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Sample records for chemical mass balance

  1. Oxalate Mass Balance During Chemical Cleaning in Tank 5F

    Energy Technology Data Exchange (ETDEWEB)

    Poirier, M.; Fink, S.

    2011-07-08

    The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 5F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate.

  2. OXALATE MASS BALANCE DURING CHEMICAL CLEANING IN TANK 6F

    Energy Technology Data Exchange (ETDEWEB)

    Poirier, M.; Fink, S.

    2011-07-22

    The Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRR personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 6F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate. Some conclusions from this work are: (1) Approximately 65% of the oxalate added as oxalic acid was removed with the decanted liquid. (2) Approximately 1% of the oxalate (added to the tank as oxalic acid) formed precipitates with compounds such as nickel, manganese, sodium, and iron (II), and was dissolved with nitric acid. (3) As much as 30% of the oxalate may have decomposed forming carbon dioxide. The balance does not fully account for all the oxalate added. The offset represents the combined uncertainty in the analyses and sampling.

  3. Meta-analysis of mass balances examining chemical fate during wastewater treatment.

    Science.gov (United States)

    Heidler, Jochen; Halden, Rolf U

    2008-09-01

    Mass balances are an instructive means for investigating the fate of chemicals during wastewater treatment. In addition to the aqueous-phase removal efficiency (phi), they can inform on chemical partitioning, transformation, and persistence, as well as on the chemical loading to streams and soils receiving, respectively, treated effluent and digested sewage sludge (biosolids). Release rates computed on a per-capita basis can serve to extrapolate findings to a larger scale. This review examines over a dozen mass balances conducted for various organic wastewater contaminants, including prescription drugs, estrogens, fragrances, antimicrobials, and surfactants of differing sorption potential (hydrophobicity), here expressed as the 1-octanol-water partition coefficient (K(OW)) and the organic carbon normalized sorption coefficient (K(OC)). Major challengesto mass balances are the collection of representative samples and accurate quantification of chemicals in sludge. A meta-analysis of peer-reviewed data identified sorption potential as the principal determinant governing chemical persistence in biosolids. Occurrence data for organic wastewater compounds detected in digested sludge followed a simple nonlinear model that required only K(OW) or K(OC) as the input and yielded a correlation coefficient of 0.9 in both instances. The model predicted persistence in biosolids for the majority (> 50%) of the input load of organic wastewater compounds featuring a log10 K(OW) value of greater than 5.2 (log10 K(OC) > 4.4). In contrast, hydrophobicity had no or only limited value for estimating, respectively, phi and the overall persistence of a chemical during conventional wastewater treatment.

  4. SOURCE APPORTIONMENT OF PM 2.5 AND CARBON IN SEATTLE USING CHEMICAL MASS BALANCE AND POSITIVE MATRIX FACTORIZATION

    Science.gov (United States)

    Three years of PM2.5 speciated data were collected and chemically analyzed using the IMPROVE protocol at the Beacon Hill site in Seattle. The data were analyzed by the Chemical Mass Balance Version 8 (CMB8) and Positive Matrix Factorization (PMF) source apportionment models. T...

  5. [Pollutant source apportionment of combined sewer overflows using chemical mass balance method].

    Science.gov (United States)

    Dai, Mei-Hong; Li, Tian; Zhang, Wei

    2013-11-01

    Pollutant characteristics of surface runoff, sanitary sewage and sewer deposits from a combined sewer system in Shanghai were studied. It was confirmed that the content of Zn, NH4(+) -N, P, respectively in surface runoff, sanitary sewage and sewer deposits was specific and relatively stable based on contrasting pollutant characteristics of different sources. Three non-dimensional parameters-Zn/P, NH4(+) -N/Zn, P/K were proposed as characteristic index for surface runoff, sanitary sewage and sewer deposits. In order to find sources of pollutants in CSO, the application of chemical mass balance method was discussed: the average contributions to CSO were 42.8% for surface runoff, 12.2% for sanitary sewage, 23.8% for sewer deposits, and the results basically reflected the composition of CSO pollution. The research method and results can provide guidance for pollutant source apportionment of combined sewer overflows.

  6. Chemical mass balance source apportionment of PM 10 in an industrialized urban area of Northern Greece

    Science.gov (United States)

    Samara, C.; Kouimtzis, Th; Tsitouridou, R.; Kanias, G.; Simeonov, V.

    Ambient PM 10 were sampled at three sites in an industrialized urban area of Northern Greece during June 1997-June 1998 and analyzed for 17 chemical elements, 5 water-soluble ions and 13 polycyclic aromatic hydrocarbons. In addition, chemical source profiles consisting of the same particulate components were obtained for a number of industrial activities (cement, fertilizer and asphalt production, quarry operations, metal electroplating, metal welding and tempering, steel manufacture, lead and bronze smelters, metal scrap incineration), residential oil burning, non-catalyst and catalyst-equipped passenger cars, diesel fuelled taxis and buses, as well as for geological fugitive sources (paved road dust and soil from open lands). Ambient and source data were used in a chemical mass balance (CMB) receptor model for source identification and apportionment. Results of CMB modeling showed that major source of ambient PM 10 at all three sites was diesel vehicle exhaust. Significant contribution from industrial oil burning was also evidenced at the site located closest to the industrial area.

  7. Chemical mass balance source apportionment of fine and PM10 in the Desert Southwest, USA

    Directory of Open Access Journals (Sweden)

    Andrea L. Clements

    2016-03-01

    Full Text Available The Desert Southwest Coarse Particulate Matter Study was undertaken in Pinal County, Arizona, to better understand the origin and impact of sources of fine and coarse particulate matter (PM in rural, arid regions of the U.S. southwestern desert. The desert southwest experiences some of the highest PM10 mass concentrations in the country. To augment previously reported results, 6-week aggregated organic speciation data that included ambient concentrations of n-alkanes, polycyclic aromatic hydrocarbons, organic acids, and saccharides were used in chemical mass balance modeling (CMB. A set of re-suspended soil samples were analyzed for specific marker species to provide locally-appropriate source profiles for the CMB analysis. These profiles, as well as previously collected plant and fungal spore profiles from the region, were combined with published source profiles for other relevant sources and used in the CMB analysis. The six new region-specific source profiles included both organic and inorganic species for four crustal material sources, one plant detritus source, and one fungal spore source.Results indicate that up to half of the ambient PM2.5 was apportioned to motor vehicles with the highest regional contribution observed in the small urban center of Casa Grande. Daily levels of apportioned crustal material accounted for up to 50% of PM2.5 mass with the highest contributions observed at the sites closest to active agricultural areas. Apportioned secondary PM, biomass burning, and road dust typically contributed less than 35% as a group to the apportioned PM2.5 mass. Crustal material was the primary source apportioned to PM10 and accounted for between 50–90% of the apportioned mass. Of the other sources apportioned to PM10, motor vehicles and road dust were the largest contributors at the urban and one of the rural sites, whereas road dust and meat cooking operations were the largest contributors at the other rural site.

  8. Evaluation of organic markers for chemical mass balance source apportionment at the Fresno Supersite

    Directory of Open Access Journals (Sweden)

    J. C. Chow

    2007-01-01

    Full Text Available Sources of PM2.5 at the Fresno Supersite during high PM2.5 episodes occurring from 15 December 2000–3 February 2001 were estimated with the Chemical Mass Balance (CMB receptor model. The ability of source profiles with organic markers to distinguish motor vehicle, residential wood combustion (RWC, and cooking emissions was evaluated with simulated data. Organics improved the distinction between gasoline and diesel vehicle emissions and allowed a more precise estimate of the cooking source contribution. Sensitivity tests using average ambient concentrations showed that the gasoline vehicle contribution was not resolved without organics. Organics were not required to estimate hardwood contributions. The most important RWC marker was the water-soluble potassium ion. The estimated cooking contribution did not depend on cholesterol because its concentrations were below the detection limit in most samples. Winter time source contributions were estimated by applying the CMB model to individual and average sample concentrations. RWC was the largest source, contributing 29–31% of measured PM2.5. Hardwood and softwood combustion accounted for 16–17% and 12–15%, respectively. Secondary ammonium nitrate and motor vehicle emissions accounted for 31–33% and 9–15%, respectively. The gasoline vehicle contribution (3–10% was comparable to the diesel vehicle contribution (5–6%. The cooking contribution was 5–19% of PM2.5. Fresno source apportionment results were consistent with those estimated in previous studies.

  9. Effects of systematic error, estimates and uncertainties in chemical mass balance apportionments: Quail Roost II revisited

    Science.gov (United States)

    Lowenthal, Douglas H.; Hanumara, R. Choudary; Rahn, Kenneth A.; Currie, Lloyd A.

    The Quail Roost II synthetic data set II was used to derive a comprehensive method of estimating uncertainties for chemical mass balance (CMB) apportionments. Collinearity-diagnostic procedures were applied to CMB apportionments of data set II to identify seriously collinear source profiles and evaluate the effects of the degree of collinearity on source-strength estimates and their uncertainties. Fractional uncertainties of CMB estimates were up to three times higher for collinear source profiles than for independent ones. A theoretical analysis of CMB results for synthetic data set II led to the following general conclusions about CMB methodology. Uncertainties for average estimated source strengths will be unrealistically low unless sources whose estimates are constrained to zero are included when calculating uncertainties. Covariance in source-strength estimates is caused by collinearity and systematic errors in source specification and composition. Propagated uncertainties may be underestimated unless covariances as well as variances of estimates are included. Apportioning the average aerosol will account for systematic errors only when the correct model is known, when measurement uncertainties in ambient and source-profile data are realistic, and when the source profiles are not collinear.

  10. On the Mathematical Structure of Balanced Chemical Reaction Networks Governed by Mass Action Kinetics

    CERN Document Server

    van der Schaft, Arjan; Jayawardhana, Bayu

    2011-01-01

    Motivated by recent progress on the interplay between graph theory, dynamics, and systems theory, we revisit the analysis of chemical reaction networks described by mass action kinetics. For reaction networks possessing a thermodynamic equilibrium we derive a compact formulation exhibiting at the same time the structure of the complex graph and the stoichiometry of the network, and which admits a direct thermodynamical interpretation. This formulation allows us to easily characterize the set of equilibria and their stability properties. Furthermore, we develop a framework for interconnection of chemical reaction networks. Finally we discuss how the established framework leads to a new approach for model reduction.

  11. Assessing the regional impact of Indonesian biomass burning emissions based on organic molecular tracers and chemical mass balance modeling

    Directory of Open Access Journals (Sweden)

    G. Engling

    2014-01-01

    Full Text Available Biomass burning activities commonly occur in Southeast Asia (SEA, and are particularly intense in Indonesia during dry seasons. The effect of biomass smoke emissions on air quality in the city state of Singapore was investigated during a haze episode in October 2006. Substantially increased levels of airborne particulate matter (PM and associated chemical species were observed during the haze period. Specifically, the enhancement in the concentration of molecular tracers for biomass combustion such as levoglucosan by as much as two orders of magnitude and diagnostic ratios of individual organic compounds indicated that biomass burning emissions caused a regional smoke haze episode due to their long-range transport by prevailing winds. With the aid of air mass back trajectories and chemical mass balance modeling, large-scale forest and peat fires in Sumatra and Kalimantan were identified as the sources of the smoke aerosol, exerting a significant impact on air quality in downwind areas, such as Singapore.

  12. Assessing the regional impact of indonesian biomass burning emissions based on organic molecular tracers and chemical mass balance modeling

    Science.gov (United States)

    Engling, G.; He, J.; Betha, R.; Balasubramanian, R.

    2014-08-01

    Biomass burning activities commonly occur in Southeast Asia (SEA), and are particularly intense in Indonesia during the dry seasons. The effect of biomass smoke emissions on air quality in the city state of Singapore was investigated during a haze episode in October 2006. Substantially increased levels of airborne particulate matter (PM) and associated chemical species were observed during the haze period. Specifically, the enhancement in the concentration of molecular tracers for biomass combustion such as levoglucosan by as much as two orders of magnitude and the diagnostic ratios of individual organic compounds indicated that biomass burning emissions caused a regional smoke haze episode due to their long-range transport by prevailing winds. With the aid of air mass backward trajectories and chemical mass balance modeling, large-scale forest and peat fires in Sumatra and Kalimantan were identified as the sources of the smoke aerosol, exerting a significant impact on air quality in downwind areas, such as Singapore.

  13. Evaluation of optimization methods for solving the receptor model for chemical mass balance

    Directory of Open Access Journals (Sweden)

    Anu N.

    2015-01-01

    Full Text Available Balance (CMB model has been extensively used in order to determine source contribution for particulate matters (size diameters less than 10 μm and 2.5 μm in the air quality analysis. A comparison of the source contribution estimated from the three CMB models (CMB 8.2, CMB-fmincon and CMB-GA have been carried out through optimization techniques such as ‘fmincon’ (CMB-fmincon and genetic algorithm (CMB-GA using MATLAB. The proposed approach has been validated using San Joaquin Valley Air Quality Study (SJVAQS California Fresno and Bakersfield PM10 and PM2.5 followed with Oregon PM10 data. The source contribution estimated from CMB-GA was better in source interpretation in comparison with CMB8.2 and CMB-fmincon. The performance accuracy of three CMB approaches were validated using R-square, reduced chi-square and percentage mass tests. The R-square (0.90, 0.67 and 0.81, 0.83, Chi-square (0.36, 0.66 and 0.65, 0.43 and percentage mass (67.36 %, 55.03 % and 94.24 %, 74.85 % of CMB-GA showed high correlation for PM10, PM2.5 Fresno and Bakersfield data respectively. To make a complete decision, the proposed methodology has been bench marked with Portland, Oregon PM10 data with best fit with R2 (0.99, Chi-square (1.6 and percentage mass (94.4 % from CMB-GA. Therefore, the study revealed that CMB with genetic algorithm optimization method holds better stability in determining the source contributions.

  14. Nitrogen losses from dairy manure estimated through nitrogen mass balance and chemical markers

    Science.gov (United States)

    Hristov, Alexander N.; Zaman, S.; Vander Pol, M.; Ndegwa, P.; Campbell, L.; Silva, S.

    2009-01-01

    Ammonia is an important air and water pollutant, but the spatial variation in its concentrations presents technical difficulties in accurate determination of ammonia emissions from animal feeding operations. The objectives of this study were to investigate the relationship between ammonia volatilization and ??15N of dairy manure and the feasibility of estimating ammonia losses from a dairy facility using chemical markers. In Exp. 1, the N/P ratio in manure decreased by 30% in 14 d as cumulative ammonia losses increased exponentially. Delta 15N of manure increased throughout the course of the experiment and ??15N of emitted ammonia increased (p Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  15. Chemical mass balance estimation of arsenic in atmospheric dust fall out in an urban residential area, Raipur, Central India

    Directory of Open Access Journals (Sweden)

    G. Balakrishna

    2010-11-01

    Full Text Available The components and quantities of atmospheric dust fallout have been reported to be the pollution indicator of large urban areas. The multiplicity and complexity of sources of atmospheric dusts in urban regions has put forward the need of source apportionment of these sources indicating their contribution to specific environmental receptor. The study presented here is focused on investigation of source contribution estimates of Arsenic in urban dust fallout in an urban-industrial area, Raipur, India. Source-receptor based representative sampling plan using longitudinal study design has been adopted. Six sampling sites have been identified on the basis of land use for development plan of anthropogenic activities and factors related to the transportation and dispersion pattern of atmospheric dusts. Source apportionment has been done using Chemical Mass Balance (CMB 8. Good fit parameters and relative source contribution has been analyzed and documented. Dominance of coal fired industries sources on arsenic levels measured at selected ambient residential receptors compared to line sources has been observed. Road-traffic has shown highest contribution of dust at indoor houses and out door-street automobile exhaust has shows highest contribution for arsenic. The results of CMB output and regression data of source-receptor dust matrices have shown comparable pattern.

  16. MAM-An Aquivalence-based Dynamic Mass Balance Model for the Fate of Non-Volatile Organic Chemicals in the Agricultural Environment

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    Mohammad A. Batiha

    2008-01-01

    Full Text Available A Multimedia Agricultural Model (MAM for predicting the fate and transport of Non-Volatile Organic Chemicals (NVOCs in the agricultural environment was presented. It is an expanded and modified version of the three compartmental model introduced by Batiha and co-authors in 2007, which is an aquivalence-based level IV. MAM considered five environmental compartments to include the air, water, soil, sediment and vegetation. It calculates the complete steady-state mass budgets for the air, water and particulate organic carbon between the model compartments. MAM compartments were connected by advective and intermedia transport processes. Degradation can take place in every compartment. The mass balances for each of the compartments result in a system of five differential equations, solved numerically to yield estimates of concentrations, masses, transport fluxes and reaction rates as a function of time. All the equations required for MAM calculations were provided.

  17. Catchment-scale denudation and chemical erosion rates determined from 10Be and mass balance geochemistry (Mt. Lofty Ranges of South Australia)

    Science.gov (United States)

    Bestland, Erick A.; Liccioli, Caterina; Soloninka, Lesja; Chittleborough, David J.; Fink, David

    2016-10-01

    Global biogeochemical cycles have, as a central component, estimates of physical and chemical erosion rates. These erosion rates are becoming better quantified by the development of a global database of cosmogenic radionuclide 10Be (CRN) analyses of soil, sediment, and outcrops. Here we report the denudation rates for two small catchments (~ 0.9 km2) in the Mt. Lofty Ranges of South Australia as determined from 10Be concentrations from quartz sand from the following landscape elements: 1) dissected plateaux, or summit surfaces (14.10 ± 1.61 t km- 2 y- 1), 2) sandstone outcrops (15.37 ± 1.32 t km- 2 y- 1), 3) zero-order drainages (27.70 ± 1.42 t km- 2 y- 1), and 4) stream sediment which reflect a mix of landscape elements (19.80 ± 1.01 t km- 2 y- 1). Thus, the more slowly eroding plateaux and ridges, when juxtaposed with the more rapidly eroding side-slopes, are leading to increased relief in this landscape. Chemical erosion rates for this landscape are determined by combining cosmogenic denudation rates with the geochemical mass balance of parent rock, soil and saprolite utilizing zirconium immobility and existing mass balance methods. Two different methods were used to correct for chemical weathering and erosion in the saprolite zone that is shielded at depth from CRN production. The corrected values are higher than uncorrected values: total denudation of 33.24 or 29.11 t km- 2 y- 1, and total chemical erosion of 15.64 or 13.68 t km- 2 y- 1. Thus, according to these methods, 32-40% of the denudation is taking place by chemical weathering and erosion in the saprolite below CRN production depth. Compared with other similar areas, the overall denudation and chemical erosion rates are low. In most areas with sub-humid climates and tectonic uplift, physical erosion is much greater than chemical erosion. The low physical erosion rates in these Mt. Lofty Range catchments, in what is a relatively active tectonic setting, are thought to be due to low rainfall intensity

  18. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    Energy Technology Data Exchange (ETDEWEB)

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  19. Source apportionment for sediment PAHs using hybrid genetic pattern search treatment of a chemical mass balance receptor model: application to the Pearl River Delta region, China.

    Science.gov (United States)

    Wu, Jin; Teng, Yanguo; Chen, Haiyang

    2014-10-01

    In order to solve the collinear problem and improve the estimation accuracy of the chemical mass balance (CMB) model which can be essentially regarded as a constrained optimization process, in this study, a hybrid genetic pattern search algorithm (HGPS) was proposed and applied to apportion the source contributions for sediment polycyclic aromatic hydrocarbons (PAHs) in the Pearl River Delta (PRD) region, China. Simulation results with developed synthetic datasets indicated that the estimated source contributions by HGPS were more close to the true values than CMB8.2. Utilizing the HGPS-CMB, residential coal and traffic tunnel were apportioned as the major sources of sediment PAHs in the PRD region. For freshwater surface sediments, the average contribution from residential coal ranged from 32 to 55%, and traffic tunnel ranged from 13 to 33%, while the major sources for marine sediments were traffic tunnel (10 ~ 56%). These results provide information for developing better PAH pollution control strategies for the PRD.

  20. Chemical mass balance of refractory particles (T=300 °C) at the tropospheric research site Melpitz, Germany

    Science.gov (United States)

    Poulain, L.; Birmili, W.; Canonaco, F.; Crippa, M.; Wu, Z. J.; Nordmann, S.; Spindler, G.; Prévôt, A. S. H.; Wiedensohler, A.; Herrmann, H.

    2013-10-01

    In the fine particle mode (aerodynamic diameter MAAP), and an aerosol mass spectrometer (AMS). The data were collected during two atmospheric field experiments in May/June 2008 as well as February/March 2009. As a basic result, we detected average refractory particle volume fractions of 11±3% (2008) and 17±8% (2009). In both periods, BC was in close linear correlation with the refractory fraction, but not sufficient to quantitatively explain the refractory particle mass concentration. Based on the assumption that BC is not altered by the heating process, the refractory particle mass fraction could be explained by the sum of black carbon BC (47% in summer, 59% in winter) and a refractory organic contribution estimated as part of the Low-Volatility Oxygenated Organic Aerosol (LV-OOA) (53% in summer, 41% in winter); the latter was identified from AMS data by factor analysis. Our results suggest that organics were more volatile in summer (May-June 2008) than in winter (February/March 2009). Although carbonaceous compounds dominated the sub-μm refractory particle mass fraction most of the time, a cross-sensitivity to partially volatile aerosol particles of maritime origin could be seen. These marine particles could be distinguished, however, from the carbonaceous particles by a characteristic particle volume size distribution. The paper discusses the uncertainty of the volatility measurements and outlines the possible merits of volatility analysis as part of continuous atmospheric aerosol measurements.

  1. 14 CFR 23.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 23.659 Section 23.659 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS... Surfaces § 23.659 Mass balance. The supporting structure and the attachment of concentrated mass...

  2. 14 CFR 29.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 29.659 Section 29.659... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Design and Construction Rotors § 29.659 Mass balance. (a) The rotor... flutter at any speed up to the maximum forward speed. (b) The structural integrity of the mass...

  3. 14 CFR 27.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 27.659 Section 27.659... STANDARDS: NORMAL CATEGORY ROTORCRAFT Design and Construction Rotors § 27.659 Mass balance. (a) The rotors... flutter at any speed up to the maximum forward speed. (b) The structural integrity of the mass...

  4. Chemical mass balance of refractory particles (T=300 °C at the tropospheric research site Melpitz, Germany

    Directory of Open Access Journals (Sweden)

    L. Poulain

    2013-10-01

    Full Text Available In the fine particle mode (aerodynamic diameter <1 μm refractory material has been associated with black carbon (BC and low-volatile organics and, to a lesser extent, with sea salt and mineral dust. This work analyses refractory particles at the tropospheric research station Melpitz (Germany, combining experimental methods such as a mobility particle size spectrometer (3–800 nm, a thermodenuder operating at 300 °C, a multi-angle absorption photometer (MAAP, and an aerosol mass spectrometer (AMS. The data were collected during two atmospheric field experiments in May/June 2008 as well as February/March 2009. As a basic result, we detected average refractory particle volume fractions of 11±3% (2008 and 17±8% (2009. In both periods, BC was in close linear correlation with the refractory fraction, but not sufficient to quantitatively explain the refractory particle mass concentration. Based on the assumption that BC is not altered by the heating process, the refractory particle mass fraction could be explained by the sum of black carbon BC (47% in summer, 59% in winter and a refractory organic contribution estimated as part of the Low-Volatility Oxygenated Organic Aerosol (LV-OOA (53% in summer, 41% in winter; the latter was identified from AMS data by factor analysis. Our results suggest that organics were more volatile in summer (May–June 2008 than in winter (February/March 2009. Although carbonaceous compounds dominated the sub-μm refractory particle mass fraction most of the time, a cross-sensitivity to partially volatile aerosol particles of maritime origin could be seen. These marine particles could be distinguished, however, from the carbonaceous particles by a characteristic particle volume size distribution. The paper discusses the uncertainty of the volatility measurements and outlines the possible merits of volatility analysis as part of continuous atmospheric aerosol measurements.

  5. Chemical mass balance of 300 °C non-volatile particles at the tropospheric research site Melpitz, Germany

    Science.gov (United States)

    Poulain, L.; Birmili, W.; Canonaco, F.; Crippa, M.; Wu, Z. J.; Nordmann, S.; Spindler, G.; Prévôt, A. S. H.; Wiedensohler, A.; Herrmann, H.

    2014-09-01

    In the fine-particle mode (aerodynamic diameter MAAP), and an aerosol mass spectrometer (AMS). The data were collected during two atmospheric field experiments in May-June 2008 as well as February-March 2009. As a basic result, we detected average non-volatile particle-volume fractions of 11 ± 3% (2008) and 17 ± 8% (2009). In both periods, BC was in close linear correlation with the non-volatile fraction, but not sufficient to quantitatively explain the non-volatile particle mass concentration. Based on the assumption that BC is not altered by the heating process, the non-volatile particle mass fraction could be explained by the sum of black carbon (47% in summer, 59% in winter) and a non-volatile organic contribution estimated as part of the low-volatility oxygenated organic aerosol (LV-OOA) (53% in summer, 41% in winter); the latter was identified from AMS data by factor analysis. Our results suggest that LV-OOA was more volatile in summer (May-June 2008) than in winter (February-March 2009) which was linked to a difference in oxidation levels (lower in summer). Although carbonaceous compounds dominated the sub-μm non-volatile particle mass fraction most of the time, a cross-sensitivity to partially volatile aerosol particles of maritime origin could be seen. These marine particles could be distinguished, however from the carbonaceous particles by a characteristic particle volume-size distribution. The paper discusses the uncertainty of the volatility measurements and outlines the possible merits of volatility analysis as part of continuous atmospheric aerosol measurements.

  6. Source apportionment for sediment PAHs from the Daliao River (China) using an extended fit measurement mode of chemical mass balance model.

    Science.gov (United States)

    Chen, Hai-Yang; Teng, Yan-Guo; Wang, Jin-Sheng

    2013-02-01

    To minimize the selection uncertainties of source profiles and obtain the higher model performance, an extended fit measurement mode for chemical mass balance model (EFMM-CMB) was proposed and applied to estimate source contributions for sediment PAHs from the Daliao River around which is the important industrial bases with oil, chemical and steel factories in the northeast part of China. Based on least squares fitting method, EFMM-CMB initially calculated the fit measurement index to every one of the possible combinations that can be made from the source profiles. Any successful applications of the fitting method were ranked according to performance measures, and then determined by maximizing an overall fitting index for a unique solution. Apportionment results from two case scenarios showed that the values of performance measures for EFMM-CMB were better to that for CMB8.2 results. With species selection of high molecular weight PAHs, power plant (45.75%), biomass burning (29.34%) and traffic tunnel (10.59%) were identified as the major sources of sediment PAHs from the Daliao River region.

  7. Source Apportionment of Ambient PM10 in the Urban Area of Longyan City, China: a Comparative Study Based on Chemical Mass Balance Model and Factor Analysis Method

    Institute of Scientific and Technical Information of China (English)

    QIU Li-min; LIU Miao; WANG Ju; ZHANG Sheng-nan; FANG Chun-sheng

    2012-01-01

    In order to identify the day and night pollution sources of PM10 in ambient air in Longyan City,the authors analyzed the elemental composition of respirable particulate matters in the day and night ambient air samples and various pollution sources which were collected in January 2010 in Longyan with inductivity coupled plasma-mass spectrometry(ICP-MS).Then chemical mass balance(CMB)model and factor analysis(FA)method were applied to comparatively study the inorganic components in the sources and receptor samples.The results of factor analysis show that the major sources were road dust,waste incineration and mixed sources which contained automobile exhaust,soil dust/secondary dust and coal dust during the daytime in Longyan City,China.There are two major sources of pollution which are soil dust and mixture sources of automobile exhaust and secondary dust during the night in Longyan.The results of CMB show that the major sources are secondary dust,automobile exhaust and road dust during the daytime in Longyan.The major sources are secondary dust,soil dust and automobile exhaust during the night in Longyan.The results of the two methods are similar to each other and the results will guide us to plan to control the PM10 pollution sources in Longyan.

  8. TSP, PM depositions, and trace elements in the vicinity of a cement plant and their source apportionments using chemical mass balance model in Izmir, Turkey.

    Science.gov (United States)

    Yatkin, Sinan; Bayram, Abdurrahman

    2010-08-01

    Total suspended particles mass concentrations (TSP) and bulk depositions of particulate matter (PM depositions) were measured around a cement plant located in the multi-impacted area to assess the affect of the plant on the ambient air in the vicinity in Izmir, Turkey. TSP samples were collected five times a month whereas PM depositions were sampled monthly at four sites between August 2003 and January 2004. The concentrations of Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V, and Zn in TSP and PM depositions (except Cu) were reported. Chemical mass balance (CMB) receptor model with local source profiles was run in order to calculate the source contributions of the PM sources to the concentrations of TSP, PM depositions, and trace elements. Traffic was found to be the major contributor to TSP whereas PM depositions dominantly result from area sources including several stone quarries, concrete plants, lime kilns, and asphalt plants in the region. CMB model results indicate that the cement plant is a significant contributor to TSP, PM depositions, and trace elements, particularly Cd.

  9. Hydrogeochemical cycling and chemical denudation in the Fort River Watershed, central Massachusetts: An appraisal of mass-balance studies

    Science.gov (United States)

    Yuretich, Richard F.; Batchelder, Gail L.

    1988-01-01

    The Fort River watershed in central Massachusetts receives precipitation with a composition similar to that in Hubbard Brook (New Hampshire), yet the average stream water chemistry is substantially different, showing higher pH and TDS. This is largely a function of bedrock and surficial geology, and chemical differences among small streams within the Fort River watershed are apparently controlled by the composition and thickness of the prevailing surficial cover. The surficial deposits determine groundwater and surface water flow paths, thereby affecting the resultant contact time with mineral matter and the chemistry of the runoff. Despite the rural setting, over 95% of the annual sodium and chloride in the streams comes from road salt; after correcting for this factor, cation denudation rates are about equal to those at Hubbard Brook. However, silica removal is occurring at a rate more than 30% greater in the Fort River. When climatic conditions in Hubbard Brook and Fort River are normalized, weathering rates appear consistently higher in the Fort River, reflecting differences in weathering processes (i.e., cation exchange and silicate breakdown) and hydrogeology. Because of uncertainties in mechanisms of cation removal from watersheds, the silica denudation rate may be a better index of weathering intensity.

  10. On the Mass Balance of Asphaltene Precipitation

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar; Lira-Galeana, C.; Stenby, Erling Halfdan

    2001-01-01

    In the evaluation of experimental data as well as in calculation of phase equilibria the necessity of the application of mass balances is obvious. In the case of asphaltenes the colloidal nature of these compounds may highly affect the mass balance. In the present paper several experiments are pe...

  11. Chemical Ionization Mass Spectrometry.

    Science.gov (United States)

    1980-01-30

    mass spectrometer. Also discussed were Corporation, St. Louis , Mo. unique analytical applications of several negative ion chemical Synthesis of the...were purchsed from obtained at a probe temperature of 180-200 °C and displays Sigma Chemical Co.. St. Louis , Mo. Arginine hydrochloride (4) a M4...13) Rosenstock. H, M.: Drax . K.: Stener. B. W: Hernon J. T. J. Phys. Chem, Ref. Data 1977, 6, Supl. 1. 774-783,167 occur in the ratio of 10/ 1

  12. Miniature Piezoelectric Macro-Mass Balance

    Science.gov (United States)

    Sherrit, Stewart; Trebi-Ollennu, Ashitey; Bonitz, Robert G.; Bar-Cohen, Yoseph

    2010-01-01

    Mass balances usually use a strain gauge that requires an impedance measurement and is susceptible to noise and thermal drift. A piezoelectric balance can be used to measure mass directly by monitoring the voltage developed across the piezoelectric balance, which is linear with weight or it can be used in resonance to produce a frequency change proportional to the mass change (see figure). The piezoelectric actuator/balance is swept in frequency through its fundamental resonance. If a small mass is added to the balance, the resonance frequency shifts down in proportion to the mass. By monitoring the frequency shift, the mass can be determined. This design allows for two independent measurements of mass. Additionally, more than one sample can be verified because this invention allows for each sample to be transported away from the measuring device upon completion of the measurement, if required. A piezoelectric actuator, or many piezoelectric actuators, was placed between the collection plate of the sampling system and the support structure. As the sample mass is added to the plate, the piezoelectrics are stressed, causing them to produce a voltage that is proportional to the mass and acceleration. In addition, a change in mass delta m produces a change in the resonance frequency with delta f proportional to delta m. In a microgravity environment, the spacecraft could be accelerated to produce a force on the piezoelectric actuator that would produce a voltage proportional to the mass and acceleration. Alternatively, the acceleration could be used to force the mass on the plate, and the inertial effects of the mass on the plate would produce a shift in the resonance frequency with the change in frequency related to the mass change. Three prototypes of the mass balance mechanism were developed. These macro-mass balances each consist of a solid base and an APA 60 Cedrat flextensional piezoelectric actuator supporting a measuring plate. A similar structure with 3 APA

  13. Reanalysing glacier mass balance measurement series

    Directory of Open Access Journals (Sweden)

    M. Zemp

    2013-08-01

    Full Text Available Glacier-wide mass balance has been measured for more than sixty years and is widely used as an indicator of climate change and to assess the glacier contribution to runoff and sea level rise. Until recently, comprehensive uncertainty assessments have rarely been carried out and mass balance data have often been applied using rough error estimation or without consideration of errors. In this study, we propose a framework for reanalysing glacier mass balance series that includes conceptual and statistical toolsets for assessment of random and systematic errors, as well as for validation and calibration (if necessary of the glaciological with the geodetic balance results. We demonstrate the usefulness and limitations of the proposed scheme, drawing on an analysis that comprises over 50 recording periods for a dozen glaciers, and we make recommendations to investigators and users of glacier mass balance data. Reanalysing glacier mass balance series needs to become a standard procedure for every monitoring programme to improve data quality, including reliable uncertainty estimates.

  14. Mass Transfer with Chemical Reaction.

    Science.gov (United States)

    DeCoursey, W. J.

    1987-01-01

    Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)

  15. Chemical mass balance (CMB) source apportionment and organic speciation of PM(2.5) in Missoula, Montana including the 2000 wildfire season

    Science.gov (United States)

    Ward, Tony J.

    A yearlong sampling program for PM2.5, Semi- Volatile Organic Compounds (SVOCs), and Volatile Organic Compounds (VOCs) was conducted in 2000/2001. The data were used in a Chemical Mass Balance (CMB) Source Apportionment Model (Version 8.0) to apportion the sources of PM2.5 in the Missoula Valley. Results showed that wood combustion contributed an average of 41% to the fine fraction throughout the year. The second largest source of PM 2.5 was diesel (19%), followed by ammonium nitrate (17%), the kraft recovery boilers from Smurfit-Stone Container (14%), other hog fuel boilers (6%), and street sand (5%). Results also showed that PM2.5 levels and contributions from sources were consistent on both sides of the Missoula Valley, but VOCs were twice as high in Missoula compared to Frenchtown. Another aspect of this program was to investigate the organic fraction of the Missoula Valley PM2.5 by evaluating a modified Federal Reference Method (FRM) PM2.5 sampler. A method comparison was also made between sampling for SVOCs using the modified PM2.5 sampler and in using a Hi-volume Polyurethane Foam (PUF) sampler. Results showed that the PM 2.5 PUF measured more of the lighter SVOCs compared to the Hi-vol PUF sampler. This is most likely the result of the higher flows through the Hi-vol PUF which ``strip'' the lighter organics from the surface of the filter. The wildland fires of summer 2000 comprised one of the most severe fire seasons is U.S. history, and had a direct impact on the city of Missoula. Sampling in Missoula was already in progress when the fires began and smoke started rolling into the Missoula Valley. Samples were collected before, during, and after the 2000 fire season, and a detailed characterization of particulate and gaseous emissions from extensive wildland fires was obtained. The 2000/2001 CMB Sampling Program data collected during the 2000 fire season suggest that the main health impacts to downwind populations reside in the fine particulate exposures

  16. Composting: Mass Balances and Product Quality

    DEFF Research Database (Denmark)

    Boldrin, Alessio; Christensen, Thomas Højlund; Körner, I.

    2011-01-01

    While the basic processes involved in composting of waste are described in Chapter 9.1 and the main composting technologies are presented in Chapter 9.2, this chapter focuses on mass balances, environmental emissions, unit process inventories and the quality of the compost produced. Understanding...

  17. Greenland ice sheet mass balance: a review

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Aschwanden, Andy; Bjørk, Anders A.

    2015-01-01

    Over the past quarter of a century the Arctic has warmed more than any other region on Earth, causing a profound impact on the Greenland ice sheet (GrIS) and its contribution to the rise in global sea level. The loss of ice can be partitioned into processes related to surface mass balance...... and to ice discharge, which are forced by internal or external (atmospheric/oceanic/basal) fluctuations. Regardless of the measurement method, observations over the last two decades show an increase in ice loss rate, associated with speeding up of glaciers and enhanced melting. However, both ice discharge...... and melt-induced mass losses exhibit rapid short-term fluctuations that, when extrapolated into the future, could yield erroneous long-term trends. In this paper we review the GrIS mass loss over more than a century by combining satellite altimetry, airborne altimetry, interferometry, aerial photographs...

  18. Dynamics and mass balance of Taylor Glacier, Antarctica: 3. State of mass balance

    Science.gov (United States)

    Kavanaugh, J. L.; Cuffey, K. M.; Morse, D. L.; Bliss, A. K.; Aciego, S. M.

    2009-11-01

    Taylor Glacier flows from the East Antarctic Ice Sheet and terminates in the McMurdo Dry Valleys, where it has left a geomorphologic record of past incursions. Here we use new data on the flow, thickness, and surface balance of Taylor Glacier to calculate ice fluxes and assess the current state of mass balance. Overall, the glacier is close to a state of zero net balance, and has largely adjusted to reduced snowfall on the Taylor Dome source region in the mid Holocene. One region of the upper ablation zone appears to be losing mass. Evidence from ice surface morphology and stable isotope profiles suggests that this mass loss is a long-term phenomenon, hence probably a lingering response to the earlier drying of Taylor Dome. Our data give a general indication of the size of ablation or accumulation changes needed for ice to advance far into Taylor Valley, as occurred 70 to 130 ka ago.

  19. Mass-sensitive chemical preconcentrator

    Science.gov (United States)

    Manginell, Ronald P.; Adkins, Douglas R.; Lewis, Patrick R.

    2007-01-30

    A microfabricated mass-sensitive chemical preconcentrator actively measures the mass of a sample on an acoustic microbalance during the collection process. The microbalance comprises a chemically sensitive interface for collecting the sample thereon and an acoustic-based physical transducer that provides an electrical output that is proportional to the mass of the collected sample. The acoustic microbalance preferably comprises a pivot plate resonator. A resistive heating element can be disposed on the chemically sensitive interface to rapidly heat and release the collected sample for further analysis. Therefore, the mass-sensitive chemical preconcentrator can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  20. Capillary Action may Cool Systems and Precisely balance Chemical Reactions

    Science.gov (United States)

    Kriske, Richard

    2011-10-01

    It is well known that it takes no work for Water to rise in a Capillary tube against the force of Gravity. There is a precise balance in this system that resembles Robert Millikan's ``Oil Drop'' experiment, where mass was balanced against the electrostatic force. If at the top of the capillary tube there is evaporation, one can see that the system is cooled as another water molecule has room to move up the column. Furthermore, if the evaporation process can be controlled one photon at a time, a precise balance is created between a photon, and the height/mass of the column. If other molecules are place in the column, they can be moved up and down the column, in a chromatograph way, in a fairly precise manner, by controlling evaporation and molecular weight. If in addition to all of this, the interface of the solution against the walls of the column have Fermi levels, it can be seen as a very precise Electrochemical Device. In the situation of nanotubes, as opposed to trees and plants, these properties can be used to create measure environmental properties and to Balance Chemical Reactions. Forests, and Plants may cool themselves and their environment using this process, and using this process coupled with more energetic photons through photosynthesis.

  1. Quantifying mass balance processes on the Southern Patagonia Icefield

    DEFF Research Database (Denmark)

    Schaefer, M.; Machguth, Horst; Falvey, M.;

    2015-01-01

    measured accumulation of snow of up to 15.4m w.e. yr(-1) (meters water equivalent per year) as well as the high measured ablation of up to 11m w.e. yr(-1) is reproduced by the model. The overall modeled surface mass balance was positive and increasing during 1975-2011. Subtracting the surface mass balance......We present surface mass balance simulations of the Southern Patagonia Icefield (SPI) driven by downscaled reanalysis data. The simulations were evaluated and interpreted using geodetic mass balances, measured point balances and a complete velocity field of the icefield for spring 2004. The high...... from geodetic balances, calving fluxes were inferred. Mass losses of the SPI due to calving were strongly increasing from 1975-2000 to 2000-2011 and higher than losses due to surface melt. Calving fluxes were inferred for the individual glacier catchments and compared to fluxes estimated from velocity...

  2. Sustainability of algae derived biodiesel: a mass balance approach.

    Science.gov (United States)

    Pfromm, Peter H; Amanor-Boadu, Vincent; Nelson, Richard

    2011-01-01

    A rigorous chemical engineering mass balance/unit operations approach is applied here to bio-diesel from algae mass culture. An equivalent of 50,000,000 gallons per year (0.006002 m3/s) of petroleum-based Number 2 fuel oil (US, diesel for compression-ignition engines, about 0.1% of annual US consumption) from oleaginous algae is the target. Methyl algaeate and ethyl algaeate diesel can according to this analysis conceptually be produced largely in a technologically sustainable way albeit at a lower available diesel yield. About 11 square miles of algae ponds would be needed with optimistic assumptions of 50 g biomass yield per day and m2 pond area. CO2 to foster algae growth should be supplied from a sustainable source such as a biomass-based ethanol production. Reliance on fossil-based CO2 from power plants or fertilizer production renders algae diesel non-sustainable in the long term.

  3. A reconciled estimate of ice-sheet mass balance

    DEFF Research Database (Denmark)

    Shepherd, Andrew; Ivins, Erik R; A, Geruo;

    2012-01-01

    We combined an ensemble of satellite altimetry, interferometry, and gravimetry data sets using common geographical regions, time intervals, and models of surface mass balance and glacial isostatic adjustment to estimate the mass balance of Earth's polar ice sheets. We find that there is good...

  4. Mass and heat balance approach for oil sand flowsheets

    Energy Technology Data Exchange (ETDEWEB)

    Salama, A.I.A. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Energy Technology Centre

    2009-07-01

    Plant flowsheet mass balance is carried out in many industrial applications to evaluate overall plant performance and to optimize plant recoveries. This information is necessary for improving the economics of the operation and improving profitability. Flowsheet mass balance begins with the collection of plant stream samples using well-known sampling schemes. Stream samples collected using ASTM sampling standards are then analyzed using ASTM analytical techniques to characterize stream components which often contain sampling and analytical errors. The paper presented an approach for oil sands flowsheet mass and heat balance where different objective functions were presented depending on the nature of the stream error distributions. Hot water or steam is used to heat plant streams in oil sands extraction and froth treatment plants. As such, an approach is needed to integrate mass and heat balance. The mass and heat balance approach proposed in this paper integrated mass and heat balance and optimized the deviations/errors between the raw/observed and estimated data sets. The estimated data set was constrained to satisfy mass and heat balance conditions around the flowsheet internal nodes. Stream normalization and stream normalization conditions were forced. The relationship between the flowsheet independent, dependent, and reference streams were identified. The number of the independent stream mass splits was expressed in terms of the number of streams, number of nodes, and number of reference streams. 9 refs., 3 tabs., 2 figs.

  5. Quantifying mass balance processes on the Southern Patagonia Icefield

    Directory of Open Access Journals (Sweden)

    M. Schaefer

    2014-06-01

    Full Text Available We present surface mass balance simulations of the Southern Patagonia Icefield driven by downscaled reanalysis data. The simulations were validated and interpreted using geodetic mass balances, measured point balances and a complete velocity field of the Icefield from spring 2004. The high measured accumulation of snow as well as the high measured ablation is reproduced by the model. The overall modeled surface mass balance was positive and increasing during 1975–2011. Subtracting the surface mass balance from geodetic balances, calving fluxes were inferred. Mass losses of the SPI due to calving were strongly increasing from 1975–2000 to 2000–2011 and higher than losses due to surface melt. Calving fluxes were inferred for the individual glacier catchments and compared to fluxes estimated from velocity data. Measurements of ice thickness and flow velocities at the glaciers' front and spatially distributed accumulation measurements can help to reduce the uncertainties of the different terms in the mass balance of the Southern Patagonia Icefield.

  6. Juneau Icefield Mass Balance Program 1946–2011

    Directory of Open Access Journals (Sweden)

    M. Pelto

    2013-05-01

    Full Text Available The mass balance records of the Lemon Creek Glacier and Taku Glacier observed by the Juneau Icefield Research Program are the longest continuous glacier mass balance data sets in North America. On Taku Glacier annual mass balance averaged +0.40 m a−1 from 1946–1985 and −0.08 m a−1 from 1986–2011. The recent mass balance decline has resulted in the cessation of the long term thickening of the glacier. Mean annual mass balance on Lemon Creek Glacier has declined from −0.30 m a−1 for the 1953–1985 period to −0.60 m a−1 during the 1986–2011 period. The overall mass balance change is −26.6 m water equivalent, a 29 m of ice thinning over the 55 yr. Probing transects above the transient snow line (TSL indicate a consistent balance gradient from year to year. Observations of the rate of summer TSL rise on Lemon Creek and Taku Glacier indicate a comparatively consistent rate of 3.8 to 4.1 m d−1. The relationship between TSL on Lemon Creek and Taku Glacier to other Juneau Icefield glaciers, Norris, Mendenhall, Herbert, and Eagle, is strong with correlations exceeding 0.82 in all cases. doi:10.5065/D6NZ85N3

  7. Juneau Icefield Mass Balance Program 1946-2011

    Science.gov (United States)

    Pelto, M.; Kavanaugh, J.; McNeil, C.

    2013-11-01

    The annual surface mass balance records of the Lemon Creek Glacier and Taku Glacier observed by the Juneau Icefield Research Program are the longest continuous glacier annual mass balance data sets in North America. Annual surface mass balance (Ba) measured on Taku Glacier averaged +0.40 m a-1 from 1946-1985, and -0.08 m a-1 from 1986-2011. The recent annual mass balance decline has resulted in the cessation of the long-term thickening of the glacier. Mean Ba on Lemon Creek Glacier has declined from -0.30 m a-1 for the 1953-1985 period to -0.60 m a-1 during the 1986-2011 period. The cumulative change in annual surface mass balance is -26.6 m water equivalent, a 29 m of ice thinning over the 55 yr. Snow-pit measurements spanning the accumulation zone, and probing transects above the transient snow line (TSL) on Taku Glacier, indicate a consistent surface mass balance gradient from year to year. Observations of the rate of TSL rise on Lemon Creek Glacier and Taku Glacier indicate a comparatively consistent migration rate of 3.8 to 4.1 m d-1. The relationship between TSL on Lemon Creek Glacier and Taku Glacier to other Juneau Icefield glaciers (Norris, Mendenhall, Herbert, and Eagle) is strong, with correlations exceeding 0.82 in all cases. doi:10.5065/D6NZ85N3

  8. Uncertainties and re-analysis of glacier mass balance measurements

    Directory of Open Access Journals (Sweden)

    M. Zemp

    2013-03-01

    Full Text Available Glacier-wide mass balance has been measured for more than sixty years and is widely used as an indicator of climate change and to assess the glacier contribution to runoff and sea level rise. Until present, comprehensive uncertainty assessments have rarely been carried out and mass balance data have often been applied using rough error estimation or without error considerations. In this study, we propose a framework for re-analyzing glacier mass balance series including conceptual and statistical toolsets for assessment of random and systematic errors as well as for validation and calibration (if necessary of the glaciological with the geodetic balance results. We demonstrate the usefulness and limitations of the proposed scheme drawing on an analysis that comprises over 50 recording periods for a dozen glaciers and we make recommendations to investigators and users of glacier mass balance data. Reanalysis of glacier mass balance series needs to become a standard procedure for every monitoring programme to improve data quality and provide thorough uncertainty estimates.

  9. Binary stars: Mass transfer and chemical composition

    Science.gov (United States)

    Lambert, D. L.

    1982-01-01

    It is noted that mass exchange (and mass loss) within a binary system should produce observable changes in the surface chemical composition of both the mass losing and mass gaining stars as a stellar interior exposed to nucleosyntheses is uncovered. Three topics relating mass exchange and/or mass loss to nucleosynthesis are sketched: the chemical composition of Algol systems; the accretion disk of a cataclysmic variable fed by mass from a dwarf secondary star; and the hypothesis that classical Ba II giants result from mass transfer from a more evolved companion now present as a white dwarf.

  10. A Simple Watt Balance for the Absolute Determination of Mass

    Science.gov (United States)

    Quinn, Terry; Quinn, Lucas; Davis, Richard

    2013-01-01

    A watt balance is an electromechanical device that allows a mass to be determined in terms of measurable electrical and mechanical quantities, themselves traceable to the fundamental constants of physics. International plans are well advanced to redefine the unit of mass, the kilogram, in terms of a fixed numerical value for the Planck constant. A…

  11. 50 years of mass balance observations at Vernagtferner, Eastern Alps

    Science.gov (United States)

    Braun, Ludwig; Mayer, Christoph

    2016-04-01

    The determination and monitoring of the seasonal and annual glacier mass balances of Vernagtferner, Austria, started in 1964 by the Commission of Glaciology, Bavarian Academy of Sciences. Detailed and continuous climate- and runoff measurements complement this mass balance series since 1974. Vernagtferner attracted the attention of scientists since the beginning of the 17th century due to its rapid advances and the resulting glacier lake outburst floods in the Ötztal valley. This is one reason for the first photogrammetric survey in 1889, which was followed by frequent topographic surveys, adding up to more than ten digital elevation models of the glacier until today. By including the known maximum glacier extent at the end of the Little Ice Age in 1845, the geodetic glacier volume balances cover a time span of almost 170 years. The 50 years of glacier mass balance and 40 years of water balance in the drainage basin are therefore embedded in a considerably longer period of glacier evolution, allowing an interpretation within an extended frame of climatology and ice dynamics. The direct mass balance observations cover not only the period of alpine-wide strong glacier mass loss since the beginning of the 1990s. The data also contain the last period of glacier advances between 1970 and 1990. The combination of the observed surface mass exchange and the determined periodic volumetric changes allows a detailed analysis of the dynamic reaction of the glacier over the period of half a century. The accompanying meteorological observations are the basis for relating these reactions to the climatic changes during this period. Vernagtferner is therefore one of the few glaciers in the world, where a very detailed glacier-climate reaction was observed for many decades and can be realistically reconstructed back to the end of the Little Ice Age.

  12. Satellite-retrieval and modeling of glacier mass balance

    NARCIS (Netherlands)

    Ruyter de Wildt, Martijn Sybren de

    2002-01-01

    In this research project we use satellite measurements to infer the mean specific mass balance (Bm) of glaciers. Vatnajökull, the largest ice cap in Europe, is being used as a test-case because this ice cap has often been studied. Only one aspect of Vatnajökull has not been investigated so far, and

  13. Behavior, a Balanced Network of Chemical Transformations(Biokinetics)

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, D.F.; Calvin, M.

    1954-01-13

    While the concept of a biological system as a balanced network of chemical transformations is not a new one, experimental definition of specific systems has been lacking. This paper defines theoretically and experimentally a number of such networks and their behavior and response to some limited environmental changes.

  14. The climatic mass balance of Svalbard glaciers: a 10-year simulation with a coupled atmosphere-glacier mass balance model

    Science.gov (United States)

    Aas, Kjetil S.; Dunse, Thorben; Collier, Emily; Schuler, Thomas V.; Berntsen, Terje K.; Kohler, Jack; Luks, Bartłomiej

    2016-05-01

    In this study we simulate the climatic mass balance of Svalbard glaciers with a coupled atmosphere-glacier model with 3 km grid spacing, from September 2003 to September 2013. We find a mean specific net mass balance of -257 mm w.e. yr-1, corresponding to a mean annual mass loss of about 8.7 Gt, with large interannual variability. Our results are compared with a comprehensive set of mass balance, meteorological, and satellite measurements. Model temperature biases of 0.19 and -1.9 °C are found at two glacier automatic weather station sites. Simulated climatic mass balance is mostly within about 100 mm w.e. yr-1 of stake measurements, and simulated winter accumulation at the Austfonna ice cap shows mean absolute errors of 47 and 67 mm w.e. yr-1 when compared to radar-derived values for the selected years 2004 and 2006. Comparison of modeled surface height changes from 2003 to 2008, and satellite altimetry reveals good agreement in both mean values and regional differences. The largest deviations from observations are found for winter accumulation at Hansbreen (up to around 1000 mm w.e. yr-1), a site where sub-grid topography and wind redistribution of snow are important factors. Comparison with simulations using 9 km grid spacing reveal considerable differences on regional and local scales. In addition, 3 km grid spacing allows for a much more detailed comparison with observations than what is possible with 9 km grid spacing. Further decreasing the grid spacing to 1 km appears to be less significant, although in general precipitation amounts increase with resolution. Altogether, the model compares well with observations and offers possibilities for studying glacier climatic mass balance on Svalbard both historically as well as based on climate projections.

  15. A Reconciled Estimate of Ice-Sheet Mass Balance

    Science.gov (United States)

    Shepherd, Andrew; Ivins, Erik R.; Geruo, A.; Barletta, Valentia R.; Bentley, Mike J.; Bettadpur, Srinivas; Briggs, Kate H.; Bromwich, David H.; Forsberg, Rene; Galin, Natalia; Horwath, Martin; Jacobs, Stan; Joughin, Ian; King, Matt A.; Lenaerts, Jan T. M.; Li, Jilu; Ligtenberg, Stefan R. M.; Luckman, Adrian; Luthcke, Scott B.; McMillan, Malcolm; Meister, Rakia; Milne, Glenn; Mouginot, Jeremie; Muir, Alan; Nicolas,Julien P.; Paden, John; Payne, Antony J.; Pritchard, Hamish; Rignot, Eric; Rott, Helmut; Sorensen, Louise Sandberg; Scambos, Ted A.; Yi, Dohngui; Zwally, H. Jay

    2012-01-01

    We combined an ensemble of satellite altimetry, interferometry, and gravimetry data sets using common geographical regions, time intervals, and models of surface mass balance and glacial isostatic adjustment to estimate the mass balance of Earth's polar ice sheets. We find that there is good agreement between different satellite methods-especially in Greenland and West Antarctica-and that combining satellite data sets leads to greater certainty. Between 1992 and 2011, the ice sheets of Greenland, East Antarctica, West Antarctica, and the Antarctic Peninsula changed in mass by -142 plus or minus 49, +14 plus or minus 43, -65 plus or minus 26, and -20 plus or minus 14 gigatonnes year(sup -1), respectively. Since 1992, the polar ice sheets have contributed, on average, 0.59 plus or minus 0.20 millimeter year(sup -1) to the rate of global sea-level rise.

  16. Hypsometric control on glacier mass balance sensitivity in Alaska

    Science.gov (United States)

    McGrath, D.; Sass, L.; Arendt, A. A.; O'Neel, S.; Kienholz, C.; Larsen, C.; Burgess, E. W.

    2015-12-01

    Mass loss from glaciers in Alaska is dominated by strongly negative surface balances, particularly on small, continental glaciers but can be highly variable from glacier to glacier. Glacier hypsometry can exert significant control on mass balance sensitivity, particularly if the equilibrium line altitude (ELA) is in a broad area of low surface slope. In this study, we explore the spatial variability in glacier response to future climate forcings on the basis of hypsometry. We first derive mass balance sensitivities (30-70 m ELA / 1° C and 40-90 m ELA / 50% decrease in snow accumulation) from the ~50-year USGS Benchmark glaciers mass balance record. We subsequently assess mean climate fields in 2090-2100 derived from the IPCC AR5/CMIP5 RCP 6.0 5-model mean. Over glaciers in Alaska, we find 2-4° C warming and 10-20% increase in precipitation relative to 2006-2015, but a corresponding 0-50% decrease in snow accumulation due to rising temperatures. We assess changes in accumulation area ratios (AAR) to a rising ELA using binned individual glacier hypsometries. For an ELA increase of 150 m, the mean statewide AAR drops by 0.45, representing a 70% reduction in accumulation area on an individual glacier basis. Small, interior glaciers are the primary drivers of this reduction and for nearly 25% of all glaciers, the new ELA exceeds the glacier's maximum elevation, portending eventual loss. The loss of small glaciers, particularly in the drier interior of Alaska will significantly modify streamflow properties (flashy hydrographs, earlier and reduced peak flows, increased interannual variability, warmer temperatures) with poorly understood downstream ecosystem and oceanographic impacts.

  17. Regional and interannual variability of sea ice mass balance

    Science.gov (United States)

    Richter-Menge, J. A.; Perovich, D. K.; Nghiem, S. V.; Overland, J. E.

    2006-12-01

    The Arctic sea ice cover is undergoing significant climate-induced changes, affecting both its extent and thickness. The ice mass balance provides key insights into the nature of these changes by attributing them to variations in growth, surface melt, and bottom ablation. Ice mass balance buoys (IMB) autonomously monitor snow accumulation and ablation, ice growth and melt, and internal ice temperature. These buoys have been deployed in many locations, with an emphasis on the Beaufort Sea and the North Pole Environmental Observatory (NPEO). At the NPEO, the IMB sites are complemented by web cams which provide photographs showing changing surface conditions and the evolution of melt ponds in summer. IMB results indicate that there is significant regional and interannual variability in the mass balance. North Pole buoys, in particular, have recorded significant interannual variability in surface ablation, with values ranging from 0 to 35 cm from 2000 to 2005. There is good agreement determining the onset of melt and freezeup dates at the sites from both IMB results and from QuikScat satellite data. Results suggest that the total amount of surface melting is most significantly influenced by the date of the onset of summer melt. Quikscat results indicated that melt onset occurs concurrently over hundreds of kilometers providing a thermodynamic length scale, which may then be used to extrapolate the point measurements from the IMBs to larger scales.

  18. Milligram mass metrology using an electrostatic force balance

    Science.gov (United States)

    Shaw, Gordon A.; Stirling, Julian; Kramar, John A.; Moses, Alexander; Abbott, Patrick; Steiner, Richard; Koffman, Andrew; Pratt, Jon R.; Kubarych, Zeina J.

    2016-10-01

    Although mass is typically defined within the International System of Units (SI) at the kilogram level, the pending SI redefinition provides an opportunity to realize mass at any scale using electrical metrology. We propose the use of an electromechanical balance to realize mass at the milligram level using SI electrical units. An integrated concentric-cylinder vacuum gap capacitor allows us to leverage the highly precise references available for capacitance, voltage and length to generate an electrostatic reference force. Weighing experiments performed on 1 mg and 20 mg artifacts show the same or lower uncertainty than similar experiments performed by subdividing the kilogram. The measurement is currently limited by the stability of the materials that compose the mass artifacts and the changes in adsorbed layers on the artifact surfaces as they are transferred from vacuum to air.

  19. Mass balance inverse modelling of methane in the 1990s using a Chemistry Transport Model

    OpenAIRE

    T. M. Butler; Simmonds, I.; Rayner, P. J.

    2004-01-01

    International audience; A mass balance inverse modelling procedure is applied with a time-dependent methane concentration boundary condition and a chemical transport model to relate observed changes in the surface distribution of methane mixing ratios during the 1990s to changes in its surface sources. The model reproduces essential features of the global methane cycle, such as the latitudinal distribution and seasonal cycle of fluxes, without using a priori knowledge of methane fluxes. A det...

  20. Mass balance of the Lambert Glacier basin, East Antarctica

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Since it is the largest glacier system in Antarctica, the Lambert Glacier basin plays an important role in the mass balance of the overall Antarctic ice sheet. The observed data and shallow core studies from the inland traverse investigations in recent years show that there are noticeable differences in the distribution and variability of the snow accumulation rate between east and west sides. On the east side, the accumulation is higher on the average and has increased in the past decades, while on the west side it is contrary. The ice movement measurement and the ice flux calculation indicate that the ice velocity and the flux are larger in east than in west, meaning that the major part of mass supply for the glacier is from the east side. The mass budget estimate with the latest data gives that the integrated accumulation over the upstream area of the investigation traverse route is larger than the outflow ice flux by 13%, suggesting that the glacier basin is in a positive mass balance state and the ice thickness will increase if the present climate is keeping.

  1. Modelled climate sensitivity of the mass balance of Morteratschgletscher and its dependence on albedo parameterization

    NARCIS (Netherlands)

    Klok, E.J.; Oerlemans, J.

    2004-01-01

    This paper presents a study of the climate sensitivity of the mass balance of Morteratschgletscher in Switzerland, estimated from a two-dimensional mass balance model. Since the albedo scheme chosen is often the largest error source in mass balance models, we investigated the impact of using differe

  2. Balancing mass and momentum in the Local Group

    CERN Document Server

    Diaz, Jonathan D; Irwin, Mike; Belokurov, Vasily; Evans, Wyn

    2014-01-01

    In the rest frame of the Local Group (LG), the total momentum of the Milky Way (MW) and Andromeda (M31) should balance to zero. We use this fact to constrain new solutions for the solar motion with respect to the LG centre-of-mass, the total mass of the LG, and the individual masses of M31 and the MW. Using the set of remote LG galaxies at $>350$ kpc from the MW and M31, we find that the solar motion has amplitude $V_{\\odot}=299\\pm 15 {\\rm ~km~s^{-1}}$ in a direction pointing toward galactic longitude $l_{\\odot}=98.4^{\\circ}\\pm 3.6^{\\circ}$ and galactic latitude $b_{\\odot}=-5.9^{\\circ}\\pm 3.0^{\\circ}$. The velocities of M31 and the MW in this rest frame give a direct measurement of their mass ratio, for which we find $\\log_{10} (M_{\\rm M31}/M_{\\rm MW})=0.36 \\pm 0.29$. We combine these measurements with the virial theorem to estimate the total mass within the LG as $M_{\\rm LG}=(2.5\\pm 0.4)\\times 10^{12}~{\\rm M}_{\\odot}$. Our value for $M_{\\rm LG}$ is consistent with the sum of literature values for $M_{\\rm MW}...

  3. A Simplified Model of Human Alcohol Metabolism That Integrates Biotechnology and Human Health into a Mass Balance Team Project

    Science.gov (United States)

    Yang, Allen H. J.; Dimiduk, Kathryn; Daniel, Susan

    2011-01-01

    We present a simplified human alcohol metabolism model for a mass balance team project. Students explore aspects of engineering in biotechnology: designing/modeling biological systems, testing the design/model, evaluating new conditions, and exploring cutting-edge "lab-on-a-chip" research. This project highlights chemical engineering's impact on…

  4. The mass balance of the Greenland ice sheet: sensitivity to climate change as revealed by energy-balance modelling

    NARCIS (Netherlands)

    Oerlemans, J.

    1991-01-01

    The sensitivity of the mass balance of the Greenland ice sheet to climate change is studied with an energy-balance model of the ice/snow surface, applied at 200 m elevation intervals for four characteristic regions of the ice sheet. Solar radiation, longwave radiation, turbulent heat fluxes and refr

  5. Greenland Ice sheet mass balance from satellite and airborne altimetry

    Science.gov (United States)

    Khan, S. A.; Bevis, M. G.; Wahr, J. M.; Wouters, B.; Sasgen, I.; van Dam, T. M.; van den Broeke, M. R.; Hanna, E.; Huybrechts, P.; Kjaer, K.; Korsgaard, N. J.; Bjork, A. A.; Kjeldsen, K. K.

    2013-12-01

    Ice loss from the Greenland Ice Sheet (GrIS) is dominated by loss in the marginal areas. Dynamic induced ice loss and its associated ice surface lowering is often largest close to the glacier calving front and may vary from rates of tens of meters per years to a few meters per year over relatively short distances. Hence, high spatial resolution data are required to accurately estimate volume changes. Here, we estimate ice volume change rate of the Greenland ice sheet using data from Ice, Cloud and land Elevation Satellite (ICESat) laser altimeter during 2003-2009 and CryoSat-2 data during 2010-2012. To improve the volume change estimate we supplement the ICESat and CryoSat data with altimeter surveys from NASA's Airborne Topographic Mapper (ATM) during 2003-2012 and NASA's Land, Vegetation and Ice Sensor (LVIS) during 2007-2012. The Airborne data are mainly concentrated along the ice margin and therefore significantly improve the estimate of the total volume change. Furthermore, we divide the GrIS into six major drainage basins and provide volume loss estimates during 2003-2006, 2006-2009 and 2009-2012 for each basin and separate between melt induced and dynamic ice loss. In order to separate dynamic ice loss from melt processes, we use SMB values from the Regional Atmospheric Climate Model (RACMO2) and SMB values from a positive degree day runoff retention model (Janssens & Huybrechts 2000, Hanna et al. 2011 JGR, updated for this study). Our results show increasing SMB ice loss over the last decade, while dynamic ice loss increased during 2003-2009, but has since been decreasing. Finally, we assess the estimated mass loss using GPS observations from stations located along the edge of the GrIS and measurements from the Gravity Recovery and Climate Experiment (GRACE) satellite gravity mission. Hanna, E., et al. (2011), Greenland Ice Sheet surface mass balance 1870 to 2010 based on Twentieth Century Reanalysis, and links with global climate forcing, J. Geophys. Res

  6. Modelling aeolian sand transport using a dynamic mass balancing approach

    Science.gov (United States)

    Mayaud, Jerome R.; Bailey, Richard M.; Wiggs, Giles F. S.; Weaver, Corinne M.

    2017-03-01

    Knowledge of the changing rate of sediment flux in space and time is essential for quantifying surface erosion and deposition in desert landscapes. Whilst many aeolian studies have relied on time-averaged parameters such as wind velocity (U) and wind shear velocity (u*) to determine sediment flux, there is increasing field evidence that high-frequency turbulence is an important driving force behind the entrainment and transport of sand. At this scale of analysis, inertia in the saltation system causes changes in sediment transport to lag behind de/accelerations in flow. However, saltation inertia has yet to be incorporated into a functional sand transport model that can be used for predictive purposes. In this study, we present a new transport model that dynamically balances the sand mass being transported in the wind flow. The 'dynamic mass balance' (DMB) model we present accounts for high-frequency variations in the horizontal (u) component of wind flow, as saltation is most strongly associated with the positive u component of the wind. The performance of the DMB model is tested by fitting it to two field-derived (Namibia's Skeleton Coast) datasets of wind velocity and sediment transport: (i) a 10-min (10 Hz measurement resolution) dataset; (ii) a 2-h (1 Hz measurement resolution) dataset. The DMB model is shown to outperform two existing models that rely on time-averaged wind velocity data (e.g. Radok, 1977; Dong et al., 2003), when predicting sand transport over the two experiments. For all measurement averaging intervals presented in this study (10 Hz-10 min), the DMB model predicted total saltation count to within at least 0.48%, whereas the Radok and Dong models over- or underestimated total count by up to 5.50% and 20.53% respectively. The DMB model also produced more realistic (less 'peaky') time series of sand flux than the other two models, and a more accurate distribution of sand flux data. The best predictions of total sand transport are achieved using

  7. Assessing streamflow sensitivity to variations in glacier mass balance

    Science.gov (United States)

    O'Neel, Shad; Hood, Eran; Arendt, Anthony; Sass, Louis

    2014-01-01

    The mountains ringing the Gulf of Alaska (GOA) receive upwards of 4–8 m yr−1 of precipitation (Simpson et al.2005; Weingartner et al. 2005; O’Neel 2012), much of which runs off into productive coastal waters. The alpine landscape is heavily glacierized, and storage and turnover of water by glaciers substantially influences the regional surface water balance (Neal et al. 2010). In turn, the land-to-ocean flux of freshwater impacts the biogeochemistry, physical oceanography, freshwater and marine ecology of the downstream components of the GOA ecosystem (e.g., Royer et al. 2001; Hood and Scott 2008). In this way, the links between terrestrial and ocean ecosystems along the GOA have widespread impacts on regional socioeconomic issues including water and hydropower resources, fish populations, and sea level change (Dorava and Milner 2000; Royer and Grosch 2006; Cherry et al. 2010; Gardner et al. 2013). Moreover, predicting future changes in physical, chemical and biological processes in near-shore ecosystems along the GOA hinges, in part, on developing a robust understanding of water storage and transfer by glaciers through streams to the ocean.

  8. Mass balance and composition analysis of shredder residue.

    Energy Technology Data Exchange (ETDEWEB)

    Pomykala, J. A., Jr.; Jody, B. J.; Spangenberger, J. S.; Daniels, E. J.; Energy Systems

    2007-01-01

    The process of shredding end-of-life vehicles to recover metals results in a byproduct commonly referred to as shredder residue. The four-and-a-half million metric tons of shredder residue produced annually in the United States is presently land filled. To meet the challenges of automotive materials recycling, the U.S. Department of Energy is supporting research at Argonne National Laboratory in cooperation with the Vehicle Recycling Partnership (VRP) of the United States Council for Automotive Research (USCAR) and the American Plastics Council. This paper presents the results of a study that was conducted by Argonne to determine variations in the composition of shredder residue from different shredders. Over 90 metric tons of shredder residues were processed through the Argonne pilot plant. The contents of the various separated streams were quantitatively analyzed to determine their composition and to identify materials that should be targeted for recovery. The analysis established a reliable mass balance for the different materials in shredder residue.

  9. Stable isotope mass balance of lakes: a contemporary perspective

    Science.gov (United States)

    Gibson, J. J.; Birks, S. J.; Yi, Y.

    2016-01-01

    The theoretical basis for application of stable isotope mass balance of lakes is described for a range of climatic situations including low latitude, high latitude, high altitude, continental and coastal systems, as well as cases where the atmospheric boundary layer is significantly modified by the lake evaporation process. The effects of seasonality on isotopic offset between precipitation and atmospheric vapour and the slope of the local evaporation line are described. Atmospheric feedback and its role in labelling the isotopic composition of the Laurentian Great Lakes and tropical lakes is discussed. Several important considerations are suggested to improve parameterization of quantitative paleoclimatic reconstructions including use of assumptions that are appropriate for the climatic setting, for the atmospheric feedback situation, for salinity, and headwater setting. Potential for use of dual-isotopes to trace past changes in seasonality and input, and a dual-lake index method that can potentially be used to trace connectivity of lakes are presented. In cases where modern or paleo-evaporation systems may be under-defined there are inherent limitations in the degree of quantification that can be attained.

  10. Surface mass balance reanalysis of Taku and Lemon Creek glaciers, Alaska: 1946-2015

    Science.gov (United States)

    McNeil, Christopher

    We reanalyzed geodetic and glaciological surface mass balance records of Taku and Lemon Creek glaciers for the period 1946--2015 to determine what has driven the contradictory behavior of these glaciers. During the past century, Taku Glacier has been increasing in area and mass, while Lemon Creek Glacier has simultaneously shrunk in area and mass. Between 1948 and 1999 geodetic mass balance rates are +0.33+/-0.34 m w.e. a--1 for Taku Glacier and 0.61+/-0.34 m w.e. a--1 for Lemon Creek Glacier. Geodetic mass balance rates decreased to +0.01+/-0.23 m w.e. a--1 and --0.65 +/-0.23 m w.e. a--1 for Taku and Lemon Creek glaciers respectively, between 1999 and 2013. We updated the glaciological analysis of annual field data, and found no significant difference between updated and previous annual mass balance solutions (p--value Lemon Creek Glacier record. Comparing mass balance anomalies we determined inter--annual variability of surface mass balance is the same for Taku and Lemon Creek glaciers. However, differences in glacier specific hypsometry and mass balance profile drive systematic differences in both annual and long--term glacier mass balance rates.

  11. Runoff, precipitation, mass balance, and ice velocity measurements at South Cascade Glacier, Washington, 1993 balance year

    Science.gov (United States)

    Krimmel, R.M.

    1994-01-01

    Winter snow accumulation and summer snow, firn, and ice ablation were measured at South Cascade Glacier, Wash., to determine the winter and net balance for the 1993 balance year. The 1993 winter balance, averaged over the glacier, was 1.98 meters, and the net balance was -1.23 meters. This negative valance continued a trend of negative balance years beginning in 1977. Air temperature, barometric pressure, and runoff from this glacier basin and an adjacent non-glacierized basin were also continuously measured. Surface ice velocity was measured over an annual period. This report makes all these data available to users throughout the glaciological and climato1ogical community.

  12. Mass balance of nitrogen and potassium in urban groundwater in Central Africa, Yaounde/Cameroon.

    Science.gov (United States)

    Kringel, R; Rechenburg, A; Kuitcha, D; Fouépé, A; Bellenberg, S; Kengne, I M; Fomo, M A

    2016-03-15

    Mass flow of nutrients from innumerous latrines and septic tanks was assessed to best describe the groundwater quality situation in the urban environment of Yaounde. 37 groundwater samples were taken at the end of dry season 2012 and analysed for nutrient related (NO3(-), NH4(+), NO2(-), K(+), Cl(-), HPO4(2-) and TOC) and physico-chemical ambient parameters. A survey on waste water discharge close to water points constrained point sources from sanitation. The results showed that the median of nitrate concentration exceeds the WHO limit. We realized that EC increases from the geogenic background to very high levels in the urban area within short distance, suggesting anthropogenic input. Dug wells showed nitrate and ammonium in equivalent concentrations, indicating incomplete nitrification and mandating their inclusion into water type classification. The mass turnover of nutrients in urban groundwater scales high in comparison to national statistical figures on fertilizer import for 2012. A mass N,K balance for infiltration water overestimates observed concentrations by a factor of 4.5. The marked balance gap is attributed to dynamic non-equilibrium between input and output. Unresolved questions like a) urban sanitation, b) hygiene & health and c) environmental protection urgently call for closing the nutrient cycle. In the light of Cameroonian strategies on rural development, tackling the groundwater nutrient, urban agriculture, food--NEXUS might partially restore urban and periurban ecosystem services under economical constraints and thus improve living conditions.

  13. Dynamic mass balancing for wastewater treatment data quality control using CUSUM charts.

    Science.gov (United States)

    Spindler, A; Vanrolleghem, P A

    2012-01-01

    Mass balancing is a widely used tool for data quality control in wastewater treatment. It can effectively detect systematic errors in data. To overcome the limitations of the mean balancing error as a measure of data quality, a well established method for statistical process control (the CUSUM chart) is adopted for application on the error vector of balancing data. Two examples show how time periods with stable low mass balancing errors can be detected by the method. The detectability of such time periods depends on the variability of the balancing error which is an important measure for the precision of the data.

  14. Mass balance investigation of alpine glaciers through LANDSAT TM data

    Science.gov (United States)

    Bayr, Klaus J.

    1989-01-01

    An analysis of LANDSAT Thematic Mapper (TM) data of the Pasterze Glacier and the Kleines Fleisskees in the Austrian Alps was undertaken and compared with meteorological data of nearby weather stations. Alpine or valley glaciers can be used to study regional and worldwide climate changes. Alpine glaciers respond relatively fast to a warming or cooling trend in temperature through an advance or a retreat of the terminus. In addition, the mass balance of the glacier is being affected. Last year two TM scenes of the Pasterze Glacier of Aug. 1984 and Aug. 1986 were used to study the difference in reflectance. This year, in addition to the scenes from last year, one MSS scene of Aug. 1976 and a TM scene from 1988 were examined for both the Pasterze Glacier and the Kleines Fleisskees. During the overpass of the LANDSAT on 6 Aug. 1988 ground truthing on the Pasterze Glacier was undertaken. The results indicate that there was considerable more reflectance in 1976 and 1984 than in 1986 and 1988. The climatological data of the weather stations Sonnblick and Rudolfshuette were examined and compared with the results found through the LANDSAT data. There were relations between the meteorological and LANDSAT data: the average temperature over the last 100 years showed an increase of .4 C, the snowfall was declining during the same time period but the overall precipitation did not reveal any significant change over the same period. With the use of an interactive image analysis computer, the LANDSAT scenes were studied. The terminus of the Pasterze Glacier retreated 348 m and the terminus of the Kleines Fleisskees 121 m since 1965. This approach using LANDSAT MSS and TM digital data in conjunction with meteorological data can be effectively used to monitor regional and worldwide climate changes.

  15. Mass-balance ecosystem model of the East China Sea

    Institute of Scientific and Technical Information of China (English)

    Jiahua Cheng; William W.L. Cheung; Tony J. Pitcher

    2009-01-01

    Using the Ecopath mass-balance trophodynamic model, this paper analyzed the trophic levels, flows, food web structure and ecosys-tem maturity of the East China Sea, and identified ecologically important functional groups in the ecosystem. The model is based on fishery resource surveys of the East China Sea in 2000, studies on diet composition and global databases such as FishBase and the Sea Around Us Project Database. The results showed that trophic levels of the functional groups are between 2.86 and 4.37, with an average of 3.32. Anchocy (Engraulis japonicus), small fishes and benthic crustaceans such as shrimps and crabs are important groups in terms of the trophic structure and flow dynamics in the East China Sea. Energy flows of most groups are between specific trophic levels, except file fish (Thamnaconus spp.), pomfret (Pampus spp.) and cephalopods. Trophic transfer efficiency of levels Ⅱ,Ⅲ,Ⅳ and more than Ⅴ are 11.8%, 21.1%, 17.4% and 22.1-22.5%, respectively. Effects of fishery-the largest 'consumer' of the ecosystem -are much stronger than those exerted by biological groups in the system. The model suggests that the current fishery can further reduce the complexity of the ecosystem. Evaluations of the system indices suggest that maturity of the ecosystem is low. The conclusion of this model indicates that it was the overfishing that caused the ecosystem of the East China Sea declined, which should be taken into account as a critical reference for fisheries management in the future.

  16. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    NARCIS (Netherlands)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker; Ahlstrøm, Andreas P.; Abermann, Jakob; Andersen, Morten L.; Andersen, Signe B.; Bjørk, Anders A.; Box, Jason E.; Braithwaite, Roger J.; Bøggild, Carl E.; Citterio, Michele; Clement, Poul; Colgan, William; Fausto, Robert S.; Gleie, Karin; Gubler, Stefanie; Hasholt, Bent; Hynek, Bernhard; Knudsen, Niels T.; Larsen, Signe H.; Mernild, Sebastian H.; Oerlemans, Johannes; Oerter, Hans; Olesen, Ole B.; Smeets, C. J P Paul; Steffen, Konrad; Stober, Manfred; Sugiyama, Shin; Van As, Dirk; Van Den Broeke, Michiel R.; Van De Wal, Roderik S W

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in glac

  17. Spatial patterns of North Atlantic Oscillation influence on mass balance variability of European glaciers

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-06-01

    Full Text Available We present and validate a set of minimal models of glacier mass balance variability. The most skillful model is then applied to reconstruct 7735 individual time series of mass balance variability for all glaciers in the European Alps and Scandinavia. Subsequently, we investigate the influence of atmospheric variability associated with the North Atlantic Oscillation (NAO on the glaciers' mass balances.

    We find a spatial coherence in the glaciers' sensitivity to NAO forcing which is caused by regionally similar mechanisms relating the NAO forcing to the mass balance: in southwestern Scandinavia, winter precipitation causes a correlation of mass balances with the NAO. In northern Scandinavia, temperature anomalies outside the core winter season cause an anti-correlation between NAO and mass balances. In the western Alps, both temperature and winter precipitation anomalies lead to a weak anti-correlation of mass balances with the NAO, while in the eastern Alps, the influences of winter precipitation and temperature anomalies tend to cancel each other, and only on the southern side a slight anti-correlation of mass balances with the NAO prevails.

  18. Comparison of Various Dynamic Balancing Principles Regarding Additional Mass and Additional Inertia

    NARCIS (Netherlands)

    Wijk, van der Volkert; Demeulenaere, Bram; Herder, Just L.

    2009-01-01

    The major disadvantage of existing dynamic balancing principles is that a considerable amount of mass and inertia is added to the system. The objectives of this article are to summarize, to compare, and to evaluate existing complete balancing principles regarding the addition of mass and the additio

  19. Basin-scale partitioning of Greenland ice sheet mass balance components (2007-2011)

    DEFF Research Database (Denmark)

    Andersen, M.L.; Stenseng, Lars; Skourup, Henriette;

    2015-01-01

    The current deficit in Greenland ice sheet mass balance is due to both a decrease in surface mass balance (SMB) input and an increase in ice discharge (D) output. While SMB processes are beginning to be well captured by observationally-constrained climate modeling, insight into D is relatively li...

  20. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik; Weidick, Anker;

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in g...

  1. Chemical and mass evolution of galaxies

    CERN Document Server

    Ziegler, B L

    2004-01-01

    An introduction is given to projects investigating galaxy evolution quantitatively by spectroscopic observations of very distant galaxies that have weak apparent brightnesses and small sizes as it is feasible with 10m-class telescopes like SALT. Such methods encompass scaling relations like the Tully-Fisher and Fundamental Plane relations that can be utilized to determine the luminosity evolution and mass assembly of galaxies. The stellar populations can be analyzed with respect to age, metallicity, and chemical enrichment by measureing absorption line strengths. Possible effects on galaxy evolution of the environment in rich clusters of galaxies compared to the field are also addressed. For each method, recent applications are presented like the evolution of the TFR determined with 77 field spirals up to z=1, a study of the internal kinematics of distant cluster spirals and a comparison of the stellar populations of ellipticals in the field and in rich clusters at z=0.4.

  2. Hybrid inventory, gravimetry and altimetry (HIGA mass balance product for Greenland and the Canadian Arctic

    Directory of Open Access Journals (Sweden)

    W. Colgan

    2014-01-01

    Full Text Available We present a novel inversion algorithm that generates a mass balance field that is simultaneously consistent with independent observations of glacier inventory derived from optical imagery, cryosphere-attributed mass changes derived from satellite gravimetry, and ice surface elevation changes derived from airborne and satellite altimetry. We use this algorithm to assess mass balance across Greenland and the Canadian Arctic over the December 2003 to December 2010 period at 26 km resolution. We assess a total mass loss of 316 ± 37 Gt a−1 over Greenland and the Canadian Arctic, with 217 ± 20 Gt a−1 being attributed to the Greenland Ice Sheet proper, and 38 ± 6 Gt a−1 and 50 ± 8 Gt a−1 being attributed to peripheral glaciers in Greenland and the Canadian Arctic, respectively. These absolute values are dependent on the gravimetry-derived spherical harmonic representation we invert. Our attempt to validate local values of algorithm-inferred mass balance reveals a paucity of in situ observations. At four sites, where direct comparison between algorithm-inferred and in situ mass balance is valid, we find an RMSD of 0.18 m WE a−1. Differencing algorithm-inferred mass balance with previously modelled surface mass balance, in order to solve the ice dynamic portion of mass balance as a residual, allows the transient glacier continuity equation to be spatially partitioned across Greenland.

  3. Net mass balance calculations for the Shirase Drainage Basin, east Antarctica, using the mass budget method

    Science.gov (United States)

    Nakamura, Kazuki; Yamanokuchi, Tsutomu; Doi, Koichiro; Shibuya, Kazuo

    2016-06-01

    We quantify the mass budget of the Shirase drainage basin (SHI), Antarctica, by separately estimating snow accumulation (surface mass balance; SMB) and glacier ice mass discharge (IMD). We estimated the SMB in the SHI, using a regional atmospheric climate model (RACMO2.1). The SMB of the mainstream A flow region was 12.1 ± 1.5 Gt a-1 for an area of 1.985 × 105 km2. Obvious overestimation of the model round the coast, ∼0.5 Gt a-1, was corrected for. For calculating the IMD, we employed a 15-m resolution Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) with a digital elevation model (DEM) to determine the heights at the grounding line (GL), after comparison with the interpolated Bamber DEM grid heights; the results of this are referred to as the measured heights. Ice thickness data at the GL were inferred by using a free-board relationship between the measured height and the ice thickness, and considering the measured firn depth correction (4.2 m with the reference ice density of 910 kg m-3) for the nearby blue-ice area. The total IMD was estimated to be 14.0 ± 1.8 Gt a-1. Semi-empirical firn densification model gives the estimate within 0.1-0.2 Gt a-1 difference. The estimated net mass balance, -1.9 Gt a-1, has a two-σ uncertainty of ±3.3 Gt a-1, and probable melt water discharge strongly suggests negative NMB, although the associated uncertainty is large.

  4. Mass Balance of a Maritime Glacier on the Southeast Tibetan Plateau and Its Climatic Sensitivity

    Science.gov (United States)

    Yang, W.

    2014-12-01

    Based on glacio-meteorological measurements and mass-balance stake records during the five-year period of 2005-2010 on the southeast Tibetan Plateau, an energy-mass balance model was applied to study the surface mass balance of the Parlung No. 94 Glacier, as well as its response to regional climate conditions. The primary physical parameters involved in the model were locally calibrated by using relevant glacio-meteorological datasets. The good agreement between the snowpack height/mass balance simulations and the in-situ measurements available from a total of 12 monitoring stakes over this glacier confirmed the satisfactory performance of the energy-mass balance model. Results suggested that the recent state of the Parlung No. 94 Glacier was far removed from the 'ideal' climatic regime leading to zero mass balance, with its annual mass balance of approximately -0.9 m w.e. during 2005-2010. Climatic sensitivity experiments were also carried out to interpret the observed mass-balance changes, and the experiments demonstrated that the maritime glaciers concerned herein were theoretically more vulnerable to ongoing climate warming on the Tibetan Plateau than potential changes in the amount of precipitation. A plausible causal explanation for the recent glacier shrinkage in this region was concerned with the increasing air temperature. Moreover, both the mass balance simulations and the field measurements indicated that the mass accumulation over this maritime glacier occurred primarily in the boreal spring. Such "spring-accumulation type" glaciers are presumed to be distributed mainly within a narrow wedge-shaped region along the Brahmaputra River. Climatic sensitivities of the glacier mass balanceare also found to be closely linked to the regional precipitation seasonality that is simultaneously modulated by various atmospheric circulation patterns, such as the southern westerlies, the Bay of Bengal vortex in the spring season and the Indian monsoon in the summer

  5. Mass balance, runoff and surges of the Bering Glacier, Alaska

    Directory of Open Access Journals (Sweden)

    W. Tangborn

    2012-12-01

    Full Text Available The historical net, ablation and accumulation daily balances and runoff of the Bering Glacier, Alaska are determined for the 1951–2011 period with the PTAA (precipitation-temperature-area-altitude model, using daily precipitation and temperature observations collected at the Cordova and Yakutat weather stations, together with the area-altitude distribution of the glacier. The mean annual balance for this 61-yr period is −0.6 mwe, the accumulation balance is +1.4 and the ablation balance is −2.0 mwe. Periodic surges of this glacier transport large volumes of ice to lower elevations where the ablation rate is higher, producing more negative balances and increasing runoff. During the 1993–1995 surge the average ablation balance is −3.3 mwe, over a meter greater than the 1951–2011 average. Runoff from the Bering Glacier (derived from simulated ablation and precipitation as rain is highly correlated with the four glacier surges that have been observed since 1951. Ice volume loss for the 1972–2003 period measured with the PTAA model is 2.3 km3 we a−1 and closely agrees with losses for the same period measured with the geodetic method.

  6. Mass balance, runoff and surges of Bering Glacier, Alaska

    Directory of Open Access Journals (Sweden)

    W. Tangborn

    2013-05-01

    Full Text Available The historical net, ablation and accumulation daily balances, as well as runoff of Bering Glacier, Alaska are determined for the 1951–2011 period with the PTAA (precipitation-temperature-area-altitude model, using daily precipitation and temperature observations collected at the Cordova and Yakutat weather stations, together with the area-altitude distribution of the glacier. The model mean annual balance for this 61 yr period is −0.6 m w.e., the accumulation balance is +1.4 and the ablation balance is −2.0 m w.e. Average annual runoff is 2.5 m w.e. Periodic surges of this glacier transport large volumes of ice to lower elevations where the ablation rate is higher, producing more negative balances and increasing runoff. Runoff from Bering Glacier (derived from simulated ablation and precipitation as rain is highly correlated with four of the glacier surges that have occurred since 1951. Ice volume loss for the 1972–2003 period measured with the PTAA model is 2.7 km3 w.e. a−1 and closely agrees with losses for the same period measured with the geodetic method. It is proposed that the timing and magnitude of daily snow accumulation and runoff, both of which are controlled by the glacier's area-altitude distribution and are calculated with the PTAA model, can be used to determine the probability that a glacier will surge.

  7. Mass balance re-analysis of Findelengletscher, Switzerland; benefits of extensive snow accumulation measurements

    Directory of Open Access Journals (Sweden)

    Leo eSold

    2016-02-01

    Full Text Available A re-analysis is presented here of a 10-year mass balance series at Findelengletscher, a temperate mountain glacier in Switzerland. Calculating glacier-wide mass balance from the set of glaciological point balance observations using conventional approaches, such as the profile or contour method, resulted in significant deviations from the reference value given by the geodetic mass change over a five-year period. This is attributed to the sparsity of observations at high elevations and to the inability of the evaluation schemes to adequately estimate accumulation in unmeasured areas. However, measurements of winter mass balance were available for large parts of the study period from snow probings and density pits. Complementary surveys by helicopter-borne ground-penetrating radar (GPR were conducted in three consecutive years. The complete set of seasonal observations was assimilated using a distributed mass balance model. This model-based extrapolation revealed a substantial mass loss at Findelengletscher of -0.43m w.e. a^-1 between 2004 and 2014, while the loss was less pronounced for its former tributary, Adlergletscher (-0.30m w.e. a^-1. For both glaciers, the resulting time series were within the uncertainty bounds of the geodetic mass change. We show that the model benefited strongly from the ability to integrate seasonal observations. If no winter mass balance measurements were available and snow cover was represented by a linear precipitation gradient, the geodetic mass balance was not matched. If winter balance measurements by snow probings and snow density pits were taken into account, the model performance was substantially improved but still showed a significant bias relative to the geodetic mass change. Thus the excellent agreement of the model-based extrapolation with the geodetic mass change was owed to an adequate representation of winter accumulation distribution by means of extensive GPR measurements.

  8. Mass balance and long-term fate of PCDD/Fs in a lagoon sediment and paddy soil, Niigata, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Mizuki [National Institute for Agro-Environmental Science, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan)], E-mail: mizukis@affrc.go.jp; Seike, Nobuyasu [National Institute for Agro-Environmental Science, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan)], E-mail: seike@niaes.affrc.go.jp; Kobayashi, Jun [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan)], E-mail: kobayashi.jun@nies.go.jp; Kajihara, Hideo [National Institute of Advanced Industrial Science and Technology, 16-1 Tsukuba, Ibaraki 305-8569 (Japan)], E-mail: kajihara.hideo@aist.go.jp; Takahashi, Yukio [Academic Assembly Institute of Science and Technology, Niigata University, 2-8050 Ikarashi, Niigata City 950-2181 (Japan)], E-mail: yukitak@eng.niigata-u.ac.jp

    2008-12-15

    Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in a sediment core and in samples of surface sediment and paddy soil collected from the Toyano lagoon and Kameda basin in Niigata, Japan, were analyzed to elucidate the temporal trends of their concentrations in the lagoon sediment and the relationship between the sediment and the paddy soil. The mass balance of these pollutants was also estimated to determine their long-term fate in surface waters. An analysis by chemical mass balance identified the agrochemicals pentachlorophenol and 2,4,6-trichlorophenyl 4-nitrophenyl ether as the major sources of PCDD/Fs. On the basis of the findings regarding the mass balance in the Kameda basin over the last 40 years, we estimate that more than half the input of PCDD/Fs to the Kameda basin has disappeared. We suggest that the PCDD/Fs that flowed out from the paddy fields have been transferred to the lower basin. - The long-term mass balance of PCDD/Fs in sediments from paddy soil is elucidated.

  9. Mass Balance Modeling for Electric Arc Furnace and Ladle Furnace System in Steelmaking Facility in Turkey

    Institute of Scientific and Technical Information of China (English)

    (I)smail Ekmek(c)i; Ya(s)ar Yetisken; (U)nal (C)amdali

    2007-01-01

    In the electric arc furnace (EAF) steel production processes, scrap steel is principally used as a raw material instead of iron ore. In the steelmaking process with EAF, scrap is first melted in the furnace and then the desired chemical composition of the steel can be obtained in a special furnace such as ladle furnace (LF). This kind of furnace process is used for the secondary refining of alloy steel. LF furnace offers strong heating fluxes and enables precise temperature control, thereby allowing for the addition of desired amounts of various alloying elements. It also provides outstanding desulfurization at high-temperature treatment by reducing molten steel fluxes and removing deoxidation products. Elemental analysis with mass balance modeling is important to know the precise amount of required alloys for the LF input with respect to scrap composition. In present study, chemical reactions with mass conservation law in EAF and LF were modeled altogether as a whole system and chemical compositions of the final steel alloy output can be obtained precisely according to different scrap compositions, alloying elements ratios, and other input amounts. Besides, it was found that the mass efficiency for iron element in the system is 95.93%. These efficiencies are calculated for all input elements as 8.45% for C, 30.31% for Si, 46.36% for Mn, 30.64% for P, 41.96% for S, and 69.79% for Cr, etc. These efficiencies provide valuable ideas about the amount of the input materials that are vanished or combusted for 100 kg of each of the input materials in the EAF and LF system.

  10. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker;

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...... in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from...

  11. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from......Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...

  12. Global application of a surface mass balance model using gridded climate data

    Directory of Open Access Journals (Sweden)

    R. H. Giesen

    2012-04-01

    Full Text Available Global applications of surface mass balance models have large uncertainties, as a result of poor climate input data and limited availability of mass balance measurements. This study addresses several possible consequences of these limitations for the modelled mass balance. This is done by applying a simple surface mass balance model that only requires air temperature and precipitation as input data, to glaciers in different regions. In contrast to other models used in global applications, this model separately calculates the contributions of net solar radiation and the temperature-dependent fluxes to the energy balance. We derive a relation for these temperature-dependent fluxes using automatic weather station (AWS measurements from glaciers in different climates. With local, hourly input data, the model is well able to simulate the observed seasonal variations in the surface energy and mass balance at the AWS sites. Replacing the hourly local data by monthly gridded climate data removes summer snowfall and winter melt events and hence influences the modelled mass balance most on locations with a small seasonal temperature cycle. Representative values for the multiplication factor and vertical gradient of precipitation are determined by fitting modelled winter mass balance profiles to observations on 80 glaciers in different regions. For 72 of the 80 glaciers, the precipitation provided by the climate data set has to be multiplied with a factor above unity; the median factor is 2.55. The vertical precipitation gradient ranges from negative to positive values, with more positive values for maritime glaciers and a median value of 1.5 mm a−1 m. With calibrated precipitation, the modelled annual mass balance gradient closely resembles the observations on the 80 glaciers, the absolute values are matched by adjusting either the incoming solar radiation, the temperature-dependent flux or the air temperature. The mass balance sensitivity to

  13. Changes in self-reported energy balance behaviours and body mass index during a mass media campaign

    NARCIS (Netherlands)

    Verheijden, M.W.; Dommelen, P. van; Empelen, P. van; Crone, M.R.; Werkman, A.M.; Kesteren, N.M.C. van

    2012-01-01

    Background: Prevention of (serious) overweight can be achieved by means of small behaviour changes in physical activity and/or diet. Objective: To evaluate a mass media campaign promoting energy balance behaviours in a Dutch population. Effects were examined for body mass index (BMI) and five energy

  14. Exploring uncertainty in glacier mass balance modelling with Monte Carlo simulation

    NARCIS (Netherlands)

    Machguth, H.; Purves, R.S.; Oerlemans, J.; Hoelzle, M.; Paul, F.

    2008-01-01

    By means of Monte Carlo simulations we calculated uncertainty in modelled cumulative mass balance over 400 days at one particular point on the tongue of Morteratsch Glacier, Switzerland, using a glacier energy balance model of intermediate complexity. Before uncertainty assessment, the model was tun

  15. Torsion-balance experiments and ultra-low-mass fields

    Science.gov (United States)

    Terrano, William

    2017-01-01

    Many of the solutions to outstanding problems in modern cosmology posit new, ultra-light fields. Unifying General Relativity and Quantum Mechanics appears to require new ultra-light fields at some level. Such fields are also invoked to drive inflation and dark energy. Ultra-light fields may also make up much or all of the dark matter density of the universe. Torsion pendulums, a technology that dates to the 18th century, remain one of the most sensitive experimental techniques to search for ultra-light, weakly interacting fields. I will explain how torsion balance experiments can search for beyond-the-standard-model fields using laboratory-based as well as galactic sources, and the important cosmological implications of these measurements. I will also describe a new experimental signature for which certain torsion balance geometries make very sensitive direct dark matter detectors over a broad range of interesting dark matter parameter space.

  16. Point measurements of surface mass balance, Eklutna Glacier, Alaska, 2008-2015

    Science.gov (United States)

    Sass, Louis; Loso, Michael G; Geck, Jason

    2017-01-01

    This data set consists of a time-series of direct measurements of glacier surface mass balance, at Eklutna Glacier, Alaska. It includes seasonal measurements of winter snow accumulation and summer snow and ice ablation.

  17. USGS Alaska Benchmark Glacier Mass Balance Data - Phase 1; Gulkana and Wolverine Glaciers

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Since the late 1950s, USGS has maintained a long-term glacier mass-balance program at three North American glaciers. Similar measurements began at Sperry Glacier, MT...

  18. BALANCE

    Science.gov (United States)

    Carmichael, H.

    1953-01-01

    A torsional-type analytical balance designed to arrive at its equilibrium point more quickly than previous balances is described. In order to prevent external heat sources creating air currents inside the balance casing that would reiard the attainment of equilibrium conditions, a relatively thick casing shaped as an inverted U is placed over the load support arms and the balance beam. This casing is of a metal of good thernnal conductivity characteristics, such as copper or aluminum, in order that heat applied to one portion of the balance is quickly conducted to all other sensitive areas, thus effectively preventing the fornnation of air currents caused by unequal heating of the balance.

  19. Erosion rates deduced from Seasonal mass balance along an active braided river in Tianshan

    Directory of Open Access Journals (Sweden)

    Y. Liu

    2011-07-01

    Full Text Available We report measurements performed during two complete flow seasons on the Urumqi River, a proglacial mountain stream in the northeastern ank of the Tianshan, an active mountain range in Central Asia. This survey of flow dynamics and sediment transport (dissolved, suspended and bed loads, together with a 25-year record of daily discharge, enables the assessment of secular denudation rates on this high mountain catchment of Central Asia. Our results show that chemical weathering accounts for more than one third of the total denudation rate. Sediment transported as bed load cannot be neglected in the balance given that sand and gravel transport accounts for one third of the solid load of the river. Overall, the mean denudation rates are low, averaging 46 t × km−2 × yr−1 (17–18 m Myr−1. We furthermore analyse the hydrologic record to show that the long-term sediment budget is not dominated by extreme and rare events but by the total amount of rainfall or annual runoff. The rates we obtain are in agreement with rates obtained from the mass balance reconstruction of the Plio-Quaternary gravely deposits of the foreland but signicantly lower than the rates recently obtained from cosmogenic dating of river sand. We show that the resolution of this incompatibility has an important consequence for our understanding of the interplay between erosion and tectonics in the semi-humid ranges of Central Asia.

  20. Quantifying the Mass Balance of Ice Caps on Severnaya Zemlya, Russian High Arctic. I: Climate and Mass Balance of the Vavilov Ice Cap

    NARCIS (Netherlands)

    Bassford, R.P.; Siegert, M.J.; Dowdeswell, J.A.; Oerlemans, J.; Glazovsky, A.F.; Macheret, Y.Y.

    2006-01-01

    Due to their remote location within the Russian High Arctic, little is known about the mass balance of ice caps on Severnaya Zemlya now and in the past. Such information is critical, however, to building a global picture of the cryospheric response to climate change. This paper provides a numerical

  1. Seasonal Ice Mass-Balance Buoys: Adapting Tools to the Changing Arctic

    Science.gov (United States)

    2011-01-01

    drilled through the ice completely and are connected by umbilical cords to a central housing. One structure positions acoustic sonar units above and below...ice mass-balance buoy (IMB). Polashenski and others: Seasonal ice mass-balance buoys 19 IMB, connected by umbilical cords, is one example. The design...seasonal landfast ice just north of Barrow, Alaska. The location chosen was 1 km offshore on a flat undeformed pan of first-year ice approximately 1.6

  2. System Identification and Automatic Mass Balancing of Ground-Based Three-Axis Spacecraft Simulator

    Science.gov (United States)

    2006-08-01

    System Identification and Automatic Mass Balancing of Ground-Based Three-Axis Spacecraft Simulator Jae-Jun Kim∗ and Brij N. Agrawal † Department of...TITLE AND SUBTITLE System Identification and Automatic Mass Balancing of Ground-Based Three-Axis Spacecraft Simulator 5a. CONTRACT NUMBER 5b...and Dynamics, Vol. 20, No. 4, July-August 1997, pp. 625-632. 6Schwartz, J. L. and Hall, C. D., “ System Identification of a Spherical Air-Bearing

  3. Uncertainty of solute flux estimation in ungauged small streams: potential implications for input-output nutrient mass balances at stream reach scale

    Directory of Open Access Journals (Sweden)

    A. Butturini

    2005-01-01

    Full Text Available Input-output mass balances within stream reaches provide in situ estimates of stream nutrient retention/release under a wide spectrum of hydrological conditions. Providing good estimates of the mass balances for nutrients depends on precise hydrological monitoring and good chemical characterisation of stream water at the input and output ends of the stream reach. There is a need to optimise the hydrological monitoring and the frequencies of water sampling to yield precise annual mass balances, so as to avoid undue cost - high resolution monitoring and subsequent chemical analysis can be labour intensive and costly. In this paper, simulation exercises were performed using a data set created to represent the instantaneous discharge and solute dynamics at the input and output ends of a model stream reach during a one year period. At the output end, stream discharge and water chemistry were monitored continuously, while the input end was assumed to be ungauged; water sampling frequency was changed arbitrarily. Instantaneous discharge at the ungauged sampling point was estimated with an empirical power model linking the discharge to the catchment area (Hooper, 1986. The model thus substitutes for the additional gauge station. Simulations showed that 10 days was the longest chemical sampling interval which could provide reach annual mass balances of acceptable precision. Presently, the relationship between discharge and catchment area is usually assumed to be linear but simulations indicate that small departures from the linearity of this relationship could cause dramatic changes in the mass balance estimations.

  4. Understanding the Role of Wind in Reducing the Surface Mass Balance Estimates over East Antarctica

    Science.gov (United States)

    Das, I.; Scambos, T. A.; Koenig, L.; Creyts, T. T.; Bell, R. E.; van den Broeke, M. R.; Lenaerts, J.; Paden, J. D.

    2014-12-01

    Accurate quantification of surface snow-accumulation over Antarctica is important for mass balance estimates and climate studies based on ice core records. An improved estimate of surface mass balance must include the significant role near-surface wind plays in the sublimation and redistribution of snow across Antarctica. We have developed an empirical model based on airborne radar and lidar observations, and modeled surface mass balance and wind fields to produce a continent-wide prediction of wind-scour zones over Antarctica. These zones have zero to negative surface mass balance, are located over locally steep ice sheet areas (>0.002) and controlled by bedrock topography. The near-surface winds accelerate over these zones, eroding and sublimating the surface snow. This scouring results in numerous localized regions (≤ 200 km2) with reduced surface accumulation. Each year, tens of gigatons of snow on the Antarctic ice sheet are ablated by persistent near-surface katabatic winds over these wind-scour zones. Large uncertainties remain in the surface mass balance estimates over East Antarctica as climate models do not adequately represent the small-scale physical processes that lead to mass loss through sublimation or redistribution over the wind-scour zones. In this study, we integrate Operation IceBridge's snow radar over the Recovery Ice Stream with a series of ice core dielectric and depth-density profiles for improved surface mass balance estimates that reflect the mass loss over the wind-scour zones. Accurate surface mass balance estimates from snow radars require spatially variable depth-density profiles. Using an ensemble of firn cores, MODIS-derived surface snow grain size, modeled accumulation rates and surface temperatures from RACMO2, we assemble spatially variable depth-density profiles and use our mapping of snow density variations to estimate layer mass and net accumulation rates from snow radar layer data. Our study improves the quantification of

  5. Mass balance investigation of perfluorooctanoic acid PFOA environmental levels, emissions and sinks in the northern hemisphere

    Energy Technology Data Exchange (ETDEWEB)

    Cousins, I.T.; Prevedouros, K. [Stockholm Univ., Stockholm (Sweden); Buck, R.C.; Korzeniowski, S.H. [Dupont Chemical Solutions, Wilmington, DE (United States)

    2005-07-01

    Perfluoroalkyl sulfonic acids (PFAS) and perfluoroalkyl carboxylic acids (PFCAs) and their precursors are found in a wide array of environmental samples, and have no known degradation mechanisms. PFCAs have been used for over 50 years as processing aids in the manufacture of fluoropolymers. PFASs and fluorotelomer products are used in a wide variety of products and industrial processes. This study provided a detailed account of direct and indirect sources of perfluorooctanoic acid (PFOA) in the environment. A mass balance investigation between sources and amounts residing in the northern hemisphere was conducted, and the magnitude of historical removal processes was estimated. It was hypothesized that the majority of historical PFOA production use, and emissions occurred in the northern hemisphere. The study considered both direct and indirect sources. Production and emissions were calculated from a number of published and unpublished chemical industry data. A mass balance computation was performed to estimate historical PFOA emissions with existing environmental levels and historical losses. A literature search was used to estimate representative PFOA levels in sediments and biota. The study confirmed the importance of surface water compartments for PFOA storage. Important sink processes included physical mixing and sedimentation to the deep oceans and sediment burial. Maximum and minimum ranges of the sum of the total environmental inventory and historical sink processes overlapped the ranges of emission estimates. It was concluded that a quantitative comparison of the atmospheric transport of PFOA precursors and the aquatic transport of the substances showed that ocean transport is the most significant transport routes of PFOAs. 13 refs., 1 tab., 1 fig.

  6. Endocrine disrupting compounds (EDC) in municipal wastewater treatment: a need for mass balance.

    Science.gov (United States)

    Lee, Y M; Oleszkiewicz, J A; Cicek, N; Londry, K

    2004-06-01

    Increasing attention has been focused on endocrine disrupting compounds (EDCs) as pollutants in municipal wastewater. Recent studies have shown that these compounds can have a negative impact on the environment, and that in many cases they are not efficiently removed in wastewater treatment plants (WWTPs). Studies have also revealed that their destruction and transport out into the environment depend on the design and operational characteristics of these treatment systems and on the properties of the chemicals themselves. This paper reviews the current knowledge on EDCs, natural and synthetic hormones including estrone (E1), 17beta-estradiol (E2), and 17alpha-ethinylestradiol (EE2) in WWTP. Several key data gaps are addressed when assessing the removal of EDCs in WWTPs. First, analytical methods used by most researchers do not account for the inactive or conjugated form of the compounds, yet they can become deconjugated to active forms during treatment, leading to an additional source of contaminant load. Next, insufficient measurements are made at various stages within the WWTP preventing adequate analyses on how each u nit process contributes to degradation. Currently, there is no standardized procedure for assessing degradation of EDCs in WWTPs, and it is often difficult to compare published data generated by individual test protocols. This paper identifies streams that should be sampled in WWTPs and suggests a mass balance approach that takes into account all forms of the compound in both liquid and solid phases. Issues of potential concern in performing mass balances are discussed leading to a proposal of variables that should be analyzed and included in published articles. The adoption of similar methods by researchers in future work will produce a better picture of the presence and fate of these compounds in the environment.

  7. Compact Sensitive Piezoelectric Mass Balance for Measurement of Unconsolidated Materials in Space

    Science.gov (United States)

    Sherrit, Stewart; Trebi-Ollennu, Ashitey; Bonitz, Robert; Bar-Cohen, Yoseph; Yen, Jesse T.

    2010-01-01

    In many in-situ instruments information about the mass of the sample could aid in the interpretation of the data and portioning instruments might require an accurate sizing of the sample mass before dispensing the sample. In addition, on potential sample return missions a method to directly assess the captured sample size would be required to determine if the sampler could return or needs to continue attempting to acquire sample. In an effort to meet these requirements piezoelectric balances were developed using flextensional actuators which are capable of monitoring the mass using two methods. A piezoelectric balance could be used to measure mass directly by monitoring the voltage developed across the piezoelectric which is linear with force, or it could be used in resonance to produce a frequency change proportional to the mass change. In this case of the latter, the piezoelectric actuator/balance would be swept in frequency through its fundamental resonance. If a mass is added to the balance the resonance frequency would shift down proportionally to the mass. By monitoring the frequency shift the mass could be determined. This design would allow for two independent measurements of the mass. In microgravity environments spacecraft thrusters could be used to provide acceleration in order to produce the required force for the first technique or to bring the mass into contact with the balance in the second approach. In addition, the measuring actuators, if driven at higher voltages, could be used to fluidize the powder to aid sample movement. In this paper, we outline some of our design considerations and present the results of a few prototype balances that we have developed.

  8. Local reduction of decadal glacier thickness loss through mass balance management in ski resorts

    Science.gov (United States)

    Fischer, Andrea; Helfricht, Kay; Stocker-Waldhuber, Martin

    2016-11-01

    For Austrian glacier ski resorts, established in the 1970s and 1980s during a period of glacier advance, negative mass balances with resulting glacier area loss and decrease in surface elevation present an operational challenge. Glacier cover, snow farming, and technical snow production were introduced as adaptation measures based on studies on the effect of these measures on energy and mass balance. After a decade of the application of the various measures, we studied the transition from the proven short-term effects of the measures on mass balance to long-term effects on elevation changes. Based on lidar digital elevation models and differential GPS measurements, decadal surface elevation changes in 15 locations with mass balance management were compared to those without measures (apart from piste grooming) in five Tyrolean ski resorts on seven glaciers. The comparison of surface elevation changes presents clear local differences in mass change, and it shows the potential to retain local ice thickness over 1 decade. Locally up to 21.1 m ± 0.4 m of ice thickness was preserved on mass balance managed areas compared to non-maintained areas over a period of 9 years. In this period, mean annual thickness loss in 15 of the mass balance managed profiles is 0.54 ± 0.04 m yr-1 lower (-0.23 ± 0.04 m yr-1on average) than in the respective reference areas (-0.78 ± 0.04 m yr-1). At two of these profiles the surface elevation was preserved altogether, which is promising for a sustainable maintenance of the infrastructure at glacier ski resorts. In general the results demonstrate the high potential of the combination of mass balance management by snow production and glacier cover, not only in the short term but also for multi-year application to maintain the skiing infrastructure.

  9. Glaciological and geodetic mass balance of ten long-term glaciers in Norway

    Directory of Open Access Journals (Sweden)

    L. M. Andreassen

    2015-11-01

    Full Text Available The glaciological and geodetic methods provide independent observations of glacier mass balance. The glaciological method measures the surface mass balance, on a seasonal or annual basis, whereas the geodetic method measures surface, internal and basal mass balances, over a period of years or decades. In this paper, we reanalyse the 10 glaciers with long-term mass balance series in Norway. The reanalysis includes (i homogenisation of both glaciological and geodetic observation series, (ii uncertainty assessment, (iii estimates of generic differences including estimates of internal and basal melt, (iv validation, and (v partly calibration of mass balance series. This study comprises an extensive set of data (454 mass balance years, 34 geodetic surveys and large volumes of supporting data, such as metadata and field notes. In total, 21 periods of data were compared and the results show discrepancies between the glaciological and geodetic methods for some glaciers, which in part are attributed to internal and basal ablation and in part to inhomogeneity in the data processing. Deviations were smaller than 0.2 m w.e. a−1 for 12 out of 21 periods. Calibration was applied to seven out of 21 periods, as the deviations were larger than the uncertainty. The reanalysed glaciological series shows a more consistent signal of glacier change over the period of observations than previously reported: six glaciers had a significant mass loss (14–22 m w.e. and four glaciers were nearly in balance. All glaciers have lost mass after year 2000. More research is needed on the sources of uncertainty, to reduce uncertainties and adjust the observation programmes accordingly. The study confirms the value of carrying out independent high-quality geodetic surveys to check and correct field observations.

  10. Reconstructing mass balance of Garabashi Glacier (1800–2005 using dendrochronological data

    Directory of Open Access Journals (Sweden)

    E. A. Dolgova

    2013-01-01

    Full Text Available The exploration whether tree-ring data can be effectually applied for the mass balance reconstruction in Caucasus was the main goal of this research. Tree-ring width and maximum density chronologies of pine (Pinus sylvestris L. at seven high-elevation sites in Northern Caucasus were explored for this purpose. As well as in other places of the temperate zone tree- ring width has complex climate signal controlled both temperature and precipitation. Instrumental mass balance records of Garabashi Gglacier started at 1983s. It is well known that Caucasus glaciers intensively retreat in the last decades and according to instrumental data mass balance variations are mostly controlled by the ablation, i.e. summer temperature variations. Maximum density chronology has statistically significant correlation with mass balance due to summer temperature sensitivity and great input of ablation to total mass balance variations. To include in our reconstruction different climatically sensitive parameters, stepwise multiple regression model was used. The strongest relation (r = 0.88; r2 = 0.78; p < 0.05 between two ring-width and one maximum density chronologies was identified. Cross-validation test (r = 0.79; r2 = 0.62; p < 0.05 confirmed model adequacy and it allowed to reconstruct Garabashi Glacier mass balance for 1800–2005ss. Reconstructed and instrumental mass balance values coincide well except the most recent period in 2000s, when the reconstructed mass balance slightly underestimated the real values. However even in this period it remained negative as well as the instrumental records. The bias can be explained by the weak sensitivity of the chronologies to winter precipitation (i.e. accumulation. The tree-ring based mass balance reconstruction was compared with one based on meteorological data (since 1905s. Both reconstructions have good interannual agreement (r = 0.53; p < 0.05 particularly for the period between 1975 and 2005. According to the

  11. A LEGO Watt balance: An apparatus to determine a mass based on the new SI

    Science.gov (United States)

    Chao, L. S.; Schlamminger, S.; Newell, D. B.; Pratt, J. R.; Seifert, F.; Zhang, X.; Sineriz, G.; Liu, M.; Haddad, D.

    2015-11-01

    A global effort to redefine our International System of Units (SI) is underway, and the change to the new system is expected to occur in 2018. Within the newly redefined SI, the present base units will still exist but be derived from fixed numerical values of seven reference constants. In particular, the unit of mass (the kilogram) will be realized through a fixed value of the Planck constant h. A so-called watt balance, for example, can then be used to realize the kilogram unit of mass within a few parts in 108. Such a balance has been designed and constructed at the National Institute of Standards and Technology. For educational outreach and to demonstrate the principle, we have constructed a LEGO tabletop watt balance capable of measuring a gram-level masses to 1% relative uncertainty. This article presents the design, construction, and performance of the LEGO watt balance and its ability to determine h.

  12. Insight into glacier climate interaction: reconstruction of the mass balance field using ice extent data

    Science.gov (United States)

    Visnjevic, Vjeran; Herman, Frédéric; Licul, Aleksandar

    2016-04-01

    With the end of the Last Glacial Maximum (LGM), about 20 000 years ago, ended the most recent long-lasting cold phase in Earth's history. We recently developed a model that describes large-scale erosion and its response to climate and dynamical changes with the application to the Alps for the LGM period. Here we will present an inverse approach we have recently developed to infer the LGM mass balance from known ice extent data, focusing on a glacier or ice cap. The ice flow model is developed using the shallow ice approximation and the developed codes are accelerated using GPUs capabilities. The mass balance field is the constrained variable defined by the balance rate β and the equilibrium line altitude (ELA), where c is the cutoff value: b = max(βṡ(S(z) - ELA), c) We show that such a mass balance can be constrained from the observed past ice extent and ice thickness. We are also investigating several different geostatistical methods to constrain spatially variable mass balance, and derive uncertainties on each of the mass balance parameters.

  13. A high-resolution record of Greenland mass balance

    Science.gov (United States)

    McMillan, Malcolm; Leeson, Amber; Shepherd, Andrew; Briggs, Kate; Armitage, Thomas W. K.; Hogg, Anna; Kuipers Munneke, Peter; Broeke, Michiel; Noël, Brice; Berg, Willem Jan; Ligtenberg, Stefan; Horwath, Martin; Groh, Andreas; Muir, Alan; Gilbert, Lin

    2016-07-01

    We map recent Greenland Ice Sheet elevation change at high spatial (5 km) and temporal (monthly) resolution using CryoSat-2 altimetry. After correcting for the impact of changing snowpack properties associated with unprecedented surface melting in 2012, we find good agreement (3 cm/yr bias) with airborne measurements. With the aid of regional climate and firn modeling, we compute high spatial and temporal resolution records of Greenland mass evolution, which correlate (R = 0.96) with monthly satellite gravimetry and reveal glacier dynamic imbalance. During 2011-2014, Greenland mass loss averaged 269 ± 51 Gt/yr. Atmospherically driven losses were widespread, with surface melt variability driving large fluctuations in the annual mass deficit. Terminus regions of five dynamically thinning glaciers, which constitute less than 1% of Greenland's area, contributed more than 12% of the net ice loss. This high-resolution record demonstrates that mass deficits extending over small spatial and temporal scales have made a relatively large contribution to recent ice sheet imbalance.

  14. Elevation change and remote-sensing mass-balance methods on the Greenland ice sheet

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Reeh, Niels; Christensen, Erik Lintz

    radar (InSAR), it is possible to apply the principle of mass conservation and derive the mass balance from this. The method has previously been applied to a flow line, but the intention is here to attempt a regional, distributed calculation. We will present the method and its weaknesses and show a map...

  15. A 3-axis force balanced accelerometer using a single proof-mass

    Energy Technology Data Exchange (ETDEWEB)

    Lemkin, M.A.; Boser, B.E.; Auslander, D. [Univ. of California, Berkeley, CA (United States); Smith, J. [Sandia National Lab., Albuquerque, NM (United States)

    1997-04-01

    This paper presents a new method for wideband force balancing a proof-mass in multiple axes simultaneously. Capacitive position sense and force feedback are accomplished using the same air-gap capacitors through time multiplexing. Proof of concept is experimentally demonstrated with a single-mass monolithic surface micromachined 3-axis accelerometer.

  16. Can we close the long term mass balance equation for pollutants in highway ponds?

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby; Larsen, Torben; Rasmussen, Michael R.

    2007-01-01

    The paper discusses the prospects of finding the long term mass balance on basis of short term simulations. A step in this process is to see to which degree the mass balance equation can be closed by measurements. Accordingly the total accumulation of heavy metals and PAH's in 8 Danish detention...... ponds only receiving runoff from highways have been measured. The result shows that the incoming mass of heavy metals from short term runoff events is accumulated. This is not observable in the same magnitude for the toxic organic compounds. The results also show that the accumulation rates...

  17. Mass and chemical asymmetry in QCD matter

    CERN Document Server

    Palhares, L F; Villavicencio, C

    2008-01-01

    We consider two-flavor asymmetric QCD combined with a low-energy effective model inspired by chiral perturbation theory and lattice data to investigate the effects of masses, isospin and baryon number on the pressure and the deconfinement phase transition. Remarkable agreement with lattice results is found for the critical temperature behavior. Further analyses of the cold, dense case and the influence of quark mass asymmetry are also presented.

  18. Munition Mass Properties Measurement Procedures Using a Spin Balance Machine

    Science.gov (United States)

    2015-03-09

    POI and CG offset unbalance, Torsion Pendulum Oscillation to measure MOI, and Static Measurement of CG offset moment. The WSMR measuring machine is...invalid. The same is true if the order is reversed when taking tare readings after measuring the payload properties. (2) The machine/interface...Radius of gyration. D.3 The Torsion Pendulum method is the method used in most commercial mass properties machines. This method suspends or

  19. Estimating the avalanche contribution to the mass balance of debris covered glaciers

    Directory of Open Access Journals (Sweden)

    A. Banerjee

    2014-01-01

    Full Text Available Avalanche from high head walls dominates the net accumulation in many debris covered glaciers in the Himalaya. These avalanche contributions are difficult to directly measure and may cause a systematic bias in glaciological mass balance measurements. In this paper we develop a method to estimate the avalanche contribution using available data, within the context of an idealised flowline model of the glacier. We focus on Hamtah glacier in Western Himalaya and estimate the magnitude of the avalanche accumulation to its specific mass balance profile. Our estimate explains the reported discrepancy between values of recent glaciological and geodetic net mass balance for this glacier. Model estimate of accumulation area ratio (AAR for this glacier is small (0.1 even at a steady state. This shows that empirical mass balance–AAR relationships derived from glaciers which do not have a significant avalanche contribution will not apply to a large region containing a significant fraction avalanche fed ones.

  20. Dynamics and mass balance of Taylor Glacier, Antarctica: 2. Force balance and longitudinal coupling

    Science.gov (United States)

    Kavanaugh, J. L.; Cuffey, K. M.

    2009-11-01

    Taylor Glacier, Antarctica, exemplifies an ice sheet outlet that flows through a region of rugged topography and dry climate. In contrast to other well-studied outlets, Taylor Glacier moves very slowly, despite a thickness of order 1 km and driving stresses averaging 1.5 bars. Here we analyze new measurements of glacier geometry and surface velocity to elucidate flow dynamics of Taylor Glacier. Force balance and basal temperatures are calculated at six locations along the glacier's length using an algorithm developed for this study. The effects of stress-gradient coupling on longitudinal flow variations are also examined; we ask whether Kamb and Echelmeyer's (1986) linearized theory adequately describes the observed response of flow to large-amplitude variations in driving stress. The force balance calculations indicate that no basal motion is needed to explain the observed flow of Taylor Glacier. Inferred basal temperatures are within a few degrees of the melting point in regions of kilometer-thick ice and well below the melting point elsewhere; deformation of subfreezing ice largely controls the flow of Taylor Glacier. Basal drags are mostly in the range 0.9 to 1.2 bars, and lateral drags are in the range 0.2 to 0.5 bar. Stress-gradient coupling strongly reduces the variability of velocities along the glacier. The velocity variations can be described as the convolution of a forcing function with a spatial filter, as Kamb and Echelmeyer suggested, but the form of the forcing function differs from the theoretical relation derived for small-amplitude perturbations (the power on driving stress is one, not three).

  1. The influence of changes in glacier extent and surface elevation on modeled mass balance

    Directory of Open Access Journals (Sweden)

    F. Paul

    2010-12-01

    Full Text Available Glaciers are widely recognized as unique demonstration objects for climate change impacts, mostly due to the strong change of glacier length in response to small climatic changes. However, glacier mass balance as the direct response to the annual atmospheric conditions can be better interpreted in meteorological terms. When the climatic signal is deduced from long-term mass balance data, changes in glacier geometry (i.e. surface extent and elevation must be considered as such adjustments form an essential part of the glacier reaction to new climatic conditions. In this study, a set of modelling experiments is performed to assess the influence of changes in glacier geometry on mass balance for constant climatic conditions. The calculations are based on a simplified distributed energy/mass balance model in combination with information on glacier extent and surface elevation for the years 1850 and 1973/1985 for about 60 glaciers in the Swiss Alps. The results reveal that over this period about 50–70% of the glacier reaction to climate change (here a one degree increase in temperature is "hidden" in the geometric adjustment, while only 30–50% can be measured as the long-term mean mass balance. For larger glaciers, the effect of the areal change is partly reduced by a lowered surface elevation, which results in a slightly more negative balance despite a potential increase of topographic shading. In view of several additional reinforcement feedbacks that are observed in periods of strong glacier decline, it seems that the climatic interpretation of long-term mass balance data is rather complex.

  2. The influence of changes in glacier extent and surface elevation on modeled mass balance

    Directory of Open Access Journals (Sweden)

    F. Paul

    2010-06-01

    Full Text Available Glaciers are widely recognized as unique demonstration objects for climate change impacts, mostly due to the strong change of glacier length in response to small climatic changes. However, glacier mass balance as the direct response to the annual atmospheric conditions can be better interpreted in meteorological terms. When the climatic signal is deduced from long-term mass balance data, changes in glacier geometry (i.e. surface extent and elevation must be considered as such adjustments form an essential part of the glacier reaction to new climatic conditions. In this study, a set of modeling experiments is performed to assess the influence of changes in glacier geometry on mass balance for constant climatic conditions. The calculations are based on a simplified distributed energy/mass balance model in combination with information on glacier extent and surface elevation for the years 1850 and 1973/1985 for a larger sample of glaciers in the Swiss Alps. The results reveal that about 50–70% of the glacier reaction to climate change (here a one degree increase in temperature is "hidden" in the geometric adjustment, while only 30–50% can be measured as the long-term mean mass balance. Thereby, changes in glacier extent alone have an even stronger effect, but they are partly compensated for by a lowered surface elevation which gives on average a slightly more negative balance despite an increase of topographic shading. In view of several additional reinforcement feedbacks that are observed in periods of strong glacier decline, it seems that the climatic interpretation of mass balance data is also rather complex.

  3. Understanding the distribution, degradation and fate of organophosphate esters in an advanced municipal sewage treatment plant based on mass flow and mass balance analysis.

    Science.gov (United States)

    Liang, Kang; Liu, Jingfu

    2016-02-15

    Although organophosphate esters (OPEs) in the ambient environment are from sewage treatment plants due to the discharge of effluent and application of sludge, the distribution, degradation and fate of OPEs in advanced municipal sewage treatment plants remain unclear. This work focused on the use of mass flow and mass balance analysis to understand the behaviors and fate of 14 OPEs in an advanced municipal sewage treatment plant. OPEs were detected in all sewage water and sludge samples with total OPEs (ΣOPEs) concentrations of 1399 ± 263 ng/L in raw sewage aqueous phase, 833 ± 175 ng/L in tertiary effluent aqueous phase, and 315 ± 89 ng/g dry weight in dewatered sludge. The dissolved concentrations of ΣOPEs significantly decreased during biological treatment, whereas negligible decrease was observed in mechanical and physical-chemical treatments. For individual OPE, the chlorinated tris(2-chloroethyl) phosphate (TCEP) and tris(2-chloroisopropyl) phosphate (TCPP) did not decrease but increased during both biological treatment and physical-chemical treatment. Mass flow analysis indicated the total removal efficiency of ΣOPEs in aqueous phase was 40.5%, and the polarity-specific removal efficiencies for individual OPE were positively related to their solid-water partition coefficients (Kd). Furthermore, mass balance results showed that 53.1% and 6.3% of the initial OPE mass flow were eventually transferred to the effluents and dewatered sludge, respectively, while the remaining 39.9% and 0.7% were lost due to biodegradation and physical-chemical treatment, respectively. It was indicated that the activated sludge treatment system with anaerobic/anoxic/aerobic bioreactors was a major factor in the removal of OPEs from the raw sewage, while transfer to dewatered sludge governed by hydrophobic interactions was limited during the sewage treatment. Meanwhile, the degradation difference of OPEs in activated sludge treatment was more related with their molecular

  4. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005-2015

    Science.gov (United States)

    Clark, Adam M.; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, -3.41, and -0.40 m w.e. yr-1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  5. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005–2015

    Science.gov (United States)

    Clark, Adam; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, −3.41, and −0.40 m w.e. yr−1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  6. Introduction to computational mass transfer with applications to chemical engineering

    CERN Document Server

    Yu, Kuo-Tsong

    2014-01-01

    This book presents a new computational methodology called Computational Mass Transfer (CMT). It offers an approach to rigorously simulating the mass, heat and momentum transfer under turbulent flow conditions with the help of two newly published models, namely the C’2—εC’ model and the Reynolds  mass flux model, especially with regard to predictions of concentration, temperature and velocity distributions in chemical and related processes. The book will also allow readers to understand the interfacial phenomena accompanying the mass transfer process and methods for modeling the interfacial effect, such as the influences of Marangoni convection and Rayleigh convection. The CMT methodology is demonstrated by means of its applications to typical separation and chemical reaction processes and equipment, including distillation, absorption, adsorption and chemical reactors. Professor Kuo-Tsong Yu is a Member of the Chinese Academy of Sciences. Dr. Xigang Yuan is a Professor at the School of Chemical Engine...

  7. An improved technique for the reconstruction of former glacier mass-balance and dynamics

    Science.gov (United States)

    Carr, Simon; Coleman, Christopher

    2007-11-01

    The recognition of past glacier extent and dynamics is a fundamental aspect of investigations of the climatic sensitivity of glaciers, especially when examining short-lived climate events such as the Younger Dryas or Little Ice Age. Existing approaches to the reconstruction of glacier form and dynamics depend on speculative reasoning of key glacier dynamic parameters, including the role of basal slip and subglacial deformation in glacier mass-transfer. This study reviews approaches to glacier reconstruction, derivation of former glacier equilibrium line altitudes (ELA's) and estimation of mass-balance and dynamics, concluding that most reconstructions of glacier mass-balance are compromised by a lack of glaciological considerations. An alternative approach to glacier reconstruction is presented, demonstrated and discussed, by which an empirical relationship between ablation gradient and mass loss at the ELA is used to derive mass-balance, mass-flux through the ELA and average balance velocity at the ELA. This 'glaciological' approach is applied to four reconstructed glaciers to test previous interpretations that each reflects Younger Dryas glaciation in the UK. The study concludes that this approach provides a more robust technique for reconstructing former glacier dynamics, and may be applied to test geomorphological interpretations of former mountain glaciation.

  8. Relations between atmospheric circulation and mass balance of South Cascade Glacier, Washington, USA

    Science.gov (United States)

    McCabe, G.J.; Fountain, A.G.

    1995-01-01

    The yearly net mass balance of South Cascade Glacier, Washington, has decreased since the mid-1970s. Resuls show that the decrease is primarily caused by a significant decrease in the winter mass balance. Changes in atmospheric circulation indicate a decrease in the movement of storms and moisture from the Pacific Ocean into the western contiguous United States. In addition, the increase in winter mean 700-mb heights over western Canada and the northern western contiguous United States indicates an increase in subsidence, which results in a warming and drying of the air that further reduces precipitation and also increases the ratio of rain to snow during the cold season. These factors contribute to below-average winter mass balances. -from Authors

  9. Hybrid inventory, gravimetry and altimetry (HIGA) mass balance product for Greenland and the Canadian Arctic

    DEFF Research Database (Denmark)

    Colgan, W.; Abdalati, W.; Citterio, M.

    2015-01-01

    an RMSE of 0.15 mWE/a, and highlights a paucity of in situ observations from regions of high dynamic mass loss and peripheral glaciers. We assess mass losses of 212 ± 67 Gt/a to the Greenland ice sheet proper, 38 ± 11 Gt/a to peripheral glaciers in Greenland, and 42 ± 11 Gt/a to glaciers in the Canadian...... Arctic. These magnitudes of mass loss are dependent on the gravimetry-derived spherical harmonic mass trend we invert. We spatially partition the transient glacier continuity equation by differencing algorithm-inferred mass balance from modeled surface mass balance, in order to solve the horizontal......We present a novel inversion algorithm that generates a mass balance field that is simultaneously consistent with independent observations of glacier inventory derived from optical imagery, cryosphere-attributed mass trends derived from satellite gravimetry, and ice surface elevation trends derived...

  10. Investigating glacial mass balance variability around the Prince Gustav Channel

    Science.gov (United States)

    Royston, Samantha; Gudmundsson, Hilmar; Clarke, Lucy; Fox, Adrian

    2015-04-01

    Glaciers on the Antarctic Peninsula have shown a varied response to recent climatic change. Most commonly, AP tidewater glaciers have retreated at the calving front and their flow rate has accelerated, increasing the contribution to sea level rise. Here, we utilise the results from a new photogrammetric technique that unlocks the archives of aerial photography from the 1940's to present, to investigate the driving mechanisms of glacier mass change on the AP over this period. Surface DEMs at different epochs have been derived using the new technique for a number of individual glacier basins. A higher-order vertically-integrated ice stream model is used to investigate the driving mechanisms of change for the area around the Prince Gustav Channel, incorporating basins covered by the new datasets. The Prince Gustav Ice Shelf collapsed in January 1995, followed by significant frontal retreat and speed up of its tributary glaciers. Additionally, significant changes have been observed for non-tributary glaciers such as Whisky Glacier on James Ross Island. Here, we investigate the sensitivity of this region's glaciers to ice shelf collapse, atmospheric and oceanic variability.

  11. Re-analysis of Alaskan benchmark glacier mass-balance data using the index method

    Science.gov (United States)

    Van Beusekom, Ashely E.; O'Nell, Shad R.; March, Rod S.; Sass, Louis C.; Cox, Leif H.

    2010-01-01

    At Gulkana and Wolverine Glaciers, designated the Alaskan benchmark glaciers, we re-analyzed and re-computed the mass balance time series from 1966 to 2009 to accomplish our goal of making more robust time series. Each glacier's data record was analyzed with the same methods. For surface processes, we estimated missing information with an improved degree-day model. Degree-day models predict ablation from the sum of daily mean temperatures and an empirical degree-day factor. We modernized the traditional degree-day model and derived new degree-day factors in an effort to match the balance time series more closely. We estimated missing yearly-site data with a new balance gradient method. These efforts showed that an additional step needed to be taken at Wolverine Glacier to adjust for non-representative index sites. As with the previously calculated mass balances, the re-analyzed balances showed a continuing trend of mass loss. We noted that the time series, and thus our estimate of the cumulative mass loss over the period of record, was very sensitive to the data input, and suggest the need to add data-collection sites and modernize our weather stations.

  12. Mass and Heat Transfer Enhancement of Chemical Heat Pumps

    Institute of Scientific and Technical Information of China (English)

    Gui-PingLin; Xiu-GanYuan

    1993-01-01

    An inert additive,expanded graphit(EG),has been prepared and used to enhance the heat and mass transfer process of chemical heat pumps.The effects of mixing ratio and mixing method on the chemical reaction time are investigated.

  13. Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

    Science.gov (United States)

    Mills, Patrick C.; Duncker, James J.; Over, Thomas M.; Marian Domanski,; ,; Engel, Frank

    2014-01-01

    A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows.

  14. A simple, mass balance model of carbon flow in a controlled ecological life support system

    Science.gov (United States)

    Garland, Jay L.

    1989-01-01

    Internal cycling of chemical elements is a fundamental aspect of a Controlled Ecological Life Support System (CELSS). Mathematical models are useful tools for evaluating fluxes and reservoirs of elements associated with potential CELSS configurations. A simple mass balance model of carbon flow in CELSS was developed based on data from the CELSS Breadboard project at Kennedy Space Center. All carbon reservoirs and fluxes were calculated based on steady state conditions and modelled using linear, donor-controlled transfer coefficients. The linear expression of photosynthetic flux was replaced with Michaelis-Menten kinetics based on dynamical analysis of the model which found that the latter produced more adequate model output. Sensitivity analysis of the model indicated that accurate determination of the maximum rate of gross primary production is critical to the development of an accurate model of carbon flow. Atmospheric carbon dioxide was particularly sensitive to changes in photosynthetic rate. The small reservoir of CO2 relative to large CO2 fluxes increases the potential for volatility in CO2 concentration. Feedback control mechanisms regulating CO2 concentration will probably be necessary in a CELSS to reduce this system instability.

  15. A heuristic simulation model of Lake Ontario circulation and mass balance transport

    Science.gov (United States)

    McKenna, J.E.; Chalupnicki, M.A.

    2011-01-01

    The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.

  16. Characterization and mass balance of trace elements in an iron ore sinter plant

    Directory of Open Access Journals (Sweden)

    Lucas Ladeira Lau

    2016-04-01

    Full Text Available Environmental legislation is becoming more restrictive in several industrial sectors, especially in the steel industry, which is well known for its large pollution potential. With the recent growth of interest in effects of trace elements on the environment and health, the inclusion of emission limits on these elements in this legislation has become increasingly popular. This article aims to describe the partitioning of trace elements between the products (sinter and plant emissions in an iron ore sinter plant, aiming to better understand the behavior of these elements in the sintering process to eventually support interventions to modify these partitions. Chemical characterization of several sintering inputs was initially performed, revealing that the steel-making residues contained large concentrations of trace elements, whereas low concentrations were observed in the flux. Based on the trace element concentrations, we analyzed the injection of trace elements in a sintering pilot using a sintering mixture. Mass balance was then used to determine the theoretical partitioning of trace elements in the sinter and emissions; cadmium, nickel, lead, mercury, and copper exhibited greater tendencies to concentrate in atmospheric emissions.

  17. A mass balance of tri-hexabrominated diphenyl ethers in lactating cows.

    Science.gov (United States)

    Kierkegaard, Amelie; De Wit, Cynthia A; Asplund, Lillemor; McLachlan, Michael S; Thomas, Gareth O; Sweetman, Andrew J; Jones, Kevin C

    2009-04-01

    Beef and dairy products can be important vectors of human exposure to polybrominated diphenylethers (BDEs), and hence an understanding of BDE transfer from feed to cows' milk and tissue is important for BDE exposure assessment The fate of tri- to hexaBDEs in lactating cows exposed to a naturally contaminated diet was studied by analyzing feed, feces, and milk samples from a mass balance study. Tissue distribution was studied in one cowslaughtered afterthe experiment The carryover rates from feed to milk ranged from 0.15 to 0.35 for the major congeners. Lower values were observed for several of the tetrabrominated congeners, and this was attributed to metabolism. The dietary absorption efficiency decreased with increasing octanol-water partition coefficient of the BDE congener. The absorption behavior was consistent with a model based on chemical lipophilicity, but agreed less well with a model based on effective molecular diameter, and it violated Lipinski's "rule of 5". The lipid normalized concentrations were similar in all tissues analyzed including liver and milk, suggesting that tissue distribution is governed by partitioning into lipids. Overall, the behavior of the tri- to hexaBDEs was consistent with that observed for other classes of halogenated aromatic contaminants such as PCBs and PCDD/Fs, but it differed markedly from the behavior of the hepta- decaBDEs.

  18. Recent geodetic mass balance of Monte Tronador glaciers, northern Patagonian Andes

    Science.gov (United States)

    Ruiz, Lucas; Berthier, Etienne; Viale, Maximiliano; Pitte, Pierre; Masiokas, Mariano H.

    2017-02-01

    Glaciers in the northern Patagonian Andes (35-46° S) have shown a dramatic decline in area in the last decades. However, little is known about glacier mass balance changes in this region. This study presents a geodetic mass balance estimate of Monte Tronador (41.15° S; 71.88° W) glaciers by comparing a Pléiades digital elevation model (DEM) acquired in 2012 with the Shuttle Radar Topography Mission (SRTM) X-band DEM acquired in 2000. We find a slightly negative Monte-Tronador-wide mass budget of -0.17 m w.e. a-1 (ranging from -0.54 to 0.14 m w.e. a-1 for individual glaciers) and a slightly negative trend in glacier extent (-0.16 % a-1) over the 2000-2012 period. With a few exceptions, debris-covered valley glaciers that descend below a bedrock cliff are losing mass at higher rates, while mountain glaciers with termini located above this cliff are closer to mass equilibrium. Climate variations over the last decades show a notable increase in warm season temperatures in the late 1970s but limited warming afterwards. These warmer conditions combined with an overall drying trend may explain the moderate ice mass loss observed at Monte Tronador. The almost balanced mass budget of mountain glaciers suggests that they are probably approaching a dynamic equilibrium with current (post-1977) climate, whereas the valley glaciers tongues will continue to retreat. The slightly negative overall mass budget of Monte Tronador glaciers contrasts with the highly negative mass balance estimates observed in the Patagonian ice fields further south.

  19. Seasonal and annual mass balances of Mera and Pokalde glaciers (Nepal Himalaya since 2007

    Directory of Open Access Journals (Sweden)

    P. Wagnon

    2013-07-01

    Full Text Available In the Everest region, Nepal, ground-based monitoring programs were started on the debris-free Mera Glacier (27.7° N, 86.9° E; 5.1 km2, 6420 to 4940 m a.s.l. in 2007 and on the small Pokalde Glacier (27.9° N, 86.8° E; 0.1 km2, 5690 to 5430 m a.s.l., ∼ 25 km North of Mera Glacier in 2009. These glaciers lie on the southern flank of the central Himalaya under the direct influence of the Indian monsoon and receive more than 80% of their annual precipitation in summer (June to September. Despite a large inter-annual variability with glacier-wide mass balances ranging from −0.77± 0.40 m w.e. in 2011–2012 (Equilibrium-line altitude (ELA at ∼ 6055 m a.s.l. to + 0.46 ± 0.40 m w.e. in 2010–2011 (ELA at ∼ 5340 m a.s.l., Mera Glacier has been shrinking at a moderate mass balance rate of −0.10± 0.40 m w.e. yr−1 since 2007. Ice fluxes measured at two distinct transverse cross sections at ∼ 5350 m a.s.l. and ∼ 5520 m a.s.l. confirm that the mean state of this glacier over the last one or two decades corresponds to a limited mass loss, in agreement with remotely-sensed region-wide mass balances of the Everest area. Seasonal mass balance measurements show that ablation and accumulation are concomitant in summer which in turn is the key season controlling the annual glacier-wide mass balance. Unexpectedly, ablation occurs at all elevations in winter due to wind erosion and sublimation, with remobilized snow likely being sublimated in the atmosphere. Between 2009 and 2012, the small Pokalde Glacier lost mass more rapidly than Mera Glacier with respective mean glacier-wide mass balances of −0.72 and −0.26 ± 0.40 m w.e. yr−1. Low-elevation glaciers, such as Pokalde Glacier, have been usually preferred for in-situ observations in Nepal and more generally in the Himalayas, which may explain why compilations of ground-based mass balances are biased toward negative values compared with the regional mean under the present-day climate.

  20. Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

    Science.gov (United States)

    Harvey, J.W.; Fuller, C.C.

    1998-01-01

    cumulative effect of hyporheic exchange in Pinal Creek basin was to remove approximately 20% of the dissolved manganese flowing out of the drainage basin. Our results illustrate that the cumulative significance of reactive uptake in the hyporheic zone depends on the balance between chemical reaction rates, hyporheic porewater residence time, and turnover of streamflow through hyporheic flow paths. The similarity between the hyporheic reaction timescale (1??(s) ??? 1.3 hours), and the hyporheic porewater residence timescale (t(s) ??? 8 min) ensured that there was adequate time for the reaction to progress. Furthermore, it was the similarity between the turnover length for stream water flow through hyporheic flow paths (L(s) = stream velocity/storage-zone exchange coefficient ??? 1.3 km) and the length of Pinal Creek (L ??? 7 km), which ensured that all stream water passed through hyporheic flow paths several times. As a means to generalize our findings to other sites where similar types of hydrologic and chemical information are available, we suggest a cumulative significance index for hyporheic reactions, R(s) = ??(s)t(s)L/L(s) (dimensionless); higher values indicate a greater potential for hyporheic reactions to influence geochemical mass balance. Our experience in Pinal Creek basin suggests that values of R(s) > 0.2 characterize systems where hyporheic reactions are likely to influence geochemical mass balance at the drainage-basin scale.

  1. Elastodynamic Effects of Mass-Balancing: Experimental Investigation of a Four-Bar Linkage

    Directory of Open Access Journals (Sweden)

    Alberto Martini

    2013-01-01

    Full Text Available This paper deals with static balancing of closed-loop mechanisms. The long-term goal of the research is enhancing the performance of parallel robots by means of effective static balancing strategies that take into account the system dynamic behaviour. In this contribution, the influence of mass-balancing on the elastodynamic performance of a four-bar linkage, intended as the simplest example of closed-loop mechanism, is experimentally investigated. The design of the experimental apparatus is discussed and the results of tests on both an unbalanced linkage and its balanced variant are presented. Base-transmitted forces and vibrations are monitored for constant-speed operations and for velocity ramp tests in order to characterize the elastodynamic behaviour of the linkages. The analysis is supported by implementing a flexible multibody model of the experimental apparatus that enhances the interpretation of the experimental data.

  2. How to do an energy balance in the PRESENCE of chemical reaction - Part 1

    OpenAIRE

    Fernandez-Torres, Maria J.

    2013-01-01

    A solved example for the determination of the increment in enthalpy for the energy balances for open systems in the context of chemical engineering is presented. The example shows how to tackle this kind of problems when it has been decided not to make use of the enthalpy of the reaction. The substances elements will be used as reference state.

  3. How to do an energy balance in the PRESENCE of chemical reaction - part 2

    OpenAIRE

    Fernandez-Torres, Maria J.

    2013-01-01

    A solved example for the determination of the increment in enthalpy for the energy balances for open systems in the context of chemical engineering is presented. The example shows how to tackle this kind of problems when it has been decided to make use of the enthalpy of the reaction.

  4. Teaching Population Balances for Chemical Engineering Students: Application to Granulation Processes

    Science.gov (United States)

    Bucala, Veronica; Pina, Juliana

    2007-01-01

    The population balance equation (PBE) is a useful tool to predict particle size distributions in granulation processes. When PBE is taught to advanced chemical engineering students, the internal coordinates (particle properties) are particularly hard to understand. In this paper, the flow of particles along different coordinates is carefully…

  5. Impact of Seminal Chemical Elements on the Oxidative Balance in Bovine Seminal Plasma and Spermatozoa

    OpenAIRE

    Eva Tvrdá; Norbert Lukáč; Monika Schneidgenová; Jana Lukáčová; Csaba Szabó; Zofia Goc; Agnieszka Greń; Peter Massányi

    2013-01-01

    Mutual relationships between selected chemical elements (Na, K, Fe, Cu, Mg, and Zn), basic motility characteristics (motility and progressive motility), and markers of the oxidative balance (superoxide dismutase, catalase, glutathione, albumin, and malondialdehyde) were investigated in bovine seminal plasma and spermatozoa. Computer assisted sperm analysis was used to assess the motility parameters; mineral concentrations were determined by the voltammetric method and flame absorption spectro...

  6. Evaluating Greenland glacial isostatic adjustment corrections using GRACE, altimetry and surface mass balance data

    NARCIS (Netherlands)

    Sutterley, T.C.; Velicogna, I.; Csatho, B.; van den Broeke, M.R.; Rezvan-Behbahani, S.; Babonis, G.

    2014-01-01

    Glacial isostatic adjustment (GIA) represents a source of uncertainty for ice sheet mass balance estimates from the Gravity Recovery and Climate Experiment (GRACE) timevariable gravity measurements. We evaluate Greenland GIA corrections from Simpson et al (2009 Quat. Sci. Rev. 28 1631–57), A et al (

  7. High variability of climate and surface mass balance induced by Antarctic ice rises

    NARCIS (Netherlands)

    Lenaerts, Jan; Brown, Joel; van den Broeke, Michiel; Matsuoka, Kenichi; Drews, Reinhard; Callens, Denis; Philippe, Morgane; Gorodetskaya, I.V.; van Meijgaard, E.; Tijm - Reijmer, Catharina; Pattyn, F.; van Lipzig, N.P.M.

    2014-01-01

    Ice rises play key roles in buttressing the neighbouring ice shelves and potentially provide palaeoclimate proxies from ice cores drilled near their divides. Little is known, however, about their influence on local climate and surface mass balance (SMB). Here we combine 12 years (2001–12) of regiona

  8. Combining satellite altimetry and gravimetry data to improve Antarctic mass balance and gia estimates

    NARCIS (Netherlands)

    Gunter, B.C.; Didova, O.; Riva, R.E.M.; van den Broeke, M.R.; Ligtenberg, S.R.M.; Lenaerts, J.T.M.; King, M.; Urban, T.

    2012-01-01

    This study explores an approach that simultaneously estimates Antarctic mass balance and glacial isostatic adjustment (GIA) through the combination of satellite gravity and altimetry data sets. The results improve upon previous efforts by incorporating reprocessed data sets over a longer period of t

  9. Thorium Mass Balance for the Moon from Lunar Prospector and Sample Data: Implications for Thermal Evolution

    Science.gov (United States)

    Jolliff, Bradley L.; Gillis, Jeffrey J.; Haskin, Larry A.

    2000-01-01

    A global lunar mass-balance model for Th based on Lunar Prospector gamma-ray and lunar sample data is presented within the context of major crustal terranes. The consequences of strong enrichment of Th in the Procellarum KREEP Terrane are discussed.

  10. Regulatory aspects of human radiolabeled mass balance studies in oncology : concise review

    NARCIS (Netherlands)

    Nijenhuis, C. M.; Schellens, J. H M; Beijnen, J. H.

    2016-01-01

    Human radiolabeled mass balance studies are performed to obtain information about the absorption, distribution, metabolism, and excretion of a drug in development. The main goals are to determine the route of elimination and major metabolic pathways. This review provides an overview of the current r

  11. Microbial transglutaminase production by Streptoverticillium mobaraense: Analysis of amino acid metabolism using mass balances

    NARCIS (Netherlands)

    Zhu, Y.; Rinzema, A.; Bonarius, H.P.J.; Tramper, J.; Bol, J.

    1998-01-01

    Metabolic flows, especially those of amino acids, were determined and analyzed at different stages of a batch fermentation for microbial transglutaminase production by Streptoverticillium mobaraense. The method is mainly based on mass balances and measurements of amino acids and other metabolites. T

  12. THE LAKE MICHIGAN MASS BALANCE PROJECT: QUALITY ASSURANCE PLAN FOR MATHEMATICAL MODELLING

    Science.gov (United States)

    This report documents the quality assurance process for the development and application of the Lake Michigan Mass Balance Models. The scope includes the overall modeling framework as well as the specific submodels that are linked to form a comprehensive synthesis of physical, che...

  13. Nitrate Removal in Two Relict Oxbow Urban Wetlands: A 15N Mass-balance Approach

    Science.gov (United States)

    A 15N-tracer method was used to quantify nitrogen (N) removal processes in two relict oxbow wetlands located adjacent to the Minebank Run restored stream reach in Baltimore County (Maryland, USA) during summer 2009 and early spring 2010. A mass-balance approach was used to determ...

  14. Mass Balance Model, A study of contamination effects in AMS 14C sample analysis

    NARCIS (Netherlands)

    Prokopiou, Markella

    2010-01-01

    In this training thesis a background correction analysis, also known as mass balance model, was implemented to study the contamination effects in AMS 14C sample processing. A variety of backgrounds and standards with sizes ranging from 50 μg C to 1500 μg

  15. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    NARCIS (Netherlands)

    Rae, J.G.L.; Aðalgeirsdóttir, G.; Edwards, T.L.; Fettweis, X.; Gregory, J.M.; Hewitt, H.T.; Lowe, J.A.; Lucas-Picher, P.; Mottram, R.H.; Payne, A.J.; Ridley, J.K.; Shannon, S.R.; van de Berg, W.J.; van de Wal, R.S.W.; van den Broeke, M.R.

    2012-01-01

    Four high-resolution regional climate models (RCMs) have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB), and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution gener

  16. Influence of persistent wind scour on the surface mass balance of Antarctica

    NARCIS (Netherlands)

    Das, I.; Bell, R.E.; Lenaerts, J.T.M.; Broeke, M.R. van den

    2013-01-01

    Accurate quantification of surface snow accumulation over Antarctica is a key constraint for estimates of the Antarctic mass balance, as well as climatic interpretations of ice-core records1,2. Over Antarctica, near-surface winds accelerate down relatively steep surface slopes, eroding and sublimati

  17. The application of a phosphorus mass balance model for estimating the carrying capacity of Lake Kariba

    OpenAIRE

    MHLANGA, Lindah; MHLANGA, Wilson; MWERA, Paul

    2013-01-01

    The aim of this study was to use an empirical mass balance equation to estimate the carrying capacity of Lake Kariba, where cage culture for Nile tilapia Oreochromis niloticus has been practiced since 1996. The carrying capacity for the lake was estimated at 33.2 × 103 t per year using the Dillon-Rigler phosphorus budget model.

  18. Monthly solutions of ice sheet mass balance at basin scale – and their associated uncertainties

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Barletta, Valentina Roberta; Forsberg, René

    2012-01-01

    There are still discrepancies in published ice sheet mass balance results, even between ones based on the same data sets. It can be difficult to conclude from where the discrepancies arise, and it is therefore important to cross calibrate methods, data and models in order to determine...

  19. Future climate warming increases Greenland ice sheet surface mass balance variability

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.; Price, S.

    2014-01-01

    The integrated surface mass balance (SMB) of the Greenland ice sheet (GrIS) has large interannual variability. Long-term future changes to this variability will affect GrIS dynamics, freshwater fluxes, regional oceanography, and detection of changes in ice volume trends. Here we analyze a simulated

  20. Implementation of depth-dependent soil concentrations in multimedia mass balance models.

    NARCIS (Netherlands)

    Hollander, A.; Hessels, L.; Voogt, P De; Meent, D. van de

    2004-01-01

    In standard multimedia mass balance models, the soil compartment is modeled as a box with uniform concentrations, which often does not correspond with actual field situations. Therefore, the theoretically expected decrease of soil concentrations with depth was implemented in the multimedia model Sim

  1. Implementation of depth-dependent soil concentrations in multimedia mass balance models

    NARCIS (Netherlands)

    Hollander, A.; Hessels, L.; de Voogt, P.; van de Meent, D.

    2004-01-01

    In standard multimedia mass balance models, the soil compartment is modeled as a box with uniform concentrations, which often does not correspond with actual field situations. Therefore, the theoretically expected decrease of soil concentrations with depth was implemented in the multimedia model Sim

  2. Computer Aided Mass Balance Analysis for AC Electric Arc Furnace Steelmaking

    Institute of Scientific and Technical Information of China (English)

    (ü)nal Camdali; Murat Tunc

    2005-01-01

    A mass balance analysis was undertaken for liquid steel production using a computer program specially developed for the AC electric arc furnace at an important alloy steel producer in Turkey. The data obtained by using the computer program were found to be very close to the actual production ones.

  3. Transdermal administration of radiolabelled [14C]rotigotine by a patch formulation: A mass balance trial

    NARCIS (Netherlands)

    Cawello, W.; Wolff, H.M.; Meuling, W.J.A.; Horstmann, R.; Braun, M.

    2007-01-01

    Background and objective: The dopamine agonist rotigotine has been formulated in a silicone-based transdermal system for once-daily administration. The objective of the present study was to characterise the mass balance of rotigotine in humans after administration of a single transdermal patch conta

  4. MASS BALANCE: A KEY TO ADVANCING MONITORED AND ENHANCED ATTENUATION FOR CHLORINATED SOLVENTS

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B; Karen Vangelas, K; Karen-M Adams, K; Francis H. Chappelle; Tom O. Early; Claire H. Sink

    2006-06-30

    removal is needed or when to turn off active remediation and transition to MNA. It cannot be used to evaluate potential enhancement options (unless a long period of post enhancement monitoring is planned). It provides only indirect information about process and treats the plume as a ''black box''. The empirical approach has the advantage that, when sufficient monitoring data are available, the attenuation capacity can be defined inexpensively and with a high degree of certainty. Alternatively, a deterministic approach can be used to assess mass balance and plume stability. In this approach, the physical, chemical, and biological attenuation processes are used to assess contaminant loading and attenuation. The deterministic approach has the advantage that, when sufficient hydrologic, geochemical, and microbiological data are available, it is possible to project how a system will respond to contaminant removal actions or enhancements of natural attenuation processes. The ''black box'' of the plume is taken apart, quantified, and put back together again. The disadvantage of the deterministic approach is that it is difficult to measure all or most of the relevant hydrologic, geochemical, and biological parameters with any certainty. Case studies over the past decade demonstrate that empirical and deterministic approaches to MNA/EA are not mutually exclusive. These studies document that improved decision support and efficiency result by combining these methods based on the individual challenges presented by a given site. Whenever possible, the empirical approach is used to quantify mass loading and attenuation capacity (mass of contaminant/unit time) at particular sites. This is the most effective way to demonstrate the efficiency of ongoing natural attenuation processes in accordance with current regulatory guidance. But in addition, the monitoring well networks needed to apply the empirical approach can also yield estimates of the

  5. Long-term mass- and energy balance of Kongsvegen glacier, Spitzbergen

    Science.gov (United States)

    Krismer, Thomas; Obleitner, Friedrich; Kohler, Jack

    2010-05-01

    We present meteorological and glaciological data from the equilibrium line (ELA) of Kongsvegen glacier (550masl) in Svalbard, covering the period 2000 until 2008. Mean annual air temperatures for the period range from -6.9 to -10.1°C and specific net annual mass balances range from -670 to +281 mm w eq. During some years substantial superimposed ice was formed and even survived the summer. The meteorological data were homogenized and used for input and validation of mass- and energy-balance simulations. The meteorological regime at the ELA is characterized by a coreless winter and summer temperatures around 0°C. Wind conditions are largely determined by katabatic winds and topgraphically channeled upper-air winds. Net short-wave radiation is determined by cloudiness during the polar day and by the seasonal evolution of glacier surface albedo. Long-wave radiation fluxes withdraw energy throughout the year and the mean annual net radiation is almost negligible. The turbulent sensible heat fluxes constitute a comparatively strong and continuous source of energy. The latent heat flux is characterized by prevailing condensation during winter and evaporation during summer. On average, however, the turbulent fluxes provide only a small amount of heat to the glacier. Most of the energy available from the atmosphere is used for summer melt and a small amount goes into heating the near surface ice layers. Similar investigations were performed at the tongue of the glacier (170masl) for a shorter period. Here the conditions are characterized by enhanced input from the atmospheric fluxes and correspondingly increased melt rates. In addition, accumulation is usually small (>50 cm snow) and melt can also occur during winter. We then investigate whether spatially distributed mass balance can be simulated using data measured outside of the glacier. Regression models were developed to derive model input from climate data measured at a nearby research station. These models are

  6. Mass balance of Greenland and the Canadian Ice Caps from combined altimetry and GRACE inversion

    DEFF Research Database (Denmark)

    Forsberg, René; Simonsen, Sebastian Bjerregaard; Sørensen, Louise Sandberg

    The combination of GRACE and altimetry data may yield a high resolution mass balance time series of the Greenlandice sheet, highlighting the varying individual mass loss behaviour of major glaciers. By including the Canadian arctic ice caps in the estimation, a more reliable estimate of the mass...... loss of both Greenlandand the Canadian ice caps may be obtained, minimizing the leakage errors otherwise unavoidable by GRACE. Actually, the absolute value of the Greenlandice sheet mass loss is highly dependent on methods and how the effects of Arctic Canadian ice caps are separated in the GRACE...... loss of the ice caps and ice sheet basins for the period 2003-15. This period shows a marked increase of ice sheet melt, especially in NW and NE Greenland, but also show large variability, with the melt anomaly year of 2012 showing a record mass loss, followed by 2013 with essentially no Greenland mass...

  7. The seasonal in-situ mass balance, temperature and precipitation of Yala Glacier, Langtang Valley, Nepal, from 2011 to 2015

    Science.gov (United States)

    Stumm, Dorothea; Fujita, Koji; Gurung, Tika; Joshi, Sharad; Litt, Maxime; Shea, Joseph; Sherpa, Mingma; Sinisalo, Anna; Wagnon, Patrick

    2016-04-01

    In-situ glacier mass balance measurements are still scarce in the Hindu Kush Himalayan (HKH) region and little is known about the seasonal balances. The glaciers in the Nepalese Himalaya have been considered summer accumulation glacier types because of the assumption that the majority of the accumulation occurs in the summer months during the monsoon. The glacier mass balance of Yala Glacier in the Langtang Valley of Nepal has been measured using the glaciological method since autumn 2011. Stakes were measured biannually in pre- and post-monsoon, usually in early May and in November, respectively. The measured mass balance gradient for the summer balance was larger than the winter balance, which is typical for glaciers with distinct ablation and accumulation seasons. On Yala Glacier, the summer balance was negative, and the winter balance was positive in all years with measurements. However, the annual net balance was negative for all four mass balance years from 2011 to 2015. The mass balances were further compared to temperature and precipitation data measured at nearby climate stations during the same time periods. In October 2013 and 2014, the Central Himalayas received large amounts of precipitation brought by the cyclones Phailin and Hudhud. These precipitation events contributed to the summer balance since the measurements were taken after the cyclones passed. In conclusion, on Yala Glacier accumulation processes dominated ablation processes during the winter, and ablation processes dominated during the summer, which could be explained by the low elevation range of Yala Glacier and precipitation from westerlies in the winter. Hence, this should be kept in mind when using the term 'summer accumulation glacier' for Yala Glacier. For future research in the HKH region, seasonal mass balances should be measured, and the processes impacting the mass balance and the role of winter precipitation should be investigated for other glaciers in the HKH region.

  8. Processes governing the mass balance of Chhota Shigri Glacier (Western Himalaya, India assessed by point-scale surface energy balance measurements

    Directory of Open Access Journals (Sweden)

    M. F. Azam

    2014-06-01

    Full Text Available Recent studies revealed that Himalayan glaciers have been shrinking at an accelerated rate since the beginning of the 21st century. However the climatic causes for this shrinkage remain unclear given that surface energy balance studies are almost nonexistent in this region. In this study, a point-scale surface energy balance analysis was performed using in-situ meteorological data from the ablation zone of Chhota Shigri Glacier over two separate periods (August 2012 to February 2013 and July to October 2013 in order to understand the response of mass balance to climate change. Energy balance numerical modeling provides quantification of the surface energy fluxes and identification of the factors affecting glacier mass balance. The computed ablation was validated by stake observations. During summer-monsoon period, net radiation was the primary component of the surface energy balance with 82% of the total heat flux which was complimented with turbulent sensible and latent heat fluxes with a share of 13% and 5%, respectively. A striking feature of energy balance is the positive turbulent latent heat flux, thus condensation or re-sublimation of moist air at the glacier surface takes place, during summer-monsoon period which is characterized by relatively high air temperature, high relative humidity and almost permanent melting surface. The impact of Indian summer monsoon on Chhota Shigri Glacier mass balance has also been assessed. This analysis demonstrates that the intensity of snowfall events during the summer-monsoon season plays a key role on surface albedo, in turn on melting, and thus is among the most important drivers controlling the annual mass balance of the glacier. Summer-monsoon air temperature, controlling the precipitation phase (rain vs. snow and thus albedo, counts, indirectly, also among the most important drivers for the glacier mass balance.

  9. Influence of Persistent Wind Scour on the Surface Mass Balance of Antarctica

    Science.gov (United States)

    Das, Indrani; Bell, Robin E.; Scambos, Ted A.; Wolovick, Michael; Creyts, Timothy T.; Studinger, Michael; Fearson, Nicholas; Nicolas, Julien P.; Lenaerts, Jan T. M.; vandenBroeke, Michiel R.

    2013-01-01

    Accurate quantification of surface snow accumulation over Antarctica is a key constraint for estimates of the Antarctic mass balance, as well as climatic interpretations of ice-core records. Over Antarctica, near-surface winds accelerate down relatively steep surface slopes, eroding and sublimating the snow. This wind scour results in numerous localized regions (Antarctica. The scour zones are persistent because they are controlled by bedrock topography. On the basis of our Dome A observations, we develop an empirical model to predict wind-scour zones across the Antarctic continent and find that these zones are predominantly located in East Antarctica. We estimate that approx. 2.7-6.6% of the surface area of Antarctica has persistent negative net accumulation due to wind scour, which suggests that, across the continent, the snow mass input is overestimated by 11-36.5 Gt /yr in present surface-mass-balance calculations.

  10. Development of the ECLSS Sizing Analysis Tool and ARS Mass Balance Model Using Microsoft Excel

    Science.gov (United States)

    McGlothlin, E. P.; Yeh, H. Y.; Lin, C. H.

    1999-01-01

    The development of a Microsoft Excel-compatible Environmental Control and Life Support System (ECLSS) sizing analysis "tool" for conceptual design of Mars human exploration missions makes it possible for a user to choose a certain technology in the corresponding subsystem. This tool estimates the mass, volume, and power requirements of every technology in a subsystem and the system as a whole. Furthermore, to verify that a design sized by the ECLSS Sizing Tool meets the mission requirements and integrates properly, mass balance models that solve for component throughputs of such ECLSS systems as the Water Recovery System (WRS) and Air Revitalization System (ARS) must be developed. The ARS Mass Balance Model will be discussed in this paper.

  11. Mass balance of Nef glacier (Patagonia) by means of laser altimetry

    Science.gov (United States)

    Lopez, P.; Casassa, G.; Wendt, J.; Wendt, A.; Delclaux, F.

    2009-04-01

    Glaciers of Southern Patagonia Icefield (SPI) and Northern Patagonia Icefield (NPI) have shown an enhanced wasting and an increased melting in recent decades, mainly in reaction to regional warming. In consequence, water resources originating from those glaciers are also affected by their negative mass balance. Mass balance measurements provide information about the mass changes of both the accumulation and the ablation zones. A main limitation in attempting estimations of glacier mass balance of the NPI (4,197 km²) and the SPI (13,000 km²) is the difficulty in performing field observations, particularly within the accumulation areas, largely because of unfavourable meteorological conditions as well as the limitations due to the large size of the icefields. There is thus a need for carrying out detailed analyses of individual representative glaciers in Patagonia, covering both the ablation and accumulation areas. The Nef Glacier (138 km² in February 2005), is one of the largest and most representative glaciers of the eastern side of the NPI. During the last century it has been retreating and losing mass, and its evolution has been similar to other large glaciers of the NPI. Moreover, the Nef River is one of the most important tributaries of the Baker River, the largest drainage basin in the region and the river with the highest discharge in Chile. In this paper we present results of mass balance (2008 - 2009) of Nef glacier estimated using the geodetic method, where Digital Elevation Models (DEMs) of the glacier constructed at different dates are compared. The DEMs have been constructed using data from airborne laser altimetry with CECS Airborne Laser Scanner (Wendt et al., 2008), which has the advantage over airborne photogrammetry that it involves less data processing and practically no ground control, yielding excellent sub-meter precision.

  12. Exploring uncertainty in glacier mass balance modelling with Monte Carlo simulation

    Directory of Open Access Journals (Sweden)

    H. Machguth

    2008-12-01

    Full Text Available By means of Monte Carlo simulations we calculated uncertainty in modelled cumulative mass balance over 400 days at one particular point on the tongue of Morteratsch Glacier, Switzerland, using a glacier energy balance model of intermediate complexity. Before uncertainty assessment, the model was tuned to observed mass balance for the investigated time period and its robustness was tested by comparing observed and modelled mass balance over 11 years, yielding very small deviations. Both systematic and random uncertainties are assigned to twelve input parameters and their respective values estimated from the literature or from available meteorological data sets. The calculated overall uncertainty in the model output is dominated by systematic errors and amounts to 0.7 m w.e. or approximately 10% of total melt over the investigated time span. In order to provide a first order estimate on variability in uncertainty depending on the quality of input data, we conducted a further experiment, calculating overall uncertainty for different levels of uncertainty in measured global radiation and air temperature. Our results show that the output of a well calibrated model is subject to considerable uncertainties, in particular when applied for extrapolation in time and space where systematic errors are likely to be an important issue.

  13. Gulkana Glacier, Alaska-Mass balance, meteorology, and water measurements, 1997-2001

    Science.gov (United States)

    March, Rod S.; O'Neel, Shad

    2011-01-01

    The measured winter snow, maximum winter snow, net, and annual balances for 1997-2001 in the Gulkana Glacier basin are determined at specific points and over the entire glacier area using the meteorological, hydrological, and glaciological data. We provide descriptions of glacier geometry to aid in estimation of conventional and reference surface mass balances and descriptions of ice motion to aid in the understanding of the glacier's response to its changing geometry. These data provide annual estimates for area altitude distribution, equilibrium line altitude, and accumulation area ratio during the study interval. New determinations of historical area altitude distributions are given for 1900 and annually from 1966 to 2001. As original weather instrumentation is nearing the end of its deployment lifespan, we provide new estimates of overlap comparisons and precipitation catch efficiency. During 1997-2001, Gulkana Glacier showed a continued and accelerated negative mass balance trend, especially below the equilibrium line altitude where thinning was pronounced. Ice motion also slowed, which combined with the negative mass balance, resulted in glacier retreat under a warming climate. Average annual runoff augmentation by glacier shrinkage for 1997-2001 was 25 percent compared to the previous average of 13 percent, in accordance with the measured glacier volume reductions.

  14. Exploring uncertainty in glacier mass balance modelling with Monte Carlo simulation

    Directory of Open Access Journals (Sweden)

    H. Machguth

    2008-06-01

    Full Text Available By means of Monte Carlo simulations we calculated uncertainty in modelled cumulative mass balance over 400 days at one particular point on the tongue of Morteratsch Glacier, Switzerland, using a glacier energy balance model of intermediate complexity. Before uncertainty assessment, the model was tuned to observed mass balance for the investigated time period and its robustness was tested by comparing observed and modelled mass balance over 11 years, yielding very small deviations. Both systematic and random uncertainties are assigned to twelve input parameters and their respective values estimated from the literature or from available meteorological data sets. The calculated overall uncertainty in the model output is dominated by systematic errors and amounts to 0.7 m w.e. or approximately 10% of total melt over the investigated time span. In order to provide a first order estimate on variability in uncertainty depending on the quality of input data, we conducted a further experiment, calculating overall uncertainty for different levels of uncertainty in measured global radiation and air temperature. Our results show that the output of a well calibrated model is subject to considerable uncertainties, in particular when applied for extrapolation in time and space where systematic errors are likely to be an important issue.

  15. Nonequilibrium Thermodynamic Formalism of Nonlinear Chemical Reaction Systems with Waage-Guldberg's Law of Mass Action

    CERN Document Server

    Ge, Hao

    2016-01-01

    Macroscopic entropy production $\\sigma^{(tot)}$ in the general nonlinear isothermal chemical reaction system with mass action kinetics is decomposed into a free energy dissipation and a house-keeping heat: $\\sigma^{(tot)}=\\sigma^{(fd)}+\\sigma^{(hk)}$; $\\sigma^{(fd)}=-\\rd A/\\rd t$, where $A$ is a generalized free enegy function. This yields a novel nonequilibrium free energy balance equation $\\rd A/\\rd t=-\\sigma^{(tot)}+\\sigma^{(hk)}$, which is on a par with celebrated entropy balance equation $\\rd S/\\rd t=\\sigma^{(tot)}+\\eta^{(ex)}$ where $\\eta^{(ex)}$ is the rate of entropy exchange with the environment.For kinetic system with complex balance,$\\sigma^{(fd)},\\sigma^{(hk)}\\ge 0$: $\\sigma^{(fd)}$ characterizes the irreversibility of a transient relaxation kinetics; while $\\sigma^{(hk)}$ is positive even in a steady state, representing irreversibility in open,driven chemical systems with a chemostat.For kinetic system withoutcomplex balance, negative $\\sigma^{(fd)}$ is a necessary condition for multistability, w...

  16. The spatial and temporal variability of the surface mass balance in Antarctica: results from a regional climate model

    NARCIS (Netherlands)

    Lipzig, N.P.M. van; Meijgaard, E. van; Oerlemans, J.

    2002-01-01

    A 14 year integration with a regional atmospheric model (RACMO) is used to obtain detailed information on the Antarctic surface mass balance and to understand the mechanisms that are responsible for the spatial and temporal distribution of the surface mass balance. The model (Δx = 55 km) uses the pa

  17. Mass Balance Model for Sustainable Phosphorus Recovery in a US Wastewater Treatment Plant.

    Science.gov (United States)

    Venkatesan, Arjun K; Hamdan, Abdul-Hakeem M; Chavez, Vanessa M; Brown, Jasmine D; Halden, Rolf U

    2016-01-01

    In response to limited phosphorus (P) reserves worldwide, several countries have demonstrated the prospect of recovering significant amounts of P from wastewater treatment plants (WWTPs). This technique uses enhanced biological P removal (EBPR) to concentrate P in sludge followed by chemical precipitation of P as struvite, a usable phosphate mineral. The present study models the feasibility of this enhanced removal and recovery technique in a WWTP in Arizona with design parameters typical of infrastructure in the United States. A mass balance was performed for existing treatment processes and modifications proposed to estimate the quantity of P that could be recovered under current and future flow conditions. Modeling results show that about 71 to 96% of the P being lost potentially could be recovered as struvite. About 491 ± 64 t yr of struvite may be recovered after process modification, which corresponds to $150,000 ± $20,000 yr in P sales to fertilizer industries. The process was projected to be economically feasible, with a payback period of 45 ± 30 yr in the studied WWTP and a much shorter duration of 3 ± 1 yr for WWTPs already using an EBPR process. Furthermore, modeling results suggest that P recovery can improve the quality of biosolids by favorably reducing the P:N ratio. Implementation of this strategy at US WWTPs may increase national security by reducing dependence of limited P resources. Considering all aspects of the recovery process with respect to environmental, economic, and social implications, the examined technique is concluded to represent a cost-attractive and sustainable method for P management in US WWTPs.

  18. Simulation and reconstruction of parameters of streamflow and glacier mass balance in the Northern Caucasus

    Directory of Open Access Journals (Sweden)

    V. G. Konovalov

    2014-01-01

    Full Text Available The work was aimed at numerical modeling of spatial-temporal variability of the river Terek seasonal (April to September streamflow characteristics and long-term fluctuations of components of annual glacier mass balances in this basin and on the adjacent territories. Mass balance of glaciers Djankuat and Garabashi was calculated. Simulation was performed by means of stochastic modeling and discrete data presenting fields of main meteorological parameters (precipitation, air temperature and humidity having effect on the streamflow. Realization of this approach is complicated by the fact that spatial representativeness of hydrological and meteorological sites are not corresponding one to another. Data on the runoff is clearly related to the total drainage area closed by a gauging station. And for this data we study a relationship with meteorological parameters which are measured at a non-regular observational network whose spatial representativeness is unknown. These stations are generally located beyond the area under investigation (Fig. 2. Similar problem exists when we analyze a relationship between components of the mass balance of individual glaciers (Djankuat and Garabashi and the above climate characteristics measured at some stations located on the whole Caucasus territory. The same takes place when long-term indices of width and density of tree annual rings obtained in upper reaches of the river Kuban’ are used for analysis of variations of the runoff and the glacier mass balance in the river Terek basin located at a distance of 100-150 km from the Kuban’ dendrologic sites.To solve the problem we used a wide number of factors which directly (various information about the climate or indirectly (indices of the climate dryness, wood ring characteristics characterize conditions of formation of annual and seasonal river runoff and components of glacier mass balance in the North Caucasus. Use of all obtained information made possible the

  19. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Yanqing; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán; Wright, Heather M.; Vazquez, Jorge A.

    2016-01-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous “excess sulfur” problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the “petrologic estimate”), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of

  20. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Y.; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán.; Wright, Heather; Vazquez, Jorge

    2016-08-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous "excess sulfur" problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the "petrologic estimate"), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of vapor

  1. 3D viscosity maps for Greenland and effect on GRACE mass balance estimates

    Science.gov (United States)

    van der Wal, Wouter; Xu, Zheng

    2016-04-01

    The GRACE satellite mission measures mass loss of the Greenland ice sheet. To correct for glacial isostatic adjustment numerical models are used. Although generally found to be a small signal, the full range of possible GIA models has not been explored yet. In particular, low viscosities due to a wet mantle and high temperatures due to the nearby Iceland hotspot could have a significant effect on GIA gravity rates. The goal of this study is to present a range of possible viscosity maps, and investigate the effect on GRACE mass balance estimates. Viscosity is derived using flow laws for olivine. Mantle temperature is computed from global seismology models, based on temperature derivatives for different mantle compositions. An indication for grain sizes is obtained by xenolith findings at a few locations. We also investigate the weakening effect of the presence of melt. To calculate gravity rates, we use a finite-element GIA model with the 3D viscosity maps and the ICE-5G loading history. GRACE mass balances for mascons in Greenland are derived with a least-squares inversion, using separate constraints for the inland and coastal areas in Greenland. Biases in the least-squares inversion are corrected using scale factors estimated from a simulation based on a surface mass balance model (Xu et al., submitted to The Cryosphere). Model results show enhanced gravity rates in the west and south of Greenland with 3D viscosity maps, compared to GIA models with 1D viscosity. The effect on regional mass balance is up to 5 Gt/year. Regional low viscosity can make present-day gravity rates sensitivity to ice thickness changes in the last decades. Therefore, an improved ice loading history for these time scales is needed.

  2. Ocean Basalt Simulator version 1 (OBS1): Trace element mass balance in adiabatic melting of a pyroxenite-bearing peridotite

    Science.gov (United States)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2015-01-01

    present a new numerical trace element mass balance model for adiabatic melting of a pyroxenite-bearing peridotite for estimating mantle potential temperature, depth of melting column, and pyroxenite fraction in the source mantle for a primary ocean basalt/picrite. The Ocean Basalt Simulator version 1 (OBS1) uses a thermodynamic model of adiabatic melting of a pyroxenite-bearing peridotite with experimentally/thermodynamically parameterized liquidus-solidus intervals and source mineralogy. OBS1 can be used to calculate a sequence of adiabatic melting with two melting models, including (1) melting of peridotite and pyroxenite sources with simple mixing of their fractional melts (melt-melt mixing model), and (2) pyroxenite melting, melt metasomatism in the host peridotite, and melting of the metasomatized peridotite (source-metasomatism model). OBS1 can be used to explore (1) the fractions of peridotite and pyroxenite, (2) mantle potential temperature, (3) pressure of termination of melting, (4) degree of melting, and (5) residual mode of the sources. In order to constrain these parameters, the model calculates a mass balance for 26 incompatible trace elements in the sources and in the generated basalt/picrite. OBS1 is coded in an Excel spreadsheet and runs with VBA macros. Using OBS1, we examine the source compositions and conditions of the mid-oceanic ridge basalts, Loihi-Koolau basalts in the Hawaiian hot spot, and Jurassic Shatsky Rise and Mikabu oceanic plateau basalts and picrites. The OBS1 model shows the physical conditions, chemical mass balance, and amount of pyroxenite in the source peridotite, which are keys to global mantle recycling.

  3. kLa determination: comparative study for a gas mass balance method.

    Science.gov (United States)

    Poughon, L; Duchez, D; Cornet, J F; Dussap, C G

    2003-07-01

    The determination of k(L) a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and fixed-bed column reactors) with a gassing-in and with a classical chemical sulphite oxidation method. The mathematical relations required for the determination of the k(L) a value are detailed. In coalescing gas-liquid conditions, the values calculated by the three methods are shown to be comparable. The gas balance method is more rapid than either the steady-state gassing-in or the chemical sulphite reaction rate measurement methods. It is also well adapted for three-phase systems (gas-liquid-solid) in which the non-coalescing effects of sulphite solution are reduced by solid interferences.

  4. Marketing research in positioning and launching of yoghurt with a balanced chemical composition

    Directory of Open Access Journals (Sweden)

    M. Mardar

    2016-12-01

    Full Text Available Annotation. This article presents the analysis of marketing environment of the enterprises that produce yogurt products in Ukraine. In order to carry out a deeper analysis of the marketing environment of the new yoghurt drinks with a balanced composition of the major nutrients in food and increased probiotic properties, PEST and SWOT-analyses were conducted, they identified environmental factors that have favorable and adverse effects as well as internal strengths and weaknesses of the new product. Based on the results of marketing research of consumer preferences, the core audience of new yoghurt drink with a balanced chemical composition and the elevated concentration of Bifidobacteria were defined. The received results led to justification of the expediency of elaboration of new yoghurt drinks with probiotic properties and balanced composition of basic food nutrients as well as to formulation of a strategy of new product promotion on the consumer market of Ukraine.

  5. 20 years of mass balances on the Piloto glacier, Las Cuevas river basin, Mendoza, Argentina

    Science.gov (United States)

    Leiva, J. C.; Cabrera, G. A.; Lenzano, L. E.

    2007-10-01

    Climatic changes of the 20th century have altered the water cycle in the Andean basins of central Argentina. The most visible change is seen in the mountain glaciers, with loss of part of their mass due to decreasing thickness and a substantial recession in the last 100 years. This paper briefly describes the results of glacier mass balance research since 1979 in the Piloto Glacier at the Cajón del Rubio, in the headwaters of Las Cuevas River, presenting new results for the period 1997-2003. Very large interannual variability of net annual specific balance is evident, due largely to variations in winter snow accumulation, with a maximum net annual value of + 151 cm w.e. and a minimum value of - 230 cm w.e. Wet El Niño years are normally associated with positive net annual balances, while dry La Niña years generally result in negative balances. Within the 24-year period, 67% of the years show negative net annual specific balances, with a cumulative mass balance loss of - 10.50 m water equivalent (w.e.). Except for exceptions normally related to El Niño events, a general decreasing trend of winter snow accumulation is evident in the record, particularly after 1992, which has a strong effect in the overall negative mass balance values. The glacier contribution to Las Cuevas River runoff is analysed based on the Punta de Vacas River gauge station for a hypothetical year without snow precipitation (YWSP), when the snowmelt component is zero. Extremely dry years similar to a YWSP have occurred in 1968-1969, 1969-1970 and 1996-1997. The Punta de Vacas gauge station is located 62 km downstream from Piloto Glacier, and the basin contains 3.0% of uncovered glacier ice and 3.7% of debris-covered ice. The total glacier contribution to Las Cuevas River discharge is calculated as 82 ± 8% during extremely dry years. If glacier wastage continues at the present trend as observed during the last 2 decades, it will severely affect the water resources in the arid central Andes of

  6. Reconstructing glacier mass balances in the Central Andes of Chile and Argentina using local and regional hydro-climatic data

    Directory of Open Access Journals (Sweden)

    M. H. Masiokas

    2015-09-01

    Full Text Available Despite the great number and variety of glaciers in southern South America, in situ glacier mass balance records are extremely scarce and glacier–climate relationships are still poorly understood in this region. Here we use the longest (> 35 years and most complete in situ mass balance record, available for glaciar Echaurren Norte in the Andes at ~34° S, to develop a minimal glacier surface mass balance model that relies on nearby monthly precipitation and air temperature data as forcing. This basic model is able to explain 78 % of the variance in the annual glacier mass balance record over the 1978–2013 calibration period. An attribution assessment indicates that precipitation variability constitutes the most important forcing modulating annual glacier mass balances at this site. A regionally-averaged series of mean annual streamflow records from both sides of the Andes is then used to estimate, through simple linear regression, this glacier's annual mass balance variations since 1909. The reconstruction model captures 68 % of the observed glacier mass balance variability and shows three periods of sustained positive mass balances embedded in an overall negative trend totaling almost −42 m w.eq. over the past 105 years. The three periods of sustained positive mass balances (centered in the 1920s–1930s, in the 1980s and in the first decade of the 21st century coincide with several documented glacier advances in this region. Similar trends observed in other shorter glacier mass balance series suggest the glaciar Echaurren Norte reconstruction is representative of larger-scale conditions and could be useful for more detailed glaciological, hydrological and climatological assessments in this portion of the Andes.

  7. Twenty-one years of mass balance observations along the K-transect, West Greenland

    Directory of Open Access Journals (Sweden)

    R. S. W. van de Wal

    2012-08-01

    Full Text Available A 21-yr record is presented of surface mass balance measurements along the K-transect. The series covers the period 1990–2011. Data are available at eight sites along a transect over an altitude range of 380–1850 m at approximately 67° N in West Greenland. The surface mass balance gradient is on average 3.8 × 10−3 m w.e. m−1, and the mean equilibrium line altitude is 1553 m a.s.l. Only the lower three sites within 10 km of the margin up to an elevation of 700 m experience a significant increasing trend in the ablation over the entire period. Data are available at: doi:10.1594/PANGAEA.779181.

  8. Twenty-one years of mass balance observations along the K-transect, West Greenland

    Directory of Open Access Journals (Sweden)

    R. S. W. van de Wal

    2012-05-01

    Full Text Available A 21-yr record is presented of surface mass balance measurements along the K-transect. The series covers the period 1990–2011. Data are available at 8 sites along a transect over an altitude range of 390–1850 m at approximately 67° N in West Greenland. The surface mass balance gradient is on average 3.8 × 10−3 m w.e. m−1, and the mean equilibrium line altitude is 1553 m a.s.l. Only the lower 3 sites within 10 km of the margin experience a significant increasing trend in the ablation over the entire period. Data are available at: http://doi.pangaea.de/10.1594/PANGAEA.779181.

  9. A Coupled Chemical and Mass Transport Model for Concrete Durability

    DEFF Research Database (Denmark)

    Jensen, Mads Mønster; Johannesson, Björn; Geiker, Mette Rica

    2012-01-01

    curves which is established from a set of mathematical criteria. The chemical degradation is modelled with the geochemical code iphreeqc, which provides a general tool for evaluating different paste compositions. The governing system of equations is solved by the finite element method with a Newton......-Raphson iteration scheme arising from the non-linearity. The overall model is a transient problem, solved using a single parameter formulation. The sorption hysteresis and chemical equilibrium is included as source or sink terms. The advantages with this formulation is that each node in the discrete system has......In this paper a general continuum theory is used to evaluate the service life of cement based materials, in terms of mass transport processes and chemical degradation of the solid matrix. The model established is a reactive mass transport model, based on an extended version of the Poisson...

  10. Quantification of colloidal and aqueous element transfer in soils: The dual-phase mass balance model

    Science.gov (United States)

    Bern, Carleton R.; Thompson, Aaron; Chadwick, Oliver A.

    2015-01-01

    Mass balance models have become standard tools for characterizing element gains and losses and volumetric change during weathering and soil development. However, they rely on the assumption of complete immobility for an index element such as Ti or Zr. Here we describe a dual-phase mass balance model that eliminates the need for an assumption of immobility and in the process quantifies the contribution of aqueous versus colloidal element transfer. In the model, the high field strength elements Ti and Zr are assumed to be mobile only as suspended solids (colloids) and can therefore be used to distinguish elemental redistribution via colloids from redistribution via dissolved aqueous solutes. Calculations are based upon element concentrations in soil, parent material, and colloids dispersed from soil in the laboratory. We illustrate the utility of this model using a catena in South Africa. Traditional mass balance models systematically distort elemental gains and losses and changes in soil volume in this catena due to significant redistribution of Zr-bearing colloids. Applying the dual-phase model accounts for this colloidal redistribution and we find that the process accounts for a substantial portion of the major element (e.g., Al, Fe and Si) loss from eluvial soil. In addition, we find that in illuvial soils along this catena, gains of colloidal material significantly offset aqueous elemental loss. In other settings, processes such as accumulation of exogenous dust can mimic the geochemical effects of colloid redistribution and we suggest strategies for distinguishing between the two. The movement of clays and colloidal material is a major process in weathering and pedogenesis; the mass balance model presented here is a tool for quantifying effects of that process over time scales of soil development.

  11. Base flow separation: A comparison of analytical and mass balance methods

    Science.gov (United States)

    Lott, Darline A.; Stewart, Mark T.

    2016-04-01

    Base flow is the ground water contribution to stream flow. Many activities, such as water resource management, calibrating hydrological and climate models, and studies of basin hydrology, require good estimates of base flow. The base flow component of stream flow is usually determined by separating a stream hydrograph into two components, base flow and runoff. Analytical methods, mathematical functions or algorithms used to calculate base flow directly from discharge, are the most widely used base flow separation methods and are often used without calibration to basin or gage-specific parameters other than basin area. In this study, six analytical methods are compared to a mass balance method, the conductivity mass-balance (CMB) method. The base flow index (BFI) values for 35 stream gages are obtained from each of the seven methods with each gage having at least two consecutive years of specific conductance data and 30 years of continuous discharge data. BFI is cumulative base flow divided by cumulative total discharge over the period of record of analysis. The BFI value is dimensionless, and always varies from 0 to 1. Areas of basins used in this study range from 27 km2 to 68,117 km2. BFI was first determined for the uncalibrated analytical methods. The parameters of each analytical method were then calibrated to produce BFI values as close to the CMB derived BFI values as possible. One of the methods, the power function (aQb + cQ) method, is inherently calibrated and was not recalibrated. The uncalibrated analytical methods have an average correlation coefficient of 0.43 when compared to CMB-derived values, and an average correlation coefficient of 0.93 when calibrated with the CMB method. Once calibrated, the analytical methods can closely reproduce the base flow values of a mass balance method. Therefore, it is recommended that analytical methods be calibrated against tracer or mass balance methods.

  12. Relative appendicular skeletal muscle mass is associated with isokinetic muscle strength and balance in healthy collegiate men.

    Science.gov (United States)

    Kim, Sung-Eun; Hong, Ju; Cha, Jun-Youl; Park, Jung-Min; Eun, Denny; Yoo, Jaehyun; Jee, Yong-Seok

    2016-11-01

    There are few studies on the relationship between skeletal muscle mass and balance in the young ages. We investigated the relationship between appendicular skeletal muscle mass, isokinetic muscle strength of lower extremity, and balance among healthy young men using relative skeletal muscle index. Thirty men were grouped according to relative appendicular skeletal muscle mass index: higher skeletal muscle group (n = 15) and lower skeletal muscle group (n = 15). Static and dynamic balance abilities were measured using the following: a test where participants stood on one leg with eyes closed, a modified Clinical Test of Sensory Interaction on Balance (mCTSIB) with eyes open and eyes closed, a stability test, and limits of stability test. The muscle strength of lower extremities was measured with an isokinetic analyser in hip, knee, and ankle joints. Participants with higher appendicular skeletal muscle mass were significantly more stable in maintaining dynamic balance than those with lower appendicular skeletal muscle mass. Moreover, appendicular skeletal muscle mass index was positively correlated with dynamic balance ability. Participants with higher appendicular skeletal muscle mass had stronger strength in the lower extremity, and there were significant differences in the isokinetic torque ratios between groups. From these results, it can be inferred that higher appendicular skeletal muscle mass relates to muscle strength and the alteration in the peak torque ratio of the lower extremity, contributing to the maintenance of balance.

  13. A Range Correction for Icesat and Its Potential Impact on Ice-sheet Mass Balance Studies

    Science.gov (United States)

    Borsa, A. A.; Moholdt, G.; Fricker, H. A.; Brunt, Kelly M.

    2014-01-01

    We report on a previously undocumented range error in NASA's Ice, Cloud and land Elevation Satellite (ICESat) that degrades elevation precision and introduces a small but significant elevation trend over the ICESat mission period. This range error (the Gaussian-Centroid or 'G-C'offset) varies on a shot-to-shot basis and exhibits increasing scatter when laser transmit energies fall below 20 mJ. Although the G-C offset is uncorrelated over periods less than1 day, it evolves over the life of each of ICESat's three lasers in a series of ramps and jumps that give rise to spurious elevation trends of -0.92 to -1.90 cm yr(exp -1), depending on the time period considered. Using ICESat data over the Ross and Filchner-Ronne ice shelves we show that (1) the G-C offset introduces significant biases in ice-shelf mass balance estimates, and (2) the mass balance bias can vary between regions because of different temporal samplings of ICESat.We can reproduce the effect of the G-C offset over these two ice shelves by fitting trends to sample-weighted mean G-C offsets for each campaign, suggesting that it may not be necessary to fully repeat earlier ICESat studies to determine the impact of the G-C offset on ice-sheet mass balance estimates.

  14. The footprint of Asian monsoon dynamics in the mass and energy balance of a Tibetan glacier

    Science.gov (United States)

    Mölg, T.; Maussion, F.; Yang, W.; Scherer, D.

    2012-12-01

    Determinations of glacier-wide mass and energy balance are still scarce for the remote mountains of the Tibetan Plateau, where field measurements are challenging. Here we run and evaluate a physical, distributed mass balance model for Zhadang Glacier (central Tibet, 30° N) based on in-situ measurements over 2009-2011 and an uncertainty estimate by Monte Carlo and ensemble strategies. The model application aims to provide the first quantification of how the Indian Summer Monsoon (ISM) impacts an entire glacier over the various stages of the monsoon's annual cycle. We find a strong and systematic ISM footprint on the interannual scale. Early (late) monsoon onset causes higher (lower) accumulation, and reduces (increases) the available energy for ablation primarily through changes in absorbed shortwave radiation. By contrast, only a weak footprint exists in the ISM cessation phase. Most striking though is the core monsoon season: local mass and energy balance variability is fully decoupled from the active/break cycle that defines large-scale atmospheric variability during the ISM. Our results demonstrate quantitatively that monsoon onset strongly affects the ablation season of glaciers in Tibet. However, we find no direct ISM impact on the glacier in the main monsoon season, which has not been acknowledged so far. This result also adds cryospheric evidence that, once the monsoon is in full swing, regional atmospheric variability prevails on the Tibetan Plateau in summer.

  15. Estimating riverine discharge of nitrogen from the South Korea by the mass balance approach.

    Science.gov (United States)

    Kim, Taehoon; Kim, Geonha; Kim, Sungwon; Choi, Euiso

    2008-01-01

    The main objective of this research was to estimate the total mass of nitrogen discharged from various sources in Korea using the mass balance approach. Three different nitrogen mass balances were presented: (1) agricultural activities including raising crops and animal husbandry; (2) domestic activities, and (3) activities in forest and urban areas. These nitrogen balances were combined to estimate riverine discharge of nitrogen to the ocean in national scale. Nitrogen inputs include atmospheric deposition, biological nitrogen fixation, application of inorganic fertilizers/manures, animal feed/imported foodstuffs, and meat/fish. Nitrogen outputs include ammonia volatilization, denitrification, human/animal waste generation, crop/meat production, and riverine discharge to the ocean. The estimated total nitrogen input in Korea was 1,194.5 x 10(3) tons N/year. Nitrogen discharged into rivers was estimated as 408-422 x 10(3) tons N/year, of which 66-71% was diffuse in origin. The estimated diffuse discharges for land uses were estimated as 82 x 10(3) tons N/year from agricultural areas, 7 x 10(3) tons N/year from forestry and 75 x 10(3) tons N/year from urban and industrial areas.

  16. The footprint of Asian monsoon dynamics in the mass and energy balance of a Tibetan glacier

    Directory of Open Access Journals (Sweden)

    T. Mölg

    2012-08-01

    Full Text Available Determinations of glacier-wide mass and energy balance are still scarce for the remote mountains of the Tibetan Plateau, where field measurements are challenging. Here we run and evaluate a physical, distributed mass balance model for Zhadang glacier (central Tibet, 30° N, based on in-situ measurements over 2009–2011 and an uncertainty estimate by Monte Carlo and ensemble strategies. The model application aims to provide the first quantification of how the Indian Summer Monsoon (ISM impacts an entire glacier over the various stages of the monsoon's annual cycle. We find a strong and systematic ISM footprint on the interannual scale. Early (late monsoon onset causes higher (lower accumulation, and reduces (increases the available energy for ablation primarily through changes in absorbed shortwave radiation. By contrast, only a weak footprint exists in the ISM cessation phase. Most striking though is the core monsoon season: local mass and energy balance variability is fully decoupled from the active/break cycle that defines large-scale atmospheric variability during the ISM. Our results demonstrate quantitatively that monsoon onset strongly affects the ablation season of glaciers in Tibet. However, we find no direct ISM impact on the glacier in the main monsoon season, which has not been acknowledged so far. This result also adds cryospheric evidence that regional modification of the large-scale monsoon flow prevails on the Tibetan Plateau in summer.

  17. The footprint of Asian monsoon dynamics in the mass and energy balance of a Tibetan glacier

    Directory of Open Access Journals (Sweden)

    T. Mölg

    2012-12-01

    Full Text Available Determinations of glacier-wide mass and energy balance are still scarce for the remote mountains of the Tibetan Plateau, where field measurements are challenging. Here we run and evaluate a physical, distributed mass balance model for Zhadang Glacier (central Tibet, 30° N based on in-situ measurements over 2009–2011 and an uncertainty estimate by Monte Carlo and ensemble strategies. The model application aims to provide the first quantification of how the Indian Summer Monsoon (ISM impacts an entire glacier over the various stages of the monsoon's annual cycle. We find a strong and systematic ISM footprint on the interannual scale. Early (late monsoon onset causes higher (lower accumulation, and reduces (increases the available energy for ablation primarily through changes in absorbed shortwave radiation. By contrast, only a weak footprint exists in the ISM cessation phase. Most striking though is the core monsoon season: local mass and energy balance variability is fully decoupled from the active/break cycle that defines large-scale atmospheric variability during the ISM. Our results demonstrate quantitatively that monsoon onset strongly affects the ablation season of glaciers in Tibet. However, we find no direct ISM impact on the glacier in the main monsoon season, which has not been acknowledged so far. This result also adds cryospheric evidence that, once the monsoon is in full swing, regional atmospheric variability prevails on the Tibetan Plateau in summer.

  18. Long term mass balance of the Helheim and Kangerdlugssuaq glaciers in

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Fitzner, Antje; Kjær, Kurt;

    2013-01-01

    Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve the projec......Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve...... the projection of future sea level rise, a long-term data record that reveals the mass balance between episodic events is required. Here, we extend the observational record of marginal thinning of Helheim glacier (HG) and Kangerdlugssuaq glacier (KG) from 7 to 30 years. Our measurements reveal that, although...... in air temperature suggest that both outlet glaciers respond immediately to small fluctuations in both the SST and air temperature. Furthermore, we compare our observations of ice flow speed and elevation changes with predictions based on the The Parallel Ice Sheet Model (PISM) software....

  19. Micrometeorological Mass Balance Measurements of Greenhouse Gas Emissions from Composting Green-waste

    Science.gov (United States)

    Kent, E. R.; Bailey, S.; Stephens, J.; Horwath, W. R.; Paw U, K.

    2013-12-01

    Managed decomposition of organic materials is increasingly being used as an alternative waste management option and the resulting compost can be used as a fertilizer and soil amendment in home gardens and agriculture. An additional benefit is the avoidance of methane emissions associated with anaerobic decomposition in landfills. Greenhouse gases are still emitted during the composting process, but few studies have measured emissions from a full-scale windrow of composting green-waste. This study uses a micrometeorological mass balance technique (upwind and downwind vertical profile measurements of trace gas concentrations and wind velocity) to calculate emissions of carbon dioxide, methane, and nitrous oxide from a pile of composting green-waste during the dry season in Northern California. The expected source pattern was observed in measured upwind-downwind concentration differences of all three gases averaged over the study period despite substantial noise seen in the half-hourly emission calculations. Sources of uncertainty are investigated and temporal patterns analyzed. An in-situ zero-source test was conducted to examine the mass balance technique when the source of emissions was removed. Results from the micrometeorological mass balance measurements are compared with measurements taken using the more common open chamber technique.

  20. Large-scale subduction of continental crust implied by India-Asia mass-balance calculation

    Science.gov (United States)

    Ingalls, Miquela; Rowley, David B.; Currie, Brian; Colman, Albert S.

    2016-11-01

    Continental crust is buoyant compared with its oceanic counterpart and resists subduction into the mantle. When two continents collide, the mass balance for the continental crust is therefore assumed to be maintained. Here we use estimates of pre-collisional crustal thickness and convergence history derived from plate kinematic models to calculate the crustal mass balance in the India-Asia collisional system. Using the current best estimates for the timing of the diachronous onset of collision between India and Eurasia, we find that about 50% of the pre-collisional continental crustal mass cannot be accounted for in the crustal reservoir preserved at Earth's surface today--represented by the mass preserved in the thickened crust that makes up the Himalaya, Tibet and much of adjacent Asia, as well as southeast Asian tectonic escape and exported eroded sediments. This implies large-scale subduction of continental crust during the collision, with a mass equivalent to about 15% of the total oceanic crustal subduction flux since 56 million years ago. We suggest that similar contamination of the mantle by direct input of radiogenic continental crustal materials during past continent-continent collisions is reflected in some ocean crust and ocean island basalt geochemistry. The subduction of continental crust may therefore contribute significantly to the evolution of mantle geochemistry.

  1. Recent mass balance of Arctic glaciers derived from repeat-track ICESat altimetry (Invited)

    Science.gov (United States)

    Moholdt, G.; Nuth, C.; Hagen, J. M.; Wolken, G. J.; Gardner, A.

    2010-12-01

    thickness and density make it difficult to convert these volume changes into mass balances, so we apply several different density assumptions to assess the range of possible mass balances in each region. The results show a negative mass balance over most of the Arctic, with the largest losses occurring in the Canadian Arctic, especially during the last 3 years. This is in good agreement with coincident mass balance estimates from field measurements and surface mass balance modelling using meteorological reanalysis data.

  2. Calculating carbon mass balance from unsaturated soil columns treated with CaSO₄₋minerals: test of soil carbon sequestration.

    Science.gov (United States)

    Han, Young-Soo; Tokunaga, Tetsu K

    2014-12-01

    Renewed interest in managing C balance in soils is motivated by increasing atmospheric concentrations of CO2 and consequent climate change. Here, experiments were conducted in soil columns to determine C mass balances with and without addition of CaSO4-minerals (anhydrite and gypsum), which were hypothesized to promote soil organic carbon (SOC) retention and soil inorganic carbon (SIC) precipitation as calcite under slightly alkaline conditions. Changes in C contents in three phases (gas, liquid and solid) were measured in unsaturated soil columns tested for one year and comprehensive C mass balances were determined. The tested soil columns had no C inputs, and only C utilization by microbial activity and C transformations were assumed in the C chemistry. The measurements showed that changes in C inventories occurred through two processes, SOC loss and SIC gain. However, the measured SOC losses in the treated columns were lower than their corresponding control columns, indicating that the amendments promoted SOC retention. The SOC losses resulted mostly from microbial respiration and loss of CO2 to the atmosphere rather than from chemical leaching. Microbial oxidation of SOC appears to have been suppressed by increased Ca(2+) and SO4(2)(-) from dissolution of CaSO4 minerals. For the conditions tested, SIC accumulation per m(2) soil area under CaSO4-treatment ranged from 130 to 260 g C m(-1) infiltrated water (20-120 g C m(-1) infiltrated water as net C benefit). These results demonstrate the potential for increasing C sequestration in slightly alkaline soils via CaSO4-treatment.

  3. Quantification of Submarine Groundwater Discharge Using a Radon (222-Rn) Mass Balance and Hydrogeological Modelling

    Science.gov (United States)

    Petermann, Eric; Stollberg, Reiner; Scholten, Jan; Knöller, Kay; Schubert, Michael

    2016-04-01

    Apart from river and surface water runoff subsurface discharge of groundwater plays a key role in coastal water and matter budgets. Two major forms of submarine groundwater discharge (SGD) can be distinguished: (i) pure freshwater discharge from continental aquifers that are connected to the coastal sea driven by a positive hydraulic gradient (fresh SGD) and (ii) re-circulation of seawater that has penetrated permeable coastal sediments (re-circulated SGD), e.g. driven by tidal pumping. The localization of SGD zones and the quantification of SGD fluxes is of high interest for coastal water management due to potential threats related to SGD, namely (i) the detrimental impact of discharging nutrient- or contaminant-laden groundwater on coastal seawater quality, an aspect that is of relevance along coastlines which are impacted by agriculture, industry or intense urbanization, and (ii) the loss of freshwater to the ocean, an issue that is of major relevance in all coastal areas with (seasonally) limited freshwater availability. In this work, we discuss estimates for the total (fresh + re-circulated) SGD fluxes derived from a mass balance of the radioactive noble gas radon (222-Rn) with estimates of fresh SGD fluxes derived by hydrogeological modelling. The precision of the mass balance results depends on the adequate determination of the mass balance source and sink terms. These terms are calculated based on field observations of environmental tracers (salinity, δ18O, 222-Rn, 223-Ra, 224-Ra, 226-Ra) in seawater and porewater, as well as on meteorological data. The numerical hydrogeological model estimates groundwater flow based on groundwater monitoring data, river flow data, groundwater recharge estimates, tidal dynamics, and density effects along the freshwater/seawater interface. We compare these two independent methodological approaches of SGD flux estimation, discuss results regarding their relevance for the regional water balance and reason the implications of

  4. On the interest of positive degree day models for mass balance modeling in the inner tropics

    Directory of Open Access Journals (Sweden)

    L. Maisincho

    2014-05-01

    Full Text Available A positive degree-day (PDD model was tested on Antizana Glacier 15α (0.28 km2; 0°28' S, 78°09' W to assess to what extent this approach is suitable for studying glacier mass balance in the inner tropics. Cumulative positive temperatures were compared with field measurements of melting amount and with surface energy balance computations. A significant link was revealed when a distinction was made between the snow and ice comprising the glacier surface. Significant correlations allowed degree-day factors to be retrieved for snow, and clean and dirty ice. The relationship between melt amount and temperature was mainly explained by the role of net shortwave radiation in both melting and in the variations in the temperature of the surface layer. However, this relationship disappeared from June to October (Period 1, because high wind speeds and low humidity cause highly negative turbulent latent heat fluxes. However, this had little impact on the computed total amount of melting at the annual time scale because temperatures are low and melting is generally limited during Period 1. At the daily time scale, melting starts when daily temperature means are still negative, because around noon incoming shortwave radiation is very high, and compensates for energy losses when the air is cold. The PDD model was applied to the 2000–2008 period using meteorological inputs measured on the glacier foreland. Results were compared to the glacier-wide mass balances measured in the field and were good, even though the melting factor should be adapted to the glacier surface state and may vary with time. Finally, the model was forced with precipitation and temperature data from the remote Izobamba station and NCEP-NCAR reanalysis data, also giving good results and showing that temperature variations are homogenous at the regional scale, meaning glacier mass balances can be modelled over large areas.

  5. The mid-cretaceous water bearer: Isotope mass balance quantification of the Albian hydrologic cycle

    Science.gov (United States)

    Ufnar, David F.; Gonzalez, Luis A.; Ludvigson, Greg A.; Brenner, Richard L.; Witzke, B.J.

    2002-01-01

    A latitudinal gradient in meteoric ??18O compositions compiled from paleosol sphaerosiderites throughout the Cretaceous Western Interior Basin (KWIB) (34-75??N paleolatitude) exhibits a steeper, more depleted trend than modern (predicted) values (3.0??? [34??N latitude] to 9.7??? [75??N] lighter). Furthermore, the sphaerosiderite meteoric ??18O latitudinal gradient is significantly steeper and more depleted (5.8??? [34??N] to 13.8??? [75??N] lighter) than a predicted gradient for the warm mid-Cretaceous using modern empirical temperature-??18O precipitation relationships. We have suggested that the steeper and more depleted (relative to the modern theoretical gradient) meteoric sphaerosiderite ??18O latitudinal gradient resulted from increased air mass rainout effects in coastal areas of the KWIB during the mid-Cretaceous. The sphaerosiderite isotopic data have been used to constrain a mass balance model of the hydrologic cycle in the northern hemisphere and to quantify precipitation rates of the equable 'greenhouse' Albian Stage in the KWIB. The mass balance model tracks the evolving isotopic composition of an air mass and its precipitation, and is driven by latitudinal temperature gradients. Our simulations indicate that significant increases in Albian precipitation (34-52%) and evaporation fluxes (76-96%) are required to reproduce the difference between modern and Albian meteoric siderite ??18O latitudinal gradients. Calculations of precipitation rates from model outputs suggest mid-high latitude precipitation rates greatly exceeded modern rates (156-220% greater in mid latitudes [2600-3300 mm/yr], 99% greater at high latitudes [550 mm/yr]). The calculated precipitation rates are significantly different from the precipitation rates predicted by some recent general circulation models (GCMs) for the warm Cretaceous, particularly in the mid to high latitudes. Our mass balance model by no means replaces GCMs. However, it is a simple and effective means of obtaining

  6. Reconciling high-altitude precipitation in the upper Indus basin with glacier mass balances and runoff

    Science.gov (United States)

    Immerzeel, Walter; Wanders, Niko; Lutz, Arthur; Shea, Joseph; Bierkens, Marc

    2016-04-01

    Mountain ranges in Asia are important water suppliers, especially if downstream climates are arid, water demands are high and glaciers are abundant. In such basins, the hydrological cycle depends heavily on high-altitude precipitation. Yet direct observations of high-altitude precipitation are lacking and satellite derived products are of insufficient resolution and quality to capture spatial variation and magnitude of mountain precipitation. Here we use glacier mass balances to inversely infer the high-altitude precipitation in the upper Indus basin and show that the amount of precipitation required to sustain the observed mass balances of large glacier systems is far beyond what is observed at valley stations or estimated by gridded precipitation products. An independent validation with observed river flow confirms that the water balance can indeed only be closed when the high altitude precipitation on average is more than twice as high and in extreme cases up to a factor of 10 higher than previously thought. We conclude that these findings alter the present understanding of high-altitude hydrology and will have an important bearing on climate change impact studies, planning and design of hydropower plants and irrigation reservoirs as well as the regional geopolitical situation in general.

  7. Active tuned mass damper in vehicles. Integrated mass and energy balance; Mechatronische Schwingungstilger in Fahrzeugen. Ganzheitliche Massen- und Energiebilanz

    Energy Technology Data Exchange (ETDEWEB)

    Granzow, Sebastian

    2012-04-02

    The number of mechatronic automotive applications is growing rapidly and becoming more and more important. On the other hand, the automotive industry is faced with the ambitious challenge to significantly reduce CO{sub 2}-emissions. The vehicle mass is as a part of the driving resistance is a starting point. New innovative approaches are required for lightweight constructions. Taking the two aspects together, this leads inevitably to the question: Is it possible to support automotive lightweight construction by using mechatronic systems? The Mechatronic vibration absorber is a combination of a mechanical oscillating system with an electronically controllable force component. This allows a broadband and situation-dependent influence of vehicle vibration behavior. Mechatronic vibration absorbers are suitable to compensate a loss of riding comfort due to a reduction of the body mass. Essential for this is a multidisciplinary simulation environment. The mechatronic vibration absorber, including appropriate control systems, the nonlinear chassis and the elastic body characteristics, inclusive of mutual interactions are mapped in the simulation environment Matlab. In addition to the representation of the oscillating vehicle the determination of the total energy requirements is necessary. To achieve a CO{sub 2}-reduction target, the overall energy balance of lightweight and the electrical vibration absorber energy, which is offered by the vehicle, is required. The question of the real vibration absorber energy needs to be discussed in the context of the individual driving behavior. Ultimately, the overall energy balance is inherently dependent of the individual driving behavior.

  8. Antarctic Ice-Sheet Mass Balance from Satellite Altimetry 1992 to 2001

    Science.gov (United States)

    Zwally, H. Jay; Brenner, Anita C.; Cornejo, Helen; Giovinetto, Mario; Saba, Jack L.; Yi, Donghui

    2003-01-01

    A major uncertainty in understanding the causes of the current rate of sea level rise is the potential contributions from mass imbalances of the Greenland and Antarctic ice sheets. Estimates of the current mass balance of the Antarctic ice sheet are derived from surface- elevation changes obtained from 9 years of ERS - 1 & 2 radar altimeter data. Elevation time-series are created from altimeter crossovers among 90-day data periods on a 50 km grid to 81.5 S. The time series are fit with a multivariate linear/sinusoidal function to give the average rate of elevation change (dH/dt). On the major Rome-Filchner, Ross, and Amery ice shelves, the W d t are small or near zero. In contrast, the ice shelves of the Antarctic Peninsula and along the West Antarctic coast appear to be thinning significantly, with a 23 +/- 3 cm per year surface elevation decrease on the Larsen ice shelf and a 65 +/- 4 cm per year decrease on the Dotson ice shelf. On the grounded ice, significant elevation decreases are obtained over most of the drainage basins of the Pine Island and Thwaites glaciers in West Antarctica and inland of Law Dome in East Antarctica. Significant elevation increases are observed within about 200 km of the coast around much of the rest of the ice sheet. Farther inland, the changes are a mixed pattern of increases and decreases with increases of a few centimeters per year at the highest elevations of the East Antarctic plateau. The derived elevation changes are combined with estimates of the bedrock uplift from several models to provide maps of ice thickness change. The ice thickness changes enable estimates of the ice mass balances for the major drainage basins, the overall mass balance, and the current contribution of the ice sheet to global sea level change.

  9. Mass balance of Mars' residual south polar cap from CTX images and other data

    Science.gov (United States)

    Thomas, P. C.; Calvin, W.; Cantor, B.; Haberle, R.; James, P. B.; Lee, S. W.

    2016-04-01

    Erosion of pits in the residual south polar cap (RSPC) of Mars concurrent with deposition and fluctuating cap boundaries raises questions about the mass balance and long term stability of the cap. Determining a mass balance by measurement of a net gain or loss of atmospheric CO2 by direct pressure measurements (Haberle, R.M. et al. [2014]. Secular climate change on Mars: An update using one Mars year of MSL pressure data. American Geophysical Union (Fall). Abstract 3947), although perhaps the most direct method, has so far given ambiguous results. Estimating volume changes from imaging data faces challenges, and has previously been attempted only in isolated areas of the cap. In this study we use 6 m/pixel Context Imager (CTX) data from Mars year 31 to map all the morphologic units of the RSPC, expand the measurement record of pit erosion rates, and use high resolution images to place limits on vertical changes in the surface of the residual cap. We find the mass balance in Mars years 9-31 to be -6 to +4 km3/♂y, or roughly -0.039% to +0.026% of the mean atmospheric CO2 mass/♂y. The indeterminate sign results chiefly from uncertainty in the amounts of deposition or erosion on the upper surfaces of deposits (as opposed to scarp retreat). Erosion and net deposition in this period appear to be controlled by summertime planetary scale dust events, the largest occurring in MY 9, another, smaller one in MY 28. The rates of erosion and the deposition observed since MY 9 appear to be consistent with the types of deposits and erosional behavior found in most of the residual cap. However, small areas (deposits may require extended periods (>100 ♂y) of depositional and/or erosional conditions different from those occurring in the period since MY 9, although these environmental differences could be subtle.

  10. Regional Modeling of Dust Mass Balance and Radiative Forcing over East Asia using WRF-Chem

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Siyu; Zhao, Chun; Qian, Yun; Leung, Lai-Yung R.; Huang, J.; Huang, Zhongwei; Bi, Jianrong; Zhang, Wu; Shi, Jinsen; Yang, Lei; Li, Deshuai; Li, Jinxin

    2014-12-01

    The Weather Research and Forecasting model with Chemistry (WRF-Chem) is used to investigate the seasonal and annual variations of mineral dust over East Asia during 2007-2011, with a focus on the dust mass balance and radiative forcing. A variety of measurements from in-stu and satellite observations have been used to evaluate simulation results. Generally, WRF-Chem reproduces not only the column variability but also the vertical profile and size distribution of mineral dust over and near the dust source regions of East Asia. We investigate the dust lifecycle and the factors that control the seasonal and spatial variations of dust mass balance and radiative forcing over the seven sub-regions of East Asia, i.e. source regions, the Tibetan Plateau, Northern China, Southern China, the ocean outflow region, and Korea-Japan regions. Results show that, over the source regions, transport and dry deposition are the two dominant sinks. Transport contributes to ~30% of the dust sink over the source regions. Dust results in a surface cooling of up to -14 and -10 W m-2, atmospheric warming of up to 20 and 15 W m-2, and TOA cooling of -5 and -8 W m-2 over the two major dust source regions of East Asia, respectively. Over the Tibetan Plateau, transport is the dominant source with a peak in summer. Over identified outflow regions, maximum dust mass loading in spring is contributed by the transport. Dry and wet depositions are the comparably dominant sinks, but wet deposition is larger than dry deposition over the Korea-Japan region, particularly in spring (70% versus 30%). The WRF-Chem simulations can generally capture the measured features of dust aerosols and its radaitve properties and dust mass balance over East Asia, which provides confidence for use in further investigation of dust impact on climate over East Asia.

  11. Mass balance of the Greenland ice sheet (2003-2008) from ICESat data

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Simonsen, Sebastian Bjerregaard; Nielsen, Karina;

    2011-01-01

    of the Greenland ice sheet. Firn dynamics and surface densities are important factors that contribute to the mass change derived from remote-sensing altimetry. The volume change derived from ICESat data is corrected for changes in firn compaction over the observation period, vertical bedrock movement...... and an intercampaign elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by the application of a simple surface density model, in which some of the ice dynamics are accounted for. The firn compaction and density models are driven by the HIRHAM5 regional climate...... altimetry data. Three different methods for deriving elevation changes from the ICESat altimetry dataset are used. This multi-method approach provides a method to assess the complexity of deriving elevation changes from this dataset. The altimetry alone can not provide an estimate of the mass balance...

  12. Mass balance and mass loading of polybrominated diphenyl ethers (PBDEs) in a tertiary wastewater treatment plant using SBSE-TD-GC/MS.

    Science.gov (United States)

    Rocha-Gutiérrez, Beatriz A; Lee, Wen-Yee; Shane Walker, W

    2016-01-01

    A mass loading and mass balance analysis was performed on selected polybromodiphenyl ethers (PBDEs) in the first full-scale indirect potable reuse treatment plant in the United States. Chemical analysis of PBDEs was performed using an environmentally friendly sample preparation technique, called stir-bar sorptive extraction (SBSE), coupled with thermal desorption and gas chromatography/mass spectrometry (GC/MS). The three most dominant PBDEs found in all the samples were: BDE-47, BDE-99 and BDE-100. In the wastewater influent, the concentrations of studied PBDEs ranged from 94 to 775 ng/L, and in the effluent, the levels were below the detection limit. Concentrations in sludge ranged from 50 to 182 ng/g. In general, a removal efficiency of 92-96% of the PBDEs in the plant was accomplished through primary and secondary processes. The tertiary treatment process was able to effectively reduce the aforementioned PBDEs to less than 10 ng/L (>96% removal efficiency) in the effluent. If PBDEs remain in the treated wastewater effluent, they may pose environmental and health impacts through aquifer recharge, irrigation, and sludge final disposal.

  13. Chemical Diversity in High-Mass Star Formation

    CERN Document Server

    Beuther, H; Bergin, E A; Sridharan, T K

    2008-01-01

    Massive star formation exhibits an extremely rich chemistry. However, not much evolutionary details are known yet, especially at high spatial resolution. Therefore, we synthesize previously published Submillimeter Array high-spatial-resolution spectral line observations toward four regions of high-mass star formation that are in various evolutionary stages with a range of luminosities. Estimating column densities and comparing the spatially resolved molecular emission allows us to characterize the chemical evolution in more detail. Furthermore, we model the chemical evolution of massive warm molecular cores to be directly compared with the data. The four regions reveal many different characteristics. While some of them, e.g., the detection rate of CH3OH, can be explained by variations of the average gas temperatures, other features are attributed to chemical effects. For example, C34S is observed mainly at the core-edges and not toward their centers because of temperature-selective desorption and successive g...

  14. Uncertainty in modeling dust mass balance and radiative forcing from size parameterization

    Directory of Open Access Journals (Sweden)

    C. Zhao

    2013-07-01

    Full Text Available This study examines the uncertainties in simulating mass balance and radiative forcing of mineral dust due to biases in the dust size parameterization. Simulations are conducted quasi-globally (180° W–180° E and 60° S–70° N using the WRF-Chem model with three different approaches to represent dust size distribution (8-bin, 4-bin, and 3-mode. The biases in the 3-mode or 4-bin approaches against a relatively more accurate 8-bin approach in simulating dust mass balance and radiative forcing are identified. Compared to the 8-bin approach, the 4-bin approach simulates similar but coarser size distributions of dust particles in the atmosphere, while the 3-mode approach retains more fine dust particles but fewer coarse dust particles due to its prescribed σg of each mode. Although the 3-mode approach yields up to 10 days longer dust mass lifetime over the remote oceanic regions than the 8-bin approach, the three size approaches produce similar dust mass lifetime (3.2 days to 3.5 days on quasi-global average, reflecting that the global dust mass lifetime is mainly determined by the dust mass lifetime near the dust source regions. With the same global dust emission (∼6000 Tg yr-1, the 8-bin approach produces a dust mass loading of 39 Tg, while the 4-bin and 3-mode approaches produce 3% (40.2 Tg and 25% (49.1 Tg higher dust mass loading, respectively. The difference in dust mass loading between the 8-bin approach and the 4-bin or 3-mode approaches has large spatial variations, with generally smaller relative difference (-2 and atmospheric warming (0.39∼0.96 W m-2 and in a tremendous difference of a factor of ∼10 in dust TOA cooling (-0.24∼-2.20 W m-2. An uncertainty of a factor of 2 is quantified in dust emission estimation due to the different size parameterizations. This study also highlights the uncertainties in modeling dust mass and number loading, deposition fluxes, and radiative forcing resulting from different size

  15. The equilibrium flow and mass balance of the Taku Glacier, Alaska 1950–2006

    Directory of Open Access Journals (Sweden)

    K. F. Sprenke

    2008-05-01

    Full Text Available The Taku Glacier, Alaska has advanced 7.5 km since the late nineteenth century, while all other primary outlet glaciers of the Juneau Icefield are in retreat. The Juneau Icefield Research Program has completed field work on the Taku Glacier annually since 1946. The collected observations of surface mass balance, glacier velocity and glacier thickness at Profile IV 29 km above the terminus and 4 km above the equilibrium line provide a means to assess the equilibrium nature of the Taku Glacier. Velocity measured over a twelve month span and annual summer velocity measurements completed at a Profile IV from 1950–2006 indicate insignificant variations in velocity seasonally or from year to year. The consistency of velocity over the 56-year period indicates that in the vicinity of the equilibrium line, the flow of the Taku Glacier has been in an equilibrium state. Surface mass balance was positive from 1946–1988 averaging +0.42 m a−1. This led to glacier thickening. From 1988–2006 an important change has occurred and annual balance has been −0.14 m a−1, and the glacier thickness has ceased increasing along Profile IV. Field measurements of ice depth and surface velocity allow calculation of the volume flux at Profile IV. Volume flux is then compared with the surface balance flux from the region of the glacier above Profile IV, determined annually in the field. Above Profile IV the observed mean surface flux is 5.50×108 m3/a (±5%, while the calculated volume flux range flowing through profile IV is 5.00–5.47×108 m3/a. The mean surface flux has been greater than the volume flux, which has led to slow thickening of the Taku Glacier up to 1988. The thickening has not led to a change in the flow of Taku Glacier at Profile IV.

  16. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste

    Energy Technology Data Exchange (ETDEWEB)

    Danon-Schaffer, Monica N. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Tetra Tech, 800-555 West Hastings Street, Vancouver, Canada V6B 1M1 (Canada); Mahecha-Botero, Andrés, E-mail: andresm@chbe.ubc.ca [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Grace, John R. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Ikonomou, Michael [Institute of Ocean Sciences, P.O. Box 6000, 9860 West Saanich Road, Sidney, B.C., Canada V8L 4B2 (Canada)

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables. - Graphical abstract: Schematic of the various mass transfer (MT) and input/output steps for sub-systems in the landfill model. NeWS is defined as non-electronic waste solids, including sand and soil added as cover materials. Highlights: • A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs). • Landfill samples and laboratory results are used to estimate the model

  17. Absorption and desorption mass transfer rates in chemically enhanced reactive systems. Part I : Chemical enhancement factors

    NARCIS (Netherlands)

    Hamborg, Espen S.; Versteeg, Geert F.

    2012-01-01

    The chemical enhancement factors have been measured in a controlled environment for absorption and desorption mass transfer processes in aqueous 2.0 M MDEA solutions at temperatures of 298.15, 313.15, and 333.15 K and the loading of CO2 ranging from 0 to 0.8 in a batch-operated stirred tank reactor.

  18. The potential role of mass balance models for the management of upwelling ecosystems

    DEFF Research Database (Denmark)

    Jarre, Astrid

    1998-01-01

    Upwelling ecosystems are productive fishing grounds, contributing >30% to the world's catch of marine fish. A set of seven trophic mass balance models of productive subsystems of the four largest upwelling areas is used to demonstrate key features of the modeling process and the analysis...... set of species interactions, and its impact can thus be readily compared to that of other piscivores in the ecosystem. This approach consequently allows us to assess the ecological sustainability of a fishery. It therefore addresses the Code of Conduct for Responsible Fisheries recently published...

  19. Integrated configurable equipment selection and line balancing for mass production with serial-parallel machining systems

    Science.gov (United States)

    Battaïa, Olga; Dolgui, Alexandre; Guschinsky, Nikolai; Levin, Genrikh

    2014-10-01

    Solving equipment selection and line balancing problems together allows better line configurations to be reached and avoids local optimal solutions. This article considers jointly these two decision problems for mass production lines with serial-parallel workplaces. This study was motivated by the design of production lines based on machines with rotary or mobile tables. Nevertheless, the results are more general and can be applied to assembly and production lines with similar structures. The designers' objectives and the constraints are studied in order to suggest a relevant mathematical model and an efficient optimization approach to solve it. A real case study is used to validate the model and the developed approach.

  20. Tank 12H Acidic Chemical Cleaning Sample Analysis And Material Balance

    Energy Technology Data Exchange (ETDEWEB)

    Martino, C. J.; Reboul, S. H.; Wiersma, B. J.; Coleman, C. J.

    2013-11-08

    A process of Bulk Oxalic Acid (BOA) chemical cleaning was performed for Tank 12H during June and July of 2013 to remove all or a portion of the approximately 4400 gallon sludge heel. Three strikes of oxalic acid (nominally 4 wt% or 2 wt%) were used at 55°C and tank volumes of 96- to 140-thousand gallons. This report details the sample analysis of a scrape sample taken prior to BOA cleaning and dip samples taken during BOA cleaning. It also documents a rudimentary material balance for the Tank 12H cleaning results.

  1. Endoreversible four-mass-reservoir chemical pump with diffusive mass transfer law

    Directory of Open Access Journals (Sweden)

    Dan Xia, Lingen Chen, Fengrui Sun

    2011-11-01

    Full Text Available The performance of an isothermal endoreversible four-mass-reservoir chemical pump, in which the mass transfer obeys diffusive law, is analyzed and optimized in this paper. The relation between the rate of energy pumping and the coefficient of performance of the isothermal chemical pump is derived by using finite-time thermodynamics. Moreover, the optimal operating regions and the influences of some parameters on the performance of the cycle are studied. The results obtained herein can provide some new theoretical guidelines for the optimal design of a class of apparatus such as mass exchangers, and electrochemical, photochemical, and solid-state devices, as well as fuel pumps for solar-energy conversion systems.

  2. A mass-balance model to separate and quantify colloidal and solute redistributions in soil

    Science.gov (United States)

    Bern, C.R.; Chadwick, O.A.; Hartshorn, A.S.; Khomo, L.M.; Chorover, J.

    2011-01-01

    Studies of weathering and pedogenesis have long used calculations based upon low solubility index elements to determine mass gains and losses in open systems. One of the questions currently unanswered in these settings is the degree to which mass is transferred in solution (solutes) versus suspension (colloids). Here we show that differential mobility of the low solubility, high field strength (HFS) elements Ti and Zr can trace colloidal redistribution, and we present a model for distinguishing between mass transfer in suspension and solution. The model is tested on a well-differentiated granitic catena located in Kruger National Park, South Africa. Ti and Zr ratios from parent material, soil and colloidal material are substituted into a mixing equation to quantify colloidal movement. The results show zones of both colloid removal and augmentation along the catena. Colloidal losses of 110kgm-2 (-5% relative to parent material) are calculated for one eluviated soil profile. A downslope illuviated profile has gained 169kgm-2 (10%) colloidal material. Elemental losses by mobilization in true solution are ubiquitous across the catena, even in zones of colloidal accumulation, and range from 1418kgm-2 (-46%) for an eluviated profile to 195kgm-2 (-23%) at the bottom of the catena. Quantification of simultaneous mass transfers in solution and suspension provide greater specificity on processes within soils and across hillslopes. Additionally, because colloids include both HFS and other elements, the ability to quantify their redistribution has implications for standard calculations of soil mass balances using such index elements. ?? 2011.

  3. Sugarcane bagasse pretreatment using three imidazolium-based ionic liquids; mass balances and enzyme kinetics

    Directory of Open Access Journals (Sweden)

    Karatzos Sergios

    2012-08-01

    Full Text Available Abstract Background Effective pretreatment is key to achieving high enzymatic saccharification efficiency in processing lignocellulosic biomass to fermentable sugars, biofuels and value-added products. Ionic liquids (ILs, still relatively new class of solvents, are attractive for biomass pretreatment because some demonstrate the rare ability to dissolve all components of lignocellulosic biomass including highly ordered (crystalline cellulose. In the present study, three ILs, 1-butyl-3-methylimidazolium chloride ([C4mim]Cl, 1-ethyl-3-methylimidazolium chloride ([C2mim]Cl, 1-ethyl-3-methylimidazolium acetate ([C2mim]OAc are used to dissolve/pretreat and fractionate sugarcane bagasse. In these IL-based pretreatments the biomass is completely or partially dissolved in ILs at temperatures greater than 130°C and then precipitated by the addition of an antisolvent to the IL biomass mixture. For the first time mass balances of IL-based pretreatments are reported. Such mass balances, along with kinetics data, can be used in process modelling and design. Results Lignin removals of 10% mass of lignin in bagasse with [C4mim]Cl, 50% mass with [C2mim]Cl and 60% mass with [C2mim]OAc, are achieved by limiting the amount of water added as antisolvent to 0.5 water:IL mass ratio thus minimising lignin precipitation. Enzyme saccharification (24 h, 15FPU yields (% cellulose mass in starting bagasse from the recovered solids rank as: [C2mim]OAc(83% > >[C2mim]Cl(53% = [C4mim]Cl(53%. Composition of [C2mim]OAc-treated solids such as low lignin, low acetyl group content and preservation of arabinosyl groups are characteristic of aqueous alkali pretreatments while those of chloride IL-treated solids resemble aqueous acid pretreatments. All ILs are fully recovered after use (100% mass as determined by ion chromatography. Conclusions In all three ILs regulated addition of water as an antisolvent effected a polysaccharide enriched precipitate since some of the lignin

  4. Improving Surface Mass Balance Over Ice Sheets and Snow Depth on Sea Ice

    Science.gov (United States)

    Koenig, Lora Suzanne; Box, Jason; Kurtz, Nathan

    2013-01-01

    Surface mass balance (SMB) over ice sheets and snow on sea ice (SOSI) are important components of the cryosphere. Large knowledge gaps remain in scientists' abilities to monitor SMB and SOSI, including insufficient measurements and difficulties with satellite retrievals. On ice sheets, snow accumulation is the sole mass gain to SMB, and meltwater runoff can be the dominant single loss factor in extremely warm years such as 2012. SOSI affects the growth and melt cycle of the Earth's polar sea ice cover. The summer of 2012 saw the largest satellite-recorded melt area over the Greenland ice sheet and the smallest satellite-recorded Arctic sea ice extent, making this meeting both timely and relevant.

  5. The impact of Saharan dust and black carbon on albedo and long-term mass balance of an Alpine glacier

    Directory of Open Access Journals (Sweden)

    J. Gabbi

    2015-07-01

    Full Text Available Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e., mineral dust and black carbon (BC, on albedo and glacier mass balance. The analysis was performed over the period 1914–2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100-year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the effects of melt and accumulation processes on the impurity concentration at the surface and thus on albedo and glacier mass balance. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04–0.06 depending on the location on the glacier. Consequently, annual melt was increased by 15–19 %, and the mean annual mass balance was reduced by about 280–490 mm w.e. BC clearly dominated absorption which is about 3 times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust and BC-enriched layers due to frequent years with negative mass balances.

  6. The impact of Saharan dust and black carbon on albedo and long-term mass balance of an Alpine glacier

    Science.gov (United States)

    Gabbi, J.; Huss, M.; Bauder, A.; Cao, F.; Schwikowski, M.

    2015-07-01

    Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e., mineral dust and black carbon (BC), on albedo and glacier mass balance. The analysis was performed over the period 1914-2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100-year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the effects of melt and accumulation processes on the impurity concentration at the surface and thus on albedo and glacier mass balance. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04-0.06 depending on the location on the glacier. Consequently, annual melt was increased by 15-19 %, and the mean annual mass balance was reduced by about 280-490 mm w.e. BC clearly dominated absorption which is about 3 times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust and BC-enriched layers due to frequent years with negative mass balances.

  7. Mass balance attending gel palagonitization of hyaloclastites in the HSDP 2 Phase 1 core

    Science.gov (United States)

    Walton, A. W.; Schiffman, P.; MacPherson, G.

    2002-12-01

    In the HSDP 2 core, the alteration of hyaloclastites is multi-episodic, but the predominant, "normal" alteration process - recorded in samples from depths between 1573 m and the bottom of the hole at over 3000 m - entails the conversion of rinds of sideromelane-rich shards to gel palagonite and growth of pore-filling chabazite. This reaction must occur relatively rapidly, because point-count porosity in the zone of normal alteration approaches zero within 200 m of the top of this zone and remains very low to the deepest samples. Furthermore, thickness of palagonite rinds does not increase down hole. Using modes from point counts on thin sections, major element analyses by electron microprobe, and trace element analyses by LAM-ICPMS, we have modeled the elemental mass balance for the normal palagonitization process in the HSDP hyaloclastites. Petrographic evidence suggests that this reaction does not involve solids other than sideromelane, gel palagonite, and chabazite and that the conversion of sideromelane to gel palagonite is isovolumetric. We used literature values of density: 2.80 g/cc for sideromelane, 2.00 for gel palagonite, and 2.075 for chabazite. The major elemental balance calculated for these conditions, and averaged over 10 samples shows net addition of K2O (by 17%), TiO2 (19%), and water, with net losses of MgO (73%), P2O5 (52%), MnO (29%), CaO (17%), Na2O (36%), SiO2 (19%), FeO (15%), and Al2O3 (18%). Individual samples show similar patterns. Decreasing the gel palagonite density (to 1.9 g/cc) and allowing for a 5% volume decrease reduces the TiO2 uptake (to 8%), but also increases the apparent loss of other "immobile" elements (FeO to 23% and Al2O3 to 22%). Normalized REE patterns for sideromelane versus gel palagonite show no systematic fractionations, although the normal reaction requires net gains on the order of 10-20% for most REEs. HFS elements are enriched in gel palagonite, relative to values in sideromelane, but LIL elements are depleted

  8. Impact of sublimation losses in the mass balance of glaciers in semi-arid mountain regions

    Science.gov (United States)

    Ayala, Alvaro; Pellicciotti, Francesca; Burlando, Paolo; MacDonell, Shelley; McPhee, James

    2016-04-01

    Glaciers in semiarid mountain regions may lose an important part of their winter snow accumulation through sublimation processes that are enhanced by the high-elevation, intense radiation and dry atmosphere of these environments. As glaciers in these regions secure freshwater resources to lower valleys during summer and drought periods, it is important to advance in a detailed quantification of their sublimation losses. However, logistical concerns and complex meteorological features make the measuring and modelling of glacier mass balances a difficult task. In this study, we estimated the spring-summer mass balances of Tapado and Juncal Norte glaciers in the semiarid Andes of north-central Chile by running a distributed energy balance model that accounts for melt, refreezing and sublimation from the surface and blowing snow. Meteorological input data were available from on-glacier Automatic Weather Stations (AWS) that were installed during the ablation season of years 2005-06, 2008-09, 2013-14 and 2014-15. Snow pits, ablation stakes and a time-lapse camera that provided surface albedo were also available. Distributed air temperature and wind speed were dynamically downscaled from NASA MERRA reanalysis using the software WINDSIM and validated against the data from the AWSs. The rest of the meteorological variables were distributed using statistical relations with air temperature derived from the AWSs data. Initial snow conditions were estimated using satellite images and distributed manual snow depth measurements. Preliminary results show that total ablation diminishes with elevation and that, during the early ablation season (October-November), melt is the main ablation component below 4500 m with sublimation dominating the ablation above this elevation. Above 4500 m an important fraction of meltwater refreezes during night. As the ablation season advances (December-February), melt extends to higher elevations, refreezing plays a smaller role and sublimation is

  9. Stable climate and surface mass balance in Svalbard over 1979–2013 despite the Arctic warming

    Directory of Open Access Journals (Sweden)

    C. Lang

    2015-01-01

    (Model for Interdisciplinary Research on Climate global model (MARMIROC5 from the CMIP5 (Coupled Model Intercomparison Project database, we have modelled the climate and surface mass balance of Svalbard at a 10 km resolution over 1979–2013. The integrated total surface mass balance (SMB over Svalbard modelled by MARERA is negative (−1.6 Gt yr−1 with a large interannual variability (7.1 Gt but, unlike over Greenland, there has been no acceleration of the surface melt over the past 35 years because of the recent change in atmospheric circulation bringing northwesterly flows in summer over Svalbard, contrasting the recent observed Arctic warming. However, in 2013, the atmospheric circulation changed to a south–southwesterly flow over Svalbard causing record melt, SMB (−20.4 Gt yr−1 and summer temperature. MIROC5 is significantly colder than ERA-Interim over 1980–2005 but MARMIROC5 is able to improve the near-surface MIROC5 results by simulating not significant SMB differences with MARERA over 1980–2005. On the other hand, MIROC5 does not represent the recent atmospheric circulation shift in summer and induces in MARMIROC5 a significant trend of decreasing SMB (−0.6 Gt yr−2 over 1980–2005.

  10. A metabolism perspective on alternative urban water servicing options using water mass balance.

    Science.gov (United States)

    Farooqui, Tauheed A; Renouf, Marguerite A; Kenway, Steven J

    2016-12-01

    Urban areas will need to pursue new water servicing options to ensure local supply security. Decisions about how best to employ them are not straightforward due to multiple considerations and the potential for problem shifting among them. We hypothesise that urban water metabolism evaluation based a water mass balance can help address this, and explore the utility of this perspective and the new insights it provides about water servicing options. Using a water mass balance evaluation framework, which considers direct urban water flows (both 'natural' hydrological and 'anthropogenic' flows), as well as water-related energy, we evaluated how the use of alternative water sources (stormwater/rainwater harvesting, wastewater/greywater recycling) at different scales influences the 'local water metabolism' of a case study urban development. New indicators were devised to represent the water-related 'resource efficiency' and 'hydrological performance' of the urban area. The new insights gained were the extent to which alternative water supplies influence the water efficiency and hydrological performance of the urban area, and the potential energy trade-offs. The novel contribution is the development of new indicators of urban water resource performance that bring together considerations of both the 'anthropogenic' and 'natural' water cycles, and the interactions between them. These are used for the first time to test alternative water servicing scenarios, and to provide a new perspective to complement broader sustainability assessments of urban water.

  11. Long term mass balance of the Helheim and Kangerdlugssuaq glaciers in southeast Greenland

    Science.gov (United States)

    Khan, Shfaqat Abbas; Fitzner, Antje; Kjær, Kurt; Korsgaard, Niels; Aschwanden, Andy; Bjørk, Anders; Bevan, Suzanne; Kjeldsen, Kristian; Bueler, Edward; Luckman, Adrian; van den Broeke, Michiel

    2013-04-01

    Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve the projection of future sea level rise, a long-term data record that reveals the mass balance between episodic events is required. Here, we extend the observational record of marginal thinning of Helheim glacier (HG) and Kangerdlugssuaq glacier (KG) from 7 to 30 years. Our measurements reveal that, although the frontal portion of HG thinned by more than 100 m during 2003-2006, it thickened by more than 50 m during 1981-1997. During the same periods, KG was stable until 1998 and experienced major thinning only after 2003. Analyses of their sensitivity to sea surface temperature (SST) anomalies and variations in air temperature suggest that both outlet glaciers respond immediately to small fluctuations in both the SST and air temperature. Furthermore, we compare our observations of ice flow speed and elevation changes with predictions based on the The Parallel Ice Sheet Model (PISM) software.

  12. A mass balance study on nitrification and deammonification in vertical flow constructed wetlands treating landfill leachate.

    Science.gov (United States)

    Sun, G; Austin, D

    2007-01-01

    A laboratory-scale, mass-balance study was carried out on the transformation of nitrogenous pollutants in four vertical flow wetland columns. Landfill leachate containing low organic matter, but a high concentration of ammoniacal-nitrogen, was treated under dissolved oxygen concentrations close to saturation. Influent total nitrogen (TN) comprised ammoniacal-nitrogen with less than 1% nitrate and nitrite, negligible organic nitrogen, and very low BOD. Nitrification occurred in three of the four columns. There was a substantial loss of total nitrogen (52%) in one column, whereas other columns exhibited zero to minor losses (< 12%). Nitrogen loss under study conditions was unexpected. Two hypotheses are proposed to account for it: (1) either the loss of TN is attributed to nitrogen transformation into a form (provisionally termed alpha-nitrogen) that is undetectable by the analytical methods used; or (2) the loss is caused by microbial denitrification or deammonification. By elimination and stoichiometric mass balance calculations, completely autotrophic nitrogen-removal over nitrite (CANON) deammonification is confirmed as responsible for nitrogen loss in one column. This result reveals that CANON can be native to aerobic engineered wetland systems treating high ammonia, low organic content wastewater.

  13. Aquatic Exposure Predictions of Insecticide Field Concentrations Using a Multimedia Mass-Balance Model.

    Science.gov (United States)

    Knäbel, Anja; Scheringer, Martin; Stehle, Sebastian; Schulz, Ralf

    2016-04-05

    Highly complex process-driven mechanistic fate and transport models and multimedia mass balance models can be used for the exposure prediction of pesticides in different environmental compartments. Generally, both types of models differ in spatial and temporal resolution. Process-driven mechanistic fate models are very complex, and calculations are time-intensive. This type of model is currently used within the European regulatory pesticide registration (FOCUS). Multimedia mass-balance models require fewer input parameters to calculate concentration ranges and the partitioning between different environmental media. In this study, we used the fugacity-based small-region model (SRM) to calculate predicted environmental concentrations (PEC) for 466 cases of insecticide field concentrations measured in European surface waters. We were able to show that the PECs of the multimedia model are more protective in comparison to FOCUS. In addition, our results show that the multimedia model results have a higher predictive power to simulate varying field concentrations at a higher level of field relevance. The adaptation of the model scenario to actual field conditions suggests that the performance of the SRM increases when worst-case conditions are replaced by real field data. Therefore, this study shows that a less complex modeling approach than that used in the regulatory risk assessment exhibits a higher level of protectiveness and predictiveness and that there is a need to develop and evaluate new ecologically relevant scenarios in the context of pesticide exposure modeling.

  14. Mass balance for lead in the California South Coast Air Basin: an update.

    Science.gov (United States)

    Lankey, R L; Davidson, C I; McMichael, F C

    1998-08-01

    A mass balance for lead for the year 1989 in the South Coast Air Basin has inputs to the atmosphere of 600 +/- 190 kg/day and outputs of 580 +/- 160 kg/day, showing rough agreement. Stationary sources are responsible for only about 5% of the total lead emissions. The bulk of the lead is emitted from vehicles using leaded gasoline (37%) and unleaded gasoline (15%), as well as from resuspension of previously deposited lead on roads (43%). Over half of the total emitted lead deposits on roads and nearby soil, while about one-third is carried out the basin by wind. A small amount, less than 10%, is deposited on surfaces throughout the basin. These percentages are approximately the same as those in a mass balance for the same region calculated for 1972, when lead emissions from leaded gasoline were about a factor of 70 greater than leaded gas emissions in 1989. When the lead emissions are used as inputs to a simple continuously stirred flow reactor model for the basin, reasonable agreement is obtained between calculated and measured concentrations.

  15. Estimating groundwater exchange with lakes: 1. The stable isotope mass balance method

    Science.gov (United States)

    Krabbenhoft, David P.; Bowser, Carl J.; Anderson, Mary P.; Valley, John W.

    1990-01-01

    Groundwater inflow and outflow contributions to the hydrologic budget of lakes can be determined using a stable isotope (18O/16O) mass balance method. The stable isotope method provides a way of integrating the spatial and temporal complexities of the flow field around a lake, thereby offering an appealing alternative to the traditional time and labor intensive methods using seepage meters and an extensive piezometer network. In this paper the method is applied to a lake in northern Wisconsin, demonstrating that it can be successfully applied to lakes in the upper midwest where thousands of similar lakes exist. Inflow and outflow rates calculated for the Wisconsin lake using the isotope mass balance method are 29 and 54 cm/yr, respectively, which compare well to estimates, derived independently using a three-dimensional groundwater flow and solute transport model, of 20 and 50 cm/yr. Such a favorable comparison lends confidence to the use of the stable isotope method to estimate groundwater exchange with lakes. In addition, utilization of stable isotopes in studies of groundwater-lake systems lends insight into mixing processes occurring in the unsaturated zone and in the aquifer surrounding the lake and verifies assumed flow paths based on head measurements in piezometers.

  16. Long Term Sea Level Change and Water Mass Balance in the South China Sea

    Institute of Scientific and Technical Information of China (English)

    RONG Zengrui; LIU Yuguang; ZONG Haibo; XIU Peng

    2009-01-01

    Sea level anomalies observed by altimeter during the 1993-2006 period, thermosterie sea level anomalies estimated by using subsurface temperature data produced by Ishii and SODA reanalysis data, tide gauge records and HOAPS freshwater flux data were analyzed to investigate the long term sea level change and the water mass balance in the South China Sea. The altimeter-observed sea level showed a rising rate of (3.5±0.9)mm yr-1 during the period 1993-2006, but this figure was considered to have been highly distorted by the relatively short time interval and the large inter-decadal variability, which apparently exists in both the thermosteric sea level and the observed sea level. Long term thermosteric sea level from 1945 to 2004 gave a rising rate of 0.15±0.06 mmyr-1. Tide gauge data revealed this discrepancy and the regional distributions of the sea-level trends. Both the 'real' and the thermosteric sea level showed a good correspondence to ENSO: decreasing during E1 Nifio years and increasing during La Nina years. Amplitude and phase differences between the 'real' sea level and the thermosteic sea level were substantially revealed on both seasonal and interannual time scales. As one of the possible factors, the freshwater flux might play an important role in balancing the water mass.

  17. Distributed modeling of snow cover mass and energy balance in the Rheraya watershed (High Atlas, Morocco)

    Science.gov (United States)

    Marchane, Ahmed; Gascoin, Simon; Jarlan, Lionel; Hanich, Lahoucine

    2016-04-01

    The mountains of the High Moroccan Atlas represent an important source of water for the neighboring arid plains. Despite the importance of snow in the regional water balance, few studies were devoted to the modeling of the snow cover at the watershed scale. This type of modeling is necessary to characterize the contribution of snowmelt to water balance and understanding its sensitivity to natural and human-induced climate fluctuations. In this study, we applied a spatially-distributed model of the snowpack evolution (SnowModel, Liston & Elder 2006) on the Rheraya watershed (225 km²) in the High Atlas in order to simulate the mass and energy balance of the snow cover and the evolution of snow depth over a full season (2008-2009). The model was forced by 6 meteorological stations. The model was evaluated locally at the Oukaimeden meteorological station (3230 m asl) where snow depth is recorded continuously. To evaluate the model at the watershed scale we used the daily MODIS snow cover products and a series of 15 cloud-free optical images acquired by the FORMOSAT-2 satellite at 8-m resolution from February to June 2009. The results showed that the model is able to simulate the snow depth in the Oukaimeden station for the 2008-2009 season, and also to simulate the spatial and temporal variation of of the snow cover area in the watershed Rheraya. Based on the model output we examine the importance of the snow sublimation on the water balance at the watershed scale.

  18. Mass transfer in porous media with heterogeneous chemical reaction

    Directory of Open Access Journals (Sweden)

    Souza S.M.A.G.Ulson de

    2003-01-01

    Full Text Available In this paper, the modeling of the mass transfer process in packed-bed reactors is presented and takes into account dispersion in the main fluid phase, internal diffusion of the reactant in the pores of the catalyst, and surface reaction inside the catalyst. The method of volume averaging is applied to obtain the governing equation for use on a small scale. The local mass equilibrium is assumed for obtaining the one-equation model for use on a large scale. The closure problems are developed subject to the length-scale constraints and the model of a spatially periodic porous medium. The expressions for effective diffusivity, hydrodynamic dispersion, total dispersion and the Darcy's law permeability tensors are presented. Solution of the set of final equations permits the variations of velocity and concentration of the chemical species along the packed-bed reactors to be obtained.

  19. A LEGO Watt Balance: An apparatus to demonstrate the definition of mass based on the new SI

    CERN Document Server

    Chao, L S; Newell, D B; Pratt, J R; Sineriz, G; Seifert, F; Cao, A; Haddad, D; Zhang, X

    2014-01-01

    A global effort to redefine our International System of Units (SI) is underway and the change to the new system is expected to occur in 2018. Within the newly redefined SI, the present base units will still exist but be derived from fixed numerical values of seven reference constants. More specifically, the unit of mass, the kilogram, will be realized through a fixed value of the Planck constant $h$. For instance, a watt balance can be used to realize the kilogram unit of mass within a few parts in $10^8$. Such a balance has been designed and constructed at the National Institute of Standards and Technology. For educational outreach and to demonstrate the principle, we have constructed a LEGO tabletop watt balance capable of measuring a gram size mass to 1 % relative uncertainty. This article presents the design, construction, and performance of the LEGO watt balance and its ability to determine $h$

  20. The impact of Saharan dust and black carbon on albedo and long-term glacier mass balance

    Directory of Open Access Journals (Sweden)

    J. Gabbi

    2015-02-01

    Full Text Available Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e. Saharan dust and black carbon (BC, on albedo and glacier mass balance. The analysis was performed over the period 1914–2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100 year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the dust/BC-albedo feedback. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04–0.06 and increased melt by 15–19% on average depending on the location on the glacier. BC clearly dominated absorption which is about three times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust-enriched layers due to frequent years with negative mass balances.

  1. Atmospheric deposition of polycyclic aromatic hydrocarbons to water surfaces: A mass balance approach

    Science.gov (United States)

    McVeety, Bruce D.; Hites, Ronald A.

    A mass balance model was developed to explain the movement of polycyclic aromatic hydrocarbons (PAH) into and out of Siskiwit Lake, which is located on a wilderness island in northern Lake Superior. Because of its location, the PAH found in this lake must have originated exclusively from atmospheric sources. Using gas Chromatographie mass spectrometry, 11 PAH were quantified in rain, snow, air, lake water, sediment core and sediment trap samples. From the dry deposition fluxes, an aerosol deposition velocity of 0.99 ± 0.15 cm s -1 was calculated for indeno[1,2,3- cd]pyrene and benzo[ ghi]perylene, two high molecular weight PAH which are not found in the gas phase. The dry aerosol deposition was found to dominate the wet removal mechanism by an average ratio of 9:1. The dry gas flux was negative, indicating that surface volatilization was taking place; it accounted for 10-80 % of the total output flux depending on the volatility of the PAH. The remaining PAH were lost to sedimentation. From the dry gas flux, an overall mass transfer coefficient for PAH was calculated to be 0.18 ± 0.06 m d -1. In this case, the overall mass transfer is dominated by the liquid phase resistance.

  2. Super-atmospheric pressure chemical ionization mass spectrometry.

    Science.gov (United States)

    Chen, Lee Chuin; Rahman, Md Matiur; Hiraoka, Kenzo

    2013-03-01

    Super-atmospheric pressure chemical ionization (APCI) mass spectrometry was performed using a commercial mass spectrometer by pressurizing the ion source with compressed air up to 7 atm. Similar to typical APCI source, reactant ions in the experiment were generated with corona discharge using a needle electrode. Although a higher needle potential was necessary to initiate the corona discharge, discharge current and detected ion signal were stable at all tested pressures. A Roots booster pump with variable pumping speed was installed between the evacuation port of the mass spectrometer and the original rough pumps to maintain a same pressure in the first pumping stage of the mass spectrometer regardless of ion source pressure. Measurement of gaseous methamphetamine and research department explosive showed an increase in ion intensity with the ion source pressure until an optimum pressure at around 4-5 atm. Beyond 5 atm, the ion intensity decreased with further increase of pressure, likely due to greater ion losses inside the ion transport capillary. For benzene, it was found that besides molecular ion and protonated species, ion due to [M + 2H](+) which was not so common in APCI, was also observed with high ion abundance under super-atmospheric pressure condition.

  3. Constraining Anthropogenic and Biogenic Emissions Using Chemical Ionization Mass Spectrometry

    Science.gov (United States)

    Spencer, Kathleen M.

    Numerous gas-phase anthropogenic and biogenic compounds are emitted into the atmosphere. These gases undergo oxidation to form other gas-phase species and particulate matter. Whether directly or indirectly, primary pollutants, secondary gas-phase products, and particulate matter all pose health and environmental risks. In this work, ambient measurements conducted using chemical ionization mass spectrometry are used as a tool for investigating regional air quality. Ambient measurements of peroxynitric acid (HO2NO2) were conducted in Mexico City. A method of inferring the rate of ozone production, PO3, is developed based on observations of HO2NO 2, NO, and NO2. Comparison of this observationally based PO3 to a highly constrained photochemical box model indicates that regulations aimed at reducing ozone levels in Mexico City by reducing NOx concentrations may be effective at higher NO x levels than predicted using accepted photochemistry. Measurements of SO2 and particulate sulfate were conducted over the Los Angeles basin in 2008 and are compared to measurements made in 2002. A large decrease in SO2 concentration and a change in spatial distribution are observed. Nevertheless, only a modest reduction in sulfate concentration is observed at ground sites within the basin. Possible explanations for these trends are investigated. Two techniques, single and triple quadrupole chemical ionization mass spectrometry, were used to quantify ambient concentrations of biogenic oxidation products, hydroxyacetone and glycolaldehyde. The use of these techniques demonstrates the advantage of triple quadrupole mass spectrometry for separation of mass analogues, provided the collision-induced daughter ions are sufficiently distinct. Enhancement ratios of hydroxyacetone and glycolaldehyde in Californian biomass burning plumes are presented as are concentrations of these compounds at a rural ground site downwind of Sacramento.

  4. Titanium Mass-balance Analysis of Paso Robles Soils: Elemental Gains and Losses as Affected by Acid Alteration Fluids

    Science.gov (United States)

    Sutter, Brad; Ming, Douglas W.

    2010-01-01

    The Columbia Hills soils have been exposed to aqueous alteration in alkaline [1] as well as acid conditions [2,3]. The Paso Robles class soils are bright soils that possess the highest S concentration of any soil measured on Mars [2]. Ferric-sulfate detection by Moessbauer analysis indicated that acid solutions were involved in forming these soils [4]. These soils are proposed to have formed by alteration of nearby rock by volcanic hydrothermal or fumarolic activity. The Paso Robles soils consist of the original Paso Robles-disturbed-Pasadena (PR-dist), Paso Robles- PasoLight (PR-PL), Arad-Samra, Arad-Hula, Tyrone- Berker Island1 and Tyrone-MountDarwin [2 ,3. ]Chemical characteristics indicate that the PR-dist and PR-PL soils could be derived from acid weathering of local Wishstone rocks while the Samra and Hula soils are likely derived from local Algonquin-Iroquet rock [3]. The Paso Robles soils were exposed to acidic sulfur bearing fluids; however, little else is known about the chemistry of the alteration fluid and its effects on the alteration of the proposed parent materials. The objectives of this work are to conduct titanium normalized mass-balance analysis to1) assess elemental gains and losses from the parent materials in the formation of the Paso Robles soils and 2) utilize this information to indicate the chemical nature of the alteration fluids.

  5. Sensitivity of annual mass balance gradient and Hypsometry to the changing climate: the case of Dokriani Glacier, central Himalaya, India

    Science.gov (United States)

    Pratap, B.

    2015-12-01

    The glacier mass balance is undelayed, unfiltered and direct method to assess the impact of climate change on the glaciers. Many studies suggest that some of the Himalayan glaciers have lost their mass at an increased rate during the past few decades. Furthermore, the mass balance gradient and hypsometric analysis are important to understand the glacier response towards climatic perturbations. Our long term in-situ monitoring on the Dokriani Glacier provides great insights to understand the variability in central Himalayan glaciers. We report the relationship between glacier hypsometry and annual mass balance gradient (12 years) to understand the glacier's response towards climate change. Dokriani Glacier in the Bhagirathi basin is a small (7 km2) NNW exposed glacier in the western part of central Himalaya, India. The study analysed the annual balance, mass balance gradient and length changes observed during first decade of 21st century (2007-2013) and compare with the previous observations of 1990s (1992-2000). A large spatial variability in the mass balance gradients of two different periods has been observed. The equilibrium-line altitude (ELA) was fluctuated between 5000 and 5100 m a.s.l. and the derived time averaged ELA (ELAn) and balance budget ELA (ELA0) were 5075 and 4965 m a.s.l respectively during 1992-2013. The observed time-averaged accumulation-area ratio (AARn) and balance budget AAR (AAR0) were 0.67 and 0.72 respectively during 1992-2013. The higher value of AAR comprises due to flat and broader accumulation area (4.50 km2) of the glacier. Although, having larger accumulation area, the glacier has faced strong mass wasting with average annual ablation of -1.82 m w.e. a-1 in the ablation zone as compare to residual average annual accumulation of 0.41 m w.e. a-1. Based on the annual mass balance series (12 years) Dokriani Glacier has continuous negative annual balances with monotonically negative cumulative mass loss of -3.86 m w.e with the average

  6. Does mechanistic modeling of filter strip pesticide mass balance and degradation processes affect environmental exposure assessments?

    Science.gov (United States)

    Muñoz-Carpena, Rafael; Ritter, Amy; Fox, Garey A; Perez-Ovilla, Oscar

    2015-11-01

    Vegetative filter strips (VFS) are a widely adopted practice for limiting pesticide transport from adjacent fields to receiving waterbodies. The efficacy of VFS depends on site-specific input factors. To elucidate the complex and non-linear relationships among these factors requires a process-based modeling framework. Previous research proposed linking existing higher-tier environmental exposure models with a well-tested VFS model (VFSMOD). However, the framework assumed pesticide mass stored in the VFS was not available for transport in subsequent storm events. A new pesticide mass balance component was developed to estimate surface pesticide residue trapped in the VFS and its degradation between consecutive runoff events. The influence and necessity of the updated framework on acute and chronic estimated environmental concentrations (EECs) and percent reductions in EECs were investigated across three, 30-year U.S. EPA scenarios: Illinois corn, California tomato, and Oregon wheat. The updated framework with degradation predicted higher EECs than the existing framework without degradation for scenarios with greater sediment transport, longer VFS lengths, and highly sorbing and persistent pesticides. Global sensitivity analysis (GSA) assessed the relative importance of mass balance and degradation processes in the context of other input factors like VFS length (VL), organic-carbon sorption coefficient (Koc), and soil and water half-lives. Considering VFS pesticide residue and degradation was not important if single, large runoff events controlled transport, as is typical for higher percentiles considered in exposure assessments. Degradation processes become more important when considering percent reductions in acute or chronic EECs, especially under scenarios with lower pesticide losses.

  7. Adjustment of regional climate model output for modeling the climatic mass balance of all glaciers on Svalbard.

    Science.gov (United States)

    Möller, Marco; Obleitner, Friedrich; Reijmer, Carleen H; Pohjola, Veijo A; Głowacki, Piotr; Kohler, Jack

    2016-05-27

    Large-scale modeling of glacier mass balance relies often on the output from regional climate models (RCMs). However, the limited accuracy and spatial resolution of RCM output pose limitations on mass balance simulations at subregional or local scales. Moreover, RCM output is still rarely available over larger regions or for longer time periods. This study evaluates the extent to which it is possible to derive reliable region-wide glacier mass balance estimates, using coarse resolution (10 km) RCM output for model forcing. Our data cover the entire Svalbard archipelago over one decade. To calculate mass balance, we use an index-based model. Model parameters are not calibrated, but the RCM air temperature and precipitation fields are adjusted using in situ mass balance measurements as reference. We compare two different calibration methods: root mean square error minimization and regression optimization. The obtained air temperature shifts (+1.43°C versus +2.22°C) and precipitation scaling factors (1.23 versus 1.86) differ considerably between the two methods, which we attribute to inhomogeneities in the spatiotemporal distribution of the reference data. Our modeling suggests a mean annual climatic mass balance of -0.05 ± 0.40 m w.e. a(-1) for Svalbard over 2000-2011 and a mean equilibrium line altitude of 452 ± 200 m  above sea level. We find that the limited spatial resolution of the RCM forcing with respect to real surface topography and the usage of spatially homogeneous RCM output adjustments and mass balance model parameters are responsible for much of the modeling uncertainty. Sensitivity of the results to model parameter uncertainty is comparably small and of minor importance.

  8. Greenland Ice Sheet Mass Balance: Distribution of Increased Mass Loss with Climate Warming; 2003-07 Versus 1992-2002

    Science.gov (United States)

    Zwally, H. Jay; Li, Jun; Benner, Anita C.; Beckley, Matthew; Cornejo, Helen G.; DiMarzio, John; Giovinetto, Mario B.; Neumann, Thomas A.; Robbins, John; Saba, Jack L.; Yi, Donghui; Wang, Weili

    2011-01-01

    We derive mass changes of the Greenland ice sheet (GIS) for 2003-07 from ICESat laser altimetry and compare them with results for 1992-2002 from ERS radar and airborne laser altimetry. The GIS continued to grow inland and thin at the margins during 2003 07, but surface melting and accelerated flow significantly increased the marginal thinning compared with the 1990s. The net balance changed from a small loss of 7 plus or minus 3 Gt a 1(sup -1) in the 1990s to 171 plus or minus 4 Gt a (sup -1) for 2003-07, contributing 0.5 mm a(sup -1) to recent global sea-level rise. We divide the derived mass changes into two components: (1) from changes in melting and ice dynamics and (2) from changes in precipitation and accumulation rate. We use our firn compaction model to calculate the elevation changes driven by changes in both temperature and accumulation rate and to calculate the appropriate density to convert the accumulation-driven changes to mass changes. Increased losses from melting and ice dynamics (17-206 Gt a(sup-1) are over seven times larger than increased gains from precipitation (10 35 Gt a(sup-1) during a warming period of approximately 2 K (10 a)(sup -1) over the GIS. Above 2000m elevation, the rate of gain decreased from 44 to 28 Gt a(sup-1), while below 2000m the rate of loss increased from 51 to 198 Gt a(sup-1). Enhanced thinning below the equilibrium line on outlet glaciers indicates that increased melting has a significant impact on outlet glaciers, as well as accelerating ice flow. Increased thinning at higher elevations appears to be induced by dynamic coupling to thinning at the margins on decadal timescales.

  9. Uncertainty in alpine snow mass balance simulations due to snow model parameterisation and windflow representation

    Science.gov (United States)

    Musselman, K. N.; Pomeroy, J. W.; Essery, R.; Leroux, N.

    2013-12-01

    Despite advances in alpine snow modelling there remain two fundamental areas of divergent scientific thought in estimating alpine snow mass balances: i) blowing snow sublimation losses, and ii) wind flow representation. Sublimation calculations have poorly understood humidity feedbacks that vary considerably and mathematical representations of alpine windflow vary in complexity - these differences introduce uncertainty. To better estimate and restrain this uncertainty, a variety of physically based, spatially distributed snowmelt models that consider the physics of wind redistribution and sublimation of blowing snow were evaluated for their ability to simulate seasonal snow distribution and melt patterns in a windy alpine environment in the Canadian Rockies. The primary difference in the snow models was their calculation of blowing snow sublimation losses which ranged from large to small estimates. To examine the uncertainty introduced by windflow calculations on the snow model simulations, each model was forced with output from windflow models of varying computational complexity and physical realism from a terrain-based empirical interpolation of station observations to a simple turbulence model to a computational fluid dynamics model that solves for the Navier-Stokes equations. The high-resolution snow simulations were run over a 1 km2 spatial extent centred on a ridgetop meteorological station within the Marmot Creek Research basin, Alberta, Canada. The three windflow simulations all produced reasonable results compared to wind speeds measured on two opposing slopes (bias better than ×0.3 m s-1; RMSE errors were greatest when forced with output from the empirical wind model and smallest using output from either of the two turbulence models. Simulations with higher blowing snow sublimation rates tended to better match measured SWE at multiple scales, confirming that alpine blowing snow sublimation is an important component of the snow mass balance in this region

  10. Recycled Uranium Mass Balance Project Y-12 National Security Complex Site Report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-12-01

    This report has been prepared to summarize the findings of the Y-12 National Security Complex (Y-12 Complex) Mass Balance Project and to support preparation of associated U. S. Department of Energy (DOE) site reports. The project was conducted in support of DOE efforts to assess the potential for health and environmental issues resulting from the presence of transuranic (TRU) elements and fission products in recycled uranium (RU) processed by DOE and its predecessor agencies. The United States government used uranium in fission reactors to produce plutonium and tritium for nuclear weapons production. Because uranium was considered scarce relative to demand when these operations began almost 50 years ago, the spent fuel from U.S. fission reactors was processed to recover uranium for recycling. The estimated mass balance for highly enriched RU, which is of most concern for worker exposure and is the primary focus of this project, is summarized in a table. A discrepancy in the mass balance between receipts and shipments (plus inventory and waste) reflects an inability to precisely distinguish between RU and non-RU shipments and receipts involving the Y-12 Complex and Savannah River. Shipments of fresh fuel (non-RU) and sweetener (also non-RU) were made from the Y-12 Complex to Savannah River along with RU shipments. The only way to distinguish between these RU and non-RU streams using available records is by enrichment level. Shipments of {le}90% enrichment were assumed to be RU. Shipments of >90% enrichment were assumed to be non-RU fresh fuel or sweetener. This methodology using enrichment level to distinguish between RU and non-RU results in good estimates of RU flows that are reasonably consistent with Savannah River estimates. Although this is the best available means of distinguishing RU streams, this method does leave a difference of approximately 17.3 MTU between receipts and shipments. Slightly depleted RU streams received by the Y-12 Complex from ORGDP and

  11. Mass balance and hydrological contribution of glaciers in northern and central Chile

    Science.gov (United States)

    MacDonell, Shelley; Vivero, Sebastian; McPhee, James; Ayala, Alvaro; Pellicciotti, Francesca; Campos, Cristian; Caro, Dennys; Ponce, Rodrigo

    2016-04-01

    Water is a critical resource in the northern and central regions of Chile, as the area supports more than 40% of the country's population, and the regional economy depends on agricultural production and mining, which are two industries that rely heavily on a consistent water supply. Due to relatively low rates of rainfall, meltwater from snow and ice bodies in the highland areas provides a key component of the annual water supply in these areas. Consequently, accurate estimates of the rates of ablation of the cryosphere (i.e. snow and ice) are crucial for predicting current supply rates, and future projections. Whilst snow is generally a larger contributor of freshwater, during periods of drought, glaciers provide a significant source. This study aims to determine the contribution of glaciers to two catchments in northern and central Chile during a 2.5 year period, which largely consisted of extreme dry periods, but also included the recent El Niño event. This study combined field and modelling studies to understand glacier and rock glacier contributions in the Tapado (30°S), Yeso (33°S) catchments. In the field we undertook glaciological mass balance monitoring of three glaciers, monitored albedo and snow line changes using automatic cameras for three glaciers, measured discharge continuously at several points, installed six automatic weather stations and used thermistors to monitor thermal regime changes of two rock glaciers. The combination of these datasets where used to drive energy balance and hydrological models to estimate the contribution of ice bodies to streamflow in the two studied catchments. Over the course of the study all glaciers maintained a negative mass balance, however glaciers in central Chile lost more mass, which is due to the higher melt rates experienced due to lower elevations and higher temperatures. Areas free of debris generally contributed more to streamflow than sediment covered regions, and snow generally contributed more over

  12. Linking glacier annual mass balance and glacier albedo retrieved from MODIS data

    Directory of Open Access Journals (Sweden)

    M. Dumont

    2012-12-01

    Full Text Available Albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODerate Imaging Spectroradiometer (MODIS on board the TERRA and AQUA satellites, provide a means to monitor glacier surface albedo. In this study, different methods to retrieve broadband glacier surface albedo from MODIS data are compared. The effect of multiple reflections due to the rugged topography and of the anisotropic reflection of snow and ice are particularly investigated. The methods are tested on the Saint Sorlin Glacier (Grandes Rousses area, French Alps. The accuracy of the retrieved albedo is estimated using both field measurements, at two automatic weather stations located on the glacier, and albedo values derived from terrestrial photographs. For summers 2008 and 2009, the root mean square deviation (RMSD between field measurements and the broadband albedo retrieved from MODIS data at 250 m spatial resolution was found to be 0.052 or about 10% relative error. The RMSD estimated for the MOD10 daily albedo product is about three times higher. One decade (2000–2009 of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin Glacier during the ablation season. The annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (average over the whole glacier surface observed with MODIS during the ablation season. A strong linear correlation exists between the two variables. Furthermore, the date when the average albedo of the whole glacier reaches a minimum closely corresponds to the period when the snow line is located at its highest elevation, thus when the snow line is a good indicator of the glacier equilibrium line. This indicates that this strong correlation results from the fact that the minimal average albedo values of the glacier contains considerable information regarding the relative share of areal surfaces between the ablation zone (i.e. ice with generally

  13. Linking glacier annual mass balance and glacier albedo retrieved from MODIS data

    Science.gov (United States)

    Dumont, M.; Gardelle, J.; Sirguey, P.; Guillot, A.; Six, D.; Rabatel, A.; Arnaud, Y.

    2012-12-01

    Albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODerate Imaging Spectroradiometer (MODIS) on board the TERRA and AQUA satellites, provide a means to monitor glacier surface albedo. In this study, different methods to retrieve broadband glacier surface albedo from MODIS data are compared. The effect of multiple reflections due to the rugged topography and of the anisotropic reflection of snow and ice are particularly investigated. The methods are tested on the Saint Sorlin Glacier (Grandes Rousses area, French Alps). The accuracy of the retrieved albedo is estimated using both field measurements, at two automatic weather stations located on the glacier, and albedo values derived from terrestrial photographs. For summers 2008 and 2009, the root mean square deviation (RMSD) between field measurements and the broadband albedo retrieved from MODIS data at 250 m spatial resolution was found to be 0.052 or about 10% relative error. The RMSD estimated for the MOD10 daily albedo product is about three times higher. One decade (2000-2009) of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin Glacier during the ablation season. The annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (average over the whole glacier surface) observed with MODIS during the ablation season. A strong linear correlation exists between the two variables. Furthermore, the date when the average albedo of the whole glacier reaches a minimum closely corresponds to the period when the snow line is located at its highest elevation, thus when the snow line is a good indicator of the glacier equilibrium line. This indicates that this strong correlation results from the fact that the minimal average albedo values of the glacier contains considerable information regarding the relative share of areal surfaces between the ablation zone (i.e. ice with generally low albedo

  14. Linking glacier annual mass balance and glacier albedo retrieved from MODIS data

    Directory of Open Access Journals (Sweden)

    M. Dumont

    2012-07-01

    Full Text Available Albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODerate Imaging Spectroradiometer (MODIS on board the TERRA and AQUA satellites, provide a means to monitor glacier surface albedo. In this study, different methods to retrieve broadband glacier surface albedo from MODIS data are compared. The effect of multiple reflections due to the rugged topography and of the anisotropic reflection of snow and ice are particularly investigated. The methods are tested on the Saint Sorlin Glacier (Grandes Rousses area, French Alps. The accuracy of the retrieved albedo is estimated using both field measurements, at two automatic weather stations located on the glacier, and albedo values derived from terrestrial photographs. For summers 2008 and 2009, the Root Mean Square Deviation (RMSD between field measurements and the broadband albedo retrieved from MODIS data at 250 m spatial resolution was found to be 0.052 or about 10% relative error. The RMSD estimated for the MOD10 daily albedo product is about three times higher. One decade (2000–2009 of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin Glacier during the ablation season. The annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (average over the whole glacier surface observed with MODIS during the ablation season. A strong linear correlation exists between the two variables. Furthermore, the date when the average albedo of the whole glacier reaches a minimum closely corresponds to the period when the snowline is located at its highest elevation, thus when the snowline is a good indicator of the glacier equilibrium line. This indicates that this strong correlation results from the fact that the minimal average albedo values of the glacier contains a considerable information regarding the relative share of areal surfaces between the ablation zone (i.e. ice with generally

  15. Linking glacier annual mass balance and glacier albedo from MODIS data

    Science.gov (United States)

    Dumont, M.; Gardelle, J.; Arnaud, Y.; Guillot, A.; Sirguey, P.; Six, D.

    2012-04-01

    The albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODIS on board TERRA and AQUA, provide a means to monitor glacier albedo. In this study, different methods to retrieve broadband glacier albedo from MODIS data are compared. In particular, the effect of the multiple reflections due to the rugged topography and that of the anisotropic reflection of snow and ice are investigated. The methods are tested on the Saint Sorlin glacier (Grandes Rousses area, French Alps). The accuracy of the retrieved albedo is estimated using both field measurements and albedo derived from terrestrial photographs. The root mean square deviation between field measurements and the broadband albedo retrieved from MODIS pixels at 250m spatial resolution was found to be less than 0.06. One decade (2000-2010) of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin glacier during the ablation season. It appears that the albedo in the ablation area of the glacier does not exhibit any marked decreasing trend during the decade under study. This contrasts with the situation observed on other glaciers in the Alps. In addition, the annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (spatial averaged over the whole glacier) observed with MODIS during the ablation season. A high linear correlation exists between the two variables. Furthermore, the day on which the albedo reaches a minimum over the glacier closely corresponds to the day on which the snowline is found to be at its highest elevation, thus close to the glacier's equilibrium line. This indicates that the high correlation can be explained by the fact that this minimal albedo contains a high degree of information regarding the relative share of areal surfaces between the ablation zone (i.e., ice with a generally lower albedo) and the accumulation zone (i.e., snow with a relatively high albedo). This implies

  16. Application of terrestrial photogrammetry for the mass balance calculation on Montasio Occidentale Glacier (Julian Alps, Italy)

    Science.gov (United States)

    Piermattei, Livia; Carturan, Luca; Calligaro, Simone; Blasone, Giacomo; Guarnieri, Alberto; Tarolli, Paolo; Dalla Fontana, Giancarlo; Vettore, Antonio

    2014-05-01

    Digital elevation models (DEMs) of glaciated terrain are commonly used to measure changes in geometry and hence infer the mass balance of glaciers. Different tools and methods exist to obtain information about the 3D geometry of terrain. Recent improvements on the quality and performance of digital cameras for close-range photogrammetry, and the development of automatic digital photogrammetric processing makes the 'structure from motion' photogrammetric technique (SfM) competitive for high quality 3D models production, compared to efficient but also expensive and logistically-demanding survey technologies such as airborn and terrestrial laser scanner (TLS). The purpose of this work is to test the SfM approach, using a consumer-grade SLR camera and the low-cost computer vision-based software package Agisoft Photoscan (Agisoft LLC), to monitor the mass balance of Montasio Occidentale glacier, a 0.07km2, low-altitude, debris-covered glacier located in the Eastern Italian Alps. The quality of the 3D models produced by the SfM process has been assessed by comparison with digital terrain models obtained through TLS surveys carried out at the same dates. TLS technique has indeed proved to be very effective in determining the volume change of this glacier in the last years. Our results shows that the photogrammetric approach can produce point cloud densities comparable to those derived from TLS measurements. Furthermore, the horizontal and vertical accuracies are also of the same order of magnitude as for TLS (centimetric to decimetric). The effect of different landscape characteristics (e.g. distance from the camera or terrain gradient) and of different substrata (rock, debris, ice, snow and firn) was also evaluated in terms of SfM reconstruction's accuracy vs. TLS. Given the good results obtained on the Montasio Occidentale glacier, it can be concluded that the terrestrial photogrammetry, with the advantageous features of portability, ease of use and above all low costs

  17. Selenium removal and mass balance in a constructed flow-through wetland system.

    Science.gov (United States)

    Gao, S; Tanji, K K; Lin, Z Q; Terry, N; Peters, D W

    2003-01-01

    A field study on the removal of Se from agricultural subsurface drainage was conducted from May 1997 to February 2001 in the Tulare Lake Drainage District (TLDD) of San Joaquin Valley, California. A flow-through wetland system was constructed consisting of ten 15- x 76-m unlined cells that were continuously flooded and planted with either a monotype or combination of plants, including sturdy bulrush [Schoenoplectus robustus (Pursh) M.T. Strong], baltic rush (Juncus balticus Willd.), smooth cordgrass (Spartina alterniflora Loisel.), rabbitsfoot grass [Polypogon monspeliensis (L.) Desf.], salt-grass lDistichlis spicata (L.) Greene], cattail (Typha latifolia L.), tule [Schoenoplectus acutus (Muhl. ex Bigelow) A. Löve & D. Löve], and widgeon grass (Ruppia maritima L.). One cell had no vegetation planted. The objectives of this research were to evaluate Se removal efficiency of each wetland cell and to carry out a mass balance on Se. The inflow drainage water to the cells had average annual Se concentrations of 19 to 22 microg L(-1) dominated by selenate [Se(VI), 95%]. Average weekly water residence time varied from about 3 to 15 d for Cells 1 through 7 (target 7 d), 19 to 33 d for Cells 8 and 9 (target 21 d), and 13 to 18 d for Cell 10 (target 14 d). Average weekly Se concentration ratios of outflow to inflow ranged from 0.45 to 0.79 and mass ratio (concentration x water volume) from 0.24 to 0.52 for year 2000, that is, 21 to 55% reduction in Se concentration and 48 to 76% Se removal in mass by the wetland, respectively. The nonvegetated cell showed the least Se removal both in concentration and in mass. The global mass balance showed that on the average about 59% of the total inflow Se was retained within the cells and Se outputs were outflow (35%), seepage (4%), and volatilization (2%). Independent measurements of the Se retained in the cells totaled 53% of the total Se inflow: 33% in the surface (0-20 cm) sediment, 18% in the organic detrital layer above the

  18. Chemical tracers of episodic accretion in low-mass protostars

    CERN Document Server

    Visser, Ruud; Jorgensen, Jes K

    2015-01-01

    Aims: Accretion rates in low-mass protostars can be highly variable in time. Each accretion burst is accompanied by a temporary increase in luminosity, heating up the circumstellar envelope and altering the chemical composition of the gas and dust. This paper aims to study such chemical effects and discusses the feasibility of using molecular spectroscopy as a tracer of episodic accretion rates and timescales. Methods: We simulate a strong accretion burst in a diverse sample of 25 spherical envelope models by increasing the luminosity to 100 times the observed value. Using a comprehensive gas-grain network, we follow the chemical evolution during the burst and for up to 10^5 yr after the system returns to quiescence. The resulting abundance profiles are fed into a line radiative transfer code to simulate rotational spectra of C18O, HCO+, H13CO+, and N2H+ at a series of time steps. We compare these spectra to observations taken from the literature and to previously unpublished data of HCO+ and N2H+ 6-5 from th...

  19. Impact of Seminal Chemical Elements on the Oxidative Balance in Bovine Seminal Plasma and Spermatozoa.

    Science.gov (United States)

    Tvrdá, Eva; Lukáč, Norbert; Schneidgenová, Monika; Lukáčová, Jana; Szabó, Csaba; Goc, Zofia; Greń, Agnieszka; Massányi, Peter

    2013-01-01

    Mutual relationships between selected chemical elements (Na, K, Fe, Cu, Mg, and Zn), basic motility characteristics (motility and progressive motility), and markers of the oxidative balance (superoxide dismutase, catalase, glutathione, albumin, and malondialdehyde) were investigated in bovine seminal plasma and spermatozoa. Computer assisted sperm analysis was used to assess the motility parameters; mineral concentrations were determined by the voltammetric method and flame absorption spectrophotometry; antioxidants and malondialdehyde were evaluated by UV/VIS spectrophotometry. Concentrations of chemical elements in both seminal fractions were in the following descending order: Na > K > Zn > Mg > Fe > Cu. Higher amounts of all minerals and nonenzymatic antioxidants were detected in the seminal plasma (P Zn were positively correlated with the motility and antioxidant parameters (P < 0.05; P < 0.01; P < 0.001). Inversely, K exhibited the positive associations with malondialdehyde (P < 0.05). This study demonstrates that most chemical elements are integral components of bovine semen and are needed for the protection against oxidative stress development.

  20. Impact of Seminal Chemical Elements on the Oxidative Balance in Bovine Seminal Plasma and Spermatozoa

    Directory of Open Access Journals (Sweden)

    Eva Tvrdá

    2013-01-01

    Full Text Available Mutual relationships between selected chemical elements (Na, K, Fe, Cu, Mg, and Zn, basic motility characteristics (motility and progressive motility, and markers of the oxidative balance (superoxide dismutase, catalase, glutathione, albumin, and malondialdehyde were investigated in bovine seminal plasma and spermatozoa. Computer assisted sperm analysis was used to assess the motility parameters; mineral concentrations were determined by the voltammetric method and flame absorption spectrophotometry; antioxidants and malondialdehyde were evaluated by UV/VIS spectrophotometry. Concentrations of chemical elements in both seminal fractions were in the following descending order: Na > K > Zn > Mg > Fe > Cu. Higher amounts of all minerals and nonenzymatic antioxidants were detected in the seminal plasma (P<0.01; P<0.001, while higher MDA concentration and activity of enzymatic antioxidants were recorded in the cell lysates (P<0.01; P<0.001. Na, Fe, Cu, Mg, and Zn were positively correlated with the motility and antioxidant parameters (P<0.05; P<0.01; P<0.001. Inversely, K exhibited the positive associations with malondialdehyde (P<0.05. This study demonstrates that most chemical elements are integral components of bovine semen and are needed for the protection against oxidative stress development.

  1. Cloud effects on the surface energy and mass balance of Brewster Glacier, New Zealand

    Directory of Open Access Journals (Sweden)

    J. P. Conway

    2015-02-01

    Full Text Available A thorough understanding of the influence of clouds on glacier surface energy balance (SEB and surface mass balance (SMB is critical for forward and backward modelling of glacier–climate interactions. A validated 22 month time series of SEB/SMB was constructed for the ablation zone of the Brewster Glacier, using high quality radiation data to carefully evaluate SEB terms and define clear-sky and overcast conditions. A fundamental change in glacier SEB in cloudy conditions was driven by increased effective sky emissivity and surface vapour pressure, rather than the minimal change in air temperature and wind speed. During overcast conditions, positive net longwave radiation and latent heat fluxes allowed melt to be maintained through a much greater length of time compared to clear-sky conditions, and led to similar melt in each sky condition. The sensitivity of SMB to changes in air temperature was greatly enhanced in overcast compared to clear-sky conditions due to more frequent melt and the occurrence of precipitation, which enabled a strong accumulation–albedo feedback. During the spring and autumn seasons, the sensitivity during overcast conditions was strongest. There is a need to include the effects of atmospheric moisture (vapour, cloud and precipitation on melt processes when modelling glacier–climate interactions.

  2. Columbia Glacier stake location, mass balance, glacier surface altitude, and ice radar data, 1978 measurement year

    Science.gov (United States)

    Mayo, L.R.; Trabant, D.C.; March, Rod; Haeberli, Wilfried

    1979-01-01

    A 1 year data-collection program on Columbia Glacier, Alaska has produced a data set consisting of near-surface ice kinematics, mass balance, and altitude change at 57 points and 34 ice radar soundings. These data presented in two tables, are part of the basic data required for glacier dynamic analysis, computer models, and predictions of the number and size of icebergs which Columbia Glacier will calve into shipping lanes of eastern Prince William Sound. A metric, sea-level coordinate system was developed for use in surveying throughout the basin. Its use is explained and monument coordinates listed. A series of seven integrated programs for calculators were used in both the field and office to reduce the surveying data. These programs are thoroughly documented and explained in the report. (Kosco-USGS)

  3. Effects of Extratropical Cyclone Frequency and Intensity on mass balance of the Greenland Ice Sheet

    Science.gov (United States)

    Auger, J.; Birkel, S. D.; Maasch, K. A.; Mayewski, P. A.

    2014-12-01

    Significant Arctic-wide warming over the past decade is thought to result in part from a weakening of the equator-pole thermal gradient in the atmosphere. Francis and Vavrus (2012) and others link Arctic amplification, or enhanced Arctic warming, to decreasing extratropical cyclone (ETC) speeds, and increasing northward meridional heat transports. Here, we are using the latest high-resolution reanalysis models (ASR, JRA-55, CFSR, ERA-Interim, MERRA) to evaluate how Arctic amplification may be impacting the mass balance of the Greenland Ice Sheet. Our approach is to assess synoptic-scale changes in circulation as represented by changes in storm tracks and storm intensities in the North Atlantic region. As part of this work, we are validating the reanalysis models against existing accumulation, ablation, and meteorological station data available across Greenland, and therefore hope to gain insights on model performance and applicability to the problem domain.

  4. The recycling of heavy-metalcontaining wastes: Mass balances and economical estimations

    Science.gov (United States)

    Antrekowitsch, J.; Steinlechner, S.

    2011-01-01

    As environmental legislation has become stricter in recent decades, efforts for treating residues have also increased. The existing pyrometallurgical reprocessing methods for metal-containing wastes recover mainly only one valuable metal or produce low-grade byproducts. The aim of developing an economic process has to be the simultaneous recovery of more than one valuable metal and increased product quality. In the case of zinccontaining residues the goal has to be a high-quality zinc product. Moreover, the target is a nearly zero waste process and, accordingly, small amounts of generated residues. In this paper four possible secondary raw materials are compared regarding their mass and energy balance for a treatment in a carbon-containing metal bath. Furthermore, an evaluation of the economy is given for a neutral leaching residue, Waelz kiln slag, dust from secondary copper industry as well as an electro arc furnace dust from carbon steel production.

  5. Challenges for Greenland-wide mass balance from Cryosat-2 radar-altimetry

    DEFF Research Database (Denmark)

    Simonsen, Sebastian Bjerregaard; Forsberg, René; Sørensen, Louise Sandberg

    be interpreted as actual surface elevation changes seen from the satellite radar altimetry (Nilsson et al., 2015).Here, we investigate how to correct the elevation change observed from the ESA Cryosat-2 radar altimetry mission to derive elevation change of the air/snow interface of the Greenland ice sheet......As the Greenland ice sheet warms, a change in the structure of the upper snow/firn occurs. This change further induces changes in the reflective properties of the firn seen from satellite radar altimetry. If not identified as changes in the reflective properties of the firn, these may....... The elevation change of this “real” physical surface is crucial, if the goal is to derive Greenland mass balance as done for LiDAR missions.The investigations look into waveform parameters to correct for the observed bias between Radar and LiDAR observations when using Croysat-2 level-2 data. Based...

  6. New considerations on the mass and energy balances in one-dimensional two-phase flow at steady state

    Energy Technology Data Exchange (ETDEWEB)

    Collado, F.J. [Zaragoza Univ. (Spain). Dept. de Ingenieria Mecanica; Munoz, M. [Zaragoza Univ. (Spain). Dept. de Ingenieria Mecanica

    1997-08-01

    A new equation to be added to the classical mass balance expressions for two-phase flow is presented. It is based on the definition of new differential control volumes of variable length which are proportional to the gas velocity in a compressible flow. The new equation is equivalent to the gas-solids velocity ratio being constant throughout the duct, and it is used to derive a new expression of the energy balance for a two-phase, non-reacting flow. Through this energy balance, new correlations for the pressure drop in pneumatic conveying lines are obtained, showing an excellent agreement with experimental data from the high-pressure research facility of the Institute of Gas Technology, Chicago, IL. Finally, a more general equation, which is also valid for the mass balance of reacting flows, is supplied. (orig.)

  7. Source identification and mass balance studies of mercury in Lake An-dong, S. Korea

    Science.gov (United States)

    Han, J.; Byeon, M.; Yoon, J.; Park, J.; Lee, M.; Huh, I.; Na, E.; Chung, D.; Shin, S.; Kim, Y.

    2009-12-01

    In this study, mercury and methylmercury were measured in atmospheric, tributary, open-lake water column, sediment, planktons and fish samples in the catchments area of Lake An-dong, S. Korea. Lake An-dong, an artificial freshwater lake is located on the upstream of River Nak-dong. It has 51.5 km2 of open surface water and 1.33 year of hydraulic residence time. It is a source of drinking water for 0.3 million S. Koreans. Recently, the possibilities of its mercury contamination became an issue since current studies showed that the lake had much higher mercury level in sediment and certain freshwater fish species than any other lakes in S. Korea. This catchments area has the possibilities of historical mercury pollution by the location of more than 50 abandoned gold mines and Young-poong zinc smelter. The objective of this study was to develop a mercury mass balance and identify possible mercury sources in the lake. The results of this study are thus expected to offer valuable insights for the sources of mercury loading through the watershed. In order to estimate the mercury flux, TGM, RGM and particulate mercury were measured using TEKRAN 2537 at the five sites surrounding Lake An-dong from May, 2009 with wet and dry deposition. The fate and transport of mercury in water body were predicted by using EFDC (Environmental Dynamic Fluid Code) and Mercury module in WASP7 (Water quality analysis program) after subsequent distribution into water body, sediments, followed by bioaccumulation and ultimate uptake by humans. The mercury mass balance in Young-poong zinc smelter was also pre-estimated by measuring mercury content in zinc ores, emission gases, sludge, wastewater and products.

  8. Sensitivity of alpine glacial change detection and mass balance to sampling and datum inconsistencies

    Directory of Open Access Journals (Sweden)

    T. Goulden

    2013-01-01

    Full Text Available Glacial mass balance estimated through the geodetic method requires glacial surface coordinate observations from historical and contemporary sources. Contemporary observations and historical topographic maps are typically referenced to separate horizontal and vertical datums and observed with different sampling intervals. This research demonstrates the sensitivity of glacial change detection to the datum considerations and sampling schemes through case studies of Andrei, Bridge and Peyto glaciers in Western Canada. To simulate the procedure of observing the glacial surfaces, profile lines were sampled from Digital Elevation Model (DEMs on contour intervals for historical data and horizontal intervals for contemporary data. Profile lines from the following scenarios were compared: (1 different horizontal and vertical sampling schemes; (2 the horizontal datum was correctly reconciled but the vertical datum was not; (3 the vertical datum was correctly reconciled but the horizontal datum was not; (4 both the horizontal and vertical datums were correctly reconciled; and (5 both the horizontal and vertical datums were incorrectly reconciled. Vertical errors of up to 6.9 m, 6.0 m and 5.0 m were observed due to sampling effects and vertical errors of 22.2 m, 9.9 m and 55.0 m were observed due to datum inconsistencies on Bridge, Andrei and Peyto glacier respectively. Horizontal datum inconsistencies manifested as erratic levels of growth or downwasting along the glacial surface profile and vertical datum errors manifested as a consistent vertical offset. Datum inconsistencies were identified to contribute errors of up to 257.2 × 106 m3 (or 87% and 54.6 × 106 m3 (or 580% of estimated volume change below and above the equilibrium line respectively on Peyto Glacier. The results of this study provide an estimate of typical errors due to sampling constraints or datum inconsistencies as well as guidance for

  9. Geochemical cycling, mass balance, and Earth’s dynamic structure (Invited)

    Science.gov (United States)

    Allegre, C. J.

    2009-12-01

    The use of radiogenic tracers is now established as one of the standard methods (together with seismic tomography) to constrain Earth models. One of the advantages of radiogenic tracers is that they constrain not only present day structures, but also their historical evolution since the earliest time. A mandatory condition is to use not only one but all of the available isotopic systems, with their diverse cycling properties and different radioactive half-lives. Mass balances calculations are the basic tool which allows one to use quantitatively the various tracers. However, the inverse method approach, when applied to mass balance, is strongly non-linear, particularly for tracers with intermediate to short half lives. 142Nd, 82W, and 129Xe allows one to define a consistent model for the Present and past evolutions. Results point to a 3-layer model for the present mantle: an upper mantle with two layers separated by the 450 km discontinuity, and a lower mantle below the 670 km discontinuity. These layers all convect independently though none of them is fully isolated. They exchange matter and energy, not necessarily through the same process. For instance, most hotspots (though not all of them!) are boundary layer instabilities generated at the 670 km discontinuity, but there is important heat transfer from the lower mantle through megablobs. Recent results on the Hadean period are in agreement with core-mantle- atmosphere differentiation at 4444 My. The early crust was mostly anorthositic but has been recycled into the upper mantle within the first billion years. Formation of granitic continents started at 4300 My. 80% of their material was already present on the surface as acidic rocks by 2500 My. The reworking process involved in continental development increased continuously with time and today is the dominant process. Continents are now in a stage of steady state, with general addition of mantle and subducted continental material.

  10. Viewing the Chemical Evolution of the Quark-Gluon Plasma with Charge Balance Functions

    CERN Document Server

    Pratt, Scott

    2013-01-01

    Correlations from charge conservation are affected by when charge/anticharge pairs are created during the course of a relativistic heavy ion collision. For charges created early, balancing charges are typically separated by the order of one unit of spatial rapidity by the end of the collision, whereas those charges produced later in the collision are far more correlated. By analyzing correlations from STAR for different species, I show that one can distinguish the two separate waves of charge creation expected in a high-energy collision, one at early times when the QGP is formed and a second at hadronization. Further, I extract the density of up, down and strange quarks at in the QGP and find agreement at the 20% level with expectations for a chemically thermalized plasma.

  11. Mass and heat balances in the Santa Barbara Channel: estimation, description and forcing

    Science.gov (United States)

    Auad, Guillermo; Hendershott, Myrl C.; Winant, Clinton D.

    1999-01-01

    Current meter, temperature and wind observations from the 1984 MMS experiment are used to estimate the mass and heat budgets in the Santa Barbara Channel. The mass transports estimated at the western, eastern and southern boundaries of the channel are characterized by fluctuations whose energy is concentrated around three different periods: 5, 14 and 2.8 days respectively. These three transports fluctuate along with the dominant EOF modes obtained at those 3 entrances respectively. The mean transport passing through the channel from east to west is about 0.28 Sv. There are two frequency bands where winds and mass transports are coherent: 2.5-3.0 and 4.7-5.2 day bands. Winds on the northern shelf lead the transports in both bands by about 1.0 day. At the western half of the channel there is a recirculating (counterclockwise) mean transport of about 0.30 Sv. The time dependent part of the recirculating transport is coherent with the wind in the 4.7-5.2 day band where it also shows an absolute maximum of variance. The recirculating transport lags the local downwelling-favorable winds by about 1.5 day and seems to be the channel response to wind relaxations with respect to its most persistent upwelling-favorable state. The main mean balance in the channel-integrated heat equation is between the heat transport passing through the western mouth, which cools off the channel, and the heat transport caused by the mass transport (the transport heat flux), which warms up the channel. This latter transport results from the advection of the temperature difference between the channel boundaries (mainly east and west) by the mass transport. There are no two terms that dominate the heat equation for the time dependent heat transports, but it can be simplified by balancing the along channel heat divergence (heat transport passing through the mouth plus transport heat flux), the vertical heat flux and the local change of heat. A clear thermal-wind balance at the eastern and western

  12. Chemical ionization mass spectrometer (CIMS for ambient measurements of ammonia

    Directory of Open Access Journals (Sweden)

    D. R. Benson

    2010-03-01

    Full Text Available This study describes a chemical ionization mass spectrometer (CIMS for fast response, in-situ measurements for gas phase ammonia. Protonated ethanol ions were used as the ion-molecule reaction reagent. The CIMS sensitivity was estimated to be between 4–25 Hz/pptv with 30% uncertainty. The instrument background was below 1 ppbv and at lowest was 300 pptv. The uncertainty associated with the instrumental background was less than 30 pptv under the optimized experimental conditions. The time response was less than 30 s, and the detection limit was approximately 60 pptv. This CIMS was used to measure the ambient NH3 in Kent, Ohio, for several weeks throughout three seasons. The measured ammonia mixing ratios were usually at the sub-ppbv level, and higher during the spring (200±120 pptv than in the winter (60±75 pptv and fall (150±80 pptv.

  13. Mass transport measurements and modeling for chemical vapor infiltration

    Energy Technology Data Exchange (ETDEWEB)

    Starr, T.L.; Chiang, D.Y.; Fiadzo, O.G.; Hablutzel, N. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Materials Science and Engineering

    1997-12-01

    This project involves experimental and modeling investigation of densification behavior and mass transport in fiber preforms and partially densified composites, and application of these results to chemical vapor infiltration (CVI) process modeling. This supports work on-going at ORNL in process development for fabrication of ceramic matrix composite (CMC) tubes. Tube-shaped composite preforms are fabricated at ORNL with Nextel{trademark} 312 fiber (3M Corporation, St. Paul, MN) by placing and compressing several layers of braided sleeve on a tubular mandrel. In terms of fiber architecture these preforms are significantly different than those made previously with Nicalon{trademark} fiber (Nippon Carbon Corp., Tokyo, Japan) square weave cloth. The authors have made microstructure and permeability measurements on several of these preforms and a few partially densified composites so as to better understand their densification behavior during CVI.

  14. Mass Casualty Chemical Incident Operational Framework, Assessment and Best Practices

    Energy Technology Data Exchange (ETDEWEB)

    Greenwalt, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hibbard, W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-08-09

    Emergency response agencies in most US communities are organized, sized, and equipped to manage those emergencies normally expected. Hospitals in particular do not typically have significant excess capacity to handle massive numbers of casualties, as hospital space is an expensive luxury if not needed. Unfortunately this means that in the event of a mass casualty chemical incident the emergency response system will be overwhelmed. This document provides a self-assessment means for emergency managers to examine their response system and identify shortfalls. It also includes lessons from a detailed analysis of five communities: Baltimore, Boise, Houston, Nassau County, and New Orleans. These lessons provide a list of potential critical decisions to allow for pre-planning and a library of best practices that may be helpful in reducing casualties in the event of an incident.

  15. The first long-term and continuous measurements of firn mass-balance and compaction on the Greenland Ice Sheet

    Science.gov (United States)

    Howat, I. M.; Behar, A.; de la Peña, S.; Price, S. F.; Desilets, D.; Crowell, J. M.; Thanga, J.; Womack, G.

    2015-12-01

    Direct, continuous measurements of ice sheet surface mass balance are lacking, particularly in the accumulation zone where the surface snow and firn varies in density. Nearly all of our knowledge of surface mass variability comes from snow pit and ice core stratigraphy, providing annual resolution with relatively large uncertainties that are inadequate for constraining meteorological models. Further, little information is available on how the density of the firn layer changes with time, hampering efforts to estimate mass change from altimetry measurements. Since the spring of 2012 we have obtained continuous measurements of changes in firn column density and, since spring 2015, mass balance at multiple sites in the percolation zone of the Jakobshavn Isbrae catchment in western Greenland. Surface mass balance is obtained from both snow scale and cosmic ray sensors, providing cross-validation. Following a description of the multiple technologies employed, we assess variations in compaction and surface mass balance in relation to meteorological variables. We then compare our measurements to model estimates and conclude with recommendations for continued and expanded observational activities.

  16. Tissue proteomics using chemical immobilization and mass spectrometry.

    Science.gov (United States)

    Shah, Punit; Zhang, Bai; Choi, Caitlin; Yang, Shuang; Zhou, Jianying; Harlan, Robert; Tian, Yuan; Zhang, Zhen; Chan, Daniel W; Zhang, Hui

    2015-01-15

    Proteomics analysis is important for characterizing tissues to gain biological and pathological insights, which could lead to the identification of disease-associated proteins for disease diagnostics or targeted therapy. However, tissues are commonly embedded in optimal cutting temperature medium (OCT) or are formalin-fixed and paraffin-embedded (FFPE) in order to maintain tissue morphology for histology evaluation. Although several tissue proteomic analyses have been performed on FFPE tissues using advanced mass spectrometry (MS) technologies, high-throughput proteomic analysis of OCT-embedded tissues has been difficult due to the interference of OCT in the MS analysis. In addition, molecules other than proteins present in tissues further complicate tissue proteomic analysis. Here, we report the development of a method using chemical immobilization of proteins for peptide extraction (CIPPE). In this method, proteins are chemically immobilized onto a solid support; interferences from tissues and OCT embedding are removed by extensive washing of proteins conjugated on the solid support. Peptides are then released from the solid phase by proteolysis, enabling MS analysis. This method was first validated by eliminating OCT interference from a standard protein, human serum albumin, where all of the unique peaks contributed by OCT contamination were eradicated. Finally, this method was applied for the proteomic analysis of frozen and OCT-embedded tissues using iTRAQ (isobaric tag for relative and absolute quantitation) labeling and two-dimensional liquid chromatography tandem mass spectrometry. The data showed reproducible extraction and quantitation of 10,284 proteins from 3996 protein groups and a minimal impact of OCT embedding on the analysis of the global proteome of the stored tissue samples.

  17. Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2015-02-01

    This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream.

  18. Estimation of the Greenland ice sheet surface mass balance during 20th and 21st centuries

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2008-04-01

    Full Text Available Results from a regional climate simulation (1970–2006 over the Greenland ice sheet (GrIS reveals that more than 97% of the interannual variability of the modelled Surface Mass Balance (SMB can be explained by the GrIS summer temperature anomaly and the GrIS annual precipitation anomaly. This multiple regression is then used to empirically estimate the GrIS SMB since 1900 from climatological time series. The projected SMB changes in the 21st century are investigated with the set of simulations performed with atmosphere-ocean general circulation models (AOGCMs of the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR4. These estimates show that the high surface mass loss rates of recent years are not unprecedented in the GrIS history of the last hundred years. The minimum SMB rate seems to have occurred earlier in the 1930s. The AOGCMs project that the SMB rate of the 1930s would be common at the end of 2100. The temperature would be higher than in the 1930s but the increase of accumulation in the 21st century would partly offset the acceleration of surface melt due to the temperature increase. However, these assumptions are based on an empirical multiple regression only validated for recent/current climatic conditions, and the accuracy and time homogeneity of the data sets and AOGCM results used in these estimations constitute a large uncertainty.

  19. Re-assessment of recent (2008–2013 surface mass balance over Dome Argus, Antarctica

    Directory of Open Access Journals (Sweden)

    Minghu Ding

    2016-04-01

    Full Text Available At Dome Argus, East Antarctica, the surface mass balance (SMB from 2008 to 2013 was evaluated using 49 stakes installed across a 30×30 km area. Spatial analysis showed that at least 12 and 20 stakes are needed to obtain reliable estimates of SMB at local scales (a few hundred square metres and regional scales (tens of square kilometres, respectively. The estimated annual mean SMB was 22.9±5.9 kg m−2 yr−1, including a net loss by sublimation of −2.22±0.02 kg m−2 yr−1 and a mass gain by deposition of 1.37±0.01 kg m−2 yr−1. Therefore, ca. 14.3% of precipitation was modified after deposition, which should be considered when interpreting snow or ice core records produced by future drilling projects. The surface snow density and SMB in the western portion of Dome Argus are higher than in other areas, and these differences are likely related to the katabatic wind, which is strengthened by topography in this sector. A new digital elevation model (DEM of Dome Argus was generated, confirming that both peaks of the dome can be considered as the summit of the East Antarctic Ice Sheet. Findings from this study should be valuable for validating SMB estimates obtained from regional climate models and DEMs established using remote-sensing data.

  20. Glacier mass balance in high-arctic areas with anomalous gravity

    Science.gov (United States)

    Sharov, A.; Rieser, D.; Nikolskiy, D.

    2012-04-01

    All known glaciological models describing the evolution of Arctic land- and sea-ice masses in changing climate treat the Earth's gravity as horizontally constant, but it isn't. In the High Arctic, the strength of the gravitational field varies considerably across even short distances under the influence of a density gradient, and the magnitude of free air gravity anomalies attains 100 mGal and more. On long-term base, instantaneous deviations of gravity can have a noticeable effect on the regime and mass budget of glaciological objects. At best, the gravity-induced component of ice mass variations can be determined on topographically smooth, open and steady surfaces, like those of arctic planes, regular ice caps and landfast sea ice. The present research is devoted to studying gravity-driven impacts on glacier mass balance in the outer periphery of four Eurasian shelf seas with a very cold, dry climate and rather episodic character of winter precipitation. As main study objects we had chosen a dozen Russia's northernmost insular ice caps, tens to hundreds of square kilometres in extent, situated in a close vicinity of strong gravity anomalies and surrounded with extensive fields of fast and/or drift ice for most of the year. The supposition about gravitational forcing on glacioclimatic settings in the study region is based on the results of quantitative comparison and joint interpretation of existing glacier change maps and available data on the Arctic gravity field and solid precipitation. The overall mapping of medium-term (from decadal to half-centennial) changes in glacier volumes and quantification of mass balance characteristics in the study region was performed by comparing reference elevation models of study glaciers derived from Russian topographic maps 1:200,000 (CI = 20 or 40 m) representing the glacier state as in the 1950s-1980s with modern elevation data obtained from satellite radar interferometry and lidar altimetry. Free-air gravity anomalies were

  1. Mass balance of decabromodiphenyl ethane and decabromodiphenyl ether in a WWTP.

    Science.gov (United States)

    Ricklund, Niklas; Kierkegaard, Amelie; McLachlan, Michael S; Wahlberg, Cajsa

    2009-01-01

    The additive flame retardant decabromodiphenyl ethane (deBDethane) has been identified in the environment, but little is known about its environmental behaviour. It is structurally similar to decabromodiphenyl ether (decaBDE), making it conceivable that it may also become an environmental contaminant of concern. In this study a mass balance of deBDethane and decaBDE was undertaken in a modern WWTP in Stockholm serving 7.05x10(5) inhabitants. Flow proportional samples of plant influent and effluent as well as daily grab samples of digested sludge were collected during two 7-day periods. All samples were analyzed with GC/HRMS using isotope labelled internal standards. The mean mass flows of deBDethane and decaBDE to the WWTP were 6.0 g per day and 55 g per day, respectively. Of this, less than 1% of both BFRs left the WWTP via the effluent, while the bulk was sequestered into the digested sludge, where the mean concentrations of deBDethane and decaBDE were 81 and 800 ng g(-1)d.wt., respectively. It is concluded that the transfer efficiency of deBDethane from the technosphere to the environment via WWTPs is similar to that of decaBDE.

  2. Chemically peculiar stars as seen with 2MASS

    CERN Document Server

    Herdin, A; Netopil, M

    2016-01-01

    The chemically peculiar (CP) stars of the upper main sequence are well suited for investigating the impact of magnetic fields and diffusion on the surface layers of slowly rotating stars. They can even be traced in the Magellanic Clouds and are important to the understanding of the stellar formation and evolution. A systematic investigation of the near-infrared (NIR), 2MASS JHKs, photometry for the group of CP stars has never been performed. Nowadays, there is a great deal of data available in the NIR that reach very large distances. It is therefore very important for CP stars to be unambiguously detected in the NIR region and for these detections to be used to derive astrophysical parameters (age and mass) by applying isochrone fitting. Furthermore, we investigated whether the CP stars behave in a different way to normal-type stars in the various photometric diagrams. For our analysis, we carefully compiled a sample of CP and apparently normal (non-peculiar) type stars. Only stars for which high-quality (i.e...

  3. Balanced biochemical reactions: a new approach to unify chemical and biochemical thermodynamics.

    Directory of Open Access Journals (Sweden)

    Antonio Sabatini

    Full Text Available A novel procedure is presented which, by balancing elements and electric charge of biochemical reactions which occur at constant pH and pMg, allows assessing the thermodynamics properties of reaction Δ(rG'⁰, Δ(rH'⁰, Δ(rS'⁰ and the change in binding of hydrogen and magnesium ions of these reactions. This procedure of general applicability avoids the complex calculations required by the use of the Legendre transformed thermodynamic properties of formation Δ(fG'⁰, Δ(fH'⁰ and Δ(fS'⁰ hitherto considered an obligatory prerequisite to deal with the thermodynamics of biochemical reactions. As a consequence, the term "conditional" is proposed in substitution of "Legendre transformed" to indicate these thermodynamics properties. It is also shown that the thermodynamic potential G is fully adequate to give a criterion of spontaneous chemical change for all biochemical reactions and then that the use of the Legendre transformed G' is unnecessary. The procedure proposed can be applied to any biochemical reaction, making possible to re-unify the two worlds of chemical and biochemical thermodynamics, which so far have been treated separately.

  4. MEMS device for mass market gas and chemical sensors

    Science.gov (United States)

    Kinkade, Brian R.; Daly, James T.; Johnson, Edward A.

    2000-08-01

    Gas and chemical sensors are used in many applications. Industrial health and safety monitors allow companies to meet OSHA requirements by detecting harmful levels of toxic or combustible gases. Vehicle emissions are tested during annual inspections. Blood alcohol breathalizers are used by law enforcement. Refrigerant leak detection ensures that the Earth's ozone layer is not being compromised. Industrial combustion emissions are also monitored to minimize pollution. Heating and ventilation systems watch for high levels of carbon dioxide (CO2) to trigger an increase in fresh air exchange. Carbon monoxide detectors are used in homes to prevent poisoning from poor combustion ventilation. Anesthesia gases are monitored during a patients operation. The current economic reality is that two groups of gas sensor technologies are competing in two distinct existing market segments - affordable (less reliable) chemical reaction sensors for consumer markets and reliable (expensive) infrared (IR) spectroscopic sensors for industrial, laboratory, and medical instrumentation markets. Presently high volume mass-market applications are limited to CO detectros and on-board automotive emissions sensors. Due to reliability problems with electrochemical sensor-based CO detectors there is a hesitancy to apply these sensors in other high volume applications. Applications such as: natural gas leak detection, non-invasive blood glucose monitoring, home indoor air quality, personal/portable air quality monitors, home fire/burnt cooking detector, and home food spoilage detectors need a sensor that is a small, efficient, accurate, sensitive, reliable, and inexpensive. Connecting an array of these next generation gas sensors to wireless networks that are starting to proliferate today creates many other applications. Asthmatics could preview the air quality of their destinations as they venture out into the day. HVAC systems could determine if fresh air intake was actually better than the air

  5. Occurrence and simulation of trihalomethanes in swimming pool water: A simple prediction method based on DOC and mass balance.

    Science.gov (United States)

    Peng, Di; Saravia, Florencia; Abbt-Braun, Gudrun; Horn, Harald

    2016-01-01

    Trihalomethanes (THM) are the most typical disinfection by-products (DBPs) found in public swimming pool water. DBPs are produced when organic and inorganic matter in water reacts with chemical disinfectants. The irregular contribution of substances from pool visitors and long contact time with disinfectant make the forecast of THM in pool water a challenge. In this work occurrence of THM in a public indoor swimming pool was investigated and correlated with the dissolved organic carbon (DOC). Daily sampling of pool water for 26 days showed a positive correlation between DOC and THM with a time delay of about two days, while THM and DOC didn't directly correlate with the number of visitors. Based on the results and mass-balance in the pool water, a simple simulation model for estimating THM concentration in indoor swimming pool water was proposed. Formation of THM from DOC, volatilization into air and elimination by pool water treatment were included in the simulation. Formation ratio of THM gained from laboratory analysis using native pool water and information from field study in an indoor swimming pool reduced the uncertainty of the simulation. The simulation was validated by measurements in the swimming pool for 50 days. The simulated results were in good compliance with measured results. This work provides a useful and simple method for predicting THM concentration and its accumulation trend for long term in indoor swimming pool water.

  6. The Multiplexed Chemical Kinetic Photoionization Mass Spectrometer: A New Approach To Isomer-resolved Chemical Kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Osborne, David L.; Zou, Peng; Johnsen, Howard; Hayden, Carl C.; Taatjes, Craig A.; Knyazev, Vadim D.; North, Simon W.; Peterka, Darcy S.; Ahmed, Musahid; Leone, Stephen R.

    2008-08-28

    We have developed a multiplexed time- and photon-energy?resolved photoionizationmass spectrometer for the study of the kinetics and isomeric product branching of gasphase, neutral chemical reactions. The instrument utilizes a side-sampled flow tubereactor, continuously tunable synchrotron radiation for photoionization, a multi-massdouble-focusing mass spectrometer with 100percent duty cycle, and a time- and positionsensitive detector for single ion counting. This approach enables multiplexed, universal detection of molecules with high sensitivity and selectivity. In addition to measurement of rate coefficients as a function of temperature and pressure, different structural isomers can be distinguished based on their photoionization efficiency curves, providing a more detailed probe of reaction mechanisms. The multiplexed 3-dimensional data structure (intensity as a function of molecular mass, reaction time, and photoionization energy) provides insights that might not be available in serial acquisition, as well as additional constraints on data interpretation.

  7. Mass, energy and material balances of SRF production process. Part 1: SRF produced from commercial and industrial waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2014-08-01

    This paper presents the mass, energy and material balances of a solid recovered fuel (SRF) production process. The SRF is produced from commercial and industrial waste (C&IW) through mechanical treatment (MT). In this work various streams of material produced in SRF production process are analyzed for their proximate and ultimate analysis. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. Here mass balance describes the overall mass flow of input waste material in the various output streams, whereas material balance describes the mass flow of components of input waste stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. A commercial scale experimental campaign was conducted on an MT waste sorting plant to produce SRF from C&IW. All the process streams (input and output) produced in this MT plant were sampled and treated according to the CEN standard methods for SRF: EN 15442 and EN 15443. The results from the mass balance of SRF production process showed that of the total input C&IW material to MT waste sorting plant, 62% was recovered in the form of SRF, 4% as ferrous metal, 1% as non-ferrous metal and 21% was sorted out as reject material, 11.6% as fine fraction, and 0.4% as heavy fraction. The energy flow balance in various process streams of this SRF production process showed that of the total input energy content of C&IW to MT plant, 75% energy was recovered in the form of SRF, 20% belonged to the reject material stream and rest 5% belonged with the streams of fine fraction and heavy fraction. In the material balances, mass fractions of plastic (soft), plastic (hard), paper and cardboard and wood recovered in the SRF stream were 88%, 70%, 72% and 60% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC), rubber material and non

  8. Mass, energy and material balances of SRF production process. Part 2: SRF produced from construction and demolition waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2014-11-01

    In this work, the fraction of construction and demolition waste (C&D waste) complicated and economically not feasible to sort out for recycling purposes is used to produce solid recovered fuel (SRF) through mechanical treatment (MT). The paper presents the mass, energy and material balances of this SRF production process. All the process streams (input and output) produced in MT waste sorting plant to produce SRF from C&D waste are sampled and treated according to CEN standard methods for SRF. Proximate and ultimate analysis of these streams is performed and their composition is determined. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. By mass balance means the overall mass flow of input waste material stream in the various output streams and material balances mean the mass flow of components of input waste material stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. The results from mass balance of SRF production process showed that of the total input C&D waste material to MT waste sorting plant, 44% was recovered in the form of SRF, 5% as ferrous metal, 1% as non-ferrous metal, and 28% was sorted out as fine fraction, 18% as reject material and 4% as heavy fraction. The energy balance of this SRF production process showed that of the total input energy content of C&D waste material to MT waste sorting plant, 74% was recovered in the form of SRF, 16% belonged to the reject material and rest 10% belonged to the streams of fine fraction and heavy fraction. From the material balances of this process, mass fractions of plastic (soft), paper and cardboard, wood and plastic (hard) recovered in the SRF stream were 84%, 82%, 72% and 68% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC) and rubber material was found in the reject material

  9. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.;

    2010-01-01

    in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign...... elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by surface density modelling. The firn compaction and density models are driven by a dynamically downscaled simulation of the HIRHAM5 regional climate model using ERA-Interim reanalysis lateral......ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...

  10. Biomass Allocation and Leaf Chemical Defence in Defoliated Seedlings of Quercus serrata with Respect to Carbon–Nitrogen Balance

    OpenAIRE

    Hikosaka, Kouki; TAKASHIMA, TERUYUKI; Kabeya, Daisuke; HIROSE, TADAKI; Kamata, Naoto

    2005-01-01

    • Background and Aims Both nutrient availability and defoliation affect the carbon–nutrient balance in plants, which in turn influences biomass allocation (e.g. shoot-to-root ratio) and leaf chemical composition (concentration of nitrogen and secondary compounds). In this study it is questioned whether defoliation alters biomass allocation and chemical defence in a similar fashion to the response to nutrient deficiency.

  11. Surface Elevation Changes in West Antarctica from Satellite Altimetry: Mass Balance Implications

    Science.gov (United States)

    Zwally, H. Jay; Brenner, Anita C.; Cornejo, Helen; Koblinsky, Chester J. (Technical Monitor)

    2001-01-01

    Time-series of surface elevation change, which are constructed from 7-years (1992-1999) of ERS-1 and 2 satellite radar altimeter data of Antarctica, show significant seasonal, inter-annual, and long-term changes. Elevation time-series are created from altimeter crossovers among 90-day data periods on a 50 km grid to 81.5 degrees S and fit with a multivariate linear/sinusoidal function to give the average rate of elevation change (dH/dt) and account for seasonal changes. On the major Ronne, Filchner, and Ronne ice shelves, the dH/dt are small or near zero. In contrast, the ice shelves of the Antarctic Peninsula and along the West Antarctic coast appear to be thinning significantly, with a 23 +/- 3 cm a(exp -1) surface elevation decrease on the Larsen ice shelf and a 65 +/- 4 cm a(exp -1) decrease on the Dotson ice shelf. Significant elevation decreases are obtained over most of the drainage basins of the Pine Island and Thwaites glaciers. Significant increases are obtained over most of the other grounded ice in Marie Byrd Land, the Antarctic Peninsula, and Coates Land. Over the sector from 85 degrees W to 115 degrees W, which includes the Pine Island and Thwaites basins, the average elevation is significantly decreasing by 8.1 cm a(exp -1). The corresponding ice thickness change is about -11 cm a(exp -1), with a corresponding mass loss of 82 Gt a(exp -1), and a 0.22 mm a(exp -1) contribution to global sea level rise. In terms of elevation change, the decrease in the Pine Island-Thwaites sector is largely balanced by the increase in the Marie Byrd Land, but only balanced by about 1/4 in terms of ice thickness change and contribution to sea level rise. The overall average elevation change for the grounded ice is + 1.2 cm a(exp -1). Using an average bedrock uplift of 2.5 cm a(exp -1), implies an average ice thickness decrease of 1.3 cm a(exp -1), a mass loss of 22 Gt a(exp -1), and a 0.06 mm a(exp -1) contribution to global sea level rise.

  12. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960–2014

    OpenAIRE

    2015-01-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes compaction, meltwater percolation, and refreezing. The model is forced with surface mass fluxes and temperature from a regional climate model for the period 1960–2014. The model results...

  13. Mass balance of the Greenland ice sheet – a study of ICESat data, surface density and firn compaction modelling

    Directory of Open Access Journals (Sweden)

    L. S. Sørensen

    2010-10-01

    Full Text Available ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat altimetry data.

    Four different methods for deriving the elevation changes from the ICESat altimetry data set are used. This multi method approach gives an understanding of the complexity associated with deriving elevation changes from the ICESat altimetry data set.

    The altimetry can not stand alone in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by surface density modelling. The firn compaction and density models are driven by a dynamically downscaled simulation of the HIRHAM5 regional climate model using ERA-Interim reanalysis lateral boundary conditions.

    We find an annual mass loss of the Greenland ice sheet of 210 ± 21 Gt yr−1 in the period from October 2003 to March 2008. This result is in good agreement with other studies of the Greenland ice sheet mass balance, based on different remote sensing techniques.

  14. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960-2014

    NARCIS (Netherlands)

    Kuipers Munneke, P.; Ligtenberg, S. R M; Noël, B. P Y; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; Van Den Broeke, M. R.

    2015-01-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes compac

  15. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    NARCIS (Netherlands)

    van Angelen, J.H.; Lenaerts, J.T.M.; Lhermitte, S.; Fettweis, X.; Kuipers Munneke, P.; van den Broeke, M.R.; van Meijgaard, E.; Smeets, C.J.P.P.

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover,

  16. Estimating Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    NARCIS (Netherlands)

    Fettweis, X.; Franco, B.; Tedesco, M.; van Angelen, J.H.; Lenaerts, J.T.M.; van den Broeke, M.R.; Gallee, H

    2012-01-01

    We report future projections of Surface Mass Balance (SMB) over the Greenland ice sheet (GrIS) obtained with the regional climate model MAR, forced by the outputs of three CMIP5 General Circulation Models (GCMs) when considering two different warming scenarios (RCP 4.5 and RCP 8.5). The GCMs selecte

  17. Contemporary (1960–2012) Evolution of the Climate and Surface Mass Balance of the Greenland Ice Sheet

    NARCIS (Netherlands)

    van Angelen, J. H.; van den Broeke, M. R.; Wouters, B.; Lenaerts, J. T M

    2013-01-01

    We assess the contemporary (1960–2012) surface mass balance (SMB) of the Greenland ice sheet (GrIS), its individual components and trends. We use output of the high-resolution (11 km) regional atmospheric climate model (RACMO2), evaluated with automatic weather stations and GRACE data. A persistent

  18. Process monitoring and modeling of a continuous pharmaceutical from powder to tablet process Line using a mass & energy balance

    DEFF Research Database (Denmark)

    Beer, Thomas De; Mortier, Séverine Thérèse F.C.; Gernaey, Krist

    2014-01-01

    The intention to shift from batch to continuous production processes within the pharmaceutical industry enhances the need to monitor and control the process in-line and real-time to continuously guarantee the end-product quality. Mass and energy balances have been successfully applied to a drying...

  19. Mobile Element Reservoir Mass Balance on Mars: New SIMS and EMP Data from Lonar and Mistastin Craters

    Science.gov (United States)

    Newsom, H. E.; Hagerty, J. J.; Shearer, C. W.

    2002-01-01

    New SIMS data for mobile elements in Lonar Crater clay minerals are remarkably similar to data for alteration material in the Lafayette Mars meteorite. This work strongly supports the use of terrestrial analogues for Mars, including a new mass balance model for mobile elements through time. Additional information is contained in the original extended abstract.

  20. Mass spectrometric analysis of chemical warfare agents in support of a chemical terrorist event

    Energy Technology Data Exchange (ETDEWEB)

    Hancock, J.R.; D' Agostino, P.A.; Chenier, C.L. [Defence R and D Canada Suffield, Medicine Hat, AB (Canada)

    2003-07-01

    Chemical warfare (CW) agents are considered to be any chemicals which, through their chemical action on life processes can cause death, temporary incapacitation or permanent harm to humans or animals. In Canada, the probability of a CW terrorist attack is low despite the catastrophic consequences that would result from such an attack. The three levels of government would be responding to such an event. CW agent response training for all levels of government is offered at Defence R and D Canada-Suffield. Appropriate samples must be collected for analysis in a laboratory, as such an event would lead to a criminal investigation. Research into new methods for the identification of CW agents is being conducted by the analytical laboratory at Defence R and D Canada-Suffield. Gas chromatography and mass spectrometry (GC-MS) are being used extensively to separate and characterize CW agents in organic extracts. In the case of aqueous samples, another method might be more appropriate, since additional sample handling is required before GC-MS analysis can be performed. Minimal sample handling is required when using liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS) for direct analysis of CW agents. The authors demonstrated the use of LC-ESI-MS for analyzing CW agents and their hydrolysis products in aqueous samples. For the analysis of nerve agents and phosphonic acids in soil, comparable or superior results to organic extraction and GC-MS were obtained for aqueous extractions followed by LC-ESI-MS. The combination of GC-MS and LC-ESI-MS for the analysis of mustard related compounds in soil extracts from a former mustard storage area showed that the two methods are complementary in this situation. 9 refs., 3 tabs., 5 figs.

  1. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-06-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual-mean near-surface air temperature increase over Greenland of ~2 C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice-sheet would eventually be eliminated.

  2. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-11-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual mean near-surface air temperature increase over Greenland of ~ 2°C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice sheet would eventually be eliminated.

  3. Pilot scale study on steam explosion and mass balance for higher sugar recovery from rice straw.

    Science.gov (United States)

    Sharma, Sandeep; Kumar, Ravindra; Gaur, Ruchi; Agrawal, Ruchi; Gupta, Ravi P; Tuli, Deepak K; Das, Biswapriya

    2015-01-01

    Pretreatment of rice straw on pilot scale steam explosion has been attempted to achieve maximum sugar recovery. Three different reaction media viz. water, sulfuric acid and phosphoric acid (0.5%, w/w) were explored for pretreatment by varying operating temperature (160, 180 and 200°C) and reaction time (5 and 10min). Using water and 0.5% SA showed almost similar sugar recovery (∼87%) at 200 and 180°C respectively. However, detailed studies showed that the former caused higher production of oligomeric sugars (13.56g/L) than the later (3.34g/L). Monomeric sugar, followed the reverse trend (7.83 and 11.62g/L respectively). Higher oligomers have a pronounced effect in reducing enzymatic sugar yield as observed in case of water. Mass balance studies for water and SA assisted SE gave total saccharification yield as 81.8% and 77.1% respectively. However, techno-economical viability will have a trade-off between these advantages and disadvantages offered by the pretreatment medium.

  4. Radium mass balance and submarine groundwater discharge in Sepetiba Bay, Rio de Janeiro State, Brazil

    Science.gov (United States)

    Smoak, Joseph M.; Sanders, Christian J.; Patchineelam, Sambasiva R.; Moore, Willard S.

    2012-11-01

    Radium-226 and 228Ra activities were determined in water samples from within and adjacent to Sepetiba Bay, Rio de Janeiro State (Brazil) in 1998, 2005 and 2007. Surface waters in Sepetiba Bay were substantially higher in 226Ra and 228Ra compared to ocean end member samples. Using the residence time of water in the bay we calculated the flux required to maintain the observed enrichment over the ocean end members. We then applied a radium mass balance to estimate the volume of submarine groundwater discharge (SGD) into the bay. The estimates of SGD into Sepetiba Bay (in 1010 L day-1) were 2.56, 3.75, and 1.0, respectively for 1998, 2005, and 2007. These estimates are equivalent to approximately 1% of the total volume of the bay each day or 50 L m-2 day-1. It is likely that a substantial portion of the SGD in Sepetiba Bay consists of infiltrated seawater. This large flux of SGD has the potential to supply substantial quantities of nutrients, carbon and metals into coastal waters. The SGD found here is greater than what is typically found in SGD studies along the eastern United States and areas with similar geologic characteristics. Considering there are many coastal areas around the world like Sepetiba Bay, this could revise upward the already important contribution of SGD to coastal as well as oceanic budgets.

  5. Mass, energy, entropy and exergy rate balance in a ranque-hilsh vortex tube

    Directory of Open Access Journals (Sweden)

    Edorta Carrascal

    2013-12-01

    Full Text Available The purpose of this paper is to exhibit a laboratory practicum designed for the subject of Thermodynamics at the Department of Thermal Engineering of the University of the Basque Country. With reference to one of the problems stated in the text of Moran, Shapiro, Boettner, Bailey (2012, the balances of mass, energy, entropy and exergy are applied in a particular Control Volume, and the ideal gas model is used. Using a Ranque-Hilsh vortex tube (Ranque, 1934, the division of a compressed air flow into two streams at a lower pressure is achieved; one hot  whose temperature can exceed 100 °C and another cold that can reach temperatures below -40 °C. Therefore an air flow is divided into two, one hot and one cold stream, without any thermal interaction with hot or cold focuses. The vortex tube operation can serve to expose the bases of the first and second law of thermodynamics. Even, this practical lab can be used to give sense to one of the most known theoretical experiments in thermodynamics, such as the one of Maxwell's demon (Lewins & Bejan, 1999; Liew, Zeegers, Kuerten & Michalek, 2012. On the other hand once a compressed air source is provided, the material needed to prepare the lab is simple and affordable and it has a very interesting and suggestive appeal.

  6. Nutrient mass balance for the Albemarle-Pamlico Drainage Basin, North Carolina and Virginia, 1990

    Science.gov (United States)

    McMahon, G.; Woodside, M.D.

    1997-01-01

    A 1990 nitrogen and phosphorus mass balance calculated for eight National Stream Quality Accounting Network (NASQAN) basins in the Albemarle-Pamlico Drainage Basin indicated the importance of agricultural nonpoint sources of nitrogen and phosphorus and watershed nitrogen retention and processing capabilities. Basin total nitrogen and phosphorus input estimates were calculated for atmospheric deposition (which averaged 27 percent of total nitrogen inputs and 22 percent of total phosphorus inputs); crop fertilizer (27 and 25 percent); animal-waste (22 and 50 percent, respectively); point sources (3 percent each of total nitrogen and total phosphorus inputs); and biological nitrogen fixation (21 percent of total nitrogen inputs). Highest in-stream nitrogen and phosphorus loads were measured in predominantly agricultural drainage areas. Intermediate loads were observed in mixed agricultural/urban drainage areas; the lowest loads were measured in mixed agricultural/forested drainage areas. The difference between the sum of the nutrient input categories and the sum of the instream nutrient loads and crop-harvest nutrient removal was assigned to a residual category for the basin. The residual category averaged 51 percent of total nitrogen inputs and 54 percent of total phosphorus inputs.

  7. An updated and quality controlled surface mass balance dataset for Antarctica

    Directory of Open Access Journals (Sweden)

    V. Favier

    2012-09-01

    Full Text Available We present an updated and quality controlled surface mass balance (SMB database for the Antarctic ice sheet. We retrieved a total of 5284 SMB data documented with important meta-data, to which a filter was applied to discard data with limited spatial and temporal representativeness, too small measurement accuracy, or lack of quality control. A total of 3438 reliable data was obtained, which is about four times more than by applying the same data filtering process to previously available databases. New important data with high spatial resolution are now available over long traverses, and at low elevation in some areas. However, the quality control led to a considerable reduction in the spatial density of data in several regions, particularly over West Antarctica. Over interior plateaus, where the SMB is low, the spatial density of measurements remained high. This quality controlled dataset was compared to results from ERA-Interim reanalysis to assess model representativeness over Antarctica, and also to identify large areas where data gaps impede model validation. Except for very few areas (e.g. Adelie Land, the elevation range between 200 m and 1000 m a.s.l. is not correctly sampled in the field, and measurements do not allow a thorough validation of models in regions with complex topography, where the highest scattering of SMB values is reported. Clearly, increasing the spatial density of field measurements at low elevations, in the Antarctic Peninsula and in West Antarctica remains a scientific priority.

  8. Computer Simulation of the Mass and Energy Balance during Gasification of Sugarcane Bagasse

    Directory of Open Access Journals (Sweden)

    Anthony Anukam

    2014-01-01

    Full Text Available This paper investigated the mass and energy balance of the gasification of sugarcane bagasse using computer simulation. The key parameters and gasifier operating conditions were investigated in order to establish their impact on gas volume and conversion efficiency of the gasification process. The heating value of sugarcane bagasse was measured and found to be 17.8 MJ/kg which was used during calculation of the conversion efficiency of the gasification process. Fuel properties and gasifier design parameters were found to have an impact on conversion efficiency of the gasification process of sugarcane bagasse. The moisture content of sugarcane bagasse was varied by 1.14%, 15%, and 25%, respectively. Optimum conversion efficiency was achieved at low moisture content (1.14% after computer simulation of the gasification process. The volume of carbon monoxide increased at low moisture content. It was also found that maximum conversion efficiency was achieved at reduced particle diameter (6 cm and at reduced throat diameter (10 cm and throat angle (25°, respectively, after these parameters were varied. Temperature of input air was also found to have an impact on the conversion efficiency of the gasification process as conversion efficiency increased slightly with increasing temperature of input air.

  9. Fluxes and the mass balance of mercury in Augusta Bay (Sicily, southern Italy)

    Science.gov (United States)

    Salvagio Manta, Daniela; Bonsignore, Maria; Oliveri, Elvira; Barra, Marco; Tranchida, Giorgio; Giaramita, Luigi; Mazzola, Salvatore; Sprovieri, Mario

    2016-11-01

    The flux (Φ) of mercury (Hg) at the sediment-seawater interface was investigated in Augusta Bay (southern Italy) where uncontrolled industrial discharge from one of the most important chlor-alkali plant in Europe has caused significant negative effects on the environment. Hg fluxes were measured by the deployment of in-situ benthic chamber. The obtained value of 1.3 kmol y-1 clearly emphasizes the role of the sediments as source of Hg for the overlying water column. Moreover, Hg concentrations in the outflowing bottom waters were measured to estimate the export of this pollutant from Augusta Bay to the open sea. The calculated value of 0.54 kmol y-1, corresponding to ∼4% of the anthropogenic input of Hg from coastal point/diffuse sources to the Mediterranean Sea (12.5 kmol y-1; Rajar et al., 2007; UNEP-MAP, 2001), assigns this area a crucial role in the Hg inventory of the entire Mediterranean basin. Finally, a consistent and robust mass balance for Hg in Augusta Bay was provided by combining the obtained data with Hg fluxes at seawater-atmosphere interface.

  10. Stable climate and surface mass balance in Svalbard over 1979–2013 despite the Arctic warming

    Directory of Open Access Journals (Sweden)

    C. Lang

    2014-08-01

    Full Text Available With the help of the regional climate model MAR forced by the ERA-Interim reanalysis (MARERA and the MIROC5 global model (MARMIROC5 from the CMIP5 database, we have modelled the climate and surface mass balance of Svalbard at a 10 km resolution over 1979–2013. The integrated total SMB over Svalbard modelled by MARERA is negative (−1.6 Gt yr−1 with a large interannual variability (7.1 Gt but, unlike over Greenland, there has been no acceleration of the surface melt over the past 35 years because of the recent change in atmospheric circulation bringing northerly flows in summer over Svalbard, contrasting the recent observed Arctic warming. However, in 2013, the atmospheric circulation changed to a southwesterly flow over Svalbard causing a record of melt, SMB (−20.4 Gt yr−1 and summer temperature. MIROC5 is significantly colder than ERA-Interim over 1980–2005 but MARMIROC5 is able to improve the near-surface MIROC5 results by simulating not significant SMB differences with MARERA over 1980–2005. On the other hand, MIROC5 does not represent the recent atmospheric circulation shift in summer and induces in MARMIROC5 a significant trend of decreasing SMB (−0.6 Gt yr−2 over 1980–2005.

  11. A Chemical Ionization Mass Spectrometer for ambient measurements of Ammonia

    Directory of Open Access Journals (Sweden)

    D. R. Benson

    2010-08-01

    Full Text Available This study presents a chemical ionization mass spectrometer (CIMS for fast response, in-situ measurements of gas phase ammonia (NH3. The NH3 background level detected with the CIMS ranged between 0.3–1 ppbv, with an uncertainty of 30 pptv under optimized conditions. The instrument sensitivity varied from 4–25 Hz/pptv for >1 MHz of reagent ion signals (protonated ethanol ions, with a 30% uncertainty estimated based on variability in calibration signals. The CIMS detection limit for NH3 was ~60 pptv at a 1 min integration time (3 sigma. The CIMS time response was <30 s. This new NH3-CIMS has been used for ambient measurements in Kent, Ohio, for several weeks throughout three seasons. The measured NH3 mixing ratios were usually at the sub-ppbv level and higher in spring (200 ± 120 pptv than in winter (60 ± 75 pptv and fall (150 ± 80 pptv. High emissions of SO2 from power plants in this region, and thus possible high acidity of aerosol particles, may explain these low NH3 mixing ratios in general.

  12. Freshwater mass balance and exchange of water masses with the open sea: the Mljet Lakes (Croatia, Adriatic Sea)

    Science.gov (United States)

    Martincic, Urska; Bezak, Nejc; Zagar, Dusan; Makovec, Tihomir; Lucic, Davor; Onofri, Vladimir; Malacic, Vlado

    2016-04-01

    Two karstic seawater lakes (Veliko - Big and Malo - Small Lake) located in the National Park Mljet on the Mljet Island in Croatia were investigated in this study. The Small and the Big Lake cover 0.25 and 1.45 km2, respectively. The two lakes are connected to each other and to the sea by narrow channels. The connecting channel between the Big Lake and the sea is 12 m wide and 3 m deep. The connection to the Small Lake leads through another artificial channel (2.7 m wide and 0.8 m deep). The average salinity of the Big and the Small lake is 37.75 and 36.9, respectively, and the average salinity of the open sea is 38.5. While previous studies have been conducted due to the lakes' unique ecosystem and the karstic characteristics of the area, the main aim of this study was to determine the freshwater mass balance and exchange of water masses with the nearby sea. Several measurement campaigns were performed between 2008 and 2015 when meteorological parameters as well as salinity, water temperature and water velocities in both lakes and the channels were observed. A perpetual year was determined using available meteorological data. The contribution of the surface runoff to both lakes was modelled using the hydrological rainfall-runoff HEC-HMS model. Curve number parameter was estimated using the CLC Corine Land cover and geomorphological maps. Evaporation from the lake was calculated using the Verburg, Kondo and Coare equations. We found that the annual evaporation approximately equals the annual rainfall to the lake surface (cca. 550-600 mm). From the hydrological model and the difference between precipitation and evaporation from the lake surface we calculated the annual net excess of freshwater between 0.5 106 and 0.7 106 m3. The average salinity in both lakes is lower than the salinity in the sea; therefore, we hypothesize that the excess water should be discharged either through the channel between the Big Lake and the open sea or through underwater karstic sink

  13. Mass balance evolution of Martial Este Glacier, Tierra del Fuego (Argentina for the period 1960–2099

    Directory of Open Access Journals (Sweden)

    M. Buttstädt

    2009-12-01

    Full Text Available The Martial Este Glacier in southern Tierra del Fuego was studied in order to estimate the surface mass balance from 1960 until 2099. For this reason a degree-day model was calibrated. Air temperature and precipitation data obtained from 3 weather stations as well as glaciological measurements were applied. The model was driven using a vertical air temperature gradient of 0.69 K/100 m, a degree-day factor for snow of 4.7 mm w.e. K−1 day−1, a degree-day factor for ice of 9.4 mm w.e. K−1 day−1 and a precipitation gradient of 22%/100 m. For the purpose of surface mass balance reconstruction for the time period 1960 until 2006 a winter vertical air temperature gradient of 0.57 K/100 m and a summer vertical air temperature gradient of 0.71 K/100 m were added as well as a digital terrain model. The key finding is an almost continuous negative mass balance of −772 mm w.e. a−1 throughout this period. While the calculation of the mass balance for the period 1960–2006 is based on instrumental records, the mass balance for the years 2007 until 2099 was estimated based on the IPCC SRES A2-scenario. To accomplish this estimation, the dataset of the global climate model HadCM3 was statistically downscaled to fit local conditions at Martial Este Glacier. Subsequently, the downscaled air temperature and precipitation were applied to a volume-area scaling glacier change model. Findings reveal an enduring deglaciation resulting in a surface area reduction of nearly 93% until 2099. This implicates that the Martial Este Glacier might be melted off at the beginning of the 22nd century.

  14. Application of Lithium Attachment Mass Spectrometry for Knudsen Evaporation and Chemical Ionisation Mass Spectrometry (KEMS, CIMS)

    Science.gov (United States)

    Bannan, Thomas; Booth, A. Murray; Alfarra, Rami; Bacak, Asan; Pericval, Carl

    2016-04-01

    Lithium ion attachment mass spectrometry provides a non-specific, non-fragmenting and sensitive method for detection of volatile species in the gas phase. The design, manufacture, and results from lithium ion attachment ionisation sources for two mass spectrometry systems are presented. Trace gas analysis is investigated using a modified Chemical Ionization Mass Spectrometer (CIMS) and vapour pressure (VP) measurements using a modified Knudsen Effusion Mass Spectrometer (KEMS) are presented. The Li+ modified CIMS provided limits of detection of 4 ppt for acetone, 0.2 ppt for formic acid, 15 ppt for nitric acid and 120 ppt from ammonia. Despite improvements, the problem of burnout remained persistent. The Li+ CIMS would unlikely be suitable for field or aircraft work, but could be appropriate for certain lab applications. The KEMS currently utilizes an electron impact (EI) ionisation source which provides a highly sensitive source, with the drawback of fragmentation of ionized molecules (Booth et al., 2009). Using Li+ KEMS the VP of samples can be measured without fragmentation and can therefore be used to identify VPs of individual components in mixtures. The validity of using Li+ for determining the VP of mixtures was tested by making single component VP measurements, which showed good agreement with EI measurements of Poly ethylene glycol (PEG) 3 and PEG 4, both when individually measured and when mixed. The Li+ KEMS was then used to investigate a system of atmospheric relevance, α-pinene secondary organic aerosol, generated in a reaction chamber (Alfarra et al., 2012). The VPs of the individual components from this generated sample are within the range we expect for compounds capable of partitioning between the particle and gas phase of an aerosol (0.1-10-5 Pa). Li+ source has a calculated sensitivity approximately 75 times less than that of EI, but the lack of fragmentation using the Li+ source is a significant advantage.

  15. Improved GRACE regional mass balance estimates of the Greenland ice sheet cross-validated with the input-output method

    Science.gov (United States)

    Xu, Zheng; Schrama, Ernst J. O.; van der Wal, Wouter; van den Broeke, Michiel; Enderlin, Ellyn M.

    2016-04-01

    In this study, we use satellite gravimetry data from the Gravity Recovery and Climate Experiment (GRACE) to estimate regional mass change of the Greenland ice sheet (GrIS) and neighboring glaciated regions using a least squares inversion approach. We also consider results from the input-output method (IOM). The IOM quantifies the difference between the mass input and output of the GrIS by studying the surface mass balance (SMB) and the ice discharge (D). We use the Regional Atmospheric Climate Model version 2.3 (RACMO2.3) to model the SMB and derive the ice discharge from 12 years of high-precision ice velocity and thickness surveys. We use a simulation model to quantify and correct for GRACE approximation errors in mass change between different subregions of the GrIS, and investigate the reliability of pre-1990s ice discharge estimates, which are based on the modeled runoff. We find that the difference between the IOM and our improved GRACE mass change estimates is reduced in terms of the long-term mass change when using a reference discharge derived from runoff estimates in several subareas. In most regions our GRACE and IOM solutions are consistent with other studies, but differences remain in the northwestern GrIS. We validate the GRACE mass balance in that region by considering several different GIA models and mass change estimates derived from data obtained by the Ice, Cloud and land Elevation Satellite (ICESat). We conclude that the approximated mass balance between GRACE and IOM is consistent in most GrIS regions. The difference in the northwest is likely due to underestimated uncertainties in the IOM solutions.

  16. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.;

    2010-01-01

    boundary conditions. We find an annual mass loss of the Greenland ice sheet of 210 ± 21 Gt yr-1 in the period from October 2003 to March 2008. This result is in good agreement with other studies of the Greenland ice sheet mass balance, based on different remote sensing techniques.......ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...... altimetry data. Four different methods for deriving the elevation changes from the ICESat altimetry data set are used. This multi method approach gives an understanding of the complexity associated with deriving elevation changes from the ICESat altimetry data set. The altimetry can not stand alone...

  17. Application of a contaminant mass balance method at an old landfill to assess the impact on water resources

    DEFF Research Database (Denmark)

    Thomsen, Nanna Isbak; Milosevic, Nemanja; Bjerg, Poul Løgstrup

    2012-01-01

    linking soil and groundwater contamination to surface water pollution are required. This paper presents a method which provides an estimate of the contaminant mass discharge, using a combination of a historical investigation and contaminant mass balance approach. The method works at the screening level...... of chloride to the small Risby Stream down gradient of the landfill was approximately 31kg/year. The contaminant mass balance method worked well for chloride and dissolved organic carbon, but the uncertainties were elevated for ammonium due to substantial spatial variability in the source composition......Old and unlined landfill sites pose a risk to groundwater and surface water resources. While landfill leachate plumes in sandy aquifers have been studied, landfills in clay till settings and their impact on receiving water bodies are not well understood. In addition, methods for quantitatively...

  18. Greenland ice sheet surface mass-balance modeling in a 131-year perspective, 1950-2080

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.; Hiemstra, Christopher [COLORADO STATE UNIV.; Christensen, Jens [DANISH METEOROLOGICAL INS.

    2009-01-01

    Fluctuations in the Greenland Ice Sheet (GrIS) surface mass-balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise. SnowModel, a state-of-the-art snow-evolution modeling system, was used to simulate variations in the GrIS melt extent, surface water balance components, changes in SMB, and freshwater influx to the ocean. The simulations are based on the IPCC scenario AlB modeled by the HIRHAM4 RCM (using boundary conditions from ECHAM5 AOGCM) from 1950 through 2080. In-situ meteorological station (GC-Net and WMO DMI) observations from inside and outside the GrIS were used to validate and correct RCM output data before it was used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirm the model's robustness. We simulated a {approx}90% increase in end-of-summer surface melt extent (0.483 x 10{sup 6} km{sup 2}) from 1950 to 2080, and a melt index (above 2,000-m elevation) increase of 138% (1.96 x 10{sup 6} km{sup 2} x days). The greatest difference in melt extent occured in the southern part of the GrIS, and the greatest changes in the number of melt days was seen in the eastern part of the GrIS ({approx}50-70%) and was lowest in the west ({approx}20-30%). The rate of SMB loss, largely tied to changes in ablation processes, lead to an enhanced average loss of 331 km{sup 3} from 1950 to 2080, an average 5MB level of -99 km{sup 3} for the period 2070-2080. GrIS surface freshwater runoff yielded an eustatic rise in sea level from 0.8 {+-} 0.1 (1950-1959) to 1.9 {+-} 0.1 mm (2070-2080) sea level equivalent (SLE) y{sup -1}. The accumulated GrIS freshwater runoff contribution from surface melting equaled 160 mm SLE from 1950 through 2080.

  19. Mass balance and surface velocity reconstructions of two reference Caucasus glaciers

    Science.gov (United States)

    Rybak, Oleg; Kaminskaia, Mariia; Kutuzov, Stanislav; Lavrentiev, Ivan; Morozova, Polina; Popovnin, Victor; Rybak, Elena

    2016-04-01

    Total glacial volume of the Greater Caucasus exceeds 40 cubic km and its area exceeds 1 thousand square km. During the 20th century, mountain glaciers at the Greater Caucasus were continuously degrading. According to various estimates, their area reduced more than one-third and their volume almost by half. The process of degradation was accompanied by growing population and economical development on surrounding territories. In the 21st century under proceeding global warming, a tendency of shrinking of area and volume of glaciation is obviously expected to continue. Working out of strategy of sustainable economic development of the region is the main motivation for elaboration of predictions of glaciers' evolution in the changing environment. Growing demand of fresh water is the basic challenge for the local economy, and efficient planning of water resources is impossible without knowing future state of glaciation. Therefore our research aims at obtaining accurate evaluation of probable future change of the most prominent mountain glaciers of the Greater Caucasus in forthcoming decades and at studying impacts of changing characteristics of glaciation on the run-off in the area. Initially, we focus on two so-called reference glaciers - Marukh (Western Caucasus) and Djankuat (Central Caucasus). Intensive field observations on both of them have been conducted during the last half of the century and essential amount of detailed relevant information has been collected on their geometry change and on mass balance. Besides, meteorological measurements were episodically carried out directly on the glaciers providing enough data for correlation of the local weather conditions with the data from the closest meteorological stations. That is why studying of response of Marukh and Djankuat on the environmental change can be accurately verified, which is crucial for understanding mechanisms driving evolution of large glaciated area in the Caucasus. As the instrument of research

  20. The mass balance of production and consumption: Supporting policy-makers for aquatic food security

    Science.gov (United States)

    Lopes, A. S.; Ferreira, J. G.; Vale, C.; Johansen, J.

    2017-03-01

    This work addresses divergences between data on consumption and availability for wild-caught and farmed fish, and normalisation of reported production data, to support integrated fisheries and aquaculture management. The methodologies developed, centred on improved parameterisation and on mass balance closure, were tested in two case studies: (i) the cod fishery in Europe, with particular emphasis on Iceland and the United Kingdom; and (ii) the overall balance of aquatic products for Portugal, the ICES member with the most diverse range of landed marine species. Data for consumption, Illegal, Unreported, or Unregulated (IUU) catch, and official availability statistics were used to identify discrepancies between consumption and official availability data. The identification of discrepancies between supply and demand, when coupled with source-discriminated data, showed a pattern where products with no unmet demand tend to display a considerable IUU percentage-above 9% in three cases (hake, sardine, and horse mackerel). By contrast with fished products with an over-met demand such as cod (144%) and sardine (124%), farmed species display low Optimal Consumption Level (OCL) satisfaction. Atlantic salmon, gilthead seabream, and European seabass register 45%, 58% and 44% respectively; this suggests a considerable unmet demand for these products and/or a high volume of undeclared fish reaching consumers, which may be due to the lack of landings control that exists for wild-caught fish. Improvements to production estimates using live-weight coefficients illustrate the impacts of seafood processing. Different processing methods can generate variations in live-weight estimates, leading to errors in officially reported data, and expose the limitations of the current statistical methods. As an example, the corrected per capita consumption for Portugal for 2014 (the latest FAO data) increases from 57 to 66 kg ind-1 y-1, which places the country as the second-greatest consumer in

  1. Comparison of Balance, Proprioception and Skeletal Muscle Mass in Total Hip Replacement Patients With and Without Fracture: A Pilot Study

    Science.gov (United States)

    2016-01-01

    Objective To determine whether there was a difference in balance, proprioception, and skeletal muscle mass among patients who undergo hip fracture surgery relative to and elective total hip replacement (THR). Methods Thirty-one THR patients were enrolled. The patients were categorized into two groups: fracture group (n=15) and non-fracture group (n=16). Berg Balance Scale (BBS) was used to balance the proprioception of the hip joint while a joint position sense (JPS) test was used to evaluate it. Skeletal muscle mass was measured by bioelectrical impedance analysis and expressed as a skeletal muscle mass index (SMI). Quality of life (QOL) was also assessed using a 36-item short form health survey (SF-36). All tests were assessed at 3 months after the surgery. An independent t-test was used to compare the fracture group and non-fracture group. Spearman correlation was used to identify the correlation of each variable. Results In an independent t-test, the BBS score of patients undergoing elective surgery was higher than the BBS score of patients undergoing hip fracture surgery. There was a significant correlation between the BBS and JPS score after a THR. SMI also correlated with the score of BBS. Conclusion It seems that THR patients undergoing surgery for a hip fracture might have more trouble balancing than elective THR patients. Therefore THR patients undergoing hip fracture surgery might need more care during rehabilitation. PMID:28119837

  2. Calcium Mass Balance during Citrate Hemodialysis: A Randomized Controlled Trial Comparing Normal and Low Ionized Calcium Target Ranges

    Science.gov (United States)

    Orsag, Alesa; Ponikvar, Rafael; Buturovic-Ponikvar, Jadranka

    2016-01-01

    Background Regional citrate anticoagulation (RCA) during hemodialysis interferes with calcium homeostasis. Optimal ionized calcium (iCa) target range during RCA and consequent calcium balance are unknown. Methods In a randomized controlled trial (ACTRN12613001029785) 30 chronic hemodialysis patients were assigned to normal (1.1–1.2 mmol/) or low (0.95–1.05 mmol/l) iCa target range during a single hemodialysis with RCA. The primary outcome was calcium mass balance during the procedure, using a partial spent dialysate collection method; magnesium mass balance was also measured. Intact parathormone (iPTH), total calcium (tCa) and magnesium were measured before and after procedures. Results Mean iCa during procedures was significantly different in the two groups (1.12±0.06 in normal and 1.06±0.07 mmol/l in low iCa group, p <0.001), resulting in different tCa (2.18±0.22 vs. 1.95±0.17, p = 0.003) after the procedure. Mean delivered calcium during the procedure was 58.3±4.8 mmol in the normal and 51.5±8.2 mmol in the low iCa group (p = 0.010), which resulted in a significantly higher mean positive calcium mass balance of 14.6±8.3 mmol (584±333 mg) per procedure in normal as compared to 7.2±8.5 mmol (290±341 mg) in low iCa group (p = 0.024). Linear mixed effects model showed a significant interaction effect of time and iCa target range group on iPTH, i.e. a significant increase in iPTH in the low as compared to normal iCa target group (p = 0.008). Magnesium mass balance was mildly negative and comparable in both groups. Conclusions Low iCa target range resulted in a significantly less positive calcium mass balance, but in a significant increase in iPTH. To achieve a more neutral calcium balance, we recommend allowing a mild hypocalcemia during hemodialysis with RCA, especially when it is used for prolonged periods. PMID:28030601

  3. Preliminary Investigation into Pyrotechnic Chemical Products via Mass Spectrometry Techniques

    Science.gov (United States)

    2015-03-11

    via Mass Spectrometry Techniques 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Jonathan Dilger, Eric...undesirable side reactions within the combustion. Mass spectrometry (MS) enables the rapid analysis of these products with instrumentation that offers...predicted by theory. 15. SUBJECT TERMS mass spectrometry , gas chromatography, pyrolysis, combustion products, pyrotechnics 16. SECURITY CLASSIFICATION OF

  4. Chloride-mass-balance for predicting increased recharge after land-use change

    Energy Technology Data Exchange (ETDEWEB)

    Gee, G.W.; Zhang, Z.F.; Tyler, S.W.; Albright, W.H.; Singleton, M.J.

    2004-02-23

    The chloride-mass-balance (CMB) method has been used extensively to estimate recharge in arid and semi-arid environments. Required data include estimates of annual precipitation, total chloride input (from dry fallout and precipitation), and pore-water chloride concentrations. Typically, CMB has been used to estimate ancient recharge but recharge from recent land-use change has also been documented. Recharge rates below a few mm/yr are reliably detected with CMB; however, estimates above a few mm/yr appear to be less reliable. We tested the CMB method against 26 years of drainage from a 7.6-m-deep lysimeter at a simulated waste-burial ground, located on the Department of Energy s Hanford Site in southeastern Washington State, USA where land-use change has increased recharge rates. Measured drainage from the lysimeter for the past 26 years averaged 62 mm/yr. Precipitation averaged 190 mm/yr with an estimated chloride input of 0.225 mg/L. Initial pore-water chloride concentration was 88 mg/L and decreased to about 6 mg/L after 26 years, while the drainage water decreased to less than 1 mg/L. A recharge estimate made using chloride concentrations in drain water was within 20 percent of the measured drainage rate. In contrast, recharge estimates using 1:1 (water: soil) extracts were lower than actual by factors ranging from 2 to 8 or more. The results suggest that when recharge is above a few mm/yr, soil water extracts can lead to unreliable estimates of recharge. For conditions of elevated recharge, direct sampling of pore water is the preferred method, because chloride concentrations are often 20 to 50 times higher in directly-sampled pore water than in pore-water extracts.

  5. Mercury dynamics of an arctic tundra ecosystem in northern Alaska: a mass balance

    Science.gov (United States)

    Obrist, D.; Helmig, D.; Agnan, Y.; Hedge, C.; Moore, C. W.; Paxton, D.; Hueber, J.

    2015-12-01

    To constrain the mercury (Hg) mass balance of a tundra ecosystem, we measured atmospheric mercury (Hg) concentrations and surface-atmosphere exchange at Toolik Field Station (68° 38' N) beginning September 2014. We also conducted automated measurements of gaseous Hg in soil pores and snow interstitial air to quantify gas exchange between soils, snow, and the atmosphere; and characterized wet and dry deposition and plant-derived Hg inputs. Results show that atmospheric Hg concentrations peak in winter, decrease in spring, and show summertime minima. Oxidized atmospheric Hg was below detection limits (0.05 ng m-3) indicating no significant dry deposition. Summertime minima of atmospheric Hg concentrations were associated with depositional fluxes of gaseous Hg (up to 2.8 ng m-2 hr-1; measured by a gradient method) that emerged after complete snowmelt. In contrast, gaseous Hg fluxes were below detection limits when snowpack was present; this was supported by in situ snowpack measurements and in contrast to commonly observed gaseous emissions from temperate snowpacks. The cumulative annual gaseous deposition flux of mercury was 12 µg m-2, in similar range as plant-derived inputs (17 µg m-2 yr-1) which we consider the major reason for observed gaseous Hg sink. Wet deposition was extremely low (<1 µg m-2 yr-1) compared to other sites. Hg concentrations in plants and soils are similar to levels found at temperate sites, but terrestrial pool sizes are large in comparison ranging around 400 g ha-1. The results suggest that: atmospheric Hg exposure is low at this site; that deposition is dominated by plant-derived deposition; and that significant Hg pools accumulate in tundra soils, likely driven by strong retention and low re-emissions after deposition. The high Hg soil pool sizes and key role of plant-productivity for Hg deposition may indicate a high sensitivity to climate change, in particular to permafrost soil thawing and increased growing season length.

  6. A Mass balance mercury budget for a mine-dominated lake: Clear Lake, California

    Science.gov (United States)

    Suchanek, T.H.; Cooke, J.; Keller, K.; Jorgensen, S.; Richerson, P.J.; Eagles-Smith, C. A.; Harner, E.J.; Adam, D.P.

    2009-01-01

    The Sulphur Bank Mercury Mine (SBMM), active intermittently from 1873-1957 and now a USEPA Superfund site, was previously estimated to have contributed at least 100 metric tons (105 kg) of mercury (Hg) into the Clear Lake aquatic ecosystem. We have confirmed this minimum estimate. To better quantify the contribution of the mine in relation to other sources of Hg loading into Clear Lake and provide data that might help reduce that loading, we analyzed Inputs and Outputs of Hg to Clear Lake and Storage of Hg in lakebed sediments using a mass balance approach. We evaluated Inputs from (1) wet and dry atmospheric deposition from both global/regional and local sources, (2) watershed tributaries, (3) groundwater inflows, (4) lakebed springs and (5) the mine. Outputs were quantified from (1) efflux (volatilization) of Hg from the lake surface to the atmosphere, (2) municipal and agricultural water diversions, (3) losses from out-flowing drainage of Cache Creek that feeds into the California Central Valley and (4) biotic Hg removal by humans and wildlife. Storage estimates include (1) sediment burial from historic and prehistoric periods (over the past 150-3,000 years) from sediment cores to ca. 2.5m depth dated using dichloro diphenyl dichloroethane (DDD), 210Pb and 14C and (2) recent Hg deposition in surficial sediments. Surficial sediments collected in October 2003 (11 years after mine site remediation) indicate no reduction (but a possible increase) in sediment Hg concentrations over that time and suggest that remediation has not significantly reduced overall Hg loading to the lake. Currently, the mine is believed to contribute ca. 322-331 kg of Hg annually to Clear Lake, which represents ca. 86-99% of the total Hg loading to the lake. We estimate that natural sedimentation would cover the existing contaminated sediments within ca. 150-300 years. ?? 2008 Springer Science+Business Media B.V.

  7. Mass balance for POPs in hazardous and municipal solid waste incinerators.

    Science.gov (United States)

    Van Caneghem, J; Block, C; Van Brecht, A; Wauters, G; Vandecasteele, C

    2010-02-01

    The amount of different persistent organic pollutants (POPs) in the input of waste incinerators was compared to that in the output. Three cases were considered: a rotary kiln incinerating hazardous waste, a grate furnace incinerating municipal solid waste (MSW) and the same grate furnace co-incinerating plastics of waste of electrical and electronic equipment (WEEE) and automotive shredder residue (ASR) with MSW. The mass balance for PCBs in the rotary kiln indicates that these POPs are destroyed effectively during incineration. The grate furnace can be a sink or source of PCDD/Fs and PCBs depending on the concentrations in the incinerated waste. In order to compare the total amount of POPs in input and output, a methodology was developed whereby the amount of POPs was weighed according to minimal risk doses (MRDs) or cancer potency factors. For both incinerators the PCDD/Fs, PCBs and polyaromatic hydrocarbons (PAHs) are the main contributors to total weighed POP output. In MSW, the PCDD/Fs, PBDD/Fs and polybrominated diphenylethers (PBDEs) are the main contributors to the weighed POP input. The ratios of the weighed POP-input over -output clearly indicate that the rotary kiln incinerating hazardous waste is a weighed POP sink. The grate furnace incinerating MSW is a weighed POP sink or source depending on the POP-concentrations in the waste, but the difference between output and input is rather limited. When e.g. ASR and plastics of WEEE, containing high concentrations of PBDEs and PCBs, are co-incinerated in the grate furnace, it is clearly a weighed POP sink.

  8. The modelled surface mass balance of the Antarctic Peninsula at 5.5 km horizontal resolution

    Science.gov (United States)

    van Wessem, J. M.; Ligtenberg, S. R. M.; Reijmer, C. H.; van de Berg, W. J.; van den Broeke, M. R.; Barrand, N. E.; Thomas, E. R.; Turner, J.; Wuite, J.; Scambos, T. A.; van Meijgaard, E.

    2016-02-01

    This study presents a high-resolution (˜ 5.5 km) estimate of surface mass balance (SMB) over the period 1979-2014 for the Antarctic Peninsula (AP), generated by the regional atmospheric climate model RACMO2.3 and a firn densification model (FDM). RACMO2.3 is used to force the FDM, which calculates processes in the snowpack, such as meltwater percolation, refreezing and runoff. We evaluate model output with 132 in situ SMB observations and discharge rates from six glacier drainage basins, and find that the model realistically simulates the strong spatial variability in precipitation, but that significant biases remain as a result of the highly complex topography of the AP. It is also clear that the observations significantly underrepresent the high-accumulation regimes, complicating a full model evaluation. The SMB map reveals large accumulation gradients, with precipitation values above 3000 mm we yr-1 in the western AP (WAP) and below 500 mm we yr-1 in the eastern AP (EAP), not resolved by coarser data sets such as ERA-Interim. The average AP ice-sheet-integrated SMB, including ice shelves (an area of 4.1 × 105 km2), is estimated at 351 Gt yr-1 with an interannual variability of 58 Gt yr-1, which is dominated by precipitation (PR) (365 ± 57 Gt yr-1). The WAP (2.4 × 105 km2) SMB (276 ± 47 Gt yr-1), where PR is large (276 ± 47 Gt yr-1), dominates over the EAP (1.7 × 105 km2) SMB (75 ± 11 Gt yr-1) and PR (84 ± 11 Gt yr-1). Total sublimation is 11 ± 2 Gt yr-1 and meltwater runoff into the ocean is 4 ± 4 Gt yr-1. There are no significant trends in any of the modelled AP SMB components, except for snowmelt that shows a significant decrease over the last 36 years (-0.36 Gt yr-2).

  9. Waste assay and mass balance for the decontamination and volume reduction system at LANL

    Energy Technology Data Exchange (ETDEWEB)

    Gruetzmacher, Kathleen M.; Ferran, Scott G.; Garner, Scott E.; Romero, Mike J.; Christensen, Davis V.; Bustos, Roland M.

    2003-07-01

    The Decontamination and Volume Reduction System (DVRS) operated by the Solid Waste Operations (SWO) Group at Los Alamos National Laboratory (LANL) processes large volume, legacy radioactive waste items. Waste boxes, in sizes varying from 4 ft x 4 ft x 8 ft to 10 ft x 12 ft x 40 ft, are assayed prior to entry into the processing building. Inside the building, the waste items are removed from their container, decontaminated and/or size reduced if necessary, and repackaged for shipment to the Waste Isolation Pilot Plant (WIPP) or on-site low-level waste disposal. The repackaged items and any secondary waste produced (e.g., personal protective equipment) are assayed again at the end of the process and a mass balance is done to determine whether there is any significant hold-up material left in the DVRS building. The DVRS building is currently classed as a radiological facility, with a building limit of 0.52 Ci of Pu239 and Am241, and 0.62 Ci of Pu238, the most common radionuclides processed. This requires tight controls on the flow of nuclear material. The large volume of the initial waste packages, the (relatively) small amounts of radioactive material in them, and the tight ceiling on the building inventory require accurate field measurements of the nuclear material. This paper describes the radioactive waste measurement techniques, the computer modeling used to determine the amount of nuclear material present in a waste package, the building inventory database, and the DVRS process itself. Future plans include raising the limit on the nuclear material inventory allowed in the building to accommodate higher activity waste packages. All DOE sites performing decontamination and decommissioning of radioactive process equipment face challenges related to waste assay and inventory issues. This paper describes an ongoing operation, incorporating lessons learned over the life of the project to date.

  10. Bulk arc strain, crustal thickening, magma emplacement, and mass balances in the Mesozoic Sierra Nevada arc

    Science.gov (United States)

    Cao, Wenrong; Paterson, Scott; Saleeby, Jason; Zalunardo, Sean

    2016-03-01

    Quantifying crustal deformation is important for evaluating mass balance, material transfer, and the interplay between tectonism and magmatism in continental arcs. We present a dataset of >650 finite strain analyses compiled from published works and our own studies with associated structural, geochronologic, and geobarometric information in central and southern Sierra Nevada, California, to quantify the arc crust deformation. Our results show that Mesozoic tectonism results in 65% arc-perpendicular bulk crust shortening under a more or less plane strain condition. Mesozoic arc magmatism replaced ∼80% of this actively deforming arc crust with plutons requiring significantly greater crustal thickening. We suggest that by ∼85 Ma, the arc crust thickness was ∼80 km with a 30-km-thick arc root, resulting in a ∼5 km elevation. Most tectonic shortening and magma emplacement must be accommodated by downward displacements of crustal materials into growing crustal roots at the estimated downward transfer rate of 2-13 km/Myr. The downward transfer of crustal materials must occur in active magma channels, or in "escape channels" in between solidified plutons that decrease in size with time and depth resulting in an increase in the intensity of constrictional strain with depth. We argue that both tectonism and magmatism control the thickness of the crust and surface elevation with slight modification by surface erosion. The downward transported crustal materials initially fertilize the MASH zone thus enhancing to the generation of additional magmas. As the crustal root grows it may potentially pinch out and cool the mantle wedge and thus cause reduction of arc magmatism.

  11. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, Clay A [DRI; Hershey, Ronald L [DRI; Healey, John M [DRI; Lyles, Brad F [DRI

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  12. Mass balance of the Amitsulôq ice cap, West Greenland

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Bøggild, Carl Egede; Olesen, Ole B.

    2007-01-01

    with a recent satellite-derived digital elevation model to calculate the specific balance, which is in turn compared to discharge data from the adjacent Tasersiaq basin. The correlation between specific summer balance and discharge is R2 = 0.93 indicating that the basin discharge is dominated by glacial...

  13. Antarctic ice-mass balance 2003 to 2012: regional reanalysis of GRACE satellite gravimetry measurements with improved estimate of glacial-isostatic adjustment based on GPS uplift rates

    NARCIS (Netherlands)

    Sasgen, I.; Konrad, H.; Ivins, E.R.; van den Broeke, M.R.; Bamber, J.L.; Martinec, Z.; Klemann, V.

    2013-01-01

    We present regional-scale mass balances for 25 drainage basins of the Antarctic Ice Sheet (AIS) from satellite observations of the Gravity and Climate Experiment (GRACE) for time period January 2003 to September 2012. Satellite gravimetry estimates of the AIS mass balance are strongly influenced by

  14. Dynamics and Mass Balance of Riiser-Larsen Ice Shelf, Antarctica, and its Drainage Area

    Science.gov (United States)

    Klauke, S.; Oelke, C.; Kleiner, T.; Lange, M. A.; Baessler, M.; Dietrich, R.

    2006-12-01

    A coupled finite difference ice sheet/ice shelf model is used to investigate the flow regime of Riiser-Larsen ice shelf, Eastern Weddell Sea, Antarctica, and its drainage area. The model takes into account higher order terms that are neglected in the popular shallow ice approximation. The modeled region has a total area of roughly 130 · 103 km2. The model grid consists of 2.5 km × 2.5 km cells horizontally, and of 10 sigma layers vertically. As input data for the simulation, a new DEM is derived mainly from recent ICESat/GLAS laser-altimetry data. In the ice sheet part of the modeled area, ice thickness data are taken from the BEDMAP data set. For the ice shelf, the thickness distribution is computed from the DEM by assuming isostatic equilibrium. For this purpose, vertical density variations inside the ice shelf are derived by comparison of GLAS altimetry data with airborne RES ice thickness measurements from the EPICA mission. The modeled ice flow velocity is compared with interferometrically derived surface flow velocities from ERS-SAR scenes of the ice sheet and with published in-situ measurements of the ice shelf. In order to minimize the difference between modeled and measured velocities, the boundary conditions and free parameters of the flow model are adjusted. The boundary condition at the ice-rock interface turns out to play a crucial role in optimizing the agreement. Thus, the basal sliding velocity of the ice body is calculated from the basal temperature and the basal shear stress following a widely used relation originally proposed by Weertman, and by adjusting its parameters. In the ice shelf, the viscosity of the ice is used as a tuning parameter and is adjusted to maximize the agreement with in-situ measurements. From the result of the simulation with an optimal set of parameters a mass flow over the grounding line of roughly 2 · 1013 kg yr-1 is derived. The comparison with published surface accumulation data suggests a stable mass balance for

  15. The modelled surface mass balance of the Antarctic Peninsula at 5.5 km horizontal resolution

    Directory of Open Access Journals (Sweden)

    J. M. van Wessem

    2015-09-01

    Full Text Available This study presents a high-resolution (~ 5.5 km estimate of Surface Mass Balance (SMB over the period 1979–2014 for the Antarctic Peninsula (AP, generated by the regional atmospheric climate model RACMO2.3 and a Firn Densification Model (FDM. RACMO2.3 is used to force the FDM, which calculates processes in the snowpack, such as meltwater percolation, refreezing and runoff. We evaluate model output with 132 in-situ SMB observations and discharge rates from 6 glacier drainage basins, and find that the model realistically simulates the strong spatial variability in precipitation, but that significant biases remain as a result of the highly complex topography of the AP. It is also clear that the observations significantly underrepresent the high-accumulation regimes. The SMB map reveals large accumulation gradients, with precipitation values above 3000 mm we yr−1 over the western AP (WAP and below 500 mm we yr−1 on the eastern AP (EAP, not resolved by coarser data-sets such as ERA-Interim. The other SMB components are one order of magnitude smaller, with drifting snow sublimation the largest ablation term removing up to 100 mm we yr−1 of mass. Snowmelt is widespread over the AP, reaching 500 mm we yr−1 towards the northern ice shelves, but the meltwater mostly refreezes. As a result runoff fluxes are low, but still considerable (200 mm we yr−1 over the Larsen (B/C, Wilkins and George VI ice shelves. The average AP ice sheet integrated SMB, including ice shelves (an area of 4.1 × 105 km2, is estimated at 351 Gt yr−1 with an interannual variability of 58 Gt yr−1, which is dominated by precipitation (PR (365 ± 57 Gt yr−1. The WAP (2.4 × 105 km2 SMB (276 ± 47 Gt yr−1, where PR is large (276 ± 47 Gt yr−1, dominates over the EAP (1.7 × 105 km2 SMB (75 ± 11 Gt yr−1 and PR (84 ± 11 Gt yr−1. Total sublimation is 11 ± 2 Gt yr−1 and meltwater runoff into the ocean is 4 ± 4 Gt yr−1. There are no significant trends in any

  16. Coupled heat/mass-balance model for analyzing correlation between excess AlF3 concentration and aluminum electrolyte temperature

    Institute of Scientific and Technical Information of China (English)

    HUANG Yong-bo; QU Xiang-dong; ZHOU Jie-min

    2009-01-01

    The influence of aluminum electrolyte component on its temperature is an important issue within the field of aluminum reduction with pre-baked cells. The characteristic correlation between excess AlF3 concentration and aluminum electrolyte temperature was explored through the modeling of heat and mass transfer processes in industrial pre-baked aluminum reduction cells. A coupled heat/mass-balance model was derived theoretically from the mass and energy balance of an electrolysis cell, and then was simplified properly into a practical expression. The model demonstrates that if environmental temperature and Al2O3 concentration keep constant, the excess AlF3 concentration decreases with the aluminum electrolyte temperature linearly and its decrease rate is dependent on the heat transfer property of aluminum electrolyte, side wall and cell shell. Secondly, experiments were conducted on site with two industrial cells in an aluminum electrolysis plant. Excess AlF3 concentration and aluminum electrolyte temperature were obtained simultaneously together with other parameters such as Al2O3, CaF2, MgF2 and LiF concentrations. Results show that the maximum absolute error between the tested value and the calculated value of excess AlF3 concentration using the proposed model is less than 2%. This reveals that the coupled heat/mass-balance model can appropriately characterize the correlation between excess AlF3 concentration and aluminum electrolyte temperature with good accuracy and practicability.

  17. Moisture and drug solid-state monitoring during a continuous drying process using empirical and mass balance models

    DEFF Research Database (Denmark)

    Fonteyne, Margot; Gildemyn, Delphine; Peeters, Elisabeth

    2014-01-01

    of Process Analytical Technology (PAT) tools (Raman and NIR spectroscopy) and a mass balance approach. The six-segmented fluid bed drying system being part of a fully continuous from-powder-to-tablet production line (ConsiGma™-25) was used for this study. A theophylline:lactose:PVP (30:67.5:2.5) blend...... was chosen as model formulation. For the development of the NIR-based moisture determination model, 15 calibration experiments in the fluid bed dryer were performed. Six test experiments were conducted afterwards, and the product was monitored in-line with NIR and Raman spectroscopy during drying....... The results (drying endpoint and residual moisture) obtained via the NIR-based moisture determination model, the classical approach by means of indirect parameters and the mass balance model were then compared. Our conclusion is that the PAT-based method is most suited for use in a production set-up. Secondly...

  18. The changing impact of snow conditions and refreezing on the mass balance of an idealized Svalbard glacier

    Science.gov (United States)

    Van Pelt, Ward; Pohjola, Veijo; Reijmer, Carleen

    2016-11-01

    Glacier surface melt and runoff depend strongly on seasonal and perennial snow (firn) conditions. Not only does the presence of snow and firn directly affect melt rates by reflecting solar radiation, it may also act as a buffer against mass loss by storing melt water in refrozen or liquid form. In Svalbard, ongoing and projected amplified climate change with respect to the global mean change has severe implications for the state of snow and firn and its impact on glacier mass loss. Model experiments with a coupled surface energy balance - firn model were done to investigate the surface mass balance and the changing role of snow and firn conditions for an idealized Svalbard glacier. A climate forcing for the past, present and future (1984-2104) is constructed, based on observational data from Svalbard Airport and a seasonally dependent projection scenario. Results illustrate ongoing and future firn degradation in response to an elevational retreat of the equilibrium line altitude (ELA) of 31 m decade-1. The temperate firn zone is found to retreat and expand, while cold ice in the ablation zone warms considerably. In response to pronounced winter warming and an associated increase in winter rainfall, the current prevalence of refreezing during the melt season gradually shifts to the winter season in a future climate. Sensitivity tests reveal that in a present and future climate the density and thermodynamic structure of Svalbard glaciers are heavily influenced by refreezing. Refreezing acts as a net buffer against mass loss. However, the net mass balance change after refreezing is substantially smaller than the amount of refreezing itself, which can be ascribed to melt-enhancing effects after refreezing, which partly offset the primary mass-retaining effect of refreezing.

  19. The changing impact of snow conditions and refreezing on the mass balance of an idealized Svalbard glacier

    Directory of Open Access Journals (Sweden)

    Ward Van Pelt

    2016-11-01

    Full Text Available Glacier surface melt and runoff depend strongly on seasonal and perennial snow (firn conditions. Not only does the presence of snow and firn directly affect melt rates by reflecting solar radiation, it may also act as a buffer against mass loss by storing melt water in refrozen or liquid form. In Svalbard, ongoing and projected amplified climate change with respect to the global mean change has severe implications for the state of snow and firn and its impact on glacier mass loss. Model experiments with a coupled surface energy balance - firn model were done to investigate the surface mass balance and the changing role of snow and firn conditions for an idealized Svalbard glacier. A climate forcing for the past, present and future (1984-2104 is constructed, based on observational data from Svalbard Airport and a seasonally dependent projection scenario. Results illustrate ongoing and future firn degradation in response to an elevational retreat of the equilibrium line altitude (ELA of 31 m decade−1. The temperate firn zone is found to retreat and expand, while cold ice in the ablation zone warms considerably. In response to pronounced winter warming and an associated increase in winter rainfall, the current prevalence of refreezing during the melt season gradually shifts to the winter season in a future climate. Sensitivity tests reveal that in a present and future climate the density and thermodynamic structure of Svalbard glaciers are heavily influenced by refreezing. Refreezing acts as a net buffer against mass loss. However, the net mass balance change after refreezing is substantially smaller than the amount of refreezing itself, which can be ascribed to melt-enhancing effects after refreezing, which partly offset the primary mass-retaining effect of refreezing.

  20. Catchment conceptualisation for examining applicability of chloride mass balance method in an area with historical forest clearance

    OpenAIRE

    H. Guan; Love, A. J.; Simmons, C.T.; J. Hutson; Ding, Z.

    2010-01-01

    Of the various approaches for estimating groundwater recharge, the chloride mass balance (CMB) method is one of the most frequently used, especially for arid and semiarid regions. Widespread native vegetation clearance, common in many areas globally, has changed the land surface boundary condition, posing the question as to whether the current system has reached new chloride equilibrium, required for a CMB application. Although a one-dimensional CMB can be applied at a point where the water a...

  1. Catchment conceptualisation for examining applicability of chloride mass balance method in an area of historical forest clearance

    OpenAIRE

    H. Guan; Love, A.; Simmons, C.T.; Ding, Z.; J. Hutson

    2009-01-01

    Among various approaches for estimating groundwater recharge, chloride mass balance (CMB) method is one of the most frequently used, in particular, for arid and semiarid regions. Widespread native vegetation clearance, common history in many areas globally, has changed land surface boundary condition, posing a question whether the current system has reached new chloride equilibrium for CMB application. To examine CMB applicability for catchments, conceptual catchment types of various chloride...

  2. Aquifer Recharge Estimation through Atmospheric Chloride Mass Balance at Las Cañadas Caldera, Tenerife, Canary Islands, Spain

    OpenAIRE

    Rayco Marrero-Diaz; Alcalá, Francisco J.; Pérez, Nemesio M.; Dina L. López; Melián, Gladys V.; Eleazar Padrón; Germán D. Padilla

    2015-01-01

    The atmospheric chloride mass balance (CMB) method was used to estimate net aquifer recharge in Las Cañadas Caldera, an endorheic summit aquifer area about 2000 m a.s.l. with negligible surface runoff, which hosts the largest freshwater reserve in Tenerife Island, Canary Islands, Spain. The wet hydrological year 2005–2006 was selected to compare yearly atmospheric chloride bulk deposition and average chloride content in recharge water just above the water table, both deduced from periodical...

  3. Energy and mass balances in multiple-effect upward solar distillers with air flow through the last-effect unit

    Energy Technology Data Exchange (ETDEWEB)

    Homing Yeh; Chiidong Ho [Tamkang Univ. Tamsui, Dept. of Chemical Engineering, Taipei Hsien (Taiwan)

    2000-04-01

    Considerable improvement in productivity may be obtained if water vapor in the last-effect unit is carried away directly by flowing air. The theory of a closed-type upward multiple-effect solar distiller has been modified to that of an open-type device, and the energy and mass balances have been derived. The production rate of distilled water for each effect under various climate, design, and operational conditions may be predicted by simultaneously solving the appropriate equations. (Author)

  4. Impact of co-digestion on existing salt and nutrient mass balances for a full-scale dairy energy project.

    Science.gov (United States)

    Camarillo, Mary Kay; Stringfellow, William T; Spier, Chelsea L; Hanlon, Jeremy S; Domen, Jeremy K

    2013-10-15

    Anaerobic digestion of manure and other agricultural waste streams with subsequent energy production can result in more sustainable dairy operations; however, importation of digester feedstocks onto dairy farms alters previously established carbon, nutrient, and salinity mass balances. Salt and nutrient mass balance must be maintained to avoid groundwater contamination and salination. To better understand salt and nutrient contributions of imported methane-producing substrates, a mass balance for a full-scale dairy biomass energy project was developed for solids, carbon, nitrogen, sulfur, phosphorus, chloride, and potassium. Digester feedstocks, consisting of thickened manure flush-water slurry, screened manure solids, sudan grass silage, and feed-waste, were tracked separately in the mass balance. The error in mass balance closure for most elements was less than 5%. Manure contributed 69.2% of influent dry matter while contributing 77.7% of nitrogen, 90.9% of sulfur, and 73.4% of phosphorus. Sudan grass silage contributed high quantities of chloride and potassium, 33.3% and 43.4%, respectively, relative to the dry matter contribution of 22.3%. Five potential off-site co-digestates (egg waste, grape pomace, milk waste, pasta waste, whey wastewater) were evaluated for anaerobic digestion based on salt and nutrient content in addition to bio-methane potential. Egg waste and wine grape pomace appeared the most promising co-digestates due to their high methane potentials relative to bulk volume. Increasing power production from the current rate of 369 kW to the design value of 710 kW would require co-digestion with either 26800 L d(-1) egg waste or 60900 kg d(-1) grape pomace. However, importation of egg waste would more than double nitrogen loading, resulting in an increase of 172% above the baseline while co-digestion with grape pomace would increase potassium by 279%. Careful selection of imported co-digestates and management of digester effluent is required to

  5. The Mass Balance of Glacier No. 1 at the Headwaters of the Urumqi River in Relation to Northern Hemisphere Teleconnection Patterns

    Directory of Open Access Journals (Sweden)

    Feifei Yuan

    2016-03-01

    Full Text Available Most small glaciers in the world have significantly decreased their volume during the last century, which has caused water shortage problems. Glacier No. 1, at the headwaters of the Urumqi River, Tianshan, China, has been monitored since 1959 and similarly has experienced significant mass and volume losses over the last few decades. Thus, we examined the trend and potential abrupt changes of the mass balance of Glacier No. 1. Principal component analysis and singular value decomposition were used to find significant relations between the mass balance of Glacier No. 1 and Northern Hemisphere teleconnection patterns using climate indices. It was found that the mass balance of Glacier No. 1 had a significantly decreasing trend corresponding to −14.5 mm/year from 1959 to 2010. A change point was detected in 1997 with 99% confidence level. Two time periods with different mass balances were identified as 1959–1996 and 1997–2010. The mass balance for the first period was −136.4 mm/year and up to −663.9 mm/year for the second period. The mass balance of Glacier No. 1 is positively related to the Scandinavian Pattern (SCA, and negatively related to the East Atlantic Pattern (EA. These relationships are useful in better understanding the interaction between glacier mass balance and climate variability.

  6. Modeling mass balance and volume of Xiao Dongkemadi glacier in the Central Tibetan Plateau from 1989 to 2050

    Science.gov (United States)

    Duan, K.

    2015-12-01

    The Tibetan Plateau (TP) holds ten thousands of alpine glaciers in mid-latitude, which have shrunk with an accelerating retreat rate recently. Here, we applied a temperature-index distributed mass-balance model coupled with a volume-area scaling method to Xiao Dongkemadi Glacier (XDG) in the central TP, to assess its response to climate change. The result shows the simulated mass balance is in a good agreement with observations (R2=0.75, p<0.001) during the period of 1989-2012. The simulated mean annual mass balance (-213 mm w.e.) is close to the observation (-233 mm w.e.), indicating the model can be used to estimate the glacier variation in the future. Then the model was forced by the output of RegCM4 under the climate scenarios RCP4.5 and RCP8.5 from 2013 to 2050. The simulated terminus elevation of the glacier will rise from 5454m a.s.l. in 2013 to 5533m a.s.l. (RCP4.5) and 5543m a.s.l (RCP8.5) in 2050. XDG will lose its volume with an increasing rate of 600-700m3 a-1 during the period of 1989-2050, indicating the melting water will enhance the river runoff. But for the long term, the contribution to the river runoff will decrease for shrinkage of glacier scale.

  7. Atmospheric Ammonia Emissions and a Nitrogen Mass Balance for a Dairy

    Science.gov (United States)

    Rumburg, B. P.; Mount, G. H.; Filipy, J. M.; Lamb, B.; Yonge, D.; Wetherelt, S.

    2003-12-01

    Atmospheric ammonia (NH3) emissions have many impacts on the environment and human health. Environmental NH3 impacts include terrestrial and aquatic eutrophication, soil acidification, and aerosol formation. Aerosols affect global radiative transfer and have been linked to human health effects. The global emissions of NH3 are estimated to be 45 Tg N yr-1 (Dentener and Crutzen, 1994) with most of the emissions coming from domestic animals. The largest per animal emission come from dairy cows at 33 kg N animal{-1} year{-1} versus 10 kg N animal{-1} {-1} for cattle. On a global scale the emissions uncertainty is about 25%, but local emissions are highly uncertain (Bouwman et al., 1997). Local emissions determination is required for proper treatment in air pollution models. The main sources of emission from dairies are the cow stalls where urea and manure react to form NH3, the storage lagoons where NH3 is the end product of microbial degradation and the disposal of the waste. There have been numerous studies of NH3 emissions in Europe but farming practices are quite different in Europe than in the U.S.. The impact of these differences on emissions is unknown. We have been studying the NH3 emissions from the Washington State University dairy for three years to develop a detailed emission model for use in a regional air pollution model. NH3 is measured using a short-path spectroscopic absorption near 200 nm with a sensitivity of a few ppbv and a time resolution of a few seconds. The open air short-path method is advantageous because it is self calibrating and avoids inlet wall adherence which is a major problem for most NH3 measurement techniques. A SF6 tracer technique has been used to measure fluxes from the three main emission sources: the cow stalls, anaerobic lagoon and the waste application to grass fields using a sprinkler system. Estimated yearly emissions from each source will be compared to a nitrogen mass balance model for the dairy.

  8. [Characteristic of Mercury Emissions and Mass Balance of the Typical Iron and Steel Industry].

    Science.gov (United States)

    Zhang, Ya-hui; Zhang, Cheng; Wang, Ding-yong; Luo, Cheng-zhong; Yang, Xi; Xu, Feng

    2015-12-01

    To preliminarily discuss the mercury emission characteristics and its mass balance in each process of the iron and steel production, a typical iron and steel enterprise was chosen to study the total mercury in all employed materials and estimate the input and output of mercury during the steel production process. The results showed that the mercury concentrations of input materials in each technology ranged 2.93-159.11 µg · kg⁻¹ with the highest level observed in ore used in blast furnace, followed by coal of sintering and blast furnace. The mercury concentrations of output materials ranged 3.09-18.13 µg · kg⁻¹ and the mercury concentration of dust was the highest, followed by converter slag. The mercury input and the output in the coking plant were 1346.74 g · d⁻¹ ± 36.95 g · d⁻¹ and 177.42 g · d⁻¹ ± 13.73 g · d⁻¹, respectively. In coking process, mercury mainly came from the burning of coking coal. The sintering process was the biggest contributor for mercury input during the iron and steel production with the mercury input of 1075. 27 g · d⁻¹ ± 60.89 g · d⁻¹ accounting for 68.06% of the total mercury input during this production process, and the ore powder was considered as the main mercury source. For the solid output material, the output in the sintering process was 14.15 g · d⁻¹ ± 0.38 g · d⁻¹, accounting for 22.61% of the total solid output. The mercury emission amount from this studied iron and steel enterprise was estimated to be 553.83 kg in 2013 with the emission factor of 0.092 g · t⁻¹ steel production. Thus, to control the mercury emissions, iron and steel enterprises should combine with production practice, further reduce energy consumption of coking and sintering, or improve the quality of raw materials and reduce the input of mercury.

  9. Material-mass Balance of Smallholder Oil Palm Processing in the Niger Delta, Nigeria

    Directory of Open Access Journals (Sweden)

    Elijah I. Ohimain

    2013-03-01

    Full Text Available This study evaluates the material-mass balance of smallholder oil palm processing in Niger Delta Nigeria. Ten smallholder oil palm processing mills were randomly sampled. Measuring scale was used to measure the weight of the Fresh Fruit Bunch (FFB and all the processing intermediates/products including Threshed Fresh Fruit (TFF, Palm Pressed Fibre (PPF, Palm Kernel Shell (PKS, Empty Fruit Bunch (EFB, Crude Palm Oil (CPO, chaff and nut. During the study period (13-22 April 2012, 8 of the mills processed 90-400 bunches of Dura variety, while the remaining 2 mills processed 65-200 bunches of Tenera variety. During the batch processing of Dura variety, the proportion of the intermediate products computed in relation to the weight of the FFB (100% are as follows; TFF (66.0-75.0%, mesocarp (44.8-51.1%, nuts (19.0-27.5%, kernel (5.7-7.2%, water in mesocarp (9.0-12.1% and water in nut (2.4-3.4%, EFB (23.7-32.4%, chaff (0.8-2.4%, Palm Kernel Shell (PKS (10.0-18.8%, Palm Press Fibre (PPF (23.2-28.1% and Crude Palm Oil (CPO (9.4-12.8%. For the Tenera varieties, the compositions are as follows; TFF (70.9-72.9%, mesocarp (56.4-58.0%, nuts (14.5-14.9%, kernel (5.5-5.6%, water in mesocarp (10.1-10.4% and water in the nut (1.9-2.1%, EFB (25.7-28.2%, chaff (0.9-1.4%, PKS (6.8-7.5%, (19.1-20.3% and CPO (26.0-28.2%. This result shows that Tenera produces more oil and less wastes compared to the Dura variety. The solid wastes fractions are used as energy sources during the processing of oil palm and as filling materials for upgrading access roads to palm plantations. Except the huge volume of wastes (71.8-90.6% generated by smallholder oil palm processors is effectively utilized, the process will be unsustainable.

  10. Mass-balance modeling of mineral weathering rates and CO2 consumption in the forested, metabasaltic Hauver Branch watershed, Catoctin Mountain, Maryland, USA

    Science.gov (United States)

    Rice, Karen; Price, Jason R.; Szymanski, David W.

    2013-01-01

    Mineral weathering rates and a forest macronutrient uptake stoichiometry were determined for the forested, metabasaltic Hauver Branch watershed in north-central Maryland, USA. Previous studies of Hauver Branch have had an insufficient number of analytes to permit determination of rates of all the minerals involved in chemical weathering, including biomass. More equations in the mass-balance matrix were added using existing mineralogic information. The stoichiometry of a deciduous biomass term was determined using multi-year weekly to biweekly stream-water chemistry for a nearby watershed, which drains relatively unreactive quartzite bedrock.At Hauver Branch, calcite hosts ~38 mol% of the calcium ion (Ca2+) contained in weathering minerals, but its weathering provides ~90% of the stream water Ca2+. This occurs in a landscape with a regolith residence time of more than several Ka (kiloannum). Previous studies indicate that such old regolith does not typically contain dissolving calcite that affects stream Ca2+/Na+ ratios. The relatively high calcite dissolution rate likely reflects dissolution of calcite in fractures of the deep critical zone.Of the carbon dioxide (CO2) consumed by mineral weathering, calcite is responsible for approximately 27%, with the silicate weathering consumption rate far exceeding that of the global average. The chemical weathering of mafic terrains in decaying orogens thus may be capable of influencing global geochemical cycles, and therefore, climate, on geological timescales. Based on carbon-balance calculations, atmospheric-derived sulfuric acid is responsible for approximately 22% of the mineral weathering occurring in the watershed. Our results suggest that rising air temperatures, driven by global warming and resulting in higher precipitation, will cause the rate of chemical weathering in the Hauver Branch watershed to increase until a threshold temperature is reached. Beyond the threshold temperature, increased recharge would

  11. Assessing the Sensitivity of Satellite-Derived Estimates of Ice Sheet Mass Balance to Regional Climate Model Simulations of Snow Accumulation and Firn Compaction

    Science.gov (United States)

    Briggs, K.; Shepherd, A.; Horwath, M.; Horvath, A.; Nagler, T.; Wuite, J.; Muir, A.; Gilbert, L.; Mouginot, J.

    2015-12-01

    Surface mass balance (SMB) estimates from Regional Climate Models (RCMs) are fundamental for assessing and understanding ice sheet mass trends. Mass budget and altimetry assessments rely on RCMs both directly for estimates of the SMB contribution to the total mass trend, and indirectly for ancillary data in the form of firn compaction corrections. As such, mass balance assessments can be highly sensitive to RCM outputs and therefore their accuracy. Here we assess the extent to which geodetic measurements of mass balance are sensitive to RCM model outputs at different resolutions. We achieve this by comparing SMB dependent estimates of mass balance from the mass budget method and altimetry, with those from satellite gravimetry that are independent of SMB estimates. Using the outputs of the RACMO/ANT 2.3 model at 5.5 km and 27 km horizontal spatial resolution, we generate estimates of mass balance using the mass budget method and altimetry for the Western Palmer Land region of the Antarctic Peninsula between 2003 and 2014. We find a 19% increase in the long-term (1980 to 2014) mean annual SMB for the region when enhancing the model resolution to 5.5 km. This translates into an approximate 50% reduction in the total mass loss from 2003 to 2014 calculated with the mass budget method and a 15% increase in the altimetry estimate. The use of the enhanced resolution product leads to consistency between the estimates of mass loss from the altimetry and the mass budget method that is not observed with the coarser resolution product, in which estimates of cumulative mass fall beyond the relative errors. Critically, when using the 5.5 km product, we find excellent agreement, both in pattern and magnitude, with the independent estimate derived from gravimetry. Our results point toward the crucial need for high resolution SMB products from RCMs for mass balance assessments, particularly in regions of high mass turnover and complex terrain as found over the Antarctic Peninsula.

  12. Intermediate mass dilepton production in a chemically equilibrating quark-gluon matter

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    We find that in a chemically equilibrating baryon-rich quark-gluon matter, due to the slow cooling rate, high initial temperature, large gluon density as well as large fusion cross section ofin the intermediate mass region, the gluon fusion provides a dominant contribution to dileptons with intermediate masses, resulting in the significant enhancement of intermediate mass dileptons.

  13. Influence of Finite Chemical Potential on Critical Boson Mass in QED3

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yun-Qiang; LI Zhen; FENG Hong-Tao

    2007-01-01

    Using the coupled Dyson-Schwinger equation for the fermion propagator at finite chemical potential μ,we investigate the fermion chiral condensate when the gauge boson mass is nonzero in QED3. We show that the chiral symmetry restores when the boson mass is large enough, and the critical boson mass depends little on μ.

  14. Electrode Mass Balancing as an Inexpensive and Simple Method to Increase the Capacitance of Electric Double-Layer Capacitors

    Science.gov (United States)

    Andres, Britta; Engström, Ann-Christine; Blomquist, Nicklas; Forsberg, Sven; Dahlström, Christina; Olin, Håkan

    2016-01-01

    Symmetric electric double-layer capacitors (EDLCs) have equal masses of the same active material in both electrodes. However, having equal electrode masses may prevent the EDLC to have the largest possible specific capacitance if the sizes of the hydrated anions and cations in the electrolyte differ because the electrodes and the electrolyte may not be completely utilized. Here we demonstrate how this issue can be resolved by mass balancing. If the electrode masses are adjusted according to the size of the ions, one can easily increase an EDLC’s specific capacitance. To that end, we performed galvanostatic cycling to measure the capacitances of symmetric EDLCs with different electrode mass ratios using four aqueous electrolytes— Na2SO4, H2SO4, NaOH, and KOH (all with a concentration of 1 M)—and compared these to the theoretical optimal electrode mass ratio that we calculated using the sizes of the hydrated ions. Both the theoretical and experimental values revealed lower-than-1 optimal electrode ratios for all electrolytes except KOH. The largest increase in capacitance was obtained for EDLCs with NaOH as electrolyte. Specifically, we demonstrate an increase of the specific capacitance by 8.6% by adjusting the electrode mass ratio from 1 to 0.86. Our findings demonstrate that electrode mass balancing is a simple and inexpensive method to increase the capacitance of EDLCs. Furthermore, our results imply that one can reduce the amount of unused material in EDLCs and thus decrease their weight, volume and cost. PMID:27658253

  15. 40 CFR 1065.655 - Chemical balances of fuel, intake air, and exhaust.

    Science.gov (United States)

    2010-07-01

    ... , = carbon mass fraction of fuel. M C = molar mass of carbon. α = atomic hydrogen-to-carbon ratio of the... O = molar mass of oxygen. γ = atomic sulfur-to-carbon ratio of the mixture of fuel(s) being combusted, weighted by molar consumption. M S = molar mass of sulfur. δ = atomic nitrogen-to-carbon ratio...

  16. Glaciers in a changing global climate: first results of worldwide glacier mass balance measurements 2000/2001

    Science.gov (United States)

    Frauenfelder, R.; Hoelzle, M.; Haeberli, W.

    2003-04-01

    Glacier signals from mountain areas are key elements of early detection strategies for dealing with possible man-induced climate change. The IPCC Third Assessment Report indeed defines mountain glaciers as one of the best natural indicators of atmospheric warming with the highest reliability ranking. In the chain of processes linking climate and glacier fluctuations, glacier length variation is the indirect/delayed response, whereas glacier mass change is the direct/undelayed reaction. Internationally coordinated long-term monitoring of glaciers started in 1894. The responsibility to collect and publish standardized data has been assumed since 1986 by the World Glacier Monitoring Service (WGMS). This work is primarily being carried out under the auspices of the International Commission on Snow and Ice (ICSI/IAHS) and the Federation of Astronomical and Geophysical Services (FAGS/ICSU). The WGMS maintains data exchange with the ICSU World Data Center A (WDC-A) for Glaciology in Boulder, Colorado. Corresponding data bases and measurement networks form an essential part of the Global Terrestrial Network for Glaciers (GTN-G: operated by the WGMS) as a pilot project within the Global Terrestrial Observing System (GTOS/GCOS). A network of 60 glacier mass balance observations provides information on presently observed rates of change in glacier mass, corresponding acceleration trends and regional distribution patterns. A preliminary calculation of the mass balance observations in 2000/2001 relating to 23 selected data sets provide a mean specific (annual) net balance of -367 mm w.e., 26 % of the observed balances were positive. The corresponding mean in six mountain ranges was -571 mm w.e. Such values indicate that mass losses in 2000/2001 have been less extreme than in the extraordinary years before but are still strongly negative. Over the past two decades glacier melt appears to continue at a considerable and possibly even an accelerating rate. The observed average

  17. Introduction to computational mass transfer with applications to chemical engineering

    CERN Document Server

    Yu, Kuo-Tsung

    2017-01-01

    This book offers an easy-to-understand introduction to the computational mass transfer (CMT) method. On the basis of the contents of the first edition, this new edition is characterized by the following additional materials. It describes the successful application of this method to the simulation of the mass transfer process in a fluidized bed, as well as recent investigations and computing methods for predictions for the multi-component mass transfer process. It also demonstrates the general issues concerning computational methods for simulating the mass transfer of the rising bubble process. This new edition has been reorganized by moving the preparatory materials for Computational Fluid Dynamics (CFD) and Computational Heat Transfer into appendices, additions of new chapters, and including three new appendices on, respectively, generalized representation of the two-equation model for the CMT, derivation of the equilibrium distribution function in the lattice-Boltzmann method, and derivation of the Navier-S...

  18. Performance of on-site pilot static granular bed reactor (SGBR) for treating dairy processing wastewater and chemical oxygen demand balance modeling under different operational conditions.

    Science.gov (United States)

    Oh, Jin Hwan; Park, Jaeyoung; Ellis, Timothy G

    2015-02-01

    The performance and operational stability of a pilot-scale static granular bed reactor (SGBR) for the treatment of dairy processing wastewater were investigated under a wide range of organic and hydraulic loading rates and temperature conditions. The SGBR achieved average chemical oxygen demand (COD), biological oxygen demand (BOD), and total suspended solids (TSS)-removal efficiencies higher than 90% even at high loading rates up to 7.3 kg COD/m(3)/day, with an hydraulic retention time (HRT) of 9 h, and at low temperatures of 11 °C. The average methane yield of 0.26 L CH4/g COD(removed) was possibly affected by a high fraction of particulate COD and operation at low temperatures. The COD mass balance indicated that soluble COD was responsible for most of the methane production. The reactor showed the capacity of the methanogens to maintain their activity and withstand organic and hydraulic shock loads.

  19. Climate change threatens archaeologically significant ice patches: insights into their age, internal structure, mass balance and climate sensitivity

    Science.gov (United States)

    Strand Ødegård, Rune; Nesje, Atle; Isaksen, Ketil; Andreassen, Liss Marie; Eiken, Trond; Schwikowski, Margit; Uglietti, Chiara

    2017-01-01

    Despite numerous spectacular archaeological discoveries worldwide related to melting ice patches and the emerging field of glacial archaeology, governing processes related to ice patch development during the Holocene and their sensitivity to climate change are still largely unexplored. Here we present new results from an extensive 6-year (2009-2015) field experiment at the Juvfonne ice patch in Jotunheimen in central southern Norway. Our results show that the ice patch has existed continuously since the late Mesolithic period. Organic-rich layers and carbonaceous aerosols embedded in clear ice show ages spanning from modern at the surface to ca. 7600 cal years BP at the bottom. This is the oldest dating of ice in mainland Norway. The expanding ice patch covered moss mats appearing along the margin of Juvfonne about 2000 years ago. During the study period, the mass balance record showed a strong negative balance, and the annual balance is highly asymmetric over short distances. Snow accumulation is poorly correlated with estimated winter precipitation, and single storm events may contribute significantly to the total winter balance. Snow accumulation is approx. 20 % higher in the frontal area compared to the upper central part of the ice patch. There is sufficient meltwater to bring the permeable snowpack to an isothermal state within a few weeks in early summer. Below the seasonal snowpack, ice temperatures are between -2 and -4 °C. Juvfonne has clear ice stratification of isochronic origin.

  20. Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan

    Science.gov (United States)

    Ting, Cheh-Shyh; Kerh, Tienfuan; Liao, Chiu-Jung

    Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically. Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve the accuracy of future groundwater-simulation and management models in the plain. Résumé Du fait de la croissance économique rapide de la plaine de Pingtung à Taiwan, l'utilisation des ressources en eau souterraine s'est considérablement modifié. La surexploitation des aquifères, qui a abaissé le niveau des nappes, n'affecte pas seulement la région côtière, mais a de sérieuses répercutions sur l'agriculture dans toute la plaine. Afin de déterminer les ressources renouvelables de l'aquifère sous la plaine, une estimation précise de la recharge de la nappe est nécessaire. Dans cette étude, le taux de recharge de la nappe a d'abord été estimé au moyen d'un bilan de matière de chlorure. Quatre sites de la partie centrale ont été sélectionnés pour réaliser ces estimations, à l'aide d'un chromatographe ionique et de la méthode des polygones de Thiessen. A partir des résultats mesurés et calculés, à chaque site, et en prenant comme limites les montagnes et les rivi

  1. Antarctic Ice Sheet Surface Mass Balance Estimates from 2003 TO 2015 Using Icesat and CRYOSAT-2 Data

    Science.gov (United States)

    Xie, Huan; Hai, Gang; Chen, Lei; Liu, Shijie; Liu, Jun; Tong, Xiaohua; Li, Rongxing

    2016-06-01

    An assessment of Antarctic ice sheet surface mass balance from 2003 to 2015 has been carried out using a combination of ICESat data from 2003 to 2009 and CryoSat-2 data from 2010 to 2015. Both data sets are of L2 and are currently processed separately using different models. First, a repeat-track processing method that includes terms accounting for the trend and the first order fit of topography is applied to repeat-track measurements of all ICESat Campaigns. It uses the Least Squares fitting of the model to all observations in a box of 500 m x 500 m. The estimated trends in these boxes are then averaged inside a 30 km x 30 km cell. Similarly, the cells are used to estimate basin and ice sheet level surface elevation change trends. Mass balance calculating is performed at the cell level by multiplying the ice density by the volume change and then extended to the basin and the ice sheet level. Second, in CryoSat-2 data processing we applied a model within a cell of 5 km x 5 km considering that CryoSat-2 does not maintain repeated tracks. In this model the elevation trend, and a higher order topography are solved in an iterative way using the least squares technique. The mass change is computed at the cell level in the same way as the ICESat data. GIA correction is applied for both ICESat and CryoSat-2 estimates. Detailed information about the data processing, elevation and mass balance changes, and comparison with other studies will be introduced.

  2. Nutrient Mass Balance for the Mobile River Basin in Alabama, Georgia, and Mississippi

    Science.gov (United States)

    Harned, D. A.; Harvill, J. S.; McMahon, G.

    2001-12-01

    The source and fate of nutrients in the Mobile River drainage basin are important water-quality concerns in Alabama, Georgia, and Mississippi. Land cover in the basin is 74 percent forested, 16 percent agricultural, 2.5 percent developed, and 4 percent wetland. A nutrient mass balance calculated for 18 watersheds in the Mobile River Basin indicates that agricultural non-point nitrogen and phosphorus sources and urban non-point nitrogen sources are the most important factors associated with nutrients in the streams. Nitrogen and phosphorus inputs from atmospheric deposition, crop fertilizer, biological nitrogen fixation, animal waste, and point sources were estimated for each of the 18 drainage basins. Total basin nitrogen inputs ranged from 27 to 93 percent from atmospheric deposition (56 percent mean), 4 to 45 percent from crop fertilizer (25 percent mean), biological nitrogen fixation (8 percent mean), 2 to 14 percent from animal waste (8 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Total basin phosphorus inputs ranged from 10 to 39 percent from atmospheric deposition (26 percent mean), 7 to 51 percent from crop fertilizer (28 percent mean), 20 to 64 percent from animal waste (41 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Nutrient outputs for the watersheds were estimated by calculating instream loads and estimating nutrient uptake, or withdrawal, by crops. The difference between the total basin inputs and outputs represents nutrients that are retained or processed within the basin while moving from the point of use to the stream, or in the stream. Nitrogen output, as a percentage of the total basin nitrogen inputs, ranged from 19 to 79 percent for instream loads (35 percent mean) and from 0.01 to 32 percent for crop harvest (10 percent mean). From 53 to 87 percent (75 percent mean) of nitrogen inputs were retained within the 18 basins. Phosphorus output ranged from 9 to 29 percent for instream loads (18

  3. Dissolved Carbon Flux and Mass Balance From a Wetland-Dominated Karstic Headwater Catchment

    Science.gov (United States)

    Duval, T. P.; Waddington, J. M.; Branfireun, B. A.

    2009-05-01

    The stream-borne dissolved carbon efflux of peatland-draining catchments is dominated by organic carbon, whereas inorganic carbon dominates the flux from calcareous bedrock catchments. The export of dissolved carbon from calcareous bedrock catchments with significant wetland coverage has not previously been determined. This study documents the spatiotemporal variability of dissolved carbon (inorganic + organic) along a headwater stream in southern Ontario, Canada, as it drains three distinct wetland types: a calcareous fen, a riparian cedar swamp, and a cattail marsh. Upon emergence from the groundwater seeps, the spring water contained 28 times more CO2 than in equilibrium with the atmosphere. This supersaturation decreased to just 5 times equilbrium as the stream leaves the catchment through the marsh, representing a decrease in CO2 concentration of 11 mg L-1, lost to the atmosphere as exsolution. The groundwater seeps contained an average of 1.25±0.75 mg L-1 of dissolved organic carbon (DOC) from May to November 2007, one of the driest years on record in the region. At the catchment outlet through the marsh, DOC concentrations were slightly higher and more variable during the same period at 2.27±1.29 mg L-1, as a fall flushing event resulted in concentrations > 7 mg L-1. This DOC concentration is small compared to the 58.72±3.9 mg L-1 of dissolved inorganic carbon (DIC, as bicarbonate ion) contained within the water leaving the catchment. At 0.21 and 0.17 g m-2 d-1 from May-July and August-November 2007, respectively, the DIC dominated the carbon flux out of the watershed, compared with 0.007 and 0.008 g m- 2 d-1 DOC and 0.015 and 0.009 g m-2 d-1 CO2 exsolution during the same period. Results of the 2007 season will be contrasted to the 2008 season, one of the wettest on record. The watershed is underlain by Silurian dolomite that exhibits karst fractures, resulting in a complex subsurface hydrogeology that influences carbon transport and mass balances

  4. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  5. Toxic Industrial Chemicals: A Future Weapons of Mass Destruction Threat

    Science.gov (United States)

    2007-11-02

    dependent on factors, such as temperature , pressure, and wind speed (US Army 1990; 1994; and 1998a). In addition to CW agents’ toxicities, their chemical...expected to be at especially high risk of shigellosis, malaria, sandfly fever, and cutaneous leishmaniasis (Quin 1992). Studies conducted since the war

  6. Garnet and clinopyroxene pseudomorphs: example of local mass balance in the Caledonides of western Norway.

    Science.gov (United States)

    Centrella, Stephen; Austrheim, Håkon; Putnis, Andrew

    2015-04-01

    et al., 2014) were used to quantify the local mass transfer required during the replacement processes and to identify the importance of fluid in metamorphic reactions. Lanari, P., Vidal, O., Andrade, V. de, Dubacq, B., Lewin, E., Grosch, E.G., and Schwartz, S., 2014, XMapTools: A MATLAB©-based program for electron microprobe X-ray image processing and geothermobarometry. In: Computers & Geosciences, v. 62, p. 227-240. Putnis A, Austrheim H (2012) Mechanisms of metasomatism and metamorphism on the local mineral scale: The role of dissolution-reprecipitation during mineral re-equilibration. In: Metasomatism and the chemical transformation of rock; the role of fluids in terrestrial and extraterrestrial processes, Springer pp 141-170. Putnis A, Putnis CV (2007) The mechanism of reequilibration of solids in the presence of a fluid phase. J Solid State Chem 180: 1783-1786. Xia F, Brugger J, Chen G, Ngothai Y, O'Neill B, Putnis A, Pring A (2009) Mechanism and kinetics of pseudomorphic mineral replacement reactions: a case study of the replacement of pentlandite by violarite, Geochim Cosmochim Acta 73: 1945-1969. ase fill in your abstract text.

  7. Influence of oxygen on alcoholic fermentation by a wine strain of Torulaspora delbrueckii: kinetics and carbon mass balance.

    Science.gov (United States)

    Brandam, Cédric; Lai, Quoc Phong; Julien-Ortiz, Anne; Taillandier, Patricia

    2013-01-01

    Torulaspora delbrueckii metabolism was assessed in a synthetic culture medium similar to grape must under various conditions: no aeration and three different oxygen feeds, in order to determine the effect of oxygen on metabolism. Carbon and nitrogen mass balances were calculated to quantify metabolic fluxes. The effect of oxygen was to decrease the flux of carbon going into the fermentation pathway in favor of growth. In the absence of aeration, higher amounts of glycerol were produced, probably to maintain the redox balance. The oxygen requirement of this strain was high, since even for the highest air supply oxygen became limiting after 24 h. Nevertheless, this strain developed well in the absence of oxygen and consumed 220 g/L of sugars (glucose/fructose) in 166 h at 20 °C, giving a good ethanol yield (0.50 g/g).

  8. Recent mass balance of the Purogangri Ice Cap, central Tibetan Plateau, by means of differential X-band SAR interferometry

    Directory of Open Access Journals (Sweden)

    N. Neckel

    2013-10-01

    Full Text Available Due to their remoteness, altitude and harsh climatic conditions, little is known about the glaciological parameters of ice caps on the Tibetan Plateau. This study presents a geodetic mass balance estimate of the Purogangri Ice Cap, Tibet's largest ice field between 2000 and 2012. We utilized data from the actual TerraSAR-X mission and its add-on for digital elevation measurements and compared it with elevation data from the Shuttle Radar Topography Mission. The employed data sets are ideal for this approach as both data sets were acquired at X-band at nearly the same time of the year and are available at a fine grid spacing. In order to derive surface elevation changes we employed two different methods. The first method is based on differential synthetic radar interferometry while the second method uses common DEM differencing. Both approaches revealed a slightly negative mass budget of −44 ± 15 and −38 ± 23 mm w.eq. a−1 (millimeter water equivalent respectively. A slightly negative trend of −0.15 ± 0.01 km2 a−1 in glacier extent was found for the same time period employing a time series of Landsat data. Overall, our results show an almost balanced mass budget for the studied time period. Additionally, we detected one continuously advancing glacier tongue in the eastern part of the ice cap.

  9. Mass Balance Assessment for Six Neonicotinoid Insecticides During Conventional Wastewater and Wetland Treatment: Nationwide Reconnaissance in United States Wastewater

    Science.gov (United States)

    2016-01-01

    Occurrence and removal of six high-production high-volume neonicotinoids was investigated in 13 conventional wastewater treatment plants (WWTPs) and one engineered wetland. Flow-weighted daily composites were analyzed by isotope dilution liquid chromatography tandem mass spectrometry, revealing the occurrence of imidacloprid, acetamiprid, and clothianidin at ng/L concentrations in WWTP influent (60.5 ± 40.0; 2.9 ± 1.9; 149.7 ± 289.5, respectively) and effluent (58.5 ± 29.1; 2.3 ± 1.4; 70.2 ± 121.8, respectively). A mass balance showed insignificant removal of imidacloprid (p = 0.09, CI = 95%) and limited removal of the sum of acetamiprid and its degradate, acetamiprid-N-desmethyl (18 ± 4%, p = 0.01, CI = 95%). Clothianidin was found only intermittently, whereas thiamethoxam, thiacloprid, and dinotefuran were never detected. In the wetland, no removal of imidacloprid or acetamiprid was observed. Extrapolation of data from 13 WWTPs to the nation as a whole suggests annual discharges on the order of 1000–3400 kg/y of imidacloprid contained in treated effluent to surface waters nationwide. This first mass balance and first United States nationwide wastewater reconnaissance identified imidacloprid, acetamiprid, and clothianidin as recalcitrant sewage constituents that persist through wastewater treatment to enter water bodies at significant loadings, potentially harmful to sensitive aquatic invertebrates. PMID:27196423

  10. Surface elevation change and mass balance of Icelandic ice caps derived from swath mode CryoSat-2 altimetry

    Science.gov (United States)

    Foresta, L.; Gourmelen, N.; Pálsson, F.; Nienow, P.; Björnsson, H.; Shepherd, A.

    2016-12-01

    We apply swath processing to CryoSat-2 interferometric mode data acquired over the Icelandic ice caps to generate maps of rates of surface elevation change at 0.5 km postings. This high-resolution mapping reveals complex surface elevation changes in the region, related to climate, ice dynamics, and subglacial geothermal and magmatic processes. We estimate rates of volume and mass change independently for the six major Icelandic ice caps, 90% of Iceland's permanent ice cover, for five glaciological years between October 2010 and September 2015. Annual mass balance is highly variable; during the 2014/2015 glaciological year, the Vatnajökull ice cap ( 70% of the glaciated area) experienced positive mass balance for the first time since 1992/1993. Our results indicate that between glaciological years 2010/2011and 2014/2015 Icelandic ice caps have lost 5.8 ± 0.7 Gt a-1 on average, 40% less than the preceding 15 years, contributing 0.016 ± 0.002 mm a-1 to sea level rise.

  11. Changes in the Mass Balance of the Greenland Ice Sheet in a Warming Climate During 2003-2009

    Science.gov (United States)

    Zwally, H. Jay; Luthcke, Scott

    2010-01-01

    Mass changes of the Greenland ice sheet (GIS) derived from ICESat and GRACE data both show that the net mass loss from GIS during 2003-2009 is about 175 Gt/year, which contributes 0.5mm/yr global sea-level rise. The rate of mass loss has increased significantly since the 1990's when the GIS was close to mass balance. Even though the GIS was close to mass balance during the 1990's, it was already showing characteristics of responding to8 warmer climate, specifically thinning at the margins and thickening inland at higher elevations. During 2003-2009, increased ice thinning due to increases in melting and acceleration of outlet glaciers began to strongly exceed the inland thickening from increases in accumulation. Over the entire GIS, the mass loss between the two periods, from increased melting and ice dynamics, increased by about 190 Gt/year while the mass gain, from increased precipitation and accumulation, increased by only about 15Gt/year. These ice changes occurred during a time when the temperature on GIS changed at rate of about 2K/decade. The distribution of elevation and mass changes derived from ICESat have high spatial resolution showing details over outlet glaciers, by drainage systems, and by elevation. However, information on the seasonal cycle of changes from ICESat data is limited, because the ICESat lasers were only operated during two to three campaigns per year of about 35 days duration each. In contrast, the temporal resolution of GRACE data, provided by the continuous data collection, is much better showing details of the seasonal cycle and the inter-annual variability. The differing sensitivity of the ICESat altimetry and the GRACE gravity methods to motion of the underlying bedrock from glacial isostatic adjustment (GIA) is used to evaluate the GIA corrections provided by models. The two data types are also combined to make estimates of the partitioning of the mass gains and losses among accumulation, melting, and ice discharge from outlet

  12. Use of geomorphic, hydrologic, and nitrogen mass balance data to model ecosystem nitrate retention in tidal freshwater wetlands

    Directory of Open Access Journals (Sweden)

    E. D. Seldomridge

    2012-02-01

    Full Text Available Geomorphic characteristics have been used as scaling parameters to predict water and other fluxes in many systems. In this study, we combined geomorphic analysis with in-situ mass balance studies of nitrate retention (NR to evaluate which geomorphic scaling parameters best predicted NR in a tidal freshwater wetland ecosystem. Geomorphic characteristics were measured for 267 individual marshes that constitute the freshwater tidal wetland ecosystem of the Patuxent River, Maryland. Nitrate retention was determined from mass balance measurements conducted at the inlets of marshes of varying size (671, 5705, and 536 873 m2 over a period of several years. Mass balance measurements indicate that NR is proportional to total water flux over the tidal cycle. Relationships between estimated tidal prism (total water volume for spring tides and various geomorphic parameters (marsh area, total channel length, and inlet width were defined and compared to field data. From these data, NR equations were determined for each geomorphic parameter, and used to estimate NR for all marshes in the ecosystem for a reference spring (high tide. The resulting ecosystem NR estimates were evaluated for: (a accuracy and completeness of geomorphic data, (b relationship between the geomorphic parameters and hydrologic flux, and (c the ability to adapt the geomorphic parameter to varying tidal conditions. This analysis indicated that inlet width data were the most complete and provided the best estimate of ecosystem nitrate retention. Predictions based on marsh area were significantly lower than the inlet width-based predictions. Cumulative probability distributions of nitrate retention indicate that the largest 3–4 % of the marshes retained half of the total nitrate for the ecosystem.

  13. Use of geomorphic, hydrologic, and nitrogen mass balance data to model ecosystem nitrate retention in tidal freshwater wetlands

    Directory of Open Access Journals (Sweden)

    E. D. Seldomridge

    2012-07-01

    Full Text Available Geomorphic characteristics have been used as scaling parameters to predict water and other fluxes in many systems. In this study, we combined geomorphic analysis with in-situ mass balance studies of nitrate retention (NR to evaluate which geomorphic scaling parameters best predicted NR in a tidal freshwater wetland ecosystem. Geomorphic characteristics were measured for 267 individual marshes that constitute the freshwater tidal wetland ecosystem of the Patuxent River, Maryland. Nitrate retention was determined from mass balance measurements conducted at the inlets of marshes of varying size (671, 5705, and 536 873 m2 over a period of several years. Mass balance measurements indicate that NR is proportional to total water flux over the tidal cycle. Relationships between estimated tidal prism (calculated water volume for spring tides and various geomorphic parameters (marsh area, total channel length, and inlet width were defined using measurements from air photos and compared to field data. From these data, NR equations were determined for each geomorphic parameter, and used to estimate NR for all marshes in the ecosystem for a reference spring (high tide. The resulting ecosystem NR estimates were evaluated for (a accuracy and completeness of geomorphic data, (b relationship between the geomorphic parameters and hydrologic flux, and (c the ability to adapt the geomorphic parameter to varying tidal conditions. This analysis indicated that inlet width data were the most complete and provided the best estimate of ecosystem nitrate retention. Predictions based on marsh area were significantly lower than the inlet width-based predictions. Cumulative probability distributions of nitrate retention indicate that the largest 3–4% of the marshes retained half of the total nitrate for the ecosystem.

  14. Further Support of the Reliability of the Limit on Photon Mass Given by the Rotating Torsion Balance Experiment

    Institute of Scientific and Technical Information of China (English)

    刘琳霞; 邓罡

    2012-01-01

    We consider there is a vacancy in the plasma in the solar system, and calculate the vector potential produced by the magnetic field frozen in the plasma. The result shows that, in the vacancy, the vector potential produced by the magnetic field frozen in the plasma is much less than the large scale cosmic vector potential. This means if our earth is in such a vacancy, the total vector potential on the surface of the earth is dominated by the cosmic magnetic vector potential, which gives a further support of the reliability of the limit on photon mass given by rotating torsion balance experiment [Phys. Rev. Lett. 90 (2003) 081801].

  15. Mass balance and near-surface ice temperature structure of Baishui Glacier No.1 in Mt.Yulong

    Institute of Scientific and Technical Information of China (English)

    DU Jiankuo; HE Yuanqing; LI Shuang; WANG Shijin; NIU Hewen; XIN Huijuan; PU Tao

    2013-01-01

    The accumulation and ablation of a glacier directly reflect its mass income and wastage,and ice temperature indicates glacier's climatic and dynamic conditions.Glaciological studies at Baishui Glacier No.1 in Mt.Yulong are important for estimating recent changes of the cryosphere in Hengduan Mountains.Increased glacier ablation and higher ice temperatures can cause the incidents of icefall.Therefore,it is important to conduct the study of glacier mass balance and ice temperature,but there are few studies in relation to glacier's mass balance and active-layer temperature in China's monsoonal temperate glacier region.Based on the field observations of mass balance and glacier temperature at Baishui Glacier No.1,its accumulation,ablation,net balance and near-surface ice temperature structure were analyzed and studied in this paper.Results showed that the accumulation period was ranged from October to the following mid-May,and the ablation period occurred from mid-May to October,suggesting that the ablation period of temperate glacier began about 15 days earlier than that of continental glaciers,while the accumulation period began about 15 days later.The glacier ablation rate was 6.47 cm d-1 at an elevation of 4600 m between June 23 and August 30,and it was 7.4 cm d-1 at 4800 m between June 26 and July 11 in 1982,moreover,they respectively increased to 9.2 cm d-1 and 10.8 cm d-1 in the corresponding period and altitude in 2009,indicating that glacier ablation has greatly intensified in the past years.The temperature of the main glacier body was close to melting point in summer,and it dropped from the glacier surface and reached a minimum value at a depth of 4-6 m in the ablation zone.The temperature then rose to around melting point with the depth increment.In winter,the ice temperature rose gradually with the increasing depth,and close to melting point at the depth of 10 m.Compared with the data from 1982,the glacier temperature has risen in the ablation zone in

  16. Analysing drying unit performance in a continuous pharmaceutical manufacturing line by means of mass – Energy balances

    DEFF Research Database (Denmark)

    Mortier, Séverine Thérèse F.C.; Gernaey, Krist; De Beer, Thomas De Beer

    2014-01-01

    used. In this paper the data of the six-segmented fluidized bed dryer in the line are used for the development and evaluation of a mass and energy balance. The objectives are multiple: (1) prediction of the moisture content of the granules leaving the dryer solely based on the currently logged data...... in the fluidized bed can be used to predict the gas temperature in different horizontal sections of the dryer. An extra sensor measuring the gas temperature and the humidity at the wet transfer line would increase the accuracy of the calculations. An extra gas velocity sensor at the outlet would be useful...

  17. Development of an in vivo animal model for skin penetration in hairless rats assessed by mass balance

    DEFF Research Database (Denmark)

    Simonsen, Lene; Petersen, Mads B; Benfeldt, Eva

    2002-01-01

    acid and (14)C-butyl salicylate were topically applied. Rapid and differentiated percutaneous absorption of both compounds were shown by urinary excretion data. For (14)C-salicylic acid the amount on the skin surface, in the stratum corneum and in the viable skin was determined. Total mass balance...... rat and free mobility throughout the test period. By consecutive tape stripping, monitored by measurements of transepidermal water loss and confirmed by histological examination of skin biopsies, 10 tape strippings were found to remove the stratum corneum completely. For assessment of the model, (14)C-salicylic...

  18. The Impact of a Mild Sub-Critical Hydrothermal Carbonization Pretreatment on Umbila Wood. A Mass and Energy Balance Perspective

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Cuvilas

    2015-03-01

    Full Text Available Over the last years, the pretreatment of biomass as a source of energy has become one of the most important steps of biomass conversion. In this work the effect of a mild subcritical hydrothermal carbonization of a tropical woody biomass was studied. Results indicate considerable change in carbon content from 52.78% to 65.1%, reduction of oxygen content from 41.14% to 28.72% and ash slagging and fouling potential. Even though decarboxylation, decarbonylation and dehydration reactions take place, dehydration is the one that prevails. The mass and energy balance was affected by the treatment conditions than the severity of the treatment.

  19. Characterization of typical chemical background interferences in atmospheric pressure ionization liquid chromatography-mass spectrometry

    NARCIS (Netherlands)

    Guo, Xinghua; Bruins, Andries P.; Covey, Thomas R.

    2006-01-01

    The structures and origins of typical chemical background noise ions in positive atmospheric pressure ionization liquid chromatography/mass spectrometry (API LC/MS) are investigated and summarized in this study. This was done by classifying chemical background ions using precursor and product ion sc

  20. Investigating ice cliff evolution and contribution to glacier mass-balance using a physically-based dynamic model

    Science.gov (United States)

    Buri, Pascal; Miles, Evan; Ragettli, Silvan; Brun, Fanny; Steiner, Jakob; Pellicciotti, Francesca

    2016-04-01

    Supraglacial cliffs are a surface feature typical of debris-covered glaciers, affecting surface evolution, glacier downwasting and mass balance by providing a direct ice-atmosphere interface. As a result, melt rates can be very high and ice cliffs may account for a significant portion of the total glacier mass loss. However, their contribution to glacier mass balance has rarely been quantified through physically-based models. Most cliff energy balance models are point scale models which calculate energy fluxes at individual cliff locations. Results from the only grid based model to date accurately reflect energy fluxes and cliff melt, but modelled backwasting patterns are in some cases unrealistic, as the distribution of melt rates would lead to progressive shallowing and disappearance of cliffs. Based on a unique multitemporal dataset of cliff topography and backwasting obtained from high-resolution terrestrial and aerial Structure-from-Motion analysis on Lirung Glacier in Nepal, it is apparent that cliffs exhibit a range of behaviours but most do not rapidly disappear. The patterns of evolution cannot be explained satisfactorily by atmospheric melt alone, and are moderated by the presence of supraglacial ponds at the base of cliffs and by cliff reburial with debris. Here, we document the distinct patterns of evolution including disappearance, growth and stability. We then use these observations to improve the grid-based energy balance model, implementing periodic updates of the cliff geometry resulting from modelled melt perpendicular to the ice surface. Based on a slope threshold, pixels can be reburied by debris or become debris-free. The effect of ponds are taken into account through enhanced melt rates in horizontal direction on pixels selected based on an algorithm considering distance to the water surface, slope and lake level. We use the dynamic model to first study the evolution of selected cliffs for which accurate, high resolution DEMs are available

  1. A mass casualty incident involving children and chemical decontamination.

    Science.gov (United States)

    Timm, Nathan; Reeves, Scott

    2007-01-01

    Mass casualty incidents involving contaminated children are a rare but ever-present possibility. In this article we outline one such event that resulted in 53 pediatric patients and 3 adults presenting to the emergency department of a children's hospital for decontamination and treatment. We pay special attention to the training that allowed this responses to occur. We also outline the institutional response with emphasis on incident command, communication, and resource utilization. Specific lessons learned are explored in detail. Finally, we set forth a series of recommendations to assist other institutions should they be called upon to care for and decontaminate pediatric patients.

  2. Sea level changes from monthly solutions of ice sheet mass balance

    DEFF Research Database (Denmark)

    Barletta, Valentina Roberta; Sørensen, Louise Sandberg; Forsberg, René

    We present mass change time series at basin scale for both Greenland and Antarctica, de-rived from GRACE data, and use these data to find the associated global sea level changes. We use two independent methods for GRACE ice mass loss estimation, including use of different GIA models and estimation...... also compare our GRACE derived regional estimates with independent mass change results based on altimetry data from NASA’s Ice Cloud and land Elevation Satellite. From the estimated Greenland and Antarctica mass changes we compute the gravitationally self-consistent sea-level changes and its associated...... uncertainties, and show results of the impact of Earth model uncertainties in the global sea level change and its regional “fingerprints”....

  3. Phase Diagram of Wilson and Twisted Mass Fermions at finite isospin chemical potential

    CERN Document Server

    Kieburg, M; Verbaarschot, J J M; Zafeiropoulos, S

    2014-01-01

    Wilson Fermions with untwisted and twisted mass are widely used in lattice simulations. Therefore one important question is whether the twist angle and the lattice spacing affect the phase diagram. We briefly report on the study of the phase diagram of QCD in the parameter space of the degenerate quark masses, isospin chemical potential, lattice spacing, and twist angle by employing chiral perturbation theory. Moreover we calculate the pion masses and their dependence on these four parameters.

  4. Method to reduce chemical background interference in atmospheric pressure ionization liquid chromatography-mass spectrometry using exclusive reactions with the chemical reagent dimethyl disulfide

    NARCIS (Netherlands)

    Guo, Xinghua; Bruins, Andries P.; Covey, Thomas R.

    2007-01-01

    The interference of chemical background ions (chemical noise) has been a problem since the inception of mass spectrometry. We present here a novel method to reduce the chemical noise in LC-MS based on exclusive gas-phase reactions with a reactive collision gas in a triple-quadrupole mass spectromete

  5. Mass spectrometry analysis of polychlorinated biphenyls: chemical ionization and selected ion chemical ionization using methane as a reagent gas

    Directory of Open Access Journals (Sweden)

    RAYMOND E. MARCH

    2000-06-01

    Full Text Available In the present paper a quadrupole ion trap mass spectrometer, coupled with a gas chromatograph, was used to compare the electron impact ionization (EI and chemical ionization (Cl technique, in terms of their selectivity in polychlorinated biphenyls (PCBs quantitative analysis. The experiments were carried out with a modified Varian SATURN III quadrupole ion-storage mass spectrometer equipped with Varian waveform generator, coupled with a gas chromatograph with DB-5 capillary column. The disadvantage of using EI in the analysis of PCBs congeners is the extensive fragmentation of the molecular ion. The main fragmentation pattern recorded in the EI mass spectra of PCBs was the loss of a chlorine atom from the molecular ion. Therefore the fragment-ion signal overlapped with the molecular-ion cluster of lower mass congener. The fragmentation reactions of PCBs are suppressed if methane is used as a reagent gas for chemical ionization, but fragment ions are also present in the spectrum as an obstruction for quantitative analysis. The most selective method for PCBs quantitative analysis appears to be Cl with mass-selected C2H5+ ions from methane, which results in a mass spectrum with a negligible amount of fragment ions.

  6. Elevation change of the Greenland ice sheet due to surface mass balance and firn processes, 1960-2013

    Science.gov (United States)

    Kuipers Munneke, P.; Ligtenberg, S. R. M.; Noël, B. P. Y.; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; van den Broeke, M. R.

    2015-06-01

    Observed changes in the surface elevation of the Greenland ice sheet are caused by ice dynamics, basal elevation change, surface mass balance (SMB) variability, and by compaction of the overlying firn. The latter two contributions are quantified here using a firn model that includes compaction, meltwater percolation, and refreezing. The model is forced with surface mass fluxes and temperature from a regional climate model for the period 1960-2013. The model results agree with observations of surface density, density profiles from 62 firn cores, and altimetric observations from regions where ice-dynamical surface height changes are likely small. We find that the firn layer in the high interior is generally thickening slowly (1-5 cm yr-1). In the percolation and ablation areas, firn and SMB processes account for a surface elevation lowering of up to 20-50 cm yr-1. Most of this firn-induced marginal thinning is caused by an increase in melt since the mid-1990s, and partly compensated by an increase in the accumulation of fresh snow around most of the ice sheet. The total firn and ice volume change between 1980 and 2013 is estimated at -3900 ± 1030 km3 due to firn and SMB, corresponding to an ice-sheet average thinning of 2.32 ± 0.61 m. Most of this volume decrease occurred after 1995. The computed changes in surface elevation can be used to partition altimetrically observed volume change into surface mass balance and ice-dynamically related mass changes.

  7. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960-2014

    Science.gov (United States)

    Kuipers Munneke, P.; Ligtenberg, S. R. M.; Noël, B. P. Y.; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; van den Broeke, M. R.

    2015-11-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes compaction, meltwater percolation, and refreezing. The model is forced with surface mass fluxes and temperature from a regional climate model for the period 1960-2014. The model results agree with observations of surface density, density profiles from 62 firn cores, and altimetric observations from regions where ice-dynamical surface height changes are likely small. In areas with strong surface melt, the firn model overestimates density. We find that the firn layer in the high interior is generally thickening slowly (1-5 cm yr-1). In the percolation and ablation areas, firn and SMB processes account for a surface elevation lowering of up to 20-50 cm yr-1. Most of this firn-induced marginal thinning is caused by an increase in melt since the mid-1990s and partly compensated by an increase in the accumulation of fresh snow around most of the ice sheet. The total firn and ice volume change between 1980 and 2014 is estimated at -3295 ± 1030 km3 due to firn and SMB changes, corresponding to an ice-sheet average thinning of 1.96 ± 0.61 m. Most of this volume decrease occurred after 1995. The computed changes in surface elevation can be used to partition altimetrically observed volume change into surface mass balance and ice-dynamically related mass changes.

  8. Chemical mass balance source apportionment of fine and PM10 in the Desert Southwest, USA

    Science.gov (United States)

    The Desert Southwest Coarse Particulate Matter Study was undertaken in Pinal County, Arizona, to better understand the origin and impact of sources of fine and coarse particulate matter (PM) in rural, arid regions of the U.S. southwestern desert. The desert southwest experiences ...

  9. Very high resolution surface mass balance over Greenland modeled by the regional climate model MAR with a downscaling technique

    Science.gov (United States)

    Kittel, Christoph; Lang, Charlotte; Agosta, Cécile; Prignon, Maxime; Fettweis, Xavier; Erpicum, Michel

    2016-04-01

    This study presents surface mass balance (SMB) results at 5 km resolution with the regional climate MAR model over the Greenland ice sheet. Here, we use the last MAR version (v3.6) where the land-ice module (SISVAT) using a high resolution grid (5km) for surface variables is fully coupled while the MAR atmospheric module running at a lower resolution of 10km. This online downscaling technique enables to correct near-surface temperature and humidity from MAR by a gradient based on elevation before forcing SISVAT. The 10 km precipitation is not corrected. Corrections are stronger over the ablation zone where topography presents more variations. The model has been force by ERA-Interim between 1979 and 2014. We will show the advantages of using an online SMB downscaling technique in respect to an offline downscaling extrapolation based on local SMB vertical gradients. Results at 5 km show a better agreement with the PROMICE surface mass balance data base than the extrapolated 10 km MAR SMB results.

  10. The impact of a seasonally ice free Arctic Ocean on the climate and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2011-07-01

    Full Text Available General circulation models (GCMs predict a rapid decrease in Arctic sea ice extent in the 21st century. The decline of September sea ice is expected to continue until the Arctic Ocean is seasonally ice free, leading to a much perturbed Arctic climate with large changes in surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers which are extremely sensitive to changes in climate. Records of past accumulation indicate that the surface mass balance (SMB of Svalbard is also sensitive to changes in the position of the sea ice edge.

    To investigate the impact of 21st Century sea ice decline on the climate and surface mass balance of Svalbard a high resolution (25 km regional climate model (RCM was forced with a repeating cycle of sea surface temperatures (SSTs and sea ice conditions for the periods 1961–1990 and 2061–2090. By prescribing 20th Century SSTs and 21st Century sea ice for one simulation, the impact of sea ice decline is isolated. This study shows that the coupled impact of sea ice decline and SST increase results in a decrease in SMB, whereas the impact of sea ice decline alone causes an increase in SMB of similar magnitude.

  11. High-resolution simulations of the surface mass balance of Greenland at the end of this century

    Directory of Open Access Journals (Sweden)

    G. Krinner

    2007-09-01

    Full Text Available We present atmospheric general circulation model simulations of the present (1981–2005 and future (2081–2100 climate according to the SRES A1B greenhouse gas scenario. Focusing on Greenland, we use a stretched grid in the global model, thereby reaching a horizontal grid spacing of 60 km in the region of interest. This allows to capture reasonably the escarpment zone of the ice sheet. For the end of this century, the model suggests a precipitation increase in the central region of Greenland, which is overcompensated for by a strong increase of meltwater production in the lower areas. We calculate the changes of water fluxes into the adjacent seas according the simulated surface mass balances changes. The calculated freshwater flux at the end of the 21st century appears too weak to induce a significant reduction of the meridional overturning circulation in the North Atlantic. The resulting surface mass balance decrease between the last decades of the 20th and 21st centuries is equivalent to a positive contribution of 0.8 mm yr−1 to global eustatic sea-level rise.

  12. Increasing meltwater discharge from the Nuuk region of the Greenland ice sheet and implications for mass balance (1960-2012)

    DEFF Research Database (Denmark)

    van As, Dirk; Langer Andersen, Morten; Petersen, Dorthe

    2014-01-01

    We assess the runoff and surface mass balance (SMB) of the Greenland ice sheet in the Nuuk region (southwest) using output of two regional climate models (RCMs) evaluated by observations. The region encompasses six glaciers that drain into Godthåbsfjord. RCM data (1960-2012) are resampled to a hi...... of the marine-terminating glaciers, the region lost 10-20km3w.e. a-1 in 2010-12. If 2010 melting prevails during the remainder of this century, a low-end estimate of sea-level rise of 5mm is expected by 2100 from this relatively small section (2.6%) of the ice sheet alone.......We assess the runoff and surface mass balance (SMB) of the Greenland ice sheet in the Nuuk region (southwest) using output of two regional climate models (RCMs) evaluated by observations. The region encompasses six glaciers that drain into Godthåbsfjord. RCM data (1960-2012) are resampled to a high...... spatial resolution to include the narrow (relative to the native grid spacing) glacier trunks in the ice mask. Comparing RCM gridded results with automaticweather station (AWS) point measurements reveals that locally models can underestimate ablation andoverestimate accumulation by up to tens of per cent...

  13. A single dose mass balance study of the Hedgehog pathway inhibitor vismodegib (GDC-0449) in humans using accelerator mass spectrometry.

    Science.gov (United States)

    Graham, Richard A; Lum, Bert L; Morrison, Glenn; Chang, Ilsung; Jorga, Karin; Dean, Brian; Shin, Young G; Yue, Qin; Mulder, Teresa; Malhi, Vikram; Xie, Minli; Low, Jennifer A; Hop, Cornelis E C A

    2011-08-01

    Vismodegib (GDC-0449), a small-molecule Hedgehog pathway inhibitor, was well tolerated in patients with solid tumors and showed promising efficacy in advanced basal cell carcinoma in a Phase I trial. The purpose of the study presented here was to determine routes of elimination and the extent of vismodegib metabolism, including assessment and identification of metabolites in plasma, urine, and feces. Six healthy female subjects of nonchildbearing potential were enrolled; each received a single 30-ml oral suspension containing 150 mg of vismodegib with 6.5 μg of [(14)C]vismodegib to yield a radioactivity dose of approximately 37 kBq (1000 nCi). Plasma, urine, and feces samples were collected over 56 days to permit sample collection for up to 5 elimination half-lives. Nonradioactive vismodegib was measured in plasma using liquid chromatographic-tandem mass spectrometry, and total radioactivity in plasma, urine, and feces was measured using accelerator mass spectrometry. Vismodegib was slowly eliminated by a combination of metabolism and excretion of parent drug, most of which was recovered in feces. The estimated excretion of the administered dose was 86.6% on average, with 82.2 and 4.43% recovered in feces and urine, respectively. Vismodegib was predominant in plasma, with concentrations representing >98% of the total circulating drug-related components. Metabolic pathways of vismodegib in humans included oxidation, glucuronidation, and uncommon pyridine ring cleavage. We conclude that vismodegib and any associated metabolic products are mainly eliminated through feces after oral administration in healthy volunteers.

  14. Balanced conditions or slight mass gain of glaciers in the Lahaul and Spiti region (northern India, Himalaya during the nineties preceded recent mass loss

    Directory of Open Access Journals (Sweden)

    C. Vincent

    2013-04-01

    Full Text Available The volume change of the Chhota Shigri Glacier (India, 32° 20 N, 77° 30' E between 1988 and 2010 has been determined using in situ geodetic measurements. This glacier has experienced only a slight mass loss between 1988 and 2010 (−3.8 ± 2.0 m w.e. (water equivalent corresponding to −0.17 ± 0.09 m w.e. yr−1. Using satellite digital elevation models (DEM differencing and field measurements, we measure a negative mass balance (MB between 1999 and 2010 (−4.8 ± 1.8 m w.e. corresponding to −0.44 ± 0.16 m w.e. yr−1. Thus, we deduce a slightly positive or near-zero MB between 1988 and 1999 (+1.0 ± 2.7 m w.e. corresponding to +0.09 ± 0.24 m w.e. yr−1. Furthermore, satellite DEM differencing reveals that the MB of the Chhota Shigri Glacier (−0.39 ± 0.15 m w.e. yr−1 has been only slightly less negative than the MB of a 2110 km2 glaciarized area in the Lahaul and Spiti region (−0.44 ± 0.09 m w.e. yr−1 during 1999−2011. Hence, we conclude that the ice wastage is probably moderate in this region over the last 22 yr, with near equilibrium conditions during the nineties, and an ice mass loss after. The turning point from balanced to negative mass budget is not known but lies probably in the late nineties and at the latest in 1999. This positive or near-zero MB for Chhota Shigri Glacier (and probably for the surrounding glaciers of the Lahaul and Spiti region during at least part of the 1990s contrasts with a recent compilation of MB data in the Himalayan range that indicated ice wastage since 1975. However, in agreement with this compilation, we confirm more negative balances since the beginning of the 21st century.

  15. Estimation of glacier mass balance: An approach based on satellite-derived transient snowlines and a temperature index driven by meteorological observations

    Science.gov (United States)

    Tawde, S. A.; Kulkarni, A. V.; Bala, G.

    2015-12-01

    In the Himalaya, large area is comprised of glaciers and seasonal snow, mainly due to its high elevated mountain ranges. Long term and continuous assessment of glaciers in this region is important for climatological and hydrological applications. However, rugged terrains and severe weather conditions in the Himalaya lead to paucity in field observations. Therefore, in recent decades, glacier dynamics are extensively monitored using remote sensing in inaccessible terrain like Himalaya. Estimation of glacier mass balance using empirical relationship between mass balance and area accumulation ratio (AAR) requires an accurate estimate of equilibrium-line altitude (ELA). ELA is defined as the snowline at the end of the hydrological year. However, identification of ELA, using remote sensing is difficult because of temporal gaps, cloud cover and intermediate snowfall on glaciers. This leads to large uncertainty in glacier mass-balance estimates by the conventional AAR method that uses satellite-derived highest snowline in ablation season as an ELA. The present study suggests a new approach to improve estimates of ELA location. First, positions of modelled snowlines are optimized using satellite-derived snowlines in the early melt season. Secondly, ELA at the end of the glaciological year is estimated by the melt and accumulation models driven using in situ temperature and precipitation records. From the modelled ELA, mass balance is estimated using the empirical relationship between AAR and mass balance. The modelled mass balance is validated using field measurements on Chhota Shigri and Hamtah glaciers, Himachal Pradesh, India. The new approach shows a substantial improvement in glacier mass-balance estimation, reducing bias by 46% and 108% for Chhota Shigiri and Hamtah glaciers respectively. The cumulative mass loss reconstructed from our approach is 0.85 Gt for nine glaciers in the Chandra basin from 2001 to 2009. The result of the present study is in agreement with

  16. Model of operating and balancing assembly line in a mass customization environment

    Institute of Scientific and Technical Information of China (English)

    Wei Dong; Jin Ye; Wang Rong; Wang Zheng

    2003-01-01

    The successful implementation of mass customization lies on reengineering technology and management methods to organize the production. Especially in assembly phase, various product con figurations, due-time penalties and order-driven strategy challenge the traditional operation and man agement of assembly lines. The business features and the operation pattern of assembly line based on mass customization are analyzed. And the research emphatically studies various technologic factors to improve customer satisfaction and their corresponding implement methods in operating assembly line.In addition, the models are proposed for operating assembly line under dynamic process environment in mass customization. A genetic approach is developed to provide the optimal solution to the models.The effectiveness of the proposed approach is evaluated with an industrial application.

  17. Surface desorption atmospheric pressure chemical ionization mass spectrometry for direct ambient sample analysis without toxic chemical contamination.

    Science.gov (United States)

    Chen, Huanwen; Zheng, Jian; Zhang, Xie; Luo, Mingbiao; Wang, Zhichang; Qiao, Xiaolin

    2007-08-01

    Ambient mass spectrometry, pioneered with desorption electrospray ionization (DESI) technique, is of increasing interest in recent years. In this study, a corona discharge ionization source is adapted for direct surface desorption chemical ionization of compounds on various surfaces at atmospheric pressure. Ambient air, with about 60% relative humidity, is used as a reagent to generate primary ions such as H(3)O(+), which is then directed to impact the sample surface for desorption and ionization. Under experimental conditions, protonated or deprotonated molecules of analytes present on various samples are observed using positive or negative corona discharge. Fast detection of trace amounts of analytes present in pharmaceutical preparations, viz foods, skins and clothes has been demonstrated without any sample pretreatment. Taking the advantage of the gasless setup, powder samples such as amino acids and mixtures of pharmaceutical preparations are rapidly analyzed. Impurities such as sudan dyes in tomato sauce are detected semiquantitatively. Molecular markers (e.g. putrescine) for meat spoilage are successfully identified from an artificially spoiled fish sample. Chemical warfare agent stimulants, explosives and herbicides are directly detected from the skin samples and clothing exposed to these compounds. This provides a detection limit of sub-pg (S/N > or = 3) range in MS2. Metabolites and consumed chemicals such as glucose are detected successfully from human skins. Conclusively, surface desorption atmospheric pressure chemical ionization (DAPCI) mass spectrometry, without toxic chemical contamination, detects various compounds in complex matrices, showing promising applications for analyses of human related samples.

  18. New Balancing Equipment for Mass Production of Small and Medium-Sized Electrical Machines

    DEFF Research Database (Denmark)

    Argeseanu, Alin; Ritchie, Ewen; Leban, Krisztina Monika

    2010-01-01

    The level of vibration and noise is an important feature. It is good practice to explain the significance of the indicators of the quality of electrical machines. The mass production of small and medium-sized electrical machines demands speed (short typical measurement time), reliability...

  19. Balancing the false negative and positive rates in suspect screening with high-resolution Orbitrap mass spectrometry using multivariate statistics.

    Science.gov (United States)

    Vergeynst, Leendert; Van Langenhove, Herman; Demeestere, Kristof

    2015-02-17

    Modern high-resolution mass spectrometry (HRMS) enables full-spectrum trace level analysis of emerging environmental organic contaminants. This raises the opportunity for post-acquisition suspect screening when no reference standards are a priori available. When setting up a conventional screening identification train based on successively different identification criteria including mass error and isotope fit, the false negative rate typically accumulates upon advancing through the decision tree. The challenge is thus to elaborate a well-balanced screening, in which the different criteria are equally stringent, leading to a controllable number of false negatives. Presented is a novel suspect screening approach using liquid-chromatography Orbitrap HRMS. Based on a multivariate statistical model, the screening takes into account the accurate mass error of the mono isotopic ion and up to three isotopes, isotope ratios, and a peak/noise filter. As such, for the first time, controlling the overall false negative rate of the screening algorithm to a desired level (5% in this study) is achieved. Simultaneously, a well-balanced identification decision is guaranteed taking the different identification criteria as a whole in a holistic statistical approach. Taking into account 1, 2, and 3 isotopes decreases the false positive rate from 22, 2.8 to <0.3%, but the cost of increasing the median limits of identification from 200, 2000 to 2062 ng L(-1), respectively, should also be considered. As proof of concept, 7 biologically treated wastewaters were screened toward 77 suspect pharmaceuticals resulting in the indicative identification of 25 suspects. Subsequently obtained reference standards allowed confirmation for 19 out of these 25 pharmaceutical contaminants.

  20. Real time monitoring of accelerated chemical reactions by ultrasonication-assisted spray ionization mass spectrometry.

    Science.gov (United States)

    Lin, Shu-Hsuan; Lo, Ta-Ju; Kuo, Fang-Yin; Chen, Yu-Chie

    2014-01-01

    Ultrasonication has been used to accelerate chemical reactions. It would be ideal if ultrasonication-assisted chemical reactions could be monitored by suitable detection tools such as mass spectrometry in real time. It would be helpful to clarify reaction intermediates/products and to have a better understanding of reaction mechanism. In this work, we developed a system for ultrasonication-assisted spray ionization mass spectrometry (UASI-MS) with an ~1.7 MHz ultrasonic transducer to monitor chemical reactions in real time. We demonstrated that simply depositing a sample solution on the MHz-based ultrasonic transducer, which was placed in front of the orifice of a mass spectrometer, the analyte signals can be readily detected by the mass spectrometer. Singly and multiply charged ions from small and large molecules, respectively, can be observed in the UASI mass spectra. Furthermore, the ultrasonic transducer used in the UASI setup accelerates the chemical reactions while being monitored via UASI-MS. The feasibility of using this approach for real-time acceleration/monitoring of chemical reactions was demonstrated. The reactions of Girard T reagent and hydroxylamine with steroids were used as the model reactions. Upon the deposition of reactant solutions on the ultrasonic transducer, the intermediate/product ions are readily generated and instantaneously monitored using MS within 1 s. Additionally, we also showed the possibility of using this reactive UASI-MS approach to assist the confirmation of trace steroids from complex urine samples by monitoring the generation of the product ions.

  1. Mass Balance of the Northern Antarctic Peninsula and its Ongoing Response to Ice Shelf Loss

    Science.gov (United States)

    Scambos, T. A.; Berthier, E.; Haran, T. M.; Shuman, C. A.; Cook, A. J.; Bohlander, J. A.

    2012-12-01

    An assessment of the most rapidly changing areas of the Antarctic Peninsula (north of 66°S) shows that ice mass loss for the region is dominated by areas affected by eastern-Peninsula ice shelf losses in the past 20 years. Little if any of the mass loss is compensated by increased snowfall in the northwestern or far northern areas. We combined satellite stereo-image DEM differencing and ICESat-derived along-track elevation changes to measure ice mass loss for the Antarctic Peninsula north of 66°S between 2001-2010, focusing on the ICESat-1 period of operation (2003-2009). This mapping includes all ice drainages affected by recent ice shelf loss in the northeastern Peninsula (Prince Gustav, Larsen Inlet, Larsen A, and Larsen B) as well as James Ross Island, Vega Island, Anvers Island, Brabant Island and the adjacent west-flowing glaciers. Polaris Glacier (feeding the Larsen Inlet, which collapsed in 1986) is an exception, and may have stabilized. Our method uses ASTER and SPOT-5 stereo-image DEMs to determine dh/dt for elevations below 800 m; at higher elevations ICESat along-track elevation differencing is used. To adjust along-track path offsets between its 2003-2009 campaigns, we use a recent DEM of the Peninsula to establish and correct for cross-track slope (Cook et al., 2012, doi:10.5194/essdd-5-365-2012; http://nsidc.org/data/nsidc-0516.html) . We reduce the effect of possible seasonal variations in elevation by using only integer-year repeats of the ICESat tracks for comparison. Mass losses are dominated by the major glaciers that had flowed into the Prince Gustav (Boydell, Sjorgren, Röhss), Larsen A (Edgeworth, Bombardier, Dinsmoor, Drygalski), and Larsen B (Hektoria, Jorum, and Crane) embayments. The pattern of mass loss emphasizes the significant and multi-decadal response to ice shelf loss. Areas with shelf losses occurring 30 to 100s of years ago seem to be relatively stable or losing mass only slowly (western glaciers, northernmost areas). The

  2. Fate of perfluoroalkyl acids in the aquatic environment with a focus on mass balance studies

    OpenAIRE

    2015-01-01

    Perfluoroalkyl substances (PFASs) are man-made chemicals. Their unique properties make them beneficial for a wide range of industrial and consumer product applications, such as in aqueous film forming foam (AFFF), durable water repellent clothing, hydraulic oils and food packaging materials. Perfluoroalkyl acids (PFAAs), a class of PFASs, are highly persistent in the environment, and long chain PFAAs are bioaccumulative and toxic. International regulation and voluntary actions by the industry...

  3. Vanadium methyl-bipyridine organoligand and its influence on energy balance and organs mass.

    Science.gov (United States)

    Krośniak, Mirosław; Francik, Renata; Wojtanowska-Krośniak, Agnieszka; Tedeschi, Cinzia; Krasoń-Nowak, Małgorzata; Chłopicka, Joanna; Gryboś, Ryszard

    2014-09-01

    In the treatment of lifestyle diseases, including metabolic syndrome and type 2 diabetes, it is important to lower body mass and fat tissue, and consequently, to increase insulin-sensitivity. Unfortunately, it often happens that low-energy diet which would lower overweight is not observed and, thus, it does not bring the expected effects. This paper discusses the influence of three diets-control, high-fructose, and high-fatty diet-on absorption of energy from food in order to transform it into body mass. The kJ/g ratio which describes this process has been calculated. In the tested diets, the addition of fructose (79.13 ± 2.47 kJ/g) or fat (82.48 ± 2.28 kJ/g) results in higher transformation of energy into body mass than in the case of control diet (89.60 ± 1.86 kJ/g). The addition of Na[VO(O2)2(4,4′-Me2-2,2′-bpy)]•8H2O (where 4,4′-Me2-2,2′-bpy = 4,4′-dimethyl-2,2′-bipyridine) results in statistical increase of that ratio: fructose diet (86.88 ± 0.44 kJ/g), fat diet (104.68 ± 3.01 kJ/g), and control diet (115.98 ± 0.56 kJ/g), respectively. Fat diet statistically influences the decrease of kidney mass in comparison to the other diets. The application of the tested vanadium compound results also in the statistical decrease of the fatty liver caused by fructose and fat diet.

  4. Exact Mass Measurements for a-Allenic Alcohol by Atmospheric Pressure Chemical Ionization/Time-of-flight Mass Spectrometry

    Institute of Scientific and Technical Information of China (English)

    何萍; 郭寅龙; 陈国强; 徐代旺; 麻生明

    2003-01-01

    The atmospheric pressure chemical ionization/time,of-flight mass speetrmtry (APEI/TOF-MS) was applied to determine the mass of five a.aIIenic alcohols via their vrotonated molecu.lar ions nslna Imsifive ion mode. Polyethylene Idycol (PEG) was used as the hlternal reference. All results were obtained under the resolution of about 5000 FWHM (full width at the half maximum). Solvent effects were studied and the satired results were obtained in acetonitrile. Comvared with the theoreflcal values, nun absolute errors were less thRn 1.0 mmu. The efTeets Of nozzle pote.Jldal, push pulse potential, pug pulse potentlai, puO bias potential and ic(lulsltion rate on exact mass determina/lon were also discussed. APCI/TOF.MS is proven to be a very semi/ire analytical technique and an alternative ionizafion mode in analytical technique lablle compounds with relatively weak polarity, such as a-allenic alcohol.

  5. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste.

    Science.gov (United States)

    Danon-Schaffer, Monica N; Mahecha-Botero, Andrés; Grace, John R; Ikonomou, Michael

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables.

  6. Assessing the uncertainty of glacier mass-balance simulations in the European Arctic based on variance decomposition

    Science.gov (United States)

    Sauter, T.; Obleitner, F.

    2015-12-01

    State-of-the-art numerical snowpack models essentially rely on observational data for initialization, forcing, parametrization, and validation. Such data are available in increasing amounts, but the propagation of related uncertainties in simulation results has received rather limited attention so far. Depending on their complexity, even small errors can have a profound effect on simulations, which dilutes our confidence in the results. This paper aims at quantification of the overall and fractional contributions of some archetypical measurement uncertainties on snowpack simulations in arctic environments. The sensitivity pattern is studied at two sites representing the accumulation and ablation area of the Kongsvegen glacier (Svalbard), using the snowpack scheme Crocus. The contribution of measurement errors on model output variance, either alone or by interaction, is decomposed using global sensitivity analysis. This allows one to investigate the temporal evolution of the fractional contribution of different factors on key model output metrics, which provides a more detailed understanding of the model's sensitivity pattern. The analysis demonstrates that the specified uncertainties in precipitation and long-wave radiation forcings had a strong influence on the calculated surface-height changes and surface-energy balance components. The model output sensitivity patterns also revealed some characteristic seasonal imprints. For example, uncertainties in long-wave radiation affect the calculated surface-energy balance throughout the year at both study sites, while precipitation exerted the most influence during the winter and at the upper site. Such findings are valuable for identifying critical parameters and improving their measurement; correspondingly, updated simulations may shed new light on the confidence of results from snow or glacier mass- and energy-balance models. This is relevant for many applications, for example in the fields of avalanche and

  7. Inter-comparison of ice sheet mass balance products from GRACE: ESA CCI Round Robin results

    DEFF Research Database (Denmark)

    Groth, A.; Horwath, M.; Horvath, A.

    spatial resolution and complex error structures place particular demands on the applied processing strategy. To choose the most suitable algorithm which minimizes the impact of GRACE errors and signal leakage errors on GMB products, an open Round Robin experiment was set up. Participants were asked...... of the Earth (e.g. cryoshpere, ocean, continental hydrology). By comparing the derived synthetic mass changes with the a priori known 'synthetic truth', leakage errors can be quantified.Here we inter-compare the Round Robin results from six individual contributions, relying on different processing strategies...

  8. Temporal and spatial changes of Laika Glacier, Canadian Arctic, since 1959, inferred from satellite remote sensing and mass-balance modelling

    Science.gov (United States)

    Huss, Matthias; Stöckli, Reto; Kappenberger, Giovanni; Blatter, Heinz

    The retreat of Laika Glacier (4.4 km2), part of a small ice cap situated on Coburg Island, Canadian Arctic Archipelago, is analyzed using field data, satellite remote sensing and mass-balance modelling. We present a methodology for merging various data types and numerical models and investigate the temporal and spatial changes of a remote glacier during the past five decades. A glacier mass-balance and surface-evolution model is run for the period 1959-2006, forced with in situ weather observations and climate re-analysis data (ERA-40, NARR). The model is calibrated using the ice-volume change observed between 1959 and 1971, and measured seasonal mass balances. Calculated glacier surface elevation is validated against ICESat GLAS altimeter data and ASTER-derived elevation. Landsat-derived glacier outlines are used to validate calculated ice extent. The piedmont tongue of Laika Glacier has retreated considerably and is in a state of disintegration. The modelled glacier mass balance between 1959 and 2006 was -0.41 m w.e.a-1, on average. Model results indicate a significant trend towards higher mass-balance gradients. A complete wastage of Laika Glacier by 2100 is predicted by model runs based on climate scenarios.

  9. Intermediate mass dilepton production during the chemical equilibration of quark gluon plasma

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The production of dileptons from the chemically equilibrating quark gluon plasma in the intermediate mass region has been studied. Comparing with the calculated results based on the thermodynamic equilibrium system of quark gluon plasma, it has been found that the quark phase of the chemically equilibrating system gives rise to an even larger enhancement of the dileptons production. Therefore, such an enhancement of dilepton production may signal the formation of quark gluon plasma.

  10. Reversible Diffusion-Limited Reactions: "Chemical Equilibrium" State and the Law of Mass Action Revisited

    OpenAIRE

    Voituriez, R.; Moreau, M.; Oshanin, G.

    2004-01-01

    The validity of two fundamental concepts of classical chemical kinetics - the notion of "Chemical Equilibrium" and the "Law of Mass Action" - are re-examined for reversible \\textit{diffusion-limited} reactions (DLR), as exemplified here by association/dissociation $A+A \\rightleftharpoons B$ reactions. We consider a general model of long-ranged reactions, such that any pair of $A$ particles, separated by distance $\\mu$, may react with probability $\\omega_+(\\mu)$, and any $B$ may dissociate wit...

  11. Evolution of the Digital Society Reveals Balance between Viral and Mass Media Influence

    Science.gov (United States)

    Kleineberg, Kaj-Kolja; Boguñá, Marián

    2014-07-01

    Online social networks (OSNs) enable researchers to study the social universe at a previously unattainable scale. The worldwide impact and the necessity to sustain the rapid growth of OSNs emphasize the importance of unraveling the laws governing their evolution. Empirical results show that, unlike many real-world growing networked systems, OSNs follow an intricate path that includes a dynamical percolation transition. In light of these results, we present a quantitative two-parameter model that reproduces the entire topological evolution of a quasi-isolated OSN with unprecedented precision from the birth of the network. This allows us to precisely gauge the fundamental macroscopic and microscopic mechanisms involved. Our findings suggest that the coupling between the real preexisting underlying social structure, a viral spreading mechanism, and mass media influence govern the evolution of OSNs. The empirical validation of our model, on a macroscopic scale, reveals that virality is 4-5 times stronger than mass media influence and, on a microscopic scale, individuals have a higher subscription probability if invited by weaker social contacts, in agreement with the "strength of weak ties" paradigm.

  12. A STUDY TO DETERMINE THE ASSOCIATION OF BODY MASS INDEX WITH PERFORMANCE-BASED MEASURES OF BALANCE AND MOBILITY IN YOUNG ADULTS

    Directory of Open Access Journals (Sweden)

    Madhuri Gaur

    2015-08-01

    Full Text Available Background: The incidence of obesity is increasing in younger adults, with associated worsening of disability. Little is known about the impact of body mass index (BMI on performance-based balance and mobility measures in younger adults. Objective: The purpose of this study was to examine the association of BMI with measures of balance and mobility. Methods: Young adults who participated in the study (N=50 were classified as normal weight, overweight, moderately obese, or severely obese. Mobility and balance were assessed by performance-based measures. Pearson correlation test was used to examine the association among BMI, mobility, and balance after controlling for potential confounding variables. Results: There is a significant correlation between mobility and BMI at 0.01 levels. There is also a significant correlation between balance and BMI, though there was no correlation found between standing with narrow base balance and BMI. Conclusions: Higher BMI levels are associated with poorer mobility and balance. Furthermore, individuals classified as being of normal weight and those classified as overweight were similar in mobility and balance, whereas individuals with obesity had greater impairments in mobility and balance.

  13. Quantification and reduction of the uncertainty in mass balance models by Monte Carlo analysis of prior data

    Energy Technology Data Exchange (ETDEWEB)

    Lesht, B.M.

    1991-12-31

    The general objective of this workshop is to investigate and discuss methods by which uncertainties in mass balance models for toxics in the Great Lakes may be reduced. As described by the workshop prospectus, this paper is focused on problems of reducing (and quantifying) uncertainty as they relate to ``in situ field observations/system response measurements for the establishment of initial conditions, boundary conditions, calibration/confirmation data sets, and model post-audit data sets.`` I have taken this description to refer not only to the evaluation of uncertainty in the field observations themselves, but also to the uncertainty associated the analyses of in situ observations as they interact in the overall modeling process. Thus, I will be concerned here with quantification and reduction of uncertainty both (1) as they may be applied to descriptions of the system that is being modeled and (2) as they may be associated with model simulations.

  14. Quantification and reduction of the uncertainty in mass balance models by Monte Carlo analysis of prior data

    Energy Technology Data Exchange (ETDEWEB)

    Lesht, B.M.

    1991-01-01

    The general objective of this workshop is to investigate and discuss methods by which uncertainties in mass balance models for toxics in the Great Lakes may be reduced. As described by the workshop prospectus, this paper is focused on problems of reducing (and quantifying) uncertainty as they relate to in situ field observations/system response measurements for the establishment of initial conditions, boundary conditions, calibration/confirmation data sets, and model post-audit data sets.'' I have taken this description to refer not only to the evaluation of uncertainty in the field observations themselves, but also to the uncertainty associated the analyses of in situ observations as they interact in the overall modeling process. Thus, I will be concerned here with quantification and reduction of uncertainty both (1) as they may be applied to descriptions of the system that is being modeled and (2) as they may be associated with model simulations.

  15. Atmospheric bromine flux from the coastal Abu Dhabi sabkhat: A ground-water mass-balance investigation

    Science.gov (United States)

    Wood, Warren W.; Sanford, Ward E.

    2007-07-01

    A solute mass-balance study of ground water of the 3000 km2 coastal sabkhat (salt flats) of the Emirate of Abu Dhabi, United Arab Emirates, documents an annual bromide loss of approximately 255 metric tons (0.0032 Gmoles), or 85 kg/km2. This value is an order of magnitude greater than previously published direct measurements from the atmosphere over an evaporative environment of a salar in Bolivia. Laboratory evidence, consistent with published reports, suggests that this loss is by vapor transport to the atmosphere. If this bromine flux to the atmosphere is representative of the total earth area of active salt flats then it is a significant, and generally under recognized, input to the global atmospheric bromide flux.

  16. Simulation of rock mass balance of two typical altered rocks in Wulong gold deposit of Liaoning, China

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Wulong gold deposit hosted in granite and fine-grained diorite dikes, is a typical gold deposit of quartz vein type. Granite and fine-grained diorite dikes in the ore deposit were altered by metallogenic fluid.Based on the altered zoning, the samples of petrochemistry were collected and major and trace elements were analyzed systematically. Calculation of rock mass balance shows that the major elements (SiO2, K2 O, P2O5,Fe2 O3) in the two typical altered rocks are clearly added into the altered system, and that trace elements (V,Y, Zr, Ni, Co, Sr) assume an increasing and decreasing tendencies in the altered granite and altered diorite dike, respectively. The fluid/rock ratios are 30.17-181.00 and 115.44-692.67 respectively for altered granite and altered diorite dike, they have profoundly effects on metallogenesis.

  17. Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign

    Science.gov (United States)

    Savarino, Joël; Vicars, William C.; Legrand, Michel; Preunkert, Suzanne; Jourdain, Bruno; Frey, Markus M.; Kukui, Alexandre; Caillon, Nicolas; Gil Roca, Jaime

    2016-03-01

    Variations in the stable oxygen isotope composition of atmospheric nitrate act as novel tools for studying oxidative processes taking place in the troposphere. They provide both qualitative and quantitative constraints on the pathways determining the fate of atmospheric nitrogen oxides (NO + NO2 = NOx). The unique and distinctive 17O excess (Δ17O = δ17O - 0.52 × δ18O) of ozone, which is transferred to NOx via oxidation, is a particularly useful isotopic fingerprint in studies of NOx transformations. Constraining the propagation of 17O excess within the NOx cycle is critical in polar areas, where there exists the possibility of extending atmospheric investigations to the glacial-interglacial timescale using deep ice core records of nitrate. Here we present measurements of the comprehensive isotopic composition of atmospheric nitrate collected at Dome C (East Antarctic Plateau) during the austral summer of 2011/2012. Nitrate isotope analysis has been here combined for the first time with key precursors involved in nitrate production (NOx, O3, OH, HO2, RO2, etc.) and direct observations of the transferrable Δ17O of surface ozone, which was measured at Dome C throughout 2012 using our recently developed analytical approach. Assuming that nitrate is mainly produced in Antarctica in summer through the OH + NO2 pathway and using concurrent measurements of OH and NO2, we calculated a Δ17O signature for nitrate on the order of (21-22 ± 3) ‰. These values are lower than the measured values that ranged between 27 and 31 ‰. This discrepancy between expected and observed Δ17O(NO3-) values suggests the existence of an unknown process that contributes significantly to the atmospheric nitrate budget over this East Antarctic region. However, systematic errors or false isotopic balance transfer functions are not totally excluded.

  18. Effect of body mass and melanism on heat balance in Liolaemus lizards of the goetschi clade.

    Science.gov (United States)

    Moreno Azócar, Débora Lina; Bonino, Marcelo Fabián; Perotti, María Gabriela; Schulte, James A; Abdala, Cristian Simón; Cruz, Félix Benjamín

    2016-04-15

    The body temperature of ectotherms depends on the environmental temperatures and behavioral adjustments, but morphology may also have an effect. For example, in colder environments, animals tend to be larger and to show higher thermal inertia, as proposed by Bergmann's rule and the heat balance hypothesis (HBH). Additionally, dark coloration increases solar radiation absorption and should accelerate heat gain (thermal melanism hypothesis, TMH). We tested Bergmann's rule, the HBH and the TMH within the ITALIC! Liolaemus goetschilizard clade, which shows variability in body size and melanic coloration. We measured heating and cooling rates of live and euthanized animals, and tested how morphology and color affect these rates. Live organisms show less variable and faster heating rates compared with cooling rates, suggesting behavioral and/or physiological adjustments. Our results support Bergmann's rule and the HBH, as larger species show slower heating and cooling rates. However, we did not find a clear pattern to support the TMH. The influence of dorsal melanism on heating by radiation was masked by the body size effect in live animals, and results from euthanized individuals also showed no clear effects of melanism on heating rates. Comparison among three groups of live individuals with different degrees of melanism did not clarify the influence of melanism on heating rates. However, when euthanized animals from the same three groups were compared, we observed that darker euthanized animals actually heat faster than lighter ones, favoring the TMH. Although unresolved aspects remain, body size and coloration influenced heat exchange, suggesting complex thermoregulatory strategies in these lizards, probably regulated through physiology and behavior, which may allow these small lizards to inhabit harsh weather environments.

  19. Very high resolution modelling of the Surface Mass Balance of the Greenland Ice Sheet: Present day conditions and future prospects.

    Science.gov (United States)

    Mottram, Ruth; Aðalgeirsdóttir, Guðfinna; Boberg, Fredrik; Hesselbjerg Christensen, Jens; Bøssing Christensen, Ole; Langen, Peter; Rodehacke, Christian; Stendel, Martin; Yang, Shuting

    2014-05-01

    Recent experiments with the Regional Climate Model (RCM) HIRHAM5 have produced new surface mass balance (SMB) estimates at the unprecedented high horizontal resolution of 0.05 degrees (~5.5km). These simulations indicate a present day SMB of 347 ± 98 Gt/year over the whole ice sheet averaged over the period 1989 - 2012 driven by the ERA-Interim reanalysis dataset. We validate accumulation rates over the ice sheet using estimates from shallow firn cores to confirm the importance of resolution to accurate estimates of accumulation. Comparison with PROMICE and GC-Net automatic weather station observations shows the model represents present day climate and climate variability well when driven by the ERA-Interim reanalysis dataset. Comparison with a simulation at 0.25 degrees (~27km) resolution from the same model shows a significantly different calculated SMB over the whole ice sheet, largely due to changes in precipitation distribution over Greenland. The very high resolution requires a more sophisticated treatment of sub-grid scale processes in the snow pack including meltwater retention and refreezing and an enhanced albedo scheme. Our results indicate retention processes account for a significant proportion of the total surface budget based on a new parameterization scheme in the model. SMB projections, driven by the EC-Earth Global Climate Model (GCM) at the boundaries for the RCP 4.5 scenario indicate a declining surface mass balance over the 21st century with some compensation for warmer summer temperatures and enhanced melt in the form of increased precipitation. A cold bias in the driving GCM for present day conditions suggests that this simulation likely underestimates the change in SMB. However, the downscaled precipitation fields compare well with those in the reanalysis driven simulations. A soon-to-be complete simulation uses driving fields from the GCM running the RCP8.5 scenario.

  20. Mass and heat flux balance of La Soufrière volcano (Guadeloupe) from aerial infrared thermal imaging

    Science.gov (United States)

    Gaudin, Damien; Beauducel, François; Coutant, Olivier; Delacourt, Christophe; Richon, Patrick; de Chabalier, Jean-Bernard; Hammouya, Gilbert

    2016-06-01

    La Soufrière of Guadeloupe is an active volcano of Lesser Antilles that is closely monitored due to a high eruptive hazard potential. Since 1992 it exhibits a medium-level but sustained background hydrothermal activity with low-energy and shallow seismicity, hot springs temperature increase and high flux acidic gas fumaroles at the summit. The problem of estimating the heat balance and quantifying the evolution of hydrothermal activity has become a key challenge for surveillance. This work is the first attempt of a global mapping and quantification of La Soufrière thermal activity performed in February 2010 using aerial thermal infrared imagery. After instrument calibration and data processing, we present a global map of thermal anomalies allowing to spot the main active sites: the summit area (including the fumaroles of Tarissan Pit and South Crater), the Ty Fault fumarolic zone, and the hot springs located at the vicinity of the dome. In a second step, we deduce the mass and the energy fluxes released by the volcano. In particular, we propose a simple model of energy balance to estimate the mass flux of the summit fumaroles from their brightness temperature and size. In February 2010, Tarissan Pit had a 22.8 ± 8.1 kg s -1 flux (1970 ± 704 tons day -1), while South Crater vents had a total of 19.5 ± 4.0 kg s -1 (1687 ± 348 tons day -1). Once converted into energy flux, summit fumaroles represent 98% of the 106 ± 30 MW released by the volcano, the 2% remaining being split between the hot springs and the thermal anomalies at the summit and at the Ty Fault fumarolic zone. These values are in the high range of the previous estimations, highlighting the short-term variability of the expelled fluxes. Such a heat flux requires the cooling of 1500 m 3 of magma per day, in good agreement with previous geochemical studies.

  1. Nitrogen attenuation in the Connecticut River, northeastern USA; a comparison of mass balance and N2 production modeling approaches

    Science.gov (United States)

    Smith, T.E.; Laursen, A.E.; Deacon, J.R.

    2008-01-01

    Two methods were used to measure in-stream nitrogen loss in the Connecticut River during studies conducted in April and August 2005. A mass balance on nitrogen inputs and output for two study reaches (55 and 66 km), at spring high flow and at summer low flow, was computed on the basis of total nitrogen concentrations and measured river discharges in the Connecticut River and its tributaries. In a 10.3 km subreach of the northern 66 km reach, concentrations of dissolved N2 were also measured during summer low flow and compared to modeled N2 concentrations (based on temperature and atmospheric gas exchange rates) to determine the measured "excess" N2 that indicates denitrification. Mass balance results showed no in-stream nitrogen loss in either reach during April 2005, and no nitrogen loss in the southern 55 km study reach during August 2005. In the northern 66 km reach during August 2005, however, nitrogen output was 18% less than the total nitrogen inputs to the reach. N2 sampling results gave an estimated rate of N2 production that would remove 3.3% of the nitrogen load in the river over the 10.3 km northern sub-reach. The nitrogen losses measured in the northern reach in August 2005 may represent an approximate upper limit for nitrogen attenuation in the Connecticut River because denitrification processes are most active during warm summer temperatures and because the study was performed during the annual low-flow period when total nitrogen loads are small. ?? 2008 Springer Science+Business Media B.V.

  2. Balancing health benefits and chemical risks associated to dietary habits: RIBEFOOD, a new Internet resource.

    Science.gov (United States)

    Martí-Cid, Roser; Bocio, Ana; Llobet, Juan M; Domingo, José L

    2008-02-28

    In recent years, a notable number of studies have shown that some foodstuffs might be a potential source of exposure to chemical pollutants, some of them with a well-known toxicity in humans. Based on the importance of a healthy diet, we have designed the software RIBEFOOD, a new Internet resource that allows the quantitative determination of the human intake of a long series of micro- and macronutrients contained in widely consumed foodstuffs, and with an important nutritional value. RIBEFOOD is also able to determine the dietary intake of a number of chemical contaminants (i.e., metals, dioxins and furans, PCBs, polycyclic aromatic hydrocarbons, etc.). In this paper, we introduce RIBEFOOD, and how it may be used as an easy Internet tool in order to optimize the dietary habits of any subject by increasing the intake of beneficial nutrients and by reducing that of toxic pollutants. RIBEFOOD can be useful not only for professionals (general physicians, nutritionists, endocrinologists, toxicologists, etc.), but also for the general population. It is available at: http://www.fmcs.urv.cat/ribefood/.

  3. Quantifying the Mass Balance of Ice Caps on Severnaya Zemlya, Russian High Arctic. III: Sensitivity of Ice Caps in Severnaya Zemlya to Future Climate Change

    OpenAIRE

    Bassford, R.P.; Siegert, M. J.; J. A. Dowdeswell

    2006-01-01

    A coupled surface mass balance and ice-flow model was used to predict the response of three ice caps on Severnaya Zemlya, Russian Arctic, to the present climate and to future climate changes as postulated by the Intergovernmental Panel on Climate Change (IPCC). Ice cap boundary conditions are derived from recent airborne geophysical surveying (Dowdeswell et al., 2002), and model inputs are constructed from available climate data. Model results indicate that, currently, the state of balance of...

  4. Navigating the Chemical Space of HCN Polymerization and Hydrolysis: Guiding Graph Grammars by Mass Spectrometry Data

    Directory of Open Access Journals (Sweden)

    Peter F. Stadler

    2013-09-01

    Full Text Available Polymers of hydrogen cyanide and their hydrolysis products constitute a plausible, but still poorly understood proposal for early prebiotic chemistry on Earth. HCN polymers are generated by the interplay of more than a dozen distinctive reaction mechanisms and form a highly complex mixture. Here we use a computational model based on graph grammars as a means of exploring the chemical spaces of HCN polymerization and hydrolysis. A fundamental issue is to understand the combinatorial explosion inherent in large, complex chemical systems. We demonstrate that experimental data, here obtained by mass spectrometry, and computationally predicted free energies together can be used to guide the exploration of the chemical space and makes it feasible to investigate likely pathways and chemical motifs even in potentially open-ended chemical systems.

  5. Mass Balance Changes and Ice Dynamics of Greenland and Antarctic Ice Sheets from Laser Altimetry

    Science.gov (United States)

    Babonis, G. S.; Csatho, B.; Schenk, T.

    2016-06-01

    During the past few decades the Greenland and Antarctic ice sheets have lost ice at accelerating rates, caused by increasing surface temperature. The melting of the two big ice sheets has a big impact on global sea level rise. If the ice sheets would melt down entirely, the sea level would rise more than 60 m. Even a much smaller rise would cause dramatic damage along coastal regions. In this paper we report about a major upgrade of surface elevation changes derived from laser altimetry data, acquired by NASA's Ice, Cloud and land Elevation Satellite mission (ICESat) and airborne laser campaigns, such as Airborne Topographic Mapper (ATM) and Land, Vegetation and Ice Sensor (LVIS). For detecting changes in ice sheet elevations we have developed the Surface Elevation Reconstruction And Change detection (SERAC) method. It computes elevation changes of small surface patches by keeping the surface shape constant and considering the absolute values as surface elevations. We report about important upgrades of earlier results, for example the inclusion of local ice caps and the temporal extension from 1993 to 2014 for the Greenland Ice Sheet and for a comprehensive reconstruction of ice thickness and mass changes for the Antarctic Ice Sheets.

  6. Textile protection of snow and ice: Measured and simulated effects on the energy- and mass balance

    Science.gov (United States)

    Olefs, Marc; Lehning, Michael

    2010-05-01

    Measurements and simulations of the energy fluxes and mass changes of an artificially covered snow and ice surface (geotextile material) and a reference plot within an Austrian glacier ski resort are presented and compared. A modified version of the snow cover model SNOWPACK is used to successfully reproduce the artificially compacted and the additionally covered snow cover in a physically based way. Supplementary measurements of crucial material properties of the 0.0045 m thin geotextile serve as model input as well. Results indicate that the shortwave reflectivity of the covers is responsible for half the performance (47%). Thermal insulation of the material (14%) and a negative latent heat flux due to evaporation of precipitation from the cover surface (10%) have almost the same contribution. An assumed layer of air between the cover and the snow and ice surface (thickness 0.075 m to 0.12 m) adds the rest, which is at the upper limit of observations and may therefore also compensate for model errors. This generally explains the high performance of the method in glacier skiing resorts and, most importantly, an altitude dependant application limit of the method: the method becomes less effective at lower altitudes, where sensible heat fluxes become more important compared to short wave radiation.

  7. Dynamics and mass balance of Taylor Glacier, Antarctica: 1. Geometry and surface velocities

    Science.gov (United States)

    Kavanaugh, J. L.; Cuffey, K. M.; Morse, D. L.; Conway, H.; Rignot, E.

    2009-11-01

    Taylor Glacier, Antarctica, exemplifies a little-studied type of outlet glacier, one that flows slowly through a region of rugged topography and dry climate. This glacier, in addition, connects the East Antarctic Ice Sheet with the McMurdo Dry Valleys, a region much studied for geomorphology, paleoclimate, and ecology. Here we report extensive new measurements of surface velocities, ice thicknesses, and surface elevations, acquired with InSAR, GPS, and GPR. The latter two were used to construct elevation models of the glacier's surface and bed. Ice velocities in 2002-2004 closely matched those in 2000 and the mid-1970s, indicating negligible interannual variations of flow. Comparing velocities with bed elevations shows that, along much of the glacier, flow concentrates in a narrow axis of relatively fast flowing ice that overlies a bedrock trough. The flow of the glacier over major undulations in its bed can be regarded as a “cascade” it speeds up over bedrock highs and through valley narrows and slows down over deep basins and in wide spots. This pattern is an expected consequence of mass conservation for a glacier near steady state. Neither theory nor data from this Taylor Glacier study support the alternative view, recently proposed, that an outlet glacier of this type trickles slowly over bedrock highs and flows fastest over deep basins.

  8. Fast Differential Analysis of Propolis Using Surface Desorption Atmospheric Pressure Chemical Ionization Mass Spectrometry

    Science.gov (United States)

    Huang, Xue-yong; Guo, Xia-li; Luo, Huo-lin; Fang, Xiao-wei; Zhu, Teng-gao; Zhang, Xing-lei; Chen, Huan-wen; Luo, Li-ping

    2015-01-01

    Mass spectral fingerprints of 24 raw propolis samples, including 23 from China and one from the United States, were directly obtained using surface desorption atmospheric pressure chemical ionization mass spectrometry (SDAPCI-MS) without sample pretreatment. Under the optimized experimental conditions, the most abundant signals were detected in the mass ranges of 70 to 500 m/z and 200 to 350 m/z, respectively. Principal component analyses (PCA) for the two mass ranges showed similarities in that the colors had a significant correlation with the first two PCs; in contrast there was no correlation with the climatic zones from which the samples originated. Analytes such as chrysin, pinocembrin, and quercetin were detected and identified using multiple stage mass spectrometry within 3 min. Therefore, SDAPCI-MS can be used for rapid and reliable high-throughput analysis of propolis. PMID:26339245

  9. Modelling the geometry of a moving laser melt pool and deposition track via energy and mass balances

    Science.gov (United States)

    Pinkerton, Andrew J.; Li, Lin

    2004-07-01

    The additive manufacturing technique of laser direct metal deposition allows multiple tracks of full density metallic material to be built to form complex parts for rapid tooling and manufacture. Practical results and theoretical models have shown that the geometries of the tracks are governed by multiple factors. Original work with single layer cladding identified three basic clad profiles but, so far, models of multiple layer, powder-feed deposition have been based on only two of them. At higher powder mass flow rates, experimental results have shown that a layer's width can become greater than the melt pool width at the substrate surface, but previous analytical models have not been able to accommodate this. In this paper, a model based on this third profile is established and experimentally verified. The model concentrates on mathematical analysis of the melt pool and establishes mass and energy balances based on one-dimensional heat conduction to the substrate. Deposition track limits are considered as arcs of circles rather than of ellipses, as used in most established models, reflecting the dominance of surface tension forces in the melt pool, and expressions for elongation of the melt pool with increasing traverse speed are incorporated. Trends in layer width and height with major process parameters are captured and predicted layer dimensions correspond well to the experimental values.

  10. Variable elimination in chemical reaction networks with mass-action kinetics

    DEFF Research Database (Denmark)

    Feliu, Elisenda; Wiuf, C.

    2012-01-01

    We consider chemical reaction networks taken with mass-action kinetics. The steady states of such a system are solutions to a system of polynomial equations. Even for small systems the task of finding the solutions is daunting. We develop an algebraic framework and procedure for linear elimination...

  11. On the graph and systems analysis of reversible chemical reaction networks with mass action kinetics

    NARCIS (Netherlands)

    Rao, Shodhan; Jayawardhana, Bayu; Schaft, Arjan van der

    2012-01-01

    Motivated by the recent progresses on the interplay between the graph theory and systems theory, we revisit the analysis of reversible chemical reaction networks described by mass action kinetics by reformulating it using the graph knowledge of the underlying networks. Based on this formulation, we

  12. Application and validation of long-range terrestrial laser scanning to monitor the mass balance of very small glaciers in the Swiss Alps

    Science.gov (United States)

    Fischer, Mauro; Huss, Matthias; Kummert, Mario; Hoelzle, Martin

    2016-06-01

    Due to the relative lack of empirical field data, the response of very small glaciers (here defined as being smaller than 0.5 km2) to current atmospheric warming is not fully understood yet. Investigating their mass balance, e.g. using the direct glaciological method, is a prerequisite to fill this knowledge gap. Terrestrial laser scanning (TLS) techniques operating in the near infrared range can be applied for the creation of repeated high-resolution digital elevation models and consecutive derivation of annual geodetic mass balances of very small glaciers. This method is promising, as laborious and potentially dangerous field measurements as well as the inter- and extrapolation of point measurements can be circumvented. However, it still needs to be validated. Here, we present TLS-derived annual surface elevation and geodetic mass changes for five very small glaciers in Switzerland (Glacier de Prapio, Glacier du Sex Rouge, St. Annafirn, Schwarzbachfirn, and Pizolgletscher) and two consecutive years (2013/14-2014/15). The scans were acquired with a long-range Riegl -6000 especially designed for surveying snow- and ice-covered terrain. Zonally variable conversion factors for firn and bare ice surfaces were applied to convert geodetic volume to mass changes. We compare the geodetic results to direct glaciological mass balance measurements coinciding with the TLS surveys and assess the uncertainties and errors included in both methods. Average glacier-wide mass balances were negative in both years, showing stronger mass losses in 2014/15 (-1.65 m w.e.) compared to 2013/14 (-0.59 m w.e.). Geodetic mass balances were slightly less negative but in close agreement with the direct glaciological ones (R2 = 0.91). Due to the dense in situ measurements, the uncertainties in the direct glaciological mass balances were small compared to the majority of measured glaciers worldwide (±0.09 m w.e. yr-1 on average), and similar to uncertainties in the TLS-derived geodetic mass

  13. The effect of intermediate mass close binaries on the chemical evolution of Globular Clusters II

    CERN Document Server

    Mennekens, N; De Greve, J P

    2013-01-01

    The chemical processes during the Asymptotic Giant Branch (AGB) evolution of intermediate mass single stars predict most of the observations of the different populations in Globular Clusters although some important issues still need to be further clarified. In particular, to reproduce the observed anticorrelations of Na-O and Al-Mg, chemically enriched gas lost during the AGB phase of intermediate mass single stars must be mixed with matter with a pristine chemical composition. The source of this matter is still a matter of debate. Furthermore, observations reveal that a significant fraction of the intermediate mass and massive stars are born as components of close binaries. We will investigate the effects of binaries on the chemical evolution of Globular Clusters and on the origin of matter with a pristine chemical composition that is needed for the single star AGB scenario to work. We use a population synthesis code that accounts for binary physics in order to estimate the amount and the composition of the ...

  14. Robust automated mass spectra interpretation and chemical formula calculation using mixed integer linear programming.

    Science.gov (United States)

    Baran, Richard; Northen, Trent R

    2013-10-15

    Untargeted metabolite profiling using liquid chromatography and mass spectrometry coupled via electrospray ionization is a powerful tool for the discovery of novel natural products, metabolic capabilities, and biomarkers. However, the elucidation of the identities of uncharacterized metabolites from spectral features remains challenging. A critical step in the metabolite identification workflow is the assignment of redundant spectral features (adducts, fragments, multimers) and calculation of the underlying chemical formula. Inspection of the data by experts using computational tools solving partial problems (e.g., chemical formula calculation for individual ions) can be performed to disambiguate alternative solutions and provide reliable results. However, manual curation is tedious and not readily scalable or standardized. Here we describe an automated procedure for the robust automated mass spectra interpretation and chemical formula calculation using mixed integer linear programming optimization (RAMSI). Chemical rules among related ions are expressed as linear constraints and both the spectra interpretation and chemical formula calculation are performed in a single optimization step. This approach is unbiased in that it does not require predefined sets of neutral losses and positive and negative polarity spectra can be combined in a single optimization. The procedure was evaluated with 30 experimental mass spectra and was found to effectively identify the protonated or deprotonated molecule ([M + H](+) or [M - H](-)) while being robust to the presence of background ions. RAMSI provides a much-needed standardized tool for interpreting ions for subsequent identification in untargeted metabolomics workflows.

  15. The mass balance calculation of hydrothermal alteration in Sarcheshmeh porphyry copper deposit

    Directory of Open Access Journals (Sweden)

    Mohammad Maanijou

    2013-10-01

    Full Text Available Sarcheshmeh porphyry copper deposit is located 65 km southwest of Rafsanjan in Kerman province. The Sarcheshmeh deposit belongs to the southeastern part of Urumieh-Dokhtar magmatic assemblage (i.e., Dehaj-Sarduyeh zone. Intrusion of Sarcheshmeh granodiorite stock in faulted and thrusted early-Tertiary volcano-sedimentary deposits, led to mineralization in Miocene. In this research, the mass changes and element mobilities during hydrothermal process of potassic alteration were studied relative to fresh rock from the deeper parts of the plutonic body, phyllic relative to potassic, argillic relative to phyllic and propylitic alteration relative to fresh andesites surrounding the deposit. In the potassic zone, enrichment in Fe2O3 and K2O is so clear, because of increasing Fe coming from biotite alteration and presence of K-feldspar, respectively. Copper and molybdenum enrichments resulted from presence of chalcopyrite, bornite and molybdenite mineralization in this zone. Enrichment of SiO2 and depletion of CaO, MgO, Na2O and K2O in the phyllic zone resulted from leaching of sodium, calcium and magnesium from the aluminosilicate rocks and alteration of K-feldspar to sericite and quartz. In the argillic zone, Al2O3, CaO, MgO, Na2O and MnO have also been enriched in which increasing Al2O3 may be from kaolinite and illite formation. Also, enrichment in SiO2, Al2O3 and CaO in propylitic alteration zone can be attributed to the formation of chlorite, epidote and calcite as indicative minerals of this zone.

  16. Oxygen Isotope Mass-Balance Constraints on Pliocene Sea Level and East Antarctic Ice Sheet Stability

    Science.gov (United States)

    Winnick, M. J.; Caves, J. K.

    2015-12-01

    The mid-Pliocene Warm Period (MPWP, 3.3-2.9 Ma), with reconstructed atmospheric pCO2 of 350-450 ppm, represents a potential analogue for climate change in the near future. Current highly cited estimates place MPWP maximum global mean sea level (GMSL) at 21 ± 10 m above modern, requiring total loss of the Greenland (GIS) and marine West Antarctic Ice Sheets (WAIS) and a substantial loss of the East Antarctic Ice Sheet (EAIS), with only a concurrent 2-3 ºC rise in global temperature. Many estimates of Pliocene GMSL are based on the partitioning of oxygen isotope records from benthic foraminifera (δ18Ob) into changes in deep-sea temperatures and terrestrial ice sheets. These isotopic budgets are underpinned by the assumption that the δ18O of Antarctic ice (δ18Oi) was the same in the Pliocene as it is today, and while the sensitivity of δ18Ob to changing meltwater δ18O has been previously considered, these analyses neglect conservation of 18O/16O in the ocean-ice system. Using well-calibrated δ18O-temperature relationships for Antarctic precipitation along with estimates of Pliocene Antarctic surface temperatures, we argue that the δ18Oi of the Pliocene Antarctic ice sheet was at minimum 1‰-4‰ higher than present. Assuming conservation of 18O/16O in the ocean-ice system, this requires lower Pliocene seawater δ18O (δ18Osw) without a corresponding change in ice sheet mass. This effect alone accounts for 5%-20% of the δ18Ob difference between the MPWP interglacials and the modern. With this amended isotope budget, we suggest that Pliocene GMSL was likely 9-13.5 m and very likely 5-17 m above modern, which suggests the EAIS is less sensitive to radiative forcing than previously inferred from the geologic record.

  17. Application of mass spectrometry in the characterization of chemicals in coal-derived liquids.

    Science.gov (United States)

    Liu, Fang-Jing; Fan, Maohong; Wei, Xian-Yong; Zong, Zhi-Min

    2016-04-13

    Coal-derived liquids (CDLs) are primarily generated from pyrolysis, carbonization, gasification, direct liquefaction, low-temperature extraction, thermal dissolution, and mild oxidation. CDLs are important feedstocks for producing value-added chemicals and clean liquid fuels as well as high performance carbon materials. Accordingly, the compositional characterization of chemicals in CDLs at the molecular level with advanced analytical techniques is significant for the efficient utilization of CDLs. Although reviews on advancements have been rarely reported, great progress has been achieved in this area by using gas chromatography/mass spectrometry (GC/MS), two-dimensional GC-time of flight mass spectrometry (GC × GC-TOFMS), and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). This review focuses on characterizing hydrocarbon, oxygen-containing, nitrogen-containing, sulfur-containing, and halogen-containing chemicals in various CDLs with these three mass spectrometry techniques. Small molecular (< 500 u), volatile and semi-volatile, and less polar chemicals in CDLs have been identified with GC/MS and GC × GC-TOFMS. By equipped with two-dimensional GC, GC × GC-TOFMS can achieve a clearly chromatographic separation of complex chemicals in CDLs without prior fractionation, and thus can overcome the disadvantages of co-elution and serious peak overlap in GC/MS analysis, providing much more compositional information. With ultrahigh resolving power and mass accuracy, FT-ICR MS reveals a huge number of compositionally distinct compounds assigned to various chemical classes in CDLs. It shows excellent performance in resolving and characterizing higher-molecular, less volatile, and polar chemicals that cannot be detected by GC/MS and GC × GC-TOFMS. The application of GC × GC-TOFMS and FT-ICR MS to chemical characterization of CDLs is not as prevalent as that of petroleum and largely remains to be developed in many respects

  18. Mass and surface energy balance of A.P. Olsen ice cap, NE Greenland, from observations and modeling (1995-2011)

    Science.gov (United States)

    Hillerup Larsen, S.; Citterio, M.; Hock, R. M.; Ahlstrom, A. P.

    2012-12-01

    The A.P. Olsen Ice Cap (74.6 N, 21.5 W) in NE Greenland covers an area of 295 km2, is composed by two domes, of which the western is the largest, and spans an elevation range between 200 and 1450 m a.s.l. In this study we calculate the 2008-2011 annual glacier mass balance based on in situ observations, we model the surface energy balance over the same period, and we reconstruct annual glacier mass balance since 1995. We use GlacioBasis Monitoring Programme observations from a network of 15 ablation stakes and three automatic weather stations (AWS) at 600 m (ca. 100 m higher than the terminus) and at 840 m on the main glacier outlet of the western dome, and at 1430 m in the accumulation area. Accumulation is measured every year in springtime by snow radar surveys calibrated with manual probing and density profiles from snow pits. GlacioBasis data start in 2008, but a longer time series starting in 1995 is available from a weather station at 44 m a.s.l. close to Zackenberg Research Station, ca. 30 km further west. Shorter data series from three more AWS on land at 145 m, 410 m and 1283 m a.s.l. are used to estimate monthly average temperature lapse rates outside of the glacier boundary layer, and to detect the occurrence of temperature inversions. The surface energy mass balance is dominated by the radiative fluxes. We discuss the effect of shadows from the valley sides over parts of the tongue, especially early and late in the melt season when the sun is lower over the horizon, and analyze the modeled mass balance sensitivity to a 1 °C temperature increase. A temperature index model driven by the 1995-2008 time series and calibrated using post-2008 glacier mass balance measurements shows large interannual variability, with 5 of the most negative mass balance years of the entire 1995-2011period occurring between 2003 and 2008. In particular during 2008 the glacier experienced almost no net accumulation over the entire elevation range. This matches 2008 mass balance

  19. MASS TRANSFER EFFECTS ON ACCELERATED VERTICAL PLATE IN A ROTATING FLUID WITH FIRST ORDER CHEMICAL REACTION

    Directory of Open Access Journals (Sweden)

    R. Muthucumaraswamy

    2012-12-01

    Full Text Available The precise analysis of the rotation effects on the unsteady flow of an incompressible fluid past a uniformly accelerated infinite vertical plate with variable temperature and mass diffusion has been undertaken, in the presence of a homogeneous first order chemical reaction. The dimensionless governing equations are solved using the Laplace-transform technique. The plate temperature as well as the concentration near the plate increase linearly with time. The velocity profiles, temperature and concentration are studied for different physical parameters, like the chemical reaction parameter, thermal Grashof number, mass Grashof number, Schmidt number, Prandtl number and time. It is observed that the velocity increases with increasing values of thermal Grashof number or mass Grashof number. It is also observed that the velocity increases with decreasing rotation parameter Ω.

  20. PGC-1α is important for maintaining the balance of muscle mass and myofiber types in unloaded muscle atrophy

    Science.gov (United States)

    Chen, Xiaoping; He, Jian; Wang, Fei; Zhang, Peng; Liu, Hongju; Li, Wenjiong

    2016-07-01

    PGC-1α, a transcriptional co-activator, has been shown mainly to determine the development of oxidative myofibers in skeletal muscle. However, whether PGC-1α functions to regulate the unloaded muscle atrophy and composition of myofiber types keeps unclear. MCK-PGC-1α overexpression transgenic mice (TG) and its wild type littermates (WT) were subjected to hindlimb unloading (HU) and induced unloaded muscle atrophy. After 14 days of HU, the mass of gastrocnemius, soleus, and plantaris muscles in WT mice decreased 17.9%, 28.2%, and 14.8%, respectively (Preal-time PCR and Western blot analysis confirmed that PGC-1α overexpression mice markedly rescued the muscle atrophy and myofiber switching from oxidative to glycolytic associated with a decrease in pSmad3 level after 14 days of HU. Importantly, overexpression of PGC-1α in C2C12 myoblasts protected PGC-1α-transfected myotubes from atrophy in vitro and the effect could be partially blocked by inducing pSmad3 with constitutively activated Smad3(C.A. smad3) transfection. Therefore, this study demonstrated a novel role and mechanism for PGC-1α in maintaining the balance of muscle mass and myofiber type MHCs in unloaded muscle atrophy via suppressing Smad3 activation. This report may prompt a hopeful therapeutic strategy for maintaining muscle mass and fiber type composition in disused muscle atrophies such as space weightlessness- or immobilization-induced muscle atrophy. Acknowledgments This work was supported by the Natural Sciences Foundation of China (31171144, 81272177 and 31171148), the State Key Laboratory Grant of Space Medicine Fundamentals and Application (SMFA13A01), and the National Key Laboratory Grant of Human Factors Engineering (SYFD140051801).

  1. Chemical defense balanced by sequestration and de novo biosynthesis in a lepidopteran specialist.

    Directory of Open Access Journals (Sweden)

    Joel Fürstenberg-Hägg

    Full Text Available The evolution of sequestration (uptake and accumulation relative to de novo biosynthesis of chemical defense compounds is poorly understood, as is the interplay between these two strategies. The Burnet moth Zygaena filipendulae (Lepidoptera and its food-plant Lotus corniculatus (Fabaceae poses an exemplary case study of these questions, as Z. filipendulae belongs to the only insect family known to both de novo biosynthesize and sequester the same defense compounds directly from its food-plant. Z. filipendulae and L. corniculatus both contain the two cyanogenic glucosides linamarin and lotaustralin, which are defense compounds that can be hydrolyzed to liberate toxic hydrogen cyanide. The overall amounts and ratios of linamarin and lotaustralin in Z. filipendulae are tightly regulated, and only to a low extent reflect the ratio in the ingested food-plant. We demonstrate that Z. filipendulae adjusts the de novo biosynthesis of CNglcs by regulation at both the transcriptional and protein level depending on food plant composition. Ultimately this ensures that the larva saves energy and nitrogen while maintaining an effective defense system to fend off predators. By using in situ PCR and immunolocalization, the biosynthetic pathway was resolved to the larval fat body and integument, which infers rapid replenishment of defense compounds following an encounter with a predator. Our study supports the hypothesis that de novo biosynthesis of CNglcs in Z. filipendulae preceded the ability to sequester, and facilitated a food-plant switch to cyanogenic plants, after which sequestration could evolve. Preservation of de novo biosynthesis allows fine-tuning of the amount and composition of CNglcs in Z. filipendulae.

  2. Influence of secondary settling tank performance on suspended solids mass balance in activated sludge systems.

    Science.gov (United States)

    Patziger, M; Kainz, H; Hunze, M; Józsa, J

    2012-05-01

    Secondary settling is the final step of the activated sludge-based biological waste water treatment. Secondary settling tanks (SSTs) are therefore an essential unit of producing a clear effluent. A further important function of SSTs is the sufficient thickening to achieve highly concentrated return sludge and biomass within the biological reactor. In addition, the storage of activated sludge is also needed in case of peak flow events (Ekama et al., 1997). Due to the importance of a high SST performance the problem has long been investigated (Larsen, 1977; Krebs, 1991; Takács et al., 1991; Ekama et al., 1997; Freimann, 1999; Patziger et al., 2005; Bürger et al., 2011), however, a lot of questions are still to solve regarding e.g. the geometrical features (inflow, outflow) and operations (return sludge control, scraper mechanism, allowable maximum values of surface overflow rates). In our study we focused on SSTs under dynamic load considering both the overall unsteady behaviour and the features around the peaks, investigating the effect of various sludge return strategies as well as the inlet geometry on SST performance. The main research tool was a FLUENT-based novel mass transport model consisting of two modules, a 2D axisymmetric SST model and a mixed reactor model of the biological reactor (BR). The model was calibrated and verified against detailed measurements of flow and concentration patterns, sludge settling, accompanied with continuous on-line measurement of in- and outflow as well as returned flow rates of total suspended solids (TSS) and water. As to the inlet arrangement a reasonable modification of the geometry could result in the suppression of the large scale flow structures of the sludge-water interface thus providing a significant improvement in the SST performance. Furthermore, a critical value of the overflow rate (q(crit)) was found at which a pronounced large scale circulation pattern develops in the vertical plane, the density current in

  3. Snowpack and snowmelt modeling of a subarctic catchment in northern Quebec, Canada, using an energy and mass balance approach

    Science.gov (United States)

    Oreiller, M.; Rousseau, A. N.; Minville, M.

    2012-12-01

    There is a growing interest in modeling snowpack evolution and spring runoff in northern Quebec, Canada, where there are several large-scale hydropower complexes. This region (49th to 55th degree north), characterized by boreal forest, lakes and wetlands, is highly remote and snowpack observations are very sparse. The objective of this study is to improve the snow module of HYDROTEL, a distributed continuous hydrological model currently used to predict inflows to large hydropower reservoirs of the region, with the help of continuous in-situ measurements of snow water equivalent. Up to now HYDROTEL has relied on a mixed degree-day/energy balance method to simulate accumulation and depletion of the snow cover. This approach has the advantage of requiring a small number of input data, but under changing climate conditions such as those recently experienced unusually high temperature in late winter or rain-on-snow events it has a tendency to generate unreliable results. We thus implemented a completely physically-based snow module, CROCUS, and try to determine whether HYDROTEL could benefit from an energy and mass balance approach. CROCUS, originally developed for snowpack simulations in the French Alps, has been adapted to the specific environmental characteristics of the boreal region. The simulation can now be validated with snow water equivalent collected by a GMON sensor, which evaluates absorption of the natural ground gamma radiation by the snowpack. The number of input data required by CROCUS is more important (seven meteorological variables on an hourly basis instead of two on a daily basis for the current version of HYDROTEL's snow module) which makes it more complex to use and at this points too complex to be implemented directly as a subroutine in HYDROTEL. However, this study shows that HYDROTEL is much more effective at predicting winter and spring runoff when using CROCUS as the snow module.

  4. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy).

    Science.gov (United States)

    Biganzoli, L; Falbo, A; Forte, F; Grosso, M; Rigamonti, L

    2015-08-15

    Waste electrical and electronic equipment (WEEE) is one of the fastest growing waste streams in Europe, whose content of hazardous substances as well as of valuable materials makes the study of the different management options particularly interesting. The present study investigates the WEEE management system in Lombardia Region (Italy) in the year 2011 by applying the life cycle assessment (LCA) methodology. An extensive collection of primary data was carried out to describe the main outputs and the energy consumptions of the treatment plants. Afterwards, the benefits and burdens associated with the treatment and recovery of each of the five categories in which WEEE is classified according to the Italian legislation (heaters and refrigerators - R1, large household appliances - R2, TV and monitors - R3, small household appliances - R4 and lighting equipment - R5) were evaluated. The mass balance of the treatment and recovery system of each of the five WEEE categories showed that steel and glass are the predominant streams of materials arising from the treatment; a non-negligible amount of plastic is also recovered, together with small amounts of precious metals. The LCA of the regional WEEE management system showed that the benefits associated with materials and energy recovery balance the burdens of the treatment processes, with the sole exception of two impact categories (human toxicity-cancer effects and freshwater ecotoxicity). The WEEE categories whose treatment and recovery resulted more beneficial for the environment and the human health are R3 and R5. The contribution analysis showed that overall the main benefits are associated with the recovery of metals, as well as of plastic and glass. Some suggestions for improving the performance of the system are given, as well as an indication for a more-in-depth analysis for the toxicity categories and a proposal for a new characterisation method for WEEE.

  5. The oceanic mass balance of copper and zinc isotopes, investigated by analysis of their inputs, and outputs to ferromanganese oxide sediments

    Science.gov (United States)

    Little, S. H.; Vance, D.; Walker-Brown, C.; Landing, W. M.

    2014-01-01

    The oceanic biogeochemical cycles of the transition metals have been eliciting considerable attention for some time. Many of them have isotope systems that are fractionated by key biological and chemical processes so that significant information about such processes may be gleaned from them. However, for many of these nascent isotopic systems we currently know too little of their modern oceanic mass balance, making the application of such systems to the past speculative, at best. Here we investigate the biogeochemical cycling of copper (Cu) and zinc (Zn) isotopes in the ocean. We present estimates for the isotopic composition of Cu and Zn inputs to the oceans based on new data presented here and published data. The bulk isotopic composition of dissolved Cu and Zn in the oceans (δ65Cu ∼+0.9‰, δ66Zn ∼+0.5‰) is in both cases heavier than their respective inputs (at around δ65Cu = +0.6‰ and δ66Zn = +0.3‰, respectively), implying a marine process that fractionates them and a resulting isotopically light sedimentary output. For the better-known molybdenum isotope system this is achieved by sorption to Fe-Mn oxides, and this light isotopic composition is recorded in Fe-Mn crusts. Hence, we present isotopic data for Cu and Zn in three Fe-Mn crusts from the major ocean basins, which yield δ65Cu = 0.44 ± 0.23‰ (mean and 2SD) and δ66Zn = 1.04 ± 0.21‰. Thus for Cu isotopes output to particulate Fe-Mn oxides can explain the heavy isotopic composition of the oceans, while for Zn it cannot. The heavy Zn in Fe-Mn crusts (and in all other authigenic marine sediments measured so far) implies that a missing light sink is still to be located. These observations are some of the first to place constraints on the modern oceanic mass balance of Cu and Zn isotopes.

  6. Implications of elevated CO2 on pelagic carbon fluxes in an Arctic mesocosm study - an elemental mass balance approach

    Science.gov (United States)

    Czerny, J.; Schulz, K. G.; Boxhammer, T.; Bellerby, R. G. J.; Büdenbender, J.; Engel, A.; Krug, S. A.; Ludwig, A.; Nachtigall, K.; Nondal, G.; Niehoff, B.; Silyakova, A.; Riebesell, U.

    2013-05-01

    Recent studies on the impacts of ocean acidification on pelagic communities have identified changes in carbon to nutrient dynamics with related shifts in elemental stoichiometry. In principle, mesocosm experiments provide the opportunity of determining temporal dynamics of all relevant carbon and nutrient pools and, thus, calculating elemental budgets. In practice, attempts to budget mesocosm enclosures are often hampered by uncertainties in some of the measured pools and fluxes, in particular due to uncertainties in constraining air-sea gas exchange, particle sinking, and wall growth. In an Arctic mesocosm study on ocean acidification applying KOSMOS (Kiel Off-Shore Mesocosms for future Ocean Simulation), all relevant element pools and fluxes of carbon, nitrogen and phosphorus were measured, using an improved experimental design intended to narrow down the mentioned uncertainties. Water-column concentrations of particulate and dissolved organic and inorganic matter were determined daily. New approaches for quantitative estimates of material sinking to the bottom of the mesocosms and gas exchange in 48 h temporal resolution as well as estimates of wall growth were developed to close the gaps in element budgets. However, losses elements from the budgets into a sum of insufficiently determined pools were detected, and are principally unavoidable in mesocosm investigation. The comparison of variability patterns of all single measured datasets revealed analytic precision to be the main issue in determination of budgets. Uncertainties in dissolved organic carbon (DOC), nitrogen (DON) and particulate organic phosphorus (POP) were much higher than the summed error in determination of the same elements in all other pools. With estimates provided for all other major elemental pools, mass balance calculations could be used to infer the temporal development of DOC, DON and POP pools. Future elevated pCO2 was found to enhance net autotrophic community carbon uptake in two of

  7. Implications of elevated CO2 on pelagic carbon fluxes in an Arctic mesocosm study – an elemental mass balance approach

    Directory of Open Access Journals (Sweden)

    J. Czerny

    2013-05-01

    Full Text Available Recent studies on the impacts of ocean acidification on pelagic communities have identified changes in carbon to nutrient dynamics with related shifts in elemental stoichiometry. In principle, mesocosm experiments provide the opportunity of determining temporal dynamics of all relevant carbon and nutrient pools and, thus, calculating elemental budgets. In practice, attempts to budget mesocosm enclosures are often hampered by uncertainties in some of the measured pools and fluxes, in particular due to uncertainties in constraining air–sea gas exchange, particle sinking, and wall growth. In an Arctic mesocosm study on ocean acidification applying KOSMOS (Kiel Off-Shore Mesocosms for future Ocean Simulation, all relevant element pools and fluxes of carbon, nitrogen and phosphorus were measured, using an improved experimental design intended to narrow down the mentioned uncertainties. Water-column concentrations of particulate and dissolved organic and inorganic matter were determined daily. New approaches for quantitative estimates of material sinking to the bottom of the mesocosms and gas exchange in 48 h temporal resolution as well as estimates of wall growth were developed to close the gaps in element budgets. However, losses elements from the budgets into a sum of insufficiently determined pools were detected, and are principally unavoidable in mesocosm investigation. The comparison of variability patterns of all single measured datasets revealed analytic precision to be the main issue in determination of budgets. Uncertainties in dissolved organic carbon (DOC, nitrogen (DON and particulate organic phosphorus (POP were much higher than the summed error in determination of the same elements in all other pools. With estimates provided for all other major elemental pools, mass balance calculations could be used to infer the temporal development of DOC, DON and POP pools. Future elevated pCO2 was found to enhance net autotrophic community carbon

  8. Functioning of an ancient sediment routing system; Mass balance and sediment budget of the Eocene Escanilla Formation, Spanish central Pyrenees

    Science.gov (United States)

    Michael, N. A.; Whittaker, A. C.; Allen, P. A.

    2013-12-01

    One of the key challenges that sedimentologists and stratigraphers face is trying to understand what controls grain-size and sedimentary facies in basins, with the ultimate goal of stratigraphic prediction. It has been shown that the crucial parameters that control grain-size trends are the sediment discharge into the basin, the characteristic grain size mix of the supply, and the spatial distribution of subsidence. In this paper we present an outcrop case study of the Escanilla Formation, where all these parameters have been constrained, and explore how knowledge of these parameters translates into stratigraphic architecture. The mid-upper Eocene Escanilla Formation is part of a 200 km-long sediment routing system that was sourced primarily from the Axial Zone of the South-Central Pyrenees and deposited in a series of wedge-top basins (La Pobla, Tremp-Graus, Ainsa and Jaca basins). The Escanilla system consists of a wide variety of depositional environments and is one of the rare examples where all components of the ancient routing system are readily available for study: from proximal alluvial fanglomerates in the Sis and Gurb paleovalleys, braided river deposits in the Tremp-Graus and eastern Ainsa basins, deltaic, shallow marine and continental slope deposits in the western Ainsa Basin, and deep marine turbidite deposits in the Jaca Basin. This makes it a world class siliciclastic analogue for hydrocarbon exploration. In this study we examine how the mass balance and sediment budget influenced sedimentary trends within this paleo-sediment routing system. The entire sediment routing system has been delimited using new provenance data and a correlation from source to sink is proposed, subdividing the 7.7 Myr duration of deposition into three time intervals of roughly equal duration. Within these time intervals, the sedimentary budgets of the Escanilla system have been calculated and a mass balance framework established, enabling the quantitative assessment of how

  9. Ice flow dynamics and mass balance of Vatnajökull outlet glaciers observed by X-band SAR Data

    Science.gov (United States)

    Nagler, T.; Rott, H.; Magnússon, E.; Floricioiu, D.; Mueller, F.; Scharrer, K.

    2012-04-01

    Several outlet glaciers of the major ice caps in Iceland are affected by sub-glacial outburst floods, so-called jökulhlaups. Sources of these outbreaks are water accumulations beneath the glacier due to geothermal or volcanic activity. One component of the project NorthHydrology, carried out within the ESA STSE (Support to Science Element) programme, addresses techniques and applications of satellite data for studying drainage mechanisms and water outbreaks of sub-glacial lakes in Iceland. Such events are usually related to surface deformation and changes in ice velocities, sometimes occurring already well ahead of the peak of the flood wave. High resolution repeat pass SAR data are able to deliver spatially detailed information on surface motion and displacement, which are highly relevant for advancing the understanding of glacier hydraulics and jökulhlaup processes. A template matching technique is applied to data stacks of TerraSAR-X and Cosmo-SkyMed amplitude images acquired between summer 2008 to summer 2010 in order to study the ice dynamics and mass balance of outlet glaciers of Vatnajökull in Iceland. This technique requires distinct and stable surface features, as usually available on ice surfaces of glaciers. Main outlet glaciers, investigated in the project, are Breidamerkurjökull and Skeiderarjökull, with the fronts terminating close to the coast. The lower terminus of these glaciers exhibits significant melting during summer, and sometimes even during winter. At these glaciers in-situ data on ice velocity and surface elevation changes have been recorded at in situ GPS stations, operated by University of Iceland. The ice motion field was derived using ascending and descending repeat pass SAR images. In order to retrieve the 3D ice motion vector, effects of surface melt are taken into account by modelling the ablation. Combining maps of displacement shifts from ascending and descending passes and compensating for surface lowering due to melt, maps

  10. Evaluation of Primary Production in the Lower Amazon River Based on a Dissolved Oxygen Stable Isotopic Mass Balance

    Energy Technology Data Exchange (ETDEWEB)

    Gagne-Maynard, William C.; Ward, Nicholas D.; Keil, Richard G.; Sawakuchi, Henrique O.; Da Cunha, Alan C.; Neu, Vania; Brito, Daimio C.; Da Silva Less, Diani F.; Diniz, Joel E. M.; De Matos Valerio, Aline; Kampel, Milton; Krusche, Alex V.; Richey, Jeffrey E.

    2017-02-07

    The Amazon River outgasses nearly an equivalent amount of CO2 as the rainforest sequesters on an annual basis due to microbial decomposition of terrigenous and aquatic organic matter. Most research performed in the Amazon has been focused on unraveling the mechanisms driving CO2 production since the recognition of a persistent state of CO2 supersaturation. However, although the river system is clearly net heterotrophic, the interplay between primary production and respiration is an essential aspect to understanding the overall metabolism of the ecosystem and potential transfer of energy up trophic levels. For example, an efficient ecosystem is capable of both decomposing high amounts of organic matter at lower trophic levels, driving CO2 emissions, and accumulating energy/biomass in higher trophic levels, stimulating fisheries production. Early studies found minimal evidence for primary production in the Amazon River mainstem and it has since been assumed that photosynthesis is strongly limited by low light penetration attributed to the high sediment load. Here, we test this assumption by measuring the stable isotopic composition of O218O-O2) and O2 saturation levels in the lower Amazon River from Óbidos to the river mouth and its major tributaries, the Xingu and Tapajós rivers, during high and low water periods. An oxygen mass balance model was developed to estimate the input of photosynthetic oxygen in the discrete reach from Óbidos to Almeirim, midway to the river mouth. Based on the oxygen mass balance we estimate that primary production occurred at a rate of 0.39 ± 0.24 g O m3 d-1 at high water and 1.02 ± 0.55 g O m3 d-1 at low water. This translates to 41 ± 24% of the rate of O2 drawdown via respiration during high water and 67 ± 33% during low water. These primary production rates are 2-7 times higher than

  11. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  12. Antarctic ice-mass balance 2002 to 2011: regional re-analysis of GRACE satellite gravimetry measurements with improved estimate of glacial-isostatic adjustment

    Directory of Open Access Journals (Sweden)

    I. Sasgen

    2012-09-01

    Full Text Available We present regional-scale mass balances for 25 drainage basins of the Antarctic Ice Sheet (AIS from satellite observations of the Gravity and Climate Experiment (GRACE for the years 2002–2011. Satellite gravimetry estimates of the AIS mass balance are strongly influenced by mass movement in the Earth interior caused by ice advance and retreat during the last glacial cycle. Here, we develop an improved glacial-isostatic adjustment (GIA estimate for Antarctica using newly available GPS uplift rates, allowing us to more accurately separate GIA-induced trends in the GRACE gravity fields from those caused by current imbalances of the AIS. Our revised GIA estimate is considerably lower than previous predictions, yielding an (upper estimate of apparent mass change of 48 ± 18 Gt yr−1. Therefore, our AIS mass balance of −103 ± 23 Gt yr−1 is considerably less negative than previous GRACE estimates. The Northern Antarctic Peninsula and the Amundsen Sea Sector exhibit the largest mass loss (−25 ± 6 Gt yr−1 and −126 ± 11 Gt yr−1, respectively. In contrast, East Antarctica exhibits a slightly positive mass balance (19 ± 16 Gt yr−1, which is, however, mostly the consequence of compensating mass anomalies in Dronning Maud and Enderby Land (positive and Wilkes and George V Land (negative due to interannual accumulation variations. In total, 7% of the area constitute more than half of the AIS imbalance (53%, contributing −151 ± 9 Gt yr−1 to global mean sea-level change. Most of this imbalance is caused by long-term ice-dynamic speed up expected to prevail in the future.

  13. Simulating the climatic mass balance of Svalbard glaciers from 2003 to 2013 with a high-resolution coupled atmosphere-glacier model

    Directory of Open Access Journals (Sweden)

    K. S. Aas

    2015-10-01

    Full Text Available In this study we simulate the climatic mass balance of Svalbard glaciers with a coupled atmosphere-glacier model with 3 km grid spacing, from September 2003 to September 2013. We find a mean specific net mass balance of −167 mm w.e. yr−1, corresponding to a mean annual mass loss of about 5.7 Gt, with large interannual variability. Our results are compared with a comprehensive set of mass balance, meteorological and satellite measurements. Model temperature biases of 0.17 and −1.9 °C are found at two glacier automatic weather station sites. Simulated climatic mass balance is mostly within about 0.1 m w.e. yr−1 of stake measurements, and simulated winter accumulation at the Austfonna ice cap shows mean absolute errors of 0.05 and 0.06 m w.e. yr−1 when compared to radar-derived values for the selected years 2004 and 2006. Comparison of surface height changes from 2003 to 2008 from model, and satellite altimetry reveals good agreement in both mean values and regional differences. The largest deviations from observations are found for winter accumulation at Hansbreen (up to around 1 m w.e. yr−1, a site where sub-grid topography and wind redistribution of snow are important factors. Comparison with simulations using a 9 km grid spacing reveal considerable differences on regional and local scales. In addition, the 3 km grid spacing allows for a much more detailed comparison with observations than what is possible with a 9 km grid spacing. Further decreasing the grid spacing to 1 km appears to be less significant, although in general precipitation amounts increase with resolution. Altogether, the model compares well with observations and offers possibilities for studying glacier climatic mass balance on Svalbard both historically as well as based on climate projections.

  14. Humidity independent mass spectrometry for gas phase chemical analysis via ambient proton transfer reaction

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Hongying; Huang, Guangming, E-mail: gmhuang@ustc.edu.cn

    2015-03-31

    Graphical abstract: Direct and humidity independent mass spectrometry analysis of gas phase chemicals could be achieved via ambient proton transfer ionization, ion intensity was found to be stable with humidity ranged from ∼10% to ∼100%. - Highlights: • A humidity independent mass spectrometric method for gas phase samples analysis. • A universal and good sensitivity method. • The method can real time identify plant released raw chemicals. - Abstract: In this work, a humidity independent mass spectrometric method was developed for rapid analysis of gas phase chemicals. This method is based upon ambient proton transfer reaction between gas phase chemicals and charged water droplets, in a reaction chamber with nearly saturate humidity under atmospheric pressure. The humidity independent nature enables direct and rapid analysis of raw gas phase samples, avoiding time- and sample-consuming sample pretreatments in conventional mass spectrometry methods to control sample humidity. Acetone, benzene, toluene, ethylbenzene and meta-xylene were used to evaluate the analytical performance of present method. The limits of detection for benzene, toluene, ethylbenzene and meta-xylene are in the range of ∼0.1 to ∼0.3 ppbV; that of benzene is well below the present European Union permissible exposure limit for benzene vapor (5 μg m{sup −3}, ∼1.44 ppbV), with linear ranges of approximately two orders of magnitude. The majority of the homemade device contains a stainless steel tube as reaction chamber and an ultrasonic humidifier as the source of charged water droplets, which makes this cheap device easy to assemble and facile to operate. In addition, potential application of this method was illustrated by the real time identification of raw gas phase chemicals released from plants at different physiological stages.

  15. Estimating the Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    NARCIS (Netherlands)

    Fettweis, X.; Franco, B.; Tedesco, M.; van Angelen, J.H.; Lenaerts, J.T.M.; van den Broeke, M.R.; Gallée, H.

    2013-01-01

    To estimate the sea level rise (SLR) originating from changes in surface mass balance (SMB) of the Greenland ice sheet (GrIS), we present 21st century climate projections obtained with the regional climate model MAR (Mod`ele Atmosph´erique R´egional), forced by output of three CMIP5 (Coupled Model I

  16. Modeling Glacier Mass Balance and Runoff in the Koxkar River Basin on the South Slope of the Tianshan Mountains, China, from 1959 to 2009

    Directory of Open Access Journals (Sweden)

    Min Xu

    2017-02-01

    Full Text Available Water resources provided by alpine glaciers are an important pillar for people in the arid regions of west China. In this study, the Hydrologiska Byrans Vattenavdelning (HBV light model was applied to simulate glacier mass balance (GMB and runoff in the Koxkar River Basin (KRB on the south slope of Mount Tumur, in the western Tianshan Mountains. Daily temperature and precipitation were calculated by multiple linear regressions and gradient-inverse distance weighting, respectively, based on in-situ observed data by automatic weather stations (AWSs in the Koxkar River Basin (KRB; 2007–2009 and four meteorological stations neighboring the basin (1959–2009. Observed daily air temperature and precipitation were input into HBV model. The runoff data in 2007/2008 and 2008/2009 were used to calibrate and validate the model in 2009/2010 and 2010/2011. Generally, the model simulated runoff very well. The annual glacier mass balance and runoff were calculated by the HBV model and were driven by interpolated meteorological data between 1959 and 2009. The calculated glacier mass balances were reasonable, and were compared with nearby glaciers. The results indicate the decreasing trend of mass balance in the Koxkar Glacier, with an average value of ablation of −370.4 mm·a−1 between 1959 and 2009. The annual runoff showed an increasing trend (5.51 mm·a−1. Further analysis showed that the runoff is more sensitive to temperature than precipitation in KRB.

  17. Impact of model resolution on simulated wind, drifting snow and surface mass balance in Terre Adélie, East Antarctica

    NARCIS (Netherlands)

    Lenaerts, J.T.M.; van den Broeke, M.R.; Scarchilli, C.; Agosta, C.

    2012-01-01

    This paper presents the impact of model resolution on the simulated wind speed, drifting snow climate and surface mass balance (SMB) of Terre Ad´elie and its surroundings, East Antarctica. We compare regional climate model simulations at 27 and 5.5 km resolution for the year 2009. The wind speed max

  18. The impact of a seasonally ice free Arctic Ocean on the temperature, precipitation and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2012-01-01

    Full Text Available The observed decline in summer sea ice extent since the 1970s is predicted to continue until the Arctic Ocean is seasonally ice free during the 21st Century. This will lead to a much perturbed Arctic climate with large changes in ocean surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers and is expected to experience rapid warming over the 21st Century. The total sea level rise if all the land ice on Svalbard were to melt completely is 0.02 m.

    The purpose of this study is to quantify the impact of climate change on Svalbard's surface mass balance (SMB and to determine, in particular, what proportion of the projected changes in precipitation and SMB are a result of changes to the Arctic sea ice cover. To investigate this a regional climate model was forced with monthly mean climatologies of sea surface temperature (SST and sea ice concentration for the periods 1961–1990 and 2061–2090 under two emission scenarios. In a novel forcing experiment, 20th Century SSTs and 21st Century sea ice were used to force one simulation to investigate the role of sea ice forcing. This experiment results in a 3.5 m water equivalent increase in Svalbard's SMB compared to the present day. This is because over 50 % of the projected increase in winter precipitation over Svalbard under the A1B emissions scenario is due to an increase in lower atmosphere moisture content associated with evaporation from the ice free ocean. These results indicate that increases in precipitation due to sea ice decline may act to moderate mass loss from Svalbard's glaciers due to future Arctic warming.

  19. Contemporary (1960-2012) Evolution of the Climate and Surface Mass Balance of the Greenland Ice Sheet

    Science.gov (United States)

    van Angelen, J. H.; van den Broeke, M. R.; Wouters, B.; Lenaerts, J. T. M.

    2014-09-01

    We assess the contemporary (1960-2012) surface mass balance (SMB) of the Greenland ice sheet (GrIS), its individual components and trends. We use output of the high-resolution (11 km) regional atmospheric climate model (RACMO2), evaluated with automatic weather stations and GRACE data. A persistent negative North Atlantic oscillation index over the last 6 years resulted in the summertime advection of relatively warm continental air toward the GrIS. Added to the enhanced radiative forcing by increased CO2 levels, this has resulted in an increase in near-surface temperature of more than 2 K during 2007-2012 compared to 1960-1990. The associated decrease in albedo led to an extra absorption of shortwave radiation of ˜6 Wm-2 (11 %) in the summer months, which is the main driver of enhanced surface melting and runoff in recent years. From 1990 onward, we see a steady increase in meltwater runoff and an associated decrease in the SMB, accelerating after 2005, with the record low SMB year in 2010. Despite the fact that the GrIS was subject to the highest surface melt rates in 2012, relatively high accumulation rates prevented 2012 to set a record low SMB. In 2012, melt occurred relatively high on the ice sheet where melt water refreezes in the porous firn layer. Up to 2005, increased runoff was partly offset by increased accumulation rates. Since then, accumulation rates have decreased, resulting in low SMB values. Other causes of decreased SMB are the loss of firn pore space and decreasing refreezing rates in the higher ablation area. The GrIS has lost in total 1,800 ± 300 Gt of mass from surface processes alone since 1990 and about half of that in the last 6 years.

  20. Intermediate Mass Dilepton Production in a Chemically Equilibrating Quark-Gluon Matter

    Institute of Scientific and Technical Information of China (English)

    HE Ze-Jun; ZHOU Wen-Jie; ZHANG Jia-Ju; LIU Bo

    2001-01-01

    Dilepton production during the chemical equilibration of quark-gluon matter with a finite baryon density has been studied. We find that due to the slowing down of the cooling rate and the high initial temperature of the quark-gluon matter produced at RHIC energies, the quark phase contribution to dileptons with intermediate masses is significantly heightened and is much larger than that calculated by the evolution of the thermodynamic equilibrium system. The latter has shown an enhancement of intermediate mass dileptons from the quark phase. Therefore, such an enhancement of dileptons should be a signature for quark-gluon matter formation.

  1. The Alteration History of Clovis Class Rocks in Gusev Crater as Determined by Ti-Normalzed Mass Balance Analysis

    Science.gov (United States)

    Sutter, Brat; Ming, Douglas W.; Niles, P. B.; Golden, D. C.

    2012-01-01

    The West Spur Clovis class rocks in Gusev Crater are some of the most altered rocks in Gusev Crater and likely contain a mixed sulfate and phyllosilicate mineralogy [1,2]. The high S and Cl content of the Clovis rocks suggests that acidic vapors or fluids of H2SO4 and HCl reacted with the Clovis parent rock to form Ca, Mg,- sulfates, iron-oxyhydroxides and secondary aluminosilicates (approx.60 wt.%) of a poorly crystalline nature (e.g., allophane) [1]. Up to 14-17 wt.% phyllosilicates (e.g., kaolinite, chlorite, serpentine) are hypothesized to exist in the Clovis materials suggesting that Clovis parent materials while possibly exposed to acidic pHs were likely neutralized by basalt dissolution which resulted in mildly acidic pHs (4-6) [1, 2]. This work proposes that subsequent to the alteration of the Clovis rocks, alteration fluids became concentrated in ions resulting in the addition of silicate and salts. The objective of this work is to utilize Ti-normalized mass balance analysis to evaluate (1) mineral gains and losses and (2) elemental gains and losses in the Clovis rocks. Results of this work will be used evaluate the nature of geochemical conditions that affect phyllosilicate and sulfate formation at Gusev crater.

  2. A 90-day oral (dietary) toxicity and mass balance study of corn starch fiber in Sprague Dawley rats.

    Science.gov (United States)

    Crincoli, Christine M; Nikiforov, Andrey I; Rihner, Marisa O; Lambert, Elizabeth A; Greeley, Melanie A; Godsey, Justin; Eapen, Alex K; van de Ligt, Jennifer L G

    2016-11-01

    The potential toxicity of corn starch fiber was assessed and compared to polydextrose, a commonly used bulking agent with a long history of safe use in the food supply. Groups of male and female Crl:CD(SD) rats were fed 0 (control), 1,000, 3,000, or 10,000 mg/kg-bw/day corn starch fiber in the diet for 90 days. The polydextrose reference article was offered on a comparable regimen at 10,000 mg/kg-bw/day. Following a single gavage dose of [(14)C]-corn starch fiber on study day 13 or 90, the mass balance of the test article was assessed by analysis of excreta samples collected from 0 to 168 h post-dose. There were no toxicologically or biologically relevant findings in any of the test article-treated groups. The few minor differences observed between the corn starch fiber and polydextrose exposed groups were considered to be due to normal biological variation. Following [(14)C]-corn starch fiber dosing, nearly complete excretion of the administered dose occurred over 168 h post-dosing, with the majority excreted in the feces. The dietary no-observed-adverse-effect level of corn starch fiber after 90 days was 10,000 mg/kg-bw/day. Similar toxicity profiles for corn starch fiber and polydextrose were observed due to the structural and compositional similarities of these materials.

  3. A daily, 1 km resolution data set of downscaled Greenland ice sheet surface mass balance (1958-2015)

    Science.gov (United States)

    Noël, Brice; van de Berg, Willem Jan; Machguth, Horst; Lhermitte, Stef; Howat, Ian; Fettweis, Xavier; van den Broeke, Michiel R.

    2016-10-01

    This study presents a data set of daily, 1 km resolution Greenland ice sheet (GrIS) surface mass balance (SMB) covering the period 1958-2015. Applying corrections for elevation, bare ice albedo and accumulation bias, the high-resolution product is statistically downscaled from the native daily output of the polar regional climate model RACMO2.3 at 11 km. The data set includes all individual SMB components projected to a down-sampled version of the Greenland Ice Mapping Project (GIMP) digital elevation model and ice mask. The 1 km mask better resolves narrow ablation zones, valley glaciers, fjords and disconnected ice caps. Relative to the 11 km product, the more detailed representation of isolated glaciated areas leads to increased precipitation over the southeastern GrIS. In addition, the downscaled product shows a significant increase in runoff owing to better resolved low-lying marginal glaciated regions. The combined corrections for elevation and bare ice albedo markedly improve model agreement with a newly compiled data set of ablation measurements.

  4. Present-day and future Antarctic ice sheet climate and surface mass balance in the Community Earth System Model

    Science.gov (United States)

    Lenaerts, Jan T. M.; Vizcaino, Miren; Fyke, Jeremy; van Kampenhout, Leo; van den Broeke, Michiel R.

    2016-09-01

    We present climate and surface mass balance (SMB) of the Antarctic ice sheet (AIS) as simulated by the global, coupled ocean-atmosphere-land Community Earth System Model (CESM) with a horizontal resolution of {˜ }1° in the past, present and future (1850-2100). CESM correctly simulates present-day Antarctic sea ice extent, large-scale atmospheric circulation and near-surface climate, but fails to simulate the recent expansion of Antarctic sea ice. The present-day Antarctic ice sheet SMB equals 2280 ± 131 {Gt year^{-1}}, which concurs with existing independent estimates of AIS SMB. When forced by two CMIP5 climate change scenarios (high mitigation scenario RCP2.6 and high-emission scenario RCP8.5), CESM projects an increase of Antarctic ice sheet SMB of about 70 {Gt year^{-1}} per degree warming. This increase is driven by enhanced snowfall, which is partially counteracted by more surface melt and runoff along the ice sheet's edges. This intensifying hydrological cycle is predominantly driven by atmospheric warming, which increases (1) the moisture-carrying capacity of the atmosphere, (2) oceanic source region evaporation, and (3) summer AIS cloud liquid water content.

  5. Coupling of climate models and ice sheet models by surface mass balance gradients: application to the Greenland Ice Sheet

    Directory of Open Access Journals (Sweden)

    M. M. Helsen

    2012-03-01

    Full Text Available It is notoriously difficult to couple surface mass balance (SMB results from climate models to the changing geometry of an ice sheet model. This problem is traditionally avoided by using only accumulation from a climate model, and parameterizing the meltwater run-off as a function of temperature, which is often related to surface elevation (Hs. In this study, we propose a new strategy to calculate SMB, to allow a direct adjustment of SMB to a change in ice sheet topography and/or a change in climate forcing. This method is based on elevational gradients in the SMB field as computed by a regional climate model. Separate linear relations are derived for ablation and accumulation, using pairs of Hs and SMB within a minimum search radius. The continuously adjusting SMB forcing is consistent with climate model forcing fields, also for initially non-glaciated areas in the peripheral areas of an ice sheet. When applied to an asynchronous coupled ice sheet – climate model setup, this method circumvents traditional temperature lapse rate assumptions. Here we apply it to the Greenland Ice Sheet (GrIS. Experiments using both steady-state forcing and glacial-interglacial forcing result in realistic ice sheet reconstructions.

  6. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    Directory of Open Access Journals (Sweden)

    J. H. van Angelen

    2012-10-01

    Full Text Available We present a sensitivity study of the surface mass balance (SMB of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover, solar zenith angle and black carbon concentration. For the control experiment the overestimation of absorbed shortwave radiation (+6% at the K-transect (west Greenland for the period 2004–2009 is considerably reduced compared to the previous density-dependent albedo scheme (+22%. To simulate realistic snow albedo values, a small concentration of black carbon is needed, which has strongest impact on melt in the accumulation area. A background ice albedo field derived from MODIS imagery improves the agreement between the modeled and observed SMB gradient along the K-transect. The effect of enhanced meltwater retention and refreezing is a decrease of the albedo due to an increase in snow grain size. As a secondary effect of refreezing the snowpack is heated, enhancing melt and further lowering the albedo. Especially in a warmer climate this process is important, since it reduces the refreezing potential of the firn layer that covers the Greenland Ice Sheet.

  7. A Mass Balance Model for Designing Green Roof Systems that Incorporate a Cistern for Re-Use

    Directory of Open Access Journals (Sweden)

    Manoj Chopra

    2012-11-01

    Full Text Available Green roofs, which have been used for several decades in many parts of the world, offer a unique and sustainable approach to stormwater management. Within this paper, evidence is presented on water retention for an irrigated green roof system. The presented green roof design results in a water retention volume on site. A first principle mass balance computer model is introduced to assist with the design of these green roof systems which incorporate a cistern to capture and reuse runoff waters for irrigation of the green roof. The model is used to estimate yearly stormwater retention volume for different cistern storage volumes. Additionally, the Blaney and Criddle equation is evaluated for estimation of monthly evapotranspiration rates for irrigated systems and incorporated into the model. This is done so evapotranspiration rates can be calculated for regions where historical data does not exist, allowing the model to be used anywhere historical weather data are available. This model is developed and discussed within this paper as well as compared to experimental results.

  8. Aquifer Recharge Estimation through Atmospheric Chloride Mass Balance at Las Cañadas Caldera, Tenerife, Canary Islands, Spain

    Directory of Open Access Journals (Sweden)

    Rayco Marrero-Diaz

    2015-05-01

    Full Text Available The atmospheric chloride mass balance (CMB method was used to estimate net aquifer recharge in Las Cañadas Caldera, an endorheic summit aquifer area about 2000 m a.s.l. with negligible surface runoff, which hosts the largest freshwater reserve in Tenerife Island, Canary Islands, Spain. The wet hydrological year 2005–2006 was selected to compare yearly atmospheric chloride bulk deposition and average chloride content in recharge water just above the water table, both deduced from periodical sampling. The potential contribution of chloride to groundwater from endogenous HCl gas may invalidate the CMB method. The chloride-to-bromide molar ratio was an efficient tracer used to select recharge water samples having atmospheric origin of chloride. Yearly net aquifer recharge was 631 mm year−1, i.e., 69% of yearly precipitation. This result is in agreement with potential aquifer recharge estimated through an independent lumped-parameter rainfall-runoff model operated by the Insular Water Council of Tenerife. This paper illustrates basic procedures and routines to use the CMB method for aquifer recharge in active volcanic oceanic islands having sparse-data coverage and groundwater receiving contribution of endogenous halides.

  9. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    Directory of Open Access Journals (Sweden)

    J. H. van Angelen

    2012-04-01

    Full Text Available We present a sensitivity study of the surface mass balance (SMB of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo parameterization. The snow albedo parameterization uses grain size as a prognostic variable and further depends on cloud cover, solar zenith angle and black carbon concentration. For the control experiment the overestimation of absorbed shortwave radiation (+6 % at the K-transect (West Greenland for the period 2004–2009 is considerably reduced compared to the previous density-dependent albedo parameterization (+22 %. To simulate realistic snow albedo values, a small concentration of black carbon is needed. A background ice albedo field derived from MODIS imagery improves the agreement between the modeled and observed SMB gradient along the K-transect. The effect of enhanced retention and refreezing is a decrease of the albedo due to an increase in snow grain size. As a secondary effect of refreezing the snowpack is heated, enhancing melt and further lowering the albedo. Especially in a warmer climate this process is important, since it reduces the refreezing potential of the firn layer covering the Greenland Ice Sheet.

  10. Anthropogenic impact on Antarctic surface mass balance, currently masked by natural variability, to emerge by mid-century

    Science.gov (United States)

    Previdi, Michael; Polvani, Lorenzo M.

    2016-09-01

    Global and regional climate models robustly simulate increases in Antarctic surface mass balance (SMB) during the twentieth and twenty-first centuries in response to anthropogenic global warming. Despite these robust model projections, however, observations indicate that there has been no significant change in Antarctic SMB in recent decades. We show that this apparent discrepancy between models and observations can be explained by the fact that the anthropogenic climate change signal during the second half of the twentieth century is small compared to the noise associated with natural climate variability. Using an ensemble of 35 global coupled climate models to separate signal and noise, we find that the forced SMB increase due to global warming in recent decades is unlikely to be detectable as a result of large natural SMB variability. However, our analysis reveals that the anthropogenic impact on Antarctic SMB is very likely to emerge from natural variability by the middle of the current century, thus mitigating future increases in global sea level.

  11. Recent mass balance of Purogangri ice cap, central Tibetan Plateau, by means of differential X-band SAR interferometry

    Directory of Open Access Journals (Sweden)

    N. Neckel

    2013-03-01

    Full Text Available Due to their remoteness, altitude and harsh climatic conditions, little is known about the glaciological parameters of ice caps on the Tibetan Plateau (TP. This study presents an interferometrical approach aiming at surface elevation changes of Purogangri ice cap, located on the central TP. Purogangri ice cap covers an area of 397 ± 9.7 km2 and is the largest ice cap on the TP. Its behavior is determined by dry and cold continental climate suggesting a polar-type glacier regime. We employed data from the actual TerraSAR-X mission and its add-on for Digital Elevation Measurements (TanDEM-X and compare it with elevation data from the Shuttle Radar Topography Mission (SRTM. These datasets are ideal for this approach as both datasets feature the same wavelength of 3.1 cm and are available at a fine grid spacing. Similar snow conditions can be assumed since the data were acquired in early February 2000 and late January 2012. The trend in glacier extend was extracted using a time series of Landsat data. Our results show a balanced mass budget for the studied time period which is in agreement with previous studies. Additionally, we detected an exceptional fast advance of one glacier tongue in the eastern part of the ice cap between 1999 and 2011.

  12. Auto-digital gain balancing: a new detection scheme for high-speed chemical species tomography of minor constituents

    Science.gov (United States)

    Pal, Sandip; McCann, Hugh

    2011-11-01

    In many dynamic gas-phase reaction processes, there is great interest to measure the distribution of minor constituents, i.e. automotive gasoline engine exhaust by catalytic conversion, where a characteristic challenge is to image the distribution of 10 ppm (average) of carbon monoxide (CO) at 1000 frames per second across a 50 mm diameter exhaust pipe; this particular problem has been pursued as a case study. In this paper, we present a novel electronic scheme that achieves the required measurement of around 10-3 absorption with 10-4 precision at kHz bandwidth. This was not previously achievable with any known technology. We call the new scheme Auto-Digital Gain Balancing. It is amenable to replication for many simultaneous measurement channels, and it permits simultaneous measurement of multiple species, in some circumstances. Experimental demonstrations are presented in the near-infrared. In single scans of a tunable diode laser, measurements of both CO and CO2 have been made with 20 dB signal-to-noise ratio at peak absorption. This work paves the way for chemical species tomography of minor constituents in many dynamic gas-phase systems.

  13. Probing native protein structures by chemical cross-linking, mass spectrometry, and bioinformatics.

    Science.gov (United States)

    Leitner, Alexander; Walzthoeni, Thomas; Kahraman, Abdullah; Herzog, Franz; Rinner, Oliver; Beck, Martin; Aebersold, Ruedi

    2010-08-01

    Chemical cross-linking of reactive groups in native proteins and protein complexes in combination with the identification of cross-linked sites by mass spectrometry has been in use for more than a decade. Recent advances in instrumentation, cross-linking protocols, and analysis software have led to a renewed interest in this technique, which promises to provide important information about native protein structure and the topology of protein complexes. In this article, we discuss the critical steps of chemical cross-linking and its implications for (structural) biology: reagent design and cross-linking protocols, separation and mass spectrometric analysis of cross-linked samples, dedicated software for data analysis, and the use of cross-linking data for computational modeling. Finally, the impact of protein cross-linking on various biological disciplines is highlighted.

  14. Materials balance on a chemically-dispersed oil and a whole oil exposed to an experimental beach front

    Energy Technology Data Exchange (ETDEWEB)

    Page, C.; Sumner, P.; Autenrieth, R. [Texas A and M Univ., Civil Engineering Dept., College Station, TX (United States); Bonner, J.; McDonald, T. [Texas A and M Univ., The Conrad Blucher Inst., Corpus Christi, TX (United States)

    1999-07-01

    A ten-day experiment simulating an oil spill and investigating the fate of both dispersed and whole oil in a near-shore environment was carried out at a wave tank facility in Corpus Christi, Texas. At one end of each tank, a sandy beach was configured and influent water was pumped from nearby Laguna Madre. The influent water flow was varied to simulate high and low tides, while the effluent rate was held constant. After oil application, time-dependent sediment and water column samples were taken throughout the ten-day experimental period, and materials balance on the oil was determined for both oil treatments using total petroleum hydrocarbon results from gas chromatography/mass spectroscopy analysis. Results showed that after 10 days nearly half of the applied oil in the oiled treatment remained in the tank, either sorbed to sediments, tank surfaces or other available surfaces within the tanks. The remaining oil was removed via the effluent. In the case of the dispersed oil all of the oil was flushed from the tanks with no detectable oil remaining on the sediments, suggesting that in an environmental context the use of dispersants can reduce the accumulation of residual oil on a sandy beach. 14 refs., 2 tabs., 2 figs.

  15. Materials balance on a chemically-dispersed oil and a whole oil exposed to an experimental beach front

    Energy Technology Data Exchange (ETDEWEB)

    Page, C.; Sumner, P.; Autenrieth, R. [Texas A and M Univ., Civil Engineering Dept., College Station, TX (United States); Bonner, J.; McDonald, T. [Texas A and M Univ., The Conrad Blucher Inst., Corpus Christi, TX (United States)

    1999-08-01

    A ten-day experiment simulating an oil spill and investigating the fate of both dispersed and whole oil in a near-shore environment was carried out at a wave tank facility in Corpus Christi, Texas. At one end of each tank, a sandy beach was configured and influent water was pumped from nearby Laguna Madre. The influent water flow was varied to simulate high and low tides, while the effluent rate was held constant. After oil application, time-dependent sediment and water column samples were taken throughout the ten-day experimental period, and materials balance on the oil was determined for both oil treatments using total petroleum hydrocarbon results from gas chromatography/mass spectroscopy analysis. Results showed that after 10 days nearly half of the applied oil in the oiled treatment remained in the tank, either sorbed to sediments, tank surfaces or other available surfaces within the tanks. The remaining oil was removed via the effluent. In the case of the dispersed oil all of the oil was flushed from the tanks with no detectable oil remaining on the sediments, suggesting that in an environmental context the use of dispersants can reduce the accumulation of residual oil on a sandy beach. 14 refs., 2 tabs., 2 figs.

  16. Comprehensive theory of the Deans' switch as a variable flow splitter: fluid mechanics, mass balance, and system behavior.

    Science.gov (United States)

    Boeker, Peter; Leppert, Jan; Mysliwietz, Bodo; Lammers, Peter Schulze

    2013-10-01

    The Deans' switch is an effluent switching device based on controlling flows of carrier gas instead of mechanical valves in the analytical flow path. This technique offers high inertness and a wear-free operation. Recently new monolithic microfluidic devices have become available. In these devices the whole flow system is integrated into a small metal device with low thermal mass and leak-tight connections. In contrast to a mechanical valve-based system, a flow-controlled system is more difficult to calculate. Usually the Deans' switch is used to switch one inlet to one of two outlets, by means of two auxiliary flows. However, the Deans' switch can also be used to deliver the GC effluent with a specific split ratio to both outlets. The calculation of the split ratio of the inlet flow to the two outlets is challenging because of the asymmetries of the flow resistances. This is especially the case, if one of the outlets is a vacuum device, such as a mass spectrometer, and the other an atmospheric detector, e.g. a flame ionization detector (FID) or an olfactory (sniffing) port. The capillary flows in gas chromatography are calculated with the Hagen-Poiseuille equation of the laminar, isothermal and compressible flow in circular tubes. The flow resistances in the new microfluidic devices have to be calculated with the corresponding equation for rectangular cross-section microchannels. The Hagen-Poiseuille equation underestimates the flow to a vacuum outlet. A corrected equation originating from the theory of rarefied flows is presented. The calculation of pressures and flows of a Deans' switch based chromatographic system is done by the solution of mass balances. A specific challenge is the consideration of the antidiffusion resistor between the two auxiliary gas lines of the Deans' switch. A full solution for the calculation of the Deans' switch including this restrictor is presented. Results from validation measurements are in good accordance with the developed

  17. Estimating Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2012-08-01

    Full Text Available We report future projections of Surface Mass Balance (SMB over the Greenland ice sheet (GrIS obtained with the regional climate model MAR, forced by the outputs of three CMIP5 General Circulation Models (GCMs when considering two different warming scenarios (RCP 4.5 and RCP 8.5. The GCMs selected in this study have been chosen according to their ability to simulate the current climate over Greenland. Our results indicate that in a warmer climate (i the mass gained due to increased precipitation over GrIS does not compensate the mass lost through increased run-off; (ii the surface melt increases non-linearly with rising temperatures due to the positive feedback between surface albedo and melt, associated with the expansion of bare ice zones which, in addition, decreases the ice sheet refreezing capacity; (iii most of the precipitation is expected to fall as rainfall in summer, which further increases surface melt; (iv no considerable change is expected on the length of the melting season, since heavier winter snowfall dampens the melt increase at the end of spring; (v the increase of meltwater run-off versus temperature anomalies is dependent of the GCM-forced MAR ability to simulate the current climate; (vi the MAR-simulated SMB changes can be approximated