前置铁屑固定床和间歇曝气沉淀可作为强化矿化垃圾反应床处理填埋场渗滤液的有效途径,为经济有效地处理填埋场渗滤液提供了一条新思路.%In order to build the optimal process of waste iron scraps coupling with aged-refuse-based reactor, the influences of retention time on the iron-scraps-based treatment of landfill leachate and the effluent from the aged-refuse-based reactor have been contrasted and analyzed, respectively. Subsequently, the treatment effect of the preceding waste-iron-scraps coupling with the aged-refuse-based reactor on the landfill leachate is investigated. The results show that without pH adjustment,the preceding iron-scraps-fixed reactor and the intermittent aeration-sedimentation have apparent capacity for strengthening the removal performance of the aged-refuse-based reactor in terms of COD and ammonium-nitrogen. The COD and ammonium-nitrogen concentrations in the effluent are less than 150 mg/L and 5 mg/L. With the continuous improvement in the iron-scrap-fixed reactor,the preceding iron-scraps-fixed reactor and the intermittent aeration-sedimentation could be considered as a promising way in strengthening the removal performance of the aged-refuse-based reactor,which is of great significance for the economic and effective treatment of landfill leachates.

  11. Combinatorial bio/chemical analysis of dioxin and dioxin-like compounds in waste recycling, feed/food, humans/wildlife and the environment.

    Science.gov (United States)

    Behnisch, P A; Hosoe, K; Sakai, S

    2001-12-01

    The present review describes international activities using bioassays/biomarkers in combination with chemical analysis to measure the effects of dioxin and dioxin-like compounds (DLCs) in the environment. The above authors reviewed already the state-of-art bioanalytical detection methods (BDMs) for dioxins and DLCs [Environ Int (2001)]. The aim of this study will be to review applications of these bioassays/biomarkers to evaluate potential dioxins and DLCs. The present literature study lists relative potencies (REPs) of polyhalogenated dibenzo-p-dioxins and -furans (PXDD/Fs; X = Cl, Br, F), their thio analogues polychlorinated dibenzothiophenes (PCDTs) and thianthrens (PCTAs), polyhalogenated biphenyls (PXBs), polychlorinated naphthalenes (PCNs) and other Ah receptor agonists measured by several biodetectors (Tier 3 screening). The authors will discuss some examples of the applications of some of these biodetectors in biomonitoring programmes and recently occurred dioxin crisis in feed/food. The diagnosis of the biopotency of these pollutants in technical processes like thermally treated waste, waste water treatment, landfill leachate treatment, commercial PCB-mixtures, the release into the environment (soil, air and water) and the final intake into wildlife and humans will be reviewed.

  12. Idaho Chemical Processing Plant low-level waste grout stabilization development program FY-96 status report

    Energy Technology Data Exchange (ETDEWEB)

    Herbst, A.K.

    1996-09-01

    The general purpose of the Grout Stabilization Development Program is to solidify and stabilize the liquid low-level wastes (LLW) generated at the Idaho Chemical Processing Plant (ICPP). It is anticipated that LLW will be produced from the following: (1) chemical separation of the tank farm high-activity sodium-bearing waste; (2) retrieval, dissolution, and chemical separation of the aluminum, zirconium, and sodium calcines; (3) facility decontamination processes; and (4) process equipment waste. The main tasks completed this fiscal year as part of the program were chromium stabilization study for sodium-bearing waste and stabilization and solidification of LLW from aluminum and zirconium calcines. The projected LLW will be highly acidic and contain high amounts of nitrates. Both of these are detrimental to Portland cement chemistry; thus, methods to precondition the LLW and to cure the grout were explored. A thermal calcination process, called denitration, was developed to solidify the waste and destroy the nitrates. A three-way blend of Portland cement, blast furnace slag, and fly ash was successfully tested. Grout cubes were prepared at various waste loadings to maximize loading while meeting compressive strength and leach resistance requirements. For the sodium LLW, a 25% waste loading achieves a volume reduction of 3.5 and a compressive strength of 2,500 pounds per square inch while meeting leach, mix, and flow requirements. It was found that the sulfur in the slag reduces the chromium leach rate below regulatory limits. For the aluminum LLW, a 15% waste loading achieves a volume reduction of 8.5 and a compressive strength of 4,350 pounds per square inch while meeting leach requirements. Likewise for zirconium LLW, a 30% waste loading achieves a volume reduction of 8.3 and a compressive strength of 3,570 pounds per square inch.

  13. Detection and quantification of methane leakage from landfills

    Energy Technology Data Exchange (ETDEWEB)

    Ljungberg, Sven-Aake; Maartensson, Stig-Goeran (Univ. of Gaevle, Gaevle (Sweden)); Meijer, Jan-Erik; Rosqvist, Haakan (NSR AB, Helsingborg (Sweden))

    2009-03-15

    The purpose of this project was to detect gas leakage and to measure and quantify methane emission from landfills using modern remote sensing techniques. In this project, a handheld laser instrument and an IR camera were used. The overall objective was to develop cost-effective methods for detecting and quantifying methane emissions from landfills. There are many methods available for measuring the methane concentration in air, both from close-up and from long distances. Combined with the use of a tracer gas, the methane emission from entire landfills can be measured relatively accurately. A number of methods are used to detect leakage from parts of landfill surfaces, but there are few methods for quantifying leakage from sub-zones. Field measurements with the laser instrument and the IR camera were carried out at seven Swedish landfills and two landfills in France. The investigated surfaces at the Swedish landfills were divided into different zones, such as top surface, slope, crest and toe of slope. The field measurements in France were taken over entire landfills. The methane emission varied between the different landfills in the project, and also between the different landfill zones. The results from repeated field measurements indicated that a landfill with a final cap and a successful gas recovery system produces barely measurable emissions. The weak points at a landfill are generally slopes, including crests and toes of slopes. Where the covering of the waste is inadequate, leakage often occurs at lift joints and in areas where waste protrudes through the cover. Other weak points are deficiencies in the gas recovery system. Leachate systems can lead landfill gas and thereby cause methane leakage. Along with wind velocity and variations in atmospheric pressure, moisture content in the ground is an important factor that affects methane emissions from landfill surfaces. Results from field measurements of the same feature/surface at different points in time and

  14. Analyses of Environmental Impacts of Non Hazardous Regional Landfills in Macedonia

    Directory of Open Access Journals (Sweden)

    Katerina Donevska

    2013-12-01

    Full Text Available This paper presents an assessment of potential environmental impacts for eight planned non-hazardous regional landfills in Macedonia. Waste quantities for each waste management region and landfill capacities are estimated. Expected leachate quantities are calculated using Water Balance Method. Analyses and comparison of the likely landfill leachate per capita are presented, demonstrating that higher rates of leachate are generated per capita in waste management regions with higher annual sums of rainfall. An assessment of the potential landfill impacts on the water environment taking into consideration local geology and hydrogeology conditions is presented. Some general measures for leachate treatment that are in compliance with the modern EU standards are indicated. The goal of the study is to facilitate a better understanding about the sustainable waste management practices in cases of landfilling of municipal solid waste.

  15. Staff exchange with Chemical Waste Management. Final project report

    Energy Technology Data Exchange (ETDEWEB)

    Harrer, B.J.; Barak, D.W.

    1993-12-01

    Original objective was transfer of PNL technology and expertise in computational chemistry and waste flow/treatment modeling to CWM. Identification and characterization of a broader portfolio of PNL`s environmental remediation technologies with high potential for rapid application became the focus of the exchange, which included E-mail exchanges. Of the 14 technologies discussed, the following were identified as being of high interest to CWM: six phase soil heating (in-situ heating), high energy electrical corona, RAAS/ReOpt{trademark} (remedial, expert system), TEES{trademark} (catalytic production of methane from biological wastes), PST (process for treating petroleum sludge). CWM`s reorganization and downsizing reduced the potential benefits to industry, but a proposal for transfer and application of PST to Wheelabrator was made.

  16. Methods for chemical analysis of water and wastes

    Energy