WorldWideScience

Sample records for chemical recovery deteccao

  1. Fault detection-case: modelling of temperature control of smelt in a chemical recovery; Deteccao de defeitos via redes neurais: aplicacao no sistema de resfriamento das bicas de fundidos de uma caldeira de recuperacao

    Energy Technology Data Exchange (ETDEWEB)

    Martinelli, Sergio H.S. [Universidade Estadual de Maringa, PR (Brazil); Klabin Papeis Monte Alegre, Telemaco Borba, PR (Brazil); Neitzel, Ivo [Faculdade de Telemaco Borba, PR (Brazil); Universidade Estadual de Maringa, PR (Brazil); Vieira, Osvaldo [Universidade Estadual de Maringa, PR (Brazil); Klabin Papeis Monte Alegre, Telemaco Borba, PR (Brazil)

    2008-07-01

    This paper proposes a method for the detection of defects in the control systems components which was applied in the smelt spouts cooling system of a chemical recovery boiler. The almost static behavior of the system was modeled with neural networks. The comparison between the inferred variable by the model and the measurement in the process generated a residual vector. A second neural network, the classification type, was built to analyze the residue. The training process of this neural network was carried out with two types of data base, one of them where there was no defect (classified as non faulty data) and the other where there were defects in one of the process control system sensors. The generation of faulty data was carried out through defects simulation by neural model. Both neural networks were programmed on Excel software to make the continuous monitoring of the productive process possible. The process data feeding in the system was done though the Plant Information (PI) software. The rate of false alarm of process monitoring for two and half months was of 3%. Errors ranging from 2 to 15% were simulated at the manipulated variable of the control system to test the performance of the method. Within the range of 10% simulated errors the detection of defects rate was of 97% for the set of non trained standards. (author)

  2. Chemically enhanced in situ recovery

    Energy Technology Data Exchange (ETDEWEB)

    Sale, T. [CH2M Hill, Denver, CO (United States); Pitts, M.; Wyatt, K. [Surtek, Inc., Golden, CO (United States)] [and others

    1996-08-01

    Chemically enhanced recovery is a promising alternative to current technologies for management of subsurface releases of organic liquids. Through the inclusion of surfactants, solvents, polymers, and/or alkaline agents to a waterflood, the transport of targeted organic compounds can be increased and rates of recovery enhanced. By far, the vast majority of work done in the field of chemically enhanced recovery has been at a laboratory scale. The following text focuses on chemically enhanced recovery from a field application perspective with emphasis given to chlorinated solvents in a low permeability setting. While chlorinated solvents are emphasized, issues discussed are also relevant to organic liquids less dense than water such as petroleum products. Topics reviewed include: (1) Description of technology; (2) General technology considerations; (3) Low permeability media considerations; (4) Cost and reliability considerations; (5) Commercial availability; and (6) Case histories. Through this paper an appreciation is developed of both the potential and limitations of chemically enhanced recovery. Excluded from the scope of this paper is the in situ destruction of organic compounds through processes such as chemical or biological oxidation, chemically enhanced recovery of inorganic compounds, and ex situ soil treatment processes. 11 refs., 2 figs., 1 tab.

  3. Chemical agent recoveries

    Data.gov (United States)

    U.S. Environmental Protection Agency — Dataset shows the calculation of reported decontamination efficacies from the raw data (i.e., measured amount of chemical recovered from test coupons and positive...

  4. Recovery from chemical, biological, and radiological incidents :

    Energy Technology Data Exchange (ETDEWEB)

    Franco, David Oliver; Yang, Lynn I.; Hammer, Ann E.

    2012-06-01

    To restore regional lifeline services and economic activity as quickly as possible after a chemical, biological or radiological incident, emergency planners and managers will need to prioritize critical infrastructure across many sectors for restoration. In parallel, state and local governments will need to identify and implement measures to promote reoccupation and economy recovery in the region. This document provides guidance on predisaster planning for two of the National Disaster Recovery Framework Recovery Support Functions: Infrastructure Systems and Economic Recovery. It identifies key considerations for infrastructure restoration, outlines a process for prioritizing critical infrastructure for restoration, and identifies critical considerations for promoting regional economic recovery following a widearea disaster. Its goal is to equip members of the emergency preparedness community to systematically prioritize critical infrastructure for restoration, and to develop effective economic recovery plans in preparation for a widearea CBR disaster.

  5. Chemical enhanced recovery of heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Soveran, D.W.; Scoular, R.J.; Kurucz, L.; Renouf, G.; Verkoczy, B. [Saskatchewan Research Council, Regina, SK (Canada)

    2003-09-01

    A unique chemical/emulsion enhanced oil recovery (EOR) process was laboratory tested to determine its suitability for field demonstration purposes in 3 heavy oil reservoirs in the Lloydminster area of Saskatchewan. The promising chemical agents for the process were identified and optimized. The 3 reservoirs selected represented a cross-section of crude oil qualities typical for the region. The ultimate objective was to develop a process to replace waterflooding as the standard for post-primary production. Several modified core screening tests were conducted to formulate a chemical mixture for the lowest viscosity crude oil. This proved to be the best candidate among the 3 reservoirs. The mixture resulted in additional oil recovery of 26 per cent original oil in place, which is better than a typical waterflood. Two conventional core displacement tests confirmed the success of the modified core flood method. A new polymer was then used in combination with the new coreflood method to produce an additional oil recovery of 30 per cent. Laboratory studies indicate that the lowest viscosity crude oil field is a good candidate for the chemical EOR field study. Results show that the method can recover even the most highly viscous crude oil at a cost below C$10 per barrel. The field shows good potential for chemical EOR even though produced water from the reservoir formed heavy precipitate. 3 tabs., 6 figs.

  6. Cell Recovery after Combined Action of Ionizing Radiation and Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Kyu; Roh, Chang Hyun; Ryu, Tae Ho [Korea Atomic Energy Research Institute, Jeongeup (Korea, Republic of); Komarova, Ludmila N.; Petin, Vladislav G. [Medical Radiological Research Center, Obninsk (Russian Federation)

    2012-05-15

    Damage repair in malignant cells would be problematic in sterilization of microorganisms and treatment of cancer, as well. The inhibition of cell recovery and DNA single and double strand breaks repair by chemicals is expressed both as a deceleration of recovery rate and a lesser extent of recovery. Three possibilities are involved in the inhibition of cell recovery: (1) impairment of the recovery process itself, (2) increased irreversible damage, and (3) simultaneous exert of the two. There have been fee publications regarding these problems. The aim of this study was to determine which of these points are involved in the inhibition of cell recovery. In this study, a quantitative approach describing cell recovery from potentially lethal damage as a decrease in the effective dose was used

  7. Factors influencing recovery and restoration following a chemical incident.

    Science.gov (United States)

    Peña-Fernández, A; Wyke, S; Brooke, N; Duarte-Davidson, R

    2014-11-01

    Chemicals are an important part of our society. A wide range of chemicals are discharged into the environment every day from residential, commercial and industrial sources. Many of these discharges do not pose a threat to public health or the environment. However, global events have shown that chemical incidents or accidents can have severe consequences on human health, the environment and society. It is important that appropriate tools and technical guidance are available to ensure that a robust and efficient approach to developing a remediation strategy is adopted. The purpose of remediation is to protect human health from future exposure and to return the affected area back to normal as soon as possible. There are a range of recovery options (techniques or methods for remediation) that are applicable to a broad range of chemicals and incidents. Recovery options should be evaluated according to their appropriateness and efficacy for removing contaminants from the environment; however economic drivers and social and political considerations often influence decision makers on which remedial actions are implemented during the recovery phase of a chemical incident. To date, there is limited information in the literature on remediation strategies and recovery options that have been implemented following a chemical incident, or how successful they have been. Additional factors that can affect the approach taken for recovery are not well assessed or understood by decision makers involved in the remediation and restoration of the environment following a chemical incident. The identification of this gap has led to the development of the UK Recovery Handbook for Chemical Incidents to provide a framework for choosing an effective recovery strategy. A compendium of practical evidence-based recovery options (techniques or methods for remediation) for inhabited areas, food production systems and water environments has also been developed and is included in the chemical

  8. Olefin Recovery from Chemical Industry Waste Streams

    Energy Technology Data Exchange (ETDEWEB)

    A.R. Da Costa; R. Daniels; A. Jariwala; Z. He; A. Morisato; I. Pinnau; J.G. Wijmans

    2003-11-21

    The objective of this project was to develop a membrane process to separate olefins from paraffins in waste gas streams as an alternative to flaring or distillation. Flaring these streams wastes their chemical feedstock value; distillation is energy and capital cost intensive, particularly for small waste streams.

  9. Biological Kraft Chemical Recycle for Augmentation of Recovery Furnace Capacity

    Energy Technology Data Exchange (ETDEWEB)

    Stuart E. Strand

    2001-12-06

    The chemicals used in pulping of wood by the kraft process are recycled in the mill in the recovery furnace, which oxidizes organics while simultaneously reducing sulfate to sulfide. The recovery furnace is central to the economical operation of kraft pulp mills, but it also causes problems. The total pulp production of many mills is limited by the recovery furnace capacity, which cannot easily be increased. The furnace is one of the largest sources of air pollution (as reduced sulfur compounds) in the kraft pulp mill.

  10. Enhanced oil recovery chemicals from renewable wood resources

    Energy Technology Data Exchange (ETDEWEB)

    Grune, W.N.; Compere, A.L.; Griffith, W.L.; Crenshaw, J.M.

    1979-04-01

    Most of the wood pulp in the U.S. is produced by cooking, or digesting, wood chips in a chemical solution. These pulping processes have effluent streams which contain dissolved lignins, lignin breakdown products, and carbohydrates. There is a substantial economic incentive to use these materials as feedstocks for the production of high-valued micellar flood chemicals. The pulp and paper industries have practiced chemical recovery for almost a century. The largest chemical recycle processes are the internal recycle of inorganic salts for reuse in pulping. This is coupled with the use of waste organic compounds in the liquor as a fuel for directly-fired evaporation processes. Diversion of effluent and low valued streams for chemical recovery using fermentation, purification, or synthesis methods appears technically feasible in several cases. The use of new recovery processes could yield a variety of different wood-effluent based products. Some of the sugar acids in pulping liquors might be used as sequestering agents in reservoirs where there are large amounts of multivalent cations in flood brines. Fermentation production of high viscosity polymers, sequestering agents, and coagent alcohols appears worth further investigation. Tall oil acids and their derivatives can be used as surfactants in some reservoirs. Some waste constituents may adsorb preferentially on formations and thereby reduce loss of surfactants and other higher-valued chemicals.

  11. Recovery of palladium using chemically modified cedar wood powder.

    Science.gov (United States)

    Parajuli, Durga; Hirota, Koichi

    2009-10-15

    Japanese cedar wood powder (CWP) was chemically modified to a tertiary-amine-type adsorbent and studied for the selective recovery of Pd(II) from various industrial waters. Batch adsorption tests performed from 0.1 M to 5 M HCl and HNO3 systems reveal stable performance with better results in HNO3 medium. The maximum loading capacity for Pd(II) was studied in HCl as well as in HNO3. A continuous-flow experiment taking a real industrial solution revealed the feasibility of using modified CWP for the selective uptake and preconcentration of traces of palladium contained in acidic effluents. In addition, stable adsorption performance even on long exposure to gamma-irradiation and selective recovery of palladium from simulated high-level liquid waste (HLW) are important outcomes of the study.

  12. Chemical control in steam systems by using a stabilized inorganic product with gain of energy and speed in detecting contaminations; Controle quimico em geradores de vapor, pelo uso de agente inorganico estabilizado, com ganhos de energia e celeridade na deteccao de contaminacoes

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Barny de; Pereira, Renato Andre Nunes [Kurita do Brasil, Rio de Janeiro, RJ (Brazil)

    2010-07-01

    This paper shows the basic conditions to control the relation between phosphate and sodium in high pressure boilers by applying a stabilized chemical product ensuring operation with low variability and energy gain by the eliminating of corrective blowdown. It presents the routine and the relevant benefits provided by a strong monitoring program of phosphate application in high pressure boilers as an important tool do detect deviations and to get better control of silica solubilization in this pressure level. (author)

  13. Electrodialytic recovery of phosphorus from chemically precipitated sewage sludge ashes

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.;

    Phosphorus scarcity requires improved recover and reuse of urban sources; the recycling of this nutrient from sewage sludge has become increasingly important in the last years. Using an innovative electrodialytic process, the present study shows the potential for P separation from Fe and Al preci...... precipitated sewage sludge ash using this technique, with a recovery rate of around 70%. Furthermore, heavy metals were removed from the phosphorous fraction, producing a pure and safe phosphorus source in the end....

  14. Electrodialytic recovery of phosphorus from chemically precipitated sewage sludge ashes

    DEFF Research Database (Denmark)

    Viader, Raimon Parés; Erland Jensen, Pernille; Ottosen, Lisbeth M.

    Phosphorus scarcity requires improved recover and reuse of urban sources; the recycling of this nutrient from sewage sludge has become increasingly important in the last years. Using an innovative electrodialytic process, the present study shows the potential for P separation from Fe and Al preci...... precipitated sewage sludge ash using this technique, with a recovery rate of around 70%. Furthermore, heavy metals were removed from the phosphorous fraction, producing a pure and safe phosphorus source in the end...

  15. Electrodialytic recovery of phosphorus from chemically precipitated sewage sludge ashes

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    Phosphorus scarcity requires improved recover and reuse of urban sources; the recycling of this nutrient from sewage sludge has become increasingly important in the last years. Using an innovative electrodialytic process, the present study shows the potential for P separation from Fe and Al preci...... precipitated sewage sludge ash using this technique, with a recovery rate of around 70%. Furthermore, heavy metals were removed from the phosphorous fraction, producing a pure and safe phosphorus source in the end....

  16. Key Planning Factors for Recovery from a Chemical Warfare Agent Incident

    Science.gov (United States)

    2012-07-01

    chemical scenario involving the release of a blister agent (mustard lewisite) would result in a waste that the State of Colorado would regulate as... Waste Management ................................................................. 24 4.3 Key Planning Factors: Recovery Planning...Planning Factors, this document presents a chemical warfare agent scenario featuring Agent Yellow, a blister agent. Agent Yellow is a mixture of

  17. Recovery from chemical, biological, and radiological incidents. Critical infrastructure and economic impact considerations

    Energy Technology Data Exchange (ETDEWEB)

    Franco, David Oliver [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Yang, Lynn I. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Hammer, Ann E. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2012-06-01

    To restore regional lifeline services and economic activity as quickly as possible after a chemical, biological or radiological incident, emergency planners and managers will need to prioritize critical infrastructure across many sectors for restoration. In parallel, state and local governments will need to identify and implement measures to promote reoccupation and economy recovery in the region. This document provides guidance on predisaster planning for two of the National Disaster Recovery Framework Recovery Support Functions: Infrastructure Systems and Economic Recovery. It identifies key considerations for infrastructure restoration, outlines a process for prioritizing critical infrastructure for restoration, and identifies critical considerations for promoting regional economic recovery following a widearea disaster. Its goal is to equip members of the emergency preparedness community to systematically prioritize critical infrastructure for restoration, and to develop effective economic recovery plans in preparation for a widearea CBR disaster.

  18. Recovery and chemical purification of actinides at JRC, Karlsruhe

    Science.gov (United States)

    Bokelund, H.; Apostolidis, C.; Glatz, J.-P.

    1989-07-01

    The application of actinide elements in research and in technology is many times subject to rather stringent purity requirements; often a nuclear grade quality is specified. The additional possible demand for a high isotopic purity is a special feature in the handling of these elements. The amount of actinide elements contained in or adhering to materials declared as waste should be low for safety reasons and out of economic considerations. The release of transuranium elements to the environment must be kept negligible. For these and for other reasons a keen interest in the separation of actinides from various materials exists, either for a re-use through recycling, or for their safe confinement in waste packages. This paper gives a short review of the separation methods used for recovery and purification of actinide elements over the past years in the European Institute for Transuranium Elements. The methods described here involve procedures based on precipitation, ion exchange or solvent extraction; often used in a combination. The extraction methods were preferably applied in a Chromatographie column mode. The actinide elements purified and/or separated from each other by the above methods include uranium, neptunium, plutonium, americium, curium, and californium. For the various elements the work was undertaken with different aims, ranging from reprocessing and fabrication of nuclear fuels on a kilogramme scale, over the procurement of alpha-free waste, to the preparation of neutron sources of milligramme size.

  19. Increase of heavy oil reservoir recovery using chemical injection

    Directory of Open Access Journals (Sweden)

    Mohammad Amin Alishvandi

    2016-12-01

    Full Text Available Due to thermal properties, Nano fluids may be new generation of thermal transfer fluids that would be used invarious industries. Energy carrier Nano fluids as waters, lubricants and ethylene glycol include of particles with dimensions of 100 nm as metal, metal oxid or carbon Nano tubes. Based on evaluation, with increase of viscosity of Nano fluid surfactant, absorbed dispersion materials would be increased and Nano particles dispersion and stability and thermal transfer would be developed. Using chemical injection to reservoirs, surfactant is cause of oil entrapment based on decrease of surface tension force, self generate- emulation and change of wetting. According to reservoir temperature,by Nano fluid and surfactant, thermal properties would be achieved to heat oil and decrease viscosity without any change of reservoir stone wetting.

  20. Chemical Compounds Recovery in Carboxymethyl Cellulose Wastewater Treatment

    Directory of Open Access Journals (Sweden)

    P.-H. Rao

    2015-05-01

    Full Text Available Carboxymethyl cellulose (CMC is a kind of cellulose ether widely used in industrial production. CMC wastewater usually have high chemical oxygen demand (COD and salinity (>10 %, which result from organic and inorganic by-products during CMC production. It is significant that the wastewater is pretreated to decrease salinity and recover valuable organics before biochemical methods are employed. In this paper, distillation-extraction method was used to pretreat CMC wastewater and recover valuable chemical compounds from wastewater (Fig. 1. Initial pH of CMC wastewater was adjusted to different values (6.5, 8.5, 9.5, 10.5, 12.0 before distillation to study the effect of pH on by-products in wastewater. By-products obtained from CMC wastewater were extracted and characterized by NMR, XRD and TGA. Distillate obtained from distillation of wastewater was treated using biological method, i.e., upflow anaerobic sludge blanket (UASB-contact oxidation process. Domestic sewage and flushing water from manufacturing shop was added into distillate to decrease initial COD and increase nutrients such as N, P, K. Experimental results showed that by-products extracted from CMC wastewater mainly include ethoxyacetic acid and NaCl, which were confirmed by NMR and XRD (Fig. 2. TGA results of by-products indicated that the content of NaCl in inorganic by-products reached 96 %. Increasing initial pH value of CMC wastewater might significantly raise the purity of ethoxyacetic acid in organic by-products. UASB-contact oxidation process showed a good resistance to shock loading. Results of 45-day continuous operation revealed that CODCr of final effluent might be controlled below 500 mg l−1 and meet Shanghai Industrial Wastewater Discharge Standard (CODCr −1, which indicated that the treatment process in this study was appropriate to treat distillate of wastewater from CMC production industry.

  1. Bio-/Photo-Chemical Separation and Recovery of Uranium

    Energy Technology Data Exchange (ETDEWEB)

    Francis,A.J.; Dodge, C.J.

    2008-03-12

    Citric acid forms bidentate, tridentate, binuclear or polynuclear species with transition metals and actinides. Biodegradation of metal citrate complexes is influenced by the type of complex formed with metal ions. While bidentate complexes are readily biodegraded, tridentate, binuclear and polynuclear species are recalcitrant. Likewise certain transition metals and actinides are photochemically active in the presence of organic acids. Although the uranyl citrate complex is not biodegraded, in the presence of visible light it undergoes photochemical oxidation/reduction reactions which result in the precipitation of uranium as UO{sub 3} {center_dot} H{sub 2}O. Consequently, we developed a process where uranium is extracted from contaminated soils and wastes by citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, whereas uranyl citrate which is recalcitrant remains in solution. Photochemical degradation of the uranium citrate complex resulted in the precipitation of uranium. Thus the toxic metals and uranium in mixed waste are recovered in separate fractions for recycling or for disposal. The use of naturally-occurring compounds and the combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in cost.

  2. Modification of reservoir chemical and physical factors in steamfloods to increase heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1996-12-31

    Thermal methods, and particularly steam injection, are currently recognized as the most promising for the efficient recovery of heavy oil. Despite significant progress, however, important technical issues remain open. Specifically, still inadequate is our knowledge of the complex interaction between porous media and the various fluids of thermal recovery (steam, water, heavy oil, gases, and chemicals). While, the interplay of heat transfer and fluid flow with pore- and macro-scale heterogeneity is largely unexplored. The objectives of this contract are to continue previous work and to carry out new fundamental studies in the following areas of interest to thermal recovery: displacement and flow properties of fluids involving phase change (condensation-evaporation) in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on thermal recovery. The specific projects are motivated by and address the need to improve heavy oil recovery from typical reservoirs as well as less conventional fractured reservoirs producing from vertical or horizontal wells. During this past quarter, work continued on: the development of relative permeabilities during steam displacement; the optimization of recovery processes in heterogeneous reservoirs by using optical control methods; and in the area of chemical additives, work continued on the behavior of non-Newtonian fluid flow and on foam displacements in porous media.

  3. Ecological Recovery Potential of Freshwater Organisms: Consequences for Environmental Risk Assessment of Chemicals.

    Science.gov (United States)

    Gergs, Andre; Classen, Silke; Strauss, Tido; Ottermanns, Richard; Brock, Theo C M; Ratte, Hans Toni; Hommen, Udo; Preuss, Thomas G

    2016-01-01

    Chemical contaminants released into the in the environment may have adverse effects on (non-target) species, populations and communities. The return of a stressed system to its pre-disturbance or other reference state, i.e. the ecological recovery, may depend on various factors related to the affected taxon, the ecosystem of concern and the type of stressor with consequences for the assessment and management of risks associated with chemical contaminants. Whereas the effects caused by short-term exposure might be acceptable to some extent, the conditions under which ecological recovery can serve as a decision criterion in the environmental risk assessment of chemical stressors remains to be evaluated. For a generic consideration of recovery in the risk assessment of chemicals, we reviewed case studies of natural and artificial aquatic systems and evaluate five aspects that might cause variability in population recovery time: (1) taxonomic differences and life-history variability, (2) factors related to ecosystem type and community processes, (3) type of disturbance, (4) comparison of field and semi-field studies, and (5) effect magnitude, i.e., the decline in population size following disturbance. We discuss our findings with regard to both retrospective assessments and prospective risk assessment.

  4. Synthesis and analysis of separation networks for the recovery of intracellular chemicals generated from microbial-based conversions

    National Research Council Canada - National Science Library

    Kirti M Yenkie; Wenzhao Wu; Christos T Maravelias

    2017-01-01

    Background Bioseparations can contribute to more than 70% in the total production cost of a bio-based chemical, and if the desired chemical is localized intracellularly, there can be additional challenges associated with its recovery...

  5. Sulfomethylated lignosulfonates as additives in oil recovery processes involving chemical recovery agents

    Energy Technology Data Exchange (ETDEWEB)

    Kalfoglou, G.

    1979-10-30

    A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of sulfomethylated lignosulfonate salt as a sacrificial agent to inhibit the deposition of surfactant and/or polymer on the reservoir matrix. The process may best be carried out by injecting the sulfomethylated lignosulfonates into the formation through the injection well mixed with either a polymer, a surfactant solution and/or a micellar dispersion. This mixture would then be followed by a drive fluid such as water to push the chemicals to the production well.

  6. Sulfomethylated lignosulfonates as additives in oil recovery processes involving chemical recovery agents

    Energy Technology Data Exchange (ETDEWEB)

    Kalfoglou, G.

    1981-05-26

    A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of sulfomethylated lignosulfonate salt as a sacrificial agent to inhibit the deposition of surfactant and/or polymer on the reservoir matrix. The process may best be carried out by injecting the sulfomethylated lignosulfonates into the formation through the injection well mixed with either a polymer, a surfactant solution and/or a micellar dispersion. This mixture would then be followed by a drive fluid such as water to push the chemicals to the production well.

  7. Recovery from a chemical weapons accident or incident: A concept paper on planning

    Energy Technology Data Exchange (ETDEWEB)

    Herzenberg, C.L.; Haffenden, R.; Lerner, K.; Meleski, S.A.; Tanzman, E.A. [Argonne National Lab., IL (United States); Lewis, L.M. [US Dept. of Agriculture (United States); Hemphill, R.C. [Niagara Mohawk Power Corporation (United States); Adams, J.D. [US Environmental Protection Agency (United States)

    1994-04-01

    Emergency planning for an unintended release of chemical agent from the nation`s chemical weapons stockpile should include preparation for. the period following implementation of immediate emergency response. That period -- the recovery, reentry, and restoration stage -- is the subject of this report. The report provides an overview of the role of recovery, reentry, and restoration planning in the Chemical Stockpile Emergency Preparedness Program (CSEPP), describes the transition from immediate emergency response to restoration, and analyzes the legal framework that would govern restoration activities. Social, economic, and administrative issues, as well as technical ones, need to be considered in the planning effort. Because of possible jurisdictional conflicts, appropriate federal, state, and local agencies need to be included in a coordinated planning process. Advance consideration should be given to the pertinent federal and state statutes and regulations. On the federal level, the principal statutes and regulations to be considered are those associated with the Comprehensive Environmental Response, Compensation, and Liability Act; the Resource Conservation and Recovery Act; and the National Environmental Policy Act. This report recommends that extensive preaccident planning be undertaken for the recovery, reentry, and restoration stage and outlines several key issues that should be considered in that planning. The need for interagency cooperation and coordination at all levels of the planning process is emphasized.

  8. Modification of reservoir chemical and physical factors in steamfloods to increase heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    Thermal methods, and particularly steam injection, are currently recognized as the most promising for the efficient recovery of heavy oil. Despite significant progress, however, important technical issues remain open. Specifically, still inadequate is our knowledge of the complex interaction between porous media and the various fluids of thermal recovery (steam, water, heavy oil, gases, and chemicals). While, the interplay of heat transfer and fluid flow with pore- and macro-scale heterogeneity is largely unexplored. The objectives of this contract are to continue previous work and to carry out new fundamental studies in the following areas of interest to thermal recovery: displacement and flow properties of fluids involving phase change (condensation-evaporation) in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on thermal recovery. The specific projects are motivated by and address the need to improve heavy oil recovery from typical reservoirs as well as less conventional fractured reservoirs producing from vertical or horizontal wells. During this quarter work continued on: development of relative permeabilities during steam injection; optimization of recovery processes in heterogeneous reservoirs by using optimal control methods; and behavior of non-Newtonian fluid flow and on foam displacements in porous media.

  9. Heat Recovery from High Temperature Slags: A Review of Chemical Methods

    Directory of Open Access Journals (Sweden)

    Yongqi Sun

    2015-03-01

    Full Text Available Waste heat recovery from high temperature slags represents the latest potential way to remarkably reduce the energy consumption and CO2 emissions of the steel industry. The molten slags, in the temperature range of 1723–1923 K, carry large amounts of high quality energy. However, the heat recovery from slags faces several fundamental challenges, including their low thermal conductivity, inside crystallization, and discontinuous availability. During past decades, various chemical methods have been exploited and performed including methane reforming, coal and biomass gasification, and direct compositional modification and utilization of slags. These methods effectively meet the challenges mentioned before and help integrate the steel industry with other industrial sectors. During the heat recovery using chemical methods, slags can act as not only heat carriers but also as catalysts and reactants, which expands the field of utilization of slags. Fuel gas production using the waste heat accounts for the main R&D trend, through which the thermal heat in the slag could be transformed into high quality chemical energy in the fuel gas. Moreover, these chemical methods should be extended to an industrial scale to realize their commercial application, which is the only way by which the substantial energy in the slags could be extracted, i.e., amounting to 16 million tons of standard coal in China.

  10. Comparison of media for recovery of total coliform bacteria from chemically treated water.

    OpenAIRE

    Rice, E W; Fox, K R; Nash, H D; Read, E J; Smith, A P

    1987-01-01

    Five broth media and two solid media were compared for their ability to quantitatively recover total coliform bacteria from chemically treated water. M-Endo LES and mT7 media were used in the membrane filter technique. Lauryl tryptose broth, lactose broth, presence-absence broth, lactose broth with twice the amount of lactose, and lauryl tryptose broth with twice the amount of sodium lauryl sulfate were used in the fermentation tube procedure. The differences in recovery were not significant ...

  11. Recent advancement of hybrid materials used in chemical enhanced oil recovery (CEOR): A review

    Science.gov (United States)

    Hamza, M. F.; Sinnathambi, C. M.; Merican, Z. M. A.

    2017-06-01

    Depletion of natural oil reserves has forced oil industries to focus on tertiary recovery methods to extract residual oil after exhausting the primary and secondary methods. Among the Enhance Oil Recovery (EOR) technologies, Chemical EOR (CEOR) is gaining popularity. Despite research efforts to increase the recovery using CEOR, increasing complexity in extraction methods are encountered. With changes in reservoir conditions (high temperature, pressure and salinity) and crude oil properties, existing chemicals used in CEOR, such as alkali, polymers and surfactants do not function desirably. These conditions have detrimental effects on the performance of EOR chemicals, like precipitation, degradation, etc. Development and utilization of effective EOR hybrids such as surfactant-polymer, polymer-nanomaterial, surfactant-nanomaterial and polymer-surfactant-nanomaterial had prevailed the effects of harsh reservoir conditions, and their applications in oil fields in recent years have increased the success of EOR. The synergistic effects between the hybrid components play major roles in improving the properties that could withstand the effect of extreme reservoir conditions and changes in crude oil properties. Therefore, this paper is aimed at reviewing recent advances in CEOR hybrid technologies, and discusses the basic concept, applications, advancement and limitations of different hybrid materials used in CEOR processes.

  12. Nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization without chemical additions.

    Science.gov (United States)

    Song, Yong-Hui; Qiu, Guang-Lei; Yuan, Peng; Cui, Xiao-Yu; Peng, Jian-Feng; Zeng, Ping; Duan, Liang; Xiang, Lian-Cheng; Qian, Feng

    2011-06-15

    Anaerobically digested swine wastewater contains high concentrations of phosphorus (P) and nitrogen (N). A pilot-scale experiment was carried out for nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization. In the pilot plant, a sequencing batch reactor (SBR) and a continuous-flow reactor with struvite accumulation devices were designed and employed. The wastewater pH value was increased by CO(2) stripping, and the struvite crystallization process was performed without alkali and Mg(2+) additions. Results of the long-term operation of the system showed that, both reactors provided up to 85% P removal and recovery over wide ranges of aeration times (1.0-4.0 h), hydraulic retention times (HRT) (6.0-15.0 h) and temperatures (0-29.5°C) for an extended period of 247 d, in which approximate 30% of P was recovered by the struvite accumulation devices. However, 40-90% of NH(4)(+)-N removed was through air stripping instead of being immobilized in the recovered solids. The recovered products were detected and analyzed by scanning electron microscope (SEM), X-ray diffraction (XRD) and chemical methods, which were proved to be struvite with purity of more than 90%. This work demonstrated the feasibility and effects of nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization without chemical additions.

  13. Chemical enhanced oil recovery (EOR) activities in Indonesia: How it's future

    Science.gov (United States)

    Abdurrahman, Muslim

    2017-05-01

    Enhanced oil recovery (EOR) is a proven method for increasing oil production in many oil fields in the world. Huge oil remaining in the reservoir after primary and secondary recovery stage are the main reason for developing EOR methods. Approximately of 49.50 billion barrels oil as a candidate for EOR activities in Indonesia. This present study focuses on the chemical EOR activities involved surfactant and polymer. This research based on pertinent information from various resources such as journal papers, conference papers, and report from the government. Based on this information, this paper explain in detail the progress of each project and it shows the potential oil field employ chemical EOR in the near future. Generally, the EOR activities can be categorized into two phases such as preliminary study phase and field implementation phase. In the preliminary study, the activities simply involve experimental and/or simulation works. Following the preliminary is the field implementation phase which can be categorized into three phases such as field trial, pilot project, and full-scale. In fact, several activities have been conducted by Lemigas (government oil and gas research center), Institut Teknologi Bandung, Institut Pertanian Bogor. These activities focused on laboratory and simulation work. Those institutions have been developing the chemical formula collaborating with oil companies for applying the EOR method in their oil fields. Currently, status of chemical EOR activities include 5 oil fields under pilot project and 12 oil fields under field trial. There are 7 oil fields applying surfactant, 4 oil fields by alkaline-surfactant-polymer (ASP), 2 oil fields by polymer, 1 oil field by surfactant polymer (SP), and 1 oil field by caustic. According to this information, we will have insight knowledge about the EOR current activities, the main issues, future activities on chemical EOR in Indonesia. Moreover, this study can became the preliminary information for

  14. Improving oil recovery in the CO2 flooding process by utilizing nonpolar chemical modifiers☆

    Institute of Scientific and Technical Information of China (English)

    Yong Yang; Xiangliang Li; Ping Guo; Yayun Zhuo; Yong Sha

    2016-01-01

    By means of experiments of CO2 miscibility with crude oil, four nonpolar chemicals were evaluated in order to enhance the miscibility of CO2 with crude oil. Through pre-slug injection and joint injection of toluene in CO2, crude oil displacement experiments in the slim-tube were conducted to investigate effects of the toluene-enhanced CO2 flooding under simulated subterranean reservoir conditions. Experimental results showed that toluene can enhance extraction of oil into CO2 and dissolution of CO2 into oil with the increment of 251%and 64%respectively. Addition of toluene can obviously improve the oil recovery in either pre-slug injection or joint injection, and the crude oil recovery increased with the increase of the toluene concentration. The oil recov-ery can increase by 22.5%in pre-slug injection with the high toluene concentration. Pre-slug injection was recom-mended because it can consume less toluene than joint injection. This work could be useful to development and application of the CO2 flooding in the oil recovery as wel as CO2 emission reduction.

  15. Fluid Diversion and Sweep Improvement with Chemical Gels in Oil Recovery Processes

    Energy Technology Data Exchange (ETDEWEB)

    Seright, R.S.; Martin, F.D.

    1991-11-01

    This report describes progress made during the second year of the three-year project, Fluid diversion and Sweep Improvement with Chemical Gels in Oil Recovery Processes.'' The objectives of this project are to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants are being examined. This research is directed at gel applications in water injection wells, in production wells, and in high-pressure gasfloods. The work examines how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals include determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. 93 refs., 39 figs., 43 tabs.

  16. Use of amine oxide surfactants for chemical flooding EOR (enhanced oil recovery)

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, D.K.

    1989-11-01

    The use of amine oxides with and without alcohols as cosolvents, and in combination with other surfactants as mixed micellar formulations for enhanced oil recovery by surfactant flooding was investigated. Amine oxides are a salt-tolerant class of surfactants that produce low interfacial tension and can develop viscosity without the addition of polymers. These salt-tolerant formulations generate three-phase regions with hydrocarbons over a broad salinity range, develop moderate solubilization, and produce low interfacial tensions, however oil recovery from amine oxide-alcohol phase behavior optimized formulations was directly dependent upon the quantity of surfactant injected. The large pore volume and high concentration of surfactant required prohibits their economic use as the primary surfactant in chemical flooding EOR. Dimethylalkylamine oxides are useful as cosurfactants and viscosifiers in formulations with other surfactants for chemical flooding EOR but the use of ethoxylated and propoxylated amine oxides should be avoided due to the decomposition of these amine oxides under reservoir conditions. Phase behavior, phase inversion temperatures, and viscosity scans have been correlated with surfactant structures to provide a guide for amine oxide applications in chemical flooding. 36 refs., 5 figs., 6 tabs.

  17. Prevention of Preharvest Sprouting through Hormone Engineering and Germination Recovery by Chemical Biology.

    Science.gov (United States)

    Nonogaki, Mariko; Nonogaki, Hiroyuki

    2017-01-01

    Vivipary, germination of seeds on the maternal plant, is observed in nature and provides ecological advantages in certain wild species, such as mangroves. However, precocious seed germination in agricultural species, such as preharvest sprouting (PHS) in cereals, is a serious issue for food security. PHS reduces grain quality and causes economical losses to farmers. PHS can be prevented by translating the basic knowledge of hormone biology in seeds into technologies. Biosynthesis of abscisic acid (ABA), which is an essential hormone for seed dormancy, can be engineered to enhance dormancy and prevent PHS. Enhancing nine-cis-epoxycarotenoid dioxygenase (NCED), a rate-limiting enzyme of ABA biosynthesis, through a chemically induced gene expression system, has successfully been used to suppress germination of Arabidopsis seeds. The more advanced system NCED positive-feedback system, which amplifies ABA biosynthesis in a seed-specific manner without chemical induction, has also been developed. The proofs of concept established in the model species are now ready to be applied to crops. A potential problem is recovery of germination from hyperdormant crop grains. Hyperdormancy induced by the NCED systems can be reversed by inducing counteracting genes, such as NCED RNA interference or gibberellin (GA) biosynthesis genes. Alternatively, seed sensitivity to ABA can be modified to rescue germination using the knowledge of chemical biology. ABA antagonists, which were developed recently, have great potential to recover germination from the hyperdormant seeds. Combination of the dormancy-imposing and -releasing approaches will establish a comprehensive technology for PHS prevention and germination recovery.

  18. Prevention of Preharvest Sprouting through Hormone Engineering and Germination Recovery by Chemical Biology

    Science.gov (United States)

    Nonogaki, Mariko; Nonogaki, Hiroyuki

    2017-01-01

    Vivipary, germination of seeds on the maternal plant, is observed in nature and provides ecological advantages in certain wild species, such as mangroves. However, precocious seed germination in agricultural species, such as preharvest sprouting (PHS) in cereals, is a serious issue for food security. PHS reduces grain quality and causes economical losses to farmers. PHS can be prevented by translating the basic knowledge of hormone biology in seeds into technologies. Biosynthesis of abscisic acid (ABA), which is an essential hormone for seed dormancy, can be engineered to enhance dormancy and prevent PHS. Enhancing nine-cis-epoxycarotenoid dioxygenase (NCED), a rate-limiting enzyme of ABA biosynthesis, through a chemically induced gene expression system, has successfully been used to suppress germination of Arabidopsis seeds. The more advanced system NCED positive-feedback system, which amplifies ABA biosynthesis in a seed-specific manner without chemical induction, has also been developed. The proofs of concept established in the model species are now ready to be applied to crops. A potential problem is recovery of germination from hyperdormant crop grains. Hyperdormancy induced by the NCED systems can be reversed by inducing counteracting genes, such as NCED RNA interference or gibberellin (GA) biosynthesis genes. Alternatively, seed sensitivity to ABA can be modified to rescue germination using the knowledge of chemical biology. ABA antagonists, which were developed recently, have great potential to recover germination from the hyperdormant seeds. Combination of the dormancy-imposing and -releasing approaches will establish a comprehensive technology for PHS prevention and germination recovery.

  19. Possibilities for recovery and prospects of the Serbian chemical industry in the light of sustainable development

    Directory of Open Access Journals (Sweden)

    Đukić Petar M.

    2014-01-01

    Full Text Available There are numerous dilemmas related to the meaning of common terms associated with modern economic sectors, and especially the ones concerning industry. Chemical industry is a typical example of a term which changes rapidly and qualitatively, exactly with the pace of changing of the very technology based on knowledge, procedure, processes, raw materials, energy, as well as on the products themselves and on the way of their use. Numerous difficulties caused by huge changes in global market, by transition of command economies towards market system, as well as by the latest global economic-financial crisis, have brought the chemical industry in modern Serbia to an unenviable position. We cannot generally claim that chemical industry is collapsing, but the recovery of the whole chemical industry, as well as of the industry in general, necessitates many favourable presumptions from the environment, as well as strategic, systemic and operative measures, of the state within the so-called industry policy, as well as of the very companies which deal with chemical industry. The re-industrialization strategy, adopted officially during the first crisis blow, but to the full extent only during the prolonged crisis period in Serbia (2009-2013 should not be based on direct state incentives, but above all on the institutional infrastructure and business environment improvement which will lead to the investments in technological reconstruction and re-organization of the entire sector. However, chemical industry cannot be observed as a chance for economic growth per se, nor it can lead to higher employment rate in such a short period of time, but above all to productive use of profession, or of growth potential based on knowledge factor. This is why a proper evolution and prosperity of the Serbian chemical industry can be comprehended, not only through contribution of one separate sector, but as complementary and useful technologies within many other industries

  20. Physical, morphological and chemical characteristics, oil recovery and fatty acid composition of Balanites aegyptiaca Del. kernels.

    Science.gov (United States)

    Mohamed, A M; Wolf, W; Spiess, W E L

    2002-01-01

    Balanites aegyptiaca Del. kernels were chemically, physically and morphologically characterized. Crude oil (49.0%) and crude protein (32.4%) were the two major constituents of the kernels. Phytic acid content was relatively high compared to other legumes. In contrast, antitryptic activities of the kernel flours were very low. Sapogenin contents of the full fat, defatted and testa flours were 1.5, 2.7 and 3.0%, respectively. The hardness of the kernel was found to be about 10.4 x 10(5) N/m2, which was somewhat high. The morphological structure of the kernel using a scanning electron microscope revealed that the protein matrix was embedded in a lake of oil droplets. Oil recovery, as a function of pressing time, pressure, temperature and particle size was investigated. With increasing temperature up to 70 degrees C at 400 bar, for 120 min, an oil recovery of 79.4% was obtained. Using an expeller at 115 degrees C, about 85% of the kernel oil was recovered. The reduction of particle size had a negative effect on oil recovery under the same conditions. The fatty acid composition was not affected by the pressing temperature up to 115 degrees C. The total amount of the unsaturated fatty acids was found to be up to 74.8% (50 degrees C) and 75.1% (115 degrees C) of the total fatty acids content.

  1. Expedited, chemically enhanced sperm cell recovery from cotton swabs for rape kit analysis.

    Science.gov (United States)

    Norris, Jessica V; Manning, Kate; Linke, Sarah J; Ferrance, Jerome P; Landers, James P

    2007-07-01

    This report focuses on the development of a method for chemically induced enhancement of cell elution and recovery from cotton swabs. The method exploits the exclusive use of detergents for intact cell removal, and can be utilized in conjunction with, or to circumvent, conventional differential extraction (DE). Samples treated with Sarkosyl (54.4 +/- 1.8%) and sodium dodecyl sulfate (SDS) (78.5 +/- 0.7%) yielded higher sperm cell recoveries than a conventional DE buffer (39.4 +/- 2.1%). The results indicated that the choice of detergent affected sperm cell yield, with anionic detergents having the greatest effect. Storage time of samples affected the concentration of detergent required for optimal sperm cell recovery, longer times requiring increased detergent concentrations. In addition, the extent of sperm cell lysis by proteinase K digestion was evaluated. The results indicate that the exclusive use of SDS enhances the release of sperm and epithelial cells from a cotton swab as compared with DE buffer, providing for a more effective DNA analysis.

  2. Draft Guidance: Response, Remediation, and Recovery Checklist for Chemically Contaminated Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Raber, E; Mancieri, S; Carlsen, T; Fish, C; Hirabayashi-Dethier, J; Intrepido, A; MacQueen, D; Michalik, R; Richards, J

    2007-09-04

    A key part of preparedness in the event of a chemical warfare agent (CWA) or toxic industrial chemical (TIC) release at a large facility, such as an airport or subway, is to develop a concept of operations that allows for an effective incident response and recovery. This document is intended as a component of the concept of operations and will be used in the Emergency Operations Center (EOC) as a decision tool for the Unified Command (UC). The Checklist for Facility Response, Remediation, and Recovery presented in this document is principally focused on the Consequence Management Phase (see Figure 1; LLNL 2007a and 2007b) of a chemical release. Information in this document conforms to the National Response Plan (NRP) (DHS 2004) and the National Incident Management System (NIMS 2004). Under these two guidance documents, personnel responsible for managing chemical response and recovery efforts--that is, the decision-makers--are members of an Incident Command (IC), which is likely to transition to a UC in the event of a CWA or TIC attack. A UC is created when more than one agency has incident jurisdiction or when incidents cross political jurisdictions. The location for primary, tactical-level command and management is referred to as the Incident Command Post (ICP), as described in the NRP. Thus, regardless of whether an IC or a UC is used, the responsible entities are located at an ICP. Agencies work together through designated members of the UC to establish their designated Incident Commanders at a single ICP and to establish a common set of objectives and strategies and a single Incident Action Plan. Initially during the Crisis Management Phase (see Figure 1), the Incident Commander is likely to be the Chief of the fire department that serves the affected facility. As life-safety issues are resolved and the Crisis Management Phase shifts to the Consequence Management Phase, the work of characterization, decontamination, and facility clearance begins. There will

  3. Procedure of Destructive Chemical Recovery of Precious Metals in Nitric Acid Production

    Directory of Open Access Journals (Sweden)

    Ljubičić, M.

    2012-07-01

    Full Text Available The heart of the nitric acid production process is the chemical reactor containing a platinum-based catalyst pack and an associated catchment system, which allows the ammonia oxidation reaction to take place efficiently. Under the severe operating conditions imposed by the high-pressure ammonia oxidation process, the catalyst gauzes experience progressive deterioration, as shown by the restricted surface of the catalyst wires, the loss of catalytic activity and the loss of catalytic materials. The higher the pressure of gaseous ammonia oxidation, the greater the loss of platinum group metals from the surface of the applied selective heterogeneous catalysts. Total losses for one batch over the whole period of using selective heterogeneous catalysts may account in the range from 20 to 40 % of the total installed quantity of precious metals. An important part of the platinum removed from the platinum-rhodium alloy wires can be recovered at the outlet of the reactor by means of palladium catchment gauzes. However, this catchment process, which is based on the great ability of palladium to alloy with platinum, is not 100 % effective and a fraction of the platinum and practically all of the rhodium lost by the catalyst wires, evades the catchment package and is then deposited in other parts of the plant, especially heat exchangers. From the above mentioned operating equipment, the retained mass of precious metals can be recovered by the technical procedure of non-destructive and destructive chemical solid-liquid extraction.Shown is the technical procedure of destructive chemical recovery of preheater and boiler for preheating and production of steam by applying sulfuric acid (w = 20 % and subsequent procedure of raffination of derived sludge, to the final recovery of precious metals. The technical procedure of destructive chemical recovery of precious metals from preheater and boiler for preheating and production of steam in nitric acid production is

  4. Chemical and Microbial Characterization of North Slope Viscous Oils to Assess Viscosity Reduction and Enhanced Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Shirish Patil; Abhijit Dandekar; Mary Beth Leigh

    2008-12-31

    A large proportion of Alaska North Slope (ANS) oil exists in the form of viscous deposits, which cannot be produced entirely using conventional methods. Microbially enhanced oil recovery (MEOR) is a promising approach for improving oil recovery for viscous deposits. MEOR can be achieved using either ex situ approaches such as flooding with microbial biosurfactants or injection of exogenous surfactant-producing microbes into the reservoir, or by in situ approaches such as biostimulation of indigenous surfactant-producing microbes in the oil. Experimental work was performed to analyze the potential application of MEOR to the ANS oil fields through both ex situ and in situ approaches. A microbial formulation containing a known biosurfactant-producing strain of Bacillus licheniformis was developed in order to simulate MEOR. Coreflooding experiments were performed to simulate MEOR and quantify the incremental oil recovery. Properties like viscosity, density, and chemical composition of oil were monitored to propose a mechanism for oil recovery. The microbial formulation significantly increased incremental oil recovery, and molecular biological analyses indicated that the strain survived during the shut-in period. The indigenous microflora of ANS heavy oils was investigated to characterize the microbial communities and test for surfactant producers that are potentially useful for biostimulation. Bacteria that reduce the surface tension of aqueous media were isolated from one of the five ANS oils (Milne Point) and from rock oiled by the Exxon Valdez oil spill (EVOS), and may prove valuable for ex situ MEOR strategies. The total bacterial community composition of the six different oils was evaluated using molecular genetic tools, which revealed that each oil tested possessed a unique fingerprint indicating a diverse bacterial community and varied assemblages. Collectively we have demonstrated that there is potential for in situ and ex situ MEOR of ANS oils. Future work

  5. Combined heating and chemical treatment for oil recovery from aging crude oil.

    Science.gov (United States)

    Hou, Chunjuan; Jiang, Qingzhe; Song, Zhaozheng; Tan, Guorong; Shi, Zhan

    2016-07-01

    With increasing use of chemical oil displacement agents in tertiary recovery and the application of various demulsifiers for crude oil dehydration, a large amount of aging crude oil containing a high ratio of water is produced, and it is very difficult for processing and utilisation. In this article, we chose aging crude oil samples from a union station in an oilfield in China. Sample composition was analysed to demonstrate that the key of aging crude oil dehydration is the removal of solid impurities. Thus, an efficient method of combining heating and chemical treatments was developed to treat aging crude oil. It includes two steps: The first step is washing of aging crude oil with hot water with sodium dodecylbenzene sulfonate; the second step is chemical demulsification of the above mixture with hydrochloric acid and sodium chloride solution. The result showed that 2.9% of solid impurities and 29.2% of water were removed in the first step; 27.2% of oil, 24.3% of water, and 3.47% of solid impurities in the aging crude oil were recycled in the second step. A total 87.07% of aging crude oil could be solved with this method. The present two-step treatment method can ensure that the dehydration process runs normally and efficiently in the union station, making it a promising method in the recycling of aging crude oil. © The Author(s) 2016.

  6. A taxonomy of chemicals of emerging concern based on observed fate at water resource recovery facilities.

    Science.gov (United States)

    Jones, Steven M; Chowdhury, Zaid K; Watts, Michael J

    2017-03-01

    As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient, and the upcycling of chemicals of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place. A multiple month survey, of both primary and secondary effluents, from three (3) WRRFs, for 95 CECs was conducted in 2014 to classify CECs by their persistence through conventional water reclamation processes. By sampling the participating WRRF process trains at their peak performance (as determined by measured bulk organics and particulates removal), a short-list of recalcitrant CECs that warrant monitoring to assess treatment performance at advanced water reclamation and production facilities. The list of identified CECs for potable water reclamation (indirect or direct potable reuse) include a herbicide and its degradants, prescription pharmaceuticals and antibiotics, a female hormone, an artificial sweetener, and chlorinated flame retardants.

  7. A pressure recovery system for chemical oxygen-iodine laser based on an active diffuser

    Science.gov (United States)

    Malkov, V. M.; Kiselev, I. A.; Orlov, A. E.; Shatalov, I. V.

    2011-09-01

    An open-type pressure recovery system (PRS) for chemical oxygen-iodine laser was designed and fabricated. As a first stage, an active diffuser was used in which the ejecting gas supply was organized through nozzles disposed around the channel periphery. The second stage was a supersonic ejector. Numerical simulation data for the viscous turbulent flow with heat release through the diffuser gas-dynamic channel, and also data obtained by testing the active diffuser in operation on a model facility equipped with a vacuum chamber, are reported. The obtained data were used to develop a full-scale setup with exhaust of laser gas into the atmosphere; this has allowed us to optimize the performance characteristics of the setup and substantially improve its mass-dimensional characteristics. Special attention was paid to parameter matching and synchronization of laser start with the operation of PRS components.

  8. Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

    Institute of Scientific and Technical Information of China (English)

    Tao Zhang; Qiucheng Li; Lili Ding; Hongqiang Ren; Ke Xu; Yonggang Wu; Dong Sheng

    2011-01-01

    Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium nitrogen (NH4+-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4+-N recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4+-N recovery from coking wastewater was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative significance of reaction factors and the interactive effects of solution conditons. Thermodynamic modeling indicated that the saturation index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4+ molar ratio (Mg/N) and the initial NH4+-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4+ and CO32-/NH4+molar ratios (Ca/N and CO32-/N), respectively. The trends for NH4+-N removal at different pH and Mg/N levels were similar to the thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N)× (CO32-/N),(pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4+-Nrecovery.

  9. Impact of innovations on future energy supply - chemical enhanced oil recovery (CEOR).

    Science.gov (United States)

    Bittner, Christian

    2013-01-01

    The International Energy Agency (IEA) expects an increase of global energy demand by one-third during next 20 years together with a change in the global energy mix. A key-influencing factor is a strong expected increase in oil and gas production in the United States driven by 'new' technologies such as hydraulic fracturing. Chemical enhanced oil recovery (CEOR) is another strong growing technology with the potential of a step change innovation, which will help to secure future oil supply by turning resources into reserves. While conventional production methods give access to on average only one-third of original oil in place, the use of surfactants and polymers allows for recovery of up to another third of this oil. In the case of polymer flooding with poly acrylamide, the number of full field implementations has increased in recent years. In the meantime new polymers have been developed to cover previously unmet needs - such polymers can be applied in fields of high salinity and high temperature. Use of surfactants is in an earlier stage, but pilot tests show promising results.

  10. Chemical waste treatment and recovery laboratory: an alternative for industrial waste of southern Minas Gerais

    Directory of Open Access Journals (Sweden)

    Luciano Tavares da Costa

    2015-06-01

    Full Text Available This manuscript consisted to obtain data, such as costs, equipments and investments necessary for the implementation of a Waste Treatment and Recovery Laboratory at UNIFAL-MG, campus II in Alfenas. In order to give support for the implementation and operation of this laboratory, in a way to guarantee a sustainable investment from the economic point of view, the EVTE was applied. This work was performed following the steps: identification and quantification of the wastes, EVTE elaboration, draft of the physical laboratory architecture and the analysis of the potential financial resources. It was verified that the implementation and management of the Chemical Waste Treatment Laboratory get to support an initial waste volume of 372 L/month and 3.5 kg/month of inorganic salts, beyond other industrial wastes from the neighborhood region. The implementation and maintenance of this laboratory are economic viable depending on the treated, recovered and recycled waste volume as well as on the provided service for the industry client. It is necessary to highlight the environmental benefits, especially due to the chemical waste disposal reduction, the academic formation opportunity and the social awareness promoted by the action of the laboratory. It can be add on the principle related to the Sustainable Logistic Plan in the Federal Public Administration.JEL-Code | Q01; QR3; L65.

  11. Study of the reduction in detection limits of track detectors used for {sup 10}B(n,α){sup 7}Li reaction rate measure through annealing and chemical etching experiments; Estudo da reducao nos limites de deteccao de detectores de tracos utilizados na medida de taxa de reacao {sup 10}B(n, α){sup 7}Li atraves de experimentos de annealing e ataque quimico

    Energy Technology Data Exchange (ETDEWEB)

    Vasconcellos, Herminiane L.; Smilgys, Barbara; Guedes, Sandro, E-mail: hluizav@ifi.unicamp.br [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Instituto de Fisica Gleb Wataghin; Castro, Vinicius A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Engenharia Nuclear

    2013-08-15

    The Boron Neutron Capture Therapy (BNCT) is an experimental radiotherapy for cancer treatment. It is based on {sup 10}B(n, α){sup 7}Li reaction, which can be measured by track detectors capable of recording events that strike them. With this recording, it is possible to determine the number of alpha particles and recoiling Lithium-7 nucleus, reaction products, and from this information, which amount of radiation dose a patient is exposed to. In this work, PADC detectors were characterized, irradiated at the IEA-R1 IPEN/CNEN reactor to assess the contribution of the{sup 10}B(n, α){sup 7}Li reaction and protons from fast neutron scattering with the elements that compounds the tissue. With the aim of reducing the proton background, the detectors were subjected to heating experiments at 80°C for periods in the range 0-100 hours. This was done in order to restore partially modified structure of the detector, causing a reduction in the size and density of tracks. This effect is known as annealing. For the visualization of tracks at microscope, detectors were made three chemical attacks with sodium hydroxide (NaOH) for 30, 60 and 90 minutes at 70°C. It was observed a reduction in the track density achieving a plateau heating time of 50 hours. For detectors that have not undergone annealing and were etched with another etchant, PEW solution, a reduction of 87% in track density was obtained. (author)

  12. Reef ecology. Chemically mediated behavior of recruiting corals and fishes: a tipping point that may limit reef recovery.

    Science.gov (United States)

    Dixson, Danielle L; Abrego, David; Hay, Mark E

    2014-08-22

    Coral reefs are in global decline, converting from dominance by coral to dominance by seaweed. Once seaweeds become abundant, coral recovery is suppressed unless herbivores return to remove seaweeds, and corals then recruit. Variance in the recovery of fishes and corals is not well understood. We show that juveniles of both corals and fishes are repelled by chemical cues from fished, seaweed-dominated reefs but attracted to cues from coral-dominated areas where fishing is prohibited. Chemical cues of specific seaweeds from degraded reefs repulsed recruits, and cues from specific corals that are typical of healthy reefs attracted recruits. Juveniles were present at but behaviorally avoided recruiting to degraded reefs dominated by seaweeds. For recovery, degraded reefs may need to be managed to produce cues that attract, rather than repel, recruiting corals and fishes.

  13. Nanoscale Hydrophobic Recovery: A Chemical Force Microscopy Study of UV/Ozone-Treated Cross-Linked Poly(dimethylsiloxane)

    NARCIS (Netherlands)

    Hillborg, Henrik; Tomczak, Nikodem; Oláh, Attila; Schönherr, Holger; Vancso, G. Julius

    2004-01-01

    Chemical force microscopy (CFM) in water was used to map the surface hydrophobicity of UV/ozone-treated poly(dimethylsiloxane) (PDMS; Sylgard 184) as a function of the storage/recovery time. In addition to CFM pull-off force mapping, we applied indentation mapping to probe the changes in the normali

  14. 40 CFR 60.2558 - What if a chemical recovery unit is not listed in § 60.2555(n)?

    Science.gov (United States)

    2010-07-01

    ... process flow diagram) of the process in which the materials are burned, highlighting the type, design, and operation of the equipment used in this process. (4) A description (including a process flow diagram) of the chemical constituent recovery process, highlighting the type, design, and operation of the equipment used...

  15. 40 CFR 60.2025 - What if my chemical recovery unit is not listed in § 60.2020(n)?

    Science.gov (United States)

    2010-07-01

    ... materials that are recovered. (3) A description (including a process flow diagram) of the process in which... process. (4) A description (including a process flow diagram) of the chemical constituent recovery process, highlighting the type, design, and operation of the equipment used in this process. (5) A description of the...

  16. Techno-economic evaluation of membrane filtration for the recovery and re-use of tanning chemicals.

    Science.gov (United States)

    Scholz, W; Lucas, M

    2003-04-01

    The majority of pollution generated from leather manufacturing can be contributed to the inefficiency of chemical use in leather processing and to organic substances derived from the hides during processing. In particular, the overall tanning processes performed in drums can be characterized by a high consumption of water and chemicals, most of which are found in the final wastewater. To ensure full penetration and reaction of chemicals with collagen, chemicals are added in excess and are only partly up-taken by the leather. Significant savings of chemicals can be achieved by recovery and recycling of chemicals and water from part streams, thus reducing environmental impacts. This research formed an integrated approach to investigate and exploit the potential of a closed loop operation for various part streams of tanneries. Each of the process streams was separately collected, treated and purified by membrane technologies to obtain a recyclable liquor which can be re-used operationally. In this way a complete recovery of process liquors can be achieved for immediate operational re-use. Membrane technology has been applied to recover chemicals from un-hairing, vegetable tanning, chrome liquors and to polish saline part streams for re-use. By applying membrane filtration up to 90% of the treated liquors can be recovered giving a remaining concentrate volume of only 10%. The permeate obtained from several process areas contained to a high extent chemicals, which were re-used for leather processing.

  17. Chemicals for enhanced oil recovery. Biennial report, April 1978-March 1980

    Energy Technology Data Exchange (ETDEWEB)

    Compere, A.L.; Crenshaw, J.M.; Greene, S.V.; Griffith, W.L.; Hall, J.E. Jr.; Johnson, J.S. Jr.; Jones, R.M.; Magid, L.J.; Triolo, R.; Westmoreland, C.G.

    1981-03-01

    The objective of Chemicals for Enhanced Oil Recovery is to lower barriers to implementation of the micellar flood approach by decreasing cost and increasing availability of chemicals used in the process. This is done by finding alternative feedstocks in wastes or low valued organic byproducts and by development of lower cost production procedures. For biopolymers in particular, emphasis has been on developments important for field production, to obviate the expense necessary for preparation of a dry product, feasible for shipping, and of redispersion for injection into formations. Because of the large quantities of waste and low valued byproducts generated by the paper industry, wood pulping streams have received particular attention. The interests have been not only in surfactants and mobility control polymers, but also in cosurfactants, sequestering agents for control of hardness, and competitive adsorbates. Some of the highlights of this period are: microscreens compared favorably in installed cost and operating energy to diatomaceous earth filtration and centrifugation for gross biomass removal; four fungi from genera other than Sclerotium, Helotium, or Stromatinia were tested and found to be potential biopolymer producers; methods of hydrolyzing polymers sequentially from the ends were investigated, and pH and temperature optima for these were obtained; coagent alcohols and alcohol-ketone mixture were readily produced from weak acid sulfite liquor, condenser effluent, and thermomechanical effluent streams; preparations of pure sodium oleate and a number of derivatives with substituents on the carbon next to the carboxylate were carried out and their phase behavior in systems containing a fixed cosurfactant were compared as a function of alkane molecular weight and of NaCl concentration; commercial ethoxylated fatty acids of different hydrophilic/hydrophobic ratios were evaluated, both alone and in conjunction with a petroleum sulfonate surfactant.

  18. Recovery of phosphorus and aluminium from sewage sludge ash by a new wet chemical elution process (SESAL-Phos-recovery process).

    Science.gov (United States)

    Petzet, S; Peplinski, B; Bodkhe, S Y; Cornel, P

    2011-01-01

    The potential of a new wet chemical process for phosphorus and aluminium recovery from sewage sludge ash by sequential elution with acidic and alkaline solutions has been investigated: SESAL-Phos (sequential elution of sewage sludge ash for aluminium and phosphorus recovery). Its most innovative aspect is an acidic pre-treatment step in which calcium is leached from the sewage sludge ash. Thus the percentage of alkaline soluble aluminium phosphates is increased from 20 to 67%. This aluminium phosphate is then dissolved in alkali. Subsequently, the dissolved phosphorus is precipitated as calcium phosphate with low heavy metal content and recovered from the alkaline solution. Dissolved aluminium is recovered and may be reused as a precipitant in wastewater treatment plants.

  19. Mathematical modelling of flux recovery during chemical cleaning of tubular membrane fouled with whey proteins

    Directory of Open Access Journals (Sweden)

    Marković Jelena Đ.

    2009-01-01

    Full Text Available Membrane process efficiency in the dairy industry is impaired by the formation of deposits during filtration processes. This work describes cleaning procedures for ceramic tubular membrane (50 nm fouled with whey proteins. Also, mathematical modelling was performed to obtain models which allow deeper insight into the mechanisms involved during cleaning procedures. The caustic solutions (0.2%w/w, 0.4%w/w and 1.0%w/w NaOH and the mixture of two commercial detergents (0.8%w/w P3-ultrasil 69+0.5% w/w P3-ultrasil 67 and 1.2% P3-ultrasil 69+0.75 P3-ultrasil 67 were used as chemical cleaning agents. The results showed that the best flux recovery was achieved with 0.4%w/w NaOH solution. After analyzing the experimental data, five parameter and six parameter kinetic models were suggested for alkali and detergent cleaning, respectively. The changes of total and specific resistances, as well as the change of the effective pore diameter and deposit thickness during cleaning are estimated by applying these models.

  20. Thin-layer detection using reflection seismic; Deteccao de camadas delgadas usando sismica de reflexao

    Energy Technology Data Exchange (ETDEWEB)

    Farias, Armando Lopes [PETROBRAS, Rio de Janeiro, RJ (Brazil). Exploracao e Producao; Freitas, Lucas Batista; Tygel, Martin [Universidade Estadual de Campinas (LGC/UNICAMP), SP (Brazil). Lab. Geofisica Computacional

    2008-03-15

    Improvement of vertical resolution in seismic data is one of the major challenges for the seismic reflection method. The main problem is related to the larger loss of high frequencies relative to the lower ones during seismic wave propagation. As a consequence, the contribution of lower frequencies in the final section is significantly greater than the corresponding one due to higher frequencies. In principle, this situation should not constitute an obstacle to the full recovery of the spectrum, because of the powerful tools available in seismic processing, designed to equalize all frequencies that are present in the data volume. The main reason why these tools in general do not succeed is the presence of noise, for example random noise. Such situation gives rise to a critical frequency, such that all frequencies above it are impossible to recover and, as a consequence, the seismic pulse cannot be made short enough to allow for optimal resolution. Methods to solve the problem by means of random noise attenuation have been extensively investigated and tested without relevant results. The alternative to such techniques is the enhancement of the multiplicity that can be used for stacking. Since the amplitude decays exponentially with frequency, a large multiplicity is necessary in order to attain a significant effective frequency gain. The capability to attain extremely large multiplicity is exactly the main virtue of the Common Reflection Surface (CRS) method. In this paper, we propose the strategy of combining the CRS method with the spectral whitening, a known frequency recovery technique, so as to optimize vertical resolution in seismic data and, as a consequence, improve the discrimination of thin reservoirs. First tests on synthetic and real data shown in this work are very encouraging and permit to conclude that the proposed approach has a good potential for practical application. (author)

  1. Concurrent reduction and distillation: an improved technique for the recovery and chemical refinement of the isotopes of cadmium and zinc

    Energy Technology Data Exchange (ETDEWEB)

    Caudill, H.H.; McBride, L.E.; McDaniel, E.W.

    1982-01-01

    The Electromagnetic Isotope Separations Program of the Oak Ridge National Laboratory has been involved in the separation, chemical recovery, and refinement of the stable isotopes of cadmium and zinc since 1946. Traditionally, the chemical refinement procedures for these elements consisted of ion exchange separations using anion exchange resins followed by pH-controlled hydrogen sulfide precipitations. The procedures were quite time-consuming and made it difficult to remove trace quantities of sulfur which interferes in subsequent attempts to prepare rolled metal foils. As demands for /sup 113/Cd and /sup 68/Zn (a precursor for the production of the radiopharmaceutical /sup 67/Ga) increased, it became evident that a quicker, more efficient refinement procedure was needed. Details of an improved method, which employs concurrent hydrogen reduction and distillation in the recovery and refinement of isotopically enriched zinc, are described. Modifications of the procedure suitable for the refinement of cadmium isotopes are also described. 3 figures, 1 table.

  2. Urban Area Recovery Planning with Chemical, Biological, and Radiological Hazards: Lessons Learned from Seattle and Denver

    Science.gov (United States)

    2012-11-01

    themes ). Another option is that the region selects those RSFs that are most applicable for that region which maybe a...Historic and Cultural Preservation Cultural and historical importance and value National Park Service or Bureau of Land Management Use of...Community Development Department Economic Recovery Tourism / Visitor and Convention Bureau Economic Recovery Local downtown/urban development councils

  3. Sequential electrodialytic recovery of phosphorus from low-temperature gasification ashes of chemically precipitated sewage sludge

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

    2017-01-01

    availability and the presence of heavy metals. Previously, more than 80% of P was recovered from incineration sewage sludge ashes using a two-compartment electrodialytic cell. In contrast, the recovery was below 30% for ashes from low-temperature gasification using the same setup. The low recovery was due...

  4. Quantifying impacts of coupled chemical and physical heterogeneity on water quality evolution during Aquifer Storage and Recovery

    Science.gov (United States)

    Deng, H.; Descourvieres, C.; Seibert, S.; Harris, B.; Atteia, O.; Siade, A. J.; Prommer, H.

    2014-12-01

    Aquifer storage and recovery (ASR) is an important water management option in water-scarce regions. During wet periods surplus water is injected into suitable aquifers for storage and later recovery. ASR sites are, however, also ideal natural laboratories that provide opportunities for studying coupled physical and geochemical processes and water quality evolution at field-scale under well-controlled hydrological conditions. In this study, we use reactive transport modelling to assess the impacts of physical and chemical heterogeneities on the water quality evolution during the injection of oxic surface water into the anoxic, pyrite-bearing Leederville aquifer in Perth, Western Australia. Physical heterogeneity was identified from geophysical well logs and time lapse temperature logs. Those data were used to define the spatial, depth-varying alternation of three lithofacies (sandstone, siltstone and clay). Chemical heterogeneity was incorporated through distinct chemical zones, based on data derived from a comprehensive pre-trial geochemical characterization and from dedicated laboratory respirometer experiments. Calibration of flow and conservative transport parameters was constrained by the spatially varying measured chloride breakthrough behavior. Subsequent reactive transport modeling discerned the key geochemical processes that affected the water quality evolution during ASR. Clearly identified processes included oxidation of pyrite, mineralization of sedimentary organic carbon, ion exchange, dissolution of calcite and precipitation of ferrihydrite and siderite. We use the calibrated model to analyze the individual and the combined effects of the physical and chemical heterogeneities on the chemical composition of the recovered water during ASR.

  5. Modification of chemical and physical factors in steamflood to increase heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Yanis C.

    2000-01-19

    This report covers the work performed in the various physicochemical factors for the improvement of oil recovery efficiency. In this context the following general areas were studied: (1) The understanding of vapor-liquid flows in porous media, including processes in steam injection; (2) The effect of reservoir heterogeneity in a variety of foams, from pore scale to macroscopic scale; (3) The flow properties of additives for improvement of recovery efficiency, particularly foams and other non-Newtonian fluids; and (4) The development of optimization methods to maximize various measures of oil recovery.

  6. Chemical inhibition of cell recovery after irradiation with sparsely and densely ionizing radiation

    Energy Technology Data Exchange (ETDEWEB)

    Evastratova, Ekaterina S.; Petin, Vladislav [A. Tsyb Medical Radiological Research Centre-branch of the National Medical Research Radiological Centre of the Ministry of Health of the Russian Federation, Obninsk (Russian Federation); Kim, Jin Hong; Kim, Jin Kyu [Korea Atomic Energy Research Institute, Advanced Radiation Technology Institute (ARTI), Jeongeup (Korea, Republic of); Lim, Youg Khi [Dept. of Radiological Science, Gachon University, Incheon (Korea, Republic of)

    2017-02-15

    The dependence of cell survival on exposure dose and the duration of the liquid holding recovery (LHR) was obtained for diploid yeast cells irradiated with ionizing radiation of different linear energy transfer (LET) and recovering from radiation damage without and with various concentrations of cisplatin - the most widely used anticancer drug. The ability of yeast cells to recover from radiation damage was less effective after cell exposure to high-LET radiation, when cells were irradiated without drug. The increase in cisplatin concentration resulted in the disappearance of this difference whereas the fraction of irreversible damage was permanently enlarged independently of radiation quality. The probability of cell recovery was shown to be constant for various conditions of irradiation and recovery. A new mechanism of cisplatin action was suggested according with which the inhibition of cell recovery after exposure to ionizing radiations was completely explained by the production of irreversible damage.

  7. Assessment of Risk Due to Chemicals Transferred in a Watershed: A Case of an Aquifer Storage Transfer and Recovery Site

    Directory of Open Access Journals (Sweden)

    Hyon Wook Ji

    2016-06-01

    Full Text Available This paper presents an analysis of the potential risks of chemicals that can affect an aquifer storage transfer and recovery (ASTR site. ASTR is a water supply system that injects surface water into an aquifer and then extracts naturally filtered groundwater. The pilot site of the ASTR supplying drinking water is located downstream of the Nakdong River in South Korea. Hazard analysis and critical control points (HACCP was adopted to ensure suitable water quality in response to the deteriorated water quality of the Nakdong River. HACCP is a proactive management system for ensuring consistent confidence in food (or water. Hazard analysis, the first of the seven principles of HACCP, assesses physical, microbial, chemical, and radioactive hazards. This study focuses on the chemicals that are most likely to be involved in major hazardous events. Pollutant release and transfer register (PRTR data were used to analyze potential risks of chemicals. A PRTR is a national environmental database of potentially hazardous chemicals. Potential risk analysis considers the total amount of chemicals transferred off-site for treatment or disposal. Fifty-five cities and the top 10 chemicals released in the Nakdong River basin were investigated. Potential risk was defined as a function of total transfers, the relative distance, and toxicity. The top 10 cities with high potential risks were identified, and the city with the highest potential risk turned out to be Ulju.

  8. A Novel Ion Exchange System to Purify Mixed ISS Waste Water Brines for Chemical Production and Enhanced Water Recovery

    Science.gov (United States)

    Lunn, Griffin; Spencer, LaShelle; Ruby, Anna-Maria; McCaskill, Andrew

    2014-01-01

    Current International Space Station water recovery regimes produce a sizable portion of waste water brine. This brine is highly toxic and water recovery is poor: a highly wasteful proposition. With new biological techniques that do not require waste water chemical pretreatment, the resulting brine would be chromium-free and nitrate rich which can allow possible fertilizer recovery for future plant systems. Using a system of ion exchange resins we can remove hardness, sulfate, phosphate and nitrate from these brines to leave only sodium and potassium chloride. At this point modern chlor-alkali cells can be utilized to produce a low salt stream as well as an acid and base stream. The first stream can be used to gain higher water recovery through recycle to the water separation stage while the last two streams can be used to regenerate the ion exchange beds used here, as well as other ion exchange beds in the ISS. Conveniently these waste products from ion exchange regeneration would be suitable as plant fertilizer. In this report we go over the performance of state of the art resins designed for high selectivity of target ions under brine conditions. Using ersatz ISS waste water we can evaluate the performance of specific resins and calculate mass balances to determine resin effectiveness and process viability. If this system is feasible then we will be one step closer to closed loop environmental control and life support systems (ECLSS) for current or future applications.

  9. Modification of chemical and physical factors in steamflood to increase heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1992-04-01

    This report covers work performed in the area related to the physicochemical factors for the improvement of the oil recovery efficiency in steamfloods. In this context, three general areas are studied: (1) The understanding of vapor-liquid flow in porous media, whether the flow is internal (boiling), external (steam injection) or countercurrent (as in vertical heat pipes). (2) The effect of reservoir heterogeneity, particularly as it regards fractured systems and long and narrow reservoirs (which are typical of oil reservoirs). (3) The flow properties of additives for the improvement of recovery efficiency, in particular the properties of foams.

  10. Recovery of microbial diversity and activity during bioremediation following chemical oxidation of diesel contaminated soils

    NARCIS (Netherlands)

    Sutton, N.B.; Langenhoff, A.A.M.; Hidalgo Lasso, D.; Zaan, van der B.M.; Gaans, van P.; Maphosa, F.; Smidt, H.; Grotenhuis, J.T.C.; Rijnaarts, H.H.M.

    2014-01-01

    To improve the coupling of in situ chemical oxidation and in situ bioremediation, a systematic analysis was performed of the effect of chemical oxidation with Fenton's reagent, modified Fenton's reagent, permanganate, or persulfate, on microbial diversity and activity during 8 weeks of incubation in

  11. Recovery of microbial diversity and activity during bioremediation following chemical oxidation of diesel contaminated soils

    NARCIS (Netherlands)

    Sutton, N.B.; Langenhoff, A.A.M.; Hidalgo Lasso, D.; Zaan, van der B.M.; Gaans, van P.; Maphosa, F.; Smidt, H.; Grotenhuis, J.T.C.; Rijnaarts, H.H.M.

    2014-01-01

    To improve the coupling of in situ chemical oxidation and in situ bioremediation, a systematic analysis was performed of the effect of chemical oxidation with Fenton's reagent, modified Fenton's reagent, permanganate, or persulfate, on microbial diversity and activity during 8 weeks of incubation in

  12. Investigation of Chemical Reactivity, Mass Recovery and Biological Activity During Thermal Treatment of DNAPL Source Zones

    Science.gov (United States)

    2009-10-01

    electronic circuitry. In Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries IV, J.C. Marra and G.T. Chandler (Eds...COCl2 phosgene COH3COO- glycolate COOHCOO- oxalate CROW Contained Recovery of Oily Wastes ™ CT carbon tetrachloride Cu copper cis-DCE cis...in parallel, with compatible treatment technologies including bioremediation and oxidation- reduction processes. E.2.1. Rates of Abiotic TCE

  13. Nanoscale hydrophobic recovery: A chemical force microscopy study of UV/ozone-treated cross-linked poly(dimethylsiloxane).

    Science.gov (United States)

    Hillborg, Henrik; Tomczak, Nikodem; Olàh, Attila; Schönherr, Holger; Vancso, G Julius

    2004-02-01

    Chemical force microscopy (CFM) in water was used to map the surface hydrophobicity of UV/ozone-treated poly(dimethylsiloxane) (PDMS; Sylgard 184) as a function of the storage/recovery time. In addition to CFM pull-off force mapping, we applied indentation mapping to probe the changes in the normalized modulus. These experiments were complemented by results on surface properties assessed on the micrometer scale by X-ray photoelectron spectroscopy and water contact-angle measurements. Exposure times of < or = 30 min resulted in laterally homogeneously oxidized surfaces, which are characterized by an increased modulus and a high segmental mobility of PDMS. As detected on a sub-50-nm level, the subsequent "hydrophobic recovery" was characterized by a gradual increase in the pull-off forces and a decrease in the normalized modulus, approaching the values of unexposed PDMS after 8-50 days. Lateral imaging on briefly exposed PDMS showed the appearance of liquid PDMS in the form of droplets with an increasing recovery time. Longer exposure times (60 min) led to the formation of a hydrophilic silica-like surface layer. Under these conditions, a gradual surface reconstruction within the silica-like layer occurred with time after exposure, where a hydrophilic SiOx-enriched phase formed < 100-nm-sized domains, surrounded by a more hydrophobic matrix with lower normalized modulus. These results provide new insights into the lateral homogeneity of oxidized PDMS with a resolution in the sub-50-nm range.

  14. Simplified recovery process of Ralstonia solanacearum-synthesized polyhydroxyalkanoates via chemical extraction complemented by liquid-liquid phase separation

    Directory of Open Access Journals (Sweden)

    Karine L. Macagnan

    Full Text Available Poly (3-hydroxybutyrate (P(3HB is the most studied thermoplastic biopolymer belonging to the polyhydroxyalkanoate (PHA family, the main features of which include rapid biodegradability and biocompatibility. The bioplastic recovery process is an important step during production and can directly influence the characteristics of PHAs. However, more efficient methods for the production of P(3HB are necessary to make it economically viable. The aim of the present study was to improve the standard, chloroform-based, extraction step for the recovery of P(3HB. The polymer was produced using a Ralstonia solanacearum strain. The following parameters were improved in the recovery process: heating time, separation method (filtration or liquid-liquid phase separation, biomass state (fresh or dry cell concentrate and the solvent:biomass ratio. By improving the chemical extraction of P(3HB we recovered 98% of the cumulative polymer and reduced the heating time by 75%. Furthermore, we improved the separation process and developed an extraction solution that was faster and more economical.

  15. SYNTHESIS AND CHARACTERIZATION O F SODIUM METHYL ESTER SULFONATE FOR CHEMICALLY-ENHANCED OIL RECOVERY

    Directory of Open Access Journals (Sweden)

    K. Babu

    2015-09-01

    Full Text Available AbstractAttention has been given to reduce the cost of surfactant by using castor oil as an alternative natural source of feedstock. A new surfactant, sodium methyl ester sulfonate (SMES was synthesised using ricinoleic acid methyl ester, which is obtained from castor oil, for enhanced oil recovery in petroleum industries. The performance of SMES was studied by measuring the surface tension with and without sodium chloride and its thermal stability at reservoir temperature. SMES exhibited good surface activity, reducing the surface tension of surfactant solution up to 38.4 mN/m and 27.6 mN/m without and with NaCl, respectively. During the thermal analysis of SMES, a 31.2% mass loss was observed from 70 ˚C to 500 ˚C. The phase behavior of the cosurfactant/SMES-oil-water system plays a key role in interpreting the performance of enhanced oil recovery by microemulsion techniques. Flooding experiments were performed using a 0.5 pore volume of synthesized SMES solutions at three different concentrations. In each case chase water was used to maintain the pressure gradient. The additional recoveries in surfactant flooding were found to be 24.53%, 26.04% and 27.31% for 0.5, 0.6 and 0.7 mass% of surfactant solutions, respectively.

  16. Developing a Robust Surrogate Model of Chemical Flooding Based on the Artificial Neural Network for Enhanced Oil Recovery Implications

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Ahmadi

    2015-01-01

    Full Text Available Application of chemical flooding in petroleum reservoirs turns into hot topic of the recent researches. Development strategies of the aforementioned technique are more robust and precise when we consider both economical points of view (net present value, NPV and technical points of view (recovery factor, RF. In current study many attempts have been made to propose predictive model for estimation of efficiency of chemical flooding in oil reservoirs. To gain this end, a couple of swarm intelligence and artificial neural network (ANN is employed. Also, lucrative and high precise chemical flooding data banks reported in previous attentions are utilized to test and validate proposed intelligent model. According to the mean square error (MSE, correlation coefficient, and average absolute relative deviation, the suggested swarm approach has acceptable reliability, integrity and robustness. Thus, the proposed intelligent model can be considered as an alternative model to predict the efficiency of chemical flooding in oil reservoir when the required experimental data are not available or accessible.

  17. SYSTEM FOR DETECTION AND CONTROL OF DEPOSITION IN KRAFT CHEMICAL RECOVERY BOILERS AND MONITORING GLASS FURNACES

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Peter Ariessohn

    2003-04-15

    Combustion Specialists, Inc. has just completed a project designed to develop the capability to monitor and control the formation of deposits on the outside of boiler tubes inside an operating kraft recovery furnace. This project, which was carried out in the period from April 1, 2001 to January 31, 2003, was funded by the Department of Energy's Inventions and Innovations program. The primary objectives of the project included the development and demonstration of the ability to produce clear images of deposits throughout the convective sections of operating recovery boilers using newly developed infrared imaging technology, to demonstrate the automated detection and quantification of these deposits using custom designed image processing software developed as part of the project, and to demonstrate the feasibility of all technical elements required for a commercial ''smart'' sootblowing control system based on direct feedback from automated imaging of deposits in real-time. All of the individual tasks have been completed and all objectives have been substantially achieved. Imaging of deposits throughout the convective sections of several recovery boilers has been demonstrated, a design for a combined sootblower/deposit inspection probe has been developed and a detailed heat transfer analysis carried out to demonstrate the feasibility of this design, an improved infrared imager which can be sufficiently miniaturized for this application has been identified, automated deposit detection software has been developed and demonstrated, a detailed design for all the necessary communications and control interfaces has been developed, and a test has been carried out in a glass furnace to demonstrate the applicability of the infrared imaging sensor in that environment. The project was completed on time and within the initial budget. A commercial partner has been identified and further federal funding will be sought to support a project to develop a

  18. Recovery of microbial diversity and activity during bioremediation following chemical oxidation of diesel contaminated soils.

    Science.gov (United States)

    Sutton, Nora B; Langenhoff, Alette A M; Lasso, Daniel Hidalgo; van der Zaan, Bas; van Gaans, Pauline; Maphosa, Farai; Smidt, Hauke; Grotenhuis, Tim; Rijnaarts, Huub H M

    2014-03-01

    To improve the coupling of in situ chemical oxidation and in situ bioremediation, a systematic analysis was performed of the effect of chemical oxidation with Fenton's reagent, modified Fenton's reagent, permanganate, or persulfate, on microbial diversity and activity during 8 weeks of incubation in two diesel-contaminated soils (peat and fill). Chemical oxidant and soil type affected the microbial community diversity and biodegradation activity; however, this was only observed following treatment with Fenton's reagent and modified Fenton's reagent, and in the biotic control without oxidation. Differences in the highest overall removal efficiencies of 69 % for peat (biotic control) and 59 % for fill (Fenton's reagent) were partially explained by changes in contaminant soil properties upon oxidation. Molecular analysis of 16S rRNA and alkane monooxygenase (alkB) gene abundances indicated that oxidation with Fenton's reagent and modified Fenton's reagent negatively affected microbial abundance. However, regeneration occurred, and final relative alkB abundances were 1-2 orders of magnitude higher in chemically treated microcosms than in the biotic control. 16S rRNA gene fragment fingerprinting with DGGE and prominent band sequencing illuminated microbial community composition and diversity differences between treatments and identified a variety of phylotypes within Alpha-, Beta-, and Gammaproteobacteria. Understanding microbial community dynamics during coupled chemical oxidation and bioremediation is integral to improved biphasic field application.

  19. Measuring Dimensions of Spirituality in Chemical Dependence Treatment and Recovery: Research and Practice

    Science.gov (United States)

    Shorkey, Clayton; Uebel, Michael; Windsor, Liliane C.

    2008-01-01

    Spirituality and religiousness have long been associated with physical and mental health. The scientific treatment of religiosity as a multi-dimensional phenomenon is well established, especially in relation to chemical dependence treatment. Indeed, over 100 instruments are available for measuring various dimensions of religiosity. The more recent…

  20. Environmentally Friendly Propylene/Propane Recovery Process Increases Economic Benefits to Daqing Chemical Research Center

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ "The process for recovering propylene/propane from Oxo-synthesis purge gas" performed by Daqing Chemical Re-search Center has been granted the Heilongjiang Governor's Special Award. This technology since its application at Daqing Petrochemical Company starting at the end of 2001 has contributed to effective materials utilization and envi-ronmental protection.

  1. A facile chemical route for recovery of high quality zinc oxide nanoparticles from spent alkaline batteries.

    Science.gov (United States)

    Deep, Akash; Sharma, Amit L; Mohanta, Girish C; Kumar, Parveen; Kim, Ki-Hyun

    2016-05-01

    Recycling of spent domestic batteries has gained a great environmental significance. In the present research, we propose a new and simple technique for the recovery of high-purity zinc oxide nanoparticles from the electrode waste of spent alkaline Zn-MnO2 batteries. The electrode material was collected by the manual dismantling and mixed with 5M HCl for reaction with a phosphine oxide reagent Cyanex 923® at 250°C for 30min. The desired ZnO nanoparticles were restored from the Zn-Cyanex 923 complex through an ethanolic precipitation step. The recovered particle product with about 5nm diameter exhibited fluorescent properties (emission peak at 400nm) when excited by UV radiation (excitation energy of 300nm). Thus, the proposed technique offered a simple and efficient route for recovering high purity ZnO nanoparticles from spent alkaline batteries.

  2. Procedure of Destructive Chemical Recovery of Precious Metals in Nitric Acid Production

    OpenAIRE

    Ljubičić, M.; Zečević, N.

    2012-01-01

    The heart of the nitric acid production process is the chemical reactor containing a platinum-based catalyst pack and an associated catchment system, which allows the ammonia oxidation reaction to take place efficiently. Under the severe operating conditions imposed by the high-pressure ammonia oxidation process, the catalyst gauzes experience progressive deterioration, as shown by the restricted surface of the catalyst wires, the loss of catalytic activity and the loss of catalytic materials...

  3. Anionic Extraction for Efficient Recovery of Biobased 2,3-Butanediol-A Platform for Bulk and Fine Chemicals

    DEFF Research Database (Denmark)

    Drabo, Peter; Tiso, Till; Heyman, Benedikt

    2017-01-01

    2,3-Butanediol (BDO) presents a promising platform molecule for the synthesis of basic and fine chemicals. Biotechnological production of BDO from renewable resources with living microbes enables high concentrations in the fermentation broth. The recovery of high-boiling BDO from an aqueous...... fermentation broth presents a subsequent challenge. A method is proposed for BDO isolation based on reversible complexation with phenylboronate in an anionic complex. BDO can be recovered by back-extraction into an acidic solution. The composition of the extracted species was determined by NMR spectroscopy, MS......, and GC-MS methods. The conditions of extraction and back-extraction were optimized by using commercial BDO and finally applied to different fermentation broths. Up to 72-93 % BDO can be extracted and up to 80-90 % can be back-extracted under the optimized conditions. Purified bio-BDO was used...

  4. Methods for chemical recovery of non-carrier-added radioactive tin from irradiated intermetallic Ti-Sb targets

    Science.gov (United States)

    Lapshina, Elena V [Troitsk, RU; Zhuikov, Boris L [Troitsk, RU; Srivastava, Suresh C [Setauket, NY; Ermolaev, Stanislav V [Obninsk, RU; Togaeva, Natalia R [Obninsk, RU

    2012-01-17

    The invention provides a method of chemical recovery of no-carrier-added radioactive tin (NCA radiotin) from intermetallide TiSb irradiated with accelerated charged particles. An irradiated sample of TiSb can be dissolved in acidic solutions. Antimony can be removed from the solution by extraction with dibutyl ether. Titanium in the form of peroxide can be separated from tin using chromatography on strong anion-exchange resin. In another embodiment NCA radiotin can be separated from iodide solution containing titanium by extraction with benzene, toluene or chloroform. NCA radiotin can be finally purified from the remaining antimony and other impurities using chromatography on silica gel. NCA tin-117m can be obtained from this process. NCA tin-117m can be used for labeling organic compounds and biological objects to be applied in medicine for imaging and therapy of various diseases.

  5. The Role of Dissolved Organic Carbon and Preadaptation in the Biotransformation of Trace Organic Chemicals during Aquifer Recharge and Recovery

    KAUST Repository

    Ouf, Mohamed

    2012-05-01

    Aquifer recharge and recovery (ARR) is a low-cost and environmentally-friendly treatment technology which uses conventionally treated wastewater effluent for groundwater recharge and subsequent recovery for agricultural, industrial or drinking water uses. This study investigated the effect of different dissolved organic carbon (DOC) composition in wastewater effluent on the fate of trace organic chemicals (TOrCs) during ARR. Four biologically active columns were setup receiving synthetic wastewater effluent with varying DOC compositions. The difference in DOC composition triggered variations in the microbial community’s diversity and hence its ability to degrade TOrCs. It was found that the presence of protein-like DOC enhances the removal of DOC in comparison with the presence of humic-like DOC. On the other hand, the presence of humic-like DOC, which is more difficult to degrade, improved the removal of several degradable TOrCs. Other column experiments were also carried out to investigate the role of previous and continuous exposure to TOrCs in their removal. The use of soil pre-exposed to low concentrations of TOrCs and DOC provided better removal of both DOC and TOrCs. The findings of this study suggest that the presence of more humic-like DOC in the effluent enhances the biotransformation of TOrCs during ARR. In addition, long exposure to both DOC and TOrCs increases the degree of their removal over time

  6. Bioelectrochemical Integration of Waste Heat Recovery, Waste-to- Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes

    Energy Technology Data Exchange (ETDEWEB)

    Mac Dougall, James [Air Products and Chemicals, Inc., Allentown, PA (United States)

    2016-02-05

    Many U.S. manufacturing facilities generate unrecovered, low-grade waste heat, and also generate or are located near organic-content waste effluents. Bioelectrochemical systems, such as microbial fuel cells and microbial electrolysis cells, provide a means to convert organic-content effluents into electric power and useful chemical products. A novel biochemical electrical system for industrial manufacturing processes uniquely integrates both waste heat recovery and waste effluent conversion, thereby significantly reducing manufacturing energy requirements. This project will enable the further development of this technology so that it can be applied across a wide variety of US manufacturing segments, including the chemical, food, pharmaceutical, refinery, and pulp and paper industries. It is conservatively estimated that adoption of this technology could provide nearly 40 TBtu/yr of energy, or more than 1% of the U.S. total industrial electricity use, while reducing CO2 emissions by more than 6 million tons per year. Commercialization of this technology will make a significant contribution to DOE’s Industrial Technology Program goals for doubling energy efficiency and providing a more robust and competitive domestic manufacturing base.

  7. Fluid diversion and sweep improvement with chemical gels in oil recovery processes

    Energy Technology Data Exchange (ETDEWEB)

    Seright, F.S.; Martin, F.D.

    1991-04-01

    The objectives of this project are to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants are being examined. This research is directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work will establish how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals include determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. This report describes progress made during the first year of this three-year study the following tasks: gel screening studies; impact of gelation pH, rock permeability, and lithology on the performance of a monomer-based gel; preliminary study of the permeability reduction for CO{sub 2} and water using a resorcinol-formaldehyde gel; preliminary study of permeability reduction for oil and water using a resorcinol-formaldehyde gel; rheology of Cr(III)-xanthan gel and gelants in porous media; impact of diffusion, dispersion, and viscous fingering on gel placement in injection wells; examination of flow-profile changes for field applications of gel treatments in injection wells; and placement of gels in production wells. Papers have been indexed separately for inclusion on the data base.

  8. Gravity packaging final waste recovery based on gravity separation and chemical imaging control.

    Science.gov (United States)

    Bonifazi, Giuseppe; Serranti, Silvia; Potenza, Fabio; Luciani, Valentina; Di Maio, Francesco

    2017-02-01

    Plastic polymers are characterized by a high calorific value. Post-consumer plastic waste can be thus considered, in many cases, as a typical secondary solid fuels according to the European Commission directive on End of Waste (EoW). In Europe the practice of incineration is considered one of the solutions for waste disposal waste, for energy recovery and, as a consequence, for the reduction of waste sent to landfill. A full characterization of these products represents the first step to profitably and correctly utilize them. Several techniques have been investigated in this paper in order to separate and characterize post-consumer plastic packaging waste fulfilling the previous goals, that is: gravity separation (i.e. Reflux Classifier), FT-IR spectroscopy, NIR HyperSpectralImaging (HSI) based techniques and calorimetric test. The study demonstrated as the proposed separation technique and the HyperSpectral NIR Imaging approach allow to separate and recognize the different polymers (i.e. PolyVinyl Chloride (PVC), PolyStyrene (PS), PolyEthylene (PE), PoliEtilene Tereftalato (PET), PolyPropylene (PP)) in order to maximize the removal of the PVC fraction from plastic waste and to perform the full quality control of the resulting products, can be profitably utilized to set up analytical/control strategies finalized to obtain a low content of PVC in the final Solid Recovered Fuel (SRF), thus enhancing SRF quality, increasing its value and reducing the "final waste". Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Fluid diversion and sweep improvement with chemical gels in oil recovery processes

    Energy Technology Data Exchange (ETDEWEB)

    Seright, F.S.; Martin, F.D.

    1991-04-01

    The objectives of this project are to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants are being examined. This research is directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work will establish how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals include determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. This report describes progress made during the first year of this three-year study the following tasks: gel screening studies; impact of gelation pH, rock permeability, and lithology on the performance of a monomer-based gel; preliminary study of the permeability reduction for CO{sub 2} and water using a resorcinol-formaldehyde gel; preliminary study of permeability reduction for oil and water using a resorcinol-formaldehyde gel; rheology of Cr(III)-xanthan gel and gelants in porous media; impact of diffusion, dispersion, and viscous fingering on gel placement in injection wells; examination of flow-profile changes for field applications of gel treatments in injection wells; and placement of gels in production wells. Papers have been indexed separately for inclusion on the data base.

  10. Selective recovery of precious metals by persimmon waste chemically modified with dimethylamine.

    Science.gov (United States)

    Xiong, Ying; Adhikari, Chaitanya Raj; Kawakita, Hidetaka; Ohto, Keisuke; Inoue, Katsutoshi; Harada, Hiroyuki

    2009-09-01

    Persimmon waste was chemically modified with dimethylamine (DMA) to obtain a tertiary-amine-type gel, named DMA persimmon waste gel (DMA-PW). It was found to be effective for the adsorption of Au(III), Pd(II), and Pt(IV) in hydrochloric acid medium. In contrast, base metals such as Cu(II), Zn(II), Fe(III), and Ni(II) were not practically adsorbed. The formation of ion pairs of the metal chloro complex anions with the protonated adsorption gels was proposed as the main adsorption process. The gel exhibited selectivity only for precious metals with a remarkably high capacity for Au(III), i.e., 5.63 mol/kg dry gel and comparable capacities, i.e., 0.42 and 0.28 mol/kg for Pd(II) and Pt(IV), respectively. According to the kinetic and electrochemical studies, the adsorption rate of Au(III) was greatly enhanced by the chemical modification. Also, its excellent adsorption characteristics for the precious metals were confirmed by adsorption and elution tests using a column packed with the DMA-PW gel.

  11. Analysis of Thermal and Chemical Effets on Negative Valve Overlap Period Energy Recovery for Low-Temperature Gasoline Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ekoto, Dr Isaac [Sandia National Laboratories (SNL); Peterson, Dr. Brian [University of Edinburgh; Szybist, James P [ORNL; Northrop, Dr. William [University of Minnesota

    2015-01-01

    A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate. Gas sampling at the end of the NVO period was performed via a custom dump-valve apparatus, with detailed sample speciation by in-house gas chromatography. The balance of NVO-period input and output energy flows was calculated in terms of fuel energy, work, heat loss, and change in sensible energy. Experiment results were complemented by detailed chemistry single-zone reactor simulations performed at relevant mixing and thermodynamic conditions, with results used to evaluate ignition behavior and expected energy recovery yields. For the intermediate bulk-gas temperatures present during the NVO period (900-1100 K), weak negative temperature coefficient behavior with iso-octane fueling significantly lengthened ignition delays relative to similar ethanol fueled conditions. Faster ethanol ignition chemistry led to lower recovered fuel intermediate yields relative to similar iso-octane fueled conditions due to more complete fuel oxidation. From the energy analysis it was found that increased NVO-period global equivalence ratio, either from lower NVOperiod oxygen

  12. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Wei-Ping; Cao, Yan

    2012-11-30

    Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen

  13. Chemical Structure, Property and Potential Applications of Biosurfactants Produced by Bacillus subtilis in Petroleum Recovery and Spill Mitigation

    Directory of Open Access Journals (Sweden)

    Jin-Feng Liu

    2015-03-01

    Full Text Available Lipopeptides produced by microorganisms are one of the five major classes of biosurfactants known and they have received much attention from scientific and industrial communities due to their powerful interfacial and biological activities as well as environmentally friendly characteristics. Microbially produced lipopeptides are a series of chemical structural analogues of different families and, among them, 26 families covering about 90 lipopeptide compounds have been reported in the last two decades. This paper reviews the chemical structural characteristics and molecular behaviors of surfactin, one of the representative lipopeptides of the 26 families. In particular, two novel surfactin molecules isolated from cell-free cultures of Bacillus subtilis HSO121 are presented. Surfactins exhibit strong self-assembly ability to form sphere-like micelles and larger aggregates at very low concentrations. The amphipathic and surface properties of surfactins are related to the existence of the minor polar and major hydrophobic domains in the three 3-D conformations. In addition, the application potential of surfactin in bioremediation of oil spills and oil contaminants, and microbial enhanced oil recovery are discussed.

  14. Recovery of metal values from spent lithium-ion batteries with chemical deposition and solvent extraction

    Science.gov (United States)

    Nan, Junmin; Han, Dongmei; Zuo, Xiaoxi

    This paper describes a new recycling process of metal values from spent lithium-ion batteries (LIBs). After the dismantling of the spent batteries steel crusts, the leaching of battery internal substances with alkaline solution and the dissolving of the residues with H 2SO 4 solution were carried out. Then mass cobalt was chemically deposited as oxalate, and Acorga M5640 and Cyanex272 extracted the small quantities of copper and cobalt, respectively. Lithium was recovered as deposition of lithium carbonate. It is shown that about 90% cobalt was deposited as oxalate with less than 0.5% impurities, and Acorga M5640 and Cyanex272 were efficient and selective for the extraction of copper and cobalt in sulfate solution. Over 98% of the copper and 97% of the cobalt was recovered in the given process. In addition, the waste solution was treated innocuously, and LiCoO 2 positive electrode material with good electrochemical performance was also synthesized by using the recovered compounds of cobalt and lithium as precursors. The process is feasible for the recycling of spent LIBs in scale-up.

  15. Electrochemically induced crystallization as a sustainable method for product recovery of building block chemicals: techno-economic evaluation of fumaric acid separation

    NARCIS (Netherlands)

    Nasrollahnejad, T.; Urbanus, J.; Horst, J.H. ter; Verdoes, D.; Roelands, C.P.M.

    2012-01-01

    Carboxylic acids are key platform chemicals for use as biobased alternatives for fossil-based applications. State-of-the-art fermentations of carboxylic acids at neutral pH with downstream product recovery by pH-shift crystallization are not sustainable due to the accompanied production of waste sal

  16. Electrochemically Induced Crystallization as a Sustainable Method for Product Recovery of Building Block Chemicals: Techno-Economic Evaluation of Fumaric Acid Separation

    NARCIS (Netherlands)

    Nasrollahnejad, T.; Urbanus, J.; Ter Horst, J.H.; Verdoes, D.; Roelands, C.P.M.

    2012-01-01

    Carboxylic acids are key platform chemicals for use as biobased alternatives for fossil-based applications. State-of-the-art fermentations of carboxylic acids at neutral pH with downstream product recovery by pH-shift crystallization are not sustainable due to the accompanied production of waste sal

  17. Anionic Extraction for Efficient Recovery of Biobased 2,3-Butanediol-A Platform for Bulk and Fine Chemicals.

    Science.gov (United States)

    Drabo, Peter; Tiso, Till; Heyman, Benedikt; Sarikaya, Eda; Gaspar, Paula; Förster, Jochen; Büchs, Jochen; Blank, Lars Mathias; Delidovich, Irina

    2017-08-24

    2,3-Butanediol (BDO) presents a promising platform molecule for the synthesis of basic and fine chemicals. Biotechnological production of BDO from renewable resources with living microbes enables high concentrations in the fermentation broth. The recovery of high-boiling BDO from an aqueous fermentation broth presents a subsequent challenge. A method is proposed for BDO isolation based on reversible complexation with phenylboronate in an anionic complex. BDO can be recovered by back-extraction into an acidic solution. The composition of the extracted species was determined by NMR spectroscopy, MS, and GC-MS methods. The conditions of extraction and back-extraction were optimized by using commercial BDO and finally applied to different fermentation broths. Up to 72-93 % BDO can be extracted and up to 80-90 % can be back-extracted under the optimized conditions. Purified bio-BDO was used in the presence of sulfuric acid for the synthesis of methyl ethyl ketone, an established organic solvent and discussed tailor-made biofuel. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Selective recovery of pure copper nanopowder from indium-tin-oxide etching wastewater by various wet chemical reduction process: Understanding their chemistry and comparisons of sustainable valorization processes.

    Science.gov (United States)

    Swain, Basudev; Mishra, Chinmayee; Hong, Hyun Seon; Cho, Sung-Soo

    2016-05-01

    Sustainable valorization processes for selective recovery of pure copper nanopowder from Indium-Tin-Oxide (ITO) etching wastewater by various wet chemical reduction processes, their chemistry has been investigated and compared. After the indium recovery by solvent extraction from ITO etching wastewater, the same is also an environmental challenge, needs to be treated before disposal. After the indium recovery, ITO etching wastewater contains 6.11kg/m(3) of copper and 1.35kg/m(3) of aluminum, pH of the solution is very low converging to 0 and contain a significant amount of chlorine in the media. In this study, pure copper nanopowder was recovered using various reducing reagents by wet chemical reduction and characterized. Different reducing agents like a metallic, an inorganic acid and an organic acid were used to understand reduction behavior of copper in the presence of aluminum in a strong chloride medium of the ITO etching wastewater. The effect of a polymer surfactant Polyvinylpyrrolidone (PVP), which was included to prevent aggregation, to provide dispersion stability and control the size of copper nanopowder was investigated and compared. The developed copper nanopowder recovery techniques are techno-economical feasible processes for commercial production of copper nanopowder in the range of 100-500nm size from the reported facilities through a one-pot synthesis. By all the process reported pure copper nanopowder can be recovered with>99% efficiency. After the copper recovery, copper concentration in the wastewater reduced to acceptable limit recommended by WHO for wastewater disposal. The process is not only beneficial for recycling of copper, but also helps to address environment challenged posed by ITO etching wastewater. From a complex wastewater, synthesis of pure copper nanopowder using various wet chemical reduction route and their comparison is the novelty of this recovery process.

  19. Short term recovery of soil physical, chemical, micro- and mesobiological functions in a new vineyard under organic farming

    Science.gov (United States)

    Costantini, E. A. C.; Agnelli, A. E.; Fabiani, A.; Gagnarli, E.; Mocali, S.; Priori, S.; Simoni, S.; Valboa, G.

    2014-12-01

    vineyard and time, increasing with rain precipitations in the old vineyard. Though the euedaphic forms, well adapted to soil life, were always rare. Microbiological analysis revealed a different structure of eubacterial communities between old and new vineyard in the whole period. However, the DGGE similarity values of such communities increased of about 2.5% per year, suggesting that at least 3 years more are needed to compare intra- and inter-specific diversity of the two vineyards. In conclusion, the consequences of deep earthworks on soil chemical, micro and mesobiological properties were still evident after four years from planting, indicating that more time is necessary for the recovery of soil functions, probably longer than that needed to obtain an economic grape production.

  20. Modification of reservoir chemical and physical factors in steamfloods to increase heavy oil recovery. [Quarterly report], January 1--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C. [University of Southern California, Los Angeles, CA (United States)

    1997-08-01

    Thermal methods, and particularly steam injection, are currently recognized as the most promising for the efficient recovery of heavy oil. Despite significant progress, however, important technical issues remain open. Specifically, still inadequate is our knowledge of the complex interaction between porous media and the various fluids of thermal recovery (steam, water, heavy oil, gases, and chemicals). While, the interplay of heat transfer and fluid flow with pore- and macro-scale heterogeneity is largely unexplored. The objectives of this contract are to continue previous work and to carry out new fundamental studies in the following areas of interest to thermal recovery: displacement and flow properties of fluids involving phase change (condensation-evaporation) in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on thermal recovery. The specific projects are motivated by and address the need to improve heavy oil recovery from typical reservoirs as well as less conventional fractured reservoirs producing from vertical or horizontal wells. During this quarter, work continued on the development of relative permeabilities during steam displacement. Most of the work concentrated on the representation of the three-phase flow in terms of a double-drainage process. Work continued on the optimization of recovery processes in heterogeneous reservoirs by using optimal control methods. The effort at present is concentrating in fine-tuning the optimization algorithm as well as in developing control methodologies with different constraints. In parallel, we continued experiments in a Hele-Shaw cell with two controlled injection wells and one production well. In the area of chemical additives work continued on the behavior of non-Newtonian fluid flow and on foam displacements in porous media.

  1. Effects of Non Process Elements in the chemical recovery system of a kraft pulp mill from the incineration in the recovery boiler of biological sludge; Effekter av PFG vid indunstning och foerbraenning av bioslam i ett massabruks sodapanna

    Energy Technology Data Exchange (ETDEWEB)

    Dahlbom, Johan

    2003-01-01

    The purpose of this project was to investigate the effects of incineration of biological sludge in the recovery boiler of a Swedish Kraft pulp mill, StoraEnso Pulp AB Skutskaers Bruk, which has practiced incineration of sludge in the recovery boiler during the last two years. The following aspects of the technique were investigated: Experience from operation of incineration of biological sludge in the recovery boiler; The content of Non-Process Elements (NPE) in process flows and evaluate the risks of incrustations in the system; The build-up of NPE in the chemicals recovery system and the estimated increase in make-up lime demand; and Technical risks for mills with different process equipment. This study comprises the following NPE: aluminium, silicon, phosphorus, magnesium, calcium, chloride, iron, manganese, potassium, copper, and nitrogen. The operational experience from the system for hydrolysis of the biological sludge and evaporation/incineration in the recovery boiler is excellent. The handling of the sludge takes place in a closed system that demands little supervision and maintenance. Overall, the mill has not seen any negative effects that can be explained by increased intake of NPEs to the chemical recovery system. Aluminium can lead to troublesome incrustations of sodium-aluminium-silicates on the heat surfaces in the evaporation plant. An effective elimination of aluminium by the green liquor dreg is obtained with the double salt hydrotalcite if the quotient Mg/Al is kept higher than 4-5 in the black liquor. The need for make-up lime has increased due to the build-up of phosphorus in the lime. Depending on the level of make-up lime the need will increase 2-5 kg/ t{sub 90} at a price of 2-5 kr/t{sub 90}. If a higher level of phosphorus is accepted instead of increasing lime make-up the running costs will be somewhat higher, 0,5-1 kr/t{sub 90} due to increased ballast. NO{sub x} in the flue gases from the recovery boiler has not increased since the

  2. 煤化工项目硫回收工艺技术分析%Analysis of Sulfur Recovery Processes in Coal-chemical Projects

    Institute of Scientific and Technical Information of China (English)

    张明成; 蒋保林

    2011-01-01

    介绍了煤化工装置硫回收的特点,评述煤化工装置三类常用的硫回收工艺,并对这三类工艺进行对比。结果表明,目前中国煤化工领域硫回收装置主要采用的是克劳斯的延伸工艺。%In the paper,the sulfur recovery characteristics of coal-chemical plant were introduced.Three kings of commonly used sulfur recovery processes were reviewed and compared also.The result showed that the extension of claus process was widely used in coal-chemical industry.

  3. Short-term recovery of soil physical, chemical, micro- and mesobiological functions in a new vineyard under organic farming

    Science.gov (United States)

    Costantini, E. A. C.; Agnelli, A. E.; Fabiani, A.; Gagnarli, E.; Mocali, S.; Priori, S.; Simoni, S.; Valboa, G.

    2015-06-01

    abundances and community structures, in relation to both vineyard and time. Rainfall appeared to have an enhancing effect on microarthropod abundance, but only in the old vineyard, where the biota was more structured than in the new one. The euedaphic forms, well adapted to soil life, were always rare. Microbiological analysis revealed a different structure of eubacterial communities between the old and the new vineyard in the whole period. However, the DGGE similarity values of these communities increased by about 2.5% per year, suggesting that at least 3 years more are needed to compare intra- and inter-specific diversity of the two vineyards. In conclusion, the consequences of deep earthworks on soil chemical, micro- and mesobiological properties were still evident 4 years after planting, indicating that more time is necessary for the recovery of soil functions, probably longer than the time needed to reach a state of economically viable grape production.

  4. Modification of chemical and physical factors in steamflood to increase heavy oil recovery. Annual report, October 1, 1992--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1994-10-01

    Thermal methods, and particularly steam injection, are currently recognized as the most promising for the efficient recovery of heavy oil. Despite significant progress, however, important technical issues remain open. Specifically, still inadequate is our knowledge of the complex interaction between porous media and the various fluids of thermal recovery (steam, water, heavy oil, gases, and chemicals). While, the interplay of heat transfer and fluid flow with pore- and macro-scale heterogeneity is largely unexplored. Objectives of this work contract are to carry out new studies in the following areas: displacement and flow properties of fluids involving phase change in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on thermal recovery. Specific projects address the need to improve heavy oil recovery from typical reservoirs as well as less conventional fractured reservoirs producing from vertical or horizontal wells. In the area of vapor-liquid flow, we present the continuation of work on the pore network modeling of bubble growth in porous media driven by the application of a prescribed heat flux or superheat. The scaling of bubble growth in porous media is also discussed. In another study we study the problem of steam injection in fractured systems using visualization in micromodels. The interplay of drainage, imbibition and bubble growth problems is discussed.

  5. RE-UTILIZATION OF INORGANIC SOLID WASTE (LIME MUD AS FOREST ROAD STABILIZER FROM THE CHEMICAL RECOVERY PROCESS IN KRAFT PULP MILL

    Directory of Open Access Journals (Sweden)

    Habip Eroğlu

    2005-04-01

    Full Text Available Waste handling is a concern in all pulp and paper mills. Best available techniques for reducing waste is to minimize the generation of solid waste and/or reuse these materials, wherever practicable. One of the most important solid wastes is lime mud which is generated from the kraft pulping in its chemical recovery process. This paper explores the composition of lime mud resulting from the chemical recovery unite of kraft pulp mill and investigation of this waste for re-using beneficially on sub grade and pavement of forest road as a alternative disposal method. Lime mud obtained from the re-causticising process in SEKA pulp mill that utilizes wheat straw and reed as the principal raw material was supplied with % 47 water content and its chemical and physical characterisations was performed according to standard methods. Dried waste to environmental condition was mixed with certain amount to composite cement for using on pavement and sandy clay, loamy clay and clay soils for enriching forest road sub grade properties. In order to investigate the lime mud addition on pavement and sub grade properties necessary physical tests were performed. As a consequence this study reveals that while waste of lime mud causes environmental and economical problem with conventional disposal techniques and/or abandoning to environment, this waste can be used as good stabilisation materials on forest road sub-grade and pavement without any environmental problem.

  6. A roadmap for the synthesis of separation networks for the recovery of bio-based chemicals: Matching biological and process feasibility.

    Science.gov (United States)

    Yenkie, Kirti M; Wu, WenZhao; Clark, Ryan L; Pfleger, Brian F; Root, Thatcher W; Maravelias, Christos T

    2016-12-01

    Microbial conversion of renewable feedstocks to high-value chemicals is an attractive alternative to current petrochemical processes because it offers the potential to reduce net CO2 emissions and integrate with bioremediation objectives. Microbes have been genetically engineered to produce a growing number of high-value chemicals in sufficient titer, rate, and yield from renewable feedstocks. However, high-yield bioconversion is only one aspect of an economically viable process. Separation of biologically synthesized chemicals from process streams is a major challenge that can contribute to >70% of the total production costs. Thus, process feasibility is dependent upon the efficient selection of separation technologies. This selection is dependent on upstream processing or biological parameters, such as microbial species, product titer and yield, and localization. Our goal is to present a roadmap for selection of appropriate technologies and generation of separation schemes for efficient recovery of bio-based chemicals by utilizing information from upstream processing, separation science and commercial requirements. To achieve this, we use a separation system comprising of three stages: (I) cell and product isolation, (II) product concentration, and (III) product purification and refinement. In each stage, we review the technology alternatives available for different tasks in terms of separation principles, important operating conditions, performance parameters, advantages and disadvantages. We generate separation schemes based on product localization and its solubility in water, the two most distinguishing properties. Subsequently, we present ideas for simplification of these schemes based on additional properties, such as physical state, density, volatility, and intended use. This simplification selectively narrows down the technology options and can be used for systematic process synthesis and optimal recovery of bio-based chemicals.

  7. Strong Seasonality in the Response of Streams to Declining Acidic Deposition—the Latest on the Chemical Recovery of Adirondack Streams

    Science.gov (United States)

    Lawrence, G. B.; Siemion, J.; Baldigo, B. P.; Roy, K. M.

    2016-12-01

    Acidic deposition effects on surface waters have been well documented in North America, and several decades of declining sulfur deposition along with more recent declines in nitrogen deposition have shifted the focus to recovery. Partial chemical recovery of surface waters has been recorded in impacted areas such as the Adirondack region of NY, but most information on surface-water recovery in the northeastern U.S. has been collected from lakes. Because lakes can provide in-lake acid-buffering that doesn't occur in streams, these water bodies may not follow the same recovery trajectory. To provide up-to-date information on how stream chemistry is responding to declining deposition, 64 Adirondack streams were sampled in 2004-05 during summer base flow and spring snowmelt, and again in 2014-15 during the same seasons and flow conditions. Two tributaries of Buck Creek, in the same region, also provided biweekly and event chemistry data from 1998 to 2015. Decreases in SO4 concentrations were observed in nearly all streams and were likely to be driving the decreases also observed in base-flow concentrations of inorganic monomeric Al, the form toxic to aquatic biota (P 0.1) in BCS during snowmelt. Despite decreasing atmospheric N deposition throughout the study period, concentrations of NO3 showed no difference between 2004-05 and 2014-15 on an annual basis (P >0.1), although concentrations were higher during snowmelt (P Buck Creek during elevated flows, regardless of season. As a result of base flow recovery and continued high-flow acidification driven by NO3 release, wide fluctuations in stream chemistry continue to occur.

  8. Linking mechanistic toxicology to population models in forecasting recovery from chemical stress: A case study from Jackfish Bay, Ontario, Canada

    Science.gov (United States)

    A Beneficial Use Impairment (BUI) common at Great Lakes Areas of Concern (AOCs) is loss of fish and wildlife populations. Consequently, recovery of populations after stressor mitigation serves as a basis for evaluating remediation success. We describe a framework that can be a...

  9. Modification of the Recovery Behavior of TiNi Shape Memory Alloy (SMA) by Chemical Heat Treatment

    Institute of Scientific and Technical Information of China (English)

    WANG Gao-chao; YANG Gang; HUANG Yi-bin; MIN Si-lin

    2004-01-01

    In order to improve the linear recovery behavior, TiNi shape memory alloy springs were samariumed at 550℃for 4 hours with SmH3 as samarium source, in a vacuum furnace. The phase of samariumed layer was determined by X-ray diffractometer (XRD). The fracture surface of TiNi SMA spring was investigated by scanning electronic microscope (SEM). The experimental results indicate that a 2μm thick samariumed layer composed of NiSm intermetallics existed on the fracture surface. Additionally, a new idea of linear recovery behavior in shape memory alloy(SMA) has been proposed, and its properties have been defined. The reversion measurements show that the linear recovery properties of TiNi SMA were obviously improved. The temperature range of the linear reversion (Tw) was enlarged from 4℃ to 8℃, The ratio of linear reversion (η) was increased from 54% to 75%, the proportion of linear reversion (PL) was increased from 56% to 70%, and the proportion of non-linear reversion (Ps) was decreased from 44%to 10%, but the proportion of total reversion (PT) has a little decrease. These results were attributed to the strengthening effect of NiSm intermetallics.

  10. A study of the effects of enhanced oil recovery agents on the quality of Strategic Petroleum Reserves crude oil. [Physical and chemical interactions of Enhanced Oil Recovery reagents with hydrocarbons present in petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Kabadi, V.N.

    1992-10-01

    The project was initiated on September 1, 1990. The objective of the project was to carry out a literature search to estimate the types and extents of long time interactions of enhanced oil recovery (EOR) agents, such as surfactants, caustics and polymers, with crude oil. This information is necessary to make recommendations about mixing EOR crude oil with crude oils from primary and secondary recovery processes in the Strategic Petroleum Reserve (SPR). Data were sought on both adverse and beneficial effects of EOR agents that would impact handling, transportation and refining of crude oil. An extensive literature search has been completed, and the following informations has been compiled: (1) a listing of existing EOR test and field projects; (2) a listing of currently used EOR agents; and (3) evidence of short and long term physical and chemical interactions of these EOR-agents with hydrocarbons, and their effects on the quality of crude oil at long times. This information is presented in this report. Finally some conclusions are derived and recommendations are made. Although the conclusions are based mostly on extrapolations because of lack of specific data, it is recommended that the enhancement of the rates of biodegradation of oil catalyzed by the EOR agents needs to be further studied. There is no evidence of substantial long term effects on crude oil because of other interactions. Some recommendations are also made regarding the types of studies that would be necessary to determine the effect of certain EOR agents on the rates of biodegradation of crude oil.

  11. 化学水处理系统自用水回收利用%Chemical Water Treatment and Recovery for Water Utilization System

    Institute of Scientific and Technical Information of China (English)

    袁育亭; 刘政修

    2014-01-01

    According to the importance of water resource and the reality of the lack of analysis of chemical use, water recycling necessity. According to the typical chemical water treatment process, analysis of chemical water treatment system for water quality, water use rate. The chemical water treatment system for water (chemical pretreatment system and chemical osmosis equipment) should pay attention to the problem of recovery and utilization. The company of chemical water treatment system process, chemical water treatment system for the calculation of water, on the basis of chemical water treatment system for water quality, water quantity, in accordance with the“cascade use, decontamination triage”principle, established the system of chemical water treatment for water recycling and reuse scheme, and to the social and economic benefits the analysis.%依据水资源重要性及严重匮乏的现实情况,分析了化学自用水回收利用必要性。根据典型化学水处理工艺,分析了化学水处理系统自用水质量、自用水率。介绍了化学水处理系统自用水(化学预处理系统及化学反渗透设备)回收利用应该注意的问题。介绍了公司化学水处理系统工艺流程,计算了化学水处理系统自用水量,依据化学水处理系统自用水水质、水量,按照“梯级使用、清污分流”的原则,制订了化学水处理系统自用水分类回收和重复利用方案,并对社会及经济效益进行了分析。

  12. Modification of reservoir chemical and physical factors in steamfloods to increase heavy oil recovery. [Quarterly report], January 1--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1996-07-01

    Thermal methods, and particularly steam injection, are currently recognized as the most promising for the efficient recovery of heavy oil. Despite significant progress, however, important technical issues remain open. Specifically, still inadequate is our knowledge of the complex interaction between porous media and the various fluids of thermal recovery (steam, water, heavy oil, gases, and chemicals). While, the interplay of heat transfer and fluid flow with pore- and macro-scale heterogeneity is largely unexplored. The objectives of this contract are to continue previous work and to carry out new fundamental studies in the following areas of interest to thermal recovery: displacement and flow properties of fluids involving phase change in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on thermal recovery. During this quarter, we focused on the development of relative permeabilities during steam displacement. Two particular directions were pursued: One involves the derivation of relative permeabilities based on a recently completed work on the pore-level mechanics of steam displacement. Progress has been made to relate the relative permeabilities to effects such as heat transfer and condensation, which are specific to steam injection problems. The second direction involves the development of three-phase relative permeabilities using invasion percolation concepts. We have developed models that predict the specific dependence of the permeabilities of three immiscible phases (e.g. awe, water and gas) on saturations and the saturation history. Both works are still in progress. In addition, work continues in the analysis of the stability of phase change fronts in porous media using a macroscopic approach.

  13. A consideration of potential confounding factors limiting chemical and biological recovery at Lochnagar, a remote mountain loch in Scotland

    Directory of Open Access Journals (Sweden)

    Derek MUIR

    2004-02-01

    Full Text Available Lochnagar, a remote loch in the Grampian Mountains of Scotland is one of the most studied freshwater bodies in the UK. It represents a key site in a number of monitoring programmes and has become the UK’s 'flag-ship' mountain lake in various EU funded projects over the last 15 years. Palaeolimnological studies have revealed the extent and diverse provenance of atmospherically deposited pollution at the site and show that the loch began to acidify in the mid-19th century. However, despite abatement strategies dramatically reducing the emission and deposition of non-marine sulphate and trace metals since the 1970s, the loch pH shows little sign of recovery and full basin fluxes of, for example, Pb and Hg show no decline or even a continued increase. It is suggested that the lack of recovery from acidification over the last 15 years of monitoring results from the balancing of the decline in sulphate by increased nitrate, and that this increase is related to winter duration and severity. The lack of response by the sediment record to declines in metal deposition is thought to be due to a continuing input of previously deposited metals from the catchment. Hypotheses for these enhanced catchment inputs involve responses to a changing climate. Site specific climate reconstructions and predictions for the 21st century suggest an accelerated increase in temperature rise and increased winter precipitation and storminess. These predicted changes are likely to exacerbate the input of metals (and other stored pollutants from the catchment but higher temperatures may also help to promote recovery from acidification.

  14. CHEMICALS

    CERN Document Server

    Medical Service

    2002-01-01

    It is reminded that all persons who use chemicals must inform CERN's Chemistry Service (TIS-GS-GC) and the CERN Medical Service (TIS-ME). Information concerning their toxicity or other hazards as well as the necessary individual and collective protection measures will be provided by these two services. Users must be in possession of a material safety data sheet (MSDS) for each chemical used. These can be obtained by one of several means : the manufacturer of the chemical (legally obliged to supply an MSDS for each chemical delivered) ; CERN's Chemistry Service of the General Safety Group of TIS ; for chemicals and gases available in the CERN Stores the MSDS has been made available via EDH either in pdf format or else via a link to the supplier's web site. Training courses in chemical safety are available for registration via HR-TD. CERN Medical Service : TIS-ME :73186 or service.medical@cern.ch Chemistry Service : TIS-GS-GC : 78546

  15. Enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Chakma, A.; Rafiq Islam, M.; Berruti, F.

    1991-01-01

    Some forty to sixty percent of the original oil in place typically remains trapped in the reservoir after primary and secondary recoveries. Enhanced oil recovery refers to the recovery of the residual oil by different techniques. Many of the existing and proposed enhanced oil recovery techniques require sound understanding of basic chemical engineering principles such as fluid flow, heat and mass transfer, interfacial phenomena etc. Chemical EOR techniques require a good understanding of interfacial phenomena, chemical reaction, multicomponent absorption. Understanding of the fundamentals of the various EOR processes is not adequate. EOR is increasingly attracting a growing number of chemical engineers and, as a result, some of the fundamental aspect of EOR are now being investigated. However, much more remains to be done and chemical engineers can play an important role in providing a better understanding of EOR fundamentals. This volume presents selected papers on EOR presented at AICHE meetings.

  16. Recovery of Americium-241 from lightning rod by the method of chemical treatment; Recuperacion del Americio-241 provenientes de los pararrayos por el metodo de tratamiento quimico

    Energy Technology Data Exchange (ETDEWEB)

    Cruz, W.H., E-mail: wcruz@ipen.gob.pe [Instituto Peruano de Energia Nuclear (GRRA/IPEN), Lima (Peru). Division de Gestion de Residuos Radiactivos

    2013-07-01

    About 95% of the lightning rods installed in the Peruvian territory have set in their structures, pose small amounts of radioactive sources such as Americium-241 ({sup 241}Am), fewer and Radium 226 ({sup 226}Ra) these are alpha emitters and have a half life of 432 years and 1600 years respectively. In this paper describes the recovery of radioactive sources of {sup 241}Am radioactive lightning rods using the conventional chemical treatment method using agents and acids to break down the slides. The {sup 241}Am recovered was as excitation source and alpha particle generator for analysing samples by X Ray Fluorescence, for fixing the stainless steel {sup 241}Am technique was used electrodeposition. (author)

  17. Modification of chemical and physical factors in steamflood to increase heavy oil recovery. Annual report, October 1, 1991--September 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1993-07-01

    This report covers work performed in the various physicochemical factors for the improvement of oil recovery efficiency. In this context, three general areas were studied: (i) The understanding of vapor-liquid flow in porous media, whether the flow is internal (boiling), external (steam injection) or countercurrent (as in vertical heat pipes); (ii) The effect of reservoir heterogeneity, particularly as it regards fractured systems; (iii) The flow properties of additives for the improvement of recovery efficiency, in particular the injection of caustic and foams. The studies completed under this contract involved ap three research tools, analysis, computation and experiments. We have focused on pore level modeling using pore networks and on flow visualization using Hele-Shaw cells. Experiments involving core samples were conducted for the chemical additives investigation. Finally, simulation at the pore scale, pore network scale and reservoir scale were also undertaken. Part of the work has been detailed in five DOE Technical Reports as shown at the end of this report.

  18. Synthesis and Performance of an Acrylamide Copolymer Containing Nano-SiO2 as Enhanced Oil Recovery Chemical

    Directory of Open Access Journals (Sweden)

    Zhongbin Ye

    2013-01-01

    Full Text Available A novel copolymer containing nano-SiO2 was synthesized by free radical polymerization using acrylamide (AM, acrylic acid (AA, and nano-SiO2 functional monomer (NSFM as raw materials under mild conditions. The AM/AA/NSFM copolymer was characterized by infrared (IR spectroscopy, 1H NMR spectroscopy, elemental analysis, and scanning electron microscope (SEM. It was found that the AM/AA/NSFM copolymer exhibited higher viscosity than the AM/AA copolymer at 500 s−1 shear rate (18.6 mPa·s versus 8.7 mPa·s. It was also found that AM/AA/NSFM could achieve up to 43.7% viscosity retention rate at 95°C. Mobility control results indicated that AM/AA/NSFM could establish much higher resistance factor (RF and residual resistance factor (RRF than AM/AA under the same conditions (RF: 16.52 versus 12.17, RRF: 3.63 versus 2.59. At last, the enhanced oil recovery (EOR of AM/AA/NSFM was up to 20.10% by core flooding experiments at 65°C.

  19. Recovery Swaps

    OpenAIRE

    Berd, Arthur M.

    2010-01-01

    We derive an arbitrage free relationship between recovery swap rates, digital default swap spreads and conventional CDS spreads, and argue that the fair forward recovery rate used in recovery swaps must contain a convexity premium over the expected recovery value.

  20. Assessment of Impact and Recovery Needs in Communities Affected by the Elk River Chemical Spill, West Virginia, April 2014.

    Science.gov (United States)

    Burrer, Sherry L; Fechter-Leggett, Ethan; Bayleyegn, Tesfaye; Mark-Carew, Miguella; Thomas, Carrie; Bixler, Danae; Noe, Rebecca S; Hsu, Joy; Haddy, Loretta; Wolkin, Amy

    In January 2014, 4-methylcyclohexanemethanol spilled into the Elk River near Charleston, West Virginia, contaminating the water supply for about 120 000 households. The West Virginia American Water Company (WVAWC) issued a "do not use" water order for 9 counties. After the order was lifted (10 days after the spill), the communities' use of public water systems, information sources, alternative sources of water, and perceived impact of the spill on households were unclear to public health officials. To assist in recovery efforts, the West Virginia Bureau for Public Health and the Centers for Disease Control and Prevention conducted a Community Assessment for Public Health Emergency Response (CASPER). We used the CASPER 2-stage cluster sampling design to select a representative sample of households to interview, and we conducted interviews in 171 households in April 2014. We used a weighted cluster analysis to generate population estimates in the sampling frame. Before the spill, 74.4% of households did not have a 3-day alternative water supply for each household member and pet. Although 83.6% of households obtained an alternative water source within 1 day of the "do not use" order, 37.4% of households reportedly used WVAWC water for any purpose. Nearly 3 months after the spill, 36.1% of households believed that their WVAWC water was safe, and 33.5% reported using their household water for drinking. CASPER results identified the need to focus on basic public health messaging and household preparedness efforts. Recommendations included (1) encouraging households to maintain a 3-day emergency water supply, (2) identifying additional alternative sources of water for future emergencies, and (3) increasing community education to address ongoing concerns about water.

  1. Optimising energy recovery and use of chemicals, resources and materials in modern waste-to-energy plants.

    Science.gov (United States)

    De Greef, J; Villani, K; Goethals, J; Van Belle, H; Van Caneghem, J; Vandecasteele, C

    2013-11-01

    Due to ongoing developments in the EU waste policy, Waste-to-Energy (WtE) plants are to be optimized beyond current acceptance levels. In this paper, a non-exhaustive overview of advanced technical improvements is presented and illustrated with facts and figures from state-of-the-art combustion plants for municipal solid waste (MSW). Some of the data included originate from regular WtE plant operation - before and after optimisation - as well as from defined plant-scale research. Aspects of energy efficiency and (re-)use of chemicals, resources and materials are discussed and support, in light of best available techniques (BAT), the idea that WtE plant performance still can be improved significantly, without direct need for expensive techniques, tools or re-design. In first instance, diagnostic skills and a thorough understanding of processes and operations allow for reclaiming the silent optimisation potential.

  2. A New Graphical Technique for Energy Efficient Design of Heat Recovery System in Chemical/Refining Industries

    Directory of Open Access Journals (Sweden)

    Dina Ahmed Kamel

    2016-12-01

    Full Text Available Chemical processes are energy intensive industries; the majority of energy consumed in industrial processes is mainly used for heating and cooling requirements. This results in increasing the interest in obtaining the optimum design of the heat exchanger networks to reduce the energy consumption and face the growing energy crises. Most of the published literature over the last fifty years promotes the process integration technology as a main part of the process system engineering science. Graphical Pinch Analysis method normally includes two key steps, firstly obtaining the energy targets which include the minimum energy required for the HEN design, then designing the heat exchanger network (HEN. This paper introduces a new graphical approach for the design of new heat exchanger networks (HENs based on pinch analysis rules. The HEN is represented on a simple graph, where the cold stream temperatures are plotted on the X-axis while the driving forces for each exchanger are plotted on the Y-axis. This graphical technique can describe the energy analysis problems in term of temperature driving force inside the heat exchanger, which is an important factor in the design process as the differences in these driving forces are involved in calculating the area of heat exchangers, and consequently affecting the cost.

  3. Optimising energy recovery and use of chemicals, resources and materials in modern waste-to-energy plants

    Energy Technology Data Exchange (ETDEWEB)

    De Greef, J.; Villani, K.; Goethals, J.; Van Belle, H. [Keppel Seghers, Center of Excellence, Hoofd 1, B-2830 Willebroek (Belgium); Van Caneghem, J., E-mail: jo.vancaneghem@cit.kuleuven.be [University of Leuven, Department of Chemical Engineering, ProcESS (Process Engineering for Sustainable Systems) Division, Willem De Croylaan 46, 3001 Leuven (Belgium); Group T Leuven Engineering College, Association of the University of Leuven, Andreas Vesaliusstraat 13, B-3000 Leuven (Belgium); Vandecasteele, C. [University of Leuven, Department of Chemical Engineering, ProcESS (Process Engineering for Sustainable Systems) Division, Willem De Croylaan 46, 3001 Leuven (Belgium)

    2013-11-15

    Highlights: • WtE plants are to be optimized beyond current acceptance levels. • Emission and consumption data before and after 5 technical improvements are discussed. • Plant performance can be increased without introduction of new techniques or re-design. • Diagnostic skills and a thorough understanding of processes and operation are essential. - Abstract: Due to ongoing developments in the EU waste policy, Waste-to-Energy (WtE) plants are to be optimized beyond current acceptance levels. In this paper, a non-exhaustive overview of advanced technical improvements is presented and illustrated with facts and figures from state-of-the-art combustion plants for municipal solid waste (MSW). Some of the data included originate from regular WtE plant operation – before and after optimisation – as well as from defined plant-scale research. Aspects of energy efficiency and (re-)use of chemicals, resources and materials are discussed and support, in light of best available techniques (BAT), the idea that WtE plant performance still can be improved significantly, without direct need for expensive techniques, tools or re-design. In first instance, diagnostic skills and a thorough understanding of processes and operations allow for reclaiming the silent optimisation potential.

  4. Periphyton changes over 20 years of chemical recovery of Lake Orta, Italy: differential response to perturbation of littoral and pelagic communities

    Directory of Open Access Journals (Sweden)

    Giuseppe MORABITO

    2011-08-01

    Full Text Available Lake Orta, a large Italian subalpine lake, has a long history of industrial pollution by acid, ammonia, and metals. A whole-lake liming treatment in 1989-1990 led to a gradual increase in pH (from 4.4 to 7 and a concomitant decline in ammonia (from 2.5 to 0.05 mg L-1 and metal concentrations (e.g., copper: from 35 to 3 μg L-1. In this study, we examine the response of the littoral zone, in terms of chemistry and periphyton assemblages, to contamination and recovery of Lake Orta. We compare these findings with a long-term data set of chemistry and phytoplankton collected in the pelagic zone. We sampled periphyton at two sites from the liming period (1989 through 2010 when the lake approached chemical equilibrium. Chemical variables collected in the littoral zone near the periphyton samples followed the same temporal trends observed in the pelagic zone. Chlorophytes, the dominant algae in the preliming period, progressively waned after the calcium carbonate addition. Diatom importance gradually increased to reach up to 80% of the total biovolume in the most recent years. There was a clear shift in the diatom taxonomic composition over the study period. Acidophilous Pinnularia subcapitata var. hilseana and metal-tolerant Achnanthes minutissima were dominant before liming. With the progressive increase in pH and decline in metal concentrations, there was successively the dominance of Fragilaria nanoides (formerly identified as Synedra tenera and Cymbella microcephala in the transition period and of circumneutral Navicula cryptocephala, N. radiosa, and Synedra ulna in the most recent period. Pelagic diatoms were more affected than benthic diatoms by the industrial pollution and their recovery after the liming intervention was slower. Whereas present periphyton diatom assemblages are similar to those observed in nearby unpolluted Lake Mergozzo, pelagic assemblages are still in transition from severe disturbance towards characteristics reported before

  5. Experimental design and optimization of leaching process for recovery of valuable chemical elements (U, La, V, Mo, Yb and Th) from low-grade uranium ore

    Energy Technology Data Exchange (ETDEWEB)

    Zakrzewska-Koltuniewicz, Grażyna, E-mail: g.zakrzewska@ichtj.waw.pl [Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw (Poland); Herdzik-Koniecko, Irena [Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw (Poland); Cojocaru, Corneliu [Institute of Macromolecular Chemistry “Petru Poni”, Aleea Grigore Ghica Voda, nr. 41A, 700487 Iasi (Romania); Chajduk, Ewelina [Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw (Poland)

    2014-06-30

    Highlights: • The experimental design for optimization of leaching process of uranium from low-grade ores was applied. • Multi-objective optimization method based on desirability approach was employed. • The recovery of associated metals like vanadium, molybdenum and lanthanides was considered. • The effects of factors were identified by 3-D surface plots. • The optimum condition for valuable metals: P = 5 bar, T = 120 °C and t = 90 min has been determined. - Abstract: The paper deals with experimental design and optimization of leaching process of uranium and associated metals from low-grade, Polish ores. The chemical elements of interest for extraction from the ore were U, La, V, Mo, Yb and Th. Sulphuric acid has been used as leaching reagent. Based on the design of experiments the second-order regression models have been constructed to approximate the leaching efficiency of elements. The graphical illustrations using 3-D surface plots have been employed in order to identify the main, quadratic and interaction effects of the factors. The multi-objective optimization method based on desirability approach has been applied in this study. The optimum condition have been determined as P = 5 bar, T = 120 °C and t = 90 min. Under these optimal conditions, the overall extraction performance is 81.43% (for U), 64.24% (for La), 98.38% (for V), 43.69% (for Yb) and 76.89% (for Mo) and 97.00% (for Th)

  6. Chemical Method to Improve CO{sub 2} Flooding Sweep Efficiency for Oil Recovery Using SPI-CO{sub 2} Gels

    Energy Technology Data Exchange (ETDEWEB)

    Burns, Lyle D.

    2009-04-14

    hydrocarbon combustion for energy, chemical and fertilizer plants. For example, coal fired power plants emit large amounts of CO{sub 2} in order to produce electrical energy. Carbon dioxide sequestration is gaining attention as concerns mount over possible global climate change caused by rising emissions of greenhouse gases. Removing the CO{sub 2} from the energy generation process would make these plants more environmentally friendly. In addition, CO{sub 2} flooding is an attractive means to enhance oil and natural gas recovery. Capture and use of the CO{sub 2} from these plants for recycling into CO{sub 2} flooding of marginal reservoirs provides a “dual use” opportunity prior to final CO{sub 2} sequestration in the depleted reservoir. Under the right pressure, temperature and oil composition conditions, CO{sub 2} can act as a solvent, cleaning oil trapped in the microscopic pores of the reservoir rock. This miscible process greatly increases the recovery of crude oil from a reservoir compared to recovery normally seen by waterflooding. An Enhanced Oil Recovery (EOR) project that uses an industrial source of CO{sub 2} that otherwise would be vented to the atmosphere has the added environmental benefit of sequestering the greenhouse gas.

  7. Use of Several Plant Materials and Chemicals to inhibit Soil Urease Activity and Increase Nitrogen Recovery Rate of Urea by Plant

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Effects of residues of 9 plants, lemon eucalyptus (Eucalyptus citriodora Hook., P1), robust eucalyptus (E. robusta Smith, P2), Nepal camphortree (Cinnamomum glanduliferum (Wall.) Nees, P3), tea (Camellia sinensis (Linn.) O. Ktze. f., P4), oleander (Nerium indicum Mill, P5), rape (Brassica campestris L., P6),Chinese tallow tree (Sapium sebiferum L., P7), tung (Vernicia fordii (Hemsl.), P8), and croton (Croton tiglium L., P9), 7 chemicals, boric acid (C1), borax (C2), oxalic acid (C3), sodium oxalite (C4), sodium dihydrogen phosphate (C6), sodium silicate (C7) and sodium citrate (C8), and a natural organic substance,humic acid (C5), on urease activity of a neutral purple soil and recovery of urea nitrogen by maize were studied through incubation and pot experiments. Hydroquinone (HQ) was applied as the reference inhibitor. After incubation at 37 ℃ for 24 h, 7 inhibitors with higher ability to inhibit urease activity were selected and then incubated for 14 days at 25 ℃. Results of the incubation experiments showed that soil urease activity was greatly inhibited by them, and the inhibition effect followed an order of P2>P4>C3>C2>P3>C1>HQ>P1.The 7 selected materials reduced the accumulative amounts of N released from urea and the maximum urease activity by 11.7%~28.4% and 26.7%~39.7%, respectively, and postponed the N release peak by 2~4 days in the incubation period of 14 days under constant temperature, as compared to the control (no inhibitor).In the pot experiment with the 7 materials at two levels of addition, low (L) and high (H), the C1 (H), C3(H), C1 (L), P4 (L) and C2 (L) treatments could significantly increase the dry weights of the aboveground parts and the total biomass of the maize plants and the apparent recovery rate of urea-N was increased by 6.3%~32.4% as compared to the control (no hibitor).

  8. Steam sauna and mother roasting in Lao PDR: practices and chemical constituents of essential oils of plant species used in postpartum recovery

    Directory of Open Access Journals (Sweden)

    de Boer Hugo J

    2011-12-01

    Full Text Available Abstract Background Fundamental in traditional postpartum recovery in Lao PDR is the use of hotbeds, mother roasting, steam sauna and steam baths. During these treatments medicinal plants play a crucial role, but little has been published about how the treatments are carried out precisely, which species are used, the medicinal properties of these species, and the medicinal efficacy of their chemical constituents. Methods Sixty-five interviews, in 15 rural villages, with women of 4 different ethnic groups were conducted to survey confinement rituals, and postpartum plant use and salience. Essential oils from the main species used were extracted using steam distillation and the main chemical constituents characterized using gas chromatography-mass spectrometry (GC-MS. Results A total of 10 different species were used by three or more of the ethnic groups included in this study. All species were used in steam sauna and bath, but only 3 species were used in hotbed and mother roasting. Essential oils of Amomum villosum, Amomum microcarpum and Blumea balsamifera were found to contain significant amounts of the following terpenes: β-pinene, camphor, bornyl acetate, borneol, linalool, D-limonene, fenchone, terpinen-4-ol and α-terpinene. Conclusions Many of these terpenes have documented antimicrobial and analgesic properties, and some have also synergistic interactions with other terpenes. The mode of application in hotbed and mother roasting differs from the documented mechanisms of action of these terpenes. Plants in these two practices are likely to serve mainly hygienic purposes, by segregating the mother from infection sources such as beds, mats, stools, cloth and towels. Steam sauna medicinal plant use through inhalation of essential oils vapors can possibly have medicinal efficacy, but is unlikely to alleviate the ailments commonly encountered during postpartum convalescence. Steam sauna medicinal plant use through dermal condensation of

  9. 煤基化工CO2回收多联产系统探讨%Coal-based Chemical CO2 Recovery Polygeneration System to Explore

    Institute of Scientific and Technical Information of China (English)

    巴淑丽; 王民民

    2012-01-01

    随着社会的进步,能源利用在人类社会发展中的作用越来越重要。但是,当前存在着资源的开发,能源的利用以及环境的保护等各方面的相互独立。煤基化工一动力多联产系统实现了能源利用,化工生产以及环境保护的有机结合,从而为能源的可持续发展与利用提供一条新的道路。介绍了多联产系统,阐述了二氧化碳的分离;同时,从介绍了不同分离方式下,二氧化碳的能量的利用。最后,介绍了基于二氧化碳回收的多联产系统,通过系统能耗分析和二氧化碳的产出发现,回收二氧化碳的多联产系统的二氧化碳产量最少。%With the progress of society, the role of energy use in the development of human society is more and more important. However, the current existence of mutually independent resource development, the use of energy, and the protection of the environment and other aspects. Coal-based chemical industry the-dynamic polygeneration system to achieve a combination of energy use, chemical production and environmental protection, so as to provide a new path for sustainable energy development and utilization. The polygeneration system on the separation of carbon dioxide; same time, from the different separation energy use, carbon dioxide. Finally, the polygeneration system based on carbon dioxide recovery polygeneration system of recycling carbon dioxide carbon dioxide production at least through the system energy analysis and carbon dioxide output.

  10. Seasonal changes in chemical and mineralogical composition of sewage sludge incineration residues and their potential for metallic elements and valuable components recovery

    Science.gov (United States)

    Kasina, Monika; Kowalski, Piotr R.; Michalik, Marek

    2017-04-01

    Increasing energy needs, the implementation of the circular economy principles and rising environmental awareness caused that waste management is becoming a major social and economic issue. The EU Member States have committed to a significant reduction in the amount of waste produced and landfilled and to use their inherent energy and raw materials potential. One of the most reasonable option to fulfil these commitments is waste incineration. The aim of the waste incineration is to reduce their volume and toxicity by disinfection and detoxification at high temperatures. Thermal process and reduction of volume allows the recovery of minerals and metallic elements from residues as well as the energy production (waste-to-energy strategy) during incineration. As a result of waste incineration a variety of solid residues (bottom ash, fly ash, air pollution control residues) and technological waste (gas waste, wastewater) are produced. The goal of this study is to characterize fly ash and air pollution control (APC) residues formed as a result of municipal sewage sludge incineration in terms of their chemical and mineral composition and their extractive potential. Residues were sampled quarterly to study their seasonal changes in composition. The fly ash was a Si-P-C-Fe-Al dominated material, whereas the APC residues composition was dominated by Na-rich soluble phases. The removal of soluble phase ( 98% of the material) from the APC residues by dissolution in deionised water caused significant mass reduction and concentration of non-soluble elements. The main mineral phases in fly ash were quartz, hematite, Fe-PO4, whitlockite and feldspar, while in APC thenardite, and in lower amount calcite, apatite and quartz were present. The chemical composition of fly ash was practically invariable in different seasons, but significant differences were observed in APC residues. The lowest concentrations of all elements and the highest TOC content were measured in the samples

  11. Modification of chemical and physical factors in steamflood to increase heavy oil recovery. Annual report, October 1, 1990--September 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C.

    1992-04-01

    This report covers work performed in the area related to the physicochemical factors for the improvement of the oil recovery efficiency in steamfloods. In this context, three general areas are studied: (1) The understanding of vapor-liquid flow in porous media, whether the flow is internal (boiling), external (steam injection) or countercurrent (as in vertical heat pipes). (2) The effect of reservoir heterogeneity, particularly as it regards fractured systems and long and narrow reservoirs (which are typical of oil reservoirs). (3) The flow properties of additives for the improvement of recovery efficiency, in particular the properties of foams.

  12. The role of the chemist/chemical engineer for the trouble-free operation of thermal plants with heat recovery steam generators

    Energy Technology Data Exchange (ETDEWEB)

    Addison, David; Weir, Judy [Thermal Chemistry Limited, Horsham Downs, Hamilton (New Zealand)

    2012-06-15

    The importance of a chemist/chemical engineer for the reliable and efficient operation of combined cycle gas turbine (CCGT) plants is discussed along with the key differences between routine and strategic chemistry and how these potentially impact on CCGT plant operation. Potential risks and issues with the full outsourcing of cycle chemistry services for a CCGT plant to chemical service providers are outlined. Also discussed are the interactions between a chemist/chemical engineer and plant management, operations, engineering and maintenance personnel. Proposed chemist/chemical engineer staffing levels for a number of hypothetical CCGT plants are also discussed. (orig.)

  13. Leak detection technologies for oil and gas pipelines; Tecnologias para deteccao e localizacao de vazamento em dutos de oleo e ou gas

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Julio R. [MTT Aselco Automacao Ltda., Sao Paulo, SP (Brazil)

    2005-07-01

    Two concepts are available for leak detection in oil and/or gas pipelines: On-line leak detection system and off-line leak detection technique. The off-line leak detection technique is, usually, portable and does net configure a 'system'. This technique includes hydro-test, acoustic emission of high frequency, tracer of chemical substances, ultrasonic flow meter (UT), thermographic infra-red mapping, electromagnetic offset registration, etc. Since most of those methods requests stop of the system or depend on direct and detailed inspection of the whole monitored piping they are limited to the off-line inspection. In the current days there are only two technologies applied to detect and locate leaks on-line: The acoustic Leak Detection System and the modeling of computerized simulation also called as RTM (Real Time Modeling), RTTM or Mass Balance. There are still other techniques in the market, as acoustic emission, pressure analysis (PPA) beyond other rough techniques, without good results. Even some of these techniques are working without success, they are still used to accomplish with government standards. (author)

  14. Backup & Recovery

    CERN Document Server

    Preston, W

    2009-01-01

    Packed with practical, freely available backup and recovery solutions for Unix, Linux, Windows, and Mac OS X systems -- as well as various databases -- this new guide is a complete overhaul of Unix Backup & Recovery by the same author, now revised and expanded with over 75% new material.

  15. Recovery Online

    Science.gov (United States)

    Clark, John R.

    2007-01-01

    Since the founding of Alcoholics Anonymous (AA) in 1935, programs offering opportunity for recovery from alcoholism and other addictions have undergone vast changes. The Internet has created nearly limitless opportunities for recovering people and those seeking recovery to find both meetings and places where they can gather virtually and discuss…

  16. Effect of side-stream phosphorus recovery on biological phosphorus removal performance investigated by chemical and microbial analyses in a novel BNR-IC process.

    Science.gov (United States)

    Zou, H M; Lu, X W; Li, T

    2014-01-01

    The aim of this study was to assess the effect of side-stream ratio (SSR) on performance of phosphorus (P) removal and recovery in a novel process linking biological nutrients removal (BNR) and induced crystallization (IC). Results showed that P removal efficiency was significantly enhanced when given an appropriate SSR, resulting in effluent P concentrations decreasing from 0.75 to 0.39 mg/L with an increase of SSR from 0 to 35%, where a maximum of 7.19 mg/L P recovery amount was obtained at 35% of SSR. Increasing the SSR can favor the P recovery, while an excessively high SSR (more than 35%) would have a negative effect on the subsequent biological P removal in the BNR-IC system. Polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) analysis showed that in total, 11 DGGE bands of highest species richness were visually detected and significant changes in microbial community structure were found, with SSR variations ranging from 0 to 55%. Moreover, an increase in SSR can cause an increase in microbial community biodiversity; where microbial populations correspond to the 11 bands, they were generally classified into five different phyla or classes (Beta-, Gamma-, and Deltaproteobacteria, as well as Clostridia and Flavobacteria) based on the evolutionary tree analysis.

  17. Modification of chemical and physical factors in steamflood in increase heavy oil recovery. Annual report, October 1, 1994--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Y.C

    1996-10-01

    The objectives of this contract is to carry our fundamental research in heavy oil recovery in the following areas: displacement and flow properties of fluids involving phase change (condensation-evaporation) in porous media; flow properties of mobility control fluids (such as foam); and the effect of reservoir heterogeneity on oil recovery. The specific projects are motivated by and address the need to improve heavy oil recovery from typical reservoirs as well as less conventional fractured reservoirs. This report covers the work performed in these three areas in the past year. In the area of vapor-liquid flow we present a theoretical and numerical study of steam injection in a pore network. We characterize the displacement in terms of an effective mobility ratio and heat transfer parameters. Displacement patterns axe identified in the parameter space. In another study we discuss the problem of steam injection in fractured systems using visualization with micromodels. The interplay of drainage, imbibition and bubble growth is visualized. Conclusions are reached regarding the potential for steamflooding fractured systems. A third study focuses on the development of a pore-network model for foam formation and propagation in porous media. This model, for the first time, accounts for the fundamental mechanisms of foam propagation at the microscale and leads to the determination of various parameters that are currently treated empirically. The effect of viscous forces in displacements in heterogeneous media is described in two separate studies, one involving an extension of percolation theory to account for viscous effects, and another discussing the effect of geometry in general displacement processes.

  18. Ruthenium recovery from acetic acid industrial effluent using chemically stable and high-performance polyethylenimine-coated polysulfone-Escherichia coli biomass composite fibers

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sok [Division of Environmental Science and Ecological Engineering, College of Life Sciences and Biotechnology, Korea University, Seoul 02841 (Korea, Republic of); Division of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonbuk 54896 (Korea, Republic of); Choi, Yoon-E, E-mail: yechoi@korea.ac.kr [Division of Environmental Science and Ecological Engineering, College of Life Sciences and Biotechnology, Korea University, Seoul 02841 (Korea, Republic of); Yun, Yeoung-Sang, E-mail: ysyun@jbnu.ac.kr [Division of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonbuk 54896 (Korea, Republic of); Department of Bioprocess Engineering, Chonbuk National University, Jeonbuk 54896 (Korea, Republic of)

    2016-08-05

    Highlights: • The PEI-PSBF was fabricated and used for Ru recovery from industrial effluent. • PEI-PSBF was not swollen nor dissolved in the effluent. • PEI-PSBF showed superior sorption capacity to commercial resins. • Thin fiber type PEI-PSBF could be successfully applied in flow-through column. - Abstract: Recovery of precious metal ions from waste effluents is of high concern. In general, ruthenium (Ru) is used in the Cativa process as promoter for carbonylation catalyst and discharged into acetic acid effluent. In the present work, we have designed and developed polyethylenimine-coated polysulfone-bacterial biomass composite fiber (PEI-PSBF) to recover Ru from industrial effluent. The sorbent was manufactured by electrostatic attachment of polyethylenimine (PEI) to the surface of polysulfone-biomass composite fiber (PSBF), which was prepared through spinning of the mixture of polysulfone and Escherichia coli biomass in N,N-dimethylformamide (DMF) into water. Developed PEI-PSBF was highly stable in the acetic acid effluent. The maximum sorption capacity of the developed sorbent PEI-PSBF, coated with PEI (with M.W. of 75,000), was 121.28 ± 13.15 mg/g, which was much higher than those of ion exchange resins, TP214, Amberjet 4200, and M500. The PEI-PSBF could be successfully applied in the flow-through column system, showing 120 beds of breakthrough volume.

  19. Disaster Debris Recovery Database - Recovery

    Data.gov (United States)

    U.S. Environmental Protection Agency — The US EPA Region 5 Disaster Debris Recovery Database includes public datasets of over 6,000 composting facilities, demolition contractors, transfer stations,...

  20. Computational non-chemically equilibrium model on the current zero simulation in a model N2 circuit breaker under the free recovery condition

    Science.gov (United States)

    Sun, Hao; Tanaka, Yasunori; Tomita, Kentaro; Wu, Yi; Rong, Mingzhe; Uesugi, Yoshihiko; Ishijima, Tatsuo

    2016-02-01

    A non-chemically equilibrium (non-CE) model was established to investigate the N2 arc plasma in the decaying phase during the arc interruption, and was validated by comparison with the experimental results based on laser Thomson scattering. Unlike the conventional model assuming the local thermodynamic equilibrium (LTE), in this non-CE model, the magneto-hydro-dynamics (MHD) method was coupled with the reaction kinetics to obtain the time-dependent species compositions and properties. The current calculation took into account five species in hot gas and 22 chemical reactions in total. The time-dependent species compositions of hot N2 were derived from the mass conservation equation for each species, considering the effect of the convection, diffusion and the chemical reaction. The influence of the non-CE compositions on the arc decaying behavior was realized by updating the thermodynamic and transport properties at each iterative step. The results indicate that the non-CE model can result in the departure of the arc decaying behavior from the LTE model, because it alters the time evolution of the species composition and consequently changes the thermodynamic and transport properties. At the edge of the arc, the time evolutions of the species are dominant by both the diffusion and the chemical reactions while at the center of the arc they are mainly influenced by the chemical reactions. Generally, the non-CE effect can lead to the delay of all the particles’ variations, particularly the electron decay, so that the arc interruption performance will be reduced compared with that in the LTE model.

  1. Recovery Spirituality

    Directory of Open Access Journals (Sweden)

    Ernest Kurtz

    2015-01-01

    Full Text Available There is growing interest in Alcoholics Anonymous (A.A. and other secular, spiritual, and religious frameworks of long-term addiction recovery. The present paper explores the varieties of spiritual experience within A.A., with particular reference to the growth of a wing of recovery spirituality promoted within A.A. It is suggested that the essence of secular spirituality is reflected in the experience of beyond (horizontal and vertical transcendence and between (connection and mutuality and in six facets of spirituality (Release, Gratitude, Humility, Tolerance, Forgiveness, and a Sense of Being-at-home shared across religious, spiritual, and secular pathways of addiction recovery. The growing varieties of A.A. spirituality (spanning the “Christianizers” and “Seculizers” reflect A.A.’s adaptation to the larger diversification of religious experience and the growing secularization of spirituality across the cultural contexts within which A.A. is nested.

  2. Preference of multi-walled carbon nanotube (MWCNT) to single-walled carbon nanotube (SWCNT) and activated carbon for preparing silica nanohybrid pickering emulsion for chemical enhanced oil recovery (C-EOR)

    Science.gov (United States)

    AfzaliTabar, M.; Alaei, M.; Ranjineh Khojasteh, R.; Motiee, F.; Rashidi, A. M.

    2017-01-01

    The aim of this research was to determine the best nano hybrid that can be used as a Pickering emulsion Chemical Enhanced Oil Recovery (C-EOR). Therefore, we have prepared different carbon structures nano hybrids with SiO2 nano particles with different weight percent using sol-gel method. The as-prepared nano materials were characterized with X-Ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FE-SEM) and Thermal Gravimetric Analysis (TGA). Pickering emulsions of these nanohybrids were prepared at pH=7 in ambient temperature and with distilled water. Stability of the mentioned Pickering emulsions was controlled for one month. Emulsion phase morphology was investigated using optical microscopic imaging. Evaluation results demonstrated that the best sample is the 70% MWCNT/SiO2 nanohybrid. Stability of the selected nanohybrid (70% MWCNT/SiO2 nanohybrid) was investigated by alteration of salinity, pH and temperature. Results showed that the mentioned Pickering emulsion has very good stability at 0.1%, 1% salinity, moderate and high temperature (25 °C and 90 °C) and neutral and alkaline pH (7, 10) that is suitable for the oil reservoirs conditions. The effect of the related nano fluid on the wettability of carbonate rock was investigated by measuring the contact angle and interfacial tension. Results show that the nanofluid could significantly change the wettability of the carbonate rock from oil wet to water wet and can decrease the interfacial tension. Therefore, the 70% MWCNT/SiO2 nanohybrid Pickering emulsion can be used for Chemical Enhanced Oil Recovery (C-EOR).

  3. Spontaneous Recovery

    Science.gov (United States)

    Rescorla, Robert A.

    2004-01-01

    Spontaneous recovery from extinction is one of the most basic phenomena of Pavlovian conditioning. Although it can be studied by using a variety of designs, some procedures are better than others for identifying the involvement of underlying learning processes. A wide range of different learning mechanisms has been suggested as being engaged by…

  4. 废旧PET的化学回收方法研究进展%Progress in Chemical Recovery of Post PET and its Applications

    Institute of Scientific and Technical Information of China (English)

    陈佳宇; 廖正福; 刘觉靖; 黄思勰

    2014-01-01

    The chemical methods of recycling post PET,such as alcoholysis,aminolysis,hydrolysis and pyrolysis, etc. ,were reviewed in this article. By using these chemical methods,post PET can depolymerize into monomers or oligomers,which may act as raw materials for preparation unsaturated polyester resin,polyurethane,etc. . The main goal of this work is to provide reference for comprehensive utilization of post PET.%PET综合性能良好,应用广泛,但难以生物降解,随着排入自然界的废旧PET日益增多,对其进行回收利用已迫在眉睫。回收方法包括物理方法、化学方法、物理化学方法等,其中,化学回收方法将PET解聚成单体或低聚体,是实现废旧 PET 循环利用最有前途的途径之一,包括醇解法、水解法等。本文重点对废旧PET的化学回收方法研究现状及新进展进行了综述,旨在为PET的工业回收利用提供参考。

  5. Enhanced Etching, Surface Damage Recovery, and Submicron Patterning of Hybrid Perovskites using a Chemically Gas-Assisted Focused-Ion Beam for Subwavelength Grating Photonic Applications

    KAUST Repository

    Alias, Mohd Sharizal

    2015-12-22

    The high optical gain and absorption of organic–inorganic hybrid perovskites have attracted attention for photonic device applications. However, owing to the sensitivity of organic moieties to solvents and temperature, device processing is challenging, particularly for patterning. Here, we report the direct patterning of perovskites using chemically gas-assisted focused-ion beam (GAFIB) etching with XeF2 and I2 precursors. We demonstrate etching enhancement in addition to controllability and marginal surface damage compared to focused-ion beam (FIB) etching without precursors. Utilizing the GAFIB etching, we fabricated a uniform and periodic submicron perovskite subwavelength grating (SWG) absorber with broadband absorption and nanoscale precision. Our results demonstrate the use of FIB as a submicron patterning tool and a means of providing surface treatment (after FIB patterning to minimize optical loss) for perovskite photonic nanostructures. The SWG absorber can be patterned on perovskite solar cells to enhance the device efficiency through increasing light trapping and absorption.

  6. Enhanced Etching, Surface Damage Recovery, and Submicron Patterning of Hybrid Perovskites using a Chemically Gas-Assisted Focused-Ion Beam for Subwavelength Grating Photonic Applications.

    Science.gov (United States)

    Alias, Mohd S; Yang, Yang; Ng, Tien K; Dursun, Ibrahim; Shi, Dong; Saidaminov, Makhsud I; Priante, Davide; Bakr, Osman M; Ooi, Boon S

    2016-01-01

    The high optical gain and absorption of organic-inorganic hybrid perovskites have attracted attention for photonic device applications. However, owing to the sensitivity of organic moieties to solvents and temperature, device processing is challenging, particularly for patterning. Here, we report the direct patterning of perovskites using chemically gas-assisted focused-ion beam (GAFIB) etching with XeF2 and I2 precursors. We demonstrate etching enhancement in addition to controllability and marginal surface damage compared to focused-ion beam (FIB) etching without precursors. Utilizing the GAFIB etching, we fabricated a uniform and periodic submicron perovskite subwavelength grating (SWG) absorber with broadband absorption and nanoscale precision. Our results demonstrate the use of FIB as a submicron patterning tool and a means of providing surface treatment (after FIB patterning to minimize optical loss) for perovskite photonic nanostructures. The SWG absorber can be patterned on perovskite solar cells to enhance the device efficiency through increasing light trapping and absorption.

  7. SirX: a selective inversion recovery experiment on X-nuclei for the determination of the exchange rate of slow chemical exchanges between two sites.

    Science.gov (United States)

    Xie, Xiulan; Bönisch, Friedrich

    2015-10-01

    Nuclear magnetic resonance spectroscopy has proven to be powerful for the study of dynamic processes. A new pulse sequence, SirX, is designed to provide boundary conditions that simplify the McConnell equations. Both an initial rate approximation and a whole curve fitting to the time course of magnetization can be used to calculate the exchange rate. These methods were used to study the exchange kinetics of N,N-dimethylacetamide. As compared with the well-established exchange spectroscopy suitable to studies of slow exchange, SirX has the advantage of being less time consuming and capable of providing more reliable kinetic data. Furthermore, by setting the observation on X-nuclei with larger chemical shift dispersion as compared with an observation on (1)H resonance, SirX extends the upper limit of a reliable determination of exchange rates.

  8. Experimental design and optimization of leaching process for recovery of valuable chemical elements (U, La, V, Mo, Yb and Th) from low-grade uranium ore.

    Science.gov (United States)

    Zakrzewska-Koltuniewicz, Grażyna; Herdzik-Koniecko, Irena; Cojocaru, Corneliu; Chajduk, Ewelina

    2014-06-30

    The paper deals with experimental design and optimization of leaching process of uranium and associated metals from low-grade, Polish ores. The chemical elements of interest for extraction from the ore were U, La, V, Mo, Yb and Th. Sulphuric acid has been used as leaching reagent. Based on the design of experiments the second-order regression models have been constructed to approximate the leaching efficiency of elements. The graphical illustrations using 3-D surface plots have been employed in order to identify the main, quadratic and interaction effects of the factors. The multi-objective optimization method based on desirability approach has been applied in this study. The optimum condition have been determined as P=5 bar, T=120 °C and t=90 min. Under these optimal conditions, the overall extraction performance is 81.43% (for U), 64.24% (for La), 98.38% (for V), 43.69% (for Yb) and 76.89% (for Mo) and 97.00% (for Th).

  9. 浅谈化学废旧电池的回收和利用%Talking about the Recovery and Utilization of Chemical Waste Batteries

    Institute of Scientific and Technical Information of China (English)

    陆成禹

    2016-01-01

    本文简要介绍了锌锰干电池、镍镉蓄电池等几种电池类型,同时分析了废旧电池对环境、人体的危害,并详细介绍了化学废旧电池的回收处理技术,以便人们能够对上述两种电池及其他类电池加以妥善处理,避免其对环境以及人体造成污染与危害。%This article briefly describes the zinc-manganese batteries, nickel-cadmium batteries, such as several battery types, and analyzes the waste batteries on the environment, health hazards, and details of chemical waste battery recycling technology, so that people be able to both batteries and other types of batteries are properly handled, avoid pollution and harm to the envi-ronment and the human body.

  10. Evaluating and modeling the effects of surface sampling factors on the recovery of organic chemical attribution signatures using the accelerated diffusion sampler and solvent extraction

    Energy Technology Data Exchange (ETDEWEB)

    Mo, Kai-For; Heredia-Langner, Alejandro; Fraga, Carlos G.

    2017-03-01

    In this study, an experimental design matrix was created and executed in order to test the effects of various real-world factors on the ability of the (1) accelerated diffusion sampler with solid phase micro-extraction (ADS-SPME) and (2) solvent extraction to capture organic chemical attribution signatures (CAS) from dimethyl methylphosphonate (DMMP) spiked onto painted wall board (PWB) surfaces. The DMMP CAS organic impurities sampled by ADS-SPME and solvent extraction were analyzed by gas chromatography/mass spectrometry (GC/MS). The number of detected DMMP CAS impurities and their respective GC/MS peak areas were determined as a function of DMMP stock, DMMP spiked volume, exposure time, SPME sampling time, and ADS headspace pressure. Based on the statistical analysis of experimental results, several general conclusions are made: (1) ADS-SPME with vacuum (i.e., reduced pressure) increased the amount of detected CAS impurity, as measured by GC/MS peak area, by a factor of 1.7 to 1.9 for PWB under certain experimental conditions, (2) the amount of detected CAS impurity was most influenced by spiked volume, stock, and ADS headspace pressure, (3) the ADS had no measurable effect on the number of detected DMMP impurities, that is, the ADS (with and without reduced pressure) had no practical effect on the DMMP impurity profile collected from spiked PWB, and (4) solvent extraction out performed ADS-SPME in terms of consistently capturing all or most of the targeted DMMP impurities from spiked PWB.

  11. Evaluating and modeling the effects of surface sampling factors on the recovery of organic chemical attribution signatures using the accelerated diffusion sampler and solvent extraction.

    Science.gov (United States)

    Mo, Kai-For; Heredia-Langner, Alejandro; Fraga, Carlos G

    2017-03-01

    In this study, an experimental design matrix was created and executed to test the effects of various real-world factors on the ability of (1) the accelerated diffusion sampler with solid phase micro-extraction (ADS-SPME) and (2) solvent extraction to capture organic chemical attribution signatures (CAS) from dimethyl methylphosphonate (DMMP) spiked onto painted wall board (PWB) surfaces. The DMMP CAS organic impurities sampled by ADS-SPME and solvent extraction were analyzed by gas chromatography/mass spectrometry (GC/MS). The number of detected DMMP CAS impurities and their respective GC/MS peak areas were determined as a function of DMMP stock, DMMP spiked volume, exposure time, SPME sampling time, and ADS headspace pressure. Based on the statistical analysis of experimental results, several general conclusions are made: (1) the amount of CAS impurity detected using ADS-SPME and GC/MS was most influenced by spiked volume, stock, and ADS headspace pressure, (2) reduced ADS headspace pressure increased the amount of detected CAS impurity, as measured by GC/MS peak area, by up to a factor of 1.7-1.9 compared to ADS at ambient headspace pressure, (3) the ADS had no measurable effect on the number of detected DMMP impurities, that is, ADS (with and without reduced pressure) had no practical effect on the DMMP impurity profile collected from spiked PWB, and (4) solvent extraction out performed ADS-SPME in terms of consistently capturing all or most of the targeted DMMP impurities from spiked PWB.

  12. The Role of Attrition and Solids Recovery in a Chemical Looping Combustion Process; Effet de l'attrition et de la recuperation des particules dans le procede de combustion en boucle chimique

    Energy Technology Data Exchange (ETDEWEB)

    Kramp, M.; Thon, A.; Hartge, E.U.; Heinrich, S.; Werther, J. [Institute of Solids Process Engineering and Particle Technology, Hamburg University of Technology, 21071 Hamburg (Germany)

    2011-03-15

    In the present work, the steady-state behavior of a Chemical Looping Combustion process of interconnected fluidized bed reactors is simulated. The simulations have been carried out in two different scales, 50 kWth and 100 MWth. Attrition model derived from small scale laboratory experiments has been employed for the prediction of the process behavior in terms of attrition and Oxygen Carrier loss. Information on Oxygen Carrier characteristics and reaction kinetics were taken from literature. Realistic circulation mass flows of Oxygen Carrier particles are obtained and Oxygen Carrier losses are quantified. The large scale process looses significantly more Oxygen Carrier than the small scale process based on the same amount of thermal energy produced. Incomplete conversion in the air reactor could be identified as a critical point. Another issue is the fuel gas bypassing the Oxygen Carrier particles through bubbles in the large scale process which leads to lowered fuel conversions. The simulations indicate that a similar performance of a pilot scale and a large scale process is not guaranteed due to the scale-up effect on fluid dynamics. Furthermore, the simulations allow an assessment of the influence of the quality of the solids recovery system on the Oxygen Carrier loss. The distribution of the losses between possible origins is investigated and different changes in the solids recovery system are discussed regarding their potential to decrease the Oxygen Carrier loss. For example, the addition of a second-stage cyclone after the air reactor of the large scale process reduces the Oxygen Carrier loss significantly. (authors)

  13. Isopropyl alcohol recovery by heteroazeotropic batch distillation

    OpenAIRE

    Van Baelen, Guy; Vreysen, Steven; Gerbaud, Vincent; Rodriguez-Donis, Ivonne; Geens, Jeroen; Janssens, Bart

    2010-01-01

    Solvent recovery is becoming a major issue in the pharmaceutical and specialty chemical industries. Solvent recovery by conventional batch distillation is limited by the frequent presence of azeotropes in the used solvent mixtures. Most distillation processes for the separation of azeotropic or difficult zeotropic mixtures involve the addition of an entrainer (homogeneous and heterogeneous azeotropic distillation or extractive distillation). In this study the recovery of IPA (isopropyl alc...

  14. Plant hydrocarbon recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Dzadzic, P.M.; Price, M.C.; Shih, C.J.; Weil, T.A.

    1982-01-26

    A process for production and recovery of hydrocarbons from hydrocarbon-containing whole plants in a form suitable for use as chemical feedstocks or as hydrocarbon energy sources which process comprises: (A) pulverizing by grinding or chopping hydrocarbon-containing whole plants selected from the group consisting of euphorbiaceae, apocynaceae, asclepiadaceae, compositae, cactaceae and pinaceae families to a suitable particle size, (B) drying and preheating said particles in a reducing atmosphere under positive pressure (C) passing said particles through a thermal conversion zone containing a reducing atmosphere and with a residence time of 1 second to about 30 minutes at a temperature within the range of from about 200* C. To about 1000* C., (D) separately recovering the condensable vapors as liquids and the noncondensable gases in a condition suitable for use as chemical feedstocks or as hydrocarbon fuels.

  15. Page 1 CHEMICALLY ENHANCEO RECOVERY OF BCARBONATE ...

    African Journals Online (AJOL)

    hence the derivation of sodium bicarbonate from lakesalt was finished by bubbling CO, through solutions of derived salt mixtures heated to 90°C. Also acetic acid and hydrochloric acid were ... the reaction was delivered through a glass.

  16. Study on chemical steam flood to enhance recovery ratio of ninth block of Gudong oilfield%孤东油田九区稠油油藏化学蒸汽驱提高采收率技术

    Institute of Scientific and Technical Information of China (English)

    刘广友

    2012-01-01

    With steam injection times and production time of steamed well increasing, the problem that production declines quickly and serious steam channels become very common, and recovery enhancing of this kind of reservoir become more difficult after the viscous oil reservoir undergoes steam soak and steam flood. Thermal chemical flood is the foam system that is acceded to steam and thermal water which is injected to reservoir, distinguishing feature of foam system that "water shutoff and not oil shutoff" and " low shutoff and more high shutoff" can change flow direction of medium, repress steam overlapping and steam channeling and supply producing energy, so that it can get the performance of enhancing recovery and economic benefit. According to numerical simulation and production reality of reservoir, injection and production parameters are designed; equally steam injection rate after foam flooding is 3.9 t/h, production/injection ratio is 1.3, quality fraction of foam is 0.5% , length of slug flow is injection 30 d and stop 60 d, and steam is injected in all process. The result indicates that, compared with old unregulated well, the ninth block can produce more llyears and increment of productive capacity is 1. 15×104 t after foam steam injection is designed, meanwhile, the recovery ratio of block can be enhanced by 14. 63%.%稠油油藏在经历了蒸汽吞吐和蒸汽驱开发后,随着注蒸汽井吞吐次数和开采时间的增加,产量递减快、汽窜严重等现象成为开发中后期面临的共性问题,同时也严重制约了该类油藏采收率的大幅提高.化学蒸汽驱在注入蒸汽或热水的同时,加入泡沫体系,利用泡沫体系“堵水不堵油”和“堵低更堵高”的特点,改变注入介质的流动方向,抑制蒸汽超覆和汽窜,补充地层能量,可达到提高稠油油藏采收率和经济效益的目的.根据数值模拟研究和开发实际,设计了孤东油田九区化学蒸汽驱注采参数:泡沫

  17. Combustion for Enhanced Recovery of Light Oil at Medium Pressures

    NARCIS (Netherlands)

    Khoshnevis Gargar, N.

    2014-01-01

    Using conventional production methods, recovery percentages from oil reservoirs range from 5% for difficult oil to 50% for light oil in highly permeable homogeneous reservoirs. To increase the oil recovery factor, enhanced oil recovery (EOR) methods are used. We distinguish EOR that uses chemical

  18. Combustion for Enhanced Recovery of Light Oil at Medium Pressures

    NARCIS (Netherlands)

    Khoshnevis Gargar, N.

    2014-01-01

    Using conventional production methods, recovery percentages from oil reservoirs range from 5% for difficult oil to 50% for light oil in highly permeable homogeneous reservoirs. To increase the oil recovery factor, enhanced oil recovery (EOR) methods are used. We distinguish EOR that uses chemical me

  19. Combustion for Enhanced Recovery of Light Oil at Medium Pressures

    NARCIS (Netherlands)

    Khoshnevis Gargar, N.

    2014-01-01

    Using conventional production methods, recovery percentages from oil reservoirs range from 5% for difficult oil to 50% for light oil in highly permeable homogeneous reservoirs. To increase the oil recovery factor, enhanced oil recovery (EOR) methods are used. We distinguish EOR that uses chemical me

  20. Ecological Recovery Potential of Freshwater Organisms

    DEFF Research Database (Denmark)

    Gergs, André; Classen, Silke; Strauss, Tido

    2016-01-01

    serve as a decision criterion in the environmental risk assessment of chemical stressors remains to be evaluated. For a generic consideration of recovery in the risk assessment of chemicals, we reviewed case studies of natural and artificial aquatic systems and evaluate five aspects that might cause...

  1. Combustion for Enhanced Recovery of Light Oil at Medium Pressures

    OpenAIRE

    Khoshnevis Gargar, N.

    2014-01-01

    Using conventional production methods, recovery percentages from oil reservoirs range from 5% for difficult oil to 50% for light oil in highly permeable homogeneous reservoirs. To increase the oil recovery factor, enhanced oil recovery (EOR) methods are used. We distinguish EOR that uses chemical methods, (partially) miscible methods and thermal methods. Air injection is categorized as a thermal recovery method as it leads to combustion and therefore high temperature in the reservoir. However...

  2. strong water sensitivity; heavy oil reservoir; thermal recovery; thermal compound chemical flooding; electron microscope analysisA study on a thermal compound chemical method for improving development efficiency of heavy-oil reservoirs with strong sensiti%热复合化学方法改善极强敏感性稠油油藏开发效果机理

    Institute of Scientific and Technical Information of China (English)

    曹嫣镔; 于田田; 林吉生; 刘冬青; 何绍群; 王全; 夏道宏

    2013-01-01

    Heavy-oil reservoirs with extremely strong water sensitivity in the Shengli oilfield are mainly distributed in the Jinjia oilfield and their reserves amount to more than 20 million tons. In addition, the thermal recovery effect only by steam injection seems poor and it is difficult to effectively produce these reserves because the water sensitivity index for this kind of reservoirs exceeds 0. 9. In view of the above contradiction, a thermal compound chemical method research was carried out, in which real cores from the Jinjia oilfield were used to evaluate different displacement manners based on thermal compound chemical flooding, such as the vapor + high-temperature antiswelling agent, steam + high-performance oil displacement agent, and steam + high-performance oil displacement a-gent + high-temperature condensation agent. Composition changes of clay minerals, clay distributions in pore throats and radius distributions of pore throats were measured by means of X diffraction, scanning electron microscope, cast thin section and mercury-injection in order to explore principle mechanisms of the enhanced oil recovery with the thermal compound chemical method under high-temperature conditions. The results showed that the thermal compound chemical displacement manner with the steam + high-temperature oil displacement agent + high-temperature condensation agent can promote the transformation of montmorillonite to illite and the dissolution of part kaolinite at the same time, which can greatly improve pore-throat flow channels of reservoirs to form large "hot-wormholes" that remarkably increase the permeability and flooding displacement efficiency of heavy-oil reservoirs with strong water sensitivity.%胜利油田极强水敏性稠油油藏主要分布在金家油田,储量在2 000×104 t以上,该类油藏水敏指数在0.9以上,单纯注蒸汽热采开发效果差,无法实现有效动用.笔者针对以上矛盾,开展了热复合化学方法开采技术研究.利用

  3. Bioelectrochemical metal recovery from wastewater: a review.

    Science.gov (United States)

    Wang, Heming; Ren, Zhiyong Jason

    2014-12-01

    Metal contaminated wastewater posts great health and environmental concerns, but it also provides opportunities for precious metal recovery, which may potentially make treatment processes more cost-effective and sustainable. Conventional metal recovery technologies include physical, chemical and biological methods, but they are generally energy and chemical intensive. The recent development of bioelectrochemical technology provides a new approach for efficient metal recovery, because it offers a flexible platform for both oxidation and reduction reaction oriented processes. While dozens of recent studies demonstrated the feasibility of the bioelectrochemical metal recovery concept, the mechanisms have been different and confusing. This study provides a review that summarizes and discusses the different fundamental mechanisms of metal conversion, with the aim of facilitating the scientific understanding and technology development. While the general approach of bioelectrochemical metal recovery is using metals as the electron acceptor in the cathode chamber and organic waste as the electron donor in the anode chamber, there are so far four mechanisms that have been reported: (1) direct metal recovery using abiotic cathodes; (2) metal recovery using abiotic cathodes supplemented by external power sources; (3) metal conversion using bio-cathodes; and (4) metal conversion using bio-cathodes supplemented by external power sources.

  4. Recovery from schizophrenia and the recovery model.

    Science.gov (United States)

    Warner, Richard

    2009-07-01

    The recovery model refers to subjective experiences of optimism, empowerment and interpersonal support, and to a focus on collaborative treatment approaches, finding productive roles for user/consumers, peer support and reducing stigma. The model is influencing service development around the world. This review will assess whether optimism about outcome from serious mental illness and other tenets of the recovery model are borne out by recent research. Remission of symptoms has been precisely defined, but the definition of 'recovery' is a more diffuse concept that includes such factors as being productive and functioning independently. Recent research and a large, earlier body of data suggest that optimism about outcome from schizophrenia is justified. A substantial proportion of people with the illness will recover completely and many more will regain good social functioning. Outcome is better for people in the developing world. Mortality for people with schizophrenia is increasing but is lower in the developing world. Working appears to help people recover from schizophrenia, and recent advances in vocational rehabilitation have been shown to be effective in countries with differing economies and labor markets. A growing body of research supports the concept that empowerment is an important component of the recovery process. Key tenets of the recovery model - optimism about recovery from schizophrenia, the importance of access to employment and the value of empowerment of user/consumers in the recovery process - are supported by the scientific research. Attempts to reduce the internalized stigma of mental illness should enhance the recovery process.

  5. RECOVERY OF POLYHYDROXYALKANOATES (PHAs FROM BACTERIAL CELLS USING ENZYMATIC PROCESS

    Directory of Open Access Journals (Sweden)

    S. Marsudi

    2012-02-01

    Full Text Available Polyhydroxyalkanoates (PHAs are intracellular material accumulated by several bacteria. Commercial production of PHAs faces the issue of high production cost especially substrate cost and recovery/separation cost. An alternative to reduce the production cost is to use enzyme and or chemical to recover PHAs from bacterial cells. Recovery of PHAs from bacterial cells was done using enzyme, chemical, and a mixture of enzyme and chemical. Enzyme (s and or chemical(s were added into culture broth to disrupt cells after adjusting pH and temperature of the culture broth. Treatment by adding enzyme or chemical only into culture broth showed a low level of PHAs recovered from bacterial cells. Treatment by adding a mixture of enzymes and chemicals showed the best result among 22 examined combinations, i.e. a mixture of EDTA, lisozyme, papain enzyme, and SDS. This combination gave a PHA recovery of 65 % w/w.

  6. EPA Recovery Mapper

    Data.gov (United States)

    U.S. Environmental Protection Agency — The EPA Recovery Mapper is an Internet interactive mapping application that allows users to discover information about every American Recovery and Reinvestment Act...

  7. Youth in Recovery

    Science.gov (United States)

    de Miranda, John; Williams, Greg

    2011-01-01

    Young people are entering long-term recovery probably in greater numbers than ever before. A key word here is "probably" because we know precious little about the phenomenon of young people who recover from alcohol and drug addition. This article is a preliminary exploration of youth in recovery. It reviews several types of recovery support…

  8. Recovery from mental illness

    DEFF Research Database (Denmark)

    Petersen, Kirsten Schultz; Friis, Vivi Soegaard; Haxholm, Birthe Lodahl;

    2015-01-01

    Mental health services strive to implement a recovery-oriented approach to rehabilitation. Little is known about service users' perception of the recovery approach. The aim is to explore the service user's perspectives on facilitators and barriers associated with recovery. Twelve residents living...

  9. Battleground Energy Recovery Project

    Energy Technology Data Exchange (ETDEWEB)

    Bullock, Daniel [USDOE Gulf Coast Clean Energy Application Center, Woodlands, TX (United States)

    2011-12-31

    In October 2009, the project partners began a 36-month effort to develop an innovative, commercial-scale demonstration project incorporating state-of-the-art waste heat recovery technology at Clean Harbors, Inc., a large hazardous waste incinerator site located in Deer Park, Texas. With financial support provided by the U.S. Department of Energy, the Battleground Energy Recovery Project was launched to advance waste heat recovery solutions into the hazardous waste incineration market, an area that has seen little adoption of heat recovery in the United States. The goal of the project was to accelerate the use of energy-efficient, waste heat recovery technology as an alternative means to produce steam for industrial processes. The project had three main engineering and business objectives: Prove Feasibility of Waste Heat Recovery Technology at a Hazardous Waste Incinerator Complex; Provide Low-cost Steam to a Major Polypropylene Plant Using Waste Heat; and Create a Showcase Waste Heat Recovery Demonstration Project.

  10. Inherently safe in situ uranium recovery

    Science.gov (United States)

    Krumhansl, James L; Brady, Patrick V

    2014-04-29

    An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

  11. Recovery of volatile bioproducts by pervaporation

    Energy Technology Data Exchange (ETDEWEB)

    Boeddeker, K.W.

    1994-01-01

    Organophilic prevaporation is linkened to steam distillation in the recovery of volatile bioproducts of fermentation or plant origin. Potential applications are to biosynthetic chemicals (e.g., EtOH; BuOH), aroma compounds (e.g., gamma-decalactone; 6-pentyl-2-pyrone), and essential oils. Unlike steam distillation, pervaporation may be combined with an active fermenter. (orig.)

  12. Carbon dioxide recovery: large scale design trends

    Energy Technology Data Exchange (ETDEWEB)

    Mariz, C. L.

    1998-07-01

    Carbon dioxide recovery from flue gas streams for use in enhanced oil recovery were examined, focusing on key design and operating issues and trends that appear promising in reducing plant investment and operating costs associated with this source of carbon dioxide. The emphasis was on conventional processes using chemical solvents, such as the Fluor Daniel ECONAMINE FG{sup S}M process. Developments in new tower packings and solvents and their potential impact on plant and operating costs were reviewed, along with the effects on these costs of the flue gas source. Sample operating and capital recovery cost data is provided for a 1,000 tonne/day plant. This size plant would be one large enough to support an enhanced oil recovery project. 11 refs., 4 figs.

  13. Fundamental research in the chemistry of industrial oil recovery processes

    Energy Technology Data Exchange (ETDEWEB)

    Emanuel, N.M.

    1984-01-01

    The causes of low oil recovery from formations and physiochemical methods for increasing oil recovery are analyzed. A survey of results from research in this field at the chemical institutes of the Academy of Sciences of the USSR is given. The primary concepts of interformation combustion are examined together with the possibilities for using this method to control the combustion processes and enhance oil recovery as well as to optimize combustion processes.

  14. Recovery and money management.

    Science.gov (United States)

    Rowe, Michael; Serowik, Kristin L; Ablondi, Karen; Wilber, Charles; Rosen, Marc I

    2013-06-01

    Social recovery and external money management are important approaches in contemporary mental health care, but little research has been done on the relationship between the two or on application of recovery principles to money management for people at risk of being assigned a representative payee or conservator. Out of 49 total qualitative interviews, 25 transcripts with persons receiving Social Security insurance or Social Security disability insurance who were at risk of being assigned a money manager were analyzed to assess the presence of recognized recovery themes. The recovery principles of self-direction and responsibility were strong themes in participant comments related to money management. Money management interventions should incorporate peoples' recovery-related motivations to acquire financial management skills as a means to direct and assume responsibility for one's finances. Staff involved in money management should receive training to support client's recovery-related goals. (PsycINFO Database Record (c) 2013 APA, all rights reserved).

  15. Beyond enhanced recovery?

    DEFF Research Database (Denmark)

    Jørgensen, Christoffer C; Kehlet, Henrik

    2014-01-01

    We read with great interest the special article by Smart and Daniels discussing several important topics of perioperative care, especially regarding lack of consensus on the definition of "postoperative recovery", and need for further understanding of the pathogenic mechanisms. However, we disagr...... that a "new, clearly defined standard of what "recovery" actually is", demands "a look beyond enhanced recovery"(1) for several reasons. This article is protected by copyright. All rights reserved....

  16. 峡江化工厂节能余热回收发电供车间温度调控的应用研究%Energy-Saving Waste Heat Recovery Power Generation for Temperature Control in Workshop of Xiajiang Chemical Plant

    Institute of Scientific and Technical Information of China (English)

    王振华

    2013-01-01

    Heat energy in acid making process at 1 000 ℃ can be recovered. Waste heat recovery is a crucial energy-efficient technology based on requirements about indoor temperature control in preparation workshop of chemical plant. The recovery boiler is utilized for heat recovery. Then waste heat enters into converter, heat exchanger, economizer and superheater to form superheated steam of 450 ℃ and 3.82 MPa, finally into the turbine for generating. The design result shows the waste heat recovery reach 6000 kW/h, which solves the power required for temperature control in workshop, and saves 3.563 million yuan per year for electricity purchasing, with direct economic benefits of 6.15 million yuan per year.%根据化工厂制配车间建筑体室内温度控制的要求,结合硫磺制酸混合燃烧生成1000℃左右的高温炉气热能实施余热回收设计,采取中压锅炉回收热量,经转化器、热交换器、省煤器、过热器产生温度450℃、压力3.82 MPa的中温中压过热蒸汽,进入汽轮发电机组发电。设计结果表明,余热回收热量6000 kW/h,解决了车间建筑温控所需电能,节省外购电费356.3万元/a,获得直接经济效益615万元/a。

  17. 化学沉淀法回收污泥中氮磷的影响因素研究%Impact Factors on Recovery of Nitrogen and Phosphorus by Chemical Precipitation in Sludge

    Institute of Scientific and Technical Information of China (English)

    员建; 苑宏英; 陈轶; 池勇志

    2011-01-01

    污水处理厂污泥上清液中富集着较高浓度溶解性的氮磷,将此部分氮磷形成磷酸盐沉淀(如磷酸氨镁、磷酸钙、磷酸铝等)加以回收利用,受到各种因素的影响.文章以正交试验得出的影响因素为基础,深入研究了pH、初始PO43--p的浓度、Mg/P和反应时间对某污水厂污泥上清液中磷酸氨镁沉淀法回收氮磷的影响.结果表明:pH是影响污泥上清液中氮磷回收的关键因素,最佳pH范围9.5~10.5,控制pH=10.0,初始PO43--P浓度在78.20 mg/L以上,无外加镁剂,搅拌时间为10 min,PO43--P和NH4+-N回收率分别可达到90%和20%.%Sludge supernatant of wastewater treatment plant contains a great quantity of soluble nitrogen and phosphorus.Many parameters affected on the recovery and reuse process of phosphorus precipitation including magnesium ammonium phosphate, calcium phosphate and aluminum phosphate. Based on the results of orthogonal experiment, effect of pH, initial PO43--P concentration, Mg/P and reaction time on recovery of nitrogen and phosphorus for magnesium ammonium phosphate precipitation in sludge supematant were studied. Results showed that pH was the key parameter, under the optimal condition of nitrogen and phosphorus recovery for precipitation in sludge supematant as pH 9.5~10.5, initial PO43--P concentrations over 78.20 mg/L, no plus magnesium and 10 min of reaction time, the recovery rate of NH4+-N and PO43--P was 90% and 20% respectively.

  18. Physical-chemical bases of the recovery of surface active materials from aqueous solutions and waste water. Fiziko-Khimicheskie osnovy izvlecheniya poverkhnostno-aktivnykh veshchestv izvodnykh rastvorov i stochnykh vod

    Energy Technology Data Exchange (ETDEWEB)

    Koganovskii, A.M.; Klimenko, N.A.

    1978-01-01

    Contemporary data are given on the adsorption of surfactants on adsorbents of various chemical makeup, on the effect of the structure of their solutions, and the presence of strong electrolytes. An examination is made of the connection between the chemical structure of surfactants, their state in solution, and the structure of the adsorption layers. Data are presented for the first time on the joint adsorption of components from solubilized systems and the products resulting from the interaction between surfactants and dissolved dyes. Physico-chemical substantiation is offered for the absorption technology of removing surfactants and concomitant organic matter from industrial waste. Fundamental technological systems are presented for the sorption purification of sewage polluted by surfactants, and the conditions for their most effective utilization are substantiated. The book is intended for specialists engaged in the physical chemistry of surface phenomena as well as for investigators and planning personnel who are developing the technology of purifying industrial sewage. 81 figures, 53 tables.

  19. "Sizing Up" Codependency Recovery.

    Science.gov (United States)

    Messner, Beth A.

    1996-01-01

    Analyzes codependency related, self-help literature with a dramatistic lens to explore M. Beattie's bibliotherapeutic portrayal of codependency and codependency recovery. Depicts Beattie's "stylistic medicine" for codependency recovery as a three-step, rebirth experience: (1) recognize the codependent pollution within; (2) engage in…

  20. "Sizing Up" Codependency Recovery.

    Science.gov (United States)

    Messner, Beth A.

    1996-01-01

    Analyzes codependency related, self-help literature with a dramatistic lens to explore M. Beattie's bibliotherapeutic portrayal of codependency and codependency recovery. Depicts Beattie's "stylistic medicine" for codependency recovery as a three-step, rebirth experience: (1) recognize the codependent pollution within; (2) engage in…

  1. Chemical Emergencies

    Science.gov (United States)

    When a hazardous chemical has been released, it may harm people's health. Chemical releases can be unintentional, as in the case of an ... the case of a terrorist attack with a chemical weapon. Some hazardous chemicals have been developed by ...

  2. Biotechnology in petroleum recovery. The microbial EOR

    Energy Technology Data Exchange (ETDEWEB)

    Sen, Ramkrishna [Department of Biotechnology, Indian Institute of Technology (IIT), Kharagpur, West Bengal 721302 (India)

    2008-12-15

    Biotechnology has played a significant role in enhancing crude oil recovery from the depleted oil reservoirs to solve stagnant petroleum production, after a three-stage recovery process employing mechanical, physical and chemical methods. Biotechnologically enhanced oil recovery processes, known as microbial enhanced oil recovery (MEOR), involve stimulating indigenous reservoir microbes or injecting specially selected consortia of natural bacteria into the reservoir to produce specific metabolic events that lead to improved oil recovery. This also involves flooding with oil recovery agents produced ex situ by industrial or pilot scale fermentation. This paper essentially reviews the operating mechanisms and the progress made in enhanced oil recovery through the use of microbes and their metabolic products. Improvement in oil recovery by injecting solvents and gases or by energizing the reservoir microflora to produce them in situ for carbonate rock dissolution and reservoir re-pressurization has been enunciated. The role of biosurfactants in oil mobilization through emulsification and that of biopolymers for selective plugging of oil-depleted zones and for biofilm formation have been delineated. The spoil sport played by sulfate-reducing bacteria (SRB) in MEOR has also been briefly reviewed. The importance of mathematical models used in predicting the applicability of an MEOR strategy and the microbial growth and transport has been qualitatively discussed. The results of some laboratory studies and worldwide field trials applying ex situ and in situ MEOR technologies were compiled and interpreted. However, the potential of the MEOR technologies has not been fully realized due to poor yield of the useful microbial metabolic products, growth inhibition by accumulated toxic metabolites and longer time of incubation. A complete evaluation and assessment of MEOR from an engineering standpoint based on economics, applicability and performance is required to further

  3. Domestic wastewater heat recovery

    OpenAIRE

    Veijola, T.

    2017-01-01

    The aim of this thesis is to study and explain the purpose and the function of drain water heat exchangers. The thesis goes over theory behind heat transfer and heat exchangers and presents the general solutions of domestic drain water heat recovery systems. Systems gone over in detail are the different general shower drain water heat recovery systems. Another part of the thesis is a case study of an actual shower drain water heat recovery system of a Finnish household. The purpose of th...

  4. Isolation and recovery of microbial polyhydroxyalkanoates

    Directory of Open Access Journals (Sweden)

    2011-07-01

    Full Text Available The deleterious environmental impacts caused by plastic wastes have attracted worldwide concern. The biobased and biodegradable polyhydroxyalkanoate (PHA appears to be one of the potential candidates to replace some conventional plastics. However, high production cost of PHAs has limited their market penetration. The major cost absorbing factors are the upstream fermentation processes and the downstream PHA recovery technologies. The latter significantly affects the overall process economics. Various recovery technologies have been proposed and studied in small scales in the laboratory as well as in industrial scales. These include solvent extraction, chemical digestion, enzymatic treatment and mechanical disruption, supercritical fluid disruption, flotation techniques, use of gamma irradiation and aqueous two-phase system. This paper reviews all the recovery methods known to date and compares their efficiency and the quality of the resulting PHA. Some of the large-scale production of PHA and the strategies employed to reduce the production cost are also discussed.

  5. Recent motor functional recovery after acellular nerve allograft by chemical extraction%化学去细胞神经同种异体移植后近期运动功能的恢复

    Institute of Scientific and Technical Information of China (English)

    衷鸿宾; 侯树勋; 徐莹

    2004-01-01

    目的:研究去细胞同种异体神经移植修复大型哺乳类动物粗大和长段周围神经缺损的效果.方法:15只犬分成去细胞神经同种异体移植组6只、自体神经移植组6只、新鲜神经同种异体移植组3只.右侧坐骨神经主干造成5.0 cm长缺损,分别以上述3种神经移植物桥接修复.术后6个月进行步态分析.结果:同种异体移植组和自体神经移植组功能恢复一般情况相似,正常组、同种异体移植组及自体神经移植组犬距小腿关节角度平均极大值分别为59.0.,58.0.和61.9.,平均极小值分别为16.4.,7.6.和8.4..新鲜神经同种异体移植组无任何恢复;同种异体移植组和自体神经移植组的右后肢运动及步态周期非常相似,距小腿关节跖屈及背伸肌群的肌力均有一定程度的恢复,但不及正常犬.结论:化学去细胞神经同种异体移植修复犬坐骨神经长段缺损,在术后6个月近期运动功能恢复与自体神经移植相似.%OBJECTIVE: To study the effect of acellular nerve allograft on therestoration of the defects in thick and long segment of peripheral nerve in bigmammalia.METHODS: Fifteen canines were grouped into acellular nerve allograftinggroup(ANG group) with 6 canines, autografting group(AG group) with 6canines, and fresh nerve allografting group(FNG group) with 3 canines. A5.0 cm defect was made in the right side of sciatic nerve in all animals andrepaired by above three nerve grafts respectively. A gait analysis was operatedat 6 months after operation.RESULTS: The general functional recoveries in ANG and AG groups weresimilar. The mean maximum value of angle of ankle joint in the canines ofcontrol, ANG, AG groups were 59.0°, 58.0°, and 61.9° respectively and themean minimum values were 16.4°, 7.6° and 8.4° respectively. There was norecovery in FNG group. The hindlimb movement and gait cycle of ANG andAG group were very similar and the myodynamic of flexor and extensormuscle had a

  6. Spatially Dispersed Employee Recovery

    DEFF Research Database (Denmark)

    Hvass, Kristian Anders; Torfadóttir, Embla

    2014-01-01

    Employee recovery addresses either employee well-being or management's practices in aiding employees in recovering themselves following a service failure. This paper surveys the cabin crew at a small, European, low-cost carrier and investigates employees' perceptions of management practices to aid...... personnel achieve service recovery. Employee recovery within service research often focuses on front-line employees that work in a fixed location, however a contribution to the field is made by investigating the recovery of spatially dispersed personnel, such as operational personnel in the transport sector......, who have a work place away from a fixed or central location and have minimal management contact. Results suggest that the support employees receive from management, such as recognition, information sharing, training, and strategic awareness are all important for spatially dispersed front...

  7. Recovery Action Mapping Tool

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Recovery Action Mapping Tool is a web map that allows users to visually interact with and query actions that were developed to recover species listed under the...

  8. Ecological recovery in ERA

    DEFF Research Database (Denmark)

    EFSA Scientific Committee (Scientific Committee); Topping, Christopher John

    2016-01-01

    recognises the importance of more integrated ERAs considering both the local and landscape scales, as well as the possible co-occurrence of multiple potential stressors that fall under the remit of EFSA, which are important when addressing ecological recovery. In this scientific opinion, the Scientific...... ecological recovery for any assessed products, and invasive alien species that are harmful for plant health. This framework proposes an integrative approach based on well-defined specific protection goals, scientific knowledge derived by means of experimentation, modelling and monitoring, and the selection...... Committee gathered scientific knowledge on the potential for the recovery of non-target organisms for the further development of ERA. Current EFSA guidance documents and opinions were reviewed on how ecological recovery is addressed in ERA schemes. In addition, this scientific opinion is based on expert...

  9. A Bumpy Recovery

    Institute of Scientific and Technical Information of China (English)

    CHEN FENGYING

    2010-01-01

    @@ The world economic situation has been extremely complicated in 2010. This year saw fluctuating market confidence,changing commodity prices, imbalanced economic recovery, diverse economic policies, lingering trade protectionism, and fierce currency battles.

  10. Recovery Audit Program

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Recovery Audit Programs mission is to identify and correct Medicare improper payments through the efficient detection and collection of overpayments made on...

  11. Disaster Debris Recovery Database

    Data.gov (United States)

    U.S. Environmental Protection Agency — The US EPA Region 5 Disaster Debris Recovery Database includes public datasets of over 3,500 composting facilities, demolition contractors, haulers, transfer...

  12. Silver recovery system data

    Energy Technology Data Exchange (ETDEWEB)

    Boulineau, B.

    1991-08-26

    In August of 1990 the Savannah River Site Photography Group began testing on a different type of silver recovery system. This paper describes the baseline study and the different phases of installation and testing of the system.

  13. FEMA Disaster Recovery Centers

    Data.gov (United States)

    Department of Homeland Security — This is a search site for FEMA's Disaster Recovery Centers (DRC). A DRC is a readily accessible facility or mobile office set up by FEMA where applicants may go for...

  14. Death Dilemma and Organism Recovery in Ecotoxicology.

    Science.gov (United States)

    Ashauer, Roman; O'Connor, Isabel; Hintermeister, Anita; Escher, Beate I

    2015-08-18

    Why do some individuals survive after exposure to chemicals while others die? Either, the tolerance threshold is distributed among the individuals in a population, and its exceedance leads to certain death, or all individuals share the same threshold above which death occurs stochastically. The previously published General Unified Threshold model of Survival (GUTS) established a mathematical relationship between the two assumptions. According to this model stochastic death would result in systematically faster compensation and damage repair mechanisms than individual tolerance. Thus, we face a circular conclusion dilemma because inference about the death mechanism is inherently linked to the speed of damage recovery. We provide empirical evidence that the stochastic death model consistently infers much faster toxicodynamic recovery than the individual tolerance model. Survival data can be explained by either, slower damage recovery and a wider individual tolerance distribution, or faster damage recovery paired with a narrow tolerance distribution. The toxicodynamic model parameters exhibited meaningful patterns in chemical space, which is why we suggest toxicodynamic model parameters as novel phenotypic anchors for in vitro to in vivo toxicity extrapolation. GUTS appears to be a promising refinement of traditional survival curve analysis and dose response models.

  15. Recovery of succinic acid from fermentation broth.

    Science.gov (United States)

    Kurzrock, Tanja; Weuster-Botz, Dirk

    2010-03-01

    Succinic acid is of high interest as bio-feedstock for the chemical industry. It is a precursor for a variety of many other chemicals, e.g. 1,4-butandiol, tetrahydrofuran, biodegradable polymers and fumaric acid. Besides optimized production strains and fermentation processes it is indispensable to develop cost-saving and energy-effective downstream processes to compete with the current petrochemical production process. Various methods such as precipitation, sorption and ion exchange, electrodialysis, and liquid-liquid extraction have been investigated for the recovery of succinic acid from fermentation broth and are reviewed critically here.

  16. Structural insights into the recovery of aldolase activity in N-acetylneuraminic acid lyase by replacement of the catalytically active lysine with γ-thialysine by using a chemical mutagenesis strategy.

    Science.gov (United States)

    Timms, Nicole; Windle, Claire L; Polyakova, Anna; Ault, James R; Trinh, Chi H; Pearson, Arwen R; Nelson, Adam; Berry, Alan

    2013-03-01

    Chemical modification has been used to introduce the unnatural amino acid γ-thialysine in place of the catalytically important Lys165 in the enzyme N-acetylneuraminic acid lyase (NAL). The Staphylococcus aureus nanA gene, encoding NAL, was cloned and expressed in E. coli. The protein, purified in high yield, has all the properties expected of a class I NAL. The S. aureus NAL which contains no natural cysteine residues was subjected to site-directed mutagenesis to introduce a cysteine in place of Lys165 in the enzyme active site. Subsequently chemical mutagenesis completely converted the cysteine into γ-thialysine through dehydroalanine (Dha) as demonstrated by ESI-MS. Initial kinetic characterisation showed that the protein containing γ-thialysine regained 17 % of the wild-type activity. To understand the reason for this lower activity, we solved X-ray crystal structures of the wild-type S. aureus NAL, both in the absence of, and in complex with, pyruvate. We also report the structures of the K165C variant, and the K165-γ-thialysine enzyme in the presence, or absence, of pyruvate. These structures reveal that γ-thialysine in NAL is an excellent structural mimic of lysine. Measurement of the pH-activity profile of the thialysine modified enzyme revealed that its pH optimum is shifted from 7.4 to 6.8. At its optimum pH, the thialysine-containing enzyme showed almost 30 % of the activity of the wild-type enzyme at its pH optimum. The lowered activity and altered pH profile of the unnatural amino acid-containing enzyme can be rationalised by imbalances of the ionisation states of residues within the active site when the pK(a) of the residue at position 165 is perturbed by replacement with γ-thialysine. The results reveal the utility of chemical mutagenesis for the modification of enzyme active sites and the exquisite sensitivity of catalysis to the local structural and electrostatic environment in NAL.

  17. Efficient Recovery of Nickel Salt Chemical Sludge Production Technology of Nickel Sulfate Process Analysis%高效回收镍盐化工污泥制取硫酸镍技术工艺分析

    Institute of Scientific and Technical Information of China (English)

    葛宝义

    2016-01-01

    The nickel salt chemical sludge nickel leaching conditions were analyzed and investigated on leaching solution pH value Shen iron and nickel plating were analyzed system;using washing process crude products hydroxide removal of nickel impurities to analyze the eventual adoption of acid dissolution and evaporative crystallization only way to nickel sulfate product.%对镍盐化工污泥中镍的浸出条件进行了分析和考察,对浸出液中沉铁和沉镍的pH值进行了系统的分析;采用水洗工艺对粗产品中氢氧化镍杂质的去除效果进行分析,最终采用加酸溶解和蒸发结晶的方式制取硫酸镍产物。

  18. The structure and behavior of salts in kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R.; Badoi, R.D.; Enestam, S. [Aabo Akademi Univ., Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The melting behavior in the salt system (Na,K)(CO{sub 3},SO{sub 4},S,Cl,OH) is investigated by laboratory methods to enhance and further develop a chemical model for salt mixtures with compositions relevant for recovery boilers. The model, based on both literature data and experimental work can be used as (a) submodel in models for the over-all chemistry in recovery boilers and to estimate (b) deposit formation on heat transfer surfaces (fouling), (c) the melting properties of the fly ash, and (d) the smelt bed in recovery boilers. Experimental techniques used are thermal analysis, high temperature microscopy` and scanning electron microscopy. The model is implemented in a global calculation model which can handle both gas phases and condensed phases in the recovery boiler. The model gives a detailed description of the chemical reactions involved in the fume and dust formation in different locations of the flue gas channel in the boiler. (orig.)

  19. Recovery from vestibular ototoxicity

    Science.gov (United States)

    Black, F. O.; Gianna-Poulin, C.; Pesznecker, S. C.

    2001-01-01

    OBJECTIVE: Determine whether subjects with documented vestibular ototoxicity recover vestibular function and, if so, investigate the recovery dynamics. STUDY DESIGN: Prospective and retrospective reviews and repeated measures. SETTING: Clinical research and technology center. SUBJECTS: Twenty-eight subjects who received vestibulotoxic medications were followed for at least 12 months after initial treatment. CONTROLS: Our subject sample was compared with a published database of normal individuals. INTERVENTIONS: All 28 subjects received systemically administered medications known to be ototoxic. The subjects' treating physicians controlled medication, dosage, and administration schedules. MAIN OUTCOME MEASURES: Tests of horizontal canal vestibulo-ocular function were performed. Subjects' auditory and vestibular symptoms were recorded. RESULTS: Eleven subjects (39%) showed changes in horizontal canal vestibulo-ocular gain constant (GC) and/or time constant (TC) consistent with vestibular ototoxicity. When tested 1 year after ototoxic drug administration, eight of the nine subjects who experienced ototoxic decrease in GC showed a recovery of GC to normal limits. Only one of the eight subjects who experienced ototoxic decrease in TC showed recovery of TC to within normal limits. Ototoxicity onset and recovery were independent of baseline vestibular function, and ototoxicity onset did not correlate with cumulative dose of ototoxic medication. There was no relationship between subjective symptoms and ototoxicity onset. CONCLUSIONS: Recovery of GC after vestibular ototoxicity is more commonly observed than recovery of TC. Because ototoxic changes developed and continued in an unpredictable time and manner in relation to ototoxic drug administration, we propose that once ototoxic changes in vestibulo-ocular reflex are detected, ototoxic medications should be discontinued as soon as possible.

  20. Ventilation with heat recovery

    DEFF Research Database (Denmark)

    Tommerup, Henrik M.; Svendsen, Svend

    2005-01-01

    This paper presents the experiences from the use of ventilation with heat recovery in several experimental single-family houses developed and built within the last four years to meet the new Danish energy requirements of 2005. Included are descriptions of the ventilation system components...... and the main functional demands as well as measurements of the thermal efficiency, electricity consumptions and building air tightness. The paper addresses the aspects of minimizing the heat loss from the duct system and the heat recovery unit (when placed in an unheated attic space) in order to obtain...

  1. Orimulsion containment and recovery

    Energy Technology Data Exchange (ETDEWEB)

    Sommerville, M. [Briggs Marine Environmental Services, Aberdeen (United Kingdom)

    1999-01-01

    This paper focuses on the need for examination of Orimulsion fuel and its spill behaviour in the light of the anticipated increase in consumption of this fuel which comprises bitumen dispersed in water with addition of a small amount of surfactant. The behaviour and fate of Orimulsion at sea, and observations from experimental and sea trials are examined. The identification of spill control techniques, spill detection, the predictive modeling of the spill and response, sub-surface plume measurement, and containment and deflection are considered. Recovery of the bitumen produced from an Orimulsion spill, combined containment and recovery, dispersed Orimulsion, and beach cleaning are addressed. The properties of Orimulsion are tabulated. (UK)

  2. Recovery in aluminium

    DEFF Research Database (Denmark)

    Gundlach, Carsten

    2006-01-01

    In the present thesis the development of a unique experimental method for volume characterisation of individual embedded crystallites down to a radius of 150 nm is presented. This method is applied to in-situ studies of recovery in aluminium. The method is an extension of 3DXRD microscopy, an X...... are represented as strings. To identify the strings a combination of a 5D connected component type algorithm and multi-peak fitting was found to be superior. The first use of the method was a study of recovery of a deformed aluminium alloy (AA1050). The aluminium alloy was deformed by cold rolling to a thickness...

  3. Ventilation with heat recovery

    DEFF Research Database (Denmark)

    Tommerup, Henrik M.; Svendsen, Svend

    2005-01-01

    and the main functional demands as well as measurements of the thermal efficiency, electricity consumptions and building air tightness. The paper addresses the aspects of minimizing the heat loss from the duct system and the heat recovery unit (when placed in an unheated attic space) in order to obtain......This paper presents the experiences from the use of ventilation with heat recovery in several experimental single-family houses developed and built within the last four years to meet the new Danish energy requirements of 2005. Included are descriptions of the ventilation system components...

  4. Epigenetics in Stroke Recovery

    Science.gov (United States)

    Kassis, Haifa; Shehadah, Amjad; Chopp, Michael; Zhang, Zheng Gang

    2017-01-01

    Abstract: While the death rate from stroke has continually decreased due to interventions in the hyperacute stage of the disease, long-term disability and institutionalization have become common sequelae in the aftermath of stroke. Therefore, identification of new molecular pathways that could be targeted to improve neurological recovery among survivors of stroke is crucial. Epigenetic mechanisms such as post-translational modifications of histone proteins and microRNAs have recently emerged as key regulators of the enhanced plasticity observed during repair processes after stroke. In this review, we highlight the recent advancements in the evolving field of epigenetics in stroke recovery. PMID:28264471

  5. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit o

  6. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit o

  7. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit

  8. CT imaging of enhanced oil recovery experiments

    Energy Technology Data Exchange (ETDEWEB)

    Gall, B.L.

    1992-12-01

    X-ray computerized tomography (Cr) has been used to study fluid distributions during chemical enhanced oil recovery experiments. Four CT-monitored corefloods were conducted, and oil saturation distributions were calculated at various stages of the experiments. Results suggested that this technique could add significant information toward interpretation and evaluation of surfactant/polymer EOR recovery methods. CT-monitored tracer tests provided information about flow properties in the core samples. Nonuniform fluid advance could be observed, even in core that appeared uniform by visual inspection. Porosity distribution maps based on CT density calculations also showed the presence of different porosity layers that affected fluid movement through the cores. Several types of CT-monitored corefloods were conducted. Comparisons were made for CT-monitored corefloods using chemical systems that were highly successful in reducing residual oil saturations in laboratory experiments and less successful systems. Changes were made in surfactant formulation and in concentration of the mobility control polymer. Use of a poor mobility control agent failed to move oil that was not initially displaced by the injected surfactant solution; even when a good'' surfactant system was used. Use of a less favorable surfactant system with adequate mobility control could produce as much oil as the use of a good surfactant system with inadequate mobility control. The role of mobility control, therefore, becomes a critical parameter for successful application of chemical EOR. Continuation of efforts to use CT imaging in connection with chemical EOR evaluations is recommended.

  9. CT imaging of enhanced oil recovery experiments

    Energy Technology Data Exchange (ETDEWEB)

    Gall, B.L.

    1992-12-01

    X-ray computerized tomography (Cr) has been used to study fluid distributions during chemical enhanced oil recovery experiments. Four CT-monitored corefloods were conducted, and oil saturation distributions were calculated at various stages of the experiments. Results suggested that this technique could add significant information toward interpretation and evaluation of surfactant/polymer EOR recovery methods. CT-monitored tracer tests provided information about flow properties in the core samples. Nonuniform fluid advance could be observed, even in core that appeared uniform by visual inspection. Porosity distribution maps based on CT density calculations also showed the presence of different porosity layers that affected fluid movement through the cores. Several types of CT-monitored corefloods were conducted. Comparisons were made for CT-monitored corefloods using chemical systems that were highly successful in reducing residual oil saturations in laboratory experiments and less successful systems. Changes were made in surfactant formulation and in concentration of the mobility control polymer. Use of a poor mobility control agent failed to move oil that was not initially displaced by the injected surfactant solution; even when a ``good`` surfactant system was used. Use of a less favorable surfactant system with adequate mobility control could produce as much oil as the use of a good surfactant system with inadequate mobility control. The role of mobility control, therefore, becomes a critical parameter for successful application of chemical EOR. Continuation of efforts to use CT imaging in connection with chemical EOR evaluations is recommended.

  10. A Bumpy Recovery

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The world economy crawls ahead amid risk and uncertainty The world economic situation has been extremely complicated in 2010. This year saw fluctuating market confidence,changing commodity prices, imbalanced economic recovery, diverse economic policies, lingering trade protectionism, and fierce currency battles.

  11. Recovery post ICU.

    Science.gov (United States)

    Jones, Christina

    2014-10-01

    Many ICU patients struggle to recovery following critical illness and may be left with physical, cognitive and psychological problems, which have a negative impact on their quality of life. Gross muscle mass loss and weakness can take some months to recover after the patients' Intensive Care Unit (ICU) discharge, in addition critical illness polyneuropathies can further complicate physical recovery. Psychological problems such as anxiety, depression and post traumatic stress disorder (PTSD) are common and have an negative impact on the patients' ability to engage in rehabilitation after ICU discharge. Finally cognitive deficit affecting memory can be a significant problem. The first step in helping patients to recover from such a devastating illness is to recognise those who have the greatest need and target interventions. Research now suggests that there are interventions that can accelerate physical recovery and reduce the incidence of psychological problems such as anxiety, depression and PTSD. Cognitive rehabilitation, however, is still in its infancy. This review will look at the research into patients' recovery and what can be done to improve this where needed.

  12. Sulfur recovery further improved

    Energy Technology Data Exchange (ETDEWEB)

    Borsboom, J.; Grinsven, M. van; Warners, A. van [Jacobs Nederland B.V., (Netherlands); Nisselrooy, P. van [Gastec N.V., (Netherlands)

    2002-04-01

    The original 100-year-old Claus process for producing sulfur from hydrogen sulfide in acid gas is described together with improvements which have been made over the years. The most recent modification, EUROCLAUS, achieves sulfur recoveries of 99-99.9 per cent. Five commercial units are being designed.

  13. Recovery of Interdependent Networks

    CERN Document Server

    Di Muro, M A; Stanley, H E; Havlin, S; Braunstein, L A

    2015-01-01

    Recent network research has focused on the cascading failures in a system of interdependent networks and the necessary preconditions for system collapse. An important question that has not been addressed is how to repair a failing system before it suffers total breakdown. Here we introduce a recovery strategy of nodes and develop an analytic and numerical framework for studying the concurrent failure and recovery of a system of interdependent networks based on an efficient and practically reasonable strategy. Our strategy consists of repairing a fraction of failed nodes, with probability of recovery $\\gamma$, that are neighbors of the largest connected component of each constituent network. We find that, for a given initial failure of a fraction $1-p$ of nodes, there is a critical probability of recovery above which the cascade is halted and the system fully restores to its initial state and below which the system abruptly collapses. As a consequence we find in the plane $\\gamma-p$ of the phase diagram three ...

  14. Cost Recovery Through Depreciation.

    Science.gov (United States)

    Forrester, Robert T.; Wesolowski, Leonard V.

    1983-01-01

    The approach of adopting depreciation rather than use allowance in order to recover more accurately the cost of college buildings and equipment used on federal projects is considered. It is suggested that depreciation will offer most colleges and universities a higher annual recovery rate, and an opportunity for better facilities planning. For…

  15. Recovery in the East

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    As robust as the economic recovery in East Asia has been in recent months,attention must now be turned to managing emerging risks challenging macroeconomic stability,said World Bank’s latest East Asia and Pacific Economic Update released on October 19.Edited excerpts follow

  16. Separation optimization for the recovery of phenyl ethyl alcohol.

    Science.gov (United States)

    Priddy, S A; Hanley, T R; Effler, W T

    1999-01-01

    Phenyl ethyl alcohol is a compound that occurs naturally in flower petals and in many common beverages, such as beer. Desire for the floral, rose-like notes imparted by phenyl ethyl alcohol has created a unique niche for this chemical in flavor and fragrance industries. Phenyl ethyl alcohol can be produced by Saccharomyces cerevisiae via bioconversion. Often this method of production results in extremely low yields, thus placing a great deal of importance on recovery and purification of the valuable metabolite. To determine the best method for recovering the chemical, a primary recovery step and a secondary recovery step were developed. The primary recovery step consisted of comparing dead-end filtration with crossflow ultrafiltration. Crossflow ultrafiltration was ultimately selected to filter the fermentation broth because of its high flow rates and low affinity for the product. The secondary recovery step consisted of a comparison of liquid- liquid extraction and hydrophobic resin recovery. The hydrophobic resin was selected because of its higher rate of recovery and a higher purity than the liquid-liquid extraction, the current practice of Brown-Forman.

  17. High efficiency shale oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Adams, D.C.

    1993-04-22

    The overall project objective is to demonstrate the high efficiency of the Adams Counter-Current shale oil recovery process. The efficiency will first be demonstrated on a small scale, in the current phase, after which the demonstration will be extended to the operation of a small pilot plant. Thus the immediate project objective is to obtain data on oil shale retorting operations in a small batch rotary kiln that will be representative of operations in the proposed continuous process pilot plant. Although an oil shale batch sample is sealed in the batch kiln from the start until the end of the run, the process conditions for the batch are the same as the conditions that an element of oil shale would encounter in a continuous process kiln. Similar chemical and physical conditions (heating, mixing, pyrolysis, oxidation) exist in both systems.The two most important data objectives in this phase of the project are to demonstrate (1) that the heat recovery projected for this project is reasonable and (2) that an oil shale kiln will run well and not plug up due to sticking and agglomeration. The following was completed this quarter. (1) Twelve pyrolysis runs were made on five different oil shales. All of the runs exhibited a complete absence of any plugging, tendency. Heat transfer for Green River oil shale in the rotary kiln was 84.6 Btu/hr/ft[sup 2]/[degrees]F, and this will provide for ample heat exchange in the Adams kiln. (2) One retorted residue sample was oxidized at 1000[degrees]F. Preliminary indications are that the ash of this run appears to have been completely oxidized. (3) Further minor equipment repairs and improvements were required during the course of the several runs.

  18. Caracterização química e mineralógica da incrustação em rede de ferro fundido e potencial de recuperação da capacidade hidráulica Chemical and mineralogical incrustation characterization and potential of hydraulic performance recovery

    Directory of Open Access Journals (Sweden)

    Rodrigo Braga Moruzzi

    2012-09-01

    Full Text Available O objetivo deste trabalho foi caracterizar química e mineralogicamente os depósitos em rede de ferro fundido e avaliado o potencial de recuperação da capacidade hidráulica em tubulação altamente comprometida pela incrustação. Para tal, foram feitas medidas do coeficiente de resistência (pitometria em trecho isolado de 71 m, análises química ( P-ES e ICP-MS, mineralógicas (laminação, difração de raios-X e microscopia eletrônica, dureza (escala de Mohs e simulações em setor hipotético com cenários distintos (de C1 a C4 de troca e substituição da rede. Os resultados indicaram que a rede altamente comprometida tem potencial limitado de recuperação (de 3,9 a 14,0 m0,367.s-1. As caracterizações química e mineralógica indicaram Magnetita e Goethita, com dureza da ordem de 6 na escala Mohs. As simulações demonstraram potências relativas (razões Ci/C1 da ordem de 86,00, 1,00 e 0,02% em relação ao cenário atual.The purpose of this work was to characterize chemical and mineralogical the water supply networks and to assess the hydraulic recovery on high-degraded pipe. Thus, the resistance (by pitometric essays, chemical analyses (ICP-MS and ICP-ES, mineralogical analysis (petrographic thin sections, X-ray difractometry and scanning electronic microscopy, hardness (Mohs scale and simulations for pipe's change and rehabilitations scenarios were investigated (from Scenario 1 to 4. The results showed that the high-degraded pipe had a limited recovery (from 3,9 to 14,0 m0,367.s-1. The deposits were formed by oxide and hydroxide of iron (magnetite and goethite, which are materials of high hardness (6 on Mohs scale. The simulations indicated the required power ratio (Ci/C1 around 86.00, 1.00 and 0.02% in relation to present scenario.

  19. Tracer monitoring of enhanced oil recovery projects

    Directory of Open Access Journals (Sweden)

    Kleven R.

    2013-05-01

    Full Text Available In enhanced oil recovery (EOR, chemicals are injected into the oil reservoir, either to increase macroscopic sweep efficiency, or to reduce remaining oil saturation in swept zones. Tracers can be used to identify reservoirs that are specifically suited for EOR operations. Injection of a selection of partitioning tracers, combined with frequent sample analysis of produced fluids, provides information suited for estimation of residual oil saturation. Tracers can also be used to evaluate and optimize the application of EOR chemicals in the reservoir. Suitable tracers will follow the EOR chemicals and assist in evaluation of retention, degradation or trapping. In addition to field applications, tracers also have a large potential as a tool to perform mechanistic studies of EOR chemicals in laboratory experiments. By labelling EOR chemicals with radioactive isotopes of elements such as H, C and S, detailed studies of transport mechanisms can be carried out. Co-injection of labelled compounds in dynamic flooding experiments in porous media will give information about retention or separation of the unique compounds constituting the chemical formulation. Separation of such compounds may be detrimental to obtaining the EOR effect expected. The paper gives new information of specific methods, and discusses current status for use of tracers in EOR operations.

  20. Karner Blue Butterfly Recovery Plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This recovery plan has been prepared by the Karner Blue Butterfly Recovery Team under the leadership of Dr. David Andow, University of Minnesota-St. Paul. Dr. John...

  1. Anatomically Correct Surface Recovery

    DEFF Research Database (Denmark)

    Jensen, Rasmus Ramsbøl; Nielsen, Jannik Boll; Larsen, Rasmus

    2015-01-01

    using the learned statistics. A quantitative evaluation is performed on a data set of 10 laser scans of ear canal impressions with minimal noise and artificial holes. We also present a qualitative evaluation on authentic partial scans from an actual direct in ear scanner prototype. Compared to a state......We present a method for 3D surface recovery in partial surface scans. The method is based on an Active Shape Model, which is used to predict missing data. The model is constructed using a bootstrap framework, where an initially small collection of hand-annotated samples is used to fit...... to and register unknown samples, resulting in an extensive statistical model. The statistical recovery uses a multivariate point prediction, where the distribution of the points is given by the Active Shape Model. We show how missing data in a partial scan, once point correspondence is achieved, can be predicted...

  2. Gasoline Vapor Recovery

    Science.gov (United States)

    1979-01-01

    Gasoline is volatile and some of it evaporates during storage, giving off hydrocarbon vapor. Formerly, the vapor was vented into the atmosphere but anti-pollution regulations have precluded that practice in many localities, so oil companies and storage terminals are installing systems to recover hydrocarbon vapor. Recovery provides an energy conservation bonus in that most of the vapor can be reconverted to gasoline. Two such recovery systems are shown in the accompanying photographs (mid-photo at right and in the foreground below). They are actually two models of the same system, although.configured differently because they are customized to users' needs. They were developed and are being manufactured by Edwards Engineering Corporation, Pompton Plains, New Jersey. NASA technological information proved useful in development of the equipment.

  3. Spontaneous recovery from acalculia.

    Science.gov (United States)

    Basso, Anna; Caporali, Alessandra; Faglioni, Pietro

    2005-01-01

    A topic much considered in research on acalculia was its relationship with aphasia. Far less attention has been given to the natural course of acalculia. In this retrospective study, we examined the relationship between aphasia and acalculia in an unselected series of 98 left-brain-damaged patients and the spontaneous recovery from acalculia in 92 acalculic patients with follow-up. There was a significant association between aphasia and acalculia although 19 participants exhibited aphasia with no acalculia and six acalculia with no aphasia. We observed significant improvement between a first examination carried out between 1 and 5 months post-onset and a second examination carried out between 3 and 11 months later (mean: 5 months). The mechanisms of spontaneous recovery are discussed.

  4. A Bridge to Recovery

    Directory of Open Access Journals (Sweden)

    Rebecca M. Loya

    2015-02-01

    Full Text Available Sexual violence can trigger adverse economic events for survivors, including increased expenses and decreased earnings. Using interview data, this exploratory study examines how access to assets (liquid assets, familial financial assistance, and homeownership affects survivors’ economic well-being during recovery. In keeping with asset theory, liquid assets and familial assistance can help offset post-assault expenses and facilitate access to services. Homeownership, meanwhile, appears to have mixed effects on survivors’ economic well-being. These findings suggest that the economic costs of sexual violence can burden survivors with fewer financial resources more heavily than those who own significant assets. As such, these findings shift the focus toward a dimension of inequality in recovery from sexual violence that is often overlooked in research and that may have implications for public policy and victim services.

  5. Superconducting energy recovery linacs

    Science.gov (United States)

    Ben-Zvi, Ilan

    2016-10-01

    High-average-power and high-brightness electron beams from a combination of laser photocathode electron guns and a superconducting energy recovery linac (ERL) is an emerging accelerator science with applications in ERL light sources, high repetition rate free electron lasers , electron cooling, electron ion colliders and more. This paper reviews the accelerator physics issues of superconducting ERLs, discusses major subsystems and provides a few examples of superconducting ERLs.

  6. Water recovery from dew

    OpenAIRE

    Nikolayev, Vadim; Beysens, D; Gioda, A; Milimouk, I; Katiushin, E; Morel, J.-P

    1996-01-01

    International audience; The recovery of clean water from dew has remained a longstanding challenge in many places all around the world. It is currently believed that the ancient Greeks succeeded in recovering atmospheric water vapour on a scale large enough to supply water to the city of Theodosia (presently Feodosia, Crimea, Ukraine). Several attempts were made in the early 20th Cent. to build artificial dew-catching constructions which were subsequently abandoned because of their low yield....

  7. Chemical use

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This is a summary of research and activities related to chemical use on Neal Smith National Wildlife Refuge between 1992 and 2009. The chemicals used on the Refuge...

  8. Chemical Peel

    Science.gov (United States)

    ... 20, 2015. Anitha B. Prevention of complications in chemical peeling. Journal of Cutaneous and Aesthetic Surgery. 2010;3:186. Langsdon PR, et al. Latest chemical peel innovations. Facial and Plastic Surgery Clinics of ...

  9. Chemical Reactors.

    Science.gov (United States)

    Kenney, C. N.

    1980-01-01

    Describes a course, including content, reading list, and presentation on chemical reactors at Cambridge University, England. A brief comparison of chemical engineering education between the United States and England is also given. (JN)

  10. Recovery From Comorbidity

    Directory of Open Access Journals (Sweden)

    Mathew Carter

    2013-11-01

    Full Text Available Comorbidity among mood, anxiety, and alcohol disorders is common and burdensome, affecting individuals, families, and public health. A systematic and integrative review of the literature across disciplines and research methodologies was performed. Supradisciplinary approaches were applied to the review and the ensuing critical appraisal. Definitions, measurement, and estimation are controversial and inconstant. Recovery from comorbidity cannot be easily extricated from a sociocultural milieu. Methodological challenges in quantitative and qualitative research and across disciplines are many and are discussed. The evidence supporting current treatments is sparse and short-term, and modalities operating in isolation typically fail. People easily fall into the cracks between mental health and addiction services. Clinicians feel untrained and consumers bear the brunt of this: Judgmental and moralistic interactions persist and comorbidity is unrecognized in high-risk populations. Competing historical paradigms of mental illness and addiction present a barrier to progress and reductionism is an impediment to care and an obstacle to the integration and interpretation of research. What matters to consumers is challenging to quantify but worth considering: Finding employment, safe housing, and meaning are crucial to recovery. Complex social networks and peer support in recovery are important but poorly understood. The focus on modalities of limited evidence or generalizability persists in literature and practice. We need to consider different combinations of comorbidity, transitions as opposed to dichotomies of use or illness, and explore the long-term view and emic perspectives.

  11. Recovery definitions: Do they change?

    Science.gov (United States)

    Kaskutas, Lee Ann; Witbrodt, Jane; Grella, Christine E

    2015-09-01

    The term "recovery" is widely used in the substance abuse literature and clinical settings, but data have not been available to empirically validate how recovery is defined by individuals who are themselves in recovery. The "What Is Recovery?" project developed a 39-item definition of recovery based on a large nationwide online survey of individuals in recovery. The objective of this paper is to report on the stability of those definitions one to two years later. To obtain a sample for studying recovery definitions that reflected the different pathways to recovery, the parent study involved intensive outreach. Follow-up interviews (n=1237) were conducted online and by telephone among respondents who consented to participate in follow-up studies. Descriptive analyses considered endorsement of individual recovery items at both surveys, and t-tests of summary scores studied significant change in the sample overall and among key subgroups. To assess item reliability, Cronbach's alpha was estimated. Rates of endorsement of individual items at both interviews was above 90% for a majority of the recovery elements, and there was about as much transition into endorsement as out of endorsement. Statistically significant t-test scores were of modest magnitude, and reliability statistics were high (ranging from .782 to .899). Longitudinal analyses found little evidence of meaningful change in recovery definitions at follow-up. Results thus suggest that the recovery definitions developed in the parent "What Is Recovery?" survey represent stable definitions of recovery that can be used to guide service provision in Recovery-Oriented Systems of Care. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  12. Bridging the Gap between Chemical Flooding and Independent Oil Producers

    Energy Technology Data Exchange (ETDEWEB)

    Stan McCool; Tony Walton; Paul Whillhite; Mark Ballard; Miguel Rondon; Kaixu Song; Zhijun Liu; Shahab Ahmed; Peter Senior

    2012-03-31

    Ten Kanas oil reservoirs/leases were studied through geological and engineering analysis to assess the potential performance of chemical flooding to recover oil. Reservoirs/leases that have been efficiently waterflooded have the highest performance potential for chemical flooding. Laboratory work to identify efficient chemical systems and to test the oil recovery performance of the systems was the major effort of the project. Efficient chemical systems were identified for crude oils from nine of the reservoirs/leases. Oil recovery performance of the identified chemical systems in Berea sandstone rocks showed 90+ % recoveries of waterflood residual oil for seven crude oils. Oil recoveries increased with the amount of chemical injected. Recoveries were less in Indiana limestone cores. One formulation recovered 80% of the tertiary oil in the limestone rock. Geological studies for nine of the oil reservoirs are presented. Pleasant Prairie, Trembley, Vinland and Stewart Oilfields in Kansas were the most favorable of the studied reservoirs for a pilot chemical flood from geological considerations. Computer simulations of the performance of a laboratory coreflood were used to predict a field application of chemical flooding for the Trembley Oilfield. Estimates of field applications indicated chemical flooding is an economically viable technology for oil recovery.

  13. Bridging the Gap between Chemical Flooding and Independent Oil Producers

    Energy Technology Data Exchange (ETDEWEB)

    Stan McCool; Tony Walton; Paul Willhite; Mark Ballard; Miguel Rondon; Kaixu Song; Zhijun Liu; Shahab Ahmend; Peter Senior

    2012-03-31

    Ten Kanas oil reservoirs/leases were studied through geological and engineering analysis to assess the potential performance of chemical flooding to recover oil. Reservoirs/leases that have been efficiently waterflooded have the highest performance potential for chemical flooding. Laboratory work to identify efficient chemical systems and to test the oil recovery performance of the systems was the major effort of the project. Efficient chemical systems were identified for crude oils from nine of the reservoirs/leases. Oil recovery performance of the identified chemical systems in Berea sandstone rocks showed 90+ % recoveries of waterflood residual oil for seven crude oils. Oil recoveries increased with the amount of chemical injected. Recoveries were less in Indiana limestone cores. One formulation recovered 80% of the tertiary oil in the limestone rock. Geological studies for nine of the oil reservoirs are presented. Pleasant Prairie, Trembley, Vinland and Stewart Oilfields in Kansas were the most favorable of the studied reservoirs for a pilot chemical flood from geological considerations. Computer simulations of the performance of a laboratory coreflood were used to predict a field application of chemical flooding for the Trembley Oilfield. Estimates of field applications indicated chemical flooding is an economically viable technology for oil recovery.

  14. Integrated Resource Management and Recovery

    DEFF Research Database (Denmark)

    Astrup, Thomas Fruergaard

    2014-01-01

    resources, i.e. security of supply, but also the need for efficient recovery of the same resources after the use-phase of the products. While this recovery may appear simple, considerable challenges exist. Management and recovery of resources in waste materials, or in general residual streams in society......, depends on the quality of these resources and technological abilities to extract resources from mixed materials, e.g. mobile phones, solar cells, or mixed domestic waste. The "effort" invested in recovery of secondary resources should not be more than the "benefit" associated with the secondary resources....... Over the recent decades, DTU Environment has worked extensively both with resource recovery technologies and life cycle assessment (LCA) models (www.EASETECH.dk) dedicated to evaluating resource management and recovery systems. Advanced sustainability assessments of resource recovery and utilization...

  15. Umbilical Cable Recovery Load Analysis

    Institute of Scientific and Technical Information of China (English)

    YAN Shu-wang; JIA Zhao-lin; FENG Xiao-wei; LI Shi-tao

    2013-01-01

    Umbilical cable is a kind of integrated subsea cable widely used in the exploration and exploitation of oil and gas field.The severe ocean environment makes great challenges to umbilical maintenance and repair work.Damaged umbilical is usually recovered for the regular operation of the offshore production system.Analysis on cables in essence is a two-point boundary problem.The tension load at the mudline must be known first,and then the recovery load and recovery angle on the vessel can be solved by use of catenary equation.The recovery analysis also involves umbilicalsoil interaction and becomes more complicated.Calculation methods for recovery load of the exposed and buried umbilical are established and the relationship between the position of touch down point and the recovery load as well as the recovery angle and recovery load are analyzed.The analysis results provide a theoretical reference for offshore on-deck operation.

  16. Umbilical cable recovery load analysis

    Science.gov (United States)

    Yan, Shu-wang; Jia, Zhao-lin; Feng, Xiao-wei; Li, Shi-tao

    2013-06-01

    Umbilical cable is a kind of integrated subsea cable widely used in the exploration and exploitation of oil and gas field. The severe ocean environment makes great challenges to umbilical maintenance and repair work. Damaged umbilical is usually recovered for the regular operation of the offshore production system. Analysis on cables in essence is a two-point boundary problem. The tension load at the mudline must be known first, and then the recovery load and recovery angle on the vessel can be solved by use of catenary equation. The recovery analysis also involves umbilical-soil interaction and becomes more complicated. Calculation methods for recovery load of the exposed and buried umbilical are established and the relationship between the position of touch down point and the recovery load as well as the recovery angle and recovery load are analyzed. The analysis results provide a theoretical reference for offshore on-deck operation.

  17. The ALEXIS mission recovery

    Energy Technology Data Exchange (ETDEWEB)

    Bloch, J.; Armstrong, T.; Dingler, B.; Enemark, D.; Holden, D.; Little, C.; Munson, C.; Priedhorsky, B.; Roussel-Dupre, D.; Smith, B. [Los Alamos National Lab., NM (United States); Warner, R.; Dill, B.; Huffman, G.; McLoughlin, F.; Mills, R.; Miller, R. [AeroAstro, Inc., Herndon, VA (United States)

    1994-03-01

    The authors report the recovery of the ALEXIS small satellite mission. ALEXIS is a 113-kg satellite that carries an ultrasoft x-ray telescope array and a high-speed VHF receiver/digitizer (BLACKBEARD), supported by a miniature spacecraft bus. It was launched by a Pegasus booster on 1993 April 25, but a solar paddle was damaged during powered flight. Initial attempts to contact ALEXIS were unsuccessful. The satellite finally responded in June, and was soon brought under control. Because the magnetometer had failed, the rescue required the development of new attitude control-techniques. The telemetry system has performed nominally. They discuss the procedures used to recover the ALEXIS mission.

  18. URANIUM RECOVERY PROCESS

    Science.gov (United States)

    Bailes, R.H.; Long, R.S.; Olson, R.S.; Kerlinger, H.O.

    1959-02-10

    A method is described for recovering uranium values from uranium bearing phosphate solutions such as are encountered in the manufacture of phosphate fertilizers. The solution is first treated with a reducing agent to obtain all the uranium in the tetravalent state. Following this reduction, the solution is treated to co-precipitate the rcduced uranium as a fluoride, together with other insoluble fluorides, thereby accomplishing a substantially complete recovery of even trace amounts of uranium from the phosphate solution. This precipitate usually takes the form of a complex fluoride precipitate, and after appropriate pre-treatment, the uranium fluorides are leached from this precipitate and rccovered from the leach solution.

  19. Energy Recovery Linacs

    Energy Technology Data Exchange (ETDEWEB)

    Nikolitsa Merminga

    2007-06-01

    The success and continuing progress of the three operating FELs based on Energy Recovery Linacs (ERLs), the Jefferson Lab IR FEL Upgrade, the Japan Atomic Energy Agency (JAEA) FEL, and the Novosibirsk High Power THz FEL, have inspired multiple future applications of ERLs, which include higher power FELs, synchrotron radiation sources, electron cooling devices, and high luminosity electron-ion colliders. The benefits of using ERLs for these applications are presented. The key accelerator physics and technology challenges of realizing future ERL designs, and recent developments towards resolving these challenges are reviewed.

  20. Polymeric surfactants for enhanced oil recovery : A review

    NARCIS (Netherlands)

    Raffa, Patrizio; Broekhuis, Antonius A.; Picchioni, Francesco

    Chemical enhanced oil recovery (EOR) is surely a topic of interest, as conventional oil resources become more scarce and the necessity of exploiting heavy and unconventional oils increases. EOR methods based on polymer flooding, surfactant-polymer flooding and alkali-surfactant-polymer flooding are

  1. Polymeric surfactants for enhanced oil recovery : A review

    NARCIS (Netherlands)

    Raffa, Patrizio; Broekhuis, Antonius A.; Picchioni, Francesco

    2016-01-01

    Chemical enhanced oil recovery (EOR) is surely a topic of interest, as conventional oil resources become more scarce and the necessity of exploiting heavy and unconventional oils increases. EOR methods based on polymer flooding, surfactant-polymer flooding and alkali-surfactant-polymer flooding are

  2. Polymeric surfactants for enhanced oil recovery : A review

    NARCIS (Netherlands)

    Raffa, Patrizio; Broekhuis, Antonius A.; Picchioni, Francesco

    2016-01-01

    Chemical enhanced oil recovery (EOR) is surely a topic of interest, as conventional oil resources become more scarce and the necessity of exploiting heavy and unconventional oils increases. EOR methods based on polymer flooding, surfactant-polymer flooding and alkali-surfactant-polymer flooding are

  3. Chemical dehumidification and heat recovery: Open-cycle heat pump

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R.; Longo, G.A.; Piccininni, F. (Padua Univ. (Italy). Ist. di Fisica Tecnica)

    1992-02-01

    This article examines an open-cycle heat pump based on a stacked column working with an absorbing solution. The column treats both the expelled air and the fumes generated by the combustion of the methane feeding the solution regenerator. The system is quite easy: it consists of a stacked column, a regenerator with its condenser and four heat exchangers. A simulation - based on a 12kW charge with a 1000 kg/h air exchange - proved that it is possible to obtain an REP higher than 1.5.

  4. Contracts for field projects and supporting research on enhanced oil recovery. Progress review number 87

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    Approximately 30 research projects are summarized in this report. Title of the project, contract number, company or university, award amount, principal investigators, objectives, and summary of technical progress are given for each project. Enhanced oil recovery projects include chemical flooding, gas displacement, and thermal recovery. Most of the research projects though are related to geoscience technology and reservoir characterization.

  5. Inherently safe in situ uranium recovery.

    Energy Technology Data Exchange (ETDEWEB)

    Krumhansl, James Lee; Beauheim, Richard Louis; Brady, Patrick Vane; Arnold, Bill Walter; Kanney, Joseph F.; McKenna, Sean Andrew

    2009-05-01

    Expansion of uranium mining in the United States is a concern to some environmental groups and sovereign Native American Nations. An approach which may alleviate some problems is to develop inherently safe in situ uranium recovery ('ISR') technologies. Current ISR technology relies on chemical extraction of trace levels of uranium from aquifers that, once mined, can still contain dissolved uranium and other trace metals that are a health concern. Existing ISR operations are few in number; however, high uranium prices are driving the industry to consider expanding operations nation-wide. Environmental concerns and enforcement of the new 30 ppb uranium drinking water standard may make opening new mining operations more difficult and costly. Here we propose a technological fix: the development of inherently safe in situ recovery (ISISR) methods. The four central features of an ISISR approach are: (1) New 'green' leachants that break down predictably in the subsurface, leaving uranium, and associated trace metals, in an immobile form; (2) Post-leachant uranium/metals-immobilizing washes that provide a backup decontamination process; (3) An optimized well-field design that increases uranium recovery efficiency and minimizes excursions of contaminated water; and (4) A combined hydrologic/geochemical protocol for designing low-cost post-extraction long-term monitoring. ISISR would bring larger amounts of uranium to the surface, leave fewer toxic metals in the aquifer, and cost less to monitor safely - thus providing a 'win-win-win' solution to all stakeholders.

  6. Robust Disaster Recovery System Model

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Highly security-critical system should possess features of continuous service. We present a new Robust Disaster Recovery System Model (RDRSM). Through strengthening the ability of safe communications, RDRSM guarantees the secure and reliable command on disaster recovery. Its self-supervision capability can monitor the integrality and security of disaster recovery system itself. By 2D and 3D real-time visible platform provided by GIS, GPS and RS, the model makes the using, management and maintenance of disaster recovery system easier. RDRSM possesses predominant features of security, robustness and controllability. And it can be applied to highly security-critical environments such as E-government and bank. Conducted by RDRSM, an important E-government disaster recovery system has been constructed successfully. The feasibility of this model is verified by practice. We especially emphasize the significance of some components of the model, such as risk assessment, disaster recovery planning, system supervision and robust communication support.

  7. Recovery of Sparsely Corrupted Signals

    CERN Document Server

    Studer, Christoph; Pope, Graeme; Bölcskei, Helmut

    2011-01-01

    We investigate the recovery of signals exhibiting a sparse representation in a general (i.e., possibly redundant or incomplete) dictionary that are corrupted by additive noise admitting a sparse representation in another general dictionary. This setup covers a wide range of applications, such as image inpainting, super-resolution, signal separation, and recovery of signals that are impaired by, e.g., clipping, impulse noise, or narrowband interference. We present deterministic recovery guarantees based on a novel uncertainty relation for pairs of general dictionaries and we provide corresponding practicable recovery algorithms. The recovery guarantees we find depend on the signal and noise sparsity levels, on the coherence parameters of the involved dictionaries, and on the amount of prior knowledge on the support sets of signal and noise. We finally identify situations under which the recovery guarantees are tight.

  8. Teaching recovery to medical students.

    LENUS (Irish Health Repository)

    Feeney, Larkin

    2013-03-01

    Community mental health services are evolving toward more holistic, patient-centered, recovery-based practices. This change necessitates an attitudinal shift from mental health workers, and training in recovery principles is helpful in achieving this change. Medical students often have narrow, doctor-centered concepts of mental health care. Traditional clinical placements in psychiatry do little to address this. We evaluated a recovery-focused teaching program for medical students in psychiatry.

  9. Chemical sensors

    Science.gov (United States)

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1991-07-02

    Sensors responsive to small changes in the concentration of chemical species are disclosed. The sensors comprise a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment. They are operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical response. 9 figures.

  10. Superdiffusive gas recovery from nanopores

    Science.gov (United States)

    Wu, Haiyi; He, Yadong; Qiao, Rui

    2016-11-01

    Understanding the recovery of gas from reservoirs featuring pervasive nanopores is essential for effective shale gas extraction. Classical theories cannot accurately predict such gas recovery and many experimental observations are not well understood. Here we report molecular simulations of the recovery of gas from single nanopores, explicitly taking into account molecular gas-wall interactions. We show that, in very narrow pores, the strong gas-wall interactions are essential in determining the gas recovery behavior both quantitatively and qualitatively. These interactions cause the total diffusion coefficients of the gas molecules in nanopores to be smaller than those predicted by kinetic theories, hence slowing down the rate of gas recovery. These interactions also lead to significant adsorption of gas molecules on the pore walls. Because of the desorption of these gas molecules during gas recovery, the gas recovery from the nanopore does not exhibit the usual diffusive scaling law (i.e., the accumulative recovery scales as R ˜t1 /2 ) but follows a superdiffusive scaling law R ˜tn (n >0.5 ), which is similar to that observed in some field experiments. For the system studied here, the superdiffusive gas recovery scaling law can be captured well by continuum models in which the gas adsorption and desorption from pore walls are taken into account using the Langmuir model.

  11. Register file soft error recovery

    Science.gov (United States)

    Fleischer, Bruce M.; Fox, Thomas W.; Wait, Charles D.; Muff, Adam J.; Watson, III, Alfred T.

    2013-10-15

    Register file soft error recovery including a system that includes a first register file and a second register file that mirrors the first register file. The system also includes an arithmetic pipeline for receiving data read from the first register file, and error detection circuitry to detect whether the data read from the first register file includes corrupted data. The system further includes error recovery circuitry to insert an error recovery instruction into the arithmetic pipeline in response to detecting the corrupted data. The inserted error recovery instruction replaces the corrupted data in the first register file with a copy of the data from the second register file.

  12. Planning tiger recovery

    DEFF Research Database (Denmark)

    Wilting, Andreas; Courtiol, Alexandre; Christiansen, Per;

    2015-01-01

    approaches to plan tiger recovery are partly impeded by the lack of a consensus on the number of tiger subspecies or management units, because a comprehensive analysis of tiger variation is lacking. We analyzed variation among all nine putative tiger subspecies, using extensive data sets of several traits...... two subspecies: the Sunda tiger, Panthera tigris sondaica, and the continental tiger, Panthera tigris tigris, which consists of two (northern and southern) management units. Conservation management programs, such as captive breeding, reintroduction initiatives, or trans-boundary projects, rely......, which will have profound implications for the management of in situ and ex situ tiger populations and boost conservation efforts by facilitating a pragmatic approach to tiger conservation management worldwide....

  13. Planning tiger recovery

    DEFF Research Database (Denmark)

    Wilting, Andreas; Courtiol, Alexandre; Christiansen, Per

    2015-01-01

    approaches to plan tiger recovery are partly impeded by the lack of a consensus on the number of tiger subspecies or management units, because a comprehensive analysis of tiger variation is lacking. We analyzed variation among all nine putative tiger subspecies, using extensive data sets of several traits...... two subspecies: the Sunda tiger, Panthera tigris sondaica, and the continental tiger, Panthera tigris tigris, which consists of two (northern and southern) management units. Conservation management programs, such as captive breeding, reintroduction initiatives, or trans-boundary projects, rely......, which will have profound implications for the management of in situ and ex situ tiger populations and boost conservation efforts by facilitating a pragmatic approach to tiger conservation management worldwide....

  14. Forerunner of Recovery

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    It has been an accepted fact that the sweeping financial crisis has thrown the world economy into a tailspin.Some Western countries are succumbing to a deepening recession.In China,the chilly winds blowing through the global economy have even put a damper on this year’s lunar New Year. The looming question now is which country will be the first to bottom out-the United States or China?Have they laid the groundwork for recovery?Zuo Xiaolei,chief economist at China Galaxy Securities Co.Ltd.in Beijing,discussed these questions in a recent article in the China Securities Journal.Edited excerpts follow

  15. Speech recovery device

    Energy Technology Data Exchange (ETDEWEB)

    Frankle, Christen M.

    2004-04-20

    There is provided an apparatus and method for assisting speech recovery in people with inability to speak due to aphasia, apraxia or another condition with similar effect. A hollow, rigid, thin-walled tube with semi-circular or semi-elliptical cut out shapes at each open end is positioned such that one end mates with the throat/voice box area of the neck of the assistor and the other end mates with the throat/voice box area of the assisted. The speaking person (assistor) makes sounds that produce standing wave vibrations at the same frequency in the vocal cords of the assisted person. Driving the assisted person's vocal cords with the assisted person being able to hear the correct tone enables the assisted person to speak by simply amplifying the vibration of membranes in their throat.

  16. RECOVERY OF LOWER DISCOPATHIES

    Directory of Open Access Journals (Sweden)

    Florina Paraschita

    2015-10-01

    Full Text Available Discopathy lumbar (DVL is characterized by localized back pain in the lumbar region and radiating to the buttocks and along the leg, under certain nerve pathways. The purpose of this study was to find the best treatment for improving pronounced as back pain in lumbar-sacral and cervical region. In the study took part two women aged 42 to 55 years, with disease acquired due to requesting or incorrect posture, one being a former athlete, the other being an accountant and sitting a lot on the chair because the profession. Patients with lower discopathies can improve spinal mobility and may relieve back pain through chiropractic methods, massage and electrotherapy. It is necessary to apply as early as possible a comprehensive program of recovery (Exercise WILLIAMS, showing continuity in time and aim to reduce or eliminate pain patient.

  17. Speech recovery device

    Energy Technology Data Exchange (ETDEWEB)

    Frankle, Christen M.

    2000-10-19

    There is provided an apparatus and method for assisting speech recovery in people with inability to speak due to aphasia, apraxia or another condition with similar effect. A hollow, rigid, thin-walled tube with semi-circular or semi-elliptical cut out shapes at each open end is positioned such that one end mates with the throat/voice box area of the neck of the assistor and the other end mates with the throat/voice box area of the assisted. The speaking person (assistor) makes sounds that produce standing wave vibrations at the same frequency in the vocal cords of the assisted person. Driving the assisted person's vocal cords with the assisted person being able to hear the correct tone enables the assisted person to speak by simply amplifying the vibration of membranes in their throat.

  18. Hazardous Chemicals

    Centers for Disease Control (CDC) Podcasts

    2007-04-10

    Chemicals are a part of our daily lives, providing many products and modern conveniences. With more than three decades of experience, The Centers for Disease Control and Prevention (CDC) has been in the forefront of efforts to protect and assess people's exposure to environmental and hazardous chemicals. This report provides information about hazardous chemicals and useful tips on how to protect you and your family from harmful exposure.  Created: 4/10/2007 by CDC National Center for Environmental Health.   Date Released: 4/13/2007.

  19. Technology strategy for enhanced recovery; Technology Target Areas; TTA3 - enhanced recovery

    Energy Technology Data Exchange (ETDEWEB)

    2007-07-01

    The Norwegian Continental Shelf (NCS) is facing new challenges in reserve replacement and improved recovery in order to maintain the overall oil production rate from the area. A new target for an increase in oil reserves of 800 million Sm3 of oil (5 billion barrels) by year 2015 has been set by NPD. This is an ambitious goal considering several of the large fields are on a steep decline, and most of the recent discoveries are relatively small. A significant part of these increased reserves will have to come from fields currently on production, from reservoir areas that have been partly or fully swept, and it is therefore evident that Enhanced Oil Recovery (EOR) methods have to play a key role in achieving this target. EOR methods can be divided into gas based EOR methods and water based EOR methods. Thermal methods are not considered applicable on the NCS due to the relatively light oils present, and the depth of the reservoirs. Gas Based EOR; Water Based EOR; CO{sub 2} injection; Surfactants; Air injection; Polymer; Nitrogen injection; Alkaline; Flue gas injection; Polymer gels; WAG; MEOR; FAWAG. The former OG21 strategy document gave high priority to Water Alternating Gas (WAG) methods and CO{sub 2} injection for enhanced recovery. A lot of research and development and evaluation projects on CO{sub 2} injection were launched and are on-going, most of these are being CO{sub 2} WAG studies. The main challenge now in order to realize CO{sub 2} injection on the NCS is on CO{sub 2} availability and transport. It is also believed that increasing gas prices will limit the availability of hydrocarbon gas for injection purposes in the future. There is, however, a clear need for developing alternative cost efficient EOR methods that can improve the sweep efficiency significantly. Since a majority of the fields on the NCS are being produced under water flooding (or WAG), methods that can improve the water flooding efficiency by chemical additives are of special interest and

  20. Activities of the Oil Implementation Task Force, reporting period March--August 1991; Contracts for field projects and supporting research on enhanced oil recovery, reporting period October--December 1990

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    Activities of DOE's Oil Implementation Task Force for the period March--August 1991 are reviewed. Contracts for fields projects and supporting research on enhanced oil recovery are discussed, with a list of related publications given. Enhanced recovery processes covered include chemical flooding, gas displacement, thermal recovery, and microbial recovery.

  1. Untreated Recovery from Eating Disorders

    Science.gov (United States)

    Woods, Susan

    2004-01-01

    This retrospective study explored the experience of recovery from anorexia nervosa and bulimia nervosa without professional treatment. A nine-question open-ended electronic survey was posted for a period of four months at a mid-western university. Sixteen female and two male respondents reported recovery from adolescent-onset full syndrome…

  2. Recovery from Binge Eating Disorder

    Science.gov (United States)

    Krentz, Adrienne; Chew, Judy; Arthur, Nancy

    2005-01-01

    The purpose of this study was to characterize the psychological processes of recovery from binge eating disorder (BED). A model was developed by asking the research question, "What is the experience of recovery for women with BED?" Unstructured interviews were conducted with six women who met the DSM-IV criteria for BED, and who were recovered…

  3. Biomass Program Recovery Act Factsheet

    Energy Technology Data Exchange (ETDEWEB)

    None

    2010-03-01

    The Biomass Program has awarded about $718 million in American Recovery and Reinvestment Act (Recovery Act) funds. The projects the Program is supporting are intended to: Accelerate advanced biofuels research, development, and demonstration; Speed the deployment and commercialization of advanced biofuels and bioproducts; Further the U.S. bioindustry through market transformation and creating or saving a range of jobs.

  4. CHEMICAL PROPERTIES.

    African Journals Online (AJOL)

    However, the amount of soil organic matter and total nitrogen content was. T DIFFERENT HOURS ... burning such as improvement in soil physical ... chemical properties. The aim is to find .... Humid Tropics with particular reference to. Nigeria.

  5. Conceptual process synthesis for recovery of natural products from plants

    DEFF Research Database (Denmark)

    Malwade, Chandrakant R.; Qu, Haiyan; Rong, Ben-Guang;

    2013-01-01

    A systematic method of conceptual process synthesis for recovery of natural products from their biological sources is presented. This methodology divides the task into two major subtasks namely, isolation of target compound from a chemically complex solid matrix of biological source (crude extract......) and purification of target compound(s) from the crude extract. Process analytical technology (PAT) is used in each step to understand the nature of material systems and separation characteristics of each separation method. In the present work, this methodology is applied to generate process flow sheet for recovery...

  6. Heat Recovery From Tail Gas Incineration To Generate Power

    Energy Technology Data Exchange (ETDEWEB)

    Tawfik, Tarek

    2010-09-15

    Many industrial processes result in tail gas wastes that must be flared or incinerated to abide with environmental guidelines. Tail gas incineration occurs in several chemical processes resulting in high-temperature exhaust gas that simply go to the stack, thus wasting all that valuable heat! This paper discusses useful heat recovery and electric power generation utilizing available heat in exhaust gas from tail gas incinerators. This heat will be recovered in a waste-heat recovery boiler that will produce superheated steam to expand in a steam turbine to generate power. A detailed cost estimate is presented.

  7. LHC Report: Rocky Recovery

    CERN Multimedia

    Mike Lamont for the LHC Team

    2011-01-01

    The last technical stop finished on Friday 8 July, but the machine returned to its pre-stop performance level over a week later.   Efficiency of LHC fills between 16 July and 20 July, 2011. The cryogenics team had the entire ring cold by Saturday morning and the usual post-technical stop tests with circulating beams started soon after. Unfortunately, they were interrupted by a major perturbation to CERN’s electrical network caused by an impressive thunderstorm that swept over the Pays de Gex. There were major knock-on effects, including the loss of cooling to the cryogenics and an inevitable recovery period once normal service had been re-established. The beams were circulating again by Tuesday afternoon and the post-technical stop checks continued, beefed up with further tests to address a number of issues related to the power cut.  Before the stop, the LHC had managed to get 1380 bunches per beam into collisions and the plan was to ramp back up relatively quickly to this leve...

  8. Immune recovery vitritis

    Directory of Open Access Journals (Sweden)

    Dujić Mirjana

    2007-01-01

    Full Text Available Introduction Immune recovery vitritis (IRV is symptomatic vitritis of > 1+ severity associated with inactive cytomegalovirus (CMV retinitis. It is an opportunistic infection of the eye, in the patients who suffer from AIDS, and is treated with a highly active antiretroviral therapy (HAART. As a result of this therapy, there is an immune reconstitution in the body and inflammation of the vitreous body. Objective The aim of the study was to show the incidence of IRV in patients treated with HAART. Method A retrospective study was conducted in patients who suffered from CMV retinitis. Twenty-one were treated with HAART and had the diagnosis of CMV retinitis, as well. All of them were examined by the same ophthalmologist who peformed slit lamp examination with mydriasis and indirect ophthalmoscopy. Results Nine of 21 patients developed IRV as a complication of HAART, two had cystoid macular edema (CMO. Conclusion CMV retinitis develops when the number of CD4+ T lymphocytes drops below 50/mm3. This results in necrotic retinitis which, if untreated, leads to complete loss of vision. With the introduction of HAART, we learned that the reconstitution of immune status was achieved as well as life expectancy, but there was a dramatic decline in the opportunistic infection, including CMV retinitis, as well. With the immune reconstitution, the inflammation develops in the eye, known as IRV. Sometimes, it is necessary to treat this condition, but in the case of our patients, the inflammation was mild, and no treatment was necessary.

  9. PHA recovery from biomass.

    Science.gov (United States)

    Madkour, Mohamed H; Heinrich, Daniel; Alghamdi, Mansour A; Shabbaj, Ibraheem I; Steinbüchel, Alexander

    2013-09-09

    The recovery of polyhydroxyalkanoates (PHAs) from biomass, that is, from bacterial cells, is one of the major obstacles in the industrial production of these polyesters. Since PHAs are naturally synthesized as intracellular storage compounds for carbon and energy and are for this deposited in the cytoplasm of the bacterial cell, PHAs are more or less tightly linked with the entire biomass, and the polyesters must be released from the cells before their isolation and purification can be conducted. This additional step, that is, the release from the cells, is a major difference from most other biotechnological processes where the product occurs outside of the cells because it is secreted into the medium in a bioreactor or because it is synthesized in vitro in an enzyme reactor in a cell free system. This additional step contributes significantly to the overall costs of production. In this review we provide an overview about the different processes that result in the release of PHA from the cells, and we evaluate these processes with regard to the suitability at large scale in the industry.

  10. Chemical Dependence and Personality

    Directory of Open Access Journals (Sweden)

    Carlos Henrique Sancineto da Silva Nunes

    2009-01-01

    Full Text Available This study investigated the relationships between chemical dependency and personalitystructure in a Brazilian sample. Participants were college students (n=35 and patients of a drug recovery center (n= 48. Two personality scales based on the Big-5 Model were used to measure Extraversion and Agreeableness. A semi-structured interview was used to identify events in the patients' life histories that might support specific classifications. Participants' scores were also compared to Brazilian normative samples. The results showed significant differences between clinical and non-clinical groups in Agreeableness, but not in Extraversion. Logistic regression analyses were conducted using scales and interview aspects for predicting group membership. The model showed 92.1% general predictive power. Results pointed to the advantage of using both interview and objective techniques to assess individuals with antisocial personality symptoms.

  11. General introduction and recovery factors

    Science.gov (United States)

    Verma, Mahendra K.

    2017-07-17

    IntroductionThe U.S. Geological Survey (USGS) compared methods for estimating an incremental recovery factor (RF) for the carbon dioxide enhanced oil recovery (CO2-EOR) process involving the injection of CO2 into oil reservoirs. This chapter first provides some basic information on the RF, including its dependence on various reservoir and operational parameters, and then discusses the three development phases of oil recovery—primary, second­ary, and tertiary (EOR). It ends with a brief discussion of the three approaches for estimating recovery factors, which are detailed in subsequent chapters.

  12. Prediction of Recovery from Coma After CPR

    Science.gov (United States)

    ... THEIR FAMILIES PREDICTION OF RECOVERY FROM COMA AFTER CPR This summary will provide you with information about ... help doctors predict poor recovery from coma after CPR. In this case, poor recovery means death, continued ...

  13. Comparing population recovery after insecticide exposure for four aquatic invertebrate species using models of different complexity

    NARCIS (Netherlands)

    Baveco, H.; Norman, S.; Roessink, I.; Galic, N.G.; Brink, van den P.J.

    2014-01-01

    Population models, in particular individual-based models (IBMs), are becoming increasingly important in chemical risk assessment. They can be used to assess recovery of spatially structured populations after chemical exposure that varies in time and space. The authors used an IBM coupled to a

  14. Chemical thermodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Rock, P.A.

    1983-01-01

    This book, suitable as an introductory text for undergraduates, presents temperature, internal energy, and entropy with a minimum of mathematics. The basic mathematical models of classical chemical thermodynamics are developed later in the text. Includes numerous problems at the end of each chapter, an appendix giving thermodynamic data for common substances, a short list of references, answers to selected problems, and a subject index. Contents, abridged: Energy and the first law of thermodynamics. Thermodynamic functions. The third law of thermodynamics and absolute entropies. Thermodynamics of chemical reactions. Phase equilibria: the activity function. Thermodynamics of ions in solution. Statistical thermodynamics. Appendices. Index.

  15. Recovery Processes of Organic Acids from Fermentation Broths in the Biomass-Based Industry.

    Science.gov (United States)

    Li, Qian-Zhu; Jiang, Xing-Lin; Feng, Xin-Jun; Wang, Ji-Ming; Sun, Chao; Zhang, Hai-Bo; Xian, Mo; Liu, Hui-Zhou

    2016-01-01

    The new movement towards green chemistry and renewable feedstocks makes microbial production of chemicals more competitive. Among the numerous chemicals, organic acids are more attractive targets for process development efforts in the renewable-based biorefinery industry. However, most of the production costs in microbial processes are higher than that in chemical processes, among which over 60% are generated by separation processes. Therefore, the research of separation and purification processes is important for a promising biorefinery industry. This review highlights the progress of recovery processes in the separation and purification of organic acids, including their advantages and disadvantages, current situation, and future prospects in terms of recovery yields and industrial application.

  16. Pacific Coastal Salmon Recovery Fund

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Congress established the Pacific Coastal Salmon Recovery Fund (PCSRF) to monitor the restoration and conservation of Pacific salmon and steelhead populations and...

  17. Disaster Debris Recovery Database - Landfills

    Data.gov (United States)

    U.S. Environmental Protection Agency — The US EPA Region 5 Disaster Debris Recovery Database includes public datasets of over 6,000 composting facilities, demolition contractors, transfer stations,...

  18. Recovery after abdominal wall reconstruction

    DEFF Research Database (Denmark)

    Jensen, Kristian Kiim

    2017-01-01

    was lacking. Study II was a case-control study of the effects of an enhanced recovery after surgery pathway for patients undergoing abdominal wall reconstruction for a giant hernia. Sixteen consecutive patients were included prospectively after the implementation of a new enhanced recovery after surgery...... pathway at the Digestive Disease Center, Bispebjerg Hospital, and compared to a control group of 16 patients included retrospectively in the period immediately prior to the implementation of the pathway. The enhanced recovery after surgery pathway included preoperative high-dose steroid, daily assessment...... of revised discharge criteria and an aggressive approach to restore bowel function (chewing gum and enema on postoperative day two). Patients who followed the enhanced recovery after surgery pathway reported low scores of pain, nausea and fatigue, and were discharged significantly faster than patients...

  19. FEMA Disaster Recovery Centers - KML

    Data.gov (United States)

    Department of Homeland Security — This is a KML file for FEMA's Disaster Recovery Centers (DRC). A DRC is a readily accessible facility or mobile office set up by FEMA where applicants may go for...

  20. Uncovering Recovery: The Resistible Rise of Recovery and Resilience

    Directory of Open Access Journals (Sweden)

    David Harper

    2012-10-01

    Full Text Available Discourses of recovery and resilience have risen to positions of dominance in the mental health field. Models of recovery and resilience enjoy purchase, in both policy and practice, across a range of settings from self-described psychiatric survivors through to mental health charities through to statutory mental health service providers. Despite this ubiquity, there is confusion about what recovery means. In this article we problematize notions of recovery and resilience, and consider what, if anything, should be recovered from these concepts. We focus on three key issues, i individualization, ii the persistence of a deficit model, and iii collective approaches to recovery. Through documentary analysis we consider these issues across third sector organizations, and public and mental health policy. Firstly, definitional debates about recovery reflect wider ideological debates about the nature of mental health. The vagueness of these concepts and implicit assumptions inherent in dominant recovery and resilience discourses render them problematic because they individualize what are social problems. Secondly, these discourses, despite being seen as inherently liberatory are conceptually dependent on a notion of deficit in that talk of “positives” and “strengths” requires the existence of “negatives” and “weaknesses” for these concepts to make sense.  We argue that this does little to substantially transform dominant understandings of psychological distress. Thirdly, these issues combine to impact upon the progressive potential of recovery. It comes to be seen as an individualistic experiential narrative accompaniment to medical understandings where the structural causes of distress are obscured. This in turn impacts upon the potential for recovery to be used to explore more collective, political aspects of emotional distress. Drawing on the work of Fraser, we use this critique to characterize “recovery” as a “struggle for

  1. CRISIS FOCUS: Risks to Recovery

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    A sustained recovery of the global economy at a slow but steady pace should be expected in the first quarter of 2010, according to the quarterly report on global economic and financial outlook compiled by the International Finance Research Institute of the Bank of China. But three risks stand out, the report said, that threaten recovery efforts: the sovereign credit crisis, growing inflation pressures and increasing numbers of small and medium-sized U.S. banks filing for bankruptcy.

  2. Potential for domestic heat recovery

    Science.gov (United States)

    Feldman, K. T., Jr.; Tsai, G. J.

    1981-11-01

    The potential for reducing gas-fired heating costs by the use of waste heat is discussed. A heat recovery heat exchanger can be installed to recover waste heat from the hot exhaust gases going up the flue pipe from a furnace, water heater, or clothes dryer. Some specific designs are described for heat recovery equipment. Specific design and performance of the Hallofin heat exchanger and the heat pipe heat exchanger are evaluated.

  3. Wearable Sensors for Chemical & Biological Detection

    Energy Technology Data Exchange (ETDEWEB)

    Ozanich, Richard M.

    2017-08-31

    One of PNNL’s strengths is the ability to conduct comprehensive technology foraging and objective assessments of various technology areas. The following examples highlight leading research by others in the area of chemical and biological (chem/bio) detection that could be further developed into a robust, highly integrated wearables to aid preparedness, response and recovery.

  4. Agricultural utilization of sewage sludge: effect on the chemical and physical properties of soils and on the productivity and recovery of degraded areas/ Uso agrícola do lodo de esgoto: influência nas propriedades químicas e físicas do solo, produtividade e recuperação de áreas degradadas

    Directory of Open Access Journals (Sweden)

    João Tavares Filho

    2006-07-01

    Full Text Available This study is an overview of the agricultural recycling of sewage sludge and its impact on the chemical and physical properties of soils and on the productivity and recovery of degraded areas. Sewage sludge contains some of the essential plant nutrients (nitrogen, phosphorous, and micronutrients; it also has variable humidity content and is rich in organic matter. Sewage sludge also acts as a soil conditioner, improving soil structure and aggregation, thus decreasing density and increasing aeration of soils.Sewage sludge can complement other crop fertilization techniques by reducing the use of chemical fertilizers and fertilization costs as it increases nutrient availability in soils. As a result, the sludge can enhance plant development and productivity. Sludge application in degraded areas leads to a rapid growth of gramineous and leguminous plants. Plants growing in sludge-applied areas tend to be more vigorous and to cover larger areas (percentage; they also tend to have higher productivity and a better development of the root system. Soil recovery by liming and mineral fertilization can also lead to vegetation regrowth; however, the poor physical and biological soil conditions can deteriorate the cover plants before the soil is actually recovered. Sewage sludge must be processed before being used and cannot be applied directly to agricultural or forested land until biological treatments reduce the sludge organic content and promote organic matter stabilization. In the State of Paraná, Brazil, the direct application of sewage sludge on horticultural and other products that are ingested raw, is not recommended. Sludge fertilization is recommended for corn, wheat, sugarcane, sorghum, fruitiferous plants, and for forest plant species used to recover degraded areas. State regulations determine the levels of heavy metals allowed in the sludge and the maximum dosage of 50 ton biosolid matter/ha, for a 10-year period.Objetivou-se com esta revis

  5. Developing a Regional Recovery Framework

    Energy Technology Data Exchange (ETDEWEB)

    Lesperance, Ann M.; Olson, Jarrod; Stein, Steven L.; Clark, Rebecca; Kelly, Heather; Sheline, Jim; Tietje, Grant; Williamson, Mark; Woodcock, Jody

    2011-09-01

    Abstract A biological attack would present an unprecedented challenge for local, state, and federal agencies; the military; the private sector; and individuals on many fronts ranging from vaccination and treatment to prioritization of cleanup actions to waste disposal. To prepare the Seattle region to recover from a biological attack, the Seattle Urban Area Security Initiative (UASI) partners collaborated with military and federal agencies to develop a Regional Recovery Framework for a Biological Attack in the Seattle Urban Area. The goal was to reduce the time and resources required to recover and restore wide urban areas, military installations, and other critical infrastructure following a biological incident by providing a coordinated systems approach. Based on discussions in small workshops, tabletop exercises, and interviews with emergency response agency staff, the partners identified concepts of operation for various areas to address critical issues the region will face as recovery progresses. Key to this recovery is the recovery of the economy. Although the Framework is specific to a catastrophic, wide-area biological attack using anthrax, it was designed to be flexible and scalable so it could also serve as the recovery framework for an all-hazards approach. The Framework also served to coalesce policy questions that must be addressed for long-term recovery. These questions cover such areas as safety and health, security, financial management, waste management, legal issues, and economic development.

  6. Global patterns of drought recovery

    Energy Technology Data Exchange (ETDEWEB)

    Schwalm, Christopher R.; Anderegg, William; Michalak, A. M.; Fisher, J.B.; Biondi, Franco; Koch, George; Litvak, Marcy; Ogle, Kiona; Shaw, John D.; Wolf, Adam; Huntzinger, Deborah; Schaefer, Kevin; Cook, R. B.; Wei, Yaxing; Fang, Yuanyuan; Hayes, Daniel J.; Huang, Maoyi; Jain, Atul K.; Tian, Hanqin

    2017-08-09

    Drought is a recurring multi-factor phenomenon with major impacts on natural and human systems1-3. Drought is especially important for land carbon sink variability, influencing climate regulation of the terrestrial biosphere4. While 20th Century trends in drought regime are ambiguous, “more extreme extremes” as well as more frequent and severe droughts3,7 are expected in the 21st Century. Recovery time, the length of time an ecosystem requires to revert to its pre-drought functional state, is a critical metric of drought impact. Yet the spatiotemporal patterning and controls of drought recovery are largely unknown. Here we use three distinct global datasets of gross primary productivity to show that across diverse terrestrial ecosystems drought recovery times are driven by biological productivity and biodiversity, with drought length and severity of secondary importance. Recovery time, especially for extreme droughts, and the areal extent of ecosystems in recovery from drought generally increase over the 20th Century, supporting an increase globally in drought impact8. Our results indicate that if future Anthropocene droughts become more widespread as expected, that droughts will become more frequent relative to recovery time. This increases the risk of entering a new regime where vegetation never recovers to its original state and widespread degradation of the land carbon sink ensues.

  7. Chemical Mahjong

    Science.gov (United States)

    Cossairt, Travis J.; Grubbs, W. Tandy

    2011-01-01

    An open-access, Web-based mnemonic game is described whereby introductory chemistry knowledge is tested using mahjong solitaire game play. Several tile sets and board layouts are included that are themed upon different chemical topics. Introductory tile sets can be selected that prompt the player to match element names to symbols and metric…

  8. Chemical dispersants

    NARCIS (Netherlands)

    Rahsepar, Shokouhalsadat; Smit, Martijn P.J.; Murk, Albertinka J.; Rijnaarts, Huub H.M.; Langenhoff, Alette A.M.

    2016-01-01

    Chemical dispersants were used in response to the Deepwater Horizon oil spill in the Gulf of Mexico, both at the sea surface and the wellhead. Their effect on oil biodegradation is unclear, as studies showed both inhibition and enhancement. This study addresses the effect of Corexit on oil biodeg

  9. Chemical dispersants

    NARCIS (Netherlands)

    Rahsepar, Shokouhalsadat; Smit, Martijn P.J.; Murk, Albertinka J.; Rijnaarts, Huub H.M.; Langenhoff, Alette A.M.

    2016-01-01

    Chemical dispersants were used in response to the Deepwater Horizon oil spill in the Gulf of Mexico, both at the sea surface and the wellhead. Their effect on oil biodegradation is unclear, as studies showed both inhibition and enhancement. This study addresses the effect of Corexit on oil

  10. Potential metal recovery from waste streams

    Science.gov (United States)

    Smith, Kathleen S.; Hageman, Philip L.; Plumlee, Geoffrey S.; Budahn, James R.; Bleiwas, Donald I.

    2015-01-01

    ‘Waste stream’ is a general term that describes the total flow of waste from homes, businesses, industrial facilities, and institutions that are recycled, burned or isolated from the environment in landfills or other types of storage, or dissipated into the environment. The recovery and reuse of chemical elements from waste streams have the potential to decrease U.S. reliance on primary resources and imports, and to lessen unwanted dispersion of some potentially harmful elements into the environment. Additional benefits might include reducing disposal or treatment costs and decreasing the risk of future environmental liabilities for waste generators. Elemental chemistry and mineralogical residences of the elements are poorly documented for many types of waste streams.

  11. Reservoir characterization and enhanced oil recovery research

    Energy Technology Data Exchange (ETDEWEB)

    Lake, L.W.; Pope, G.A.; Schechter, R.S.

    1992-03-01

    The research in this annual report falls into three tasks each dealing with a different aspect of enhanced oil recovery. The first task strives to develop procedures for accurately modeling reservoirs for use as input to numerical simulation flow models. This action describes how we have used a detail characterization of an outcrop to provide insights into what features are important to fluid flow modeling. The second task deals with scaling-up and modeling chemical and solvent EOR processes. In a sense this task is the natural extension of task 1 and, in fact, one of the subtasks uses many of the same statistical procedures for insight into the effects of viscous fingering and heterogeneity. The final task involves surfactants and their interactions with carbon dioxide and reservoir minerals. This research deals primarily with phenomena observed when aqueous surfactant solutions are injected into oil reservoirs.

  12. Enhanced Oil Recovery: An Update Review

    Directory of Open Access Journals (Sweden)

    Vladimir Alvarado

    2010-08-01

    Full Text Available With the decline in oil discoveries during the last decades it is believed that EOR technologies will play a key role to meet the energy demand in years to come. This paper presents a comprehensive review of EOR status and opportunities to increase final recovery factors in reservoirs ranging from extra heavy oil to gas condensate. Specifically, the paper discusses EOR status and opportunities organized by reservoir lithology (sandstone and carbonates formations and turbiditic reservoirs to a lesser extent and offshore and onshore fields. Risk and rewards of EOR methods including growing trends in recent years such as CO2 injection, high pressure air injection (HPAI and chemical flooding are addressed including a brief overview of CO2-EOR project economics.

  13. "Smart" Multifunctional Polymers for Enhanced Oil Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Charles McCormick; Andrew Lowe

    2007-03-20

    Recent recommendations made by the Department of Energy, in conjunction with ongoing research at the University of Southern Mississippi, have signified a need for the development of 'smart' multi-functional polymers (SMFPs) for Enhanced Oil Recovery (EOR) processes. Herein we summarize research from the period of September 2003 through March 2007 focusing on both Type I and Type II SMFPs. We have demonstrated the synthesis and behavior of materials that can respond in situ to stimuli (ionic strength, pH, temperature, and shear stress). In particular, Type I SMFPs reversibly form micelles in water and have the potential to be utilized in applications that serve to lower interfacial tension at the oil/water interface, resulting in emulsification of oil. Type II SMFPs, which consist of high molecular weight polymers, have been synthesized and have prospective applications related to the modification of fluid viscosity during the recovery process. Through the utilization of these advanced 'smart' polymers, the ability to recover more of the original oil in place and a larger portion of that by-passed or deemed 'unrecoverable' by conventional chemical flooding should be possible.

  14. Permeability recovery of damaged water sensitive core using ultrasonic waves.

    Science.gov (United States)

    Khan, Nasir; Pu, Chunsheng; Li, Xu; He, Yanlong; Zhang, Lei; Jing, Cheng

    2017-09-01

    It is imperative to recover the well productivity lose due to formation damage nearby wellbore during variant well operations. Some indispensable issues in conventional techniques make ultrasonic technology more attractive due to simple, reliable, favorable, cost-effective, and environment friendly nature. This study proposes the independent and combined use of ultrasonic waves and chemical agents for the treatment of already damaged core samples caused by exposure to distilled water. Results elucidate that ultrasonic waves with optimum (20kHz, 1000W) instead of maximum frequency and power worked well in the recovery owing to peristaltic transport caused by matching of natural frequency with acoustic waves frequency. In addition, hundred minutes was investigated as optimum irradiation time which provided ample time span to detach fine loosely suspended particles. However, further irradiation adversely affected the damaged permeability recovery. Moreover, permeability improvement attributes to cavitation due to ultrasonic waves propagation through fluid contained in porous medium and thermal energy generated by three different ways. Eventually, experimental outcomes indicated that maximum (25.3%) damaged permeability recovery was witnessed by applying ultrasonic waves with transducer #2 (20kHz and 1000W) and optimum irradiation timeframe (100min). This recovery was further increased to 45.8% by applying chemical agent and optimum ultrasonic waves simultaneously. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Natural thorium resources and recovery: Options and impacts

    Science.gov (United States)

    Ault, Timothy; Van Gosen, Bradley S.; Krahn, Steven; Croff, Allen

    2016-01-01

    This paper reviews the front end of the thorium fuel cycle, including the extent and variety of thorium deposits, the potential sources of thorium production, and the physical and chemical technologies required to isolate and purify thorium. Thorium is frequently found within rare earth element–bearing minerals that exist in diverse types of mineral deposits, often in conjunction with other minerals mined for their commercial value. It may be possible to recover substantial quantities of thorium as a by-product from active titanium, uranium, tin, iron, and rare earth mines. Incremental physical and chemical processing is required to obtain a purified thorium product from thorium minerals, but documented experience with these processes is extensive, and incorporating thorium recovery should not be overly challenging. The anticipated environmental impacts of by-product thorium recovery are small relative to those of uranium recovery since existing mining infrastructure utilization avoids the opening and operation of new mines and thorium recovery removes radionuclides from the mining tailings.

  16. Loop transfer recovery for general observer architecture

    DEFF Research Database (Denmark)

    Niemann, Hans Henrik; Søgaard-Andersen, Per; Stoustrup, Jakob

    1991-01-01

    A general and concise formulation is given of the loop transfer recovery (LTR) design problem based on recovery errors. Three types of recovery errors are treated: open loop recovery, sensitivity recovery and input-output recovery errors. The three corresponding versions of the asymptotic recovery...... recovery cases. This general recovery formulation covers all known observer based compensator types as special cases. The conditions given in this setting are effectively the aim of all known LTR design methods. The recovery formulation is interpreted in terms of a modelmatching problem as well, which...... is examined by means of the Q-parametrization. It is shown how the general controller obtained by the Q-parametrization can be written as a Luenberger observer based controller. In all cases, n controller states suffice to achieve recovery. The compensators are characterized for errors both on the input...

  17. The Design and Verification of Disaster Recovery Strategies in Cloud Disaster Recovery Center

    Directory of Open Access Journals (Sweden)

    Gang Li

    2013-10-01

    Full Text Available  Disaster recovery is an important means to ensure business continuity. However, the disaster recovery investment is so huge that the cloud disaster recovery becomes a best choice for enterprises, especially for SMEs. This paper discusses the necessity and importance of the cloud disaster recovery center and the vital indicators of disaster recovery by analyzing the classification and selecting principle of cloud disaster recovery strategy, developing disaster recovery strategy based on major disaster recovery strategy finally. In the end, this paper verifies the feasibility of the disaster recovery strategy by two specific cases of disaster recovery implementation.

  18. Comparison of heat recovery systems in public indoor swimming pools

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R.M. [Istituto di Ingeneria Gestionale, Universita di Padova (Italy); Longo, G.A. [Istituto di Fisica Tecnica, Universita di Padova (Italy)

    1996-07-01

    The heating of swimming pools can be expensive in terms of energy costs and energy-saving measures which are much more effective than the simple recovery of the exhausted air are recommended. A new open-cycle absorption system is presented here, operating by chemical dehumidification on the exhausted air. It allows important energy savings of the same order as the motor-driven heat pump systems, although its technology is in principle simpler and cheaper. (Author)

  19. Optimizing the procedure for mercury recovery from dental amalgam

    Directory of Open Access Journals (Sweden)

    Flávia Godoy Iano

    2008-06-01

    Full Text Available Mercury, as any other heavy metal, may cause environmental damages due to its accumulation and biotransformation. Dental offices, whether private or institutional, use dental amalgam as a restorative material on a daily basis. Dental amalgam is composed of mercury (50%, silver (30% and other metals. Approximately 30% of the amalgam prepared in dental offices (0.6 g per capsule are wasted and inadequately discarded without any treatment. Methods for mercury recovery have been proposed previously, using high temperatures through exposure to direct flame (650°C, long processing time, and hazardous reagents as potassium cyanide. The purpose of this study was to develop a method to replace the direct flame by an electrical mantle in the process of mercury recovery. Results showed an average mercury recovery of 90% from 2 kg of amalgam after 30 minutes of processing time, thus optimizing the procedure. The proposed modifications allowed a significant reduction in processing time and a mercury recovery with high purity. The modified process also provided minimization of operator exposure to physical, chemical and ergonomic hazards, representing a technological advance compared to the risks inherent to the original method. It also provided environmental health and economy of energy resources by replacing a finite energy source (fossil and organic by a more environmentally appropriate electric source, resulting in significant improvement of the procedure for mercury recovery from dental amalgam.

  20. Effects of phosphorus recovery requirements on Swedish sludge management.

    Science.gov (United States)

    Levlin, E; Löwén, M; Stark, K; Hultman, B

    2002-01-01

    Expected requirements of phosphorus recovery, restrictions on sludge disposal on landfill, and difficulties in obtaining consensus on sludge use on agricultural land has led to several development works in Sweden to change sludge management methods. Especially sludge fractionation has gained interest including following steps to recover products and separate transfer of toxic substances into a small stream. Commercial systems are offered based on technology by Cambi/KREPRO and BioCon and other companies and many other methods are under development. Iron salts are widely used in Sweden as precipitation agents for phosphorus removal and this technology has some disadvantages for phosphorus recovery compared with the use of biological phosphorus removal. The amount of chemicals needed for a KREPRO or a BioCon system was calculated for a treatment plant which has an addition of iron salt resulting in 1,900 mole Fe per tonne DS. The result was compared with the chemical consumption of recovery systems installed at plants with lower use of iron for precipitation. The chemical consumption in equivalents per tonne DS was found to be 5,000 + 6,000 * (molar ratio iron to phosphorus).

  1. (Chemical thermodynamics)

    Energy Technology Data Exchange (ETDEWEB)

    Mesmer, R.E.

    1990-09-12

    The purpose of this travel was for the traveler to participate in the 11th IUPAC International Conference on Chemical Thermodynamics and to present a paper of which he is co-author entitled The Transition from Strong-to-Weak Electrolyte Behavior Near the Critical Point of Water'' in the session on Solutions. The conference brought together nearly 500 scientists from around the world to discuss broad aspects of experimental thermodynamics and theoretical modeling. The traveler also visited the University of Karlsruhe to discuss current research with E.U. Franck and his collaborators. This institution has been for many years one of the leading centers for experimental studies on phase equilibrium and physical chemical studies especially on pure substances under the direction of Franck.

  2. Chemicals Industry New Process Chemistry Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2000-08-01

    The Materials Technology I workshop was held in November 1998 to address future research needs for materials technology that will support the chemical industry. Areas covered included disassembly, recovery, reuse and renewable technology; new materials; and materials measurement and characterization. The Materials Technology II workshop was held in September 1999 and covered additives, modeling and prediction and an additional segment on new materials. Materials Technology Institute (MTI) for the Chemical Process Industries, Inc. and Air Products & Chemicals lead the workshops. The Materials Technology Roadmap presents the results from both workshops.

  3. Capacity efficiency of recovery request bundling

    DEFF Research Database (Denmark)

    Ruepp, Sarah Renée; Dittmann, Lars; Berger, Michael Stübert

    2010-01-01

    This paper presents a comparison of recovery methods in terms of capacity efficiency. In particular, a method where recovery requests are bundled towards the destination (Shortcut Span Protection) is evaluated against traditional recovery methods. Our simulation results show that Shortcut Span...... Protection uses more capacity than the unbundled related methods, but this is compensated by easier control and management of the recovery actions....

  4. Ecological distribution of pelagic copepods and species relationship to acidification, liming and natural recovery in a boreal area

    OpenAIRE

    Svein Birger WÆRVÅGEN; Jens Petter NILSSEN

    2003-01-01

    Distribution and ecology of pelagic copepods were studied in a boreal area strongly affected by acidification in southern Norway. Differential regional composition of bedrock geology and Quaternary deposits combined with liming have produced aquatic sites with contrasting acidification and recovery histories. The omnivorous species Eudiaptomus gracilis showed a striking ability to tolerate both acidification and chemical recovery. The predominantly carnivorous species Heterocope saliens incre...

  5. Thermal recovery of NIF amplifiers

    Energy Technology Data Exchange (ETDEWEB)

    Sutton, S.; Marshall, C.; Petty, C.; Smith, L.; van Wonterghem, B.; Mills, S.

    1997-02-01

    The issue of thermal recovery of the NIF amplifiers has taken on increased emphasis as program goals move toward increasing the shot rate to once every four hours. This paper addresses the technical issues associated with achieving thermal recovery in the NIF amplifiers. We identify two temperature related thermal recovery quantities: (1) the difference between the average slab temperature and the temperature of other surfaces in the amplifier cavity, and (2) the temperature difference in the slab over the aperture. The first quantity relates to optical disturbances in the gas column in the system, while the second quantity is associated with optical aberrations in the laser media itself. Calculations and experiments are used to quantify recovery criteria, and develop cooling approaches. The cooling approaches discussed are (1) active cooling of the flashlamps with ambient gas and chilled gas, and (2) active cooling of the slab edge cladding. Calculations indicate that the NIF baseline cooling approach of 20 cfm per lamp ambient temperature gas flow in both the central and side flashlamp cassettes is capable of meeting thermal recovery requirements for an 8 hour shot period, while to achieve a 4 hour shot period requires use of chilled gas and edge cladding cooling. In addition, the effect of changing the amplifier cavity and beamtube fill gas from nitrogen to helium is addressed, showing that a factor of 8 reduction in the sensitivity to thermal disturbances is possible. 6 refs., 9 figs., 1 tab.

  6. Individual recovery profiles in basketball players.

    Science.gov (United States)

    Moreno, Jordi; Ramos-Castro, Juan; Rodas, Gil; Tarragó, Joan R; Capdevila, Lluís

    2015-01-01

    In the sport context, recovery has been characterized as a multifactor process (physiological, psychological, behavioral, social, etc.). This study takes a multidisciplinary approach to find psychophysiological markers of the stress-recovery process. It aims to determine how athletes' specific recovery actions relate to their perceptions of recovery, and Heart Rate Variability (HRV). A total of 196 assessments were analyzed from 6 players on a men's professional basketball team within the Liga LEB Oro basketball federation (2012/2013 season). Perceptions of recovery, recovery strategies, and HRV were recorded. The results show a pattern of individual differences in behavior related to athletes' recovery actions and HRV profiles throughout the season (p < .05). Moreover, we observed that each player had different recovery needs. In light of these results, we suggest an individualistic approach to evaluating and monitoring recovery to attend more accurately to each player's recovery needs.

  7. The Role of Attrition and Solids Recovery in a Chemical Looping Combustion Process Effet de l’attrition et de la récupération des particules dans le procédé de combustion en boucle chimique

    Directory of Open Access Journals (Sweden)

    Kramp M.

    2011-05-01

    Full Text Available In the present work, the steady-state behavior of a Chemical Looping Combustion process of interconnected fluidized bed reactors is simulated. The simulations have been carried out in two different scales, 50 kWth and 100 MWth. Attrition model derived from small scale laboratory experiments has been employed for the prediction of the process behavior in terms of attrition and Oxygen Carrier loss. Information on Oxygen Carrier characteristics and reaction kinetics were taken from literature. Realistic circulation mass flows of Oxygen Carrier particles are obtained and Oxygen Carrier losses are quantified. The large scale process looses significantly more Oxygen Carrier than the small scale process based on the same amount of thermal energy produced. Incomplete conversion in the air reactor could be identified as a critical point. Another issue is the fuel gas bypassing the Oxygen Carrier particles through bubbles in the large scale process which leads to lowered fuel conversions. The simulations indicate that a similar performance of a pilot scale and a large scale process is not guaranteed due to the scale-up effect on fluid dynamics. Furthermore, the simulations allow an assessment of the influence of the quality of the solids recovery system on the Oxygen Carrier loss. The distribution of the losses between possible origins is investigated and different changes in the solids recovery system are discussed regarding their potential to decrease the Oxygen Carrier loss. For example, the addition of a second-stage cyclone after the air reactor of the large scale process reduces the Oxygen Carrier loss significantly. Le présent travail propose un modèle de simulation en continu du procédé de combustion en boucle chimique constitué de deux lits fluidisés interconnectés. Les simulations ont été conduites à deux échelles 50 kWth correspondant à une installation pilote et 100 MWth correspondant à une installation industrielle. Un modèle d

  8. Physostigmine in recovery from anaesthesia.

    Science.gov (United States)

    Hamilton-Davies, C; Bailie, R; Restall, J

    1995-05-01

    Intravenous ketamine anaesthesia has been used by the British army in the field for many years. A recognised problem has been the unpredictable recovery profile this produces. We anaesthetised 28 ASA 1 patients using a standard British military technique. At termination of the anaesthetic, half of the patients were given a physostigmine/glycopyrronium mixture and half were given the equivalent volume of saline 0.9%. There was a significant difference between the two groups with regard to recovery times (p < 0.001). There was no significant difference with regard to other variables. In trauma anaesthesia the improved recovery profile from the use of physostigmine following ketamine anaesthesia may lead to earlier evacuation of the patient.

  9. Microbial enhanced oil recovery (MEOR).

    Science.gov (United States)

    Brown, Lewis R

    2010-06-01

    Two-thirds of the oil ever found is still in the ground even after primary and secondary production. Microbial enhanced oil recovery (MEOR) is one of the tertiary methods purported to increase oil recovery. Since 1946 more than 400 patents on MEOR have been issued, but none has gained acceptance by the oil industry. Most of the literature on MEOR is from laboratory experiments or from field trials of insufficient duration or that lack convincing proof of the process. Several authors have made recommendations required to establish MEOR as a viable method to enhance oil recovery, and until these tests are performed, MEOR will remain an unproven concept rather than a highly desirable reality. Copyright 2010 Elsevier Ltd. All rights reserved.

  10. The existential way to recovery.

    Science.gov (United States)

    Moore, Laurie Jo; Goldner-Vukov, Mila

    2009-12-01

    This paper explores the essential features of recovery and the need for an existential approach in psychiatry. The biopsychosocial model often fails to sufficiently validate the existential suffering of patients. We review the major principles of recovery and the philosophical and psychiatric principles of existentialism. The ontological or intrinsic existential issues of death, isolation, freedom and meaninglessness are described and their manifestations are explored in clinical syndromes. When ultimate existential concerns are recognised, patients have an opportunity to understand their life on a deeper level that is not defined as a medical disorder but as a part of human existence. Understanding that existential concerns underlie a great deal of human behaviour helps to free patients from the stigma of psychiatric labels. An existential approach is a humanistic way toward recovery.

  11. Chemical carcinogenesis

    Directory of Open Access Journals (Sweden)

    Paula A. Oliveira

    2007-12-01

    Full Text Available The use of chemical compounds benefits society in a number of ways. Pesticides, for instance, enable foodstuffs to be produced in sufficient quantities to satisfy the needs of millions of people, a condition that has led to an increase in levels of life expectancy. Yet, at times, these benefits are offset by certain disadvantages, notably the toxic side effects of the chemical compounds used. Exposure to these compounds can have varying effects, ranging from instant death to a gradual process of chemical carcinogenesis. There are three stages involved in chemical carcinogenesis. These are defined as initiation, promotion and progression. Each of these stages is characterised by morphological and biochemical modifications and result from genetic and/or epigenetic alterations. These genetic modifications include: mutations in genes that control cell proliferation, cell death and DNA repair - i.e. mutations in proto-oncogenes and tumour suppressing genes. The epigenetic factors, also considered as being non-genetic in character, can also contribute to carcinogenesis via epigenetic mechanisms which silence gene expression. The control of responses to carcinogenesis through the application of several chemical, biochemical and biological techniques facilitates the identification of those basic mechanisms involved in neoplasic development. Experimental assays with laboratory animals, epidemiological studies and quick tests enable the identification of carcinogenic compounds, the dissection of many aspects of carcinogenesis, and the establishment of effective strategies to prevent the cancer which results from exposure to chemicals.A sociedade obtém numerosos benefícios da utilização de compostos químicos. A aplicação dos pesticidas, por exemplo, permitiu obter alimento em quantidade suficiente para satisfazer as necessidades alimentares de milhões de pessoas, condição relacionada com o aumento da esperança de vida. Os benefícios estão, por

  12. From recovery values to recovery-oriented practice?

    DEFF Research Database (Denmark)

    Dalum, Helle; Pedersen, Inge Kryger; Cunningham, Harry

    2015-01-01

    with mental illness; “A New Focus in the Dialogue With Clients” thematizes how the HCPs focus more on the individual's own goal for recovery rather than disease-induced goals in the dialog with clients; “A Person-Centered Role” comprises a shift in the professional role whereby the HCPs value the client's own...

  13. Lower Bounds for Sparse Recovery

    CERN Document Server

    Ba, Khanh Do; Price, Eric; Woodruff, David P

    2011-01-01

    We consider the following k-sparse recovery problem: design an m x n matrix A, such that for any signal x, given Ax we can efficiently recover x' satisfying ||x-x'||_1 <= C min_{k-sparse} x"} ||x-x"||_1. It is known that there exist matrices A with this property that have only O(k log (n/k)) rows. In this paper we show that this bound is tight. Our bound holds even for the more general /randomized/ version of the problem, where A is a random variable and the recovery algorithm is required to work for any fixed x with constant probability (over A).

  14. The Vessel Schedule Recovery Problem

    DEFF Research Database (Denmark)

    Brouer, Berit Dangaard; Plum, Christian Edinger Munk; Vaaben, Bo;

    Maritime transportation is the backbone of world trade and is accountable for around 3% of the worlds CO2 emissions. We present the Vessel Schedule Recovery Problem (VSRP) to evaluate a given disruption scenario and to select a recovery action balancing the trade off between increased bunker cons...... consumption and the impact on the remaining network and the customer service level. The model is applied to 4 real cases from Maersk Line. Solutions are comparable or superior to those chosen by operations managers. Cost savings of up to 58% may be achieved....

  15. Mental health recovery and quilting

    DEFF Research Database (Denmark)

    Wilson, Rhonda Lynne

    2014-01-01

    recovery environment might be fostered within the broader community. The goals of the project were to reduce mental health stigma and to foster recovery. This was achieved as a mental health nurse, quilt maker, and a team of sewers came together to produce a quilt as a tangible expression of care...... and support for both the quilt recipient and each other. This project, as a case study, demonstrates how a church faith community and mental health care can be combined and yield positive outcomes. This article outlines how the project proceeded and presents the results of a post-project evaluation survey....

  16. Scaling up of renewable chemicals.

    Science.gov (United States)

    Sanford, Karl; Chotani, Gopal; Danielson, Nathan; Zahn, James A

    2016-04-01

    The transition of promising technologies for production of renewable chemicals from a laboratory scale to commercial scale is often difficult and expensive. As a result the timeframe estimated for commercialization is typically underestimated resulting in much slower penetration of these promising new methods and products into the chemical industries. The theme of 'sugar is the next oil' connects biological, chemical, and thermochemical conversions of renewable feedstocks to products that are drop-in replacements for petroleum derived chemicals or are new to market chemicals/materials. The latter typically offer a functionality advantage and can command higher prices that result in less severe scale-up challenges. However, for drop-in replacements, price is of paramount importance and competitive capital and operating expenditures are a prerequisite for success. Hence, scale-up of relevant technologies must be interfaced with effective and efficient management of both cell and steel factories. Details involved in all aspects of manufacturing, such as utilities, sterility, product recovery and purification, regulatory requirements, and emissions must be managed successfully.

  17. Chemical cosmology

    CERN Document Server

    Boeyens, Jan CA

    2010-01-01

    The composition of the most remote objects brought into view by the Hubble telescope can no longer be reconciled with the nucleogenesis of standard cosmology and the alternative explanation, in terms of the LAMBDA-Cold-Dark-Matter model, has no recognizable chemical basis. A more rational scheme, based on the chemistry and periodicity of atomic matter, opens up an exciting new interpretation of the cosmos in terms of projective geometry and general relativity. The response of atomic structure to environmental pressure predicts non-Doppler cosmical redshifts and equilibrium nucleogenesis by alp

  18. Recovery of mineral oil from waste emulsion using electrocoagulation method

    Directory of Open Access Journals (Sweden)

    Razali Mohd Najib

    2016-01-01

    Full Text Available This paper presents a research to recover mineral oil from industrial waste emulsion. This research also evaluates the standard of water produced after the oil recovery. The ecosystem could be polluted if this waste is not treated prior to discharge. The equipment needed for this experiment is power supply (generator, connecting wire and metal plate for providing the coagulant. The chosen plates were aluminium and iron plate. The power supply will be connected to the plate producing anode (positive terminal and cathode (negative terminal. Both plates are immersed into a beaker containing waste emulsion. The charge supplied by the current will cause the aluminium or ferum to dissisipate and became ions. These ions will attract the oil to flock together and float at the surface. The water will then filter by using filter paper. Electrocoagulation was done without addition of chemical thus can prevent the hazard from the chemicals. The samples was sent for oil and grease test. The optimum time needed for recovery of oil was 3 hours. The percentage recovery reach constant trend of 95% afterwards. When the power consumption increases, the percentage recovery also increases. However, the current should be lower than 0.5 ampere as it is the limit that human body can withstand. Thus, power consumption of 27.5 Watt was chosen as optimum value. The oil recovery of at power consumption at 27.5W is 96%. The best plate in the process was the aluminium pair which can recover more than ferum plate. The present work concludes the promising future for waste water treatment by usage of electrocoagulation technique.

  19. 化学去细胞异体神经周围复合BMSCs生物蛋白胶复合物促周围神经缺损修复%EFFECT OF CHEMICAL EXTRACTED ACELLULAR NERVE ALLOGRAFT SUPPLEMENTING WITH BONE MARROW MESENCHYMAL STEM CELLS EMBEDDED IN FIBRIN GLUE ON FUNCTIONAL RECOVERY OF TRANSECTED SCIATIC NERVES

    Institute of Scientific and Technical Information of China (English)

    赵喆; 许文静; 卢世璧; 王玉; 彭江; 赵斌; 赵庆; 刘炎; 任志午; 詹胜峰; 张莉

    2011-01-01

    目的 将BMSCs复合在化学去细胞异体神经(chemical extracted acellular nerve allograft,CEANA)周围,观察对CEANA修复周围神经缺损效果的影响.方法 成年雄性C57小鼠21只,体重25~30 g;成年雄性Balb/c小鼠15只,体重25~30 g.取Balb/c小鼠双侧坐骨神经,制备CEANA.取C57小鼠3只,分离培养BMSCs,取5 x 106个第3代BMSCs添加到500μL生物蛋白胶制备BMSCs生物蛋白胶复合物,共培养3、7、14、21 d后,分别取其上清与PC12细胞共培养,观察对PC12细胞的影响.取成年雄性C57小鼠18只,制备小鼠左侧坐骨神经10mm缺损模型,随机分成3组(n=6),分别采用自体神经移植复合生物蛋白胶(A组)、CEANA移植复合BMSCs生物蛋白胶复合物(B组)、CEANA移植复合生物蛋白胶(C组)修复坐骨神经缺损;实验动物右侧切开暴露坐骨神经,作为正常对照.术后行大体观察;术前及术后2、4、6、8周测量小鼠坐骨神经指数(static sciatic index,SSI);术后8周取材计算术侧小腿三头肌湿重恢复率并行小腿三头肌Masson染色观察,吻合口远端神经行甲苯胺蓝染色和透射电镜观察.结果 BMSCs在生物蛋白胶内均匀分布,外观呈球形,培养3d后可见BMSCs呈多个长突起.加入BMSCs生物蛋白胶复合物共培养3、7、14、21 d的上清,PC12细胞均分化为类神经元样细胞.术后各组动物切口愈合良好.各组SSI随时间延长逐渐增加,术后4、6、8周A组SSI均高于B、C组,差异有统计学意义(P0.05).术后8周,B组小腿三头肌湿重恢复率、有髓神经纤维总数均优于C组,但较A组差,差异有统计学意义(P0.05).结论 在CEANA周围添加BMSCs生物蛋白胶复合物可提高周围神经损伤修复效果.%Objective To investigate the effect of bone marrow mesenchymal stem cells (BMSCs) embedded in fibrin glue around chemical extracted acellular nerve allograft (CEANA) on the peripheral nerve regeneration. Methods Twenty-one adult male C57 mice (weighing 25-30 g

  20. Assessment of susceptibility to pollution in littoral waters using the concept of recovery time.

    Science.gov (United States)

    Gómez, Aina G; Juanes, José A; Ondiviela, Bárbara; Revilla, José A

    2014-04-15

    Susceptibility to pollution can be related to the flushing capacity of aquatic systems. Transport time scales constitute a useful tool for representing the water exchange and transport processes. A new transport time scale, recovery time, and a methodology to estimate it by means of numerical models is hereby developed. Recovery time, calculated in Gijon, Santander and Tarragona harbours, is significantly related to physical, chemical and biological water quality indicators. Susceptibility, assessed through recovery time values, provides spatial patterns of expected flushing capacity, being sensitive to physical and hydrodynamic characteristics. The developed method is appropriate to estimate recovery time and assess susceptibility against pollution in littoral waters having great potential to be applied to different disciplines. Recovery time could be used in littoral waters as a surrogate of water quality indicators, to establish efficient monitoring programs, to define and characterize modified water bodies or to improve the design of marine infrastructures.

  1. Development of alkaline/surfactant/polymer (ASP flooding technology for recovery of Karazhanbas oil

    Directory of Open Access Journals (Sweden)

    Birzhan Zhappasbaev

    2016-03-01

    Full Text Available The tertiary oil recovery methods like alkaline, surfactant and polymer (ASP flooding are very perspective in order to achieve the synergetic effect out of the different impacts which are caused by these chemicals, which affect oil and water filtration in the reservoir and increase oil recovery. In this communication, we consider the applicability of hydrophobically modified polyampholyte – poly(hexadecylaminocrotonatebetaine (PHDACB as ASP flooding agent for recovery of oil from Karazhanbas oilfield. As “polysoap”, the aqueous solution of PHDACB dissolved in aqueous KOH was used. This system combines the advantages of alkaline, surfactant and polymer and exhibits the synergistic effect. The laboratory results showed that the ASP flooding considerably increases the oil recovery in addition to water flooding. In perspective, the ASP flooding may substitute the steam injection and other thermal enhanced oil recovery (EOR technologies.

  2. Multimodal approach to postoperative recovery

    DEFF Research Database (Denmark)

    Kehlet, Henrik

    2009-01-01

    PURPOSE OF REVIEW: To provide updated information on recent developments within individual components of multimodal interventions to improve postoperative outcome (fast-track methodology). RECENT FINDINGS: The value of the fast-track methodology to improve recovery and decrease hospital stay...

  3. Recovery mechanisms in nanostructured aluminium

    DEFF Research Database (Denmark)

    Yu, Tianbo; Hansen, Niels; Huang, Xiaoxu

    2012-01-01

    Commercial purity aluminium (99.5%) has been cold rolled to a true strain of 5.5 (99.6% reduction in thickness). The material is very strong but low temperature recovery may be a limiting factor. This has been investigated by isothermal annealing treatments in the temperature range 5–100C. Hardness...

  4. Indirect effects of recovery strategies

    DEFF Research Database (Denmark)

    Andersen, Ken Haste; Rice, Jake

    in isolation,but the expected consequences for the rest of the ecosystem must be analyzed. We use ageneral size- and trait-based model to calculate the ecosystem effects of fishing andrecovery. We present a general analysis of a recovery strategies targeting either large fishes(consumer fishery), small fishes...

  5. Notation-Parametric Grammar Recovery

    NARCIS (Netherlands)

    Zaytsev, V.; Sloane, A.M.; Andova, S.

    2012-01-01

    Automation of grammar recovery is an important research area that received attention over the last decade and a half. Given the abundance of available documentation for software languages that is only going to keep increasing in the future, there is need for reliable extraction techniques that allow

  6. Recovery Rate of Clustering Algorithms

    NARCIS (Netherlands)

    Li, Fajie; Klette, Reinhard; Wada, T; Huang, F; Lin, S

    2009-01-01

    This article provides a simple and general way for defining the recovery rate of clustering algorithms using a given family of old clusters for evaluating the performance of the algorithm when calculating a family of new clusters. Under the assumption of dealing with simulated data (i.e., known old

  7. Notation-Parametric Grammar Recovery

    NARCIS (Netherlands)

    V. Zaytsev (Vadim); A.M. Sloane; S. Andova

    2012-01-01

    htmlabstractAutomation of grammar recovery is an important research area that received attention over the last decade and a half. Given the abundance of available documentation for software languages that is only going to keep increasing in the future, there is need for reliable extraction

  8. Enzyme recovery using reversed micelles.

    NARCIS (Netherlands)

    Dekker, M.

    1990-01-01

    The objective of this study was to develop a liquid-liquid extraction process for the recovery of extracellular enzymes. The potentials of reaching this goal by using reversed micelles in an organic solvent have been investigated.Reversed micelles are aggregates of surfactant molecules containing an

  9. Recovery of precious metals from industrial wastes using membrane separation

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Jin Ki; Lee, Jae Chun; Youn, In Ju [Korea Inst. of Geology Mining and Materials, Taejon (Korea, Republic of)

    1995-12-01

    The purpose of the research is to develop a membrane technology for the recovery of Au by the concentration of used cyanide solution. Au and Ag have been widely used in various advanced technology due to their excellent physical and chemical properties. In most of their application, they were electrodeposited in the cyanide solution. The solution was also used as an etchant for the decorative gold alloys such as 14 K and 18 K. Due to the expanding related industry, the amount of used cyanide solution has been greatly increased. The used solution normally contains about 1-3 g/1 of Au. Due to their high prices various separation method has been developed and commercialized for long time. The concentration method which removes water offers various advantages like the reduction of used solution, the needless of additional cyanide, and the increase in the recovery rate. The main objective of the study was laid in the development of an economical recovery process for precious metals including Au from used cyanide solution. To achieve this goal related processes were reviewed comprehensively focussing on the membrane process and the concentration process. The feasibility of membrane process was evaluated by the measurement of separation efficiency and concentration efficiency of cyanide. In addition, various CN analysis was compared in order to develop a simple and routine procedure for future experiment. The process does not require additional cyanide and thus prevents further environmental contamination. It is economical because the recovery can be increased by the concentration of the solution during the recovery process. In addition, it can be applied to other metals waste system due to the reduced recovery process by concentration. The used water can also be reused. (author). 23 refs., 16 figs., 5 tabs.

  10. Recovery technologies for building materials

    Science.gov (United States)

    Karu, Veiko; Nurme, Martin; Valgma, Ingo

    2015-04-01

    Mining industry provides building materials for construction. Civil engineers have settled the quality parameters for construction materials. When we produce high quality building materials from carbonate rock (limestone, dolostone), then the estimated waste share is 25% to 30%, depending on crushing principles and rock quality. The challenge is to find suitable technology for waste recovery. During international mining waste related cooperation project MIN-NOVATION (www.min-novation.eu), partners mapped possibilities for waste recovery in mining industry and pointed out good examples and case studies. One example from Estonia showed that when we produce limestone aggregate, then we produce up to 30% waste material (fines with size 0-4mm). This waste material we can see as secondary raw material for building materials. Recovery technology for this fine grained material has been achieved with CDE separation plant. During the process the plant washes out minus 63 micron material from the limestone fines. This technology allows us to use 92% of all limestone reserves. By-product from 63 microns to 4 mm we can use as filler in concrete or as fine limestone aggregate for building or building materials. MIN-NOVATION project partners also established four pilot stations to study other mineral waste recovery technologies and solutions. Main aims on this research are to find the technology for recovery of mineral wastes and usage for new by-products from mineral mining waste. Before industrial production, testing period or case studies are needed. This research is part of the study of Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/

  11. Uses and abuses of recovery: implementing recovery-oriented practices in mental health systems

    OpenAIRE

    Slade, Mike; Amering, M.; FARKAS, MARIANNE; Hamilton, Bridget; O'Hagan, Mary; Panther, Gavin; Perkins, Rachel; Shepherd, Geoff; Tse, Samson; Whitley, R.

    2014-01-01

    An understanding of recovery as a personal and subjective experience has emerged within mental health systems. This meaning of recovery now underpins mental health policy in many countries. Developing a focus on this type of recovery will involve transformation within mental health systems. Human systems do not easily transform. In this paper, we identify seven mis-uses (“abuses”) of the concept of recovery: recovery is the latest model; recovery does not apply to “my” patients; services can ...

  12. Chemical Analyses

    Science.gov (United States)

    Bulluck, J. W.; Rushing, R. A.

    1994-01-01

    As a preliminary study on the effects of chemical aging of polymer materials MERL and TRI have examined two polymeric materials that are typically used for offshore umbilical applications. These two materials were Tefzel, a copolymer of ethylene and tetrafluoroethylene, and Coflon, polyvinylidene fluoride. The Coflon specimens were cut from pipe sections and exposed to H2S at various temperatures and pressures. One of these specimens was tested for methane permeation, and another for H2S permeation. The Tefzel specimens were cut from .05 mm sheet stock material and were exposed to methanol at elevated temperature and pressure. One of these specimens was exposed to methanol permeation for 2 days at 100 C and 2500 psi. An additional specimen was exposed to liquid methanol for 3 days at 150 C and 15 Bar. Virgin specimens of each material were similarly prepared and tested.

  13. Defining recovery in adult bulimia nervosa.

    Science.gov (United States)

    Yu, Jessica; Agras, W Stewart; Bryson, Susan

    2013-01-01

    To examine how different definitions of recovery lead to varying rates of recovery, maintenance of recovery, and relapse in bulimia nervosa (BN), end-of-treatment (EOT) and follow-up data were obtained from 96 adults with BN. Combining behavioral, physical, and psychological criteria led to recovery rates between 15.5% and 34.4% at EOT, though relapse was approximately 50%. Combining these criteria and requiring abstinence from binge eating and purging when defining recovery may lead to lower recovery rates than those found in previous studies; however, a strength of this definition is that individuals who meet this criteria have no remaining disordered behaviors or symptoms.

  14. Enzymes for Enhanced Oil Recovery (EOR)

    Energy Technology Data Exchange (ETDEWEB)

    Nasiri, Hamidreza

    2011-04-15

    enzymes on interactions in the oil/brine/solid system was studied. It was found that enzymes can change the adhesion behavior of the crude oil on glass surfaces from adhesion to non-adhesion when they are added to the brine solution. This was confirmed by contact angle measurements, which showed that contact angles became more water-wet (i.e. decreased) after exposure to enzyme solutions. Possible mechanisms giving rise to these observations, including catalysis of ester hydrolysis and enzyme adsorption, were discussed and tested. An experimental study of changes in oil-water interfacial properties by addition of enzymes and proteins, including measurements of interfacial tension and electrophoretic mobility, has been performed. It was found that the effect of enzymes on oil-water properties is minor compared to their effect on oil-water-solid properties. Their contribution to change interfacial tension between oil and water is not significant while they affect the electrophoretic mobility of emulsified oil in enzyme-brine solution to some extent. Attempts were also made to study changes in both oil and water phase composition after equilibration with enzymes. However, since the chemical composition of crude oil is highly complex, a model oil was used in some of the experiments. The model oil was chosen to be a water insoluble ester (ethyl decanoate) solved in mineral oil in an effort to verify the possible role of catalysis of ester hydrolysis. Dynamic core displacements using sandstone and carbonate rocks were conducted to show the potential of improved oil recovery by enzyme- and combined enzyme-surfactant flooding. Most of the core flooding experiments commenced with water flooding from initial water saturation, Swi, (established with synthetic sea water) which will be referred to as secondary mode displacements. Accordingly, tertiary oil recovery processes were used to describe injection of enzyme and/or enzyme-surfactant solutions from residual oil saturation, Sor

  15. Actinide recovery using aqueous biphasic extraction: Initial developmental studies

    Energy Technology Data Exchange (ETDEWEB)

    Chaiko, D.J.; Mensah-Biney, R.; Mertz, C.J.; Rollins, A.N.

    1992-08-01

    Aqueous biphasic extraction systems are being developed to treat radioactive wastes. The separation technique involves the selective partitioning of either solutes or colloid-size particles between two scible aqueous phases. Wet grinding of plutonium residues to an average particle size of one micron will be used to liberate the plutonium from the bulk of the particle matrix. The goal is to produce a plutonium concentrate that will integrate with existing and developing chemical recovery processes. Ideally, the process would produce a nonTRU waste stream. Coupling physical beneficiation with chemical processing will result in a substantial reduction in the volume of mixed wastes generated from dissolution recovery processes. As part of this program, we will also explore applications of aqueous biphasic extraction that include the separation and recovery of dissolved species such as metal ions and water-soluble organics. The expertise and data generated in this work will form the basis for developing more cost-effective processes for handling waste streams from environmental restoration and waste management activities within the DOE community. This report summarizes the experimental results obtained during the first year of this effort. Experimental efforts were focused on elucidating the surface and solution chemistry variables which govern partitioning behavior of plutonium and silica in aqueous biphasic extraction systems. Additional efforts were directed toward the development of wet grinding methods for producing ultrafine particles with diameters of one micron or less.

  16. Production and Recovery of Pyruvic Acid: Recent Advances

    Science.gov (United States)

    Pal, Dharm; Keshav, Amit; Mazumdar, Bidyut; Kumar, Awanish; Uslu, Hasan

    2017-07-01

    Pyruvic acid is an important keto-carboxylic acid and can be manufactured by both chemical synthesis and biotechnological routes. In the present paper an overview of recent developments and challenges in various existing technique for the production and recovery of pyruvic acid from fermentation broth or from waste streams has been presented. The main obstacle in biotechnological production of pyruvic acid is development of suitable microorganism which can provide high yield and selectivity. On the other hand, technical limitation in recovery of pyruvic acid from fermentation broth is that, it could not be separated as other carboxylic acid in the form of salts by addition of alkali. Besides, pyruvic acid cannot be crystallized. Commercial separation by distillation is very expensive because pyruvic acid decomposes at higher temperature. It is also chemically reactive due to its peculiar molecular structure and has tendency to polymerize. Thus, at high concentration the various type of reaction leads to lower yield of the product, and hence, conventional methods are not favorable. Alternate separation technologies viable to both synthetic and biological routes are the current research areas. Latest techniques such as reactive extraction is new to the field of recovery of pyruvic acid. Recent development and future prospects in downstream processing of biochemically produced pyruvic acids has been discussed in this review article.

  17. Microfluidics: an enabling screening technology for enhanced oil recovery (EOR).

    Science.gov (United States)

    Lifton, Victor A

    2016-05-21

    Oil production is a critical industrial process that affects the entire world population and any improvements in its efficiency while reducing its environmental impact are of utmost societal importance. The paper reviews recent applications of microfluidics and microtechnology to study processes of oil extraction and recovery. It shows that microfluidic devices can be useful tools in investigation and visualization of such processes used in the oil & gas industry as fluid propagation, flooding, fracturing, emulsification and many others. Critical macro-scale processes that define oil extraction and recovery are controlled by the micro-scale processes based on wetting, adhesion, surface tension, colloids and other concepts of microfluidics. A growing number of research efforts demonstrates that microfluidics is becoming, albeit slowly, an accepted methodology in this area. We propose several areas of development where implementation of microfluidics may bring about deeper understanding and hence better control over the processes of oil recovery based on fluid propagation, droplet generation, wettability control. Studies of processes such as hydraulic fracturing, sand particle propagation in porous networks, high throughput screening of chemicals (for example, emulsifiers and surfactants) in microfluidic devices that simulate oil reservoirs are proposed to improve our understanding of these complicated physico-chemical systems. We also discuss why methods of additive manufacturing (3D printing) should be evaluated for quick prototyping and modification of the three-dimensional structures replicating natural oil-bearing rock formations for studies accessible to a wider audience of researchers.

  18. When 'exact recovery' is exact recovery in compressed sensing simulation

    DEFF Research Database (Denmark)

    Sturm, Bob L.

    2012-01-01

    In a simulation of compressed sensing (CS), one must test whether the recovered solution \\(\\vax\\) is the true solution \\(\\vx\\), i.e., ``exact recovery.'' Most CS simulations employ one of two criteria: 1) the recovered support is the true support; or 2) the normalized squared error is less than...... for a given distribution of \\(\\vx\\)? We show that, in a best case scenario, \\(\\epsilon^2\\) sets a maximum allowed missed detection rate in a majority sense....

  19. Applied in situ product recovery in ABE fermentation

    Science.gov (United States)

    Lalander, Carl‐Axel; Lee, Jonathan G. M.; Davies, E. Timothy; Harvey, Adam P.

    2017-01-01

    The production of biobutanol is hindered by the product's toxicity to the bacteria, which limits the productivity of the process. In situ product recovery of butanol can improve the productivity by removing the source of inhibition. This paper reviews in situ product recovery techniques applied to the acetone butanol ethanol fermentation in a stirred tank reactor. Methods of in situ recovery include gas stripping, vacuum fermentation, pervaporation, liquid–liquid extraction, perstraction, and adsorption, all of which have been investigated for the acetone, butanol, and ethanol fermentation. All techniques have shown an improvement in substrate utilization, yield, productivity or both. Different fermentation modes favored different techniques. For batch processing gas stripping and pervaporation were most favorable, but in fed‐batch fermentations gas stripping and adsorption were most promising. During continuous processing perstraction appeared to offer the best improvement. The use of hybrid techniques can increase the final product concentration beyond that of single‐stage techniques. Therefore, the selection of an in situ product recovery technique would require comparable information on the energy demand and economics of the process. © 2017 American Institute of Chemical Engineers Biotechnol. Prog., 33:563–579, 2017 PMID:28188696

  20. Hydrometallurgical Recovery of Metals from Large Printed Circuit Board Pieces

    Science.gov (United States)

    Jadhav, U.; Hocheng, H.

    2015-09-01

    The recovery of precious metals from waste printed circuit boards (PCBs) is an effective recycling process. This paper presents a promising hydrometallurgical process to recover precious metals from waste PCBs. To simplify the metal leaching process, large pieces of PCBs were used instead of a pulverized sample. The chemical coating present on the PCBs was removed by sodium hydroxide (NaOH) treatment prior to the hydrometallurgical treatment. Among the leaching reagents examined, hydrochloric acid (HCl) showed great potential for the recovery of metals. The HCl-mediated leaching of waste PCBs was investigated over a range of conditions. Increasing the acid concentration decreased the time required for complete metal recovery. The shaking speed showed a pronounced positive effect on metal recovery, but the temperature showed an insignificant effect. The results showed that 1 M HCl recovered all of the metals from 4 cm × 4 cm PCBs at room temperature and 150 rpm shaking speed in 22 h.

  1. Hydrometallurgical Recovery of Metals from Large Printed Circuit Board Pieces.

    Science.gov (United States)

    Jadhav, U; Hocheng, H

    2015-09-29

    The recovery of precious metals from waste printed circuit boards (PCBs) is an effective recycling process. This paper presents a promising hydrometallurgical process to recover precious metals from waste PCBs. To simplify the metal leaching process, large pieces of PCBs were used instead of a pulverized sample. The chemical coating present on the PCBs was removed by sodium hydroxide (NaOH) treatment prior to the hydrometallurgical treatment. Among the leaching reagents examined, hydrochloric acid (HCl) showed great potential for the recovery of metals. The HCl-mediated leaching of waste PCBs was investigated over a range of conditions. Increasing the acid concentration decreased the time required for complete metal recovery. The shaking speed showed a pronounced positive effect on metal recovery, but the temperature showed an insignificant effect. The results showed that 1 M HCl recovered all of the metals from 4 cm × 4 cm PCBs at room temperature and 150 rpm shaking speed in 22 h.

  2. Recovery rates, enhanced oil recovery and technological limits.

    Science.gov (United States)

    Muggeridge, Ann; Cockin, Andrew; Webb, Kevin; Frampton, Harry; Collins, Ian; Moulds, Tim; Salino, Peter

    2014-01-13

    Enhanced oil recovery (EOR) techniques can significantly extend global oil reserves once oil prices are high enough to make these techniques economic. Given a broad consensus that we have entered a period of supply constraints, operators can at last plan on the assumption that the oil price is likely to remain relatively high. This, coupled with the realization that new giant fields are becoming increasingly difficult to find, is creating the conditions for extensive deployment of EOR. This paper provides a comprehensive overview of the nature, status and prospects for EOR technologies. It explains why the average oil recovery factor worldwide is only between 20% and 40%, describes the factors that contribute to these low recoveries and indicates which of those factors EOR techniques can affect. The paper then summarizes the breadth of EOR processes, the history of their application and their current status. It introduces two new EOR technologies that are beginning to be deployed and which look set to enter mainstream application. Examples of existing EOR projects in the mature oil province of the North Sea are discussed. It concludes by summarizing the future opportunities for the development and deployment of EOR.

  3. CAMEO Chemicals Software

    Science.gov (United States)

    CAMEO Chemicals is an extensive chemical database, available for download, with critical response information for thousands of chemicals, and a tool that tells you what reactions might occur if chemicals were mixed together.

  4. Possibilities of energy recovery from municipal waste

    National Research Council Canada - National Science Library

    Vladimír Lapčík; Marta Lapčíková

    2012-01-01

    The article summarizes possibilities of energy recovery from municipal waste. It describes the history of incineration and energy recovery from municipal waste in Czechoslovakia and then in the Czech Republic...

  5. Addiction recovery: its definition and conceptual boundaries.

    Science.gov (United States)

    White, William L

    2007-10-01

    The addiction field's failure to achieve consensus on a definition of "recovery" from severe and persistent alcohol and other drug problems undermines clinical research, compromises clinical practice, and muddles the field's communications to service constituents, allied service professionals, the public, and policymakers. This essay discusses 10 questions critical to the achievement of such a definition and offers a working definition of recovery that attempts to meet the criteria of precision, inclusiveness, exclusiveness, measurability, acceptability, and simplicity. The key questions explore who has professional and cultural authority to define recovery, the defining ingredients of recovery, the boundaries (scope and depth) of recovery, and temporal benchmarks of recovery (when recovery begins and ends). The process of defining recovery touches on some of the most controversial issues within the addictions field.

  6. chemical safety and chemical security overview

    African Journals Online (AJOL)

    IICBA01

    expert in chemical security and work hard to safeguard the communities. Items discussed in this ... the public from injury, fire or other damage. In order to achieve these ..... 10.8 Transportation of hazardous chemicals and wastes? ... Chemical Security Engagement Program: https://chemsecurity.sandia.gov/. Chemical Safety.

  7. CHEMICAL EVOLUTION

    Energy Technology Data Exchange (ETDEWEB)

    Calvin, Melvin

    1965-06-01

    How did life come to be on the surface of the earth? Darwin himself recognized that his basic idea of evolution by variation and natural selection must be a continuous process extending backward in time through that period in which the first living things arose and into the period of 'Chemical Evolution' which preceded it. We are approaching the examination of these events by two routes. One is to seek for evidence in the ancient rocks of the earth which were laid down prior to that time in which organisms capable of leaving their skeletons in the rocks to be fossilized were in existence. This period is sometime prior to approximately 600 million years ago. The earth is believed to have taken its present form approximately 4700 million years ago. We have found in rocks whose age is about 1000 million years certain organic molecules which are closely related to the green pigment of plants, chlorophyll. This seems to establish that green plants were already fluorishing prior to that time. We have now found in rocks of still greater age, namely, 2500 million years, the same kinds of molecules mentioned above which can be attributed to the presence of living organisms. If these molecules are as old as the rocks, we have thus shortened the time available for the generation of the complex biosynthetic sequences which give rise to these specific hydrocarbons (polyisoprenoids) to less than 2000 million years.

  8. Oil recovery apparatus and method

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, J.G.

    1981-05-19

    An oil recovery apparatus and method, particularly for removing oil and grease from the discharge of dishwashing machines or the like, provides a small size assembly employing the same principle as in U.S. Pat. No. 4,051,024. This apparatus and method employs single rotating discs of plastic or plastic coated material and each disk has a pair of scraper blades arranged to scrape opposite sides of the rotating blade. Exterior of the container for the oil recovery apparatus is at least one filter basket adapted to receive the flow into the strainer container of large particles of food and other waste such as cigarette butts and the like. Each filter is disposed for the ready cleaning of accumulated matter from the basket. There is shown plural filters, valve controls, auxiliary heating and disc support means to be more fully described.

  9. Heat recovery equipment for engines

    Energy Technology Data Exchange (ETDEWEB)

    Segaser, C.L.

    1977-04-01

    The recovery and use of waste heat from prime movers is an important consideration for evaluating an on-site power system, since it is the basic factor that makes possible a substantial increase in fuel-use efficiency. The equipment usually employed to recover waste heat can be categorized as: (a) shell-and-tube type heat exchangers, (b) radiator-type heat exchangers, (c) exhaust gas boilers for the generation of pressurized hot water and/or steam, (d) steam separators, and (e) combined packaged units for ebulliently cooled internal combustion piston engines. The functional requirements and cost considerations involved in applying these devices for the recovery of waste heat from various types of prime-movers considered for application in the ICES Systems Engineering Program are examined.

  10. Recovery from blocking between outcomes.

    Science.gov (United States)

    Wheeler, Daniel S; Miller, Ralph R

    2005-10-01

    Contemporary associative learning research largely focuses on cue competition phenomena that occur when 2 cues are paired with a common outcome. Little research has been conducted to investigate similar phenomena occurring when a single cue is trained with 2 outcomes. Three conditioned lick suppression experiments with rats assessed whether treatments known to alleviate blocking between cues would also attenuate blocking between outcomes. In Experiment 1, conditioned responding recovered from blocking between outcomes when a long retention interval was interposed between training and testing. Experiment 2 obtained recovery from blocking between outcomes when the blocking outcome was extinguished after the blocking treatment. In Experiment 3, a recovery from blocking between outcomes occurred when a reminder stimulus was presented in a novel context prior to testing. Collectively, these studies demonstrate that blocking of outcomes, like blocking of cues, appears to be caused by a deficit in the expression of an acquired association.

  11. Al-Anon and recovery.

    Science.gov (United States)

    Cermak, T L

    1989-01-01

    The history of Al-Anon and its current demographics are reviewed. In order to understand 12-step recovery and psychotherapy for family members of alcoholics, the concept of codependence is defined with a set of diagnostic criteria consistent with the DSM-III-R definition of personality traits and disorders. At the core of codependence are denial and an unrealistic relationship to willpower. The therapeutic implications of considering codependence as a personality disorder are explored, as are the characteristics that make codependence unique among personality disorders: the central role of denial and the existence of a self-help organization to facilitate recovery. The dynamics of working the 12 steps on codependent characteristics are outlined. A synergistic relationship between psychotherapy and the 12 steps is described. Special attention is given the emergence of Al-Anon adult children of alcoholic meetings, and the future of codependence is discussed.

  12. Predictors of recovery in first episode psychosis

    DEFF Research Database (Denmark)

    Austin, Stephen F; Mors, Ole; Secher, Rikke Gry

    2013-01-01

    Recovery, the optimal goal in treatment, is the attainment of both symptomatic and functional remission over a sustained period of time. Identification of factors that promote recovery can help develop interventions that facilitate good outcomes for people with first episode psychosis.......Recovery, the optimal goal in treatment, is the attainment of both symptomatic and functional remission over a sustained period of time. Identification of factors that promote recovery can help develop interventions that facilitate good outcomes for people with first episode psychosis....

  13. Chemical information science coverage in Chemical Abstracts.

    Science.gov (United States)

    Wiggins, G

    1987-02-01

    For many years Chemical Abstracts has included in its coverage publications on chemical documentation or chemical information science. Although the bulk of those publications can be found in section 20 of Chemical Abstracts, many relevant articles were found scattered among 39 other sections of CA in 1984-1985. In addition to the scattering of references in CA, the comprehensiveness of Chemical Abstracts as a secondary source for chemical information science is called into question. Data are provided on the journals that contributed the most references on chemical information science and on the languages of publication of relevant articles.

  14. Counterpulse railgun energy recovery circuit

    Energy Technology Data Exchange (ETDEWEB)

    Honig, Emanuel M. (Los Alamos, NM)

    1986-01-01

    In an electromagnetic launcher such as a railgun for propelling a projectile at high velocity, a counterpulse energy recovery circuit is employed to transfer stored inductive energy from a source inductor to the railgun inductance to propel the projectile down the railgun. Switching circuitry and an energy transfer capacitor are used to switch the energy back to the source inductor in readiness for a repetitive projectile propelling cycle.

  15. Overpulse railgun energy recovery circuit

    Energy Technology Data Exchange (ETDEWEB)

    Honig, Emanuel M. (Los Alamos, NM)

    1989-01-01

    In an electromagnetic launcher such as a railgun for propelling a projectile at high velocity, an overpulse energy recovery circuit is employed to transfer stored inductive energy from a source inductor to the railgun inductance to propel the projectile down the railgun. Switching circuitry and an energy transfer capacitor are used to switch the energy back to the source inductor in readiness for a repetitive projectile propelling cycle.

  16. Boiler Stack Gas Heat Recovery

    Science.gov (United States)

    1987-09-01

    recover about 17 million Btu/hr. The fact that the exhaust gas was loaded with fiber made the spray recu- perator a prime candidate since it could also wash... properties of water, heating feedwater is more effective than heating air. Research in heat-recovery material technology has identified materials which are...and Acidic fluids up to 180 OF. Piping Fans and Blowers 350 OF flue gas. Scrubbers 300 to 350 OF bagasse flue gas, trash burner flue gas. Electrostatic

  17. Electrical stimulation and motor recovery.

    Science.gov (United States)

    Young, Wise

    2015-01-01

    In recent years, several investigators have successfully regenerated axons in animal spinal cords without locomotor recovery. One explanation is that the animals were not trained to use the regenerated connections. Intensive locomotor training improves walking recovery after spinal cord injury (SCI) in people, and >90% of people with incomplete SCI recover walking with training. Although the optimal timing, duration, intensity, and type of locomotor training are still controversial, many investigators have reported beneficial effects of training on locomotor function. The mechanisms by which training improves recovery are not clear, but an attractive theory is available. In 1949, Donald Hebb proposed a famous rule that has been paraphrased as "neurons that fire together, wire together." This rule provided a theoretical basis for a widely accepted theory that homosynaptic and heterosynaptic activity facilitate synaptic formation and consolidation. In addition, the lumbar spinal cord has a locomotor center, called the central pattern generator (CPG), which can be activated nonspecifically with electrical stimulation or neurotransmitters to produce walking. The CPG is an obvious target to reconnect after SCI. Stimulating motor cortex, spinal cord, or peripheral nerves can modulate lumbar spinal cord excitability. Motor cortex stimulation causes long-term changes in spinal reflexes and synapses, increases sprouting of the corticospinal tract, and restores skilled forelimb function in rats. Long used to treat chronic pain, motor cortex stimuli modify lumbar spinal network excitability and improve lower extremity motor scores in humans. Similarly, epidural spinal cord stimulation has long been used to treat pain and spasticity. Subthreshold epidural stimulation reduces the threshold for locomotor activity. In 2011, Harkema et al. reported lumbosacral epidural stimulation restores motor control in chronic motor complete patients. Peripheral nerve or functional electrical

  18. Branched alkyl alcohol propoxylated sulfate surfactants for improved oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Y.; Iglauer, S.; Shuler, P.; Tang, Y. [California Institute of Technology, Covina, CA (US). Power, Environmental and Energy Research (PEER) Center; Goddard, W.A. III [California Institute of Technology, Pasadena, CA (United States). Materials and Process Simulation Center

    2010-05-15

    This investigation considers branched alkyl alcohol propoxylated sulfate surfactants as candidates for chemical enhanced oil recovery (EOR) applications. Results show that these anionic surfactants may be preferred candidates for EOR as they can be effective at creating low interfacial tension (IFT) at dilute concentrations, without requiring an alkaline agent or cosurfactant. In addition, some of the formulations exhibit a low IFT at high salinity, and hence may be suitable for use in more saline reservoirs. Adsorption tests onto kaolinite clay indicate that the loss of these surfactants can be comparable to or greater than other types of anionic surfactants. Surfactant performance was evaluated in oil recovery core flood tests. Selected formulations recovered 35-50% waterflood residual oil even with dilute 0.2 wt% surfactant concentrations from Berea sandstone cores. (orig.)

  19. C41SR and Urban Disasters Disaster Response & Recovery Tools

    Energy Technology Data Exchange (ETDEWEB)

    Brouillette, Greg A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Risk Analysis and Decision Support Group

    2007-03-27

    These are slides for various presentations on C41SR and urban disasters disasters response and recovery tools. These are all mainly charts and images of disaster response and recovery tools. Slides included have headings such as the following: vignette of a disaster response, situational awareness and common operating picture available to EOC, plume modeling capability, Program ASPECT Chemical Response Products, EPA ASPECT - Hurricane RITA Response 9/25/2005, Angel Fire Imagery, incident commander's view/police chief's view/ EMS' view, common situational awareness and collaborative planning, exercise, training capability, systems diagram, Austere Challenge 06 Sim/C4 Requirements, common situational awareness and collaborative planning, exercise, training environment, common situational awareness, real world, crisis response, and consequence management.

  20. Continuous microalgae recovery using electrolysis with polarity exchange.

    Science.gov (United States)

    Kim, Jungmin; Ryu, Byung-Gon; Kim, Bo-Kyong; Han, Jong-In; Yang, Ji-Won

    2012-05-01

    There is increasing interest in the use of microalgae as a renewable source for the production of fuels and chemicals, but improvements are needed in all steps of this process, including harvesting. A continuous microalgae harvest system was developed based on electrolysis, referred to here as a continuous electrolytic microalgae (CEM) harvest system. This innovative system combines cultivation and harvesting and enables continuous and efficient concentration of microalgae. The electrodes were subject to a polarity exchange (PE) in the middle of the operation to further improve the harvest efficiency. Use of PE, rather than conventional electro-coagulation-flotation (ECF), led to more efficient cell recovery and more uniform recovery over the entire harvest chamber. In addition, PE increased the cell growth rate and the circulated cells remained intact after harvesting. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. Product Recovery From Hemlock "Pulpwood" From Alaska.

    Science.gov (United States)

    Thomas D. Fahey

    1983-01-01

    A total of 363 western hemlock (Tsuga heterophylla (Raf.) Sarg.) logs from Alaska were sawn to compare recovery at a stud mill and at a dimension mill. Recovery at both mills varied by log diameters and by log scaling system. Lumber grade recovery was primarily in Stud grade at the stud mill and in Standard and Construction grade at the dimension...

  2. Capacity efficiency of recovery request bundling

    DEFF Research Database (Denmark)

    Ruepp, Sarah Renée; Dittmann, Lars; Berger, Michael Stübert

    2010-01-01

    This paper presents a comparison of recovery methods in terms of capacity efficiency. In particular, a method where recovery requests are bundled towards the destination (Shortcut Span Protection) is evaluated against traditional recovery methods. Our simulation results show that Shortcut Span...

  3. Nature's chemicals and synthetic chemicals: comparative toxicology.

    OpenAIRE

    Ames, B N; Profet, M; Gold, L S

    1990-01-01

    The toxicology of synthetic chemicals is compared to that of natural chemicals, which represent the vast bulk of the chemicals to which humans are exposed. It is argued that animals have a broad array of inducible general defenses to combat the changing array of toxic chemicals in plant food (nature's pesticides) and that these defenses are effective against both natural and synthetic toxins. Synthetic toxins such as dioxin are compared to natural chemicals, such as indole carbinol (in brocco...

  4. Uses and abuses of recovery: implementing recovery-oriented practices in mental health systems

    Science.gov (United States)

    Slade, Mike; Amering, Michaela; Farkas, Marianne; Hamilton, Bridget; O'Hagan, Mary; Panther, Graham; Perkins, Rachel; Shepherd, Geoff; Tse, Samson; Whitley, Rob

    2014-01-01

    An understanding of recovery as a personal and subjective experience has emerged within mental health systems. This meaning of recovery now underpins mental health policy in many countries. Developing a focus on this type of recovery will involve transformation within mental health systems. Human systems do not easily transform. In this paper, we identify seven mis-uses (“abuses”) of the concept of recovery: recovery is the latest model; recovery does not apply to “my” patients; services can make people recover through effective treatment; compulsory detention and treatment aid recovery; a recovery orientation means closing services; recovery is about making people independent and normal; and contributing to society happens only after the person is recovered. We then identify ten empirically-validated interventions which support recovery, by targeting key recovery processes of connectedness, hope, identity, meaning and empowerment (the CHIME framework). The ten interventions are peer support workers, advance directives, wellness recovery action planning, illness management and recovery, REFOCUS, strengths model, recovery colleges or recovery education programs, individual placement and support, supported housing, and mental health trialogues. Finally, three scientific challenges are identified: broadening cultural understandings of recovery, implementing organizational transformation, and promoting citizenship. PMID:24497237

  5. Uses and abuses of recovery: implementing recovery-oriented practices in mental health systems.

    Science.gov (United States)

    Slade, Mike; Amering, Michaela; Farkas, Marianne; Hamilton, Bridget; O'Hagan, Mary; Panther, Graham; Perkins, Rachel; Shepherd, Geoff; Tse, Samson; Whitley, Rob

    2014-02-01

    An understanding of recovery as a personal and subjective experience has emerged within mental health systems. This meaning of recovery now underpins mental health policy in many countries. Developing a focus on this type of recovery will involve transformation within mental health systems. Human systems do not easily transform. In this paper, we identify seven mis-uses ("abuses") of the concept of recovery: recovery is the latest model; recovery does not apply to "my" patients; services can make people recover through effective treatment; compulsory detention and treatment aid recovery; a recovery orientation means closing services; recovery is about making people independent and normal; and contributing to society happens only after the person is recovered. We then identify ten empirically-validated interventions which support recovery, by targeting key recovery processes of connectedness, hope, identity, meaning and empowerment (the CHIME framework). The ten interventions are peer support workers, advance directives, wellness recovery action planning, illness management and recovery, REFOCUS, strengths model, recovery colleges or recovery education programs, individual placement and support, supported housing, and mental health trialogues. Finally, three scientific challenges are identified: broadening cultural understandings of recovery, implementing organizational transformation, and promoting citizenship.

  6. Evaluation of procedures for determination of Ra-226 in water by alpha-particle spectrometry with emphasis on the recovery.

    Science.gov (United States)

    Benedik, L; Repinc, U; Strok, M

    2010-01-01

    Radium-226 is one of the best known long-lived alpha-emitters abundantly present in the environment. The determination of radium isotopes in environmental samples usually requires a demanding chemical separation before measurement and quantification. Each step in the chemical separation process can involve losses of the analyte, therefore it is of vital importance that the recovery of the whole radiochemical procedure is evaluated. The emphasis of the work presented was determination of the chemical recovery using the different yield tracers Ra-223, Ra-225 and Ba-133.

  7. Optimization of Surfactant Mixtures and Their Interfacial Behavior for Advanced Oil Recovery, Annual Report, September 30, 1999-September 30, 2000

    Energy Technology Data Exchange (ETDEWEB)

    Somasundaran, Prof. P.

    2001-04-04

    The goal of this report is to develop improved extraction processes to mobilize and produce the oil left untapped using conventional techniques. Current chemical schemes for recovering the residual oil have been in general less than satisfactory. High cost of the processes as well as significant loss of chemicals by adsorption on reservoir materials and precipitation has limited the utility of chemical-flooding operations. There is a need to develop cost-effective, improved reagent schemes to increase recovery from domestic oil reservoirs. The goal of the report was to develop and evaluate novel mixtures of surfactants for improved oil recovery.

  8. Microbial enhanced oil recovery and wettability research program

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, C.P.; Bala, G.A.; Duvall, M.L.

    1991-07-01

    This report covers research results for the microbial enhanced oil recovery (MEOR) and wettability research program conducted by EG G Idaho, Inc. at the Idaho National Engineering Laboratory (INEL). The isolation and characterization of microbial species collected from various locations including target oil field environments is underway to develop more effective oil recovery systems for specific applications. The wettability research is a multi-year collaborative effort with the New Mexico Petroleum Recovery Research Center (NMPRRC), to evaluate reservoir wettability and its effects on oil recovery. Results from the wettability research will be applied to determine if alteration of wettability is a significant contributing mechanism for MEOR systems. Eight facultatively anaerobic surfactant producing isolates able to function in the reservoir conditions of the Minnelusa A Sands of the Powder River Basin in Wyoming were isolated from naturally occurring oil-laden environments. Isolates were characterized according to morphology, thermostability, halotolerance, growth substrates, affinity to crude oil/brine interfaces, degradative effects on crude oils, and biochemical profiles. Research at the INEL has focused on the elucidation of microbial mechanisms by which crude oil may be recovered from a reservoir and the chemical and physical properties of the reservoir that may impact the effectiveness of MEOR. Bacillus licheniformis JF-2 (ATCC 39307) has been used as a benchmark organism to quantify MEOR of medium weight crude oils (17.5 to 38.1{degrees}API) the capacity for oil recovery of Bacillus licheniformis JF-2 utilizing a sucrose-based nutrient has been elucidated using Berea sandstone cores. Spacial distribution of cells after microbial flooding has been analyzed with scanning electron microscopy. Also the effect of microbial surfactants on the interfacial tensions (IFT) of aqueous/crude oil systems has been measured. 87 refs., 60 figs., 15 tabs.

  9. Recovery of silver residues from dental amalgam

    Directory of Open Access Journals (Sweden)

    Heloísa Aparecida Barbosa da Silva Pereira

    2010-04-01

    Full Text Available Dental amalgam residues are probably the most important chemical residues generated from clinical dental practice because of the presence of heavy metals among its constituents, mainly mercury and silver. OBJECTIVE: The purpose of this study was to develop an alternative method for the recovery of silver residues from dental amalgam. MATERIAL AND METHODS: The residue generated after vacuum distillation of dental amalgam for the separation of mercury was initially diluted with 32.5% HNO3, followed by precipitation with 20% NaCl. Sequentially, under constant heating and agitation with NaOH and sucrose, the sample was reduced to metallic silver. However, the processing time was too long, which turned this procedure not viable. In another sequence of experiments, the dilution was accomplished with concentrated HNO3 at 90ºC, followed by precipitation with 20% NaCl. After washing, the pellet was diluted with concentrated NH4OH, water and more NaCl in order to facilitate the reaction with the reducer. RESULTS: Ascorbic acid was efficiently used as reducer, allowing a fast reduction, thus making the procedure viable. CONCLUSIONS: The proposed methodology is of easy application and does not require sophisticated equipment or expensive reagents.

  10. Super-Diffusive Gas Recovery from Nanopores

    CERN Document Server

    Wu, Haiyi; Qiao, Rui

    2016-01-01

    Understanding the recovery of gas from reservoirs featuring pervasive nanopores is essential for effective shale gas extraction. Classical theories cannot accurately predict such gas recovery and many experimental observations are not well understood. Here we report molecular simulations of the recovery of gas from single nanopores, explicitly taking into account molecular gas-wall interactions. We show that, in very narrow pores, the strong gas-wall interactions are essential in determining the gas recovery behavior both quantitatively and qualitatively. These interactions cause the total diffusion coefficients of the gas molecules in nanopores to be smaller than those predicted by kinetic theories, hence slowing down the rate of gas recovery. These interactions also lead to significant adsorption of gas molecules on the pore walls. Because of the desorption of these gas molecules during gas recovery, the gas recovery from the nanopore does not exhibit the usual diffusive scaling law (i.e., the accumulative ...

  11. ON THE RECOVERY OF HEMICELLULOSE BEFORE KRAFT PULPING

    Directory of Open Access Journals (Sweden)

    Carlos Vila,

    2012-07-01

    Full Text Available To assess the feasibility of implementing hemicellulose recovery stages in kraft mills, Eucalyptus globulus wood samples were subjected to aqueous treatments with hot, compressed water (autohydrolysis processing to achieve partial dissolution of xylan. Autohydrolyzed solids were subjected to kraft pulping under selected conditions to yield a pulp of low kappa number, and to an optimized TCF bleaching sequence made up of three stages (alkaline oxygen delignification, chelating, and pressurized hydrogen peroxide, with minimized additions of pulping and bleaching chemicals. The final product had a relatively low kappa number (1.4, 641 mL/g ISO intrinsic viscosity, and 86.4% brightness.

  12. Diamond Processing by Focused Ion Beam - Surface Damage and Recovery

    CERN Document Server

    Bayn, Igal; Cytermann, Catherine; Meyler, Boris; Richter, Vladimir; Salzman, Joseph; Kalish, Rafi

    2011-01-01

    The Nitrogen Vacancy color center (NV-) in diamond is of great interest for novel photonic applications. Diamond nano-photonic structures are often implemented using Focused-Ion-Beam (FIB) processing, leaving a damaged surface which has a detrimental effect on the color center luminescence. The FIB processing effect on single crystal diamond surfaces and their photonic properties is studied by Time of Flight Secondary Ion Mass Spectrometry (TOF-SIMS) and photoluminescence (PL). Exposing the processed surface to hydrogen plasma, followed by chemical etching, drastically decreases implanted Ga concentration, resulting in a recovery of the NV- photo-emission and in a significant increase of the NV-/NV0 ratio.

  13. Technical review of enhanced oil recovery literature. Final report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-04-01

    This report represents the work done under DOE grant No. DE-FG05-79ER10086. It reviews the chemical, miscible and thermal areas of enhanced and recovery (EOR) and has produced a comprehensive bibliography and glossary of terms. The analysis looks into several areas of interest, including: screening criteria, process design, variable interaction and reservoir applicability. In this summary section, the following are shown: (1) screening criteria for process selection; (2) screening guide summary for EOR process; and (3) representative schematics of three major process operations.

  14. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H. [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1998-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  15. Overpulse railgun energy recovery circuit

    Energy Technology Data Exchange (ETDEWEB)

    Honig, E.M.

    1984-09-28

    The invention presented relates to a high-power pulsing circuit and more particularly to a repetitive pulse inductive energy storage and transfer circuit for an electromagnetic launcher. In an electromagnetic launcher such as a railgun for propelling a projectile at high velocity, an overpulse energy recovery circuit is employed to transfer stored inductive energy from a source inductor to the railgun inductance to propel the projectile down the railgun. Switching circuitry and an energy transfer capacitor are used to switch the energy back to the source inductor in readiness for a repetitive projectile propelling cycle.

  16. Counterpulse railgun energy recovery circuit

    Energy Technology Data Exchange (ETDEWEB)

    Honig, E.M.

    1984-09-28

    The invention presented relates to a high-power pulsing circuit and more particularly to a repetitive pulse inductive energy storage and transfer circuit for an electromagnetic launcher. In an electromagnetic launcher such as a railgun for propelling a projectile at high velocity, a counterpulse energy recovery circuit is employed to transfer stored inductive energy from a source inductor to the railgun inductance to propel the projectile down the railgun. Switching circuitry and an energy transfer capacitor are used to switch the energy back to the source inductor in readiness for a repetitive projectile propelling cycle.

  17. System i Disaster Recovery Planning

    CERN Document Server

    Dolewski, Richard

    2008-01-01

    Mapping out all the preparations necessary for an effective disaster recovery plan and its safeguard-a continuous maintenance program-this guide is aimed at IT managers of small and medium businesses. The opening section covers the initial steps of auditing vulnerability, ranking essential IT functions, and reviewing the storage of tape backups, with the following discussion focused on the elements of the plan itself. The plan includes a mission statement, a definition of disaster, the assignment of staff to teams, methods of compensating for human error, and standards for documenting the step

  18. MediaWiki Grammar Recovery

    CERN Document Server

    Zaytsev, Vadim

    2011-01-01

    The paper describes in detail the recovery effort of one of the official MediaWiki grammars. Over two hundred grammar transformation steps are reported and annotated, leading to delivery of a level 2 grammar, semi-automatically extracted from a community created semi-formal text using at least five different syntactic notations, several non-enforced naming conventions, multiple misspellings, obsolete parsing technology idiosyncrasies and other problems commonly encountered in grammars that were not engineered properly. Having a quality grammar will allow to test and validate it further, without alienating the community with a separately developed grammar.

  19. Alcohol, Athletic Performance and Recovery

    Directory of Open Access Journals (Sweden)

    David Cameron-Smith

    2010-07-01

    Full Text Available Alcohol consumption within elite sport has been continually reported both anecdotally within the media and quantitatively in the literature. The detrimental effects of alcohol on human physiology have been well documented, adversely influencing neural function, metabolism, cardiovascular physiology, thermoregulation and skeletal muscle myopathy. Remarkably, the downstream effects of alcohol consumption on exercise performance and recovery, has received less attention and as such is not well understood. The focus of this review is to identify the acute effects of alcohol on exercise performance and give a brief insight into explanatory factors.

  20. Microwave Plasma Hydrogen Recovery System

    Science.gov (United States)

    Atwater, James; Wheeler, Richard, Jr.; Dahl, Roger; Hadley, Neal

    2010-01-01

    A microwave plasma reactor was developed for the recovery of hydrogen contained within waste methane produced by Carbon Dioxide Reduction Assembly (CRA), which reclaims oxygen from CO2. Since half of the H2 reductant used by the CRA is lost as CH4, the ability to reclaim this valuable resource will simplify supply logistics for longterm manned missions. Microwave plasmas provide an extreme thermal environment within a very small and precisely controlled region of space, resulting in very high energy densities at low overall power, and thus can drive high-temperature reactions using equipment that is smaller, lighter, and less power-consuming than traditional fixed-bed and fluidized-bed catalytic reactors. The high energy density provides an economical means to conduct endothermic reactions that become thermodynamically favorable only at very high temperatures. Microwave plasma methods were developed for the effective recovery of H2 using two primary reaction schemes: (1) methane pyrolysis to H2 and solid-phase carbon, and (2) methane oligomerization to H2 and acetylene. While the carbon problem is substantially reduced using plasma methods, it is not completely eliminated. For this reason, advanced methods were developed to promote CH4 oligomerization, which recovers a maximum of 75 percent of the H2 content of methane in a single reactor pass, and virtually eliminates the carbon problem. These methods were embodied in a prototype H2 recovery system capable of sustained high-efficiency operation. NASA can incorporate the innovation into flight hardware systems for deployment in support of future long-duration exploration objectives such as a Space Station retrofit, Lunar outpost, Mars transit, or Mars base. The primary application will be for the recovery of hydrogen lost in the Sabatier process for CO2 reduction to produce water in Exploration Life Support systems. Secondarily, this process may also be used in conjunction with a Sabatier reactor employed to

  1. Chemical Function Predictions for Tox21 Chemicals

    Data.gov (United States)

    U.S. Environmental Protection Agency — Random forest chemical function predictions for Tox21 chemicals in personal care products uses and "other" uses. This dataset is associated with the following...

  2. 26 CFR 1.43-2 - Qualified enhanced oil recovery project.

    Science.gov (United States)

    2010-04-01

    ... tertiary recovery method terminated. In July 1992, C begins drilling injection wells as part of a project... injection of water that has been made chemically basic by the addition of alkali metal hydroxides, silicates... originally produced; (iii) Horizontal drilling—The drilling of horizontal, rather than vertical, wells...

  3. Exergy losses of resource recovery from a waste-to-energy plant

    DEFF Research Database (Denmark)

    Vyzinkarova, Dana; Laner, D.; Astrup, Thomas Fruergaard

    2013-01-01

    . In this study, focusing on recovery from waste-to-energy plants with basic and advanced BA treatment, the goal is to give an indication about quality of selected recovered resources (Fe, Al, and Cu) by means of exergy analysis. Metal flows are modeled through both incineration scenarios, and then chemical...

  4. Gas-permeable hydrophobic tubular membranes for ammonia recovery in bio-electrochemical systems

    NARCIS (Netherlands)

    Kuntke, P.; Zamora, P.; Saakes, M.; Buisman, C.J.N.; Hamelers, H.V.M.

    2016-01-01

    The application of a gas-permeable hydrophobic tubular membrane in bio-electrochemical systems enables efficient recovery of ammonia (NH3) from their cathode compartments. Due to a hydrogen evolution reaction at the cathode, no chemical addition was required to increase the pH for continuous NH3

  5. Simulated Moving Bed Chromatography: Separation and Recovery of Sugars and Ionic Liquid from Biomass Hydrolysates

    Science.gov (United States)

    Caes, Benjamin R.; Van Oosbree, Thomas R.; Lu, Fachuang; Ralph, John; Maravelias, Christos T.

    2015-01-01

    Simulated moving bed chromatography, a continuous separation method, enables the nearly quantitative recovery of sugar products and ionic liquid solvent from chemical hydrolysates of biomass. The ensuing sugars support microbial growth, and the residual lignin from the process is intact. PMID:23939991

  6. Enhancing recovery of ammonia from swine manure anaerobic digester effluent using gas-permeable membrane technology

    Science.gov (United States)

    Gas-permeable membrane technology is useful to recover ammonia from manure. In this study, the technology was enhanced using aeration instead of alkali chemicals to increase pH and the ammonia recovery rate. Digested effluents from covered anaerobic swine lagoons containing 1375 to 2089 milligram am...

  7. Impact of Remembering Childhood Sexual Abuse on Addiction Recovery for Young Adult Lesbians

    Science.gov (United States)

    Galvin, Christina R.; Brooks-Livingston, Angela

    2011-01-01

    This article examines the impact of childhood sexual abuse on young adult lesbians' sexual identity and their recovery from chemical dependency. The authors recommend that counselors assess for sexual orientation (past and present), sexual abuse, and possible dual diagnosis. Implications for counselors are discussed.

  8. Modelling recovery from soil acidification in European forests under climate change

    NARCIS (Netherlands)

    Reinds, G.J.; Posch, M.; Leemans, R.

    2009-01-01

    A simple soil acidification model was applied to evaluate the effects of sulphur and nitrogen emission reductions on the recovery of acidified European forest soils. In addition we included the effects of climate change on soil solution chemistry, by modelling temperature effects on soil chemical

  9. Reduction efficiency prediction of CENIBRA's recovery boiler by direct minimization of gibbs free energy

    Directory of Open Access Journals (Sweden)

    W. L. Silva

    2008-09-01

    Full Text Available The reduction efficiency is an important variable during the black liquor burning process in the Kraft recovery boiler. This variable value is obtained by slow experimental routines and the delay of this measure disturbs the pulp and paper industry customary control. This paper describes an optimization approach for the reduction efficiency determination in the furnace bottom of the recovery boiler based on the minimization of the Gibbs free energy. The industrial data used in this study were directly obtained from CENIBRA's data acquisition system. The resulting approach is able to predict the steady state behavior of the chemical composition of the furnace recovery boiler, - especially the reduction efficiency when different operational conditions are used. This result confirms the potential of this approach in the analysis of the daily operation of the recovery boiler.

  10. Pharmacogenetics of neural injury recovery.

    Science.gov (United States)

    Pearson-Fuhrhop, Kristin M; Cramer, Steven C

    2013-10-01

    Relatively few pharmacological agents are part of routine care for neural injury, although several are used or under consideration in acute stroke, chronic stroke, traumatic brain injury and secondary stroke prevention. Tissue plasminogen activator is approved for the treatment of acute ischemic stroke, and genetic variants may impact the efficacy and safety of this drug. In the chronic phase of stroke, several drugs such as L-dopa, fluoxetine and donepezil are under investigation for enhancing rehabilitation therapy, with varying levels of evidence. One potential reason for the mixed efficacy displayed by these drugs may be the influence of genetic factors that were not considered in prior studies. An understanding of the genetics impacting the efficacy of dopaminergic, serotonergic and cholinergic drugs may allow clinicians to target these potential therapies to those patients most likely to benefit. In the setting of stroke prevention, which is directly linked to neural injury recovery, the most highly studied pharmacogenomic interactions pertain to clopidogrel and warfarin. Incorporating pharmacogenomics into neural injury recovery has the potential to maximize the benefit of several current and potential pharmacological therapies and to refine the choice of pharmacological agent that may be used to enhance benefits from rehabilitation therapy.

  11. Spontaneous recovery in dynamical networks

    Science.gov (United States)

    Majdandzic, Antonio; Podobnik, Boris; Buldyrev, Sergey V.; Kenett, Dror Y.; Havlin, Shlomo; Eugene Stanley, H.

    2014-01-01

    Much research has been carried out to explore the structural properties and vulnerability of complex networks. Of particular interest are abrupt dynamic events that cause networks to irreversibly fail. However, in many real-world phenomena, such as brain seizures in neuroscience or sudden market crashes in finance, after an inactive period of time a significant part of the damaged network is capable of spontaneously becoming active again. The process often occurs repeatedly. To model this marked network recovery, we examine the effect of local node recoveries and stochastic contiguous spreading, and find that they can lead to the spontaneous emergence of macroscopic `phase-flipping' phenomena. As the network is of finite size and is stochastic, the fraction of active nodes z switches back and forth between the two network collective modes characterized by high network activity and low network activity. Furthermore, the system exhibits a strong hysteresis behaviour analogous to phase transitions near a critical point. We present real-world network data exhibiting phase switching behaviour in accord with the predictions of the model.

  12. Inapproximability of maximal strip recovery

    CERN Document Server

    Jiang, Minghui

    2009-01-01

    In comparative genomic, the first step of sequence analysis is usually to decompose two or more genomes into syntenic blocks that are segments of homologous chromosomes. For the reliable recovery of syntenic blocks, noise and ambiguities in the genomic maps need to be removed first. Maximal Strip Recovery (MSR) is an optimization problem proposed by Zheng, Zhu, and Sankoff for reliably recovering syntenic blocks from genomic maps in the midst of noise and ambiguities. Given $d$ genomic maps as sequences of gene markers, the objective of \\msr{d} is to find $d$ subsequences, one subsequence of each genomic map, such that the total length of syntenic blocks in these subsequences is maximized. For any constant $d \\ge 2$, a polynomial-time 2d-approximation for \\msr{d} was previously known. In this paper, we show that for any $d \\ge 2$, \\msr{d} is APX-hard, even for the most basic version of the problem in which all gene markers are distinct and appear in positive orientation in each genomic map. Moreover, we provi...

  13. Recovery of Copper from Cyanidation Tailing by Flotation

    Science.gov (United States)

    Qiu, Tingsheng; Huang, Xiong; Yang, Xiuli

    2016-02-01

    In this work, sodium hypochlorite, hydrogen peroxide, sodium metabisulfite and copper sulfate as activators were investigated to lessen the depression effect of cyanide for deep-depressing chalcopyrite. The experimental results indicate that the copper recovery exceeded 94%, 84% and 97% at the dosage: sodium hypochlorite 3 mL/L, hydrogen peroxide 2 mL/L, sodium metabisulfite 2 × 10-3 mol/L and copper sulfate 1.67 × 10-4 mol/L, respectively. According to the results of zeta potential and Fourier transform infrared spectrum, it is suggested that chalcopyrite was depressed because of the chemical adsorption of cyanide on the chalcopyrite surfaces. Sodium hypochlorite, hydrogen peroxide and sodium metabisulfite can destroy Cu-C bond on the deep-depressing chalcopyrite surface by chemical reaction. Copper sulfate can activate deep-depressing chalcopyrite by copper ion adsorption.

  14. Contracts for field projects and supporting research on enhanced oil recovery. Progress review No. 82, quarterly report, January--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    This document consists of a list of projects supporting work on oil recovery programs. A publications list and index of companies and institutions is provided. The remaining portion of the document provides brief descriptions on projects in chemical flooding, gas displacement, thermal recovery, geoscience, resource assessment, and reservoir class field demonstrations.

  15. Microfluidic chemical reaction circuits

    Science.gov (United States)

    Lee, Chung-cheng; Sui, Guodong; Elizarov, Arkadij; Kolb, Hartmuth C.; Huang, Jiang; Heath, James R.; Phelps, Michael E.; Quake, Stephen R.; Tseng, Hsian-rong; Wyatt, Paul; Daridon, Antoine

    2012-06-26

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  16. Condensed tannins increase nitrogen recovery by trees following insect defoliation.

    Science.gov (United States)

    Madritch, Michael D; Lindroth, Richard L

    2015-10-01

    While the importance of plant secondary metabolites to belowground functioning is gaining recognition, the perception remains that secondary metabolites are produced for herbivore defense, whereas their belowground impacts are ecological by-products, or 'afterlife' effects. However, plants invest a significant amount of resources into production of secondary metabolites that have minimal effects on herbivore resistance (e.g. condensed tannins and insect herbivores). We show that genetically mediated variation in condensed tannin concentration is correlated with plant nitrogen recovery following a severe defoliation event. We used single-tree mesocosms labeled with (15) N to track nitrogen through both the frass and litter cycling pathways. High concentrations of leaf tannins in Populus tremuloides were correlated with (15) N recovery from frass within the same growing season and in the following growing season. Likewise, leaf tannin concentrations were also correlated with (15) N recovery from the litter of defoliated trees in the growing season following the defoliation event. Conversely, tannins were not well correlated with nitrogen uptake under conditions of nominal herbivory. Our results suggest that tannins may confer benefits in response to herbivore pressure through conserved belowground nitrogen cycling, rather than via defensive properties. Consequently, tannins may be considered as chemical mediators of tolerance rather than resistance.

  17. LCA of Chemicals and Chemical Products

    DEFF Research Database (Denmark)

    Fantke, Peter; Ernstoff, Alexi

    2017-01-01

    This chapter focuses on the application of Life Cycle Assessment (LCA) to evaluate the environmental performance of chemicals as well as of products and processes where chemicals play a key role. The life cycle stages of chemical products, such as pharmaceuticals drugs or plant protection products...... of potential environmental impacts occurs during the early product life cycle stages, potential impacts related to chemicals that are found as ingredients or residues directly in products can be dominated by the product use stage. Finally, methodological challenges in LCA studies in relation to chemicals......, are discussed and differentiated into extraction of abiotic and biotic raw materials, chemical synthesis and processing, material processing, product manufacturing, professional or consumer product use, and finally end-of-life . LCA is discussed in relation to other chemicals management frameworks and concepts...

  18. Chemical Security Analysis Center

    Data.gov (United States)

    Federal Laboratory Consortium — In 2006, by Presidential Directive, DHS established the Chemical Security Analysis Center (CSAC) to identify and assess chemical threats and vulnerabilities in the...

  19. Methane productivity and nutrient recovery from manure

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, H.B.

    2003-07-01

    The efficient recovery of energy and improvements in the handling of nutrients from manure have attracted increased research focus during recent decades. Anaerobic digestion is a key process in any strategy for the recovery of energy, while slurry separation is an important component in an improved nutrient-handling strategy. This thesis is divided into two parts: the first deals mainly with nutrient recovery strategies and the second examines biological degradation processes, including controlled anaerobic digestion. (au)

  20. Energy recovery for a road vehicle

    Science.gov (United States)

    Tarulescu, R.

    2016-08-01

    In this paper the author analyse the possibility of fluid energy recovery, generated from a road vehicle through the aerodynamic impact. The suggested dynamic recovery system use an axial wind turbine, bended with the vehicle. Also, are presented the benefits (economic and energetic) and the disadvantages (constructive and functional) in the base of a calculus statement, with original parts. The results of some numeric calculus for a concrete opportunity are hopeful, the degree of recovery (in fluid - mechanic - electric conversion) tending to 40%.

  1. Disaster Recovery plan for healthcare organisation

    OpenAIRE

    Prokeš, David

    2015-01-01

    Theme of this thesis is Disaster Recovery and Business Continuity Planning. Main goal is design of Disaster Recovery plan for specific healthcare organization. One part of the design is analysis of analyzed hospital and identification of core applications and weak spots of the system. Within the analysis is risk assessment and assessment of its impact on the main applications. Based on this research the Disaster Recovery Plan is proposed. First part defines basic parts of Business Continuity ...

  2. Functional Recovery After Severe Traumatic Brain Injury

    DEFF Research Database (Denmark)

    Hart, Tessa; Kozlowski, Allan; Whyte, John

    2014-01-01

    OBJECTIVE: To examine person, injury, and treatment characteristics associated with recovery trajectories of people with severe traumatic brain injury (TBI) during inpatient rehabilitation. DESIGN: Observational prospective longitudinal study. SETTING: Two specialized inpatient TBI rehabilitation...... functional levels received more treatment and more treatment was associated with slower recovery, presumably because treatment was allocated according to need. Thus, effects of treatment on outcome could not be disentangled from effects of case mix factors. CONCLUSIONS: FIM gain during inpatient recovery...

  3. Recovery following bereavement: metaphor, phenomenology, and culture.

    Science.gov (United States)

    Rosenblatt, Paul C

    2008-01-01

    The concept of recovery following bereavement can be both useful and misleading. As a metaphor, the concept of recovery highlights some aspects of bereavement and obscures others. Bereaved people interviewed in 3 different studies typically did not bring up the term recovery so it did not seem to be a term that described their experience. Across cultures, the concept of recovery can be irrelevant or even misleading in understanding what goes on following bereavement. Arguably, a postmodern perspective in which no single concept is considered relevant for framing what goes on or what is desirable following bereavement might be best.

  4. Recovery of Overpayments Accounting Reporting Master

    Data.gov (United States)

    Social Security Administration — Contains detailed accounting of refund and remittance data, beneficiary data, and a history of overpayment recovery efforts. It also house data for overpayments of...

  5. LGBTQ women and mental health "recovery".

    Science.gov (United States)

    Das, A

    2012-12-01

    This study investigated what women identifying as lesbian, gay, bisexual, transgender, and/or queer (LGBTQ) think about mental health "recovery." We used a grounded theory analysis of 13 participant interviews. Three novel critiques emerged, including rejection of mental health "recovery" based on participants' identities as "mad," sexual assault survivors, and/or LGBTQ. While a medicalized interpretation of "recovery" may not work for some women, alternative understandings, such as using "recovery" to heal from discrimination and demand systemic changes, have liberatory potential. It is essential that supporters discern and utilize each woman's chosen language.

  6. Leading a Recovery-oriented Social Enterprise.

    Science.gov (United States)

    Raeburn, Toby; Hungerford, Catherine; Sayers, Jan; Escott, Phil; Lopez, Violeta; Cleary, Michelle

    2015-05-01

    Recovery-oriented mental health services promote the principles of recovery, such as hope and optimism, and are characterized by a personalized approach to developing consumer self-determination. Nurse leaders are increasingly developing such services as social enterprises, but there is limited research on the leadership of these programs. Leading a recovery-oriented mental health nurse social enterprise requires visionary leadership, collaboration with consumers and local health providers, financial viability, and commitment to recovery-focused practice. This article describes the framework of an Australian mental health nursing social enterprise, including the service attributes and leadership lessons that have been learned from developing program sustainability.

  7. Resource Conservation and Recovery Act Information (RCRAInfo)

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Resource Conservation and Recovery Act Information (RCRAInfo) system contains information reported to the state environmental programs on activities and cleanup...

  8. Diagnostic Approach to Functional Recovery

    DEFF Research Database (Denmark)

    Havsteen, Inger; Madsen, Kristoffer H; Christensen, Hanne Krarup

    2013-01-01

    a substantial capacity to reorganize after a focal ischemic (or hemorrhagic) brain lesion. This functional reorganization contributes to functional recovery after stroke. Functional magnetic resonance imaging (fMRI) provides a valuable tool to capture the spatial and temporal activity changes in response......, only up to 20-25% of patients are eligible to causal treatment. Further, care in a specialized stroke unit improves prognosis in all patients independent of age and stroke severity. Even when it is not possible to prevent tissue loss, the surviving brain areas of functional brain networks have...... to an acute ischemic lesion. Task-related as well as resting-state fMRI have been successfully applied to elucidate post-stroke remodeling of functional brain networks. This includes regional changes in neuronal activation as well as distributed changes in functional brain connectivity. Since fMRI is readily...

  9. Mechanical Treatment: Material Recovery Facilities

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Bilitewski, B.

    2011-01-01

    .g. shredding prior to incineration or screening after composting). The mechanical treatment unit process is in the latter case an integrated part of the overall treatment usually with the purpose of improving the quality of the input material, or the efficiency or stability of the biological or thermal process......, or improving the quality of the output material. Examples hereof appear in the chapters on biological and thermal treatment. Mechanical treatment unit processes may also appear at industries using recycled material as part of their feedstock, for example, for removing impurities and homogenizing the material....... Examples hereof appear in the chapters describing the recycling of materials. Mechanical treatment unit processes most often perform only one function, but placing different mechanical unit processes in a series or ‘treatment train’ creating a material recovery facility, often called an MRF, output...

  10. Aerobic microbial enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Torsvik, T. [Univ. of Bergen (Norway); Gilje, E.; Sunde, E.

    1995-12-31

    In aerobic MEOR, the ability of oil-degrading bacteria to mobilize oil is used to increase oil recovery. In this process, oxygen and mineral nutrients are injected into the oil reservoir in order to stimulate growth of aerobic oil-degrading bacteria in the reservoir. Experiments carried out in a model sandstone with stock tank oil and bacteria isolated from offshore wells showed that residual oil saturation was lowered from 27% to 3%. The process was time dependent, not pore volume dependent. During MEOR flooding, the relative permeability of water was lowered. Oxygen and active bacteria were needed for the process to take place. Maximum efficiency was reached at low oxygen concentrations, approximately 1 mg O{sub 2}/liter.

  11. Thermal method of oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Sergeev, A.I.; Sheinman, A.B.; Malofeev, G.E.

    1963-08-02

    In a thermal method of oil recovery, an oxidizer is fed through one hole so that the air expels the water from the formation and starts to circulate between this and a second hole. The combustion heat is formed so that as air is added and the combustion products are drawn off through the other, the heat of combustion will in fact move along the oil formation toward the flow of oxidizing agent. The highly heated zone of rock which forms lies perpendicular to the water flow. When air is stopped, pressure is reduced and the water is re-admitted to this zone. It evaporates and fills the cavity in the rock, cools the area behind, while the heated zone moves on and heats the area in front. The water vapor and hot water expel the oil.

  12. Toward a Heat Recovery Chimney

    Directory of Open Access Journals (Sweden)

    Min Pan

    2011-11-01

    Full Text Available The worldwide population increase and subsequent surge in energy demand leads electricity producers to increase supply in an attempt to generate larger profit margins. However, with Global Climate Change becoming a greater focus in engineering, it is critical for energy to be converted in as environmentally benign a way as possible. There are different sustainable methods to meet the energy demand. However, the focus of this research is in the area of Waste Heat Recovery. The waste heat stored in the exiting condenser cooling water is delivered to the air flow through a water-air cross flow heat exchanger. A converging thermal chimney structure is then applied to increase the velocity of the airflow. The accelerated air can be used to turn on the turbine-generator installed on the top the thermal chimney so that electricity can be generated. This system is effective in generating electricity from otherwise wasted heat.

  13. Factors controlling alkali salt deposition in recovery boilers. Release mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    McKeough, P.; Kurkela, M.; Kylloenen, H.; Tapola, E. [VTT Energy, Espoo (Finland). Process Technology Group

    1997-10-01

    The research was part of an ongoing cooperative research effort aimed at developing a model to describe the behaviour of inorganic compounds in kraft recovery boilers. During 1996 experimental investigations of sulphur release were continued. Experiments at elevated pressures and employing larger particle sizes were performed in order to gain information about mass transfer effects. The first experiments yielding data on the rates of the sulphur-release reactions were performed. This data will be used as the basis of a drop model for sulphur release being developed in cooperation with another research group. The other part of the work during 1996 explored the possibility of using chemical equilibrium calculations to predict the release of sodium, potassium and chlorine in the recovery furnace. The approach is essentially different from that employed in earlier studies in that the effects of fume formation are taken into account. So far, the predictions of the chemical equilibrium release model have, in no way, conflicted with field measurements. (orig.)

  14. RECOVERY STRATEGIES FOR SERVICE FAILURES

    Directory of Open Access Journals (Sweden)

    Budeanu Andreea

    2015-07-01

    Full Text Available Internationally, services represent the most important sector of the economy both in terms of economic performance and labor utilization. Becoming essential part of today society, they are considered the basis of a healthy economy, fact that has increased the importance of services and the research in the field.T hrough this work we intend to address a number of issues that require clarification and are relevant to this sector. Increased competition and customers higher demands lead to difficulties in service delivery, so managers of service organizations must work hard towards developing appropiate strategies that can lead to improved customers satisfaction and to increased efficiency. Because it is inevitably for service providers to face situations in which service failure occurs and their customers are not satisfied, understanding the nature of service failures and the ways in which an organization can recover after a failure are considered key factors for achieving customer satisfaction. Since the data suggests that over 50% of customers who are facing problems are not satisfied with the way they were resolved, we consider appropriate to approach this topic. We intend to draw attention to service providers to the importance of proper management of service failure. They can find ways to recover from these failures and even to turn them into some very pleasant situations that can contribute to customer loyalty. This paper begins by highlighting the various features specific to services which contribute to the increased chances of failure, it continues by presenting the concepts of service failure and service recovery and then it presents some links that exist between service recovery and other aspects of providing services that are demonstrated in the literature. We hope that this paper will significantly contribute to the knowledge and development of the sector under analysis and will highlight some practices that will lead to improved

  15. Phase behavior and oil recovery investigations using mixed and alkaline-enhanced surfactant systems

    Energy Technology Data Exchange (ETDEWEB)

    Llave, F.M.; Gall, B.L.; French, T.R.; Noll, L.A.; Munden, S.A.

    1992-03-01

    The results of an evaluation of different mixed surfactant and alkaline-enhanced surfactant systems for enhanced oil recovery are described. Several mixed surfactant systems have been studies to evaluate their oil recovery potential as well as improved adaptability to different ranges of salinity, divalent ion concentrations, and temperature. Several combinations of screening methods were used to help identify potential chemical formulations and determine conditions where particular chemical systems can be applied. The effects of different parameters on the behavior of the overall surfactant system were also studied. Several commercially available surfactants were tested as primary components in the mixtures used in the study. These surfactants were formulated with different secondary as well as tertiary components, including ethoxylated and non-ethoxylated sulfonates and sulfates. Improved salinity and hardness tolerance was achieved for some of these chemical systems. The salinity tolerance of these systems were found to be dependent on the molecular weight, surfactant type, and concentration of the surfactant components.

  16. Dynamics and recovery of a sediment-exposed Chironomus riparius population: A modelling approach.

    Science.gov (United States)

    Diepens, Noël J; Beltman, Wim H J; Koelmans, Albert A; Van den Brink, Paul J; Baveco, Johannes M

    2016-06-01

    Models can be used to assess long-term risks of sediment-bound contaminants at the population level. However, these models usually lack the coupling between chemical fate in the sediment, toxicokinetic-toxicodynamic processes in individuals and propagation of individual-level effects to the population. We developed a population model that includes all these processes, and used it to assess the importance of chemical uptake routes on a Chironomus riparius population after pulsed exposure to the pesticide chlorpyrifos. We show that particle ingestion is an important additional exposure pathway affecting C. riparius population dynamics and recovery. Models ignoring particle ingestion underestimate the impact and the required recovery times, which implies that they underestimate risks of sediment-bound chemicals. Additional scenario studies showed the importance of selecting the biologically relevant sediment layer and showed population effects in the long term.

  17. Recovery of Elemental Palladium by Shewanella putrefaciens

    Science.gov (United States)

    Akasaka, S.; Xia, X.; Sawada, K.; Enokida, Y.; Yamamoto, I.; Ohnuki, T.

    2006-12-01

    Microbial reduction of metals plays an important role in environmental behavior and provides a technique for the recovery of metals from industrial wastewater. Recently, demand for platinum group metals (PGMs) increases by their catalytic properties. The extreme rarity of PGMs have led to a growing interest in their recovery. Palladium, one of PGMs, has different oxidation states of Pd(II) and Pd(0). The oxidized form of Pd(II) is soluble, while the reduced form of Pd(0) is insoluble. In this study, microbial reduction of palladium by Fe(III)- reducing bacterium, Shewanella putrefaceins was conducted. This bacterium is known to be capable of reducing metals, such as Mn(IV), U(VI), or Tc(VII) with organic C or H2 as an electron donor. In order to investigate the potential of S. putrefaciens to reduce Pd(II) in solution, resting cells or heat-killed cells were suspended under anaerobic conditions with lactate or H2 as an electron donor. The cells of S. putrefaciens (NBRC3908) were grown in aerobic medium, harvested by centrifugation, and then washed with 25 mmol/dm3 HEPES and 100 mmol/dm3 NaCl (HEPES-NaCl) solution (pH 7.0). The heat-killed cells were autoclaved for 20 min at 121 degrees C. The cell suspension (21.5 mg in dry weight) was resuspended in the HEPES-NaCl solution which contained 1.0 mmol/dm3 Na2PdCl4 (Wako Pure chemical Industries, Ltd). The suspensions were bubbled with N2 for 15 min before 10 mmol/dm3 lactate or 4.8 v/v% H2 was added. The suspensions were then incubated at 30 degrees C. Redox potential (Eh) and pH of the solutions were measured in an inert glove box with Ar gas. Concentration of Pd(II) was measured by Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES). Deposited Pd and cells were analyzed by X-ray powder diffraction (XRD) and Scanning Electron Microscope (SEM) with Energy-Dispersive Spectroscopy (EDS). Approximately 86% of Pd(II) of the initial concentration was removed from solution by the resting cells within 24 h when

  18. Contracts for field projects and supporting research on enhanced oil recovery. Progress review number 83, quarter ending June 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-01

    Summaries of 41 research projects on enhanced recovery are presented under the following sections: (1) chemical flooding; (2) gas displacement; (3) thermal recovery; (4) geoscience technology; (5) resource assessment technology; and (6) reservoir classes. Each presentation gives the title of the project, contract number, research facility, contract date, expected completion data, amount of the award, principal investigator, and DOE program manager, and describes the objectives of the project and a summary of the technical progress.

  19. Automobile shredder residue: some recycling, resource recovery and disposal options

    Energy Technology Data Exchange (ETDEWEB)

    Day, M. [National Research Council of Canada, Inst. for Chemical Process and Environmental Technology, Ottawa, ON (Canada)

    2001-07-01

    Obsolete automobiles are the most recycled high-volume consumer product, with a recovery rate of between 75 and 80 per cent by weight. Ferrous scrap metal from old automobiles in North America amounts to about 10 million tons per year. However, each ton of steel that is recovered, produces about 300 kg of automobile shredder residue (ASR), comprised of plastics, rubber, glass, foam, and textiles, contaminated by oil and other fluids. All combined, this represents about 0.3 million tons of waste materials from the 22 shredders in Canada. This amount is likely to increase as the amount of steel in automobiles decreases due to downsizing and weight reduction, emphasizing the need for new resource recovery and application techniques to deal with the ASR problem. This paper describes a number of new initiatives primarily in two areas: separation technologies, ranging from selective disassembly to physical/mechanical/chemical separation processes, and pyrolysis techniques for the recovery of valuable hydrocarbon resources contained in the plastics in the ASR. Recycling of the material into high performance composite materials, such as additives to concrete for increased tensile strength, shrinkage and crack resistance, without adverse effect on other properties such as durability and workability, also received attention. Energy recovery options and engineered landfilling wherein ASR is used as a landfill day cover material, are some other techniques that show considerable promise. In landfill applications the high absorption capacity of ASR for heavy metals such as lead, its high compressibility, erosion resistance, and good traction make it a highly desirable choice for use as day cover material. 25 refs.

  20. Recovery and distribution of incinerated aluminum packaging waste.

    Science.gov (United States)

    Hu, Y; Bakker, M C M; de Heij, P G

    2011-12-01

    A study was performed into relations between physical properties of aluminum packaging waste and the corresponding aluminum scraps in bottom ash from three typical incineration processes. First, Dutch municipal solid waste incineration (MSWI) bottom ash was analyzed for the identifiable beverage can alloy scraps in the +2mm size ranges using chemical detection and X-ray fluorescence. Second, laboratory-scale pot furnace tests were conducted to investigate the relations between aluminum packaging in base household waste and the corresponding metal recovery rates. The representative packaging wastes include beverage cans, foil containers and thin foils. Third, small samples of aluminum packaging waste were incinerated in a high-temperature oven to determine leading factors influencing metal recovery rates. Packaging properties, combustion conditions, presence of magnesium and some specific contaminants commonly found in household waste were investigated independently in the high-temperature oven. In 2007, the bottom ash (+2mm fraction) from the AEB MSWI plant was estimated to be enriched by 0.1 wt.% of aluminum beverage cans scrap. Extrapolating from this number, the recovery potential of all eleven MSWI plants in the Netherlands is estimated at 720 ton of aluminum cans scrap. More than 85 wt.% of this estimate would end up in +6mm size fractions and were amenable for efficient recycling. The pot furnace tests showed that the average recovery rate of metallic aluminum typically decreases from beverage cans (93 wt.%) to foil containers (85 wt.%) to thin foils (77 wt.%). The oven tests showed that in order of decreasing impact the main factors promoting metallic aluminum losses are the packaging type, combustion temperature, residence time and salt contamination. To a lesser degree magnesium as alloying element, smaller packaging size and basic contaminations may also promote losses.

  1. Impediments to recovery from acid deposition

    Science.gov (United States)

    Watmough, Shaun A.; Eimers, Catherine; Baker, Scott

    2016-12-01

    In response to large reductions in sulphur (S) emissions over the past 30 years, sulphate (SO42-) concentrations in precipitation at Plastic Lake in south-central Ontario, Canada, have declined by more than 70%. More recent decreases in NOx emissions have similarly led to a reduction in nitrate deposition (NO3-) and consequently the pH of bulk precipitation has increased by approximately 0.8 pH units since 1980. Despite the large decrease in acidic deposition, chemical recovery of the streams, as measured by an increase in pH and decrease in aluminum (Al), has been much less than expected, primarily due to losses of base cations from the shallow, base-poor soils. While nitrogen (N) is almost totally retained within the terrestrial catchment, S export continues to exceed inputs measured in bulk deposition and during the early part of the record approximately 70% of the anions in streams were buffered by calcium (Ca2+) and magnesium (Mg2+) compared with only 60% in 2011/12. In the wetland-draining stream (PC1), peak depressions in stream pH and peaks in SO42- and Al concentration in the fall are significantly positively correlated with annual drought days defined as the number of days when stream flow ceases. Even though reductions in SO2 and NOx emissions in Canada have resulted in large improvements in precipitation chemistry, the combined influence of soil acidification and climate-mediated biogeochemical processes occurring in wetlands cause acidification-related issues to persist. Forecasting the longer-term response of soils and surface waters in light of these observations is required to fully assess the need for further emission reductions.

  2. Physical Constraints on Microbially Enhanced Oil Recovery

    Science.gov (United States)

    Marshall, S. L.

    2007-12-01

    Secondary and tertiary oil recovery from mature or depleted reservoirs usually involves modification of fluid properties (especially the oil-water interfacial tension), or increasing the efficiency of water flooding by selective permeability reduction. The use of microbes for both of these strategies - through production of biosurfactants and extracellular polymeric material, respectively - is the subject of considerable current interest, but as pointed out by Bryant and Lockhart [SPE paper 79719, 2002] is constrained by chemical reaction kinetics. Continuing in the spirit of the engineering analysis presented by these authors, the purpose of this paper is to consider, on the basis of simplified physical models, the constraints that apply to the injection of microbes as a concentrated slurry and their subsequent dispersion through the pores of the formation. This involves solution of the advection-dispersion equation in conjunction with the Newtonian flow distribution between an injection well and a production well, and a more general flow distribution based on a non-Newtonian (power-law) constitutive equation used to describe the rheological properties of concentrated suspensions. By analogy with the better-known example of blood flow through capillaries, such deviations from Newtonian flow behavior are expected to become more significant in flow through media of low permeabilities, where the diameters of the suspended particles are non-negligible in relation to the mean diameters of the flow channels. The nature and extent of these deviations from Newtonian behavior are examined by calculating the pressure drops corresponding to a given flow rate in one dimension at different suspension concentrations, and the nonlinearities resulting from retention or `filtration' of bacteria by the porous medium are investigated by performing a population-balance analysis to determine the evolving profiles of retained bacteria as a function of distance and time. These

  3. Resource Recovery Technology Application Document.

    Science.gov (United States)

    1982-06-01

    P.E.T. Bottles (polyethylene terephthalate ) are the only consumer plastics being recycled in any appreciable quantity. e Thermosets can not be melted...Centrifuge Not included tial nutrients Vacuum filter Not included 5 Produce pipeline quality Acid gas removal system Not included gas System Alternatives The...can be processed into a variety of organic chemicals and feed stocks, including benzene, toluene, xylene , napthalene, resins, and gasoline substitutes

  4. The chemical life(1).

    Science.gov (United States)

    Hodges, Nathan

    2015-01-01

    You write this narrative autoethnography to open up a conversation about our chemical lives. You go through your day with chemical mindfulness, questioning taken-for-granted ideas about natural and artificial, healthy and unhealthy, dependency and addiction, trying to understand the chemical messages we consume through the experiences of everyday life. You reflect on how messages about chemicals influence and structure our lives and why some chemicals are celebrated and some are condemned. Using a second-person narrative voice, you show how the personal is relational and the chemical is cultural. You write because you seek a connection, a chemical bond.

  5. Recovery methods in municipal refuse management

    Energy Technology Data Exchange (ETDEWEB)

    Affholder, M.; Gony, J.N.; Colardeau, J.

    1977-10-01

    Various refuse screening tecniques and methods for organizing selective collection of paper, cardboard, and glass are described. Recovery of incinerated refuse developed by USBM and the French Bureau of Geological and Mining Research is detailed. The economics of municipal refuse recovery methods are examined. The sale of recovered material is explored.

  6. Nutrition for recovery in aquatic sports.

    Science.gov (United States)

    Burke, Louise M; Mujika, Iñigo

    2014-08-01

    Postexercise recovery is an important topic among aquatic athletes and involves interest in the quality, quantity, and timing of intake of food and fluids after workouts or competitive events to optimize processes such as refueling, rehydration, repair, and adaptation. Recovery processes that help to minimize the risk of illness and injury are also important but are less well documented. Recovery between workouts or competitive events may have two separate goals: (a) restoration of body losses and changes caused by the first session to restore performance for the next and (b) maximization of the adaptive responses to the stress provided by the session to gradually make the body become better at the features of exercise that are important for performance. In some cases, effective recovery occurs only when nutrients are supplied, and an early supply of nutrients may also be valuable in situations in which the period immediately after exercise provides an enhanced stimulus for recovery. This review summarizes contemporary knowledge of nutritional strategies to promote glycogen resynthesis, restoration of fluid balance, and protein synthesis after different types of exercise stimuli. It notes that some scenarios benefit from a proactive approach to recovery eating, whereas others may not need such attention. In fact, in some situations it may actually be beneficial to withhold nutritional support immediately after exercise. Each athlete should use a cost-benefit analysis of the approaches to recovery after different types of workouts or competitive events and then periodize different recovery strategies into their training or competition programs.

  7. 7 CFR 1779.95 - Future recovery.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Future recovery. 1779.95 Section 1779.95 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE DISPOSAL PROGRAMS GUARANTEED LOANS § 1779.95 Future recovery. After a loan...

  8. A Modest Proposal about Bereavement and Recovery

    Science.gov (United States)

    Balk, David E.

    2008-01-01

    The author argues that the term "recovery" aptly describes the trajectory following the bereavement of most persons. While the term "resilience" has gained ascendancy in the thanatology literature and the term "recovery" has been dismissed as inappropriate to denote responses over time to being bereaved, the irony is that all dictionaries of the…

  9. Recovery from Psychosis: A Phenomenological Inquiry

    Science.gov (United States)

    Nixon, Gary; Hagen, Brad; Peters, Tracey

    2010-01-01

    While mainstream psychiatry tends to view psychosis as an enduring and chronic condition, there is growing interest in the possibility of recovery from psychosis. A phenomenological research method was utilized in interviewing 17 individuals who all self-identified as being in recovery from psychosis. The research question was, "What was the lived…

  10. Immiscible foam for enhancing oil recovery

    NARCIS (Netherlands)

    Simjoo, M.

    2012-01-01

    Growing worldwide oil demand increased the need of new and efficient oil recovery methods. Gas injection in oil reservoirs is deemed one of the most widely used methods to increase oil recovery. However, the full potential of gas injection is often not realized due to poor vertical and areal sweep e

  11. Electrochemical phosphate recovery from nanofiltration concentrates

    NARCIS (Netherlands)

    Kappel, C.; Yasadi, K.; Temmink, B.G.; Metz, S.J.; Kemperman, A.J.B.; Nijmeijer, K.; Zwijnenburg, A.; Witkamp, G.J.; Rijnaarts, H.

    2013-01-01

    The high total phosphorus content of raw domestic wastewater with its significant eutrophication potential offers an excellent possibility for phosphate recovery. Continuous recirculation of NF concentrate to an MBR and simultaneous phosphate recovery from the NF concentrate can be applied to produc

  12. 75 FR 6681 - National Disaster Recovery Framework

    Science.gov (United States)

    2010-02-10

    ... SECURITY Federal Emergency Management Agency National Disaster Recovery Framework AGENCY: Federal Emergency... accepting comments on the draft National Disaster Recovery Framework (NDRF). The NDRF is intended to work in concert with the National Response Framework to provide organizing constructs and principles solely...

  13. Immiscible foam for enhancing oil recovery

    NARCIS (Netherlands)

    Simjoo, M.

    2012-01-01

    Growing worldwide oil demand increased the need of new and efficient oil recovery methods. Gas injection in oil reservoirs is deemed one of the most widely used methods to increase oil recovery. However, the full potential of gas injection is often not realized due to poor vertical and areal sweep e

  14. Carbon dioxide recovery: large scale design trends

    Energy Technology Data Exchange (ETDEWEB)

    Mariz, C.L. [Fluor Daniel Inc. (United States)

    1995-10-01

    The key design, operating issues, and trends are examined for new unit designs that hold potential for reducing the costs of CO{sub 2} recovery from flue gas. The ECONAMINE FG process is described. Operating costs for a CO{sub 2} recovery plant depend on size and CO{sub 2} content of the incoming stream. An operating cost breakdown and capital recovery analysis is given for a 1000 tonne/day CO{sub 2} recovery plant with a hypothetical U.S. Gulf Coast location. The analysis shows that the plant is not economic at the current price of crude oil. It is concluded that much larger plants (2000 tonne/day and larger) and newer and lower energy solvents could make carbon dioxide from flue gases attractive for enhanced oil recovery. 11 refs., 4 figs., 2 tabs.

  15. Development of krypton recovery and storage technology

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Shin-ichiro; Shoji, Hisashi; Kurihara, Takayuki; Kawashima, Nobuyoshi [Japan Nuclear Cycle Development Inst., Tokai Works, Tokai, Ibaraki (Japan); Osawa, Toshiyuki; Yamato, Haruo; Aizawa, Toshihiro [Sanko Inc., Tokyo (Japan)

    2002-12-01

    The Krypton-Recovery Development Facility was constructed as a pilot plant which has a piratical capacity at Tokai Reprocessing Plant. Various tests such as performance confirmation corresponding to parameter changing of each process by cold test, safety assurance of confinement performance of radioactive gas etc. and confirmation of the krypton recovery rate by connecting run with the reprocessing process were executed in order to develop recovery and storage technology of radioactive krypton from the shearing and dissolution process off-gas aiming to reduce the release of radioactivity to the environment. As a result, it was assured that krypton recovery rate with a cryogenic distillation was beyond the target value of 90% as krypton recovery technology, and storage technology by high pressure cylinder method was established as storage technology of recovered krypton. The immobilization technology of recovered krypton that is necessary for long term storage by ion implantation method is under development. (author)

  16. Activities of the Oil Implementation Task Force; Contracts for field projects and supporting research on enhanced oil recovery, July--September 1990

    Energy Technology Data Exchange (ETDEWEB)

    Tiedemann, H.A. (ed.) (USDOE Bartlesville Project Office, OK (USA))

    1991-05-01

    The report contains a general introduction and background to DOE's revised National Energy Strategy Advanced Oil Recovery Program and activities of the Oil Implementation Task Force; a detailed synopsis of the symposium, including technical presentations, comments and suggestions; a section of technical information on deltaic reservoirs; and appendices containing a comprehensive listing of references keyed to general deltaic and geological aspects of reservoirs and those relevant to six selected deltaic plays. Enhanced recovery processes include chemical floodings, gas displacement, thermal recovery, geoscience, and microbial recovery.

  17. Sorption recovery of copper (II and zinc (II from chloride aqueous solutions

    Directory of Open Access Journals (Sweden)

    Kononova Olga N.

    2014-01-01

    Full Text Available The present investigation is devoted to simultaneous sorption recovery of copper (II and zinc (II ions on some commercial anion exchangers with different physical-chemical properties. The initial concentrations of zinc and copper were 1-3 mmol L-1 and the recovery was carried out in 0.01 M and 2 M hydrochloric acid solutions. It was shown that the investigated anion exchangers possess good sorption and kinetic properties. After the recovery of copper and zinc from strong acidic solutions, their selective elution was carried out by means of 2 M hydrochloric acid solution (zinc recovery and 2 M ammonia solution (copper recovery. In weak acidic solutions, copper and zinc were separated during sorption, as zinc sorption did not proceed in this case. The subsequent copper (II elution was carried out by 2 M ammonia solution. The anion exchangers Purolite S985, Purolite A500 and AM-2B can be recommended for zinc and copper recovery from acidic industrial solutions and waste water.

  18. Improved oil recovery (IOR). Possibility and challenges on the Norwegian continental shelf

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-01

    Recently, estimates of the oil reserves on the Norwegian continental shelf have been substantially adjusted upwards due to technological development. In this report, the Norwegian Petroleum Directorate presents the current status. Based on current technology and recovery plans, an average of 41% of the oil that was originally in place in Norwegian fields will be recovered. Of these reserves, totaling just over 3 billion Sm{sup 3} of oil, about half have been produced. The potential for improved oil recovery is estimated at 1 billion Sm{sup 3} and it is anticipated that this potential can be realised. The objective is to attain an average recovery factor of at least 50%. Among the great technological advances that have taken place are developments within drilling and well technology and better techniques for reservoir management and reservoir monitoring. Technology using chemicals is available that will counteract increased water production and unwanted breakthrough of gas in oil producing wells. A significant part of the development of improved oil recovery technology is made jointly by the oil companies, often with the authorities as active providers. FORCE (FOrum for Reservoir Characterisation and reservoir Engineering) has been established in this context as a central forum for exchange of experience. Gas injection will be an efficient way of achieving high recovery factors for a number of fields. The foremost objective in projects for improved oil recovery is to be capable of achieving a total value creation while also ensuring that environmental considerations are taken into account. 21 figs., 2 tabs.

  19. Comparison Study of Different Ionic Liquid Pretreatments in Maximizing Total Reducing Sugars Recovery

    Directory of Open Access Journals (Sweden)

    Kiat Moon Lee

    2014-01-01

    Full Text Available A process scheme combining the most suitable ionic liquid pretreatment, followed by solid acid and enzymatic saccharification was used to maximize the reducing sugars recovery from sago waste. Three types of ionic liquids, i.e. 1-butyl-3-methylimidazolium chloride ([BMIM]Cl, 1-ethyl-3-methylimidazolium acetate ([EMIM][OAc] and 1-ethyl-3-methylimidazolium diethyl phosphate ([EMIM][(EtO2PO2] were evaluated based on their performance in terms of the total reducing sugars recovery, chemical cost, and pretreatment energy requirement. The results showed that all the ionic liquids assisted the saccharification processes by dissolving and depolymerizing the carbohydrates of the sago waste into shorter chain soluble oligosaccharides, as well as disrupting the biomass structure to produce an amorphous pretreated solid residue. The solid acid saccharifications of the prehydrolysates obtained from the [BMIM]Cl pretreatment gave the highest reducing sugars recovery (61-63% irrespective of the solid acid catalyst employed. On the other hand, enzymatic saccharification of [EMIM][OAc] pretreated solid residues showed the highest reducing sugars recovery (29%. A maximum recovery of 90% reducing sugars was achieved via incorporation of the ionic liquid pretreatment, solid acid and enzymatic saccharifications using [BMIM]Cl, Amberlyst 15 (A15 and Trichoderma viride cellulase respectively. This study suggests that the combined sequential process can maximize the reducing sugars recovery from sago waste effectively.

  20. Stage 2 vapor recovery system

    Energy Technology Data Exchange (ETDEWEB)

    Koch, W.H.; Strock, D.J.; Butkovich, M.S.; Hartman, H.B.

    1993-05-25

    A vapor recovery system is described, comprising: a set of elongated underground storage tanks, each storage tank containing a different grade of gasoline; vent pipes; a series of dispensing units; fuel flow lines; vapor return lines; an array of fuel pumps for pumping gasoline from said storage tanks to said dispenser units; an elongated condensate liquid pickup tube; an elongated inner spout providing a fuel conduit and having an outer tip defining a fuel outlet for discharging gasoline into a filler pipe of a motor vehicle tank during fueling; an outer spout assembly; extending into and engaging said spout-receiving socket, said outer spout assembly comprising an outer spout providing a vapor return conduit and defining apertures providing a vapor inlet spaced from said fuel outlet for withdrawing, removing, and returning a substantial amount of gasoline vapors emitted during said fueling; an elongated liquid sensing tube; a manually operable level; a flow control valve assembly; an automatic shutoff valve assembly; and a venturi sleeve assembly positioned in said venturi sleeve receiving chamber.

  1. Ceramic Membranes for Ammonia Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Camus, O.; Perera, S.; Crittenden, B. [Department of Chemical Engineering, University of Bath, Bath, BA2 7AY (United Kingdom); Van Delft, Y.C.; Meyer, D.F.; Pex, P.P.A.C. [ECN Solar Energy, Westerduinweg 3, P.O. Box 1, 1755 ZG Petten (Netherlands); Kumakiri, I.; Miachon, S.; Dalmon, J.A. [CNRS-Institut de Recherches sur la Catalyse 2, av. A. Einstein, 69626 Villeurbanne (France); Tennison, S. [MAST Carbon, Ltd., Henley Park, Guildford, Surrey, GU3 2AF (United Kingdom); Chanaud, P. [Pall-Exekia, BP1, Usine a Bazet (France); Groensmit, E. [Kemira GrowHow SA/NV, Avenue Einstein 11, B-1300 Wavre (Belgium); Nobel, W. [Continental Engineers BV, Rustenburg 114, 1506 AZ Zaandam (Netherlands)

    2008-12-15

    An extensive screening program has been performed to find a suitable membrane configuration and operating conditions for the effective recovery of ammonia from the syngas loop. All the experiments have been performed at steady state. MFI zeolite membranes in tubular and multi-channel fiber configurations have been tested along with tubular silica membranes. At 80C, a high ammonia permeance (2.1 x 10{sup -7} mol.m{sup -2}.s{sup -1}.Pa{sup -1}), and a selectivity of about 10 were found with the tubular zeolite membrane, whereas for the silica membrane an even higher ammonia permeance was measured (7.6 x 10{sup -7} mol.m{sup -2}.s{sup -1}.Pa{sup -1}) with a selectivity of about 7. For both silica and zeolite membranes, the selectivity was found to increase with increasing temperature up to 80C. This is a combined effect of weaker adsorption of ammonia and increased diffusion at higher temperature. The results have been modeled using both the well-mixed reactor and the log mean pressure difference approaches. To overcome their limitations in addressing changes in feed concentration along the membrane surface, a segmental model has been used to obtain suitable operating conditions and membrane areas required for an industrial application.

  2. Californium Recovery from Palladium Wire

    Energy Technology Data Exchange (ETDEWEB)

    Burns, Jon D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-08-01

    The recovery of 252Cf from palladium-252Cf cermet wires was investigated to determine the feasibility of implementing it into the cermet wire production operation at Oak Ridge National Laboratory’s Radiochemical Engineering Development Center. The dissolution of Pd wire in 8 M HNO3 and trace amounts of HCl was studied at both ambient and elevated temperatures. These studies showed that it took days to dissolve the wire at ambient temperature and only 2 hours at 60°C. Adjusting the ratio of the volume of solvent to the mass of the wire segment showed little change in the kinetics of dissolution, which ranged from 0.176 mL/mg down to 0.019 mL/mg. A successful chromatographic separation of 153Gd, a surrogate for 252Cf, from Pd was demonstrated using AG 50x8 cation exchange resin with a bed volume of 0.5 mL and an internal diameter of 0.8 cm.

  3. Californium Recovery from Palladium Wire

    Energy Technology Data Exchange (ETDEWEB)

    Burns, Jon D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-08-01

    The recovery of 252Cf from palladium-252Cf cermet wires was investigated to determine the feasibility of implementing it into the cermet wire production operation at Oak Ridge National Laboratory’s Radiochemical Engineering Development Center. The dissolution of Pd wire in 8 M HNO3 and trace amounts of HCl was studied at both ambient and elevated temperatures. These studies showed that it took days to dissolve the wire at ambient temperature and only 2 hours at 60°C. Adjusting the ratio of the volume of solvent to the mass of the wire segment showed little change in the kinetics of dissolution, which ranged from 0.176 mL/mg down to 0.019 mL/mg. A successful chromatographic separation of 153Gd, a surrogate for 252Cf, from Pd was demonstrated using AG 50x8 cation exchange resin with a bed volume of 0.5 mL and an internal diameter of 0.8 cm.

  4. The decreasing importance of acidification episodes with recovery from acidification: an analysis of the 30-year record from Birkenes, Norway

    Directory of Open Access Journals (Sweden)

    R. F. Wright

    2007-09-01

    Full Text Available The 30-year record 1975–2004 of weekly samples of streamwater chemistry from Birkenes, Norway, shows 106 acid episodes below the threshold of ANC –50 μeq l−1. The frequency, severity and duration of episodes have diminished since about 1990 due to chemical recovery following reduced deposition of sulphur. In particular SO4-driven episodes in the first runoff following drought have become less intense and less frequent, whereas episodes driven by climate (wind, high flow continue. The data show significant empirical relationships between strength of the driver, degree of chemical recovery, and severity of ANC depression.

  5. The decreasing importance of acidification episodes with recovery from acidification: an analysis of the 30-year record from Birkenes, Norway

    Directory of Open Access Journals (Sweden)

    R. F. Wright

    2008-03-01

    Full Text Available The 30-year record 1975–2004 of weekly samples of streamwater chemistry from Birkenes, Norway, shows 106 acid episodes below the threshold of ANC−50 µeq l−1. The frequency, severity and duration of episodes have diminished since about 1990 due to chemical recovery following reduced deposition of sulphur. In particular SO4-driven episodes in the first runoff following drought have become less intense and less frequent, whereas episodes driven by climate (wind, high flow continue. The data show significant empirical relationships between strength of the driver, degree of chemical recovery, and severity of ANC depression.

  6. Recovery post treatment: plans, barriers and motivators

    Directory of Open Access Journals (Sweden)

    Duffy Paul

    2013-01-01

    Full Text Available Abstract Background The increasing focus on achieving a sustained recovery from substance use brings with it a need to better understand the factors (recovery capital that contribute to recovery following treatment. This work examined the factors those in recovery perceive to be barriers to (lack of capital or facilitators of (presence of capital sustained recovery post treatment. Methods A purposive sample of 45 participants was recruited from 11 drug treatment services in northern England. Semi-structured qualitative interviews lasting between 30 and 90 minutes were conducted one to three months after participants completed treatment. Interviews examined key themes identified through previous literature but focused on allowing participants to explore their unique recovery journey. Interviews were transcribed and analysed thematically using a combination of deductive and inductive approaches. Results Participants generally reported high levels of confidence in maintaining their recovery with most planning to remain abstinent. There were indications of high levels of recovery capital. Aftercare engagement was high, often through self referral, with non substance use related activity felt to be particularly positive. Supported housing was critical and concerns were raised about the ability to afford to live independently with financial stability and welfare availability a key concern in general. Employment, often in the substance use treatment field, was a desire. However, it was a long term goal, with substantial risks associated with pursuing this too early. Positive social support was almost exclusively from within the recovery community although the re-building of relationships with family (children in particular was a key motivator post treatment. Conclusions Addressing internal factors and underlying issues i.e. ‘human capital’, provided confidence for continued recovery whilst motivators focused on external factors such as family and

  7. Existing chemicals: international activities.

    Science.gov (United States)

    Purchase, J F

    1989-01-01

    The standards of care used in the protection of the health and safety of people exposed to chemicals has increased dramatically in the last decade. Standards imposed by regulation and those adopted by industry have required a greater level of knowledge about the hazards of chemicals. In the E.E.C., the 6th amendment of the dangerous substances directive imposed the requirement that al new chemicals should be tested according to prescribed programme before introduction on to the market. The development of a European inventory of existing chemicals was an integral part of the 6th amendment. It has now become clear that increased standards of care referred to above must be applied to the chemicals on the inventory list. There is, however, a considerable amount of activity already under way in various international agencies. The OECD Chemicals Programme has been involved in considering the problem of existing chemicals for some time, and is producing a priority list and action programme. The International Programme on Chemical Safety produces international chemical safety cards, health and safety guides and environmental health criteria documents. The international register of potentially toxic compounds (part of UNEP) has prepared chemical data profiles on 990 compounds. The International Agency for Research on Cancer prepared monographs on the carcinogenic risk of chemicals to man. So far 42 volumes have been prepared covering about 900 substances. IARC and IPCS also prepare periodic reports on ongoing research on carcinogenicity or toxicity (respectively) of chemicals. The chemical industry through ECETOC (the European Chemical Industry Ecology and Toxicology Centre) has mounted a major initiative on existing chemicals. Comprehensive reviews of the toxicity of selected chemicals are published (Joint Assessment of Commodity Chemicals). In its technical report no. 30 ECETOC lists reviews and evaluations by major national and international organisations, which provides

  8. Process Model of A Fusion Fuel Recovery System for a Direct Drive IFE Power Reactor

    Science.gov (United States)

    Natta, Saswathi; Aristova, Maria; Gentile, Charles

    2008-11-01

    A task has been initiated to develop a detailed representative model for the fuel recovery system (FRS) in the prospective direct drive inertial fusion energy (IFE) reactor. As part of the conceptual design phase of the project, a chemical process model is developed in order to observe the interaction of system components. This process model is developed using FEMLAB Multiphysics software with the corresponding chemical engineering module (CEM). Initially, the reactants, system structure, and processes are defined using known chemical species of the target chamber exhaust. Each step within the Fuel recovery system is modeled compartmentally and then merged to form the closed loop fuel recovery system. The output, which includes physical properties and chemical content of the products, is analyzed after each step of the system to determine the most efficient and productive system parameters. This will serve to attenuate possible bottlenecks in the system. This modeling evaluation is instrumental in optimizing and closing the fusion fuel cycle in a direct drive IFE power reactor. The results of the modeling are presented in this paper.

  9. Leak detection and localization system through acoustics; Sistema de deteccao e localizacao de vazamentos por acustica

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Julio [Aselco Automacao, Sao Paulo, SP (Brazil)

    2003-07-01

    Acoustic Leak Detection Systems (ALDS) are used on both liquid and gas pipelines as well as multi-phase flow pipelines to detect leaks quickly and provide a means of limiting product loss. The real-time acoustic signal is continuously compared against signature leak profiles for the particular operating and geometric conditions. These profiles were developed from a database established from over 20 years of experimental and field leak tests. This technique not only drastically reduces the false alarm rate, but also significantly improves the sensitivity and leak location accuracy. This system will also detect leaks with shut-in flow (zero flow rate in the pipeline). With the use of GPS (Global Positioning System) it not only improves leak location accuracy, but also allows for continuous leak detection during the loss of communications. (author)

  10. Sulfate reducing bacteria detection in gas pipelines; Deteccao de bacterias redutoras de sulfato em gasodutos

    Energy Technology Data Exchange (ETDEWEB)

    Lutterbach, Marcia Teresa S.; Oliveira, Ana Lucia C. de; Cavalcanti, Eduardo H. de S. [Instituto Nacional de Tecnologia (INT), Rio de Janeiro, RJ (Brazil). Div. de Corrosao e Degradacao]. E-mails: marciasl@int.gov.br; analucia@int.gov.br; eduardoh@int.gov.br

    2004-07-01

    Microbiology induced corrosion (MIC) process associated with sulfate reducing bacteria (BRS) are one of the most important matter of concern for the oil and gas industry as 77% of failures have been attributed this sort of degradation. Corrosion products found present in gas transportation pipelines, the so-called 'black-powder' problem, are also a nuisance and source of economic losses for the gas industry. According to the literature, the incidence of black-powder can be ascribed to the metabolism of BRS that can be found in the gas environment. Integrity monitoring programs of gas pipelines adopt pigging as an important tool for internal corrosion monitoring. Solid residue such as the black-powder, collected by pigging, as well as the condensed, can be seen as a very valuable samples for microbiological analyses that can be used to detect and quantify bacteria related to the incidence of MIC processes. In the present work results concerning samples collected by pigging and condensed are presented. Small populations of viable BRS have been found in the pipeline. It can be seen that the inclusion of microbiological analyses of solid and liquid residues as a complementary action in the integrity monitoring programs adopted by gas transportation industry can be very helpful on the decision making concerning preventive and corrective actions to be taken in order to maintain the CIM processes under control. (author)

  11. Algorithms for boundary detection in radiographic images; Algoritmos de deteccao de bordas em imagens radiograficas

    Energy Technology Data Exchange (ETDEWEB)

    Gonzaga, Adilson [Sao Paulo Univ., Sao Carlos, SP (Brazil). Escola de Engenharia. Dept. de Engenharia Eletrica; Franca, Celso Aparecido de [Sao Paulo Univ., SP (Brazil). Inst. de Fisica. Dept. de Fisica e Informatica

    1996-12-31

    Edge detecting techniques applied to radiographic digital images are discussed. Some algorithms have been implemented and the results are displayed to enhance boundary or hide details. An algorithm applied in a pre processed image with contrast enhanced is proposed and the results are discussed 5 refs., 4 figs.

  12. Detection of plastic explosives by thermic neutron radiography; Deteccao de explosivos plasticos por neutrongrafia termica

    Energy Technology Data Exchange (ETDEWEB)

    Hacidume, Leo R.; Crispim, Verginia R.; Silva, Ademir X. da [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear

    2000-07-01

    This work aims to demonstrate the potentiality of the neutron radiography technique, allied to the computerized tomography by transmission, to both detect and visualize plastic explosive samples in several hidden conditions, using a simple scanner as a digitalisation instrument. Each tomographic essay was obtained in the J-9 channel of the Argonauta Research Reactor of IEN/CNEN, in groups of six neutron radiographic projections, performed with an angular increment of 30 in a period of time of 30 minutes for each projection. Two groups of tomographic reconstructions were generated, distinguished by the digitalisation process of the interested lines in the reconstruction plane coming from the projection groups, utilizing a scanner and a microdensitometer, respectively. The reconstruction of the bi-dimensional image of the transverse section, in relation to this plane, was processed making use of the Image reconstruction algorithmic of an image based on the maximum entropy principle (ARIEM). From the qualitative analysis of the images, we conclude that the neutron radiographic system was able to detect the explosive sample in a satisfactory way while the quantitative analysis confirmed the application effectiveness of a scanner to acquire the projection dates whose objective is only a reconnaissance. (author)

  13. Detection of plastic explosives using thermal neutron radiography; Deteccao de explosivos plasticos por neutrongrafia termica

    Energy Technology Data Exchange (ETDEWEB)

    Hacidume, Leo Ryoske

    1999-12-01

    The work aims to demonstrate the potentiality of the neutron radiography technique, allied to the computerized tomography by transmission, to both detect and visualize plastic explosive samples in several hidden conditions, using a simple scanner as a digitalisation instrument. Each tomographic essay was obtained in the J-9 channel of the Argonauta Research Reactor of IEN/CNEN, in groups of six neutron radiographic projections, performed with an angular increment of 30 deg C, in a period of time of 30 minutes for each projection. Two groups of tomographic reconstructions were generated, distinguished by the digitalisation process of the interested lines in the reconstruction plane coming from the projection groups, utilization a scanner and a microdensitometer, respectively. The reconstruction of the bi-dimensional image of the transverse section, in relation to this plane, was processed making use of the Image Reconstruction Algorithmic of an Image based on the Maximum Entropy principle (ARIEM). From the qualitative analysis of the images, we conclude that the neutron radiographic system was able to detect the explosive sample in a satisfactory way while the quantitative analysis confirmed the application effectiveness of a scanner to acquire the projection dates whose objective is only a reconnaissance. (author)

  14. Identification of environmentally relevant chemicals in bibliographic databases: a comparative analysis

    DEFF Research Database (Denmark)

    Ellegaard, Ole; Wallin, Johan Albert

    2013-01-01

    takes as its starting point environmentally important chemicals and the retrieval of selectively chosen substances in the four databases: SciFinder, Web of Science (WoS), Scopus and Google Scholar. The way chemical data are stored in the databases plays a major role in the recovery process...

  15. Identification of environmentally relevant chemicals in bibliographic databases: a comparative analysis

    DEFF Research Database (Denmark)

    Ellegaard, Ole; Wallin, Johan Albert

    2013-01-01

    takes as its starting point environmentally important chemicals and the retrieval of selectively chosen substances in the four databases: SciFinder, Web of Science (WoS), Scopus and Google Scholar. The way chemical data are stored in the databases plays a major role in the recovery process...

  16. Advances in chemical physics

    CERN Document Server

    Rice, Stuart A

    2012-01-01

    The Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Quantum Dynamical Resonances in Ch

  17. Components in Chemical Thermodynamics

    Science.gov (United States)

    Alberty, Robert A.

    1995-09-01

    Chemical equations are actually matrix equations, and this has important implications for their thermodynamic treatment. The fundamental equation for chemical thermodynamics for a chemical reaction system can be written in terms of species, but at chemical equilibrium, it has to be written in terms of components. The number of components is equal to the number of species minus the number of independent chemical reactions. The fundamental equation for the Gibbs energy of a system containing ethylene, methane, ethane, and propane is discussed. At chemical equilibrium there are two components, which can be taken to be carbon and hydrogen or ethylene and methane. There are advantages in using matrix notation.

  18. Recovery in England: transforming statutory services?

    Science.gov (United States)

    Perkins, Rachel; Slade, Mike

    2012-02-01

    English mental health policy has explicitly supported a focus on recovery since 2001. More recently, this has been elaborated through policy support for social inclusion, employment and well-being. We review several drivers for this political orientation, including a refocusing of the role of health services as a whole from treating illnesses to helping people to make the most of their lives, the shift to greater power for the individual, reflected in personal social care and personal health budgets, and the evidence informing clinical guidelines issued by the National Institute for Health and Clinical Excellence (NICE). A disjunction remains between policy and practice, with organizational policies espousing a recovery orientation and teams re-branding as 'recovery and support' teams, whilst pursuing clinical practices which prioritize symptomatic treatment rather than recovery support. The next phase of development in English statutory mental health services is therefore bridging this gap, through organizational transformation in mental health services towards a focus on recovery. We describe two funded initiatives to support this process of organizational transformation. The first (ImROC) is a national initiative to develop a pro-recovery organizational climate. The second (REFOCUS) is a multi-site cluster randomized controlled trial (ISRCTN02507940) investigating a team-level pro-recovery intervention.

  19. Localized recovery of complex networks against failure

    Science.gov (United States)

    Shang, Yilun

    2016-07-01

    Resilience of complex networks to failure has been an important issue in network research for decades, and recent studies have begun to focus on the inverse recovery of network functionality through strategically healing missing nodes or edges. However, the effect of network recovery is far from fully understood, and a general theory is still missing. Here we propose and study a general model of localized recovery, where a group of neighboring nodes are restored in an invasive way from a seed node. We develop a theoretical framework to compare the effect of random recovery (RR) and localized recovery (LR) in complex networks including Erdős-Rényi networks, random regular networks, and scale-free networks. We find detailed phase diagrams for the subnetwork of occupied nodes and the “complement network” of failed nodes under RR and LR. By identifying the two competitive forces behind LR, we present an analytical and numerical approach to guide us in choosing the appropriate recovery strategy and provide estimation on its effect by using the degree distribution of the original network as the only input. Our work therefore provides insight for quantitatively understanding recovery process and its implications in infrastructure protection in various complex systems.

  20. Adaptation to and Recovery from Global Catastrophe

    Directory of Open Access Journals (Sweden)

    Seth D. Baum

    2013-03-01

    Full Text Available Global catastrophes, such as nuclear war, pandemics and ecological collapse threaten the sustainability of human civilization. To date, most work on global catastrophes has focused on preventing the catastrophes, neglecting what happens to any catastrophe survivors. To address this gap in the literature, this paper discusses adaptation to and recovery from global catastrophe. The paper begins by discussing the importance of global catastrophe adaptation and recovery, noting that successful adaptation/recovery could have value on even astronomical scales. The paper then discusses how the adaptation/recovery could proceed and makes connections to several lines of research. Research on resilience theory is considered in detail and used to develop a new method for analyzing the environmental and social stressors that global catastrophe survivors would face. This method can help identify options for increasing survivor resilience and promoting successful adaptation and recovery. A key point is that survivors may exist in small isolated communities disconnected from global trade and, thus, must be able to survive and rebuild on their own. Understanding the conditions facing isolated survivors can help promote successful adaptation and recovery. That said, the processes of global catastrophe adaptation and recovery are highly complex and uncertain; further research would be of great value.

  1. Do psychological variables affect early surgical recovery?

    Directory of Open Access Journals (Sweden)

    Michael N Mavros

    Full Text Available BACKGROUND: Numerous studies have examined the effect of psychological variables on surgical recovery, but no definite conclusion has been reached yet. We sought to examine whether psychological factors influence early surgical recovery. METHODS: We performed a systematic search in PubMed, Scopus and PsycINFO databases to identify studies examining the association of preoperative psychological variables or interventions with objectively measured, early surgical outcomes. RESULTS: We identified 16 eligible studies, 15 of which reported a significant association between at least one psychological variable or intervention and an early postoperative outcome. However, most studies also reported psychological factors not influencing surgical recovery and there was significant heterogeneity across the studies. Overall, trait and state anxiety, state anger, active coping, subclinical depression, and intramarital hostility appeared to complicate recovery, while dispositional optimism, religiousness, anger control, low pain expectations, and external locus of control seemed to promote healing. Psychological interventions (guided relaxation, couple support visit, and psychiatric interview also appeared to favor recovery. Psychological factors unrelated to surgical outcomes included loneliness, perceived social support, anger expression, and trait anger. CONCLUSION: Although the heterogeneity of the available evidence precludes any safe conclusions, psychological variables appear to be associated with early surgical recovery; this association could bear important implications for clinical practice. Large clinical trials and further analyses are needed to precisely evaluate the contribution of psychology in surgical recovery.

  2. 76 FR 58781 - Endangered and Threatened Species; Recovery Plans; Recovery Plan for the Kemp's Ridley Sea Turtle

    Science.gov (United States)

    2011-09-22

    ... Plans; Recovery Plan for the Kemp's Ridley Sea Turtle AGENCY: National Marine Fisheries Service (NMFS...- National Recovery Plan (Recovery Plan) for the Kemp's Ridley Sea Turtle (Lepidochelys kempii). The Recovery...: The Bi-National Recovery Plan for the Kemp's Ridley Sea Turtle (Lepidochelys kempii) is available...

  3. Functional recovery after cervical spinal cord injury: Role of neurotrophin and glutamatergic signaling in phrenic motoneurons.

    Science.gov (United States)

    Gill, Luther C; Gransee, Heather M; Sieck, Gary C; Mantilla, Carlos B

    2016-06-01

    Cervical spinal cord injury (SCI) interrupts descending neural drive to phrenic motoneurons causing diaphragm muscle (DIAm) paralysis. Recent studies using a well-established model of SCI, unilateral spinal hemisection of the C2 segment of the cervical spinal cord (SH), provide novel information regarding the molecular and cellular mechanisms of functional recovery after SCI. Over time post-SH, gradual recovery of rhythmic ipsilateral DIAm activity occurs. Recovery of ipsilateral DIAm electromyogram (EMG) activity following SH is enhanced by increasing brain-derived neurotrophic factor (BDNF) in the region of the phrenic motoneuron pool. Delivery of exogenous BDNF either via intrathecal infusion or via mesenchymal stem cells engineered to release BDNF similarly enhance recovery. Conversely, recovery after SH is blunted by quenching endogenous BDNF with the fusion-protein TrkB-Fc in the region of the phrenic motoneuron pool or by selective inhibition of TrkB kinase activity using a chemical-genetic approach in TrkB(F616A) mice. Furthermore, the importance of BDNF signaling via TrkB receptors at phrenic motoneurons is highlighted by the blunting of recovery by siRNA-mediated downregulation of TrkB receptor expression in phrenic motoneurons and by the enhancement of recovery evident following virally-induced increases in TrkB expression specifically in phrenic motoneurons. BDNF/TrkB signaling regulates synaptic plasticity in various neuronal systems, including glutamatergic pathways. Glutamatergic neurotransmission constitutes the main inspiratory-related, excitatory drive to motoneurons, and following SH, spontaneous neuroplasticity is associated with increased expression of ionotropic N-methyl-d-aspartate (NMDA) receptors in phrenic motoneurons. Evidence for the role of BDNF/TrkB and glutamatergic signaling in recovery of DIAm activity following cervical SCI is reviewed.

  4. Predicting chemical impacts on vertebrate endocrine systems.

    Science.gov (United States)

    Nichols, John W; Breen, Miyuki; Denver, Robert J; Distefano, Joseph J; Edwards, Jeremy S; Hoke, Robert A; Volz, David C; Zhang, Xiaowei

    2011-01-01

    Animals have evolved diverse protective mechanisms for responding to toxic chemicals of both natural and anthropogenic origin. From a governmental regulatory perspective, these protective responses complicate efforts to establish acceptable levels of chemical exposure. To explore this issue, we considered vertebrate endocrine systems as potential targets for environmental contaminants. Using the hypothalamic-pituitary-thyroid (HPT), hypothalamic-pituitary-gonad (HPG), and hypothalamic-pituitary-adrenal (HPA) axes as case examples, we identified features of these systems that allow them to accommodate and recover from chemical insults. In doing so, a distinction was made between effects on adults and those on developing organisms. This distinction was required because endocrine system disruption in early life stages may alter development of organs and organ systems, resulting in permanent changes in phenotypic expression later in life. Risk assessments of chemicals that impact highly regulated systems must consider the dynamics of these systems in relation to complex environmental exposures. A largely unanswered question is whether successful accommodation to a toxic insult exerts a fitness cost on individual animals, resulting in adverse consequences for populations. Mechanistically based mathematical models of endocrine systems provide a means for better understanding accommodation and recovery. In the short term, these models can be used to design experiments and interpret study findings. Over the long term, a set of validated models could be used to extrapolate limited in vitro and in vivo testing data to a broader range of untested chemicals, species, and exposure scenarios. With appropriate modification, Tier 2 assays developed in support of the U.S. Environmental Protection Agency's Endocrine Disruptor Screening Program could be used to assess the potential for accommodation and recovery and inform the development of mechanistically based models.

  5. Ecological distribution of pelagic copepods and species relationship to acidification, liming and natural recovery in a boreal area

    Directory of Open Access Journals (Sweden)

    Svein Birger WÆRVÅGEN

    2003-02-01

    Full Text Available Distribution and ecology of pelagic copepods were studied in a boreal area strongly affected by acidification in southern Norway. Differential regional composition of bedrock geology and Quaternary deposits combined with liming have produced aquatic sites with contrasting acidification and recovery histories. The omnivorous species Eudiaptomus gracilis showed a striking ability to tolerate both acidification and chemical recovery. The predominantly carnivorous species Heterocope saliens increased numerically during acidification, both because it is tolerant to acidic environments and because fish predation diminished or disappeared altogether. After chemical recovery, H. saliens, having an endogenous egg-bank, most readily produced viable populations with numerical abundance depending upon fish predation pressure. Thermocyclops oithonoides and Cyclops scutifer were negatively affected by strongly acidic environments, whereas Mesocyclops leuckarti tolerated acidic conditions better. All three cyclopoid species increased in abundance after chemical recovery, most probably from small residual populations. The hypolimnetic C. scutifer faced dispersal problems in re-establishing following liming. Deep lakes (>20 m harboured considerable residual populations of C. scutifer which recovered rapidly to pre-acidic conditions. Cyclops abyssorum inhabited the pelagial during early recovery of formerly chronically acidified lakes as a fugitive species, probably due to rapid dispersal capacities. Littoral cyclopoids, such as Acanthocyclops vernalis and Diacyclops nanus, were commonly distributed in the free waters of the most acidic lakes (pH = 4.5-4.8, but disappeared from the pelagial shortly after chemical recovery. The total community of pelagic copepods forms a promising tool to identify historical acidification and trajectories of recovery in the freshwater environment.

  6. Application of Stochastic Resonance Signal Recovery

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ying; WANG Taiyong; LENG Yonggang; DENG Hui

    2009-01-01

    Stochastic resonance(SR) enhances the nonlinear system behavior with the assistance of noise, including the sensitivity and selectivity of the response to the exterior stimulus. The energy-transfer mechanism makes the weak information revealed in the output spectrum, while the time-waveform is distorted. The distortion analysis was made both from the particle's dynamics and signal processing. The factors causing the deviation in the output are presented and the function of the recovery system is proposed. By the investigation of the particle's motion track in the bistable system and the suggested recovery system, the influences of noise and system parameters on the recovery course were discussed. Moreover, the pulse distortion appearing the recovery waveform caused by the particle's transitions at the bistable potential' inflexions was explained. Due to different characteristics, cascaded-bistable SR or mono-stable SR was introduced to process different types of signals. The final recovery signal is just the suggested recovery system's response to the SR output. Meanwhile, the recovery system is optional, as parameter-tuned or parameter-fixed. Since the method requires no average processing, it is applicable to a single sample with limited length. The numerical simulations reveal that the SR recovery method can recover the waveform containing weak information submerged in noise effectively. The engineering application to the vibration analysis of metal cutting chose the combination of mono-stable SR and the parameter-fixed recovery system. Because the optimal SR state is not required strongly, the system parameters are tuned in a wider range than the traditional SR processing methods.

  7. Stress and Recovery during Simulated Microgravity

    Science.gov (United States)

    Nicolas, Michel

    The aim of this study was to determine the effects of a 60-day head-down tilt long-term bed rest (HDT) on stress and recovery in sixteen healthy female volunteers during the WISE-2005 study (Women International Space Simulation for Exploration). Participants were randomly assigned to either an exercise group (Exe) that followed a training program combining resistive and aerobic exercises, or to a no-exercise control group (Ctl). Psychological states were assessed using the Rest-Q, a validated questionnaire based on stress-recovery responses. A longitudinal analysis revealed significant changes in the general and specific stress scales for all participants throughout the experiment with a critical stage from supine to standing posture leading to a significant decrease in physical recovery. During HDT, Exe reported higher scores in stress subscales, as well as lower recovery scores compared to the Ctl. During the post HDT ambulatory recovery period, the exercisers still reported higher scores than the non-exercisers on the Lack of energy stress related scale, along with lower scores in general well-being and personal accomplishment. The present findings show that simulated weightlessness such as HDT may induce psychological stress and lead to subsequent alterations in perceived recovery. Exercise did not reduce HDT impaired effects on stress and recovery states. In the perspective of spaceflights of long-duration such as the future missions to Mars, there is a need for additional experiments to further investigate spaceflight-induced changes of stress and recovery parameters and the effects of exercise on these parameters. Further studies might determine and analyze the psychological factors involved, but also how to intervene concerning these factors with efficient psychological preparation which, although not yet fully investigated, may reduce stress, promote recovery and support adaptive responses to such extreme environments.

  8. Plasma glucagon and glucose recovery after hypoglycemia

    DEFF Research Database (Denmark)

    Hilsted, J; Frandsen, Henrik Lund; Holst, Janett

    1991-01-01

    ) and of isolated alpha-adrenergic blockade on hormonal responses to hypoglycemia and on blood glucose recovery after hypoglycemia in healthy subjects. Neither of the pharmacological blockades had any significant effects on plasma glucagon responses to hypoglycemia nor had they any effect on the rate of blood...... glucose recovery after hypoglycemia. We conclude that the autonomic nervous system has no major influence on the glucagon response to hypoglycemia in healthy man. Changes in autonomic nervous activity are not essential for blood glucose recovery after hypoglycemia in healthy man....

  9. Probabilistic Recovery Guarantees for Sparsely Corrupted Signals

    CERN Document Server

    Pope, Graeme; Studer, Christoph

    2012-01-01

    We consider the recovery of sparse signals subject to sparse interference, as introduced in Studer et al., IEEE Trans. IT, 2012. We present novel probabilistic recovery guarantees for this framework, covering varying degrees of knowledge of the signal and interference support, which are relevant for a large number of practical applications. Our results assume that the sparsifying dictionaries are solely characterized by coherence parameters and we require randomness only in the signal and/or interference. The obtained recovery guarantees show that one can recover sparsely corrupted signals with overwhelming probability, even if the sparsity of both the signal and interference scale (near) linearly with the number of measurements.

  10. Spousal recovery support, recovery experiences, and life satisfaction crossover among dual-earner couples.

    Science.gov (United States)

    Park, YoungAh; Fritz, Charlotte

    2015-03-01

    Research has indicated the importance of recovery from work stress for employee well-being and work engagement. However, very little is known about the specific factors that may support or hinder recovery in the context of dual-earner couples. This study proposes spousal recovery support as a potential resource that dual-earner couples can draw on to enhance their recovery experiences and well-being. It was hypothesized that spousal recovery support would be related to the recipient spouse's life satisfaction via his or her own recovery experiences (i.e., psychological detachment, relaxation, and mastery experiences). The study further investigated the crossover of life satisfaction between working spouses as a potential outcome of recovery processes. Data from 318 full-time employed married couples in South Korea were analyzed using structural equation modeling. Results showed that spousal recovery support was positively related to all 3 recovery experiences of the recipient spouse. Moreover, this recovery support was related to the recipient spouse's life satisfaction via relaxation and mastery experiences. Unexpectedly, psychological detachment was negatively related to life satisfaction, possibly indicating a suppression effect. Life satisfaction crossed over between working spouses. No gender differences were found in the hypothesized paths. Based on these findings, theoretical and practical implications are discussed, and future research directions are presented.

  11. Chemical Search Web Utility

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Chemical Search Web Utility is an intuitive web application that allows the public to easily find the chemical that they are interested in using, and which...

  12. Chemicals Industry Vision

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1996-12-01

    Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

  13. Tobacco and chemicals (image)

    Science.gov (United States)

    Some of the chemicals associated with tobacco smoke include ammonia, carbon dioxide, carbon monoxide, propane, methane, acetone, hydrogen cyanide and various carcinogens. Other chemicals that are associated with chewing ...

  14. Chemical Industry Bandwidth Study

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2006-12-01

    The Chemical Bandwidth Study provides a snapshot of potentially recoverable energy losses during chemical manufacturing. The advantage of this study is the use of "exergy" analysis as a tool for pinpointing inefficiencies.

  15. Capacitive chemical sensor

    Science.gov (United States)

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  16. Chemical thermodynamics: plenary review.

    Science.gov (United States)

    Fegley, B., Jr.

    1990-05-01

    The invited and contributed papers dealing with the applications of chemical thermodynamics to planetary atmospheres research are briefly reviewed. The key areas for future applications of chemical thermodynamics research to planetary atmospheres are also described.

  17. Hydrometallurgical Recovery of Precious Metals and Removal of Hazardous Metals Using Persimmon Tannin and Persimmon Wastes

    Directory of Open Access Journals (Sweden)

    Katsutoshi Inoue

    2015-10-01

    Full Text Available Novel and environmentally benign adsorbents were prepared via a simple sulfuric acid treatment process using the wastes of astringent persimmon, a type of biomass waste, along with persimmon tannin extract which is currently employed for the tanning of leather and as natural dyes and paints. The effectiveness of these new biosorbents was exemplified with regards to hydrometallurgical and environmental engineering applications for the adsorptive removal of uranium and thorium from rare earths, cesium from other alkaline metals such as sodium, hexa-valent chromium from zinc as well as adsorptive recovery of gold from chloride media. Furthermore, reductive coagulation of gold from chloride media for the direct recovery of metallic gold and adsorptive recovery of palladium and platinum using chemically modified persimmon tannin extract were studied. OPEN

  18. New perspectives for the design of sustainable bioprocesses for phosphorus recovery from waste.

    Science.gov (United States)

    Tarayre, Cédric; De Clercq, Lies; Charlier, Raphaëlle; Michels, Evi; Meers, Erik; Camargo-Valero, Miller; Delvigne, Frank

    2016-04-01

    Phosphate rock has long been used for the production of phosphorus based chemicals. However, considering the depletion of the reservoirs and the decrease of the quality of phosphate rocks, a potential market is now emerging for the recovery of phosphate from waste and its reuse for different applications. Notably, phosphate recovery from wastewater could be included in a circular economy approach. This review focuses on the use of microbial systems for phosphorus accumulation and recovery, by considering the actual range of analytical techniques available for the monitoring of phosphorus accumulating organisms, as well as the actual biochemical and metabolic engineering toolbox available for the optimization of bioprocesses. In this context, knowledge gathered from process, system and synthetic biology could potentially lead to innovative process design. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Improved Energy Recovery by Anaerobic Grey Water Sludge Treatment with Black Water

    Directory of Open Access Journals (Sweden)

    Taina Tervahauta

    2014-08-01

    Full Text Available This study presents the potential of combining anaerobic grey water sludge treatment with black water in an up-flow anaerobic sludge blanket (UASB reactor to improve energy recovery within source-separated sanitation concepts. Black water and the mixture of black water and grey water sludge were compared in terms of biochemical methane potential (BMP, UASB reactor performance, chemical oxygen demand (COD mass balance and methanization. Grey water sludge treatment with black water increased the energy recovery by 23% in the UASB reactor compared to black water treatment. The increase in the energy recovery can cover the increased heat demand of the UASB reactor and the electricity demand of the grey water bioflocculation system with a surplus of 0.7 kWh/cap/y electricity and 14 MJ/cap/y heat. However, grey water sludge introduced more heavy metals in the excess sludge of the UASB reactor and might therefore hinder its soil application.

  20. Experimental study on mass transfer of contaminants through an enthalpy recovery unit with polymer membrane foils

    DEFF Research Database (Denmark)

    Nie, Jinzhe; Fang, Lei

    2014-01-01

    recovery unit with polymer membrane foils was used as refeering unit in this study. The experiments were conducted with different outdoor thermal climates e.g. warm-humid and cold-dry climates; isothermal and non isothermal as well as equal humidity and non equal humidity with indoor climate. Three......Laboratory experimental studies were conducted to investigate the mass transfer of contaminants through a total heat recovery unit with polymer membranes foils. The studies were conducted in twin climate chambers which simulated outdoor and indoor thermal climates. One manufacturd total heat...... chemical gases were used to simulate air contaminants. The concentrations of dosed contaminants in the supply and exhaust air upstream and downstream of the total heat recovery unit were measured with Multi-Gas Monitor Innova 1316 in real time. Experiment results showed that 5% to 9% of dosed contaminants...

  1. Limited recovery of soil microbial activity after transient exposure to gasoline vapors

    DEFF Research Database (Denmark)

    Modrzyński, Jakub J.; Christensen, Jan H.; Mayer, Philipp

    2016-01-01

    During gasoline spills complex mixtures of toxic volatile organic compounds (VOCs) are released to terrestrial environments. Gasoline VOCs exert baseline toxicity (narcosis) and may thus broadly affect soil biota. We assessed the functional resilience (i.e. resistance and recovery of microbial...... functions) in soil microbial communities transiently exposed to gasoline vapors by passive dosing via headspace for 40 days followed by a recovery phase of 84 days. Chemical exposure was characterized with GC-MS, whereas microbial activity was monitored as soil respiration (CO2 release) and soil bacterial...... microbial activity indicating residual soil toxicity, which could not be attributed to BTEX, but rather to mixture toxicity of more persistent gasoline constituents or degradation products. Our results indicate a limited potential for functional recovery of soil microbial communities after transient...

  2. Analysis of energy recovery potential using innovative technologies of waste gasification.

    Science.gov (United States)

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2012-04-01

    In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production. Copyright © 2011 Elsevier Ltd. All rights reserved.

  3. Chemical Spill Response Manual

    NARCIS (Netherlands)

    Marieke Zeinstra; Wierd Koops

    2014-01-01

    A two year programme has been carried out by the NHL University of Applied Sciences together with private companies in the field of oil and chemical spill response to finalize these manuals on oil and chemical spill response. These manuals give a good overview of all aspects of oil and chemical spil

  4. Chemicals for worldwide aquaculture

    Science.gov (United States)

    Schnick, R.A.

    1991-01-01

    Regulations and therapeutants or other safe chemicals that are approved or acceptable for use in the aquaculture industry in the US, Canada, Europe and Japan are presented, discussing also compounds that are unacceptable for aquaculture. Chemical use practices that could affect public health are considered and details given regarding efforts to increase the number of registered and acceptable chemicals.

  5. Chemical Recycle of Plastics

    Directory of Open Access Journals (Sweden)

    Sara Fatima

    2014-11-01

    Full Text Available Various chemical processes currently prevalent in the chemical industry for plastics recycling have been discussed. Possible future scenarios in chemical recycling have also been discussed. Also analyzed are the effects on the environment, the risks, costs and benefits of PVC recycling. Also listed are the various types of plastics and which plastics are safe to use and which not after rcycle

  6. Chemical Physics Courses.

    Science.gov (United States)

    Lee, J.; Munn, R. W.

    1978-01-01

    This is a guide to the chemical physics major. The scope of chemical physics is presented, along with the general features of course contents and possible course structures. This information was derived from a survey of British universities and colleges offering undergraduate degree courses in chemical physics. (BB)

  7. Chemical Spill Response Manual

    NARCIS (Netherlands)

    Marieke Zeinstra; Wierd Koops

    2014-01-01

    A two year programme has been carried out by the NHL University of Applied Sciences together with private companies in the field of oil and chemical spill response to finalize these manuals on oil and chemical spill response. These manuals give a good overview of all aspects of oil and chemical

  8. Delmarva Fox Squirrel Recovery Plan 1979

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The primary objective of the Recovery Plan is to restore the Delmarva fox squirrel to secure status throughout its former range, which is described in this plan. The...

  9. Whooping crane recovery activities : April - September, 2006

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Summary of whooping crane recovery activities for April through September 2006 for the Aransas/Wood Buffalo flock, the Florida non-migratory flock, and captive...

  10. Metal recovery from high-grade WEEE

    DEFF Research Database (Denmark)

    Bigum, Marianne; Brogaard, Line Kai-Sørensen; Christensen, Thomas Højlund

    2012-01-01

    and refining of ore. The resource recovery per tonne of high-grade WEEE ranged from 2 g of palladium to 386 kg of iron. Quantified in terms of person-equivalents the recovery of palladium, gold, silver, nickel and copper constituted the major environmental benefit of the recovery of metals from WEEE......Based on available data in the literature the recovery of aluminium, copper, gold, iron, nickel, palladium and silver from high-grade WEEE was modeled by LCA. The pre-treatment of WEEE included manual sorting, shredding, magnetic sorting, Eddy-current sorting, air classification and optical sorting....... These benefits are most likely underestimated in the model, since we did not find adequate data to include all the burdens from mining and refining of ore; burdens that are avoided when metals are recovered from WEEE. The processes connected to the pre-treatment of WEEE were found to have little environmental...

  11. Developing sustainable resource recovery and recycling

    Energy Technology Data Exchange (ETDEWEB)

    Clapham, M. [Natural Resources Canada, Ottawa, ON (Canada). Minerals and Metals Sector

    2003-07-01

    The issues that should be addressed when developing resource recovery and recycling programs and initiatives were highlighted. When well thought out, these initiatives result in substantial increases in the recovery of products and materials at their end-of-life cycle. The issues discussed included design for the environment, consumption patterns, sustainable markets for recovered products, infrastructure, policy mechanisms, and technology. Each issue was examined from a life cycle approach. The author outlined several benefits associated with a resource recovery and recycling program including materials and energy efficiencies, reduced burdens to landfill, reduced greenhouse gas emissions, and social implications. The author also presented some examples of Canadian initiatives in the resource recovery and recycling sector. 15 refs., 1 tab., 4 figs.

  12. ENHANCED OIL RECOVERY USING LOCAL ALKALINE

    African Journals Online (AJOL)

    user

    trapped in the reservoir even after primary and secondary recovery process have been completed, ... concerns that most of the newly discovered hydrocarbon .... free sandstone cores. ..... Porous Media: A Review”, SPE 8799, presented at.

  13. Recovery After Stroke: Bladder and Bowel Function

    Science.gov (United States)

    ... easier for you to use the toilet.  Social workers can help with financial issues. They can with ... your doctor, “Where am I on my stroke recovery journey?” Note: This fact sheet is compiled from ...

  14. Modeling premature brain injury and recovery

    Science.gov (United States)

    Scafidi, Joey; Fagel, Devon M.; Ment, Laura R.; Vaccarino, Flora M.

    2009-01-01

    Premature birth is a growing and significant public health problem because of the large number of infants that survive with neurodevelopmental sequelae from brain injury. Recent advances in neuroimaging have shown that although some neuroanatomical structures are altered, others improve over time. This review outlines recent insights into brain structure and function in these preterm infants at school age and relevant animal models. These animal models have provided scientists with an opportunity to explore in depth the molecular and cellular mechanisms of injury as well as the potential of the brain for recovery. The endogenous potential that the brain has for neurogenesis and gliogenesis, and how environment contributes to recovery, are also outlined. These preclinical models will provide important insights into the genetic and epigenetic mechanisms responsible for variable degrees of injury and recovery, permitting the exploration of targeted therapies to facilitate recovery in the developing preterm brain. PMID:19482072

  15. Recovery Act. Tapoco project. Cheoah upgrade

    Energy Technology Data Exchange (ETDEWEB)

    Tran, Paul [Alcoa Inc., Alcoa Center, PA (United States)

    2013-10-02

    Under Funding Opportunity Announcement Number: DE-FOA-0000120, Recovery Act: Hydroelectric Facility Modernization, Alcoa Power Generating Inc. (APGI), a fully owned subsidiary of Alcoa Inc., implemented major upgrades at its Cheoah hydroelectric facility near Robbinsville, North Carolina.

  16. Ballistic Rail Gun Soft Recovery Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Ballistic Rail Gun Soft Recovery Facility accommodates a 155mm Howitzer, fired horizontally into a 104-foot long water trough to slow the projectile and recover...

  17. Delmarva Peninsula Fox Squirrel Recovery Plan 1983

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The primary objective of the Recovery Plan is to restore the Delmarva fox squirrel to secure status throughout its former range. The plan includes the following...

  18. Further development of recovery boiler; Soodakattilan kehitystyoe

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Siiskonen, P.; Sundstroem, K. [Tampella Power Oy, Tampere (Finland)] [and others

    1996-12-01

    The global model of a recovery boiler was further developed. The aim is to be able to model the velocity, temperature and concentration fields in a boiler. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. The preliminary study of NO{sub x} and fly ash behaviour in a boiler was carried out. The study concerning flow field in the superheater area was carried out a 2-dimensional case in which the inflow parameters were taken from global model of a recovery boiler. Further the prediction methods of fouling in a recovery boiler were developed based on theoretical calculations of smelting behaviour of multicomponent mixtures and measurements at operating recovery boilers. (author)

  19. Social Stressors at Work, Sleep, and Recovery.

    Science.gov (United States)

    Pereira, Diana; Gross, Sven; Elfering, Achim

    2016-03-01

    Many employees in service work are required to work on Saturdays, recovering during work-free Sundays and working again Mondays. We examined the effects of social stressors at work on recovery status at Sunday noon and Monday noon, and investigated if sleep quality mediates the negative effects of social stressors at work on recovery. From Saturday until Monday morning, 41 participants wore actigraphs to measure sleep duration and sleep fragmentation. Social stressors at work were assessed by self-reported questionnaires administered on Saturday. Recovery status was reported Sunday noon and Monday noon. Hierarchical regression analysis revealed that social stressors at work were negatively related to recovery status on Sunday and on Monday. Supporting our assumptions, more social stressors at work predicted higher sleep fragmentation in the night to Monday. A mediation effect of sleep quality, however, was not found. Theoretical and practical implications of these results are discussed.

  20. Recovery of Gait After Stroke: What Changes?

    NARCIS (Netherlands)

    Buurke, Jaap H.; Nene, Anand V.; Kwakkel, Gert; Erren-Wolters, Victorien; IJzerman, Maarten J.; Hermens, Hermie J.

    2008-01-01

    Background. Little is known about whether changes in coordination patterns of muscle activation after stroke are related to functional recovery of walking. Objective . The present study investigated the longitudinal relationship between changes in neuromuscular activation patterns of paretic muscles