WorldWideScience

Sample records for chemical accident investigation

  1. Supervisor's accident investigation handbook

    International Nuclear Information System (INIS)

    1980-02-01

    This pamphlet was prepared by the Environmental Health and Safety Department (EH and S) of Lawrence Berkeley Laboratory (LBL) to provide LBL supervisors with a handy reference to LBL's accident investigation program. The publication supplements the Accident and Emergencies section of LBL's Regulations and Procedures Manual, Pub. 201. The present guide discusses only accidents that are to be investigated by the supervisor. These accidents are classified as Type C by the Department of Energy (DOE) and include most occupational injuries and illnesses, government motor-vehicle accidents, and property damages of less than $50,000

  2. Credible investigation of air accidents

    International Nuclear Information System (INIS)

    Smart, K.

    2004-01-01

    Within the United Kingdom the Air Accidents Investigation Branch (AAIB) has been used as a model for the other transport modes accident investigation bodies. Government Ministers considered that the AAIB's approach had established the trust of the public and the aviation industry in its ability to conduct independent and objective investigations. The paper will examine the factors that are involved in establishing this trust. They include: the investigation framework; the actual and perceived independence of the accident investigating body; the aviation industry's safety culture; the qualities of the investigators and the quality of their liaison with bereaved families those directly affected by the accidents they investigate

  3. Experimental investigation of material chemical effects on emergency core cooling pump suction filter performance after loss of coolant accident

    International Nuclear Information System (INIS)

    Park, Jong Woon; Park, Byung Gi; Kim, Chang Hyun

    2009-01-01

    Integral tests of head loss through an emergency core cooling filter screen are conducted, simulating reactor building environmental conditions for 30 days after a loss of coolant accident. A test rig with five individual loops each of whose chamber is established to test chemical product formation and measure the head loss through a sample filter. The screen area at each chamber and the amounts of reactor building materials are scaled down according to specific plant condition. A series of tests have been performed to investigate the effects of calcium-silicate, reactor building spray, existence of calcium-silicate with tri-sodium phosphate (TSP), and composition of materials. The results showed that head loss across the chemical bed with even a small amount of calcium-silicate insulation instantaneously increased as soon as TSP was added to the test solution. Also, the head loss across the filter screen is strongly affected by spray duration and the head loss increase is rapid at the early stage, because of high dissolution and precipitation of aluminum and zinc. After passivation of aluminum and zinc by corrosion, the head loss increase is much slowed down and is mainly induced by materials such as calcium, silicon, and magnesium leached from NUKON TM and concrete. Furthermore, it is newly found that the spay buffer agent, tri-sodium phosphate, to form protective coating on the aluminum surface and reduce aluminum leaching is not effective for a large amount of aluminum and a long spray.

  4. Accident investigation board report on the May 14, 1997, chemical explosion at the Plutonium Reclamation Facility, Hanford Site,Richland, Washington - summary report

    International Nuclear Information System (INIS)

    Gerton, R.E.

    1997-01-01

    This report is a summary of the Accident Investigation Board Report on the May 14, 1997, Chemical Explosion at the Plutonium Reclamation Facility, Hanford Site, Richland, Washington (DOE/RL-97-59). The referenced report provides a greater level of detail and includes a complete discussion of the facts identified, analysis of those facts, conclusions derived from the analysis, identification of the accident's causal factors, and recommendations that should be addressed through follow-up action by the U.S. Department of Energy and its contractors. This companion document provides a concise summary of that report, with emphasis on management issues. Evaluation of emergency and occupational health response to, and radiological and chemical releases from, this accident was not within the scope of this investigation, but is the subject of a separate investigation and report (see DOE/RL-97-62)

  5. Traffic accidents: an econometric investigation

    OpenAIRE

    Tito Moreira; Adolfo Sachsida; Loureiro Paulo

    2004-01-01

    Based on a sample of drivers in Brasilia's streets, this article investigates whether distraction explains traffic accidents. A probit model is estimated to determine the predictive power of several variables on traffic accidents. The main conclusion drawn from this study is that the proxies used to measure distraction, such as the use of cell phones and cigarette smoking in a moving vehicle, are significant factors in determining traffic accidents.

  6. Accident investigation board report on the May 14, 1997, chemical explosion at the Plutonium Reclamation Facility, Hanford Site,Richland, Washington - final report

    International Nuclear Information System (INIS)

    Gerton, R.E.

    1997-01-01

    On May 14, 1997, at 7:53 p.m. (PDT), a chemical explosion occur-red in Tank A- 109 in Room 40 of the Plutonium Reclamation Facility (Facility) located in the 200 West Area of the Hanford Site, approximately 30 miles north of Richland, Washington. The inactive processing Facility is part of the Plutonium Finishing Plant (PFP). On May 16, 1997, Lloyd L. Piper, Deputy Manager, acting for John D. Wagoner, Manager, U.S. Department of Energy (DOE), Richland Operations Office (RL), formally established an Accident Investigation Board (Board) to investigate the explosion in accordance with DOE Order 225. 1, Accident Investigations. The Board commenced its investigation on May 15, 1997, completed the investigation on July 2, 1997, and submitted its findings to the RL Manager on July 26, 1997. The scope of the Board's investigation was to review and analyze the circumstances of the events that led to the explosion; to analyze facts and to determine the causes of the accident; and to develop conclusions and judgments of need that may help prevent a recurrence of the accident. The scope also included the application of lessons learned from similar accidents within DOE. In addition to this detailed report, a companion document has also been prepared that provides a concise summary of the facts and conclusions of this report, with an emphasis on management issues (DOE/RL-97-63)

  7. Multidisciplinary accident investigation : volume 2

    Science.gov (United States)

    1976-05-01

    The Task II final report for 1974 of the Multidisciplinary Accident Investigation : Team of the Maryland Medical-Legal Foundation, Inc. is presented. This report describes some preliminary findings emanating from a series of comprehensive, multivaria...

  8. Multidisciplinary accident investigation : volume 1

    Science.gov (United States)

    1976-09-01

    The final report of the Multidisciplinary Accident Investigation Team of the Maryland Medical-Legal Foundation, Inc. is presented. The report describes the methodology, results, discussions, conclusions and recommendations pertaining to the investiga...

  9. Accidents in chemical industry: are they foreseeable?

    NARCIS (Netherlands)

    Sonnemans, P.J.M.; Körvers, P.M.W.

    2006-01-01

    Accidents recur,’ which is what Kletz [Kletz T. (1993). Lessons from disasters, how organisations have no memory and accidents recur. UK: Institution of Chemical Engineers] wrote in 1993. Indeed, despite all measures taken accidents may re-occur, but ‘disruptions’ in a process reoccur much more

  10. 29 CFR 1960.29 - Accident investigation.

    Science.gov (United States)

    2010-07-01

    ... reflective of the seriousness of the accident. (b) In any case, each accident which results in a fatality or... evidence uncovered during accident investigations which would be of benefit in developing a new OSHA...

  11. Chemical phenomena under severe accident conditions

    International Nuclear Information System (INIS)

    Powers, D.A.

    1988-01-01

    A severe nuclear reactor accident is expected to involve a vast number of chemical processes. The chemical processes of major safety significance begin with the production of hydrogen during steam oxidation of fuel cladding. Physico-chemical changes in the fuel and the vaporization of radionuclides during reactor accidents have captured much of the attention of the safety community in recent years. Protracted chemical interactions of core debris with structural concrete mark the conclusion of dynamic events in a severe accident. An overview of the current understanding of chemical processes in severe reactor accident is provided in this paper. It is shown that most of this understanding has come from application of findings from other fields though a few areas have in the past been subject to in-depth study of a fundamental nature. Challenges in the study of severe accident chemistry are delineated

  12. Deepwater Horizon Accident Investigation Report

    International Nuclear Information System (INIS)

    2010-09-01

    On the evening of April 20, 2010, a well control event allowed hydrocarbons to escape from the Macondo well onto Transocean's Deepwater Horizon, resulting in explosions and fire on the rig. Eleven people lost their lives, and 17 others were injured. The fire, which was fed by hydrocarbons from the well, continued for 36 hours until the rig sank. Hydrocarbons continued to flow from the reservoir through the wellbore and the blowout preventer (BOP) for 87 days, causing a spill of national significance. BP Exploration and Production Inc. was the lease operator of Mississippi Canyon Block 252, which contains the Macondo well. BP formed an investigation team that was charged with gathering the facts surrounding the accident, analyzing available information to identify possible causes and making recommendations to enable prevention of similar accidents in the future. The BP investigation team began its work immediately in the aftermath of the accident, working independently from other BP spill response activities and organizations. The ability to gather information was limited by a scarcity of physical evidence and restricted access to potentially relevant witnesses. The team had access to partial real-time data from the rig, documents from various aspects of the Macondo well's development and construction, witness interviews and testimony from public hearings. The team used the information that was made available by other companies, including Transocean, Halliburton and Cameron. Over the course of the investigation, the team involved over 50 internal and external specialists from a variety of fields: safety, operations, subsea, drilling, well control, cementing, well flow dynamic modeling, BOP systems and process hazard analysis. This report presents an analysis of the events leading up to the accident, eight key findings related to the causal chain of events and recommendations to enable the prevention of a similar accident. The investigation team worked separately

  13. Deepwater Horizon Accident Investigation Report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-09-15

    On the evening of April 20, 2010, a well control event allowed hydrocarbons to escape from the Macondo well onto Transocean's Deepwater Horizon, resulting in explosions and fire on the rig. Eleven people lost their lives, and 17 others were injured. The fire, which was fed by hydrocarbons from the well, continued for 36 hours until the rig sank. Hydrocarbons continued to flow from the reservoir through the wellbore and the blowout preventer (BOP) for 87 days, causing a spill of national significance. BP Exploration and Production Inc. was the lease operator of Mississippi Canyon Block 252, which contains the Macondo well. BP formed an investigation team that was charged with gathering the facts surrounding the accident, analyzing available information to identify possible causes and making recommendations to enable prevention of similar accidents in the future. The BP investigation team began its work immediately in the aftermath of the accident, working independently from other BP spill response activities and organizations. The ability to gather information was limited by a scarcity of physical evidence and restricted access to potentially relevant witnesses. The team had access to partial real-time data from the rig, documents from various aspects of the Macondo well's development and construction, witness interviews and testimony from public hearings. The team used the information that was made available by other companies, including Transocean, Halliburton and Cameron. Over the course of the investigation, the team involved over 50 internal and external specialists from a variety of fields: safety, operations, subsea, drilling, well control, cementing, well flow dynamic modeling, BOP systems and process hazard analysis. This report presents an analysis of the events leading up to the accident, eight key findings related to the causal chain of events and recommendations to enable the prevention of a similar accident. The investigation team worked

  14. Lessons learned from accidents investigations

    Energy Technology Data Exchange (ETDEWEB)

    Zuniga-Bello, P. [Consejo Nacional de Ciencia y Tecnologia (CONACYT), Mexico City (Mexico); Croft, J. [National Radiological Protection Board (United Kingdom); Glenn, J

    1997-12-31

    Accidents from three main practices: medical applications, industrial radiography and industrial irradiators are used to illustrate some common causes of accidents and the main lessons to be learned. A brief description of some of these accidents is given. Lessons learned from the described accidents are approached by subjects covering: safety culture, quality assurance, human factors, good engineering practice, defence in depth, security of sources, safety assessment and monitoring and verification compliance. (author)

  15. Lessons learned from accident investigations

    International Nuclear Information System (INIS)

    Zuniga-Bello, P.; Croft, J.R.; Glenn, J.

    1998-01-01

    Accidents in three main practices - medical applications, industrial radiography and industrial irradiators - are used to illustrate some common causes of accidents and the main lessons to be learned from them. A brief description of some of these accidents is given. Lessons learned from the accidents described are approached bearing in mind: safety culture, quality assurance, human factors, good engineering practice, defence in depth, security of sources, safety assessment and monitoring and verification compliance. (author)

  16. Multidisciplinary perspective on accident investigation

    International Nuclear Information System (INIS)

    Basnyat, S.; Chozos, N.; Palanque, P.

    2006-01-01

    The increasing complexity of many computer-controlled application processes is placing increasing demands on the investigation of adverse events. At the same time, there is a growing realisation that accident investigators must consider a wider range of contributory and contextual factors that help to shape human behaviour in the causes of safety-related incidents. A range of techniques have been developed to address these issues. For example (as we show in this paper), task modelling techniques have been extended from human computer interaction and systems design to analyse the causes and consequences of operator 'error'. Similarly, barrier analysis has been widely used to identify the way in which defences either protected or failed to protect a target system from potential hazards. Many barriers fail from common causes, including misconceptions that can be traced back to early stages in the development of a safety-critical system. For instance, unwarranted assumptions can be made about the impact of training on operator behaviour in emergency situations. Similarly, barrier analysis can also be used before a system has been designed to inform the system model and make it more tolerant to errors by incorporating human and technical barriers into the design. Task models often uncover deep-rooted problems, for instance, in workload allocation across many different aspects of an interactive control system. It can be difficult to use barrier and task analysis to trace these common causes that lie behind the failure of many different defences. In order to deal with this complex combination of contributory factors and systems, we promote the use of abstraction (via models) as a way of representing these components and their interrelations whether it is design, construction or investigation. We use, to formally model an abstraction of the system. Additionally, the system model (described using a dialect of high-level Petri-nets) allows to reason about the system and to

  17. Chemical considerations in severe accident analysis

    International Nuclear Information System (INIS)

    Malinauskas, A.P.; Kress, T.S.

    1988-01-01

    The Reactor Safety Study presented the first systematic attempt to include fission product physicochemical effects in the determination of expected consequences of hypothetical nuclear reactor power plant accidents. At the time, however, the data base was sparse, and the treatment of fission product behavior was not entirely consistent or accurate. Considerable research has since been performed to identify and understand chemical phenomena that can occur in the course of a nuclear reactor accident, and how these phenomena affect fission product behavior. In this report, the current status of our understanding of the chemistry of fission products in severe core damage accidents is summarized and contrasted with that of the Reactor Safety Study

  18. Multidisciplinary perspective on accident investigation

    Energy Technology Data Exchange (ETDEWEB)

    Basnyat, S. [LIIHS-IRIT, Universite Paul Sabatier, 118, route de Narbonne, 31062 Toulouse Cedex 4 (France)]. E-mail: basnyat@irit.fr; Chozos, N. [Dept. of Computing Science, University of Glasgow, Glasgow, G12 8QQ, Scotland (United Kingdom)]. E-mail: nick@dcs.gla.ac.uk; Palanque, P. [LIIHS-IRIT, Universite Paul Sabatier, 118, route de Narbonne, 31062 Toulouse Cedex 4 (France)]. E-mail: palanque@irit.fr

    2006-12-15

    The increasing complexity of many computer-controlled application processes is placing increasing demands on the investigation of adverse events. At the same time, there is a growing realisation that accident investigators must consider a wider range of contributory and contextual factors that help to shape human behaviour in the causes of safety-related incidents. A range of techniques have been developed to address these issues. For example (as we show in this paper), task modelling techniques have been extended from human computer interaction and systems design to analyse the causes and consequences of operator 'error'. Similarly, barrier analysis has been widely used to identify the way in which defences either protected or failed to protect a target system from potential hazards. Many barriers fail from common causes, including misconceptions that can be traced back to early stages in the development of a safety-critical system. For instance, unwarranted assumptions can be made about the impact of training on operator behaviour in emergency situations. Similarly, barrier analysis can also be used before a system has been designed to inform the system model and make it more tolerant to errors by incorporating human and technical barriers into the design. Task models often uncover deep-rooted problems, for instance, in workload allocation across many different aspects of an interactive control system. It can be difficult to use barrier and task analysis to trace these common causes that lie behind the failure of many different defences. In order to deal with this complex combination of contributory factors and systems, we promote the use of abstraction (via models) as a way of representing these components and their interrelations whether it is design, construction or investigation. We use, to formally model an abstraction of the system. Additionally, the system model (described using a dialect of high-level Petri-nets) allows to reason about the

  19. Chemical Accident Prevention: Site Security

    Science.gov (United States)

    This chemical safety alert assists facilities that routinely handle extremely hazardous substances, along with SERCs, LEPCs, and emergency responders, in their efforts to reduce criminally caused releases and vulnerability to terrorist activity.

  20. NIF: Impacts of chemical accidents and comparison of chemical/radiological accident approaches

    International Nuclear Information System (INIS)

    Lazaro, M.A.; Policastro, A.J.; Rhodes, M.

    1996-01-01

    The US Department of Energy (DOE) proposes to construct and operate the National Ignition Facility (NIF). The goals of the NIF are to (1) achieve fusion ignition in the laboratory for the first time by using inertial confinement fusion (ICF) technology based on an advanced-design neodymium glass solid-state laser, and (2) conduct high-energy-density experiments in support of national security and civilian applications. The primary focus of this paper is worker-public health and safety issues associated with postulated chemical accidents during the operation of NIF. The key findings from the accident analysis will be presented. Although NIF chemical accidents will be emphasized, the important differences between chemical and radiological accident analysis approaches and the metrics for reporting results will be highlighted. These differences are common EIS facility and transportation accident assessments

  1. Human Factors in Cabin Accident Investigations

    Science.gov (United States)

    Chute, Rebecca D.; Rosekind, Mark R. (Technical Monitor)

    1996-01-01

    Human factors has become an integral part of the accident investigation protocol. However, much of the investigative process remains focussed on the flight deck, airframe, and power plant systems. As a consequence, little data has been collected regarding the human factors issues within and involving the cabin during an accident. Therefore, the possibility exists that contributing factors that lie within that domain may be overlooked. The FAA Office of Accident Investigation is sponsoring a two-day workshop on cabin safety accident investigation. This course, within the workshop, will be of two hours duration and will explore relevant areas of human factors research. Specifically, the three areas of discussion are: Information transfer and resource management, fatigue and other physical stressors, and the human/machine interface. Integration of these areas will be accomplished by providing a suggested checklist of specific cabin-related human factors questions for investigators to probe following an accident.

  2. Domino effect in chemical accidents: main features and accident sequences

    OpenAIRE

    Casal Fàbrega, Joaquim; Darbra Roman, Rosa Maria

    2010-01-01

    The main features of domino accidents in process/storage plants and in the transportation of hazardous materials were studied through an analysis of 225 accidents involving this effect. Data on these accidents, which occurred after 1961, were taken from several sources. Aspects analyzed included the accident scenario, the type of accident, the materials involved, the causes and consequences and the most common accident sequences. The analysis showed that the most frequent causes a...

  3. A Serious Game for Traffic Accident Investigators

    Science.gov (United States)

    Binsubaih, Ahmed; Maddock, Steve; Romano, Daniela

    2006-01-01

    In Dubai, traffic accidents kill one person every 37 hours and injure one person every 3 hours. Novice traffic accident investigators in the Dubai police force are expected to "learn by doing" in this intense environment. Currently, they use no alternative to the real world in order to practice. This paper argues for the use of an…

  4. Vulnerability assessment of chemical industry facilities in South Korea based on the chemical accident history

    Science.gov (United States)

    Heo, S.; Lee, W. K.; Jong-Ryeul, S.; Kim, M. I.

    2016-12-01

    The use of chemical compounds are keep increasing because of their use in manufacturing industry. Chemical accident is growing as the consequence of the chemical use increment. Devastating damages from chemical accidents are far enough to aware people's cautious about the risk of the chemical accident. In South Korea, Gumi Hydrofluoric acid leaking accident triggered the importance of risk management and emphasized the preventing the accident over the damage reducing process after the accident occurs. Gumi accident encouraged the government data base construction relate to the chemical accident. As the result of this effort Chemical Safety-Clearing-house (CSC) have started to record the chemical accident information and damages according to the Harmful Chemical Substance Control Act (HCSC). CSC provide details information about the chemical accidents from 2002 to present. The detail informations are including title of company, address, business type, accident dates, accident types, accident chemical compounds, human damages inside of the chemical industry facilities, human damage outside of the chemical industry facilities, financial damages inside of the chemical industry facilities, and financial damages outside of the chemical industry facilities, environmental damages and response to the chemical accident. Collected the chemical accident history of South Korea from 2002 to 2015 and provide the spatial information to the each accident records based on their address. With the spatial information, compute the data on ArcGIS for the spatial-temporal analysis. The spatial-temporal information of chemical accident is organized by the chemical accident types, damages, and damages on environment and conduct the spatial proximity with local community and environmental receptors. Find the chemical accident vulnerable area of South Korea from 2002 to 2015 and add the vulnerable area of total period to examine the historically vulnerable area from the chemical accident in

  5. Domino effect in chemical accidents: main features and accident sequences.

    Science.gov (United States)

    Darbra, R M; Palacios, Adriana; Casal, Joaquim

    2010-11-15

    The main features of domino accidents in process/storage plants and in the transportation of hazardous materials were studied through an analysis of 225 accidents involving this effect. Data on these accidents, which occurred after 1961, were taken from several sources. Aspects analyzed included the accident scenario, the type of accident, the materials involved, the causes and consequences and the most common accident sequences. The analysis showed that the most frequent causes are external events (31%) and mechanical failure (29%). Storage areas (35%) and process plants (28%) are by far the most common settings for domino accidents. Eighty-nine per cent of the accidents involved flammable materials, the most frequent of which was LPG. The domino effect sequences were analyzed using relative probability event trees. The most frequent sequences were explosion→fire (27.6%), fire→explosion (27.5%) and fire→fire (17.8%). Copyright © 2010 Elsevier B.V. All rights reserved.

  6. Lockout/tagout accident investigation.

    Science.gov (United States)

    White, James R

    2014-08-01

    When I was in boot camp, our drill instructor told us that assume makes an ass out of u and me. It was true then, and it is true today. In this instance, assumptions came into play several times, both by the worker and by the companies involved. The good news is that it did not result in a fatality, but that does not relieve the pain and suffering that the employee had to endure. This same type of scenario is likely repeated at many job sites throughout the United States. Multiple contractors, dozens--maybe hundreds--of workers, power system equipment and devices; all of these have to be taken into consideration when performing maintenance activities. It can become a blur. People are people, and people make mistakes. That is why we have OSHA regulations, NFPA 70E, company procedures, policies, etc. Most if not all of us have either been involved in accidents or know people who have been. It's not like it's a secret that people make mistakes, but talk to some and they seem to think only others have that failing. Safety is not about just any one procedure or rule. It's about slowing down, making a plan, and executing that plan. There are plenty of tools available to help us: policies, procedures, codes, standards, federal regulations, and state and local laws. I am not about to say that the worker involved in this incident was not taking safety seriously, but he failed to follow some fundamental safety rules like test-before-touch. If he had taken just that one step, there would be nothing to write about.

  7. Emergency Evacuation of Hazardous Chemical Accidents Based on Diffusion Simulation

    OpenAIRE

    Jiang-Hua Zhang; Hai-Yue Liu; Rui Zhu; Yang Liu

    2017-01-01

    The recent rapid development of information technology, such as sensing technology, communications technology, and database, allows us to use simulation experiments for analyzing serious accidents caused by hazardous chemicals. Due to the toxicity and diffusion of hazardous chemicals, these accidents often lead to not only severe consequences and economic losses, but also traffic jams at the same time. Emergency evacuation after hazardous chemical accidents is an effective means to reduce the...

  8. 32 CFR 634.29 - Traffic accident investigation reports.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Traffic accident investigation reports. 634.29... records. Installation law enforcement officials will record traffic accident investigations on Service/DLA... traffic accident investigation reports pertaining to accidents investigated by military police that...

  9. Diamond Fire: Serious Accident Investigation Report

    Science.gov (United States)

    John Waconda; Ivan Pupulidy; Leonard Diaz; Robin Broyles; Roberta Junge; James Saveland

    2012-01-01

    This incident is effectively two studies. The first study, and the reason the Serious Accident Investigation Team was assembled, was due to a fatality, which the autopsy later determined to have been caused by a heart attack. The team was not aware of the cause of death for over 4 weeks after the incident occurred. However, the observed and reported cases of heat...

  10. 32 CFR 636.13 - Traffic accident investigation reports.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Traffic accident investigation reports. 636.13... Stewart, Georgia § 636.13 Traffic accident investigation reports. In addition to the requirements in § 634... record traffic accident investigations on DA Form 3946 (Military Police Traffic Accident Report) and DA...

  11. Chemical dosimetry system for criticality accidents.

    Science.gov (United States)

    Miljanić, Saveta; Ilijas, Boris

    2004-01-01

    Ruder Bosković Institute (RBI) criticality dosimetry system consists of a chemical dosimetry system for measuring the total (neutron + gamma) dose, and a thermoluminescent (TL) dosimetry system for a separate determination of the gamma ray component. The use of the chemical dosemeter solution chlorobenzene-ethanol-trimethylpentane (CET) is based on the radiolytic formation of hydrochloric acid, which protonates a pH indicator, thymolsulphonphthalein. The high molar absorptivity of its red form at 552 nm is responsible for a high sensitivity of the system: doses in the range 0.2-15 Gy can be measured. The dosemeter has been designed as a glass ampoule filled with the CET solution and inserted into a pen-shaped plastic holder. For dose determinations, a newly constructed optoelectronic reader has been used. The RBI team took part in the International Intercomparison of Criticality Accident Dosimetry Systems at the SILENE Reactor, Valduc, June 2002, with the CET dosimetry system. For gamma ray dose determination TLD-700 TL detectors were used. The results obtained with CET dosemeter show very good agreement with the reference values.

  12. Additional investigations on the consequences of accidents

    International Nuclear Information System (INIS)

    Ehrhardt, J.; Bayer, A.; Burkart, K.

    1982-01-01

    As a first step to improve the accident consequence model of the German Risk Study within the Phase B, additional investigations on special problems and questions were performed. In detail attention is given to the following topics: emergency protective actions in the vicinity of the site; latent cancer fatalities - allocated to the population living during the nuclear accident and to persons born afterwards, within and beyond a distance of 540 km from the site, caused by radiation doses below the dose limits of the German radiation protection regulations estimated assuming a nonlinear dose response function; risk assessments of nuclear power plants with lower capacities; loss of life expectancy after accidental radiation exposure. All results are presented separately for the 8 release categories of the German Risk Study. (orig.) [de

  13. Independent accident investigation: a modern safety tool

    International Nuclear Information System (INIS)

    Stoop, John A.

    2004-01-01

    Historically, safety has been subjected to a fragmented approach. In the past, every department has had its own responsibility towards safety, focusing either on working conditions, internal safety, external safety, rescue and emergency, public order or security. They each issued policy documents, which in their time were leading statements for elaboration and regulation. They also addressed safety issues with tools of various nature, often specifically developed within their domain. Due to a series of major accidents and disasters, the focus of attention is shifting from complying with quantitative risk standards towards intervention in primary operational processes, coping with systemic deficiencies and a more integrated assessment of safety in its societal context. In The Netherlands recognition of the importance of independent investigations has led to an expansion of this philosophy from the transport sector to other sectors. The philosophy now covers transport, industry, defense, natural disaster, environment and health and other major occurrences such as explosions, fires, and collapse of buildings or structures. In 2003 a multi-sector covering law will establish an independent safety board in The Netherlands. At a European level, mandatory investigation agencies are recognized as indispensable safety instruments for aviation, railways and the maritime sector, for which EU Directives are in place or being progressed [Transport accident and incident investigation in the European Union, European Transport Safety Council, ISBN 90-76024-10-3, Brussel, 2001]. Due to a series of major events, attention has been drawn to the consequences of disasters, highlighting the involvement of rescue and emergency services. They also have become subjected to investigative efforts, which in return, puts demands on investigation methodology. This paper comments on an evolutionary development in safety thinking and of safety boards, highlighting some consequences for strategic

  14. Chemical factors affecting fission product transport in severe LMFBR accidents

    International Nuclear Information System (INIS)

    Wichner, R.P.; Jolley, R.L.; Gat, U.; Rodgers, B.R.

    1984-10-01

    This study was performed as a part of a larger evaluation effort on LMFBR accident, source-term estimation. Purpose was to provide basic chemical information regarding fission product, sodium coolant, and structural material interactions required to perform estimation of fission product transport under LMFBR accident conditions. Emphasis was placed on conditions within the reactor vessel; containment vessel conditions are discussed only briefly

  15. Managing major chemical accidents in China: Towards effective risk information

    NARCIS (Netherlands)

    He, G.; Zhang, L.; Lu, Y.; Mol, A.P.J.

    2011-01-01

    Chemical industries, from their very inception, have been controversial due to the high risks they impose on safety of human beings and the environment. Recent decades have witnessed increasing impacts of the accelerating expansion of chemical industries and chemical accidents have become a major

  16. Managing major chemical accidents in China: Towards effective risk information

    International Nuclear Information System (INIS)

    He Guizhen; Zhang Lei; Lu Yonglong; Mol, Arthur P.J.

    2011-01-01

    Chemical industries, from their very inception, have been controversial due to the high risks they impose on safety of human beings and the environment. Recent decades have witnessed increasing impacts of the accelerating expansion of chemical industries and chemical accidents have become a major contributor to environmental and health risks in China. This calls for the establishment of an effective chemical risk management system, which requires reliable, accurate and comprehensive data in the first place. However, the current chemical accident-related data system is highly fragmented and incomplete, as different responsible authorities adopt different data collection standards and procedures for different purposes. In building a more comprehensive, integrated and effective information system, this article: (i) reviews and assesses the existing data sources and data management, (ii) analyzes data on 976 recorded major hazardous chemical accidents in China over the last 40 years, and (iii) identifies the improvements required for developing integrated risk management in China.

  17. Investigation of accidents within construction zones in Louisiana.

    Science.gov (United States)

    1981-07-01

    This investigation is to analyze construction and maintenance work zone accidents by reviewing accident data to determine if deficiencies exist and recommend possible corrective measures for future traffic control applications. To accomplish this, a ...

  18. 32 CFR 634.28 - Traffic accident investigation.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Traffic accident investigation. 634.28 Section... ENFORCEMENT AND CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION Traffic Supervision § 634.28 Traffic accident investigation. Installation law enforcement personnel must make detailed investigations of...

  19. Strategies for dealing with resistance to recommendations from accident investigations

    DEFF Research Database (Denmark)

    Lundberg, J.; Rollenhagen, C.; Hollnagel, E.

    2012-01-01

    Accident investigation reports usually lead to a set of recommendations for change. These recommendations are, however, sometimes resisted for reasons such as various aspects of ethics and power. When accident investigators are aware of this, they use several strategies to overcome the resistance....... This paper describes strategies for dealing with four different types of resistance to change. The strategies were derived from qualitative analysis of 25 interviews with Swedish accident investigators from seven application domains. The main contribution of the paper is a better understanding of effective...... strategies for achieving change associated with accident investigation. (C) 2011 Elsevier Ltd. All rights reserved....

  20. Strategies for dealing with resistance to recommendations from accident investigations.

    Science.gov (United States)

    Lundberg, Jonas; Rollenhagen, Carl; Hollnagel, Erik; Rankin, Amy

    2012-03-01

    Accident investigation reports usually lead to a set of recommendations for change. These recommendations are, however, sometimes resisted for reasons such as various aspects of ethics and power. When accident investigators are aware of this, they use several strategies to overcome the resistance. This paper describes strategies for dealing with four different types of resistance to change. The strategies were derived from qualitative analysis of 25 interviews with Swedish accident investigators from seven application domains. The main contribution of the paper is a better understanding of effective strategies for achieving change associated with accident investigation. Copyright © 2011 Elsevier Ltd. All rights reserved.

  1. 32 CFR 636.12 - Traffic accident investigation.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Traffic accident investigation. 636.12 Section... ENFORCEMENT AND CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.12 Traffic accident investigation. In addition to the requirements in § 634.28 of...

  2. Evaluating advancements in accident investigations using a novel framework

    NARCIS (Netherlands)

    Karanikas, N.; Soltani, P.; de Boer, R.J.; Roelen, A.

    2015-01-01

    Safety is monitored by various proactive and reactive methods, including the investigation of adverse accidents and incidents, which are collectively known as safety investigations. In this study we demonstrate how accident and incident investigation reports can be useful to identify implicit safety

  3. Strategies for dealing with resistance to recommendations from accident investigations

    OpenAIRE

    Lundberg, Jonas; Rollenhagen, Carl; Hollnagel, Erik; Rankin, Amy

    2012-01-01

    Accident investigation reports usually lead to a set of recommendations for change. These recommendations are, however, sometimes resisted for reasons such as various aspects of ethics and power. When accident investigators are aware of this, they use several strategies to overcome the resistance. This paper describes strategies for dealing with four different types of resistance to change. The strategies were derived from qualitative analysis of 25 interviews with Swedish accident investigat...

  4. Biomass accident investigations – missed opportunities for learning and accident prevention

    DEFF Research Database (Denmark)

    Hedlund, Frank Huess

    2017-01-01

    The past decade has seen a major increase in the production of energy from biomass. The growth has been mirrored in an increase of serious biomass related accidents involving fires, gas explosions, combustible dust explosions and the release of toxic gasses. There are indications that the number...... of bioenergy related accidents is growing faster than the energy production. This paper argues that biomass accidents, if properly investigated and lessons shared widely, provide ample opportunities for improving general hazard awareness and safety performance of the biomass industry. The paper examines...... selected serious accidents involving biogas and wood pellets in Denmark and argues that such opportunities for learning were missed because accident investigations were superficial, follow-up incomplete and information sharing absent. In one particularly distressing case, a facility saw a repeat accident...

  5. Research investigation report on Fukushima Daiichi nuclear accident

    International Nuclear Information System (INIS)

    2012-03-01

    This report was issued in February 2012 by Rebuild Japan Initiative Foundation's Independent Investigation Commission on the Fukushima Daiichi Nuclear Accident, which consisted of six members from the private sector in independent positions and with no direct interest in the business of promoting nuclear power. Commission aimed to determine the truth behind the accident by clarifying the various problems and reveal systematic problems behind these issues so as to create a new starting point by identifying clear lessons learned. Report composed of four chapters; (1) progression of Fukushima accident and resulting damage (accident management after Fukushima accident, and effects and countermeasure of radioactive materials discharged into the environment), (2) response against Fukushima accident (emergency response of cabinet office against nuclear disaster, risk communication and on-site response against nuclear disaster), (3) analysis of historical and structural factors (technical philosophy of nuclear safety, problems of nuclear safety regulation of Fukushima accident, safety regulatory governance and social background of 'Safety Myth'), (4) Global Context (implication in nuclear security, Japan in nuclear safety regime, U.S.-Japan relations for response against Fukushima accident, lessons learned from Fukushima accident - aiming at creation of resilience). Report could identify causes of Fukushima accident and factors related to resulting damages, show the realities behind failure to prevent the spread of damage, and analyze the overall structural and historical background behind the accidents. (T. Tanaka)

  6. Emergency Evacuation of Hazardous Chemical Accidents Based on Diffusion Simulation

    Directory of Open Access Journals (Sweden)

    Jiang-Hua Zhang

    2017-01-01

    Full Text Available The recent rapid development of information technology, such as sensing technology, communications technology, and database, allows us to use simulation experiments for analyzing serious accidents caused by hazardous chemicals. Due to the toxicity and diffusion of hazardous chemicals, these accidents often lead to not only severe consequences and economic losses, but also traffic jams at the same time. Emergency evacuation after hazardous chemical accidents is an effective means to reduce the loss of life and property and to smoothly resume the transport network as soon as possible. This paper considers the dynamic changes of the hazardous chemicals’ concentration after their leakage and simulates the diffusion process. Based on the characteristics of emergency evacuation of hazardous chemical accidents, we build a mixed-integer programming model and design a heuristic algorithm using network optimization and diffusion simulation (hereafter NODS. We then verify the validity and feasibility of the algorithm using Jinan, China, as a computational example. In the end, we compare the results from different scenarios to explore the key factors affecting the effectiveness of the evacuation process.

  7. Safety investigation of team performance in accidents

    International Nuclear Information System (INIS)

    Petkov, G.; Todorov, V.; Takov, T.; Petrov, V.; Stoychev, K.; Vladimirov, V.; Chukov, I.

    2004-01-01

    The paper presents the capacities of the performance evaluation of teamwork (PET) method. Its practicability and efficiency are illustrated by retrospective human reliability analyse of the famous nuclear and maritime accidents. A quantitative assessment of operators' performance on the base of thermo-hydraulic (T/H) calculations and full-scope simulator data for set of NPP design basic accidents with WWER is demonstrated. The last data are obtained on the 'WWER-1000' full-scope simulator of Kozloduy NPP during the regular practical training of the operators' teams. An outlook on the 'evaluation system of main control room (MCR) operators' reliability' project, based on simulator data of operators' training is given

  8. Application of forensic image analysis in accident investigations.

    Science.gov (United States)

    Verolme, Ellen; Mieremet, Arjan

    2017-09-01

    Forensic investigations are primarily meant to obtain objective answers that can be used for criminal prosecution. Accident analyses are usually performed to learn from incidents and to prevent similar events from occurring in the future. Although the primary goal may be different, the steps in which information is gathered, interpreted and weighed are similar in both types of investigations, implying that forensic techniques can be of use in accident investigations as well. The use in accident investigations usually means that more information can be obtained from the available information than when used in criminal investigations, since the latter require a higher evidence level. In this paper, we demonstrate the applicability of forensic techniques for accident investigations by presenting a number of cases from one specific field of expertise: image analysis. With the rapid spread of digital devices and new media, a wealth of image material and other digital information has become available for accident investigators. We show that much information can be distilled from footage by using forensic image analysis techniques. These applications show that image analysis provides information that is crucial for obtaining the sequence of events and the two- and three-dimensional geometry of an accident. Since accident investigation focuses primarily on learning from accidents and prevention of future accidents, and less on the blame that is crucial for criminal investigations, the field of application of these forensic tools may be broader than would be the case in purely legal sense. This is an important notion for future accident investigations. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Traffic Accident Investigation: A Suitable Theme for Teaching Mechanics.

    Science.gov (United States)

    Tao, P. K.

    1987-01-01

    Suggests the development of curriculum materials on the applications of physics to traffic accident investigations as a theme for teaching mechanics. Describes several standard investigation techniques and the physics principles involved, along with some sample exercises. (TW)

  10. A Tool for Safety Officers Investigating " simple" Accidents

    DEFF Research Database (Denmark)

    Jørgensen, Kirsten

    2010-01-01

    Most workplace accidents that happen in enterprises are simple and seldom result in serious injuries. Very often these kinds of workplace accidents are not investigated, and if they are, then the investigation is very brief, with comments such as that it was the victim’s own fault or just...... accidents normally caused by apparent banalities occur much more frequently and with a higher rate of fatalities, disablements and other serious injuries than the ostensibly most dangerous kinds of accidents. In 1999 a practical tool for use by safety officers was developed; this tool is based...... on the investigation methods applied in major accidents, but comprises a simpler and more user-friendly presentation. The tool involves three steps: Mapping the facts, analysing the events, and developing preventive solutions. Practical application of the tool has shown that it affords managers and workers...

  11. ACCOUNT OF ROAD CONDITIONS WHILE INVESTIGATING TRAFFIC ACCIDENTS

    Directory of Open Access Journals (Sweden)

    D. D. Selioukov

    2010-01-01

    Full Text Available The paper considers problems on better traffic safety at government, authority, engineering and driver activity levels, account of road conditions while investigating traffic accidents. The paper also provides road defects mentioned in forensic transport examinations of traffic accidents.

  12. An operational centre for managing major chemical industrial accidents.

    Science.gov (United States)

    Kiranoudis, C T; Kourniotis, S P; Christolis, M; Markatos, N C; Zografos, K G; Giannouli, I M; Androutsopoulos, K N; Ziomas, I; Kosmidis, E; Simeonidis, P; Poupkou, N

    2002-01-28

    The most important characteristic of major chemical accidents, from a societal perspective, is their tendency to produce off-site effects. The extent and severity of the accident may significantly affect the population and the environment of the adjacent areas. Following an accident event, effort should be made to limit such effects. Management decisions should be based on rational and quantitative information based on the site specific circumstances and the possible consequences. To produce such information we have developed an operational centre for managing large-scale industrial accidents. Its architecture involves an integrated framework of geographical information system (GIS) and RDBMS technology systems equipped with interactive communication capabilities. The operational centre was developed for Windows 98 platforms, for the region of Thriasion Pedion of West Attica, where the concentration of industrial activity and storage of toxic chemical is immense within areas of high population density. An appropriate case study is given in order to illuminate the use and necessity of the operational centre.

  13. Psychosocial reconstruction inventory : a postdictal instrument in aircraft accident investigation.

    Science.gov (United States)

    1972-01-01

    A new approach to the investigation of aviation accidents has recently been initiated, utilizing a follow-on to the psychological autopsy. This approach, the psychosocial reconstruction inventory, enables the development of a dynamic, retrospective p...

  14. Investigating accidents involving aircraft manufactured from polymer composite materials

    OpenAIRE

    Dunn, Leigh

    2013-01-01

    This thesis looks into the examination of polymer composite wreckage from the perspective of the aircraft accident investigator. It develops an understanding of the process of wreckage examination as well as identifying the potential for visual and macroscopic interpretation of polymer composite aircraft wreckage. The in-field examination of aircraft wreckage, and subsequent interpretations of material failures, can be a significant part of an aircraft accident investigation. ...

  15. Investigating accidents involving aircraft manufactured from polymer composite materials

    Science.gov (United States)

    Dunn, Leigh

    This study looks into the examination of polymer composite wreckage from the perspective of the aircraft accident investigator. It develops an understanding of the process of wreckage examination as well as identifying the potential for visual and macroscopic interpretation of polymer composite aircraft wreckage. The in-field examination of aircraft wreckage, and subsequent interpretations of material failures, can be a significant part of an aircraft accident investigation. As the use of composite materials in aircraft construction increases, the understanding of how macroscopic failure characteristics of composite materials may aid the field investigator is becoming of increasing importance.. The first phase of this research project was to explore how investigation practitioners conduct wreckage examinations. Four accident investigation case studies were examined. The analysis of the case studies provided a framework of the wreckage examination process. Subsequently, a literature survey was conducted to establish the current level of knowledge on the visual and macroscopic interpretation of polymer composite failures. Relevant literature was identified and a compendium of visual and macroscopic characteristics was created. Two full-scale polymer composite wing structures were loaded statically, in an upward bending direction, until each wing structure fractured and separated. The wing structures were subsequently examined for the existence of failure characteristics. The examination revealed that whilst characteristics were present, the fragmentation of the structure destroyed valuable evidence. A hypothetical accident scenario utilising the fractured wing structures was developed, which UK government accident investigators subsequently investigated. This provided refinement to the investigative framework and suggested further guidance on the interpretation of polymer composite failures by accident investigators..

  16. Investigation of the management of the wastes from plant accident

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    The accident in Fukushima Daiichi Nuclear Power Plant discharged large amount of radio-nuclides and contaminated wide areas in and out of the site. The decontamination, storage, treatment and disposal of generated wastes are now under planning. Though regulations for the radioactive wastes arisen from normal operation and decommissioning of nuclear facilities have been prepared, it is necessary to make amendment of those regulations to deal with wastes from the severe accident which may have much different features on nuclides contents, or possible accompanying hazardous chemical materials. Characteristics of wastes from accidents in foreign nuclear installations, and the treatment and the disposal of those wastes were surveyed by literature and radionuclide migration from the assumed temporally storage yards of the disaster debris was analyzed for consideration of future regulation. (author)

  17. Investigations on accidents with massive water ingress exemplified by the pebble bed reactor PNP-500

    International Nuclear Information System (INIS)

    Moormann, R.

    1986-01-01

    A computer code is used for analyses of massive water ingress accidents in the High-Temperature Gas Cooled Reactor concept PNP-500 with pebble bed core. The analyses are mainly focussed on graphite corrosion processes. For the investigated accidents a correct reactor shut down in assumed. The mass of water ingressing into the primary circuit is varied between 1000 and 7500 kg (i.e., up to hypothetical values). The dependence of accident consequences on parameters such as intensity and starting time of the afterheat removal system or kinetic values of the chemical processes is examined. The results show that even under pessimistic assumptions the extent of the graphite corrosion is relatively low; significant damaging of fuel elements or graphite components does not occur. A primary circuit depressurization, combined with local burning of water gas, would probably not affect the fission product retention potential of the (gastight) containment. Summing up, the risk caused by these accidents remains small. (orig.) [de

  18. Chemical Plant Accidents in a Nuclear Hydrogen Generation Scheme

    International Nuclear Information System (INIS)

    Brown, Nicholas R.; Revankar, Shripad T.

    2011-01-01

    A high temperature nuclear reactor (HTR) could be used to drive a steam reformation plant, a coal gasification facility, an electrolysis plant, or a thermochemical hydrogen production cycle. Most thermochemical cycles are purely thermodynamic, and thus achieve high thermodynamic efficiency. HTRs produce large amounts of heat at high temperature (1100 K). Helium-cooled HTRs have many passive, or inherent, safety characteristics. This inherent safety is due to the high design basis limit of the maximum fuel temperature. Due to the severity of a potential release, containment of fission products is the single most important safety issue in any nuclear reactor facility. A HTR coupled to a chemical plant presents a complex system, due primarily to the interactive nature of both plants. Since the chemical plant acts as the heat sink for the nuclear reactor, it important to understand the interaction and feedback between the two systems. Process heat plants and HTRs are generally very different. Some of the major differences include: time constants of plants, safety standards, failure probability, and transient response. While both the chemical plant and the HTR are at advanced stages of testing individually, no serious effort has been made to understand the operation of the integrated system, especially during accident events that are initiated in the chemical plant. There is a significant lack of knowledge base regarding scaling and system integration for large scale process heat plants coupled to HTRs. Consideration of feedback between the two plants during time-dependent scenarios is absent from literature. Additionally, no conceptual studies of the accidents that could occur in either plant and impact the entire coupled system are present in literature

  19. Investigation on accident management measures for VVER-1000 reactors

    International Nuclear Information System (INIS)

    Tusheva, P.; Schaefer, F.; Rohde, U.; Reinke, N.

    2009-01-01

    A consequence of a total loss of AC power supply (station blackout) leading to unavailability of major active safety systems which could not perform their safety functions is that the safety criteria ensuring a secure operation of the nuclear power plant would be violated and a consequent core heat-up with possible core degradation would occur. Currently, a study which examines the thermal-hydraulic behaviour of the plant during the early phase of the scenario is being performed. This paper focuses on the possibilities for delay or mitigation of the accident sequence to progress into a severe one by applying Accident Management Measures (AMM). The strategy 'Primary circuit depressurization' as a basic strategy, which is realized in the management of severe accidents is being investigated. By reducing the load over the vessel under severe accident conditions, prerequisites for maintaining the integrity of the primary circuit are being created. The time-margins for operators' intervention as key issues are being also assessed. The task is accomplished by applying the GRS thermal-hydraulic system code ATHLET. In addition, a comparative analysis of the accident progression for a station blackout event for both a reference German PWR and a reference VVER-1000, taking into account the plant specifics, is being performed. (authors)

  20. An endothermic chemical process facility coupled to a high temperature reactor. Part I: Proposed accident scenarios within the chemical plant

    International Nuclear Information System (INIS)

    Brown, Nicholas R.; Seker, Volkan; Revankar, Shripad T.; Downar, Thomas J.

    2012-01-01

    Highlights: ► The paper identifies possible transient and accident scenarios in a coupled PBMR and thermochemical sulfur cycle based hydrogen plant. ► Key accidents scenarios were investigated through qualitative reasoning. ► The accidents were found to constitute loss of heat sink event for the nuclear reactor. - Abstract: Hydrogen generation using a high temperature nuclear reactor as a thermal driving vector is a promising future option for energy carrier production. In this scheme, the heat from the nuclear reactor drives an endothermic water-splitting plant, via coupling, through an intermediate heat exchanger. Quantitative study of the possible operational or accident events within the coupled plant is largely absent from the literature. In this paper, seven unique case studies are proposed based on a thorough review of possible events. The case studies are: (1) feed flow failure from one section of the chemical plant to another with an accompanying parametric study of the temperature in an individual reaction chamber, (2) product flow failure (recycle) within the chemical plant, (3) rupture or explosion within the chemical plant, (4) nuclear reactor helium inlet overcooling due to a process holding tank failure, (5) helium inlet overcooling as an anticipated transient without emergency nuclear reactor shutdown, (6) total failure of the chemical plant, (7) control rod insertion in the nuclear reactor. The qualitative parameters of each case study are outlined as well as the basis in literature. A previously published modeling scheme is described and adapted for application as a simulation platform for these transient events. The results of the quantitative case studies are described within part II of this paper.

  1. Investigations of Human and Organizational Factors in hazardous vapor accidents

    International Nuclear Information System (INIS)

    Wang Yanfu; Faghih Roohi, Shahrzad; Hu Xiuming; Xie Min

    2011-01-01

    Highlights: → HFACS provides a systematic guideline in accident investigations. The hierarchal structure of HFACS forces investigators to seek out latent HOFs. → Bayesian Network enhances the ability of the HFACS by allowing experts to quantify the degree of relationships among the HOFs. → The fuzzy AHP helps to reduce the subjective biases by avoiding the need to give explicit probability values for the variables' states. - Abstract: This paper presents a model to assess the contribution of Human and Organizational Factor (HOF) to accidents. The proposed model is made up of two phases. The first phase is the qualitative analysis of HOF responsible for accidents, which utilizes Human Factors Analysis and Classification System (HFACS) to seek out latent HOFs. The hierarchy of HOFs identified in the first phase provides inputs for the analysis in the second phase, which is a quantitative analysis using Bayesian Network (BN). BN enhances the ability of HFACS by allowing investigators or domain experts to measure the degree of relationships among the HOFs. In order to estimate the conditional probabilities of BN, fuzzy analytical hierarchy process and decomposition method are applied in the model. Case studies show that the model is capable of seeking out critical latent human and organizational errors and carrying out quantitative analysis of accidents. Thereafter, corresponding safety prevention measures are derived.

  2. NUMERICAL SIMULATION OF TOXIC CHEMICAL DISPERSION AFTER ACCIDENT AT RAILWAY

    Directory of Open Access Journals (Sweden)

    M. M. Biliaiev

    2016-04-01

    Full Text Available Purpose. This research focuses on the development of an applied numerical model to calculate the dynamics of atmospheric pollution in the emission of dangerous chemical substances in the event of transportation by railway. Methodology. For the numerical simulation of transport process of the dangerous chemical substance in the atmosphere the equation of convection-diffusion pollutant transport is used. This equation takes into account the effect of wind, atmospheric diffusion, the power of emission source, as well as the movement of the source of emission (depressurized tank on the process of pollutant dispersion. When carrying out computing experiment one also takes into account the profile of the speed of the wind flow. For the numerical integration of pollutant transport in the atmosphere implicit finite-difference splitting scheme is used. The numerical calculation is divided into four steps of splitting and at each step of splitting the unknown value of the concentration of hazardous substance is determined by the explicit running account scheme. On the basis of the numerical model it was created the code using the algorithmic language FORTRAN. One conducted the computational experiments to assess the level of air pollution near the railway station «Illarionovo» in the event of a possible accident during transportation of ammonia. Findings. The proposed model allows you to quickly calculate the air pollution after the emission of chemically hazardous substance, taking into account the motion of the emission source. The model makes it possible to determine the size of the land surface pollution zones and the amount of pollutants deposited on a specific area. Using the developed numerical model it was estimated the environmental damage near the railway station «Illarionovo». Originality. One can use the numerical model to calculate the size and intensity of the chemical contamination zones after accidents on transport. Practical value

  3. 32 CFR 634.30 - Use of traffic accident investigation report data.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Use of traffic accident investigation report data... § 634.30 Use of traffic accident investigation report data. (a) Data derived from traffic accident... accidents (collision diagram) will be examined. (b) Law enforcement personnel and others who prepare traffic...

  4. Enforcement Alert: EPA Enforcement Efforts Focus on Prevention of Chemical Accidents

    Science.gov (United States)

    This Alert is intended to inform the industry that companies must take responsibility to prevent accidental releases of dangerous chemicals like anhydrous ammonia through compliance with CAA’s Chemical Accident Prevention Program.

  5. Introduction of the Space Shuttle Columbia Accident, Investigation Details, Findings and Crew Survival Investigation Report

    Science.gov (United States)

    Chandler, Michael

    2010-01-01

    As the Space Shuttle Program comes to an end, it is important that the lessons learned from the Columbia accident be captured and understood by those who will be developing future aerospace programs and supporting current programs. Aeromedical lessons learned from the Accident were presented at AsMA in 2005. This Panel will update that information, closeout the lessons learned, provide additional information on the accident and provide suggestions for the future. To set the stage, an overview of the accident is required. The Space Shuttle Columbia was returning to Earth with a crew of seven astronauts on 1Feb, 2003. It disintegrated along a track extending from California to Louisiana and observers along part of the track filmed the breakup of Columbia. Debris was recovered from Littlefield, Texas to Fort Polk, Louisiana, along a 567 statute mile track; the largest ever recorded debris field. The Columbia Accident Investigation Board (CAIB) concluded its investigation in August 2003, and released their findings in a report published in February 2004. NASA recognized the importance of capturing the lessons learned from the loss of Columbia and her crew and the Space Shuttle Program managers commissioned the Spacecraft Crew Survival Integrated Investigation Team (SCSIIT) to accomplish this. Their task was to perform a comprehensive analysis of the accident, focusing on factors and events affecting crew survival, and to develop recommendations for improving crew survival, including the design features, equipment, training and procedures intended to protect the crew. NASA released the Columbia Crew Survival Investigation Report in December 2008. Key personnel have been assembled to give you an overview of the Space Shuttle Columbia accident, the medical response, the medico-legal issues, the SCSIIT findings and recommendations and future NASA flight surgeon spacecraft accident response training. Educational Objectives: Set the stage for the Panel to address the

  6. Accident Investigation and Analysis - a roadmap for organisational learning -

    OpenAIRE

    Jacinto, Celeste

    2016-01-01

    1. Scope & Objective Scope: The investigation of occupational accidents has long been a matter of discussion, mainly among specialists, but its translation into company practice has only registered real growth on the turn of the new millennium, essentially as a natural consequence of the H&S (Health & Safety) emerging management systems. In Europe, the many H&S Directives have also played a central role in this field by bringing about new requirements and creating new needs. This trend has...

  7. Investigation of air cleaning system response to accident conditions

    International Nuclear Information System (INIS)

    Andrae, R.W.; Bolstad, J.W.; Foster, R.D.; Gregory, W.S.; Horak, H.L.; Idar, E.S.; Martin, R.A.; Ricketts, C.I.; Smith, P.R.; Tang, P.K.

    1980-01-01

    Air cleaning system response to the stress of accident conditions are being investigated. A program overview and hghlight recent results of our investigation are presented. The program includes both analytical and experimental investigations. Computer codes for predicting effects of tornados, explosions, fires, and material transport are described. The test facilities used to obtain supportive experimental data to define structural integrity and confinement effectiveness of ventilation system components are described. Examples of experimental results for code verification, blower response to tornado transients, and filter response to tornado and explosion transients are reported

  8. Stable Chemical Dosimeters for Partial Reconstruction of Nuclear Accident Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Dvornik, I.; Zec, U.; Baric, M.; Razem, D. [Ruder Boskovic Nuclear Institute, Zagreb, Yugoslavia (Croatia)

    1969-10-15

    The application of chemical dosimeters, tissue equivalent with respect to gamma rays and neutrons, is proposed for dosimetric topography of the space around nuclear devices in case of accidents. The dosimeters in the form of sealed glass ampoules have sufficient sensitivity and long-term stability and are evaluated or checked directly by conventional spectrophotometry. The sensitivity, expressed as yield per rad, is approximately equal for gamma rays and neutrons. The resolution in both cases is about one rad, and the range is up to several thousand rads. The precision of dosimetry is {+-} 1 rad or {+-} 2%, whichever is higher. In free space and unshielded the dosimeter measures the total rad-absorbed dose delivered by gamma rays and neutrons, i.e. the first collision gamma plus neutron dose. If used on- or in-phantom, especially if several dosimeters are disposed within and around the same phantom, it can give important data about the amount of the neutron component of the dose and about the effective mean energy of incident neutrons. The neutron component of the dose can be directly measured if the gamma dosimeter is used together with the chemical dosimeter. The experiments giving the change of optical density per rad and the radiation chemical yield with respect to the absorbed dose delivered by 14-MeV neutrons are described in detail. The possibility is also mentioned of applying the dosimeter as a very sensitive monitor for thermal neutrons, which is due to the chlorine content of 4.73% and activation to {sup 38}Cl. The opinion is expressed that this dosimeter deserves some attention as a part of future planning and development work on area and personnel accidental dosimetry systems. (author)

  9. The situation of hazardous chemical accidents in China between 2000 and 2006

    Energy Technology Data Exchange (ETDEWEB)

    Duan Weili [Institute of Safety Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong (China); Chen Guohua, E-mail: scut.safetycenter@gmail.com [Institute of Safety Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong (China); Ye Qing; Chen Qingguang [Institute of Safety Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong (China)

    2011-02-28

    From the aspects of the total quantity of accidents, regional inequality, enterprises scale and environmental pollution accidents, this study makes an analysis of hazardous chemical accidents in China for the period spanning from 2000 to 2006. The following results are obtained: firstly, there were lots of accidents and fatalities in hazardous chemical business, i.e., the number of casualty accidents fluctuated between 200 and 600/year, the number of fatality fluctuated between 220 and 1100/year. Secondly, the accident rate in developed southeast coastal areas, e.g., Guangdong, Zhejiang and Jiangsu, was far higher than that in the northwest regions, e.g., Xizang, Xinjiang, and Qinghai. Thirdly, nearly 80% of dangerous chemical accidents had occurred in small and medium-sized enterprises (SMEs). Finally, various sudden environmental pollution accidents resulted from hazardous chemicals were frequent in recent years, causing a huge damage to human and property. Then, based on the readjustment of economic structure in the last decades, the development status of Occupational Health and Safety (OHS) in SMEs and other factors, the paper explores the main causes, which offers valuable insight into measures that should be taken to reduce hazardous chemical accidents.

  10. The situation of hazardous chemical accidents in China between 2000 and 2006

    International Nuclear Information System (INIS)

    Duan Weili; Chen Guohua; Ye Qing; Chen Qingguang

    2011-01-01

    From the aspects of the total quantity of accidents, regional inequality, enterprises scale and environmental pollution accidents, this study makes an analysis of hazardous chemical accidents in China for the period spanning from 2000 to 2006. The following results are obtained: firstly, there were lots of accidents and fatalities in hazardous chemical business, i.e., the number of casualty accidents fluctuated between 200 and 600/year, the number of fatality fluctuated between 220 and 1100/year. Secondly, the accident rate in developed southeast coastal areas, e.g., Guangdong, Zhejiang and Jiangsu, was far higher than that in the northwest regions, e.g., Xizang, Xinjiang, and Qinghai. Thirdly, nearly 80% of dangerous chemical accidents had occurred in small and medium-sized enterprises (SMEs). Finally, various sudden environmental pollution accidents resulted from hazardous chemicals were frequent in recent years, causing a huge damage to human and property. Then, based on the readjustment of economic structure in the last decades, the development status of Occupational Health and Safety (OHS) in SMEs and other factors, the paper explores the main causes, which offers valuable insight into measures that should be taken to reduce hazardous chemical accidents.

  11. [Investigation of emergency capacities for occupational hazard accidents in silicon solar cell producing enterprises].

    Science.gov (United States)

    Yang, D D; Xu, J N; Zhu, B L

    2016-11-20

    Objective: To investigate and analyze the influential factors of occupational hazard acci-dents, emergency facilities and emergency management in Silicon solar cell producing enterprises, then to pro-vide scientific strategies. Methods: The methods of occupationally healthy field investigating, inspecting of ven-tilation effectiveness, setup of emergency program and wearing chemical suit were used. Results: The mainly occupational hazard accidents factors in the process of Silicon solar cell producing included poisoning chemi-cals, high temperature, onizing radiation and some workplaces. The poisoning chemicals included nitric acid, hydrofluoric acid, sulfuric acid, hydrochloric acid, sodium hydroxide, potassium hydroxide, chlorine, phos-phorus oxychloride, phosphorus pentoxide, nitrogen dioxide, ammonia, silane, and so on; the workplaces in-cluded the area of producing battery slides and auxiliary producing area. Among the nine enterprises, gas detec-tors were installed in special gas supplying stations and sites, but the height, location and alarmvalues of gas detectors in six enterprises were not according with standard criteria; emergency shower and eyewash equip-ment were installed in workplaces with strong corrosive chemicals, but the issues of waste water were not solved; ventilation systems were set in the workplaces with ammonia and silane, but not qualified with part lo-cations and parameters in two enterprises; warehouses with materials of acid, alkali, chemical ammonia and phosphorus oxychloride were equipped with positive - pressure air respirator resuscitator and emergency cabi-nets, but with insufficient quantity in seven enterprises and expiration in part of products. The error rate of set-up emergency program and wearing chemical cloth were 30%~100% and 10%~30%, respectively. Among the nine enterprises, there were emergency rescue plans for dangerous chemical accidents, but without profession-al heatstroke and irradiation accident emergency plans

  12. The significance of domino effect in chemical accidents

    OpenAIRE

    Hemmatian, Behrouz; Abdolhamidzadeh, B; Darbra Roman, Rosa Maria; Casal Fàbrega, Joaquim

    2014-01-01

    A historical survey was performed on 330 accidents involving domino effect, occurred in process/storage plants and in the transportation of hazardous materials; only accidents occurred after 1st-January-1961 have been considered. The main features – geographical location, type of accident, materials involved, origin and causes, consequences, domino sequences – were analyzed, with special consideration to the situation in the developing countries and compared to those from other previous surve...

  13. Investigation of Zircaloy-2 oxidation model for SFP accident analysis

    Energy Technology Data Exchange (ETDEWEB)

    Nemoto, Yoshiyuki, E-mail: nemoto.yoshiyuki@jaea.go.jp [Japan Atomic Energy Agency, 2-4 Shirakata, Ohaza, Tokai-mura, Naka-gun, Ibaraki, 319-1195 (Japan); Kaji, Yoshiyuki; Ogawa, Chihiro; Kondo, Keietsu [Japan Atomic Energy Agency, 2-4 Shirakata, Ohaza, Tokai-mura, Naka-gun, Ibaraki, 319-1195 (Japan); Nakashima, Kazuo; Kanazawa, Toru; Tojo, Masayuki [Global Nuclear Fuel – Japan Co., Ltd., 2-3-1, Uchikawa, Yokosuka-shi, Kanagawa, 239-0836 (Japan)

    2017-05-15

    The authors previously conducted thermogravimetric analyses on Zircaloy-2 in air. By using the thermogravimetric data, an oxidation model was constructed in this study so that it can be applied for the modeling of cladding degradation in spent fuel pool (SFP) severe accident condition. For its validation, oxidation tests of long cladding tube were conducted, and computational fluid dynamics analyses using the constructed oxidation model were proceeded to simulate the experiments. In the oxidation tests, high temperature thermal gradient along the cladding axis was applied and air flow rates in testing chamber were controlled to simulate hypothetical SFP accidents. The analytical outputs successfully reproduced the growth of oxide film and porous oxide layer on the claddings in oxidation tests, and validity of the oxidation model was proved. Influence of air flow rate for the oxidation behavior was thought negligible in the conditions investigated in this study. - Highlights: •An oxidation model of Zircaloy-2 in air environment was developed. •The oxidation model was validated by the comparison with oxidation tests using long cladding tubes in hypothetical spent fuel pool accident condition. •The oxidation model successfully reproduced the typical oxidation behavior in air.

  14. Accidents, often the result of an 'uncontrolled business process' - a study in the (Dutch) chemical industry

    NARCIS (Netherlands)

    Sonnemans, P.J.M.; Körvers, P.M.W.; Brombacher, A.C.; Beek, van P.C.; Reinders, J.E.A.

    2003-01-01

    Often companies in the (petro-) chemical industry claim that all possible countermeasures against potential accidents have been taken and therefore accidents are unforeseeable. In this paper we question this statement by analysing the pre-warning signals (precursors) preceding a number of industrial

  15. Hemijski udesi i procena rizika / Chemical accidents and hazard assessment

    Directory of Open Access Journals (Sweden)

    Rade Biočanin

    2004-09-01

    Full Text Available Brojni su udesi vezani za transport i upotrebu hemijskih materija. Ova činjenica je važna i zbog toga što se naša zemlja nalazi na raskrsnici značajnih svetskih komunikacija kojima se ovakvi tereti prevoze. Veliki broj vrsta hemijskih materija može znatno da naruši životnu sredinu za duži period. Ovaj rad, kroz različite parametre, nastoji da prouči takvu mogućnost i ukaže na načine za prevenciju sličnih događaja i zaštitu stanovništva u miru i tokom ratnih dejstava. Ostvarenje projekta jedinstvenog sistema ABHO daje mogućnost da se, korišćenjem savremene opreme za komunikaciju i efikasnih jedinica za brzo reagovanje u realnom vremenu, uspešno obavi monitoring opasnosti, uzbunjivanje, zaštita i dekontaminacija. / There is a growing number of accidents involving hazardous chemical substances during transportation. Serbia and Montenegro are at the crossroads of numerous important European transport links where a lot of such transports pass through. A great number of such substances can considerably damage environment for a very long period of time. This paper studies such events applying different parameters; it tries to point at successful prevention and protection from this threat at peace, as well as during war operations. The realization of the universal and united system of the NBCD of the Army of Serbia and Montenegro, together with modern communication equipment and very effective mobile units, enables on - time reaction and successful monitoring, alarming, protection and decontamination.

  16. Lessons learned from major accidents relating to ageing of chemical plants

    OpenAIRE

    GYENES ZSUZSANNA; WOOD Maureen

    2016-01-01

    Major industrial accidents that occurred in the past and even recently, such as the Flixborough, UK in 1974, the ConocoPhillips, UK in 2001 and the Chevron, US in 2012 show that ageing is still a disturbing phenomenon present in chemical process industries. Further to these cases, it is estimated that 30 % of the major accidents reported in the eMARS accident database run by the Major Accident Hazards Bureau of the European Commission are connected to at least one ageing phenomenon. It is som...

  17. An investigation of construction accidents in Rwanda: Perspectives from Kigali

    OpenAIRE

    Cokeham, M; Tutesigensi, A

    2013-01-01

    The International Labour Organization suggests that measuring accident statistics is the first step in reducing accident numbers. However, many developing countries, especially in sub-Saharan Africa, including Rwanda, do not record accident statistics. In response to this, a questionnaire survey of 130 construction workers was undertaken in Kigali, the capital of the Republic of Rwanda, to raise awareness of construction accidents within the country. The survey generated information about 482...

  18. Response to a Chemical Incident or Accident -- Who Is In Charge?

    National Research Council Canada - National Science Library

    Briggs, Darryl J

    2007-01-01

    .... The thesis of the paper is as follows: Combatant Commanders and the Services must have specific guidance and appropriate authorities to be able to effectively manage a Chemical Accident and Incident Response and Assistance (CAIRA...

  19. Estimation of fatality and injury risk by means of in-depth fatal accident investigation data.

    Science.gov (United States)

    Yannis, George; Papadimitriou, Eleonora; Dupont, Emmanuelle; Martensen, Heike

    2010-10-01

    In this article the factors affecting fatality and injury risk of road users involved in fatal accidents are analyzed by means of in-depth accident investigation data, with emphasis on parameters not extensively explored in previous research. A fatal accident investigation (FAI) database is used, which includes intermediate-level in-depth data for a harmonized representative sample of 1300 fatal accidents in 7 European countries. The FAI database offers improved potential for analysis, because it includes information on a number of variables that are seldom available, complete, or accurately recorded in road accident databases. However, the fact that only fatal accidents are examined requires for methodological adjustments, namely, the correction for two types of effects on a road user's baseline risk: "accident size" effects, and "relative vulnerability" effects. Fatality and injury risk can be then modeled through multilevel logistic regression models, which account for the hierarchical dependences of the road accident process. The results show that the baseline fatality risk of road users involved in fatal accidents decreases with accident size and increases with the vulnerability of the road user. On the contrary, accident size increases nonfatal injury risk of road users involved in fatal accidents. Other significant effects on fatality and injury risk in fatal accidents include road user age, vehicle type, speed limit, the chain of accident events, vehicle maneuver, and safety equipment. In particular, the presence and use of safety equipment such as seat belt, antilock braking system (ABS), and electronic stability program (ESP) are protection factors for car occupants, especially for those seated at the front seats. Although ABS and ESP systems are typically associated with positive effects on accident occurrence, the results of this research revealed significant related effects on accident severity as well. Moreover, accident consequences are more severe

  20. Investigation of Qom Rural Area Water Network Accident in 2010 and Minimization Approaches of Accident Frequencies

    Directory of Open Access Journals (Sweden)

    Hossein Jafari Mansoorian

    2016-02-01

    Full Text Available Background & Aims of the Study : Accidents in water networks can lead to increase the uncounted water, costs of repair, maintenance, restoration and enter water contaminants to water network. The aim of this study is to survey the accidents of Qom rural water network and choose the right approaches to reduce the number of accidents. Materials & Methods: In this cross-sectional study, four sector of Qom province (Markazi, Dastjerd, Kahak and Qahan, were assessed over a period of 8 months (July – January 2010. This study was conducted through questionnaire of Ministry of Energy. Results: The total number of accidents was 763. The highest number of accidents in the four sectors was related to Markazi sector with 228 accidents. According to the time of the accident, the highest and lowest number of accident was related to September (19.7% and November (6.8%, respectively. According to the location of the accident on network, the highest and lowest number of accident was related to distribution network (64% and connections (17.5% and transmission pipe (18.34%, respectively. According to the type of the accident, the highest and lowest number of accident was related to breaking (47.8% and gasket failure (1.2%, respectively. Considering with the pipes’ material, the highest and lowest number of accident was related to polyethylene pipes (93% and steel and cast iron pipes (0.5%, 0.5%, respectively. Conclusions: Due to the high break rate of Polyethylene pipes, it is recommended to be placed in priority of leak detection and rehabilitation.   .

  1. Case examples of chemical plant accidents. What we learn from them?

    International Nuclear Information System (INIS)

    Nakamura, Masayoshi

    2009-01-01

    Lessons learned from the JCO Nuclear Criticality Accident of 30 September 1999 in a uranium conversion test plant in Tokai-mura, Japan, are reviewed by referring some pertinent matters from the official report of this accident to remind of the universal characteristics among possible accidents of chemical plants. The paper discusses the responsibility of the establishment or institution to the demand alternation or request change from the client, how to respond to the proposal arising from the factory floor, and the safety control system of every-day maintenance of the factory which are important to prevent accidents in chemical plants. After explaining a background leading to the JCO accident, the author summarizes the lessons as follows: (1) changeable control system, (2) perfect provision of the manual considering the actual condition, and (3) clarification of the roles each played by the managers and the workers are most necessary and important. (S. Ohno)

  2. Comparison of different methods for work accidents investigation in hospitals: A Portuguese case study.

    Science.gov (United States)

    Nunes, Cláudia; Santos, Joana; da Silva, Manuela Vieira; Lourenço, Irina; Carvalhais, Carlos

    2015-01-01

    The hospital environment has many occupational health risks that predispose healthcare workers to various kinds of work accidents. This study aims to compare different methods for work accidents investigation and to verify their suitability in hospital environment. For this purpose, we selected three types of accidents that were related with needle stick, worker fall and inadequate effort/movement during the mobilization of patients. A total of thirty accidents were analysed with six different work accidents investigation methods. The results showed that organizational factors were the group of causes which had the greatest impact in the three types of work accidents. The methods selected to be compared in this paper are applicable and appropriate for the work accidents investigation in hospitals. However, the Registration, Research and Analysis of Work Accidents method (RIAAT) showed to be an optimal technique to use in this context.

  3. Possibility of the development of a Serbian protection system against chemical accidents

    Directory of Open Access Journals (Sweden)

    Dejan R. Inđić

    2012-10-01

    Full Text Available The paper presents a draft of a system model for responding in case of chemical accidents in accordance with the current legislation regarding the environment protection, the structure and elements of the existing response system in case of chemical accidents, other works dealing with the issue as well as the prospects planned by those responsible for the environmental protection. The paper discuss the possibilities of different institutions and agencies of the Republic of Serbia to engage in specialized methods of cooperation and protection against chemical hazards in accordance with Article X of the Convention on the Prohibition of Chemical Weapons.

  4. Accident investigation practices in Europe--main responses from a recent study of accidents in industry and transport.

    Science.gov (United States)

    Roed-Larsen, Sverre; Valvisto, T; Harms-Ringdahl, L; Kirchsteiger, C

    2004-07-26

    Europe has during recent years been shocked by disasters from natural events and technical breakdowns. The consequences have been comprehensive, measured by lost lives, injuries, and material and environmental damage. ESReDA wanted in 2000--by setting up a special expert group on accident investigation--to clarify the state of art of accident investigation practices and to map the use of thoroughly accident investigation in order to learn lessons from past disasters and prevent new ones. The scope was to cover three sectors in the society: transport, production processes and storage of hazardous materials, and energy production. The main method used was a questionnaire, which was sent in 2001 to about 150 organisations. About 50 replies were analysed. The replies showed great variations but also similarities, among others in definition of accident and incident, the objectives of the investigation team, criteria used to start an investigation, the status of the investigation organisation, the flow of information, the composition of the investigation team, and the use of internal or international procedures or rules. Several methods (in total 14 different methods were mentioned) were used for carrying out accident /incident investigations. Most of the respondents were willing to co-operate in one or another way with ESReDA. Although there are important biases in the material, the results from questionnaire are important inputs to the future work of ESReDA Expert group in this field. 3 safety approaches have been identified.

  5. THE ATMOSPHERE PROTECTION FROM AN ACCIDENT WITH HAZARDOUS CHEMICAL CARGO

    Directory of Open Access Journals (Sweden)

    V. M. Lysniak

    2009-09-01

    Full Text Available The 3D CFD model to simulate the pollutant transfer and the process of neutralization of toxic gas after accidents was developed. The model is based on the transport gradient model. The results of numerical experiments are presented.

  6. Chemical and nuclear emergencies: Interchanging lessons learned from planning and accident experience

    International Nuclear Information System (INIS)

    Adler, V.; Sorensen, J.H.; Rogers, G.O.

    1989-01-01

    Because the goal of emergency preparedness for both chemical and nuclear hazards is to reduce human exposure to hazardous materials, this paper examines the interchange of lessons learned from emergency planning and accident experience in both industries. While the concerns are slightly different, sufficient similarity is found for each to draw implications from the others experience. Principally the chemical industry can learn from the dominant planning experience associated with nuclear power plants, while the nuclear industry can chiefly learn from the chemical industry's accident experience. 23 refs

  7. [Preparation of the database and the homepage on chemical accidents relating to health hazard].

    Science.gov (United States)

    Yamamoto, M; Morita, M; Kaminuma, T

    1998-01-01

    We collected the data on accidents due to chemicals occurred in Japan, and prepared the database. We also set up the World Wide Web homepage containing the explanation on accidents due to chemicals and the retrieval page for the database. We designed the retrieval page so that users can search the data from keywords such as chemicals (e.g. chlorine gas, hydrogen sulfide, pesticides), places (e.g. home, factory, vehicles, tank), causes (e.g. reaction, leakage, exhaust gas) and others (e.g. cleaning, painting, transportation).

  8. Cavity Heating Experiments Supporting Shuttle Columbia Accident Investigation

    Science.gov (United States)

    Everhart, Joel L.; Berger, Karen T.; Bey, Kim S.; Merski, N. Ronald; Wood, William A.

    2011-01-01

    The two-color thermographic phosphor method has been used to map the local heating augmentation of scaled idealized cavities at conditions simulating the windward surface of the Shuttle Orbiter Columbia during flight STS-107. Two experiments initiated in support of the Columbia Accident Investigation were conducted in the Langley 20-Inch Mach 6 Tunnel. Generally, the first test series evaluated open (length-to-depth less than 10) rectangular cavity geometries proposed as possible damage scenarios resulting from foam and ice impact during launch at several discrete locations on the vehicle windward surface, though some closed (length-to-depth greater than 13) geometries were briefly examined. The second test series was designed to parametrically evaluate heating augmentation in closed rectangular cavities. The tests were conducted under laminar cavity entry conditions over a range of local boundary layer edge-flow parameters typical of re-entry. Cavity design parameters were developed using laminar computational predictions, while the experimental boundary layer state conditions were inferred from the heating measurements. An analysis of the aeroheating caused by cavities allowed exclusion of non-breeching damage from the possible loss scenarios being considered during the investigation.

  9. Investigation into information flow during the accident at Three Mile Island

    International Nuclear Information System (INIS)

    1981-01-01

    This report was prepared in response to a request from NRC Chairman Ahearne that directed the Office of Inspection and Enforcement to resume its investigation of information flow during the accident at Three Mile Island (TMI) that occurred on March 28, 1979. This investigation was resumed on March 21, 1980. The transfer of information among individuals, agencies, and personnel from Metropolitan Edison was analyzed to ascertain what knowledge was held by various individuals of the specific events, parameters, and systems during the accident at TMI. Maximum use was made of existing records, and additional interviews were conducted to clarify areas that had not been pursued during earlier investigations. Although the passage of time between the accident and post-accident interviews hampered precise recollections of events and circumstances, the investigation revealed that information was not intentionally withheld during the accident and that the system for effective transfer of information was inadequate during the accident

  10. In-depth investigation of escalator riding accidents in heavy capacity MRT stations.

    Science.gov (United States)

    Chi, Chia-Fen; Chang, Tin-Chang; Tsou, Chi-Lin

    2006-07-01

    In 2000, the accident rate for escalator riding was about 0.815 accidents per million passenger trips through Taipei Metro Rapid Transit (MRT) heavy capacity stations. In order to reduce the probability and severity of escalator riding accidents and enhance the safety of passengers, the Drury and Brill model [Drury, C.G., Brill, M., 1983. Human factors in consumer product accident investigation. Hum. Factors 25 (3), 329-342] for in-depth investigation was adopted to analyze the 194 escalator riding accidents in terms of victim, task, product and environment. Prevention measures have been developed based on the major causes of accidents and other related contributing factors. The results from the analysis indicated that the majority of the escalator riding accidents was caused by passengers' carrying out other tasks (38 cases, including carrying luggage 24 cases, looking after accompany persons 9 cases, and 5 others), loss of balance (26 cases, 13.4%), not holding the handrail (20 cases, 10.3%), unhealthy passengers (18 cases, 9.3%), followed by people struck by other passenger (16 cases, 8.2%). For female passengers aged 15-64 years, their rushing for trains accidents could have been prevented by wearing safer footwear or by appropriate signing being provided indicating the location and traveling direction of escalators. Female passengers aged 65 years and above whose accidents were caused by loss of balance, should be encouraged to take the elevator instead. To prevent entrapment injuries, following a stricter design code can be most effective. Further in-depth accident investigation is suggested to cover the activity of the victim prior to the accident, any involved product, the location of the accident on the escalator, any medical treatment, what went wrong, opinion of the respondent on the causes of the accident, and personal characteristics of the passengers. Also, management must trade off productivity and safety appropriately to prevent "Organizational

  11. Accident Investigation on a Large Construction Project: An Ethnographic Case Study

    OpenAIRE

    Oswald, David; Smith, Simon; Sherratt, Fred

    2015-01-01

    Unsafe acts are believed to account for approximately 80 to 90 percent of accidents. This paper will investigate this issue through exploring the reasoning behind the unsafe acts that resulted in a minor accident on a large construction project (+$1B) in the UK. The study described here, part of a wider PhD project, was undertaken using an ethnographic approach. Participant observation enabled the researcher to be involved in the whole accident investigation process including witness statemen...

  12. Proposal for computer investigation of LMFBR core meltdown accidents

    International Nuclear Information System (INIS)

    Boudreau, J.E.; Harlow, F.H.; Reed, W.H.; Barnes, J.F.

    1974-01-01

    The environmental consequences of an LMFBR accident involving breach of containment are so severe that such accidents must not be allowed to happen. Present methods for analyzing hypothetical core disruptive accidents like a loss of flow with failure to scram cannot show conclusively that such accidents do not lead to a rupture of the pressure vessel. A major deficiency of present methods is their inability to follow large motions of a molten LMFBR core. Such motions may lead to a secondary supercritical configuration with a subsequent energy release that is sufficient to rupture the pressure vessel. The Los Alamos Scientific Laboratory proposes to develop a computer program for describing the dynamics of hypothetical accidents. This computer program will utilize implicit Eulerian fluid dynamics methods coupled with a time-dependent transport theory description of the neutronic behavior. This program will be capable of following core motions until a stable coolable configuration is reached. Survey calculations of reactor accidents with a variety of initiating events will be performed for reactors under current design to assess the safety of such reactors

  13. Guidelines Manual: Post Accident Procedures for Chemicals and Propellants.

    Science.gov (United States)

    1983-01-01

    verification cloud. On the other hand, the risks of materials on-scene. Also, a diaper - associated with evacuation of the sive IR instrument and portable...of direction, cloud cover and solar the 28 chemicals and propellants in this radiation level; study. The Chemical Hazard Slide Rule Is relatively easy

  14. Investigating the Differences of Single-Vehicle and Multivehicle Accident Probability Using Mixed Logit Model

    Directory of Open Access Journals (Sweden)

    Bowen Dong

    2018-01-01

    Full Text Available Road traffic accidents are believed to be associated with not only road geometric feature and traffic characteristic, but also weather condition. To address these safety issues, it is of paramount importance to understand how these factors affect the occurrences of the crashes. Existing studies have suggested that the mechanisms of single-vehicle (SV accidents and multivehicle (MV accidents can be very different. Few studies were conducted to examine the difference of SV and MV accident probability by addressing unobserved heterogeneity at the same time. To investigate the different contributing factors on SV and MV, a mixed logit model is employed using disaggregated data with the response variable categorized as no accidents, SV accidents, and MV accidents. The results indicate that, in addition to speed gap, length of segment, and wet road surfaces which are significant for both SV and MV accidents, most of other variables are significant only for MV accidents. Traffic, road, and surface characteristics are main influence factors of SV and MV accident possibility. Hourly traffic volume, inside shoulder width, and wet road surface are found to produce statistically significant random parameters. Their effects on the possibility of SV and MV accident vary across different road segments.

  15. Accident Journalism and Traffic Safety Education: A Three-Phase Investigation of Accident Reporting in the Canadian Daily Press.

    Science.gov (United States)

    Wilde, Gerald J. S.; Ackersviller, Melody J.

    A study examined the potential for development of a traffic accident-reporting form in the Canadian daily press that strengthens concern for road safety in the general population and enhances knowledge, attitudes, and behavior leading to greater safety. The investigation was conducted on three levels: a content analysis, a readership analysis, and…

  16. Systematic approach for assessment of accident risks in chemical and nuclear processing

    International Nuclear Information System (INIS)

    Senne Junior, Murillo

    2003-07-01

    The industrial accidents which occurred in the last years, particularly in the 80's, contributed a significant way to draw the attention of the government, industry and the society as a whole to the mechanisms for preventing events that could affect people's safety and the environment quality. Techniques and methods extensively used the nuclear, aeronautic and war industries so far were adapted to performing analysis and evaluation of the risks associated to other industrial activities, especially in the petroleum, chemistry and petrochemical areas. The risk analysis in industrial facilities is carried out through the evaluation of the probability or frequency of the accidents and their consequences. However, no systematized methodology that could supply the tools for identifying possible accidents likely to take place in an installation is available in the literature. Neither existing are methodologies for the identification of the models for evaluation of the accidents' consequences nor for the selection of the available techniques for qualitative or quantitative analysis of the possibility of occurrence of the accident being focused. The objective of this work is to develop and implement a methodology for identification of the risks of accidents in chemical and nuclear processing facilities as well as for the evaluation of their consequences on persons. For the development of the methodology, the main possible accidents that could occur in such installations were identified and the qualitative and quantitative techniques available for the identification of the risks and for the evaluation of the consequences of each identified accidents were selected. The use of the methodology was illustrated by applying it in two case examples adapted from the literature, involving accidents with inflammable, explosives, and radioactive materials. The computer code MRA - Methodology for Risk Assessment was developed using DELPHI, version 5.0, with the purpose of systematizing

  17. Investigating hydrogel dosimeter decomposition by chemical methods

    International Nuclear Information System (INIS)

    Jordan, Kevin

    2015-01-01

    The chemical oxidative decomposition of leucocrystal violet micelle hydrogel dosimeters was investigated using the reaction of ferrous ions with hydrogen peroxide or sodium bicarbonate with hydrogen peroxide. The second reaction is more effective at dye decomposition in gelatin hydrogels. Additional chemical analysis is required to determine the decomposition products

  18. Investigation report on causes of radiation underexposure accident at Yamagata University Hospital and Prevention of Similar accident

    International Nuclear Information System (INIS)

    2005-01-01

    The accident in the title was announced on February 18, 2004 by the hospital, which asked its investigation immediately. The group based on 4 academic societies concerned, thereby started investigations of the in-house reports on the accident and of subsequent hospital visit in March, which involved hearing from personnel concerned, physical/technological examinations and clinical evaluation, with respect to the hospital system for radiation treatment, flow of the treatment, accident details, estimation of the actual expose dose and classification of patients. The investigational group found for the actual number of patients underexposed to be 36 (63, in the in-house report) in 1,377. The cause of the accident was thought essentially the input error for the correct power coefficient 1.032 to be a wrong one 1.320 for 15 x 15 cm 4 MV X-ray. The error had been overlooked by the contract operator from the introduction of the treatment planning equipment in 1999. For prevention, setting up of quality assurance (QA) program by the hospital, the user itself, was pointed out necessary. Making the guideline for introducing the new equipment was conceivably an important work of the trader. (N.I.)

  19. Preventing external domino accidents : A framework for enhancing cooperation in the Chemical Process Industry (CPI)

    NARCIS (Netherlands)

    Reniers, G.; Dullaert, W.; Soudan, K.

    2005-01-01

    Empirical research on major accident safety in the second largest chemical cluster worldwide, the Antwerp port area, supports the design of a meta-technical framework for optimizing external domino prevention. First, the majority of Seveso top tier companies have expressed a willingness to cooperate

  20. Aspects Concerning The Rules And The Investigation Of Traffic Accidents As Work Accidents

    Science.gov (United States)

    Tarnu, Lucian Ioan

    2015-07-01

    When Romania joined the European Union, it was imposed that the Romanian legislation in the field of the security and health at work be in line with the European one. The concept of health as it is defined by the International Body of Health, refers to a good physical, mental and social condition. The improvement of the activity of preventing the traffic accidents as work accidents must have as basis the correct and accurate evaluation of risks of getting injured. The goal of the activity of prevention and protection is to ensure the best working conditions, the prevention of accidents and occupational diseases and the adjustment to the scientific and technological progress. In the road transport sector, as in any other sector, it is very important to pay attention to working conditions to ensure a workforce motivated and well qualified. Some features make it a more difficult sector risk management than other sectors. However, if one takes into account how it works in practice this sector and the characteristics of drivers and how they work routinely, risks, dangers and threats can be managed efficiently and with great success.

  1. Investigation of evaluation method for marine radiological impact during an accident

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    In 2012, JNES carried out to investigate the measurement information of radionuclide released to the ocean at Fukushima Daiichi NPP accident, the foreign regulation for marine radiological impact, and the evaluation method for release and diffusion to the ocean at the accident inside and outside Japan. (author)

  2. Dutch in-depth accident investigation: first experiences and analysis results for motorcycles and mopeds

    NARCIS (Netherlands)

    Mooi, H.G.; Galliano, F.

    2001-01-01

    In September 1999 the Dutch Accident Research Team (DART) within TNO Automotive started with the in-depth investigation of traffic accidents. In this paper, the methodology, working procedures and experiences of the team are described and explained in detail. Furthermore, an elaborate description of

  3. Onshore preparedness for hazardous chemical marine vessel accidents: A case study

    Directory of Open Access Journals (Sweden)

    Faisel T. Illiyas

    2016-09-01

    Full Text Available Hazardous and noxious substances (HNS are widely transported in marine vessels to reach every part of the world. Bulk transportation of hazardous chemicals is carried out in tank container–carrying cargo ships or in designed vessels. Ensuring the safety of HNS containers during maritime transportation is critically important as the accidental release of any substance may be lethal to the on-board crew and marine environment. A general assumption in maritime accidents in open ocean is that it will not create any danger to the coastal population. The case study discussed in this article throws light on the dangers latent in maritime HNS accidents. An accident involving an HNS-carrying marine vessel in the Arabian Sea near the coast of Yemen became a safety issue to the coastal people of Kasargod District of Kerala, India. The ship carried more than 4000 containers, which were lost to the sea in the accident. Six HNS tank containers were carried by the waves and shored at the populated coast of Kasargod, more than 650 nautical miles east from the accident spot. The unanticipated sighting of tank containers in the coast and the response of the administration to the incident, the hurdles faced by the district administration in handling the case, the need for engaging national agencies and lessons learned from the incident are discussed in the article. This case study has proven that accidents in the open ocean have the potential to put the coastal areas at risk if the on-board cargo contains hazardous chemicals. Littoral nations, especially those close to the international waterlines, must include hazardous chemical spills to their oil spill contingency plans.

  4. Scoping Study Investigating PWR Instrumentation during a Severe Accident Scenario

    Energy Technology Data Exchange (ETDEWEB)

    Rempe, J. L. [Rempe and Associates, LLC, Idaho Falls, ID (United States); Knudson, D. L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lutz, R. J. [Lutz Nuclear Safety Consultant, LLC, Asheville, NC (United States)

    2015-09-01

    The accidents at the Three Mile Island Unit 2 (TMI-2) and Fukushima Daiichi Units 1, 2, and 3 nuclear power plants demonstrate the critical importance of accurate, relevant, and timely information on the status of reactor systems during a severe accident. These events also highlight the critical importance of understanding and focusing on the key elements of system status information in an environment where operators may be overwhelmed with superfluous and sometimes conflicting data. While progress in these areas has been made since TMI-2, the events at Fukushima suggests that there may still be a potential need to ensure that critical plant information is available to plant operators. Recognizing the significant technical and economic challenges associated with plant modifications, it is important to focus on instrumentation that can address these information critical needs. As part of a program initiated by the Department of Energy, Office of Nuclear Energy (DOE-NE), a scoping effort was initiated to assess critical information needs identified for severe accident management and mitigation in commercial Light Water Reactors (LWRs), to quantify the environment instruments monitoring this data would have to survive, and to identify gaps where predicted environments exceed instrumentation qualification envelop (QE) limits. Results from the Pressurized Water Reactor (PWR) scoping evaluations are documented in this report. The PWR evaluations were limited in this scoping evaluation to quantifying the environmental conditions for an unmitigated Short-Term Station BlackOut (STSBO) sequence in one unit at the Surry nuclear power station. Results were obtained using the MELCOR models developed for the US Nuclear Regulatory Commission (NRC)-sponsored State of the Art Consequence Assessment (SOARCA) program project. Results from this scoping evaluation indicate that some instrumentation identified to provide critical information would be exposed to conditions that

  5. Psychophysiological and other factors affecting human performance in accident prevention and investigation

    International Nuclear Information System (INIS)

    Klinestiver, L.R.

    1980-01-01

    Psychophysiological factors are not uncommon terms in the aviation incident/accident investigation sequence where human error is involved. It is highly suspect that the same psychophysiological factors may also exist in the industrial arena where operator personnel function; but, there is little evidence in literature indicating how management and subordinates cope with these factors to prevent or reduce accidents. It is apparent that human factors psychophysological training is quite evident in the aviation industry. However, while the industrial arena appears to analyze psychophysiological factors in accident investigations, there is little evidence that established training programs exist for supervisors and operator personnel

  6. The Fukushima Daiichi nuclear accident final report of the AESJ investigation committee

    CERN Document Server

    Atomic Energy Society of Japan

    2015-01-01

    The Magnitude 9 Great East Japan Earthquake on March 11, 2011, followed by a massive tsunami struck  TEPCO’s Fukushima Daiichi Nuclear Power Station and triggered an unprecedented core melt/severe accident in Units 1 – 3. The radioactivity release led to the evacuation of local residents, many of whom still have not been able to return to their homes. As a group of nuclear experts, the Atomic Energy Society of Japan established the Investigation Committee on the Nuclear Accident at the Fukushima Daiichi Nuclear Power Station, to investigate and analyze the accident from scientific and technical perspectives for clarifying the underlying and fundamental causes, and to make recommendations. The results of the investigation by the AESJ Investigation Committee has been compiled herewith as the Final Report. Direct contributing factors of the catastrophic nuclear incident at Fukushima Daiichi NPP initiated by an unprecedented massive earthquake/ tsunami – inadequacies in tsunami measures, severe accident ma...

  7. An novel identification method of the environmental risk sources for surface water pollution accidents in chemical industrial parks.

    Science.gov (United States)

    Peng, Jianfeng; Song, Yonghui; Yuan, Peng; Xiao, Shuhu; Han, Lu

    2013-07-01

    The chemical industry is a major source of various pollution accidents. Improving the management level of risk sources for pollution accidents has become an urgent demand for most industrialized countries. In pollution accidents, the released chemicals harm the receptors to some extent depending on their sensitivity or susceptibility. Therefore, identifying the potential risk sources from such a large number of chemical enterprises has become pressingly urgent. Based on the simulation of the whole accident process, a novel and expandable identification method for risk sources causing water pollution accidents is presented. The newly developed approach, by analyzing and stimulating the whole process of a pollution accident between sources and receptors, can be applied to identify risk sources, especially on the nationwide scale. Three major types of losses, such as social, economic and ecological losses, were normalized, analyzed and used for overall consequence modeling. A specific case study area, located in a chemical industry park (CIP) along the Yangtze River in Jiangsu Province, China, was selected to test the potential of the identification method. The results showed that there were four risk sources for pollution accidents in this CIP. Aniline leakage in the HS Chemical Plant would lead to the most serious impact on the surrounding water environment. This potential accident would severely damage the ecosystem up to 3.8 km downstream of Yangtze River, and lead to pollution over a distance stretching to 73.7 km downstream. The proposed method is easily extended to the nationwide identification of potential risk sources.

  8. Challenging the immediate causes: A work accident investigation in an oil refinery using organizational analysis.

    Science.gov (United States)

    Beltran, Sandra Lorena; Vilela, Rodolfo Andrade de Gouveia; de Almeida, Ildeberto Muniz

    2018-01-01

    In many companies, investigations of accidents still blame the victims without exploring deeper causes. Those investigations are reactive and have no learning potential. This paper aims to debate the historical organizational aspects of a company whose policy was incubating an accident. The empirical data are analyzed as part of a qualitative study of an accident that occurred in an oil refinery in Brazil in 2014. To investigate and analyse this case we used one-to-one and group interviews, participant observation, Collective Analyses of Work and a documentary review. The analysis was conducted on the basis of concepts of the Organizational Analysis of the event and the Model for Analysis and Prevention of Work Accidents. The accident had its origin in the interaction of social and organizational factors, among them being: excessively standardized culture, management tools and outcome indicators that give a false sense of safety, the decision to speed up the project, the change of operator to facilitate this outcome and performance management that encourages getting around the usual barriers. The superficial accident analysis conducted by the company that ignored human and organizational factors reinforces the traditional safety culture and favors the occurrence of new accidents.

  9. Accident Management ampersand Risk-Based Compliance With 40 CFR 68 for Chemical Process Facilities

    International Nuclear Information System (INIS)

    O'Kula, K.R.; Taylor, R.P. Jr.; Ashbaugh, S.G.

    1995-01-01

    A risk-based logic model is suggested as an appropriate basis for better predicting accident progression and ensuing source terms to the environment from process upset conditions in complex chemical process facilities. Under emergency conditions, decision-makers may use the Accident Progression Event Tree approach to identify the best countermeasure for minimizing deleterious consequences to receptor groups before the atmospheric release has initiated. It is concluded that the chemical process industry may use this methodology as a supplemental information provider to better comply with the Environmental Protection Agency's proposed 40 CFR 68 Risk Management Program rule. An illustration using a benzene-nitric acid potential interaction demonstrates the value of the logic process. The identification of worst-case releases and planning for emergency response are improved through these methods, at minimum. It also provides a systematic basis for prioritizing facility modifications to correct vulnerabilities

  10. CHEMICAL INVESTIGATION OF THE VOLATILE CONSTITUENTS ...

    African Journals Online (AJOL)

    CHEMICAL INVESTIGATION OF THE VOLATILE CONSTITUENTS OF CLEOME VISCOSA FROM NIGERIA. Gabriel Olatunji, Peter Weyerstahl, Stephen Oguntoye. Abstract. The major volatile constituents of the oils from the integral parts of Cleome viscosa L. from Nigeria have been identified by GC, GC/MS and 1H NMR.

  11. Investigation of alpha experiment by severe accident analysis code SAMPSON

    International Nuclear Information System (INIS)

    Baglietto, Emilio; Ninokata, Hisashi; Naitoh, Masanori

    2006-01-01

    The severe accident analysis code SAMPSON is adopted in this work to evaluate its capability of reproducing the complex gap cooling phenomenon. The ALPHA experiment is adopted for validation, where molten aluminum oxide (Al 2 O 3 ) produced by a thermite reaction is poured into a water filled hemispherical vessel at the ambient pressure of approximately 1.3 MPa. The spreading and cooling of the debris that has relocated into the pressure vessel lower plenum are simulated, including the analysis of the RPV failure. The model included in the core to mimic the water penetration inside the gap is evaluated and improvements are proposed. The importance of the introduction of some mechanistic approach to describe the gap formation and evolution is underlined, where the results show its necessity in order to correctly reproduce the experimental trends. (author)

  12. Authority investigations of the effects of Chernobylsk reactor accident

    International Nuclear Information System (INIS)

    Lun, Katalin; Varga, Gyula; Jung, Jozsef; Di Gleria, Marta

    1988-01-01

    Official activities of the Health Physics Department of the Public Health Administration (KOEJAL), Budapest during and after the Chernobylsk reactor accident comprised the organization of improved environmental control services, the information of the population and the dosimetric control of certain objectives, foodstuffs passed to the institute and of persons returned from the Soviet Union. To determine the outer and inner radiation exposure of the population in Hungary wide-spread in-situ and laboratory measurements were carried out. The surface contamination and the dose rates were determined at different sites. Till the end of 1986 more than 1000 samples including aerosol, fallout, surface and drinking water, soil, plant, milk, milk-product and meat samples were taken and analysed. The institute played an important coordinative role in sampling, sample distribution among other institutes and in the evaluation of the radiation situation of the country. (V.N.) 7 refs.; 7 figs.; 3 tabs

  13. The official report of the Fukushima Nuclear Accident Independent Investigation Commission

    International Nuclear Information System (INIS)

    2012-07-01

    In October 2011, the Act regarding Fukushima Nuclear Accident Independent Investigation Commission was enacted to investigate the Fukushima accident with the authority to request documents and request the legislative branch to use its investigative powers to obtain any necessary documents or evidence required. In December 2011, chairman and nine other members were appointed. After a six-month investigation, Commission had concluded. 'In order to prevent future disasters, fundamental reforms must take place covering both the structure of electric power industry and the structure of related government and regulatory agencies as well as operation processes, for both normal and emergency situations'. Main parts of report consisted of overview, conclusions and recommendations, and six findings; (1) was the accident preventable?, (2) Escalation of the accident, (3) Emergency response to the accident, (4) Spread of the damage, (5) Organizational issues in accident prevention and response and (6) the legal system. Based on the above findings, Commission made seven recommendations regarding (1) Monitoring of the nuclear regulatory body by the National Diet, (2) Reform the crisis management system, (3) Government responsibility for public health and welfare, (4) Monitoring the operators, (5) Criteria for the new regulatory body, (6) Reforming laws related to nuclear energy and (7) Develop a system of independent investigation commissions. National Diet's thorough debate and deliberate on these recommendation was highly encouraged for the future. (T. Tanaka)

  14. Safety and Health Standard 110: Incident/accident reporting and investigation

    Energy Technology Data Exchange (ETDEWEB)

    Sones, K. [West Kootenay Power, BC (Canada)

    1999-10-01

    Incident/accident reporting requirements in effect at West Kootenay Power are discussed. Details provided include definitions of low risk, high risk, and critical events, the incidents to be reported, the nature of the reports, the timelines, the investigation to be undertaken for each type of incident/accident, counselling services available to employees involved in serious incidents, and the procedures to be followed in accidents involving serious injury to non-employees. The emphasis is on the `critical five` high risk events and the procedures relating to them.

  15. Accident investigation related to the use of chainsaw

    Directory of Open Access Journals (Sweden)

    Sirio Rossano Secondo Cividino

    2013-09-01

    Full Text Available Operating in woods might be highly dangerous as it takes place in hard environments because of slopes, uneven ground and the presence of the underwood that may prevent machines and operators from moving. The chainsaw is a widely-used tool in agriculture, in forestry as well as for professional and hobby-related purposes. This article has the aim to highlight the state of injuries both for professional and domestic uses. The research focused on web-based report of news published between 2007 and 2012 about mortal and non-mortal accidents occurred in Italy and involving people who were using a chainsaw. On the whole, 336 cases were collected over a 5-year period. The results of the work are represented by a series of thematic maps related to the causative agent, the age of the injured and the seat of the injury. Furthermore, it is confirmed that the operator’s head is the most exposed area of the body and is often correlated with the death of the operator (death is often due to collision against the chainsaw blade, facial traumas as well sudden contact with parts of the plant. The study shows the dangers of chainsaw. Even workers experts are involved in serious injury and death. The study highlights the needing of looking for technical solutions and specific procedures for training unskilled worker.

  16. Assessment of chemical loadings to Newark Bay, New Jersey from petroleum and hazardous chemical accidents occurring from 1986 to 1991

    International Nuclear Information System (INIS)

    Gunster, D.G.; Bonnevie, N.L.; Gillis, C.A.; Wenning, R.J.

    1993-01-01

    Newark Bay, New Jersey, is particularly vulnerable to ecological damage from accidental petroleum and chemical spills due to the enclosed nature of the bay and the large volume of chemical and petroleum commerce within the region. A review of the New Jersey Department of Environmental Protection and Energy's database of hazardous chemical spills in New Jersey waterways was conducted to determine the frequency and volume of chemical and petroleum spills in Newark Bay and its major tributaries. Accidents reported from 1986 to 1991 were extracted from the database and summarized. The compilation of records indicated that 1400 incidents, resulting in the release of more than 18 million gallons of hazardous materials to the estuary had been reported to state officials. The bulk of the chemicals released to the aquatic environment were petroleum products, specifically No. 2 Fuel Oil (4,636,512 gallons) and No. 6 Fuel Oil (12,600,683 gallons). The majority of the reported incidents occurred in the Arthur Kill and its tributaries. The results indicate that accidental discharge of petroleum and other hazardous chemicals to Newark Bay represents a significant ongoing source of chemical pollution

  17. Use of casual tree method for investigation of incidents and accidents involving radioactive materials

    International Nuclear Information System (INIS)

    Vasconcelos, Vanderley de; Senne Junior, Murillo; Marques, Raissa Oliveira

    2013-01-01

    There are many methodologies used for investigation of accidents to facilitate the search of the factors that cause these events in different areas of industry. These can be called proactive methods, if they are used before the occurrence of the events, or reactive methods that are applied after the occurrence of the incident or accident, and are used as a basis of information to prevent further events. One of these methods is the Causal Tree Method (CTM). The basic idea of this technique is that incidents and accidents result from variations in usual processes. These variations can be related to the individual, the task, the material or the environment. The tree starts with the end event (incident or accident) and works backwards. The facts relating to the end event are used in the construction of the causal tree. The end event is the starting point and only the facts that contributed to the incident or accident should be selected. The analyst has to identify and list the variations and then display them in the analytic tree, showing causal relations. The objective of this paper is to test the application of the CTM method in investigation of incidents and accidents involving radioactive materials, in order to evaluate its efficiency on finding the typical factors causing these events. (author)

  18. Construction of a technique plan repository and evaluation system based on AHP group decision-making for emergency treatment and disposal in chemical pollution accidents

    International Nuclear Information System (INIS)

    Shi, Shenggang; Cao, Jingcan; Feng, Li; Liang, Wenyan; Zhang, Liqiu

    2014-01-01

    Highlights: • Different chemical pollution accidents were simplified using the event tree analysis. • Emergency disposal technique plan repository of chemicals accidents was constructed. • The technique evaluation index system of chemicals accidents disposal was developed. • A combination of group decision and analytical hierarchy process (AHP) was employed. • Group decision introducing similarity and diversity factor was used for data analysis. - Abstract: The environmental pollution resulting from chemical accidents has caused increasingly serious concerns. Therefore, it is very important to be able to determine in advance the appropriate emergency treatment and disposal technology for different types of chemical accidents. However, the formulation of an emergency plan for chemical pollution accidents is considerably difficult due to the substantial uncertainty and complexity of such accidents. This paper explains how the event tree method was used to create 54 different scenarios for chemical pollution accidents, based on the polluted medium, dangerous characteristics and properties of chemicals involved. For each type of chemical accident, feasible emergency treatment and disposal technology schemes were established, considering the areas of pollution source control, pollutant non-proliferation, contaminant elimination and waste disposal. Meanwhile, in order to obtain the optimum emergency disposal technology schemes as soon as the chemical pollution accident occurs from the plan repository, the technique evaluation index system was developed based on group decision-improved analytical hierarchy process (AHP), and has been tested by using a sudden aniline pollution accident that occurred in a river in December 2012

  19. Construction of a technique plan repository and evaluation system based on AHP group decision-making for emergency treatment and disposal in chemical pollution accidents

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Shenggang [College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083 (China); College of Chemistry, Baotou Teachers’ College, Baotou 014030 (China); Cao, Jingcan; Feng, Li; Liang, Wenyan [College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083 (China); Zhang, Liqiu, E-mail: zhangliqiu@163.com [College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083 (China)

    2014-07-15

    Highlights: • Different chemical pollution accidents were simplified using the event tree analysis. • Emergency disposal technique plan repository of chemicals accidents was constructed. • The technique evaluation index system of chemicals accidents disposal was developed. • A combination of group decision and analytical hierarchy process (AHP) was employed. • Group decision introducing similarity and diversity factor was used for data analysis. - Abstract: The environmental pollution resulting from chemical accidents has caused increasingly serious concerns. Therefore, it is very important to be able to determine in advance the appropriate emergency treatment and disposal technology for different types of chemical accidents. However, the formulation of an emergency plan for chemical pollution accidents is considerably difficult due to the substantial uncertainty and complexity of such accidents. This paper explains how the event tree method was used to create 54 different scenarios for chemical pollution accidents, based on the polluted medium, dangerous characteristics and properties of chemicals involved. For each type of chemical accident, feasible emergency treatment and disposal technology schemes were established, considering the areas of pollution source control, pollutant non-proliferation, contaminant elimination and waste disposal. Meanwhile, in order to obtain the optimum emergency disposal technology schemes as soon as the chemical pollution accident occurs from the plan repository, the technique evaluation index system was developed based on group decision-improved analytical hierarchy process (AHP), and has been tested by using a sudden aniline pollution accident that occurred in a river in December 2012.

  20. CFD investigating the air ingress accident for a HTGR simulation of graphite corrosion oxidation

    International Nuclear Information System (INIS)

    Ferng, Y.M.; Chi, C.W.

    2012-01-01

    Highlights: ► A CFD model is proposed to investigate graphite oxidation corrosion in the HTR-10. ► A postulated air ingress accident is assumed in this paper. ► Air ingress flowrate is the predicted result, instead of the preset one. ► O 2 would react with graphite on pebble surface, causing the graphite corrosion. ► No fuel exposure is predicted to be occurred under the air ingress accident. - Abstract: Through a compressible multi-component CFD model, this paper investigates the characteristics of graphite oxidation corrosion in the HTR-10 core under the postulated accident of gas duct rupture. In this accident, air in the steam generator cavity would enter into the core after pressure equilibrium is achieved between the core and the cavity, which is also called as the air ingress accident. Oxygen in the air would react with graphite on pebble surface, subsequently resulting in oxidation corrosion and challenging fuel integrity. In this paper, characteristics of graphite oxidation corrosion during the air ingress accident can be reasonably captured, including distributions of graphite corrosion amount on the different cross-sections, time histories of local corrosion amount at the monitoring points and overall corrosion amount in the core, respectively. Based on the transient simulation results, the corrosion pattern and its corrosion rate would approach to the steady-state conditions as the accident continuously progresses. The total amount of graphite corrosion during a 3-day accident time is predicted to be about 31 kg with the predicted asymptotic corrosion rate. This predicted value is less than that from the previous work of Gao and Shi.

  1. Investigations of touchscreen glasses from mobile phones for retrospective and accident dosimetry

    International Nuclear Information System (INIS)

    Discher, Michael; Bortolin, Emanuela; Woda, Clemens

    2016-01-01

    Touchscreen glasses of mobile phones are sensitive to ionizing radiation and have the potential of usage as an emergency dosimeter for retrospective dosimetry for the purpose of triage after a radiological accident or attack. In this study the TL glow curves and dosimetric properties of touchscreen glasses were studied in detail, such as intrinsic background dose, dose response, reproducibility, optical stability and long-term stability of the TL signal. Preliminary results are additionally presented to minimize the intrinsic background dose by mechanically removing the surface layer of the glass samples. Additionally chemical element analyses of the touchscreen glass samples were carried out to investigate the difference between glass samples which show a TL signal and samples which show neither an intrinsic zero dose signal nor a radiation induced TL signal. An irradiation trial using glass samples stored in the dark demonstrated a successful dose recovery. However, when applying a realistic, external light exposure scenario, dose underestimation was observed, even though samples were pre-bleached prior to measurement. More investigations have to be carried out in the future to solve the challenge of the low optical stability of the TL signal, if touchscreen glasses are to be used as a reliable emergency dosimeter. - Highlights: • Touchscreen glasses are sensitive to ionizing radiation and show suitable dosimetric properties. • Mechanically treated samples demonstrated a significant reduction of the intrinsic zero dose signal. • An irradiation trial showed limitations of the used protocol for strongly bleached samples.

  2. Doses in radiation accidents investigated by chromosome aberration analysis

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Purrott, R.J.; Prosser, J.S.; White, A.D.; Dolphin, G.W.; Reeder, E.J.; Martin, L.C.; Priseman, S.J.; Gray, S.A.

    1979-01-01

    Results from cytogenetic investigations into 63 cases of suspected over-exposure to radiation during 1978 are reviewed. This report is the eighth in an annual series which together contain data on 390 studies. Results from all investigations have been pooled for general analysis. Brief accounts are given, in an appendix, of the circumstances behind the past year's investigations and, where possible, physical estimates of dose have been included for comparison. One case is described in more detail. It concerns a young man who deliberately irradiated himself with several sources of iridium-192 and received a dose of about 1.5 Gy as a fairly uniform whole body exposure. (author)

  3. THE USE OF AVIATION ACCIDENT INVESTIGATION REPORTS AS EVIDENCE IN COURT

    Directory of Open Access Journals (Sweden)

    Sorana POP PĂUN

    2016-05-01

    Full Text Available Air transport is an essential part of the international society, constituting a liaison between people and continents and an important contributor to the world economy and globalization. Aircraft operation has grown in complexity needing for a safety level to be maintained and constantly grown. Along with the development of the aviation industry, the legal system in the aviation field has registered significant challenges, one of them being the claims related to air crashes which are contested. The investigation process of an accident or incident has become not only important for the safety of operations but also to the establishment of legal fault and blame. The article proposes to present the principles of conducting and accident and incident investigation, the value of the report and new developments in relation to the recent case law on the use of the accident investigation report in Court.

  4. Review of the TMI-2 accident evaluation and vessel investigation projects

    Energy Technology Data Exchange (ETDEWEB)

    Ladekarl Thomsen, Knud

    1998-03-01

    The results of the TMI-2 Accident Evaluation Programme and the Vessel Investigation Project have been reviewed as part of a literature study on core meltdown and in-vessel coolability. The emphasis is placed on the late phase melt progression, which is of special relevance to the NKS-sponsored RAK-2.1 project on Severe Accident Phenomenology. The body of the report comprises three main sections, The TMI-2 Accident Scenario, Core Region and Relocation Path Investigations, and Lower Head Investigations. In the final discussion, the lower head gap formation mechanism is explained in terms of thermal contraction and fracturing of the debris crust. This model seems more plausible than the MAAP model based on creep expansion of the lower head. (au) 1 tab., 33 ills., 31 refs.

  5. Doses in radiation accidents investigated by chromosome aberration analysis

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Purrott, R.J.; Prosser, J.S.

    1978-01-01

    Results from cytogenetic investigations into 55 cases of suspected over-exposure to radiation during 1977 are reviewed. This report is the seventh in an annual series (previous results were published in NRPB-R5, R10, R23, R35, R41 and R57) which together contain data on 327 studies. Results from all investigations have been pooled for general analysis. Brief accounts are given in an appendix of the circumstances behind the past year's investigations and, where possible, physical estimates of dose have been included for comparison. Two cases are described in more detail: the first concerned a non-classified worker who put an iridium-192 source in his pocket and took it home; and the second involved the accidental contamination of two people with tritium gas. In a second appendix, the confidence limits on cytogenetic dosimetry for X- and γ-ray over-exposures are given and the derivation of these limits is discussed. (author)

  6. Report of investigation regarding accident in Tomsk reprocessing facilities in Russia

    International Nuclear Information System (INIS)

    1994-01-01

    At 1258 on April 6, 1993, the explosion accident of a welded tank occurred in the military reprocessing facilities in Tomsk, Siberia District, Russia. Japan carried out the investigation of the effect on the environmental radiation in Japan, dispatched the investigation mission to Russia, and explained the way of thinking on securing the safety of Japanese reprocessing plants to local communities. Science and Technology Agency organized the working group for investigating the accident, which exerted efforts to collect the information, analyze and examine it. This report is the summary of its results. The explosion occurred in the tank for adjusting the acid concentration of the solution to be supplied to the solvent extraction shop, and the building was destructed. No one died or was injured. The results of the radioactivity examination are reported. The process of the accident was inferred, and described. The factors that caused the accident were the mixing of organic impurities the use of the diluting liquid containing aromatic hydrocarbon, the contact of nitric acid with organic substances at high temperature, in sufficient agitation at the time of pouring nitric acid and so on. The safety countermeasures in Japanese reprocessing plants and the response by Japan based on the accident are described. (K.I.)

  7. Accident simulation in a chemical process facility at the Savannah River Site

    International Nuclear Information System (INIS)

    Hope, E.P.

    1993-01-01

    The US Department of Energy requires Westinghouse Savannah River Company to safely operate the chemical separations facilities at the Savannah River Site (SRS). As part of the safety analysis program, simulation of a proposed frame waste recovery (FWR) system is needed to determine the possible accident consequences that may affect public safety. This paper details the simulation process for the proposed frame waste recovery process and describes the analytical tools used in order to make estimates of accident consequences. Since the process in question has been operated, historical data and statistics about its operation are available. Software tools have been developed to allow analysis of the frame waste recovery system, including the generation of system specific dose conversion factors for a number of unique situations. Accident scenarios involving spilled liquid material are analyzed and account for the specific floor geometry of the facility. Confinement and filtration systems are considered. Analysis of source terms is a limiting factor which affects the entire evaluation process. In the past, facility source terms were generally constant with occasional variations from established patterns. As new site missions unfold, significant variations in source terms can be expected. The impact of these variations on the safety analysis is discussed

  8. Study on Developments in Accident Investigation Methods: A Survey of the 'State-of-the-Art'

    International Nuclear Information System (INIS)

    Hollnagel, Erik; Speziali, Josephine

    2008-01-01

    The objective of this project was to survey the main accident investigation methods that have been developed since the early or mid-1990s. The motivation was the increasing frequency of accidents that defy explanations in simple terms, for instance cause-effect chains or 'human error'. Whereas the complexity of socio-technical systems is steadily growing across all industrial domains, including nuclear power production, accident investigation methods are only updated when their inability to account for novel types of accidents and incidents becomes inescapable. Accident investigation methods therefore typically lag behind the socio-technological developments by 20 years or more. The project first compiled a set of methods from the recognised scientific literature and in major major research and development programs, excluding methods limited to risk assessment, technological malfunctions, human reliability, and safety management methods. An initial set of 21 methods was further reduced to seven by retaining only prima facie accident investigation methods and avoiding overlapping or highly similar methods. The second step was to develop a set of criteria used to characterise the methods. The starting point was Perrow's description of normal accidents in socio-technical systems, which used the dimensions of coupling, going from loose to tight, and interactions, going from linear to complex. For practical reasons, the second dimension was changed to that of tractability or how easy it is to describe the system, where the sub-criteria are the level of detail, the availability of an articulated model, and the system dynamics. On this basis the seven selected methods were characterised in terms of the systems - or conditions - they could account for, leading to the following four groups: methods suitable for systems that are loosely coupled and tractable, methods suitable for systems that are tightly coupled and tractable, methods suitable for systems that are loosely

  9. Doses in radiation accidents investigated by chromosome aberration analysis

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Purrott, R.J.; Prosser, J.S.; Dolphin, G.W.; Tipper, P.A.; Reeder, E.J.; White, C.M.; Cooper, S.J.; Stephenson, B.D.

    1977-01-01

    Results from cytogenetic investigations into 66 cases of suspected over-exposure to radiation during 1976 are reviewed. This report is the sixth in an annual series which together contain data on 272 studies. Previous results were published in NRPB-R5, R10, R23, R35 and R41. Results from all investigations have been pooled for general analysis. Brief accounts are given in an appendix of the circumstances behind the past year's investigations and, where possible, physical estimates of dose have been included for comparison. A short review is given of the laboratory's recently published dose response data for several energies of neutron radiation. A description is also given of the group's collaboration in an international experiment in which comparisons were made between a variety of dosemeters exposed to a controlled criticality pulse. In a second appendix two experiments are described in which inter- and intra-donor effects on chromosome aberration yields were examined. It was found that differences in dicentric yields were small whereas acentric aberrations were more variable. (author)

  10. Doses in radiation accidents investigated by chromosome aberration analysis

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Purrott, R.J.; Prosser, J.S.; White, A.D.; Hesketh, L.C.; Priseman, S.J.; Lelliot, D.J.; Stimpson, L.W.

    1980-02-01

    The results are reviewed from investigations during 1979 into 82 cases of suspected over-exposure to radiation. Of these 45 were associated with industrial radiography, 11 with one or other of the major nuclear organisations, and 26 with an institution of research, education or health. 83% of the dose estimates were in the range 0.0-0.09 Gy (0-9 rad), and 17% in the range 0.1-0.29 Gy (10-29 rad). These data are compared with data obtained by physical dosimetry, and a brief summary is given of the circumstances of each over-exposure, or suspected over-exposure. (author)

  11. Doses in radiation accidents investigated by chromosome aberration analysis

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Purrott, R.J.; Prosser, J.S.; Lelliott, D.J.; Stimpson, L.D.

    1981-03-01

    The results are reviewed from investigations during 1980 into 68 cases of suspected overexposure to radiation. Of these, 37 were associated with industrial radiography, 11 with one or other of the major nuclear organisations and 20 with an institution of research, education or health. 55 of the dose estimates were in the range 0.0 - 0.09 Gy (0 - 9 rad) 5 in the range 0.1 - 0.29 Gy (10 - 29 rad) and for various reasons in 8 cases no biological assessment of dose was possible. The dose estimate for the case with the highest confirmed overexposure was 0.22 Gy (22 rads). The chromosome data are compared with information obtained from physical dosimetry and a brief summary is given of the circumstances of each case. (author)

  12. Management of evacuation in case of fire accidents in chemical industrial areas

    International Nuclear Information System (INIS)

    Reniers, G.L.L.; Pauwels, N.; Audenaert, A.; Ale, B.J.M.; Soudan, K.

    2007-01-01

    Trade-offs between economic and safety arguments exist in the operation of chemical installations, should knock-on calamities induced by fire accidents occur: a sudden installation shutdown might result in substantial economic losses, but may be needed to ensure safety. Due to the very rare nature of domino effect risks induced decision problems an adequate evacuation decision aid model to be used by plant safety management does, to the best of the authors' knowledge, not exist. This paper develops a tentative approach to calculate the economic gains and/or losses linked to the decision problem whether or not, and when, to evacuate chemical installation(s) threatened by possible domino effect risks. The proposed model is illustrated by a case-study based on empirical data

  13. Experimental investigations on vessel-hole ablation during severe accidents

    International Nuclear Information System (INIS)

    Sehgal, B.R.; Dinh, T.N.; Green, J.A.; Paladino, D.

    1997-12-01

    This report presents experimental results, and subsequent analyses, of scaled reactor pressure vessel (RPV) failure site ablation tests conducted at the Royal Institute of Technology, Division of Nuclear Power Safety (RIT/NPS). The goal of the test program is to reduce the uncertainty level associated with the phase-change-ablation process, and, thus, improve the characterization of the melt discharge loading on the containment. In a series of moderate temperature experiments, the corium melt is simulated by the binary oxide CaO-B 2 O 3 or the binary eutectic and non-eutectic salts NaNO 3 -KNO 3 , while the RPV head steel is represented by a Pb, Sn or metal alloys plate. A complementary set of experiments was conducted at lower temperatures, using water as melt and salted ice as plate material. These experiments scale well to the postulated prototypical conditions. The multidimensional code HAMISA, developed at RIT/NPS, is employed to analyze the experiments with good pre- and post-test predictions. The effects of melt viscosity and crust surface roughness, along with failure site entrance and exit frictional losses on the ablation characteristics are investigated. Theoretical concept was proposed to describe physical mechanisms which govern the vessel-hole ablation process during core melt discharge from RPV. Experimental data obtained from hole ablation tests and separate-effect tests performed at RIT/NPS were used to validate component physical models of the HAMISA code. It is believed that the hole ablation phenomenology is quite well understood. Detailed description of experiments and experimental data, as well as results of analyses are provided in the appendixes

  14. Investigation of evaluation method for marine radiological impact during an accident

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-15

    In 2012, JNES investigated the evaluation method, long-term seawater and marine deposition for release and diffusion to the ocean at the accident, and marine impact assessment code, in Japan and overseas. Also, the foreign regulations for marine radiological impact (direct release to ocean from the facilities and fallout on marine, etc.) were investigated. Furthermore, the index (e.g., intervention level) at emergency control in USA and Europe were investigated. (author)

  15. Investigation of evaluation method for marine radiological impact during an accident

    International Nuclear Information System (INIS)

    2013-01-01

    In 2012, JNES investigated the evaluation method, long-term seawater and marine deposition for release and diffusion to the ocean at the accident, and marine impact assessment code, in Japan and overseas. Also, the foreign regulations for marine radiological impact (direct release to ocean from the facilities and fallout on marine, etc.) were investigated. Furthermore, the index (e.g., intervention level) at emergency control in USA and Europe were investigated. (author)

  16. Assessment of chemical processes for the post-accident decontamination of reactor-coolant systems. Final report

    International Nuclear Information System (INIS)

    Munson, L.F.; Card, C.J.; Divine, J.R.

    1983-02-01

    Previously used chemical decontamination processes and potentially useful new decontamination processes were examined for the usefulness following a reactor accident. Both generic fuel damage accidents and the accident at TMI-2 were considered. A total of fourteen processes were evaluated. Process evaluation included data in the following categories: technical description of the process, recorded past usage, effectiveness, process limitation, safety consideration, and waste management. These data were evaluated, and cost considerations were presented along with a description of the applicability of the process to TMI-2 and development and demonstration needs. Specific recommendations regarding a primary-system decontamination development program to support TMI-2 recovery were also presented

  17. Military Curricula for Vocational and Technical Education. Traffic Management and Accident Investigation, 17-8.

    Science.gov (United States)

    Air Force, Washington, DC.

    This teaching guide and student workbook for a postsecondary level course in traffic management and accident investigation is one of a number of military-developed curriculum packages selected for adaptation to vocational instruction and curriculum development in a civilian setting. Purpose stated for the 132-hour course is to expose students to…

  18. Lateral car collisions : characteristics of lateral car collisions based on SWOV accident investigation.

    NARCIS (Netherlands)

    1979-01-01

    During 1976 and part of 1977 the Dutch institute for road safety research SWOV carried out the field work for an accident study involving passenger cars. The purpose of this crash injury investigation was to evaluate the influence of relevant crash safety factors (like safety belts and head

  19. Investigation and evaluation for environmental impact at Fukushima Daiichi NPP accident

    International Nuclear Information System (INIS)

    2012-01-01

    In 2012, JNES investigated the weather data and the environmental monitoring data and constructed the method to specify contribution of the environmental impact from each plant based on the dose analysis result at Unit 1-3 of Fukushima Daiichi NPP accident. JNES calculated the dose rate in an accident early stage based on analysis of a monitoring data. Moreover, JNES evaluated the dose by additional release of the radioactive material in case of assuming the loss of coolant injection to a nuclear reactor by the request of NISA. (author)

  20. An investigation of the closure problem applied to reactor accident source terms

    International Nuclear Information System (INIS)

    Brearley, I.R.; Nixon, W.; Hayns, M.R.

    1987-01-01

    The closure problem, as considered here, focuses attention on the question of when in current research programmes enough has been learned about the source terms for reactor accident releases. Noting that current research is tending to reduce the estimated magnitude of the aerosol component of atmospheric, accidental releases, several possible criteria for closure are suggested. Moreover, using the reactor accident consequence model CRACUK, the effect of gradually reducing the aerosol release fractions of a pressurized water reactor (PWR2) source term (as defined in the WASH-1400 study) is investigated and the implications of applying the suggested criteria to current source term research discussed. (author)

  1. Investigation of safety measures to severe accident of Fast Breeder Reactor

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-15

    So as to plan the accident management to severe accident of Fast Breeder Reactor (FBR), it is primary important to understand the progression of severe accident (SA) precisely. In this study, it has been aimed to reveal two items that work as keys in the evaluation of SA in sodium cooled FBR. One is the cool-ability of degraded core on the core support plate by sodium natural circulation in the post accident heat removal (PAHR) phase. An obstacle that hinders the smooth heat transfer from fuel debris to coolant is the formation of sodium-uranate by chemical reaction between sodium and fuel. Following the measurement of physical values of sodium-uranate in FY 2011, experiments has been performed to reveal the conditions for sodium-uranate formation on fuel debris in sodium pool simulating the actual situation of the degraded core. The cool-ability of the debris bed was analyzed using the Lipinski 1-D model. Another research performed in this study is the measurement of fission product (cesium and antimony) evaporation rates from FBR fuel as a function of temperature, because presently the fission product evaporation rates data for LWR is also temporarily used for FBR SA analysis. The measurement was performed using the irradiated fuels in the Test Reactor JOYO. (author)

  2. Investigations of radioactivity level variations in Armenia after the Chernobyl accident

    International Nuclear Information System (INIS)

    Nalbandyan, A.

    2006-01-01

    The problem of radioactive pollution of biosphere has been acquiring a special topicality after nuclear weapon testing and NPP-induced accidents that have already brought to global pollution of the Earth with radioactive substances. One of visual examples of regional radioactive pollution is dispersion of emissions all over the territory of Central Europe after the Chernobyl accident, which aftermaths impacted Armenia, as well. Monitoring investigations in the Ararat Valley showed a precise peak of gross radioactivity of atmospheric fallout in 1986 - the year of Chernobyl accident. Gross mean annual radioactivity was established 1783 10 7 Bq/KXm 2 yr. Later, a sharp fall in the activity was observed. Mostly, radioactive fallout consisted of short-lived radionuclides. Measurements for 1986-1987 showed that gross β-radioactivity level in soils amounted to 977-1022 Bq/KXg, repeated measurements in 1991 allowed establishing 640-656 Bq/KXg. A precise indicator of radioactive emissions that reached Armenia after the Chernobyl accident was a short-lived radionuclide 134 Cs (T 1 /2=2.07 yr) identified in soils. Measurements made 2 years later showed half as much decay of 134 Cs, and in some points established were its traces only. 137 Cs/134 Cs ratio in varied 1.4 to 1.8 in atmospheric fallout and 2.1 to 33.4 in soils. Thus, monitoring investigations evidence a regional character of Chernobyl emission dispersion, this being proved by investigations of radioactivity level variations in Armenia, too

  3. Physical and chemical investigations on natural dyes

    Science.gov (United States)

    Acquaviva, S.; D'Anna, E.; de Giorgi, M. L.; Della Patria, A.; Baraldi, P.

    2010-09-01

    Natural dyes have been used extensively in the past for many purposes, such us to colour fibers and to produce inks, watercolours and paints, but their use declined rapidly after the discovery of synthetic colours. Nowadays we witness a renewed interest, as natural dyes are neither toxic nor polluting. In this work, physical and chemical properties of four selected dyes, namely red (Madder), yellow (Weld and Turmeric) and blue (Woad) colours, produced by means of traditional techniques at the Museo dei Colori Naturali (Lamoli, Italy), have been investigated. The chromatic properties have been studied through the reflectance spectroscopy, a non-invasive technique for the characterisation of chromaticity. Reflection spectra both from powders and egg-yolk tempera models have been acquired to provide the typical features of the dyes in the UV-vis spectral range. Moreover, to assess the feasibility of laser cleaning procedures, tempera layers were investigated after irradiation with an excimer laser. Micro Raman spectroscopy, Scanning Electron Microscopy and Energy Dispersive X-Ray analyses have complemented the survey, returning compositional and morphological information as well. Efforts have been made to give scientific feedback to the production processes and to support the research activity in the restoration of the artworks where these dyes were employed.

  4. Depressurization accident analysis of MPBR by PBRSIM with chemical reaction model

    International Nuclear Information System (INIS)

    No, Hee Cheon; Kadak, A. C.

    2002-01-01

    The simple model for natural circulation is implemented into PBR S IM to provide air inlet velocity from the containment air space. For the friction and form loss only the pebble region is considered conservatively modeling laminar flow through a packed bed. For the chemical reaction model of PBR S IM the oxidation rate is determined as the minimum value of three mechanisms estimated at each time step: oxygen mass flow rate entering the bottom of the reflector, oxidation rate by kinetics, and oxygen mass flow rate arriving at the graphite surface by diffusion. Oxygen mass flux arriving at the graphite surface by diffusion is estimated based on energy-mass analogy. Two types of exothermic chemical reaction are considered: (C + zO 2 → xCO + yCO 2 ) and (2CO + O 2 2CO 2 ). The heterogeneous and homogeneous chemical reaction rates by kinetics are determined by INEEL and Bruno correlations, respectively. The instantaneous depressurization accident of MPBR is simulated using PBR S IM with chemical model. The air inlet velocity is initially rapidly dropped within 10 hr and reaches a saturation value of about 1.5cm/s. The oxidation rate by the diffusion process becomes lower than that by the chemical kinetics above 600K. The maximum pebble bed temperatures without and with chemical reaction reach the peak values of 1560 and 1617 .deg. C at 80 hr and 92 hr, respectively. As the averaged temperatures in the bottom reflector and the pebble bed regions increase with time, (C+1/2O2 ->CO) reaction becomes dominant over (C+O 2 →CO 2 ) reaction. Also, the CO generated by (C+1/2O 2 →CO) reaction will be consumed by (2CO+O 2 →2CO 2 ) reaction and the energy homogeneously generated by this CO depletion reaction becomes dominant over the heterogeneous reaction

  5. THE FUNCTION AND PURPOSE OF AIRCRAFT ACCIDENT INVESTIGATION ACCORDING TO THE INTERNATIONAL AIR LAW

    Directory of Open Access Journals (Sweden)

    Atip Latipulhayat

    2015-10-01

    Full Text Available The main objective of an aircraft accident investigation is to find out the most probable causes of such accident. This represents a technical investigation in nature. At the practical level, however, this report is often used as legal evidence before the court. This paper argues that the main purpose of an aircraft acccident investigation is technical in nature and judicial investigation is carried out when the technical investigation found elements of crime that has been alleged as the most probable cause of the accident.   Menurut Konvensi Chicago 1944, tujuan utama suatu investigasi kecelakaan pesawat udara adalah untuk menemukan penyebab terjadinya kecelakaan tersebut. Jadi, investigasi ini bersifat teknis. Namun, laporan investigasi ini seringkali dijadikan alat bukti di pengadilan khususnya apabila faktor kesalahan manusia dianggap sebagai penyebab utama terjadinya kecelakaan tersebut. Investigasi teknis berubah menjadi investigasi yuridis. Tulisan ini berpendapat bahwa hakikat investigasi kecelakaan pesawat udara adalah bersifat teknis dan investigasi yuridis hanya akan dilakukan apabila laporan investigasi teknis menunjukkan adanya elemen kriminal.

  6. An analysis on human factor issues in criticality accident at a uranium processing plant. Investigation on human behavior contributing to the criticality accident. Interim report

    International Nuclear Information System (INIS)

    Sasou, Kuonihide; Goda, Hideki; Hirotsu, Yuko

    1999-01-01

    At 10:30 am, September 30th, 1999, a criticality accident occurred in a conversion building of a uranium processing plant in Tokai, Ibaraki prefecture. 69 people including 3 workers who then worked at the building, 3 fire fighters who dispatched to rescue them were exposed to the radiation. People with a 350 m-radius of the site were recommended to evacuate themselves from the region to a temporarily prepared evacuation center. And about one hundred thousand people within a 10 km-radius were also advised to stay inside of their home. Nuclear Safety Commission's Accident Investigation Committee is investigating causes of this accident and have been revealing that deviation from government-authorized processing method and negligence of its illegal procedure had contributed to the accident. The influence of this accident is expanding not only to the plant operating company, local people but also to Japanese nuclear power policy, the whole nuclear industry in Japan. Especially pervasion of 'Safety Culture' is strongly being required. This report analyses latent factors of some human behavior directly contributing to the criticality accident. It also mentions that 4 critical points on the poor climate for safety in the work place, the inadequate safety management, the unsuitable equipment and the production-biased company's policy are the latent factors of this accident. It also finds that the poor climate and the production-biased policy are the most important factors. It can be said that some people directly or indirectly having caused the accident are the victims of them. (author)

  7. An investigation of awareness on the Fukushima nuclear accident and Radioactive contamination

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Jeong Chul; Song, Young Ju [Dept. of Consumer Safety, Korea Consumer Agency, Eumseong (Korea, Republic of)

    2016-05-15

    The objective of this study was to investigate Korean people's awareness about impact of the Fukushima nuclear power plant accident in Japan and radioactive contamination caused by it. The respondents of the survey were 600 adults who resided in the Seoul metropolitan area. The survey results show that the majority of respondents were concerned about impact of radiation leakage that might have an effect on our environment. They were worried about radioactive contamination of foodstuffs, particularly fishery products and preferred to acquire information through TV(49.8%) or the Internet(31.3%). Meanwhile, respondents mentioned that the information on the Fukushima nuclear accident and radioactive contamination had not been sufficient and they didn't know well about the follow-up measures of the government on the accident. Most respondents answered that information on radioactive contamination levels and safety of foods and environment was most needed. The results of this study could be useful to enhance awareness on radioactivity and improve risk communication on nuclear power plant accidents.

  8. Proposed chemical plant initiated accident scenarios in a sulphur-iodine cycle plant coupled to a pebble bed modular reactor

    International Nuclear Information System (INIS)

    Brown, N.R.; Revankar, S.T.; Seker, V.; Downar, Th.J.

    2010-01-01

    In the sulphur-iodine (S-I) cycle nuclear hydrogen generation scheme the chemical plant acts as the heat sink for the very high temperature nuclear reactor (VHTR). Thus, any accident which occurs in the chemical plant must feedback to the nuclear reactor. There are many different types of accidents which can occur in a chemical plant. These accidents include intra-reactor piping failure, inter-reactor piping failure, reaction chamber failure and heat exchanger failure. Since the chemical plant acts as the heat sink for the nuclear reactor, any of these accidents induce a loss-of-heat-sink accident in the nuclear reactor. In this paper, several chemical plant initiated accident scenarios are presented. The following accident scenarios are proposed: i) failure of the Bunsen chemical reactor; ii) product flow failure from either the H 2 SO 4 decomposition section or HI decomposition section; iii) reactant flow failure from either the H 2 SO 4 decomposition section or HI decomposition section; iv) rupture of a reaction chamber. Qualitative analysis of these accident scenarios indicates that each result in either partial or total loss of heat sink accidents for the nuclear reactor. These scenarios are reduced to two types: i) discharge rate limited accidents; ii) discontinuous reaction chamber accidents. A discharge rate limited rupture of the SO 3 decomposition section of the SI cycle is proposed and modelled. Since SO 3 decomposition occurs in the gaseous phase, critical flow out of the rupture is calculated assuming ideal gas behaviour. The accident scenario is modelled using a fully transient control volume model of the S-I cycle coupled to a THERMIX model of a 268 MW pebble bed modular reactor (PBMR-268) and a point kinetics model. The Bird, Stewart and Lightfoot source model for choked gas flows from a pressurised chamber was utilised as a discharge rate model. A discharge coefficient of 0.62 was assumed. Feedback due to the rupture is observed in the nuclear

  9. The Importance of Bloodstain Pattern Analysis in the Investigation of Road Traffic Accidents: A Case Report

    Directory of Open Access Journals (Sweden)

    Younis M. Albalooshi

    2015-12-01

    Full Text Available Bloodstain pattern analysis has become a field of specialization in Forensic sciences and plays an important role in the reconstruction of events at a crime scene. Research, books, and articles have been published on the analysis and interpretation of bloodstain patterns We present a case study of a road traffic accident in which bloodstain pattern analysis helped us to solve the discrepancy between reports produced by forensic examiners and by the forensic biology department. The case was of a 22-year-old man who died immediately and a 31- year-old woman who survived a road traffic accident. They were both found outside their overturned car and it was impossible to ascertain from initial observations which of the victims was driving the car at the time of the accident. An external examination of the man revealed multiple injuries, and the cause of his death was severe brain injury. The woman survived with a fracture of the forearm, dislocated clavicle bone, and other minor injuries. After initial examination of the car and based on the pattern of injuries the deceased received, forensic examiner concluded that the man was the driving the car at the time of accident. On the other hand, the forensic DNA analysis of bloodstains obtained from the driver's seat matched that of the woman, suggesting that she was the driver. This apparent discrepancy directed the forensic examiner to carry out a bloodstain pattern analysis on the driver's seat. The bloodstain pattern analysis helped resolve the discrepancy and enabled the investigators to identify the driver correctly. This case report emphasizes the importance of bloodstain pattern analysis in the reconstruction of cases involving road traffic accidents.

  10. Investigation into slipping and falling accidents and materials handling in the South African mining industry.

    CSIR Research Space (South Africa)

    Schutte, PC

    2003-03-01

    Full Text Available The objective of this study was to analyze information on slipping and falling accidents and materials handling activities in the South African mining industry. Accident data pertaining to slipping, falling and materials handling accidents...

  11. Emergency Response System for Pollution Accidents in Chemical Industrial Parks, China

    Directory of Open Access Journals (Sweden)

    Weili Duan

    2015-07-01

    Full Text Available In addition to property damage and loss of lives, environment pollution, such as water pollution and air pollution caused by accidents in chemical industrial parks (CIPs is a significant issue in China. An emergency response system (ERS was therefore planned to properly and proactively cope with safety incidents including fire and explosions occurring in the CIPs in this study. Using a scenario analysis, the stages of emergency response were divided into three levels, after introducing the domino effect, and fundamental requirements of ERS design were confirmed. The framework of ERS was composed mainly of a monitoring system, an emergency command center, an action system, and a supporting system. On this basis, six main emergency rescue steps containing alarm receipt, emergency evaluation, launched corresponding emergency plans, emergency rescue actions, emergency recovery, and result evaluation and feedback were determined. Finally, an example from the XiaoHu Chemical Industrial Park (XHCIP was presented to check on the integrality, reliability, and maneuverability of the ERS, and the result of the first emergency drill with this ERS indicated that the developed ERS can reduce delays, improve usage efficiency of resources, and raise emergency rescue efficiency.

  12. Description of Survey Data Regarding the Chemical Repackaging Plant Accident West Helena, Arkansas

    Energy Technology Data Exchange (ETDEWEB)

    Sorensen, J.H.; Vogt, B.M.

    1999-03-01

    Shortly after 1:00 p.m. on Thursday, May 8, 1997, clouds of foul-smelling smoke began pouring from an herbicide and pesticide packaging plant in West Helena, Arkansas. An alert was sounded, employees evacuated, and the West Helena fire department was called. As three firefighters prepared to enter the plant, the chemical compounds exploded, collapsing a solid concrete block wall, and killing all three firefighters. As the odorous smoky cloud drifted away from the plant, authorities ordered residents in a 2-mile area downwind of the plant to evacuate and those in the 2- to 3-mile zone to shelter in place. This study examines and compares the responses to a mail survey of those ordered to evacuate and those told to shelter in place. Among the variables examined are compliance with official orders and perceived warnings, threat perception, time and source of first warning, response times, and behavior characteristics for both populations. The findings indicate that 90% of those that were told to evacuate did so but only 27% of those told to shelter-in-place did so, with 68% opting to evacuate instead. The implications of these findings for emergency managers is that people will likely choose to evacuate when both warnings to evacuate and warnings to shelter are issued to residents in close proximity to each other. The findings on warning times closely resemble other findings from evacuations when chemical accidents occur and route notification is used for warning residents.

  13. The application of FLUENT in simulating outcomes from chlorine leakage accidents in a typical chemical factory.

    Science.gov (United States)

    Li, Jianfeng; Zhang, Bin; Tang, Sichuang; Tong, Ruipeng

    2016-05-01

    For improvements in market competitiveness, old brand chemical enterprises did some expansion and reconstruction on the base of original equipment. Because it is the reconstruction on the basis of the existing production equipment, it is bound to raise problems of reutilization existing in pipelines and equipment. A simplified typical chemical factory was established referring the actual workshop layout. Further, trustable accident scenarios were conducted to reveal the diffusion process. In a larger leakage rate, the chlorine leak-affected area in the downwind became larger a bit, also in a relatively shorter time, lethal scope will become larger quickly, resulting in more threats to the lives and properties in the vicinity of the factories. Further, it is not possible that the heavier-than-air effect of the chlorine will inevitably result in a higher concentration for a lower surface than that of higher surface. Actually at a certain height, a relatively higher monitoring surface has a larger diffusion range and a larger concentration than a relatively lower surface. It can be inferred that within a certain height, chlorine diffusion rate closer to the ground would be slower due to existence of turbulence or the relative resistance on the ground. © The Author(s) 2014.

  14. Investigations of postulated accident sequences for the Fort St. Vrain HTGR

    International Nuclear Information System (INIS)

    Ball, S.J.; Cleveland, J.C.; Conklin, J.C.; Hatta, M.; Sanders, J.P.

    1978-01-01

    The systems analysis capability of the ORNL HTGR Safety analysis research program includes a family of computer codes: an overall plant NSSS simulation (ORTAP), and detailed component codes for investigating core neutronic accidents (CORTAP), shutdown emergency-cooling accidents via a 3-dimensional core model (ORECA), and once-through steam generator transients (BLAST). The component codes can either be run independently or in the overall NSSS code. Verification efforts have consisted primarily of using existing Fort St. Vrain reactor dynamics data to compare against code predictions. Comparisons of core thermal conditions made for reactor scrams from power levels between 30 and 50% showed good agreement. An optimization program was used to rationalize the difference between the predicted and measured refueling region outlet temperatures, and, in general, excellent agreement was attained by adjustment of models and parameters within their uncertainty ranges. However, more work is required to establish a unique and valid set of models

  15. Investigation of the possible effect of the Chernobyl accident on Irish mortality rates

    International Nuclear Information System (INIS)

    Crowley, M.J.; Reville, W.J.

    1989-01-01

    Radioactive fallout from the Chernobyl accident reached Ireland in May 1986 and caused serious concern with regard to its possible effects on health. Reports of a large scale American study claim an almost immediate effect of Chernobyl fallout in terms of increased mortality rates. A study of Irish mortality rates reported a substantial increase in numbers of deaths during the three months immediately post-Chernobyl. The present study investigates whether there is a statistically significant basis for the reported increase in mortality in Ireland. No discernible evidence was found for increased mortality rates in Ireland during 1986, following the Chernobyl accident. The initial report of increased mortality rates was based on provisional mortality registration statistics and not on actual day to day data. (author)

  16. PSB-VVER experimental and analytical investigation of station blackout accident in VVER-1000

    Energy Technology Data Exchange (ETDEWEB)

    Lipatov, I.A.; Kapustin, A.V.; Nikonov, S.M.; Rovnov, A.A.; Basov, A.V. [Electrogorsk Research and Engineering Centre (EREC), Moscow Region (Russian Federation); Elkin, I.V. [NSI RRC, Kurchatov Institute, Moscow (Russian Federation)

    2007-07-01

    In November 2003, an experiment simulating station blackout accident was carried out in the PSB-VVER integral test facility at the Electrogorsk Research and Engineering Centre (Russia). The purpose of the experiment was to provide missing data for code validation as well as to investigate the VVER thermohydraulics in the blackout conditions. The experiment covers a wide range of phenomena relating not only to transients but also to small break loss-of-coolant accidents. The data gained in the test has been used to assess the RELAP5/MOD3.3 code. In this paper, a special attention has been paid to the code assessment regarding the mixture level and entrainment in steam generator secondary side. The analysis of the recorded transient has shown that the calculation of the heat transfer on the secondary side of steam generators is very sensitive to the steam generator nodalization. (authors)

  17. Chemical removal of radionuclides in contaminated spinach derived from the Fukushima nuclear accident

    International Nuclear Information System (INIS)

    Shiba, Kazuhiro; Kitamura, Yoji; Kozaka, Takashi; Uno, Izumi; Miyoshi, Hirokazu; Yanaga, Makoto

    2012-01-01

    We examined a simple and effective removal method for contaminated farm products to ensure the relief of farmers and the security of consumers. Removal of radionuclides from spinach by chemical methods was investigated. The result of chemical removal showed that antioxidant agents removed radionuclides from spinach by 70–80% for 131 I and more than 80% for radiocesium. In particular, ascorbic acid is promising as a safe and versatile option. (author)

  18. Construction of a technique plan repository and evaluation system based on AHP group decision-making for emergency treatment and disposal in chemical pollution accidents.

    Science.gov (United States)

    Shi, Shenggang; Cao, Jingcan; Feng, Li; Liang, Wenyan; Zhang, Liqiu

    2014-07-15

    The environmental pollution resulting from chemical accidents has caused increasingly serious concerns. Therefore, it is very important to be able to determine in advance the appropriate emergency treatment and disposal technology for different types of chemical accidents. However, the formulation of an emergency plan for chemical pollution accidents is considerably difficult due to the substantial uncertainty and complexity of such accidents. This paper explains how the event tree method was used to create 54 different scenarios for chemical pollution accidents, based on the polluted medium, dangerous characteristics and properties of chemicals involved. For each type of chemical accident, feasible emergency treatment and disposal technology schemes were established, considering the areas of pollution source control, pollutant non-proliferation, contaminant elimination and waste disposal. Meanwhile, in order to obtain the optimum emergency disposal technology schemes as soon as the chemical pollution accident occurs from the plan repository, the technique evaluation index system was developed based on group decision-improved analytical hierarchy process (AHP), and has been tested by using a sudden aniline pollution accident that occurred in a river in December 2012. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Description of interview data regarding Pittsburgh and confluence toxic chemical accidents

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, G.O.; Shumpert, B.L.; Sorensen, J.H.

    1990-11-01

    Evacuation is the protective action most often recommended in response to chemical releases in the United States. The appropriateness of a decision to evacuate depends on whether the affected areas can be cleared of residents before it is contaminated by the chemical release. In determining whether an evacuation can be completed in time, emergency officials must consider both technical and behavioral aspects. The technical components can be readily conceived and quantified. In contrast, the behavioral components are much more abstract and more difficult to estimate. This report summarizes the univariate analysis of responses to surveys conducted in two communities where evacuation was recommended following train derailments involving hazardous chemicals. The surveys were designed to identify the actions taken by residents upon receiving the emergency warning; determine when people received the warning, decided to take action, and implemented the action; and ascertain factors that might explain the nature and timing of their actions. The surveys were conducted in the Bloomfield section of Pittsburgh, Pennsylvania, and in the town of Confluence, Pennsylvania. The study confirms that compliance with an emergency warning to evacuate varies and that potentially dangerous delays can be expected. Significant differences were noted, however, in the rate and speed of compliance in the two communities. The surveys provide information on several factors that may be useful in determining the reasons for differences in the responses from the two communities as well as differences among individual respondents. Such factors include the time of day when the accident occurred, where the respondent was at the time, whether the family was together, previous disaster experience, pet ownership, the content of the warning message, and demographic characteristics. 4 refs., 4 figs., 18 tabs.

  20. 49 CFR 837.3 - Published reports, material contained in the public accident investigation dockets, and accident...

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 7 2010-10-01 2010-10-01 false Published reports, material contained in the... OF RECORDS IN LEGAL PROCEEDINGS § 837.3 Published reports, material contained in the public accident... submitted, in writing, to the Public Inquiries Branch. Demands for specific published reports and studies...

  1. Aircraft accident investigation: the decision-making in initial action scenario.

    Science.gov (United States)

    Barreto, Marcia M; Ribeiro, Selma L O

    2012-01-01

    In the complex aeronautical environment, the efforts in terms of operational safety involve the adoption of proactive and reactive measures. The process of investigation begins right after the occurrence of the aeronautical accident, through the initial action. Thus, it is in the crisis scenario, that the person responsible for the initial action makes decisions and gathers the necessary information for the subsequent phases of the investigation process. Within this scenario, which is a natural environment, researches have shown the fragility of rational models of decision making. The theoretical perspective of naturalistic decision making constitutes a breakthrough in the understanding of decision problems demanded by real world. The proposal of this study was to verify if the initial action, after the occurrence of an accident, and the decision-making strategies, used by the investigators responsible for this activity, are characteristic of the naturalistic decision making theoretical approach. To attend the proposed objective a descriptive research was undertaken with a sample of professionals that work in this activity. The data collected through individual interviews were analyzed and the results demonstrated that the initial action environment, which includes restricted time, dynamic conditions, the presence of multiple actors, stress and insufficient information is characteristic of the naturalistic decision making. They also demonstrated that, when the investigators make their decisions, they use their experience and the mental simulation, intuition, improvisation, metaphors and analogues cases, as strategies, all of them related to the naturalistic approach of decision making, in order to satisfy the needs of the situation and reach the objectives of the initial action in the accident scenario.

  2. Theoretical and experimental investigations on the behaviour of iodine during severe accidents: volatile iodine. Final report

    International Nuclear Information System (INIS)

    Funke, F.; Zeh, P.; Greger, G.U.; Hellmann, S.

    1999-01-01

    Analysis of the consequences of severe accidents in nuclear power plants requires knowledge of the behaviour of radionuclides relevant from the radiological viewpoint, especially the iodine. The current modelling of iodine behaviour is not conclusive, owing to insufficiently known data. This project is intended to eliminate some of these data gaps in critical areas. 350 tests on the radiation-induced oxidation of elemental iodine (I 2 ) in the containment atmosphere were performed yielding an extended database. Moreover, irradiation tests were performed on the formation and decomposition of ozone which is a reaction partner for I 2 . The reaction with ozone converts volatile I 2 into non-volatile iodine oxides or iodate. An improved kinetic modelling was developed for the iodine accident code IMPAIR. Now the model is valid also for steam-containing atmospheres and, additionally, considers dose rate and thus the actual ozone concentration. An assessment of the literature concludes that β and γ radiation have no different impact on iodine chemistry and thus do not need to be modelled separately in iodine accident codes. An assessment of the literature shows a partly significant chemical interaction of volatile iodine with aerosols. Since such reactions lead to a faster decrease of volatile iodine at least at high aerosol concentrations, a modelling should be foreseen in the future. In the frame of the international ISP-41 project, calculations to an integral test in the Canadian Radioiodine Test Facility (RTF) were performed with IMPAIR. The existing model of the radiation-induced I 2 formation in the sump in IMPAIR is identified as a weakness requiring future improvement. A theoretical assessment on the iodine chemistry in the droplets of a spray system concludes that a modelling is necessary in case of spraying with fresh water, and that this is already contained in available spray models. During recirculation spraying in an examplary, hypothetical EPR case, no

  3. Psychophysiological and other factors affecting human performance in accident prevention and investigation. [Comparison of aviation with other industries

    Energy Technology Data Exchange (ETDEWEB)

    Klinestiver, L.R.

    1980-01-01

    Psychophysiological factors are not uncommon terms in the aviation incident/accident investigation sequence where human error is involved. It is highly suspect that the same psychophysiological factors may also exist in the industrial arena where operator personnel function; but, there is little evidence in literature indicating how management and subordinates cope with these factors to prevent or reduce accidents. It is apparent that human factors psychophysological training is quite evident in the aviation industry. However, while the industrial arena appears to analyze psychophysiological factors in accident investigations, there is little evidence that established training programs exist for supervisors and operator personnel.

  4. Investigating High School Students' Understanding of Chemical Equilibrium Concepts

    Science.gov (United States)

    Karpudewan, Mageswary; Treagust, David F.; Mocerino, Mauro; Won, Mihye; Chandrasegaran, A. L.

    2015-01-01

    This study investigated the year 12 students' (N = 56) understanding of chemical equilibrium concepts after instruction using two conceptual tests, the "Chemical Equilibrium Conceptual Test 1" ("CECT-1") consisting of nine two-tier multiple-choice items and the "Chemical Equilibrium Conceptual Test 2"…

  5. Using Occupational Safety and Health Administration accident investigations to study patterns in work fatalities.

    Science.gov (United States)

    Mendeloff, J M; Kagey, B T

    1990-11-01

    Investigations of fatalities by the Occupational Safety and Health Administration (OSHA) provide the most detailed available information about traumatic workplace deaths that are potentially related to violations of existing safety standards. Comparison of the number of such deaths investigated by OSHA from 1977 to 1986 with the comparable category of deaths reported to the Bureau of Labor Statistics Survey of Occupational Injuries and Illnesses indicates that the overall magnitudes have been roughly similar. The OSHA data contain more information than other sources and are especially valuable for analyses of fatalities at smaller workplaces. The OSHA data show that death rates decline sharply with establishment size; the inverted "U" pattern for lost workday injury rates is absent. Because accident investigations are conducted as part of an administrative system, the OSHA data can be influenced by changes in administrative policies. Changes over time in the percent of fatalities in which violations of OSHA standards were cited have clearly been influenced by changes in OSHA citation policy and thus do not provide a valid measure of the rate of violation-caused deaths. Realization of the epidemiological value of this data source depends upon a commitment from OSHA to maintain consistency in investigating accidents and to improve its data collection methods.

  6. A “JUST CULTURE”? CONFLICTS OF INTEREST IN THE INVESTIGATION OF AVIATION ACCIDENTS

    Directory of Open Access Journals (Sweden)

    Tomasz BALCERZAK

    2017-03-01

    Full Text Available The sole purpose of air accident investigations should be the prevention of accidents and other incidents in the future, without apportioning blame or liability. A civil aviation safety system is based on feedback and lessons learned from accidents and incidents, while requiring the strict application of rules on confidentiality in order to ensure the availability of valuable sources of information in the future. Therefore, related data, especially sensitive safety information, should be protected in an appropriate manner. Information provided by an individual in the framework of a safety investigation should not be used against them, in full respect of constitutional principles, and national and international law. Each “involved person” who knows about an accident or serious incident should promptly notify the competent state authority for carrying out an investigation of the event. “Involved person” refers to one of the following: the owner; a member of the crew; the operator of the aircraft involved in an accident or serious incident; any person involved in the maintenance, design, manufacture of that aircraft or in the training of its crew; any person involved in air traffic control, providing flight information or providing airport services, which provided services for the aircraft concerned; staff of the national civil aviation authority; or staff of the European Aviation Safety Agency. In terms of the protection level of the organization (employer, employees who report an event or submit an application to the investigation cannot bear any prejudice from their employer because of information provided by the applicant. The protection does not cover (exclusions: infringement with wilful misconduct (direct intent, recklessness infringement; infringement committed by a clear and serious disregard of the obvious risks; and serious professional negligence, i.e., the failure to provide unquestionably duty of care required under the

  7. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 4 – Integrated chemical effects testing

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Amir; LaBrier, Daniel [Department of Nuclear Engineering, University of New Mexico (United States); Blandford, Edward, E-mail: edb@unm.edu [Department of Nuclear Engineering, University of New Mexico (United States); Howe, Kerry [Department of Civil Engineering, University of New Mexico (United States)

    2016-04-15

    Highlights: • Integrated test explored the material release of a postulated large break LOCA. • Aluminum concentration was very low (<0.1 mg/L) throughout the test duration. • Zinc concentration was low (<1 mg/L) in TSP-buffered system. • Calcium release showed two distinguished release zones: prompt and meta-stable. • Copper and iron has no distinguishable concentration up to first 24 h of testing. - Abstract: This paper presents the results of an integrated chemical effects experiment executed under conditions representative of the containment pool following a postulated loss of coolant accident (LOCA) at the Vogtle nuclear power plant, operated by the Southern Nuclear Operating Company (SNOC). This test was conducted for closure of a series of bench scale experiments conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of aluminum (Howe et al., 2015) and zinc (Pease et al., 2015) from metallic surfaces, and calcium from NUKON fiberglass insulation (Olson et al., 2015) . The integrated test was performed in the Corrosion/Chemical Head Loss Experimental (CHLE) facility with representative amounts of zinc, aluminum, carbon steel, copper, NUKON fiberglass, and latent debris. The test was conducted using borated TSP-buffered solution under a post-LOCA prototypical temperature profile lasting for 30 days. The results presented in this article demonstrate trends for zinc, aluminum, and calcium release that are consistent with separate bench scale testing and previous integrated tests under TSP conditions. The release rate and maximum concentrations of the released materials were slightly different than the separate effect testing as a result of different experimental conditions (temperature, surface area-to-water volume ratio) and/or the presence of other metals and chemicals in the integrated test. Samples of metal coupons and fiberglass were selected for analysis using Scanning Electron Microscopy

  8. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 4 – Integrated chemical effects testing

    International Nuclear Information System (INIS)

    Ali, Amir; LaBrier, Daniel; Blandford, Edward; Howe, Kerry

    2016-01-01

    Highlights: • Integrated test explored the material release of a postulated large break LOCA. • Aluminum concentration was very low (<0.1 mg/L) throughout the test duration. • Zinc concentration was low (<1 mg/L) in TSP-buffered system. • Calcium release showed two distinguished release zones: prompt and meta-stable. • Copper and iron has no distinguishable concentration up to first 24 h of testing. - Abstract: This paper presents the results of an integrated chemical effects experiment executed under conditions representative of the containment pool following a postulated loss of coolant accident (LOCA) at the Vogtle nuclear power plant, operated by the Southern Nuclear Operating Company (SNOC). This test was conducted for closure of a series of bench scale experiments conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of aluminum (Howe et al., 2015) and zinc (Pease et al., 2015) from metallic surfaces, and calcium from NUKON fiberglass insulation (Olson et al., 2015) . The integrated test was performed in the Corrosion/Chemical Head Loss Experimental (CHLE) facility with representative amounts of zinc, aluminum, carbon steel, copper, NUKON fiberglass, and latent debris. The test was conducted using borated TSP-buffered solution under a post-LOCA prototypical temperature profile lasting for 30 days. The results presented in this article demonstrate trends for zinc, aluminum, and calcium release that are consistent with separate bench scale testing and previous integrated tests under TSP conditions. The release rate and maximum concentrations of the released materials were slightly different than the separate effect testing as a result of different experimental conditions (temperature, surface area-to-water volume ratio) and/or the presence of other metals and chemicals in the integrated test. Samples of metal coupons and fiberglass were selected for analysis using Scanning Electron Microscopy

  9. Investigation of the behavior of TMI-2 containment structure for hydrogen burn accidents

    International Nuclear Information System (INIS)

    Kamil, H.; Chen, M.C.; Kost, G.; Miller, A.

    1981-01-01

    The paper describes the following main tasks performed as part of this investigation: 1) definition of design; 2) identification of conservatisms in design; 3) review of load functions; 4) determination of preliminary capacity of the containment. The basic design criteria, acceptance criteria, and analytical procedures which formed the basis of the original containment design were first briefly reviewed. The conservatisms in the various assumptions and parameters used in the design and analysis of the containment were then identified. The postulated load functions for hydrogen burn accidents used in the evaluation of the containment capacity were then reviewed. (orig./HP)

  10. Status of ANL out-of-pile investigations of severe accident phenomena for liquid metal reactors

    International Nuclear Information System (INIS)

    Spencer, B.W.; Marchaterre, J.F.; Anderson, R.P.

    1986-01-01

    Research addressing LMFBR whole core accidents has been terminated, and there is now emphasis on quantifying reactivity feedbacks, and in particular enhancing negative feedback, so that advanced LMR designs will provide inherently safe operation. The status of recent HCDA-related laboratory research performed at ANL, up to the time that such activities were no longer needed to support CRBR licensing, is described. Included are descriptions of programs addressing sodium channel voiding, fuel sweepout, fuel dispersal and plugging, boiled-up pool, UO 2 /sodium FCI, and debris coolability. Descriptions of recent investigations involving the metal fuel/sodium system are also included

  11. Investigation of primary-to-secondary leakage accident on the PSB-VVER integral test facility

    International Nuclear Information System (INIS)

    Lipatov, I.A.; Dremin, G.I.; Galtchanskaya, S.A.; Chmal, I.I.; Moloshnikov, A.S.; Gorbunov, Y.S.; Antonova, A.I.; Elkin, I.V.

    2001-01-01

    the core residual heat by opening the ADS in one of the intact loop. The results show that AM-procedure related to the accident investigated is adequate to prevent core overheating. (authors)

  12. Investigation of primary-to-secondary leakage accident on the PSB-VVER integral test facility

    Energy Technology Data Exchange (ETDEWEB)

    Lipatov, I.A.; Dremin, G.I.; Galtchanskaya, S.A.; Chmal, I.I.; Moloshnikov, A.S.; Gorbunov, Y.S.; Antonova, A.I. [Electrogorsk Research and Engineering Center, EREC, Moscow (Russian Federation); Elkin, I.V. [RRC ' ' Kurchatov Institute, Moscow (Russian Federation)

    2001-07-01

    and begins to remove the core residual heat by opening the ADS in one of the intact loop. The results show that AM-procedure related to the accident investigated is adequate to prevent core overheating. (authors)

  13. Analysis of Waste Leak and Toxic Chemical Release Accidents from Waste Feed Delivery (WFD) Diluent System

    Energy Technology Data Exchange (ETDEWEB)

    WILLIAMS, J.C.

    2000-09-15

    Radiological and toxicological consequences are calculated for 4 postulated accidents involving the Waste Feed Delivery (WFD) diluent addition systems. Consequences for the onsite and offsite receptor are calculated. This analysis contains technical information used to determine the accident consequences for the River Protection Project (RPP) Final Safety Analysis Report (FSAR).

  14. Analysis of Waste Leak and Toxic Chemical Release Accidents from Waste Feed Delivery (WFD) Diluent System

    International Nuclear Information System (INIS)

    WILLIAMS, J.C.

    2000-01-01

    Radiological and toxicological consequences are calculated for 4 postulated accidents involving the Waste Feed Delivery (WFD) diluent addition systems. Consequences for the onsite and offsite receptor are calculated. This analysis contains technical information used to determine the accident consequences for the River Protection Project (RPP) Final Safety Analysis Report (FSAR)

  15. Investigation on the health effects and radioactive contamination after the Chernobyl accident

    International Nuclear Information System (INIS)

    Nagataki, Shigenobu; Yokoyama, Naokata

    1996-01-01

    In the screening of the thyroid diseases in the radiation cohort, it is essential to make correct diagnosis, to measure radiation dose in every subjects and to analyze the dose response relationship by the most appropriate statistical method. Based on experiences of atomic bomb survivors in Nagasaki, children around Chernobyl area were examined. In the Chernobyl accident, various investigations were supported by many international organizations and groups in the world. More than 80,000 children were screened in 5 diagnostic centers; Klincy in Russia, Mogilev and Gomel in Beralus and Kiev and Korosten in Ukraine. Children with thyroid cancer confirmed by histology were 2 in Mogilev. 19 in Gomel, 6 in Kiev, 5 in Korosten and 4 in Klincy until the end of 1994. The prevalence of thyroid cancer was remarkably high (lowest 100 and highest 1,000/million children), compared to the other parts of the world (0.2 to 5/millions/year). However, there was no dose response relationship between the prevalence of thyroid diseases and whole body 137 Cs radioactivity or the soil 137 Cs radio contaminated levels. Although a significant correlation between thyroid cancer and reconstructed thyroid 131 I dose was presented, there are no previous reports to prove that 131 I produces thyroid cancer in human. It is concluded about childhood thyroid cancer around Chernobyl that; it is confirmed that there are many children with thyroid cancer in Belarus, Ukraine and Russia and its diagnosis is correct. The increases of the incidence of thyroid cancer after the Chernobyl accident is probable confirmed. It is suspected but no confirmed that cause of thyroid cancer is the radioactive fallout of Chernobyl accident. Investigation on internal radiation and short lived isotopes along with 131 I may be important to elucidate the cause of thyroid cancer. (K.H.)

  16. Aviation safety and maintenance under major organizational changes, investigating non-existing accidents.

    Science.gov (United States)

    Herrera, Ivonne A; Nordskag, Arve O; Myhre, Grete; Halvorsen, Kåre

    2009-11-01

    The objective of this paper is to discuss the following questions: Do concurrent organizational changes have a direct impact on aviation maintenance and safety, if so, how can this be measured? These questions were part of the investigation carried out by the Accident Investigation Board, Norway (AIBN). The AIBN investigated whether Norwegian aviation safety had been affected due to major organizational changes between 2000 and 2004. The main concern was the reduction in safety margins and its consequences. This paper presents a summary of the techniques used and explains how they were applied in three airlines and by two offshore helicopter operators. The paper also discusses the development of safety related indicators in the aviation industry. In addition, there is a summary of the lessons learned and safety recommendations. The Norwegian Ministry of Transport has required all players in the aviation industry to follow up the findings and recommendations of the AIBN study.

  17. Accident investigation of construction sites in Qom city using Pareto chart (2009-2012

    Directory of Open Access Journals (Sweden)

    M. H. Beheshti

    2015-07-01

    .Conclusions: Employing Pareto charts as a method for analyzing and identification of accident causes can have an effective role in the management of work-related accidents, proper allocation of funds and time.

  18. Investigate the causes of transport and tramming accidents on coal mines.

    CSIR Research Space (South Africa)

    Rushworth, AM

    1999-03-01

    Full Text Available Transport and tramming accidents on coal mines in South Africa are a major component in the overall pattern of colliery accidents. Furthermore, there is now a widespread acceptance that human error is a common cause of failure in accident patterns...

  19. Fukushima nuclear accident independent investigation commission by the National Diet of Japan

    International Nuclear Information System (INIS)

    Kurokawa, Kiyoshi

    2013-01-01

    After the Fukushima nuclear accident, Independent Investigation Commission (IIC) was firstly established in constitutional government by the National Diet of Japan. This article described recognition of its necessity, its setup process, its framework with start from almost zero and about 6 months period and time, its basic way to proceed investigation and several obstacles and hardships, significance of openness to the public, web's communication and simultaneous interpretation (transparency) and basic philosophy of the report. Further significance of Diet's IIC in the democratic system and evaluation of the report were added. As a problem of separation of three powers in Japan, specific recommendations to the legislation of IIC and their future evaluation, nation's governance system problem and social responsibility of scientists and others were also discussed. If Japan were not to be changed after the disaster, Japanese future might be unreliable. (T. Tanaka)

  20. Chemical investigation of Titan and Triton tholins

    Science.gov (United States)

    Mcdonald, Gene D.; Thompson, W. R.; Heinrich, Michael; Khare, Bishun N.; Sagan, Carl

    1994-01-01

    We report chromatographic and spectroscopic analyses of both Titan and Triton tholins, organic solids made from the plasma irradiation of 0.9:0.1 and 0.999:0.001 N2/CH4 gas mixtures, respectively. The lower CH4 mixing ratio leads to a nitrogen-richer tholin (N/C greater than 1), probably including nitrogen heterocyclic compounds. Unlike Titan tholin, bulk Triton tholin is poor in nitriles. From high-pressure liquid chromatography, ultraviolet and infrared spectroscopy, and molecular weight estimation by gel filtration chromatography, we conclude that (1) several H2O-soluble fractions, each with distinct UV and IR spectral signatures, are present, (2) these fractions are not identical in the two tholins, (3) the H2O-soluble fractions of Titan tholins do not contain significant amounts of nitriles, despite the major role of nitriles in bulk Titan tholin, and (4) the H2O-soluble fractions of both tholins are mainly molcules containing about 10 to 50 (C + N) atoms. We report yields of amino acids upon hydrolysis of Titan and Triton tholins. Titan tholin is largely insoluble in the putative hydrocarbon lakes or oceans on Titan, but can yield the H2O-soluble species investigated here upon contact with transient (e.g., impact-generated) liquid water.

  1. Chemical investigations related to some environmental pollutants

    International Nuclear Information System (INIS)

    El-Sofany, E.A.

    1997-01-01

    Pesticides represent one the environmental pollutants. The determination of these pesticides in water and soil samples are of major importance. In the fist part of the present work, the assessment and optimization of the determination of certain pesticides by High performance liquid chromatography HPLC and Gas chromatography GC were investigated. When using HPLC, two eluent were used ACN: H 2 O and MeOH: H 2 O with two systems; isocreatic and gradient elution's. The optimum conditions for the measurements of Bromoxynil, Cypermethrin, methomyl, Dimethoat, carbofuran, simazine are gradient elution at a timetable of wavelengths. With GC measurements the ECD detector was found to be the best one for the working pesticides and at oven temperature from 100-160 degree C at range 20 deg./ min. and second rate from 160-280 degree C with rate 4 deg./min. at final time 20 min. The second part is the application of the optimised method on surface water samples from El-manzala lake three pesticides are present; simazine, atrazine and carbofuran. The third part of this work is the treatment of the contaminated water samples using economic adsorbents such as animal bones pyrolysis residue, apricot stone shell, Sm-4 and Sm-7. By using animal bones pyrolysis residue 100% of carbofuran and 60% of simazine and atrazine were removed from solutions at concentration 1 mg/L. 26 tabs., 28 figs., 61 refs

  2. Radioactive particles revealed by electron microscopy. Chemical and physical properties of radioactive particles in aerosol samples emitted during the early stage of Fukushima Dai-ichi Nuclear Power Plant accident

    International Nuclear Information System (INIS)

    Adachi, Kouji

    2015-01-01

    Water-insoluble radioactive materials emitted during an early stage of the Fukushima Dai-ichi Nuclear Power Plant accident in 2011 were identified, and their chemical and physical properties were characterized as particulate matters. In this report, studies on radioactive particles collected from filter samples in Tsukuba on March 14–15, 2011 are summarized. Their compositions, chemical states, sizes, shapes, crystallinity, and hygroscopicity were analyzed using microscopic analyses such as electron microscopy and synchrotron with a micro-beam. The results indicate that they include Cs, Fe, and Zn as well as elements from fission products and are water insoluble, spherical-glassy particles with ca. 2 micrometer in size. Understanding of their detailed properties is significant to improve the numerical models during the accident and to understand their occurrences in soil as well as the accident itself. In addition to the water-insoluble radioactive materials, water-soluble radioactive materials, which were likely emitted in different events during the accident, should be investigated to have comprehensive understanding of the accident and its environmental effects. More samples from various environments such as soil will be needed, and more detailed chemical and physical analyses will help to understand their formation process, influences on human health, and long term decrements in ambient conditions. (author)

  3. RMP Guidance for Chemical Distributors - Chapter 3: Five-Year Accident History

    Science.gov (United States)

    A five year accident history must be completed for each covered process, and all accidental release events meeting specified criteria must be reported in the Risk Management Plan (RMP) for that process.

  4. Investigation of a fatal airplane crash: autopsy, computed tomography, and injury pattern analysis used to determine who was steering the plane at time of accident. A case report

    DEFF Research Database (Denmark)

    Høyer, Christian Bjerre; Nielsen, Trine Skov; Nagel, Lise Loft

    2012-01-01

    A fatal accident is reported in which a small single-engine light airplane crashed. The airplane carried two persons in the front seats, both of whom possessed valid pilot certificates. Both victims were subject to autopsy, including post-mortem computed tomography scanning (PMCT) prior...... to the autopsy. The autopsies showed massive destruction to the bodies of the two victims but did not identify any signs of acute or chronic medical conditions that could explain loss of control of the airplane. PMCT, histological examination, and forensic chemical analysis also failed to identify an explanation...... for the crash. A detailed review of an airplane identical to the crashed airplane was performed in collaboration with the Danish Accident Investigation Board and the Danish National Police, National Centre of Forensic Services. The injuries were described using the abbreviated injury scale, the injury severity...

  5. Investigations on the Chemical Degradation of Silver Gelatine Prints

    OpenAIRE

    Maha Ahmed ALI; Mona Fouad ALI; Mohammed Osama SAKER; Abdel Azez El Bayoumi ABDEL ALEEM; Khaled Ibrahim EL NAGAR

    2012-01-01

    Photographs are considered composite objects with complex chemical and physical structures. Therefore they are more prone to damage as compared to other objects. Chemical degradation is by far the most common decay form found among photographic collections. This study investigates the chemical degradation of silver gelatin prints (DOP) and the reaction of the image, silver, gelatin, and paper to accelerated aging, to the action of light, and oxidizing gases, in terms of their physical and che...

  6. Investigation of relationship between mental workload and information flow rate of accident diagnosis tasks in NPPs

    International Nuclear Information System (INIS)

    Ha, Chang Hoon

    2005-02-01

    The objective of this study is to investigate experimentally the relationship between an operator's mental workload and the information flow rate of accident diagnosis tasks and further to propose the information flow rate as an analytic method for measuring the mental workload. There are two types of mental workload in the advanced MCR of NPPs: the information processing workload, which is the processing that the human operator must actually perform in order to complete the diagnosis task, and emotional stress workload experienced by the operator. In this study, the focus is on the former. Three kinds of methods are used to measure the operator's workload: information flow rate, subjective methods, and physiological measures. Information flows for eight accident diagnosis tasks are modeled qualitatively using a stage model and are quantified using Conant's model. The eight accident cases are considered here are: Loss Of Coolant Accident (LOCA), Steam Generator Tube Rupture (SGTR), Steam Line Break (SLB), Feedwater Line Break (FLB), Pressurizer (PZR) spray and heater failure, Reactor Coolant Pump (RCP) trip, Main Steam Isolation Valve (MSIV) failure, and PZR spray failure. The information flow rate is obtained for each diagnosis task by imposing time limit restrictions for the tasks. Subjective methods require the operators to respond to questionnaires to rate their level of mental effort. NASA-TLX and MCH scale are selected as subjective methods. NASA-TLX is a subjective method used in the various fields including the aviation, automobile, and nuclear industries. It has a multi-dimensional rating technique and provides an overall workload score based on a weighted average on six subscales using pair-wise comparison tests. MCH, on the other hand, is one-dimensional and uses a 10- point rating technique. As with NASA-TLX, the higher the score is, the higher the subjective workload is. For the physiological measurements, an eye tracking system analyzes eye movements

  7. Investigation of relationship between mental workload and information flow rate of accident diagnosis tasks in NPPs

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Chang Hoon

    2005-02-15

    The objective of this study is to investigate experimentally the relationship between an operator's mental workload and the information flow rate of accident diagnosis tasks and further to propose the information flow rate as an analytic method for measuring the mental workload. There are two types of mental workload in the advanced MCR of NPPs: the information processing workload, which is the processing that the human operator must actually perform in order to complete the diagnosis task, and emotional stress workload experienced by the operator. In this study, the focus is on the former. Three kinds of methods are used to measure the operator's workload: information flow rate, subjective methods, and physiological measures. Information flows for eight accident diagnosis tasks are modeled qualitatively using a stage model and are quantified using Conant's model. The eight accident cases are considered here are: Loss Of Coolant Accident (LOCA), Steam Generator Tube Rupture (SGTR), Steam Line Break (SLB), Feedwater Line Break (FLB), Pressurizer (PZR) spray and heater failure, Reactor Coolant Pump (RCP) trip, Main Steam Isolation Valve (MSIV) failure, and PZR spray failure. The information flow rate is obtained for each diagnosis task by imposing time limit restrictions for the tasks. Subjective methods require the operators to respond to questionnaires to rate their level of mental effort. NASA-TLX and MCH scale are selected as subjective methods. NASA-TLX is a subjective method used in the various fields including the aviation, automobile, and nuclear industries. It has a multi-dimensional rating technique and provides an overall workload score based on a weighted average on six subscales using pair-wise comparison tests. MCH, on the other hand, is one-dimensional and uses a 10- point rating technique. As with NASA-TLX, the higher the score is, the higher the subjective workload is. For the physiological measurements, an eye tracking system analyzes

  8. Doses in radiation accidents investigated by chromosome aberration analysis XVI: A review of cases investigated, 1985

    International Nuclear Information System (INIS)

    Lloyd, D.C.; Edwards, A.A.; Prosser, J.S.; Moquet, J.E.; Finnon, P.

    1986-04-01

    During 1985, 28 cases of suspected overexposure to ionising radiation were referred to NRPB for investigation by cytogenetic analysis, and the results are presented in this report. Of the 28 cases, 17 were associated with industrial radiography, 9 from major nuclear organisations and 2 from research, education and health institutions. In 20 cases, no biological indication of overexposure was found. The remaining 8 cases all arose from industrial uses of radiation. The highest overexposure to a sealed source in 1985 ws about 0.4 Gy from an 192 Ir source that became detached from its winding mechanism. Two serious incidents involving unsealed sources are also described; an accidental ingestion of 125 I, for which cytogenetic analysis is of limited relevance, and an inhalation of droplets of tritiated water. The latter also produced a committed dose equivalent of about 0.4 Sv, the estimates from cytogenetic analysis and urine analysis being in good agreement. (author)

  9. An outline of the interim report of the investigation committee on the accident at Fukushima Nuclear Power Stations

    International Nuclear Information System (INIS)

    Yoshioka, Hitoshi

    2012-01-01

    Interim report of the Investigation Committee of the Accident at Fukushima Nuclear Power Stations (NPSs) was published in December 26, 2011. The Japanese cabinet approved ten committee members including the author in May 2011. The committee interviewed more than 400 people over a total of 900 hours of hearings with about 40 staffs consisting of administrative team and three investigation teams of social system, root causes of the accident and countermeasures to prevent damage expansion of the accident. Interim report concluded 'the accident at Fukushima NPSs was caused by failures of every provision against reactor severe accident'. The failures appeared on (1) function of supervisory system for emergency response, (2) Fukushima Daiichi NPSs on-site disaster response especially related with operation of isolation condenser of unit 1 and high-pressure coolant injection system of unit 3, (3) Fukushima Daiichi NPSs off-site disaster response such the government failed to make use of data on the radioactive plumes released from the plant for evacuations, and (4) preparedness against tsunami and severe accident management. Possible worst or best simulation cases were also discussed. With no human support available on-site, workers might not have been able to prevent the meltdowns. Final report was due at the end of July 2012. (T. Tanaka)

  10. Use of questionnaires and an expert panel to judge the environmental consequences of chemical spills for the development of an environment-accident index.

    Science.gov (United States)

    Andersson, Asa Scott; Stjernström, Olof; Fängmark, Ingrid

    2005-05-01

    Assessing the environmental consequences of a chemical accident is a complex task. To date, the methods used to evaluate the environmental effects of an acute release of a chemical have often been based on measurements of chemical and physical variables deemed to be important, such as the concentration of the chemical. However, a broader strategy is needed to predict the environmental consequences of potential accidents during the planning process. An Environment-Accident Index (EAI), a simple tool based on such a strategy, has been developed to facilitate the consideration of a multitude of influential variables. The objectives of this study were to evaluate whether questionnaire-based expert panel's judgements could provide useful data on the environmental consequences of chemical spills, and an effective basis for further development of the EAI. As expected, the judgements did not agree perfectly, but they do give rough indications of the environmental effects, and highlight consistent trends that should be useful inputs for planning, prevention and decontamination processes. The different accidents were also judged to have caused everything from minor to very major effects in the environment, implying that a wide range of accident scenarios were represented in the material and covered by the EAI. Therefore, questionnaires and expert panel judgements can be used to collect useful data for estimating the likely environmental consequences of chemical accidents and for further development of the EAI.

  11. Investigation of the radiological impact of reactor accidents under probabilistic aspects

    International Nuclear Information System (INIS)

    Huebschmann, W.; Vogt, S.

    1977-01-01

    An analysis and conceptional investigation have been performed for the accident consequence model of the German reactor risk study. A dynamic atmospheric diffusion model is developed, which is applied in the first stage of the study to all distance ranges, and will be restricted finally to the long distance range. The wind direction and its variations are not taken into account in this model. The program set UFO-BAS calculates the time integrated nuclide concentration in air at any location downwind of the source. A further model which takes into account wind direction variations is being developed. On the basis of the proposals for the calculation of the health effects in the German risk study considerations on the storage requirements were accomplished. By means of these assessments a revised grid of parameters was evaluated. Furthermore, considerations were made for the implementation of an evaluation model, which will be developed by the Institut fuer Unfallforschung. (orig./RW) [de

  12. The investigation on the public panic caused from the Fukushima nuclear accident

    International Nuclear Information System (INIS)

    Liao Li; Wang Yilong; He Xu

    2012-01-01

    March 11, 2011, a huge earthquake and tidal waves in Japan lead to dangerous levels of nuclear leakage at Fukushima nuclear plant, the nuclear accident also cause public panic m many countries. To investigate the reason of the public panic, we employ the theories of sociology and psychology, analyzed that the public panic come from Ignorant Panic. Herd Behavior, Primacy Effect, Stereotype Activation Effect, and the superposition of these effects. In addition, we proposed three measures to the public panic: First, we should emphasize the safety of nuclear power and establish the positive image of nuclear power Second, we should emphasize the popular science of nuclear power so that nu clear power can be accepted in the public; Third, we should enhance the psychological intervention system for nuclear safe emergency and improve the effect of psychological intervention

  13. The crisis of investigative Journalism in Spain. The journalism practice in the Spanair accident

    Directory of Open Access Journals (Sweden)

    José Vicente García-Santamaría, Ph.D.

    2010-01-01

    Full Text Available The crash of the McDonnell Douglas plane operated by the Spanish airline Spanair, on 20 August 2008 at Barajas Airport, and the journalistic treatment it received undoubtedly represent a unique opportunity to address the current state of journalism in Spain. In particular, this article studies the use of information sources in a crisis situation, which requires a major effort to find the maximum number of primary and specialised sources to provide, in a short period of time, the audience with the key facts to understand the event. This accident also represents an excellent opportunity to study some practices within investigative journalism and the different factors that condition the media agenda. Finally, as in any other air tragedy, where millionaire compensations can be paid to the victims, it is important to examine the application of a series of ethical frameworks, which have been captured in deontological codes designed to assure fair journalistic practices.

  14. The unique field experiments on the assessment of accident consequences at industrial enterprises of gas-chemical complexes

    International Nuclear Information System (INIS)

    Belov, N.S.; Trebin, I.S.; Sorokovikova, O.

    1998-01-01

    Sour natural gas fields are the unique raw material base for setting up such large enterprises as gas chemical complexes. The presence of high toxic H 2 S in natural gas results in widening a range of dangerous and harmful factors for biosphere. Emission of such gases into atmosphere during accidents at gas wells and gas pipelines is of especial danger for environment and first of all for people. Development of mathematical forecast models for assessment of accidents progression and consequences is one of the main elements of works on safety analysis and risk assessment. The critical step in development of such models is their validation using the experimental material. Full-scale experiments have been conducted by the All-Union Scientific-Research institute of Natural Gases and Gas Technology (VNIIGAZ) for grounding of sizes of hazard zones in case of the severe accidents with the gas pipelines. The source of emergency gas release was the working gas pipelines with 100 mm dia. And 110 km length. This pipeline was used for transportation of natural gas with significant amount of hydrogen sulphide. During these experiments significant quantities of the gas including H 2 S were released into the atmosphere and then concentrations of gas and H 2 S were measured in the accident region. The results of these experiments are used for validation of atmospheric dispersion models including the new Lagrangian trace stochastic model that takes into account a wide range of meteorological factors. This model was developed as a part of computer system for decision-making support in case of accident release of toxic gases into atmosphere at the enterprises of Russian gas industry. (authors)

  15. Occupational hazards in hospitals: accidents, radiation, exposure to noxious chemicals, drug addiction and psychic problems, and assault

    Energy Technology Data Exchange (ETDEWEB)

    Gestal, J.J.

    1987-08-01

    Except for infectious diseases all the main occupational hazards affecting health workers are reviewed: accidents (explosions, fires, electrical accidents, and other sources of injury); radiation (stochastic and non-stochastic effects, protective measures, and personnel most at risk); exposure to noxious chemicals, whose effects may be either local (allergic eczema) or generalised (cancer, mutations), particular attention being paid to the hazards presented by formol, ethylene oxide, cytostatics, and anaesthetic gases; drug addiction (which is more common among health workers than the general population) and psychic problems associated with promotion, shift work, and emotional stress; and assault (various types of assault suffered by health workers, its causes, and the characterisation of the most aggressive patients).

  16. Occupational hazards in hospitals: accidents, radiation, exposure to noxious chemicals, drug addiction and psychic problems, and assault

    International Nuclear Information System (INIS)

    Gestal, J.J.

    1987-01-01

    Except for infectious diseases all the main occupational hazards affecting health workers are reviewed: accidents (explosions, fires, electrical accidents, and other sources of injury); radiation (stochastic and non-stochastic effects, protective measures, and personnel most at risk); exposure to noxious chemicals, whose effects may be either local (allergic eczema) or generalised (cancer, mutations), particular attention being paid to the hazards presented by formol, ethylene oxide, cytostatics, and anaesthetic gases; drug addiction (which is more common among health workers than the general population) and psychic problems associated with promotion, shift work, and emotional stress; and assault (various types of assault suffered by health workers, its causes, and the characterisation of the most aggressive patients). (author)

  17. Investigation of Evaluation method of chemical runaway reaction

    International Nuclear Information System (INIS)

    Sato, Yoshihiko; Sasaya, Shinji; Kurakata, Koichiro; Nojiri, Ichiro

    2002-02-01

    Safety study 'Study of evaluation of abnormal occurrence for chemical substances in the nuclear fuel facilities' will be carried out from 2001 to 2005. In this study, the prediction of thermal hazards of chemical substances will be investigated and prepared. The hazard prediction method of chemical substances will be constructed from these results. Therefore, the hazard prediction methods applied in the chemical engineering in which the chemical substances with the hazard of fire and explosion were often treated were investigated. CHETAH (The ASTM Computer Program for Chemical Thermodynamic and Energy Release Evaluation) developed by ASTM (American Society for Testing and Materials) and TSS (Thermal Safety Software) developed by CISP (ChemInform St. Petersburg) were introduced and the fire and explosion hazards of chemical substances and reactions in the reprocessing process were evaluated. From these evaluated results, CHETAH could almost estimate the heat of reaction at 10% accuracy. It was supposed that CHETAH was useful as a screening for the hazards of fire and explosion of the new chemical substances and so on. TSS could calculate the reaction rate and the reaction behavior from the data measured by the various calorimeters rapidly. It was supposed that TSS was useful as an evaluation method for the hazards of fire and explosion of the new chemical reactions and so on. (author)

  18. Safety in the Chemical Laboratory. Epidemiology of Accidents in Academic Chemistry Laboratories, Part 2. Accident Intervention Study, Legal Aspects, and Observations.

    Science.gov (United States)

    Hellmann, Margaret A.; And Others

    1986-01-01

    Reports on a chemistry laboratory accident intervention study conducted throughout the state of Colorado. Addresses the results of an initial survey of institutions of higher learning. Discusses some legal aspects concerning academic chemistry accidents. Provides some observations about academic chemistry laboratory accidents on the whole. (TW)

  19. Experimental investigations relevant for hydrogen and fission product issues raised by the Fukushima accident

    Directory of Open Access Journals (Sweden)

    Sanjeev Gupta

    2015-02-01

    Full Text Available The accident at Japan's Fukushima Daiichi nuclear power plant in March 2011, caused by an earthquake and a subsequent tsunami, resulted in a failure of the power systems that are needed to cool the reactors at the plant. The accident progression in the absence of heat removal systems caused Units 1-3 to undergo fuel melting. Containment pressurization and hydrogen explosions ultimately resulted in the escape of radioactivity from reactor containments into the atmosphere and ocean. Problems in containment venting operation, leakage from primary containment boundary to the reactor building, improper functioning of standby gas treatment system (SGTS, unmitigated hydrogen accumulation in the reactor building were identified as some of the reasons those added-up in the severity of the accident. The Fukushima accident not only initiated worldwide demand for installation of adequate control and mitigation measures to minimize the potential source term to the environment but also advocated assessment of the existing mitigation systems performance behavior under a wide range of postulated accident scenarios. The uncertainty in estimating the released fraction of the radionuclides due to the Fukushima accident also underlined the need for comprehensive understanding of fission product behavior as a function of the thermal hydraulic conditions and the type of gaseous, aqueous, and solid materials available for interaction, e.g., gas components, decontamination paint, aerosols, and water pools. In the light of the Fukushima accident, additional experimental needs identified for hydrogen and fission product issues need to be investigated in an integrated and optimized way. Additionally, as more and more passive safety systems, such as passive autocatalytic recombiners and filtered containment venting systems are being retrofitted in current reactors and also planned for future reactors, identified hydrogen and fission product issues will need to be coupled

  20. Study on Developments in Accident Investigation Methods: A Survey of the 'State-of-the-Art'

    Energy Technology Data Exchange (ETDEWEB)

    Hollnagel, Erik; Speziali, Josephine (Ecole des Mines de Paris, F-06904 Sophia Antipolis (France))

    2008-01-15

    The objective of this project was to survey the main accident investigation methods that have been developed since the early or mid-1990s. The motivation was the increasing frequency of accidents that defy explanations in simple terms, for instance cause-effect chains or 'human error'. Whereas the complexity of socio-technical systems is steadily growing across all industrial domains, including nuclear power production, accident investigation methods are only updated when their inability to account for novel types of accidents and incidents becomes inescapable. Accident investigation methods therefore typically lag behind the socio-technological developments by 20 years or more. The project first compiled a set of methods from the recognised scientific literature and in major major research and development programs, excluding methods limited to risk assessment, technological malfunctions, human reliability, and safety management methods. An initial set of 21 methods was further reduced to seven by retaining only prima facie accident investigation methods and avoiding overlapping or highly similar methods. The second step was to develop a set of criteria used to characterise the methods. The starting point was Perrow's description of normal accidents in socio-technical systems, which used the dimensions of coupling, going from loose to tight, and interactions, going from linear to complex. For practical reasons, the second dimension was changed to that of tractability or how easy it is to describe the system, where the sub-criteria are the level of detail, the availability of an articulated model, and the system dynamics. On this basis the seven selected methods were characterised in terms of the systems - or conditions - they could account for, leading to the following four groups: methods suitable for systems that are loosely coupled and tractable, methods suitable for systems that are tightly coupled and tractable, methods suitable for systems that

  1. Investigation program on PWR-steel-containment behavior under accident conditions

    International Nuclear Information System (INIS)

    Krieg, R.; Eberle, F.; Goeller, B.; Gulden, W.; Kadlec, J.; Messemer, G.; Mueller, S.; Wolf, E.

    1983-10-01

    This report is a first documentation of the KfK/PNS activities and plans to investigate the behaviour of steel containments under accident conditions. The investigations will deal with a free standing spherical containment shell built for the latest type of a German pressurized water reactor. The diameter of the containment shell is 56 m. The minimum wall thickness is 38 mm. The material used is the ferritic steel 15MnNi63. According to the actual planning the program is concerned with four different problems which are beyond the common design and licensing practice: Containment behavior under quasi-static pressure increase up to containment failure. Containment behavior under high transient pressures. Containment oscillations due to earthquake loadings; consideration of shell imperfections. Containment buckling due to earthquake loadings. The investigation program consists of both theoretical and experimental activities including membrane tests allowing for very high plastic strains and oscillation tests with a thin-walled, high-accurate spherical shell. (orig.) [de

  2. Investigating Prevalence of deaths from Traffic Accidents and Factors Associated with it in Yazd in 2009

    Directory of Open Access Journals (Sweden)

    Gh Soltani

    2014-02-01

    Conclusion: This study findings provide useful information for setting priorities in order to prevent the traffic accidents injuries. In addition, appropriate intervention programs are necessary in order to prevent traffic accidents and their complications, as well as to minimize injuries in accordance with other relevant organizations.

  3. Decision support systems for major accident prevention in the chemical process industry : A developers' survey

    NARCIS (Netherlands)

    Reniers, Genserik L L; Ale, B. J.M.; Dullaert, W.; Foubert, B.

    2006-01-01

    Solid major accident prevention management is characterized by efficient and effective risk assessments. As a means of addressing the efficiency aspect, decision support analysis software is becoming increasingly available. This paper discusses the results of a survey of decision support tools for

  4. Chemical, physical and tribological investigation of polymercaptanized soybean oil

    Science.gov (United States)

    Polymercaptanized soybean oil (PMSO) was investigated for its chemical, physical and tribological properties relative to soybean oil (SO) and also as a potential multi-functional lubricant additive in high oleic sunflower oil (HOSuO). Analytical investigations showed that PMSO is obtained by convers...

  5. Improvement of radiological consequence estimation methodologies for NPP accidents in the ARGOS and RODOS decision support systems through consideration of contaminant physico-chemical forms

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, K.G.; Roos, P. [Technical University of Denmark - DTU (Denmark); Lind, O.C.; Salbu, B. [Norwegian University of Life Sciences/CERAD - NMBU (Norway); Bujan, A.; Duranova, T. [VUJE, Inc. (Slovakia); Ikonomopoulos, A.; Andronopoulos, S. [National Centre for Scientific Research ' Demokritos' (Greece)

    2014-07-01

    The European standard computerized decision support systems RODOS and ARGOS, which are integrated in the operational nuclear emergency preparedness in practically all European countries, as well as in a range of non-European countries, are highly valuable tools for radiological consequence estimation, e.g., in connection with planning and exercising as well as in justification and optimization of intervention strategies. Differences between the Chernobyl and Fukushima accident atmospheric release source terms have demonstrated that differences in release conditions and processes may lead to very different degrees of volatilization of some radionuclides. Also the physico-chemical properties of radionuclides released can depend strongly on the release process. An example from the Chernobyl accident of the significance of this is that strontium particles released in the fire were oxidized and thus generally physico-chemically different from those released during the preceding explosion. This is reflected in the very different environmental mobility of the two groups of particles. The initial elemental matrix characteristics of the contaminants, as well as environmental parameters like pH, determine for instance the particle dissolution time functions, and thus the environmental mobility and potential for uptake in living organisms. As ICRP recommends optimization of intervention according to residual dose, it is crucial to estimate long term dose contributions adequately. In the EURATOM FP7 project PREPARE, an effort is made to integrate physico-chemical forms of contaminants in scenario-specific source term determination, thereby enabling consideration of influences on atmospheric dispersion/deposition, post-deposition migration, and effectiveness of countermeasure implementation. The first step in this context was to investigate, based on available experience, the important physico-chemical properties of radio-contaminants that might potentially be released to the

  6. Analysis and prognosis of radiation exposure following the accident at the Siberian chemical combine Tomsk-7

    International Nuclear Information System (INIS)

    Vakulovski, S.M.; Shershakov, V.M.; Borodin, R.V.; Vozzhennikov, O.I.; gaziev, Y.I.; Kosykh, V.S.; Makhon'ko, K.P.; Chumichev, V.B.

    1994-10-01

    On the basis of the work (ground investigations and gamma aerial surveys) carried out jointly by the Rosgidromet organizations and Berezovgeologiya, data on the radiation exposure in Russia were obtained shortly after the accident of April 6, 1993 already. These data were transmitted to interested institutions. The measurements performed on April 11 and 12, 1993 indicated that within the isolines of 10 μR/h a contaminated area of up to 25 km in length and up to 6 km in width extended towards the northeastern direction. Thus, the contaminated area outside of the premises of the combine covered about 100 km 2 . The total amount of radioactive substances in this area was 530 - 590 Ci. Isotope composition of the radioactive trace was determined by ruthenium-103 (1%), ruthenium-106 (31%), zirconium-95 (22%), niobium-95 (45%) and plutonium-239 (0.02%). Contamination heterogeneity is caused by the existence of 'hot' particles with an activity of up to 10-11 Ci/particle. In the contaminated area the gamma exposure rate varied between 14 and 42 μR/h at 1 m height, yielding the maximum external radiation dose 100 mrem/year for the population of Georgievka. The Pu-239 inhalation dose of the population of Georgievka when passing the radioactive cloud did not exceed 1.5 mrem. A prognosis was made with regard to water contamination of the rivers Samuska and Tom during the flood in spring. Furthermore, contamination of the air layer adjacent to the ground resulting from the wind transport of radionuclides in the summer months at Georgievka was predicted. The values were far below the limits fixed according to the valid radiation protection regulations. However, that radionuclide concentration of the snow water may exceed the limits specified for drinking water. According to the data measured by the meteorological stations, the radioactive products were not entrained beyond the borders of the country. Source estimation was successfully obtained using RIMPUFF, the Risoe on

  7. An examination of aviation accidents in the context of a conflict of interests between law enforcement, insurers, commissions for aircraft accident investigations and other entities

    Directory of Open Access Journals (Sweden)

    Tomasz BALCERZAK

    2017-06-01

    Full Text Available The sole purpose of air accident investigations should be the prevention of accidents and incidents in the future without apportioning blame or liability. Any civil aviation safety system is based on feedback and lessons learned from accidents and incidents, which require the strict application of rules on confidentiality in order to ensure the availability of valuable sources of information in the future. Therefore, related data, especially sensitive safety information, should be protected in an appropriate manner. Information provided by a person in the framework of a safety investigation should not be used against that person, in full respect of constitutional principles, as well as national and international law. Each “involved person” in an accident or another serious incident should promptly notify the competent investigating authority of the state of the event. An “involved person” means the owner, a member of the crew, the operator of the aircraft involved in an accident or other serious incident, or any person involved in the maintenance, design, manufacture of the affected aircraft or in the training of its crews, as well as any person involved in air traffic control, providing flight information or providing airport services to the aircraft in question, the staff of the national civil aviation authority, or staff of the European Aviation Safety Agency. The protection level of the organization (employer: employees who report an event or replace applications following an event with regard to the appropriate reporting systems should not face any prejudice from their employer because of information provided by the applicant. The protection does not cover (exclusions: infringement with wilful misconduct (direct intent, recklessness infringement; infringement committed by a clear and serious disregard of the obvious risks; and serious professional negligence of an unquestionably duty of care required under the circumstances

  8. Microscopic and Metallurgical Aspects of the Space Shuttle Columbia Accident Investigation and Reconstruction

    Science.gov (United States)

    McDaniels, Steven J.

    2004-01-01

    The Space Shuttle Columbia was descending for a landing at the Kennedy Space Center (KSC) on February 1, 2003. Approximately 20 minutes prior to touchdown, the Columbia began disintegrating over the western United States; the majority of debris eventually impacted in eastern Texas and western Louisiana. A monumental effort eventually recovered approximately 84,000 pieces of debris, approximately 38% of the Orbiter's original dry weight. The debris was transported to KSC, where the items were catalogued and evaluated. Critical areas of interest, such as the left and right leading edge surfaces and the underside of the ship, were placed upon a grid to aid in the reconstruction. Items of interest included metallic structures, reinforced carbon-carbon composites, and ceramic heat insulation tiles. Many of the leading edge elements had re-solidified metallic deposits spattered on them. These deposits became known as slag and were one of the main focuses of the investigation. In order to help determine the sequence of events inside the left wing during the accident, the slag's composition, layering order, and directionality of deposition were studied. A myriad of analytical tests were performed in an attempt to ascertain the compositional and depositional characteristics of selected slag deposits, including the ordering of deposited layers within each individual slag deposit harvested. Initially, Scanning Electron Microscopy and Energy Dispersive X-Ray Spectroscopy (SEM/EDX) were performed to quickly characterize the overall composition of individual slag deposits: SEM utilizes a narrowlyfocused high-energy electron beam impinging upon a specimen. The incident beam excites and liberates lower energy secondary electrons, which are detected and analyzed, providing a visual representation of the sample's surface topography. EDX also relies on an incident electron beam, except an EDX unit measures X-ray energies generated by the impinging beam. Each element generates a

  9. Results of the reliability investigations for the design basis accident 'Rupture of a cold primary coolant system'

    International Nuclear Information System (INIS)

    Hoertner, H.; Nieckau, E.; Spindler, H.

    1976-12-01

    This report gives a comprehensive presentation of the detailed reliability investigation carried out for the engineered safety features installed to cope with the design basis accident 'Large LOCA' of a German nuclear power plant with pressurized water reactor. The investigation is based on the engineered safety features of the Biblis Nuclear Power Plant, Unit A. The reliability investigation is carried out by means of a fault tree analysis. The influence of common-mode failures is assessed. (orig.) [de

  10. Investigation Effect of Biorhythm on Work-Related Accidents in The Metal Industry (A Short Report

    Directory of Open Access Journals (Sweden)

    Ehsanollah Habibi

    2016-07-01

    Full Text Available Biorhythm is one of the newest subjects in the field of cognition of mental ergonomics which can be very effective in reduction of work-related accidents or mistakes with no apparent reason. With evaluating Biorhythm individuals can intervention action to reduce job accidents carried out. Thus, the aim of this study was to determine the relationship Biorhythm and work-related accidents in the metal industry. This research is a cross-sectional and analytical-descriptive in the metal industrial Isfahan city of 120 work-related accidents during 2015. The required information was collected from available documents in HSE unit of the company biorhythm charts were drawn based on a date of accidents and participants birthdays, using natural Biorhythm Software V3.02 Conduct. Finally، the data were analyzed using spss version 20 and descriptive statistics.This study showed that the frequency of accidents in critical days and negative section of physical cycle was more than expected. Also the frequency of accidents in critical days and negative section of emotional and intellectual cycles was less than expected. Most type of injury, including cuts to 35.8 percent and the lowest type of injury was torsion with 5 percent. Most limb injury, hands and fingers with 51.7 percent and the lowest limb injury were back at 2.5 percent. Accidents outbreak in physical cycles was 38.3 percent. These 120 accidents in additionally were causing 120 loss of working days in effect accident. Most percent of loss of working days were for 20 to 30 days with of 39.2 percent. Most percent of loss of working days were for 20 to 30 days with of 39.2 percent. Due to the physical nature of the work activities in the metal industry can be stated that the study showed that in physical work activities, frequency of accidents in critical days and negative section of physical cycle in which the person is not physically ready to do the job was more than expected. Therefore, by training

  11. Case study on chemical plant accidents for flow-sheet design of the HTTR-IS system

    International Nuclear Information System (INIS)

    Homma, Hiroyuki; Sato, Hiroyuki; Kasahara, Seiji; Hara, Teruo; Kato, Ryoma; Sakaba, Nariaki; Ohashi, Hirofumi

    2007-02-01

    At the present time, we are alarmed by depletion of fossil energy and adverse effect of rapid increase in fossil fuel burning on environment such as climate changes and acid rain, because our lives depend still heavily upon fossil energy. It is thus widely recognized that hydrogen is one of important future energy carriers in which it is used without emission of carbon dioxide greenhouse gas and atmospheric pollutants and that hydrogen demand will increase greatly as fuel cells are developed and applied widely in the near future. To meet massive demand of hydrogen, hydrogen production from water utilizing nuclear, especially by thermochemical water-splitting Iodine-Sulphur (IS) process utilizing heat from High-Temperature Gas-cooled Reactors (HTGRs), offers one of the most attractive zero-emission energy strategies and the only one practical on a substantial scale. However, to establish a technology based for the HTGR hydrogen production by the IS process, we should close several technology gaps through R and D with the High-Temperature Engineering Test Reactor (HTTR), which is the only Japanese HTGR built and operated at the Oarai Research and Development Centre of Japan Atomic Energy Agency (JAEA). We have launched design studies of the IS process hydrogen production system coupled with the HTTR (HTTR-IS system) to demonstrate HTGR hydrogen production. In designing the HTTR-IS system, it is necessary to consider preventive and breakdown maintenance against accidents occurred in the IS process as a chemical plant. This report describes case study on chemical plant accidents relating to the IS process plant and shows a proposal of accident protection measures based on above case study, which is necessary for flow-sheet design of the HTTR-IS system. (author)

  12. Chemical interactions between aerosols and vapors in the primary circuit of an LWR during a severe accident

    International Nuclear Information System (INIS)

    Wheatley, C.J.

    1988-01-01

    Aerosol formation, agglomeration, convection and deposition within the primary circuit of an LWR during a severe accident significantly affect the transport of fission products, even though they may compose only a small fraction of the aerosol material. Intra-particle and vapor chemical interactions are important to this through mass transfer between the aerosol and vapor. The authors will describe a model that attempts to account for these processes and of the two-way coupling that exists with the thermal hydraulics. They will discuss what agglomeration and deposition mechanisms must be included, alternatives for treating intra-particle chemical interactions, mechanisms of aerosol formation, and methods for solving the resulting equations. Results will be presented that illustrate the importance of treating the two-way coupling and the extent to which disequilibrium between the aerosol and vapor affects fission product behavior

  13. Constructing the Indicators of Assessing Human Vulnerability to Industrial Chemical Accidents: A Consensus-based Fuzzy Delphi and Fuzzy AHP Approach.

    Science.gov (United States)

    Fatemi, Farin; Ardalan, Ali; Aguirre, Benigno; Mansouri, Nabiollah; Mohammadfam, Iraj

    2017-04-10

    Industrial chemical accidents have been increased in developing countries. Assessing the human vulnerability in the residents of industrial areas is necessary for reducing the injuries and causalities of chemical hazards. The aim of this study was to explore the key indicators for the assessment of human vulnerability in the residents living near chemical installations. The indicators were established in the present study based on the Fuzzy Delphi method (FDM) and Fuzzy Analytic Hierarchy Process (FAHP). The reliability of FDM and FAHP was calculated. The indicators of human vulnerability were explored in two sets of social and physical domains. Thirty-five relevant experts participated in this study during March-July 2015. According to experts, the top three indicators of human vulnerability according to the FDM and FAHP were vulnerable groups, population density, and awareness. Detailed sub-vulnerable groups and awareness were developed based on age, chronic or severe diseases, disability, first responders, and residents, respectively. Each indicator and sub-indicator was weighted and ranked and had an acceptable consistency ratio. The importance of social vulnerability indicators are about 7 times more than physical vulnerability indicators. Among the extracted indicators, vulnerable groups had the highest weight and the greatest impact on human vulnerability. however, further research is needed to investigate the applicability of established indicators and generalizability of the results to other studies. Fuzzy Delphi; Fuzzy AHP; Human vulnerability; Chemical hazards.

  14. Safety-critical human factors issues derived from analysis of the TEPCO Fukushima Daiichi accident investigation reports

    International Nuclear Information System (INIS)

    Sakuda, Hiroshi; Takeuchi, Michiru

    2013-01-01

    The Fukushima Daiichi nuclear power plant accident on March 11, 2011 had a large impact both in and outside Japan, and is not yet concluded. After Tokyo Electric Power Co.'s (TEPCO's) Fukushima accident, electric power suppliers have taken measures to respond in the event that the same state of emergency occurs - deploying mobile generators, temporary pumps and hoses, and training employees in the use of this equipment. However, it is not only the “hard” problems including the design of equipment, but the “soft” problems such as organization and safety culture that have been highlighted as key contributors in this accident. Although a number of organizations have undertaken factor analysis of the accident and proposed issues to be reviewed and measures to be taken, a systematic overview about electric power suppliers' organization and safety culture has not yet been undertaken. This study is based on three major reports: the report by the national Diet of Japan Fukushima Nuclear Accident Independent Investigation Commission (the Diet report), the report by the Investigation Committee on the Accident at Fukushima Nuclear Power Stations of Tokyo Electric Power Company (Government report), and the report by the non-government committee supported by the Rebuild Japan Initiative Foundation (Non-government report). From these reports, the sections relevant to electric power suppliers' organization and safety culture were extracted. These sections were arranged to correspond with the prerequisites for the ideal organization, and 30 issues to be reviewed by electric power suppliers were extracted using brainstorming methods. It is expected that the identified issues will become a reference for every organization concerned to work on preventive measures hereafter. (author)

  15. The investigation on the mass media reports on the JCO accident in the major atomic energy countries and Asian countries

    International Nuclear Information System (INIS)

    1999-12-01

    The JCO (Japan Conversion Organization) accident is the worst one in the history of the atomic energy developments in Japan. The many reports about the accident appeared in the 44 mass media in the world from Sep. 30 to Oct. 14, 1999. Chronological statistics of issued 522 articles are listed under particular criteria. Some of them were based on wrong knowledge and/or overestimations about the accident based on delivered articles by the news agency. Some of others gave critics over the total atomic energy industries of Japan, especially on safety managements and so-called similar Japan syndromes. This investigation gives emphasis on the articles based on wrong knowledge. We identified the countries and the newspaper publishers and the news agencies those gave wrong descriptions. Total 25 articles used the words [explosion] and [fire], which were delivered from the Kyodo News Service. Some of the Asian newspaper wrote that a large quantity of radioactivity, radioactive material and/or nuclear fuels was released. Some other news publishers said the accident was happened at fuel reprocessing facilities, when the waste fuel rods were under cutting. Critics delivered in the individual countries were summarized, i.e. USA, Canada, France, UK, German, Russia, Australia, China, Korea, Thailand, Vietnam, Indonesia, Taiwan and the news agencies. One of the key issues is the exact information release for the press corps on the early stage of the accidents. The second point is to recognize the different status on atomic energy in the individual countries, when Japan want to explain their domestic situations. Accidents of atomic energy gave many impacts on various aspects to other countries. Japan should understand the neighborhood by collecting world information on atomic energy and analyzing them. Summaries of 522 articles appeared in the mass media were attached in this investigation among the report of 180 pages. (Tanaka, Y.)

  16. An investigation of core liquid level depression in small break loss-of-coolant accidents

    International Nuclear Information System (INIS)

    Schultz, R.R.; Watkins, J.C.; Motley, F.E.; Stumpf, H.; Chen, Y.S.

    1991-08-01

    Core liquid level depression can result in partial core dryout and heatup early in a small break loss-of-coolant accident (SBLOCA) transient. Such behavior occurs when steam, trapped in the upper regions of the reactor primary system (between the loop seal and the core inventory), moves coolant out of the core region and uncovers the rod upper elevations. The net result is core liquid level depression. Core liquid level depression and subsequent core heatups are investigated using subscale data from the ROSA-IV Program's 1/48-scale Large Scale Test Facility (LSTF) and the 1/1705-scale Semiscale facility. Both facilities are Westinghouse-type, four-loop, pressurized water reactor simulators. The depression phenomena and factors which influence the minimum core level are described and illustrated using examples from the data. Analyses of the subject experiments, conducted using the TRAC-PF1/MOD1 (Version 12.7) thermal-hydraulic code, are also described and summarized. Finally, the response of a typical Westinghouse four-loop plant (RESAR-3S) was calculated to qualitatively study coal liquid level depression in a full-scale system. 31 refs., 37 figs., 6 tabs

  17. Post-test investigation result on the WWER-1000 fuel tested under severe accident conditions

    International Nuclear Information System (INIS)

    Goryachev, A.; Shtuckert, Yu.; Zwir, E.; Stupina, L.

    1996-01-01

    The model bundle of WWER-type were tested under SFD condition in the out-of-pile CORA installation. The objective of the test was to provide an information on the WWER-type fuel bundles behaviour under severe fuel damage accident conditions. Also it was assumed to compare the WWER-type bundle damage mechanisms with these experienced in the PWR-type bundle tests with aim to confirm a possibility to use the various code systems, worked our for PWR as applied to WWER. In order to ensure the possibility of the comparison of the calculated core degradation parameters with the real state of the tested bundle, some parameters have been measured on the bundle cross-sections under examination. Quantitative parameters of the bundle degradation have been evaluated by digital image processing of the bundle cross-sections. The obtained results are shown together with corresponding results obtained by the other participants of this investigation. (author). 3 refs, 13 figs

  18. Investigation of the different scenarios occurring in a PWR in case of a TMLB accident

    International Nuclear Information System (INIS)

    Pochard, R.; Dufresne, J.; Autrusson, B.

    1988-10-01

    Severe accidents in light water reactors fall into one of two main categories, depending on whether or not core meltdown is accompanied by a pressure buildup in the primary system. The way in which the accident develops is, in fact, largely conditioned by this pressure aspect: temperature distribution in the core and primary system resulting from natural convection gas streams; fuel clad failure mode, etc... One major effect of pressure buildup on the accident scenario is primary system failure under the combined actions of pressure and temperature. The purpose of the present paper is to present, after a detailed thermalhydraulic study, an analysis of the timing and location of the system failures in case of a TMLB accident on CPY french type reactor

  19. Investigating of the effect of Biorhythm on work-related Accidents

    Directory of Open Access Journals (Sweden)

    F. Arab

    2014-07-01

    Conclusion: Findings of this research showed that bad and critical days of individuals’ biorhythms cycle influence the occurrence of accidents. Therefore, by training and increasing the knowledge of workers regarding biological cycle and its effects on mental, emotional and physical status, each person effects can make some changes to theire work plans during days that they do not feel well, physically or mentally, in order to prevent the likely accidents.

  20. Investigating plutonium contamination in marine sediments off Fukushima coast following the Fukushima Dai-ichi Nuclear Power Plant accident

    International Nuclear Information System (INIS)

    Bu Wenting; Guo Qiuju; Zheng, Jian; Aono, Tatsuo; Tagami, Keiko; Uchida, Shigeo; Zhang, Jing; Yamada, Masatoshi

    2013-01-01

    The Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident has caused large amounts of anthropogenic radionuclides to be released into the atmosphere as well as directly discharged into the sea. To obtain the vertical distribution of Pu isotopes in marine sediments and to better assess the possible contamination from the FDNPP accident in the marine environment, activities of "2"3"9"+"2"4"0Pu and "2"4"1Pu, as well as the atom ratios of "2"4"0Pu/"2"3"9Pu and "2"4"1Pu/"2"3"9Pu, were investigated in a sediment core collected from the western North Pacific in July 2011. The observed vertical profile of "2"3"9"+"2"4"0Pu activities and "2"4"0Pu/"2"3"9Pu atom ratios showed no extra injection of Pu from the accident, indicating no immediate Pu contamination from the FDNPP accident in the marine sediments in the region investigated. (author)

  1. Investigation of accident management procedures related to loss of feedwater and station blackout in PSB-VVER integral test facility

    Energy Technology Data Exchange (ETDEWEB)

    Bucalossi, A. [EC JRC, (JRC F.5) PO Box 2, 1755 ZG Petten (Netherlands); Del Nevo, A., E-mail: alessandro.delnevo@enea.it [ENEA, C.R. Brasimone, 40032 Camugnano (Italy); Moretti, F.; D' Auria, F. [GRNSPG, Universita di Pisa, via Diotisalvi 2, 56100 Pisa (Italy); Elkin, I.V.; Melikhov, O.I. [Electrogorsk Research and Engineering Centre, Electrogorsk, Moscow Region (Russian Federation)

    2012-09-15

    Highlights: Black-Right-Pointing-Pointer Four integral test facility experiments related to VVER-1000 reactor. Black-Right-Pointing-Pointer TH response of the VVER-1000 primary system following total loss of feedwater and station blackout scenarios. Black-Right-Pointing-Pointer Accident management procedures in case of total loss of feedwater and station blackout. Black-Right-Pointing-Pointer Experimental data represent an improvement of existing database for TH code validation. - Abstract: VVER 1000 reactors have some unique and specific features (e.g. large primary and secondary side fluid inventory, horizontal steam generators, core design) that require dedicated experimental and analytical analyses in order to assess the performance of safety systems and the effectiveness of possible accident management strategies. The European Commission funded project 'TACIS 2.03/97', Part A, provided valuable experimental data from the large-scale (1:300) PSB-VVER test facility, investigating accident management procedures in VVER-1000 reactor. A test matrix was developed at University of Pisa (responsible of the project) with the objective of obtaining the experimental data not covered by the OECD VVER validation matrix and with main focus on accident management procedures. Scenarios related to total loss of feed water and station blackout are investigated by means of four experiments accounting for different countermeasures, based on secondary cooling strategies and primary feed and bleed procedures. The transients are analyzed thoroughly focusing on the identification of phenomena that will challenge the code models during the simulations.

  2. Chemical investigation of the effluents of selected chemical industries in NWFP (Pakistan)

    International Nuclear Information System (INIS)

    Jan, M.R.; Shah, J.; Shah, H.

    2002-01-01

    Samples of effluents were collected from the waste water drains of selected chemical industries, located at small industries estate Kohat Road Peshawar on monthly basis from November 1994 to October 1995. These samples were studied for physico chemical properties and heavy metals like Pb, Ag, Cu, Zn, Fe, Cr, Cd, Mn and Ni using spectroscopic techniques. The results of our investigation are presented and discussed. (author)

  3. Advances in chemical investigations of the heaviest elements

    Directory of Open Access Journals (Sweden)

    Türler Andreas

    2016-01-01

    Full Text Available Although somewhat in the shadow of the discoveries of new elements, experimental chemical investigations of the heaviest elements have made tremendous progress in the last decades. Indeed, it was possible to experimentally determine thermochemical properties of heavy transactinide elements such as copernicium or flerovium. But will it be possible to chemically study all currently known elements of the periodic table up to element 118? While it is experimentally feasible to work with single atoms, the short half-lives of even the longest currently known isotopes of elements 115 through 118 call for new experimental approaches.

  4. Investigation into the March 28, 1979 Three Mile Island accident by Office of Inspection and Enforcement (Investigative Report No. 50-320/79-10)

    International Nuclear Information System (INIS)

    1979-07-01

    On March 28, 1979, the Three Mile Island Unit 2 Nuclear Power Plant experienced the most severe accident in U.S. commercial nuclear power plant operating history. This report sets forth the facts concerning the events of the accident determined as a result of an investigation by the NRC Office of Inspection and Enforcement. The IE investigation is limited to two aspects of the accident: (1) Those related operational actions by the licensee during the period from before the initiating event until approximately 8:00 p.m., March 28, when primary coolant flow was re-established by starting a reactor coolant pump, and (2) Those steps taken by the licensee to control the release of radioactive material to the off-site environs, and to implement his emergency plan during the period from the initiation of the event to midnight, March 30. These investigation periods were selected because they include the licensee actions which most significantly affected the accident sequence and its results

  5. Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

    Energy Technology Data Exchange (ETDEWEB)

    Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H [Royal Inst. of Tech., Stockholm (Sweden). Div. of Nuclear Power Safety

    1999-08-01

    This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

  6. Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

    International Nuclear Information System (INIS)

    Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H

    1999-08-01

    This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

  7. Computational Aerodynamics of Shuttle Orbiter Damage Scenarios in Support of the Columbia Accident Investigation

    Science.gov (United States)

    Bibb, Karen L.; Prabhu, Ramadas K.

    2004-01-01

    In support of the Columbia Accident Investigation, inviscid computations of the aerodynamic characteristics for various Shuttle Orbiter damage scenarios were performed using the FELISA unstructured CFD solver. Computed delta aerodynamics were compared with the reconstructed delta aerodynamics in order to postulate a progression of damage through the flight trajectory. By performing computations at hypervelocity flight and CF4 tunnel conditions, a bridge was provided between wind tunnel testing in Langley's 20-Inch CF4 facility and the flight environment experienced by Columbia during re-entry. The rapid modeling capability of the unstructured methodology allowed the computational effort to keep pace with the wind tunnel and, at times, guide the wind tunnel efforts. These computations provided a detailed view of the flowfield characteristics and the contribution of orbiter components (such as the vertical tail and wing) to aerodynamic forces and moments that were unavailable from wind tunnel testing. The damage scenarios are grouped into three categories. Initially, single and multiple missing full RCC panels were analyzed to determine the effect of damage location and magnitude on the aerodynamics. Next is a series of cases with progressive damage, increasing in severity, in the region of RCC panel 9. The final group is a set of wing leading edge and windward surface deformations that model possible structural deformation of the wing skin due to internal heating of the wing structure. By matching the aerodynamics from selected damage scenarios to the reconstructed flight aerodynamics, a progression of damage that is consistent with the flight data, debris forensics, and wind tunnel data is postulated.

  8. Investigations of soil-plant transfer of radiocesium after deposition from the Chernobyl reactor accident

    International Nuclear Information System (INIS)

    Bilo, M.

    1991-11-01

    Due to the low deposition of radiocaesium in NRW after the Chernobyl accident of about 2500 Bq 137 Cs/m 2 and 720 Bq 134 Cs/m 2 , radiocaesium was not detectable in cereals from NRW. A deposition of about 44,100 Bq 137 Cs/m 2 and 13,500 Bq 134 Cs/m 2 was calculated for the vicinity of Tannheim, a village in Upper Swabia. Nevertheless, the content of radiocaesium in grain from Upper Swabia was found to be more than one hundred times lower than that of natural 40 K. Transferfactors (TF/SP) for radiocaesium were determined for cereals from the three investigated soil types: Kalkvega (FAO classification: Calcaric Fluvisol), Braunerde (Cambisol) and Parabraunerde-Pseudogley (Luvisol-Planosol). The total variation in TF(SP) from 54 sampling sites was a factor of 43 (grain) and 18 (straw). However, the values did not reach the calculation basis of the German Regulatory Guide of 0.05 (Allgemeine Berechnungsgrundlage). The maximum TF(SP) for 134/137 Cs in grain of 0.026 is clearly below that limit. A drastic increase of radioactivity in sewage sludge was observed in Upper Swabia. In the Tannheim sewage plant a radiocaesium content of about 12,500 Bq/kg dry matter was measured. In order to obtain further information on the possible radioecological consequences of using this sewage sludge as fertilizer a lysimeter study was carried out with application of the contaminated sewage sludge. Radioactivity in soil and several crops was measured for the growing periods 1989 and 1990. Although the soil type ('worst-case model') could have led one to expect high TF(SP) the increase of radiocaesium in plants was quite small. A higher uptake of radiocaesium by plants is caused by varying the potassium contents of the soil rather than by the application of the contaminated sewage sludge. (orig./HP) [de

  9. Report from investigation committee on the accident at the Fukushima Nuclear Power Stations of Tokyo Electric Power Company

    International Nuclear Information System (INIS)

    Koshizuka, Seiichi

    2012-01-01

    Government's Investigation Committee on the Accident at Fukushima Nuclear Power Stations of Tokyo Electric Power Company published its final report on July 23, 2012. Results of investigation combined final report and interim report published on December 26, 2011. The author was head of accident accuse investigation team mostly in charge of site response, prior measure and plant behavior. This article reported author related technical investigation results focusing on site response and prior measures against tsunamis of units 1-3 of Fukushima Nuclear Power Stations. Misunderstanding of working state of isolation condenser of unit 1, unsuitability of alternative water injection at manual stop of high-pressure coolant injection (HPCI) system of unit 3 and improper prior measure against tsunami and severe accident were pointed out in interim report. Improper monitoring of suppression chamber of unit 2 and again unsuitable work for HPCI system of unit 3 were reported in final report. Thorough technical investigation was more encouraged to update safety measures of nuclear power stations. (T. Tanaka)

  10. Chemical protection and sensitization to ionizing radiation:molecular investigations

    International Nuclear Information System (INIS)

    Badiello, R.

    1980-01-01

    Chemical radioprotection and radiosensitization are induced by the presence of certain chemical compounds, which reduce or enhance the effect of ionizing radiation on living organisms. Such substances are either naturally present or may be artificially introduced in the living cells. Chemical radioprotectors are interesting for possible application in the health protection of both professionally exposed workers and patients treated by radiation for diagnostic and thereapeutic purposes. Interest in chemical radiosensitization has increased recently because of its potential application in the radiotherapy of tumours. Both radioprotection and radiosensitization occur by means of complicated mechanisms, which at first correspond to very fast reactions. The mechanism of the interaction between such substances and radiation-induced biological radicals has been investigated by means of pulse radiolysis and rapid mixing techniques. Examples of the application of these techniques are given to illustrate how information has been obtained on the molecular basis of radiation chemical modi-fication at the cellular level. In particular some interactions between model systems of biological interest (DNA, DNA components, enzymes, amino acids, etc.) and sulphur-containing radioprotectors (glutathione, cysteine, etc.) and/or electroaffinic radiosensitizers, are described. (H.K.)

  11. Investigation of an accident in a resins manufacturing site: The role of accelerator on polymerisation of methyl methacrylate

    Energy Technology Data Exchange (ETDEWEB)

    Casson, Valeria, E-mail: valeria.casson.moreno@gmail.com [Alma Mater Studiorum—Università di Bologna, Dipartimento di Ingegneria Chimica, Mineraria e delle Tecnologie Ambientali, Bologna (Italy); Dipartimento di Ingegneria Industriale, Via Marzolo 9, 35131 Padova (Italy); Snee, Tim, E-mail: Tim.Snee@hsl.gsi.gov.uk [Health and Safety Laboratory, Harpur Hill, Buxton, Derbyshire SK 179 JN (United Kingdom); Maschio, Giuseppe, E-mail: giuseppe.maschio@unipd.it [Dipartimento di Ingegneria Industriale, Via Marzolo 9, 35131 Padova (Italy)

    2014-04-01

    Highlights: • The accelerator produces an increase in the initial rate of polymerisation. • The accelerator increases the extent of polymerisation in certain conditions. • The accelerator decreases the induction time due to the presence of inhibitor. • Runaway reaction is more likely to occur in presence of the accelerator. • The experimental data support the hypothesis about the accident. - Abstract: This paper analyzes the effect of an accelerator on the polymerisation of methyl methacrylate (MMA). This study is based on the results of an investigation of an accident in a manufacturing site for resins located in the United Kingdom. As sequence of event to cause the accident the following was assumed: during an unattended batch process a runaway undesired polymerisation of methyl methacrylate occurred, generating rapid vaporisation of monomer, which in contact with an ignition source, led to an explosion followed by a fire. Since no initiator for the polymerisation reaction had been jet added to the blend, it was supposed that the accelerator contributed to the onset of the undesired polymerisation. The accelerator involved in the accident t has therefore been tested by differential scanning calorimetry and adiabatic calorimetry. The experimental data allowed the authors to prove the hypothesis made and to define safety ranges for the polymerisation reaction.

  12. Hard X-ray photoelectron spectroscopy study for transport behavior of CsI in heating test simulating a BWR severe accident condition: Chemical effects of boron vapors

    Energy Technology Data Exchange (ETDEWEB)

    Okane, T., E-mail: okanet@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Hyogo, 679-5148 (Japan); Kobata, M. [Quantum Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Hyogo, 679-5148 (Japan); Sato, I. [Oarai Research and Development Center, Japan Atomic Energy Agency, 4002 Narita-cho, Oarai-machi, Ibaraki, 311-1393 (Japan); Kobayashi, K. [Quantum Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Hyogo, 679-5148 (Japan); Osaka, M. [Nuclear Science and Engineering Center, Japan Atomic Energy Agency, 4002 Narita-cho, Oarai-machi, Ibaraki, 311-1393 (Japan); Yamagami, H. [Quantum Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Hyogo, 679-5148 (Japan); Faculty of Science, Kyoto Sangyo University, Motoyama, Kamigamo, Kita-ku, Kyoto, 603-8555 (Japan)

    2016-02-15

    Highlights: • We have clarified the temperature-dependent chemical forms of Cs/I products. • We have examined the CsI-decomposing effects of B{sub 2}O{sub 3} vapor. • The possibility of Cs re-evaporation from CsI-deposited surface is suggested. • We have demonstrated the usefulness of HAXPES on FP chemistry. - Abstract: Transport behavior of CsI in the heating test, which simulated a BWR severe accident, was investigated by hard X-ray photoelectron spectroscopy (HAXPES) with an emphasis on the chemical effect of boron vapors. CsI deposited on metal tube at temperatures ranging from 150 °C to 750 °C was reacted with vapor/aerosol B{sub 2}O{sub 3}, and the chemical form of reaction products on the sample surface was examined from the HAXPES spectra of core levels, e.g., Ni 2p, Cs 3d and I 3d levels, and valence band. For the samples at ∼300 °C, while the chemical form of major product on the sample surface without an exposure to B{sub 2}O{sub 3} was suggested to be CsI from the HAXPES spectra, an intensity ratio of Cs/I was dramatically reduced at the sample surface after the reaction with B{sub 2}O{sub 3}. The results suggest the possibility of significant decomposition of deposited CsI induced by the chemical reaction with B{sub 2}O{sub 3} at specific temperatures.

  13. Investigation into the causes of accidents on scraper systems in the gold and platinum mining sectors

    CSIR Research Space (South Africa)

    Moseme, R

    2003-11-01

    Full Text Available and cleaning operations of the scraper winch systems that require identification. This research report identifies the risk and hazards associated with scraper winch systems that may lead to potential accidents in the gold and platinum sector. The research also...

  14. Pathmorphological investigation of pulmonary infections complications in persons dying from acute radiation sickness after Chernobyl accident

    International Nuclear Information System (INIS)

    Vlasov, P.A.; Kvacheva, Yu.E.

    1993-01-01

    Lungs of 27 persons who participated in liquidation of Chernobyl accident and died from acute radiation sickness were studied histologically. Pulmonary infections were found, including invasion of viral, bacterial and fungal agents. Being depended on hematopoietic function the inflammatory reactions were areactive during postirradiation aplasia and became typical within the recovery beginning

  15. Applying the AcciMap methodology to investigate the tragic Sewol Ferry accident in South Korea.

    Science.gov (United States)

    Lee, Samuel; Moh, Young Bo; Tabibzadeh, Maryam; Meshkati, Najmedin

    2017-03-01

    This study applies the AcciMap methodology, which was originally proposed by Professor Jens Rasmussen (1997), to the analysis of the tragic Sewol Ferry accident in South Korea on April 16, 2014, which killed 304 mostly young people and is considered as a national disaster in that country. This graphical representation, by incorporating associated socio-technical factors into an integrated framework, provides a big-picture to illustrate the context in which an accident occurred as well as the interactions between different levels of the studied system that resulted in that event. In general, analysis of past accidents within the stated framework can define the patterns of hazards within an industrial sector. Such analysis can lead to the definition of preconditions for safe operations, which is a main focus of proactive risk management systems. In the case of the Sewol Ferry accident, a lot of the blame has been placed on the Sewol's captain and its crewmembers. However, according to this study, which relied on analyzing all available sources published in English and Korean, the disaster is the result of a series of lapses and disregards for safety across different levels of government and regulatory bodies, Chonghaejin Company, and the Sewol's crewmembers. The primary layers of the AcciMap framework, which include the political environment and non-proactive governmental body; inadequate regulations and their lax oversight and enforcement; poor safety culture; inconsideration of human factors issues; and lack of and/or outdated standard operating and emergency procedures were not only limited to the maritime industry in South Korea, and the Sewol Ferry accident, but they could also subject any safety-sensitive industry anywhere in the world. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. An endothermic chemical process facility coupled to a high temperature reactor. Part II: Transient simulation of accident scenarios within the chemical plant

    International Nuclear Information System (INIS)

    Brown, Nicholas R.; Revankar, Shripad T.

    2012-01-01

    Highlights: ► Seven quantitative transient case studies were analyzed in a coupled PBMR and thermochemical sulfur cycle based hydrogen plant. ► Positive power excursion in the nuclear reactor were found for helium-inlet overcoolings. ► In all cases studied the maximum fuel temperatures in the nuclear reactor were 200 K below the design basis limit. - Abstract: Hydrogen generation using a high temperature nuclear reactor as a thermal driving vector is a promising future option for energy carrier production. In this scheme, the heat from the nuclear reactor drives an endothermic water-splitting plant, via coupling, through an intermediate heat exchanger. Transient study of the operational or accident events within the coupled plant is largely absent from the literature. In this paper, seven quantitative transient case studies are analyzed. The case studies consist of: (1) feed flow failure from one section of the chemical plant to another with an accompanying parametric study of the temperature in an individual reaction chamber, (2) product flow failure (recycle) within the chemical plant, (3) rupture or explosion within the chemical plant, (4) nuclear reactor helium inlet overcooling due to a process holding tank failure, (5) helium inlet overcooling as an anticipated transient without emergency nuclear reactor shutdown, (6) total failure of the chemical plant, (7) control rod insertion in the nuclear reactor. Various parametric studies based on the magnitude of the events were also performed. The only chemical plant initiated events that caused a positive power excursion in the nuclear reactor were helium-inlet overcoolings due to process holding tank failures or reaction chamber ruptures. Even for a severe sustained overcooling, the calculated maximum fuel temperatures in the nuclear reactor were 200 K below the design basis limit. The qualitative basis for the case studies and the analysis models are summarized in part I of this paper.

  17. Systematic approach for assessment of accident risks in chemical and nuclear processing; Abordagem sistematica para avaliacao de riscos de acidentes em instalacoes de processamento quimico e nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Senne, Junior, Murillo

    2003-07-15

    The industrial accidents which occurred in the last years, particularly in the 80's, contributed a significant way to draw the attention of the government, industry and the society as a whole to the mechanisms for preventing events that could affect people's safety and the environment quality. Techniques and methods extensively used the nuclear, aeronautic and war industries so far were adapted to performing analysis and evaluation of the risks associated to other industrial activities, especially in the petroleum, chemistry and petrochemical areas. The risk analysis in industrial facilities is carried out through the evaluation of the probability or frequency of the accidents and their consequences. However, no systematized methodology that could supply the tools for identifying possible accidents likely to take place in an installation is available in the literature. Neither existing are methodologies for the identification of the models for evaluation of the accidents' consequences nor for the selection of the available techniques for qualitative or quantitative analysis of the possibility of occurrence of the accident being focused. The objective of this work is to develop and implement a methodology for identification of the risks of accidents in chemical and nuclear processing facilities as well as for the evaluation of their consequences on persons. For the development of the methodology, the main possible accidents that could occur in such installations were identified and the qualitative and quantitative techniques available for the identification of the risks and for the evaluation of the consequences of each identified accidents were selected. The use of the methodology was illustrated by applying it in two case examples adapted from the literature, involving accidents with inflammable, explosives, and radioactive materials. The computer code MRA - Methodology for Risk Assessment was developed using DELPHI, version 5.0, with the purpose of systematizing

  18. Systematic approach for assessment of accident risks in chemical and nuclear processing; Abordagem sistematica para avaliacao de riscos de acidentes em instalacoes de processamento quimico e nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Senne Junior, Murillo

    2003-07-15

    The industrial accidents which occurred in the last years, particularly in the 80's, contributed a significant way to draw the attention of the government, industry and the society as a whole to the mechanisms for preventing events that could affect people's safety and the environment quality. Techniques and methods extensively used the nuclear, aeronautic and war industries so far were adapted to performing analysis and evaluation of the risks associated to other industrial activities, especially in the petroleum, chemistry and petrochemical areas. The risk analysis in industrial facilities is carried out through the evaluation of the probability or frequency of the accidents and their consequences. However, no systematized methodology that could supply the tools for identifying possible accidents likely to take place in an installation is available in the literature. Neither existing are methodologies for the identification of the models for evaluation of the accidents' consequences nor for the selection of the available techniques for qualitative or quantitative analysis of the possibility of occurrence of the accident being focused. The objective of this work is to develop and implement a methodology for identification of the risks of accidents in chemical and nuclear processing facilities as well as for the evaluation of their consequences on persons. For the development of the methodology, the main possible accidents that could occur in such installations were identified and the qualitative and quantitative techniques available for the identification of the risks and for the evaluation of the consequences of each identified accidents were selected. The use of the methodology was illustrated by applying it in two case examples adapted from the literature, involving accidents with inflammable, explosives, and radioactive materials. The computer code MRA - Methodology for Risk Assessment was developed using DELPHI, version 5.0, with the purpose of

  19. Investigations on the Chemical Degradation of Silver Gelatine Prints

    Directory of Open Access Journals (Sweden)

    Maha Ahmed ALI

    2012-06-01

    Full Text Available Photographs are considered composite objects with complex chemical and physical structures. Therefore they are more prone to damage as compared to other objects. Chemical degradation is by far the most common decay form found among photographic collections. This study investigates the chemical degradation of silver gelatin prints (DOP and the reaction of the image, silver, gelatin, and paper to accelerated aging, to the action of light, and oxidizing gases, in terms of their physical and chemical nature. The test materials used are properly washed and poorly washed grayscale, black-and-white processed images on photographic paper (Black & White Photographic Paper BH 0 Bromofort 6P0661 Tropical from Forte Photochemical Company Vác, Hungary. After exposure, the results were studied by means of visual inspection, amino acid analyzer, Fourier transform infrared and transmission electron microscope. The results were compared with those of the control samples. Our study revealed that the image, silver, gelatin and photographic paper are greatly affected by oxidizing agents and that the effect increased if the photographic prints were inadequately washed at the time of their processing. Furthermore, our results indicated that an increased amount of ammonia and amino acid in the silver gelatin print is a reliable indicator of the degradation of its gelatine emulsion.

  20. Accidents - Chernobyl accident; Accidents - accident de Tchernobyl

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This file is devoted to the Chernobyl accident. It is divided in four parts. The first part concerns the accident itself and its technical management. The second part is relative to the radiation doses and the different contaminations. The third part reports the sanitary effects, the determinists ones and the stochastic ones. The fourth and last part relates the consequences for the other European countries with the case of France. Through the different parts a point is tackled with the measures taken after the accident by the other countries to manage an accident, the cooperation between the different countries and the groups of research and studies about the reactors safety, and also with the international medical cooperation, specially for the children, everything in relation with the Chernobyl accident. (N.C.)

  1. Accident analysis of railway transportation of low-level radioactive and hazardous chemical wastes: Application of the /open quotes/Maximum Credible Accident/close quotes/ concept

    Energy Technology Data Exchange (ETDEWEB)

    Ricci, E.; McLean, R.B.

    1988-09-01

    The maximum credible accident (MCA) approach to accident analysis places an upper bound on the potential adverse effects of a proposed action by using conservative but simplifying assumptions. It is often used when data are lacking to support a more realistic scenario or when MCA calculations result in acceptable consequences. The MCA approach can also be combined with realistic scenarios to assess potential adverse effects. This report presents a guide for the preparation of transportation accident analyses based on the use of the MCA concept. Rail transportation of contaminated wastes is used as an example. The example is the analysis of the environmental impact of the potential derailment of a train transporting a large shipment of wastes. The shipment is assumed to be contaminated with polychlorinated biphenyls and low-level radioactivities of uranium and technetium. The train is assumed to plunge into a river used as a source of drinking water. The conclusions from the example accident analysis are based on the calculation of the number of foreseeable premature cancer deaths the might result as a consequence of this accident. These calculations are presented, and the reference material forming the basis for all assumptions and calculations is also provided.

  2. Accident analysis of railway transportation of low-level radioactive and hazardous chemical wastes: Application of the /open quotes/Maximum Credible Accident/close quotes/ concept

    International Nuclear Information System (INIS)

    Ricci, E.; McLean, R.B.

    1988-09-01

    The maximum credible accident (MCA) approach to accident analysis places an upper bound on the potential adverse effects of a proposed action by using conservative but simplifying assumptions. It is often used when data are lacking to support a more realistic scenario or when MCA calculations result in acceptable consequences. The MCA approach can also be combined with realistic scenarios to assess potential adverse effects. This report presents a guide for the preparation of transportation accident analyses based on the use of the MCA concept. Rail transportation of contaminated wastes is used as an example. The example is the analysis of the environmental impact of the potential derailment of a train transporting a large shipment of wastes. The shipment is assumed to be contaminated with polychlorinated biphenyls and low-level radioactivities of uranium and technetium. The train is assumed to plunge into a river used as a source of drinking water. The conclusions from the example accident analysis are based on the calculation of the number of foreseeable premature cancer deaths the might result as a consequence of this accident. These calculations are presented, and the reference material forming the basis for all assumptions and calculations is also provided

  3. A study of maintenance-related major accident cases in the 21st century

    OpenAIRE

    Okoh, Peter; Haugen, Stein

    2014-01-01

    This paper is based on a review of 183 detailed, major accident investigation and analysis reports related to the handling, processing and storage of hydrocarbons and hazardous chemicals over a decade from 2000 to 2011. The reports cover technical, human and organizational factors. In this paper, the Work and Accident Process (WAP) classification scheme is applied to the accident reports with the intention of investigating to what extent maintenance has been a cause of major accidents and wha...

  4. Evaluation of total loss of feedwater accident/recovery phase and investigation of the associated EOP

    International Nuclear Information System (INIS)

    Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung

    1993-01-01

    To evaluate the sequence of event and the thermohydraulic behavior during total loss of feedwater accident and recovery procedure, a RELAP5/MOD3 calculation is performed and compared with the LOFT L9-1/L3-3 experiment. Also, the predictability of the code for the major thermohydraulic phenomena following the accident is assessed. As a result, it is found that a pressure control using the spray until the time the water level reaches the top of the pressurizer, an overpressure protection by pressurizer PORV, a recovery of the secondary heat removal capability by refilling steam generator, and an effective cooldown by the continued natural circulation can be perfomed without core uncovery. It is also found that the plantspecific evaluation is necessary to confirm the effectiveness of the current symptom-oriented emergency operating procedure, especially in an overpressure protection performance and steam generator recovery performance. (Author)

  5. Recreational Boat Safety Collision Research - Phase 2. Volume 2. Collision Accident Investigations - 1975

    Science.gov (United States)

    1976-07-01

    Collisfon - .t tone person in a runabout wus pulling a skier and was turned, looking aft. He hit a johnboat. Thw ;ohnboat...based on the narrotive, the boat load distribution, and knowledge of the boat charactens;, .: From the load dstribution, it can be assumed that the boat...visibility) and the operator’s lack of knowledge of where he was and the characteristics of this harbor were the primary causes of this accident, along with

  6. Immunological and epidemiological investigations in regions contaminated by radionuclides after the Chernobyl accident

    Energy Technology Data Exchange (ETDEWEB)

    Shubik, V M [Institute of Radiation Hygiene, St. Petersburg (Russian Federation)

    1997-09-01

    We have carried out in Novozybkov district of Bryansk region, Russia, immunologic inspection of residents with simultaneous evaluation of radionuclides content in the body and individual dose burden. We have not found any correlation between the dose and immune characteristics: amount of T and B lymphocytes, antibodies level. Only 3 months after the accident increased level of antibodies against thyroid antigens, thyroglobulin and microsomes was found at thyroid doses over 75 cGy. 3 tabs.

  7. Immunological and epidemiological investigations in regions contaminated by radionuclides after the Chernobyl accident

    International Nuclear Information System (INIS)

    Shubik, V.M.

    1997-01-01

    We have carried out in Novozybkov district of Bryansk region, Russia, immunologic inspection of residents with simultaneous evaluation of radionuclides content in the body and individual dose burden. We have not found any correlation between the dose and immune characteristics: amount of T and B lymphocytes, antibodies level. Only 3 months after the accident increased level of antibodies against thyroid antigens, thyroglobulin and microsomes was found at thyroid doses over 75 cGy. 3 tabs

  8. Posture control and the risk of industrial accident: a stabilographic investigation in a naval shipyard.

    Science.gov (United States)

    Moll van Charante, A W; Snijders, C J; Mulder, P G

    1991-10-01

    In a previous case-control study on the effect of impaired perceptual acuity on the risk of industrial injuries at a naval shipyard, three factors which might influence the perception and processing of sensory impressions--alcohol consumption, hearing loss exceeding 20 decibels (dB) and exposure to noise exceeding 82 dB(A)--were found to contribute to the risk of injury. According to recent reports, these factors can all lead to impaired posture control. Because in general about 40% of all accidents are associated with falling, tripping, slipping and the like, a supplementary study has been carried out to unravel possible confounding effects of posture control on these three risk factors. Cases (who had suffered two or more accidents during the preceding 4 years) and controls (who had been accident-free in the same period) were compared as regards posture control measured during silence or noise. No significant difference in posture control was found between cases and controls, either in silence or during exposure to heavy noise.

  9. Type A Accident Investigation Board report on the January 17, 1996, electrical accident with injury in Technical Area 21 Tritium Science and Fabrication Facility Los Alamos National Laboratory. Final report

    International Nuclear Information System (INIS)

    1996-04-01

    An electrical accident was investigated in which a crafts person received serious injuries as a result of coming into contact with a 13.2 kilovolt (kV) electrical cable in the basement of Building 209 in Technical Area 21 (TA-21-209) in the Tritium Science and Fabrication Facility (TSFF) at Los Alamos National Laboratory (LANL). In conducting its investigation, the Accident Investigation Board used various analytical techniques, including events and causal factor analysis, barrier analysis, change analysis, fault tree analysis, materials analysis, and root cause analysis. The board inspected the accident site, reviewed events surrounding the accident, conducted extensive interviews and document reviews, and performed causation analyses to determine the factors that contributed to the accident, including any management system deficiencies. Relevant management systems and factors that could have contributed to the accident were evaluated in accordance with the guiding principles of safety management identified by the Secretary of Energy in an October 1994 letter to the Defense Nuclear Facilities Safety Board and subsequently to Congress

  10. Type A Accident Investigation Board report on the January 17, 1996, electrical accident with injury in Technical Area 21 Tritium Science and Fabrication Facility Los Alamos National Laboratory. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    An electrical accident was investigated in which a crafts person received serious injuries as a result of coming into contact with a 13.2 kilovolt (kV) electrical cable in the basement of Building 209 in Technical Area 21 (TA-21-209) in the Tritium Science and Fabrication Facility (TSFF) at Los Alamos National Laboratory (LANL). In conducting its investigation, the Accident Investigation Board used various analytical techniques, including events and causal factor analysis, barrier analysis, change analysis, fault tree analysis, materials analysis, and root cause analysis. The board inspected the accident site, reviewed events surrounding the accident, conducted extensive interviews and document reviews, and performed causation analyses to determine the factors that contributed to the accident, including any management system deficiencies. Relevant management systems and factors that could have contributed to the accident were evaluated in accordance with the guiding principles of safety management identified by the Secretary of Energy in an October 1994 letter to the Defense Nuclear Facilities Safety Board and subsequently to Congress.

  11. Recovery from a chemical weapons accident or incident: A concept paper on planning

    Energy Technology Data Exchange (ETDEWEB)

    Herzenberg, C.L.; Haffenden, R.; Lerner, K.; Meleski, S.A.; Tanzman, E.A. [Argonne National Lab., IL (United States); Lewis, L.M. [US Dept. of Agriculture (United States); Hemphill, R.C. [Niagara Mohawk Power Corporation (United States); Adams, J.D. [US Environmental Protection Agency (United States)

    1994-04-01

    Emergency planning for an unintended release of chemical agent from the nation`s chemical weapons stockpile should include preparation for. the period following implementation of immediate emergency response. That period -- the recovery, reentry, and restoration stage -- is the subject of this report. The report provides an overview of the role of recovery, reentry, and restoration planning in the Chemical Stockpile Emergency Preparedness Program (CSEPP), describes the transition from immediate emergency response to restoration, and analyzes the legal framework that would govern restoration activities. Social, economic, and administrative issues, as well as technical ones, need to be considered in the planning effort. Because of possible jurisdictional conflicts, appropriate federal, state, and local agencies need to be included in a coordinated planning process. Advance consideration should be given to the pertinent federal and state statutes and regulations. On the federal level, the principal statutes and regulations to be considered are those associated with the Comprehensive Environmental Response, Compensation, and Liability Act; the Resource Conservation and Recovery Act; and the National Environmental Policy Act. This report recommends that extensive preaccident planning be undertaken for the recovery, reentry, and restoration stage and outlines several key issues that should be considered in that planning. The need for interagency cooperation and coordination at all levels of the planning process is emphasized.

  12. A computer investigation of chemically mediated detachment in bacterial biofilms.

    Science.gov (United States)

    Hunt, Stephen M; Hamilton, Martin A; Sears, John T; Harkin, Gary; Reno, Jason

    2003-05-01

    A three-dimensional computer model was used to evaluate the effect of chemically mediated detachment on biofilm development in a negligible-shear environment. The model, BacLAB, combines conventional diffusion-reaction equations for chemicals with a cellular automata algorithm to simulate bacterial growth, movement and detachment. BacLAB simulates the life cycle of a bacterial biofilm from its initial colonization of a surface to the development of a mature biofilm with cell areal densities comparable to those in the laboratory. A base model founded on well established transport equations that are easily adaptable to investigate conjectures at the biological level has been created. In this study, the conjecture of a detachment mechanism involving a bacterially produced chemical detachment factor in which high local concentrations of this detachment factor cause the bacteria to detach from the biofilm was examined. The results show that the often observed 'mushroom'-shaped structure can occur if detachment events create voids so that the remaining attached cells look like mushrooms.

  13. Chemical structure investigation on SFEF fractions of Dagang vacuum residue

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z.; Yan, G.; Zhao, S.; Guo, S. [China Univ. of Petroleum, Beijing (China). State Key Laboratory of Heavy Oil Processing; Zhang, Z. [Beijing Aeronautical Technology Research Center, Beijing (China)

    2006-07-01

    One of the most important problems in petroleum chemistry is the molecular structure and composition of heavy oil fractions and its importance in applications pertaining to the recovery, refining, and upgrading of petroleum. This paper presented an investigation into the chemical structure on supercritical fluid extraction and fraction (SFEF) factions of Dagang vacuum residue. Dagang vacuum residue was cut into sixteen fractions and a tailing with SFEF instrument. Then, using a chromatography, all SFEF fractions were further separated into four group compositions, notably saturated hydrocarbons, aromatic hydrocarbons, resins and asphaltenes (SARA). Last, the chemical structure was explored through a thorough analysis of the products from the ruthenium ions-catalyzed oxidation (RICO) reaction of those aromatics, resins and asphaltenes. The paper discussed the experiment in terms of samples and chemicals; supercritical fluid extraction and fraction; SARA separation; and RICO. The results and discussions focused on alkyl side chains attached to aromatic carbon; polymethylene bridges connecting two aromatic units; benzenecarboxylic acids an aromatic units; and others. The study has brought to light useful characterization on covalent molecular structure of two typical SFEF fractions, notably the tenth and fifteen fraction. 17 refs., 6 tabs., 16 figs., 1 appendix.

  14. Investigating the multi-causal and complex nature of the accident causal influence of construction project features.

    Science.gov (United States)

    Manu, Patrick A; Ankrah, Nii A; Proverbs, David G; Suresh, Subashini

    2012-09-01

    Construction project features (CPFs) are organisational, physical and operational attributes that characterise construction projects. Although previous studies have examined the accident causal influence of CPFs, the multi-causal attribute of this causal phenomenon still remain elusive and thus requires further investigation. Aiming to shed light on this facet of the accident causal phenomenon of CPFs, this study examines relevant literature and crystallises the attained insight of the multi-causal attribute by a graphical model which is subsequently operationalised by a derived mathematical risk expression that offers a systematic approach for evaluating the potential of CPFs to cause harm and consequently their health and safety (H&S) risk implications. The graphical model and the risk expression put forth by the study thus advance current understanding of the accident causal phenomenon of CPFs and they present an opportunity for project participants to manage the H&S risk associated with CPFs from the early stages of project procurement. Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. XPS and EPXMA investigation and chemical speciation of aerosol samples formed in LWR core melting experiments

    International Nuclear Information System (INIS)

    Moers, H.; Jenett, H.; Kaufmann, R.; Klewe-Nebenius, H.; Pfennig, G.; Ache, H.J.

    1985-09-01

    Aerosol samples consisting of fission products and elements of light water reactor structural materials were collected during simulating in a laboratory scale the heat-up phase of a core melt accident. The aerosol particles were formed in a steam atmosphere at temperatures between 1200 and 1900 0 C of the melting charge. The investigation of the samples by use of X-ray photoelectron spectroscopy (XPS) permitted the chemical speciation of the detected aerosol constituents silver, cadmium, indium, tellurium, iodine, and cesium. A comparison of the elemental analysis results obtained from XPS with those achieved from electron probe X-ray micro analysis (EPXMA) revealed that aerosol particle surface and aerosol particle bulk are principally composed of the same elements and that these compositions vary with release temperature. In addition, quantitative differences between the composition of surface and bulk have only been observed for those aerosol samples which were collected at higher melting charge temperatures. In order to obtain direct information on chemical species below the surface selected samples were argon ion bombarded. Changes in composition and chemistry were monitored by XPS, and the results were interpreted in light of the effects, which were observed when appropriate standard samples were sputtered. (orig.) [de

  16. The investigation of Passive Accident Mitigation Scheme for advanced PWR NPP

    International Nuclear Information System (INIS)

    Shi, Er-bing; Fang, Cheng-yue; Wang, Chang; Xia, Geng-lei; Zhao, Cui-na

    2015-01-01

    Highlights: • We put forward a new PAMS and analyze its operation characteristics under SBO. • We conduct comparative analysis between PAMS and Traditional Secondary Side PHRS. • The PAMS could cope with SBO accident and maintain the plant in safe conditions. • PAMS could decrease heat removal capacity of PHRS. • PAMS has advantage in reducing cooling rate and PCCT temperature rising amplitude. - Abstract: To enhance inherent safety features of nuclear power plant, the advanced pressurized water reactors implement a series of passive safety systems. This paper puts forward and designs a new Passive Accident Mitigation Scheme (PAMS) to remove residual heat, which consists of two parts: the first part is Passive Auxiliary Feedwater System (PAFS), and the other part is Passive Heat Removal System (PHRS). This paper takes the Westinghouse-designed Advanced Passive PWR (AP1000) as research object and analyzes the operation characteristics of PAMS to cope with the Station Blackout Accident (SBO) by using RELAP5 code. Moreover, the comparative analysis is also conducted between PAMS and Traditional Secondary Circuit PHRS to derive the advantages of PAMS. The results show that the designed scheme can remove core residual heat significantly and maintain the plant in safe conditions; the first part of PAMS would stop after 120 min and the second part has to come into use simultaneously; the low pressurizer (PZR) pressure signal would be generated 109 min later caused by coolant volume shrinkage, which would actuate the Passive Safety Injection System (PSIS) to recovery the water level of pressurizer; the flow instability phenomenon would occur and last 21 min after the PHRS start-up; according to the comparative analysis, the coolant average temperature gradient and the Passive Condensate Cooling Tank (PCCT) water temperature rising amplitude of PAMS are lower than those of Traditional Secondary Circuit PHRS

  17. Investigation of a Monte Carlo model for chemical reactions

    International Nuclear Information System (INIS)

    Hamm, R.N.; Turner, J.E.; Stabin, M.G.

    1998-01-01

    Monte Carlo computer simulations are in use at a number of laboratories for calculating time-dependent yields, which can be compared with experiments in the radiolysis of water. We report here on calculations to investigate the validity and consistency of the procedures used for simulating chemical reactions in our code, RADLYS. Model calculations were performed of the rate constants themselves. The rates thus determined showed an expected rapid decline over the first few hundred ps and a very gradual decline thereafter out to the termination of the calculations at 4.5 ns. Results are reported for different initial concentrations and numbers of reactive species. Generally, the calculated rate constants are smallest when the initial concentrations of the reactants are largest. It is found that inhomogeneities that quickly develop in the initial random spatial distribution of reactants persist in time as a result of subsequent chemical reactions, and thus conditions may poorly approximate those assumed from diffusion theory. We also investigated the reaction of a single species of one type placed among a large number of randomly distributed species of another type with which it could react. The distribution of survival times of the single species was calculated by using three different combinations of the diffusion constants for the two species, as is sometimes discussed in diffusion theory. The three methods gave virtually identical results. (orig.)

  18. The physical and chemical degradation of PWR fuel rods in severe accident conditions

    International Nuclear Information System (INIS)

    Parsons, P.D.; Mowat, J.A.S.; Dewhurst, D.W.F.; Hughes, T.E.

    1983-01-01

    An experimental study of the interaction between Zircaloy-4 cladding and UO 2 in PWR fuel rods heated to high temperatures with a negligible differential pressure across the cladding wall is described. The fuel rods were of dimensions appropriate to the 17x17 PWR fuel sub-assembly and were heated in a non-oxidising environment (vacuum) up to approx. 1850 deg. C either isothermally or through heating ramps. Observations were made concerning the extent and nature of the reaction zone between Zircaloy-4 and UO 2 over the temperature range 1500-1850 deg. C for times ranging from 1 min to 125 min. The location, morphology and the chemical composition of the phases formed are described along with the kinetics of their formation. (author)

  19. Investigation of controlled flight into terrain : descriptions of flight paths for selected controlled flight into terrain (CFIT) aircraft accidents, 1985-1997

    Science.gov (United States)

    1999-03-01

    This report documents an investigation of the flight paths of 13 selected controlled flight into terrain (CFIT) aircraft accidents that occurred between 1985 and 1997. The Operations Assessment Division (DTS-43) and the Aviation Safety Division (DTS-...

  20. Investigation into radiation-chemical transformations of polyamide P-54

    International Nuclear Information System (INIS)

    Khabarov, V.N.; Kozlov, L.L.; Panchenkov, G.M.

    1981-01-01

    Investigation results of alcohol-soluble polyamide P-54 radiolysis by different physicochemical methods are presented. It has been established that under the effect of γ-radiation certain processes take place in polyamide, which are connected with branching, structurization and destruction of macromolecules. Radiation-chemical yields of gaseous products during irradiation in the air and in vacuum at irradiation temperatures from 273 to 393 K are calculated. The ratio of the rates of lacing and destruction processes is found and radiation yields of the processes are determined. Under irradiation in the air at temperatures >333 K chain oxidation of P-54 takes place and the growth of pe-- roxide compounds with 8 molecules/100 eV at 298 K up to 135 mole-- cules/100 eV at irradiation temperature 373 K testifies to the fact

  1. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 1 – Aluminum

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Kerry J., E-mail: howe@unm.edu [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Mitchell, Lana, E-mail: lmitchell@alionscience.com [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Kim, Seung-Jun, E-mail: skim@lanl.gov [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Blandford, Edward D., E-mail: edb@unm.edu [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Kee, Ernest J., E-mail: erniekee@gmail.com [South Texas Project Nuclear Operating Company, P.O. Box 270, Wadsworth, TX 77483 (United States)

    2015-10-15

    Highlights: • Trisodium phosphate (TSP) causes aluminum corrosion to cease after 24 h of exposure. • Chloride, iron, and copper have a minimal effect on the rate of aluminum corrosion when TSP is present. • Zinc can reduce the rate of aluminum corrosion when TSP is present. • Aluminum occasionally precipitates at concentrations lower than the calculated solubility for Al(OH){sub 3}. • Corrosion and solubility equations can be used to calculate the solids generated during a LOCA. - Abstract: Bench experiments were conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of aluminum from metallic aluminum surfaces under conditions representative of the containment pool following a postulated loss of coolant accident at a nuclear power generating facility. The experiments showed that TSP is capable of passivating the aluminum surface and preventing continued corrosion after about 24 h at the conditions tested. A correlation that describes the rate of corrosion including the passivation effect was developed from the bench experiments and validated with a separate set of experiments from a different test system. The saturation concentration of aluminum was shown to be well described by the solubility of amorphous aluminum hydroxide for the majority of cases, but instances have been observed when aluminum precipitates at concentrations lower than the calculated aluminum hydroxide solubility. Based on the experimental data and previous literature, an equation was developed to calculate the saturation concentration of aluminum as a function of pH and temperature under conditions representative of a loss of coolant accident (LOCA) in a TSP-buffered pressurized water reactor (PWR) containment. The corrosion equation and precipitation equation can be used in concert with each other to calculate the quantity of solids that would form as a function of time during a LOCA if the temperature and pH profiles were known.

  2. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 1 – Aluminum

    International Nuclear Information System (INIS)

    Howe, Kerry J.; Mitchell, Lana; Kim, Seung-Jun; Blandford, Edward D.; Kee, Ernest J.

    2015-01-01

    Highlights: • Trisodium phosphate (TSP) causes aluminum corrosion to cease after 24 h of exposure. • Chloride, iron, and copper have a minimal effect on the rate of aluminum corrosion when TSP is present. • Zinc can reduce the rate of aluminum corrosion when TSP is present. • Aluminum occasionally precipitates at concentrations lower than the calculated solubility for Al(OH) 3 . • Corrosion and solubility equations can be used to calculate the solids generated during a LOCA. - Abstract: Bench experiments were conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of aluminum from metallic aluminum surfaces under conditions representative of the containment pool following a postulated loss of coolant accident at a nuclear power generating facility. The experiments showed that TSP is capable of passivating the aluminum surface and preventing continued corrosion after about 24 h at the conditions tested. A correlation that describes the rate of corrosion including the passivation effect was developed from the bench experiments and validated with a separate set of experiments from a different test system. The saturation concentration of aluminum was shown to be well described by the solubility of amorphous aluminum hydroxide for the majority of cases, but instances have been observed when aluminum precipitates at concentrations lower than the calculated aluminum hydroxide solubility. Based on the experimental data and previous literature, an equation was developed to calculate the saturation concentration of aluminum as a function of pH and temperature under conditions representative of a loss of coolant accident (LOCA) in a TSP-buffered pressurized water reactor (PWR) containment. The corrosion equation and precipitation equation can be used in concert with each other to calculate the quantity of solids that would form as a function of time during a LOCA if the temperature and pH profiles were known

  3. Safety Culture: Lessons Learned from the US Chemical Safety and Hazard Investigations Board

    International Nuclear Information System (INIS)

    Griffon, M.

    2016-01-01

    The U.S. Chemical Safety and Hazard Investigation Board (CSB) investigation of the 2005 BP Texas City Refinery disaster as well as the Baker Panel Report have set the stage for the consideration of human and organizational factors and safety culture as contributing causes of major accidents in the oil and gas industry. The investigation of the BP Texas City tragedy in many ways started a shift in the way the oil and chemical industry sectors looked at process safety and the importance of human and organizational factors in improving safety. Since the BP Texas City incident the CSB has investigated several incidents, including the 2010 Macondo disaster in the Gulf of Mexico, where organizational factors and safety culture, once again, were contributing causes of the incidents. In the Texas City incident the CSB found that “while most attention was focused on the injury rate, the overall safety culture and process safety management (PSM) program had serious deficiencies.” The CSB concluded that “safety campaigns, goals, and rewards focused on improving personal safety metrics and worker behaviors rather than on process safety and management safety systems.” The Baker panel, established as a result of a CSB recommendation, did a more extensive review of BPs safety culture. The Baker panel found that ‘while BP has aspirational goals of “no accidents, no harm to people” BP has not provided effective leadership in making certain it’s management and US refining workforce understand what is expected of them regarding process safety performance.’ This may have been in part due to a misinterpretation of positive trends in personal injury rates as an indicator of effective process safety. The panel also found that “at some of its US refineries BP has not established a positive, trusting and open environment with effective lines of communication between management and the workforce, including employee representatives.” In 2010 when the CSB began to

  4. Prevention and investigations of core degradation in case of beyond design accidents of the 2400 MWTH gas-cooled fast reactor

    International Nuclear Information System (INIS)

    Bertrand, F.; Gatin, V.; Bentivoglio, F.; Gueneau, C.

    2011-01-01

    The present paper deals with studies carried out to assess the ability of the core of the Gas Fast Reactor (GFR) to withstand beyond design accidents. The work presented here is aimed at simulating the behaviour of this core by using analytical models whose input parameters are calculated with the CATHARE2 code. Among possible severe accident initiators, the Unprotected Loss Of Coolant Accident (ULOCA of 3 Inches diameter) is investigated in detail in the paper with CATHARE2. Additionally, a simplified pessimistic assessment of the effect of a postulated power excursion that could result from the failure of prevention provisions is presented. (author)

  5. Experimental Investigation of Operation of VVER Steam Generator in Condensation Mode in the Event of the Severe Accident

    Energy Technology Data Exchange (ETDEWEB)

    Morozov, Andrey [Institute for Physics and Power Engineering by A.I. Leypunsky, 1 Bondarenko sq. Obninsk, 249033 (Russian Federation)

    2008-07-01

    For new Russian nuclear power plants with VVER-1200 reactor in the event of a beyond design basis accident, provision is made for the use of passive safety systems for necessary core cooling. These safety systems include the passive heat removal system (PHRS). In the case of leakage in the primary circuit this system assures the transition of steam generators (SG) to operation in the mode of condensation of the primary circuit steam. As a result, the condensate from SG arrives at the core providing its additional cooling. To investigate the condensation mode of VVER SG operation, a large scale HA2M-SG test facility was constructed. The rig incorporates: buffer tank, SG model with scale is 1:46, PHRS heat exchanger. Experiments at the test facility have been performed to investigate condensation mode of operation of SG model at the pressure 0.4 MPa, correspond to VVER reactor pressure at the last stage of the beyond design basis accident. The report presents the test procedure and the basic obtained test results. (authors)

  6. Structural investigation of chemically synthesized ferrite magnetic nanomaterials

    Science.gov (United States)

    Uyanga, E.; Sangaa, D.; Hirazawa, H.; Tsogbadrakh, N.; Jargalan, N.; Bobrikov, I. A.; Balagurov, A. M.

    2018-05-01

    In recent times, interest in ferrite magnetic nanomaterials has considerably grown, mainly due to their highly promising medical and biological applications. Spinel ferrite powder samples, with high heat generation abilities in AC magnetic fields, were studied for their application to the hyperthermia treatment of cancer tumors. These properties of ferrites strongly depend on their chemical composition, ion distribution between crystallographic positions, magnetic structure and method of preparation. In this study, crystal and magnetic structures of several magnetic spinels were investigated by neutron diffraction. The explanation of the mechanism triggering the heat generation ability in the magnetic materials, and the electronic and magnetic states of ferrite-spinel type structures, were theoretically defined by a first-principles method. Ferrites with the composition of CuxMg1-xFe2O4 have been investigated as a heat generating magnetic nanomaterial. Atomic fraction of copper in ferrite was varied between 0 and 100% (that is, x between 0 and 1.0 with 0.2 steps), with the copper dope limit corresponding to appear a tetragonal phase.

  7. An experimental investigation of chemical communication in the polar bear

    Science.gov (United States)

    Owen, Megan A.; Swaisgood, Ronald R.; Slocomb, C.; Amstrup, Steven C.; Durner, George M.; Simac, Kristin S.; Pessier, Allan P.

    2015-01-01

    The polar bear (Ursus maritimus), with its wide-ranging movements, solitary existence and seasonal reproduction, is expected to favor chemosignaling over other communication modalities. However, the topography of its Arctic sea ice habitat is generally lacking in stationary vertical substrates routinely used for targeted scent marking in other bears. These environmental constraints may have shaped a marking strategy, unique to polar bears, for widely dispersed continuous dissemination of scent via foot pads. To investigate the role of chemical communication, pedal scents were collected from free-ranging polar bears of different sex and reproductive classes captured on spring sea ice in the Beaufort and Chukchi seas, and presented in a controlled fashion to 26 bears in zoos. Results from behavioral bioassays indicated that bears, especially females, were more likely to approach conspecific scent during the spring than the fall. Male flehmen behavior, indicative of chemosignal delivery to the vomeronasal organ, differentiated scent donor by sex and reproductive condition. Histologic examination of pedal skin collected from two females indicated prominent and profuse apocrine glands in association with large compound hair follicles, suggesting that they may produce scents that function as chemosignals. These results suggest that pedal scent, regardless of origin, conveys information to conspecifics that may facilitate social and reproductive behavior, and that chemical communication in this species has been adaptively shaped by environmental constraints of its habitat. However, continuously distributed scent signals necessary for breeding behavior may prove less effective if current and future environmental conditions cause disruption of scent trails due to increased fracturing of sea ice.

  8. Investigation of Focusing Effect according to the Cooling Condition and Height of the Metallic layer in a Severe Accident

    Energy Technology Data Exchange (ETDEWEB)

    Moon, Je-Young; Chung, Bum-Jin [Kyung Hee University, Yongin (Korea, Republic of)

    2015-05-15

    The Fukushima nuclear power plant accident has led to renewed research interests in severe accidents of nuclear power plants. In-Vessel Retention (IVR) of core melt is one of key severe accident management strategies adopted in nuclear power plant design. The metallic layer is heated from below by the radioactive decay heat generated at the oxide pool, and is cooled from above and side walls. During the IVR process, reactor vessel may be cooled externally (ERVC) and the heat fluxes to the side wall increase with larger temperature difference than above. This {sup F}ocusing effect{sup i}s varied by cooling condition of upper boundary and height of the metallic layer. A sulfuric acid–copper sulfate (H{sub 2}SO{sub 4} - CuSO{sub 4}) electroplating system was adopted as the mass transfer system. Numerical analysis using the commercial CFD program FLUENT 6.3 were carried out with the same material properties and cooling conditions to examine the variation of the cell. The experimental and numerical studies were performed to investigate the focusing effect according to cooling condition of upper boundary and the height in metallic layer. The height of the side wall was varied for three different cooling conditions: top only, side only, and both top and side. Mass transfer experiments, based on the analogy concept, were carried out in order to achieve high Rayleigh number. The experimental results agreed well with the Rayleigh-Benard convection correlations of Dropkin and Somerscales and Globe and Dropkin. The heat transfer on side wall cooling condition without top cooling is highest and was enhanced by decreasing the aspect ratio. The numerical results agreed well with the experimental results. Each cell pattern (cell size, cell direction, central location of cell) differed in the cooling condition. Therefore, it is difficult to predict the internal flow due to complexity of cell formation behavior.

  9. Main investigation results on the forest radioecology in the Kyshtym and Chernobyl accident zones

    International Nuclear Information System (INIS)

    Tikhomirov, F.A.; Shcheglov, A.I.

    1994-01-01

    As a result of the long-term studies of radionuclide migration in forest ecosystems in zones of radioactive contamination after the Kyshtym and Chernobyl accidents, the following trends were revealed: (1) High retention capacity of stand canopy with respect to radioactive fallout. This leads to high doses absorbed by apical and leaf meristems, β-radiation giving the main part of the dose; (2) Fast self-decontamination of crowns during the growth period and relatively slow decontamination in the phase of physiological rest, regardless of amount of atmospheric precipitation. The rate of crown decontamination determines the value and duration of radiation stress on woody plants; (3) Accumulation not less than 95% of the total radionuclide amount in the forest litter 1-2 years after the cessation of radioactive fallout; (4) Relatively slow migration of strontium and cesium radionuclides along the forest soil profile; (5) High capacity of the forest when serving as a biogeochemical barrier to the routes of horizontal and vertical radionuclide migration and export out of the zone of initial contamination, including migration into the river water; (6) Considerable difference between strontium and cesium when migrating in forest soils and in the soil-plant system; (7) Broad variations in transfer factors for uptake of cesium-137 from soil into forest plants depending on the plant species and soil type. The primary radiobiological effects connected with irradiation of organisms are considered and secondary disturbances due to changes of ecological bonds between the components of irradiated forest ecosystem are discussed

  10. SIMBATH 1976-1992, seventeen years of experimental investigation of key issues concerned with severe reactor accidents

    International Nuclear Information System (INIS)

    Kaiser, A.; Peppler, W.; Will, H.

    1994-01-01

    The course of the initiating phase of severe fast reactor accidents is determined by early material motion. In simulation experiments (SIMBATH, simulation experiments in fuel element mock-ups with thermite) the behavior of single pin, 7 pin, 19 pin, 37 pin bundles undergoing meltdown was investigated. Thermite (Al + Fe 2 O 3 ) filled tubes were used to simulate fuel rods, while exothermal heat of the thermite reaction simulated the nuclear heat. The energy of 3.4 kJ per centimeter of pin length resulted in melting temperature of about 3200 K. SIMBATH is an out-of-pile experimental program with non-radioactive materials which provided the possibility to perform numerous experiments. The x-ray high speed photography used in the test enabled to visualise material motion and relocation qualitatively, and furthermore to gain quantitative results by additionally installed photodiodes. The results of the experiment serve as a database to evaluate physical phenomena relevant to be modelled by computer codes (SIMMER) and to verify the codes. The experiments were carried out either in stagnant sodium with an axial temperature gradient, or in flowing sodium, simulating unprotected loss of flow (ULOF) or unprotected transient overpower accidents (UTOP) conditions, respectively

  11. Investigation of relation between operator's mental workload and information flow in accident diagnosis tasks of nuclear power plant

    International Nuclear Information System (INIS)

    Ha, Chang Hoon; Kim, Jong Hyun; Seong, Poong Hyun

    2004-01-01

    In the main control room (MCR) of a nuclear power plant (NPP), there are lots of dynamic information sources for MCR operator's situation awareness. As the human-machine interface in MCR is advanced, operator's information acquisition, information gathering and decision-making is becoming an important part to maintain the effective and safe operation of NPPs. Diagnostic task in complex and huge systems like NPP is the most difficult and mental effort-demanding for operators. This research investigates the relation between operator's mental workload and information flow in accident diagnosis tasks. The amount of information flow is quantified, using information flow model and Conant's model, a kind of information theory. For the mental workload measure, eye blink rate, blink duration, fixation time, number of fixation, and gaze direction are measured during accident diagnosis tasks. Subjective methods such as NASA-Task Load Index (NASA-TLX) and Modified Cooper-Harper (MCH) method are also used in the experiment. It is shown that the operator's mental workload has significant relation to information flow of diagnosis task. It makes possible to predict the mental workload through the quantity of the information flow of a system

  12. A Chemical Investigation of the Leaves of Morus alba L.

    Science.gov (United States)

    Chen, Xiao-Yan; Zhang, Ting; Wang, Xin; Hamann, Mark T; Kang, Jie; Yu, De-Quan; Chen, Ruo-Yun

    2018-04-26

    The leaves of Morus alba L. are an important herbal medicine in Asia. The systematic isolation of the metabolites of the leaves of Morus alba L. was achieved using a combination of liquid chromatography techniques. The structures were elucidated by spectroscopic data analysis and the absolute configuration was determined based on electronic circular dichroism (ECD) spectroscopic data and hydrolysis experiments. Their biological activity was evaluated using different biological assays, such as the assessment of their capacity to inhibit the aldose reductase enzyme; the determination of their cytotoxic activity and the evaluation of their neuroprotective effects against the deprivation of serum or against the presence of nicouline. Chemical investigation of the leaves of Morus alba L. resulted in four new structures 1 ⁻ 4 and a known molecule 5 . Compounds 2 and 5 inhibited aldose reductase with IC 50 values of 4.33 μM and 6.0 μM compared with the potent AR inhibitor epalrestat (IC 50 1.88 × 10 −3 μM). Pretreatment with compound 3 decreased PC12 cell apoptosis subsequent serum deprivation condition and pretreatment with compound 5 decreased nicouline-induced PC12 cell apoptosis as compared with control cells ( p < 0.001).

  13. Investigations of radiocaesium in the natural terrestrial environment in Norway following the Chernobyl accident

    International Nuclear Information System (INIS)

    Bretten, S.; Steinnes, E.

    1992-01-01

    Radioactive fallout from the Chernobyl accident affected parts of central Norway to a considerable extent, in particular the 134 Cs + 137 Cs deposition had a significant impact on the natural environment. When this became apparent, a comprehensive radioecological research programme was initiated in order to study the behaviour of radiocaesium in boreal and alpine ecosystems, with emphasis on food-chains leading to exposure of species used for human consumption, i.e., reindeer and freshwater fish. In this paper results from the terrestrial part of this research programme during the period 1986-1990 are presented. The work was mainly confined to the mountain areas of Dovre and Rondane. Parallel studies were performed in eutrophic and strongly oligotrophic communities. The influence of local variations in topography and microclimate on the observed radiocaesium levels in topsoils, lichens and vascular plants was studied in detail. Currently a significant re-distribution of radiocaesium from the originally strongly exposed surfaces to those that were less exposed is observed. In the soil, radiocaesium is strongly retained in the litter and raw humus layers. Current levels in lichens are 1-2 orders of magnitude higher than in vascular plants. This strongly affects the seasonal variation of radiocaesium in reindeer, showing winter maxima of about 5 times higher than the August levels. The radiocaesium levels in reindeer showed a decline of approximately a factor of 3 during the period 1987-1990. Other animal species studied in the programme exhibited substantially lower radiocaesium levels than reindeer, but a considerable interspecies variation was observed. (author)

  14. How shift scheduling practices contribute to fatigue amongst freight rail operating employees: Findings from Canadian accident investigations.

    Science.gov (United States)

    Rudin-Brown, Christina M; Harris, Sarah; Rosberg, Ari

    2018-02-01

    Canada's freight rail system moves 70% of the country's surface goods and almost half of all exports (RAC, 2016). These include dangerous goods. Anonymous survey of freight rail operating employees conducted by the Teamsters Canada Rail Conference (TCRC, 2014) revealed that many do not report getting enough sleep because of their work schedules, and that fatigue may be affecting their performance at work. Besides general impairments in attention and cognitive functioning, fatigue in railway operating employees slows reaction time to safety alarms and impairs conformance to train operating requirements. Shift scheduling practices can contribute to sleep-related fatigue by restricting sleep opportunities, requiring extended periods of wakefulness and by disrupting daily (circadian) rhythms. The primary goal of accident investigation is to identify causal and contributing factors so that similar occurrences can be prevented. A database search of Transportation Safety Board (TSB) rail investigation reports published in the 21-year period from 1995 to 2015 identified 18 that cited sleep-related fatigue of freight rail operating employees as a causal, contributing, or risk finding. This number represents about 20% of TSB rail investigations from the same period in which a human factors aspect of freight train activities was a primary cause. Exploration of accident themes suggests that management of fatigue and shift scheduling in the freight rail industry is a complex issue that is often not conducive to employee circadian rhythms and sleep requirements. It also suggests that current shift scheduling and fatigue management practices may be insufficient to mitigate the associated safety risk. Railway fatigue management systems that are based on the principles of modern sleep science are needed to improve scheduling practices and mitigate the ongoing safety risk. Crown Copyright © 2018. Published by Elsevier Ltd. All rights reserved.

  15. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 2 – Zinc

    International Nuclear Information System (INIS)

    Pease, David; LaBrier, Daniel; Ali, Amir; Blandford, Edward D.; Howe, Kerry J.

    2016-01-01

    Highlights: • Zinc release is limited to less than 1 mg/L in TSP-buffered solution under a variety of conditions (pH, temperature, zinc source). • Zinc release in high-temperature non-TSP-buffered environment is approximately 25 mg/L. • Long-term zinc release is controlled by passivation (without TSP) and zinc solubility (with TSP). • Precipitation and solubility of zinc phosphate limit the release of zinc. - Abstract: Bench experiments were conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of zinc from metallic zinc-bearing surfaces under conditions representative of the containment pool following a postulated loss of coolant accident (LOCA) at a nuclear power generating facility. The experiments showed that in non-buffered (acidic) environments, measurable quantities of zinc are released from zinc-bearing surfaces. Precipitation and solubility of phosphate-based corrosion products, such as zinc phosphate, limit the release of zinc from zinc-bearing surfaces. These experiments have found that under a variety of conditions, including variations of temperature, pH, and across different zinc-bearing surfaces, the release of zinc into solution is limited to <1 mg/L when phosphate is present. When phosphate is not present, zinc release is instead bounded by a markedly higher saturation limit which is a strong function of the solution temperature.

  16. Type A behavior pattern, accident optimism and fatalism: an investigation into non-compliance with safety work behaviors among hospital nurses.

    Science.gov (United States)

    Ugwu, Fabian O; Onyishi, Ike E; Ugwu, Chidi; Onyishi, Charity N

    2015-01-01

    Safety work behavior has continued to attract the interest of organizational researchers and practitioners especially in the health sector. The goal of the study was to investigate whether personality type A, accident optimism and fatalism could predict non-compliance with safety work behaviors among hospital nurses. One hundred and fifty-nine nursing staff sampled from three government-owned hospitals in a state in southeast Nigeria, participated in the study. Data were collected through Type A Behavior Scale (TABS), Accident Optimism, Fatalism and Compliance with Safety Behavior (CSB) Scales. Our results showed that personality type A, accident optimism and fatalism were all related to non-compliance with safety work behaviors. Personality type A individuals tend to comply less with safety work behaviors than personality type B individuals. In addition, optimistic and fatalistic views about accidents and existing safety rules also have implications for compliance with safety work behaviors.

  17. Accidents - Chernobyl accident

    International Nuclear Information System (INIS)

    2004-01-01

    This file is devoted to the Chernobyl accident. It is divided in four parts. The first part concerns the accident itself and its technical management. The second part is relative to the radiation doses and the different contaminations. The third part reports the sanitary effects, the determinists ones and the stochastic ones. The fourth and last part relates the consequences for the other European countries with the case of France. Through the different parts a point is tackled with the measures taken after the accident by the other countries to manage an accident, the cooperation between the different countries and the groups of research and studies about the reactors safety, and also with the international medical cooperation, specially for the children, everything in relation with the Chernobyl accident. (N.C.)

  18. Investigation of Chemical Equilibrium Kinetics by the Electromigration Method

    CERN Document Server

    Bozhikov, G A; Bontchev, G D; Maslov, O D; Milanov, M V; Dmitriev, S N

    2002-01-01

    Measurement of the chemical reaction rates for complex formation as well as hydrolysis type reactions by the method of horizontal zone electrophoresis is outlined. The correlation between chemical equilibrium kinetics and electrodiffusion processes in a constant d.c. electric field is described. In model electromigration experiments the reaction rate constant of the complex formation of Hf(IV) and DTPA is determined.

  19. Investigation of Countercurrent Helium-Air Flows in Air-ingress Accidents for VHTRs

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xiaodong; Christensen, Richard; Oh, Chang

    2013-10-03

    The primary objective of this research is to develop an extensive experimental database for the air- ingress phenomenon for the validation of computational fluid dynamics (CFD) analyses. This research is intended to be a separate-effects experimental study. However, the project team will perform a careful scaling analysis prior to designing a scaled-down test facility in order to closely tie this research with the real application. As a reference design in this study, the team will use the 600 MWth gas turbine modular helium reactor (GT-MHR) developed by General Atomic. In the test matrix of the experiments, researchers will vary the temperature and pressure of the helium— along with break size, location, shape, and orientation—to simulate deferent scenarios and to identify potential mitigation strategies. Under support of the Department of Energy, a high-temperature helium test facility has been designed and is currently being constructed at Ohio State University, primarily for high- temperature compact heat exchanger testing for the VHTR program. Once the facility is in operation (expected April 2009), this study will utilize high-temperature helium up to 900°C and 3 MPa for loss-of-coolant accident (LOCA) depressurization and air-ingress experiments. The project team will first conduct a scaling study and then design an air-ingress test facility. The major parameter to be measured in the experiments is oxygen (or nitrogen) concentration history at various locations following a LOCA scenario. The team will use two measurement techniques: 1) oxygen (or similar type) sensors employed in the flow field, which will introduce some undesirable intrusiveness, disturbing the flow, and 2) a planar laser-induced fluorescence (PLIF) imaging technique, which has no physical intrusiveness to the flow but requires a transparent window or test section that the laser beam can penetrate. The team will construct two test facilities, one for high-temperature helium tests with

  20. New Tools for Investigating Chemical and Product Use

    Science.gov (United States)

    - The timely characterization of the human and ecological risk posed by thousands of existing and emerging commercial chemicals is a critical challenge - High throughput (HT) risk prioritization relies on hazard and exposure characterization - While advances have been made ...

  1. Investigating the effects of different physical and chemical stress ...

    African Journals Online (AJOL)

    2018-04-09

    Apr 9, 2018 ... bacteria from extreme physical and chemical stress conditions. Additionally .... by inducing stress response genes, become more tolerant phenotypes ..... biofilm, monochloramine is more effective than free chlorine over long ...

  2. An investigation into the chemical composition of alternative invertebrate prey

    NARCIS (Netherlands)

    Oonincx, D.G.A.B.; Dierenfeld, E.S.

    2012-01-01

    The aim of this study was to determine the chemical composition of eight invertebrate species and evaluate their suitability as alternative prey. The species selected were rusty red cockroaches (Blatta lateralis), six-spotted cockroaches (Eublaberus distanti), Madagascar hissing cockroaches

  3. Postulated accidents

    International Nuclear Information System (INIS)

    Ullrich, W.

    1980-01-01

    This lecture on 'Postulated Accidents' is the first of a series of lectures on the dynamic and transient behaviour of nuclear power plants, especially pressurized water reactors. The main points covered will be: Reactivity Accidents, Transients (Intact Loop) and Loss of Cooland Accidents (LOCA) including small leak. This lecture will discuss the accident analysis in general, the definition of the various operational phases, the accident classification, and, as an example, an accident sequence analysis on the basis of 'Postulated Accidents'. (orig./RW)

  4. An Investigation of the Correlation between Safety Locus of Control and Occupational Accidents in Selected Medium-sized Manufacturing Industries in Qom Province, Iran, 2015

    Directory of Open Access Journals (Sweden)

    mohammad khandan

    2016-12-01

    Full Text Available Background and Objectives: Today, occupational accidents impose many direct and indirect costs on communities. In order to prevent the occurrence of work-related accidents, it is necessary that environmental factors be considered along with personal factors, such as safety Locus of control (SLOC. The present study aimed to investigate the correlation between safety locus of control and occupational accidents in two manufacturing companies in Qom province in 2015. Methods: This descriptive cross-sectional study was conducted on 163 workers who participated in the census. The tools used for data collection were valid questionnaire for SLOC and demographic questionnaire, and accidents were stated as self-report. Data were analyzed using t-, one-way ANOVA, and Poisson regression statistical tests. Results: Among all workers, 52.8% were female and others were male. The average age of the workers was 29.8±6.6 years. A total of 37 (22.8% workers had experienced occupational accident. Also, score of SLOC was 39.1±6.7. Among the demographic variables, there was no significant relationship between work history and number of occupational accidents (p=0.06, but there was a significant relationship between external control (one of the SLOC subscales and occupational accidents (p<0.05. Conclusion: Based on the findings, subjects who perceive positive or negative events as consequences of their own behavior, and attribute them to chance, fate, and uncontrollable environmental factors, experience more occupational accidents compared to other people. Hence, paying attention to psychological and cognitive factors in work environments should be a priority for managers and decision makers of the industry.  

  5. CHEMICAL EFFECTS ON PWR SUMP STRAINER BLOCKAGE AFTER A LOSS-OF-COOLANT ACCIDENT: REVIEW ON U.S. RESEARCH EFFORTS

    Directory of Open Access Journals (Sweden)

    CHI BUM BAHN

    2013-06-01

    Full Text Available Industry- or regulatory-sponsored research activities on the resolution of Generic Safety Issue (GSI-191 were reviewed, especially on the chemical effects. Potential chemical effects on the head loss across the debris-loaded sump strainer under a post-accident condition were experimentally evidenced by small-scale bench tests, integrated chemical effects test (ICET, and vertical loop head loss tests. Three main chemical precipitates were identified by WCAP-16530-NP: calcium phosphate, aluminum oxyhydroxide, and sodium aluminum silicate. The former two precipitates were also identified as major chemical precipitates by the ICETs. The assumption that all released calcium would form precipitates is reasonable. CalSil insulation needs to be minimized especially in a plant using trisodium phosphate buffer. The assumption that all released aluminum would form precipitates appears highly conservative because ICETs and other studies suggest substantial solubility of aluminum at high temperature and inhibition of aluminum corrosion by silicate or phosphate. The industry-proposed chemical surrogates are quite effective in increasing the head loss across the debris-loaded bed and more effective than the prototypical aluminum hydroxide precipitates generated by in-situ aluminum corrosion. There appears to be some unresolved potential issues related to GSI-191 chemical effects as identified in NUREG/CR-6988. The United States Nuclear Regulatory Commission, however, concluded that the implications of these issues are either not generically significant or are appropriately addressed, although several issues associated with downstream in-vessel effects remain.

  6. Quantum chemical investigation of mechanisms of silane oxidation

    DEFF Research Database (Denmark)

    Mader, Mary M.; Norrby, Per-Ola

    2001-01-01

    Several mechanisms for the peroxide oxidation of organosilanes to alcohols are compared by quantum chemical calculations, including solvation with the PCM method. Without doubt, the reaction proceeds via anionic, pentacoordinate silicate species, but a profound difference is found between in vacuo...

  7. Rocket Scientist for a Day: Investigating Alternatives for Chemical Propulsion

    Science.gov (United States)

    Angelin, Marcus; Rahm, Martin; Gabrielsson, Erik; Gumaelius, Lena

    2012-01-01

    This laboratory experiment introduces rocket science from a chemistry perspective. The focus is set on chemical propulsion, including its environmental impact and future development. By combining lecture-based teaching with practical, theoretical, and computational exercises, the students get to evaluate different propellant alternatives. To…

  8. Additional investigations within the research programme launched after the Chernobyl accident

    International Nuclear Information System (INIS)

    Anon.

    1987-01-01

    The additional investigations concern the determination of the transfer of the fission products I-131, Cs-137, Cs-134, and Te-132 along the pasture-cattle-milk pathway insolving fresh grass, and of the fission products Cs-137 and Cs-134 from winter fodder to milk, beef and veal, and the enrichment of Cs-137 and Sr-90 in the human organism as well as the migration of the fission products Cs-137, Cs-134, Ru-103, and K-40 from the Chernobyl fall-out to the soil. (DG) [de

  9. Incomplete understanding of biogas chemical hazards – Serious gas poisoning accident while unloading food waste at biogas plant

    DEFF Research Database (Denmark)

    Hedlund, Frank Huess; Madsen, Michael

    2018-01-01

    . Ventilation systems were overwhelmed. The driver narrowly escaped death. Several would-be rescuers collapsed. Under marginally different conditions, this accident could have led to five fatalities. The case offers a rich account of the actions of fellow workers who with stubborn determination sought...

  10. Features of RAPTA-SFD code modelling of chemical interactions of basic materials of the WWER active zone in accident conditions with severe fuel damage

    International Nuclear Information System (INIS)

    Bibilashvili, Yu.K.; Sokolov, N.B.; Salatov, A.V.; Nechaeva, O.A.; Andreyeva-Andrievskaya, L.N.; Vlasov, F.Yu.

    1996-01-01

    A brief description of RAPTA-SFD code intended for computer simulations of WWER-type fuel elements (simulator or absorber element) in conditions of accident with severe damage of fuel. Presented are models of chemical interactions of basic materials of the active zone, emphasized are special feature of their application in carrying out of the CORA-W2 experiment within the framework of International Standard Problem ISP-36. Results obtained confirm expediency of phenomenological models application. (author). 6 refs, 7 figs, 1 tab

  11. Surface properties of hydrogenated nanodiamonds: a chemical investigation.

    Science.gov (United States)

    Girard, H A; Petit, T; Perruchas, S; Gacoin, T; Gesset, C; Arnault, J C; Bergonzo, P

    2011-06-28

    Hydrogen terminations (C-H) confer to diamond layers specific surface properties such as a negative electron affinity and a superficial conductive layer, opening the way to specific functionalization routes. For example, efficient covalent bonding of diazonium salts or of alkene moieties can be performed on hydrogenated diamond thin films, owing to electronic exchanges at the interface. Here, we report on the chemical reactivity of fully hydrogenated High Pressure High Temperature (HPHT) nanodiamonds (H-NDs) towards such grafting, with respect to the reactivity of as-received NDs. Chemical characterizations such as FTIR, XPS analysis and Zeta potential measurements reveal a clear selectivity of such couplings on H-NDs, suggesting that C-H related surface properties remain dominant even on particles at the nanoscale. These results on hydrogenated NDs open up the route to a broad range of new functionalizations for innovative NDs applications development. This journal is © the Owner Societies 2011

  12. Investigation of chemical equilibrium kinetics by the electromigration method

    International Nuclear Information System (INIS)

    Bozhikov, G.A.; Ivanov, P.I.; Maslov, O.D.; Dmitriev, S.N.; Bontchev, G.D.; Milanov, M.V.

    2003-01-01

    The measurement of the chemical reaction rates for complex formation as well as hydrolysis type reactions by the method of horizontal zone electrophoresis is outlined. The correlation between chemical equilibrium kinetics and electrodiffusion processes in a constant d.c. electric field is described. In model electromigration experiments the reaction rate constant of the formation a complex by Hf(IV) and diethylenetriaminepentaacetic acid (DTPA) is determined. The electrophoretic mobility, diffusion coefficient and stability constant of the [HfDTPA] - complex are calculated, taking into account experimental electrophoretic data obtained at 298.15±0.05 K and constant ionic strength. No-carrier-added 175 Hf radionuclide was used in electromigration experiments at concentrations of 10 -10 -10 -11 M. (orig.)

  13. Chemical Investigations of the Castor Bean Plant Ricinus communis

    Science.gov (United States)

    2012-12-01

    This technical report documents the progress made against the chemistry milestones contained in the NSST grant. This report will inform the clients ...of this work program (AFP, Chemical Warfare Agent Laboratory Network (CWALN) members, other national security clients ) of some of the capability...Umetrics AB, Umëa, Sweden) and subjected to Pareto UNCLASSIFIED 40 UNCLASSIFIED DSTO-TR-2786 scaling. Data matrices were subjected to both OPLS

  14. Acidentes químicos ampliados: um desafio para a saúde pública The increase in chemical accidents: a challenge for public health

    Directory of Open Access Journals (Sweden)

    Carlos M. de Freitas

    1995-12-01

    Full Text Available Os acidentes envolvendo substâncias perigosas nas atividades de transporte, armazenamento e produção industrial de produtos químicos constituem um sério risco à saúde e ao meio ambiente. Objetiva-se discutir, no âmbito da saúde pública, alguns dos desafios que esses tipos de acidentes colocam, principalmente para os países de economia periférica. Através da combinação de informações quantitativas e qualitativas, foram definidos e caracterizados esses tipos de acidentes e seus diversos riscos. Esses acidentes têm se apresentado com a maior gravidade nos países de economia periférica, embora a maioria deles venha ocorrendo sem o adequado registro de informações básicas para a avaliação e vigilância, como é demonstrado no caso do Rio de Janeiro (Brasil. Além da tarefa de se avaliar as conseqüências de eventos, por vezes extremamente complexos, coloca-se também, a de formular estratégias de controle e prevenção em realidades sociais que configuram um terreno fértil para a ocorrência e agravamento dos mesmos.Chemical accidents involving explosions, large fires and leakages of hazardous substances occuring during transport, storage and industrial production of chemicals constitute a real challeng to health, environmental and industrial safety professionals. The aim of this article is to discuss the main questions that this kind of accident provokes, in terms of public helth, particularly in developing countries such as Brazil. The paper defines and characterises these accidents and the various health risk they involve excluding the leakages of hazardous substances during "normal" production in industry - through the combination of quantitative and qualitative information drawn from the international literature on the subject. From some examples of chemical accidents such as occurred in Bophal (Índia, Vila Socó (Brazil, São Paulo (México and data of the World Health Organization (WHO, the authors seek to show

  15. An Overall Investigation of Direct Vessel Injection Line Break Accidents of the ATLAS Facility

    International Nuclear Information System (INIS)

    Kim, Yeon-Sik; Choi, Ki-Yong; Cho, Seok; Kim, Bok-Deuk

    2015-01-01

    For parametric evaluations of direct vessel injection (DVI) line break scenarios, the pressurizer (PZR) pressure, core collapsed water level, and peak cladding temperature were investigated between the analyses and tests. The PZR pressure was mainly dependent upon the break flow model, e.g., discharge coefficient of the Henry-Fauske critical model. The core collapsed water level and peak cladding temperature were mainly dependent on the counter-current flow limit (CCFL) option of the fuel alignment plate (FAP). The CCFL option of the cross-over leg (COL) affected the PZR pressure owing to the loop seal clearings and seemed to have little effect on the core collapsed water level. Proper C d values and applicable CCFL options were summarized. C d values seemed to be dependent on the sizes of the DVI line break. The PZR pressure was mainly dependent on the break flow model, e.g., the discharge coefficient of the Henry-Fauske critical model. The core collapsed water level and peak cladding temperature were mainly dependent on the CCFL option of the FAP. The CCFL option of the COL affected the PZR pressure owing to loop seal clearings and seemed to have little effect on the core collapsed water level. From parametric evaluations, proper C d values and applicable CCFL options were suggested. The C d values seemed to be dependent on the sizes of the DVI line break. Although there was little difference in the CCFL options of the COL, the Ku-option was the preferred one for COLs' CCFL option. The CCFL options of the FAP appeared sensitive to the core collapsed water level and peak cladding temperature. The Ku-option of the FAP tended to negatively exaggerate the core behavior and showed excessively conservative results, especially on the peak cladding temperature. For smaller breaks, e.g., 25%, NA- and Wa-options would be applicable for the FAP. However, for larger breaks, e.g., 50%, the Wa-option of the FAP was the preferred one. Comparisons between the tests and

  16. Learning non-technical skill lessons from testimony given in the investigation of the nuclear accident at the Fukushima Nuclear Power Stations

    International Nuclear Information System (INIS)

    Hikono, Masaru; Sakuda, Hiroshi; Matsui, Yuko; Goto, Manabu; Kanayama, Masaki

    2016-01-01

    The Government Investigation Committee on the Accident at the Fukushima Nuclear Power Stations interviewed individuals concerned. The hearing records, published in 2014, are considered to have valuable lessons for power station managers who encounter severe accidents. In this study, descriptions from the hearing records were extracted as lessons for managers. The extractions were classified by the subject (for whom the lessons are intended), and the category of the non-technical skills. The results showed the possibility of pointing out the lessons in accordance with responsibilities. (author)

  17. Investigation of a hydrogen mitigation system during large break loss-of-coolant accident for a two-loop pressurized water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Dehjourian, Mehdi; Rahgoshay, Mohmmad; Jahanfamia, Gholamreza [Dept. of Nuclear Engineering, Science and Research Branch, Islamic Azad University of Tehran, Tehran (Iran, Islamic Republic of); Sayareh, Reza [Faculty of Electrical and Computer Engineering, Kerman Graduate University of Technology, Kerman (Iran, Islamic Republic of); Shirani, Amir Saied [Faculty of Engineering, Shahid Beheshti University, Tehran (Iran, Islamic Republic of)

    2016-10-15

    Hydrogen release during severe accidents poses a serious threat to containment integrity. Mitigating procedures are necessary to prevent global or local explosions, especially in large steel shell containments. The management of hydrogen safety and prevention of over-pressurization could be implemented through a hydrogen reduction system and spray system. During the course of the hypothetical large break loss-of-coolant accident in a nuclear power plant, hydrogen is generated by a reaction between steam and the fuel-cladding inside the reactor pressure vessel and also core concrete interaction after ejection of melt into the cavity. The MELCOR 1.8.6 was used to assess core degradation and containment behavior during the large break loss-of-coolant accident without the actuation of the safety injection system except for accumulators in Beznau nuclear power plant. Also, hydrogen distribution in containment and performance of hydrogen reduction system were investigated.

  18. Chemical investigation of sewage effluents of Hyderabad city

    International Nuclear Information System (INIS)

    Laghari, A.; Chandio, S.N.; Khushawar, M.Y.; Laghari, M.Y.

    2000-01-01

    Water samples of sewage effluents were collected from sewage collection points located at Latifabad units 9-11, Husainabad and Qasimabad sewage pumping stations. The sewage is pumped towards Southern Sewage treatment plant (SSTP) or is used for agricultural purposes. The water samples from SSTP were also collected and analyzed for pH, conducively, salinity, alkalinity, chlorides, hardness, total, volatile and fixed residues, dissolved oxygen, chemical oxygen demand, nitrogen and phosphorous contents. Variation in the results between sewage water and effluents were noted. (author)

  19. An environmental chamber for investigating the evaporation of volatile chemicals.

    Science.gov (United States)

    Dillon, H K; Rumph, P F

    1998-03-01

    An inexpensive test chamber has been constructed that provides an environment appropriate for testing the effects of temperature and chemical interactions on gaseous emissions from test solutions. Temperature, relative humidity, and ventilation rate can be controlled and a well-mixed atmosphere can be maintained. The system is relatively simple and relies on heated tap water or ice to adjust the temperature. Temperatures ranging from 9 to 21 degrees C have been maintained. At an average temperature of 15.1 degrees C, temperatures at any location within the chamber vary by no more than 0.5 degree C, and the temperature of the test solution within the chamber varies by no more than 0.1 degree C. The temperatures within the chamber are stable enough to generate precise steady-state concentrations. The wind velocities within the chamber are reproducible from run to run. Consequently, the effect of velocity on the rate of evaporation of a test chemical is expected to be uniform from run to run. Steady-state concentrations can be attained in less than 1 hour at an air exchange rate of about 5 per hour.

  20. Experimental investigations of pressure and temperature loads on a containment after a loss-of-coolant accident

    International Nuclear Information System (INIS)

    Kanzleiter, T.F.

    1976-01-01

    For the design of an LWR containment one of the important conditions to be considered is the rapid rise of internal pressure and temperature caused by a loss-of-coolant accident (LOCA) of the primary cooling system. The phenomena occurring within a containment during a LOCA are currently investigated through experiments with a model containment. The experimental results are compared with the results of model calculations to improve the calculational methods. An experimental facility was built, consisting of a primary coolant circuit and a special model containment. The model containment, built in conventional reinforced concrete, has a diameter of 12 m, a height of 12.5 m, a capacity of 580 m 3 and is designed for an internal pressure of 6 bar. The interior is divided by concrete walls and removable partitions into several compartments, which are interconnected through openings with adjustable cross sections. By exchanging the removable partitions it is possible to modify the interior of the containment and to simulate different containment shapes. For the first experiments a PWR configuration with nine compartments has been installed. The model scales of the compartment volumes and the overflow areas are about 1 : 64 compared to the 1200 MW PWR plant Biblis A. (Auth.)

  1. Analysis methodology for RBMK-1500 core safety and investigations on corium coolability during a LWR severe accident

    International Nuclear Information System (INIS)

    Jasiulevicius, Audrius

    2003-01-01

    This thesis presents the work involving two broad aspects within the field of nuclear reactor analysis and safety. These are: - development of a fully independent reactor dynamics and safety analysis methodology of the RBMK-1500 core transient accidents and - experiments on the enhancement of coolability of a particulate bed or a melt pool due to heat removal through the control rod guide tubes. The first part of the thesis focuses on the development of the RBMK-1500 analysis methodology based on the CORETRAN code package. The second part investigates the issue of coolability during severe accidents in LWR type reactors: the coolability of debris bed and melt pool for in-vessel and ex-vessel conditions. The first chapter briefly presents the status of developments in both the RBMK-1500 core analysis and the corium coolability areas. The second chapter describes the generation of the RBMK-1500 neutron cross section data library with the HELIOS code. The cross section library was developed for the whole range of the reactor conditions. The results of the benchmarking with the WIMS-D4 code and validation against the RBMK Critical Facility experiments is also presented here. The HELIOS generated neutron cross section data library provides a close agreement with the WIMS-D4 code results. The validation against the data from the Critical Experiments shows that the HELIOS generated neutron cross section library provides excellent predictions for the criticality, axial and radial power distribution, control rod reactivity worths and coolant reactivity effects, etc. The reactivity effects of voiding for the system, fuel assembly and additional absorber channel are underpredicted in the calculations using the HELIOS code generated neutron cross sections. The underprediction, however, is much less than that obtained when the WIMS-D4 code generated cross sections are employed. The third chapter describes the work, performed towards the accurate prediction, assessment and

  2. A system of safety management practices and worker engagement for reducing and preventing accidents: an empirical and theoretical investigation.

    Science.gov (United States)

    Wachter, Jan K; Yorio, Patrick L

    2014-07-01

    The overall research objective was to theoretically and empirically develop the ideas around a system of safety management practices (ten practices were elaborated), to test their relationship with objective safety statistics (such as accident rates), and to explore how these practices work to achieve positive safety results (accident prevention) through worker engagement. Data were collected using safety manager, supervisor and employee surveys designed to assess and link safety management system practices, employee perceptions resulting from existing practices, and safety performance outcomes. Results indicate the following: there is a significant negative relationship between the presence of ten individual safety management practices, as well as the composite of these practices, with accident rates; there is a significant negative relationship between the level of safety-focused worker emotional and cognitive engagement with accident rates; safety management systems and worker engagement levels can be used individually to predict accident rates; safety management systems can be used to predict worker engagement levels; and worker engagement levels act as mediators between the safety management system and safety performance outcomes (such as accident rates). Even though the presence of safety management system practices is linked with incident reduction and may represent a necessary first-step in accident prevention, safety performance may also depend on mediation by safety-focused cognitive and emotional engagement by workers. Thus, when organizations invest in a safety management system approach to reducing/preventing accidents and improving safety performance, they should also be concerned about winning over the minds and hearts of their workers through human performance-based safety management systems designed to promote and enhance worker engagement. Copyright © 2013 The Authors. Published by Elsevier Ltd.. All rights reserved.

  3. Isotopic and chemical investigations on Angra dos Reis

    International Nuclear Information System (INIS)

    Wasserburg, G.J.; Tera, F.; Papanastassiou, D.A.; Huneke, J.C.

    1977-01-01

    Extensive isotopic studies of Pb, Sr and Xe and chemical abundance measurements of K, Rb, Sr, Ba, Nd, Sm, U and Th for total meteorite and mineral separates of the Angra dos Reis achondrite are reported on. U-Pb, Th-Pb and Pb-Pb ages are concordant at 4.54 AE for the total meteorite and for high-purity whitlockite in Angra dos Reis. This establishes Angra dos Reis as an early planetary differentiate which has not been disturbed for these systems since 4.54 AE ago. Measured 87 Sr/ 86 Sr in pyroxene and whitlockite for Angra dos Reis (ADOR) are distinctly below BABI by two parts in 10 4 and only one part in 10 4 above the lowest 87 Sr/ 86 Sr (ALL) measured in an Allende inclusion. The difference in ADOR-ALL corresponds to an interval of condensation in the solar nebula of approximately 3 m.y. If 26 Al was the heat source for the magmatism on the parent planets of Angra dos Reis and the basaltic achondrites (BABI) then the relatively large difference in 87 Sr/ 86 Sr, BABI - ALL, must be the result of planetary evolution rather than condensation over approximately 10 m.y. Xe isotopic measurements confirm the presence of large amounts of 244 Pu-produced fission Xe and show that 244 Pu was enriched in the whitlockite relative to the pyroxene by a factor of approximately 18. Chemical element enrichment factors between the whitlockite and the fassaitic pyroxene in Angra dos Reis are presented. The enrichment factors demonstrate close analogy between the rare earth elements and their actinide analogs. The enrichment factor for Pu is intermediate to the enrichment factors of Nd and Sm. (Auth.)

  4. Dental implant treatment following trauma: An investigation into the failure to complete Accident Compensation Corporation funded care.

    Science.gov (United States)

    Kennedy, R; Murray, C; Leichter, J

    2016-03-01

    Among other restorative strategies, the Accident Compensation Corporation (ACC) provides benefits for dental implant treatment to replace teeth lost as a result of trauma. While ACC has funded over 15,000 dental implants since 2002, the outcomes of this treatment and patient perceptions of this treatment have not been investigated. The aim of this study was to investigate the perceptions of the dental implant treatment outcomes and reasons for failure to complete restorative treatment in patients who had undergone trauma-related implant surgery funded by ACC between February 2006 and September 2009, but had not completed the prosthetic component of the treatment. A randomly selected sample of 399 patients, who had undergone dental implant surgery but not completed the crown restoration, was identified from the ACC database. These individuals were contacted by mail for expressions of interest and 181 clients were interviewed by telephone. Responses to open-ended questions were entered into an Excel spreadsheet and analysed using a general inductive technique. A common emergent theme was the high level of satisfaction expressed by participants with the implant process, however just under half of those responding felt they had been pushed into having implants and were given the impression that this was the only treatment ACC paid for. The cost of the prosthetic phase of the treatment and surgical complications were identified as the primary reasons why participants failed to complete the restorative phase of treatment, after completing the surgical phase. The results highlighted the need to better inform patients of their treatment options and to allow time for them to process this information before progressing with care. A patient decision tool may help to give greater ownership of the treatment options. Newly implemented protocols to assist dentists to better assess treatment needs may also assist in achieving improvements in perceived treatment outcomes for

  5. Accident management

    International Nuclear Information System (INIS)

    Lutz, R.J.; Monty, B.S.; Liparulo, N.J.; Desaedeleer, G.

    1989-01-01

    The foundation of the framework for a Severe Accident Management Program is the contained in the Probabilistic Safety Study (PSS) or the Individual Plant Evaluations (IPE) for a specific plant. The development of a Severe Accident Management Program at a plant is based on the use of the information, in conjunction with other applicable information. A Severe Accident Management Program must address both accident prevention and accident mitigation. The overall Severe Accident Management framework must address these two facets, as a living program in terms of gathering the evaluating information, the readiness to respond to an event. Significant international experience in the development of severe accident management programs exist which should provide some direction for the development of Severe Accident Management in the U.S. This paper reports that the two most important elements of a Severe Accident Management Program are the Emergency Consultation process and the standards for measuring the effectiveness of individual Severe Accident Management Programs at utilities

  6. Analysis methodology for RBMK-1500 core safety and investigations on corium coolability during a LWR severe accident

    Energy Technology Data Exchange (ETDEWEB)

    Jasiulevicius, Audrius

    2003-07-01

    This thesis presents the work involving two broad aspects within the field of nuclear reactor analysis and safety. These are: - development of a fully independent reactor dynamics and safety analysis methodology of the RBMK-1500 core transient accidents and - experiments on the enhancement of coolability of a particulate bed or a melt pool due to heat removal through the control rod guide tubes. The first part of the thesis focuses on the development of the RBMK-1500 analysis methodology based on the CORETRAN code package. The second part investigates the issue of coolability during severe accidents in LWR type reactors: the coolability of debris bed and melt pool for in-vessel and ex-vessel conditions. The first chapter briefly presents the status of developments in both the RBMK-1500 core analysis and the corium coolability areas. The second chapter describes the generation of the RBMK-1500 neutron cross section data library with the HELIOS code. The cross section library was developed for the whole range of the reactor conditions. The results of the benchmarking with the WIMS-D4 code and validation against the RBMK Critical Facility experiments is also presented here. The HELIOS generated neutron cross section data library provides a close agreement with the WIMS-D4 code results. The validation against the data from the Critical Experiments shows that the HELIOS generated neutron cross section library provides excellent predictions for the criticality, axial and radial power distribution, control rod reactivity worths and coolant reactivity effects, etc. The reactivity effects of voiding for the system, fuel assembly and additional absorber channel are underpredicted in the calculations using the HELIOS code generated neutron cross sections. The underprediction, however, is much less than that obtained when the WIMS-D4 code generated cross sections are employed. The third chapter describes the work, performed towards the accurate prediction, assessment and

  7. Chemical and pharmacological investigation of Acacia and Santalum species

    DEFF Research Database (Denmark)

    Knudsen, Diana Jæger

    compounds from plants still have a huge potential for investigation for medicinal properties as possible drug leads. Humans have a long history of using plant medicine in treatments and indigenous cultures are a remarkable source for immense knowledge about plants and the uses of them - knowledge that has...... often only exists amongst members of communities or groups of the land where it has arisen. In this PhD project the three Australian plant species Acacia ligulata A.Cunn. ex Benth, Santalum spicatum (R.Br.) A.DC and Santalum lanceolatum R.Br were investigated for their bioactivity and chemistry...

  8. Investigation regarding the long-term security developments in the Swedish nuclear power and the response to the accident at Fukushima

    International Nuclear Information System (INIS)

    Skaanberg, Lars

    2012-01-01

    Swedish nuclear plants need to continue to work on analysis and actions in the plants, partly to meet the demands of legislation and agreed action plans, and partly due to additional security requirements on account of experiences from the Fukushima Dai-ichi accident, stress tests, security investigations and investigations relating to physical protection. It is also essential to continue with safety improvements to gradually increase margins against unforeseen events in aging plants during long-term operation

  9. Unavoidable Accident

    OpenAIRE

    Grady, Mark F.

    2009-01-01

    In negligence law, "unavoidable accident" is the risk that remains when an actor has used due care. The counterpart of unavoidable accident is "negligent harm." Negligence law makes parties immune for unavoidable accident even when they have used less than due care. Courts have developed a number of methods by which they "sort" accidents to unavoidable accident or to negligent harm, holding parties liable only for the latter. These sorting techniques are interesting in their own right and als...

  10. DNA fingerprinting, biological and chemical investigation of certain Yucca species.

    Science.gov (United States)

    El Hawary, Seham; El Sayed, Abeer; Helmy, Maged W; El Naggar, El Moataz Bellah; Marzouk, Hanan S; Bassam, Samar M

    2018-01-05

    Yucca aloifolia, Y. aloifolia variegata, Y. elephantipes and Y. filamentosa were investigated. DNA sequencing was performed for the four plants and a genomic DNA fingerprint was obtained and provided. The cytotoxic activities against four human cancer cell lines were investigated. The ethanolic extracts of leaves of Y. aloifolia variegata prevailed, especially against liver cancer HepG-2 and breast cancer MCF-7. In vivo assessment of hepatoprotective activity in rats also revealed the hepatoprotective potential of the ethanolic extracts of the four plants against CCl 4 - induced rats' liver damage. Qualitative and quantitative analysis of the flavonoid and phenolic content of the promising species was performed using HPLC. The analysis identified and quantified 18 flavonoids and 19 phenolic acids in the different fractions of Y. aloifolia variegata, among which the major flavonoids were hesperidin and kaemp-3-(2-p-coumaroyl) glucose and the major phenolic acids were gallic acid and protocatechuic acid.

  11. Development of Assessment Methodology of Chemical Behavior of Volatile Iodide under Severe Accident Conditions Using EPICUR Experiments

    International Nuclear Information System (INIS)

    Oh, Jae Yong; Yun, Jong Il; Kim, Do Sam; Han Chul

    2011-01-01

    Iodine is one of the most important fission products produced in nuclear power plants. Under severe accident condition, iodine exists as a variety of species in the containment such as aqueous iodide, gaseous iodide, iodide aerosol, etc. Following release of iodine from the reactor, mostly in the form of CsI aerosol, volatile iodine can be generated from the containment sump and release to the environment. Especially, volatile organic iodide can be produced from interaction between nonvolatile iodine and organic substances present in the containment. Volatile iodide could significantly influence the alienated residents surrounding the nuclear power plant. In particular, thyroid is vulnerable to radioiodine due to its high accumulation. Therefore, it is necessary for the Korea Institute of Nuclear Safety (KINS) to develop an evaluation model which can simulate iodine behavior in the containment following a severe accident. KINS also needs to make up its methodology for radiological consequence analysis, based on MELCOR-MACCS2 calculation, by coupling a simple iodine model which can conveniently deal with organic iodides. In the long term, such a model can contribute to develop an accident source term, which is one of urgent domestic needs. Our strategy for developing the model is as follows: 1. Review the existing methodologies, 2. Develop a simple stand-alone model, 3. Validate the model using ISTP-EPICUR (Experimental Program on Iodine Chemistry under Radiation) and OECD-BIP (Behavior of Iodine Project) experimental data. In this paper we present the context of development and validation of our model named RAIM (Radio-active iodine chemistry model)

  12. Development of Assessment Methodology of Chemical Behavior of Volatile Iodide under Severe Accident Conditions Using EPICUR Experiments

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Jae Yong; Yun, Jong Il [KAIST, Daejeon (Korea, Republic of); Kim, Do Sam; Han Chul [Korea Institue of Nuclear Safety, Daejeon (Korea, Republic of)

    2011-05-15

    Iodine is one of the most important fission products produced in nuclear power plants. Under severe accident condition, iodine exists as a variety of species in the containment such as aqueous iodide, gaseous iodide, iodide aerosol, etc. Following release of iodine from the reactor, mostly in the form of CsI aerosol, volatile iodine can be generated from the containment sump and release to the environment. Especially, volatile organic iodide can be produced from interaction between nonvolatile iodine and organic substances present in the containment. Volatile iodide could significantly influence the alienated residents surrounding the nuclear power plant. In particular, thyroid is vulnerable to radioiodine due to its high accumulation. Therefore, it is necessary for the Korea Institute of Nuclear Safety (KINS) to develop an evaluation model which can simulate iodine behavior in the containment following a severe accident. KINS also needs to make up its methodology for radiological consequence analysis, based on MELCOR-MACCS2 calculation, by coupling a simple iodine model which can conveniently deal with organic iodides. In the long term, such a model can contribute to develop an accident source term, which is one of urgent domestic needs. Our strategy for developing the model is as follows: 1. Review the existing methodologies, 2. Develop a simple stand-alone model, 3. Validate the model using ISTP-EPICUR (Experimental Program on Iodine Chemistry under Radiation) and OECD-BIP (Behavior of Iodine Project) experimental data. In this paper we present the context of development and validation of our model named RAIM (Radio-active iodine chemistry model)

  13. Investigation of effect of stopping supply flow into the cell on the confinement of the radioactive materials under fire accident

    International Nuclear Information System (INIS)

    Abe, Hitoshi; Watanabe, Koji

    1999-03-01

    On November 20th 1997, a fire accident happened at Uranium Enrichment Research Laboratory, Tokai, Japan Atomic Energy Research Institute and ventilation filters in the laboratory clogged. When fire accident occurs in a controlled area, a large quantity of smoke generates in the area and dropping exhaust flow from the area by the clogging of ventilation filters and rising pressure in the area are caused. Moreover, leakage of smoke including radioactive materials from the area by the pressure rising is expected. To prevent the leakage, it is expected that stopping supply flow to the area during a fire accident is effective, however, quantitative evaluation about this effect has not been performed. By using CELVA-1D code, one-dimensional thermofluid analysis code, this effect is evaluated quantitatively by modeling the laboratory and estimating source terms released during the fire accident. As the results, it has been found that the efficiency of confinement of the radioactive materials into the area is preserved in the slightly long period of time in case of stopping supply flow to the area, however, this effect can be neglected in case that scale of fire accident is relatively large. (author)

  14. Barriers to learning from incidents and accidents

    NARCIS (Netherlands)

    Dechy, N.; Dien, Y.; Drupsteen, L.; Felicio, A.; Cunha, C.; Roed-Larsen, S.; Marsden, E.; Tulonen, T.; Stoop, J.; Strucic, M.; Vetere Arellano, A.L.; Vorm, J.K.J. van der; Benner, L.

    2015-01-01

    This document provides an overview of knowledge concerning barriers to learning from incidents and accidents. It focuses on learning from accident investigations, public inquiries and operational experience feedback, in industrial sectors that are exposed to major accident hazards. The document

  15. Chemical treatments to reduce the transfer of caesium radioisotopes to the human foodchain after a serious nuclear accident

    International Nuclear Information System (INIS)

    Silva, S.

    1993-01-01

    The aim of the project is to produce a reduction of the transfer factors of radiocesium in plants, milk and meat owing to a deposition of radioactive products following a severe nuclear accident. The project includes two distinct working departments. The first studies the possibility to reduce the translocation of radiocesium from the areal parts to the edible products of crops. The second studies the possibility to reduce the radiocesium in the milk and in the meat as a consequence of the feeding with contaminated fodder. (R.P.) 4 refs., 5 figs., 7 tabs

  16. Characterization of Space Shuttle Thermal Protection System (TPS) Materials for Return-to-Flight following the Shuttle Columbia Accident Investigation

    Science.gov (United States)

    Wingard, Doug

    2006-01-01

    During the Space Shuttle Columbia Accident Investigation, it was determined that a large chunk of polyurethane insulating foam (= 1.67 lbs) on the External Tank (ET) came loose during Columbia's ascent on 2-1-03. The foam piece struck some of the protective Reinforced Carbon-Carbon (RCC) panels on the leading edge of Columbia's left wing in the mid-wing area. This impact damaged Columbia to the extent that upon re-entry to Earth, superheGed air approaching 3,000 F caused the vehicle to break up, killing all seven astronauts on board. A paper after the Columbia Accident Investigation highlighted thermal analysis testing performed on External Tank TPS materials (1). These materials included BX-250 (now BX-265) rigid polyurethane foam and SLA-561 Super Lightweight Ablator (highly-filled silicone rubber). The large chunk of foam from Columbia originated fiom the left bipod ramp of the ET. The foam in this ramp area was hand-sprayed over the SLA material and various fittings, allowed to dry, and manually shaved into a ramp shape. In Return-to-Flight (RTF) efforts following Columbia, the decision was made to remove the foam in the bipod ramp areas. During RTF efforts, further thermal analysis testing was performed on BX-265 foam by DSC and DMA. Flat panels of foam about 2-in. thick were sprayed on ET tank material (aluminum alloys). The DSC testing showed that foam material very close to the metal substrate cured more slowly than bulk foam material. All of the foam used on the ET is considered fully cured about 21 days after it is sprayed. The RTF culminated in the successful launch of Space Shuttle Discovery on 7-26-05. Although the flight was a success, there was another serious incident of foam loss fiom the ET during Shuttle ascent. This time, a rather large chunk of BX-265 foam (= 0.9 lbs) came loose from the liquid hydrogen (LH2) PAL ramp, although the foam did not strike the Shuttle Orbiter containing the crew. DMA testing was performed on foam samples taken fiom

  17. Investigating the effect of Alcohol Brief Interventions within accident and emergency departments using a data informatics methodology.

    Science.gov (United States)

    Baldacchino, Alex; O'Rourke, Louise; Humphris, Gerry

    2018-07-01

    Alcohol Brief Interventions (ABI) have been implemented throughout Scotland since 2008 and aim to reduce hazardous drinking through a Scottish Government funded initiative delivered in a range of settings, including Accident and Emergency (A and E) departments. To study the extent to which Alcohol Brief Interventions (ABI) are associated with later health service use. An opportunistic informatics approach was applied. A unique patient identifier was used to link patient data with core datasets spanning two years previous and two years post ABI. Variables included inpatient attendance, outpatient attendance, psychiatric admissions, and A and E attendance and prescribing. Patients (N = 1704) who presented at A and E departments who reported an average alcohol consumption of more than 8 units daily received the ABI. Fast Alcohol Screening Test (FAST) was used to assess patients for hazardous alcohol consumption. Multilevel linear modelling was employed to predict post-intervention utilisation using pre-ABI variables and controlling for person characteristics and venue. Significant decrease in A and E usage was found at one and two years following the ABI intervention. Previous health service use was predictive of later service use. A single question (Item 4) on the FAST was predictive of A and E attendance at one and two years. This investigation and methodology used provide support for the delivery of the ABI. However, it cannot be ascertained whether this is due to the ABI or simply is a result of making contact with a specialist in the addiction field. Copyright © 2018 Elsevier B.V. All rights reserved.

  18. On the results of investigating cause of sodium leak accident in prototype fast breeder reactor 'Monju' in Power Reactor and Nuclear Fuel Development Corporation

    International Nuclear Information System (INIS)

    1997-01-01

    The sodium leak accident in the secondary system of Monju occurred on December 8, 1995. The task force for investigating the accident was established in Nuclear Safety Bureau, and on May 23, 1996, the May report on the results of investigation was published. In order to elucidate the details of the fact that only one thermometer in the secondary system was broken and the reaction of leaked sodium with steel materials, the investigation was continued. In this report, also the results of these additional investigations are included. First, the accident of this time is outlined. As for the cause of the occurrence of sodium leak, the examination of the fracture surface of the broken thermometer, the high cycle fatigue due to hydrodynamic vibration, the investigation of the design, manufacture and installation of the thermometer, and the evaluation of secondary system thermometers which were not broken are reported. The cause that only one thermometer was broken was the way of its insertion which made the restraint of vibration amplitude ineffective. As the effects of sodium leak, the pile of sodium compound on floor liner, the damage of ducts and gratings, and the color change of concrete walls were observed. The burning experiment due to sodium leak was carried out to confirm the effects. (K.I.)

  19. Isotopic and chemical investigations of quaternary aquifer in sinai peninsula

    International Nuclear Information System (INIS)

    Sadek, M.A.; Ahmed, M.A.; Awad, M.A.

    2001-01-01

    The present study has been conducted to investigate the renewal activity and mineralization potential of the quaternary aquifer in Sinai peninsula using environmental isotopes and hydrochemistry. The quaternary aquifer is vital for development processes as it has a wide extension and shallow water table. The total dissolved salts vary greatly from one location to another and range widely between 510-7060 mg/1, reflecting all categories from fresh to saline water. The change in salinity all over Sinai can be attributed to variations in the rate of evaporation. Leaching and dissolution of terrestrial salts during floods as well as the effects of sea spray and saline water intrusion. The main sources of groundwater recharge are the infiltration of Local precipitation and surface runoff as well as lateral flow through hydraulic connection with fractured aquifers. Snow melt also contributes to aquifer recharge in some areas in the central part of southern Sinai. The environmental stable isotopic contents of the ground water in the quaternary aquifer in Sinai reflect the isotopic composition of rain water from continental and east Mediterranean precipitation and monsonal air mass which comes from Indian ocean as well as the seepage of partly evaporated floodwater. The southern samples are more suitable for drinking and irrigation purposes due to its lower salinity and sodium hazard

  20. Recriticality, a Key Phenomenon to Investigate in Core Disruptive Accident Scenarios of Current and Future Fast Reactor Designs

    International Nuclear Information System (INIS)

    Maschek, W.; Rineiski, A.; Flad, M.; Kriventsev, V.; Gabrielli, F.; Morita, K.

    2012-01-01

    Final comments and conclusions: • Modern plants, should have performed better under Fukushima type event. • In future fast reactor systems significantly higher active and passive safety features are installed, which should cope with events like Fukushima. • One important lesson: put a focus on rare initiators, accident routes and consequences that are neither expected nor have been observed, events that are categorized under ‘black swans’. • Importance of severe accident research demonstrated - both analytically and experimentally for assessing and interpreting accident scenarios and developments. Precondition for developing preventive & mitigative safety measures. Passive safety measures are in the focus of advanced design options and must work under conditions of multiple loads and aggravating events. • Fast reactor systems behavior as the SFR under severe accident conditions: – In fast spectrum systems as the SFR the core is not in its neutronically most reactive configuration and SFRs may be loaded with MAs for waste management; – Recriticalities have a high probability because of the higher enrichment levels; – Short time scales have to be envisioned for core melt-down; – Decay heat levels might be significantly higher, if MA bearing fuel is involved. • Improve design by measures for prevention and/or mitigation of recriticalities; – High reliability of simulations required for proof; • Assessment of fuel relocated on peripheral structures; • Preventive/mitigating measures should not replace containment measures

  1. Effect of Containment Spray Additives on the Chemical Effect after a Loss of Coolant Accident in Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Seung Chan; Park, Jong Woon; Lee, Guen Sung [KOREA HYDRO and NUCLEAR POWER Co., Daejeon (Korea, Republic of)

    2007-10-15

    As a part of USNRC GSI-191, evaluation of Kori Unit 1 ECCS recirculation sump performance has been carried out in 2006. The work is derived from the result of first PSR(Periodic Safety Review) of Kori Unit1. In this work, we have considered the replacement of spray additive in containment building to solve issues of GSI-191 and GL2004-02. We estimated the chemical effect of changing NaOH into TSP(Trisodium Phosphate) based on SRP(Standard Review Plan) 6.5.2. Rev.02. WCAP-16530 methodology is used to compare chemical effects of spray additive(or buffering agents). In the other side, chemical thermodynamic simulation can be utilized. Herein, the results using WCAP-16530 methodology and chemical simulation are presented.

  2. Preventing accidents

    Science.gov (United States)

    2005-08-01

    As the most effective strategy for improving safety is to prevent accidents from occurring at all, the Volpe Center applies a broad range of research techniques and capabilities to determine causes and consequences of accidents and to identify, asses...

  3. Inferring the chemical form of 137Cs deposited by the Fukushima Dai-ichi Nuclear Power Plant accident by measuring (137)Cs incorporated into needle leaves and male cones of Japanese cedar trees.

    Science.gov (United States)

    Kanasashi, Tsutomu; Takenaka, Chisato; Sugiura, Yuki

    2016-05-15

    We hypothesized that the water-soluble (ionic) and water-insoluble (stable) radiocesium from the initial fallout of the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident was distributed in various proportions in the surrounding areas and that this distribution was reflected in the trees that suffered deposition from the initial fallout. This study attempted to evaluate local variations in the chemical form of (137)Cs derived from the initial fallout of the FDNPP accident and whether its chemical form affected the radiocesium concentration in the tissues currently growing in trees, even after the initial fallout ceased. For these estimations, the ratio between the (137)Cs concentration in Cryptomeria japonica needle leaves in the tree crown, which existed before the FDNPP accident and subsequently directly exposed to the initial fallout ((137)Cs pre-accident N), and the amount of (137)Cs in the initial fallout itself ((137)Cs fallout) was determined ((137)Cs pre-accident N/(137)Cs fallout) at 66 sites. In addition, the (137)Cs ratios between the male cones produced in 2012 ((137)Cs male cone) and needle leaves that had elongated in the spring of 2011 ((137)Cs 2011N) was determined at 82 sites ((137)Cs male cone/(137) Cs 2011N). Most of the sites with lower (137)Cs pre-accident N /(137)Cs fallout ratios were distributed in eastern Fukushima, relatively close to the Pacific Ocean coastline. Lower (137)Cs pre-accident N/(137)Cs fallout and higher (137)Cs malecone/(137)Cs 2011N were found to be associated with higher proportions of (137)Cs in ionic forms. These observations are consistent with the hypothesis, and likely reflect regional variations in the chemical form of the deposited radiocesium. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Police recording of road accident in-patients : investigation into the completeness, representativity, and reliability of police records of hospitalized traffic victims. Article published in Accident Analysis and Prevention, 1984/06. 16(3) pp167-184.

    NARCIS (Netherlands)

    Maas, M.W. & Harris, S.

    1984-01-01

    Many road safety research projects make use of the official police road accident data. Their use is often restricted to the data of fatal accidents and fatalities because it is the only complete registration, and the extent of underreporting of injury accidents is unknown. The need to extend the use

  5. Investigations on the optimum design of chemical addition system for nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Byong Hoon [Junior College of Inchon, Inchon (Korea, Republic of); Chung, Chang Kyu; Choi, Han Rim; Kim, Eun Kee; Ro, Tae Sun [Korea Power Engineering Company, Inc. Taejon (Korea, Republic of)

    1997-12-31

    Mixing characteristics of the chemical additives in the chemical injection tank of the chemical and volume control system(CVCS) were investigated for the Yonggwang Nuclear units 5 and 6. Numerical calculations were performed with a low-Reynolds number turbulence model. Studies were also conducted for the injection tank with a disk located at 1/4H, 2/4H, and 3/4H from the inlet in order to see the effect in the enhancement of chemical mixing. Results show that the optimum arrangement is to locate a disk close to the inlet. 10 refs., 4 figs. (Author)

  6. Investigations on the optimum design of chemical addition system for nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Byong Hoon [Junior College of Inchon, Inchon (Korea, Republic of); Chung, Chang Kyu; Choi, Han Rim; Kim, Eun Kee; Ro, Tae Sun [Korea Power Engineering Company, Inc. Taejon (Korea, Republic of)

    1998-12-31

    Mixing characteristics of the chemical additives in the chemical injection tank of the chemical and volume control system(CVCS) were investigated for the Yonggwang Nuclear units 5 and 6. Numerical calculations were performed with a low-Reynolds number turbulence model. Studies were also conducted for the injection tank with a disk located at 1/4H, 2/4H, and 3/4H from the inlet in order to see the effect in the enhancement of chemical mixing. Results show that the optimum arrangement is to locate a disk close to the inlet. 10 refs., 4 figs. (Author)

  7. Chemical Investigations of Marine Filamentous and Zoosporic Fungi and Studies in Marine Microbial Chemical Ecology

    OpenAIRE

    Jenkins, Kelly M.

    1998-01-01

    The natural products chemistry of marine microorganisms is an emerging area of organic chemistry with the aim of discovering novel secondary metabolites exhibiting both biomedical and ecological activities. While marine bacteria have proven to be a productive source of new natural products, there are many groups of marine microorganisms which have not been fully investigated. In particular, marine fungi represent an untapped and potentially novel source of bioactive secondary metabolites. Whi...

  8. Co-operation of medical and chemical services to provide radiation safety in special zone during Chernobyl' accident response

    International Nuclear Information System (INIS)

    Terent'ev, V.I.

    1990-01-01

    Cooperation of medical and chemical services of the operation group in the special zone during intensive decontamination of the site and neighboring herritories at the Chernobyl NPP are considered. Responsibilities of medical and chemical services, their relations with civie and millitary organizations within the ChNPP region and 30-km zone are reviewed. Cooperation of the services mentioned above consisted in information exchange aimed at overall comprehension of the situation, cooperative activities in the commision and at elaboration of recommendations with an account of radiation safety measures

  9. Accident management for severe accidents

    International Nuclear Information System (INIS)

    Bari, R.A.; Pratt, W.T.; Lehner, J.; Leonard, M.; Disalvo, R.; Sheron, B.

    1988-01-01

    The management of severe accidents in light water reactors is receiving much attention in several countries. The reduction of risk by measures and/or actions that would affect the behavior of a severe accident is discussed. The research program that is being conducted by the US Nuclear Regulatory Commission focuses on both in-vessel accident management and containment and release accident management. The key issues and approaches taken in this program are summarized. 6 refs

  10. Theoretical investigations of the fission product release out of the core of a high temperature reactor during hypothetical heat up accidents as example of caesium

    International Nuclear Information System (INIS)

    Batalas, T.A.; Iniotakis, N.; Decken, C.B. von der.

    1986-03-01

    The investigation has been performed by means of a physical model, taking into account the micro- and macro-structures of the pyrolytical and graphitical reactor components as well as renouncing an introduction of effective diffusion coefficients by the description of the fission products transport through the coated particle layers and the fuel elements and renouncing an assumption of the spontaneously adsorption-desorption equilibrium on the surface of the fuel elements. The solving method and the respective computer codes were also developed. In addition the theoretically calculated and the experimentally determined results regarding the caesium release from single coated particles as well as fuel elements at accident temperatures were compared. Finally the caesium release from the core of the PNP-500 reactor during a heat up accident has been estimated and discussed. (orig./HP) [de

  11. A pharmacokinetic approach to investigate the uptake of 137Cs by children after the reactor accident in Chernobyl

    International Nuclear Information System (INIS)

    Wellner, U.

    1989-01-01

    The course of 137 Cs content of children after the reactor accident of Chernobyl measured by means of a whole-body counter could be reconstructed theoretically by a pharmacokinetic model. The children of the kindergarten of the hospital of the University of Cologne accumulated during the vegetation periods 1986/87 (I) 86.9, 1987/88 (II) 114.4 and 1988/89 (III) 24.4 Bq 137 Cs per kg body weight. (orig.) [de

  12. [An investigative report concerning safety and management in the magnetic resonance environment: there are more accidents than expected].

    Science.gov (United States)

    Doi, Tsukasa; Yamatani, Yuya; Ueyama, Tsuyoshi; Nishiki, Shigeo; Ogura, Akio; Kawamitsu, Hideaki; Tsuchihashi, Toshio; Okuaki, Tomoyuki; Matsuda, Tsuyoshi; Kumashiro, Masayuki

    2011-01-01

    Using a questionnaire, we surveyed 2,500 facilities in Japan to clarify medical accidents concerning the magnetic resonance device and its environment. Data derived from 1,319 valid responses (52.8%), allowed us to analyze the situation of (or the reason for) the occurrence of the accidents and their environmental factors. Five hundred and nine facilities (39% of all facilities) had the experience of magnetically induced displacement of the large ferromagnetic material. Intravenous (I.V.) drip stands were involved the largest number of them: 31% (228 cases). Oxygen bottles had the second largest number of incidents: 20%. There were also many incidents involving various materials brought in by non-medical staff (e.g. stepladder for construction). About 20% of the accidents occurred outside of working hours. Patients in 12% of the facilities (154 facilities) experienced burns. In 39 of the cases, burns were received to the inside of the thighs. In 38 of the cases, patients received burns from an electrical cable touching the skin. There were also frequent incidents of burning regarding the boa. We received reports of burns and pain from the halo vest even though it's required to be worn for MR safety. Regarding incidents of contraindications, 280 patients with pacemakers were brought into the magnetic resonance (MR) inspection room. Twelve percent of the facilities experienced natural quench. Lack of training for the staff who introduce and operate high magnetic field devices are considered involving frequently occurring accidents of attractions and burns at hospitals with over 500 beds caused by carrying in materials.

  13. Chernobyl accident

    International Nuclear Information System (INIS)

    Bar'yakhtar, V.G.

    1995-01-01

    The monograph contains the catastrophe's events chronology, the efficiency assessed of those measures assumed for their localization as well as their environmental and socio-economic impact. Among materials of the monograph the results are presented of research on the radioactive contamination field forming as well as those concerning the investigation of biogeochemical properties of Chernobyl radionuclides and their migration process in the environment of the Ukraine. The data dealing with biological effects of the continued combined internal and external radioactive influence on plants, animals and human health under the circumstances of Chernobyl accident are of the special interest. In order to provide the scientific generalizing information on the medical aspects of Chernobyl catastrophe, the great part of the monograph is allotted to appraise those factors affecting the health of different population groups as well as to depict clinic aspects of Chernobyl events and medico-sanitarian help system. The National Programme of Ukraine for the accident consequences elimination and population social protection assuring for the years 1986-1993 and this Programme concept for the period up to the year 2000 with a special regard of the world community participation there

  14. Investigations on Health Conditions of Chernobyl Nuclear Power Plant Accident Recovery Workers from Latvia in Late Period after Disaster

    Directory of Open Access Journals (Sweden)

    Reste Jeļena

    2016-10-01

    Full Text Available The paper summarises the main findings on Chernobyl Nuclear Power Plant (CNPP accident recovery workers from Latvia and their health disturbances, which have been studied by the authors during the last two decades. Approximately 6000 persons from Latvia participated in CNPP clean-up works in 1986–1991. During their work period in Chernobyl they were exposed to external as well as to internal irradiation, but since their return to Latvia they were living in a relatively uncontaminated area. Regular careful medical examinations and clinical studies of CNPP clean-up workers have been conducted during the 25 years after disaster, gathering knowledge on radiation late effects. The aim of the present review is to summarise the most important information about Latvian CNPP clean-up worker health revealed by thorough follow-up and research conducted in the period of 25 years after the accident. This paper reviews data of the Latvian State Register of Persons Exposed to Radiation due to CNPP Accident and gives insight in main health effects found by the researchers from the Centre of Occupational and Radiological Medicine (Pauls Stradiņš Clinical University Hospital and Rīga Stradiņš University in a number of epidemiological, clinical, biochemical, immunological, and physiological studies. Latvian research data on health condition of CNPP clean-up workers in the late period after disaster indicate that ionising radiation might cause premature ageing and severe polymorbidity in humans.

  15. The EPR investigation of tooth enamel for measurements of tooth enamel for measurements of absorbed gamma doses of people irradiated in Chernobyl accident

    International Nuclear Information System (INIS)

    Baran, N.P.; Barchuk, V.I.; Bar'yakhtar, V.G.; Bugaj, A.A.; Koval', G.N.; Maksimenko, V.M.; Berezhnoj, A.B.; Zakharash, M.P.; AN Ukrainskoj SSR, Kiev

    1993-01-01

    The EPR spectra of the tooth enamel of Chernobyl 'liquidators' were investigated. A lot of people were engaged in work at the Chernobyl area after the accident in 1986. A part of them is under regular medical control at the Ukrainian security service hospital. When patients lose the teeth for some reasons the EPR spectra of radiation centers in tooth enamel caused by emergency gamma radiation were investigated. The measurement of the intensities of the EPR spectra give the real individual absorbed doses of gamma radiation which are much higher than the official values registered in the medical cards of liquidators

  16. [Analisys of work-related accidents and incidents in an oil refinery in Rio de Janeiro].

    Science.gov (United States)

    de Souza, Carlos Augusto Vaz; de Freitas, Carlos Machado

    2003-01-01

    Accidents in the chemical industry can have serious consequences for workers, communities, and the environment and are thus highly relevant to public health. This article is the result of an occupational surveillance project involving several public institutions. We analyze 800 work-related accidents that resulted in injuries, environmental damage, or loss of production in 1997 in an oil refinery located in Rio de Janeiro, Brazil. The methodology was based on managerial and organizational approaches to accident investigation, with the European Union reporting system as the reference. The results highlight various limitations in the process of reporting and investigating accidents, as well as a certain hierarchy of accidents, with more attention given to accidents involving loss of production and less to those resulting in injuries, particularly among outsourced workers.

  17. Utilization of the IAIA (Investigation and Analysis of Incidents and Accidents) method in the investigation of the P-36 platform accident; Utilizacao do metodo IAIA (Investigacao e Analise de Acidentes e Incidentes) na investigacao do acidente ocorrido na plataforma P-36

    Energy Technology Data Exchange (ETDEWEB)

    Teles, Marcus de Barros [ARCE - Agencia Reguladora de Servicos Publicos Delegados do Estado do Ceara, Fortaleza, CE (Brazil)

    2004-07-01

    In the beginning of XXI century the Brazilian oil industry report a big accident involving that which was the biggest petroleum platform of the world. With capacity production of 180.000 barrels a day and capacity compression of 7,2 million cubic meter a day of natural gas, the off-shore platform P-36 was situated on Roncador field, in Campos basin, operating in 1360 meters of water. As consequences, eleven deaths with irreparable traumas to the families, friends and worker partners, one billion dollars in prejudices to brazilian country, environmental damages by oil leak and injuries to PETROBRAS reputation in Brazil and in the world. The method of investigation and analysis of incidents and accidents - IAIA is very wide and its philosophy contain a lot of topics, since basic concepts, investigation actions, analysis action and diagnosis by the general kind of fail. Using this method and taking advantage from the report elaborated by the commission organized by ANP - Agencia Nacional do Petroleo and DPC - Diretoria de Portos e Costas, responsible for the investigation and analysis of the accident occurred with P-36, this paper identify the direct and indirect causes of the accident, in attempt to avoid new similar situations. (author)

  18. Investigation of indoor chemical pollutants and perceived odor in an area with complaints of unpleasant odors

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Chiung-Yu.; Wu, Tzong-Jer [Graduate Institute of Occupational Safety and Health, Kaohsiung Medical University, 100, Shih-Chuan 1st Road, Kaohsiung 807 (China); Lan, Cheng-Hang [Department of Occupational Safety and Health, Chung-Hwa University of Medical Technology, Tai-Nan County 717 (China)

    2009-10-15

    An uncomfortable smell was reported by employees of an IT office (information technological office) in a medical center. This problem started two years ago when the office was refurbished. The objectives of this study are to characterize the indoor air quality of this complaint area in terms of chemical pollutants and odor characteristics, and identify possible sources of this foul smell. Carbonyl chemicals and volatile organic compounds (VOCs) were investigated in this study, since these two groups are associated with odors and health effects. Additionally, the odor was evaluated by odor assessors (non-smokers) who recorded odor characters that appeared in offices. By comparing chemical measurements between complaint and non-complaint areas, calculating odor indices, and correlating odor and chemical measurements, we got results showing that a higher correlation coefficient is found between odor presence frequencies and VOC concentrations. Further investigating found nonanal and decanal are possible chemicals for malodors. The concentration levels of these two chemicals in the complaint area are higher than those in the non-complaint areas and exceeding odor thresholds. Possible sources of these long-chain aldehydes are formed during the oxidation degradations of fatty acids like linoleic acid, linolenic acid and oleic acid which are ingredients for many building products like linoleum and surface coating. In order to mitigate this malodor problem, extra and effective ventilation flow rate should be provided to reduce the concentrations of odorous chemicals and the precursors for these odorous chemicals. (author)

  19. Household Chemical Emergencies

    Science.gov (United States)

    ... Content Home Be Informed Household Chemical Emergencies Household Chemical Emergencies Although the risk of a chemical accident ... reduce the risk of injury. Before a Household Chemical Emergency It is critical to store household chemicals ...

  20. Longitudinal investigation into implicit stigma of epilepsy among Japanese medical students before and after mass media coverage of car accidents associated with people with epilepsy.

    Science.gov (United States)

    Nagamori, Chizuko; Hara, Keiko; Ohta, Katsuya; Akaza, Miho; Sumi, Yuki

    2017-08-01

    Public attitudes and stigma toward epilepsy may limit patient motivation for treatment and participation in social activities. Stigma research requiring individuals to report personal beliefs is useful but is subject to social desirability bias. Self-reporting methods often do not capture implicit attitudes; therefore, in this study, implicit stigma was measured using the implicit association test (IAT), which is a word sorting task to minimize this bias. Recently, in Japan, several serious car accidents caused by people with epilepsy (PWE) resulted in pedestrian fatalities. Traffic accidents involving PWE have been reported extensively and repeatedly in the media since 2011. The present study aimed to examine differences in implicit stigma toward epilepsy among medical students in 2010, 2013, and 2016. We recruited 41 medical students in 2010, 44 medical students in 2013 and 42 medical students in 2016. We investigated the strength of conceptual associations between the words "Epilepsy" or "Hypertension", and "Safety" or "Danger" in the IAT. The association between the words "Epilepsy" and "Danger" was stronger in 2013 compared with that in 2010; however, the association was weaker in 2016 compared with that in 2013. There was no significant difference between 2010 and 2016. The change in IAT results between 2010 and 2013 might be due to the traffic accident involving PWE in Japan. However, the result in 2016 might indicate that the implicit attitudes toward epilepsy were improved to the same level as those in 2010. Copyright © 2017 Elsevier Inc. All rights reserved.

  1. [Bioinorganic chemical composition of the lens and methods of its investigation].

    Science.gov (United States)

    Avetisov, S E; Novikov, I A; Pakhomova, N A; Motalov, V G

    2018-01-01

    Bioinorganic chemical composition of the lens of human and experimental animals (cows, dogs, rats, rabbits) have been analyzed in various studies. In most cases, the studies employed different methods to determine the gross (total) composition of chemical elements and their concentrations in the examined samples. Less frequently, they included an assessment of the distribution of chemical elements in the lens and correlation of their concentration with its morphological changes. Chemical elements from all groups (series) of the periodic classification system were discovered in the lens substance. Despite similar investigation methods, different authors obtained contradicting results on the chemical composition of the lens. This article presents data suggesting possible correlation between inorganic chemical elements in the lens substance with the development and formation of lenticular opacities. All currently employed methods are known to only analyze limited number of select chemical elements in the tissues and do not consider the whole range of elements that can be analyzed with existing technology; furthermore, the majority of studies are conducted on the animal model lens. Therefore, it is feasible to continue the development of the chemical microanalysis method by increasing the sensitivity of Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS) with the purpose of assessing the gross chemical composition and distribution of the elements in the lens substance, as well as revealing possible correlation between element concentration and morphological changes in the lens.

  2. Chernobyl accident

    International Nuclear Information System (INIS)

    Capra, D.; Facchini, U.; Gianelle, V.; Ravasini, G.; Bacci, P.

    1988-01-01

    The radioactive cloud released during the Chernobyl accident reached the Padana plain and Lombardy in the night of April 30th 1986; the cloud remained in the northern Italian skies for a few days and then disappeared either dispersed by winds and washed by rains. The evidence in atmosphere of radionuclides as Tellurium, Iodine, Cesium, was promptly observed. The intense rain, in first week of may, washed the radioactivity and fall-out contamined the land, soil, grass. The present work concerns the overall contamination of the Northern Italy territory and in particular the radioactive fall-out in the Lakes region. Samples of soil have been measured at the gamma spectroscope; a correlation is found between the radionuclides concentration in soil samples and the rain intensity, when appropriate deposition models are considered. A number of measurements has been done on the Como'lake ecosystem: sediments, plankton, fishes and the overall fall-out in the area has been investigated

  3. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 3—Calcium

    Energy Technology Data Exchange (ETDEWEB)

    Olson, Sterling; Ali, Amir; LaBrier, Daniel [Department of Nuclear Engineering, University of New Mexico (United States); Blandford, Edward D, E-mail: edb@unm.edu [Department of Nuclear Engineering, University of New Mexico (United States); Howe, Kerry [Department of Civil Engineering, University of New Mexico (United States)

    2016-04-15

    Highlights: • Calcium leaching from NUKON fiberglass in borated TSP-buffered solution is independent of the level of fiberglass destruction. • The initial calcium release rate and the maximum calcium concentration increases with increased fiber concentration. • The calcium release in solution has a repeatable pattern of four distinct regions (prompt release, metastable, autocatalytic drop, and stable region) for all experiments. • Magnesium plays a significant role in initiating calcium precipitation in TSP-buffered environment. • Head loss through multi-constituents debris beds was found to increase progressively in all calcium concentration regions. - Abstract: Calcium that leaches from damaged or destroyed NUKON fiberglass in containment post a loss of coolant accident (LOCA) could lead to the formation of chemical precipitates. These precipitates could be filtered through the accumulated fibrous debris on the sump screen and compromising the emergency core cooling system (ECCS) sump pump performance. Reduced-scale leaching experiments were conducted on three solution inventory scales—bench (0.5 L), vertical column (31.5 L), and tank (1136 L) using three different flow conditions, and fiberglass concentrations (1.18–8 g/L) to investigate calcium release from NUKON fiber. All experiments were conducted in simulated post-LOCA water chemistry. (∼220 mM boric acid with ∼5.8 mM trisodium phosphate (TSP) buffer). Prior to the leaching tests, a preliminary experiment was carried out on the bench scale to determine the effect of the fiber preparation (unaltered and blended) method on calcium leaching. Results indicate that the extent of fiberglass destruction does not affect the amount of calcium released from fiberglass. Long-term calcium leach testing at constant temperature (80 °C) in borated TSP-buffered solution had repeatable behavior on all solution scales for different fiberglass concentrations. The calcium-leaching pattern can be divided into

  4. Savannah River Site RCRA Facility Investigation plan: Road A Chemical Basin

    International Nuclear Information System (INIS)

    1989-06-01

    The nature of wastes disposed of at the Road A Chemical Basin (RACB) is such that some degree of soil contamination is probable. Lead has also been detected in site monitoring wells at concentrations above SRS background levels. A RCRA Facility Investigation (RFI) is proposed for the RACB and will include a ground penetrating radar (GPR) survey, collection and chemical and radiological analyses of soil cores, installation of groundwater monitoring wells, collection and chemical and radiological analyses of groundwater samples, and collection of chemical and radiological analyses of surface water and sediment samples. Upon completion of the proposed RFI field work and chemical and radiological analyses, and RFI report should be prepared to present conclusions on the nature and extent of contamination at the site, and to make recommendations for site remediation. If contamination is detected at concentrations above SRS background levels, a receptor analysis should be done to evaluate potential impacts of site contamination on nearby populations

  5. Effect of alternative aging and accident simulations on polymer properties

    International Nuclear Information System (INIS)

    Bustard, L.D.; Chenion, J.; Carlin, F.; Alba, C.; Gaussens, G.; LeMeur, M.

    1985-05-01

    The influence of accident irradiation, steam, and chemical spray exposures on the behavior of twenty-three age-preconditioned polymer sample sets (twenty-one different materials) has been investigated. The test program varied the following conditions: (1) Accident simulations of irradiation and thermodynamic (steam and chemical spray) conditions were performed both sequentially and simultaneously. (2) Accident thermodynamic (steam and chemical spray) exposures were performed both with and without air present during the exposures. (3) Sequential accident irradiations were performed both at 28 0 C and 70 0 C. (4) Age preconditioning was performed both sequentially and simultaneously. (5) Sequential aging irradiations were performed both at 27 0 C and 70 0 C. (6) Sequential aging exposures were performed using two sequences: (1) thermal followed by irradiation and (2) irradiation followed by thermal. We report both general trends applicable to a majority of the tested materials as well as specific results for each polymer. Our data base consists of ultimate tensile properties at the completion of the accident exposure for three XLPO and XLPE, five EPR and EPDM, two CSPE (HYPALON), one CPE, one VAMAC, one polydiallylphtalate, and one PPS material. We also report bend test results at completion of the accident exposures for two TEFZEL materials and permanent set after compression results for three EPR, one VAMAC, one BUNA N, one SILICONE, and one VITON material

  6. Nuclear accidents

    International Nuclear Information System (INIS)

    1987-01-01

    On 27 May 1986 the Norwegian government appointed an inter-ministerial committee of senior officials to prepare a report on experiences in connection with the Chernobyl accident. The present second part of the committee's report describes proposals for measures to prevent and deal with similar accidents in the future. The committee's evaluations and proposals are grouped into four main sections: Safety and risk at nuclear power plants; the Norwegian contingency organization for dealing with nuclear accidents; compensation issues; and international cooperation

  7. Reconstruction of the size of nuclear fuel particle aerosol by the investigation of a radionuclide behaviour in body of the Chernobyl accident witnesses

    International Nuclear Information System (INIS)

    Kutkov, V.A.

    1996-01-01

    As a result of the Chernobyl NPP (ChNPP) accident aerosol particles of dispersed nuclear fuel were released to the atmosphere. Inhalation of those aerosol became the source of internal exposure for witnesses of the Chernobyl accident. To assess correctly internal doses from a mixture of radionuclides present in air in the form of aerosol particles one mast assign each radionuclide to a certain inhalation class by its chemical speciation in aerosol and define the airborne characteristics (the activity median aerodynamic diameter, AMAD and the standard geometric deviation, fig) of that particular aerosol. Moreover, information on any particular radionuclide is useless for other components since, in such a mixture, the radionuclides are generally independent and may belong to different particles. On the contrary, all nuclear fuel particle (NFP) radionuclides belong to the same particle, being matrix-bound. The collective behaviour of the matrix-bound radionuclides in the environment and in the human barrier organs makes it possible to spread to the aerosol of NFP any estimates of AMAD and β g obtained for any particular NFP radionuclide. This is principal feature of NFP aerosol as distinguished from a mere mixture of aerosol particles carry different radionuclides. (author)

  8. Techniques for SMM/THz Chemical Analysis: Investigations and Exploitation of the Large Molecule Limit

    Science.gov (United States)

    2014-03-03

    SECURITY CLASSIFICATION OF: It has long been recognized that the SMM /THz has a unique combinations of attributes that make it attractive as a basis for...applicability of SMM chemical sensors; the second is to explore infrared – SMM double resonance as a basis for atmospheric remote sensing; and the third...2014 12-Aug-2009 11-Aug-2013 Approved for Public Release; Distribution Unlimited Techniques for SMM /THz Chemical Analysis: Investigations and

  9. Report of the investigation of the accident at the MIDAS MYTH/MILAGRO Trailer Park on Rainier Mesa at Nevada Test Site on February 15, 1984

    International Nuclear Information System (INIS)

    1984-01-01

    Fourteen persons were injured, one fatally, when the ground upon which they were working collapsed, forming a subsidence crater in the recording trailer park of the MIDAS MYTH/MILAGRO nuclear weapons effects test on Rainier Mesa at the US Department of Energy's Nevada Test Site on February 15, 1984. Those persons injured were contractor and laboratory employees from Reynolds Electrical and Engineering Co., Inc. (REECo), Pan American World Services, Inc. (PANAM), and the Los Alamos National Laboratory (LANL). This report presents the results of an investigation into the causes, effects, and response to the accident. 42 figures

  10. Model for melt blockage (slug) relocation and physico-chemical interactions during core degradation under severe accident conditions

    International Nuclear Information System (INIS)

    Veshchunov, M.S.; Shestak, V.E.

    2008-01-01

    The model describing massive melt blockage (slug) relocation and physico-chemical interactions with steam and surrounding fuel rods of a bundle is developed on the base of the observations in the CORA tests. Mass exchange owing to slug oxidation and fuel rods dissolution is described by the previously developed 2D model for the molten pool oxidation. Heat fluxes in oxidising melt along with the oxidation heat effect at the melt relocation front are counterbalanced by the heat losses in the surrounding media and the fusion heat effect of the Zr claddings attacked by the melt. As a result, the slug relocation velocity is calculated from the heat flux matches at the melt propagation front (Stefan problem). A numerical module simulating the slug behaviour is developed by tight coupling of the heat and mass exchange modules. The new model demonstrates a reasonable capability to simulate the main features of the massive slug behaviour observed in the CORA-W1 test

  11. Status and results of the theoretical and experimental investigations on the LWR fuel rod behavior under accident conditions

    International Nuclear Information System (INIS)

    Bocek, M.; Hofmann, P.; Leistikow, S.; Class, G.; Meyder, R.; Raff, S.; Erbacher, F.; Hofmann, G.; Ihle, P.; Karb, E.; Fiege, A.

    1978-09-01

    In this report the status of knowledge is described which has been gathered up to the end of 1977 of the LWR fuel rod behavior in loss-of-coolant accidents. The majority of results indicated have been derived from studies on the fuel rod behavior performed within the framework of the Nuclear Safety Project (PNS); partly, also the results of cooperating research establishments and fm international exchange of experience are referred to. The report has been subdivided into two complete parts: Part I provides a survey of the most significant results of the theoretical and experimental research projects on fuel rod behavior. Part II describes by detailed individual presentations the status as well as the results with respect to the major central subjects. (orig.) 891 RW 892 AP [de

  12. Survey of awareness about hazardous chemicals of residents living near chemical plants in South Korea.

    Science.gov (United States)

    Han, Don-Hee; Park, Min Soo

    2018-02-10

    With economic growth, the use of chemicals has continually increased, resulting in an increase of chemical accidents. Chemical accidents pose a life threat and can lead to many health problems among the residents living in close proximity to chemical plants. This study aimed to investigate the awareness of the residents living near chemical plants about hazardous chemicals, as well as to survey the awareness of workers who do not directly handle chemicals at chemical plants (WNHCs). To this end, a questionnaire survey was conducted among a total of 600 residents and 160 WNHCs. The questionnaire was composed of three items: awareness of chemical risk, awareness of countermeasures in chemical accidents, and imperious necessity of PPE (personal protective equipment). Statistical analysis of the data was performed with the Statistical Package for Social Sciences (SPSS) version 18.0. The results show that the government needs to complement the notification system of chemical risk for residents who live close to chemical plants. The highest priority of PPE which residents want to prepare for chemical accidents was respiratory protective equipment (RPE). They responded that, if necessary to purchase PPE, they could bear a portion of the expenses (up to US $30). This study provides basic data for the development of programs and policies on chemical safety relevant for the residents living in close proximity to chemical plants in South Korea.

  13. Radiation accidents and defence of population

    International Nuclear Information System (INIS)

    Memmedov, A.M.

    2002-01-01

    Full text: Development of nuclear physics, the fundamental and the applied researches in the field of radioactive insured wide possibility for application of radionuclides and ionizing radiation source in the different fields of national economy. Application of radionuclides in chemical, metallurgical, food industry, in agriculture and etc. Fields provide a large economic profit. It's hard to apprise significance of ionizing radiation source using in medicine for diagnostics and treatment of different disease. Nuclear power engineering and nuclear industry are developing intensively. At same time nuclear power, ionizing radiation sources incur potential treat for surroundings and health of population. As even that stage of protective measure development: there is no possibility of that happening of radiation accidents. A radiation accident qualifies as loss of ionizing radiation sources direction, which provoked by disrepair equipment, natural calamity or other causes which could bring to unplanned irradiation of population or radioactive pollution of surroundings. At present some following typical cases connected with radiation accident have been chosen: Contentious using or keeping of ionizing radiation source with breach of established requires; Loss, theft of ionizing radiation sources or radiation plants, instruments; Leaving the sources of ionizing radiation in the holes; Refusal radiation technic exploited in industry, medicine, SRI and etc; Disrepair in nuclear transport means of conveyance; Crashes and accidents at NPP and at other enterprises of nuclear industry. The radiation accidents according to character, degree and scales have been divided into two groups: Radiation accidents not connected with NPP; Accidents in the nuclear engineering and industry; The radiation accidents not connected with NPP according their consequence divide into 5 groups; accidents which do not come to irradiation of personal, persons from population (more PN-permissible norm

  14. Chemical investigation on wood tree species in a temperate forest, east-northern Romania

    Directory of Open Access Journals (Sweden)

    Teaca, C. A.

    2007-02-01

    Full Text Available A quantitative evaluation of wood chemical components for some tree species in a forest area from east-northern Romania is presented here, through a comparative study from 1964 to 2000. Investigation upon the wood tree-rings in a Quercus robur L. tree species, as a dominant species, as regards its chemical composition and structure of the natural polymer constituents - cellulose and lignin - was also performed through chemical methods to separate the main wood components, FT-IR spectroscopy, and thermogravimetry. Having in view the impact of climate and external factors (such as pollutant depositions, some possible correlations between wood chemical composition and its further use can be made. The FT-IR spectra give evidence of differences in the frequency domains of 3400-2900 cm-1 and 1730-1640 cm-1, due to some interactions between the chemical groups (OH, C=O. The crystallinity index of cellulose presents variations in the oak wood tree-rings. Thermogravimetry analyses show different behaviour of cellulose at thermal decomposition, as a function of radial growth and tree’s height. A preliminary chemical investigation of oak wood sawdust shows a relatively high content of mineral elements (ash, compared with a previous study performed in 1964, fact that may indicate an intense drying process of the oak tree, a general phenomenon present in European forests for this species.

  15. Skidding accidents : considerations on road surface and vehicle characteristics : summary of the present situation. Provisional recommendation concerning skidding resistance of road surfaces investigation programme. Interim report of the SWOV Working Group "Tyres, road surfaces and skidding accidents"

    NARCIS (Netherlands)

    SWOV Working Group "Tyres, road surfaces and skidding accidents"

    1970-01-01

    This is the first report of SWOV Working Group "Tyres, road surfaces and skidding accidents". Skidding is considered to be an important contributory factor in traffic accidents. Skidding can in principle be prevented in two ways, viz: (1) reduction of the minimum necessary friction, and (2)

  16. Quantum chemical investigation of levofloxacin-boron complexes: A computational approach

    Science.gov (United States)

    Sayin, Koray; Karakaş, Duran

    2018-04-01

    Quantum chemical calculations are performed over some boron complexes with levofloxacin. Boron complex with fluorine atoms are optimized at three different methods (HF, B3LYP and M062X) with 6-31 + G(d) basis set. The best level is determined as M062X/6-31 + G(d) by comparison of experimental and calculated results of complex (1). The other complexes are optimized by using the best level. Structural properties, IR and NMR spectrum are examined in detail. Biological activities of mentioned complexes are investigated by some quantum chemical descriptors and molecular docking analyses. As a result, biological activities of complex (2) and (4) are close to each other and higher than those of other complexes. Additionally, NLO properties of mentioned complexes are investigated by some quantum chemical parameters. It is found that complex (3) is the best candidate for NLO applications.

  17. Using Think-Aloud Protocols to Investigate Secondary School Chemistry Teachers' Misconceptions about Chemical Equilibrium

    Science.gov (United States)

    Cheung, Derek

    2009-01-01

    Secondary school chemistry teachers' understanding of chemical equilibrium was investigated through interviews using the think-aloud technique. The interviews were conducted with twelve volunteer chemistry teachers in Hong Kong. Their teaching experience ranged from 3 to 18 years. They were asked to predict what would happen to the equilibrium…

  18. Investigating High-School Chemical Kinetics: The Greek Chemistry Textbook and Students' Difficulties

    Science.gov (United States)

    Gegios, Theodoros; Salta, Katerina; Koinis, Spyros

    2017-01-01

    In this study we present an analysis of how the structure and content of the Greek school textbook approaches the concepts of chemical kinetics, and an investigation of the difficulties that 11th grade Greek students face regarding these concepts. Based on the structure and content of the Greek textbook, a tool was developed and applied to…

  19. Chemical properties of gutta-percha endodontic filling material: investigation of five commercial brands

    International Nuclear Information System (INIS)

    Silva Junior, Joao Batista A.; Paula, Regina C.M.; Feitosa, Judith P.A.; Gurgel Filho, Eduardo; Teixeira, Fabricio B

    2001-01-01

    Chemical composition e thermal stability of five brands of gutta-percha endodontic filling material were investigated. Samples with higher amount of organic materials possess higher thermal stability. Investigation of gutta-percha polymer extracted from the endodontic filling by IR and NMR shows that the polymer is predominantly trans-polyisoprene. The thermal stability and molar mass were similar for four brands, however the 'Tanari' brand has got lower molar mass value than the other ones. (author)

  20. THE CBS SPECTRA INVESTIGATION AS METHOD OF THE PN CHEMICAL COMPOSITION ANALYSIS

    OpenAIRE

    Shimanskaya, N. N.; Shimansky, V. V.; Bikmaev, I. F.; Sakhibullin, N. A.; Zhuchkov, R. Ya.

    2007-01-01

    We report the results of the investigations of chemical composition of close binaries which had gone through the stage of common envelope and which are the remnants of planetary nebular cores. High resolution spectra for different phases of orbital period of V471 Tau were taken by RTT-150 telescope and were investigated by the modified SYNTH-K program. It was found that the spectra show noticeable variability with appearance of emission components depended on the orbital period phase. For che...

  1. Normal accidents

    International Nuclear Information System (INIS)

    Perrow, C.

    1989-01-01

    The author has chosen numerous concrete examples to illustrate the hazardousness inherent in high-risk technologies. Starting with the TMI reactor accident in 1979, he shows that it is not only the nuclear energy sector that bears the risk of 'normal accidents', but also quite a number of other technologies and industrial sectors, or research fields. The author refers to the petrochemical industry, shipping, air traffic, large dams, mining activities, and genetic engineering, showing that due to the complexity of the systems and their manifold, rapidly interacting processes, accidents happen that cannot be thoroughly calculated, and hence are unavoidable. (orig./HP) [de

  2. Theoretical investigations of the meltoff and resolidification process of fuel claddings during accidents in liquid metal cooled fast breeder reactors

    International Nuclear Information System (INIS)

    Angerer, G.

    1978-08-01

    During loss-of-coolant-flow accidents in liquid metal cooled fast breeder reactors with failure to scram the fuel claddings will melt after boiling and evaporation of the coolant. The CMOT model presented here describes the subsequent process of relocation and resolidification of the molten claddings. The basic thermohydrodynamics equations of the two-phase flow of cladding material and sodium vapor are solved numerically by differential approximations in a Eulerian reference net. The results calculated by the model improved the insight into the dynamics of the cladding relocation process. Here are the main results: - Shortly after the onset of cladding relocation large waves of molten cladding material are generated. The motion of these waves contributes considerably to the material transport. - The dynamics of cladding relocation exhibits strong local incoherences. - The formation of cladding blockages observed at the ends of the fuel region is confirmed by the calculations. - In case of incoherent cladding meltoff less cladding material is transported upwards. - Cladding relocation strongly depends on the axial pressure drop and the underlying friction factor correlations. Recalculation of the R5 loss-of-coolant-flow experiment performed in the U.S. TREAT test reactor is in good agreement with the experimental data. (orig./HP) 891 HP [de

  3. Database on aircraft accidents

    International Nuclear Information System (INIS)

    Nishio, Masahide; Koriyama, Tamio

    2012-09-01

    The Reactor Safety Subcommittee in the Nuclear Safety and Preservation Committee published the report 'The criteria on assessment of probability of aircraft crash into light water reactor facilities' as the standard method for evaluating probability of aircraft crash into nuclear reactor facilities in July 2002. In response to the report, Japan Nuclear Energy Safety Organization has been collecting open information on aircraft accidents of commercial airplanes, self-defense force (SDF) airplanes and US force airplanes every year since 2003, sorting out them and developing the database of aircraft accidents for latest 20 years to evaluate probability of aircraft crash into nuclear reactor facilities. This year, the database was revised by adding aircraft accidents in 2010 to the existing database and deleting aircraft accidents in 1991 from it, resulting in development of the revised 2011 database for latest 20 years from 1991 to 2010. Furthermore, the flight information on commercial aircrafts was also collected to develop the flight database for latest 20 years from 1991 to 2010 to evaluate probability of aircraft crash into reactor facilities. The method for developing the database of aircraft accidents to evaluate probability of aircraft crash into reactor facilities is based on the report 'The criteria on assessment of probability of aircraft crash into light water reactor facilities' described above. The 2011 revised database for latest 20 years from 1991 to 2010 shows the followings. The trend of the 2011 database changes little as compared to the last year's one. (1) The data of commercial aircraft accidents is based on 'Aircraft accident investigation reports of Japan transport safety board' of Ministry of Land, Infrastructure, Transport and Tourism. 4 large fixed-wing aircraft accidents, 58 small fixed-wing aircraft accidents, 5 large bladed aircraft accidents and 114 small bladed aircraft accidents occurred. The relevant accidents for evaluating

  4. Inferring the chemical form of {sup 137}Cs deposited by the Fukushima Dai-ichi Nuclear Power Plant accident by measuring {sup 137}Cs incorporated into needle leaves and male cones of Japanese cedar trees

    Energy Technology Data Exchange (ETDEWEB)

    Kanasashi, Tsutomu, E-mail: kanasashi.tsutomu@g.mbox.nagoya-u.ac.jp [Graduate School of Bioagricultural Sciences, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601 (Japan); Takenaka, Chisato [Graduate School of Bioagricultural Sciences, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601 (Japan); Sugiura, Yuki [Japan Atomic Energy Agency, 765-1 Funaishikawa, Tokai-mura, Naka-gun, Ibaraki 319-1184 (Japan)

    2016-05-15

    We hypothesized that the water-soluble (ionic) and water-insoluble (stable) radiocesium from the initial fallout of the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident was distributed in various proportions in the surrounding areas and that this distribution was reflected in the trees that suffered deposition from the initial fallout. This study attempted to evaluate local variations in the chemical form of {sup 137}Cs derived from the initial fallout of the FDNPP accident and whether its chemical form affected the radiocesium concentration in the tissues currently growing in trees, even after the initial fallout ceased. For these estimations, the ratio between the {sup 137}Cs concentration in Cryptomeria japonica needle leaves in the tree crown, which existed before the FDNPP accident and subsequently directly exposed to the initial fallout ({sup 137}Cs{sub pre-accident} {sub N}), and the amount of {sup 137}Cs in the initial fallout itself ({sup 137}Cs{sub fallout}) was determined ({sup 137}Cs{sub pre-accident} {sub N}/{sup 137}Cs{sub fallout}) at 66 sites. In addition, the {sup 137}Cs ratios between the male cones produced in 2012 ({sup 137}Cs{sub male} {sub cone}) and needle leaves that had elongated in the spring of 2011 ({sup 137}Cs{sub 2011N}) was determined at 82 sites ({sup 137}Cs{sub male} {sub cone}/{sup 137} Cs{sub 2011N}). Most of the sites with lower {sup 137}Cs{sub pre-accident} {sub N}/{sup 137}Cs{sub fallout} ratios were distributed in eastern Fukushima, relatively close to the Pacific Ocean coastline. Lower {sup 137}Cs{sub pre-accidentN}/{sup 137}Cs{sub fallout} and higher {sup 137}Cs{sub malecone}/{sup 137}Cs{sub 2011N} were found to be associated with higher proportions of {sup 137}Cs in ionic forms. These observations are consistent with the hypothesis, and likely reflect regional variations in the chemical form of the deposited radiocesium. - Highlights: • Study of spatial variation of ionic and stable {sup 137}Cs in the initial

  5. Investigation of effect of Ag(1), Cd(2) and Zn(2) on chemical nickel plating

    International Nuclear Information System (INIS)

    Lunyatskas, A.M.; Tarozajte, R.K.; Gyanutene, I.K.; Lyaukonis, Yu.Yu.

    1978-01-01

    Investigated is the effect of Ag(1), Cd(2) and Zn(2) on chemical nickel plating using hypophosphite aimed to get corresponding alloys from alkali solutions. The H 2 formed volume and potential of coating have been measured while nickel plating. It is possible to have plating of Ni-P-Ag, Ni-P-Zn, Ni-P-Cd, Ni-P-Zn-Cd content coatings in alkali solutions using hypophosphite Ni-P-Zh and Ni-P-Zn-Cd coatings have corrosion resistance and unporousness. Cd and Zn inclusion in Ni-P coating is supposed to have both chemical and electrochemical origin

  6. Investigation of relation between operator's mental workload and information flow in accident diagnosis tasks of nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Chang Hoon; Kim, Jong Hyun; Seong, Poong Hyun [KAIST, Taejon (Korea, Republic of)

    2004-07-01

    In the main control room (MCR) of a nuclear power plant (NPP), there are lots of dynamic information sources for MCR operator's situation awareness. As the human-machine interface in MCR is advanced, operator's information acquisition, information gathering and decision-making is becoming an important part to maintain the effective and safe operation of NPPs. Diagnostic task in complex and huge systems like NPP is the most difficult and mental effort-demanding for operators. This research investigates the relation between operator's mental workload and information flow in accident diagnosis tasks. The amount of information flow is quantified, using information flow model and Conant's model, a kind of information theory. For the mental workload measure, eye blink rate, blink duration, fixation time, number of fixation, and gaze direction are measured during accident diagnosis tasks. Subjective methods such as NASA-Task Load Index (NASA-TLX) and Modified Cooper-Harper (MCH) method are also used in the experiment. It is shown that the operator's mental workload has significant relation to information flow of diagnosis task. It makes possible to predict the mental workload through the quantity of the information flow of a system.

  7. Accident Statistics

    Data.gov (United States)

    Department of Homeland Security — Accident statistics available on the Coast Guard’s website by state, year, and one variable to obtain tables and/or graphs. Data from reports has been loaded for...

  8. Radiation accidents

    International Nuclear Information System (INIS)

    Nenot, J.C.

    1996-01-01

    Analysis of radiation accidents over a 50 year period shows that simple cases, where the initiating events were immediately recognised, the source identified and under control, the medical input confined to current handling, were exceptional. In many cases, the accidents were only diagnosed when some injuries presented by the victims suggested the radiological nature of the cause. After large-scale accidents, the situation becomes more complicated, either because of management or medical problems, or both. The review of selected accidents which resulted in severe consequences shows that most of them could have been avoided; lack of regulations, contempt for rules, human failure and insufficient training have been identified as frequent initiating parameters. In addition, the situation was worsened because of unpreparedness, insufficient planning, unadapted resources, and underestimation of psychosociological aspects. (author)

  9. Sports Accidents

    CERN Multimedia

    Kiebel

    1972-01-01

    Le Docteur Kiebel, chirurgien à Genève, est aussi un grand ami de sport et de temps en temps médecin des classes genevoises de ski et également médecin de l'équipe de hockey sur glace de Genève Servette. Il est bien qualifié pour nous parler d'accidents de sport et surtout d'accidents de ski.

  10. Radiation accidents

    International Nuclear Information System (INIS)

    Poplavskij, K.K.; Smorodintseva, G.I.

    1978-01-01

    On the basis of a critical analysis of the available data on causes and consequences of radiation accidents (RA), a classification of RA by severity (five groups of accidents) according to biomedical consequences and categories of exposed personnel is proposed. A RA is defined and its main characteristics are described. Methods of RA prevention are proposed, as is a plan of specific measures to deal with RA in accordance with the proposed classification

  11. Cytogenetic investigation of individuals living in areas of the Ukraine contaminated by fault from the Chernobyl reactor accident

    Energy Technology Data Exchange (ETDEWEB)

    Bondar, A Yu; Zamostian, V P [Research Center for Radiation Medicine, Kiev, (Ukraine)

    1997-12-31

    A number of areas in Ukraine were severely contaminated by fallout from Chernobyl Nuclear Power Plant accident. The purpose of the study was to determine whether the exposures received by individuals in these areas were sufficiently high to produce measurable increase in chromosomal aberrations. The individuals studied were selected from the Koselets, Chernigov, Narodichi, and Ovruch regions specifically the districts of Chernigov and the districts of Jitomir. Indication of radiation exposure was based on an increase of total frequency of aberrant cells and frequency of aberration of chromosomal type. All cytogenetic abnormalities in metaphases were examined. The highest cytogenetic effects was observed in individuals from Ovruch and Narodichi regions, for which the mean levels of chromosome aberration were 1.88 and 1.29 per 100 cells, respectively. Among individuals living in Narodichi region, the observed frequency of dicentric and centric rings was 0.04 and for double minutes was 0.87 per 100 cells. among all exposed groups, the frequency of chromatid type was approximately the same. The results of the study of subjects with effective dose equivalent below 10 c Sv show that the mean frequency of (chromosomal type aberrations i.e dicentric, centric, and acentric rings) among individuals living in different contaminated regions of Ukraine was significantly higher that the mean population indices. Moreover, individuals exposed to long-lived radionuclides such as Cs{sup 137} and Sr{sup 90} were observed as having higher chromosome aberration frequency when compared with individuals exposed to short-lived iodine radionuclides. Continued observation on high-risk individuals who live in the contaminated areas is recommended. Similarly, there is a need for objective criteria to define when further monitoring of the genetic effects among the exposed adults and children in the Ukraine is appropriate. (Abstract Truncated)

  12. Active hydrothermal and non-active massive sulfide mound investigation using a new multiparameter chemical sensor

    Science.gov (United States)

    Han, C.; Wu, G.; Qin, H.; Wang, Z.

    2012-12-01

    Investigation of active hydrothermal mound as well as non-active massive sulfide mound are studied recently. However, there is still lack of in-situ detection method for the non-active massive sulfide mound. Even though Transient ElectroMagnetic (TEM) and Electric Self-potential (SP) methods are good, they both are labour, time and money cost work. We proposed a new multiparameter chemical sensor method to study the seafloor active hydrothermal mound as well as non-active massive sulfide mound. This sensor integrates Eh, S2- ions concentration and pH electrochemical electrodes together, and could found chemical change caused by the active hydrothermal vent, even weak chemical abnormalities by non-active massive sulfide hydrothermal mound which MARP and CTD sometimes cannot detect. In 2012, the 1st Leg of the Chinese 26th cruise, the multiparameter chemical sensor was carried out with the deepsea camera system over the Carlsberg Ridge in Indian Ocean by R/V DAYANGYIHAO. It was shown small Eh and S2- ions concentration abnormal around a site at Northwest Indian ridge. This site was also evidenced by the TV grab. In the 2nd Leg of the same cruise in June, this chemical sensor was carried out with TEM and SP survey system. The chemical abnormalities are matched very well with both TEM and SP survey results. The results show that the multiparameter chemical sensor method not only can detect active hydrothermal mound, but also can find the non-active massive sulfide hydrothermal mound.

  13. Subsurface injection of dissolved ferric chloride to form a chemical barrier: Laboratory investigations

    International Nuclear Information System (INIS)

    Morrison, S.J.; Spangler, R.R.; Morris, S.A.

    1996-01-01

    A chemical barrier is a permeable zone of reactive materials emplaced in the subsurface to remove ground-water contaminants while allowing clean ground water to pass through. Because dissolved ferric chloride hydrolyzes to amorphous ferric oxyhydroxide when it contacts calcite (CaCO 3 ), it may be viable to emplace a zone of amorphous ferric oxyhydroxide (an absorbent for U, Mo, and other inorganic contaminants) into calcite-bearing geologic units by injecting ferric chloride through wells. For a chemical barrier to be successful, it must remain permeable and must be immobile. This investigation monitored chemical compositions, hydraulic conductivity, and iron mobility in laboratory columns and in a two-dimensional tank to determine the viability of injecting ferric chloride to form an amorphous ferric oxyhydroxide chemical barrier. The authors introduced a ferric chloride solution (1,345 mg/1[0.024 m] Fe) to calcite-bearing alluvial gravel to form a chemical barrier of amorphous ferric oxyhydroxide, followed by solutions contaminated with U and Mo. The simulated chemical barriers decreased U and Mo concentrations to less than 0.05 mg/l (2.1 x 10 -7 m) and 0.01 (1.0 x 10 -7 m), respectively; however, the breakthrough front is spread out with concentrations increasing to more than regulatory guideline values sooner than predicted. The hydraulic conductivity of calcite-bearing alluvial gravel decreased substantially during ferric chloride introduction because of the formation of carbon dioxide but increased to within factors of 1 to 5 of the original value as synthetic ground water flowed through the system. Amorphous ferric oxyhydroxide that formed in these experiments remained immobile at flow rates exceeding those typical of ground water. These laboratory results, in conjunction with site-specific characterization data, can be used to design chemical barriers emplaced by injection of ferric chloride

  14. 40 CFR 68.42 - Five-year accident history.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Five-year accident history. 68.42... (CONTINUED) CHEMICAL ACCIDENT PREVENTION PROVISIONS Hazard Assessment § 68.42 Five-year accident history. (a) The owner or operator shall include in the five-year accident history all accidental releases from...

  15. Investigating positive leadership, psychological empowerment, work engagement and satisfaction with life in a chemical industry

    Directory of Open Access Journals (Sweden)

    Tersia Nel

    2015-11-01

    Research purpose: The objective of this study was to investigate whether perceived positive leadership behaviour could predict psychological empowerment, work engagement, and satisfaction with life of employees in a chemical organisation in South Africa and whether positive leadership behaviour has an indirect effect on employees work engagement and satisfaction with life by means of psychological empowerment. Motivation for the study: The motivation for this study arose from the evident gap in academic literature as well as in terms of practical implications for the chemical industry regarding positive leadership behaviour, psychological empowerment, work engagement and satisfaction with life of employees. Research design, approach and method: A cross-sectional survey design was used with a convenience sample (n = 322. Structural equation modelling (SEM was used to examine the structural relationships between the constructs. Main findings: Statistically significant relationships were found between positive leadership behaviour, psychological empowerment, work engagement and satisfaction with life of employees. Positive leadership has an indirect effect on work engagement and satisfaction with life via psychological empowerment. Practical/managerial implications: This study adds to the lack of literature in terms of positive leadership, psychological empowerment, work engagement and satisfaction with life within a chemical industry. It can also assist managers and personnel within the chemical industry to understand and perhaps further investigate relationships that exist between the above mentioned concepts. Contribution/value-add: It is recommended that leadership discussions, short training programs and individual coaching about positive leadership and particularly psychological empowerment take place.

  16. [Injury pattern and identification after airplane catastrophies. Cooperation between forensic medicine and federal criminal investigations. An airplane accident in Mühlheim/Ruhr 8 February 1988].

    Science.gov (United States)

    Weiler, G; Risse, M

    1989-01-01

    On February 8th 1988, a two-motor passenger aircraft of Metroliner type with 21 people on board entered a front of heavy weather at an altitude of 900 m and crashed after being struck by lightning which led to complete breakdown of the electrical systems on board. The site of the crash was in the marshy Ruhr meadows. The formation of the terrain enabled a subdivision into plan squares for rescue. The identification of the 21 bodies was carried out in the Essen Institute of Forensic Medicine in collaboration with the identification commission of the Federal Criminal Investigation Office. The experience and recommendations for future (possibly larger-scale) disasters derived from this are described. Furthermore, the accident pattern in the casualties typical for this air crash is discussed.

  17. Chemical Investigations of Volatile Oil of Salvia yosgadensis Freyn et Bornm

    OpenAIRE

    ŞARER, Engin

    1988-01-01

    There are 44 endemic species of the Salvia genera growing in Anatolia. In this research, the physical properties and the chemical composition of the volatile oil of S. yosgadensis Freyn. et Bornm. as an endemic species have been investigated. The flowers and leaves of the plant contain 0.30 per cent volatile oil. In this oil 14 monoterpene hydrocarbons and 15 oxygen-containing compounds and sesquiter

  18. Investigation of conditions inside the reactor building annulus of a PWR plant of KONVOI type in case of severe accidents with increased containment leakages

    Energy Technology Data Exchange (ETDEWEB)

    Bakalov, Ivan [Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) gGmbH, Berlin (Germany); Sonnenkalb, Martin [Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) gGmbH, Koeln (Germany)

    2018-02-15

    Improvements of the implemented severe accident management (SAM) concepts have been done in all operating German NPPs after the Fukushima Daiichi accidents following recommendations of the German Reactor Safety Commission (RSK) and as a result of the stress test being performed. The efficiency of newly developed severe accident management guidelines (SAMG) for a PWR KONVOI reference plant related to the mitigation of challenging conditions inside the reactor building (RB) annulus due to increased containment leakages during severe accidents have been assessed. Based on two representative severe accident scenarios the releases of both hydrogen and radionuclides into the RB annulus have been predicted with different boundary conditions. The accident scenarios have been analysed without and with the impact of several SAM measures (already planned or proposed in addition), which turned out to be efficient to mitigate the consequences. The work was done within the frame of a research project financially supported by the Federal Ministry BMUB.

  19. Investigation of conditions inside the reactor building annulus of a PWR plant of KONVOI type in case of severe accidents with increased containment leakages

    International Nuclear Information System (INIS)

    Bakalov, Ivan; Sonnenkalb, Martin

    2018-01-01

    Improvements of the implemented severe accident management (SAM) concepts have been done in all operating German NPPs after the Fukushima Daiichi accidents following recommendations of the German Reactor Safety Commission (RSK) and as a result of the stress test being performed. The efficiency of newly developed severe accident management guidelines (SAMG) for a PWR KONVOI reference plant related to the mitigation of challenging conditions inside the reactor building (RB) annulus due to increased containment leakages during severe accidents have been assessed. Based on two representative severe accident scenarios the releases of both hydrogen and radionuclides into the RB annulus have been predicted with different boundary conditions. The accident scenarios have been analysed without and with the impact of several SAM measures (already planned or proposed in addition), which turned out to be efficient to mitigate the consequences. The work was done within the frame of a research project financially supported by the Federal Ministry BMUB.

  20. Occupational accidents aboard merchant ships

    DEFF Research Database (Denmark)

    Hansen, H.L.; Nielsen, D.; Frydenberg, Morten

    2002-01-01

    Objectives: To investigate the frequency, circumstances, and causes of occupational accidents aboard merchant ships in international trade, and to identify risk factors for the occurrence of occupational accidents as well as dangerous working situations where possible preventive measures may...... be initiated. Methods: The study is a historical follow up on occupational accidents among crew aboard Danish merchant ships in the period 1993–7. Data were extracted from the Danish Maritime Authority and insurance data. Exact data on time at risk were available. Results: A total of 1993 accidents were...... aboard. Relative risks for notified accidents and accidents causing permanent disability of 5% or more were calculated in a multivariate analysis including ship type, occupation, age, time on board, change of ship since last employment period, and nationality. Foreigners had a considerably lower recorded...

  1. A dispersion model of transport media in radiotracer investigations on selected chemical installations

    International Nuclear Information System (INIS)

    Iller, E.

    1999-01-01

    Tracer investigations of media transport through chemical reactors play a significant role in the chemical technology. They provide the basis for the determination of some important process parameters, such as flow character of the transported medium, degree of utilisation of the reactor volume during chemical transitions of substrates or even indicate possible mechanisms of chemical reactions. Determination of the medium flow characteristics is closely connected with the mathematical description of the process - a mathematical model of transport. The method of assessment of radiotracers suitability for the investigation of distillation processes presented in this paper allows to determine, in a simple manner, the parameters of distillation characteristics of the radionuclides, the average distillation temperature, the range of distillation temperatures, a suitable radiochemical purity. These parameters precisely determine the behavior of tracers to be expected in a wide range of variable conditions of the distillation process. Applications of tracer tested in such a manner to the investigations of dynamics of media in the industrial rectification columns has resulted in obtaining a dependable evaluation of the performance of these columns in a wide range of changes of their operational parameters. Particular attention has been paid to dynamics of the liquid [phase on the column plate. A dispersion model of liquid flow with hold-up zones has been proposed for the description of the liquid phase transport in the plate - overall assembly.The model consists of a number of flow and stagnant zones, with mass transfer between them. Another example of practical application of results from radiotracer investigation is an analysis of of phase dynamics in the installations designed for the process of liquefaction of Polish coals by means of their catalytic hydrogenation. For the analysis of phase transport in a reaction vessel various mathematical models were applied with

  2. Criticality accident:

    International Nuclear Information System (INIS)

    Canavese, Susana I.

    2000-01-01

    A criticality accident occurred at 10:35 on September 30, 1999. It occurred in a precipitation tank in a Conversion Test Building at the JCO Tokai Works site in Tokaimura (Tokai Village) in the Ibaraki Prefecture of Japan. STA provisionally rated this accident a 4 on the seven-level, logarithmic International Nuclear Event Scale (INES). The September 30, 1999 criticality accident at the JCO Tokai Works Site in Tokaimura, Japan in described in preliminary, technical detail. Information is based on preliminary presentations to technical groups by Japanese scientists and spokespersons, translations by technical and non-technical persons of technical web postings by various nuclear authorities, and English-language non-technical reports from various news media and nuclear-interest groups. (author)

  3. Database on aircraft accidents

    International Nuclear Information System (INIS)

    Nishio, Masahide; Koriyama, Tamio

    2013-11-01

    The Reactor Safety Subcommittee in the Nuclear Safety and Preservation Committee published 'The criteria on assessment of probability of aircraft crash into light water reactor facilities' as the standard method for evaluating probability of aircraft crash into nuclear reactor facilities in July 2002. In response to this issue, Japan Nuclear Energy Safety Organization has been collecting open information on aircraft accidents of commercial airplanes, self-defense force (SDF) airplanes and US force airplanes every year since 2003, sorting out them and developing the database of aircraft accidents for the latest 20 years to evaluate probability of aircraft crash into nuclear reactor facilities. In this report the database was revised by adding aircraft accidents in 2011 to the existing database and deleting aircraft accidents in 1991 from it, resulting in development of the revised 2012 database for the latest 20 years from 1992 to 2011. Furthermore, the flight information on commercial aircrafts was also collected to develop the flight database for the latest 20 years from 1992 to 2011 to evaluate probability of aircraft crash into reactor facilities. The method for developing the database of aircraft accidents to evaluate probability of aircraft crash into reactor facilities is based on the report 'The criteria on assessment of probability of aircraft crash into light water reactor facilities' described above. The 2012 revised database for the latest 20 years from 1992 to 2011 shows the followings. The trend of the 2012 database changes little as compared to the last year's report. (1) The data of commercial aircraft accidents is based on 'Aircraft accident investigation reports of Japan transport safety board' of Ministry of Land, Infrastructure, Transport and Tourism. The number of commercial aircraft accidents is 4 for large fixed-wing aircraft, 58 for small fixed-wing aircraft, 5 for large bladed aircraft and 99 for small bladed aircraft. The relevant accidents

  4. Criticality accident alarm system

    International Nuclear Information System (INIS)

    Malenfant, R.E.

    1991-01-01

    The American National Standard ANSI/ANS-8.3-1986, Criticality Accident Alarm System provides guidance for the establishment and maintenance of an alarm system to initiate personnel evacuation in the event of inadvertent criticality. In addition to identifying the physical features of the components of the system, the characteristics of accidents of concern are carefully delineated. Unfortunately, this ANSI Standard has led to considerable confusion in interpretation, and there is evidence that the ''minimum accident of concern'' may not be appropriate. Furthermore, although intended as a guide, the provisions of the standard are being rigorously applied, sometimes with interpretations that are not consistent. Although the standard is clear in the use of absorbed dose in free air of 20 rad, at least one installation has interpreted the requirement to apply to dose in soft tissue. The standard is also clear in specifying the response to both neutrons and gamma rays. An assembly of uranyl fluoride enriched to 5% 235 U was operated to simulate a potential accident. The dose, delivered in a free run excursion 2 m from the surface of the vessel, was greater than 500 rad, without ever exceeding a rate of 20 rad/min, which is the set point for activating an alarm that meets the standard. The presence of an alarm system would not have prevented any of the five major accidents in chemical operations nor is it absolutely certain that the alarms were solely responsible for reducing personnel exposures following the accident. Nevertheless, criticality alarm systems are now the subject of great effort and expense. 13 refs

  5. Use of PSA and severe accident assessment results for the accident management

    International Nuclear Information System (INIS)

    Jang, S. H.; Kim, H. G.; Jang, H. S.; Moon, S. K.; Park, J. U.

    1993-12-01

    The objectives for this study are to investigate the basic principle or methodology which is applicable to accident management, by using the results of PSA and severe accident research, and also facilitate the preparation of accidents management program in the future. This study was performed as follows: derivation of measures for core damage prevention, derivation of measures for accident mitigation, application of computerized tool to assess severe accident management

  6. Use of PSA and severe accident assessment results for the accident management

    Energy Technology Data Exchange (ETDEWEB)

    Jang, S H; Kim, H G; Jang, H S; Moon, S K; Park, J U [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    1993-12-15

    The objectives for this study are to investigate the basic principle or methodology which is applicable to accident management, by using the results of PSA and severe accident research, and also facilitate the preparation of accidents management program in the future. This study was performed as follows: derivation of measures for core damage prevention, derivation of measures for accident mitigation, application of computerized tool to assess severe accident management.

  7. Best practices in incident investigation in the chemical process industries with examples from the industry sector and specifically from Nova Chemicals

    International Nuclear Information System (INIS)

    Morrison, Lisa M.

    2004-01-01

    This paper will summarize best practices in incident investigation in the chemical process industries and will provide examples from both the industry sector and specifically from NOVA Chemicals. As a sponsor of the Center for Chemical Process Safety (CCPS), an industry technology alliance of the American Institute of Chemical Engineers, NOVA Chemicals participates in a number of working groups to help develop best practices and tools for the chemical process and associated industries in order to advance chemical process safety. A recent project was to develop an update on guidelines for investigating chemical process incidents. A successful incident investigation management system must ensure that all incidents and near misses are reported, that root causes are identified, that recommendations from incident investigations identify appropriate preventive measures, and that these recommendations are resolved in a timely manner. The key elements of an effective management system for incident investigation will be described. Accepted definitions of such terms as near miss, incident, and root cause will be reviewed. An explanation of the types of incident classification systems in use, along with expected levels of follow-up, will be provided. There are several incident investigation methodologies in use today by members of the CCPS; most of these methodologies incorporate the use of several tools. These tools include: timelines, sequence diagrams, causal factor identification, brainstorming, checklists, pre-defined trees, and team-defined logic trees. Developing appropriate recommendations and then ensuring their resolution is the key to prevention of similar events from recurring, along with the sharing of lessons learned from incidents. There are several sources of information on previous incidents and lessons learned available to companies. In addition, many companies in the chemical process industries use their own internal databases to track recommendations from

  8. Fluorescence spectroscopic investigation of the interaction of citrinin with native and chemically modified cyclodextrins

    Energy Technology Data Exchange (ETDEWEB)

    Poór, Miklós, E-mail: poor.miklos@pte.hu [Department of Pharmacology and Pharmacotherapy, Toxicology Section, University of Pécs, Szigeti út 12, Pécs H-7624 (Hungary); Matisz, Gergely; Kunsági-Máté, Sándor [Department of General and Physical Chemistry, University of Pécs, Ifjúság útja 6, Pécs H-7624 (Hungary); János Szentágothai Research Center, Ifjúság útja 20, Pécs H-7624 (Hungary); Derdák, Diána [Department of General and Physical Chemistry, University of Pécs, Ifjúság útja 6, Pécs H-7624 (Hungary); Szente, Lajos [CycloLab Cyclodextrin Research & Development Laboratory Ltd., Illatos út 7, Budapest H-1097 (Hungary); and others

    2016-04-15

    Citrinin (CIT) is a nephrotoxic mycotoxin produced by several Aspergillus, Penicillium and Monascus species. CIT is unavoidable contaminant of different foods and drinks due to its wide occurrence and high thermal stability. For this reason, development of new, more sensitive analytical methods and decontamination strategies has high importance. In our study, the complex formation of CIT with native and chemically modified cyclodextrins was investigated using fluorescence spectroscopy. Furthermore, thermodynamic and molecular modeling studies were also performed for the deeper understanding of these host-guest interactions. Our results show that among the tested compounds methylated β-cyclodextrins form the most stable complexes with CIT and these derivatives cause the highest fluorescence enhancement of CIT as well. These observations recommend that some of the chemically modified derivatives show more favourable properties than the native cyclodextrin, and suggesting more promising analytical applicability and higher affinity as potential toxin binders.

  9. Chemical and structural investigation of lipid nanoparticles: drug-lipid interaction and molecular distribution

    Energy Technology Data Exchange (ETDEWEB)

    Anantachaisilp, Suranan; Smith, Siwaporn Meejoo [Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400 (Thailand); Treetong, Alongkot; Ruktanonchai, Uracha Rungsardthong [National Nanotechnology Center, National Science and Technology Development Agency, 111 Thailand Science Park, Paholyothin Road, Klong 1, Klong Luang, Pathumthani 12120 (Thailand); Pratontep, Sirapat [College of KMITL Nanotechnology, King Mongkut' s Institute of Technology Ladkrabang, Bangkok (Thailand); Puttipipatkhachorn, Satit, E-mail: uracha@nanotec.or.th [Department of Manufacturing Pharmacy, Faculty of Pharmacy, Mahidol University, Bangkok 10400 (Thailand)

    2010-03-26

    Lipid nanoparticles are a promising alternative to existing carriers in chemical or drug delivery systems. A key challenge is to determine how chemicals are incorporated and distributed inside nanoparticles, which assists in controlling chemical retention and release characteristics. This study reports the chemical and structural investigation of {gamma}-oryzanol loading inside a model lipid nanoparticle drug delivery system composed of cetyl palmitate as solid lipid and Miglyol 812 as liquid lipid. The lipid nanoparticles were prepared by high pressure homogenization at varying liquid lipid content, in comparison with the {gamma}-oryzanol free systems. The size of the lipid nanoparticles, as measured by the photon correlation spectroscopy, was found to decrease with increased liquid lipid content from 200 to 160 nm. High-resolution proton nuclear magnetic resonance ({sup 1}H-NMR) measurements of the medium chain triglyceride of the liquid lipid has confirmed successful incorporation of the liquid lipid in the lipid nanoparticles. Differential scanning calorimetric and powder x-ray diffraction measurements provide complementary results to the {sup 1}H-NMR, whereby the crystallinity of the lipid nanoparticles diminishes with an increase in the liquid lipid content. For the distribution of {gamma}-oryzanol inside the lipid nanoparticles, the {sup 1}H-NMR revealed that the chemical shifts of the liquid lipid in {gamma}-oryzanol loaded systems were found at rather higher field than those in {gamma}-oryzanol free systems, suggesting incorporation of {gamma}-oryzanol in the liquid lipid. In addition, the phase-separated structure was observed by atomic force microscopy for lipid nanoparticles with 0% liquid lipid, but not for lipid nanoparticles with 5 and 10% liquid lipid. Raman spectroscopic and mapping measurements further revealed preferential incorporation of {gamma}-oryzanol in the liquid part rather than the solid part of in the lipid nanoparticles. Simple models

  10. Chemical and structural investigation of lipid nanoparticles: drug-lipid interaction and molecular distribution

    Science.gov (United States)

    Anantachaisilp, Suranan; Meejoo Smith, Siwaporn; Treetong, Alongkot; Pratontep, Sirapat; Puttipipatkhachorn, Satit; Rungsardthong Ruktanonchai, Uracha

    2010-03-01

    Lipid nanoparticles are a promising alternative to existing carriers in chemical or drug delivery systems. A key challenge is to determine how chemicals are incorporated and distributed inside nanoparticles, which assists in controlling chemical retention and release characteristics. This study reports the chemical and structural investigation of γ-oryzanol loading inside a model lipid nanoparticle drug delivery system composed of cetyl palmitate as solid lipid and Miglyol 812® as liquid lipid. The lipid nanoparticles were prepared by high pressure homogenization at varying liquid lipid content, in comparison with the γ-oryzanol free systems. The size of the lipid nanoparticles, as measured by the photon correlation spectroscopy, was found to decrease with increased liquid lipid content from 200 to 160 nm. High-resolution proton nuclear magnetic resonance (1H-NMR) measurements of the medium chain triglyceride of the liquid lipid has confirmed successful incorporation of the liquid lipid in the lipid nanoparticles. Differential scanning calorimetric and powder x-ray diffraction measurements provide complementary results to the 1H-NMR, whereby the crystallinity of the lipid nanoparticles diminishes with an increase in the liquid lipid content. For the distribution of γ-oryzanol inside the lipid nanoparticles, the 1H-NMR revealed that the chemical shifts of the liquid lipid in γ-oryzanol loaded systems were found at rather higher field than those in γ-oryzanol free systems, suggesting incorporation of γ-oryzanol in the liquid lipid. In addition, the phase-separated structure was observed by atomic force microscopy for lipid nanoparticles with 0% liquid lipid, but not for lipid nanoparticles with 5 and 10% liquid lipid. Raman spectroscopic and mapping measurements further revealed preferential incorporation of γ-oryzanol in the liquid part rather than the solid part of in the lipid nanoparticles. Simple models representing the distribution of γ-oryzanol and

  11. Chemical and structural investigation of lipid nanoparticles: drug-lipid interaction and molecular distribution

    International Nuclear Information System (INIS)

    Anantachaisilp, Suranan; Smith, Siwaporn Meejoo; Treetong, Alongkot; Ruktanonchai, Uracha Rungsardthong; Pratontep, Sirapat; Puttipipatkhachorn, Satit

    2010-01-01

    Lipid nanoparticles are a promising alternative to existing carriers in chemical or drug delivery systems. A key challenge is to determine how chemicals are incorporated and distributed inside nanoparticles, which assists in controlling chemical retention and release characteristics. This study reports the chemical and structural investigation of γ-oryzanol loading inside a model lipid nanoparticle drug delivery system composed of cetyl palmitate as solid lipid and Miglyol 812 as liquid lipid. The lipid nanoparticles were prepared by high pressure homogenization at varying liquid lipid content, in comparison with the γ-oryzanol free systems. The size of the lipid nanoparticles, as measured by the photon correlation spectroscopy, was found to decrease with increased liquid lipid content from 200 to 160 nm. High-resolution proton nuclear magnetic resonance ( 1 H-NMR) measurements of the medium chain triglyceride of the liquid lipid has confirmed successful incorporation of the liquid lipid in the lipid nanoparticles. Differential scanning calorimetric and powder x-ray diffraction measurements provide complementary results to the 1 H-NMR, whereby the crystallinity of the lipid nanoparticles diminishes with an increase in the liquid lipid content. For the distribution of γ-oryzanol inside the lipid nanoparticles, the 1 H-NMR revealed that the chemical shifts of the liquid lipid in γ-oryzanol loaded systems were found at rather higher field than those in γ-oryzanol free systems, suggesting incorporation of γ-oryzanol in the liquid lipid. In addition, the phase-separated structure was observed by atomic force microscopy for lipid nanoparticles with 0% liquid lipid, but not for lipid nanoparticles with 5 and 10% liquid lipid. Raman spectroscopic and mapping measurements further revealed preferential incorporation of γ-oryzanol in the liquid part rather than the solid part of in the lipid nanoparticles. Simple models representing the distribution of γ-oryzanol and

  12. [Drugs and occupational accident].

    Science.gov (United States)

    Bratzke, H; Albers, C

    1996-02-01

    In a case of a fatal occupational accident (construction worker, fall from roof, urine test positive for cocaine and THC, e.g. cannabis) the question arised to what extent those drug-related occupational accidents occur. In the literature only few cases, mainly dealing with cannabis influence, have been reported, however, a higher number is suspected. Cocaine and other stimulating drugs (amphetamine) are more often used to increase physical fitness. By direct or indirect interference with vigilance these compounds may provoke accidents. Due to the lack of a legal basis proving of the influence of drugs at the working place is still very limited, although highly sensitive chemical-toxicological assay procedures are available to detect even the chronic abuse (in hair). In the general conditions of accident insurances a compensation is excluded when alcohol is involved, but drugs are not mentioned. It is indeed difficult to establish a concentration limit for drugs like that existing for alcohol (1.1%). In each case the assay of the drug involved and exact knowledge of its specific effects is in an essential prerequisite to prove the causal relationship.

  13. Experimental investigations of pressure and temperature loads on a containment after a loss-of-coolant accident

    International Nuclear Information System (INIS)

    Kanzleiter, T.

    1975-10-01

    The phenomena occuring within a containment during a LOCA are currently investigated through experiments with a modelcontainment at Battelle-Institut Frankfurt on behalf of the Bundesministerium fuer Forschung und Technologie, Bonn. The experimental results are to be compared with the results of model calculations in order to improve the calculational methods. An experimental facility was built, consisting of a primary coolant circuit and a special model-containment. The model-containment, built in conventional reinforced concrete, has a diameter of 12 m, a height of 12.5 m, a capacity of 580 m 3 and is designed for an internal pressure of 6 bar. The interior is divided by concrete walls and removable partitions into several compartments, which are interconnected through openings with adjustable cross section. By exchanging the removable partitions it is possible to modify the interior of the containment and to simulate different containment shapes. For the first experiment a PWR-configuration with nine compartments has been istalled. The model scale of the compartment volumes and the overflow areas are about 1:64 compared to the 1,200-MW-PWR-plant Biblis A. Later investigations will also include BWR-experiments and experiments leading to an extremely high load on special containment structures. (orig.) [de

  14. Geochemical investigation of groundwater in the Tono area, Japan. Chemical characteristics and groundwater evolution

    International Nuclear Information System (INIS)

    Iwatsuki, Teruki; Hama, Katsuhiro; Yoshida, Hidekazu

    1997-01-01

    Geochemical investigations form an important part of the R and D program at the Tono study site, central Japan. Detailed geological structure and groundwater chemistry have been studied to understand the geochemical environment in the sedimentary and crystalline rocks distributed in this area. The chemical evolution of the groundwater in the sedimentary rocks is characterized with the variation in Na + , Ca 2+ and HCO 3 - concentrations, and ion exchange and dissolution of calcite are dominant reactions in the evolution of groundwater. Geological investigation shows that a fracture system of crystalline rock can be classified into:intact zone, moderately fractured zone and intensely fractured zone, according to the frequency and the width of fractures and fractured zones. The groundwater in the intact and fractured zones of crystalline rock are characterized by Na + -Ca 2+ -HCO 3 - or Na + -HCO 3 - dominated water, and Na + -Ca 2+ -Fe 2+ -HCO 3 - dominated water. The chemical evolution of groundwater is, generally, controlled by water-rock interaction between plagioclase, iron minerals and groundwater. The groundwater at depth of G.L.-186m in the crystalline rock at the Tono area is characterized by the mixture between the oxidized surface water and the reduced groundwater. The investigation based on correlation between geological structures and groundwater chemistry can be applied to understand the geochemical environment in deep crystalline rock, and will support the development of a realistic hydrogeochemical model. (author)

  15. Investigation of the chemical effects of nuclear transformations by Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Nagy, G.A.

    1978-01-01

    Moessbauer spectroscopy proved to be a very successful method for the investigation of the effect of nuclear transformations in solid matrixes. This method makes possible the observation of the atoms to be investigated without the dissolution of the sample i.e. without interfering with the eventual intermediates or their environment, ensuring thus ''in situ'' analysis. The method besides the informations concerning the chemical state of the derivative gives data concerning its immediate environment and its site in the crystal lattice. Products having a very short lifetime can be observed, too. Though the method is suitable only for the investigation of such nucleogenetic nuclei which are at the same time also Moessbauer atoms, the method has several times given fundamental information on the chemical and crystal-structural effects of transformations in solid compounds. Isotopes from nuclear reactions are in general pushed back at a high kinetical energy during their formation, and the method makes possible to deduce the consequences of this push-back effect and of radioactive decays and nuclear reactions. A separate chapter summarizes the recent statements concerning the consequences of the electron capture in solid cobalt compounds, the consequences of the isomer transition of Sn-119 in solid tin compounds etc. (P.J.)

  16. Nuclear and Chemical Weapons and Materiel: Chemical Surety

    National Research Council Canada - National Science Library

    2001-01-01

    .... It has been revised to update responsibilities, Personnel Reliability Program (PRP) procedures, transportation policies, chemical event notification, chemical accident or incident response and assistance (CAIRA...

  17. WSSRAP chemical plant geotechnical investigations for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

    International Nuclear Information System (INIS)

    1990-12-01

    This document has been prepared for the United states Department of Energy (DOE) Weldon Spring Site Remedial Action Project (WSSRAP) by the Project Management Contractor (PMC), which consists of MK-Ferguson Company (MKF) and Morrison Knudsen Corporation Environmental Services Group (MKES) with Jacobs Engineering Group (JEG) as MKF's predesignated subcontractor. This report presents the results of site geotechnical investigations conducted by the PMC in the vicinity of the Weldon Spring chemical plant and raffinate pits (WSCP/RP) and in potential on-site and off-site clayey material borrow sources. The WSCP/RP is the proposed disposal cell (DC) site. 39 refs., 24 figs., 12 tabs

  18. An Investigation on the Formation of Carbon Nanotubes by Two-Stage Chemical Vapor Deposition

    Directory of Open Access Journals (Sweden)

    M. S. Shamsudin

    2012-01-01

    Full Text Available High density of carbon nanotubes (CNTs has been synthesized from agricultural hydrocarbon: camphor oil using a one-hour synthesis time and a titanium dioxide sol gel catalyst. The pyrolysis temperature is studied in the range of 700–900°C at increments of 50°C. The synthesis process is done using a custom-made two-stage catalytic chemical vapor deposition apparatus. The CNT characteristics are investigated by field emission scanning electron microscopy and micro-Raman spectroscopy. The experimental results showed that structural properties of CNT are highly dependent on pyrolysis temperature changes.

  19. Deepwater Horizon: Experience the Events That Led to This Accident, Follow the Investigation as They Uncover the Human Factors

    International Nuclear Information System (INIS)

    Bannerman, T.

    2016-01-01

    With the Key themes of leadership, culture, reputation and risk, process safety and the human and organizational factors inside partnership and joint ventures, this session run by AKT immerses you into the situation on board the Deepwater Horizon drilling rig in the Gulf of Mexico on the day of the disaster 20 April 2010. The sequence of events are acted out and then we follow the investigation as they uncover negligence, poor regulation, inadequate maintenance, and catastrophic decision making and what the US authorities called “a reckless disregard for safety”. This session will show how this type of workshop event has been used in different organizations, and the actors run the session to show how the facts of the disaster can be used to enhance knowledge of managers and senior leaders of factors that can trigger a major event. (author)

  20. Numerical investigation of the reactor pressure vessel behaviour under severe accident conditions taking into account the combined processes of the vessel creep and the molten pool natural convection

    International Nuclear Information System (INIS)

    Loktionov, V.D.; Mukhtarov, E.S.; Yaroshenko, N.I.; Orlov, V.E.

    1999-01-01

    Analysis of the WWER lower head behaviour and its failure has been performed for several molten pool structures and internal overpressure levels in a reactor pressure vessel (RPV). The different types of the molten pools (homogeneous, conventionally homogeneous, conventionally stratified, stratified) cover the bounding scenarios during a hypothetical severe accident. The parametric investigations of the failure mode and RPV behaviour for various molten pool types, its heights and internal overpressure levels are presented herein. A coupled treatment in this investigation includes: (i) a 2-D thermohydraulic analysis of a molten pool natural convection. Domestic NARAUFEM code has been used in this detailed analysis for prediction of the heat flux from the molten pool to the RPV inner surface; and (ii) a detailed 3-D transient thermal analysis of the RPV lower head. Domestic 3-D ASHTER-VVR finite element code has been used for the numerical simulations of the high temperature creep and failure of the lower head. The effect of an external RPV cooling, temperature-dependent physical properties of the molten pool and vessel steel, the hydrostatic forces and vessel dead-weight were taken into account in this study. The obtained results show that lower head failure occurs as a result of the vessel creep process which is significantly dependent on both an internal overpressure level and the type of molten pool structure. In particular, it was found that there were combinations of 'overpressure-molten pool structure' when the vessel failure started at the 'hot' layers of the vessel. (orig.)

  1. Investigation of radiation-chemical behaviour of divalent palladium in perchloric acid solutions

    International Nuclear Information System (INIS)

    Vladimirova, M.V.; Kalinina, S.V.

    1988-01-01

    Gamma-radiolysis of divalent palladium in perchloric acid solutions is studied. Absorption spectra of intermediate palladium compounds formed in the irradiated solution are taken. The analysis of literature data as well as comparative analysis of the absorption spectra obtained under irradiation of palladium (2) perchloric acid solutions with absorption spectra of palladium chlorocomplexes allows to suppose that the mentioned compounds are chlorocomplexes of palladium (2) of different composition depending on HClO 4 concentration in the initial solution and absorbed radiation dose. Radiation-chemical reduction of palladium (2) up to metal is stated to take place in the whole studied range of initial concentrations of components of the system and dose rates. Kinetic dependences of metallic palladium formation are obtained. Values of radiation-chemical yields of metallic palladium formation depending on the initial concentrations of palladium (2) and perchloric acid are given. A mechanism of radiolytic reduction of palladium (2) in the investigated system is suggested based on the experimental data, and a theoretical value of the radiation-chemical yield of palladium (2) reduction being in a good agreement with experimentally found values is calculated

  2. Chemical Composition and Biological Investigations of Eryngium triquetrum Essential Oil from Algeria.

    Science.gov (United States)

    Medbouhi, Ali; Merad, Nadjiya; Khadir, Abdelmounaim; Bendahou, Mourad; Djabou, Nassim; Costa, Jean; Muselli, Alain

    2018-01-01

    The chemical composition, antibacterial and antioxidant activities of the essential oil obtained from Eryngium triquetrum from Algeria were studied. The chemical composition of sample oils from 25 locations was investigated using GC-FID and GC/MS. Twenty-four components representing always more than 87% were identified in essential oils from total aerial parts of plants, stems, flowers and roots. Falcarinol is highly dominant in the essential oil from the roots (95.5%). The relative abundance of falcarinol in the aerial parts correlates with the phenological stages of the plant. Aerial parts of E. triquetrum produce an essential oil dominated by falcarinol during the early flowering stage, and then there is a decrease in falcarinol and rebalancing of octanal during the flowering stage. To our knowledge, the present study is the first report of the chemical composition of E. triquetrum essential oil. Evaluation of the antibacterial activity by means of the paper disc diffusion method and minimum inhibitory concentration assays, showed a moderate efficiency of E. triquetrum essential oil. Using the DPPH method, the interesting antioxidant activity of E. triquetrum essential oil was established. These activities could be attributed to the dominance of falcarinol. The outcome of our literature search on the occurrence of falcarinol in essential oils suggests that E. triquetrum from Algeria could be considered as a possible source of natural falcarinol. © 2018 Wiley-VHCA AG, Zurich, Switzerland.

  3. Synthesis and investigation of novel shelf-stable, brain-specific chemical delivery system

    International Nuclear Information System (INIS)

    Al-Obaid, Abdulrahman M.; Farag, Hassan A.; Khalil, Ashraf A.; Hamide, Sami G. Abdel; Ahmed, Hassan S.; Al-Affifi, Ahmed M.; Gadkariem Elrasheed, A.; El-Subbagh, Hussein I.; Al-Shabanah, Othman A.; El-Kashef, Hassan A.

    2006-01-01

    A 1, 4-dihydropyridine pyridinium salt type redox system is described as a general and flexible method for site-specific and sustained delivery of drugs into the brain. Monoamine oxidase inhibitors (MAOIs) were used as a model example to be delivered into the brain. Chemical and biological oxidations of these compounds were investigated. The prepared 1, 4-dihydropyridines were subjected to various chemical and biological oxidations to evaluate their ability to cross blood brain barrier (BBB), and to be oxidized biologically into their corresponding quaternary compounds. 1-(Ethioxy-carbonylmethyl)-3, 5-bis[N-(2-fluoro-benzylideneamino)carbamoyl]-1, 4-dyhydropyridine (31) proved to cross BBB in adequate rate and converted by the oxidizing enzymes into the corresponding quaternary salt N-(ethoxycarbolynmethyl)-3, 5-bis[N-(2-fluorobenylideneamino)carbamoyl]pyridimium bromide(20). Stability studies of the synthesized chemical delivery systems (CDSs) at various pH values and temperatures showed the shelf life time of a solution containing compound 31 is 20.53 days at 5C, which recommended a lower storage temperature for such solutions. The prepared CDSs proved to be fairly stable for powder form storage. The stability of the prepared compounds is attributed to the conjugation of the two carboxylic functions at C3 and C5 of the pyridine ring with their adjacent double bonds. These results are in consistency with the original rationale design. (author)

  4. Chemical segregation in hot cores with disk candidates. An investigation with ALMA

    Science.gov (United States)

    Allen, V.; van der Tak, F. F. S.; Sánchez-Monge, Á.; Cesaroni, R.; Beltrán, M. T.

    2017-07-01

    Context. In the study of high-mass star formation, hot cores are empirically defined stages where chemically rich emission is detected toward a massive YSO. It is unknown whether the physical origin of this emission is a disk, inner envelope, or outflow cavity wall and whether the hot core stage is common to all massive stars. Aims: We investigate the chemical makeup of several hot molecular cores to determine physical and chemical structure. We use high spectral and spatial resolution submillimeter observations to determine how this stage fits into the formation sequence of a high-mass star. Methods: The submillimeter interferometer ALMA (Atacama Large Millimeter Array) was used to observe the G35.20-0.74N and G35.03+0.35 hot cores at 350 GHz in Cycle 0. We analyzed spectra and maps from four continuum peaks (A, B1, B2 and B3) in G35.20-0.74N, separated by 1000-2000 AU, and one continuum peak in G35.03+0.35. We made all possible line identifications across 8 GHz of spectral windows of molecular emission lines down to a 3σ line flux of 0.5 K and determined column densities and temperatures for as many as 35 species assuming local thermodynamic equilibrium (LTE). Results: In comparing the spectra of the four continuum peaks, we find each has a distinct chemical composition expressed in over 400 different transitions. In G35.20, B1 and B2 contain oxygen- and sulfur-bearing organic and inorganic species but few nitrogen-bearing species whereas A and B3 are strong sources of O-, S-, and N-bearing organic and inorganic species (especially those with the CN bond). Column densities of vibrationally excited states are observed to be equal to or greater than the ground state for a number of species. Deuterated methyl cyanide is clearly detected in A and B3 with D/H ratios of 8 and 13%, respectively, but is much weaker at B1 and undetected at B2. No deuterated species are detected in G35.03, but similar molecular abundances to G35.20 were found in other species. We also

  5. Investigations of chemical reactions between U-Zr alloy and FBR cladding materials

    International Nuclear Information System (INIS)

    Ishii, Tetsuya; Ukai, Shigeharu

    2005-07-01

    U-Pu-Zr alloys are candidate materials for commercial FBR fuel. However, informations about chemical reactions with cladding materials developed by JNC for commercial FBR have not been well obtained. In this work, the reaction zones formed in four diffusion couples U-10wt.%Zr/PNC-FMS, U-10wt.%Zr/9Cr-ODS, U-10wt.%Zr/12Cr-ODS, and U-10wt.%Zr/Fe at about 1013K have been examined and following results were obtained. 1) At about 1013K, in the U-10wt.%Zr/Fe couple, the liquid phase zones were obtained. In the other couples U-10wt.%Zr/PNC-FMS, U-10wt.%Zr/9Cr-ODS and U-10wt.%Zr/12Cr-ODS, no liquid phase zones were obtained. The obtained chemical reaction zones in the later 3 couples were similar to the reported ones obtained in U-Zr/Fe couples without liquid phase formation. In comparison with the reaction zones obtained in the U-10wt.%Zr/Fe couple, the reaction zones inside cladding materials obtained in the PNC-FMS, 9Cr-ODS, and 12Cr-ODS couples were thin. 2) From the investigations of relationship between the obtained depths of the chemical reaction zones inside cladding materials and composition of the cladding materials, it was considered that the depth of chemical reaction zone would depend on the Cr content of the cladding materials and the depth would decrease with increasing Cr content, resulting in prevention of liquid phase formation. 3) From the investigations of the mechanisms of chemical reactions between U-Pu-Zr/cladding materials, it was considered that the same effect of Cr obtained in the U-Zr/cladding materials would be expected in U-Pu-Zr/cladding materials. Those seemed to indicate that the threshold temperatures of liquid phase formation for U-Pu-Zr/PNC-FMS, U-Pu-Zr/9Cr-ODS, and U-Pu-Zr/12Cr-ODS might be higher than that for U-Pu-Zr/Fe. (author)

  6. A Kine-chemical Investigation of the AB Dor Moving Group "Stream"

    Science.gov (United States)

    Barenfeld, Scott A.; Bubar, Eric J.; Mamajek, Eric E.; Young, Patrick A.

    2013-03-01

    The AB Dor Moving Group consists of a "nucleus" of ~10 stars at d ~= 20 pc, along with dozens of purported "stream" members distributed across the sky. We perform a chemical and kinematic analysis of a subsample of AB Dor stream stars to test whether they constitute a physical stellar group. We use the NEMO Galactic kinematic code to investigate the orbits of the stream members, and perform a chemical abundance analysis using high resolution spectra taken with the Magellan Clay 6.5 m telescope. Using a χ2 test with the measured abundances for 10 different elements, we find that only half of the purported AB Dor stream members could possibly constitute a statistically chemically homogeneous sample. Some stream members with three-dimensional velocities were hundreds of parsecs from the AB Dor nucleus ~108 yr ago, and hence were unlikely to share a common origin. We conclude that the published lists of AB Dor moving group stream members are unlikely to represent the dispersed remnant of a single star formation episode. A subsample of the stream stars appears to be both statistically chemically homogeneous and in the vicinity of the AB Dor nucleus at birth. Their mean metallicity is [Fe/H] = 0.02 ± 0.02 dex, which we consider representative for the AB Dor group. Finally, we report a strong lower limit on the age of the AB Dor nucleus of >110 Myr based on the pre-main sequence contraction times for K-type members which have reached the main sequence.

  7. Transient thermal hydraulic analysis of the IAEA 10 MW MTR reactor during Loss of Flow Accident to investigate the flow inversion

    International Nuclear Information System (INIS)

    AL-Yahia, Omar S.; Albati, Mohammad A.; Park, Jonghark; Chae, Heetaek; Jo, Daeseong

    2013-01-01

    Highlights: • Transient analyses of a slow and fast LOFA were investigated. • A reactor kinetic and thermal hydraulic coupled model was developed. • Based on force balance, the flow rate during flow inversion was determined. • Flow inversion in a hot channel occurred earlier than in an average channel. • Two temperature peaks were observed during both slow and fast LOFA. - Abstract: Transient analyses of the IAEA 10 MW MTR reactor are investigated during a fast and slow Loss of Flow Accident (LOFA) with a neutron kinetic and thermal hydraulic coupling model. A spatial-dependent thermal hydraulic technique is adopted for analyzing the local thermal hydraulic parameters and hotspot location during a flow inversion. The flow rate through the channel is determined in terms of a balance between driving and preventing forces. Friction and buoyancy forces act as resistance of the flow before a flow inversion while buoyancy force becomes the driving force after a flow inversion. By taking into account the buoyancy effect to determine the flow rate, the difference in the flow inversion time between hot and average channels is investigated: a flow inversion occurs earlier in the hot channel than in an average channel. Furthermore, the movement of the hotspot location before and after a flow inversion is investigated for a slow and fast LOFA. During a flow inversion, two temperature peaks are observed: (1) the first temperature peak is at the initiation of the LOFA, and (2) the second temperature peak is when a flow inversion occurs. The maximum temperature of the cladding is found at the second temperature peak for both LOFA analyses, and is lower than the saturation temperature

  8. Physico-chemical investigations of limestones from different localities in the Republic of Macedonia

    International Nuclear Information System (INIS)

    Arabadzhiev, Dimitrios M.; Stefov, Viktor; Boev, Blazho

    2001-01-01

    Physico-chemical investigations were carried out for limestone samples at different localities in the Republic of Macedonia: mine for nonmetals O graiden , Strumica (sample-granulation below: 4, 10, 20, 32, 40, 63 and 90 gm), A.D. M ikrogranulat , Gostivar, mine 'Banjani' - Skopje, mine 'Toplica' near Demir Hisar and from the separation of GP Mavrovo, Skopje, located near Pletvar. Investigation of samples from the previously mentioned localities were carried out using different methods: volumetry, gravimetry, UV-VIS and infrared spectroscopy, as well as atomic absorption and X-ray fluorescence spectrometry, X-ray diffraction and flame photometry. The obtained results lead to the conclusion that all granulometric classes of the limestone samples from 'Ograzhden', Strumica, are of the best quality. (Original)

  9. Molecular structure, vibrational analysis (IR and Raman) and quantum chemical investigations of 1-aminoisoquinoline

    Science.gov (United States)

    Sivaprakash, S.; Prakash, S.; Mohan, S.; Jose, Sujin P.

    2017-12-01

    Quantum chemical calculations of energy and geometrical parameters of 1-aminoisoquinoline [1-AIQ] were carried out by using DFT/B3LYP method using 6-311G (d,p), 6-311G++(d,p) and cc-pVTZ basis sets. The vibrational wavenumbers were computed for the energetically most stable, optimized geometry. The vibrational assignments were performed on the basis of potential energy distribution (PED) using VEDA program. The NBO analysis was done to investigate the intra molecular charge transfer of the molecule. The frontier molecular orbital (FMO) analysis was carried out and the chemical reactivity descriptors of the molecule were studied. The Mulliken charge analysis, molecular electrostatic potential (MEP), HOMO-LUMO energy gap and the related properties were also investigated at B3LYP level. The absorption spectrum of the molecule was studied from UV-Visible analysis by using time-dependent density functional theory (TD-DFT). Fourier Transform Infrared spectrum (FT-IR) and Raman spectrum of 1-AIQ compound were analyzed and recorded in the range 4000-400 cm-1 and 3500-100 cm-1 respectively. The experimentally determined wavenumbers were compared with those calculated theoretically and they complement each other.

  10. Spectroscopic studies and quantum chemical investigations of (3,4-dimethoxybenzylidene) propanedinitrile.

    Science.gov (United States)

    Gupta, Ujval; Kumar, Vinay; Singh, Vivek K; Kant, Rajni; Khajuria, Yugal

    2015-04-05

    The Fourier Transform Infrared (FTIR), Ultra-Violet Visible (UV-Vis) spectroscopy and Thermogravimetric (TG) analysis of (3,4-dimethoxybenzylidene) propanedinitrile have been carried out and investigated using quantum chemical calculations. The molecular geometry, harmonic vibrational frequencies, Mulliken charges, natural atomic charges and thermodynamic properties in the ground state have been investigated by using Hartree Fock Theory (HF) and Density Functional Theory (DFT) using B3LYP functional with 6-311G(d,p) basis set. Both HF and DFT methods yield good agreement with the experimental data. Vibrational modes are assigned with the help of Vibrational Energy Distribution Analysis (VEDA) program. UV-Visible spectrum was recorded in the spectral range of 190-800nm and the results are compared with the calculated values using TD-DFT approach. Stability of the molecule arising from hyperconjugative interactions, charge delocalization have been analyzed using natural bond orbital (NBO) analysis. The results obtained from the studies of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) are used to calculate molecular parameters like ionization potential, electron affinity, global hardness, electron chemical potential and global electrophilicity. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Tchernobyl accident

    International Nuclear Information System (INIS)

    1986-06-01

    First, R.M.B.K type reactors are described. Then, safety problems are dealt with reactor control, behavior during transients, normal loss of power and behavior of the reactor in case of leak. A possible scenario of the accident of Tchernobyl is proposed: events before the explosion, possible initiators, possible scenario and events subsequent to the core meltdown (corium-concrete interaction, interaction with the groundwater table). An estimation of the source term is proposed first from the installation characteristics and the supposed scenario of the accident, and from the measurements in Europe; radiological consequences are also estimated. Radioactivity measurements (Europe, Scandinavia, Western Europe, France) are given in tables (meteorological maps and fallouts in Europe). Finally, a description of the site is given [fr

  12. Accident: Reminder

    CERN Multimedia

    2003-01-01

    There is no left turn to Point 1 from the customs, direction CERN. A terrible accident happened last week on the Route de Meyrin just outside Entrance B because traffic regulations were not respected. You are reminded that when travelling from the customs, direction CERN, turning left to Point 1 is forbidden. Access to Point 1 from the customs is only via entering CERN, going down to the roundabout and coming back up to the traffic lights at Entrance B

  13. Chemical compatibility between UO{sub 2} fuel and SiC cladding for LWRs. Application to ATF (Accident-Tolerant Fuels)

    Energy Technology Data Exchange (ETDEWEB)

    Braun, James, E-mail: james.braun@cea.fr [DEN-Service de Recherches Métallurgiques Appliquées (SRMA), CEA, Université Paris-Saclay, F-91191, Gif-sur-Yvette (France); Guéneau, Christine; Alpettaz, Thierry [DEN-Service de la Corrosion et du Comportement des Matériaux dans leur Environnement (SCCME), CEA, Université Paris-Saclay, F-91191, Gif-sur-Yvette (France); Sauder, Cédric [DEN-Service de Recherches Métallurgiques Appliquées (SRMA), CEA, Université Paris-Saclay, F-91191, Gif-sur-Yvette (France); Brackx, Emmanuelle; Domenger, Renaud [CEA, DEN, Marcoule, Metallography and Chemical Analysis Laboratory, F-30207 Bagnols-sur-Cèze (France); Gossé, Stéphane [DEN-Service de la Corrosion et du Comportement des Matériaux dans leur Environnement (SCCME), CEA, Université Paris-Saclay, F-91191, Gif-sur-Yvette (France); Balbaud-Célérier, Fanny [DEN-Service d’Etudes Analytiques et de Réactivité des Surfaces (SEARS), CEA, Université Paris-Saclay, F-91191, Gif-sur-Yvette (France)

    2017-04-15

    Silicon carbide-silicon carbide (SiC/SiC) composites are considered to replace the current zirconium-based cladding materials thanks to their good behavior under irradiation and their resistance under oxidative environments at high temperature. In the present work, a thermodynamic analysis of the UO{sub 2±x}/SiC system is performed. Moreover, using two different experimental methods, the chemical compatibility of SiC towards uranium dioxide, with various oxygen contents (UO{sub 2±x}) is investigated in the 1500–1970 K temperature range. The reaction leads to the formation of mainly uranium silicides and carbides phases along with CO and SiO gas release. Knudsen Cell Mass Spectrometry is used to measure the gas release occurring during the reaction between UO{sub 2+x} and SiC powders as function of time and temperature. These experimental conditions are representative of an open system. Diffusion couple experiments with pellets are also performed to study the reaction kinetics in closed system conditions. In both cases, a limited chemical reaction is observed below 1700 K, whereas the reaction is enhanced at higher temperature due to the decomposition of SiC leading to Si vaporization. The temperature of formation of the liquid phase is found to lie between 1850 < T < 1950 K. - Highlights: •A limited chemical reaction occurs between SiC and UO{sub 2+x} up to 1514 K. •CO gas along with the generation of USi{sub x} are detected over 1514 K in open system. •A liquid phase forms between 1850 and 1950 K in the UO{sub 2+x}/SiC system. •Results are encouraging for the use of SiC/SiC cladding in nuclear reactors.

  14. LJUNGSKILE 1.0 A Computer Program for Investigation of Uncertainties in Chemical Speciation

    International Nuclear Information System (INIS)

    Ekberg, Christian; Oedegaard-Jensen, Arvid

    2002-11-01

    In analysing the long-term safety of nuclear waste disposal, there is a need to investigate uncertainties in chemical speciation calculations. Chemical speciation is of importance in evaluating the solubility of radionuclides, the chemical degradation of engineering materials, and chemical processes controlling groundwater composition. The uncertainties in chemical speciation may for instance be related to uncertainties in thermodynamic data, the groundwater composition, or the extrapolation to the actual temperature and ionic strength. The magnitude of such uncertainties and its implications are seldom explicitly evaluated in any detail. Commonly available chemical speciation programmes normally do not have a build-in option to include uncertainty ranges. The program developed within this project has the capability of incorporating uncertainty ranges in speciation calculations and can be used for graphical presentation of uncertainty ranges for dominant species. The program should be regarded as a starting point for assessing uncertainties in chemical speciation, since it is not yet comprehensive in its capabilities. There may be limitations in its usefulness to address various geochemical problems. The LJUNGSKILE code allows the user to select two approaches: the Monte Carlo (MC) approach and the Latin Hypercube Sampling (LHS). LHS allows to produce a satisfactory statistics with a minimum of CPU time. It is, in general, possible to do a simple theoretical speciation calculation within seconds. There are, admittedly, alternatives to LHS and there is criticism towards the uncritical use of LHS output because commonly correlation between some of the input variables exists. LHS, like MC, is not capable to take these correlations into account. Such a correlation can, i.e. exist between the pH of a solution and the partial pressure of CO 2 : higher pH solutions may absorb larger amounts of CO 2 and can reduce the CO 2 partial pressure. It is therefore of advantage to

  15. CHEMICALS

    CERN Multimedia

    Medical Service

    2002-01-01

    It is reminded that all persons who use chemicals must inform CERN's Chemistry Service (TIS-GS-GC) and the CERN Medical Service (TIS-ME). Information concerning their toxicity or other hazards as well as the necessary individual and collective protection measures will be provided by these two services. Users must be in possession of a material safety data sheet (MSDS) for each chemical used. These can be obtained by one of several means : the manufacturer of the chemical (legally obliged to supply an MSDS for each chemical delivered) ; CERN's Chemistry Service of the General Safety Group of TIS ; for chemicals and gases available in the CERN Stores the MSDS has been made available via EDH either in pdf format or else via a link to the supplier's web site. Training courses in chemical safety are available for registration via HR-TD. CERN Medical Service : TIS-ME :73186 or service.medical@cern.ch Chemistry Service : TIS-GS-GC : 78546

  16. Improving performance with accident tolerant-fuels

    International Nuclear Information System (INIS)

    Gomes, Daniel S.; Muniz, Rafael O.R.; Giovedi, Claudia; Universidade de São Paulo

    2017-01-01

    After the Fukushima reactor accident, efforts to improve risk management in nuclear operations have included the intensification of research on accident-tolerant fuels (ATFs). In this investigation, the physical properties of recently developed ATFs were compared with those of the current standard fuel, UO 2 - Zr. The goals for innovative fuel design include a rigorous characterization of the thermal, mechanical, and chemical considerations. The intentions are to lengthen the burnup cycle, raise the power density, and improve safety. Fuels must have a high uranium density - above that supported by UO 2 - and possess a coating that exhibits better oxidation resistance than Zircaloys. ATFs such as U 3 Si 2 , UN, and UC contain a higher uranium density and thermal conductivity than UO 2 , providing significant benefits. The ideal combination of fuel and cladding must increase performance in a loss-of-coolant accident. However, U 3 Si 2 , UN, and UC have a disadvantage; their respective swelling rates are higher than that of UO 2 . These ATFs also have thermal conductivities approximately four times higher than that of UO 2 . A study was conducted investigating the hydrogen generated by the oxidation of zirconium alloys in contact with steam using cladding options such as Fe-Cr-Al and silicon carbide. It was confirmed that ferritic alloys offer a better response under severe conditions, because of their mechanical properties as creep rate. The findings of this study indicate that advanced fuels should replace UO 2 - Zr as the fuel system of choice. (author)

  17. Spin-locking vs. chemical exchange saturation transfer MRI for investigating chemical exchange process between water and labile metabolite protons

    Science.gov (United States)

    Jin, Tao; Autio, Joonas; Obata, Takayuki; Kim, Seong-Gi

    2010-01-01

    Chemical exchange saturation transfer (CEST) and spin-locking (SL) experiments were both able to probe the exchange process between protons of non-equivalent chemical environments. To compare the characteristics of the CEST and SL approaches in the study of chemical exchange effects, we performed CEST and SL experiments at varied pH and concentrated metabolites with exchangeable amide, amine, and hydroxyl protons at 9.4 T. Our results show that: i) On-resonance SL is most sensitive to chemical exchanges in the intermediate exchange regime and is able to detect hydroxyl and amine protons on a millimolar concentration scale. Off-resonance SL and CEST approaches are sensitive to slow-exchanging protons when an optimal SL or saturation pulse power matches the exchanging rate, respectively. ii) Offset frequency-dependent SL and CEST spectra are very similar, and can be explained well with an SL model recently developed by Trott and Palmer. iii) The exchange rate and population of metabolite protons can be determined from offset-dependent SL or CEST spectra or from on-resonance SL relaxation dispersion measurements. iv) The asymmetry of the magnetization transfer ratio (MTRasym) is highly dependent on the choice of saturation pulse power. In the intermediate exchange regime, MTRasym becomes complicated and should be interpreted with care. PMID:21500270

  18. Spin-locking versus chemical exchange saturation transfer MRI for investigating chemical exchange process between water and labile metabolite protons.

    Science.gov (United States)

    Jin, Tao; Autio, Joonas; Obata, Takayuki; Kim, Seong-Gi

    2011-05-01

    Chemical exchange saturation transfer (CEST) and spin-locking (SL) experiments were both able to probe the exchange process between protons of nonequivalent chemical environments. To compare the characteristics of the CEST and SL approaches in the study of chemical exchange effects, we performed CEST and SL experiments at varied pH and concentrated metabolite phantoms with exchangeable amide, amine, and hydroxyl protons at 9.4 T. Our results show that: (i) on-resonance SL is most sensitive to chemical exchanges in the intermediate-exchange regime and is able to detect hydroxyl and amine protons on a millimolar concentration scale. Off-resonance SL and CEST approaches are sensitive to slow-exchanging protons when an optimal SL or saturation pulse power matches the exchanging rate, respectively. (ii) Offset frequency-dependent SL and CEST spectra are very similar and can be explained well with an SL model recently developed by Trott and Palmer (J Magn Reson 2002;154:157-160). (iii) The exchange rate and population of metabolite protons can be determined from offset-dependent SL or CEST spectra or from on-resonance SL relaxation dispersion measurements. (iv) The asymmetry of the magnetization transfer ratio (MTR(asym)) is highly dependent on the choice of saturation pulse power. In the intermediate-exchange regime, MTR(asym) becomes complicated and should be interpreted with care. Copyright © 2010 Wiley-Liss, Inc.

  19. Young Investigator Proposal, Research Area 7.4 Reactive Chemical Systems: Multifunctional, Bimetallic Nanomaterials Prepared by Atomic Layer Electroless Deposition

    Science.gov (United States)

    2017-09-30

    Report: Young Investigator Proposal, Research Area 7.4 Reactive Chemical Systems: Multifunctional, Bimetallic Nanomaterials Prepared by Atomic Layer ...Chemical Systems: Multifunctional, Bimetallic Nanomaterials Prepared by Atomic Layer Electroless Deposition Report Term: 0-Other Email: pcappillino... Layer Electroless Deposition (ALED, Figure 1) is the ability to tune growth mechanism, hence growth morphology, by altering conditions. In this

  20. Investigation of correlations in some chemical impurities and isotope ratios for nuclear forensic purposes

    International Nuclear Information System (INIS)

    Wallenius, M.; Mayer, K.; Nicholl, A.; Horta, J.

    2002-01-01

    Full text: Institute for Transuranium Elements (ITU) has worked in the area of nuclear forensic science since 1992 when the first seized sample was analysed. From the beginning the analytical tools for seized materials were adapted from safeguards measurements and from materials science. Especially in the view of the origin determination the spectrum of parameters to be taken into account had to be widened. In addition to the development of a comprehensive database on nuclear materials for power reactor fuels, experimental investigations were started to identify characteristic parameters. These systematic investigations comprised the development of methodologies for age determination of Pu and highly enriched uranium, surface roughness determination of UO 2 pellets and n( 18 O)/n( 16 O) measurements in uranium oxides. However, a more profound understanding on the nature of the characteristic chemical impurities and their propagation throughout the entire process appeared necessary in particular for uranium materials. Therefore a systematic research programme was launched in order to better understand which chemical impurities might be considered as characteristic for the origin of the base material. On the other hand some impurities are introduced intentionally during the processing of the material. These impurities might be characteristic for the process used or for the plant where the material was processed. We carried out impurity measurements on uranium ores, on intermediate products (Ammoniumdiuranate or yellow cake) and on (natural) uranium oxides, hence 'vertically' throughout the process in individual facilities. n( 18 O)/n( 16 O) ratio measurements have been proven to provide useful additional information on the geographic origin of the materials. We therefore investigated the n( 18 O)/n( 16 O) isotope ratios in these different compounds, in order to obtain further experimental evidence for a consistent set of materials reportedly originating from the same

  1. How to reduce the number of accidents

    CERN Multimedia

    2012-01-01

    Among the safety objectives that the Director-General has established for CERN in 2012 is a reduction in the number of workplace accidents.   The best way to prevent workplace accidents is to learn from experience. This is why any accident, fire, instance of pollution, or even a near-miss, should be reported using the EDH form that can be found here. All accident reports are followed up. The departments investigate all accidents that result in sick leave, as well as all the more common categories of accidents at CERN, essentially falls (slipping, falling on stairs, etc.), regardless of whether or not they lead to sick leave. By studying the accident causes that come to light in this way, it is possible to take preventive action to avoid such accidents in the future. If you have any questions, the HSE Unit will be happy to answer them. Contact us at safety-general@cern.ch. HSE Unit

  2. Containment severe accident thermohydraulic phenomena

    International Nuclear Information System (INIS)

    Frid, W.

    1991-08-01

    This report describes and discusses the containment accident progression and the important severe accident containment thermohydraulic phenomena. The overall objective of the report is to provide a rather detailed presentation of the present status of phenomenological knowledge, including an account of relevant experimental investigations and to discuss, to some extent, the modelling approach used in the MAAP 3.0 computer code. The MAAP code has been used in Sweden as the main tool in the analysis of severe accidents. The dependence of the containment accident progression and containment phenomena on the initial conditions, which in turn are heavily dependent on the in-vessel accident progression and phenomena as well as associated uncertainties, is emphasized. The report is in three parts dealing with: * Swedish reactor containments, the severe accident mitigation programme in Sweden and containment accident progression in Swedish PWRs and BWRs as predicted by the MAAP 3.0 code. * Key non-energetic ex-vessel phenomena (melt fragmentation in water, melt quenching and coolability, core-concrete interaction and high temperature in containment). * Early containment threats due to energetic events (hydrogen combustion, high pressure melt ejection and direct containment heating, and ex-vessel steam explosions). The report concludes that our understanding of the containment severe accident progression and phenomena has improved very significantly over the parts ten years and, thereby, our ability to assess containment threats, to quantify uncertainties, and to interpret the results of experiments and computer code calculations have also increased. (au)

  3. Prevention of pedestrian accidents.

    OpenAIRE

    Kendrick, D

    1993-01-01

    Child pedestrian accidents are the most common road traffic accident resulting in injury. Much of the existing work on road traffic accidents is based on analysing clusters of accidents despite evidence that child pedestrian accidents tend to be more dispersed than this. This paper analyses pedestrian accidents in 573 children aged 0-11 years by a locally derived deprivation score for the years 1988-90. The analysis shows a significantly higher accident rate in deprived areas and a dose respo...

  4. Evaluation of severe accident environmental conditions taking accident management strategy into account for equipment survivability assessments

    International Nuclear Information System (INIS)

    Lee, Byung Chul; Jeong, Ji Hwan; Na, Man Gyun; Kim, Soong Pyung

    2003-01-01

    This paper presents a methodology utilizing accident management strategy in order to determine accident environmental conditions in equipment survivability assessments. In case that there is well-established accident management strategy for specific nuclear power plant, an application of this tool can provide a technical rationale on equipment survivability assessment so that plant-specific and time-dependent accident environmental conditions could be practically and realistically defined in accordance with the equipment and instrumentation required for accident management strategy or action appropriately taken. For this work, three different tools are introduced; Probabilistic Safety Assessment (PSA) outcomes, major accident management strategy actions, and Accident Environmental Stages (AESs). In order to quantitatively investigate an applicability of accident management strategy to equipment survivability, the accident simulation for a most likely scenario in Korean Standard Nuclear Power Plants (KSNPs) is performed with MAAP4 code. The Accident Management Guidance (AMG) actions such as the Reactor Control System (RCS) depressurization, water injection into the RCS, the containment pressure and temperature control, and hydrogen concentration control in containment are applied. The effects of these AMG actions on the accident environmental conditions are investigated by comparing with those from previous normal accident simulation, especially focused on equipment survivability assessment. As a result, the AMG-involved case shows the higher accident consequences along the accident environmental stages

  5. Model review and evaluation for application in DOE safety basis documentation of chemical accidents - modeling guidance for atmospheric dispersion and consequence assessment

    Energy Technology Data Exchange (ETDEWEB)

    Lazaro, M. A. [Argonne National Lab. (ANL), Argonne, IL (United States); Woodarad, K. [Argonne National Lab. (ANL), Argonne, IL (United States); Hanna, S. R. [Argonne National Lab. (ANL), Argonne, IL (United States); Hesse, D. J. [Argonne National Lab. (ANL), Argonne, IL (United States); Huang, J. -C. [Argonne National Lab. (ANL), Argonne, IL (United States); Lewis, J. [Argonne National Lab. (ANL), Argonne, IL (United States); Mazzola, C. A. [Argonne National Lab. (ANL), Argonne, IL (United States)

    1997-09-01

    The U.S. Department of Energy (DOE), through its Defense Programs (DP), Office of Engineering and Operations Suppon, established the Accident Phenomenology and Consequence (AP AC) Methodology Evaluation Program to identify and evaluate methodologies and computer codes to support accident phenomenological and consequence calculations for both radiological and nonradiological materials at DOE facilities and to identify development needs. The program is also intended to define and recommend "best or good engineering/safety analysis practices" to be followed in preparing ''design or beyond design basis" assessments to be included in DOE nuclear and nonnuclear facility safety documents. The AP AC effort is intended to provide scientifically sound and more consistent analytical approaches, by identifying model selection procedures and application methodologies, in order to enhance safety analysis activities throughout the DOE complex.

  6. An investigation of changes in element distribution and chemical states during differentiation of embryonic stem cells

    International Nuclear Information System (INIS)

    Sugimoto, T.; Ide-Ektessabi, A.; Ishihara, R.; Tanigaki, M.

    2004-01-01

    Metallic elements and their organic compounds have dynamic regulatory functions in cells. In this study, we implemented a new approach to investigate the mechanism of differentiation of embryonic stem cells, by measuring and analyzing the change in distribution and chemical states of intracellular trace elements. We anticipate that trace metal elements and metalloproteins play important roles in the direction of differentiation, both as active centers, and as factors in the death of neural cells in neurodegenerative disorders. The aim of this study is to analyze the distribution and chemical states of trace elements during the process of differentiation of mouse embryonic stem cells, and to understand how these factors relate to the differentiation process. Using the experimental results, some previously unexplained points are considered, namely (1) how the intracellular elements change during the process of neuronal differentiation, and (2) what the optimal conditions of such elements are for neuronal differentiation. The information obtained during this study is relevant to nervous system development and evolution

  7. Investigation on the effect of chemical composition on the texture and bake hardening I F steels

    International Nuclear Information System (INIS)

    Kariman, M.; Motaghi, A.; Raygan, Sh.; Habibi Parsa, M.; Nili Ahmadabadi, M.

    2008-01-01

    Interstitial free steels have good formability and also excellent deep draw ability. These features make them one of the applicable materials in automotive industry. Chemical composition and thermomechanical treatment used to process these steels have important role in final properties of them. In this study, the effect of chemical composition on texture, anisotropic properties and bake harden ability of these steels were investigated. The results showed that contribution of vanadium as a weak carbonitride former element with titanium as strong carbonitride former could change the texture of steels. Replacing titanium with vanadium caused harmful effect on mechanical properties. In this research deep drawing properties of five steels were compared based on I {111} / I{001} and I {111} / I{110} parameters. The results of bake harden ability test showed that there were critical limits for vanadium volume fractions above which bake harden properties was improved. It was shown that the bake harden properties of Nb-steels were better than that of Ti-steels. This was due to the better solution of Nb(C,N) compared to Ti(C,N). Addition of vanadium to Ti-steels may improve bake harden properties of I F steels

  8. Experimental investigation of the chemical looping method on a 1 MW pilot plant

    International Nuclear Information System (INIS)

    Orth, Matthias

    2014-01-01

    Attempting to counteract the consequences of climate change, leading industrial nations have agreed on reducing their CO 2 emissions significantly. To reach these reduction goals, it is essential to reduce the CO 2 emissions in the field of energy conversion. This PHD thesis covers the field of chemical looping combustion, a technology that uses fossil fuels for energy conversion with inherent capture of CO 2 . Since the research regarding chemical looping had so far focused mainly on lab scale or small scale experiments, a 1 MW pilot plant has been erected at Technische Universitaet Darmstadt in order to investigate the process in a semi-industrial scale and to check the process efficiency with commercially usable equipment. This pilot consists of two interconnected fluidized bed reactors and has an overall height of more than 11 m. In this thesis, some experiments with ilmenite - used as the oxygen carrier - are explained. Furthermore, the design, erection and commissioning of the pilot plant are presented as well as the results of the first test campaigns. The evaluation of the latter proves that the process can be handled in the design configuration and that CO 2 can be safely captured in a pilot plant of this scale.

  9. Quantum chemical molecular dynamical investigation of alkyl nitrite photo-dissociated on copper surfaces

    International Nuclear Information System (INIS)

    Wang Xiaojing; Wang Wei; Han Peilin; Kubo, Momoji; Miyamoto, Akira

    2008-01-01

    An accelerated quantum chemical molecular dynamical code 'Colors-Excite' was used to investigate the photolysis of alkyl nitrites series, RONO (R=CH 3 and C(CH 3 ) 3 ) on copper surfaces. Our calculations showed that the photo-dissociated processes are associated with the alkyl substituents of RONO when adsorbed on copper surfaces. For R=CH 3 , a two-step photolysis reaction occurred, yielding diverse intermediate products including RO radical, NO, and HNO, consistent with those reported in gas phase. While for R=C(CH 3 ) 3 , only one-step photolysis reaction occurred and gave intermediate products of RO radical and NO. Consequently, pure RO species were achieved to adsorb on metal surfaces by removing the NO species in photolysis reaction. The detailed photo-dissociated behaviors of RONO on copper surfaces with different alkyl substituents which are uncovered by the present simulation can be extended to explain the diverse dissociative mechanism experimentally observed. The quantum chemical molecular dynamical code 'Colors-Excite' is proved to be highly applicable to the photo-dissociations on metal surfaces

  10. Chemical investigation, isolation and structural analysis of flavones from primula veris

    International Nuclear Information System (INIS)

    Huck, Ch.

    1998-01-01

    The chemical investigation, isolation and structural analysis of six flavones present in flowers of Primula veris is described. Sample preparation of substances G from Primula veris comprised methanol extraction, low pressure chromatography on aluminum oxide, medium pressure chromatography on silica gel, and RP-HPLC on ODS. The six flavones, which were identified by their blue fluorescence after separation by thin layer chromatography, were named substance G1, G2, G3, G4, G5 and G6 according to their Rf-values. Fractions were collected during each of the separation processes and the fractions were analyzed by NP-HPLC and RP-HPLC. Higher resolution was obtained by NP-HPLC on a silica gel column and an n-hexane/ isopropanol (92:8 v/v) eluent, where 6 peaks (G1, G2, G3, G4, G5 and G6) were obtained. Diode array detection from 190 - 350 nm was utilized for the recording of UV-spectra for peak identification and peak-purity-analysis. The structures of Substance G4 and Substance G6 were established on the basis of UV, NMR, EI-MS and APCI-MS. The structure of the isolated substance G4 was verified by chemical synthesis. (author)

  11. Investigation of the Pulsed Annular Gas Jet for Chemical Reactor Cleaning

    Directory of Open Access Journals (Sweden)

    Zvegintsev Valery Ivanovich

    2012-01-01

    Full Text Available The most economical technology for production of titanium dioxide pigment is plasma-chemical syntheses with the heating of the oxygen. The highlight of the given reaction is formation of a solid phase as a result of interactions between two gases, thus brings the formation of particle deposits on the reactor walls, and to disturbing the normal operation of the technological process. For the solving of the task of reactor internal walls cleaning the pulsed gaseous system was suggested and investigated, which throws circular oxygen jet along surfaces through regular intervals. Study of aerodynamic efficiency of the impulse system was carried by numerical modeling and experimentally with the help of a specially created experimental facility. The distribution of the pulsed flow velocity at the exit of cylindrical reactor was measured. The experimental results have shown that used impulse device creates a pulsed jet with high value of the specified flow rate. It allows to get high velocities that are sufficient for the particle deposits destruction and their removal away. Designed pulsed peelings system has shown high efficiency and reliability in functioning that allows us to recommend it for wide spreading in chemical industry.

  12. Structural, vibrational, electronic investigations and quantum chemical studies of 2-amino-4-methoxybenzothiazole

    Science.gov (United States)

    Arjunan, V.; Raj, Arushma; Santhanam, R.; Marchewka, M. K.; Mohan, S.

    2013-02-01

    Extensive vibrational investigations of 2-amino-4-methoxybenzothiazole have been carried out with FTIR and FT-Raman spectral techniques. The electronic structure of the molecule has been analysed by UV-Visible and NMR spectroscopies. The DFT studies were carried out with B3LYP and HF methods utilising 6-31G(d,p), 6-311++G(d,p) and cc-pVDZ basis sets to determine the structural, thermodynamical, vibrational, electronic characteristics of the compound and also to understand the electronic and steric influence of the methoxy amino groups on the skeletal frequencies. The mixing of the fundamental modes was determined with the help of total energy distribution (TED). The energies of the frontier molecular orbitals have also been determined. The kinetic and thermodynamic stability and chemical hardness of the molecule have been determined. Complete NBO analysis was also carried out to find out the intramolecular electronic interactions and their stabilisation energy. 1H and 13C NMR chemical shifts and the electronic transitions of the molecule are also discussed.

  13. Investigation of the chemical mechanisms involved in the electropulsation of membranes at the molecular level.

    Science.gov (United States)

    Breton, Marie; Mir, Lluis M

    2018-02-01

    The chemical consequences of electropulsation on giant unilamellar vesicles (GUVs), in particular the possible oxidation of unsaturated phospholipids, have been investigated by mass spectrometry, flow cytometry and absorbance methods. Pulse application induced oxidation of the GUV phospholipids and the oxidation level depended on the duration of the pulse. Light and O 2 increased the level of pulse-induced lipid peroxidation whereas the presence of antioxidants either in the membrane or in the solution completely suppressed peroxidation. Importantly, pulse application did not create additional reactive oxygen species (ROS) in GUV-free solution. Lipid peroxidation seems to result from a facilitation of the lipid peroxidation by the ROS already present in the solution before pulsing, not from a direct pulse-induced peroxidation. The pulse would facilitate the entrance of ROS in the core of the membrane, allowing the contact between ROS and lipid chains and provoking the oxidation. Our findings demonstrate that the application of electric pulses on cells could induce the oxidation of the membrane phospholipids since cell membranes contain unsaturated lipids. The chemical consequences of electropulsation will therefore have to be taken into account in future biomedical applications of electropulsation since oxidized phospholipids play a key role in many signaling pathways and diseases. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Structural, vibrational, electronic investigations and quantum chemical studies of 2-amino-4-methoxybenzothiazole.

    Science.gov (United States)

    Arjunan, V; Raj, Arushma; Santhanam, R; Marchewka, M K; Mohan, S

    2013-02-01

    Extensive vibrational investigations of 2-amino-4-methoxybenzothiazole have been carried out with FTIR and FT-Raman spectral techniques. The electronic structure of the molecule has been analysed by UV-Visible and NMR spectroscopies. The DFT studies were carried out with B3LYP and HF methods utilising 6-31G(d,p), 6-311++G(d,p) and cc-pVDZ basis sets to determine the structural, thermodynamical, vibrational, electronic characteristics of the compound and also to understand the electronic and steric influence of the methoxy amino groups on the skeletal frequencies. The mixing of the fundamental modes was determined with the help of total energy distribution (TED). The energies of the frontier molecular orbitals have also been determined. The kinetic and thermodynamic stability and chemical hardness of the molecule have been determined. Complete NBO analysis was also carried out to find out the intramolecular electronic interactions and their stabilisation energy. (1)H and (13)C NMR chemical shifts and the electronic transitions of the molecule are also discussed. Copyright © 2012 Elsevier B.V. All rights reserved.

  15. An investigation of changes in element distribution and chemical states during differentiation of embryonic stem cells

    Energy Technology Data Exchange (ETDEWEB)

    Sugimoto, T.; Ide-Ektessabi, A. E-mail: h51167@sakura.kudpc.kyoto-u.ac.jp; Ishihara, R.; Tanigaki, M

    2004-07-01

    Metallic elements and their organic compounds have dynamic regulatory functions in cells. In this study, we implemented a new approach to investigate the mechanism of differentiation of embryonic stem cells, by measuring and analyzing the change in distribution and chemical states of intracellular trace elements. We anticipate that trace metal elements and metalloproteins play important roles in the direction of differentiation, both as active centers, and as factors in the death of neural cells in neurodegenerative disorders. The aim of this study is to analyze the distribution and chemical states of trace elements during the process of differentiation of mouse embryonic stem cells, and to understand how these factors relate to the differentiation process. Using the experimental results, some previously unexplained points are considered, namely (1) how the intracellular elements change during the process of neuronal differentiation, and (2) what the optimal conditions of such elements are for neuronal differentiation. The information obtained during this study is relevant to nervous system development and evolution.

  16. Chemical interactions between the metallic silver aerosols and the iodide compounds in the containment building of a PWR reactor during a serious accident; Interactions chimiques entre les aerosols d'argent metallique et les composes iodes dans l'enceinte de confinement d'un reacteur nucleaire a eau pressurisee en cas d'accident grave

    Energy Technology Data Exchange (ETDEWEB)

    Serra, D.; Saint-Raymond, O.; Zoulalian, A. [Universite Henri Poincare, LERMAB-ENSTIB, 54 - Vandoeuvre-les-Nancy (France); Montanelli, T. [CEA/Cadarache, Inst. de Protection et de Surete Nucleaire, IPSN/DRS/SESHP/LEATS, 13 - Saint-Paul-lez-Durance (France)

    2000-07-01

    During an hypothetical severe accident in a PWR, the iodide fission products can be transferred into the liquid phase of the containment with silver particles (or silver colloid) resulting from the fusion and the vaporization of neutronic control rods. The chemical interactions between the iodide ions and the molecular iodine with the silver particles are studied in an aqueous phase separately and without radiation. The interaction between the iodide ions and silver particles requires a preliminary oxidation step of the silver particles the rate of which depends on the pH, the temperature and the liquid oxygen concentration. A kinetic model including two independent stoichiometries allows to represent correctly the whole experimental runs. At pH = 3, the chemical interactions between molecular iodine and silver particles do not require an oxidation step and a second order kinetic model is able to represent the experimental results considering the operating conditions studied. (authors)

  17. Investigation of 3D spatial effect on point kinetics estimation of the thermal hydraulics code RELAP for the analysis of MSLB accident of KK-NP

    International Nuclear Information System (INIS)

    Bera, S.; Pradhan, S.K.; Dubey, S.K.; Gupta, S.K.

    2011-01-01

    In general safety analyses of design basis accident of NPPs are being carried out using system thermal hydraulics code like RELAP. In RELAP, power is calculated based on point kinetics approximation, which virtually ignores the space and energy dependence of neutron flux. To include the space and energy dependence of neutron flux, three-dimensional neutronics code TRIHEXFA has been externally coupled with RELAP through interface program, TRIHEXFA-RELAP Interface Program (TRIP). Calculation methodology of TRIP program is based on adiabatic approximation. In the adiabatic approximation the neutron flux is being factored into spatial and amplitude part. Spatial part of flux is slowly varying with time whereas amplitude part is strongly varying function. The RELAP controls the transient time steps. Transient time is divided into several major and minor time steps. Minor time step is the sub-step of major time step. Thermal hydraulics and neutronics data are exchanged at each major time step. Spatial part of neutron flux has been updated at each major time step using TRIHEXFA code. But amplitude part of the neutron flux is calculated at each minor time step using RELAP code. Convergence of results of the coupled code, TRIP has been checked through coupling time step descritization study. This study determines the minimum coupling time step. Transient concerning VVER-1000 Main Steam Line Break, MSLB has been considered to investigate the space-time effect on point kinetics. MSLB occurs as a consequence of the rupture of one steam line upstream of main steam line isolation valves. Reference design and data from Kudankulam Nuclear Power Plant (KK-NPP) are used for the analysis. From this investigation it is found that TRIP significantly overestimates the maximum reactor power against uncoupled RELAP result. The time of scram also occur six seconds earlier in TRIP calculation compared to the RELAP. This exercise has also shown a proof of principle that coupling 3D

  18. Investigating the role for adaptation of the microbial community to transform trace organic chemicals during managed aquifer recharge

    KAUST Repository

    Alidina, Mazahirali; Li, Dong; Drewes, Jorg

    2014-01-01

    This study was undertaken to investigate whether adaptation by pre-exposure to trace organic chemicals (TOrCs) was necessary for microbial transformation during managed aquifer recharge (MAR). Two pairs of laboratory-scale soil columns, each

  19. Notification: FY 2012 Management Challenges and Internal Control Weaknesses for the Chemical Safety and Hazard Investigation Board

    Science.gov (United States)

    February 1, 2012. The EPA Office of Inspector General is beginning work to update our list of areas we consider to be the key management challenges confronting the Chemical Safety and Hazard Investigation Board.

  20. Chemical Stability Investigations of Polyisobutylene as New Binder for Application in Lithium Air-Batteries

    International Nuclear Information System (INIS)

    Heine, Jennifer; Rodehorst, Uta; Badillo, Juan Pablo; Winter, Martin; Bieker, Peter

    2015-01-01

    ABSTRACT: The side reactions of LiO 2 , Li 2 O 2 and Li 2 O, formed during the discharge process at the cathode/electrolyte interphase, are still a main challenge of lithium-air batteries. During these reactions, polyvinylidene difluoride (PVdF), as the commonly used cathode binder material, is decomposing, leading to a shorter lifetime of the battery. In this paper, we introduced and investigated polyisobutylene (PIB), a chemically and electrochemically inert polymeric material, to substitute PVdF as binder for lithium-air batteries. Results obtained by X-ray diffraction and spectroscopic methods showed, that PIB is far more stable in the presence of O 2 − , O 2 2− as well as O 2− species compared to PVdF. This distinct inertness makes PIB a promising binder for lithium-air batteries

  1. Chemical investigations of isotope separation on line target units for carbon and nitrogen beams

    CERN Document Server

    Franberg, H; Gäggeler, H W; Köster, U

    2006-01-01

    Radioactive ion beams (RIBs) are of significant interest in a number of applications. Isotope separation on line (ISOL) facilities provide RIB with high beam intensities and good beam quality. An atom that is produced within the ISOL target will first diffuse out from the target material. During the effusion towards the transfer line and into the ion source the many contacts with the surrounding surfaces may cause unacceptable delays in the transport and, hence, losses of the shorter-lived isotopes. We performed systematic chemical investigations of adsorption in a temperature and concentration regime relevant for ISOL targets and ion source units, with regard to CO/sub x/ and NOmaterials are potential construction materials for the above-mentioned areas. Off-line and on-line tests have been performed using a gas thermochromatography setup with radioactive tracers. The experiments were performed at the production of tracers for atmospheric chemistry (PROTRAC) facility at the Paul Schener Institute in Villigen...

  2. Spectroscopic (vibrational, NMR and UV-vis.) and quantum chemical investigations on 4-hexyloxy-3-methoxybenzaldehyde.

    Science.gov (United States)

    Abbas, Ashgar; Gökce, Halil; Bahçeli, Semiha

    2016-01-05

    In this study, the 4-hexyloxy-3-methoxybenzaldehyde compound as one of the derivatives of vanillin which is a well known flavoring agent, C14H20O3, has been investigated by experimentally and extensively utilizing density functional theory (DFT) at the B3LYP/6-311++G(d,p) level. In this context, the optimized geometry, vibrational frequencies, (1)H and (13)C NMR chemical shifts, UV-vis. (in gas phase and in methanol solvent) spectra, HOMO-LUMO analysis, molecular electrostatic potential (MEP), thermodynamic parameters and atomic charges of 4-hexyloxy-3-methoxybenzaldehyde have been calculated. In addition, theoretically predicted IR, Raman and UV-vis. (in gas phase and in methanol solvent) spectra of the mentioned molecule have been constructed. The results calculated were compared with the experimental data. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Chemical and isotopic investigations of runoff in a mountainous watershed, Venezuelan Andes (Rio Bocono)

    International Nuclear Information System (INIS)

    Cornieles, M.; Moreau, A.; Valles, V.; Travi, Y.

    1999-01-01

    The Rio Bocono watershed, located in the Western part of Venezuela on the South western side of Andes is considered by the 'Ministerio de1 Ambiente y de los Recursos Naturales Renovables' (MARN) as a priority zone for environmental management. The studies of relation between flow, dissolved elements and solid transport are essential to estimate soil degradation and sediment deposition which provokes loss of depth in the dam reservoir at the Southern margin of the basin. Because of the large surface which reach 1540 km 2 , the lack of equipment and the flash flood character of the river do not enable the flow mechanisms and transit times to be determined using usual hydrologic methods; therefore this problem has been approached by the way of chemical and isotopic investigation

  4. A Marine Sulfate-Reducing Bacterium Producing Multiple Antibiotics: Biological and Chemical Investigation

    Directory of Open Access Journals (Sweden)

    Xiaoliang Wang

    2009-07-01

    Full Text Available A marine sulfate-reducing bacterium SRB-22 was isolated by means of the agar shake dilution method and identified as Desulfovibrio desulfuricans by morphological, physiological and biochemical characteristics and 16S rDNA analysis. In the bioassay, its extract showed broad-spectrum antimicrobial activity using the paper disc agar diffusion method. This isolate showed a different antimicrobial profile than either ampicillin or nystatin and was found to produce at least eight antimicrobial components by bioautography. Suitable fermentation conditions for production of the active constituents were determined to be 28 day cultivation at 25 °C to 30 °C with a 10% inoculation ratio. Under these conditions, the SRB-22 was fermented, extracted and chemically investigated. So far an antimicrobial compound, mono-n-butyl phthalate, and an inactive compound, thymine, have been isolated and characterized.

  5. Investigation of CdS/InP heterojunction prepared by chemical bath deposition

    International Nuclear Information System (INIS)

    Rakovics, V.; Horvath, Zs.J.; Horvath, Zs.E.; Barsony, I.; Frigeri, C.; Besagni, T.

    2007-01-01

    CdS thin films have been deposited on InP and glass substrates using the chemical bath deposition technique. Baths containing CdSO 4 , thiourea, and NH 3 were used. The temperature of the deposition process was 65 C and the duration of deposition varied between 20 and 160 minutes. The properties of the CdS/InP heterojunction were investigated by TEM, EDS and X-ray diffraction. TEM pictures, EDS and X-ray rocking curves indicate the formation of a β-In 2 S 3 transition layer at the InP-CdS interface, which may reduce the lattice mismatch between InP and CdS. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. An investigation of the chemical composition and acid corrosion of pedra sabão (soapstone

    Directory of Open Access Journals (Sweden)

    ROBSON FERNANDES DE FARIAS

    2005-02-01

    Full Text Available In this paper the results of a basic study of the chemical composition and structure of soapstone are reported. An investigation of the effects of aqueous sulfuric acid solutions on the physical integrity of the stone was also performed. The studied soapstone samples had a lamellar nanostructure as verified by DRX data. Furthermore, they contained isolated silanol (Si–OH groups, as indicated by FTIR data, and the majority of the silicon atoms were bonded to OH groups, as shown by 29Si CPMAS NMR analysis. Is was also shown that a low resistance to acid attack is associated with a large amount of magnesium and/or iron in the stone.

  7. Investigation of Acute Toxicity of a Chemical Warfare Agent in Kidneys

    Directory of Open Access Journals (Sweden)

    Turgut Topal

    2007-08-01

    Full Text Available One of the most important chemical warfare agents, sulfur mustard (SM causes crucial acute and chronic toxic effects. Lung, skin, eye and kidneys are the most affected organs. In this work, it was investigated if increased nitric oxide (NO and peroxynitrite are involved in nitrogen mustard (NM induced kidney damage. In this experimen, aminoguanidine (AG as inducible nitric oxide synthase (iNOS inhibitor and ebselen as peroxynitrite scavenger were used. NM administration resulted in important oxidant and antioxidant changes as well as tissue damage in kidneys. Therapeutic agents showed significant protection and reduced oxidant parameteres leading to tissue healing was observed. Results of this study suggest that drugs with similar properties can be used to protect kidney damage caused by NM. [TAF Prev Med Bull. 2007; 6(4: 227-232

  8. Investigation of Acute Toxicity of a Chemical Warfare Agent in Kidneys

    Directory of Open Access Journals (Sweden)

    Turgut Topal

    2007-08-01

    Full Text Available One of the most important chemical warfare agents, sulfur mustard (SM causes crucial acute and chronic toxic effects. Lung, skin, eye and kidneys are the most affected organs. In this work, it was investigated if increased nitric oxide (NO and peroxynitrite are involved in nitrogen mustard (NM induced kidney damage. In this experimen, aminoguanidine (AG as inducible nitric oxide synthase (iNOS inhibitor and ebselen as peroxynitrite scavenger were used. NM administration resulted in important oxidant and antioxidant changes as well as tissue damage in kidneys. Therapeutic agents showed significant protection and reduced oxidant parameteres leading to tissue healing was observed. Results of this study suggest that drugs with similar properties can be used to protect kidney damage caused by NM. [TAF Prev Med Bull 2007; 6(4.000: 227-232

  9. Remedial investigation for the chemical plant area of the Weldon Spring Site

    International Nuclear Information System (INIS)

    1992-11-01

    The US Department of Energy (DOE) is responsible for management of the Weldon Spring Site Remedial Action Project (WSSRAP) under its Environmental Restoration and Waste Management Program. Major goals include eliminating potential public and environmental hazards due to site contamination and releasing the property for alternate uses to the maximum extent practicable. The purpose of the remedial investigation described in this report was to determine the extent of contamination associated with the portion of the Weldon Spring site known as the chemical plant and raffinate pit area. The DOE has assumed responsibility for investigating and remediating all on-site soil contamination and off-site soil which is radiologically contaminated as a result of uranium and thorium processing operations. The DOE has also assumed the responsibility for radiologically contaminated groundwater on and off site. The Weldon Spring site remedial investigation also involved the evaluation of the sources, nature and extent, and environmental fate and transport of contaminants to provide a basis for defining the risks that the contaminants may pose to human health and the environment. Data are included in this report to support the screening of remedial technologies and to permit the development and detailed analysis of alternatives for remedial action at the site during the feasibility study process

  10. Criticality accident of nuclear fuel facility. Think back on JCO criticality accident

    International Nuclear Information System (INIS)

    Naito, Keiji

    2003-09-01

    This book is written in order to understand the fundamental knowledge of criticality safety or criticality accident of nuclear fuel facility by the citizens. It consists of four chapters such as critical conditions and criticality accident of nuclear facility, risk of criticality accident, prevention of criticality accident and a measure at an occurrence of criticality accident. A definition of criticality, control of critical conditions, an aspect of accident, a rate of incident, damage, three sufferers, safety control method of criticality, engineering and administrative control, safety design of criticality, investigation of failure of safety control of JCO criticality accident, safety culture are explained. JCO criticality accident was caused with intention of disregarding regulation. It is important that we recognize the correct risk of criticality accident of nuclear fuel facility and prevent disasters. On the basis of them, we should establish safety culture. (S.Y.)

  11. Student-selected component in the medical curriculum: investigations and psychiatric referral for paracetamol overdose in an accident and emergency department

    Directory of Open Access Journals (Sweden)

    Cowman JG

    2017-08-01

    Full Text Available James G Cowman, Manuel Bakheet Royal College of Surgeons in Ireland – Medical University of Bahrain, Manama, Bahrain Background: A student-selected component (SSC of the medical curriculum requires the student to be self-directed in locating and undertaking a placement in a clinical specialty of their choosing and completing a project. The clinical area for experience was an accident and emergency department, and our topic was a focused audit on the investigations and referral for paracetamol overdose. The purpose of this paper is twofold: to reflect on the education value to medical students of an SSC in a medical curriculum, and to highlight learning and understanding through completion of an audit.Materials and methods: An audit approach was applied. The aim of the project study was to investigate the level of compliance with best-practice guidelines for investigations and psychiatric referral in paracetamol overdose.Results: A total of 40 cases meeting the inclusion criteria were randomly selected. The sample had a mean age of 27 years, of whom 70.5% were female, and the ingested dose of paracetamol ranged from 0.864 to 80 g. Paracetamol abuse may present as intentional and unintentional overdose. In our study, 85% of cases were identified as intentional overdose and 76% had a history of psychiatric illness. Generally, medical management was compliant with guidelines, with some minor irregularities. The international normalized ratio was the most underperformed test.Conclusion: Our choice of topic, paracetamol overdose, contributed to our understanding of the breadth of factors to be considered in the emergency medical management of a patient. In this regard, we had the benefit of understanding how the diagnostic and therapeutic factors, when applied in accordance with best-practice guidelines, work very effectively. The SSC impacted positively on our cognitive, personal, and professional development. In facilitating the student with

  12. Radiation accidents

    International Nuclear Information System (INIS)

    Saenger, E.L.

    1986-01-01

    It is essential that emergency physicians understand ways to manage patients contaminated by radioactive materials and/or exposed to external radiation sources. Contamination accidents require careful surveys to identify the metabolic pathway of the radionuclides to guide prognosis and treatment. The level of treatment required will depend on careful surveys and meticulous decontamination. There is no specific therapy for the acute radiation syndrome. Prophylactic antibodies are desirable. For severely exposed patients treatment is similar to the supportive care given to patients undergoing organ transplantation. For high-dose extremity injury, no methods have been developed to reverse the fibrosing endarteritis that eventually leads to tissue death so frequently found with this type of injury. Although the Three Mile Island episode of March 1979 created tremendous public concern, there were no radiation injuries. The contamination outside the reactor building and the release of radioiodine were negligible. The accidental fuel element meltdown at Chernobyl, USSR, resulted in many cases of acute radiation syndrome. More than 100,000 people were exposed to high levels of radioactive fallout. The general principles outlined here are applicable to accidents of that degree of severity

  13. Reactor accidents of four decades

    International Nuclear Information System (INIS)

    Szabo, Z.

    1982-11-01

    The report covers the period between 1942 and June 30, 1982. A detailed description and a comparative analysis of reactor accidents and chemical-processing-plant excursions are presented. The analysis takes into account the following points: causes (design, maintenance, operation); events (initiating event and sequence of events); consequences (environmental impacts, personnel effects and equipment damages). (author)

  14. Thule accident 1968

    International Nuclear Information System (INIS)

    Melgaard, L.; Moeller Kristensen, H.

    1987-01-01

    On January 21, 1968 an American B-52 bomber crashed on the ice at Thule in Nothern Greenland. The bomber carried 4 nuclear weapons that were destroyed. The radioactive material of the bombs was spread over a large area of the ice. About 850 Danes stayed at the Thule base in 1968 for a shorter or longer period. Out of these 850 probably between 70 and 170 men took part in the clearing after the accident. Danish and American authorities establised that the radioactive contamination from the accident was too small to cause any health effects. For that reason the Danish authorities did not follow the Danish workers in order to show late effects, if any. In defiance of the authorities' very cocksure attitude towards possible late effets parts of the Danish press in the Summer 1986 started to be interested in the matter and to search for previous Thule-workers. Up till January 1987 aboput 600 workers have been contacted by the press, trade unions, and private persons. About 500 out of the 600 workers report on illness, cancers and deaths. This report tries to compile the accessible informations on the matter, to descibe the possible radioactive and chemical effects, to compare the Thule accident with a similar incident in Spain in 1966, and to propose a comprehensive health examination of all the workers. (LN)

  15. 29 CFR 1960.70 - Reporting of serious accidents.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 9 2010-07-01 2010-07-01 false Reporting of serious accidents. 1960.70 Section 1960.70... accidents. Agencies must provide the Office of Federal Agency Programs with a summary report of each fatal and catastrophic accident investigation. The summaries shall address the date/time of accident, agency...

  16. Investigation of break location effects on thermal-hydraulics during intermediate break loss-of-coolant accident experiments at ROSA-III

    International Nuclear Information System (INIS)

    Koizumi, Yasuo; Tasaka, Kanji

    1986-01-01

    The rig of safety assessment (ROSA)-III facility is a volumetrically scaled (1/424) boiling water reactor (BWR/6) system with an electrically heated core designed for integral loss-of-coolant accident (LOCA) and emergency core cooling system (ECCS) tests. Break location effects on thermal-hydraulics during intermediate LOCAs were investigated by using four experiments at the ROSA-III, the 15 and 25 % main recirculation pump suction line break (MRPS-B) experiments, the 21 % single-ended jet pump drive line break (JPD-B) experiment and the 15 % main steam line break (MSL-B) experiment. Water injection from the high pressure core spray (HPCS) was not used in any of the experiments. Failure of ECCS actuation by the high containment pressure was also assumed in the tests. In the MRPS-B experiments, the discharge flow turned from low quality fluid to high quality fluid when the downcomer water level dropped to the main recirculation line outlet elevation, which suppressed coolant loss from the vessel and the core. In the JPD-B experiment, the jet pump drive nozzle was covered with low quality fluid and low quality fluid discharge continued even after the downcomer water level reached the jet pump suction elevation. Low quality fluid discharge ceased after the ADS actuation. It suggestes that the JPD-B LOCA has the possibility of causing larger and more severe core dryout and cladding temperature excursion than the MRPS-B LOCA. The MSL-B LOCA was characterized by mixture level swell in the downcomer and the core. The core mixture level swell resulted in the much later core dryout initiation than that in the MRPS-B LOCA, however, ECCS actuation was also delayed because of slow downcomer water level drop. (author)

  17. Contribution to the description of the absorber rod behavior in severe accident conditions: An experimental investigation of the Ag–Zr phase diagram

    Energy Technology Data Exchange (ETDEWEB)

    Decreton, A. [Institut de Radioprotection et Sureté Nucléaire, B.P. 3, 13115 Saint Paul-lez-Durance Cedex (France); Benigni, P.; Rogez, J.; Mikaelian, G. [IM2NP, UMR7334, CNRS, Aix-Marseille Université, Campus de Saint Jérôme, Avenue Escadrille Normandie Niémen – Case 251, 13397 Marseille Cedex 20 (France); Barrachin, M., E-mail: marc.barrachin@irsn.fr [Institut de Radioprotection et Sureté Nucléaire, B.P. 3, 13115 Saint Paul-lez-Durance Cedex (France); Lomello-Tafin, M.; Antion, C.; Janghorban, A. [Laboratoire SYMME, Polytech Annecy Chambéry – Université de Savoie, BP. 80439, 74944 Annecy-Le-Vieux Cedex (France); Fischer, E. [Université Grenoble Alpes, CMTC, SIMAP, 38000 Grenoble (France)

    2015-10-15

    Most pressurized water reactor (PWR) absorber rods are composed of an Ag–In–Cd (SIC) alloy inside a stainless steel (SS) cladding, themselves inserted into a Zircaloy tube. During a severe accident, the SIC alloy which melts at 800 °C does not practically interact with SS. However, the cladding failure results from its internal pressurization and its eutectic interaction with Zircaloy and occurs at temperatures greater than 1200 °C. The subsequent interaction between the SIC melt and the Zircaloy has a strong impact on the quantities of aerosols released into the primary circuit and finally on the iodine chemistry. Accurate knowledge of the Ag–Zr system is a prerequisite to address this issue. Within this concern, our experimental work is focused both on the investigation of the Ag–Zr phase diagram and on the determination of the thermodynamic properties of the intermetallic compounds in the system. Two intermetallic compounds (AgZr and AgZr{sub 2}) were identified. Ag–Zr cast alloys with a Ag/Zr ratio of 1:1 elaborated using an arc-melting furnace, once annealed, contained only a single phase AgZr. From metallographic observations, it appears that AgZr{sub 2} likely forms by the peritectic reaction from liquid and the bcc (βZr) phase. The partial enthalpies of solution of silver and zirconium in aluminum were experimentally determined at 723 °C in order to determine the enthalpies of formation of the intermetallic compounds. For silver solution calorimetry in aluminum bath, our measurements were successful and in agreement with the previous data. Yet, this study shows that liquid aluminum should not be used as a solvent for zirconium below 1000 °C.

  18. Role of noble metal nanoparticles in DNA base damage and catalysis: a radiation chemical investigation

    International Nuclear Information System (INIS)

    Sharma, Geeta K.

    2011-01-01

    In the emerging field of nanoscience and nanotechnology, tremendous focus has been made by researcher to explore the applications of nanomaterials for human welfare by converting the findings into technology. Some of the examples have been the use of nanoparticles in the field of opto-electronic, fuel cells, medicine and catalysis. These wide applications and significance lies in the fact that nanoparticles possess unique physical and chemical properties very different from their bulk precursors. Numerous methods for the synthesis of noble nanoparticles with tunable shape and size have been reported in literature. The goal of our group is to use different methods of synthesis of noble metal nanoparticles (Au, Ag, Pt and Pd) and test their protective/damaging role towards DNA base damage induced by ionizing radiation (Au and Ag) and to test the catalytic activity of nanoparticles (Pt and Pd) in certain known organic synthesis/electron transfer reactions. Using radiation chemical techniques such as pulse radiolysis and steady state radiolysis complemented by the product analysis using HPLC/LC-MS, a detailed mechanism for the formation of transient species, kinetics leading to the formation of stable end products is studied in the DNA base damage induced by ionizing radiation in presence and absence of Au and Ag nanoparticles. Unraveling the complex interaction between catalysts and reactants under operando conditions is a key step towards gaining fundamental insight in catalysis. The catalytic activity of Pt and Pd nanoparticles in electron transfer and Suzuki coupling reactions has been determined. Investigations are currently underway to gain insight into the interaction between catalysts and reactants using time resolved spectroscopic measurements. These studies will be detailed during the presentation. (author)

  19. Investigation of short and long term trends in chemical composition of Eastern Mediterranean aerosols

    International Nuclear Information System (INIS)

    2011-01-01

    A collaborative study was started with the Middle East Technical University, Environmental Engineering Department in 2004 in order to determine the transport of air pollutants and their deposition rates to Eastern Mediterranean with the ultimate aim of filling the gaps in knowledge on the current status of Eastern Mediterranean air quality profile. Collection sufficient amount of representative samples, analyzes of the collected samples with high accuracy and precision and interpretation of generated data are crucial efforts. To attain this goal, EDXRF spectrometer, which is a rapid, reliable and sensitive analytical instrument, located at our center was employed in analysis of the collected samples after calibration with 'NIST 2783 Air Particles on Filter'. The effectiveness of the control strategies taken on the emissions was discussed by investigating the short and long term variations in the chemical composition of samples collected between 1993 and 2001 at Antalya station. In this context, generated data set was studied for short (daily) term, seasonal and long term variations. It has been found that short term variations in the concentrations of pollutants in short time scale are highly episodic. The concentration of measured pollutants was changed 10-20 folds in the subsequent two days. The most important factors affecting the chemical composition of pollutants in short time interval are meteorological factors such as precipitation and variations observed at the emission strength of pollutants. The declined in Pb concentrations at the Antalya station was attributed to observed decrease in Pb emissions in Europe after the introduction of leaded gasoline. Highest summer averages were reported for anthropogenic pollutants in summer months. Aegean Sea (Izmir-Aliaga) studies of the project will be completed this year

  20. The cause-consequence data base: a retrieval system for records pertaining to accident management

    International Nuclear Information System (INIS)

    Kumamoto, H.; Inoue, K.; Sawaragi, Y.

    1981-01-01

    This paper describes a proposal to store in a data base important paragraphs from reports of investigations into many types of accidents. The data base is to handle not only reports on TMI, but also reports on other events at nuclear reactors, chemical plant explosions, earthquakes, hurricanes, fires, and so forth. (author)

  1. Radiation accident in Vietnam

    International Nuclear Information System (INIS)

    Wheatley, J.

    1994-01-01

    In November 1992 a Vietnamese research physicist was working with a microtron accelerator when he received a radiation overexposure that required the subsequent amputation of his right hand. A team from the International Atomic Energy Agency visited Hanoi in March 1993 to carry out an investigation. It was concluded that the accident occurred primarily because of a lack of safety systems, although the lack of both written procedures and training in basic radiation safety were also major contributors. (author)

  2. Major accidents involving dangerous chemicals and Standard Basic Self-Protection; Accidentes graves en los que intervangan sustancias quimica peligrosas y Norma Basica de Autoproteccion

    Energy Technology Data Exchange (ETDEWEB)

    Alonso Fernandez, L.

    2011-07-01

    Nuclear and radioactive facilities and other centers, institutions and agencies engaged in activities that may lead to emergency situations, are subject to specific regulations directed to take measures to prevent and control risks at source and to act initially in emergency situations and limit the consequences, in order to protect people, property and the environment. With these premise, place the following article, which summarizes the basic guidelines in the field of major accident and self-protection, summarizing the implications of current legislation in this field. (Author)

  3. Physico-chemical aspects of radionuclide removal under accident conditions in nuclear power plants by means of containment-building spray systems

    International Nuclear Information System (INIS)

    Alm, M.

    1976-01-01

    A survey is given on industrial spray solutions, their thermal and radiation stability, drop effects, and the corrosion behaviour of reactor and containment materials. From the hitherto known spray experiments it may be concluded that (1) spray solutions can be used for the effective decontamination of the containment atmosphere in the event of a loss-of-coolant accident, (2) the spray efficiency for the removal of gaseous and volatile fission products can be assessed by means of simplified model considerations, (3) further work is necessary to optimize the technology of the spray process. (author)

  4. 40 CFR 68.168 - Five-year accident history.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Five-year accident history. 68.168 Section 68.168 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CHEMICAL ACCIDENT PREVENTION PROVISIONS Risk Management Plan § 68.168 Five-year accident history...

  5. Investigation of hydrogen generation in a three reactor chemical looping reforming process

    International Nuclear Information System (INIS)

    Khan, Mohammed N.; Shamim, Tariq

    2016-01-01

    Highlights: • Three-reactor based chemical looping reforming system for hydrogen production. • Investigation of operating parameters using a system-level model. • Optimum operating conditions for hydrogen production are identified. • Different operating parameters affect the reactor temperatures differently. - Abstract: Chemical looping reforming (CLR) is a relatively new method to produce hydrogen (H_2) and is also used as an energy conversion method for solid, liquid or gaseous fuels. There are various advantages of this method such as inherent carbon dioxide (CO_2) capture, minimal NOx emissions and the H_2 production. In this process, there is no direct contact between the fuel and oxidizer. This method utilizes oxygen from an oxygen carrier which may be a transition metal. The idea is to split the combustion process into three separate sub-processes by employing three separate reactors: air reactor where the oxygen carrier is oxidized by air, fuel reactor where natural gas is oxidized to produce a stream of CO_2 and H_2O and steam reactor where the steam is reduced to produce H_2. In this study, a thermodynamic model with iron oxides as oxygen carrier has been developed using Aspen Plus by employing conservation of mass and energy for all the components of the CLR system. The developed model was employed to investigate the effect of various operating parameters such as mass flow rates of air, fuel, steam and oxygen carrier and fraction of inert material on H_2 and CO_2 production and key reactor temperatures. The results show that the H_2 production increases with the increase in air, fuel and steam flow rates up to a certain limit and stays constant for higher flow rates. The CO_2 production follows a similar trend. Similarly, the H_2 production also increases with the increase in oxide flow rate and fraction of inert material up to a particular value, but then decrease for higher oxide flow rates and inert fractions. Reactor temperatures were also

  6. Self-reported accidents

    DEFF Research Database (Denmark)

    Møller, Katrine Meltofte; Andersen, Camilla Sloth

    2016-01-01

    The main idea behind the self-reporting of accidents is to ask people about their traffic accidents and gain knowledge on these accidents without relying on the official records kept by police and/or hospitals.......The main idea behind the self-reporting of accidents is to ask people about their traffic accidents and gain knowledge on these accidents without relying on the official records kept by police and/or hospitals....

  7. Accident Assessment

    International Nuclear Information System (INIS)

    Tripputi, Ivo; Lund, Ingemar

    2002-01-01

    There is a general feeling that decommissioning is an activity involving limited risks, compared to NPP operation, and in particular risks involving the general public. This is technically confirmed by licensing analysis and evaluations, where, once the spent fuel has been removed from the plant, the radioactivity inventory available to be released to the environment is very limited. Decommissioning activities performed so far in the world have also confirmed the first assumptions and no specific issue has been identified, in this field, to justify a completely new approach. Commercial interests in international harmonization, which could drive an in-depth discussion about the bases of this approach, are weak at the moment. However, there are several reasons why a discussion in an international framework about the Safety Case for decommissioning (and, in particular, about Accident Assessment) may be considered necessary and important, and why it may show some specific and peculiar aspects. An effort for a comprehensive and systematic D and D accident safety assessment of the decommissioning process is justified. It is necessary also to explore in a holistic way the aspects of industrial safety, and develop tools for the decision-making process optimization. The expected results are the implementation of appropriate and optimized protective measures in any event and of adequate on/off-site emergency plans for optimal public and workers protection. The experience from other decommissioning projects and large-scale industrial activities is essential to balance provisions and an Operating Experience review process (specific for decommissioning) should help to focus on real issues

  8. Estimating the Influence of Accident Related Factors on Motorcycle Fatal Accidents using Logistic Regression (Case Study: Denpasar-Bali

    Directory of Open Access Journals (Sweden)

    Wedagama D.M.P.

    2010-01-01

    Full Text Available In Denpasar the capital of Bali Province, motorcycle accident contributes to about 80% of total road accidents. Out of those motorcycle accidents, 32% are fatal accidents. This study investigates the influence of accident related factors on motorcycle fatal accidents in the city of Denpasar during period 2006-2008 using a logistic regression model. The study found that the fatality of collision with pedestrians and right angle accidents were respectively about 0.44 and 0.40 times lower than collision with other vehicles and accidents due to other factors. In contrast, the odds that a motorcycle accident will be fatal due to collision with heavy and light vehicles were 1.67 times more likely than with other motorcycles. Collision with pedestrians, right angle accidents, and heavy and light vehicles were respectively accounted for 31%, 29%, and 63% of motorcycle fatal accidents.

  9. Contributing factors in construction accidents.

    Science.gov (United States)

    Haslam, R A; Hide, S A; Gibb, A G F; Gyi, D E; Pavitt, T; Atkinson, S; Duff, A R

    2005-07-01

    This overview paper draws together findings from previous focus group research and studies of 100 individual construction accidents. Pursuing issues raised by the focus groups, the accident studies collected qualitative information on the circumstances of each incident and the causal influences involved. Site based data collection entailed interviews with accident-involved personnel and their supervisor or manager, inspection of the accident location, and review of appropriate documentation. Relevant issues from the site investigations were then followed up with off-site stakeholders, including designers, manufacturers and suppliers. Levels of involvement of key factors in the accidents were: problems arising from workers or the work team (70% of accidents), workplace issues (49%), shortcomings with equipment (including PPE) (56%), problems with suitability and condition of materials (27%), and deficiencies with risk management (84%). Employing an ergonomics systems approach, a model is proposed, indicating the manner in which originating managerial, design and cultural factors shape the circumstances found in the work place, giving rise to the acts and conditions which, in turn, lead to accidents. It is argued that attention to the originating influences will be necessary for sustained improvement in construction safety to be achieved.

  10. Strategy generation in accident management support

    International Nuclear Information System (INIS)

    Sirola, M.

    1995-01-01

    An increased interest for research in the field of Accident Management can be noted. Several international programmes have been started in order to be able to understand the basic physical and chemical phenomena in accident conditions. A feasibility study has shown that it would be possible to design and develop a computerized support system for plant staff in accident situations. To achieve this goal the Halden Project has initiated a research programme on Computerized Accident Management Support (CAMS project). The aim is to utilize the capabilities of computerized tools to support the plant staff during the various accident stages. The system will include identification of the accident state, assessment of the future development of the accident and planning of accident mitigation strategies. A prototype is developed to support operators and the Technical Support Centre in decision making during serious accident in nuclear power plants. A rule based system has been built to take care of the strategy generation. This system assists plant personnel in planning control proposals and mitigation strategies from normal operation to severe accident conditions. The ideal of a safety objective tree and knowledge from the emergency procedures have been used. Future prediction requires good state identification of the plant status and some knowledge about the history of some critical variables. The information needs to be validated as well. Accurate calculations in simulators and a large database including all important information form the plant will help the strategy planning. (author). 12 refs, 2 figs

  11. Modelling the chemical behaviour of tellurium species in the reactor pressure vessel and the reactor cooling system under severe accident conditions

    International Nuclear Information System (INIS)

    Alonso, A.; Gonzalez, C.

    1991-07-01

    This state of the art report contains information on the behaviour of tellurium and its compounds in the reactor pressure vessel and the reactor coolant system under light water reactor severe accident conditions. To characterise tellurium behaviour, it is necessary the previous knowledge of the species of tellurium released from the core, and simultaneity of its release with that of other materials which can alter the transport, for instance, control rod and structural materials. Release and transport experiments have been reviewed along with the models implemented in the codes which are used in the international community: TRAPMELT, RAFT, VICTORIA and SOPHIE. From the experiments, it can be concluded that other species different to Te 2 , such as tin telluride and cesium telluride, may be released from the fuel. That is why they must be considered in the transport phenomena. There is also experimental evidence of the strong interaction of Te 2 with Inconel 600 and stainless steel of the pipe walls and structures, however this strong interaction is in competition with the interaction of tellurium with aerosols, which under severe accident conditions may represent an area greater than that of the primary system. It is for the absence of significant tellurium species in the transport models, and also for the interaction of tellurium with aerosols, for which some codes show the greatest deficiencies

  12. Development of a deformation and failure model for Zircaloy at high temperatures for light water reactor loss-of-coolant-accident investigations

    International Nuclear Information System (INIS)

    Raff, S.

    1982-11-01

    To describe Zircaloy-4 deformation and failure behaviour at high temperatures (600 to 1400 0 C), the phenomenological model NORA was developed and verified against numerous experimental results. The model can be applied to the calculation of fuel rod cladding deformation during small and large break loss-of-coolant-accidents. (orig./RW) [de

  13. Chemical diversity in opisthobranch molluscs from scarcely investigated Indo-Pacific areas

    Digital Repository Service at National Institute of Oceanography (India)

    Wahidullah, S.; Guo, Y.-W.; Fakhr, I.M.I.; Mollo, E.

    on Nudibranchs Nudibranchs are exclusively carnivorous with a broad range of alimentary habits. They appear to have the ability to sequester, accumulate and modify dietary metabolites as well as to synthesize defensive compounds de novo (Cimino and Ghiselin... of the chemical data reviewed in this chapter, taking into account alimentary habits and geographical chemical variations, suggests some interesting generalizations. 8.6.1 Nudibranchs The intra-specific geographic variations observed in the chemical...

  14. Scaling and design analyses of a scaled-down, high-temperature test facility for experimental investigation of the initial stages of a VHTR air-ingress accident

    International Nuclear Information System (INIS)

    Arcilesi, David J.; Ham, Tae Kyu; Kim, In Hun; Sun, Xiaodong; Christensen, Richard N.; Oh, Chang H.

    2015-01-01

    Highlights: • A 1/8th geometric-scale test facility that models the VHTR hot plenum is proposed. • Geometric scaling analysis is introduced for VHTR to analyze air-ingress accident. • Design calculations are performed to show that accident phenomenology is preserved. • Some analyses include time scale, hydraulic similarity and power scaling analysis. • Test facility has been constructed and shake-down tests are currently being carried out. - Abstract: A critical event in the safety analysis of the very high-temperature gas-cooled reactor (VHTR) is an air-ingress accident. This accident is initiated, in its worst case scenario, by a double-ended guillotine break of the coaxial cross vessel, which leads to a rapid reactor vessel depressurization. In a VHTR, the reactor vessel is located within a reactor cavity that is filled with air during normal operating conditions. Following the vessel depressurization, the dominant mode of ingress of an air–helium mixture into the reactor vessel will either be molecular diffusion or density-driven stratified flow. The mode of ingress is hypothesized to depend largely on the break conditions of the cross vessel. Since the time scales of these two ingress phenomena differ by orders of magnitude, it is imperative to understand under which conditions each of these mechanisms will dominate in the air ingress process. Computer models have been developed to analyze this type of accident scenario. There are, however, limited experimental data available to understand the phenomenology of the air-ingress accident and to validate these models. Therefore, there is a need to design and construct a scaled-down experimental test facility to simulate the air-ingress accident scenarios and to collect experimental data. The current paper focuses on the analyses performed for the design and operation of a 1/8th geometric scale (by height and diameter), high-temperature test facility. A geometric scaling analysis for the VHTR, a time

  15. Chemical Investigations of ISOL target units for carbon and nitrogen beams

    CERN Document Server

    Franberg, H; Gäggeler, H W; Köster, U

    2006-01-01

    Radioactive Ion Beams (RIB) are of significant interest in a number of applications. ISOL (Isotope Separation On Line) facilities provide RIB with high beam intensities and good beam quality. An atom that is produced within the ISOL target will first diffuse out from the target material. During the effusion towards the transfer line and into the ion source the many contacts with the surrounding surfaces may cause unacceptable delays in the transport and, hence, losses of the shorter-lived isotopes. We performed systematic chemical investigations of adsorption in a temperature and concentration regime relevant for ISOL targets and ion source units, with regard to COx and NOx on Al2O3 and SiO2. These materials are potential construction materials for the above mentioned areas. Off-line and on-line tests have been performed using a gas thermo-chromatography set-up with radioactive tracers. The experiments were performed at the PROTRAC facility at Paul Scherrer Institute in Villigen, Switzerland.

  16. Properties of screen printed electrocardiography smartware electrodes investigated in an electro-chemical cell.

    Science.gov (United States)

    Rattfält, Linda; Björefors, Fredrik; Nilsson, David; Wang, Xin; Norberg, Petronella; Ask, Per

    2013-07-05

    ECG (Electrocardiogram) measurements in home health care demands new sensor solutions. In this study, six different configurations of screen printed conductive ink electrodes have been evaluated with respect to electrode potential variations and electrode impedance. The electrode surfaces consisted of a Ag/AgCl-based ink with a conduction line of carbon or Ag-based ink underneath. On top, a lacquer layer was used to define the electrode area and to cover the conduction lines. Measurements were performed under well-defined electro-chemical conditions in a physiologic saline solution. The results showed that all printed electrodes were stable and have a very small potential drift (less than 3 mV/30 min). The contribution to the total impedance was 2% of the set maximal allowed impedance (maximally 1 kΩ at 50 Hz), assuming common values of input impedance and common mode rejection ratio of a regular amplifier. Our conclusions are that the tested electrodes show satisfying properties to be used as elements in a skin electrode design that could be suitable for further investigations by applying the electrodes on the skin.

  17. Chemical elemental distribution and soil DNA fingerprints provide the critical evidence in murder case investigation.

    Directory of Open Access Journals (Sweden)

    Giuseppe Concheri

    Full Text Available BACKGROUND: The scientific contribution to the solution of crime cases, or throughout the consequent forensic trials, is a crucial aspect of the justice system. The possibility to extract meaningful information from trace amounts of samples, and to match and validate evidences with robust and unambiguous statistical tests, are the key points of such process. The present report is the authorized disclosure of an investigation, carried out by Attorney General appointment, on a murder case in northern Italy, which yielded the critical supporting evidence for the judicial trial. METHODOLOGY/PRINCIPAL FINDINGS: The proportional distribution of 54 chemical elements and the bacterial community DNA fingerprints were used as signature markers to prove the similarity of two soil samples. The first soil was collected on the crime scene, along a corn field, while the second was found in trace amounts on the carpet of a car impounded from the main suspect in a distant location. The matching similarity of the two soils was proven by crossing the results of two independent techniques: a elemental analysis via inductively coupled plasma mass spectrometry (ICP-MS and optical emission spectrometry (ICP-OES approaches, and b amplified ribosomal DNA restriction analysis by gel electrophoresis (ARDRA. CONCLUSIONS: Besides introducing the novel application of these methods to forensic disciplines, the highly accurate level of resolution observed, opens new possibilities also in the fields of soil typing and tracking, historical analyses, geochemical surveys and global land mapping.

  18. Investigation on the relation between pressure drops and fluid chemical treatment

    International Nuclear Information System (INIS)

    Brun, C.; Engler, N.; Berthollon, G.; Muller, T.; Sala, B.; Combrade, P.; Turluer, G.

    2002-01-01

    Variations of primary coolant flow rate were sometimes observed on some plants some years ago. These variations come from variations of pressure drops in the various zones of the primary system. After many investigations, these changes were attributed to variations of physical and chemical conditions. One specific difficulty was to explain the level of head loss variations with the low amount of oxide present in a primary circuit. Another one was to account for the formation of deposits under high water velocity conditions. Therefore, Framatome-ANP launched laboratory tests to reproduce the observed head loss variations, identify the conditions of their occurrence and try to identify the root mechanisms. A small loop - called EMILIE - was implemented in the laboratories of the Technical Centre of Framatome-ANP in Le Creusot. It allows us to study the effect of the water chemistry and velocity, as well as the nature of the circuit surfaces on the occurrence of head loss variations and their relation with the amount, nature and morphology of oxide deposits. This paper summarizes the first results obtained and briefly discusses a possible mechanism. (authors)

  19. Investigation of the nucleation process of chemical vapour deposited diamond films

    International Nuclear Information System (INIS)

    Katai, S.

    2001-01-01

    The primary aim of this work was to contribute to the understanding of the bias enhanced nucleation (BEN) process during the chemical vapour deposition (CVD) of diamond on silicon. The investigation of both the gas phase environment above the substrate surface, by in situ mass selective energy analysis of ions, and of the surface composition and structure by in vacuo surface analytic methods (XPS, EELS) have been carried out. In both cases, the implementation of these measurements required the development and construction of special experimental apparatus as well. The secondary aim of this work was to give orientation to our long term goal of growing diamond films with improved quality. For this reason, (1) contaminant levels at the diamond-silicon interface after growth were studied by SIMS, (2) the internal stress distribution of highly oriented free-standing diamond films were studied by Raman spectroscopy, and (3) an attempt was made to produce spatially regular oriented nuclei formation by nucleating on a pattern created by laser treatment on silicon substrates. (orig.)

  20. Design of a high-pressure single pulse shock tube for chemical kinetic investigations

    International Nuclear Information System (INIS)

    Tranter, R. S.; Brezinsky, K.; Fulle, D.

    2001-01-01

    A single pulse shock tube has been designed and constructed in order to achieve extremely high pressures and temperatures to facilitate gas-phase chemical kinetic experiments. Postshock pressures of greater than 1000 atmospheres have been obtained. Temperatures greater than 1400 K have been achieved and, in principle, temperatures greater than 2000 K are easily attainable. These high temperatures and pressures permit the investigation of hydrocarbon species pyrolysis and oxidation reactions. Since these reactions occur on the time scale of 0.5--2 ms the shock tube has been constructed with an adjustable length driven section that permits variation of reaction viewing times. For any given reaction viewing time, samples can be withdrawn through a specially constructed automated sampling apparatus for subsequent species analysis with gas chromatography and mass spectrometry. The details of the design and construction that have permitted the successful generation of very high-pressure shocks in this unique apparatus are described. Additional information is provided concerning the diaphragms used in the high-pressure shock tube

  1. Comparative investigation of smooth polycrystalline diamond films on dental burs by chemical vapor deposition

    Science.gov (United States)

    Sein, Htet; Ahmed, Waqar; Rego, Christopher; Jackson, Mark; Polini, Riccardo

    2006-04-01

    Depositions of hot filament chemical vapor-deposited diamond on cobalt-cemented tungsten carbide (WC-Co) rotary cutting dental burs are presented. Conventional dental tools made of sintered polycrystalline diamond have a number of problems associated with the heterogeneity of the crystallite, decreased cutting efficiency, and short life. A preferential (111) faceted diamond was obtained after 15 h of deposition at a growth rate of 1.1 µm/h. Diamond-coated WC-Co dental burs and conventional sintered burs are mainly used in turning, milling, and drilling operations for machining metal ceramic hard alloys such as CoCr, composite teeth, and aluminum alloy in the dental laboratory. The influence of structure, the mechanical characteristics of both diamond grains and hard alloys on the wear behavior, as well as the regimen of grinding on diamond wear are considered. Erosion wear properties are also investigated under air-sand erosion testing. After machining with excessive cutting performance, calculations can be made on flank and crater wear areas. Diamond-coated WC-Co dental burs offered significantly better erosion and wear resistance compared with uncoated WC-Co tools and sintered burs.

  2. Biochemical and chemical investigations of pikeperch fingerlings (Sander Lucioperca L. after wintering

    Directory of Open Access Journals (Sweden)

    A. Ivanova

    2016-12-01

    Full Text Available Abstract. The purpose of the present studywas to investigate some basic biochemical and chemical parameters of pikeperch (Sander lucioperca L. yearlings reared in ponds after wintering. The investigation has been carried out in the Institute of Fisheries and Aquaculture, Plovdiv. The fish included in the study were randomly selected from one pond, with area of 0.40 ha. Blood samples were collected from 10 pikeperches with average weight from 80 to 100 g. Blood biochemical parameters were individually analysed. For hemoglobin determination, blood was anticoagulated with sodium citrate. Samples for body tissue о analysis (without the head and viscera were collected from 4 fish, autoclaved and used for analysis of water content, % (drying at 105 С, 24 h; Bulgarian State Standard – SR ISO 5984, protein content, % (Kjeldahl method, Bulgarian State Standard – SR ISO 5983 semi-automated DK 6 digester unit and UDK 132 o distillation system, Velp Scientifica, fats (% by the method of Smidt-Boudzynski Ratzlaff and ash (% by burning in a muffle furnace at 550 С, BSS – SR ISO -1 -1 -1 6496. The average blood serum total protein was 66.1±0.12 g.l , blood glucose concentration was 92.8±3.42 mg.100 ml (5.15 mmol.l and average -1 hemoglobin content was 44.7±0.33 g.l . The average protein content in analysed fish samples was 16.65±0.23 %. Protein content was the highest among studied dry matter components, followed by the ash (1.97±0.06 % and fat content (0.84±0.03 %. The levels of blood serum total protein, blood glucose and hemoglobin content as well as body composition parameters - water, protein, fat and ash of pikeperch fingerlings (Sander lucioperca L. after wintering reflect the specific equilibrium of plastic and energy substances after the winter period, with no deviations from the reference ranges.

  3. Investigation of the potential influence of production treatment chemicals on produced water toxicity

    International Nuclear Information System (INIS)

    Stine, E.R.; Gala, W.R.; Henry, L.R.

    1993-01-01

    Production treatment chemicals represent a diverse collection of chemical classes, added at various points from the wellhead to the final flotation cell, to prevent operational upsets and enhance the separation of oil from water. Information in the literature indicates that while many treatment chemicals are thought to partition into oil and not into the produced water, there are cases where a sufficiently water soluble treatment chemical is added at high enough concentrations to suggest that the treatment chemical may add to the aquatic toxicity of the produced water. A study was conducted to evaluate the potential effect of production treatment chemicals on the toxicity of produced waters using the US EPA Seven-day Mysidopsis bahia Survival, Growth and Fecundity Test. Samples of produced water were collected and tested for toxicity from three platforms under normal operating conditions, followed by repeated sampling and testing after a 72-hour period in which treatment chemical usage was discontinued, to the degree possible. Significant reductions in produced water toxicity were observed for two of the three platforms tested following either cessation of treatment chemical usage, or by comparing the toxicity of samples collected upstream and downstream of the point of treatment chemical addition

  4. Mass Spectrometric Determination of Chemical Warfare Agents in Indoor Sample Media Typically Collected During Forensic Investigations

    National Research Council Canada - National Science Library

    D'Agostino, P. A; Hancock, J. R; Chenier, C. L

    2005-01-01

    .... DRDC Suffield, in collaboration with the Royal Canadian Mounted Police, identified a need for analytical methods for chemical warfare agent identification in media, including flooring, wall surfaces...

  5. Surface analytical investigations of the release behaviour of volatile fission products during simulated core meltdown accidents and of the reaction behaviour of iodine with silver surfaces

    International Nuclear Information System (INIS)

    Moers, H.

    1986-07-01

    The report presents the results of the analysis of aerosol particles formed in simulated laboratory scale core meltdown experiments. In addition the interaction of silver surfaces with gaseous molecular iodine and with iodide and molecular iodine in aqueous solution was investigated. The composition of the aerosol samples and the progress of the reactions mentioned were determined by use of surface analytical techniques (X-ray photoelectron spectroscopy, Auger electron spectroscopy, secondary ion mass spectroscopy). The major information can be evaluated from X-ray photoelectron spectra which exhibit chemical shifts of the photoelectron lines which allowing a discrimination between different chemical species of the same element. The analyses showed that iodine is present in the aerosol particles mainly as caesium iodide and, to a smaller fraction, as silver iodide. During the adsorption of gaseous molecular iodine at metallic silver surfaces a closed silver iodide overlayer is formed. In aqueous iodide solutions one observes chemisorption of the iodide anions up to a coverage of the metallic silver surface of about half a monolayer. Molecular iodine in aqueous solution is completely converted to silver iodide which covers the substrate irregularly. (orig./HP) [de

  6. Predicted occurrence rate of severe transportation accidents involving large casks

    International Nuclear Information System (INIS)

    Dennis, A.W.

    1978-01-01

    A summary of the results of an investigation of the severities of highway and railroad accidents as they relate to the shipment of large radioactive materials casks is discussed. The accident environments considered are fire, impact, crash, immersion, and puncture. For each of these environments, the accident severities and their predicted frequencies of occurrence are presented. These accident environments are presented in tabular and graphic form to allow the reader to evaluate the probabilities of occurrence of the accident parameter severities he selects

  7. Preventing marine accidents caused by technology-induced human error

    OpenAIRE

    Bielić, Toni; Hasanspahić, Nermin; Čulin, Jelena

    2017-01-01

    The objective of embedding technology on board ships, to improve safety, is not fully accomplished. The paper studies marine accidents caused by human error resulting from improper human-technology interaction. The aim of the paper is to propose measures to prevent reoccurrence of such accidents. This study analyses the marine accident reports issued by Marine Accidents Investigation Branch covering the period from 2012 to 2014. The factors that caused these accidents are examined and categor...

  8. Experimental investigation of void distribution in Suppression Pool during the initial blowdown period of a Loss of Coolant Accident using air–water two-phase mixture

    International Nuclear Information System (INIS)

    Rassame, Somboon; Griffiths, Matthew; Yang, Jun; Lee, Doo Yong; Ju, Peng; Choi, Sung Won; Hibiki, Takashi; Ishii, Mamoru

    2014-01-01

    Highlights: • Basic understanding of the venting phenomena in the SP during a LOCA was obtained. • A series of experiment is carried out using the PUMA-E test facility. • Two phases of experiments, namely, an initial and a quasi-steady phase were observed. • The maximum void penetration depth was experienced during the initial phase. - Abstract: During the initial blowdown period of a Loss of Coolant Accident (LOCA), the non-condensable gas initially contained in the BWR containment is discharged to the pressure suppression chamber through the blowdown pipes. The performance of Emergency Core Cooling System (ECCS) can be degraded due to the released gas ingestion into the suction intakes of the ECCS pumps. The understanding of the relevant phenomena in the pressure suppression chamber is important in analyzing potential gas intrusion into the suction intakes of ECCS pumps. To obtain the basic understanding of the relevant phenomena and the generic data of void distribution in the pressure suppression chamber during the initial blowdown period of a LOCA, tests with various blowdown conditions were conducted using the existing Suppression Pool (SP) tank of the integral test facility, called Purdue University Multi-Dimensional Integral Test Assembly for ESBWR applications (PUMA-E) facility, a scaled downcomer pipe installed in the PUMA-E SP, and air discharge pipe system. Two different diameter sizes of air injection pipe (0.076 and 0.102 m), a range of air volumetric flux (7.9–24.7 m/s), initial void conditions in an air injection pipe (fully void, partially void, and fully filled with water) and different air velocity ramp rates (1.0, 1.5, and 2.0 s) are used to investigate the impact of the blowdown conditions to the void distribution in the SP. Two distinct phases of experiments, namely, an initial and a quasi-steady phase were observed. The maximum void penetration depth was experienced during the initial phase. The quasi-steady phase provided less void

  9. Termination of light-water reactor core-melt accidents with a chemical core catcher: the core-melt source reduction system (COMSORS)

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Parker, G.W.; Rudolph, J.C.; Osborne-Lee, I.W.; Kenton, M.A.

    1996-09-01

    The Core-Melt Source Reduction System (COMSORS) is a new approach to terminate light-water reactor core melt accidents and ensure containment integrity. A special dissolution glass is placed under the reactor vessel. If core debris is released onto the glass, the glass melts and the debris dissolves into the molten glass, thus creating a homogeneous molten glass. The molten glass, with dissolved core debris, spreads into a wide pool, distributing the heat for removal by radiation to the reactor cavity above or by transfer to water on top of the molten glass. Expected equilibrium glass temperatures are approximately 600 degrees C. The creation of a low-temperature, homogeneous molten glass with known geometry permits cooling of the glass without threatening containment integrity. This report describes the technology, initial experiments to measure key glass properties, and modeling of COMSORS operations

  10. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    International Nuclear Information System (INIS)

    Roake, W.E.; Adamson, M.G.; Hilbert, R.F.; Langer, S.

    1977-01-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to ∼60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  11. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    Energy Technology Data Exchange (ETDEWEB)

    Roake, W E [Westinghouse-Hanford Co., Richland, WA (United States); Adamson, M G [General Electric Company, Vallecitos Nuclear Center, Pleasanton, CA (United States); Hilbert, R F; Langer, S

    1977-04-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to {approx}60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  12. Accident Precursor Analysis and Management: Reducing Technological Risk Through Diligence

    Science.gov (United States)

    Phimister, James R. (Editor); Bier, Vicki M. (Editor); Kunreuther, Howard C. (Editor)

    2004-01-01

    Almost every year there is at least one technological disaster that highlights the challenge of managing technological risk. On February 1, 2003, the space shuttle Columbia and her crew were lost during reentry into the atmosphere. In the summer of 2003, there was a blackout that left millions of people in the northeast United States without electricity. Forensic analyses, congressional hearings, investigations by scientific boards and panels, and journalistic and academic research have yielded a wealth of information about the events that led up to each disaster, and questions have arisen. Why were the events that led to the accident not recognized as harbingers? Why were risk-reducing steps not taken? This line of questioning is based on the assumption that signals before an accident can and should be recognized. To examine the validity of this assumption, the National Academy of Engineering (NAE) undertook the Accident Precursors Project in February 2003. The project was overseen by a committee of experts from the safety and risk-sciences communities. Rather than examining a single accident or incident, the committee decided to investigate how different organizations anticipate and assess the likelihood of accidents from accident precursors. The project culminated in a workshop held in Washington, D.C., in July 2003. This report includes the papers presented at the workshop, as well as findings and recommendations based on the workshop results and committee discussions. The papers describe precursor strategies in aviation, the chemical industry, health care, nuclear power and security operations. In addition to current practices, they also address some areas for future research.

  13. Non-empirical analysis of the chemical reaction of cesium with steam; Cs+H{sub 2}O {yields} CsOH+H, in severe light water reactor accidents

    Energy Technology Data Exchange (ETDEWEB)

    Inada, Yasuzi [Fuji Research Inst. Corp., Tokyo (Japan). Computational Engineering Div.

    1998-04-01

    The elementary chemical reaction of cesium which is a volatile fission product with steam (water) shown in the title are analyzed from the first principle. The activation energies for both reactions of the forward and the backward are calculated for the first time with a computer program Gamess, which is based on the non-empirical molecular orbital theory. The calculated values are expected to agree with those of experiments within an accuracy of several tens of kJ/mol. Using the values obtained above, the rate constants are also calculated in the framework of the transition state theory. The derived rate constants will allow us to predict the orders of magnitude of experimental values under high temperature conditions (1,000 K or higher). Thus these rate constants are available as input data for the kinetic (non-equilibrium state) study of cesium in severe light water reactor accidents. (author)

  14. The handling of radiation accidents

    International Nuclear Information System (INIS)

    1977-01-01

    The symposium was attended by 204 participants from 39 countries and 5 international organizations. Forty-two papers were presented in 8 sessions. The purpose of the meeting was to foster an exchange of experiences gained in establishing and exercising plans for mitigating the effects of radiation accidents and in the handling of actual accident situations. Only a small number of accidents were reported at the symposium, and this reflects the very high standards of safety that has been achieved by the nuclear industry. No accidents of radiological significance were reported to have occurred at commercial nuclear power plants. Of the accidents reported, industrial radiography continues to be the area in which most of the radiation accidents occur. The experience gained in the reported accident situations served to confirm the crucial importance of the prompt availability of medical and radiological services, particularly in the case of uptake of radioactive material, and emphasized the importance of detailed investigation into the causes of the accident in order to improve preventative measures. One of the principal themes of the symposium involved emergency procedures related to nuclear power plant accidents, and several papers defining the scope, progression and consequences of design base accidents for both thermal and fast reactor systems were presented. These were complemented by papers defining the resultant protection requirements that should be satisfied in the establishment of plans designed to mitigate the effects of the postulated accident situations. Several papers were presented describing existing emergency organizational arrangements relating both to specific nuclear power plants and to comprehensive national schemes, and a particularly informative session was devoted to the topic of training of personnel in the practical conduct of emergency arrangements. The general feeling of the participants was one of studied confidence in the competence and

  15. Determinants of injuries in passenger vessel accidents.

    Science.gov (United States)

    Yip, Tsz Leung; Jin, Di; Talley, Wayne K

    2015-09-01

    This paper investigates determinants of crew and passenger injuries in passenger vessel accidents. Crew and passenger injury equations are estimated for ferry, ocean cruise, and river cruise vessel accidents, utilizing detailed data of individual vessel accidents that were investigated by the U.S. Coast Guard during the time period 2001-2008. The estimation results provide empirical evidence (for the first time in the literature) that crew injuries are determinants of passenger injuries in passenger vessel accidents. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Theoretical and experimental investigations on the behaviour of iodine during severe accidents: organic iodide, iodine/silver reaction, iodine/iron reaction. Pt. 4: organic iodide. Final report

    International Nuclear Information System (INIS)

    Hellmann, S.; Greger, G.U.; Funke, F.; Bleier, A.; Zeeh, W.

    1995-11-01

    Analysis of the consequences of severe accidents in nuclear power plants requires knowledge of the behaviour of radionuclides relevant from the radiological viewpoint. The role played by radioiodine is particularly important. In the current modelling of iodine behaviour the heterogeneous formation of organic iodide is not adequately taken into consideration owing to a lack of data or insufficient accuracy of data. This project is intended to eliminate some gaps in critical areas. This final report, part 4, describes the tests carried out in the two relevant areas - heterogeneous formation of organic coatings in the gas phase (containment atmosphere) - heterogeneous formation of organic iodide at organic coatings in aqueous phase (containment sump). Moreover, modelling suggestions how to include the resulting knowledge in the iodine accident behaviour code IMPAIR are given. (orig.) [de

  17. Theoretical and experimental investigations into the filtration of the atmosphere within the containments of pressurized water reactors after serious reactor accidents

    International Nuclear Information System (INIS)

    Dillmann, H.G.; Pasler, H.

    1981-01-01

    For serious accidents in nuclear power stations equipped with pressurized water reactors and with boundary conditions assumed, a conservative evaluation was made of the condition of the atmosphere within the reactor containment, particularly referring to pressure, temperature, air humidity and activity release. Based on these data the loads were calculated of accident filter systems of different designs as a function of parameters such as the course of releases and the volume flow through the filter systems. A number of experimental results are indicated on the behaviour of iodine sorption materials under extreme conditions including the least favorable temperature, humidity and pressure derived from the calculations above. Reference is made to the targets of future R and D work on aerosol removal

  18. Speciation analysis of I-127,129 in the crop field soil contaminated by the Fukushima Dai-ichi nuclear power plant accident with newly developed chemical separation techniques

    Science.gov (United States)

    Honda, Maki; Matsuzaki, Hiroyuki; Saito, Takumi; Nagai, Hisao

    2014-05-01

    In previous study, we investigated the depth profile of the accident derived I-129 and downward migration speed in soils of near-field of Fukushima Dai-ichi Nuclear Power Plant, including crop fields and man-made fields. I-129 in soil was measured by AMS and stable iodine (I-127) was measured by ICP-MS at MALT (Micro Analysis Laboratory, Tandem accelerator), The University of Tokyo. It was found that I-129 was concentrated near surface but distributed deeper compared with Cs-137. It was also found that I-129 seems to move downward more quickly than Cs-137. To investigate the adsorption mechanism and the elemental process of migration of the accident derived I-129 in soil, it is important to know what kind of component the I-129 combines with. Recent studies on the X-ray absorption fine structure (XAFS), especially near edge structure (XANES), reported that the stable iodine (I-127) in soil existed as an organic component. However, it had not yet been proved that it was also the case with the accident derived I-129 because it had been incorporated in the soil system only recently and the abundance of I-129 in soil was more than 8 orders of magnitude smaller than sub-ppm level stable iodine (I-127). In this study a progressive sequential extraction method including the dialysis and the dynamic headspace method was newly developed to obtain only the iodine sticking to the soil organic component. The stable iodine can be quantified by direct analysis of the fraction and I-129 can be quantified by AMS method of the fraction added with carrier. The fraction of the organic component for I-127 and I-129 can be evaluated respectively by comparing with the other fraction and/or with the total concentration obtained by the bulk analysis (e.g. by the pyrohydrolysis).

  19. Accident information needs

    International Nuclear Information System (INIS)

    Hanson, D.J.; Arcieri, W.C.; Ward, L.W.

    1992-01-01

    A Five-step methodology has been developed to evaluate information needs for nuclear power plants under accident conditions and the availability of plant instrumentation during severe accidents. Step 1 examines the credible accidents and their relationships to plant safety functions. Step 2 determines the information personnel involved in accident management will need to understand plant behavior. Step 3 determines the capability of the instrumentation to function properly under severe accident conditions. Step 4 determines the conditions expected during the identified severe accidents. Step 5 compares the instrument capabilities and the severe accident conditions to evaluate the availability of the instrumentation to supply needed plant information

  20. Accident information needs

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, D.J.; Arcieri, W.C.; Ward, L.W.

    1992-12-31

    A Five-step methodology has been developed to evaluate information needs for nuclear power plants under accident conditions and the availability of plant instrumentation during severe accidents. Step 1 examines the credible accidents and their relationships to plant safety functions. Step 2 determines the information personnel involved in accident management will need to understand plant behavior. Step 3 determines the capability of the instrumentation to function properly under severe accident conditions. Step 4 determines the conditions expected during the identified severe accidents. Step 5 compares the instrument capabilities and the severe accident conditions to evaluate the availability of the instrumentation to supply needed plant information.