Phased charging and discharging in capacitive desalinatio

Science.gov (United States)

Stadermann, Michael; Qu, Yatian; Santiago, Juan G.; Hemmatifar, Ali

2017-09-12

A system combines complete, ultra-thin cells into a monolithic and robust framework necessary for desalination applications which yields orders of magnitude faster desalination. The electrode pairs are located so that a flow of feed water flows through or around the electrode pairs with the flow perpendicular to sequentially applied electric potentials. The system is controlled to charge the series of electrode pairs sequentially or phased. That means the charging of the second electrode pair is delayed with regard to the charging of the first electrode pair and the charging of a third electrode pair is delayed with respect to the charging of the second electrode pair.

Thermodynamic geometry and phase transitions of dyonic charged AdS black holes

Energy Technology Data Exchange (ETDEWEB)

Chaturvedi, Pankaj; Sengupta, Gautam [Indian Institute of Technology Kanpur, Department of Physics, Kanpur (India); Das, Anirban [Tata Institute of Fundamental Research, Department of Theoretical Physics, Mumbai (India)

2017-02-15

We investigate phase transitions and critical phenomena of four dimensional dyonic charged AdS black holes in the framework of thermodynamic geometry. In a mixed canonical-grand canonical ensemble with a fixed electric charge and varying magnetic charge these black holes exhibit a liquid-gas like first order phase transition culminating in a second order critical point similar to the van der Waals gas. We show that the thermodynamic scalar curvature R for these black holes follow our proposed geometrical characterization of the R-crossing Method for the first order liquid-gas like phase transition and exhibits a divergence at the second order critical point. The pattern of R crossing and divergence exactly corresponds to those of a van der Waals gas described by us in an earlier work. (orig.)

High-resolution x-ray scattering studies of charge ordering in highly correlated electron systems

International Nuclear Information System (INIS)

Ghazi, M.E.

2002-01-01

Many important properties of transition metal oxides such as, copper oxide high-temperature superconductivity and colossal magnetoresistance (CMR) in manganites are due to strong electron-electron interactions, and hence these systems are called highly correlated systems. These materials are characterised by the coexistence of different kinds of order, including charge, orbital, and magnetic moment. This thesis contains high-resolution X-ray scattering studies of charge ordering in such systems namely the high-T C copper oxides isostructural system, La 2-x Sr x NiO 4 with various Sr concentrations (x = 0.33 - 0.2), and the CMR manganite system, Nd 1/2 Sr 1/2 MnO 3 . It also includes a review of charge ordering in a large variety of transition metal oxides, such as ferrates, vanadates, cobaltates, nickelates, manganites, and cuprates systems, which have been reported to date in the scientific literature. Using high-resolution synchrotron X-ray scattering, it has been demonstrated that the charge stripes exist in a series of single crystals of La 2-x Sr x NiO 4 with Sr concentrations (x = 0.33 - 0.2) at low temperatures. Satellite reflections due to the charge ordering were found with the wavevector (2ε, 0, 1) below the charge ordering transition temperature, T CO , where 2ε is the amount of separation from the corresponding Bragg peak. The charge stripes are shown to be two-dimensional in nature both by measurements of their correlation lengths and by measurement of the critical exponents of the charge stripe melting transition with an anomaly at x = 0.25. The results show by decreasing the hole concentration from the x = 0.33 to 0.2, the well-correlated charge stripes change to a glassy state at x = 0.25. The electronic transition into the charge stripe phase is second-order without any corresponding structural transition. Above the second-order transition critical scattering was observed due to fluctuations into the charge stripe phase. In a single-crystal of Nd

Evidence of a splitting of the Mn-O distance and of a large lattice disorder in the charge-ordered phase of LiMn2O4 obtained by EXAFS

International Nuclear Information System (INIS)

Paolone, A.; Castellano, C.; Cantelli, R.; Rousse, G.; Masquelier, C.

2003-01-01

We measured the extended x-ray-absorption fine-structure (EXAFS) spectrum of LiMn 2 O 4 below room temperature in the charge-ordered phase and for comparison at room temperature in the cubic phase. By means of a standard fit procedure we verified that, as reported by neutron-scattering experiments, also at the local level there are two different Mn-O distances below room temperature, which correspond to the surroundings of well-defined Mn 3+ and Mn 4+ ions. This result is different from the ones obtained from previous EXAFS measurements and confirms the physical picture of the phase transition caused by the ordering of charges in contrast to a cooperative Jahn-Teller phenomenon. Moreover a large lattice disorder in the charge-ordered state, which determines a significant static contribution to the EXAFS Debye-Waller factor, has been found. This last result can be considered as the EXAFS spectral mark of charge-order transitions, even in those materials in which there is no clear evidence of the splitting of bond lengths

Charge modulation as fingerprints of phase-string triggered interference

Energy Technology Data Exchange (ETDEWEB)

Zhu, Zheng; Tian, Chushun; Jiang, Hong-Chen; Qi, Yang; Weng, Zheng-Yu; Zaanen, Jan

2015-07-07

Charge order appears to be an ubiquitous phenomenon in doped Mott insulators, which is currently under intense experimental and theoretical investigations particularly in the high T _c cuprates. This phenomenon is conventionally understood in terms of Hartree-Fock-type mean-field theory. Here we demonstrate a mechanism for charge modulation which is rooted in the many-particle quantum physics arising in the strong coupling limit. Specifically, we consider the problem of a single hole in a bipartite t - J ladder. As a remnant of the fermion signs, the hopping hole picks up subtle phases pending the fluctuating spins, the so-called phase-string effect. We demonstrate the presence of charge modulations in the density matrix renormalization group solutions which disappear when the phase strings are switched off. This form of charge modulation can be understood analytically in a path-integral language with a mean-field-like approximation adopted, showing that the phase strings give rise to constructive interferences leading to self-localization. When the latter occurs, left- and right-moving propagating modes emerge inside the localization volume and their interference is responsible for the real space charge modulation.

f-electron-nuclear hyperfine-coupled multiplets in the unconventional charge order phase of filled skutterudite PrRu4P12

International Nuclear Information System (INIS)

Aoki, Yuji; Namiki, Takahiro; Saha, Shanta R.; Sato, Hideyuki; Tayama, Takashi; Sakakibara, Toshiro; Shiina, Ryousuke; Shiba, Hiroyuki; Sugawara, Hitoshi

2011-01-01

The filled skutterudite PrRu 4 P 12 is known to undergo an unconventional charge order phase transition at 63 K, below which two sublattices with distinct f-electron crystalline-electric-field ground states are formed. In this paper, we study experimentally and theoretically the properties of the charge order phase at very low temperature, particularly focusing on the nature of the degenerate triplet ground state on one of the sublattices. First, we present experimental results of specific heat and magnetization measured with high quality single crystals. In spite of the absence of any symmetry breaking, the specific heat shows a peak structure at T p =0.30 K in zero field; it shifts to higher temperatures as the magnetic field is applied. In addition, the magnetization curve has a remarkable rounding below 1 T. Then, we study the origin of these experimental findings by considering the hyperfine interaction between 4f electron and nuclear spin. We demonstrate that the puzzling behaviors at low temperatures can be well accounted for by the formation of 4f-electron-nuclear hyperfine-coupled multiplets, the first thermodynamical observation of its kind. (author)

Devil's staircase of odd-number charge order modulations in divalent β -vanadium bronzes under pressure

Science.gov (United States)

Yamauchi, Touru; Ueda, Hiroaki; Ohwada, Kenji; Nakao, Hironori; Ueda, Yutaka

2018-03-01

A common characteristic of quasi-one-dimensional (q1D) conductors β -A0.33V2O5 (A = Li, Na, and Ag) is that the charge ordering (CO), the ground state (GS) at ambient pressure, and the superconducting (SC) phases, the GS under high pressure, are competing with each other. We have explored high-pressure properties of divalent β -vanadium bronzes, β -A0.33V2O5 (A = Ca, Sr, and Pb), which are A -cation stoichiometry finely controlled single-crystal/powder samples, and found the absence of the SC phase. In these observations, however, we observed enormous and novel phase transitions, a kind of "devil's staircase"-type phase transitions in the charge ordering (CO) phases. The most surprising discovery in this devil's staircase, which was found mainly in β -Sr0.33V2O5 , is that all the charge modulation vectors of many kinds of CO phases can be represented as a primitive lattice translation vector along the b axis multiplied by several odd numbers. This discovery surely demonstrates interplay between the charge degree freedom and the crystallographic symmetry. We propose two possible mechanisms to explain this phenomenon: "self-charge transfer (carrier redistribution)" between the two subsystems in these compounds and "sequential symmetry reduction" that was discussed in Landau theory of phase transitions. In β -Ca0.33V2O5 we also found a P -T phase diagram similar in outlook but different in detail. The devil's staircase was also observed but it is an incomplete one. Furthermore, the charge modulation vectors in it are shorter than those in β -Sr0.33V2O5 . In β -Pb0.33V2O5 , which has no CO phase at ambient pressure, the pressure-induced antiferromagnetic ordering was observed at around 50 K above 0.5 GPa. Using these two kinds of mechanisms, we also explain the global high-pressure properties in all the stoichiometric divalent β -vanadium bronzes, which were observed as a wide variety of electromagnetic states. In addition, we also discuss a possible key for

Local structural changes in paramagnetic and charge-ordered phases of Sm0.2Pr0.3Sr0.5MnO3: an EXAFS study

International Nuclear Information System (INIS)

Priolkar, K R; Kulkarni, Vishwajeet; Sarode, P R; Emura, S

2008-01-01

Sm 0.5-x Pr x Sr 0.5 MnO 3 exhibits a variety of ground states as x is varied from 0 to 0.5. At an intermediate doping of x = 0.3 a charge-ordered CE-type antiferromagnetic insulating (AFI) ground state is seen. The transition to this ground state is from a paramagnetic-insulating (PMI) phase through a ferromagnetic-metallic phase (FMM). Local structures in PMI and AFI phases of the x = 0.3 sample have been investigated using Pr K-edge and Sm K-edge extended x-ray absorption fine structure (EXAFS). It can be seen that the tilting and rotation of the MnO 6 octahedra about the b-axis are responsible for the charge-ordered CE-type antiferromagnetic ground state at low temperatures. In addition a shift in the position of the rare-earth ion along the c-axis has to be considered to account for observed distribution of bond distances around the rare-earth ion

High-order space charge effects using automatic differentiation

International Nuclear Information System (INIS)

Reusch, Michael F.; Bruhwiler, David L.

1997-01-01

The Northrop Grumman Topkark code has been upgraded to Fortran 90, making use of operator overloading, so the same code can be used to either track an array of particles or construct a Taylor map representation of the accelerator lattice. We review beam optics and beam dynamics simulations conducted with TOPKARK in the past and we present a new method for modeling space charge forces to high-order with automatic differentiation. This method generates an accurate, high-order, 6-D Taylor map of the phase space variable trajectories for a bunched, high-current beam. The spatial distribution is modeled as the product of a Taylor Series times a Gaussian. The variables in the argument of the Gaussian are normalized to the respective second moments of the distribution. This form allows for accurate representation of a wide range of realistic distributions, including any asymmetries, and allows for rapid calculation of the space charge fields with free space boundary conditions. An example problem is presented to illustrate our approach

Charge-Orbital Ordering and Verwey Transition in Magnetite Measured by Resonant Soft X-Ray Scattering

International Nuclear Information System (INIS)

Huang, D.J.; Lin, H.-J.; Okamoto, J.; Hsu, C.-H.; Huang, C.-M.; Yang, C.S.; Chao, K.S.; Wu, W.B.; Jeng, H.-T.; Guo, G.Y.; Ling, D.C.; Chen, C.T.

2006-01-01

We report experimental evidence for the charge-orbital ordering in magnetite below the Verwey transition temperature T V . Measurements of O K-edge resonant x-ray scattering on magnetite reveal that the O 2p states in the vicinity of the Fermi level exhibit a charge-orbital ordering along the c axis with a spatial periodicity of the doubled lattice parameter of the undistorted cubic phase. Such a charge-orbital ordering vanishes abruptly above T V and exhibits a thermal hysteresis, correlating closely with the Verwey transition in magnetite

Holographic Van der Waals phase transition of the higher-dimensional electrically charged hairy black hole

International Nuclear Information System (INIS)

Li, Hui-Ling; Feng, Zhong-Wen; Zu, Xiao-Tao

2018-01-01

With motivation by holography, employing black hole entropy, two-point connection function and entanglement entropy, we show that, for the higher-dimensional Anti-de Sitter charged hairy black hole in the fixed charged ensemble, a Van der Waals-like phase transition can be observed. Furthermore, based on the Maxwell equal-area construction, we check numerically the equal-area law for a first order phase transition in order to further characterize the Van der Waals-like phase transition. (orig.)

Holographic Van der Waals phase transition of the higher-dimensional electrically charged hairy black hole

Energy Technology Data Exchange (ETDEWEB)

Li, Hui-Ling [University of Electronic Science and Technology of China, School of Physical Electronics, Chengdu (China); Shenyang Normal University, College of Physics Science and Technology, Shenyang (China); Feng, Zhong-Wen [China West Normal University, College of Physics and Space Science, Nanchong (China); Zu, Xiao-Tao [University of Electronic Science and Technology of China, School of Physical Electronics, Chengdu (China)

2018-01-15

With motivation by holography, employing black hole entropy, two-point connection function and entanglement entropy, we show that, for the higher-dimensional Anti-de Sitter charged hairy black hole in the fixed charged ensemble, a Van der Waals-like phase transition can be observed. Furthermore, based on the Maxwell equal-area construction, we check numerically the equal-area law for a first order phase transition in order to further characterize the Van der Waals-like phase transition. (orig.)

High-order space charge effects using automatic differentiation

International Nuclear Information System (INIS)

Reusch, M.F.; Bruhwiler, D.L.; Computer Accelerator Physics Conference Williamsburg, Virginia 1996)

1997-01-01

The Northrop Grumman Topkark code has been upgraded to Fortran 90, making use of operator overloading, so the same code can be used to either track an array of particles or construct a Taylor map representation of the accelerator lattice. We review beam optics and beam dynamics simulations conducted with TOPKARK in the past and we present a new method for modeling space charge forces to high-order with automatic differentiation. This method generates an accurate, high-order, 6-D Taylor map of the phase space variable trajectories for a bunched, high-current beam. The spatial distribution is modeled as the product of a Taylor Series times a Gaussian. The variables in the argument of the Gaussian are normalized to the respective second moments of the distribution. This form allows for accurate representation of a wide range of realistic distributions, including any asymmetries, and allows for rapid calculation of the space charge fields with free space boundary conditions. An example problem is presented to illustrate our approach. copyright 1997 American Institute of Physics

First principle calculations of charge ordering in manganites

International Nuclear Information System (INIS)

Baldomir, D.; Pardo, V.; Castro, J.; Iglesias, M.; Arias, J.E.; Rivas, J.

2007-01-01

Electronic structure calculations were performed on the compound La 0.5 Ca 0.5 MnO 3 to study the relationship between the magnetic ordering, the charge ordering and the geometry of the compound. Charge ordering is intimately related to the magnetic ordering. An antiferromagnetic ordering induces charge disproportionation via a Jahn-Teller distortion. A full disproportionation in Mn 3+ /Mn 4+ occurs for the experimental geometry and allows to predict the experimentally found antiferromagnetic insulating state

Formal Valence, 3 d Occupation, and Charge Ordering Transitions

Science.gov (United States)

Pickett, Warren

2014-03-01

The metal-insulator transition (MIT), discovered by Verwey in the late 1930s, has been thought to be one of the best understood of MITs, the other ones being named after Wigner, Peierls, Mott, and Anderson. Continuing work on these transitions finds in some cases less and less charge to order, raising the fundamental question of just where the entropy is coming from, and just what is ordering. To provide insight into the mechanism of charge-ordering transitions, which conventionally are pictured as a disproportionation, I will (1) review and reconsider the charge state (or oxidation number) picture itself, (2) introduce new theoretical results for the rare earth nickelates (viz. YNiO3), the putative charge ordering compound AgNiO2, and the dual charge state insulator AgO, and (3) analyze cationic occupations of actual (not formal) charge, and work to reconcile the conundrums that arise. Several of the clearest cases of charge ordering transitions involve no disproportion; moreover, the experimental data used to support charge ordering can be accounted for within density functional based calculations that contain no charge transfer The challenge of modeling charge ordering transitions with model Hamiltonians will be discussed. Acknowledgment: Y. Quan, V. Pardo. Supported by NSF award DMR-1207622-0.

Semimetallic and charge-ordered α -(BEDT-TTF)2I3: On the role of disorder in dc transport and dielectric properties

Science.gov (United States)

Ivek, Tomislav; Čulo, Matija; Kuveždić, Marko; Tutiš, Eduard; Basletić, Mario; Mihaljević, Branimir; Tafra, Emil; Tomić, Silvia; Löhle, Anja; Dressel, Martin; Schweitzer, Dieter; Korin-Hamzić, Bojana

2017-08-01

α -(BEDT-TTF)2I3 is a prominent example of charge ordering among organic conductors. In this work, we explore the details of transport within the charge-ordered as well as semimetallic phase at ambient pressure. In the high-temperature semimetallic phase, the mobilities and concentrations of both electrons and holes conspire in such a way to create an almost temperature-independent conductivity as well as a low Hall effect. We explain these phenomena as a consequence of a predominantly interpocket scattering which equalizes mobilities of the two types of charge carriers. At low temperatures, within the insulating charge-ordered phase two channels of conduction can be discerned: a temperature-dependent activation, which follows the mean-field behavior, and a nearest-neighbor-hopping contribution. Together with negative magnetoresistance, the latter relies on the presence of disorder. The charge-ordered phase also features a prominent dielectric peak which bears a similarity to relaxor ferroelectrics. Its dispersion is determined by free-electron screening and pushed by disorder well below the transition temperature. The source of this disorder can be found in the anion layers which randomly perturb BEDT-TTF molecules through hydrogen bonds.

Charge ordering transition in GdBaCo2O5: Evidence of reentrant behavior

Science.gov (United States)

Allieta, M.; Scavini, M.; Lo Presti, L.; Coduri, M.; Loconte, L.; Cappelli, S.; Oliva, C.; Ghigna, P.; Pattison, P.; Scagnoli, V.

2013-12-01

We present a detailed study on the charge ordering transition in a GdBaCo2O5.0 system by combining high-resolution synchrotron powder/single-crystal diffraction with electron paramagnetic resonance experiments as a function of temperature. We found a second-order structural phase transition at TCO = 247 K (Pmmm to Pmma) associated with the onset of long-range charge ordering. At Tmin ≈ 1.2TCO, the electron paramagnetic resonance linewidth rapidly broadens, providing evidence of antiferromagnetic spin fluctuations. This likely indicates that, analogously to manganites, the long-range antiferromagnetic order in GdBaCo2O5.0 sets in at ≈TCO. Pair distribution function analysis of diffraction data revealed signatures of structural inhomogeneities at low temperature. By comparing the average and local bond valences, we found that above TCO the local structure is consistent with a fully random occupation of Co2+ and Co3+ in a 1:1 ratio and with a complete charge ordering below TCO. Below T ≈ 100 K the charge localization is partially melted at the local scale, suggesting a reentrant behavior of charge ordering. This result is supported by the weakening of superstructure reflections and the temperature evolution of electron paramagnetic resonance linewidth that is consistent with paramagnetic reentrant behavior reported in the GdBaCo2O5.5 parent compound.

Pressure-induced charge ordering of LiV2O4

International Nuclear Information System (INIS)

Takeda, K.; Hidaka, H.; Kotegawa, H.; Kobayashi, T.C.; Shimizu, K.; Harima, H.; Fujiwara, K.; Miyoshi, K.; Takeuchi, J.; Ohishi, Y.; Adachi, T.; Takata, M.; Nishibori, E.; Sakata, M.; Watanuki, T.; Shimomura, O.

2005-01-01

The powder X-ray diffraction experiments of LiV 2 O 4 have been performed at low temperature and high pressure using synchrotron radiation. In the isothermal experiment at 10K, the cubic-rhombohedral phase transition corresponding to the metal-insulator transition is found at around 13GPa. This transition seems to be due to charge ordering of V ions on the analogy of the metal-insulator transition in AlV 2 O 4

Phase separation in strongly correlated electron systems with two types of charge carriers

International Nuclear Information System (INIS)

Kugel, K.I.; Rakhmanov, A.L.; Sboychakov, A.O.

2007-01-01

Full text: A competition between the localization of the charge carriers due to Jahn-Teller distortions and the energy gain due to their delocalization in doped manganite and related magnetic oxides is analyzed based on a Kondo-lattice type model. The resulting effective Hamiltonian is, in fact, a generalization of the Falicov-Kimball model. We find that the number of itinerant charge carriers can be significantly lower than that implied by the doping level x. The phase diagram of the model in the T plane is constructed. The system exhibits magnetic ordered (antiferromagnetic, ferromagnetic, or canted) states as well the paramagnetic states with zero and nonzero density of the itinerant electrons. It is shown that a phase-separation is favorable in energy for a wide doping range. The characteristic size of inhomogeneities in a phase-separated state is of the order of several lattice constants. We also analyzed the two-band Hubbard model in the limit of strong on-site Coulomb repulsion. It was shown that such a system has a tendency to phase separation into the regions with different charge densities even in the absence of magnetic or any other ordering, if the ratio of the bandwidths is large enough. The work was supported by the European project CoMePhS and by the Russian Foundation for Basic Research, project no. 05-02-17600. (authors)

Mixed-mode reversed phase/positively charged repulsion chromatography for intact protein separation.

Science.gov (United States)

Ding, Ling; Guo, Zhimou; Hu, Zhuo; Liang, Xinmiao

2017-05-10

A mixed-mode reversed phase/positively charged repulsion stationary phase C8PN composed of octyl and amino group has been developed for separation of intact protein. Before the separation of proteins, a set of probe compounds were employed to evaluate the chromatographic properties of C8PN, demonstrating typical reversed phase/positively charged repulsion interaction on this stationary phase as estimated. Then the new C8PN stationary phase was used to separate a standard protein mixture on the reversed phase mode. Compared with a commercial C4 stationary phase, it showed different selectivity for some proteins. In order to better understand the properties of C8PN, the effect of acetonitrile content was investigated based on retention equation. Higher values of the equation parameters on C8PN demonstrated that the protein retentions were more sensitive to the change of acetonitrile content. Besides, the influences of buffer salt additives on the protein retentions were also studied. The retention factors of the proteins got larger with the increase of buffer salt concentration, which confirmed the positively charged repulsion interaction on the column. Finally, the C8PN was further applied to separate oxidized- and reduced- forms of Recombinant Human Growth Hormone. Our study indicated the advantages and application potential of mixed-mode reversed phase/positively charged repulsion stationary phase for intact protein separation. Copyright © 2017 Elsevier B.V. All rights reserved.

Melting of Domain Wall in Charge Ordered Dirac Electron of Organic Conductor α-(BEDT-TTF)2I3

Science.gov (United States)

Ohki, Daigo; Matsuno, Genki; Omori, Yukiko; Kobayashi, Akito

2018-05-01

The origin of charge order melting is identified by using the real space dependent mean-field theory in the extended Hubbard model describing an organic Dirac electron system α-(BEDT-TTF)2I3. In this model, the width of a domain wall which arises between different types of the charge ordered phase exhibits a divergent increase with decreasing the strength of electron-electron correlations. By analyzing the finite-size effect carefully, it is shown that the divergence coincides with a topological transition where a pair of Dirac cones merges in keeping with a finite gap. It is also clarified that the gap opening point and the topological transition point are different, which leads to the existence of an exotic massive Dirac electron phase with melted-type domain wall and gapless edge states. The present result also indicated that multiple metastable states are emerged in massive Dirac Electron phase. In the trivial charge ordered phase, the gapless domain-wall bound state takes place instead of the gapless edge states, accompanying with a form change of the domain wall from melted-type into hyperbolic-tangent-type.

Phase transition detection by surface photo charge effect in liquid crystals

Science.gov (United States)

Ivanov, O.; Petrov, M.; Naradikian, H.; Perez-Diaz, J. L.

2018-05-01

The surface photo charge effect (SPCE) was applied for the first time at structure and phase transitions study of hydrogen bonded in dimer liquid crystals (HBDLCs). Due to the high sensitivity of this method, besides first-order phase transitions, characteristic for the p,n-octyloxibenzoic acids (8OBA), an order transition was definitely detected within the nematic range. We state that the SPCE, arising at the solid-HBDLCs interface due to the double electrical layer, is invariably concomitant with solid surface-liquid interfaces, and indicates that the changes of the characteristics of this layer, under incident optical irradiation, induce surface charge rearrangement and alternating potential difference. A mechanism of induction of the SPCE at the interface of solid surface-anisotropic liquids is proposed. We also indicate that this mechanism can be adapted for solid surface-isotropic liquid interface, including colloids (milk) and fog (aerosols)-condensed medium.

On the relation between Jahn-Teller ordering and charge ordering

International Nuclear Information System (INIS)

Eijndhoven, J.C.M van.

1978-01-01

This thesis compares the structures of KCusup(II)F 3 and Cs 2 Ausup(I)Ausup(III)Cl 6 . Both compounds have a structure that can be thought to result from a deformation of the cubic perovskite structure. The deformation of KCusup(II)F 3 is a result of a cooperative Jahn-Teller effect and the deformation of Cs 2 Ausup(I)Ausup(III)Cl 6 results in two sublattices. The structures of both compounds result from a continuous phase transition from the cubic pervskite structure due to a deformation of symmetry. Using local coordinates and a calculation of the electron-lattice interaction in a static approximation, four structure types were derived. One is the structure of Cs 2 AuAuCl 6 at ambient temperature and pressure and the second contains a group of structures corresponding to the structures found for KCuF 3 . The third structure type was recently suggested for Cs 2 AuAuCl 6 under pressure and the fourth has not been found experimentally. Two types show a Jahn-Teller ordering and the other two charge ordering (Auth./C.F.)

The Mixed Phase of Charged AdS Black Holes

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Piyabut Burikham

2016-01-01

Full Text Available We study the mixed phase of charged AdS black hole and radiation when the total energy is fixed below the threshold to produce a stable charged black hole branch. The coexistence conditions for the charged AdS black hole and radiation are derived for the generic case when radiation particles carry charge. The phase diagram of the mixed phase is demonstrated for both fixed potential and charge ensemble. In the dual gauge picture, they correspond to the mixed phase of quark-gluon plasma (QGP and hadron gas in the fixed chemical potential and density ensemble, respectively. In the nuclei and heavy-ion collisions at intermediate energies, the mixed phase of exotic QGP and hadron gas could be produced. The mixed phase will condense and evaporate into the hadron gas as the fireball expands.

Measurement of the azimuthal ordering of charged hadrons with the ATLAS detector

CERN Document Server

Aad, Georges; Abdallah, Jalal; Abdelalim, Ahmed Ali; Abdesselam, Abdelouahab; Abdinov, Ovsat; Abi, Babak; Abolins, Maris; AbouZeid, Ossama; Abramowicz, Halina; Abreu, Henso; Acerbi, Emilio; Acharya, Bobby Samir; Adamczyk, Leszek; Adams, David; Addy, Tetteh; Adelman, Jahred; Aderholz, Michael; Adomeit, Stefanie; Adragna, Paolo; Adye, Tim; Aefsky, Scott; Aguilar-Saavedra, Juan Antonio; Aharrouche, Mohamed; Ahlen, Steven; Ahles, Florian; Ahmad, Ashfaq; Ahsan, Mahsana; Aielli, Giulio; Akdogan, Taylan; Åkesson, Torsten Paul Ake; Akimoto, Ginga; Akimov, Andrei; Akiyama, Kunihiro; Alam, Mohammad; Alam, Muhammad Aftab; Albert, Justin; Albrand, Solveig; Aleksa, Martin; Aleksandrov, Igor; Alessandria, Franco; Alexa, Calin; Alexander, Gideon; Alexandre, Gauthier; Alexopoulos, Theodoros; Alhroob, Muhammad; Aliev, Malik; Alimonti, Gianluca; Alison, John; Aliyev, Magsud; Allport, Phillip; Allwood-Spiers, Sarah; Almond, John; Aloisio, Alberto; Alon, Raz; Alonso, Alejandro; Alvarez Gonzalez, Barbara; Alviggi, Mariagrazia; Amako, Katsuya; Amaral, Pedro; Amelung, Christoph; Ammosov, Vladimir; Amorim, Antonio; Amorós, Gabriel; Amram, Nir; Anastopoulos, Christos; Ancu, Lucian Stefan; Andari, Nansi; Andeen, Timothy; Anders, Christoph Falk; Anders, Gabriel; Anderson, Kelby; Andreazza, Attilio; Andrei, George Victor; Andrieux, Marie-Laure; Anduaga, Xabier; Angerami, Aaron; Anghinolfi, Francis; Anisenkov, Alexey; Anjos, Nuno; Annovi, Alberto; Antonaki, Ariadni; Antonelli, Mario; Antonov, Alexey; Antos, Jaroslav; Anulli, Fabio; Aoun, Sahar; Aperio Bella, Ludovica; Apolle, Rudi; Arabidze, Giorgi; Aracena, Ignacio; Arai, Yasuo; Arce, Ayana; Archambault, John-Paul; Arfaoui, Samir; Arguin, Jean-Francois; Arik, Engin; Arik, Metin; Armbruster, Aaron James; Arnaez, Olivier; Arnault, Christian; Artamonov, Andrei; Artoni, Giacomo; Arutinov, David; Asai, Shoji; Asfandiyarov, Ruslan; Ask, Stefan; Åsman, Barbro; Asquith, Lily; Assamagan, Ketevi; Astbury, Alan; Astvatsatourov, Anatoli; Aubert, Bernard; Auge, Etienne; Augsten, Kamil; Aurousseau, Mathieu; Avolio, Giuseppe; Avramidou, Rachel Maria; Axen, David; Ay, Cano; Azuelos, Georges; Azuma, Yuya; Baak, Max; Baccaglioni, Giuseppe; Bacci, Cesare; Bach, Andre; Bachacou, Henri; Bachas, Konstantinos; Bachy, Gerard; Backes, Moritz; Backhaus, Malte; Badescu, Elisabeta; Bagnaia, Paolo; Bahinipati, Seema; Bai, Yu; Bailey, David; Bain, Travis; Baines, John; Baker, Oliver Keith; Baker, Mark; Baker, Sarah; Banas, Elzbieta; Banerjee, Piyali; Banerjee, Swagato; Banfi, Danilo; Bangert, Andrea Michelle; Bansal, Vikas; Bansil, Hardeep Singh; Barak, Liron; Baranov, Sergei; Barashkou, Andrei; Barbaro Galtieri, Angela; Barber, Tom; Barberio, Elisabetta Luigia; Barberis, Dario; Barbero, Marlon; Bardin, Dmitri; Barillari, Teresa; Barisonzi, Marcello; Barklow, Timothy; Barlow, Nick; Barnett, Bruce; Barnett, Michael; Baroncelli, Antonio; Barone, Gaetano; Barr, Alan; Barreiro, Fernando; Barreiro Guimarães da Costa, João; Barrillon, Pierre; Bartoldus, Rainer; Barton, Adam Edward; Bartsch, Valeria; Bates, Richard; Batkova, Lucia; Batley, Richard; Battaglia, Andreas; Battistin, Michele; Bauer, Florian; Bawa, Harinder Singh; Beale, Steven; Beare, Brian; Beau, Tristan; Beauchemin, Pierre-Hugues; Beccherle, Roberto; Bechtle, Philip; Beck, Hans Peter; Becker, Sebastian; Beckingham, Matthew; Becks, Karl-Heinz; Beddall, Andrew; Beddall, Ayda; Bedikian, Sourpouhi; Bednyakov, Vadim; Bee, Christopher; Begel, Michael; Behar Harpaz, Silvia; Behera, Prafulla; Beimforde, Michael; Belanger-Champagne, Camille; Bell, Paul; Bell, William; Bella, Gideon; Bellagamba, Lorenzo; Bellina, Francesco; Bellomo, Massimiliano; Belloni, Alberto; Beloborodova, Olga; Belotskiy, Konstantin; Beltramello, Olga; Ben Ami, Sagi; Benary, Odette; Benchekroun, Driss; Benchouk, Chafik; Bendel, Markus; Benekos, Nektarios; Benhammou, Yan; Benhar Noccioli, Eleonora; Benitez Garcia, Jorge-Armando; Benjamin, Douglas; Benoit, Mathieu; Bensinger, James; Benslama, Kamal; Bentvelsen, Stan; Berge, David; Bergeaas Kuutmann, Elin; Berger, Nicolas; Berghaus, Frank; Berglund, Elina; Beringer, Jürg; Bernat, Pauline; Bernhard, Ralf; Bernius, Catrin; Berry, Tracey; Bertella, Claudia; Bertin, Antonio; Bertinelli, Francesco; Bertolucci, Federico; Besana, Maria Ilaria; Besson, Nathalie; Bethke, Siegfried; Bhimji, Wahid; Bianchi, Riccardo-Maria; Bianco, Michele; Biebel, Otmar; Bieniek, Stephen Paul; Bierwagen, Katharina; Biesiada, Jed; Biglietti, Michela; Bilokon, Halina; Bindi, Marcello; Binet, Sebastien; Bingul, Ahmet; Bini, Cesare; Biscarat, Catherine; Bitenc, Urban; Black, Kevin; Blair, Robert; Blanchard, Jean-Baptiste; Blanchot, Georges; Blazek, Tomas; Blocker, Craig; Blocki, Jacek; Blondel, Alain; Blum, Walter; Blumenschein, Ulrike; Bobbink, Gerjan; Bobrovnikov, Victor; Bocchetta, Simona Serena; Bocci, Andrea; Boddy, Christopher Richard; Boehler, Michael; Boek, Jennifer; Boelaert, Nele; Böser, Sebastian; Bogaerts, Joannes Andreas; Bogdanchikov, Alexander; Bogouch, Andrei; Bohm, Christian; Boisvert, Veronique; Bold, Tomasz; Boldea, Venera; Bolnet, Nayanka Myriam; Bona, Marcella; Bondarenko, Valery; Bondioli, Mario; Boonekamp, Maarten; Boorman, Gary; Booth, Chris; Bordoni, Stefania; Borer, Claudia; Borisov, Anatoly; Borissov, Guennadi; Borjanovic, Iris; Borroni, Sara; Bos, Kors; Boscherini, Davide; Bosman, Martine; Boterenbrood, Hendrik; Botterill, David; Bouchami, Jihene; Boudreau, Joseph; Bouhova-Thacker, Evelina Vassileva; Boumediene, Djamel Eddine; Bourdarios, Claire; Bousson, Nicolas; Boveia, Antonio; Boyd, James; Boyko, Igor; Bozhko, Nikolay; Bozovic-Jelisavcic, Ivanka; Bracinik, Juraj; Braem, André; Branchini, Paolo; Brandenburg, George; Brandt, Andrew; Brandt, Gerhard; Brandt, Oleg; Bratzler, Uwe; Brau, Benjamin; Brau, James; Braun, Helmut; Brelier, Bertrand; Bremer, Johan; Brenner, Richard; Bressler, Shikma; Breton, Dominique; Britton, Dave; Brochu, Frederic; Brock, Ian; Brock, Raymond; Brodbeck, Timothy; Brodet, Eyal; Broggi, Francesco; Bromberg, Carl; Bronner, Johanna; Brooijmans, Gustaaf; Brooks, William; Brown, Gareth; Brown, Heather; Bruckman de Renstrom, Pawel; Bruncko, Dusan; Bruneliere, Renaud; Brunet, Sylvie; Bruni, Alessia; Bruni, Graziano; Bruschi, Marco; Buanes, Trygve; Buat, Quentin; Bucci, Francesca; Buchanan, James; Buchanan, Norman; Buchholz, Peter; Buckingham, Ryan; Buckley, Andrew; Buda, Stelian Ioan; Budagov, Ioulian; Budick, Burton; Büscher, Volker; Bugge, Lars; Bulekov, Oleg; Bunse, Moritz; Buran, Torleiv; Burckhart, Helfried; Burdin, Sergey; Burgess, Thomas; Burke, Stephen; Busato, Emmanuel; Bussey, Peter; Buszello, Claus-Peter; Butin, François; Butler, Bart; Butler, John; Buttar, Craig; Butterworth, Jonathan; Buttinger, William; Cabrera Urbán, Susana; Caforio, Davide; Cakir, Orhan; Calafiura, Paolo; Calderini, Giovanni; Calfayan, Philippe; Calkins, Robert; Caloba, Luiz; Caloi, Rita; Calvet, David; Calvet, Samuel; Camacho Toro, Reina; Camarri, Paolo; Cambiaghi, Mario; Cameron, David; Caminada, Lea Michaela; Campana, Simone; Campanelli, Mario; Canale, Vincenzo; Canelli, Florencia; Canepa, Anadi; Cantero, Josu; Capasso, Luciano; Capeans Garrido, Maria Del Mar; Caprini, Irinel; Caprini, Mihai; Capriotti, Daniele; Capua, Marcella; Caputo, Regina; Caramarcu, Costin; Cardarelli, Roberto; Carli, Tancredi; Carlino, Gianpaolo; Carminati, Leonardo; Caron, Bryan; Caron, Sascha; Carrillo Montoya, German D; Carter, Antony; Carter, Janet; Carvalho, João; Casadei, Diego; Casado, Maria Pilar; Cascella, Michele; Caso, Carlo; Castaneda Hernandez, Alfredo Martin; Castaneda-Miranda, Elizabeth; Castillo Gimenez, Victoria; Castro, Nuno Filipe; Cataldi, Gabriella; Cataneo, Fernando; Catinaccio, Andrea; Catmore, James; Cattai, Ariella; Cattani, Giordano; Caughron, Seth; Cauz, Diego; Cavalleri, Pietro; Cavalli, Donatella; Cavalli-Sforza, Matteo; Cavasinni, Vincenzo; Ceradini, Filippo; Santiago Cerqueira, Augusto; Cerri, Alessandro; Cerrito, Lucio; Cerutti, Fabio; Cetin, Serkant Ali; Cevenini, Francesco; Chafaq, Aziz; Chakraborty, Dhiman; Chan, Kevin; Chapleau, Bertrand; Chapman, John Derek; Chapman, John Wehrley; Chareyre, Eve; Charlton, Dave; Chavda, Vikash; Chavez Barajas, Carlos Alberto; Cheatham, Susan; Chekanov, Sergei; Chekulaev, Sergey; Chelkov, Gueorgui; Chelstowska, Magda Anna; Chen, Chunhui; Chen, Hucheng; Chen, Shenjian; Chen, Tingyang; Chen, Xin; Cheng, Shaochen; Cheplakov, Alexander; Chepurnov, Vladimir; Cherkaoui El Moursli, Rajaa; Chernyatin, Valeriy; Cheu, Elliott; Cheung, Sing-Leung; Chevalier, Laurent; Chiefari, Giovanni; Chikovani, Leila; Childers, John Taylor; Chilingarov, Alexandre; Chiodini, Gabriele; Chizhov, Mihail; Choudalakis, Georgios; Chouridou, Sofia; Christidi, Illectra-Athanasia; Christov, Asen; Chromek-Burckhart, Doris; Chu, Ming-Lee; Chudoba, Jiri; Ciapetti, Guido; Ciba, Krzysztof; Ciftci, Abbas Kenan; Ciftci, Rena; Cinca, Diane; Cindro, Vladimir; Ciobotaru, Matei Dan; Ciocca, Claudia; Ciocio, Alessandra; Cirilli, Manuela; Citterio, Mauro; Ciubancan, Mihai; Clark, Allan G; Clark, Philip James; Cleland, Bill; Clemens, Jean-Claude; Clement, Benoit; Clement, Christophe; Clifft, Roger; Coadou, Yann; Cobal, Marina; Coccaro, Andrea; Cochran, James H; Coe, Paul; Cogan, Joshua Godfrey; Coggeshall, James; Cogneras, Eric; Colas, Jacques; Colijn, Auke-Pieter; Collins, Neil; Collins-Tooth, Christopher; Collot, Johann; Colon, German; Conde Muiño, Patricia; Coniavitis, Elias; Conidi, Maria Chiara; Consonni, Michele; Consorti, Valerio; Constantinescu, Serban; Conta, Claudio; Conventi, Francesco; Cook, James; Cooke, Mark; Cooper, Ben; Cooper-Sarkar, Amanda; Copic, Katherine; Cornelissen, Thijs; Corradi, Massimo; Corriveau, Francois; Cortes-Gonzalez, Arely; Cortiana, Giorgio; Costa, Giuseppe; Costa, María José; Costanzo, Davide; Costin, Tudor; Côté, David; Coura Torres, Rodrigo; Courneyea, Lorraine; Cowan, Glen; Cowden, Christopher; Cox, Brian; Cranmer, Kyle; Crescioli, Francesco; Cristinziani, Markus; Crosetti, Giovanni; Crupi, Roberto; Crépé-Renaudin, Sabine; Cuciuc, Constantin-Mihai; Cuenca Almenar, Cristóbal; Cuhadar Donszelmann, Tulay; Curatolo, Maria; Curtis, Chris; Cuthbert, Cameron; Cwetanski, Peter; Czirr, Hendrik; Czodrowski, Patrick; Czyczula, Zofia; D'Auria, Saverio; D'Onofrio, Monica; D'Orazio, Alessia; Da Silva, Paulo Vitor; Da Via, Cinzia; Dabrowski, Wladyslaw; Dai, Tiesheng; Dallapiccola, Carlo; Dam, Mogens; Dameri, Mauro; Damiani, Daniel; Danielsson, Hans Olof; Dannheim, Dominik; Dao, Valerio; Darbo, Giovanni; Darlea, Georgiana Lavinia; Daum, Cornelis; Davey, Will; Davidek, Tomas; Davidson, Nadia; Davidson, Ruth; Davies, Eleanor; Davies, Merlin; Davison, Adam; Davygora, Yuriy; Dawe, Edmund; Dawson, Ian; Dawson, John; Daya-Ishmukhametova, Rozmin; De, Kaushik; de Asmundis, Riccardo; De Castro, Stefano; De Castro Faria Salgado, Pedro; De Cecco, Sandro; de Graat, Julien; De Groot, Nicolo; de Jong, Paul; De La Taille, Christophe; De la Torre, Hector; De Lotto, Barbara; de Mora, Lee; De Nooij, Lucie; De Pedis, Daniele; De Salvo, Alessandro; De Sanctis, Umberto; De Santo, Antonella; De Vivie De Regie, Jean-Baptiste; Dean, Simon; Dearnaley, William James; Debbe, Ramiro; Debenedetti, Chiara; Dedovich, Dmitri; Degenhardt, James; Dehchar, Mohamed; Del Papa, Carlo; Del Peso, Jose; Del Prete, Tarcisio; Delemontex, Thomas; Deliyergiyev, Maksym; Dell'Acqua, Andrea; Dell'Asta, Lidia; Della Pietra, Massimo; della Volpe, Domenico; Delmastro, Marco; Delruelle, Nicolas; Delsart, Pierre-Antoine; Deluca, Carolina; Demers, Sarah; Demichev, Mikhail; Demirkoz, Bilge; Deng, Jianrong; Denisov, Sergey; Derendarz, Dominik; Derkaoui, Jamal Eddine; Derue, Frederic; Dervan, Paul; Desch, Klaus Kurt; Devetak, Erik; Deviveiros, Pier-Olivier; Dewhurst, Alastair; DeWilde, Burton; Dhaliwal, Saminder; Dhullipudi, Ramasudhakar; Di Ciaccio, Anna; Di Ciaccio, Lucia; Di Girolamo, Alessandro; Di Girolamo, Beniamino; Di Luise, Silvestro; Di Mattia, Alessandro; Di Micco, Biagio; Di Nardo, Roberto; Di Simone, Andrea; Di Sipio, Riccardo; Diaz, Marco Aurelio; Diblen, Faruk; Diehl, Edward; Dietrich, Janet; Dietzsch, Thorsten; Diglio, Sara; Dindar Yagci, Kamile; Dingfelder, Jochen; Dionisi, Carlo; Dita, Petre; Dita, Sanda; Dittus, Fridolin; Djama, Fares; Djobava, Tamar; Barros do Vale, Maria Aline; Do Valle Wemans, André; Doan, Thi Kieu Oanh; Dobbs, Matt; Dobinson, Robert; Dobos, Daniel; Dobson, Ellie; Dodd, Jeremy; Doglioni, Caterina; Doherty, Tom; Doi, Yoshikuni; Dolejsi, Jiri; Dolenc, Irena; Dolezal, Zdenek; Dolgoshein, Boris; Dohmae, Takeshi; Donadelli, Marisilvia; Donega, Mauro; Donini, Julien; Dopke, Jens; Doria, Alessandra; Dos Anjos, Andre; Dosil, Mireia; Dotti, Andrea; Dova, Maria-Teresa; Dowell, John; Doxiadis, Alexander; Doyle, Tony; Drasal, Zbynek; Drees, Jürgen; Dressnandt, Nandor; Drevermann, Hans; Driouichi, Chafik; Dris, Manolis; Dubbert, Jörg; Dube, Sourabh; Duchovni, Ehud; Duckeck, Guenter; Dudarev, Alexey; Dudziak, Fanny; Dührssen, Michael; Duerdoth, Ian; Duflot, Laurent; Dufour, Marc-Andre; Dunford, Monica; Duran Yildiz, Hatice; Duxfield, Robert; Dwuznik, Michal; Dydak, Friedrich; Düren, Michael; Ebenstein, William; Ebke, Johannes; Eckweiler, Sebastian; Edmonds, Keith; Edwards, Clive; Edwards, Nicholas Charles; Ehrenfeld, Wolfgang; Ehrich, Thies; Eifert, Till; Eigen, Gerald; Einsweiler, Kevin; Eisenhandler, Eric; Ekelof, Tord; El Kacimi, Mohamed; Ellert, Mattias; Elles, Sabine; Ellinghaus, Frank; Ellis, Katherine; Ellis, Nicolas; Elmsheuser, Johannes; Elsing, Markus; Emeliyanov, Dmitry; Engelmann, Roderich; Engl, Albert; Epp, Brigitte; Eppig, Andrew; Erdmann, Johannes; Ereditato, Antonio; Eriksson, Daniel; Ernst, Jesse; Ernst, Michael; Ernwein, Jean; Errede, Deborah; Errede, Steven; Ertel, Eugen; Escalier, Marc; Escobar, Carlos; Espinal Curull, Xavier; Esposito, Bellisario; Etienne, Francois; Etienvre, Anne-Isabelle; Etzion, Erez; Evangelakou, Despoina; Evans, Hal; Fabbri, Laura; Fabre, Caroline; Fakhrutdinov, Rinat; Falciano, Speranza; Fang, Yaquan; Fanti, Marcello; Farbin, Amir; Farilla, Addolorata; Farley, Jason; Farooque, Trisha; Farrington, Sinead; Farthouat, Philippe; Fassnacht, Patrick; Fassouliotis, Dimitrios; Fatholahzadeh, Baharak; Favareto, Andrea; Fayard, Louis; Fazio, Salvatore; Febbraro, Renato; Federic, Pavol; Fedin, Oleg; Fedorko, Woiciech; Fehling-Kaschek, Mirjam; Feligioni, Lorenzo; Fellmann, Denis; Feng, Cunfeng; Feng, Eric; Fenyuk, Alexander; Ferencei, Jozef; Ferland, Jonathan; Fernando, Waruna; Ferrag, Samir; Ferrando, James; Ferrara, Valentina; Ferrari, Arnaud; Ferrari, Pamela; Ferrari, Roberto; Ferrer, Antonio; Ferrer, Maria Lorenza; Ferrere, Didier; Ferretti, Claudio; Ferretto Parodi, Andrea; Fiascaris, Maria; Fiedler, Frank; Filipčič, Andrej; Filippas, Anastasios; Filthaut, Frank; Fincke-Keeler, Margret; Fiolhais, Miguel; Fiorini, Luca; Firan, Ana; Fischer, Gordon; Fischer, Peter; Fisher, Matthew; Flechl, Martin; Fleck, Ivor; Fleckner, Johanna; Fleischmann, Philipp; Fleischmann, Sebastian; Flick, Tobias; Flores Castillo, Luis; Flowerdew, Michael; Fokitis, Manolis; Fonseca Martin, Teresa; Forbush, David Alan; Formica, Andrea; Forti, Alessandra; Fortin, Dominique; Foster, Joe; Fournier, Daniel; Foussat, Arnaud; Fowler, Andrew; Fowler, Ken; Fox, Harald; Francavilla, Paolo; Franchino, Silvia; Francis, David; Frank, Tal; Franklin, Melissa; Franz, Sebastien; Fraternali, Marco; Fratina, Sasa; French, Sky; Friedrich, Felix; Froeschl, Robert; Froidevaux, Daniel; Frost, James; Fukunaga, Chikara; Fullana Torregrosa, Esteban; Fuster, Juan; Gabaldon, Carolina; Gabizon, Ofir; Gadfort, Thomas; Gadomski, Szymon; Gagliardi, Guido; Gagnon, Pauline; Galea, Cristina; Gallas, Elizabeth; Gallo, Valentina Santina; Gallop, Bruce; Gallus, Petr; Gan, KK; Gao, Yongsheng; Gapienko, Vladimir; Gaponenko, Andrei; Garberson, Ford; Garcia-Sciveres, Maurice; García, Carmen; García Navarro, José Enrique; Gardner, Robert; Garelli, Nicoletta; Garitaonandia, Hegoi; Garonne, Vincent; Garvey, John; Gatti, Claudio; Gaudio, Gabriella; Gaumer, Olivier; Gaur, Bakul; Gauthier, Lea; Gavrilenko, Igor; Gay, Colin; Gaycken, Goetz; Gayde, Jean-Christophe; Gazis, Evangelos; Ge, Peng; Gee, Norman; Geerts, Daniël Alphonsus Adrianus; Geich-Gimbel, Christoph; Gellerstedt, Karl; Gemme, Claudia; Gemmell, Alistair; Genest, Marie-Hélène; Gentile, Simonetta; George, Matthias; George, Simon; Gerlach, Peter; Gershon, Avi; Geweniger, Christoph; Ghazlane, Hamid; Ghodbane, Nabil; Giacobbe, Benedetto; Giagu, Stefano; Giakoumopoulou, Victoria; Giangiobbe, Vincent; Gianotti, Fabiola; Gibbard, Bruce; Gibson, Adam; Gibson, Stephen; Gilbert, Laura; Gilewsky, Valentin; Gillberg, Dag; Gillman, Tony; Gingrich, Douglas; Ginzburg, Jonatan; Giokaris, Nikos; Giordani, MarioPaolo; Giordano, Raffaele; Giorgi, Francesco Michelangelo; Giovannini, Paola; Giraud, Pierre-Francois; Giugni, Danilo; Giunta, Michele; Giusti, Paolo; Gjelsten, Børge Kile; Gladilin, Leonid; Glasman, Claudia; Glatzer, Julian; Glazov, Alexandre; Glitza, Karl-Walter; Glonti, George; Goddard, Jack Robert; Godfrey, Jennifer; Godlewski, Jan; Goebel, Martin; Göpfert, Thomas; Goeringer, Christian; Gössling, Claus; Göttfert, Tobias; Goldfarb, Steven; Golling, Tobias; Golovnia, Serguei; Gomes, Agostinho; Gomez Fajardo, Luz Stella; Gonçalo, Ricardo; Goncalves Pinto Firmino Da Costa, Joao; Gonella, Laura; Gonidec, Allain; Gonzalez, Saul; González de la Hoz, Santiago; Gonzalez Parra, Garoe; Gonzalez Silva, Laura; Gonzalez-Sevilla, Sergio; Goodson, Jeremiah Jet; Goossens, Luc; Gorbounov, Petr Andreevich; Gordon, Howard; Gorelov, Igor; Gorfine, Grant; Gorini, Benedetto; Gorini, Edoardo; Gorišek, Andrej; Gornicki, Edward; Gorokhov, Serguei; Goryachev, Vladimir; Gosdzik, Bjoern; Gosselink, Martijn; Gostkin, Mikhail Ivanovitch; Gough Eschrich, Ivo; Gouighri, Mohamed; Goujdami, Driss; Goulette, Marc Phillippe; Goussiou, Anna; Goy, Corinne; Gozpinar, Serdar; Grabowska-Bold, Iwona; Grafström, Per; Grahn, Karl-Johan; Grancagnolo, Francesco; Grancagnolo, Sergio; Grassi, Valerio; Gratchev, Vadim; Grau, Nathan; Gray, Heather; Gray, Julia Ann; Graziani, Enrico; Grebenyuk, Oleg; Greenshaw, Timothy; Greenwood, Zeno Dixon; Gregersen, Kristian; Gregor, Ingrid-Maria; Grenier, Philippe; Griffiths, Justin; Grigalashvili, Nugzar; Grillo, Alexander; Grinstein, Sebastian; Grishkevich, Yaroslav; Grivaz, Jean-Francois; Groh, Manfred; Gross, Eilam; Grosse-Knetter, Joern; Groth-Jensen, Jacob; Grybel, Kai; Guarino, Victor; Guest, Daniel; Guicheney, Christophe; Guida, Angelo; Guindon, Stefan; Guler, Hulya; Gunther, Jaroslav; Guo, Bin; Guo, Jun; Gupta, Ambreesh; Gusakov, Yury; Gushchin, Vladimir; Gutierrez, Andrea; Gutierrez, Phillip; Guttman, Nir; Gutzwiller, Olivier; Guyot, Claude; Gwenlan, Claire; Gwilliam, Carl; Haas, Andy; Haas, Stefan; Haber, Carl; Hadavand, Haleh Khani; Hadley, David; Haefner, Petra; Hahn, Ferdinand; Haider, Stefan; Hajduk, Zbigniew; Hakobyan, Hrachya; Hall, David; Haller, Johannes; Hamacher, Klaus; Hamal, Petr; Hamer, Matthias; Hamilton, Andrew; Hamilton, Samuel; Han, Hongguang; Han, Liang; Hanagaki, Kazunori; Hanawa, Keita; Hance, Michael; Handel, Carsten; Hanke, Paul; Hansen, John Renner; Hansen, Jørgen Beck; Hansen, Jorn Dines; Hansen, Peter Henrik; Hansson, Per; Hara, Kazuhiko; Hare, Gabriel; Harenberg, Torsten; Harkusha, Siarhei; Harper, Devin; Harrington, Robert; Harris, Orin; Harrison, Karl; Hartert, Jochen; Hartjes, Fred; Haruyama, Tomiyoshi; Harvey, Alex; Hasegawa, Satoshi; Hasegawa, Yoji; Hassani, Samira; Hatch, Mark; Hauff, Dieter; Haug, Sigve; Hauschild, Michael; Hauser, Reiner; Havranek, Miroslav; Hawes, Brian; Hawkes, Christopher; Hawkings, Richard John; Hawkins, Anthony David; Hawkins, Donovan; Hayakawa, Takashi; Hayashi, Takayasu; Hayden, Daniel; Hayward, Helen; Haywood, Stephen; Hazen, Eric; He, Mao; Head, Simon; Hedberg, Vincent; Heelan, Louise; Heim, Sarah; Heinemann, Beate; Heisterkamp, Simon; Helary, Louis; Heller, Claudio; Heller, Matthieu; Hellman, Sten; Hellmich, Dennis; Helsens, Clement; Henderson, Robert; Henke, Michael; Henrichs, Anna; Henriques Correia, Ana Maria; Henrot-Versille, Sophie; Henry-Couannier, Frédéric; Hensel, Carsten; Henß, Tobias; Medina Hernandez, Carlos; Hernández Jiménez, Yesenia; Herrberg, Ruth; Hershenhorn, Alon David; Herten, Gregor; Hertenberger, Ralf; Hervas, Luis; Hessey, Nigel; Higón-Rodriguez, Emilio; Hill, Daniel; Hill, John; Hill, Norman; Hiller, Karl Heinz; Hillert, Sonja; Hillier, Stephen; Hinchliffe, Ian; Hines, Elizabeth; Hirose, Minoru; Hirsch, Florian; Hirschbuehl, Dominic; Hobbs, John; Hod, Noam; Hodgkinson, Mark; Hodgson, Paul; Hoecker, Andreas; Hoeferkamp, Martin; Hoffman, Julia; Hoffmann, Dirk; Hohlfeld, Marc; Holder, Martin; Holmgren, Sven-Olof; Holy, Tomas; Holzbauer, Jenny; Homma, Yasuhiro; Hong, Tae Min; Hooft van Huysduynen, Loek; Horazdovsky, Tomas; Horn, Claus; Horner, Stephan; Hostachy, Jean-Yves; Hou, Suen; Houlden, Michael; Hoummada, Abdeslam; Howarth, James; Howell, David; Hristova, Ivana; Hrivnac, Julius; Hruska, Ivan; Hryn'ova, Tetiana; Hsu, Pai-hsien Jennifer; Hsu, Shih-Chieh; Huang, Guang Shun; Hubacek, Zdenek; Hubaut, Fabrice; Huegging, Fabian; Huettmann, Antje; Huffman, Todd Brian; Hughes, Emlyn; Hughes, Gareth; Hughes-Jones, Richard; Huhtinen, Mika; Hurst, Peter; Hurwitz, Martina; Husemann, Ulrich; Huseynov, Nazim; Huston, Joey; Huth, John; Iacobucci, Giuseppe; Iakovidis, Georgios; Ibbotson, Michael; Ibragimov, Iskander; Ichimiya, Ryo; Iconomidou-Fayard, Lydia; Idarraga, John; Iengo, Paolo; Igonkina, Olga; Ikegami, Yoichi; Ikeno, Masahiro; Ilchenko, Yuri; Iliadis, Dimitrios; Ilic, Nikolina; Imbault, Didier; Imori, Masatoshi; Ince, Tayfun; Inigo-Golfin, Joaquin; Ioannou, Pavlos; Iodice, Mauro; Ippolito, Valerio; Irles Quiles, Adrian; Isaksson, Charlie; Ishikawa, Akimasa; Ishino, Masaya; Ishmukhametov, Renat; Issever, Cigdem; Istin, Serhat; Ivashin, Anton; Iwanski, Wieslaw; Iwasaki, Hiroyuki; Izen, Joseph; Izzo, Vincenzo; Jackson, Brett; Jackson, John; Jackson, Paul; Jaekel, Martin; Jain, Vivek; Jakobs, Karl; Jakobsen, Sune; Jakubek, Jan; Jana, Dilip; Jankowski, Ernest; Jansen, Eric; Jansen, Hendrik; Jantsch, Andreas; Janus, Michel; Jarlskog, Göran; Jeanty, Laura; Jelen, Kazimierz; Jen-La Plante, Imai; Jenni, Peter; Jeremie, Andrea; Jež, Pavel; Jézéquel, Stéphane; Jha, Manoj Kumar; Ji, Haoshuang; Ji, Weina; Jia, Jiangyong; Jiang, Yi; Jimenez Belenguer, Marcos; Jin, Ge; Jin, Shan; Jinnouchi, Osamu; Joergensen, Morten Dam; Joffe, David; Johansen, Lars; Johansen, Marianne; Johansson, Erik; Johansson, Per; Johnert, Sebastian; Johns, Kenneth; Jon-And, Kerstin; Jones, Graham; Jones, Roger; Jones, Tegid; Jones, Tim; Jonsson, Ove; Joram, Christian; Jorge, Pedro; Joseph, John; Jovin, Tatjana; Ju, Xiangyang; Jung, Christian; Jungst, Ralph Markus; Juranek, Vojtech; Jussel, Patrick; Juste Rozas, Aurelio; Kabachenko, Vasily; Kabana, Sonja; Kaci, Mohammed; Kaczmarska, Anna; Kadlecik, Peter; Kado, Marumi; Kagan, Harris; Kagan, Michael; Kaiser, Steffen; Kajomovitz, Enrique; Kalinin, Sergey; Kalinovskaya, Lidia; Kama, Sami; Kanaya, Naoko; Kaneda, Michiru; Kaneti, Steven; Kanno, Takayuki; Kantserov, Vadim; Kanzaki, Junichi; Kaplan, Benjamin; Kapliy, Anton; Kaplon, Jan; Kar, Deepak; Karagounis, Michael; Karagoz, Muge; Karnevskiy, Mikhail; Karr, Kristo; Kartvelishvili, Vakhtang; Karyukhin, Andrey; Kashif, Lashkar; Kasieczka, Gregor; Kass, Richard; Kastanas, Alex; Kataoka, Mayuko; Kataoka, Yousuke; Katsoufis, Elias; Katzy, Judith; Kaushik, Venkatesh; Kawagoe, Kiyotomo; Kawamoto, Tatsuo; Kawamura, Gen; Kayl, Manuel; Kazanin, Vassili; Kazarinov, Makhail; Keeler, Richard; Kehoe, Robert; Keil, Markus; Kekelidze, George; Kennedy, John; Kenney, Christopher John; Kenyon, Mike; Kepka, Oldrich; Kerschen, Nicolas; Kerševan, Borut Paul; Kersten, Susanne; Kessoku, Kohei; Keung, Justin; Khalil-zada, Farkhad; Khandanyan, Hovhannes; Khanov, Alexander; Kharchenko, Dmitri; Khodinov, Alexander; Kholodenko, Anatoli; Khomich, Andrei; Khoo, Teng Jian; Khoriauli, Gia; Khoroshilov, Andrey; Khovanskiy, Nikolai; Khovanskiy, Valery; Khramov, Evgeniy; Khubua, Jemal; Kim, Hyeon Jin; Kim, Min Suk; Kim, Peter; Kim, Shinhong; Kimura, Naoki; Kind, Oliver; King, Barry; King, Matthew; King, Robert Steven Beaufoy; Kirk, Julie; Kirsch, Lawrence; Kiryunin, Andrey; Kishimoto, Tomoe; Kisielewska, Danuta; Kittelmann, Thomas; Kiver, Andrey; Kladiva, Eduard; Klaiber-Lodewigs, Jonas; Klein, Max; Klein, Uta; Kleinknecht, Konrad; Klemetti, Miika; Klier, Amit; Klimek, Pawel; Klimentov, Alexei; Klingenberg, Reiner; Klinkby, Esben; Klioutchnikova, Tatiana; Klok, Peter; Klous, Sander; Kluge, Eike-Erik; Kluge, Thomas; Kluit, Peter; Kluth, Stefan; Knecht, Neil; Kneringer, Emmerich; Knobloch, Juergen; Knoops, Edith; Knue, Andrea; Ko, Byeong Rok; Kobayashi, Tomio; Kobel, Michael; Kocian, Martin; Kodys, Peter; Köneke, Karsten; König, Adriaan; Koenig, Sebastian; Köpke, Lutz; Koetsveld, Folkert; Koevesarki, Peter; Koffas, Thomas; Koffeman, Els; Kogan, Lucy Anne; Kohn, Fabian; Kohout, Zdenek; Kohriki, Takashi; Koi, Tatsumi; Kokott, Thomas; Kolachev, Guennady; Kolanoski, Hermann; Kolesnikov, Vladimir; Koletsou, Iro; Koll, James; Kollar, Daniel; Kollefrath, Michael; Kolya, Scott; Komar, Aston; Komori, Yuto; Kondo, Takahiko; Kono, Takanori; Kononov, Anatoly; Konoplich, Rostislav; Konstantinidis, Nikolaos; Kootz, Andreas; Koperny, Stefan; Korcyl, Krzysztof; Kordas, Kostantinos; Koreshev, Victor; Korn, Andreas; Korol, Aleksandr; Korolkov, Ilya; Korolkova, Elena; Korotkov, Vladislav; Kortner, Oliver; Kortner, Sandra; Kostyukhin, Vadim; Kotamäki, Miikka Juhani; Kotov, Sergey; Kotov, Vladislav; Kotwal, Ashutosh; Kourkoumelis, Christine; Kouskoura, Vasiliki; Koutsman, Alex; Kowalewski, Robert Victor; Kowalski, Tadeusz; Kozanecki, Witold; Kozhin, Anatoly; Kral, Vlastimil; Kramarenko, Viktor; Kramberger, Gregor; Krasny, Mieczyslaw Witold; Krasznahorkay, Attila; Kraus, James; Kraus, Jana; Kreisel, Arik; Krejci, Frantisek; Kretzschmar, Jan; Krieger, Nina; Krieger, Peter; Kroeninger, Kevin; Kroha, Hubert; Kroll, Joe; Kroseberg, Juergen; Krstic, Jelena; Kruchonak, Uladzimir; Krüger, Hans; Kruker, Tobias; Krumnack, Nils; Krumshteyn, Zinovii; Kruth, Andre; Kubota, Takashi; Kuehn, Susanne; Kugel, Andreas; Kuhl, Thorsten; Kuhn, Dietmar; Kukhtin, Victor; Kulchitsky, Yuri; Kuleshov, Sergey; Kummer, Christian; Kuna, Marine; Kundu, Nikhil; Kunkle, Joshua; Kupco, Alexander; Kurashige, Hisaya; Kurata, Masakazu; Kurochkin, Yurii; Kus, Vlastimil; Kuwertz, Emma Sian; Kuze, Masahiro; Kvita, Jiri; Kwee, Regina; La Rosa, Alessandro; La Rotonda, Laura; Labarga, Luis; Labbe, Julien; Lablak, Said; Lacasta, Carlos; Lacava, Francesco; Lacker, Heiko; Lacour, Didier; Lacuesta, Vicente Ramón; Ladygin, Evgueni; Lafaye, Remi; Laforge, Bertrand; Lagouri, Theodota; Lai, Stanley; Laisne, Emmanuel; Lamanna, Massimo; Lampen, Caleb; Lampl, Walter; Lancon, Eric; Landgraf, Ulrich; Landon, Murrough; Landsman, Hagar; Lane, Jenna; Lange, Clemens; Lankford, Andrew; Lanni, Francesco; Lantzsch, Kerstin; Laplace, Sandrine; Lapoire, Cecile; Laporte, Jean-Francois; Lari, Tommaso; Larionov, Anatoly; Larner, Aimee; Lasseur, Christian; Lassnig, Mario; Laurelli, Paolo; Lavrijsen, Wim; Laycock, Paul; Lazarev, Alexandre; Le Dortz, Olivier; Le Guirriec, Emmanuel; Le Maner, Christophe; Le Menedeu, Eve; Lebel, Céline; LeCompte, Thomas; Ledroit-Guillon, Fabienne Agnes Marie; Lee, Hurng-Chun; Lee, Jason; Lee, Shih-Chang; Lee, Lawrence; Lefebvre, Michel; Legendre, Marie; Leger, Annie; LeGeyt, Benjamin; Legger, Federica; Leggett, Charles; Lehmacher, Marc; Lehmann Miotto, Giovanna; Lei, Xiaowen; Leite, Marco Aurelio Lisboa; Leitner, Rupert; Lellouch, Daniel; Leltchouk, Mikhail; Lemmer, Boris; Lendermann, Victor; Leney, Katharine; Lenz, Tatiana; Lenzen, Georg; Lenzi, Bruno; Leonhardt, Kathrin; Leontsinis, Stefanos; Leroy, Claude; Lessard, Jean-Raphael; Lesser, Jonas; Lester, Christopher; Leung Fook Cheong, Annabelle; Levêque, Jessica; Levin, Daniel; Levinson, Lorne; Levitski, Mikhail; Lewis, Adrian; Lewis, George; Leyko, Agnieszka; Leyton, Michael; Li, Bo; Li, Haifeng; Li, Shu; Li, Xuefei; Liang, Zhijun; Liao, Hongbo; Liberti, Barbara; Lichard, Peter; Lichtnecker, Markus; Lie, Ki; Liebig, Wolfgang; Lifshitz, Ronen; Limbach, Christian; Limosani, Antonio; Limper, Maaike; Lin, Simon; Linde, Frank; Linnemann, James; Lipeles, Elliot; Lipinsky, Lukas; Lipniacka, Anna; Liss, Tony; Lissauer, David; Lister, Alison; Litke, Alan; Liu, Chuanlei; Liu, Dong; Liu, Hao; Liu, Jianbei; Liu, Minghui; Liu, Shengli; Liu, Yanwen; Livan, Michele; Livermore, Sarah; Lleres, Annick; Llorente Merino, Javier; Lloyd, Stephen; Lobodzinska, Ewelina; Loch, Peter; Lockman, William; Loddenkoetter, Thomas; Loebinger, Fred; Loginov, Andrey; Loh, Chang Wei; Lohse, Thomas; Lohwasser, Kristin; Lokajicek, Milos; Loken, James; Lombardo, Vincenzo Paolo; Long, Robin Eamonn; Lopes, Lourenco; Lopez Mateos, David; Lorenz, Jeanette; Losada, Marta; Loscutoff, Peter; Lo Sterzo, Francesco; Losty, Michael; Lou, Xinchou; Lounis, Abdenour; Loureiro, Karina; Love, Jeremy; Love, Peter; Lowe, Andrew; Lu, Feng; Lubatti, Henry; Luci, Claudio; Lucotte, Arnaud; Ludwig, Andreas; Ludwig, Dörthe; Ludwig, Inga; Ludwig, Jens; Luehring, Frederick; Luijckx, Guy; Lumb, Debra; Luminari, Lamberto; Lund, Esben; Lund-Jensen, Bengt; Lundberg, Björn; Lundberg, Johan; Lundquist, Johan; Lungwitz, Matthias; Lutz, Gerhard; Lynn, David; Lys, Jeremy; Lytken, Else; Ma, Hong; Ma, Lian Liang; Macana Goia, Jorge Andres; Maccarrone, Giovanni; Macchiolo, Anna; Maček, Boštjan; Machado Miguens, Joana; Mackeprang, Rasmus; Madaras, Ronald; Mader, Wolfgang; Maenner, Reinhard; Maeno, Tadashi; Mättig, Peter; Mättig, Stefan; Magnoni, Luca; Magradze, Erekle; Mahalalel, Yair; Mahboubi, Kambiz; Mahout, Gilles; Maiani, Camilla; Maidantchik, Carmen; Maio, Amélia; Majewski, Stephanie; Makida, Yasuhiro; Makovec, Nikola; Mal, Prolay; Malaescu, Bogdan; Malecki, Pawel; Malecki, Piotr; Maleev, Victor; Malek, Fairouz; Mallik, Usha; Malon, David; Malone, Caitlin; Maltezos, Stavros; Malyshev, Vladimir; Malyukov, Sergei; Mameghani, Raphael; Mamuzic, Judita; Manabe, Atsushi; Mandelli, Luciano; Mandić, Igor; Mandrysch, Rocco; Maneira, José; Mangeard, Pierre-Simon; Manhaes de Andrade Filho, Luciano; Manjavidze, Ioseb; Mann, Alexander; Manning, Peter; Manousakis-Katsikakis, Arkadios; Mansoulie, Bruno; Manz, Andreas; Mapelli, Alessandro; Mapelli, Livio; March, Luis; Marchand, Jean-Francois; Marchese, Fabrizio; Marchiori, Giovanni; Marcisovsky, Michal; Marin, Alexandru; Marino, Christopher; Marroquim, Fernando; Marshall, Robin; Marshall, Zach; Martens, Kalen; Marti-Garcia, Salvador; Martin, Andrew; Martin, Brian; Martin, Brian Thomas; Martin, Franck Francois; Martin, Jean-Pierre; Martin, Philippe; Martin, Tim; Martin, Victoria Jane; Martin dit Latour, Bertrand; Martin-Haugh, Stewart; Martinez, Mario; Martinez Outschoorn, Verena; Martyniuk, Alex; Marx, Marilyn; Marzano, Francesco; Marzin, Antoine; Masetti, Lucia; Mashimo, Tetsuro; Mashinistov, Ruslan; Masik, Jiri; Maslennikov, Alexey; Massa, Ignazio; Massaro, Graziano; Massol, Nicolas; Mastrandrea, Paolo; Mastroberardino, Anna; Masubuchi, Tatsuya; Mathes, Markus; Matricon, Pierre; Matsumoto, Hiroshi; Matsunaga, Hiroyuki; Matsushita, Takashi; Mattravers, Carly; Maugain, Jean-Marie; Maurer, Julien; Maxfield, Stephen; Maximov, Dmitriy; May, Edward; Mayne, Anna; Mazini, Rachid; Mazur, Michael; Mazzanti, Marcello; Mazzoni, Enrico; Mc Kee, Shawn Patrick; McCarn, Allison; McCarthy, Robert; McCarthy, Tom; McCubbin, Norman; McFarlane, Kenneth; Mcfayden, Josh; McGlone, Helen; Mchedlidze, Gvantsa; McLaren, Robert Andrew; Mclaughlan, Tom; McMahon, Steve; McPherson, Robert; Meade, Andrew; Mechnich, Joerg; Mechtel, Markus; Medinnis, Mike; Meera-Lebbai, Razzak; Meguro, Tatsuma; Mehdiyev, Rashid; Mehlhase, Sascha; Mehta, Andrew; Meier, Karlheinz; Meirose, Bernhard; Melachrinos, Constantinos; Mellado Garcia, Bruce Rafael; Mendoza Navas, Luis; Meng, Zhaoxia; Mengarelli, Alberto; Menke, Sven; Menot, Claude; Meoni, Evelin; Mercurio, Kevin Michael; Mermod, Philippe; Merola, Leonardo; Meroni, Chiara; Merritt, Frank; Messina, Andrea; Metcalfe, Jessica; Mete, Alaettin Serhan; Meyer, Carsten; Meyer, Christopher; Meyer, Jean-Pierre; Meyer, Jochen; Meyer, Joerg; Meyer, Thomas Christian; Meyer, W Thomas; Miao, Jiayuan; Michal, Sebastien; Micu, Liliana; Middleton, Robin; Migas, Sylwia; Mijović, Liza; Mikenberg, Giora; Mikestikova, Marcela; Mikuž, Marko; Miller, David; Miller, Robert; Mills, Bill; Mills, Corrinne; Milov, Alexander; Milstead, David; Milstein, Dmitry; Minaenko, Andrey; Miñano Moya, Mercedes; Minashvili, Irakli; Mincer, Allen; Mindur, Bartosz; Mineev, Mikhail; Ming, Yao; Mir, Lluisa-Maria; Mirabelli, Giovanni; Miralles Verge, Lluis; Misiejuk, Andrzej; Mitrevski, Jovan; Mitrofanov, Gennady; Mitsou, Vasiliki A; Mitsui, Shingo; Miyagawa, Paul; Miyazaki, Kazuki; Mjörnmark, Jan-Ulf; Moa, Torbjoern; Mockett, Paul; Moed, Shulamit; Moeller, Victoria; Mönig, Klaus; Möser, Nicolas; Mohapatra, Soumya; Mohr, Wolfgang; Mohrdieck-Möck, Susanne; Moisseev, Artemy; Moles-Valls, Regina; Molina-Perez, Jorge; Monk, James; Monnier, Emmanuel; Montesano, Simone; Monticelli, Fernando; Monzani, Simone; Moore, Roger; Moorhead, Gareth; Mora Herrera, Clemencia; Moraes, Arthur; Morange, Nicolas; Morel, Julien; Morello, Gianfranco; Moreno, Deywis; Moreno Llácer, María; Morettini, Paolo; Morii, Masahiro; Morin, Jerome; Morley, Anthony Keith; Mornacchi, Giuseppe; Morozov, Sergey; Morris, John; Morvaj, Ljiljana; Moser, Hans-Guenther; Mosidze, Maia; Moss, Josh; Mount, Richard; Mountricha, Eleni; Mouraviev, Sergei; Moyse, Edward; Mudrinic, Mihajlo; Mueller, Felix; Mueller, James; Mueller, Klemens; Müller, Thomas; Mueller, Timo; Muenstermann, Daniel; Muir, Alex; Munwes, Yonathan; Murray, Bill; Mussche, Ido; Musto, Elisa; Myagkov, Alexey; Myska, Miroslav; Nadal, Jordi; Nagai, Koichi; Nagano, Kunihiro; Nagasaka, Yasushi; Nagel, Martin; Nairz, Armin Michael; Nakahama, Yu; Nakamura, Koji; Nakamura, Tomoaki; Nakano, Itsuo; Nanava, Gizo; Napier, Austin; Narayan, Rohin; Nash, Michael; Nation, Nigel; Nattermann, Till; Naumann, Thomas; Navarro, Gabriela; Neal, Homer; Nebot, Eduardo; Nechaeva, Polina; Negri, Andrea; Negri, Guido; Nektarijevic, Snezana; Nelson, Andrew; Nelson, Silke; Nelson, Timothy Knight; Nemecek, Stanislav; Nemethy, Peter; Nepomuceno, Andre Asevedo; Nessi, Marzio; Neubauer, Mark; Neusiedl, Andrea; Neves, Ricardo; Nevski, Pavel; Newman, Paul; Nguyen Thi Hong, Van; Nickerson, Richard; Nicolaidou, Rosy; Nicolas, Ludovic; Nicquevert, Bertrand; Niedercorn, Francois; Nielsen, Jason; Niinikoski, Tapio; Nikiforou, Nikiforos; Nikiforov, Andriy; Nikolaenko, Vladimir; Nikolaev, Kirill; Nikolic-Audit, Irena; Nikolics, Katalin; Nikolopoulos, Konstantinos; Nilsen, Henrik; Nilsson, Paul; Ninomiya, Yoichi; Nisati, Aleandro; Nishiyama, Tomonori; Nisius, Richard; Nodulman, Lawrence; Nomachi, Masaharu; Nomidis, Ioannis; Nordberg, Markus; Nordkvist, Bjoern; Norton, Peter; Novakova, Jana; Nozaki, Mitsuaki; Nozka, Libor; Nugent, Ian Michael; Nuncio-Quiroz, Adriana-Elizabeth; Nunes Hanninger, Guilherme; Nunnemann, Thomas; Nurse, Emily; Nyman, Tommi; O'Brien, Brendan Joseph; O'Neale, Steve; O'Neil, Dugan; O'Shea, Val; Oakes, Louise Beth; Oakham, Gerald; Oberlack, Horst; Ocariz, Jose; Ochi, Atsuhiko; Oda, Susumu; Odaka, Shigeru; Odier, Jerome; Ogren, Harold; Oh, Alexander; Oh, Seog; Ohm, Christian; Ohshima, Takayoshi; Ohshita, Hidetoshi; Ohsugi, Takashi; Okada, Shogo; Okawa, Hideki; Okumura, Yasuyuki; Okuyama, Toyonobu; Olariu, Albert; Olcese, Marco; Olchevski, Alexander; Oliveira, Miguel Alfonso; Oliveira Damazio, Denis; Oliver Garcia, Elena; Olivito, Dominick; Olszewski, Andrzej; Olszowska, Jolanta; Omachi, Chihiro; Onofre, António; Onyisi, Peter; Oram, Christopher; Oreglia, Mark; Oren, Yona; Orestano, Domizia; Orlov, Iliya; Oropeza Barrera, Cristina; Orr, Robert; Osculati, Bianca; Ospanov, Rustem; Osuna, Carlos; Otero y Garzon, Gustavo; Ottersbach, John; Ouchrif, Mohamed; Ouellette, Eric; Ould-Saada, Farid; Ouraou, Ahmimed; Ouyang, Qun; Ovcharova, Ana; Owen, Mark; Owen, Simon; Ozcan, Veysi Erkcan; Ozturk, Nurcan; Pacheco Pages, Andres; Padilla Aranda, Cristobal; Pagan Griso, Simone; Paganis, Efstathios; Paige, Frank; Pais, Preema; Pajchel, Katarina; Palacino, Gabriel; Paleari, Chiara; Palestini, Sandro; Pallin, Dominique; Palma, Alberto; Palmer, Jody; Pan, Yibin; Panagiotopoulou, Evgenia; Panes, Boris; Panikashvili, Natalia; Panitkin, Sergey; Pantea, Dan; Panuskova, Monika; Paolone, Vittorio; Papadelis, Aras; Papadopoulou, Theodora; Paramonov, Alexander; Park, Woochun; Parker, Andy; Parodi, Fabrizio; Parsons, John; Parzefall, Ulrich; Pasqualucci, Enrico; Passaggio, Stefano; Passeri, Antonio; Pastore, Fernanda; Pastore, Francesca; Pásztor, Gabriella; Pataraia, Sophio; Patel, Nikhul; Pater, Joleen; Patricelli, Sergio; Pauly, Thilo; Pecsy, Martin; Pedraza Morales, Maria Isabel; Peleganchuk, Sergey; Peng, Haiping; Pengo, Ruggero; Penson, Alexander; Penwell, John; Perantoni, Marcelo; Perez, Kerstin; Perez Cavalcanti, Tiago; Perez Codina, Estel; Pérez García-Estañ, María Teresa; Perez Reale, Valeria; Perini, Laura; Pernegger, Heinz; Perrino, Roberto; Perrodo, Pascal; Persembe, Seda; Perus, Antoine; Peshekhonov, Vladimir; Peters, Krisztian; Petersen, Brian; Petersen, Jorgen; Petersen, Troels; Petit, Elisabeth; Petridis, Andreas; Petridou, Chariclia; Petrolo, Emilio; Petrucci, Fabrizio; Petschull, Dennis; Petteni, Michele; Pezoa, Raquel; Phan, Anna; Phillips, Peter William; Piacquadio, Giacinto; Piccaro, Elisa; Piccinini, Maurizio; Piec, Sebastian Marcin; Piegaia, Ricardo; Pignotti, David; Pilcher, James; Pilkington, Andrew; Pina, João Antonio; Pinamonti, Michele; Pinder, Alex; Pinfold, James; Ping, Jialun; Pinto, Belmiro; Pirotte, Olivier; Pizio, Caterina; Plamondon, Mathieu; Pleier, Marc-Andre; Pleskach, Anatoly; Poblaguev, Andrei; Poddar, Sahill; Podlyski, Fabrice; Poggioli, Luc; Poghosyan, Tatevik; Pohl, Martin; Polci, Francesco; Polesello, Giacomo; Policicchio, Antonio; Polini, Alessandro; Poll, James; Polychronakos, Venetios; Pomarede, Daniel Marc; Pomeroy, Daniel; Pommès, Kathy; Pontecorvo, Ludovico; Pope, Bernard; Popeneciu, Gabriel Alexandru; Popovic, Dragan; Poppleton, Alan; Portell Bueso, Xavier; Posch, Christoph; Pospelov, Guennady; Pospisil, Stanislav; Potrap, Igor; Potter, Christina; Potter, Christopher; Poulard, Gilbert; Poveda, Joaquin; Prabhu, Robindra; Pralavorio, Pascal; Pranko, Aliaksandr; Prasad, Srivas; Pravahan, Rishiraj; Prell, Soeren; Pretzl, Klaus Peter; Pribyl, Lukas; Price, Darren; Price, Joe; Price, Lawrence; Price, Michael John; Prieur, Damien; Primavera, Margherita; Prokofiev, Kirill; Prokoshin, Fedor; Protopopescu, Serban; Proudfoot, James; Prudent, Xavier; Przybycien, Mariusz; Przysiezniak, Helenka; Psoroulas, Serena; Ptacek, Elizabeth; Pueschel, Elisa; Purdham, John; Purohit, Milind; Puzo, Patrick; Pylypchenko, Yuriy; Qian, Jianming; Qian, Zuxuan; Qin, Zhonghua; Quadt, Arnulf; Quarrie, David; Quayle, William; Quinonez, Fernando; Raas, Marcel; Radescu, Voica; Radics, Balint; Radloff, Peter; Rador, Tonguc; Ragusa, Francesco; Rahal, Ghita; Rahimi, Amir; Rahm, David; Rajagopalan, Srinivasan; Rammensee, Michael; Rammes, Marcus; Randle-Conde, Aidan Sean; Randrianarivony, Koloina; Ratoff, Peter; Rauscher, Felix; Raymond, Michel; Read, Alexander Lincoln; Rebuzzi, Daniela; Redelbach, Andreas; Redlinger, George; Reece, Ryan; Reeves, Kendall; Reichold, Armin; Reinherz-Aronis, Erez; Reinsch, Andreas; Reisinger, Ingo; Reljic, Dusan; Rembser, Christoph; Ren, Zhongliang; Renaud, Adrien; Renkel, Peter; Rescigno, Marco; Resconi, Silvia; Resende, Bernardo; Reznicek, Pavel; Rezvani, Reyhaneh; Richards, Alexander; Richter, Robert; Richter-Was, Elzbieta; Ridel, Melissa; Rijpstra, Manouk; Rijssenbeek, Michael; Rimoldi, Adele; Rinaldi, Lorenzo; Rios, Ryan Randy; Riu, Imma; Rivoltella, Giancesare; Rizatdinova, Flera; Rizvi, Eram; Robertson, Steven; Robichaud-Veronneau, Andree; Robinson, Dave; Robinson, James; Robinson, Mary; Robson, Aidan; Rocha de Lima, Jose Guilherme; Roda, Chiara; Roda Dos Santos, Denis; Rodriguez, Diego; Roe, Adam; Roe, Shaun; Røhne, Ole; Rojo, Victoria; Rolli, Simona; Romaniouk, Anatoli; Romano, Marino; Romanov, Victor; Romeo, Gaston; Romero Adam, Elena; Roos, Lydia; Ros, Eduardo; Rosati, Stefano; Rosbach, Kilian; Rose, Anthony; Rose, Matthew; Rosenbaum, Gabriel; Rosenberg, Eli; Rosendahl, Peter Lundgaard; Rosenthal, Oliver; Rosselet, Laurent; Rossetti, Valerio; Rossi, Elvira; Rossi, Leonardo Paolo; Rotaru, Marina; Roth, Itamar; Rothberg, Joseph; Rousseau, David; Royon, Christophe; Rozanov, Alexander; Rozen, Yoram; Ruan, Xifeng; Rubinskiy, Igor; Ruckert, Benjamin; Ruckstuhl, Nicole; Rud, Viacheslav; Rudolph, Christian; Rudolph, Gerald; Rühr, Frederik; Ruggieri, Federico; Ruiz-Martinez, Aranzazu; Rumiantsev, Viktor; Rumyantsev, Leonid; Runge, Kay; Rurikova, Zuzana; Rusakovich, Nikolai; Rust, Dave; Rutherfoord, John; Ruwiedel, Christoph; Ruzicka, Pavel; Ryabov, Yury; Ryadovikov, Vasily; Ryan, Patrick; Rybar, Martin; Rybkin, Grigori; Ryder, Nick; Rzaeva, Sevda; Saavedra, Aldo; Sadeh, Iftach; Sadrozinski, Hartmut; Sadykov, Renat; Safai Tehrani, Francesco; Sakamoto, Hiroshi; Salamanna, Giuseppe; Salamon, Andrea; Saleem, Muhammad; Salihagic, Denis; Salnikov, Andrei; Salt, José; Salvachua Ferrando, Belén; Salvatore, Daniela; Salvatore, Pasquale Fabrizio; Salvucci, Antonio; 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Swedish, Stephen; Sykora, Ivan; Sykora, Tomas; Szeless, Balazs; Sánchez, Javier; Ta, Duc; Tackmann, Kerstin; Taffard, Anyes; Tafirout, Reda; Taiblum, Nimrod; Takahashi, Yuta; Takai, Helio; Takashima, Ryuichi; Takeda, Hiroshi; Takeshita, Tohru; Takubo, Yosuke; Talby, Mossadek; Talyshev, Alexey; Tamsett, Matthew; Tanaka, Junichi; Tanaka, Reisaburo; Tanaka, Satoshi; Tanaka, Shuji; Tanaka, Yoshito; Tanasijczuk, Andres Jorge; Tani, Kazutoshi; Tannoury, Nancy; Tappern, Geoffrey; Tapprogge, Stefan; Tardif, Dominique; Tarem, Shlomit; Tarrade, Fabien; Tartarelli, Giuseppe Francesco; Tas, Petr; Tasevsky, Marek; Tassi, Enrico; Tatarkhanov, Mous; Tayalati, Yahya; Taylor, Christopher; Taylor, Frank; Taylor, Geoffrey; Taylor, Wendy; Teinturier, Marthe; Teixeira Dias Castanheira, Matilde; Teixeira-Dias, Pedro; Temming, Kim Katrin; Ten Kate, Herman; Teng, Ping-Kun; Terada, Susumu; Terashi, Koji; Terron, Juan; Testa, Marianna; Teuscher, Richard; Thadome, Jocelyn; Therhaag, Jan; Theveneaux-Pelzer, Timothée; Thioye, Moustapha; Thoma, Sascha; Thomas, Juergen; Thompson, Emily; Thompson, Paul; Thompson, Peter; Thompson, Stan; Thomson, Evelyn; Thomson, Mark; Thun, Rudolf; Tian, Feng; Tibbetts, Mark James; Tic, Tomáš; Tikhomirov, Vladimir; Tikhonov, Yury; Timoshenko, Sergey; Tipton, Paul; Tique Aires Viegas, Florbela De Jes; Tisserant, Sylvain; Toczek, Barbara; Todorov, Theodore; Todorova-Nova, Sharka; Toggerson, Brokk; Tojo, Junji; Tokár, Stanislav; Tokunaga, Kaoru; Tokushuku, Katsuo; Tollefson, Kirsten; Tomoto, Makoto; Tompkins, Lauren; Toms, Konstantin; Tong, Guoliang; Tonoyan, Arshak; Topfel, Cyril; Topilin, Nikolai; Torchiani, Ingo; Torrence, Eric; Torres, Heberth; Torró Pastor, Emma; Toth, Jozsef; Touchard, Francois; Tovey, Daniel; Trefzger, Thomas; Tremblet, Louis; Tricoli, Alesandro; Trigger, Isabel Marian; Trincaz-Duvoid, Sophie; Trinh, Thi Nguyet; Tripiana, Martin; Trischuk, William; Trivedi, Arjun; Trocmé, Benjamin; Troncon, Clara; Trottier-McDonald, Michel; Trzebinski, Maciej; Trzupek, Adam; 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van der Poel, Egge; van der Ster, Daniel; van Eldik, Niels; van Gemmeren, Peter; van Kesteren, Zdenko; van Vulpen, Ivo; Vanadia, Marco; Vandelli, Wainer; Vandoni, Giovanna; Vaniachine, Alexandre; Vankov, Peter; Vannucci, Francois; Varela Rodriguez, Fernando; Vari, Riccardo; Varnes, Erich; Varouchas, Dimitris; Vartapetian, Armen; Varvell, Kevin; Vassilakopoulos, Vassilios; Vazeille, Francois; Vegni, Guido; Veillet, Jean-Jacques; Vellidis, Constantine; Veloso, Filipe; Veness, Raymond; Veneziano, Stefano; Ventura, Andrea; Ventura, Daniel; Venturi, Manuela; Venturi, Nicola; Vercesi, Valerio; Verducci, Monica; Verkerke, Wouter; Vermeulen, Jos; Vest, Anja; Vetterli, Michel; Vichou, Irene; Vickey, Trevor; Vickey Boeriu, Oana Elena; Viehhauser, Georg; Viel, Simon; Villa, Mauro; Villaplana Perez, Miguel; Vilucchi, Elisabetta; Vincter, Manuella; Vinek, Elisabeth; Vinogradov, Vladimir; Virchaux, Marc; Virzi, Joseph; Vitells, Ofer; Viti, Michele; Vivarelli, Iacopo; Vives Vaque, Francesc; Vlachos, Sotirios; 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Zeman, Martin; Zemla, Andrzej; Zendler, Carolin; Zenin, Oleg; Ženiš, Tibor; Zinonos, Zinonas; Zenz, Seth; Zerwas, Dirk; Zevi della Porta, Giovanni; Zhan, Zhichao; Zhang, Dongliang; Zhang, Huaqiao; Zhang, Jinlong; Zhang, Xueyao; Zhang, Zhiqing; Zhao, Long; Zhao, Tianchi; Zhao, Zhengguo; Zhemchugov, Alexey; Zheng, Shuchen; Zhong, Jiahang; Zhou, Bing; Zhou, Ning; Zhou, Yue; Zhu, Cheng Guang; Zhu, Hongbo; Zhu, Junjie; Zhu, Yingchun; Zhuang, Xuai; Zhuravlov, Vadym; Zieminska, Daria; Zimmermann, Robert; Zimmermann, Simone; Zimmermann, Stephanie; Ziolkowski, Michael; Zitoun, Robert; Živković, Lidija; Zmouchko, Viatcheslav; Zobernig, Georg; Zoccoli, Antonio; Zolnierowski, Yves; Zsenei, Andras; zur Nedden, Martin; Zutshi, Vishnu; Zwalinski, Lukasz

2012-01-01

This paper presents a measurement of the ordering of charged hadrons in the azimuthal angle relative to the beam axis in high-energy proton-proton collisions at the Large Hadron Collider (LHC). A spectral analysis of correlations between longitudinal and transverse components of the momentum of the charged hadrons, driven by the search for phenomena related to the structure of the QCD field, is performed. Data were recorded with the ATLAS detector at centre-of-mass energies of $\\sqrt{s}$ = 900 GeV and $\\sqrt{s}$ = 7 TeV. The correlations measured in a phase space region dominated by low-pT particles are not well described by conventional models of hadron production. The measured spectra show features consistent with the fragmentation of a QCD string represented by a helix-like ordered gluon chain.

139La and 63Cu NMR investigation of charge order in La2CuO4 +y (Tc=42 K)

Science.gov (United States)

Imai, T.; Lee, Y. S.

2018-03-01

We report 139La and 63Cu NMR investigation of the successive charge order, spin order, and superconducting transitions in superoxygenated La2CuO4 +y single crystal with stage-4 excess oxygen order at Tstage≃290 K. We show that the stage-4 order induces tilting of CuO6 octahedra below Tstage, which in turn causes 139La NMR line broadening. The structural distortion continues to develop far below Tstage, and completes at Tcharge≃60 K, where charge order sets in. This sequence is reminiscent of the the charge-order transition in Nd codoped La1.88Sr0.12CuO4 that sets in once the low-temperature tetragonal phase is established. We also show that the paramagnetic 63Cu NMR signals are progressively wiped out below Tcharge due to enhanced low-frequency spin fluctuations in charge-ordered domains, but the residual 63Cu NMR signals continue to exhibit the characteristics expected for optimally doped superconducting CuO2 planes. This indicates that charge order in La2CuO4 +y does not take place uniformly in space. In addition, unlike the typical second-order magnetic phase transitions, low-frequency Cu spin fluctuations as probed by 139La nuclear spin-lattice relaxation rate do not exhibit critical divergence at Tspin(≃Tc ) =42 K. These findings, including the spatially inhomogeneous nature of the charge-ordered state, are qualitatively similar to the case of La1.885Sr0.115CuO4 [Imai et al., Phys. Rev. B 96, 224508 (2017), 10.1103/PhysRevB.96.224508 and Arsenault et al., Phys. Rev. B 97, 064511 (2018), 10.1103/PhysRevB.97.064511], but both charge and spin order take place more sharply in the present case.

Frequency effects on charge ordering in Y0.5Ca0.5MnO3 by impedance spectroscopy

Science.gov (United States)

Sarwar, Tuba; Qamar, Afzaal; Nadeem, Muhammad

2015-02-01

In this work, structural and electrical properties of Y0.5Ca0.5MnO3 are investigated by employing X-ray diffraction and impedance spectroscopy, respectively. Applied ac electric field showed the charge ordering transition temperature around 265 K and below this temperature the heteromorphic behavior of the sample is discussed in the proximity of TCO. With frequency effects the volume of robust charge orbital ordering (COO) domains diminishes due to different competing phases along with Jahn Teller distortions. Comprehensive melting and collapse of charge orbital ordering occurs below TN(125 K), where a colossal drop in the value of impedance is observed. The change in profile of modulus plane plots determines the spreading of relaxation time of intermingled phases. Hopping mechanism is elaborated in terms of strong electron phonon coupling. Variable range hopping model and Arrhenius model are used to discuss the short and long range hopping between Mn3+ and Mn4+ channels assessing the activation energy Ea.

Modeling and analysis of LiFePO4/Carbon battery considering two-phase transition during galvanostatic charging/discharging

International Nuclear Information System (INIS)

Li, Xueyan; Xiao, Meng; Choe, Song-Yul; Joe, Won Tae

2015-01-01

Highlights: • Reduced order model for LiFePO 4 particles considering two-phase transition • Model validation with experimental results of current and voltage • Analysis of two-phase transition and path dependence - Abstract: Batteries with lithium iron phosphate (LFP) cathode and carbon anode have shown various advantages over those with other chemistries, but the plateau and path dependence caused by the two-phase transition taking place during charging and discharging make it difficult to estimate the states of battery. Thus, based on electrochemical principles we propose a new reduced order model that has been validated against experimental data obtained during galvanostatic charging/discharging. The mechanism of the two-phase transition during lithiation and delithiation in LFP particles is approximated using a shrinking corewith a moving interface between the two phases and is described by modified diffusion equations that take into account multiple layers formed within LFP particles. The shrinking core model is integrated into a cell model developed previously, which is used to analyze the path dependence at different load profiles. The results show that the model is capable of representing the characteristics of the plateau and path dependence. Particularly, the available charge at a certain State of Charge (SOC) varies dependent upon paths to reach the SOC. When an initial SOC is reached by discharging, the cell can accept more charges during charging, while when an initial SOC is reached by charging, more charge will be available during discharging

Charge and current orders in the spin-fermion model with overlapping hot spots

Science.gov (United States)

Volkov, Pavel A.; Efetov, Konstantin B.

2018-04-01

Experiments carried over the last years on the underdoped cuprates have revealed a variety of symmetry-breaking phenomena in the pseudogap state. Charge-density waves, breaking of C4 rotational symmetry as well as time-reversal symmetry breaking have all been observed in several cuprate families. In this regard, theoretical models where multiple nonsuperconducting orders emerge are of particular interest. We consider the recently introduced [Volkov and Efetov, Phys. Rev. B 93, 085131 (2016), 10.1103/PhysRevB.93.085131] spin-fermion model with overlapping `hot spots' on the Fermi surface. Focusing on the particle-hole instabilities we obtain a rich phase diagram with the chemical potential relative to the dispersion at (0 ,π );(π ,0 ) and the Fermi surface curvature in the antinodal regions being the control parameters. We find evidence for d-wave Pomeranchuk instability, d-form factor charge density waves, as well as commensurate and incommensurate staggered bond current phases similar to the d-density wave state. The current orders are found to be promoted by the curvature. Considering the appropriate parameter range for the hole-doped cuprates, we discuss the relation of our results to the pseudogap state and incommensurate magnetic phases of the cuprates.

Charge ordering and opening of spin gap in NaV2O5

NARCIS (Netherlands)

Mostovoy, M.V.; Khomskii, D.I.

1999-01-01

We argue that the origin of the phase transition in quasi-one-dimensional antiferromagnet NaV2O5 is not the spin-Peierls (SP) instability, but a charge ordering. The opening of the spin gap and the lattice dimerization, characteristic for the spin-Peierls systems, in NaV2O5 result from the interplay

Doping dependence of charge order in electron-doped cuprate superconductors

Science.gov (United States)

Mou, Yingping; Feng, Shiping

2017-12-01

In the recent studies of the unconventional physics in cuprate superconductors, one of the central issues is the interplay between charge order and superconductivity. Here the mechanism of the charge-order formation in the electron-doped cuprate superconductors is investigated based on the t-J model. The experimentally observed momentum dependence of the electron quasiparticle scattering rate is qualitatively reproduced, where the scattering rate is highly anisotropic in momentum space, and is intriguingly related to the charge-order gap. Although the scattering strength appears to be weakest at the hot spots, the scattering in the antinodal region is stronger than that in the nodal region, which leads to the original electron Fermi surface is broken up into the Fermi pockets and their coexistence with the Fermi arcs located around the nodal region. In particular, this electron Fermi surface instability drives the charge-order correlation, with the charge-order wave vector that matches well with the wave vector connecting the hot spots, as the charge-order correlation in the hole-doped counterparts. However, in a striking contrast to the hole-doped case, the charge-order wave vector in the electron-doped side increases in magnitude with the electron doping. The theory also shows the existence of a quantitative link between the single-electron fermiology and the collective response of the electron density.

First- and second-order charged particle optics

International Nuclear Information System (INIS)

Brown, K.L.; Servranckx, R.V.

1984-07-01

Since the invention of the alternating gradient principle there has been a rapid evolution of the mathematics and physics techniques applicable to charged particle optics. In this publication we derive a differential equation and a matrix algebra formalism valid to second-order to present the basic principles governing the design of charged particle beam transport systems. A notation first introduced by John Streib is used to convey the essential principles dictating the design of such beam transport systems. For example the momentum dispersion, the momentum resolution, and all second-order aberrations are expressed as simple integrals of the first-order trajectories (matrix elements) and of the magnetic field parameters (multipole components) characterizing the system. 16 references, 30 figures

The Roles of Structural Order and Intermolecular Interactions in Determining Ionization Energies and Charge-Transfer State Energies in Organic Semiconductors

KAUST Repository

Graham, Kenneth

2016-08-17

The energy landscape in organic semiconducting materials greatly influences charge and exciton behavior, which are both critical to the operation of organic electronic devices. These energy landscapes can change dramatically depending on the phases of material present, including pure phases of one molecule or polymer and mixed phases exhibiting different degrees of order and composition. In this work, ultraviolet photoelectron spectroscopy measurements of ionization energies (IEs) and external quantum efficiency measurements of charge-transfer (CT) state energies (ECT) are applied to molecular photovoltaic material systems to characterize energy landscapes. The results show that IEs and ECT values are highly dependent on structural order and phase composition. In the sexithiophene:C60 system both the IEs of sexithiophene and C60 shift by over 0.4 eV while ECT shifts by 0.5 eV depending on molecular composition. By contrast, in the rubrene:C60 system the IE of rubrene and C60 vary by ≤0.11 eV and ECT varies by ≤0.04 eV as the material composition varies. These results suggest that energy landscapes can exist whereby the binding energies of the CT states are overcome by energy offsets between charges in CT states in mixed regions and free charges in pure phases. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Charge order-superfluidity transition in a two-dimensional system of hard-core bosons and emerging domain structures

Science.gov (United States)

Moskvin, A. S.; Panov, Yu. D.; Rybakov, F. N.; Borisov, A. B.

2017-11-01

We have used high-performance parallel computations by NVIDIA graphics cards applying the method of nonlinear conjugate gradients and Monte Carlo method to observe directly the developing ground state configuration of a two-dimensional hard-core boson system with decrease in temperature, and its evolution with deviation from a half-filling. This has allowed us to explore unconventional features of a charge order—superfluidity phase transition, specifically, formation of an irregular domain structure, emergence of a filamentary superfluid structure that condenses within of the charge-ordered phase domain antiphase boundaries, and formation and evolution of various topological structures.

Multiferroic nature of charge-ordered rare earth manganites

International Nuclear Information System (INIS)

Serrao, Claudy Rayan; Sundaresan, A; Rao, C N R

2007-01-01

Charge-ordered rare earth manganites Nd 0.5 Ca 0.5 MnO 3 ,La 0.25 Nd 0.25 Ca 0.5 MnO 3 , Pr 0.7 Ca 0.3 MnO 3 and Pr 0.6 Ca 0.4 MnO 3 are found to exhibit dielectric constant anomalies around the charge-ordering or the antiferromagnetic transition temperatures. Magnetic fields have a marked effect on the dielectric properties, indicating the presence of coupling between the magnetic and electrical order parameters. The observation of magnetoferroelectricity in these manganites is in accord with the recent theoretical predictions of Khomskii and co-workers

First order and second order fermi acceleration of energetic charged particles by shock waves

International Nuclear Information System (INIS)

Webb, G.M.

1983-01-01

Steady state solutions of the cosmic ray transport equation describing first order Fermi acceleration of energetic charged particles at a plane shock (without losses) and second order Fermi acceleration in the downstream region of the shock are derived. The solutions for the isotropic part of the phase space distribution function are expressible as eigenfunction expansions, being superpositions of series of power law momentum spectra, with the power law indices being the roots of an eigenvalue equation. The above exact analytic solutions are for the case where the spatial diffusion coefficient kappa is independent of momentum. The solutions in general depend on the shock compression ratio, the modulation parameters V 1 L/kappa 1 , V 2 L/kappa 2 (V is the plasma velocity, kappa is the energetic particle diffusion coefficient, and L a characteristic length over which second order Fermi acceleration is effective) in the upstream and downstream regions of the shock, respectively, and also on a further dimensionless parameter, zeta, characterizing second order Fermi acceleration. In the limit as zeta→0 (no second order Fermi acceleration) the power law momentum spectrum characteristic of first order Fermi acceleration (depending only on the shock compression ratio) obtained previously is recovered. Perturbation solutions for the case where second order Fermi effects are small, and for realistic diffusion coefficients (kappainfinityp/sup a/, a>0, p = particle momentum), applicable at high momenta, are also obtained

Nonequilibrium response of an electron-mediated charge density wave ordered material to a large dc electric field

Science.gov (United States)

Matveev, O. P.; Shvaika, A. M.; Devereaux, T. P.; Freericks, J. K.

2016-01-01

Using the Kadanoff-Baym-Keldysh formalism, we employ nonequilibrium dynamical mean-field theory to exactly solve for the nonlinear response of an electron-mediated charge-density-wave-ordered material. We examine both the dc current and the order parameter of the conduction electrons as the ordered system is driven by the electric field. Although the formalism we develop applies to all models, for concreteness, we examine the charge-density-wave phase of the Falicov-Kimball model, which displays a number of anomalous behaviors including the appearance of subgap density of states as the temperature increases. These subgap states should have a significant impact on transport properties, particularly the nonlinear response of the system to a large dc electric field.

Uniaxial-Strain-Orientation Dependence of the Competition between Mott and Charge Ordered Phases and their Corresponding Superconductivity of β-(BDA-TTP)2I3

Science.gov (United States)

Nuruzzaman, Md.; Yokogawa, Keiichi; Yoshino, Harukazu; Yoshimoto, Haruo; Kikuchi, Koichi; Kaihatsu, Takayuki; Yamada, Jun-ichi; Murata, Keizo

2012-12-01

We studied the electronic transport properties of the charge transfer salt β-(BDA-TTP)2I3 [BDA-TTP: 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene] by applying uniaxial strains along the three crystallographic axes, and obtained three corresponding temperature-pressure phase diagrams. Three phase diagrams were quite dependent on the direction of compression. Following the preceding paper by Kikuchi et al., we speculate that the insulating states are of 1/2-filled Mott insulators for the a- and b-axes compressions, and of 1/4-filled charge ordered states for the c-axis compression as well as hydrostatic pressure. The superconducting phase under uniaxial strain was realized with Tc = 5 K at 1.9 GPa along the a-axis and with Tc = 5.6 K at 1.75 GPa along the b-axis. Superconductivity was also reproduced with a Tc of 9.5 K at 1.0 GPa for the c-axis compressions in the range of 0.85 to 1.53 GPa as previously reported. We studied tentative measurement on upper critical fields, Bc2's of these superconductivities and found that the extrapolated values, Bc2(0)'s, exceeded Pauli-limit by about 2--3 times. However, at least in terms of Bc2, the difference in superconductivity associated with two different insulating states was not clear.

Anomalous columnar order of charged colloidal platelets

Science.gov (United States)

Morales-Anda, L.; Wensink, H. H.; Galindo, A.; Gil-Villegas, A.

2012-01-01

Monte Carlo computer simulations are carried out for a model system of like-charged colloidal platelets in the isothermal-isobaric ensemble (NpT). The aim is to elucidate the role of electrostatic interactions on the structure of synthetic clay systems at high particle densities. Short-range repulsions between particles are described by a suitable hard-core model representing a discotic particle. This potential is supplemented with an electrostatic potential based on a Yukawa model for the screened Coulombic potential between infinitely thin disklike macro-ions. The particle aspect-ratio and electrostatic parameters were chosen to mimic an aqueous dispersion of thin, like-charged, rigid colloidal platelets at finite salt concentration. An examination of the fluid phase diagram reveals a marked shift in the isotropic-nematic transition compared to the hard cut-sphere reference system. Several statistical functions, such as the pair correlation function for the center-of-mass coordinates and structure factor, are obtained to characterize the structural organization of the platelets phases. At low salinity and high osmotic pressure we observe anomalous hexagonal columnar structures characterized by interpenetrating columns with a typical intercolumnar distance corresponding to about half of that of a regular columnar phase. Increasing the ionic strength leads to the formation of glassy, disordered structures consisting of compact clusters of platelets stacked into finite-sized columns. These so-called "nematic columnar" structures have been recently observed in systems of charge-stabilized gibbsite platelets. Our findings are corroborated by an analysis of the static structure factor from a simple density functional theory.

Investigation of magnetic and magneto-transport properties of ferromagnetic-charge ordered core-shell nanostructures

Science.gov (United States)

Das, Kalipada

2017-10-01

In our present study, we address in detail the magnetic and magneto-transport properties of ferromagnetic-charge ordered core-shell nanostructures. In these core-shell nanostructures, well-known half metallic La0.67Sr0.33MnO3 nanoparticles (average particle size, ˜20 nm) are wrapped by the charge ordered antiferromagnetic Pr0.67Ca0.33MnO3 (PCMO) matrix. The intrinsic properties of PCMO markedly modify it into such a core-shell form. The robustness of the PCMO matrix becomes fragile and melts at an external magnetic field (H) of ˜20 kOe. The analysis of magneto-transport data indicates the systematic reduction of the electron-electron and electron-magnon interactions in the presence of an external magnetic field in these nanostructures. The pronounced training effect appears in this phase separated compound, which was analyzed by considering the second order tunneling through the grain boundaries of the nanostructures. Additionally, the analysis of low field magnetoconductance data supports the second order tunneling and shows the close value of the universal limit (˜1.33).

Frequency effects on charge ordering in Y{sub 0.5}Ca{sub 0.5}MnO{sub 3} by impedance spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Sarwar, Tuba, E-mail: sarwartuba@gmail.com [EMMG, Physics Division, PINSTECH, P. O. Nilore, Islamabad (Pakistan); DPAM, PIEAS, P. O. Nilore, Islamabad (Pakistan); Qamar, Afzaal [Queensland Micro-Nanotechnology Centre, Griffith University, Nathan, QLD 4111 (Australia); Nadeem, Muhammad [EMMG, Physics Division, PINSTECH, P. O. Nilore, Islamabad (Pakistan)

2015-02-01

In this work, structural and electrical properties of Y{sub 0.5}Ca{sub 0.5}MnO{sub 3} are investigated by employing X-ray diffraction and impedance spectroscopy, respectively. Applied ac electric field showed the charge ordering transition temperature around 265 K and below this temperature the heteromorphic behavior of the sample is discussed in the proximity of T{sub CO}. With frequency effects the volume of robust charge orbital ordering (COO) domains diminishes due to different competing phases along with Jahn Teller distortions. Comprehensive melting and collapse of charge orbital ordering occurs below T{sub N}(125 K), where a colossal drop in the value of impedance is observed. The change in profile of modulus plane plots determines the spreading of relaxation time of intermingled phases. Hopping mechanism is elaborated in terms of strong electron phonon coupling. Variable range hopping model and Arrhenius model are used to discuss the short and long range hopping between Mn{sup 3+} and Mn{sup 4+} channels assessing the activation energy E{sub a}. - Highlights: • Present study contains a detailed investigation over the electrical and structural properties of Y{sub 0.5}Ca{sub 0.5}MnO{sub 3} especially its behavior across the charge ordering transition. • Impedance measurements illustrate the comprehensive melting and collapse of robust charge orbital ordering with colossal drop in impedance. • In T{sub N}phases indicating the contribution of grain boundary and grain interior. • Variable range hopping model and Arrhenius model are used to discuss the short and long range hopping between Mn{sup 3+} and Mn{sup 4+} channels assessing the activation energy E{sub a}.

Multiferroic nature of charge-ordered rare earth manganites

Energy Technology Data Exchange (ETDEWEB)

Serrao, Claudy Rayan [Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, Bangalore-560064 (India); Sundaresan, A [Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, Bangalore-560064 (India); Rao, C N R [Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, Bangalore-560064 (India)

2007-12-12

Charge-ordered rare earth manganites Nd{sub 0.5}Ca{sub 0.5}MnO{sub 3},La{sub 0.25}Nd{sub 0.25}Ca{sub 0.5}MnO{sub 3}, Pr{sub 0.7}Ca{sub 0.3}MnO{sub 3} and Pr{sub 0.6}Ca{sub 0.4}MnO{sub 3} are found to exhibit dielectric constant anomalies around the charge-ordering or the antiferromagnetic transition temperatures. Magnetic fields have a marked effect on the dielectric properties, indicating the presence of coupling between the magnetic and electrical order parameters. The observation of magnetoferroelectricity in these manganites is in accord with the recent theoretical predictions of Khomskii and co-workers.

A novel magnetoresistance induced by charge ordering in ferromagnetic/charge-ordered/ferromagnetic trilayers

Science.gov (United States)

Wang, Haiou; Li, Jinwei; Su, Kunpeng; Huo, Dexuan; Tan, Weishi

2015-10-01

Microstructure, magnetoresistance (MR) and magnetic properties of Pr0.7Sr0.3MnO3/La0.5Ca0.5MnO3/Pr0.7Sr0.3MnO3 trilayers, which are shown to be tunable with different La0.5Ca0.5MnO3 spacer thickness, are investigated. The trilayer with 6 nm thick La0.5Ca0.5MnO3 spacer show \\text{MR}∼37{%} at 195 K in 1 T and \\text{MR}∼80{%} at 220 K in 9 T, which is realized through the double-exchange mechanism. In contrast, trilayers with the thicker La0.5Ca0.5MnO3 spacer show enhanced MR at a wide low-temperature range. The obtained \\text{MR}∼52{%} at 50 K in 1 T in the trilayer with 18 nm thick La0.5Ca0.5MnO3 spacer is superior to that of other magnetic nanoscales. We surmise that this MR originates in the ferromagnetic/antiferromagnetic competition accompanied with the formation of a charge-ordered antiferromagnetic state and the collapse of the charge-ordered state at the applied magnetic field, rather than in the double-exchange mechanism. Large and tunable MR can be realized by controlling the strain state (the thickness of the La0.5Ca0.5MnO3 spacer), which can be applied in the used devices.

X-cube model on generic lattices: Fracton phases and geometric order

Science.gov (United States)

Slagle, Kevin; Kim, Yong Baek

2018-04-01

Fracton order is a new kind of quantum order characterized by topological excitations that exhibit remarkable mobility restrictions and a robust ground-state degeneracy (GSD) which can increase exponentially with system size. In this paper, we present a generic lattice construction (in three dimensions) for a generalized X-cube model of fracton order, where the mobility restrictions of the subdimensional particles inherit the geometry of the lattice. This helps explain a previous result that lattice curvature can produce a robust GSD, even on a manifold with trivial topology. We provide explicit examples to show that the (zero-temperature) phase of matter is sensitive to the lattice geometry. In one example, the lattice geometry confines the dimension-1 particles to small loops, which allows the fractons to be fully mobile charges, and the resulting phase is equivalent to (3+1)-dimensional toric code. However, the phase is sensitive to more than just lattice curvature; different lattices without curvature (e.g., cubic or stacked kagome lattices) also result in different phases of matter, which are separated by phase transitions. Unintuitively, however, according to a previous definition of phase [X. Chen et al., Phys. Rev. B 82, 155138 (2010), 10.1103/PhysRevB.82.155138], even just a rotated or rescaled cubic results in different phases of matter, which motivates us to propose a coarser definition of phase for gapped ground states and fracton order. This equivalence relation between ground states is given by the composition of a local unitary transformation and a quasi-isometry (which can rotate and rescale the lattice); equivalently, ground states are in the same phase if they can be adiabatically connected by varying both the Hamiltonian and the positions of the degrees of freedom (via a quasi-isometry). In light of the importance of geometry, we further propose that fracton orders should be regarded as a geometric order.

Higgs-mode radiance and charge-density-wave order in 2 H -NbSe2

Science.gov (United States)

Grasset, Romain; Cea, Tommaso; Gallais, Yann; Cazayous, Maximilien; Sacuto, Alain; Cario, Laurent; Benfatto, Lara; Méasson, Marie-Aude

2018-03-01

Despite being usually considered two competing phenomena, charge-density wave and superconductivity coexist in few systems, the most emblematic one being the transition-metal dichalcogenide 2 H -NbSe2 . This unusual condition is responsible for specific Raman signatures across the two phase transitions in this compound. While the appearance of a soft phonon mode is a well-established fingerprint of the charge-density-wave order, the nature of the sharp subgap mode emerging below the superconducting temperature is still under debate. In this work we use external pressure as a knob to unveil the delicate interplay between the two orders, and consequently the nature of the superconducting mode. Thanks to an advanced extreme-conditions Raman technique, we are able to follow the pressure evolution and the simultaneous collapse of the two intertwined charge-density-wave and superconducting modes. The comparison with microscopic calculations in a model system supports the Higgs-type nature of the superconducting mode and suggests that charge-density wave and superconductivity in 2 H -NbSe2 involve mutual electronic degrees of freedom. These findings fill the knowledge gap on the electronic mechanisms at play in transition-metal dichalcogenides, a crucial step to fully exploit their properties in few-layer systems optimized for device applications.

Long-range string orders and topological quantum phase transitions in the one-dimensional quantum compass model.

Science.gov (United States)

Wang, Hai Tao; Cho, Sam Young

2015-01-14

In order to investigate the quantum phase transition in the one-dimensional quantum compass model, we numerically calculate non-local string correlations, entanglement entropy and fidelity per lattice site by using the infinite matrix product state representation with the infinite time evolving block decimation method. In the whole range of the interaction parameters, we find that four distinct string orders characterize the four different Haldane phases and the topological quantum phase transition occurs between the Haldane phases. The critical exponents of the string order parameters β = 1/8 and the cental charges c = 1/2 at the critical points show that the topological phase transitions between the phases belong to an Ising type of universality classes. In addition to the string order parameters, the singularities of the second derivative of the ground state energies per site, the continuous and singular behaviors of the Von Neumann entropy and the pinch points of the fidelity per lattice site manifest that the phase transitions between the phases are of the second-order, in contrast to the first-order transition suggested in previous studies.

Bond index: relation to second-order density matrix and charge fluctuations

International Nuclear Information System (INIS)

Giambiagi, M.S. de; Giambiagi, M.; Jorge, F.E.

1985-01-01

It is shown that, in the same way as the atomic charge is an invariant built from the first-order density matrix, the closed-shell generalized bond index is an invariant associated with the second-order reduced density matrix. The active charge of an atom (sum of bond indices) is shown to be the sum of all density correlation functions between it and the other atoms in the molecule; similarly, the self-charge is the fluctuation of its total charge. (Author) [pt

Approaching Pomeranchuk instabilities from ordered phase: A crossing-symmetric equation method

International Nuclear Information System (INIS)

Reidy, Kelly; Quader, Khandker; Bedell, Kevin

2014-01-01

We explore features of a 3D Fermi liquid near generalized Pomeranchuk instabilities using a tractable crossing-symmetric equation method. We approach the instabilities from the ordered ferromagnetic phase. We find “quantum multi-criticality” as approach to the ferromagnetic instability drives instability in other channel(s). It is found that a charge nematic instability precedes and is driven by Pomeranchuk instabilities in both the ℓ=0 spin and density channels

Charge imbalance waves and nonequilibrium dynamics near a superconducting phase-slip center

International Nuclear Information System (INIS)

Kadin, A.M.; Smith, L.N.; Skocpol, W.J.

1980-01-01

Using a generalized two-fluid picture to describe a quasi-one-dimensional superconductor near T/sub c/, we provide a heuristic derivation for a set of equations governing the temporal and spatial evolution of the charge imbalance (or branch imbalance) in the quasiparticles. We show that these equations are isomorphic to those that describe a simple electrical transmission line, so that charge imbalance waves may propagate in the superconductor in analogy with electrical signals that propagate down the transmission line. We propose as a model for a phase-slip center in a superconducting filament a localized Josephson oscillator coupled to the transmission line. Applying standard transmission-line theory to solve the problem, we show that the Josephson oscillations in the center generate charge imbalance waves that the propagate out to a frequency-dependent distance of the order of the quasiparticle diffusion length GAMMA/sub Q/*= (Dtau/sub Q/*)/sup 1/2/ before they damp out. The time-averaged behavior of the model reduces to the earlier model of Skocpol, Beasley, and Tinkham. A novel consequence of the model is a prediction of intrinsic hysteresis in the dc current--voltage relation. The model also provides a convenient framework for dealing with ac effects in phase-slip centers, including resonance and synchronization in systems of closely spaced phase-slip centers and microbridges

Temperature-dependent vibrational spectroscopy to study order-disorder transitions in charge transfer complexes

Science.gov (United States)

Isaac, Rohan; Goetz, Katelyn P.; Roberts, Drew; Jurchescu, Oana D.; McNeil, L. E.

2018-02-01

Charge-transfer (CT) complexes are a promising class of materials for the semiconductor industry because of their versatile properties. This class of compounds shows a variety of phase transitions, which are of interest because of their potential impact on the electronic characteristics. Here temperature-dependent vibrational spectroscopy is used to study structural phase transitions in a set of organic CT complexes. Splitting and broadening of infrared-active phonons in the complex formed between pyrene and pyromellitic dianhydride (PMDA) confirm the structural transition is of the order-disorder type and complement previous x-ray diffraction (XRD) results. We show that this technique is a powerful tool to characterize transitions, and apply it to a range of binary CT complexes composed of polyaromatic hyrdocarbons (anthracene, perylene, phenanthrene, pyrene, and stilbene) and PMDA. We extend the understanding of transitions in perylene-PMDA and pyrene-PMDA, and show that there are no order-disorder transitions present in anthracene-PMDA, stilbene-PMDA and phenanthrene-PMDA in the temperature range investigated here.

Charge-order driven multiferroic and magneto-dielectric properties of rare earth manganates

International Nuclear Information System (INIS)

Serrao, Claudy Rayan; Sahu, Jyoti Ranjan; Ghosh, Anirban

2010-01-01

Charge-order driven magnetic ferroelectricity is shown to occur in several rare earth manganates of the general formula, Ln 1-x A x MnO 3 (Ln rare earth, A = alkaline earth). Charge-ordered manganates exhibit dielectric constant anomalies around the charge-ordering or the antiferromagnetic transition temperature. Magnetic fields have a marked effect on the dielectric properties of these compounds, indicating the presence of coupling between the magnetic and electrical order parameters. Magneto-dielectric properties are retained in small particles of the manganates. The observation of magneto-ferroelectricity in these manganates is in accordance with theoretical predictions. (author)

Charge ordered insulating phases of DODHT salts with octahedral anions and a new radical salt, β''-(DODHT)2TaF6

Science.gov (United States)

Nishikawa, H.; Oshio, H.; Higa, M.; Kondo, R.; Kagoshima, S.; Nakao, A.; Sawa, H.; Yasuzuka, S.; Murata, K.

2008-10-01

Physical properties of isostructural β''-(DODHT)2X [DODHT = (l,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene; X = PF6, AsF6, and SbF6] at ambient pressure have been compared. The insulating phase of β''-(DODHT)2PF6 salt has already been revealed to be a charge ordering (CO) state by X-ray diffraction study and magnetic behavior. CO in this salt was also confirmed by the observation of satellite reflections in oscillation photograph using synchrotron radiation. Transport property of β''-(DODHT)2SbF6 salt was reinvestigated up to the pressure of 3.7 GPa applied by a cubic anvil apparatus. Although the SbF6 salt turned to be metallic above 2.0 GPa, no superconductivity was observed. In order to examine the anion size dependence of DODHT salts with octahedral anions, we prepared a new DODHT salt, β''-(DODHT)2TaF6, which has the larger counter anion compared with the previous salts. Crystal structure of this salt was isostructural to the other DODHT salts. The electrical and magnetic properties of this salt were similar to those of β''-(DODHT)2SbF6 salt.

Microscopic theory of longitudinal sound velocity in charge ordered manganites

International Nuclear Information System (INIS)

Rout, G C; Panda, S

2009-01-01

A microscopic theory of longitudinal sound velocity in a manganite system is reported here. The manganite system is described by a model Hamiltonian consisting of charge density wave (CDW) interaction in the e g band, an exchange interaction between spins of the itinerant e g band electrons and the core t 2g electrons, and the Heisenberg interaction of the core level spins. The magnetization and the CDW order parameters are considered within mean-field approximations. The phonon Green's function was calculated by Zubarev's technique and hence the longitudinal velocity of sound was finally calculated for the manganite system. The results show that the elastic spring involved in the velocity of sound exhibits strong stiffening in the CDW phase with a decrease in temperature as observed in experiments.

Microscopic theory of longitudinal sound velocity in charge ordered manganites

Energy Technology Data Exchange (ETDEWEB)

Rout, G C [Condensed Matter Physics Group, PG Department of Applied Physics and Ballistics, FM University, Balasore 756 019 (India); Panda, S, E-mail: gcr@iopb.res.i [Trident Academy of Technology, F2/A, Chandaka Industrial Estate, Bhubaneswar 751 024 (India)

2009-10-14

A microscopic theory of longitudinal sound velocity in a manganite system is reported here. The manganite system is described by a model Hamiltonian consisting of charge density wave (CDW) interaction in the e{sub g} band, an exchange interaction between spins of the itinerant e{sub g} band electrons and the core t{sub 2g} electrons, and the Heisenberg interaction of the core level spins. The magnetization and the CDW order parameters are considered within mean-field approximations. The phonon Green's function was calculated by Zubarev's technique and hence the longitudinal velocity of sound was finally calculated for the manganite system. The results show that the elastic spring involved in the velocity of sound exhibits strong stiffening in the CDW phase with a decrease in temperature as observed in experiments.

Chemical approach to neutral-ionic valence instability, quantum phase transition, and relaxor ferroelectricity in organic charge-transfer complexes

International Nuclear Information System (INIS)

Horiuchi, Sachio; Kumai, Reiji; Okimoto, Yoichi; Tokura, Yoshinori

2006-01-01

Neutral-ionic (NI) phase transition is a reversible switching of organic charge-transfer complexes between distinct valence states by external stimuli. This phase transformation in the low-dimensional system is demonstrated to provide a variety of novel dielectric, structural, and electronic properties. Importantly, ionization of the electron donor-acceptor pairs is usually accompanied by a ferroelectric or antiferroelectric order of the molecular lattice, leading to huge dielectric response near the transition point. Although these characteristics are potentially useful for future electronic and optical applications, the thermally accessible NI transition (TINIT) is still an extremely rare case. The TINIT compounds including some new materials are overviewed in order to provide convenient guides to their design and experimental identifications. The phase transition and dielectric properties can be closely controlled in various ways depending on chemical and physical modifications of the crystals. Among them, a quantum phase transition and relaxor ferroelectricity, both of which are currently attracting subjects from both scientific and practical perspectives, are highlighted as the first achievements in organic charge-transfer complexes

Temperature-dependent vibrational spectroscopy to study order-disorder transitions in charge transfer complexes

Directory of Open Access Journals (Sweden)

Rohan Isaac

2018-02-01

Full Text Available Charge-transfer (CT complexes are a promising class of materials for the semiconductor industry because of their versatile properties. This class of compounds shows a variety of phase transitions, which are of interest because of their potential impact on the electronic characteristics. Here temperature-dependent vibrational spectroscopy is used to study structural phase transitions in a set of organic CT complexes. Splitting and broadening of infrared-active phonons in the complex formed between pyrene and pyromellitic dianhydride (PMDA confirm the structural transition is of the order-disorder type and complement previous x-ray diffraction (XRD results. We show that this technique is a powerful tool to characterize transitions, and apply it to a range of binary CT complexes composed of polyaromatic hyrdocarbons (anthracene, perylene, phenanthrene, pyrene, and stilbene and PMDA. We extend the understanding of transitions in perylene-PMDA and pyrene-PMDA, and show that there are no order-disorder transitions present in anthracene-PMDA, stilbene-PMDA and phenanthrene-PMDA in the temperature range investigated here.

On the Origin of Charge Order in RuCl3

Science.gov (United States)

Berlijn, Tom

RuCl3 has been proposed to be a spin-orbit assisted Mott insulator close to the Kitaev-spin-liquid ground state, an exotic state of matter that could protect information in quantum computers. Recent STM experiments [M. Ziatdinov et al, Nature Communications (in press)] however, show the presence of a puzzling short-range charge order in this quasi two dimensional material. Understanding the nature of this charge order may provide a pathway towards tuning RuCl3 into the Kitaev-spin-liquid ground state. Based on first principles calculations I investigate the possibility that the observed charge order is caused by a combination of short-range magnetic correlations and strong spin-orbit coupling. From a general perspective such a mechanism could offer the exciting possibility of probing local magnetic correlations with standard STM. This work was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division.

Surface charge sensing by altering the phase transition in VO2

Science.gov (United States)

Kumar, S.; Esfandyarpour, R.; Davis, R.; Nishi, Y.

2014-08-01

Detection of surface charges has various applications in medicine, electronics, biotechnology, etc. The source of surface charge induction may range from simple charge-polarized molecules like water to complicated proteins. It was recently discovered that surface charge accumulation can alter the temperature at which VO2 undergoes a Mott transition. Here, we deposited polar molecules onto the surface of two-terminal thin-film VO2 lateral devices and monitored the joule-heating-driven Mott transition, or conductance switching. We observed that the power required to induce the conductance switching reduced upon treatment with polar molecules and, using in-situ blackbody-emission direct measurement of local temperature, we show that this reduction in power was accompanied by reduction in the Mott transition temperature. Further evidence suggested that this effect has specificity to the nature of the species used to induce surface charges. Using x-ray absorption spectroscopy, we also show that there is no detectable change in oxidation state of vanadium or structural phase in the bulk of the 40 nm VO2 thin-film even as the phase transition temperature is reduced by up to 20 K by the polar molecules. The ability to alter the phase transition parameters by depositing polar molecules suggests a potential application in sensing surface charges of different origins and this set of results also highlights interesting aspects of the phase transition in VO2.

Coexistence of charge order and antiferromagnetism in (TMTTF){sub 2}SbF{sub 6}: NMR study

Energy Technology Data Exchange (ETDEWEB)

Nomura, K., E-mail: knmr@phys.sci.hokudai.ac.jp; Yamamoto, M.; Matsunaga, N.; Hirose, S.; Shimohara, N.; Satoh, T.; Isome, T.; Liu, Y.; Kawamoto, A.

2015-03-01

The electronic state of (TMTTF){sub 2}SbF{sub 6} was investigated by the {sup 1}H and {sup 13}C NMR measurements. The temperature dependence of T{sub 1}{sup −1} in {sup 1}H NMR shows a sharp peak associated with the antiferromagnetic transition at T{sub AF}=6 K. The temperature dependence of T{sub 1}{sup −1} is described by the power law T{sup 2.4} below T{sub AF}. This suggests the nodal gapless spin wave excitation in antiferromagnetic phase. In {sup 13}C NMR, two sharp peaks at high temperature region, associated with the inner and the outer carbon sites in TMTTF dimer, split into four peaks below 150 K. It indicates that the charge disproportionation occurs. The degree of charge disproportionation Δρ is estimated as (0.25±0.09)e from the chemical shift difference. This value of Δρ is consistent with that obtained from the infrared spectroscopy. In the antiferromagnetic state (AFI), the observed line shape is well fitted by eight Lorentzian peaks. This suggests that the charge order with the same degree still remains in the AF state. From the line assignment, the AF staggered spin amplitude is obtained as 0.70 μ{sub B} and 0.24 μ{sub B} at the charge rich and the poor sites, respectively. These values corresponding to almost 1 μ{sub B} per dimer are quite different from 0.11 μ{sub B} of another AF (AFII) state in (TMTTF){sub 2}Br with effective higher pressure. As a result, it is understood that the antiferromagnetic staggered spin order is stabilized on the CO state in the AFI phase of (TMTTF){sub 2}SbF{sub 6}.

Electronically soft phases in manganites.

Science.gov (United States)

Milward, G C; Calderón, M J; Littlewood, P B

2005-02-10

The phenomenon of colossal magnetoresistance in manganites is generally agreed to be a result of competition between crystal phases with different electronic, magnetic and structural order; a competition which can be strong enough to cause phase separation between metallic ferromagnetic and insulating charge-modulated states. Nevertheless, closer inspection of phase diagrams in many manganites reveals complex phases where the two order parameters of magnetism and charge modulation unexpectedly coexist. Here we show that such experiments can be naturally explained within a phenomenological Ginzburg-Landau theory. In contrast to models where phase separation originates from disorder or as a strain-induced kinetic phenomenon, we argue that magnetic and charge modulation coexist in new thermodynamic phases. This leads to a rich diagram of equilibrium phases, qualitatively similar to those seen experimentally. The success of this model argues for a fundamental reinterpretation of the nature of charge modulation in these materials, from a localized to a more extended 'charge-density wave' picture. The same symmetry considerations that favour textured coexistence of charge and magnetic order may apply to many electronic systems with competing phases. The resulting 'electronically soft' phases of matter with incommensurate, inhomogeneous and mixed order may be general phenomena in correlated systems.

Interplay of charge, orbital and magnetic order in Pr1-xCaxMnO3

International Nuclear Information System (INIS)

Zimmermann V, M.; Hill, J.P.; Gibbs, D.; Blume, M.; Casa, D.; Keimer, B.; Murakami, Y.; Tomioka, Y.; Tokura, Y.

1999-01-01

The authors report resonant x-ray scattering studies of charge and orbital order in Pr 1-x Ca x MnO 3 with x = 0.4 and 0.5. Below the ordering temperature, T O = 245 K, the charge and orbital order intensities follow the same temperature dependence, including an increase at the antiferromagnetic ordering temperature, T N . High resolution measurements reveal, however, that long range orbital order is never achieved. Rather, an orbital domain state is formed. Above T O , the charge order fluctuations are more highly correlated than the orbital fluctuations. Similar phenomenology is observed in a magnetic field. They conclude that the charge order drives the orbital order at the transition

Phase behavior of charged hydrophobic colloids on flat and spherical surfaces

Science.gov (United States)

Kelleher, Colm P.

For a broad class of two-dimensional (2D) materials, the transition from isotropic fluid to crystalline solid is described by the theory of melting due to Kosterlitz, Thouless, Halperin, Nelson and Young (KTHNY). According to this theory, long-range order is achieved via elimination of the topological defects which proliferate in the fluid phase. However, many natural and man-made 2D systems posses spatial curvature and/or non-trivial topology, which require the presence of topological defects, even at T=0. In principle, the presence of these defects could profoundly affect the phase behavior of such a system. In this thesis, we develop and characterize an experimental system of charged colloidal particles that bind electrostatically to the interface between an oil and an aqueous phase. Depending on how we prepare the sample, this fluid interface may be flat, spherical, or have a more complicated geometry. Focusing on the cases where the interface is flat or spherical, we measure the interactions between the particles, and probe various aspects of their phase behavior. On flat interfaces, this phase behavior is well-described by KTHNY theory. In spherical geometries, however, we observe spatial structures and inhomogeneous dynamics that cannot be captured by the measures traditionally used to describe flat-space phase behavior. We show that, in the spherical system, ordering is achieved by a novel mechanism: sequestration of topological defects into freely-terminating grain boundaries ("scars"), and simultaneous spatial organization of the scars themselves on the vertices of an icosahedron. The emergence of icosahedral order coincides with the localization of mobility into isolated "lakes" of fluid or glassy particles, situated at the icosahedron vertices. These lakes are embedded in a rigid, connected "continent" of locally crystalline particles.

Collective Dynamics and Strong Pinning near the Onset of Charge Order in La1.48Nd0.4Sr0.12CuO4

Science.gov (United States)

Baity, P. G.; Sasagawa, T.; Popović, Dragana

2018-04-01

The dynamics of charge-ordered states is one of the key issues in underdoped cuprate high-temperature superconductors, but static short-range charge-order (CO) domains have been detected in almost all cuprates. We probe the dynamics across the CO (and structural) transition in La1.48Nd0.4Sr0.12CuO4 by measuring nonequilibrium charge transport, or resistance R as the system responds to a change in temperature and to an applied magnetic field. We find evidence for metastable states, collective behavior, and criticality. The collective dynamics in the critical regime indicates strong pinning by disorder. Surprisingly, nonequilibrium effects, such as avalanches in R , are revealed only when the critical region is approached from the charge-ordered phase. Our results on La1.48Nd0.4Sr0.12CuO4 provide the long-sought evidence for the fluctuating order across the CO transition, and also set important constraints on theories of dynamic stripes.

Space charge and beam stability issues of the Fermilab proton driver in Phase I

Energy Technology Data Exchange (ETDEWEB)

K. Y. Ng

2001-08-24

Issues concerning beam stability of the proposed Fermilab Proton Driver are studied in its Phase I. Although the betatron tune shifts are dominated by space charge, these shifts are less than 0.25 and will therefore not drive the symmetric and antisymmetric modes of the beam envelope into instability. The longitudinal space charge force is large and inductive inserts may be needed to compensate for the distortion of the rf potential. Although the longitudinal impedance is space charge dominated, it will not drive any microwave instability, unless the real part of the impedance coming from the inductive inserts and wall resistivity of the beam tube are large enough. The design of the beam tube is therefore very important in order to limit the flow of eddy current and keep wall resistivity low. The transverse impedance is also space charge dominated. With the Proton Driver operated at an imaginary transition gamma, however, Landau damping will never be canceled and beam stability can be maintained with negative chromaticities.

Charge, spin and orbital order in the candidate multiferroic material LuFe2O4

International Nuclear Information System (INIS)

Groot, Joost de

2012-01-01

at T N ∝240 K accompanied at T LT ∝170 K by a low temperature phase transition into a phase with glassy magnetic dynamics. It is proposed that this magnetic behavior best approximates the intrinsic defectfree behavior of LuFe 2 O 4 . The spin structures of the long-range ordered phases could be refined properly by neutron diffraction as antiferromagnetic (AFM) and ferrimagnetic (fM) spin alignments. The two solutions exhibit a simple geometrical relation, where all spins in half of the bilayers change their sign. Furthermore, it is demonstrated that at T N and H=0 competing AFM and fM spin structures, which correspond respectively to ferro and antiferro stacking of equivalently ordered bilayers, are nearly degenerate. The observation of diffuse magnetic scattering in neutron diffraction far above T N indicates the random stacking of still individually ferrimagnetic ordered bilayers. The first crystal structural refinement, taking into account the superstructure due to the CO in LuFe 2 O 4 , was performed on these stoichiometric samples with the help of a monoclinic unit-cell and the C2/m symmetry. By clearly identifying the positions of Fe 2+ and Fe 3+ valences in this structure with the Bond Valence Sum (BVS) analysis, a completely new and unexpected CO pattern with charged Fe/O bilayers emerges. This new CO arrangement with charged, and consequently non-polar, bilayers is in strong contrast to all previously suggested CO configurations with polar bilayers. The implications of this result on ''ferroelectricity from CO'' in LuFe 2 O 4 are discussed, addressing the possibility of polarizing the charged bilayers by an external electric or magnetic field, which could not be verified for our samples. In summary, a possible ferroelectric behavior of LuFe 2 O 4 from CO is very unlikely. This is discussed in the light of the so far published work, where some doubt about the ''ferroelectricity from CO'' scenario is already present. It is worth emphasizing that although

The effect of charged groups on hydrophilic monolithic stationary phases on their chromatographic properties.

Science.gov (United States)

Li, Haibin; Liu, Chusheng; Wang, Qiqin; Zhou, Haibo; Jiang, Zhengjin

2016-10-21

In order to investigate the effect of charged groups present in hydrophilic monolithic stationary phases on their chromatographic properties, three charged hydrophilic monomers, i.e. N,N-dimethyl-N-acryloyloxyethyl-N-(3-sulfopropyl)ammonium betaine (SPDA), [2-(acryloyloxy)ethyl]trimethylammonium chloride (AETA), and 3-sulfopropyl acrylate potassium salt (SPA) were co-polymerized with the crosslinker N,N'-methylenebisacrylamide (MBA), respectively. The physicochemical properties of the three resulting charged hydrophilic monolithic columns were evaluated using scanning electron microscopy, ζ-potential analysis and micro-HPLC. High column efficiency was obtained on the three monolithic columns at a linear velocity of 1mm/s using thiourea as test compound. Comparative characterization of the three charged HILIC phases was then carried out using a set of model compounds, including nucleobases, nucleosides, benzoic acid derivatives, phenols, β-blockers and small peptides. Depending on the combination of stationary phase/mobile phase/solute, both hydrophilic interaction and other potential secondary interactions, including electrostatic interaction, hydrogen-bonding interaction, molecular shape selectivity, could contribute to the over-all retention of the analytes. Because of the strong electrostatic interaction provided by the quaternary ammonium groups in the poly (AETA-co-MBA) monolith, this cationic HILIC monolith exhibited the strongest retention for benzoic acid derivatives and small peptides with distorted peak shapes and the weakest retention for basic β-blockers. The sulfonyl groups on the poly (SPA-co-MBA) hydrophilic monolith could provide strong electrostatic attraction and hydrogen bonding for positively charged analytes and hydrogen-donor/acceptor containing analytes, respectively. Therefore, basic drugs, nucleobases and nucleotides exhibited the strongest retention on this anionic monolith. Because of the weak but distinct cation exchange properties of

Commissioning and Charge Readout Calibration of a 5 Ton Dual Phase Liquid Argon TPC

CERN Document Server

AUTHOR|(CDS)2098555

Dual phase time projection chambers with amplification of ionization electrons provide a novel technique for measuring and analyzing rare events with excellent spatial resolution and great calorimetric properties. This thesis describes the commissioning of the WA105 3 x 1 x 1 m3 dual phase liquid argon detector, built to demonstrate the performance of this kind of detector on large scales in order to determine the viability of giant dual phase time projection chambers in long baseline neutrino oscillation experiments. The properties of the insulation and the main tank vessel are described and analyzed, such as the pressure, temperature and argon purity requirements during operation in order to guarantee stable conditions and good event tracking. As signals are induced due to electrons from ionizing radiation, crosstalk is caused by capacitive couplings between strips of the charge readout plane and in the electronics of the data acquisition. These induced signals are studied and compared to capacitance and pu...

Molecular structure of the discotic liquid crystalline phase of hexa-peri-hexabenzocoronene/oligothiophene hybrid and their charge transport properties

International Nuclear Information System (INIS)

Bag, Saientan; Maingi, Vishal; Maiti, Prabal K.; Yelk, Joe; Glaser, Matthew A.; Clark, Noel A.; Walba, David M.

2015-01-01

Using atomistic molecular dynamics simulation, we study the discotic columnar liquid crystalline (LC) phases formed by a new organic compound having hexa-peri-Hexabenzocoronene (HBC) core with six pendant oligothiophene units recently synthesized by Nan Hu et al. [Adv. Mater. 26, 2066 (2014)]. This HBC core based LC phase was shown to have electric field responsive behavior and has important applications in organic electronics. Our simulation results confirm the hexagonal arrangement of columnar LC phase with a lattice spacing consistent with that obtained from small angle X-ray diffraction data. We have also calculated various positional and orientational correlation functions to characterize the ordering of the molecules in the columnar arrangement. The molecules in a column are arranged with an average twist of 25° having an average inter-molecular separation of ∼5 Å. Interestingly, we find an overall tilt angle of 43° between the columnar axis and HBC core. We also simulate the charge transport through this columnar phase and report the numerical value of charge carrier mobility for this liquid crystal phase. The charge carrier mobility is strongly influenced by the twist angle and average spacing of the molecules in the column

Charge Order in (TMTTF)2TaF6 by Infrared Spectroscopy

Science.gov (United States)

Oka, Yuki; Matsunaga, Noriaki; Nomura, Kazushige; Kawamoto, Atsuhi; Yamamoto, Kaoru; Yakushi, Kyuya

2015-11-01

We have performed infrared spectroscopy in (TMTTF)2TaF6 (TMTTF: tetramethyltetrathiafulvalene) to investigate the relationship between the charge order (CO) state and the antiferromagnetic (AF) insulating ground state. A clear peak splitting corresponding to the charge disproportionation was observed below the CO transition temperature. We estimated the degree of charge disproportionation, Δρ = ρrich - ρpoor, as 0.28e from the peak splitting and found that the CO state coexists with the AF state and there is no charge redistribution below the AF transition.

Controlled phase gate for solid-state charge-qubit architectures

International Nuclear Information System (INIS)

Schirmer, S.G.; Oi, D.K.L.; Greentree, Andrew D.

2005-01-01

We describe a mechanism for realizing a controlled phase gate for solid-state charge qubits. By augmenting the positionally defined qubit with an auxiliary state, and changing the charge distribution in the three-dot system, we are able to effectively switch the Coulombic interaction, effecting an entangling gate. We consider two architectures, and numerically investigate their robustness to gate noise

Coulombic charge ice

Science.gov (United States)

McClarty, P. A.; O'Brien, A.; Pollmann, F.

2014-05-01

We consider a classical model of charges ±q on a pyrochlore lattice in the presence of long-range Coulomb interactions. This model first appeared in the early literature on charge order in magnetite [P. W. Anderson, Phys. Rev. 102, 1008 (1956), 10.1103/PhysRev.102.1008]. In the limit where the interactions become short ranged, the model has a ground state with an extensive entropy and dipolar charge-charge correlations. When long-range interactions are introduced, the exact degeneracy is broken. We study the thermodynamics of the model and show the presence of a correlated charge liquid within a temperature window in which the physics is well described as a liquid of screened charged defects. The structure factor in this phase, which has smeared pinch points at the reciprocal lattice points, may be used to detect charge ice experimentally. In addition, the model exhibits fractionally charged excitations ±q/2 which are shown to interact via a 1/r potential. At lower temperatures, the model exhibits a transition to a long-range ordered phase. We are able to treat the Coulombic charge ice model and the dipolar spin ice model on an equal footing by mapping both to a constrained charge model on the diamond lattice. We find that states of the two ice models are related by a staggering field which is reflected in the energetics of these two models. From this perspective, we can understand the origin of the spin ice and charge ice ground states as coming from a dipolar model on a diamond lattice. We study the properties of charge ice in an external electric field, finding that the correlated liquid is robust to the presence of a field in contrast to the case of spin ice in a magnetic field. Finally, we comment on the transport properties of Coulombic charge ice in the correlated liquid phase.

First-Order 0-π Quantum Phase Transition in the Kondo Regime of a Superconducting Carbon-Nanotube Quantum Dot

Directory of Open Access Journals (Sweden)

Romain Maurand

2012-02-01

Full Text Available We study a carbon-nanotube quantum dot embedded in a superconducting-quantum-interference-device loop in order to investigate the competition of strong electron correlations with a proximity effect. Depending on whether local pairing or local magnetism prevails, a superconducting quantum dot will exhibit a positive or a negative supercurrent, referred to as a 0 or π Josephson junction, respectively. In the regime of a strong Coulomb blockade, the 0-to-π transition is typically controlled by a change in the discrete charge state of the dot, from even to odd. In contrast, at a larger tunneling amplitude, the Kondo effect develops for an odd-charge (magnetic dot in the normal state, and quenches magnetism. In this situation, we find that a first-order 0-to-π quantum phase transition can be triggered at a fixed valence when superconductivity is brought in, due to the competition of the superconducting gap and the Kondo temperature. The superconducting-quantum-interference-device geometry together with the tunability of our device allows the exploration of the associated phase diagram predicted by recent theories. We also report on the observation of anharmonic behavior of the current-phase relation in the transition regime, which we associate with the two accessible superconducting states. Our results finally demonstrate that the spin-singlet nature of the Kondo state helps to enhance the stability of the 0 phase far from the mixed-valence regime in odd-charge superconducting quantum dots.

Clapeyron equation and phase equilibrium properties in higher dimensional charged topological dilaton AdS black holes with a nonlinear source

Energy Technology Data Exchange (ETDEWEB)

Li, Huai-Fan; Zhao, Hui-Hua; Zhang, Li-Chun; Zhao, Ren [Shanxi Datong University, Institute of Theoretical Physics, Datong (China); Shanxi Datong University, Department of Physics, Datong (China)

2017-05-15

Using Maxwell's equal area law, we discuss the phase transition of higher dimensional charged topological dilaton AdS black hole with a nonlinear source. The coexisting region of the two phases is found and we depict the coexistence region in the P-v diagrams. The two-phase equilibrium curves in the P-T diagrams are plotted, and we take the first order approximation of volume v in the calculation. To better compare with a general thermodynamic system, the Clapeyron equation is derived for a higher dimensional charged topological black hole with a nonlinear source. The latent heat of an isothermal phase transition is investigated. We also study the effect of the parameters of the black hole on the region of two-phase coexistence. The results show that the black hole may go through a small-large phase transition similar to those of usual non-gravity thermodynamic systems. (orig.)

Radiation-reaction force on a small charged body to second order

Science.gov (United States)

Moxon, Jordan; Flanagan, Éanna

2018-05-01

In classical electrodynamics, an accelerating charged body emits radiation and experiences a corresponding radiation-reaction force, or self-force. We extend to higher order in the total charge a previous rigorous derivation of the electromagnetic self-force in flat spacetime by Gralla, Harte, and Wald. The method introduced by Gralla, Harte, and Wald computes the self-force from the Maxwell field equations and conservation of stress-energy in a limit where the charge, size, and mass of the body go to zero, and it does not require regularization of a singular self-field. For our higher-order computation, an adjustment of the definition of the mass of the body is necessary to avoid including self-energy from the electromagnetic field sourced by the body in the distant past. We derive the evolution equations for the mass, spin, and center-of-mass position of the body through second order. We derive, for the first time, the second-order acceleration dependence of the evolution of the spin (self-torque), as well as a mixing between the extended body effects and the acceleration-dependent effects on the overall body motion.

Effect of net surface charge on particle sizing and material recognition by using phase Doppler anemometry

International Nuclear Information System (INIS)

Zhou Jun; Xie Li

2011-01-01

By taking net surface charge into consideration, the scattering field of particles illuminated by dual laser beams of phase Doppler anemometry (PDA) is computed based on Mie's theory, and the effect of net surface charge on the phase-diameter relationship and the phase ratio is studied. It is found that the phase-diameter relationship and the relationship between the phase ratio and the refractive index of charged particles could be significantly different from those of uncharged particles, which would lead to errors in particle sizing and the measurement of refractive indices. A method of recognizing charged particles and determining the value of their surface conductivity, which is related to net surface charge, is proposed by utilizing the effect of net surface charge on the measurement of refractive indices using PDA.

Effect of net surface charge on particle sizing and material recognition by using phase Doppler anemometry

Energy Technology Data Exchange (ETDEWEB)

Zhou Jun; Xie Li

2011-01-20

By taking net surface charge into consideration, the scattering field of particles illuminated by dual laser beams of phase Doppler anemometry (PDA) is computed based on Mie's theory, and the effect of net surface charge on the phase-diameter relationship and the phase ratio is studied. It is found that the phase-diameter relationship and the relationship between the phase ratio and the refractive index of charged particles could be significantly different from those of uncharged particles, which would lead to errors in particle sizing and the measurement of refractive indices. A method of recognizing charged particles and determining the value of their surface conductivity, which is related to net surface charge, is proposed by utilizing the effect of net surface charge on the measurement of refractive indices using PDA.

Effect of charge ordering and phase separation on the electrical and magnetoresistive properties of polycrystalline La0.4Eu0.1Ca0.5MnO3

Science.gov (United States)

Krichene, A.; Boujelben, W.; Mukherjee, S.; Shah, N. A.; Solanki, P. S.

2018-03-01

We have investigated the effect of charge ordering and phase separation on the electrical and magnetotransport properties of La0.4Eu0.1Ca0.5MnO3 polycrystalline sample. Temperature dependence of resistivity shows a metal-insulator transition at transition temperature Tρ. A hysteretic behavior is observed for zero field resistivity curves with Tρ = 128 K on cooling process and Tρ = 136 K on warming process. Zero field resistivity curves follow Zener polynomial law in the metallic phase with unusual n exponent value ∼9. Presence of resistivity minimum at low temperatures has been ascribed to the coulombic electron-electron scattering process. Resistivity modification due to the magnetic field cycling testifies the presence of the training effect. Magnetization and resistivity appear to be highly correlated. Magnetoresistive study reveals colossal values of negative magnetoresistance reaching about 75% at 132 K under only 2T applied field. Colossal values of magnetoresistance suggest the possibility of using this sample for magnetic field sensing and spintronic applications.

High Charge PHIN Photo Injector at CERN with Fast Phase switching within the Bunch Train for Beam Combination

CERN Document Server

Csatari Divall, M; Bolzon, B; Bravin, E; Chevallay, E; Dabrowski, A; Doebert, S; Drozdy, A; Fedosseev, V; Hessler, C; Lefevre, T; Livesley, S; Losito, R; Olvegaard, M; Petrarca, M; Rabiller, A N; Egger, D; Mete, O

2011-01-01

The high charge PHIN photo-injector was developed within the framework of the European CARE program to provide an alternative to the drive beam thermionic gun in the CTF3 (CLIC Test Facility) at CERN. In PHIN 1908 electron bunches are delivered with bunch spacing of 1.5 GHz and 2.33 nC charge per bunch. Furthermore the drive beam generated by CTF3 requires several fast 180 deg phase-shifts with respect to the 1.5 GHz bunch repetition frequency in order to allow the beam combination scheme developed at CTF3. A total of 8 subtrains, each 140 ns long and shifted in phase with respect to each other, have to be produced with very high phase and amplitude stability. A novel fiber modulator based phase-switching technique developed on the laser system provides this phase-shift between two consecutive pulses much faster and cleaner than the base line scheme, where a thermionic electron gun and sub-harmonic bunching are used. The paper describes the fiber-based switching system and the measurements verifying the schem...

Steering Charge Kinetics of Tin Niobate Photocatalysts: Key Roles of Phase Structure and Electronic Structure.

Science.gov (United States)

Huang, Shushu; Wang, Chunyan; Sun, Hao; Wang, Xiaojing; Su, Yiguo

2018-05-23

Tin niobate photocatalysts with the phase structures of froodite (SnNb 2 O 6 ) and pyrochlore (Sn 2 Nb 2 O 7 ) were obtained by a facile solvothermal method in order to explore the impact of phase structure and electronic structure on the charge kinetics and photocatalytic performance. By employing tin niobate as a model compound, the effects of phase structure over electronic structure, photocatalytic activity toward methyl orange solution and hydrogen evolution were systematically investigated. It is found that the variation of phase structure from SnNb 2 O 6 to Sn 2 Nb 2 O 7 accompanied with modulation of particle size and band edge potentials that has great consequences on photocatalytic performance. In combination with the electrochemical impedance spectroscopy (EIS), transient photocurrent responses, transient absorption spectroscopy (TAS), and the analysis of the charge-carrier dynamics suggested that variation of electronic structure has great impacts on the charge separation and transfer rate of tin niobate photocatalysts and the subsequent photocatalytic performance. Moreover, the results of the X-ray photoelectron spectroscopy (XPS) indicated that the existent of Sn 4+ species in Sn 2 Nb 2 O 7 could result in a decrease in photocatalytic activity. Photocatalytic test demonstrated that the SnNb 2 O 6 (froodite) catalyst possesses a higher photocatalytic activity toward MO degradation and H 2 evolution compared with the sample of Sn 2 Nb 2 O 7 (pyrochlore). On the basis of spin resonance measurement and trapping experiment, it is expected that photogenerated holes, O 2 -• , and OH • active species dominate the photodegradation of methyl orange.

Magnetic and electrical studies on La{sub 0.4}Sm{sub 0.1}Ca{sub 0.5}MnO{sub 3} charge ordered manganite

Energy Technology Data Exchange (ETDEWEB)

Krichene, A., E-mail: akramkri@hotmail.fr [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Université de Sfax, B. P. 1171, 3000 Sfax (Tunisia); Solanki, P.S. [Department of Physics, Saurashtra University, Rajkot 360005 (India); Venkateshwarlu, D. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India); Rayaprol, S. [UGC-DAE Consortium for Scientific Research, Mumbai Centre, B.A.R.C. Campus, Mumbai 400085 (India); Ganesan, V. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India); Boujelben, W. [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Université de Sfax, B. P. 1171, 3000 Sfax (Tunisia); Kuberkar, D.G. [Department of Physics, Saurashtra University, Rajkot 360005 (India)

2015-05-01

We have reported in this work the effect of the partial substitution of lanthanum by samarium on the structural, electrical and magnetic properties of La{sub 0.5}Ca{sub 0.5}MnO{sub 3}. The magnetic study indicated that substitution promotes charge ordering and weakens ferromagnetism. Below T{sub C}=123 K, the compound La{sub 0.4}Sm{sub 0.1}Ca{sub 0.5}MnO{sub 3} is a mixture of ferromagnetic and charge ordered antiferromagnetic domains. Between T{sub C} and T{sub CO}=215 K, the structure is paramagnetic with the presence of antiferromagnetic domains. The fractions of the coexisting magnetic phases are highly dependent on the applied magnetic field value. Resistivity measurements reveal the presence of an insulating-metal transition at T{sub ρ}=123 K. The equality between T{sub C} and T{sub ρ} indicates the presence of a correlation between magnetization and resistivity. For only 1 T applied field, we have reported a colossal value of magnetoresistance reaching 73% around T{sub C}. The origin of this high value is attributed to phase separation phenomenon. - Highlights: • Sm doping enhances charge ordering and weakens ferromagnetism in La{sub 0.5}Ca{sub 0.5}MnO{sub 3.} • Colossal magnetoresistance (73%) is recorded at 123 K for only 1 T applied field. • Phase separation is responsible for the magnetic and the magnetoresistive behavior.

Phase transitions to dipolar clusters and charge density waves in high T_c superconductors

International Nuclear Information System (INIS)

Saarela, M.; Kusmartsev, F.V.

2017-01-01

We show that doping of hole charge carriers leads to formation of electric dipolar clusters in cuprates. They are created by many-body interactions between the dopant ion outside and holes inside the CuO planes. Because of the two-fold degeneracy holes in the CuO plane cluster into four-particles resonance valence bond plaquettes bound with dopant ions. Such dipoles may order into charge-density waves (CDW) or stripes or form a disordered state depending on doping and temperature. The lowest energy of the ordered system corresponds to a local anti-ferroelectric ordering. The mobility of individual disordered dipoles is very low at low temperatures and they prefer first to bind into dipole-dipole pairs. Electromagnetic radiation interacts strongly with electric dipoles and when the sample is subjected to it the mobility changes significantly. This leads to a fractal growth of dipolar clusters. The existence of electric dipoles and CDW induce two phase transitions with increasing temperature, melting of the ordered state and disappearance of the dipolar state. Ferroelectricity at low doping is a natural consequence of such dipole moments. We develop a theory based on two-level systems and dipole-dipole interaction to explain the behavior of the polarization as a function of temperature and electric field.

Competing p-wave orders

International Nuclear Information System (INIS)

Donos, Aristomenis; Gauntlett, Jerome P; Pantelidou, Christiana

2014-01-01

We construct electrically charged, asymptotically AdS 5 black hole solutions that are dual to d = 4 CFTs in a superfluid phase with either p-wave or (p + ip)-wave order. The two types of black holes have non-vanishing charged two-form in the bulk and appear at the same critical temperature in the unbroken phase. Both the p-wave and the (p + ip)-wave phase can be thermodynamically preferred, depending on the mass and charge of the two-form, and there can also be first order transitions between them. The p-wave black holes have a helical structure and some of them exhibit the phenomenon of pitch inversion as the temperature is decreased. Both the p-wave and the (p + ip)-wave black holes have zero entropy density ground states at zero temperature and we identify some new ground states which exhibit scaling symmetry, including a novel scenario for the emergence of conformal symmetry in the IR. (paper)

Interface reconstruction with emerging charge ordering in hexagonal manganite

Science.gov (United States)

Xu, Changsong; Han, Myung-Geun; Bao, Shanyong; Nan, Cewen; Bellaiche, Laurent

2018-01-01

Multiferroic materials, which simultaneously have multiple orderings, hold promise for use in the next generation of memory devices. We report a novel self-assembled MnO double layer forming at the interface between a multiferroic YMnO3 film and a c-Al2O3 substrate. The crystal structures and the valence states of this MnO double layer were studied by atomically resolved scanning transmission electron microscopy and spectroscopy, as well as density functional theory (DFT) calculations. A new type of charge ordering has been identified within this MnO layer, which also contributes to a polarization along the [001] direction. DFT calculations further establish the occurrence of multiple couplings between charge and lattice in this novel double layer, in addition to the polarization in nearby YMnO3 single layer. The interface reconstruction reported here creates a new playground for emergent physics, such as giant ferroelectricity and strong magnetoelectric coupling, in manganite systems. PMID:29795782

Effect of quenched disorder on charge-orbital-spin ordering in single-layer manganites

International Nuclear Information System (INIS)

Uchida, Masaya; Mathieu, Roland; He, Jinping; Kaneko, Yoshio; Tokura, Yoshinori; Asamitsu, Atsushi; Kumai, Reiji; Tomioka, Yasuhide; Matsui, Yoshio

2006-01-01

Structural and magnetic properties have been investigated for half-doped single-layer manganites RE 0.5 Sr 1.5 MnO 4 [RE=La, (La, Pr), Pr, Nd, Sm, and Eu]. Analyses of electron diffraction and ac susceptibility measurements have revealed that the long-range charge-orbital ordering (CO-OO) state as observed in La 0.5 Sr 1.5 MnO 4 is suppressed for the other materials: the CO-OO transition temperature, as well as the correlation length decreases with a decrease in the cation size of RE. Such a short-range CO-OO state shows a spin-glass behavior at low temperatures. A new electronic phase diagram is established with quenched disorder as the control parameter. (author)

Chaos in charged AdS black hole extended phase space

Science.gov (United States)

Chabab, M.; El Moumni, H.; Iraoui, S.; Masmar, K.; Zhizeh, S.

2018-06-01

We present an analytical study of chaos in a charged black hole in the extended phase space in the context of the Poincare-Melnikov theory. Along with some background on dynamical systems, we compute the relevant Melnikov function and find its zeros. Then we analyse these zeros either to identify the temporal chaos in the spinodal region, or to observe spatial chaos in the small/large black hole equilibrium configuration. As a byproduct, we derive a constraint on the Black hole' charge required to produce chaotic behaviour. To the best of our knowledge, this is the first endeavour to understand the correlation between chaos and phase picture in black holes.

Ultrasonic study of the charge mismatch effect in charge-ordered (Nd{sub 0.75}Na{sub 0.25}){sub x}(Nd{sub 0.5}Ca{sub 0.5}){sub 1-x}MnO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Jiang Liang; Su Jinrui; Kong Hui; Liu Yi; Zheng Shiyuan; Zhu Changfei [Laboratory of Advanced Functional Materials and Devices, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China)

2006-09-20

The resistivity, magnetization and ultrasonic properties of charge-ordered polycrystalline (Nd{sub 0.75}Na{sub 0.25}){sub x}(Nd{sub 0.5}Ca{sub 0.5}){sub 1-x}MnO{sub 3} have been investigated from 50 to 300 K. A considerable velocity softening accompanied by an attenuation peak was observed around the charge-ordering transition temperature (T{sub CO}) upon cooling. The simultaneous occurrence of the charge ordering (CO) and the ultrasonic anomaly implies strong electron-phonon coupling, which originates from the cooperative Jahn-Teller effect. At very low temperature, another broad attenuation peak was observed, which is attributed to the phase separation (PS) and gives a direct evidence of spin-phonon coupling in the compound. With increasing x, T{sub CO} shifts to lower temperature, the magnetization of the system is strengthened and the PS is enhanced. The temperature dependence of the longitudinal modulus shows that the Jahn-Teller coupling energy E{sub JT} decreases with increasing Na content. The analysis suggests that the charge mismatch effect may be the main reason for the suppression of the CO and enhancement of the PS.

Energy barriers between metastable states in first-order quantum phase transitions

Science.gov (United States)

Wald, Sascha; Timpanaro, André M.; Cormick, Cecilia; Landi, Gabriel T.

2018-02-01

A system of neutral atoms trapped in an optical lattice and dispersively coupled to the field of an optical cavity can realize a variation of the Bose-Hubbard model with infinite-range interactions. This model exhibits a first-order quantum phase transition between a Mott insulator and a charge density wave, with spontaneous symmetry breaking between even and odd sites, as was recently observed experimentally [Landig et al., Nature (London) 532, 476 (2016), 10.1038/nature17409]. In the present paper, we approach the analysis of this transition using a variational model which allows us to establish the notion of an energy barrier separating the two phases. Using a discrete WKB method, we then show that the local tunneling of atoms between adjacent sites lowers this energy barrier and hence facilitates the transition. Within our simplified description, we are thus able to augment the phase diagram of the model with information concerning the height of the barrier separating the metastable minima from the global minimum in each phase, which is an essential aspect for the understanding of the reconfiguration dynamics induced by a quench across a quantum critical point.

Short range charge/orbital ordering in La1-xSrxMn1-zBzO3 (B Cu,Zn) manganites

International Nuclear Information System (INIS)

Popovic, Z V; Cantarero, A; Thijssen, W H A; Paunovic, N; Dohcevic-Mitrovic, Z; Sapina, F

2005-01-01

We have measured the reflectivity spectra of La 1-x Sr x Mn 1-z B z O 3 (B = Cu, Zn; 0.17 ≤ x ≤ 0.30; 0 ≤ z ≤ 0.10) manganites over wide frequency (100-4000 cm -1 ) and temperature (80-300 K) ranges. Besides the previously observed infrared active modes or mode pairs at about 160 cm -1 (external mode), 350 cm -1 (bond bending mode) and 590 cm -1 (bond stretching mode), we have clearly observed two additional phonon modes at about 645 and 720 cm -1 below the temperature T 1 (T 1 C ), which coincides with the phase transition temperature when the system transforms from ferromagnetic metallic into a ferromagnetic insulator state. This transition is related to the formation of short range charge/orbitally ordered domains. The temperature T 1 of the phase transition is dependent on the doping concentration and for optimally doped samples we have found that T 1 ∼(0.93 ± 0.02) T C . Electrical resistivity and magnetization measurements versus temperature and magnetic field support the short range charge/orbital ordering scenario

Rate-induced solubility and suppression of the first-order phase transition in olivine LiFePO4.

Science.gov (United States)

Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P; Brownrigg, Alex; Wright, Jonathan P; van Dijk, Niels H; Wagemaker, Marnix

2014-05-14

The impact of ultrahigh (dis)charge rates on the phase transition mechanism in LiFePO4 Li-ion electrodes is revealed by in situ synchrotron diffraction. At high rates the solubility limits in both phases increase dramatically, causing a fraction of the electrode to bypass the first-order phase transition. The small transforming fraction demonstrates that nucleation rates are consequently not limiting the transformation rate. In combination with the small fraction of the electrode that transforms at high rates, this indicates that higher performances may be achieved by further optimizing the ionic/electronic transport in LiFePO4 electrodes.

Long-wavelength behaviour of charge-charge structure factor in insulating and metallic ground state of condensed hydrogen under pressure

International Nuclear Information System (INIS)

Amato, M.A.; March, N.H.

1988-09-01

Using the quantum Monte Carlo charge-charge structure factor S qq (k) it is argued that (i) in the metallic phase the small k expasion is non-analytic at order k 5 , reflecting plasmon dispersion, while in the insulating phase the non-analyticity occurs at O(k 3 ), due to van der Waals interaction between the protons. (author) [pt

Fluctuating Charge-Order in Optimally Doped Bi- 2212 Revealed by Momentum-resolved Electron Energy Loss Spectroscopy

Science.gov (United States)

Husain, Ali; Vig, Sean; Kogar, Anshul; Mishra, Vivek; Rak, Melinda; Mitrano, Matteo; Johnson, Peter; Gu, Genda; Fradkin, Eduardo; Norman, Michael; Abbamonte, Peter

Static charge order is a ubiquitous feature of the underdoped cuprates. However, at optimal doping, charge-order has been thought to be completely suppressed, suggesting an interplay between the charge-ordering and superconducting order parameters. Using Momentum-resolved Electron Energy Loss Spectroscopy (M-EELS) we show the existence of diffuse fluctuating charge-order in the optimally doped cuprate Bi2Sr2CaCu2O8+δ (Bi-2212) at low-temperature. We present full momentum-space maps of both elastic and inelastic scattering at room temperature and below the superconducting transition with 4meV resolution. We show that the ``rods'' of diffuse scattering indicate nematic-like fluctuations, and the energy width defines a fluctuation timescale of 160 fs. We discuss the implications of fluctuating charge-order on the dynamics at optimal doping. This work was supported by the Gordon and Betty Moore Foundation's EPiQS Initiative through Grant GBMF-4542. An early prototype of the M-EELS instrument was supported by the DOE Center for Emergent Superconductivity under Award No. DE-AC02-98CH10886.

Few-layer and symmetry-breaking effects on the electrical properties of ordered CF3Cl phases on graphene

Science.gov (United States)

Morales-Cifuentes, Josue; Wang, Yilin; Reutt-Robey, Janice; Einstein, T. L.

2014-03-01

An effective pseudopotential mechanism for breaking the inherent sub-lattice symmetry of graphene has been studied using DFT calculations on hexagonal boron nitride. Electrical detection of CF3Cl phase transitions on graphene shows the existence of a commensurate ordered phase in which this can be tested. We study the electronic properties of this phase using VASP ver 5.3.3, with ab initio van der Waals density functionals (vdW-DF1 and vdW-DF2). Consistent with a physisorbed phase, binding energies and charge transfer per CF3Cl molecule are calculated to be on the order of 280meV and 0.01e, respectively. By exploring different coverages and orientations of this ordered phase we are able to open a band gap in some configurations; said gap is in the range of 8 to 80meV depending on the strength of the effective pseudopotential. Furthermore, we calculate the screening of these effects in bi-layer and tri-layer graphene. Work supported by NSF-MRSEC at UMD, grant DMR 05-20471 and NSF-CHE 13-05892.

Fragile charge order in the nonsuperconducting ground state of the underdoped high-temperature superconductors.

Science.gov (United States)

Tan, B S; Harrison, N; Zhu, Z; Balakirev, F; Ramshaw, B J; Srivastava, A; Sabok-Sayr, S A; Sabok, S A; Dabrowski, B; Lonzarich, G G; Sebastian, Suchitra E

2015-08-04

The normal state in the hole underdoped copper oxide superconductors has proven to be a source of mystery for decades. The measurement of a small Fermi surface by quantum oscillations on suppression of superconductivity by high applied magnetic fields, together with complementary spectroscopic measurements in the hole underdoped copper oxide superconductors, point to a nodal electron pocket from charge order in YBa2Cu3(6+δ). Here, we report quantum oscillation measurements in the closely related stoichiometric material YBa2Cu4O8, which reveals similar Fermi surface properties to YBa2Cu3(6+δ), despite the nonobservation of charge order signatures in the same spectroscopic techniques, such as X-ray diffraction, that revealed signatures of charge order in YBa2Cu3(6+δ). Fermi surface reconstruction in YBa2Cu4O8 is suggested to occur from magnetic field enhancement of charge order that is rendered fragile in zero magnetic fields because of its potential unconventional nature and/or its occurrence as a subsidiary to more robust underlying electronic correlations.

Berry phase in superconducting charge qubits interacting with a cavity field

International Nuclear Information System (INIS)

Abdel-Aty, Mahmoud

2009-01-01

We propose a method for analyzing Berry phase for a multi-qubit system of superconducting charge qubits interacting with a microwave field. By suitably choosing the system parameters and precisely controlling the dynamics, novel connection found between the Berry phase and entanglement creations.

Liquid-liquid and liquid-solid phase separation and flocculation for a charged colloidal dispersion

International Nuclear Information System (INIS)

Lai, S.K.; Wu, K.L.

2002-01-01

We model the intercolloidal interaction by a hard-sphere Yukawa repulsion to which is added the long-range van der Waals attraction. In comparison with the Derjaguin-Landau-Verwey-Overbeek repulsion, the Yukawa repulsion explicitly incorporates the spatial correlations between colloids and small ions. As a result, the repulsive part can be expressed analytically and has a coupling strength depending on the colloidal volume fraction. By use of this two-body potential of mean force and in conjunction with a second-order thermodynamic perturbation theory, we construct the colloidal Helmholtz free energy and use it to calculate the thermodynamic quantities, pressure and chemical potential, needed in the determination of the liquid-liquid and liquid-solid phase diagrams. We examine, in an aqueous charged colloidal dispersion, the effects of the Hamaker constant and particle size on the conformation of a stable liquid-liquid phase transition calculated with respect to the liquid-solid coexistence phases. We find that there exists a threshold Hamaker constant or particle size whose value demarcates the stable liquid-liquid coexistence phases from their metastable counterparts. Applying the same technique and using the energetic criterion, we extend our calculations to study the flocculation phenomenon in aqueous charged colloids. Here, we pay due attention to determining the loci of a stability curve stipulated for a given temperature T 0 , and obtain the parametric phase diagram of the Hamaker constant vs the coupling strength or, at given surface potential, the particle size. By imposing T 0 to be the critical temperature T c , i.e., setting k B T 0 (=k B T c ) equal to a reasonable potential barrier, we arrive at the stability curve that marks the irreversible reversible phase transition. The interesting result is that there occurs a minimum size for the colloidal particles below (above) which the colloidal dispersion is driven to an irreversible (reversible) phase

Phase transitions to dipolar clusters and charge density waves in high T{sub c} superconductors

Energy Technology Data Exchange (ETDEWEB)

Saarela, M., E-mail: Mikko.Saarela@oulu.fi [Department of Physics, University of Oulu, P.O. Box 3000, FIN-90014 (Finland); Kusmartsev, F.V. [Department of Physics, Loughborough University, LE11 3TU (United Kingdom)

2017-02-15

We show that doping of hole charge carriers leads to formation of electric dipolar clusters in cuprates. They are created by many-body interactions between the dopant ion outside and holes inside the CuO planes. Because of the two-fold degeneracy holes in the CuO plane cluster into four-particles resonance valence bond plaquettes bound with dopant ions. Such dipoles may order into charge-density waves (CDW) or stripes or form a disordered state depending on doping and temperature. The lowest energy of the ordered system corresponds to a local anti-ferroelectric ordering. The mobility of individual disordered dipoles is very low at low temperatures and they prefer first to bind into dipole-dipole pairs. Electromagnetic radiation interacts strongly with electric dipoles and when the sample is subjected to it the mobility changes significantly. This leads to a fractal growth of dipolar clusters. The existence of electric dipoles and CDW induce two phase transitions with increasing temperature, melting of the ordered state and disappearance of the dipolar state. Ferroelectricity at low doping is a natural consequence of such dipole moments. We develop a theory based on two-level systems and dipole-dipole interaction to explain the behavior of the polarization as a function of temperature and electric field.

The energetics of ordered intermetallic alloys (of the transition metals)

International Nuclear Information System (INIS)

Watson, R.E.; Weinert, M.; Davenport, J.W.; Fernando, G.W.; Bennett, L.H.

1992-01-01

The atomically ordered phases in ordered transition metal alloys are discussed. This chapter is divided into: physical parameters controlling phase stability (Hume-Rothery, structural maps, Miedema Hamiltonian), wave functions ampersand band theory, comment on entropy terms, cohesive energies (electron promotion energies, Hund's rule on orbital effects), structural energies/stabilities of elemental solids, total energies and atomic positions, charge transfer (Au alloys, charge tailing), heats of formation of ordered compounds

Origin of Asymmetric Charge Partitioning in the Dissociation of Gas-Phase Protein Homodimers

OpenAIRE

Jurchen, John C.; Williams, Evan R.

2003-01-01

The origin of asymmetric charge and mass partitioning observed for gas-phase dissociation of multiply charged macromolecular complexes has been hotly debated. These experiments hold the potential to provide detailed information about the interactions between the macromolecules within the complex. Here, this unusual phenomenon of asymmetric charge partitioning is investigated for several protein homodimers. Asymmetric charge partitioning in these ions depends on a number of factors, including ...

Charge ordering phenomena and superconductivity in underdoped cuprates

Energy Technology Data Exchange (ETDEWEB)

Tassini, Leonardo [Bayerische Akademie der Wissenschaften, Muenchen (Germany). Lehrstuhl E23 fuer Technische Physik

2008-01-16

In this thesis electronic properties of two prototypical copper-oxygen superconductors were studied with Raman scattering. The underdoped regime including the onset point of superconductivity p{sub sc1} was investigated. Evidence of quasi one-dimensional (1D) dynamical stripes was found. The 1D structures have a universal preferential orientation along the diagonals of the CuO{sub 2} planes below p{sub sc1}. At p{sub sc1}, lattice and electron dynamics change discontinuously. The results show that charge ordering drives the transition at p{sub sc1} and that the maximal transition temperature to superconductivity at optimal doping T{sub c}{sup MAX} depends on the type of ordering at p{sub sc1}. (orig.)

Charge/orbital ordering structure in ordered perovskite Sm sub 1 sub / sub 2 Ba sub 1 sub / sub 2 MnO sub 3

CERN Document Server

Uchida, M; Akahoshi, D; Kumai, R; Tomioka, Y; Tokura, Y; Arima, T H

2002-01-01

In an A-site ordered perovskite manganite Sm sub 1 sub / sub 2 Ba sub 1 sub / sub 2 MnO sub 3 , a new charge/orbital ordering pattern was found at room temperature. Electron diffraction studies revealed a series of superlattice reflections with modulation vectors at q sub 2 =(1/2, 1/2, 1/2) as well as at q sub 1 =(1/4, 1/4, 0) in the tetragonal setting (a sub p x a sub p x 2a sub p , a sub p being the cubic perovskite lattice parameter). Together with the results of the resonant X-ray scattering and the charge-transport and magnetization measurements, a new model for the three-dimensional charge/orbital ordering in the ordered perovskite is proposed. (author)

First order electroweak phase transition

International Nuclear Information System (INIS)

Buchmueller, W.; Fodor, Z.

1993-01-01

In this work, the authors have studied the phase transition in the SU(2)gauge theory at finite temperature. The authors' improved perturbative approach does not suffer from the infrared problems appearing in the ordinary loop expansion. The authors have calculated the effective potential up to cubic terms in the couplings. The higher order terms suggest that the method is reliable for Higgs masses smaller than 80 GeV. The authors have obtained a non-vanishing magnetic mass which further weakens the transitions. By use of Langer's theory of metastability, the authors have calculated the nucleation rate for critical bubbles and have discussed some cosmological consequences. For m H <80 GeV the phase transition is first order and proceeds via bubble nucleation and growth. The thin wall approximation is only marginally applicable. Since the phase transition is quite weak SM baryogenesis is unlikely. 8 refs., 5 figs

Fluctuations and correlations of conserved charges near the QCD critical point

International Nuclear Information System (INIS)

Fu Weijie; Wu Yueliang

2010-01-01

We study the fluctuations and correlations of conserved charges, such as the baryon number, the electric charge and the strangeness, at the finite temperature and the nonzero baryon chemical potential in an effective model. The fluctuations are calculated up to the fourth-order and the correlations to the third-order. We find that the second-order fluctuations and correlations have a peak or valley structure when the chiral phase transition takes place with the increase of the baryon chemical potential; the third-order fluctuations and correlations change their signs during the chiral phase transition; and the fourth-order fluctuations have two maxima and one minimum. We also depict contour plots of various fluctuations and correlations of conserved charges in the plane of temperature and the baryon chemical potential. It is found that higher-order fluctuations and correlations of conserved charges are superior to the second-order ones to be used to search for the critical point in heavy ion collision experiments.

Gravity dual of spin and charge density waves

Science.gov (United States)

Jokela, Niko; Järvinen, Matti; Lippert, Matthew

2014-12-01

At high enough charge density, the homogeneous state of the D3-D7' model is unstable to fluctuations at nonzero momentum. We investigate the end point of this instability, finding a spatially modulated ground state, which is a charge and spin density wave. We analyze the phase structure of the model as a function of chemical potential and magnetic field and find the phase transition from the homogeneous state to be first order, with a second-order critical point at zero magnetic field.

Determination of gas phase protein ion densities via ion mobility analysis with charge reduction.

Science.gov (United States)

Maisser, Anne; Premnath, Vinay; Ghosh, Abhimanyu; Nguyen, Tuan Anh; Attoui, Michel; Hogan, Christopher J

2011-12-28

We use a charge reduction electrospray (ESI) source and subsequent ion mobility analysis with a differential mobility analyzer (DMA, with detection via both a Faraday cage electrometer and a condensation particle counter) to infer the densities of single and multiprotein ions of cytochrome C, lysozyme, myoglobin, ovalbumin, and bovine serum albumin produced from non-denaturing (20 mM aqueous ammonium acetate) and denaturing (1 : 49.5 : 49.5, formic acid : methanol : water) ESI. Charge reduction is achieved through use of a Po-210 radioactive source, which generates roughly equal concentrations of positive and negative ions. Ions produced by the source collide with and reduce the charge on ESI generated drops, preventing Coulombic fissions, and unlike typical protein ESI, leading to gas-phase protein ions with +1 to +3 excess charges. Therefore, charge reduction serves to effectively mitigate any role that Coulombic stretching may play on the structure of the gas phase ions. Density inference is made via determination of the mobility diameter, and correspondingly the spherical equivalent protein volume. Through this approach it is found that for both non-denaturing and denaturing ESI-generated ions, gas-phase protein ions are relatively compact, with average densities of 0.97 g cm(-3) and 0.86 g cm(-3), respectively. Ions from non-denaturing ESI are found to be slightly more compact than predicted from the protein crystal structures, suggesting that low charge state protein ions in the gas phase are slightly denser than their solution conformations. While a slight difference is detected between the ions produced with non-denaturing and denaturing ESI, the denatured ions are found to be much more dense than those examined previously by drift tube mobility analysis, in which charge reduction was not employed. This indicates that Coulombic stretching is typically what leads to non-compact ions in the gas-phase, and suggests that for gas phase

Tunable spin-charge conversion through topological phase transitions in zigzag nanoribbons

KAUST Repository

Li, Hang

2016-06-29

We study spin-orbit torques and charge pumping in magnetic quasi-one-dimensional zigzag nanoribbons with a hexagonal lattice, in the presence of large intrinsic spin-orbit coupling. Such a system experiences a topological phase transition from a trivial band insulator to a quantum spin Hall insulator by tuning of either the magnetization direction or the intrinsic spin-orbit coupling. We find that the spin-charge conversion efficiency (i.e., spin-orbit torque and charge pumping) is dramatically enhanced at the topological transition, displaying a substantial angular anisotropy.

Tunable spin-charge conversion through topological phase transitions in zigzag nanoribbons

KAUST Repository

Li, Hang; Manchon, Aurelien

2016-01-01

We study spin-orbit torques and charge pumping in magnetic quasi-one-dimensional zigzag nanoribbons with a hexagonal lattice, in the presence of large intrinsic spin-orbit coupling. Such a system experiences a topological phase transition from a trivial band insulator to a quantum spin Hall insulator by tuning of either the magnetization direction or the intrinsic spin-orbit coupling. We find that the spin-charge conversion efficiency (i.e., spin-orbit torque and charge pumping) is dramatically enhanced at the topological transition, displaying a substantial angular anisotropy.

Charge, spin and orbital order in the candidate multiferroic material LuFe{sub 2}O{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Groot, Joost de

2012-06-28

main focus is on samples exhibiting a sharp magnetic transition to long-range spin order at T{sub N}{proportional_to}240 K accompanied at T{sub LT} {proportional_to}170 K by a low temperature phase transition into a phase with glassy magnetic dynamics. It is proposed that this magnetic behavior best approximates the intrinsic defectfree behavior of LuFe{sub 2}O{sub 4}. The spin structures of the long-range ordered phases could be refined properly by neutron diffraction as antiferromagnetic (AFM) and ferrimagnetic (fM) spin alignments. The two solutions exhibit a simple geometrical relation, where all spins in half of the bilayers change their sign. Furthermore, it is demonstrated that at T{sub N} and H=0 competing AFM and fM spin structures, which correspond respectively to ferro and antiferro stacking of equivalently ordered bilayers, are nearly degenerate. The observation of diffuse magnetic scattering in neutron diffraction far above T{sub N} indicates the random stacking of still individually ferrimagnetic ordered bilayers. The first crystal structural refinement, taking into account the superstructure due to the CO in LuFe{sub 2}O{sub 4}, was performed on these stoichiometric samples with the help of a monoclinic unit-cell and the C2/m symmetry. By clearly identifying the positions of Fe{sup 2+} and Fe{sup 3+} valences in this structure with the Bond Valence Sum (BVS) analysis, a completely new and unexpected CO pattern with charged Fe/O bilayers emerges. This new CO arrangement with charged, and consequently non-polar, bilayers is in strong contrast to all previously suggested CO configurations with polar bilayers. The implications of this result on ''ferroelectricity from CO'' in LuFe{sub 2}O{sub 4} are discussed, addressing the possibility of polarizing the charged bilayers by an external electric or magnetic field, which could not be verified for our samples. In summary, a possible ferroelectric behavior of LuFe{sub 2}O{sub 4} from CO is

Alternating phase focussing including space charge

International Nuclear Information System (INIS)

Cheng, W.H.; Gluckstern, R.L.

1992-01-01

Longitudinal stability can be obtained in a non-relativistic drift tube accelerator by traversing each gap as the rf accelerating field rises. However, the rising accelerating field leads to a transverse defocusing force which is usually overcome by magnetic focussing inside the drift tubes. The radio frequency quadrupole is one way of providing simultaneous longitudinal and transverse focusing without the use of magnets. One can also avoid the use of magnets by traversing alternate gaps between drift tubes as the field is rising and falling, thus providing an alternation of focussing and defocusing forces in both the longitudinal and transverse directions. The stable longitudinal phase space area is quite small, but recent efforts suggest that alternating phase focussing (APF) may permit low velocity acceleration of currents in the 100-300 ma range. This paper presents a study of the parameter space and a test of crude analytic predictions by adapting the code PARMILA, which includes space charge, to APF. 6 refs., 3 figs

Local magnetic susceptibility, spin dynamics, and charge order in the quasi-one-dimensional conductor β -Li0.33V2O5 investigated by site-selective 51V NMR

Science.gov (United States)

Yamauchi, Ichihiro; Itoh, Masayuki; Yamauchi, Touru; Yamaura, Jun-Ichi; Ueda, Yutaka

2017-11-01

51V NMR measurements have been conducted on a single crystal of the quasi-one-dimensional conductor β -Li0.33V2O5 which undergoes a metal-insulator (MI) transition at TMI˜170 K. In the metallic phase, we obtain 51V Knight shift and electric field gradient tensors. From the analysis of the 51V Knight shifts, we find that the charge disproportionation appears even in the metallic state and the electronic structure is represented within a model of weakly coupled ladders containing two types of ladders with distinct carrier densities. Based on the 51V nuclear spin-lattice relaxation rate, we discuss the spin dynamics within the one-dimensional electron gas model. From the analysis of several nonmagnetic V5 + spectra observed in the insulating phase, we propose a possible charge-order pattern which has a superlattice modulation larger than those in other family members of β -A0.33V2O5 (A =Na and Ag). Finally, we discuss the A -ion dependence of the electronic structure, the charge disproportionation, and the charge order in β -A0.33V2O5 .

Model of electric field-induced charge disordering in praseodymium manganites

International Nuclear Information System (INIS)

Lapinskas, S.; Tornau, E.E.; Semiconductor Physics Inst., Vilnius

2001-01-01

We propose a model for an electric field-driven transition from the ordered NaCl-type phase to the disordered phase. Such a transition might be a prototype of charge disordering transition observed in Pr 1-c Ca c MnO 3 . We assume the lattice-gas model and hopping conductivity of charge carriers. The solution of this model, performed by the Monte Carlo method, demonstrates that considerably high electric field can disorder well-ordered phases. The comparison with the data for charge disordering in Pr 1-c Ca c MnO 3 shows that required fields are much too high. We analyze the obtained results trying to determine a possible scenario for conductivity in Pr 1-c Ca c MnO 3 . (orig.)

Gravitational waves from global second order phase transitions

Energy Technology Data Exchange (ETDEWEB)

Jr, John T. Giblin [Department of Physics, Kenyon College, 201 North College Rd, Gambier, OH 43022 (United States); Price, Larry R.; Siemens, Xavier; Vlcek, Brian, E-mail: giblinj@kenyon.edu, E-mail: larryp@caltech.edu, E-mail: siemens@gravity.phys.uwm.edu, E-mail: bvlcek@uwm.edu [Center for Gravitation and Cosmology, Department of Physics, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, WI 53201 (United States)

2012-11-01

Global second-order phase transitions are expected to produce scale-invariant gravitational wave spectra. In this manuscript we explore the dynamics of a symmetry-breaking phase transition using lattice simulations. We explicitly calculate the stochastic gravitational wave background produced during the transition and subsequent self-ordering phase. We comment on this signal as it compares to the scale-invariant spectrum produced during inflation.

Mixed-order phase transition in a colloidal crystal

Science.gov (United States)

Alert, Ricard; Tierno, Pietro; Casademunt, Jaume

2017-12-01

Mixed-order phase transitions display a discontinuity in the order parameter like first-order transitions yet feature critical behavior like second-order transitions. Such transitions have been predicted for a broad range of equilibrium and nonequilibrium systems, but their experimental observation has remained elusive. Here, we analytically predict and experimentally realize a mixed-order equilibrium phase transition. Specifically, a discontinuous solid-solid transition in a 2D crystal of paramagnetic colloidal particles is induced by a magnetic field H. At the transition field Hs, the energy landscape of the system becomes completely flat, which causes diverging fluctuations and correlation length ξ∝|H2-Hs2|-1/2. Mean-field critical exponents are predicted, since the upper critical dimension of the transition is du=2. Our colloidal system provides an experimental test bed to probe the unconventional properties of mixed-order phase transitions.

Mixed-order phase transition in a colloidal crystal.

Science.gov (United States)

Alert, Ricard; Tierno, Pietro; Casademunt, Jaume

2017-12-05

Mixed-order phase transitions display a discontinuity in the order parameter like first-order transitions yet feature critical behavior like second-order transitions. Such transitions have been predicted for a broad range of equilibrium and nonequilibrium systems, but their experimental observation has remained elusive. Here, we analytically predict and experimentally realize a mixed-order equilibrium phase transition. Specifically, a discontinuous solid-solid transition in a 2D crystal of paramagnetic colloidal particles is induced by a magnetic field [Formula: see text] At the transition field [Formula: see text], the energy landscape of the system becomes completely flat, which causes diverging fluctuations and correlation length [Formula: see text] Mean-field critical exponents are predicted, since the upper critical dimension of the transition is [Formula: see text] Our colloidal system provides an experimental test bed to probe the unconventional properties of mixed-order phase transitions.

Positron study of negative charge states in order-disorder ferroelectrics

Energy Technology Data Exchange (ETDEWEB)

Troev, T.; Berovsky, K.; Peneva, S. [Bulgarian Academy of Sciences, Sofia (Bulgaria). Inst. for Nuclear Research and Nuclear Energy

2001-07-01

The positive positron charge opens the possibility for determining the changes in charge states in technologically important order-disorder ferroelectrics. Here we show that dipole polarization disordering within domains affects the positron annihilation mechanism. The positron lifetime parameters in triglycine sulphate (TGS) (NH{sub 3}CH{sub 2}COOH){sub 3}H{sub 2}SO{sub 4}, Rochelle salt (RS) NaKC{sub 4}H{sub 4}O{sub 6}.4H{sub 2}O and Potassium dihydrogen phosphate (KDP) KH{sub 2}PO{sub 4}, at different temperatures and gamma-irradiation doses depend on the charge point defects. The increase of the positron long lifetime component {tau}{sub 2} is proportional to the temperature and gamma-irradiation dose. In gamma irradiated TGS positrons are trapped in defect electron states of oxigen ions of two radicals CH{sub 2}COO{sup -} and NH{sub 3}CHCOO{sup -}. In RS positrons are trapped also in defect electron states of oxygen ions and OH groups. (orig.)

Incorporating space charge in the transverse phase-space matching and tomography at PITZ

Energy Technology Data Exchange (ETDEWEB)

Kourkafas, Georgios

2015-11-15

The ever-expanding achievements in the field of particle accelerators push their specifications to very demanding levels. The performance of many modern applications depends on their ability to be operated with high bunch charges confined in small volumes. However, the consequence of increased intensity is strong space-charge forces, which perplex the beam manipulation and undermine the beam quality. As a result, reliable methods are needed to control and measure the accelerated particles under these extraordinary conditions. The phase space tomography is a diagnostic technique which can reveal details of the transverse beam parameters for a wide range of intensities and energies, with minimal influence from the machine instabilities, in a quasi non-destructive way. The accuracy of this method relies on the precise knowledge and control of the particle dynamics under the influence of space charge in different stages of the measurement. On the one hand, the matching of the beam to the measurement's design transverse parameters requires a procedure which efficiently compensates the effects of space charge. Depending on the structure of the magnetic lattice, different aspects of these effects prevail, therefore different strategies have to be developed. On the other hand, the impact of the space-charge forces on the phase-space transformations during the data acquisition has to be included in the model which is used for the tomographic reconstruction. The aim of this thesis is to provide and test time-efficient solutions for the incorporation of space charge in the transverse beam matching and phase space tomography.

Incorporating space charge in the transverse phase-space matching and tomography at PITZ

International Nuclear Information System (INIS)

Kourkafas, Georgios

2015-11-01

The ever-expanding achievements in the field of particle accelerators push their specifications to very demanding levels. The performance of many modern applications depends on their ability to be operated with high bunch charges confined in small volumes. However, the consequence of increased intensity is strong space-charge forces, which perplex the beam manipulation and undermine the beam quality. As a result, reliable methods are needed to control and measure the accelerated particles under these extraordinary conditions. The phase space tomography is a diagnostic technique which can reveal details of the transverse beam parameters for a wide range of intensities and energies, with minimal influence from the machine instabilities, in a quasi non-destructive way. The accuracy of this method relies on the precise knowledge and control of the particle dynamics under the influence of space charge in different stages of the measurement. On the one hand, the matching of the beam to the measurement's design transverse parameters requires a procedure which efficiently compensates the effects of space charge. Depending on the structure of the magnetic lattice, different aspects of these effects prevail, therefore different strategies have to be developed. On the other hand, the impact of the space-charge forces on the phase-space transformations during the data acquisition has to be included in the model which is used for the tomographic reconstruction. The aim of this thesis is to provide and test time-efficient solutions for the incorporation of space charge in the transverse beam matching and phase space tomography.

Higher-order geodesic deviation for charged particles and resonance induced by gravitational waves

Science.gov (United States)

Heydari-Fard, M.; Hasani, S. N.

We generalize the higher-order geodesic deviation for the structure-less test particles to the higher-order geodesic deviation equations of the charged particles [R. Kerner, J. W. van Holten and R. Colistete Jr., Class. Quantum Grav. 18 (2001) 4725]. By solving these equations for charged particles moving in a constant magnetic field in the spacetime of a gravitational wave, we show for both cases when the gravitational wave is parallel and perpendicular to the constant magnetic field, a magnetic resonance appears at wg = Ω. This feature might be useful to detect the gravitational wave with high frequencies.

Impurity Induced Phase Competition and Supersolidity

Science.gov (United States)

Karmakar, Madhuparna; Ganesh, R.

2017-12-01

Several material families show competition between superconductivity and other orders. When such competition is driven by doping, it invariably involves spatial inhomogeneities which can seed competing orders. We study impurity-induced charge order in the attractive Hubbard model, a prototypical model for competition between superconductivity and charge density wave order. We show that a single impurity induces a charge-ordered texture over a length scale set by the energy cost of the competing phase. Our results are consistent with a strong-coupling field theory proposed earlier in which superconducting and charge order parameters form components of an SO(3) vector field. To discuss the effects of multiple impurities, we focus on two cases: correlated and random distributions. In the correlated case, the CDW puddles around each impurity overlap coherently leading to a "supersolid" phase with coexisting pairing and charge order. In contrast, a random distribution of impurities does not lead to coherent CDW formation. We argue that the energy lowering from coherent ordering can have a feedback effect, driving correlations between impurities. This can be understood as arising from an RKKY-like interaction, mediated by impurity textures. We discuss implications for charge order in the cuprates and doped CDW materials such as NbSe2.

Quantum phases for point-like charged particles and for electrically neutral dipoles in an electromagnetic field

Science.gov (United States)

Kholmetskii, A. L.; Missevitch, O. V.; Yarman, T.

2018-05-01

We point out that the known quantum phases for an electric/magnetic dipole moving in an electromagnetic (EM) field must be presented as the superposition of more fundamental quantum phases emerging for elementary charges. Using this idea, we find two new fundamental quantum phases for point-like charges, next to the known electric and magnetic Aharonov-Bohm (A-B) phases, named by us as the complementary electric and magnetic phases, correspondingly. We further demonstrate that these new phases can indeed be derived via the Schrödinger equation for a particle in an EM field, where however the operator of momentum is re-defined via the replacement of the canonical momentum of particle by the sum of its mechanical momentum and interactional field momentum for a system "charged particle and a macroscopic source of EM field". The implications of the obtained results are discussed.

Next-to-leading-order electroweak corrections to the production of three charged leptons plus missing energy at the LHC

Science.gov (United States)

Biedermann, Benedikt; Denner, Ansgar; Hofer, Lars

2017-10-01

The production of a neutral and a charged vector boson with subsequent decays into three charged leptons and a neutrino is a very important process for precision tests of the Standard Model of elementary particles and in searches for anomalous triple-gauge-boson couplings. In this article, the first computation of next-to-leading-order electroweak corrections to the production of the four-lepton final states μ + μ -e+ ν e, {μ}+{μ}-{e}-{\\overline{ν}}e , μ + μ - μ + ν μ , and {μ}+{μ}-{μ}-{\\overline{ν}}_{μ } at the Large Hadron Collider is presented. We use the complete matrix elements at leading and next-to-leading order, including all off-shell effects of intermediate massive vector bosons and virtual photons. The relative electroweak corrections to the fiducial cross sections from quark-induced partonic processes vary between -3% and -6%, depending significantly on the event selection. At the level of differential distributions, we observe large negative corrections of up to -30% in the high-energy tails of distributions originating from electroweak Sudakov logarithms. Photon-induced contributions at next-to-leading order raise the leading-order fiducial cross section by +2%. Interference effects in final states with equal-flavour leptons are at the permille level for the fiducial cross section, but can lead to sizeable effects in off-shell sensitive phase-space regions.

Density Functional Theory for Phase-Ordering Transitions

Energy Technology Data Exchange (ETDEWEB)

Wu, Jianzhong [Univ. of California, Riverside, CA (United States)

2016-03-30

Colloids display astonishing structural and dynamic properties that can be dramatically altered by modest changes in the solution condition or an external field. This complex behavior stems from a subtle balance of colloidal forces and intriguing mesoscopic and macroscopic phase transitions that are sensitive to the processing conditions and the dispersing environment. Whereas the knowledge on the microscopic structure and phase behavior of colloidal systems at equilibrium is now well-advanced, quantitative predictions of the dynamic properties and the kinetics of phase-ordering transitions in colloids are not always realized. Many important mesoscopic and off-equilibrium colloidal states remain poorly understood. The proposed research aims to develop a new, unifying approach to describe colloidal dynamics and the kinetics of phase-ordering transitions based on accomplishments from previous work for the equilibrium properties of both uniform and inhomogeneous systems and on novel concepts from the state-of-the-art dynamic density functional theory. In addition to theoretical developments, computational research is designed to address a number of fundamental questions on phase-ordering transitions in colloids, in particular those pertinent to a competition of the dynamic pathways leading to various mesoscopic structures, off-equilibrium states, and crystalline phases. By providing a generic theoretical framework to describe equilibrium, metastable as well as non-ergodic phase transitions concurrent with the colloidal self-assembly processes, accomplishments from this work will have major impacts on both fundamental research and technological applications.

Phase behaviour and structure of stable complexes of oppositely charged polyelectrolytes

Science.gov (United States)

Mengarelli, V.; Auvray, L.; Zeghal, M.

2009-03-01

We study the formation and structure of stable electrostatic complexes between oppositely charged polyelectrolytes, a long polymethacrylic acid and a shorter polyethylenimine, at low pH, where the polyacid is weakly charged. We explore the phase diagram as a function of the charge and concentration ratio of the constituents. In agreement with theory, turbidity and ζ potential measurements show two distinct regimes of weak and strong complexation, which appear successively as the pH is increased and are separated by a well-defined limit. Weak complexes observed by neutron scattering and contrast matching have an open, non-compact structure, while strong complexes are condensed.

Phase transformation order-disorder in nonstoichiometric titanium carbide

International Nuclear Information System (INIS)

Vlasov, V.A.; Karmo, Yu.S.; Kustova, L.V.

1986-01-01

Titanium carbide delta-phase is studied using the methods of electric conductivity and differential thermal analysis (DTA). It is shown on the Ti-C system phase diagram that two regions of TiCsub(0.46-0.60) and TiCsub(0.65-1.00) compositions, different in their properties, correspond to delta-phase. Both ordered and disordered phases exist within the TiCsub(0.046-0.60) concentration range, and in equilibrium heating or cooling one phase converts to another at 590 deg C (the first order phase transformation). Samples of the TiCsub(0.65-1.00) composition are characterized by low electric conductivity stability, that is explained by strong titanium carbide electric conductivity sensitivity to defects and impurities

Charge ordered insulating phases of DODHT salts with octahedral anions and a new radical salt, {beta}''-(DODHT){sub 2}TaF{sub 6}

Energy Technology Data Exchange (ETDEWEB)

Nishikawa, H; Oshio, H; Yasuzuka, S [Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571 (Japan); Higa, M; Kondo, R; Kagoshima, S [Department of Basic Science, University of Tokyo, Tokyo 153-8902 (Japan); Nakao, A; Sawa, H [Photon Factory, Institute of Material Structure Science, High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Murata, K [Graduate School of Science, Osaka City University, Osaka 558-8585 (Japan)], E-mail: nishikaw@chem.tsukuba.ac.jp

2008-10-15

Physical properties of isostructural {beta}''-(DODHT){sub 2}X [DODHT = (l,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene; X = PF{sub 6}, AsF{sub 6}, and SbF{sub 6}] at ambient pressure have been compared. The insulating phase of {beta}''-(DODHT){sub 2}PF{sub 6} salt has already been revealed to be a charge ordering (CO) state by X-ray diffraction study and magnetic behavior. CO in this salt was also confirmed by the observation of satellite reflections in oscillation photograph using synchrotron radiation. Transport property of {beta}''-(DODHT){sub 2}SbF{sub 6} salt was reinvestigated up to the pressure of 3.7 GPa applied by a cubic anvil apparatus. Although the SbF{sub 6} salt turned to be metallic above 2.0 GPa, no superconductivity was observed. In order to examine the anion size dependence of DODHT salts with octahedral anions, we prepared a new DODHT salt, {beta}''-(DODHT){sub 2}TaF{sub 6}, which has the larger counter anion compared with the previous salts. Crystal structure of this salt was isostructural to the other DODHT salts. The electrical and magnetic properties of this salt were similar to those of {beta}''-(DODHT){sub 2}SbF{sub 6} salt.

RESONANT X-RAY SCATTERING AS A PROBE OF ORBITAL AND CHARGE ORDERING

International Nuclear Information System (INIS)

NELSON, C.S.; HILL, J.P.; GIBBS, D.

2002-01-01

Resonant x-ray scattering is a powerful experimental technique for probing orbital and charge ordering. It involves tuning the incident photon energy to an absorption edge of the relevant ion and observing scattering at previously 'forbidden' Bragg peaks, and it allows high-resolution, quantitative studies of orbital and charge order--even from small samples. Further, resonant x-ray scattering from orbitally ordered systems exhibits polarization- and azimuthal-dependent properties that provide additional information about the details of the orbital order that is difficult, or impossible, to obtain with any other technique. In the manganites, the sensitivity to charge and orbital ordering is enhanced when the incident photon energy is tuned near the Mn K absorption edge (6.539 keV), which is the lowest energy at which a 1s electron can be excited into an unoccupied state. In this process, the core electron is promoted to an intermediate excited state, which decays with the emission of a photon. The sensitivity to charge ordering is believed to be due to the small difference in K absorption edges of the Mn 3+ and Mn 4+ sites. For orbital ordering, the sensitivity arises from a splitting--or difference in the weight of the density of states [239]--of the orbitals occupied by the excited electron in the intermediate state. In the absence of such a splitting, there is no resonant enhancement of the scattering intensity. In principle, other absorption edges in which the intermediate state is anisotropic could be utilized, but the strong dipole transition to the Mn 4p levels--and their convenient energies for x-ray diffraction--make the K edge well-suited to studies of manganites. The Mn 4p levels are affected by the symmetry of the orbital ordering, which makes the technique sensitive to the orbital degree of freedom. Therefore resonant x-ray scattering can be used to obtain important quantitative information concerning the details of this electronic order. Two

Charge Mediated Compaction and Rearrangement of Gas-Phase Proteins: A Case Study Considering Two Proteins at Opposing Ends of the Structure-Disorder Continuum

Science.gov (United States)

Jhingree, Jacquelyn R.; Bellina, Bruno; Pacholarz, Kamila J.; Barran, Perdita E.

2017-07-01

Charge reduction in the gas phase provides a direct means of manipulating protein charge state, and when coupled to ion mobility mass spectrometry (IM-MS), it is possible to monitor the effect of charge on protein conformation in the absence of solution. Use of the electron transfer reagent 1,3-dicyanobenzene, coupled with IM-MS, allows us to monitor the effect of charge reduction on the conformation of two proteins deliberately chosen from opposite sides of the order to disorder continuum: bovine pancreatic trypsin inhibitor (BPTI) and beta casein. The ordered BPTI presents compact conformers for each of three charge states accompanied by narrow collision cross-section distributions (TWCCSDN2→He). Upon reduction of BPTI, irrespective of precursor charge state, the TWCCSN2→He decreases to a similar distribution as found for the nESI generated ion of identical charge. The behavior of beta casein upon charge reduction is more complex. It presents over a wide charge state range (9-28), and intermediate charge states (13-18) have broad TWCCSDN2→He with multiple conformations, where both compaction and rearrangement are seen. Further, we see that the TWCCSDN2→He of the latter charge states are even affected by the presence of radical anions. Overall, we conclude that the flexible nature of some proteins result in broad conformational distributions comprised of many families, even for single charge states, and the barrier between different states can be easily overcome by an alteration of the net charge.

Rapid Estimation Method for State of Charge of Lithium-Ion Battery Based on Fractional Continual Variable Order Model

Directory of Open Access Journals (Sweden)

Xin Lu

2018-03-01

Full Text Available In recent years, the fractional order model has been employed to state of charge (SOC estimation. The non integer differentiation order being expressed as a function of recursive factors defining the fractality of charge distribution on porous electrodes. The battery SOC affects the fractal dimension of charge distribution, therefore the order of the fractional order model varies with the SOC at the same condition. This paper proposes a new method to estimate the SOC. A fractional continuous variable order model is used to characterize the fractal morphology of charge distribution. The order identification results showed that there is a stable monotonic relationship between the fractional order and the SOC after the battery inner electrochemical reaction reaches balanced. This feature makes the proposed model particularly suitable for SOC estimation when the battery is in the resting state. Moreover, a fast iterative method based on the proposed model is introduced for SOC estimation. The experimental results showed that the proposed iterative method can quickly estimate the SOC by several iterations while maintaining high estimation accuracy.

Thermotropic phase transitions of catanionic dodecylsulfates with multi-charged and multi-tailed quaternary ammonium centers

Energy Technology Data Exchange (ETDEWEB)

Mihelj, Tea, E-mail: tmihelj@irb.hr [Ruđer Bošković Institute, Department of Physical Chemistry, Laboratory for Synthesis and Processes of Self-assembling of Organic Molecules, Bijenička c. 54, P.O. Box 180, HR-10002 Zagreb (Croatia); Popović, Jasminka [Division for Materials Physics, Ruđer Bošković Institute, POB 180, HR-10002 Zagreb (Croatia); Skoko, Željko [Department of Physics, Faculty of Science, University of Zagreb, Bijenička cesta 32, HR-10000 Zagreb (Croatia); Tomašić, Vlasta, E-mail: vlastom@irb.hr [Ruđer Bošković Institute, Department of Physical Chemistry, Laboratory for Synthesis and Processes of Self-assembling of Organic Molecules, Bijenička c. 54, P.O. Box 180, HR-10002 Zagreb (Croatia)

2014-09-10

Highlights: • Thermal behavior of quaternary ammonium n-dodecylsulfates is characterized. • Typical layered structure dominates in all examined compounds at room temperature. • The dimeric didodecylsulfate crystallizes in monoclinic space group P21/m. • Thermotropic phases formation characteristic for multi-tailed n-dodecylsulfates. • Multi-charged n-dodecylsulfates are soft crystals at higher temperatures. - Abstract: Five novel anhydrous catanionic dodecylsulfates containing multi-charged and multi-tailed quaternary ammonium centers were synthesized and examined with light microscopy, differential scanning calorimetry and X-ray powder diffraction. This study is an attempt to explain the relationship between chemical structure, molecular architecture, phase transition characteristics and thermodynamics and the nature of intermolecular interactions of the individual amphiphiles that ultimately lead to different mesomorphic product. All examined compounds are of typical layered structure at room temperature. The long spacing decreases linearly with the increase of either ionic head or n-dodecyl chain number. The thermal analysis of the examined multi-charged catanionics indicates thermotropic mesomorphism, whereas multi-tailed dodecylsulfates show only properties of soft crystals. Maltese crosses, oily streaks textures, stepped drops and fan-shaped textures affirmed the existence of various smectic mesophases at room and higher temperatures. Thermodynamically the most ordered compound is dimeric didodecylsulfate, and the most disordered is three-tailed dodecylsulfate. The addition of the new quaternary ammonium center or alkyl chain causes the increment of the lattice energy first, and it decreases by further changes in the structure. The temperatures of crystallization decrease by any mentioned addition.

Inducement of ferromagnetic-metallic phase in intermediate-doped charge-ordered Pr0.75Na0.25MnO3 manganite by K+ substitution

Science.gov (United States)

Rozilah, R.; Ibrahim, N.; Mohamed, Z.; Yahya, A. K.; Khan, Nawazish A.; Khan, M. Nasir

2017-09-01

Polycrystalline Pr0.75Na0.25-xKxMnO3 (x = 0, 0.05, 0.10, 0.15 and 0.20) ceramics were prepared using conventional solid-state method and their structural, magnetic and electrical transport properties were investigated. Magnetization versus temperature measurements showed un-substituted sample exhibited paramagnetic behavior with charge-ordered temperature, TCO around 218 K followed by antiferromagnetic behavior at transition temperature, TN ∼ 170 K. K+-substitution initially weakened CO state for x = 0.05-0.10 then successfully suppressed the CO state for x = 0.15-0.20 and inducing ferromagnetic-paramagnetic transition with Curie temperature, TC increased with x. In addition, deviation of the temperature dependence of inverse magnetic susceptibility curves from the Curie-Weiss law suggests the existence of Griffiths phase-like increased with x. Magnetization versus magnetic field curves show existence of hysteresis loops at T critical field. Electrical resistivity measurements showed an insulating behavior for x = 0 sample while for x = 0.05-0.20 samples showed metal-insulator transition and transition temperature, TMI increased with x. The increased in TC and TMI are attributed to the increase in tolerance factor which indicates reduction in MnO6 octahedral distortion consequently enhanced double exchange interaction.

Phase space properties of charged fields in theories of local observables

International Nuclear Information System (INIS)

Buchholz, D.; D'Antoni, C.

1994-10-01

Within the setting of algebraic quantum field theory a relation between phase-space properties of observables and charged fields is established. These properties are expressed in terms of compactness and nuclarity conditions which are the basis for the characterization of theories with physically reasonable causal and thermal features. Relevant concepts and results of phase space analysis in algebraic qunatum field theory are reviewed and the underlying ideas are outlined. (orig.)

Paramagnetic fluctuations in Pr0.65Ca0.35MnO3 around the charge-ordering temperature

International Nuclear Information System (INIS)

Daoud-Aladine, A; Roessli, B; Gvasaliya, S N; Perca, C; Pinsard-Gaudart, L; Rodriguez-Carvajal, J; Revcolevschi, A

2006-01-01

We have studied the ferromagnetic and antiferromagnetic fluctuations in the charge-ordered Pr 0.65 Ca 0.35 MnO 3 antiferromagnet by triple-axis neutron spectrometry. Whereas ferromagnetic fluctuations are observed above and below the charge-ordering transition (T CO ), the antiferromagnetic fluctuations develop only below T CO . The dynamical exponent z of both ferromagnetic and antiferromagnetic fluctuations are determined. The ferromagnetic fluctuations are not completely suppressed below T CO and their correlation lengths are short-ranged at all temperatures. The results are discussed with respect to the Zener polaron model recently introduced to describe the charge-ordered state of Pr 0.6 Ca 0.40 MnO 3

Effect of three-body forces on the phase behavior of charged colloids

International Nuclear Information System (INIS)

Wu, J. Z.; Bratko, D.; Blanch, H. W.; Prausnitz, J. M.

2000-01-01

Statistical-thermodynamic theory for predicting the phase behavior of a colloidal solution requires the pair interaction potential between colloidal particles in solution. In practice, it is necessary to assume pairwise additivity for the potential of mean force between colloidal particles, but little is known concerning the validity of this assumption. This paper concerns interaction between small charged colloids, such as surfactant micelles or globular proteins, in electrolyte solutions and the multibody effect on phase behavior. Monte Carlo simulations for isolated colloidal triplets in equilateral configurations show that, while the three-body force is repulsive when the three particles are near contact, it becomes short-ranged attractive at further separations, contrary to a previous study where the triplet force is attractive at all separations. The three-body force arises mainly from hard-sphere collisions between colloids and small ions; it is most significant in solutions of monovalent salt at low concentration where charged colloids experience strong electrostatic interactions. To illustrate the effect of three-body forces on the phase behavior of charged colloids, we calculated the densities of coexisting phases using van der Waals-type theories for colloidal solutions and for crystals. For the conditions investigated in this work, even though the magnitude of the three-body force may be as large as 10% of the total force at small separations, three-body forces do not have a major effect on the densities of binary coexisting phases. However, coexisting densities calculated using Derjaguin-Landau-Verwey-Overbeek theory are much different from those calculated using our simulated potential of mean force. (c) 2000 American Institute of Physics

Phase space imaging of a beam of charged particles by frictional forces

International Nuclear Information System (INIS)

Daniel, H.

1977-01-01

In the case of frictional forces, defined by always acting opposite to the particle motion, Liouville's theorem does not apply. The effect of such forces on a beam of charged particles is calculated in closed form. Emphasis is given to the phase space imaging by a moderator. Conditions for an increase in phase space density are discussed. (Auth.)

Superconductivity, charge orderings, magnetism, and their phase separations in the ground state of lattice models of superconductor with very short coherence length

OpenAIRE

Kapcia, Konrad Jerzy

2015-01-01

This is an author-created, un-copyedited version of an article accepted for publication in Journal of Superconductivity and Novel Magnetism. We present the ground state results for lattice models of superconductor (SC) with extremely short coherence length, which also involve the interplay with charge (CO) and (anti-)ferromagnetic orderings. Our preliminary results at zero-temperature (derived by means of the variational approach which treats the on-site interaction term exactly and the in...

Disentangled Cooperative Orderings in Artificial Rare-Earth Nickelates

Science.gov (United States)

Middey, S.; Meyers, D.; Kareev, M.; Cao, Yanwei; Liu, X.; Shafer, P.; Freeland, J. W.; Kim, J.-W.; Ryan, P. J.; Chakhalian, J.

2018-04-01

Coupled transitions between distinct ordered phases are important aspects behind the rich phase complexity of correlated oxides that hinder our understanding of the underlying phenomena. For this reason, fundamental control over complex transitions has become a leading motivation of the designer approach to materials. We have devised a series of new superlattices by combining a Mott insulator and a correlated metal to form ultrashort period superlattices, which allow one to disentangle the simultaneous orderings in RENiO3 . Tailoring an incommensurate heterostructure period relative to the bulk charge ordering pattern suppresses the charge order transition while preserving metal-insulator and antiferromagnetic transitions. Such selective decoupling of the entangled phases resolves the long-standing puzzle about the driving force behind the metal-insulator transition and points to the site-selective Mott transition as the operative mechanism. This designer approach emphasizes the potential of heterointerfaces for selective control of simultaneous transitions in complex materials with entwined broken symmetries.

Longitudinal Phase Space Tomography with Space Charge

CERN Document Server

Hancock, S; Lindroos, M

2000-01-01

Tomography is now a very broad topic with a wealth of algorithms for the reconstruction of both qualitative and quantitative images. In an extension in the domain of particle accelerators, one of the simplest algorithms has been modified to take into account the non-linearity of large-amplitude synchrotron motion. This permits the accurate reconstruction of longitudinal phase space density from one-dimensional bunch profile data. The method is a hybrid one which incorporates particle tracking. Hitherto, a very simple tracking algorithm has been employed because only a brief span of measured profile data is required to build a snapshot of phase space. This is one of the strengths of the method, as tracking for relatively few turns relaxes the precision to which input machine parameters need to be known. The recent addition of longitudinal space charge considerations as an optional refinement of the code is described. Simplicity suggested an approach based on the derivative of bunch shape with the properties of...

Poisson–Boltzmann theory of the charge-induced adsorption of semi-flexible polyelectrolytes

NARCIS (Netherlands)

Ubbink, J.; Khokhlov, A.R.

2004-01-01

A model is suggested for the structure of an adsorbed layer of a highly charged semi-flexible polyelectrolyte on a weakly charged surface of opposite charge sign. The adsorbed phase is thin, owing to the effective reversal of the charge sign of the surface upon adsorption, and ordered, owing to the

Robust second-order scheme for multi-phase flow computations

Science.gov (United States)

Shahbazi, Khosro

2017-06-01

A robust high-order scheme for the multi-phase flow computations featuring jumps and discontinuities due to shock waves and phase interfaces is presented. The scheme is based on high-order weighted-essentially non-oscillatory (WENO) finite volume schemes and high-order limiters to ensure the maximum principle or positivity of the various field variables including the density, pressure, and order parameters identifying each phase. The two-phase flow model considered besides the Euler equations of gas dynamics consists of advection of two parameters of the stiffened-gas equation of states, characterizing each phase. The design of the high-order limiter is guided by the findings of Zhang and Shu (2011) [36], and is based on limiting the quadrature values of the density, pressure and order parameters reconstructed using a high-order WENO scheme. The proof of positivity-preserving and accuracy is given, and the convergence and the robustness of the scheme are illustrated using the smooth isentropic vortex problem with very small density and pressure. The effectiveness and robustness of the scheme in computing the challenging problem of shock wave interaction with a cluster of tightly packed air or helium bubbles placed in a body of liquid water is also demonstrated. The superior performance of the high-order schemes over the first-order Lax-Friedrichs scheme for computations of shock-bubble interaction is also shown. The scheme is implemented in two-dimensional space on parallel computers using message passing interface (MPI). The proposed scheme with limiter features approximately 50% higher number of inter-processor message communications compared to the corresponding scheme without limiter, but with only 10% higher total CPU time. The scheme is provably second-order accurate in regions requiring positivity enforcement and higher order in the rest of domain.

Two-Phase Equilibrium Properties in Charged Topological Dilaton AdS Black Holes

Directory of Open Access Journals (Sweden)

Hui-Hua Zhao

2016-01-01

Full Text Available We discuss phase transition of the charged topological dilaton AdS black holes by Maxwell equal area law. The two phases involved in the phase transition could coexist and we depict the coexistence region in P-v diagrams. The two-phase equilibrium curves in P-T diagrams are plotted, the Clapeyron equation for the black hole is derived, and the latent heat of isothermal phase transition is investigated. We also analyze the parameters of the black hole that could have an effect on the two-phase coexistence. The results show that the black holes may go through a small-large phase transition similar to that of a usual nongravity thermodynamic system.

Improper ferroelectric polarization in a perovskite driven by intersite charge transfer and ordering

Science.gov (United States)

Chen, Wei-Tin; Wang, Chin-Wei; Wu, Hung-Cheng; Chou, Fang-Cheng; Yang, Hung-Duen; Simonov, Arkadiy; Senn, M. S.

2018-04-01

It is of great interest to design and make materials in which ferroelectric polarization is coupled to other order parameters such as lattice, magnetic, and electronic instabilities. Such materials will be invaluable in next-generation data storage devices. Recently, remarkable progress has been made in understanding improper ferroelectric coupling mechanisms that arise from lattice and magnetic instabilities. However, although theoretically predicted, a compact lattice coupling between electronic and ferroelectric (polar) instabilities has yet to be realized. Here we report detailed crystallographic studies of a perovskite HgAMn3A'Mn4BO12 that is found to exhibit a polar ground state on account of such couplings that arise from charge and orbital ordering on both the A'- and B-sites, which are themselves driven by a highly unusual MnA '-MnB intersite charge transfer. The inherent coupling of polar, charge, orbital, and hence magnetic degrees of freedom make this a system of great fundamental interest, and demonstrating ferroelectric switching in this and a host of recently reported hybrid improper ferroelectrics remains a substantial challenge.

Quantum phases for a charged particle and electric/magnetic dipole in an electromagnetic field

Science.gov (United States)

Kholmetskii, Alexander; Yarman, Tolga

2017-11-01

We point out that the known quantum phases for an electric/magnetic dipole moving in an electromagnetic field must be composed from more fundamental quantum phases emerging for moving elementary charges. Using this idea, we have found two new fundamental quantum phases, next to the known magnetic and electric Aharonov-Bohm phases, and discuss their general properties and physical meaning.

Investigation of the charge-orbital ordering mechanism in single-layered Pr0.5Ca1.5MnO4

Science.gov (United States)

Rangkuti, C. N.; Majidi, M. A.

2018-04-01

Motivated by the experimental study of half-doped single-layered Pr0.5Ca1.5MnO4 showing charge, orbital, and spin orderings [1], we propose a model to theoretically study the system to explain such ordering phenomena. The ground state electron configuration reveals that the charges form a checkerboard pattern with alternating Mn3+/Mn4+ sites, while the orbitals are aligned in zigzag chains [1, 2]. We calculate the ground state energy of this system to find the most preferable configuration by comparing three types of configurations (charge-unordered, charge-ordered, and charge-orbital-ordered states). The calculations are based on a tight-binding model representing effective electron hoppings among Mn ions in MnO2-plane. We take into account the horizontally- and vertically-oriented orbital and spin degrees of freedom at Mn sites. We assume that the hopping integral values depend on the relative orientation between the corresponding orbitals of adjacent Mn ions. The interaction terms we incorporate into our effective Hamiltonian include inter-orbital, intra-orbital Hubbard repulsions, and Jahn-Teller distortion [2]. We absorb the exchange interaction between spins into local self-energy that we calculate within dynamical mean field algorithm [2]. Within our model we show a circumstance in which the charge-orbital ordered configuration has the lowest energy, consistent with the ground state ordering revealed by the experimental data.

Gravitational radiation from first-order phase transitions

International Nuclear Information System (INIS)

Child, Hillary L.; Giblin, John T. Jr.

2012-01-01

It is believed that first-order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles using only scalar fields, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase enhances this radiation even in the absence of a coupled fluid or turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier

Gravitational radiation from first-order phase transitions

Energy Technology Data Exchange (ETDEWEB)

Child, Hillary L.; Giblin, John T. Jr., E-mail: childh@kenyon.edu, E-mail: giblinj@kenyon.edu [Department of Physics, Kenyon College, 201 North College Road, Gambier, OH 43022 (United States)

2012-10-01

It is believed that first-order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles using only scalar fields, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase enhances this radiation even in the absence of a coupled fluid or turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier.

Spin ordering in three-leg ladders in Ludwigite systems

International Nuclear Information System (INIS)

Vallejo, E.; Avignon, M.

2007-01-01

We study the spin ordering in a three-leg ladder present in Ludwigite systems formed of localized spins interacting with an extra electron per rung. We also consider the competition with super exchange interactions resulting in a very rich phase diagram. Among the phases we find the possibility of ferromagnetic rungs ordered antiferromagnetically and a zigzag spin ordering linked to the formation of a charge ordering as observed

Correction of the deterministic part of space–charge interaction in momentum microscopy of charged particles

Energy Technology Data Exchange (ETDEWEB)

Schönhense, G., E-mail: schoenhense@uni-mainz.de [Institut für Physik, Johannes Gutenberg-Universität, 55128 Mainz (Germany); Medjanik, K. [Institut für Physik, Johannes Gutenberg-Universität, 55128 Mainz (Germany); Tusche, C. [Max-Planck-Institut für Mikrostrukturphysik, 06120 Halle (Germany); Loos, M. de; Geer, B. van der [Pulsar Physics, Burghstraat 47, 5614 BC Eindhoven (Netherlands); Scholz, M.; Hieke, F.; Gerken, N. [Physics Department and Center for Free-Electron Laser Science, Univ. Hamburg, 22761 Hamburg (Germany); Kirschner, J. [Max-Planck-Institut für Mikrostrukturphysik, 06120 Halle (Germany); Wurth, W. [Physics Department and Center for Free-Electron Laser Science, Univ. Hamburg, 22761 Hamburg (Germany); DESY Photon Science, 22607 Hamburg (Germany)

2015-12-15

Ultrahigh spectral brightness femtosecond XUV and X-ray sources like free electron lasers (FEL) and table-top high harmonics sources (HHG) offer fascinating experimental possibilities for analysis of transient states and ultrafast electron dynamics. For electron spectroscopy experiments using illumination from such sources, the ultrashort high-charge electron bunches experience strong space–charge interactions. The Coulomb interactions between emitted electrons results in large energy shifts and severe broadening of photoemission signals. We propose a method for a substantial reduction of the effect by exploiting the deterministic nature of space–charge interaction. The interaction of a given electron with the average charge density of all surrounding electrons leads to a rotation of the electron distribution in 6D phase space. Momentum microscopy gives direct access to the three momentum coordinates, opening a path for a correction of an essential part of space–charge interaction. In a first experiment with a time-of-flight momentum microscope using synchrotron radiation at BESSY, the rotation in phase space became directly visible. In a separate experiment conducted at FLASH (DESY), the energy shift and broadening of the photoemission signals were quantified. Finally, simulations of a realistic photoemission experiment including space–charge interaction reveals that a gain of an order of magnitude in resolution is possible using the correction technique presented here. - Highlights: • Photoemission spectromicroscopy with high-brightness pulsed sources is examined. • Deterministic interaction of an electron with the average charge density can be corrected. • Requires a cathode-lens type microscope optimized for best k-resolution in reciprocal plane. • Extractor field effectively separates pencil beam of secondary electrons from true signal. • Simulations reveal one order of magnitude gain in resolution.

Persistent Charge-Density-Wave Order in Single-Layer TaSe2.

Science.gov (United States)

Ryu, Hyejin; Chen, Yi; Kim, Heejung; Tsai, Hsin-Zon; Tang, Shujie; Jiang, Juan; Liou, Franklin; Kahn, Salman; Jia, Caihong; Omrani, Arash A; Shim, Ji Hoon; Hussain, Zahid; Shen, Zhi-Xun; Kim, Kyoo; Min, Byung Il; Hwang, Choongyu; Crommie, Michael F; Mo, Sung-Kwan

2018-02-14

We present the electronic characterization of single-layer 1H-TaSe 2 grown by molecular beam epitaxy using a combined angle-resolved photoemission spectroscopy, scanning tunneling microscopy/spectroscopy, and density functional theory calculations. We demonstrate that 3 × 3 charge-density-wave (CDW) order persists despite distinct changes in the low energy electronic structure highlighted by the reduction in the number of bands crossing the Fermi energy and the corresponding modification of Fermi surface topology. Enhanced spin-orbit coupling and lattice distortion in the single-layer play a crucial role in the formation of CDW order. Our findings provide a deeper understanding of the nature of CDW order in the two-dimensional limit.

The tight binding model study of the role of anisotropic AFM spin ordering in the charge ordered CMR manganites

Science.gov (United States)

Kar, J. K.; Panda, Saswati; Rout, G. C.

2017-05-01

We propose here a tight binding model study of the interplay between charge and spin orderings in the CMR manganites taking anisotropic effect due to electron hoppings and spin exchanges. The Hamiltonian consists of the kinetic energies of eg and t2g electrons of manganese ion. It further includes double exchange and Heisenberg interactions. The charge density wave interaction (CDW) describes an extra mechanism for the insulating character of the system. The CDW gap and spin parameters are calculated using Zubarev's Green's function technique and computed self-consistently. The results are reported in this communication.

Delocalization Drives Free Charge Generation in Conjugated Polymer Films

Energy Technology Data Exchange (ETDEWEB)

Rumbles, Garry [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Reid, Obadiah G [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Pace, Natalie A [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2018-02-19

We demonstrate that the product of photoinduced electron transfer between a conjugated polymer host and a dilute molecular sensitizer is controlled by the structural state of the polymer. Ordered semicrystalline solids exhibit free charge generation, while disordered polymers in the melt phase do not. We use photoluminescence (PL) and time-resolved microwave conductivity (TRMC) measurements to sweep through polymer melt transitions in situ. Free charge generation measured by TRMC turns off upon melting, whereas PL quenching of the molecular sensitizers remains constant, implying unchanged electron transfer efficiency. The key difference is the intermolecular order of the polymer host in the solid state compared to the melt. We propose that this order-disorder transition modulates the localization length of the initial charge-transfer state, which controls the probability of free charge formation.

Point charges optimally placed to represent the multipole expansion of charge distributions.

Directory of Open Access Journals (Sweden)

Ramu Anandakrishnan

Full Text Available We propose an approach for approximating electrostatic charge distributions with a small number of point charges to optimally represent the original charge distribution. By construction, the proposed optimal point charge approximation (OPCA retains many of the useful properties of point multipole expansion, including the same far-field asymptotic behavior of the approximate potential. A general framework for numerically computing OPCA, for any given number of approximating charges, is described. We then derive a 2-charge practical point charge approximation, PPCA, which approximates the 2-charge OPCA via closed form analytical expressions, and test the PPCA on a set of charge distributions relevant to biomolecular modeling. We measure the accuracy of the new approximations as the RMS error in the electrostatic potential relative to that produced by the original charge distribution, at a distance 2x the extent of the charge distribution--the mid-field. The error for the 2-charge PPCA is found to be on average 23% smaller than that of optimally placed point dipole approximation, and comparable to that of the point quadrupole approximation. The standard deviation in RMS error for the 2-charge PPCA is 53% lower than that of the optimal point dipole approximation, and comparable to that of the point quadrupole approximation. We also calculate the 3-charge OPCA for representing the gas phase quantum mechanical charge distribution of a water molecule. The electrostatic potential calculated by the 3-charge OPCA for water, in the mid-field (2.8 Å from the oxygen atom, is on average 33.3% more accurate than the potential due to the point multipole expansion up to the octupole order. Compared to a 3 point charge approximation in which the charges are placed on the atom centers, the 3-charge OPCA is seven times more accurate, by RMS error. The maximum error at the oxygen-Na distance (2.23 Å is half that of the point multipole expansion up to the octupole

Entanglement scaling at first order quantum phase transitions

Science.gov (United States)

Yuste, A.; Cartwright, C.; De Chiara, G.; Sanpera, A.

2018-04-01

First order quantum phase transitions (1QPTs) are signalled, in the thermodynamic limit, by discontinuous changes in the ground state properties. These discontinuities affect expectation values of observables, including spatial correlations. When a 1QPT is crossed in the vicinity of a second order one, due to the correlation length divergence of the latter, the corresponding ground state is modified and it becomes increasingly difficult to determine the order of the transition when the size of the system is finite. Here we show that, in such situations, it is possible to apply finite size scaling (FSS) to entanglement measures, as it has recently been done for the order parameters and the energy gap, in order to recover the correct thermodynamic limit (Campostrini et al 2014 Phys. Rev. Lett. 113 070402). Such a FSS can unambiguously discriminate between first and second order phase transitions in the vicinity of multicritical points even when the singularities displayed by entanglement measures lead to controversial results.

Bond-order wave phase of the extended Hubbard model: Electronic solitons, paramagnetism, and coupling to Peierls and Holstein phonons

Science.gov (United States)

Kumar, Manoranjan; Soos, Zoltán G.

2010-10-01

The bond-order wave (BOW) phase of the extended Hubbard model (EHM) in one dimension (1D) is characterized at intermediate correlation U=4t by exact treatment of N -site systems. Linear coupling to lattice (Peierls) phonons and molecular (Holstein) vibrations are treated in the adiabatic approximation. The molar magnetic susceptibility χM(T) is obtained directly up to N=10 . The goal is to find the consequences of a doubly degenerate ground state (gs) and finite magnetic gap Em in a regular array. Degenerate gs with broken inversion symmetry are constructed for finite N for a range of V near the charge-density-wave boundary at V≈2.18t where Em≈0.5t is large. The electronic amplitude B(V) of the BOW in the regular array is shown to mimic a tight-binding band with small effective dimerization δeff . Electronic spin and charge solitons are elementary excitations of the BOW phase and also resemble topological solitons with small δeff . Strong infrared intensity of coupled molecular vibrations in dimerized 1D systems is shown to extend to the regular BOW phase while its temperature dependence is related to spin solitons. The Peierls instability to dimerization has novel aspects for degenerate gs and substantial Em that suppresses thermal excitations. Finite Em implies exponentially small χM(T) at low temperature followed by an almost linear increase with T . The EHM with U=4t is representative of intermediate correlations in quasi-1D systems such as conjugated polymers or organic ion-radical and charge-transfer salts. The vibronic and thermal properties of correlated models with BOW phases are needed to identify possible physical realizations.

Non-singlet coefficient functions for charged-current deep-inelastic scattering to the third order in QCD

International Nuclear Information System (INIS)

Davies, J.; Vogt, A.

2016-06-01

We have calculated the coefficient functions for the structure functions F_2, F_L and F_3 in ν- anti ν charged-current deep-inelastic scattering (DIS) at the third order in the strong coupling α_s, thus completing the description of unpolarized inclusive W"±-exchange DIS to this order of massless perturbative QCD. In this brief note, our new results are presented in terms of compact approximate expressions that are sufficiently accurate for phenomenological analyses. For the benefit of such analyses we also collect, in a unified notation, the corresponding lower-order contributions and the flavour non-singlet coefficient functions for ν+ anti ν charged-current DIS. The behaviour of all six third-order coefficient functions at small Bjorken-x is briefly discussed.

Critical behavior and microscopic structure of charged AdS black holes via an alternative phase space

Directory of Open Access Journals (Sweden)

Amin Dehyadegari

2017-05-01

Full Text Available It has been argued that charged Anti-de Sitter (AdS black holes have similar thermodynamic behavior as the Van der Waals fluid system, provided one treats the cosmological constant as a thermodynamic variable (pressure in an extended phase space. In this paper, we disclose the deep connection between charged AdS black holes and Van der Waals fluid system from an alternative point of view. We consider the mass of an AdS black hole as a function of square of the charge Q2 instead of the standard Q, i.e. M=M(S,Q2,P. We first justify such a change of view mathematically and then ask if a phase transition can occur as a function of Q2 for fixed P. Therefore, we write the equation of state as Q2=Q2(T,Ψ where Ψ (conjugate of Q2 is the inverse of the specific volume, Ψ=1/v. This allows us to complete the analogy of charged AdS black holes with Van der Waals fluid system and derive the phase transition as well as critical exponents of the system. We identify a thermodynamic instability in this new picture with real analogy to Van der Waals fluid with physically relevant Maxwell construction. We therefore study the critical behavior of isotherms in Q2–Ψ diagram and deduce all the critical exponents of the system and determine that the system exhibits a small–large black hole phase transition at the critical point (Tc,Qc2,Ψc. This alternative view is important as one can imagine such a change for a given single black hole i.e. acquiring charge which induces the phase transition. Finally, we disclose the microscopic properties of charged AdS black holes by using thermodynamic geometry. Interestingly, we find that scalar curvature has a gap between small and large black holes, and this gap becomes exceedingly large as one moves away from the critical point along the transition line. Therefore, we are able to attribute the sudden enlargement of the black hole to the strong repulsive nature of the internal constituents at the phase transition.

Phase slip process and charge density wave dynamics in a one dimensional conductor

Science.gov (United States)

Habiballah, N.; Zouadi, M.; Arbaoui, A.; Qjani, M.; Dumas, J.

In this paper, we study the phase slip effect on the charge density wave (CDW) dynamics in a one-dimensional conductor in the weak pinning limit. A considerable enhancement of JCDW is observed in the presence of phase slips. In addition, a spatial dependence of the CDW current density JCDW is also studied showing that a decrease of JCDW with distance from the current contact occurs. The results are discussed in terms the relationship between additional phase slips and the mobility of phase dislocations nucleated at electrical contacts.

Multiple ordered phases in a block copolymer melt

DEFF Research Database (Denmark)

Almdal, K.; Koppi, K.A.; Bates, F.S.

1992-01-01

A poly(ethylenepropylene)-poly(ethylethylene) (PEP-PEE) diblock copolymer containing 65% by volume PEP was investigated using small-angle neutron scattering (SANS) and rheological measurements. Four distinct phases have been identified as a function of temperature: three ordered phases at low...

Continuous fractional-order Zero Phase Error Tracking Control.

Science.gov (United States)

Liu, Lu; Tian, Siyuan; Xue, Dingyu; Zhang, Tao; Chen, YangQuan

2018-04-01

A continuous time fractional-order feedforward control algorithm for tracking desired time varying input signals is proposed in this paper. The presented controller cancels the phase shift caused by the zeros and poles of controlled closed-loop fractional-order system, so it is called Fractional-Order Zero Phase Tracking Controller (FZPETC). The controlled systems are divided into two categories i.e. with and without non-cancellable (non-minimum-phase) zeros which stand in unstable region or on stability boundary. Each kinds of systems has a targeted FZPETC design control strategy. The improved tracking performance has been evaluated successfully by applying the proposed controller to three different kinds of fractional-order controlled systems. Besides, a modified quasi-perfect tracking scheme is presented for those systems which may not have available future tracking trajectory information or have problem in high frequency disturbance rejection if the perfect tracking algorithm is applied. A simulation comparison and a hardware-in-the-loop thermal peltier platform are shown to validate the practicality of the proposed quasi-perfect control algorithm. Copyright © 2018 ISA. Published by Elsevier Ltd. All rights reserved.

Holographic entanglement entropy in two-order insulator/superconductor transitions

Energy Technology Data Exchange (ETDEWEB)

Peng, Yan, E-mail: yanpengphy@163.com; Liu, Guohua

2017-04-10

We study holographic superconductor model with two orders in the five dimensional AdS soliton background away from the probe limit. We disclose properties of phase transitions mostly from the holographic topological entanglement entropy approach. Our results show that the entanglement entropy is useful in investigating transitions in this general model and in particular, there is a new type of first order phase transition in the insulator/superconductor system. We also give some qualitative understanding and obtain the analytical condition for this first order phase transition to occur. As a summary, we draw the complete phase diagram representing effects of the scalar charge on phase transitions.

Short locking time and low jitter phase-locked loop based on slope charge pump control

International Nuclear Information System (INIS)

Guo Zhongjie; Liu Youbao; Wu Longsheng; Wang Xihu; Tang Wei

2010-01-01

A novel structure of a phase-locked loop (PLL) characterized by a short locking time and low jitter is presented, which is realized by generating a linear slope charge pump current dependent on monitoring the output of the phase frequency detector (PFD) to implement adaptive bandwidth control. This improved PLL is created by utilizing a fast start-up circuit and a slope current control on a conventional charge pump PLL. First, the fast start-up circuit is enabled to achieve fast pre-charging to the loop filter. Then, when the output pulse of the PFD is larger than a minimum value, the charge pump current is increased linearly by the slope current control to ensure a shorter locking time and a lower jitter. Additionally, temperature variation is attenuated with the temperature compensation in the charge pump current design. The proposed PLL has been fabricated in a kind of DSP chip based on a 0.35 μm CMOS process. Comparing the characteristics with the classical PLL, the proposed PLL shows that it can reduce the locking time by 60% with a low peak-to-peak jitter of 0.3% at a wide operation temperature range. (semiconductor integrated circuits)

A Bayesian Interpretation of First-Order Phase Transitions

Science.gov (United States)

Davis, Sergio; Peralta, Joaquín; Navarrete, Yasmín; González, Diego; Gutiérrez, Gonzalo

2016-03-01

In this work we review the formalism used in describing the thermodynamics of first-order phase transitions from the point of view of maximum entropy inference. We present the concepts of transition temperature, latent heat and entropy difference between phases as emergent from the more fundamental concept of internal energy, after a statistical inference analysis. We explicitly demonstrate this point of view by making inferences on a simple game, resulting in the same formalism as in thermodynamical phase transitions. We show that analogous quantities will inevitably arise in any problem of inferring the result of a yes/no question, given two different states of knowledge and information in the form of expectation values. This exposition may help to clarify the role of these thermodynamical quantities in the context of different first-order phase transitions such as the case of magnetic Hamiltonians (e.g. the Potts model).

Semi-analytic variable charge solitary waves involving dust phase-space vortices (holes)

Energy Technology Data Exchange (ETDEWEB)

Tribeche, Mouloud; Younsi, Smain; Amour, Rabia; Aoutou, Kamel [Plasma Physics Group, Faculty of Sciences-Physics, Theoretical Physics Laboratory, University of Bab-Ezzouar, USTHB BP 32, El Alia, Algiers 16111 (Algeria)], E-mail: mtribeche@usthb.dz

2009-09-15

A semi-analytic model for highly nonlinear solitary waves involving dust phase-space vortices (holes) is outlined. The variable dust charge is expressed in terms of the Lambert function and we take advantage of this transcendental function to investigate the localized structures that may occur in a dusty plasma with variable charge trapped dust particles. Our results which complement the previously published work on this problem (Schamel et al 2001 Phys. Plasmas 8 671) should be of basic interest for experiments that involve the trapping of dust particles in ultra-low-frequency dust acoustic modes.

Semi-analytic variable charge solitary waves involving dust phase-space vortices (holes)

International Nuclear Information System (INIS)

Tribeche, Mouloud; Younsi, Smain; Amour, Rabia; Aoutou, Kamel

2009-01-01

A semi-analytic model for highly nonlinear solitary waves involving dust phase-space vortices (holes) is outlined. The variable dust charge is expressed in terms of the Lambert function and we take advantage of this transcendental function to investigate the localized structures that may occur in a dusty plasma with variable charge trapped dust particles. Our results which complement the previously published work on this problem (Schamel et al 2001 Phys. Plasmas 8 671) should be of basic interest for experiments that involve the trapping of dust particles in ultra-low-frequency dust acoustic modes.

Molecular orientational re-ordering and the transformation of a Landau second order phase transition to first order in a nematic liquid crystal

International Nuclear Information System (INIS)

Ponce, T.C.

1988-08-01

We consider the nature of the nematic to isotropic phase transition in terms of the molecular orientational re-ordering, expressed by the variation of the order parameter, s, in the light of Landau's theory of second order phase transition. Then, we show how the de Gennes modification to the Landau thermodynamic potential converts the transition to first order which is in better agreement with the experimental observations. (author). 9 refs, 2 figs, 1 tab

Photo-induced charge-transfer phase transition of rubidium manganese hexacyanoferrate in ferromagnetic and paramagnetic states

International Nuclear Information System (INIS)

Tokoro, Hiroko; Hashimoto, Kazuhito; Ohkoshi, Shin-ichi

2007-01-01

A charge transfer phase transition with thermal hysteresis loop is observed in a series of rubidium manganese hexacyanoferrates, RbMn[Fe(China) 6 ] (1), Rb 0.88 Mn[Fe(China) 6 ] 0.96 .0.6H 2 O (2), and Rb 0.97 Mn[Fe(China) 6 ] 0.99 .0.2H 2 O (3). This phase transition is accompanied by a structural change from cubic (F4-bar 3m) to tetragonal (I4-bar m2). Its high-temperature (HT) and low-temperature (LT) phases are composed of Mn II (S=2/5)NC-Fe III (S=1/2) and Mn III (S=2)-NC-Fe II (S=0), respectively. The phase transition is caused by a metal-to-metal charge transfer from Mn II to Fe III and a Jahn-Teller distortion of the produced Mn III ion. At the ferromagnetic state in LT phase of 2, the photo-induced phase transition is observed, i.e., magnetization is quenched by the irradiation with only one shot of laser pulse. This phenomenon is caused by a photo-induced phase transition from the LT phase to the HT phase. In 3, optical switching between LT and HT phases at room temperature in paramagnetic region is observed

Charge-regulation phase transition on surface lattices of titratable sites adjacent to electrolyte solutions: An analog of the Ising antiferromagnet in a magnetic field

Science.gov (United States)

Shore, Joel D.; Thurston, George M.

2018-01-01

We report a charge-patterning phase transition on two-dimensional square lattices of titratable sites, here regarded as protonation sites, placed in a low-dielectric medium just below the planar interface between this medium and a salt solution. We calculate the work-of-charging matrix of the lattice with use of a linear Debye-Hückel model, as input to a grand-canonical partition function for the distribution of occupancy patterns. For a large range of parameter values, this model exhibits an approximate inverse cubic power-law decrease of the voltage produced by an individual charge, as a function of its in-lattice separation from neighboring titratable sites. Thus, the charge coupling voltage biases the local probabilities of proton binding as a function of the occupancy of sites for many neighbors beyond the nearest ones. We find that even in the presence of these longer-range interactions, the site couplings give rise to a phase transition in which the site occupancies exhibit an alternating, checkerboard pattern that is an analog of antiferromagnetic ordering. The overall strength W of this canonical charge coupling voltage, per unit charge, is a function of the Debye length, the charge depth, the Bjerrum length, and the dielectric coefficients of the medium and the solvent. The alternating occupancy transition occurs above a curve of thermodynamic critical points in the (pH-pK,W) plane, the curve representing a charge-regulation analog of variation of the Néel temperature of an Ising antiferromagnet as a function of an applied, uniform magnetic field. The analog of a uniform magnetic field in the antiferromagnet problem is a combination of pH-pK and W, and 1/W is the analog of the temperature in the antiferromagnet problem. We use Monte Carlo simulations to study the occupancy patterns of the titratable sites, including interactions out to the 37th nearest-neighbor category (a distance of 74 lattice constants), first validating simulations through

Phase behavior of charged colloids on spherical surfaces

Science.gov (United States)

Kelleher, Colm; Guerra, Rodrigo; Chaikin, Paul

For a broad class of 2D materials, the transition from isotropic fluid to crystalline solid is described by the theory of melting due to Kosterlitz, Thouless, Halperin, Nelson and Young. According to this theory, long-range order is achieved via elimination of the topological defects which proliferate in the fluid phase. However, many natural and man-made 2D systems posses spatial curvature and/or non-trivial topology, which require the presence of defects, even at T = 0 . In principle, the presence of these defects could profoundly affect the phase behavior of such a system. In this presentation, we describe experiments and simulations we have performed on repulsive particles which are bound to the surface of a sphere. We observe spatial structures and inhomogeneous dynamics that cannot be captured by the measures traditionally used to describe flat-space phase behavior. We show that ordering is achieved by a novel mechanism: sequestration of topological defects into freely-terminating grain boundaries (``scars''), and simultaneous spatial organization of the scars themselves on the vertices of an icosahedron. The emergence of icosahedral order coincides with the localization of mobility into isolated ``lakes'' of fluid or glassy particles, situated at the icosahedron vertices.

Equilibrium phase-space distributions and space charge limits in linacs

International Nuclear Information System (INIS)

Lysenko, W.P.

1977-10-01

Limits on beam current and emittance in proton and heavy ion linear accelerators resulting from space charge forces are calculated. The method involves determining equilibrium distributions in phase space using a continuous focusing, no acceleration, model in two degrees of freedom using the coordinates r and z. A nonlinear Poisson equation must be solved numerically. This procedure is a matching between the longitudinal and transverse directions to minimize the effect of longitudinal-transverse coupling which is believed to be the main problem in emittance growth due to space charge in linacs. Limits on the Clinton P. Anderson Meson Physics Facility (LAMPF) accelerator performance are calculated as an example. The beam physics is described by a few space charge parameters so that accelerators with different physical parameters can be compared in a natural way. The main result of this parameter study is that the requirement of a high-intensity beam is best fulfilled with a low-frequency accelerator whereas the requirement of a high-brightness beam is best fulfilled with a high-frequency accelerator

Phase coexistence and electric-field control of toroidal order in oxide superlattices.

Science.gov (United States)

Damodaran, A R; Clarkson, J D; Hong, Z; Liu, H; Yadav, A K; Nelson, C T; Hsu, S-L; McCarter, M R; Park, K-D; Kravtsov, V; Farhan, A; Dong, Y; Cai, Z; Zhou, H; Aguado-Puente, P; García-Fernández, P; Íñiguez, J; Junquera, J; Scholl, A; Raschke, M B; Chen, L-Q; Fong, D D; Ramesh, R; Martin, L W

2017-10-01

Systems that exhibit phase competition, order parameter coexistence, and emergent order parameter topologies constitute a major part of modern condensed-matter physics. Here, by applying a range of characterization techniques, and simulations, we observe that in PbTiO 3 /SrTiO 3 superlattices all of these effects can be found. By exploring superlattice period-, temperature- and field-dependent evolution of these structures, we observe several new features. First, it is possible to engineer phase coexistence mediated by a first-order phase transition between an emergent, low-temperature vortex phase with electric toroidal order and a high-temperature ferroelectric a 1 /a 2 phase. At room temperature, the coexisting vortex and ferroelectric phases form a mesoscale, fibre-textured hierarchical superstructure. The vortex phase possesses an axial polarization, set by the net polarization of the surrounding ferroelectric domains, such that it possesses a multi-order-parameter state and belongs to a class of gyrotropic electrotoroidal compounds. Finally, application of electric fields to this mixed-phase system permits interconversion between the vortex and the ferroelectric phases concomitant with order-of-magnitude changes in piezoelectric and nonlinear optical responses. Our findings suggest new cross-coupled functionalities.

Phase coexistence and electric-field control of toroidal order in oxide superlattices

International Nuclear Information System (INIS)

Damodaran, A. R.; Clarkson, J. D.; Hong, Z.

2017-01-01

Systems that exhibit phase competition, order parameter coexistence, and emergent order parameter topologies constitute a major part of modern condensed-matter physics. Here, by applying a range of characterization techniques, and simulations, we observe that in PbTiO 3 /SrTiO 3 superlattices all of these effects can be found. By exploring superlattice period-, temperature- and field-dependent evolution of these structures, we observe several new features. First, it is possible to engineer phase coexistence mediated by a first-order phase transition between an emergent, low-temperature vortex phase with electric toroidal order and a high-temperature ferroelectric a 1 /a 2 phase. At room temperature, the coexisting vortex and ferroelectric phases form a mesoscale, fibre-textured hierarchical superstructure. The vortex phase possesses an axial polarization, set by the net polarization of the surrounding ferroelectric domains, such that it possesses a multi-order-parameter state and belongs to a class of gyrotropic electrotoroidal compounds. Finally, application of electric fields to this mixed-phase system permits interconversion between the vortex and the ferroelectric phases concomitant with order-of-magnitude changes in piezoelectric and nonlinear optical responses. Here, our findings suggest new cross-coupled functionalities.

Revisiting 63Cu NMR evidence for charge order in superconducting La1.885Sr0.115CuO4

Science.gov (United States)

Imai, T.; Takahashi, S. K.; Arsenault, A.; Acton, A. W.; Lee, D.; He, W.; Lee, Y. S.; Fujita, M.

2017-12-01

The presence of charge and spin stripe order in the La2CuO4 -based family of superconductors continues to lead to new insight on the unusual ground-state properties of high-Tc cuprates. Soon after the discovery of charge stripe order at Tcharge≃65 K in Nd3 + co-doped La1.48Nd0.4Sr0.12CuO4 (Tc≃6 K) [Tranquada et al., Nature (London) 375, 561 (1995), 10.1038/375561a0], Hunt et al. demonstrated that La1.48Nd0.4Sr0.12CuO4 and superconducting La2 -xSrxCuO4 with x ˜1 /8 (Tc≃30 K) share nearly identical NMR anomalies near Tcharge of the former [Phys. Rev. Lett. 82, 4300 (1999), 10.1103/PhysRevLett.82.4300]. Their inevitable conclusion that La1.885Sr0.115CuO4 also undergoes charge order at a comparable temperature became controversial, because diffraction measurements at the time were unable to detect Bragg peaks associated with charge order. Recent advances in x-ray diffraction techniques finally led to definitive confirmations of the charge order Bragg peaks in La1.885Sr0.115CuO4 with an onset at as high as Tcharge≃80 K. Meanwhile, improved instrumental technology has enabled routine NMR measurements that were not feasible two decades ago. Motivated by these new developments, we revisit the charge order transition of a La1.885Sr0.115CuO4 single crystal based on 63Cu NMR techniques. We demonstrate that 63Cu NMR properties of the nuclear spin Iz=-1/2 to +1/2 central transition below Tcharge exhibit unprecedentedly strong dependence on the measurement time scale set by the separation time τ between the 90∘ and 180∘ radio-frequency pulses; a new kind of anomalous, very broad winglike 63Cu NMR signals gradually emerge below Tcharge only for extremely short τ ≲4 μ s , while the spectral weight INormal of the normal NMR signals is progressively wiped out. The NMR linewidth and relaxation rates depend strongly on τ below Tcharge, and their enhancement in the charge ordered state indicates that charge order turns on strong but inhomogeneous growth of Cu spin

Quasi-phase transformation in ferromagnetic semiconductors with two-charged donors

International Nuclear Information System (INIS)

Kovalenko, A.A.; Nagaev, Eh.L.

1978-01-01

Effect of term inversion of two-charged donors 1s2s → 1s 2 on properties of ferromagnetic semiconductors, has been investigated. Term inversion is accompanied by changes in local magnetic ordering in the donor area and takes place as spread phase transformation of the first type in the system of n 2 atoms, enveloped by donor 2s-orbit. It is a reason for creating not only heat capacity peak at Tsub(c), but another peak at inversion temperature Tsub(i) as well. At temperatures T > Tsub(i) introduction of external magnetic field can lead to a reverse term inversion 1s 2 → 1s2s, under that condition crystal magnetization should clearly increase. Term inversion tells upon electric properties of crystals: in Ti inversion point, the energy of conductivity activation of ungenerate semiconductors changes abruptly. In the case of larger concentrations of donors, term inversion can lead to metal-insulator transformation. Analysis of experimental data on magnetic susceptibility of EuO crystals with oxygen vacancies, shows that transformation in these crystals takes place according to a different mechanism

Low to High Spin-State Transition Induced by Charge Ordering in Antiferromagnetic YBaCo2O5

International Nuclear Information System (INIS)

Vogt, T.; Woodward, P. M.; Karen, P.; Hunter, B. A.; Henning, P.; Moodenbaugh, A. R.

2000-01-01

The oxygen-deficient double perovskite YBaCo 2 O 5 , containing corner-linked CoO 5 square pyramids as principal building units, undergoes a paramagnetic to antiferromagnetic spin ordering at 330 K. This is accompanied by a tetragonal to orthorhombic distortion. Below 220 K orbital ordering and long-range Co 2+ /Co 3+ charge ordering occur as well as a change in the Co 2+ spin state from low to high spin. This transition is shown to be very sensitive to the oxygen content of the sample. To our knowledge this is the first observation of a spin-state transition induced by long-range orbital and charge ordering. (c) 2000 The American Physical Society

Charge disproportionation of mixed-valent Cr triggered by Bi lone-pair effect in the A -site-ordered perovskite BiC u3C r4O12

Science.gov (United States)

Etter, Martin; Isobe, Masahiko; Sakurai, Hiroya; Yaresko, Alexander; Dinnebier, Robert E.; Takagi, Hidenori

2018-05-01

A new A -site-ordered perovskite BiC u3C r4O12 is synthesized under a high pressure of 7.7 GPa. A phase transition from a paramagnetic metal to a ferrimagnetic metal is observed at Tc=190 K accompanied with a structural change from cubic to monoclinic. Structural analysis of the low-temperature monoclinic phase reveals that this transition represents a charge disproportionation of C r3.75 + into C r4 + and C r3.5 + . We argue that the asymmetric displacement of Bi caused by a lone-pair effect triggers the formation of a dimeric Cr4+2O5 unit and leads to an ordering of C r4 + and C r3.5 + below the transition.

Short range charge/orbital ordering in La{sub 1-x}Sr{sub x}Mn{sub 1-z}B{sub z}O{sub 3} (B Cu,Zn) manganites

Energy Technology Data Exchange (ETDEWEB)

Popovic, Z V [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Cantarero, A [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Thijssen, W H A [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Paunovic, N [Centre for Solid State Physics and New Materials, Institute of Physics, PO Box 68, 11080 Belgrade/Zemun (Serbia and Montenegro); Dohcevic-Mitrovic, Z [Centre for Solid State Physics and New Materials, Institute of Physics, PO Box 68, 11080 Belgrade/Zemun (Serbia and Montenegro); Sapina, F [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain)

2005-01-19

We have measured the reflectivity spectra of La{sub 1-x}Sr{sub x}Mn{sub 1-z}B{sub z}O{sub 3} (B = Cu, Zn; 0.17 {<=} x {<=} 0.30; 0 {<=} z {<=} 0.10) manganites over wide frequency (100-4000 cm{sup -1}) and temperature (80-300 K) ranges. Besides the previously observed infrared active modes or mode pairs at about 160 cm{sup -1} (external mode), 350 cm{sup -1} (bond bending mode) and 590 cm{sup -1} (bond stretching mode), we have clearly observed two additional phonon modes at about 645 and 720 cm{sup -1} below the temperature T{sub 1} (T{sub 1}phase transition temperature when the system transforms from ferromagnetic metallic into a ferromagnetic insulator state. This transition is related to the formation of short range charge/orbitally ordered domains. The temperature T{sub 1} of the phase transition is dependent on the doping concentration and for optimally doped samples we have found that T{sub 1} {approx}(0.93 {+-} 0.02) T{sub C}. Electrical resistivity and magnetization measurements versus temperature and magnetic field support the short range charge/orbital ordering scenario.

Phase shift PWM with double two-switch bridge for high power capacitor charging

International Nuclear Information System (INIS)

Karandikar, U.S.; Singh, Yashpal; Thakurta, A.C.

2013-01-01

Pulse power supply systems working at higher voltage and high repetition rate demands for higher power from capacitor chargers. Capacitor charging requirement become more challenging in such cases. In pulse power circuits, energy storage capacitor should be charged to its desired voltage before the next switching occurs. It is discharged within a small time, delivering large pulse power. A capacitor charger has to work with wide load variation repeatedly. Many schemes are used for this purpose. The proposed scheme aims at reducing stresses on switches by reducing peak current and their evils. A high voltage power supply is designed for capacitor charging. The proposed scheme is based on a Phase-Shifted PWM without using any extra component to achieve soft switching. Indirect constant average current capacitor charging is achieved with a simple control scheme. A double two-switch bridge is proposed to enhance reliability. Power supply has been developed to charge a capacitor of 50 μF to 2.5 kV at 25 Hz. (author)

Twinning microstructure and charge ordering in the colossal magnetoresistive manganite Nd1/2Sr1/2MnO3

International Nuclear Information System (INIS)

Luo, Z.P.; Miller, D.J.; Mitchell, J.F.

2000-01-01

Charge ordering (C.O.) in the colossal magnetoresistive (CMR) manganites gives rise to an insulating, high-resistance state. This charge ordered state can be melted into a low-resistance metallic-like state by the application of magnetic field. Thus, the potential to attain high values of magnetoresistance with the application of small magnetic fields may be aided by a better understanding of the charge-ordering phenomenon. This study focused on microstructural characterization in Nd 1/2 Sr 1/2 MnO 3 . In Nd 1/2 Sr 1/2 MnO 3 , the nominal valence of Mn is 3.5+. On cooling, charge can localize and lead to a charge ordering between Mn 3+ and Mn 4+. The ordering of charge results in a superlattice structure and a reduction in symmetry. Thin foil specimens were prepared from bulk samples by conventional thinning and ion milling (at LiqN 2 temperature) methods. The room temperature TEM observation of Nd 1/2 Sr 1/2 MnO 3 reveals that it contains a highly twinned microstructure, together with a small number of stacking faults (SFS). A figure shows the same area of the specimen at different zone axes obtained by tilting around two perpendicular directions as indicated. Three grains A, B and C are labeled for each of the zone axes. The room temperature EDPs from the matrix and twins shows an approximate 90degree rotation suggesting a 90degree twin orientation. These results are further confirmed by C.O. at low temperatures. The twinning planes can be determined by tilting with large angles

Amperean Pairing and the Pseudogap Phase of Cuprate Superconductors

Science.gov (United States)

Lee, Patrick A.

2014-07-01

The enigmatic pseudogap phase in underdoped cuprate high-Tc superconductors has long been recognized as a central puzzle of the Tc problem. Recent data show that the pseudogap is likely a distinct phase, characterized by a medium range and quasistatic charge ordering. However, the origin of the ordering wave vector and the mechanism of the charge order is unknown. At the same time, earlier data show that precursive superconducting fluctuations are also associated with this phase. We propose that the pseudogap phase is a novel pairing state where electrons on the same side of the Fermi surface are paired, in strong contrast with conventional Bardeen-Cooper-Schrieffer theory which pairs electrons on opposite sides of the Fermi surface. In this state the Cooper pair carries a net momentum and belongs to a general class called pair density wave. The microscopic pairing mechanism comes from a gauge theory formulation of the resonating valence bond (RVB) picture, where spinons traveling in the same direction feel an attractive force in analogy with Ampere's effects in electromagnetism. We call this Amperean pairing. Charge order automatically appears as a subsidiary order parameter even when long-range pair order is destroyed by phase fluctuations. Our theory gives a prediction of the ordering wave vector which is in good agreement with experiment. Furthermore, the quasiparticle spectrum from our model explains many of the unusual features reported in photoemission experiments. The Fermi arc, the unusual way the tip of the arc terminates, and the relation of the spanning vector of the arc tips to the charge ordering wave vector also come out naturally. Finally, we propose an experiment that can directly test the notion of Amperean pairing.

Charge dynamics of the antiferromagnetically ordered Mott insulator

International Nuclear Information System (INIS)

Han, Xing-Jie; Li, Xin; Chen, Jing; Liao, Hai-Jun; Xiang, Tao; Liu, Yu; Liu, Zhi-Yuan; Xie, Zhi-Yuan; Normand, B

2016-01-01

We introduce a slave-fermion formulation in which to study the charge dynamics of the half-filled Hubbard model on the square lattice. In this description, the charge degrees of freedom are represented by fermionic holons and doublons and the Mott-insulating characteristics of the ground state are the consequence of holon–doublon bound-state formation. The bosonic spin degrees of freedom are described by the antiferromagnetic Heisenberg model, yielding long-ranged (Néel) magnetic order at zero temperature. Within this framework and in the self-consistent Born approximation, we perform systematic calculations of the average double occupancy, the electronic density of states, the spectral function and the optical conductivity. Qualitatively, our method reproduces the lower and upper Hubbard bands, the spectral-weight transfer into a coherent quasiparticle band at their lower edges and the renormalisation of the Mott gap, which is associated with holon–doublon binding, due to the interactions of both quasiparticle species with the magnons. The zeros of the Green function at the chemical potential give the Luttinger volume, the poles of the self-energy reflect the underlying quasiparticle dispersion with a spin-renormalised hopping parameter and the optical gap is directly related to the Mott gap. Quantitatively, the square-lattice Hubbard model is one of the best-characterised problems in correlated condensed matter and many numerical calculations, all with different strengths and weaknesses, exist with which to benchmark our approach. From the semi-quantitative accuracy of our results for all but the weakest interaction strengths, we conclude that a self-consistent treatment of the spin-fluctuation effects on the charge degrees of freedom captures all the essential physics of the antiferromagnetic Mott–Hubbard insulator. We remark in addition that an analytical approximation with these properties serves a vital function in developing a full understanding of

Charge dynamics of the antiferromagnetically ordered Mott insulator

Science.gov (United States)

Han, Xing-Jie; Liu, Yu; Liu, Zhi-Yuan; Li, Xin; Chen, Jing; Liao, Hai-Jun; Xie, Zhi-Yuan; Normand, B.; Xiang, Tao

2016-10-01

We introduce a slave-fermion formulation in which to study the charge dynamics of the half-filled Hubbard model on the square lattice. In this description, the charge degrees of freedom are represented by fermionic holons and doublons and the Mott-insulating characteristics of the ground state are the consequence of holon-doublon bound-state formation. The bosonic spin degrees of freedom are described by the antiferromagnetic Heisenberg model, yielding long-ranged (Néel) magnetic order at zero temperature. Within this framework and in the self-consistent Born approximation, we perform systematic calculations of the average double occupancy, the electronic density of states, the spectral function and the optical conductivity. Qualitatively, our method reproduces the lower and upper Hubbard bands, the spectral-weight transfer into a coherent quasiparticle band at their lower edges and the renormalisation of the Mott gap, which is associated with holon-doublon binding, due to the interactions of both quasiparticle species with the magnons. The zeros of the Green function at the chemical potential give the Luttinger volume, the poles of the self-energy reflect the underlying quasiparticle dispersion with a spin-renormalised hopping parameter and the optical gap is directly related to the Mott gap. Quantitatively, the square-lattice Hubbard model is one of the best-characterised problems in correlated condensed matter and many numerical calculations, all with different strengths and weaknesses, exist with which to benchmark our approach. From the semi-quantitative accuracy of our results for all but the weakest interaction strengths, we conclude that a self-consistent treatment of the spin-fluctuation effects on the charge degrees of freedom captures all the essential physics of the antiferromagnetic Mott-Hubbard insulator. We remark in addition that an analytical approximation with these properties serves a vital function in developing a full understanding of the

Thermal algebraic-decay charge liquid driven by competing short-range Coulomb repulsion

Science.gov (United States)

Kaneko, Ryui; Nonomura, Yoshihiko; Kohno, Masanori

2018-05-01

We explore the possibility of a Berezinskii-Kosterlitz-Thouless-like critical phase for the charge degrees of freedom in the intermediate-temperature regime between the charge-ordered and disordered phases in two-dimensional systems with competing short-range Coulomb repulsion. As the simplest example, we investigate the extended Hubbard model with on-site and nearest-neighbor Coulomb interactions on a triangular lattice at half filling in the atomic limit by using a classical Monte Carlo method, and find a critical phase, characterized by algebraic decay of the charge correlation function, belonging to the universality class of the two-dimensional XY model with a Z6 anisotropy. Based on the results, we discuss possible conditions for the critical phase in materials.

Phase-only optical encryption based on the zeroth-order phase-contrast technique

Science.gov (United States)

Pizolato, José Carlos; Neto, Luiz Gonçalves

2009-09-01

A phase-only encryption/decryption scheme with the readout based on the zeroth-order phase-contrast technique (ZOPCT), without the use of a phase-changing plate on the Fourier plane of an optical system based on the 4f optical correlator, is proposed. The encryption of a gray-level image is achieved by multiplying the phase distribution obtained directly from the gray-level image by a random phase distribution. The robustness of the encoding is assured by the nonlinearity intrinsic to the proposed phase-contrast method and the random phase distribution used in the encryption process. The experimental system has been implemented with liquid-crystal spatial modulators to generate phase-encrypted masks and a decrypting key. The advantage of this method is the easy scheme to recover the gray-level information from the decrypted phase-only mask applying the ZOPCT. An analysis of this decryption method was performed against brute force attacks.

Influence of composition on phase occurrence during charge process of AB5+x Ni-MH negative electrode materials

International Nuclear Information System (INIS)

Vivet, S.; Latroche, M.; Chabre, Y.; Joubert, J.-M.; Knosp, B.; Percheron-Guegan, A.

2005-01-01

Multi-substituted LaNi 5 -type alloys (AB 5+ x ) are widely used as negative electrode materials in commercial Ni-MH batteries. Cobalt substitution on Ni sites allows to enhance battery cycle life by reducing alloy pulverization induced by hydrogen cycling. This improvement is attributed to the occurrence of a three-phase process (α, β and γ) during electrochemical hydrogen loading. In order to better understand the effect of the composition on the phase occurrence and to reduce the rate of costly cobalt, an in situ neutron diffraction study has been performed at room temperature during electrochemical charge of two different electrode materials MmNi 4.07 Mn 0.63 Al 0.2 M 0.4 with M=Fe and Mn and B/A=5.3. These cobalt free compounds show cycle life comparable to that of commercial materials. The results show that three phases are also observed for these samples. The γ-phase content depends on M and is higher for M=Fe than for M=Mn. These results are related to the improved cycle lives and to the alloy pulverization process

Magnetic ordering and charge transport in electron-doped La1-yCeyMnO3 (0.1 ≤ y ≤ 0.3) films

International Nuclear Information System (INIS)

Prokhorov, V.G.; Kaminsky, G.G.; Flis, V.S.; Hyun, Y.H.; Park, S.Y.; Lee, Y.P.; Svetchnikov, V.L.

2009-01-01

The microstructure and the magnetic and transport properties of as-deposited La 10-y Ce y MnO 3 (0.1≤ y≤ 0.3) films prepared by pulsed laser deposition are investigated in a wide region of temperature and magnetic field. The microstructure analysis reveals that all films have a high c-oriented texture, an orthorhombic crystal lattice, and a negligible quantity of CeO 2 inclusions. The observed strip-domain phase with a periodic spacing of about 3c, the crystal lattice of which is the same as for the basic film phase, exhibits magnetic behavior typical for the Griffiths phase. Regions of the double-period modulated phase are found at room temperature in the y=0.1 film, which is interpreted as Mn 3+ /Mn 2+ ordering with a partial ferromagnetic → antiferromagnetic transition at T N ≤ 80 K. At the same time, the investigation reveals that the magnetic and transport properties of the electron-doped La 1-y Ce y MnO 3 films, driven by cation doping, are similar to those for the hole-doped La/Ca manganites. Therefore, one can conclude that there is no fundamental difference between the mechanisms of spin ordering and charge transport in the hole-doped and electron-doped manganites

Spiro-OMeTAD single crystals: Remarkably enhanced charge-carrier transport via mesoscale ordering

KAUST Repository

Shi, Dong

2016-04-15

We report the crystal structure and hole-transport mechanism in spiro-OMeTAD [2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)9,9′-spirobifluorene], the dominant hole-transporting material in perovskite and solid-state dye-sensitized solar cells. Despite spiro-OMeTAD’s paramount role in such devices, its crystal structure was unknown because of highly disordered solution-processed films; the hole-transport pathways remained ill-defined and the charge carrier mobilities were low, posing a major bottleneck for advancing cell efficiencies. We devised an antisolvent crystallization strategy to grow single crystals of spiro-OMeTAD, which allowed us to experimentally elucidate its molecular packing and transport properties. Electronic structure calculations enabled us to map spiro-OMeTAD’s intermolecular charge-hopping pathways. Promisingly, single-crystal mobilities were found to exceed their thin-film counterparts by three orders of magnitude. Our findings underscore mesoscale ordering as a key strategy to achieving breakthroughs in hole-transport material engineering of solar cells.

Charge density wave instabilities and incommensurate structural phase transformations

International Nuclear Information System (INIS)

Axe, J.D.

1977-10-01

Incommensurate structural phase transformations involve the appearance of modulated atomic displacements with spatial periodicity unrelated to the fundamental periodicity of the basic lattice. In the case of some quasi one- or two-dimensional metals such transformations are the result of Fermi-surface instabilities that also produce electronic charge density waves (CDW's) and soft phonon modes due to metallic electron screening singularities. Incommensurate soft mode instabilities have been found in insulators as well. Recent neutron scattering studies of both the statics and dynamics of incommensurate structural instabilities will be reviewed

Higher-order phase transitions on financial markets

Science.gov (United States)

Kasprzak, A.; Kutner, R.; Perelló, J.; Masoliver, J.

2010-08-01

Statistical and thermodynamic properties of the anomalous multifractal structure of random interevent (or intertransaction) times were thoroughly studied by using the extended continuous-time random walk (CTRW) formalism of Montroll, Weiss, Scher, and Lax. Although this formalism is quite general (and can be applied to any interhuman communication with nontrivial priority), we consider it in the context of a financial market where heterogeneous agent activities can occur within a wide spectrum of time scales. As the main general consequence, we found (by additionally using the Saddle-Point Approximation) the scaling or power-dependent form of the partition function, Z(q'). It diverges for any negative scaling powers q' (which justifies the name anomalous) while for positive ones it shows the scaling with the general exponent τ(q'). This exponent is the nonanalytic (singular) or noninteger power of q', which is one of the pilar of higher-order phase transitions. In definition of the partition function we used the pausing-time distribution (PTD) as the central one, which takes the form of convolution (or superstatistics used, e.g. for describing turbulence as well as the financial market). Its integral kernel is given by the stretched exponential distribution (often used in disordered systems). This kernel extends both the exponential distribution assumed in the original version of the CTRW formalism (for description of the transient photocurrent measured in amorphous glassy material) as well as the Gaussian one sometimes used in this context (e.g. for diffusion of hydrogen in amorphous metals or for aging effects in glasses). Our most important finding is the third- and higher-order phase transitions, which can be roughly interpreted as transitions between the phase where high frequency trading is most visible and the phase defined by low frequency trading. The specific order of the phase transition directly depends upon the shape exponent α defining the stretched

Phase behaviour of charged colloidal sphere dispersions with added polymer chains

International Nuclear Information System (INIS)

Fortini, Andrea; Dijkstra, Marjolein; Tuinier, Remco

2005-01-01

We study the stability of mixtures of highly screened repulsive charged spheres and non-adsorbing ideal polymer chains in a common solvent using free volume theory. The effective interaction between charged colloids in an aqueous salt solution is described by a screened Coulomb pair potential, which supplements the pure hard-sphere interaction. The ideal polymer chains are treated as spheres that are excluded from the colloids by a hard-core interaction, whereas the interaction between two ideal chains is set to zero. In addition, we investigate the phase behaviour of charged colloid-polymer mixtures in computer simulations, using the two-body (Asakura-Oosawa pair potential) approximation to the effective one-component Hamiltonian of the charged colloids. Both our results obtained from simulations and from free volume theory show similar trends. We find that the screened Coulomb repulsion counteracts the effect of the effective polymer-mediated attraction. For mixtures of small polymers and relatively large charged colloidal spheres, the fluid-crystal transition shifts to significantly larger polymer concentrations with increasing range of the screened Coulomb repulsion. For relatively large polymers, the effect of the screened Coulomb repulsion is weaker. The resulting fluid-fluid binodal is only slightly shifted towards larger polymer concentrations upon increasing the range of the screened Coulomb repulsion. In conclusion, our results show that the miscibility of dispersions containing charged colloids and neutral non-adsorbing polymers increases upon increasing the range of the screened Coulomb repulsion, or upon lowering the salt concentration, especially when the polymers are small compared to the colloids

Dependence of charge transfer phenomena during solid-air two-phase flow on particle disperser

Science.gov (United States)

Tanoue, Ken-ichiro; Suedomi, Yuuki; Honda, Hirotaka; Furutani, Satoshi; Nishimura, Tatsuo; Masuda, Hiroaki

2012-12-01

An experimental investigation of the tribo-electrification of particles has been conducted during solid-air two-phase turbulent flow. The current induced in a metal plate by the impact of polymethylmethacrylate (PMMA) particles in a high-speed air flow was measured for two different plate materials. The results indicated that the contact potential difference between the particles and a stainless steel plate was positive, while for a nickel plate it was negative. These results agreed with theoretical contact charge transfer even if not only the particle size but also the kind of metal plate was changed. The specific charge of the PMMA particles during solid-air two-phase flow using an ejector, a stainless steel branch pipe, and a stainless steel straight pipe was measured using a Faraday cage. Although the charge was negative in the ejector, the particles had a positive specific charge at the outlet of the branch pipe, and this positive charge increased in the straight pipe. The charge decay along the flow direction could be reproduced by the charging and relaxation theory. However, the proportional coefficients in the theory changed with the particle size and air velocity. Therefore, an unexpected charge transfer occurred between the ejector and the branch pipe, which could not be explained solely by the contact potential difference. In the ejector, an electrical current in air might have been produced by self-discharge of particles with excess charge between the nickel diffuser in the ejector and the stainless steel nozzle or the stainless steel pipe due to a reversal in the contact potential difference between the PMMA and the stainless steel. The sign of the current depended on the particle size, possibly because the position where the particles impacted depended on their size. When dual coaxial glass pipes were used as a particle disperser, the specific charge of the PMMA particles became more positive along the particle flow direction due to the contact

Quantum corrections for the phase diagram of systems with competing order

Science.gov (United States)

Silva, N. L., Jr.; Continentino, Mucio A.; Barci, Daniel G.

2018-06-01

We use the effective potential method of quantum field theory to obtain the quantum corrections to the zero temperature phase diagram of systems with competing order parameters. We are particularly interested in two different scenarios: regions of the phase diagram where there is a bicritical point, at which both phases vanish continuously, and the case where both phases coexist homogeneously. We consider different types of couplings between the order parameters, including a bilinear one. This kind of coupling breaks time-reversal symmetry and it is only allowed if both order parameters transform according to the same irreducible representation. This occurs in many physical systems of actual interest like competing spin density waves, different types of orbital antiferromagnetism, elastic instabilities of crystal lattices, vortices in a multigap SC and also applies to describe the unusual magnetism of the heavy fermion compound URu2Si2. Our results show that quantum corrections have an important effect on the phase diagram of systems with competing orders.

Quantum corrections for the phase diagram of systems with competing order.

Science.gov (United States)

Silva, N L; Continentino, Mucio A; Barci, Daniel G

2018-06-06

We use the effective potential method of quantum field theory to obtain the quantum corrections to the zero temperature phase diagram of systems with competing order parameters. We are particularly interested in two different scenarios: regions of the phase diagram where there is a bicritical point, at which both phases vanish continuously, and the case where both phases coexist homogeneously. We consider different types of couplings between the order parameters, including a bilinear one. This kind of coupling breaks time-reversal symmetry and it is only allowed if both order parameters transform according to the same irreducible representation. This occurs in many physical systems of actual interest like competing spin density waves, different types of orbital antiferromagnetism, elastic instabilities of crystal lattices, vortices in a multigap SC and also applies to describe the unusual magnetism of the heavy fermion compound URu 2 Si 2 . Our results show that quantum corrections have an important effect on the phase diagram of systems with competing orders.

X-ray absorption measurements of charge-ordered La{sub 0.5}Sr{sub 1.5}MnO{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Saitoh, T.; Villella, P.M.; Dessau, D.S. [Univ. of Colorado, Boulder, CO (United States)] [and others

1997-04-01

Perovskite and {open_quotes}layered perovskite{close_quotes}-type manganese oxides show a variety of electronic and magnetic properties such as the colossal magnetoresistance (CMR) or the charge ordering. Among them, La{sub 0.5}Sr{sub 1.5}MnO{sub 4} (K{sub 2}NiF{sub 4} structure) which has 0.5 holes per Mn site (d{sup 3.5}) shows the charge-order transition at {approximately}220 K below which Mn{sup 3+} and Mn{sup 4+} sites are believed to order in the CE-type. Although the charge ordering phenomenon has also been observed in the perovskite manganites Pr{sub 0.5}Sr{sub 1.5}MnO{sub 3} or Pr{sub 0.5}Ca{sub 1.5}MnO{sub 3}, the present system has another advantage that it has a layered structure. This enables the authors to address the issue of the orbital symmetry which should be directly related to the charge ordering. In this report, they present the results of x-ray absorption spectroscopy (XAS) on La{sub 0.5}Sr{sub 1.5}MnO{sub 4}, for two polarization angles and two (above and below the transition temperature T{sub CO}) temperatures.

Quantum phase transition with dissipative frustration

Science.gov (United States)

Maile, D.; Andergassen, S.; Belzig, W.; Rastelli, G.

2018-04-01

We study the quantum phase transition of the one-dimensional phase model in the presence of dissipative frustration, provided by an interaction of the system with the environment through two noncommuting operators. Such a model can be realized in Josephson junction chains with shunt resistances and resistances between the chain and the ground. Using a self-consistent harmonic approximation, we determine the phase diagram at zero temperature which exhibits a quantum phase transition between an ordered phase, corresponding to the superconducting state, and a disordered phase, corresponding to the insulating state with localized superconducting charge. Interestingly, we find that the critical line separating the two phases has a nonmonotonic behavior as a function of the dissipative coupling strength. This result is a consequence of the frustration between (i) one dissipative coupling that quenches the quantum phase fluctuations favoring the ordered phase and (ii) one that quenches the quantum momentum (charge) fluctuations leading to a vanishing phase coherence. Moreover, within the self-consistent harmonic approximation, we analyze the dissipation induced crossover between a first and second order phase transition, showing that quantum frustration increases the range in which the phase transition is second order. The nonmonotonic behavior is reflected also in the purity of the system that quantifies the degree of correlation between the system and the environment, and in the logarithmic negativity as an entanglement measure that encodes the internal quantum correlations in the chain.

Structural studies of charge disproportionation and magnetic order in CaFeO3

International Nuclear Information System (INIS)

Woodward, P.M.; Cox, D.E.; Moshopoulou, E.; Sleight, A.W.; Morimoto, S.

2000-01-01

The crystal and magnetic structures of CaFeO 3 have been determined at 300 and 15 K using synchrotron x-ray and neutron powder-diffraction techniques. At 300 K, CaFeO 3 adopts the GdFeO 3 structure, space group Pbnm with unit-cell dimensions a=5.326 30(4), b=5.352 70(4), and c=7.539 86(6) A. This structure is distorted from the ideal perovskite structure by tilting of the FeO 6 octahedra about [110] and [001]. The average Fe-O distance is 1.922(2) A, and the Fe-O-Fe angles are 158.4(2) deg. and 158.1(1) deg. . At 15 K the crystal structure belongs to space group P2 1 /n with a=5.311 82(3), b=5.347 75(4), c=7.520 58(5) A and β=90.065(1) deg. , and contains two distinct Fe sites. The average Fe-O bond length is 1.872(6) A about the one iron site, and 1.974(6) A about the second site, with bond valence sums of 4.58 and 3.48, respectively. This provides quantitative evidence for charge disproportionation, 2Fe 4+ →Fe 3+ +Fe 5+ , at low temperature. The temperature evolution of the lattice parameters indicates a second- (or higher-) order phase transition from the orthorhombic charge-delocalized state to the monoclinic charge-disproportionated state, beginning just below room temperature. The magnetic structure at 15 K is incommensurate, having a modulation vector [δ,0,δ] with δ ∼0.322, corresponding to one of the directions in the pseudocubic cell. A reasonable fit to the magnetic intensities is obtained with the recently proposed screw spiral structure [S. Kawasaki et al., J. Phys. Soc. Jpn. 67, 1529 (1998)], with Fe moments of 3.5 and 2.5μ B , respectively. However, a comparable fit is given by a sinusoidal amplitude-modulated model in which the Fe moments are directed along [010], which leaves open the possibility that the true magnetic structure may be intermediate between the spiral and sinusoidal models (a fan structure)

Geometric phases in astigmatic optical modes of arbitrary order

International Nuclear Information System (INIS)

Habraken, Steven J. M.; Nienhuis, Gerard

2010-01-01

The transverse spatial structure of a paraxial beam of light is fully characterized by a set of parameters that vary only slowly under free propagation. They specify bosonic ladder operators that connect modes of different orders, in analogy to the ladder operators connecting harmonic-oscillator wave functions. The parameter spaces underlying sets of higher-order modes are isomorphic to the parameter space of the ladder operators. We study the geometry of this space and the geometric phase that arises from it. This phase constitutes the ultimate generalization of the Gouy phase in paraxial wave optics. It reduces to the ordinary Gouy phase and the geometric phase of nonastigmatic optical modes with orbital angular momentum in limiting cases. We briefly discuss the well-known analogy between geometric phases and the Aharonov-Bohm effect, which provides some complementary insights into the geometric nature and origin of the generalized Gouy phase shift. Our method also applies to the quantum-mechanical description of wave packets. It allows for obtaining complete sets of normalized solutions of the Schroedinger equation. Cyclic transformations of such wave packets give rise to a phase shift, which has a geometric interpretation in terms of the other degrees of freedom involved.

Charging of carbon thin films in scanning and phase-plate transmission electron microscopy

DEFF Research Database (Denmark)

Hettler, Simon; Kano, Emi; Dries, Manuel

2018-01-01

A systematic study on charging of carbon thin films under intense electron-beam irradiation was performed in a transmission electron microscope to identify the underlying physics for the functionality of hole-free phase plates. Thin amorphous carbon films fabricated by different deposition techni...

Conserved charge fluctuations at vanishing and non-vanishing chemical potential

Science.gov (United States)

Karsch, Frithjof

2017-11-01

Up to 6th order cumulants of fluctuations of net baryon-number, net electric charge and net strangeness as well as correlations among these conserved charge fluctuations are now being calculated in lattice QCD. These cumulants provide a wealth of information on the properties of strong-interaction matter in the transition region from the low temperature hadronic phase to the quark-gluon plasma phase. They can be used to quantify deviations from hadron resonance gas (HRG) model calculations which frequently are used to determine thermal conditions realized in heavy ion collision experiments. Already some second order cumulants like the correlations between net baryon-number and net strangeness or net electric charge differ significantly at temperatures above 155 MeV in QCD and HRG model calculations. We show that these differences increase at non-zero baryon chemical potential constraining the applicability range of HRG model calculations to even smaller values of the temperature.

The model of metal-insulator phase transition in vanadium oxide

International Nuclear Information System (INIS)

Vikhnin, V.S.; Lysenko, S.; Rua, A.; Fernandez, F.; Liu, H.

2005-01-01

Thermally induced metal-insulator phase transitions (PT) in VO 2 thin films are studied theoretically and experimentally. The hysteresis phenomena in the region of the transition for different type thin films were investigated. The phenomenological model of the PT is suggested. The charge transfer-lattice instability in VO 2 metallic phase is considered as basis of the first order metal-insulator PT in VO 2 . The charge transfer is treated as an order parameter

Effects of Hydrogen Charging on the Phase Transformation of Martensitic NiTi Shape Memory Alloy Wires

Science.gov (United States)

Snir, Yoav; Carl, Matthew; Ley, Nathan A.; Young, Marcus L.

2017-12-01

Ti-rich martensitic NiTi shape memory alloy (SMA) wires of 0.5 mm diameter were tested under hydrogen-charging conditions to reveal the effects on phase transformation. Hydrogen charging was performed by immersion testing for several durations. The SMA wires were characterized by differential scanning calorimetry (DSC), scanning electron microscopy with energy dispersive spectroscopy, and synchrotron radiation X-ray diffraction (SR-XRD) for the the as-received, polished, and hydrogen-charged conditions. The DSC revealed the phase-transformation behavior of the NiTi SMA wires. Single and triple heating/cooling cycles in the DSC show the relationship between hydrogen and temperature on the material. Five distinct peaks (peaks I-V) are observed during heating/cooling in the DSC. Peak I corresponds to the martensite-to-austenite (M → A) transformation. Peaks II, III, and IV are related to hydrogen charging. Peak II appears at about 210-230 °C, while peaks III and IV appear at about 350 and 440 °C, respectively. These higher temperature peaks, peaks II-IV, were observed for the first time for a martensitic NiTi SMA due to the large temperature range covered using the DSC. Only one peak (peak V) appears during cooling and corresponds to the austenite-to-martensite transformation peak. Ex situ and in situ SR-XRD revealed the phases and the crystallographic relationship to peaks I-V in the DSC.

Order-disorder phase transition in ZrV2Dsub(3.6)

International Nuclear Information System (INIS)

Didisheim, J.-J.; Yvon, K.; Tissot, P.

1981-01-01

The deuterated C15-type Laves phase ZrV 2 Dsub(3.6) undergoes a structural phase transition near room temperature (T of the order of 325 K). In the cubic high-temperature phase the deuterium atoms are disordered over two types of tetrahedral interstices, the centres of which are 1.3 A apart. In the tetragonal low-temperature phase the D atoms are ordered and occupy only the energetically more favourable interstices. The tetragonal structure is isotypic with the low-temperature phase of HfV 2 D 4 . The shortest D-D distance is 2.1 A. (author)

A crystalline quark-hadron mixed phase in neutron stars

International Nuclear Information System (INIS)

Glendenning, N.K.

1994-01-01

The mixed phase of a substance undergoing a first order phase transition has entirely different behavior according as the substance has more than one conserved charge or only one, as in the text book examples. In the latter case the pressure and nature of the phases are constants throughout the coexistence phase. For systems with more than one conserved charge (or independent component) we prove two theorems: (1) The pressure and the nature of the phases in equilibrium change continuously as the proportion of the phases varies from one pure phase to the other. (2) If one of the conserved charges is the Coulomb force, an intermediate-range order will be created by the competition between Coulomb and surface interface energy. Their sum is minimized when the coexistence phase assumes a Coulomb lattice of one phase immersed in the other. The geometry will vary continuously as the proportion of phases. We illustrate the theorems for a simple description of the hadron to quark phase transition in neutron stars and find a crystalline phase many kilometers thick. However the theorems are general and pertain to chemical mixtures, nuclear systems, either static as in stars or dynamic as in collisions, and have possible application to phase transitions in the early universe

Benchmarking of 3D space charge codes using direct phase space measurements from photoemission high voltage dc gun

Directory of Open Access Journals (Sweden)

Ivan V. Bazarov

2008-10-01

Full Text Available We present a comparison between space charge calculations and direct measurements of the transverse phase space of space charge dominated electron bunches from a high voltage dc photoemission gun followed by an emittance compensation solenoid magnet. The measurements were performed using a double-slit emittance measurement system over a range of bunch charge and solenoid current values. The data are compared with detailed simulations using the 3D space charge codes GPT and Parmela3D. The initial particle distributions were generated from measured transverse and temporal laser beam profiles at the photocathode. The beam brightness as a function of beam fraction is calculated for the measured phase space maps and found to approach within a factor of 2 the theoretical maximum set by the thermal energy and the accelerating field at the photocathode.

Doping Induced Transition from an Antiferro-Type Order to Phase Separation

International Nuclear Information System (INIS)

Lemanski, R.; Gajek, Z.

2003-01-01

A sequence of transitions from an antiferro-type order to a phase separate state under doping away from half filling is studied within the 1D Falicov-Kimball model. Using the method of restricted phase diagrams the system is analyzed exactly in the thermodynamic limit. Various kinds of ordering, including periodic n-molecular phases and their mixtures are found for a set of values of the interaction constant U. (author)

Comparisons of Modeling and State of Charge Estimation for Lithium-Ion Battery Based on Fractional Order and Integral Order Methods

Directory of Open Access Journals (Sweden)

Renxin Xiao

2016-03-01

Full Text Available In order to properly manage lithium-ion batteries of electric vehicles (EVs, it is essential to build the battery model and estimate the state of charge (SOC. In this paper, the fractional order forms of Thevenin and partnership for a new generation of vehicles (PNGV models are built, of which the model parameters including the fractional orders and the corresponding resistance and capacitance values are simultaneously identified based on genetic algorithm (GA. The relationships between different model parameters and SOC are established and analyzed. The calculation precisions of the fractional order model (FOM and integral order model (IOM are validated and compared under hybrid test cycles. Finally, extended Kalman filter (EKF is employed to estimate the SOC based on different models. The results prove that the FOMs can simulate the output voltage more accurately and the fractional order EKF (FOEKF can estimate the SOC more precisely under dynamic conditions.

Experiments indicating a second hydrogen ordered phase of ice VI.

Science.gov (United States)

Gasser, Tobias M; Thoeny, Alexander V; Plaga, Lucie J; Köster, Karsten W; Etter, Martin; Böhmer, Roland; Loerting, Thomas

2018-05-14

In the last twelve years five new ice phases were experimentally prepared. Two of them are empty clathrate hydrates and three of them represent hydrogen ordered counterparts of previously known disordered ice phases. Here, we report on hydrogen ordering in ice VI samples produced by cooling at pressures up to 2.00 GPa. Based on results from calorimetry, dielectric relaxation spectroscopy, Raman spectroscopy, and powder X-ray diffraction the existence of a second hydrogen ordered polymorph related to ice VI is suggested. Powder X-ray data show the oxygen network to be the one of ice VI. For the 1.80 GPa sample the activation energy from dielectric spectroscopy is 45 kJ mol -1 , which is much larger than for the known hydrogen ordered proxy of ice VI, ice XV. Raman spectroscopy indicates the 1.80 GPa sample to be more ordered than ice XV. It is further distinct from ice XV in that it experiences hydrogen disordering above ≈103 K which is 26 K below the ice XV to ice VI disordering transition. Consequently, below 103 K it is thermodynamically more stable than ice XV, adding a stability region to the phase diagram of water. For the time being we suggest to call this new phase ice β-XV and to relabel it ice XVIII once its crystal structure is known.

Third-order QCD corrections to the charged-current structure function F3

International Nuclear Information System (INIS)

Moch, S.; Vermaseren, J.A.M.; Vogt, A.

2008-12-01

We compute the coefficient function for the charge-averaged W ± -exchange structure function F 3 in deep-inelastic scattering (DIS) to the third order in massless perturbative QCD. Our new three-loop contribution to this quantity forms, at not too small values of the Bjorken variable x, the dominant part of the next-to-next-to-next-to-leading order corrections. It thus facilitates improved determinations of the strong coupling α s and of 1/Q 2 power corrections from scaling violations measured in neutrino-nucleon DIS. The expansion of F 3 in powers of α s is stable at all values of x relevant to measurements at high scales Q 2 . At small x the third-order coefficient function is dominated by diagrams with the colour structure d abc d abc not present at lower orders. At large x the coefficient function for F 3 is identical to that of F 1 up to terms vanishing for x→1. (orig.)

Generalized second-order Coulomb phase shift functions

International Nuclear Information System (INIS)

Rosendorff, S.

1982-01-01

Some specific properties and the evaluation of the generalized second-order Coulomb phase shift functions (two-dimensional integrals of four spherical cylinder functions) are discussed. The dependence on the three momenta k 1 ,k-bar,k 2 , corresponding to the final, intermediate, and initial states is illustrated

Selective suppression of high-order harmonics within phase-matched spectral regions.

Science.gov (United States)

Lerner, Gavriel; Diskin, Tzvi; Neufeld, Ofer; Kfir, Ofer; Cohen, Oren

2017-04-01

Phase matching in high-harmonic generation leads to enhancement of multiple harmonics. It is sometimes desired to control the spectral structure within the phase-matched spectral region. We propose a scheme for selective suppression of high-order harmonics within the phase-matched spectral region while weakly influencing the other harmonics. The method is based on addition of phase-mismatched segments within a phase-matched medium. We demonstrate the method numerically in two examples. First, we show that one phase-mismatched segment can significantly suppress harmonic orders 9, 15, and 21. Second, we show that two phase-mismatched segments can efficiently suppress circularly polarized harmonics with one helicity over the other when driven by a bi-circular field. The new method may be useful for various applications, including the generation of highly helical bright attosecond pulses.

Magnetocaloric materials and first order phase transitions

DEFF Research Database (Denmark)

Neves Bez, Henrique

and magnetocaloric regenerative tests. The magnetic, thermal and structural properties obtained from such measurements are then evaluated through different models, i.e. the Curie-Weiss law, the Bean-Rodbell model, the free electron model and the Debye model.The measured magnetocaloric properties of La0.67Ca0.33MnO3...... heat capacity, magnetization and entropy change measurements. By measuring bulky particles (with a particle size in the range of 5001000 μm) of La(Fe,Mn,Si)13Hz with first order phase transition, it was possible to observe very sharp transitions. This is not the case for finer ground particles which......This thesis studies the first order phase transitions of the magnetocaloric materials La0.67Ca0.33MnO3 and La(Fe,Mn,Si)13Hz trying to overcome challenges that these materials face when applied in active magnetic regenerators. The study is done through experimental characterization and modelling...

Spatially-resolved studies of charge-density-wave phase slip and dynamics in NbSe3

International Nuclear Information System (INIS)

Lemay, S.G.; Adelman, T.L.; Zaitsev-Zotov, S.V.; Thorne, R.E.

1999-01-01

We review our spatially and temporally resolved studies of charge-density-wave (CDW) phase slip and dynamics in NbSe 3 . Measurements of the steady-state CDW current, phase slip and strain profiles and their transient evolutions in response to a change in current direction provide a detailed picture of the interplay between elastic deformations and plasticity in this material. (orig.)

A Single-Phase Transformerless Inverter With Charge Pump Circuit Concept for Grid-Tied PV Applications

DEFF Research Database (Denmark)

Ardashir, Jaber Fallah; Sabahi, Mehran; Hosseini, Seyed Hossein

2017-01-01

This paper proposes a new single-phase transformerless photovoltaic (PV) inverter for grid-tied PV systems. The topology is derived from the concept of a charge pump circuit in order to eliminate the leakage current. It is composed of four power switches, two diodes, two capacitors, and an LCL...... resonant control strategy is used to control the injected current. The main benefits of the proposed inverter are: the neutral of the grid is directly connected to the negative terminal of the PV panel, so the leakage current is eliminated; its compact size; low cost; the used dc voltage of the proposed...... are presented. Experimental results are presented to confirm both the theoretical analysis and the concept of the proposed inverter. The obtained results clearly validate the performance of the proposed inverter and its practical application in grid-tied PV systems....

Effective interactions between concentration fluctuations and charge transfer in chemically ordering liquid alloys

International Nuclear Information System (INIS)

Akdeniz, Z.; Tosi, M.P.

1992-08-01

The correlations between long-wavelength fluctuations of concentration in a liquid binary alloy are determined by a balance between an elastic strain free energy and an Ornstein-Zernike effective interaction. The latter is extracted from thermodynamic data in the case of the Li-Pb system, which is well known to chemically order with stoichiometric composition corresponding to Li 4 Pb. Strong attractive interactions between concentration fluctuations near the composition of chemical ordering originate from electronic charge transfer, which is estimated from the electron-ion partial structure factors as functions of composition in the liquid alloy. (author). 20 refs, 2 figs

Quasi-phase-matching of only even-order high harmonics.

Science.gov (United States)

Diskin, Tzvi; Cohen, Oren

2014-03-24

High harmonic spectrum of a quasi-monochromatic pump that interacts with isotropic media consists of only odd-order harmonics. Addition of a secondary pump, e.g. a static field or the second harmonic of the primary pump, can results with generation of both odd and even harmonics of the primary pump. We propose a method for quasi-phase matching of only the even-order harmonics of the primary pump. We formulate a theory for this process and demonstrate it numerically. We also show that it leads to attosecond pulse trains with constant carrier envelop phase and high repetition rate.

Magnetic phase transitions with incommensurate structures in systems with coupled order parameters

International Nuclear Information System (INIS)

Izyumov, Yu.A.; Laptev, V.M.; Petrov, S.B.

1984-01-01

Modulated magnetic phases are investigated for the case when symmetry does not allow linear by gradients Lifshits invariants and magnetic momenta are converted by two irreducible representations. Possible phase diagrams with participation of incommensurable phases are plotted on the base of Ginsburg-Landau functional for 2 bound parameters of the order. The role of the highest harmonics in spatial distribution of the order parameters is clarified on the example of magnetic phase transitions in Er

Phase modulation spectroscopy of space-charge wave resonances in Bi12SiO20

DEFF Research Database (Denmark)

Vasnetsov, M.; Buchhave, Preben; Lyuksyutov, S.

1997-01-01

A new experimental method for the study of resonance effects and space-charge wave excitation in photorefractive Bi12SiO20 crystals by using a combination of frequency detuning and phase modulation technique has been developed. The accuracy of the method allows a detection of resonance peaks...... of diffraction efficiency within 0.5 Hz. Numerical simulations of the nonlinear differential equations describing the behaviour of the space-charge waves in photorefractive crystals have been performed and found to be in a good agreement with experiment. We have measured the photocurrent through the crystal...

Superrotation charge and supertranslation hair on black holes

International Nuclear Information System (INIS)

Hawking, Stephen W.; Perry, Malcolm J.; Strominger, Andrew

2017-01-01

It is shown that black hole spacetimes in classical Einstein gravity are characterized by, in addition to their ADM mass M, momentum P-vector , angular momentum J-vector and boost charge K-vector , an infinite head of supertranslation hair. The distinct black holes are distinguished by classical superrotation charges measured at infinity. Solutions with supertranslation hair are diffeomorphic to the Schwarzschild spacetime, but the diffeomorphisms are part of the BMS subgroup and act nontrivially on the physical phase space. It is shown that a black hole can be supertranslated by throwing in an asymmetric shock wave. A leading-order Bondi-gauge expression is derived for the linearized horizon supertranslation charge and shown to generate, via the Dirac bracket, supertranslations on the linearized phase space of gravitational excitations of the horizon. The considerations of this paper are largely classical augmented by comments on their implications for the quantum theory.

Superrotation charge and supertranslation hair on black holes

Energy Technology Data Exchange (ETDEWEB)

Hawking, Stephen W.; Perry, Malcolm J. [DAMTP, Centre for Mathematical Sciences, University of Cambridge,Wilberforce Road, Cambridge (United Kingdom); Strominger, Andrew [Center for the Fundamental Laws of Nature, Harvard University,17 Oxford Street, Cambridge, MA (United States)

2017-05-31

It is shown that black hole spacetimes in classical Einstein gravity are characterized by, in addition to their ADM mass M, momentum P-vector , angular momentum J-vector and boost charge K-vector , an infinite head of supertranslation hair. The distinct black holes are distinguished by classical superrotation charges measured at infinity. Solutions with supertranslation hair are diffeomorphic to the Schwarzschild spacetime, but the diffeomorphisms are part of the BMS subgroup and act nontrivially on the physical phase space. It is shown that a black hole can be supertranslated by throwing in an asymmetric shock wave. A leading-order Bondi-gauge expression is derived for the linearized horizon supertranslation charge and shown to generate, via the Dirac bracket, supertranslations on the linearized phase space of gravitational excitations of the horizon. The considerations of this paper are largely classical augmented by comments on their implications for the quantum theory.

Superrotation charge and supertranslation hair on black holes

Science.gov (United States)

Hawking, Stephen W.; Perry, Malcolm J.; Strominger, Andrew

2017-05-01

It is shown that black hole spacetimes in classical Einstein gravity are characterized by, in addition to their ADM mass M, momentum \\overrightarrow{P} , angular momentum \\overrightarrow{J} and boost charge \\overrightarrow{K} , an infinite head of supertranslation hair. The distinct black holes are distinguished by classical superrotation charges measured at infinity. Solutions with super-translation hair are diffeomorphic to the Schwarzschild spacetime, but the diffeomorphisms are part of the BMS subgroup and act nontrivially on the physical phase space. It is shown that a black hole can be supertranslated by throwing in an asymmetric shock wave. A leading-order Bondi-gauge expression is derived for the linearized horizon supertranslation charge and shown to generate, via the Dirac bracket, supertranslations on the linearized phase space of gravitational excitations of the horizon. The considerations of this paper are largely classical augmented by comments on their implications for the quantum theory.

First-order phase transition in the quantum spin glass at T=0

Energy Technology Data Exchange (ETDEWEB)

Viana, J. Roberto; Nogueira, Yamilles; Sousa, J. Ricardo de

2003-05-26

The van Hemmen model with transverse and random longitudinal field is studied to analyze the tricritical behavior in the quantum Ising spin glass at T=0. The free energy and order parameter are calculated for two types of probability distributions: Gaussian and bimodal. We obtain the phase diagram in the {omega}-H plane, where {omega} and H are the transverse and random longitudinal fields, respectively. For the case of Gaussian distribution the phase transition is of second order, while the bimodal distribution we observe second-order transition for high-transverse field and first-order transition for small transverse field, with a tricritical point in the phase diagram.

First-order phase transition in the quantum spin glass at T=0

International Nuclear Information System (INIS)

Viana, J. Roberto; Nogueira, Yamilles; Sousa, J. Ricardo de

2003-01-01

The van Hemmen model with transverse and random longitudinal field is studied to analyze the tricritical behavior in the quantum Ising spin glass at T=0. The free energy and order parameter are calculated for two types of probability distributions: Gaussian and bimodal. We obtain the phase diagram in the Ω-H plane, where Ω and H are the transverse and random longitudinal fields, respectively. For the case of Gaussian distribution the phase transition is of second order, while the bimodal distribution we observe second-order transition for high-transverse field and first-order transition for small transverse field, with a tricritical point in the phase diagram

Optical method for mapping the transverse phase space of a charged particle beam

International Nuclear Information System (INIS)

Fiorito, R.B.; Shkvarunets, A.G.; O'Shea, P.G.

2002-01-01

We are developing an all optical method to map the transverse phase space map of a charged particle beam. Our technique employs OTR interferometry (OTRI) in combination with a scanning pinhole to make local orthogonal (x,y) divergence and trajectory angle measurements as function of position within the transverse profile of the beam. The localized data allows a reconstruction of the horizontal and vertical phase spaces of the beam. We have also demonstrated how single and multiple pinholes can in principle be used to make such measurements simultaneously

R-charge Conservation and More in Factorizable and Non-Factorizable Orbifolds

CERN Document Server

Bizet, Nana Geraldine Cabo; Pena, Damian Kaloni Mayorga; Parameswaran, Susha L; Schmitz, Matthias; Zavala, Ivonne

2013-01-01

We consider the string theory origin of R-charge conservation laws in heterotic orbifold compactifications, deriving the corresponding string coupling selection rule for factorizable and non-factorizable orbifolds, with prime ordered and non-prime ordered point groups. R-charge conservation arises due to symmetries among the worldsheet instantons that can mediate the couplings. Among our results is a previously missed non-trivial contribution to the conserved R-charges from the Gamma-phases in non-prime orbifolds, which weakens the R-charge selection rule. Symmetries among the worldsheet instantons can also lead to additional selection rules for some couplings. We make a similar analysis for Rule 4 or the 'torus lattice selection rule'. Moreover, we identify a new string selection rule, that we call Rule 6 or the 'coset vector selection rule'.

Charged dilatonic black holes in gravity's rainbow

Energy Technology Data Exchange (ETDEWEB)

Hendi, S.H. [Shiraz University, Physics Department and Biruni Observatory, College of Sciences, Shiraz (Iran, Islamic Republic of); Research Institute for Astronomy and Astrophysics of Maragha (RIAAM), Maragha (Iran, Islamic Republic of); Faizal, Mir [University of Waterloo, Department of Physics and Astronomy, Waterloo, ON (Canada); Panah, B.E. [Shiraz University, Physics Department and Biruni Observatory, College of Sciences, Shiraz (Iran, Islamic Republic of); Panahiyan, S. [Shiraz University, Physics Department and Biruni Observatory, College of Sciences, Shiraz (Iran, Islamic Republic of); Shahid Beheshti University, Physics Department, Tehran (Iran, Islamic Republic of)

2016-05-15

In this paper, we present charged dilatonic black holes in gravity's rainbow. We study the geometric and thermodynamic properties of black hole solutions. We also investigate the effects of rainbow functions on different thermodynamic quantities for these charged black holes in dilatonic gravity's rainbow. Then we demonstrate that the first law of thermodynamics is valid for these solutions. After that, we investigate thermal stability of the solutions using the canonical ensemble and analyze the effects of different rainbow functions on the thermal stability. In addition, we present some arguments regarding the bound and phase transition points in context of geometrical thermodynamics. We also study the phase transition in extended phase space in which the cosmological constant is treated as the thermodynamic pressure. Finally, we use another approach to calculate and demonstrate that the obtained critical points in extended phase space represent a second order phase transition for these black holes. (orig.)

Issues concerning gravity waves from first-order phase transitions

International Nuclear Information System (INIS)

Kosowsky, A.

1993-01-01

The stochastic background of gravitational radiation is a unique and potentially valuable source of information about the early universe. Photons thermally decoupled when the universe was around 100,000 years old; electromagnetic radiation cannot directly provide information about the epoch earlier than this. In contrast, gravitons presumably decoupled around the Planck time, when the universe was only 10 -44 seconds old. Since gravity wave propagate virtually unimpeded, any energetic event in the evolution of the universe will leave an imprint on the gravity wave background. Turner and Wilczek first suggested that first-order phase transitions, and particularly transitions which occur via the nucleation, expansion, and percolation of vacuum bubbles, will be a particularly efficient source of gravitational radiation. Detailed calculations with scalar-field vacuum bubbles confirm this conjecture and show that strongly first-order phase transitions are probably the strongest stochastic gravity-wave source yet conjectured. In this work the author first reviews the vacuum bubble calculations, stressing their physical assumptions. The author then discusses realistic scenarios for first-order phase transitions and describes how the calculations must be modified and extended to produce reliable results. 11 refs

Oligosaccharides and glycolipids addition in charged lamellar phases

International Nuclear Information System (INIS)

Ricoul, F.

1997-01-01

The aim of this work is to study the addition of oligosaccharides and glycolipids in lamellar phases of the cationic surfactant DDAB (di-dodecyl-dimethyl-ammonium bromide). Two steps have been followed: the determination of phases prisms and the thermodynamic interpretation in terms of molecular interactions. In order to characterize these systems, two new experimental small angle scattering methods have been perfected: 1) a neutron scattering contrast variation method which allows to study the adsorption of aqueous solution in bilayers and 2) a capillary concentration gradient method to establish directly and quantitatively the phases diagrams of ternary systems by X rays scattering. It has been pointed out that the oligosaccharides induce a depletion attractive force on the lamellar-lamellar equilibrium of the DDAB when they are excluded of the most concentrated phase. For the two studied glycolipids: 2-O lauroyl-saccharose and N-lauroyl N-nonyl lactitol, the ternary phase diagrams water-DDAB-glycolipid have been established in terms of temperature. Critical points at ambient temperature have been given. The osmotic pressure in concentrated lamellar phases has been measured. It has been shown that glycolipids increase the hydration repulsion at short distance and that the electrostatic repulsion is outstanding and unchanged at high distance if there is at less 1 mole percent of ionic surfactant. In a dilute solution, glycolipids decrease the maximum swelling of lamellar phases, with a competition between the lamellar phase and the micellae dilute phase for water. (O.M.)

Scaling behavior in first-order quark-hadron phase transition

International Nuclear Information System (INIS)

Hwa, R.C.

1994-01-01

It is shown that in the Ginzburg-Landau description of first-order quark-hadron phase transition the normalized factorial moments exhibit scaling behavior. The scaling exponent ν depends on only one effective parameter g, which characterizes the strength of the transition. For a strong first-order transition, we find ν=1.45. For weak transition it is 1.30 in agreement with the earlier result on second-order transition

Phase coexistence and pinning of charge density waves by interfaces in chromium

Science.gov (United States)

Singer, A.; Patel, S. K. K.; Uhlíř, V.; Kukreja, R.; Ulvestad, A.; Dufresne, E. M.; Sandy, A. R.; Fullerton, E. E.; Shpyrko, O. G.

2016-11-01

We study the temperature dependence of the charge density wave (CDW) in a chromium thin film using x-ray diffraction. We exploit the interference between the CDW satellite peaks and Laue oscillations to determine the amplitude, the phase, and the period of the CDW. We find discrete half-integer periods of CDW in the film and switching of the number of periods by one upon cooling/heating with a thermal hysteresis of 20 K. The transition between different CDW periods occurs over a temperature range of 30 K, slightly larger than the width of the thermal hysteresis. A comparison with simulations shows that the phase transition occurs as a variation of the volume fraction of two distinct phases with well-defined periodicities. The phase of the CDW is constant for all temperatures, and we attribute it to strong pinning of the CDW by the mismatch-induced strain at the film-substrate interface.

Annealed Scaling for a Charged Polymer

International Nuclear Information System (INIS)

Caravenna, F.; Hollander, F. den; Pétrélis, N.; Poisat, J.

2016-01-01

This paper studies an undirected polymer chain living on the one-dimensional integer lattice and carrying i.i.d. random charges. Each self-intersection of the polymer chain contributes to the interaction Hamiltonian an energy that is equal to the product of the charges of the two monomers that meet. The joint probability distribution for the polymer chain and the charges is given by the Gibbs distribution associated with the interaction Hamiltonian. The focus is on the annealed free energy per monomer in the limit as the length of the polymer chain tends to infinity. We derive a spectral representation for the free energy and use this to prove that there is a critical curve in the parameter plane of charge bias versus inverse temperature separating a ballistic phase from a subballistic phase. We show that the phase transition is first order. We prove large deviation principles for the laws of the empirical speed and the empirical charge, and derive a spectral representation for the associated rate functions. Interestingly, in both phases both rate functions exhibit flat pieces, which correspond to an inhomogeneous strategy for the polymer to realise a large deviation. The large deviation principles in turn lead to laws of large numbers and central limit theorems. We identify the scaling behaviour of the critical curve for small and for large charge bias. In addition, we identify the scaling behaviour of the free energy for small charge bias and small inverse temperature. Both are linked to an associated Sturm-Liouville eigenvalue problem. A key tool in our analysis is the Ray-Knight formula for the local times of the one-dimensional simple random walk. This formula is exploited to derive a closed form expression for the generating function of the annealed partition function, and for several related quantities. This expression in turn serves as the starting point for the derivation of the spectral representation for the free energy, and for the scaling theorems

Annealed Scaling for a Charged Polymer

Energy Technology Data Exchange (ETDEWEB)

Caravenna, F., E-mail: francesco.caravenna@unimib.it [Università degli Studi di Milano-Bicocca, Dipartimento di Matematica e Applicazioni (Italy); Hollander, F. den, E-mail: denholla@math.leidenuniv.nl [Leiden University, Mathematical Institute (Netherlands); Pétrélis, N., E-mail: nicolas.petrelis@univ-nantes.fr [Université de Nantes, Laboratoire de Mathématiques Jean Leray UMR 6629 (France); Poisat, J., E-mail: poisat@ceremade.dauphine.fr [Université Paris-Dauphine, PSL Research University, CEREMADE, UMR 7534 (France)

2016-03-15

This paper studies an undirected polymer chain living on the one-dimensional integer lattice and carrying i.i.d. random charges. Each self-intersection of the polymer chain contributes to the interaction Hamiltonian an energy that is equal to the product of the charges of the two monomers that meet. The joint probability distribution for the polymer chain and the charges is given by the Gibbs distribution associated with the interaction Hamiltonian. The focus is on the annealed free energy per monomer in the limit as the length of the polymer chain tends to infinity. We derive a spectral representation for the free energy and use this to prove that there is a critical curve in the parameter plane of charge bias versus inverse temperature separating a ballistic phase from a subballistic phase. We show that the phase transition is first order. We prove large deviation principles for the laws of the empirical speed and the empirical charge, and derive a spectral representation for the associated rate functions. Interestingly, in both phases both rate functions exhibit flat pieces, which correspond to an inhomogeneous strategy for the polymer to realise a large deviation. The large deviation principles in turn lead to laws of large numbers and central limit theorems. We identify the scaling behaviour of the critical curve for small and for large charge bias. In addition, we identify the scaling behaviour of the free energy for small charge bias and small inverse temperature. Both are linked to an associated Sturm-Liouville eigenvalue problem. A key tool in our analysis is the Ray-Knight formula for the local times of the one-dimensional simple random walk. This formula is exploited to derive a closed form expression for the generating function of the annealed partition function, and for several related quantities. This expression in turn serves as the starting point for the derivation of the spectral representation for the free energy, and for the scaling theorems

Geometric quantum discord and Berry phase between two charge qubits coupled by a quantum transmission line

International Nuclear Information System (INIS)

Zhu Han-Jie; Zhang Guo-Feng

2014-01-01

Geometric quantum discord (GQD) and Berry phase between two charge qubits coupled by a quantum transmission line are investigated. We show how GQDs evolve and investigate their dependencies on the parameters of the system. We also calculate the energy and the Berry phase and compare them with GQD, finding that there are close connections between them. (general)

Superconductivity and Competing Ordered Phase in RuPn (Pn = As, P)

Science.gov (United States)

Hirai, Daigorou; Takayama, Tomohiro; Hashizume, Daisuke; Yamamoto, Ayako; Takagi, Hidenori

2011-03-01

Unconventional superconductivity likely manifests itself when some competing electronic phases are suppressed down to zero temperature such as cuprates and iron-pnictide superconductors. Therefore, the correlated metallic state neighboring a competing electronic ordering can be a promising playground for unconventional superconductivity. Here we report superconductivity emerging adjacent to electronically ordered phases of RuPn (Pn = As, P). We found that RuAs(P) exhibits phase transitions at 240 (265) K, which is discerned as a drop of magnetic susceptibility or a resistivity upturn. Such anomalies can be suppressed by substituting Rh to the Ru site. Accompanied by the disappearance of the electronic order, superconductivity was found to emerge below 1.8 K and 3.8 K for RuAs and RuP, respectively. The superconductivity in Rh substituted RuPn, which neighbors a competing electronic order, might exhibit an exotic pairing state as seen in the unconventional superconductors known to date.

Generation of initial kinetic distributions for simulation of long-pulse charged particle beams with high space-charge intensity

Directory of Open Access Journals (Sweden)

Steven M. Lund

2009-11-01

Full Text Available Self-consistent Vlasov-Poisson simulations of beams with high space-charge intensity often require specification of initial phase-space distributions that reflect properties of a beam that is well adapted to the transport channel—both in terms of low-order rms (envelope properties as well as the higher-order phase-space structure. Here, we first review broad classes of kinetic distributions commonly in use as initial Vlasov distributions in simulations of unbunched or weakly bunched beams with intense space-charge fields including the following: the Kapchinskij-Vladimirskij (KV equilibrium, continuous-focusing equilibria with specific detailed examples, and various nonequilibrium distributions, such as the semi-Gaussian distribution and distributions formed from specified functions of linear-field Courant-Snyder invariants. Important practical details necessary to specify these distributions in terms of standard accelerator inputs are presented in a unified format. Building on this presentation, a new class of approximate initial kinetic distributions are constructed using transformations that preserve linear focusing, single-particle Courant-Snyder invariants to map initial continuous-focusing equilibrium distributions to a form more appropriate for noncontinuous focusing channels. Self-consistent particle-in-cell simulations are employed to show that the approximate initial distributions generated in this manner are better adapted to the focusing channels for beams with high space-charge intensity. This improved capability enables simulations that more precisely probe intrinsic stability properties and machine performance.

Effect of positively charged short peptides on stability of cubic phases of monoolein/dioleoylphosphatidic acid mixtures.

Science.gov (United States)

Masum, Shah Md; Li, Shu Jie; Awad, Tarek S; Yamazaki, Masahito

2005-06-07

To elucidate the stability and phase transition of cubic phases of biomembranes with infinite periodic minimal surface is indispensable from biological and physicochemical aspects. In this report, we investigated the effect of positively charged peptide-3K (LLKKK) and poly(L-lysine) on the phase stability of monoolein (MO) membranes containing negatively charged dioleoylphosphatidic acid (DOPA) (i.e., DOPA/MO membranes) using small-angle X-ray scattering. At first, the effect of peptide-3K on 10% DOPA/90% MO membrane in excess water, which is in the Q229 phase, was investigated. At 3.4 mM peptide-3K, a Q229 to Q230 phase transition occurred, and at >3.4 mM peptide-3K, the membrane was in the Q230 phase. Poly(L-lysine) (M(w) 1K-4K) also induced the Q230 phase, but peptide-2K (LLKK) could not induce it in the same membrane. We also investigated the effect of peptide-3K on the multilamellar vesicle (MLV) of 25% DOPA/75% MO membrane, which is in L(alpha) phase. In the absence of peptide, the spacing of MLV was very large (11.3 nm), but at > or = 8 mM peptide-3K, it greatly decreased to a constant value (5.2 nm), irrespective of the peptide concentration, indicating that peptide-3K and the membranes form an electrostatically stabilized aggregation with low water content. Poly(L-lysine) also decreased greatly the spacing of the 25% DOPA/75% MO MLV, indicating the formation of a similar aggregation. To compare the effects of peptide-3K and poly(L-lysine) with that of osmotic stress on stability of the cubic phase, we investigated the effect of poly(ethylene glycol) with molecular weight 7500 (PEG-6K) on the phase stability of 10% DOPA/90% MO membrane. With an increase in PEG-6K concentration, i.e., with an increase in osmotic stress, the most stable phase changed as follows; Q229 (Schwartz's P surface) --> Q224 (D) --> Q230 (G). On the basis of these results, we discuss the mechanism of the effects of the positively charged short peptides (peptide-3K) and poly

The Phase Transition of Higher Dimensional Charged Black Holes

International Nuclear Information System (INIS)

Li, Huaifan; Zhao, Ren; Zhang, Lichun; Guo, Xiongying

2016-01-01

We have studied phase transitions of higher dimensional charge black hole with spherical symmetry. We calculated the local energy and local temperature and find that these state parameters satisfy the first law of thermodynamics. We analyze the critical behavior of black hole thermodynamic system by taking state parameters (Q,Φ) of black hole thermodynamic system, in accordance with considering the state parameters (P,V) of van der Waals system, respectively. We obtain the critical point of black hole thermodynamic system and find that the critical point is independent of the dual independent variables we selected. This result for asymptotically flat space is consistent with that for AdS spacetime and is intrinsic property of black hole thermodynamic system.

Colossal thermoelectric power in charge ordered lanthanum calcium manganites (La{sub 0.5}Ca{sub 0.5}MnO{sub 3})

Energy Technology Data Exchange (ETDEWEB)

Joy, Lija K.; Anantharaman, M. R., E-mail: mraiyer@yahoo.com [Department of Physics, Cochin University of Science and Technology, Cochin 682022 (India); Shanmukharao Samatham, S.; Ganesan, V. [Low temperature division, UGC-DAE Consortium for Scientific Research, Indore (India); Thomas, Senoy [Material Science and Technology Division, National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram–695019 (India); Al-Harthi, Salim [Department of Physics, Sultan Qaboos University, Muscat PC 123, Sultanate of Oman (Oman); Liebig, A.; Albrecht, M. [Institute of Physics, University of Augsburg, Augsburg 86135 (Germany)

2014-12-07

Lanthanum calcium manganites (La{sub 0.5}Ca{sub 0.5}MnO{sub 3}) with a composition close to charge ordering, synthesized by high energy ball milling, was found to exhibit colossal thermoelectric power. Thermoelectric power (TEP) data was systematically analyzed by dividing the entire temperature range (5 K–300 K) into three different regimes to explore different scattering mechanisms involved. Mandal's model has been applied to explain TEP data in the region below the Curie temperature (T{sub C}). It has been found that the variation of thermoelectric power with temperature is pronounced when the system enters the charge ordered region at T < 200 K. For temperatures lower than 120 K, due to the co-existence of charge ordered state with a spin-glass state, the variation of thermoelectric power is maximum and exhibited a peak value of −80 mV/K at 58 K. This has been explained by incorporating Kondo properties of the spin-glass along with magnon scattering. FC-ZFC magnetization measurements indicate the existence of a glassy state in the region corresponding to a maximum value of thermoelectric power. Phonon drag contribution instead of spin-glass contribution is taken into account to explain TEP in the region 120 K < T < T{sub C}. Mott's polaronic contribution of charge carriers are considered to interpret TEP in the high temperature region (T > T{sub C}). The optimal Mn{sup 4+}-Mn{sup 3+} concentration in charge ordered La{sub 0.5}Ca{sub 0.5}MnO{sub 3} was examined by X-ray Photoelectron Spectroscopy analysis which confirms the charge ordered nature of this compound.

Design study of beam position monitors for measuring second-order moments of charged particle beams

Science.gov (United States)

Yanagida, Kenichi; Suzuki, Shinsuke; Hanaki, Hirofumi

2012-01-01

This paper presents a theoretical investigation on the multipole moments of charged particle beams in two-dimensional polar coordinates. The theoretical description of multipole moments is based on a single-particle system that is expanded to a multiparticle system by superposition, i.e., summing over all single-particle results. This paper also presents an analysis and design method for a beam position monitor (BPM) that detects higher-order (multipole) moments of a charged particle beam. To calculate the electric fields, a numerical analysis based on the finite difference method was created and carried out. Validity of the numerical analysis was proven by comparing the numerical with the analytical results for a BPM with circular cross section. Six-electrode BPMs with circular and elliptical cross sections were designed for the SPring-8 linac. The results of the numerical calculations show that the second-order moment can be detected for beam sizes ≧420μm (circular) and ≧550μm (elliptical).

Higher-order spin and charge dynamics in a quantum dot-lead hybrid system.

Science.gov (United States)

Otsuka, Tomohiro; Nakajima, Takashi; Delbecq, Matthieu R; Amaha, Shinichi; Yoneda, Jun; Takeda, Kenta; Allison, Giles; Stano, Peter; Noiri, Akito; Ito, Takumi; Loss, Daniel; Ludwig, Arne; Wieck, Andreas D; Tarucha, Seigo

2017-09-22

Understanding the dynamics of open quantum systems is important and challenging in basic physics and applications for quantum devices and quantum computing. Semiconductor quantum dots offer a good platform to explore the physics of open quantum systems because we can tune parameters including the coupling to the environment or leads. Here, we apply the fast single-shot measurement techniques from spin qubit experiments to explore the spin and charge dynamics due to tunnel coupling to a lead in a quantum dot-lead hybrid system. We experimentally observe both spin and charge time evolution via first- and second-order tunneling processes, and reveal the dynamics of the spin-flip through the intermediate state. These results enable and stimulate the exploration of spin dynamics in dot-lead hybrid systems, and may offer useful resources for spin manipulation and simulation of open quantum systems.

Darwin-Lagrangian analysis for the interaction of a point charge and a magnet: considerations related to the controversy regarding the Aharonov-Bohm and Aharonov-Casher phase shifts

International Nuclear Information System (INIS)

Boyer, Timothy H

2006-01-01

The classical electromagnetic interaction of a point charge and a magnet is discussed by first calculating the interaction of a point charge with a simple model magnetic moment and then suggesting a multiparticle limit. The Darwin-Lagrangian is used to analyse the electromagnetic behaviour of the model magnetic moment (composed of two oppositely charged particles of different masses in an initially circular Coulomb orbit) interacting with a passing point charge. Considerations of force, energy, momentum and centre of energy are treated through second order in 1/c. The changing magnetic moment is found to put a force back on a passing charge; this force is of order 1/c 2 and depends upon the magnitude of the magnetic moment. The limit of a many-particle magnet arranged as a toroid is discussed. It is suggested that in the multiparticle limit, the electric fields of the passing charge are screened out of the body of the magnet while the magnetic fields of the passing charge penetrate into the body of the magnet. This is consistent with our understanding of the penetration of electromagnetic velocity fields into ohmic conductors. The proposed multiparticle limit is consistent with the conservation laws for energy and momentum, as well as constant motion of the centre of energy, and Newton's third law for the net Lorentz forces on the magnet and on the point charge. The work corresponds to a classical electromagnetic analysis of the interaction which is basic to understanding the controversy over the Aharonov-Bohm and Aharonov-Casher phase shifts and represents a refutation of the suggestions of Aharonov, Pearle and Vaidman

High-charge and multiple-star vortex coronagraphy from stacked vector vortex phase masks.

Science.gov (United States)

Aleksanyan, Artur; Brasselet, Etienne

2018-02-01

Optical vortex phase masks are now installed at many ground-based large telescopes for high-contrast astronomical imaging. To date, such instrumental advances have been restricted to the use of helical phase masks of the lowest even order, while future giant telescopes will require high-order masks. Here we propose a single-stage on-axis scheme to create high-order vortex coronagraphs based on second-order vortex phase masks. By extending our approach to an off-axis design, we also explore the implementation of multiple-star vortex coronagraphy. An experimental laboratory demonstration is reported and supported by numerical simulations. These results offer a practical roadmap to the development of future coronagraphic tools with enhanced performances.

Modulated phase matching and high-order harmonic enhancement mediated by the carrier-envelope phase

International Nuclear Information System (INIS)

Faccio, Daniele; Serrat, Carles; Cela, Jose M.; Farres, Albert; Di Trapani, Paolo; Biegert, Jens

2010-01-01

The process of high-order harmonic generation in gases is numerically investigated in the presence of a few-cycle pulsed-Bessel-beam pump, featuring a periodic modulation in the peak intensity due to large carrier-envelope-phase mismatch. A two-decade enhancement in the conversion efficiency is observed and interpreted as the consequence of a mechanism known as a nonlinearly induced modulation in the phase mismatch.

Effects of HVEM irradiation on ordered phases in Ni-Ti

International Nuclear Information System (INIS)

Pelton, A.R.

1983-01-01

Various ordered phases in the Ni-Ti system were subjected to electron irradiation in the Berkeley HVEM. Austenitic NiTi (B2 structure) disorders and turns amorphous with room-temperature irradiations at accelerating potentials between 1 and 1.5 MeV. Total doses for the onset of amorphiticity range between 0.7 x 10 22 and 3 x 10 22 e.cm -2 (0.4 to 1.0dpa). At 90K the dose requirement decreases to 4 x 10 20 e.cm -2 (approx. 10 -2 dpa). Martensitic NiTi (distorted monoclinic structure) readily detwins and transforms to austenite when irradiated for short times (approx. 10 seconds). Vapor-deposited amorphous films were crystallized to produce NiTi, Phase X (ordered nickel-rich phase with unknown structure) and Ni 3 Ti (DO 24 structure). Upon electron irradiation, NiTi and Phase X disorder and become amorphous, while Ni 3 Ti disorders but does not turn amorphous with doses up to 4 x 10 22 e.cm -2 at 90K. These results are discussed in terms of the requirement of a critical concentration of defects and their relative mobilities. Brimhall's solubility criteria for amorphization of ordered alloys by ion bombardment is apparantly applicable to electron-induced crystalline to amorphous transitions in this alloy

Short range order and phase separation in Ti-rich Ti-Al alloys

International Nuclear Information System (INIS)

Liew, H.J.

1999-01-01

Many metals and alloys are used in service under conditions in which they are metastable or unstable with respect to phase separation or transformation. Analytical and numerical models exist for relatively simple decomposition processes, such as nucleation and growth mechanisms and spinodal decomposition. In reality, however, more complex phase transformations may occur which are less well understood. For example, reactions involving coupled ordering and phase separation, such as the 'conditional spinodal mechanism', have been predicted. A 'conditional spinodal' is defined as a reaction in which compositional phase separation is thermodynamically possible only after a prior process, such as ordering at the parent composition. There is some debate regarding which real alloy systems exhibit such complex behaviour. Previous atom probe field ion microscopy work on titanium-rich titanium-aluminium based alloys has led to the suggestion that formation of the α 2 phase in this system may occur by a complex phase separation process. As well as being of interest from the point of view of fundamental materials science, this has potential engineering significance as the Ti-Al system forms the basis of the current generation of high-temperature Ti-based alloys for compressor applications in jet engines. This thesis describes an investigation into the phase decomposition process taking place in a titanium-rich Ti-Al alloy lying in the two-phase α+α 2 region. Experimentally, a binary alloy containing 15at% aluminium was heat-treated and examined using electron microscopy, X-ray diffraction, atom probe field ion microscopy and mechanical testing methods. Neutron diffraction experiments were also completed on this system for the first time. In addition, fully three-dimensional atomistic simulations were conducted using a Monte Carlo computer model based on first principles thermodynamic stability calculations of the Ti-Al system. The results provide an insight into many aspects

Gravitational waves from the sound of a first order phase transition.

Science.gov (United States)

Hindmarsh, Mark; Huber, Stephan J; Rummukainen, Kari; Weir, David J

2014-01-31

We report on the first three-dimensional numerical simulations of first-order phase transitions in the early Universe to include the cosmic fluid as well as the scalar field order parameter. We calculate the gravitational wave (GW) spectrum resulting from the nucleation, expansion, and collision of bubbles of the low-temperature phase, for phase transition strengths and bubble wall velocities covering many cases of interest. We find that the compression waves in the fluid continue to be a source of GWs long after the bubbles have merged, a new effect not taken properly into account in previous modeling of the GW source. For a wide range of models, the main source of the GWs produced by a phase transition is, therefore, the sound the bubbles make.

Bubble nucleation in first-order inflation and other cosmological phase transitions

International Nuclear Information System (INIS)

Turner, M.S.; Weinberg, E.J.; Widrow, L.M.

1992-01-01

We address in some detail the kinematics of bubble nucleation and percolation in first-order cosmological phase transitions, with the primary focus on first-order inflation. We study how a first-order phase transition completes, describe measures of its progress, and compute the distribution of bubble sizes. For example, we find that the typical bubble size in a successful transition is of order 1% to 100% of the Hubble radius, and depends very weakly on the energy scale of the transition. We derive very general conditions that must be satisfied by Γ/H 4 to complete the phase transition (Γ=bubble nucleation rate per unit volume; H=expansion rate; physically, Γ/H 4 corresponds to the volume fraction of space occupied by bubbles nucleated over a Hubble time). In particular, Γ/H 4 must exceed 9/4π to successfully end inflation. To avoid the deleterious effects of bubbles nucleated early during inflation on primordial nucleosynthesis and on the isotropy and spectrum of the cosmic microwave background radiation, during most of inflation Γ/H 4 must be less than order 10 -4 --10 -3 . Our constraints imply that in a successful model of first-order inflation the phase transition must complete over a period of at most a few Hubble times and all but preclude individual bubbles from providing an interesting source of density perturbation. We note, though, that it is just possible for Poisson fluctuations in the number of moderately large-size bubbles to lead to interesting isocurvature perturbations, whose spectrum is not scale invariant. Finally, we analyze in detail several recently proposed models of first-order inflation

Phase behavior of mixtures of oppositely charged nanoparticles: Heterogeneous Poisson-Boltzmann cell model applied to lysozyme and succinylated lysozyme

NARCIS (Netherlands)

Biesheuvel, P.M.; Lindhoud, S.; Vries, de R.J.; Stuart, M.A.C.

2006-01-01

We study the phase behavior of mixtures of oppositely charged nanoparticles, both theoretically and experimentally. As an experimental model system we consider mixtures of lysozyme and lysozyme that has been chemically modified in such a way that its charge is nearly equal in magnitude but opposite

Molecular dynamics simulation of the rotational order-disorder phase transition in calcite

International Nuclear Information System (INIS)

Kawano, Jun; Miyake, Akira; Shimobayashi, Norimasa; Kitamura, Masao

2009-01-01

Molecular dynamics (MD) simulation of calcite was carried out with the interatomic potential model based on ab initio calculations to elucidate the phase relations for calcite polymorphs and the mechanism of the rotational order-disorder transition of calcite at high temperature at the atomic scale. From runs of MD calculations with increasing temperature within a pressure range of 1 atm and 2 GPa, the transition of calcite with R3-barc symmetry into a high-temperature phase with R3-barm symmetry was reproduced. In the high-temperature R3-barm phase, CO 3 groups vibrate with large amplitudes either around the original positions in the R3-barc structure or around other positions rotated ± 60 deg., and their positions change continuously with time. Moreover, contrary to the suggestion of previous investigators, the motion of CO 3 groups is not two-dimensional. At 1 atm, the transition between R3-barc and R3-barm is first order in character. Upon increasing temperature at high pressure, however, first a first-order isosymmetric phase transition between the R3-barc phases occurs, which corresponds to the start of ± 120 deg. flipping of CO 3 groups. Then, at higher temperatures, the transition of R3-barc to R3-barm phases happens, which can be considered second order. This set of two types of transitions at elevated pressure can be characterized by the appearance of an 'intermediate' R3-barc phase between the stable region of calcite and the high-temperature R3-barm phase, which may correspond to the CaCO 3 -IV phase.

First-Order Quantum Phase Transition for Dicke Model Induced by Atom-Atom Interaction

International Nuclear Information System (INIS)

Zhao Xiu-Qin; Liu Ni; Liang Jiu-Qing

2017-01-01

In this article, we use the spin coherent state transformation and the ground state variational method to theoretically calculate the ground function. In order to consider the influence of the atom-atom interaction on the extended Dicke model’s ground state properties, the mean photon number, the scaled atomic population and the average ground energy are displayed. Using the self-consistent field theory to solve the atom-atom interaction, we discover the system undergoes a first-order quantum phase transition from the normal phase to the superradiant phase, but a famous Dicke-type second-order quantum phase transition without the atom-atom interaction. Meanwhile, the atom-atom interaction makes the phase transition point shift to the lower atom-photon collective coupling strength. (paper)

Static phenomena at the charged surface of liquid hydrogen

International Nuclear Information System (INIS)

Levchenko, A.A.; Kolmakov, G.V.; Mezhov-Deglin, L.P.; Mikhjlov, M.G.; Trusov, A.B.

1999-01-01

The shape evolution of the equipotentially charged surface of liquid hydrogen layer covering the lower plate of a horizontally arranged diode in external electric fields has been studied experimentally for the first time. A reconstruction phenomenon (the formation of a stationary hump) at the flat charged surface at voltages higher than a certain critical U c1 was observed under the conditions of total compensation of the electric field in the bulk liquid by a surface charge. It is shown that the transition of the flat charged surface into the reconstructed state is a phase transition closed to the second order phase transition. The height of the hump increased with increasing the voltage and at U c2 > 1,2 U c1 the reconstructed surface lost the stability, and a stream discharge pulse was observed. The shape evolution of a changed droplet of constant volume suspended at the upper plate of the diode when the stretching electric field and gravity forces act in the same direction was studied as the voltage was increased up to the discharge

A general relationship between disorder, aggregation and charge transport in conjugated polymers

KAUST Repository

Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen; Koch, Felix P. V.; Stingelin, Natalie; Smith, Paul; Toney, Michael F.; Salleo, Alberto

2013-01-01

Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials. © 2013 Macmillan Publishers Limited. All rights reserved.

A general relationship between disorder, aggregation and charge transport in conjugated polymers

KAUST Repository

Noriega, Rodrigo

2013-08-04

Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials. © 2013 Macmillan Publishers Limited. All rights reserved.

Influence of strontium on the cubic to ordered hexagonal phase

Indian Academy of Sciences (India)

... Refresher Courses · Symposia · Live Streaming. Home; Journals; Bulletin of Materials Science; Volume 23; Issue 6. Influence of strontium on the cubic to ordered hexagonal phase transformation in barium magnesium niobate. M Thirumal A K Ganguli. Phase Transitions Volume 23 Issue 6 December 2000 pp 495-498 ...

CP violation and strong phases from penguins in B±→VV decays

International Nuclear Information System (INIS)

Kramer, G.

1993-12-01

We calculate direct CP-violating observables in charged B → VV decays arising from the interference of amplitudes with different strong and CKM phases. The perturbative strong phases develop at order α s from absorptive parts of one-loop matrix elements of the next-to-leading logarithm corrected effective Hamiltonian. CPT constraints are maintained. Based on this model, we find that partial rate asymmetries between charge conjugate B ± decays can be as high as 15-30% for certain channels with branching ratios in the 10 -6 range. The small values of the coefficients of angular correlations, which we calculated previously to be of order 10 -2 , are not significantly degraded by the strong phases. The charge asymmetries of rates and angular distributions would provide unambiguous evidence for direct CP violation. (orig.)

Distinct charge orders in the planes and chains of ortho-III-ordered YBa2Cu3O(6+δ) superconductors identified by resonant elastic x-ray scattering.

Science.gov (United States)

Achkar, A J; Sutarto, R; Mao, X; He, F; Frano, A; Blanco-Canosa, S; Le Tacon, M; Ghiringhelli, G; Braicovich, L; Minola, M; Sala, M Moretti; Mazzoli, C; Liang, Ruixing; Bonn, D A; Hardy, W N; Keimer, B; Sawatzky, G A; Hawthorn, D G

2012-10-19

Recently, charge density wave (CDW) order in the CuO(2) planes of underdoped YBa(2)Cu(3)O(6+δ) was detected using resonant soft x-ray scattering. An important question remains: is the chain layer responsible for this charge ordering? Here, we explore the energy and polarization dependence of the resonant scattering intensity in a detwinned sample of YBa(2)Cu(3)O(6.75) with ortho-III oxygen ordering in the chain layer. We show that the ortho-III CDW order in the chains is distinct from the CDW order in the planes. The ortho-III structure gives rise to a commensurate superlattice reflection at Q=[0.33 0 L] whose energy and polarization dependence agrees with expectations for oxygen ordering and a spatial modulation of the Cu valence in the chains. Incommensurate peaks at [0.30 0 L] and [0 0.30 L] from the CDW order in the planes are shown to be distinct in Q as well as their temperature, energy, and polarization dependence, and are thus unrelated to the structure of the chain layer. Moreover, the energy dependence of the CDW order in the planes is shown to result from a spatial modulation of energies of the Cu 2p to 3d(x(2)-y(2)) transition, similar to stripe-ordered 214 cuprates.

Thermal blurring effects on fluctuations of conserved charges in rapidity space

Energy Technology Data Exchange (ETDEWEB)

Asakawa, M.; Kitazawa, M.; Onishi, Y.; Sakaida, M.

2016-12-15

We argue that the diffusion in the hadron phase and the thermal blurring at thermal freezeout affect observed conserved charge fluctuations considerably in relativistic heavy ion collisions, and show that their effects are of similar order at RHIC and LHC, and thus equally important in understanding experimental data. We also argue that, in order to disentangle them and obtain the initial state charge fluctuations, which we are interested in, it is crucial to measure their dependence on the rapidity window size. In the energy range of the beam energy scan program at RHIC, the diffusion effect would be less important because of the shorter duration of the hadron phase, but the importance of thermal blurring is not reduced. In addition, it is necessary to take account of the complex correspondence between the space-time rapidity and rapidity of observed particles, there.

Anisotropic magnetoresistance across Verwey transition in charge ordered Fe3O4 epitaxial films

KAUST Repository

Liu, Xiang

2017-12-26

The anisotropic magnetoresistance (AMR) near the Verwey temperature (T-V) is investigated in charge ordered Fe3O4 epitaxial films. When the temperature continuously decreases below T-V, the symmetry of AMR in Fe3O4(100) film evolves from twofold to fourfold at a magnetic field of 50 kOe, where the magnetic field is parallel to the film surface, whereas AMR in Fe3O4(111) film maintains twofold symmetry. By analyzing AMR below T-V, it is found that the Verwey transition contains two steps, including a fast charge ordering process and a continuous formation process of trimeron, which is comfirmed by the temperature-dependent Raman spectra. Just below T-V, the twofold AMR in Fe3O4(100) film originates from uniaxial magnetic anisotropy. The fourfold AMR at a lower temperature can be ascribed to the in-plane trimerons. By comparing the AMR in the films with two orientations, it is found that the trimeron shows a smaller resistivity in a parallel magnetic field. The field-dependent AMR results show that the trimeron-sensitive field has a minimum threshold of about 2 kOe.

Influence of Chirality in Ordered Block Copolymer Phases

Science.gov (United States)

Prasad, Ishan; Grason, Gregory

2015-03-01

Block copolymers are known to assemble into rich spectrum of ordered phases, with many complex phases driven by asymmetry in copolymer architecture. Despite decades of study, the influence of intrinsic chirality on equilibrium mesophase assembly of block copolymers is not well understood and largely unexplored. Self-consistent field theory has played a major role in prediction of physical properties of polymeric systems. Only recently, a polar orientational self-consistent field (oSCF) approach was adopted to model chiral BCP having a thermodynamic preference for cholesteric ordering in chiral segments. We implement oSCF theory for chiral nematic copolymers, where segment orientations are characterized by quadrupolar chiral interactions, and focus our study on the thermodynamic stability of bi-continuous network morphologies, and the transfer of molecular chirality to mesoscale chirality of networks. Unique photonic properties observed in butterfly wings have been attributed to presence of chiral single-gyroid networks, this has made it an attractive target for chiral metamaterial design.

Energy Budget of Cosmological First-order Phase Transitions

CERN Document Server

Espinosa, Jose R; No, Jose M; Servant, Geraldine

2010-01-01

The study of the hydrodynamics of bubble growth in first-order phase transitions is very relevant for electroweak baryogenesis, as the baryon asymmetry depends sensitively on the bubble wall velocity, and also for predicting the size of the gravity wave signal resulting from bubble collisions, which depends on both the bubble wall velocity and the plasma fluid velocity. We perform such study in different bubble expansion regimes, namely deflagrations, detonations, hybrids (steady states) and runaway solutions (accelerating wall), without relying on a specific particle physics model. We compute the efficiency of the transfer of vacuum energy to the bubble wall and the plasma in all regimes. We clarify the condition determining the runaway regime and stress that in most models of strong first-order phase transitions this will modify expectations for the gravity wave signal. Indeed, in this case, most of the kinetic energy is concentrated in the wall and almost no turbulent fluid motions are expected since the s...

Minimization of the emittance growth of multi-charge particle beams in the charge stripping section of RAON

Energy Technology Data Exchange (ETDEWEB)

Hwang, Ji-Gwang [Department of Physics, Kyungpook National University, Daegu 702-701 (Korea, Republic of); Kim, Eun-San, E-mail: eskim1@knu.ac.kr [Department of Physics, Kyungpook National University, Daegu 702-701 (Korea, Republic of); Kim, Hye-Jin, E-mail: hjkim87@ibs.re.kr [Rare Isotope Science Project, Institute for Basic Science, Jeonmin-dong, Yuseong-gu, Daejeon (Korea, Republic of); Jeon, Dong-O [Rare Isotope Science Project, Institute for Basic Science, Jeonmin-dong, Yuseong-gu, Daejeon (Korea, Republic of)

2014-12-11

The charge stripping section of the Rare isotope Accelerator Of Newness (RAON), which is one of the critical components to achieve a high power of 400 kW with a short lianc, is a source of transverse emittance growth. The dominant effects are the angular straggling in the charge stripper required to increase the charge state of the beam and chromatic aberrations in the dispersive section required to separate the selected ion beam from the various ion beams produced in the stripper. Since the main source of transverse emittance growth in the stripper is the angular straggling, it can be compensated for by changing the angle of the phase ellipse. Therefore the emittance growth is minimized by optimizing the Twiss parameters at the stripper. The emittance growth in the charge selection section is also minimized by the correction of high-order aberrations using six sextupole magnets. In this paper, we present a method to minimize the transverse emittance growth in the stripper by changing the Twiss parameters and in the charge selection section by using sextupole magnets.

Spectroelectrochemical evidence for the effect of phase structure and interface on charge behavior in poly(3-hexylthiophene): Fullerene active layer

International Nuclear Information System (INIS)

Hu, Rong; Ni, Haitao; Wang, Zhaodong; Liu, Yurong; Liu, Hongdong; Yang, Xin; Cheng, Jiang

2016-01-01

Highlights: • The steady-state absorption spectra of P3HT"·"+, P3HT"·"−, PCBM"+ and PCBM"− were obtained. • The effect of morphology of active layer on charge generation was identified. • Non-equilibrium transport of electron and hole was confirmed in PSCs. - Abstract: To investigate the correlation between morphology of active layer and performance of polymer solar cells (PSCs). Poly(3-hexylthiophene):[6,6]-phenyl-C_6_1-butyric acid methyl ester (P3HT:PCBM) were selected as research object and five PSCs based on active layers with varied morphology were fabricated. The results showed that P3HT crystalline phase and donor-acceptor (D-A) interface had an important influence on PSCs performance, which was revealed by structure characterization and J-V measurement. To further understanding the effect of phase structure and D-A interface on charge behavior. Spectroelectrochemistry measurement (SEC) was performed to characterize the steady-state optical absorption of P3HT, PCBM cation and anion in varied active layers, and the spectra difference of cations and anions was analyzed. The results were found that D-A interface could promote charge generation. P3HT crystalline phase and PCBM aggregation phase were beneficial for improving the charge transport ability. Meanwhile, the non-equilibrium transport of electron and hole in PSCs was corroborated by SEC.

Mechanical model for filament buckling and growth by phase ordering.

Science.gov (United States)

Rey, Alejandro D; Abukhdeir, Nasser M

2008-02-05

A mechanical model of open filament shape and growth driven by phase ordering is formulated. For a given phase-ordering driving force, the model output is the filament shape evolution and the filament end-point kinematics. The linearized model for the slope of the filament is the Cahn-Hilliard model of spinodal decomposition, where the buckling corresponds to concentration fluctuations. Two modes are predicted: (i) sequential growth and buckling and (ii) simultaneous buckling and growth. The relation among the maximum buckling rate, filament tension, and matrix viscosity is given. These results contribute to ongoing work in smectic A filament buckling.

Holographic entanglement entropy and the extended phase structure of STU black holes

International Nuclear Information System (INIS)

Caceres, Elena; Nguyen, Phuc H.; Pedraza, Juan F.

2015-01-01

We study the extended thermodynamics, obtained by considering the cosmological constant as a thermodynamic variable, of STU black holes in 4-dimensions in the fixed charge ensemble. The associated phase structure is conjectured to be dual to an RG-flow on the space of field theories. We find that for some charge configurations the phase structure resembles that of a Van der Waals gas: the system exhibits a family of first order phase transitions ending in a second order phase transition at a critical temperature. We calculate the holographic entanglement entropy for several charge configurations and show that for the cases where the gravity background exhibits Van der Waals behavior, the entanglement entropy presents a transition at the same critical temperature. To further characterize the phase transition we calculate appropriate critical exponents and show that they coincide. Thus, the entanglement entropy successfully captures the information of the extended phase structure. Finally, we discuss the physical interpretation of the extended space in terms of the boundary QFT and construct various holographic heat engines dual to STU black holes.

REVIEWS OF TOPICAL PROBLEMS: Order-disorder transformations and phase equilibria in strongly nonstoichiometric compounds

Science.gov (United States)

Gusev, Aleksandr I.

2000-01-01

Data on order-disorder phase transformations in strongly nonstoichiometric carbides and nitrides MXy (X=C, N) of Group IV and V transition metals at temperatures below 1300-1400 K are reviewed. The order-parameter functional method as applied to atomic and vacancy ordering in strongly nonstoichiometric MXy compounds and to phase equilibrium calculations for M-X systems is discussed. Phase diagram calculations for the Ti-C, Zr-C, Hf-C, V-C, Nb-C, Ta-C, Ti-N, and Ti-B-C systems (with the inclusion of the ordering of nonstoichiometric carbides and nitrides) and those for pseudobinary carbide M(1)C-M(2)C systems are presented. Heat capacity, electrical resistivity and magnetic susceptibility changes at reversible order-disorder phase transformations in nonstoichiometric carbides are considered.

Order-disorder phase transitions in Au-Cu nanocubes: from nano-thermodynamics to synthesis.

Science.gov (United States)

Mendoza-Cruz, R; Bazán-Diaz, L; Velázquez-Salazar, J J; Samaniego-Benitez, J E; Ascencio-Aguirre, F M; Herrera-Becerra, R; José-Yacamán, M; Guisbiers, G

2017-07-13

Catalysts have been widely used in industries and can be optimized by tuning the composition and chemical ordering of the elements involved in the nano-alloy. Among bi-metallic alloys, the Au-Cu system is of particular interest because it exhibits ordered phases at low temperatures. Nevertheless, the temperature at which these ordered structures are formed is totally unknown at the nanoscale. Consequently, to speed up the development of these catalysts, this paper theoretically predicts the structural phase transitions between ordered and disordered phases for the Au-Cu system by using nano-thermodynamics. Following the predictions, the suggested annealing temperatures have been carefully chosen and consequently, Au-Cu ordered nanocubes have been successfully synthesized through a solventless protocol. The results are fully supported by electron microscopy observations.

Numerical simulation of the motion of charged suspended particle in multi-phase flow

Energy Technology Data Exchange (ETDEWEB)

Abd Elkhalek, M M [Nuclear Research Center-Atomic Energy Authority, Cairo (Egypt)

1997-12-31

A method for computing numerical simulation of the motion of charged suspended particle in multi-phase flow between two-long parallel plates is described in detail. The equation of motion of a suspended particle was suggested by closkin. The equations of motion are reduced to ordinary differential equations by similarity transformations and solved numerically by using Runge-Kutta method. The trajectories of particles are calculated by integrating the equation of motion of a single particle. Numerical solutions of the resulting ordinary differential equations provide velocity distributions for both fluid and solid phases and density distributions for the solid. The present simulation requires some empirical parameters concerning the collision of the particles with the wall. Some typical results for both fluid and particle phases and density distributions of the particles are presented graphically. 4 figs.

Numerical Simulation of the Motion of Charged Suspended Particle in Multi-Phase Flow

International Nuclear Information System (INIS)

Abd-El Khalek, M.M.

1998-01-01

A method for computing Numerical simulation of the motion of charged suspended particle in multi-phase flow between two-long parallel plates is described in detail. The equation of motion of a suspended particle was suggested by Closkin. The equations of motion are reduced to ordinary differential equations by similarity transformations and solved numerically by using the Runge-Kutta method. The trajectories of particles are calculated by integrating the equation of motion of a single particle. Numerical solutions of the resulting ordinary differential equations provide velocity distributions for both fluid and solid phases and density distributions for the solid. The present simulation requires some empirical parameters concerning the collision of the particles with the wall. Some typical results for both fluid and particle phases and density distributions of the particles are presented graphically

Charge ordering in reactive sputtered (1 0 0) and (1 1 1) oriented epitaxial Fe3O4 films

KAUST Repository

Mi, Wenbo

2013-06-01

Epitaxial Fe3O4 films with (1 0 0) and (1 1 1) orientations fabricated by reactive sputtering present simultaneous magnetic and electrical transitions at 120 and 124 K, respectively. The symmetry decreases from face-centered cubic to monoclinic structure across the Verwey transition. Extra spots with different brightness at different positions appear in selected-area diffraction patterns at 95 K. The extra spots come from the charge ordering of outer-layer electrons of Fe atoms, and should be related to the charge ordering of octahedral B-site Fe atoms. © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Charge ordering in reactive sputtered (1 0 0) and (1 1 1) oriented epitaxial Fe3O4 films

KAUST Repository

Mi, Wenbo; Guo, Zaibing; Wang, Qingxiao; Yang, Yang; Bai, Haili

2013-01-01

Epitaxial Fe3O4 films with (1 0 0) and (1 1 1) orientations fabricated by reactive sputtering present simultaneous magnetic and electrical transitions at 120 and 124 K, respectively. The symmetry decreases from face-centered cubic to monoclinic structure across the Verwey transition. Extra spots with different brightness at different positions appear in selected-area diffraction patterns at 95 K. The extra spots come from the charge ordering of outer-layer electrons of Fe atoms, and should be related to the charge ordering of octahedral B-site Fe atoms. © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Possible higher order phase transition in large-N gauge theory at finite temperature

Energy Technology Data Exchange (ETDEWEB)

Nishimura, Hiromichi

2017-08-07

We analyze the phase structure of SU(¥) gauge theory at finite temperature using matrix models. Our basic assumption is that the effective potential is dominated by double-trace terms for the Polyakov loops. As a function of the temperature, a background field for the Polyakov loop, and a quartic coupling, it exhibits a universal structure: in the large portion of the parameter space, there is a continuous phase transition analogous to the third-order phase transition of Gross,Witten and Wadia, but the order of phase transition can be higher than third. We show that different confining potentials give rise to drastically different behavior of the eigenvalue density and the free energy. Therefore lattice simulations at large N could probe the order of phase transition and test our results. Critical

Critical phenomena and chemical potential of a charged AdS black hole

Science.gov (United States)

Wei, Shao-Wen; Liang, Bin; Liu, Yu-Xiao

2017-12-01

Inspired by the interpretation of the cosmological constant from the boundary gauge theory, we here treat it as the number of colors N and its conjugate quantity as the associated chemical potential μ in the black hole side. Then the thermodynamics and the chemical potential for a five-dimensional charged AdS black hole are studied. It is found that there exists a small-large black hole phase transition of van der Waals type. The critical phenomena are investigated in the N2-μ chart. The result implies that the phase transition can occur for large number of colors N , while is forbidden for small number. This to some extent implies that the interaction of the system increases with the number. In particular, in the reduced parameter space, all the thermodynamic quantities can be rescaled with the black hole charge such that these reduced quantities are charge-independent. Then we obtain the coexistence curve and the phase diagram. The latent heat is also numerically calculated. Moreover, the heat capacity and the thermodynamic scalar are studied. The result indicates that the information of the first-order black hole phase transition is encoded in the heat capacity and scalar. However, the phase transition point cannot be directly calculated with them. Nevertheless, the critical point linked to a second-order phase transition can be determined by either the heat capacity or the scalar. In addition, we calculate the critical exponents of the heat capacity and the scalar for the saturated small and large black holes near the critical point.

Second-order phase transition in gφ42 theory

International Nuclear Information System (INIS)

Ganbold, G.; Efimov, G.V.

1993-08-01

We have suggested a regular scheme for calculating systematically the leading term and next corrections to it up to the fourth order for the effective potential in the scalar φ 4 2 theory. The obtained results give evidence in favour of a second-order phase transition at (g/2πm 2 ) crit ≅ 0.9 in the theory under consideration. (author). 18 refs, 1 fig

Do phase transitions survive binomial reducibility and thermal scaling?

Energy Technology Data Exchange (ETDEWEB)

Moretto, L.G.; Phair, L.; Wozniak, G.J.

1996-05-01

First order phase transitions are described in terms of the microcanonical and canonical ensemble, with special attention to finite size effects. Difficulties in interpreting a `caloric curve` are discussed. A robust parameter indicating phase coexistence (univariance) or single phase (bivariance) is extracted for charge distributions. 9 refs., 4 figs.

Reduced order modeling of flashing two-phase jets

Energy Technology Data Exchange (ETDEWEB)

Gurecky, William, E-mail: william.gurecky@utexas.edu; Schneider, Erich, E-mail: eschneider@mail.utexas.edu; Ballew, Davis, E-mail: davisballew@utexas.edu

2015-12-01

Highlights: • Accident simulation requires ability to quickly predict two-phase flashing jet's damage potential. • A reduced order modeling methodology informed by experimental or computational data is described. • Zone of influence volumes are calculated for jets of various upstream thermodynamic conditions. - Abstract: In the event of a Loss of Coolant Accident (LOCA) in a pressurized water reactor, the escaping coolant produces a highly energetic flashing jet with the potential to damage surrounding structures. In LOCA analysis, the goal is often to evaluate many break scenarios in a Monte Carlo style simulation to evaluate the resilience of a reactor design. Therefore, in order to quickly predict the damage potential of flashing jets, it is of interest to develop a reduced order model that relates the damage potential of a jet to the pressure and temperature upstream of the break and the distance from the break to a given object upon which the jet is impinging. This work presents framework for producing a Reduced Order Model (ROM) that may be informed by measured data, Computational Fluid Dynamics (CFD) simulations, or a combination of both. The model is constructed by performing regression analysis on the pressure field data, allowing the impingement pressure to be quickly reconstructed for any given upstream thermodynamic condition within the range of input data. The model is applicable to both free and fully impinging two-phase flashing jets.

Surface-induced ordering of a liquid crystal in the isotropic phase

International Nuclear Information System (INIS)

Miyano, K.

1979-01-01

A detailed account of a measurement of order parameter of a liquid crystal at the boundary by means of the wall-induced pretransitional birefringence is given. Several surface treatments were studied including surfactants and evaporated films. Although all treatments produced good alignment in the nematic phase, the boundary order parameter (hence the strength of the aligning force) in the isotropic phase differed very much depending on the treatment, indicating the diverse nature of the alignment process

Mixed-order phase transition in a one-dimensional model.

Science.gov (United States)

Bar, Amir; Mukamel, David

2014-01-10

We introduce and analyze an exactly soluble one-dimensional Ising model with long range interactions that exhibits a mixed-order transition, namely a phase transition in which the order parameter is discontinuous as in first order transitions while the correlation length diverges as in second order transitions. Such transitions are known to appear in a diverse classes of models that are seemingly unrelated. The model we present serves as a link between two classes of models that exhibit a mixed-order transition in one dimension, namely, spin models with a coupling constant that decays as the inverse distance squared and models of depinning transitions, thus making a step towards a unifying framework.

Comparison of the orientational order of lipid chains in the Lα and HII phases

International Nuclear Information System (INIS)

Lafleur, M.; Cullis, P.R.; Fine, B.; Bloom, M.

1990-01-01

The orientational order profile has been determined by using deuterium nuclear magnetic resonance ( 2 H NMR) for POPE in the lamellar liquid-crystalline (L α ) and the hexagonal (H II ) phases and is shown to be sensitive to the symmetry of the lipid phase. In the H II phase, as compared to the L α phase, the acyl chains are characterized by a greater motional freedom, and the orientational order is distributed more uniformly along the lipid acyl chain. This is consistent with a change from a cylindrical to a wedge-shaped space available for the lipid chain. 2 H NMR studies of POPE dispersions containing tetradecanol or decane, both of which can induce H II phase structure, show very different behavior. Tetradecanol appears to align with the phospholipid chains and experience the L α to H II phase transition with a similar change in motional averaging as observed for the phospholipid chains themselves. In contrast, decane is apparently deeply embedded in the lipid structure and exhibits only a small degree of orientation. The L α to H II phase transition for systems containing decane leads to a dramatic increase of the motional freedom of decane which is more pronounced than that observed for the lipid chains. The presence of decane in the H II phase structure does not modify the order of the lipid chains. However, the L α phase of POPE is slightly disordered by the addition of 9 mol% decane whereas it can accommodate as much as 20 mol% tetradecanol without a significant change of order. Finally, the concept of a stretching vector associated with the lipid acyl chain has been introduced to analyze the orientational order profile obtained in the H II phase. With this model, the average order parameter of the H II phase has been calculated and found to be in good agreement with experiment

Phase separation in Sr doped BiMnO3

International Nuclear Information System (INIS)

Li Guan-Nan; Gao Qing-Qing; Luo Jun; Liu Guang-Yao; Liang Jing-Kui; Rao Guang-Hui; Huang Qing-Zhen; Li Jing-Bo

2014-01-01

Phase separation in Sr doped BiMnO 3 (Bi 1−x Sr x MnO 3 , x = 0.4−0.6) was studied by means of temperature-dependent high-resolution neutron powder diffraction (NPD), high resolution X-ray powder diffraction (XRD), and physical property measurements. All the experiments indicate that a phase separation occurs at the temperature coinciding with the reported charge ordering temperature (T CO ) in the literature. Below the reported T CO , both the phases resulting from the phase separation crystallize in the orthorhombically distorted perovskite structure with space group Imma. At lower temperature, these two phases order in the CE-type antiferromagnetic structure and the A-type antiferromagnetic structure, respectively. However, a scrutiny of the high-resolution NPD and XRD data at different temperatures and the electron diffraction experiment at 300 K did not manifest any evidence of a long-range charge ordering (CO) in our investigated samples, suggesting that the anomalies of physical properties such as magnetization, electric transport, and lattice parameters at the T CO might be caused by the phase separation rather than by a CO transition

Design study of beam position monitors for measuring second-order moments of charged particle beams

Directory of Open Access Journals (Sweden)

Kenichi Yanagida

2012-01-01

Full Text Available This paper presents a theoretical investigation on the multipole moments of charged particle beams in two-dimensional polar coordinates. The theoretical description of multipole moments is based on a single-particle system that is expanded to a multiparticle system by superposition, i.e., summing over all single-particle results. This paper also presents an analysis and design method for a beam position monitor (BPM that detects higher-order (multipole moments of a charged particle beam. To calculate the electric fields, a numerical analysis based on the finite difference method was created and carried out. Validity of the numerical analysis was proven by comparing the numerical with the analytical results for a BPM with circular cross section. Six-electrode BPMs with circular and elliptical cross sections were designed for the SPring-8 linac. The results of the numerical calculations show that the second-order moment can be detected for beam sizes ≧420  μm (circular and ≧550  μm (elliptical.

Mixed-order phase transition in a minimal, diffusion-based spin model.

Science.gov (United States)

Fronczak, Agata; Fronczak, Piotr

2016-07-01

In this paper we exactly solve, within the grand canonical ensemble, a minimal spin model with the hybrid phase transition. We call the model diffusion based because its Hamiltonian can be recovered from a simple dynamic procedure, which can be seen as an equilibrium statistical mechanics representation of a biased random walk. We outline the derivation of the phase diagram of the model, in which the triple point has the hallmarks of the hybrid transition: discontinuity in the average magnetization and algebraically diverging susceptibilities. At this point, two second-order transition curves meet in equilibrium with the first-order curve, resulting in a prototypical mixed-order behavior.

Effect of the hydrogen charging of AISI 316 stainless steel from solutions containing As2 O3

International Nuclear Information System (INIS)

Brito, S.D. de.

1973-01-01

The hydrogen charging of AISI 316 stainless steel has turned unstable the austenitic structure which partially decomposes into two phases: ε (hexagonal close packed) and α ' (body centered cubic). A 1 N H 2 SO 4 solution was used as electrolyte, with varying concentrations of As 2 O 3 (0, 1, 5 and 100 mg/l) for a single constant applied current density (i o = 0,22 A/cm 2 ). It was observed that a smaller austenitic grain as well as a larger hydrogen charging time, improve the phase transformation. It was established that the order in which the transformation products of the austenite appear through hydrogen charging follows the sequence: Y → Y-bar + ε → Y + ε + α ', although there is still some doubt about the equivalent transformation order by plastic deformation. (author)

Transformers: the changing phases of low-dimensional vanadium oxide bronzes.

Science.gov (United States)

Marley, Peter M; Horrocks, Gregory A; Pelcher, Kate E; Banerjee, Sarbajit

2015-03-28

In this feature article, we explore the electronic and structural phase transformations of ternary vanadium oxides with the composition MxV2O5 where M is an intercalated cation. The periodic arrays of intercalated cations ordered along quasi-1D tunnels or layered between 2D sheets of the V2O5 framework induce partial reduction of the framework vanadium atoms giving rise to charge ordering patterns that are specific to the metal M and stoichiometry x. This periodic charge ordering makes these materials remarkably versatile platforms for studying electron correlation and underpins the manifestation of phenomena such as colossal metal-insulator transitions, quantized charge corrals, and superconductivity. We describe current mechanistic understanding of these emergent phenomena with a particular emphasis on the benefits derived from scaling these materials to nanostructured dimensions wherein precise ordering of cations can be obtained and phase relationships can be derived that are entirely inaccessible in the bulk. In particular, structural transformations induced by intercalation are dramatically accelerated due to the shorter diffusion path lengths at nanometer-sized dimensions, which cause a dramatic reduction of kinetic barriers to phase transformations and facilitate interconversion between the different frameworks. We conclude by summarizing numerous technological applications that have become feasible due to recent advances in controlling the structural chemistry and both electronic and structural phase transitions in these versatile frameworks.

Evolution and control of the phase competition morphology in a manganite film

OpenAIRE

Zhou, Haibiao; Wang, Lingfei; Hou, Yubin; Huang, Zhen; Lu, Qingyou; Wu, Wenbin

2015-01-01

The competition among different phases in perovskite manganites is pronounced since their energies are very close under the interplay of charge, spin, orbital and lattice degrees of freedom. To reveal the roles of underlying interactions, many efforts have been devoted towards directly imaging phase transitions at microscopic scales. Here we show images of the charge-ordered insulator (COI) phase transition from a pure ferromagnetic metal with reducing field or increasing temperature in a str...

On the phenomenology of charged Higgs bosons in the complex MSSM

Energy Technology Data Exchange (ETDEWEB)

Thi Nhung Dao

2012-02-16

In this thesis, we study various decay and production processes of charged Higgs bosons at the Large Hadron Collider (LHC) in the context of a general complex Minimal Supersymmetric Standard Model (MSSM) with minimal flavor violation. We investigate the effect of the complex phases of the soft supersymmetry breaking parameters and of the Higgsino mixing parameter, {mu}, on the decay widths and production rates. The CP violating asymmetries induced by those phases are also considered. The calculations are done at the one-loop level. This is nontrivial since there are a large number of Feynman diagrams and various types of singularities (UV divergences, soft and collinear singularities, threshold singularities). We discuss in detail our calculation method and how to handle those divergences. In particular, the topic of one-loop renormalization and neutral-Higgs mixing effects in the complex MSSM for processes involving Higgs bosons are addressed. The higher order corrections to the decay of charged Higgs bosons into aW-boson and the lightest neutral Higgs boson are calculated and shown to be significantly large. The CP asymmetry arising from all complex phases is considered, especially from the top-quark trilinear coupling, A{sub t}, and {mu}, which induce a large contribution to the CP asymmetry. We perform a complete calculation of the next-to-leading order (NLO) electroweak (EW) corrections to the charged Higgs production in association with a W-boson via the bb annihilation channel and a consistent combination with other contributions including the standard and supersymmetric-QCD corrections and the gg fusion, with resummation of the leading radiative corrections to the bottom-Higgs couplings and the neutral Higgs-boson propagators. We observe a strong dependence of the production rates on the phases of A{sub t} and of the gluino-mass parameter M{sub 3} and a large CP asymmetry arising mainly from the gg fusion. The NLO EW corrections to the charged Higgs

Direct observation of competition between superconductivity and charge density wave order in YBa2Cu3O6.67

DEFF Research Database (Denmark)

Chang, J.; Blackburn, E.; Holmes, A. T.

2012-01-01

Superconductivity often emerges in the proximity of, or in competition with, symmetry-breaking ground states such as antiferromagnetism or charge density waves (CDW). A number of materials in the cuprate family, which includes the high transition-temperature (high-Tc) superconductors, show spin...... and charge density wave order. Thus a fundamental question is to what extent do these ordered states exist for compositions close to optimal for superconductivity. Here we use high-energy X-ray diffraction to show that a CDW develops at zero field in the normal state of superconducting YBa2Cu3O6.67 (Tc= 67 K......). This sample has a hole doping of 0.12 per copper and a well-ordered oxygen chain superstructure. Below Tc, the application of a magnetic field suppresses superconductivity and enhances the CDW. Hence, the CDW and superconductivity in this typical high-Tc material are competing orders with similar energy...

Stochasticity of phase trajectory of a charged particle in a plasma wave

International Nuclear Information System (INIS)

Murakami, Akihiko; Nomura, Yasuyuki; Momota, Hiromu.

1980-06-01

Stochastic behavior of charged particles in finite amplitude plasma waves is examined by means of particle simulations under the condition that Chirikov's criterion is broken down. The process of growint the stochastic region is clarified and accordingly the width of the stochastic region is discussed. Discussions on the effects of higher order resonances are also presented. (author)

Dynamic Monte Carlo Simulations of Phase Ordering in Br Electrosorption on Ag(100)

Science.gov (United States)

Mitchell, S. J.; Brown, G.; Rikvold, P. A.

2000-03-01

We study the dynamics of Br electrosorption on single-crystal Ag(100) by Monte Carlo simulation. The system has a second-order phase transition from a low-coverage disordered phase at more negative potentials to a doubly degenerate c(2× 2) ordered phase at more positive potentials.(B.M. Ocko, et al.), Phys. Rev. Lett. 79, 1511 (1997). Effective lateral interactions were estimated by fitting equilibrium Monte Carlo isotherms to experiments. These are well described by nearest-neighbor exclusion and repulsive 1/r^3 interactions.(M.T.M. Koper, J. Electroanal. Chem. 450), 189 (1997). Considering adsorption/desorption and diffusion with barriers estimated from ab-initio calculations,(A. Ignaczak and J.A.N.F. Gomes, J. Electroanal. Chem. 420), 71 (1997). we simulate the time dependent Br coverage, order parameter, and x-ray scattering intensity following sudden potential steps across the phase boundary. For steps far into the ordered phase, dynamical scaling is observed. For smaller steps, the dynamics are more complicated. We also analyze hysteresis in a simulated cyclic-voltammetry experiment. Movies at http://www.scri.fsu.edu/ ~mitchell/.

Phase transition type change in order-order and order-disorder transformations of LaH2+c-like superstoichiometric dihydrides

International Nuclear Information System (INIS)

Ratishvili, I.G.

1999-01-01

Phase transformations in metal-hydrogen systems associated with the ordering processes in the subsystem of interstitial hydrogen atoms are considered. It is shown that in a particular class of superstoichiometric rare-earth dihydrides, where the ordering subsystem is characterized by two long-range-order parameters η 1 , η 2 and the energy parameter p 0 (1) (p) ≤ c ≤ c 0 (2) (p), it becomes discontinuous outside of this region. Dependence of critical concentrations c 0 (1) and c 0 (2) upon the energy parameter p is deduced. It is shown, as well, that there exists a second sequence of critical concentrations, c 1 (1) (p) and c 1 (2) (p), denoting the boundaries between the regions of continuous and discontinuous order-disorder transformations. (orig.)

Optical properties of two-dimensional charge density wave materials

Science.gov (United States)

Sayers, Charles; Karbassi, Sara; Friedemann, Sven; da Como, Enrico

Titanium diselenide (TiSe2) is a member of the layered transition metal dichalcogenide (TMD) materials. It exhibits unusual chiral charge ordering below 190 K after undergoing an initial phase transition to a commensurate (2 x 2 x 2) charge density wave (CDW) at 200 K which is enhanced further in the monolayer. Recently, the first evidence of chirality in a CDW system was discovered in this material by scanning tunneling microscopy and time-resolved reflectivity experiments, where separate left and right handed charge-ordered domains were found to exist within a single sample. We have prepared single crystals of 1T-TiSe2 using iodine vapour transport, and confirmed their quality by x-ray analysis and charge transport measurements. Using a combination of polarised optical spectroscopy techniques in the mid to far infrared (4 to 700 meV photon energy), we have measured an anisotropy relating to the CDW gap. We discuss the results on the basis of chiral domains with different handedness and the nature of the CDW transition.

Real-space calculations of nonspherically averaged charge densities for substitutionally disordered alloys

International Nuclear Information System (INIS)

Singh, P.P.; Gonis, A.

1993-01-01

Based on screening transformations of muffin-tin orbitals introduced by Andersen and Jepsen [Phys. Rev. Lett. 53, 2571 (1984)], we have developed a formalism for calculating the nonspherically averaged charge densities of substitutionally disordered alloys using the Korringa-Kohn-Rostoker coherent-potential-approximation (KKR CPA) method in the atomic-sphere approximation (ASA). We have validated our method by calculating charge densities for ordered structures, where we find that our approach yields charge densities that are essentially indistinguishable from the results of full-potential methods. Calculations and comparisons are reported for Si, Al, and Li. For substitutionally disordered alloys, where full-potential methods have not been implemented so far, our approach can be used to calculate reliable nonspherically averaged charge densities from spherically symmetric one-electron potentials obtained from the KKR-ASA CPA. We report on our study of differences in charge density between ordered AlLi in the L1 0 phase and substitutionally disordered Al 0.5 Li 0.5 on a face-centered-cubic lattice

Third-order QCD corrections to the charged-current structure function F{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Moch, S. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Vermaseren, J.A.M. [NIKHEF, Amsterdam (Netherlands); Vogt, A. [Liverpool Univ. (United Kingdom). Dept. of Mathematical Sciences

2008-12-15

We compute the coefficient function for the charge-averaged W{sup {+-}}-exchange structure function F{sub 3} in deep-inelastic scattering (DIS) to the third order in massless perturbative QCD. Our new three-loop contribution to this quantity forms, at not too small values of the Bjorken variable x, the dominant part of the next-to-next-to-next-to-leading order corrections. It thus facilitates improved determinations of the strong coupling {alpha}{sub s} and of 1/Q{sup 2} power corrections from scaling violations measured in neutrino-nucleon DIS. The expansion of F{sub 3} in powers of {alpha}{sub s} is stable at all values of x relevant to measurements at high scales Q{sup 2}. At small x the third-order coefficient function is dominated by diagrams with the colour structure d{sup abc}d{sub abc} not present at lower orders. At large x the coefficient function for F{sub 3} is identical to that of F{sub 1} up to terms vanishing for x{yields}1. (orig.)

On entropy change measurements around first order phase transitions in caloric materials.

Science.gov (United States)

Caron, Luana; Ba Doan, Nguyen; Ranno, Laurent

2017-02-22

In this work we discuss the measurement protocols for indirect determination of the isothermal entropy change associated with first order phase transitions in caloric materials. The magneto-structural phase transitions giving rise to giant magnetocaloric effects in Cu-doped MnAs and FeRh are used as case studies to exemplify how badly designed protocols may affect isothermal measurements and lead to incorrect entropy change estimations. Isothermal measurement protocols which allow correct assessment of the entropy change around first order phase transitions in both direct and inverse cases are presented.

Magnetic impurity effect on charge and magnetic order in doped La1.5Ca0.5CoO4

Science.gov (United States)

Horigane, K.; Hiraka, H.; Tomiyasu, K.; Ohoyama, K.; Louca, D.; Yamada, K.

2012-02-01

Neutron scattering experiments were performed on single crystals of magnetic impurity doped cobalt oxides La1.5Ca0.5CoO4 to characterize the charge and spin orders. We newly found contrasting impurity effects. Two types of magnetic peaks are observed at q = (0.5,0,L) with L = half-integer and integer in La1.5Ca0.5CoO4, while magnetic peak at L = half-integer (integer) was only observed in Mn (Fe)-substituted sample. Although Mn and Fe impurities degrade charge and magnetic order, Cr impurity stabilizes the ordering at x = 0.5. Based on the crystal structural analysis of Cr doped sample, we found that the excess oxygen and change of octahedron around Co3+ were realized in Cr doped sample.

Reduced order generalized integrators with phase compensation for three-phase active power filter

DEFF Research Database (Denmark)

Xie, Chuan; Li, Kai; Zhao, Xin

2017-01-01

-order generalized integrators (SOGIs) are utilized to achieve those objectives. However, it will increase the computational burden due to calculation of the multiple paralleled SOGIs. To overcome this issue, phase compensated reduced order generalized integrator (ROGI) is proposed in this paper. Compared...... paralleled ROGIs in positive and negative resonant frequencies. Moreover, the controller parameters are designed and optimized by means of Nyquist diagrams and sensitivity functions in z-domain for directly digital implementation. Finally, the laboratory tests of APF are performed to validate the feasibility...

Charge ordering, ferroelectric, and magnetic domains in LuFe{sub 2}O{sub 4} observed by scanning probe microscopy

Energy Technology Data Exchange (ETDEWEB)

Yang, I. K.; Jeong, Y. H., E-mail: yhj@postech.ac.kr [Department of Physics, POSTECH, 77 Cheongam-Ro, Pohang 790-784 (Korea, Republic of); Kim, Jeehoon [Department of Physics, POSTECH, 77 Cheongam-Ro, Pohang 790-784 (Korea, Republic of); CALDES, Institute of Basic Science, 77 Cheongam-Ro, Pohang 790-784 (Korea, Republic of); Lee, S. H. [YE Team, Samsung Electronics, 1 Samsungjeonja-Ro, Hwaseong 445-330 (Korea, Republic of); Cheong, S.-W. [Laboratory of Pohang Emergent Materials, POSTECH, 77 Cheongam-Ro, Pohang 790-784 (Korea, Republic of); Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854 (United States)

2015-04-13

LuFe{sub 2}O{sub 4} is a multiferroic system which exhibits charge order, ferroelectricity, and ferrimagnetism simultaneously below ∼230 K. The ferroelectric/charge order domains of LuFe{sub 2}O{sub 4} are imaged with both piezoresponse force microscopy (PFM) and electrostatic force microscopy (EFM), while the magnetic domains are characterized by magnetic force microscopy (MFM). Comparison of PFM and EFM results suggests that the proposed ferroelectricity in LuFe{sub 2}O{sub 4} is not of usual displacive type but of electronic origin. Simultaneous characterization of ferroelectric/charge order and magnetic domains by EFM and MFM, respectively, on the same surface of LuFe{sub 2}O{sub 4} reveals that both domains have irregular patterns of similar shape, but the length scales are quite different. The domain size is approximately 100 nm for the ferroelectric domains, while the magnetic domain size is much larger and gets as large as 1 μm. We also demonstrate that the origin of the formation of irregular domains in LuFe{sub 2}O{sub 4} is not extrinsic but intrinsic.

The Roles of Structural Order and Intermolecular Interactions in Determining Ionization Energies and Charge-Transfer State Energies in Organic Semiconductors

KAUST Repository

Graham, Kenneth; Ngongang Ndjawa, Guy Olivier; Conron, Sarah M.; Munir, Rahim; Vandewal, Koen; Chen, John J.; Sweetnam, Sean; Thompson, Mark E.; Salleo, Alberto; Mcgehee, Michael D.; Amassian, Aram

2016-01-01

The energy landscape in organic semiconducting materials greatly influences charge and exciton behavior, which are both critical to the operation of organic electronic devices. These energy landscapes can change dramatically depending on the phases

Charge-transport simulations in organic semiconductors

Energy Technology Data Exchange (ETDEWEB)

May, Falk

2012-07-06

In this thesis we have extended the methods for microscopic charge-transport simulations for organic semiconductors, where weak intermolecular interactions lead to spatially localized charge carriers, and the charge transport occurs as an activated hopping process between diabatic states. In addition to weak electronic couplings between these states, different electrostatic environments in the organic material lead to a broadening of the density of states for the charge energies which limits carrier mobilities. The contributions to the method development include (i) the derivation of a bimolecular charge-transfer rate, (ii) the efficient evaluation of intermolecular (outer-sphere) reorganization energies, (iii) the investigation of effects of conformational disorder on intramolecular reorganization energies or internal site energies and (iv) the inclusion of self-consistent polarization interactions for calculation of charge energies. These methods were applied to study charge transport in amorphous phases of small molecules used in the emission layer of organic light emitting diodes (OLED). When bulky substituents are attached to an aromatic core in order to adjust energy levels or prevent crystallization, a small amount of delocalization of the frontier orbital to the substituents can increase electronic couplings between neighboring molecules. This leads to improved charge-transfer rates and, hence, larger charge-mobility. We therefore suggest using the mesomeric effect (as opposed to the inductive effect) when attaching substituents to aromatic cores, which is necessary for example in deep blue OLEDs, where the energy levels of a host molecule have to be adjusted to those of the emitter. Furthermore, the energy landscape for charges in an amorphous phase cannot be predicted by mesoscopic models because they approximate the realistic morphology by a lattice and represent molecular charge distributions in a multipole expansion. The microscopic approach shows that

Strongly first-order electroweak phase transition and classical scale invariance

Science.gov (United States)

Farzinnia, Arsham; Ren, Jing

2014-10-01

In this work, we examine the possibility of realizing a strongly first-order electroweak phase transition within the minimal classically scale-invariant extension of the standard model (SM), previously proposed and analyzed as a potential solution to the hierarchy problem. By introducing one complex gauge-singlet scalar and three (weak scale) right-handed Majorana neutrinos, the scenario was successfully rendered capable of achieving a radiative breaking of the electroweak symmetry (by means of the Coleman-Weinberg mechanism), inducing nonzero masses for the SM neutrinos (via the seesaw mechanism), presenting a pseudoscalar dark matter candidate (protected by the CP symmetry of the potential), and predicting the existence of a second CP-even boson (with suppressed couplings to the SM content) in addition to the 125 GeV scalar. In the present treatment, we construct the full finite-temperature one-loop effective potential of the model, including the resummed thermal daisy loops, and demonstrate that finite-temperature effects induce a first-order electroweak phase transition. Requiring the thermally driven first-order phase transition to be sufficiently strong at the onset of the bubble nucleation (corresponding to nucleation temperatures TN˜100-200 GeV) further constrains the model's parameter space; in particular, an O(0.01) fraction of the dark matter in the Universe may be simultaneously accommodated with a strongly first-order electroweak phase transition. Moreover, such a phase transition disfavors right-handed Majorana neutrino masses above several hundreds of GeV, confines the pseudoscalar dark matter masses to ˜1-2 TeV, predicts the mass of the second CP-even scalar to be ˜100-300 GeV, and requires the mixing angle between the CP-even components of the SM doublet and the complex singlet to lie within the range 0.2≲sinω ≲0.4. The obtained results are displayed in comprehensive exclusion plots, identifying the viable regions of the parameter space

Critical phenomena of static charged AdS black holes in conformal gravity

Directory of Open Access Journals (Sweden)

Wei Xu

2014-09-01

Full Text Available The extended thermodynamics of static charged AdS black holes in conformal gravity is analyzed. The P–V criticality of these black holes has some unusual features. There exists a single critical point with critical temperature Tc and critical pressure Pc. At fixed T>Tc (or at fixed P>Pc, there are two zeroth order phase transition points but no first order phase transition points. The systems favors large pressure states at constant T, or high temperature states at constant P.

Organic charge transfer phase formation in thin films of the BEDT-TTF/TCNQ donor-acceptor system

DEFF Research Database (Denmark)

Solovyeva, Vita; Keller, K.; Huth, M.

2009-01-01

We have performed charge transfer phase formation studies on the donor/acceptor system bis-(ethylendithio)tetrathiafulvalene (BEDT-TTF)/tetracyanoquinodimethane,(TCNQ) by means of physical vapor deposition. We prepared donor/acceptor bilayer structures on glass and Si(100)/SiO substrates held...

Phase diagram, correlation gap, and critical properties of the Coulomb glass

Science.gov (United States)

Palassini, Matteo; Goethe, Martin

2009-03-01

We investigate the lattice Coulomb glass model in three dimensions via extensive Monte Carlo simulations. 1. No evidence for an equilibrium glass phase is found down to very low temperatures, contrary to mean-field predictions, although the correlation length increases rapidly near T=0. 2. The single-particle density of states near the Coulomb gap satisfies the scaling law g(e,T)=T^λf(e/T) with λ 2.2. 3. A charge-ordered phase exists at low disorder. The phase transition from the fluid to the charge ordered phase is consistent with the Random Field Ising universality class, which shows that the interaction is effectively screened at moderate temperature. Results from nonequilibrium simulations will also be briefly discussed. Reference: M.Goethe and M.Palassini, arXiv:0810.1047

Spontaneous charged lipid transfer between lipid vesicles.

Science.gov (United States)

Richens, Joanna L; Tyler, Arwen I I; Barriga, Hanna M G; Bramble, Jonathan P; Law, Robert V; Brooks, Nicholas J; Seddon, John M; Ces, Oscar; O'Shea, Paul

2017-10-03

An assay to study the spontaneous charged lipid transfer between lipid vesicles is described. A donor/acceptor vesicle system is employed, where neutrally charged acceptor vesicles are fluorescently labelled with the electrostatic membrane probe Fluoresceinphosphatidylethanolamine (FPE). Upon addition of charged donor vesicles, transfer of negatively charged lipid occurs, resulting in a fluorescently detectable change in the membrane potential of the acceptor vesicles. Using this approach we have studied the transfer properties of a range of lipids, varying both the headgroup and the chain length. At the low vesicle concentrations chosen, the transfer follows a first-order process where lipid monomers are transferred presumably through the aqueous solution phase from donor to acceptor vesicle. The rate of transfer decreases with increasing chain length which is consistent with energy models previously reported for lipid monomer vesicle interactions. Our assay improves on existing methods allowing the study of a range of unmodified lipids, continuous monitoring of transfer and simplified experimental procedures.

Research of Charging(Discharging Orderly and Optimizing Load Curve for Electric Vehicles Based on Dynamic Electric Price and V2G

Directory of Open Access Journals (Sweden)

Yang Shuai

2016-01-01

Full Text Available Firstly, using the Monte Carlo method and simulation analysis, this paper builds models for the behaviour of electric vehicles, the conventional charging model and the fast charging model. Secondly, this paper studies the impact that the number of electric vehicles which get access to power grid has on the daily load curve. Then, the paper put forwards a dynamic pricing mechanism of electricity, and studies how this dynamic pricing mechanism guides the electric vehicles to charge orderly. Last but not the least, the paper presents a V2G mechanism. Under this mechanism, electric vehicles can charge orderly and take part in the peak shaving. Research finds that massive electric vehicles’ access to the power grid will increase the peak-valley difference of daily load curve. Dynamic pricing mechanism and V2G mechanism can effectively lead the electric vehicles to take part in peak-shaving, and optimize the daily load curve.

Nucleation of relativistic first-order phase transitions

International Nuclear Information System (INIS)

Csernai, L.P.; Kapusta, J.I.

1992-01-01

The authors apply the general formalism of Langer to compute the nucleation rate for systems of relativistic particles with zero or small baryon number density and which undergo first-order phase transitions. In particular, the pre-exponential factor is computed and it is proportional to the viscosity. The initial growth rate of a critical size bubble or droplet is limited by the ability of dissipative processes to transport latent heat away from the surface. 30 refs., 4 figs

The Hagedorn spectrum, nuclear level densities and first order phase transitions

International Nuclear Information System (INIS)

Moretto, Luciano G.; Larsen, A. C.; Guttormsen, M.; Siem, S.

2015-01-01

An exponential mass spectrum, like the Hagedorn spectrum, with slope 1/T H was interpreted as fixing an upper limiting temperature T H that the system can achieve. However, thermodynamically, such spectrum indicates a 1 st order phase transition at a fixed temperature T H . A much lower energy example is the log linear level nuclear density below the neutron binding energy that prevails throughout the nuclear chart. We show that, for non-magic nuclei, such linearity implies a 1 st order phase transition from the pairing superfluid to an ideal gas of quasi particles

Supermolecular structure and charge carriers mobilities of perylene diimides

Energy Technology Data Exchange (ETDEWEB)

Marcon, Valentina; Pisula, Wojtek; Andrienko, Denis [Max-Planck-Institut fuer Polymerforschung, Mainz (Germany); Kirkpatrick, James [Max-Planck-Institut fuer Polymerforschung, Mainz (Germany); Department of Physics, Imperial College London, London (United Kingdom)

2008-07-01

Perylene diimides form columnar phases, where the molecules stack on top of each other and the columns arrange in a regular lattice. The self-organization into well-ordered columns results in the one-dimensional charge transport along the stack of the aromatic cores of the molecules. Most of the discotic molecules which organize in columns are p-type semiconductors, while the class of rylene diimide molecules, to which perylene belongs, forms n-type organic semiconductors. Using atomistic molecular dynamics (MD) simulations we study the columnar phases of perylene diimides and establish correlations between the molecular structure, packing, and dynamical properties of these materials. By using a scheme which combines electronic structure calculations, MD and kinetic Monte Carlo simulations, a correlation is then established between the molecular structure and charge mobility of perylenes columnar mesophases.

Phase diagram and topological phases in the triangular lattice Kitaev-Hubbard model

Science.gov (United States)

Li, Kai; Yu, Shun-Li; Gu, Zhao-Long; Li, Jian-Xin

2016-09-01

We study the half-filled Hubbard model on a triangular lattice with spin-dependent Kitaev-like hopping. Using the variational cluster approach, we identify five phases: a metallic phase, a non-coplanar chiral magnetic order, a 120° magnetic order, a nonmagnetic insulator (NMI), and an interacting Chern insulator (CI) with a nonzero Chern number. The transition from CI to NMI is characterized by the change of the charge gap from an indirect band gap to a direct Mott gap. Based on the slave-rotor mean-field theory, the NMI phase is further suggested to be a gapless Mott insulator with a spinon Fermi surface or a fractionalized CI with nontrivial spinon topology, depending on the strength of the Kitaev-like hopping. Our work highlights the rising field in which interesting phases emerge from the interplay between band topology and Mott physics.

Compositional modeling of three-phase flow with gravity using higher-order finite element methods

KAUST Repository

Moortgat, Joachim

2011-05-11

A wide range of applications in subsurface flow involve water, a nonaqueous phase liquid (NAPL) or oil, and a gas phase, such as air or CO2. The numerical simulation of such processes is computationally challenging and requires accurate compositional modeling of three-phase flow in porous media. In this work, we simulate for the first time three-phase compositional flow using higher-order finite element methods. Gravity poses complications in modeling multiphase processes because it drives countercurrent flow among phases. To resolve this issue, we propose a new method for the upwinding of three-phase mobilities. Numerical examples, related to enhanced oil recovery and carbon sequestration, are presented to illustrate the capabilities of the proposed algorithm. We pay special attention to challenges associated with gravitational instabilities and take into account compressibility and various phase behavior effects, including swelling, viscosity changes, and vaporization. We find that the proposed higher-order method can capture sharp solution discontinuities, yielding accurate predictions of phase boundaries arising in computational three-phase flow. This work sets the stage for a broad extension of the higher-order methods for numerical simulation of three-phase flow for complex geometries and processes.

The Impact of Donor-Acceptor Phase Separation on the Charge Carrier Dynamics in pBTTT:PCBM Photovoltaic Blends

KAUST Repository

Gehrig, Dominik W.; Howard, Ian A.; Sweetnam, Sean; Burke, Timothy M.; McGehee, Michael D.; Laquai, Fré dé ric

2015-01-01

The effect of donor–acceptor phase separation, controlled by the donor–acceptor mixing ratio, on the charge generation and recombination dynamics in pBTTT-C14:PC70BM bulk heterojunction photovoltaic blends is presented. Transient absorption (TA) spectroscopy spanning the dynamic range from pico- to microseconds in the visible and near-infrared spectral regions reveals that in a 1:1 blend exciton dissociation is ultrafast; however, charges cannot entirely escape their mutual Coulomb attraction and thus predominantly recombine geminately on a sub-ns timescale. In contrast, a polymer:fullerene mixing ratio of 1:4 facilitates the formation of spatially separated, that is free, charges and reduces substantially the fraction of geminate charge recombination, in turn leading to much more efficient photovoltaic devices. This illustrates that spatially extended donor or acceptor domains are required for the separation of charges on an ultrafast timescale (<100 fs), indicating that they are not only important for efficient charge transport and extraction, but also critically influence the initial stages of free charge carrier formation.

The Impact of Donor-Acceptor Phase Separation on the Charge Carrier Dynamics in pBTTT:PCBM Photovoltaic Blends

KAUST Repository

Gehrig, Dominik W.

2015-04-07

The effect of donor–acceptor phase separation, controlled by the donor–acceptor mixing ratio, on the charge generation and recombination dynamics in pBTTT-C14:PC70BM bulk heterojunction photovoltaic blends is presented. Transient absorption (TA) spectroscopy spanning the dynamic range from pico- to microseconds in the visible and near-infrared spectral regions reveals that in a 1:1 blend exciton dissociation is ultrafast; however, charges cannot entirely escape their mutual Coulomb attraction and thus predominantly recombine geminately on a sub-ns timescale. In contrast, a polymer:fullerene mixing ratio of 1:4 facilitates the formation of spatially separated, that is free, charges and reduces substantially the fraction of geminate charge recombination, in turn leading to much more efficient photovoltaic devices. This illustrates that spatially extended donor or acceptor domains are required for the separation of charges on an ultrafast timescale (<100 fs), indicating that they are not only important for efficient charge transport and extraction, but also critically influence the initial stages of free charge carrier formation.

Phase and fringe order determination in wavelength scanning interferometry.

Science.gov (United States)

Moschetti, Giuseppe; Forbes, Alistair; Leach, Richard K; Jiang, Xiang; O'Connor, Daniel

2016-04-18

A method to obtain unambiguous surface height measurements using wavelength scanning interferometry with an improved repeatability, comparable to that obtainable using phase shifting interferometry, is reported. Rather than determining the conventional fringe frequency-derived z height directly, the method uses the frequency to resolve the fringe order ambiguity, and combine this information with the more accurate and repeatable fringe phase derived z height. A theoretical model to evaluate the method's performance in the presence of additive noise is derived and shown to be in good agreement with experiments. The measurement repeatability is improved by a factor of ten over that achieved when using frequency information alone, reaching the sub-nanometre range. Moreover, the z-axis non-linearity (bleed-through or ripple error) is reduced by a factor of ten. These order of magnitude improvements in measurement performance are demonstrated through a number of practical measurement examples.

Monte Carlo studies of diamagnetism and charge density wave order in the cuprate pseudogap regime

Science.gov (United States)

Hayward Sierens, Lauren; Achkar, Andrew; Hawthorn, David; Melko, Roger; Sachdev, Subir

2015-03-01

The pseudogap regime of the hole-doped cuprate superconductors is often characterized experimentally in terms of a substantial diamagnetic response and, from another point of view, in terms of strong charge density wave (CDW) order. We introduce a dimensionless ratio, R, that incorporates both diamagnetic susceptibility and the correlation length of CDW order, and therefore reconciles these two fundamental characteristics of the pseudogap. We perform Monte Carlo simulations on a classical model that considers angular fluctuations of a six-dimensional order parameter, and compare our Monte Carlo results for R with existing data from torque magnetometry and x-ray scattering experiments on YBa2Cu3O6+x. We achieve qualitative agreement, and also propose future experiments to further investigate the behaviour of this dimensionless ratio.

Poisson-Boltzmann theory of the charge-induced adsorption of semi-flexible polyelectrolytes.

Science.gov (United States)

Ubbink, Job; Khokhlov, Alexei R

2004-03-15

A model is suggested for the structure of an adsorbed layer of a highly charged semi-flexible polyelectrolyte on a weakly charged surface of opposite charge sign. The adsorbed phase is thin, owing to the effective reversal of the charge sign of the surface upon adsorption, and ordered, owing to the high surface density of polyelectrolyte strands caused by the generally strong binding between polyelectrolyte and surface. The Poisson-Boltzmann equation for the electrostatic interaction between the array of adsorbed polyelectrolytes and the charged surface is solved for a cylindrical geometry, both numerically, using a finite element method, and analytically within the weak curvature limit under the assumption of excess monovalent salt. For small separations, repulsive surface polarization and counterion osmotic pressure effects dominate over the electrostatic attraction and the resulting electrostatic interaction curve shows a minimum at nonzero separations on the Angstrom scale. The equilibrium density of the adsorbed phase is obtained by minimizing the total free energy under the condition of equality of chemical potential and osmotic pressure of the polyelectrolyte in solution and in the adsorbed phase. For a wide range of ionic conditions and charge densities of the charged surface, the interstrand separation as predicted by the Poisson-Boltzmann model and the analytical theory closely agree. For low to moderate charge densities of the adsorbing surface, the interstrand spacing decreases as a function of the charge density of the charged surface. Above about 0.1 M excess monovalent salt, it is only weakly dependent on the ionic strength. At high charge densities of the adsorbing surface, the interstrand spacing increases with increasing ionic strength, in line with the experiments by Fang and Yang [J. Phys. Chem. B 101, 441 (1997)]. (c) 2004 American Institute of Physics.

Contribution to the investigation of phase transitions induced by irradiation in insulating crystalline ceramics

International Nuclear Information System (INIS)

Simeone, D.

2003-01-01

The author gives a rather detailed overview of his research activities on the behaviour of ceramics subjected to irradiations by charged or not-charged particles. He reports the development of a new application of low incidence X ray diffraction to assess the evolutions within irradiated solids. Coupling this technique with Raman spectroscopy studies enabled the monitoring of order parameter evolution in these solids. He shows that, in some oxides, irradiation effects entail order-disorder type transitions and, more surprisingly, displacive phase transitions. From this experimental work, he developed a modelling of these phase transitions induced by irradiation. Quantitative data obtained on the evolutions of order parameters enabled these phase transitions to be explained within the frame of the thermodynamics of off-equilibrium phenomena

Surface charges for gravity and electromagnetism in the first order formalism

Science.gov (United States)

Frodden, Ernesto; Hidalgo, Diego

2018-02-01

A new derivation of surface charges for 3  +  1 gravity coupled to electromagnetism is obtained. Gravity theory is written in the tetrad-connection variables. The general derivation starts from the Lagrangian, and uses the covariant symplectic formalism in the language of forms. For gauge theories, surface charges disentangle physical from gauge symmetries through the use of Noether identities and the exactness symmetry condition. The surface charges are quasilocal, explicitly coordinate independent, gauge invariant and background independent. For a black hole family solution, the surface charge conservation implies the first law of black hole mechanics. As a check, we show the first law for an electrically charged, rotating black hole with an asymptotically constant curvature (the Kerr–Newman (anti-)de Sitter family). The charges, including the would-be mass term appearing in the first law, are quasilocal. No reference to the asymptotic structure of the spacetime nor the boundary conditions is required and therefore topological terms do not play a rôle. Finally, surface charge formulae for Lovelock gravity coupled to electromagnetism are exhibited, generalizing the one derived in a recent work by Barnich et al Proc. Workshop ‘ About Various Kinds of Interactions’ in honour of Philippe Spindel (4–5 June 2015, Mons, Belgium) C15-06-04 (2016 (arXiv:1611.01777 [gr-qc])). The two different symplectic methods to define surface charges are compared and shown equivalent.

Anharmonic phonons and second-order phase-transitions by the stochastic self-consistent harmonic approximation

Science.gov (United States)

Mauri, Francesco

Anharmonic effects can generally be treated within perturbation theory. Such an approach breaks down when the harmonic solution is dynamically unstable or when the anharmonic corrections of the phonon energies are larger than the harmonic frequencies themselves. This situation occurs near lattice-related second-order phase-transitions such as charge-density-wave (CDW) or ferroelectric instabilities or in H-containing materials, where the large zero-point motion of the protons results in a violation of the harmonic approximation. Interestingly, even in these cases, phonons can be observed, measured, and used to model transport properties. In order to treat such cases, we developed a stochastic implementation of the self-consistent harmonic approximation valid to treat anharmonicity in the nonperturbative regime and to obtain, from first-principles, the structural, thermodynamic and vibrational properties of strongly anharmonic systems. I will present applications to the ferroelectric transitions in SnTe, to the CWD transitions in NbS2 and NbSe2 (in bulk and monolayer) and to the hydrogen-bond symmetrization transition in the superconducting hydrogen sulfide system, that exhibits the highest Tc reported for any superconductor so far. In all cases we are able to predict the transition temperature (pressure) and the evolution of phonons with temperature (pressure). This project has received funding from the European Union's Horizon 2020 research and innovation programme under Grant agreement No. 696656 GrapheneCore1.

Space Charge Effects

CERN Document Server

Ferrario, M.; Palumbo, L.

2014-12-19

The space charge forces are those generated directly by the charge distribution, with the inclusion of the image charges and currents due to the interaction of the beam with a perfectly conducting smooth pipe. Space charge forces are responsible for several unwanted phenomena related to beam dynamics, such as energy loss, shift of the synchronous phase and frequency , shift of the betatron frequencies, and instabilities. We will discuss in this lecture the main feature of space charge effects in high-energy storage rings as well as in low-energy linacs and transport lines.

Can macular xanthophylls replace cholesterol in formation of the liquid-ordered phase in lipid-bilayer membranes?

Science.gov (United States)

Subczynski, Witold K; Wisniewska-Becker, Anna; Widomska, Justyna

2012-01-01

Lateral organization of membranes made from binary mixtures of dimyristoylphosphatidylcholine (DMPC) or dipalmitoylphosphatidylcholine (DPPC) and macular xanthophylls (lutein or zeaxanthin) was investigated using the saturation-recovery (SR) EPR spin-labeling discrimination by oxygen transport (DOT) method in which the bimolecular collision rate of molecular oxygen with the nitroxide spin label is measured. This work was undertaken to examine whether or not lutein and zeaxanthin, macular xanthophylls that parallel cholesterol in its function as a regulator of both membrane fluidity and hydrophobicity, can parallel other structural functions of cholesterol, including formation of the liquid-ordered phase in membranes. The DOT method permits discrimination of different membrane phases when the collision rates (oxygen transport parameter) differ in these phases. Additionally, membrane phases can be characterized by the oxygen transport parameter in situ without the need for separation, which provides information about the dynamics of each phase. In gel-phase membranes, two coexisting phases were discriminated in the presence of macular xanthophylls - namely, the liquid-ordered-like and solid-ordered-like phases. However, in fluid-phase membranes, xanthophylls only induce the solitary liquid-ordered-like phase, while at similar concentrations, cholesterol induces coexisting liquid-ordered and liquid-disordered phases. No significant differences between the effects of lutein and zeaxanthin were found.

Absence of Long-Ranged Charge Order in NaxCa2-xCuO2Cl2 (x=0.08)

Energy Technology Data Exchange (ETDEWEB)

Smadici,S.; Abbamonte, P.; Taguchi, M.; Kohsaka, Y.; Sasagawa, T.; Azuma, M.; Takano, M.; Takagi, H.

2007-01-01

Recent scanning-tunneling spectroscopy (STS) studies of the cupric oxychloride Na{sub x}Ca{sub 2-x}CuO{sub 2}Cl{sub 2} (NCCOC) have uncovered a periodic 4a x 4a density of states (DOS) modulation, termed a 'checkerboard' (T. Hanaguri et al., Nature (London) 430, 1001 (2004)). The periodicity of this phase is the same as that of the 'stripe' charge order observed with neutron scattering in the very similar systems La{sub 1.48}Nd{sub 0.4}Sr{sub 0.12}CuO{sub 4} (LNSCO). This raises the question of whether the stripes are, in fact, actually checkerboards. Unfortunately, NCCOC samples are very small and LBCO and LNSCO samples do not cleave, so neutron and STS measurements cannot be carried out on the same system. To determine the relationship between stripes and checkers, we used resonant soft-x-ray scattering, previously applied to LBCO, to study single crystals of NCCOC. No evidence was seen for a 4a x 4a DOS modulation, indicating that the checkerboard effect is not directly related to the stripe modulation in LBCO. We place an upper bound on the product of the charge amplitude and the square of the in-plane correlation length of 2.3 x 10{sup 3} hole {angstrom}{sup 2}. Our measurements suggest that the checkers in NCCOC are either glassy or are nucleated by the surface, as suggested by Brown et al.

First-Order Transitions and the Magnetic Phase Diagram of CeSb

DEFF Research Database (Denmark)

Lebech, Bente; Clausen, Kurt Nørgaard; Vogt, O.

1980-01-01

might exist in the magnetic phase diagram of CeSb at 16K for a field of approximately 0.3 T. The present study concludes that the transitions from the paramagnetic to the magnetically ordered states are of first order for fields below 0.8 T. Within the experimental accuracy no change has been observed......The high-temperature (14-17K) low-magnetic field (0-0.8 T) region of the phase diagram of the anomalous antiferromagnet CeSb has been reinvestigated by neutron diffraction in an attempt to locate a possible tricritical point. Previous neutron diffraction studies indicated that a tricritical point...

The Hagedorn spectrum, nuclear level densities and first order phase transitions

Energy Technology Data Exchange (ETDEWEB)

Moretto, Luciano G., E-mail: lgmoretto@lbl.gov [Department of Chemistry, University of California, Berkeley, Lawrence Berkeley National Laboratory 1 Cyclotron Road, Berkeley, CA 94720 (United States); Larsen, A. C.; Guttormsen, M.; Siem, S. [Department of Physics, University of Oslo, N-0316 Oslo (Norway)

2015-10-15

An exponential mass spectrum, like the Hagedorn spectrum, with slope 1/T{sub H} was interpreted as fixing an upper limiting temperature T{sub H} that the system can achieve. However, thermodynamically, such spectrum indicates a 1{sup st} order phase transition at a fixed temperature T{sub H}. A much lower energy example is the log linear level nuclear density below the neutron binding energy that prevails throughout the nuclear chart. We show that, for non-magic nuclei, such linearity implies a 1{sup st} order phase transition from the pairing superfluid to an ideal gas of quasi particles.

Analysis and development of fourth order LCLC resonant based capacitor charging power supply for pulse power applications.

Science.gov (United States)

Naresh, P; Hitesh, C; Patel, A; Kolge, T; Sharma, Archana; Mittal, K C

2013-08-01

A fourth order (LCLC) resonant converter based capacitor charging power supply (CCPS) is designed and developed for pulse power applications. Resonant converters are preferred t utilize soft switching techniques such as zero current switching (ZCS) and zero voltage switching (ZVS). An attempt has been made to overcome the disadvantages in 2nd and 3rd resonant converter topologies; hence a fourth order resonant topology is used in this paper for CCPS application. In this paper a novel fourth order LCLC based resonant converter has been explored and mathematical analysis carried out to calculate load independent constant current. This topology provides load independent constant current at switching frequency (fs) equal to resonant frequency (fr). By changing switching condition (on time and dead time) this topology has both soft switching techniques such as ZCS and ZVS for better switching action to improve the converter efficiency. This novel technique has special features such as low peak current through switches, DC blocking for transformer, utilizing transformer leakage inductance as resonant component. A prototype has been developed and tested successfully to charge a 100 μF capacitor to 200 V.

Phase transitions in dense matter

Science.gov (United States)

Dexheimer, Veronica; Hempel, Matthias; Iosilevskiy, Igor; Schramm, Stefan

2017-11-01

As the density of matter increases, atomic nuclei disintegrate into nucleons and, eventually, the nucleons themselves disintegrate into quarks. The phase transitions (PT's) between these phases can vary from steep first order to smooth crossovers, depending on certain conditions. First-order PT's with more than one globally conserved charge, so-called non-congruent PT's, have characteristic differences compared to congruent PT's. In this conference proceeding we discuss the non-congruence of the quark deconfinement PT at high densities and/or temperatures relevant for heavy-ion collisions, neutron stars, proto-neutron stars, supernova explosions, and compact-star mergers.

The second workshop on phase separation with ordering

International Nuclear Information System (INIS)

Osamura, K.; Furusaka, M.

1993-04-01

The second workshop on phase separation with ordering was held at the seminar room of Booster, National Laboratory for High Energy Physics, KEK, Tsukuba, in March 16-17, 1992. 31 participants attended this meeting. The structure and its dynamical change were discussed mainly in the experimental viewpoint, and the theories have been developed and the results of simulation were reported. (J.P.N.) 115 refs

Three-charge black holes on a circle

International Nuclear Information System (INIS)

Harmark, Troels; Obers, Niels A.; Roenne, Peter B.; Kristjansson, Kristjan R.

2007-01-01

We study phases of five-dimensional three-charge black holes with a circle in their transverse space. In particular, when the black hole is localized on the circle we compute the corrections to the metric and corresponding thermodynamics in the limit of small mass. When taking the near-extremal limit, this gives the corrections to the finite entropy of the extremal three-charge black hole as a function of the energy above extremality. For the partial extremal limit with two charges sent to infinity and one finite we show that the first correction to the entropy is in agreement with the microscopic entropy by taking into account that the number of branes shift as a consequence of the interactions across the transverse circle. Beyond these analytical results, we also numerically obtain the entire phase of non- and near-extremal three- and two-charge black holes localized on a circle. More generally, we find in this paper a rich phase structure, including a new phase of three-charge black holes that are non-uniformly distributed on the circle. All these three-charge black hole phases are found via a map that relates them to the phases of five-dimensional neutral Kaluza-Klein black holes

Stability of charge and orbital order in half-doped Y{sub 0.5}Ca{sub 0.5}MnO{sub 3} nanocrystallites

Energy Technology Data Exchange (ETDEWEB)

Chowdhury, Putul Malla, E-mail: putularun@gmail.com; Ghosh, Barnali, E-mail: barnali@bose.res.in; Raychaudhuri, A. K., E-mail: arup@bose.res.in [S N Bose National Centre for Basic Sciences, Unit for Nano Science, Department of Condensed Matter Physics and Materials Science (India); Kaushik, S. D.; Siruguri, V. [UGC-DAE Consortium for Scientific Research Mumbai Centre, R-5 Shed, Bhabha Atomic Research Centre (India)

2013-04-15

In this paper, we report a detailed study of the structure, magnetic, and electrical transport properties in nanocrystallites of hole-doped manganite Y{sub 0.5}Ca{sub 0.5}MnO{sub 3}, with the aim to study the effect of size reduction on the stability of the charge-orbital order and the antiferromagnetic spin order that are seen in the bulk samples of the half-doped manganite. The investigations have been done in the general context of investigating how size reduction affects competing interactions in complex oxides and thus, changes their ground state. The bulk sample of the material (average crystallite size {approx}1 {mu}m), with the smallest radius of the cation in A-site (Y), shows a robust charge and orbital ordered insulating state below the transition temperature near 290 K and an antiferromagnetic spin order at 110 K. The experiments carried out on well-characterized nanocrystalline samples, with average crystallite sizes down to 75 nm, establish that the size reduction changes the structural parameters, and the charge and orbital ordering are suppressed. However, the antiferromagnetic spin order (as revealed by neutron diffraction experiments carried out down to 2 K) persists in the nanocrystallites and co-exists with ferromagnetic order below 110 K. The nanocrystalline samples have significant lower resistivities (by few orders) compared to those of the bulk samples in the temperature range 10-300 K. This corroborates the formation of the ferromagnetic moments in the nanocrystallites.

Direct observation of the bandwidth-disorder induced variation of charge/orbital ordering structure in RE0.5(Ca1-ySry)1.5MnO4

International Nuclear Information System (INIS)

Yu, X Z; Arima, T; Kaneko, Y; He, J P; Mathieu, R; Asaka, T; Hara, T; Kimoto, K; Matsui, Y; Tokura, Y

2007-01-01

Changes in the charge/orbital ordering (CO/OO) structure with the bandwidth of the e g band and quenched disorder were investigated in doped manganites RE 0.5 (Ca 1-y Sr y ) 1.5 MnO 4 (RE = Pr,Eu) with a single-layer perovskite structure. A systematic study of the modulation structure associated with the CO/OO phase demonstrated that the long-range commensurate structure changes to a short-range incommensurate structure with increasing Sr content through the enhancement of the bandwidth and quenched disorder in these systems. At the same time, the transition temperature of CO/OO (T CO/OO ) decreases. Changes in structure and T CO/OO with different A-site combinations reveal that the CO/OO phase is strongly suppressed by the widening of the e g band and the stronger quenched disorder in these layered manganites. (fast track communication)

Phase transition and hysteresis in a rechargeable lithium battery

Energy Technology Data Exchange (ETDEWEB)

Dreyer, Wolfgang [Weierstrass-Institut fuer Angewandte Analysis und Stochastik (WIAS) im Forschungsverbund Berlin e.V. (Germany); Gaberscek, Miran; Jamnik, Janko [Kemijski Institut Ljubljana Slovenija (Slovenia). L10 Lab. for Materials Electrochemistry

2007-07-01

We develop a model which describes the evolution of a phase transition that occurs in some part of a rechargeable lithium battery during the process of charging/discharging. The model is capable to simulate hysteretic behavior of the voltage - charge characteristics. During discharging of the battery, the interstitial lattice sites of a small crystalline host system are filled up with lithium atoms and these are released again during charging. We show within the context of a sharp interface model that two mechanical phenomena go along with a phase transition that appears in the host system during supply and removal of lithium. At first the lithium atoms need more space than it is available by the interstitial lattice sites, which leads to a maximal relative change of the crystal volume of about 6%. Furthermore there is an interface between two adjacent phases that has very large curvature of the order of magnitude 100 m, which evoke here a discontinuity of the normal component of the stress. In order to simulate the dynamics of the phase transitions and in particular the observed hysteresis we establish a new initial and boundary value problem for a nonlinear PDE system that can be reduced in some limiting case to an ODE system. (orig.)

Charged dust in planetary magnetospheres: Hamiltonian dynamics and numerical simulations for highly charged grains

Science.gov (United States)

Schaffer, L.; Burns, J. A.

1994-01-01

We use a combination of analytical and numerical methods to investigate the dynamics of charged dust grains in planetary magnetospheres. Our emphasis is on obtaining results valid for particles that are not necessarily dominated either by gravitational or electromagnetic forces. A Hamiltonian formulation of the problem yields exact results, for all values of charge-to-mass ratio, when we introduce two constraints: particles remain in the equatorial plane and the magnetic field is taken as axially symmetric. In particular, we obtain locations of equilibrium points, the frequencies of stable periodic orbits, the topology of separatrices in phase space, and the rate of longitudinal drift. These results are significant for specific applications: motion in the nearly aligned dipolar field of Saturn, and the trajectories of arbitrarily charged particles in complex magnetic fields for limited periods of time after ejection from parent bodies. Since the model is restrictive, we also use numerical integrations of the full three-dimensional equations of motion and illustrate under what conditions the constrained problem yields reasonable results. We show that a large fraction of the intermediately charged and highly charged (gyrating) particles will always be lost to a planet's atmosphere within a few hundred hours, for motion through tilted-dipole magnetic fields. We find that grains must have a very high charge-to-mass ratio in order to be mirrored back to the ring plane. Thus, except perhaps at Saturn where the dipole tilt is very small, the likely inhabitants of the dusty ring systems are those particles that are either nearly Keplerian (weakly charged) grains or grains whose charges place them in the lower end of the intermediate charge zone. Fianlly, we demonstrate the effect of plasma drag on the orbits of gyrating particles to be a rapid decrease in gyroradius followed by a slow radial evolution of the guiding center.

A first order phase transition from inflationary to big bang universe

International Nuclear Information System (INIS)

Horwitz, G.

1986-01-01

The microcanonical entropy is calculated for a system of massive, conformally coupled, scalar bosons using a conformal gravitational theory. The resulting entropy is seen to indicate a first order phase transition from an inflationary expansion stage (where the amplitude of the scalar boson follows that of the scale function of the universe and the mass of the solar boson is the source of the cosmological constant) to a big bang stage (where neither of these conditions hold). Such a first order phase transition involves an entropy increase of some thirty orders of magnitude. In the author's theory, the invariant temperature (proper temperature times scale function) is not zero, nor is it the Hawking temperature, but it is tens of magnitudes smaller than the corresponding temperature of the big bang stage. A specific model for these bosons that provides the phase transition and serves as the source of the cosmological constant is also examined briefly, where the bosons are identified as spontaneously generated primordial black holes as in the cosmological model of Brout, Englert and Casher. In that case, the decay of the black holes provides a decaying cosmological constant and an explicit mechanism for heating up the universe

Two-order parameters theory of the metal-insulator phase transition kinetics in the magnetic field

Science.gov (United States)

Dubovskii, L. B.

2018-05-01

The metal-insulator phase transition is considered within the framework of the Ginzburg-Landau approach for the phase transition described with two coupled order parameters. One of the order parameters is the mass density which variation is responsible for the origin of nonzero overlapping of the two different electron bands and the appearance of free electron carriers. This transition is assumed to be a first-order phase one. The free electron carriers are described with the vector-function representing the second-order parameter responsible for the continuous phase transition. This order parameter determines mostly the physical properties of the metal-insulator transition and leads to a singularity of the surface tension at the metal-insulator interface. The magnetic field is involved into the consideration of the system. The magnetic field leads to new singularities of the surface tension at the metal-insulator interface and results in a drastic variation of the phase transition kinetics. A strong singularity in the surface tension results from the Landau diamagnetism and determines anomalous features of the metal-insulator transition kinetics.

Diffusionless phase transition with two order parameters in spin-crossover solids

Energy Technology Data Exchange (ETDEWEB)

Gudyma, Iurii, E-mail: yugudyma@gmail.com; Ivashko, Victor [Department of General Physics, Chernivtsi National University, 58012 Chernivtsi (Ukraine); Linares, Jorge [Groupe d' Etude de la Matière Condensée (GEMAC), UMR 8635, CNRS, Université de Versailles Saint Quentin, 45 avenue des Etats-Unis, 78035 Versailles (France)

2014-11-07

The quantitative analysis of the interface boundary motion between high-spin and low-spin phases is presented. The nonlinear effect of the switching front rate on the temperature is shown. A compressible model of spin-crossover solid is studied in the framework of the Ising-like model with two-order parameters under statistical approach, where the effect of elastic strain on interaction integral is considered. These considerations led to examination of the relation between the order parameters during temperature changes. Starting from the phenomenological Hamiltonian, entropy has been derived using the mean field approach. Finally, the phase diagram, which characterizes the system, is numerically analyzed.

Phase domain structures in cylindrical magnets under conditions of a first-order magnetic phase transition

International Nuclear Information System (INIS)

Dzhezherya, Yu.I.; Klymuk, O.S.

2011-01-01

The magnetic and resonance properties of cylindrical magnets at first-order phase transition from paramagnetic to ferromagnetic state were theoretically studied. It has been shown that in the external magnetic field directed perpendicularly to the rotation axis, formation of a specific domain structure of paramagnetic and ferromagnetic layers can be energetically favorable. The parameters of cylindrical phase domains as well as their dependences on temperature, magnetic field and material characteristics have been calculated. Peculiarities of the magnetic resonance spectra appearing as a result of the phase domain formation have been considered. Dependence of the resonance field of the system of ferromagnetic domains on magnetization and temperature has been obtained. - Highlights: → Parameters of the equilibrium system of cylindrical phase domains are calculated. → The range of fields for PM and FM phases coexistence is found. → FMR field of the disk domains is found to be lower than that of the PMR field.→ The resonance field increases with the decrease of temperature lower than T || .

Current Flow in the Bubble and Stripe Phases

Science.gov (United States)

Friess, B.; Umansky, V.; von Klitzing, K.; Smet, J. H.

2018-03-01

The spontaneous ordering of spins and charges in geometric patterns is currently under scrutiny in a number of different material systems. A topic of particular interest is the interaction of such ordered phases with itinerant electrons driven by an externally imposed current. It not only provides important information on the charge ordering itself but potentially also allows manipulating the shape and symmetry of the underlying pattern if current flow is strong enough. Unfortunately, conventional transport methods probing the macroscopic resistance suffer from the fact that the voltage drop along the sample edges provides only indirect information on the bulk properties because a complex current distribution is elicited by the inhomogeneous ground state. Here, we promote the use of surface acoustic waves to study these broken-symmetry phases and specifically address the bubble and stripe phases emerging in high-quality two-dimensional electron systems in GaAs /AlGaAs heterostructures as prototypical examples. When driving a unidirectional current, we find a surprising discrepancy between the sound propagation probing the bulk of the sample and the voltage drop along the sample edges. Our results prove that the current-induced modifications observed in resistive transport measurements are in fact a local phenomenon only, leaving the majority of the sample unaltered. More generally, our findings shed new light on the extent to which these ordered electron phases are impacted by an external current and underline the intrinsic advantages of acoustic measurements for the study of such inhomogeneous phases.

Tunability of Open-Shell Character, Charge Asymmetry, and Third-Order Nonlinear Optical Properties of Covalently Linked (Hetero)Phenalenyl Dimers.

Science.gov (United States)

Minamida, Yuka; Kishi, Ryohei; Fukuda, Kotaro; Matsui, Hiroshi; Takamuku, Shota; Yamane, Masaki; Tonami, Takayoshi; Nakano, Masayoshi

2018-02-06

Tunability of the open-shell character, charge asymmetry, and third-order nonlinear optical (NLO) properties of covalently linked (hetero)phenalenyl dimers are investigated by using the density functional theory method. By changing the molecular species X and substitution position (i, j) for the linker part, a variety of intermonomer distances R and relative alignments between the phenalenyl dimers can be realized from the geometry optimizations, resulting in a wide-range tuning of diradical character y and charge asymmetry. It is found that the static second hyperpolarizabilities along the stacking direction, γ yyyy , are one-order enhanced for phenalenyl dimer systems exhibiting intermediate y, a feature that is in good agreement with the "y-γ correlation". By replacing the central carbon atoms of the phenalenyl rings with a boron or a nitrogen, we have also designed covalently linked heterophenalenyl dimers. The introduction of such a charge asymmetry to the open-shell systems, which leads to closed-shell ionic ground states, is found to further enhance the γ yyyy values of the systems having longer intermonomer distance R with intermediate ionic character, that is, charge asymmetry. The present results demonstrate a promising potential of covalently linked NLO dimers with intermediate open-shell/ionic characters as a new building block of highly efficient NLO systems. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Ultracold Atoms in a Square Lattice with Spin-Orbit Coupling: Charge Order, Superfluidity, and Topological Signatures

Science.gov (United States)

Rosenberg, Peter; Shi, Hao; Zhang, Shiwei

2017-12-01

We present an ab initio, numerically exact study of attractive fermions in square lattices with Rashba spin-orbit coupling. The ground state of this system is a supersolid, with coexisting charge and superfluid order. The superfluid is composed of both singlet and triplet pairs induced by spin-orbit coupling. We perform large-scale calculations using the auxiliary-field quantum Monte Carlo method to provide the first full, quantitative description of the charge, spin, and pairing properties of the system. In addition to characterizing the exotic physics, our results will serve as essential high-accuracy benchmarks for the intense theoretical and especially experimental efforts in ultracold atoms to realize and understand an expanding variety of quantum Hall and topological superconductor systems.

Thermal conductivity of solid cyclohexane in orientationally ordered and disordered phases

International Nuclear Information System (INIS)

Konstantinov, V. A.; Revyakin, V. P.; Sagan, V. V.; Pursky, O. I.; Sysoev, V. M.

2011-01-01

Thermal conductivity Λ P of solid cyclohexane is measured at a pressure P = 0.1 MPa in the temperature range from 80 K to the melting point, which covers the ranges of low-temperature orientationally ordered phase II and high-temperature orientationally disordered phase I. Thermal conductivity Λ V is measured at a constant volume in orientationally disordered phase I. The thermal conductivity measured at atmospheric pressure decreases with increasing temperature as Λ P ∝ T −1.15 in phase II, whereas Λ P ∝ T −0.3 in phase I. As temperature increases, isochoric thermal conductivity Λ V in phase I increases gradually. The experimental data are described in terms of a modified Debye model of thermal conductivity with allowance for heat transfer by both phonons and “diffuse” modes.

An ordered metallic glass solid solution phase that grows from the melt like a crystal

International Nuclear Information System (INIS)

Chapman, Karena W.; Chupas, Peter J.; Long, Gabrielle G.; Bendersky, Leonid A.; Levine, Lyle E.; Mompiou, Frédéric; Stalick, Judith K.; Cahn, John W.

2014-01-01

We report structural studies of an Al–Fe–Si glassy solid that is a solid solution phase in the classical thermodynamic sense. We demonstrate that it is neither a frozen melt nor nanocrystalline. The glass has a well-defined solubility limit and rejects Al during formation from the melt. The pair distribution function of the glass reveals chemical ordering out to at least 12 Å that resembles the ordering within a stable crystalline intermetallic phase of neighboring composition. Under isothermal annealing at 305 °C the glass first rejects Al, then persists for approximately 1 h with no detectable change in structure, and finally is transformed by a first-order phase transition to a crystalline phase with a structure that is different from that within the glass. It is possible that this remarkable glass phase has a fully ordered atomic structure that nevertheless possesses no long-range translational symmetry and is isotropic

Extension of the self-consistent-charge density-functional tight-binding method: third-order expansion of the density functional theory total energy and introduction of a modified effective coulomb interaction.

Science.gov (United States)

Yang, Yang; Yu, Haibo; York, Darrin; Cui, Qiang; Elstner, Marcus

2007-10-25

The standard self-consistent-charge density-functional-tight-binding (SCC-DFTB) method (Phys. Rev. B 1998, 58, 7260) is derived by a second-order expansion of the density functional theory total energy expression, followed by an approximation of the charge density fluctuations by charge monopoles and an effective damped Coulomb interaction between the atomic net charges. The central assumptions behind this effective charge-charge interaction are the inverse relation of atomic size and chemical hardness and the use of a fixed chemical hardness parameter independent of the atomic charge state. While these approximations seem to be unproblematic for many covalently bound systems, they are quantitatively insufficient for hydrogen-bonding interactions and (anionic) molecules with localized net charges. Here, we present an extension of the SCC-DFTB method to incorporate third-order terms in the charge density fluctuations, leading to chemical hardness parameters that are dependent on the atomic charge state and a modification of the Coulomb scaling to improve the electrostatic treatment within the second-order terms. These modifications lead to a significant improvement in the description of hydrogen-bonding interactions and proton affinities of biologically relevant molecules.

Spin excitations in the quasi-two-dimensional charge-ordered insulator α -(BEDT-TTF ) 2I3 probed via 13C NMR

Science.gov (United States)

Ishikawa, Kyohei; Hirata, Michihiro; Liu, Dong; Miyagawa, Kazuya; Tamura, Masafumi; Kanoda, Kazushi

2016-08-01

The spin excitations from the nonmagnetic charge-ordered insulating state of α -(BEDT-TTF ) 2I3 at ambient pressure have been investigated by probing the static and low-frequency dynamic spin susceptibilities via site-selective nuclear magnetic resonance at 13C sites. The site-dependent values of the shift and the spin-lattice relaxation rate 1 /T1 below the charge-ordering transition temperature (TCO≈135 K ) demonstrate a spin density imbalance in the unit cell, in accord with the charge-density ratio reported earlier. The shift and 1 /T1 show activated temperature dependence with a static (shift) gap ΔS≈47 -52 meV and a dynamic (1 /T1 ) gap ΔR≈40 meV . The sizes of the gaps are well described in terms of a localized spin model, where spin-1/2 antiferromagnetic dimer chains are weakly coupled with each other.

Impact of charge-transfer excitons in regioregular polythiophene on the charge separation at polythiophene-fullerene heterojunctions

Science.gov (United States)

Polkehn, M.; Tamura, H.; Burghardt, I.

2018-01-01

This study addresses the mechanism of ultrafast charge separation in regioregular oligothiophene-fullerene assemblies representative of poly-3-hexylthiophene (P3HT)-[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) heterojunctions, with special emphasis on the inclusion of charge transfer excitons in the oligothiophene phase. The formation of polaronic inter-chain charge separated species in highly ordered oligothiophene has been demonstrated in recent experiments and could have a significant impact on the net charge transfer to the fullerene acceptor. The present approach combines a first-principles parametrized multi-site Hamiltonian, based on time-dependent density functional theory calculations, with accurate quantum dynamics simulations using the multi-layer multi-configuration time-dependent Hartree method. Quantum dynamical studies are carried out for up to 182 electronic states and 112 phonon modes. The present analysis follows up on our previous study of (Huix-Rotllant et al 2015 J. Phys. Chem. Lett. 6 1702) and significantly expands the scope of this analysis by including the dynamical role of charge transfer excitons. Our investigation highlights the pronounced mixing of photogenerated Frenkel excitons with charge transfer excitons in the oligothiophene domain, and the opening of new transfer channels due the creation of such charge-separated species. As a result, it turns out that the interfacial donor/acceptor charge transfer state can be largely circumvented due to the presence of charge transfer excitons. However, the latter states in turn act as a trap, such that the free carrier yield observed on ultrafast time scales is tangibly reduced. The present analysis underscores the complexity of the transfer pathways at P3HT-PCBM type junctions.

QCD-Electroweak First-Order Phase Transition in a Supercooled Universe

Science.gov (United States)

Iso, Satoshi; Serpico, Pasquale D.; Shimada, Kengo

2017-10-01

If the electroweak sector of the standard model is described by classically conformal dynamics, the early Universe evolution can be substantially altered. It is already known that—contrarily to the standard model case—a first-order electroweak phase transition may occur. Here we show that, depending on the model parameters, a dramatically different scenario may happen: A first-order, six massless quark QCD phase transition occurs first, which then triggers the electroweak symmetry breaking. We derive the necessary conditions for this dynamics to occur, using the specific example of the classically conformal B -L model. In particular, relatively light weakly coupled particles are predicted, with implications for collider searches. This scenario is also potentially rich in cosmological consequences, such as renewed possibilities for electroweak baryogenesis, altered dark matter production, and gravitational wave production, as we briefly comment upon.

QCD-Electroweak First-Order Phase Transition in a Supercooled Universe.

Science.gov (United States)

Iso, Satoshi; Serpico, Pasquale D; Shimada, Kengo

2017-10-06

If the electroweak sector of the standard model is described by classically conformal dynamics, the early Universe evolution can be substantially altered. It is already known that-contrarily to the standard model case-a first-order electroweak phase transition may occur. Here we show that, depending on the model parameters, a dramatically different scenario may happen: A first-order, six massless quark QCD phase transition occurs first, which then triggers the electroweak symmetry breaking. We derive the necessary conditions for this dynamics to occur, using the specific example of the classically conformal B-L model. In particular, relatively light weakly coupled particles are predicted, with implications for collider searches. This scenario is also potentially rich in cosmological consequences, such as renewed possibilities for electroweak baryogenesis, altered dark matter production, and gravitational wave production, as we briefly comment upon.

Hopf bifurcation and chaos in a third-order phase-locked loop

Science.gov (United States)

Piqueira, José Roberto C.

2017-01-01

Phase-locked loops (PLLs) are devices able to recover time signals in several engineering applications. The literature regarding their dynamical behavior is vast, specifically considering that the process of synchronization between the input signal, coming from a remote source, and the PLL local oscillation is robust. For high-frequency applications it is usual to increase the PLL order by increasing the order of the internal filter, for guarantying good transient responses; however local parameter variations imply structural instability, thus provoking a Hopf bifurcation and a route to chaos for the phase error. Here, one usual architecture for a third-order PLL is studied and a range of permitted parameters is derived, providing a rule of thumb for designers. Out of this range, a Hopf bifurcation appears and, by increasing parameters, the periodic solution originated by the Hopf bifurcation degenerates into a chaotic attractor, therefore, preventing synchronization.

Visible and dark matter from a first-order phase transition in a baryon-symmetric universe

International Nuclear Information System (INIS)

Petraki, Kalliopi; Volkas, Raymond R.; Trodden, Mark

2012-01-01

The similar cosmological abundances observed for visible and dark matter suggest a common origin for both. By viewing the dark matter density as a dark-sector asymmetry, mirroring the situation in the visible sector, we show that the visible and dark matter asymmetries may have arisen simultaneously through a first-order phase transition in the early universe. The dark asymmetry can then be equal and opposite to the usual visible matter asymmetry, leading to a universe that is symmetric with respect to a generalised baryon number. We present both a general structure, and a precisely defined example of a viable model of this type. In that example, the dark matter is ''atomic'' as well as asymmetric, and various cosmological and astrophysical constraints are derived. Testable consequences for colliders include a Z' boson that couples through the B−L charge to the visible sector, but also decays invisibly to dark sector particles. The additional scalar particles in the theory can mix with the standard Higgs boson and provide other striking signatures

Implication of b → sγ for CP violation in charged scalar exchange

International Nuclear Information System (INIS)

Grossman, Y.; Nir, Y.

1993-06-01

In model of three or more scalar doublets, new CP violating phases appear in charged scalar exchange. These phases affect CP asymmetries in natural B decay, even is Natural Flavor Conservation holds. The recent upper bound on the decay b → sγ constraints the effect to be at most of order a few percent. Modifications of constraints on CKM parameters open an interesting new region in the sin 2α - sin 2 β plane even in the absence of new phases. (authors)

Geometric Phase of the Gyromotion for Charged Particles in a Time-dependent Magnetic Field

International Nuclear Information System (INIS)

Liu, Jian; Qin, Hong

2011-01-01

We study the dynamics of the gyrophase of a charged particle in a magnetic field which is uniform in space but changes slowly with time. As the magnetic field evolves slowly with time, the changing of the gyrophase is composed of two parts. The rst part is the dynamical phase, which is the time integral of the instantaneous gyrofrequency. The second part, called geometric gyrophase, is more interesting, and it is an example of the geometric phase which has found many important applications in different branches of physics. If the magnetic field returns to the initial value after a loop in the parameter space, then the geometric gyrophase equals the solid angle spanned by the loop in the parameter space. This classical geometric gyrophase is compared with the geometric phase (the Berry phase) of the spin wave function of an electron placed in the same adiabatically changing magnetic field. Even though gyromotion is not the classical counterpart of the quantum spin, the similarities between the geometric phases of the two cases nevertheless reveal the similar geometric nature of the different physics laws governing these two physics phenomena.

New theory for competing interactions and microstructures in partially-ordered (liquid-crystalline) phases

International Nuclear Information System (INIS)

Dowell, F.

1987-01-01

A summary of results from a unique statistical-physics theory to predict and explain competing interactions and resulting microstructures in some partially-ordered [in this case, liquid-crystalline (LC)] phases is presented. The static aspects of both partial orientational and partial positional ordering of the molecules into various microstructures in these phases (including the incommensurate smectic-Ad phase) can be understood in terms of various competing interactions (both entropic and energetic) involved in the packing together of the different molecular sub-units at given pressures and temperatures. These microstructures are predicted and explained (using no ad hoc or arbitrarily adjustable parameter) as a function of molecule chemical structure [including lengths and shapes (from bond lengths and angles), intramolecular rotations, site-site polarizabilities and pair potentials, dipole moments, etc]. Theoretical results are presented for the nematic, re-entrant nematic, smectic-Ad, and smectic-Al LC phases and the isotropic phase

Study of Charge Carrier Transport in GaN Sensors

Science.gov (United States)

Gaubas, Eugenijus; Ceponis, Tomas; Kuokstis, Edmundas; Meskauskaite, Dovile; Pavlov, Jevgenij; Reklaitis, Ignas

2016-01-01

Capacitor and Schottky diode sensors were fabricated on GaN material grown by hydride vapor phase epitaxy and metal-organic chemical vapor deposition techniques using plasma etching and metal deposition. The operational characteristics of these devices have been investigated by profiling current transients and by comparing the experimental regimes of the perpendicular and parallel injection of excess carrier domains. Profiling of the carrier injection location allows for the separation of the bipolar and the monopolar charge drift components. Carrier mobility values attributed to the hydride vapor phase epitaxy (HVPE) GaN material have been estimated as μe = 1000 ± 200 cm2/Vs for electrons, and μh = 400 ± 80 cm2/Vs for holes, respectively. Current transients under injection of the localized and bulk packets of excess carriers have been examined in order to determine the surface charge formation and polarization effects. PMID:28773418

Experimental Evidence for Static Charge Density Waves in Iron Oxypnictides

KAUST Repository

Martinelli, A.; Manfrinetti, P.; Provino, A.; Genovese, Alessandro; Caglieris, F.; Lamura, G.; Ritter, C.; Putti, M.

2017-01-01

In this Letter we report high-resolution synchrotron x-ray powder diffraction and transmission electron microscope analysis of Mn-substituted LaFeAsO samples, demonstrating that a static incommensurate modulated structure develops across the low-temperature orthorhombic phase, whose modulation wave vector depends on the Mn content. The incommensurate structural distortion is likely originating from a charge-density-wave instability, a periodic modulation of the density of conduction electrons associated with a modulation of the atomic positions. Our results add a new component in the physics of Fe-based superconductors, indicating that the density wave ordering is charge driven.

Experimental Evidence for Static Charge Density Waves in Iron Oxypnictides

KAUST Repository

Martinelli, A.

2017-02-01

In this Letter we report high-resolution synchrotron x-ray powder diffraction and transmission electron microscope analysis of Mn-substituted LaFeAsO samples, demonstrating that a static incommensurate modulated structure develops across the low-temperature orthorhombic phase, whose modulation wave vector depends on the Mn content. The incommensurate structural distortion is likely originating from a charge-density-wave instability, a periodic modulation of the density of conduction electrons associated with a modulation of the atomic positions. Our results add a new component in the physics of Fe-based superconductors, indicating that the density wave ordering is charge driven.

Models for Master-Slave Clock Distribution Networks with Third-Order Phase-Locked Loops

OpenAIRE

Piqueira, José Roberto Castilho; de Carvalho Freschi, Marcela

2007-01-01

The purpose of this work is to study the processing and transmission of clock signals in networks of geographically distributed nodes, in order to derive conditions for frequency and phase synchronization between the nodes. The focus is on the master-slave architecture, which presents a priority scheme of clock distribution. One-way master-slave (OWMS ) and two-way master-slave (TWMS) chains are studied, considering that the slave nodes are third-order phase-locked loops...

Local Symmetry and Domain Patterns: Ordering Phenomena in Transition-Metal Oxides

OpenAIRE

Buchholz, Marcel

2013-01-01

Transition-metal oxides (TMOs) show rich phase diagrams with various magnetic and electronic phases that arise from the complex interplay between spin, charge, orbital, and lattice degrees of freedom. The most prominent class of materials, which has attracted a lot of attention in the last decades, are probably high-temperature superconductors (HTS), in which the resitivity drops to zero below a critical temperature. Further examples are different kind of complex ordering phenomena, for examp...

Charge density wave fluctuations in La{sub 2-x}Sr{sub x}CuO{sub 4} and their competition with superconductivity

Energy Technology Data Exchange (ETDEWEB)

Croft, Thomas; Lester, Christopher; Hayden, Stephen [H.H. Wills Physics Laboratory, University of Bristol (United Kingdom); Bombardi, Alessandro; Senn, Mark [Diamond Light Source Ltd., Harwell Science and Innovation Campus, Didcot, Oxfordshire (United Kingdom)

2015-07-01

The recent observations of charge and stripe correlations in YBa{sub 2}Cu{sub 3}O{sub 6+x} and La{sub 2-x}Ba{sub x}CuO{sub 4} has reinvigorated interest in their role in influencing the superconductivity of the cuprates. However, structural complications of these systems makes it difficult to isolate the effect the lattice has in inducing the charge order. Here, we report hard X-ray diffraction measurements on three compositions (x=0.11,0.12,0.13) of the high-temperature superconductor La{sub 2-x}Sr{sub x}CuO{sub 4}, a canonical example of HTS with T{sub c} ∼ 35 K and a simple crystal structure. All samples show charge-density-wave (CDW) order with onset temperatures in the range 51-80 K and ordering wavevectors close to (0.23,0,0.5). We present a phase diagram of La{sub 2-x}Sr{sub x}CuO{sub 4} including the pseudogap phase, CDW and magnetic order.

Ordered phase and non-equilibrium fluctuation in stock market

Science.gov (United States)

Maskawa, Jun-ichi

2002-08-01

We analyze the statistics of daily price change of stock market in the framework of a statistical physics model for the collective fluctuation of stock portfolio. In this model the time series of price changes are coded into the sequences of up and down spins, and the Hamiltonian of the system is expressed by spin-spin interactions as in spin glass models of disordered magnetic systems. Through the analysis of Dow-Jones industrial portfolio consisting of 30 stock issues by this model, we find a non-equilibrium fluctuation mode on the point slightly below the boundary between ordered and disordered phases. The remaining 29 modes are still in disordered phase and well described by Gibbs distribution. The variance of the fluctuation is outlined by the theoretical curve and peculiarly large in the non-equilibrium mode compared with those in the other modes remaining in ordinary phase.

Thermally coupled moving boundary model for charge-discharge of LiFePO4/C cells

Science.gov (United States)

Khandelwal, Ashish; Hariharan, Krishnan S.; Gambhire, Priya; Kolake, Subramanya Mayya; Yeo, Taejung; Doo, Seokgwang

2015-04-01

Optimal thermal management is a key requirement in commercial utilization of lithium ion battery comprising of phase change electrodes. In order to facilitate design of battery packs, thermal management systems and fast charging profiles, a thermally coupled electrochemical model that takes into account the phase change phenomenon is required. In the present work, an electrochemical thermal model is proposed which includes the biphasic nature of phase change electrodes, such as lithium iron phosphate (LFP), via a generalized moving boundary model. The contribution of phase change to the heat released during the cell operation is modeled using an equivalent enthalpy approach. The heat released due to phase transformation is analyzed in comparison with other sources of heat such as reversible, irreversible and ohmic. Detailed study of the thermal behavior of the individual cell components with changing ambient temperature, rate of operation and heat transfer coefficient is carried out. Analysis of heat generation in the various regimes is used to develop cell design and operating guidelines. Further, different charging protocols are analyzed and a model based methodology is suggested to design an efficient quick charging protocol.

Fourth-Order Conservative Vlasov-Maxwell Solver for Cartesian and Cylindrical Phase Space Coordinates

Science.gov (United States)

Vogman, Genia

Plasmas are made up of charged particles whose short-range and long-range interactions give rise to complex behavior that can be difficult to fully characterize experimentally. One of the most complete theoretical descriptions of a plasma is that of kinetic theory, which treats each particle species as a probability distribution function in a six-dimensional position-velocity phase space. Drawing on statistical mechanics, these distribution functions mathematically represent a system of interacting particles without tracking individual ions and electrons. The evolution of the distribution function(s) is governed by the Boltzmann equation coupled to Maxwell's equations, which together describe the dynamics of the plasma and the associated electromagnetic fields. When collisions can be neglected, the Boltzmann equation is reduced to the Vlasov equation. High-fidelity simulation of the rich physics in even a subset of the full six-dimensional phase space calls for low-noise high-accuracy numerical methods. To that end, this dissertation investigates a fourth-order finite-volume discretization of the Vlasov-Maxwell equation system, and addresses some of the fundamental challenges associated with applying these types of computationally intensive enhanced-accuracy numerical methods to phase space simulations. The governing equations of kinetic theory are described in detail, and their conservation-law weak form is derived for Cartesian and cylindrical phase space coordinates. This formulation is well known when it comes to Cartesian geometries, as it is used in finite-volume and finite-element discretizations to guarantee local conservation for numerical solutions. By contrast, the conservation-law weak form of the Vlasov equation in cylindrical phase space coordinates is largely unexplored, and to the author's knowledge has never previously been solved numerically. Thereby the methods described in this dissertation for simulating plasmas in cylindrical phase space

Cooperative photoinduced metastable phase control in strained manganite films

Science.gov (United States)

Zhang, Jingdi; Tan, Xuelian; Liu, Mengkun; Teitelbaum, S. W.; Post, K. W.; Jin, Feng; Nelson, K. A.; Basov, D. N.; Wu, Wenbin; Averitt, R. D.

2016-09-01

A major challenge in condensed-matter physics is active control of quantum phases. Dynamic control with pulsed electromagnetic fields can overcome energetic barriers, enabling access to transient or metastable states that are not thermally accessible. Here we demonstrate strain-engineered tuning of La2/3Ca1/3MnO3 into an emergent charge-ordered insulating phase with extreme photo-susceptibility, where even a single optical pulse can initiate a transition to a long-lived metastable hidden metallic phase. Comprehensive single-shot pulsed excitation measurements demonstrate that the transition is cooperative and ultrafast, requiring a critical absorbed photon density to activate local charge excitations that mediate magnetic-lattice coupling that, in turn, stabilize the metallic phase. These results reveal that strain engineering can tune emergent functionality towards proximal macroscopic states to enable dynamic ultrafast optical phase switching and control.

Measurement of the topological charge and index of vortex vector optical fields with a space-variant half-wave plate.

Science.gov (United States)

Liu, Gui-Geng; Wang, Ke; Lee, Yun-Han; Wang, Dan; Li, Ping-Ping; Gou, Fangwang; Li, Yongnan; Tu, Chenghou; Wu, Shin-Tson; Wang, Hui-Tian

2018-02-15

Vortex vector optical fields (VVOFs) refer to a kind of vector optical field with an azimuth-variant polarization and a helical phase, simultaneously. Such a VVOF is defined by the topological index of the polarization singularity and the topological charge of the phase vortex. We present a simple method to measure the topological charge and index of VVOFs by using a space-variant half-wave plate (SV-HWP). The geometric phase grating of the SV-HWP diffracts a VVOF into ±1 orders with orthogonally left- and right-handed circular polarizations. By inserting a polarizer behind the SV-HWP, the two circular polarization states project into the linear polarization and then interfere with each other to form the interference pattern, which enables the direct measurement of the topological charge and index of VVOFs.

Phase transitions in the Hubbard Hamiltonian

International Nuclear Information System (INIS)

Chaves, C.M.; Lederer, P.; Gomes, A.A.

1977-05-01

Phase transition in the isotropic non-degenerate Hubbard Hamiltonian within the renormalization group techniques is studied, using the epsilon = 4 - d expansion to first order in epsilon. The functional obtained from the Hubbard Hamiltonian displays full rotation symmetry and describes two coupled fields: a vector spin field, with n components and a non-soft scalar charge field. This coupling is pure imaginary, which has interesting consequences on the critical properties of this coupled field system. The effect of simple constraints imposed on the charge field is considered. The relevance of the coupling between the fields in producing Fisher renormalization of the critical exponents is discussed. The possible singularities introduced in the charge-charge correlation function by the coupling are also discussed

Thermodynamics of charged Lovelock: AdS black holes

International Nuclear Information System (INIS)

Prasobh, C.B.; Suresh, Jishnu; Kuriakose, V.C.

2016-01-01

We investigate the thermodynamic behavior of maximally symmetric charged, asymptotically AdS black hole solutions of Lovelock gravity. We explore the thermodynamic stability of such solutions by the ordinary method of calculating the specific heat of the black holes and investigating its divergences which signal second-order phase transitions between black hole states. We then utilize the methods of thermodynamic geometry of black hole spacetimes in order to explain the origin of these points of divergence. We calculate the curvature scalar corresponding to a Legendre-invariant thermodynamic metric of these spacetimes and find that the divergences in the black hole specific heat correspond to singularities in the thermodynamic phase space. We also calculate the area spectrum for large black holes in the model by applying the Bohr-Sommerfeld quantization to the adiabatic invariant calculated for the spacetime. (orig.)

Thermodynamics of charged Lovelock: AdS black holes

Science.gov (United States)

Prasobh, C. B.; Suresh, Jishnu; Kuriakose, V. C.

2016-04-01

We investigate the thermodynamic behavior of maximally symmetric charged, asymptotically AdS black hole solutions of Lovelock gravity. We explore the thermodynamic stability of such solutions by the ordinary method of calculating the specific heat of the black holes and investigating its divergences which signal second-order phase transitions between black hole states. We then utilize the methods of thermodynamic geometry of black hole spacetimes in order to explain the origin of these points of divergence. We calculate the curvature scalar corresponding to a Legendre-invariant thermodynamic metric of these spacetimes and find that the divergences in the black hole specific heat correspond to singularities in the thermodynamic phase space. We also calculate the area spectrum for large black holes in the model by applying the Bohr-Sommerfeld quantization to the adiabatic invariant calculated for the spacetime.

Interfacial Charge Transfer States in Condensed Phase Systems

Science.gov (United States)

Vandewal, Koen

2016-05-01

Intermolecular charge transfer (CT) states at the interface between electron-donating (D) and electron-accepting (A) materials in organic thin films are characterized by absorption and emission bands within the optical gap of the interfacing materials. CT states efficiently generate charge carriers for some D-A combinations, and others show high fluorescence quantum efficiencies. These properties are exploited in organic solar cells, photodetectors, and light-emitting diodes. This review summarizes experimental and theoretical work on the electronic structure and interfacial energy landscape at condensed matter D-A interfaces. Recent findings on photogeneration and recombination of free charge carriers via CT states are discussed, and relations between CT state properties and optoelectronic device parameters are clarified.

Phase transition in the non-degenerate Hubbard Hamiltonian

International Nuclear Information System (INIS)

Chaves, C.M.; Lederer, P.; Gomes, A.A.

1976-01-01

Phase transition in the isotropic non-degenerate Hubbard Hamiltonian within the renormalization group techniques, using the epsilon = 4 - d expansion to first order in epsilon, is studied. The functional obtained from the Hubbard Hamiltonian displays full rotation symmetry and describes two coupled fields: a vector spin field, with n components and a non-soft scalar charge field. The possibility of tricritical behavior then emerges. The effects of simple constraints imposed on the charge field is considered. The relevance of the coupling between the fields in producing Fisher renormalization of the critical exponents is discussed. The possible singularities introduced in the charge-charge correlation function by the coupling are also discussed

The influence of microstructure on charge separation dynamics in organic bulk heterojunction materials for solar cell applications

KAUST Repository

Scarongella, Mariateresa; Paraecattil, Arun Aby; Buchaca-Domingo, Ester; Douglas, Jessica D.; Beaupré , Serge; McCarthy-Ward, Thomas; Heeney, Martin J.; Moser, Jacques Edouard; Leclerc, Mario; Frechet, Jean; Stingelin, Natalie; Banerji, Natalie

2014-01-01

Light-induced charge formation is essential for the generation of photocurrent in organic solar cells. In order to gain a better understanding of this complex process, we have investigated the femtosecond dynamics of charge separation upon selective excitation of either the fullerene or the polymer in different bulk heterojunction blends with well-characterized microstructure. Blends of the pBTTT and PBDTTPD polymers with PCBM gave us access to three different scenarios: either a single intermixed phase, an intermixed phase with additional pure PCBM clusters, or a three-phase microstructure of pure polymer aggregates, pure fullerene clusters and intermixed regions. We found that ultrafast charge separation (by electron or hole transfer) occurs predominantly in intermixed regions, while charges are generated more slowly from excitons in pure domains that require diffusion to a charge generation site. The pure domains are helpful to prevent geminate charge recombination, but they must be sufficiently small not to become exciton traps. By varying the polymer packing, backbone planarity and chain length, we have shown that exciton diffusion out of small polymer aggregates in the highly efficient PBDTTPD:PCBM blend occurs within the same chain and is helped by delocalization. This journal is © the Partner Organisations 2014.

Phase transitions in local equation-of-state approximation and anomalies of spatial charge profiles in non-uniform plasma

Science.gov (United States)

Chigvintsev, A. Yu; Zorina, I. G.; Noginova, L. Yu; Iosilevskiy, I. L.

2018-01-01

Impressive appearance of discontinuities in equilibrium spatial charge profiles in non-uniform Coulomb systems is under discussions in wide number of thermoelectrostatics problems. Such discontinuities are considered as peculiar micro-level manifestation of phase transitions and intrinsic macro-level non-ideality effects in local equation of state (EOS), which should be used for description of non-ideal ionic subsystem in frames of local-density (or “pseudofluid”, or “jellium” etc) approximation. Such discontinuities were discussed already by the authors for electronic subsystems. Special emphasis is made in present paper on the mentioned above non-ideality effects in non-uniform ionic subsystems, such as micro-ions profile within screening “cloud” around macro-ion in complex (dusty, colloid etc) plasmas, equilibrium charge profile in ionic traps or (and) in the neighborhood vicinity of “charged wall” etc). Multiphase EOS for simplified ionic model of classical charged hard spheres on uniformly compressible electrostatic compensating background was constructed and several illustrative examples of discussed discontinuous ionic profiles were calculated.

Influence of High Magnetic Field and Zn Doping on Robust CO Phase of La0.5Ca0.5MnO3

Science.gov (United States)

Jin, Z.; Xia, Z. C.; Wei, M.; Yang, F.; Huang, S.; Xiao, G. L.; Shang, C.; Cheng, H.; Wu, H.; Zhang, X. X.; Ouyang, Z. W.

2017-08-01

Magnetic and electrical transport properties of La0.5Ca0.5- x Zn x MnO3 ( x = 0, 0.1, 0.15) have been investigated in a wide magnetic field range from 0 T to 50 T. Experimental results show that doping of nonmagnetic Zn2+ ion at Ca site and application of high magnetic field had obvious tuning effects on the stability of the robust charge-order phase, inducing new magnetization and electrical transport behaviors. In particular, obvious temperature and field hysteresis was induced, leading to enhanced magnetoresistance at around room temperature. Based on the intricate interplay between the external magnetic field and chemical strain (lattice distortion) induced by the dopant, which changed the bond length and the angle of double exchange and partially destroyed the charge-order phase, a weak ferromagnetic phase formed. The hysteretic behavior and enhanced magnetoresistance can be understood based on the tuning effects of the high magnetic field and dopant on the stability of the charge-order phase.

Echoes of inflationary first-order phase transitions in the CMB

Energy Technology Data Exchange (ETDEWEB)

Jiang, Hongliang, E-mail: hjiangag@connect.ust.hk [Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong Special Administrative Region (Hong Kong); Liu, Tao, E-mail: taoliu@ust.hk [Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong Special Administrative Region (Hong Kong); Sun, Sichun, E-mail: sichun@uw.edu [Jockey Club Institute for Advanced Study, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong Special Administrative Region (Hong Kong); Wang, Yi, E-mail: phyw@ust.hk [Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong Special Administrative Region (Hong Kong)

2017-02-10

Cosmological phase transitions (CPTs), such as the Grand Unified Theory (GUT) and the electroweak (EW) ones, play a significant role in both particle physics and cosmology. In this letter, we propose to probe the first-order CPTs, by detecting gravitational waves (GWs) which are generated during the phase transitions through the cosmic microwave background (CMB). If happened around the inflation era, the first-order CPTs may yield low-frequency GWs due to bubble dynamics, leaving imprints on the CMB. In contrast to the nearly scale-invariant primordial GWs caused by vacuum fluctuation, these bubble-generated GWs are scale dependent and have non-trivial B-mode spectra. If decoupled from inflaton, the EWPT during inflation may serve as a probe for the one after reheating where the baryon asymmetry could be generated via EW baryogenesis (EWBG). The CMB thus provides a potential way to test the feasibility of the EWBG, complementary to the collider measurements of Higgs potential and the direct detection of GWs generated during EWPT.

Ordering of ''ladder'' operators, the Wigner function for number and phase, and the enlarged Hilbert space

International Nuclear Information System (INIS)

Luks, A.; Perinova, V.

1993-01-01

A suitable ordering of phase exponential operators has been compared with the antinormal ordering of the annihilation and creation operators of a single mode optical field. The extended Wigner function for number and phase in the enlarged Hilbert space has been used for the derivation of the Wigner function for number and phase in the original Hilbert space. (orig.)

Charge and pairing dynamics in the attractive Hubbard model: Mode coupling and the validity of linear-response theory

Science.gov (United States)

Bünemann, Jörg; Seibold, Götz

2017-12-01

Pump-probe experiments have turned out as a powerful tool in order to study the dynamics of competing orders in a large variety of materials. The corresponding analysis of the data often relies on standard linear-response theory generalized to nonequilibrium situations. Here we examine the validity of such an approach for the charge and pairing response of systems with charge-density wave and (or) superconducting (SC) order. Our investigations are based on the attractive Hubbard model which we study within the time-dependent Hartree-Fock approximation. In particular, we calculate the quench and pump-probe dynamics for SC and charge order parameters in order to analyze the frequency spectra and the coupling of the probe field to the specific excitations. Our calculations reveal that the "linear-response assumption" is justified for small to moderate nonequilibrium situations (i.e., pump pulses) in the case of a purely charge-ordered ground state. However, the pump-probe dynamics on top of a superconducting ground state is determined by phase and amplitude modes which get coupled far from the equilibrium state indicating the failure of the linear-response assumption.

Charge ordering in amorphous WOx films

International Nuclear Information System (INIS)

Kopelevich, Yakov; Silva, Robson R. da; Rougier, Aline; Luk'yanchuk, Igor A.

2008-01-01

We observed highly anisotropic viscous electronic conducting phase in amorphous WO 1.55 films that occurs below a current (I)- and frequency (f)-dependent temperature T*(I, f). At T< T*(I, f) the rotational symmetry of randomly disordered electronic background is broken leading to the appearance of mutually perpendicular metallic- and insulating-like states. A rich dynamic behavior of the electronic matter occurring at T< T*(I, f) provides evidence for an interplay between pinning effects and electron-electron interactions. The results suggest a dynamic crystallization of the disordered electronic matter, viz. formation of sliding Wigner crystal, as well as the occurrence of quantum liquid-like crystal or stripe phase at low drives

Neutron scattering study of charge-ordering in R1/3Sr2/3FeO3 (R=La, Pr, Nd, Sm, and Y)

International Nuclear Information System (INIS)

Ma, Jie

2010-01-01

The complicated physical phenomena in complex transition-metal oxides (TMO), such as high Tc superconductivity, colossal magnetoresistivity, metal-insulator transitions, etc., have long been the focus of intense inquiry and debate in condensed matter science, since they are related to strong electronic correlations and cannot be explained within the 'standard model' of solid state physics. These novel functionalities of the correlated electron systems have a wide range of potential for applications in industry, such as information storage, energy transportation, and so on. The charge-ordering (CO) transition is very common in TMO and there is a specific CO transition temperature, TCO. Above TCO, the charge is not ordered, which means that the electrons in a compound are itinerant and the positions of the electrons are not fixed. Below TCO, the charge is ordered, which means that the electrons are localized and the positions of the electrons are settled. Hence, the electrical conductivity of a material is changed at TCO and this transition is classified as metal-insulator transition. Usually the CO with commensurate hole doping in TMO is thought to play an important role in various cases, including the superconducting cuprates, where the spin/charge stripe formation competes with superconducting states, colossal magnetoresistive manganites, where CO competes with ferromagnetic metallic state stabilized by an external magnetic field, layered nickelates, where CO takes the form of the small polaron lattices, and layered manganites, where CO could be bothered by the correlated dynamics of spins and charges. Therefore understanding the causes and implications of CO phenomena is significantly important.

Neutron scattering study of charge-ordering in R1/3Sr2/3FeO3 (R=La, Pr, Nd, Sm, and Y)

Energy Technology Data Exchange (ETDEWEB)

Ma, Jie [Iowa State Univ., Ames, IA (United States)

2010-01-01

The complicated physical phenomena in complex transition-metal oxides (TMO), such as high T_c superconductivity, colossal magnetoresistivity, metal-insulator transitions, etc., have long been the focus of intense inquiry and debate in condensed matter science, since they are related to strong electronic correlations and cannot be explained within the 'standard model' of solid state physics. These novel functionalities of the correlated electron systems have a wide range of potential for applications in industry, such as information storage, energy transportation, and so on. The charge-ordering (CO) transition is very common in TMO and there is a specific CO transition temperature, TCO. Above TCO, the charge is not ordered, which means that the electrons in a compound are itinerant and the positions of the electrons are not fixed. Below TCO, the charge is ordered, which means that the electrons are localized and the positions of the electrons are settled. Hence, the electrical conductivity of a material is changed at TCO and this transition is classified as metal-insulator transition. Usually the CO with commensurate hole doping in TMO is thought to play an important role in various cases, including the superconducting cuprates, where the spin/charge stripe formation competes with superconducting states, colossal magnetoresistive manganites, where CO competes with ferromagnetic metallic state stabilized by an external magnetic field, layered nickelates, where CO takes the form of the small polaron lattices, and layered manganites, where CO could be bothered by the correlated dynamics of spins and charges. Therefore understanding the causes and implications of CO phenomena is significantly important.

Microscopic analysis of order parameters in nuclear quantum phase transitions

International Nuclear Information System (INIS)

Li, Z. P.; Niksic, T.; Vretenar, D.; Meng, J.

2009-01-01

Microscopic signatures of nuclear ground-state shape phase transitions in Nd isotopes are studied using excitation spectra and collective wave functions obtained by diagonalization of a five-dimensional Hamiltonian for quadrupole vibrational and rotational degrees of freedom, with parameters determined by constrained self-consistent relativistic mean-field calculations for triaxial shapes. As a function of the physical control parameter, the number of nucleons, energy gaps between the ground state and the excited vibrational states with zero angular momentum, isomer shifts, and monopole transition strengths exhibit sharp discontinuities at neutron number N=90, which is characteristic of a first-order quantum phase transition.

Nano-phase separation and structural ordering in silica-rich mixed network former glasses.

Science.gov (United States)

Liu, Hao; Youngman, Randall E; Kapoor, Saurabh; Jensen, Lars R; Smedskjaer, Morten M; Yue, Yuanzheng

2018-06-13

We investigate the structure, phase separation, glass transition, and crystallization in a mixed network former glass series, i.e., B2O3-Al2O3-SiO2-P2O5 glasses with varying SiO2/B2O3 molar ratio. All the studied glasses exhibit two separate glassy phases: droplet phase (G1) with the size of 50-100 nm and matrix phase (G2), corresponding to a lower calorimetric glass transition temperature (Tg1) and a higher one (Tg2), respectively. Both Tg values decrease linearly with the substitution of B2O3 for SiO2, but the magnitude of the decrease is larger for Tg1. Based on nuclear magnetic resonance and Raman spectroscopy results, we infer that the G1 phase is rich in boroxol rings, while the G2 phase mainly involves the B-O-Si network. Both phases contain BPO4- and AlPO4-like units. Ordered domains occur in G2 upon isothermal and dynamic heating, driven by the structural heterogeneity in the as-prepared glasses. The structural ordering lowers the activation energy of crystal growth, thus promoting partial crystallization of G2. These findings are useful for understanding glass formation and phase separation in mixed network former oxide systems, and for tailoring their properties.

Entanglement and local extremes at an infinite-order quantum phase transition

International Nuclear Information System (INIS)

Rulli, C. C.; Sarandy, M. S.

2010-01-01

The characterization of an infinite-order quantum phase transition (QPT) by entanglement measures is analyzed. To this aim, we consider two closely related solvable spin-1/2 chains, namely, the Ashkin-Teller and the staggered XXZ models. These systems display a distinct pattern of eigenstates but exhibit the same thermodynamics, that is, the same energy spectrum. By performing exact diagonalization, we investigate the behavior of pairwise and block entanglement in the ground state of both models. In contrast with the XXZ chain, we show that pairwise entanglement fails in the characterization of the infinite-order QPT in the Ashkin-Teller model, although it can be achieved by analyzing the distance of the pair state from the separability boundary. Concerning block entanglement, we show that both XXZ and Ashkin-Teller models exhibit identical von Neumann entropies as long as a suitable choice of blocks is performed. Entanglement entropy is then shown to be able to identify the quantum phase diagram, even though its local extremes (either maximum or minimum) may also appear in the absence of any infinite-order QPT.

X-ray diffraction observations of a charge-density-wave order in superconducting ortho-II YBa2Cu3O6.54 single crystals in zero magnetic field

DEFF Research Database (Denmark)

Blackburn, E.; Chang, J.; Hücker, M.

2013-01-01

X-ray diffraction measurements show that the high-temperature superconductor YBa2Cu3O6.54, with ortho-II oxygen order, has charge-density-wave order in the absence of an applied magnetic field. The dominant wave vector of the charge density wave is qCDW=(0,0.328(2),0.5), with the in-plane component...

Direct interferometric measurement of the atomic dipole phase in high-order harmonic generation

International Nuclear Information System (INIS)

Chiara Corsi; Angela Pirri; Emiliano Sali

2006-01-01

Complete test of publication follows. For low gas densities and negligible ionization, the so-called atomic dipole phase, connected with the electronic dynamics involved in the generation process, is the main source of phase modulation and incoherence of high-order harmonics. To accurately determine these laser-intensity-induced phase shifts is therefore of great importance, both for the possible spectroscopic applications of harmonics and for the controlled generation of attosecond pulses. In a semiclassical description, only two electronic trajectories contribute to generate plateau harmonics during each pump optical half-cycle. Electrons appearing in the continuum by tunnel ionization may follow two different quantum paths, namely a long (l) and a short (s) trajectory before recombination. According to the SFA approximation, the harmonic of q th order acquires a phase proportional to the electronic classical action, and simply given by: ψ 0 j (r,t) -α q j I(r,t) with j = l, s where α q j are non-linear phase coefficients, roughly proportional to the time that the originating electron spends in the continuum before recombination. The space and time variation of the laser intensity (I(r,t), causes just a little phase modulation for the s-trajectory harmonic component, while the l-trajectory component becomes strongly chirped and spatially defocused; this gives rise to two spatially-separated regions having different temporal coherence. Here we report the first direct measurement of such atomic dipole phase in the process of high-order harmonic generation. Differently from previous measurements based in the most natural way, i.e., by interferometry. Two phase-locked pump pulses generate two phase-locked harmonic pulses in two nearby positions in a gas jet; one of them is used as a fixed phase reference while the generating intensity of the other is varied. The shift of the XUV interference fringes observed in the far field then gives a direct estimate of the

Analytical and experimental study of high phase order induction motors

Science.gov (United States)

Klingshirn, Eugene A.

1989-01-01

Induction motors having more than three phases were investigated to determine their suitability for electric vehicle applications. The objective was to have a motor with a current rating lower than that of a three-phase motor. The name chosen for these is high phase order (HPO) motors. Motors having six phases and nine phases were given the most attention. It was found that HPO motors are quite suitable for electric vehicles, and for many other applications as well. They have characteristics which are as good as or better than three-phase motors for practically all applications where polyphase induction motors are appropriate. Some of the analysis methods are presented, and several of the equivalent circuits which facilitate the determination of harmonic currents and losses, or currents with unbalanced sources, are included. The sometimes large stator currents due to harmonics in the source voltages are pointed out. Filters which can limit these currents were developed. An analysis and description of these filters is included. Experimental results which confirm and illustrate much of the theory are also included. These include locked rotor test results and full-load performance with an open phase. Also shown are oscillograms which display the reduction in harmonic currents when a filter is used with the experimental motor supplied by a non-sinusoidal source.

Coupling between Spin and Charge Order Driven by Magnetic Field in Triangular Ising System LuFe2O4+δ

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Lei Ding

2018-02-01

Full Text Available We present a study of the magnetic-field effect on spin correlations in the charge ordered triangular Ising system LuFe2O4+δ through single crystal neutron diffraction. In the absence of a magnetic field, the strong diffuse neutron scattering observed below the Neel temperature (TN = 240 K indicates that LuFe2O4+δ shows short-range, two-dimensional (2D correlations in the FeO5 triangular layers, characterized by the development of a magnetic scattering rod along the 1/3 1/3 L direction, persisting down to 5 K. We also found that on top of the 2D correlations, a long range ferromagnetic component associated with the propagation vector k1 = 0 sets in at around 240 K. On the other hand, an external magnetic field applied along the c-axis effectively favours a three-dimensional (3D spin correlation between the FeO5 bilayers evidenced by the increase of the intensity of satellite reflections with propagation vector k2 = (1/3, 1/3, 3/2. This magnetic modulation is identical to the charge ordered superstructure, highlighting the field-promoted coupling between the spin and charge degrees of freedom. Formation of the 3D spin correlations suppresses both the rod-type diffuse scattering and the k1 component. Simple symmetry-based arguments provide a natural explanation of the observed phenomenon and put forward a possible charge redistribution in the applied magnetic field.

Photoemission spectroscopy of the charge-ordering transition in Pr0.5Sr0.5MnO3

International Nuclear Information System (INIS)

Chainani, A.; Kumigashira, H.; Takahashi, T.; Tomioka, Y.; Kuwahara, H.; Tokura, Y.

1996-01-01

In this paper, the electronic structure of the magnetite Pr 0.5 Sr 0.5 MnO 3 across the charge ordering transition is studied using temperature-dependent photoemission spectroscopy. Ultra-violet photoemission spectroscopy have been performed as a function of temperature (25-300K) to investigate the changes in the single-particle density of states across the metal-nonmetal and the para-ferro transitions

Order-disorder antiferroelectric phase transition in a hybrid inorganic-organic framework with the perovskite architecture.

Science.gov (United States)

Jain, Prashant; Dalal, Naresh S; Toby, Brian H; Kroto, Harold W; Cheetham, Anthony K

2008-08-13

[(CH3)2NH2]Zn(HCOO)3, 1, adopts a structure that is analogous to that of a traditional perovskite, ABX3, with A = [(CH3)2NH2], B = Zn, and X = HCOO. The hydrogen atoms of the dimethyl ammonium cation, which hydrogen bond to oxygen atoms of the formate framework, are disordered at room temperature. X-ray powder diffraction, dielectric constant, and specific heat data show that 1 undergoes an order-disorder phase transition on cooling below 156 K. We present evidence that this is a classical paraelectric to antiferroelectric phase transition that is driven by ordering of the hydrogen atoms. This sort of electrical ordering associated with order-disorder phase transition is unprecedented in hybrid frameworks and opens up an exciting new direction in rational synthetic strategies to create extended hybrid networks for applications in ferroic-related fields.

'Second' Ehrenfest equation for second order phase transition under hydrostatic pressure