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Sample records for chemical milling

  1. Reusable neoprene jacket protects parts for chemical milling

    Science.gov (United States)

    1965-01-01

    Reusable neoprene jacket is used to prepare metal part or panel for chemical milling. Jacket covers back and upper rim of part and is sealed before the masking solution is applied to surface to be milled. This reduces amount of masking material required for milling identical parts and increases production.

  2. Chemical milling solution produces smooth surface finish on aluminum

    Science.gov (United States)

    Lorenzen, H. C.

    1966-01-01

    Elementary sulfur mixed into a solution of caustic soda and salts produces an etchant which will chemically mill end-grain surfaces on aluminum plate. This composition results in the least amount of thickness variation and pitting.

  3. Chemical-milling solution for invar alloy

    Science.gov (United States)

    Batiuk, W.

    1980-01-01

    Excellent surface finishes and tolerances are achieved using two formulations. Solution A gives finish of 3.17 micrometers after milling at 57 to 63 deg C. Constituents of A are: Hydrofluoric acid (70%), 5,8 oz/gal; nitric acid (40-42) degrees Baume), 40 oz/gal. Alternative solution gives 2.16 micrometer finish, and differs from A by addition of 7% phosphoric acid. Formulations eliminate channeling at root fillets, dishing, island formation, and overhangs.

  4. Fermentation and chemical treatment of pulp and paper mill sludge

    Science.gov (United States)

    Lee, Yoon Y; Wang, Wei; Kang, Li

    2014-12-02

    A method of chemically treating partially de-ashed pulp and/or paper mill sludge to obtain products of value comprising taking a sample of primary sludge from a Kraft paper mill process, partially de-ashing the primary sludge by physical means, and further treating the primary sludge to obtain the products of value, including further treating the resulting sludge and using the resulting sludge as a substrate to produce cellulase in an efficient manner using the resulting sludge as the only carbon source and mixtures of inorganic salts as the primary nitrogen source, and including further treating the resulting sludge and using the resulting sludge to produce ethanol.

  5. Analysis and Physico-Chemical Parameters of Sarvar Devla Sugar Mill Studies of Effluents

    Directory of Open Access Journals (Sweden)

    R. K. Pathak

    2012-12-01

    Full Text Available The physico-chemical characteristics contents in the effluents discharged from Neoly sugar mill have been explored. The physico-chemical parameters such as colour, odour, temperature, pH, electrical conductivity, COD, BOD, alkalinity, total hardness,Ca+2, Mg+2, chloride, of the effluent collected from the various sites between the exit point at the mill and discharge point In, have been determined.

  6. Replacing chemicals in recycle mills with mechanical alternatives

    Energy Technology Data Exchange (ETDEWEB)

    Institute of Paper Science Technology

    2002-07-01

    A high-intensity spark fired underwater decomposes a small amount of the water into hydroxyl radicals, which are strong oxidants. These are able to oxidize contaminants such as glue and wood pitch that enter paper recycling mills as a part of the incoming furnish and cost the industry several hundred million dollars. The sparking technique is safe, inexpensive, and is capable of treating large volumes of water, which makes it attractive for mill applications. Several mill trials were run. Sparking caused a decrease in the tack of the deposits in one case. Lower bleach use occurred in two other mills; sparking reduced the degree of ink reattachment to fiber. The payback for either application is attractive. Sparking induced deposition of contaminants in another mill, which is a positive development--if it can be controlled. The technique is also able to degas water and to oxidize odor-causing sulfur compounds. Although one unit has been purchased by a mill, second-order effects caused by the technology needs to be defined further before the technology can be broadly applied.

  7. Chemical Diversity in Lippia alba (Mill.) N. E. Brown Germplasm

    Science.gov (United States)

    Camêlo, Lídia Cristina Alves; Pinheiro, José Baldin; Andrade, Thiago Matos; Alves, Péricles Barreto

    2015-01-01

    The aim of this study was to perform chemical characterization of Lippia alba accessions from the Active Germplasm Bank of the Federal University of Sergipe. A randomized block experimental design with two replications was applied. The analysis of the chemical composition of the essential oils was conducted using a gas chromatograph coupled to a mass spectrometer. The chemical composition of the essential oils allowed the accessions to be allocated to the following six groups: group 1: linalool, 1,8-cineole, and caryophyllene oxide; group 2: linalool, geranial, neral, 1,8-cineol, and caryophyllene oxide; group 3: limonene, carvone, and sabinene; group 4: carvone, limonene, g-muurolene, and myrcene; group 5: neral, geranial, and caryophyllene oxide; and group 6: geranial, neral, o-cymene, limonene, and caryophyllene oxide. PMID:26075292

  8. Physico-chemical assessment of paper mill effluent and its heavy metal remediation using aquatic macrophytes--a case study at JK Paper mill, Rayagada, India.

    Science.gov (United States)

    Mishra, Swayamprabha; Mohanty, Monalisa; Pradhan, Chinmay; Patra, Hemanta Kumar; Das, Ritarani; Sahoo, Santilata

    2013-05-01

    The present investigation aims to assess the phytoremediation potential of six aquatic macrophytes, viz. Eichhornia crassipes, Hydrilla verticillata, Jussiaea repens, Lemna minor, Pistia stratiotes and Trapa natans grown in paper mill effluent of JK Paper mill of Rayagada, Orissa, for remediation of heavy metals. The experiment was designed in pot culture experiments. Assessment of physico-chemical parameters of paper mill effluent showed significant decrease in pH, conductivity, total dissolved solids, total suspended solids, chlorine, sulphur, biological and chemical oxygen demand after growth of macrophytes for 20 days. Phytoremediation ability of these aquatic macrophytic species for copper (Cu) and mercury (Hg) was indicated by assessing the decrease in the levels of heavy metals from effluent water. Maximum reduction (66.5 %) in Hg content of untreated paper mill effluent was observed using L. minor followed by T. natans (64.8 %). L. minor showed highest reduction (71.4 %) of Cu content from effluent water followed by E. crassipes (63.6 %). Phytoextraction potential of L. minor was remarkable for Hg and Cu, and bioaccumulation was evident from bioconcentration factor values, i.e. 0.59 and 0.70, respectively. The present phytoremediation approach was considered more effective than conventional chemical treatment method for removing toxic contaminants from paper mill effluent.

  9. Chemical reaction of hexagonal boron nitride and graphite nanoclusters in mechanical milling systems

    Energy Technology Data Exchange (ETDEWEB)

    Muramatsu, Y.; Grush, M.; Callcott, T.A. [Univ. of Tennessee, Knoxville, TN (United States)] [and others

    1997-04-01

    Synthesis of boron-carbon-nitride (BCN) hybrid alloys has been attempted extensively by many researchers because the BCN alloys are considered an extremely hard material called {open_quotes}super diamond,{close_quotes} and the industrial application for wear-resistant materials is promising. A mechanical alloying (MA) method of hexagonal boron nitride (h-BN) with graphite has recently been studied to explore the industrial synthesis of the BCN alloys. To develop the MA method for the BCN alloy synthesis, it is necessary to confirm the chemical reaction processes in the mechanical milling systems and to identify the reaction products. Therefore, the authors have attempted to confirm the chemical reaction process of the h-BN and graphite in mechanical milling systems using x-ray absorption near edge structure (XANES) methods.

  10. Application of mechano-chemical synthesis for protective coating on steel grinding media prior to ball milling of copper

    Indian Academy of Sciences (India)

    Indranil Lahiri; K Balasubramanian

    2007-04-01

    One of the major sources of contamination during mechanical milling/alloying is from the surface erosion of the container and the grinding medium. This can either be prevented by using grinding medium and container of same material of the milled material or by adding a coating of the milled material on them. The paper describes the observations made during a mechano-chemical reaction, being used for coating the balls and vials in a planetary ball mill. Visual observation, XRD, optical micrography and EDS analysis were used to understand the progress of the reaction. Copper was successfully coated on the steel balls and vials. The method can easily be adopted in daily production purposes, prior to mechanical milling of a Cu-based powder for prevention of Fe contamination.

  11. MgB2 ultrathin films fabricated by hybrid physical chemical vapor deposition and ion milling

    Directory of Open Access Journals (Sweden)

    Narendra Acharya

    2016-08-01

    Full Text Available In this letter, we report on the structural and transport measurements of ultrathin MgB2 films grown by hybrid physical-chemical vapor deposition followed by low incident angle Ar ion milling. The ultrathin films as thin as 1.8 nm, or 6 unit cells, exhibit excellent superconducting properties such as high critical temperature (Tc and high critical current density (Jc. The results show the great potential of these ultrathin films for superconducting devices and present a possibility to explore superconductivity in MgB2 at the 2D limit.

  12. MgB2 ultrathin films fabricated by hybrid physical chemical vapor deposition and ion milling

    Science.gov (United States)

    Acharya, Narendra; Wolak, Matthäus A.; Tan, Teng; Lee, Namhoon; Lang, Andrew C.; Taheri, Mitra; Cunnane, Dan; Karasik, Boris. S.; Xi, X. X.

    2016-08-01

    In this letter, we report on the structural and transport measurements of ultrathin MgB2 films grown by hybrid physical-chemical vapor deposition followed by low incident angle Ar ion milling. The ultrathin films as thin as 1.8 nm, or 6 unit cells, exhibit excellent superconducting properties such as high critical temperature (Tc) and high critical current density (Jc). The results show the great potential of these ultrathin films for superconducting devices and present a possibility to explore superconductivity in MgB2 at the 2D limit.

  13. Enhancement of dewatering performance of digested paper mill sludge by chemical pretreatment

    Science.gov (United States)

    Lin, Y. Q.; Zeng, C.; Wu, H. H.; Zeng, B. X.

    2016-08-01

    The wide application of anaerobic digestion (AD) for waste sludge results in a huge amount of digested sludge, while the appropriate reuse of digested sludge depends on effective solid-liquid separation. Thus, chemical (acid/alkali) pretreatment effects on dewaterability of digested paper mill sludge (DPMS) for better downstream reuse based on enhanced solid- liquid separation were investigated in this research. The dewatering properties of paper mill sludge (PMS) were also investigated to elucidate the impact of AD on sludge dewaterability. The results indicated that a higher DPMS dewaterability was noted with acid pretreatment (pH5). A 41.37% moisture content and 74.41% dewatering efficiency were determined for DPMS after acid (pH5) pretreatment within 25 min. In addition, a 7.13 mg•g-1 VSS of extracellular polymeric substances (EPS) and 101.50 μm of average particle size were observed. It was also observed that both EPS concentrations and particle sizes were key parameters influencing DPMS dewaterability. Lower EPS concentrations with larger average particle sizes contributed to enhanced sludge dewaterability. Moreover, dewaterability of PMS was higher than that of DPMS, which illustrated that AD would decrease the sludge dewaterability.

  14. CHEMICAL CHARACTERISATION AND DILUTE-ACID HYDROLYSIS OF RICE HULLS FROM AN ARTISAN MILL

    Directory of Open Access Journals (Sweden)

    Yoney López

    2010-09-01

    Full Text Available The chemical composition of rice hulls produced in an artisan mill and its conversion to fermentable sugars was investigated. The carbohydrate fraction represented 59.2% (w/w of the dry hulls. Cellulose, with 36.6%, was the main component, followed by xylan with 13.9%. An important contribution of starch (8.7% was also detected. The content of ash (19.6% and lignin (15.5% was comparable with that of rice hulls obtained in industrial mills. Dilute-sulphuric acid hydrolysis at different temperatures, from 160 to 210°C, was evaluated for production of fermentable sugars. Due to starch hydrolysis, the concentration of glucose in the hydrolysates produced at 160°C was higher than the values that have previously been reported for industrial sorts of rice hulls under comparable conditions. The xylan-to-xylose conversion increased steadily with increase of the temperature and reached a maximum (67.7% at 190°C. Further increases of the hydrolysis temperature decreased the yield of sugars due to their dehydration to furfural and HMF.

  15. Groundwater contamination from an inactive uranium mill tailings pile: 1. Application of a chemical mixing model

    Science.gov (United States)

    White, A. F.; Delany, J. M.; Narasimhan, T. N.; Smith, A.

    1984-11-01

    Low-pH process waters contained in a number of inactive and abandoned uranium mill tailings in the United States represent potential sources of radionuclide and trace metal contamination of groundwater. Detailed investigations at a typical site at Riverton, Wyoming, indicate that chemical transport occurs from initial dewatering of the tailings, downward infiltration due to precipitation, and groundwater intrusion into the base of the tailings pile. Except for elevated uranium and molybdenum concentrations, current radionuclide and trace metal transport is limited by the near-neutral pH conditions of the groundwater. Significant reactions include the dissolution of calcite, production of CO2, and precipitation of gypsum and the hydroxides of iron and aluminum. A geochemical mixing model employing the PHREEQE computer code is used to estimate current rates of the groundwater contamination by tailings water. A maximum mixing of 1.7% of pore water is a factor of 2 less than steady state estimates based on hydraulic parameters.

  16. Chemical milling of Zircaloy tubing to produce integral OD spiral finned tubes (AWBA development program)

    Energy Technology Data Exchange (ETDEWEB)

    Horwood, W.A.

    1982-02-01

    A detailed process description is provided for producing integral spiral fins on the outside surface of Zircaloy nuclear fuel cladding tubes by masking with pressure sensitive tape strips and then chemical milling (pickling) the tube wall between the tape strips to leave the fins in relief. Fins up to 0.020 inch high by 0.05 to 0.12 inch wide were consistently produced on tubes having wall thickness of 0.008 inch or greater after fin pickling. Wall thickness uniformity was excellent. Information is provided on tube surface preparation to maximize tape mask adhesion time during pickling, acid chemistry control to prevent local tube wall thinning near the fin, and pickling techniques to promote uniform material removal. Simple fixture designs are described for quickly and conveniently applying the tape strips to the tube wall in an accurate spiral. 13 figures, 4 tables.

  17. Chemical reactions of metal powders with organic and inorganic liquids during ball milling

    Science.gov (United States)

    Arias, A.

    1975-01-01

    Chromium and/or nickel powders were milled in metal chlorides and in organic liquids representative of various functional groups. The powders always reacted with the liquid and became contaminated with elements from them. The milled powders had specific surface areas ranging from 0.14 to 37 sq m/g, and the total contamination with elements from the milling liquid ranged from 0.01 to 56 weight percent. Compounds resulting from substitution, addition, or elimination reactions formed in or from the milling liquid.

  18. Chemical constituents of Phragmanthera austroarabica A. G. Mill and J. A. Nyberg with potent antioxidant activity

    Directory of Open Access Journals (Sweden)

    Jihan M Badr

    2015-01-01

    Full Text Available Background: Phragmanthera austroarabica A.G. Mill. and J. A. Nyberg is a semi parasitic plant belonging to family Loranthaceae. It was collected from Saudi Arabia. It is widely used in folk medicine among the kingdom in treatment of various diseases including diabetes mellitus. Objective: The total alcoholic extract of P. austroarabica collected from Saudi Arabia was investigated for the chemical structure and prominent biological activity of the main constituents. Materials and Methods: Isolation of the active constituents was performed using different chromatographic techniques including column chromatography packed with silica or sephadex and preparative thin layer chromatography. The structures of the isolated compounds were established based on different spectroscopic data as mass spectrum, one-dimensional and two-dimensional nuclear magnetic resonance (correlation spectroscopy, heteronuclear single quantum coherence, and heteronuclear multiple-bond correlation. Results: Phytochemical investigation of the plant resulted in isolation of 12 compounds. The isolated compounds were identified as chrysophanic acid, emodin, chrysophanic acid-8-O-glucoside, emodin-8-O-glucoside, pectolinarigenin, quercetin, dillenetin-3-O-glucoside, catechin, catechin-4′-O-gallate, methyl gallate, lupeol and ursolic acid. All the isolated phenolic compounds revealed significant free radical scavenging activities when tested using 2,2-diphenyl-1-picrylhydrazyl reagent. Conclusion: The antioxidant activities of the isolated compounds can justify the use of P. austroarabica in traditional medicine for treatment of diabetes and verify its possible application as an antihyperglycemic drug.

  19. Getting nanometric MoO{sub 3} through chemical synthesis and high energy milling

    Energy Technology Data Exchange (ETDEWEB)

    Santos-Beltrán, M. [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes No. 120, C.P. 31136 Chihuahua, Chih. (Mexico); Paraguay-Delgado, F., E-mail: francisco.paraguay@cimav.edu.mx [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes No. 120, C.P. 31136 Chihuahua, Chih. (Mexico); Santos-Beltrán, A. [Universidad Tecnológica de Chihuahua Sur, Km. 3 Carretera Chihuahua a Aldama s/n, C.P. 31050 Chihuahua, Chih. (Mexico); Fuentes, L. [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes No. 120, C.P. 31136 Chihuahua, Chih. (Mexico)

    2015-11-05

    The effects of high energy mechanical milling (HEMM) were studied on the microstructure and optical properties of MoO{sub 3} for hexagonal and orthorhombic phases. Employing HEMM was possible change particle size as a function of mechanical milling time, as well as the small quantity transformation percentage from hexagonal to orthorhombic phase. The relationship between microstrain and optical properties generated was studied. The electronic structures were calculated using the Density Functional Theory (DFT); to determinate partial density of state (PDOS). Band gap structure calculations show a good correlation between experimental and simulated data. The approximated values of microstrain, particle size, lattice parameters and oxygen vacancies were obtained employing the Rietveld refinement of X-ray diffraction patterns. Samples were characterized by electron microscopy techniques, surface area analysis (BET), thermal-gravimetric analysis (TGA), differential scanning calorimetry (DSC) and ultraviolet–visible spectroscopy (UV–Vis). It was possible, obtain particles with size below 40 nm by 30 min milling. - Graphical abstract: Orthorhombic phase, SEM image, SAED before milling, milling NPs, Particle size and band gap variation by milling time. - Highlights: • MoO{sub 3} with hexagonal and orthorhombic structures was synthesized selectively. • By milling short time (30 m), it was possible get 40 nm diameter particles. • The band gap decrease for nanoparticles, then corroborated by simulation. • MoO{sub 3} nanoparticles get high surface area for new technologic applications.

  20. Identification of Chemical Constituents in the Extract and Rat Serum from Ziziphus Jujuba Mill by HPLC-PDA-ESI-MSn.

    Science.gov (United States)

    Wang, Shuping; Zhang, Jingze; Zhang, Zhidan; Gao, Wenyuan; Yan, Yanan; Li, Xia; Liu, Changxiao

    2014-01-01

    Chinese jujube (Ziziphus jujuba Mill.) has long been widely used for human consumption and medicinal purposes in China. It has been reported to possess several vital biological activities. However, the systematic study on the chemical constituents absorbed into plasma and their metabolites is still insufficient.A high-performance liquid chromatography-photodiode array detector-electrospray ionization ion-mass spectrometry (HPLC-PDA-ESI-MS(n)) method was established to analyze the ethanol extract in Ziziphus jujuba Mill and the constituents absorbed into rat serum. In the present study, a dose of 10 mL/Kg of ethanol extract of jujube, which is equivalent to 12.5 g crude dried herb/Kg, was orally administrated to rats. The main components were analyzed in the ethanol extract of Ziziphus jujuba Mill and the parent constituents and metabolites were studied in rat plasma samples after oral administration of the ethanol extract of jujube.D101 macroporous polystyrene resin was a good pretreatment method to obtain better separation and impurity removal effect. Twenty-two compounds were identified in the ethanol extract of Ziziphus jujuba Mill. Four parent compounds and four metabolites were detected in rat serum. Among them, seventeen compounds were reported for the first time.

  1. Remediation of uranium mill tailings by an integrated biological and chemical process

    Energy Technology Data Exchange (ETDEWEB)

    Torma, A.E.

    1992-01-01

    Dilute calcium chloride brine solution was found to be effective in the solubilization of toxic heavy metals and long half-life radionuclides (Th-230, Ra-226 and Pb-210) from uranium ores and mill tailings. The recovery of heavy metals and radionuclides from uranium mill tailing effluents was studied with calcium alginate beads. The maximum cadmium and zinc uptakes by calcium alginate beads were determined to be 2.8 [times] 10[sup [minus]3] and 2.3 [times] 10[sup [minus]3] mol/dry weight of alginate. The kinetic values, V[sub m] and K, were calculated for uranium uptake by calcium alginate to be 96.2 mg/l/s and 0.125 g/l, respectively.

  2. Remediation of uranium mill tailings by an integrated biological and chemical process

    Energy Technology Data Exchange (ETDEWEB)

    Torma, A.E.

    1992-12-31

    Dilute calcium chloride brine solution was found to be effective in the solubilization of toxic heavy metals and long half-life radionuclides (Th-230, Ra-226 and Pb-210) from uranium ores and mill tailings. The recovery of heavy metals and radionuclides from uranium mill tailing effluents was studied with calcium alginate beads. The maximum cadmium and zinc uptakes by calcium alginate beads were determined to be 2.8 {times} 10{sup {minus}3} and 2.3 {times} 10{sup {minus}3} mol/dry weight of alginate. The kinetic values, V{sub m} and K, were calculated for uranium uptake by calcium alginate to be 96.2 mg/l/s and 0.125 g/l, respectively.

  3. Chemical oxidation methods in the closure of paper mill water circulations; Hapetustekniikoiden kaeyttoe metsaeteollisuuden vesikiertojen sulkemisessa - EKT 04

    Energy Technology Data Exchange (ETDEWEB)

    Laari, A.; Kallas, J. [Lappeenranta Univ. of Technology (Finland); Korhonen, S. [Kuopio Univ. (Finland); Tuhkanen, T. [Mikkelin Ammattikorkeakoulu, Mikkeli (Finland)

    1998-12-31

    When water circulations are closed some harmful compounds tend to accumulate in the circulation waters. These compounds include lipophilic extractives, like resin and fatty acids, triglycerides and sterols, but also other compounds, like lignins, lignans and sugars. Microbial growth will increase due to elevated organic concentrations. The purpose of this project is to find out the possibilities of the use of ozonation and wet oxidation in the treatment of paper mill water circulations. In chemical oxidation organic matter is destroyed in oxidation reactions. Especially lipophilic extractives are selectively oxidated by ozone. Chemical oxidation reactions are carried out in gas-liquid reactors, where ozone or oxygen are transferred from gas to liquid phase where the oxidation reactions happen. One target of the project is to estimate kinetic parameters for different groups of compounds on the basis of experimental data. Kinetic parameters are then used in modelling of reactors and in estimation of process costs. (orig.)

  4. MgB2UltrathinFilms Fabricated by Hybrid Physical Chemical Vapor Deposition and Subsequent Ion Milling

    Science.gov (United States)

    Acharya, Narendra; Wolak, Matthaeus; Tan, Teng; Cunnane, Daniel; Karasik, Boris; Xi, Xiaoxing

    Hot electron bolometer (HEB) mixers are a great tool for measuring high-resolution spectroscopy at Terahertz frequencies. MgB2offers a higher critical temperature (39 K) compared to commonly used Nb and NbN and boasts a shorter intrinsic electron-phonon relaxation time, giving rise to a broader intermediate frequency (IF) bandwidth. We have fabricated high quality ultrathin MgB2films using hybrid physical-chemical vapor deposition (HPCVD) and employing ion milling to achieve thickness down to 2 nm. The thinnest achieved films show high Tc of 28 K with residual resistivity below 28 µ Ωcm and high critical current Jcof 1x106 A/cm2at 20 K. As a result of the employed low angle ion milling process, the films remain well connected even after being thinned down since the initial thick films offer a better connectivity than as-grown thin films. The established process offers a way to realize MgB2 based HEB mixers of extremely low thickness and therefore small local oscillator power requirements and increased IF bandwidth.

  5. A study of chemical and microbiological characteristics of olive mill waste water in Morocco

    Directory of Open Access Journals (Sweden)

    Mouncif, M.

    1993-12-01

    Full Text Available Olive mill waste water samples from different traditional mills were analyzed for their microbiota and the physicochemical characteristic. A survey of the most frequent microorganisms including standard plate count (SPG, counts of the indicator microorganisms (total and fecal coliforms and enterococci staphylococci, Salmonella, sporeforming bacteria (Clostridium and Bacillus, yeasts and molds and the lipolytic microorganisms. The physicochemical analysis grouped the determination of pH, salinity, density, conductivity, alkalinity, acidity, total dry matter, non volatile dry matter, suspended solids, organic carbon, ammoniacal nitrogen, organic nitrogen, fat, polyphenols, polyphosphates, sodium and potassium and the BOD and COD. Results showed that the physicochemical factors were higher than the reported values in other countries. The microbial load was low and mainly made of yeasts and molds as well as the lactic acid bacteria. A net difference between the traditional mill samples and the industrial samples was observed for both analyses.

    Se ha realizado un estudio bacteriológico y físico químico de alpechín de diferentes almazaras tradicionales. Se han investigado los siguientes parámetros físico químicos: pH, salinidad, densidad, conductividad, alcalinidad, acidez, materia seca total, materia seca volátil, materia en suspensión, carbono orgánico, nitrógeno amoniacal, nitrógeno orgánico, grasa, polifenoles, fosfatos, sodio, potasio, BOD y COD. Las determinaciones microbiológicas efectuadas son: recuento de aerobios mesofilos, conliformes totales y fecales, enterococos, Staphylococcus, Salmonella, esporulados (Clostridium y Bacillus, levaduras, mohos y microorganismos lipolíticos. Los valores de los parámetros físico químicos son superiores comparados con los obtenidos por otros autores en otros países. La carga microbiana es débil y está representada principalmente por

  6. 21 CFR 173.320 - Chemicals for controlling microorganisms in cane-sugar and beet-sugar mills.

    Science.gov (United States)

    2010-04-01

    ...-sugar and beet-sugar mills. 173.320 Section 173.320 Food and Drugs FOOD AND DRUG ADMINISTRATION... controlling microorganisms in cane-sugar and beet-sugar mills. Agents for controlling microorganisms in cane-sugar and beet-sugar mills may be safely used in accordance with the following conditions: (a) They...

  7. Effect of Different Doses of NK Chemical Fertilizers and Compost on Growth and Yield Attributes of Tomato (Lycopersicon esculentum Mill.

    Directory of Open Access Journals (Sweden)

    Thayamini Harold Seran

    2016-07-01

    Full Text Available This study was conducted to evaluate the effect of NK chemical fertilizers in combination with compost on the growth and yield attributes of tomato (Lycopersicon esculentum Mill.. The pot experiment was done in a complete randomized block design possessing eight treatments with four replicates. Fruit weight, pulp weight, seed weight, total soluble solid, leaf area and dry weights of plat parts were taken and fruit yield was calculated. All the collected data were subjected to statistical analysis. The results revealed that there were significant differences in fruit and seed weights, total soluble solid, pulp weight, 100 seed weight, pulp consistency, leaf area and crop residue. In these parameters, higher mean values were recorded in chemical fertilizers (7.5 g N + 6 g K2O + 15 g P2O5 per m2 with compost (2 kg per m2 than those in the chemical fertilizers applied alone (9.0 g N + 8 g K2O + 15 g P2O5 per m2as standard control. Total soluble solid and fruit yield were 5.73 obrix and 3.21 kg/m2 respectively in the chemical fertilizers with compost (7.5 g N + 6 g K2O + 15 g P2O5 +2 kg compost per m2 treated plants and these were statically on par with the standard control which gave 4.36 obrix total soluble solid and 3.05 kg/m2 fruit yield. The result could be concluded that application of chemical fertilizers (7.5 g N + 6 g K2O + 15 g P2O5 per m2 with compost (2 kg per m2 could increase the total soluble solid and fruit yield as well as reduce the usage of chemical fertilizers in tomato cultivation over the standard control in sandy regosol.

  8. Chemical and cellular antioxidant activity of phytochemicals purified from olive mill waste waters.

    Science.gov (United States)

    Angelino, Donato; Gennari, Lorenzo; Blasa, Manuela; Selvaggini, Roberto; Urbani, Stefania; Esposto, Sonia; Servili, Maurizio; Ninfali, Paolino

    2011-03-09

    The isolation and identification of a phytocomplex from olive mill waste waters (OMWW) was achieved. The isolated phytocomplex is made up of the following three phenolic compounds: hydroxytyrosol (3,4-DHPEA), tyrosol (p-HPEA) and the dialdehydic form of decarboxymethyl elenolic acid, linked with (3,4-dihydroxyphenyl)ethanol (3,4-DHPEA-EDA). The purification of this phytocomplex was reached by partial dehydration of the OMWW, followed by liquid-liquid extraction with ethyl acetate and middle pressure liquid chromatography (MPLC) on a Sephadex LH-20 column. The phytocomplex accounted for 6% of the total phenolic content of the OMWW. The phytocomplex and individual compounds were tested for antioxidant capacity by the oxygen radical absorbance capacity (ORAC) method. The ORAC phytocomplex produced 10,000 ORAC units/g dry weight, whereas the cellular antioxidant activity, measured by the cellular antioxidant activity in red blood cell (CAA-RBC) method, demonstrated that the phytocomplex and all of the components are able to permeate the cell membrane thus exhibiting antioxidant activity inside the red blood cells. Our phytocomplex could be employed in the formulation of fortified foods and nutraceuticals, with the goal to obtain substantial health protective effects due to the suitable combination of the component molecules.

  9. Chemical composition and metabolizable energy values of corn germ meal obtained by wet milling for layers

    Directory of Open Access Journals (Sweden)

    CS Albuquerque

    2014-03-01

    Full Text Available An experiment was carried out to determine the chemical composition, metabolizable energy values, and coefficients of nutrient digestibility of corn germ meal for layers. The chemical composition of corn germ meal was determined, and then a metabolism assay was performed to determine its apparent metabolizable energy (AME and apparent metabolizable energy corrected for nitrogen (AMEn values and its dry matter and gross energy apparent metabolizability coefficients (CAMDM and CAMGE, respectively. In the 8-day assay (four days of adaptation and four days of total excreta collection, 60 29-week-old white Lohman LSL layers were used. A completely randomized experimental design, with three treatments with five replicates of four birds each, was applied. Treatments consisted of a reference diet and two test diets, containing 20 or 30% corn germ meal. Results were submitted to analysis of variance and means were compared by the Tukey tests at 5% probability level. The chemical composition of corn germ meal was: 96.39% dry matter, 49.48% ether extract, 1.87% ashes, 7243 kcal gross energy/kg, 11.48% protein, 0.19% methionine, 0.21% cystine, 0.48% lysine, 0.40% threonine, 0.72% arginine, 0.35% isoleucine, 0.83% leucine, 0.57% valine, and 0.37% histidine, on as-fed basis. There were no statistical differences in AME, AMEn, CAMDM, and CAMGE values with the inclusion of 20 and 30% corn germ meal in the diets. On dry matter basis, AME, AMEn, CAMDM, and CAMGE values of corn germ meal were: 4,578 and 4,548 kcal/kg, 4,723 and 4,372 kcal/kg, 64.95 and 61.86%, respectively.

  10. Dose and frequency dependent effects of olive mill wastewater treatment on the chemical and microbial properties of soil.

    Science.gov (United States)

    Magdich, Salwa; Ben Ahmed, Chedlia; Jarboui, Raja; Ben Rouina, Béchir; Boukhris, Makki; Ammar, Emna

    2013-11-01

    Olive mill wastewater (OMW) is a problematic by-product of olive oil production. While its high organic load and polyphenol concentrations are associated with troublesome environmental effects, its rich mineral and organic matter contents represent valuable nutrients. This study aimed to investigate the valorization of this waste biomass as a potential soil conditioner and fertilizer in agriculture. OMW was assayed at three doses 50, 100, and 200 m(3) ha(-1) year(-1)) over three successive years in olive fields. The effects of the effluent on the physico-chemical and microbial properties of soil-layers were assessed. The findings revealed that the pH of the soil decreased but electrical conductivity and organic matter, total nitrogen, sodium, and potassium soil contents increased in proportion with OMW concentration and frequency of application. While no variations were observed in phosphorus content, slow increases were recorded in calcium and magnesium soil contents. Compared to their control soil counterparts, aerobic bacteria and fungi increased in proportion with OMW spreading rates. The models expressing the correlation between progress parameters and OMW doses were fitted into a second degree polynomial model. Principal component analysis showed a strong correlation between soil mineral elements and microorganisms. These parameters were not related to phosphorus and pH.

  11. Treatment of olive-mill wastewater from a two-phase process by chemical oxidation on an industrial scale.

    Science.gov (United States)

    Nieto, L M; Hodaifa, G; Vives, S R; Casares, J A G; Driss, S B; Grueso, R

    2009-01-01

    This study offers a solution for reducing the environmental effect of wastewaters generated by the olive-oil industry. Olive-oil companies produce variable quantities of wastewaters, which require treatment for disposal or reuse. Today, regulations are becoming increasingly strict regarding the parameters measured in these effluents. In Spain, the resolution by the president of the Hydrographical Confederation of the Guadalquivir on water use 2004 set parameter limits as follows: pH = 6.0-9.0, total suspended solid = 500 mg/L; and COD and BOD(5) (20)=1,500 mg O(2)/L. For the year 2006, maximum values for COD and BOD(5) (20) were fixed at 1,000 mg O(2)/L. To solve this problem, a study has been made to derive irrigation water from the above-mentioned effluents through chemical oxidation based on the Fenton's process. This would be first step towards using a closed-circuit system in olive-oil mills to treat and reuse effluents.

  12. Chemical investigation of the volatile components of shade-dried petals of damask rose (Rosa damascena Mill.

    Directory of Open Access Journals (Sweden)

    Verma Swaroop Ram

    2011-01-01

    Full Text Available Roses are always appreciated because of their inimitable aroma, many uses and of course their beauty. In addition to the different damask rose (Rosa damascena Mill. products (oil, water, concrete, absolute, gulkand etc., its dried petals are also used for various health purposes. The hydrodistilled volatile oil and water of shade-dried damask rose petals were investigated by GC and GC-MS. The predominant components of tThe essential oil and rose water were aliphatic hydrocarbons (56.4 and 46.3%, followed by oxygenated monoterpenes (14.7 and 8.7%. The main aliphatic hydrocarbons of the essential oil and rose water were heneicosane (19.7 and 15.7%, nonadecane (13.0 and 8.4%, tricosane (11.3 and 9.3% and pentacosane (5.3 and 5.1% while the content of 2-phenyl ethyl alcohol was 0.4% and 7.1% in the essential oil and rose water, respectively. The chemical composition of the dried rose petal volatiles is quite different from fresh flower volatiles.

  13. Anatomical, chemical, and biochemical characterization of cladodes from prickly pear [Opuntia ficus-indica (L.) Mill.].

    Science.gov (United States)

    Ginestra, Giovanna; Parker, Mary L; Bennett, Richard N; Robertson, Jim; Mandalari, Giuseppina; Narbad, Arjan; Lo Curto, Rosario B; Bisignano, Giuseppe; Faulds, Craig B; Waldron, Keith W

    2009-11-11

    Opuntia ficus-indica cladodes represent the green stem of the plant and are generally used as animal feed or disposed of in landfills. The present work investigated the anatomical and chemical composition of Opuntia cladodes, which form the basis of their pharmacological effects. Glucose and galacturonic acid were the main sugars of Opuntia cladodes, whereas high-performance liquid chromatography (HPLC) analysis showed the presence of mainly kaempherol and isorhamnetin glycosides (glucoside and rhamnoside). The presence of high amounts of calcium oxalate crystals was demonstrated by light microscopy on fresh and lyophilized cladodes. No antimicrobial activity was observed even after enzymatic treatment. O. ficus-indica cladodes may retain material tightly associated with cell-wall components, and this property will have the potential to greatly reduce the bioavailability of bioactive compounds.

  14. Effect of spent cotton stalks on color removal and chemical oxygen demand lowering in olive oil mill wastewater by white rot fungi.

    Science.gov (United States)

    Kahraman, S; Yeşilada, O

    1999-01-01

    Wastewater from olive oil mill was decolorized (and its chemical oxygen demand reduced in static cultivation) using the fungi Coriolus versicolor, Funalia trogii, Phanerochaete chrysosporium and Pleurotus sajor-caju. The effect of cotton stalk on decolorizing and COD removing capability was demonstrated. P. chrysosporium (in 20% medium with cotton stalk) reduced the COD by 48% and color by 58%, F. trogii (in 30% medium with cotton stalk)) by 51 and 55%, respectively.

  15. RE-UTILIZATION OF INORGANIC SOLID WASTE (LIME MUD AS FOREST ROAD STABILIZER FROM THE CHEMICAL RECOVERY PROCESS IN KRAFT PULP MILL

    Directory of Open Access Journals (Sweden)

    Habip Eroğlu

    2005-04-01

    Full Text Available Waste handling is a concern in all pulp and paper mills. Best available techniques for reducing waste is to minimize the generation of solid waste and/or reuse these materials, wherever practicable. One of the most important solid wastes is lime mud which is generated from the kraft pulping in its chemical recovery process. This paper explores the composition of lime mud resulting from the chemical recovery unite of kraft pulp mill and investigation of this waste for re-using beneficially on sub grade and pavement of forest road as a alternative disposal method. Lime mud obtained from the re-causticising process in SEKA pulp mill that utilizes wheat straw and reed as the principal raw material was supplied with % 47 water content and its chemical and physical characterisations was performed according to standard methods. Dried waste to environmental condition was mixed with certain amount to composite cement for using on pavement and sandy clay, loamy clay and clay soils for enriching forest road sub grade properties. In order to investigate the lime mud addition on pavement and sub grade properties necessary physical tests were performed. As a consequence this study reveals that while waste of lime mud causes environmental and economical problem with conventional disposal techniques and/or abandoning to environment, this waste can be used as good stabilisation materials on forest road sub-grade and pavement without any environmental problem.

  16. Chemical Attributes of Soil Fertilized with Cassava Mill Wastewater and Cultivated with Sunflower

    Directory of Open Access Journals (Sweden)

    Mara Suyane Marques Dantas

    2014-01-01

    Full Text Available The use of waste arising from agroindustrial activities, such as cassava wastewater, has been steadily implemented in order to reduce environmental pollution and nutrient utilization. The aim of this study is that the changes in chemical properties of dystrophic red-yellow latosol (oxisol were evaluated at different sampling times after reuse of cassava wastewater as an alternative to mineral fertilizer in the cultivation of sunflower, hybrid Helio 250. The experiment was conducted at the Experimental Station of the Agricultural Research Company of Pernambuco (IPA, located in Vitória de Santo Antão. The experimental design was randomized blocks with 6×5 subplots; six doses of cassava wastewater (0; 8.5; 17.0; 34.0; 68.0; and 136 m3 ha−1; and five sampling times (21, 42, 63, 84, and 105 days after applying the cassava wastewater, with four replications. Concentrations of available phosphorus and exchangeable potassium, calcium, magnesium and sodium, pH, and electrical conductivity of the soil saturation extract were evaluated. Results indicate that cassava wastewater is an efficient provider of nutrients to the soil and thus to the plants, making it an alternative to mineral fertilizers.

  17. Phenotypic Variations in the Foliar Chemical Profile of Persea americana Mill. cv. Hass.

    Science.gov (United States)

    García-Rodríguez, Yolanda Magdalena; Torres-Gurrola, Guadalupe; Meléndez-González, Claudio; Espinosa-García, Francisco J

    2016-12-01

    The Hass avocado tree Persea americana cv. Hass was derived from a single hybrid tree of P. americana var. drymifolia and P. americana var. guatemalensis, and it is propagated clonally by grafting. This cultivar is the most widely planted in the world but its profile of secondary metabolites has been studied rarely despite of its importance in plant protection. We illustrate the variability of the volatilome of mature leaves by describing the average chemical composition and the phenotypic variability found in 70 trees. Contrary to the uniformity expected in the Hass cultivar, high variability coefficients were found for most of the 36 detected foliar volatile compounds; furthermore we found six chemotypes grouping the foliar phenotypes of the sampled trees using hierarchical cluster analysis. About 48% of trees were grouped in one chemotype; five chemotypes grouped the remaining trees. The compounds that determined these chemotypes were: estragole, α-farnesene, β-caryophyllene, germacrene D, α-cubebene and eugenol. This striking variation in a cultivar propagated clonally is discussed in terms of somatic mutation.

  18. Utilizing Palm Oil Mill Effluent Compost for Improvement of Acid Mineral Soil Chemical Properties and Soybean Yield

    Directory of Open Access Journals (Sweden)

    Ermadani Ermadani

    2013-09-01

    Full Text Available Effluent from a palm oil mill contains organic matters and nutrients. It can result in water pollution when it is discharged into river without treatment. One way to manage this effluent is through composting that has potential to allow the recycling of effluent nutrients in a sustainable and environmentally friendly manner so that it can be used as organic fertilizer. This study wasintended to evaluate the benefit of effluent compost application to improve soil chemical properties and soybean yield. Effluent wascomposted with chicken manure and lime for eight weeks. A pot experiment of which each pot was filled with 10 kg of soil (Ultisolwas conducted in a screen house from April to November 2012 at the Experimental Farm, University of Jambi, Muaro JambiResidency. The treatments were without compost (adding 0,25 g Urea, 0,75 g SP-36 and 0,50 g KCl and compost application with amounts of 12,5 ml, 25 ml, 37,5 ml, 50 ml, 62,5 ml, and 75 ml. The indicator plant was soybean. The treatments were arranged in acompletely randomized design and replicated four times. Results of study showed a significant improvement of soil chemicalproperties with compost application in which application of 75 ml compost resulted in the highest increase of pH, organic C, cationexchange capacity, total N, available P, exchangeable cations (K, Ca, Mg. Furthermore, the dry weight of shoot, pod number and dryweight of seed increased significantly with compost application. The highest dry weight of seed was 28 g (equivalent to 2, 82 t ha-1obtained by compost application of 75 ml (equivalent to 15 t ha -1.

  19. Research upon the quality assurance of the rolling-mill rolls and the variation boundaries of the chemical composition

    Directory of Open Access Journals (Sweden)

    Kiss, I.

    2008-08-01

    Full Text Available The cast-iron rolls must present higher hardness at the rolling surface and lower in the core and the necks, adequate with mechanical resistance and in the high work temperature. If in the zone of the rolling surface, the hardness is guarantied by the irons structure, through the cementite quantities, the core of rolls must contain graphite, to assure this property. Starting from the lamination equipments aspects, from the form of rolls, of the technological interest zones and the structure, which assures the exploitation property, it was establish, through modeling, to the mathematical description of a direct influences, and in final, through successive determinations, to an optimum. One of the parameters, which are determined the structure of the irons destined for rolls casting, is the chemical composition, which guaranties the exploitation properties of the each roll in the stand of rolling mill. The realization of optimum chemical compositions of the cast-iron can constitute a technical efficient way to assure the exploitation properties, the material from which the rolling mills rolls are manufactured having an important role in this sense. Although the manufacture of rolls is in continuously perfecting, the requirements for superior quality rolls are not yet completely satisfied, in many cases, the absence of quality rolls preventing the realization of quality laminates or the realization of productivities of which rolling mills are capable. This paper presents an analysis of the main alloying elements from chemical composition, the influences upon the mechanical properties of the cast-iron rolls, and presents also some graphical addenda. Using the Matlab calculation and graphical programs we determinate some correlations between the hardness (on the working surface and on necks and the chemical composition. Using the double and triple correlations is really helpful in the foundry practice, as it allows us to determine variation

  20. Ability of the aquatic fern Azolla to remove chemical oxygen demand and polyphenols from olive mill wastewater

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    Sacchi, Angelo

    2007-03-01

    Full Text Available We investigated the biofiltration ability of the aquatic fern Azolla to remove polyphenols and chemical oxygen demand (COD from olive mill wastewater (OMWw collected from the traditional (TS and continuous (CS extraction systems. Azolla biomass was packed into five sequential Imhoff cones and five sequential columns. In both experiments, the filtrates collected from the 5th biofilter showed a decrease in polyphenol contents: from 7650 mg l–1 to 3610 mg l–1 in TS OMWw and from 3852 mg l–1 to 1351 mg l–1 in CS OMWw. The COD contents decreased from 110200 mg L–1 to 52400 mg L–1 in TS OMWw and from 41600 mg L–1 to 2300 mg L–1 in CS OMWw. A 5:1 OMWw to Azolla-fresh-weight ratio was optimal for both polyphenol and COD removal. The biofiltration ability of alfalfa was compared with that of Azolla, but the treatment with alfalfa did not result in the reduction of COD or polyphenols.La eficacia del helecho de agua azolla para eliminar polifenoles y reducir la demanda química de oxígeno (DQO de los alpechines obtenidos en el proceso de obtención tradicional y continuo del aceite de oliva, fue investigado mediante ensayos de filtración. Cinco conos secuenciales de Imhoff y cinco columnas secuenciales se rellenaron de biomasa de Azolla. En ambos experimentos, el filtrado procedente de la quinta extracción mostró una disminución en el contenido de polifenoles de 7650 mg L–1 a 3610 mg L–1en el alpechín obtenido mediante el sistema tradicional y de 3852 mg L–1 a 1351 mg L–1en el alpechín del sistema continuo. La demanda química de oxígeno del alpechín del sistema tradicional disminuyó de 110200 mg L–1 a 52400 mg L–1 en y de 41600 mg L–1a 2300 mg L–1en el procedente del sistema continuo. Una proporción en peso 5:1 de alpechín: Azolla fue la óptima tanto para la reducción de los polifenoles como para la de la DQO. La eficiencia del tratamiento biológico con alfalfa se comparó con la obtenida con Azolla. Los

  1. Chemical composition, antimicrobial and antioxidant activities of anethole-rich oil from leaves of selected varieties of fennel [Foeniculum vulgare Mill. ssp. vulgare var. azoricum (Mill.) Thell].

    Science.gov (United States)

    Senatore, Felice; Oliviero, Filomena; Scandolera, Elia; Taglialatela-Scafati, Orazio; Roscigno, Graziana; Zaccardelli, Massimo; De Falco, Enrica

    2013-10-01

    The chemical composition and biological activity of the essential oils obtained from the leaves of two different cultivars of Florence fennel cropped under three different fertilization treatments (Control not fertilized; Mineral Fertilization; Compost from Municipal Solid Wastes) have been analyzed. All the oils were characterized by high anethole concentration and some showed also a good percentage of limonene. Thus, the leaves of Florence fennel, which are agricultural wastes, could be used for the recovery of anethole to be used for its flavoring and biomedical properties. The antimicrobial activity expressed by assays on the examined oils indicates an appreciable effect, generally higher on Gram-positive bacteria. The various samples of Florence fennel analyzed did not show any results with FRAP test. The DPPH test showed a weak capacity of the samples to catch the free radicals from the solution, attributable to their content in anethole.

  2. Chemical characterisation and in vitro assessment of the nutritive value of co-products yield from the corn wet-milling process.

    Science.gov (United States)

    Malumba, Paul; Boudry, Christelle; Roiseux, Olivier; Bindelle, Jérôme; Beckers, Yves; Béra, François

    2015-01-01

    The chemical characteristics of co-products recovered during a laboratory-scale wet milling procedure as well as that of whole corn flour were characterised and their digestibility and fermentability value determined using a 2 steps in vitro digestibility and fermentation model of the pig digestive tract. Five co-products differing in their chemical composition were collected and analysed. These co-products differed in their in vitro dry matter Digestibility and in their kinetic of fermentation. High coefficients of digestibility were observed for starchy samples, while low coefficients of digestibility were observed for samples rich in lignocellulosic components. Fermentation patterns of samples analysed were different as well as the profile of volatile fatty acids produced during the fermentation. The production of straight-chain fatty acids produced was significantly correlated with the proportion of starch in the sample, while branched-chain fatty acids were correlated to proteins concentration of samples.

  3. Decolourisation of palm oil mill biogas plant wastewater using Poly-Diallyldimethyl Ammonium Chloride (polyDADMAC) and other chemical coagulants

    Science.gov (United States)

    Zahrim, A. Y.; Dexter, Z. D.

    2016-06-01

    Palm oil mill effluent was expected as a future source of renewable biogas. Nevertheless,colours in palm oil mill biogas plant wastewater (POMBPW) causes negative perception among the public and the wastewater is difficult to be treated biologically. In this study, the performance of various chemical coagulants i.e., calcium lactate, magnesium hydroxide, ferric chloride, aluminium chlorohydrate i.e. CK-800, CK-1000, and polyDADMAC, forPOMBPW colour removal were investigated. PolyDADMAC (1,000 mg/L) shows best colour removal (∼48%). The main coagulation process with polyDADMACcould be due to charge neutralization-bridging mechanism. The zeta potential analysis supports the finding where the value became positive as the dosage increases. The addition of polyDADMAC has increased the conductivity of the treated wastewater up to 9.22%; however, the final pH is maintained (8.0-8.3). It can be deduced that polyDADMAC has potential to treat POMBPW at low dosage.

  4. Chemical Constituents of Foeniculum vulgare Mill.%小茴香根的化学成分研究

    Institute of Scientific and Technical Information of China (English)

    张嫩玲; 马青云; 胡江苗; 周俊; 赵友兴

    2011-01-01

    Five known compounds were isolated from the roots of Foeniculum vulgare Mill.. On the basis of MS and NMR analysis, these compounds were determined as dillapiol ( 1 ), sucrose linoleate (2),3R, 8S,9Z-falcarindiol (3) ,β-sitosterol (4) ,and stigmasteryl-β-D-glueopyranoside (5) ,among which two compounds (2 and 3) were obtained from this plant for the first time.%从小茴香(Foeniculum vulgare Mill.)根的乙醇提取物中分离得到了5个化合物,通过MS和NMR等方法鉴定为:莳萝脑(1),亚油酸蔗糖苷(2),镰叶芹二醇(3),β-谷甾醇(4),豆甾醇-β-D-吡喃葡萄糖苷(5),其中化合物2和3首次从该种植物中分离得到.

  5. Technological, physico-chemical and sensory properties of raw and cooked meat batter incorporated with various levels of cold milled flaxseed powder.

    Science.gov (United States)

    Yogesh, K; Langoo, B A; Sharma, S K; Yadav, D N

    2015-03-01

    Flaxseed has been proven for its multidimensional health benefits and can be used for development of emulsion type functional meat products. In view of this the incorporation of cold milled flaxseed powder (FSP) in meat batter at level 1-5 % was investigated. The results revealed that incorporation significantly (P batter. The surface and internal color values were differed significantly (P < 0.05) among treatments at initial as well as during refrigerated storage period. Texture values especially hardness and chewiness values were found less (P < 0.05) in FSP treated samples and textural properties in FSP treated samples were not deteriorated during storage as compared to control samples. Thus incorporation of FSP had some beneficial effects on physico-chemical properties and textural properties which were also stable during storage period. However the redness values and sensory scores were observed less in FSP treated samples.

  6. Removal of Organic Pollutants and Decolorization of Bleaching Effluents from Pulp and Paper Mill by Adsorption using Chemically Treated Oil Palm Empty Fruit Bunch Fibers

    Directory of Open Access Journals (Sweden)

    Mohd Shaiful Sajab

    2014-06-01

    Full Text Available Treatment of bleaching effluents from pulp and paper mills using oil palm empty fruit bunch (EFB fibers as an adsorbent was conducted to remove color and organic pollutants. Empty fruit bunch fibers were chemically modified with polyethylenimine to enhance the adsorption capacity toward anionic species in the effluents. Effluents from the primary clarifier and aerated treatment pond were treated, and the performance of the adsorbent was investigated in terms of decolorization, total organic carbon, and oxygen demand level. Increasing adsorbent dosage and lower pH resulted in greater adsorption performance. The highest decolorization and reduction of total organic carbon of the effluents were 95.0% and 58.2%, respectively. The adsorption equilibrium can be achieved after 4 h of the adsorption process.

  7. Study on Chemical Constituents of Polygonatum odoratum(Mill.)Druce%玉竹化学成分研究

    Institute of Scientific and Technical Information of China (English)

    李海明; 白虹; 李巍; 王元书; 赵焕新

    2010-01-01

    目的 研究黄精属植物玉竹[Polygonatum odoratum(Mill.)Druce]的化学成分.方法 用硅胶,Sephadex LH-20,ODS柱层析和制备HPLC等分离纯化,通过波谱及质谱分析鉴定化合物结构.结果 分离得到5种化合物,分别鉴定为N-反式阿魏酸酪酰胺 (N-trans-feruloyl tyramine,Ⅰ),5-羟甲基糠醛(5-hydroxymethyl-2-furfural,Ⅱ),(-)-丁香树脂酚[(-)-syringaresinol,Ⅲ],3β,14α-二羟基-(25S)-螺甾烷醇-5-烯[3β,14α-dihydroxy-(25S)-spirost-5-ene,Ⅳ]和β-谷甾醇(β-sitosterol,Ⅴ).结论 化合物Ⅰ系首次从黄精属中分离得到,化合物Ⅱ、Ⅲ系首次从玉竹中分离得到.

  8. Molecular microbial and chemical investigation of the bioremediation of two-phase olive mill waste using laboratory-scale bioreactors.

    Science.gov (United States)

    Morillo, J A; Aguilera, M; Antízar-Ladislao, B; Fuentes, S; Ramos-Cormenzana, A; Russell, N J; Monteoliva-Sánchez, M

    2008-05-01

    Two-phase olive mill waste (TPOMW) is a semisolid effluent that is rich in contaminating polyphenols and is produced in large amounts by the industry of olive oil production. Laboratory-scale bioreactors were used to investigate the biodegradation of TPOMW by its indigenous microbiota. The effect of nutrient addition (inorganic N and P) and aeration of the bioreactors was studied. Microbial changes were investigated by PCR-temperature time gradient electrophoresis (TTGE) and following the dynamics of polar lipid fatty acids (PLFA). The greatest decrease in the polyphenolic and organic matter contents of bioreactors was concomitant with an increase in the PLFA fungal/bacterial ratio. Amplicon sequences of nuclear ribosomal internal transcribed spacer region (ITS) and 16S rDNA allowed identification of fungal and bacterial types, respectively, by comparative DNA sequence analyses. Predominant fungi identified included members of the genera Penicillium, Candida, Geotrichum, Pichia, Cladosporium, and Aschochyta. A total of 14 bacterial genera were detected, with a dominance of organisms that have previously been associated with plant material. Overall, this work highlights that indigenous microbiota within the bioreactors through stimulation of the fungal fraction, is able to degrade the polyphenolic content without the inoculation of specific microorganisms.

  9. Biochemical activity and chemical-structural properties of soil organic matter after 17 years of amendments with olive-mill pomace co-compost.

    Science.gov (United States)

    Aranda, V; Macci, C; Peruzzi, E; Masciandaro, G

    2015-01-01

    This study evaluates soil fertility, biochemical activity and the soil's ability to stabilize organic matter after application of composted olive-mill pomace. This organic amendment was applied in two different olive groves in southern Spain having different soil typologies (carbonated and silicic). Olive grove soils after 17 years of organic management with application of olive-mill pomace co-compost were of higher quality than those with conventional management where no co-compost had been applied. The main chemical parameters studied (total organic carbon, total nitrogen, available phosphorus, exchangeable bases, cation exchange capacity, total extractable carbon (TEC), and humic-to-fulvic acids ratio), significantly increased in soils treated with the organic amendment. In particular, the more resistant pool of organic matter (TEC) enhanced by about six and eight fold in carbonated and silicic soils, respectively. Moreover, the amended silicic soils showed the most significant increases in enzyme activities linked to C and P cycles (β-glucosidase twenty-five fold higher and phosphatase seven fold higher). Organic management in both soils induced higher organic matter mineralization, as shown by the higher pyrrole/phenol index (increasing 40% and 150% in carbonated and silicic soils, respectively), and lower furfural/pyrrole index (decreasing 27% and 71% in carbonated and silicic soils, respectively). As a result of mineralization, organic matter incorporated was also more stable as suggested by the trend of the aliphatic/aromatic index (decreasing 36% and 30% in carbonated and silicic soils, respectively). Therefore, management system and soil type are key factors in increasing long-term C stability or sequestration in soils. Thus application of olive-oil extraction by-products to soils could lead to important mid-to -long-term agro-environmental benefits, and be a valuable alternative use for one of the most widespread polluting wastes in the Mediterranean

  10. Iranian wheat flours from rural and industrial mills: Exploitation of the chemical and technology features, and selection of autochthonous sourdough starters for making breads.

    Science.gov (United States)

    Pontonio, Erica; Nionelli, Luana; Curiel, José Antonio; Sadeghi, Alireza; Di Cagno, Raffaella; Gobbetti, Marco; Rizzello, Carlo Giuseppe

    2015-05-01

    This study aimed at describing the main chemical and technology features of eight Iranian wheat flours collected from industrial and artisanal mills. Their suitability for bread making was investigated using autochthonous sourdough starters. Chemical analyses showed high concentration of fibers and ash, and technology aptitude for making breads. As shown through 2-DE analyses, gliadin and glutenin subunits were abundant and varied among the flours. According to the back slopping procedure, type I sourdoughs were prepared from Iranian flours, and lactic acid bacteria were typed and identified. Strains of Pediococcus pentosaceus, Weissella cibaria, Weissella confusa, and Leuconostoc citreum were the most abundant. Based on the kinetics of growth and acidification, quotient of fermentation and concentration of total free amino acids, lactic acid bacteria were selected and used as sourdough mixed starters for bread making. Compared to spontaneous fermentation, sourdoughs fermented with selected and mixed starters favored the increase of the concentrations of organic acids and total free amino acids, the most suitable quotient of fermentation, and the most intense phytase and antioxidant activities. Although the high concentration of fibers, selected and mixed starters improved the textural features of the breads. This study might had contribute to the exploitation of the potential of Iranian wheat flours and to extend the use of sourdough, showing positive technology, nutritional and, probably, economic repercussions.

  11. Chemical composition, antioxidant potential and phenolic profile of oil mill waste water from Tunisian olive varieties (Chetoui and Chemlali

    Directory of Open Access Journals (Sweden)

    Maissa Khemakhem Sellami

    2016-07-01

    Full Text Available Oil mill waste water (OMWW is of great interest due to the presence of valuable resources such as biophenols that can be recovered as food additives and pharmaceuticals. The aim of this study is to investigate the variation of physicochemical composition of OMWW from Chetoui and Chemlali varieties, to evaluate phenolic composition, antioxidant potential and phenolic profile of OMWW extracts under native and acidified conditions. Liquid-liquid extraction was performed for the extraction of polyphenols. Antioxidant activity was investigated by DPPH•, ABTS•+ and FRAP tests. Phenolic compounds content was determined by HPLC-DAD method. OMWW from Chetoui variety has been shown to contain an important amount of K, Ca and Na whereas Chemlali cultivar was rich in Mg. Phenolic extract from Chetoui fruit (COCt has been  shown to contain the highest amount of polyphenols (2.48 ± 0.21 g L-1 as well as an appreciable content of flavonoids (9.39 ± 0.32 g L-1. However, phenolic extract from Chemlali fruit (COCm has been shown to have the highest content of proanthocyanidins (0.39 ± 0.00 g L-1. Acidification treatment improved polyphenol recovery of extracts from both varieties. COCt was more active using DPPH (EC50 of 7.5 mg L-1 and FRAP tests. However, COCt and COCm exhibited the same activity using ABTS test. In general, acidification treatment decreased antioxidant activity of extracts. COCt has been shown to contain higher amount of hydroxytyrosol when compared to COCm (157.16 ± 0.820 and 23.440 ± 0.440 mg g-1 D.W. of extract, respectively as revealed by HPLC-DAD analysis. 

  12. Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals in Pulp Mill and Bleach Plant Streams

    Energy Technology Data Exchange (ETDEWEB)

    Frederick, W.J. Jr.; Rudie, A.W.; Schmidl, G.W.; Sinquefield, S.A.; Rorrer, G.L.; Laver, M.L.; Yantasee, W.; Ming, D.

    2000-08-01

    The overall goal of this project was to develop fundamental, experimentally based methods for predicting the solubility or organic and inorganic matter and their interactions in recycled effluent from kraft pulp mills and bleach plants. This included: characterizing the capacity of wood pulp and dissolved organic matter to bind metal ions, developing a thermodynamic database of properties needed to describe the solubility of inorganic matter in pulp mill streams, incorporation of the database into equilibrium calculation software for predicting the solubility of the metals of interest, and evaluating its capability to predict the distribution of the metals between pulp fibers, inorganic precipitates, and solution.

  13. Investigation of the influence of the chemical composition of HSLA steel grades on the microstructure homogeneity during hot rolling in continuous rolling mills using a fast layer model

    Science.gov (United States)

    Schmidtchen, M.; Rimnac, A.; Warczok, P.; Kozeschnik, E.; Bernhard, C.; Bragin, S.; Kawalla, R.; Linzer, B.

    2016-03-01

    The newly developed LaySiMS simulation tool provides new insight for inhomogeneous material flow and microstructure evolution in an endless strip production (ESP) plant. A deepened understanding of the influence of inhomogeneities in initial material state, temperature profile and material flow and their impact on the finished product can be reached e.g. by allowing for variable layer thickness distributions in the roll gap. Coupling temperature, deformation work and work hardening/recrystallization phenomena accounts for covering important effects in the roll gap. The underlying concept of the LaySiMS approach will be outlined and new insight gained regarding microstructural evolution, shear and inhomogeneous stress and strain states in the roll gap as well as local residual stresses will be presented. For the case of thin slab casting and direct rolling (TSDR) the interrelation of inhomogeneous initial state, micro structure evolution and dissolution state of micro alloying elements within the roughing section of an ESP line will be discussed. Special emphasis is put on the influence of the local chemical composition arising from direct charging on throughthickness homogeneity of the final product. It is concluded that, due to the specific combination of large reductions in the high reduction mills (HRM) and the highly inhomogeneous inverse temperature profile, the ESP-concept provides great opportunities for homogenizing the microstructure across the strip thickness.

  14. Effect of different extraction methods on fatty acids, volatile compounds, and physical and chemical properties of avocado (Persea americana Mill.) oil.

    Science.gov (United States)

    Moreno, Alicia Ortiz; Dorantes, Lidia; Galíndez, Juvencio; Guzmán, Rosa I

    2003-04-09

    Because Mexico is the number one producer of avocados in the world, this fruit has potential as a source for oil extraction. It is appropriate to further investigate the detailed changes that the oil undergoes when different extraction methods are applied. This research paper presents the study of the physical and chemical changes, the fatty acids profile, the trans fatty acid content, and the identification of volatile compounds of the oils from avocado pulp (Persea americana Mill.), obtained by four different extraction methods. The method with the greatest extraction yield was the combined microwave-hexane method. The amount of trans fatty acids produced in the microwave-squeezing treatment was <0.5 g/100 g. On the other hand, the amounts of trans fatty acids produced with the hexane and acetone treatments were 0.52 and 0.87 g/100 g, respectively. The method that caused the slightest modification to the oil quality was a novel combined extraction method of microwave-squeezing proposed by the authors.

  15. Occupational exposure to chemical and biological agents in the nonproduction departments of pulp, paper, and paper product mills: an international study.

    Science.gov (United States)

    Teschke, K; Ahrens, W; Andersen, A; Boffetta, P; Fincham, S; Finkelstein, M; Henneberger, P; Kauppinen, T; Kogevinas, M; Korhonen, K; Liss, G; Liukkonnen, T; Osvoll, P; Savela, A; Szadkowska-Stanczyk, I; Westberg, H; Widerkiewicz, K

    1999-01-01

    As part of an international epidemiological study of workers in the pulp and paper industry, previously unpublished exposure measurements were assembled in a database. This article describes 7293 measurements in nonproduction departments from 147 mills in 11 countries. The greatest variety of agents was measured in the maintenance, construction, and cleaning department, where high exposures to asbestos, chromium [VI] compounds, copper, mercury in urine, nitrogen dioxide, ozone, styrene, sulfur dioxide, trichloroethylene, and welding fumes were observed. Measurements in the storage, yard, loading, and shipping department indicated high exposures to asbestos, carbon monoxide, fungal spores, nitrogen oxides, sulfur dioxide, and total dust. The steam and power generation department had high exposures to methyl mercaptan, silica, and total dust. Measurements in process and effluent water treatment, laboratory and research, engineering, and office, administration, and cafeteria areas had few elevated exposures. Throughout the nonproduction departments, measurements of pulp-production chemicals such as chlorine and sulfur compounds tended to be low, with many below detection limits. There were some problems with the available data; in particular, detection limits were often not specified, and the data tended to be clustered in such a way that sources of exposure variability could not be distinguished. Despite these problems, the data provide new insight into the exposures of nonproduction pulp and paper industry personnel.

  16. Chemical Composition and Acaricidal Effects of Essential Oils of Foeniculum vulgare Mill. (Apiales: Apiaceae and Lavandula angustifolia Miller (Lamiales: Lamiaceae against Tetranychus urticae Koch (Acari: Tetranychidae

    Directory of Open Access Journals (Sweden)

    Asgar Ebadollahi

    2014-01-01

    Full Text Available Utilization of synthetic acaricides causes negative side-effects on nontarget organisms and environment and most of the mite species such as two spotted spider mite, Tetranychus urticae Koch, are becoming resistant to these chemicals. In the present study, essential oils of fennel, Foeniculum vulgare Mill., and lavender, Lavandula angustifolia Miller, were hydrodistilled using Clevenger apparatus and chemical composition of these oils was analyzed by GC-MS. Anethole (46.73%, limonene (13.65%, and α-fenchone (8.27% in the fennel essential oil and linalool (28.63%, 1,8-cineole (18.65%, and 1-borneol (15.94% in the lavender essential oil were found as main components. Contact and fumigant toxicity of essential oils was assessed against adult females of T. urticae after 24 h exposure time. The essential oils revealed strong toxicity in both contact and fumigant bioassays and the activity dependeds on essential oil concentrations. Lethal concentration 50% for the population of mite (LC50 was found as 0.557% (0.445–0.716 and 0.792% (0.598–1.091 in the contact toxicity and 1.876 μL/L air (1.786–1.982 and 1.971 μL/L air (1.628–2.478 in the fumigant toxicity for fennel and lavender oils, respectively. Results indicated that F. vulgare and L. angustifolia essential oils might be useful for managing of two spotted spider mite, T. urticae.

  17. Radioactive and chemical contamination of the water resources in the former uranium mining and milling sites of Mailuu Suu (Kyrgyzstan).

    Science.gov (United States)

    Corcho Alvarado, J A; Balsiger, B; Röllin, S; Jakob, A; Burger, M

    2014-12-01

    An assessment of the radioactive and chemical contamination of the water resources at the former uranium mines and processing sites of Mailuu-Suu, in Kyrgyzstan, was carried out. A large number of water samples were collected from the drinking water distribution system (DWDS), rivers, shallow aquifers and drainage water from the mine tailings. Radionuclides and trace metal contents in water from the DWDS were low in general, but were extremely high for Fe, Al and Mn. These elements were associated with the particle fractions in the water and strongly correlated with high turbidity levels. Overall, these results suggest that water from the DWDS does not represent a serious radiological hazard to the Mailuu Suu population. However, due to the high turbidities and contents of some elements, this water is not good quality drinking water. Water from artesian and dug wells were characterized by elevated levels of U (up to 10 μg/L) and some trace elements (e.g. As, Se, Cr, V and F) and anions (e.g. Cl(-), NO3(-), SO4(2-)). In two artesian wells, the WHO guideline value of 10 μg/L for As in water was exceeded. As the artesian wells are used as a source of drinking water by a large number of households, special care should be taken in order to stay within the WHO recommended guidelines. Drainage water from the mine tailings was as expected highly contaminated with many chemicals (e.g. As) and radioactive contaminants (e.g. U). The concentrations of U were more than 200 times the WHO guideline value of 30 μg/L for U in drinking water. A large variation in (234)U/(238)U isotopic ratios in water was observed, with values near equilibrium at the mine tailings and far from equilibrium outside this area (reaching ratios of 2.3 in the artesian well). This result highlights the potential use of this ratio as an indicator of the origin of U contamination in Mailuu Suu.

  18. Chemical composition and antidermatophytic properties of volatile fractions of hexanic extract from leaves of Cupressus lusitanica Mill. from Cameroon.

    Science.gov (United States)

    Kuiate, Jules-Roger; Bessière, Jean Marie; Zollo, Paul Henri Amvam; Kuate, Serge Philibert

    2006-01-16

    The chemical composition of five column fractions of hexanic leaf extract of Cupressus lusitanica were analysed by gas chromatography and gas chromatography-mass spectrometry and then tested for their antidermatophytic activities using the agar dilution method. The first fraction (F(1)) has only hydrocabon monoterpenes with alpha-pinene (80.0%) as major component. The main constituents of the second fraction (F(2)) were epi-bicyclosesquiphellandrene (35.3%), epi-zonarene (10.3%), 1S, cis-calamenene (13.1%) and beta-himachalene (10.4%). The third fraction (F(3)) was rich in hydrocarbon sesquiterpenes (45.4%) and a relatively high amount of diterpenes (29.8%) with epi-bicyclosesquiphellandrene (14.3%), pimaric acid (7.5%), kaurenoic acid (6.9%) and 8-beta-hydroxysandaracopimarane (3.5%) as main components. The last two fractions contain high molecular weight aliphatic hydrocarbons, their main constituents been eicosane (41.1%) and tricosane (37.3%) and heptacosane (22.1%). The agar dilution method was used to evaluate the antifungal properties of the crude extract and its fractions. These fractions showed several degrees of antidermatophytic activities against Microsporum audouinii, Microsporum Langeronii, Microsporum canis, Trichophyton rubrum and Trichophyton tonsurans. Fractions F(1) and F(3) exhibited the highest antidermatophytic activities with repective MICs of 250 and 125 mug/ml while the fractions F(4) and F(5) did not prevent the growth of the tested fungi up to dose 2,500 mug/ml.

  19. Co-Digestion of Palm Oil Mill Effluent and Refined Glycerin Wash Water for Chemical Oxygen Demand Removal and Methane Production

    Directory of Open Access Journals (Sweden)

    A. Sulaiman

    2009-01-01

    Full Text Available Problem statement: Refined Glycerin Wash Water (RGWW from the oleochemical industry contains high Chemical Oxygen Demand (COD and requires proper treatment before disposal. Unfortunately the wash water also contains high concentration of sodium chloride (NaCl that could cause inhibition to the normal biological treatment process. However, there is feasibility of co-digesting the RGWW and Palm Oil Mill Effluent (POME for its treatment and methane recovery. Approach: A large 500 m3 semi-commercial closed digester tank was used to study the effect of co-digesting POME and RGWW under mesophilic condition at different RGWW percentage. The digester performance in terms of COD removal efficiency and methane production rate and stability based on total Volatile Fatty Acids (VFA accumulation, Mixed Liquor Volatile Suspended Solid (MLVSS and pH were evaluated. Results: At 1.0% of RGWW co-digested, both COD removal efficiency and methane production rate showed satisfactory results with higher than 90% and 505 m3 day-1, respectively. However, once the percentage was increased to a maximum of 5.25%, COD removal efficiency remains high but the methane production rate reduced significantly down to 307 m3 day-1. At this stage, the digester was already unstable with high total VFA recorded of 913 mg L-1 and low cells concentration of 8.58 g L-1. This was probably due to the effect of plasmolysis on the methanogens at high concentration of NaCl in the digester of nearly 4000 mg L-1. Conclusion: Co-digesting of RGWW with high NaCl content and POME is satisfactory for COD removal but not for increasing the methane production.

  20. Palladium nanoparticles obtained by mechanical milling

    Energy Technology Data Exchange (ETDEWEB)

    Sampedro, B.; Hernando, A. [Instituto de Magnetismo Aplicado (RENFE-UCM-CSIC), P.O. Box 155, 28230 Las Rozas, Madrid (Spain); Dpto. Fisica de Materiales, UCM, 28040 Madrid (Spain); Rojas, T.C.; Fernandez, A. [Instituto de Ciencia de Materiales de Sevilla, Centro mixto CSIC-UNIV, 41092 Sevilla (Spain)

    2006-05-15

    Opposed to the existing chemical methods, we have used a physical one in order to obtain palladium nanoparticles. In this work we present the HRTEM observation of Pd nanoparticles obtained by mechanical milling. These particles are around 6 nm in size. The Pd milled samples have exhaustively been structurally characterized. We have also studied its magnetic properties as a function of the milling time and magnetic measurements are according to those previously carried out by us in palladium nanoparticles obtained by chemical methods. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  1. 进口氧化皮化学特性及X射线荧光光谱分析%Chemical Features and X-ray Fluorescence Spectrum Analysis of Imported Mill Scale

    Institute of Scientific and Technical Information of China (English)

    张庆建; 丁仕兵; 冯丽丽; 孙博

    2012-01-01

    采用玻璃片法熔融进口氧化皮样品,并应用X射线荧光光谱法测定其中全铁和硅、铝、磷、钙、镁、钛、砷、铅等15种杂质元素的含量.根据氧化皮成分含量范围,利用多个铁矿石标准样品、部分标准样品添加基准物质Fe2O3配制系列校准物质,建立工作曲线.结果表明,该方法能准确、快速地对氧化皮进行分析,测量值与经典方法或标准值比较没有显著性差异.%Mill scale sample is prepared by fused bead. And the total iron and other impurity elementssuch as silicon, phosphorus, calcium, magnesium, titanium, arsenic and lead in mill scale sample aremeasured by X-ray fluorescence spectrum. Calibration curve is set up by iron ore certified referencematerials,and Fe2O3 are added into some of them according to the elements contents of mill scale. Theresults are favorable in terms of accuracy and precision as compared to chemical method or certifiedvalues.

  2. 木立芦荟挥发油成分GC-MS分析%Study on Chemical Components of Essential Oil in Aloe arborescens Mill.by GC-MS

    Institute of Scientific and Technical Information of China (English)

    柏金辰; 杨晓虹; 高丽娜; 刘安; 王文娜; 孙薇

    2012-01-01

    用气相色谱-质谱法对木立芦荟的挥发油进行化学成分分析.采用水蒸气蒸馏法从木立芦荟中提取挥发油,用归一化法测定其百分含量,并用气相色谱-质谱法对化学成分进行鉴定.共鉴定了19种成分,占挥发油总量的63.66%以上.本方法稳定可靠、重现性好,适用于中药挥发油的化学成分分析.%The chemical components of the essential oil from A loe arborescens Mill. Were analyzed by GC-MS. Method. The essential oil was extracted from Aloe arborescens Mill. By steam distillation method, and the amount of the components from the essential oil were determined by normalization method. The components were identified by GC-MS. 19 components which were 63.66% of the total essential oil, were separated and identified. The method is reliable, stable and good repeatability. So this method can be applied to the analysis of chemical components in the essential oil from the traditional chinese medicine.

  3. Coal Moisture Estimation in Power Plant Mills

    DEFF Research Database (Denmark)

    Andersen, Palle; Bendtsen, Jan Dimon; Pedersen, Tom S.;

    2009-01-01

    Knowledge of moisture content in raw coal feed to a power plant coal mill is of importance for efficient operation of the mill. The moisture is commonly measured approximately once a day using offline chemical analysis methods; however, it would be advantageous for the dynamic operation...... of the plant if an on-line estimate were available. In this paper we such propose an on-line estimator (an extended Kalman filter) that uses only existing measurements. The scheme is tested on actual coal mill data collected during a one-month operating period, and it is found that the daily measured moisture...

  4. Biomass torrefaction mill

    Science.gov (United States)

    Sprouse, Kenneth M.

    2016-05-17

    A biomass torrefaction system includes a mill which receives a raw biomass feedstock and operates at temperatures above 400 F (204 C) to generate a dusty flue gas which contains a milled biomass product.

  5. 75 FR 71463 - Woodland Mills Corporation Mill Spring, NC; Notice of Revised Determination on Reconsideration

    Science.gov (United States)

    2010-11-23

    ... Employment and Training Administration Woodland Mills Corporation Mill Spring, NC; Notice of Revised... of Woodland Mills Corporation, Mill Spring, North Carolina, to apply for Trade Adjustment Assistance... yarn produced by Woodland Mills Corporation, Mill Spring, North Carolina Woodland Mills...

  6. Effects of Non Process Elements in the chemical recovery system of a kraft pulp mill from the incineration in the recovery boiler of biological sludge; Effekter av PFG vid indunstning och foerbraenning av bioslam i ett massabruks sodapanna

    Energy Technology Data Exchange (ETDEWEB)

    Dahlbom, Johan

    2003-01-01

    The purpose of this project was to investigate the effects of incineration of biological sludge in the recovery boiler of a Swedish Kraft pulp mill, StoraEnso Pulp AB Skutskaers Bruk, which has practiced incineration of sludge in the recovery boiler during the last two years. The following aspects of the technique were investigated: Experience from operation of incineration of biological sludge in the recovery boiler; The content of Non-Process Elements (NPE) in process flows and evaluate the risks of incrustations in the system; The build-up of NPE in the chemicals recovery system and the estimated increase in make-up lime demand; and Technical risks for mills with different process equipment. This study comprises the following NPE: aluminium, silicon, phosphorus, magnesium, calcium, chloride, iron, manganese, potassium, copper, and nitrogen. The operational experience from the system for hydrolysis of the biological sludge and evaporation/incineration in the recovery boiler is excellent. The handling of the sludge takes place in a closed system that demands little supervision and maintenance. Overall, the mill has not seen any negative effects that can be explained by increased intake of NPEs to the chemical recovery system. Aluminium can lead to troublesome incrustations of sodium-aluminium-silicates on the heat surfaces in the evaporation plant. An effective elimination of aluminium by the green liquor dreg is obtained with the double salt hydrotalcite if the quotient Mg/Al is kept higher than 4-5 in the black liquor. The need for make-up lime has increased due to the build-up of phosphorus in the lime. Depending on the level of make-up lime the need will increase 2-5 kg/ t{sub 90} at a price of 2-5 kr/t{sub 90}. If a higher level of phosphorus is accepted instead of increasing lime make-up the running costs will be somewhat higher, 0,5-1 kr/t{sub 90} due to increased ballast. NO{sub x} in the flue gases from the recovery boiler has not increased since the

  7. Revitalizing America's Mills: A Report on Brownfields Mill Projects

    Science.gov (United States)

    This report focuses on mills -- former textile, wood, paper, iron, and steel mills. The report describes the challenges and opportunities of mill sites with case studies highlighting some of the most creative solutions from across the country.

  8. Treatment of Olive Oil Mill Wastewater With Fungi

    OpenAIRE

    YEŞİLADA, Özer

    1999-01-01

    : Olive oil mills produce a liquid waste called olive black water in the olive oil production process. In this study, olive oil mill wastewater (OOMW) was analysed and then treated aerobically with fungi. Consequently, high chemical oxygen demand (COD), phenol and color reduction were obtained. High biomass yields and laccase enzyme activities were also determined.

  9. Milling of organic solids in a jet mill. Part 1 : Determination of the selection function and related mechanical material properties

    NARCIS (Netherlands)

    de Vegt, O; Vromans, H; Faassen, F; Maarschalk, KV

    2005-01-01

    The particle size distribution of pharmaceutically active materials and other fine chemicals determines the performance of the final product to a large extent. Often milling of these particles is necessary. It is not possible to determine the milling conditions solely on the basis of the particle si

  10. 小茴香根皮化学成分研究%On the chemical constituents from the root barks of Foeniculum vulgare Mill

    Institute of Scientific and Technical Information of China (English)

    林健博; 古丽娜·沙比尔

    2014-01-01

    目的 分析新疆小茴香(Foeniculum vulgare Mill)根皮中的化学成分.方法 采用硅胶柱层析法反复分离纯化技术,通过质谱分析、核磁共振等现代波谱技术对新疆小茴香根皮中的化学成分进行结构鉴定.结果 从新疆小茴香中分离得到6种化合物:7-羟基-6-甲氧基香豆素(Scopoletin,Ⅰ).5-羟甲基糠(5-Hydroxymethylfurfural,Ⅱ)、焦谷氨酸乙酯(5-oxo-2-pyrrolidinecarboxylic acid;(±)-form,ET ester,Ⅲ)、胡萝卜苷(Daucosterol,Ⅳ)、β-谷甾醇(β-Sitosterol,V)、蔗糖(Sucrose,Ⅵ).结论 化合物Ⅰ~Ⅲ为首次从茴香属植物中分离得到,为进一步研究新疆小茴香的化学成分提供理论依据.

  11. Short-term impact of olive mill wastewater (OMWW) applications on the physico-chemical and microbiological soil properties of an olive grove in Argentina.

    Science.gov (United States)

    Pierantozzi, Pierluigi; Torres, Mariela; Verdenelli, Romina; Basanta, María; Maestri, Damián M; Meriles, José M

    2013-01-01

    The purpose of this work was to investigate the effects of spreading olive oil mill wastewater (OMWW) on soil biochemical parameters and olive production in an organically managed olive orchard. The experiment was carried out with three different doses of OMWW (80, 160 and 500 m(3) ha(-1)) and a control (untreated soil). Three samplings were done at 10, 30 and 90 days after the administration of the byproduct. OMWW application differentially modified the biochemical properties of the soil analyzed. Organic matter, organic carbon, total nitrogen and extractable phosphorus soil contents increased proportionally with each increasing dose. The values of these parameters decreased gradually with time. Total microbial activity was altered and the OMWW 500 m(3) ha(-1) treatment proved to be the most active when compared with the other applied doses. OMWW agricultural application also modified the structure of soil microbial communities, particularly affecting Gram positive and negative bacteria, while fungal biomass did not show consistent changes. Although there was a salinity increase in the treated soil, especially at the highest dose, the productive parameters analyzed (fruit and oil tree(-1)) were not affected. In light of the obtained results, we consider that low dose of OMWW could be considered an alternative farming practice for semiarid regions.

  12. Role of H2O2 in the fluctuating patterns of COD (chemical oxygen demand) during the treatment of palm oil mill effluent (POME) using pilot scale triple frequency ultrasound cavitation reactor.

    Science.gov (United States)

    Manickam, Sivakumar; Abidin, Norhaida binti Zainal; Parthasarathy, Shridharan; Alzorqi, Ibrahim; Ng, Ern Huay; Tiong, Timm Joyce; Gomes, Rachel L; Ali, Asgar

    2014-07-01

    Palm oil mill effluent (POME) is a highly contaminating wastewater due to its high chemical oxygen demand (COD) and biochemical oxygen demand (BOD). Conventional treatment methods require longer residence time (10-15 days) and higher operating cost. Owing to this, finding a suitable and efficient method for the treatment of POME is crucial. In this investigation, ultrasound cavitation technology has been used as an alternative technique to treat POME. Cavitation is the phenomenon of formation, growth and collapse of bubbles in a liquid. The end process of collapse leads to intense conditions of temperature and pressure and shock waves which assist various physical and chemical transformations. Two different ultrasound systems i.e. ultrasonic bath (37 kHz) and a hexagonal triple frequency ultrasonic reactor (28, 40 and 70 kHz) of 15 L have been used. The results showed a fluctuating COD pattern (in between 45,000 and 60,000 mg/L) while using ultrasound bath alone, whereas a non-fluctuating COD pattern with a final COD of 27,000 mg/L was achieved when hydrogen peroxide was introduced. Similarly for the triple frequency ultrasound reactor, coupling all the three frequencies resulted into a final COD of 41,300 mg/L compared to any other individual or combination of two frequencies. With the possibility of larger and continuous ultrasonic cavitational reactors, it is believed that this could be a promising and a fruitful green process engineering technique for the treatment of POME.

  13. EDTA Titrimetric Determination of Fluorion in Chemical Milling Solution and Acid Pickling Solution for Titanium Alloys%EDTA滴定法测定钛合金化铣液和酸洗液中氟的含量

    Institute of Scientific and Technical Information of China (English)

    乔永莲; 沙春鹏; 张敏; 严鹏飞

    2016-01-01

    为测定钛合金化铣液和酸洗液中氟的含量,将待测液酸度调节至pH 2.0,加入过量镧(Ⅲ)标准溶液并煮沸2 min,使溶液中F-与La3+生成难溶的LaF3沉淀,加入乙酸-乙酸钠缓冲溶液10 mL。用EDTA标准溶液滴定溶液中过量的镧(Ⅲ),从而间接算出待测液中氟离子的含量。对已知含F-的质量浓度为45.00 g·L-1的氢氟酸溶液连续按所提出的方法测定10次,测得回收率几近100%,测定值的相对标准偏差为0.080%。对化铣液和酸洗液实样分别按本法及硝酸钍滴定法进行测定,所得氟离子的测定值相符。%For the determination of content of F- in samples of chemical milling and acid pickling solution used for titanium alloys,an aliquot of the sample solution was adjusted to pH 2.0 and buffered with 10 mL of HOAc-NaOAc buffer solution;an excess of standard La3+solution was added to the sample solution and the mixture was heated to boiling for 2 min to precipitate completely the F- as LaF3 .Excess of La3+ in the solution was then titrated with standard EDTA solution,and the content of F-was determined indirectly by calculation on the base of the amount of titrant consumed.To test for the accuracy and precision of the proposed method,10 successive determinations were made with a known HF solution of 45 .00 g·L-1 F-by the proposed method,giving values of recovery very close to 100% and of RSD′s of 0.080%.Substantial samples of chemical milling solution and acid pickling solution were analyzed by the present method and checked by the Th(NO3 )4 titrimetric method,consistent results were obtained.

  14. Pitt Mill Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Oder, R.R.; Borzone, L.A.

    1990-05-01

    Results of a technical and economic evaluation of application of the Pitt Mill to fine coal grinding are presented. The Pitt Mill is a vertically oriented, batch operated, intermediate energy density (0. 025 kW/lb media), stirred ball mill. The mill grinds coal from coarse sizes (typically 3/16 inch or 4 mesh topsize) to the 10 micron to 20 micron mean particle diameter size range in a single step using a shallow grinding bed containing inexpensive, readily available, course grinding media. Size reduction is efficient because of rapid product circulation through the grinding bed caused by action of a novel circulation screw mounted on the agitator shaft. When a dispersant is employed, the grinding can be carried out to 50% to 60% solids concentration. Use of coarse grinding media offers the possibility of enhanced mineral liberation because size reduction is achieved more by impact shattering than by attrition. The batch method offers the possibility of very close control over product particle size distribution without overproduction of fines. A two- phase program was carried out. In the first phase, Grinding Studies, tests were run to determine a suitable configuration of the Pitt Mill. Machine design parameters which were studied included screw configuration, media type, agitator RPM, time, media size, and slurry chamber aspect ratio. During the last part of this phase of the program, tests were carried out to compare the results of grinding Pocahontas seam, Pittsburgh {number sign}8, and East Kentucky Mingo County coals by the Pitt Mill and by a two-stage grinding process employing a Netzsch John mill to feed a high energy density (0.05 kW/Lb media) disc mill. 22 refs., 25 tabs.

  15. Análise da madeira do Pinus oocarpa parte II: caracterização estrutural da lignina de madeira moída Chemical analysis of the Pinus oocarpa wood. Part II: characterization of the milled wood lignin

    Directory of Open Access Journals (Sweden)

    Sérgio Antônio Lemos de Morais

    2005-06-01

    Full Text Available Este estudo caracterizou a Lignina de Madeira Moída (LMM proveniente de Pinus oocarpa cultivado na região do Cerrado brasileiro. A LMM foi isolada e analisada por meio das espectrometrias no infravermelho com transformada de Fourier (IVTF, de ressonância magnética nuclear do próton e carbono-13 e por intermédio de métodos químicos de análise por via úmida. A LMM apresentou uma fórmula mínima igual a C9H9,2O2,6(OCH 30,8 e massas molares médias em massa (Mw e numérica (Mn de 3.969 e 1.133 Da, respectivamente. A LMM dessa madeira se enquadra dentro das ligninas típicas de coníferas.This work presents the characterization of the milled wood lignin (MWL of the Pinus oocarpa cultivated in the Brazilian cerrado. FTIR, carbon-13 and proton NMR spectroscopies as well as wet chemical methods were used. The established C9 unit formula for MWL was C9H9,2O2,6(OCH 30,8 and its relative molecular weights (Mw and (Mn were 3969 and 1133 Da, respectively. Pinus oocarpa MWL was typical of softwood lignins.

  16. Top-down, in-plane GaAs nanowire MOSFETs on an Al2O3 buffer with a trigate oxide from focused ion-beam milling and chemical oxidation

    Science.gov (United States)

    Lee, S. C.; Neumann, A.; Jiang, Y.-B.; Artyushkova, K.; Brueck, S. R. J.

    2016-09-01

    The top-down fabrication of an in-plane nanowire (NW) GaAs metal-oxide-semiconductor field-effect transistor (MOSFET) with a trigate oxide implemented by liquid-phase chemical-enhanced oxidation (LPCEO) is reported. A 2 μm long channel having an effective cross section ˜70 × 220 nm2 is directly fabricated into an epitaxial n +-GaAs layer. This in-plane NW structure is achieved by focused ion beam (FIB) milling and hydrolyzation oxidation resulting in electronic isolation from the substrate through a semiconductor-on-insulator structure with an n +-GaAs/Al2O3 layer stack. The channel is epitaxially connected to the μm-scale source and drain within a single layer for a planar MOSFET to avoid any issues of ohmic contact and LPCEO to the NW. To fabricate a MOSFET, the top and the two sidewalls of the in-plane NW are oxidized by LPCEO to relieve the surface damage from FIB as well as to transform these surfaces to a ˜15 nm thick gate oxide. This trigate device has threshold voltage ˜0.14 V and peak transconductance ˜35 μS μm-1 with a subthreshold swing ˜150 mV/decade and on/off ratio of drain current ˜103, comparable to the performance of bottom-up NW devices.

  17. Methods of chemical oxidation to close the water cycle at paper mills. Process development and modelling; Hapetustekniikoiden kaeyttoe metsaeteollisuuden vesikiertojen sulkemisessa: prosessin kehitys ja mallinnus

    Energy Technology Data Exchange (ETDEWEB)

    Laari, A.; Kallas, J. [Lappeenranta Univ. of Technology (Finland); Korhonen, S. [Mikkeli Polytechnic, School of Engineering, Mikkeli (Finland); Tuhkanen, T. [Tampere Univ. of Technology (Finland)

    1999-07-01

    Chemical oxidation with ozone was studied as means of the removal of lipophyllic wood extractives (LWEs) from thermo- mechanical pulp (TMP) circulation water. Ozonation was also tested as the method of microbiological control for the circulation water of paper machines. Ozone was found to selectively oxidise LWEs in TMP-waters. The dosage of ozone sufficient to remove 50 % of the LWEs was found to be from 75 to 300 mg O{sub 3}/l. Ozone dose from 500 to 800 mg O{sub 3}/l was required for 90 % removal of LWEs. The ozone dose from 10 to 40 mg O{sub 3}/l was necessary to inactivate micro-organisms by two orders of magnitude (99%). The model of ozonation process simulation was developed, which consists of the model of reaction kinetics and the reactor model. The model of reaction kinetics assumes two simultaneous competitive reactions with ozone: (a) oxidation of LWEs and (b) oxidation of other organic substances defined as chemical oxygen demand (COD). The selectivity of oxidation was defined as the ratio of the rate coefficients of the mentioned reactions and was calculated from experimental data. The selectivity was found to be different in different TMP circulation water samples and varied with LWEs composition. The selectivity of oxidation also decreased as the ozonation proceeded. The value of the selectivity ratio ranged between 7 and 10 was used in simulation of ozonation reactor. (orig.)

  18. 维药小茴香根皮乙酸乙酯部位化学成分研究%study on chemical constituents of ethyl acetate portion of roots of Foeniculum vulgare Mill

    Institute of Scientific and Technical Information of China (English)

    宋凤凤; 美丽万·阿不都热依木

    2014-01-01

    To study on chemical constituents of the ethyl acetate extract part of roots of FOeNiculum vulGare Mill. Ethyl acetate extract part were isolated and pured by silica gel column chromatography,Sephadex LH-20 and recrystallization,their chemical structures were elucidated by spectral data analysis( 1 H NMR and 13 C NMR). Result showed that five compounds were isolated from the ethyl acetate extract part,they were identified as dillapiol(1),butyl isobutyl phthalate(2),3R,8S 9Z-falcarindiol(3),β-sitosterol(4), linoleic acid( 5 ). This research provides basic understanding about the medicinal values of F. vulGare roots.%采用硅胶柱色谱、Sephadex LH-20和重结晶等分离手段对维药小茴香根皮中乙酸乙酯提取部分进行分离纯化,通过1 H NMR、13 C NMR进行结构鉴定。结果表明,从乙酸乙酯提取部分分离5个化合物,分别鉴定为莳萝脑(1)、邻苯二甲酸丁基异丁基二酯(2)、镰叶芹二醇(3)、β-谷甾醇(4)、甘油酸(5)。该研究为了解维药茴香根皮的药用价值提供了研究基础。

  19. Chemical components of volatile oil in roots of Foeniculum vulgare mill from different habitats by GC-MS%不同产地茴香根皮挥发油成分的GC-MS分析

    Institute of Scientific and Technical Information of China (English)

    宋凤凤; 美丽万·阿不都热依木; 周静

    2014-01-01

    To analyze and compare the chemical components of the volatile oil in roots of Foeniculum vul-gare mill from ten different habitats. The volatile oil was extracted by steam distillation. The components of volatile oil were separated and analyzed by GC-MS. The relative content of each constituent was calculated by normalization. Result showed that twenty-six components in the volatile oil of roots of Foeniculum vul-gare mill from ten different habitats were identified. 13,7,11,10,14,11,14,11,10,10 components were identified from Xiaoerbage,Lawati,Tacheng,Bageqi,Shufu,Lasikui,Manglai,Yili,Moyu,Buzhake of Xin-jiang. Dill Apiol and 1,3-benzodioxole,4,7-dimethoxy-5-(2-propen-1-yl)-and 1,3-benzodioxole,4-me-thoxy-6-(2-propenyl)-are its common and main ingredients,which account for 90. 81% ~96. 18% and 0. 54% ~2. 76% and 0. 10% ~3. 33% of the total oils.%采用水蒸气蒸馏法提取10个不同产地小茴香根挥发油,运用气相色谱-质谱联用技术( GC-MS)进行化学成分分析,面积归一化法测定各成分的相对百分含量。结果表明,从10个不同产地的茴香根挥发油中共鉴定出26个成分,其中肖尔巴格乡、阿瓦提乡、塔城、巴格其镇、疏附县、拉丝奎镇、芒来乡、伊犁、墨玉县、布扎克乡分别鉴定出了13、7、11、10、14、11、14、11、10、10个成分,其中莳萝芹菜脑、洋芹脑和肉豆蔻醚是它们的共有成分和主要成分,莳萝芹菜脑占挥发油总量的90.81%~96.18%,洋芹脑占挥发油总量的0.54%~2.76%,肉豆蔻醚占挥发油总量的0.10%~3.33%。

  20. Pretreated cheese whey wastewater management by agricultural reuse: chemical characterization and response of tomato plants Lycopersicon esculentum Mill. under salinity conditions.

    Science.gov (United States)

    Prazeres, Ana R; Carvalho, Fátima; Rivas, Javier; Patanita, Manuel; Dôres, Jóse

    2013-10-01

    The agricultural reuse of pretreated industrial wastewater resulting from cheese manufacture is shown as a suitable option for its disposal and management. This alternative presents attractive advantages from the economic and pollution control viewpoints. Pretreated cheese whey wastewater (CWW) has high contents of biodegradable organic matter, salinity and nutrients, which are essential development factors for plants with moderate to elevated salinity tolerance. Five different pretreated CWW treatments (1.75 to 10.02 dS m(-1)) have been applied in the tomato plant growth. Fresh water was used as a control run (average salinity level=1.44 dS m(-1)). Chemical characterization and indicator ratios of the leaves, stems and roots were monitored. The sodium and potassium leaf concentrations increased linearly with the salinity level in both cultivars, Roma and Rio Grande. Similar results were found in the stem sodium content. However, the toxic sodium accumulations in the cv. Roma exceeded the values obtained in the cv. Rio Grande. In this last situation, K and Ca uptake, absorption, transport and accumulation capacities were presented as tolerance mechanisms for the osmotic potential regulation of the tissues and for the ion neutralization. Consequently, Na/Ca and Na/K ratios presented lower values in the cv. Rio Grande. Na/Ca ratio increased linearly with the salinity level in leaves and stems, regardless of the cultivar. Regarding the Na/K ratio, the values demonstrated competition phenomena between the ions for the cv. Rio Grande. Despite the high chloride content of the CWW, no significant differences were observed for this nutrient in the leaves and stems. Thus, no nitrogen deficiency was demonstrated by the interaction NO3(-)/Cl(-). Nitrogen also contributes to maintain the water potential difference between the tissues and the soil. Na, P, Cl and N radicular concentrations were maximized for high salinity levels (≥2.22 dS m(-1)) of the pretreated CWW.

  1. CHEMICALS

    CERN Multimedia

    Medical Service

    2002-01-01

    It is reminded that all persons who use chemicals must inform CERN's Chemistry Service (TIS-GS-GC) and the CERN Medical Service (TIS-ME). Information concerning their toxicity or other hazards as well as the necessary individual and collective protection measures will be provided by these two services. Users must be in possession of a material safety data sheet (MSDS) for each chemical used. These can be obtained by one of several means : the manufacturer of the chemical (legally obliged to supply an MSDS for each chemical delivered) ; CERN's Chemistry Service of the General Safety Group of TIS ; for chemicals and gases available in the CERN Stores the MSDS has been made available via EDH either in pdf format or else via a link to the supplier's web site. Training courses in chemical safety are available for registration via HR-TD. CERN Medical Service : TIS-ME :73186 or service.medical@cern.ch Chemistry Service : TIS-GS-GC : 78546

  2. Efeito dos tratamentos físicos e químicos no resíduo de lixadeira do algodão Effects of physical and chemical treatments in cotton textile mill waste

    Directory of Open Access Journals (Sweden)

    Juliana dos Santos

    2004-08-01

    Full Text Available O experimento foi conduzido no Departamento de Zootecnia (UFLA e no Laboratório de Alimentos (UNIFENAS, com o objetivo de avaliar o valor nutritivo do resíduo de lixadeira do algodão pela composição bromatológica (PB, FDN, FDA e pela degradabilidade da MS e da FDN. Os tratamentos foram: T1 - in natura (IN; T2 - pressão e vapor (127ºC/1,5 kgf/cm²/35min; PV; T3 - 4% hidróxido de sódio (por 24 horas; NaOH; T4 - 3% uréia (por 28 dias; U; T5 - 4% NaOH + 3% uréia (NaOH/U; T6 - PV + 4% NaOH (PV/NaOH; T7 - PV + 3% uréia (PV/U. Pelos resultados referentes à composição química, conclui-se que os tratamentos associados foram mais eficientes em aumentar o valor nutritivo do resíduo, sendo o tratamento NaOH/U o que apresentou os melhores resultados para PB, FDN e FDA. Os maiores valores para a degradabilidade efetiva da MS foram verificados para o resíduo tratado com PV, U, NaOH/U, PV/NaOH, PV/U, que também apresentaram maior fração solúvel e menor fração insolúvel potencialmente degradável (b. Os tratamentos U, PV/NaOH e PV/U apresentaram as maiores de degradabilidade efetiva da FDN e maior fração solúvel. Os tratamentos associados aumentaram a degradabilidade e o valor nutritivo do resíduo de lixadeira do algodão.The experiment was carried out at the Department of Animal Science of the Universidade Federal de Lavras and at the Food Laboratory at the Universidade José do Rosário Vellano (UNIFENAS, with the objective to evaluate the nutritive value of cotton textile mill waste using chemical composition (DM, CP, NDF, ADF and ruminal degradability of the dry matter and NDF. The treatments were: T1 - in natura residue (IN; T2 - residue submitted to the pressure and steam treated (127ºC/1,5 kgf/cm²/35"; PS; T3 - 4% sodium hydroxide treated residue (four 24 hours; NaOH; T4 - 3% urea treated residue (for 28 days; U; T5 - 4% NaOH +3% urea treated residue (NaOH/U; T6 - pressure and steam + 4% NaOH treated residue (PS/NaOH; T7

  3. CVD carbon powders modified by ball milling

    Directory of Open Access Journals (Sweden)

    Kazmierczak Tomasz

    2015-09-01

    Full Text Available Carbon powders produced using a plasma assisted chemical vapor deposition (CVD methods are an interesting subject of research. One of the most interesting methods of synthesizing these powders is using radio frequency plasma. This method, originally used in deposition of carbon films containing different sp2/sp3 ratios, also makes possible to produce carbon structures in the form of powder. Results of research related to the mechanical modification of these powders have been presented. The powders were modified using a planetary ball mill with varying parameters, such as milling speed, time, ball/powder mass ratio and additional liquids. Changes in morphology and particle sizes were measured using scanning electron microscopy and dynamic light scattering. Phase composition was analyzed using Raman spectroscopy. The influence of individual parameters on the modification outcome was estimated using statistical method. The research proved that the size of obtained powders is mostly influenced by the milling speed and the amount of balls. Powders tend to form conglomerates sized up to hundreds of micrometers. Additionally, it is possible to obtain nanopowders with the size around 100 nm. Furthermore, application of additional liquid, i.e. water in the process reduces the graphitization of the powder, which takes place during dry milling.

  4. NOISE IN TEXTILE MILLS

    Directory of Open Access Journals (Sweden)

    P. Meshgi

    1977-06-01

    Full Text Available The mean noise levels were measured in the different sections of six representative mills in the Isfahan area, and audiometric measurements were made in 282 male workers employed in these mills. The mean noise levels were on average 95 dBA in the weaving sections and 88 d BA in the spinning sections. The audiometric findings showed a significant loss of gearing in the textile workers as compared to controls who were employed in a quiet environment. The study indicated that noisiness depended; on the whole, on the age and number of machines deployed per unit area of shop-floor. On the basis of this study certain recommendations were made to improve the working conditions.

  5. Shear Roll Mill Reactivation

    Science.gov (United States)

    2012-09-13

    accommodate a trial run of inert single base pellet feed for use in a twin screw extruder. 15. SUBJECT TERMS INIT248, Advanced Propellant Technology...Bldg. 4909-5 – Shear Roll Mill Pilot Plant at the Radford Army Ammunition Plant (RFAAP) in order to produce pellet feed for a twin screw extruder used...propellant to simulate feed for a twin screw extruder. Preventive maintenance procedures were in progress in final preparation for running with

  6. Swedish Pulp Mill Biorefineries. A vision of future possibilities

    Energy Technology Data Exchange (ETDEWEB)

    Berntsson, Thore (Chamers Univ. of Technology, Goeteborg (Sweden)); Axegaard, Peter; Backlund, Birgit; Samuelsson, Aasa; Berglin, Niklas; Lindgren, Karin (STFI-Packforsk, Stockholm (Sweden))

    2008-07-01

    Today, modern science could make it possible to develop techniques for refining almost the whole wood-matter, pulp mill side streams and bark compounds into platform chemicals, electricity, high quality fuels and structured feed-stock for chemicals and materials. The major challenge is to convert the state of basic scientific knowledge into industrial practise. Our definition of an integrated biorefinery is: 'Full utilization of the incoming biomass and other raw materials for simultaneous and economically optimized production of fibres, chemicals and energy'. Examples of products from a pulp mill biorefinery are: Chemicals and Materials (Phenols, adhesives, carbon fibres, activated carbon, binders, barriers, adhesives, antioxidants, surfactants, chelants, solvents, adhesives surfactants, descaling agents, specialty polymers, pharmaceuticals, nutraceuticals, cosmetics etc., Biofuels (pellets, lignin fuel, methanol, DME, ethanol etc), Electricity (BLGCC, condensing power etc.). The new or increased amounts of traditional products can be made from internal and/or external biomass. Three different levels can be identified: A high degree of energy saving in future mills, especially chemical pulp mills, will lead to large amounts of excess internal biomass which can be transferred to products mentioned above, Components in e.g. the black liquor, forest residues and bark can be upgraded to more valuable ones and the energy balance of the mill is kept through fuel import, wholly or partly depending on the level of mill energy efficiency. This imported fuel can be biomass or other types. External (imported) biomass (in some cases together with excess internal biomass) can be upgraded using synergy effects of docking this upgrading to a pulp mill. Electricity has been included as one of the possible biorefinery products. The electricity production in a mill can be increased in several ways which cannot be directly considered as biorefineries, e.g. recovery boiler

  7. 7 CFR 868.310 - Grades and grade requirements for the classes Long Grain Milled Rice, Medium Grain Milled Rice...

    Science.gov (United States)

    2010-01-01

    ... Grain Milled Rice, Medium Grain Milled Rice, Short Grain Milled Rice, and Mixed Milled Rice. (See also Â... Milled Rice Principles Governing Application of Standards § 868.310 Grades and grade requirements for the classes Long Grain Milled Rice, Medium Grain Milled Rice, Short Grain Milled Rice, and Mixed Milled...

  8. Characterization and Feasibility Assessment of Recycled Paper Mill Sludges for Land Application in Relation to the Environment

    OpenAIRE

    Rosazlin Abdullah; Che Fauziah Ishak; Wan Rasidah Kadir; Rosenani Abu Bakar

    2015-01-01

    The disposal of industrial paper mill sludge waste is a big issue and has a great importance all over the world. A study was conducted to determine the chemical properties of recycled paper mill sludge (RPMS) and assess its possibilities for land application. RPMS samples were collected from six different paper mills in Malaysia and analyzed for physical and chemical properties, heavy metals, polycyclic aromatic hydrocarbons, 13C-NMR spectra and for the presence of dioxins/furans. The RPMS w...

  9. Effect of milling time on the synthesis of magnetite nanoparticles by wet milling

    Energy Technology Data Exchange (ETDEWEB)

    Can, Musa Mutlu [SNTG Laboratory, Physics Engineering Department, Hacettepe University, Beytepe, 06800, Ankara (Turkey); Ozcan, Sadan, E-mail: sadan@hacettepe.edu.tr [SNTG Laboratory, Physics Engineering Department, Hacettepe University, Beytepe, 06800, Ankara (Turkey); Ceylan, Abdullah; Firat, Tezer [SNTG Laboratory, Physics Engineering Department, Hacettepe University, Beytepe, 06800, Ankara (Turkey)

    2010-08-15

    In this study, nanosize magnetite (Fe{sub 3}O{sub 4}) particles have been prepared directly from metallic iron (Fe) powder within distilled water (H{sub 2}O) by using a planetary ball mill, and the effect of milling time has been investigated. According to Rietveld refinement result obtained from X-ray diffraction (XRD) analyses, the amount of Fe decreases from 98.2% to 0.0%, and it is transformed into Fe{sub 3}O{sub 4}, from 1.8% to 100.0%, with the increasing milling time from 1 to 48 h. Due to similar crystal structure of the magnetite and maghemite ({gamma}-Fe{sub 2}O{sub 3}), FTIR and Raman spectroscopies as well as a chemical analysis method was used to verify the magnetite structure. FTIR spectra have clearly revealed absorption peaks around 628, 581 and 443 cm{sup -1}, which are in good agreement with the characteristic absorption peaks of Fe{sub 3}O{sub 4}. In addition Raman analysis verified the formation of magnetite phase with a clear main band peak at 671 cm{sup -1}. Chemical analyses have shown that the total amount of Fe in the milled sample for 48 h is 73.04%, which contains 24.10% Fe{sup 2+} and 49.34% Fe{sup 3+}. These results are consistent with the theoretically estimated values of the magnetite. It has been observed that the saturation magnetization decreased from 146.02 to 63.68 emu/g with increasing milling time due to the formation of the ferrimagnetic magnetite phase.

  10. Japan steel mill perspective

    Energy Technology Data Exchange (ETDEWEB)

    Murase, K. [Kobe Steel Ltd., Tokyo (Japan)

    2004-07-01

    The international and Japan's steel industry, the coking coal market, and Japan's expectations from Canada's coal industry are discussed. Japan's steel mills are operating at full capacity. Crude steel production for the first half of 2004 was 55.8 million tons. The steel mills are profitable, but costs are high, and there are difficulties with procuring raw materials. Japan is trying to enhance the quality of coke, in order to achieve higher productivity in the production of pig iron. Economic growth is rising disproportionately in the BRICs (Brazil, Russia, India, and China), with a large increase in coking coal demand from China. On the supply side, there are several projects underway in Australia and Canada to increase production. These include new developments by Elk Valley Coal Corporation, Grande Cache Coal, Western Canadian Coal, and Northern Energy and Mining in Canada. The Elga Mine in the far eastern part of Russia is under development. But the market is expected to remain tight for some time. Japan envisions Canadian coal producers will provide a stable coal supply, expansion of production and infrastructure capabilities, and stabilization of price. 16 slides/overheads are included.

  11. Wear of micro end mills

    DEFF Research Database (Denmark)

    Bissacco, Giuliano; Hansen, Hans Nørgaard; De Chiffre, Leonardo

    2005-01-01

    This paper addresses the important issue of wear on micro end mills considering relevant metrological tools for its characterization and quantification. Investigation of wear on micro end mills is particularly difficult and no data are available in the literature. Small worn volumes cause large d...

  12. Catalytic Effect of Nb2O5 in MgH2-Nb2O5 Ball-Milled Composites

    Directory of Open Access Journals (Sweden)

    Somei Ohnuki

    2012-09-01

    Full Text Available We report a study on the desorption properties, crystallography and chemical state of MgH2 and 1 mol% Nb2O5 ball-milled composites. Desorption temperatures of the composites decreased with increase of ball-milling time. Size of MgH2 crystallites decreased during ball-milling. Reduction of Nb2O5 after ball-milling was confirmed by tracing the chemical state of Nb and was further supported by TEM observation. The reduced phases may act as more effective catalysts improving the desorption properties.

  13. 影响DD6铸件化学铣切速率因素的研究%Discussing on the Factors Effecting on the Rate of DD6 Casting Chemical Milling

    Institute of Scientific and Technical Information of China (English)

    曲彦平; 杨爱宁; 石娇; 曲世超

    2011-01-01

    To determine the primary and secondary effect factors on milling rate of DD6 casting, using the orthogonal experimental method, by studying the amount of hydrofluoric acid, hydrochloric acid, nitric acid and chromic anhydride in influence on the milling rate at room temperature, the corresponding suitable process control parameters were put forward. The experimental results show that the primary and secondary effect factors on milling rate as follows:HNO3 > HF> HCl>CrO3, when nitric acid concentration is 110 mL/L, hydrofluoric acid concentration is 200 mL/L,hydrochloric acid concentration is 180 mL/L, inhibitor concentration is 20 g/L, the sample surface shows good uniformity and the process is stable and controllable.%为了确定影响DD6铸件化铣速率的主次因素,采用正交试验方法,在室温条件下,通过研究酸基锐切液中氢氟酸、盐酸、硝酸、铬酐的用量对化铣速率的影响,得出了相对适宜的工艺参数.结果表明:影响化锐速率的主次因素依次为硝酸用量>氢氟酸用量>盐酸用量>铬酐用量,且硝酸110 ML/L氢氟酸200 mL/L,盐酸180 ml./I.,铬酐20 g/L较为适宜,在该工艺条件下,试件表面铣切均匀性好,铣切过程稳定可控.

  14. INVESTIGATION ON HARDENED STEEL MILLING WITH MICRO-END MILL

    Institute of Scientific and Technical Information of China (English)

    HUYing-ning; WANGCheng-yong; WUXue-qi; QINZhe; ZENGBao-ping

    2004-01-01

    Tool wear and breakage of the micro-milling tool is an important problem for high speed machining of hardened steel die and mould. Dry milling of S136 hardened steel is carried out using TiA1N coated carbide micro-end mill (Ф2 mm). The effect of cutting speed, feed per tooth and radial depth of cut on cutting force is analyzed. Cutting parameters adapting to dry machining and strategy optimized for higher rate of material removal with lower cutting force are attained. Results of SEM observation show that the main failure patterns of micro-end mill are breakage of tool tip, wear and drop-off of surface coating, micro-chipping, and breakage of flank.

  15. Understanding milling induced changes: Some results

    Indian Academy of Sciences (India)

    K Chattopadhyay; N Ravishankar; T A Abinandanan; Viji Varghese

    2003-10-01

    The effect of mechanical milling on materials has been studied using simple model systems. The results show that milling leads to enhancement in both thermodynamic driving force and transport kinetics. A study of some characteristic physical properties of the milled samples in comparison to the bulk shows how milling affects the properties.

  16. Measurement of the Residual Stress Induced by Milling in Titanium Alloys Based on Chemical Milling and the Changes of Bending Deflection%基于化铣剥层和挠度变化的钛合金铣削加工表面内应力的测量∗

    Institute of Scientific and Technical Information of China (English)

    王毅

    2015-01-01

    对Ti6 Al4 V材料零件利用侧铣进行加工,其被加工表面会产生一内应力(即残余应力)层。为了测量加工引起的随深度变化的残余应力,通过对零件的应力层进行腐蚀剥层,并测量此过程中零件挠度的变化。根据弯矩与挠度的关系以及应力与弯矩的关系,最终计算得到铣削加工引起的随深度变化的残余应力。将计算得到的应力值带入有限元模型中进行计算,将计算得到的挠度的变化与实验测得的挠度的变化进行对比,发现两条曲线的重合度很高,由此说明此测量方法精度很高,可以运用与实践中加工残余应力的测量。%Flank milling was used to machine Ti6Al4V parts, and there would be high residual stress in-duced by milling in the superficial layer of the parts. The stress layers were removed gradually and the chan-ges of parts’ bending deflection were also measured. Based on the relationship between the bending deflec-tion and the bending moment, the bending moment and the residual stresses, the stresses values were calcu-lated out at last. The calculated stress values were loaded to the FEM model, a compasion of the bending deflection calculated by FEM and that measured in the experiments was made, it can be seen that they corre-spond to each other very well, so it can be concluded that the accuracy of this method is high enough, and it can be used to measure the residual stresses induced by milling in practice.

  17. Chalk Line Mill, Anniston, AL

    Science.gov (United States)

    The Chalk Line Mill property was the site of a textile mill which operated from 1887 until 1994. Demolition activities in 2004 removed most of the structures on-site, but also left large, unsightly piles of debris scattered across this 14-acre property. The City applied for and received a $200,000 Brownfields cleanup grant in 2007 to address contamination on the property and the Appalachian Regional Commission provided an additional $150,000 in funding.

  18. Brookside Mills, Knox County, TN

    Science.gov (United States)

    Brookside Mills, located in Knox County, TN, was a textile mill that was founded in 1885 and at its peak employed over 1,000 people. Its former uses included fabric weaving, dying, and sewing operations. It was at some point a department store, and during a portion of its history, coal was used as an energy source. Weaving operations continued in some form at the Brookside factory until 1969. In 1996 the buildings were demolished.

  19. Solid-state reactions to synthesize nanostructured lead selenide semiconductor powders by high-energy milling

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: uu_gg_oo@yahoo.com.mx [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco (Mexico) and Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada - IPN, Legaria 694, Col. Irrigacion, Del. Miguel Hidalgo (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM, Circuito de la Investigacion Cientifica s/n, C.U. Del. Coyoacan (Mexico); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco (Mexico)

    2011-10-15

    Highlights: {yields} PbSe synthesized from PbO instead of Pb powder do not require an inert atmosphere. {yields} During high-energy milling oxygen has to be chemically reduced from the lead oxide. {yields} Solid-state and solid-gas chemical reactions promote both solid and gaseous products. -- Abstract: Both solid-solid and gas-solid reactions have been traced during high-energy milling of Se and PbO powders under vial (P, T) conditions in order to synthesize the PbSe phase. Chemical and thermodynamic arguments are postulated to discern the high-energy milling mechanism to transform PbO-Se micropowders onto PbSe-nanocrystals. A set of reactions were evaluated at around room temperature. Therefore an experimental campaign was designed to test the nature of reactions in the PbO-Se system during high-energy milling.

  20. Suppressing Heavy Metal Leaching through Ball Milling of Fly Ash

    Directory of Open Access Journals (Sweden)

    Zhiliang Chen

    2016-07-01

    Full Text Available Ball milling is investigated as a method of reducing the leaching concentration (often termed stablilization of heavy metals in municipal solid waste incineration (MSWI fly ash. Three heavy metals (Cu, Cr, Pb loose much of their solubility in leachate by treating fly ash in a planetary ball mill, in which collisions between balls and fly ash drive various physical processes, as well as chemical reactions. The efficiency of stabilization is evaluated by analysing heavy metals in the leachable fraction from treated fly ash. Ball milling reduces the leaching concentration of Cu, Cr, and Pb, and water washing effectively promotes stabilization efficiency by removing soluble salts. Size distribution and morphology of particles were analysed by laser particle diameter analysis and scanning electron microscopy. X-ray diffraction analysis reveals significant reduction of the crystallinity of fly ash by milling. Fly ash particles can be activated through this ball milling, leading to a significant decrease in particle size, a rise in its BET-surface, and turning basic crystals therein into amorphous structures. The dissolution rate of acid buffering materials present in activated particles is enhanced, resulting in a rising pH value of the leachate, reducing the leaching out of some heavy metals.

  1. Analyzing the performance of diamond-coated micro end mills.

    Energy Technology Data Exchange (ETDEWEB)

    Torres, C. D.; Heaney, P. J.; Sumant, A. V.; Hamilton, M. A.; Carpick, R. W.; Pfefferkorn, F. E.; Univ. of Wisconsin at Madison; Univ. of Pennsylvania

    2009-06-01

    A method is presented to improve the tool life and cutting performance of 300 {micro}m diameter tungsten carbide (WC) micro end mills by applying thin (<300 nm) fine-grained diamond (FGD) and nanocrystalline diamond (NCD) coatings using the hot-filament chemical vapor deposition (HF-CVD) process. The performance of the diamond-coated tools has been evaluated by comparing their performance in dry slot milling of 6061-T6 aluminum against uncoated WC micro end mills. Tool wear, coating integrity, and chip morphology were characterized using SEM and white light interferometry. The initial test results show a dramatic improvement in the tool integrity (i.e., corners not breaking off), a lower wear rate, no observable adhesion of aluminum to the diamond-coated tool, and a significant reduction in the cutting forces (>50%). Reduction of the cutting forces is attributed to the low friction and adhesion of the diamond coating. However, approximately 80% of the tools coated with the larger FGD coatings failed during testing due to delamination. Additional machining benefits were attained for the NCD films, which was obtained by using a higher nucleation density seeding process for diamond growth. This process allowed for thinner, smaller grained diamond coatings to be deposited on the micro end mills, and enabled continued operation of the tool even after the integrity of the diamond coating had been compromised. As opposed to the FGD-coated end mills, only 40% of the NCD-tools experienced delamination issues.

  2. GC-MS Analysis and Antioxidant Activity of Chemical Constituents of Volatile Oil from Rose Damascena Mill%突厥玫瑰挥发油化学成分的 GC-MS分析及其抗氧化活性研究

    Institute of Scientific and Technical Information of China (English)

    弓宝; 陈德力; 赵祥升; 杨新全

    2016-01-01

    The volatile oil from Rose damascena Mill.was extracted by steam distillation.The chemical con-stituents of volatile oil from Rose damascena Mill.were analyzed by a GC-MS.The antioxidant activity of vola-tile oil from Rose damascena Mill.was determined by a DPPH+FRAP method.The relative content of volatile oil from Rose damascena Mill.was determined by a peak area normalization.Total 42 compounds were identi-fied,accounting for 79.57% of the total volatile oil content.The main chemical constituents of volatile oil were citronellol(26.1 1%),α-geraniol(5.89%),β-nerol(4.36%),α-geranial(3.56%),terpinen-4-ol(SG)(3.48%), phenethyl alcohol(2.64%),α-guaiene(2.33%),ocimene(2.32%),and neryl acetate(2.17%).The DPPH free radical scavenging rate of volatile oil was 58.9%,and the FRAP value was 402.1 μmol·L-1 .The results provide reliable experimental data and a theoretical basis for further development and utilization of Rose damascena Mill..%采用水蒸气蒸馏法提取突厥玫瑰挥发油,并通过气质联用仪(GC-MS)对其化学成分进行分析,采用 DPPH+FRAP 法对其抗氧化活性进行测定。采用面积归一化法对突厥玫瑰挥发油中的主要成分进行了定量分析,共鉴定出42种化合物,占挥发油总成分的79.57%,主要成分为香茅醇(26.11%)、α-香叶醇(5.89%)、β-橙花醇(4.36%)、α-香叶醛(3.56%)、松油-4-醇(3.48%)、苯乙醇(2.64%)、α-愈创烯(2.33%)、罗勒烯(2.32%)、乙酸橙花酯(2.17%);突厥玫瑰挥发油对 DPPH 自由基的清除率最高为58.9%,FRAP 值为402.1μmol·L-1。为突厥玫瑰的进一步产业化开发提供了可靠的实验数据和理论依据。

  3. YANG-MILLS FIELD CAPACITOR

    Directory of Open Access Journals (Sweden)

    Trunev A. P.

    2015-10-01

    Full Text Available The article presents a project of the capacitor in the Yang-Mills theory. Model capacitor represents the equipotential surfaces separated by a space. To describe the mechanism of condensation chromodynamics field used numerical models developed based on an average of the Yang-Mills theory. In the present study, we used eight-scalar component model that in the linear case is divided into two groups containing three or five fields respectively. In contrast to classical electrodynamics, a static model of the Yang-Mills is not divided into independent equations because of the nonlinearity of the model itself. However, in the case of a linear theory separation is possible. It is shown that in this particular case, the Yang-Mills theory is reduced to Poisson theory, which describes the electrostatic and magnetostatic phenomena. In the present work it is shown that in a certain region of the parameters of the capacitor of the Yang-Mills theory on the functional properties of the charge accumulation and retention of the field is similar to the capacitor of the electrostatic field or a magnet in magnetostatics. This means that in nature there are two types of charges, which are sources of macroscopic Yang-Mills field, which are similar to the properties of electric and magnetic charges in the Poisson theory. It is shown that in Yang-Mills only one type of charge may be associated with the distribution density of the substance, while another type of charge depends on the charge distribution of the first type. This allows us to provide an explanation for the lack of symmetry between electric and magnetic charges

  4. Noise exposure in oil mills

    Directory of Open Access Journals (Sweden)

    Prasanna Kumar G

    2008-01-01

    Full Text Available Context: Noise of machines in various agro-based industries was found to be the major occupational hazard for the workers of industries. The predominant noise sources need to be identified and the causes of high noise need to be studied to undertake the appropriate measures to reduce the noise level in one of the major agro-based industries, oil mills. Aims: To identify the predominant noise sources in the workrooms of oil mills. To study the causes of noise in oil mills. To measure the extent of noise exposure of oil mill workers. To examine the response of workers towards noise, so that appropriate measures can be undertaken to minimize the noise exposure. Settings and Design: A noise survey was conducted in the three renowned oil mills of north-eastern region of India. Materials and Methods: Information like output capacity, size of power source, maintenance condition of the machines and workroom configurations of the oil mills was collected by personal observations and enquiry with the owner of the mill. Using a Sound Level Meter (SLM (Model-824, Larson and Davis, USA, equivalent SPL was measured at operator′s ear level in the working zone of the workers near each machine of the mills. In order to study the variation of SPL in the workrooms of the oil mill throughout its operation, equivalent SPL was measured at two appropriate locations of working zone of the workers in each mill. For conducting the noise survey, the guidelines of Canadian Centre for Occupational Health and Safety (CCOHS were followed. Grid points were marked on the floor of the workroom of the oil mill at a spacing of 1 m x 1 m. SPL at grid points were measured at about 1.5 m above the floor. The direction of the SLM was towards the nearby noisy source. To increase accuracy, two replications were taken at each grid point. All the data were recorded for 30 sec. At the end of the experiment, data were downloaded to a personal computer. With the help of utility software of

  5. Structural and magnetic stability of high energy ball milled Co{sub 2}MnSi

    Energy Technology Data Exchange (ETDEWEB)

    Vinesh, A., E-mail: attatappa85@gmail.com [Department of Physics, Amity School of Applied Sciences, Amity University Haryana, Gurgaon 122413 (India); Sudheesh, V.D. [Department of Physics, MohanlalSukhadia University Udaipur, Rajasthan 313001 (India); Sebastian, Varkey [Department of Physics, Nimalagiri College, Nirmalagiri, Kannur, Kerala 670701 (India); Lakshmi, N.; Venugopalan, K. [Department of Physics, MohanlalSukhadia University Udaipur, Rajasthan 313001 (India)

    2015-07-15

    Structural and magnetic properties of ball milled Co{sub 2}MnSi have been studied and compared with that of ordered bulk sample. The milled sample (with average size determined using the Williamson–Hall method) shows that the chemical ordering for this sample is very stable and is little effected by high energy ball milling. However, the reduction in the saturation magnetic moment of the milled sample shows that there is spin disordering induced on ball milling – attributable to the formation of a magnetically dead layer at the surface of the nano-sized samples. The ordered sample (unmilled) has a saturation moment value of 4.4 µ{sub B} per formula unit at room temperature and is in agreement with the prediction of Slater Pauling curve. On milling it reduces to ~3 µ{sub B} per formula unit at room temperature with an accompanying increase in the coercivity, retentivity and squareness factor. - Highlights: • We studied the magnetic and structural properties of bulk and ball milled Co{sub 2}MnSi. • Structural disordering is minimal even at 36 nm. • Constant value of T{sub C} shows strong ferromagnetic interaction in smaller particles. • Formation of magnetically dead surface layer results reduction in magnetic moment. • Variation of magnetic parameters is systematic with variation in milling time/size.

  6. Controlling the number of walls in multi walled carbon nanotubes/alumina hybrid compound via ball milling of precipitate catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Nosbi, Norlin [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia (USM), 14300 Nibong Tebal, Seberang Perai Selatan, Pulau Pinang (Malaysia); Akil, Hazizan Md, E-mail: hazizan@usm.my [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia (USM), 14300 Nibong Tebal, Seberang Perai Selatan, Pulau Pinang (Malaysia); Cluster for Polymer Composite (CPC), Science and Engineering Research Centre, Engineering Campus, Universiti Sains Malaysia (USM), 14300 Nibong Tebal, Seberang Perai Selatan, Pulau Pinang (Malaysia)

    2015-06-15

    Graphical abstract: - Highlights: • We report that, to manipulate carbon nanotubes geometry and number of walls are by controlling the precipitate catalyst size. • Number of walls and geometry effects depend on the milling time of the precipitate catalyst. • Increasing milling of time will decrease the carbon nanotubes number of walls. • Increasing milling of time will increase the carbon nanotubes thermal conductivity. - Abstract: This paper reports the influence of milling time on the structure and properties of the precipitate catalyst of multi walled carbon nanotubes (MWCNT)/alumina hybrid compound, produced through the chemical vapour deposition (CVD) process. For this purpose, light green precipitate consisted of aluminium, nickel(II) nitrate hexahydrate and sodium hydroxide mixture was placed in a planetary mill equipped with alumina vials using alumina balls at 300 rpm rotation speed for various milling time (5–15 h) prior to calcinations and CVD process. The compound was characterized using various techniques. Based on high-resolution transmission electron microscopy analysis, increasing the milling time up to 15 h decreased the diameter of MWCNT from 32.3 to 13.1 nm. It was noticed that the milling time had a significant effect on MWCNT wall thickness, whereby increasing the milling time from 0 to 15 h reduced the number of walls from 29 to 12. It was also interesting to note that the carbon content increased from 23.29 wt.% to 36.37 wt.% with increasing milling time.

  7. Evaluation of in vitro dissolution rates of thorium in uranium mill tailings.

    Science.gov (United States)

    Reif, R H

    1994-11-01

    Dissolution rates of thorium from the uranium mill tailings piles at two Department of Energy Uranium Mill Tailings Remedial Action Project (UMTRAP) sites have been evaluated. The thorium dissolution rates were evaluated in vitro using simulated lung fluid. The former uranium mills at the UMTRAP sites employed different chemical processes (acid leach and alkaline pressure leach) to extract the uranium from the ore, and the thorium dissolution rates at these sites were found to be markedly different. A site specific annual limit on intake (ALI) value for 230Th was calculated for the UMTRAP site that was associated with a multiple component dissolution curve.

  8. YANG-MILLS FIELD AMPLIFIER

    Directory of Open Access Journals (Sweden)

    Trunev A. P.

    2015-09-01

    Full Text Available The article presents a project of the Yang-Mills amplifier. Amplifier model is a multilayer spherical shell with increasing density towards the center. In the center of the amplifier is the core of high-density material. It is shown that in such a system, the amplitude of the Yang-Mills waves rises from the periphery to the center of several orders of magnitude. The role of the Yang-Mills field in the processes occurring in the nuclei of galaxies, stars and planets is discussed. The data modeling to strengthen the Yang-Mills field in the bowels of the planet, with an atomic explosion, and in some special devices such as the voltaic pile. To describe the mechanism of amplification chromodynamics field used as accurate results in Yang-Mills theory and numerical models developed based on an average and the exact equations as well. Among the exact solutions of the special role played by the centralsymmetric metric describing the contribution of the Yang-Mills field in the speed of recession of galaxies. Among the approximate numerical models can be noted the eight-scalar model we have developed for the simulation of non-linear color oscillations and chaos in the Yang-Mills theory. Earlier models were investigated spatio-temporal oscillations of the YangMills theory in the case of three and eight colors. The results of numerical simulation show that the nonlinear interaction does not lead to a spatial mixing of colors as it might be in the case of turbulent diffusion. Depending on the system parameters there is a suppression of the amplitude of the oscillations the first three by five colors or vice versa. The kinetic energy fluctuations or shared equally between the color components, or dominated by the kinetic energy of repressed groups of colors. In the present study, we found that amplification chromodynamic field leads to a sharp increase in the amplitude of the suppressed color, which can lead to an increase in entropy, excitation of nuclear

  9. Treatment and valorization of olive mill wastewaters

    Directory of Open Access Journals (Sweden)

    Nabila Slimani Alaoui

    2016-04-01

    Full Text Available This study aims to evaluate the effectiveness of the physicochemical process with lime and ferric chloride in removing the pollution generated by the olive mill wastewaters (OMW .The characterization of the samples has shown that they are acidic, with a black color and a strong organic load due to the presence of phenolic compounds. The combination of the lime and the ferric chloride allows the removal of 87% of the total suspended solid (TSs, 58% of chemical oxygen demand (COD and 75% of Phenolic compounds. After purification the treated OMW were valorised as wash water or used for irrigation of green spaces and the generated sludge were dried and used to combustion. 

  10. Simulation and Optimization of a Generic Kraft Pulp Mill

    OpenAIRE

    Barahona Vazquez, Javier

    2010-01-01

    The Canadian pulp and paper industry is going through an economic crisis mainly due to a decrease of world demand and aggressive competition from emerging nations. In this context, the forest biorefinery which can be defined as the “full integration of the incoming biomass and other raw materials, including energy, for simultaneous production of fibres for paper products, chemicals and energy”, is one of the solutions for pulp and paper mills to diversify their core business and regain compet...

  11. Machine Shop. Module 6: Milling. Instructor's Guide.

    Science.gov (United States)

    Walden, Charles H.

    This document consists of materials for a 12-unit course on the following topics: (1) introduction to milling; (2) structure and accessories; (3) safety and maintenance; (4) cutting-tool variables; (5) basic set-up activities; (6) squaring a workpiece; (7) hole-making operations; (8) form milling; (9) machining keyways; (10) milling angular…

  12. 77 FR 14837 - Bioassay at Uranium Mills

    Science.gov (United States)

    2012-03-13

    ... COMMISSION Bioassay at Uranium Mills AGENCY: Nuclear Regulatory Commission. ACTION: Draft regulatory guide... for public comment draft regulatory guide (DG), DG-8051, ``Bioassay at Uranium Mills.'' This guide describes a bioassay program acceptable to the NRC staff for uranium mills and applicable portions...

  13. Study of Commercial Wheat Flour Milling Process:Relation of Flour Yield,Ash and Protein Contents of Flour Mill and Characteristics of Wheat Blend%Study of Commercial Wheat Flour Milling Process: Relation of Flour Yield, Ash and Protein Contents of Flour Mill and Characteristics of Wheat Blend

    Institute of Scientific and Technical Information of China (English)

    Y S Kim; C W Deyoe; O K Chung; E Haque

    2006-01-01

    The profit margin in the flour milling industry is quite narrow, so high-quality raw materials and efficiency of milling operations are crucial for every company. Many flour mills, especially those which import wheat from other countries and have limited storage space for the different varieties or classes of wheat, can not afford to buy low quality wheat. Consequently, a mathematical model which can test the impact and interactions of raw materials, in technical point of view, would be a useful decision-making tool for the milling industry. A flour miller tests wheat for physical and chemical characteristics, cleanness and soundness. The miller also performs experimental milling, if available, to have some idea how the given wheat will behave during commercial milling. Based on these test results, the miller can only guess the commercial milling results such as flour yields and flour ash and protein contents. Thus, the objective of this study was to develop empirical equations to estimate commercial milling results, using the physical, chemical and experimental milling data of the given wheat blend and also, additionally, flour ash and protein specifications of the end-user. This was done by using the actual commercial milling procedures and their wheat physical, chemical, experimental milling data, and other vital data. Data were collected from a commercial mill located in East Asia that had four production lines and used wheat blend combinations from five different wheat classes, i.e. Hard Red Winter (HRW),Dark Northern Spring (DNS), Soft White (SW), Australian Soft (AS), and Australian Standard White (ASW) wheat to produce over 40 different products. The wheat physical and chemical characteristics included test weight, thousand kernel weight, ash and protein contents. The experimental milling data were straight-grade and patent flour yields, along with patent flour ash and protein contents from a Buhler experimental mill. The commercial milling results included

  14. Anaerobic digestion of pulp and paper mill wastewater and sludge.

    Science.gov (United States)

    Meyer, Torsten; Edwards, Elizabeth A

    2014-11-15

    Pulp and paper mills generate large amounts of waste organic matter that may be converted to renewable energy in form of methane. The anaerobic treatment of mill wastewater is widely accepted however, usually only applied to few selected streams. Chemical oxygen demand (COD) removal rates in full-scale reactors range between 30 and 90%, and methane yields are 0.30-0.40 m(3) kg(-1) COD removed. Highest COD removal rates are achieved with condensate streams from chemical pulping (75-90%) and paper mill effluents (60-80%). Numerous laboratory and pilot-scale studies have shown that, contrary to common perception, most other mill effluents are also to some extent anaerobically treatable. Even for difficult-to-digest streams such as bleaching effluents COD removal rates range between 15 and 90%, depending on the extent of dilution prior to anaerobic treatment, and the applied experimental setting. Co-digestion of different streams containing diverse substrate can level out and diminish toxicity, and may lead to a more robust microbial community. Furthermore, the microbial population has the ability to become acclimated and adapted to adverse conditions. Stress situations such as toxic shock loads or temporary organic overloading may be tolerated by an adapted community, whereas they could lead to process disturbance with an un-adapted community. Therefore, anaerobic treatment of wastewater containing elevated levels of inhibitors or toxicants should be initiated by an acclimation/adaptation period that can last between a few weeks and several months. In order to gain more insight into the underlying processes of microbial acclimation/adaptation and co-digestion, future research should focus on the relationship between wastewater composition, reactor operation and microbial community dynamics. The potential for engineering and managing the microbial resource is still largely untapped. Unlike in wastewater treatment, anaerobic digestion of mill biosludge (waste activated

  15. Integration of micro milling highspeed spindle on a microEDM-milling machine set-up

    DEFF Research Database (Denmark)

    De Grave, Arnaud; Hansen, Hans Nørgaard; Andolfatto, Loic

    2009-01-01

    In order to cope with repositioning errors and to combine the fast removal rate of micro milling with the precision and small feature size achievable with micro EDM milling, a hybrid micro-milling and micro-EDM milling centre was built and tested. The aim was to build an affordable set-up, easy...... by micro milling. Examples of test parts are shown and used as an experimental validation....

  16. J. S. Mill on Education

    Science.gov (United States)

    Ryan, Alan

    2011-01-01

    Mill may be said either to have written rather little on education or to have written a very great deal. He himself distinguished between a "narrow" and a "wider" sense of education, the former limited to what happens in formal educational settings, the latter embracing all the influences that make us who and what we are. He wrote rather little on…

  17. Structural causes of defects in a cast iron mill roll

    Directory of Open Access Journals (Sweden)

    J. Krawczyk

    2008-07-01

    Full Text Available This paper describes an analysis of a defective microstructure of a mill roll. For this purpose, a piece of a broken roll was collected. That roll was made of mottled cast iron. Its microstructure consisted of modular graphite, transformed ledeburite and a matrix composed of bainite and martensite. Metallographic investigations were performed nearby the fracture in the roll. Observations were conducted on polished sections, first not etched, and then etched, which allowed us to trace carefully the propagation of the fracture. There was found a strict correlation between the microstructure of the roll and the progress occurring in the crack. It was ascertained that the basic reason for the damage to the roll was banded precipitations of ledeburitic cementite. In addition, cementite formed a continuous network. Another microstructure defects of that roll are also precipitations of secondary carbides on the boundaries of former grain of austenite as well as the occurrence of upper bainite in its matrix. The results obtained hereunder allow broadening the data base relative to the genesis of damages to mill rolls, which in future will permit one to design a proper microstructure of cast iron mill rolls. Proper microstructure of cast iron mill roll should be shaped at the stage of designing the chemical composition, conditions of crystallization or heat treatment if any.

  18. Bioplastic production using wood mill effluents as feedstock.

    Science.gov (United States)

    Ben, M; Mato, T; Lopez, A; Vila, M; Kennes, C; Veiga, M C

    2011-01-01

    Fibreboard production is one of the most important industrial activities in Galicia (Spain). Great amounts of wastewater are generated, with properties depending on the type of wood, treatment process, final product and water reusing, among others. These effluents are characterized by a high chemical oxygen demand, low pH and nutrients limitation. Although anaerobic digestion is one of the most suitable processes for the treatment, lately bioplastics production (mainly polyhydroxyalkanoates) from wastewaters with mixed cultures is being evaluated. Substrate requirements for these processes consist of high organic matter content and low nutrient concentration. Therefore, wood mill effluents could be a suitable feedstock. In this work, the possibility of producing bioplastics from to wood mill effluents is evaluated. First, wood mill effluent was converted to volatile fatty acids in an acidogenic reactor operated at two different hydraulic retention times of 1 and 1.5 d. The acidification percentage obtained was 37% and 42%, respectively. Then, aerobic batch assays were performed using fermented wood mill effluents obtained at different hydraulic retention times. Assays were developed using different cultures as inoculums. The maximum storage yield of 0.57 Cmmol/Cmmol was obtained when when the culture was enriched on a synthetic media.

  19. Chemical hygiene plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    This plan was written to administer and monitor safety measures and chemical hygiene principles in the TAC Uranium Mill Tailing Remedial Action Project sample preparation facility in Albuquerque, New Mexico. It applies to toxic and/or hazardous materials to radioactive materials.

  20. Avaliação agronômica e química de dezessete acessos de erva-cidreira [Lippia alba (Mill. N.E.Brown] - quimiotipo citral, cultivados no Distrito Federal Agronomic and chemical evaluation of seventeen accessions of "erva-cidreira" [Lippia alba (Mill. N.E.Brown] - citral chemotype, cultivated at the Federal District, Brazil

    Directory of Open Access Journals (Sweden)

    H. Jannuzzi

    2011-01-01

    Full Text Available A erva-cidreira [Lippia alba (Mill. N.E.Brown] é uma espécie nativa utilizada como planta medicinal em todo o Brasil. O citral é responsável pela ação sedativa da erva cidreira, sendo um dos principais componentes do óleo essencial. O objetivo deste trabalho foi avaliar o comportamento agronômico, teor e rendimento de óleo essencial e de citral em 17 acessos de L. alba da coleção da Universidade de Brasília - UnB. O experimento foi realizado no período de 19/02/2005 a 18/03/2006, em latossolo vermelho, no Distrito Federal. O delineamento experimental utilizado foi o de blocos ao acaso, com três repetições, contendo três plantas por parcela. Foram avaliados os parâmetros área foliar, comprimento da haste, produção de massa fresca (folhas e hastes, produção de massa foliar seca, teor de óleo essencial e de citral, rendimento estimado de óleo essencial e de citral por planta, além da caracterização do perfil aromático do óleo essencial. Os acessos L.41 (0,75%, L.45 (0,66% e L.08 (0,62% apresentaram os maiores teores de óleo essencial. O acesso L.45 (1,32 g pl-1 apresentou o maior rendimento de óleo, seguido dos acessos L.47 (0,73 g pl-1, L.41 (0,67 g pl-1, L.34 (0,67 g pl-1 e L.33 (0,62 g pl-1. Os acessos apresentaram teores de citral variando de 51,7% (L.34 a 75,1% (L.09, com média de 63,6% e predominância do isômero geranial (36,4% sobre o neral (27,8%. O acesso L.45 (0,83 g pl-1 apresentou o maior rendimento de citral. Treze acessos apresentaram o quimiotipo citral; três o quimiotipo citral-limoneno e apenas um apresentou o quimiotipo citral-mirceno. Os resultados evidenciam o potencial de produção de citral do acesso L.45, o qual poderá ser utilizado para melhorar a qualidade da matéria prima de erva-cidreira utilizada nos programas de fitoterapia no país ou em programas de melhoramento genético para esta finalidade."Erva-cidreira" [Lippia alba (Mill. N.E.Brown] is a native species used as a medicinal

  1. Measurement of moisture in mill feed ore

    Energy Technology Data Exchange (ETDEWEB)

    Timm, A.R.; Moench, P.; Moisel, E. (Council for Mineral Technology, Randburg (South Africa))

    1985-04-01

    The control of the moisture in the feed to a mill is very important for efficient mill operation. Water is added continuously to the ore fed to a mill to maintain a suitable mix of ore and moisture in the mill. However, problems arise because of the large variation in the moisture content of the ore, which affects the efficiency of the grind. If too little moisture is present, the mill is unable to grind the ore finely enough, creating instead a thick 'porridge' that causes the mill to choke up. On the other hand, too much moisture results in inefficient grinding because the ore is flushed through the mill too quickly. Several techniques are available for measuring moisture and Mintek undertook an investigation in an attempt to develop a reliable robust moisture meter suitable for monitoring the moisture content of ore, which include the following: neutron backscattering, infrared absorption, microwaves, capacitance and moisture as a function of conductivity.

  2. Environmental benchmarking of energy-related kraft mill modifications using LCA

    Energy Technology Data Exchange (ETDEWEB)

    Gaudreault, C.; Wising, U.; Martin, G.; Samson, R.; Stuart, P. [Ecole Polytechnique, Montreal, PQ (Canada)

    2008-12-15

    Life cycle assessment (LCA) tools were used to assess energy efficiency modifications at an integrated kraft pulp and paper mill. The tools were used to build a life cycle model of mill processes and products suitable for benchmarking environmental performance. An iterative process was used for all mill processes in the LCA system boundaries. Process options involving the use of waste paper were considered. Forest operations data included processes from planting seedlings to loading logs onto trucks as well as the manufacturing of fuel, chemicals, and amounts electricity needed. The state-specific fuel mix for electricity supply was applied to mill processes. Emission and resources were classified into categories and potential impacts were evaluated. The study showed that on-site mill operations were the main contributors to the ecotoxicity indicator and human health particulates indicator (HHP). Non mill-related activities accounted for most of the environmental impacts from fossil fuel usage. Paper end-of-life was the principal contributor to the eutrophication indicator. The study showed that converting steam production from coal to bark significantly reduced the environmental impacts of the mill. However the integration of a cogeneration plant did not significantly improve energy efficiency. 20 refs., 7 tabs., 11 figs.

  3. CHEMICAL COMPOUNDS FOR METAL SHAPING

    Science.gov (United States)

    ALLOYS, *CHEMICAL MILLING, *METALS, *REFRACTORY MATERIALS, AIRCRAFT, ALUMINUM ALLOYS, CARBOXYMETHYLCELLULOSE , CHEMICALS, CHROMIUM ALLOYS, GELS, HEAT...RESISTANT ALLOYS, MATERIALS, MOLYBDENUM ALLOYS, NICKEL ALLOYS, NIOBIUM, POROUS MATERIALS, PROCESSING, PRODUCTION , SOLIDS, SOLUTIONS(MIXTURES), STAINLESS STEEL, STEEL, STRUCTURES, TANTALUM, TITANIUM ALLOYS, VANADIUM ALLOYS.

  4. ROLLING MILL SYSTEM DYNAMIC DESIGN

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    It is studied how the aluminum foil chatter mark is produced and controlledThe stableness of hydraulic AGC system,fluid vibration of capsule system,and electromechanical coupling of AC/AC VVVF system and dec oupling are also studiedIt is shown that rolling mill design should go to syst em dynamic design from traditional designThe framed drawing of system dynamic design program is presented

  5. GLYCOSIDES FROM LINARIA VULGARIS MILL

    Directory of Open Access Journals (Sweden)

    Natalia Mashcenko

    2008-12-01

    Full Text Available A new flavonol glycoside, 5,4′-dimethylkaempferol 3-O-β-D-(6′′-α-Lrhamnopyranosyl -glucopyranoside, together with three known compounds were isolated from the n-butanolic soluble fraction of underground and aerial parts of Linaria vulgaris Mill, collected on the territory of Moldova. The characterisation of these compounds was achieved by various chromatographic and spectroscopic methods (IR, UV, 13C-NMR, 1H-NMR and MS.

  6. Chemical Processing Manual

    Science.gov (United States)

    Beyerle, F. J.

    1972-01-01

    Chemical processes presented in this document include cleaning, pickling, surface finishes, chemical milling, plating, dry film lubricants, and polishing. All types of chemical processes applicable to aluminum, for example, are to be found in the aluminum alloy section. There is a separate section for each category of metallic alloy plus a section for non-metals, such as plastics. The refractories, super-alloys and titanium, are prime candidates for the space shuttle, therefore, the chemical processes applicable to these alloys are contained in individual sections of this manual.

  7. Mill Designed Bio bleaching Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Institute of Paper Science Technology

    2004-01-30

    generation of laccase has a broad spectrum of operating parameters. Nonetheless, the development of future genetically engineered laccases with enhanced temperature, pH and redox potentials will dramatically improve the overall process. A second challenge for LMS bleaching technologies is the need to develop effective, catalytic mediators. From the literature we already know this is feasible since ABTS and some inorganic mediators are catalytic. Unfortunately, the mediators that exhibit catalytic properties do not exhibit significant delignification properties and this is a challenge for future research studies. Potential short-term mill application of laccase has been recently reported by Felby132 and Chandra133 as they have demonstrated that the physical properties of linerboard can be improved when exposed to laccase without a chemical mediator. In addition, xxx has shown that the addition of laccase to the whitewater of the paper machine has several benefits for the removal of colloidal materials. Finally, this research program has presented important features on the delignification chemistry of LMS{sub NHA} and LMS{sub VA} that, in the opinion of the author, are momentous contributions to the overall LMS chemistry/biochemistry knowledge base which will continue to have future benefits.

  8. Online SAG Mill Pluse Measurement and Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Raj Rajamani; Jose Delgadillo; Vishal Duriseti

    2007-06-30

    The grinding efficiency of semi autogenous milling or ball milling depends on the tumbling motion of the total charge within the mill. Utilization of this tumbling motion for efficient breakage of particles depends on the conditions inside the mill. However, any kind of monitoring device to measure the conditions inside the mill shell during operation is virtually impossible due to the severe environment presented by the tumbling charge. An instrumented grinding ball, which is capable of surviving a few hours and transmitting the impacts it experiences, is proposed here. The spectrum of impacts collected over 100 revolutions of the mills presents the signature of the grinding environment inside mill. This signature could be effectively used to optimize the milling performance by investigating this signature's relation to mill product size, mill throughput, make-up ball size, mill speed, liner profile and ball addition rates. At the same time, it can also be used to design balls and liner systems that can survive longer in the mill. The technological advances made in electronics and communication makes this leap in instrumentation certainly viable. Hence, the instrumented grinding ball offers the ability to qualitatively observe and optimize the milling environment. An instrumented load cell package that can measure the force of impacts inside the grinding chamber of a mill is developed here. The signal from the instrumented load cell package is interpreted in terms of a histogram termed as an impact spectrum which is a plot of the number of impacts at a specific energy level against the energy. It reflects on the average force regime of the mill. The instrumented load cell package was calibrated against the ultra fast load cell which has been unanimously accepted as a standard to measure single breakage events. The load cell package was successfully used to produce impact spectra in an 8.5 inch lab scale mill. The mill speed and the ball size were varied to

  9. Novel spin glasses by mechanical milling

    Institute of Scientific and Technical Information of China (English)

    周国富; H.Bakker

    1996-01-01

    Novel spin-glass alloys were synthesized by milling intermetallic compounds and also by milling mixtures of crystalline elemental powder in a high-energy ball mill.Spin glass behaviour was found in amorphous Co2Ge,which was amorphised by milling in mechanically disordered crystalline GdAl2 in ball-milled crystalline and amorphous CoZr,and in mechanically alloyed Co-Cu,which formed a supersaturated f.c.c.solid solution.All these materials are binary alloys and tlie concentration of the magnetic element is high,which makes them novel types of spin glasses.It is shown that ball milling may not only lead to structural metallic glasses,but can also generate the magnetic pendant of a structural glass,namely the spin glass.

  10. Formation of surface coating on milling balls during milling of Cr powders

    Institute of Scientific and Technical Information of China (English)

    王成国; 齐宝森; 王瑞华

    2002-01-01

    The formation regularity of surface coating on milling balls during milling of Cr powders was investigated, revealing that the plastic deformation of the balls surface plays an important role in the formation of coating and that the stronger affinity between the powders and the balls is a necessary pre-condition for the coating. The size of Cr powders, the coating thickness and the microhardness vary consistently with milling time during milling. At initial milling stage, the powder size decreases, while the coating thickness and the microhardness increase, however, after milling for 24h, they all change slightly with prolonged milling, indicating a dynamic equilibrium between the powders cold welding and crashing, i.e. an almost equal rate for the powders attaching to and breaking off the milling balls.

  11. 75 FR 49524 - Woodland Mills Corporation, Mill Spring, NC; Notice of Affirmative Determination Regarding...

    Science.gov (United States)

    2010-08-13

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF LABOR Employment and Training Administration Woodland Mills Corporation, Mill Spring, NC; Notice of Affirmative Determination Regarding Application for Reconsideration By application dated July 22, 2010,...

  12. Bio-refinery system of DME or CH4 production from black liquor gasification in pulp mills.

    Science.gov (United States)

    Naqvi, M; Yan, J; Fröling, M

    2010-02-01

    There is great interest in developing black liquor gasification technology over recent years for efficient recovery of bio-based residues in chemical pulp mills. Two potential technologies of producing dimethyl ether (DME) and methane (CH(4)) as alternative fuels from black liquor gasification integrated with the pulp mill have been studied and compared in this paper. System performance is evaluated based on: (i) comparison with the reference pulp mill, (ii) fuel to product efficiency (FTPE) and (iii) biofuel production potential (BPP). The comparison with the reference mill shows that black liquor to biofuel route will add a highly significant new revenue stream to the pulp industry. The results indicate a large potential of DME and CH(4) production globally in terms of black liquor availability. BPP and FTPE of CH(4) production is higher than DME due to more optimized integration with the pulping process and elimination of evaporation unit in the pulp mill.

  13. STABILIZATION OF EXPANSIVE SOIL USING MILL SCALE

    OpenAIRE

    Y.I.Murthy

    2012-01-01

    The present paper deals with the evaluation of the mechanical properties of black cotton soil mixed with mill scale in varying proportions and comparing the same with the results of pure black cotton soil. The mechanical properties of mill scale and black cotton soil are individually determined first and then the two are combined in varying proportions. The properties like plastic limit, CBR and Permeability of the same are evaluated. It is found that mixing mill scale in varying proportions ...

  14. Geometrical characterization of micro end milling tools

    DEFF Research Database (Denmark)

    Borsetto, Francesca; Bariani, Paolo; Bissacco, Giuliano;

    2005-01-01

    Performance of the milling process is directly affected by the accuracy of tool geometry. Development of methods suitable for dimensional characterization of such tools, with low measurement uncertainties is therefore of relevance. The present article focuses on the geometrical characterization...... of a flat micro end milling tool with a nominal mill diameter of 200 microns. An experimental investigation was carried out involving two different non-contact systems...

  15. Robotic milling for rapid ceramic pototyping

    Institute of Scientific and Technical Information of China (English)

    HAN Guang-chao; ZHANG Hai-ou; WANG Gui-lan

    2005-01-01

    Robotic milling is a developing method for rapidly producing prototypes and parts, but the application is limited for materials such as wax, wood, plastic and light metal, etc. The reason for this is because of the robotic weak rigidity. In this paper, a method of robotic milling for ceramic prototyping is developed, one that has been successfully applied in a new rapid hard tooling technology-Direct Prototype Spray Tooling[1]. At first, the appropriate ceramic materials mixed with metal powder are confirmed for the robotic milling and the following plasma spraying process. Then the 6 - DOF robotic milling paths are extracted from the NC code and transformed into the robotic JBI type file, the NC code generated through the general CAD/CAM software such as UG -NX.Finally, the robotic milling characteristics such as moving path accuracy and milling force are tested to find the best milling parameters and to ensure the executable, accurate and efficient ceramic prototype milling technology.The development of this method not only broadens the robotic milling material range but also extends the rapid prototyping fields. It can also be used for producing ceramic parts that are difficult to machine.

  16. Structural evolution of ball-milled permalloy

    Energy Technology Data Exchange (ETDEWEB)

    Brzozka, K., E-mail: kbrzozka@poczta.f [Technical University, Department of Physics (Poland); Oleksakova, D.; Kollar, P. [P.J. Safarik University, Department of Condensed Matter Physics, Institute of Physics, Faculty of Science (Slovakia); Szumiata, T.; Gorka, B.; Gawronski, M. [Technical University, Department of Physics (Poland)

    2006-02-15

    Two series of Fe{sub 19.8}Ni{sub 80.2} samples obtained by ball milling and differing in the form of starting material were investigated by Moessbauer spectroscopy. In the case of milled elemental powder, strong structural evolution was stated: both {alpha} and {gamma} phases arise and a small amount of pure iron is present as well. The annealing of as-milled powder at 490{sup o}C causes faster forming of {gamma}-(Ni-Fe) phase. Only slight changes in atomic order were stated in the series of milled polycrystalline ribbon.

  17. Cutting Characteristics of Force Controllable Milling Head

    Institute of Scientific and Technical Information of China (English)

    Shirakashi; Takahiro; Shibuya; Wataru

    2002-01-01

    In order to control cutting force and its direction i n milling operation, a new milling head was developed. The head has two milling cutters, which are connected by a pair of gears and rotate in opposite direction respectively. Both up-cut and down-cut can be carried out simultaneously by t hese milling cutters. The each depth of cut, the ratio of up/down cutting depth , by these cutters can be also selected. The cutting force characteristics were experimentally discussed by changing the ratio. The cut...

  18. Process engineering with planetary ball mills.

    Science.gov (United States)

    Burmeister, Christine Friederike; Kwade, Arno

    2013-09-21

    Planetary ball mills are well known and used for particle size reduction on laboratory and pilot scales for decades while during the last few years the application of planetary ball mills has extended to mechanochemical approaches. Processes inside planetary ball mills are complex and strongly depend on the processed material and synthesis and, thus, the optimum milling conditions have to be assessed for each individual system. The present review focuses on the insight into several parameters like properties of grinding balls, the filling ratio or revolution speed. It gives examples of the aspects of grinding and illustrates some general guidelines to follow for modelling processes in planetary ball mills in terms of refinement, synthesis' yield and contamination from wear. The amount of energy transferred from the milling tools to the powder is significant and hardly measurable for processes in planetary ball mills. Thus numerical simulations based on a discrete-element-method are used to describe the energy transfer to give an adequate description of the process by correlation with experiments. The simulations illustrate the effect of the geometry of planetary ball mills on the energy entry. In addition the imaging of motion patterns inside a planetary ball mill from simulations and video recordings is shown.

  19. THE EFFICIENCY OF NEW INSECTICIDE CARBAMATE IN CHEMICAL CONTROL OF TOMATO LEAFMINER (Scrobipalpuloides absoluta MEYRIC, 1917 IN TOMATO PLANTS (Lycopersicon esculentum, MILL EFICIÊNCIA DE NOVO INSETICIDA CARBAMATO NO CONTROLE QUÍMICO DA TRAÇA (Scrobipalpuloides absoluta Meyric1917 SOBRE TOMATEIRO (Lycopersicon esculentum, Mill

    Directory of Open Access Journals (Sweden)

    Antônio Lopes da Silva

    2007-09-01

    Full Text Available

    The tomato leafminer (Scrobipalpuloides absoluta, a common pest of tomato plants, is known in many regions in Brazil. In order to determine the efficiency of new insecticide alanycarb, to control the tomato leafminer a field experiment was carried out in Goiânia, Goiás, Brazil. The treatments and dosage of the insecticides per hectare were: alanycarb 300: 1.0, 1.5 and 2.0 l; cartap 500 BR: 2.0 kg; abamectin 18 CE: 1.0 1 plus an untreated check. The results obtained in this experiment showed that all insecticides were efficient in controlling the tomato leafminer until 8 days after treatment application and they were able to increase productivity.

    KEY-WORDS: Scrobipalpuloides absoluta; tomato leafminer; chemical control.

    O experimento foi realizado na área de horticultura da Escola de Agronomia da Universidade Federal de Goiás, visando ao controle químico da traça do tomateiro (Scrobipalpuloides absoluta Meyric, 1917, no período de setembro a dezembro de 1995, para avaliar a eficiência do inseticida Onic 300 (Alanycarb nas dosagens de 1,0, 1,5 e 2,0 litros do produto formulado por ha, comparando-o com Cartap 500 BR (Cartap na dosagem de 2,4 kg/ha, Vertimec 18 CE (Abamectin na dosagem de 1,0 l/ha misturado a um óleo mineral e uma testemunha. Pelos resultados obtidos concluiu-se que todos os inseticidas utilizados controlaram eficientemente a traça em tomateiro até 8 dias após aplicação e que todos os tratamentos promoveram aumento de produtividade.

    PALAVRAS-CHAVE: Traça; Scrobipalpuloides absoluta; controle químico; tomateiro.

  20. Palm Oil Milling Wastes and Sustainable Development

    Directory of Open Access Journals (Sweden)

    A. C. Er

    2011-01-01

    Full Text Available Problem statement: Palm oil milling generates solid wastes, effluent and gaseous emissions. The aim of this study is to assess the progress made in waste management by the Malaysian palm oil milling sector towards the path of sustainable development. Sustainable development is defined as the utilization of renewable resources in harmony with ecological systems. Inclusive in this definition is the transition from low value-added to higher value-added transformation of wastes into resources. Approach: A longitudinal study was carried out from 2003-2010 via, initially a field survey and subsequently a key informant approach with observation as a complementation for both. Results: Solid wastes, inclusive of solid wastes derived from air emissions and palm oil mil effluent, have a utility function with zero wastage. The principal source of effluent is palm oil mill effluent. Treated palm oil mill effluent is utilized for cropland application by plantation-based palm oil mills. However, independent mills discharge treated palm oil mill effluent in accordance to environmental parameters into receiving waterways. Methane is also released by palm oil mill effluent. Biogas from palm oil mill effluent and biomass energy from solid wastes are potential sources of renewable energy in Malaysia. Conclusion: In general, the wastes from palm oil milling are returned to the field for cropland application, utilized in-house or in the plantation, or sold to third parties. Thus, there is progress made towards sustainable development. The addition of new technologies and replacement of old mills will help to reduce the carbon footprint. However, at this juncture, the feed-in tariff for renewable energy is not financially attractive. If the biogas and biomass renewable energy sector were to take-off, enhancement in the value chain would occur and in tandem further progress towards sustainable development can be attained.

  1. A survey of Canadian mechanical pulp and paper mill effluents: insights concerning the potential to affect fish reproduction.

    Science.gov (United States)

    Kovacs, Tibor G; Martel, Pierre H; O'Connor, Brian I; Hewitt, L Mark; Parrott, Joanne L; McMaster, Mark E; MacLatchy, Deborah L; Van Der Kraak, Glen J; Van Den Heuvel, Michael R

    2013-01-01

    Building on breakthroughs recently made at kraft mills, a survey of mechanical pulp and paper mill effluents was undertaken to gain insights concerning potential effects on fish reproduction. Effluents from seven Canadian mills were characterized chemically for conventional parameters such as biochemical oxygen demand (BOD) and total suspended solids (TSS). Each sample was further subjected to solvent extraction followed by gas chromatographic separation for the determination of resin/fatty acids and for the estimation of a gas chromatography (GC) profile index. Each mill effluent was assessed for the potential to affect fish reproduction in the laboratory using a five day adult fathead minnow (Pimephales promelas) egg production bioassay with exposures to 100% effluent. The seven effluents were found to have substantial variation both in terms of chemical characterization and effects on fish reproduction. Temporal variations were also noted in effluent quality at mills sampled on different occasions. Similar to what has been observed for kraft mills, a general trend of greater reductions in egg production caused by effluents with greater BOD concentrations and GC profile indices was noted. Effluents with BOD > 25 mg/L and GC Profile indices >5.0 caused a complete cessation of egg production. At the same time, about half of the total effluents sampled had BOD reproductive effects caused by such effluents is presently unclear. The effluent quality parameters considered in this study may require further refinement to address their utility in predicting the adverse reproductive effects induced by effluents from mechanical pulp and paper mills.

  2. Study on the effect of super micro-milling on physio-chemical properties of Elaeagnus angustifolia L. powders%沙枣细粉超微粉碎后对物化特性的影响研究

    Institute of Scientific and Technical Information of China (English)

    梁琪; 毕阳; 米兰; 张炎; 刘英英

    2012-01-01

    The differences of physio-chemical between Elaeagnus angustifolia L. ultrafine powders and particles were studied. UItrafine powders were achieved by turbine crusher,the morphology,main ingredients,the angle of repose and slide,swelling capacity,density and solubility were determined. The results showed that it was more uniform on the grain size of Elaeagnus angustifolia L. ultrafine powders. The active ingredients of Elaeagnus angustifolia L. ultrafine powders and particles were not changed through FTIR spectroscopy. The fluidity of Elaeagnus angustifolia L. ultrafine powders was poorer,but the force of expansion,solubility and stacking density had different increases than particles. It was useful for the nutrition and application because of the physical properties of Elaeagnus angustifolia L. ultrafine powders improved.%研究普通粉碎的沙枣细粉经超微粉碎后的微粉之间物化特性的差异。利用涡轮粉碎机对沙枣细粉进行超微粉碎,测定分析微粉与细粉粉体形貌、主要成分、休止角、滑角、膨胀力、松密度以及水溶性等指标的变化。结果表明,沙枣微粉的颗粒大小均匀,红外光谱显示沙枣经超微粉碎后其主要成分未发生变化;沙枣微粉与细粉相比,粉体的流动性变差,膨胀力、松密度和水溶性较之细粉均有不同程度的提高。沙枣微粉物理特性的改善有助于营养成分溶出及指导微粉的应用生产。

  3. Effect of Initial Aluminum Alloy Particle Size on the Damage of Carbon Nanotubes during Ball Milling

    Directory of Open Access Journals (Sweden)

    Xian Zhu

    2016-03-01

    Full Text Available Damage to carbon nanotubes (CNTs during the fabrication process of CNT reinforced composites has great influence on their mechanical properties. In this study, the 2014 Al with powder sizes of 20, 9 and 5 μm was selected to study the effect of initial particle size on the damage to carbon nanotubes (CNTs during ball milling. The result shows that for CNTs in the ball milled CNT/Al (with powder size of 20 and 9 μm mixtures, the intensity ratio of the D band and the G band (ID/IG first increased and then reached a plateau, mainly because most of the CNTs are embedded, to a certain extent, in the aluminum powder after milling, which could protect the CNTs from damage during further milling. While for CNTs in the ball milled CNT/Al (with powder size of 5 μm mixture, the ID/IG ratio continues to climb from 1.31 to 2.33 with time, indicating continuous damage to the CNTs occurs during the milling. Differential scanning calorimetry (DSC analysis demonstrates that the chemical instability increased with an increase in the damage level of CNTs, resulting in the formation of aluminum carbide (Al4C3 at a lower temperature before the melting of aluminum, which is detrimental to their mechanical properties.

  4. Uranium mill ore dust characterization

    Energy Technology Data Exchange (ETDEWEB)

    Knuth, R.H.; George, A.C.

    1980-11-01

    Cascade impactor and general air ore dust measurements were taken in a uranium processing mill in order to characterize the airborne activity, the degree of equilibrium, the particle size distribution and the respirable fraction for the /sup 238/U chain nuclides. The sampling locations were selected to limit the possibility of cross contamination by airborne dusts originating in different process areas of the mill. The reliability of the modified impactor and measurement techniques was ascertained by duplicate sampling. The results reveal no significant deviation from secular equilibrium in both airborne and bulk ore samples for the /sup 234/U and /sup 230/Th nuclides. In total airborne dust measurements, the /sup 226/Ra and /sup 210/Pb nuclides were found to be depleted by 20 and 25%, respectively. Bulk ore samples showed depletions of 10% for the /sup 226/Ra and /sup 210/Pb nuclides. Impactor samples show disequilibrium of /sup 226/Ra as high as +-50% for different size fractions. In these samples the /sup 226/Ra ratio was generally found to increase as particle size decreased. Activity median aerodynamic diameters of the airborne dusts ranged from 5 to 30 ..mu..m with a median diameter of 11 ..mu..m. The maximum respirable fraction for the ore dusts, based on the proposed International Commission on Radiological Protection's (ICRP) definition of pulmonary deposition, was < 15% of the total airborne concentration. Ore dust parameters calculated for impactor duplicate samples were found to be in excellent agreement.

  5. The effects of lifter configurations and mill speeds on the mill power draw and performance

    Science.gov (United States)

    Usman, Husni; Taylor, Patrick; Spiller, D. Erik

    2017-01-01

    Grinding mills used in the mining industries are the most energy-intensive operation and require a large number of wear resistant materials as well. The 1-m mill was used to investigate the effects of three lifter configurations, namely Hi (High), Rail and Hi-Lo (High-Low), and mill speeds on the mill performance. The MillTraj software was also utilized to simulate the outermost charge trajectories of the mill. At the given operating conditions, the power draw of Hi lifter was slightly lower than that of the Rail and the Hi-Lo and thus, the Hi lifter showed improvement in the mill efficiency. The product size distributions of the different lifters are very close and the size distribution of Hi-Lo lifter is slightly finer than those of the other lifters. At 74% critical speed, the size distributions of the Rail and Hi-Lo lifters were finer than at 70% critical speed, while that of Hi lifter otherwise occurs. At 80% critical speed, the size distributions of the lifters were coarser than at 74% critical speed. In this case, the outer charge trajectories of each lifter could go down on the mill shell rather than on the toe of the mill charge, resulting in ineffective grinding. Increasing face angles and/or mill charge would allow the mill to be operated at higher speeds.

  6. Vertical mill simulation applied to iron ores

    Directory of Open Access Journals (Sweden)

    Douglas Batista Mazzinghy

    2015-04-01

    Full Text Available The application of vertical mills in regrind circuits is consolidated. This type of mill is now attracting interest in primary grinding applications, due to its higher efficiency when compared to ball mills, which are usually used at this stage. In this study, a coarse sample of iron ore was tested in a pilot scale grinding circuit with a vertical mill. Other three samples of pellet feed had already been tested with the methodology used in this study. The sample of coarse iron ore was characterized in laboratory tests carried out in a small batch ball mill. Selection and breakage function parameters were determined from the laboratory tests. The parameters were then used for simulating the pilot scale tests using Modsim™ software. The model previously implemented in Modsim™ has been successfully applied to represent the vertical mill operated with different ores. The simulations produced particle size distributions that were very close to the actual size distributions, and the predictions were accomplished only by imputing the calibrated parameters from the batch tests, the power draw and the feed size distribution of the pilot tests. The methodology is therefore useful for scale-up and simulation of vertical mills, only requiring laboratory tests that can be carried out in standard laboratory batch ball mills with small amounts of samples.

  7. Jiangsu Mills Attempt to Adjust Production

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The profit squeeze on China’s textile mills continues. In Jiangsu Province, a very important market, mills are reacting in a variety of ways to this situation. Spinners and weavers of man-made fiber appear to be the most adversely affected,

  8. Improvement of the stone elimination roller mill

    Institute of Scientific and Technical Information of China (English)

    SunGuofeng

    2005-01-01

    Elimination roller mill as raw materials preparing equipments is universally used in brick making industry. Stone Elimination Roller Mill should have following characteristics: high machine strength and good wearresistant of roller shell, safety reliability, high machinery intensity (impact strength) and rigidity, reliable hermetically sealed construction.

  9. Radiological health aspects of uranium milling

    Energy Technology Data Exchange (ETDEWEB)

    Fisher, D.R.; Stoetzel, G.A.

    1983-05-01

    This report describes the operation of conventional and unconventional uranium milling processes, the potential for occupational exposure to ionizing radiation at the mill, methods for radiological safety, methods of evaluating occupational radiation exposures, and current government regulations for protecting workers and ensuring that standards for radiation protection are adhered to. In addition, a survey of current radiological health practices is summarized.

  10. Evaluation of the Phytotoxic and Genotoxic Potential of Pulp and Paper Mill Effluent Using Vigna radiata and Allium cepa

    OpenAIRE

    Izharul Haq; Vineeta Kumari; Sharad Kumar; Abhay Raj; Mohtashim Lohani; Ram Naresh Bhargava

    2016-01-01

    Pulp and paper mill effluent induced phytotoxicity and genotoxicity in mung bean (Vigna radiata L.) and root tip cells of onion (Allium cepa L.) were investigated. Physicochemical characteristics such as electrical conductivity (EC), biological oxygen demand (BOD5), chemical oxygen demand (COD), and total phenols of the pulp and paper mill effluent were beyond the permissible limit specified for the discharge of effluent in inland water bodies. Compared to control plants, seedling exposed to ...

  11. Effect of paper mill effluent on germination of green gram (Phaseolus aureus Roxb.) and growth behaviour of it's seedlings.

    Science.gov (United States)

    Malla, Luna; Mohanty, B K

    2005-06-01

    Effect of paper mill effluents on Phaseolus aureus Roxb was studied. The effluent significantly inhibited germination of root and shoot length. The bio-chemical injury does not appear spontaneously but with the increase in effluent treatment there is reduction in observed biochemical parameters (chlorophyll, protein, amino acid, nuclic acids and carbohydrate) which are negatively correlated. The shoots of the seedlings were found to be resistant; whereas roots of the seedlings were susceptible to paper mill effluent treatment.

  12. Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams

    Energy Technology Data Exchange (ETDEWEB)

    Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

    2007-04-01

    Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25°C with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

  13. Selective Enrichment of a Methanol-Utilizing Consortium Using Pulp and Paper Mill Waste Streams

    Science.gov (United States)

    Mockos, Gregory R.; Smith, William A.; Loge, Frank J.; Thompson, David N.

    Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater. Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Wasteactivated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25°C with a hydraulic residence time and a solids retention time of 4 days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24-h feed/ decant cycles ranged from 79 to 89%, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste-activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen-limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen-limited conditions. This indicates that selectively enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

  14. Hydrolysis behavior of zirconium diboride during attrition milling

    Energy Technology Data Exchange (ETDEWEB)

    Yin Jie; Zhang Hui; Yan Yongjie [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Huang Zhengren, E-mail: zrhuang@mail.sic.ac.cn [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Liu Xuejian [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Yang Yong, E-mail: yangyong@mail.sic.ac.cn [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Jiang Dongliang [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer The surface was mainly covered of Zr-O, B-O and B-OH bonds after hydrolysis. Black-Right-Pointing-Pointer ZrB{sub 2} powder tended to behave like a B{sub 2}O{sub 3}-modified surface by milling treatment. Black-Right-Pointing-Pointer The surface B/Zr atomic ratio decreased from water to ethanol medium. Black-Right-Pointing-Pointer The nano-sized oxide layer ({approx}5 nm) was observed and helped to improve the dispersion of ZrB{sub 2} particles in dilute aqueous media. - Abstract: The hydrolysis behavior of ZrB{sub 2} powder during attrition milling was studied in de-ionized water and ethanol. Surface characterization, thermal analysis, chemical analysis and electron microscopy were utilized to analyze the surface properties of as-milled powders. The results proved that the surface of ZrB{sub 2} powder was mainly composed of Zr-O, B-O and B-OH bonds as hydrolysis proceeded, and the amount of surface B-O bond was found to increase rapidly in water, suggesting a more B{sub 2}O{sub 3}-like surface behavior were developed. Results also showed when milled at 300 rpm for 4 h in water, 64.45 at% of B was in the form of B{sub 2}O{sub 3} at a thickness of {approx}3 nm from the surface. The nano-sized surface Zr-B-O oxide layer ({approx}5 nm in thickness) could help to improve the dispersion of powder in aqueous media.

  15. Structural, microstructural and vibrational characterization of apatite-type lanthanum silicates prepared by mechanical milling

    Science.gov (United States)

    Rodríguez-Reyna, E.; Fuentes, A. F.; Maczka, M.; Hanuza, J.; Boulahya, K.; Amador, U.

    2006-02-01

    Apatite-type lanthanum silicates have been successfully prepared at room temperature by dry milling hexagonal A-La 2O 3 and either amorphous or low cristobalite SiO 2. Milling a stochiometric mixture of these chemicals in a planetary ball mill with a moderate rotating disc speed (350 rpm), allows the formation of the target phase after only 3 h although longer milling times are needed to eliminate all SiO 2 and La 2O 3 traces. Thus, the mechanically activated chemical reaction proceeds faster when using amorphous silica instead of low cristobalite as silicon source and pure phases are obtained after only 9 and 18 h, respectively. As obtained powder phases are not amorphous and show an XRD pattern as well as IR and Raman bands characteristic of the lanthanum silicate. The domain size of the as-prepared phases varies gradually with the temperature of post-milling thermal treatment with activation energies of about 26(8) and 52(10) kJ mol -1 K -1 for the apatites obtained from amorphous silica and low-cristobalite, respectively. These values suggest crystallite growth to be favored when using amorphous silica as reactant.

  16. Einstein--Yang--Mills strings

    CERN Document Server

    Galtsov, D V; Volkov, M S; Davydov, Evgeny A.; Gal'tsov, Dmitri V.; Volkov, Mikhail S.

    2006-01-01

    We present globally regular vortex-type solutions for a pure SU(2) Yang-Mills field coupled to gravity in 3+1 dimensions. These gravitating vortices are static, cylindrically symmetric and purely magnetic, and they support a non-zero chromo-magnetic flux through their cross section. In addition, they carry a constant non-Abelian current, and so in some sense they are analogs of the superconducting cosmic strings. They have a compact central core dominated by a longitudinal magnetic field and endowed with an approximately Melvin geometry. This magnetic field component gets color screened in the exterior part of the core, outside of which the fields approach exponentially fast those of the electrovacuum Bonnor solutions with a circular magnetic field. In the far field zone the solutions are not asymptotically flat but tend to vacuum Kasner metrics.

  17. Biological Kraft Chemical Recycle for Augmentation of Recovery Furnace Capacity

    Energy Technology Data Exchange (ETDEWEB)

    Stuart E. Strand

    2001-12-06

    The chemicals used in pulping of wood by the kraft process are recycled in the mill in the recovery furnace, which oxidizes organics while simultaneously reducing sulfate to sulfide. The recovery furnace is central to the economical operation of kraft pulp mills, but it also causes problems. The total pulp production of many mills is limited by the recovery furnace capacity, which cannot easily be increased. The furnace is one of the largest sources of air pollution (as reduced sulfur compounds) in the kraft pulp mill.

  18. Active chatter control in a milling machine

    Energy Technology Data Exchange (ETDEWEB)

    Dohner, J.L.; Hinnerichs, T.D.; Lauffer, J.P. [and others

    1997-08-01

    The use of active feedback compensation to mitigate cutting instabilities in an advanced milling machine is discussed in this paper. A linear structural model delineating dynamics significant to the onset of cutting instabilities was combined with a nonlinear cutting model to form a dynamic depiction of an existing milling machine. The model was validated with experimental data. Modifications made to an existing machine model were used to predict alterations in dynamics due to the integration of active feedback compensation. From simulations, subcomponent requirements were evaluated and cutting enhancements were predicted. Active compensation was shown to enable more than double the metal removal rate over conventional milling machines. 25 refs., 10 figs., 1 tab.

  19. Yang-Mills origin of gravitational symmetries

    CERN Document Server

    Anastasiou, A; Duff, M J; Hughes, L J; Nagy, S

    2014-01-01

    By regarding gravity as the convolution of left and right Yang-Mills theories, we derive in linearised approximation the gravitational symmetries of general covariance, p-form gauge invariance, local Lorentz invariance and local supersymmetry from the flat space Yang-Mills symmetries of local gauge invariance and global super-Poincar\\'e. As a concrete example we focus on the new-minimal (12+12) off-shell version of simple four-dimensional supergravity obtained by tensoring the off-shell Yang-Mills multiplets (4 + 4, N_L = 1) and (3 + 0, N_R = 0).

  20. Wilson Loops in Noncommutative Yang Mills

    CERN Document Server

    Ishibashi, N; Kawai, H; Kitazawa, Y; Ishibashi, Nobuyuki; Iso, Satoshi; Kawai, Hikaru; Kitazawa, Yoshihisa

    2000-01-01

    We study the correlation functions of the Wilson loops in noncommutative Yang-Mills theory based upon its equivalence to twisted reduced models. We point out that there is a crossover at the noncommutativity scale. At large momentum scale, the Wilson loops in noncommmutative Yang-Mills represent extended objects. They coincide with those in ordinary Yang-Mills theory in low energy limit. The correlation functions on D-branes in IIB matrix model exhibit the identical crossover behavior. It is observed to be consistent with the supergravity description with running string coupling. We also explain that the results of Seiberg and Witten can be simply understood in our formalism.

  1. Simulation of accelerated strip cooling on the hot rolling mill run-out roller table

    Directory of Open Access Journals (Sweden)

    E.Makarov

    2016-07-01

    Full Text Available A mathematical model of the thermal state of the metal in the run-out roller table continuous wide hot strip mill. The mathematical model takes into account heat generation due to the polymorphic γ → α transformation of supercooled austenite phase state and the influence of the chemical composition of the steel on the physical properties of the metal. The model allows calculation of modes of accelerated cooling strips on run-out roller table continuous wide hot strip mill. Winding temperature calculation error does not exceed 20°C for 98.5 % of strips of low-carbon and low-alloy steels

  2. One step conversion of wheat straw to sugars by simultaneous ball milling, mild acid, and fungus Penicillium simplicissimum treatment.

    Science.gov (United States)

    Yuan, Li; Chen, Zhenhua; Zhu, Yonghua; Liu, Xuanming; Liao, Hongdong; Chen, Ding

    2012-05-01

    Wheat straw is one of the major lignocellulosic plant residues in many countries including China. An attractive alternative is the utilization of wheat straw for bioethanol production. This article mainly studies a simple one-step wet milling with Penicillium simplicissimum and weak acid to hydrolysis of wheat straw. The optimal condition for hydrolysis was ball milling 48 h in citrate solvent (pH = 4) with P. simplicissimum H5 at the speed of 500 rpm and the yield of sugar increased with increased milling time. Corresponding structure transformations before and after milling analyzed by X-ray diffraction, transmission Fourier transform infrared spectroscopy, and environmental scanning electron microscopy clearly indicated that this combined treatment could be attributed to the crystalline and chemical structure changes of cellulose in wheat straw during ball milling. This combined treatment of ball milling, mild acid, and fungus hydrolysis enabled the conversion of the wheat straw. Compared with traditional method of ball milling, this work showed a more simple, novel, and environmentally friendly way in mechanochemical treatment of wheat straw.

  3. Microstructural Evolution, Thermodynamics, and Kinetics of Mo-Tm2O3 Powder Mixtures during Ball Milling

    Directory of Open Access Journals (Sweden)

    Yong Luo

    2016-10-01

    Full Text Available The microstructural evolution, thermodynamics, and kinetics of Mo (21 wt % Tm2O3 powder mixtures during ball milling were investigated using X-ray diffraction and transmission electron microscopy. Ball milling induced Tm2O3 to be decomposed and then dissolved into Mo crystal. After 96 h of ball milling, Tm2O3 was dissolved completely and the supersaturated nanocrystalline solid solution of Mo (Tm, O was obtained. The Mo lattice parameter increased with increasing ball-milling time, opposite for the Mo grain size. The size and lattice parameter of Mo grains was about 8 nm and 0.31564 nm after 96 h of ball milling, respectively. Ball milling induced the elements of Mo, Tm, and O to be distributed uniformly in the ball-milled particles. Based on the semi-experimental theory of Miedema, a thermodynamic model was developed to calculate the driving force of phase evolution. There was no chemical driving force to form a crystal solid solution of Tm atoms in Mo crystal or an amorphous phase because the Gibbs free energy for both processes was higher than zero. For Mo (21 wt % Tm2O3, it was mechanical work, not the negative heat of mixing, which provided the driving force to form a supersaturated nanocrystalline Mo (Tm, O solid solution.

  4. Bioremediation of Agro-Based Pulp Mill Effluent by Microbial Consortium Comprising Autochthonous Bacteria

    Directory of Open Access Journals (Sweden)

    Virendra Kumar

    2012-01-01

    Full Text Available Small-scale agro-based pulp and paper mills are characterized as highly polluting industries. These mills use Kraft pulping process for paper manufacturing due to which toxic lignified chemicals are released into the environment. Lack of infrastructure, technical manpower, and research and development facilities restricts these mills to recover these chemicals. Therefore, the chemical oxygen demand (COD of the emanating stream is quite high. For solving the above problem, four bacteria were isolated from the premises of agro-based pulp and paper mill which were identified as species of Pseudomonas, Bacillus, Pannonibacter, and Ochrobacterum. These bacteria were found capable of reducing COD up to 85%–86.5% in case of back water and 65-66% in case of back water : black liquor (60 : 40, respectively, after acclimatization under optimized conditions (pH 6.8, temperature 35°C, and shaking 200 rpm when the wastewater was supplemented with nitrogen and phosphorus as trace elements.

  5. GENERALIZED SIMULATION MODEL FOR MILLED SURFACE TOPOGRAPHY-APPLICATION TO PERIPHERAL MILLING

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Based on analyzing various factors influencing milled surface topography, firstly, a generalized model for milled surface topography is proposed. Secondly, using the principles of transformation matrix and vector operation, the trajectory equation of cutting edge relative to workpiece is derived. Then, a three-dimensional topography simulation algorithm is constructed through dividing the workpiece into regular grids. Finally, taking the peripheral milling process as an example, the generalized model is simplified, and the corresponding simulation examples are given. The results indicate that it is very efficient for the generalized model to be used to analyze and simulate the peripherally milled surface topography.

  6. Chemical milling solution reveals stress corrosion cracks in titanium alloy

    Science.gov (United States)

    Braski, D. N.

    1967-01-01

    Solution of hydrogen flouride, hydrogen peroxide, and water reveals hot salt stress corrosion cracks in various titanium alloys. After the surface is rinsed in water, dried, and swabbed with the solution, it can be observed by the naked eye or at low magnification.

  7. Continuous grinding mill simulation using Austin's model

    Directory of Open Access Journals (Sweden)

    André Carlos Silva

    2012-01-01

    Full Text Available Comminution is a frequently-required step in mineral processing and is responsible for almost 90% of all energy consumption in a mineral processing plant. Tumbling mill design has been studied since the middle of the XIX century. There are many comminution models in the literature, with preponderance, however, of Austin’s model (2002 for mineral impact breakage. In this paper, Austin’s model was applied to tubular tumbling mills. Once Austin's model was proposed for batch processing of narrowly-distributed fraction sizes, an artifice has allowed it to be used in continuous grinding mill processes with widely-distributed fraction sizes. Interesting results were obtained with errors less than 0.005 for mills with sharp residence time distributions.

  8. Uranium Mill and ISL Facility Database

    Data.gov (United States)

    U.S. Environmental Protection Agency — An Excel database on NRC and Agreement State licensed mills providing status, locational/operational/restoration data, maps, and environmental reports including...

  9. Scientific basis for risk assessment and management of uranium mill tailings

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    A National Research Council study panel, convened by the Board on Radioactive Waste Management, has examined the scientific basis for risk assessment and management of uranium mill tailings and issued this final report containing a number of recommendations. Chapter 1 provides a brief introduction to the problem. Chapter 2 examines the processes of uranium extraction and the mechanisms by which radionuclides and toxic chemicals contained in the ore can enter the environment. Chapter 3 is devoted to a review of the evidence on health risks associated with radon and its decay products. Chapter 4 provides a consideration of conventional and possible new technical alternatives for tailings management. Chapter 5 explores a number of issues of comparative risk, provides a brief history of uranium mill tailings regulation, and concludes with a discussion of choices that must be made in mill tailing risk management. 211 refs., 30 figs., 27 tabs.

  10. Reducibility mill scale industrial waste via coke breeze at 850-950ºC

    Directory of Open Access Journals (Sweden)

    Gaballah N.M.

    2015-01-01

    Full Text Available Mill scale is a very attractive industrial waste due to its elevated iron content (about = 69.33% Fe besides being suiTab. for direct recycling to the blast furnace via sintering plant. In this paper the characteristics of raw materials and the briquettes produced from this mill scale were studied by different methods of analyses. The produced briquettes were reduced with different amounts of coke breeze at varying temperatures, and the reduction kinetics was determined. The activation energy of this reaction ≈ 61.5 kJ/mole for reduction of mill scale with coke breeze in the form of briquettes with 2% molasses where the chemical reaction interface model is applicable.

  11. Root causes for failures in flattening test in high frequency induction welded steel pipe mill

    Energy Technology Data Exchange (ETDEWEB)

    Babakri, Khalid Ali [Saudi Steel Pipe Company, Dammam, (Saudi Arabia)

    2010-07-01

    The flattening test is used to test weld integrity in high frequency induction welded (HFIW) steel pipe mills. The flattening test failures happen mostly with the formation of oxides in the weld area during HFIZ process. This study investigated the root causes for failure in flattening test due to improper process control in the HFIW steel pipe mill. Several flattening tests have been carried out on API 5L X60 steel pipes with various chemical compositions and various procedures (height of the ductility test). A microstructure analysis was also established (EDAX analysis). Based on the experimental data, it is found that the mills can improve flattening test performance by applying various policies. It is proposed that the acceptance criteria in the international specifications related to the test of weld ductility be modified. The reasonable height for measuring weld ductility is usually at two thirds of the specified outside diameter of the pipe.

  12. Dynamic study of milling low depth channels

    Directory of Open Access Journals (Sweden)

    Rosca Dorin Mircea

    2017-01-01

    Full Text Available This paper presents a study of dynamic aspects of the milling cutters used in particular case of low depth channels. A new calculation method was developed, taking into account the high variations of cutting forces during milling small depth channels with peripheral cutting tools. A new formula was established for the minimal value of channel depth that allows cutting process to be performed in conditions of dynamic stability.

  13. Mills' ratio: Reciprocal concavity and functional inequalities

    CERN Document Server

    Baricz, Árpád

    2010-01-01

    This note contains suficient conditions for the probability density function of an arbitrary continuous univariate distribution such that the corresponding Mills ratio to be reciprocally convex (concave). To illustrate the applications of the main results, the Mills ratio of some common continuous univariate distributions, like gamma, log-normal and Student's t distributions, are discussed in details. The application to monopoly theory is also summarized.

  14. The microbiology of olive mill wastes.

    Science.gov (United States)

    Ntougias, Spyridon; Bourtzis, Kostas; Tsiamis, George

    2013-01-01

    Olive mill wastes (OMWs) are high-strength organic effluents, which upon disposal can degrade soil and water quality, negatively affecting aquatic and terrestrial ecosystems. The main purpose of this review paper is to provide an up-to-date knowledge concerning the microbial communities identified over the past 20 years in olive mill wastes using both culture-dependent and independent approaches. A database survey of 16S rRNA gene sequences (585 records in total) obtained from olive mill waste environments revealed the dominance of members of Alphaproteobacteria, Betaproteobacteria, Gammaproteobacteria, Firmicutes, and Actinobacteria. Independent studies confirmed that OMW microbial communities' structure is cultivar dependent. On the other hand, the detection of fecal bacteria and other potential human pathogens in OMWs is of major concern and deserves further examination. Despite the fact that the degradation and detoxification of the olive mill wastes have been mostly investigated through the application of known bacterial and fungal species originated from other environmental sources, the biotechnological potential of indigenous microbiota should be further exploited in respect to olive mill waste bioremediation and inactivation of plant and human pathogens. The implementation of omic and metagenomic approaches will further elucidate disposal issues of olive mill wastes.

  15. The influence of milling-burnishing successive and simultaneous processes on the material hardness

    Science.gov (United States)

    Grigoraş, C. C.; Brabie, G.; Chirita, B.

    2016-08-01

    Recent developments in the field of bio-engineering allow the use of magnesium alloys as a substitute for medical implants. The issue with such alloys is the degradation rate witch has to be improved in order to provide the necessary support for the entire duration of the bone fraction healing. For improving the bone shielding heat treatment does not represent a solution, but chemical and/or mechanical do. One mechanical process that has excellent result is burnishing, but this process is difficult to be implemented on a milling machine. Therefore, it was necessary that a new tool and tool holder to be developed, that allow the simultaneous process to take place. A high-pressure hydraulic roller burnishing tool with a special tool holder was used on a CNC milling machine. The material used for this study is magnesium alloy AZ31B-F, and one of the main purposes was to improve the material hardness (HV). The milling-burnishing parameters that where varied are the speed and feed, burnishing pressure and depth, type of process (successive or simultaneous), machining direction and the material hardness after milling. The results were analyzed as percentage improvement between the milling and burnishing measured values.

  16. The Relationship Between Organic Loading and Effects on Fish Reproduction for Pulp Mill Effluents Across Canada.

    Science.gov (United States)

    Martel, Pierre H; O'Connor, Brian I; Kovacs, Tibor G; Van Den Heuvel, Michael R; Parrott, Joanne L; McMaster, Mark E; MacLatchy, Deborah L; Van Der Kraak, Glen J; Hewitt, L Mark

    2017-02-21

    This study builds upon the work of a multiagency consortium tasked with determining cost effective solutions for the effects of pulp mill effluents on fish reproduction. A laboratory fathead minnow egg production test and chemical characterization tools were used to benchmark eighty-one effluents from twenty mills across Canada, representing the major pulping, bleaching and effluent treatment technologies. For Kraft and mechanical pulp mills, effluents containing less than 20 mg/L BOD5 were found to have the greatest probability of having no effects. Organic loading, expressed as the total detected solvent-extractable components by gas chromatography/mass spectrometry (GC/MS), also correlate with decreased egg laying. Exceptions were found for specific Kraft, mechanical and sulfite mills, suggesting yet unidentified, causative agents are involved. Recycled fibre mill effluents, tested for the first time, were found to have little potential for reproductive effects despite large variations in BOD5 and the GC/MS profiles. Effluent treatment systems across all production types were generally efficient, achieving a combined 82-98 % BOD5 removal. Further reductions of final effluent organic loadings towards the target of less than 20 mg/L are recommended and can be realized through biotreatment optimization, the reduction of organic losses associated with production upsets and selecting best available technologies that reduce organic loadings to biotreatment.

  17. Olive mill wastewater treatment in single-chamber air-cathode microbial fuel cells.

    Science.gov (United States)

    Bermek, Hakan; Catal, Tunc; Akan, S Süha; Ulutaş, Mehmet Sefa; Kumru, Mert; Özgüven, Mine; Liu, Hong; Özçelik, Beraat; Akarsubaşı, Alper Tunga

    2014-04-01

    Olive mill wastewaters create significant environmental issues in olive-processing countries. One of the most hazardous groups of pollutants in these wastewaters is phenolic compounds. Here, olive mill wastewater was used as substrate and treated in single-chamber air-cathode microbial fuel cells. Olive mill wastewater yielded a maximum voltage of 381 mV on an external resistance of 1 kΩ. Notable decreases in the contents of 3,4-dihydroxybenzoic acid, tyrosol, gallic acid and p-coumaric acid were detected. Chemical oxygen demand removal rates were 65 % while removal of total phenolics by the process was lower (49 %). Microbial community analysis during the olive mill wastewater treating MFC has shown that both exoelectrogenic and phenol-degrading microorganisms have been enriched during the operation. Brevundimonas-, Sphingomonas- and Novosphingobium-related phylotypes were enriched on the anode biofilm, while Alphaproteobacteria and Bacteriodetes dominated the cathode biofilm. As one of the novel studies, it has been demonstrated that recalcitrant olive mill wastewaters could be treated and utilized for power generation in microbial fuel cells.

  18. DECOLORIZATION OF PROCESS WATERS IN DEINKING MILLS AND SIMILAR APPLICATIONS: A REVIEW

    Directory of Open Access Journals (Sweden)

    Patrick Huber,

    2012-01-01

    Full Text Available Process waters in deinking mills often feature a strong coloration, due to dyes and pigments released from the recovered paper. This can usually be remediated by pulp bleaching treatment with appropriate chemicals. However, the red shade (from rhodamine dye is resistant to conventional bleaching treatments. This largely limits the use of deinked pulp in white paper grades. In this review, the available technologies for process water decolorization are discussed (chemical methods, physico-chemical methods and biological treatments. Ozonation of the process water appears to be the most promising technique for decolorization of process water in deinking mills. Other emerging technologies such as photo-catalytic treatment or mineralization by white-rot fungi (after adsorption on low-cost agricultural residues should be considered as well.

  19. 制造无胶纤维板过程中木纤维形态特征及化学特性1)--以酸性蒸气蒸煮热磨制造方法为例%Morphological Characteristics and Chemical Properties of Wood Fiber in th e Binderless Fiberboard during the Manufacture Process with the Acidic Steam Steaming Hot Mill Method

    Institute of Scientific and Technical Information of China (English)

    金春德; 李景鹏; 杨巍; 王喆; 韩申杰

    2014-01-01

    以杨木木片、按常规中密度纤维板生产方法热磨得到的杨木纤维、经酸性蒸气蒸煮热磨得到的杨木纤维、酸性蒸气蒸煮热磨法制造的无胶纤维板为原料,用扫描电镜(SEM)、X射线衍射(XRD)、傅里叶变换红外吸收光谱( FTIR),对酸性蒸气蒸煮热磨法制造无胶纤维板过程中不同阶段的木纤维的形态特征变化、结晶特性和化学组分进行表征分析,并进一步对不同阶段木纤维细胞壁各组分的化学变化进行测量分析。结果表明:热磨过程中木纤维表面光滑,酸化热磨纤维表面凸凹不平,增加了纤维间的啮合,有利于纤维板的成型,无胶纤维板中木纤维相互呈网状交联结构。整个处理过程并未改变木纤维的晶型结构,其晶型结构仍为天然纤维素Ⅰ型结构。FITR分析表明:杨木木片在酸性蒸气蒸煮热磨过程中,木纤维的木质素发生降解,各纤维间经羟基缔合形成了氢键,有利于纤维间自胶胶合成板。化学测试分析结构,进一步证实了木纤维在酸化热磨过程中木质素和游离糠醛质量分数增加,均有益于纤维间胶合。%The experiment was conducted to study the morphological characteristics and chemical properties of the binderless fi-berboard used wood fiber during the manufacture process by the acidic steam steaming hot mill method, with the poplar wooden chips, the fiber stemmed from the conventional method of medium density fiberboard, the poplar fiber with acidifi-cation and the binderless fiberboard making through acidic steam steaming hot mill method.By scanning electron microsco-py(SEM), X-ray powder diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), the experiment was conducted to characterize the morphological characteristics , crystallization properties and chemical composition of the wood fiber at the different stages in the course of the manufacture process of the

  20. Recent Developments with Degree Mills: Accreditation Mills and Counterfeit Diploma and Transcript Operations

    Science.gov (United States)

    Ezell, Allen

    2009-01-01

    This article updates developments regarding Diploma Mills, Accreditation Mills, and Counterfeit Diploma & Transcript operations. It will cover identification & prosecution, to new entities now appearing in these growth industries with annual revenues over one billion dollars. This article will address federal and state laws, a new Federal…

  1. Improving milling and production of a dust-producing unit equipped with hammer mills

    Energy Technology Data Exchange (ETDEWEB)

    Vorotnikov, Ye.G.; Nikiforov, A.A.; Rasputin, O.V.; Sukhunin, V.I.

    1982-01-01

    This paper presents generalized experience for deriving coarse ground coal dust in hammer mills by providing comparison data on improving efficiency of operation of the unit when switching to a coarser-type grind of the fuel. Need to have more precise formulas to calculate grinding potential of hammer mills when using a coarser grind is shown.

  2. Reducing the Environmental Impact of Olive Mill Wastewater

    Directory of Open Access Journals (Sweden)

    Awni Khatib

    2009-01-01

    Full Text Available Problem Statement: A research was needed to monitor the environmental impact of olive mill wastewater (OMW: production and relative production of olive mill waste. This was achieved by collecting data from 92 local olive mills in order to study the olive production yield, water consumption in olive washing and in oil recovery, wastewater generation relative to olive processed and oil generated, and solid waste generation. The OMW is usually discharged in the open environment, thus producing pollution to the soil surface and underground water. Approach: The progress on this problem is made by reducing the chemical oxygen demand (COD as a major OMW pollutant. An upper flow anaerobic sludge bed (UASB facility was constructed and operated for eight months in a progressive program operation for standardization and optimization purpose, and so to treat the waste by COD reduction. Results: The results reveal local variation in most of the investigated parameters. The olives in some area are found to contain large solid waste than other areas, resulting in lower oil yield and higher solid generation per ton of olive produced. The COD concentration was increased gradually from 5,000-30,000 mg/L and the efficiency improved significantly during the operation from 46%-84% COD removal. The organic load of OMW 27,000mg/L was reduce below 5,000 mg/L, that permits its direct discharge into municipal wastewater treatment plants. Conclusion: The implications and relevance of the results imply that OMW must be treated before discharge to the sewer system. On the other hand, the nonconformity between areas must be taken into consideration for future work.

  3. Efeito da adubação e do uso de nematicida na composição química da palma forrageira (Opuntia ficus indica Mill Fertilization and nematicide effects on the chemical composition of cactus forage cv. "Gigante"

    Directory of Open Access Journals (Sweden)

    Margareth Maria Teles

    2004-12-01

    Full Text Available O experimento foi realizado em casa de vegetação do Departamento de Zootecnia da UFRPE, com o objetivo de avaliar o efeito da adubação e de nematicida na composição da palma forrageira cv. gigante, com sintoma de amarelecimento. Para o plantio utilizaram-se cladódios de cor amarela de palma (Opuntia ficus indica, Mill. Cv. Gigante provenientes da Estação Experimental de Caruaru - IPA, onde foi observado o amarelecimento das plantas. Os tratamentos constaram da presença e ausência de macronutrientes, micronutrientes e de nematicida, em delineamento experimental de blocos ao acaso, com quatro repetições. Não foram observadas diferenças significativas entre os tratamentos para teores de matéria seca, de K, de Ca e de Mg. Para teores de N, de P e de S, a análise de variância revelou diferença significativa. A média geral para teores de MS, N, P, K, Ca, Mg e S foi de 7,29; 1,19; 0,17; 3,31; 1,84; 0,59 e 0,17%, respectivamente. A adição de micronutrientes e de nematicida não influenciou os resultados obtidos para teores de N, P, K, Ca, Mg e S. Os teores de nitrogênio, fósforo e potássio foram superiores nos cladódios mais jovens da planta. Os nutrientes nitrogênio, fósforo e enxofre foram os únicos que influenciaram a composição química.This experiment was carried out in a greenhouse at the Animal Science Department/UFRPE and aimed to evaluate the fertilization and nematicide effects on the chemical composition of cactus forage cv. "Gigante" suffering chlorotic symptoms. Chlorotic cladodes of Cactus forage cv. "Gigante" were used as planting material and they were collected at the Caruaru Experimental Station/IPA in the same location where those symptoms were previously observed. The treatments tested the presence or absence of macronutrients, micronutrients, and nematicide. A completely randomized block design was used and the treatments were replicated four times. No significant differences were found for dry matter

  4. Optimization of FIB milling for rapid NEMS prototyping

    DEFF Research Database (Denmark)

    Malm, Bjarke; Petersen, Dirch Hjorth; Lei, Anders;

    2011-01-01

    We demonstrate an optimized milling technique to focused ion beam (FIB) milling in template silicon membranes for fast prototyping of nanoelectromechanical systems (NEMS). Using a single-pass milling strategy the highly topology dependent sputtering rate is boosted and shorter milling time...... is achieved. Drift independence is obtained for small critical features using a radial scan strategy, and a back scan routine ensures minimal line width deviation removing redeposited material. Milling a design similar to a nano four-point probe with a pitch down to 400nm we display what optimized FIB milling...

  5. Practitioner Profile: An Interview With Amanda Mills

    Directory of Open Access Journals (Sweden)

    Amanda Mills

    2012-01-01

    Full Text Available For more than 25 years, Amanda Mills has been working with arts organizations across Canada and with artists of all kinds to assist them in achieving financial sanity. She has taught business management at the University of Victoria and has prepared thousands of tax returns for writers, visual artists, choreographers, actors, filmmakers, broadcasters, and creative entrepreneurs. Ten years ago, bringing together her work on trauma, with twenty years of business management, Mills founded Loose Change Financial Therapy – the place where money and feelings meet. Mills has presented Loose Change workshops for social workers, teachers, psychotherapists, artists, anti-poverty activists, sex trade workers, women’s groups, and the general public.  She has been a guest on major Canadian radio and television broadcasts and profiled in many major Canadian newspapers and periodicals. Mills is also a crisis counselor and co-wrote a bestselling book on recovering from trauma. A tax professional and business manager, she is certified as a financial counselor under the Bankruptcy and Insolvency Act. Mills is also currently completing a certificate in mediation.

  6. The possibility of palm oil mill effluent for biogas production

    Directory of Open Access Journals (Sweden)

    EDWI MAHAJOENO

    2008-01-01

    Full Text Available The world currently obtains its energy from the fossil fuels such as oil, natural gas and coal. However, the international crisis in the Middle East, rapid depletion of fossil fuel reserves as well as climate change have driven the world towards renewable energy sources which are abundant, untapped and environmentally friendly. Indonesia has abundant biomass resources generated from the agricultural industry particularly the large commodity, palm oil (Elaeis guiinensis Jacq.. The aims of the research were to (i characterize palm oil mill effluent which will be used as source of biogas production, (ii know the biotic and abiotic factors which effect POME substrate for biogas production by anaerobic digestion in bulk system. The results show that POME sludge generated from PT Pinago Utama mill is viscous, brown or grey and has an average total solid (TS content of, 26.5-45.4, BOD is 23.5-29.3, COD is 49.0-63.6 and SS is 17.1-35.9 g/L, respectively. This substrate is a potential source of environmental pollutants. The biotic factors were kind and concentration of the inoculums, i.e. seed sludge of anaerobic lagoon II and 20% (w/v respectively. Both physical and chemical factors such as pre-treated POME pH, pH neutralizer matter Ca (OH2, temperature ≥40oC, agitation effect to increase biogas production, but in both coagulant concentration, FeCl2 were not.

  7. PbSe nanocubes obtained by high-energy milling

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: hrojasc@ipn.mx [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada - IPN (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM (Mexico); Achimovicova, M. [Slovak Academy of Sciences, Institute of Geotechnics (Slovakia); Daneu, N. [Jozef Stefan Institute, Department for Nanostructured Materials (Slovenia); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN (Mexico)

    2012-06-15

    In this study, PbSe nanocubes were obtained by high-energy milling, and their optical properties were investigated by measuring the UV-VIS-IR spectra in the range of 200-2,000 nm. The optical absorption of all samples showed a strong UV emission band at 1.45 eV. Previously, to obtain only PbSe nanocubes, an intermediate phase was identified, PbSeO{sub 3}. Although both PbSeO{sub 3} and PbSe were traced through this study, a major effort is devoted to characterize the latter. To trace how chemical transitions evolve from precursors to PbSe, X-ray diffraction and Rietveld refinement were carried out. Therefore, the following parameters were evaluated as a function of milling time: phase percentages, area-to-volume ratio, average crystallite dimensions, specific surface area, and morphology changes. To corroborate previous findings, nitrogen adsorption and transmission electron microscopy techniques were used. All the set experimental results unambiguously confirm that crystallites show a cubic morphology, with its average crystallite size distribution being around 24 nm.

  8. The postharvest of mill olives

    Directory of Open Access Journals (Sweden)

    Yousfi, Khaled

    2006-03-01

    Full Text Available The greatest deterioration of olive oil is due to poor handling of the olives during the time between harvesting and processing. Storage of olive fruits is carried out by simple heaping in fruit piles, waiting their processing. These fruits develop all kinds of degenerative processes in a short period of time. Oils obtained from them show characteristics hydrolytic and oxidative deteriorations confirmed by their high acidity values, peroxide value or ultraviolet absorbance at 232 and 270 nm. To avoid this situation, the industry is currently reducing the interval between harvesting and processing, through an increase in milling capacity. However, the equipment necessary for preventing the accumulation of fruit in January would be unnecessary for the rest of the season. In this chapter, refrigeration of the olive fruits, or the use of physical treatments, to allow the processing of unripe fruits, are analysed as possible alternatives.El mayor deterioro del aceite de oliva es debido a la inadecuada manipulación de las aceitunas durante el tiempo que media entre su cosecha y su procesado. El almacenamiento de las aceitunas se lleva acabo mediante el simple amontonamiento del fruto, esperando su procesamiento. Estos frutos desarrollan toda clase de procesos degenerativos en un corto periodo de tiempo. Los aceites obtenidos a partir de estos frutos exhiben deterioros hidrolíticos y oxidativos característicos, confirmados por sus valores altos de acidez, de índice de peróxidos o de absorbancia en la región ultravioleta a 232 y 270 nm. Para evitar esta situación, la industria intenta reducir al máximo el intervalo entre la cosecha y el procesado del fruto, mediante un aumento de la capacidad de molturación. Sin embargo, el equipo necesario para prevenir la acumulación de fruto en Enero no se precisa para el resto de la campaña. En este capítulo, la refrigeración de las aceitunas o el uso de tratamientos físicos, que permiten el procesado

  9. Milling Stability Analysis Based on Chebyshev Segmentation

    Science.gov (United States)

    HUANG, Jianwei; LI, He; HAN, Ping; Wen, Bangchun

    2016-09-01

    Chebyshev segmentation method was used to discretize the time period contained in delay differential equation, then the Newton second-order difference quotient method was used to calculate the cutter motion vector at each time endpoint, and the Floquet theory was used to determine the stability of the milling system after getting the transfer matrix of milling system. Using the above methods, a two degree of freedom milling system stability issues were investigated, and system stability lobe diagrams were got. The results showed that the proposed methods have the following advantages. Firstly, with the same calculation accuracy, the points needed to represent the time period are less by the Chebyshev Segmentation than those of the average segmentation, and the computational efficiency of the Chebyshev Segmentation is higher. Secondly, if the time period is divided into the same parts, the stability lobe diagrams got by Chebyshev segmentation method are more accurate than those of the average segmentation.

  10. Recycling of mill scale in sintering process

    Directory of Open Access Journals (Sweden)

    El-Hussiny N.A.

    2011-01-01

    Full Text Available This investigation deals with the effect of replacing some amount of Baharia high barite iron ore concentrate by mill scale waste which was characterized by high iron oxide content on the parameters of the sintering process., and investigation the effect of different amount of coke breeze added on sintering process parameters when using 5% mill scale waste with 95% iron ore concentrate. The results of this work show that, replacement of iron ore concentrate with mill scale increases the amount of ready made sinter, sinter strength and productivity of the sinter machine and productivity at blast furnace yard. Also, the increase of coke breeze leads to an increase the ready made sinter and productivity of the sintering machine at blast furnace yard. The productivity of the sintering machine after 5% decreased slightly due to the decrease of vertical velocity.

  11. Underground void filling by cemented mill tailings

    Institute of Scientific and Technical Information of China (English)

    Choudhary Bhanwar Singh; Kumar Santosh

    2013-01-01

    Underground mining always create voids. These voids can cause subsidence of surface. So it is always a demand to fill the void in such a manner that the effect of underground mining can be minimized. Void filling using mill tailings especially in metal mining is one of the best techniques. The tailings produced in milling process have traditionally been disposed in tailing ponds creating a waste disposal and environ-mental problems in terms of land degradation, air and water pollution, etc. This disposal practice is more acute in the metal milling industry where the fine grinding, required for value liberation, results in the production of very fine tailings in large percentage. This paper includes discussions on the effectiveness of different paste mixes with varying cement contents in paste backfilling operations. The results revealed that material composition and use of super plasticizer strongly influenced the strength of cemented backfill.

  12. Structural characterization of mechanically milled ZnO: influence of zirconia milling media

    Energy Technology Data Exchange (ETDEWEB)

    Vojisavljevic, K; Sreckovic, T; Brankovic, Z; Brankovic, G [Institute of Multidisciplinary Research, Kneza Viseslava 1, 11030 Belgrade (Serbia); Scepanovic, M; Grujic-Brojcin, M [Center for Solid State Physics and New Materials, Institute of Physics, Pregrevica 118, 11080 Belgrade (Serbia)], E-mail: katarina@cms.bg.ac.yu

    2008-11-26

    Zinc oxide nanoparticles were obtained by milling in a planetary ball mill with a zirconia milling assembly for up to 5 h in air. The samples were characterized by scanning electron microscopy, x-ray diffraction (XRD) and Raman spectroscopy methods. The deviation of the lattice parameters from single crystal values was related to defect creation and increase of strain inside the hexagonal lattice of milled ZnO nanoparticles. The observed redshift and peak broadening of the major first-order Raman modes were ascribed to the formation of intrinsic defects by mechanical milling combined with the effects of phonon confinement in nanosized powders. To investigate the type of intrinsic defects and impurities introduced during milling, it was necessary to analyze both milled and thermally treated ZnO. After thermal treatment, the intensity of the Raman spectra increased and the peak positions reverted to values similar to those in unmilled ZnO powder, pointing to defect annihilation. XRD patterns of sintered samples confirmed the existence of zirconia impurities and the Rietveld analysis revealed a small amount of zirconium introduced in the ZnO crystal lattice on the Zn sites or interstitial sites. The large influence of those impurities on the micro-Raman spectra of thermally treated samples was observed in this study.

  13. Structural characterization of mechanically milled ZnO: influence of zirconia milling media

    Science.gov (United States)

    Vojisavljević, K.; Šćepanović, M.; Srećković, T.; Grujić-Brojčin, M.; Branković, Z.; Branković, G.

    2008-11-01

    Zinc oxide nanoparticles were obtained by milling in a planetary ball mill with a zirconia milling assembly for up to 5 h in air. The samples were characterized by scanning electron microscopy, x-ray diffraction (XRD) and Raman spectroscopy methods. The deviation of the lattice parameters from single crystal values was related to defect creation and increase of strain inside the hexagonal lattice of milled ZnO nanoparticles. The observed redshift and peak broadening of the major first-order Raman modes were ascribed to the formation of intrinsic defects by mechanical milling combined with the effects of phonon confinement in nanosized powders. To investigate the type of intrinsic defects and impurities introduced during milling, it was necessary to analyze both milled and thermally treated ZnO. After thermal treatment, the intensity of the Raman spectra increased and the peak positions reverted to values similar to those in unmilled ZnO powder, pointing to defect annihilation. XRD patterns of sintered samples confirmed the existence of zirconia impurities and the Rietveld analysis revealed a small amount of zirconium introduced in the ZnO crystal lattice on the Zn sites or interstitial sites. The large influence of those impurities on the micro-Raman spectra of thermally treated samples was observed in this study.

  14. Transportation of the MOAB Uranium Mill Tailings to White Mesa Mill by Slurry Pipeline

    Energy Technology Data Exchange (ETDEWEB)

    Hochstein, R. F.; Warner, R.; Wetz, T. V.

    2003-02-26

    The Moab uranium mill tailings pile, located at the former Atlas Minerals Corporation site approximately three miles north of Moab, Utah, is now under the control of the US Department of Energy (''DOE''). The location of the tailings pile adjacent to the Colorado River, and the ongoing contamination of groundwater and seepage of pollutants into the river, have lead to the investigation, as part of the final site remediation program, of alternatives to relocate the tailings to a qualified permanent disposal site. This paper will describe the approach being taken by the team formed between International Uranium (USA) Corporation (''IUC'') and Washington Group International (''WGINT'') to develop an innovative technical proposal to relocate the Moab tailings to IUC's White Mesa Mill south of Blanding, Utah. The proposed approach for relocating the tailings involves using a slurry pipeline to transport the tailings to the White Mesa Mill. The White Mesa Mill is a fully licensed, active uranium mill site that is uniquely suited for permanent disposal of the Moab tailings. The tailings slurry would be dewatered at the White Mesa Mill, the slurry water would be recycled to the Moab site for reuse in slurry makeup, and the ''dry'' tailings would be permanently disposed of in an approved below grade cell at the mill site.

  15. CO2 laser milling of hard tissue

    Science.gov (United States)

    Werner, Martin; Ivanenko, Mikhail; Harbecke, Daniela; Klasing, Manfred; Steigerwald, Hendrik; Hering, Peter

    2007-02-01

    Drilling of bone and tooth tissue belongs to recurrent medical procedures (screw- and pin-bores, bores for implant inserting, trepanation etc.). Small round bores can be in general quickly produced with mechanical drills. Problems arise however by angled drilling, by the necessity to fulfill the drilling without damaging of sensitive soft tissue beneath the bone, or by the attempt to mill precisely noncircular small cavities. We present investigations on laser hard tissue "milling", which can be advantageous for solving these problems. The "milling" is done with a CO2 laser (10.6 μm) with pulse duration of 50 - 100 μs, combined with a PC-controlled galvanic beam scanner and with a fine water-spray, which helps to avoid thermal side-effects. The damaging of underlying soft tissue can be prevented through control of the optical or acoustical ablation signal. The ablation of hard tissue is accompanied with a strong glowing, which is absent during the laser beam action on soft tissue. The acoustic signals from the diverse tissue types exhibit distinct differences in the spectral composition. Also computer image analysis could be a useful tool to control the operation. Laser "milling" of noncircular cavities with 1 - 4 mm width and about 10 mm depth is particularly interesting for dental implantology. In ex-vivo investigations we found conditions for fast laser "milling" of the cavities without thermal damage and with minimal tapering. It included exploration of different filling patterns (concentric rings, crosshatch, parallel lines and their combinations), definition of maximal pulse duration, repetition rate and laser power, optimal position of the spray. The optimized results give evidences for the applicability of the CO2 laser for biologically tolerable "milling" of deep cavities in the hard tissue.

  16. Validation of the Hot Strip Mill Model

    Energy Technology Data Exchange (ETDEWEB)

    Richard Shulkosky; David Rosberg; Jerrud Chapman

    2005-03-30

    The Hot Strip Mill Model (HSMM) is an off-line, PC based software originally developed by the University of British Columbia (UBC) and the National Institute of Standards and Technology (NIST) under the AISI/DOE Advanced Process Control Program. The HSMM was developed to predict the temperatures, deformations, microstructure evolution and mechanical properties of steel strip or plate rolled in a hot mill. INTEG process group inc. undertook the current task of enhancing and validating the technology. With the support of 5 North American steel producers, INTEG process group tested and validated the model using actual operating data from the steel plants and enhanced the model to improve prediction results.

  17. Supermembrane limit of Yang-Mills theory

    CERN Document Server

    Lechtenfeld, Olaf

    2015-01-01

    We consider Yang-Mills theory with $N{=}1$ super translation group in eleven auxiliary dimensions as the structure group. The gauge theory is defined on a direct product manifold $\\Sigma_3\\times S^1$, where $\\Sigma_3$ is a three-dimensional Lorentzian manifold and $S^1$ is a circle. We show that in the infrared limit, when the metric on $S^1$ is scaled down, the Yang-Mills action supplemented by a Wess-Zumino-type term reduces to the action of an M2-brane.

  18. Wollstonecraft, Mill, and Women's Human Rights

    OpenAIRE

    Botting, Eileen Hunt

    2016-01-01

    This book argues that Mary Wollstonecraft and John Stuart Mill are the two primary architects of the modern theory of women’s rights as human rights. It only through addressing women’s rights, Botting argues, that the idea of human rights was given universal scope and application. Botting describes the development of the idea of women’s human rights beginning with the work of Wollstonecraft and Mill, and gives an account of their reception in both western and nonwestern contexts. Her goal is ...

  19. Einstein-Yang-Mills-Lorentz Black Holes

    CERN Document Server

    Cembranos, Jose A R

    2015-01-01

    Different black hole solutions of the coupled Einstein-Yang-Mills equations are well known from long time. They have attracted much attention from mathematicians and physicists from their discovery. In this work, we analyze black holes associated with the gauge Lorentz group. In particular, we study solutions which identify the gauge connection with the spin connection. This ansatz allows to find exact solutions to the complete system of equations. By using this procedure, we show the equivalence between the Yang-Mills-Lorentz model in curved space-time and a particular set of extended gravitational theories.

  20. Prototyping of Dental Structures Using Laser Milling

    Science.gov (United States)

    Andreev, A. O.; Kosenko, M. S.; Petrovskiy, V. N.; Mironov, V. D.

    2016-02-01

    The results of experimental studies of the effect of an ytterbium fiber laser radiation parameters on processing efficiency and quality of ZrO2 ceramics widely used in stomatology are presented. Laser operating conditions with optimum characteristics for obtaining high quality final surfaces and rapid material removal of dental structures are determined. The ability of forming thin-walled ceramic structures by laser milling technology (a minimum wall thickness of 50 μm) is demonstrated. The examples of three-dimensional dental structures created in computer 3D-models of human teeth using laser milling are shown.

  1. Operating System For Numerically Controlled Milling Machine

    Science.gov (United States)

    Ray, R. B.

    1992-01-01

    OPMILL program is operating system for Kearney and Trecker milling machine providing fast easy way to program manufacture of machine parts with IBM-compatible personal computer. Gives machinist "equation plotter" feature, which plots equations that define movements and converts equations to milling-machine-controlling program moving cutter along defined path. System includes tool-manager software handling up to 25 tools and automatically adjusts to account for each tool. Developed on IBM PS/2 computer running DOS 3.3 with 1 MB of random-access memory.

  2. Superiority of wet-milled over dry-milled superfine powdered activated carbon for adsorptive 2-methylisoborneol removal.

    Science.gov (United States)

    Pan, Long; Matsui, Yoshihiko; Matsushita, Taku; Shirasaki, Nobutaka

    2016-10-01

    Superfine powdered activated carbon (SPAC), which is produced from conventionally sized powdered activated carbon (PAC) by wet milling in a bead mill, has attracted attention for its high adsorptive removal ability in both research and practice. In this study, the performance of dry-milled SPAC was investigated. 2-Methylisoborneol (MIB), an earthy-musty compound commonly targeted by water treatment systems, was used as the target adsorbate. Dry-milled SPAC exhibited lower adsorptive removal of MIB than wet-milled SPAC, even when both SPACs were produced from the same PAC and were composed of particles of the same size. One reason for the lower removal of MIB by the dry-milled SPAC was a higher degree of aggregation in the dry-milled SPAC after production; as a result the apparent particle size of dry-milled SPAC was larger than that of wet-milled SPAC. The dry-milled SPAC was also more negatively charged than the wet-milled SPAC, and, owing to its higher repulsion, it was more amenable to dispersion by ultrasonication. However, even after the dry-milled SPAC was ultrasonicated so that its apparent particle size was similar to or less than that of the wet-milled SPAC, the dry-milled SPAC was still inferior in adsorptive removal to the wet-milled SPAC. Therefore, another reason for the lower adsorptive removal of dry-milled SPAC was its lower equilibrium adsorption capacity due to the oxidation during the milling. The adsorption kinetics by SPACs with different degrees of particle aggregation were successfully simulated by a pore diffusion model and a fractal aggregation model.

  3. Investigation of the milling capabilities of the F10 Fine Grind mill using Box-Behnken designs.

    Science.gov (United States)

    Tan, Bernice Mei Jin; Tay, Justin Yong Soon; Wong, Poh Mun; Chan, Lai Wah; Heng, Paul Wan Sia

    2015-01-01

    Size reduction or milling of the active is often the first processing step in the design of a dosage form. The ability of a mill to convert coarse crystals into the target size and size distribution efficiently is highly desirable as the quality of the final pharmaceutical product after processing is often still dependent on the dimensional attributes of its component constituents. The F10 Fine Grind mill is a mechanical impact mill designed to produce unimodal mid-size particles by utilizing a single-pass two-stage size reduction process for fine grinding of raw materials needed in secondary processing. Box-Behnken designs were used to investigate the effects of various mill variables (impeller, blower and feeder speeds and screen aperture size) on the milling of coarse crystals. Response variables included the particle size parameters (D10, D50 and D90), span and milling rate. Milled particles in the size range of 5-200 μm, with D50 ranging from 15 to 60 μm, were produced. The impeller and feeder speeds were the most critical factors influencing the particle size and milling rate, respectively. Size distributions of milled particles were better described by their goodness-of-fit to a log-normal distribution (i.e. unimodality) rather than span. Milled particles with symmetrical unimodal distributions were obtained when the screen aperture size was close to the median diameter of coarse particles employed. The capacity for high throughput milling of particles to a mid-size range, which is intermediate between conventional mechanical impact mills and air jet mills, was demonstrated in the F10 mill. Prediction models from the Box-Behnken designs will aid in providing a better guide to the milling process and milled product characteristics.

  4. The influence of milling on the dissolution performance of simvastatin

    DEFF Research Database (Denmark)

    Zimper, Ulrike; Aaltonen, Jaakko; Krauel-Goellner, Karen

    2012-01-01

    properties such as solubility and dissolution rate and, therefore, process induced solid state modifications need to be monitored. The aim of this study was two-fold: firstly, to investigate the dissolution rates of milled and unmilled simvastatin; and secondly, to screen for the main milling factors...... milling frequency, milling time and ball quantity at a set drug load, out of which milling frequency was found to be the most important factor for particle size as well as process induced disorder. Milling frequency and milling time exhibited an interaction effect on the responses. The optimum milling...... revealed that the process induced disorder was negligible with regard to the dissolution rate. The predicted primary particle size of 1.4 µm could be confirmed experimentally, but due to agglomeration of the primary particles a dissolution rate advantage was not shown, highlighting the importance...

  5. Complete Mill Simulation of the Rolling Process of 1660 mm Hot Strip Continuous Mills

    Institute of Scientific and Technical Information of China (English)

    Yingrui WANG; Zhenshan CUI; Yingjie WANG; Hongmin LIU

    2004-01-01

    The three-dimensional plastic deformations of strip are analyzed using the stream surface strip element method, the elastic deformations of rolls are analyzed using the influence coefficient method, the analyzing and computing model of shape and crown of 4-high mill was established by combining them, and the rolling process of 1660 mm hot strip continuous mills was simulated. The simulated results tally well with the experimental results. The model and the method for simulation of shape analysis and control of hot strip mills were provided.

  6. Preparation of natural pyrite nanoparticles by high energy planetary ball milling as a nanocatalyst for heterogeneous Fenton process

    Energy Technology Data Exchange (ETDEWEB)

    Fathinia, Siavash [Department of Mining Engineering, Faculty of Engineering and Technology, Imam Khomeini International University, Qazvin (Iran, Islamic Republic of); Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of); Fathinia, Mehrangiz [Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of); Rahmani, Ali Akbar [Department of Mining Engineering, Faculty of Engineering and Technology, Imam Khomeini International University, Qazvin (Iran, Islamic Republic of); Khataee, Alireza, E-mail: a_khataee@tabrizu.ac.ir [Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)

    2015-02-01

    Graphical abstract: - Highlights: • Pyrite nanoparticles were successfully produced by planetary ball milling process. • The physical and chemical properties of pyrite nanoparticles were fully examined. • The degradation of AO7 was notably enhanced by pyrite nanoparticles Fenton system. • The influences of basic operational parameters were investigated using CCD. - Abstract: In the present study pyrite nanoparticles were prepared by high energy mechanical ball milling utilizing a planetary ball mill. Various pyrite samples were produced by changing the milling time from 2 h to 6 h, in the constant milling speed of 320 rpm. X-ray diffraction (XRD), scanning electron microscopy (SEM) linked with energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FT-IR) analysis and Brunauer–Emmett–Teller (BET) were performed to explain the characteristics of primary (unmilled) and milled pyrite samples. The average particle size distribution of the produced pyrite during 6 h milling was found to be between 20 nm and 100 nm. The catalytic performance of the different pyrite samples was examined in the heterogeneous Fenton process for degradation of C.I. Acid Orange 7 (AO7) solution. Results showed that the decolorization efficiency of AO7 in the presence of 6 h-milled pyrite sample was the highest. The impact of key parameters on the degradation efficiency of AO7 by pyrite nanoparticles catalyzed Fenton process was modeled using central composite design (CCD). Accordingly, the maximum removal efficiency of 96.30% was achieved at initial AO7 concentration of 16 mg/L, H{sub 2}O{sub 2} concentration of 5 mmol/L, catalyst amount of 0.5 g/L and reaction time of 25 min.

  7. A long-term, multitrophic level study to assess pulp and paper mill effluent effects on aquatic communities in four US receiving waters: characteristics of the study streams, sample sites, mills, and mill effluents.

    Science.gov (United States)

    Hall, Timothy J; Ragsdale, Renee L; Arthurs, William J; Ikoma, Joan; Borton, Dennis L; Cook, Diana L

    2009-04-01

    upstream or downstream of the effluent discharge. In addition, broader watershed differences were evident on Codorus Creek, where a relatively rich riparian corridor and stream structure occurred upstream in contrast to areas of canopy and stream-structure loss in the downstream urban area. The mill effluent discharges contributed to increases in receiving-water color and conductivity, although upstream tributaries contributed additional conductivity to Codorus Creek and color to the Leaf River. The McKenzie River provided the only example of a nutrient increase immediately downstream of a mill discharge. This increase in total nitrogen (0.11 vs 0.16 mg/L) could not, however, be differentiated with respect to whether it was of mill effluent or tributary stream origin. Tributary streams were potentially important total nitrogen contributors on Codorus Creek and the Willamette River. As an integrated study, the effluent quality and physical/chemical watershed descriptions provided here represent 1 component of the broader study addressing potential point-source effluent effects within the context of the larger watershed and a multiyear timescale. The absence of effluent-related in-stream chemical/physical responses, other than increases in conductivity and color, and a considerable bioassay-based margin of safety, provides for a working hypothesis that there will be no effluent-related biological population/community responses from these 4 mill discharges. This hypothesis, as it relates to periphyton, macroinvertebrate, and fish communities, will be addressed in other articles in this series.

  8. The mycotoxin distribution in maize milling fractions under experimental conditions.

    Science.gov (United States)

    Burger, H-M; Shephard, G S; Louw, W; Rheeder, J P; Gelderblom, W C A

    2013-07-01

    Mycotoxin contamination of maize and maize-based food and feed products poses a health risk to humans and animals if not adequately controlled and managed. The current study investigates the effect of dry milling on the reduction of fumonisins (FB), deoxynivalenol (DON) and zearalenone (ZEA) in maize. Five composite samples, constructed to represent different mycotoxin contamination levels were degermed yielding degermed maize and the germ. The degermed maize was milled under laboratory conditions and four major milling fractions (SPECIAL, SUPER, semolina (SEM) and milling hominy feed) collected. The whole maize, degermed maize and total hominy feed (germ+milling hominy feed) were reconstructed to ensure homogenous samples for mycotoxin analyses. For comparison, commercial dry milling fractions (whole maize, SPECIAL, SUPER and total hominy feed), collected from three South African industrial mills, were analysed for the same mycotoxins and hence a more accurate assessment of the distribution between the different milling fractions. The distribution of the mycotoxins during the experimental dry milling of the degermed maize differs, with FB mainly concentrated in the SPECIAL, DON in the SEM whereas ZEA was equally distributed between the two milling fractions. Distribution of mycotoxins between the fractions obtained during commercial dry milling generally provided similar results with the total hominy feed containing the highest and the SUPER milling fractions the lowest mycotoxin levels although variations existed. Although milling is an effective way to reduce mycotoxins in maize, kernel characteristics and resultant fungal colonisation may impact on the distribution of specific mycotoxins among the different milling fractions. Differences in industrial dry milling practices and problems encountered in sampling bulk maize remain a large problem in assessing mycotoxin contamination in milling fractions intended for human consumption.

  9. BIOTECHNOLOGICAL EMPLOYMENT OF OLIVE OIL MILL WASTEWATERS FOR WATER REMEDIATION AND POTENTIAL BIODIESEL PRODUCTION

    OpenAIRE

    Addorisio, Veria

    2010-01-01

    Olive oil mill wastewaters (OMW) are dark-colored wastes characterized by high values of COD (chemical oxygen demand) and BOD (biological oxygen demand). OMW contains high amounts of organic and inorganic compounds. The first category includes mostly sugars, polyphenols, organic acids, proteins, fatty substances, mixed phenol-polysaccharide polymers, polyalcohols, cellulose and hemicellulose, pectins and tannins. The inorganic substance, present in lower amount, includes mainly potassium and,...

  10. 7 CFR 868.301 - Definition of milled rice.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 7 2010-01-01 2010-01-01 false Definition of milled rice. 868.301 Section 868.301... FOR CERTAIN AGRICULTURAL COMMODITIES United States Standards for Milled Rice Terms Defined § 868.301 Definition of milled rice. Whole or broken kernels of rice (Oryza sativa L.) from which the hulls and...

  11. The MediaMill TRECVID 2006 semantic video search engine

    NARCIS (Netherlands)

    Snoek, C.G.M.; Gemert, J.C. van; Gevers, T.; Huurnink, B.; Koelma, D.C.; Liempt, M. van; Rooij, O. de; Sande, K.E.A. van de; Seinstra, F.J.; Smeulders, A.W.M.; Thean, A.H.C.; Veenman, C.J.; Worring, M.

    2006-01-01

    In this paper we describe our TRECVID 2006 experiments. The MediaMill team participated in two tasks: concept detection and search. For concept detection we use the MediaMill Challenge as experimental platform. The MediaMill Challenge divides the generic video indexing problem into a visual-only, te

  12. 46 CFR 50.25-3 - Manufacturer or mill certification.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Manufacturer or mill certification. 50.25-3 Section 50... PROVISIONS Acceptance of Material and Piping Components § 50.25-3 Manufacturer or mill certification. (a) A manufacturer or mill producing materials used in certain products for installation on inspected vessels,...

  13. Focused ion beam milling of photonic crystals in bulk silicon

    NARCIS (Netherlands)

    Hu, Wenbin; Ridder, de René M.; Tong, Xing-Lin

    2009-01-01

    Focused ion beam (FIB) direct milling was used to fabricate photonic crystals in bulk silicon. The milling requires the sidewalls as nearly perpendicular to the slab as possible and the top profile of the holes to be smooth. The re-deposition of milled material exaggerates the hole profiles. The eff

  14. Strip shape control capability of hot wide strip rolling mills

    Institute of Scientific and Technical Information of China (English)

    Renzhong Wang; Quan Yang; Anrui He; Jian Shao; Haitao Bian

    2008-01-01

    The elasticity deformation of rolls was analyzed by means of two-dimensional f'mite element method (FEM) with vari-able thickness. Three typical mills were used as objects for analysis. A thorough study was done on the control capabilities of these mills on the strip shape. Then the strip shape control capabilities of the three mills was compared synthetically.

  15. 7 CFR 58.419 - Curd mill and miscellaneous equipment.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Curd mill and miscellaneous equipment. 58.419 Section... Service 1 Equipment and Utensils § 58.419 Curd mill and miscellaneous equipment. Knives, hand rakes... of the curd mill should be of stainless steel. All pieces of equipment shall be so constructed...

  16. 40 CFR 61.142 - Standard for asbestos mills.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Standard for asbestos mills. 61.142... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.142 Standard for asbestos mills. (a) Each owner or operator of an asbestos mill shall...

  17. Texture formation in iron particles using mechanical milling with graphite as a milling aid

    Directory of Open Access Journals (Sweden)

    S. Motozuka

    2015-09-01

    Full Text Available Crystallographically anisotropic platelet iron particles were successfully prepared using a conventional ball mill with addition of graphite (Gp particles. The morphological and structural changes resulting from the milling were investigated using scanning electron microscopy and X-ray diffraction. The spherical iron particles were plastically deformed into platelet shapes during the milling. Simultaneously, it is suggested that the size of the Gp particles decreased and adhered as nanoparticles on the surface of the iron particles. The adhered Gp particles affected the plastic deformation behavior of the iron particles: the {001} planes of α-iron were oriented parallel to the particle face, and no preferred in-plane orientation was observed. This study not only details the preparation of soft magnetic metal particles that crystallographically oriented to enhance their magnetic properties but also provides new insight into the activities of the well-established and extensively studied mechanical milling method.

  18. Texture formation in iron particles using mechanical milling with graphite as a milling aid

    Energy Technology Data Exchange (ETDEWEB)

    Motozuka, S.; Hayashi, K. [Department of Mechanical Engineering, Gifu National College of Technology, 2236-2 Kamimakuwa, Motosu, Gifu 501-0495 (Japan); Tagaya, M. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Morinaga, M. [Toyota Physical and Chemical Research Institute, 41-1, Yokomichi, Nagakute, Aichi 480-1192 (Japan)

    2015-09-15

    Crystallographically anisotropic platelet iron particles were successfully prepared using a conventional ball mill with addition of graphite (Gp) particles. The morphological and structural changes resulting from the milling were investigated using scanning electron microscopy and X-ray diffraction. The spherical iron particles were plastically deformed into platelet shapes during the milling. Simultaneously, it is suggested that the size of the Gp particles decreased and adhered as nanoparticles on the surface of the iron particles. The adhered Gp particles affected the plastic deformation behavior of the iron particles: the (001) planes of α-iron were oriented parallel to the particle face, and no preferred in-plane orientation was observed. This study not only details the preparation of soft magnetic metal particles that crystallographically oriented to enhance their magnetic properties but also provides new insight into the activities of the well-established and extensively studied mechanical milling method.

  19. Purchases of Degrees from Diploma Mills.

    Science.gov (United States)

    Cramer, Robert J.

    In response to a request from the Permanent Subcommittee on Investigations of the Senate Committee on Governmental Affairs, the General Accounting Office (GAO) investigated issues concerning the proliferation of "diploma mills," which sell bogus academic degrees based on "life experience" or substandard or negligible work.…

  20. Cuttable Ruled Surface Strips for Milling

    DEFF Research Database (Denmark)

    Steenstrup, Kasper Hornbak; Nørbjerg, Toke Bjerge; Søndergaard, Asbjørn;

    2016-01-01

    This paper proposes a novel pre-processing method for industrial robotic CNC-milling. The method targets a hybrid machining process, in which the main bulk of material is removed through robotic hot or abrasive wire cutting, after which regular CNC-machining is employed for removal of the remaini...

  1. Buffalo calves intoxicated with Ageratum houstonianum mill

    Science.gov (United States)

    Ageratum houstonianum Mill, a noxious weed has been reported to contain pyrrolizidine alkaloids, saponins, triterpens and coumarin. It is an invasive weed that is commonly found in the pasturelands of tropical and subtropical regions. The objectives of this work were to verify the toxicity of A. ho...

  2. Rotationally Vibrating Electric-Field Mill

    Science.gov (United States)

    Kirkham, Harold

    2008-01-01

    A proposed instrument for measuring a static electric field would be based partly on a conventional rotating-split-cylinder or rotating-split-sphere electric-field mill. However, the design of the proposed instrument would overcome the difficulty, encountered in conventional rotational field mills, of transferring measurement signals and power via either electrical or fiber-optic rotary couplings that must be aligned and installed in conjunction with rotary bearings. Instead of being made to rotate in one direction at a steady speed as in a conventional rotational field mill, a split-cylinder or split-sphere electrode assembly in the proposed instrument would be set into rotational vibration like that of a metronome. The rotational vibration, synchronized with appropriate rapid electronic switching of electrical connections between electric-current-measuring circuitry and the split-cylinder or split-sphere electrodes, would result in an electrical measurement effect equivalent to that of a conventional rotational field mill. A version of the proposed instrument is described.

  3. Cuttable Ruled Surface Strips for Milling

    DEFF Research Database (Denmark)

    Steenstrup, Kasper Hornbak; Nørbjerg, Toke Bjerge; Søndergaard, Asbjørn;

    2016-01-01

    This paper proposes a novel pre-processing method for industrial robotic CNC-milling. The method targets a hybrid machining process, in which the main bulk of material is removed through robotic hot or abrasive wire cutting, after which regular CNC-machining is employed for removal of the remaining...

  4. Species status of Mill Creek Elliptio

    Energy Technology Data Exchange (ETDEWEB)

    Davis, G.M. [Academy of Natural Sciences (United States); Mulvey, M. [Savannah River Ecology Lab., Aiken, SC (United States)

    1993-12-31

    This report discusses environmental effects of the Savannah River Plant on aqautic populations in Mill Creek and surrounding tributaries. Of particular concern was the status of Elliptio. Genetics and phenotypic characteristics have shown that the current classification system is not adequate for these populations. The appendices characterize genetic variability at different loci, electrophoretic data, allele frequencies, sympatric species, and anatomical characters.

  5. 29 CFR 570.54 - Logging occupations and occupations in the operation of any sawmill, lath mill, shingle mill, or...

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 3 2010-07-01 2010-07-01 false Logging occupations and occupations in the operation of any sawmill, lath mill, shingle mill, or cooperage stock mill (Order 4). 570.54 Section 570.54 Labor Regulations Relating to Labor (Continued) WAGE AND HOUR DIVISION, DEPARTMENT OF LABOR REGULATIONS CHILD LABOR REGULATIONS, ORDERS AND STATEMENTS...

  6. 77 FR 43369 - Alumax Mill Products, Inc. Doing Business as Alcoa Mill Products Texarkana a Subsidiary of Alcoa...

    Science.gov (United States)

    2012-07-24

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF LABOR Employment and Training Administration Alumax Mill Products, Inc. Doing Business as Alcoa Mill Products..., Inc., doing business as Alcoa Mill Products Texarkana, a subsidiary of Alcoa, Inc., Nash, Texas,...

  7. Synthesis of aluminum nitride powders from a plasma-assisted ball milled precursor through carbothermal reaction

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Zhi-jie [Key Lab of Materials Modification (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Dai, Le-yang [Marine Engineering Institute, Jimei University, Xiamen 361021 (China); Yang, De-zheng; Wang, Sen [Key Lab of Materials Modification (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Zhang, Bao-jian [Marine Engineering Institute, Jimei University, Xiamen 361021 (China); Wang, Wen-chun, E-mail: wangwenc@dlut.edu.cn [Key Lab of Materials Modification (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Cheng, Tie-han [Pinggao Group Co. Ltd., State Grid Corporation of China, Pingdingshan 467000 (China)

    2015-01-15

    Highlights: • A novel and high efficiency synthesizing AlN powders method combining mechanical ball milling and DBDP has been developed. • The particle size, the crystallite size, the lattice distortion, the morphology of Al{sub 2}O{sub 3} powders, and the AlN conversion rate are investigated and compared under the ball milled Al{sub 2}O{sub 3} powders with DBDP and without DBDP. • The ball milled Al{sub 2}O{sub 3} powders with DBDP have small spherical structure morphology with very fine particles size and high specific surface area, which result in a higher chemical efficiency and a higher AlN conversion rate at lower thermal temperature. - Abstract: In this paper, aluminum nitride (AlN) powers have been produced with a novel and high efficiency method by thermal annealing at 1100–1600 °C of alumina (Al{sub 2}O{sub 3}) powders which were previously ball milled for various time up to 40 h with and without the assistant of dielectric barrier discharge plasma (DBDP). The ball milled Al{sub 2}O{sub 3} powders with DBDP and without DBDP and the corresponding synthesized AlN powers are characterized by X-ray diffraction, scanning electron microscope, and transmission electron microscopy. From the characteristics of the ball milled Al{sub 2}O{sub 3} powders with DBDP and without DBDP, it can be seen that the ball milled Al{sub 2}O{sub 3} powders with DBDP have small spherical structure morphology with very fine particles size and high specific surface area, which result in a higher chemical efficiency and a higher AlN conversion rate at lower thermal temperature. Meanwhile, the synthesized AlN powders can be known as hexagonal AlN with fine crystal morphology and irregular lump-like structure, and have uniform distribution with the average particle size of about between 500 nm and 1000 nm. This provides an important method for fabricating ultra fine powders and synthesizing nitrogen compounds.

  8. Isolation of uranium mill tailings and their component radionuclides from the biosphere; some earth science perspectives

    Science.gov (United States)

    Landa, Edward

    1980-01-01

    Uranium mining and milling is an expanding activity in the. Western United States. Although the milling process yields a uranium concentrate, the large volume of tailings remaining contains about 85 percent of the radioactivity originally associated with the ore. By virtue of the physical and chemical processing of the ore and the redistribution of the contained radionuclides at the Earth's surface, these tailings constitute a technologically enhanced source of natural radiation exposure. Sources of potential human radiation exposure from uranium mill tailings include the emanation of radon gas, the transport of particles by wind and water, and the transport of soluble radionuclides, seeping from disposal areas, by ground water. Due to the 77,000 year half-life of thorium-230, the parent of radium-226, the environmental effects associated with radionuclides contained in these railings must be conceived of within the framework of geologic processes operating over geologic time. The magnitude of erosion of cover materials and tailings and the extent of geochemical mobilization of the contained radionuclides to the atmosphere and hydrosphere should be considered in the evaluation of the potential, long-term consequences of all proposed uranium mill tailings management plans.

  9. National design environment for pulp mills; Kansallinen paperitehtaan suunnitteluympaeristoe - PMST 03

    Energy Technology Data Exchange (ETDEWEB)

    Kaijaluoto, S. [VTT Energy, Jyvaeskylae (Finland)

    1998-12-31

    The research to be done in the CACTUS research programme produces new process models and generates new knowledge about the influence of various contaminants on the runnability and the quality of paper. The generated information calls for an environment where it can be analysed and utilised. The goal of the project is to build a design environment for papermaking processes. The environment will be composed of a number of tools, all integrated together, that can be used in process design from preliminary concept screening through detailed simulation studies to the design and tuning of control systems. The design environment is based on the Balas and APMS simulation programmes developed at VTT. Balas is a general steady-state simulation package for chemical processes with emphasis on pulp and paper. Recent applications include the analysis of the influence of new drying techniques on the energy and water management of a paper mill and the evaluation of new paper machine and water treatment concepts. APMS (Advanced Pulp and Paper Mill Simulator) is a new flexible tool intended for fast modelling and efficient simulation of the dynamic performance the various unit processes in pulp and paper mill, or even of the whole integrated mill. (orig.)

  10. In-situ grouting of uranium-mill-tailings piles: an assessment

    Energy Technology Data Exchange (ETDEWEB)

    Tamura, T.; Boegly, W.J. Jr.

    1983-05-01

    Passage in 1978 of the Uranium Mill Tailings Radiation Control Act (UMTRCA) initiated a program of remedial action for 22 existing mill tailings piles generated in the period 1940 to 1970 as part of the nation's defense and nuclear power programs. The presence of these piles poses potential health and environmental contamination concerns. Possible remedial actions proposed include multilayer covers over the piles to reduce water infiltration, reduce radon gas releases, and reduce airborne transport of tailings fines. In addition, suggested remedial actions include (1) the use of liners to prevent groundwater contamination by leachates from the piles and (2) chemical stabilization of the tailings to retain the radioactive and nonradioactive sources of contamination. Lining of the piles would normally be applicable only to piles that are to be moved from their present location such that the liner could be placed between the tailings and the groundwater. However, by using civil engineering techniques developed for grouting rocks and soils for strength and water control, it may be possible to produce an in situ liner for piles that are not to be relocated. The Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project Office requested that ORNL assess the potential application of grouting as a remedial action. This report examines the types of grouts, the equipment available, and the costs, and assesses the possibility of applying grouting technology as a remedial action alternative for uranium mill tailings piles.

  11. Development of hemicelluloses biorefineries for integration into kraft pulp mills

    Science.gov (United States)

    Ajao, Olumoye Abiodun

    The development and wide spread acceptance of production facilities for biofuels, biochemicals and biomaterials is an important condition for reducing reliance on limited fossil resources and transitioning towards a global biobased economy. Pulp and paper mills in North America are confronted with high energy prices, high production costs and intense competition from emerging economies and low demand for traditional products. Integrated forest biorefineries (IFBR) have been proposed as a mean to diversify their product streams, increase their revenue and become more sustainable. This is feasible because they have access to forest biomass, an established feedstock supply chain and wood processing experience. In addition, the integration of a biorefinery process that can share existing infrastructure and utilities on the site of pulp mill would significantly lower investment cost and associated risks. Kraft pulping mills are promising receptor processes for a biorefinery because they either possess a prehydrolysis step for extracting hemicelluloses sugars prior to wood pulping or it can be added by retrofit. The extracted hemicelluloses could be subsequently transformed into a wide range of value added products for the receptor mill. To successfully implement hemicelluloses biorefinery, novel processes that are technically and economically feasible are required. It is necessary to identify products that would be profitable, develop processes that are energy efficient and the receptor mill should be able to supply the energy, chemicals and material demands of the biorefinery unit. The objective of this thesis is to develop energy efficient and economically viable hemicelluloses biorefineries for integration into a Kraft pulping process. A dissolving pulp mill was the reference case study. The transformation of hemicellulosic sugars via a chemical and biochemical conversion pathway, with furfural and ethanol as representative products for each pathway was studied. In

  12. Vibrations in High Speed Milling of Thin-walled Components

    Institute of Scientific and Technical Information of China (English)

    WANG Tongyue; HE Ning; LI Liang

    2006-01-01

    Thin-walled structures have been widely used in the aerospace industry. The dynamic interaction between the milling cutter and thin-walled workpiece can easily lead to vibration. This paper investigates the vibration caused during milling the thin-walled workpiece on the NC machining center, presents a theoretical milling vibration model of thin-walled beam. The model was verified by using milling experiments and numerical simulations. Some valuable conclusions are derived, this will be references to scientific research and guides to the vibration-free milling of thin-walled structures at different cutting speeds.

  13. Exposure to paper mill effluent at a site in North Central Florida elicits molecular-level changes in gene expression indicative of progesterone and androgen exposure.

    Science.gov (United States)

    Brockmeier, Erica K; Jayasinghe, B Sumith; Pine, William E; Wilkinson, Krystan A; Denslow, Nancy D

    2014-01-01

    Endocrine disrupting compounds (EDCs) are chemicals that negatively impact endocrine system function, with effluent from paper mills one example of this class of chemicals. In Florida, female Eastern mosquitofish (Gambusia holbrooki) have been observed with male secondary sexual characteristics at three paper mill-impacted sites, indicative of EDC exposure, and are still found at one site on the Fenholloway River. The potential impacts that paper mill effluent exposure has on the G. holbrooki endocrine system and the stream ecosystem are unknown. The objective of this study was to use gene expression analysis to determine if exposure to an androgen receptor agonist was occurring and to couple this analysis with in vitro assays to evaluate the presence of androgen and progesterone receptor active chemicals in the Fenholloway River. Focused gene expression analyses of masculinized G. holbrooki from downstream of the Fenholloway River paper mill were indicative of androgen exposure, while genes related to reproduction indicated potential progesterone exposure. Hepatic microarray analysis revealed an increase in the expression of metabolic genes in Fenholloway River fish, with similarities in genes and biological processes compared to G. holbrooki exposed to androgens. Water samples collected downstream of the paper mill and at a reference site indicated that progesterone and androgen receptor active chemicals were present at both sites, which corroborates previous chemical analyses. Results indicate that G. holbrooki downstream of the Fenholloway River paper mill are impacted by a mixture of both androgens and progesterones. This research provides data on the mechanisms of how paper mill effluents in Florida are acting as endocrine disruptors.

  14. Performance test of single step continuous dry attrition mill

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young Woo; Joung, C. Y.; Lee, Y. W.; Na, S. H.; Kim, H. S.; Kim, S

    2001-02-01

    This report describes the improvement of the two-step attrition mill to solve problems associated with its complexity and those of batch type attrition mill as well as the results of the performance test in view of the comparison. In the performance test of the improved single step continuous attrition mill, powder milling and discharge time per pass was systematically measured, and UO{sup 2}-5wt%CeO{sub 2} powder mixture, UO{sup 2}-5wt%CeO{sub 2} powder mixture with poreformer, M{sub 3}O{sub 8} powder and/or MO2 scrap were milled to compare the performance of the milling operations between the 2-step attrition mill and improved single-step attrition mill. The results of the performance test shows, in addition to its improved milling operation, an improved function in less contamination with impurities, simpler handling with easier operation and maintenance and hence, less contamination of operational location, especially when used for the operation in a confinement system, for the improved single step attrition mill compared with a batch type or continuous 2-step attrition mill.

  15. Chatter Prediction for Variable Pitch and Variable Helix Milling

    Directory of Open Access Journals (Sweden)

    Yong Wang

    2015-01-01

    Full Text Available Regenerative chatter is a self-excited vibration that can occur during milling, which shortens the lifetime of the tool and results in unacceptable surface quality. In this paper, an improved semidiscretization method for modeling and simulation with variable pitch and variable helix milling is proposed. Because the delay between each flute varies along the axial depth of the tool in milling, the cutting tool is discrete into some axial layers to simplify calculation. A comparison of the predicted and observed performance of variable pitch and variable helix against uniform pitch and uniform helix milling is presented. It is shown that variable pitch and variable helix milling can obtain larger stable cutting area than uniform pitch and uniform helix milling. Thus, it is concluded that variable pitch and variable helix milling are an effective way for suppressing chatter.

  16. Effect of the Milling Time of the Precursors on the Physical Properties of Sprayed Aluminum-Doped Zinc Oxide (ZnO:Al Thin Films

    Directory of Open Access Journals (Sweden)

    María De La Luz Olvera

    2012-08-01

    Full Text Available Aluminum doped zinc oxide (ZnO:Al thin films were deposited on soda-lime glass substrates by the chemical spray technique. The atomization of the solution was carried out by ultrasonic excitation. Six different starting solutions from both unmilled and milled Zn and Al precursors, dissolved in a mix of methanol and acetic acid, were prepared. The milling process was carried out using a planetary ball mill at a speed of 300 rpm, and different milling times, namely, 15, 25, 35, 45, and 60 min. Molar concentration, [Al]/[Zn] atomic ratio, deposition temperature and time, were kept at constant values; 0.2 M, 3 at.%, 475 °C, and 10 min, respectively. Results show that, under the same deposition conditions, electrical resistivities of ZnO:Al thin films deposited from milled precursors are lower than those obtained for films deposited from unmilled precursors. X-ray diffraction analysis revealed that all films display a polycrystalline structure, fitting well with the hexagonal wurtzite structure. Changes in surface morphology were observed by scanning electron microscopy (SEM as well, since films deposited from unmilled precursors show triangular shaped grains, in contrast to films deposited from 15 and 35 min milled precursors that display thin slices with hexagonal shapes. The use of milled precursors to prepare starting solutions for depositing ZnO:Al thin films by ultrasonic pyrolysis influences their physical properties.

  17. Understanding dental CAD/CAM for restorations - dental milling machines from a mechanical engineering viewpoint. Part A: chairside milling machines.

    Science.gov (United States)

    Lebon, Nicolas; Tapie, Laurent; Duret, Francois; Attal, Jean-Pierre

    2016-01-01

    The dental milling machine is an important device in the dental CAD/CAM chain. Nowadays, dental numerical controlled (NC) milling machines are available for dental surgeries (chairside solution). This article provides a mechanical engineering approach to NC milling machines to help dentists understand the involvement of technology in digital dentistry practice. First, some technical concepts and definitions associated with NC milling machines are described from a mechanical engineering viewpoint. The technical and economic criteria of four chairside dental NC milling machines that are available on the market are then described. The technical criteria are focused on the capacities of the embedded technologies of these milling machines to mill both prosthetic materials and types of shape restorations. The economic criteria are focused on investment costs and interoperability with third-party software. The clinical relevance of the technology is assessed in terms of the accuracy and integrity of the restoration.

  18. Beneficial uses of paper mill residuals for New York State`s recycled-paper mills. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This report evaluates the New York paper mill industry in terms of the productive management and treatment of solid wastes. It identifies current efforts by recycling mills to beneficially use paper mill residuals (often called sludge) and suggests additional options that should be considered by the industry in general and individual mills in particular. It also examines the regulations and economics affecting the mills and suggests actions that could improve the industry`s ability to convert wastes to value-added products. The report recommends that the mills should continue measures to reduce fiber and filler clay losses, promote the transfer of usable fiber and clay to mills able to use them, upgrade sludge dewatering capabilities, and take a more regional approach to solid waste disposal problems. State agencies are urged to support these efforts, encourage the development and commercialization of new beneficial use technologies, and reduce regulatory barriers whenever possible.

  19. Development of a novel ophthalmic ciclosporin A-loaded nanosuspension using top-down media milling methods.

    Science.gov (United States)

    Kim, Jeong Hoon; Jang, Sun Woo; Han, Sang Dug; Hwang, Hyung Don; Choi, Han-Gon

    2011-07-01

    To develop a novel ciclosporin A (CsA)-loaded nanosuspension causing less ocular irritation, a range of nanosuspensions was prepared with various polymers using a media milling method. The effects of polymer, milling time, milling speed and bead material on the particle size of the nanosuspension were investigated. Stability and irritation tests in rabbits' eyes were then performed comparing the nanosuspension with a commercial product. Of the nanosuspensions prepared with various polymers, that with PVA showed no creaming or sedimentation phenomena and gave the smallest particles of about 530 nm. The particle size decreased abruptly as the milling time increased to 2 h and then hardly decreased further. As the milling speed was increased, the particle size of CsA in the nanosuspension also increased. Nanosuspensions prepared with zirconia beads gave significantly finer particles than those with polystyrene beads. In particular, the CsA-loaded nanosuspension with a CsA/PVA/water weight ratio of 0.5/1/100 prepared using the top-down media milling method with zirconia beads of 300 microm diameter at 1000 rpm for 2 h gave a minimum particle size of about 530 nm. This nansuspension was physcally and chemically stable for at least two months. In the Draize test, both this nanosuspension and the commercial product gave very slight ocular irritation. However, in the Schirmer tear test, this nanosuspension caused less irritation to the rabbits' eyes compared to the commercial product. Thus, the CsA-loaded nanosuspension prepared with PVA and water using the top-down media milling method could be a promising candidate for causing less ocular irritation.

  20. Biomanagement of paper mill sludge using an indegenous (Lampito mauritii) and two exotic (Eudrilus eugineae and Eisenia foetida) earthworms.

    Science.gov (United States)

    Banu, J R; Logakanthi, S; Vijayalakshmi, G S

    2001-07-01

    Paper mills have severe problem in disposing effluent or semisolid sludge despite repeated recycling. It requires treatment prior to disposal of sludge. In recent years biological treatment methods received much attention and considered as efficient low-cost treatment. One such method is vermiculture treatment. The present study was carried out to dispose the paper mill sludge biologically using 2 exotic species (Eudrilus eugineae and Eiseniafoetida) and an indigenous species (Lampito mauritii) of earthworm. The paper mill sludge in various concentration 25%,50% and 75% were subjected to vermitub treatment for a period of 60 days. During the period of study data were collected on reproductive strategies of earthworm and chemical analysis of wastes before and after treatment. Results obtained indicate that 25% concentration of sludge was ideal and of the three worms used Eiseniafoetida proved to be the best worm for biomanagement.

  1. Effect of technological parameters and wood properties on cutting power in plane milling of juvenile poplar wood

    Directory of Open Access Journals (Sweden)

    Barcík Štefan

    2008-10-01

    Full Text Available This paper presents the results of experimental measurements aimed at observing the effect of technological parameters (cutting speed vc and feed speed vf , type of wood (juvenile wood and mature wood andwood species (aspen Populus tremula, L. and hybrid poplar Populus x Euramericana „Serotina“ on cutting power during plane milling of poplar wood. The results showed the reduction of cutting power with the decrease of cutting speed and feed speed. Lower cutting power was also measured in milling hybrid poplar than in milling aspen. The test also confirmed the effect of different anatomical and chemical structure of juvenile wood in relation to mature wood on different physical and mechanical properties of such wood and hence also on the cutting power in processing juvenile wood.

  2. Feasibility of vermicomposting dewatered sludge from paper mills using Perionyx excavatus

    Directory of Open Access Journals (Sweden)

    Puspanjali Sonowal

    2013-06-01

    Full Text Available India has a large network of pulp and paper mills of varying capacity. On an industrial scale the sludge from paper and pulp mills is disposed of either as landfill or incinerated. Both methods result in the loss of a valuable resource and have obvious environmental and economic disadvantages. The solid waste from pulp and paper mills is a source of organic matter and its proper disposal and management is the responsibility of the industry. As composting/vermicomposting could be used to transform this waste trials were carried out to determine the feasibility of converting dewatered sludge (DS into a value added end product using an earthworm, Perionyx excavatus. The vermicomposting of the waste resulted in an increase in its electrical conductivity (EC, ash content, total nitrogen (TN, total phosphorous (TP and available phosphorous (AP, respectively, and a decrease in total organic carbon (TOC, biochemical oxygen demand (BOD, chemical oxygen demand (COD, oxygen uptake rate (OUR and evolution of carbon dioxide (CO2. Overall, the best treatment was T5 in which there was a 76.1% increase in TP, 58.7% in TN, 74.5% decrease in TOC , and a reduction of 6.7 fold in the production of CO2 and 10.7 fold in BOD, respectively. Our trials demonstrate that vermicomposting using an epigeic earthworm, Perionyx excavatus, is an alternate and environmentally safe way of recycling paper mill sludge if it is mixed with an appropriate amount of cow dung and food processing waste. Overall T5 was the best combination of paper mill sludge and waste for vermicomposting followed by T3, T2, T4 and T1, respectively.

  3. Does wastewater from olive mills induce toxicity and water repellency in soil?

    Science.gov (United States)

    Peikert, B.; Bandow, N.; Schaumann, G. E.

    2012-04-01

    Olive oil mill wastewater is the effluent generated by the olive oil extraction process. It is the main waste product of this industry mainly being produced in the Mediterranean Basin. Because proper treatment options are rare it is often disposed into the environment, e.g. fields or wadies. Due to its high concentration of fatty acids and phytotoxic phenolic compounds and its high chemical and biological oxygen demand, olive oil mill wastewater becomes a serious environmental problem. In this screening study we investigated long-term effects of olive oil mill wastewater application on soil properties in several locations in the West Bank and Israel. We determined wettability via water drop penetration time and the contact angle as well as general soil properties including pH, EC, carbon content, and we conducted thermogravimetrical analyses in order to characterize the impact of the waste water on the quality of soil organic matter. Our results show that application of olive oil mill wastewater has various effects. We determined contact angles between 110 and 120° and water drop penetration times up to 1367 s indicating significant reduction in wettability. Furthermore, soil carbon and nitrogen content and water extractable organic matter increased as well as electric conductivity, which could be pointed out as a fertilizing effect. In contrast soil pH was significantly reduced. Conducting thermal analyses we observed an increase in the labile and refractory carbon fraction. Probably first one is responsible for induced water repellency. As a consequence the reduced wettability negatively affects soil quality. It would therefore be promising to minimize the hydrophobizing impacts without losing fertilizing effects of the olive oil mill wastewater.

  4. Surface water contamination by uranium Mining/Milling activities in Northern guangdong province, China

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jin; Song, Gang; Chen, Yongheng; Zhu, Li [Key Laboratory of Waters Safety and Protection in the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou (China); Liu, Juan [Key Laboratory of Waters Safety and Protection in the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou (China); Department of Geosciences, National Taiwan University, Taipei (China); Li, Hongchun [Department of Geosciences, National Taiwan University, Taipei (China); Xiao, Tangfu [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang (China); Qi, Jianying [South China Institute of Environmental Science, Ministry of Environmental Protection, Guangzhou (China)

    2012-12-15

    The northern region of Guangdong Province, China, has suffered from the extensive mining/milling of uranium for several decades. In this study, surface waters in the region were analyzed by inductively coupled plasma optical emission spectrometry (ICP-OES) for the concentrations of uranium (U), thorium (Th), and non-radioactive metals (Fe, Mn, Mg, Li, Co, Cu, Ni, and Zn). Results showed highly elevated concentrations of the studied radionuclides and metals in the discharged effluents and the tailing seepage of the U mining/milling sites. Radionuclide and heavy metal concentrations were also observed to be overall enhanced in the recipient stream that collected the discharged effluents from the industrial site, compared to the control streams, and rivers with no impacts from the U mining/milling sites. They displayed significant spatial variations and a general decrease downstream away from upper point-source discharges of the industrial site. In addition, obvious positive correlations were found between U and Th, Fe, Zn, Li, and Co (R{sup 2} > 0.93, n = 28) in the studied water samples, which suggest for an identical source and transport pathway of these elements. In combination with present surface water chemistry and chemical compositions of uraniferous minerals, the elevation of the analyzed elements in the recipient stream most likely arose from the liquid effluents, processing water, and acid drainage from the U mining/milling facilities. The dispersion of radionuclides and hazardous metals is actually limited to a small area at present, but some potential risk should not be negligible for local ecosystem. The results indicate that environmental remediation work is required to implement and future cleaner production technology should be oriented to avoid wide dispersion of radioactivity and non-radioactive hazards in U mining/milling sites. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Effect of milling duration on the evolution of shape memory properties in a powder processed Cu-Al-Ni-Ti alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Mohit; Gupta, Gaurav K.; Shafeeq, Muhamed M.; Modi, Om P.; Prasad, Braj K. [CSIR - Advanced Materials and Processes Research Institute, Bhopal (India)

    2013-09-15

    The present work describes the effect of milling duration on the properties of a powder metallurgy processed Cu-Al-Ni-Ti shape memory alloy employing mechanical alloying. Powder mixtures milled for different durations were sintered in order to investigate the formation of solid solution and evolution of martensitic structure. The idea was to optimize the duration of milling (mechanical alloying) to obtain chemical homogeneity as well as shape memory properties in the processed material without undergoing extensive post homogenization treatment. The martensitic structure was noted to evolve in the powder mix milled for at least 16 hrs, whereas complete transformation to martensite occurred after milling for 40 hrs. Interestingly, the dissolution of alloying elements (to form the {beta} phase prior to the formation of martensite) was noted to complete partially only during mechanical alloying for 40 hrs and remaining during subsequent sintering for 1 hr. The hot pressed compacts of the powders milled for 40 hrs were chemically homogeneous and consisted of fully martensite phase, which is essential for the realization of shape memory properties. They also revealed almost 100% shape recovery at the applied pre-strain levels of 1 and 2%. (orig.)

  6. Investigation for parametric vibration of rolling mill

    Institute of Scientific and Technical Information of China (English)

    唐华平; 丁睿; 吴运新; 钟掘

    2002-01-01

    The vibration unsteady condition of rolling mill caused by flexural vibration of strip has been investigated. The parametric flexural vibration equation of rolled strip has been established. The parametric flexural vibration stability of rolled strip has been studied and the regions of stability and unstability have been determined based on Floquet theory and perturbation method. The flexural-vibration of strip is unstable when the frequency of variable tension is two times as the natural frequency of flexural-vibration strip. The characteristic of current in a temp driving motor's main loop has been studied and tested, it has been proved that there are 6 harmonic component and 12 harmonic component in main loop of driving motor electricity. The vertical vibration of working roller has been tested, the test result approves that the running unsteady is caused by parametric vibration. It attaches importance to the parametric vibration of rolling mill.

  7. Coiling Temperature Control in Hot Strip Mill

    Science.gov (United States)

    Imanari, Hiroyuki; Fujiyama, Hiroaki

    Coiling temperature is one of the most significant factors in products of hot strip mill to determine material properties such as strength, toughness of steel, so it is very important to achieve accurate coiling temperature control (CTC). Usually there are a few pyrometers on the run out table in hot strip mill, therefore temperature model and its adapting system have large influences on the accuracy of CTC. Also unscheduled change of rolling speed has a bad effect to keep coiling temperature as its target. Newly developed CTC system is able to get very accurate coiling temperature against uncertain factors and disturbances by adopting easily identified temperature model, learning method and dynamic set up function. The features of the CTC system are discussed with actual data, and the effectiveness of the system is shown by actual control results.

  8. Analytic representations of Yang-Mills amplitudes

    Science.gov (United States)

    Bjerrum-Bohr, N. E. J.; Bourjaily, Jacob L.; Damgaard, Poul H.; Feng, Bo

    2016-12-01

    Scattering amplitudes in Yang-Mills theory can be represented in the formalism of Cachazo, He and Yuan (CHY) as integrals over an auxiliary projective space-fully localized on the support of the scattering equations. Because solving the scattering equations is difficult and summing over the solutions algebraically complex, a method of directly integrating the terms that appear in this representation has long been sought. We solve this important open problem by first rewriting the terms in a manifestly Möbius-invariant form and then using monodromy relations (inspired by analogy to string theory) to decompose terms into those for which combinatorial rules of integration are known. The result is the foundations of a systematic procedure to obtain analytic, covariant forms of Yang-Mills tree-amplitudes for any number of external legs and in any number of dimensions. As examples, we provide compact analytic expressions for amplitudes involving up to six gluons of arbitrary helicities.

  9. Paper mill wastewater detoxification by solar photocatalysis

    Energy Technology Data Exchange (ETDEWEB)

    Sattler, C.; Funken, K.H.; Oliveira, L. de; Tzschirner, M. [German Aerospace Center, Inst. of Technical Thermodynamics - Solar Research, Cologne (Germany); Machado, A.E.H. [Lab. de Fotoquimica - Inst. de Quimica, Univ. Federal de Uberlandia, Uberlandia, MG (Brazil)

    2003-07-01

    In the WATER project the German Aerospace Center, DLR, and the Universidade Federal de Uberlandia, UFU, analyse the possibilities of treating paper mill effluents by solar photocatalysis for the paper mill of the Brazilian paper producer Votorantim Celulose e Papel, VCP, at Luiz Antonio, SP, Brazil. The degradation of the bio-polymer lignin is a vast problem in paper production. The tests have shown that treatment by the photocatalyst TiO{sub 2} and solar radiation is an ecological future oriented approach to solve this problem. The treatment of lignin containing process water by solar photocatalysis was optimised and the economics for solar treatment plants of different sizes was estimated to check the possibilities for implementing the technology in industrial processes. (orig.)

  10. Analytic Representations of Yang-Mills Amplitudes

    CERN Document Server

    Bjerrum-Bohr, N E J; Damgaard, Poul H; Feng, Bo

    2016-01-01

    Scattering amplitudes in Yang-Mills theory can be represented in the formalism of Cachazo, He and Yuan (CHY) as integrals over an auxiliary projective space---fully localized on the support of the scattering equations. Because solving the scattering equations is difficult and summing over the solutions algebraically complex, a method of directly integrating the terms that appear in this representation has long been sought. We solve this important open problem by first rewriting the terms in a manifestly Mobius-invariant form and then using monodromy relations (inspired by analogy to string theory) to decompose terms into those for which combinatorial rules of integration are known. The result is a systematic procedure to obtain analytic, covariant forms of Yang-Mills tree-amplitudes for any number of external legs and in any number of dimensions. As examples, we provide compact analytic expressions for amplitudes involving up to six gluons of arbitrary helicities.

  11. Quality assessment of corn batches received at a feed mill in the brazilian cerrado

    Directory of Open Access Journals (Sweden)

    SIFC Rodrigues

    2014-09-01

    Full Text Available This study aimed at investigating factors that contribute to changes in the quality of corn used in compound poultry feeds. Samples were collected from 6488 bulk cargos received at a feed mill located close to Brasília, Brazil. The parameters studied were divided into two groups: those related to corn chemical composition, including crude protein (% CP, ether extract (% EE, crude fiber (% CF, nitrogen-free extract (% NFE, and estimated metabolizable energy (ME, and corn physical characteristics, including density, moisture, and grain physical damage. High coefficients of determination (R² and low coefficients of variation (CV were determined for the chemical and physical parameters. The analysis of variance showed low to medium R². Month, year, supplier, and their interactions influenced (p <0.05 all chemical properties, as well as density, moisture, and ME. Physical characteristics were less affected by those factors, except for quantity of damaged grains. The principal component analysis separated the physical and chemical factors. The coefficients of the first component explained 54% of the total variation between variables. The first principal component showed that NFE and ME increased as humidity decreased. The second component also showed a decrease of physical problems due to reduction in humidity. Results indicate that the feed mills should take preventive measures when selecting suppliers, and diets should be formulated according to the differences in chemical and physical composition of corn supplied in different months and years.

  12. Mathematical modelling to predict the roughness average in micro milling process

    Science.gov (United States)

    Burlacu, C.; Iordan, O.

    2016-08-01

    Surface roughness plays a very important role in micro milling process and in any machining process, because indicates the state of the machined surface. Many surface roughness parameters that can be used to analyse a surface, but the most common surface roughness parameter used is the average roughness (Ra). This paper presents the experimental results obtained at micro milling of the C45W steel and the ways to determine the Ra parameter with respect to the working conditions. The chemical characteristics of the material were determined from a spectral analysis, chemical composition was measured at one point and two points, graphical and tabular. A profilometer Surtronic 3+ was used to examine the surface roughness profiles; the effect of independent parameters can be investigated and can get a proper relationship between the Ra parameter and the process variables. The mathematical model were developed, using multiple regression method with four independent variables D, v, ap, fz; the analysis was done using statistical software SPSS. The ANOVA analysis of variance and the F- test was used to justify the accuracy of the mathematical model. The multiple regression method was used to determine the correlation between a criterion variable and the predictor variables. The prediction model can be used for micro milling process optimization.

  13. Multifractal properties of ball milling dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Budroni, M. A., E-mail: mabudroni@uniss.it; Pilosu, V.; Rustici, M. [Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari, Via Vienna 2, Sassari 07100 (Italy); Delogu, F. [Dipartimento di Ingegneria Meccanica, Chimica, e dei Materiali, Università degli Studi di Cagliari, via Marengo 2, Cagliari 09123 (Italy)

    2014-06-15

    This work focuses on the dynamics of a ball inside the reactor of a ball mill. We show that the distribution of collisions at the reactor walls exhibits multifractal properties in a wide region of the parameter space defining the geometrical characteristics of the reactor and the collision elasticity. This feature points to the presence of restricted self-organized zones of the reactor walls where the ball preferentially collides and the mechanical energy is mainly dissipated.

  14. Kinetic reduction of mill scale via hydrogen

    Directory of Open Access Journals (Sweden)

    Gaballah N.M.

    2014-01-01

    Full Text Available Mill scale is very attractive industrial waste since it is rich in iron (about = 72 % Fe and it is suiTab. for direct recycling to the blast furnace via sintering plant. In this paper the characterizations of raw materials were studied by different methods of analyses. The produced briquettes were reduced with different amounts of hydrogen at varying temperatures, and the reduction kinetics was determined. Two models were applied and the energy of activation was calculated.

  15. Higher derivative super Yang-Mills theories

    NARCIS (Netherlands)

    Bergshoeff, E.; Rakowski, M.; Sezgin, E.

    1987-01-01

    The most general higher derivative Yang-Mills actions of the type (F^2 + α^2F^4) which are globally supersymmetric up to order α^2 in six- and ten-dimensional spacetimes are given. The F^4-terms turn out to occur in the combination α^2[tr F^4 - ¼(tr F^2)^2], where the trace is over the Lorentz i

  16. Geothermal Mill Redevelopment Project in Massachusetts

    Energy Technology Data Exchange (ETDEWEB)

    Vale, A.Q.

    2009-03-17

    Anwelt Heritage Apartments, LLC redeveloped a 120-year old mill complex into a mixed-use development in a lower-income neighborhood in Fitchburg, Massachusetts. Construction included 84 residential apartments rented as affordable housing to persons aged 62 and older. The Department of Energy (“DOE”) award was used as an essential component of financing the project to include the design and installation of a 200 ton geothermal system for space heating and cooling.

  17. Homogeneity of ball milled ceramic powders: Effect of jar shape and milling conditions

    Directory of Open Access Journals (Sweden)

    M. Broseghini

    2017-02-01

    Full Text Available This paper contains data and supporting information of and complementary to the research article entitled “Effect of jar shape on high-energy planetary ball milling efficiency: simulations and experiments” (Broseghini et al., [1]. Calcium fluoride (CaF2 was ground using two jars of different shape (cylindrical and half-moon installed on a planetary ball-mill, exploring different operating conditions (jar-to-plate angular velocity ratio and milling time. Scanning Electron Microscopy (SEM images and X-Ray Powder Diffraction data (XRPD were collected to assess the effect of milling conditions on the end-product crystallite size. Due to the inhomogeneity of the end product, the Whole Powder Pattern Model (WPPM, (Scardi, 2008 [2] analysis of XRPD data required the hypothesis of a bimodal distribution of sizes – respectively ground (fine fraction and less-to-not ground (coarse fraction – confirmed by SEM images and suggested by the previous literature (Abdellatief et al., 2013 [3,4]. Predominance of fine fraction clearly indicates optimal milling conditions.

  18. Cutting force prediction for circular end milling process

    Institute of Scientific and Technical Information of China (English)

    Wu Baohai; Yan Xue; Luo Ming; Gao Ge

    2013-01-01

    A deduced cutting force prediction model for circular end milling process is presented in this paper.Traditional researches on cutting force model usually focus on linear milling process which does not meet other cutting conditions,especially for circular milling process.This paper presents an improved cutting force model for circular end milling process based on the typical linear milling force model.The curvature effects of tool path on chip thickness as well as entry and exit angles are analyzed,and the cutting force model of linear milling process is then corrected to fit circular end milling processes.Instantaneous cutting forces during circular end milling process are predicted according to the proposed model.The deduced cutting force model can be used for both linear and circular end milling processes.Finally,circular end milling experiments with constant and variable radial depth were carried out to verify the availability of the proposed method.Experiment results show that measured results and simulated results corresponds well with each other.

  19. EQUIVALENT NORMAL CURVATURE APPROACH MILLING MODEL OF MACHINING FREEFORM SURFACES

    Institute of Scientific and Technical Information of China (English)

    YI Xianzhong; MA Weiguo; QI Haiying; YAN Zesheng; GAO Deli

    2008-01-01

    A new milling methodology with the equivalent normal curvature milling model machining freeform surfaces is proposed based on the normal curvature theorems on differential geometry. Moreover, a specialized whirlwind milling tool and a 5-axis CNC horizontal milling machine are introduced. This new milling model can efficiently enlarge the material removal volume at the tip of the whirlwind milling tool and improve the producing capacity. The machining strategy of this model is to regulate the orientation of the whirlwind milling tool relatively to the principal directions of the workpiece surface at the point of contact, so as to create a full match with collision avoidance between the workpiece surface and the symmetric rotational surface of the milling tool. The practical results show that this new milling model is an effective method in machining complex three- dimensional surfaces. This model has a good improvement on finishing machining time and scallop height in machining the freeform surfaces over other milling processes. Some actual examples for manufacturing the freeform surfaces with this new model are given.

  20. Twin Supergravities from Yang-Mills Squared

    CERN Document Server

    Anastasiou, A; Duff, M J; Hughes, M J; Marrani, A; Nagy, S; Zoccali, M

    2016-01-01

    We consider `twin supergravities' - pairs of supergravities with $\\mathcal{N}_+$ and $\\mathcal{N}_-$ supersymmetries, $\\mathcal{N}_+>\\mathcal{N}_-$, with identical bosonic sectors - in the context of tensoring super Yang-Mills multiplets. It is demonstrated that the pairs of twin supergravity theories are related through their left and right super Yang-Mills factors. This procedure generates new theories from old. In particular, the matter coupled $\\mathcal{N}_-$ twins in $D=3,5,6$ and the $\\mathcal{N}_-=1$ twins in $D=4$ have not, as far as we are aware, been obtained previously using the double-copy construction, adding to the growing list of double-copy constructible theories. The use of fundamental matter multiplets in the double-copy construction leads us to introduce a bi-fundamental scalar that couples to the well-known bi-adjoint scalar field. It is also shown that certain matter coupled supergravities admit more than one factorisation into left and right super Yang-Mills-matter theories.

  1. Superstring limit of Yang-Mills theories

    Science.gov (United States)

    Lechtenfeld, Olaf; Popov, Alexander D.

    2016-11-01

    It was pointed out by Shifman and Yung that the critical superstring on X10 =R4 ×Y6, where Y6 is the resolved conifold, appears as an effective theory for a U(2) Yang-Mills-Higgs system with four fundamental Higgs scalars defined on Σ2 ×R2, where Σ2 is a two-dimensional Lorentzian manifold. Their Yang-Mills model supports semilocal vortices on R2 ⊂Σ2 ×R2 with a moduli space X10. When the moduli of slowly moving thin vortices depend on the coordinates of Σ2, the vortex strings can be identified with critical fundamental strings. We show that similar results can be obtained for the low-energy limit of pure Yang-Mills theory on Σ2 × Tp2, where Tp2 is a two-dimensional torus with a puncture p. The solitonic vortices of Shifman and Yung then get replaced by flat connections. Various ten-dimensional superstring target spaces can be obtained as moduli spaces of flat connections on Tp2, depending on the choice of the gauge group. The full Green-Schwarz sigma model requires extending the gauge group to a supergroup and augmenting the action with a topological term.

  2. John Stuart Mill on socialism and accountability

    Directory of Open Access Journals (Sweden)

    Francisco José Sales Rocha

    2010-01-01

    Full Text Available http://dx.doi.org/10.5007/1677-2954.2010v9n1p17Este artigo mostra que o tipo de socialismo proposto por John Stuart Mill é marcado por uma forte preocupação com a controlabilidade do poder econômico e político. Ele rejeitou enfaticamente os modelos centralistas de socialismo por entender que eles levam a uma grande concentração de poder que compromete a liberdade. Para J. S. Mill, o socialismo deve ser implantado lentamente a partir de reformas amplamente discutidas que favoreçam a cidadania econômica dos trabalhadores, promovam a participação deles nas decisões referentes ao processo produtivo e em associações voluntárias. J. S. Mill acreditava que a competição econômica é essencial para o adequado funcionamento de uma economia socialista. Ele não esperava que tal economia se tornasse uma realidade em um futuro próximo.

  3. Folate in oats and its milling fractions.

    Science.gov (United States)

    Edelmann, Minnamari; Kariluoto, Susanna; Nyström, Laura; Piironen, Vieno

    2012-12-01

    Total folate content in oat varieties from three harvesting years (2006-2008), and in oats milling fractions, was determined using microbiological assay. Furthermore, folate vitamer distribution in milling fractions were examined with the UPLC method, which was taken in use and validated. The total folate content of the cultivars varied moderately within each year. The average content in the 2008 samples was 685ng/gdm. The UPLC method proved fast and sensitive for determining seven folate monoglutamates in cereal samples. Folate content in fractions, which are normally discarded, such as flour from oat cutting and flaking, were 1.5- to 2.5-fold higher than in native grain. The main folate vitamers found in the oat fractions were 5-CH(3)-H(4)folate, 5-HCO-H(4)folate, and 5,10-CH(+)-H(4)folate. The UPLC results more closely matched the microbiological results compared to those that are usually achieved with HPLC methods. This study illustrates that oats and, especially, by-products of milling are good sources of folate.

  4. Bioconversion of paper mill sludge to bioethanol in the presence of accelerants or hydrogen peroxide pretreatment.

    Science.gov (United States)

    Gurram, Raghu Nandan; Al-Shannag, Mohammad; Lecher, Nicholas Joshua; Duncan, Shona M; Singsaas, Eric Lawrence; Alkasrawi, Malek

    2015-09-01

    In this study we investigated the technical feasibility of convert paper mill sludge into fuel ethanol. This involved the removal of mineral fillers by using either chemical pretreatment or mechanical fractionation to determine their effects on cellulose hydrolysis and fermentation to ethanol. In addition, we studied the effect of cationic polyelectrolyte (as accelerant) addition and hydrogen peroxide pretreatment on enzymatic hydrolysis and fermentation. We present results showing that removing the fillers content (ash and calcium carbonate) from the paper mill sludge increases the enzymatic hydrolysis performance dramatically with higher cellulose conversion at faster rates. The addition of accelerant and hydrogen peroxide pretreatment further improved the hydrolysis yields by 16% and 25% (g glucose / g cellulose), respectively with the de-ashed sludge. The fermentation process of produced sugars achieved up to 95% of the maximum theoretical ethanol yield and higher ethanol productivities within 9h of fermentation.

  5. Stability studies of As4S4 nanosuspension prepared by wet milling in Poloxamer 407.

    Science.gov (United States)

    Bujňáková, Zdenka; Dutková, Erika; Baláž, Matej; Turianicová, Erika; Baláž, Peter

    2015-01-15

    In this paper the stability of the arsenic sulfide (As4S4) nanosuspension prepared by wet milling in a circulation mill in the environment of copolymer Poloxamer 407 was studied. The obtained As4S4 particles in nanosuspension were of ∼ 100 nm in size. The influence of temperature and UV irradiation on the changes in physical and/or chemical properties was followed. Long-term stability was observed via particle size distribution and zeta potential measurements. Influence of UV irradiation was studied via UV-vis spectroscopy (UV-vis), photoluminicsence (PL) technique and Fourier transform infrared spectroscopy (FTIR) measurements. The best stability of the nanosuspension (24 weeks) was achieved when stored at 4°C and in the dark.

  6. Influence of milling time on fineness of Centella Asiatica particle size produced using planetary ball mill

    Science.gov (United States)

    Borhan, M. Z.; Ahmad, R.; Rusop, M.; Abdullah, S.

    2012-11-01

    Centella Asiatica (C. Asiatica)contains asiaticoside as bioactive constituent which can be potentially used in skin healing process. Unfortunately, the normal powders are difficult to be absorbed by the body effectively. In order to improve the value of use, nano C. Asiatica powder was prepared. The influence of milling time was carried out at 0.5, 2, 4, 6, 8 hours and 10 hours. The effect of ball milling at different times was characterized using particles size analysis and FTIR Spectroscopy. The fineness of ground product was evaluated by recording the z-Average (nm), undersize distribution and polydispersity index (PdI). The results show that the smallest size particles by mean is 233 nm while FTIR spectra shows that there is no changing in the major component in the C. Asiatica powders with milling time.

  7. John Stuart Mill: utilitarismo e liberalismo = John Stuart Mill: utilitarianism and liberalism

    Directory of Open Access Journals (Sweden)

    Simões, Mauro Cardoso

    2013-01-01

    Full Text Available Meu objetivo, neste trabalho, é investigar a compatibilidade das teses utilitaristas e liberais de John Stuart Mill. Apresentarei, inicialmente, os principais críticos da filosofia moral e política de Mill, para os quais o discípulo de Bentham teria abandonado o utilitarismo ou, ainda, não esclarecido suficientemente seu princípio da liberdade, o que o tornaria um pensador assistemático e inconsistente. Minha tese é contrária a tais interpretações, uma vez que sustenta ser Mill consistente. Em seguida, defenderei uma interpretação do princípio da liberdade e da individualidade, procurando demonstrar que seu utilitarismo é compatível com seu liberalismo

  8. Effects of mechanical milling on the carbothermal reduction of oxide of WC/Co hardmetal scrap

    Science.gov (United States)

    Lee, Gil-Geun; Ha, Gook-Hyun

    2016-03-01

    The effects of mechanical milling on the carbothermal reduction of oxidized WC/Co hardmetal scrap with solid carbon were examined. Mixed powders were manufactured by milling the WC/Co hard metal scrap oxide and carbon powder in either a tumbler-ball mill or a planetary-ball mill. The milling type affected the carbothermal reduction of the oxide owing to the differing collision energies (mechanical milling energies) in the mills. The hardmetal scrap oxide powder (WO3, CoWO4) milled at high energy was more greatly reduced and at a lower temperature than that milled at lower mechanical energy. The formation of WC by the carburization reaction with solid carbon reached completion at a lower temperature after higher-energy milling than after lower-energy milling. The WC/Co composite particles synthesized by the combined oxidationmechanical milling-carbothermal reduction process were smaller when the initial powder was milled at higher mechanical energy.

  9. Design and Manufacturing of Ultra-Hard Micro-Milling Tool

    Institute of Scientific and Technical Information of China (English)

    战忠波; 李亮; 何宁; 卞荣; 赵孟

    2014-01-01

    Based on the study of existing typical micro-milling tools and the actual demand for micro-milling tools, the P3 design principle and design flow for ultra-hard micro-milling tool were introduced to give basic guidance for the optimization of micro-milling tools. Then, according to the P3 design flow, the manufacturing process of polycrystal-line diamond (PCD) micro-milling tool was proposed, and the PCD micro-milling tool with diameter of 0.5 mm was developed. Finally, the micro-milling test on the slot was carried out to study the milling performance of PCD micro-milling tool.

  10. Fractal and Chaos Characteristics in Rock Milled Process

    Directory of Open Access Journals (Sweden)

    Chenxu LUO

    2013-07-01

    Full Text Available In order to research the mechanism and to reveal the natural characteristics in rock milled process, the milling load was deemed to be a component of the deterministic nonlinear dissipation system. The characteristic factor model of milling load was built on the basis of time delay method, and the phase-space of milling load was rebuilt. the dimensional phase-type of broken attractor was described. The results indicated that the broken attractor was a fractal set ,which acquired through the scale conversion of phase-space developed by each dimension. The relevant dimension of broken attractor can be as the identification to reflect the change of rock broken mechanism. And the Lyapunov exponential spectrum and the maximum Lyapunov exponent were acquired by confirming the system reconstruction dimension. The chaos phenomenon was existed in the rock milled process, which provides the basis for building the deterministic model of rock milled process.

  11. Fault Detection in Coal Mills used in Power Plants

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, Babak

    2006-01-01

    In order to achieve high performance and efficiency of coal-fired power plants, it is highly important to control the coal flow into the furnace in the power plant. This means suppression of disturbances and force the coal mill to deliver the required coal flow, as well as monitor the coal mill...... in order to detect faults in the coal mill when they emerge. This paper deals with the second objective. Based on a simple dynamic model of the energy balance a residual is formed for the coal mill. An optimal unknown input observer is designed to estimate this residual. The estimated residual is following...... tested on measured data of a fault in a coal mill, it can hereby be concluded that this residual is very useful for detecting faults in the coal mill....

  12. Chemical activation of MgH2; a new route to superior hydrogen storage materials.

    Science.gov (United States)

    Johnson, Simon R; Anderson, Paul A; Edwards, Peter P; Gameson, Ian; Prendergast, James W; Al-Mamouri, Malek; Book, David; Harris, I Rex; Speight, John D; Walton, Allan

    2005-06-14

    We report the discovery of a new, chemical route for 'activating' the hydrogen store MgH2, that results in highly effective hydrogen uptake/release characteristics, comparable to those obtained from mechanically-milled material.

  13. Experimental studies on pulp and paper mill sludge ash behavior in fluidized bed combustors

    Energy Technology Data Exchange (ETDEWEB)

    Latva-Somppi, J. [VTT Chemical Technology, Espoo (Finland). Process Technology

    1998-11-01

    Ash formation during the fluidized bed combustion (FBC) of pulp and paper mill sludges has been experimentally studied on an industrial and bench scale. The methods included aerosol measurements, chemical and crystalline composition analyses, thermogravimetry and electron microscopy. Fly ash mass and number size distributions and elemental enrichment in submicron particles and bottom ash were measured. Fly ash, bottom ash and ash deposits were characterized and their formation mechanisms are discussed. During combustion the fine paper-making additives in sludge, clay minerals and calcite, sintered fanning porous agglomerates. The fly ash mass mean size was 7.5 - 15 lam and the supermicron particles included 93.6 - 97.3 % of the fly ash. Condensation of the volatilized inorganic species formed spherical submicron particles in the fly ash. Their mass concentration was almost negligible when co-firing paper mill sludges and wood. This suggests that the fraction of the volatilized inorganic species in the paper mill sludges was low. Results from pulp mill sludge and bark co-firing were different. A clear mass mode below 0.3 pm, presenting 2.2 - 5.0 weight-% of the fly ash was detected. The condensed species included K, Na, S and Cl. Their mass fraction was higher in the pulp mill sludge than in the paper mill sludge. Evidently this resulted in increased volatilization and formation of condensed particles. The following trace elements were enriched in the submicron ash during pulp mill sludge and wood co-firing: As, Cd, Rb and Pb. The main part of the volatile species was, however, captured in the bulk ash. Presumably, this was due to the high surface area concentration in the bulk ash. Sludge moisture was observed to reduce the inorganic species volatilization. Probably steam vaporization from the wet sludge through the burning layer decreased combustion temperatures on char surface and less char was produced. Hence, the volatilization of ash forming species was

  14. Research on Frequency Response Characteristics of Rolling Mill

    Institute of Scientific and Technical Information of China (English)

    CaiZhengguo; ZhangKenan

    2005-01-01

    The measurement method of frequency response characteristics for rolling mill is established by imposing different signal excitation on PID input of rolling mill under the different rolling conditions. The analysis results declare that sweep sine signal was relative efficient to evaluation for the frequency response character of hydraulic system. The practical application shows that the corresponding relationship between the parameters and the frequency response range of the rolling mill is helpful for parameters verification of process control and condition monitoring of hydraulic system.

  15. Dynamical Breaking of Generalized Yang-Mills Theory

    Institute of Scientific and Technical Information of China (English)

    WANGDian-Fu; SONGHe-Shan

    2004-01-01

    The dynamical breaking of a generalized Yang-Mills theory is discussed. It is shown, in terms of the Nambu Jona-Lasinio mechanism, that the gauge symmetry breaking can be realized dynamically in the generalized Yang-Mills theory. The combination of the generalized Yang-Mills theory and the NJL mechanism provides a way to overcome the difficulties related to the Higgs field and the Higgs mechanism in the usual spontaneous symmetry breaking theory.

  16. Dynamical Breaking of Generalized Yang-Mills Theory

    Institute of Scientific and Technical Information of China (English)

    WANG Dian-Fu; SONG He-Shah

    2004-01-01

    The dynamical breaking of a generalized Yang-Mills theory is discussed. It is shown, in terms of the Nambu-Jona-Lasinio mechanism, that the gauge symmetry breaking can be realized dynamically in the generalized Yang-Mills theory. The combination of the generalized Yang-Mills theory and the NJL mechanism provides a way to overcome the difficulties related to the Higgs field and the Higgs mechanism in the usual spontaneous symmetry breaking theory.

  17. HEAT FLOW FOR YANG-MILLS-HIGGS FIELDS, PART I

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The Yang-Mills-Higgs field generalizes the Yang-Mills field. The authors establish the local existence and uniqueness of the weak solution to the heat flow for the Yang-Mills-Higgs field in a vector bundle over a compact Riemannian 4-manifold, and show that the weak solution is gauge-equivalent to a smooth solution and there are at most finite singularities at the maximum existing time.

  18. Removal of the organic content from a bleached kraft pulp mill effluent by a treatment with silica-alginate-fungi biocomposites.

    Science.gov (United States)

    Duarte, Katia; Justino, Celine I L; Pereira, Ruth; Panteleitchouk, Teresa S L; Freitas, Ana C; Rocha-Santos, Teresa A P; Duarte, Armando C

    2013-01-01

    This study attempts a treatment strategy of a bleached kraft pulp mill effluent with Rhizopus oryzae or Pleurotus sajor caju encapsulated on silica-alginate (biocomposite of silica-alginate-fungi, with the purpose of reducing its potential impact in the environment. Active (alive) or inactive (death by sterilization) Rhizopus oryzae or Pleurotus sajor caju was encapsulated in alginate beads. Five beads containing active and inactive fungus were placed in a mold and filled with silica hydrogel (biocomposites). The biocomposites were added to batch reactors containing the bleached kraft pulp mill effluent. The treatment of bleached kraft pulp mill effluent by active and inactive biocomposites was performed throughout 29 days at 28°C. The efficiency of treatment was evaluated by measuring the removal of organic compounds, chemical oxygen demand and the relative absorbance ratio over time. Both fungi species showed potential for removal of organic compounds, colour and chemical oxygen demand. Maximum values of reduction in terms of colour (56%), chemical oxygen demand (65%) and organic compounds (72-79%) were attained after 29 days of treatment of bleached kraft pulp mill effluent by active Rhizopus oryzae biocomposites. The immobilization of fungi, the need for low fungal biomass, and the possibility of reutlization of the biocomposites clearly demonstrate the industrial and environmental interest in bleached kraft pulp mill effluent treatment by silica-alginate-fungi biocomposites.

  19. Simulation of Vertical Planetary Mill Based on Virtual Prototyping

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The mechanical model of vertical planetary mill is set up, whose dynamic and kinetic characteristics are described as well. Based on the analysis of system dynamics of vertical planetary mill, virtual prototyping technology is applied in the simulation of this mill. The development of virtual prototype of equipment, virtual test and optimization of virtual prototype are stated in detail. Some useful conclusions which have theoretical meaning for the manufacturing of vertical planetary mill have been obtained. Furthermore, it is pointed out that virtual prototyping technology shows great advantage and is bound to become a main method of developing product in the future.

  20. Model Predictive Control for an Industrial SAG Mill

    DEFF Research Database (Denmark)

    2012-01-01

    identication. When applied to MIMO systems we call this controller a MIMO-ARX based MPC. We use an industrial Semi-Autogenous Grinding (SAG) mill to illustrate the performance of this controller. SAG mills are the primary units in a grinding chain and also the most power consuming units. Therefore, improved...... control of SAG mills has the potential to signicantly improve eciency and reduce the specic energy consumption for mineral processes. Grinding circuits involving SAG mills are multivariate processes. Commissioning of a control system based on a classical single-loop controllers with logic is time...

  1. Preparation of iron sulphides by high energy ball milling

    DEFF Research Database (Denmark)

    Lin, R.; Jiang, Jianzhong; Larsen, R.K.;

    1998-01-01

    The reaction of a powder mixture consisting of 50 a.% Fe and 50 a.% S during high energy ball milling has been studied by x-ray diffraction and Mossbauer spectroscopy. After around 19 h of milling FeS2 and FeS havebeen formed. By further milling the FeS compound becomes dominating and only Fe......S with an average crystallite size of about 10 nm was observed after milling times longer than 67 h. Mossbauer spectra obtained with applied fields show that the particles are antiferromagnetic or have a strongly canted spin structure....

  2. Nutritional Impacts of Different Whole Grain Milling Techniques: A Review of Milling Practices and Existing Data

    NARCIS (Netherlands)

    Miller Jones, J.; Adams, J.; Harriman, C.; Miller, C.; Kamp, J.W. van der

    2015-01-01

    The majority of whole grain flour is produced using modern milling techniques, usually with steel rollers, in which a batch of grain is separated into multiple millstreams, sifted, and recombined. In some cases constituent millstreams are purchased and combined by a supplier or end user to achieve a

  3. Nutritional impacts of different whole grain milling techniques : A review of milling practices and existing data

    NARCIS (Netherlands)

    Miller Jones, J.; Adams, J.; Harriman, C.; Miller, C.; Kamp, J.W. van der

    2015-01-01

    The majority of whole grain flour is produced using modern milling techniques, usually with steel rollers, in which a batch of grain is separated into multiple millstreams, sifted, and recombined. In some cases constituent millstreams are purchased and combined by a supplier or end user to achieve a

  4. Yang-Mills theory in Coulomb gauge; Yang-Mills-theorie in Coulombeichung

    Energy Technology Data Exchange (ETDEWEB)

    Feuchter, C.

    2006-07-01

    In this thesis we study the Yang-Mills vacuum structure by using the functional Schroedinger picture in Coulomb gauge. In particular we discuss the scenario of colour confinement, which was originally formulated by Gribov. After a short introduction, we recall some basic aspects of Yang-Mills theories, its canonical quantization in the Weyl gauge and the functional Schroedinger picture. We then consider the minimal Coulomb gauge and the Gribov problem of the gauge theory. The gauge fixing of the Coulomb gauge is done by using the Faddeev-Popov method, which enables the resolution of the Gauss law - the constraint on physical states. In the third chapter, we variationally solve the stationary Yang-Mills Schroedinger equation in Coulomb gauge for the vacuum state. Therefor we use a vacuum wave functional, which is strongly peaked at the Gribov horizon. The vacuum energy functional is calculated and minimized resulting in a set of coupled Schwinger-Dyson equations for the gluon energy, the ghost and Coulomb form factors and the curvature in gauge orbit space. Using the angular approximation these integral equations have been solved analytically in both the infrared and the ultraviolet regime. The asymptotic analytic solutions in the infrared and ultraviolet regime are reasonably well reproduced by the full numerical solutions of the coupled Schwinger-Dyson equations. In the fourth chapter, we investigate the dependence of the Yang-Mills wave functional in Coulomb gauge on the Faddeev-Popov determinant. (orig.)

  5. Highly Productive Tools For Turning And Milling

    Science.gov (United States)

    Vasilko, Karol

    2015-12-01

    Beside cutting speed, shift is another important parameter of machining. Its considerable influence is shown mainly in the workpiece machined surface microgeometry. In practice, mainly its combination with the radius of cutting tool tip rounding is used. Options to further increase machining productivity and machined surface quality are hidden in this approach. The paper presents variations of the design of productive cutting tools for lathe work and milling on the base of the use of the laws of the relationship among the highest reached uneveness of machined surface, tool tip radius and shift.

  6. Perturbative spacetimes from Yang-Mills theory

    CERN Document Server

    Luna, Andres; Nicholson, Isobel; Ochirov, Alexander; O'Connell, Donal; Westerberg, Niclas; White, Chris D.

    2016-01-01

    The double copy relates scattering amplitudes in gauge and gravity theories. In this paper, we expand the scope of the double copy to construct spacetime metrics through a systematic perturbative expansion. The perturbative procedure is based on direct calculation in Yang-Mills theory, followed by squaring the numerator of certain perturbative diagrams as specified by the double-copy algorithm. The simplest spherically symmetric, stationary spacetime from the point of view of this procedure is a particular member of the Janis-Newman-Winicour family of naked singularities. Our work paves the way for applications of the double copy to physically interesting problems such as perturbative black-hole scattering.

  7. Landau gauge Yang-Mills correlation functions

    Science.gov (United States)

    Cyrol, Anton K.; Fister, Leonard; Mitter, Mario; Pawlowski, Jan M.; Strodthoff, Nils

    2016-09-01

    We investigate Landau gauge S U (3 ) Yang-Mills theory in a systematic vertex expansion scheme for the effective action with the functional renormalization group. Particular focus is put on the dynamical creation of the gluon mass gap at nonperturbative momenta and the consistent treatment of quadratic divergences. The nonperturbative ghost and transverse gluon propagators as well as the momentum-dependent ghost-gluon, three-gluon and four-gluon vertices are calculated self-consistently with the classical action as the only input. The apparent convergence of the expansion scheme is discussed and within the errors, our numerical results are in quantitative agreement with available lattice results.

  8. String Scale in Noncommutative Yang-Mills

    CERN Document Server

    Ishibashi, N; Kawai, H; Kitazawa, Y

    2000-01-01

    We identify the effective string scale of noncommutative Yang-Mills theory (NCYM) with the noncommutativity scale through its dual supergravity description. We argue that Newton's force law may be obtained with 4 dimensional NCYM with maximal SUSY. It provides a nonperturbative compactification mechanism of IIB matrix model. We can associate NCYM with the von Neumann lattice by the bi-local representation. We argue that it is superstring theory on the von Neumann lattice. We show that our identification of its effective string scale is consistent with exact T-duality (Morita equivalence) of NCYM.

  9. Duality in supersymmetric Yang-Mills theory

    Energy Technology Data Exchange (ETDEWEB)

    Peskin, M.E.

    1997-02-01

    These lectures provide an introduction to the behavior of strongly-coupled supersymmetric gauge theories. After a discussion of the effective Lagrangian in nonsupersymmetric and supersymmetric field theories, the author analyzes the qualitative behavior of the simplest illustrative models. These include supersymmetric QCD for N{sub f} < N{sub c}, in which the superpotential is generated nonperturbatively, N = 2 SU(2) Yang-Mills theory (the Seiberg-Witten model), in which the nonperturbative behavior of the effect coupling is described geometrically, and supersymmetric QCD for N{sub f} large, in which the theory illustrates a non-Abelian generalization of electric-magnetic duality. 75 refs., 12 figs.

  10. Design and Fabrication of Savonious Wind Mill

    Directory of Open Access Journals (Sweden)

    P. L. N. V. Aashrith

    2014-06-01

    Full Text Available The project deals with the design and fabrication of Savonius wind mill. Pw – Wind power (watt, and Power produced by the turbine Pt has been calculated using m – Mass flow rate (kg/s, Swept area of the windfall ,V- Velocity of the wind, Θ- Angular position of turbine, T- Torque obtained by wind, Pt- Shaft power , Cp- Power coffecient ,Ct- Torque co-efficient , μ – Tip speed ratio , r – Radius of rotor , d- Diameter of rotor ,w- Angular speed of rotor. Various operations involved in fabrication process and characteristics & specifications of wind turbine has been mentioned

  11. Children's Rights, "die Antipadagogen," and the Paternalism of John Stuart Mill.

    Science.gov (United States)

    Nordenbo, Sven Erik

    1989-01-01

    Examines how John Stuart Mill would have viewed present-day educational liberalists' claims that children should be included in Mill's principle of individual liberty. Concludes that educational liberalists cannot rightly claim Mill as spokesman for their views. (KO)

  12. Mechanically milled aluminium matrix composites reinforced with halloysite nanotubes

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2012-12-01

    Full Text Available Purpose: The present work describes fabrication of aluminium AlMg1SiCu matrix composite materials reinforced with halloysite nanotubes by powder metallurgy techniques and hot extrusion.Design/methodology/approach: Mechanical milling, compacting and hot extrusion successively are considering as a method for manufacturing metal composite powders with a controlled fine microstructure and enhanced mechanical properties. It is possible by the repeated welding and fracturing of powders particles mixture in a highly energetic ball mill.Findings: The milling process has a huge influence on the properties of powder materials, changing the spherical morphology of as-received powder during milling process to flattened one due to particle deformation followed by welding and fracturing particles of deformed and hardened enough which allows to receive equiaxial particles morphology again. The investigation shows that so called brittle mineral particles yields to plastic deformation as good as ductile aluminium alloy particles. That indicates that the halloysite powder can play a role of the accelerator during mechanical milling. High energy ball milling as a method of mechanical milling improves the distribution of the halloysite reinforcing particles throughout the aluminium matrix, simultaneously reducing the size of particles. The apparent density changes versus milling time can be used to control the composite powders production by mechanical milling and the presence of halloysite reinforcements particles accelerates the mechanical milling process.Research limitations/implications: Contributes to knowledge about technology, structure and properties of aluminium alloy matrix composite material reinforced with mineral nanoparticles.Practical implications: Conducted research shows that applied technology allows obtaining very good microstructural characteristics.Originality/value: It has been confirmed that halloysite nanotubes can be applied as an effective

  13. Influence of the control atmosphere and milling time on the morphology and microstructure of pure copper and copper-2.5 % lithium powders produced by mechanical alloying; Influencia de la atmosfera de control y tiempo de molienda sobre la morfologia y microestructura de polvos de cobre puro y cobre-2,5% litio producidos por aleado mecanio

    Energy Technology Data Exchange (ETDEWEB)

    Rojas, P. A.; Alvarez, M. P.; Penaloza, A.; Zuniga, A.; Ordonez, S.

    2009-07-01

    In the present work was investigated the effect of two milling parameters, atmosphere and milling time, on the morphology and microstructure of pure copper powder and a mixture of copper-2,5 wt. % lithium. The mechanical alloying was performed in a SPEX 8000D mill, using steel containers and balls. The two control atmospheres were argon and nitrogen and the milling time was varied from 3 up to 30 hours. The microstructural changes and the phases after milling were analyzed using scanning microscopy and X ray diffraction, whereas the amount of iron was measured by atomic absorption spectroscopy and the amount of oxygen by infrared spectroscopy. The results show the effect of the milling parameters studied on the microstructure as well as on the chemical composition of the samples. (Author) 22 refs.

  14. Influence of milling process in the surface energy of glass tile frits; Influencia de la molienda en la energia superficial de fritas para esmaltes

    Energy Technology Data Exchange (ETDEWEB)

    Tamayo, A.; Rubio, F.; Oteo, J. L.; Rubio, J.

    2013-05-01

    In this work has been studied the influence of the milling process of two ceramic frits used in the ceramic tile industry. Both glass frits were of similar chemical composition changing SiO{sub 2} by 5% of B{sub 2}O{sub 3} and both of them were water or dry milled. Glass frit surfaces were characterized by FT-IR, Karl-Fischer (K-F) titration and Inverse Gas Chromatography at Infinite Dilution (IGC-ID). By K-F titration it was observed that water milled frits presented 28 and 26 OH groups for 100 A{sup 2} if they do not contain or contain boron, respectively. These surface changes are also observed by IGC-ID. Thus, the glass frit without boron and dry milled presented the highest dispersive surface energy (44 mJ.m{sup -}2) and the less acidic constant (0.13 kJ.mol{sup -}1). Both glass frits are amphoteric with acidic and base surface active sites, and that frit without boron presents the higher basicity. Milling process influences in the acid-base surface characteristics of both frits by increasing the basicity for the one without boron and increasing for the other one. This has been assigned to the different location of hydroxyl groups where the higher interaction is the one that does not contain boron and dry milled as K-F results. (Author) 30 refs.

  15. Influence of milling process in the surface energy of glass tile frits; Influencia de la molienda en la energia superficial de fritas para esmaltes

    Energy Technology Data Exchange (ETDEWEB)

    Tamayo, A.; Rubio, F.; Otero, J. L.; Rubio, J.

    2013-06-01

    In this work has been studied the influence of the milling process of two ceramic frits used in the ceramic tile industry. Both glass frits were of similar chemical composition changing SiO{sub 2} by 5% of B{sub 2}O{sub 3} and both of them were water or dry milled. Glass frit surfaces were characterized by FT-IR, Karl-Fischer (K-F) titration and Inverse Gas Chromatography at Infinite Dilution (IGC-ID). By K-F titration it was observed that water milled frits presented 28 and 26 OH groups for 100 A{sup 2} if they do not contain or contain boron, respectively. These surface changes are also observed by IGC-ID. Thus, the glass frit without boron and dry milled presented the highest dispersive surface energy (44 mJ.m{sup -}2) and the less acidic constant (0.13 kJ.mol{sup -}1). Both glass frits are amphoteric with acidic and base surface active sites, and that frit without boron presents the higher basicity. Milling process influences in the acid-base surface characteristics of both frits by increasing the basicity for the one without boron and increasing for the other one. This has been assigned to the different location of hydroxyl groups where the higher interaction is the one that does not contain boron and dry milled as K-F results. (Author)

  16. The effect of calcination on reactive milling of anthracite as potential precursor for graphite production

    Energy Technology Data Exchange (ETDEWEB)

    Burgess-Clifford, Caroline E.; Van Essendelft, Dirk T. [The EMS Energy Institute, C211 Coal Utilization Laboratory, Penn State University, University Park, PA 16802 (United States); Narayanan, Deepa L. [Puget Sound Energy, 10885 NE 4th PSE-09S, Bellevue, WA 98004 (United States); Jain, Puja; Lueking, Angela D. [Department of Energy and Mineral Engineering, Pennsylvania State University, 120 Hosler, University Park, PA 16802 (United States); Sakti, Apurba [School of Earth Atmospheric and Environmental Sciences, University of Manchester, Manchester (United Kingdom)

    2009-12-15

    The effect of a pretreatment using reactive ball milling and calcination on the graphitizability of an anthracite coal is explored. A thermal anneal of Buck Mountain anthracite at 1400 C in argon increased the L{sub c} crystallite dimension (from 12 to 20 A) and led to an increase in the oxidation temperature of the product. Ball milling of the coal reduced particle size with a nominal effect on carbon order and the degree of graphitization after the 1400 C thermal anneal (L{sub c} from 18 to 29 A). Ball milling in cyclohexene led to a substantial increase in the graphitizability at 1400 C (L{sub c} from 12 to 50 A). The enhanced reactivity was due to both carbon structure and introduced metal. The products of the mechano-chemical pretreatment and thermal anneal consisted of nanographene ribbons and multi-walled nanopolyhedral particles. It oxidized at moderate temperatures and had a high (74.3%) degree of graphitization based on X-ray diffraction analysis; the derived material has potential as filler for production of graphite. (author)

  17. Electrocoagulation of palm oil mill effluent as wastewater treatment and hydrogen production using electrode aluminum.

    Science.gov (United States)

    Nasution, M Ansori; Yaakob, Z; Ali, Ehsan; Tasirin, S M; Abdullah, S R S

    2011-01-01

    Palm oil mill effluent (POME) is highly polluting wastewater generated from the palm oil milling process. Palm oil mill effluent was used as an electrolyte without any additive or pretreatment to perform electrocoagulation (EC) using electricity (direct current) ranging from 2 to 4 volts in the presence of aluminum electrodes with a reactor volume of 20 L. The production of hydrogen gas, removal of chemical oxygen demand (COD), and turbidity as a result of electrocoagulation of POME were determined. The results show that EC can reduce the COD and turbidity of POME by 57 and 62%, respectively, in addition to the 42% hydrogen production. Hydrogen production was also helpful to remove the lighter suspended solids toward the surface. The production of Al(OH)XHO at the aluminum electrode (anode) was responsible for the flocculation-coagulation process of suspended solids followed by sedimentation under gravity. The production of hydrogen gas from POME during EC was also compared with hydrogen gas production by electrolysis of tap water at pH 4 and tap water without pH adjustment under the same conditions. The main advantage of this study is to produce hydrogen gas while treating POME with EC to reduce COD and turbidity effectively.

  18. Color, TOC and AOX removals from pulp mill effluent by advanced oxidation processes: a comparative study.

    Science.gov (United States)

    Catalkaya, Ebru Cokay; Kargi, Fikret

    2007-01-10

    Pulp mill effluent containing toxic chemicals was treated by different advanced oxidation processes (AOPs) consisting of treatments by hydrogen peroxide, Fenton's reagent (H2O2/Fe2+), UV, UV/H2O2, photo-Fenton (UV/H2O2/Fe2+), ozonation and peroxone (ozone/H2O2) in laboratory-scale reactors for color, total organic carbon (TOC) and adsorbable organic halogens (AOX) removals from the pulp mill effluent. Effects of some operating parameters such as the initial pH, oxidant and catalyst concentrations on TOC, color, AOX removals were investigated. Almost every method used resulted in some degree of color removal from the pulp mill effluent. However, the Fenton's reagent utilizing H2O2/Fe2+ resulted in the highest color, TOC and AOX removals under acidic conditions when compared with the other AOPs tested. Approximately, 88% TOC, 85% color and 89% AOX removals were obtained by the Fenton's reagent at pH 5 within 30 min. Photo-Fenton process yielded comparable TOC (85%), color (82%) and AOX (93%) removals within 5 min due to oxidations by UV light in addition to the Fenton's reagent. Fast oxidation reactions by the photo-Fenton treatment makes this approach more favorable as compared to the others used.

  19. Synthesis and Characterizations of Nanocrystalline WC-Co Composite Powders by a Unique Ball Milling Process

    Institute of Scientific and Technical Information of China (English)

    Jun SHEN; Jianfei SUN; Faming ZHANG

    2004-01-01

    In order to explore the high efficiency of fabricating nanocrystalline WC-Co composite powders, this paper presented a unique high energy ball milling process with variable rotation rate and repeatious circulation, by which nanocrystalline WC-10Co0.8VC-0.2Cr3C2 (wt pct) composite powders with mean grain size of 25 nm were prepared in 32 min, and the quantity of the powders for a batch was as much as 800 grams. The as-prepared powders were analyzed and characterized by chemical analysis,X-ray diffraction (XRD), transmission electron microscopy (TEM) and differential thermal analysis (DTA). The results show that high energy ball milling with variable rotation rates and repeatious circulation could be used to produce nanocrystalline WC-Co powder composites with high efficiency. The compositions of the powders meet its specifications with low impurity content. The mean grain size decreases, lattice distortion and system energy increase with increasing the milling time. The morphology of nanocrystalline WC-Co particles displays dominantly sphere shape and their particle sizes are all lower than 80nm. The eutectic temperature of the nanocrystalline WC-10Co-0.8VC-0.2Cr3C2 composites is about 1280℃.

  20. Pilot scale nanofiltration treatment of olive mill wastewater: a technical and economical evaluation.

    Science.gov (United States)

    Sanches, S; Fraga, M C; Silva, N A; Nunes, P; Crespo, J G; Pereira, V J

    2016-11-22

    The treatment of large volumes of olive mill wastewater is presently a challenge. This study reports the technical and economical feasibility of a sequential treatment of olive mill wastewater comprising a dissolved air flotation pre-treatment and nanofiltration. Different pilot nanofiltration assays were conducted in a concentration mode up to different volume reduction factors (29, 45, 58, and 81). Data attained demonstrated that nanofiltration can be operated at considerably high volume reduction factors and still be effective towards the removal of several components. A flux decline of approximately 50% was observed at the highest volume reduction factor, mainly due to increase of the osmotic pressure. Considerably high rejections were obtained across all experiments for total suspended solids (83 to >99%), total organic carbon (64 to 99%), chemical oxygen demand (53 to 77%), and oil and grease (67 to >82%). Treated water was in compliance with European legal limits for discharge regarding total suspended solids and oil and grease. The potential recovery of phenolic compounds was evaluated and found not relevant. It was demonstrated that nanofiltration is economically feasible, involving operation costs of approximately 2.56-3.08 €/m(3), depending on the working plan schedule and volume reduction factor, and requiring a footprint of approximately 52 m(2) to treat 1000 m(3) of olive mill wastewater.

  1. The Potential in Bioethanol Production From Waste Fiber Sludges in Pulp Mill-Based Biorefineries

    Science.gov (United States)

    Sjöde, Anders; Alriksson, Björn; Jönsson, Leif J.; Nilvebrant, Nils-Olof

    Industrial production of bioethanol from fibers that are unusable for pulp production in pulp mills offers an approach to product diversification and more efficient exploitation of the raw material. In an attempt to utilize fibers flowing to the biological waste treatment, selected fiber sludges from three different pulp mills were collected, chemically analyzed, enzymatically hydrolyzed, and fermented for bioethanol production. Another aim was to produce solid residues with higher heat values than those of the original fiber sludges to gain a better fuel for combustion. The glucan content ranged between 32 and 66% of the dry matter. The lignin content varied considerably (1-25%), as did the content of wood extractives (0.2-5.8%). Hydrolysates obtained using enzymatic hydrolysis were found to be readily fermentable using Saccharomyces cerevisiae. Hydrolysis resulted in improved heat values compared with corresponding untreated fiber sludges. Oligomeric xylan fragments in the solid residue obtained after enzymatic hydrolysis were identified using matrix-assisted laser desorption ionization-time of flight and their potential as a new product of a pulp mill-based biorefinery is discussed.

  2. STUDY ON QUALITY PARAMETERS AND ENZYMATIC ACTIVITY OF GRAIN MILL PRODUCTS REGION IN TRANSYLVANIA

    Directory of Open Access Journals (Sweden)

    Glevitzky Mirel

    2011-07-01

    Full Text Available This paper aims at determining the main quality parameters of grain mill products in the Transylvania region, also studying and emphasizing the enzymatic activity of flour. Determination of quality characteristics of grain mill products entails establishing physical, chemical and sensory parameters and assessing them against the limits imposed by law. Analysis was performed on samples formed by mixing basic medium extracted from different batches. Incremental size, sampling tools, how to extract them, the training sample and laboratory environments, packaging and labeling of samples were performed according to STAS 1068 69. Determination of the fall (Falling Number, an empirical test that relies on the ability of endogenous ?-amylase to reduce viscosity of the treated warm flour suspension is used, large scale milling and bakery industry to predict and assess the Baking quality of flour. In sprouted wheat, characterised by a low Falling number, dextrin produced by the action of ?-amylase leads to a sticky bread core. Experiments suggest that the values fall turnover (FN does not shrink in direct proportion to the percentage of germinating seeds. Amylolytic activity depends on the stage of sprouting of grains. Lack of ?-amylase activity can be corrected by adding malt grain ?-amylase or fungal ?-amylase.

  3. FAILURE ANALYSIS IN TUBING OF AIR PREHEATER OF BOILER FROM A SUGARCANE MILL

    Directory of Open Access Journals (Sweden)

    Joner Oliveira Alves

    2014-10-01

    Full Text Available The increased demand for energy from sugarcane bagasse has made the sugar and alcohol mills search alternatives to reduce maintenance of the boilers, releasing more time to the production. The stainless steel use has become one of the main tools for such reduction. However, specification errors can lead to premature failures. This work reports the factors that led tubes of AISI 409 stainless steel fail after half season when applied in a air preheater of boiler from a sugarcane mill. In such application, the AISI 304 lasts about 15 seasons and the carbon steel about 3. A tube sent by the sugar mill was characterized by wet chemical analysis, optical microscopy and EDS. Results indicated chloride formation on the internal walls of the tube, which combined with the environment, accelerated the corrosion process. The carbon steel showed high lifetime due to a 70% higher thickness. Due to the work condictions is recommended the use of stainless steels with higher corrosion resistance, such as the traditional AISI 304 or the ferritic AISI 444, the last presents better thermal exchange.

  4. Focused-Ion-Beam-Milled Carbon Nanoelectrodes for Scanning Electrochemical Microscopy

    Science.gov (United States)

    Chen, Ran; Hu, Keke; Yu, Yun; Mirkin, Michael V.; Amemiya, Shigeru

    2016-01-01

    Nanoscale scanning electrochemical microscopy (SECM) has emerged as a powerful electrochemical method that enables the study of interfacial reactions with unprecedentedly high spatial and kinetic resolution. In this work, we develop carbon nanoprobes with high electrochemical reactivity and well-controlled size and geometry based on chemical vapor deposition of carbon in quartz nanopipets. Carbon-filled nanopipets are milled by focused ion beam (FIB) technology to yield a flat disk tip with a thin quartz sheath as confirmed by transmission electron microscopy. The extremely high electroactivity of FIB-milled carbon nanotips is quantified by enormously high standard electron-transfer rate constants of ≥10 cm/s for Ru(NH3)63+. The tip size and geometry are characterized in electrolyte solutions by SECM approach curve measurements not only to determine inner and outer tip radii of down to ~27 and ~38 nm, respectively, but also to ensure the absence of a conductive carbon layer on the outer wall. In addition, FIB-milled carbon nanotips reveal the limited conductivity of ~100 nm-thick gold films under nanoscale mass-transport conditions. Importantly, carbon nanotips must be protected from electrostatic damage to enable reliable and quantitative nanoelectrochemical measurements. PMID:27642187

  5. Analysis and pollution sources speculations of toxic gases in a secondary fiber paper mill.

    Science.gov (United States)

    Tong, Xin; Liu, Zhang; Chen, Xiao Q; Shen, Wen H

    2016-11-09

    This paper quantitatively investigates the compositions of the gaseous pollutants in the ambient air of a secondary fiber paper mill. Total volatile organic compounds (TVOC), formaldehyde (HCHO), sulfur compounds (H2S), and hydrocarbon compounds (CxHy) were analyzed on six sampling sites with photo-ionisation detector, acetylacetone spectrophotometric method, and gas detector. The results revealed that, the high levels of TVOC and CxHy were detected at the wet end of paper machine and the office area, respectively; all the H2S contents on the six sites exceeded the limit (0.06 mg m(-3)) seriously; the HCHO concentrations at other five sites were out of the limit (0.10 mg m(-3)) except for the wastewater treatment plant. Furthermore, the necessary discussions about the possible pollution sources were considered on the process flow, the chemical agents used, and the ambient conditions in the paper mill. For the sake of air pollution control in paper mills, these remarkable results and analysis lay some technical basis in the following researches that should attract more attentions.

  6. Phytoremediation of parboiled rice mill wastewater using water lettuce (Pistia stratiotes).

    Science.gov (United States)

    Mukherjee, Bidisha; Majumdar, Madhurina; Gangopadhyay, Amitava; Chakraborty, Sankar; Chaterjee, Debashish

    2015-01-01

    Phytoremediation is an emerging technology applied for treatment of wastewater. It is a suitable option notably in developing countries as it is simple, sustainable and cost effective. In the present lab-based batch study the free floating aquatic plant water lettuce (Pistia stratiotes) is used for treatment of parboiled rice mill wastewater having low pH, high chemical oxygen demand (COD), nitrogen, and phosphate. In raw rice mill wastewater (undiluted) growth of water lettuce is found to be inhibited. Later on, two different dilution approaches (raw and facultative pond effluent 1:1; raw and tap water 1:1) are applied in order to effectively use this technology. In all cases a control (without plant) is maintained to compare the performance with the Aquatic Plant based Treatment (APT) system. In the APT system results reveal that removal of soluble COD (SCOD), ammoniacal nitrogen (NH4-N), nitrate nitrogen (NO3-N), and soluble phosphorus (sol. P) are upto 65%, 98%, 70%, and 65% respectively. The study highlights the efficacy of water lettuce in removing organics and nutrients from parboiled rice mill wastewater.

  7. Removal of stigmasterol from Kraft mill effluent by aerobic biological treatment with steroidal metabolite detection.

    Science.gov (United States)

    Chamorro, Soledad; Vergara, Juan P; Jarpa, Mayra; Hernandez, Victor; Becerra, Jose; Vidal, Gladys

    2016-10-14

    Stigmasterol is a phytosterol contained in Kraft mill effluent that is able to increase over 100% after aerobic biological treatment. This compound can act as an endocrine disrupter as its structure is similar to that of cholesterol. The aim of this study was to evaluate the removal of stigmasterol from Kraft mill effluents treated by a moving bed biofilm reactor (MBBR) with steroidal metabolite detection. The MBBR was operated for 145 days, with a hydraulic retention time of 2 days. Stigmasterol and steroidal metabolites were detected by gas chromatography with a flame ionization detector during MBBR operation. The results show that the MBBR removed 87.4% of biological oxygen demand (BOD5), 61.5% of chemical oxygen demand (COD), 24.5% of phenol and 31.5% of lignin, expressed in average values. The MBBR system successfully removed 100% of the stigmasterol contained in the influent (33 µg L(-1)) after 5 weeks of operation. In that case, the organic load rate was 0.343 kg COD m(-3) d(-1). Furthermore, different steroidal compounds (e.g., testosterone propionate, stigmast-4-en-3-one, 5α-pregnan-12-one-20α-hydroxy, 5α-pregnane-3,11,20-trione and 3α-hydroxy-5α-androstane-11,17-dione were detected in the Kraft mill effluent as potential products of phytosterol biotransformation.

  8. Deformations of Yang-Mills theory

    CERN Document Server

    Cofano, Marco; Krasnov, Kirill

    2015-01-01

    We introduce and study a new class of power-counting non-renormalisable gauge theories in four space-time dimensions. The Lagrangian is an arbitrary function of the self-dual part of the field strength. The resulting perturbation theory has the property that whenever two derivatives act on an internal line propagator, the result is a delta-function and the line collapses to a point. This means that there remains at most one derivative on each internal line, which gives improved ulta-violet behaviour. For many purposes, this class of theories behaves just like ordinary Yang-Mills theory. In particular, they all share the Yang-Mills theory MHV amplitudes. Moreover, these theories remain constructible in the sense that higher-point tree level scattering amplitudes can be obtained from the lower-point amplitudes using the BCFW recursion relations. Also, the square of these gauge-theory amplitudes gives the scattering amplitudes of "deformations" of General Relativity, at least for the low particle numbers that we...

  9. Quantum Yang--Mills Dark Energy

    CERN Document Server

    Pasechnik, Roman

    2016-01-01

    In this short review, I discuss basic qualitative characteristics of quantum non-Abelian gauge dynamics in the non-stationary background of the expanding Universe in the framework of the standard Einstein--Yang--Mills formulation. A brief outlook of existing studies of cosmological Yang--Mills fields and their properties will be given. Quantum effects have a profound impact on the gauge field-driven cosmological evolution. In particular, a dynamical formation of the spatially-homogeneous and isotropic gauge field condensate may be responsible for both early and late-time acceleration, as well as for dynamical compensation of non-perturbative quantum vacua contributions to the ground state of the Universe. The main properties of such a condensate in the effective QCD theory at the flat Friedmann--Lema\\'itre--Robertson--Walker (FLRW) background will be discussed within and beyond perturbation theory. Finally, a phenomenologically consistent dark energy can be induced dynamically as a remnant of the QCD vacua co...

  10. Olive mill wastewater treatment: an experimental study.

    Science.gov (United States)

    Bettazzi, E; Morelli, M; Caffaz, S; Caretti, C; Azzari, E; Lubello, C

    2006-01-01

    Olive oil production, one of the main agro-industries in Mediterranean countries, generates significant amounts of olive mill wastewaters (OMWs), which represent a serious environmental problem, because of their high organic load, the acidic pH and the presence of recalcitrant and toxic substances such as phenolic and lipidic compounds (up to several grams per litre). In Italy, traditional disposal on the soil is the most common way to discharge OMWs. This work is aimed at investigating the efficiency and feasibility of AOPs and biological processes for OMW treatment. Trials have been carried out on wastewaters taken from one of the largest three-phase mills of Italy, located in Quarrata (Tuscany), as well as on synthetic solutions. Ozone and Fenton's reagents applied both on OMWs and on phenolic synthetic solutions guaranteed polyphenol removal efficiency up to 95%. Aerobic biological treatment was performed in a batch reactor filled with raw OMWs (pH = 4.5, T = 30 degrees C) without biomass inoculum. A biomass rich of fungi, developed after about 30 days, was able to biodegrade phenolic compounds reaching a removal efficiency of 70%. Pretreatment of OMWs by means of oxidation increased their biological treatability.

  11. Uranium Mill Tailings Remedial Action Project surface project management plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    This Project Management Plan describes the planning, systems, and organization that shall be used to manage the Uranium Mill Tailings Remedial Action Project (UMTRA). US DOE is authorized to stabilize and control surface tailings and ground water contamination at 24 inactive uranium processing sites and associated vicinity properties containing uranium mill tailings and related residual radioactive materials.

  12. Structural and magnetic properties of ball milled copper ferrite

    DEFF Research Database (Denmark)

    Goya, G.F.; Rechenberg, H.R.; Jiang, Jianzhong

    1998-01-01

    The structural and magnetic evolution in copper ferrite (CuFe2O4) caused by high-energy ball milling are investigated by x-ray diffraction, Mössbauer spectroscopy, and magnetization measurements. Initially, the milling process reduces the average grain size of CuFe2O4 to about 6 nm and induces ca...

  13. Stonecutter Mills, Inc., Isothermal Community College. PLATO Evaluation Series.

    Science.gov (United States)

    Sherman, Greg

    Stonecutter Mills, Inc., is a textile manufacturing company with a major production facility in Spindale, North Carolina. In the past few years, Stonecutter Mills employees have been given an opportunity to spend up to 2 hours a week on company time to participate in PLATO-supported learning at Isothermal Community College. Employees could choose…

  14. The MediaMill TRECVID 2010 semantic video search engine

    NARCIS (Netherlands)

    Snoek, C.G.M.; van de Sande, K.E.A.; de Rooij, O.; Huurnink, B.; Gavves, E.; Odijk, D.; de Rijke, M.; Gevers, T.; Worring, M.; Koelma, D.C.; Smeulders, A.W.M.

    2010-01-01

    In this paper we describe our TRECVID 2010 video retrieval experiments. The MediaMill team participated in three tasks: semantic indexing, known-item search, and instance search. The starting point for the MediaMill concept detection approach is our top-performing bag-of-words system of TRECVID 2009

  15. John Stuart Mill on Freedom, Education, and Social Reform.

    Science.gov (United States)

    Carbone, Peter F.

    1983-01-01

    Examines the social philosophy of John Stuart Mill, emphasizing his views on freedom, education, and social reform. Considers Mill's individualism and reformism, the conflict between freedom and control that characterizes his work, and the importance of freedom and education. Suggests caution in drawing educational implications from his work. (DAB)

  16. Dynamic Model of Gap Loop for HCW Mill

    Institute of Scientific and Technical Information of China (English)

    YANG Jing-ming; YANG Qiu-xia; CHE Hai-jun; CHANG Ling-fang

    2004-01-01

    The hydraulic automatic gauge control system using gap loop for cold mill was designed. The stiffness of HCW cold mill was defined for gap loop, and the dynamic model of gauge control system for gap loop was built with mechanism analysis. The stiffness for gap loop and the cylinder displacement loop were measured.

  17. 33 CFR 117.800 - Mill Neck Creek.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Mill Neck Creek. 117.800 Section 117.800 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements New York § 117.800 Mill Neck Creek. The draw of...

  18. 33 CFR 117.225 - Yellow Mill Channel.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Yellow Mill Channel. 117.225 Section 117.225 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements Connecticut § 117.225 Yellow Mill Channel....

  19. Improved hydrogen sorption kinetics in wet ball milled Mg hydrides

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Li

    2011-05-04

    In this work, wet ball milling method is used in order to improve hydrogen sorption behaviour due to its improved microstructure of solid hydrogen materials. Compared to traditional ball milling method, wet ball milling has benefits on improvement of MgH{sub 2} microstructure and further influences on its hydrogen sorption behavior. With the help of solvent tetrahydrofuran (THF), wet ball milled MgH{sub 2} powder has much smaller particle size and its specific surface area is 7 times as large as that of dry ball milled MgH{sub 2} powder. Although after ball milling the grain size is decreased a lot compared to as-received MgH{sub 2} powder, the grain size of wet ball milled MgH{sub 2} powder is larger than that of dry ball milled MgH{sub 2} powder due to the lubricant effect of solvent THF during wet ball milling. The improved particle size and specific surface area of wet ball milled MgH{sub 2} powder is found to be determining its hydrogen sorption kinetics especially at relatively low temperatures. And it also shows good cycling sorption behavior, which decides on its industrial applicability. With three different catalysts MgH{sub 2} powder shows improved hydrogen sorption behavior as well as the cyclic sorption behavior. Among them, the Nb{sub 2}O{sub 5} catalyst is found to be the most effective one in this work. Compared to the wet ball milled MgH{sub 2} powder, the particle size and specific surface area of the MgH{sub 2} powder with catalysts are similar to the previous ones, while the grain size of the MgH{sub 2} with catalysts is much finer. In this case, two reasons for hydrogen sorption improvement are suggested: one is the reduction of the grain size. The other may be as pointed out in some literatures that formation of new oxidation could enhance the hydrogen sorption kinetics, which is also the reason why its hydrogen capacity is decreased compared to without catalysts. After further ball milling, the specific surface area of wet ball milled Mg

  20. Observer-based Coal Mill Control using Oxygen Measurements

    DEFF Research Database (Denmark)

    Andersen, Palle; Bendtsen, Jan Dimon; S., Tom;

    2006-01-01

    This paper proposes a novel approach to coal flow estimation in pulverized coal mills, which utilizes measurements of oxygen content in the flue gas. Pulverized coal mills are typically not equipped with sensors that detect the amount of coal injected into the furnace. This makes control of the c......This paper proposes a novel approach to coal flow estimation in pulverized coal mills, which utilizes measurements of oxygen content in the flue gas. Pulverized coal mills are typically not equipped with sensors that detect the amount of coal injected into the furnace. This makes control...... into the furnace and oxygen concentration in the flue gas is designed to estimate the actual coal flow injected into the furnace. With this estimate, it becomes possible to close an inner loop around the coal mill itself, thus giving a better disturbance rejection capability. The approach is validated against...

  1. Simulation and Optimization of Turning-Milling Complex Machining

    Directory of Open Access Journals (Sweden)

    Shihong Guo

    2013-05-01

    Full Text Available In this study, the turning-milling complex processing simulation platform is established based on the simulation and optimization platform of VERICUT NC machining, with WFL M65 turning-milling complex machining center as the research object; taking barrel body parts as an example, the simulation machining and related process issues checking in machining process is made and the analysis and optimization of effect factors is made for processing efficiency. The application indicates that: the research results effectively realize the simulation of the turning-milling complex machining process and the correctness verification and process optimization of the NC machining program, improve the processing efficiency and the processing quality, well improve the application level of enterprise turning-milling complex machining center, promote the development of the turning-milling complex machining technology.

  2. Diamond micro-milling of lithium niobate for sensing applications

    Science.gov (United States)

    Huo, Dehong; Jie Choong, Zi; Shi, Yilun; Hedley, John; Zhao, Yan

    2016-09-01

    Lithium niobate (LiNbO3) is a crystalline material which is widely applied in surface acoustic wave, microelectromechanical systems (MEMS), and optical devices, owing to its superior physical, optical, and electronic properties. Due to its low toughness and chemical inactivity, LiNbO3 is considered to be a hard-to-machine material and has been traditionally left as as an inert substrate upon which other micro structures are deposited. However, in order to make use of its superior material properties and increase efficiency, the fabrication of microstructures directly on LiNbO3 is in high demand. This paper presents an experimental investigation on the micro machinability of LiNbO3 via micro milling with the aim of obtaining optimal process parameters. Machining of micro slots was performed on Z-cut LiNbO3 wafers using single crystal diamond tools. Surface and edge quality, cutting forces, and the crystallographic effect were examined and characterized. Ductile mode machining of LiNbO3 was found to be feasible at a low feed rate and small depth of cut. A strong crystallographic effect on the machined surface quality was also observed. Finally, some LiNbO3 micro components applicable to sensing applications were fabricated.

  3. Ash from a pulp mill boiler--characterisation and vitrification.

    Science.gov (United States)

    Ribeiro, Ana S M; Monteiro, Regina C C; Davim, Erika J R; Fernandes, M Helena V

    2010-07-15

    The physical, chemical and mineralogical characterisation of the ash resulting from a pulp mill boiler was performed in order to investigate the valorisation of this waste material through the production of added-value glassy materials. The ash had a particle size distribution in the range 0.06-53 microm, and a high amount of SiO(2) (approximately 82 wt%), which was present as quartz. To favour the vitrification of the ash and to obtain a melt with an adequate viscosity to cast into a mould, different amounts of Na(2)O were added to act as fluxing agent. A batch with 80 wt% waste load melted at 1350 degrees C resulting in a homogeneous transparent green-coloured glass with good workability. The characterisation of the produced glass by differential thermal analysis and dilatometry showed that this glass presents a stable thermal behaviour. Standard leaching tests revealed that the concentration of heavy metals in the leaching solution was lower than those allowed by the Normative. As a conclusion, by vitrification of batch compositions with adequate waste load and additive content it is possible to produce an ash-based glass that may be used in similar applications as a conventional silicate glass inclusively as a building ecomaterial.

  4. Value Added Products from Hemicellulose Utilization in Dry Mill Ethanol Plants

    Energy Technology Data Exchange (ETDEWEB)

    Rodney Williamson, ICPB; John Magnuson, PNNL; David Reed, INL; Marco Baez, Dyadic; Marion Bradford, ICPB

    2007-03-30

    The Iowa Corn Promotion Board is the principal contracting entity for this grant funded by the US Department of Agriculture and managed by the US Department of Energy. The Iowa Corn Promotion Board subcontracted with New Jersey Institute of Technology, KiwiChem, Pacific Northwest National Lab and Idaho National Lab to conduct research for this project. KiwiChem conducted the economic engineering assessment of a dry-mill ethanol plant. New Jersey Institute of Technology conducted work on incorporating the organic acids into polymers. Pacific Northwest National Lab conducted work in hydrolysis of hemicellulose, fermentation and chemical catalysis of sugars to value-added chemicals. Idaho National Lab engineered an organism to ferment a specific organic acid. Dyadic, an enzme company, was a collaborator which provided in-kind support for the project. The Iowa Corn Promotion Board collaborated with the Ohio Corn Marketing Board and the Minnesota Corn Merchandising Council in providing cost share for the project. The purpose of this diverse collaboration was to integrate the hydrolysis, the conversion and the polymer applications into one project and increase the likelihood of success. This project had two primary goals: (1) to hydrolyze the hemicellulose fraction of the distillers grain (DG) coproduct coming from the dry-mill ethanol plants and (2) convert the sugars derived from the hemicellulose into value-added co-products via fermentation and chemical catalysis.

  5. Preparation, characterization and optoelectronic properties of nanodiamonds doped zinc oxide nanomaterials by a ball milling technique

    Science.gov (United States)

    Ullah, Hameed; Sohail, Muhammad; Malik, Uzma; Ali, Naveed; Bangash, Masroor Ahmad; Nawaz, Mohsan

    2016-07-01

    Zinc oxide (ZnO) is one of the very important metal oxides (MOs) for applications in optoelectronic devices which work in the blue and UV regions. However, to meet the challenges of obtaining ZnO nanomaterials suitable for practical applications, various modifications in physico-chemical properties are highly desirable. One of the ways adopted for altering the properties is to synthesize composite(s) of ZnO with various reinforcements. Here we report on the tuning of optoelectronic properties of ZnO upon doping by nanodiamonds (NDs) using the ball milling technique. A varying weight percent (wt.%) of NDs were ball milled for 2 h with ZnO nanoparticles prepared by a simple precipitation method. The effects of different parameters, the calcination temperature of ZnO, wt.% of NDs and mechanical milling upon the optoelectronic properties of the resulting ZnO-NDs nanocomposites have been investigated. The ZnO-NDs nanocomposites were characterized by IR spectroscopy, powder x-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). The UV-vis spectroscopy revealed the alteration in the bandgap energy (Eg ) of ZnO as a function of the calcination temperature of ZnO, changing the concentration of NDs, and mechanical milling of the resulting nanocomposites. The photoluminescence (PL) spectroscopy showed a decrease in the deep level emission (DLE) peaks and an increase in near-band-edge transition peaks as a result of the increasing concentration of NDs. The decrease in DLE and increase in band to band transition peaks were due to the strong interaction between the NDs and the Zn+; consequently, the Zn+ concentration decreased on the interstitial sites.

  6. Tuning the length dispersion of multi-walled carbon nanotubes by ball milling

    Directory of Open Access Journals (Sweden)

    László Forró

    2013-09-01

    Full Text Available The statistical analysis of the length distribution of catalytic chemical vapour deposition synthesized multi-walled carbon nanotubes cut by planetary ball milling is reported. The nanotube lengths follow a log-normal distribution in a broad range of grinding time and rotational speed. We show that the scale parameter of the distribution, which equals the mean of the natural logarithm of the tube lengths, decreases linearly with the product of the duration time and the rotational speed. This relation can be used for tailoring nanotube lengths by a suitable choice of process parameters for a wide range of applications.

  7. Essential oil composition and antifungal activity of Foeniculum vulgare Mill obtained by different distillation conditions.

    Science.gov (United States)

    Mimica-Dukić, N; Kujundzić, S; Soković, M; Couladis, M

    2003-04-01

    The influence of different hydrodistillation conditions was evaluated from the standpoint of essential oil yield, chemical composition and antifungal activity from seeds of Foeniculum vulgare Mill. Three hydrodistillation conditions were considered. The main constituents of the oils were: (E)-anethole (72.27%-74.18%), fenchone (11.32%-16.35%) and methyl chavicol (3.78%-5.29%). The method of distillation significantly effected the essential oil yield and quantitative composition, although the antifungal activity of the oils against some fungi was only slightly altered.

  8. The Semi-Quantitative Study of Magnetization Process on Milling and Reannealing of Barium Hexaferrite (BaO.6Fe2O3

    Directory of Open Access Journals (Sweden)

    Ridwan

    2009-07-01

    Full Text Available Barium hexaferrite (BaO.6Fe2O3 is as a hard magnetic material with good chemical stability which has been intensively used as permanent magnet components. Many works have been done in order to improve their magnetic properties either through chemical process or powders metallurgy technique. In this work, commercial BaO.6Fe2O3 was milled using high-energy milling machine for 10, 20 and 30 hours and followed by reannealing for 3 hours at 1000⁰C in air. X-ray diffraction pattern indicate no phase decomposition occurred caused the mill processing, annealing of milled powders recovered the crystal system and promoted crystallite growth. The magnetic hysteresis curve measured by vibrating sample magnetometer (VSM shows the coercivity of annealed BaO.6Fe2O3 increases to two times higher than the original one. By using Jiles-Atherton model, all the hysteresis parameters Ms, k, α, a and c, have been determined adopted to the Genetic Algorithm (GA. The analyzed hysteretic parameters obtained from this work is congruent to the change of magnetic properties of as-milled and annealed powders of barium hexaferrite.

  9. Nanoscale characterisation and clustering mechanism in an Fe-Y{sub 2}O{sub 3} model ODS alloy processed by reactive ball milling and annealing

    Energy Technology Data Exchange (ETDEWEB)

    Brocq, M., E-mail: mathilde.brocq@cea.fr [CEA, DEN, DMN, Service de Recherches de Metallurgie Physique, F-91191 Gif-sur-Yvette (France); Radiguet, B.; Le Breton, J.-M.; Cuvilly, F.; Pareige, P. [Universite et INSA de Rouen, Groupe de Physique des Materiaux - UMR 6634 CNRS, 76801 Saint Etienne du Rouvray (France); Legendre, F. [CEA, DEN, DMN, Service de Recherches de Metallurgie Physique, F-91191 Gif-sur-Yvette (France)

    2010-03-15

    Reactive ball milling and annealing is proposed as a new production method for oxide dispersion strengthened (ODS) steels. A highly concentrated Fe-38 atm.% Y{sub 2}O{sub 3} ODS model alloy was processed by reactive ball milling and annealing of YFe{sub 3} and Fe{sub 2}O{sub 3} powders so as to induce the chemical reaction 2YFe{sub 3} + Fe{sub 2}O{sub 3} {yields} 8Fe + Y{sub 2}O{sub 3}. The model alloy was characterised after milling and annealing by complementary techniques, including atom probe tomography. Ball milling up to the stationary state results in the formation of two metastable nanometric interconnected phases: super-saturated {alpha}-iron and an yttrium and oxygen rich phase. Annealing leads the system towards equilibrium through: (i) a chemical evolution of each phase to nearly pure {alpha}-Fe and Y{sub 2}O{sub 3} oxide slightly sub-stoichiometric in oxygen; and (ii) growth of the phases. A pure iron matrix reinforced by nanometric Y{sub 2}O{sub 3} particles was successfully synthesised by reactive ball milling and annealing.

  10. Hybrid ABC Optimized MARS-Based Modeling of the Milling Tool Wear from Milling Run Experimental Data

    Directory of Open Access Journals (Sweden)

    Paulino José García Nieto

    2016-01-01

    Full Text Available Milling cutters are important cutting tools used in milling machines to perform milling operations, which are prone to wear and subsequent failure. In this paper, a practical new hybrid model to predict the milling tool wear in a regular cut, as well as entry cut and exit cut, of a milling tool is proposed. The model was based on the optimization tool termed artificial bee colony (ABC in combination with multivariate adaptive regression splines (MARS technique. This optimization mechanism involved the parameter setting in the MARS training procedure, which significantly influences the regression accuracy. Therefore, an ABC–MARS-based model was successfully used here to predict the milling tool flank wear (output variable as a function of the following input variables: the time duration of experiment, depth of cut, feed, type of material, etc. Regression with optimal hyperparameters was performed and a determination coefficient of 0.94 was obtained. The ABC–MARS-based model's goodness of fit to experimental data confirmed the good performance of this model. This new model also allowed us to ascertain the most influential parameters on the milling tool flank wear with a view to proposing milling machine's improvements. Finally, conclusions of this study are exposed.

  11. Chemical Emergencies

    Science.gov (United States)

    When a hazardous chemical has been released, it may harm people's health. Chemical releases can be unintentional, as in the case of an ... the case of a terrorist attack with a chemical weapon. Some hazardous chemicals have been developed by ...

  12. Phyto-Pharmacology of Ziziphus jujuba Mill- A plant review

    Directory of Open Access Journals (Sweden)

    R T Mahajan

    2009-01-01

    Full Text Available Herbs have always been the natural form of medicine in India. Medicinal plants have curative properties due to presence of various complex chemical substances of different composition which contain secondary metabolites such as alkaloids, flavonoids, terpenoids, saponin and phenolic compounds distributed in different parts of the plants. Ziziphus jujuba Mill, a member of the family Rhamnaceae, commonly known as Bor, is used traditionally as tonic and aphrodisiac and sometimes as Hypnotic-sedative and Anxiolytic, anticancer (Melanoma cells, Antifungal, Antibacterial, Antiulcer, Anti-inflammatory, Cognitive, Antispastic, Antifertility/contraception, Hypotensive and Antinephritic, Cardiotonic, Antioxidant, Immunostimulant, and Wound healing properties. It possesses allied compounds viz. Ascorbic acid, thiamine, riboflavin-bioflavonoids and Pectin A and various chemical substances like Mauritine-A; Amphibine-H; Jubanine-A; Jubanine-B; Mucronine-D and Nummularine-B. Sativanine-E. Frangufoline, Ziziphine-A to Q, betulinic acid colubrinic acid, alphitolic acid, 3-O-cis-p-coumaroylalphitolic acid, 3-O-transp-coumaroylalphitolic acid, 3-O-cis-p-coumaroylmaslinic acid, 3-O-trans-pcoumaroylmaslinic acid, oleanolic acid, betulonic acid, oleanonic acid, zizyberenalic acid and betulinic acid, jujubosides A, B, A1 B1 and C and acetyljujuboside B and the protojujubosides A, B and B1, saponin, ziziphin, from the dried leaves of Z. jujube - 3-O-a-L-rhamnopyranosyl (1-2-a-arabinopyranosyl-20-O- (2,3-di-O-acetyl-a-L-rhamnopyranosyl jujubogenin. Saponin from leaves and stem are 3-O- ((2-O- alpha - D - furopyranosyl - 3-O- beta - D -glucopyranosyl - alpha - L - arabinopyranosyl jujubogenin and (6′′′-sinapoylspinosin, 6′′′-feruloylspinosin and 6′′′-p-coumaroylspinosin. The present review discusses photo-chemistry, pharmacology, medicinal properties and biological activities of Za jujuba and its usage in different ailments.

  13. Characterization of steel mill electric-arc furnace dust.

    Science.gov (United States)

    Sofilić, Tahir; Rastovcan-Mioc, Alenka; Cerjan-Stefanović, Stefica; Novosel-Radović, Vjera; Jenko, Monika

    2004-06-18

    In order to make a complete characterization of electric-arc furnace (EAF) dust, as hazardous industrial waste, and to solve its permanent disposal and/or recovery, bearing in mind both the volumes formed in the Croatian steel industry and experiences of developed industrial countries, a study of its properties was undertaken. For this purpose, samples of EAF dust, taken from the regular production process in the Zeljezara Sisak Steel Mill between December 2000 and December 2001, were subjected to a series of tests. The chemical composition of EAF dust samples was investigated by means of a several different analytical methods. The results from the chemical analysis show that the approximate order of abundance of major elements in EAF dusts is as follows: Fe, Zn, Mn, Ca, Mg, Si, Pb, S, Cr, Cu, Al, C, Ni, Cd, As and Hg. Granular-metric composition of single samples was determined by applying sieve separation. Scanning electron micro-structural examination of EAF dust microstructure was performed and results indicated that all twelve EAF dusts were composed of solid spherical agglomerates with Fe, Zn, Pb, O, Si and Ca as the principal element. The investigation of grain morphology and the mineralogical composition of EAF dust were taken by combination of high resolution Auger electron spectroscopy (HR AES), X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction analysis. The analysis of XPS-spectra determined the presence of zinc in the form of ZnO phase and the presence of lead in the form of PbO phase, i.e. PbSO3/PbSO4 forms. The results of the X-ray diffraction phase analysis show that the basis of the examined EAF dust samples is made of a mixture of metal oxides, silicates and sulphates. The metal concentration, anions, pH value and conductivity in water eluates was determined in order to define the influence of EAF dust on the environment.

  14. Nonperturbative aspects of Yang-Mills theory

    Energy Technology Data Exchange (ETDEWEB)

    Schleifenbaum, Wolfgang

    2008-07-01

    The subject of this thesis is the theory of strong interactions of quarks and gluons, with particular emphasis on nonperturbative aspects of the gluon sector. Continuum methods are used to investigate in particular the confinement phenomenon. Confinement which states that the elementary quarks and gluons cannot be detected as free particles requires an understanding of large-scale correlations. In perturbation theory, only short-range correlations can be reliably described. A nonperturbative approach is given by the set of integral Dyson Schwinger equations involving all Green functions of the theory. A solution for the gluon propagator is obtained in the infrared and ultraviolet asymptotic limits. In chapter 1, redundant degrees of freedom of the Yang Mills gauge theory are removed by fixing the Weyl and Coulomb gauge prior to quantization. The constrained quantization in the Dirac bracket formalism is then performed explicitly to produce the quantized Yang Mills Hamiltonian. The asymptotic infrared limits of Coulomb gauge correlation functions are studied analytically in chapter 2 in the framework of the Gribov Zwanziger confinement scenario. The Coulomb potential between heavy quarks as part of the Yang Mills Hamiltonian is calculated in this limit. A connection between the infrared limits of Coulomb and Landau gauge is established. The Hamiltonian derived paves the way in chapter 3 for finding the Coulomb gauge vacuum wave functional by means of the variational principle. Numerical solutions for the propagators in this vacuum state are discussed and seen to reproduce the anticipated infrared limit. The discussion is extended to the vertex functions. The effect of the approximations on the results is examined. Chapter 4 is mainly devoted to the ultraviolet behavior of the propagators. The discussion is issued in both Coulomb and Landau gauge. A nonperturbative running coupling is defined and calculated. The ultraviolet tails of the variational solutions from

  15. Enzymatic corn wet milling: engineering process and cost model

    Directory of Open Access Journals (Sweden)

    McAloon Andrew J

    2009-01-01

    Full Text Available Abstract Background Enzymatic corn wet milling (E-milling is a process derived from conventional wet milling for the recovery and purification of starch and co-products using proteases to eliminate the need for sulfites and decrease the steeping time. In 2006, the total starch production in USA by conventional wet milling equaled 23 billion kilograms, including modified starches and starches used for sweeteners and ethanol production 1. Process engineering and cost models for an E-milling process have been developed for a processing plant with a capacity of 2.54 million kg of corn per day (100,000 bu/day. These models are based on the previously published models for a traditional wet milling plant with the same capacity. The E-milling process includes grain cleaning, pretreatment, enzymatic treatment, germ separation and recovery, fiber separation and recovery, gluten separation and recovery and starch separation. Information for the development of the conventional models was obtained from a variety of technical sources including commercial wet milling companies, industry experts and equipment suppliers. Additional information for the present models was obtained from our own experience with the development of the E-milling process and trials in the laboratory and at the pilot plant scale. The models were developed using process and cost simulation software (SuperPro Designer® and include processing information such as composition and flow rates of the various process streams, descriptions of the various unit operations and detailed breakdowns of the operating and capital cost of the facility. Results Based on the information from the model, we can estimate the cost of production per kilogram of starch using the input prices for corn, enzyme and other wet milling co-products. The work presented here describes the E-milling process and compares the process, the operation and costs with the conventional process. Conclusion The E-milling process

  16. Dry face milling of titanium alloys

    Institute of Scientific and Technical Information of China (English)

    Ahmed Hassan; Zhenqiang Yao

    2004-01-01

    In machining titanium alloys, cutting tools generally wear out very rapidly because of the high cutting temperature resulted from the low thermal conductivity and density of the work material. In order to increase the tool life, it is necessary to suppress the cutting heat as much as possible by applying an abundant amount of coolant, but this will entail serious techno-environmental and biological problems. To study the performance and avoid these limitations, a PVD-coated insert was used to the dry face mill of (α +β) titanium alloys. As a result it was found that the inserts exhibit an excellent cutting performance at low cutting speeds and feed rates, and there is no significant difference in the dominant insert failure mode between the wet and dry cutting in discontinuous cutting.

  17. Band Structure in Yang-Mills Theories

    CERN Document Server

    Bachas, Constantin

    2016-01-01

    We show how Yang-Mills theory on $S^3\\times R$ can exhibit a spectrum with continuous bands if coupled either to a topological 3-form gauge field, or to a dynamical axion with heavy Peccei-Quinn scale. The basic mechanism consists in associating winding histories to a bosonic zero mode whose role is to convert a circle in configuration space into a helix. The zero mode is, respectively, the holonomy of the 3-form field or the axion momentum. In these models different theta sectors coexist but are not mixed by local operators. Our analysis sheds light on, and extends Seiberg's proposal for modifying the topological sums in quantum field theories. It refutes a recent claim that $B+L$ violation at LHC is unsuppressed.

  18. Quantum Yang-Mills field theory

    Science.gov (United States)

    Frasca, Marco

    2017-01-01

    We show that the Dyson-Schwinger set of equations for the Yang-Mills theory can be exactly solved till the two-point function. This is obtained given a set of nonlinear waves solving the classical equations of motion. Translation invariance is maintained by the proper choice of the solution of the equation for the two-point function as devised by Coleman. The computation of the Dyson-Schwinger equations is performed in the same way as devised by Bender, Milton and Savage providing a set of partial differential equations whose proof of existence of the solutions is standard. So, the correlation functions of the theory could be proved to exist and the two-point function manifests a mass gap.

  19. Steel mill products analysis using qualities methods

    Directory of Open Access Journals (Sweden)

    B. Gajdzik

    2016-10-01

    Full Text Available The article presents the subject matter of steel mill product analysis using quality tools. The subject of quality control were bolts and a ball bushing. The Pareto chart and fault mode and effect analysis (FMEA were used to assess faultiness of the products. The faultiness analysis in case of the bolt enabled us to detect the following defects: failure to keep the dimensional tolerance, dents and imprints, improper roughness, lack of pre-machining, non-compatibility of the electroplating and faults on the surface. Analysis of the ball bushing has also revealed defects such as: failure to keep the dimensional tolerance, dents and imprints, improper surface roughness, lack of surface premachining as well as sharp edges and splitting of the material.

  20. Automatic Flatness Control of Cold Rolling Mill

    Science.gov (United States)

    Anbe, Yoshiharu; Sekiguchi, Kunio

    One of the subjects of cold rolling is a flatness of the rolled strip. Conventionally, measured strip flatness was approximated by polynomial (2th, 4th, 6th) equation across the entire strip width. This made it difficult to deal with desired loose edge or any desired flatness across the entire strip width. Also conventional flatness control was done for the entire strip width, so if there is a different flatness error among drive side and work side, conventional flatness control can not control properly. We propose independent strip flatness control among drive side and work side, and also automatic flatness control (AFC) system with arbitrary desired strip flatness. Also some applied results to cold mill are shown.

  1. Solid-solid and gas-solid interactions induced during high-energy milling to produce PbTe nanopowders

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: rojas_hugo@ittlahuac2.edu.mx [Instituto Tecnologico de Tlahuac - II (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM (Mexico); Garibay-Febles, V. [Instituto Mexicano del Petroleo, Laboratorio de Microscopia Electronica de Ultra Alta Resolucion (Mexico); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN (Mexico)

    2013-05-15

    Transformations from precursors to nanoparticles by high-energy milling are promoted by two major driving forces, namely physical and/or chemical. While the former has been difficult to trace since stress, strain and recovery may occur almost simultaneously during milling, the latter has been sequentially followed as an evolution from precursors to intermediate phases and thereof to high purity nanocrystals. The specific objective of this work is to discern how solid-solid and partially solid-gas reactions manifest themselves correspondingly as a short-range diffusion through an interface or how vapor species, as a subliming phenomenon, grows as a different phase on an active local surface. These series of changes were traced by sub-cooling the as-milled powders extracted during a milling cycle. Through this experimental technique, samples were electron microscopically analyzed and where it was required, selected area electron diffraction images were obtained. High-resolution transmission electron microscopy results, unambiguously, confirm that nanocrystals in the last stage show a cubic morphology which average size distributions are around 17 nm.

  2. Distribution of Fusarium mycotoxins in UK wheat mill fractions.

    Science.gov (United States)

    Edwards, S G; Dickin, E T; MacDonald, S; Buttler, D; Hazel, C M; Patel, S; Scudamore, K A

    2011-12-01

    The EU has set maximum limits for the Fusarium mycotoxins, deoxynivalenol (DON) and zearalenone (ZON). The maximum permitted level decreases from unprocessed wheat, through intermediary products, e.g. flour, to finished products such as bakery goods and breakfast cereals. It is, therefore, important to understand the effects of processing on the mycotoxin distribution in mill fractions. Between 2004 and 2007, samples were taken at commercial flour mills at various points in the milling process and analysed for trichothecenes and ZON. Samples with a range of mycotoxin concentrations harvested in 2004 and 2005 were processed in a pilot mill and the mycotoxins in the different mill fractions quantified. In the commercial samples, DON was the predominant mycotoxin with highest levels detected in the bran fraction. Analysis of the pilot mill fractions identified a significant difference between the two years and between mycotoxins. The proportion of DON and nivalenol in the mill fractions varied between years. DON and nivalenol were higher in flour fractions and lower in bran and offal in samples from 2004 compared to samples from 2005. This may be a consequence of high rainfall pre-harvest in 2004 resulting in movement of these mycotoxins within grains before harvest. There was no significant difference in the distribution of ZON within mill fractions between the two years. For DON, higher concentrations in the grain resulted in a greater proportion of DON within the flour fractions. Understanding the factors that impact on the fractionation of mycotoxins during milling will help cereal processors to manufacture products within legislative limits.

  3. Yang-Mills Instanton Sheaves with Arbitrary Topological Charges

    CERN Document Server

    Lai, Sheng-Hong; Lai, I-Hsun

    2016-01-01

    We use a set of ADHM 3-instanton data to systematically construct a class of SU(2) Yang-Mills instanton solutions with arbitrary topological charges. Moreover, by using the biquaternion calculation with biconjugation operation developed recently, these new ADHM data are used to construct a class of SL(2,C) Yang-Mills instanton sheaves on CP^3 with arbitrary topological charges k greater than 3. This result extends the previous construction of Yang-Mills 2-instanton sheaves to arbitrary higher k-instanton sheaves.

  4. Formation of ball-milled Fe-Mo nanostructured powders

    Energy Technology Data Exchange (ETDEWEB)

    Moumeni, H. [Laboratoire de Magnetisme et de Spectroscopie des Solides, LM2S, Departement de Physique, Faculte des Sciences, Universite de Annaba, B.P. 12, 23000 Annaba-Algerie (Algeria) and Departement de Physique, Faculte des Sciences et de l' Ingenierie, Universite de Guelma, B.P. 401, 24000 Guelma-Algerie (Algeria)]. E-mail: hmoumeni@yahoo.fr; Alleg, S. [Laboratoire de Magnetisme et de Spectroscopie des Solides, LM2S, Departement de Physique, Faculte des Sciences, Universite de Annaba, B.P. 12, 23000 Annaba-Algerie (Algeria); Greneche, J.M. [Laboratoire de Physique de l' Etat Condense, UMR CNRS 6087, Universite du Maine, Faculte des Sciences, F-72085, Le Mans Cedex 9 (France)

    2006-08-10

    Nanostructured Fe-6 wt.%Mo powders were prepared by mechanical alloying in a high-energy planetary ball-mill. The structural changes and the kinetics of Mo dissolution were studied by using X-ray diffraction. The crystallite size reduction down to about 11 nm is accompanied by the introduction of internal strains up to 1.1% (root-mean square strain, rms). After 24 h of milling, a bcc Fe(Mo) solid solution is formed. The kinetics of Mo dissolution into the Fe matrix during the milling process can be described by two regimes characterized by small values of Avrami parameter which do not exceed unit.

  5. The Parisi-Sourlas Mechanism in Yang-Mills Theory?

    CERN Document Server

    Magpantay, J A

    2000-01-01

    The Parisi-Sourlas mechanism is exhibited in pure Yang-Mills theory. Using the new scalar degrees of freedom derived from the non-linear gauge condition, we show that the non-perturbative sector of Yang-Mills theory is equivalent to a 4D O(1,3) sigma model in a random field. We then show that the leading term of this equivalent theory is invariant under supersymmetry transformations where (x^{2}+\\thetabar\\theta) is unchanged. This leads to dimensional reduction proving the equivalence of the non-perturbative sector of Yang-Mills theory to a 2D O(1,3) sigma model.

  6. Noncommutative Yang-Mills in IIB Matrix Model

    CERN Document Server

    Aoki, H; Iso, S; Kawai, H; Kitazawa, Y; Tada, T

    2000-01-01

    We show that twisted reduced models can be interpreted as noncommutative Yang-Mills theory. Based upon this correspondence, we obtain noncommutative Yang-Mills theory with D-brane backgrounds in IIB matrix model. We propose that IIB matrix model with D-brane backgrounds serve as a concrete definition of noncommutative Yang-Mills. We investigate D-instanton solutions as local excitations on D3-branes. When instantons overlap, their interaction can be well described in gauge theory and AdS/CFT correspondence. We show that IIB matrix model gives us the consistent potential with IIB supergravity when they are well separated.

  7. Frequency Modulation of High-Speed Mill Chatter

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Mill chatter is a common phenomenon in the metal strip rolling process. Product defects caused by mill vibration were reported worldwide during last two decades, which is usually classified as torque vibration of the driving system with low frequencies and vertical vibration of the mill stand with comparative higher frequencies. The frequency range of the vertical vibration is wide (in general from more than 100 Hz to more than 1 000 Hz), and the vibration phenomena are very complex, even it is very diffic...

  8. Simulation of type selection for 6-high cold tandem mill based on shape control ability

    Institute of Scientific and Technical Information of China (English)

    PENG Yan; LIU Hong-min; WANG Dong-cheng

    2007-01-01

    A theoretical method for selecting strip rolling mill type that considered shape control ability was established using the figure alteration range that was worked by the alteration track of vector expressing strip's cross section (crown) to express the shape control ability of rolling mill. With the mathematical models and simulation software that were developed by the authors' own models, four types of mills were aimed, including HCM (6-high middle rolls shift type HC (high crown) -mill), HCMW (6-high middle rolls and work rolls shift type HC-mill), UCM (6-high middle rolls shift type HC-mill with middle roll bender) and UCMW (6-high middle rolls and work rolls shift type HC-mill with middle roll bender), and the shape and crown control ability of every mill type was analyzed and compared. An appropriate arrangement mode of tandem mill was brought forward. The results show that UCMW mill is a perfect choice for controlling shape and crown, and the area of control characteristics curve of UCMW (or UCM) is twice than that of HCM, but UCM mill is also a good choice for its simple frame. In other word, the shape and crown controlling ability of UCMW mill is better than that of UCM mill, but the frame of UCM mill is simpler than that of UCMW mill. As for the final type of mill, should be synthetically decided by thinking over fund and equipment technology.

  9. Jet milling from a particle perspective : predicting particle fracture based on mechanical material properties

    NARCIS (Netherlands)

    Vegt, Onno Martinus

    2007-01-01

    Milling is a very old discipline originated in milling agricultural products to flour. Despite the enormous literature on size reduction, milling is a unit operation which has no sound underlying theory comparable to those existing for other unit operations. The design of milling equipment for a giv

  10. 29 CFR 1910.216 - Mills and calenders in the rubber and plastics industries.

    Science.gov (United States)

    2010-07-01

    ... in accordance with this section and Subpart S of this part. (4) Mill roll heights. All new mill...) Mill safety controls—(1) Safety trip control. A safety trip control shall be provided in front and in back of each mill. It shall be accessible and shall operate readily on contact. The safety trip...

  11. 75 FR 11153 - Main Mill Street Investments, LLC; Notice of Preliminary Permit Application Accepted for Filing...

    Science.gov (United States)

    2010-03-10

    ... Energy Regulatory Commission Main Mill Street Investments, LLC; Notice of Preliminary Permit Application.... On November 16, Main Mill Street Investments, LLC (Main Mill Street Investments) filed an application... feasibility of the Imperial Mill Dam Hydroelectric Project No. 13631, to be located at the existing...

  12. 46 CFR 50.25-5 - Products requiring manufacturer or mill certification.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Products requiring manufacturer or mill certification... manufacturer or mill certification. (a) Products required to be certified by a manufacturer or by mill... will not normally be subject to mill inspection by the Coast Guard except as required by § 50.25-7....

  13. Study on the Method for Collecting Vibration Signals from Mill Shell Based on Measuring the Fill Level of Ball Mill

    Directory of Open Access Journals (Sweden)

    Peng Huang

    2014-01-01

    Full Text Available At present the method for measuring the fill level which used the vibration signal of mill shell shows its advantage compared with other methods. However, this method is developed late, and the technique for collecting the vibration signal from mill shell is immature. In this paper, a novel method for collecting the vibration data from mill shell is proposed. Firstly, the layout scheme of vibration sensors on mill shell is given by analyzing the axial and circumferential movement of coal powder in roller. And a special data acquisition system is developed, which can acquire vibration data from different axial and circumferential positions on mill shell. Then the sampling frequency is obtained based on impact model and hierarchical model of steel balls. At the same time, the impact region on mill shell caused by steel balls is considered as the collecting region of vibration signals. Experimental result shows that vibration signals collected by the method proposed in this paper present a high sensitivity to the changes on fill level compared with vibration data of mill bearing, which provides a reliable basis for accurate measurement of the fill level.

  14. Hemicellulases in the bleaching of chemical pulps.

    Science.gov (United States)

    Suurnäkki, A; Tenkanen, M; Buchert, J; Viikari, L

    1997-01-01

    Hemicellulase-aided bleaching is the first full-scale biotechnical application in the pulp and paper industry which truly exploits the unique specificity and safety of biocatalysts. Hemicellulases are used to modify the structure of xylan and glucomannan in pulp fibers in order to enhance the chemical delignification. This technology can be combined with various types of kraft pulping processes and bleaching sequences. The aims of the enzymatic treatment depend on the actual mill conditions, and may be related to environmental demands, reduction of chemical costs, or maintenance or even improvement of product quality. The technology is applied on the mill scale in several countries. This review describes the principles of the enzyme-aided bleaching, the composition of the fiber substrates, the basic enzymology involved, and the present knowledge of the mechanisms of the action of enzymes, as well as the practical results and advantages obtained on the laboratory and industrial scale.

  15. Roll Gap Crown Adjustment Characteristics of 1700 mm Cold Rolling Mills

    Institute of Scientific and Technical Information of China (English)

    GUO Jian-bin

    2014-01-01

    The 4-hi cold mill is one of the key wide strip tandem cold rolling mills and has many advantages and characteristics. The mill type is the most important, fundamental and long-term effective factor for the strip shape control. Many advanced mill types such as CVC-4, HCW and PC-4, etc are created based on the conventional four-roll mill. The factors of mill type which affect the deformation of roll system, such as strip width, rolling force, bending force, work roll diameter, backup diameter and so on, are studied how to affect roll gap crown. It provides a good foundation for improving the shape performance of mill.

  16. Real-time and in situ monitoring of mechanochemical milling reactions.

    Science.gov (United States)

    Friščić, Tomislav; Halasz, Ivan; Beldon, Patrick J; Belenguer, Ana M; Adams, Frank; Kimber, Simon A J; Honkimäki, Veijo; Dinnebier, Robert E

    2013-01-01

    Chemical and structural transformations have long been carried out by milling. Such mechanochemical steps are now ubiquitous in a number of industries (such as the pharmaceutical, chemical and metallurgical industries), and are emerging as excellent environmentally friendly alternatives to solution-based syntheses. However, mechanochemical transformations are typically difficult to monitor in real time, which leaves a large gap in the mechanistic understanding required for their development. We now report the real-time study of mechanochemical transformations in a ball mill by means of in situ diffraction of high-energy synchrotron X-rays. Focusing on the mechanosynthesis of metal-organic frameworks, we have directly monitored reaction profiles, the formation of intermediates, and interconversions of framework topologies. Our results reveal that mechanochemistry is highly dynamic, with reaction rates comparable to or greater than those in solution. The technique also enabled us to probe directly how catalytic additives recently introduced in the mechanosynthesis of metal-organic frameworks, such as organic liquids or ionic species, change the reactivity pathways and kinetics.

  17. Capture and Sequestration of CO2 at the Boise White Paper Mill

    Energy Technology Data Exchange (ETDEWEB)

    B.P. McGrail; C.J. Freeman; G.H. Beeman; E.C. Sullivan; S.K. Wurstner; C.F. Brown; R.D. Garber; D. Tobin E.J. Steffensen; S. Reddy; J.P. Gilmartin

    2010-06-16

    This report documents the efforts taken to develop a preliminary design for the first commercial-scale CO2 capture and sequestration (CCS) project associated with biomass power integrated into a pulp and paper operation. The Boise Wallula paper mill is located near the township of Wallula in Southeastern Washington State. Infrastructure at the paper mill will be upgraded such that current steam needs and a significant portion of the current mill electric power are supplied from a 100% biomass power source. A new biomass power system will be constructed with an integrated amine-based CO2 capture plant to capture approximately 550,000 tons of CO2 per year for geologic sequestration. A customized version of Fluor Corporation’s Econamine Plus™ carbon capture technology will be designed to accommodate the specific chemical composition of exhaust gases from the biomass boiler. Due to the use of biomass for fuel, employing CCS technology represents a unique opportunity to generate a net negative carbon emissions footprint, which on an equivalent emissions reduction basis is 1.8X greater than from equivalent fossil fuel sources (SPATH and MANN, 2004). Furthermore, the proposed project will offset a significant amount of current natural gas use at the mill, equating to an additional 200,000 tons of avoided CO2 emissions. Hence, the total net emissions avoided through this project equates to 1,100,000 tons of CO2 per year. Successful execution of this project will provide a clear path forward for similar kinds of emissions reduction that can be replicated at other energy-intensive industrial facilities where the geology is suitable for sequestration. This project also represents a first opportunity for commercial development of geologic storage of CO2 in deep flood basalt formations. The Boise paper mill site is host to a Phase II pilot study being carried out under DOE’s Regional Carbon Partnership Program. Lessons learned from this pilot study and other separately

  18. Terpenoid variations within and among half-sibling avocado trees, Persea americana Mill. (Lauraceae).

    Science.gov (United States)

    Niogret, Jerome; Epsky, Nancy D; Schnell, Raymond J; Boza, Edward J; Kendra, Paul E; Heath, Robert R

    2013-01-01

    Chemical analyses were conducted to determine the qualitative and quantitative differences in monoterpenes and sesquiterpenes in plant material from avocado trees, Persea americana Mill. (Lauraceae). The initial study analyzed plant material sampled from the trunk to the leaves through different branch diameters to quantify proximo-distal spatial differences within a tree. All trees were seedlings initiated from a single maternal tree. Two-way analysis of variance was conducted on 34 chemicals that comprised at least 3% of the total chemical content of at least one tree and/or location within a tree. There were significant interactions between genotype and location sampled for most chemicals. Parentage analysis using microsatellite molecular markers (SSR's) determined that the four trees had three fathers and that they represented two full-siblings and two half-sibling trees. Descriptive discriminant analysis found that both genotype and location within a tree could be separated based on chemical content, and that the chemical content from full-siblings tended to be more similar than chemical content from half-siblings. To further explore the relationship between genetic background and chemical content, samples were analyzed from leaf material from 20 trees that included two sets of full-sibling seedling trees, the maternal tree and the surviving paternal tree. Descriptive discriminant analysis found good separation between the two full-sibling groups, and that the separation was associated with chemistry of the parental trees. Six groups of chemicals were identified that explained the variation among the trees. We discuss the results in relation to the discrimination process used by wood-boring insects for site-selection on host trees, for tree selection among potential host trees, and the potential use of terpenoid chemical content in chemotaxonomy of avocado trees.

  19. Terpenoid variations within and among half-sibling avocado trees, Persea americana Mill. (Lauraceae.

    Directory of Open Access Journals (Sweden)

    Jerome Niogret

    Full Text Available Chemical analyses were conducted to determine the qualitative and quantitative differences in monoterpenes and sesquiterpenes in plant material from avocado trees, Persea americana Mill. (Lauraceae. The initial study analyzed plant material sampled from the trunk to the leaves through different branch diameters to quantify proximo-distal spatial differences within a tree. All trees were seedlings initiated from a single maternal tree. Two-way analysis of variance was conducted on 34 chemicals that comprised at least 3% of the total chemical content of at least one tree and/or location within a tree. There were significant interactions between genotype and location sampled for most chemicals. Parentage analysis using microsatellite molecular markers (SSR's determined that the four trees had three fathers and that they represented two full-siblings and two half-sibling trees. Descriptive discriminant analysis found that both genotype and location within a tree could be separated based on chemical content, and that the chemical content from full-siblings tended to be more similar than chemical content from half-siblings. To further explore the relationship between genetic background and chemical content, samples were analyzed from leaf material from 20 trees that included two sets of full-sibling seedling trees, the maternal tree and the surviving paternal tree. Descriptive discriminant analysis found good separation between the two full-sibling groups, and that the separation was associated with chemistry of the parental trees. Six groups of chemicals were identified that explained the variation among the trees. We discuss the results in relation to the discrimination process used by wood-boring insects for site-selection on host trees, for tree selection among potential host trees, and the potential use of terpenoid chemical content in chemotaxonomy of avocado trees.

  20. Synthesis of Fe3O4 nanoparticles by wet milling iron powder in a planetary ball mill

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Fe3O4 nanoparticles with sizes ranging from 30 to 80nm were synthesized by wet milling iron powders in a planetary ball mill. The phase composition and the morphologies of the as-synthesized products were measured by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Nanosized Fe3O4 particles were prepared by wet milling metallic iron powder (-200 mesh, 99%)rotation speed of 300 rpm. The use of the iron balls in this method played a key role in Fe3O4 formation. The present technique is simple and the process is easy to carry out.

  1. Flatness and Profile Integration Control Model for Tandem Cold Mills

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Using the effective matrix methods of flatness and profile control synthetically, the flatness and profile in- tegration control scheme for tandem cold mills is built in order to increase flatness and profile control precision of tan- dem cold mills. Corresponding control strategies are adopted for various control objectives of different stands and the coordination control strategies of various stands are given, which makes the on-line flatness control cooperate with on-line profile control and implements the parallel control of different stands. According to the measured flatness and profile data of some 1550 mm tandem cold mills, the control scheme is verified and the result indicates that the scheme has high flatness and profile control precision with steady and reliable control process. A new way and method is supplied for researching shade control of tandem cold mills.

  2. Raske retk, mille auhinnaks on veelgi raskem retk / Mihkel Loide

    Index Scriptorium Estoniae

    Loide, Mihkel

    2004-01-01

    Ülevaade Valgamaal 14.-15. mail 2004 toimunud Kaitseliidu-sisesest Eel-Erna patrullvõistlusest, mille tulemusena selgusid Erna retkest osavõtjad. Tabel: Kaitseliidu patrullvõistluse Eel-Erna 2004 lõpuprotokoll

  3. Nanocrystalline Al Composites from Powder Milled under Ammonia Gas Flow

    Directory of Open Access Journals (Sweden)

    J. Cintas

    2014-01-01

    Full Text Available The production of high hardness and thermally stable nanocrystalline aluminium composites is described. Al powder was milled at room temperature in an ammonia flow for a period of less than 5 h. NH3 dissociation during milling provokes the absorption, at a high rate, of nitrogen into aluminium, hardening it by forming a solid solution. Controlled amounts of AlN and Al5O6N are formed during the subsequent sintering of milled powders for consolidation. The pinning action of these abundant dispersoids highly restrains aluminium grain growth during heating. The mean size of the Al grains remains below 45 nm and even after the milled powder is sintered at 650°C for 1 h.

  4. Research on product size and grinding dynamics of vibration mills

    Institute of Scientific and Technical Information of China (English)

    YIN Zhong-jun; HAN Tian; CHEN Bing; ZHANG Wen-zhong

    2007-01-01

    In order to improve vibration mills grinding effect and increase productive efficiency, prime factors of vibration mills were gained much attention. The purpose of this study is to reveal product size distribution and grinding dynamics of vibration mills by orthogonal experi-ments. The metallurgical refractory materials were used as research object. In order to explore the relationships between grinding effect and primary factors, lots of milling experiments were carried out. Based on the results, the conclusions can be summarized: as time runs, the size distri-bution shows exponential trend, and range becomes more and more narrow. Also the quantitative analysis result between grinding effect and primary factors was obtained by non-linear regres-sion: high frequency, high amplitude and low fill ratio can increase grinding speed.

  5. Genetic Evolutionary Approach for Cutting Forces Prediction in Hard Milling

    Science.gov (United States)

    Taylan, Fatih; Kayacan, Cengiz

    2011-11-01

    Hard milling is a very common used machining procedure in the last years. Therefore the prediction of cutting forces is important. The paper deals with this prediction using genetic evolutionary programming (GEP) approach to set mathematical expression for out cutting forces. In this study, face milling was performed using DIN1.2842 (90MnCrV8) cold work tool steel, with a hardness of 61 HRC. Experimental parameters were selected using stability measurements and simulations. In the hard milling experiments, cutting force data in a total of three axes were collected. Feed direction (Fx) and tangential direction (Fy) cutting forces generated using genetic evolutionary programming were modelled. Cutting speed and feed rate values were treated as inputs in the models, and average cutting force values as output. Mathematical expressions were created to predict average Fxand Fy forces that can be generated in hard material milling.

  6. Cylindrically symmetric Einstein-Yang-Mills-Higgs gauge configurations.

    Science.gov (United States)

    Mondaini, R. P.

    1985-02-01

    Two solutions are obtained for coupled Einstein-Yang-Mills-Higgs fields with cylindrical symmetry and rigid rotation. The Higgs fields are responsible for the creation of singularities and infinite energy densities at the cylinder's axis.

  7. In-Orbit Construction with a Helical Seam Pipe Mill

    Science.gov (United States)

    Gilhooley, N.

    The challenges of building large structures in space, and in particular a torus habitat, require novel processes. One potential method is to manufacture helical seam (also called spiral) pipe in orbit using a pipe mill. These machines turn rolls of steel or alloy into fully formed, welded and inspected pipe, pressure vessels and silos of various diameters. Pipe mills are highly automated and efficient in a factory environment and are increasingly being used for in-situ repair. By constructing in-orbit (on-orbit assembly) the launch vehicle can supply full payloads of compact, robust rolls of material; and the installation design is less restricted by fairing constraints and modular limitations. The use of a pipe mill is discussed as a possible construction method, for comparison an example design envelope is shown and further pipe mill products are considered.

  8. John Stuart Mill, labour issue and the problem of socialism

    Directory of Open Access Journals (Sweden)

    Đurković Miša

    2006-01-01

    Full Text Available The topic of this article is the analysis of Mill's attitude to socialism The author starts from the contemporary libertarian dogma about Mill as the spoiler of liberalism who supposedly turned this ideology towards socialist trends. The detailed and taxonomic analysis based on Mill's Principles of Political Economy and Chapters on Socialism shows that this theory in not correct; that the opposite is true - Mill actually, as the first serious critic of socialism, set all the relevant arguments which the liberal theory would later use to challenge this rival ideology. The emphasis is placed on the problems of redistribution and extension of the right to vote, but the author also tackles the issues of corporations, protectionism and tax policy.

  9. Gravity as the square of Yang-Mills?

    CERN Document Server

    Borsten, L

    2016-01-01

    In these lectures we review how the symmetries of gravitational theories may be regarded as originating from those of "Yang-Mills squared". We begin by motivating the idea that certain aspects of gravitational theories can be captured by the product, in some sense, of two distinct Yang-Mills theories, particularly in the context of scattering amplitudes. We then introduce a concrete dictionary for the covariant fields of (super)gravity in terms of the product of two (super) Yang-Mills theories. The dictionary implies that the symmetries of each (super) Yang-Mills factor generate the symmetries of the corresponding (super)gravity theory: general covariance, $p$-form gauge invariance, local Lorentz invariance, local supersymmetry, R-symmetry and U-duality.

  10. Microbiological treatment of oil mill waste waters

    Directory of Open Access Journals (Sweden)

    Ranalli, A.

    1992-02-01

    Full Text Available Experiments of the biological treatment of the oil mill waste waters, deriving from continuous system, have been carried out with selected mutant ferments, adapted to rather forced toxic conditions. The commercial microbio formulations SNKD, LLMO and PSBIO have been utilized; the last two are liquid suspensions, constituted by living micro-organisms that, in contrast to those frozen or lyophilized, do not need be revitalized before their use and became completely active in short time. The experiments with the SNKD biological preparation were carried out both on filtered oil mill outflows (type A with an initial COD of approximately 43 g/l and on waste water dephenolized by Caro-acid (type B with a COD equal to 30 g/l. The experiments with LLMO and PSBIO complexes were conduced both on oil mill outflows filtered and diluted (ratio 1:0.5 with an initial COD equal to 44 g/l (type C, and on waste water that were filtered and preventatively subjected to a cryogenic treatment (type D, with an initial COD of approximately 22 g/l. The residual COD with the microbio formulation SNKD, was about 15 g/l (type A and 5 g/l (type B; with the PSBIO It was about 7 g/l (type C and 1.5 g/l (type D; with the microbio formulation LLMO it resulted in 6 g/l (type C and 1.3 g/l (type D.

    Han sido efectuadas pruebas de tratamiento biológico de alpechines, provenientes de sistemas continuos, con fermentos seleccionados adaptados a condiciones de toxicidad muy elevadas. Han sido utilizadas las formulaciones microbianas SNKD, LLMO y PSBIO; las dos últimas son suspensiones líquidas, constituidas por microorganismos vivos, los cuales a diferencia de los liofilizados o congelados, no deben ser revitalizados antes del uso; estos tienen una fase «lag» más breve y entran antes en completa actividad. Las pruebas con la preparación biológica SNKD han sido efectuadas en los alpechines filtrados (tipo A con DQO inicial alrededor de 43 g/l, y también con alpech

  11. Power generation and export: a new strategy for the survival of the Kamloops pulp mill

    OpenAIRE

    Ryan, Anthony John

    2006-01-01

    This paper presents a new strategy for survival of the Kamloops Cellulose Fibers softwood pulp mill. The mill currently competes exclusively in the North American softwood segment of the global kraft market, and is not generating returns sufficient to cover the cost of capital. The mill?s boilers need replacing or rebuilding in five years and the mill faces a more stringent environmental permit. Pressures on production costs make it increasingly difficult to continue operating profitably. By ...

  12. Jet milling from a particle perspective: predicting particle fracture based on mechanical material properties

    OpenAIRE

    Vegt, Onno Martinus

    2007-01-01

    Milling is a very old discipline originated in milling agricultural products to flour. Despite the enormous literature on size reduction, milling is a unit operation which has no sound underlying theory comparable to those existing for other unit operations. The design of milling equipment for a given application is based on accumulated experiences of the manufactures. It is not for lack of either interest or investigation that a quantitative theory of milling does not exist. In contrast, the...

  13. A Qualitative Approach of Identifying Major Cost Influencing Factors in Palm Oil Mills and the Relations towards Production Cost of Crude Palm Oil

    Directory of Open Access Journals (Sweden)

    Elaine L.Y. Man

    2011-01-01

    Full Text Available Problem statement: The oil palm industry, which heavily depends on the world market, is an export oriented industry. Worlds palm oil consumption was growing over the years. In addition, Indonesia and Malaysia dominated the oil palm industry. The oil palm industry in Malaysia is very competitive and become one of the major economic sectors contributing to the total revenue of the country. In year 2009, there was a total of 22.40 million tons of oil palm products including palm oil, palm kernel oil, palm kernel cake, oleo-chemicals and finished products, equivalent to RM 49.59 billion of export revenue. However, cost of production for Crude Palm Oil (CPO varies in a big gap. Therefore, it is essential to identify the major cost influencing factors in the production of CPO. Approach: The study system started with collection of Fresh Fruits Bunches (FFB from oil palm plantation to the production of CPO at palm oil mills. Two palm oil mills of different production capacity were chosen for this study. Statistical analysis was done to identify the major cost influencing factors of production cost for CPO. Results: The production cost of CPO for small scale palm oil mills preferably lied between RM 45 to RM 50 per metric tons while large scale palm oil mills lied below RM 45 per metric tons. Conclusion: Palm oil mills with higher production capacity were efficient in producing CPO than lower production capacity palm oil mills. Thus, the production cost of CPO was lower compared to that of small scale palm oil mills.

  14. Mechano-activated surface modification of calcium carbonate in wet stirred mill and its properties

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Surface modification of calcium carbonate particles using sodium stearate(SDS) as a modification agent incorporated with the simultaneous wet ultra-fine grinding in the laboratory stirred mill was investigated. The physical properties and application properties of modified calcium carbonate were measured and evaluated. The action mechanism between SDS and calcium carbonate in the modification was studied by infrared spectrometry(IR) and X-ray photoelectron energy spectroscopy(XPS). The results indicate that the crushing mechanic force intensity can obviously influence the modification effect of calcium carbonate because of mechano-chemical effect. The hydrophilic surface of calcium carbonate is turned into hydrophobic after modification. The properties of polyethylene(PE) filled by modified calcium carbonate powder is markedly improved. And the adsorption of SDS could occur by chemical reaction with calcium carbonate surface.

  15. Ozone treatment of olive mill wastewater; Tratamiento con ozono de las aguas residuales de almazara

    Energy Technology Data Exchange (ETDEWEB)

    Beltran de Heredia Alonso, J.; Torregrosa Anton, J.; Garcia Rodriguez, J.; Dominguez Vargas, J. R. [Universidad de Extremadura. Badajoz (Spain)

    2000-07-01

    In the present work, the ozonization of olive mill wastewater has been studied. The evolution process was followed by measuring the chemical oxygen demand, the aromaticity and the contents of phenolic compounds. The aromaticity conversion ranged between 4.85 and 21% chemical oxygen demand degradation varied from 3.25 to 19.4% and the total polyphenolic reduction varied between 6.86 and 43.7%. The ozone consumption in the reduction of each variable was determined, being the average values of 57.2 g COD/mol O{sub 3} 2.9 un. Abs/mol O{sub 2} and 3.3 g poly phen./mol O{sub 3}. Finally, considering a first order kinetic equation with respect to each reactant, the apparent kinetic constants are evaluated for the studied variables. (Author) 19 refs.

  16. Impact of Modal Parameters on Milling Process Chatter Stability Lobes

    Institute of Scientific and Technical Information of China (English)

    LI Zhongqun; LIU Qiang

    2006-01-01

    Modals of the machine/tool and machine/part system are the principal factors affecting the stability of a milling process. Based on the modeling of chatter stability of milling process, the influence of modal parameters on chatter stability lobes independently or jointly has been analyzed by simulation. Peak-to-valley specific value, lobe coefficient and the corresponding calculation formula have been put forward. General laws and steps of modal simplification for multimodality system have been summarized.

  17. Calculation Method for Media in Ball Mills by Layers

    Institute of Scientific and Technical Information of China (English)

    徐志强; 张荣曾; 曾鸣

    2002-01-01

    Based on analyzing the moving principle of media in ball mill, it is implicated that there is the significant difference of movement situation among each single layer. A new method to calculate each single was put forward. The results from lab experiment and actual data from 26 sets industrial mills state indicate that the new calculation method reaches the high accuracy with excellent practicab ility.

  18. A QCD Model Using Generalized Yang-Mills Theory

    Institute of Scientific and Technical Information of China (English)

    WANG Dian-Fu; SONG He-Shan; KOU Li-Na

    2007-01-01

    Generalized Yang-Mills theory has a covariant derivative,which contains both vector and scalar gauge bosons.Based on this theory,we construct a strong interaction model by using the group U(4).By using this U(4)generalized Yang-Mills model,we also obtain a gauge potential solution,which can be used to explain the asymptotic behavior and color confinement.

  19. Exact solutions for classical Yang-Mills fields

    OpenAIRE

    2014-01-01

    We provide a set of exact solutions of the classical Yang-Mills equations. They have the property to satisfy a massive dispersion relation and hold in all gauges. These solutions can be used to describe the vacuum of the quantum Yang-Mills theory and so, they provide a general framework to build a quantum field theory. The components of the field become separated on a generic gauge but are all equal just in the Lorenz (Landau) gauge.

  20. Modeling for driving systems of four-high rolling mill

    Institute of Scientific and Technical Information of China (English)

    贺建军; 喻寿益; 钟掘

    2002-01-01

    A modeling method for driving systems of four-high rolling mill was put forward in order to analyze the origin of rolling mill's chatter that brings about light and shade streaks on the surface of steel strip from aspect of electromechanical coupling. The process and steps of modeling method was introduced by means of an example. The correctness of the model and the feasibility of the modeling method were verified in simulation experiment.

  1. Mineral-vegetal co-milling: An effective process to improve lignocellulosic biomass fine milling and to increase interweaving between mixed particles.

    Science.gov (United States)

    Motte, J-C; Delenne, J-Y; Rouau, X; Mayer-Laigle, C

    2015-09-01

    Fine-milling is a crucial objective for lignocellulosic biomass valorization. Co-milling appears to be a promising technique to improve its efficiency. However, the mechanisms occurring while co-milling remain poorly understood. In this study, an experimental work was performed to produce co-milled powders from both lignocellulosic (wheat, straw or pine sawdust) and mineral materials (limestone, quartzite or tile) with very contrasted physicochemical properties. The main consequences of co-milling were studied for both materials. A two-component mixing law for the prediction of the blend properties was proposed (particle sizes and true densities) to highlight the gain of this single processing step compared to separate milling and mixing. The predicted values were compared with experimental data for co-milled powders at 7 biomass contents from 0% to 100%. In all cases, co-milling leads to a reduction in particle size of lignocellulosic materials and create strong interweaving with mineral particles.

  2. Jet milling effect on wheat flour characteristics and starch hydrolysis.

    Science.gov (United States)

    Angelidis, Georgios; Protonotariou, Styliani; Mandala, Ioanna; Rosell, Cristina M

    2016-01-01

    The interest for producing wheat flour with health promoting effect and improved functionality has led to investigate new milling techniques that can provide finer flours. In this study, jet milling treatment was used to understand the effect of ultrafine size reduction onto microstructure and physicochemical properties of wheat flour. Three different conditions of jet milling, regarding air pressure (4 or 8 bars) feed rate and recirculation, were applied to obtain wheat flours with different particle size (control, F1, F2 and F3 with d50 127.45, 62.30, 22.94 and 11.4 μm, respectively). Large aggregates were gradually reduced in size, depending on the intensity of the process, and starch granules were separated from the protein matrix. Damaged starch increased while moisture content decreased because of milling intensity. Notable changes were observed in starch hydrolysis kinetics, which shifted to higher values with milling. Viscosity of all micronized samples was reduced and gelatinization temperatures (To, Tp, Tc) for F2 and F3 flours increased. Controlling jet milling conditions allow obtaining flours with different functionality, with greater changes at higher treatment severity that induces large particle reduction.

  3. A study on rheological characteristics of roller milled fenugreek fractions.

    Science.gov (United States)

    Sakhare, Suresh D; Inamdar, Aashitosh A; Prabhasankar, P

    2016-01-01

    Fenugreek seeds were fractionated by roller milling to get various fractions. The roller milled fractions and whole fenugreek flour (WFF) were evaluated for the flow behavior and time-dependent flow properties using a rotational viscometer at the temperatures of 10-60 (0)C. The samples subjected to a programmed shear rate increase linearly from 0 to 300 s(-1) in 3 min and successive decrease linearly shear rate from 300 s(-1) to 0 in 3 min. The roller milled fractions and WFF paste exhibited non-Newtonian pseudoplastic behavior. Difference in hysteresis loop area was observed among the roller milled fractions and WFF, being more noticeable at lower temperatures. Power law and Casson models were used to predict flow properties of samples. The power law model described well the flow behavior of the roller milled fractions and WFF at temperatures tested. Except flour (FL) fraction, consistency coefficient, m, increased with the temperature both in the forward and backward measurements. The roller milled fractions and WFF exhibited rheopectic behavior that increased viscosity with increasing the shear speed and the temperature. For all the sample tested, initial shear stress increased with increase in shear rate and temperature.

  4. Land Application-Based Olive Mill Wastewater Μanagement

    Directory of Open Access Journals (Sweden)

    Iosif Kapellakis

    2015-01-01

    Full Text Available Land application of olive mill wastewater (OMW is considered a promising low-cost practice for olive-oil producing countries. The objectives of this work were to investigate: (i OMW treatment potential of a land treatment system (LTS, planted with a E. camaldulensis species, regarding N, P, C, and phenols; (ii the effects of OMW on chemical properties of soil and soil solution characteristics; and (iii the performance of E. camaldulensis in terms of biomass production and N and P recovery. E. camaldulensis received OMW for two growing seasons at rates based on maximum organic loading. These rates were almost equivalent to the reference evapotranspiration of the area. Soil solution and soil samples were collected from three different depths (15, 30 and 60 cm at specified time intervals. -Also, samples of plant tissues were collected at the end of application periods. OMW land application resulted in significant reduction in inorganic and organic constituents of OMW. At 15 cm of soil profile, the average removal of COD, TKN, NH4+-N, TP, In-P, and total phenols approached 93%, 86%, 70%, 86%, 82%, and 85%, respectively, while an increase in soil depth (30 and 60 cm did not improve significantly treatment efficiency. Furthermore, OMW increased soil organic matter (SOM, total kjeldahl nitrogen (TKN, and available P, particularly in the upper soil layer. In contrast, low inorganic N content was observed in the soil throughout the study period caused probably by increased competition among soil microorganisms induced by the organic substrate supply and high C/N ratio. Also, electrical conductivity (EC and SAR increased by OMW addition, but at levels that may do not pose severe risk for soil texture. Enhancement of soil fertility due to OMW application sustained eucalyptus trees and provided remarkable biomass yield. In conclusion, land application of OMW has a great potential for organic matter and phenol assimilation and can be effectively used for OMW

  5. Pretreatment of Palm Oil Mill Effluent (POME Using Magnetic Chitosan

    Directory of Open Access Journals (Sweden)

    N. Saifuddin

    2011-01-01

    Full Text Available Chitosan is a natural organic polyelectrolyte of high molecular weight and charge density; obtained from deacetylation of chitin. This study explored the potential and effectiveness of applying chitosan-magnetite nanocomposite particles as a primary coagulant and flocculent, in comparison with chitosan for pre-treatment of palm oil mill effluent (POME. A series of batch coagulation processes with chitosan-magnetite nanocomposite particles and chitosan under different conditions, i.e. dosage and pH were conducted, in order to determine their optimum conditions. The performance was assessed in terms of turbidity, total suspended solids (TSS and chemical oxygen demand (COD reductions. Chitosan-magnetite particles showed better parameter reductions with much lower dosage consumption, compared to chitosan, even at the original pH of POME, i.e. 4.5. At pH 6, the optimum chitosan-magnetite dosage of 250 mg/L was able to reduce turbidity, TSS and COD levels by 98.8%, 97.6% and 62.5% respectively. At this pH, the coagulation of POME by chitosan-magnetite was brought by the combination of charge neutralization and polymer bridging mechanism. On the other hand, chitosan seems to require much higher dosage, i.e. 370 mg/L to achieve the best turbidity, TSS and COD reductions, which were 97.7%, 91.7% and 42.70%, respectively. The synergistic effect of cationic character of both the chitosan amino group and the magnetite ion in the pre-treatment process for POME brings about enhanced performance for effective agglomeration, adsorption and coagulation.

  6. Rheology of coal-water slurries prepared by the HP roll mill grinding of coal. Quarterly technical progress report number 11, March 1--May 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.

    1995-06-01

    The objective of this research is the development of improved technology for the preparation of coal-water slurries that have potential for replacing fuel oil in direct combustion. Detailed investigations of the effect of solids content and chemical additives on the rheology of coal-water slurries, prepared with fines produced by the ball milling of Pittsburgh No. 8 coal, were conducted during the first phase of the research program. These experiments were to provide a baseline against which the rheological behavior of slurries prepared with fines produced by high-pressure roll milling or hybrid high-pressure, roll mill/ball mill grinding could be compared. The viscosity of slurries with high solids content is strongly influenced by the packing density of the feed material. The packing density can be significantly altered by mixing distributions of different median sizes, and to an extent by modifying the grinding environment. The research during this quarter was, therefore, directed towards: (1) establishing the relationship between the packing characteristic of fines and the viscosity of slurries prepared with the fines; (2) investigation of the effect of mixing distribution on the rheology; and (3) study of the effect of grinding environment in the ball mill on the rheology of coal-water slurries.

  7. Measurements of uranium mill tailings consolidation characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Fayer, M J

    1985-02-01

    A series of experiments were conducted on uranium mill tailings from the tailings pile in Grand Junction, Colorado, to determine their consolidation characteristics. Three materials (sand, sand/slimes mix, slimes) were loaded under saturated conditions to determine their saturated consolidated behavior. During a separate experiment, samples of the slimes material were kept under a constant load while the pore pressure was increased to determine the partially saturated consolidation behavior. Results of the saturated tests compared well with published data. Sand consolidated the least, while slimes consolidated the most. As each material consolidated, the measured hydraulic conductivity decreased in a linear fashion with respect to the void ratio. Partially saturated experiments with the slimes indicated that there was little consolidation as the pore pressure was increased progressively above 7 kPa. The small amount of consolidation that did occur was only a fraction of the amount of saturated consolidation. Preliminary measurements between pore pressures of 0 and 7 kPa indicated that measurable consolidation could occur in this range of pore pressure, but only if there was no load. 13 references, 13 figures.

  8. Catalytic pyrolysis of olive mill wastewater sludge

    Science.gov (United States)

    Abdellaoui, Hamza

    From 2008 to 2013, an average of 2,821.4 kilotons/year of olive oil were produced around the world. The waste product of the olive mill industry consists of solid residue (pomace) and wastewater (OMW). Annually, around 30 million m3 of OMW are produced in the Mediterranean area, 700,000 m3 year?1 in Tunisia alone. OMW is an aqueous effluent characterized by an offensive smell and high organic matter content, including high molecular weight phenolic compounds and long-chain fatty acids. These compounds are highly toxic to micro-organisms and plants, which makes the OMW a serious threat to the environment if not managed properly. The OMW is disposed of in open air evaporation ponds. After evaporation of most of the water, OMWS is left in the bottom of the ponds. In this thesis, the effort has been made to evaluate the catalytic pyrolysis process as a technology to valorize the OMWS. The first section of this research showed that 41.12 wt. % of the OMWS is mostly lipids, which are a good source of energy. The second section proved that catalytic pyrolysis of the OMWS over red mud and HZSM-5 can produce green diesel, and 450 °C is the optimal reaction temperature to maximize the organic yields. The last section revealed that the HSF was behind the good fuel-like properties of the OMWS catalytic oils, whereas the SR hindered the bio-oil yields and quality.

  9. On maximally supersymmetric Yang-Mills theories

    CERN Document Server

    Movshev, M

    2004-01-01

    We consider ten-dimensional supersymmetric Yang-Mills theory (10D SUSY YM theory) and its dimensional reductions, in particular, BFSS and IKKT models. We formulate these theories using algebraic techniques based on application of differential graded Lie algebras and associative algebras as well as of more general objects, L_{\\infty}- and A_{\\infty}- algebras. We show that using pure spinor formulation of 10D SUSY YM theory equations of motion and isotwistor formalism one can interpret these equations as Maurer-Cartan equations for some differential Lie algebra. This statement can be used to write BV action functional of 10D SUSY YM theory in Chern-Simons form. The differential Lie algebra we constructed is closely related to differential associative algebra Omega of (0, k)-forms on some supermanifold; the Lie algebra is tensor product of Omega and matrix algebra . We construct several other algebras that are quasiisomorphic to Omega and, therefore, also can be used to give BV formulation of 10D SUSY YM theory...

  10. Curving Yang-Mills-Higgs Gauge Theories

    CERN Document Server

    Kotov, Alexei

    2015-01-01

    Established fundamental physics can be described by fields, which are maps. The source of such a map is space-time, which can be curved due to gravity. The map itself needs to be curved in its gauge field part so as to describe interaction forces like those mediated by photons and gluons. In the present article, we permit non-zero curvature also on the internal space, the target of the field map. The action functional and the symmetries are constructed in such a way that they reduce to those of standard Yang-Mills-Higgs (YMH) gauge theories precisely when the curvature on the target of the fields is turned off. For curved targets one obtains a new theory, a curved YMH gauge theory. It realizes in a mathematically consistent manner an old wish in the community: replacing structures constants by functions depending on the scalars of the theory. In addition, we provide a simple 4d toy model, where the gauge symmetry is abelian, but turning off the gauge fields, no rigid symmetry remains---another possible manife...

  11. [Sumac (Rhus chinensis Mill) biomass refinery engineering].

    Science.gov (United States)

    Wang, Lan; Wang, Ning; Li, Tan; Chen, Hongzhang

    2014-05-01

    Sumac (Rhus chinensis Mill) is an abundant and widely distributed Chinese native plant. Sumac fruit contains low content of vegetable oil, as an atypical oil plants hardly being processed through traditional vegetable oil production technologies. Based on our own studies on the characteristics of sumac fruit and branches, we established a novel model of sumac biomass refinery, and constructed the sumac biomass refinery technology system and eco-industrial chain integration. Steam explosion was the key technology, and several components fractionation technologies were integrated in the sumac biomass refinery system. The fractionated components were converted into different products depending on their functional features. Eight products including sumac fruit oil, biodiesel, protein feed, flavonoids, unbleached facial tissue, phenolic resin, biomass briquette and biogas were produced in the refinery. The extracted sumac fruit oil by steam explosion pretreatment was applied for the new food resource of Ministry of Health, and the permit was approved. This research provides a new model for the development of atypical wild plant resources.

  12. Generalisation of the Yang-Mills Theory

    CERN Document Server

    Savvidy, George

    2015-01-01

    We suggest an extension of the gauge principle which includes tensor gauge fields. In this extension of the Yang-Mills theory the vector gauge boson becomes a member of a bigger family of gauge bosons of arbitrary large integer spins. The proposed extension is essentially based on the extension of the Poincar\\'e algebra and the existence of an appropriate transversal representations. The invariant Lagrangian is expressed in terms of new higher-rank field strength tensors. It does not contain higher derivatives of tensor gauge fields and all interactions take place through three- and four-particle exchanges with a dimensionless coupling constant. We calculated the scattering amplitudes of non-Abelian tensor gauge bosons at tree level, as well as their one-loop contribution into the Callan-Symanzik beta function. This contribution is negative and corresponds to the asymptotically free theory. Considering the contribution of tensorgluons of all spins into the beta function we found that it is leading to the theo...

  13. Assessment of potential migration of radionuclides and trace elements from the White Mesa uranium mill to the Ute Mountain Ute Reservation and surrounding areas, southeastern Utah

    Science.gov (United States)

    Naftz, David L.; Ranalli, Anthony J.; Rowland, Ryan C.; Marston, Thomas M.

    2011-01-01

    collected from Entrance Spring also contained elevated concentrations of selenium and vanadium. Sediment samples collected from three ephemeral drainages east of the uranium mill site (including Entrance Spring) contained uranium concentrations exceeding background values downwind of the predominant wind directions at the site. Sediment samples collected from ephemeral drainages on the south and west boundaries of the uranium mill site generally did not exceed background-uranium concentrations. Elevated concentrations of uranium and vanadium, indicating offsite transport, were found in plant tissue samples collected north-northeast, east, and south of the mill site, downwind of 2 Assessment of potential migration of radionuclides and trace elements from the White Mesa uranium mill the predominant wind directions at the site. The uranium and vanadium concentrations in plant tissue samples collected west of the uranium mill site were low. On the basis of the study results, consideration should be given to future monitoring programs in areas surrounding the uranium mill site to address current and future environmental concerns. These potential monitoring programs should consider (1) quarterly monitoring of major- and trace-element concentrations in selected springs and wells; (2) annual monitoring of Entrance Spring for uranium isotopes, delta sulfur-34sulfate, delta oxygen-18, and delta deuterium; (3) annual monitoring of background water quality at selected spring and monitoring well sites; (4) periodic sampling and chemical analyses of sagebrush in areas east of the uranium mill site coupled with off-site fugitive dust monitoring; (5) installation of a new monitoring well upgradient from the East and West wells; (6) the addition of non-routine chemical constituents to ongoing monitoring programs within the uranium mill site that could provide additional insight(s) into potential contaminant sources and processes; and (7) archiving future monitoring data into a maintained

  14. Yang-Mills-Vlasov system in the temporal gauge. Systeme de Yang-Mills-Vlasov en jauge temporelle

    Energy Technology Data Exchange (ETDEWEB)

    Choquet-Bruhat, Y.; Noutchegueme, N. (Paris-6 Univ., 75 (FR))

    1991-01-01

    We prove a local in time existence theorem of a solution of the Cauchy problem for the Yang-Mills-Vlasov integrodifferential system. Such equations govern the evolution of plasmas, for instance of quarks and gluons (quagmas), where non abelian gauge fields and Yang-Mills charges replace the usual electromagnetic field and electric charge. We work with the temporal gauge and use functional spaces with appropriate weight on the momenta, but no fall off is required in the space direction.

  15. Surface complexation modeling of U(VI) adsorption by aquifer sediments from a former mill tailings site at Rifle, Colorado

    Science.gov (United States)

    Hyun, S.P.; Fox, P.M.; Davis, J.A.; Campbell, K.M.; Hayes, K.F.; Long, P.E.

    2009-01-01

    A study of U(VI) adsorption by aquifer sediment samples from a former uranium mill tailings site at Rifle, Colorado, was conducted under oxic conditions as a function of pH, U(VI), Ca, and dissolved carbonate concentration. Batch adsorption experiments were performed using adsorption Kd values for the sand and adsorption data. The model successfully predicted U(VI) adsorption observed from a multilevel sampling well installed at the site. A comparison of the model with the one developed previously for a uranium mill tailings site at Naturita, Colorado, indicated that possible calcite nonequilibrium of dissolved calcium concentration should be evaluated. The modeling results also illustrate the importance of the range of data used in deriving the best fit model parameters. ?? 2009 American Chemical Society.

  16. Cocomposting with and without Eisenia fetida for conversion of toxic paper mill sludge to a soil conditioner.

    Science.gov (United States)

    Kaur, Arvinder; Singh, Jaswinder; Vig, Adarsh Pal; Dhaliwal, S S; Rup, Pushpinder J

    2010-11-01

    Present study was envisaged for fast bioremediation of toxic paper mill sludge into a soil ameliorating agent. Although a rich source of organic carbon this sludge cannot be directly applied in fields and is recycled very slowly in landfills as it is deficient in other nutrients. Therefore it was mixed with cattle dung in various proportions and subjected to aerobic cocomposting (without worms) and vermicocomposting (with Eisenia fetida). It was observed that mixing cattle dung with the sludge improved physico-chemical characteristics (with transition metals in the permissible range for manures) of the products of both the processes and enhanced its acceptability for worms. Higher decline in organic carbon and higher content of nitrogen and phosphorous along with lower electrical conductivity and higher pH of the products of vermicomposting indicated that E. fetida helped in fast conversion of toxic paper mill sludge into a soil conditioner in 100days.

  17. The field emission properties of high aspect ratio diamond nanocone arrays fabricated by focused ion beam milling

    Directory of Open Access Journals (Sweden)

    Z.L. Wang, Q. Wang, H.J. Li, J.J. Li, P. Xu, Q. Luo, A.Z. Jin, H.F. Yang and C.Z. Gu

    2005-01-01

    Full Text Available High aspect ratio diamond nanocone arrays are formed on freestanding diamond film by means of focused ion beam (FIB milling technology and hot-filament chemical vapor deposition (HFCVD method. The structure and phase purity of an individual diamond nanocone are characterized by scanning electron microscopy (SEM and micro-Raman spectroscopy. The result indicates that the diamond cones with high aspect ratio and small tip apex radius can be obtained by optimizing the parameters of FIB milling and diamond growth. The diamond nanocone arrays were also used to study the electron field emission properties and electric field shielding effect, finding high emission current density, low threshold and weak shielding effect, all attributable to the high field enhancement factor and suitable cone density of the diamond nanocone emitter

  18. Tool Wear Analysis on Five-Axis Flank Milling for Curved Shape Part – Full Flute and Ground Shank End Mill

    Directory of Open Access Journals (Sweden)

    Syahrul Azwan Sundi

    2017-01-01

    Full Text Available This paper is a study on full flute (extra-long tool and ground shank end mill wear analysis by utilizing five-axis CNC to implement flank milling strategy on curved shape part. Five-axis machining eases the user to implement variations of strategy such as flank milling. Flank milling is different from point milling. Point milling cuts materials by using the tip of the tool whereas the flank milling uses the cutting tool body to cut material. The type of cutting tool used was end mill 10 mm diameter with High Speed Steel (HSS material. One factor at a time was utilized to analyze the overall data. Feed rate and spindle speed were the two main factors that been set up equally for both full flute and ground shank end mill. At the end of this research, the qualitative analysis based on tool wear between full flute and ground shank end mill is observed. Generally, both types of cutting tools showed almost the same failure indication such as broken edge or chipped off edge, formation of pinned hole on the surface and serration formation or built-up edge (BUE on the primary flute. However, the results obtained from the enlarged images which were captured by Optical Microscope indicated that, the ground shank end mill is better than the full flute end mill.

  19. Comparison of the efficiencies of attached- versus suspended-growth SBR systems in the treatment of recycled paper mill wastewater.

    Science.gov (United States)

    Muhamad, Mohd Hafizuddin; Sheikh Abdullah, Siti Rozaimah; Abu Hasan, Hassimi; Abd Rahim, Reehan Adnee

    2015-11-01

    The complexity of residual toxic organics from biologically treated effluents of pulp and paper mills is a serious concern. To date, it has been difficult to choose the best treatment technique because each of the available options has advantages and drawbacks. In this study, two different treatment techniques using laboratory-scale aerobic sequencing batch reactors (SBRs) were tested with the same real recycled paper mill effluent to evaluate their treatment efficiencies. Two attached-growth SBRs using granular activated carbon (GAC) with and without additional biomass and a suspended-growth SBR were used in the treatment of real recycled paper mill effluent at a chemical oxygen demand (COD) level in the range of 800-1300 mg/L, a fixed hydraulic retention time of 24 h and a COD:N:P ratio of approximately 100:5:1. The efficiency of this biological treatment process was studied over a 300-day period. The six most important wastewater quality parameters, namely, chemical oxygen demand (COD), turbidity, ammonia (expressed as NH3-N), phosphorus (expressed as PO4(3)-P), colour, and suspended solids (SS), were measured to compare the different treatment techniques. It was determined that these processes were able to almost completely and simultaneously eliminate COD (99%) and turbidity (99%); the removals of NH3-N (90-100%), PO4(3)-P (66-78%), colour (63-91%), and SS (97-99%) were also sufficient. The overall performance results confirmed that an attached-growth SBR system using additional biomass on GAC is a promising configuration for wastewater treatment in terms of performance efficiency and process stability under fluctuations of organic load. Hence, this hybrid system is recommended for the treatment of pulp and paper mill effluents.

  20. Effects of olive mill wastes added to olive grove soils on erosion and soil properties

    Science.gov (United States)

    Lozano-García, Beatriz; Parras-Alcántara, Luis

    2014-05-01

    INTRODUCTION The increasing degradation of olive groves by effect of organic matter losses derived from intensive agricultural practices has promoted the use (by olive farmers) of olive mill wastes (olive leaves and alperujo) which contain large amounts of organic matter and are free of heavy metals and pathogenic microorganisms. In this work we compared the effects of these oil mill wastes on the decrease of soil erosion, also, we undertook the assessment of the organic carbon and nitrogen contents of soil, their distribution across the profile, the accumulation and Stratification ratios (SRs) of soil organic carbon (SOC) and total nitrogen (TN), and the C:N ratio, in Cambisols in Mediterranean olive groves treated with olive leaves and alperujo. MATERIALS AND METHODS The study area was a typical olive grove in southern Spain under conventional tillage (CT). Three plots were established. The first one was the control plot; the second one was treated with olive leaves (CTol) and the third one, with alperujo (CTa). 9 samples per plot were collected to examine the response of the soil 3 years after application of the wastes. Soil properties determined were: soil particle size, pH, bulk density, the available water capacity, SOC, TN and C:N ratio. SOC and N stock, expressed for a specific depth in Mg ha-1. Stratification ratios (SRs) (that can be used as an indicator of dynamic soil quality) for SOC and TN at three different depths were calculated. The erosion study was based on simulations of rain; that have been carried out in order to highlight differences in the phenomena of runoff and soil losses in the three plots considered. The effect of different treatments on soil properties was analyzed using a ANOVA, followed by an Anderson-Darling test. RESULTS Supplying the soil with the wastes significantly improved physical and chemical properties in the studied soils with respect to the control. C and N stocks increased, the SOC stock was 75.4 Mg ha-1 in CT, 91.5 Mg

  1. Use and treatment of olive mill wastewater: current situation and prospects in Spain

    Directory of Open Access Journals (Sweden)

    Fiestas Ros de Ursinos, J. A.

    1992-04-01

    Full Text Available The characteristics of olive mill wastewater are set out the viewpoint of their pollutant capacity and the problems arising from their tipping in olive-growing areas. The national administration's solutions for preventing pollutions of surface waters are also stated. Special detail is given to the action taken within a research and development program financed by the Spanish Government and the EEC through the Commission MEDSPA 89 for the technical-economic evaluation of different systems for eliminating and treating olive mill wastewater, in order to determine the feasibility of their introduction at industrial level. At the same time the systems currently under evaluation are described: - Intensification of natural evaporation from olive mill wastewater stored in ponds (two systems. - Physical processes using forced evaporation to eliminate the olive mill wastewater, followed by aerobic biological processes or systems of ultrafiltration and inverse osmosis for final treatment of the condensate (two systems. - Application of physico-chemical processes to eliminate the greater part of the organic components of the olive mill wastewaters and the use of aerobic biological processes or systems of ultrafiltration and inverse osmosis for final treatment of the clarified fraction (three systems. - Biological process for the complete treatment of the olive mill wastewaters by the successive application of processes: bioconversion, biomethanisation, aerobic treatment, and physico-chemical treatment. Treatment yields of the order of 99,6% are achieved, at the same time obtaining by-products of commercial interest (one system.

    Las características de los alpechines se establecen desde el punto de vista de su capacidad contaminante y de los problemas típicos que surgen en las zonas de cultivo del olivo. También están descritas las soluciones de la administración del Estado para la prevención de la contaminación de aguas de superficie

  2. Inoculation of paperboard mill sludge versus mixed culture bacteria for hydrogen production from paperboard mill wastewater.

    Science.gov (United States)

    Farghaly, Ahmed; Tawfik, Ahmed; Danial, Amal

    2016-02-01

    A comparative evaluation of paperboard mill sludge (PMS) versus mixed culture bacteria (MCB) as inoculum for hydrogen production from paperboard mill wastewater (PMW) was investigated. The experiments were conducted at different initial cultivation pHs, inoculums to substrate ratios (ISRs gVS/gCOD), and hydraulic retention times (HRTs). The peak hydrogen yield (HY) of 5.29 ± 0.16 and 1.22 ± 0.11 mmol/gCODinitial was occurred at pH = 5 for MCB and PMS, respectively. At pH of 5, the HY and COD removal achieved the highest values of 2.26 ± 0.14 mmol/gCODinitial and 86 ± 1.6% at ISR = 6 for MCB, and 2.38 ± 0.25 mmol/gCODinitial and 60.4 ± 2.5% at ISRs = 3 for PMS. The maximum hydrogen production rate was 93.75 ± 8.9 mmol/day at HRT = 9.6 h from continuous upflow anaerobic reactor inoculated with MCB. Meanwhile, the 16S ribosomal RNA (rRNA) gene fragments indicated a dominance of a novel hydrogen-producing bacterium of Stenotrophomonas maltophilia for PMS microbial community. On the other hand, Escherichia fergusonii and Enterobacter hormaechei were the predominant species for MCB.

  3. Ultrasound pretreatment for enhanced biogas production from olive mill wastewater.

    Science.gov (United States)

    Oz, Nilgun Ayman; Uzun, Alev Cagla

    2015-01-01

    This study investigates applicability of low frequency ultrasound technology to olive mill wastewaters (OMWs) as a pretreatment step prior to anaerobic batch reactors to improve biogas production and methane yield. OMWs originating from three phase processes are characterized with high organic content and complex nature. The treatment of the wastewater is problematic and alternative treatment options should be investigated. In the first part of the study, OMW samples were subjected to ultrasound at a frequency of 20kHz with applied powers varying between 50 and 100W under temperature controlled conditions for different time periods in order to determine the most effective sonication conditions. The level of organic matter solubilization at ultrasound experiments was assessed by calculating the ratio of soluble chemical oxygen demand/total chemical oxygen demand (SCOD/TCOD). The results revealed that the optimum ultrasonic condition for diluted OMW is 20kHz, 0.4W/mL for 10min. The application of ultrasound to OMW increased SCOD/TCOD ratio from 0.59 to 0.79. Statistical analysis (Friedman's tests) show that ultrasound was significantly effective on diluted OMW (p0.05). For raw OMW, this increase has been found to be limited due to high concentration of suspended solids (SS). In the second part of the study, biogas and methane production rates of anaerobic batch reactor fed with the ultrasound pretreated OMW samples were compared with the results of control reactor fed with untreated OMW in order to determine the effect of sonication. A nonparametric statistical procedure, Mann-Whitney U test, was used to compare biogas and methane production from anaerobic batch reactors for control and ultrasound pretreated samples. Results showed that application of low frequency ultrasound to OMW significantly improved both biogas and methane production in anaerobic batch reactor fed with the wastewater (preactor fed with ultrasound pretreated diluted OMW produced approximately 20

  4. EFFECT OF PAN-MILLING ON RHEOLOGICAL PROPERTIES OF HIGH DENSITY POLYETHYLENE

    Institute of Scientific and Technical Information of China (English)

    Hua Huang

    2000-01-01

    The effect of pan-milling on the rheological properties of high density polyethylene (HDPE) was studied. An innovative milling apparatus, viz. an inlaid pan-mill, was used. Melt indexer, capillary rheometer, Haake Rheocord 90 singlescrew extruder and Brabender rheometer were used to evaluate the rheological properties ofHDPE. HDPE with higher initial molecular weight and larger particle size was easier to degrade under pan-milling stress, as indicated by the melt index.Pressure oscillation in capillary flow occurred at significantly higher shear stress and shear rate for milled HDPE than for unmilled HDPE. The apparent shear viscosity of HDPE decreased with increasing times of milling. After milling, the flow activation energy decreased and thus the sensitivity of viscosity to temperature was reduced. Die pressure and torque during single screw extrusion were reduced significantly after milling. Plasticizing time as measured in a Brabander mixer decreased markedly with increasing milling times.

  5. Treatment of Olive Mill Wastewater and the Use of Polyphenols Obtained After Treatment

    Directory of Open Access Journals (Sweden)

    Semih Otles

    2012-04-01

    Full Text Available Olive mill wastes are signicant environmental problem especially in Mediterranean areas where they are generated in huge quantities in a short period of time. They are phytotoxic materials because of their high phenol, lipid and organic acid concentrations, but these wastes also contain valuable resources that could be recycled such as a large proportion of organic matter and a wide range of nutrients. The effluent from olive oil mills contains a large amount of polyphenols that have antioxidant properties. The market value of these antioxidants is high and they are commonly used in the food, cosmetics, pharmaceutics and chemical industries. For the management of olive mill wastewater (OMW and other olive residues, various treatment methods can be used. Many scientists work on more efficient and cheaper treatment alternatives. Due to the great variety of compounds in the waste, several technologies to remove the harmful compounds for the environment should be used single or together. Some of the most used OMW treatments are drying / evaporation, forced evaporation, thermal treatment, centrifugation-ultraltration, electrocoagulation, composting, lagooning, adsorption, powdered activated carbon, filtration, sand filtration, membrane filtration, ultrafiltration, precipitation / flocculation, distillation, electrolysis, co-composting, advanced oxidation processes (AOPs such as ozonation, hydrogen peroxide / ferrous iron oxidation (the so-called Fentons reagent. Several OMW treatment technologies have been developed aiming at the removal of the main toxic organic compounds. A lot of factors must be considered to choose the treatment methods among them the investment, required area, specic training of the workers, noise and odour emissions and seasonality of production.

  6. EFFECT OF PAN-MILLING STRESS ON CRYSTAL STRUCTURES OF HIGH DENSITY POLYETHYLENE

    Institute of Scientific and Technical Information of China (English)

    Hua Huang

    2000-01-01

    A detailed study was performed on the crystal structures of pan-milled high-density polyethylene (HDPE) using differential scanning calorimetry (DSC) and X-ray diffraction. The crystallinity of HDPE first decreased slightly, followed by a gradual increase with increasing milling times. Monoclinic crystals appeared after 4 cycles of milling. With increasing times of milling, the proportion of monoclinic crystals increased significantly while the proportion of orthorhombic crystals decreased gradually. With increasing times of milling, the crystallite size of orthorhombic form decreased greatly, while the size of monoclinic crystallites kept almost constant during milling.

  7. SAXS study of nanocrystalline materials produced by ball milling

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez van Raap, M.; Socolovky, L.; Mendoza Zelis, L.; Sanchez, F.H. [La Plata Univ. Nacional (Argentina). Dept. de Fisica; Kellermann, Guinther; Torriani, Iris [Laboratorio Nacional de Luz Sincrotron (LNLS), Campinas, SP (Brazil)

    1997-12-31

    Full text. SAXS characterization of nanocrystalline materials produced by ball milling was performed at the Brazilian National Synchrotron Light-SAXS beam line. Two kind of sample were used: pure metals (Fe and Pd) milled in Ar atmosphere in a vibratory horizontal mill Resc MM2 for 12, 25 and 48 h. And Fe y Cu 1-y(05,0.10,0.14,0.18,0.20,0.35 and 0.45) alloys subjected to 75 milling hours in a low energy mill. SAXS data was collected with (formula) corresponding to a photon energy just below Fe absorption edge to avoid fluorescence, and with two camera length to be able to see Guinier and Porod regions. Mechanical work performed on any materials produces simultaneously reduction in particles sizes and in grain sizes up to the nanometer scale, increase in micro strain storage and defects. Broadening of the XRD reflection lines with milling time gives an estimation of grain sizes and volume deformation (micro strain), but no information is obtained on the nature of the defects, which due to the high milling intensity could be clustered as voids. On the other hand, for a mixture of two elements, besides the facts listed above, alloying in different metastable states (amorphous, extended solid solution, granular materials, etc.) can be obtained depending on the system and on composition. For the Fe y Cu 1-y alloys studied here, previous results indicates: the alloys are fcc, a dependence of the magneto resistivity on Fe concentration can be recorded (maximum at 0.20) and from HREM the existence of inclusion of 7.3 nm size was proposed. Our preliminary data analysis of the recorded SAXS patterns shows that for the metals no clear dependence with milling time can be established, a distribution of sizes can be predicted from the Guinier region behavior and a Porod region can be fitted indicating a fairly sharp density contrast. Patterns recorded Fe y Cu 1-y are similar of those recorded for milled metals, the possibility of distinguish from voids or from composition

  8. Rolling mill optimization using an accurate and rapid new model for mill deflection and strip thickness profile

    Science.gov (United States)

    Malik, Arif Sultan

    This work presents improved technology for attaining high-quality rolled metal strip. The new technology is based on an innovative method to model both the static and dynamic characteristics of rolling mill deflection, and it applies equally to both cluster-type and non cluster-type rolling mill configurations. By effectively combining numerical Finite Element Analysis (FEA) with analytical solid mechanics, the devised approach delivers a rapid, accurate, flexible, high-fidelity model useful for optimizing many important rolling parameters. The associated static deflection model enables computation of the thickness profile and corresponding flatness of the rolled strip. Accurate methods of predicting the strip thickness profile and strip flatness are important in rolling mill design, rolling schedule set-up, control of mill flatness actuators, and optimization of ground roll profiles. The corresponding dynamic deflection model enables solution of the standard eigenvalue problem to determine natural frequencies and modes of vibration. The presented method for solving the roll-stack deflection problem offers several important advantages over traditional methods. In particular, it includes continuity of elastic foundations, non-iterative solution when using pre-determined elastic foundation moduli, continuous third-order displacement fields, simple stress-field determination, the ability to calculate dynamic characteristics, and a comparatively faster solution time. Consistent with the most advanced existing methods, the presented method accommodates loading conditions that represent roll crowning, roll bending, roll shifting, and roll crossing mechanisms. Validation of the static model is provided by comparing results and solution time with large-scale, commercial finite element simulations. In addition to examples with the common 4-high vertical stand rolling mill, application of the presented method to the most complex of rolling mill configurations is demonstrated

  9. Biomechanical properties of wheat grains: the implications on milling

    Science.gov (United States)

    Reith, Martin

    2017-01-01

    Millennia of continuous innovation have driven ever increasing efficiency in the milling process. Mechanically characterizing wheat grains and discerning the structure and function of the wheat bran layers can contribute to continuing innovation. We present novel shear force and puncture force testing regimes to characterize different wheat grain cultivars. The forces endured by wheat grains during the milling process can be quantified, enabling us to measure the impact of commonly applied grain pretreatments, such as microwave heating, extended tempering, enzyme and hormone treatments on grains of different ‘hardness’. Using these methods, we demonstrate the importance of short tempering phases prior to milling and identify ways in which our methods can detect differences in the maximum force, energy and breaking behaviours of hard and soft grain types. We also demonstrate for the first time, endosperm weakening in wheat, through hormone stratification on single bran layers. The modern milling process is highly refined, meaning that small, cultivar specific, adjustments can result in large increases in downstream profits. We believe that methods such as these, which enable rapid testing of milling pretreatments and material properties can help to drive an innovation process that has been core to our industrial efforts since prehistory. PMID:28100826

  10. HA/Ti composite for biomedical application by mechanical milling

    Institute of Scientific and Technical Information of China (English)

    刘咏; 刘芳; 周科朝; 黄伯云

    2003-01-01

    In order to overcome the poor mechanical properties of HA and the low bioactivity of Ti, HA/Ti com-posites with various compositions were prepared by mechanical milling. The effects of milling condition and the com-position on the microstructure, the density and the hardness of the composites were studied. The results show thatduring the ball milling process, Ti particles are refined and the homogeneity of the HA/Ti mixtures is improved;HA will partially decompose due to the existence of Ti and high sintering temperature. The microstructure of HA/Ti composites is highly dependent on the milling condition and the composition. In the microstructure, Ti phase con-nects to be a continuous network, and HA/Ti mixtures disperse in the network. The longer the milling time, the fi-ner the network will be. The density of HA/Ti composites decreases with the content of HA increasing and themilling time prolonging, because HA deteriorates the sinterability of Ti. The hardness of HA/Ti composites increa-ses firstly with the content of HA increasing, and then drops when the content of HA exceeds 30%. Addition ofHA will strengthen the HA/Ti composite but will decrease the density of the composite, which accounts for theeffect of HA on the hardness of the composites.

  11. Sugarcane Tandem Mills Operation at Two Hydraulic Pressure Levels

    Directory of Open Access Journals (Sweden)

    Jorge Michel Corrales-Suárez

    2015-01-01

    Full Text Available Among the areas with more energy consumption in a sugar factory is the tandem of mills. The applied hydraulic pressure on the superior mace is one of the variables that have influence on this energy consumption. Hydraulic pressures were decreased in a value that did not affect the extraction process efficiency to determine the possibilities of decreasing this energy consumption. The research was carried out in two sugar cane tandems of six mills. The pressures were only varied in the extraction mills in humid according to a statistical design of experiments in random blocks. The results were analyzed by means of the analysis of variance of double classification. The independent variables were the hydraulic pressures in the intermediate mills while the dependent variables were the % pol and % humidity of the final bagasse. The hydraulic pressures of the intermediate mills were reduced 3.45 MPa in the Tandem 1 and 2.07 MPa in the Tandem 2. It was demonstrated that under the conditions of the experiment, the employment of working hydraulic pressures smaller than the usually established ones for each tandem did not affect the extraction process of the sugar cane sucrose significantly, but decreased 11.75% the power demand on tandem 1 and 8.17% on tandem 2.

  12. Effect of milling on DSC thermogram of excipient adipic acid.

    Science.gov (United States)

    Ng, Wai Kiong; Kwek, Jin Wang; Yuen, Aaron; Tan, Chin Lee; Tan, Reginald

    2010-03-01

    The purpose of this research was to investigate why and how mechanical milling results in an unexpected shift in differential scanning calorimetry (DSC) measured fusion enthalpy (Delta(fus)H) and melting point (T(m)) of adipic acid, a pharmaceutical excipient. Hyper differential scanning calorimetry (hyper-DSC) was used to characterize adipic acid before and after ball-milling. An experimental study was conducted to evaluate previous postulations such as electrostatic charging using the Faraday cage method, crystallinity loss using powder X-ray diffraction (PXRD), thermal annealing using DSC, impurities removal using thermal gravimetric analysis (TGA) and Karl Fischer titration. DSC thermograms showed that after milling, the values of Delta(fus)H and T(m) were increased by approximately 9% and 5 K, respectively. Previous suggestions of increased electrostatic attraction, change in particle size distribution, and thermal annealing during measurements did not explain the differences. Instead, theoretical analysis and experimental findings suggested that the residual solvent (water) plays a key role. Water entrapped as inclusions inside adipic acid during solution crystallization was partially evaporated by localized heating at the cleaved surfaces during milling. The correlation between the removal of water and melting properties measured was shown via drying and crystallization experiments. These findings show that milling can reduce residual solvent content and causes a shift in DSC results.

  13. Effect of mechanical milling on the magnetic properties of garnets

    Energy Technology Data Exchange (ETDEWEB)

    Joseyphus, R.J. [Materials Science Centre, Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai 600 025 (India); Narayanasamy, A. [Materials Science Centre, Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai 600 025 (India)]. E-mail: ansuom@yahoo.co.in; Nigam, A.K. [Department of Physics, Tata Institute of Fundamental Research, Colaba, Mumbai 400 005 (India); Krishnan, R. [Laboratoire de Magnetisme et d' Optique, de Versailles, 45 Avenue des Etat-Unis 78035-Versailles Cedex (France)

    2006-01-15

    Rare earth garnets after milling to nanosizes are found to decompose into rare earth orthoferrite and other rare earth and iron oxide phases. The magnetization for the yttrium iron garnet decreases in the nano state due to the formation of antiferromagnetic phases. But for the gadolinium iron garnet when milled up to 25 h, the room temperature magnetization increases despite the formation of antiferromagnetic and non-magnetic phases. This is attributed to the uncompensated moments of the sublattices because of the weakening of the superexchange interaction due to change in bond angles and the breaking of some superexchange bonds on account of the defects and oxygen vacancies introduced on milling. For the 10 h milled gadolinium iron garnet at 5 K, after correcting for the non-magnetic phases present, there is an increase in the magnetic moment of about 10% as compared to the value for the as-prepared garnet. The magnetic hyperfine fields corresponding to the various phases were measured using {sup 57}Fe Moessbauer spectroscopy at 16 K. The isomer shift values indicate the loss of oxygen for the samples milled for larger duration.

  14. OPTIMIZATION OF WOOD MILLING SCHEDULE – A CASE STUDY

    Directory of Open Access Journals (Sweden)

    Emilia-Adela SALCA

    2015-12-01

    Full Text Available The paper presents the results of a case study applied to the milling process of solid wood specimens made of black alder wood (Alnus glutinosa L. Gaertn. with a view to find the optimal cutting schedule when two main criteria, such as the minimum power consumption and the best surface quality are fulfilled.The experimental work was performed with black alder wood originating from mature trees from the Buzau Valley region in Romania. All samples were processed on their longitudinal edges by straight milling with a milling cutter having glued straight plates on the vertical milling machine under different cutting schedules. An electronic device connected to the machine engine and an acquisition board were used to record and compute the power consumption during milling. Roughness measurements of the samples were performed by employing an optical profilometer. All data were processed using the regression method and variance analysis. The study revealed that best results are to be obtained in terms of cutting power and surface quality when processing with low feed speeds and light cutting depths.

  15. Observer Based Fault Detection and Moisture Estimating in Coal Mill

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, Babak

    2008-01-01

    In this paper an observer-based method for detecting faults and estimating moisture content in the coal in coal mills is presented. Handling of faults and operation under special conditions, such as high moisture content in the coal, are of growing importance due to the increasing requirements to......In this paper an observer-based method for detecting faults and estimating moisture content in the coal in coal mills is presented. Handling of faults and operation under special conditions, such as high moisture content in the coal, are of growing importance due to the increasing...... requirements to the general performance of power plants. Detection  of faults and moisture content estimation are consequently of high interest in the handling of the problems caused by faults and moisture content. The coal flow out of the mill is the obvious variable to monitor, when detecting non-intended drops in the coal...... flow out of the coal mill. However, this variable is not measurable. Another estimated variable is the moisture content, which is only "measurable" during steady-state operations of the coal mill. Instead, this paper suggests a method where these unknown variables are estimated based on a simple energy...

  16. Phototreatment of Palm Oil Mill Effluent (POME over Cu/TiO2 Photocatalyst

    Directory of Open Access Journals (Sweden)

    Kim Hoong Ng

    2014-07-01

    Full Text Available The current work reported on the use of different formulations of Cu/TiO2 photocatalysts for the UV-irradiation of palm oil mills effluent (POME. Different copper loadings, viz. 2 wt%, 5 wt%, 10 wt%, 15 wt%, 20 wt% and 25 wt% were doped onto titania. XRD pattern confirmed the presence of anatase TiO2 as primary phase due to mild calcination temperature (573 K. Photo-decomposition of POME over 20 wt% Cu/TiO2 exhibited the highest conversion (27.0% attributed to its large pore diameter (20.0 nm. In addition, optimum loading was 0.83 g/l. © 2014 BCREC UNDIP. All rights reservedReceived: 5th January 2014; Revised: 8th April 2014; Accepted: 8th April 2014[How to Cite: Hoong, N.K., Deraman, M.R., Ang, C.H., Chong, S.K., Kong, Z.Y., Khan, M.R., Cheng, C.K., (2014. Phototreatment of Palm Oil Mill Effluent (POME over Cu/TiO2 Photocatalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 9 (2: 121-127. (doi:10.9767/bcrec.9.2.6011.121-127][Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.2.6011.121-127

  17. Sustainability of uranium mining and milling: toward quantifying resources and eco-efficiency.

    Science.gov (United States)

    Mudd, Gavin M; Diesendorf, Mark

    2008-04-01

    The mining of uranium has long been a controversial public issue, and a renewed debate has emerged on the potential for nuclear power to help mitigate against climate change. The central thesis of pro-nuclear advocates is the lower carbon intensity of nuclear energy compared to fossil fuels, although there remains very little detailed analysis of the true carbon costs of nuclear energy. In this paper, we compile and analyze a range of data on uranium mining and milling, including uranium resources as well as sustainability metrics such as energy and water consumption and carbon emissions with respect to uranium production-arguably the first time for modern projects. The extent of economically recoverable uranium resources is clearly linked to exploration, technology, and economics but also inextricably to environmental costs such as energy/water/chemicals consumption, greenhouse gas emissions, and social issues. Overall, the data clearly show the sensitivity of sustainability assessments to the ore grade of the uranium deposit being mined and that significant gaps remain in complete sustainability reporting and accounting. This paper is a case study of the energy, water, and carbon costs of uranium mining and milling within the context of the nuclear energy chain.

  18. Operations improvement of the recycling water-cooling systems of sugar mills

    Directory of Open Access Journals (Sweden)

    Shcherbakov Vladimir Ivanovich

    Full Text Available Water management in sugar factories doesn’t have analogues in its complexity among food industry enterprises. Water intensity of sugar production is very high. Circulation water, condensed water, pulp press water and others are used in technological processes. Water plays the main role in physical, chemical, thermotechnical processes of beet processing and sugar production. As a consequence of accession of Russia to the WTO the technical requirements for production processes are changing. The enforcements of ecological services to balance scheme of water consumption and water disposal increased. The reduction of fresh water expenditure is one of the main tasks in economy of sugar industry. The substantial role in fresh water expenditure is played by efficiency of cooling and aeration processes of conditionally clean waters of the 1st category. The article contains an observation of the technologies of the available solutions and recommendations for improving and upgrading the existing recycling water-cooling systems of sugar mills. The authors present the block diagram of the water sector of a sugar mill and a method of calculating the optimal constructive and technological parameters of cooling devices. Water cooling towers enhanced design and upgrades are offered.

  19. Abridged acid-base wet-milling synthesis of high purity hydroyapatite

    Directory of Open Access Journals (Sweden)

    Sandi Carolina Ruiz-Mendoza

    2008-06-01

    Full Text Available There is a plethora of routes to produce hydroxyapatite(HA and in general calcium phosphates(CP but production usually leads to a mixture of several phases. Besides ionic contamination, most of these methods are cumbersome, restricted to small volumes of product and require a lot of thermal energy. The acid-base route eliminates foreign ions or additives and its only byproduct is water. Heterogeneous reaction drawback is that solid reactants do not easily come in contact with each other and therefore addition and stirring times become very lengthy and still the product is a mixture. The synthesis started from calcium hydroxide and phosphoric acid (PA. Ball milling was used to favor kinetics and stoichiometry. Six sets of PA addition, paddle stirring and ball milling times were used. Products were evaluated by X ray diffraction (XRD, Fourier Transform Infrared (FTIR, scanning electron microscopy (SEM, X ray fluorescence (XRF and Ca/P ratio. Chemical analysis for calcium proceeded through oxalate precipitate and phosphorus by the phosphomolibdate technique. A set of conditions yielding high purity HA was established.

  20. Designing plant scale process integration for water management in an Indian paper mill.

    Science.gov (United States)

    Shukla, Sudheer Kumar; Kumar, Vivek; Chakradhar, B; Kim, Taesung; Bansal, M C

    2013-10-15

    In the present study, plant-scale process integration was applied to an Indian paper mill using the water cascade analysis (WCA) technique. Three limiting constraints, chemical oxygen demand (COD), total dissolved solids (TDS), and adsorbable organic halides (AOX), were considered for the study. A nearest neighbor algorithm was used to distribute the freshwater and recycled water among the plant operations. It was found that the limiting critical constraint depends upon the types of processes and streams involved in the integration. The limiting critical constraint can differ for different sections of the same industry, and can differ in different schemes of integration. After process integration, a 55.6% reduction in effluent flow, a 36% reduction in COD, and a 73% reduction in AOX were observed. After process integration, a 35.21% reduction in pollution costs can be achieved and, assuming the average production of the mill to be 225 tons per day, a savings of Indian rupees (INR) 1.73 per kg of paper produced can be achieved by employing process integration. The water cess was calculated as INR 3024.77 per day without integration for the sections that were considered for integration, while after integration, a 41.53% savings in the form of water cess was calculated.

  1. Preparation of lithium ferrite nanoparticles by high energy ball milling and characterizations

    Directory of Open Access Journals (Sweden)

    J. Touthang

    2016-11-01

    Full Text Available Ferrites are ferrimagnetic ceramic materials with inherent useful electromagnetic properties. Of them, spinelstructured ferrites are promising materials for microwave device applications; stress/torsion sensors and energy storage applications like anode materials in lithium batteries, fuel cells, solar cells etc. Nanostructured spinels further have high and wide scope of potential applications. In the present study, two different types of varied sized ferrimagnetic lithium ferrite spinel nanoparticles prepared using chemical sol-gel auto-combustion method were chosen. The prepared spinel particles were heated at 300°C for 1h. After heating the powders were milled using a High Energy Ball Mill for 30 minutes to further grind the particles and then subjected to various characterizations. Structural characterization was done using X-Ray Diffraction Method (XRD. The study revealed the spinel structure of these samples. Structural parameter such as lattice constant was determined using XRD data and found that the lattice parameter agrees with the standard data. DLS study found the agglomerations of the nanoparticles. The synthesized nanospinel particles were also characterized by the UVVis Spectroscopy, the Fourier Transform Infrared Spectroscopy (FTIR. Finally the magnetic hysteresis properties were studied using a Vibrating Sample Magnetometer (VSM.

  2. Onset of chaotic dynamics in a ball mill: Attractors merging and crisis induced intermittency

    Science.gov (United States)

    Manai, G.; Delogu, F.; Rustici, M.

    2002-09-01

    In mechanical treatment carried out by ball milling, powder particles are subjected to repeated high-energy mechanical loads which induce heavy plastic deformations together with fracturing and cold-welding events. Owing to the continuous defect accumulation and interface renewal, both structural and chemical transformations occur. The nature and the rate of such transformations have been shown to depend on variables, such as impact velocity and collision frequency that depend, in turn, on the whole dynamics of the system. The characterization of the ball dynamics under different impact conditions is then to be considered a necessary step in order to gain a satisfactory control of the experimental set up. In this paper we investigate the motion of a ball in a milling device. Since the ball motion is governed by impulsive forces acting during each collision, no analytical expression for the complete ball trajectory can be obtained. In addition, mechanical systems exhibiting impacts are strongly nonlinear due to sudden changes of velocities at the instant of impact. Many different types of periodic and chaotic impact motions exist indeed even for simple systems with external periodic excitation forces. We present results of the analysis on the ball trajectory, obtained from a suitable numerical model, under growing degree of impact elasticity. A route to high dimensional chaos is obtained. Crisis and attractors merging are also found.

  3. Ball mill assisted rapid mechanochemical extraction method for natural products from plants.

    Science.gov (United States)

    Wang, Man; Bi, Wentao; Huang, Xiaohua; Chen, David Da Yong

    2016-06-03

    A ball mill assisted mechanochemical extraction method was developed to extract compounds of natural product (NP) from plant using ionic liquid (IL). A small volume ball mill, also known as PastPrep(®) Homogenizer, which is often used for high-speed lysis of biological samples and for other applications, was used to dramatically increase the speed, completeness and reproducibility of the extraction process at room temperature to preserve the chemical integrity of the extracted compounds. In this study, tanshinones were selected as target compounds to evaluate the performance of this extraction method. Factors affecting the extraction efficiency, such as the duration, IL concentration and solid/liquid ratio were systematically optimized using the response surface methodology. Under the optimized conditions, the described method was more efficient and much faster than the conventional extraction methods such as methanol based ultrasound assisted extraction (UAE) and heat reflux extraction (HRE) that consumes a lot more organic solvent. In addition, the natural products of interest were enriched by anion metathesis of ionic liquids, combining extraction and preconcentration in the same process. The extractant was analyzed by HPLC and LC-MS. The reproducibility (RSD, n=5), correlation coefficient (r(2)) of the calibration curve, and the limit of detection, were determined to be in the range of 4.7-5.2%, 0.9992-0.9995, and 20-51ng/mL, respectively.

  4. The MillSOT-A Spiral Orbit Tribometer on a Milling Machine

    Science.gov (United States)

    Pepper, Stephen V.

    2014-01-01

    A spiral orbit tribometer (SOT) intended to characterize friction and wear phenomena has been constructed on a milling machine. The instrument, essentially a retainerless thrust bearing with one ball and flat races, is exceedingly simple and inexpensive to construct. The capabilities of the tribometer to measure both the coefficient of friction and contact electrical resistance are demonstrated with clean specimens as well as with well known lubricants such as molybdenum disulphide and Krytox oil. Operation in a purged environment of inert gas is also demonstrated. The results with these lubricants are quite close to what is obtained by other methods. Suggestions for extending the capabilities of the tribometer are given. This arrangement may find use in university mechanical engineering laboratories to introduce and study rolling contact motion as well as for research in contact mechanics and tribology.

  5. Environmental Performance of the Milling Process Of Malaysian Palm Oil Using The Life Cycle Assessment Approach

    Directory of Open Access Journals (Sweden)

    Vijaya Subramaniam

    2008-01-01

    Full Text Available Malaysia is currently the world leader in the production and export of palm oil. This study has a gate to gate system boundary. The inventory data collection starts at the oil palm fresh fruit bunch hoppers when the fresh fruit bunch is received at the mill up till the production of the crude palm oil in the storage tanks at the mill. The plantation phase and land use for the production of oil palm fresh fruit bunch is not included in this system boundary. This gate to gate case study of 12 mills identifies the potential impacts associated with the production of palm oil using the life cycle assessment approach and evaluates opportunities to overcome the potential impacts. Most of the impact categories show savings rather than impact. Within the system boundary there are only two main parameters that are causing the potential impacts to the environment; they are the Palm Oil Mill Effluent (POME followed by the boiler ash. The impact categories that the POME contributes to are under the Respiratory Organics and Climate Change. Both these impact categories are related to air emissions. The main air emission from the POME ponds during the anaerobic digestion is the biogas which consists of methane, carbon dioxide and traces of hydrogen sulfide. An alternate scenario was conducted to see how the impact will be if the biogas was harvested and used as energy and the results shows that when the biogas is harvested, the impact from the POME is removed. The other significant impact is the boiler ash. This is the ash that is produced when the biomass is burnt in the boiler. This potential impact contributes to the ecotoxicity impact category. This is mainly because of the disposal of this ash which in most cases was used for land application in the roads leading to the mil or in the plantations. If the parameters causing these two potential impacts are curbed, then this will be a further plus point for the Malaysian oil palm industry which is already

  6. Chemical use

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This is a summary of research and activities related to chemical use on Neal Smith National Wildlife Refuge between 1992 and 2009. The chemicals used on the Refuge...

  7. Chemical Reactors.

    Science.gov (United States)

    Kenney, C. N.

    1980-01-01

    Describes a course, including content, reading list, and presentation on chemical reactors at Cambridge University, England. A brief comparison of chemical engineering education between the United States and England is also given. (JN)

  8. Wet gringing of zeolite in stirred media mill

    Science.gov (United States)

    Mucsi, G.; Bohács, K.

    2016-04-01

    In the present study the results of systematic experimental series are presented with the specific goal of optimizing the zeolite nanoparticles' production using a wet stirred media mill. The diameter of the grinding media as well as the rotor velocity were varied in the experiments. Particle size distribution and "outer" specific surface area of the ground samples were measured by a laser particle size analyser. Additionally, BET, XRD and FT-IR analyses were performed for the characterization of the "total" specific surface area as well as the crystalline and material structure, respectively. Based on the results of the laboratory experiments it was found that wet stirred media milling provided significant reductions in the particle size of zeolite. Furthermore, the crystallinity of the samples also decreased, so not only the physical but the mineralogical characteristics of zeolite can be controlled by stirred media milling.

  9. Modeling and identification of HAGC system of temper rolling mill

    Institute of Scientific and Technical Information of China (English)

    HE Shang-hong; ZHONG Jue

    2005-01-01

    Including servo valve, hydraulic cylinder, mill and sensor and ignoring nonlinear factors, the linear dynamic model of hydraulic automatic gage control(HAGC) system of a temper rolling mill was theoretically derived. The order of the model is 4/4, and can be reduced to 2/2. Based on modulating functions method, utilizing numerical integration, we constructed the equivalent identification model of HAGC, and the least square estimation algorithm was established. The input and output data were acquired on line at temper rolling mill in Shangshai Baosteel Group Corporation, and the continuous time model of HAGC system was estimated with the proposed method. At different modulating window intervals, the estimated parameters changed remarkably. When the frequency bandwidth of modulating filter matches that of estimated system, the parameters can be estimated accurately. Finally, the dynamic model of the HAGC was obtained and validated based on the spectral analysis result.

  10. Exact, Schwarzschild-like solution for Yang-Mills theory

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, D.

    1995-04-01

    Exploiting the connection between general relativity and Yang-Mills theory an exact, Schwarzchild-like solution is given for an SU(N) gauge field coupled to a scalar field in the Bogomolny, Prasad, Sommerfield limit. The SU(2) solution is found using the second order Euler-Lagrange formalism, while the SU(N) generalization is given using the first order Bogomolny formalism. In analogy with the Schwarzschild solution of general relativity, these Yang-Mills solutions possess an event horizon with respect to the SU(N) charge. It is conjectured that this may be the confinement mechanism for QCD, since just as a Schwarzschild black hole will permanently confine anything which carries the charge of general relativity (mass-energy), so this Yang-Mills solution will confine any particle which carries the SU(N) charge.

  11. Quantum Yang-Mills theory: an overview of a programme

    CERN Document Server

    Milsted, Ashley

    2016-01-01

    We present an overview of a programme to understand the low-energy physics of quantum Yang-Mills theory from a quantum-information perspective. Our setting is that of the hamiltonian formulation of pure Yang-Mills theory in the temporal gauge on the lattice. Firstly, inspired by recent constructions for $\\mathbb{Z}/2\\mathbb{Z}$ lattice gauge theory, in particular, Kitaev's toric code, we describe the gauge-invariant sector of hilbert space by introducing a primitive quantum gate: the quantum parallel transporter. We then develop a nonabelian generalisation of laplace interpolation to present an ansatz for the ground state of pure Yang-Mills theory which interpolates between the weak- and strong-coupling RG fixed points. The resulting state acquires the structure of a tensor network, namely, a multiscale entanglement renormalisation ansatz, and allows for the efficient computation of local observables and Wilson loops. Various refinements of the tensor network are discussed leading to several generalisations. ...

  12. Yang-Mills Connections On Orientable and Nonorientable Surfaces

    CERN Document Server

    Ho, Nan-Kuo

    2007-01-01

    In math.SG/0605587, we studied Yang-Mills functional on the space of connections on a principal G_R-bundle over a closed, connected, nonorientable surface, where G_R is any compact connected Lie group. In this sequel, we generalize the discussion in "The Yang-Mills equations over Riemann surfaces" by Atiyah and Bott, and math.SG/0605587. We obtain explicit descriptions (as representation varieties) of Morse strata of Yang-Mills functional on orientable and nonorientable surfaces for non-unitary classical groups SO(n) and Sp(n). It turns out to be quite different from the unitary case. In the orientable case, we give a slightly modified version of Laumon and Rapoport's solution to the Atiyah-Bott recursion relation, and use it to write down explicit formulas of rational equivariant Poincar\\'{e} series of the top stratum for SO(n) and Sp(n).

  13. The Role of Promotion in Milling and Bakery Products Sales

    Directory of Open Access Journals (Sweden)

    Sergiu-Bogdan Constantin

    2009-07-01

    Full Text Available Irrespective of the avenue chosen for the retail of milling and bakery products, a key role in sales growth is the one played by promotion, information of the future customers as to the characteristics of the products, the execution and sale conditions. Such information process takes place by means of the promotional mix, consisting of a blend of advertising, sales promotion, public relations tools, trademarks, promotional events, and sales forces. The milling and baking industry uses, to certain extent, all the components of the promotional mix. Product promotion is central both to sales growth, as well as to educating, advising and informing consumers as to how they can select quality milling and bakery products.

  14. Particle size and shape distributions of hammer milled pine

    Energy Technology Data Exchange (ETDEWEB)

    Westover, Tyler Lott [Idaho National Lab. (INL), Idaho Falls, ID (United States); Matthews, Austin Colter [Idaho National Lab. (INL), Idaho Falls, ID (United States); Williams, Christopher Luke [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ryan, John Chadron Benjamin [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-04-01

    Particle size and shape distributions impact particle heating rates and diffusion of volatized gases out of particles during fast pyrolysis conversion, and consequently must be modeled accurately in order for computational pyrolysis models to produce reliable results for bulk solid materials. For this milestone, lodge pole pine chips were ground using a Thomas-Wiley #4 mill using two screen sizes in order to produce two representative materials that are suitable for fast pyrolysis. For the first material, a 6 mm screen was employed in the mill and for the second material, a 3 mm screen was employed in the mill. Both materials were subjected to RoTap sieve analysis, and the distributions of the particle sizes and shapes were determined using digital image analysis. The results of the physical analysis will be fed into computational pyrolysis simulations to create models of materials with realistic particle size and shape distributions. This milestone was met on schedule.

  15. Plate Shape Control Theory and Experiment for 20-high Mill

    Institute of Scientific and Technical Information of China (English)

    Zheng-wen YUAN; Hong XIAO

    2015-01-01

    Roll lfattening theory is an important part of plate shape control theories for 20-high mill. In order to improve the ac-curacy of roll lfattening calculation for 20-high mill, a new and more accurate roll lfattening model was proposed. In this model, the roll barrel was considered as a ifnite length semi-inifnite body. Based on the boundary integral equation method, the numerical solution of the ifnite length semi-inifnite body under the distributed force was obtained and an accurate roll lfattening model was established. Coupled with roll bending model and strip plastic deformation, a new and more accurate plate control model for 20-high mill was established. Moreover, the effects of the ifrst intermediate roll taper angle and taper length were analyzed. The ten-sion distribution calculated by analytical model was consistent with the experimental results.

  16. NUMERICAL EVALUATION OF TEMPERATURE DISTRIBUTION IN THE ROLLING MILL ROLLS

    Directory of Open Access Journals (Sweden)

    José Claudino de Lira Júnior

    2013-06-01

    Full Text Available In hot rolling processes occur changes in the profile of the rolling mill rolls (expansion and contraction and constant wear due to mechanical stress and continuous thermal cycles of heating/cooling caused by contact rolled material- working roll and the cooling system by water jets in their surface, decreasing their lifetime. This paper presents a computational model to simulate the thermal performance of rolling mill rolls. The model was developed using the finite volume method for a transient two-dimensional system and allows calculating the temperature distribution of the rolling mill rolls under various conditions of service. Here it is investigated the influence of flow rate and temperature of the cooling water on the temperature distribution. The results show that the water temperature has greater influence than the water flow to control the surface temperature of the cylinders.

  17. Milling technological experiments to reduce Fusarium toxin contamination in wheat

    Directory of Open Access Journals (Sweden)

    Véha A.

    2015-01-01

    Full Text Available We examine 4 different DON-toxin-containing (0.74 - 1.15 - 1.19 - 2.14 mg/kg winter wheat samples: they were debranned and undebranned, and we investigated the flour’s and the by-products’ (coarse, fine bran toxin content changes. SATAKE lab-debranner was used for debranning and BRABENDER lab-mill for the milling process. Without debranning, two sample flours were above the DON toxin limit (0.75 mg/kg, which are waste. By minimum debranning (and minimum debranning mass loss; 6-8%, our experience with whole flour is that the multi-stage debranning measurement significantly reduces the content of the flour’s DON toxin, while the milling by-products, only after careful consideration and DON toxin measurements, may be produced for public consumption and for feeding.

  18. [Pleasure and confusion. A footnote to Freud's translations of Mill].

    Science.gov (United States)

    Molnar, Michael

    2014-01-01

    In 1863 Theodor Gomperz came to England to propose to Helen Taylor Mill, step-daughter of J. S. Mill. For several months he delayed the proposal while studying transcripts of the Philodemus papyri in the Bodleian Library. There a threatening note, supposedly left on his desk, triggered an attack of paranoia. My study of this incident, initially a mere footnote, expanded into an examination of the obscure causes of this attack. The philosophical question of the nature of desire and the researcher's passion to reconstruct a fragmented classical text are related to Gomperz's unfocussed relationship with both Mill and his step-daughter, and his ensuing confusion between reality and fantasy. The incident is considered paradigmatic of the perils of scholarly research, when the desire to possess knowledge becomes entangled with transferential relationships.

  19. New Approach of Envelope Dynamic Analysis for Milling Process

    CERN Document Server

    Bisu, Claudiu-Florinel; Gérard, Alain; Vijelea, V; Anica, Marin

    2012-01-01

    This paper proposes a method to vibration analysis in order to on-line monitoring of milling process quality. Adapting envelope analysis to characterize the milling tool materials is an important contribution to the qualitative and quantitative characterization of milling capacity and a step by modeling the three-dimensional cutting process. An experimental protocol was designed and developed for the acquisition, processing and analyzing three-dimensional signal. The vibration envelope analysis is proposed to detect the cutting capacity of the tool with the optimization application of cutting parameters. The research is focused on FFT Fourier transform optimization of vibration analysis and vibration envelope to evaluate the dynamic behavior of the machine/ tool/workpiece

  20. Effect of Milling Time on Al-Fe-Cr-20 Wt. % Al2O3composite Prepared Through Ball Milling

    Directory of Open Access Journals (Sweden)

    Hameedur Rehman Khan

    2014-07-01

    Full Text Available One of the main challenges towards achieving a homogeneous distribution of the ceramic phase in the metal matrix composites is agglomeration of the reinforcement particles. Mechanical alloying is among the most important processing techniques used for manufacturing of metal matrix composites (MMCs.An attempt was made to synthesize Al-Fe-Cr-Al2O3composites synthesized through mechanical alloying. Al2O3 is used as reinforcement. Ethanol (5 wt. % has been used as a process control agent (PCA. Mechanical alloying is carried out in a conventional ball mill using stainless steel grinding media at 115 rpm in the argon environment for 5h, 10h and 15h. The ball to powder weight ratio was maintained at 20:1. The characterization of the ball milled powder was followed by scanning electron microscopy (SEM. Showed the formation of a homogeneous phase for all compositions after milling for 15 h. XRD patterns were recorded for the milled powders, and analyzed using Williamson–Hall method and Scherrer’s equation to determine the lattice strain and grain size.EDX is performed to check the contamination of composites during the mechanical alloying.XRD is used to study structural evolution of synthesized aluminium composite. Effect of milling time is investigated on synthesized Al-Fe-Cr-20 wt. % Al2O3 composites.

  1. Multilayered piezoceramic microactuators formed by milling in the green state

    Science.gov (United States)

    Simu, Urban; Johansson, Stefan A. I.

    1999-10-01

    Methods for the fabrication of piezoceramic microactuators that will be used in a miniaturized robot have been investigated. Multilayered structures for piezoceramic microactuators are usually fabricated by tape casting and lamination. The present structures are fabricated with a wet building process where thin layers of ceramic slurry and screen-printed electrodes are cast sequentially. The use of multilayered structures reduces the drive voltage to common levels for integrated circuits, but also result in difficulties forming complicated shapes. Dicing is a straightforward alternative to achieve a simple geometry, but it can not machine e.g. a hollow cylindrical structure. There are several methods that could be used, but only few that would be cost-efficient for large-scale production. One of these is milling with modern high-precision CNC machine tools. Conventional milling of sintered ceramic components would result in many problems since the material is rather brittle and cracks are easily formed. Cracks are detrimental to the mechanical properties as well as for the electrical properties. Milling in the ceramic green state appears to be a promising method, since microcracks does not arise. The relatively soft green body puts great demands on the milling process. A high speed of the spindle is necessary to achieve low cutting forces since sub-millimeter cutting tools are used. The paper present result from different milling test and discusses how the machining parameters affect the resulting shape. The resolution is comparable with other techniques and it can be concluded that it is sufficient for normal screen-printed multilayered components. The evaluation of resulting deformation of the material after milling and sintering is presented.

  2. Investigating Genetic Diversity of Foeniculum Vulgare Mill using Molecular Markers

    Directory of Open Access Journals (Sweden)

    Omid Jadidi

    2016-06-01

    Full Text Available Medicinal plants are considered valuable genetic resources in Iran. One of these medicinal as well as spice plants is Foeniculum Vulgare Mill from Umbellifetae family used in different industries such as food, medicine, and cosmetics. It seems that due to different climate conditions in Iran this plant represents a high and valuable genetic diversity; therefore, management of genetic resources protection and obtaining information about genetic diversity will help awareness of evolution processes as well as genetic erosion of this valuable plant. Genetic diversity in local masses of Foeniculum Vulgare Mill can be investigated using molecule markers such as AFLP, RAPD, ISSR, SRAP, RFLP, and so on. In investigation of over 30 ecotype of local Foeniculum Vulgare Mill, different markers have shown that mean polymorphic content (PIC is about 36% and mean genetic diversity is estimated about 40% in different samples. Data obtained from molecule software analyses help to categorize Foeniculum Vulgare Mill genotype in different groups based on climate and geographical conditions. Principle components analysis (PCOA has also confirmed the results of cluster analysis. Dendrogram obtained by cluster analysis based on similarity coefficient of simple matching (SM and UPGMA algorithm can also categorize population of Foeniculum Vulgare Mill in different groups. Results of molecular variance analysis (AMOVA have shown that most genetic variance between geographical groups can be seen in populations. In general, according to investigations, there is a significant genetic diversity regarding agronomic and molecular traits of Foeniculum Vulgare Mill masses in Iran and knowing this genetic diversity will help in breeding programs, complementary studies, categorization, and so on.

  3. Evaluation of the Phytotoxic and Genotoxic Potential of Pulp and Paper Mill Effluent Using Vigna radiata and Allium cepa

    Directory of Open Access Journals (Sweden)

    Izharul Haq

    2016-01-01

    Full Text Available Pulp and paper mill effluent induced phytotoxicity and genotoxicity in mung bean (Vigna radiata L. and root tip cells of onion (Allium cepa L. were investigated. Physicochemical characteristics such as electrical conductivity (EC, biological oxygen demand (BOD5, chemical oxygen demand (COD, and total phenols of the pulp and paper mill effluent were beyond the permissible limit specified for the discharge of effluent in inland water bodies. Compared to control plants, seedling exposed to 100% effluent concentration showed a reduction in root and shoot length and biomass by 65%, 67%, and 84%, respectively, after 5 days of treatment. A. cepa root tip cells exposed to effluent concentrations ranging from 25 to 100% v/v showed a significant decrease in mitotic index (MI from 32 to 11% with respect to control root tip cells (69% indicating effluent induced cytotoxicity. Further, the effluent induced DNA damage as evidenced by the presence of various chromosomal aberrations like stickiness, chromosome loss, anaphase bridge, c-mitosis, tripolar anaphase, vagrant chromosome, and telophase bridge and micronucleated and binucleated cell in A. cepa. Findings of the present study indicate that pulp and paper mill effluents may act as genotoxic and phytotoxic agents in plant model system.

  4. Paper sludge (PS) to bioethanol: Evaluation of virgin and recycle mill sludge for low enzyme, high-solids fermentation.

    Science.gov (United States)

    Boshoff, Sonja; Gottumukkala, Lalitha Devi; van Rensburg, Eugéne; Görgens, Johann

    2016-03-01

    Paper sludge (PS) from the paper and pulp industry consists primarily of cellulose and ash and has significant potential for ethanol production. Thirty-seven PS samples from 11 South African paper and pulp mills exhibited large variation in chemical composition and resulting ethanol production. Simultaneous saccharification and fermentation (SSF) of PS in fed-batch culture was investigated at high solid loadings and low enzyme dosages. Water holding capacity and viscosity of the PS influenced ethanol production at elevated solid loadings of PS. High viscosity of PS from virgin pulp mills restricted the solid loading to 18% (w/w) at an enzyme dosage of 20 FPU/gram dry PS (gdPS), whereas an optimal solid loading of 27% (w/w) was achieved with corrugated recycle mill PS at 11 FPU/gdPS. Ethanol concentration and yield of virgin pulp and corrugated recycle PS were 34.2g/L at 66.9% and 45.5 g/L at 78.2%, respectively.

  5. Co-composting of solid and liquid olive mill wastes: management aspects and the horticultural value of the resulting composts.

    Science.gov (United States)

    Aviani, I; Laor, Y; Medina, Sh; Krassnovsky, A; Raviv, M

    2010-09-01

    Successful co-composting of solid and liquid olive mill wastes (OMW) and obtaining a product of horticultural value may increase the viability of this recycling approach. Two composting cycles were performed, in which olive mill solid wastes (OMSW) were used to form five mixtures, wetted either with fresh water or with olive mill wastewater (OMWW). Up to approximately 0.3m(3) of OMWW could be applied to each m(3) of the raw materials without negatively affecting the chemical, physical and horticultural properties of the resulted composts. A growing media composed of perlite amended with 25-33% OMW-composts showed higher suppressiveness against Fusarium oxysporum f. sp. melonis as compared to equivalent perlite:peat moss mixtures. The yields of tomato plants grown in peat moss amended with 20% (v:v) of OMW-composts were not significantly different than plants grown in unamended peat. The viability of co-composting as a treatment approach for OMWW is discussed in the context of management aspects and the horticultural value of the final product.

  6. Effluent monitoring at a bleached kraft mill: directions for best management practices for eliminating effects on fish reproduction.

    Science.gov (United States)

    Martel, Pierre H; Kovacs, Tibor G; O'connor, Brian I; Semeniuk, Sharon; Hewitt, L Mark; Maclatchy, Deborah L; McMaster, Mark E; Parrott, Joanne L; van den Heuvel, Michael R; Van Der Kraak, Glen J

    2011-01-01

    A long-term monitoring study was conducted on effluents from a bleached kraft pulp and paper mill located in Eastern Canada. The study was designed to gain insights into temporal effluent variability with respect to fish reproduction as it related to production upsets, mill restarts and conditions affecting biological treatment performance. Final effluent quality was monitored between February 2007 and May 2009 using biochemical and chemical oxygen demand, total suspended solids, resin and fatty acids, a gas chromatographic profiling index, and the presence of methyl substituted 2-cyclopentenones. Selected effluent samples were evaluated for effects on fish reproduction (egg production) using a shortened version of the adult fathead minnow reproductive test. The events relating to negative effects on fish reproduction were upsets of the pulping liquor recovery system resulting in black liquor losses, operational upsets of the hardwood line resulting in the loss of oxygen delignification filtrates, and conditions that reduced the performance of biological treatment (e.g., mill shutdown and low ambient temperatures). The reductions in egg production observed in fathead minnow were associated with biochemical oxygen demand values > 20 mg/L, GC profiling indices > 1.2 and the presence of methyl-substituted 2-cyclopentenones at concentrations > 100 μg/L. This study demonstrated the importance of both in-plant measures for controlling the loss of organics as well as the optimum operation of biological effluent treatment for eliminating effluent-related effects on fish reproduction (egg production) in the laboratory.

  7. Optimization of operating variables for production of ultra-fine talc in a stirred mill. Specific surface area investigations

    Directory of Open Access Journals (Sweden)

    Toraman Oner Yusuf

    2016-01-01

    Full Text Available Due to its properties such as chemical inertness, softness, whiteness, high thermal conductivity, low electrical conductivity and adsorption properties talc has wide industrial applications in paper, cosmetics, paints, polymer, ceramics, refractory materials and pharmaceutical. The demand for ultra-fine talc is emerging which drives the mineral industry to produce value added products. In this study, it was investigated how certain grinding parameters such as mill speed, ball filling ratio, powder filling ratio and grinding time of dry stirred mill affect grindability of talc ore (d97=127 μm. A series of laboratory experiments using a 24 full factorial design was conducted to determine the optimal operational parameters of a stirred mill in order to minimize the specific surface area. The main and interaction effects on the volume specific surface area (SV, m2.cm−3 of the ground product were evaluated using the Yates analysis. Under the optimal conditions at the stirrer speed of 600 rpm, grinding time of 20 min, sample mass of 5% and ball ratio of 70%, the resulting talc powder had larger volume specific surface area (i.e., 3.48 m2.cm−3 than the starting material (i.e., 1.84 m2.cm−3.

  8. The construction of the milling process simulation models

    Science.gov (United States)

    Ślusarczyk, Ł.

    2016-09-01

    The paper has aimed at presentation of the possibilities of using computer-based techniques into scope of machine cutting processes, and mostly of analytical and numerical modeling of the milling process for austenitic high-alloy chromium-nickel steel X 5 CrNi 18-10 and verification of the results experiments. The study was mostly focused on measuring and assessment of deformations in the given sample with the specific load. The simulations were executed in modern computer simulation software which supports such activities. These include: NX by Siemens and Simulia Abaqus. The selection of parameters was based on the real values measured during the milling process.

  9. Equivariance on Discrete Space and Yang-Mills-Higgs Model

    CERN Document Server

    Ikemori, Hitoshi; Matsui, Yoshimitsu; Otsu, Hideharu; Sato, Toshiro

    2015-01-01

    We introduce the basic equivariant quantity $Q$ in the gauge theory on the noncommutative descrete $Z_{2}$ space, which plays an important role for the equivariant dimensional reduction. If the gauge configuration of the ground state on the extra dimensional space is described by the equivariant $Q$, then the extra dimensional space is invisible. Especially, using the equivariance principle, we show that the Yang-Mills theory on $R^{2}\\times Z_{2}$ space is equivalent to the Yang-Mills-Higgs model on $R^{2}$ space. It can be said that this model is the simplest model of this type.

  10. All tree amplitudes of supersymmetric Einstein-Yang-Mills theory

    CERN Document Server

    Adamo, Tim; Roehrig, Kai A; Skinner, David

    2015-01-01

    We present a new formula for all tree amplitudes in four dimensional supergravity coupled to super Yang-Mills. Like the Cachazo-He-Yuan formula, our expression is supported on solutions of the scattering equations, but with momenta written in terms of spinor helicity variables. Supersymmetry and parity are both manifest. In the pure gravity and pure Yang-Mills sectors, it reduces to the known twistor-string formulae. We show that the formula behaves correctly under factorization. We sketch how these amplitudes may be obtained from a four-dimensional (ambi)twistor string.

  11. Global coupled equations for dynamic analysis of planishing mill

    Institute of Scientific and Technical Information of China (English)

    蔡敢为; 钟掘

    2003-01-01

    The dynamic properties of rolling mill are significantly influenced by many coupling factors. Accordingto the coupled mechanical and electric dynamics theory, the global coupled equations for the dynamic analysis ofplanishing mill CM04 of Shanghai Baosteel Group Corporation were derived, by using finite element methods. Theseelasto-dynamic equations establish the coupling relations among the stand vibration system, torsional vibration sys-tem, driving motors, etc. It provides theoretical basis to a certain extent for globally dynamic simulation, analysis ofstability of motion, prediction of abnormal operating mode, globally optimum design and control, etc.

  12. Leaching of 226Ra from components of uranium mill tailings

    Science.gov (United States)

    Landa, E.R.

    1991-01-01

    A sequential extraction procedure was used to characterize the geochemical forms of 226Ra retained by mixtures of quartz sand and a variety of fine-grained rock and mineral species. These mixtures had previously been exposed to the sulfuric acid milling liquor of a simulated acid-leach uranium milling circuit. For most test cases, the major fraction of the 226Ra was extracted with 1 mol/1 NH4Cl and was deemed to be exchangeable. However, 226Ra retained by the barite-containing mixture was resistant to both 1 mol/1 NH4Cl and 1 mol/HCHCl extraction. ?? 1991.

  13. Field-dependent BRST transformations in Yang-Mills theory

    CERN Document Server

    Lavrov, Peter M

    2013-01-01

    We find an explicit form for the Jacobian of arbitrary field-dependent BRST transformations in Yang-Mills theory. For the functional-integral representation of the (gauge-fixed) Yang-Mills vacuum functional, such transformations merely amount to a precise change in the gauge-fixing functional. This proves the independence of the vacuum functional under any field-dependent BRST transformation. We also give a formula for the transformation parameter functional which generates a prescribed change of gauge and evaluate it for connecting two arbitrary R_xi gauges.

  14. Field-dependent BRST transformations in Yang–Mills theory

    Energy Technology Data Exchange (ETDEWEB)

    Lavrov, Peter M., E-mail: lavrov@tspu.edu.ru [Tomsk State Pedagogical University, Kievskaya St. 60, 634061 Tomsk (Russian Federation); Lechtenfeld, Olaf, E-mail: lechtenf@itp.uni-hannover.de [Institut für Theoretische Physik and Riemann Center for Geometry and Physics, Leibniz Universität Hannover, Appelstrasse 2, 30167 Hannover (Germany)

    2013-10-01

    We find an explicit form for the Jacobian of arbitrary field-dependent BRST transformations in Yang–Mills theory. For the functional-integral representation of the (gauge-fixed) Yang–Mills vacuum functional, such transformations merely amount to a precise change in the gauge-fixing functional. This proves the independence of the vacuum functional under any field-dependent BRST transformation. We also give a formula for the transformation parameter functional which generates a prescribed change of gauge and evaluate it for connecting two arbitrary R{sub ξ} gauges.

  15. Field-dependent BRST transformations in Yang-Mills theory

    Science.gov (United States)

    Lavrov, Peter M.; Lechtenfeld, Olaf

    2013-10-01

    We find an explicit form for the Jacobian of arbitrary field-dependent BRST transformations in Yang-Mills theory. For the functional-integral representation of the (gauge-fixed) Yang-Mills vacuum functional, such transformations merely amount to a precise change in the gauge-fixing functional. This proves the independence of the vacuum functional under any field-dependent BRST transformation. We also give a formula for the transformation parameter functional which generates a prescribed change of gauge and evaluate it for connecting two arbitrary Rξ gauges.

  16. Effect of milling time on the formation of carbon nanotube by mechano-thermal method

    Indian Academy of Sciences (India)

    Ertan Evin; Ömer Güler; Mustafa Aksoy; Seval Hale Güler

    2015-08-01

    Mechano-thermal method was used for synthesizing the carbon nanotubes (CNTs) in this study. In this method, graphite powders in the elemental form were firstly exposed to milling process in high-energy ball milling and then the milled powders were annealed at high temperatures. As a result of milling of the graphite, ultra-active disordered carbon structures were obtained. This structure serves as a carbon source for the formation of nanotubes during the annealing process. This study investigated the effect of the milling process. For this purpose, graphite powders were milled at different periods such as 5 and 150 h and then annealed at 1600°C. The transmission electron microscopy and scanning electron microscopy examinations demonstrated that CNTs formed in samples milled both for 5 and 150 h. However, the difference in the milling time influenced the amount of CNTs, their size and the formation of other structures except from nanotubes.

  17. Effects and mechanism of ball milling on torrefaction of pine sawdust.

    Science.gov (United States)

    Gong, Chunxiao; Huang, Jing; Feng, Chen; Wang, Guanghui; Tabil, Lope; Wang, Decheng

    2016-08-01

    The effects and mechanism of ball milling on the torrefaction process were studied. Ball- and hammer-milled (screen size 1mm) pine sawdust samples were torrefied at three temperatures (230, 260, and 290°C) and two durations (30 and 60min) to investigate into their torrefaction behavior and physicochemical properties. The results showed that, under identical torrefaction conditions, torrefied ball-milled pine sawdust had a higher carbon content and fixed carbon, and lower hydrogen and oxygen contents than torrefied hammer-milled pine sawdust. Torrefied ball-milled pine sawdust produced lower mass and energy yields, but higher heating values than torrefied hammer-milled pine sawdust. Ball milling destroyed the crystalline structure of cellulose and thus reduced the thermal stability of hemicellulose, cellulose, and lignin, causing them to degrade at relatively lower temperatures. In conclusion, biomass pretreated with a combination of ball milling and torrefaction has the potential to produce an alternative fuel to coal.

  18. Õppimine on tudengi töö, mille eest tuleks palka maksta / Jaan Urb

    Index Scriptorium Estoniae

    Urb, Jaan

    2006-01-01

    Pärnu linnavolikogu liige Rahvaliidu ettepanekust, mille kohaselt peaksid tudengipalka saama kõik õppurid, kes õpivad õppekava järgi, millel on riiklik koolitustellimus ning mille on akrediteerinud rahvusvaheline komisjon

  19. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Site in Lakeview, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    1994-10-01

    This Baseline Risk Assessment of Ground Water Contamination at the Uranium Mill Tailings Site in Lake view, Oregon evaluates potential impacts to public health or the environment resulting from ground water contamination at the former uranium mill processing site.

  20. 76 FR 14105 - International Paper Company, Pineville Mill Industrial Packaging Group; Pineville, LA; Notice of...

    Science.gov (United States)

    2011-03-15

    ... Employment and Training Administration International Paper Company, Pineville Mill Industrial Packaging Group... workers and former workers of International Paper Company, Pineville Mill, Industrial Packaging Group... International Paper Company (subject firm) nor any of its customers imported articles like or...

  1. Temperature Control of Hot Strip Finishing Mill with Inter Stand Cooling

    Science.gov (United States)

    Sekiguchi, Kunio; Anbe, Yoshiharu; Imanari, Hiroyuki

    It is important for hot strip mill to keep finishing mill delivery temperature to it’s target value because of yield strength and tensile strength of rolled strip. We propose a new method for finishing mill delivery temperature control (FDTC) of a hot strip mill using inter stand strip coolant (ISC). FDTC consists of initial setting (before threading) values calculation of ISC flow rate and finishing mill speed, feed forward FDTC (FF-FDTC) and feedback FDTC (FB-FDTC). The mathematical strip temperature model of finishing mill was identified using normal operating data and some tests. Actual mill application with 7 stands finishing mill showed good FDTC results and also it made possible to increase rolling speed which increase production rate.

  2. Ultra-high aspect ratio replaceable AFM tips using deformation-suppressed focused ion beam milling

    DEFF Research Database (Denmark)

    Savenko, Alexey; Yildiz, Izzet; Petersen, Dirch Hjorth;

    2013-01-01

    Fabrication of ultra-high aspect ratio exchangeable and customizable tips for atomic force microscopy (AFM) using lateral focused ion beam (FIB) milling is presented. While on-axis FIB milling does allow high aspect ratio (HAR) AFM tips to be defined, lateral milling gives far better flexibility...... FIB milling strategies for obtaining sharper tips are discussed. Finally, assembly of the HAR tips on a custom-designed probe as well as the first AFM scanning is shown....

  3. Study on High-Performance Computing for Simulation of End Milling Force

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Milling Process Simulation is one of the important re search areas in manufacturing science. For the purpose of improving the prec ision of simulation and extending its usability, numerical algorithm is more and more used in the milling modeling areas. But simulative efficiency is decreasin g with increase of its complexity. As a result, application of the method is lim ited. Aimed at above question, high-efficient algorithm for milling process sim ulation is studied. It is important for milling process...

  4. NUMERICAL SIMULATION OF EXTRUSION OF COMPOSITE POWDERS PREPARED BY HIGH ENERGY MILLING

    Institute of Scientific and Technical Information of China (English)

    X.Q. Li; W.P. Chen; W. Xia; Q.L. Zhu; Y.Y. Li; E.D. Wang

    2004-01-01

    Based on the characteristic of high energy milling and the micromechanics of composite material, a plastic constitutive equation is implemented for milled composite powders. To check the equation, the extrusion of Ti/Al composite powders prepared by high energy milling was simulated. It was from the numerical analysis that the predicted extrusion pressure mounted up with milling time and extrusion ratio increasing,which was perfect agreement with experimental results.

  5. Study on End Milling Generation Surface Model and Simulation in View of Main Axle s Tolerance

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    In accordance with the relative movement between end-milling cutter and workpiece surface, a theoretical generation model for milled surface was established with the movement error of principal axle considered. Then the milled surfaces under various cutting condition were simulated, the results of which showed that end milled surfaces were of "vaulted profile", heights of surface irregularty at various points to be different with maximum value in the middle and smaller at both sides, the difference were ...

  6. Microwave Absorption Properties of Iron Nanoparticles Prepared by Ball-Milling

    Science.gov (United States)

    Chu, Xuan T. A.; Ta, Bach N.; Ngo, Le T. H.; Do, Manh H.; Nguyen, Phuc X.; Nam, Dao N. H.

    2016-05-01

    A nanopowder of iron was prepared using a high-energy ball milling method, which is capable of producing nanoparticles at a reasonably larger scale compared to conventional chemical methods. Analyses using x-ray diffraction and magnetic measurements indicate that the iron nanoparticles are a single phase of a body-centered cubic structure and have quite stable magnetic characteristics in the air. The iron nanoparticles were then mixed with paraffin and pressed into flat square plates for free-space microwave transmission and reflection measurements in the 4-8 GHz range. Without an Al backing plate, the Fe nanoparticles seem to only weakly absorb microwave radiation. The reflected signal S 11 drops to zero and a very large negative value of reflection loss ( RL) are observed for Al-backed samples, suggesting the existence of a phase matching resonance near frequency f ˜ 6 GHz.

  7. New technology for recycling materials from oily cold rolling mill sludge

    Institute of Scientific and Technical Information of China (English)

    Bo Liu; Shen-gen Zhang; Jian-jun Tian; De-an Pan; Ling Meng; Yang Liu

    2013-01-01

    Oily cold rolling mill (CRM) sludge is one of metallurgical industry solid wastes. The recycle of these wastes can not only protect the environment but also permit their reutilization. In this research, a new process of“hydrometallurgical treatment+hydrothermal synthesis”was investigated for the combined recovery of iron and organic materials from oily CRM sludge. Hydrometallurgical treatment, mainly including acid leaching, centrifugal separation, neutralization reaction, oxidizing, and preparation of hydrothermal reaction precursor, was first utilized for processing the sludge. Then, micaceous iron oxide (MIO) pigment powders were prepared through hydrothermal reaction of the obtained precursor in alkaline media. The separated organic materials can be used for fuel or chemical feedstock. The quality of the prepared MIO pigments is in accordance with the standards of MIO pigments for paints (ISO 10601-2007). This clean, eff ective, and economical technology off ers a new way to recycle oily CRM sludge.

  8. Biological decolourisation of pulp mill effluent using white rot fungus Trametes versicolor.

    Science.gov (United States)

    Srinivasan, S V; Murthy, D V S; Swaminathan, T

    2012-07-01

    The conventional biological treatment methods employed in the pulp and paper industries are not effective in reducing the colour and chemical oxygen demand (COD). The white-rot fungi are reported to have the ability to biodegrade the lignin and its derivatives. This paper is focused on the biological treatment of pulp mill effluent from a bagasse-based pulp and paper industry using fungal treatment. Experiments were conducted using the white rot fungus, Trametes versicolor in shake flasks operated in batch mode with different carbon sources. The decolourisation efficiencies of 82.5% and 80.3% were obtained in the presence of 15 g/L and 5 g/L of glucose and sucrose concentrations respectively with a considerable COD reduction. The possibility of reusing the grown fungus was examined for repeated treatment studies.

  9. Polishing of treated palm oil mill effluent (POME) from ponding system by electrocoagulation process.

    Science.gov (United States)

    Bashir, Mohammed J K; Mau Han, Tham; Jun Wei, Lim; Choon Aun, Ng; Abu Amr, Salem S

    2016-01-01

    As the ponding system used to treat palm oil mill effluent (POME) frequently fails to satisfy the discharge standard in Malaysia, the present study aimed to resolve this problem using an optimized electrocoagulation process. Thus, a central composite design (CCD) module in response surface methodology was employed to optimize the interactions of process variables, namely current density, contact time and initial pH targeted on maximum removal of chemical oxygen demand (COD), colour and turbidity with satisfactory pH of discharge POME. The batch study was initially designed by CCD and statistical models of responses were subsequently derived to indicate the significant terms of interactive process variables. All models were verified by analysis of variance showing model significances with Prob > F electrocoagulation process optimized by CCD.

  10. Sequential treatment of olive oil mill wastewater with adsorption and biological and photo-Fenton oxidation.

    Science.gov (United States)

    Aytar, Pınar; Gedikli, Serap; Sam, Mesut; Farizoğlu, Burhanettin; Çabuk, Ahmet

    2013-05-01

    Olive oil mill wastewater (OMWW), a recalcitrant pollutant, has features including high phenolic content and dark color; thereby, several chemical or physical treatments or biological processes were not able to remediate it. In this study, the treatment efficiencies of three treatments, including adsorption, biological application, and photo-Fenton oxidation were sequentially evaluated for OMWW. Adsorption, biological treatment, and photo-Fenton caused decreasing phenolic contents of 48.69 %, 59.40 %, and 95 %, respectively. However, after three sequential treatments were performed, higher reduction percentages in phenolic (total 99 %) and organic contents (90 %) were observed. Although the studied fungus has not induced significant color reduction, photo-Fenton oxidation was considered to be an attractive solution, especially for color reduction. Besides, toxicity of OMWW treatment was significantly reduced.

  11. Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant.

    Science.gov (United States)

    Bhatia, Subhash; Othman, Zalina; Ahmad, Abdul Latif

    2007-06-25

    Moringa oleifera seeds, an environmental friendly and natural coagulant are reported for the pretreatment of palm oil mill effluent (POME). In coagulation-flocculation process, the M. oleifera seeds after oil extraction (MOAE) are an effective coagulant with the removal of 95% suspended solids and 52.2% reduction in the chemical oxygen demand (COD). The combination of MOAE with flocculant (NALCO 7751), the suspended solids removal increased to 99.3% and COD reduction was 52.5%. The coagulation-flocculation process at the temperature of 30 degrees C resulted in better suspended solids removal and COD reduction compared to the temperature of 40, 55 and 70 degrees C. The MOAE combined with flocculant (NALCO 7751) reduced the sludge volume index (SVI) to 210mL/g with higher recovery of dry mass of sludge (87.25%) and water (50.3%).

  12. Simulation model of pollution spreading in the water bodies affected by mining mill

    Directory of Open Access Journals (Sweden)

    Kalinkina Natalia Mikhailovna

    2015-09-01

    Full Text Available Water bodies of the northern Karelia are polluted by liquid wastes of Kostomukshsky iron ore-dressing mill. The main components of these wastes are potassium ions. The processes of the potassium spreading in lake-river system of the River Kenty were studied using simulation modeling. For water bodies, where chemical observations were not carried out, the reconstruction of data was realized. The parameters of the model (constants of potassium transfer for seven lakes were calculated. These constants reflect the hydrological regime of water bodies and characterize high-speed transfer of potassium in the upstream and downstream, and low transfer rate - in the middle stream. It is shown that the vast majority of potassium (70% is carried out of the system Kenty and enters the lake Srednee Kuito

  13. Modeling the milling tool wear by using an evolutionary SVM-based model from milling runs experimental data

    Science.gov (United States)

    Nieto, Paulino José García; García-Gonzalo, Esperanza; Vilán, José Antonio Vilán; Robleda, Abraham Segade

    2015-12-01

    The main aim of this research work is to build a new practical hybrid regression model to predict the milling tool wear in a regular cut as well as entry cut and exit cut of a milling tool. The model was based on Particle Swarm Optimization (PSO) in combination with support vector machines (SVMs). This optimization mechanism involved kernel parameter setting in the SVM training procedure, which significantly influences the regression accuracy. Bearing this in mind, a PSO-SVM-based model, which is based on the statistical learning theory, was successfully used here to predict the milling tool flank wear (output variable) as a function of the following input variables: the time duration of experiment, depth of cut, feed, type of material, etc. To accomplish the objective of this study, the experimental dataset represents experiments from runs on a milling machine under various operating conditions. In this way, data sampled by three different types of sensors (acoustic emission sensor, vibration sensor and current sensor) were acquired at several positions. A second aim is to determine the factors with the greatest bearing on the milling tool flank wear with a view to proposing milling machine's improvements. Firstly, this hybrid PSO-SVM-based regression model captures the main perception of statistical learning theory in order to obtain a good prediction of the dependence among the flank wear (output variable) and input variables (time, depth of cut, feed, etc.). Indeed, regression with optimal hyperparameters was performed and a determination coefficient of 0.95 was obtained. The agreement of this model with experimental data confirmed its good performance. Secondly, the main advantages of this PSO-SVM-based model are its capacity to produce a simple, easy-to-interpret model, its ability to estimate the contributions of the input variables, and its computational efficiency. Finally, the main conclusions of this study are exposed.

  14. XRD and Moessbauer characterization of iron-doped SnO{sub 2} powders obtained by ball-milling

    Energy Technology Data Exchange (ETDEWEB)

    Brito, A.D.B. de; Alves, H.W.L.; Raposo, M.T. [Universidade Federal de Sao Joao del-Rei (UFSJ), MG (Brazil); Ardisson, J.D. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2012-07-01

    Full text: Rutile SnO{sub 2} (or cassiterite) is a semiconductor oxide, with many industrial applications, mainly as spin source for spintronics because of the relevant electronic and magnetic properties changes when doped with transition elements (TE) like Fe, Co, Ni and Co. Therefore, it is meaningful for the materials science research to study the properties of SnO{sub 2} nanomaterials doped by a TE ion. In this work, mechanical alloying process has been used to produce SnO{sub 2} doped with iron. The samples were characterized by X-Ray and Moessbauer spectroscopy. The crystalline alloy were obtained by milling in a planetary ball mill with a zirconia milling assembly for up to 24 hours in air, at room temperature. The mill rotation speed was 250 rpm and two different powder-to-ball weight ratios, 1:20 and 1:10, were used. X-ray diffraction analyses of SnO{sub 2} powders indicate only the formation of the cassiterite phase. X-Ray diffraction results of SnO{sub 2} doped with 10% of iron show some peaks quite wider when compared with diffraction peaks of the undoped samples, suggesting the absorption of iron probably in a new phase with tin. However, this phase cannot be identified by X-Ray diffraction. Moessbauer spectroscopy analyses (table below) indicate the presence of 85% of {alpha}-Fe and two new phases, both related to Fe-Sn phase magnetically disordered. On the other hand, {sup 119}Sn-Moessbauer spectroscopy measurements show the presence of tetrahedral tin (IV), chemical environment of the tin species. Based on the obtained results, thermal annealing and new measurements with both XRD and Moessbauer spectroscopies will be performed and compared with them. (author)

  15. Degradation and biodegradability improvement of the olive mill wastewater by peroxi-electrocoagulation/electrooxidation-electroflotation process with bipolar aluminum electrodes.

    Science.gov (United States)

    Esfandyari, Yahya; Mahdavi, Yousef; Seyedsalehi, Mahdi; Hoseini, Mohammad; Safari, Gholam Hossein; Ghozikali, Mohammad Ghanbari; Kamani, Hossein; Jaafari, Jalil

    2015-04-01

    Olive mill wastewater is considered as one of the most polluting effluents of the food industry and constitutes a source of important environmental problems. In this study, the removal of pollutants (chemical oxygen demand (COD), biochemical oxygen demand (BOD5), polyphenols, turbidity, color, total suspended solids (TSS), and oil and grease) from olive oil mill processing wastewater by peroxi-electrocoagulation/electrooxidation-electroflotation process with bipolar aluminum electrodes was evaluated using a pilot continuous reactor. In the electrochemical unit, aluminum (Al), stainless steel, and RuO2/Ti plates were used. The effects of pH, hydrogen peroxide doses, current density, NaCl concentrations, and reaction times were studied. Under optimal conditions of pH 4, current density of 40 mA/m(2), 1000 mg/L H2O2, 1 g/L NaCl, and 30-min reaction time, the peroxi-electrochemical method yielded very effective removal of organic pollution from the olive mill wastewater diluted four times. The treatment process reduced COD by 96%, BOD5 by 93.6%, total, polyphenols by 94.4%, color by 91.4%, turbidity by 88.7, suspended solids by 97% and oil and grease by 97.1%. The biodegradability index (BOD5/COD) increased from 0.29 to 0.46. Therefore, the peroxi-electrocoagulation/electrooxidation-electroflotation process is considered as an effective and feasible process for pre-treating olive mill wastewater, making possible a post-treatment of the effluent in a biological system.

  16. Adopting strategies to improve the efficiency of ozonation in the real-scale treatment of olive oil mill wastewaters.

    Science.gov (United States)

    Martins, Rui C; Silva, Adrián M T; Castro-Silva, Sérgio; Garção-Nunes, Paulo; Quinta-Ferreira, Rosa M

    2010-12-01

    In this experimental work the ozone action on the depuration of olive oil mill wastewater is studied for different operational conditions based on an actual industrial treatment plant. It was verified that the application of a Mn-Ce-O catalyst prepared at the laboratory, with a Mn/Ce molar proportion of 70/30, enhances the depuration efficiency and the effluent biodegradability. Ozonation operation at the natural pH of the effluent is recommended. Moreover, the integration of the Fenton process as a pretreatment improves the final chemical oxygen demand removal and enables a totally biodegradable effluent to be obtained, as confirmed by respirometric techniques.

  17. Physical and Oxidative Stability of Functional olive Oil-in-Water Emulsions Formulated Using Olive Mill Wastewater and Whey Proteins

    OpenAIRE

    Caporaso, Nicola; Genovese, Alessandro; Burke, Roisin; Barry-Ryan, Catherine; Sacchi, Raffaele

    2016-01-01

    The present paper reports on the use of phenolic extracts from olive mill wastewater (OMW) in model olive oil-in-water (O/W) emulsions to study their effect on their physical and chemical stability. Spray-dried OMW polyphenols were added to a model 20% olive O/W emulsion stabilized with whey protein isolate (WPI) and xanthan gum, in phosphate buffer solution at pH 7. The emulsions were characterised under accelerated storage conditions (40 °C) up to 30 days. Physical stability was evaluated b...

  18. Synthesis of FeTi hydrogen storage material via ball milling: effect of milling energy and atmosphere.

    OpenAIRE

    Livramento, Vanessa; Rangel, C. M.; Correia, J. Brito; Shohoji, Nobumitsu; R.A. Silva

    2008-01-01

    Attempts were made earlier to synthesize and activate the FeTi intermetallic during ball milling (BM), for H2 storage using sodium boron tetra-hydride (NaBH4) additive as a process controlling agent. Simple reactive milling starting from Fe and Ti powders resulted in heavy agglomeration of powders, due to the self sustaining nature of the reaction following an incubation period. When NaBH4 was used as the process control agent to avoid agglomeration, this resulted in the production of titaniu...

  19. En route to a multi-model scheme for clinker comminution with chemical grinding aids

    CERN Document Server

    Mishra, R K; Carmona, H A; Wittel, F K; Sawley, M L; Weibel, M; Gallucci, E; Herrmann, H J; Heinz, H; Flatt, R J

    2015-01-01

    We present a multi-model simulation approach, targeted at understanding the behavior of comminution and the effect of grinding aids (GAs) in industrial cement mills. On the atomistic scale we use Molecular Dynamics (MD) simulations with validated force field models to quantify elastic and structural properties, cleavage energies as well as the organic interactions with mineral surfaces. Simulations based on the Discrete Element Method (DEM) are used to integrate the information gained from MD simulations into the clinker particle behavior at larger scales. Computed impact energy distributions from DEM mill simulations can serve as a link between large-scale industrial and laboratory sized mills. They also provide the required input for particle impact fragmentation models. Such a multi-scale, multi-model methodology paves the way for a structured approach to the design of chemical additives aimed at improving mill performance.

  20. Effect of milling on the magnetic properties of Al-Mn obtained by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Betancourt, Mirna, E-mail: betamirna@gmail.com [Instituto Universitario de Tecnologia Cumana (Venezuela, Bolivarian Republic of); Instituto Venezolano de Investigaciones Cientificas, Lab. Materiales, Centro Ingenieria de Materiales y Nanotecnologia (Venezuela, Bolivarian Republic of); Silva, Pedro [Instituto Venezolano de Investigaciones Cientificas, Lab. Materia Condensada, Centro de Fisica (Venezuela, Bolivarian Republic of); Gonzalez, Gema, E-mail: gemagonz@ivic.gob.ve [Instituto Venezolano de Investigaciones Cientificas, Lab. Materiales, Centro Ingenieria de Materiales y Nanotecnologia (Venezuela, Bolivarian Republic of)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer Al-42 at.% Mn transforms to {alpha}-Mn(Al) by mechanical milling after 5 h of milling. Black-Right-Pointing-Pointer Transformation to nano {beta}-Mn is reached after 50 h of milling with 6 nm grain size. Black-Right-Pointing-Pointer Milling strongly affects magnetic behavior. - Abstract: Al-Mn powders were prepared to obtain the compound Mn{sub 42}Al{sub 58} by mechanical alloying. The powders were milled during different periods (1 h, 5 h, 11.5 h, 15 h, 20 h and 50 h) using a SPEX 8000 mixer mill in nitrogen atmosphere. The materials were characterized by X-ray diffraction (XRD) and magnetic properties at room temperature, using a vibrating sample magnetometer (VSM). XRD shows partial transformation to {alpha}-Mn after only 1 h of milling and a mixture of {alpha}-Mn and {beta}-Mn after 11.5 h of milling and further milling resulted in transformation to {beta}-Mn phase with a grain size of 6 nm after 50 h. The change in magnetic properties with milling time is quite dramatic, from a ferromagnetic behavior for {alpha}-Mn(Al) to paramagnetic after 11.5 h of milling and showing again ferromagnetic behavior, with a strong increase of magnetization values of 5.5 emu/g, after 50 h of milling with formation of {beta}-Mn(Al).

  1. 77 FR 35431 - Final Alternative Soils Standards for the Uravan, CO, Uranium Mill

    Science.gov (United States)

    2012-06-13

    ... COMMISSION Final Alternative Soils Standards for the Uravan, CO, Uranium Mill AGENCY: Nuclear Regulatory Commission. ACTION: Notice of Uranium milling alternative standards. SUMMARY: This document announces that on... uranium mill tailings (11e.(2) byproduct material). Six Agreement States have this authority as part...

  2. 76 FR 70170 - Proposed Alternative Soils Standards for the Uravan, Colorado Uranium Mill

    Science.gov (United States)

    2011-11-10

    ... COMMISSION Proposed Alternative Soils Standards for the Uravan, Colorado Uranium Mill AGENCY: Nuclear Regulatory Commission. ACTION: Uranium milling alternative standards. SUMMARY: By letter dated October 10... Agreement States to specifically amend their Agreements to regulate uranium mill tailings (11e.(2)...

  3. Wheat Fields, Flour Mills, and Railroads: A Web of Interdependence. Teaching with Historic Places.

    Science.gov (United States)

    Koman, Rita G.

    By 1860 much of the beauty of St. Anthony Falls in Minneapolis (Minnesota) had been destroyed, as mills on both sides of the river used the power of the falls to turn millions of bushels of wheat into flour. Steel rails linked bonanza farms hundreds of miles to the west to the mills. The mills, the farms, and the railroads depended on each other…

  4. Towards the effective tool wear control in micro-EDM milling

    DEFF Research Database (Denmark)

    Bissacco, Giuliano; Valentincic, J.; Hansen, Hans Nørgaard

    2010-01-01

    The electrode wear in micro-electrical discharge milling (micro-EDM milling) is one of the main problems to be solved in order to improve machining accuracy. This paper presents an investigation on wear and material removal in micro-EDM milling for selected process parameter combinations typical ...

  5. Influence of operating parameters on product size obtained from an EVT No. 35 test mill

    Energy Technology Data Exchange (ETDEWEB)

    Borthwick, I.R.

    1984-01-01

    The broad objective is to undertake fundamental studies into the milling and drying of brown coal to obtain sufficient understanding of the processes involved to enable existing and proposed mill designs to be assessed and improved. The objective of the work reported here is to determine the effect of operating parameters and product moisture content on product size in a small scale EVT mill.

  6. Scale-up from batch to flow-through wet milling process for injectable depot formulation.

    Science.gov (United States)

    Lehocký, Róbert; Pěček, Daniel; Štěpánek, František

    2016-12-01

    Injectable depot formulations are aimed at providing long-term sustained release of a drug into systemic circulation, thus reducing plasma level fluctuations and improving patient compliance. The particle size distribution of the formulation in the form of suspension is a key parameter that controls the release rate. In this work, the process of wet stirred media milling (ball milling) of a poorly water-soluble substance has been investigated with two main aims: (i) to determine the parametric sensitivity of milling kinetics; and (ii) to develop scale-up methodology for process transfer from batch to flow-through arrangement. Ball milling experiments were performed in two types of ball mills, a batch mill with a 30ml maximum working volume, and a flow-through mill with a 250ml maximum working volume. Milling parameters were investigated in detail by methodologies of QbD to map the parametric space. Specifically, the effects of ball size, ball fill level, and rpm on the particle breakage kinetics were systematically investigated at both mills, with an additional parameter (flow-rate) in the case of the flow-through mill. The breakage rate was found to follow power-law kinetics with respect to dimensionless time, with an asymptotic d50 particle size in the range of 200-300nm. In the case of the flow-through mill, the number of theoretical passes through the mill was found to be an important scale-up parameter.

  7. 75 FR 31418 - Intermountain Region, Payette National Forest, Council Ranger District; Idaho; Mill Creek-Council...

    Science.gov (United States)

    2010-06-03

    ... Forest Service Intermountain Region, Payette National Forest, Council Ranger District; Idaho; Mill Creek... Forest will prepare an environmental impact statement (EIS) for the Mill Creek--Council Mountain... Council, Idaho. The Mill Creek--Council Mountain Landscape Restoration Project proposes to...

  8. 21 CFR 515.11 - Supplemental medicated feed mill license applications.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Supplemental medicated feed mill license... SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS MEDICATED FEED MILL LICENSE Applications § 515.11 Supplemental medicated feed mill license applications. (a) After approval of a medicated...

  9. 77 FR 5767 - Certain Tin Mill Products From Japan: Rescission of Antidumping Duty Administrative Review

    Science.gov (United States)

    2012-02-06

    ... International Trade Administration Certain Tin Mill Products From Japan: Rescission of Antidumping Duty...) initiated an administrative review of the antidumping duty order covering certain tin mill products from... antidumping duty order on certain tin mill products from Japan. See Antidumping or Countervailing Duty...

  10. 21 CFR 515.20 - Approval of medicated feed mill license applications.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Approval of medicated feed mill license... SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS MEDICATED FEED MILL LICENSE Administrative Actions on Licenses § 515.20 Approval of medicated feed mill license applications. Within 90 days after...

  11. 21 CFR 558.4 - Requirement of a medicated feed mill license.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Requirement of a medicated feed mill license. 558... Provisions § 558.4 Requirement of a medicated feed mill license. (a) A feed manufacturing facility must possess a medicated feed mill license in order to manufacture a Type B or Type C medicated feed from...

  12. 33 CFR 117.213 - New Haven Harbor, Quinnipiac and Mill Rivers.

    Science.gov (United States)

    2010-07-01

    ... Mill Rivers. 117.213 Section 117.213 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF... Haven Harbor, Quinnipiac and Mill Rivers. The draws of the Tomlinson bridge, mile 0.0, the Ferry Street... bridge, mile 0.4 across Mill River, shall operate as follows: (a) The draws shall open on signal;...

  13. 75 FR 8346 - Proposed CERCLA Administrative Settlement; Anderson-Calhoun Mine and Mill Site, Leadpoint, WA

    Science.gov (United States)

    2010-02-24

    ... AGENCY Proposed CERCLA Administrative Settlement; Anderson-Calhoun Mine and Mill Site, Leadpoint, WA... settlement for costs associated with a removal action at the Anderson-Calhoun Mine and Mill Site in Leadpoint.... Comments should reference the Anderson-Calhoun Mine and Mill Site in Leadpoint, Washington, EPA Docket...

  14. 77 FR 75917 - Drawbridge Operation Regulation; New Haven Harbor, Quinnipiac and Mill Rivers, CT

    Science.gov (United States)

    2012-12-26

    ..., Quinnipiac and Mill Rivers, CT AGENCY: Coast Guard, DHS. ACTION: Notice of proposed rulemaking; Reopening... Chapel Street Bridge, mile 0.4, across the Mill River, at New Haven, Connecticut. This notice of proposed... Street Bridge, mile 0.4, across the Mill River, to reduce the burden of crewing these bridges during...

  15. 77 FR 4559 - Ecusta Mill Site, Pisgah Forest, Transylvania County, NC; Notice of Amended Settlement

    Science.gov (United States)

    2012-01-30

    ... AGENCY Ecusta Mill Site, Pisgah Forest, Transylvania County, NC; Notice of Amended Settlement AGENCY... Ecusta Mill Superfund Site located in Pisgah Forest, Transylvania County, North Carolina. DATES: The... by Site name Ecusta Mill Superfund Site by one of the following methods:...

  16. 40 CFR 180.521 - Fumigants for grain-mill machinery; tolerances for residues.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Fumigants for grain-mill machinery... Tolerances § 180.521 Fumigants for grain-mill machinery; tolerances for residues. (a) General. Fumigants may be safely used in or on grain-mill machinery in accordance with the following prescribed...

  17. 75 FR 3195 - Ochoco National Forest, Lookout Mountain Ranger District; Oregon; Mill Creek; Allotment...

    Science.gov (United States)

    2010-01-20

    ... Forest Service Ochoco National Forest, Lookout Mountain Ranger District; Oregon; Mill Creek; Allotment... Mountain Ranger District. These four allotments are: Cox, Craig, Mill Creek, and Old Dry Creek. The... responsible official will decide whether and how to reissue grazing permits in the Cox, Craig, Mill Creek...

  18. 21 CFR 515.24 - Notice of revocation of a medicated feed mill license.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Notice of revocation of a medicated feed mill... SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS MEDICATED FEED MILL LICENSE Administrative Actions on Licenses § 515.24 Notice of revocation of a medicated feed mill license. When a...

  19. 77 FR 34938 - Certain Tin Mill Products From Japan: Continuation of Antidumping Duty Order

    Science.gov (United States)

    2012-06-12

    ... International Trade Administration Certain Tin Mill Products From Japan: Continuation of Antidumping Duty Order... Trade Commission (USITC) that revocation of the antidumping duty order on certain tin mill products from... Department published the antidumping duty order on certain tin mill products from Japan.\\1\\ On June 1,...

  20. 21 CFR 515.21 - Refusal to approve a medicated feed mill license application.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Refusal to approve a medicated feed mill license... SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS MEDICATED FEED MILL LICENSE Administrative Actions on Licenses § 515.21 Refusal to approve a medicated feed mill license application. (a)...