WorldWideScience

Sample records for chemical processes operating

  1. Modeling operators' emergency response time for chemical processing operations.

    Science.gov (United States)

    Murray, Susan L; Harputlu, Emrah; Mentzer, Ray A; Mannan, M Sam

    2014-01-01

    Operators have a crucial role during emergencies at a variety of facilities such as chemical processing plants. When an abnormality occurs in the production process, the operator often has limited time to either take corrective actions or evacuate before the situation becomes deadly. It is crucial that system designers and safety professionals can estimate the time required for a response before procedures and facilities are designed and operations are initiated. There are existing industrial engineering techniques to establish time standards for tasks performed at a normal working pace. However, it is reasonable to expect the time required to take action in emergency situations will be different than working at a normal production pace. It is possible that in an emergency, operators will act faster compared to a normal pace. It would be useful for system designers to be able to establish a time range for operators' response times for emergency situations. This article develops a modeling approach to estimate the time standard range for operators taking corrective actions or following evacuation procedures in emergency situations. This will aid engineers and managers in establishing time requirements for operators in emergency situations. The methodology used for this study combines a well-established industrial engineering technique for determining time requirements (predetermined time standard system) and adjustment coefficients for emergency situations developed by the authors. Numerous videos of workers performing well-established tasks at a maximum pace were studied. As an example, one of the tasks analyzed was pit crew workers changing tires as quickly as they could during a race. The operations in these videos were decomposed into basic, fundamental motions (such as walking, reaching for a tool, and bending over) by studying the videos frame by frame. A comparison analysis was then performed between the emergency pace and the normal working pace operations

  2. MIMO Self-Tuning Control of Chemical Process Operation

    DEFF Research Database (Denmark)

    Hallager, L.; Jørgensen, S. B.; Goldschmidt, L.

    1984-01-01

    The problem of selecting a feasible model structure for a MIMO self-tuning controller (MIMOSC) is addressed. The dependency of the necessary structure complexity in relation to the specific process operating point is investigated. Experimental results from a fixed-bed chemical reactor are used...

  3. Emissions model of waste treatment operations at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Schindler, R.E.

    1995-03-01

    An integrated model of the waste treatment systems at the Idaho Chemical Processing Plant (ICPP) was developed using a commercially-available process simulation software (ASPEN Plus) to calculate atmospheric emissions of hazardous chemicals for use in an application for an environmental permit to operate (PTO). The processes covered by the model are the Process Equipment Waste evaporator, High Level Liquid Waste evaporator, New Waste Calcining Facility and Liquid Effluent Treatment and Disposal facility. The processes are described along with the model and its assumptions. The model calculates emissions of NO x , CO, volatile acids, hazardous metals, and organic chemicals. Some calculated relative emissions are summarized and insights on building simulations are discussed

  4. NUMATH: a nuclear-material-holdup estimator for unit operations and chemical processes

    International Nuclear Information System (INIS)

    Krichinsky, A.M.

    1981-01-01

    A computer program, NUMATH (Nuclear Material Holdup Estimator), has been developed to permit inventory estimation in vessels involved in unit operations and chemical processes. This program has been implemented in an operating nuclear fuel processing plant. NUMATH's purpose is to provide steady-state composition estimates for material residing in process vessels until representative samples can be obtained and chemical analyses can be performed. Since these compositions are used for inventory estimation, the results are determined for and cataloged in container-oriented files. The estimated compositions represent material collected in applicable vessels-including consideration for material previously acknowledged in these vessels. The program utilizes process measurements and simple material balance models to estimate material holdups and distribution within unit operations. During simulated run testing, NUMATH-estimated inventories typically produced material balances within 7% of the associated measured material balances for uranium and within 16% of the associated, measured material balance for thorium during steady-state process operation

  5. Model Reduction in Chemical Engineering : Case studies applied to process analysis, design and operation

    NARCIS (Netherlands)

    Dorneanu, B.

    2011-01-01

    During the last decades, models have become widely used for supporting a broad range of chemical engineering activities, such as product and process design and development, process monitoring and control, real time optimization of plant operation or supply chain management. Although tremendous

  6. Incorporation of environmental impact criteria in the design and operation of chemical processes

    Directory of Open Access Journals (Sweden)

    P.E. Bauer

    2004-09-01

    Full Text Available Environmental impact assessment is becoming indispensable for the design and operation of chemical plants. Structured and consistent methods for this purpose have experienced a rapid development. The more rigorous and sophisticated these methods become, the greater is the demand for convenient tools. On the other hand, despite the incredible advances in process simulators, some aspects have still not been sufficiently covered. To date, applications of these programs to quantify environmental impacts have been restricted to straightforward examples of steady-state processes. In this work, a life-cycle assessment implementation with the aim of process design will be described, with a brief discussion of a dynamic simulation for analysis of transient state operations, such as process start-up. A case study shows the importance of this analysis in making possible operation at a high performance level with reduced risks to the environment.

  7. PREMATH: a Precious-Material Holdup Estimator for unit operations and chemical processes

    International Nuclear Information System (INIS)

    Krichinsky, A.M.; Bruns, D.D.

    1982-01-01

    A computer program, PREMATH (Precious Material Holdup Estimator), has been developed to permit inventory estimation in vessels involved in unit operations and chemical processes. This program has been implemented in an operating nuclear fuel processing plant. PREMATH's purpose is to provide steady-state composition estimates for material residing in process vessels until representative samples can be obtained and chemical analyses can be performed. Since these compositions are used for inventory estimation, the results are determined for and cataloged in container-oriented files. The estimated compositions represent material collected in applicable vessels - including consideration for material previously acknowledged in these vessels. The program utilizes process measurements and simple material balance models to estimate material holdups and distribution within unit operations. During simulated run testing, PREMATH-estimated inventories typically produced material balances within 7% of the associated measured material balances for uranium and within 16% of the associated, measured material balances for thorium (a less valuable material than uranium) during steady-state process operation

  8. Advances of radioisotope for design, intensification and optimization of processes and operations in chemical industry

    International Nuclear Information System (INIS)

    Joshi, J.B.

    2002-01-01

    Full text: In chemical industries different processes and operations involve a variety of multiphase contacting schemes for optimal production schedule in terms of ease of handling, time and money. A number of parameters will have to be optimized for this purpose. Further more, during the operation of a process plant, a number of problems such as reduction in process efficiency, deterioration in product quality etc. are encountered due to malfunctioning of one or more components. The successful operation of an industry depends on the early detection of the problems for appropriate remedial action. These are conveniently carried out by the application of radioisotopes either directly or in sealed condition depending upon the problem to be addressed. In this talk both types of radiotracer applications are discussed by taking specific examples

  9. NUMATH: a nuclear material holdup estimator for unit operations and chemical processes

    International Nuclear Information System (INIS)

    Krichinsky, A.M.

    1982-01-01

    NUMATH provides inventory estimation by utilizing previous inventory measurements, operating data, and, where available, on-line process measurements. For the present time, NUMATH's purpose is to provide a reasonable, near-real-time estimate of material inventory until accurate inventory determination can be obtained from chemical analysis. Ultimately, it is intended that NUMATH will further utilize on-line analyzers and more advanced calculational techniques to provide more accurate inventory determinations and estimates

  10. Idaho Chemical Processing Plant (ICPP) injection well: Operations history and hydrochemical inventory of the waste stream

    International Nuclear Information System (INIS)

    Fromm, J.; McCurry, M.; Hackett, W.; Welhan, J.

    1994-01-01

    Department of Energy (DOE), United States Geological Survey (USGS), and Idaho Chemical Processing Plant (ICPP) documents were searched for information regarding service disposal operations, and the chemical characteristics and volumes of the service waste emplaced in, and above, the Eastern Snake River Plain aquifer (ESRP) from 1953-1992. A summary database has been developed which synthesizes available, but dispersed, information. This assembled data records spatial, volumetric and chemical input patterns which will help establish the initial contaminant water characteristics required in computer modeling, aid in interpreting the monitoring well network hydrochemical information, and contribute to a better understanding of contaminant transport in the aquifer near the ICPP. Gaps and uncertainties in the input record are also identified with respect to time and type. 39 refs., 5 figs., 5 tabs

  11. Static analysis of the thermochemical hydrogen production IS process for assessment of the operation parameters and the chemical properties

    International Nuclear Information System (INIS)

    Kasahara, Seiji; Onuki, Kaoru; Nomura, Mikihiro; Nakao, Shin-ichi

    2006-01-01

    A sensitivity analysis of the operation parameters and the chemical properties in the thermochemical hydrogen production IS process (iodine-sulfur process) was carried out for a static flow sheet. These parameters were evaluated by hydrogen production thermal efficiency, the mass flow rate or heat exchange based on the heat/mass balance. The most important parameters were the concentration of HI after electro-electrodialysis (EED) and the apparent transport number of protons of the cation exchange membrane in the EED cell. HI concentration operation should be operated carefully because the parameters for optimum thermal efficiency and for the optimum flow rate and heat exchange were different. For the chemical properties, composition at the inlet of the HI decomposition procedure and HI x pseudo-azeotropic composition had great effects. The HI concentration after the EED should be optimized for each composition. The order of priority for the assessment of the operation parameters and chemical properties was determined by the evaluation. (author)

  12. Chemical mode control in nuclear power plant decommissioning during operation of technologies in individual radioactive waste processing plants

    International Nuclear Information System (INIS)

    Horvath, J.; Dugovic, L.

    1999-01-01

    Sewage treatment of nuclear power plant decommissioning is performed by system of sewage concentration in evaporator with formation of condensed rest, it means radioactive waste concentrate and breeding steam. During sewage treatment plant operation department of chemical mode performs chemical and radiochemical analysis of sewage set for treatment, chemical and radiochemical analysis of breeding steam condensate which is after final cleaning on ionization filter and fulfilling the limiting conditions released to environment; chemical and radiochemical analysis of heating steam condensate which is also after fulfilling the limiting conditions released to environment. Condensed radioactive concentrate is stored in stainless tanks and later converted into easy transportable and chemically stable matrix from the long term storage point of view in republic storage Mochovce. The article also refer to bituminous plant, vitrification plant, swimming pool decontamination plant of long term storage and operation of waste processing plant Bohunice

  13. Zinc injection implementation process at EDF: risk analysis, chemical specifications and operating procedures

    International Nuclear Information System (INIS)

    Tigeras, A.; Stutzmann, A.; Bremnes, O.; Claeys, M.; Ranchoux, G.; Segura, J.C.; Errera, J.; Bonne, S.

    2010-01-01

    Zinc's ability to replace cobalt from oxides of primary circuit surfaces has provided the first motivation for implementing the zinc addition in BWRs since the mid-1980s. The beneficial results regarding dose reductions have been demonstrated; therefore, this practice has been extended to PWRs since the 1990s, not only for radiation fields considerations, but also for reducing PWSCC. From the beginning of the 2000s, further reasons to inject zinc associated with the fuel management process have been identified (e; g; power increase, high burn-up, and/or cycle length increase). These evolutions must be accompanied by an adapted chemistry program in order to mitigate the crud deposition on fuel assemblies and the consequent AOA/CIPS or localized clad corrosion risks. The source term reduction (due to the decrease of the general corrosion rate of several materials) and the absence of negative impact on alloy cladding in the presence of zinc in the primary coolant are the main reasons for selecting zinc injection as a reliable option for preventing and/or mitigating the effects of fuel deposits. These three PWR motivations (field radiation, components performance, and fuel reliability) are also the major objectives of CANDU®, WWER, and new reactors (EPR, AP1000), where the zinc injection feasibility analyses are in progress in order to improve the safety of their operating conditions. With the purpose of achieving the optimal results of zinc injection, the process's implantation in a unit must be conducted with an appropriate risk analysis, covering all possible domains affected by this primary coolant chemistry modification : safety, fuel and component performance, radioprotection, waste, environment, human and installation security, human and material resources, staff formation, and documentation. EDF has performed a complete analysis of this enlarged scope, relying upon theoretical and experimental results as well as NPP feedback. This paper describes EDF

  14. The development and application of dynamic operational risk assessment in oil/gas and chemical process industry

    International Nuclear Information System (INIS)

    Yang Xiaole; Mannan, M. Sam

    2010-01-01

    A methodology of dynamic operational risk assessment (DORA) is proposed for operational risk analysis in oil/gas and chemical industries. The methodology is introduced comprehensively starting from the conceptual framework design to mathematical modeling and to decision making based on cost-benefit analysis. The probabilistic modeling part of DORA integrates stochastic modeling and process dynamics modeling to evaluate operational risk. The stochastic system-state trajectory is modeled according to the abnormal behavior or failure of each component. For each of the possible system-state trajectories, a process dynamics evaluation is carried out to check whether process variables, e.g., level, flow rate, temperature, pressure, or chemical concentration, remain in their desirable regions. Component testing/inspection intervals and repair times are critical parameters to define the system-state configuration, and play an important role for evaluating the probability of operational failure. This methodology not only provides a framework to evaluate the dynamic operational risk in oil/gas and chemical industries, but also guides the process design and further optimization. To illustrate the probabilistic study, we present a case-study of a level control in an oil/gas separator at an offshore plant.

  15. Chemical Processing Department monthly report, October 1963

    Energy Technology Data Exchange (ETDEWEB)

    Young, J. F.; Johnson, W. E.; Reinker, P. H.; Warren, J. H.; McCullugh, R. W.; Harmon, M. K.; Gartin, W. J.; LaFollette, T. G.; Shaw, H. P.; Frank, W. S.; Grim, K. G.; Warren, J. H.

    1963-11-21

    This report, for October 1963 from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; employee relations; weapons manufacturing operation; and safety and security.

  16. SIMULATION OF ECOLOGICALLY CONSCIOUS CHEMICAL PROCESSES: FUGITIVE EMISSIONS VERSUS OPERATING CONDITIONS

    Science.gov (United States)

    Catalytic reforming is an important refinery process for the conversion of low-octane naphtha (mostly paraffins) into high-octane motor fuels (isoparaffins, naphthenes and aromatics), light gases and hydrogen. In this study the catalytic reforming process is analyzed under differ...

  17. Chemical Processing Department monthly report, June 1958

    Energy Technology Data Exchange (ETDEWEB)

    1958-07-22

    This report for June 1958, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

  18. Chemical Processing Division monthly report, November 1966

    Energy Technology Data Exchange (ETDEWEB)

    Reed, P.E.

    1966-12-21

    This report, from the Chemical Processing Department at HAPO for November 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee-relations, and waste management.

  19. Chemical Processing Department monthly report, March 1961

    Energy Technology Data Exchange (ETDEWEB)

    1961-04-21

    This report for March 1961, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

  20. Chemical Processing Division monthly report, January 1966

    Energy Technology Data Exchange (ETDEWEB)

    Reed, P.E.

    1966-02-21

    This report, from the Chemical Processing Department at HAPO for January 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

  1. Chemical radwaste solidification processes

    International Nuclear Information System (INIS)

    Malloy, C.W.

    1979-01-01

    Some of these processes and their problems are briefly reviewed: early cement systems; urea-formaldehyde; Dow solidification process; low-viscosity chemical agents (POLYPAC); and water-extensible polyester. 9 refs

  2. Chemical process hazards analysis

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  3. A Guide for Developing Standard Operating Job Procedures for the Tertiary Chemical Treatment - Lime Precipitation Process Wastewater Treatment Facility. SOJP No. 6.

    Science.gov (United States)

    Petrasek, Al, Jr.

    This guide describes the standard operating job procedures for the tertiary chemical treatment - lime precipitation process of wastewater treatment plants. Step-by-step instructions are given for pre-start up, start-up, continuous operation, and shut-down procedures. In addition, some theoretical material is presented along with some relevant…

  4. Chemical Processing Department monthly report, May 1957

    Energy Technology Data Exchange (ETDEWEB)

    1957-06-21

    The May, 1957 monthly report for the Chemical Processing Department of the Hanford Atomic Products Operation includes information regarding research and engineering efforts with respect to the Purex and Redox process technology. Also discussed is the production operation, finished product operation, power and general maintenance, financial operation, engineering and research operations, and employee operation.(MB)

  5. Chemical Processing Department monthly report, September 1957

    Energy Technology Data Exchange (ETDEWEB)

    1957-10-22

    The September, 1957 monthly report for the Chemical Processing Department of the Hanford Atomic Products Operation includes information regarding research and engineering efforts with respect to the Purex and Redox process technology. Also discussed is the production operation, finished product operation, power and general maintenance, financial operation, engineering and research operations, and employee operation.

  6. Ultrasound in chemical processes

    International Nuclear Information System (INIS)

    Baig, S.; Farooq, R.; Malik, A.H.

    2009-01-01

    The use of ultrasound to promote chemical reactions or sono chemistry is a field of chemistry which involves the process of acoustic cavitations i.e. the collapse of microscopic bubbles in liquid. There are two essential components for the application of sono chemistry, a liquid medium and a source of high-energy vibrations. The liquid medium is necessary because sono chemistry is driven by acoustic cavitations that can only occur in liquids. The source of the vibrational energy is the transducer. The chemical effects of ultrasound include the enhancement of reaction rates at ambient temperatures and striking advancements in stoichiometric and catalytic reactions In some cases, ultrasonic irradiation can increase reactivities by nearly million fold. The ultrasound has large number of applications not only in emending old chemical processes but also in developing new synthetic strategies. Ultrasound enhances all chemical and physical processes e.g., crystallization, vitamin synthesis, preparation of catalysts, dissolution of chemicals, organometallic reactions, electrochemical processes, etc. High-power ultrasonics is a new powerful technology that is not only safe and environmentally friendly in its application but is also efficient and economical. It can be applied to existing processes to eliminate the need for chemicals and/or heat application in a variety of industrial processes. (author)

  7. Chemical Processing Department monthly report for February 1957

    Energy Technology Data Exchange (ETDEWEB)

    1957-03-21

    This report from the Chemical Processing Department at HAPO, discusses the following: Production operation, purex operation, redox operation, finished products operation, power and general maintenance operation, financial operation, facilities engineering operation, research and engineering operation, and employee relations operation.

  8. Lasers in chemical processing

    International Nuclear Information System (INIS)

    Davis, J.I.

    1982-01-01

    The high cost of laser energy is the crucial issue in any potential laser-processing application. It is expensive relative to other forms of energy and to most bulk chemicals. We show those factors that have previously frustrated attempts to find commercially viable laser-induced processes for the production of materials. Having identified the general criteria to be satisfied by an economically successful laser process and shown how these imply the laser-system requirements, we present a status report on the uranium laser isotope separation (LIS) program at the Lawrence Livermore National Laboratory

  9. Neutron interrogator assay system for the Idaho Chemical Processing Plant waste canisters and spent fuel: preliminary description and operating procedures manual

    International Nuclear Information System (INIS)

    Menlove, H.O.; Eccleston, G.; Close, D.A.; Speir, L.G.

    1978-05-01

    A neutron interrogation assay system is being designed for the measurement of waste canisters and spent fuel packages at the new Idaho Chemical Processing Plant to be operated by Allied Chemical Corp. The assay samples consist of both waste canisters from the fluorinel dissolution process and spent fuel assemblies. The assay system is a 252 Cf ''Shuffler'' that employs a cyclic sequence of fast-neutron interrogation with a 252 Cf source followed by delayed-neutron counting to determine the 235 U content

  10. Chemical Processing Department monthly report for September 1963

    Energy Technology Data Exchange (ETDEWEB)

    1963-10-21

    This report, from the Chemical Processing Department at HAPO for September 1963, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations, facilities engineering; research; employee relations; weapons manufacturing operation; and power and crafts operation.

  11. Operator programs and operator processes

    NARCIS (Netherlands)

    Bergstra, J.A.; Walters, P.

    2003-01-01

    We define a notion of program which is not a computer program but an operator program: a detailed description of actions performed and decisions taken by a human operator (computer user) performing a task to achieve a goal in a simple setting consisting of that user, one or more computers and a

  12. Monitoring of operating processes

    International Nuclear Information System (INIS)

    Barry, R.F.

    1981-01-01

    Apparatus is described for monitoring the processes of a nuclear reactor to detect off-normal operation of any process and for testing the monitoring apparatus. The processes are evaluated by response to their paramters, such as temperature, pressure, etc. The apparatus includes a pair of monitoring paths or signal processing units. Each unit includes facilities for receiving on a time-sharing basis, a status binary word made up of digits each indicating the status of a process, whether normal or off-normal, and test-signal binary words simulating the status binary words. The status words and test words are processed in succession during successive cycles. During each cycle, the two units receive the same status word and the same test word. The test words simulate the status words both when they indicate normal operation and when they indicate off-normal operation. Each signal-processing unit includes a pair of memories. Each memory receives a status word or a test word, as the case may be, and converts the received word into a converted status word or a converted test word. The memories of each monitoring unit operate into a non-coincidence which signals non-coincidence of the converted word out of one memory of a signal-processing unit not identical to the converted word of the other memory of the same unit

  13. Production of gaseous and liquid chemicals by aqueous phase reforming of crude glycerol: Influence of operating conditions on the process

    International Nuclear Information System (INIS)

    Remón, J.; Giménez, J.R.; Valiente, A.; García, L.; Arauzo, J.

    2016-01-01

    Highlights: • Aqueous phase reforming: a tailor-made process for the valorisation of crude glycerol. • In-depth understanding of the effect of the operating conditions on the process. • Process optimisation for the selective production of valuable gas and liquid products. • Low pressure and high temperature and spatial time favour gas production. • High pressure and medium temperature maximise the production of valuable liquids. - Abstract: The present work studies the influence of the temperature (200–240 °C), pressure (38–50 bar), glycerol concentration (10–50 wt.%) and mass of catalyst/ glycerol mass flow rate ratio (W/m_g_l_y_c_e_r_o_l = 10–40 g catalyst min/g glycerol) during the aqueous phase reforming (APR) of a glycerol solution obtained from the production of biodiesel. The operating conditions exerted a statistically significant influence on the reforming results. Specifically, the global glycerol conversion and the carbon converted into gas and liquid products varied as follows: 4–100%, 1–80% and 16–93%, respectively. The gas phase was made up of H_2 (8–55 vol.%), CO_2 (34–66 vol.%), CO (0–4 vol.%) and CH_4 (6–45 vol.%). The liquid phase consisted of a mixture of alcohols (monohydric: methanol and ethanol; and polyhydric: 1,2-propanediol, 1,2-ethanediol, 2,3-butanediol), aldehydes (acetaldehyde), ketones (C3-ketones: acetone and 2-propanone-1-hydroxy; C4-ketones: 2-butanone-3-hydroxy and 2-butanone-1-hydroxy; and cyclic ketones), carboxylic acids (acetic and propionic acids) and esters (1,2,3-propanetriol-monoacetate), together with unreacted glycerol and water. The relative amount (free of water and un-reacted glycerol) of these compounds in the liquid phase was as follows: monohydric alcohols: 4–47%, polyhydric-alcohols: 14–68%, aldehydes: 0–5%, C3-ketones: 2–33%, C4-ketones: 0–10%, ciclo-ketones: 0–6%, carboxylic acids: 2–43%, and esters: 0–46%. This process turned out to be highly customisable for the

  14. Idaho Chemical Processing Plant Process Efficiency improvements

    International Nuclear Information System (INIS)

    Griebenow, B.

    1996-03-01

    In response to decreasing funding levels available to support activities at the Idaho Chemical Processing Plant (ICPP) and a desire to be cost competitive, the Department of Energy Idaho Operations Office (DOE-ID) and Lockheed Idaho Technologies Company have increased their emphasis on cost-saving measures. The ICPP Effectiveness Improvement Initiative involves many activities to improve cost effectiveness and competitiveness. This report documents the methodology and results of one of those cost cutting measures, the Process Efficiency Improvement Activity. The Process Efficiency Improvement Activity performed a systematic review of major work processes at the ICPP to increase productivity and to identify nonvalue-added requirements. A two-phase approach was selected for the activity to allow for near-term implementation of relatively easy process modifications in the first phase while obtaining long-term continuous improvement in the second phase and beyond. Phase I of the initiative included a concentrated review of processes that had a high potential for cost savings with the intent of realizing savings in Fiscal Year 1996 (FY-96.) Phase II consists of implementing long-term strategies too complex for Phase I implementation and evaluation of processes not targeted for Phase I review. The Phase II effort is targeted for realizing cost savings in FY-97 and beyond

  15. Conceptualizing operations strategy processes

    DEFF Research Database (Denmark)

    Rytter, Niels Gorm; Boer, Harry; Koch, Christian

    2007-01-01

    Purpose - The purpose of this paper is to present insights into operations strategy (OS) in practice. It outlines a conceptualization and model of OS processes and, based on findings from an in-depth and longitudinal case study, contributes to further development of extant OS models and methods......; taking place in five dimensions of change - technical-rational, cultural, political, project management, and facilitation; and typically unfolding as a sequential and parallel, ordered and disordered, planned and emergent as well as top-down and bottom-up process. The proposed OS conceptualization...

  16. Microfluidics for chemical processing

    NARCIS (Netherlands)

    Gardeniers, Johannes G.E.

    2006-01-01

    Microfluidic systems, and more specifically, microfluidic chips, have a number of features that make them particularly useful for the study of chemical reactions on-line. The present paper will discuss two examples, the study of fluidic behaviour at high pressures and the excitation and detection of

  17. Modular Chemical Process Intensification: A Review.

    Science.gov (United States)

    Kim, Yong-Ha; Park, Lydia K; Yiacoumi, Sotira; Tsouris, Costas

    2017-06-07

    Modular chemical process intensification can dramatically improve energy and process efficiencies of chemical processes through enhanced mass and heat transfer, application of external force fields, enhanced driving forces, and combinations of different unit operations, such as reaction and separation, in single-process equipment. These dramatic improvements lead to several benefits such as compactness or small footprint, energy and cost savings, enhanced safety, less waste production, and higher product quality. Because of these benefits, process intensification can play a major role in industrial and manufacturing sectors, including chemical, pulp and paper, energy, critical materials, and water treatment, among others. This article provides an overview of process intensification, including definitions, principles, tools, and possible applications, with the objective to contribute to the future development and potential applications of modular chemical process intensification in industrial and manufacturing sectors. Drivers and barriers contributing to the advancement of process intensification technologies are discussed.

  18. Chemical Processing Department monthly report for July 1957

    Energy Technology Data Exchange (ETDEWEB)

    McCune, F. K.; Johnson, W. E.; MacCready, W. K.; Warren, J. H.; Schroeder, O. C.; Groswith, C. T.; Mobley, W. N.; LaFollette, T. G.; Grim, K. G.; Shaw, H. P.; Richards, R. B.; Roberts, D. S.

    1957-08-22

    This report, for July 1957 from the Chemical Processing Department at HAPO, discusses the following; Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

  19. Chemical Processing Department monthly report for December 1958

    Energy Technology Data Exchange (ETDEWEB)

    1959-01-21

    This report for December 1958, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

  20. Chemical Processing Department monthly report for February 1959

    Energy Technology Data Exchange (ETDEWEB)

    1959-03-20

    This report for February 1959, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

  1. 8. The operational processes.

    Science.gov (United States)

    2014-05-01

    There are two principal directions that disaster studies pursue: (1) interventional; and (2) noninterventional. Interventional studies are used to evaluate specific responses as to their effectiveness in meeting their respective objectives, their contribution to the overarching goal, the efficiency with which they are able to achieve their objectives, other effects created, and their respective costs. On the other hand, noninterventional studies examine the epidemiology of disasters and for the most part are observational. Both interventional and noninterventional studies require data/information obtained from assessments. This section of these Guidelines examines the operational framework used to study interventions/responses and includes the following processes: (1) assessments, (2) identification of needs; (3) strategic planning; (4) selection of intervention(s); (5) operational planning; (6) execution of interventions; and (7) monitoring and evaluation of effects and changes in levels of functions resulting from the intervention(s) being studied.

  2. Louisiana SIP: LAC 33:III Ch 21 Subchap J, 2147--Limiting Volatile Organic Compound (VOC) Emissions from Reactor Processes and Distillation Operations in Synthetic Organic Chemical manufacturing Industry (SOCMI); SIP effective 1998-02-02 (LAc74) to more..

    Science.gov (United States)

    Louisiana SIP: LAC 33:III Ch 21 Subchap J, 2147--Limiting Volatile Organic Compound (VOC) Emissions from Reactor Processes and Distillation Operations in Synthetic Organic Chemical manufacturing Industry (SOCMI); SIP effective 1998-02-02 (LAc74) more...

  3. Louisiana SIP: LAC 33:III Ch 2147. Limiting Volatile Organic Compound (VOC) Emissions from Reactor Processes and Distillation Operations in Synthetic Organic Chemical manufacturing Industry (SOCMI); SIP effective 2011-08-04 (LAd34) to 2017-09-27

    Science.gov (United States)

    Louisiana SIP: LAC 33:III Ch 2147. Limiting Volatile Organic Compound (VOC) Emissions from Reactor Processes and Distillation Operations in Synthetic Organic Chemical manufacturing Industry (SOCMI); SIP effective 2011-08-04 (LAd34) to 2017-09-27

  4. Process Security in Chemical Engineering Education

    Science.gov (United States)

    Piluso, Cristina; Uygun, Korkut; Huang, Yinlun; Lou, Helen H.

    2005-01-01

    The threats of terrorism have greatly alerted the chemical process industries to assure plant security at all levels: infrastructure-improvement-focused physical security, information-protection-focused cyber security, and design-and-operation-improvement-focused process security. While developing effective plant security methods and technologies…

  5. Chemical kinetics and oil shale process design

    Energy Technology Data Exchange (ETDEWEB)

    Burnham, A.K.

    1993-07-01

    Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

  6. Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed chemical processing systems at Building 9212, Y-12 Plant, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1995-09-01

    The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is located within the Y-12 Plant on DOE's Oak Ridge Reservation in Oak Ridge, Tennessee. The proposed replacement system would be based upon modern design criteria and safety analyses. The replacement AHF supply and distribution system equipment would be located on the existing Dock 8/8A at Building 9212. Utilities would be extended to the dock to service the process equipment. The following process equipment modules would be prefabricated for installation at the modified dock: an AHF cylinder enclosure, an AHF supply manifold and vaporizer module, an AHF sump tank and transfer skid, and an AHF supply off-gas scrubber assembly module. The fluidized-bed reactor system would be constructed in an area adjacent to the existing system in Building 9212. The replacement equipment would consist of a new reduction fluidized-bed reactor, a hydrofluorination fluidized-bed reactor, and associated air emission control equipment. The no-action alternative, which is the continued operation of the existing AHF supply and fluidized-bed reactor systems, was also evaluated

  7. Historical events of the Chemical Processing Department

    Energy Technology Data Exchange (ETDEWEB)

    Lane, W.A.

    1965-11-12

    The purpose of this report is to summarize and document the significant historical events pertinent to the operation of the Chemical Processing facilities at Hanford. The report covers, in chronological order, the major construction activities and historical events from 1944 to September, 1965. Also included are the production records achieved and a history of the department`s unit cost performance.

  8. Reactive chemicals and process hazards

    International Nuclear Information System (INIS)

    Surianarayanan, M.

    2016-01-01

    Exothermic chemical reactions are often accompanied by significant heat release, and therefore, need a thorough investigation before they are taken to a plant scale. Sudden thermal energy releases from exothermic decompositions and runaway reactions have contributed to serious fire and explosions in several chemical process plants. Similarly, thermal runaway had also occurred in storage and transportation of reactive chemicals. The secondary events of thermal runaway reactions can be rupture of process vessel, toxic spills and release of explosive vapor clouds or combination of these also. The explosion hazards are governed by the system thermodynamics and kinetics of the thermal process. Theoretical prediction of limiting temperature is difficult due to process complexities. Further, the kinetic data obtained through classical techniques, at conditions far away from runaway situation, is often not valid for assessing the runaway behavior of exothermic processes. The main focus of this lecture is to discuss the causes and several contributing factors for thermal runaway and instability and present analyses of the methodologies of the new instrumental techniques for assessing the thermal hazards of reactive chemicals during processing, storage and transportation. (author)

  9. The Operations Process

    Science.gov (United States)

    2010-03-26

    important events receive the most attention. Ensures that absentees and flank units receive changes to the operation order. Transmits changes to them...York: Vintage Books, 1991. Fuller, J. F. C. Generalship: Its Diseases and Their Cure . Harrisburg, PA: Military Service Publishing Co., 1936

  10. Operant Variability: Procedures and Processes

    Science.gov (United States)

    Machado, Armando; Tonneau, Francois

    2012-01-01

    Barba's (2012) article deftly weaves three main themes in one argument about operant variability. From general theoretical considerations on operant behavior (Catania, 1973), Barba derives methodological guidelines about response differentiation and applies them to the study of operant variability. In the process, he uncovers unnoticed features of…

  11. Applications of Process Synthesis: Moving from Conventional Chemical Processes towards Biorefinery Processes

    DEFF Research Database (Denmark)

    Yuan, Zhihong; Chen, Bingzhen; Gani, Rafiqul

    2013-01-01

    Concerns about diminishing petroleum reserves, enhanced worldwide demand for fuels and fluctuations in the global oil market, together with climate change and national security have promoted many initiatives for exploring alternative, non-petroleum based processes. Among these initiatives......, biorefinery processes for converting biomass-derived carbohydrates into transportation fuels and chemicals are now gaining more and more attention from both academia and industry. Process synthesis, which has played a vital role for the development, design and operation of (petro) chemical processes, can...

  12. MRI of chemical reactions and processes.

    Science.gov (United States)

    Britton, Melanie M

    2017-08-01

    As magnetic resonance imaging (MRI) can spatially resolve a wealth of molecular information available from nuclear magnetic resonance (NMR), it is able to non-invasively visualise the composition, properties and reactions of a broad range of spatially-heterogeneous molecular systems. Hence, MRI is increasingly finding applications in the study of chemical reactions and processes in a diverse range of environments and technologies. This article will explain the basic principles of MRI and how it can be used to visualise chemical composition and molecular properties, providing an overview of the variety of information available. Examples are drawn from the disciplines of chemistry, chemical engineering, environmental science, physics, electrochemistry and materials science. The review introduces a range of techniques used to produce image contrast, along with the chemical and molecular insight accessible through them. Methods for mapping the distribution of chemical species, using chemical shift imaging or spatially-resolved spectroscopy, are reviewed, as well as methods for visualising physical state, temperature, current density, flow velocities and molecular diffusion. Strategies for imaging materials with low signal intensity, such as those containing gases or low sensitivity nuclei, using compressed sensing, para-hydrogen or polarisation transfer, are discussed. Systems are presented which encapsulate the diversity of chemical and physical parameters observable by MRI, including one- and two-phase flow in porous media, chemical pattern formation, phase transformations and hydrodynamic (fingering) instabilities. Lastly, the emerging area of electrochemical MRI is discussed, with studies presented on the visualisation of electrochemical deposition and dissolution processes during corrosion and the operation of batteries, supercapacitors and fuel cells. Crown Copyright © 2017. Published by Elsevier B.V. All rights reserved.

  13. Stochastic processes in chemical physics

    CERN Document Server

    Shuler, K E

    2009-01-01

    The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

  14. Energy conversion technology by chemical processes

    Energy Technology Data Exchange (ETDEWEB)

    Oh, I W; Yoon, K S; Cho, B W [Korea Inst. of Science and Technology, Seoul (Korea, Republic of); and others

    1996-12-01

    The sharp increase in energy usage according to the industry development has resulted in deficiency of energy resources and severe pollution problems. Therefore, development of the effective way of energy usage and energy resources of low pollution is needed. Development of the energy conversion technology by chemical processes is also indispensable, which will replace the pollutant-producing and inefficient mechanical energy conversion technologies. Energy conversion technology by chemical processes directly converts chemical energy to electrical one, or converts heat energy to chemical one followed by heat storage. The technology includes batteries, fuel cells, and energy storage system. The are still many problems on performance, safety, and manufacturing of the secondary battery which is highly demanded in electronics, communication, and computer industries. To overcome these problems, key components such as carbon electrode, metal oxide electrode, and solid polymer electrolyte are developed in this study, followed by the fabrication of the lithium secondary battery. Polymer electrolyte fuel cell, as an advanced power generating apparatus with high efficiency, no pollution, and no noise, has many applications such as zero-emission vehicles, on-site power plants, and military purposes. After fabricating the cell components and operating the single cells, the fundamental technologies in polymer electrolyte fuel cell are established in this study. Energy storage technology provides the safe and regular heat energy, irrespective of the change of the heat energy sources, adjusts time gap between consumption and supply, and upgrades and concentrates low grade heat energy. In this study, useful chemical reactions for efficient storage and transport are investigated and the chemical heat storage technology are developed. (author) 41 refs., 90 figs., 20 tabs.

  15. Optimal operation of batch membrane processes

    CERN Document Server

    Paulen, Radoslav

    2016-01-01

    This study concentrates on a general optimization of a particular class of membrane separation processes: those involving batch diafiltration. Existing practices are explained and operational improvements based on optimal control theory are suggested. The first part of the book introduces the theory of membrane processes, optimal control and dynamic optimization. Separation problems are defined and mathematical models of batch membrane processes derived. The control theory focuses on problems of dynamic optimization from a chemical-engineering point of view. Analytical and numerical methods that can be exploited to treat problems of optimal control for membrane processes are described. The second part of the text builds on this theoretical basis to establish solutions for membrane models of increasing complexity. Each chapter starts with a derivation of optimal operation and continues with case studies exemplifying various aspects of the control problems under consideration. The authors work their way from th...

  16. Chemical reagent and process for refuse disposal

    International Nuclear Information System (INIS)

    Somerville, R.B.; Fan, L.T.

    1989-01-01

    A process for treating refuse by mixing them with a reactive chemical and a puzzolana-type material. Said chemical includes a retarding agent which modifies the viscosity and an accelerating agent. (author)

  17. Conceptual Chemical Process Design for Sustainability.

    Science.gov (United States)

    This chapter examines the sustainable design of chemical processes, with a focus on conceptual design, hierarchical and short-cut methods, and analyses of process sustainability for alternatives. The chapter describes a methodology for incorporating process sustainability analyse...

  18. Chemical process safety at fuel cycle facilities

    International Nuclear Information System (INIS)

    Ayres, D.A.

    1997-08-01

    This NUREG provides broad guidance on chemical safety issues relevant to fuel cycle facilities. It describes an approach acceptable to the NRC staff, with examples that are not exhaustive, for addressing chemical process safety in the safe storage, handling, and processing of licensed nuclear material. It expounds to license holders and applicants a general philosophy of the role of chemical process safety with respect to NRC-licensed materials; sets forth the basic information needed to properly evaluate chemical process safety; and describes plausible methods of identifying and evaluating chemical hazards and assessing the adequacy of the chemical safety of the proposed equipment and facilities. Examples of equipment and methods commonly used to prevent and/or mitigate the consequences of chemical incidents are discussed in this document

  19. CATALYSIS OF CHEMICAL PROCESSES: PARTICULAR ...

    African Journals Online (AJOL)

    IICBA01

    secondary/high schools and universities, the inhibition of the chemical reactions is frequently ... As a result, the lesson catalysis is frequently included in chemistry education curricula at ... Misinterpretations in teaching and perception of catalysis ... profile is shown as a dependence of energy on reaction progress, without ...

  20. Systemic Operational Design: Enhancing the Joint Operation Planning Process

    National Research Council Canada - National Science Library

    Delacruz, Victor J

    2007-01-01

    Operational level commanders and their staffs require relevant and current joint doctrine that articulates the critical function of operational design and its role in the Joint Operation Planning Process (JOPP...

  1. Chemical process control using Mat lab

    International Nuclear Information System (INIS)

    Kang, Sin Chun; Kim, Raeh Yeon; Kim, Yang Su; Oh, Min; Yeo, Yeong Gu; Jung, Yeon Su

    2001-07-01

    This book is about chemical process control, which includes the basis of process control with conception, function, composition of system and summary, change of laplace and linearization, modeling of chemical process, transfer function and block diagram, the first dynamic property of process, the second dynamic property of process, the dynamic property of combined process, control structure of feedback on component of control system, the dynamic property of feedback control loop, stability of closed loop control structure, expression of process, modification and composition of controller, analysis of vibration response and adjustment controller using vibration response.

  2. Plasma-chemical processes and systems

    International Nuclear Information System (INIS)

    Castro B, J.

    1987-01-01

    The direct applications of plasma technology on chemistry and metallurgy are presented. The physical fundaments of chemically active non-equilibrium plasma, the reaction kinetics, and the physical chemical transformations occuring in the electrical discharges, which are applied in the industry, are analysed. Some plasma chemical systems and processes related to the energy of hydrogen, with the chemical technology and with the metallurgy are described. Emphasis is given to the optimization of the energy effectiveness of these processes to obtain reducers and artificial energetic carriers. (M.C.K.) [pt

  3. Operation of chemical incinerator for disposal of legacy chemicals

    International Nuclear Information System (INIS)

    Singhal, R.K.; Basu, H.; Saha, S.; Pimple, M.V.; Naik, P.D.

    2017-01-01

    For safe disposal of age-old legacy and unused chemicals in BARC, Trombay, oil-fired chemical incinerator with a capacity of 20 kg h"-"1 for solid and liquid chemical is installed adjacent to trash incinerator near RSMS, Gamma Field. The Incinerator was supplied by M/s B. L. Engineering Works, Ahmedabad. Commission of the same at Trombay site was carried out, under the supervision of Civil Engineering (CED), Technical Services Division (TSD) and Analytical Chemistry Division (custodian of the facility)

  4. General areas needing chemical competence to support reactor operation

    International Nuclear Information System (INIS)

    Proksch, E.; Bildstein, H.

    1963-01-01

    Chemical competence is needed not only for the development of new types of reactors but also for the start-up and safe operation of reactors. The activities of chemistry and chemical engineering cover a number of fields, namely chemical analysis, radiochemical analysis, corrosion research, radiolysis of water and water purification. The author reviews fields in reactor operation and maintenance in which chemical competence is needed. (author). 9 refs

  5. Method for innovative synthesis-design of chemical process flowsheets

    DEFF Research Database (Denmark)

    Kumar Tula, Anjan; Gani, Rafiqul

    Chemical process synthesis-design involve the identification of the processing route to reach a desired product from a specified set of raw materials, design of the operations involved in the processing route, the calculations of utility requirements, the calculations of waste and emission...... to the surrounding and many more. Different methods (knowledge-based [1], mathematical programming [2], hybrid, etc.) have been proposed and are also currently employed to solve these synthesis-design problems. D’ Anterroches [3] proposed a group contribution based approach to solve the synthesis-design problem...... of chemical processes, where, chemical process flowsheets could be synthesized in the same way as atoms or groups of atoms are synthesized to form molecules in computer aided molecular design (CAMD) techniques [4]. That, from a library of building blocks (functional process-groups) and a set of rules to join...

  6. Chemical process engineering in the transuranium processing plant

    International Nuclear Information System (INIS)

    Collins, E.D.; Bigelow, J.E.

    1976-01-01

    Since operation of the Transuranium Processing Plant began, process changes have been made to counteract problems caused by equipment corrosion, to satisfy new processing requirements, and to utilize improved processes. The new processes, equipment, and techniques have been incorporated into a sequence of steps which satisfies all required processing functions

  7. Process safety management for highly hazardous chemicals

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

  8. Chemicals Industry New Process Chemistry Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2000-08-01

    The Materials Technology I workshop was held in November 1998 to address future research needs for materials technology that will support the chemical industry. Areas covered included disassembly, recovery, reuse and renewable technology; new materials; and materials measurement and characterization. The Materials Technology II workshop was held in September 1999 and covered additives, modeling and prediction and an additional segment on new materials. Materials Technology Institute (MTI) for the Chemical Process Industries, Inc. and Air Products & Chemicals lead the workshops. The Materials Technology Roadmap presents the results from both workshops.

  9. Remotely operated replaceable process equipment

    International Nuclear Information System (INIS)

    Westendorf, H.

    1987-01-01

    The coupling process of pneumatic and electrical auxiliary lines of a pneumatic control pressure line in a large cell of the reprocessing plant is carried out, together with the coupling process of the connecting flange of the process equipment. The coupling places of the auxiliary lines, such as control or supply lines, are laid in the flange parts of the flanges to be connected. The pipe flange on the frame side remains flush with the connecting flange of the process equipment. (DG) [de

  10. Secondary cleanup of Idaho Chemical Processing Plant solvent

    International Nuclear Information System (INIS)

    Mailen, J.C.

    1985-01-01

    Solvent from the Idaho Chemical Processing Plant (ICPP) (operated by Westinghouse Idaho Nuclear Company, Inc.) has been tested to determine the ability of activated alumina to remove secondary degradation products - those degradation products which are not removed by scrubbing with sodium carbonate

  11. Fluidized-bed reactors processes and operating conditions

    CERN Document Server

    Yates, John G

    2016-01-01

    The fluidized-bed reactor is the centerpiece of industrial fluidization processes. This book focuses on the design and operation of fluidized beds in many different industrial processes, emphasizing the rationale for choosing fluidized beds for each particular process. The book starts with a brief history of fluidization from its inception in the 1940’s. The authors present both the fluid dynamics of gas-solid fluidized beds and the extensive experimental studies of operating systems and they set them in the context of operating processes that use fluid-bed reactors. Chemical engineering students and postdocs as well as practicing engineers will find great interest in this book.

  12. Vibration and Stability of 3000-hp, Titanium Chemical Process Blower

    Directory of Open Access Journals (Sweden)

    Les Gutzwiller

    2003-01-01

    Full Text Available This 74-in-diameter blower had an overhung rotor design of titanium construction, operating at 50 pounds per square inch gauge in a critical chemical plant process. The shaft was supported by oil-film bearings and was directdriven by a 3000-hp electric motor through a metal disk type of coupling. The operating speed was 1780 rpm. The blower shaft and motor shaft motion was monitored by Bently Nevada proximity probes and a Model 3100 monitoring system.

  13. ALMA Array Operations Group process overview

    Science.gov (United States)

    Barrios, Emilio; Alarcon, Hector

    2016-07-01

    ALMA Science operations activities in Chile are responsibility of the Department of Science Operations, which consists of three groups, the Array Operations Group (AOG), the Program Management Group (PMG) and the Data Management Group (DMG). The AOG includes the Array Operators and have the mission to provide support for science observations, operating safely and efficiently the array. The poster describes the AOG process, management and operational tools.

  14. Modelling of Batch Process Operations

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Cameron, Ian; Gani, Rafiqul

    2011-01-01

    Here a batch cooling crystalliser is modelled and simulated as is a batch distillation system. In the batch crystalliser four operational modes of the crystalliser are considered, namely: initial cooling, nucleation, crystal growth and product removal. A model generation procedure is shown that s...

  15. Environmentally benign chemical synthesis and processing

    International Nuclear Information System (INIS)

    Hancock, K.G.

    1992-01-01

    A new era of university-industry-government partnership is required to address the intertwined problems of industrial economic competitiveness and environmental quality. Chemicals that go up the stacks and down the drains are simultaneously a serious detriment to the environment, a waste of natural resources, and a threat to industrial profitability. Recently, the NSF Divisions of Chemistry and chemical and Thermal Systems have joined with the Council for Chemical research in a new grant program to reduce pollution at the source by underwriting research aimed at environmentally benign chemical synthesis and processing. Part of a broader NSF initiative on environmental science research, this new program serves as a model for university-industry-government joint action and technology transfer. Other features of this program and related activities will be described in this paper

  16. Life cycle sustainability assessment of chemical processes

    DEFF Research Database (Denmark)

    Xu, Di; Lv, Liping; Ren, Jingzheng

    2017-01-01

    In this study, an integrated vector-based three-dimensional (3D) methodology for the life cycle sustainability assessment (LCSA) of chemical process alternatives is proposed. In the methodology, a 3D criteria assessment system is first established by using the life cycle assessment, the life cycl...

  17. Safety Considerations in the Chemical Process Industries

    Science.gov (United States)

    Englund, Stanley M.

    There is an increased emphasis on chemical process safety as a result of highly publicized accidents. Public awareness of these accidents has provided a driving force for industry to improve its safety record. There has been an increasing amount of government regulation.

  18. Chemical aspects of nuclear fuel fabrication processes

    Energy Technology Data Exchange (ETDEWEB)

    Naylor, A; Ellis, J F; Watson, R H

    1986-04-01

    Processes used by British Nuclear Fuels plc for the conversion of uranium ore concentrates to uranium metal and uranium hexafluoride, are reviewed. Means of converting the latter compound, after enrichment, to sintered UO/sub 2/ fuel bodies are also described. An overview is given of the associated chemical engineering technology.

  19. Desulphurization of exhaust gases in chemical processes

    Energy Technology Data Exchange (ETDEWEB)

    Asperger, K.; Wischnewski, W.

    1981-01-01

    The sulfur content of exhaust gases can be reduced by: desulphurization of fuels; modification of processes; or treatment of resultant gases. In this paper a few selected examples from the chemical industry in the German Democratic Republic are presented. Using modified processes and treating the resultant gases, the sulphuric content of exhaust gases is effectively reduced. Methods to reduce the sulfur content of exhaust gases are described in the field of production of: sulphuric acid; viscose; fertilizers; and paraffin.

  20. Engineering Process Monitoring for Control Room Operation

    OpenAIRE

    Bätz, M

    2001-01-01

    A major challenge in process operation is to reduce costs and increase system efficiency whereas the complexity of automated process engineering, control and monitoring systems increases continuously. To cope with this challenge the design, implementation and operation of process monitoring systems for control room operation have to be treated as an ensemble. This is only possible if the engineering of the monitoring information is focused on the production objective and is lead in close coll...

  1. Process/Equipment Co-Simulation on Syngas Chemical Looping Process

    Energy Technology Data Exchange (ETDEWEB)

    Zeng, Liang; Zhou, Qiang; Fan, Liang-Shih

    2012-09-30

    The chemical looping strategy for fossil energy applications promises to achieve an efficient energy conversion system for electricity, liquid fuels, hydrogen and/or chemicals generation, while economically separate CO{sub 2} by looping reaction design in the process. Chemical looping particle performance, looping reactor engineering, and process design and applications are the key drivers to the success of chemical looping process development. In order to better understand and further scale up the chemical looping process, issues such as cost, time, measurement, safety, and other uncertainties need to be examined. To address these uncertainties, advanced reaction/reactor modeling and process simulation are highly desired and the modeling efforts can accelerate the chemical looping technology development, reduce the pilot-scale facility design time and operating campaigns, as well as reduce the cost and technical risks. The purpose of this work is thus to conduct multiscale modeling and simulations on the key aspects of chemical looping technology, including particle reaction kinetics, reactor design and operation, and process synthesis and optimization.

  2. New Vistas in Chemical Product and Process Design

    DEFF Research Database (Denmark)

    Zhang, Lei; Babi, Deenesh Kavi; Gani, Rafiqul

    2016-01-01

    Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product......, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design....... Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack...

  3. Beyond Safe Operating Space: Finding Chemical Footprinting Feasible

    DEFF Research Database (Denmark)

    Posthuma, Leo; Bjørn, Anders; Zijp, Michiel C.

    2014-01-01

    undefined boundary in their selection of planetary boundaries delineating the “safe operating space for humanity”. Can we use the well-known concept of “ecological footprints” to express a chemical pollution boundary aimed at preventing the overshoot of the Earth’s capacity to assimilate environmental...... scenarios that allow us to avoid “chemical overshoot” beyond the Earth’s safe operating space....

  4. Atlantic Richfield Hanford Company chemical operator training program

    International Nuclear Information System (INIS)

    Zumhoff, R.G.

    1975-01-01

    Formal training and testing of Chemical Operators at Hanford were initiated as part of a negotiated union settlement in 1966. Consequently, it was agreed that 25 percent of the chemical operator force would receive a higher rated job (Lead Nuclear Chemical Operator) provided they satisfactorily completed a training program including testing. The training and testing program was developed in two parts. The first covered subjects of a general nature and was applicable to an operator's duties no matter what the assignment. Part II was more specifically oriented to the presently assigned work area. Renewed interest in retraining and requalification of all chemical operators was taken in 1971. This evolved from a Company concern that a program be developed to assure the fact that operators were qualified to do their assigned jobs, and an Atomic Energy Commission request for an outline of a retraining and requalification program for chemical operators. Building upon the experience gained in the LNCO (Lead Nuclear Chemical Operator) program, the two part format is retained. The use of video tapes is used to complement the manuals. An arrangement where an operator can view a lecture-type presentation is provided in seven plant locations. A small studio for in-house production of the video tapes is available to the training Specialists. A script is developed from a training manual by condensing the information into 20-minute presentations. A prime objective of each tape is to highlight the safety and control aspects that accompany operator responsibilities in each of these areas. Testing is also handled on a two part basis; one test covers the fundamentals and a separate test is designed for each of the plant subjects. A walk-through examination is also performed for the plant portion. Operators are required to be requalified on emergency procedures on an annual basis and at two-year intervals in the other areas. (U.S.)

  5. Rock fracture processes in chemically reactive environments

    Science.gov (United States)

    Eichhubl, P.

    2015-12-01

    Rock fracture is traditionally viewed as a brittle process involving damage nucleation and growth in a zone ahead of a larger fracture, resulting in fracture propagation once a threshold loading stress is exceeded. It is now increasingly recognized that coupled chemical-mechanical processes influence fracture growth in wide range of subsurface conditions that include igneous, metamorphic, and geothermal systems, and diagenetically reactive sedimentary systems with possible applications to hydrocarbon extraction and CO2 sequestration. Fracture processes aided or driven by chemical change can affect the onset of fracture, fracture shape and branching characteristics, and fracture network geometry, thus influencing mechanical strength and flow properties of rock systems. We are investigating two fundamental modes of chemical-mechanical interactions associated with fracture growth: 1. Fracture propagation may be aided by chemical dissolution or hydration reactions at the fracture tip allowing fracture propagation under subcritical stress loading conditions. We are evaluating effects of environmental conditions on critical (fracture toughness KIc) and subcritical (subcritical index) fracture properties using double torsion fracture mechanics tests on shale and sandstone. Depending on rock composition, the presence of reactive aqueous fluids can increase or decrease KIc and/or subcritical index. 2. Fracture may be concurrent with distributed dissolution-precipitation reactions in the hostrock beyond the immediate vicinity of the fracture tip. Reconstructing the fracture opening history recorded in crack-seal fracture cement of deeply buried sandstone we find that fracture length growth and fracture opening can be decoupled, with a phase of initial length growth followed by a phase of dominant fracture opening. This suggests that mechanical crack-tip failure processes, possibly aided by chemical crack-tip weakening, and distributed solution-precipitation creep in the

  6. Intelligent Controller Design for a Chemical Process

    OpenAIRE

    Mr. Glan Devadhas G; Dr.Pushpakumar S.

    2010-01-01

    Chemical process control is a challenging problem due to the strong on*line non*linearity and extreme sensitivity to disturbances of the process. Ziegler – Nichols tuned PI and PID controllers are found to provide poor performances for higher*order and non–linear systems. This paper presents an application of one*step*ahead fuzzy as well as ANFIS (adaptive*network*based fuzzy inference system) tuning scheme for an Continuous Stirred Tank Reactor CSTR process. The controller is designed based ...

  7. Performing process migration with allreduce operations

    Science.gov (United States)

    Archer, Charles Jens; Peters, Amanda; Wallenfelt, Brian Paul

    2010-12-14

    Compute nodes perform allreduce operations that swap processes at nodes. A first allreduce operation generates a first result and uses a first process from a first compute node, a second process from a second compute node, and zeros from other compute nodes. The first compute node replaces the first process with the first result. A second allreduce operation generates a second result and uses the first result from the first compute node, the second process from the second compute node, and zeros from others. The second compute node replaces the second process with the second result, which is the first process. A third allreduce operation generates a third result and uses the first result from first compute node, the second result from the second compute node, and zeros from others. The first compute node replaces the first result with the third result, which is the second process.

  8. Chemical precipitation processes for the treatment of aqueous radioactive waste

    International Nuclear Information System (INIS)

    1992-01-01

    Chemical precipitation by coagulation-flocculation and sedimentation has been commonly used for many years to treat liquid (aqueous) radioactive waste. This method allows the volume of waste to be substantially reduced for further treatment or conditioning and the bulk of the waste to de discharged. Chemical precipitation is usually applied in combination with other methods as part of a comprehensive waste management scheme. As with any other technology, chemical precipitation is constantly being improved to reduce cost to increase the effectiveness and safety on the entire waste management system. The purpose of this report is to review and update the information provided in Technical Reports Series No. 89, Chemical Treatment of Radioactive Wastes, published in 1968. In this report the chemical methods currently in use for the treatment of low and intermediate level aqueous radioactive wastes are described and illustrated. Comparisons are given of the advantages and limitations of the processes, and it is noted that good decontamination and volume reduction are not the only criteria according to which a particular process should be selected. Emphasis has been placed on the need to carefully characterize each waste stream, to examine fully the effect of segregation and the importance of looking at the entire operation and not just the treatment process when planning a liquid waste treatment facility. This general approach includes local requirements and possibilities, discharge authorization, management of the concentrates, ICRP recommendations and economics. It appears that chemical precipitation process and solid-liquid separation techniques will continue to be widely used in liquid radioactive waste treatment. Current research and development is showing that combining different processes in one treatment plant can provide higher decontamination factors and smaller secondary waste arisings. Some of these processes are already being incorporated into new and

  9. Melter operation results in chemical test at Rokkasho Reprocessing Plant

    International Nuclear Information System (INIS)

    Kanehira, Norio; Yoshioka, Masahiro; Muramoto, Hitoshi; Oba, Takaaki; Takahashi, Yuji

    2005-01-01

    Chemical Test of the glass melter system of the Vitrification Facility at Rokkasho Reprocessing Plant (RRP) was performed. In this test, basic performance of heating-up of the melter, melting glass, pouring glass was confirmed using simulated materials. Through these tests and operation of all modes, good results were gained, and training of operators was completed. (author)

  10. Outline of the Chemical Processing Facility (CPF)

    International Nuclear Information System (INIS)

    Arita, Katsuhiko

    1978-01-01

    Concerning the Chemical Processing Facility (CPF), a high level radioactive material research facility, to be installed in Tokai Works of Power Reactor and Nuclear Fuel Development Corporation (PNC), the detailed design and the governmental safety inspection were finished. The construction has been already started, and it will be completed in 1980. Under the national policy of establishing a nuclear fuel cycle, PNC is now carrying out the development of its downstream technology. The objects of the Chemical Processing Facility are the researches of the treatment techniques of high level radioactive liquid wastes from fuel reprocessing and of the reprocessing of fast reactor fuel. The following matters are described: purpose of the CPF, i.e. fast reactor fuel reprocessing and high-level liquid waste treatment; construction of the CPF, i.e. buildings, cells and an exhaust stack; test systems, i.e. fuel reprocessing and liquid waste vitrification; and facility safety. (Mori, K.)

  11. Energetic Analysis of Poultry Processing Operations

    OpenAIRE

    Simeon Olatayo JEKAYINFA

    2007-01-01

    Energy audit of three poultry processing plants was conducted in southwestern Nigeria. The plants were grouped into three different categories based on their production capacities. The survey involved all the five easily defined unit operations utilized by the poultry processing industry and the experimental design allowed the energy consumed in each unit operation to be measured. The results of the audit revealed that scalding & defeathering is the most energy intensive unit operation in al...

  12. On knowledge structures for process operators

    International Nuclear Information System (INIS)

    Wirstad, J.

    1981-05-01

    A conceptual framework for operator competency and job training planning and design being developed and used for operators in Swedish nuclear power stations is presented briefly. This conceptual framework represents a training technological approach. It uses terms which are system oriented and familiar to people working in the plant. Another conceptual framework is focusing on the information processing of the operator and its relation to physical, functional and abstract representations of the plant and the process. This conceptual framework has been developed by Risoe in Denmark especially for man process-interaction analysis and design. There are interesting relations between the two structures, e.g. human information processing in plant operation is largely a function of operator learning of the work, the processes and the plants units, its subsystems and components. The two framework are analysed and relations between them are indicated. (author)

  13. Determinants of Operational Efficiency at Chemical Cargo Terminals

    Directory of Open Access Journals (Sweden)

    T.A. Gúlcan

    2014-06-01

    Full Text Available In today’s globalized world, one of the requirements of global supply chains is efficient transportation systems. Approximately 80 per cent of world merchandise trade carried by sea and handled by ports worldwide. For this reason, maritime transport has the strategic economic importance. Loading of oil and gas has the biggest share (%30 in commodities carried by sea and 2.9 billion tons oil and gas loaded to ship in 2013. This study is focus on chemical cargo terminals which is a special terminal form where high and international levels of safety and quality elements applied. Unlike conventional bulk cargo and container cargo operations, chemical cargo operations include own priorities, applications, and the evaluation criteria. The aim of this study is to perform a qualitative research to determine the factors affecting the operational efficiency of ship, berth and warehousing operations in chemical cargo terminals.

  14. A Study on Safety and Risk Assessment of Dangerous Cargo Operations in Oil/Chemical Tankers

    OpenAIRE

    Cenk ŞAKAR; Yusuf ZORBA

    2017-01-01

    The safety and risk assessment of dangerous cargo operations in oil and chemical tankers is a necessary process to prevent possible accidents during these operations. Fire and explosion are the major accidents encountered in tanker operations. In this study, a model was constructed through the Fuzzy Bayes Network Method for the probabilistic relationships between the causes of fire and explosion accidents that could occur during the tank cleaning process. The study is composed of two stages. ...

  15. Reflow process stabilization by chemical characteristics and process conditions

    Science.gov (United States)

    Kim, Myoung-Soo; Park, Jeong-Hyun; Kim, Hak-Joon; Kim, Il-Hyung; Jeon, Jae-Ha; Gil, Myung-Goon; Kim, Bong-Ho

    2002-07-01

    With the shrunken device rule below 130nm, the patterning of smaller contact hole with enough process margin is required for mass production. Therefore, shrinking technology using thermal reflow process has been applied for smaller contact hole formation. In this paper, we have investigated the effects of chemical characteristics such as molecular weight, blocking ratio of resin, cross-linker amount and solvent type with its composition to reflow process of resist and found the optimized chemical composition for reflow process applicable condition. And several process conditions like resist coating thickness and multi-step thermal reflow method have been also evaluated to stabilize the pattern profile and improve CD uniformity after reflow process. From the experiment results, it was confirmed that the effect of crosslinker in resist to reflow properties such as reflow temperature and reflow rate were very critical and it controlled the pattern profile during reflow processing. And also, it showed stable CD uniformity and improved resist properties for top loss, film shrinkage and etch selectivity. The application of lower coating thickness of resist induced symmetric pattern profile even at edge with wider process margin. The introduction of two-step baking method for reflow process showed uniform CD value, also. It is believed that the application of resist containing crosslinker and optimized process conditions for smaller contact hole patterning is necessary for the mass production with a design rule below 130nm.

  16. Incorporation of chemical kinetic models into process control

    International Nuclear Information System (INIS)

    Herget, C.J.; Frazer, J.W.

    1981-01-01

    An important consideration in chemical process control is to determine the precise rationing of reactant streams, particularly when a large time delay exists between the mixing of the reactants and the measurement of the product. In this paper, a method is described for incorporating chemical kinetic models into the control strategy in order to achieve optimum operating conditions. The system is first characterized by determining a reaction rate surface as a function of all input reactant concentrations over a feasible range. A nonlinear constrained optimization program is then used to determine the combination of reactants which produces the specified yield at minimum cost. This operating condition is then used to establish the nominal concentrations of the reactants. The actual operation is determined through a feedback control system employing a Smith predictor. The method is demonstrated on a laboratory bench scale enzyme reactor

  17. Defense waste processing facility radioactive operations. Part 1 - operating experience

    International Nuclear Information System (INIS)

    Little, D.B.; Gee, J.T.; Barnes, W.M.

    1997-01-01

    The Savannah River Site's Defense Waste Processing Facility (DWPF) near Aiken, SC is the nation's first and the world's largest vitrification facility. Following a ten year construction program and a 3 year non-radioactive test program, DWPF began radioactive operations in March 1996. This paper presents the results of the first 9 months of radioactive operations. Topics include: operations of the remote processing equipment reliability, and decontamination facilities for the remote processing equipment. Key equipment discussed includes process pumps, telerobotic manipulators, infrared camera, Holledge trademark level gauges and in-cell (remote) cranes. Information is presented regarding equipment at the conclusion of the DWPF test program it also discussed, with special emphasis on agitator blades and cooling/heating coil wear. 3 refs., 4 figs

  18. Defense Waste Processing Facility -- Radioactive operations -- Part 3 -- Remote operations

    International Nuclear Information System (INIS)

    Barnes, W.M.; Kerley, W.D.; Hughes, P.D.

    1997-01-01

    The Savannah River Site's Defense Waste Processing Facility (DWPF) near Aiken, South Carolina is the nation's first and world's largest vitrification facility. Following a ten year construction period and nearly three years of non-radioactive testing, the DWPF began radioactive operations in March 1996. Radioactive glass is poured from the joule heated melter into the stainless steel canisters. The canisters are then temporarily sealed, decontaminated, resistance welded for final closure, and transported to an interim storage facility. All of these operations are conducted remotely with equipment specially designed for these processes. This paper reviews canister processing during the first nine months of radioactive operations at DWPF. The fundamental design consideration for DWPF remote canister processing and handling equipment are discussed as well as interim canister storage

  19. A ''master key'' to chemical separation processes

    International Nuclear Information System (INIS)

    Madic, Ch.; Hill, C.

    2002-01-01

    One of the keys to sorting nuclear waste is extracting minor actinides - the most troublesome long-lived elements - from the flow of waste by separating them from lanthanides, which have very similar chemical properties to actinides, for possible transmutation into shorter-lived elements. Thanks to a European initiative coordinated by CEA, this key is now available: its name is Sanex. There now remains to develop tough, straightforward industrial processes to integrate it into a new nuclear waste management approach by 2005. Sanex joins the Diamex process, used for the combined separation of lanthanides and minor actinides from fission products. A third process, Sesame, designed to separate americium, completes the list of available separation processes. (authors)

  20. Models and Modelling Tools for Chemical Product and Process Design

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    2016-01-01

    The design, development and reliability of a chemical product and the process to manufacture it, need to be consistent with the end-use characteristics of the desired product. One of the common ways to match the desired product-process characteristics is through trial and error based experiments......-based framework is that in the design, development and/or manufacturing of a chemical product-process, the knowledge of the applied phenomena together with the product-process design details can be provided with diverse degrees of abstractions and details. This would allow the experimental resources...... to be employed for validation and fine-tuning of the solutions from the model-based framework, thereby, removing the need for trial and error experimental steps. Also, questions related to economic feasibility, operability and sustainability, among others, can be considered in the early stages of design. However...

  1. Chemical and physicochemical characteristics changes during passion fruit juice processing

    Directory of Open Access Journals (Sweden)

    Aline Gurgel Fernandes

    2011-09-01

    Full Text Available Passion fruit is widely consumed due to its pleasant flavour and aroma acidity, and it is considered very important a source of minerals and vitamins. It is used in many products such as ice-cream, mousses and, especially, juices. However, the processing of passion fruit juice may modify the composition and biodisponibility of the bioactive compounds. Investigations of the effects of processing on nutritional components in tropical juices are scarce. Frequently, only losses of vitamin C are evaluated. The objective of this paper is to investigate how some operations of passion fruit juice processing (formulation/homogeneization/thermal treatment affect this product's chemical and physicochemical characteristics. The results showed that the chemical and physicochemical characteristics are little affected by the processing although a reduction in vitamin C contents and anthocyanin, large quantities of carotenoids was verified even after the pasteurization stage.

  2. Chemical processes in neutron capture therapy

    International Nuclear Information System (INIS)

    Brown, B.J.

    1975-01-01

    Research into the radiation chemical effects of neutron capture therapy are described. In the use of neutron capture therapy for the treatment of brain tumours, compounds containing an activatable nuclide are selectively concentrated within tumour tissue and irradiated with neutrons. Target compounds for use in therapy must accumulate selectively in high concentrations in the tumour and must be non toxic to the patient. The most suitable of these are the boron hydrides. Radiation dosages, resulting from neutron capture in normal tissue constituents are tabulated. As part of the program to study the radiation-induced chemical processes undergone by boron target compounds, the radiolytic degredation of boron hydride and phenyl boric acid system was investigated. No direct dependence between the yield of the transient radiolytic species and the concentration of the B-compound was observed. (author)

  3. Waste processing of chemical cleaning solutions

    International Nuclear Information System (INIS)

    Peters, G.A.

    1991-01-01

    This paper reports on chemical cleaning solutions containing high concentrations of organic chelating wastes that are difficult to reduce in volume using existing technology. Current methods for evaporating low-level radiative waste solutions often use high maintenance evaporators that can be costly and inefficient. The heat transfer surfaces of these evaporators are easily fouled, and their maintenance requires a significant labor investment. To address the volume reduction of spent, low-level radioactive, chelating-based chemical cleaning solutions, ECOSAFE Liquid Volume Reduction System (LVRS) has been developed. The LVRS is based on submerged combustion evaporator technology that was modified for treatment of low-level radiative liquid wastes. This system was developed in 1988 and was used to process 180,000 gallons of waste at Oconee Nuclear Station

  4. Process plant equipment operation, control, and reliability

    CERN Document Server

    Holloway, Michael D; Onyewuenyi, Oliver A

    2012-01-01

    "Process Plant Equipment Book is another great publication from Wiley as a reference book for final year students as well as those who will work or are working in chemical production plants and refinery…" -Associate Prof. Dr. Ramli Mat, Deputy Dean (Academic), Faculty of Chemical Engineering, Universiti Teknologi Malaysia "…give[s] readers access to both fundamental information on process plant equipment and to practical ideas, best practices and experiences of highly successful engineers from around the world… The book is illustrated throughout with numerous black & white p

  5. Occurrence reporting and processing of operations information

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-21

    DOE O 232.1A, Occurrence Reporting and Processing of Operations Information, and 10 CFR 830.350, Occurrence Reporting and Processing of Operations Information (when it becomes effective), along with this manual, set forth occurrence reporting requirements for Department of Energy (DOE) Departmental Elements and contractors responsible for the management and operation of DOE-owned and -leased facilities. These requirements include categorization of occurrences related to safety, security, environment, health, or operations (``Reportable Occurrences``); DOE notification of these occurrences; and the development and submission of documented follow-up reports. This Manual provides detailed information for categorizing and reporting occurrences at DOE facilities. Information gathered by the Occurrence Reporting and processing System is used for analysis of the Department`s performance in environmental protection, safeguards and security, and safety and health of its workers and the public. This information is also used to develop lessons learned and document events that significantly impact DOE operations.

  6. Occurrence reporting and processing of operations information

    International Nuclear Information System (INIS)

    1997-01-01

    DOE O 232.1A, Occurrence Reporting and Processing of Operations Information, and 10 CFR 830.350, Occurrence Reporting and Processing of Operations Information (when it becomes effective), along with this manual, set forth occurrence reporting requirements for Department of Energy (DOE) Departmental Elements and contractors responsible for the management and operation of DOE-owned and -leased facilities. These requirements include categorization of occurrences related to safety, security, environment, health, or operations (''Reportable Occurrences''); DOE notification of these occurrences; and the development and submission of documented follow-up reports. This Manual provides detailed information for categorizing and reporting occurrences at DOE facilities. Information gathered by the Occurrence Reporting and processing System is used for analysis of the Department's performance in environmental protection, safeguards and security, and safety and health of its workers and the public. This information is also used to develop lessons learned and document events that significantly impact DOE operations

  7. Engineering Process Monitoring for Control Room Operation

    CERN Document Server

    Bätz, M

    2001-01-01

    A major challenge in process operation is to reduce costs and increase system efficiency whereas the complexity of automated process engineering, control and monitoring systems increases continuously. To cope with this challenge the design, implementation and operation of process monitoring systems for control room operation have to be treated as an ensemble. This is only possible if the engineering of the monitoring information is focused on the production objective and is lead in close collaboration of control room teams, exploitation personnel and process specialists. In this paper some principles for the engineering of monitoring information for control room operation are developed at the example of the exploitation of a particle accelerator at the European Laboratory for Nuclear Research (CERN).

  8. Guidelines for safe process operations and maintenance

    CERN Document Server

    2010-01-01

    First-line managers have to maintain the integrity of facilities, control manufacturing processes, and handle unusual or emergency situations, as well as respond to the pressures of production demand. On a daily basis, they are closest to the operating personnel who may be injured by a process accident, and they are in the best position to spot problem conditions and to act to contain them. This book offers these managers ""how-to"" information on process safety management program execution in the operations and maintenance departments, recommending technical and administrative process safety

  9. Idaho Chemical Processing Plant Site Development Plan

    International Nuclear Information System (INIS)

    Ferguson, F.G.

    1994-02-01

    The Idaho Chemical Processing Plant (ICPP) mission is to receive and store spent nuclear fuels and radioactive wastes for disposition for Department of Energy (DOE) in a cost-effective manner that protects the safety of Idaho National Engineering Laboratory (INEL) employees, the public, and the environment by: Developing advanced technologies to process spent nuclear fuel for permanent offsite disposition and to achieve waste minimization. Receiving and storing Navy and other DOE assigned spent nuclear fuels. Managing all wastes in compliance with applicable laws and regulations. Identifying and conducting site remediation consistent with facility transition activities. Seeking out and implementing private sector technology transfer and cooperative development agreements. Prior to April 1992, the ICPP mission included fuel reprocessing. With the recent phaseout of fuel reprocessing, some parts of the ICPP mission have changed. Others have remained the same or increased in scope

  10. Integrated Process Design, Control and Analysis of Intensified Chemical Processes

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil

    chemical processes; for example, intensified processes such as reactive distillation. Most importantly, it identifies and eliminates potentially promising design alternatives that may have controllability problems later. To date, a number of methodologies have been proposed and applied on various problems......, that the same principles that apply to a binary non-reactive compound system are valid also for a binary-element or a multi-element system. Therefore, it is advantageous to employ the element based method for multicomponent reaction-separation systems. It is shown that the same design-control principles...

  11. Applying interactive control to waste processing operations

    International Nuclear Information System (INIS)

    Grasz, E.L.; Merrill, R.D.; Couture, S.A.

    1992-08-01

    At present waste and residue processing includes steps that require human interaction. The risk of exposure to unknown hazardous materials and the potential for radiation contamination motivates the desire to remove operators from these processes. Technologies that facilitate this include glove box robotics, modular systems for remote and automated servicing, and interactive controls that minimize human intervention. LLNL is developing an automated system which is designed to supplant the operator for glove box tasks, thus protecting the operator from the risk of radiation exposure and minimizing operator-associated waste. Although most of the processing can be automated with minimal human interaction, there are some tasks where intelligent intervention is both desirable and necessary to adapt to Enexpected circumstances and events. These activities require that the operator interact with the process using a remote manipulator which provides or reflects a natural feel to the operator. The remote manipulation system which was developed incorporates sensor fusion and interactive control, and provides the operator with an effective means of controlling the robot in a potentially unknown environment. This paper describes recent accomplishments in technology development and integration, and outlines the future goals of Lawrence Livermore National Laboratory for achieving this integrated interactive control capability

  12. DOE handbook: Guide to good practices for training and qualification of chemical operators

    International Nuclear Information System (INIS)

    1996-03-01

    The purpose of this Handbook is to provide contractor training organizations with information that can be used as a reference to refine existing chemical operator training programs, or develop new training programs where no program exists. This guide, used in conjunction with facility-specific job analyses, will provide a framework for training and qualification programs for chemical operators at DOE reactor and nonreactor facilities. Recommendations for qualification are made in four areas: education, experience, physical attributes, and training. Contents include: initial qualification; administrative training; industrial safety training; specialized skills training; on-the-job training; trainee evaluation; continuing training; training effectiveness evaluation; and program records. Two appendices describe Fundamentals training and Process operations. This handbook covers chemical operators in transportation of fuels and wastes, spent fuel receiving and storage, fuel disassembly, fuel reprocessing, and both liquid and solid low-level waste processing

  13. Radiological and chemical source terms for Solid Waste Operations Complex

    International Nuclear Information System (INIS)

    Boothe, G.F.

    1994-01-01

    The purpose of this document is to describe the radiological and chemical source terms for the major projects of the Solid Waste Operations Complex (SWOC), including Project W-112, Project W-133 and Project W-100 (WRAP 2A). For purposes of this document, the term ''source term'' means the design basis inventory. All of the SWOC source terms involve the estimation of the radiological and chemical contents of various waste packages from different waste streams, and the inventories of these packages within facilities or within a scope of operations. The composition of some of the waste is not known precisely; consequently, conservative assumptions were made to ensure that the source term represents a bounding case (i.e., it is expected that the source term would not be exceeded). As better information is obtained on the radiological and chemical contents of waste packages and more accurate facility specific models are developed, this document should be revised as appropriate. Radiological source terms are needed to perform shielding and external dose calculations, to estimate routine airborne releases, to perform release calculations and dose estimates for safety documentation, to calculate the maximum possible fire loss and specific source terms for individual fire areas, etc. Chemical source terms (i.e., inventories of combustible, flammable, explosive or hazardous chemicals) are used to determine combustible loading, fire protection requirements, personnel exposures to hazardous chemicals from routine and accident conditions, and a wide variety of other safety and environmental requirements

  14. Risk management of exposure to chemicals under operational conditions

    NARCIS (Netherlands)

    Langenberg, J.P.

    2007-01-01

    The HFM panel has decided to install an Exploratory Team, ET-078, which should advise whether or not a Technical Group (TG) should be established on the subject of risk management of exposure to chemicals under operational conditions. This paper described the context and approach of ET-078.

  15. Inventory of chemicals used at Hanford Site production plants and support operations (1944-1980)

    Energy Technology Data Exchange (ETDEWEB)

    Klem, M. J.

    1990-04-01

    A complete list of chemicals used in the production facilities and support operations of the US Department of Energy Hanford Site is presented to aid development of plans for characterizing the radioactive liquid chemical wastes stored in the 149 single-shell tanks. The complete chemical list is compared to the list provided by the regulatory agencies to identify hazardous chemicals stored in the single-shell tanks. A reduced list has been developed by others and is used to identify the chemical constituents for analysis in the Waste Characterization Plan for the Hanford Site Single-Shell Tanks. The chemical list is based on chemical process flowsheets, essential material consumption records, letters, reports, and other historical data. 14 refs., 36 tabs.

  16. Chemical process and plant design bibliography 1959-1989

    International Nuclear Information System (INIS)

    Ray, M.S.

    1991-01-01

    This book is concerned specifically with chemical process in formation and plant equipment design data. It is a source for chemical engineers, students and academics involved in process and design evaluation. Over 500 chemical categories are included, from Acetaldehyde to zirconium Dioxide, with cross-referencing within the book to appropriate associated chemicals

  17. Chemical oxygen demand reduction in coffee wastewater through chemical flocculation and advanced oxidation processes

    Institute of Scientific and Technical Information of China (English)

    ZAYAS Pérez Teresa; GEISSLER Gunther; HERNANDEZ Fernando

    2007-01-01

    The removal of the natural organic matter present in coffee processing wastewater through chemical coagulation-flocculatio and advanced oxidation processes(AOP)had been studied.The effectiveness of the removal of natural organic matter using commercial flocculants and UV/H202,UVO3 and UV/H-H202/O3 processes was determined under acidic conditions.For each of these processes,different operational conditions were explored to optimize the treatment efficiency of the coffee wastewater.Coffee wastewater is characterized by a high chemical oxygen demand(COD)and low total suspended solids.The outcomes of coffee wastewater reeatment using coagulation-flocculation and photodegradation processes were assessed in terms of reduction of COD,color,and turbidity.It was found that a reductiOn in COD of 67%could be realized when the coffee wastewater was treated by chemical coagulation-flocculatlon witll lime and coagulant T-1.When coffee wastewater was treated by coagulation-flocculation in combination with UV/H202,a COD reduction of 86%was achieved,although only after prolonged UV irradiation.Of the three advanced oxidation processes considered,UV/H202,uv/03 and UV/H202/03,we found that the treatment with UV/H2O2/O3 was the most effective,with an efficiency of color,turbidity and further COD removal of 87%,when applied to the flocculated coffee wastewater.

  18. Operational Markov Condition for Quantum Processes

    Science.gov (United States)

    Pollock, Felix A.; Rodríguez-Rosario, César; Frauenheim, Thomas; Paternostro, Mauro; Modi, Kavan

    2018-01-01

    We derive a necessary and sufficient condition for a quantum process to be Markovian which coincides with the classical one in the relevant limit. Our condition unifies all previously known definitions for quantum Markov processes by accounting for all potentially detectable memory effects. We then derive a family of measures of non-Markovianity with clear operational interpretations, such as the size of the memory required to simulate a process or the experimental falsifiability of a Markovian hypothesis.

  19. Thermodynamics principles characterizing physical and chemical processes

    CERN Document Server

    Honig, Jurgen M

    1999-01-01

    This book provides a concise overview of thermodynamics, and is written in a manner which makes the difficult subject matter understandable. Thermodynamics is systematic in its presentation and covers many subjects that are generally not dealt with in competing books such as: Carathéodory''s approach to the Second Law, the general theory of phase transitions, the origin of phase diagrams, the treatment of matter subjected to a variety of external fields, and the subject of irreversible thermodynamics.The book provides a first-principles, postulational, self-contained description of physical and chemical processes. Designed both as a textbook and as a monograph, the book stresses the fundamental principles, the logical development of the subject matter, and the applications in a variety of disciplines. This revised edition is based on teaching experience in the classroom, and incorporates many exercises in varying degrees of sophistication. The stress laid on a didactic, logical presentation, and on the relat...

  20. Overview - Defense Waste Processing Facility Operating Experience

    International Nuclear Information System (INIS)

    Norton, M.R.

    2002-01-01

    The Savannah River Site's Defense Waste Processing Facility (DWPF) near Aiken, SC is the world's largest radioactive waste vitrification facility. Radioactive operations began in March 1996 and over 1,000 canisters have been produced. This paper presents an overview of the DWPF process and a summary of recent facility operations and process improvements. These process improvements include efforts to extend the life of the DWPF melter, projects to increase facility throughput, initiatives to reduce the quantity of wastewater generated, improved remote decontamination capabilities, and improvements to remote canyon equipment to extend equipment life span. This paper also includes a review of a melt rate improvement program conducted by Savannah River Technology Center personnel. This program involved identifying the factors that impacted melt rate, conducting small scale testing of proposed process changes and developing a cost effective implementation plan

  1. Process operational readiness and operational readiness follow-on

    International Nuclear Information System (INIS)

    Nertney, R.J.

    1992-11-01

    The first document in the System Safety Development Center (SSDC) series deals with the subject of Occupancy-Use Readiness. The material included in that manual provided the basis for development of the SSDC workshop in Operational Readiness. The original Occupancy Readiness Manual, however, deals only generally with the subject of process safety; i.e., the safety of overall ''processes'' such as solar collection systems, nuclear reactors, and coal fired electrical plants. The manual also fails to detail the considerations involved in maintaining the state of readiness on a continuing basis. Both of the latter subjects are dealt with in some detail in the SSDC's Operational Readiness Workshop. The purpose of this document is to provide additional documentary material dealing with subjects introduced in SSDC-1 Occupancy-Use Readiness Manual, and SSDC-12, Safety Considerations in Evaluation of Maintenance Programs. In augmenting SSDC-1, Part I of this manual provides additional material related to process safety; in the case of SSDC-12, the subject of safety considerations in evaluation of maintenance programs is broadened in Part II to include maintenance of personnel systems and procedural systems as well as hardware. ''Maintenance'' is related more directly to the concept of operational readiness and an alternative analytical tree is provided for hardware maintenance program evaluation

  2. Reactor operating procedures for start up of continuously operated chemical plants

    NARCIS (Netherlands)

    Verwijs, J.W.; Verwijs, J.W.; Kösters, P.H.; van den Berg, Henderikus; Westerterp, K.R.; Kosters, P.G.H.

    1995-01-01

    Rules are presented for the startup of an adiabatic tubular reactor, based on a qualitative analysis of the dynamic behavior of continuously-operated vapor- and liquid-phase processes. The relationships between the process dynamics, operating criteria, and operating constraints are investigated,

  3. Energetic Analysis of Poultry Processing Operations

    Directory of Open Access Journals (Sweden)

    Simeon Olatayo JEKAYINFA

    2007-01-01

    Full Text Available Energy audit of three poultry processing plants was conducted in southwestern Nigeria. The plants were grouped into three different categories based on their production capacities. The survey involved all the five easily defined unit operations utilized by the poultry processing industry and the experimental design allowed the energy consumed in each unit operation to be measured. The results of the audit revealed that scalding & defeathering is the most energy intensive unit operation in all the three plant categories, averagely accounting for about 44% of the total energy consumption in the processing plants. Other processing operations consuming energy in the following order are eviscerating (17.5%, slaughtering (17%, washing & chilling (16% and packing (6%. The results of the study clearly indicated that the least mechanized of the plants consumed the highest energy (50.36 MJ followed by the semi-mechanized plant (28.04 MJ and the most mechanized plant (17.83 MJ. The energy audits have provided baseline information needed for carrying out budgeting, forecasting energy requirements and planning plant expansion in the poultry processing industries in the study area.

  4. Soft Sensors: Chemoinformatic Model for Efficient Control and Operation in Chemical Plants.

    Science.gov (United States)

    Funatsu, Kimito

    2016-12-01

    Soft sensor is statistical model as an essential tool for controlling pharmaceutical, chemical and industrial plants. I introduce soft sensor, the roles, the applications, the problems and the research examples such as adaptive soft sensor, database monitoring and efficient process control. The use of soft sensor enables chemical industrial plants to be operated more effectively and stably. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Processing module operating methods, processing modules, and communications systems

    Science.gov (United States)

    McCown, Steven Harvey; Derr, Kurt W.; Moore, Troy

    2014-09-09

    A processing module operating method includes using a processing module physically connected to a wireless communications device, requesting that the wireless communications device retrieve encrypted code from a web site and receiving the encrypted code from the wireless communications device. The wireless communications device is unable to decrypt the encrypted code. The method further includes using the processing module, decrypting the encrypted code, executing the decrypted code, and preventing the wireless communications device from accessing the decrypted code. Another processing module operating method includes using a processing module physically connected to a host device, executing an application within the processing module, allowing the application to exchange user interaction data communicated using a user interface of the host device with the host device, and allowing the application to use the host device as a communications device for exchanging information with a remote device distinct from the host device.

  6. New Vistas in Chemical Product and Process Design.

    Science.gov (United States)

    Zhang, Lei; Babi, Deenesh K; Gani, Rafiqul

    2016-06-07

    Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design. Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack of data needed for model development, solution strategies that incorporate multiscale options, and reliability versus predictive power. The need for an integrated model-experiment-based design approach is discussed together with benefits of employing a systematic computer-aided framework with built-in design templates.

  7. BEHAVIOR OF MERCURY DURING DWPF CHEMICAL PROCESS CELL PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    Zamecnik, J.; Koopman, D.

    2012-04-09

    The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower

  8. Chemical Processing Department monthly report, October 1957

    Energy Technology Data Exchange (ETDEWEB)

    1957-11-22

    Record highs were set for Pu output in separations plants and for amount of U processed in Purex. UO{sub 3} production and shipments exceeded schedules. Fabrication of 200 and 250 Model assemblies is reported. Unfabricated Pu production was 8.5% short. Nitric acid recovery in Purex and Redox is reported. Prototype anion exchange system for Pu was tested in Purex. Hinged agitator arms with shear pin feature was installed in UO{sub 3} plant H calciner. Operation of continuous type Task I, II facility improved. DBBP is considered for Recuplex. Methods for Pu in product solutions agreed to within 0. 10%. Purex recycle dock shelter is complete. Other projects are reported.

  9. Implementing process safety management in gas processing operations

    International Nuclear Information System (INIS)

    Rodman, D.L.

    1992-01-01

    The Occupational Safety and Health Administration (OSHA) standard entitled Process Safety Management of Highly Hazardous Chemicals; Explosives and Blasting Agents was finalized February 24, 1992. The purpose of the standard is to prevent or minimize consequences of catastrophic releases of toxic, flammable, or explosive chemicals. OSHA believes that its rule will accomplish this goal by requiring a comprehensive management program that integrates technologies, procedures, and management practices. Gas Processors Association (GPA) member companies are significantly impacted by this major standard, the requirements of which are extensive and complex. The purpose of this paper is to review the requirements of the standard and to discuss the elements to consider in developing and implementing a viable long term Process Safety Management Program

  10. Chemical decontamination process and device therefor

    International Nuclear Information System (INIS)

    Takahashi, Ryota; Sakai, Hitoshi

    1998-01-01

    The present invention provides a process and a device for chemical decontamination, which can suppress corrosion of low corrosion resistant materials, keep decontamination properties substantially as same as before and further, reduce the volume of secondary wastes. In a step of reductively melting oxide membranes on an objective material to be decontaminated, a mixture of oxalic acid and a salt thereof is used as a reducing agent, and the reductive melting is conducted while suppressing hydrogen ion concentration of an aqueous liquid system. In order to enhance the reducibility of the oxalic acid ions, it is desirable to add a cyclic hetero compound thereto. The device of the present invention comprises, a decontamination loop including a member to be decontaminated, a heater and a pH meter, a medical injection pump for injecting a reducing agent to the decontamination loop, a metal ion recovering loop including an ion exchange resin tower, a reducing agent decomposing loop including an electrolytic vessel and/or a UV ray irradiation cell, a circulation pump for circulating the decontamination liquid to each of the loops and a plurality of opening/closing valves for switching the loop in which the decontamination liquid is circulated. (T.M.)

  11. Industry Operating Experience Process at Krsko NPP

    International Nuclear Information System (INIS)

    Bach, B.; Bozin, B.; Cizmek, R.

    2012-01-01

    according to Corrective Action Program, which establishes guidance on the effective and efficient use of operating experience information to improve plant/personnel safety, plant reliability and commercial performance. The primary objectives of the Operating Experience Program are to promote the identification and transfer of lessons learned from internal and industry events to the plant personnel, and assure that such lessons are shared between Krsko NPP and the nuclear industry. The Operating Experience Program expects to prevent similar events from occurring at Krsko NPP by increasing plant personnel awareness of previous on-site and industry events and issues. Operating Experience Program should also identify and analyze weaknesses of the minor events and near misses in order to prevent occurrence of significant events. The purpose of this article is to present part of the Krsko NPP Operating Experience Program regarding to industry events. It will describe the methodology for receiving, processing, screening, reviewing, evaluating, status reporting, defining and implementing preventive/corrective actions in response to operating experience information of the events occurring off-site.(author).

  12. Interim Action Proposed Plan for the Chemicals, Metals, and Pesticides (CMP) Pits Operable Unit; FINAL

    International Nuclear Information System (INIS)

    Bradley, J.

    2002-01-01

    The purpose of this Interim Action Proposed Plan (IAPP) is to describe the preferred interim remedial action for addressing the Chemicals, Metals, and Pesticides (CMP) Pits Operable Unit and to provide an opportunity for public input into the remedial action selection process

  13. Designing new nuclear chemical processing plants for safeguards accountability

    International Nuclear Information System (INIS)

    Sprouse, K.M.

    1987-01-01

    New nuclear chemical processing plants will be required to develop material accountability control limits from measurement error propagation analysis rather than historical inventory difference data as performed in the past. In order for measurement error propagation methods to be viable alternatives, process designers must ensure that two nondimensional accountability parameters are maintained below 0.1. These parameters are ratios between the material holdup increase and the variance in inventory difference measurement uncertainty. Measurement uncertainty data for use in error propagation analysis is generally available in the open literature or readily derived from instrument calibration data. However, nuclear material holdup data has not been adequately developed for use in the material accountability design process. Long duration development testing on isolated unit operations is required to generate this necessary information

  14. 40 CFR 63.443 - Standards for the pulping system at kraft, soda, and semi-chemical processes.

    Science.gov (United States)

    2010-07-01

    ... Paper Industry § 63.443 Standards for the pulping system at kraft, soda, and semi-chemical processes. (a... operator of each pulping system using a semi-chemical or soda process subject to the requirements of this... kraft, soda, and semi-chemical processes. 63.443 Section 63.443 Protection of Environment ENVIRONMENTAL...

  15. The Eco Logic gas-phase chemical reduction process

    International Nuclear Information System (INIS)

    Hallett, D.J.; Campbell, K.R.

    1994-01-01

    Since 1986, Eco Logic has conducted research with the aim of developing a new technology for destroying aqueous organic wastes, such as contaminated harbor sediments, landfill soil and leachates, and lagoon sludges. The goal was a commercially-viable chemical process that could deal with these watery wastes and also process stored wastes. The process described in this paper was developed with a view to avoiding the expense and technical drawbacks of incinerators, while still providing high destruction efficiencies and waste volume capabilities. A lab-scale process unit was constructed in 1988 and tested extensively. Based on the results of these tests, it was decided to construct a mobile pilot-scale unit that could be used for further testing and ultimately for small commercial waste processing operations. It was taken through a preliminary round of tests at Hamilton Harbour, Ontario, where the waste processed was coal-tar-contaminated harbor sediment. In 1992, the same unit was taken through a second round of tests in Bay City, Michigan. In this test program, the pilot-scale unit processed PCBs in aqueous, organic and soil matrices. This paper describes the process reactions and the pilot-scale process unit, and presents the results of pilot-scale testing thus far

  16. Speleothems as Examples of Chemical Equilibrium Processes.

    Science.gov (United States)

    Wilson, James R.

    1984-01-01

    The chemical formation of speleothems such as stalactites and stalagmites is poorly understood by introductory geology instructors and misrepresented in most textbooks. Although evaporation may be a controlling factor in some caves, it is necessary to consider chemical precipitation as more important in controlling the diagenesis of calcium…

  17. Development of the operational information processing platform

    International Nuclear Information System (INIS)

    Shin, Hyun Kook; Park, Jeong Seok; Baek, Seung Min; Kim, Young Jin; Joo, Jae Yoon; Lee, Sang Mok; Jeong, Young Woo; Seo, Ho Jun; Kim, Do Youn; Lee, Tae Hoon

    1996-02-01

    The Operational Information Processing Platform(OIPP) is platform system which was designed to provide the development and operation environments for plant operation and plant monitoring. It is based on the Plant Computer Systems (PCS) of Yonggwang 3 and 4, Ulchin 3 and 4, and Yonggwang 5 and 6 Nuclear Power Plants (NPP). The UNIX based workstation, real time kernel and graphics design tool are selected and installed through the reviewing the function of PCS. In order to construct the development environment for open system architecture and distributed computer system, open computer system architecture was adapted both in hardware and software. For verification of system design and evaluation of technical methodologies, the PCS running under the OIPP is being designed and implemented. In this system, the man-machine interface and system functions are being designed and implemented to evaluate the differences between the UCN 3, 4 PCS and OIPP. 15 tabs., 32 figs., 11 refs. (Author)

  18. Textiles and clothing sustainability sustainable textile chemical processes

    CERN Document Server

    2017-01-01

    This book highlights the challenges in sustainable wet processing of textiles, natural dyes, enzymatic textiles and sustainable textile finishes. Textile industry is known for its chemical processing issues and many NGO’s are behind the textile sector to streamline its chemical processing, which is the black face of clothing and fashion sector. Sustainable textile chemical processes are crucial for attaining sustainability in the clothing sector. Seven comprehensive chapters are aimed to highlight these issues in the book.

  19. Slaughterhouse wastewater treatment by combined chemical coagulation and electrocoagulation process.

    Science.gov (United States)

    Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

    2012-01-01

    Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD(5) removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater.

  20. Slaughterhouse Wastewater Treatment by Combined Chemical Coagulation and Electrocoagulation Process

    Science.gov (United States)

    Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

    2012-01-01

    Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD5 removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater. PMID:22768233

  1. A review of operational, regional-scale, chemical weather forecasting models in Europe

    Directory of Open Access Journals (Sweden)

    J. Kukkonen

    2012-01-01

    Full Text Available Numerical models that combine weather forecasting and atmospheric chemistry are here referred to as chemical weather forecasting models. Eighteen operational chemical weather forecasting models on regional and continental scales in Europe are described and compared in this article. Topics discussed in this article include how weather forecasting and atmospheric chemistry models are integrated into chemical weather forecasting systems, how physical processes are incorporated into the models through parameterization schemes, how the model architecture affects the predicted variables, and how air chemistry and aerosol processes are formulated. In addition, we discuss sensitivity analysis and evaluation of the models, user operational requirements, such as model availability and documentation, and output availability and dissemination. In this manner, this article allows for the evaluation of the relative strengths and weaknesses of the various modelling systems and modelling approaches. Finally, this article highlights the most prominent gaps of knowledge for chemical weather forecasting models and suggests potential priorities for future research directions, for the following selected focus areas: emission inventories, the integration of numerical weather prediction and atmospheric chemical transport models, boundary conditions and nesting of models, data assimilation of the various chemical species, improved understanding and parameterization of physical processes, better evaluation of models against data and the construction of model ensembles.

  2. An operational centre for managing major chemical industrial accidents.

    Science.gov (United States)

    Kiranoudis, C T; Kourniotis, S P; Christolis, M; Markatos, N C; Zografos, K G; Giannouli, I M; Androutsopoulos, K N; Ziomas, I; Kosmidis, E; Simeonidis, P; Poupkou, N

    2002-01-28

    The most important characteristic of major chemical accidents, from a societal perspective, is their tendency to produce off-site effects. The extent and severity of the accident may significantly affect the population and the environment of the adjacent areas. Following an accident event, effort should be made to limit such effects. Management decisions should be based on rational and quantitative information based on the site specific circumstances and the possible consequences. To produce such information we have developed an operational centre for managing large-scale industrial accidents. Its architecture involves an integrated framework of geographical information system (GIS) and RDBMS technology systems equipped with interactive communication capabilities. The operational centre was developed for Windows 98 platforms, for the region of Thriasion Pedion of West Attica, where the concentration of industrial activity and storage of toxic chemical is immense within areas of high population density. An appropriate case study is given in order to illuminate the use and necessity of the operational centre.

  3. Technical safety appraisal of the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    1992-05-01

    On June 27, 1989, Secretary of Energy, Admiral James D. Watkins, US Navy (Retired), announced a 10-point initiative to strengthen environment, safety, and health (ES ampersand H) programs and waste management operations in the Department of Energy (DOE). One of the initiatives involved conducting independent Tiger Team Assessments (TTA) at DOE operating facilities. A TTA of the Idaho National Engineering Laboratory (INEL) was performed during June and July 1991. Technical Safety Appraisals (TSA) were conducted in conjunction with the TTA as its Safety and Health portion. However, because of operational constraints the the Idaho Chemical Processing Plant (ICPP), operated for the DOE by Westinghouse Idaho Nuclear Company, Inc. (WINCO), was not included in the Safety and Health Subteam assessment at that time. This TSA, conducted April 12 - May 8, 1992, was performed by the DOE Office of Performance Assessment to complete the normal scope of the Safety and Health portion of the Tiger Team Assessment of the Idaho National Engineering Laboratory. The purpose of TSAs is to evaluate and strengthen DOE operations by verifying contractor compliance with DOE Orders, to assure that lessons learned from commercial operations are incorporated into facility operations, and to stimulate and encourage pursuit of excellence; thus, the appraisal addresses more issues than would be addressed in a strictly compliance-oriented appraisal. A total of 139 Performance Objectives have been addressed by this appraisal in 19 subject areas. These 19 areas are: organization and administration, quality verification, operations, maintenance, training and certification, auxiliary systems, emergency preparedness, technical support, packaging and transportation, nuclear criticality safety, safety/security interface, experimental activities, site/facility safety review, radiological protection, worker safety and health compliance, personnel protection, fire protection, medical services and natural

  4. 77 FR 7613 - Dow Chemical Company; Dow Chemical TRIGA Research Reactor; Facility Operating License No. R-108

    Science.gov (United States)

    2012-02-13

    ... NUCLEAR REGULATORY COMMISSION [Docket No. 50-264; NRC-2012-0026] Dow Chemical Company; Dow Chemical TRIGA Research Reactor; Facility Operating License No. R-108 AGENCY: Nuclear Regulatory Commission... Facility Operating License No. R-108 (``Application''), which currently authorizes the Dow Chemical Company...

  5. Combined Noncyclic Scheduling and Advanced Control for Continuous Chemical Processes

    Directory of Open Access Journals (Sweden)

    Damon Petersen

    2017-12-01

    Full Text Available A novel formulation for combined scheduling and control of multi-product, continuous chemical processes is introduced in which nonlinear model predictive control (NMPC and noncyclic continuous-time scheduling are efficiently combined. A decomposition into nonlinear programming (NLP dynamic optimization problems and mixed-integer linear programming (MILP problems, without iterative alternation, allows for computationally light solution. An iterative method is introduced to determine the number of production slots for a noncyclic schedule during a prediction horizon. A filter method is introduced to reduce the number of MILP problems required. The formulation’s closed-loop performance with both process disturbances and updated market conditions is demonstrated through multiple scenarios on a benchmark continuously stirred tank reactor (CSTR application with fluctuations in market demand and price for multiple products. Economic performance surpasses cyclic scheduling in all scenarios presented. Computational performance is sufficiently light to enable online operation in a dual-loop feedback structure.

  6. Idaho Chemical Processing Plant training program

    International Nuclear Information System (INIS)

    1975-01-01

    Objectives, regulations and requirements, training methods, certification and recertification, progression and incentives, and coverage of the ICPP operator training program are discussed in detail. (LK)

  7. Simulating operator decision processes at SRL

    International Nuclear Information System (INIS)

    Hoecker, D.G.; Benhardt, H.C.; Pople, H.E. Jr.

    1991-01-01

    Cognitive environment simulation (CES) is both a methodology and an artificial intelligence (AI) tool. As a methodology, it denotes a technique that models human operators' cognitive processes to either (a) aid in designing the interface to a complex system (such as nuclear reactor control room) or (b) assess the cognitive causality that effects the likelihood of human error in specific accident scenarios. As an AI tool, CES is an expert system that models human intention formation and errors in a problem-solving context. The immediate objective of the reported work was to demonstrate the feasibility of applying CES to a new domain - that of the defense production reactors, whose design and operating philosophy differ in key areas from power reactors, where CES has already demonstrated interesting results

  8. Statistical process control support during Defense Waste Processing Facility chemical runs

    International Nuclear Information System (INIS)

    Brown, K.G.

    1994-01-01

    The Product Composition Control System (PCCS) has been developed to ensure that the wasteforms produced by the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) will satisfy the regulatory and processing criteria that will be imposed. The PCCS provides rigorous, statistically-defensible management of a noisy, multivariate system subject to multiple constraints. The system has been successfully tested and has been used to control the production of the first two melter feed batches during DWPF Chemical Runs. These operations will demonstrate the viability of the DWPF process. This paper provides a brief discussion of the technical foundation for the statistical process control algorithms incorporated into PCCS, and describes the results obtained and lessons learned from DWPF Cold Chemical Run operations. The DWPF will immobilize approximately 130 million liters of high-level nuclear waste currently stored at the Site in 51 carbon steel tanks. Waste handling operations separate this waste into highly radioactive sludge and precipitate streams and less radioactive water soluble salts. (In a separate facility, soluble salts are disposed of as low-level waste in a mixture of cement slag, and flyash.) In DWPF, the precipitate steam (Precipitate Hydrolysis Aqueous or PHA) is blended with the insoluble sludge and ground glass frit to produce melter feed slurry which is continuously fed to the DWPF melter. The melter produces a molten borosilicate glass which is poured into stainless steel canisters for cooling and, ultimately, shipment to and storage in a geologic repository

  9. Chemical aspects of radiation damage processes: radiolysis

    International Nuclear Information System (INIS)

    Asmus, K.D.

    1975-01-01

    The formation of primary species and radiation chemical yields are discussed. In a section on chemical scavenging of primary species the author considers scavenging kinetics and competition reactions and gives a brief outline of some experimental methods. The radiation chemistry of aqueous solutions is discussed as an example for polar solvents. Cyclohexane is used as an example for non-polar solvents. The importance of excited states and energy transfer is considered. Reactions in the solid state are discussed and results on linear energy transfer and average ion pair formation for various kinds of radiation are surveyed. (B.R.H.)

  10. Low temperature radio-chemical energy conversion processes

    International Nuclear Information System (INIS)

    Gomberg, H.J.

    1986-01-01

    This patent describes a radio-chemical method of converting radiated energy into chemical energy form comprising the steps of: (a) establishing a starting chemical compound in the liquid phase that chemically reacts endothermically to radiation and heat energy to produce a gaseous and a solid constituent of the compound, (b) irradiating the compound in its liquid phase free of solvents to chemically release therefrom in response to the radiation the gaseous and solid constituents, (c) physically separating the solid and gaseous phase constituents from the liquid, and (d) chemically processing the constituents to recover therefrom energy stored therein by the irradiation step (b)

  11. "Chemical transformers" from nanoparticle ensembles operated with logic.

    Science.gov (United States)

    Motornov, Mikhail; Zhou, Jian; Pita, Marcos; Gopishetty, Venkateshwarlu; Tokarev, Ihor; Katz, Evgeny; Minko, Sergiy

    2008-09-01

    The pH-responsive nanoparticles were coupled with information-processing enzyme-based systems to yield "smart" signal-responsive hybrid systems with built-in Boolean logic. The enzyme systems performed AND/OR logic operations, transducing biochemical input signals into reversible structural changes (signal-directed self-assembly) of the nanoparticle assemblies, thus resulting in the processing and amplification of the biochemical signals. The hybrid system mimics biological systems in effective processing of complex biochemical information, resulting in reversible changes of the self-assembled structures of the nanoparticles. The bioinspired approach to the nanostructured morphing materials could be used in future self-assembled molecular robotic systems.

  12. Mechanistic, kinetic, and processing aspects of tungsten chemical mechanical polishing

    Science.gov (United States)

    Stein, David

    This dissertation presents an investigation into tungsten chemical mechanical polishing (CMP). CMP is the industrially predominant unit operation that removes excess tungsten after non-selective chemical vapor deposition (CVD) during sub-micron integrated circuit (IC) manufacture. This work explores the CMP process from process engineering and fundamental mechanistic perspectives. The process engineering study optimized an existing CMP process to address issues of polish pad and wafer carrier life. Polish rates, post-CMP metrology of patterned wafers, electrical test data, and synergy with a thermal endpoint technique were used to determine the optimal process. The oxidation rate of tungsten during CMP is significantly lower than the removal rate under identical conditions. Tungsten polished without inhibition during cathodic potentiostatic control. Hertzian indenter model calculations preclude colloids of the size used in tungsten CMP slurries from indenting the tungsten surface. AFM surface topography maps and TEM images of post-CMP tungsten do not show evidence of plow marks or intergranular fracture. Polish rate is dependent on potassium iodate concentration; process temperature is not. The colloid species significantly affects the polish rate and process temperature. Process temperature is not a predictor of polish rate. A process energy balance indicates that the process temperature is predominantly due to shaft work, and that any heat of reaction evolved during the CMP process is negligible. Friction and adhesion between alumina and tungsten were studied using modified AFM techniques. Friction was constant with potassium iodate concentration, but varied with applied pressure. This corroborates the results from the energy balance. Adhesion between the alumina and the tungsten was proportional to the potassium iodate concentration. A heuristic mechanism, which captures the relationship between polish rate, pressure, velocity, and slurry chemistry, is presented

  13. Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations

    Science.gov (United States)

    Johnson, Jr., James S.; Westmoreland, Clyde G.

    1982-01-01

    The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

  14. Stereodynamics: From elementary processes to macroscopic chemical reactions

    Energy Technology Data Exchange (ETDEWEB)

    Kasai, Toshio [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Graduate School of Science, Department of Chemistry, Osaka University, Toyonaka, 560-0043 Osaka (Japan); Che, Dock-Chil [Graduate School of Science, Department of Chemistry, Osaka University, Toyonaka, 560-0043 Osaka (Japan); Tsai, Po-Yu [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Lin, King-Chuen [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Palazzetti, Federico [Scuola Normale Superiore, Pisa (Italy); Dipartimento di Chimica Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Aquilanti, Vincenzo [Dipartimento di Chimica Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, Roma (Italy); Instituto de Fisica, Universidade Federal da Bahia, Salvador (Brazil)

    2015-12-31

    This paper aims at discussing new facets on stereodynamical behaviors in chemical reactions, i.e. the effects of molecular orientation and alignment on reactive processes. Further topics on macroscopic processes involving deviations from Arrhenius behavior in the temperature dependence of chemical reactions and chirality effects in collisions are also discussed.

  15. Chemical process safety management within the Department of Energy

    International Nuclear Information System (INIS)

    Piatt, J.A.

    1995-07-01

    Although the Department of Energy (DOE) is not well known for its chemical processing activities, the DOE does have a variety of chemical processes covered under OSHA's Rule for Process Safety Management of Highly Hazardous Chemicals (the PSM Standard). DOE, like industry, is obligated to comply with the PSM Standard. The shift in the mission of DOE away from defense programs toward environmental restoration and waste management has affected these newly forming process safety management programs within DOE. This paper describes the progress made in implementing effective process safety management programs required by the PSM Standard and discusses some of the trends that have supported efforts to reduce chemical process risks within the DOE. In June of 1994, a survey of chemicals exceeding OSHA PSM or EPA Risk Management Program threshold quantities (TQs) at DOE sites found that there were 22 processes that utilized toxic or reactive chemicals over TQs; there were 13 processes involving flammable gases and liquids over TQs; and explosives manufacturing occurred at 4 sites. Examination of the survey results showed that 12 of the 22 processes involving toxic chemicals involved the use of chlorine for water treatment systems. The processes involving flammable gases and liquids were located at the Strategic Petroleum Reserve and Naval petroleum Reserve sites

  16. ICPP [Idaho Chemical Processing Plant] environmental monitoring report, CY-1988

    International Nuclear Information System (INIS)

    Krivanek, K.R.

    1989-08-01

    Summarized in this report are the data collected through Environmental Monitoring programs conducted at the Idaho Chemical Processing Plant (ICPP) by the Environmental Engineering (EE) Section of the Nuclear and Industrial Safety (N and IS) Department. The ICPP is responsible for complying with all applicable Federal, State, Local and DOE Rules, Regulations and Orders. Radiological effluent and emissions are regulated by the DOE. The Environmental Protection Agency (EPA) regulates all nonradiological waste resulting from the ICPP operations including all airborne, liquid, and solid waste. The EE subsection completed a Quality Assurance (QA) Plan for Environmental Monitoring activities during the third quarter of 1986. QA activities have resulted in the ICPP's implementation of the Environmental Protection Agency rules and guidelines pertaining to the collection, analyses, and reporting of environmentally related samples. Where no approved methods for analyses existed for radionuclides, currently used methods were submitted for the EPA approval. 33 figs., 14 tabs

  17. Fluid flow for chemical and process engineers

    CERN Document Server

    Holland, F

    1995-01-01

    This major new edition of a popular undergraduate text covers topics of interest to chemical engineers taking courses on fluid flow. These topics include non-Newtonian flow, gas-liquid two-phase flow, pumping and mixing. It expands on the explanations of principles given in the first edition and is more self-contained. Two strong features of the first edition were the extensive derivation of equations and worked examples to illustrate calculation procedures. These have been retained. A new extended introductory chapter has been provided to give the student a thorough basis to understand the methods covered in subsequent chapters.

  18. The TESS Science Processing Operations Center

    Science.gov (United States)

    Jenkins, Jon M.; Twicken, Joseph D.; McCauliff, Sean; Campbell, Jennifer; Sanderfer, Dwight; Lung, David; Mansouri-Samani, Masoud; Girouard, Forrest; Tenenbaum, Peter; Klaus, Todd; hide

    2016-01-01

    The Transiting Exoplanet Survey Satellite (TESS) will conduct a search for Earth's closest cousins starting in early 2018 and is expected to discover approximately 1,000 small planets with R(sub p) less than 4 (solar radius) and measure the masses of at least 50 of these small worlds. The Science Processing Operations Center (SPOC) is being developed at NASA Ames Research Center based on the Kepler science pipeline and will generate calibrated pixels and light curves on the NASA Advanced Supercomputing Division's Pleiades supercomputer. The SPOC will also search for periodic transit events and generate validation products for the transit-like features in the light curves. All TESS SPOC data products will be archived to the Mikulski Archive for Space Telescopes (MAST).

  19. Operational experience of gamma radiation processing facility

    International Nuclear Information System (INIS)

    Patel, Nilesh

    2014-01-01

    Universal lSO-MED is now proud to announce an extension of its irradiation service for low-dose applications specifically in agriculture commodities, food and healthcare applications with the start of Gujarat Agro Radiation Processing Facility at Village: Bavla, Ahmedabad (A Government Enterprise) Operated, Maintained and Managed by Universal Medicap Ltd. Availability of hygienic, safe and nutritious food commodities is essential for any sustainable human development. Food stability is an important element of economic stability and self-reliance of a nation. Though the need to preserve food has been felt by the mankind since the time immemorial, it is even stronger in today's context. The rising population and increasing gap between demand and supply, agro-climatic conditions, in adequate post-harvest practices, seasonal nature of produce and long distances between production and consumption centers underscore the need to device improved conservation and preservation strategies

  20. Process control upgrades yield huge operational improvements

    International Nuclear Information System (INIS)

    Fitzgerald, W.V.

    2001-01-01

    Most nuclear plants in North America were designed and built in the late 60 and 70. The regulatory nature of this industry over the years has made design changes at the plant level difficult, if not impossible, to implement. As a result, many plants in this world region have been getting by on technology that is over 40 years behind the times. What this translates into is that the plants have not been able to take advantage of the huge technology gains that have been made in process control during this period. As a result, most of these plants are much less efficient and productive than they could be. One particular area of the plant that is receiving a lot of attention is the feedwater heaters. These systems were put in place to improve efficiency, but most are not operating correctly. This paper will present a case study where one progressive mid-western utility decided that enough was enough and implemented a process control audit of their heater systems. The audit clearly pointed out the existing problems with the current process control system. It resulted in a proposal for the implementation of a state of the art, digital distributed process control system for the heaters along with a complete upgrade of the level controls and field devices that will stabilize heater levels, resulting in significant efficiency gains and lower maintenance bills. Overall the payback period for this investment should be less than 6 months and the plant is now looking for more opportunities that can provide even bigger gains. (author)

  1. Intelligent process control of fiber chemical vapor deposition

    Science.gov (United States)

    Jones, John Gregory

    Chemical Vapor Deposition (CVD) is a widely used process for the application of thin films. In this case, CVD is being used to apply a thin film interface coating to single crystal monofilament sapphire (Alsb2Osb3) fibers for use in Ceramic Matrix Composites (CMC's). The hot-wall reactor operates at near atmospheric pressure which is maintained using a venturi pump system. Inert gas seals obviate the need for a sealed system. A liquid precursor delivery system has been implemented to provide precise stoichiometry control. Neural networks have been implemented to create real-time process description models trained using data generated based on a Navier-Stokes finite difference model of the process. Automation of the process to include full computer control and data logging capability is also presented. In situ sensors including a quadrupole mass spectrometer, thermocouples, laser scanner, and Raman spectrometer have been implemented to determine the gas phase reactants and coating quality. A fuzzy logic controller has been developed to regulate either the gas phase or the in situ temperature of the reactor using oxygen flow rate as an actuator. Scanning electron microscope (SEM) images of various samples are shown. A hierarchical control structure upon which the control structure is based is also presented.

  2. Process Design and Evaluation for Chemicals Based on Renewable Resources

    DEFF Research Database (Denmark)

    Fu, Wenjing

    . In addition, another characteristic of chemicals based on renewable feedstocks is that many alternative technologies and possible routes exist, resulting in many possible process flowsheets. The challenge for process engineers is then to choose between possible process routes and alternative technologies...... development of chemicals based on renewable feedstocks. As an example, this thesis especially focuses on applying the methodology in process design and evaluation of the synthesis of 5-hydroxymethylfurfural (HMF) from the renewable feedstock glucose/fructose. The selected example is part of the chemoenzymatic......One of the key steps in process design is choosing between alternative technologies, especially for processes producing bulk and commodity chemicals. Recently, driven by the increasing oil prices and diminishing reserves, the production of bulk and commodity chemicals from renewable feedstocks has...

  3. A survey of process control computers at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Dahl, C.A.

    1989-01-01

    The Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory is charged with the safe processing of spent nuclear fuel elements for the United States Department of Energy. The ICPP was originally constructed in the late 1950s and used state-of-the-art technology for process control at that time. The state of process control instrumentation at the ICPP has steadily improved to keep pace with emerging technology. Today, the ICPP is a college of emerging computer technology in process control with some systems as simple as standalone measurement computers while others are state-of-the-art distributed control systems controlling the operations in an entire facility within the plant. The ICPP has made maximal use of process computer technology aimed at increasing surety, safety, and efficiency of the process operations. Many benefits have been derived from the use of the computers for minimal costs, including decreased misoperations in the facility, and more benefits are expected in the future

  4. Chemical engineering aspect of solvent extraction in mineral processing

    International Nuclear Information System (INIS)

    Dara, S.S.; Jakkikar, M.S.

    1975-01-01

    Solvent extraction process, types of solvents used, types of extraction, distribution isotherm and McCabe-Thiele diagram for process design, equipment for the process, operating parameters and applications are described. (M.G.B.)

  5. Microbial production of bulk chemicals: development of anaerobic processes

    NARCIS (Netherlands)

    Weusthuis, R.A.; Lamot, I.; Oost, van der J.; Sanders, J.P.M.

    2011-01-01

    nnovative fermentation processes are necessary for the cost-effective production of bulk chemicals from renewable resources. Current microbial processes are either anaerobic processes, with high yield and productivity, or less-efficient aerobic processes. Oxygen utilization plays an important role

  6. Development of chemical process for synthesis of polyunsaturated esters

    OpenAIRE

    Vera LÃcia Viana do Nascimento

    2014-01-01

    This work aimed to develop refining processes, chemical alcoholysis followed by separation of fatty acids using the complexation with urea technique for the synthesis of poly-unsaturated esters from waste of fish oils. The special crude fish oil was purchased from Company Campestre - SÃo Paulo. Initially this oil has undergone a process of physical and chemical refining. From the refined oil, an alcoholysis process was carried out to obtain the mixture of free fatty acids. From the hydrolyzed...

  7. The chemical energy unit partial oxidation reactor operation simulation modeling

    Science.gov (United States)

    Mrakin, A. N.; Selivanov, A. A.; Batrakov, P. A.; Sotnikov, D. G.

    2018-01-01

    The chemical energy unit scheme for synthesis gas, electric and heat energy production which is possible to be used both for the chemical industry on-site facilities and under field conditions is represented in the paper. The partial oxidation reactor gasification process mathematical model is described and reaction products composition and temperature determining algorithm flow diagram is shown. The developed software product verification showed good convergence of the experimental values and calculations according to the other programmes: the temperature determining relative discrepancy amounted from 4 to 5 %, while the absolute composition discrepancy ranged from 1 to 3%. The synthesis gas composition was found out practically not to depend on the supplied into the partial oxidation reactor (POR) water vapour enthalpy and compressor air pressure increase ratio. Moreover, air consumption coefficient α increase from 0.7 to 0.9 was found out to decrease synthesis gas target components (carbon and hydrogen oxides) specific yield by nearly 2 times and synthesis gas target components required ratio was revealed to be seen in the water vapour specific consumption area (from 5 to 6 kg/kg of fuel).

  8. Integrated biological, chemical and physical processes kinetic ...

    African Journals Online (AJOL)

    ... for C and N removal, only gas and liquid phase processes were considered for this integrated model. ... kLA value for the aeration system, which affects the pH in the anoxic and aerobic reactors through CO2 gas exchange. ... Water SA Vol.

  9. Microwave plasma emerging technologies for chemical processes

    NARCIS (Netherlands)

    de la Fuente, Javier F.; Kiss, Anton A.; Radoiu, Marilena T.; Stefanidis, Georgios D.

    2017-01-01

    Microwave plasma (MWP) technology is currently being used in application fields such as semiconductor and material processing, diamond film deposition and waste remediation. Specific advantages of the technology include the enablement of a high energy density source and a highly reactive medium,

  10. Safety aspects in a chemical exchange process plant

    International Nuclear Information System (INIS)

    Sharma, B.K.

    2016-01-01

    Based on a chemical exchange process involving solid liquid exchange, studies have been undertaken to enrich 10 B isotope of boron using ion exchange chromatography in which a strong base anion exchange resin in hydroxyl form is equilibrated with boric acid solution in presence of mannitol (a complexing reagent to boric acid) to enhance the acidity and hence the isotopic exchange separation factor for 10 B = 11 B exchange reaction. Using the electrochemical techniques such as pH-metry and conductimetry, the choice of a suitable complexing reagent was made amongst ethylene glycol, propylene glycol, dextrose and mannitol for cost-effective separation of isotopes of boron and monitoring of band movements using these electrochemical techniques. The optimum conditions for the regeneration of strong base anion exchange resins of type-I and type-II were determined for cost-effective separation of isotopes of boron by ion exchange chromatography. The possibility of using unspent alkali content of the effluent was also exploited. Removal of carbonate impurity from Rayon grade caustic lye (used as regenerant after dilution) and recycling of Ba(OH) 2 was studied to avoid waste disposal problems. This process is an industrially viable process. The various safety aspects followed during operation of this plant are described in this paper. (author)

  11. Kennedy Space Center Orion Processing Team Planning for Ground Operations

    Science.gov (United States)

    Letchworth, Gary; Schlierf, Roland

    2011-01-01

    Topics in this presentation are: Constellation Ares I/Orion/Ground Ops Elements Orion Ground Operations Flow Orion Operations Planning Process and Toolset Overview, including: 1 Orion Concept of Operations by Phase 2 Ops Analysis Capabilities Overview 3 Operations Planning Evolution 4 Functional Flow Block Diagrams 5 Operations Timeline Development 6 Discrete Event Simulation (DES) Modeling 7 Ground Operations Planning Document Database (GOPDb) Using Operations Planning Tools for Operability Improvements includes: 1 Kaizen/Lean Events 2 Mockups 3 Human Factors Analysis

  12. Modelling of chemical reactions in metallurgical processes

    OpenAIRE

    Kinaci, M. Efe; Lichtenegger, Thomas; Schneiderbauer, Simon

    2017-01-01

    Iron-ore reduction has attracted much interest in the last three decades since it can be considered as a core process in steel industry. The iron-ore is reduced to iron with the use of blast furnace and fluidized bed technologies. To investigate the harsh conditions inside fluidized bed reactors, computational tools can be utilized. One such tool is the CFD-DEM method, in which the gas phase reactions and governing equations are calculated in the Eulerian (CFD) side, whereas the particle reac...

  13. Chemical kinetics, stochastic processes, and irreversible thermodynamics

    CERN Document Server

    Santillán, Moisés

    2014-01-01

    This book brings theories in nonlinear dynamics, stochastic processes, irreversible thermodynamics, physical chemistry, and biochemistry together in an introductory but formal and comprehensive manner.  Coupled with examples, the theories are developed stepwise, starting with the simplest concepts and building upon them into a more general framework.  Furthermore, each new mathematical derivation is immediately applied to one or more biological systems.  The last chapters focus on applying mathematical and physical techniques to study systems such as: gene regulatory networks and ion channels. The target audience of this book are mainly final year undergraduate and graduate students with a solid mathematical background (physicists, mathematicians, and engineers), as well as with basic notions of biochemistry and cellular biology.  This book can also be useful to students with a biological background who are interested in mathematical modeling, and have a working knowledge of calculus, differential equatio...

  14. Computer-Aided Multiscale Modelling for Chemical Process Engineering

    DEFF Research Database (Denmark)

    Morales Rodriguez, Ricardo; Gani, Rafiqul

    2007-01-01

    Chemical processes are generally modeled through monoscale approaches, which, while not adequate, satisfy a useful role in product-process design. In this case, use of a multi-dimensional and multi-scale model-based approach has importance in product-process development. A computer-aided framework...

  15. Textual and chemical information processing: different domains but similar algorithms

    Directory of Open Access Journals (Sweden)

    Peter Willett

    2000-01-01

    Full Text Available This paper discusses the extent to which algorithms developed for the processing of textual databases are also applicable to the processing of chemical structure databases, and vice versa. Applications discussed include: an algorithm for distribution sorting that has been applied to the design of screening systems for rapid chemical substructure searching; the use of measures of inter-molecular structural similarity for the analysis of hypertext graphs; a genetic algorithm for calculating term weights for relevance feedback searching for determining whether a molecule is likely to exhibit biological activity; and the use of data fusion to combine the results of different chemical similarity searches.

  16. Evaluation of physical facilities and processing operations of major ...

    African Journals Online (AJOL)

    ADEYEYE

    abattoirs were as a result of failure to enforce the use of standard facilities in carrying out abattoir operations and general maintenance ... incinerator, chemical treatment and disposal. Sub- .... Veterinary laboratory .... sustainable food security.

  17. High temperature nuclear process heat systems for chemical processes

    International Nuclear Information System (INIS)

    Jiacoletti, R.J.

    1976-01-01

    The development planning and status of the very high temperature gas cooled reactor as a source of industrial process heat is presented. The dwindling domestic reserves of petroleum and natural gas dictate major increases in the utilization of coal and nuclear sources to meet the national energy demand. The nuclear process heat system offers a unique combination of the two that is environmentally and economically attractive and technically sound. Conceptual studies of several energy-intensive processes coupled to a nuclear heat source are presented

  18. Development of Chemical Process Design and Control for Sustainability

    Science.gov (United States)

    This contribution describes a novel process systems engineering framework that couples advanced control with sustainability evaluation and decision making for the optimization of process operations to minimize environmental impacts associated with products, materials, and energy....

  19. Applicable safety-related design and operations considerations from the oil and chemical industries

    International Nuclear Information System (INIS)

    Mulvihill, R.J.; Deshotels, R.L.; Master, C.A.

    1987-01-01

    Fluor Daniel has conducted several hazards and risk analyses on petroleum and chemical facilities. These analyses included qualitative hazards and operability (HAZOP) studies, preliminary hazards analyses, and qualitative fault-tree analysis as well as quantitative event-tree/fault-tree risk analysis. Several design-related problem areas were uncovered as a result of these analyses as well as deficiencies in operations and maintenance. Design deficiency areas include potential common-mode failures associated with redundant functions sharing a common distributed digital control (DDC) logic circuit board and failures in pressure relief systems. Many of the design weaknesses and potential operator errors discussed have a direct counterpart in nuclear fuel processing plants and nuclear power reactors. Counterparts that are discussed are common cause/common mode failures in control systems and failures in pressure relief systems. Overpressurization of piping and vessels resulting in rupture is discussed. Mitigating design features and operations procedures that have been implemented in the chemical process industry are described and their applicability to the nuclear industry is discussed

  20. ACToR Chemical Structure processing using Open Source ...

    Science.gov (United States)

    ACToR (Aggregated Computational Toxicology Resource) is a centralized database repository developed by the National Center for Computational Toxicology (NCCT) at the U.S. Environmental Protection Agency (EPA). Free and open source tools were used to compile toxicity data from over 1,950 public sources. ACToR contains chemical structure information and toxicological data for over 558,000 unique chemicals. The database primarily includes data from NCCT research programs, in vivo toxicity data from ToxRef, human exposure data from ExpoCast, high-throughput screening data from ToxCast and high quality chemical structure information from the EPA DSSTox program. The DSSTox database is a chemical structure inventory for the NCCT programs and currently has about 16,000 unique structures. Included are also data from PubChem, ChemSpider, USDA, FDA, NIH and several other public data sources. ACToR has been a resource to various international and national research groups. Most of our recent efforts on ACToR are focused on improving the structural identifiers and Physico-Chemical properties of the chemicals in the database. Organizing this huge collection of data and improving the chemical structure quality of the database has posed some major challenges. Workflows have been developed to process structures, calculate chemical properties and identify relationships between CAS numbers. The Structure processing workflow integrates web services (PubChem and NIH NCI Cactus) to d

  1. Modeling of biopharmaceutical processes. Part 2: Process chromatography unit operation

    DEFF Research Database (Denmark)

    Kaltenbrunner, Oliver; McCue, Justin; Engel, Philip

    2008-01-01

    Process modeling can be a useful tool to aid in process development, process optimization, and process scale-up. When modeling a chromatography process, one must first select the appropriate models that describe the mass transfer and adsorption that occurs within the porous adsorbent. The theoret......Process modeling can be a useful tool to aid in process development, process optimization, and process scale-up. When modeling a chromatography process, one must first select the appropriate models that describe the mass transfer and adsorption that occurs within the porous adsorbent...

  2. APET methodology for Defense Waste Processing Facility: Mode C operation

    International Nuclear Information System (INIS)

    Taylor, R.P. Jr.; Massey, W.M.

    1995-04-01

    Safe operation of SRS facilities continues to be the highest priority of the Savannah River Site (SRS). One of these facilities, the Defense Waste Processing Facility or DWPF, is currently undergoing cold chemical runs to verify the design and construction preparatory to hot startup in 1995. The DWPFF is a facility designed to convert the waste currently stored in tanks at the 200-Area tank farm into a form that is suitable for long term storage in engineered surface facilities and, ultimately, geologic isolation. As a part of the program to ensure safe operation of the DWPF, a probabilistic Safety Assessment of the DWPF has been completed. The results of this analysis are incorporated into the Safety Analysis Report (SAR) for DWPF. The usual practice in preparation of Safety Analysis Reports is to include only a conservative analysis of certain design basis accidents. A major part of a Probabilistic Safety Assessment is the development and quantification of an Accident Progression Event Tree or APET. The APET provides a probabilistic representation of potential sequences along which an accident may progress. The methodology used to determine the risk of operation of the DWPF borrows heavily from methods applied to the Probabilistic Safety Assessment of SRS reactors and to some commercial reactors. This report describes the Accident Progression Event Tree developed for the Probabilistic Safety Assessment of the DWPF

  3. Physical and chemical characterization of bioaerosols - Implications for nucleation processes

    Science.gov (United States)

    Ariya, P. A.; Sun, J.; Eltouny, N. A.; Hudson, E. D.; Hayes, C. T.; Kos, G.

    The importance of organic compounds in the oxidative capacity of the atmosphere, and as cloud condensation and ice-forming nuclei, has been recognized for several decades. Organic compounds comprise a significant fraction of the suspended matter mass, leading to local (e.g. toxicity, health hazards) and global (e.g. climate change) impacts. The state of knowledge of the physical chemistry of organic aerosols has increased during the last few decades. However, due to their complex chemistry and the multifaceted processes in which they are involved, the importance of organic aerosols, particularly bioaerosols, in driving physical and chemical atmospheric processes is still very uncertain and poorly understood. Factors such as solubility, surface tension, chemical impurities, volatility, morphology, contact angle, deliquescence, wettability, and the oxidation process are pivotal in the understanding of the activation processes of cloud droplets, and their chemical structures, solubilities and even the molecular configuration of the microbial outer membrane, all impact ice and cloud nucleation processes in the atmosphere. The aim of this review paper is to assess the current state of knowledge regarding chemical and physical characterization of bioaerosols with a focus on those properties important in nucleation processes. We herein discuss the potential importance (or lack thereof) of physical and chemical properties of bioaerosols and illustrate how the knowledge of these properties can be employed to study nucleation processes using a modeling exercise. We also outline a list of major uncertainties due to a lack of understanding of the processes involved or lack of available data. We will also discuss key issues of atmospheric significance deserving future physical chemistry research in the fields of bioaerosol characterization and microphysics, as well as bioaerosol modeling. These fundamental questions are to be addressed prior to any definite conclusions on the

  4. Impact of Salt Waste Processing Facility Streams on the Nitric-Glycolic Flowsheet in the Chemical Processing Cell

    Energy Technology Data Exchange (ETDEWEB)

    Martino, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-08-08

    An evaluation of the previous Chemical Processing Cell (CPC) testing was performed to determine whether the planned concurrent operation, or “coupled” operations, of the Defense Waste Processing Facility (DWPF) with the Salt Waste Processing Facility (SWPF) has been adequately covered. Tests with the nitricglycolic acid flowsheet, which were both coupled and uncoupled with salt waste streams, included several tests that required extended boiling times. This report provides the evaluation of previous testing and the testing recommendation requested by Savannah River Remediation. The focus of the evaluation was impact on flammability in CPC vessels (i.e., hydrogen generation rate, SWPF solvent components, antifoam degradation products) and processing impacts (i.e., acid window, melter feed target, rheological properties, antifoam requirements, and chemical composition).

  5. Chemical Changes in Carbohydrates Produced by Thermal Processing.

    Science.gov (United States)

    Hoseney, R. Carl

    1984-01-01

    Discusses chemical changes that occur in the carbohydrates found in food products when these products are subjected to thermal processing. Topics considered include browning reactions, starch found in food systems, hydrolysis of carbohydrates, extrusion cooking, processing of cookies and candies, and alterations in gums. (JN)

  6. Standing operating procedures for developing acute exposure guideline levels for hazardous chemicals

    National Research Council Canada - National Science Library

    National Research Council (U.S.). Subcommittee on Acute Exposure Guideline Levels

    2001-01-01

    Standing Operating Procedures for Developing Acute Exposure Guideline Levels for Hazardous Chemicals contains a detailed and comprehensive methodology for developing acute exposure guideline levels (AEGLs...

  7. Operation and Design of Diabatic Distillation Processes

    DEFF Research Database (Denmark)

    Bisgaard, Thomas

    Diabatic operation of a distillation column implies that heat is exchanged in one or more stages in the column. The most common way of realising diabatic operation is by internal heat integration resulting in a heat-integrated distillation column (HIDiC). When operating the rectifying section...... at a higher pressure, a driving forcefor transferring heat from the rectifying section to the stripping section is achieved. As a result, the condenser and reboiler duties can be significantly reduced. For two-product distillation, the HIDiC is a favourable alternative to the conventional distillation column....... Energy savings up to 83% are reported for the HIDiC compared to the CDiC, while the reported economical savings are as high as 40%. However, a simpler heat-integrated distillation column configuration exists, which employs compression in order to obtain a direct heat integration between the top vapour...

  8. Chemical sensors and gas sensors for process control in biotechnology

    International Nuclear Information System (INIS)

    Williams, D.E.

    1988-04-01

    This paper is concerned with the possibilities for chemical measurement of the progress of biotechnological processes which are offered by devices already developed for other demanding applications. It considers the potential use of ultrasonic instrumentation originally developed for the nuclear industry, gas measurement methods from the fields of environmental monitoring and combustion control, nuclear instruments developed for the oil, mining and chemical industries, robotic systems and advanced control techniques. (author)

  9. The new risk paradigm for chemical process security and safety.

    Science.gov (United States)

    Moore, David A

    2004-11-11

    The world of safety and security in the chemical process industries has certainly changed since 11 September, but the biggest challenges may be yet to come. This paper will explain that there is a new risk management paradigm for chemical security, discuss the differences in interpreting this risk versus accidental risk, and identify the challenges we can anticipate will occur in the future on this issue. Companies need to be ready to manage the new chemical security responsibilities and to exceed the expectations of the public and regulators. This paper will outline the challenge and a suggested course of action.

  10. Advances in chemical engineering in nuclear and process industries

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-06-01

    Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately.

  11. Advances in chemical engineering in nuclear and process industries

    International Nuclear Information System (INIS)

    1994-06-01

    Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately

  12. Mechanisms governing the physico-chemical processes of transfer in NPP circuits

    International Nuclear Information System (INIS)

    Brusakov, V.P.; Sedov, V.M.; Khitrov, Yu.A.; Rybalchenko, I.L.

    1983-01-01

    The paper deals with the theoretical physico-chemical processes of corrosion products and their radionuclide transport in NPS circuits by thermoelectromotive and electromotive forces of microgalvanic couples. The laboratory and rig test results as well as the NPP operating experience data confirm the developed theoretical concept validity

  13. Gold processing residue from Jacobina Basin: chemical and physical properties

    OpenAIRE

    Lima, Luiz Rogério Pinho de Andrade; Bernardez, Letícia Alonso; Barbosa, Luís Alberto Dantas

    2007-01-01

    p. 848-852 Gold processing residues or tailings are found in several areas in the Itapicuru River region (Bahia, Brazil), and previous studies indicated significant heavy metals content in the river sediments. The present work focused on an artisanal gold processing residue found in a site from this region. Samples were taken from the processing residue heaps and used to perform a physical and chemical characterization study using X-ray diffraction, scanning electron microscopy, neutron...

  14. Operational High Resolution Chemical Kinetics Simulation, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Numerical simulations of chemical kinetics are critical to addressing urgent issues in both the developed and developing world. Ongoing demand for higher resolution...

  15. Chemical-cleaning process evaluation: Westinghouse steam generators. Final report

    International Nuclear Information System (INIS)

    Cleary, W.F.; Gockley, G.B.

    1983-04-01

    The Steam Generator Owners Group (SGOG)/Electric Power Research Institute (EPRI) Steam Generator Secondary Side Chemical Cleaning Program, under develpment since 1978, has resulted in a generic process for the removal of accumulated corrosion products and tube deposits in the tube support plate crevices. The SGOG/EPRI Project S150-3 was established to obtain an evaluation of the generic process in regard to its applicability to Westinghouse steam generators. The results of the evaluation form the basis for recommendations for transferring the generic process to a plant specific application and identify chemical cleaning corrosion guidelines for the materials in Westinghouse Steam Generators. The results of the evaluation, recommendations for plant-specific applications and corrosion guidelines for chemical cleaning are presented in this report

  16. Materials control and accountability at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Denning, G.E.; Britschgi, J.J.; Spraktes, F.W.

    1985-01-01

    The ICPP high enriched uranium recovery process has historically been operated as a single Material Balance Area (MBA), with input and output measurement capabilities. Safeguards initiated changes in the last five years have resulted in significant materials control and accountability improvements. Those changes include semi-automation of process accountability measurement, data collection and recording; definition of Sub-MBAs; standard plant cleanouts; and, bimonthly inventory estimates. Process monitoring capabilities are also being installed to provide independent operational procedural compliance verification, process anomaly detection, and enhanced materials traceability. Development of a sensitivity analysis approach to defining process measurement requirements is in progress

  17. Process Analysis of the CV Group's Operation

    CERN Document Server

    Wilhelmsson, M

    2000-01-01

    This report will give an explanation of the internal reorganization that has been done because of the necessity to optimize operation in the cooling and ventilation group. The basic structure for the group was defined at the end of 1998. We understood then that change was needed to accommodate the increased workload due to the LHC project. In addition, we face a relatively large turnover of personnel (retirements and some recruitment) with related integration issues to consider. We would also like to implement new approaches in the management of both operations and maintenance. After some running-in problems during the first half of 1999, we realized that much more could be gained with the analysis and the definition and documenting of each single function and generic activity within the group. The authors will explain how this analysis was carried out and give some feedback of the outcome, so far.

  18. Chemical analysis of cyanide in cyanidation process: review of methods

    International Nuclear Information System (INIS)

    Nova-Alonso, F.; Elorza-Rodriguez, E.; Uribe-Salas, A.; Perez-Garibay, R.

    2007-01-01

    Cyanidation, the world wide method for precious metals recovery, the chemical analysis of cyanide, is a very important, but complex operation. Cyanide can be present forming different species, each of them with different stability, toxicity, analysis method and elimination technique. For cyanide analysis, there exists a wide selection of analytical methods but most of them present difficulties because of the interference of species present in the solution. This paper presents the different available methods for chemical analysis of cyanide: titration, specific electrode and distillation, giving special emphasis on the interferences problem, with the aim of helping in the interpretation of the results. (Author)

  19. The 'PROCESO' index: a new methodology for the evaluation of operational safety in the chemical industry

    International Nuclear Information System (INIS)

    Marono, M.; Pena, J.A.; Santamaria, J.

    2006-01-01

    The acknowledgement of industrial installations as complex systems in the early 1980s outstands as a milestone in the path to operational safety. Process plants are social-technical complex systems of a dynamic nature, whose properties depend not only on their components, but also on the inter-relations among them. A comprehensive assessment of operational safety requires a systemic approach, i.e. an integrated framework that includes all the relevant factors influencing safety. Risk analysis methodologies and safety management systems head the list of methods that point in this direction, but they normally require important plant resources. As a consequence, their use is frequently restricted to especially dangerous processes often driven by compliance with legal requirements. In this work a new safety index for the chemical industry, termed the 'Proceso' Index (standing for the Spanish terms for PROCedure for the Evaluation of Operational Safety), has been developed. PROCESO is based on the principles of systems theory, has a tree-like structure and considers 25 areas to guide the review of plant safety. The method uses indicators whose respective weight values have been obtained via an expert judgement technique. This paper describes the steps followed to develop this new Operational Safety Index, explains its structure and illustrates its application to process plants

  20. Influence of chemical processing on the imaging properties of microlenses

    International Nuclear Information System (INIS)

    Vasiljevic, Darko; Muric, Branka; Pantelic, Dejan; Panic, Bratimir

    2009-01-01

    Microlenses are produced by irradiation of a layer of tot'hema and eosin sensitized gelatin (TESG) by using a laser beam (Nd:YAG 2nd harmonic; 532 nm). All the microlenses obtained are concave with a parabolic profile. After the production, the microlenses are chemically processed with various concentrations of alum. The following imaging properties of microlenses were calculated and analyzed: the root mean square (rms) wavefront aberration, the geometric encircled energy and the spot diagram. The microlenses with higher concentrations of alum in solution had a greater effective focal length and better image quality. The microlenses chemically processed with 10% alum solution had near-diffraction-limited performance.

  1. Improving the Financial Resourcing Process for Civil/Military Operations

    National Research Council Canada - National Science Library

    Gadbois, Karen

    2004-01-01

    .... This was evident in the most recent stability operation in Afghanistan. Although financial resourcing is key to the planning process prior to operational commencement the intricacies of the rules and financial mechanisms are not sufficiently addressed...

  2. Sustaining Operational Resiliency: A Process Improvement Approach to Security Management

    National Research Council Canada - National Science Library

    Caralli, Richard A

    2006-01-01

    .... Coordinating these efforts to sustain operational resiliency requires a process-oriented approach that can be defined, measured, and actively managed. This report describes the fundamental elements and benefits of a process approach to security and operational resiliency and provides a notional view of a framework for process improvement.

  3. 9 CFR 590.542 - Spray process drying operations.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Spray process drying operations. 590..., Processing, and Facility Requirements § 590.542 Spray process drying operations. (a) The drying room shall be... interrupted. (1) Spray nozzles, orifices, cores, or whizzers shall be cleaned immediately after cessation of...

  4. 19 CFR 10.814 - Direct costs of processing operations.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Direct costs of processing operations. 10.814... Free Trade Agreement Rules of Origin § 10.814 Direct costs of processing operations. (a) Items included. For purposes of § 10.810(b) of this subpart, the words “direct costs of processing operations”, with...

  5. 19 CFR 10.774 - Direct costs of processing operations.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Direct costs of processing operations. 10.774... Free Trade Agreement Rules of Origin § 10.774 Direct costs of processing operations. (a) Items included. For purposes of § 10.770(b) of this subpart, the words “direct costs of processing operations”, with...

  6. Process Analysis in Chemical Plant by Means of Radioactive Tracers

    Energy Technology Data Exchange (ETDEWEB)

    Hirayama, T.; Hamada, K.; Osada, K. [Showa Denko K.K., Tokyo (Japan)

    1967-06-15

    Following the movement of solids and fluids is important in chemical processes to determine mixing efficiency and residence time. Since it is necessary to follow many complex substances such as raw materials, intermediates and reactants in plant investigations, it is often necessary to ascertain whether the behaviour of the radioisotope tracer and the substance to be traced are identical. The most difficult problem is to determine the best method of labelling, a factor which is a substantial key to the success of an experiment. Usually, there are three labelling techniques: radioisotope labelling, pre-.activation of the material and post-activation of the material. This paper deals with practical examples of the double-tracer technique, a combination of conventional radioisotope labelling and post-activation methods by means of activation analysis. In process analysis by means of tracers, a practical measurement method should also be devised and developed for each experiment. Phosphorus-32 and gold (non-radioactive) were used to measure retention time in a carbon-black plant. The radioisotope was pumped into a feed-stock pipe positioned before the reactor and samples were taken from each process of the plant, including the bag filter, mixer and product tank. After sampling from each step of the process, {sup 32}P in a semi-infinite powder sample was measured in situ by beta counting, and the gold was measured by gamma counting after activating the sample in a reactor. The experiment showed that both tracers had the same residence time, which was shorter than expected. Useful data were also obtained from the dispersion pattern of the material flow for future operation controls, including the time required to change from one grade of product to another. Practical tracer techniques to measure mixing characteristics in high-speed gas flows using {sup 85}Kr have been developed. A study of the measurement method was conducted by calculating the differential values of

  7. Radiation protection -Operation of chemical wastewater treatment facility

    International Nuclear Information System (INIS)

    Lee, M. J.; Lim, M. H.; Ahn, S. S.; Jeong, Y. S.

    1996-12-01

    The wastewater and sewage treatment facility have been operated. From the results of operation, it was confirmed that the quality of treated wastewater was 1/5 or 1/10 lower than that of regulation of law for environmental conservation. The quality of treated sewage has been maintained to 70% of regulation of law for environmental conservation. (author). 14 tabs., 8 figs

  8. Matrix Wings: Continuous Process Improvement an Operator Can Love

    Science.gov (United States)

    2016-09-01

    key processes in our normal operations. In addition to the almost inevitable resistance to change, one of the points of pushback is that members of...Fall 2016 | 9 Matrix Wings Continuous Process Improvement an Operator Can Love Dr. A. J. Briding, Colonel, USAF, Retired Disclaimer: The views and...Operations for the 21st Century (AFSO21), the latest comprehensive effort at finding the right ap- proach for implementing a continuous process

  9. Hierarchical optimal control of large-scale nonlinear chemical processes.

    Science.gov (United States)

    Ramezani, Mohammad Hossein; Sadati, Nasser

    2009-01-01

    In this paper, a new approach is presented for optimal control of large-scale chemical processes. In this approach, the chemical process is decomposed into smaller sub-systems at the first level, and a coordinator at the second level, for which a two-level hierarchical control strategy is designed. For this purpose, each sub-system in the first level can be solved separately, by using any conventional optimization algorithm. In the second level, the solutions obtained from the first level are coordinated using a new gradient-type strategy, which is updated by the error of the coordination vector. The proposed algorithm is used to solve the optimal control problem of a complex nonlinear chemical stirred tank reactor (CSTR), where its solution is also compared with the ones obtained using the centralized approach. The simulation results show the efficiency and the capability of the proposed hierarchical approach, in finding the optimal solution, over the centralized method.

  10. Quality Assessment of Film Processing Chemicals in Dentistry

    International Nuclear Information System (INIS)

    Han, Mi Ra; Kang, Byung Chul

    1999-01-01

    The purpose of this study was to compare the qualities of the four different processing chemicals (solutions). With EP 21 films (Ektaspeed plus film, Kodak Co., USA), nine unexposed and nine exposed films of a step wedge were processed utilizing automatic film processor (XR 24, Durr Co., Germany) for 5 days. During 5 days, the total number of processed films including out-patient's intraoral films were about 400-500 for each brand. Base plus fog density, film density, contrast of processed films were measured with densitometer (model 07-443 digital densitometer, Victoreen Co., USA). These measurements were analyzed for comparison. The results were as follows,1. For the base plus fog density, there was significant difference among the four chemicals (p<0.05). The sequence of the base plus fog densities was in ascending order by Kodak, X-dol 90, Agfa and Konica. 2. For the film density, all chemicals showed useful range of photographic densities (0.25-2.5). The sequence of the film densities was in ascending order by Kodak, X-dol 90, Konica and Agfa. But there was no statistically significant difference of film density between X-dol and Kodak (p<0.05). 3. The sequence of the contrasts was in ascending order by Konica, X-dol 90, Kodak and Agfa. But there was no statistically significant difference of contrast between X-dol and Konica (p<0.05). These results indicated that the four processing chemicals had the clinically useful film density and contrast, but only Kodak processing chemical had useful base plus fog density.

  11. Integrating chemical engineering fundamentals in the capstone process design project

    DEFF Research Database (Denmark)

    von Solms, Nicolas; Woodley, John; Johnsson, Jan Erik

    2010-01-01

    Reaction Engineering. In order to incorporate reactor design into process design in a meaningful way, the teachers of the respective courses need to collaborate (Standard 9 – Enhancement of Faculty CDIO skills). The students also see that different components of the chemical engineering curriculum relate......All B.Eng. courses offered at the Technical University of Denmark (DTU) must now follow CDIO standards. The final “capstone” course in the B.Eng. education is Process Design, which for many years has been typical of chemical engineering curricula worldwide. The course at DTU typically has about 30...... of the CDIO standards – especially standard 3 – Integrated Curriculum - means that the course projects must draw on competences provided in other subjects which the students are taking in parallel with Process Design – specifically Process Control and Reaction Engineering. In each semester of the B...

  12. Methods and tools for sustainable chemical process design

    DEFF Research Database (Denmark)

    Loureiro da Costa Lira Gargalo, Carina; Chairakwongsa, Siwanat; Quaglia, Alberto

    2015-01-01

    As the pressure on chemical and biochemical processes to achieve a more sustainable performance increases, the need to define a systematic and holistic way to accomplish this is becoming more urgent. In this chapter, a multilevel computer-aided framework for systematic design of more sustainable...

  13. Application of the chemical properties of ruthenium to decontamination processes

    International Nuclear Information System (INIS)

    Fontaine, A.; Berger, D.

    1965-01-01

    The chemical properties of ruthenium in the form of an aqueous solution of the nitrate and of organic tributylphosphate solution are reviewed. From this data, some known examples are given: they demonstrate the processes of separation or of elimination of ruthenium from radioactive waste. (authors) [fr

  14. Effect of maturity stage and processing on chemical composition, in ...

    African Journals Online (AJOL)

    Effect of maturity stage and processing on chemical composition, in vitro gas production and preference of Panicum maximum and Pennisetum purpureum. ... It is concluded that in order to optimize DM intake farmers should consider the type of grasses and their age at harvest particularly for Muturu. Pelleting improves ...

  15. Physico-chemical, functional and processing attributes of some ...

    African Journals Online (AJOL)

    A study was generated from six commercial potato varieties and studied for their physical, chemical, functional and processing attributes. Lady Rosetta followed by Hermes was the most appreciable varieties concerning their physical attributes. A positive correlation (R = 0.765) existed between tuber firmness and specific ...

  16. Near miss reporting in the chemical process industry: an overview

    NARCIS (Netherlands)

    Schaaf, van der T.W.

    1995-01-01

    The research programme described in this paper focuses on the human component of system failure in general, and more specifically on the design and implementation of information systems for registration and analysis of so called near misses (or: near accidents) in the chemical process industry. Its

  17. Development of Chemical Process Design and Control for Sustainability

    Directory of Open Access Journals (Sweden)

    Shuyun Li

    2016-07-01

    Full Text Available This contribution describes a novel process systems engineering framework that couples advanced control with sustainability evaluation for the optimization of process operations to minimize environmental impacts associated with products, materials and energy. The implemented control strategy combines a biologically-inspired method with optimal control concepts for finding more sustainable operating trajectories. The sustainability assessment of process operating points is carried out by using the U.S. EPA’s Gauging Reaction Effectiveness for the ENvironmental Sustainability of Chemistries with a multi-Objective Process Evaluator (GREENSCOPE tool that provides scores for the selected indicators in the economic, material efficiency, environmental and energy areas. The indicator scores describe process performance on a sustainability measurement scale, effectively determining which operating point is more sustainable if there are more than several steady states for one specific product manufacturing. Through comparisons between a representative benchmark and the optimal steady states obtained through the implementation of the proposed controller, a systematic decision can be made in terms of whether the implementation of the controller is moving the process towards a more sustainable operation. The effectiveness of the proposed framework is illustrated through a case study of a continuous fermentation process for fuel production, whose material and energy time variation models are characterized by multiple steady states and oscillatory conditions.

  18. Development of Chemical Process Design and Control for ...

    Science.gov (United States)

    This contribution describes a novel process systems engineering framework that couples advanced control with sustainability evaluation and decision making for the optimization of process operations to minimize environmental impacts associated with products, materials, and energy. The implemented control strategy combines a biologically inspired method with optimal control concepts for finding more sustainable operating trajectories. The sustainability assessment of process operating points is carried out by using the U.S. E.P.A.’s Gauging Reaction Effectiveness for the ENvironmental Sustainability of Chemistries with a multi-Objective Process Evaluator (GREENSCOPE) tool that provides scores for the selected indicators in the economic, material efficiency, environmental and energy areas. The indicator scores describe process performance on a sustainability measurement scale, effectively determining which operating point is more sustainable if there are more than several steady states for one specific product manufacturing. Through comparisons between a representative benchmark and the optimal steady-states obtained through implementation of the proposed controller, a systematic decision can be made in terms of whether the implementation of the controller is moving the process towards a more sustainable operation. The effectiveness of the proposed framework is illustrated through a case study of a continuous fermentation process for fuel production, whose materi

  19. Chemical Processes Related to Combustion in Fluidised Bed

    Energy Technology Data Exchange (ETDEWEB)

    Steenari, Britt-Marie; Lindqvist, Oliver [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Environmental Inorganic Chemistry

    2002-12-01

    with evaluation of other biomass ash particles and, as an extension, the speciation of Cu and Zn will be studied as well. Ash fractions from combustion of MSW in a BFB boiler have been investigated regarding composition and leaching properties, i.e. environmental impact risks. The release of salts from the cyclone ash fraction can be minimised by the application of a simple washing process, thus securing that the leaching of soluble substances stays within the regulative limits. The MSW ash - water systems contain some interesting chemical issues, such as the interactions between Cr(VI) and reducing substances like Al-metal. The understanding of such chemical processes is important since it gives a possibility to predict effects of a change in ash composition. An even more detailed understanding of interactions between a solution containing ions and particle surfaces can be gained by theoretical modelling. In this project (and with additional unding from Aangpannefoereningens Forskningsstiftelse) a theoretical description of ion-ion interactions and the solid-liquid-interface has been developed. Some related issues are also included in this report. The publication of a paper on the reactions of ammonia in the presence of a calcining limestone surface is one of them. A review paper on the influence of combustion conditions on the properties of fly ash and its applicability as a cement replacement in concrete is another. The licentiate thesis describing the sampling and measurement of Cd in flue gas is also included since it was finalised during the present period. A co-operation project involving the Geology Dept. at Goeteborg Univ. and our group is briefly discussed. This project concerns the utilisation of granules produced from wood ash and dolomite as nutrient source for forest soil. Finally, the plans for our flue gas simulator facility are discussed.

  20. Influence of surface coverage on the chemical desorption process

    Energy Technology Data Exchange (ETDEWEB)

    Minissale, M.; Dulieu, F., E-mail: francois.dulieu@obspm.fr [LERMA, Université de Cergy Pontoise et Observatoire de Paris, UMR 8112 du CNRS. 5, mail Gay Lussac, 95031 Cergy Pontoise (France)

    2014-07-07

    In cold astrophysical environments, some molecules are observed in the gas phase whereas they should have been depleted, frozen on dust grains. In order to solve this problem, astrochemists have proposed that a fraction of molecules synthesized on the surface of dust grains could desorb just after their formation. Recently the chemical desorption process has been demonstrated experimentally, but the key parameters at play have not yet been fully understood. In this article, we propose a new procedure to analyze the ratio of di-oxygen and ozone synthesized after O atoms adsorption on oxidized graphite. We demonstrate that the chemical desorption efficiency of the two reaction paths (O+O and O+O{sub 2}) is different by one order of magnitude. We show the importance of the surface coverage: for the O+O reaction, the chemical desorption efficiency is close to 80% at zero coverage and tends to zero at one monolayer coverage. The coverage dependence of O+O chemical desorption is proved by varying the amount of pre-adsorbed N{sub 2} on the substrate from 0 to 1.5 ML. Finally, we discuss the relevance of the different physical parameters that could play a role in the chemical desorption process: binding energy, enthalpy of formation, and energy transfer from the new molecule to the surface or to other adsorbates.

  1. Optimization of operating parameters in polysilicon chemical vapor deposition reactor with response surface methodology

    Science.gov (United States)

    An, Li-sha; Liu, Chun-jiao; Liu, Ying-wen

    2018-05-01

    In the polysilicon chemical vapor deposition reactor, the operating parameters are complex to affect the polysilicon's output. Therefore, it is very important to address the coupling problem of multiple parameters and solve the optimization in a computationally efficient manner. Here, we adopted Response Surface Methodology (RSM) to analyze the complex coupling effects of different operating parameters on silicon deposition rate (R) and further achieve effective optimization of the silicon CVD system. Based on finite numerical experiments, an accurate RSM regression model is obtained and applied to predict the R with different operating parameters, including temperature (T), pressure (P), inlet velocity (V), and inlet mole fraction of H2 (M). The analysis of variance is conducted to describe the rationality of regression model and examine the statistical significance of each factor. Consequently, the optimum combination of operating parameters for the silicon CVD reactor is: T = 1400 K, P = 3.82 atm, V = 3.41 m/s, M = 0.91. The validation tests and optimum solution show that the results are in good agreement with those from CFD model and the deviations of the predicted values are less than 4.19%. This work provides a theoretical guidance to operate the polysilicon CVD process.

  2. A Study on Safety and Risk Assessment of Dangerous Cargo Operations in Oil/Chemical Tankers

    Directory of Open Access Journals (Sweden)

    Cenk ŞAKAR

    2017-12-01

    Full Text Available The safety and risk assessment of dangerous cargo operations in oil and chemical tankers is a necessary process to prevent possible accidents during these operations. Fire and explosion are the major accidents encountered in tanker operations. In this study, a model was constructed through the Fuzzy Bayes Network Method for the probabilistic relationships between the causes of fire and explosion accidents that could occur during the tank cleaning process. The study is composed of two stages. Firstly, the variables that are the subject of the problem and that constitute the graphical structure of the Bayes Networks are identified. Then, expert opinion was sought as the statistical data on accident reports were not recorded properly while identifying the conditional probability of the relationships between the variables. Linguistic variables whose fuzzy membership functions were identified were used in detecting the probabilities. The findings of the sensitivity test revealed that the major reasons that could lead to fire and explosion during the tank cleaning process are ignition sources, reaction and safety culture.

  3. Numerical Validation of Chemical Compositional Model for Wettability Alteration Processes

    Science.gov (United States)

    Bekbauov, Bakhbergen; Berdyshev, Abdumauvlen; Baishemirov, Zharasbek; Bau, Domenico

    2017-12-01

    Chemical compositional simulation of enhanced oil recovery and surfactant enhanced aquifer remediation processes is a complex task that involves solving dozens of equations for all grid blocks representing a reservoir. In the present work, we perform a numerical validation of the newly developed mathematical formulation which satisfies the conservation laws of mass and energy and allows applying a sequential solution approach to solve the governing equations separately and implicitly. Through its application to the numerical experiment using a wettability alteration model and comparisons with existing chemical compositional model's numerical results, the new model has proven to be practical, reliable and stable.

  4. DYNSIR; A dynamic simulator for the chemical process

    International Nuclear Information System (INIS)

    Park, Hyun Soo; Yoo, Jae Hyung; Byeon, Kee Hoh; Park, Jeong Hwa; Park, Seong Won

    1990-03-01

    A program code for dynamic simulation of arbitrary chemical process, called DYNSIR, is developed. The code can simulate rather arbitrary arrangements of individual chemical processing units whose models are described by ordinary differential equations. The code structure to handle input/output, memory and data management, numerical interactive or predetermined changes in parameter values during the simulation. Individual model is easy to maintain since the modular approach is used. The integration routine is highly effective because of the development of algorithm for modular integration method using the cubic spline. DYNSIR's data structures are not the index but the pointer structure. This pointer structure allows the dynamic memory allocation for the memory management. The dynamic memory allocation methods is to minimize the amount of memories and to overcome the limitation of the number of variables to be used. Finally, it includes various functions, such as the input preprocessor, the effective error processing, and plotting and reporting routines. (author)

  5. Laser isotope separation - a new class of chemical process

    International Nuclear Information System (INIS)

    Woodall, K.B.; Mannik, L.; O'Neill, J.A.; Mader, D.L.; Nickerson, S.B.; Robins, J.R.; Bartoszek, F.E.; Gratton, D.

    1983-01-01

    Lasers may soon find several applications in chemical processing. The applications that have attracted the most research funding to date involve isotope separation for the nuclear industry. These isotopes have an unusually high value (≥$1000/kg) compared to bulk chemicals (∼$1/kg) and are generally required in very large quantities. In a laser isotope separation process, light is used to convert a separation that is very difficult or even impossible by conventional chemical engineering techniques to one that is readily handled by conventional separation technology. For some isotopes this can result in substantial capital and energy savings. A uranium enrichment process developed at the Lawrence Livermore National Laboratory is the closest to commercialization of the large scale laser isotope separation processes. Of particular interest to the Canadian nuclear industry are the laser separation of deuterium, tritium, zirconium-90 and carbon-14. In this paper, the basic principles behind laser isotope separation are reviewed and brief dscriptions of the more developed processes are given

  6. Family of commuting operators for the totally asymmetric exclusion process

    International Nuclear Information System (INIS)

    Golinelli, O; Mallick, K

    2007-01-01

    The algebraic structure underlying the totally asymmetric exclusion process is studied by using the Bethe Ansatz technique. From the properties of the algebra generated by the local jump operators, we explicitly construct the hierarchy of operators (called generalized Hamiltonians) that commute with the Markov operator. The transfer matrix, which is the generating function of these operators, is shown to represent a discrete Markov process with long-range jumps. We give a general combinatorial formula for the connected Hamiltonians obtained by taking the logarithm of the transfer matrix. This formula is proved using a symbolic calculation program for the first ten connected operators

  7. Guide to good practices for operations aspects of unique processes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    This Guide to Good Practices is written to enhance understanding of, and provide direction for, Operations Aspects of Facility Chemistry and Unique Processes, Chapter XIII of Department of Energy (DOE) Order 5480.19, Conduct of Operations Requirements for DOE Facilities. The practices in this guide should be considered when planning or reviewing employee training and facility management programs. Contractors are advised to adopt procedures that meet the intent of DOE Order 5480.19. Operations Aspects of Unique Processes is an element of an effective Conduct of Operations program. The complexity and array of activities performed in DOE facilities dictate the necessity for all personnel to coordinate interrelated activities affecting unique processes.

  8. Development of Flexible Software Process Lines with Variability Operations

    DEFF Research Database (Denmark)

    Dohrmann, Patrick; Schramm, Joachim; Kuhrmann, Marco

    2016-01-01

    the development of flexible software process lines. Method: We conducted a longitudinal study in which we studied 5 variants of the V-Modell XT process line for 2 years. Results: Our results show the variability operation instrument feasible in practice. We analyzed 616 operation exemplars addressing various...

  9. Sustainability assessment of novel chemical processes at early stage: application to biobased processes

    NARCIS (Netherlands)

    Patel, A.D.; Meesters, K.; Uil, H. den; Jong, E. de; Blok, K.; Patel, M.K.

    2012-01-01

    Chemical conversions have been a cornerstone of industrial revolution and societal progress. Continuing this progress in a resource constrained world poses a critical challenge which demands the development of innovative chemical processes to meet our energy and material needs in a sustainable way.

  10. Supercritical Fluids Processing of Biomass to Chemicals and Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Olson, Norman K. [Iowa State Univ., Ames, IA (United States)

    2011-09-28

    The main objective of this project is to develop and/or enhance cost-effective methodologies for converting biomass into a wide variety of chemicals, fuels, and products using supercritical fluids. Supercritical fluids will be used both to perform reactions of biomass to chemicals and products as well as to perform extractions/separations of bio-based chemicals from non-homogeneous mixtures. This work supports the Biomass Program’s Thermochemical Platform Goals. Supercritical fluids are a thermochemical approach to processing biomass that, while aligned with the Biomass Program’s interests in gasification and pyrolysis, offer the potential for more precise and controllable reactions. Indeed, the literature with respect to the use of water as a supercritical fluid frequently refers to “supercritical water gasification” or “supercritical water pyrolysis.”

  11. Study on microwave assisted process in chemical extraction

    International Nuclear Information System (INIS)

    Amer Ali; Rosli Mohd Yunus; Ramlan Abd Aziz

    2001-01-01

    The microwave assisted process is a revolutionary method of extraction that reduces the extraction time to as little as a few seconds, with up to a ten-fold decrease in the use of solvents. The target material is immersed in solvent that is transparent to microwaves, so only the target material is heated, and because of the microwaves tend to heat the inside of the material quickly, the target chemical are expelled in a few seconds. benefits from this process include significant reductions in the amount of energy required and substantial reductions in the cost and dispose of hazardous solvents. A thorough review has been displayed on: using the microwave in extraction, applications of microwave in industry, process flow diagram, mechanism of the process and comparison between microwave process and other extraction techniques (soxhlet, steam distillation and supercritical fluid). This review attempts to summarize the studies about microwave assisted process as a very promising technique. (Author)

  12. Exploring the Use of Design of Experiments in Industrial Processes Operating Under Closed-Loop Control

    DEFF Research Database (Denmark)

    Capaci, Francesca; Kulahci, Murat; Vanhatalo, Erik

    2017-01-01

    Industrial manufacturing processes often operate under closed-loop control, where automation aims to keep important process variables at their set-points. In process industries such as pulp, paper, chemical and steel plants, it is often hard to find production processes operating in open loop....... Instead, closed-loop control systems will actively attempt to minimize the impact of process disturbances. However, we argue that an implicit assumption in most experimental investigations is that the studied system is open loop, allowing the experimental factors to freely affect the important system...... responses. This scenario is typically not found in process industries. The purpose of this article is therefore to explore issues of experimental design and analysis in processes operating under closed-loop control and to illustrate how Design of Experiments can help in improving and optimizing...

  13. Determinants of Operational Efficiency at Chemical Cargo Terminals

    OpenAIRE

    T.A. Gúlcan; S. Esmer; Y. Zorba; G. Şengónúl

    2014-01-01

    In today’s globalized world, one of the requirements of global supply chains is efficient transportation systems. Approximately 80 per cent of world merchandise trade carried by sea and handled by ports worldwide. For this reason, maritime transport has the strategic economic importance. Loading of oil and gas has the biggest share (%30) in commodities carried by sea and 2.9 billion tons oil and gas loaded to ship in 2013. This study is focus on chemical cargo terminals which is a special ter...

  14. Counter-Chemical, Biological, Radiological, and Nuclear Operations

    Science.gov (United States)

    2007-01-26

    operating under the auspices of the PSI intercepted a marine vessel in the Mediterranean Sea on its way from Malaysia to Libya. The ship was...environments where OSHA or applicable AFOSH standards apply, including emergency response to CBRNE incidents in the United States. Also called PPE

  15. Chemical approaches to zero blowdown operation (TP93-05)

    International Nuclear Information System (INIS)

    Geiger, G.E.; Ogg, J.; Hatch, M.R.

    1993-03-01

    Zero blowdown operation was evaluated at a cooling tower at the Stanford Linear Accelerator Center in an attempt to eliminate cooling water discharge. Testing was performed with and without acid feed for pH control using a state-of-the-art treatment which contained polymer, phosphonate, and azole. Supplemental additional of a proprietary calcium carbonate scale inhibitor was also evaluated

  16. Microbiology and atmospheric processes: chemical interactions of primary biological aerosols

    Directory of Open Access Journals (Sweden)

    L. Deguillaume

    2008-07-01

    Full Text Available This paper discusses the influence of primary biological aerosols (PBA on atmospheric chemistry and vice versa through microbiological and chemical properties and processes. Several studies have shown that PBA represent a significant fraction of air particulate matter and hence affect the microstructure and water uptake of aerosol particles. Moreover, airborne micro-organisms, namely fungal spores and bacteria, can transform chemical constituents of the atmosphere by metabolic activity. Recent studies have emphasized the viability of bacteria and metabolic degradation of organic substances in cloud water. On the other hand, the viability and metabolic activity of airborne micro-organisms depend strongly on physical and chemical atmospheric parameters such as temperature, pressure, radiation, pH value and nutrient concentrations. In spite of recent advances, however, our knowledge of the microbiological and chemical interactions of PBA in the atmosphere is rather limited. Further targeted investigations combining laboratory experiments, field measurements, and modelling studies will be required to characterize the chemical feedbacks, microbiological activities at the air/snow/water interface supplied to the atmosphere.

  17. Development of Flexible Software Process Lines with Variability Operations

    DEFF Research Database (Denmark)

    Schramm, Joachim; Dohrmann, Patrick; Kuhrmann, Marco

    2015-01-01

    families of processes and, as part of this, variability operations provide means to modify and reuse pre-defined process assets. Objective: Our goal is to evaluate the feasibility of variability operations to support the development of flexible software process lines. Method: We conducted a longitudinal......Context: Software processes evolve over time and several approaches were proposed to support the required flexibility. Yet, little is known whether these approaches sufficiently support the development of large software processes. A software process line helps to systematically develop and manage...

  18. 40 CFR 723.175 - Chemical substances used in or for the manufacture or processing of instant photographic and peel...

    Science.gov (United States)

    2010-07-01

    ... manufacture and processing in the special production area. All manufacturing, processing, and use operations... shape or design during manufacture, (ii) which has end use function(s) dependent in whole or in part... production area, the ambient air concentration of the new chemical substance during manufacture, processing...

  19. Enhanced teaching and student learning through a simulator-based course in chemical unit operations design

    Science.gov (United States)

    Ghasem, Nayef

    2016-07-01

    This paper illustrates a teaching technique used in computer applications in chemical engineering employed for designing various unit operation processes, where the students learn about unit operations by designing them. The aim of the course is not to teach design, but rather to teach the fundamentals and the function of unit operation processes through simulators. A case study presenting the teaching method was evaluated using student surveys and faculty assessments, which were designed to measure the quality and effectiveness of the teaching method. The results of the questionnaire conclusively demonstrate that this method is an extremely efficient way of teaching a simulator-based course. In addition to that, this teaching method can easily be generalised and used in other courses. A student's final mark is determined by a combination of in-class assessments conducted based on cooperative and peer learning, progress tests and a final exam. Results revealed that peer learning can improve the overall quality of student learning and enhance student understanding.

  20. Materials and fabrication processes for operation in hot hydrogen

    International Nuclear Information System (INIS)

    Tuffias, R.H.; Duffy, A.J.; Arrieta, V.M.; Abrams, W.M.; Benander, R.E.

    1997-01-01

    Operation in hot (2500 endash 3000 K) hydrogen severely limits the choice of structural materials. Rhenium is nonreactive with and has low permeability to hydrogen, and has sufficient strength up to 2800 K. Carbon, in the form of graphite or carbon composites, has excellent high temperature strength but reacts with hydrogen to form methane at a rapid rate above 2000 K. The carbides of zirconium, niobium, hafnium, and tantalum are nonreactive with and have low permeability to hydrogen, but they can be reliably fabricated only in the form of coatings. In order to demonstrate the Integrated Solar Upper Stage (ISUS) solar-thermal propulsion concept, rhenium and rhenium-coated graphite were chosen as the structural materials for the receiver-absorber-converter (RAC) component of the ISUS system. Several methods were investigated for fabricating the rhenium parts and coatings, with chemical vapor deposition (CVD) and Ultramet chosen as the most likely process and company for success. The CVD or rhenium and other refractory materials were thus applied to the ISUS program for fabrication of the RAC subsystem. copyright 1997 American Institute of Physics

  1. Property Modelling for Applications in Chemical Product and Process Design

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    such as database, property model library, model parameter regression, and, property-model based product-process design will be presented. The database contains pure component and mixture data for a wide range of organic chemicals. The property models are based on the combined group contribution and atom...... is missing, the atom connectivity based model is employed to predict the missing group interaction. In this way, a wide application range of the property modeling tool is ensured. Based on the property models, targeted computer-aided techniques have been developed for design and analysis of organic chemicals......, polymers, mixtures as well as separation processes. The presentation will highlight the framework (ICAS software) for property modeling, the property models and issues such as prediction accuracy, flexibility, maintenance and updating of the database. Also, application issues related to the use of property...

  2. Process Control Systems in the Chemical Industry: Safety vs. Security

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey Hahn; Thomas Anderson

    2005-04-01

    Traditionally, the primary focus of the chemical industry has been safety and productivity. However, recent threats to our nation’s critical infrastructure have prompted a tightening of security measures across many different industry sectors. Reducing vulnerabilities of control systems against physical and cyber attack is necessary to ensure the safety, security and effective functioning of these systems. The U.S. Department of Homeland Security has developed a strategy to secure these vulnerabilities. Crucial to this strategy is the Control Systems Security and Test Center (CSSTC) established to test and analyze control systems equipment. In addition, the CSSTC promotes a proactive, collaborative approach to increase industry's awareness of standards, products and processes that can enhance the security of control systems. This paper outlines measures that can be taken to enhance the cybersecurity of process control systems in the chemical sector.

  3. Economic model predictive control theory, formulations and chemical process applications

    CERN Document Server

    Ellis, Matthew; Christofides, Panagiotis D

    2017-01-01

    This book presents general methods for the design of economic model predictive control (EMPC) systems for broad classes of nonlinear systems that address key theoretical and practical considerations including recursive feasibility, closed-loop stability, closed-loop performance, and computational efficiency. Specifically, the book proposes: Lyapunov-based EMPC methods for nonlinear systems; two-tier EMPC architectures that are highly computationally efficient; and EMPC schemes handling explicitly uncertainty, time-varying cost functions, time-delays and multiple-time-scale dynamics. The proposed methods employ a variety of tools ranging from nonlinear systems analysis, through Lyapunov-based control techniques to nonlinear dynamic optimization. The applicability and performance of the proposed methods are demonstrated through a number of chemical process examples. The book presents state-of-the-art methods for the design of economic model predictive control systems for chemical processes. In addition to being...

  4. Chemical process measurements in PWR-type nuclear power plants

    International Nuclear Information System (INIS)

    Glaeser, E.

    1978-01-01

    In order to achieve high levels of availability of nuclear power plants equipped with pressurized water reactors, strict standards have to be applied to the purity of coolant and of other media. Chemical process measurements can meet these requirements only if programmes are established giving maximum information with minimum expenditure and if these programmes are realized with effective analytical methods. Analysis programmes known from literature are proved for their usefulness, and hints are given for establishing rational programmes. Analytical techniques are compared with each other taking into consideration both methods which have already been introduced into nuclear power plant practice and methods not yet generally used in practice, such as atomic absorption spectrophotometry, gas chromatography, etc. Finally, based on the state of the art of chemical process measurements in nuclear power plants, the trends of future development are pointed out. (author)

  5. Global tree network for computing structures enabling global processing operations

    Science.gov (United States)

    Blumrich; Matthias A.; Chen, Dong; Coteus, Paul W.; Gara, Alan G.; Giampapa, Mark E.; Heidelberger, Philip; Hoenicke, Dirk; Steinmacher-Burow, Burkhard D.; Takken, Todd E.; Vranas, Pavlos M.

    2010-01-19

    A system and method for enabling high-speed, low-latency global tree network communications among processing nodes interconnected according to a tree network structure. The global tree network enables collective reduction operations to be performed during parallel algorithm operations executing in a computer structure having a plurality of the interconnected processing nodes. Router devices are included that interconnect the nodes of the tree via links to facilitate performance of low-latency global processing operations at nodes of the virtual tree and sub-tree structures. The global operations performed include one or more of: broadcast operations downstream from a root node to leaf nodes of a virtual tree, reduction operations upstream from leaf nodes to the root node in the virtual tree, and point-to-point message passing from any node to the root node. The global tree network is configurable to provide global barrier and interrupt functionality in asynchronous or synchronized manner, and, is physically and logically partitionable.

  6. Mass Casualty Chemical Incident Operational Framework, Assessment and Best Practices

    Energy Technology Data Exchange (ETDEWEB)

    Greenwalt, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hibbard, W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-08-09

    Emergency response agencies in most US communities are organized, sized, and equipped to manage those emergencies normally expected. Hospitals in particular do not typically have significant excess capacity to handle massive numbers of casualties, as hospital space is an expensive luxury if not needed. Unfortunately this means that in the event of a mass casualty chemical incident the emergency response system will be overwhelmed. This document provides a self-assessment means for emergency managers to examine their response system and identify shortfalls. It also includes lessons from a detailed analysis of five communities: Baltimore, Boise, Houston, Nassau County, and New Orleans. These lessons provide a list of potential critical decisions to allow for pre-planning and a library of best practices that may be helpful in reducing casualties in the event of an incident.

  7. Chemical Processing Department monthly report for April 1958

    Energy Technology Data Exchange (ETDEWEB)

    Warren, J.H.

    1958-05-21

    The separations plants operated on schedule, and Pu production exceeded commitment. UO{sub 3} production and shipments were also ahead of schedule. Purex operation under pseudo two-cycle conditions (elimination of HS and 1A columns, co-decontamination cycle concentrator HCP) was successful. Final U stream was 3{times} lower in Pu than ever before; {gamma} activity in recovered HNO{sub 3} was also low. Four of 6 special E metal batches were processed through Redox and analyzed. Boric acid is removed from solvent extraction process via aq waste. The filter in Task II hydrofluorinator was changed from carbon to Poroloy. Various modifications to equipment were made.

  8. Chemical and mechanical decontamination processes to minimize secondary waste decommissioning

    International Nuclear Information System (INIS)

    Enda, M.; Ichikawa, N.; Yaita, Y.; Kanasaki, T.; Sakai, H.

    2008-01-01

    In the decommissioning of commercial nuclear reactors in Japan, prior to the dismantling of the nuclear power plants, there are plans to use chemical techniques to decontaminate reactor pressure vessels (RPVs), internal parts, primary loop recirculation systems (PLRs), reactor water clean up systems (RWCUs), etc., so as to minimize radiation sources in the materials to be disposed of. After dismantling the nuclear power plants, chemical and mechanical decontamination techniques will then be used to reduce the amounts of radioactive metallic waste. Toshiba Corporation has developed pre-dismantling and post-dismantling decontamination systems. In order to minimize the amounts of secondary waste, the T-OZON process was chosen for decontamination prior to the dismantling of nuclear power plants. Dismantling a nuclear power plant results in large amounts of metallic waste requiring decontamination; for example, about 20,000 tons of such waste is expected to result from the dismantling of a 110 MWe Boiling Water Reactor (BWR). Various decontamination methods have been used on metallic wastes in preparation for disposal in consideration of the complexity of the shapes of the parts and the type of material. The materials in such nuclear power plants are primarily stainless steel and carbon steel. For stainless steel parts having simple shapes, such as plates and pipes, major sources of radioactivity can be removed from the surface of the parts by bipolar electrolysis (electrolyte: H 2 SO 4 ). For stainless steel parts having complicated shapes, such as valves and pumps, major sources of radioactivity can be removed from the surfaces by redox chemical decontamination treatments (chemical agent: Ce(IV)). For carbon steel parts having simple shapes, decontamination by blasting with zirconia grit is effective in removing major sources of radioactivity at the surface, whereas for carbon steel parts having complicated shapes, major sources of radioactivity can be removed from

  9. Chemical Assessment of White Wine during Fermentation Process

    Directory of Open Access Journals (Sweden)

    Teodora Coldea

    2014-05-01

    Full Text Available There were investigated chemical properties of indigenous white wine varieties (Fetească albă, Fetească regală and Galbenă de Odobeşti during fermentation. The white wine making process took place at Wine Pilot Station of University of Agricultural Sciences and Veterinary Medicine Cluj-Napoca. We aimed to monitorize the evolution of fermentation process parameters (temperature, alcohol content, and real extract and the quality of the bottled white wine (total acidity, alcohol content, total sulfur dioxide, total dry extract. The results obtained were in accordance to Romanian Legislation.

  10. The process monitoring computer system an integrated operations and safeguards surveillance system

    International Nuclear Information System (INIS)

    Liester, N.A.

    1995-01-01

    The use of the Process Monitoring Computer System (PMCS) at the Idaho Chemical Processing Plant (ICPP) relating to Operations and Safeguards concerns is discussed. Measures taken to assure the reliability of the system data are outlined along with the measures taken to assure the continuous availability of that data for use within the ICPP. The integration of process and safeguards information for use by the differing organizations is discussed. The PMCS successfully demonstrates the idea of remote Safeguards surveillance and the need for sharing of common information between different support organizations in an operating plant

  11. Metallurgical engineering and inspection practices in the chemical process industries

    International Nuclear Information System (INIS)

    Moller, G.E.

    1987-01-01

    The process industries, in particular the petroleum refining industry, adopted materials engineering and inspection (ME and I) practices years ago and regularly updated them because they were faced with the handling and refining of flammable, toxic, and corrosive feed stocks. These industries have a number of nonproprietary techniques and procedures, some of which may be applicable in the nuclear power generation field. Some specific inspection and engineering techniques used by the process industries within the framework of the guidelines for inspections and worthy of detailed description include the following: (1) sentry drilling or safety drilling of piping subject to relatively uniform corrosion, such as feedwater heater piping, steam piping, and extraction steam piping; (2) on-stream radiography for thickness measurement and detection of unusual conditions - damaged equipment such as valve blockage; (3) critical analysis of the chemical and refining processes for the relative probability of corrosion; (4) communication of valuable experience within the industry; (5) on-stream ultrasonic thickness testing; and (6) on-stream and off-stream crack and flaw detection. The author, trained in the petroleum refining industry but versed in electric utilities, pulp and paper, chemical process, marine, mining, water handling, waste treatment, and geothermal processes, discusses individual practices of these various industries in the paper

  12. Superhydrophobic coatings for aluminium surfaces synthesized by chemical etching process

    Directory of Open Access Journals (Sweden)

    Priya Varshney

    2016-10-01

    Full Text Available In this paper, the superhydrophobic coatings on aluminium surfaces were prepared by two-step (chemical etching followed by coating and one-step (chemical etching and coating in a single step processes using potassium hydroxide and lauric acid. Besides, surface immersion time in solutions was varied in both processes. Wettability and surface morphologies of treated aluminium surfaces were characterized using contact angle measurement technique and scanning electron microscopy, respectively. Microstructures are formed on the treated aluminium surfaces which lead to increase in contact angle of the surface (>150°. Also on increasing immersion time, contact angle further increases due to increase in size and depth of microstructures. Additionally, these superhydrophobic coatings show excellent self-cleaning and corrosion-resistant behavior. Water jet impact, floatation on water surface, and low temperature condensation tests assert the excellent water-repellent nature of coatings. Further, coatings are to be found mechanically, thermally, and ultraviolet stable. Along with, these coatings are found to be excellent regeneration ability as verified experimentally. Although aforesaid both processes generate durable and regenerable superhydrophobic aluminium surfaces with excellent self-cleaning, corrosion-resistant, and water-repellent characteristics, but one-step process is proved more efficient and less time consuming than two-step process and promises to produce superhydrophobic coatings for industrial applications.

  13. Industrial and process furnaces principles, design and operation

    CERN Document Server

    Jenkins, Barrie

    2014-01-01

    Furnaces sit at the core of all branches of manufacture and industry, so it is vital that these are designed and operated safely and effi-ciently. This reference provides all of the furnace theory needed to ensure that this can be executed successfully on an industrial scale. Industrial and Process Furnaces: Principles, 2nd Edition provides comprehensive coverage of all aspects of furnace operation and design, including topics essential for process engineers and operators to better understand furnaces. This includes: the combustion process and its control, furnace fuels, efficiency,

  14. Proton solvation and proton transfer in chemical and electrochemical processes

    International Nuclear Information System (INIS)

    Lengyel, S.; Conway, B.E.

    1983-01-01

    This chapter examines the proton solvation and characterization of the H 3 O + ion, proton transfer in chemical ionization processes in solution, continuous proton transfer in conductance processes, and proton transfer in electrode processes. Topics considered include the condition of the proton in solution, the molecular structure of the H 3 O + ion, thermodynamics of proton solvation, overall hydration energy of the proton, hydration of H 3 O + , deuteron solvation, partial molal entropy and volume and the entropy of proton hydration, proton solvation in alcoholic solutions, analogies to electrons in semiconductors, continuous proton transfer in conductance, definition and phenomenology of the unusual mobility of the proton in solution, solvent structure changes in relation to anomalous proton mobility, the kinetics of the proton-transfer event, theories of abnormal proton conductance, and the general theory of the contribution of transfer reactions to overall transport processes

  15. Application of repetitive pulsed power technology to chemical processing

    International Nuclear Information System (INIS)

    Kaye, R.J.; Hamil, R.

    1995-01-01

    The numerous sites of soil and water contaminated with organic chemicals present an urgent environmental concern that continues to grow. Electron and x-ray irradiation have been shown to be effective methods to destroy a wide spectrum of organic chemicals, nitrates, nitrites, and cyanide in water by breaking molecules to non-toxic products or entirely mineralizing the by-products to gas, water, and salts. Sandia National Laboratories is developing Repetitive High Energy Pulsed Power (RHEPP) technology capable of producing high average power, broad area electron or x-ray beams. The 300 kW RHEPP-II facility accelerates electrons to 2.5 MeV at 25 kA over 1,000 cm 2 in 60 ns pulses at repetition rates of over 100 Hz. Linking this modular treatment capability with the rapid optical-sensing diagnostics and neutral network characterization software algorithms will provide a Smart Waste Treatment (SWaT) system. Such a system would also be applicable for chemical manufacture and processing of industrial waste for reuse or disposal. This talk describes both the HREPP treatment capability and sensing technologies. Measurements of the propagated RHEPP-II beam and dose profiles are presented. Sensors and rapid detection software are discussed with application toward chemical treatment

  16. Use of the LITEE Lorn Manufacturing Case Study in a Senior Chemical Engineering Unit Operations Laboratory

    Science.gov (United States)

    Abraham, Nithin Susan; Abulencia, James Patrick

    2011-01-01

    This study focuses on the effectiveness of incorporating the Laboratory for Innovative Technology and Engineering Education (LITEE) Lorn Manufacturing case into a senior level chemical engineering unit operations course at Manhattan College. The purpose of using the case study is to demonstrate the relevance of ethics to chemical engineering…

  17. Improved management of winter operations to limit subsurface contamination with degradable deicing chemicals in cold regions

    NARCIS (Netherlands)

    French, H.K.; Zee, van der S.E.A.T.M.

    2014-01-01

    This paper gives an overview of management considerations required for better control of deicing chemicals in the unsaturated zone at sites with winter maintenance operations in cold regions. Degradable organic deicing chemicals are the main focus. The importance of the heterogeneity of both the

  18. ACTINIDE REMOVAL PROCESS SAMPLE ANALYSIS, CHEMICAL MODELING, AND FILTRATION EVALUATION

    Energy Technology Data Exchange (ETDEWEB)

    Martino, C.; Herman, D.; Pike, J.; Peters, T.

    2014-06-05

    Filtration within the Actinide Removal Process (ARP) currently limits the throughput in interim salt processing at the Savannah River Site. In this process, batches of salt solution with Monosodium Titanate (MST) sorbent are concentrated by crossflow filtration. The filtrate is subsequently processed to remove cesium in the Modular Caustic Side Solvent Extraction Unit (MCU) followed by disposal in saltstone grout. The concentrated MST slurry is washed and sent to the Defense Waste Processing Facility (DWPF) for vitrification. During recent ARP processing, there has been a degradation of filter performance manifested as the inability to maintain high filtrate flux throughout a multi-batch cycle. The objectives of this effort were to characterize the feed streams, to determine if solids (in addition to MST) are precipitating and causing the degraded performance of the filters, and to assess the particle size and rheological data to address potential filtration impacts. Equilibrium modelling with OLI Analyzer{sup TM} and OLI ESP{sup TM} was performed to determine chemical components at risk of precipitation and to simulate the ARP process. The performance of ARP filtration was evaluated to review potential causes of the observed filter behavior. Task activities for this study included extensive physical and chemical analysis of samples from the Late Wash Pump Tank (LWPT) and the Late Wash Hold Tank (LWHT) within ARP as well as samples of the tank farm feed from Tank 49H. The samples from the LWPT and LWHT were obtained from several stages of processing of Salt Batch 6D, Cycle 6, Batch 16.

  19. Improved management of winter operations to limit subsurface contamination with degradable deicing chemicals in cold regions.

    Science.gov (United States)

    French, Helen K; van der Zee, Sjoerd E A T M

    2014-01-01

    This paper gives an overview of management considerations required for better control of deicing chemicals in the unsaturated zone at sites with winter maintenance operations in cold regions. Degradable organic deicing chemicals are the main focus. The importance of the heterogeneity of both the infiltration process, due to frozen ground and snow melt including the contact between the melting snow cover and the soil, and unsaturated flow is emphasised. In this paper, the applicability of geophysical methods for characterising soil heterogeneity is considered, aimed at modelling and monitoring changes in contamination. To deal with heterogeneity, a stochastic modelling framework may be appropriate, emphasizing the more robust spatial and temporal moments. Examples of a combination of different field techniques for measuring subsoil properties and monitoring contaminants and integration through transport modelling are provided by the SoilCAM project and previous work. Commonly, the results of flow and contaminant fate modelling are quite detailed and complex and require post-processing before communication and advising stakeholders. The managers' perspectives with respect to monitoring strategies and challenges still unresolved have been analysed with basis in experience with research collaboration with one of the case study sites, Oslo airport, Gardermoen, Norway. Both scientific challenges of monitoring subsoil contaminants in cold regions and the effective interaction between investigators and management are illustrated.

  20. Catechol-Based Hydrogel for Chemical Information Processing

    Directory of Open Access Journals (Sweden)

    Eunkyoung Kim

    2017-07-01

    Full Text Available Catechols offer diverse properties and are used in biology to perform various functions that range from adhesion (e.g., mussel proteins to neurotransmission (e.g., dopamine, and mimicking the capabilities of biological catechols have yielded important new materials (e.g., polydopamine. It is well known that catechols are also redox-active and we have observed that biomimetic catechol-modified chitosan films are redox-active and possess interesting molecular electronic properties. In particular, these films can accept, store and donate electrons, and thus offer redox-capacitor capabilities. We are enlisting these capabilities to bridge communication between biology and electronics. Specifically, we are investigating an interactive redox-probing approach to access redox-based chemical information and convert this information into an electrical modality that facilitates analysis by methods from signal processing. In this review, we describe the broad vision and then cite recent examples in which the catechol–chitosan redox-capacitor can assist in accessing and understanding chemical information. Further, this redox-capacitor can be coupled with synthetic biology to enhance the power of chemical information processing. Potentially, the progress with this biomimetic catechol–chitosan film may even help in understanding how biology uses the redox properties of catechols for redox signaling.

  1. A Generic Life Cycle Assessment Tool for Chemical-biochemical Processes

    DEFF Research Database (Denmark)

    Kalakul, Sawitree; Malakul, Pomthong; Siemanond, Kitipat

    2013-01-01

    As environmental impacts and resource depletion are serious concerns for the modern society, they also provide the motivation and need to design processes that are not only economically and operationally feasible, but also environmentally friendly. In this respect, life cycle assessment (LCA......) is a tool for quantifying potential environmental impacts throughout the life cycle of the product or process. It can be used in conjunction with an economic tool to evaluate the design of any existing and/or new chemical-biochemical process and create improvement options in order to arrive at the best...

  2. Real-Time Assessment and Diagnosis of Process Operating Performance

    Directory of Open Access Journals (Sweden)

    Shabnam Sedghi

    2017-04-01

    Full Text Available Over time, the performance of processes may deviate from the initial design due to process variations and uncertainties, making it necessary to develop systematic methods for online optimality assessment based on routine operating process data. Some processes have multiple operating modes caused by the set point change of the critical process variables to achieve different product specifications. On the other hand, the operating region in each operating mode can alter, due to uncertainties. In this paper, we will establish an optimality assessment framework for processes that typically have multi-mode, multi-region operations, as well as transitions between different modes. The kernel density approach for mode detection is adopted and improved for operating mode detection. For online mode detection, the model-based clustering discriminant analysis (MclustDA approach is incorporated with some a priori knowledge of the system. In addition, multi-modal behavior of steady-state modes is tackled utilizing the mixture probabilistic principal component regression (MPPCR method, and dynamic principal component regression (DPCR is used to investigate transitions between different modes. Moreover, a probabilistic causality detection method based on the sequential forward floating search (SFFS method is introduced for diagnosing poor or non-optimum behavior. Finally, the proposed method is tested on the Tennessee Eastman (TE benchmark simulation process in order to evaluate its performance.

  3. Chemical evolution of the Earth: Equilibrium or disequilibrium process?

    Science.gov (United States)

    Sato, M.

    1985-01-01

    To explain the apparent chemical incompatibility of the Earth's core and mantle or the disequilibrium process, various core forming mechanisms have been proposed, i.e., rapid disequilibrium sinking of molten iron, an oxidized core or protocore materials, and meteorite contamination of the upper mantle after separation from the core. Adopting concepts used in steady state thermodynamics, a method is devised for evaluating how elements should distribute stable in the Earth's interior for the present gradients of temperature, pressure, and gravitational acceleration. Thermochemical modeling gives useful insights into the nature of chemical evolution of the Earth without overly speculative assumptions. Further work must be done to reconcile siderophile elements, rare gases, and possible light elements in the outer core.

  4. Field experience with KWU SG chemical cleaning process

    International Nuclear Information System (INIS)

    Odar, S.

    1989-01-01

    The ingress of corrosion products into PWR steam generators (SG's) their deposition and the subsequent concentration of salt impurities can induce a variety of mechanisms for corrosion attack on SG tubing. Already, some plants have had to replace their steam generators due to severe corrosion damage and others are seriously considering the same costly action in the near future. One of the most effective ways to counteract corrosion mechanisms and thus to reduce the likelihood of SG replacement becoming necessary is to clean the SG's and to keep them clean. For many years, the industry has been involved in developing different types of cleaning techniques. Among these, chemical cleaning has been shown to be especially effective. In this article, the KWU chemical cleaning process, for which there is considerable application experience, is described. The results of field applications will be presented together with material compatibility data and information on cleaning effectiveness. (author)

  5. Operational risk assessments by supply chain professionals : process and performance

    NARCIS (Netherlands)

    Tazelaar, F.; Snijders, C.C.P.

    2013-01-01

    We consider the "process-performance paradox" in the assessment of operational risks by professionals in the field of operations and supply chain management (OSCM). The paradox states that although professionals with more expertise tend to decide in different ways, they often do not make better

  6. Discussion of ISV Scenario Scope with Operating Process Element

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yun Goo; Oh, Eungse [Korea Hydro and Nuclear Power Co. ltd. Central Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    NUREG-0711 identifies the sampling dimension of operational conditions which includes normal operation,I and C and HSI failures, transient, and accidents. Because of practical limitation of sampling, ISV scenarios do not include every expected operational condition. To develop a scenario for the ISV, it requires much time and efforts. It takes about 1 month with 3 operating crew team for 7 scenarios for the ISV. Therefore, operational conditions are screened out for integration to scenario. TSV can be used for the evaluation of monitoring, detection, and response implementation about the inventory of information and control. However, validity of operational walkthrough for other operating process element needs to be discussed. For the situation awareness, the general acceptance check list can be derived from the result of representative scenario set of ISV. The check list may contain the number of information, type of information, level of procedure and training program. For the response planning, procedure can be used for evaluation.

  7. Lessons learned from an installation perspective for chemical demilitarization plant start-up at four operating incineration sites.

    Energy Technology Data Exchange (ETDEWEB)

    Motz, L.; Decision and Information Sciences

    2011-02-21

    This study presents the lessons learned by chemical storage installations as they prepared for the start of chemical demilitarization plant operations at the four current chemical incinerator sites in Alabama, Arkansas, Oregon, and Utah. The study included interviews with persons associated with the process and collection of available documents prepared at each site. The goal was to provide useful information for the chemical weapons storage sites in Colorado and Kentucky that will be going through plant start-up in the next few years. The study is not a compendium of what to do and what not to do. The information has been categorized into ten lessons learned; each is discussed individually. Documents that may be useful to the Colorado and Kentucky sites are included in the appendices. This study should be used as a basis for planning and training.

  8. Operating mechanisms of electrolytes in magnesium ion batteries: chemical equilibrium, magnesium deposition, and electrolyte oxidation.

    Science.gov (United States)

    Kim, Dong Young; Lim, Younhee; Roy, Basab; Ryu, Young-Gyoon; Lee, Seok-Soo

    2014-12-21

    Since the early nineties there have been a number of reports on the experimental development of Mg electrolytes based on organo/amide-magnesium chlorides and their transmetalations. However, there are no theoretical papers describing the underlying operating mechanisms of Mg electrolytes, and there is no clear understanding of these mechanisms. We have therefore attempted to clarify the operating mechanisms of Mg electrolytes by studying the characteristics of Mg complexes, solvation, chemical equilibrium, Mg-deposition processes, electrolyte-oxidation processes, and oxidative degradation mechanism of RMgCl-based electrolytes, using ab initio calculations. The formation and solvation energies of Mg complexes highly depend on the characteristics of R groups. Thus, changes in R groups of RMgCl lead to changes in the equilibrium position and the electrochemical reduction and oxidation pathways and energies. We first provide a methodological scheme for calculating Mg reduction potential values in non-aqueous electrolytes and electrochemical windows. We also describe a strategy for designing Mg electrolytes to maximize the electrochemical windows and oxidative stabilities. These results will be useful not only for designing improved Mg electrolytes, but also for developing new electrolytes in the future.

  9. Subfemtosecond directional control of chemical processes in molecules

    Science.gov (United States)

    Alnaser, Ali S.; Litvinyuk, Igor V.

    2017-02-01

    Laser pulses with a waveform-controlled electric field and broken inversion symmetry establish the opportunity to achieve directional control of molecular processes on a subfemtosecond timescale. Several techniques could be used to break the inversion symmetry of an electric field. The most common ones include combining a fundamental laser frequency with its second harmonic or with higher -frequency pulses (or pulse trains) as well as using few-cycle pulses with known carrier-envelope phase (CEP). In the case of CEP, control over chemical transformations, typically occurring on a timescale of many femtoseconds, is driven by much faster sub-cycle processes of subfemtosecond to few-femtosecond duration. This is possible because electrons are much lighter than nuclei and fast electron motion is coupled to the much slower nuclear motion. The control originates from populating coherent superpositions of different electronic or vibrational states with relative phases that are dependent on the CEP or phase offset between components of a two-color pulse. In this paper, we review the recent progress made in the directional control over chemical processes, driven by intense few-cycle laser pulses a of waveform-tailored electric field, in different molecules.

  10. Chemical elements dynamic in the fermentation process of ethanol producing

    International Nuclear Information System (INIS)

    Nepomuceno, N.; Nadai Fernandes, E.A. de; Bacchi, M.A.

    1994-01-01

    This paper provides useful information about the dynamics of chemical elements analysed by instrumental neutron activation analysis (INAA) and, found in the various segments of the fermentation process of producing ethanol from sugar cane. For this, a mass balance of Ce, Co, Cs, Eu, Fe, Hf, La, Sc, Sm, and Th, terrigenous elements, as well as Br, K, Rb, and Zn, sugar cane plant elements, has been demonstrated for the fermentation vats in industrial conditions of ethanol production. (author). 10 refs, 4 figs, 1 tab

  11. Electronic dissipation processes during chemical reactions on surfaces

    CERN Document Server

    Stella, Kevin

    2012-01-01

    Hauptbeschreibung Every day in our life is larded with a huge number of chemical reactions on surfaces. Some reactions occur immediately, for others an activation energy has to be supplied. Thus it happens that though a reaction should thermodynamically run off, it is kinetically hindered. Meaning the partners react only to the thermodynamically more stable product state within a mentionable time if the activation energy of the reaction is supplied. With the help of catalysts the activation energy of a reaction can be lowered. Such catalytic processes on surfaces are widely used in industry. A

  12. An integrated biotechnology platform for developing sustainable chemical processes.

    Science.gov (United States)

    Barton, Nelson R; Burgard, Anthony P; Burk, Mark J; Crater, Jason S; Osterhout, Robin E; Pharkya, Priti; Steer, Brian A; Sun, Jun; Trawick, John D; Van Dien, Stephen J; Yang, Tae Hoon; Yim, Harry

    2015-03-01

    Genomatica has established an integrated computational/experimental metabolic engineering platform to design, create, and optimize novel high performance organisms and bioprocesses. Here we present our platform and its use to develop E. coli strains for production of the industrial chemical 1,4-butanediol (BDO) from sugars. A series of examples are given to demonstrate how a rational approach to strain engineering, including carefully designed diagnostic experiments, provided critical insights about pathway bottlenecks, byproducts, expression balancing, and commercial robustness, leading to a superior BDO production strain and process.

  13. Job training planning and design for process plant operators

    Energy Technology Data Exchange (ETDEWEB)

    Wirstad, J.

    1983-01-01

    A method is presented by which process plant operators for nuclear power plants are trained in Sweden. It works by a top-down method of systems analysis which can be integrated into the analysis, specification, and design of the process automation system. The training methods can also be adapted to existing automation systems and operating schedules. The author's method is based on the principle that training programs should be based on job requirements, e.g. operator tasks in common, less frequent, and rare operating conditions. Procedures have been tested for the following steps: Job analysis, analysis of knowledge and experience required, analysis of operator training requirements, set-up and organisation of the training programme, achievement control, evaluation of the training programme.

  14. Job training planning and design for process plant operators

    International Nuclear Information System (INIS)

    Wirstad, J.

    1983-01-01

    A method is presented by which process plant operators for nuclear power plants are trained in Sweden. It works by a top-down method of systems analysis which can be integrated into the analysis, specification, and design of the process automation system. The training methods can also be adapted to existing automation systems and operating schedules. The author's method is based on the principle that training programs should be based on job requirements, e.g. operator tasks in common, less frequent, and rare operating conditions. Procedures have been tested for the following steps: Job analysis, analysis of knowledge and experience required, analysis of operator training requirements, set-up and organisation of the training programme, achievement control, evaluation of the training programme. (orig./HP) [de

  15. Chemical processes in the turbine and exhaust nozzle

    Energy Technology Data Exchange (ETDEWEB)

    Lukachko, S P; Waitz, I A [Massachusetts Inst. of Tech., Cambridge, MA (United States). Aero-Environmental Lab.; Miake-Lye, R C; Brown, R C; Anderson, M R [Aerodyne Research, Inc., Billerica, MA (United States); Dawes, W N [University Engineering Dept., Cambridge (United Kingdom). Whittle Lab.

    1998-12-31

    The objective is to establish an understanding of primary pollutant, trace species, and aerosol chemical evolution as engine exhaust travels through the nonuniform, unsteady flow fields of the turbine and exhaust nozzle. An understanding of such processes is necessary to provide accurate inputs for plume-wake modeling efforts and is therefore a critical element in an assessment of the atmospheric effects of both current and future aircraft. To perform these studies, a numerical tool was developed combining the calculation of chemical kinetics and one-, two-, or three-dimensional (1-D, 2-D, 3-D) Reynolds-averaged flow equations. Using a chemistry model that includes HO{sub x}, NO{sub y}, SO{sub x}, and CO{sub x} reactions, several 1-D parametric analyses were conducted for the entire turbine and exhaust nozzle flow path of a typical advanced subsonic engine to understand the effects of various flow and chemistry uncertainties on a baseline 1-D result. These calculations were also used to determine parametric criteria for judging 1-D, 2-D, and 3-D modeling requirements as well as to provide information about chemical speciation at the nozzle exit plane. (author) 9 refs.

  16. Chemical processes in the turbine and exhaust nozzle

    Energy Technology Data Exchange (ETDEWEB)

    Lukachko, S.P.; Waitz, I.A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Aero-Environmental Lab.; Miake-Lye, R.C.; Brown, R.C.; Anderson, M.R. [Aerodyne Research, Inc., Billerica, MA (United States); Dawes, W.N. [University Engineering Dept., Cambridge (United Kingdom). Whittle Lab.

    1997-12-31

    The objective is to establish an understanding of primary pollutant, trace species, and aerosol chemical evolution as engine exhaust travels through the nonuniform, unsteady flow fields of the turbine and exhaust nozzle. An understanding of such processes is necessary to provide accurate inputs for plume-wake modeling efforts and is therefore a critical element in an assessment of the atmospheric effects of both current and future aircraft. To perform these studies, a numerical tool was developed combining the calculation of chemical kinetics and one-, two-, or three-dimensional (1-D, 2-D, 3-D) Reynolds-averaged flow equations. Using a chemistry model that includes HO{sub x}, NO{sub y}, SO{sub x}, and CO{sub x} reactions, several 1-D parametric analyses were conducted for the entire turbine and exhaust nozzle flow path of a typical advanced subsonic engine to understand the effects of various flow and chemistry uncertainties on a baseline 1-D result. These calculations were also used to determine parametric criteria for judging 1-D, 2-D, and 3-D modeling requirements as well as to provide information about chemical speciation at the nozzle exit plane. (author) 9 refs.

  17. OPERATIONAL EXPERIENCE: UPGRADED MPC AND A SYSTEMS FOR THE RADIOCHEMICAL PLANT OF THE SIBERIAN CHEMICAL COMBINE

    International Nuclear Information System (INIS)

    RODRIGUEZ, C.; GOLOSKOKOV, I.; FISHBONE, L.; GOODEY, K.; LOOMIS, M.; CRAIN, B. JR.; LARSEN, R.

    2003-01-01

    The success of reducing the risk of nuclear proliferation through physical protection and material control/accounting systems depends upon the development of an effective design that includes consideration of the objectives of the systems and the resources available to implement the design. Included among the objectives of the design are facility characterization, definition of threat, and identification of targets. When considering resources, the designer must consider funds available, rapid low-cost elements, technology elements, human resources, and the availability of resources to sustain operation of the end system. The Siberian Chemical Combine (SCC) is a multi-function nuclear facility located in the Tomsk region of Siberia, Russia. Beginning in 1996, SCC joined with the United States Department of Energy (US/DOE) Material Protection, Control, and Accounting (MPC and A) Program to develop and implement MPC and A upgrades for the Radiochemical, Chemical Metallurgical, Conversion, Uranium Enrichment, and Reactor Plants of the SCC. At the Radiochemical Plant the MPC and A design and implementation process has been largely completed for the Plutonium Storage Facility and related areas of the Radiochemical Plant. Design and implementation of upgrades for the Radiochemical Plant include rapid physical protection upgrades such as bricking up of doors and windows, and installation of security-hardened doors. Rapid material control and accounting upgrades include installation of modern balances and bar code equipment. Comprehensive MPC and A upgrades include the installation of access controls to sensitive areas of the Plant, alarm communication and display (AC and D) systems to detect and annunciate alarm conditions, closed circuit (CCTV) systems to assess alarm conditions, central and secondary alarm station upgrades that enable security forces to assess and respond to alarm conditions, material control and accounting upgrades that include upgraded physical

  18. Application of a hazard and operability study method to hazard evaluation of a chemical unit of the power station.

    Science.gov (United States)

    Habibi, E; Zare, M; Barkhordari, A; Mirmohammadi, Sj; Halvani, Ghh

    2008-12-28

    The aim of this study was to identify the hazards, evaluate their risk factors and determine the measure for promotion of the process and reduction of accidents in the chemical unit of the power station. In this case and qualitative study, HAZOP technique was used to recognize the hazards and problems of operations on the chemical section at power station. Totally, 126 deviations were documented with various causes and consequences. Ranking and evaluation of identified risks indicate that the majority of deviations were categorized as "acceptable" and less than half of that were "unacceptable". The highest calculated risk level (1B) related to both the interruption of acid entry to the discharge pumps and an increased density of the acid. About 27% of the deviations had the lowest risk level (4B). The identification of hazards by HAZOP indicates that it could, systemically, assess and criticize the process of consumption or production of acid and alkali in the chemical unit of power plant.

  19. Improving a Dental School's Clinic Operations Using Lean Process Improvement.

    Science.gov (United States)

    Robinson, Fonda G; Cunningham, Larry L; Turner, Sharon P; Lindroth, John; Ray, Deborah; Khan, Talib; Yates, Audrey

    2016-10-01

    The term "lean production," also known as "Lean," describes a process of operations management pioneered at the Toyota Motor Company that contributed significantly to the success of the company. Although developed by Toyota, the Lean process has been implemented at many other organizations, including those in health care, and should be considered by dental schools in evaluating their clinical operations. Lean combines engineering principles with operations management and improvement tools to optimize business and operating processes. One of the core concepts is relentless elimination of waste (non-value-added components of a process). Another key concept is utilization of individuals closest to the actual work to analyze and improve the process. When the medical center of the University of Kentucky adopted the Lean process for improving clinical operations, members of the College of Dentistry trained in the process applied the techniques to improve inefficient operations at the Walk-In Dental Clinic. The purpose of this project was to reduce patients' average in-the-door-to-out-the-door time from over four hours to three hours within 90 days. Achievement of this goal was realized by streamlining patient flow and strategically relocating key phases of the process. This initiative resulted in patient benefits such as shortening average in-the-door-to-out-the-door time by over an hour, improving satisfaction by 21%, and reducing negative comments by 24%, as well as providing opportunity to implement the electronic health record, improving teamwork, and enhancing educational experiences for students. These benefits were achieved while maintaining high-quality patient care with zero adverse outcomes during and two years following the process improvement project.

  20. Future electro-optical sensors and processing in urban operations

    NARCIS (Netherlands)

    Grönwall, C.; Schwering, P.B.; Rantakokko, J.; Benoist, K.W.; Kemp, R.A.W.; Steinvall, O.; Letalick, D.; Björkert, S.

    2013-01-01

    In the electro-optical sensors and processing in urban operations (ESUO) study we pave the way for the European Defence Agency (EDA) group of Electro-Optics experts (IAP03) for a common understanding of the optimal distribution of processing functions between the different platforms. Combinations of

  1. Design and operation of a continuous integrated monoclonal antibody production process.

    Science.gov (United States)

    Steinebach, Fabian; Ulmer, Nicole; Wolf, Moritz; Decker, Lara; Schneider, Veronika; Wälchli, Ruben; Karst, Daniel; Souquet, Jonathan; Morbidelli, Massimo

    2017-09-01

    The realization of an end-to-end integrated continuous lab-scale process for monoclonal antibody manufacturing is described. For this, a continuous cultivation with filter-based cell-retention, a continuous two column capture process, a virus inactivation step, a semi-continuous polishing step (twin-column MCSGP), and a batch-wise flow-through polishing step were integrated and operated together. In each unit, the implementation of internal recycle loops allows to improve the performance: (a) in the bioreactor, to simultaneously increase the cell density and volumetric productivity, (b) in the capture process, to achieve improved capacity utilization at high productivity and yield, and (c) in the MCSGP process, to overcome the purity-yield trade-off of classical batch-wise bind-elute polishing steps. Furthermore, the design principles, which allow the direct connection of these steps, some at steady state and some at cyclic steady state, as well as straight-through processing, are discussed. The setup was operated for the continuous production of a commercial monoclonal antibody, resulting in stable operation and uniform product quality over the 17 cycles of the end-to-end integration. The steady-state operation was fully characterized by analyzing at the outlet of each unit at steady state the product titer as well as the process (HCP, DNA, leached Protein A) and product (aggregates, fragments) related impurities. © 2017 American Institute of Chemical Engineers Biotechnol. Prog., 33:1303-1313, 2017. © 2017 American Institute of Chemical Engineers.

  2. The constitutive distributed parameter model of multicomponent chemical processes in gas, fluid and solid phase

    International Nuclear Information System (INIS)

    Niemiec, W.

    1985-01-01

    In the literature of distributed parameter modelling of real processes is not considered the class of multicomponent chemical processes in gas, fluid and solid phase. The aim of paper is constitutive distributed parameter physicochemical model, constructed on kinetics and phenomenal analysis of multicomponent chemical processes in gas, fluid and solid phase. The mass, energy and momentum aspects of these multicomponent chemical reactions and adequate phenomena are utilized in balance operations, by conditions of: constitutive invariance for continuous media with space and time memories, reciprocity principle for isotropic and anisotropic nonhomogeneous media with space and time memories, application of definitions of following derivative and equation of continuity, to the construction of systems of partial differential constitutive state equations, in the following derivative forms for gas, fluid and solid phase. Couched in this way all physicochemical conditions of multicomponent chemical processes in gas, fluid and solid phase are new form of constitutive distributed parameter model for automatics and its systems of equations are new form of systems of partial differential constitutive state equations in sense of phenomenal distributed parameter control

  3. Nonlinear model predictive control for chemical looping process

    Science.gov (United States)

    Joshi, Abhinaya; Lei, Hao; Lou, Xinsheng

    2017-08-22

    A control system for optimizing a chemical looping ("CL") plant includes a reduced order mathematical model ("ROM") that is designed by eliminating mathematical terms that have minimal effect on the outcome. A non-linear optimizer provides various inputs to the ROM and monitors the outputs to determine the optimum inputs that are then provided to the CL plant. An estimator estimates the values of various internal state variables of the CL plant. The system has one structure adapted to control a CL plant that only provides pressure measurements in the CL loops A and B, a second structure adapted to a CL plant that provides pressure measurements and solid levels in both loops A, and B, and a third structure adapted to control a CL plant that provides full information on internal state variables. A final structure provides a neural network NMPC controller to control operation of loops A and B.

  4. The operation technology of realtime image processing system (Datacube)

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Jai Wan; Lee, Yong Bum; Lee, Nam Ho; Choi, Young Soo; Park, Soon Yong; Park, Jin Seok

    1997-02-01

    In this project, a Sparc VME-based MaxSparc system, running the solaris operating environment, is selected as the dedicated image processing hardware for robot vision applications. In this report, the operation of Datacube maxSparc system, which is high performance realtime image processing hardware, is systematized. And image flow example programs for running MaxSparc system are studied and analyzed. The state-of-the-arts of Datacube system utilizations are studied and analyzed. For the next phase, advanced realtime image processing platform for robot vision application is going to be developed. (author). 19 refs., 71 figs., 11 tabs.

  5. The application of nuclear energy to the Canadian chemical process industry

    International Nuclear Information System (INIS)

    Robertson, R.F.S.

    1976-03-01

    A study has been made to determine what role nuclear energy, either electrical or thermal, could play in the Canadian chemical process industry. The study was restricted to current-scale CANDU type power reactors. It is concluded that the scale of operation of the chemical industry is rarely large enough to use blocks of electrical power (e) of 500 MW or thermal power (t) of 1500 MW. Thus, with a few predictable exceptions, the role of nuclear energy in the Canadian chemical industry will be as a general thermal/electrical utility supplier, serving a variety of customers in a particular geographic area. This picture would change if nuclear steam generators of 20 to 50 MW(t) become available and are economically competitive. (author)

  6. Challenges in simulation of chemical processes in combustion furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Kilpinen, P. [Aabo Akademi, Turku (Finland)

    1996-12-31

    The presentation gives an introduction to some of the present issues and problems in treating the complex chemical processes in combustion. The focus is in the coupling of the hydrocarbon combustion process with nitrogen oxide formation and destruction chemistry in practical furnaces or flames. Detailed kinetic modelling based on schemes of elementary reactions are shown to be a useful novel tool for identifying and studying the key reaction paths for nitrogen oxide formation and destruction in various systems. The great importance of the interaction between turbulent mixing and combustion chemistry is demonstrated by the sensitivity of both methane oxidation chemistry and fuel nitrogen conversion chemistry to the reactor and mixing pattern chosen for the kinetic calculations. The fluidized bed combustion (FBC) nitrogen chemistry involves several important heterogeneous reactions. Particularly the char in the bed plays an essential role. Recent research has advanced rapidly and the presentation proposes an overall picture of the fuel nitrogen reaction routes in circulating FBC conditions. (author)

  7. Challenges in simulation of chemical processes in combustion furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M; Kilpinen, P [Aabo Akademi, Turku (Finland)

    1997-12-31

    The presentation gives an introduction to some of the present issues and problems in treating the complex chemical processes in combustion. The focus is in the coupling of the hydrocarbon combustion process with nitrogen oxide formation and destruction chemistry in practical furnaces or flames. Detailed kinetic modelling based on schemes of elementary reactions are shown to be a useful novel tool for identifying and studying the key reaction paths for nitrogen oxide formation and destruction in various systems. The great importance of the interaction between turbulent mixing and combustion chemistry is demonstrated by the sensitivity of both methane oxidation chemistry and fuel nitrogen conversion chemistry to the reactor and mixing pattern chosen for the kinetic calculations. The fluidized bed combustion (FBC) nitrogen chemistry involves several important heterogeneous reactions. Particularly the char in the bed plays an essential role. Recent research has advanced rapidly and the presentation proposes an overall picture of the fuel nitrogen reaction routes in circulating FBC conditions. (author)

  8. DYNSYL: a general-purpose dynamic simulator for chemical processes

    International Nuclear Information System (INIS)

    Patterson, G.K.; Rozsa, R.B.

    1978-01-01

    Lawrence Livermore Laboratory is conducting a safeguards program for the Nuclear Regulatory Commission. The goal of the Material Control Project of this program is to evaluate material control and accounting (MCA) methods in plants that handle special nuclear material (SNM). To this end we designed and implemented the dynamic chemical plant simulation program DYNSYL. This program can be used to generate process data or to provide estimates of process performance; it simulates both steady-state and dynamic behavior. The MCA methods that may have to be evaluated range from sophisticated on-line material trackers such as Kalman filter estimators, to relatively simple material balance procedures. This report describes the overall structure of DYNSYL and includes some example problems. The code is still in the experimental stage and revision is continuing

  9. Chemical process for improved oil recovery from Bakken shale

    Energy Technology Data Exchange (ETDEWEB)

    Shuler, Patrick; Tang, Hongxin; Lu, Zayne [ChemEOR Inc (United States); Tang, Youngchun [Power Environmental Energy Research Institute (United States)

    2011-07-01

    This paper presents the new chemically-improved oil recovery process (IOR) process for Bakken formation reservoirs. A custom surfactant agent can be used in standard hydraulic fracturing treatments in the Bakken to increase oil recovery. The rock formation consists of three members: the lower shale, middle dolostone and the upper shale. The dolostone was deposited as a coastal carbonate during shallower water and the shales were deposited in a relatively deep marine condition. With the widespread advent of horizontal well drilling and large-volume hydraulic fracturing treatments, production from the Bakken has become very active. The experimental results exhibited that specialized surfactant formulations will interact with this mixed oil-wet low permeability middle member to produce more oil. It was also observed that oil recovery by spontaneous imbibition was fast and significant. The best surfactant found in this study is compatible with a common fracture fluid system.

  10. Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process

    Directory of Open Access Journals (Sweden)

    H. V. Lee

    2014-01-01

    Full Text Available Lignocellulosic biomass is a complex biopolymer that is primary composed of cellulose, hemicellulose, and lignin. The presence of cellulose in biomass is able to depolymerise into nanodimension biomaterial, with exceptional mechanical properties for biocomposites, pharmaceutical carriers, and electronic substrate’s application. However, the entangled biomass ultrastructure consists of inherent properties, such as strong lignin layers, low cellulose accessibility to chemicals, and high cellulose crystallinity, which inhibit the digestibility of the biomass for cellulose extraction. This situation offers both challenges and promises for the biomass biorefinery development to utilize the cellulose from lignocellulosic biomass. Thus, multistep biorefinery processes are necessary to ensure the deconstruction of noncellulosic content in lignocellulosic biomass, while maintaining cellulose product for further hydrolysis into nanocellulose material. In this review, we discuss the molecular structure basis for biomass recalcitrance, reengineering process of lignocellulosic biomass into nanocellulose via chemical, and novel catalytic approaches. Furthermore, review on catalyst design to overcome key barriers regarding the natural resistance of biomass will be presented herein.

  11. Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process

    Science.gov (United States)

    Lee, H. V.; Hamid, S. B. A.; Zain, S. K.

    2014-01-01

    Lignocellulosic biomass is a complex biopolymer that is primary composed of cellulose, hemicellulose, and lignin. The presence of cellulose in biomass is able to depolymerise into nanodimension biomaterial, with exceptional mechanical properties for biocomposites, pharmaceutical carriers, and electronic substrate's application. However, the entangled biomass ultrastructure consists of inherent properties, such as strong lignin layers, low cellulose accessibility to chemicals, and high cellulose crystallinity, which inhibit the digestibility of the biomass for cellulose extraction. This situation offers both challenges and promises for the biomass biorefinery development to utilize the cellulose from lignocellulosic biomass. Thus, multistep biorefinery processes are necessary to ensure the deconstruction of noncellulosic content in lignocellulosic biomass, while maintaining cellulose product for further hydrolysis into nanocellulose material. In this review, we discuss the molecular structure basis for biomass recalcitrance, reengineering process of lignocellulosic biomass into nanocellulose via chemical, and novel catalytic approaches. Furthermore, review on catalyst design to overcome key barriers regarding the natural resistance of biomass will be presented herein. PMID:25247208

  12. A new method for defining and managing process alarms and for correcting process operation when an alarm occurs

    International Nuclear Information System (INIS)

    Brooks, Robin; Thorpe, Richard; Wilson, John

    2004-01-01

    A new mathematical treatment of alarms that considers them as multi-variable interactions between process variables has provided the first-ever method to calculate values for alarm limits. This has resulted in substantial reductions in false alarms and hence in alarm annunciation rates in field trials. It has also unified alarm management, process control and product quality control into a single mathematical framework so that operations improvement and hence economic benefits are obtained at the same time as increased process safety. Additionally, an algorithm has been developed that advises what changes should be made to Manipulable process variables to clear an alarm. The multi-variable Best Operating Zone at the heart of the method is derived from existing historical data using equation-free methods. It does not require a first-principles process model or an expensive series of process identification experiments. Integral with the method is a new format Process Operator Display that uses only existing variables to fully describe the multi-variable operating space. This combination of features makes it an affordable and maintainable solution for small plants and single items of equipment as well as for the largest plants. In many cases, it also provides the justification for the investments about to be made or already made in process historian systems. Field Trials have been and are being conducted at IneosChlor and Mallinckrodt Chemicals, both in the UK, of the new geometric process control (GPC) method for improving the quality of both process operations and product by providing Process Alarms and Alerts of much high quality than ever before. The paper describes the methods used, including a simple visual method for Alarm Rationalisation that quickly delivers large sets of Consistent Alarm Limits, and the extension to full Alert Management with highlights from the Field Trials to indicate the overall effectiveness of the method in practice

  13. A new method for defining and managing process alarms and for correcting process operation when an alarm occurs

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, Robin [Curvaceous Software Limited, P.O. Box 43, Gerrards Cross, Bucks SL98UX (United Kingdom)]. E-mail: enquiries@curvaceous.com; Thorpe, Richard [Curvaceous Software Limited, P.O. Box 43, Gerrards Cross, Bucks SL98UX (United Kingdom); Wilson, John [Curvaceous Software Limited, P.O. Box 43, Gerrards Cross, Bucks SL98UX (United Kingdom)

    2004-11-11

    A new mathematical treatment of alarms that considers them as multi-variable interactions between process variables has provided the first-ever method to calculate values for alarm limits. This has resulted in substantial reductions in false alarms and hence in alarm annunciation rates in field trials. It has also unified alarm management, process control and product quality control into a single mathematical framework so that operations improvement and hence economic benefits are obtained at the same time as increased process safety. Additionally, an algorithm has been developed that advises what changes should be made to Manipulable process variables to clear an alarm. The multi-variable Best Operating Zone at the heart of the method is derived from existing historical data using equation-free methods. It does not require a first-principles process model or an expensive series of process identification experiments. Integral with the method is a new format Process Operator Display that uses only existing variables to fully describe the multi-variable operating space. This combination of features makes it an affordable and maintainable solution for small plants and single items of equipment as well as for the largest plants. In many cases, it also provides the justification for the investments about to be made or already made in process historian systems. Field Trials have been and are being conducted at IneosChlor and Mallinckrodt Chemicals, both in the UK, of the new geometric process control (GPC) method for improving the quality of both process operations and product by providing Process Alarms and Alerts of much high quality than ever before. The paper describes the methods used, including a simple visual method for Alarm Rationalisation that quickly delivers large sets of Consistent Alarm Limits, and the extension to full Alert Management with highlights from the Field Trials to indicate the overall effectiveness of the method in practice.

  14. A new method for defining and managing process alarms and for correcting process operation when an alarm occurs.

    Science.gov (United States)

    Brooks, Robin; Thorpe, Richard; Wilson, John

    2004-11-11

    A new mathematical treatment of alarms that considers them as multi-variable interactions between process variables has provided the first-ever method to calculate values for alarm limits. This has resulted in substantial reductions in false alarms and hence in alarm annunciation rates in field trials. It has also unified alarm management, process control and product quality control into a single mathematical framework so that operations improvement and hence economic benefits are obtained at the same time as increased process safety. Additionally, an algorithm has been developed that advises what changes should be made to Manipulable process variables to clear an alarm. The multi-variable Best Operating Zone at the heart of the method is derived from existing historical data using equation-free methods. It does not require a first-principles process model or an expensive series of process identification experiments. Integral with the method is a new format Process Operator Display that uses only existing variables to fully describe the multi-variable operating space. This combination of features makes it an affordable and maintainable solution for small plants and single items of equipment as well as for the largest plants. In many cases, it also provides the justification for the investments about to be made or already made in process historian systems. Field Trials have been and are being conducted at IneosChlor and Mallinckrodt Chemicals, both in the UK, of the new geometric process control (GPC) method for improving the quality of both process operations and product by providing Process Alarms and Alerts of much high quality than ever before. The paper describes the methods used, including a simple visual method for Alarm Rationalisation that quickly delivers large sets of Consistent Alarm Limits, and the extension to full Alert Management with highlights from the Field Trials to indicate the overall effectiveness of the method in practice.

  15. Purex process operation and performance, 1970 Thoria Campaign

    International Nuclear Information System (INIS)

    Jackson, R.R.; Walser, R.L.

    1977-03-01

    The Hanford Purex Plant fulfilled a 1970 commitment to the Atomic Energy Commission to produce 360 kilograms of high purity 233 U as uranyl nitrate solution. Overall plant performance during both 1970 and 1966 confirmed the suitability of Purex for processing thorium on a campaign basis. The 1970 processing campaign, including flushing operations, is discussed with particular emphasis on problem areas. Background information on the process and equipment used is also presented. The organizations and their designations described are those existing in 1970

  16. Development of Operational Parameters for Advanced Voloxidation Process at KAERI

    International Nuclear Information System (INIS)

    Lee, Jae Won; Park, J. J.; Shin, J. M.; Yun, Y. W.; Park, G. I.; Lee, J. W.

    2010-10-01

    KAERI has been developing a voloxidation process as a head-end process of pyroprocessing technology with INL (Idaho National Laboratory). The work scope of KAERI is to develop the operation parameters for advanced voloxidation process at KAERI using surrogate materials and SIMFUEL. In order to evaluate operation conditions of an advanced voloxidation process, oxidation and vaporization behavior of metals and Cs compounds was investigated in terms of thermal treatment atmosphere and temperature by using thermodynamic data. And also, the oxidation and vaporization behavior of semi-volatile fission products with process pressure and temperature was investigated using surrogate materials. Particle size control for U 3 O 8 powder was investigated using SIMFUEL and a rotary voloxidizer. According to analysis of KAERI works, the operation conditions for advanced voloxiation process may be consisted of the following four steps: 1) oxidation of UO 2 pellet into U 3 O 8 powder at 500 .deg. C in oxidative atmosphere, 2) additional oxidation of noble metal alloy and vaporization of high vapor pressure of fission products at 700 .deg. C in oxidative atmosphere, 3) granulation of U 3 O 8 powder and vaporization of Cs compounds at 1200 .deg. C in an atmosphere of argon, and 4) reduction of UO 2+x granules into UO 2 granules at 1000 .deg. C in an atmosphere of 4%H 2 -Ar. This report will be used as a useful means for determining the operation parameters for advanced voloxidation process

  17. Sustainable Chemical Processes and Products. New Design Methodology and Design Tools

    OpenAIRE

    Korevaar, G.

    2004-01-01

    The current chemical industry is not sustainable, which leads to the fact that innovation of chemical processes and products is too often hazardous for society in general and the environment in particular. It really is a challenge to implement sustainability considerations in the design activities of chemical engineers. Therefore, the main question of this thesis is: how can a trained chemical engineer develop a conceptual design of a chemical process or a chemical product in such a way that ...

  18. Demining Dogs in Colombia - A Review of Operational Challenges, Chemical Perspectives, and Practical Implications.

    Science.gov (United States)

    Prada, Paola A; Chávez Rodríguez, Mario

    2016-07-01

    Within the framework of an internal armed conflict in Colombia, the use of antipersonnel mines by revolutionary armed forces represents a strategic factor for these groups. Antipersonnel mines are used by these revolutionary forces as a mean to hinder the advancement of the national armed forces in the recovery of territory and to protect tactical natural resources and illegal economies within a given area. These antipersonnel mines and improvised explosive devices (IEDs) are not of industrial manufacturing, and have a variety of activating mechanisms as well as non-metal materials which make them difficult for successful detection. The Colombian experience strongly represents the current need for advanced research and development of effective field operations within its affected territory. Current efforts are focused on a more operational demining perspective in coca cultivation sites in charge of mobile squadrons of eradication (EMCAR) from the National Police of Colombia working towards a future humanitarian demining upon an eventual peace process. The objectives of this review are not only to highlight already existing mine detection methods, but present a special emphasis on the role of mine detection canine teams in the context of this humanitarian issue in Colombia. This review seeks to bring together a description of chemical interactions of the environment with respect to landmine odor signatures, as well as mine detection dog operational perspectives for this specific detection task. The aim is to highlight that given the limited knowledge on the subject, there is a research gap that needs to be attended in order to efficiently establish optimal operating conditions for the reliable performance of mine detection dogs in Colombian demining field applications. Copyright © 2016 The Chartered Society of Forensic Sciences. Published by Elsevier Ireland Ltd. All rights reserved.

  19. Constellation Mission Operation Working Group: ESMO Maneuver Planning Process Review

    Science.gov (United States)

    Moyer, Eric

    2015-01-01

    The Earth Science Mission Operation (ESMO) Project created an Independent Review Board to review our Conjunction Risk evaluation process and Maneuver Planning Process to identify improvements that safely manages mission conjunction risks, maintains ground track science requirements, and minimizes overall hours expended on High Interest Events (HIE). The Review Board is evaluating the current maneuver process which requires support by multiple groups. In the past year, there have been several changes to the processes although many prior and new concerns exist. This presentation will discuss maneuver process reviews and Board comments, ESMO assessment and path foward, ESMO future plans, recent changes and concerns.

  20. Software features and applications in process design, integration and operation

    Energy Technology Data Exchange (ETDEWEB)

    Dhole, V. [Aspen Tech Limited, Warrington (United Kingdom)

    1999-02-01

    Process engineering technologies and tools have evolved rapidly over the last twenty years. Process simulation/modeling, advanced process control, on-line optimisation, production planning and supply chain management are some of the examples of technologies that have rapidly matured from early commercial prototypes and concepts to established tools with significant impact on profitability of process industry today. Process Synthesis or Process Integration (PI) in comparison is yet to create its impact and still remains largely in the domain of few expert users. One of the key reasons as to why PI has not taken off is because the PI tools have not become integral components of the standard process engineering environments. On the last 15 years AspenTech has grown from a small process simulation tool provider to a large multinational company providing a complete suite of process engineering technologies and services covering process design, operation, planning and supply chain management. Throughout this period, AspenTech has acquired experience in rapidly evolving technologies from their early prototype stage to mature products and services. The paper outlines AspenTech`s strategy of integrating PI with other more established process design and operational improvement technologies. The paper illustrates the key elements of AspenTech`s strategy via examples of software development initiatives and services projects. The paper also outlines AspenTech`s future vision of the role of PI in process engineering. (au)

  1. New facility for processing and storage of radioactive and toxic chemical waste

    International Nuclear Information System (INIS)

    Gallagher, F.E. III

    1976-01-01

    A new facility for the processing and storage of radioactive and toxic chemical waste is described. The facility is located in the science and engineering complex of the Santa Barbara campus of the University of California, near the Pacific Ocean. It is designed to provide a safe and secure processing and storage area for hazardous wastes, while meeting the high aesthetic standards and ecological requirements of campus and community regulatory boards. The ventilation system and fire prevention features will be described in detail. During the design phase, a small laboratory was added to provide an area for the radiation protection and industrial hygiene programs. Operational experience with this new facility is discussed

  2. The development of control technologies applied to waste processing operations

    International Nuclear Information System (INIS)

    Grasz, E.; Baker, S.; Couture, S.; Dennison, D.; Holliday, M.; Hurd, R.; Kettering, B.; Merrill, R.; Wilhelmson, K.

    1993-02-01

    Typical waste and residue processes involve some level of human interaction. The risk of exposure to unknown hazardous materials and the potential for radiation contamination provide the impetus for physically separating or removing operators from such processing steps. Technologies that facilitate separation of the operator from potential contamination include glove box robotics; modular systems for remote and automated servicing; and interactive controls that minimize human intervention. Lawrence Livermore National Laboratory (LLNL) is developing an automated system which by design will supplant the operator for glove box tasks, thus affording protection from the risk of radiation exposure and minimizing operator associated waste.This paper describes recent accomplishments in technology development and integration, and outlines the future goals at LLNL for achieving this integrated, interactive control capability

  3. Process Equipment Failure Mode Analysis in a Chemical Industry

    Directory of Open Access Journals (Sweden)

    J. Nasl Seraji

    2008-04-01

    Full Text Available Background and aims   Prevention of potential accidents and safety promotion in chemical processes requires systematic safety management in them. The main objective of this study was analysis of important process equipment components failure modes and effects in H2S and CO2  isolation from extracted natural gas process.   Methods   This study was done in sweetening unit of an Iranian gas refinery. Failure Mode and Effect Analysis (FMEA used for identification of process equipments failures.   Results   Totally 30 failures identified and evaluated using FMEA. P-1 blower's blade breaking and sour gas pressure control valve bearing tight moving had maximum risk Priority number (RPN, P-1 body corrosion and increasing plug lower side angle of reach DEAlevel control valve  in tower - 1 were minimum calculated RPN.   Conclusion   By providing a reliable documentation system for equipment failures and  incidents recording, maintaining of basic information for later safety assessments would be  possible. Also, the probability of failures and effects could be minimized by conducting preventive maintenance.

  4. Bayesian network modeling of operator's state recognition process

    International Nuclear Information System (INIS)

    Hatakeyama, Naoki; Furuta, Kazuo

    2000-01-01

    Nowadays we are facing a difficult problem of establishing a good relation between humans and machines. To solve this problem, we suppose that machine system need to have a model of human behavior. In this study we model the state cognition process of a PWR plant operator as an example. We use a Bayesian network as an inference engine. We incorporate the knowledge hierarchy in the Bayesian network and confirm its validity using the example of PWR plant operator. (author)

  5. Defense Waste Processing Facility radioactive operations -- Part 2, Glass making

    International Nuclear Information System (INIS)

    Carter, J.T.; Rueter, K.J.; Ray, J.W.; Hodoh, O.

    1996-01-01

    The Savannah River Site's Defense Waste Processing Facility (DWPF) near Aiken, SC is the nation's first and world's largest vitrification facility. Following a ten year construction period and nearly 3 year non-radioactive test program, the DWPF began radioactive operations in March, 1996. The results of the first 8 months of radioactive operations are presented. Topics include facility production from waste preparation batching to canister filling

  6. An endothermic chemical process facility coupled to a high temperature reactor. Part I: Proposed accident scenarios within the chemical plant

    International Nuclear Information System (INIS)

    Brown, Nicholas R.; Seker, Volkan; Revankar, Shripad T.; Downar, Thomas J.

    2012-01-01

    Highlights: ► The paper identifies possible transient and accident scenarios in a coupled PBMR and thermochemical sulfur cycle based hydrogen plant. ► Key accidents scenarios were investigated through qualitative reasoning. ► The accidents were found to constitute loss of heat sink event for the nuclear reactor. - Abstract: Hydrogen generation using a high temperature nuclear reactor as a thermal driving vector is a promising future option for energy carrier production. In this scheme, the heat from the nuclear reactor drives an endothermic water-splitting plant, via coupling, through an intermediate heat exchanger. Quantitative study of the possible operational or accident events within the coupled plant is largely absent from the literature. In this paper, seven unique case studies are proposed based on a thorough review of possible events. The case studies are: (1) feed flow failure from one section of the chemical plant to another with an accompanying parametric study of the temperature in an individual reaction chamber, (2) product flow failure (recycle) within the chemical plant, (3) rupture or explosion within the chemical plant, (4) nuclear reactor helium inlet overcooling due to a process holding tank failure, (5) helium inlet overcooling as an anticipated transient without emergency nuclear reactor shutdown, (6) total failure of the chemical plant, (7) control rod insertion in the nuclear reactor. The qualitative parameters of each case study are outlined as well as the basis in literature. A previously published modeling scheme is described and adapted for application as a simulation platform for these transient events. The results of the quantitative case studies are described within part II of this paper.

  7. Use of safety analysis results to support process operation

    International Nuclear Information System (INIS)

    Karvonen, I.; Heino, P.

    1990-01-01

    Safety and risk analysis carried out during the design phase of a process plant produces useful knowledge about the behavior and the disturbances of the system. This knowledge, however, often remains to the designer though it would be of benefit to the operators and supervisors of the process plant, too. In Technical Research Centre of Finland a project has been started to plan and construct a prototype of an information system to make use of the analysis knowledge during the operation phase. The project belongs to a Nordic KRM project (Knowledge Based Risk Management System). The information system is planned to base on safety and risk analysis carried out during the design phase and completed with operational experience. The safety analysis includes knowledge about potential disturbances, their causes and consequences in the form of Hazard and Operability Study, faut trees and/or event trees. During the operation disturbances can however, occur, which are not included in the safety analysis, or the causes or consequences of which have been incompletely identified. Thus the information system must also have an interface for the documentation of the operational knowledge missing from the analysis results. The main tasks off the system when supporting the management of a disturbance are to identify it (or the most important of the coexistent ones) from the stored knowledge and to present it in a proper form (for example as a deviation graph). The information system may also be used to transfer knowledge from one shift to another and to train process personnel

  8. The Characterization of Cognitive Processes Involved in Chemical Kinetics Using a Blended Processing Framework

    Science.gov (United States)

    Bain, Kinsey; Rodriguez, Jon-Marc G.; Moon, Alena; Towns, Marcy H.

    2018-01-01

    Chemical kinetics is a highly quantitative content area that involves the use of multiple mathematical representations to model processes and is a context that is under-investigated in the literature. This qualitative study explored undergraduate student integration of chemistry and mathematics during problem solving in the context of chemical…

  9. Feasibility study of sulfates as oxygen carriers for chemical looping processes

    Directory of Open Access Journals (Sweden)

    Ganesh Kale

    2012-12-01

    Full Text Available The operational feasibility temperature range of chemical looping combustion (CLC and chemical looping reforming (CLR of the fuels methane, propane, iso-octane and ethanol was explored using the common sulphates

  10. Modeling the high-temperature gas-cooled reactor process heat plant: a nuclear to chemical conversion process

    International Nuclear Information System (INIS)

    Pfremmer, R.D.; Openshaw, F.L.

    1982-05-01

    The high-temperature heat available from the High-Temperature Gas-Cooled Reactor (HTGR) makes it suitable for many process applications. One of these applications is a large-scale energy production plant where nuclear energy is converted into chemical energy and stored for industrial or utility applications. This concept combines presently available nuclear HTGR technology and energy conversion chemical technology. The design of this complex plant involves questions of interacting plant dynamics and overall plant control. This paper discusses how these questions were answered with the aid of a hybrid computer model that was developed within the time-frame of the conceptual design studies. A brief discussion is given of the generally good operability shown for the plant and of the specific potential problems and their anticipated solution. The paper stresses the advantages of providing this information in the earliest conceptual phases of the design

  11. Features of radiation chemical processes in ethylene-styrene copolymers

    International Nuclear Information System (INIS)

    Leshchenko, S.S.; Mal'tseva, A.P.; Iskakov, L.I.; Karpov, V.L.

    1976-01-01

    A study was made of statistical copolymers of ethylene with styrene to determine their structure and properties and radio-chemical transformations. The styrene content of the copolymers ranged from 1 to 85 mole%. The investigation covered non-irradiated copolymers and those irradiated with doses of 1-1000Mrad at room temperature and at liquid nitrogen temperature. It is shown that styrene units present in the CES inhibited all radio-chemical processes compared with PE irradiated under similar conditions. It is suggested that the radiation resistance of CES with styrene contents up to 10 mole % increases in the course of irradiation as a result of the formation of structures with a high degree of conjugation which are more capable of scattering absorbed energy than in the case of phenyl rings by themselves. The most promising of the CES examined is the one with a styrene content of 5 mole %. The mechanical properties of this copolymer are similar to those of PE, and its radiation resistance rises under service conditions in the presence of ionizing radiation

  12. Business process re-engineering in service operations

    International Nuclear Information System (INIS)

    McClintock, J.W.

    1995-01-01

    The concept of business process re-engineering, and how it was applied to the operations of the Consumers Gas Company were discussed. Business process re-engineering was defined as the improvement of the efficiency of the customer-service process, and the overall improvement of practices and operations. The re-engineering project was said to involve a thorough analysis of information technology, current limitations, and business operational needs, undertaken on an enterprise-wide basis. Viewed generically,a re-engineering project was said to have six major components: (1) business drivers (i.e. the articulation of the Company's strategic issues); (2) benchmark measures; (3) future state process models; (4) cost/benefit analysis; (5) a change management plan; and (6) a development plan. Business improvements expected to result from the project include reduced cost of operation, reduction of waste, and a substantially complete re-design of the business process. Management of the project involved a team approach, and help of a consultant to identify the scope of the re-design, its limitations, and future state. A life expectancy of approximately 10 years was given for the re-engineering plan, with annual benefits (in terms of cost reduction) of $4.6 million by the year 2000

  13. Chemical and radiolytical solvent degradation in the Purex process

    International Nuclear Information System (INIS)

    Stieglitz, L.; Becker, R.

    1985-01-01

    The state of the art of chemical and radiolytical solvent degradation is described. For the hydrolysis of tributylphosphate TBP->HDBP->H 2 MBP->H 3 PO 4 values are given for the individual constants in a temperature range from 23 to 90 0 C. Radiolytic yields were measured for HDBP as 80 mg/Wh, for H 2 MBP as 2 mg/Wh, and for H 3 PO 4 as 5 mg/Wh. Experimental results on the degradation products of the diluent are summarized and their influence on the process is discussed. Long chain acid phosphates and acid TBP oligomeres were identified as responsible for the retention of fission products. Techniques such as polarography, infrared spectrometry and electrolytic conductometry are applied to estimate concentrations of degradation products down to 10 -5 mol/l. (orig.) [de

  14. Chemical and radiolytical solvent degradation in the Purex process

    Energy Technology Data Exchange (ETDEWEB)

    Stieglitz, L; Becker, R

    1985-01-01

    The state of the art of chemical and radiolytical solvent degradation is described. For the hydrolysis of tributylphosphate TBP->HDBP->H/sub 2/MBP->H/sub 3/PO/sub 4/ values are given for the individual constants in a temperature range from 23 to 90/sup 0/C. Radiolytic yields were measured for HDBP as 80 mg/Wh, for H/sub 2/MBP as 2 mg/Wh, and for H/sub 3/PO/sub 4/ as 5 mg/Wh. Experimental results on the degradation products of the diluent are summarized and their influence on the process is discussed. Long chain acid phosphates and acid TBP oligomeres were identified as responsible for the retention of fission products. Techniques such as polarography, infrared spectrometry and electrolytic conductometry are applied to estimate concentrations of degradation products down to 10/sup -5/ mol/l.

  15. Application of large radiation sources in chemical processing industry

    International Nuclear Information System (INIS)

    Krishnamurthy, K.

    1977-01-01

    Large radiation sources and their application in chemical processing industry are described. A reference has also been made to the present developments in this field in India. Radioactive sources, notably 60 Co, are employed in production of wood-plastic and concrete-polymer composites, vulcanised rubbers, polymers, sulfochlorinated paraffin hydrocarbons and in a number of other applications which require deep penetration and high reliability of source. Machine sources of electrons are used in production of heat shrinkable plastics, insulation materials for cables, curing of paints etc. Radiation sources have also been used for sewage hygienisation. As for the scene in India, 60 Co sources, gamma chambers and batch irradiators are manufactured. A list of the on-going R and D projects and organisations engaged in research in this field is given. (M.G.B.)

  16. Radon: Chemical and physical processes associated with its distribution

    International Nuclear Information System (INIS)

    Castleman, A.W. Jr.

    1992-01-01

    Assessing the mechanisms which govern the distribution, fate, and pathways of entry into biological systems, as well as the ultimate hazards associated with the radon progeny and their secondary reaction products, depends on knowledge of their chemistry. Our studies are directed toward developing fundamental information which will provide a basis for modeling studies that are requisite in obtaining a complete picture of growth, attachment to aerosols, and transport to the bioreceptor and ultimate incorporation within. Our program is divided into three major areas of research. These include measurement of the determination of their mobilities, study of the role of radon progeny ions in affecting reactions, including study of the influence of the degree of solvation (clustering), and examination of the important secondary reaction products, with particular attention to processes leading to chemical conversion of either the core ions or the ligands as a function of the degree of clustering

  17. Chemical Reactions in the Processing of Mosi2 + Carbon Compacts

    Science.gov (United States)

    Jacobson, Nathan S.; Lee, Kang N.; Maloy, Stuart A.; Heuer, Arthur H.

    1993-01-01

    Hot-pressing of MoSi2 powders with carbon at high temperatures reduces the siliceous grain boundary phase in the resultant compact. The chemical reactions in this process were examined using the Knudsen cell technique. A 2.3 wt pct oxygen MoSi2 powder and a 0.59 wt pct oxygen MoSi2 powder, both with additions of 2 wt pct carbon, were examined. The reduction of the siliceous grain boundary phase was examined at 1350 K and the resultant P(SiO)/P(CO) ratios interpreted in terms of the SiO(g) and CO(g) isobars on the Si-C-O predominance diagram. The MoSi2 + carbon mixtures were then heated at the hot-pressing temperature of 2100 K. Large weight losses were observed and could be correlated with the formation of a low-melting eutectic and the formation and vaporization of SiC.

  18. Review on Physicochemical, Chemical, and Biological Processes for Pharmaceutical Wastewater

    Science.gov (United States)

    Li, Zhenchen; Yang, Ping

    2018-02-01

    Due to the needs of human life and health, pharmaceutical industry has made great progress in recent years, but it has also brought about severe environmental problems. The presence of pharmaceuticals in natural waters which might pose potential harm to the ecosystems and humans raised increasing concern worldwide. Pharmaceuticals cannot be effectively removed by conventional wastewater treatment plants (WWTPs) owing to the complex composition, high concentration of organic contaminants, high salinity and biological toxicity of pharmaceutical wastewater. Therefore, the development of efficient methods is needed to improve the removal effect of pharmaceuticals. This review provides an overview on three types of treatment technologies including physicochemical, chemical and biological processes and their advantages and disadvantages respectively. In addition, the future perspectives of pharmaceutical wastewater treatment are given.

  19. A Perspective on PSE in Fermentation Process Development and Operation

    DEFF Research Database (Denmark)

    Gernaey, Krist

    2015-01-01

    Compared to the chemical industry, the use of PSE methods and tools is not as widespread in industrial fermentation processes. This paper gives an overview of some of the main engineering challenges in industrial fermentation processes. Furthermore, a number of mathematical models are highlighted...... as examples of PSE methods and tools that are used in the context of industrial fermentation technology. Finally, it is discussed what could be done to increase the future use of PSE methods and tools within the industrial fermentation technology area....

  20. The Valduc waste incineration facility starts operations (iris process)

    International Nuclear Information System (INIS)

    Chateauvieux, H.; Guiberteuau, P.; Longuet, T.; Lannaud, J.; Lorich, M.

    1998-01-01

    In the operation of its facilities the Valduc Research Center produces alpha-contaminated solid waste and thus decided to build an incineration facility to treat the most contaminated combustible waste. The process selected for waste incineration is the IRIS process developed by the CEA at the Marcoule Nuclear Research Center. The Valduc Center asked SGN to build the incineration facility. The facility was commissioned in late 1996, and inactive waste incineration campaigns were run in 1997. The operator conducted tests with calibrated radioactive sources to qualify the systems for measuring holdup of active material from outside the equipment. Chlorinated waste incineration test runs were performed using the phosphatizing process developed by the Marcoule Research Center. Inspections performed after these incineration runs revealed the complete absence of corrosion in the equipment. Active commissioning of the facility is scheduled for mid-1998. The Valduc incinerator is the first industrial application of the IRIS process. (author)

  1. Modeling and optimization of CO2 capture processes by chemical absorption

    International Nuclear Information System (INIS)

    Neveux, Thibaut

    2013-01-01

    CO 2 capture processes by chemical absorption lead to a large energy penalty on efficiency of coal-fired power plants, establishing one of the main bottleneck to its industrial deployment. The objective of this thesis is the development and validation of a global methodology, allowing the precise evaluation of the potential of a given amine capture process. Characteristic phenomena of chemical absorption have been thoroughly studied and represented with state-of-the-art models. The e-UNIQUAC model has been used to describe vapor-liquid and chemical equilibria of electrolyte solutions and the model parameters have been identified for four solvents. A rate-based formulation has been adopted for the representation of chemically enhanced heat and mass transfer in columns. The absorption and stripping models have been successfully validated against experimental data from an industrial and a laboratory pilot plants. The influence of the numerous phenomena has been investigated in order to highlight the most limiting ones. A methodology has been proposed to evaluate the total energy penalty resulting from the implementation of a capture process on an advanced supercritical coal-fired power plant, including thermal and electric consumptions. Then, the simulation and process evaluation environments have been coupled with a non-linear optimization algorithm in order to find optimal operating and design parameters with respect to energetic and economic performances. This methodology has been applied to optimize five process flow schemes operating with an monoethanolamine aqueous solution at 30% by weight: the conventional flow scheme and four process modifications. The performance comparison showed that process modifications using a heat pump effect give the best gains. The use of technical-economic analysis as an evaluation criterion of a process performance, coupled with a optimization algorithm, has proved its capability to find values for the numerous operating and design

  2. Improving operational anodising process performance using simulation approach

    International Nuclear Information System (INIS)

    Liong, Choong-Yeun; Ghazali, Syarah Syahidah

    2015-01-01

    The use of aluminium is very widespread, especially in transportation, electrical and electronics, architectural, automotive and engineering applications sectors. Therefore, the anodizing process is an important process for aluminium in order to make the aluminium durable, attractive and weather resistant. This research is focused on the anodizing process operations in manufacturing and supplying of aluminium extrusion. The data required for the development of the model is collected from the observations and interviews conducted in the study. To study the current system, the processes involved in the anodizing process are modeled by using Arena 14.5 simulation software. Those processes consist of five main processes, namely the degreasing process, the etching process, the desmut process, the anodizing process, the sealing process and 16 other processes. The results obtained were analyzed to identify the problems or bottlenecks that occurred and to propose improvement methods that can be implemented on the original model. Based on the comparisons that have been done between the improvement methods, the productivity could be increased by reallocating the workers and reducing loading time

  3. Improving operational anodising process performance using simulation approach

    Energy Technology Data Exchange (ETDEWEB)

    Liong, Choong-Yeun, E-mail: lg@ukm.edu.my; Ghazali, Syarah Syahidah, E-mail: syarah@gapps.kptm.edu.my [School of Mathematical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor DE (Malaysia)

    2015-10-22

    The use of aluminium is very widespread, especially in transportation, electrical and electronics, architectural, automotive and engineering applications sectors. Therefore, the anodizing process is an important process for aluminium in order to make the aluminium durable, attractive and weather resistant. This research is focused on the anodizing process operations in manufacturing and supplying of aluminium extrusion. The data required for the development of the model is collected from the observations and interviews conducted in the study. To study the current system, the processes involved in the anodizing process are modeled by using Arena 14.5 simulation software. Those processes consist of five main processes, namely the degreasing process, the etching process, the desmut process, the anodizing process, the sealing process and 16 other processes. The results obtained were analyzed to identify the problems or bottlenecks that occurred and to propose improvement methods that can be implemented on the original model. Based on the comparisons that have been done between the improvement methods, the productivity could be increased by reallocating the workers and reducing loading time.

  4. Improving operational anodising process performance using simulation approach

    Science.gov (United States)

    Liong, Choong-Yeun; Ghazali, Syarah Syahidah

    2015-10-01

    The use of aluminium is very widespread, especially in transportation, electrical and electronics, architectural, automotive and engineering applications sectors. Therefore, the anodizing process is an important process for aluminium in order to make the aluminium durable, attractive and weather resistant. This research is focused on the anodizing process operations in manufacturing and supplying of aluminium extrusion. The data required for the development of the model is collected from the observations and interviews conducted in the study. To study the current system, the processes involved in the anodizing process are modeled by using Arena 14.5 simulation software. Those processes consist of five main processes, namely the degreasing process, the etching process, the desmut process, the anodizing process, the sealing process and 16 other processes. The results obtained were analyzed to identify the problems or bottlenecks that occurred and to propose improvement methods that can be implemented on the original model. Based on the comparisons that have been done between the improvement methods, the productivity could be increased by reallocating the workers and reducing loading time.

  5. SPARO - A system for process analysis of refinery operations

    Energy Technology Data Exchange (ETDEWEB)

    Kesler, M.G.; Graham, J.; Weissbrod, J.

    1987-01-01

    SPARO is a customized process simulator for the PC, designed to review as well as to guide operations of hydrocarbon processing units. It can be applied to: gas plants or refinery gas recovery units; crude/vacuum towers with associated heat exchange; light ends units, such as reforming, alkylation and isomerization; fractionation and heat exchange units of Ethylene plants; aromatics and styrene units, and others. The main uses of SPARO are discussed in this paper.

  6. Three essential management processes of nuclear power plant operators

    International Nuclear Information System (INIS)

    Qi Tunfeng

    2010-01-01

    The paper takes the operation and management of Qinshan NPP Phase II as an example, focusing on the implementation of the essential process from the following three aspects the NPP production organization, training, examination and authorization for safety-related personnel, and financing budge management. A better understanding and implementation of the essential process will enable nuclear power plants to effectively control the nuclear safety from the most fundamental managerial level. (author)

  7. Mockup testing of remote systems for zirconium fuel dissolution process at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Paige, D.M.

    1979-01-01

    A facility is being constructed at the Idaho National Engineering Laboratory for storage and dissolution of spent zirconium reactor fuels. The dissolution is carried out in chemical type equipment contained in a large shielded cell. The design provides for remote operations and maintenance as required. Equipment predicted to fail within 5 years is designed for remote maintenance. Each system was fabricated for mockup testing using readily available materials. The mockups were tested, redesigned, and retested until satisfactory remote designs were achieved. Records were made of all the work. All design changes were then incorporated into the ongoing detailed design for the actual equipment. Several of these systems are discussed and they include valve replacement, pump replacement, waste solids handling, mechanism operations and others. The mockup program has saved time and money by eliminating many future problems. In addition, the mockup program will continue through construction, cold startup, and hot operations

  8. Development Of Chemical Reduction And Air Stripping Processes To Remove Mercury From Wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, Dennis G.; Looney, Brian B.; Craig, Robert R.; Thompson, Martha C.; Kmetz, Thomas F.

    2013-07-10

    This study evaluates the removal of mercury from wastewater using chemical reduction and air stripping using a full-scale treatment system at the Savannah River Site. The existing water treatment system utilizes air stripping as the unit operation to remove organic compounds from groundwater that also contains mercury (C ~ 250 ng/L). The baseline air stripping process was ineffective in removing mercury and the water exceeded a proposed limit of 51 ng/L. To test an enhancement to the existing treatment modality a continuous dose of reducing agent was injected for 6-hours at the inlet of the air stripper. This action resulted in the chemical reduction of mercury to Hg(0), a species that is removable with the existing unit operation. During the injection period a 94% decrease in concentration was observed and the effluent satisfied proposed limits. The process was optimized over a 2-day period by sequentially evaluating dose rates ranging from 0.64X to 297X stoichiometry. A minimum dose of 16X stoichiometry was necessary to initiate the reduction reaction that facilitated the mercury removal. Competing electron acceptors likely inhibited the reaction at the lower 1 doses, which prevented removal by air stripping. These results indicate that chemical reduction coupled with air stripping can effectively treat large-volumes of water to emerging part per trillion regulatory standards for mercury.

  9. The modelling of dynamic chemical state of paper machine unit operations; Dynaamisen kemiallisen tilan mallintaminen paperikoneen yksikkoeoperaatioissa - MPKT 04

    Energy Technology Data Exchange (ETDEWEB)

    Ylen, J P; Jutila, P [Helsinki Univ. of Technology, Otaniemi (Finland)

    1999-12-31

    The chemical state of paper mass is considered to be a key factor to the smooth operation of the paper machine. There are simulators that have been developed either for dynamic energy and mass balances or for static chemical phenomena, but the combination of these is not a straight forward task. Control Engineering Laboratory of Helsinki University of Technology has studied the paper machine wet end phenomena with the emphasis on pH-modelling. VTT (Technical Research Centre of Finland) Process Physics has used thermodynamical modelling successfully in e.g. Bleaching processes. In this research the different approaches are combined in order to get reliable dynamical models and modelling procedures for various unit operations. A flexible pilot process will be constructed and different materials will be processed starting from simple inorganic substances (e.g. Calcium carbonate and distilled water) working towards more complex masses (thick pulp with process waters and various reagents). The pilot process is well instrumented with ion selective electrodes, total calcium analysator and all basic measurements. (orig.)

  10. The modelling of dynamic chemical state of paper machine unit operations; Dynaamisen kemiallisen tilan mallintaminen paperikoneen yksikkoeoperaatioissa - MPKT 04

    Energy Technology Data Exchange (ETDEWEB)

    Ylen, J.P.; Jutila, P. [Helsinki Univ. of Technology, Otaniemi (Finland)

    1998-12-31

    The chemical state of paper mass is considered to be a key factor to the smooth operation of the paper machine. There are simulators that have been developed either for dynamic energy and mass balances or for static chemical phenomena, but the combination of these is not a straight forward task. Control Engineering Laboratory of Helsinki University of Technology has studied the paper machine wet end phenomena with the emphasis on pH-modelling. VTT (Technical Research Centre of Finland) Process Physics has used thermodynamical modelling successfully in e.g. Bleaching processes. In this research the different approaches are combined in order to get reliable dynamical models and modelling procedures for various unit operations. A flexible pilot process will be constructed and different materials will be processed starting from simple inorganic substances (e.g. Calcium carbonate and distilled water) working towards more complex masses (thick pulp with process waters and various reagents). The pilot process is well instrumented with ion selective electrodes, total calcium analysator and all basic measurements. (orig.)

  11. PWR steam generator chemical cleaning. Phase I: solvent and process development. Volume II

    International Nuclear Information System (INIS)

    Larrick, A.P.; Paasch, R.A.; Hall, T.M.; Schneidmiller, D.

    1979-01-01

    A program to demonstrate chemical cleaning methods for removing magnetite corrosion products from the annuli between steam generator tubes and the tube support plates in vertical U-tube steam generators is described. These corrosion products have caused steam generator tube ''denting'' and in some cases have caused tube failures and support plate cracking in several PWR generating plants. Laboratory studies were performed to develop a chemical cleaning solvent and application process for demonstration cleaning of the Indian Point Unit 2 steam generators. The chemical cleaning solvent and application process were successfully pilot-tested by cleaning the secondary side of one of the Indian Point Unit 1 steam generators. Although the Indian Point Unit 1 steam generators do not have a tube denting problem, the pilot test provided for testing of the solvent and process using much of the same equipment and facilities that would be used for the Indian Point Unit 2 demonstration cleaning. The chemical solvent selected for the pilot test was an inhibited 3% citric acid-3% ascorbic acid solution. The application process, injection into the steam generator through the boiler blowdown system and agitation by nitrogen sparging, was tested in a nuclear environment and with corrosion products formed during years of steam generator operation at power. The test demonstrated that the magnetite corrosion products in simulated tube-to-tube support plate annuli can be removed by chemical cleaning; that corrosion resulting from the cleaning is not excessive; and that steam generator cleaning can be accomplished with acceptable levels of radiation exposure to personnel

  12. Industrial applications for remote operation in a processing plant

    International Nuclear Information System (INIS)

    Hermier, J.; Le Guennec, R.

    1984-01-01

    In the first part of this article, J. Hermier covers the use of remote handling equipment in the UP2-400 plant at La Hague near Cherbourg, in which for the most part master/slave mechanism remote handling units are used with a number of these employed in daily processing operations. As regards this subject, it is useful to remember that, at the time of the designing of this plant (UP2-400), this was the only equipment available on the market with remote-controlled remote handling equipment. In the second part, before speaking about the development of remote operation equipment in the plants now under construction and attempting to project what might be the remote operation role in future plants, R. Le Guennec reviews the problems faced by engineering in designing industrial-sized processing plants and, consequently, the motivations of engineering when faced with a choice between several possible solutions [fr

  13. Using waterjet in reverse logistic operations in discarded munitions processing

    Czech Academy of Sciences Publication Activity Database

    Hloch, S.; Tozan, H.; Yagimli, M.; Valíček, Jan; Rokosz, K.

    2011-01-01

    Roč. 18, č. 2 (2011), s. 267-271 ISSN 1330-3651 Institutional research plan: CEZ:AV0Z30860518 Keywords : abrasive waterjet * anti tank bullet * automatic line Subject RIV: JQ - Machines ; Tools Impact factor: 0.347, year: 2011 http://hrcak.srce.hr/search/?q=Using+waterjet+in+reverse+logistic+operations+in+discarded+munitions+processing

  14. Processing Interband Cascade Laser for High Temperature CW Operation

    National Research Council Canada - National Science Library

    Tober, Richard

    2004-01-01

    A narrow ridge-waveguide mid-IR interband cascade laser based on Type-II InAs/GaInSh heterostructures processed with a thick gold heat spreading layer operated CW at temperatures ranging from 80 K to 214.4 K...

  15. 9 CFR 590.547 - Albumen flake process drying operations.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Albumen flake process drying operations. 590.547 Section 590.547 Animals and Animal Products FOOD SAFETY AND INSPECTION SERVICE... free of flies, insects, and rodents. (b) Drying units, racks, and trucks shall be kept in a clean and...

  16. Automation and efficiency in the operational processes: a case study in a logistics operator

    OpenAIRE

    Nascimento, Dener Gomes do; Silva, Giovanni Henrique da

    2017-01-01

    Globalization has made the automations become increasingly feasible and with the technological development many operations can be optimized, bringing productivity gains. Logistics is a major benefit of all this development, because lives a time extremely competitive, in which being efficient is a requirement to stay alive in the market. Inserted in this context, this article seeks from the analysis of the processes in a distribution center, identify opportunities to automate operations to gai...

  17. Plant operator performance evaluation based on cognitive process analysis experiment

    International Nuclear Information System (INIS)

    Ujita, H.; Fukuda, M.

    1990-01-01

    This paper reports on an experiment to clarify plant operators' cognitive processes that has been performed, to improve the man-machine interface which supports their diagnoses and decisions. The cognitive processes under abnormal conditions were evaluated by protocol analyses interviews, etc. in the experiment using a plant training simulator. A cognitive process model is represented by a stochastic network, based on Rasmussen's decision making model. Each node of the network corresponds to an element of the cognitive process, such as observation, interpretation, execution, etc. Some observations were obtained as follows, by comparison of Monte Carlo simulation results with the experiment results: A process to reconfirm the plant parameters after execution of a task and feedback paths from this process to the observation and the task definition of next task were observed. The feedback probability average and standard deviation should be determined for each incident type to explain correctly the individual differences in the cognitive processes. The tendency for the operator's cognitive level to change from skill-based to knowledge-based via rule-based behavior was observed during the feedback process

  18. Chemical catalysis in biodiesel production (I): enzymatic catalysis processes

    International Nuclear Information System (INIS)

    Jachmarian, I.; Dobroyan, M.; Veira, J.; Vieitez, I.; Mottini, M.; Segura, N.; Grompone, M.

    2009-01-01

    There are some well known advantages related with the substitution of chemical catalysis by enzymatic catalysis processes.Some commercial immobilized lipases are useful for the catalysis of bio diesel reaction, which permits the achievement of high conversions and the recovery of high purity products, like a high quality glycerine. The main disadvantage of this alternative method is related with the last inactivation of the enzyme (by both the effect of the alcohol and the absorption of glycerol on catalyst surface), which added to the high cost of the catalyst, produces an unfavourable economical balance of the entire process. In the work the efficiency of two commercial immobilized lipases (Lipozyme TL IM y Novozyme 435 NNovozymes-Dinamarca) in the catalysis of the continuous transesterification of sunflower oil with different alcohols was studied. The intersolubility of the different mixturesinvolving reactans (S oil/alkyl esters/alcohol) and products (P mixtures with a higher content of 1% of glycerol,while for ethanol homogeneous mixtures were obtained at 12% of glycerol (44.44 12).Using and ethanolic substrate at the proportion S=19:75:6 and Lipozyme TL IM, it was possible to achieve a 98% of convertion to the corresponding biodiesel.When Novozymes 435 catalyzed the process it was possible to increase the oil concentration in the substrateaccording to proportion S=35:30:35, and a 78% conversion was obtained. The productivity shown by the firt enzyme was 70mg biodiesel g enzime-1, hora-1 while with the second one the productivity increased to 230. Results suggested that the convenient adjustement of substrate composition with the addition of biodiesel to reactants offers an efficient method for maximizing the enzyme productivity, hence improving the profitability of the enzymatic catalyzed process. (author)

  19. Preventive acid chemical cleaning operation (PACCO) on steam generator in French nuclear power plants

    International Nuclear Information System (INIS)

    Traino, Jules; Ruiz Martinez, Jose Thomas; Rottner, Bernard; Vedova, Eric

    2014-01-01

    Steam Generators (SG) usually present important deposit loading and Tube Support Blockage, resulting from Secondary Side corrosion products. These phenomena modify SG behavior which can lead to safety, heat exchange performance and lifetime problems. In this context, a Chemical Cleaning Process (PACCO) was designed to solve the issue. After almost two years of intensive lab tests, pilot simulation and mock-ups, the chemical process was finally qualified by EDF. The aim of the work was firstly the development in laboratory of a chemical process that could eliminate partially the deposit loading, respecting the integrity of materials and gas emission limits. Secondly, the objective was the design and the implementation of the process on-site. The process has been applied successfully in 3 SG in Dampierre nuclear power plant in France on July 2013. The main results were: - Corrosion < 100 μm. - 40% of the initial deposit loading, removed by SG. (authors)

  20. Facile fabrication of CNT-based chemical sensor operating at room temperature

    Science.gov (United States)

    Sheng, Jiadong; Zeng, Xian; Zhu, Qi; Yang, Zhaohui; Zhang, Xiaohua

    2017-12-01

    This paper describes a simple, low cost and effective route to fabricate CNT-based chemical sensors, which operate at room temperature. Firstly, the incorporation of silk fibroin in vertically aligned CNT arrays (CNTA) obtained through a thermal chemical vapor deposition (CVD) method makes the direct removal of CNT arrays from substrates without any rigorous acid or sonication treatment feasible. Through a simple one-step in situ polymerization of anilines, the functionalization of CNT arrays with polyaniline (PANI) significantly improves the sensing performance of CNT-based chemical sensors in detecting ammonia (NH3) and hydrogen chloride (HCl) vapors. Chemically modified CNT arrays also show responses to organic vapors like menthol, ethyl acetate and acetone. Although the detection limits of chemically modified CNT-based chemical sensors are of the same orders of magnitudes reported in previous studies, these CNT-based chemical sensors show advantages of simplicity, low cost and energy efficiency in preparation and fabrication of devices. Additionally, a linear relationship between the relative sensitivity and concentration of analyte makes precise estimations on the concentrations of trace chemical vapors possible.

  1. Processing and stabilization of Aloe Vera leaf gel by adding chemical and natural preservatives

    Directory of Open Access Journals (Sweden)

    N. Nazemi

    2017-11-01

    Full Text Available Background and objectives: Aloe vera has been used as a medicinal herb for thousands of years. Aloe vera leaves can be separated into latex and gel which have biological effects. Aloe gel is a potent source of polysaccharides. When the gel is exposed to air, it quickly decomposes and decays and loses most of its biological activity. There are various processing techniques for sterilizing and stabilizing the gel. The aim of this study was to improve stabilization of the gel by adding some chemical and natural preservatives. Methods: The gel was obtained from Aloe vera leaves and after some processing chemical and natural preservatives were added. Chemicals included citric acid, ascorbic acid, vitamin E and potassium sorbate while natural preservatives were two essential oils derived from Cinnamomum zeylanicum and Eugenia caryophyllata. All these operations were performed under sterile conditions and they were evaluated at different temperatures and times. Appearance and taste changes of gel were studied organoleptic. Microbiological tests and some physical assays such as pH, refractometry and viscosity properties as well as determination of total sugars were measured. NMR and FT-IR analyses were performed for determining the quality of samples. Results: After data analyzing, the results showed that the samples formulated with chemical additives together with essential oils were more suitable and stable compared to the control samples after 90 days and the effective ingredient acemannan, remained stable. Conclusion: The stable gel can be considered for therapeutic properties and be used for edible and medicinal purposes.

  2. The enhanced variance propagation code for the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Kern, E.A.; Zack, N.R.; Britschgi, J.J.

    1992-01-01

    The Variance Propagation (VP) Code was developed by the Los Alamos National Laboratory's Safeguard's Systems Group to provide off-line variance propagation and systems analysis for nuclear material processing facilities. The code can also be used as a tool in the design and evaluation of material accounting systems. In this regard , the VP code was enhanced to incorporate a model of the material accountability measurements used in the Idaho Chemical Processing Plant operated by the Westinghouse Idaho Nuclear Company. Inputs to the code were structured to account for the dissolves/headend process, the waste streams, process performed to determine the sensitivity of measurement and sampling errors to the overall material balance error. We determined that the material balance error is very sensitive to changes in the sampling errors. 3 refs

  3. Remote operated systems for the management of nuclear processes

    International Nuclear Information System (INIS)

    Popa, I.

    1997-01-01

    The paper shortly presents the remote techniques and systems used regularly for the management of nuclear processes according to the variability and complexity of human operations and to the degree of automation. The paper contains a synthesis of the evolution of remote operating systems and advances the model of an adaptive and self-adaptive expert-robot equipment which is a very complex equipment used for integrated management of nuclear processes. Due to the complexity and variability of the technological operations and environment conditions, none of the techniques and systems presented in the paper do satisfy completely the management of the nuclear technologies as a whole. They must be utilized selectively according to the nature of the actual characteristics of the nuclear process. The expert and expert-robot systems offer a series of advantages among which one can mention: the continuity of the high quality expert's reports, easy extension, the explanation of the decision in detail, the elimination of the routine, the diagnosis of some equipment and process state, forecast of the future behaviour of equipment, processes, market, environment, etc., the multiplying of sources of information, pertinent comparison, the increasing of the performance of the user in general. The expert and expert-robot systems maintain some important drawbacks as: the possibility of taking wrong decision, the difficulty of using information from other expert systems similar to this one at present and not in the least, the high prices. (author)

  4. Frames and operator theory in analysis and signal processing

    CERN Document Server

    Larson, David R; Nashed, Zuhair; Nguyen, Minh Chuong; Papadakis, Manos

    2008-01-01

    This volume contains articles based on talks presented at the Special Session Frames and Operator Theory in Analysis and Signal Processing, held in San Antonio, Texas, in January of 2006. Recently, the field of frames has undergone tremendous advancement. Most of the work in this field is focused on the design and construction of more versatile frames and frames tailored towards specific applications, e.g., finite dimensional uniform frames for cellular communication. In addition, frames are now becoming a hot topic in mathematical research as a part of many engineering applications, e.g., matching pursuits and greedy algorithms for image and signal processing. Topics covered in this book include: Application of several branches of analysis (e.g., PDEs; Fourier, wavelet, and harmonic analysis; transform techniques; data representations) to industrial and engineering problems, specifically image and signal processing. Theoretical and applied aspects of frames and wavelets. Pure aspects of operator theory empha...

  5. Object-oriented process dose modeling for glovebox operations

    International Nuclear Information System (INIS)

    Boerigter, S.T.; Fasel, J.H.; Kornreich, D.E.

    1999-01-01

    The Plutonium Facility at Los Alamos National Laboratory supports several defense and nondefense-related missions for the country by performing fabrication, surveillance, and research and development for materials and components that contain plutonium. Most operations occur in rooms with one or more arrays of gloveboxes connected to each other via trolley gloveboxes. Minimizing the effective dose equivalent (EDE) is a growing concern as a result of steadily declining allowable dose limits being imposed and a growing general awareness of safety in the workplace. In general, the authors discriminate three components of a worker's total EDE: the primary EDE, the secondary EDE, and background EDE. A particular background source of interest is the nuclear materials vault. The distinction between sources inside and outside of a particular room is arbitrary with the underlying assumption that building walls and floors provide significant shielding to justify including sources in other rooms in the background category. Los Alamos has developed the Process Modeling System (ProMoS) primarily for performing process analyses of nuclear operations. ProMoS is an object-oriented, discrete-event simulation package that has been used to analyze operations at Los Alamos and proposed facilities such as the new fabrication facilities for the Complex-21 effort. In the past, crude estimates of the process dose (the EDE received when a particular process occurred), room dose (the EDE received when a particular process occurred in a given room), and facility dose (the EDE received when a particular process occurred in the facility) were used to obtain an integrated EDE for a given process. Modifications to the ProMoS package were made to utilize secondary dose information to use dose modeling to enhance the process modeling efforts

  6. A review of operational, regional-scale, chemical weather forecasting models in Europe

    Czech Academy of Sciences Publication Activity Database

    Kukkonen, J.; Olsson, T.; Schultz, D.M.; Baklanov, A.; Klein, T.; Miranda, A.I.; Monteiro, A.; Hirtl, M.; Tarvainen, V.; Boy, M.; Peuch, V.H.; PoupKou, A.; Kioutsioukis, I.; Finardi, S.; Sofiev, M.; Sokhi, R.; Lehtinen, K.E.J.; Karatzas, K.; San José, R.; Astitha, M.; Kallos, G.; Schaap, M.; Reimer, E.; Jakobs, H.; Eben, Kryštof

    2012-01-01

    Roč. 12, - (2012), s. 1-87 ISSN 1680-7316 Institutional research plan: CEZ:AV0Z10300504 Keywords : chemical weather * numerical models * operational forecasting * air Subject RIV: DG - Athmosphere Sciences, Meteorology Impact factor: 5.510, year: 2012

  7. Liquid electrolyte positioning along the device channel influences the operation of Organic Electro-Chemical Transistors

    KAUST Repository

    D'angelo, Pasquale; Coppedè , Nicola; Tarabella, Giuseppe; Romeo, Agostino; Gentile, Francesco T.; Iannotta, Salvatore; Di Fabrizio, Enzo M.; Mosca, Roberto

    2014-01-01

    In this work, we show the influence of the liquid electrolyte adsorption by porous films made of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), PEDOT:PSS, on the operation of an Organic Electro-Chemical Transistor with an active channel

  8. Applying operating experience to design the CANDU 3 process

    International Nuclear Information System (INIS)

    Harris, D.S.; Hinchley, E.M.; Pauksens, J.; Snell, V.; Yu, S.K.W.

    1991-01-01

    The CANDU 3 is an advanced, smaller (450 MWe), standardized version of the CANDU now being designed for service later in the decade and beyond. The design of this evolutionary nuclear power plant has been carefully planned and organized to gain maximum benefits from new technologies and from world experience to date in designing, building, commissioning and operating nuclear power stations. The good performance record of existing CANDU reactors makes consideration of operating experience from these plants a particularly vital component of the design process. Since the completion of the first four CANDU 6 stations in the early 1980s, and with the continuing evolution of the multi-unit CANDU station designs since then, AECL CANDU has devised several processes to ensure that such feedback is made available to designers. An important step was made in 1986 when a task force was set up to review and process ideas arising from the commissioning and early operation of the CANDU 6 reactors which were, by that time, operating successfully in Argentina and Korea, as well as the Canadian provinces of Quebec and New Brunswick. The task force issued a comprehensive report which, although aimed at the design of an improved CANDU 6 station, was made available to the CANDU 3 team. By that time also, the Institute of Power Operations (INPO) in the U.S., of which AECL is a Supplier Participant member, was starting to publish Good Practices and Guidelines related to the review and the use of operating experiences. In addition, details of significant events were being made available via the INPO SEE-IN (Significant Event Evaluation and Information Network) Program, and subsequently the CANNET network of the CANDU Owners' Group (COG). Systematic review was thus possible by designers of operations reports, significant event reports, and related documents in a continuing program of design improvement. Another method of incorporating operations feedback is to involve experienced utility

  9. Applying operating experience to design the CANDU 3 process

    Energy Technology Data Exchange (ETDEWEB)

    Harris, D S; Hinchley, E M; Pauksens, J; Snell, V; Yu, S K.W. [AECL-CANDU, Ontario (Canada)

    1991-04-01

    The CANDU 3 is an advanced, smaller (450 MWe), standardized version of the CANDU now being designed for service later in the decade and beyond. The design of this evolutionary nuclear power plant has been carefully planned and organized to gain maximum benefits from new technologies and from world experience to date in designing, building, commissioning and operating nuclear power stations. The good performance record of existing CANDU reactors makes consideration of operating experience from these plants a particularly vital component of the design process. Since the completion of the first four CANDU 6 stations in the early 1980s, and with the continuing evolution of the multi-unit CANDU station designs since then, AECL CANDU has devised several processes to ensure that such feedback is made available to designers. An important step was made in 1986 when a task force was set up to review and process ideas arising from the commissioning and early operation of the CANDU 6 reactors which were, by that time, operating successfully in Argentina and Korea, as well as the Canadian provinces of Quebec and New Brunswick. The task force issued a comprehensive report which, although aimed at the design of an improved CANDU 6 station, was made available to the CANDU 3 team. By that time also, the Institute of Power Operations (INPO) in the U.S., of which AECL is a Supplier Participant member, was starting to publish Good Practices and Guidelines related to the review and the use of operating experiences. In addition, details of significant events were being made available via the INPO SEE-IN (Significant Event Evaluation and Information Network) Program, and subsequently the CANNET network of the CANDU Owners' Group (COG). Systematic review was thus possible by designers of operations reports, significant event reports, and related documents in a continuing program of design improvement. Another method of incorporating operations feedback is to involve experienced utility

  10. The production of fuels and chemicals from food processing wastes & cellulosics. Final research report

    Energy Technology Data Exchange (ETDEWEB)

    Dale, M.C.; Okos, M.; Burgos, N. [and others

    1997-06-15

    High strength food wastes of about 15-20 billion pounds solids are produced annually by US food producers. Low strength food wastes of 5-10 billion pounds/yr. are produced. Estimates of the various components of these waste streams are shown in Table 1. Waste paper/lignocellulosic crops could produce 2 to 5 billion gallons of ethanol per year or other valuable chemicals. Current oil imports cost the US about $60 billion dollars/yr. in out-going balance of trade costs. Many organic chemicals that are currently derived from petroleum can be produced through fermentation processes. Petroleum based processes have been preferred over biotechnology processes because they were typically cheaper, easier, and more efficient. The technologies developed during the course of this project are designed to allow fermentation based chemicals and fuels to compete favorably with petroleum based chemicals. Our goals in this project have been to: (1) develop continuous fermentation processes as compared to batch operations; (2) combine separation of the product with the fermentation, thus accomplishing the twin goals of achieving a purified product from a fermentation broth and speeding the conversion of substrate to product in the fermentation broth; (3) utilize food or cellulosic waste streams which pose a current cost or disposal problem as compared to high cost grains or sugar substrates; (4) develop low energy recovery methods for fermentation products; and finally (5) demonstrate successful lab scale technologies on a pilot/production scale and try to commercialize the processes. The scale of the wastes force consideration of {open_quotes}bulk commodity{close_quotes} type products if a high fraction of the wastes are to be utilized.

  11. Systematic methods for synthesis and design of sustainable chemical and biochemical processes

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    Chemical and biochemical process design consists of designing the process that can sustainably manufacture an identified chemical product through a chemical or biochemical route. The chemical product tree is potentially very large; starting from a set of basic raw materials (such as petroleum...... for process intensification, sustainable process design, identification of optimal biorefinery models as well as integrated process-control design, and chemical product design. The lecture will present the main concepts, the decomposition based solution approach, the developed methods and tools together...

  12. HEPA filter leaching concept validation trials at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Chakravartty, A.C.

    1995-04-01

    The enclosed report documents six New Waste Calcining Facility (NWCF) HEPA filter leaching trials conducted at the Idaho Chemical Processing Plant using a filter leaching system to validate the filter leaching treatment concept. The test results show that a modified filter leaching system will be able to successfully remove both hazardous and radiological constituents to RCRA disposal levels. Based on the success of the filter leach trials, the existing leaching system will be modified to provide a safe, simple, effective, and operationally flexible filter leaching system

  13. A process for treatment of mixed waste containing chemical plating wastes

    International Nuclear Information System (INIS)

    Anast, K.R.; Dziewinski, J.; Lussiez, G.

    1995-01-01

    The Waste Treatment and Minimization Group at Los Alamos National Laboratory has designed and will be constructing a transportable treatment system to treat low-level radioactive mixed waste generated during plating operations. The chemical and plating waste treatment system is composed of two modules with six submodules, which can be trucked to user sites to treat a wide variety of aqueous waste solutions. The process is designed to remove the hazardous components from the waste stream, generating chemically benign, disposable liquids and solids with low level radioactivity. The chemical and plating waste treatment system is designed as a multifunctional process capable of treating several different types of wastes. At this time, the unit has been the designated treatment process for these wastes: Destruction of free cyanide and metal-cyanide complexes from spent plating solutions; destruction of ammonia in solution from spent plating solutions; reduction of Cr VI to Cr III from spent plating solutions, precipitation, solids separation, and immobilization; heavy metal precipitation from spent plating solutions, solids separation, and immobilization, and acid or base neutralization from unspecified solutions

  14. Modelling of innovative SANEX process mal-operations

    International Nuclear Information System (INIS)

    McLachlan, F.; Taylor, R.; Whittaker, D.; Woodhead, D.; Geist, A.

    2016-01-01

    The innovative (i-) SANEX process for the separation of minor actinides from PUREX highly active raffinate is expected to employ a solvent phase comprising 0.2 M TODGA with 5 v/v% 1-octanol in an inert diluent. An initial extract / scrub section would be used to extract trivalent actinides and lanthanides from the feed whilst leaving other fission products in the aqueous phase, before the loaded solvent is contacted with a low acidity aqueous phase containing a sulphonated bis-triazinyl pyridine ligand (BTP) to effect a selective strip of the actinides, so yielding separate actinide (An) and lanthanide (Ln) product streams. This process has been demonstrated in lab scale trials at Juelich (FZJ). The SACSESS (Safety of Actinide Separation processes) project is focused on the evaluation and improvement of the safety of such future systems. A key element of this is the development of an understanding of the response of a process to upsets (mal-operations). It is only practical to study a small subset of possible mal-operations experimentally and consideration of the majority of mal-operations entails the use of a validated dynamic model of the process. Distribution algorithms for HNO_3, Am, Cm and the lanthanides have been developed and incorporated into a dynamic flowsheet model that has, so far, been configured to correspond to the extract-scrub section of the i-SANEX flowsheet trial undertaken at FZJ in 2013. Comparison is made between the steady state model results and experimental results. Results from modelling of low acidity and high temperature mal-operations are presented. (authors)

  15. Physical and chemical characterization of airborne particles from welding operations in automotive plants.

    Science.gov (United States)

    Dasch, Jean; D'Arcy, James

    2008-07-01

    Airborne particles were characterized from six welding operations in three automotive plants, including resistance spot welding, metal inert gas (MIG) welding and tungsten inert gas (TIG) welding of aluminum and resistance spot welding, MIG welding and weld-through sealer of galvanized steel. Particle levels were measured throughout the process area to select a sampling location, followed by intensive particle sampling over one working shift. Temporal trends were measured, and particles were collected on filters to characterize their size and chemistry. In all cases, the particles fell into a bimodal size distribution with very large particles >20 mum in diameter, possibly emitted as spatter or metal expulsions, and very small particles about 1 mum in diameter, possibly formed from condensation of vaporized metal. The mass median aerodynamic diameter was about 1 mum, with only about 7% of the particle mass present as ultrafine particles welding particles could be accounted for by chemical analysis, with the remainder possibly present as oxygen. Predominant species were organic carbon, elemental carbon, iron, and aluminum. More than 80% of the particle mass could be accounted for from steel welding, primarily present as iron, organic carbon, zinc, and copper. Particle concentrations and elemental concentrations were compared with allowable concentrations as recommended by the Occupational Safety and Health Administration and the American Conference of Governmental Industrial Hygienists. In all cases, workplace levels were at least 11 times lower than recommended levels.

  16. Three-dimensional chemical structure of the INEL aquifer system near the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    McCurry, M.; Estes, M.; Fromm, J.; Welhan, J.; Barrash, W.

    1994-01-01

    Sampling and analysis from the Snake River Plain aquifer using a stainless-steel and teflon constructed straddle-packer system has established detailed vertical profiles of aquifer chemistry from three wells near a major source of low-level waste injection at the Idaho Chemical Processing Plant. Multiple intervals, varying from 4.6 to 6.1 m in length, were sampled between the water table (140.5 mbls - meters below land surface), and approximately 200 mbls to obtain a wide spectrum of metals, anions, radiological and organic components analyses. Measurements were also made at the well sites of important transient parameters (T, Eh, Fe 3+ , Fe 2+ , DO and SC). The principal purpose of this ongoing work is to improve our understanding of the third (i.e. vertical) dimension of aquifer chemistry at the INEL as a basis for critically evaluating site-wide monitoring procedures, and, ultimately, for improving fate and transport models for aquifer contaminants within basalt-hosted aquifers. Chemical and radiological data indicates that substantial systematic vertical and lateral variations occur in the aquifer hydrochemistry - in particular for conservative radiological nuclide concentrations. Radiological data define a three-layered zonation. Ground water within upper and lower zones contain up to 10 times higher concentrations of H-3 and I-129 than in the middle zone. Sr-90 activity is decoupled from H-3 and I-129-relatively high activity was detected within the upper zone nearest the ICPP, but activities elsewhere are very low. 27 refs., 4 figs., 1 tab

  17. The thermal oxide reprocessing plant at Sellafield: three years of active operation in the chemical separation plant

    International Nuclear Information System (INIS)

    Philips, C.

    1998-01-01

    The Thermal Oxide Reprocessing Plant at British Nuclear Fuels' Sellafield site started operating in March 1994 with the shearing of its first irradiated fuel. In January 1995 the Chemical Separation part of the plant commenced processing the irradiated fuel feed solution that had been produced in the previous year by the Head End plant. By the Spring of 1998 over 1400 t of irradiated fuel has been reprocessed in Thorp, and the plant is being steadily and successfully ramped up to its normal operating throughput. The performance of the Thorp Chemical Separation Plant has been excellent, with the solvent extraction contactors performing as predicted by the extensive development programme. In particular the uranium-plutonium separation stage, which received intensive development to deal with the effects of the fission product technetium, has given an overall separation performance well in excess of the minimum flowsheet requirement. Decontamination of the uranium and plutonium products from fission products has in general been better than flowsheet requirements and the solvent extraction equipment has operated stably under the automatic controls developed during the R and D programme. Discharges of contaminants to waste streams have generally been in line with, or better than, expectation. This paper compares with flowsheet predictions a range of the key fission product and transuranic decontamination factors achieved in Thorp, shows how waste stream discharges are a small fraction of Sellafield Site discharge limits, demonstrates how uranium - plutonium separation performance has compared with expectation and summarises the overall performance of the Chemical Separation Plant. (author)

  18. Flux behaviour under different operational conditions in osmosis process

    DEFF Research Database (Denmark)

    Korenak, Jasmina; Zarebska, Agata; Buksek, Hermina

    the active membrane layer is facing draw solution. Osmosis process can be affected by several factors, such as operating conditions (temperature and cross flow velocity), feed and draw solution properties, and membrane characteristics. These factors can significantly contribute to the efficiency......, and total dissolved solids. Taken together our results can contribute understanding of the how performance of asymmetric FO membranes can be enhanced by feed and draw properties, membrane characteristics and operational conditions.......The transport of water molecules across a semi-permeable membrane is driven by the osmotic pressure difference between feed and draw solution. Two different operational modes can be distinguished, namely FO mode when the active membrane layer is facing the wastewater (feed), and PRO mode when...

  19. Hazard analysis and critical control point (HACCP) for an ultrasound food processing operation.

    Science.gov (United States)

    Chemat, Farid; Hoarau, Nicolas

    2004-05-01

    Emerging technologies, such as ultrasound (US), used for food and drink production often cause hazards for product safety. Classical quality control methods are inadequate to control these hazards. Hazard analysis of critical control points (HACCP) is the most secure and cost-effective method for controlling possible product contamination or cross-contamination, due to physical or chemical hazard during production. The following case study on the application of HACCP to an US food-processing operation demonstrates how the hazards at the critical control points of the process are effectively controlled through the implementation of HACCP.

  20. Emergency end of life operations for CNES remote sensing satellites—Management and operational process

    Science.gov (United States)

    Bertrand, Régis; Alby, Fernand; Costes, Thierry; Dejoie, Joël; Delmas, Dominique-Roland; Delobette, Damien; Gibek, Isabelle; Gleyzes, Alain; Masson, Françoise; Meyer, Jean-Renaud; Moreau, Agathe; Perret, Lionel; Riclet, François; Ruiz, Hélène; Schiavon, Françoise; Spizzi, Pierre; Viallefont, Pierre; Villaret, Colette

    2012-10-01

    continue its mission using the redundancy, b/. the EOL operations must be planned within a mid-term period, or c/. the EOL operations must be implemented as soon as possible by the operational teams. The paper describes this management and operational process illustrated with study cases of failures on SPOT and PLEIADES satellites corresponding to various emergency situations.

  1. NATO Advanced Study Institute on Chemical Transport in Melasomatic Processes

    CERN Document Server

    1987-01-01

    As indicated on the title page, this book is an outgrowth of the NATO Advanced Study Institute (ASI) on Chemical Transport in Metasomatic Processes, which was held in Greece, June 3-16, 1985. The ASI consisted of five days of invited lectures, poster sessions, and discussion at the Club Poseidon near Loutraki, Corinthia, followed by a two-day field trip in Corinthia and Attica. The second week of the ASI consisted of an excursion aboard M/S Zeus, M/Y Dimitrios II, and the M/S Irini to four of the Cycladic Islands to visit, study, and sample outstanding exposures of metasomatic activity on Syros, Siphnos, Seriphos, and Naxos. Nine­ teen invited lectures and 10 session chairmen/discussion leaders participated in the ASI, which was attended by a total of 92 professional scientists and graduate stu­ dents from 15 countries. Seventeen of the invited lectures and the Field Excursion Guide are included in this volume, together with 10 papers and six abstracts representing contributed poster sessions. Although more...

  2. Book of abstracts Chemical Engineering: IV All-Russian Conference on chemical engineering, All-Russian Youth Conference on chemical engineering, All-Russian school on chemical engineering for young scientists and specialists. Chemical engineering of nanomaterials. Energy- and resource-saving chemical-engineering processes and problems of their intensification. Processes and apparatuses of chemical engineering, chemical cybernetics. Ecological problems of chemical engineering and related fields

    International Nuclear Information System (INIS)

    Zakhodyaeva, Yu.A.; Belova, V.V.

    2012-01-01

    In the given volume of abstracts of the IV All-Russian Conference on chemical engineering, All-Russian Youth Conference on chemical engineering, All-Russian school on chemical engineering for young scientists and specialists (Moscow, March 18-23, 2012) there are the abstracts of the reports concerning chemical engineering of nanomaterials, energy- and resource-saving chemical-engineering processes, processes and apparatuses of chemical engineering, chemical cybernetics, ecological problems of chemical engineering and related fields. The abstracts deal with state-of-the-art and future development of theoretical and experimental investigations as well as with experience in practical realization of development works in the field of chemical engineering and relative areas [ru

  3. Experiments on data presentation to process operators in diagnostic tasks

    DEFF Research Database (Denmark)

    Rasmussen, Jens; Goodstein, L. P.

    1972-01-01

    Safety and reliability considerations in modern power plants have prompted our interest in man as an information receiver - especially in diagnostic tasks where the growing complexity of process plants and hence the amount of data involved make it imperative to give the staff proper support....... The great flexibility and capacity of the process computer for data reduction and presentation and for storing information on plant structure and functions give the system designer great freedom in the layout of information display for the staff, but the problem for the designer is how to make proper use...... of this freedom to support the operators efficiently. This is especially important in connection with unique, high-risk, and generally improbable abnormalities in plant functioning. Operator tasks and mental models and the need for matching the encoded information about the plant to these models are treated...

  4. Operating cost budgeting methods: quantitative methods to improve the process

    Directory of Open Access Journals (Sweden)

    José Olegário Rodrigues da Silva

    Full Text Available Abstract Operating cost forecasts are used in economic feasibility studies of projects and in budgeting process. Studies have pointed out that some companies are not satisfied with the budgeting process and chief executive officers want updates more frequently. In these cases, the main problem lies in the costs versus benefits. Companies seek simple and cheap forecasting methods without, at the same time, conceding in terms of quality of the resulting information. This study aims to compare operating cost forecasting models to identify the ones that are relatively easy to implement and turn out less deviation. For this purpose, we applied ARIMA (autoregressive integrated moving average and distributed dynamic lag models to data from a Brazilian petroleum company. The results suggest that the models have potential application, and that multivariate models fitted better and showed itself a better way to forecast costs than univariate models.

  5. Operational digital image processing within the Bureau of Land Management

    International Nuclear Information System (INIS)

    Work, E.A.; Story, M.

    1991-01-01

    An overview of the use of operational digital image processing at the U.S. Bureau of Land Management (BLM) is presented. The BLM digital image analysis facility for the processing and analysis of aerial photography and satellite data is described, and its role within the Bureau's operational structure is explained. Attention is given to examples of BLM digital data analysis projects that have utilized Landsat (MSS and TM), NOAA-AVHRR, or SPOT data. These projects include: landcover mapping to assist land use planning or special projects; monitoring of wilderness units to detect unauthorized activities; stratification aid for detailed field inventories; identification/quantification of unauthorized use (agricultural and mineral trespass); and fire fuels mapping and updates. 3 refs

  6. Accident simulation in a chemical process facility at the Savannah River Site

    International Nuclear Information System (INIS)

    Hope, E.P.

    1993-01-01

    The US Department of Energy requires Westinghouse Savannah River Company to safely operate the chemical separations facilities at the Savannah River Site (SRS). As part of the safety analysis program, simulation of a proposed frame waste recovery (FWR) system is needed to determine the possible accident consequences that may affect public safety. This paper details the simulation process for the proposed frame waste recovery process and describes the analytical tools used in order to make estimates of accident consequences. Since the process in question has been operated, historical data and statistics about its operation are available. Software tools have been developed to allow analysis of the frame waste recovery system, including the generation of system specific dose conversion factors for a number of unique situations. Accident scenarios involving spilled liquid material are analyzed and account for the specific floor geometry of the facility. Confinement and filtration systems are considered. Analysis of source terms is a limiting factor which affects the entire evaluation process. In the past, facility source terms were generally constant with occasional variations from established patterns. As new site missions unfold, significant variations in source terms can be expected. The impact of these variations on the safety analysis is discussed

  7. Marcoule pilot work-room: process automatic operation

    International Nuclear Information System (INIS)

    Mus, G.; Linger, C.

    1987-01-01

    Commissioned in the early 1960s, the Marcoule Pilot Plant has undergone a series of sweeping transformations. The Research and Development resources concerning irradiated fuel processing have been expanded and modified. Its reprocessing capacity has also been raised from 2 to 5 t/year. Simultaneously, the installation control system was completely remodelled. The control consoles, which were previously positioned locally near the different units, have been grouped together in a centralized control room. To do this, the measurement and operating circuits were replaced by new data acquisition and processing systems requiring the use of numerical algorithms. The management and control of certain units, including mechanical fuel preparation, sampling, and sample transport to the laboratories, have been entrusted to programmable automata. Certain unit operations, such as concentration by evaporation, are set up with complete automation. These new arrangements will expand the resources for analysing the operation of the Pilot Plant, while offering a more overall view of the operations. They have been made possible by a major effort in the development of sensors, and represent the indispensable prerequisite for the installation of expert systems [fr

  8. Design criteria for the new waste calcining facility at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Anderson, F.H.; Bingham, G.E.; Buckham, J.A.; Dickey, B.R.; Slansky, C.M.; Wheeler, B.R.

    1976-01-01

    The New Waste Calcining Facility (NWCF) at the Idaho Chemical Processing Plant (ICPP) is being built to replace the existing fluidized-bed, high-level waste calcining facility (WCF). Performance of the WCF is reviewed, equipment failures in WCF operation are examined, and pilot-plant studies on calciner improvements are given in relation to NWCF design. Design features of the NWCF are given with emphasis on process and equipment improvements. A major feature of the NWCF is the use of remote maintenance facilities for equipment with high maintenance requirements, thereby reducing personnel exposures during maintenance and reducing downtime resulting from plant decontamination. The NWCF will have a design net processing rate of 11.36 m 3 of high-level waste per day, and will incorporate in-bed combustion of kerosene for heating the fluidized bed calciner. The off-gas cleaning system will be similar to that for the WCF

  9. Chemical processing of liquid lithium fusion reactor blankets

    International Nuclear Information System (INIS)

    Weston, J.R.; Calaway, W.F.; Yonco, R.M.; Hines, J.B.; Maroni, V.A.

    1979-01-01

    A 50-gallon-capacity lithium loop constructed mostly from 304L stainless steel has been operated for over 6000 hours at temperatures in the range from 360 to 480 0 C. This facility, the Lithium Processing Test Loop (LPTL), is being used to develop processing and monitoring technology for liquid lithium fusion reactor blankets. Results of tests of a molten-salt extraction method for removing impurities from liquid lithium have yielded remarkably good distribution coefficients for several of the more common nonmetallic elements found in lithium systems. In particular, the equilibrium volumetric distribution coefficients, D/sub v/ (concentration per unit volume of impurity in salt/concentration per unit volume of impurity in lithium), for hydrogen, deuterium, nitrogen and carbon are approx. 3, approx. 4, > 10, approx. 2, respectively. Other studies conducted with a smaller loop system, the Lithium Mini-Test Loop (LMTL), have shown that zirconium getter-trapping can be effectively used to remove selected impurities from flowing lithium

  10. Zeolite Vitrification Demonstration Program nonradioactive-process operations summary

    International Nuclear Information System (INIS)

    Bryan, G.H.; Knox, C.A.; Goles, R.G.; Ethridge, L.J.; Siemens, D.H.

    1982-09-01

    The Submerged Demineralizer System is a process developed to decontaminate high-activity level water at Three Mile Island by sorbing the activity (primarily Cs and Sr) onto beds of zeolite. Pacific Northwest Laboratory's Zeolite Vitrification Demonstration Program has the responsibility of demonstrating the full-scale vitrification of this zeolite material. The first phase of this program has been to develop a glass formulation and demonstrate the vitrification process with the use of nonradioactive materials. During this phase, four full-scale nonradioactive demonstration runs were completed. The same zeolite mixture being used in the SDS system was loaded with nonradioactive isotopes of Cs and Sr, dried, blended with glass-forming chemicals and fed to a canister in an in-can melter furnace. During each run, the gaseous effluents were sampled. After each run, glass samples were removed and analyzed

  11. Effect of ozone gas processing on physical and chemical properties ...

    African Journals Online (AJOL)

    Purpose: To investigate the effects of ozone treatment on chemical and physical properties of wheat (Triticum aestivum L.) gluten, glutenin and gliadin. Methods: Wheat proteins isolated from wheat flour were treated with ozone gas. The physical and chemical properties of gluten proteins were investigated after treatment ...

  12. Real-time operation guide system for sintering process with artificial intelligence

    Institute of Scientific and Technical Information of China (English)

    FAN Xiao-hui; CHEN Xu-ling; JIANG Tao; LI Tao

    2005-01-01

    In order to optimize the sintering process, a real-time operation guide system with artificial intelligence was developed, mainly including the data acquisition online subsystem, the sinter chemical composition controller, the sintering process state controller, and the abnormal conditions diagnosis subsystem. Knowledge base of the sintering process controlling was constructed, and inference engine of the system was established. Sinter chemical compositions were controlled by the strategies of self-adaptive prediction, internal optimization and center on basicity. And the state of sintering was stabilized centering on permeability. In order to meet the needs of process change and make the system clear, the system has learning ability and explanation function. The software of the system was developed in Visual C++ programming language. The application of the system shows that the hitting accuracy of sinter compositions and burning through point prediction are more than 85%; the first-grade rate of sinter chemical composition, stability rate of burning through point and stability rate of sintering process are increased by 3%, 9% and 4%, respectively.

  13. The Operator's Diagnosis Task under Abnormal Operating Conditions in Industrial Process Plant

    DEFF Research Database (Denmark)

    Goodstein, L.P.; Pedersen, O.M.; Rasmussen, Jens

    1974-01-01

    Analysis of serious accidents in connection with the operation of technical installations demonstrate that the diagnosis task which confronts personnel under non-normal plant conditions is a critical one. This report presents a preliminary outline of characteristic traits connected with the task...... of diagnosis for use in discussions of (a) the studies which are necessary in order to formulate the operator's diagnostic procedures and (b) the possibilities which exists for supporting these procedures through appropriate data processing and display in the control system. At the same time, attempts are made...

  14. ARTIST process. A novel chemical process for treatment of spent nuclear fuel

    International Nuclear Information System (INIS)

    Tachimori, Shoichi

    2001-10-01

    A new chemical process, ARTIST process, is proposed for the treatment of spent nuclear fuel. The main concept of the ARTIST process is to recover and stock all actinides (Ans) as two groups, uranium (U) and a mixture of transuranics (TRU), to preserve their resource value and to dispose solely fission products (FPs). The process is composed of two main steps, an U exclusive isolation and a total recovery of TRU; which copes with the nuclear non-proliferation measures, and additionally of Pu separation process and soft N-donor process if requested, and optionally of processes for separation of long-lived FPs. These An products: U-product and TRU-product, are to be solidified by calcination and allowed to the interim stockpile for future utilization. These separations are achieved by use of amidic extractants in accord with the CHON principle. The technical feasibility of the ARTIST process was explained by the performance of both the branched alkyl monoamides in extracting U and suppressing the extraction of tetravalent Ans due to the steric effect and the diglycolic amide (TODGA) in thorough extraction of all TRU by tridentate fashion. When these TRU are requested to put into reactors, LWR or FBR, for power generation or the Accelerator - Driven System (ADS) for transmutation, Pu (Np) or Am-Cm (Np) are to be extracted from the TRU-product. (author)

  15. Defense Waste Processing Facility Nitric- Glycolic Flowsheet Chemical Process Cell Chemistry: Part 2

    Energy Technology Data Exchange (ETDEWEB)

    Zamecnik, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-06-06

    The conversions of nitrite to nitrate, the destruction of glycolate, and the conversion of glycolate to formate and oxalate were modeled for the Nitric-Glycolic flowsheet using data from Chemical Process Cell (CPC) simulant runs conducted by Savannah River National Laboratory (SRNL) from 2011 to 2016. The goal of this work was to develop empirical correlation models to predict these values from measureable variables from the chemical process so that these quantities could be predicted a-priori from the sludge or simulant composition and measurable processing variables. The need for these predictions arises from the need to predict the REDuction/OXidation (REDOX) state of the glass from the Defense Waste Processing Facility (DWPF) melter. This report summarizes the work on these correlations based on the aforementioned data. Previous work on these correlations was documented in a technical report covering data from 2011-2015. This current report supersedes this previous report. Further refinement of the models as additional data are collected is recommended.

  16. Method and apparatus for monitoring plasma processing operations

    Science.gov (United States)

    Smith, Jr., Michael Lane; Ward, Pamela Denise Peardon; Stevenson, Joel O'Don

    2002-01-01

    The invention generally relates to various aspects of a plasma process, and more specifically the monitoring of such plasma processes. One aspect relates in at least some manner to calibrating or initializing a plasma monitoring assembly. This type of calibration may be used to address wavelength shifts, intensity shifts, or both associated with optical emissions data obtained on a plasma process. A calibration light may be directed at a window through which optical emissions data is being obtained to determine the effect, if any, that the inner surface of the window is having on the optical emissions data being obtained therethrough, the operation of the optical emissions data gathering device, or both. Another aspect relates in at least some manner to various types of evaluations which may be undertaken of a plasma process which was run, and more typically one which is currently being run, within the processing chamber. Plasma health evaluations and process identification through optical emissions analysis are included in this aspect. Yet another aspect associated with the present invention relates in at least some manner to the endpoint of a plasma process (e.g., plasma recipe, plasma clean, conditioning wafer operation) or discrete/discernible portion thereof (e.g., a plasma step of a multiple step plasma recipe). Another aspect associated with the present invention relates to how one or more of the above-noted aspects may be implemented into a semiconductor fabrication facility, such as the distribution of wafers to a wafer production system. A final aspect of the present invention relates to a network a plurality of plasma monitoring systems, including with remote capabilities (i.e., outside of the clean room).

  17. Optimization of Nonambulant Mass Casualty Decontamination Protocols as Part of an Initial or Specialist Operational Response to Chemical Incidents.

    Science.gov (United States)

    Chilcott, Robert P; Mitchell, Hannah; Matar, Hazem

    2018-05-30

    The UK's Initial Operational Response (IOR) is a new process for improving the survival of multiple casualties following a chemical, biological, radiological or nuclear incident. Whilst the introduction of IOR represents a patient-focused response for ambulant casualties, there is currently no provision for disrobe and dry decontamination of nonambulant casualties. Moreover, the current specialist operational response (SOR) protocol for nonambulant casualty decontamination (also referred to as "clinical decontamination") has not been subject to rigorous evaluation or development. Therefore, the aim of this study was to confirm the effectiveness of putatively optimized dry (IOR) and wet (SOR) protocols for nonambulant decontamination in human volunteers. Dry and wet decontamination protocols were objectively evaluated using human volunteers. Decontamination effectiveness was quantified by liquid chromatography-mass spectrometry analysis of the recovery of a chemical warfare agent simulant (methylsalicylate) from skin and hair of volunteers, with whole-body fluorescence imaging to quantify the skin distribution of residual simulant. Both the dry and wet decontamination processes were rapid (3 and 4 min, respectively) and were effective in removing simulant from the hair and skin of volunteers, with no observable adverse effects related to skin surface spreading of contaminant. Further studies are required to assess the combined effectiveness of dry and wet decontamination under more realistic conditions and to develop appropriate operational procedures that ensure the safety of first responders.

  18. In vitro Perturbations of Targets in Cancer Hallmark Processes Predict Rodent Chemical Carcinogenesis

    Science.gov (United States)

    Thousands of untested chemicals in the environment require efficient characterization of carcinogenic potential in humans. A proposed solution is rapid testing of chemicals using in vitro high-throughput screening (HTS) assays for targets in pathways linked to disease processes ...

  19. Process Improvements to Biomass Pretreatment of Fuels and Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Teymouri, Farzaneh [Michigan Biotechnology Inst., Lansing, MI (United States)

    2015-05-30

    MBI, a 501c(3) company focusing on de-risking and scaling up bio-based technologies, has teamed with Michigan State University and the Idaho National Laboratory to develop and demonstrate process improvements to the ammonia fiber expansion (AFEX) pretreatment process. The logistical hurdles of biomass handling are well known, and the regional depot concept - in which small, distributed bioprocessing operations collect, preprocess, and densify biomass before shipping to a centralized refinery - is a promising alternative to centralized collection. AFEXTM (AFEX is a trademark of MBI) has unique features among pretreatments that would make it desirable as a pretreatment prior to densification at the depot scale. MBI has developed a novel design, using a packed bed reactor for the AFEX process that can be scaled down economically to the depot scale at a lower capital cost as compared to the traditional design (Pandia type reactor). Thus, the purpose of this project was to develop, scale-up, demonstrate, and improve this novel design The key challenges are the recovery of ammonia, consistent and complete pretreatment performance, and the overall throughput of the reactor. In this project an engineering scale packed bed AFEX system with 1-ton per day capacity was installed at MBI’s building. The system has been operational since mid-2013. During that time, MBI has demonstrated the robustness, reliability, and consistency of the process. To date, nearly 500 runs have been performed in the reactors. There have been no incidences of plugging (i.e., inability to remove ammonia from biomass after the treatment), nor has there been any instance of a major ammonia release into the atmosphere. Likewise, the sugar released via enzyme hydrolysis has remained consistent throughout these runs. Our economic model shows a 46% reduction in AFEX capital cost at the 100 ton/day scale compared to the traditional design of AFEX (Pandia type reactor). The key performance factors were

  20. Heavy oil processing impacts refinery and effluent treatment operations

    Energy Technology Data Exchange (ETDEWEB)

    Thornthwaite, P. [Nalco Champion, Northwich, Cheshire (United Kingdom)

    2013-11-01

    Heavy oils are becoming more common in Europe. The processing of heavier (opportunity or challenge) crudes, although financially attractive, introduce additional challenges to the refiner. These challenges are similar whether they come from imported crudes or in the future possibly from shale oils (tight oils). Without a strategy for understanding and mitigating the processing issues associated with these crudes, the profit potential may be eroded by decreased equipment reliability and run length. This paper focuses on the impacts at the desalter and how to manage them effectively while reducing the risks to downstream processes. Desalters have to deal with an increased viscosity, density (lower API gravity), higher solids loading, potential conductivity issues, and asphaltene stability concerns. All these factors can lead to operational problems impacting downstream of the desalter, both on the process and the water side. The other area of focus is the effluent from the desalter which can significantly impact waste water operations. This can take the form of increased oil under-carry, solids and other contaminants originating from the crudes. Nalco Champion has experience in working with these challenging crudes, not only, Azeri, Urals and African crudes, but also the Canadian oil sands, US Shale oil, heavy South American crudes and crudes containing metal naphthenates. Best practices will be shared and an outlook on the effects of Shale oil will be given. (orig.)

  1. Procafd: Computer Aided Tool for Synthesis-Design & Analysis of Chemical Process Flowsheets

    DEFF Research Database (Denmark)

    Kumar Tula, Anjan; Eden, Mario R.; Gani, Rafiqul

    2015-01-01

    and emission to the surrounding and many more. In terms of approaches to solve the synthesis-design problem three major lines of attack have emerged: (a) the knowledge based approach [1] which relies on engineering knowledge & problem insights, (b) the optimization approach [2] which relies on the use...... of mathematical programming techniques, (c) hybrid approach which combine two or more approaches. D’Anterroches [3] proposed a group contribution based hybrid approach to solve the synthesis-design problem where, chemical process flowsheets could be synthesized in the same way as atoms or groups of atoms...... parameters for the operations of the high ranked flowsheets are established through reverse engineering approaches based on driving forces available for each operation. In the final stage, rigorous simulation is performed to validate the synthesis-design. Note that since the flowsheet is synthesized...

  2. Increasing operational efficiency in a radioactive waste processing plant - 16100

    International Nuclear Information System (INIS)

    Turner, T.W.; Watson, S.N.

    2009-01-01

    The solid waste plant at Harwell in Oxfordshire, contains a purpose built facility to input, assay, visually inspect and sort remote handled intermediate level radioactive waste (RHILW). The facility includes a suite of remote handling cells, known as the head-end cells (HEC), which waste must pass through in order to be repackaged. Some newly created waste from decommissioning works on site passes through the cells, but the vast majority of waste for processing is historical waste, stored in below ground tube stores. Existing containers are not suitable for long term storage, many are already badly corroded, so the waste must be efficiently processed and repackaged in order to achieve passive safety. The Harwell site is currently being decommissioned and the land is being restored. The site is being progressively de-licensed, and redeveloped as a business park, which can only be completed when all the nuclear liabilities have been removed. The recovery and processing of old waste in the solid waste plant is a key project linked to de-licensing of a section of the site. Increasing the operational efficiency of the waste processing plant could shorten the time needed to clear the site and has the potential to save money for the Nuclear Decommissioning Authority (NDA). The waste processing facility was constructed in the mid 1990's, and commissioned in 1999. Since operations began, the yearly throughput of the cells has increased significantly every year. To achieve targets set out in the lifetime plan (LTP) for the site, throughput must continue to increase. The operations department has measured the overall equipment effectiveness (OEE) of the process for the last few years, and has used continuous improvement techniques to decrease the average cycle time. Philosophies from operational management practices such as 'lean' and 'kaizen' have been employed successfully to drive out losses and increase plant efficiency. This paper will describe how the solid waste plant

  3. The main chemical safety problems in main process of nuclear fuel reprocessing plant

    International Nuclear Information System (INIS)

    Song Fengli; Zhao Shangui; Liu Xinhua; Zhang Chunlong; Lu Dan; Liu Yuntao; Yang Xiaowei; Wang Shijun

    2014-01-01

    There are many chemical reactions in the aqueous process of nuclear fuel reprocessing. The reaction conditions and the products are different so that the chemical safety problems are different. In the paper the chemical reactions in the aqueous process of nuclear fuel reprocessing are described and the main chemical safety problems are analyzed. The reference is offered to the design and accident analysis of the nuclear fuel reprocessing plant. (authors)

  4. Purex process operation and performance: 1970 thoria campaign

    International Nuclear Information System (INIS)

    Walser, R.L.

    1978-02-01

    The Hanford Purex Plant has demonstrated suitability for reprocessing irradiated thoria (ThO 2 ) target elements on a campaign basis. A 1965 process test and major production campaigns conducted in 1966 and 1970 recovered nitrate solution form products totaling approximately 565 tons of thorium and 820 kilograms of 233 U. The overall recoveries for the 1970 campaign based on reactor input data were 94.9 percent for thorium and 95.2 percent for uranium. The primary function of the Hanford Purex Plant is reprocessing of irradiated uranium fuel elements to separate and purify uranium, plutonium and neptunium. Converting the plant to thoria reprocessing required major process development work and equipment modifications. The operation and performance of the Plant during the 1970 thoria reprocessing campaign is discussed in this report. The discussion includes background information on the process and equipment, problems encountered, and changes recommended for future campaigns

  5. Hyperplane distance neighbor clustering based on local discriminant analysis for complex chemical processes monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Chunhong; Xiao, Shaoqing; Gu, Xiaofeng [Jiangnan University, Wuxi (China)

    2014-11-15

    The collected training data often include both normal and faulty samples for complex chemical processes. However, some monitoring methods, such as partial least squares (PLS), principal component analysis (PCA), independent component analysis (ICA) and Fisher discriminant analysis (FDA), require fault-free data to build the normal operation model. These techniques are applicable after the preliminary step of data clustering is applied. We here propose a novel hyperplane distance neighbor clustering (HDNC) based on the local discriminant analysis (LDA) for chemical process monitoring. First, faulty samples are separated from normal ones using the HDNC method. Then, the optimal subspace for fault detection and classification can be obtained using the LDA approach. The proposed method takes the multimodality within the faulty data into account, and thus improves the capability of process monitoring significantly. The HDNC-LDA monitoring approach is applied to two simulation processes and then compared with the conventional FDA based on the K-nearest neighbor (KNN-FDA) method. The results obtained in two different scenarios demonstrate the superiority of the HDNC-LDA approach in terms of fault detection and classification accuracy.

  6. Hyperplane distance neighbor clustering based on local discriminant analysis for complex chemical processes monitoring

    International Nuclear Information System (INIS)

    Lu, Chunhong; Xiao, Shaoqing; Gu, Xiaofeng

    2014-01-01

    The collected training data often include both normal and faulty samples for complex chemical processes. However, some monitoring methods, such as partial least squares (PLS), principal component analysis (PCA), independent component analysis (ICA) and Fisher discriminant analysis (FDA), require fault-free data to build the normal operation model. These techniques are applicable after the preliminary step of data clustering is applied. We here propose a novel hyperplane distance neighbor clustering (HDNC) based on the local discriminant analysis (LDA) for chemical process monitoring. First, faulty samples are separated from normal ones using the HDNC method. Then, the optimal subspace for fault detection and classification can be obtained using the LDA approach. The proposed method takes the multimodality within the faulty data into account, and thus improves the capability of process monitoring significantly. The HDNC-LDA monitoring approach is applied to two simulation processes and then compared with the conventional FDA based on the K-nearest neighbor (KNN-FDA) method. The results obtained in two different scenarios demonstrate the superiority of the HDNC-LDA approach in terms of fault detection and classification accuracy

  7. National toxicology program chemical nomination and selection process

    Energy Technology Data Exchange (ETDEWEB)

    Selkirk, J.K. [National Institute of Environmental Health Sciences, Research Triangle Park, NC (United States)

    1990-12-31

    The National Toxicology Program (NTP) was organized to support national public health programs by initiating research designed to understand the physiological, metabolic, and genetic basis for chemical toxicity. The primary mandated responsibilities of NTP were in vivo and vitro toxicity testing of potentially hazardous chemicals; broadening the spectrum of toxicological information on known hazardous chemicals; validating current toxicological assay systems as well as developing new and innovative toxicity testing technology; and rapidly communicating test results to government agencies with regulatory responsibilities and to the medical and scientific communities. 2 figs.

  8. Model-Based Integrated Process Design and Controller Design of Chemical Processes

    DEFF Research Database (Denmark)

    Abd Hamid, Mohd Kamaruddin Bin

    that is typically formulated as a mathematical programming (optimization with constraints) problem is solved by the so-called reverse approach by decomposing it into four sequential hierarchical sub-problems: (i) pre-analysis, (ii) design analysis, (iii) controller design analysis, and (iv) final selection......This thesis describes the development and application of a new systematic modelbased methodology for performing integrated process design and controller design (IPDC) of chemical processes. The new methodology is simple to apply, easy to visualize and efficient to solve. Here, the IPDC problem...... are ordered according to the defined performance criteria (objective function). The final selected design is then verified through rigorous simulation. In the pre-analysis sub-problem, the concepts of attainable region and driving force are used to locate the optimal process-controller design solution...

  9. New trajectory-driven aerosol and chemical process model Chemical and Aerosol Lagrangian Model (CALM

    Directory of Open Access Journals (Sweden)

    P. Tunved

    2010-11-01

    Full Text Available A new Chemical and Aerosol Lagrangian Model (CALM has been developed and tested. The model incorporates all central aerosol dynamical processes, from nucleation, condensation, coagulation and deposition to cloud formation and in-cloud processing. The model is tested and evaluated against observations performed at the SMEAR II station located at Hyytiälä (61° 51' N, 24° 17' E over a time period of two years, 2000–2001. The model shows good agreement with measurements throughout most of the year, but fails in reproducing the aerosol properties during the winter season, resulting in poor agreement between model and measurements especially during December–January. Nevertheless, through the rest of the year both trends and magnitude of modal concentrations show good agreement with observation, as do the monthly average size distribution properties. The model is also shown to capture individual nucleation events to a certain degree. This indicates that nucleation largely is controlled by the availability of nucleating material (as prescribed by the [H2SO4], availability of condensing material (in this model 15% of primary reactions of monoterpenes (MT are assumed to produce low volatile species and the properties of the size distribution (more specifically, the condensation sink. This is further demonstrated by the fact that the model captures the annual trend in nuclei mode concentration. The model is also used, alongside sensitivity tests, to examine which processes dominate the aerosol size distribution physical properties. It is shown, in agreement with previous studies, that nucleation governs the number concentration during transport from clean areas. It is also shown that primary number emissions almost exclusively govern the CN concentration when air from Central Europe is advected north over Scandinavia. We also show that biogenic emissions have a large influence on the amount of potential CCN observed

  10. Effect of ozone gas processing on physical and chemical properties ...

    African Journals Online (AJOL)

    chemical properties of gluten proteins were investigated after treatment with .... differences in most of the visible bands among all samples. Figure 1: SDS-PAGE analysis of protein patterns in wheat gluten and glutenin, with and without ozone.

  11. Institute of Chemical Process Fundamentals of the ASCR: Expectation

    Czech Academy of Sciences Publication Activity Database

    Punčochář, Miroslav

    2013-01-01

    Roč. 62, 5-6 (2013), s. 214-215 ISSN 0022-9830 Institutional support: RVO:67985858 Keywords : laboratory investigation * large-scale applications * novel instrumentation and technology . Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  12. The importance of the reliability study for the safety operation of chemical plants. Application in heavy water plants

    International Nuclear Information System (INIS)

    Dumitrescu, Maria; Lazar, Roxana Elena; Preda, Irina Aida; Stefanescu, Ioan

    1999-01-01

    Heavy water production in Romania is based on H 2 O-H 2 S isotopic exchange process followed by vacuum isotopic distillation. The heavy water plant are complex chemical systems, characterized by an ensemble of static and dynamic equipment, AMC components, enclosures. Such equipment must have a high degree of reliability, a maximum safety in technological operation and a high availability index. Safety, reliable and economical operation heavy water plants need to maintain the systems and the components at adequate levels of reliability. The paper is a synthesis of the qualitative and quantitative assessment reliability studies for heavy water plants. The operation analysis on subsystems, each subsystems being a well-defined unit, is required by the plant complexity. For each component the reliability indicators were estimated by parametric and non-parametric methods based on the plant operation data. Also, the reliability qualitative and quantitative assessment was done using the fault tree technique. For the dual temperature isotopic exchange plants the results indicate an increase of the MTBF after the first years of operation, illustrating both the operation experience increasing and maintenance improvement. Also a high degree of availability was illustrated by the reliability studies of the vacuum distillation plant. The establishment of the reliability characteristics for heavy water plant represents an important step, a guide for highlighting the elements and process liable to failure being at the same time a planning modality to correlate the control times with the maintenance operations. This is the way to minimise maintenance, control and costs. The main purpose of the reliability study was the safety increase of the plant operation and the support for decision making. (authors)

  13. The Operational Planning Model of Transhipment Processes in the Port

    Directory of Open Access Journals (Sweden)

    Mia Jurjević

    2016-04-01

    Full Text Available Modelling of a traffic system refers to the efficiency of operations for establishing successful business performance by examining the possibilities for its improvement. The main purpose of each container terminal is to ensure continuity and dynamics of the flow of containers. The objective of this paper is to present a method for determining the amount of certain types of containers that can be transhipped at each berth, with the proper cargo handling, taking into account minimum total costs of transhipment. The mathematical model of planning the transhipment and transportation of containers at the terminal is presented. The optimal solution, obtained with the method of linear programming, represents a plan for container deployment that will ensure effective ongoing process of transhipment, providing the lowest transhipment costs. The proposed model, tested in the port of Rijeka, should be the basis for makingadequate business decisions in the operational planning of the container terminal.

  14. Safer operating conditions and optimal scaling-up process for cyclohexanone peroxide reaction

    International Nuclear Information System (INIS)

    Zang, Na; Qian, Xin-Ming; Liu, Zhen-Yi; Shu, Chi-Min

    2015-01-01

    Highlights: • Thermal hazard of cyclohexanone peroxide reaction was measured by experimental techniques. • Levenberg–Marquardt algorithm was adopted to evaluate kinetic parameters. • Safer operating conditions at laboratory scale were acquired by BDs and TDs. • The verified safer operating conditions were used to obtain the optimal scale-up parameters applied in industrial plants. - Abstract: The cyclohexanone peroxide reaction process, one of the eighteen hazardous chemical processes identified in China, is performed in indirectly cooled semibatch reactors. The peroxide reaction is added to a mixture of hydrogen peroxide and nitric acid, which form heterogeneous liquid–liquid systems. A simple and general procedure for building boundary and temperature diagrams of peroxide process is given here to account for the overall kinetic expressions. Such a procedure has been validated by comparison with experimental data. Thermally safer operating parameters were obtained at laboratory scale, and the scaled-up procedure was performed to give the minimum dosing time in an industrial plant, which is in favor of maximizing industrial reactor productivity. The results are of great significance for governing the peroxide reaction process apart from the thermal runaway region. It also greatly aids in determining optimization on operating parameters in industrial plants.

  15. Estimation of the optimal operating conditions for a radiation chemical neutralization unit

    International Nuclear Information System (INIS)

    Putilov, A.V.; Kamenetskaya, S.A.; Pshezhetskii, S.Ya.; Kazakov, M.S.; Kudryavtsev, S.L.; Petrukhin, N.V.; Misharin, B.A.; Koneev, V.Z.

    1985-01-01

    An estimate is made of the effect of the hydrodynamic conditions on the efficiency of foam units for the radiation chemical neutralization of impurities, taking into account the penetrating power of accelerated electrons having various energies. Expressions are obtained for calculating the efficiency of such units with sectionized operation of the chamber and taking account of the effect of incomplete mixing of the products of radiolysis through the height of the foam layer

  16. On the spectrum of the staggered Dirac operator at finite chemical potential

    International Nuclear Information System (INIS)

    Vink, J.C.; Nationaal Inst. voor Kernfysica en Hoge-Energiefysica

    1988-12-01

    The spectrum of the staggered Dirac operator in two-dimensional QEDF is investigated at finite chemical potential. In the quenced model, it is shown that lattice artefacts cause a spurious scattering of eigenvalues. This scattering disappears when lattice distance is taken to zero. In the unquenced model, a new approach is used to show that similar effects are absent. (author). 17 refs.; 6 figs

  17. Radium removal processes capital and operating cost estimates

    International Nuclear Information System (INIS)

    Kelly, F.J.

    1979-09-01

    An estimate of the fixed capital and operating costs for two alternative processes for the removal of dissolved Ra-226 from uranium mill effluent in Elliot Lake, Ontario is presented. Process 1 consists of barium-radium coprecipitation followed by coagulation, flocculation and sedimentation. Process 2 consists of barium-radium coprecipitation followed by gravity media filtration, sand filter backwashing and sedimentation. Cost estimates were prepared for 18 different plant configurations designed to treat 1000 and 4000 imperial gallons per minute (ig/m) of effluent, 24 hrs per day, 7 days per week and 365 days per year with several equipment options. The estimated fixed capital costs for plants equipped with gravity filters were less than those equipped with circular clarifiers. The capital costs ranged from $552,000 with a flow rate of 1000 ig/m to $2,578,000 with a flow rate of 4000 ig/m. Estimated annual operating costs, based on a plant life of 10 years, ranged from $298,000 with a flow rate of 1000 ig/m to $1,061,000 with a flow rate of 4000 ig/m

  18. Automated process flowsheet synthesis for membrane processes using genetic algorithm: role of crossover operators

    KAUST Repository

    Shafiee, Alireza

    2016-06-25

    In optimization-based process flowsheet synthesis, optimization methods, including genetic algorithms (GA), are used as advantageous tools to select a high performance flowsheet by ‘screening’ large numbers of possible flowsheets. In this study, we expand the role of GA to include flowsheet generation through proposing a modified Greedysub tour crossover operator. Performance of the proposed crossover operator is compared with four other commonly used operators. The proposed GA optimizationbased process synthesis method is applied to generate the optimum process flowsheet for a multicomponent membrane-based CO2 capture process. Within defined constraints and using the random-point crossover, CO2 purity of 0.827 (equivalent to 0.986 on dry basis) is achieved which results in improvement (3.4%) over the simplest crossover operator applied. In addition, the least variability in the converged flowsheet and CO2 purity is observed for random-point crossover operator, which approximately implies closeness of the solution to the global optimum, and hence the consistency of the algorithm. The proposed crossover operator is found to improve the convergence speed of the algorithm by 77.6%.

  19. Survey of knowledge of hazards of chemicals potentially associated with the advanced isotope separation processes

    International Nuclear Information System (INIS)

    Chester, R.O.; Kirkscey, K.A.; Randolph, M.L.

    1979-09-01

    Hazards of chemical potentially associated with the advanced isotope separation processes are estimated based on open literature references. The tentative quantity of each chemical associated with the processes and the toxicity of the chemical are used to estimate this hazard. The chemicals thus estimated to be the most potentially hazardous to health are fluorine, nitric acid, uranium metal, uranium hexafluoride, and uranium dust. The estimated next most hazardous chemicals are bromine, hydrobromic acid, hydrochloric acid, and hydrofluoric acid. For each of these chemicals and for a number of other process-associated chemicals the following information is presented: (1) any applicable standards, recommended standards and their basis; (2) a brief discussion to toxic effects including short exposure tolerance, atmospheric concentration immediately hazardous to life, evaluation of exposures, recommended control procedures, chemical properties, and a list of any toxicology reviews; and (3) recommendations for future research

  20. Survey of knowledge of hazards of chemicals potentially associated with the advanced isotope separation processes

    Energy Technology Data Exchange (ETDEWEB)

    Chester, R.O.; Kirkscey, K.A.; Randolph, M.L.

    1979-09-01

    Hazards of chemical potentially associated with the advanced isotope separation processes are estimated based on open literature references. The tentative quantity of each chemical associated with the processes and the toxicity of the chemical are used to estimate this hazard. The chemicals thus estimated to be the most potentially hazardous to health are fluorine, nitric acid, uranium metal, uranium hexafluoride, and uranium dust. The estimated next most hazardous chemicals are bromine, hydrobromic acid, hydrochloric acid, and hydrofluoric acid. For each of these chemicals and for a number of other process-associated chemicals the following information is presented: (1) any applicable standards, recommended standards and their basis; (2) a brief discussion to toxic effects including short exposure tolerance, atmospheric concentration immediately hazardous to life, evaluation of exposures, recommended control procedures, chemical properties, and a list of any toxicology reviews; and (3) recommendations for future research.

  1. Operating The Central Process Systems At Glenn Research Center

    Science.gov (United States)

    Weiler, Carly P.

    2004-01-01

    As a research facility, the Glenn Research Center (GRC) trusts and expects all the systems, controlling their facilities to run properly and efficiently in order for their research and operations to occur proficiently and on time. While there are many systems necessary for the operations at GRC, one of those most vital systems is the Central Process Systems (CPS). The CPS controls operations used by GRC's wind tunnels, propulsion systems lab, engine components research lab, and compressor, turbine and combustor test cells. Used widely throughout the lab, it operates equipment such as exhausters, chillers, cooling towers, compressors, dehydrators, and other such equipment. Through parameters such as pressure, temperature, speed, flow, etc., it performs its primary operations on the major systems of Electrical Dispatch (ED), Central Air Dispatch (CAD), Central Air Equipment Building (CAEB), and Engine Research Building (ERB). In order for the CPS to continue its operations at Glenn, a new contract must be awarded. Consequently, one of my primary responsibilities was assisting the Source Evaluation Board (SEB) with the process of awarding the recertification contract of the CPS. The job of the SEB was to evaluate the proposals of the contract bidders and then to present their findings to the Source Selecting Official (SSO). Before the evaluations began, the Center Director established the level of the competition. For this contract, the competition was limited to those companies classified as a small, disadvantaged business. After an industry briefing that explained to qualified companies the CPS and type of work required, each of the interested companies then submitted proposals addressing three components: Mission Suitability, Cost, and Past Performance. These proposals were based off the Statement of Work (SOW) written by the SEB. After companies submitted their proposals, the SEB reviewed all three components and then presented their results to the SSO. While the

  2. Process integration of chemical looping combustion with oxygen uncoupling in a coal-fired power plant

    International Nuclear Information System (INIS)

    Spinelli, Maurizio; Peltola, Petteri; Bischi, Aldo; Ritvanen, Jouni; Hyppänen, Timo; Romano, Matteo C.

    2016-01-01

    High-temperature solid looping processes for CCS (carbon capture and storage) represent a class of promising technologies that enables CO2 capture with relatively low net efficiency penalties. The novel concept of the CLOU (Chemical Looping with Oxygen Uncoupling) process is based on a system of two interconnected fluidized bed reactors that operate at atmospheric pressure. In the fuel reactor, the capability of certain metal oxides to spontaneously release molecular oxygen at high temperatures is exploited to promote the direct conversion of coal in an oxygen-rich atmosphere. As a novel CO_2 capture concept, the CLOU process requires the optimization of design and operation parameters, which may substantially influence the total power plant performance. This study approaches this issue by performing joint simulations of CLOU reactors using a 1.5D model and a steam cycle power plant. A sensitivity analysis has been performed to investigate the performance and main technical issues that are related to the integration of a CLOU island in a state-of-the-art USC (ultra-supercritical) power plant. In particular, the effect of the key process parameters has been evaluated. Superior performance has been estimated for the power plant, with electrical efficiencies of approximately 42% and more than 95% CO2 avoided. - Highlights: • Process modeling and simulation of CLOU integrated in USC coal power plant carried out. • Comprehensive sensitivity analysis on Cu-based CLOU process performed. • Electrical efficiencies of 42% and more than 95% CO_2 avoided obtained. • Reactor size and operating conditions suitable for industrial applications.

  3. Generalized Least Energy of Separation for Desalination and Other Chemical Separation Processes

    Directory of Open Access Journals (Sweden)

    Karan H. Mistry

    2013-05-01

    Full Text Available Increasing global demand for fresh water is driving the development and implementation of a wide variety of seawater desalination technologies driven by different combinations of heat, work, and chemical energy. This paper develops a consistent basis for comparing the energy consumption of such technologies using Second Law efficiency. The Second Law efficiency for a chemical separation process is defined in terms of the useful exergy output, which is the minimum least work of separation required to extract a unit of product from a feed stream of a given composition. For a desalination process, this is the minimum least work of separation for producing one kilogram of product water from feed of a given salinity. While definitions in terms of work and heat input have been proposed before, this work generalizes the Second Law efficiency to allow for systems that operate on a combination of energy inputs, including fuel. The generalized equation is then evaluated through a parametric study considering work input, heat inputs at various temperatures, and various chemical fuel inputs. Further, since most modern, large-scale desalination plants operate in cogeneration schemes, a methodology for correctly evaluating Second Law efficiency for the desalination plant based on primary energy inputs is demonstrated. It is shown that, from a strictly energetic point of view and based on currently available technology, cogeneration using electricity to power a reverse osmosis system is energetically superior to thermal systems such as multiple effect distillation and multistage flash distillation, despite the very low grade heat input normally applied in those systems.

  4. Endocrine-Disrupting Chemicals and Oil and Natural Gas Operations: Potential Environmental Contamination and Recommendations to Assess Complex Environmental Mixtures.

    Science.gov (United States)

    Kassotis, Christopher D; Tillitt, Donald E; Lin, Chung-Ho; McElroy, Jane A; Nagel, Susan C

    2016-03-01

    Hydraulic fracturing technologies, developed over the last 65 years, have only recently been combined with horizontal drilling to unlock oil and gas reserves previously deemed inaccessible. Although these technologies have dramatically increased domestic oil and natural gas production, they have also raised concerns for the potential contamination of local water supplies with the approximately 1,000 chemicals that are used throughout the process, including many known or suspected endocrine-disrupting chemicals. We discuss the need for an endocrine component to health assessments for drilling-dense regions in the context of hormonal and antihormonal activities for chemicals used. We discuss the literature on a) surface and groundwater contamination by oil and gas extraction operations, and b) potential human exposure, particularly in the context of the total hormonal and antihormonal activities present in surface and groundwater from natural and anthropogenic sources; we also discuss initial analytical results and critical knowledge gaps. In light of the potential for environmental release of oil and gas chemicals that can disrupt hormone receptor systems, we recommend methods for assessing complex hormonally active environmental mixtures. We describe a need for an endocrine-centric component for overall health assessments and provide information supporting the idea that using such a component will help explain reported adverse health trends as well as help develop recommendations for environmental impact assessments and monitoring programs.

  5. Endocrine-disrupting chemicals and oil and natural gas operations: Potential environmental contamination and recommendations to assess complex environmental mixtures

    Science.gov (United States)

    Kassotis, Christopher D.; Tillitt, Donald E.; Lin, Chung-Ho; McElroy, Jane A.; Nagel, Susan C.

    2016-01-01

    Background: Hydraulic fracturing technologies, developed over the last 65 years, have only recently been combined with horizontal drilling to unlock oil and gas reserves previously deemed inaccessible. While these technologies have dramatically increased domestic oil and natural gas production, they have also raised concerns for the potential contamination of local water supplies with the approximately 1,000 chemicals used throughout the process, including many known or suspected endocrine-disrupting chemicals.Objectives: We discuss the need for an endocrine component to health assessments for drilling-dense regions in the context of hormonal and anti-hormonal activities for chemicals used.Methods: We discuss the literature on 1) surface and ground water contamination by oil and gas extraction operations, and 2) potential human exposure, particularly in context of the total hormonal and anti-hormonal activities present in surface and ground water from natural and anthropogenic sources, with initial analytical results and critical knowledge gaps discussed.Discussion: In light of the potential for environmental release of oil and gas chemicals that can disrupt hormone receptor systems, we recommend methods for assessing complex hormonally active environmental mixtures.Conclusions: We describe a need for an endocrine-centric component for overall health assessments and provide supporting information that using this may help explain reported adverse health trends as well as help develop recommendations for environmental impact assessments and monitoring programs.

  6. Fabrication of ruthenium thin film and characterization of its chemical mechanical polishing process

    International Nuclear Information System (INIS)

    Chou, Yi-Sin; Yen, Shi-Chern; Jeng, King-Tsai

    2015-01-01

    The fabrication of Ru thin film is conducted on titanium (Ti)-based rotating disk electrodes (RDE) by electrodeposition and characteristics of its chemical mechanical polishing (CMP) are investigated to be employed for copper diffusion layer applications in various semiconductor-device interconnects. The electrodeposits obtained under different electrodeposition conditions are characterized using atomic force microscope (AFM) and field emission scanning electron microscope (FESEM). Experimental results indicate that the Ru electrodeposition exhibits a Tafel behavior with a 2e metal ion reduction process. Both exchange current density and cathodic transfer coefficient are determined. A quasi Koutecky–Levich analysis is proposed to analyze the electrodeposition processes under different applied current density conditions and the activation overpotentials together with electrodeposition rate constants are obtained. For Ru CMP operations, slurries containing metal-free 2wt% ammonium persulfate and 2wt% silica abrasive at various pH values are employed. Potentiodynamic polarization studies indicate that the corrosion current density varies in the presence of ammonia while the static etch rate remains low. Both chemical and mechanical effects are investigated and analyzed, and the CMP efficacy factors are obtained. - Highlights: • Ru electrodeposition is a 2e metal ion reduction process with Tafel behavior. • Ru electrodeposition on Ti RDE fits a quasi Koutecky–Levich equation. • Metal-free slurry is employed for CMP operation to avoid contamination. • The Ru CMP process is affected by the surface condition and the pH of slurry. • The CMP efficacy factor should be high in order to obtain a smooth surface

  7. Fabrication of ruthenium thin film and characterization of its chemical mechanical polishing process

    Energy Technology Data Exchange (ETDEWEB)

    Chou, Yi-Sin [Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Yen, Shi-Chern, E-mail: scyen@ntu.edu.tw [Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Jeng, King-Tsai [Research Division I, TIER, 7F, No. 16-8, Dehuei St., Taipei 10461, Taiwan (China)

    2015-07-15

    The fabrication of Ru thin film is conducted on titanium (Ti)-based rotating disk electrodes (RDE) by electrodeposition and characteristics of its chemical mechanical polishing (CMP) are investigated to be employed for copper diffusion layer applications in various semiconductor-device interconnects. The electrodeposits obtained under different electrodeposition conditions are characterized using atomic force microscope (AFM) and field emission scanning electron microscope (FESEM). Experimental results indicate that the Ru electrodeposition exhibits a Tafel behavior with a 2e metal ion reduction process. Both exchange current density and cathodic transfer coefficient are determined. A quasi Koutecky–Levich analysis is proposed to analyze the electrodeposition processes under different applied current density conditions and the activation overpotentials together with electrodeposition rate constants are obtained. For Ru CMP operations, slurries containing metal-free 2wt% ammonium persulfate and 2wt% silica abrasive at various pH values are employed. Potentiodynamic polarization studies indicate that the corrosion current density varies in the presence of ammonia while the static etch rate remains low. Both chemical and mechanical effects are investigated and analyzed, and the CMP efficacy factors are obtained. - Highlights: • Ru electrodeposition is a 2e metal ion reduction process with Tafel behavior. • Ru electrodeposition on Ti RDE fits a quasi Koutecky–Levich equation. • Metal-free slurry is employed for CMP operation to avoid contamination. • The Ru CMP process is affected by the surface condition and the pH of slurry. • The CMP efficacy factor should be high in order to obtain a smooth surface.

  8. Characterizing aquifer hydrogeology and anthropogenic chemical influences on groundwater near the Idaho Chemical Processing Plant, Idaho National Engineering Laboratory, Idaho

    International Nuclear Information System (INIS)

    Fromm, J.M.

    1995-01-01

    A conceptual model of the Eastern Snake River Plain aquifer in the vicinity of monitoring well USGS-44, downgradient of the Idaho Chemical Processing Plant (ICPP) on the Idaho National Engineering Laboratory (INEL), was developed by synthesis and comparison of previous work (40 years) and new investigations into local natural hydrogeological conditions and anthropogenic influences. Quantitative tests of the model, and other recommendations are suggested. The ICPP recovered fissionable uranium from spent nuclear fuel rods and disposed of waste fluids by release to the regional aquifer and lithosphere. Environmental impacts were assessed by a monitoring well network. The conceptual model identifies multiple, highly variable, interacting, and transient components, including INEL facilities multiple operations and liquid waste handling, systems; the anisotropic, in homogeneous aquifer; the network of monitoring and production wells, and the intermittent flow of the Big Lost River. Pre anthropogenic natural conditions and early records of anthropogenic activities were sparsely or unreliably documented making reconstruction of natural conditions or early hydrologic impacts impossible or very broad characterizations

  9. Flow-Injection Responses of Diffusion Processes and Chemical Reactions

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    2000-01-01

    tool of automated analytical chemistry. The need for an even lower consumption of chemicals and for computer analysis has motivated a study of the FIA peak itself, that is, a theoretical model was developed, that provides detailed knowledge of the FIA profile. It was shown that the flow in a FIA...... manifold may be characterised by a diffusion coefficient that depends on flow rate, denoted as the kinematic diffusion coefficient. The description was applied to systems involving species of chromium, both in the case of simple diffusion and in the case of chemical reactions. It is suggested that it may...... be used in the resolution of FIA profiles to obtain information about the content of interference’s, in the study of chemical reaction kinetics and to measure absolute concentrations within the FIA-detector cell....

  10. Design and operation of a remotely operated plutonium waste size reduction and material handling process

    International Nuclear Information System (INIS)

    Stewart, J.A. III; Charlesworth, D.L.

    1986-01-01

    Noncombustible 238 Pu and 239 Pu waste is generated as a result of normal operation and decommissioning activity at the Savannah River Plant, and is being retrievably stored there. As part of the long-term plant to process the stored waste and current waste for permanent disposal, a remote size reduction and material handling process is being cold-tested at Savannah River Laboratory. The process consists of a large, low-speed shredder and material handling system, a remote worktable, a bagless transfer system, and a robotically controlled manipulator. Initial testing of the shredder and material handling system and a cycle test of the bagless transfer system has been completed. Fabrication and acceptance testing of the Telerobat, a robotically controlled manipulator has been completed. Testing is scheduled to begin in 3/86. Design features maximizing the ability to remotely maintain the equipment were incorporated. Complete cold-testing of the equipment is scheduled to be completed in 1987

  11. Liquid radwaste processing, operational experience utilizing Duratek Mobile Process System (MPS)

    International Nuclear Information System (INIS)

    Hunkele, W.; Jensen, C.E.; Duratek Corp., Beltsville, MD)

    1985-01-01

    The use of Duratek's Mobile Process System (MPS) employing sluiceable pressure vessels and improved operational techniques generates operational efficiencies including volume reduction (VR), reduced personnel labor and exposure and higher flowrates for cleanup of liquid radwaste streams in an operating nuclear power plant (Salem Generating Station). Significant additional VR is achievable based on laboratory and on-site experience utilizing Durasil 70. Under high conductivity, actual waste stream conditions, this proprietary media has demonstrated through-puts of a magnitude 15 times higher than organic cation resin. A long-term problem, cobalt species removal, is mitigated by this media

  12. Laser studies of chemical reaction and collision processes

    Energy Technology Data Exchange (ETDEWEB)

    Flynn, G. [Columbia Univ., New York, NY (United States)

    1993-12-01

    This work has concentrated on several interrelated projects in the area of laser photochemistry and photophysics which impinge on a variety of questions in combustion chemistry and general chemical kinetics. Infrared diode laser probes of the quenching of molecules with {open_quotes}chemically significant{close_quotes} amounts of energy in which the energy transferred to the quencher has, for the first time, been separated into its vibrational, rotational, and translational components. Probes of quantum state distributions and velocity profiles for atomic fragments produced in photodissociation reactions have been explored for iodine chloride.

  13. Intelligent process control operator aid -- An artificial intelligence approach

    International Nuclear Information System (INIS)

    Sharma, D.D.; Miller, D.D.; Hajek, B.; Chandrasekaran, B.

    1986-01-01

    This paper describes an approach for designing intelligent process and power plant control operator aids. It is argued that one of the key aspects of an intelligent operator aid is the capability for dynamic procedure synthesis with incomplete definition of initial state, unknown goal states, and the dynamic world situation. The dynamic world state is used to determine the goal, select appropriate plan steps from prespecified procedures to achieve the goal, control the execution of the synthesized plan, and provide for dynamic recovery from failure often using a goal hierarchy. The dynamic synthesis of a plan requires integration of various problems solving capabilities such as plan generation, plan synthesis, plan modification, and failure recovery from a plan. The programming language for implementing the DPS framework provides a convenient tool for developing applications. An application of the DPS approach to a Nuclear Power Plant emergency procedure synthesis is also described. Initial test results indicate that the approach is successful in dynamically synthesizing the procedures. The authors realize that the DPS framework is not a solution for all control tasks. However, many existing process and plant control problems satisfy the requirements discussed in the paper and should be able to benefit from the framework described

  14. Minimally Processed Functional Foods: Technological and Operational Pathways.

    Science.gov (United States)

    Rodgers, Svetlana

    2016-10-01

    This paper offers a concise review of technical and operational concepts underpinning commercialization of minimally processed functional foods (FFs), foods with fresh-like qualities commanding premium prices. The growing number of permitted nutritional content/health claims, many of which relate to well-being, coupled with emerging extraction and food processing technologies offers new exciting opportunities for small and medium size enterprises (SMEs) specializing in fresh produce to play an active role in the health market. Supporting SMEs, governments could benefit from savings in healthcare costs and value creation in the economy. Consumers could benefit from novel FF formats such as refrigerated RTE (ready-to-eat) meals, a variety of fresh-like meat-, fish-, and egg-based products, fresh-cut fruits and vegetables, cereal-based fermented foods and beverages. To preserve these valuable commodities, mild biological (enzymatic treatment, fermentation and, bio-preservation) and engineering solutions are needed. The latter include nonthermal techniques such as high-pressure treatment, cook-chill, sous-vide, mirco-encapsulation, vacuum impregnation and others. "De-constructive" culinary techniques such as 3D food printing and molecular gastronomy as well as developments in nutrigenomics and digital technologies facilitate novel product formats, personalization and access to niche markets. In the operational sense, moving from nourishment to health improvement demands a shift from defensive market-oriented to offensive market-developing strategies including collaborative networks with research organizations. © 2016 Institute of Food Technologists®.

  15. Using online analytical processing to manage emergency department operations.

    Science.gov (United States)

    Gordon, Bradley D; Asplin, Brent R

    2004-11-01

    The emergency department (ED) is a unique setting in which to explore and evaluate the utility of information technology to improve health care operations. A potentially useful software tool in managing this complex environment is online analytical processing (OLAP). An OLAP system has the ability to provide managers, providers, and researchers with the necessary information to make decisions quickly and effectively by allowing them to examine patterns and trends in operations and patient flow. OLAP software quickly summarizes and processes data acquired from a variety of data sources, including computerized ED tracking systems. It allows the user to form a comprehensive picture of the ED from both system-wide and patient-specific perspectives and to interactively view the data using an approach that meets his or her needs. This article describes OLAP software tools and provides examples of potential OLAP applications for care improvement projects, primarily from the perspective of the ED. While OLAP is clearly a helpful tool in the ED, it is far more useful when integrated into the larger continuum of health information systems across a hospital or health care delivery system.

  16. Energetic analysis of fruit juice processing operations in Nigeria

    Energy Technology Data Exchange (ETDEWEB)

    Waheed, M.A.; Imeokparia, O.E. [Ladoke Akintola University of Technology, Ogbomoso, Oyo State (Nigeria). Mechanical Engineering Department; Jekayinfa, S.O.; Ojediran, J.O. [Ladoke Akintola University of Technology, Ogbomoso, Oyo State (Nigeria). Agricultural Engineering Department

    2008-01-15

    Energy and exergy studies were conducted in an orange juice manufacturing industry in Nigeria to determine the energy consumption pattern and methods of energy optimization in the company. An adaptation of the process analysis method of energy accounting was used to evaluate the energy requirement for each of the eight defined unit operations. The types of energy used in the manufacturing of orange juice were electrical, steam and manual with the respective proportions of 18.51%, 80.91% and 0.58% of the total energy. It was estimated that an average energy intensity of 1.12 MJ/kg was required for the manufacturing of orange juice. The most energy intensive operation was identified as the pasteurizer followed by packaging unit with energy intensities of 0.932 and 0.119 MJ/kg, respectively. The exergy analysis revealed that the pasteurizer was responsible for most of the inefficiency (over 90%) followed by packaging (6.60%). It was suggested that the capacity of the pasteurizer be increased to reduce the level of inefficiency of the plant. The suggestion has been limited to equipment modification rather than process alteration, which constitutes additional investment cost and may not be economical from an energy savings perspective. (author)

  17. Operator support and diagnostic reasoning in an industrial process

    Energy Technology Data Exchange (ETDEWEB)

    Aaker, O.

    1996-12-31

    Efficient use of energy in production plants requires that the various processes are well controlled. The main focus of this doctoral thesis is on detection of errors and malfunctions using analytical redundancy and on state estimation using an open loop nonlinear model. A ``residual`` is present if a system does not behave as expected, or if a certain rule is violated. ``Reasoning`` is the action of finding process malfunctions based on observed residuals. The thesis applies a new formalism for comparing diagnostic reasoning methods both in terms of what knowledge is used and how it is used, and suggests a formal model of what is known about the process. The formalism is used to illustrate the difference between diagnostic reasoning based on physically interconnected process units and streams, and reasoning about goals and functions for finding a diagnosis. As an example of application, results and experiences from a test implementation using an open loop model for operator support in a complex fertilizer factory are reported. 108 refs., 61 figs., 37 tabs.

  18. 75 FR 36306 - Chemical Mixtures Containing Listed Forms of Phosphorus and Change in Application Process

    Science.gov (United States)

    2010-06-25

    ... have large industrial uses. Regulated chemical mixtures are not items having common household uses... and others from exposure to the toxic chemicals left behind. Executive Order 12988 This regulation... 1117-AA66 Chemical Mixtures Containing Listed Forms of Phosphorus and Change in Application Process...

  19. Dynamic Processes of Conceptual Change: Analysis of Constructing Mental Models of Chemical Equilibrium.

    Science.gov (United States)

    Chiu, Mei-Hung; Chou, Chin-Cheng; Liu, Chia-Ju

    2002-01-01

    Investigates students' mental models of chemical equilibrium using dynamic science assessments. Reports that students at various levels have misconceptions about chemical equilibrium. Involves 10th grade students (n=30) in the study doing a series of hands-on chemical experiments. Focuses on the process of constructing mental models, dynamic…

  20. Baseline risk assessment for groundwater operable units at the Chemical Plant Area and the Ordnance Works Area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-14

    The U.S. Department of Energy (DOE) and the U.S. Department of the Army (DA) are evaluating conditions in groundwater and springs at the DOE chemical plant area and the DA ordnance works area near Weldon Spring, Missouri. The two areas are located in St. Charles County, about 48 km (30 mi) west of St. Louis. The 88-ha (217-acre) chemical plant area is chemically and radioactively contaminated as a result of uranium-processing activities conducted by the U.S. Atomic Energy Commission in the 1950s and 1960s and explosives-production activities conducted by the U.S. Army (Army) in the 1940s. The 6,974-ha (17,232-acre) ordnance works area is primarily chemically contaminated as a result of trinitrotoluene (TNT) and dinitrotoluene (DNT) manufacturing activities during World War II. This baseline risk assessment (BRA) is being conducted as part of the remedial investigation/feasibility study (RUFS) required under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980, as amended. The purpose of the BRA is to evaluate potential human health and ecological impacts from contamination associated with the groundwater operable units (GWOUs) of the chemical plant area and ordnance works area. An RI/FS work plan issued jointly in 1995 by the DOE and DA (DOE 1995) analyzed existing conditions at the GWOUs. The work plan included a conceptual hydrogeological model based on data available when the report was prepared; this model indicated that the aquifer of concern is common to both areas. Hence, to optimize further data collection and interpretation efforts, the DOE and DA have decided to conduct a joint RI/BRA. Characterization data obtained from the chemical plant area wells indicate that uranium is present at levels slightly higher than background, with a few concentrations exceeding the proposed U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) of 20 {micro}g/L (EPA 1996c). Concentrations of other radionuclides (e

  1. Evaluation and development of process operators' working practices

    International Nuclear Information System (INIS)

    Norros, L.

    1998-01-01

    The practical aim of our research was to enhance the safety of NPP operations through the development of competencies and design of man-machine interfaces, and through contributing to safety management by providing better human reliability assessment methods. A prerequisite for achievements in these issues is understanding of the nature of the work in the NPP. We have focused on the comprehension of the control room operators' core task. With the premise of the intentional nature of human activity we have developed a new contextual approach for the analysis of activity in real-life situations. It is called the Contextual Analysis of Working Practices (CAWP). Habit of action is a central concept, and we have proposed a practical way to identify habits of action through the analysis of the actors' ways of taking account of the possibilities and constraints of the situation and of using available resources. We have carried out empirical studies in two nuclear power plants and executed four series of simulator experiments. This has taken place in close co-operation with the simulator trainers and experts of the plants, and nearly all control room crews of these plants have been involved. The central result of this work is the development of the CAWP methodology. With the help of it we have identified differences in the NPP operators' working practices that seem to have relevance for the adequacy of process control. We have also found indications of the significance of working practices for a situationally adaptive use of information aids in the control room, which ought to be verified later. Our research method has been adapted for a routinely used simulator training method. Moreover, the methodology has been applied as a tool in the validation of control room information aids, and incorporated into a new dynamic human reliability method (not discussed here). (orig.)

  2. Conceptual design of SO3 decomposer for thermo-chemical iodine-sulfur process pilot plant

    International Nuclear Information System (INIS)

    Akihiro Kanagawa; Seiji Kasahara; Atsuhiko Terada; Shinji Kubo; Ryutaro Hino; Yoshiyuki Kawahara; Masaharu Watabe; Hiroshi Fukui; Kazuo Ishino; Toshio Takahashi

    2005-01-01

    Thermo-chemical water-splitting cycle is a method to make an effective use of the high temperature nuclear heat for hydrogen production. Japan Atomic Energy Research Institute (JAERI) has been conducting R and D on HTGR and also on thermo-chemical hydrogen production by using a thermo-chemical iodine-sulfur cycle (IS process). Based on the test results and know-how obtained through a bench-scale tests of hydrogen production of about 30 NL/hr, JAERI has a plan to construct a pilot test plant heated by high temperature helium gas, which has a hydrogen production performance of 30 Nm 3 /hr and will be operated under the high pressure up to 2 MPa. One of the key components of the pilot test plant is a SO 3 decomposer under high temperature conditions up to 850 degree C and high pressure up to 2 MPa. In this paper, a concept of the SO 3 decomposer for the pilot test plant fabricated with SiC ceramics, a corrosion-resistant material is investigated. Preliminary analyses on temperature and flow-rate distributions in the SO 3 decomposer and on thermal stress were carried out. A SO 3 decomposer model was experimentally manufactured. (authors)

  3. Biochemical Conversion Processes of Lignocellulosic Biomass to Fuels and Chemicals - A Review.

    Science.gov (United States)

    Brethauer, Simone; Studer, Michael H

    2015-01-01

    Lignocellulosic biomass - such as wood, agricultural residues or dedicated energy crops - is a promising renewable feedstock for production of fuels and chemicals that is available at large scale at low cost without direct competition for food usage. Its biochemical conversion in a sugar platform biorefinery includes three main unit operations that are illustrated in this review: the physico-chemical pretreatment of the biomass, the enzymatic hydrolysis of the carbohydrates to a fermentable sugar stream by cellulases and finally the fermentation of the sugars by suitable microorganisms to the target molecules. Special emphasis in this review is put on the technology, commercial status and future prospects of the production of second-generation fuel ethanol, as this process has received most research and development efforts so far. Despite significant advances, high enzyme costs are still a hurdle for large scale competitive lignocellulosic ethanol production. This could be overcome by a strategy termed 'consolidated bioprocessing' (CBP), where enzyme production, enzymatic hydrolysis and fermentation is integrated in one step - either by utilizing one genetically engineered superior microorganism or by creating an artificial co-culture. Insight is provided on both CBP strategies for the production of ethanol as well as of advanced fuels and commodity chemicals.

  4. Thermodynamic and chemical engineering problems arising with hybride processes

    International Nuclear Information System (INIS)

    Hunsaenger, K.

    1981-01-01

    Marginal parameters and definitions are set up for the NaK-NaKH cyclic process, the vapour-phase electrolysis on the basis of carbonates, high-temperature electrolysis using borax, the HCl/NaLiNO 3 cyclic process and the methane/methanol cyclic process. Such parameters and definitions are to create uniform conditions for the process design. (DG) [de

  5. Operational Implementation of the MARSSIM Process at the Wayne Interim Storage Site

    International Nuclear Information System (INIS)

    Hays, D. C. Jr.; Trujillo, P. A. IV.; Zoller, S. G.

    2002-01-01

    This paper describes the methodologies behind the operational implementation of the Multi Agency Radiation Site Survey and Investigation Manual (MARSSIM) process at the Wayne Interim Storage Site (WISS). The United States Army Corps of Engineers (USACE) and Environmental Chemical Corporation (ECC) have implemented the MARSSIM process using various surveys producing raw data. The final remedial status of a survey unit is derived through data reduction, while maintaining a high degree of efficiency in the construction aspects of the remedial action. Data reduction of field measurements is accomplished by merging the data outputs of a Digital Global Positioning System, an exposure rate meter, and laboratory analyses to produce maps which present exposure rates, elevations, survey unit boundaries, direct measurement locations, and sampling locations on a single map. The map serves as a data-posting plot and allows the project team to easily judge the survey unit's remedial status. The operational implementation of the MARSSIM process has been successful in determining the eligibility of survey units for final status surveys at the WISS and also in demonstrating final status radiological and chemical conditions while maintaining an efficient remedial action effort

  6. 19 CFR 10.178 - Direct costs of processing operations performed in the beneficiary developing country.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Direct costs of processing operations performed in... processing operations performed in the beneficiary developing country. (a) Items included in the direct costs of processing operations. As used in § 10.176, the words “direct costs of processing operations...

  7. TREATMENT TANK CORROSION STUDIES FOR THE ENHANCED CHEMICAL CLEANING PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Wiersma, B.

    2011-08-24

    Radioactive waste is stored in high level waste tanks on the Savannah River Site (SRS). Savannah River Remediation (SRR) is aggressively seeking to close the non-compliant Type I and II waste tanks. The removal of sludge (i.e., metal oxide) heels from the tank is the final stage in the waste removal process. The Enhanced Chemical Cleaning (ECC) process is being developed and investigated by SRR to aid in Savannah River Site (SRS) High-Level Waste (HLW) as an option for sludge heel removal. Corrosion rate data for carbon steel exposed to the ECC treatment tank environment was obtained to evaluate the degree of corrosion that occurs. These tests were also designed to determine the effect of various environmental variables such as temperature, agitation and sludge slurry type on the corrosion behavior of carbon steel. Coupon tests were performed to estimate the corrosion rate during the ECC process, as well as determine any susceptibility to localized corrosion. Electrochemical studies were performed to develop a better understanding of the corrosion mechanism. The tests were performed in 1 wt.% and 2.5 wt.% oxalic acid with HM and PUREX sludge simulants. The following results and conclusions were made based on this testing: (1) In 1 wt.% oxalic acid with a sludge simulant, carbon steel corroded at a rate of less than 25 mpy within the temperature and agitation levels of the test. No susceptibility to localized corrosion was observed. (2) In 2.5 wt.% oxalic acid with a sludge simulant, the carbon steel corrosion rates ranged between 15 and 88 mpy. The most severe corrosion was observed at 75 C in the HM/2.5 wt.% oxalic acid simulant. Pitting and general corrosion increased with the agitation level at this condition. No pitting and lower general corrosion rates were observed with the PUREX/2.5 wt.% oxalic acid simulant. The electrochemical and coupon tests both indicated that carbon steel is more susceptible to localized corrosion in the HM/oxalic acid environment than

  8. Treatment Tank Corrosion Studies For The Enhanced Chemical Cleaning Process

    International Nuclear Information System (INIS)

    Wiersma, B.

    2011-01-01

    Radioactive waste is stored in high level waste tanks on the Savannah River Site (SRS). Savannah River Remediation (SRR) is aggressively seeking to close the non-compliant Type I and II waste tanks. The removal of sludge (i.e., metal oxide) heels from the tank is the final stage in the waste removal process. The Enhanced Chemical Cleaning (ECC) process is being developed and investigated by SRR to aid in Savannah River Site (SRS) High-Level Waste (HLW) as an option for sludge heel removal. Corrosion rate data for carbon steel exposed to the ECC treatment tank environment was obtained to evaluate the degree of corrosion that occurs. These tests were also designed to determine the effect of various environmental variables such as temperature, agitation and sludge slurry type on the corrosion behavior of carbon steel. Coupon tests were performed to estimate the corrosion rate during the ECC process, as well as determine any susceptibility to localized corrosion. Electrochemical studies were performed to develop a better understanding of the corrosion mechanism. The tests were performed in 1 wt.% and 2.5 wt.% oxalic acid with HM and PUREX sludge simulants. The following results and conclusions were made based on this testing: (1) In 1 wt.% oxalic acid with a sludge simulant, carbon steel corroded at a rate of less than 25 mpy within the temperature and agitation levels of the test. No susceptibility to localized corrosion was observed. (2) In 2.5 wt.% oxalic acid with a sludge simulant, the carbon steel corrosion rates ranged between 15 and 88 mpy. The most severe corrosion was observed at 75 C in the HM/2.5 wt.% oxalic acid simulant. Pitting and general corrosion increased with the agitation level at this condition. No pitting and lower general corrosion rates were observed with the PUREX/2.5 wt.% oxalic acid simulant. The electrochemical and coupon tests both indicated that carbon steel is more susceptible to localized corrosion in the HM/oxalic acid environment than

  9. Knowledge acquisition on hazards in chemical and process industry

    International Nuclear Information System (INIS)

    Vojnovic, D.; Kozuh, M.

    1992-01-01

    The knowledge acquisition for probabilistic risk assessment and operational safety improvements are described. The procedure HazOp (Hazard and Operability Study) are used for hazard identification. The acquainted knowledge is condensed in the form of cause-consequence matrix which is very convenient for plant logic model start point definition. At the end, the possibility for HazOp performance support by use of Artificial Intelligence approach is considered. (author) [sl

  10. Screening and prioritisation of chemical risks from metal mining operations, identifying exposure media of concern.

    Science.gov (United States)

    Pan, Jilang; Oates, Christopher J; Ihlenfeld, Christian; Plant, Jane A; Voulvoulis, Nikolaos

    2010-04-01

    Metals have been central to the development of human civilisation from the Bronze Age to modern times, although in the past, metal mining and smelting have been the cause of serious environmental pollution with the potential to harm human health. Despite problems from artisanal mining in some developing countries, modern mining to Western standards now uses the best available mining technology combined with environmental monitoring, mitigation and remediation measures to limit emissions to the environment. This paper develops risk screening and prioritisation methods previously used for contaminated land on military and civilian sites and engineering systems for the analysis and prioritisation of chemical risks from modern metal mining operations. It uses hierarchical holographic modelling and multi-criteria decision making to analyse and prioritise the risks from potentially hazardous inorganic chemical substances released by mining operations. A case study of an active platinum group metals mine in South Africa is used to demonstrate the potential of the method. This risk-based methodology for identifying, filtering and ranking mining-related environmental and human health risks can be used to identify exposure media of greatest concern to inform risk management. It also provides a practical decision-making tool for mine acquisition and helps to communicate risk to all members of mining operation teams.

  11. Research on chemical vapor deposition processes for advanced ceramic coatings

    Science.gov (United States)

    Rosner, Daniel E.

    1993-01-01

    Our interdisciplinary background and fundamentally-oriented studies of the laws governing multi-component chemical vapor deposition (VD), particle deposition (PD), and their interactions, put the Yale University HTCRE Laboratory in a unique position to significantly advance the 'state-of-the-art' of chemical vapor deposition (CVD) R&D. With NASA-Lewis RC financial support, we initiated a program in March of 1988 that has led to the advances described in this report (Section 2) in predicting chemical vapor transport in high temperature systems relevant to the fabrication of refractory ceramic coatings for turbine engine components. This Final Report covers our principal results and activities for the total NASA grant of $190,000. over the 4.67 year period: 1 March 1988-1 November 1992. Since our methods and the technical details are contained in the publications listed (9 Abstracts are given as Appendices) our emphasis here is on broad conclusions/implications and administrative data, including personnel, talks, interactions with industry, and some known applications of our work.

  12. Nonlinear processes in laser heating of chemically active media

    Energy Technology Data Exchange (ETDEWEB)

    Bunkin, F V; Kirichenko, N A; Luk' yanchuk, B S

    1984-08-01

    After it had been discovered and in due measure physically comprehended that numerous nontrivial phenomena observed during laser heating of chemically active media are caused primarily by self-stress of laser radiation due to the chemical intertial nonlinearity of the medium, an approach was found for solving problems of laser thermochemistry that is most adequate from the mathematical (and physical) standpoint: the approach of the theory of nonlinear oscillations in point systems and distributed systems. This approach has provided a uniform viewpoint for examination of a variety of phenomena of spatiotemporal self-organization of chemically active media under the effect of laser radiation, qualitative, and in some cases quantitative description of such phenomena as the onset of thermochemical instability, self-oscillations, various spatial structures and the like. Evidently it can be rightly considered that at this juncture a definite stage has been completed in the development of laser thermochemistry marked by the creation of an ideology, method and overall approach to interpretation of the most diverse phenomena under conditions of actual physical experiments. References to the numerous studies that make up the content of this stage of development of laser thermochemistry are to be found in survey papers. 48 references, 10 figures.

  13. Sustaining Operational Resiliency: A Process Improvement Approach to Security Management

    National Research Council Canada - National Science Library

    Caralli, Richard A

    2006-01-01

    ... potential to significantly disrupt an organization's pursuit of its mission. Security, business continuity, and IT operations management are activities that traditionally support operational risk management...

  14. Chemical exposure among professional ski waxers--characterization of individual work operations.

    Science.gov (United States)

    Freberg, Baard Ingegerdsson; Olsen, Raymond; Thorud, Syvert; Ellingsen, Dag G; Daae, Hanne Line; Hersson, Merete; Molander, Paal

    2013-04-01

    Preparation of skis prior to skiing competitions involves several individual work operations and the use of a wide variety of chemically based ski waxing products to improve the performance of the skis, including products used after skiing for wax removal and ski sole cleaning. Modern ski waxes consist mainly of petroleum-derived straight-chain aliphatic hydrocarbons, perfluoro-n-alkanes or polyfluorinated n-alkanes. The wax cleaning products contain solvents such as neat aliphatic hydrocarbons (aliphates) or a mixture with limonene. Different ski waxing work operations can result in contaminated workroom atmospheres. The aim of this study was to assess the chemical exposures related to the individual ski waxing work operations by investigating the specific work operations in controlled model experiments. Four main work operations with potential exposures were identified: (i) application of glider waxes, (ii) scraping and brushing of applied glider waxes, (iii) application of base/grip waxes, and (iv) ski sole cleaning. Aerosol particle masses were sampled using conical samplers equipped with 37-mm PVC, 5-µm pore size filters and cyclones equipped with 37-mm PVC, 0.8-µm pore size filters for the inhalable and the respirable aerosol mass fractions, respectively. For measurements of particle number concentrations, a Scanning Mobility Particle Sizer was used. Mean aerosol particle mass concentrations of 18.6 mg m(-3) and 32.2 mg m(-3) were measured during application of glider wax powders in the respirable and in the inhalable aerosol mass fractions, respectively. Particle number concentration of ~900 000 particles cm(-3) was measured during application of glider wax powder products. Ski sole cleaning with products containing aliphates displayed solvent air concentrations up to 62.5 p.p.m. This study shows that the potential exposure to generated particles during ski waxing and ski preparation is considerable, especially during work using glide wax powders.

  15. Comparison of Electrocoagulation and Chemical Coagulation Processes in Removing Reactive red 196 from Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Ali Assadi

    2016-06-01

    Full Text Available Background: Conventional chemical coagulation is considered as an old method to dye and COD removal in textile effluent. Electrocoagulation (EC process is a robust method to achieve maximum removal. Methods: This study was designed to compare the result of operational parameters including optimum pH and coagulant concentration for chemical coagulation with ferric chloride and alum also, voltage, electrolysis time, initial pH, and conductivity for EC with iron electrodes to remove reactive red 196 (RR 196. Results: The outcomes show that ferric chloride and alum at optimum concentration were capable of removing dye and COD by 79.63 % and 84.83% and 53% and 55%, respectively. In contrast, EC process removed the dye and COD by 99.98% and 90.4%, respectively. Conclusion: The highest treatment efficiency was obtained by increasing the voltage, electrolysis time, pH and conductivity. Increase initial dye concentration reduces removal efficiency. Ultimately, it could be concluded that EC technology is an efficient procedure for handling of colored industrial wastewaters.

  16. Investigation of the fluidized bed-chemical vapor deposition (FBCVD) process using CFD-DEM method

    International Nuclear Information System (INIS)

    Liu Malin; Liu Rongzheng; Wen Yuanyun; Liu Bing; Shao Youlin

    2014-01-01

    The CFD-DEM-CVD multiscale coupling simulation concept was proposed based on the mass/momentum/energy transfer involved in the FB-CVD process. The pyrolysis process of the reaction gas in the spouted bed can be simulated by CFD method, then the concentration field and velocity field can be extracted and coupled with the particle movement behavior which can be simulated by DEM. Particle deposition process can be described by the CVD model based on particle position, velocity and neighboring gas concentration. This multiscale coupling method can be implemented in the Fluent@-EDEM@ software with their UDF (User Definition Function) and API (Application Programming Interface). Base on the multiscale coupling concept, the criterion for evaluating FB-CVD process is given. At first, the volume in the coating furnace is divided into two parts (active coating area and non-active coating area) based on simulation results of chemical pyrolysis process. Then the residence time of all particles in the active coating area can be obtained using the CFD-DEM simulation method. The residence time distribution can be used as a criterion for evaluating the gas-solid contact efficiency and operation performance of the coating furnace. At last different coating parameters of the coating furnace are compared based on the proposed criterion. And also, the future research emphasis is discussed. (author)

  17. IMPROVING THE ENVIRONMENTAL PERFORMANCE OF CHEMICAL PROCESSES THROUGH THE USE OF INFORMATION TECHNOLOGY

    Science.gov (United States)

    Efforts are currently underway at the USEPA to develop information technology applications to improve the environmental performance of the chemical process industry. These efforts include the use of genetic algorithms to optimize different process options for minimal environmenta...

  18. The fate of sulphur in the Cu-based Chemical Looping with Oxygen Uncoupling (CLOU) Process

    International Nuclear Information System (INIS)

    Adánez-Rubio, Iñaki; Abad, Alberto; Gayán, Pilar; García-Labiano, Francisco; Diego, Luis F. de; Adánez, Juan

    2014-01-01

    Highlights: • 15 h of CLOU experiments using lignite were carried out in a continuously unit. • The sulphur split between fuel- and air-reactor streams in the process was analysed. • Most of the sulphur introduced with the fuel exits as SO 2 at the fuel-reactor. • The use of a carbon separation system to reduce the S emission was evaluated. • Coals with high S content can be burnt in a CLOU process with a Cu-based material. - Abstract: The Chemical Looping with Oxygen Uncoupling (CLOU) process is a type of Chemical Looping Combustion (CLC) technology that allows the combustion of solid fuels with air, as with conventional combustion, through the use of oxygen carriers that release gaseous oxygen inside the fuel reactor. The aim of this work was to study the behaviour of the sulphur present in fuel during CLOU combustion. Experiments using lignite as fuel were carried out in a continuously operated 1.5 kW th CLOU unit during more than 15 h. Particles containing 60 wt.% CuO on MgAl 2 O 4 , prepared by spray drying, were used as the oxygen carrier in the CLOU process. The temperature in the fuel reactor varied between 900 and 935 °C. CO 2 capture, combustion efficiency and the sulphur split between fuel and air reactor streams in the process were analysed. Complete combustion of the fuel to CO 2 and H 2 O was found in all experiments. Most of the sulphur introduced with the fuel exited as SO 2 at the fuel reactor outlet, although a small amount of SO 2 was measured at the air reactor outlet. The SO 2 concentration in the air reactor exit flow decreased as the temperature in the fuel reactor increased. A carbon capture efficiency of 97.6% was achieved at 935 °C, with 87.9 wt.% of the total sulphur exiting as SO 2 in the fuel reactor. Both the reactivity and oxygen transport capacity of the oxygen carrier were unaffected during operation with a high sulphur content fuel, and agglomeration problems did not occur. Predictions were calculated regarding the use

  19. Comprehensive Mass Analysis for Chemical Processes, a Case Study on L-Dopa Manufacture

    Science.gov (United States)

    To evaluate the “greenness” of chemical processes in route selection and process development, we propose a comprehensive mass analysis to inform the stakeholders from different fields. This is carried out by characterizing the mass intensity for each contributing chemical or wast...

  20. A systems engineering approach to manage the complexity in sustainable chemical product-process design

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    This paper provides a perspective on model-data based solution approaches for chemical product-process design, which consists of finding the identity of the candidate chemical product, designing the process that can sustainably manufacture it and verifying the performance of the product during...... framework can manage the complexity associated with product-process problems very efficiently. Three specific computer-aided tools (ICAS, Sustain-Pro and VPPDLab) have been presented and their applications to product-process design, highlighted....

  1. Investigation of hydrogen generation in a three reactor chemical looping reforming process

    International Nuclear Information System (INIS)

    Khan, Mohammed N.; Shamim, Tariq

    2016-01-01

    Highlights: • Three-reactor based chemical looping reforming system for hydrogen production. • Investigation of operating parameters using a system-level model. • Optimum operating conditions for hydrogen production are identified. • Different operating parameters affect the reactor temperatures differently. - Abstract: Chemical looping reforming (CLR) is a relatively new method to produce hydrogen (H_2) and is also used as an energy conversion method for solid, liquid or gaseous fuels. There are various advantages of this method such as inherent carbon dioxide (CO_2) capture, minimal NOx emissions and the H_2 production. In this process, there is no direct contact between the fuel and oxidizer. This method utilizes oxygen from an oxygen carrier which may be a transition metal. The idea is to split the combustion process into three separate sub-processes by employing three separate reactors: air reactor where the oxygen carrier is oxidized by air, fuel reactor where natural gas is oxidized to produce a stream of CO_2 and H_2O and steam reactor where the steam is reduced to produce H_2. In this study, a thermodynamic model with iron oxides as oxygen carrier has been developed using Aspen Plus by employing conservation of mass and energy for all the components of the CLR system. The developed model was employed to investigate the effect of various operating parameters such as mass flow rates of air, fuel, steam and oxygen carrier and fraction of inert material on H_2 and CO_2 production and key reactor temperatures. The results show that the H_2 production increases with the increase in air, fuel and steam flow rates up to a certain limit and stays constant for higher flow rates. The CO_2 production follows a similar trend. Similarly, the H_2 production also increases with the increase in oxide flow rate and fraction of inert material up to a particular value, but then decrease for higher oxide flow rates and inert fractions. Reactor temperatures were also

  2. Test Operations Procedure (TOP) 08-2-188 Chemical Point Detector Vapor Testing

    Science.gov (United States)

    2018-04-27

    Final 3. DATES COVERED (From - To) 4. TITLE AND SUBTITLE Test Operations Procedure (TOP) 08-2-188 Chemical Point Detector Vapor Testing 5a. CONTRACT...NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING...ORGANIZATION NAME(S) AND ADDRESS(ES) US Army Dugway Proving Ground West Desert Test Center (TEDT-DPW) Dugway, UT 84022-5000 8. PERFORMING ORGANIZATION

  3. Coarse grain model for coupled thermo-mechano-chemical processes and its application to pressure-induced endothermic chemical reactions

    International Nuclear Information System (INIS)

    Antillon, Edwin; Banlusan, Kiettipong; Strachan, Alejandro

    2014-01-01

    We extend a thermally accurate model for coarse grain dynamics (Strachan and Holian 2005 Phys. Rev. Lett. 94 014301) to enable the description of stress-induced chemical reactions in the degrees of freedom internal to the mesoparticles. Similar to the breathing sphere model, we introduce an additional variable that describes the internal state of the particles and whose dynamics is governed both by an internal potential energy function and by interparticle forces. The equations of motion of these new variables are derived from a Hamiltonian and the model exhibits two desired features: total energy conservation and Galilean invariance. We use a simple model material with pairwise interactions between particles and study pressure-induced chemical reactions induced by hydrostatic and uniaxial compression. These examples demonstrate the ability of the model to capture non-trivial processes including the interplay between mechanical, thermal and chemical processes of interest in many applications. (paper)

  4. Biological effects of radiation and chemical agents with special regard to repair processes

    International Nuclear Information System (INIS)

    Altmann, H.; Wottawa, A.

    1980-01-01

    It is reasonably certain that the introduction or increase of pollutants in the environment can augment mutagenic and carcinogenic effects. These effects are operationally definable, but the genetic organization and the underlying mechanisms of DNA repair, mutagenesis and carcinogenesis are so complex as to make the extrapolation of results from mutagenicity test data to carcinogenicity somewhat uncertain. The subject is reviewed. Recent discoveries in gene organization and expression include overlapping genes in bacteriophages, split genes, processing of RNA and splicing, translocation of genes in eukaryotes, inactivation of the X-chromosome in mammals, etc. Apart from the genetic regulation, plasmids, insertion sequences and mutators can additionally affect mutation frequency. Cancers due to gene mutations, viruses, chemicals and physical agents are known. However, little is known about the epigenetic mechanisms involved. The value of mutagenicity test data is beyond question, but in view of the extraordinary complexities encountered our extrapolations will be more sound if the data have the underpinning of basic information. (author)

  5. Data processing in cosmic rays at the Institute of Physical and Chemical Research

    International Nuclear Information System (INIS)

    Wada, Masami

    1980-01-01

    Data processing performed by the World Data Center for Cosmic Rays, installed at the Institute of Physical and Chemical Research (IPCR) is reported. The Center was set up as a member of the World Data Center for Solar and Terrestrial Physics and performs assigned services. There are several C-level World Data Centers in Japan, and the DC for Cosmic Rays, IPCR, is described in detail, in the context of cosmic ray research itself. As to the future of the Center, IPCR, personal opinions and expectations are made. Thus a glimpse on a century of International Cooperative Observation and a quarter century of world data center operations are made from cosmic ray research side. (author)

  6. Application of positron emission tomography to particulate flow measurement in chemical engineering processes

    International Nuclear Information System (INIS)

    Bemrose, C.R.; Fowles, P.; Hawkesworth, M.R.; O'Dwyer, M.A.

    1988-01-01

    Many chemical engineering processes involve the motion of fluids or particulate solids in bulk, and a detailed knowledge of the flow characteristics is important to their efficient and reliable operation. Initial results on the application of PET to fluidized bed studies are reported. Because back-projection image reconstruction strategies are prohibitively inefficient for locating moving single labelled particles, a new technique has been developed based on the closest approach of photon trajectories to give the most probable position. Investigations involving a single particle moving in a known manner have been used to analyse the camera performance and a preliminary relationship between uncertainty and source location is described. To supplement the normal graphical presentation of results, a new animated colour display system has been developed and used to observe for the first time particle motion within a fluidized bed. (orig.)

  7. Process for controlling calcium in a leach operation

    International Nuclear Information System (INIS)

    Habib, E.J.

    1982-01-01

    A method for controlling calcium, e.g. calcite, build-up in the leach solution of a uranium and/or related values recovery operation wherein the leach solution is flowed through a value bearing ore to dissolve the desired values. A soluble fluoride, e.g. sodium fluoride, is added to the leach solution after it has passed through the ore to thereby precipitate calcium fluoride from the leach solution and lower the calcium content of the leach solution. The soluble fluoride may be added to the leach solution before the leach solution passes through the process equipment which is used to remove the values from the leach solution or the soluble fluoride may be added after the leach solution passes through the process equipment. If added before, it is preferable to also add a carbonate/bicarbonate solution along with the soluble fluoride to prevent coprecipitation of uranyl/desired value fluoride or to redissolve coprecipitated fluoride back into the leach solution

  8. Defense Waste Processing Facility staged operations: environmental information document

    International Nuclear Information System (INIS)

    1981-11-01

    Environmental information is presented relating to a staged version of the proposed Defense Waste Processing Facility (DWPF) at the Savannah River Plant. The information is intended to provide the basis for an Environmental Impact Statement. In either the integral or the staged design, the DWPF will convert the high-level waste currently stored in tanks into: a leach-resistant form containing about 99.9% of all the radioactivity, and a residual, slightly contaminated salt, which is disposed of as saltcrete. In the first stage of the staged version, the insoluble sludge portion of the waste and the long lived radionuclides contained therein will be vitrified. The waste glass will be sealed in canisters and stored onsite until shipped to a Federal repository. In the second stage, the supernate portion of the waste will be decontaminated by ion exchange. The recovered radionuclides will be transferred to the Stage 1 facility, and mixed with the sludge feed before vitrification. The residual, slightly contaminated salt solution will be mixed with Portland cement to form a concrete product (saltcrete) which will be buried onsite in an engineered landfill. This document describes the conceptual facilities and processes for producing glass waste and decontaminated salt. The environmental effects of facility construction, normal operations, and accidents are then presented. Descriptions of site and environs, alternative sites and waste disposal options, and environmental consultations and permits are given in the base Environmental Information Document

  9. Process hazards analysis (PrHA) program, bridging accident analyses and operational safety

    International Nuclear Information System (INIS)

    Richardson, J.A.; McKernan, S.A.; Vigil, M.J.

    2003-01-01

    Recently the Final Safety Analysis Report (FSAR) for the Plutonium Facility at Los Alamos National Laboratory, Technical Area 55 (TA-55) was revised and submitted to the US. Department of Energy (DOE). As a part of this effort, over seventy Process Hazards Analyses (PrHAs) were written and/or revised over the six years prior to the FSAR revision. TA-55 is a research, development, and production nuclear facility that primarily supports US. defense and space programs. Nuclear fuels and material research; material recovery, refining and analyses; and the casting, machining and fabrication of plutonium components are some of the activities conducted at TA-35. These operations involve a wide variety of industrial, chemical and nuclear hazards. Operational personnel along with safety analysts work as a team to prepare the PrHA. PrHAs describe the process; identi fy the hazards; and analyze hazards including determining hazard scenarios, their likelihood, and consequences. In addition, the interaction of the process to facility systems, structures and operational specific protective features are part of the PrHA. This information is rolled-up to determine bounding accidents and mitigating systems and structures. Further detailed accident analysis is performed for the bounding accidents and included in the FSAR. The FSAR is part of the Documented Safety Analysis (DSA) that defines the safety envelope for all facility operations in order to protect the worker, the public, and the environment. The DSA is in compliance with the US. Code of Federal Regulations, 10 CFR 830, Nuclear Safety Management and is approved by DOE. The DSA sets forth the bounding conditions necessary for the safe operation for the facility and is essentially a 'license to operate.' Safely of day-to-day operations is based on Hazard Control Plans (HCPs). Hazards are initially identified in the PrI-IA for the specific operation and act as input to the HCP. Specific protective features important to worker

  10. PROCESSES PROCEEDING ON CONCRETE COATING SURFACES IN CASE OF THEIR CHEMICAL PROTECTION AGAINST WINTER SLIPPERINESS

    Directory of Open Access Journals (Sweden)

    M. K. Pshembaev

    2016-01-01

    Full Text Available Concrete coatings of road traffic highways along with operational loadings caused by flow of traffic are subjected to weather and climate impacts. These are the following impacts: changes in temperature and air humidity, solar radiation,surface wind speed which is participating in formation of active heat-and-mass transfer in a surface layer of the concrete coating. One of the most complicated and important periods in the road traffic highway operation is so called transitional nature period (from Summer to Autumn and from Winter to Spring. These periods are accompanied by intensive rain and snow fall and possible formation of ice loading on the surface of cement and concrete coatings. These impacts significantly deteriorate friction properties of road pavement (friction factor φ is decreased up to 0.4 and less that can be a prerequisite to creation of various accident situations due to sharp increase in braking distance. For example, while having dry pavement the friction factor φ is equal to 0.80–0.85, and during icy condition of the road the factor φ constitutes 0.08–0.15 that consequently entails an increase in braking distance from 7.5 up to 20.0 m and more. It is quite possible that ice layer appears on the surface of concrete coatings when road traffic highways are used in winter season. Various methods are applicable to remove ice from the surface they can include also ice-melting chemicals and sodium chloride NaCl in particular. The chemical decreases freezing temperature of the formed brine and causes ice melting at negative temperature. Processes of NaCl dissolution and ice melting have an endothermic character, in other words these processes are accompanied by heat ingress and due to it temperature is sharply decreasing in the surface layer of the concrete coating which is under the melting ice and in this case phenomenon of thermal shock is observed.

  11. Defense Waste Processing Facility Simulant Chemical Processing Cell Studies for Sludge Batch 9

    International Nuclear Information System (INIS)

    Smith, Tara E.; Newell, J. David; Woodham, Wesley H.

    2016-01-01

    The Savannah River National Laboratory (SRNL) received a technical task request from Defense Waste Processing Facility (DWPF) and Saltstone Engineering to perform simulant tests to support the qualification of Sludge Batch 9 (SB9) and to develop the flowsheet for SB9 in the DWPF. These efforts pertained to the DWPF Chemical Process Cell (CPC). CPC experiments were performed using SB9 simulant (SB9A) to qualify SB9 for sludge-only and coupled processing using the nitric-formic flowsheet in the DWPF. Two simulant batches were prepared, one representing SB8 Tank 40H and another representing SB9 Tank 51H. The simulant used for SB9 qualification testing was prepared by blending the SB8 Tank 40H and SB9 Tank 51H simulants. The blended simulant is referred to as SB9A. Eleven CPC experiments were run with an acid stoichiometry ranging between 105% and 145% of the Koopman minimum acid equation (KMA), which is equivalent to 109.7% and 151.5% of the Hsu minimum acid factor. Three runs were performed in the 1L laboratory scale setup, whereas the remainder were in the 4L laboratory scale setup. Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles were performed on nine of the eleven. The other two were SRAT cycles only. One coupled flowsheet and one extended run were performed for SRAT and SME processing. Samples of the condensate, sludge, and off-gas were taken to monitor the chemistry of the CPC experiments.

  12. Defense Waste Processing Facility Simulant Chemical Processing Cell Studies for Sludge Batch 9

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Tara E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Newell, J. David [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Woodham, Wesley H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-08-10

    The Savannah River National Laboratory (SRNL) received a technical task request from Defense Waste Processing Facility (DWPF) and Saltstone Engineering to perform simulant tests to support the qualification of Sludge Batch 9 (SB9) and to develop the flowsheet for SB9 in the DWPF. These efforts pertained to the DWPF Chemical Process Cell (CPC). CPC experiments were performed using SB9 simulant (SB9A) to qualify SB9 for sludge-only and coupled processing using the nitric-formic flowsheet in the DWPF. Two simulant batches were prepared, one representing SB8 Tank 40H and another representing SB9 Tank 51H. The simulant used for SB9 qualification testing was prepared by blending the SB8 Tank 40H and SB9 Tank 51H simulants. The blended simulant is referred to as SB9A. Eleven CPC experiments were run with an acid stoichiometry ranging between 105% and 145% of the Koopman minimum acid equation (KMA), which is equivalent to 109.7% and 151.5% of the Hsu minimum acid factor. Three runs were performed in the 1L laboratory scale setup, whereas the remainder were in the 4L laboratory scale setup. Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles were performed on nine of the eleven. The other two were SRAT cycles only. One coupled flowsheet and one extended run were performed for SRAT and SME processing. Samples of the condensate, sludge, and off-gas were taken to monitor the chemistry of the CPC experiments.

  13. 21 CFR 170.19 - Pesticide chemicals in processed foods.

    Science.gov (United States)

    2010-04-01

    ... the concentration of the residue in the processed food when ready to eat is not greater than the... processed food when ready to eat is higher than the tolerance prescribed for the raw agricultural commodity... authorized by the regulations in this part. Food that is itself ready to eat, and which contains a higher...

  14. 21 CFR 570.19 - Pesticide chemicals in processed foods.

    Science.gov (United States)

    2010-04-01

    ... the concentration of the residue in the processed food when ready to eat is not greater than the... processed food when ready to eat is higher than the tolerance prescribed for the raw agricultural commodity... authorized by the regulations in this part. Food that is itself ready to eat, and which contains a higher...

  15. Sustainable Chemical Process Development through an Integrated Framework

    DEFF Research Database (Denmark)

    Papadakis, Emmanouil; Kumar Tula, Anjan; Anantpinijwatna, Amata

    2016-01-01

    This paper describes the development and the application of a general integrated framework based on systematic model-based methods and computer-aided tools with the objective to achieve more sustainable process designs and to improve the process understanding. The developed framework can be appli...... studies involve multiphase reaction systems for the synthesis of active pharmaceutical ingredients....

  16. Rapid Neutron Capture Process in Supernovae and Chemical ...

    Indian Academy of Sciences (India)

    A ≻ 70 and all of the actinides in the solar system are believed to have been produced in the r-process. ... mass type II supernovae being the r-process sites. In the usual picture the r- .... critically on the ambient neutron flux. λn > λβ(τn < τβ). (1).

  17. Chemical Changes in Proteins Produced by Thermal Processing.

    Science.gov (United States)

    Dutson, T. R.; Orcutt, M. W.

    1984-01-01

    Discusses effects of thermal processing on proteins, focusing on (1) the Maillard reaction; (2) heat denaturation of proteins; (3) aggregation, precipitation, gelation, and degradation; and (4) other thermally induced protein reactions. Also discusses effects of thermal processing on muscle foods, egg proteins, fruits and vegetables, and cereal…

  18. Aquaporin based biomimetic membrane in forward osmosis: Chemical cleaning resistance and practical operation

    KAUST Repository

    Li, Zhenyu

    2017-07-27

    Aquaporin plays a promising role in fabricating high performance biomimetic forward osmosis (FO) membranes. However, aquaporin as a protein also has a risk of denaturation caused by various chemicals, resulting in a possible decay of membrane performance. The present study tested a novel aquaporin based biomimetic membrane in simulated membrane cleaning processes. The effects of cleaning agents on water flux and salt rejection were evaluated. The membrane showed a good resistance to the chemical agents. The water flux after chemical cleaning showed significant increases, particularly after cleaning with NaOCl and Alconox. Changes in the membrane structure and increased hydrophilicity in the surrounding areas of the aquaporin may be accountable for the increase in water permeability. The membrane shows stable salt rejection up to 99% after all cleaning agents were tested. A 15-day experiment with secondary wastewater effluent as the feed solution and seawater as the draw solution showed a stable flux and high salt rejection. The average rejection of the dissolved organic carbon from wastewater after the 15-day test was 90%. The results demonstrated that the aquaporin based biomimetic FO membrane exhibits chemical resistance for most agents used in membrane cleaning procedures, maintaining a stable flux and high salt rejection.

  19. Aquaporin based biomimetic membrane in forward osmosis: Chemical cleaning resistance and practical operation

    KAUST Repository

    Li, Zhenyu; Valladares Linares, Rodrigo; Bucs, Szilard; Fortunato, Luca; Hé lix-Nielsen, Claus; Vrouwenvelder, Johannes S.; Ghaffour, NorEddine; Leiknes, TorOve; Amy, Gary

    2017-01-01

    Aquaporin plays a promising role in fabricating high performance biomimetic forward osmosis (FO) membranes. However, aquaporin as a protein also has a risk of denaturation caused by various chemicals, resulting in a possible decay of membrane performance. The present study tested a novel aquaporin based biomimetic membrane in simulated membrane cleaning processes. The effects of cleaning agents on water flux and salt rejection were evaluated. The membrane showed a good resistance to the chemical agents. The water flux after chemical cleaning showed significant increases, particularly after cleaning with NaOCl and Alconox. Changes in the membrane structure and increased hydrophilicity in the surrounding areas of the aquaporin may be accountable for the increase in water permeability. The membrane shows stable salt rejection up to 99% after all cleaning agents were tested. A 15-day experiment with secondary wastewater effluent as the feed solution and seawater as the draw solution showed a stable flux and high salt rejection. The average rejection of the dissolved organic carbon from wastewater after the 15-day test was 90%. The results demonstrated that the aquaporin based biomimetic FO membrane exhibits chemical resistance for most agents used in membrane cleaning procedures, maintaining a stable flux and high salt rejection.

  20. Minimizing the entropy production in a chemical process for dehydrogenation of propane

    International Nuclear Information System (INIS)

    Rosjorde, A.; Kjelstrup, S.; Johannessen, E.; Hansen, R.

    2007-01-01

    We minimize the total entropy production of a process designed for dehydrogenation of propane. The process consists of 21 units, including a plug-flow reactor, a partial condenser, two tray distillation columns and a handful of heat exchangers and compressors. The units were modeled in a manner that made them relatively insensitive to changes in the molar flow rates, to make the optimization more flexible. The operating conditions, as well as to some degree the design of selected units, which minimized the total entropy production of the process, were found. The most important variables were the amount of recycled propane and propylene, conversion and selectivity in the reactor, as well as the number of tubes in the reactor. The optimal conversion, selectivity and recycle flows were results of a very clear trade-off among the entropy produced in the reactor, the partial condenser and the two distillation columns. Although several simplifying assumptions were made for computational reasons, this shows for the first time that it is also meaningful to use the entropy production as an objective function in chemical engineering process optimization studies

  1. Processes of elimination of activated corrosion products. Chemical decontamination - fuel cleaning

    International Nuclear Information System (INIS)

    Viala, C.; Brun, C.; Neuhaus, R.; Richier, S.; Bachet, M.

    2007-01-01

    The abatement of the individual and collective dose of a PWR imposes to control the source term through different processes implemented during the plant exploitation. When the limits of these different optimization processes are reached, the abatement of dose rates requires the implementation of curative processes. The objective is thus to eliminate the contaminated oxides and deposits present on surfaces free of radiation flux, and eventually on surfaces under radiation flux and on the fuel itself. The chemical decontamination of equipments and systems is the main and universal remedy implemented at different levels. On the other hand, the ultrasonic cleaning of fuel assemblies is a promising process. This paper aims at illustrating these different techniques using concrete examples of application in France and abroad (decontamination during steam generator replacement, decontamination of primary pump scroll in hot workshop, decontamination of loop sections, ultrasonic cleaning of fuel). The description of these different operations stresses on their efficiency in terms of dosimetric gain, duration of implementation, generation of wastes, and recontamination following their implementation. (J.S.)

  2. Alternative Processes for Water Reclamation and Solid Waste Processing in a Physical/chemical Bioregenerative Life Support System

    Science.gov (United States)

    Rogers, Tom D.

    1990-01-01

    Viewgraphs on alternative processes for water reclamation and solid waste processing in a physical/chemical-bioregenerative life support system are presented. The main objective is to focus attention on emerging influences of secondary factors (i.e., waste composition, type and level of chemical contaminants, and effects of microorganisms, primarily bacteria) and to constructively address these issues by discussing approaches which attack them in a direct manner.

  3. Biorefineries to integrate fuel, energy and chemical production processes

    Directory of Open Access Journals (Sweden)

    Enrica Bargiacchi

    2007-12-01

    Full Text Available The world of renewable energies is in fast evolution and arouses political and public interests, especially as an opportunity to boost environmental sustainability by mitigation of greenhouse gas emissions. This work aims at examining the possibilities related to the development of biorefineries, where biomass conversion processes to produce biofuels, electricity and biochemicals are integrated. Particular interest is given to the production processes of biodiesel, bioethanol and biogas, for which present world situation, problems, and perspectives are drawn. Potential areas for agronomic and biotech researches are also discussed. Producing biomass for biorefinery processing will eventually lead to maximize yields, in the non food agriculture.

  4. Knowledge acquisition on hazards in chemical and process industry

    Energy Technology Data Exchange (ETDEWEB)

    Vojnovic, D; Kozuh, M [Inst. Jozef Stefan, Ljubljana (Slovenia)

    1992-07-01

    The knowledge acquisition for probabilistic risk assessment and operational safety improvements are described. The procedure HazOp (Hazard and Operability Study) are used for hazard identification. The acquainted knowledge is condensed in the form of cause-consequence matrix which is very convenient for plant logic model start point definition. At the end, the possibility for HazOp performance support by use of Artificial Intelligence approach is considered. (author) [Slovenian] V clanku se obravnava zbiranje znanja za potrebe verjetnostne ocene tveganja in izboljsanja obratovalne varnosti. Opisan je postopek za razpoznavanje nevarnosti po metodi HazOp. Zbrano znanje je predstavljeno v obliki vzrocno posledicne matrike, kar je primerna oblika za nadaljno uporabo pri logicnem modeliranju objekta. Ravno tako je obravnavana moznost uporabe diagnosticnih metod (umetna inteligenca) pri HazOp analizi. [author].

  5. Process Analytical Technology (PAT): batch-to-batch reproducibility of fermentation processes by robust process operational design and control.

    Science.gov (United States)

    Gnoth, S; Jenzsch, M; Simutis, R; Lübbert, A

    2007-10-31

    The Process Analytical Technology (PAT) initiative of the FDA is a reaction on the increasing discrepancy between current possibilities in process supervision and control of pharmaceutical production processes and its current application in industrial manufacturing processes. With rigid approval practices based on standard operational procedures, adaptations of production reactors towards the state of the art were more or less inhibited for long years. Now PAT paves the way for continuous process and product improvements through improved process supervision based on knowledge-based data analysis, "Quality-by-Design"-concepts, and, finally, through feedback control. Examples of up-to-date implementations of this concept are presented. They are taken from one key group of processes in recombinant pharmaceutical protein manufacturing, the cultivations of genetically modified Escherichia coli bacteria.

  6. Isotope separation by chemical exchange process: Final technical report

    International Nuclear Information System (INIS)

    Schneider, A.

    1987-02-01

    The feasibility of a chemical exchange method for the separation of the isotopes of europium was demonstrated in the system EuCl 2 -EuCl 3 . The single stage separation factor, α, in this system is 1.001 or 1.0005 per mass unit. This value of α is comparable to the separation factors reported for the U 4+ - U 6 and U 3+ - Y 4+ systems. The separation of the ionic species was done by precipitation of the Eu 2+ ions or by extraction of the Eu 3+ ions with HDEHP. Conceptual schemes were developed for a countercurrent reflux cascades consisting of solvent extraction contractors. A regenerative electrocel, combining simultaneous europium reduction, europium oxidation with energy generation, and europium stripping from the organic phase is described. 32 refs., 22 figs., 6 tabs

  7. Physical-chemical processes of astrophysical interest: nitrogen chemistry

    International Nuclear Information System (INIS)

    Loison, Jean-Christophe; Hickson, Kevin; Hily-Blant, Pierre; Faure, Alexandre; Vuitton, Veronique; Bacmann, A.; Maret, Sebastien; Legal, Romane; Rist, Claire; Roncero, Octavio; Larregaray, Pascal; Hochlaf, Majdi; Senent, M. L.; Capron, Michael; Biennier, Ludovic; Carles, Sophie; Bourgalais, Jeremy; Le Picard, Sebastien; Cordier, Daniel; Guillemin, Jean-Claude; Trolez, Yann; Bertin, M.; Poderoso, H.A.M.; Michaut, X.; Jeseck, P.; Philippe, L.; Fillion, J.H.; Fayolle, E.C.; Linnartz, H.; Romanzin, C.; Oeberg, K.I.; Roueff, Evelyne; Pagani, Laurent; Padovani, Marco; Wakelam, Veronique; Honvault, Beatrice; Zvereva-Loete, Natalia; Ouk, Chanda-Malis; Scribano, Yohann; Hartmann, J.M.; Pineau des Forets, Guillaume; Hernandez, Mario; Lique, Francois; Kalugina, Yulia N.; Stoecklin, T.; Hochlaf, M.; Crespos, C.; Larregaray, P.; Martin-Gondre, L.; Petuya, R.; Quintas Sanchez, E.L.; Zanchet, Alexandre; Rodriguez-Lazcano, Yamilet; Mate, Belen

    2013-06-01

    This document contains the programme and abstracts of contributions to a workshop on nitrogen chemistry within an astrophysical perspective. These contributions have been presented in sessions: Introduction (opening lecture, experimental approaches to molecular astrophysics, theoretical approaches to astrophysics, observations in molecular astrophysics), Physical-chemical theory of the gas phase (time-dependent approach in elementary activity, statistic approach in elementary activity in the case of the N+H_2 reaction, potential energy surfaces for inelastic and reactive collisions, collision rate for N_2H"+, ortho/para selection rules in the chemistry of nitrogen hydrides, cyanides/iso-cyanides excitation in the ISM, CN excitation, radiative association with N_2H as new interstellar anion, ro-vibratory excitation of HCN) Laboratory astrophysics (measurement of reaction products in the CRESUSOL project, reactivity of the CN- anion, N_2 photo-desorption in ices, CRESU study of nitrogen chemistry, chemistry of nitrogen complex molecules), Observations and chemistry of astrophysical media (the problem of interstellar nitrogen fractioning, abundance of N_2 in proto-stellar cores, HNC in Titan atmosphere and nitrogen-related mechanisms in hot Jupiters, HCN and HNC in dark clouds or how theoretical modelling helps in interpreting observations, nitrogen chemistry in cold clouds, deuteration of nitrogen hydrides, nitrogen in interstellar ices, biochemical molecules on Titan, coupling between excitation and chemistry, radiative transfer of nitrogen hydrides, ortho/para chemistry of nitrogen hydrides), Physical-chemical theory of gas-grain interactions (nitrogen reactivity on surfaces, IR spectra of ices of NH_3 and NH_3/N_2 mixtures)

  8. Start of operation of the barrel measuring facility II-01. Implementation into operational processes

    International Nuclear Information System (INIS)

    Buesing, B.; Escher, M.

    2013-01-01

    For the operation of the barrel measuring facility (FAME) II-01 a variety requirements to the measuring techniques were defined and tested in the frame of start-up. The used mechanical engineering and measuring technique complies with the state-of-the-art. Using the barrel measuring facility quality assured determinations of the dose rate and the nuclide-specific activity inventory were performed. For the evaluation of the gamma spectrometric measurements of FAME II-01 appropriately qualified personnel is available. The implementation of the facility in combination with the connection to the data base system PIK-AS and AVK it guaranteed that important data are available in real-time for the measuring process and the subsequent work steps. Besides this it is guaranteed that using the import/export functions relevant data are reviewed, supplemented and exchanged between the systems without transfer errors. The determined data of the dose rate and gamma spectrometric measurements allow an activity determination of the waste package with quality assurance and close to reality. Conservative assumptions in the frame of activity calculations for the later final disposal can be reduced. The automated operation of FAME allows also the reduction of radiation exposure of the personnel.

  9. Novel Chemical Process for Producing Chrome Coated Metal

    Directory of Open Access Journals (Sweden)

    Christopher Pelar

    2018-01-01

    Full Text Available This work demonstrates that a version of the Reduction Expansion Synthesis (RES process, Cr-RES, can create a micron scale Cr coating on an iron wire. The process involves three steps. I. A paste consisting of a physical mix of urea, chrome nitrate or chrome oxide, and water is prepared. II. An iron wire is coated by dipping. III. The coated, and dried, wire is heated to ~800 °C for 10 min in a tube furnace under a slow flow of nitrogen gas. The processed wires were then polished and characterized, primarily with scanning electron microscopy (SEM. SEM indicates the chrome layer is uneven, but only on the scale of a fraction of a micron. The evidence of porosity is ambiguous. Elemental mapping using SEM electron microprobe that confirmed the process led to the formation of a chrome metal layer, with no evidence of alloy formation. Additionally, it was found that thickness of the final Cr layer correlated with the thickness of the precursor layer that was applied prior to the heating step. Potentially, this technique could replace electrolytic processing, a process that generates carcinogenic hexavalent chrome, but further study and development is needed.

  10. Novel Chemical Process for Producing Chrome Coated Metal.

    Science.gov (United States)

    Pelar, Christopher; Greenaway, Karima; Zea, Hugo; Wu, Chun-Hsien; Luhrs, Claudia C; Phillips, Jonathan

    2018-01-05

    This work demonstrates that a version of the Reduction Expansion Synthesis (RES) process, Cr-RES, can create a micron scale Cr coating on an iron wire. The process involves three steps. I. A paste consisting of a physical mix of urea, chrome nitrate or chrome oxide, and water is prepared. II. An iron wire is coated by dipping. III. The coated, and dried, wire is heated to ~800 °C for 10 min in a tube furnace under a slow flow of nitrogen gas. The processed wires were then polished and characterized, primarily with scanning electron microscopy (SEM). SEM indicates the chrome layer is uneven, but only on the scale of a fraction of a micron. The evidence of porosity is ambiguous. Elemental mapping using SEM electron microprobe that confirmed the process led to the formation of a chrome metal layer, with no evidence of alloy formation. Additionally, it was found that thickness of the final Cr layer correlated with the thickness of the precursor layer that was applied prior to the heating step. Potentially, this technique could replace electrolytic processing, a process that generates carcinogenic hexavalent chrome, but further study and development is needed.

  11. Physical-chemical hydrodynamics of the processes of sorption-membrane technology of LRW treatment

    International Nuclear Information System (INIS)

    Alexander D Efanov; Pyotr N Martynov; Yuri D Boltoev; Ivan V Yagodkin; Nataliya G Bogdanovich; Sergey S Skvortsov; Alexander R Sokolovsky; Elena V Ignatova; Gennady V Grigoriev; Vitaly V Grigorov

    2005-01-01

    Full text of publication follows: Liquid radioactive NPP waste is generated, when radioactive water is collected and mixed from various routine and non-routine process measures being performed in accordance with the operating regulations of reactor units with water coolant. The main sources of LRW are the primary loop water coolant, deactivation, regeneration and rinse waters, waste laundry and showers water producing the initial averaged LRW as well as spent fuel element cooling pond water and water of biological protection tanks. LRW handling can be substantially advanced, in particular, through development and introduction of the non-conventional sorption-membrane technology of NPP LRW treatment, being developed at SSC RF IPPE. This technology makes use of natural inorganic sorbents (tripolite, zeolite, ion-exchange materials) and filtering nano-structured metallic and ceramic membranes (titanium, zirconium, chromium and other or their oxides, carbides and nitrides). The efficiency of the sorption membrane technology is associated just with the investigation of the physical-chemical processes of sorption, coagulation and sedimentation under the conditions of forced and free convection occurring in LRW. Besides, it is necessary to take into consideration that the hydrodynamics of the flows of LRW being decontaminated by membrane filtration depends on the structure and composition of the porous composition pare 'nano-structured membrane-substrate'. Neglecting these peculiarities can result in drastic reduction of the time of stable LRW filtration, reduction of the operability resource of filtration systems or in quick mechanical destruction of porous materials. The paper presents the investigation results on: -the effect of the convection flows being generated by air bubbling or LRW stirring by agitator on the static sorption conditions (sorption time, medium pH, sorbent dispersity, sorbent concentration in liquid medium) and on the efficiency of extraction by

  12. Online total organic carbon (TOC) monitoring for water and wastewater treatment plants processes and operations optimization

    Science.gov (United States)

    Assmann, Céline; Scott, Amanda; Biller, Dondra

    2017-08-01

    Organic measurements, such as biological oxygen demand (BOD) and chemical oxygen demand (COD) were developed decades ago in order to measure organics in water. Today, these time-consuming measurements are still used as parameters to check the water treatment quality; however, the time required to generate a result, ranging from hours to days, does not allow COD or BOD to be useful process control parameters - see (1) Standard Method 5210 B; 5-day BOD Test, 1997, and (2) ASTM D1252; COD Test, 2012. Online organic carbon monitoring allows for effective process control because results are generated every few minutes. Though it does not replace BOD or COD measurements still required for compliance reporting, it allows for smart, data-driven and rapid decision-making to improve process control and optimization or meet compliances. Thanks to the smart interpretation of generated data and the capability to now take real-time actions, municipal drinking water and wastewater treatment facility operators can positively impact their OPEX (operational expenditure) efficiencies and their capabilities to meet regulatory requirements. This paper describes how three municipal wastewater and drinking water plants gained process insights, and determined optimization opportunities thanks to the implementation of online total organic carbon (TOC) monitoring.

  13. Emergency Management Operations Process Mapping: Public Safety Technical Program Study

    Science.gov (United States)

    2011-02-01

    services Operational Activity Collect and Manage Cash Donations Once activated, refer cash donations to appropriate voluntary organizations...recovery operations. Operational Activity Conduct Euthanasia /Disposal Provide humane methods to euthanize affected animals to stop the spread of the...issue stop movement orders, and initiate animal vaccination and treatment programs, euthanasia efforts, or other protective measures designed to control

  14. Nonequilibrium thermodynamics transport and rate processes in physical, chemical and biological systems

    CERN Document Server

    Demirel, Yasar

    2014-01-01

    Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, 3rd edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapte

  15. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2018-04-17

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  16. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2017-05-23

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  17. Materials measurement and accounting in an operating plutonium conversion and purification process. Phase I. Process modeling and simulation

    International Nuclear Information System (INIS)

    Thomas, C.C. Jr.; Ostenak, C.A.; Gutmacher, R.G.; Dayem, H.A.; Kern, E.A.

    1981-04-01

    A model of an operating conversion and purification process for the production of reactor-grade plutonium dioxide was developed as the first component in the design and evaluation of a nuclear materials measurement and accountability system. The model accurately simulates process operation and can be used to identify process problems and to predict the effect of process modifications

  18. Special study for the manual transfer of process samples from CPP [Chemical Processing Plant] 601 to RAL [Remote Analytical Laboratory

    International Nuclear Information System (INIS)

    Marts, D.J.

    1987-05-01

    A study of alternate methods to manually transport radioactive samples from their glove boxes to the Remote Analytical Laboratory (RAL) was conducted at the Idaho National Engineering Laboratory. The study was performed to mitigate the effects of a potential loss of sampling capabilities that could take place if a malfunction in the Pneumatic Transfer System (PTS) occurred. Samples are required to be taken from the cell glove boxes and analyzed at the RAL regardless of the operational status of the PTS. This paper documents the conclusions of the study and how a decision was reached that determined the best handling scenarios for manually transporting 15 mL vials of liquid process samples from the K, W, U, WG, or WH cell glove boxes in the Chemical Processing Plant (CPP) 601 to the RAL. This study of methods to manually remove the samples from the glove boxes, package them for safe shipment, transport them by the safest route, receive them at the RAL, and safely unload them was conducted by EG and G Idaho, Inc., for Westinghouse Idaho Nuclear Company as part of the Glove Box Sampling and Transfer System Project for the Fuel Processing Facilities Upgrade, Task 10, Subtask 2. The study focused on the safest and most reliable scenarios that could be implemented using existing equipment. Hardware modifications and new hardware proposals were identified, and their impact on the handling scenario has been evaluated. A conclusion was reached that by utilizing the existing facility hardware, these samples can be safely transported manually from the sample stations in CPP 601 to the RAL, and that additional hardware could facilitate the transportation process even further

  19. Fatty acid methyl esters production: chemical process variables

    Directory of Open Access Journals (Sweden)

    Paulo César Narváez Rincón

    2004-05-01

    Full Text Available The advantages of fatty acid methyl esters as basic oleochemicals over fatty acids, the seventies world energy crisis and the use of those oleochemicals as fuels, have increased research interest on fats and oils trans-esterification. In this document, a review about basic aspects, uses, process variables and problems associated to the production process of fatty acid methyl esters is presented. A global view of recent researches, most of them focused in finding a new catalyst with same activity as the alcohol-soluble hydroxides (NaOH, KOH, and suitable to be used in transforming fats and oils with high levels of free fatty acids and water avoiding separation problems and reducing process costs, is also discussed.

  20. Status of the TESS Science Processing Operations Center

    Science.gov (United States)

    Jenkins, Jon M.; Twicken, Joseph D.; Campbell, Jennifer; Tenebaum, Peter; Sanderfer, Dwight; Davies, Misty D.; Smith, Jeffrey C.; Morris, Rob; Mansouri-Samani, Masoud; Girouardi, Forrest; hide

    2017-01-01

    The Transiting Exoplanet Survey Satellite (TESS) science pipeline is being developed by the Science Processing Operations Center (SPOC) at NASA Ames Research Center based on the highly successful Kepler Mission science pipeline. Like the Kepler pipeline, the TESS science pipeline will provide calibrated pixels, simple and systematic error-corrected aperture photometry, and centroid locations for all 200,000+ target stars, observed over the 2-year mission, along with associated uncertainties. The pixel and light curve products are modeled on the Kepler archive products and will be archived to the Mikulski Archive for Space Telescopes (MAST). In addition to the nominal science data, the 30-minute Full Frame Images (FFIs) simultaneously collected by TESS will also be calibrated by the SPOC and archived at MAST. The TESS pipeline will search through all light curves for evidence of transits that occur when a planet crosses the disk of its host star. The Data Validation pipeline will generate a suite of diagnostic metrics for each transit-like signature discovered, and extract planetary parameters by fitting a limb-darkened transit model to each potential planetary signature. The results of the transit search will be modeled on the Kepler transit search products (tabulated numerical results, time series products, and pdf reports) all of which will be archived to MAST.

  1. Novel Chemical Process for Producing Chrome Coated Metal

    OpenAIRE

    Pelar, Christopher; Greenaway, Karima; Zea, Hugo; Wu, Chun-Hsien; Luhrs, Claudia C.; Phillips, Jonathan

    2018-01-01

    The article of record as published may be found at http://dx.doi.org/10.3390/ma11010078 This work demonstrates that a version of the Reduction Expansion Synthesis (RES) process, Cr-RES, can create a micron scale Cr coating on an iron wire. The process involves three steps. I. A paste consisting of a physical mix of urea, chrome nitrate or chrome oxide, and water is prepared. II. An iron wire is coated by dipping. III. The coated, and dried, wire is heated to ~800 ◦C for 10 min in a tube fu...

  2. Thermo-Chemical Modelling Strategies for the Pultrusion Process

    DEFF Research Database (Denmark)

    Baran, Ismet; Hattel, Jesper Henri; Tutum, Cem Celal

    2013-01-01

    In the present study, three dimensional (3D) numerical modeling strategies of a thermosetting pultrusion process are investigated considering both transient and steady state approaches. For the transient solution, an unconditionally stable alternating direction implicit Douglas-Gunn (ADI-DG) sche...

  3. Physico-chemical, functional and processing attributes of some ...

    African Journals Online (AJOL)

    ajl yemi

    2011-12-26

    Dec 26, 2011 ... commercial processing and marketing chain is generally inevitable and ... was measured by a digital caliper (0 to 150 mm, China) with an accuracy of .... Spectrophotometer (GBC-932 Australlia), whereas Na and .... era ls (m g. /1. 0. 0 g. ) Figure 4. Correlation between ash (%) and total minerals (mg/100 g).

  4. Development of chemical conversion process of long-lived radionuclides

    International Nuclear Information System (INIS)

    Yoo, Jae Hyung; Lee, Byung Gik; Kang, Young Ho

    2001-05-01

    The objective of this project is to develop a conversion technology of long-lived radionuclides so that it can be a suitable form as a fuel or target in the nuclear transmutation system. During the first stage of the project (Apr 1997∼Mar 2001), the fundamental studies were performed with a focus on non-radioactive experiments as well as theoretical analyses in such areas as follows : fluorination of metals or metal oxides, electrorefining and electrowinning of actinides and lanthanides, pyro hydrolysis and regeneration of used molten salt. Since the chemical form of transuranium fuel in the transmutation system was assumed to be a molten fluoride, the electrolysis experiments of molten fluoride were conducted to study on the recovery of unused transuranium from the LiF-BeF 2 salt that was chosen as a basic salt medium. Fluorination of metals or metal oxides were also tested in this work by applying the method of three-phase (gas-liquid-solid) reaction. In the electrowinning experiments, the depositions of uranium, zirconium and niobium on the cathode were tested and analyzed. The electrorefining of lanthanides was studied with the salt media of FLINAK and FLICA and their behaviors were compared. In addition, the regeneration of used salts was examined by applying the method of electrolysis of molten salt, where alkali and alkali earth metals were found to be removed into the liquid lead cathode

  5. Ozone from fireworks: Chemical processes or measurement interference?

    Science.gov (United States)

    Xu, Zheng; Nie, Wei; Chi, Xuguang; Huang, Xin; Zheng, Longfei; Xu, Zhengning; Wang, Jiaping; Xie, Yuning; Qi, Ximeng; Wang, Xinfeng; Xue, Likun; Ding, Aijun

    2018-08-15

    Fireworks have been identified as one ozone source by photolyzing NO 2 or O 2 and are believed to potentially be important for the nighttime ozone during firework events. In this study, we conducted both lab and field experiments to test two types of fireworks with low and high energy with the goal to distinguish whether the visible ozone signal during firework displays is real. The results suggest that previous understanding of the ozone formation mechanism during fireworks is misunderstood. Ultraviolet ray (UV)-based ozone monitors are interfered by aerosols and some specific VOCs. High-energy fireworks emit high concentrations of particular matters and low VOCs that the artificial ozone can be easily removed by an aerosol filter. Low-energy fireworks emit large amounts of VOCs mostly from the combustion of the cardboard from fireworks that largely interferes with the ozone monitor. Benzene and phenol might be major contributors to the artificial ozone signal. We further checked the nighttime ozone concentration in Jinan and Beijing, China, during Chinese New Year, a period with intense fireworks. A signal of 3-8ppbv ozone was detected and positively correlated to NO and SO 2 , suggesting a considerable influence of these chemicals in interfering with ambient ozone monitoring. Copyright © 2018 Elsevier B.V. All rights reserved.

  6. Summary of LLNL's accomplishments for the FY93 Waste Processing Operations Program

    International Nuclear Information System (INIS)

    Grasz, E.; Domning, E.; Heggins, D.; Huber, L.; Hurd, R.; Martz, H.; Roberson, P.; Wilhelmsen, K.

    1994-04-01

    Under the US Department of Energy's (DOE's) Office of Technology Development (OTD)-Robotic Technology Development Program (RTDP), the Waste Processing Operations (WPO) Program was initiated in FY92 to address the development of automated material handling and automated chemical and physical processing systems for mixed wastes. The Program's mission was to develop a strategy for the treatment of all DOE mixed, low-level, and transuranic wastes. As part of this mission, DOE's Mixed Waste Integrated Program (MWIP) was charged with the development of innovative waste treatment technologies to surmount shortcomings of existing baseline systems. Current technology advancements and applications results from cooperation of private industry, educational institutions, and several national laboratories operated for DOE. This summary document presents the LLNL Environmental Restoration and Waste Management (ER and WM) Automation and Robotics Section's contributions in support of DOE's FY93 WPO Program. This document further describes the technological developments that were integrated in the 1993 Mixed Waste Operations (MWO) Demonstration held at SRTC in November 1993

  7. Nuclear fuel reprocessing deactivation plan for the Idaho Chemical Processing Plant, Revision 1

    International Nuclear Information System (INIS)

    Patterson, M.W.

    1994-10-01

    The decision was announced on April 28, 1992 to cease all United States Department of Energy (DOE) reprocessing of nuclear fuels. This decision leads to the deactivation of all fuels dissolution, solvent extraction, krypton gas recovery operations, and product denitration at the Idaho Chemical Processing Plant (ICPP). The reprocessing facilities will be converted to a safe and stable shutdown condition awaiting future alternate uses or decontamination and decommissioning (D ampersand D). This ICPP Deactivation Plan includes the scope of work, schedule, costs, and associated staffing levels necessary to achieve a safe and orderly deactivation of reprocessing activities and the Waste Calcining Facility (WCF). Deactivation activities primarily involve shutdown of operating systems and buildings, fissile and hazardous material removal, and related activities. A minimum required level of continued surveillance and maintenance is planned for each facility/process system to ensure necessary environmental, health, and safety margins are maintained and to support ongoing operations for ICPP facilities that are not being deactivated. Management of the ICPP was transferred from Westinghouse Idaho Nuclear Company, Inc. (WINCO) to Lockheed Idaho Technologies Company (LITCO) on October 1, 1994 as part of the INEL consolidated contract. This revision of the deactivation plan (formerly the Nuclear Fuel Reprocessing Phaseout Plan for the ICPP) is being published during the consolidation of the INEL site-wide contract and the information presented here is current as of October 31, 1994. LITCO has adopted the existing plans for the deactivation of ICPP reprocessing facilities and the plans developed under WINCO are still being actively pursued, although the change in management may result in changes which have not yet been identified. Accordingly, the contents of this plan are subject to revision

  8. Security risk assessment and protection in the chemical and process industry

    OpenAIRE

    Reniers, Genserik; van Lerberghe, Paul; van Gulijk, Coen

    2014-01-01

    This article describes a security risk assessment and protection methodology that was developed for use in the chemical- and process industry in Belgium. The approach of the method follows a risk-based approach that follows desing principles for chemical safety. That approach is beneficial for workers in the chemical industry because they recognize the steps in this model from familiar safety models .The model combines the rings-of-protection approach with generic security practices including...

  9. Leaching properties and chemical compositions of calcines produced at the Idaho Chemical Processing Plant

    International Nuclear Information System (INIS)

    Staples, B.A.; Paige, B.E.; Rhodes, D.W.; Wilding, M.W.

    1980-01-01

    No significant chemical differences were determined between retrieved and fresh calcine based on chemical and spectrochemical analyses. Little can be derived from the amounts of the radioisotopes present in the retrieved calcine samples other than the ratios of strontium-90 to cesium-137 are typical of aged fission product. The variations in concentrations of radionuclides within the composite samples of each bin also reflect the differences in compositions of waste solutions calcined. In general the leaching characteristics of both calcines by distilled water are similar. In both materials the radionuclides of cesium and strontium were selectively leached at significant rates, although cesium leached much more completely from the alumina calcine than from the zirconia calcine. Cesium and strontium are probably contained in both calcines as nitrate salts and also as fluoride salts in zirconia calcine, all of which are at least slightly soluble in water. Radionuclides of cerium, ruthenium, and plutonium in both calcines were highly resistant to leaching and leached at rates similar to or less than those of the matrix elements. These elements exist as polyvalent metal ions in the waste solutions before calcination and they probably form insoluble oxides and fluorides in the calcine. The relatively slow leaching of nitrate ion from zirconia calcine and radiocesium from both calcines suggests that the calcine matrix in some manner prevents complete or immediate contact of the soluble ions with water. Whether radiostrontium forms slightly fluoride salts or forms nitrate salts which are protected in the same manner as radiocesium is unknown. Nevertheless, selective leaching of cesium and strontim is retarded in some manner by the calcine matrix

  10. Development program of hydrogen production by thermo-chemical water splitting is process

    International Nuclear Information System (INIS)

    Ryutaro Hino

    2005-01-01

    The Japan Atomic Energy Research Institute (JAERI) has been conducting R and D on the HTGR and also on thermo-chemical water splitting hydrogen production by using a iodine-sulfur cycle (IS process) in the HTTR project. The continuous hydrogen production for one week was demonstrated with a bench-scale test apparatus made of glass, and the hydrogen production rare was about 31 NL/h. Based on the test results and know-how obtained through the bench-scale test, a pilot test plant, which has a hydrogen production performance of 30 Nm 3 /h and will be operated under the high pressure up to 2 MPa, is being designed conceptually as the next step of the IS process development aiming to realize a future nuclear hydrogen production coupled with the HTGR. In this paper, we will introduce one-week continuous hydrogen production conducted with the bench-scale test apparatus and the pilot test program including R and D and an analytical system necessary for designing the pilot test plant. MW. Figure 1 shows an overview of the HTTR-IS plant. In this paper, we will introduce latest test results obtained with the bench-scale test apparatus and concepts of key components of the IS process, a sulfuric acid (H 2 SO 4 ) and a sulfur trioxide (SO 3 ) decomposers working under high-temperature corrosive circumstance, are also introduced as well as relating R and D and an analytical system for the pilot plant design. (authors)

  11. A systems engineering approach to manage the complexity in sustainable chemical product-process design

    DEFF Research Database (Denmark)

    Gani, Rafiqul

    This paper provides a perspective on model-data based solution approaches for chemical product-process design, which consists of finding the identity of the candidate chemical product, designing the process that can sustainably manufacture it and verifying the performance of the product during...... application. The chemical product tree is potentially very large and a wide range of options exist for selecting the product to make, the raw material to use as well as the processing route to employ. It is shown that systematic computer-aided methods and tools integrated within a model-data based design...

  12. An improved probit method for assessment of domino effect to chemical process equipment caused by overpressure.

    Science.gov (United States)

    Mingguang, Zhang; Juncheng, Jiang

    2008-10-30

    Overpressure is one important cause of domino effect in accidents of chemical process equipments. Damage probability and relative threshold value are two necessary parameters in QRA of this phenomenon. Some simple models had been proposed based on scarce data or oversimplified assumption. Hence, more data about damage to chemical process equipments were gathered and analyzed, a quantitative relationship between damage probability and damage degrees of equipment was built, and reliable probit models were developed associated to specific category of chemical process equipments. Finally, the improvements of present models were evidenced through comparison with other models in literatures, taking into account such parameters: consistency between models and data, depth of quantitativeness in QRA.

  13. Liquid electrolyte positioning along the device channel influences the operation of Organic Electro-Chemical Transistors

    KAUST Repository

    D'angelo, Pasquale

    2014-11-01

    In this work, we show the influence of the liquid electrolyte adsorption by porous films made of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), PEDOT:PSS, on the operation of an Organic Electro-Chemical Transistor with an active channel based on these polymeric films. In particular, the effect of film hydration on device performance is evaluated by studying its electrical response as a function of the spatial position between the electrolyte and the channel electrodes. This is done by depositing a PEDOT:PSS film on a super-hydrophobic surface aimed at controlling the electrolyte confinement next to the electrodes. The device response shows that the confinement of ionic liquids near to the drain electrode results in a worsening of the current modulation. This result has been interpreted in the light of studies dealing with the transport of ions in semiconducting polymers, indicating that the electrolyte adsorption by the polymeric film implies the formation of liquid pathways inside its bulk. These pathways, in particular, affect the device response because they are able to assist the drift of ionic species in the electrolyte towards the drain electrode. The effect of electrolyte adsorption on the device operation is confirmed by means of moving-front measurements, and is related to the reproducibility of the device operation curves by measuring repeatedly its electrical response.

  14. Physico-chemical separation process of nanoparticles in cosmetic formulations

    International Nuclear Information System (INIS)

    Marín, R. R. Retamal; Babick, F.; Stintz, M.

    2017-01-01

    Understanding the world of nanoparticles, especially their interactions with the environment, begins with their correct detection and successive quantification. To achieve this purpose, one needs to perform correctly developed standard operating procedures (SOPs). Furthermore, the study of nanoparticles frequently requires their characterisation in complex media (e.g. in cosmetic formulations). In this study, a set of sample preparation procedures for the detection and extraction of NMs in emulsion-based formulations is proposed and their performance for model and real-life products is discussed. A separation or extraction of lipid phases is achieved by means of organic solvents. The polarity of the lipid phases is decisive for selecting an optimum solvent. The use of the Hansen Solubility Parameters (HSP) may clearly support this decision. (paper)

  15. Sustainable chemical processing and energy-carbon dioxide management: review of challenges and opportunities

    DEFF Research Database (Denmark)

    Frauzem, Rebecca; Vooradi, Ramsagar; Bertran, Maria-Ona

    2018-01-01

    This paper presents a brief review of the available energy sources for consumption, their effects in terms of CO2-emission and its management, and sustainable chemical processing where energy-consumption, CO2-emission, as well as economics and environmental impacts are considered. Not all available...... energy sources are being utilized efficiently, while, the energy source causing the largest emission of CO2 is being used in the largest amount. The CO2 management is therefore looking at "curing" the problem rather than "preventing" it. Examples highlighting the synthesis, design and analysis...... of sustainable chemical processing in the utilization of biomass-based energy-chemicals production, carbon-capture and utilization with zero or negative CO2-emission to produce value added chemicals as well as retrofit design of energy intensive chemical processes with significant reduction of energy consumption...

  16. An endothermic chemical process facility coupled to a high temperature reactor. Part II: Transient simulation of accident scenarios within the chemical plant

    International Nuclear Information System (INIS)

    Brown, Nicholas R.; Revankar, Shripad T.

    2012-01-01

    Highlights: ► Seven quantitative transient case studies were analyzed in a coupled PBMR and thermochemical sulfur cycle based hydrogen plant. ► Positive power excursion in the nuclear reactor were found for helium-inlet overcoolings. ► In all cases studied the maximum fuel temperatures in the nuclear reactor were 200 K below the design basis limit. - Abstract: Hydrogen generation using a high temperature nuclear reactor as a thermal driving vector is a promising future option for energy carrier production. In this scheme, the heat from the nuclear reactor drives an endothermic water-splitting plant, via coupling, through an intermediate heat exchanger. Transient study of the operational or accident events within the coupled plant is largely absent from the literature. In this paper, seven quantitative transient case studies are analyzed. The case studies consist of: (1) feed flow failure from one section of the chemical plant to another with an accompanying parametric study of the temperature in an individual reaction chamber, (2) product flow failure (recycle) within the chemical plant, (3) rupture or explosion within the chemical plant, (4) nuclear reactor helium inlet overcooling due to a process holding tank failure, (5) helium inlet overcooling as an anticipated transient without emergency nuclear reactor shutdown, (6) total failure of the chemical plant, (7) control rod insertion in the nuclear reactor. Various parametric studies based on the magnitude of the events were also performed. The only chemical plant initiated events that caused a positive power excursion in the nuclear reactor were helium-inlet overcoolings due to process holding tank failures or reaction chamber ruptures. Even for a severe sustained overcooling, the calculated maximum fuel temperatures in the nuclear reactor were 200 K below the design basis limit. The qualitative basis for the case studies and the analysis models are summarized in part I of this paper.

  17. Effects of chemical sensitizers on gamma radiation processing of ...

    African Journals Online (AJOL)

    The potential of gamma radiation processing in cross-linking natural rubber latex (NRL) for production of dipped goods has been studied. NRL produced in Ghana was irradiated to 10, 20, 30, 40 and 50 kGy, respectively, in a Gamma Chamber of dose rate 0.65 kGy/h. Irradiation of the NRL was also carried out in the ...

  18. Chemical modification of straw by alkaline treatment. [Trolmen process

    Energy Technology Data Exchange (ETDEWEB)

    1977-01-01

    In straw from 9 Swedish cereal cultivars of barley, oats, wheat, and rye, low molecular weight carbohydrates constituted only 0.3-1.4% of the straw with sucrose, glucose, fructose, and the sugar alcohols arabinitol and mannitol as main constituents. Hemicellulose (18-24%), cellulose (27-37%) and Klason-lignin (19-24%) were the main constituents. The ash (3-12%) and silica (0.5-3%) values showed rather high variations. After the Trolmen process, a wet closed NaOH treatment method, there was a slight enrichment of carbohydrates and ash and a decrease of Klason-lignin in the treated straw. About 1% of phenolic acids, mainly alpha ..beta.. -dihydro-p-coumatic, trans-p-coumaric, alpha ..beta.. -dihydroferulic and trans-ferulic acids, were quantified in the black liquid from the Trolmen process. These acids were probably ester-linked to the hemicellulose in the native straw and released during alkali treatment.HOAc, probably from Ac groups in xylan, and some of the silica were also released during the process. Although the amount of dissolved lignin was small, linkages between lignin and hemicellulosic polymers, perhaps also to cellulose, may be broken during the treatment. Linkages of these types may block the carbohydrates from enzymic action and reduce the digestibility. The higher digestibility of alkali-treated straw is probably due both to breaking of such linkages and to swelling of the polysaccharides rather than removal of any large amounts of undigestible components as lignin and silica.

  19. Quantifying solute transport processes: are chemically "conservative" tracers electrically conservative?

    Science.gov (United States)

    Singha, Kamini; Li, Li; Day-Lewis, Frederick D.; Regberg, Aaron B.

    2012-01-01

    The concept of a nonreactive or conservative tracer, commonly invoked in investigations of solute transport, requires additional study in the context of electrical geophysical monitoring. Tracers that are commonly considered conservative may undergo reactive processes, such as ion exchange, thus changing the aqueous composition of the system. As a result, the measured electrical conductivity may reflect not only solute transport but also reactive processes. We have evaluated the impacts of ion exchange reactions, rate-limited mass transfer, and surface conduction on quantifying tracer mass, mean arrival time, and temporal variance in laboratory-scale column experiments. Numerical examples showed that (1) ion exchange can lead to resistivity-estimated tracer mass, velocity, and dispersivity that may be inaccurate; (2) mass transfer leads to an overestimate in the mobile tracer mass and an underestimate in velocity when using electrical methods; and (3) surface conductance does not notably affect estimated moments when high-concentration tracers are used, although this phenomenon may be important at low concentrations or in sediments with high and/or spatially variable cation-exchange capacity. In all cases, colocated groundwater concentration measurements are of high importance for interpreting geophysical data with respect to the controlling transport processes of interest.

  20. Constructed wetlands for pollution control: processes, performance, design and operation

    National Research Council Canada - National Science Library

    2000-01-01

    .... Types of constructed wetland, major design parameters, role of vegetation, hydraulic patterns, loadings, treatment efficiency, construction, operation and maintenance costs are discussed in depth...