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Sample records for chalks

  1. Porosity variation in chalk

    DEFF Research Database (Denmark)

    Lind, Ida; Grøn, Peter

    1996-01-01

    Vertical porosity variations in chalk are generally assumed to result from either a vaguely defined combination of primary sedimentary and diagenetic processes or solely to diagenetic processes. In this study, image analysis of backscatter electron images of polished samples and geochemical...... microprobe mapping were applied to measure the porosity variation in a limited number of chalk samples. Microscope data indicate that in all cases the chalk has been subjected to diagenetic processes, but our data suggest that the variations in porosity originate in primary sedimentary differences....

  2. Hillerslev outcrop chalk

    Energy Technology Data Exchange (ETDEWEB)

    Lykke, M.M.

    2003-08-01

    Fractures are a great benefit to production of oil, since the matrix permeability in the oil bearing chalk reservoirs in the North Sea is low. Many of the oil fields would be marginally economic to produce without natural or induced fractures to enhance the effective permeability of the reservoirs. However, when oil is produced by use of waterflooding, an important issue is whether water fingering (fracture flow) will occur. Water fingering is due to faster flow of water in the fractures than in the matrix during waterflooding. Capillary suction of water (spontaneous or forced) must exist for waterflooding to be economic. If the matrix sucks water from the fractures, waterflooding can be a very efficient mechanism. If not, the waterflooding may fail, since the water will travel directly from the injector to the producer through the fractures, i.e. the result would be recycled water. In my Ph.D., two-phase fracture flow is investigated. The investigation is based on waterflooding tests on fractured outcrop Hillerslev chalk specimens. It is chosen to use Hillerslev outcrop chalk due to that this chalk is highly fractured and that it can be regarded as a close analogue to the oil producing Tor formation of the Valhall field located in the North Sea. To investigate fracture flow, it is important to obtain knowledge of the fractures in the chalk, i.e. it is necessary to perform a fracture study of the chalk. A field trip was made to the Hillerslev outcrop chalk quarry located in the northern part of Jutland. Here, a (global) fracture description was carried out and twelve chalk block samples were recovered at a chosen location in the Hillerslev quarry. For comparison of earlier work performed in the Hillerslev chalk quarry, this report contains a summary of the fracture description and sampling carried out during EFP-98, EFP-96 and earlier work. Measured values of porosity, permeability and capillary pressure curves of Hillerslev outcrop chalk are included to obtain

  3. Chalk as a reservoir

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    reduces porosity at the same time as it increases specific surface and thus cause permeability to be low. In the Central North Sea the silica is quartzitic. Silica rich chalk intervals are typically found in the Ekofisk and Hod formations. In addition to silica, Upper Cretaceous and Palæogene chalks...... stabilizes chemically by recrystallization. This process requires energy and is promoted by temperature. This recrystallization in principle does not influence porosity, but only specific surface, which decreases during recrystallization, causing permeability to increase. The central North Sea is a warm...... have hardly any stylolites and can have porosity above 40% or even 50% and thus also have relatively high permeability. Such intervals have the problem though, that increasing effective stress caused by hydrocarbon production results in mechanical compaction and overall subsidence. Most other chalk...

  4. Less chalk more action

    Science.gov (United States)

    Mitriceski Andelkovic, Bojana; Jovic, Sladjana

    2016-04-01

    Less chalk more action Education should not be a mechanical system that operates according to the principles of the orders and implementation. Education should respect the basic laws of the develop and progress. Curiosity is the engine of achievement and children spontaneously and happily learn only if they get interested, if teacher wake up and stimulate their creativity and individuality. We would like to present classes that are realized as thematic teaching with several subjects involved: chemistry, geography, math, art and biology. Classes were organized for students at age from 10 to 13 years, every month during autumn and winter 2015. Better students identified themselves as teachers and presented peer education .Teachers were monitoring the process of teaching and help to develop links between younger and older students, where older students were educators to younger students. Also one student with special needs was involved in this activities and was supported by other students during the workshops The benefit from this project will be represented with evaluation marks. Evaluation table shows that group of ten students(age 10 to13 years) which are selected in October as children with lack of motivation for learning, got better marks, at the end of January , then they had it in the beginning of the semester.

  5. The sedimentology of redeposited chalk

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Surlyk, Finn; Gale, Andy

    Redeposited facies in the Upper Cretaceous Chalk Group constitute major hydrocarbon reservoirs in the North Sea Central Graben. Existing facies models are largely based on publications from the early 1980's dealing with core material from the Norwegian sector. However, the recognition, interpreta...

  6. Chalk Line Mill, Anniston, AL

    Science.gov (United States)

    The Chalk Line Mill property was the site of a textile mill which operated from 1887 until 1994. Demolition activities in 2004 removed most of the structures on-site, but also left large, unsightly piles of debris scattered across this 14-acre property. The City applied for and received a $200,000 Brownfields cleanup grant in 2007 to address contamination on the property and the Appalachian Regional Commission provided an additional $150,000 in funding.

  7. Poroelasticity of high porosity chalk under depletion

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2013-01-01

    levels of pore pressure. The chalk is oil-saturated Lixhe chalk from a quarry near Liège, Belgium, with a general porosity of 45%. Additionally, we compare the theoretical lateral stress to the experimentally determined lateral stress at the onset of pore collapse. The static Biot coefficient based...

  8. Self Compacting Concrete with Chalk Filler

    DEFF Research Database (Denmark)

    Sørensen, Eigil V.

    2007-01-01

    at 28 days from about 35 MPa down to about 13 MPa. The cementing efficiency factor of the chalk filler was found to be in the range 0.21 - 0.42. The chalk filler performed equally well with a grey and a white cement; the latter opens the possibility to produce white SCC more cost effectively....

  9. Adsorption of hydrocarbons in chalk reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Madsen, L.

    1996-12-31

    The present work is a study on the wettability of hydrocarbon bearing chalk reservoirs. Wettability is a major factor that influences flow, location and distribution of oil and water in the reservoir. The wettability of the hydrocarbon reservoirs depends on how and to what extent the organic compounds are adsorbed onto the surfaces of calcite, quartz and clay. Organic compounds such as carboxylic acids are found in formation waters from various hydrocarbon reservoirs and in crude oils. In the present investigation the wetting behaviour of chalk is studied by the adsorption of the carboxylic acids onto synthetic calcite, kaolinite, quartz, {alpha}-alumina, and chalk dispersed in an aqueous phase and an organic phase. In the aqueous phase the results clearly demonstrate the differences between the adsorption behaviour of benzoic acid and hexanoic acid onto the surfaces of oxide minerals and carbonates. With NaCl concentration of 0.1 M and with pH {approx_equal} 6 the maximum adsorption of benzoic acid decreases in the order: quartz, {alpha}-alumina, kaolinite. For synthetic calcite and chalk no detectable adsorption was obtaind. In the organic phase the order is reversed. The maximum adsorption of benzoic acid onto the different surfaces decreases in the order: synthetic calcite, chalk, kaolinite and quartz. Also a marked difference in adsorption behaviour between probes with different functional groups onto synthetic calcite from organic phase is observed. The maximum adsorption decreases in the order: benzoic acid, benzyl alcohol and benzylamine. (au) 54 refs.

  10. Adsorption Properties of Chalk Reservoir Materials

    DEFF Research Database (Denmark)

    Okhrimenko, Denis

    Understanding adsorption energetics and wetting properties of calcium carbonate surfaces is essential for developing remediation strategies for aquifers, improving oil recovery, minimising risk in CO2 storage and optimising industrial processes. This PhD was focussed on comparing the vapour....../gas adsorption properties of synthetic calcium carbonate phases (calcite, vaterite and aragonite) with chalk, which is composed of biogenic calcite (>98%). In combination with data from nanotechniques, the results demonstrate the complexity of chalk behavior and the role of nanoscale clay particles. The results...

  11. Elastic behaviour of North Sea chalk

    DEFF Research Database (Denmark)

    Gommesen, Lars; Fabricius, Ida Lykke; Mukerji, T.

    2007-01-01

    We present two different elastic models for, respectively, cemented and uncemented North Sea chalk well-log data. We find that low Biot coefficients correlate with anomalously low cementation factors from resistivity measurements at low porosity and we interpret this as an indication of cementation...... to logging data than the Gassmann prediction for the far, virgin zone. We thus conclude that the Gassmann approach predicts hydrocarbons accurately in chalk in the sonic-frequency domain, but the fluid effects as recorded by the acoustic tool are significantly affected by invasion of mud filtrate...

  12. Compaction of microfossil and clay-rich chalk sediments

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2001-01-01

    The aim of this study was to evaluate the role of microfossils and clay in the compaction of chalk facies sediments. To meet this aim, chalk sediments with varying micro texture were studied. The sediments have been tested uniaxially confined in a stainless-steel compaction cell. The sediments are......: 1) Pure carbonate chalk with mudstone texture from Stevns Klint (Denmark), 2) Relatively pure chalk sediments with varying content of microfossils from the Ontong Java Plateau (Western Pacific), 3) Clay-rich chalk and mixed sediments from the Caribbean. The tested samples were characterised...... of microfossils and fine-grained silica and clay. Samples with relatively pure chalk mud supported texture compact along a common stress - matrix porosity trend. Microfossils thus have a passive role, apparently because they are supported by the chalk mud. Samples with fine-grained silica and clay can be modelled...

  13. Nickel adsorption on chalk and calcite

    DEFF Research Database (Denmark)

    Belova, Dina Alexandrovna; Lakshtanov, Leonid; Carneiro, J.F.

    2014-01-01

    and chalk and pH ranging from 7.7 to 8.8, explored the influence of initial concentration and the amount and type of sorbent on Ni uptake. Adsorption increases with increased surface area and pH. A surface complexation model describes the data well. Stability constants for the Ni surface complex are log KNi...

  14. Late Maastrichtian chalk mounds, Stevns Klint, Denmark

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Damholt, Tove; Surlyk, Finn

    Upper Maastrichtian chalk exposed in the Sigerslev quarry, Stevns Klint, Denmark shows wavy and mound-like bedding geometries outlined by bands of black flint nodules. Bedding geometries are highly variable, but four morphological elements are recognized: Southward migrating mounds, eastward...

  15. Late Maastrichtian chalk mounds, Stevns Klint, Denmark

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Damholt, Tove; Surlyk, Finn

    2007-01-01

    Upper Maastrichtian chalk exposed at the Sigerslev quarry, Stevns Klint, Denmark is characterized by wavy and mound-like bedding geometries outlined by bands of black flint nodules. Four morphological elements are recognized, although bedding geometries are highly variable: southward migrating...

  16. Slope failure of chalk channel margins

    DEFF Research Database (Denmark)

    Gale, A.; Anderskouv, Kresten; Surlyk, Finn

    2015-01-01

    The importance of mass transport and bottom currents is now widely recognized in the Upper Cretaceous Chalk Group of Northern Europe. The detailed dynamics and interaction of the two phenomena are difficult to study as most evidence is based on seismic data and drill core. Here, field observation...

  17. Chalk: composition, diagenesis and physical properties

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2007-01-01

    Chalk is a sedimentary rock of unusually high homogeneity on the scale where physical properties are measured, but the properties fall in wide ranges. Chalk may thus be seen as the ideal starting point for a physical understanding of rocks in general. Properties as porosity, permeability, capillary...... entry pressure, and elastic moduli are consequences of primary sediment composition and of subsequent diagenetic history as caused by microbial action, burial stress, temperature, and pore pressure. Porosity is a main determining factor for other properties. For a given porosity, the specific surface...... of the sediment controls permeability and capillary entry pressure. As diagenesis progresses, the specific surface is less and less due to the calcite component and more and more due to the fine-grained silicates, as a reflection of the coarsening and cementation of the calcite crystals. The elastic moduli, which...

  18. New insight into the microtexture of chalks from NMR analysis

    DEFF Research Database (Denmark)

    Faÿ-Gomord, Ophélie; Soete, Jeroen; Katika, Konstantina

    2016-01-01

    quality chalks independently of their sedimentological and/or diagenetic history. The study aims to develop an NMR-based approach to characterize a broad range of chalk samples. The provided laboratory low-field NMR chalk classification can be used as a guide to interpret NMR logging data...... size and T2 logarithmic (T2lm) was calculated. It is apparent that tight chalks, whether their characteristics are sedimentological or diagenetic, yield smaller pore body sizes (T2lm well as narrower pore throats (average radius

  19. Effect of Fluid Dynamic Viscosity on the Strength of Chalk

    DEFF Research Database (Denmark)

    Hedegaard, K.; Fabricius, Ida Lykke

    The mechanical strength of high porosity and weakly cemented chalk is affected by the fluid in the pores. In this study, the effect of the dynamic viscosity of non-polar fluids has been measured on outcrop chalk from Sigerslev Quarry, Stevns, Denmark. The outcome is that the measured strength...

  20. The Beauty of the Beasts in Chalk Pastels

    Science.gov (United States)

    Skophammer, Karen

    2010-01-01

    In this article, the author describes how her seventh-grade art students captured an image of a stuffed animal in the "whole-to-part" drawing technique using chalk pastels. Shading with chalk pastels can give a gradual change in value from dark to light. The shading and color changes the mood of the original drawing, and adds texture, too. Chalk…

  1. Stylolites, porosity, depositional texture, and silicates in chalk facies sediments

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Borre, Mai K.

    2007-01-01

    Comparison of chalk on the Ontong Java Plateau and chalk in the Central North Sea indicates that, whereas pressure dissolution is controlled by effective burial stress, pore-filling cementation is controlled by temperature. Effective burial stress is caused by the weight of all overlying water an...

  2. Chalk Formations as Natural Barriers towards Radionuclide Migration

    DEFF Research Database (Denmark)

    Pedersen, Walther Batsberg; Carlsen, Lars; Jensen, Bror Skytte

    1985-01-01

    A series of chalk samples from the cretaceous formation overlying the Erslev salt dome have been studied in order to establish permeabilities, porosities, dispersion-, diffusion-, and sorption characteristics of the chalk. The chalk was found to be porous (∊≈0.4), however, of rather low...... permeability (k≈10-7 cm/sec). It was found that the material exhibits a retarding effect on migration of cationic species as Cs+, Sr2+ , Co2+, and Eu3+, whereas ionic species as Cl- move with the water front. The geochemical implications are discussed...

  3. Kolmanda aastatuhande piraadid / kommenteerinud Peter Chalk ja Gordan Van Hook

    Index Scriptorium Estoniae

    2009-01-01

    Piraatlusest Somaalia piirkonnas ja rahvusvahelistest dokumentidest piraatluse vastu võitlemiseks 21. sajandil. Kommenteerivad uurimiskeskuse RAND Corporation vanempoliitanalüütik Peter Chalk ja transpordikompanii Maersk Line innovatsiooni ja arenduse vanemdirektor Gordan Van Hook

  4. To What Degree Thermal Cycles Affect Chalk Strength

    DEFF Research Database (Denmark)

    Livada, Tijana; Nermoen, Anders; Korsnes, Reidar Inger;

    Chalk reservoirs could potentially undergo destabilization as the result of repeated cold water injection into a hot reservoir during water flooding. Preliminary results of an ongoing study are presented in this paper, which compare the impact of temperature cycling on mechanical behavior on dry...... triaxial cell experiments. For dry rock, no significant effects of temperature cycling was found on average tensile strength, however the range of the tensile failure stress is doubled for the samples exposed to 50 temperature cycles, as opposed to those to none. For water saturated cores, the temperature...... and water saturated chalk. Sixty disks of dry Kansas chalk exposed to different number of temperature cycles were tested for tensile strength using a Brazilian test. Changes in elastic properties as function of number of temperature cycles of the same chalk, but now saturated in water, were studied using...

  5. Diagenetic Variations between Upper Cretaceous Outcrop and Deeply Buried Reservoir Chalks of the North Sea Area

    DEFF Research Database (Denmark)

    Hjuler, Morten Leth; Fabricius, Ida Lykke

    2007-01-01

    In the central North Sea Basin hydrocarbon-bearing chalks are deeply buried (2-3 km) whereas chalks in the rim areas are cropping out in the surrounding countries. The differing diagenetic histories between buried and outcrop chalk result in different rock properties, which is of great importance...... when simulating reservoir conditions using outcrop chalks as models. In general deeply buried reservoir chalks show significant overgrowth as witnessed by reshaping of particles together with strengthening of particle contacts. Most outcrop chalks are moderately affected with looser inter...

  6. Prospects of Microbial Enhanced Oil Recovery  in Danish chalk rocks

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Jørgensen, Leif Wagner; Bah Awasi, Ismail

    % of gas was produced in the presence of chalk in microbial solution and just 20% in the process of microbial fermentation with molasses (without chalk). The microbial solution improved the permeability of three chalk samples by 8.1%, 16.4% and 2658% respectively during 14 days of exposure having formed...... a big hole in the core sample in the latter case....

  7. Influence of effective stress coefficient on mechanical failure of chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Hjuler, M.L.

    2012-01-01

    , as this process could affect the grain contact cement. If this happens, the effective stress at the grain contacts in a reservoir will change according to the effective stress principle of Biot. In a p′-q space for failure analysis, we observed that a higher effective stress coefficient reduces the elastic region...... and vice versa. However, as the effective stress working on the rock decreases with increased effective stress coefficient, the reduction of elastic region will have less effect on pore collapse strength if we consider the change in the effective stress coefficient. This finding will help estimate a more......The Effective stress coefficient is a measure of how chalk grains are connected with each other. The stiffness of chalk may decrease if the amount of contact cements between the grains decreases, which may lead to an increase of the effective stress coefficient. We performed CO2 injection in chalk...

  8. Chemical and Mechanical processes during burial diagenesis of chalk

    DEFF Research Database (Denmark)

    Borre, Mai Kirstine; Lind, Ida

    1998-01-01

    or larger influence on the textural development. In the chalk interval below, compaction is not the only porosity reducing agent but it has a larger influence on texture than concurrent recrystallization. Below 850 m grain-bridging cementation becomes important resulting in a lithified limestone below 1100......Burial diagenesis of chalk is a combination of mechanical compaction and chemical recrystallization as well as cementation. We have predicted the characteristic trends in specific surface resulting from these processes. The specific surface is normally measured by nitrogen adsorption but is here...... in the Pacific, where a > 1 km thick package of chalk facies sediments accumulated from the Cretaceous to the present. In the upper 200-300 m the sediment is unconsolidated carbonate ooze, throughout this depth interval compaction is the principal porosity reducing agent, but recrystallization has an equal...

  9. Nano sized clay detected on chalk particle surfaces

    DEFF Research Database (Denmark)

    Skovbjerg, Lone; Hassenkam, Tue; Makovicky, Emil

    2012-01-01

    that in calcite saturated water, both the polar and the nonpolar functional groups adhere to the nano sized clay particles but not to calcite. This is fundamentally important information for the development of conceptual and chemical models to explain wettability alterations in chalk reservoirs...

  10. Quantitative 1D saturation profiles on chalk by NMR

    DEFF Research Database (Denmark)

    Olsen, Dan; Topp, Simon; Stensgaard, Anders;

    1996-01-01

    Quantitative one-dimensional saturation profiles showing the distribution of water and oil in chalk core samples are calculated from NMR measurements utilizing a 1D CSI spectroscopy pulse sequence. Saturation profiles may be acquired under conditions of fluid flow through the sample. Results reveal...

  11. Chalk-microfluidic: flooding microsystems with reactive fluids

    Science.gov (United States)

    Neuville, Amélie; Dysthe, Dag Kristian; Li, Lei; Hiorth, Aksel

    2014-05-01

    Experiments on core scale and field tests that have been carried out the last decade have clearly shown that water chemistry affects the final oil recovery. However, there is generally no consensus in the scientific community of why additional oil is released. Part of the reason for this is that there are very few in-situ observations of how the water chemistry affects fluid distributions on the pore scale, and/or the pore surface characteristics. In this work, as a first step, our aim is to focus on in-situ observations of single phase flow and interactions at the pore scale. In order to work at this small scale, we first investigate how to control the flow location. We propose to use the same principle as "paper-microfluidic": some areas of the chalk are chemically treated so that no fluid flows inside while other areas let the fluids flow in the chalk pores. Since chalk and paper obviously has different mechanical behavior, we need to adapt this technique. Custom-made microsystems with chalk and calcite will be presented. We will then show experiments with reacting fluids in these microsystems. These experiments are observed using wide field fluorescence microscopy and white light vertical/phase shift interferometric microscopy.

  12. Ekofisk chalk: core measurements, stochastic reconstruction, network modeling and simulation

    Energy Technology Data Exchange (ETDEWEB)

    Talukdar, Saifullah

    2002-07-01

    This dissertation deals with (1) experimental measurements on petrophysical, reservoir engineering and morphological properties of Ekofisk chalk, (2) numerical simulation of core flood experiments to analyze and improve relative permeability data, (3) stochastic reconstruction of chalk samples from limited morphological information, (4) extraction of pore space parameters from the reconstructed samples, development of network model using pore space information, and computation of petrophysical and reservoir engineering properties from network model, and (5) development of 2D and 3D idealized fractured reservoir models and verification of the applicability of several widely used conventional up scaling techniques in fractured reservoir simulation. Experiments have been conducted on eight Ekofisk chalk samples and porosity, absolute permeability, formation factor, and oil-water relative permeability, capillary pressure and resistivity index are measured at laboratory conditions. Mercury porosimetry data and backscatter scanning electron microscope images have also been acquired for the samples. A numerical simulation technique involving history matching of the production profiles is employed to improve the relative permeability curves and to analyze hysteresis of the Ekofisk chalk samples. The technique was found to be a powerful tool to supplement the uncertainties in experimental measurements. Porosity and correlation statistics obtained from backscatter scanning electron microscope images are used to reconstruct microstructures of chalk and particulate media. The reconstruction technique involves a simulated annealing algorithm, which can be constrained by an arbitrary number of morphological parameters. This flexibility of the algorithm is exploited to successfully reconstruct particulate media and chalk samples using more than one correlation functions. A technique based on conditional simulated annealing has been introduced for exact reproduction of vuggy

  13. Chalk porosity and sonic velocity versus burial depth

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Gommesen, Lars; Krogsbøll, Anette Susanne;

    2008-01-01

    Seventy chalk samples from four formations in the overpressured Danish central North Sea have been analyzed to investigate how correlations of porosity and sonic velocity with burial depth are affected by varying mineralogy, fluid pressure, and early introduction of petroleum. The results show...... for fluid pressure because the cementing ions originate from stylolites, which are mechanically similar to fractures. We find that cementation occurs over a relatively short depth interval....

  14. Horizontal spacing, depletion, and infill potential in the Austin chalk

    Energy Technology Data Exchange (ETDEWEB)

    Kyte, D.G.; Meehan, D.N.

    1996-12-31

    Estimated ultimate recoveries on a barrels per acre basis for Austin chalk wells were discussed. The study showed that the maximum six months consecutive production through the life of the well can be used to estimate ultimate recovery in horizontally drilled reservoirs. A statistical approach was used to help identify where the Austin chalk has been overdrilled and areas where infill potential exists. The barrels per acre data were analyzed by a method known as `moving domain`. This procedure involves stepping through the reservoir well by well and looking at it with respect to its nearest neighbors. To analyze for depletion, barrels per acre is compared to date of first production for groups of wells in an area, looking for declining values with time. Areas showing no evidence of depletion and having good recoveries are further studied for infill potential. By comparing effective densities in areas which are not yet being fully drained, an optimum spacing between wells can be determined for horizontal wells in a fractured chalk reservoir. An artificial neural network can also be used to provide qualitative predictions of well performance in developed reservoirs. 6 refs., 15 figs.

  15. Biot Critical Frequency Applied to Description of Failure and Yield of Highly Porous Chalk with Different Pore Fluids

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2010-01-01

    Injection of water into chalk hydrocarbon reservoirs has led to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. In case of water-saturated samples, the concentration and...... the possibility of predicting the effects of water flooding on chalk stability.......Injection of water into chalk hydrocarbon reservoirs has led to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. In case of water-saturated samples, the concentration...... and nature of dissolved salts have an effect.Water has a significant softening effect on elastic properties of chalk as calculated from wave data, and the softening increases with increasing critical frequency as defined by Biot. The critical frequency is the highest frequency where elastic wave propagation...

  16. Waveform analysis of crosshole GPR data collected in heterogeneous chalk deposits

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Nielsen, Lars; Zibar, Majken Caroline Looms;

    2014-01-01

    properties, e.g. subtle changes in porosity. We have conducted a range of high-resolution GPR crosshole experiments in Boesdal quarry in Eastern Denmark. The objective is to investigate the impact of fine-scale heterogeneity on reservoir properties in chalk. The studied chalk interval is c.15 m thick. It can...

  17. Full-waveform Inversion of Crosshole GPR Data Collected in Strongly Heterogeneous Chalk

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Zibar, Majken Caroline Looms; Nielsen, Lars;

    2015-01-01

    in an old chalk quarry in Eastern Denmark. Based on core data (including plug samples and televiewer logging data) collected in our four ~15-m-deep boreholes and results from previous related studies, it is apparent that the studied chalk is strongly heterogeneous. The upper ~7 m consist of variable coarse...

  18. Origin of channel systems in the Upper Cretaceous chalk group of the Paris Basin

    DEFF Research Database (Denmark)

    Esmerode, E. V.; Surlyk, Finn

    2009-01-01

    of the Cenozoic succession over the channel-like features as a result of intra-chalk dissolution. Both reflections correlate with indurated chalk layers and hardgrounds, and represent real unconformities. The Mid-Campanian reflection is furthermore associated with a stratigraphic hiatus. A submarine origin...

  19. From ooze to sedimentary rock, the first diagenetic processes affecting the chalk of eastern Denmark

    DEFF Research Database (Denmark)

    Moreau, Julien; Boussaha, Myriam; Nielsen, Lars

    The Stevns peninsula, situated in the eastern Danish Basin at the fringe of the Baltic Sea, is an ideal target for studying the early stages of diagenesis that affected the Upper Cretaceous chalk during its burial to 500-1400m depth. For the present study onshore and offshore high-resolution seis...... in chalk sedimentary rocks....

  20. Dynamic and static elastic moduli of North Sea and deep sea chalk

    DEFF Research Database (Denmark)

    Gommesen, Lars; Fabricius, Ida Lykke

    2001-01-01

    We have established an empirical relationship between the dynamic and the static mechanical properties of North Sea and deep sea chalk for a large porosity interval with respect to porosity, effective stress history and textural composition. The chalk investigated is from the Tor and Hod Formations...

  1. Probing the intrinsically oil-wet surfaces of pores in North Sea chalk at subpore resolution

    DEFF Research Database (Denmark)

    Hassenkam, Tue; Skovbjerg, Lone Lindbæk; Stipp, Susan Louise Svane

    2009-01-01

    Ultimate Oil recovery from chalk reservoirs is limited by many factors - including the grain size and the surface properties of the small mainly biogenic calcite particles that chalk is made off . Wettability, the tendency for water or oil to spread over a surface, of the particle surfaces is one...

  2. Groundwater recharge dynamics in unsaturated fractured chalk: a case study

    Science.gov (United States)

    Cherubini, Claudia; Pastore, Nicola; Giasi, Concetta I.; Allegretti, Nicolaetta M.

    2016-04-01

    The heterogeneity of the unsaturated zone controls its hydraulic response to rainfall and the extent to which pollutants are delayed or attenuated before reaching groundwater. It plays therefore a very important role in the recharge of aquifers and the transfer of pollutants because of the presence of temporary storage zones and preferential flows. A better knowledge of the physical processes in the unsaturated zone would allow an improved assessment of the natural recharge in a heterogeneous aquifer and of its vulnerability to surface-applied pollution. The case study regards the role of the thick unsaturated zone of the Cretaceous chalk aquifer in Picardy (North of France) that controls the hydraulic response to rainfall. In the North Paris Basin, much of the recharge must pass through a regional chalk bed that is composed of a porous matrix with embedded fractures. Different types of conceptual models have been formulated to explain infiltration and recharge processes in the unsaturated fractured rock. The present study analyses the episodic recharge in fractured Chalk aquifer using the kinematic diffusion theory to predict water table fluctuation in response to rainfall. From an analysis of the data, there is the evidence of 1) a seasonal behavior characterized by a constant increase in the water level during the winter/spring period and a recession period, 2) a series of episodic behaviors during the summer/autumn. Kinematic diffusion models are useful for predict preferential fluxes and dynamic conditions. The presented approach conceptualizes the unsaturated flow as a combination of 1) diffusive flow refers to the idealized portion of the pore space of the medium within the flow rate is driven essentially by local gradient of potential; 2) preferential flow by which water moves across macroscopic distances through conduits of macropore length.

  3. Fault zone processes in mechanically layered mudrock and chalk

    Science.gov (United States)

    Ferrill, David A.; Evans, Mark A.; McGinnis, Ronald N.; Morris, Alan P.; Smart, Kevin J.; Wigginton, Sarah S.; Gulliver, Kirk D. H.; Lehrmann, Daniel; de Zoeten, Erich; Sickmann, Zach

    2017-04-01

    A 1.5 km long natural cliff outcrop of nearly horizontal Eagle Ford Formation in south Texas exposes northwest and southeast dipping normal faults with displacements of 0.01-7 m cutting mudrock, chalk, limestone, and volcanic ash. These faults provide analogs for both natural and hydraulically-induced deformation in the productive Eagle Ford Formation - a major unconventional oil and gas reservoir in south Texas, U.S.A. - and other mechanically layered hydrocarbon reservoirs. Fault dips are steep to vertical through chalk and limestone beds, and moderate through mudrock and clay-rich ash, resulting in refracted fault profiles. Steeply dipping fault segments contain rhombohedral calcite veins that cross the fault zone obliquely, parallel to shear segments in mudrock. The vertical dimensions of the calcite veins correspond to the thickness of offset competent beds with which they are contiguous, and the slip parallel dimension is proportional to fault displacement. Failure surface characteristics, including mixed tensile and shear segments, indicate hybrid failure in chalk and limestone, whereas shear failure predominates in mudrock and ash beds - these changes in failure mode contribute to variation in fault dip. Slip on the shear segments caused dilation of the steeper hybrid segments. Tabular sheets of calcite grew by repeated fault slip, dilation, and cementation. Fluid inclusion and stable isotope geochemistry analyses of fault zone cements indicate episodic reactivation at 1.4-4.2 km depths. The results of these analyses document a dramatic bed-scale lithologic control on fault zone architecture that is directly relevant to the development of porosity and permeability anisotropy along faults.

  4. Grain size distributions of chalk from image analysis of electron micrographs

    DEFF Research Database (Denmark)

    Røgen, Birte; Gommesen, Lars; Fabricius, Ida Lykke

    2001-01-01

    In the chalk of the Ekofisk formation in the Chalk Group of the North Sea, substantial depth-related variations in porosityare observed. With the aim of obtaining a textural interpretation of these porositydata, we have developed a method to assess the grain size distribution of the chalk from...... image analysis. The chalk is composed of a fine-grained matrix of nannofossils and predominantlycalcitic fossil debris with larger microfossil grains, but the chalk may also contain significant amounts of silica and siliciclastic clay. For image analysis, we used backscatter electron images of epoxy......-impregnated, polished samples from the Ekofisk Formation, Tyra field, Danish North Sea. On backscatter images the calcite phase will appear light as opposed to the dark pore space. The procedure involves the combination of data acquired at two magnifications and bythis method analysis of only four images per sample...

  5. Improved Oil Recovery in Chalk. Spontaneous Imbibition affected by Wettability, Rock Framework and Interfacial Tension

    Energy Technology Data Exchange (ETDEWEB)

    Milter, J.

    1996-12-31

    The author of this doctoral thesis aims to improve the oil recovery from fractured chalk reservoirs, i.e., maximize the area of swept zones and their displacement efficiencies. In order to identify an improved oil recovery method in chalk, it is necessary to study wettability of calcium carbonate and spontaneous imbibition potential. The thesis contains an investigation of thin films and wettability of single calcite surfaces. The results of thin film experiments are used to evaluate spontaneous imbibition experiments in different chalk types. The chalk types were described detailed enough to permit considering the influence of texture, pore size and pore throat size distributions, pore geometry, and surface roughness on wettability and spontaneous imbibition. Finally, impacts of interfacial tension by adding anionic and cationic surfactants to the imbibing water phase are studied at different wettabilities of a well known chalk material. 232 refs., 97 figs., 13 tabs.

  6. The Effect of Bacteria Penetration on Chalk Permeability

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Shapiro, Alexander; Nielsen, Sidsel Marie;

    , the spore forming Bacillus licheniformis 421 and the non-spore forming Pseudomonas putida K12, were used. The core plugs were Stevns Klint outcrop with initial permeability at 2-4 mD. The results revealed that bacteria were able to penetrate and to be transported through the chalk. Furthermore, a higher...... number of B. licheniformis was detected on the effluent compared with P. putida. However, in the experiment with B. licheniformis mainly spores were detected in the effluent. The core permeability decreased rapidly during injection of bacteria and a starvation period of 12 days did not allow...... the permeability to return to initial condition....

  7. Dynamic up-scaling of relative permeability in chalk

    Energy Technology Data Exchange (ETDEWEB)

    Frykman, P.; Lindgaard, H.F.

    1997-12-31

    This paper describes how fine-scale geo-statistic reservoir models can be utilised for the up-scaling of two-phase flow properties, including both relative permeability and capillary pressure function. The procedure is applied to a North Sea chalk carbonate reservoir example, which is a high-porosity/low-permeability reservoir type. The study focuses on waterflooding as the main recovery scheme and for the given flow regime in the reservoir. The main purpose of the paper is to demonstrate the use of dynamic multi-step up-scaling methods in the preparation of detailed geological information for full field reservoir simulation studies. (au) EFP-96. 39 refs.

  8. Specific surface as a measure of burial diagenesis of chalk

    DEFF Research Database (Denmark)

    Borre, Mai Kirstine; Lind, Ida; Mortensen, Jeanette

    1997-01-01

    ODP Leg 130, Site 807, in the western equatorial Pacific, penetrates a sequence of pelagic carbonate ooze, chalk and limestone. Compaction, recrystallisation and cementation of the carbonate matrix are diagenetic processes expected to be taking place more or less simultaneously. In order to assess...... the relative importance of the three processes, simple models have been established to illustrate changes in pore space, particle size and -shape and the resulting trends in the specific surface. Specific surface and porosity of the samples were measured using image analysis on electron micrographs of polished...

  9. Isotope hydrology of the Chalk River Laboratories site, Ontario, Canada

    Science.gov (United States)

    Peterman, Zell; Neymark, Leonid; King-Sharp, K.J.; Gascoyne, Mel

    2016-01-01

    This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.

  10. A parameter identifiability study of two chalk tracer tests

    Directory of Open Access Journals (Sweden)

    S. A. Mathias

    2006-08-01

    Full Text Available As with most fractured rock formations, Chalk is highly heterogeneous. Therefore, meaningful estimates of model parameters must be obtained at a scale comparable with the process of concern. These are frequently obtained by calibrating an appropriate model to observed concentration-time data from radially convergent tracer tests (RCTT. Arguably, an appropriate model should consider radially convergent dispersion (RCD and Fickian matrix diffusion. Such a model requires the estimation of at least four parameters. A question arises as to whether or not this level of model complexity is supported by the information contained within the calibration data. Generally modellers have not answered this question due to the calibration techniques employed. A dual-porosity model with RCD was calibrated to two tracer test datasets from different UK Chalk aquifers. A multivariate sensitivity analysis, which assumed only a priori upper and lower bounds for each model parameter, was undertaken. Rather than looking at measures of uncertainty, the shape of the multivariate objective function surface was used to determine whether a parameter was identifiable. Non-identifiable parameters were then removed and the procedure was repeated until all remaining parameters were identifiable.

    It was found that the single fracture model (SFM (which ignores mechanical dispersion obtained the best mass recovery, excellent model performance and best parameter identifiability in both the tests studied. However, there was no objective evidence suggesting that mechanical dispersion was negligible. Moreover, the SFM (with just two parameters was found to be good at approximating the Single Fracture Dispersion Model SFDM (with three parameters when different, and potentially erroneous parameters, were used. Overall, this study emphasises the importance of adequate temporal sampling of breakthrough curve data prior to peak concentrations, to ensure adequate characterisation of

  11. Overview of the Chalk Point Cooling Tower Project, 1972-1979

    Energy Technology Data Exchange (ETDEWEB)

    Moon, M.L. (ed.)

    1979-03-01

    The objectives, methodologies, data, and analytical results of the Chalk Point Cooling Tower Program are reviewed. The overview intergrates the concepts and activities of the various program elements to provide a coherent view of the program in its entirety. Samples of the various data acquired are included together with very brief summaries of the conclusions. The report is extensively referenced to provide specific directions to the more extensive treatments of the program, data tabulations, and tape libraries available in the complete library of Chalk Point reports. The Chalk Point data is a resource for the study of cooling tower salt deposition processes and impacts in general. The methods used, while developed to facilitate the assessment of salt drift impact at Chalk Point, also have applicability to cooling tower impact analysis at other sites.

  12. Biot Critical Frequency Applied as Common Friction Factor for Chalk with Different Pore Fluids and Temperatures

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2010-01-01

    Injection of water into chalk hydrocarbon reservoirs has lead to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. Water has a significant softening effect on elastic...... and we propose that the fluid effect on mechanical properties of highly porous chalk may be the result of liquid‐solid friction. Applying a different strain or stress rate is influencing the rock strength and needs to be included. The resulting function is shown to relate to the material dependent...... and rate independent b-factor used when describing the time dependent mechanical properties of soft rock or soils. As a consequence it is then possible to further characterize the material constant from the porosity and permeability of the rock as well as from pore fluid density and viscosity which...

  13. Impact of supercritical CO2 injection on petrophysical and rock mechanics properties of chalk: an experimental study on chalk from South Arne field, North Sea

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged

    2011-01-01

    Changes in chalk due to EOR by injecting supercritical CO2 (CO2-EOR) can ideally be predicted by applying geophysical methods designed from laboratory-determined petrophysical and rock mechanics properties. A series of petrophysical and rock mechanics tests were performed on Ekofisk Formation...... and Tor Formation chalk of the South Arne field to reveal the changes in petrophysical and rock mechanics properties of chalk due to the injection of CO2 at supercritical state. An increase in porosity and decrease in specific surface was observed due to injection of supercritical CO2. This indicates...... that a reaction between CO2 enriched water and particles takes place which smoothens the particle surface. Accordingly, partial increase in permeability was also noticed. An effect is also observed from the decrease in pore-space stiffness, calculated from sonic velocity. No significant effect on wettability...

  14. Towards a simple representation of chalk hydrology in land surface modelling

    Science.gov (United States)

    Rahman, Mostaquimur; Rosolem, Rafael

    2017-01-01

    Modelling and monitoring of hydrological processes in the unsaturated zone of chalk, a porous medium with fractures, is important to optimize water resource assessment and management practices in the United Kingdom (UK). However, incorporating the processes governing water movement through a chalk unsaturated zone in a numerical model is complicated mainly due to the fractured nature of chalk that creates high-velocity preferential flow paths in the subsurface. In general, flow through a chalk unsaturated zone is simulated using the dual-porosity concept, which often involves calibration of a relatively large number of model parameters, potentially undermining applications to large regions. In this study, a simplified parameterization, namely the Bulk Conductivity (BC) model, is proposed for simulating hydrology in a chalk unsaturated zone. This new parameterization introduces only two additional parameters (namely the macroporosity factor and the soil wetness threshold parameter for fracture flow activation) and uses the saturated hydraulic conductivity from the chalk matrix. The BC model is implemented in the Joint UK Land Environment Simulator (JULES) and applied to a study area encompassing the Kennet catchment in the southern UK. This parameterization is further calibrated at the point scale using soil moisture profile observations. The performance of the calibrated BC model in JULES is assessed and compared against the performance of both the default JULES parameterization and the uncalibrated version of the BC model implemented in JULES. Finally, the model performance at the catchment scale is evaluated against independent data sets (e.g. runoff and latent heat flux). The results demonstrate that the inclusion of the BC model in JULES improves simulated land surface mass and energy fluxes over the chalk-dominated Kennet catchment. Therefore, the simple approach described in this study may be used to incorporate the flow processes through a chalk unsaturated

  15. Trace elemental analysis of school chalk using energy dispersive X-ray florescence spectroscopy (ED-XRF)

    Science.gov (United States)

    Maruthi, Y. A.; Das, N. Lakshmana; Ramprasad, S.; Ram, S. S.; Sudarshan, M.

    2015-08-01

    The present studies focus the quantitative analysis of elements in school chalk to ensure the safety of its use. The elements like Calcium (Ca), Aluminum (Al), Iron (Fe), Silicon (Si) and Chromium (Cr) were analyzed from settled chalk dust samples collected from five classrooms (CD-1) and also from another set of unused chalk samples collected from local market (CD-2) using Energy Dispersive X-Ray florescence(ED-XRF) spectroscopy. Presence of these elements in significant concentrations in school chalk confirmed that, it is an irritant and occupational hazard. It is suggested to use protective equipments like filtered mask for mouth, nose and chalk holders. This study also suggested using the advanced mode of techniques like Digital boards, marker boards and power point presentations to mitigate the occupational hazard for classroom chalk

  16. Current oil and gas production from North American Upper Cretaceous chalks

    Science.gov (United States)

    Scholle, Peter A.

    1977-01-01

    Production of oil and natural gas from North American chalks has increased significantly during the past five years, spurred by the prolific production from North Sea chalks, as well as by higher prices and improved production technology. Chalk reservoirs have been discovered in the Gulf Coast in the Austin Group, Saratoga and Annona Chalks, Ozan Formation, Selma Group, Monroe gas rock (an informal unit of Navarro age), and other Upper Cretaceous units. In the Western Interior, production has been obtained from the Cretaceous Niobrara and Greenhorn Formations. Significant, though subcommercial, discoveries of natural gas and gas condensate also have been made in the Upper Cretaceous Wyandot Formation on the Scotian Shelf of eastern Canada. All North American chalk units share a similar depositional and diagenetic history. The chalks consist primarily of whole and fragmented coccoliths with subordinate planktonic and benthonic Foraminifera, inoceramid prisms, oysters, and other skeletal grains. Most have between 10 and 35 percent HCl-insoluble residue, predominantly clay. Deposition was principally below wave base in tens to hundreds of meters of water. The diagenetic history of a chalk is critical in determining its reservoir potential. All chalk has a stable composition (low-Mg calcite) and very high primary porosity. With subsequent burial, mechanical and chemical (solution-transfer) compaction can reduce or completely eliminate pore space. The degree of loss of primary porosity in chalk sections is normally a direct function of the maximum depth to which it has been buried. Pore-water chemistry, pore-fluid pressures, and tectonic stresses also influence rates of cementation. Oil or gas reservoirs of North American chalk fall into three main groups: 1. Areas with thin overburden and significant primary porosity retention (for example, Niobrara Formation of Kansas and eastern Colorado). 2. Areas with thicker overburden but considerable fracturing. Here primary

  17. THE STUDY OF TECHNOLOGICAL PROPERTIES OF PLASTISOLS BASED EMULSION PVC FILLED WITH CHALK GIDROFOBIZIROVANNYM

    Directory of Open Access Journals (Sweden)

    V. A. Sedykh

    2014-01-01

    Full Text Available Baby toys are made using the centrifugal molding plastisol based emulsion of polyvinyl chloride plasticized with dioctylphthalate. To reduce cost and decrease biotelemetry the dioctylphthalate on the surface of the product domestic toys than toys produced in China, there was a necessity of introduction of the filler is chalk from different manufacturers. By using a Brookfield vis-cometer PV-D was studied rheology of filled hydrophobized chalk PVC plastisols in storage conditions for up to 72 hours at temperatures of 14-20°C. It was found that the flow plastisols consistent with pseudo-plastic fluids. Given the flow rates of emulsion PVC plastisols filled to 35 % of the mass. hydrophobized chalk. The influence of the content of the plasticizer dioctylphthalate in a narrow interval (37,0 - 41,4 % of the mass. on the viscosity of polymer pastes and the kinetics of its changes during storage. Revealed a linear dependence of the viscosity of the filled hydrophobized chalk plastisols on the speed of rotation of the spindle of the viscometer and during storage. Given the rate of expansion changes the viscosity of the plastisols of the speed of rotation of the spindle of the viscometer, the rate of change in viscosity and calculation of the initial viscosity. Determined the stability of the dispersion hydrophobized chalk in a colloidal solution of PVC in dioctylphthalate during storage. We determined the variation of the content of chalk (ash with top and bottom layers plastisols height 8 cm after 24 hours storage. It is proved that the temperature of the preparation and storage of polymer pastes were determining factors in the regulation of such technological properties of PVC plastisols in the presence hydrophobized chalkas viscosity, stability of the dispersion of chalk and, consequently, the efficiency of distribution plastisols in the form of a centrifugal molding.

  18. Effects of the restoration mortar on chalk stone buildings

    Science.gov (United States)

    Ion, R. M.; Teodorescu, S.; Ştirbescu, R. M.; Dulamă, I. D.; Şuică-Bunghez, I. R.; Bucurică, I. A.; Fierăscu, R. C.; Fierscu, I.; Ion, M. L.

    2016-06-01

    The monument buildings as components of cultural heritage are exposed to degradation of surfaces and chemical and mechanical degradation, often associated to soiling and irreversible deterioration of the building. In many conservative and restorative works, a cement-based mortar was used without knowing all the adverse effects of this material on the building. This paper deals with the study of the effects of natural cement used in restorative works in the particular case of the Basarabi-Murfatlar Churches Ensemble. Cement-based materials exposed to sulfate present in the chalk stone - gypsum (CaSO4.2H2O), can induce signs of deterioration, due to ettringite ([Ca3Al (OH)612H2O]2(SO4)32H2O) or thaumasite (Ca3[Si(OH)612H2O](CO3)SO4) formation. These phases contribute to strain within the material, inducing expansion, strength loss, spalling and severe degradation. Several combined techniques (XRD, EDXRF, ICP-AES, SEM, EDS, sulphates content, FT-IR and Raman analysis were carried out to put into evidence the effects of them on the building walls.

  19. Diagenesis and porosity reduction in the Late Cretaceous Wyandot Formation, offshore Nova Scotia : a comparison with Norwegian North Sea chalks

    Energy Technology Data Exchange (ETDEWEB)

    Ings, S.J.; MacRae, R.A.; Pe-Piper, G. [Saint Mary' s Univ., Halifax, NS (Canada). Dept. of Geology; Shimeld, J.W. [Natural Resources Canada, Dartmouth, NS (Canada). Geological Survey of Canada, Bedford Inst. of Oceanography

    2005-09-01

    Chalk is an attractive reservoir target for hydrocarbon exploration because even deep sea-buried chalk has the ability to preserve porosities of up to 40 per cent. The preservation of primary porosity is related to diagenesis, resedimentation, over-pressuring and hydrocarbon saturation. In the past 3 decades, large oil and gas discoveries have been made in chalk units in the North Sea, Texas, Colorado and the offshore Scotian Shelf in eastern Canada. Chalks of the Upper Cretaceous Wyandot Formation on the Scotian Shelf have preserved porosities up to 30 per cent and are the reservoir for a small gas and oil discovery in the Primrose N-50 exploration well. The Wyandot Formation extends about 500 km along the length of the margin and consists mostly of limestone with major chalk intervals. It is largely understudied, despite its potential as a hydrocarbon reservoir or seal. In this study, conventional core samples of Wyandot Formation chalk recovered from both the Primrose A-41 and Eagle D-21 wells were analyzed. The depositional history, diagenesis and porosity-reducing mechanisms within the Formation were clarified through scanning electron microscopy, oxygen and carbon isotope analysis, wireline logs and porosity data. The porosity history of North Sea chalks was then compared with that of the Wyandot Formation. It was determined that the Wyandot chalks are in situ pelagic deposits, compared to the allochthonous North Sea chalks. The dominant mechanisms of porosity reduction in the Wyandot chalks are mechanical compaction and dissolution. It is possible that North Sea type allochthonous reservoirs exist in distal locations on the Scotian Slope because large volumes of Wyandot chalk have been eroded on part of the Scotian Shelf. Therefore, further exploration is warranted to provide a better understanding of the sedimentology and porosity distribution of the in situ Wyandot Formation. 20 refs., 2 tabs., 11 figs.

  20. Subaerial Chalk Cliff Failures on the English Channel Coast, Based on Field Data From Recent Collapses

    Science.gov (United States)

    DUPERRET, A.; MARTINEZ, A.; GENTER, A.; MORTIMORE, R. N.; WATREMEZ, P.

    2001-12-01

    The chalk cliffs along the English Channel coast are currently retreating at a mean rate of 0.5 m/year. However, the erosion is not constant over time, but occurs by catastrophic collapses. For the last three years, a minimum of 40 collapses have been observed along the French chalk coastline (120 km long) and about 10 collapses along the English chalk coastline (40 km long). The observed collapsed volumes are varying from 150 000 m3 (Beachy Head, UK) to a few m3, whereas the cliff heights are varying from 20 to 200m. Two kinds of scar extension have been observed on the cliff face: either the lower part only with few volumes involved, either the whole cliff height for the largest events. Two main cases of scar shape have been evidenced: (1) scar with a vertical upper part and a curved lower part with large striations and crushed chalk (Puys, France). The rupture process is an overall sliding process, with tearing of the upper part of the cliff and shearing in its lower part. The failure is mainly controlled by rain-fall and occurred by water pressure increase on impervious marl seams of the chalk (Duperret et al., in press, JCR). (2) scar with a regular and rectilinear profile, without any striation (Birling Gap, UK). The rupture propagates along pre-existing joint sets, parallel oriented to the cliff face. Locally, pre-existing large-scale transverse fractures may bound the lateral propagation of the scar. Where the scars extend all over the cliff height, the failure is mainly controlled by continental water infiltration. However the role of water through fractured chalk may differ according to the fracture pattern. Where the scars are restrained to the lower part of the cliff, the upward extension of the scars are bounded by lithological features of the chalk, as horizontal flint bands or stratification. In this case, the role of marine parameters, as wave impact at the toe of the cliff may be invoked as a significant triggering parameter contributing to failure

  1. Trace fossils of a cyclic chalk-marl succession; the upper Maastrichtian Rørdal Member, Denmark

    DEFF Research Database (Denmark)

    Lauridsen, Bodil Wesenberg; Surlyk, Finn; Bromley, Richard Granville

    2011-01-01

    . The cyclicity is interpreted as caused by orbital changes within the Milankovitch frequency band. The carbonate content varies between 71 and 82 weight% in the marl and 82–92 weight% in the chalk beds. The material is based on 19 samples collected from six chalk and marl beds. The investigated bedding...

  2. Managing Injected Water Composition To Improve Oil Recovery: A Case Study of North Sea Chalk Reservoirs

    DEFF Research Database (Denmark)

    Zahid, Adeel; Shapiro, Alexander; Stenby, Erling Halfdan;

    2012-01-01

    In recent years, many core displacement experiments of oil by seawater performed on chalk rock samples have reported SO42–, Ca2+, and Mg2+ as potential determining ions for improving oil recovery. Most of these studies were carried out with outcrop chalk core plugs. The objective of this study...... is to investigate the potential of the advanced waterflooding process by carrying out experiments with reservoir chalk samples. The study results in a better understanding of the mechanisms involved in increasing the oil recovery with potential determining ions. We carried out waterflooding instead of spontaneous...... with the following injecting fluids: distilled water, brine with and without sulfate, and brine containing only magnesium ions. The total oil recovery, recovery rate, and interaction mechanisms of ions with rock were studied for different injecting fluids at different temperatures and wettability conditions. Studies...

  3. Persistent and emerging micro-organic contaminants in Chalk groundwater of England and France.

    Science.gov (United States)

    Lapworth, D J; Baran, N; Stuart, M E; Manamsa, K; Talbot, J

    2015-08-01

    The Chalk aquifer of Northern Europe is an internationally important source of drinking water and sustains baseflow for surface water ecosystems. The areal distribution of microorganic (MO) contaminants, particularly non-regulated emerging MOs, in this aquifer is poorly understood. This study presents results from a reconnaissance survey of MOs in Chalk groundwater, including pharmaceuticals, personal care products and pesticides and their transformation products, conducted across the major Chalk aquifers of England and France. Data from a total of 345 sites collected during 2011 were included in this study to provide a representative baseline assessment of MO occurrence in groundwater. A suite of 42 MOs were analysed for at each site including industrial compounds (n=16), pesticides (n=14) and pharmaceuticals, personal care and lifestyle products (n=12). Occurrence data is evaluated in relation to land use, aquifer exposure, well depth and depth to groundwater to provide an understanding of vulnerable groundwater settings.

  4. Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge

    DEFF Research Database (Denmark)

    Hansen, H.K.; Christensen, Iben Vernegren; Ottosen, Lisbeth M.;

    2003-01-01

    Electroosmotic dewatering has been tested in laboratory cells on four different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material. Casagra......Electroosmotic dewatering has been tested in laboratory cells on four different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material....... Casagrande's coefficients were determined for the four materials at different water contents. The experiments in this work showed that chalk could be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM by electroosmosis...

  5. Contaminated groundwater characterization at the Chalk River Laboratories, Ontario, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Schilk, A.J.; Robertson, D.E.; Thomas, C.W.; Lepel, E.A. [Pacific Northwest National Lab., Richland, WA (United States); Champ, D.R.; Killey, R.W.D.; Young, J.L.; Cooper, E.L. [Chalk River Labs., Chalk River, Ontario (Canada)

    1993-03-01

    The licensing requirements for the disposal of low-level radioactive waste (10 CFR 61) specify the performance objectives and technical requisites for federal and commercial land disposal facilities, the ultimate goal of which is to contain the buried wastes so that the general population is adequately protected from harmful exposure to any released radioactive materials. A major concern in the operation of existing and projected waste disposal sites is subterranean radionuclide transport by saturated or unsaturated flow, which could lead to the contamination of groundwater systems as well as uptake by the surrounding biosphere, thereby directly exposing the general public to such materials. Radionuclide transport in groundwater has been observed at numerous commercial and federal waste disposal sites [including several locations within the waste management area of Chalk River Laboratories (CRL)], yet the physico-chemical processes that lead to such migration are still not completely understood. In an attempt to assist in the characterization of these processes, an intensive study was initiated at CRL to identify and quantify the mobile radionuclide species originating from three separate disposal sites: (a) the Chemical Pit, which has received aqueous wastes containing various radioisotopes, acids, alkalis, complexing agents and salts since 1956, (b) the Reactor Pit, which has received low-level aqueous wastes from a reactor rod storage bay since 1956, and (c) the Waste Management Area C, a thirty-year-old series of trenches that contains contaminated solid wastes from CRL and various regional medical facilities. Water samples were drawn downgradient from each of the above sites and passed through a series of filters and ion-exchange resins to retain any particulate and dissolved or colloidal radionuclide species, which were subsequently identified and quantified via radiochemical separations and gamma spectroscopy. These groundwaters were also analyzed for anions

  6. Potential for isoproturon, atrazine and mecoprop to be degraded within a chalk aquifer system

    Science.gov (United States)

    Johnson, Andrew C.; White, Craig; Lal Bhardwaj, C.

    2000-06-01

    The potential for herbicide degradation in an unconfined chalk aquifer was examined by collecting and spiking fresh samples and incubating them in the laboratory. The microcosms were incubated at 20°C under aerobic conditions and spiked with either isoproturon, atrazine or mecoprop at a concentration of 100 μg/l. The samples were obtained from a single fieldsite within the Upper Chalk aquifer in Hampshire, UK. Groundwater samples required the presence of sterile chalk in a ratio of at least 1:13 to promote isoproturon degradation. An isoproturon degradation potential existed in the soil, and the chalk unsaturated and saturated zones. However, no degradation of isoproturon in the unsaturated zone was observed when a more appropriate simulation of in-situ moisture conditions was carried out. Apart from the soil, no potential for atrazine or mecoprop degradation could be detected in the same samples over a 200-day incubation. In a series of groundwater samples taken from different boreholes, 10-300 m apart, large differences in isoproturon degradation potential were observed. Removal rates for 100 μg/l isoproturon varied from 83-425 ng/day, but in some samples no degradation potential could be detected. The primary metabolite which could be distinguished from isoproturon degradation in chalk and groundwater was monodesmethyl-isoproturon. When a chalk groundwater sample was spiked with isoproturon at 0.9 μg/l, this was not degraded over a 300-day incubation period. Further experiments with fresh groundwater from a Triassic Sandstone site illustrated that groundwater bacteria could degrade isoproturon at the more realistic temperature of 10°C as well as at 20°C.

  7. Measuring and Modeling the Displacement of Connate Water in Chalk Core Plugs during Water Injection

    DEFF Research Database (Denmark)

    Korsbech, Uffe C C; Aage, Helle Karina; Andersen, Bertel Lohmann;

    2006-01-01

    The movement of connate water spiked with gamma emitting 22Na was studied during laboratory water flooding of oil saturated chalk from a North Sea oil reservoir. Using a one dimensional gamma monitoring technique is was observed that connate water is piled-up at the front of the injection water...... and forms a mixed water bank with almost 100% connate water in the front behind which a gradual transition to pure injection water occurs. This result underpins log interpretations from waterflooded chalk reservoirs. An ad hoc model was set up by use of the results, and the process was examined...

  8. Aerobic degradation potential of the herbicides mecoprop, dichlorprop and bentazone in groundwater from chalk aquifers

    DEFF Research Database (Denmark)

    Levi, Suzi; Hybel, Anne-Marie; Bjerg, Poul Løgstrup;

    2011-01-01

    The aerobic degradation potential of mecoprop, dichlorprop and bentazone was studied at concentration of 1 μg/L in laboratory batch experiments with groundwater from chalk aquifers. Within the incubation period of 129 days, 14C-mecoprop concentration decreased to 60-80% in the microcosms with gro......The aerobic degradation potential of mecoprop, dichlorprop and bentazone was studied at concentration of 1 μg/L in laboratory batch experiments with groundwater from chalk aquifers. Within the incubation period of 129 days, 14C-mecoprop concentration decreased to 60-80% in the microcosms...

  9. Strength and Biot's coefficient for high-porosity oil- or water-saturated chalk

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling

    . The Biot coefficient states the degree of cementation or how the pore pressure contributes to the strain resulting from an external load for a porous material. It is here calculated from dynamic measurements and correlated with the strength of outcrop chalk characterized by the onset of pore collapse...... during hydrostatic loading. The hypothesis is that the Biot coefficient and the theory of poroelasticity may cover the fluid effect by including the increased fluid bulk modulus from oil to water. A high number of test results for both oil- and water-saturated high-porosity outcrop chalk show correlation...

  10. Rock physical aspects of CO{sub 2} injection in chalk

    Energy Technology Data Exchange (ETDEWEB)

    Alam, M.M.

    2011-04-15

    Impact of supercritical CO{sub 2} on the petrophysical and rock-mechanics properties of Ekofisk Formation and Tor Formation chalk from South Arne field, Danish North Sea, chalk was investigated. A series of laboratory experiments was performed on core material collected from the reservoir zone of the South Arne field in order to reveal the changes with respect to porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical failure. In addition, a theoretical rock physical background was also established in order to be able to make sensible interpretation of laboratory data. Sound wave velocity was used as the central tool to study any change in petrophysical and rock mechanical properties. The main focus was to achieve a better understanding of effective stress coefficient (also known as Biot's coefficient); by means of which effective stress can be predicted more accurately. Independent theoretical studies were made on diagenesis, surface properties and stiffness of chalk and their relation with sonic velocity (or Biot's coefficient calculated from sonic velocity). The knowledge and experience from these studies was combined to achieve the main research objective of monitoring changes in hydrocarbon reservoirs in chalk due to CO{sub 2} injection. In order to understand the development of chalk from calcareous ooze and achieving pore stiffness, the diagenesis process of a sedimentary sequence from Kerguelen Plateau in the Indian Ocean was studied. The principal objective of the study was to explore how different porosity reduction mechanisms change the strength of these deep sea carbonate-rich sediments and how these mechanisms can be traced from the change in Biot's coefficient, alpha. In calcareous ooze, alpha was found close to one. Mechanical compaction reduces porosity, but only leads to a minor decrease in alpha. Recrystallization process renders particles smoother, but do not lead to reduction in alpha unless it gives

  11. Effect of fluid-solid friction on the stiffness of chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Nguh Akam, Hosea; Fabricius, Ida Lykke

    2011-01-01

    Chalks behave weaker at water saturated condition. We studied this softening effect as a function of Biot’s frequency ratio, which is a ratio between measured ultrasonic wave frequency and Biot critical frequency, fc. Kinematic viscosity of fluid and permeability of rock determines fc. We observe...

  12. SNG-log in borehole P7 in Faxe Chalk Quarry

    DEFF Research Database (Denmark)

    Korsbech, Uffe C C

    1996-01-01

    A spectral natural gamma-ray log in a 190 m borehole in Faxe chalk quarry confirms that Danish bryozoan and corallic limestones contain very low levels of natural radioactivity. Due to the low content of natural radioactivity it has been possible to observe the influence from cosmic radiation...

  13. Effective-stress-law behavior of Austin chalk rocks for deformation and fracture conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Warpinski, N.R.; Teufel, L.W.

    1994-08-01

    Austin chalk core has been tested to determine the effective law for deformation of the matrix material and the stress-sensitive conductivity of the natural fractures. For deformation behavior, two samples provided data on the variations of the poroelastic parameter, {alpha}, for Austin chalk, giving values around 0.4. The effective-stress-law behavior of a Saratoga limestone sample was also measured for the purpose of obtaining a comparison with a somewhat more porous carbonate rock. {alpha} for this rock was found to be near 0.9. The low {alpha} for the Austin chalk suggests that stresses in the reservoir, or around the wellbore, will not change much with changes in pore pressure, as the contribution of the fluid pressure is small. Three natural fractures from the Austin chalk were tested, but two of the fractures were very tight and probably do not contribute much to production. The third sample was highly conductive and showed some stress sensitivity with a factor of three reduction in conductivity over a net stress increase of 3000 psi. Natural fractures also showed a propensity for permanent damage when net stressed exceeded about 3000 psi. This damage was irreversible and significantly affected conductivity. {alpha} was difficult to determine and most tests were inconclusive, although the results from one sample suggested that {alpha} was near unity.

  14. The Effect of Magnesium Carbonate (Chalk) on Geometric Entropy, Force, and Electromyography During Rock Climbing.

    Science.gov (United States)

    Kilgas, Matthew A; Drum, Scott N; Jensen, Randall L; Phillips, Kevin C; Watts, Phillip B

    2016-12-01

    Rock climbers believe chalk dries the hands of sweat and improves the static coefficient of friction between the hands and the surface of the rock. The purpose of this study was to assess whether chalk affects geometric entropy or muscular activity during rock climbing. Nineteen experienced recreational rock climbers (13 males, 6 females; 173.5 ± 7.0 cm; 67.5 ± 3.4 kg) completed 2 climbing trails with and without chalk. The body position of the climber and muscular activity of the finger flexors was recorded throughout the trial. Following the movement sequence participants hung from a standard climbing hold until they slipped from the climbing structure, while the coefficient of friction and the ratio of the vertical forces on the hands and feet were determined. Although there were no differences in the coefficient of friction (P = .748), geometric entropy (P = .359), the ratio of the vertical forces between the hands and feet (P = .570), or muscular activity (P = .968), participants were able to hang longer after the use of chalk 62.9 ± 36.7 s and 49.3 ± 25.2 s (P = .046). This is advantageous because it may allow for prolonged rests, and more time to plan the next series of climbing moves.

  15. Full-waveform Inversion of Crosshole GPR Data Collected in Strongly Heterogeneous Chalk

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Zibar, Majken Caroline Looms; Nielsen, Lars

    2015-01-01

    Chalk is an important reservoir rock for hydrocarbons and for groundwater resources for many major cities. Therefore, this rock type has been extensively investigated using both geological and geophysical methods. Many applications of crosshole GPR tomography rely on the ray approximation and cor...

  16. Waveform analysis of crosshole GPR data collected in heterogeneous chalk deposits

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Nielsen, Lars; Zibar, Majken Caroline Looms

    2014-01-01

    Chalks are important reservoirs for groundwater production onshore Denmark and for hydrocarbons in the North Sea Basin. Therefore this rock type is studied extensively with geological and geophysical methods. Ground-penetrating radar (GPR) tomography is used to characterize fine-scale reservoir p...

  17. Seismic architecture of the Chalk Group from onshore reflection data in eastern Denmark

    DEFF Research Database (Denmark)

    Moreau, Julien; Anderskouv, Kresten; Boldreel, Lars Ole

    The Upper Cretaceous-Danian chalk is well exposed in the 14 km long coastal cliff of Stevns Klint (eastern Denmark). The cliff is a world renowned for its spectacular exposure of the Cretaceous-Palaeogene boundary. Based on regional geological knowledge of the field and cores, the characteristics...

  18. Sedimentology of the late cretaceous and early tertiary (tuffaceous) chalk of Northwest Europe

    NARCIS (Netherlands)

    Zijlstra, J.J.P.

    1994-01-01

    The Tuffaceous Chalk of South Limburg (The Netherlands), a friable, porous, bioclastic carbonate sandstone, became subject of scientific interest in 1770, when workers found a large skull of Mososourus comperi in the subterranean quarry of Mount St. Pieter near Maastricht. After Dumont (1849) had co

  19. Seismic stratigraphy and sedimentary architecture of the Chalk Group in south-west Denmark

    DEFF Research Database (Denmark)

    Larsen, Connie; Ineson, Jon; Boldreel, Lars Ole

    2014-01-01

    The article focuses on a study undertaken by the Chalk Group on the western onshore region of the Danish Basin in Eastern Denmark related on the seismic stratigraphy and sedimentary architecture of the region. The study is undertaken through subdividing the northern North German Basin and the south...

  20. The effect of calabash chalk on some hematological parameters in female adult Wistar rats

    Directory of Open Access Journals (Sweden)

    Amabe Otoabasi Akpantah

    2010-09-01

    Full Text Available Objective: Calabash chalk is a naturally occurring mineral consumed among the Nigerian community for pleasure and commonly by pregnant women as a remedy for morning sickness. Reports have shown that it contains different toxic substances, with lead being the most abundant. This study was therefore undertaken to ascertain the effect of two commonly available preparations of this chalk on some hematological parameters.Materials and Methods: Twenty-four adult female Wistar rats with average weight of 100 g were assigned into three groups (1, 2, 3. Group 1 served as the control and the animals received distilled water, while Groups 2 and 3 were treated by oral gavage with 40 mg/kg of non-salted (NSCC and salted calabash chalk (SCC, respectively, for 14 days.Results: The hemoglobin (Hb concentration and red blood cell (RBC count were significantly (p<0.05, 0.001 respectively lower in the NSCC group, while erythrocyte sedimentation rate (ESR was significantly (p<0.05 higher in the NSCC group compared to the control. There were no significant differences in packed cell volume (PCV, white blood cell (WBC and platelet (Pl counts compared to the control. The SCC group presented no significant difference in all blood count parameters compared to the control.Conclusion: This infers that calabash chalk, particularly the non-salted form, alters the normal concentration of Hb, RBC and Pl counts, and ESR, as observed in the female Wistar rats studied.

  1. Nuclear Magnetic Resonance and Elastic Wave Velocity of Chalk Saturated with Brines Containing Divalent Ions

    DEFF Research Database (Denmark)

    Katika, Konstantina; Alam, Mohammad Monzurul; Fabricius, Ida Lykke

    Nuclear magnetic resonance (NMR) has proven a good technique for measuring pore size distribution in reservoir rocks. The use of low field NMR together with sonic and electrical resistivity measurements, can contribute to illustrate the effect of adsorbing ions on chalk elasticity. NMR is useful...

  2. Nuclear magnetic resonance and sound velocity measurements of chalk saturated with magnesium rich brine

    DEFF Research Database (Denmark)

    Katika, Konstantina; Alam, Mohammad Monzurul; Fabricius, Ida Lykke

    2013-01-01

    The use of low field Nuclear Magnetic Resonance (NMR) to determine petrophysical properties of reservoirs has proved to be a good technique. Together with sonic and electrical resistivity measurements, NMR can contribute to illustrate the changes on chalk elasticity due to different pore water...

  3. Calabash Chalk's Geophagy Affects Gestating Rats' Behavior and the Histomorphology of the Cerebral Cortex

    Directory of Open Access Journals (Sweden)

    Moses B. Ekong

    2014-01-01

    Full Text Available Introduction. Calabash chalk contains heavy metals, and this lead to this study on the effect of this chalk on the behavior and the histomorphology of the cerebral cortex of gestating rats. Material & Methods. 24 female rats were equally divided into 4 groups and were mated at preostrous with the males. The day after mating was designated as day 1 of gestation. On gestation days 7–20, groups 1, 2, 3, and 4 animals were treated with 1 mL of distilled water, and 1 mL (200 mg/kg, 2 mL (400 mg/kg, and 3 mL (600 mg/kg of calabash chalk suspension, respectively. On pregnancy day 21, behavioral tests using the open field and the light/dark mazes were carried out and the animals subsequently euthanized and their brains were routinely processed. Results. There was no difference in ambulatory activities, but group 4 animals had more (P<0.05 transition frequency and were more averse to the dark in the light and dark field, while sections of the cerebral cortex showed a higher (P<0.05 cellular population, hypertrophied pyramidal cells, and vacuolations in the treatment groups. Conclusion. Calabash chalk may have anxiolytic effect especially at high dose in the light and dark field but not in the open field and can stimulate maternal cerebral cortical cellular changes.

  4. The surface reactivity of chalk (biogenic calcite) with hydrophilic and hydrophobic functional groups

    Science.gov (United States)

    Okhrimenko, D. V.; Dalby, K. N.; Skovbjerg, L. L.; Bovet, N.; Christensen, J. H.; Stipp, S. L. S.

    2014-03-01

    The surface properties of calcium carbonate minerals play an important role in a number of industrial and biological processes. Properties such as wettability and adsorption control liquid-solid interface behaviour and thus have a strong influence on processes such as biomineralisation, remediation of aquifers and oil recovery. We investigated how two model molecules of different polarity, namely water and ethanol, interact with reservoir and outcrop chalk samples and we compared their behaviour with that of pure, inorganically precipitated calcite. Thermodynamic quantities, such as the work of wetting, surface energy and isosteric adsorption enthalpy, were determined from vapour adsorption isotherms. The chalks were studied fresh and after extraction of organic residues that were originally present in these samples. The work of wetting correlates with the amount of organic matter present in the chalk samples but we observed a fundamental difference between the adsorption properties of chalk and pure, inorganically precipitated calcite toward the less polar, ethanol molecule. Further analysis of the chemical composition of the organic matter extracted from the chalk samples was made by gas chromatography (GC-MS). Monitoring surface composition by X-ray photoelectron spectroscopy (XPS) before and after extraction of the organic material, and with atomic force microscopy (AFM), showed that nanometer sized clay crystals observed on the chalk particle surfaces could be an important part of the reason for the differences. Removal of the extractable portion of the hydrocarbons liberates adsorption sites that have different wetting properties than the rest of the chalk and these have an energy distribution that is similar to clays. Thus, the results exemplify the complexity of biogenic calcite adsorption behaviour and demonstrate that chalk wetting in drinking water aquifers as well as oil reservoirs is controlled partly by the nanoparticles of clay that have grown on the

  5. Benthic macrofauna variations and community structure in Cenomanian cyclic chalk-marl from Southerham Grey Pit, SE England

    DEFF Research Database (Denmark)

    Lauridsen, Bodil Wesenberg; Gale, A. S.; Surlyk, Finn

    2009-01-01

    Cenomanian chalk-marl couplets from England represent the 20 ka Milankovitch precession cycle. Fossil communities from both chalk and marl are identified to test if the orbital fluctuations and the associated changes in substrate lithology and climate exerted any control on the benthic macrofauna...... adapted to both facies and thus to the fine grain size of the substrate rather than to lithology. The systematic difference in diversity between chalk and marl samples was possibly caused by long-term climatic and oceanographic changes and thus could represent a biological response to Milankovitch...

  6. Porosity and sonic velocity depth trends of Eocene chalk in Atlantic Ocean: Influence of effective stress and temperature

    DEFF Research Database (Denmark)

    Awedalkarim, Ahmed; Fabricius, Ida Lykke

    2014-01-01

    . This indicates pore-filling cementation via an activation energy mechanism. We proposed a predictive equation for porosity reduction with burial stress. This equation is relevant for basin analysis and hydrocarbon exploration to predict porosity if sonic velocity data for subsurface chalk is available.......We aimed to relate changes in porosity and sonic velocity data, measured on water-saturated Eocene chalks from 36 Ocean Drilling Program drill sites in the Atlantic Ocean, to vertical effective stress and thermal maturity. We considered only chalk of Eocene age to avoid possible influence...... of geological age on chalk compaction trends. For each depth, vertical effective stresses as defined by Terzaghi and by Biot were calculated. We used bottom-hole temperature data to calculate the time–temperature index of thermal maturity (TTI) as defined by Lopatin. Porosity and compressional wave velocity...

  7. Water weakening of chalk explaied from a fluid-solid friction factor

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2010-01-01

    were tested at temperatures from 20°C to 130°C with the following pore fluids: fresh water, synthetic seawater of different chemical compositions, methanol, glycol, and oil of varying viscosity. The data was evaluated according to failure lines and yield envelopes for all fluids and temperatures while...... to the macroscale failure and pore collapse properties. The Biot critical frequency incorporates the porosity, permeability, fluid density and fluid viscosity, where the latter is highly temperature dependent – it does not include the applied sound velocity frequency. The listed parameters are usually determined...... during laboratory tests and the fluid viscosity and density may be found in tabulated references. There exist a number of previously published laboratory test results on chalk which was collected from Brazilian, unconfined compression and triaxial tests. The data spans four different chalk types which...

  8. Change of Static and Dynamic Elastic Properties due to CO² Injection in North Sea Chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, M.L.; Christensen, H.F.;

    2012-01-01

    Reservoir modeling and monitoring uses dynamic data for predicting and determining static changes. Dynamic data are achieved from the propagation velocity of elastic waves in rock while static data are obtained from the mechanical deformation. Reservoir simulation and monitoring are particularly......% non-carbonate. We studied difference in static and dynamic behavior. Furthermore, brine saturated data were compared with CO2 injected data to reveal the effect of supercritical CO2 injection in both static and dynamic elastic properties. We used strain gauges and LVDTs to measure static deformation....... We observed lower dynamic elastic modulus for chalk with higher non-carbonate content at porosities lower than 30%. In 30% porosity chalk, dynamic compressional and bulk modulus were found significantly higher than the static modulus. Static measurements with LVDT were found lowest. The effect of CO2...

  9. Burial diagenesis of deep sea chalk as reflected in Biot's coefficient

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Alam, Mohammad Monzurul

    2013-01-01

    to limestone as burial increases and porosity decreases. The porosity decrease is accompanied by an increasing velocity to elastic waves, and consequently a decreasing Biot's coefficient, as estimated from velocity and density of core samples. When the effective burial stress is normalized to total horizontal...... cross sectional area, the porosity is found to decline as a function of stress. The porosity trend proceeds smoothly from ooze over chalk to limestone. By contrast, when vertical effective stress is normalized to grain contact area, each lithology shows a distinct porosity-decline - stress pattern....... In the ooze, we find that the natural compaction causes an increasing stress on grain contact area, indicating that the ooze particles become strongly strained. In the chalk section, contact cement is probably the reason why particles become less strained as porosity declines. In the limestone, stress...

  10. Burial diagenesis of deep sea chalk as reflected in Biot’s coefficient

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Alam, Mohammad Monzurul

    to limestone as burial increases and porosity decreases. The porosity decrease is accompanied by an increasing velocity to elastic waves, and consequently a decreasing Biot’s coefficient, as estimated from velocity and density of core samples. When the effective burial stress is normalized to total horizontal...... cross sectional area, the porosity is found to decline as a function of stress. The porosity trend proceeds smoothly from ooze over chalk to limestone. By contrast, when vertical effective stress is normalized to grain contact area, each lithology shows a distinct porosity-decline - stress pattern....... In the ooze, we find that the natural compaction causes an increasing stress on grain contact area, indicating that the ooze particles become strongly strained. In the chalk section, contact cement is probably the reason why particles become less strained as porosity declines. In the limestone, stress...

  11. How burial diagenesis of chalk sediments controls sonic velocity and porosity

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2003-01-01

    to the progress of burial diagenesis of chalk, which is revised as follows: Newly deposited carbonate ooze and mixed sediments range in porosity from 60 to 80%, depending on the prevalence of hollow microfossils. Despite the high porosity, these sediments are not in suspension, as reflected in IFs of 0.......1 or higher. Upon burial, the sediments lose porosity by mechanical compaction, and concurrently, the calcite particles recrystallize into progressively more equant shapes. High compaction rates may keep the particles in relative motion, whereas low compaction rates allow the formation of contact cement......, whereby IF increases and chalk forms. Rock mechanical tests show that when compaction requires more than in-situ stress, porosity reduction is arrested. During subsequent burial, crystals and pores grow in size as a consequence of the continuing recrystallization. ne lack of porosity loss during...

  12. Common Directions in Caucasian Chalk Circle and Keşanlı Ali Destanı

    OpenAIRE

    ODACI, Serdar

    2016-01-01

    Epic Theater founded by Bertolt Brecht influenced world literaturein the half of 20th century. Epic theater is against to Aristothalesian Theater.Naturally Brehct's plays were translated to Turkish and were presented. SuchTurkish writers as Haldun Taner and Vasıf Öngeren wrote play according toepic theater concept. In this paper common aspects in Keşanlı Ali Destanıand Caucasian Chalk Circle are examined.

  13. "Common Directions in Caucasian Chalk Circle and Keşanlı Ali Destanı"

    OpenAIRE

    ODACI, Serdar

    2010-01-01

    Epic Theater founded by Bertolt Brecht influenced world literature in the half of 20th century. Epic theater is against to Aristothalesian Theater. Naturally Brehct's plays were translated to Turkish and were presented. Such Turkish writers as Haldun Taner and Vasıf Öngeren wrote play according to epic theater concept. In this paper common aspects in Keşanlı Ali Destanı and Caucasian Chalk Circle are examined.

  14. Full-waveform inversion of cross-hole GPR data collected in a strongly heterogeneous chalk reservoir analogue with sharp permittivity and conductivity contrasts

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Zibar, Majken Caroline Looms; Moreau, Julien

    2014-01-01

    Chalk sediments form an important reservoir for groundwater onshore and for hydrocarbons in the Danish sector of the North Sea. Cross-hole Ground-penetrating radar (GPR) tomography is an efficient method to investigate subtle porosity variations in the chalk. Traditional ray-based inversion techn...

  15. Biot critical frequency applied as common friction factor for pore collapse and failure of chalk with different pore fluids and temperatures

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke; Foged, Niels Nielsen

    2011-01-01

    A fluid effect toward higher strengths for oil-saturated chalk compared with water-saturated chalk has previously been identified and labeled the "water-weakening phenomenon," but has not been further characterized physically. The hypothesis of this paper is that the Biot critical frequency...

  16. High resolution microgravity investigations for the detection and characterisation of subsidence associated with abandoned, coal, chalk and salt mines

    Energy Technology Data Exchange (ETDEWEB)

    Styles, P.; Toon, S.; Branston, M.; England, R. [Keele Univ., Applied And Environmental Geophysics Group, School of Physical and Geographical Sciences (United Kingdom); Thomas, E.; Mcgrath, R. [Geotechnology, Neath (United Kingdom)

    2005-07-01

    The closure and decay of industrial activity involving mining has scarred the landscape of urban areas and geo-hazards posed by subsurface cavities are ubiquitous throughout Europe. Features of concern consist of natural solution cavities (e.g. swallow holes and sinkholes in limestone gypsum and chalk) and man-made cavities (mine workings, shafts) in a great variety of post mining environments, including coal, salt, gypsum, anhydrite, tin and chalk. These problems restrict land utilisation, hinder regeneration, pose a threat to life, seriously damage property and services and blight property values. This paper outlines the application of microgravity techniques to characterise abandoned mining hazard in case studies from Coal, Chalk and Salt Mining environments in the UK. (authors)

  17. Mechanical and chemical processes affecting the chalk during burial, insights from combined reflection seismics, well data and field work

    DEFF Research Database (Denmark)

    Moreau, Julien; Boussaha, Myriam; Thibault, Nicolas Rudolph

    2014-01-01

    and cores analyses, respectively.However, few sites allow to combine all the different scale of observation for chalk diagenesis. Onshore and offshore high resolution seismics, two fully cored >350 m wells with wireline logging tools and very high quality exposures from a coastal cliff and a quarry form...... works have been performed with astronomical calibration based on stable isotope stratigraphy, wireline logs as well as several palaeontological proxies and detailed sedimentological analysis. Since a couple of decades, a specific kind of fractures has been described in the Chalk of Denmark, the so......-called hairline fractures. They have recently been interpreted as compaction bands associated with the pore collapse of the chalk. We have observed these fractures on the field and on the cores in specific intervals. At depth, these fractures are in genetic relation with the formation of some stylolithes...

  18. Response of invertebrates from the hyporheic zone of chalk rivers to eutrophication and land use.

    Science.gov (United States)

    Pacioglu, Octavian; Moldovan, Oana Teodora

    2016-03-01

    Whereas the response of lotic benthic macroinvertebrates to different environmental stressors is a widespread practice nowadays in assessing the water and habitat quality, the use of hyporheic zone invertebrates is still in its infancy. In this study, classification and regression trees analysis were employed in order to assess the ecological requirements and the potential as bioindicators for the hyporheic zone invertebrates inhabiting four lowland chalk rivers (south England) with contrasting eutrophication levels (based on surface nitrate concentrations) and magnitude of land use (based on percentage of fine sediments load and median interstitial space). Samples of fauna, water and sediment were sampled twice, during low (summer) and high (winter) groundwater level, at depths of 20 and 35 cm. Certain groups of invertebrates (Glossosomatidae and Psychomyiidae caddisflies, and riffle beetles) proved to be good indicators of rural catchments, moderately eutrophic and with high fine sediment load. A diverse community dominated by microcrustaceans (copepods and ostracods) were found as good indicators of highly eutrophic urban streams, with moderate-high fine sediment load. However, the use of other taxonomic groups (e.g. chironomids, oligochaetes, nematodes, water mites and the amphipod Gammarus pulex), very widespread in the hyporheic zone of all sampled rivers, is of limited use because of their high tolerance to the analysed stressors. We recommend the use of certain taxonomic groups (comprising both meiofauna and macroinvertebrates) dwelling in the chalk hyporheic zone as indicators of eutrophication and colmation and, along with routine benthic sampling protocols, for a more comprehensive water and habitat quality assessment of chalk rivers.

  19. On the origin of laminated-bioturbated chalk cycles in the Upper Maastrichtian, Danish Central Graben

    Energy Technology Data Exchange (ETDEWEB)

    Ineson, J.R.; Buchardt, B.; Lassen, S.; Rasmussen, J.A.; Schovsbo, N.H.; Schioeler, P.; Sheldon, E.; Surlyk, F.

    2004-07-01

    Metre-scale laminated-bioturbated chalk cycles form a characteristic motif in the lower levels of the Upper Maastrichtian chalks in the Dan Field area, southern Danish Central Graben. They have most recently been interpreted in the literature to reflect cycles of relative oxygenation on the sea floor, the laminated half-cycles recording poorly oxygenated conditions. Sedimentological, isotopic, palynofacies and palaeoecological (nannofossils, dinoflagellates, foraminifers) analysis was undertaken of a close suite of samples across a composite cyclic interval to investigate the validity of this interpretation and the possible factors controlling periodic variation in bottom-water ventilation. The data from benthic organisms clearly demonstrate a hostile sea-floor environment and outline a cyclicity in bottom water conditions that parallels, yet is lightly out of phase with, the laminated-bioturbated cycles. Interestingly, the planktonic foraminiferal data suggest that during periods with the most hostile bottom water conditions, the upper water masses were relatively stable whereas slight amelioration at the sea floor coincided with stressed, changeable conditions in the surface waters. Data from palynofacies and dinoflagellate analysis indicate a low productivity, oligotrophic setting and no evidence of relative sea-level variation in phase with the cycles is observed. Similarly, the calcareous plankton show no indications of major productivity peaks related to the onset of lamination in the sediment; conversely, minor peaks in productivity indicators in the nannofossil dataset correlate with the transition from laminated to bioturbated chalk i.e. are the result, rather than the cause of oxygen deprivation at the sea floor. On the basis of these data, it is proposed that these short-term cycles were probably controlled by cyclic variations in mean wind stress resulting in the alternation of a weakly stratified shelf sea, in which local dysoxia developed in

  20. Electrical tortuosity, Kozeny’s factor and cementation factor modelled for chalk

    DEFF Research Database (Denmark)

    Katika, Konstantina; Fabricius, Ida Lykke

    2015-01-01

    Based on the electrical properties of chalk from the North Sea and Stevns Klint and on published data, we explore how klinkenberg corrected permeability from experimental data relate to porosity and electrical resistivity. In the current study we use electrical conductivity data of partially water......, to calculate permeability based on electrical resistivity data. We also calculate the permeability based on a simple porosity model. Finally, we redefine Kozeny’s factor, c, using Carman’s model based on tortuosity and the model based on porosity. This resulted in a third modelled permeability, which describes...

  1. Optimization of Spore Forming Bacteria Flooding for Enhanced Oil Recovery in North Sea Chalk Reservoir

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna;

    2015-01-01

    was used for this purpose. A spore forming bacterium, Bacillus licheniformis 421, was used as it was shown to be a good candidate in the previous study. Bacterial spore can penetrate deeper into the chalk rock, squeezing through the pore throats. Our results show that B. licheniformis 421 when injected...... as a secondary technique can recover 4% more of the original oil in place (OOIP) as compared with the seawater flooding. Furthermore, when applied as tertiary technique it can recover 1.4% OOIP of the residual oil. The effective permeability decreased in the first two sections of the core (0-1.2 cm and 1...

  2. What are the governing processes during low-flows in a chalk catchment?

    Science.gov (United States)

    Lubega Musuuza, Jude; Coxon, Gemma; Hutton, Chris; Howden, Nicholas; Woods, Ross; Freer, Jim; Wagener, Thorsten

    2016-04-01

    Low flows are important because they lead to the prioritisation of different consumptive water usages, imposition of restrictions and bans, raising of water tariffs and higher production costs to industry. The partitioning of precipitation into evaporation, storage and runoff depends on the local variability in meteorological variables and site-specific characteristics e.g., topography, soils and vegetation. The response of chalk catchments to meteorological forcing especially precipitation is of particular interest because of the preferential flow through the weathered formation. This makes the observed stream discharge groundwater-dominated and hence, out of phase with precipitation. One relevant question is how sensitive the low flow characteristics of such a chalk catchment is to changes in climate and land use. It is thus important to understand all the factors that control low stream discharge periods. In this study we present the results from numerical sensitivity analysis experiments performed with a detailed physically-based model on the Kennet, a sub-catchment of the River Thames, in the UK during the historical drought years of the 1970's.

  3. The stability of chalk during flooding of carbonated sea water at reservoir in-situ conditions

    Science.gov (United States)

    Nermoen, Anders; Korsnes, Reidar I.; Madland, Merete V.

    2014-05-01

    Injection of CO2 into carbonate oil reservoirs has been proposed as a possible utilization of the captured CO2 due to its capability to enhance the oil recovery. For offshore reservoirs such as Ekofisk and Valhall it has been discussed to alternate the CO2 and sea water injection (WAG) to reduce costs and keep the beneficial effects of both sea water (SSW) and gas injection. Water and CO2 mix to form carbonic acids that enhance the solubility of carbonates, thus a serious concern has been raised upon the potential de-stabilization of the reservoirs during CO2 injection. In this study we focus on how carbonated sea water alters the mechanical integrity of carbonate rocks both to evaluate safety of carbon storage sites and in the planning of production strategies in producing oil fields since enhanced compaction may have both detrimental and beneficial effects. Here we will present results from long term experiments (approx. half year each) performed on Kansas outcrop chalk (38-41% porosity), which serves as model material to understand the physical and chemical interplaying processes taking place in chalk reservoirs. All tests are performed at uni-axial strain conditions, meaning that the confining radial stresses are automatically adjusted to ensure zero radial strain. The tests are performed at in-situ conditions and run through a series of stages that mimic the reservoir history at both Ekofisk and Valhall fields. We observe the strain response caused by the injected brine. The experimental stages are: (a) axial stress build-up by pore pressure depletion to stresses above yield with NaCl-brine which is inert to the chalk; (b) uni-axial creep at constant axial stresses with NaCl-brine; (c) sea water injection; and (d) injection of carbonated water (SSW+CO2) at various mixture concentrations. Two test series were performed in which the pore pressure was increased (re-pressurized) before stage (c) to explore the stress dependency of the fluid induced strain

  4. Mechanical and chemical processes affecting the chalk during burial, insights from combined reflection seismics, well data and field work

    DEFF Research Database (Denmark)

    Moreau, Julien; Boussaha, Myriam; Thibault, Nicolas Rudolph;

    2014-01-01

    and cores analyses, respectively.However, few sites allow to combine all the different scale of observation for chalk diagenesis. Onshore and offshore high resolution seismics, two fully cored >350 m wells with wireline logging tools and very high quality exposures from a coastal cliff and a quarry form...

  5. Population dynamics of three gammarid species (Crustacea, Amphipoda) in a French chalk stream. Part II. Standing crop

    NARCIS (Netherlands)

    Goedemakers, Annemarie

    1981-01-01

    The standing crop of Gammarus pulex pulex (Linnaeus, 1758), G. fossarum Koch in Panzer, 1836 and Echinogammarus berilloni (Catta, 1878) has been studied in a small French chalk stream, the Slack. A brief description of all amphipod species encountered in this river is given, with a key to different

  6. Influence of clay and silica on permeability and capillary entry pressure of chalk reservoirs in the North Sea

    DEFF Research Database (Denmark)

    Røgen, Birte; Fabricius, Ida Lykke

    2002-01-01

    The permeability and capillary entry pressure of chalk reservoirs are controlled by their porosity and specific surface area. Measured permeabilities are in the range 0.025-5.3 mD and are successfully predicted by use of the Kozeny equation. In this paper we focus on the factors that control...

  7. Towards an improved lithostratigraphic subdivision of the chalk group in the Netherlands North Sea area - A seismic stratigraphic approach

    NARCIS (Netherlands)

    Molen, A.S. van der; Wong, Th.E.

    2007-01-01

    In the Netherlands North Sea area, the Chalk Group has thus far been subdivided into the Cenomanian Texel Formation, the Turonian to Maastrichtian Ommelanden Formation and the Danian Ekofisk Formation. This paper describes the attempt to arrive at a more detailed lithostratigraphic subdivision for t

  8. Changes in Specific Surface as observed by NMR, caused by saturation of Chalk with porewater bearing divalent Ions

    DEFF Research Database (Denmark)

    Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

    2014-01-01

    depositional textures. We compared two cases. The first experiments on outcrop chalk with high salinity brines showed that saturation with divalent ions (Mg2+,Ca2+and SO42-) cause major shifts in the T2 distribution curve, probably due to precipitation in the pore space. In a second set of experiments, fluid...

  9. The fissured East Yorkshire Chalk, UK - a 'sustainable' aquifer under stress ?

    Science.gov (United States)

    Elliot, T.; Younger, P. L.; Chadha, D. S.

    2003-04-01

    The fissured Chalk is an important regional aquifer in East Yorkshire, UK, with a large potential for water supply to the Humberside region and especially the City of Hull. It has been exploited since the end of the 19th Century, but although there are more than a dozen long-established pumping wells in the Chalk these currently abstract only 7% of the total recharge the aquifer receives. The classical notion of ‘safe aquifer yield' equates the quantity of groundwater available for abstraction with the long-term natural recharge to the aquifer. An incautious hydrogeologist might be lead to conclude that this is a secure, under-developed resource. In this case study, the aquifer is shown to be already displaying early symptoms of hydrological stress (eg drought effects, overexploitation), and hydrogeochemical indicators point to further effects of anthropogenic pollution impacts in the unconfined aquifer and both recent and ancient saline intrusion in its semi-confined and confined zones. The hydrochemical evidence clearly reveals the importance both of recent aquifer management decisions and palaeohydrogeology in determining the distribution of water qualities within the aquifer. Waters encountered in the confined aquifer are identified as complex (and potentially dynamic) mixtures between recently recharged waters, modern seawater intrusion, and ancient seawater which entered the aquifer many millennia ago. Elliot, T. Younger, P.L. &Chadha, D.S. (1998) The future sustainability of groundwater resources in East Yorkshire - past and present perspectives. In H. Wheater and C. Kirby (Eds.) Hydrology in a Changing Environment, Vol. II, Proc. British Hydrological Society (BHS) International Conference, 6-10 July 1998, Exeter, UK. pp.21-31. Elliot, T., Chadha, D.S. &Younger, P.L. (2001) Water Quality Impacts and Palaeohydrogeology in the East Yorkshire Chalk Aquifer, UK. Quarterly Journal of Engineering Geology and Hydrogeology, 34(4): 385-398. Younger, P.L., Teutsch

  10. Multi isotopic tools to understand selenium origins in groundwaters of the Chalk aquifer in Northern France

    Science.gov (United States)

    Cary, Lise; Gourcy, Laurence; Benabderraziq, Hind; Elkhattabi, Jamal; Laurent, Alexandra; Négrel, Philippe

    2013-04-01

    Four field wells exploiting the Chalk aquifer supply Lille city in water. The little catchment area is submitted to quantitative and qualitative pressure from industrial, urban and agriculture origins. Selenium (Se) concentrations are often higher than EU standards (0.12 µmol.L-1) for potable drinking water and can reach 0.4 μmol.L-1 leading to exploitation restrictions. An integrated study was settled to determine the water sources and dynamics of elements, with a focus on Se, with the goal of managing both water quality and quantity. After a large chemical characterisation of the system, a monthly sampling campaign was held in 2012 in four wells and in the close Deûle channel. In situ physical and chemical parameters, chemical analysis of major and trace elements with a special focus on redox-sensitive elements including SeIV, SeVI, FeII, stable water isotopes (δ18O, δ2H) and δ34S and δ18O of sulphates measures were undertaken. The chemical composition of solids sampled at various depths at vicinity of the four wells was analysed. Se concentrations in groundwaters and in the solid phase vary significantly. In the northern part of the Ansereuilles north of the Deûle channel, where the highest Se concentrations in solids was found in a 13 m alluvial clay deposit above the chalk, a first main type of waters can be defined with the variable and locally highest Se concentrations (0.19 to 0.4 µmol.L-1), relatively high and stable sulphate concentrations (2.5 µmol/L), no nitrates, dissolved Fe and Mn, negative δ34S (around -20 ‰) and δ18O typical of evaporated waters. A second main type of waters can be described at Houplin, south of the Deûle channel, where the geological profile show less than 1 mg/kg of Se, with intermediate Se concentrations (0.1 to 0.2 µmol/L), variable nitrate concentrations (0.4 to 1.2 mmol/L), not quantified dissolved Fe and Mn, sulphate concentrations close to 1.5 mmol/L, variable negative δ34S (-8 to -24 ‰) and δ18O in the

  11. Tracking selenium behaviour in chalk aquifer (northern France): Sr and 34S-sulphates isotopes constraints.

    Science.gov (United States)

    Cary, Lise; Benabderraziq, Hind; Elkhattabi, Jamal; Parmentier, Marc; Gourcy, Laurence; Négrel, Philippe

    2014-05-01

    Groundwaters in parts of the Paris Basin (France) are facing increasing selenium (Se) contents that can exceed the drinking water limit of 10 μg/L according to the European Framework Directive in the field of water policy (2000/60/EC). To better understand the groundwater origins and the selenium dynamics, the water chemistry of the Chalk aquifer supplying drinkable water to Lille city was studied. This area is submitted to quantitative and qualitative pressure from industrial, urban and agriculture origins. An integrated study was settled to determine the water sources and dynamics of elements, with a focus on Se. After a large chemical characterisation of the groundwater chemistry in the four field wells, a monthly monitoring was held in four wells and in the Deûle channel. Chemical analysis of major and trace elements, stable isotopes (δ18O, δ2H), strontium isotopes, and δ34S and δ18O of sulphates were realised. The chemical composition of solids sampled at various depths at vicinity of the four wells was also analysed. The specific geochemical signature of groundwater as revealed by Sr isotopes, in addition to element concentrations ratios like Mg/Sr and Se/Sr, highlighted mixture of three main groundwaters bodies: (1) the upstream groundwaters in the recharge area with the most radiogenic 87Sr/86Sr isotopic signature; (2) the confined groundwaters with high Sr concentrations due to water-rock interactions and the lowest 87Sr/86Sr isotopic signature close to the one of the chalk in Paris and London basins; (3) the Se-rich formations of Tertiary and Quaternary. The contents of Se, mainly present as SeV I (and locally as SeIV ), displayed spatial and temporal disparities that can be explained by geological and hydrogeological conditions. Se-rich clayed sediments originating from the dismantling of Se-rich tertiary formations (i.e. Ypresian) overlay the chalk formation and can be found in saturated conditions depending of the water table level. Oxidation of

  12. Diagenesis of silica-rich mounded chalk, the Coniacian Arnager Limestone, Denmark

    DEFF Research Database (Denmark)

    Buus Madsen, Heine; Stemmerik, Lars; Surlyk, Finn

    2010-01-01

    The Coniacian Arnager Limestone Formation is exposed on the Danish island of Bornholm in the Baltic Sea. It is composed of mound-bedded siliceous chalk, and X-ray diffraction and scanning electron microscopy indicate a content of 30-70% insoluble minerals, including authigenic opal-CT, quartz......, clinoptilolite, feldspars, calcite, dolomite, and barite. Opal-CT and clinoptilolite are the most common and constitute 16-53% and 2-9%, respectively. The content of insoluble minerals varies laterally bothwithinthemounds and inplanar beds, and the opal-CT content varies by up to 10% vertically. Themounds...... precipitated in pore water with low silica activity during maximum burial, probably to depths of 200-250 m. The dissolution of sponge spicules and decomposition of the sponge tissue also resulted in the release of Ba2+, Sr2+,Mg2+, Ca2+ and CO3 2-, facilitating precipitation of barite and dolomite...

  13. Change in Biot's effective stress coefficient of chalk during pore collapse

    DEFF Research Database (Denmark)

    Alam, M. Monzurul; Fabricius, Ida Lykke

    2013-01-01

    the grains could also change during elastic deformation of the grains in a rock mechanics test. Diagenetic change in grain contact cement of chalk can be compared with stress-induced change in the laboratory. The change in porosity is studied with reference to the change in effective stress on grain contacts......Biot's effective stress coefficient (α) is a measure of how well grains in the rocks are connected with each other. The amount of contact cements between the grains determines the stiffness of rocks. Change in grain contact occurs during natural diagenesis of sedimentary rock. Contact between...... and porosity reduces at a slower rate. We noticed that presence of non carbonates and hydrocarbon could increase σ'm. During rock mechanics test in the lab, with increased applied stress, σ'm increases, Biot's effective stress coefficient shows a decreasing trend, while a minor porosity reduction was observed...

  14. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Surlyk, Finn

    2011-01-01

    , including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab­sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites......-slope evolution of debris flows. Debris flows are rep­resented by matrix-supported conglomerates, which form one of the most common facies in the succession. High-concentration, gravity-driven suspension flows passed into dilute visco-plastic flows during the final stages of deposition and resulted......The 331 m long core from the Mona-1 well in the Danish North Sea spans almost the entire Upper Cretaceous Chalk Group but only about 10% of Late Cretaceous time is represented. The succession comprises 14 facies representing pelagic deposition, turbidity flow, and mass-transport processes...

  15. Biological markers in bitumens and pyrolyzates of Upper Cretaceous bituminous chalks from the Ghareb Formation (Israel)

    Science.gov (United States)

    Rullkötter, Jürgen; Aizenshtat, Zeev; Spiro, Baruch

    1984-01-01

    The sterane and triterpane distributions of three bituminous chalks from the Upper Cretaceous Ghareb Formation (Israel) were investigated both in the original extractable bitumens and in extracts obtained after pyrolysis of whole rock and isolated kerogen samples at 450°C. Pyrolysis was performed in a closed system under hydrous (whole rock) and anhydrous conditions (isolated kerogens). The carbon number distributions of steranes and triterpanes differ significantly between original bitumen and pyrolyzates. Unlike the bitumens in which diasteranes were not detected, the anhydrous pyrolyzates contain small amounts of diasteranes. The presence of water during pyrolysis leads to an increase of sterane isomerization, the abundant formation of diasteranes and an increase of the 18α( H)- trisnorneohopane/17α( H)- trisnorhopane ratio. Sterane isomerization maturation parameters show a closer match between original bitumen and pyrolyzates after pyrolysis in a closed system when compared with an open system.

  16. Wettability of Chalk and Argillaceous Sandstones Assessed from T1/T2 Ratio

    DEFF Research Database (Denmark)

    Katika, Konstantina; Saidian, M.; Fabricius, Ida Lykke

    to mineral properties. Thus, longitudinal, T1, and transverse, T2, relaxation times should in principle be similar. However, microscopic magnetic gradients related to minerals can shorten T2 as compared to T1 provided the saturating fluid has high affinity to the solid. We consequently find that the T1/T2...... with water, oil or oil/water at irreducible water saturation. The T1/T2 ratio obtained from T1-T2 maps reflects the T2-shortening. We compare the T1/T2 ratio for the same type of rock, saturated with different fluids. The chalk shows high affinity for water, Berea sandstone has no clear preference for oil...

  17. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge, Danish North Sea: Plate 1

    Directory of Open Access Journals (Sweden)

    Surlyk, Finn

    2011-12-01

    Full Text Available The 331 m long core from the Mona-1 well in the Danish North Sea spans almost the entire Upper Cretaceous Chalk Group but only about 10% of Late Cretaceous time is represented. The succession comprises 14 facies representing pelagic deposition, turbidity flow, and mass-transport processes, including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab¬sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites, and the resultant deposits were thoroughly bioturbated if deposited during normal oxygenation at the sea floor. Periodic benthic dysoxia resulted in the preservation of primary structures, as represented by laminated chalk which consists of thin pelagic laminae alternating with thin turbidites. In addition to the thin turbidites in the laminated chalk, four dif¬ferent turbidite facies are interpreted as representing high- to low-energy flows. Clast-supported chalk conglomerates have previously not been differentiated from other turbidites, but are here interpreted to be directly related to the down-slope evolution of debris flows. Debris flows are rep¬resented by matrix-supported conglomerates, which form one of the most common facies in the succession. High-concentration, gravity-driven suspension flows passed into dilute visco-plastic flows during the final stages of deposition and resulted in the deposition of structureless chalks. Limited shear deformation produced distinct quasi-facies from which the precursor facies can be deduced, whereas intense or continued shear deformation produced a shear-banded quasi-facies from which the precursor facies cannot be deduced in all cases. A series of major slump packages (14–18 in total are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in

  18. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge, Danish North Sea

    Directory of Open Access Journals (Sweden)

    Finn Surlyk

    2011-12-01

    Full Text Available The 331 m long core from the Mona-1 well in the Danish North Sea spans almost the entire Upper Cretaceous Chalk Group but only about 10% of Late Cretaceous time is represented. The succession comprises 14 facies representing pelagic deposition, turbidity flow, and mass-transport processes, including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab¬sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites, and the resultant deposits were thoroughly bioturbated if deposited during normal oxygenation at the sea floor. Periodic benthic dysoxia resulted in the preservation of primary structures, as represented by laminated chalk which consists of thin pelagic laminae alternating with thin turbidites. In addition to the thin turbidites in the laminated chalk, four dif¬ferent turbidite facies are interpreted as representing high- to low-energy flows. Clast-supported chalk conglomerates have previously not been differentiated from other turbidites, but are here interpreted to be directly related to the down-slope evolution of debris flows. Debris flows are rep¬resented by matrix-supported conglomerates, which form one of the most common facies in the succession. High-concentration, gravity-driven suspension flows passed into dilute visco-plastic flows during the final stages of deposition and resulted in the deposition of structureless chalks. Limited shear deformation produced distinct quasi-facies from which the precursor facies can be deduced, whereas intense or continued shear deformation produced a shear-banded quasi-facies from which the precursor facies cannot be deduced in all cases. A series of major slump packages (14–18 in total are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in

  19. The relation among porosity, permeability, and specific surface of chalk from the Gorm field, Danish North Sea

    DEFF Research Database (Denmark)

    Jeanette, Mortensen; Engstrøm, Finn; Lind, Ida

    1998-01-01

    The origin to the difference in the relationship between permeability and porosity for Danian and Maastrichtian chalk from the Gorm field offshore Denmark has been investigated. The investigation was based on 300 sets of core data (He-expansion porosity and air permeability) from the well Gorm N-22......X. On 24 of the core plugs the specific surface was determined by BET and on 14 of these samples image analysis was made. The data was rationalized by the use of the Kozeny equation and it was found that each geologic unit had a characteristic relationship between porosity, permeability and specific...... surface. Furthermore it was found that the nature of porosity (intrafossil, intergranular, etc.) had no significant influence on the air permeability, so that the permeability of the chalk can be calculated from total porosity and specific surface. Kozeny's empirical constant, c, was here determined...

  20. Controls on the spatial and temporal variability of Rn-222 in riparian groundwater in a lowland Chalk catchment.

    OpenAIRE

    Mullinger, Neil J.; Pates, Jackie M.; Binley, Andrew M.; Crook, N. P.

    2009-01-01

    Radon is a powerful tracer of stream-aquifer interactions. However, it is important to consider the source and behaviour of radon in groundwater when interpreting observations of river radon in relation to groundwater discharge. Here we characterise the variability in groundwater radon concentrations in the riparian zone of a Chalk catchment. Groundwater 222Rn (radon) concentrations were determined in riparian zone boreholes at two sites in the Lambourn catchment, Berkshire, UK, over a two ye...

  1. Compaction of North-Sea Chalk by Pore-Failure and Pressure Solution in a Producing Reservoir

    OpenAIRE

    Keszthelyi, Daniel; Dysthe, Dag K.; JAMTVEIT, Bjørn

    2016-01-01

    The Ekofisk field, Norwegian North sea, is an example of a compacting chalk reservoir with considerable subsequent seafloor subsidence due to petroleum production. Previously, a number of models were created to predict the compaction using different phenomenological approaches. Here we present a different approach which includes a new creep model based on microscopic mechanisms with no fitting parameters to predict the strain rate at reservoir scale. The model is able to reproduce the magnitu...

  2. Infrared spectroscopy and density functional theory investigation of calcite, chalk, and coccoliths-do we observe the mineral surface?

    DEFF Research Database (Denmark)

    Andersson, Martin Peter; Hem, Caroline Piper; Schultz, Logan Nicholas

    2014-01-01

    broadening from macroscopic dielectric effects. We detect water adsorbed on the high surface area synthetic calcite, which permits observation of the chemistry of thin liquid films on calcite using transmission infrared spectroscopy. The combination of infrared spectroscopy and density functional theory also...... allowed us to quantify the amount of polysaccharides associated with the coccoliths. The amount of polysaccharides left in chalk, demonstrated to be present in other work, is below the IR detection limit, which is 0.5% by mass....

  3. Dual FIB-SEM 3D Imaging and Lattice Boltzmann Modeling of Porosimetry and Multiphase Flow in Chalk

    Science.gov (United States)

    Rinehart, A. J.; Yoon, H.; Dewers, T. A.; Heath, J. E.; Petrusak, R.

    2010-12-01

    Mercury intrusion porosimetry (MIP) is an often-applied technique for determining pore throat distributions and seal analysis of fine-grained rocks. Due to closure effects, potential pore collapse, and complex pore network topologies, MIP data interpretation can be ambiguous, and often biased toward smaller pores in the distribution. We apply 3D imaging techniques and lattice-Boltzmann modeling in interpreting MIP data for samples of the Cretaceous Selma Group Chalk. In the Mississippi Interior Salt Basin, the Selma Chalk is the apparent seal for oil and gas fields in the underlying Eutaw Fm., and, where unfractured, the Selma Chalk is one of the regional-scale seals identified by the Southeast Regional Carbon Sequestration Partnership for CO2 injection sites. Dual focused ion - scanning electron beam and laser scanning confocal microscopy methods are used for 3D imaging of nanometer-to-micron scale microcrack and pore distributions in the Selma Chalk. A combination of image analysis software is used to obtain geometric pore body and throat distributions and other topological properties, which are compared to MIP results. 3D data sets of pore-microfracture networks are used in Lattice Boltzmann simulations of drainage (wetting fluid displaced by non-wetting fluid via the Shan-Chen algorithm), which in turn are used to model MIP procedures. Results are used in interpreting MIP results, understanding microfracture-matrix interaction during multiphase flow, and seal analysis for underground CO2 storage. This work was supported by the US Department of Energy, Office of Basic Energy Sciences as part of an Energy Frontier Research Center. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Company, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

  4. Mass-transport deposits and reservoir quality of Upper Cretaceous Chalk within the German Central Graben, North Sea

    Science.gov (United States)

    Arfai, Jashar; Lutz, Rüdiger; Franke, Dieter; Gaedicke, Christoph; Kley, Jonas

    2016-04-01

    The architecture of intra-chalk deposits in the `Entenschnabel' area of the German North Sea is studied based on 3D seismic data. Adapted from seismic reflection characteristics, four types of mass-transport deposits (MTDs) are distinguished, i.e. slumps, slides, channels and frontal splay deposits. The development of these systems can be linked to inversion tectonics and halotectonic movements of Zechstein salt. Tectonic uplift is interpreted to have caused repeated tilting of the sea floor. This triggered large-scale slump deposition during Turonian-Santonian times. Slump deposits are characterised by chaotic reflection patterns interpreted to result from significant stratal distortion. The south-eastern study area is characterised by a large-scale frontal splay complex. This comprises a network of shallow channel systems arranged in a distributive pattern. Several slide complexes are observed near the Top Chalk in Maastrichtian and Danian sediments. These slides are commonly associated with large incisions into the sediments below. Best reservoir properties with high producible porosities are found in the reworked chalk strata, e.g. Danish North Sea, therefore MTDs detected in the study area are regarded as potential hydrocarbon reservoirs and considered as exploration targets.

  5. Integrating geophysical and hydrochemical borehole-log measurements to characterize the Chalk aquifer, Berkshire, United Kingdom

    Science.gov (United States)

    Schürch, Marc; Buckley, David

    2002-09-01

    Geophysical and hydrochemical borehole-logging techniques were integrated to characterize hydraulic and hydrogeochemical properties of the Chalk aquifer at boreholes in Berkshire, UK. The down-hole measurements were made to locate fissures in the chalk, their spatial extent between boreholes, and to determine the groundwater chemical quality of the water-bearing layers. The geophysical borehole logging methods used were caliper, focused resistivity, induction resistivity, gamma ray, fluid temperature, fluid electrical conductivity, impeller and heat-pulse flowmeter, together with borehole wall optical-imaging. A multiparameter data transmitter was used to measure groundwater temperature, electrical conductivity, dissolved oxygen, pH, and redox potential of the borehole fluid down-hole. High permeability developed at the Chalk Rock by groundwater circulation provides the major flow horizon at the Banterwick Barn study site and represents a conduit system that serves as an effective local hydraulic connection between the boreholes. The Chalk Rock includes several lithified solution-ridden layers, hardgrounds, which imply a gap in sedimentation possibly representing an unconformity. Lower groundwater temperature, high dissolved-oxygen content, and flowmeter evidence of preferential groundwater flow in the Chalk Rock indicated rapid groundwater circulation along this horizon. By repeating the logging at different times of the year under changing hydraulic conditions, other water-inflow horizons within the Chalk aquifer were recognized. Résumé. Des techniques géophysiques et hydrochimiques de diagraphies en forage ont été mises en oeuvre pour caractériser les propriétés hydrauliques et hydrogéochimiques de l'aquifère de la craie dans des forages du Berkshire (Grande-Bretagne). Les mesures en descente ont été faites pour localiser les fissures dans la craie et leur développement spatial entre forages, et pour déterminer la qualité de l'eau souterraine des

  6. Edibility of sport fishes in the Ottawa River near Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.R.; Chaput, T.; Miller, A.; Wills, C.A., E-mail: leed@aecl.ca [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2013-12-15

    To address the question of edibility of fish in the Ottawa River near Chalk River Laboratories (CRL), 123 game fish were collected for analysis from four locations: Mackey and Rolphton (45 km and 35 km upstream of Chalk River Laboratories (CRL), respectively), the Sandspit (Pointe au Bapteme) and Cotnam Island (1.6 km and 45 km downstream of CRL, respectively). Twenty-six to thirty-six game fish were collected at each location in 2007 and samples of flesh or bone were analyzed. Trap nets were used to collect only the fish required, allowing release of management-sensitive species. The focus was on walleye (Sander vitreus) because they are abundant and popular among anglers. A few northern pike (Esox lucius) and a smaller number of smallmouth bass (Micropterus dolomieui) were also collected at three of the four sites. Samples of the fish were analyzed for cesium-137 ({sup 137}Cs), strontium-90 ({sup 90}Sr), mercury (Hg), and selected organo-chlorine compounds. Concentrations of {sup 137}Cs in the flesh and {sup 90}Sr in the bones of sport fish were low and similar at all four locations and appear to reflect the global residuals from nuclear weapons testing (primarily in the 1960's) as opposed to releases from CRL. Possible explanations are: 1) Reductions in radionuclide releases from CRL in recent decades and 2) Relatively large foraging ranges of sport fish. Mercury concentrations were elevated in fishes in the Ottawa River and were significantly higher at the Sandspit and Rolphton than at Mackey and Cotnam Island (p<0.001). Mercury concentrations from the four sites are comparable to concentrations in other Ontario and Quebec lakes. It is advisable therefore, that consumers follow the fish consumption guidelines issued by provincial authorities when eating fish from the Ottawa River. Organo-chlorine compounds were not detected in walleye; however, they were detected in all eight of the pike collected at Cotnam Island. The highest organo

  7. Fault and fracture patterns in low porosity chalk and their potential influence on sub-surface fluid flow-A case study from Flamborough Head, UK

    Science.gov (United States)

    Sagi, D. A.; De Paola, N.; McCaffrey, K. J. W.; Holdsworth, R. E.

    2016-10-01

    To better understand fault zone architecture and fluid flow in mesoscale fault zones, we studied normal faults in chalks with displacements up to 20 m, at two representative localities in Flamborough Head (UK). At the first locality, chalk contains cm-thick, interlayered marl horizons, whereas at the second locality marl horizons were largely absent. Cm-scale displacement faults at both localities display ramp-flat geometries. Mesoscale fault patterns in the marl-free chalk, including a larger displacement fault (20 m) containing multiple fault strands, show widespread evidence of hydraulically-brecciated rocks, whereas clays smears along fault planes, and injected into open fractures, and a simpler fault zone architecture is observed where marl horizons are present. Hydraulic brecciation and veins observed in the marl-free chalk units suggest that mesoscale fault patterns acted as localized fault conduit allowing for widespread fluid flow. On the other hand, mesoscale fault patterns developed in highly fractured chalk, which contains interlayered marl horizons can act as localized barriers to fluid flow, due to the sealing effect of clays smears along fault planes and introduced into open fractures in the damage zone. To support our field observations, quantitative analyses carried out on the large faults suggest a simple fault zone in the chalk with marl units with fracture density/connectivity decreasing towards the protolith. Where marls are absent, density is high throughout the fault zone, while connectivity is high only in domains nearest the fault core. We suggest that fluid flow in fractured chalk is especially influenced by the presence of marls. When present, it can smear onto fault planes, forming localised barriers. Fluid flow along relatively large displacement faults is additionally controlled by the complexity of the fault zone, especially the size/geometry of weakly and intensely connected damage zone domains.

  8. Evolutionary stability of egg trading and parceling in simultaneous hermaphrodites: the chalk bass revisited.

    Science.gov (United States)

    Crowley, Philip H; Hart, Mary K

    2007-06-07

    Several species of simultaneously hermaphroditic seabasses living on coral reefs mate by alternating male and female roles with a partner. This is known as egg trading, one of the classic and most widely cited examples of social reciprocity among animals. Some of the egg-trading seabass species, including the chalk bass, Serranus tortugarum, switch mating roles repeatedly, having subdivided their clutch of eggs into parcels offered to the partner for fertilization. Here we attempt to understand these dynamics as a pair of evolutionary games, modifying some previous approaches to better reflect the biological system. We find that the trading of egg clutches is evolutionarily stable via byproduct mutualism and resistant to invasion by rare individuals that take the male role exclusively. We note why and how parceling may reflect sexual conflict between individuals in the mating pair. We estimate evolutionarily stable parcel numbers and show how they depend on parameter values. Typically, two or more sequential parcel numbers are evolutionarily stable, though the lowest of these yields the highest fitness. Assuming that parcel numbers are adjusted to local conditions, we predict that parcel numbers in nature are inversely related both to mating group density (except at low density) and predation risk.

  9. Stratigraphy and palaeoceanography of upper Masstrichtian chalks, southern Danish Central Graben

    Energy Technology Data Exchange (ETDEWEB)

    Ineson, J.R.; Buchardt, B.; Lassen, Susanne; Rasmussen, Jan A.; Schioeler, P.; Schovsbo, N.H.; Sheldon, E.; Surlyk, F. [Geological Survey of Denmark and Greenland, Copenhagen (Denmark)

    2006-07-01

    Upper Maastrichtian chalks form important hydrocarbon reservoirs in the Danish sector of the North Sea and have been intensively studied, yet their lithological uniformity can frustrate attempts to develop a high-resolution stratigraphic subdivision and a genetic understanding of the factors controlling production and sedimentation of the pelagic carbonate ooze. Recent research into these topics, by means of a multidisciplinary study involving quantitative/semiquantitative palynology, micropalaeontology (nannofossils, foraminifers) and isotope geochemistry, integrated with detailed sedimentology. Two key wells were selected, the M-1OX well from the Dan Field and the E-5X well from the Tyra SE Field, based on the extensive core coverage in these wells and on their position in the southern part of the Danish Central Graben where evidence of large-scale resedimentation (and consequent stratigraphic complexity) is uncommon within the Maastrichtian section. This study concentrated on a number of palaeoceanographic signals that can be derived from the sedimentary record. Planktonic organisms, both phytoplankton (e.g. coccolithophores, some dinoflagellates) and zooplankton (e.g. foraminifers) provide a record of conditions in the upper watermasses, largely within the photic zone, while bottom conditions are indicated by epifaunal/infaunal organisms (e.g. benthic foraminifers) and bioturbation, and by the sedimentological evidence of depositional processes at the sea floor. (LN)

  10. Scale-up of two-phase flow in heterogeneous chalk. Matrix properties

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    This investigation presents scale-up of a detailed heterogeneous geostatistical model to a full field reservoir simulation model, considering both single and two-phase flow properties. The model represents a typical low permeability Danish North Sea chalk reservoir and includes capillary pressure and saturation end-point variations. Two new up-scaling methods has been investigated, all based on fine scale simulation on a cross section of the geomodel. The first methods assumes piston style behaviour and a coupled viscosity is introduced into the basic Darcy`s equations. The second method is a modification of the JBN method traditionally applied in analysing results from core flooding experiments, which emerged as the most successful and therefore also the recommended method. 1. In addition to the up scaling work we review the Equivalent Radius Method for capillary pressure normalisation with explicit derivation of type functions for Maastrichtian and Danian chalk types. Implementation of the Equivalent Radiuo Method in the COSI reservoir simulator by an optikal set of key-words. There are six specific results from this work: 1. The equivalent radius method is robust to changes of scale and yields model initialisations by initial and irreducible water saturations on a full field simulation scale that agree well with values derived from averaging on a fine-scale. 2. The residual oil saturations are strongly scale dependent and the description of the residual oil as a function of the irreducible water is not applicable on a full field scale and will lead to an overestimation of the residual oil present in the reservoir. The effective residual oil saturations on a full field-scale must be considered functions of the effective initial water saturations, in order to take into account fine-scale variations in the oil/water contacts. 3. The effective permeability as calculated by statistical averages does not differ seriously from results obtained by fine-grid numerical

  11. Seasonal nutrient dynamics in a chalk stream: the River Frome, Dorset, UK.

    Science.gov (United States)

    Bowes, M J; Leach, D V; House, W A

    2005-01-01

    Chalk streams provide unique, environmentally important habitats, but are particularly susceptible to human activities, such as water abstraction, fish farming and intensive agricultural activity on their fertile flood-meadows, resulting in increased nutrient concentrations. Weekly phosphorus, nitrate, dissolved silicon, chloride and flow measurements were made at nine sites along a 32 km stretch of the River Frome and its tributaries, over a 15 month period. The stretch was divided into two sections (termed the middle and lower reach) and mass balances were calculated for each determinand by totalling the inputs from upstream, tributaries, sewage treatment works and an estimate of groundwater input, and subtracting this from the load exported from each reach. Phosphorus and nitrate were retained within the river channel during the summer months, due to bioaccumulation into river biota and adsorption of phosphorus to bed sediments. During the autumn to spring periods, there was a net export, attributed to increased diffuse inputs from the catchment during storms, decomposition of channel biomass and remobilisation of phosphorus from the bed sediment. This seasonality of retention and remobilisation was higher in the lower reach than the middle reach, which was attributed to downstream changes in land use and fine sediment availability. Silicon showed much less seasonality, but did have periods of rapid retention in spring, due to diatom uptake within the river channel, and a subsequent release from the bed sediments during storm events. Chloride did not produce a seasonal pattern, indicating that the observed phosphorus and nitrate seasonality was a product of annual variation in diffuse inputs and internal riverine processes, rather than an artefact of sampling, flow gauging and analytical errors.

  12. Compaction of North-sea chalk by pore-failure and pressure solution in a producing reservoir

    Directory of Open Access Journals (Sweden)

    Daniel eKeszthelyi

    2016-02-01

    Full Text Available The Ekofisk field, Norwegian North sea,is an example of compacting chalk reservoir with considerable subsequent seafloor subsidence due to petroleum production. Previously, a number of models were created to predict the compaction using different phenomenological approaches. Here we present a different approach, we use a new creep model based on microscopic mechanisms with no fitting parameters to predict strain rate at core scale and at reservoir scale. The model is able to reproduce creep experiments and the magnitude of the observed subsidence making it the first microstructural model which can explain the Ekofisk compaction.

  13. Microbial Fluid-Rock Interactions in Chalk Samples and Salinity Factor in Divalent Ca2+ ions Release for Microbial Enhanced Oil Recovery Purposes

    DEFF Research Database (Denmark)

    Jimoh, Ismaila Adetunji; Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen

    2011-01-01

    In this study, laboratory experiments were performed on chalk samples from Danish sector of the North Sea to study microbial fluid-rock interactions with carbonate rock and to evaluate the dissolution of rock matrix (CaCO3). Result showed that the average concentration of Ca2+ ions after microbial...... fluid interactions with chalk samples in media of salinity 40-100g/l increased from initial average concentration of 203 mg/l at the start of the experiment to 1178 mg/l in 28 days. 3-D surface plot (salinity, Ca2+, pH) with time revealed delineation of the measured salinity into two groups...

  14. Distribution and degradation of diesel oil in the unsaturated zone following an oil spill on a chalk aquifer

    Science.gov (United States)

    Ashley, R. P.; Lerner, D. N.; Lloyd, J. W.

    1994-07-01

    In 1976, there occurred a substantial loss of diesel oil from a storage facility at Royston in eastern England. The site is on the outcrop of the important Chalk aquifer, which is protected by an unsaturated zone 24-30 m thick. In 1986, a cored borehole was drilled through the site of the spillage to investigate the fate of the contaminants. The core samples were analysed by physical and chemical methods to determine the physical structure of the rock, and the characteristics and distribution of the oil. The chemically analysed samples included pore water extracts, scrapings from fracture surfaces, and non-fracture (matrix) samples. The results indicate that oil accumulated within a few millimetres of major fissure surfaces, and entry into the rock matrix was limited by the small size of pores and the presence of water. Oil may also have migrated along microscopic channels away from the major fissures. There was no evidence of downward migration of oil since the initial phase of movement. The adoption of certain assumptions regarding degradation, evaporation and dissolution processes allows the estimation of oil depletion caused by these processes. Physical weathering and degradation were found to have been extensive, but highly variable. Both processes occurred on the major fissure surfaces but, in the matrix, degradation appears to have been restricted. The conclusions have implications for the investigation and remediation of fissured Chalk aquifers contaminated by oil.

  15. Analysis and applications of microorganisms from a chalk oil reservoir in the North Sea

    Energy Technology Data Exchange (ETDEWEB)

    Kaster, Krista Michelle

    2009-03-15

    Ekofisk a chalk oil reservoir in the Norwegian sector of the North Sea was found to harbour an active and diverse microbial community. Microbial actives may be deleterious in nature as in reservoir souring or maybe advantageous as in microbial enhanced oil recovery. The aim of this study was to characterise the microbial communities in the Ekofisk oil reservoir and to gain insight into the microbial mechanisms important for the a) control of reservoir souring, and b) which can be utilized in enhanced oil recovery. Produced water samples from the Ekofisk oil reservoir were analysed using both culture-dependent and -independent techniques. The Ekofisk microbial community was found to be dominated by thermophilic microorganisms many of which were capable of either sulphidogenic or methanogenic physiologies. They were similar to organisms that have been previously identified from oil reservoir fluids. The dominant organisms identified directly from the produced water samples had sequences similar to members of the genera Thermotoga, Caminicella, Thermoanaerobacter, Archaeoglobus, Thermococcus, and Methanobulbus. Enrichment cultures obtained from the produced water samples were dominated by sheathed rods. Sequence analyses of the cultures indicated predominance of the genera Petrotoga, Arcobacter, Archaeoglobus and Thermococcus. Reservoir souring caused by sulphide production due the activity of sulphate reducing prokaryotes (SRP) may be reduced by the injection of nitrate or nitrite. Nitrate or nitrite mitigates sulphide production either by the stimulation of nitrate reducing bacteria (NRB) through nitrate addition or via metabolic inhibition of the reduction of sulphite to sulphide by nitrite. Here we found that nitrate addition was ineffective at controlling souring whereas nitrite proved very effective at inhibiting sulphate reduction even at very low concentrations (0.25 mM - 1 mM) in both batch culture and bioreactor studies. To investigate microbial utilization

  16. Investigation of CO2 Enhanced Oil Recovery Using Dimensionless Groups in Wettability Modified Chalk and Sandstone Rocks

    Directory of Open Access Journals (Sweden)

    Vahid Alipour Tabrizy

    2014-01-01

    Full Text Available The paper addresses enhanced oil recovery in chalk and sandstone rocks by CO2 injection, with different wettability, porosity, and permeability as well as injection rate and flooding conditions. Results indicate that an increase in Bond number has a positive effect on oil recovery whereas for capillary number, there is a limit in which recovery is improving. This limit is estimated when the pressure drop by viscous force is approximately equal to the threshold balance between capillary and gravity forces. A dimensionless group is proposed that combines the effect of capillarity, injection rate, permeability, and CO2 diffusion on the oil recovery. Recovery from all experiments in this study and reported data in the literature shows a satisfactory relationship with the proposed group.

  17. Influence of coal mine tips on the chalk aquifer. Sampling methods for three dimensional sulphate infiltration study

    Energy Technology Data Exchange (ETDEWEB)

    Barrez, F.; Mania, J. [Polytech' Lille, Dept. Genie Civil, UMR CNRS 8107 (LML), 59 - Villeneuve d' Ascq (France); Mansy, J.L. [Lille-1 Univ., Lab. de Sedimentologie et de Geodynamique, UMR CNRS 8110 (PBDS), 59 - Villeneuve d' Ascq (France); Piwakowski, B. [Ecole Centrale de Lille, Groupe Electronique Acoustique IEMN-DOAE, UMR CNRS 8520, 59 - Villeneuve d' Ascq (France)

    2005-07-01

    The coal basin of the Nord-Pas-de-Calais region (France) shows a very strong deterioration of the Chalk aquifer quality. In order to better model the hydro-dynamism and to improve knowledge on the chemical interactions, sampling according to depth of the groundwater is undertaken. The low-flow sampling and the profiles of the in-situ physicochemical parameters allow the observation of various vertical heterogeneities of the aquifer. The areas where the coal mine tips are localised appear very interesting to study. The sulphates released by the pyrite oxidation allow a 'artificial tracing' and give a visualization of the flow as well as information on the implied chemical processes between the oxidizing and reducing zones. (authors)

  18. Tilting oil-water contact in the chalk of Tyra Field as interpreted from capillary pressure data

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Rana, M.A.

    2010-01-01

    -trends from logs were compared with normalized water saturation depth-trends predicted from capillary pressure core data. The ten wells lie close to a SW–NE cross section of the field. For the gas–oil contact, a free contact measured in one well corresponds to a practically horizontal contact interpreted from......The Tyra Field in the central North Sea is located in Palaeogene and Upper Cretaceous chalk. It contains a natural gas zone underlain by an oil leg. Based on analysis of logs and core data from ten wells drilled prior to the field being put into production, normalized water saturation depth...... logging data in the remaining wells. A westerly dipping oil–water contact was found from logging data. Comparison of the depth-wise trends in normalized water saturation among the different wells indicates a regional pattern: in the western side of the field, the trends correspond to a situation...

  19. The effect of divalent ions on the elasticity and pore collapse of chalk evaluated from compressional wave velocity and low-field Nuclear Magnetic Resonance (NMR)

    DEFF Research Database (Denmark)

    Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

    2015-01-01

    electron microscopy of the materials were conducted prior to the experiments. The iso-frame model was used to predict the bulk moduli in dry and saturated conditions from the compressional modulus of water-saturated rocks. The effective stress coefficient, as introduced by Biot, was also determined from......The effects of divalent ions on the elasticity and the pore collapse of chalk were studied through rock-mechanical testing and low-field Nuclear Magnetic Resonance (NMR) measurements. Chalk samples saturated with deionized water and brines containing sodium, magnesium, calcium and sulfate ions were...... and effects on the elasticity after the saturation since none of the other plugs saturated with divalent ions (Ca2+ and SO42+) experienced it....

  20. Carbon and oxygen isotopic variation in Upper Maastrichtian chalk, Danish Central Graben. M-10X (Dan Field), E-5X (Tyra SE Field)

    Energy Technology Data Exchange (ETDEWEB)

    Schovsbo, N.H.; Buchardt, B.

    2004-07-01

    The chemostratigraphic potential of the carbon isotopic variation in Upper Maastrichtian chalk has been evaluated based on 143 bulk chalk samples from the M-10X and E-5X wells. The wells are situated 30 km apart and are located in the Dan and Tyra SE oil and gas fields, respectively. Samples were taken each metre to record the stratigraphic variation. In addition, an interval in the M-10X well was sampled on a decimetre scale to resolve the link between {delta}{sup 13}C- and {delta}{sup 18}0-isotopic variation and lithology. Across three laminated to bioturbated chalk cycles, the m-scale variation in {delta}{sup 13}C is 0.1 %o. In the middle cycle, more negative {delta}{sup 13}C values were measured in the laminated chalk compared to bioturbated chalk. These more negative {delta}{sup 13}C values are interpreted to reflect early diagenetic cement characterised by light {delta}{sup 13}C values that formed as a response to a semiclosed pore-water environment. No consistent trend was observed in the other cycles. The laminated interval is here weakly developed and possibly reflects a depositional environment characterised by a more open pore-water system that did not allow a diagenetic component to form. The m-scale variation in {delta}{sup 18}0 values amounts to 0.5 %o and shows no apparent relationship to lithology. A chemostratigraphic correlation between the wells is presented. The correlation is consistent with the established biostratigraphy based on nannofossils, pelagic foraminifers and dinoflagellates. The chemostratigraphy was established based on the m-scale variation in {delta}{sup 13}C values and consists of seven units; the chemostratigraphy thus allows a high degree of stratigraphical resolution in the uppermost Maastrichtian interval. Moreover, the combined chemo- and biostratigraphic framework confirms the stratigraphic significance of the logbased porosity markers that form the basis of the cyclostratigraphic correlation system proposed. The recorded

  1. COMPARISON OF THE TRADITIONAL CHALK AND BOARD LECTURE SYSTEM VERSUS POWER POINT PRESENTATION AS A TEACHING TECHNIQUE FOR TEACHING GROSS ANATOMY TO THE FIRST PROFESSIONAL MEDICAL STUDENTS

    Directory of Open Access Journals (Sweden)

    Nusrat

    2015-02-01

    Full Text Available Traditionally and conventionally, gross anatomy is taught by lectures and cadaveric dissection and the lectures are taken with chalk and board (C&B or chalk and talk method in, India. But there is always a debate over the most effective method of lecture delivery. AIM : The aim of this study was to compare the role and effectiveness chalk and board method versus power point presentation ( S tudent’s perception as a lecture delivering method for teaching gross anatomy. METHODS: This was a questionnaire based study where 140 out of 150 first professional MBBS students of Medical College Jammu, were asked to fill anonymously a questionnaire about their perceptions of these two lecture delivery methods. The results were analyzed to see if there was any preference of students for any particular method. RESULTS: The majority of the medical students (90.7% preferred PPT presentations, while only 9.3% of students preferred the lectures using chalkboard method. CONCLUSION: Most of the students clearly preferred and accepted the use of PPT presentations, as compared to conventional board teaching for delivery method. So teaching gross anatomy should be carefully amalgamated with use of power point in lecture hall.

  2. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

    Energy Technology Data Exchange (ETDEWEB)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.; Groshong, R.H.; Jin, G.

    1998-12-01

    This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated in hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.

  3. Identification of a New Hesperornithiform from the Cretaceous Niobrara Chalk and Implications for Ecologic Diversity among Early Diving Birds.

    Directory of Open Access Journals (Sweden)

    Alyssa Bell

    Full Text Available The Smoky Hill Member of the Niobrara Chalk in Kansas (USA has yielded the remains of numerous members of the Hesperornithiformes, toothed diving birds from the late Early to Late Cretaceous. This study presents a new taxon of hesperornithiform from the Smoky Hill Member, Fumicollis hoffmani, the holotype of which is among the more complete hesperornithiform skeletons. Fumicollis has a unique combination of primitive (e.g. proximal and distal ends of femur not expanded, elongate pre-acetabular ilium, small and pyramidal patella and derived (e.g. dorsal ridge on metatarsal IV, plantarly-projected curve in the distal shaft of phalanx III:1 hesperornithiform characters, suggesting it was more specialized than small hesperornithiforms like Baptornis advenus but not as highly derived as the larger Hesperornis regalis. The identification of Fumicollis highlights once again the significant diversity of hesperornithiforms that existed in the Late Cretaceous Western Interior Seaway. This diversity points to the existence of a complex ecosystem, perhaps with a high degree of niche partitioning, as indicated by the varying degrees of diving specializations among these birds.

  4. Projecting impacts of climate change on hydrological conditions and biotic responses in a chalk valley riparian wetland

    Science.gov (United States)

    House, A. R.; Thompson, J. R.; Acreman, M. C.

    2016-03-01

    Projected changes in climate are likely to substantially impact wetland hydrological conditions that will in turn have implications for wetland ecology. Assessing ecohydrological impacts of climate change requires models that can accurately simulate water levels at the fine-scale resolution to which species and communities respond. Hydrological conditions within the Lambourn Observatory at Boxford, Berkshire, UK were simulated using the physically based, distributed model MIKE SHE, calibrated to contemporary surface and groundwater levels. The site is a 10 ha lowland riparian wetland where complex geological conditions and channel management exert strong influences on the hydrological regime. Projected changes in precipitation, potential evapotranspiration, channel discharge and groundwater level were derived from the UK Climate Projections 2009 ensemble of climate models for the 2080s under different scenarios. Hydrological impacts of climate change differ through the wetland over short distances depending on the degree of groundwater/surface-water interaction. Discrete areas of groundwater upwelling are associated with an exaggerated response of water levels to climate change compared to non-upwelling areas. These are coincident with regions where a weathered chalk layer, which otherwise separates two main aquifers, is absent. Simulated water levels were linked to requirements of the MG8 plant community and Desmoulin's whorl snail (Vertigo moulinsiana) for which the site is designated. Impacts on each are shown to differ spatially and in line with hydrological impacts. Differences in water level requirements for this vegetation community and single species highlight the need for separate management strategies in distinct areas of the wetland.

  5. PowerPoint or chalk and talk: Perceptions of medical students versus dental students in a medical college in India

    Directory of Open Access Journals (Sweden)

    Vikas Seth

    2010-08-01

    Full Text Available Vikas Seth, Prerna Upadhyaya, Mushtaq Ahmad, Vijay MogheDepartment of Pharmacology, Mahatma Gandhi Medical College, Jaipur, Rajasthan, IndiaPurpose: To assess students’ perceptions of the impact of PowerPoint (PPT presentations in lectures in comparison to the traditional chalk and talk method and lectures using ­transparencies and overhead projector (TOHP. The study analyzes the preferences for teaching aids of medical students versus dental students.Methods: Second year medical and dental undergraduates were asked to fill in a nine-item questionnaire about their perceptions of the three lecture delivery methods. Following analysis of the questionnaire the students were interviewed further. The results were analyzed separately for medical and dental students to see if there was any difference in their perceptions.Results: The majority of the medical students (65.33% preferred PPT presentations, while 15.16% of students preferred the lectures using chalkboard, and 19.51% preferred TOHP for teaching (P < 0.001. Of the dental students: 41.84% preferred chalkboard, 31.21% preferred TOHP, and 25.85% students preferred PPT presentations in the lectures (P < 0.05. Some important comments of the students were also recorded on interview which could be valuable for the medical teachers.Conclusion: The medical students clearly preferred the use of PPT presentations while the dental students did not. The study does not bring out evidence based superiority of any lecture delivery method. It appears that in the hands of a trained teacher any teaching aid would be appropriate and effective. This highlights the need for formal training in teaching technologies to develop good presentation skills and thus motivate the students.Keywords: audiovisual aids, medical education, lecture delivery methods, PowerPoint presentations, OHP, chalkboard

  6. The impact of broadleaved woodland on water resources in lowland UK: I. Soil water changes below beech woodland and grass on chalk sites in Hampshire

    Directory of Open Access Journals (Sweden)

    J. Roberts

    2005-01-01

    Full Text Available The possible effects of broadleaved woodland on recharge to the UK Chalk aquifer have led to a study of evaporation and transpiration from beech woodland (Black Wood and pasture (Bridgets Farm, growing in shallow soils above chalk in Hampshire. Eddy correlation measurements of energy balance components above both the forest and the grassland enabled calculation of latent heat flux (evaporation and transpiration as a residual. Comparative measurements of soil water content and soil water potential in 9 m profiles under both forest and grassland found changes in soil water content down to 6 m at both sites; however, the soil water potential measurements showed upward movement of water only above a depth of about 2 m. Below this depth, water continued to drain and the soil water potential measurements showed downward movement of water at both sites, notwithstanding significant negative soil water potentials in the chalk and soil above. Seasonal differences occur in the soil water content profiles under broadleaved woodland and grass. Before the woodland foliage emerges, greater drying beneath the grassland is offset in late spring and early summer by increased drying under the forest. Yet, when the change in soil water profiles is at a maximum, in late summer, the profiles below woodland and grass are very similar. A comparison of soil water balances for Black Wood and Bridgets Farm using changes in soil water contents, local rainfall and evaporation measured by the energy balance approach allowed drainage to be calculated at each site. Although seasonal differences occurred, the difference in cumulative drainage below broadleaved woodland and grass was small.

  7. Large scale hot water migration systems around salt diapirs in the Danish Central Trough and their impact on diagenesis of chalk reservoirs

    Science.gov (United States)

    Jensenius, Jørgen; Munksgaard, Niels C.

    1989-01-01

    Fracture filling calcite from the piercement fields of East Rosa, Skjold, Rolf, North Arne, Nils and Vagn (directly underlain by salt diapirs) and the dome field Dan (overlying a deep seated salt structure) have been studied by fluorescence and cathodoluminiscence microscopy, fluid inclusion microthermometry and carbon and oxygen isotopes. The carbon and oxygen isotope compositions of the reservoir matrix chalk have also been measured. The temperature estimates obtained from fluid inclusion data suggest that the fracture filling calcite of the piercement fields precipitated during hot water flushing of the reservoirs. The flushing system only existed around the salt diapirs and was probably related to expulsion of overpressured fluid from the surrounding sediments. The thermal anomaly and the faults associated with the diapirs probably were important factors in focusing the ascending water. By combining fluid inclusion thermometry with O isotope data for the fracture filling calcites ranges of O isotopic values of the flushing water are deduced: in Skjold, Rolf, North Arne, Nils and Vagn: δ18O = - 1 to + 7%. SMOW, values typical of sedimentary porewater of sea water origin; in East Rosa: δ18O = - 4 and + 4%. SMOW, which combined with data on fluid inclusion salinities suggest that the flushing waters were responsible for substantial salt dissolution. Lower δ18O values with shallower depth of burial suggest that the porosity of chalk in the shallower fields was more severely reduced by calcite cementation during the flushing event than in the deeper fields. In the case of North Arne, Nils, Vagn and Dan, δ 13C values of the fracture filling calcites are similar to those of normal chalk (0.5 to 3.5%.). However, calcites from Rolf, Skjold and East Rosa are depleted by - 1.8, - 6.2 and - 16.7%., respectively. Only in East Rosa is the matrix chalk itself depleted in 13C (range: - 2.0 to + 0.7%.). The low δ 13C values are interpreted as the result of biodegration

  8. Capillary fringe and tritium and nitrogen tracing history in the Senonian chalk of Champagne; Frange capillaire et traces historiques du tritium et de l`azote dans la craie senonienne en Champagne

    Energy Technology Data Exchange (ETDEWEB)

    Ballif, J.L. [INRA station d`agronomie, 51 - Chalons-en-Champagne (France)

    1998-12-31

    In the middle of Champagne-Ardenne area, a chalky zone is located, directly on top of which lies the soil and in which the water table is relatively close the soil; which allows for capillary direction to the surface horizons and the renewal of water reserve. After the presentation of the hydrological characteristics, the total porosity of chalk, the pores distribution, the capillary attraction is shown by the hydrological comportment of the soil and the upper part of the unsaturated zone of chalk. In the homogeneous rock, the tritium and nitrogen transfers reveal the historical tracks. (authors) 18 refs.

  9. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Annual report, March 1996--March 1997

    Energy Technology Data Exchange (ETDEWEB)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Groshong, R.H.

    1997-08-01

    Gilbertown Field is the oldest oil field in Alabama and produces oil from chalk of the Upper Cretaceous Selma Group and from sandstone of the Eutaw Formation along the southern margin of the Gilbertown fault system. Most of the field has been in primary recovery since establishment, but production has declined to marginally economic levels. This investigation applies advanced geologic concepts designed to aid implementation of improved recovery programs. The Gilbertown fault system is detached at the base of Jurassic salt. The fault system began forming as a half graben and evolved in to a full graben by the Late Cretaceous. Conventional trapping mechanisms are effective in Eutaw sandstone, whereas oil in Selma chalk is trapped in faults and fault-related fractures. Burial modeling establishes that the subsidence history of the Gilbertown area is typical of extensional basins and includes a major component of sediment loading and compaction. Surface mapping and fracture analysis indicate that faults offset strata as young as Miocene and that joints may be related to regional uplift postdating fault movement. Preliminary balanced structural models of the Gilbertown fault system indicate that synsedimentary growth factors need to be incorporated into the basic equations of area balance to model strain and predict fractures in Selma and Eutaw reservoirs.

  10. Mapping of groundwater potential zones in Salem Chalk Hills, Tamil Nadu, India, using remote sensing and GIS techniques.

    Science.gov (United States)

    Thilagavathi, N; Subramani, T; Suresh, M; Karunanidhi, D

    2015-04-01

    This study proposes to introduce the remote sensing and geographic information system (GIS) techniques in mapping the groundwater potential zones. Remote sensing and GIS techniques have been used to map the groundwater potential zones in Salem Chalk Hills, Tamil Nadu, India. Charnockites and fissile hornblende biotite gneiss are the major rock types in this region. Dunites and peridodites are the ultramafic rocks which cut across the foliation planes of the gneisses and are highly weathered. It comprises magnesite and chromite deposits which are excavated by five mining companies by adopting bench mining. The thickness of weathered and fracture zone varies from 2.2 to 50 m in gneissic formation and 5.8 to 55 m in charnockite. At the contacts of gneiss and charnockite, the thickness ranges from 9.0 to 90.8 m favoring good groundwater potential. The mine lease area is underlined by fractured and sheared hornblende biotite gneiss where groundwater potential is good. Water catchment tanks in this area of 5 km radius are small to moderate in size and are only seasonal. They remain dry during summer seasons. As perennial water resources are remote, the domestic and agricultural activities in this region depend mainly upon the groundwater resources. The mines are located in gently slope area, and accumulation of water is not observed except in mine pits even during the monsoon period. Therefore, it is essential to map the groundwater potential zones for proper management of the aquifer system. Satellite imageries were also used to extract lineaments, hydrogeomorphic landforms, drainage patterns, and land use, which are the major controlling factors for the occurrence of groundwater. Various thematic layers pertaining to groundwater existence such as geology, geomorphology, land use/land cover, lineament, lineament density, drainage, drainage density, slope, and soil were generated using GIS tools. By integrating all the above thematic layers based on the ranks and

  11. Implementation of agronomical and geochemical modules into a 3D groundwater code for assessing nitrate storage and transport through unconfined Chalk aquifer

    Science.gov (United States)

    Picot-Colbeaux, Géraldine; Devau, Nicolas; Thiéry, Dominique; Pettenati, Marie; Surdyk, Nicolas; Parmentier, Marc; Amraoui, Nadia; Crastes de Paulet, François; André, Laurent

    2016-04-01

    Chalk aquifer is the main water resource for domestic water supply in many parts in northern France. In same basin, groundwater is frequently affected by quality problems concerning nitrates. Often close to or above the drinking water standards, nitrate concentration in groundwater is mainly due to historical agriculture practices, combined with leakage and aquifer recharge through the vadose zone. The complexity of processes occurring into such an environment leads to take into account a lot of knowledge on agronomy, geochemistry and hydrogeology in order to understand, model and predict the spatiotemporal evolution of nitrate content and provide a decision support tool for the water producers and stakeholders. To succeed in this challenge, conceptual and numerical models representing accurately the Chalk aquifer specificity need to be developed. A multidisciplinary approach is developed to simulate storage and transport from the ground surface until groundwater. This involves a new agronomic module "NITRATE" (NItrogen TRansfer for Arable soil to groundwaTEr), a soil-crop model allowing to calculate nitrogen mass balance in arable soil, and the "PHREEQC" numerical code for geochemical calculations, both coupled with the 3D transient groundwater numerical code "MARTHE". Otherwise, new development achieved on MARTHE code allows the use of dual porosity and permeability calculations needed in the fissured Chalk aquifer context. This method concerning the integration of existing multi-disciplinary tools is a real challenge to reduce the number of parameters by selecting the relevant equations and simplifying the equations without altering the signal. The robustness and the validity of these numerical developments are tested step by step with several simulations constrained by climate forcing, land use and nitrogen inputs over several decades. In the first time, simulations are performed in a 1D vertical unsaturated soil column for representing experimental nitrates

  12. Permeability prediction in chalks

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Prasad, Manika

    2011-01-01

    The velocity of elastic waves is the primary datum available for acquiring information about subsurface characteristics such as lithology and porosity. Cheap and quick (spatial coverage, ease of measurement) information of permeability can be achieved, if sonic velocity is used for permeability....... The relationships between permeability and porosity from core data were first examined using Kozeny’s equation. The data were analyzed for any correlations to the specific surface of the grain, Sg, and to the hydraulic property defined as the flow zone indicator (FZI). These two methods use two different approaches...... to enhance permeability prediction fromKozeny’s equation. The FZI is based on a concept of a tortuous flow path in a granular bed. The Sg concept considers the pore space that is exposed to fluid flow and models permeability resulting from effective flow parallel to pressure drop. The porosity-permeability...

  13. Chalk and Cheese

    Institute of Scientific and Technical Information of China (English)

    FRANCISCO; LITTLE

    2006-01-01

    Inever thought I would ever be attending a banquet on the balcony of a restaurant that looked out across the Yalujiang River, straight into the Democratic People's Republic of Korea (North Korea). There we were, a delegation from

  14. Chalk and computers

    DEFF Research Database (Denmark)

    Rasmussen, Lisa Rosén

    Since 1970 school books have first been supplemented by photocopies and later PDF files and the use of Internet sites. Chalkboards have been replaced by Smart Boards and notebooks by laptops and IPADS. Digital media has made its way into the classroom and into everyday school life. This has been ...

  15. Nutrient dynamics as indicators of karst processes: Comparison of the Chalk aquifer (Normandy, France) and the Edwards aquifer (Texas, U.S.A.)

    Science.gov (United States)

    Mahler, B.J.; Valdes, D.; Musgrove, M.; Massei, N.

    2008-01-01

    Karst aquifers display a range of geologic and geomorphic characteristics in a wide range of climatic and land-use settings; identification of transport dynamics representative of karst aquifers in general could help advance our understanding of these complex systems. To this end, nutrient, turbidity, and major ion dynamics in response to storms were compared at multiple sites in two karst aquifers with contrasting characteristics and settings: the Chalk aquifer (Eure Department, Normandy, France) and the Barton Springs segment of the Edwards Aquifer (Texas, U.S.A.). The Chalk aquifer is typified by high matrix porosity, thick surficial deposits (up to 30??m thick), and agricultural land use; the Barton Springs segment is typified by low matrix porosity, outcropping limestone, and urban land use. Following one to three storms, from 5 to 16 samples from springs and wells were analyzed for major ions, and specific conductance and turbidity were monitored continuously. Comparison of the chemographs indicated some generalized responses, including an increase in turbidity and potassium concentrations and a decrease in major ion and nitrate concentrations with infiltrating storm runoff. Factor analysis of major ions and turbidity revealed strikingly similar behavior of the chemical variables for the two aquifers: The first two factors, explaining more than 75% of the variability, illustrate that dynamics of most major ions (including nitrate) are opposed to those of turbidity and of potassium. The results demonstrate that potassium and nitrate are effective tracers of infiltrating storm runoff and resident ground water, respectively, and the similar results for these two highly contrasting aquifers suggest that the dynamics identified might be applicable to karst systems in general. ?? 2008 Elsevier B.V. All rights reserved.

  16. Reply to comment on: Lawrence, J.A., Mortimore, R.N., Stone, K.J., and Busby, J.P., 2013. Sea saltwater weakening of chalk and the impact on cliff instability. Geomorphology 191, 14-22

    Science.gov (United States)

    Lawrence, James A.; Mortimore, Rory N.

    2015-02-01

    We are grateful to Dornbusch (2014) for the opportunity to clarify the role we propose for salt water weakening of the chalk and its potential importance as a mechanism contributing to cliff instability. Dornbusch's argument is based largely on a single comment "This work challenges the established view by identifying the role of salt from seawater in the degradation of porous rocks in coastal environments as a third and potentially the most important mechanism leading to chalk cliff collapse" (Lawrence et al., 2013: 15). This was not intended as a "conclusion" as suggested by Dornbusch (2014) but is rather a qualitative introductory statement highlighting the potential importance of the salt water weakening process in coastal cliff instability. The actual conclusions of the work are not challenged by Dornbusch (2014).

  17. Impoverishment of the bryophyte and lichen flora of the Dutch chalk grasslands in the thirty years 1953-1983. [Tortella spp. ; Trichostomum spp. ; Aloina spp. ; Pleurochaete squarrosa; Abietinella abietina; Camptothecium lutescens; Brachythecium rutabulum

    Energy Technology Data Exchange (ETDEWEB)

    During, H.J.; Willems, J.H.

    1986-01-01

    The Dutch chalk grasslands were formerly very rich in bryophyte and lichen species. A comparison of data from Barkman (1953) and more recent inventories yielded the following results: (a) Lichens have disappeared nearly completely from the Dutch chalk grasslands; (b) many characteristic acrocarps (e.g., Tortella spp., Trichostomum spp., Aloina spp., Pleurochaete squarrosa) and some pleurocarps (Abietinella abietina, Camptothecium lutescens) have decreased drastically; (c) some common litter-indicator species (Brachythecium rutabulum and others) are now increasing. It is hypothesized that this change is mainly a result of combined effects of the abandonment of the old grazing regime, which is in only a few places replaced by mowing, and of air pollution. The authors are strongly in favor of current attempts to reintroduce grazing by the old race of Mergelland sheep.

  18. Impact of Nord Pas-de-Calais coal basin mine dumps on the quality of chalk aquifer waters; Impact des terrils houillers du bassin minier Nord-Pas-de-Calais sur la qualite des eaux de la nappe de la craie

    Energy Technology Data Exchange (ETDEWEB)

    Denimal, S.

    2001-12-01

    In the Nord-Pas-de-Calais region (Northern France), mining activity related to coal extraction resulted in the presence of numerous mine tips. The weathering of those wastes leads to the oxidation of the pyrite contained in the Carboniferous shales and could thus release sulphate and acid waters, potentially enriched in heavy metals within the run-off waters down to the underlying aquifer, hosted by thick Cretaceous chalk formation. The aim of this study is to determine the possible role of the mine tips on the quality of the chalk aquifer, the first-order drinking water supply at the regional scale. Two sites have been selected, according to their contrasted (hydro)geological setting: site 1 lies directly on the Senonian-Turonian chalk while site 2 lies on the sandy-clayey Tertiary formations (Argiles de Louvil and Sables d'Ostricourt) overlying the chalk formations. The chalk aquifer is a free water table excepted where the Tertiary formations make this table confined, as is the case for site 2. A release of carbon and sulphur from waste dumps surface has been evidenced. Analysis of groundwater sulphate content downstream and upstream of the two sites confirms the impact of the mine tips on the chalk waters. The use of sulphur isotopes as tracers for sulphate origin has permitted to identify two sources: a 'mine dump' source on the two sites and a second source related to the gypsum of the 'Sables d'Ostricourt' on site 2. This study has also evidenced, in the confined zone (site 2), a bacterial sulphate reduction allowed by the release of carbon from the mine spoils. No leaching of heavy metals on mine tips surface and no enrichment of the Chalk aquifer waters have been observed on the two sites. The mine spoils studied here cause an acid mine drainage (AMD) neutralized during the infiltration into the chalk aquifer. The only witnesses of this AMD are the enrichments in sulphate ions observed downstream of mine dumps and the increase

  19. Extra-Mediterranean glacial refugia in a Mediterranean faunal element: the phylogeography of the chalk-hill blue Polyommatus coridon (Lepidoptera, Lycaenidae)

    Science.gov (United States)

    Kühne, Gero; Kosuch, Joachim; Hochkirch, Axel; Schmitt, Thomas

    2017-01-01

    Most warm-adapted Central European species are thought to have survived ice ages exclusively in Mediterranean refugia. During recent years, this point of view has been questioned. Therefore, we tested the hypothesis that extra-Mediterranean refugia also played a role in warm-adapted insect species and selected the chalk-hill blue, Polyommatus coridon. We sequenced two mitochondrial loci (COI, CR) in 150 individuals from 30 populations covering nearly the complete range. Minimum spanning networks and other statistical analyses concordantly revealed four genetic lineages with strong phylogeographic signal: a western group in Italy, France and western/central Germany, an eastern lineage in the Balkan Peninsula, the Carpathian Basin and eastern Central Europe, an Alpine group with populations in the Alps and southern Germany and a Pyrenean group. Our results are generally consistent with previous analyses for P. coridon based on allozymes and DNA sequences, but provide additional insights. We propose that these four lineages have evolved during allopatry in different glacial refugia, two in typical Mediterranean refugia (Apennines and Balkan Peninsulas), but two in extra-Mediterranean areas south of the Alps and Pyrenees. This supports survival of warm-adapted organisms in these regions in close geographic proximity to the refugia of high mountain species.

  20. Observations of debris flows at Chalk Cliffs, Colorado, USA: Part 2, changes in surface morphometry from terrestrial laser scanning in the summer of 2009

    Science.gov (United States)

    Staley, Dennis M.; Wasklewicz, Thad A.; Coe, Jeffrey A.; Kean, Jason W.; McCoy, Scott W.; Tucker, Greg E.

    2011-01-01

    High resolution topographic data that quantify changes in channel form caused by sequential debris flows in natural channels are rare at the reach scale. Terrestrial laser scanning (TLS) techniques are utilized to capture morphological changes brought about by a high-frequency of debris-flow events at Chalk Cliffs, Colorado. The purpose of this paper is to compare and contrast the topographic response of a natural channel to the documented debris-flow events. TLS survey data allowed for the generation of high-resolution (2-cm) digital terrain models (DTM) of the channel. A robust network of twelve permanent control points permitted repeat scanning sessions that provided multiple DTM to evaluate fine-scale topographic change associated with three debris-flow events. Difference surfaces from the DTM permit the interpretations of spatial variations in channel morphometry and net volume of material deposited and eroded within and between a series of channel reaches. Each channel reach experienced erosion, deposition, and both net volumetric gains and losses were measured. Analysis of potential relationships between erosion and deposition magnitudes yielded no strong correlations with measures of channel-reach morphometry, suggesting that channel reach-specific predictions of potential erosion or deposition locations or rates cannot be adequately derived from statistical analyses of pre-event channel-reach morphometry.

  1. Experimental study and mechanical modelling of the effects of water-driving in an oil saturated chalk. Application to the petroleum industry; Etude experimentale et modelisation mecanique des effets du balayage a l'eau dans une craie saturee d'huile. Application a l'industrie petroliere

    Energy Technology Data Exchange (ETDEWEB)

    Mata, C.

    2001-01-01

    The production of hydrocarbons may sometimes lead to compaction of the oil-reservoir layers with substantial collapse of the soil surface; this mechanism is usually mentioned as Subsidence. Classical remedy to this problem is to sustain the fluid pressure with the help of water injection. However, in presence of high porosity chalk (porosity > 30%), this technique does not give effective results: the subsidence rate at North Sea reservoirs (Ekofisk field), after injection, has remained unchanged. Some justify the subsistence in the chalk as caused by phenomena of dissolution of the carbonates; others think it is connected to the destruction of capillary menisci. In this research, we follow this second approach. This study is finalized to a better understanding of the compaction mechanisms in pure carbonates when water is injected. This is done by proposing -in micro-scale first and in macro-scale after- a physical model that agrees with empirical observations. In order to meet this target, IFP skills and experience in physical and chemical measurements (taken before, after and during mechanical tests) have proficiently joined ENPC laboratory (CERMMO) knowledge of micro and macro modelling. The soft rock studied is a Paris basin's white chalk (Craie de Guerville). Its physical and chemical characterisation (i.e.: silica content, porosity, permeability) is very similar to North Sea chalk, but Guerville chalk has never been in contact with oil and generally it crops out of the ground surface. Strength parameters of this rock have been first determined by standard triaxial tests. Three different saturation configurations have been examined: dry, fully oil-saturated and fully water-saturated. As literature clearly state, dry chalk is stronger than oil saturated chalk and the first two are largely stronger than water saturated chalk. Therefore uniaxial strain water injection tests have been performed on oil saturated samples. Results, coupled with previous physical

  2. Impedance imaging in core analysis. Imaging of phase distributions in samples of natural cores of North Sea chalk containing conducting as well as non-conducting fluids. Part: 1-3

    Energy Technology Data Exchange (ETDEWEB)

    Laursen, S. [DTU, Inst. for Kemi (Denmark)] Moeller Nielsen, C. [DTU, Inst. for Energiteknik (Denmark)

    1997-12-31

    The present report documents the efforts to develop an impedance method for determining the distribution of the water saturation in a chalk core sample. Measurement of this distribution during a displacement process will make it possible to make numerical simulations of the process which may in turn reveal important rock parameters. The impedance method is one among other methods to determine saturation profiles in a research programme on rock parameters with participants from Danmarks Tekniske Universitet, DTU, and Danmarks og Groenlands Geologiske Undersoegelse, GEUS. The other methods investigated are nmr-scanning and {gamma}-logging. (au)

  3. Effect of dolomite, magnesium oxide (MgO) and chalk (CaCO3) on in vitro fermentation of amorphous and crystalline cellulose and meadow hay using inoculum from sheep.

    Science.gov (United States)

    Váradyová, Zora; Baran, Miroslav; Zawadzki, Wojciech; Siroka, Peter

    2003-01-01

    Some minerals can influence some biochemical parameters of rumen fermentation. The objective of this experiment was to determine the effect of different amounts (0.1, 0.25 and 0.5 g) of dolomite and to compare the effect of dolomite, magnesium oxide (MgO) and chalk (CaCO3) upon the end products of rumen fermentation in vitro. Amorphous and crystalline cellulose as well as meadow hay were used as substrates and incubated with buffered rumen fluid in sealed fermentation bottles. In dependence on the amount of dolomite and the kind of substrate an inhibitory effect of dolomite on methane production was evident. Significant differences of methane production were found between the controls, crystalline cellulose and meadow hay with 0.5 g of dolomite. An increase of total gas production was observed for cellulose with both 0.25 and 0.5 g of dolomite and also for meadow hay with 0.5 g of dolomite. It can be concluded that there was a remarkable effect of dolomite on methane production and also a slight effect of magnesium oxide and chalk as compared to the effect of dolomite on the fermentation parameters of incubated substrates.

  4. Results of detailed ground geophysical surveys for locating and differentiating waste structures in waste management area 'A' at Chalk River Laboratories, Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Tomsons, D.K.; Street, P.J.; Lodha, G.S

    1999-07-01

    Waste Management Area 'A' (WMA 'A'), located in the outer area of the Chalk River Laboratories (CRL) was in use as a waste burial site from 1946 to 1955. Waste management structures include debris-filled trenches, concrete bunkers and miscellaneous contaminated solid materials, and ditches and pits used for liquid dispersal. In order to update historical records, it was proposed to conduct detailed ground geophysical surveys to define the locations of waste management structures in WMA 'A', assist in planning of the drilling and sampling program to provide ground truth for the geophysics investigation and to predict the nature and locations of unknown/undefined shallow structures. A detailed ground geophysical survey grid was established with a total of 127 grid lines, oriented NNE and spaced one metre apart. The geophysical surveys were carried out during August and September, 1996. The combination of geophysical tools used included the Geonics EM61 metal detector, the GSM-19 magnetometer/gradiometer and a RAMAC high frequency ground penetrating radar system. The geophysical surveys were successful in identifying waste management structures and in characterizing to some extent, the composition of the waste. The geophysical surveys are able to determine the presence of most of the known waste management structures, especially in the western and central portions of the grid which contain the majority of the metallic waste. The eastern portion of the grid has a completely different geophysical character. While historical records show that trenches were dug, they are far less evident in the geophysical record. There is clear evidence for a trench running between lines 30E and 63E at 70 m. There are indications from the radar survey of other trench-like structures in the eastern portion. EM61 data clearly show that there is far less metallic debris in the eastern portion. The geophysical surveys were also successful in identifying

  5. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama -- Year 2. Annual report, March 1997--March 1998

    Energy Technology Data Exchange (ETDEWEB)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.

    1998-09-01

    Gilbertown Field is the oldest oil field in Alabama and has produced oil from fractured chalk of the Cretaceous Selma Group and glauconitic sandstone of the Eutaw Formation. Nearly all of Gilbertown Field is still in primary recovery, although waterflooding has been attempted locally. The objective of this project is to analyze the geologic structure and burial history of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas in order to suggest ways in which oil recovery can be improved. Indeed, the decline of oil production to marginally economic levels in recent years has made this type of analysis timely and practical. Key technical advancements being sought include understanding the relationship of requisite strain to production in Gilbertown reservoirs, incorporation of synsedimentary growth factors into models of area balance, quantification of the relationship between requisite strain and bed curvature, determination of the timing of hydrocarbon generation, and identification of the avenues and mechanisms of fluid transport.

  6. Analysis of Effects of Teaching with Chalk and Teaching with Multimedia%传统粉笔字教学与多媒体教学的影响分析

    Institute of Scientific and Technical Information of China (English)

    雷庆祝; 刘诗茂

    2011-01-01

    多媒体技术进入大学课堂推动了教学的改革,也引发了人们的进一步思考:传统粉笔字教学和多媒体教学从哪些方面影响着教学过程和教学质量?本文通过抽样调查,获取有关数据资料,运用因子分析方法对调查数据进行分析,寻找影响教学的因子,然后利用方差分析检验各因素的显著性,最后利用Logistic回归分析方法建立教学方式选择模型,进一步分析影响教学自々各因素,为教学方式的选择提供了理论依据。%Since multimedia is used for a teaching technique in university, progresses have been made, and it makes people to think about the following issue: From which aspects do teaching with chalk and teaching with multimedia have effects to teaching procedure and teaching quality? By conducting a survey to obtain real data, common factors of affecting teaching are firstly obtained by using the method of factor analysis factors in this article. Secondly, analysis of variance is used to test for the effects of the common factors, and at last, a binary Logit choice model is used for further analysis to determine the factors of affecting teaching in more detail. Our results provide a theoretical basis for the choice of teaching patterns.

  7. Observations of debris flows at Chalk Cliffs, Colorado, USA: Part 1, in-situ measurements of flow dynamics, tracer particle movement and video imagery from the summer of 2009

    Science.gov (United States)

    McCoy, Scott W.; Coe, Jeffrey A.; Kean, Jason W.; Tucker, Greg E.; Staley, Dennis M.; Wasklewicz, Thad A.

    2011-01-01

    Debris flows initiated by surface-water runoff during short duration, moderate- to high-intensity rainfall are common in steep, rocky, and sparsely vegetated terrain. Yet large uncertainties remain about the potential for a flow to grow through entrainment of loose debris, which make formulation of accurate mechanical models of debris-flow routing difficult. Using a combination of in situ measurements of debris flow dynamics, video imagery, tracer rocks implanted with passive integrated transponders (PIT) and pre- and post-flow 2-cm resolution digital terrain models (terrain data presented in a companion paper by STALEY et alii, 2011), we investigated the entrainment and transport response of debris flows at Chalk Cliffs, CO, USA. Four monitored events during the summer of 2009 all initiated from surface-water runoff, generally less than an hour after the first measurable rain. Despite reach-scale morphology that remained relatively constant, the four flow events displayed a range of responses, from long-runout flows that entrained significant amounts of channel sediment and dammed the main-stem river, to smaller, short-runout flows that were primarily depositional in the upper basin. Tracer-rock travel-distance distributions for these events were bimodal; particles either remained immobile or they travelled the entire length of the catchment. The long-runout, large-entrainment flow differed from the other smaller flows by the following controlling factors: peak 10-minute rain intensity; duration of significant flow in the channel; and to a lesser extent, peak surge depth and velocity. Our growing database of natural debris-flow events can be used to develop linkages between observed debris-flow transport and entrainment responses and the controlling rainstorm characteristics and flow properties.

  8. 27 CFR 9.52 - Chalk Hill.

    Science.gov (United States)

    2010-04-01

    ... Quadrangle Map”; (10) Then northerly for approximately 1.3 miles along Mark West Road (which becomes Porter Creek Road), then northeasterly for approximately 1.7 miles on Porter Creek Road to its intersection with the unnamed medium duty road that parallels Porter Creek in Section 12, T. 8 N., R. 8 W.;...

  9. Coccolithophore Cell Biology: Chalking Up Progress.

    Science.gov (United States)

    Taylor, Alison R; Brownlee, Colin; Wheeler, Glen

    2017-01-03

    Coccolithophores occupy a special position within the marine phytoplankton because of their production of intricate calcite scales, or coccoliths. Coccolithophores are major contributors to global ocean calcification and long-term carbon fluxes. The intracellular production of coccoliths requires modifications to cellular ultrastructure and metabolism that are surveyed here. In addition to calcification, which appears to have evolved with a diverse range of functions, several other remarkable features that likely underpin the ecological and evolutionary success of coccolithophores have recently been uncovered. These include complex and varied life cycle strategies related to abiotic and biotic interactions as well as a range of novel metabolic pathways and nutritional strategies. Together with knowledge of coccolithophore genetic and physiological variability, these findings are beginning to shed new light on species diversity, distribution, and ecological adaptation. Further advances in genetics and functional characterization at the cellular level will likely to lead to a rapid increase in this understanding.

  10. Coccolithophore Cell Biology: Chalking Up Progress

    Science.gov (United States)

    Taylor, Alison R.; Brownlee, Colin; Wheeler, Glen

    2017-01-01

    Coccolithophores occupy a special position within the marine phytoplankton because of their production of intricate calcite scales, or coccoliths. Coccolithophores are major contributors to global ocean calcification and long-term carbon fluxes. The intracellular production of coccoliths requires modifications to cellular ultrastructure and metabolism that are surveyed here. In addition to calcification, which appears to have evolved with a diverse range of functions, several other remarkable features that likely underpin the ecological and evolutionary success of coccolithophores have recently been uncovered. These include complex and varied life cycle strategies related to abiotic and biotic interactions as well as a range of novel metabolic pathways and nutritional strategies. Together with knowledge of coccolithophore genetic and physiological variability, these findings are beginning to shed new light on species diversity, distribution, and ecological adaptation. Further advances in genetics and functional characterization at the cellular level will likely to lead to a rapid increase in this understanding.

  11. Uranium series geochemistry in aquifers: quantification of transport mechanisms of uranium and daughter products: the chalk aquifer (Champagne, France); Desequilibres des series de l'uranium dans les aquiferes: quantification des mecanismes de transport de l'uranium et de ses descendants: cas de l'aquifere de la craie (Champagne, France)

    Energy Technology Data Exchange (ETDEWEB)

    Hubert, A

    2005-09-15

    With the increase of contaminant flux of radionuclides in surface environment (soil, river, aquifer...), there is a need to understand and model the processes that control the distribution of uranium and its daughter products during transport within aquifers. We have used U-series disequilibria as an analogue for the transport of uranium and its daughter products in aquifer to understand such mechanisms. The measurements of uranium ({sup 234}U et {sup 238}U), thorium ({sup 230}Th et {sup 232}Th), {sup 226}Ra and {sup 222}Rn isotopes in the solid and liquid phases of the chalk aquifer in Champagne (East of France) allows us to understand the processes responsible for fractionation within the uranium decay chain. Fractionations are induced by physical and chemical properties of the elements (leaching, adsorption) but also by radioactive properties (recoil effect during {alpha}-decay). For the first time a comprehensive sampling of the solid phase has been performed, allowing quantifying mechanisms responsible for the long term evolution of the aquifer. A non steady state 1D model has been developed which takes into account leaching, adsorption processes as well as radioactive filiation and {alpha}-recoil effect. Retardation coefficients have been calculated for uranium, thorium and radium. The aquifer is characterised by a double porosity, and the contribution of fracture and matrix porosity on the water/rock interaction processes has been estimated. (author)

  12. Elaboration of an Elasto-Plastic Model for High Porosity Chalks. Application to the Compaction of Petroleum Reservoirs Elaboration d'un modèle de comportement élasto-plastique pour les craies très poreuses. Application à la compaction des réservoirs pétroliers

    Directory of Open Access Journals (Sweden)

    Shahrour I.

    2006-11-01

    Full Text Available This paper presents a study of the compaction of petroleum reservoirs applied to very porous carbonate rocks such as chalk. In production estimates made in reservoir engineering, the processing of the mechanical problem is often greatly simplified. Good modelling of how materials behave gives special consideration to the influence of mechanical deformations on fluid recovery. After an analysis of the mechanical behaviour of very porous chalks, an elastoplastic behaviour model is derived so as to reproduce the principal experimental observations. This behaviour model can then be used to perform local simulations of the mechanical behaviour of a reservoir under- going depletion and thus to demonstrate the importance of the stress path and the initial stress state on the deformation of materials and hence on the recovery rate. Dans les applications pétrolières, les études de la compaction des roches réservoirs interviennent dans l'estimation des quantités de fluide récupérables et de la subsidence induite par la déplétion du champ de production. Dans la première partie du travail, nous montrons qu'à partir de l'équation linéarisée de la conservation de la masse de fluide, il est possible d'exprimer un taux de récupération distinguant les contributions respectives du fluide et de la roche. En ingénierie de réservoirs, l'hypothèse d'un chemin de contrainte prépondérant dans le milieu de production permet d'exprimer la contribution de la déformation de la roche au moyen de la compressibilité volumique des pores selon ce chemin. Le taux de récupération obtenu est alors dépendant du chemin de contrainte. Lorsque le chemin de contrainte dans le réservoir n'est pas homogène, il est alors nécessaire de connaître la loi de comportement mécanique du matériau étudié. Dans le cas des carbonates très poreux, nous désirons montrer l'influence liée au choix du chemin de contrainte sur les estimations obtenues par une m

  13. Diffusive parameters of tritiated water (HTO) and U in chalk

    Energy Technology Data Exchange (ETDEWEB)

    Descostes, M.; Gandois, O.; Frasca, B.; Radwan, J.; Juery, A. [CEA Saclay, DEN DANS DPC SECR Lab Radionuclides Migration Measurements and Modeling, 91 - Gif sur Yvette (France); Descostes, M. [Univ Evry, CNRS, UMR CEA 8587, Evry (France); Pili, E. [CEA Bruyeres le Chatel, DIF, 91 (France)

    2009-06-15

    Complete text of publication follows: The feasibility of aquifer storage and recovery systems (ASR) to counteract short and long term imbalances between freshwater supply and demand is currently investigated for the metropolitan area of Perth, Western Australia. During the planned injection of oxic excess water into a deep anoxic aquifer the water quality evolution will depend on the extent and structure of the physical and geochemical heterogeneity and reactivity of the aquifer. A detailed geochemical characterisation was undertaken to determine amount and type of sedimentary reductants within different lithological facies. The incubation of sediment samples from the target aquifer for {approx} 52 days enabled quantification of their oxygen (O{sub 2}) consumption and CO{sub 2} production [1]. Data analysis, in particular the identification of key redox and acid buffering processes, was under-pinned by hydrogeochemical modelling. Results showed that the average measured reductive capacities (MRC) towards O{sub 2} consumption increased from the sand facies, followed by the siltstone facies, and the mud-stone/shale facies. This approach identified pyrite (20 - 100%), sedimentary organic matter (SOM; 3 - 56%), siderite (3 - 28%) and Fe(II)- aluminosilicates (8 - 55%) as the main O{sub 2} reductants. Minute amounts of carbonate acted as buffering minerals, while a bounding pH of 3 indicated acid buffering by K-feldspar dissolution. The supernatants showed elevated aqueous concentrations of Ni, Cd and Pb to be a potential risk for the quality of the recovered water. [1] Hartog, Griffioen and Van der Weijden (2002) Environmental Science and Technology 36(11), 2338-2344

  14. Static and dynamic effective stress coefficient of chalk

    DEFF Research Database (Denmark)

    Alam, M. Monzurul; Fabricius, Ida Lykke; Christensen, Helle Foged

    2012-01-01

    Deformation of a hydrocarbon reservoir can ideally be used to estimate the effective stress acting on it. The effective stress in the subsurface is the difference between the stress due to the weight of the sediment and a fraction (effective stress coefficient) of the pore pressure. The effective...... elastic deformation caused by pore pressure buildup, for example, during waterflooding. By contrast, during the increase in differential stress, as in the case of pore pressure depletion due to production, n increases with stress while α decreases.......Deformation of a hydrocarbon reservoir can ideally be used to estimate the effective stress acting on it. The effective stress in the subsurface is the difference between the stress due to the weight of the sediment and a fraction (effective stress coefficient) of the pore pressure. The effective...... stress coefficient is thus relevant for studying reservoir deformation and for evaluating 4D seismic for the correct pore pressure prediction. The static effective stress coefficient n is estimated from mechanical tests and is highly relevant for effective stress prediction because it is directly related...

  15. Rock physical aspects of CO2 injection in chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul

    Ved at injicere superkritisk CO2 ned i Nordsøens kalkreservoirer kan man formentlig øge olieindvindingen med 15%. Metoden giver dog anledning til overvejelser om, hvorvidt processen kan føre til kollaps og/eller sprækkedannelse i reservoiret, og dermed om der er mulighed for lækage. Via laborator...

  16. Improved seismic inversion for mapping pre-chalk reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Moerch Pedersen, J.

    1999-08-01

    The project has demonstrated the use of an integrated reservoir characterisation technique on data from the West Lulu Middle Jurassic reservoir. It has been demonstrated how impedance derived from seismic data through seismic inversion can improve the reservoir characterisation. In this case with a modest well database so the introduction of the seismic impedance narrows the possible solutions with respect to reservoir architecture. The seismic inversion method has furthermore been improved with the implementation of time variable wavelet, an important new feature for cases where the target is below the deepest well or when large time window is inverted. (au)

  17. Colistin and polymyxin B: peas in a pod, or chalk and cheese?

    Science.gov (United States)

    Nation, Roger L; Velkov, Tony; Li, Jian

    2014-07-01

    Colistin and polymyxin B have indistinguishable microbiological activity in vitro, but they differ in the form administered parenterally to patients. Polymyxin B is administered directly as the active antibiotic, whereas colistin is administered as the inactive prodrug, colistin methanesulfonate (CMS). CMS must be converted to colistin in vivo, but this occurs slowly and incompletely. Here we summarize the key differences between parenteral CMS/colistin and polymyxin B, and highlight the clinical implications. We put forth the view that overall polymyxin B has superior clinical pharmacological properties compared with CMS/colistin. We propose that in countries such as the United States where parenteral products of both colistin and polymyxin B are available, prospective studies should be conducted to formally examine their relative efficacy and safety in various types of infections and patients. In the meantime, where clinicians have access to both polymyxins, they should carefully consider the relative merits of each in a given circumstance.

  18. Calcareous nannofossils from the Boreal upper Campanian-Maastrichtian Chalk of Denmark

    DEFF Research Database (Denmark)

    Thibault, Nicolas Rudolph

    2010-01-01

    , the Rordal-1 borehole and the Rordal quarry section, North Jylland. The moderately-preserved nannofossil assemblages consist of a total of 138 species, comprising several rarely-documented species. several species that were recently described from lower latitudes, two new species of heterococcolith...

  19. Diagenesis of Flint and Porcellanite in the Maastrichtian Chalk at Stevns Klint, Denmark

    DEFF Research Database (Denmark)

    Buus Madsen, Heine; Stemmerik, Lars

    2010-01-01

    and ordered megaquartz in irregular voids indicates that silica gel and/or opal-CT transformed to the -quartz phases, microquartz, lutecite, chalcedony, and megaquartz, through the dissolution–precipitation process (Ostwald ripening). These results motivate a conceptual model in which the replacement process...... floor was dissolved and precipitated at the redox boundary as silica gel and/or opal-CT, possibly aided by sulfide-oxidizing bacteria. During burial, the dissolution–precipitation process transformed the silica gel and opal-CT to the -quartz phases. The results of this study indicate that precipitation...

  20. Investigation of spore forming bacterial flooding for enhanced oil recovery in a North Sea chalk Reservoir

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna;

    2015-01-01

    saturation state, was able to produce additionally 1.0-2.3% original oil in place (OOIP) in homogeneous cores and 6.9-8.8% OOIP in heterogeneous cores. In addition, the pressure gradient was much higher in the heterogeneous cores, which confirms that bacterial selective plugging plays an important role...

  1. The ecology of chalk-stream invertebrates studied in a recirculating stream

    OpenAIRE

    1984-01-01

    To study and qualify the factors influencing interactions between various trophic levels in natural hard-water streams, a recirculating artificial stream channel was constructed. This structure has enabled patterns of population change of stream fauna to be observed under partially controlled physical and chemical conditions. Initial colonization of the substratum by invertebrates and subsequent succession was studied along with depth distribution and growth and production studies of inverteb...

  2. Validation of a predictive model for the growth of chalk yeasts on bread.

    Science.gov (United States)

    Burgain, Anaïs; Bensoussan, Maurice; Dantigny, Philippe

    2015-07-02

    The present study focused on the effects of temperature, T, and water activity, aw, on the growth of Hyphopichia burtonii, Pichia anomala, and Saccharomycopsis fibuligera on Sabouraud Agar Medium. Cardinal values were estimated by means of cardinal models with inflection. All the yeasts were xerophilic, and they exhibited growth at 0.85 aw. The combined effects of T, aw, and pH on the growth of these species were described by the gamma-concept and validated on bread in the range of 15-25 °C, 0.91-0.97 aw, and pH 4.6-6.8. The optimum growth rates on bread were 2.88, 0.259, and 1.06 mm/day for H. burtonii, P. anomala, and S. fibuligera, respectively. The optimal growth rate of S. fibuligera on bread was about 2 fold that obtained on Sabouraud. Due to reproduction by budding, P. anomala exhibited low growth on Sabouraud and bread. However, this species is of major concern in the baker's industry because of the production of ethyl acetate in bread.

  3. Influences of space, soil, nematodes and plants on microbial community composition of chalk grassland soils

    NARCIS (Netherlands)

    Yergeau, E.; Bezemer, T.M.; Hedlund, K.; Mortimer, S.R.; Kowalchuk, G.A.; Putten, van der W.H.

    2010-01-01

    Microbial communities respond to a variety of environmental factors related to resources (e.g. plant and soil organic matter), habitat (e.g. soil characteristics) and predation (e.g. nematodes, protozoa and viruses). However, the relative contribution of these factors on microbial community composit

  4. Experimental Study of Bacterial Penetration into Chalk Rock: Mechanisms and Effect on Permeability

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Shapiro, Alexander; Eliasson Lantz, Anna;

    2014-01-01

    Bacterial selective plugging is one of the mechanisms through which microorganisms can be applied for enhanced oil recovery, as bacteria can plug the water-swept zones of a reservoir, thus altering the flow paths and improving sweep efficiency. However, complete understanding of the penetration...

  5. Diagenesis of upper cretaceous onshore and offshore chalk from the North Sea area

    DEFF Research Database (Denmark)

    Hjuler, Morten Leth

    grund af det høje poretryk i den centrale del af Nordsøen og på trods af dyb begravelse er meget porøs. Kalken fra Valhall lader dog til at være påvirket af den højere temperatur og er mere kemisk omdannet og formentlig stivere. Et andet problem er indholdet af opal og kvarts, som påvirker...... permeabiliteten. I Nørrejylland er kalken forholdsvis rig på opal, men i det dybere begravede Valhall-felt er opalen øjensynligt omdannet til kvarts. På Stevns derimod, er opalen øjensynlig forholdsvis kort efter aflejringen opløst og genudfældet i flintlag, muligvis hjulpet af mikroorganismer. Dette giver en...

  6. Determination of saturation functions and wettability for chalk based on measured fluid saturations

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, D.; Bech, N.; Moeller Nielsen, C.

    1998-08-01

    The end effect of displacement experiments on low permeable porous media is used for determination of relative permeability functions and capillary pressure functions. Saturation functions for a drainage process are determined from a primary drainage experiment. A reversal of the flooding direction creates an intrinsic imbibition process in the sample, which enables determination if imbibition saturation functions. The saturation functions are determined by a parameter estimation technique. Scanning effects are modelled by the method of Killough. Saturation profiles are determined by NMR. (au)

  7. Importance of fines in smart water enhanced oil recovery (SmW-EOR) for chalk outcrops

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    In SmW-EOR it is generally believed that precipitation of brines must be avoided since it can have a negative impact on the SmW sweep efficiency. But substitution of Mg2+ by Ca2+ on calcite surfaces (a well-accepted phenomenon) can change the brine combination and enhance the possibility of fine ...

  8. Porosity Variation in Cenozoic and Upper Chalk from the Ontong Java Pleateau

    DEFF Research Database (Denmark)

    Borre, Mai Kirstine

    1997-01-01

    Porosity was obtained from matrix- and intraparticle porosity assessed from image analysis of backscattered electron micrographs of 3000x and 300x magnification. Comparing porosity assessed from image analysis with porosity measured by index properties, it was seen that image analysis data at 300...

  9. Marine macrofossil communities in the uppermost Maastrichtian chalk of Stevns Klint, Denmark

    DEFF Research Database (Denmark)

    Hansen, Thomas; Surlyk, Finn

    2014-01-01

    growth of small-sized bryozoans governed by nutrient-rich currents from the south. The macrofauna of this member is of very high density and richness, yet species composition is similar to that of the mound-bedded lower Sigerslev Member. The bryozoan thickets of the two members are accompanied by a rich...... in the similarly mound-bedded lower Sigerslev Member. The number of polychaete species is also greater in the Højerup Member. The faunal differences reflect the shallower-water setting and a higher influx of food during deposition of the latter unit. The final Maastrichtian benthic macrofossil community at Stevns......–Paleogene boundary, and the study thereby corroborates the increasingly dominant view of a very abrupt faunal turnover at the K/Pg boundary....

  10. Genetic architecture of grain chalk in rice and interactions with a low phytic acid locus

    Science.gov (United States)

    Grain quality characteristics have a major impact on the value of the harvested rice crop. In addition to grain dimensions which determine market classes, translucency is also required for the highest grain quality. Over the last several years, the USA rice industry has been concerned about the incr...

  11. Modeling Various Teaching Methods in a Faculty of Education in Science Education: Chalk and Talk, Virtual Labs or Hovercrafts

    Science.gov (United States)

    Laronde, Gerald; MacLeod, Katarin

    2012-01-01

    This research was conducted with 291 Junior/Intermediate (J/I) pre-service teachers in a ubiquitous laptop Bachelor of Education program at Nipissing University. The authors modeled a lesson using three different teaching styles using flight as the content medium, a specific expectation found in the Ontario Ministry of Education grade six Science…

  12. Differential early diagenetic low-Mg calcite cementation and rhythmic hardground development in Campanian-Maastrichtian chalk

    DEFF Research Database (Denmark)

    Molenaar, Nicolaas; J.J.P., Zijlstra

    1997-01-01

    The Campanian-Maastrichtian limestones in the south of the Netherlands are well-sorted fine-grained mudstones and silt- to fine sand-sized bioclastic grainstones. These limestones show a distinct lithological cyclicity manifested by fining-upward grain-size cycles with calcite-cemented layers...... and differences in the degree of early diagenesis. Cemented layers and hardgrounds are the result of differential early marine calcite cementation. In these limestones early calcite cementation cannot be explained by the supply of cementing materials from saturated seawater, An alternative model for early marine...... calcite cementation is proposed, in which early calcite cementation occurred within the sediment at some distance below the seafloor as a result of organic matter degradation and internal redistribution of bioclastic carbonate. Bacterial organic matter degradation caused dissolution of relatively unstable...

  13. High-resolution onshore-offshore morpho-bathymetric records of modern chalk and granitic shore platforms in NW France

    Science.gov (United States)

    Duperret, Anne; Raimbault, Céline; Le Gall, Bernard; Authemayou, Christine; van Vliet-Lanoë, Brigitte; Regard, Vincent; Dromelet, Elsa; Vandycke, Sara

    2016-07-01

    Modern shore platforms developed on rocky coasts are key areas for understanding coastal erosion processes during the Holocene. This contribution offers a detailed picture of two contrasted shore-platform systems, based on new high-resolution shallow-water bathymetry, further coupled with aerial LiDAR topography. Merged land-sea digital elevation models were achieved on two distinct types of rocky coasts along the eastern English Channel in France (Picardy and Upper-Normandy: PUN) and in a NE Atlantic area (SW Brittany: SWB) in NW France. About the PUN case, submarine steps, identified as paleo-shorelines, parallel the actual coastline. Coastal erosive processes appear to be continuous and regular through time, since mid-Holocene at least. In SWB, there is a discrepancy between contemporary coastline orientation and a continuous step extending from inland to offshore, identified as a paleo-shoreline. This illustrates a polyphased and inherited shore platform edification, mainly controlled by tectonic processes.

  14. The View inside the Beltway: Seattle Teacher Trades in Her Chalk for a Chance to Be a Legislative Fellow

    Science.gov (United States)

    Peterson, Kristina

    2010-01-01

    National education reform happens with or without teacher input, but teachers are increasingly finding ways to enter the policy dialogue. In addition to traditional union representation and direct contact with elected representatives, emerging web 2.0 tools have created a new level of interaction between teachers and policy makers. In this…

  15. Integrated stratigraphy and paleoenvironmental reconstruction for the Late Cretaceous Danish chalk based on the Stevns-2 core

    DEFF Research Database (Denmark)

    Boussaha, Myriam; Thibault, Nicolas Rudolph; Stemmerik, Lars

    An integrated stratigraphy of the Stevns-2 core located in eastern Denmark is hereby presented based on calcareous nannofossil biostratigraphy and carbon isotope stratigraphy. Carbon and oxygen isotope have been performed on 419 bulk samples. Calcareous nannofossil biostratigraphy has been applied...... in order to provide an age-model for Stevns-2. While using this age-model, differences in the sedimentation rates of Stevns-1 and Stevns-2 borehole are nicely expressed, although the two sites are only 8 km apart from each other. The mechanisms responsible for these changes are under investigation...

  16. Teaching without a Blackboard and Chalk: Conflicting Attitudes towards Using ICTs in Higher Education Teaching and Learning

    Science.gov (United States)

    Tummons, Jonathan; Fournier, Cathy; Kits, Olga; MacLeod, Anna

    2016-01-01

    This article, derived from a three-year ethnography of distributed medical education provision in a Canadian university, explores the ways in which information and communication technologies are used by teachers and students in their everyday work within technologically rich teaching environments. The environments being researched are two…

  17. Who Wants To Be a Teacher? An Exploration of the Theory of Communal Constructivism at the Chalk Face.

    Science.gov (United States)

    Meehan, Siobhan; Holmes, Bryn; Tangney, Brendan

    2001-01-01

    Examines classroom practice in Ireland and Japan, comparing the development of Vygotsky's notion of social constructivism to that of communal constructivism (which reflects the opportunities created by information and communications technology to share and develop knowledge as a central and moral commitment in the development of learning…

  18. Chemical properties of organic soils developed from lacustrine chalk near the lakes Strzeszowskie, Sitno, and Sierakowo (Western Pomerania, north Poland

    Directory of Open Access Journals (Sweden)

    Jarnuszewski Grzegorz

    2015-12-01

    Full Text Available The genesis of organic soils is closely connected with water. The occurrence of carbonate deposits in the central and lower part of organic soil profile points to the link between their genesis and post-glacial lakes. The studies conducted in the years 2009–2012 focused on organic soils near lakes: Strzeszowskie, Sitno (Myśliborskie Lakeland and Sierakowo (Ińskie Lakeland, north Poland. The goal of the present study was to characterize chemical properties of organic soils developed on carbonate deposits. The examined soils belonged to organic muck and sapric peat soils. They contained variable amount of organic matter (32,4–66,6%. The C/N ratio depended on the degree of mineralization. The soils under study, had a high level of available forms of Ca and low level of P, K, Cu, and Zn. Both in surface and subsurface horizons of muck and sapric peat soils the content of exchangeable cations may be ranked as follows: Ca > Mg > K > Na. Basic cations total in organic horizons was distinctly higher than in calcareous sediments. In organic horizons and limnic deposits, the share of exchangeable form of Ca in the sum of basic cations exceeded 95%.

  19. Dose-effects relationships in wild populations of the aquatic snail Campeloma decisum at Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Ruedig, E. [Colorado State University (United States); Higley, K. [Oregon State University (United States)

    2014-07-01

    In the last decade regulatory bodies worldwide have implemented standards to protect populations of non-human biota (NHB) from the consequences of radiation exposure. This is a departure from previous regulatory frameworks, which were concerned only with protecting man. The implementation of these new standards initiated an ongoing discussion concerning appropriate dose-rate limits for NHB. For the most part, the data utilized for estimating appropriately protective dose-rate limits has come from data collected via the irradiation of NHB in a laboratory setting. While some dose-effects studies have been performed under field conditions, such experiments represent a minority of the available data. This deficit in the literature has resulted in challenges to the established paradigm, with researchers reporting increased radiosensitivity in NHB under field conditions. However, many such studies overlook critical components of dose-effects analysis: lacking either robust ecological technique or dosimetric rigor. The study cited herein provides rigorous analysis of factors affecting populations of aquatic snails and is intended as a framework for identifying those factors statistically indicative of snail population. These benchmarks (e.g., number of snails, mass of individuals) were employed as proxies for snail population health, and how it was impacted by over two dozen environmental variables. Dose-rates were calculated via a novel voxel model, developed for this study to estimate internal dose rates for the species of interest. A linear regression model was employed to tease out the relationship between individual snails, their environment, and radiation dose rate. There was no evidence that snail population health was influenced by radiation exposure (p=0.70) at the observed dose rates. Of the environmental variables tested, water concentration of Ca was well correlated with snail mass size (p<0.001), while water concentration of P was well correlated with the number of snails lured to a trap (p<0.001). The protocols and procedures developed as a part of this study represent novel, robust techniques for evaluating the relationship between radiation dose and population effects in NHB. Oregon State University would like to gratefully acknowledge funding from Atomic Energy of Canada Limited for this project. Document available in abstract form only. (authors)

  20. Investigating controls on debris-flow initiation and surge frequency at Chalk Cliffs, USA: initial results from monitoring and modeling

    Science.gov (United States)

    Kean, J. W.; McCoy, S. W.; Tucker, G. E.; Staley, D. M.; Coe, J. A.

    2012-04-01

    Recent monitoring of a small (0.3 km2) bedrock-dominated catchment in central Colorado, USA, has revealed distinct differences in debris-flow surge dynamics relative to rainfall intensity. Moderate bursts of rainfall (15-40 mm/hr) typically trigger a set of coarse-grained surges with depths that can exceed 1.0 m. High-intensity bursts of rainfall (40-150 mm/hr), in contrast, often generate only a single moderate-amplitude coarse-grained surge (> 0.5 m depth), followed by several minutes of water-rich flow having comparable or greater peak depth. In both cases, debris flows are observed within minutes of rain bursts due to the rapid concentration of runoff from bedrock cliffs to channels loaded with sediment from dry ravel and rockfall. Video observations have shown that the runoff can initiate debris flows both at a steep (~40 degree) bedrock-colluvium interface, and in a lower gradient (~15 degree) section of channel. This latter style of initiation, which has only been observed at moderate rainfall intensity, involves the formation and failure of a highly porous sediment dam created by bedload transport. We speculate that this process may be responsible for the creation of the consistent surge patterns we observe with moderate intensity rainfall, and may explain the relative lack of granular surges with high-intensity rainfall. To investigate this possibility, we have developed a simple one-dimensional morphodynamic model of the formation and failure of sediment dams in an undulating bedrock channel filled with loose bed sediment. The model consists of a coupled surface-subsurface water flow model, which is used to drive bed-sediment topographic adjustments based on the mathematical divergence of the sediment transport rate. Under certain topographic and water-flow conditions, the shear stress in a section of the channel can fall below the critical shear stress, resulting in local deposition of sediment. Consistent with field observations, the modeled deposit grows in height with the addition of sediment from upstream, while water runoff is sieved through the porous dam. A simple Mohr-Coulomb slope stability model is used to evaluate the balance of forces on the dam and determine when the dam begins to move as a debris flow. Initial model results are in qualitative agreement with our field observations of surge characteristics. The calculations show that, given sufficient sediment supply, multiple episodes of dam failure could occur at the relatively low transport stages associated with moderate intensity rainfall. Rapid in-channel accumulation of sediment needed for dam formation and debris-flow initiation is less likely during the increased runoff associated with high rainfall intensity, because the high shear stress and transport stage inhibit deposition. These observations highlight that for runoff-generated debris flows, moderate rainfall can produce deep and destructive debris flows due to the likely initiation of granular surges.

  1. 水蛭炮制前后质量比较%Quality comparison of Hirudo before and after processed by French chalk

    Institute of Scientific and Technical Information of China (English)

    张永太

    2008-01-01

    目的:讨论炮制方法对水蛭的影响.方法:以热浸法测定水溶性浸出物与醇溶性浸出物的含量;以凝血酶法测定水蛭素的含量;以HPLC测定次黄嘌呤的含量.结果:生水蛭的含水量,水溶性浸出物含量,醇溶性浸出物含量,水蛭素含量,均高于制水蛭的含量,而制水蛭的次黄嘌呤含量则高于生水蛭的次黄嘌呤含量.结论:滑石粉炒水蛭使水蛭药性峻烈的活性成分含量降低,从而降低毒性,缓和其破血通经之性.

  2. Soil and plant factors driving the community of soil-borne microorganisms across chronosequences of secondary succession of chalk grasslands with a neutral pH.

    Science.gov (United States)

    Kuramae, Eiko; Gamper, Hannes; van Veen, Johannes; Kowalchuk, George

    2011-08-01

    Although soil pH has been shown to be an important factor driving microbial communities, relatively little is known about the other potentially important factors that shape soil-borne microbial community structure. This study examined plant and microbial communities across a series of neutral pH fields (pH=7.0-7.5) representing a chronosequence of secondary succession after former arable fields were taken out of production. These fields ranged from 17 to >66 years since the time of abandonment, and an adjacent arable field was included as a reference. Hierarchical clustering analysis, nonmetric multidimensional scaling and analysis of similarity of 52 different plant species showed that the plant community composition was significantly different in the different chronosequences, and that plant species richness and diversity increased with time since abandonment. The microbial community structure, as analyzed by phylogenetic microarrays (PhyloChips), was significantly different in arable field and the early succession stage, but no distinct microbial communities were observed for the intermediate and the late succession stages. The most determinant factors in shaping the soil-borne microbial communities were phosphorous and NH(4)(+). Plant community composition and diversity did not have a significant effect on the belowground microbial community structure or diversity.

  3. Sewage effluent clean-up reduces phosphorus but not phytoplankton in lowland chalk stream (River Kennet, UK) impacted by water mixing from adjacent canal.

    Science.gov (United States)

    Neal, Colin; Martin, Ellie; Neal, Margaret; Hallett, John; Wickham, Heather D; Harman, Sarah A; Armstrong, Linda K; Bowes, Mike J; Wade, Andrew J; Keay, David

    2010-10-15

    Information is provided on phosphorus in the River Kennet and the adjacent Kennet and Avon Canal in southern England to assess their interactions and the changes following phosphorus reductions in sewage treatment work (STW) effluent inputs. A step reduction in soluble reactive phosphorus (SRP) concentration within the effluent (5 to 13 fold) was observed from several STWs discharging to the river in the mid-2000s. This translated to over halving of SRP concentrations within the lower Kennet. Lower Kennet SRP concentrations change from being highest under base-flow to highest under storm-flow conditions. This represented a major shift from direct effluent inputs to a within-catchment source dominated system characteristic of the upper part to the catchment. Average SRP concentrations in the lower Kennet reduced over time towards the target for good water quality. Critically, there was no corresponding reduction in chlorophyll-a concentration, the waters remaining eutrophic when set against standards for lakes. Following the up gradient input of the main water and SRP source (Wilton Water), SRP concentrations in the canal reduced down gradient to below detection limits at times near its junction with the Kennet downstream. However, chlorophyll concentrations in the canal were in an order of magnitude higher than in the river. This probably resulted from long water residence times and higher temperatures promoting progressive algal and suspended sediment generations that consumed SRP. The canal acted as a point source for sediment, algae and total phosphorus to the river especially during the summer months when boat traffic disturbed the canal's bottom sediments and the locks were being regularly opened. The short-term dynamics of this transfer was complex. For the canal and the supply source at Wilton Water, conditions remained hypertrophic when set against standards for lakes even when SRP concentrations were extremely low.

  4. 饱和多孔白垩岩的孔隙力学性质研究%STUDY ON POROMECHANIC BEHAVIOURS OF SATURATED POROUS CHALK

    Institute of Scientific and Technical Information of China (English)

    谢守益; 徐卫亚; 贾赟; 邵建富

    2007-01-01

    研究表明,白垩岩具有两种相互独立的塑性力学机制:塑性孔隙坍塌和塑性剪切变形.据此,一个基于Gurson准则和Pietruszczak准则的本构模型被提出用来描述其塑性力学特性.该模型包含2个屈服面方程和相应的塑性流动准则,在排水条件下进行验证并获得满意的结果.然而,白垩岩力学性质除受其矿物组成、结构以及饱和条件等因素的影响外,孔隙压力对其力学特征同样具有重要影响.因此,研究饱和多孔白垩岩的力学特性必须考虑孔隙压力的影响.基于这一认识,将Coussy孔隙塑性理论扩展用于研究饱和白垩岩的孔隙塑性力学特性,根据孔隙弹塑性力学的一般框架,讨论在弹塑性域上有效应力尤其是塑性有效应力概念的有效性.通过将本构模型中两种塑性力学机制的塑性加载函数和塑性潜能表达成塑性有效应力的函数,就能够研究饱和多孔白垩岩在考虑孔隙压力变化条件下的孔隙力学性质,研究在不排水条件下,特别是在不排水三轴压缩条件下白垩岩的塑性力学特性.数值模拟和试验结果之间存在很好的特性上的一致性.研究结果表明,通过采用塑性有效应力概念的方法提出的本构模型能用来描述饱和多孔白垩岩的孔隙力学特性.

  5. 多孔岩石塑性压缩本构模型研究%CONSTITUTIVE MODEL OF PLASTIC COMPACTION FOR POROUS CHALK

    Institute of Scientific and Technical Information of China (English)

    谢守益; 徐卫亚; 邵建富

    2005-01-01

    白垩是一种典型的多孔岩石,三轴试验研究成果表明白垩具有2种塑性力学机理:塑性压缩(孔隙坍塌)和剪切破坏.孔隙度对白垩的塑性力学特征有重要影响,在描述白垩塑性行为的本构方程中,特别是描述塑性压缩(孔隙坍塌)的塑性力学机理,需要考虑孔隙的影响.基于对白垩力学机理的认识,建立了基于Gurson屈服准则的本构关系用来描述白垩的塑性压缩(孔隙坍塌)机理的本构模型,模拟结果与试验成果相一致.

  6. Observations on north-west European limestone grassland communities. V, b. An experimental approach to the study of species diversity and above-ground biomass in chalk grassland

    NARCIS (Netherlands)

    Willems, J.H.

    1980-01-01

    In plots B1, 2, and 4 in 1978 only a single species once covered over 12.5% of the surface: Leontodon hispidus. A few species covered sometimes about 5-10%, like Briza media, Triselum flavescens, Lotus corniculatus, Leontodon hispidus, and Knautia arvensis. In the course of the study the occasional

  7. PAH occurrence in chalk river systems from the Jura region (France). Pertinence of suspended particulate matter and sediment as matrices for river quality monitoring.

    Science.gov (United States)

    Chiffre, Axelle; Degiorgi, François; Morin-Crini, Nadia; Bolard, Audrey; Chanez, Etienne; Badot, Pierre-Marie

    2015-11-01

    This study investigates the variations of polycyclic aromatic hydrocarbon (PAH) levels in surface water, suspended particulate matter (SPM) and sediment upstream and downstream of the discharges of two wastewater treatment plant (WWTP) effluents. Relationships between the levels of PAHs in these different matrices were also investigated. The sum of 16 US EPA PAHs ranged from 73.5 to 728.0 ng L(-1) in surface water and from 85.4 to 313.1 ng L(-1) in effluent. In SPM and sediment, ∑16PAHs ranged from 749.6 to 2,463 μg kg(-1) and from 690.7 μg kg(-1) to 3,625.6 μg kg(-1), respectively. Investigations performed upstream and downstream of both studied WWTPs showed that WWTP discharges may contribute to the overall PAH contaminations in the Loue and the Doubs rivers. Comparison between gammarid populations upstream and downstream of WWTP discharge showed that biota was impacted by the WWTP effluents. When based only on surface water samples, the assessment of freshwater quality did not provide evidence for a marked PAH contamination in either of the rivers studied. However, using SPM and sediment samples, we found PAH contents exceeding sediment quality guidelines. We conclude that sediment and SPM are relevant matrices to assess overall PAH contamination in aquatic ecosystems. Furthermore, we found a positive linear correlation between PAH contents of SPM and sediment, showing that SPM represents an integrating matrix which is able to provide meaningful data about the overall contamination over a given time span.

  8. Integrated seismic analysis of the Chalk Group in eastern Denmark—Implications for estimates of maximum palaeo-burial in southwest Scandinavia

    DEFF Research Database (Denmark)

    Nielsen, Lars; Boldreel, Lars Ole; Hansen, Thomas Mejer;

    2011-01-01

    The origin of the topography of southwest Scandinavia is subject to discussion. Analysis of borehole seismic velocity has formed the basis for interpretation of several hundred metres of Neogene uplift in parts of Denmark.Here, refraction seismic data constrain a 7.5km long P-wave velocity model...... Group. The sonic velocities are consistent with the overall seismic layering, although they show additional fine-scale layering. Integration of gamma and sonic log with porosity data shows that seismic velocity is sensitive to clay content. In intervals near boundaries of the refraction model, moderate...

  9. Fractures and Rock Mechanics, Phase 1

    DEFF Research Database (Denmark)

    Havmøller, Ole; Krogsbøll, Anette

    1997-01-01

    The main objectives of the project are to combine geological description of fractures, chalk types and rock mechanical properties, and to investigate whether the chosen outcrops can be used as analogues to reservoir chalks. Five chalk types, representing two outcrop localities: Stevns and Hillers......The main objectives of the project are to combine geological description of fractures, chalk types and rock mechanical properties, and to investigate whether the chosen outcrops can be used as analogues to reservoir chalks. Five chalk types, representing two outcrop localities: Stevns...

  10. Electric dewatering and drying of fine-grained products; Elektrisk afvanding og toerring af finkornede produkter

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, H.K.; Villumsen, A.

    2001-07-01

    The aim of the project was to elucidate four aspects related to using electric direct current to find an energy saving alternative to existing methods within dewatering of fine-grained products. The four aspects were a) electrophoresis forced sedimentation of chalk slurry, b) electro osmotic dewatering of chalk slurry, c) electro osmotic dewatering of agricultural chalk and d) electro osmotic dewatering of liquid organic wastes. (EHS)

  11. 48 CFR 25.104 - Nonavailable articles.

    Science.gov (United States)

    2010-10-01

    .... Chalk, English. Chestnuts. Chicle. Chrome ore or chromite. Cinchona bark. Cobalt, in cathodes, rondelles..., blocks, and pigs. Triprolidine hydrochloride. Tungsten. Vanilla beans. Venom, cobra. Water chestnuts....

  12. Fractures and Rock Mechanics, Phase 1

    DEFF Research Database (Denmark)

    Krogsbøll, Anette; Jakobsen, Finn; Madsen, Lena

    1997-01-01

    The main objective of the project is to combine geological descriptions of fractures, chalk types and rock mechanical properties in order to investigate whether the chosen outcrops can be used as analogues to reservoir chalks. This report deals with 1) geological descriptions of outcrop locality...

  13. Resistivity Index Measurement without the Porous Plate

    DEFF Research Database (Denmark)

    Springer, N.; Korsbech, Uffe C C; Aage, Helle Karina

    2003-01-01

    A Desaturation Technique Based on Evaporation Produces Uniform Water Saturation Profiles and More Reliable Results for Tight North Sea Chalk......A Desaturation Technique Based on Evaporation Produces Uniform Water Saturation Profiles and More Reliable Results for Tight North Sea Chalk...

  14. Decomposition and reduction of N2O over Limestone under FBC Conditions

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Jensen, Anker; Vaaben, Rikke;

    1997-01-01

    The addition of limestone for sulfur retention in FBC has in many cases been observed to influence the emission of N2O. The catalytic activity of N2O over calcined Stevns Chalk for decomposition of N2O in a laboratory fixed bed quartz reactor was measured. It was found that calcined Stevns Chalk ...

  15. 77 FR 26438 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Approval of 2011 Consent...

    Science.gov (United States)

    2012-05-04

    ... SIP for the GenOn Chalk Point generating station located at 25100 Chalk Point Road in Aquasco... units each rated at 355 megawatts. Units 3 and 4 are cycling units permitted to burn natural gas and oil... review by the Office of Management and Budget under Executive Order 12866 (58 FR 51735, October 4,...

  16. Particle diffusion in complex nanoscale pore networks

    DEFF Research Database (Denmark)

    Müter, Dirk; Sørensen, Henning Osholm; Bock, H.;

    2015-01-01

    We studied the diffusion of particles in the highly irregular pore networks of chalk, a very fine-grained rock, by combining three-dimensional X-ray imaging and dissipative particle dynamics (DPD) simulations. X-ray imaging data were collected at 25 nm voxel dimension for two chalk samples with v...

  17. Mechanisms regulating proteostasis are involved in sympatric speciation of the blind mole rat, Spalax galili.

    Science.gov (United States)

    Rodriguez, Karl A; Li, Kexin; Nevo, Eviatar; Buffenstein, Rochelle

    2016-01-01

    Genome-wide analysis demonstrates extensive genomic adaptive complexes involved in sympatric speciation between blind mole rats (Spalax galili) in abutting populations living in basalt and chalk soils. Among the gene ontology (GO) enrichment, musculature and metabolism stood out in basalt dwellers while nutrition and neurogenetics were highlighted in chalk residents. Measurements of mechanisms regulating protein homeostasis inspired by these GO terms suggest that at the proteomic level there is also a habitat/soil-type driven divergence with the basalt residents exhibiting higher proteasome activity whereas elevated levels of markers of autophagy are evident in the chalk inhabitants.

  18. A Narrative Inquiry of Bertolt Brecht's Epic Theatre——Taking The Caucasian Chalk Circle as an example%布莱希特戏剧的叙述性探究——以《高加索灰阑记》为例

    Institute of Scientific and Technical Information of China (English)

    张智; 周芳

    2011-01-01

    布莱希特创立的以"间离-思考-行动"为核心模式的"叙事剧"戏剧理论要求把叙述性、评论性因素引入戏剧舞台,主张"舞台叙述事件",从而引导观众进行理性的评判和自我反思.布莱希特成熟期所创作的是其叙事剧理论最彻底的体现,该剧从剧本结构、表演手法、戏剧功能等方面很好地实践了他以"间离效果"为核心的"叙事剧"理论.

  19. As Like as Chalk and Cheese--Thoughts on Reading The "Great Cultural Revolution" in France in May 1968%貌似而实非--读《1968年5月法国的"文化大革命"》

    Institute of Scientific and Technical Information of China (English)

    金春明

    2005-01-01

    @@ 放在案头的一本书,把我的思绪不由自主地带进了似乎发生在昨天,许多事仍清晰在目,而实际上已相距近40年的历史回忆之中.这本书就是由法国人洛朗·若弗兰(Joffrin,L)著、中国教授万家星翻译的(原著名,法国瑟伊出版社1990年版,中文译本为长江文艺出版社2004年版).

  20. Facts About Color Blindness

    Science.gov (United States)

    ... perception of its employees, such as graphic design, photography, and food quality inspection. The Farnsworth Lantern Test ... a green chalkboard when yellow chalk is used. Art classes, which require selecting appropriate colors of paint ...

  1. Protect Your Family from Lead in Your Home

    Science.gov (United States)

    ... Hazards Deteriorating lead-based paint (peeling, chipping, chalking, cracking, or damaged paint) is a hazard and needs ... Housing Rule, which protects families in pre-1978 assisted housing, and for the lead hazard control and ...

  2. Down by the Seashore.

    Science.gov (United States)

    Alexander, Robin; Robyn, Turner

    1982-01-01

    Describes a combined art and science study of animals in which fourth graders studied seashells. Students made contour drawings of shells using pastel chalks and experimented to see how different colored lines affected the appearance of their shells' shapes. (AM)

  3. 76 FR 27988 - Certain Cased Pencils From the People's Republic of China: Final Results of the Antidumping Duty...

    Science.gov (United States)

    2011-05-13

    ... of China: Preliminary Results and Partial Rescission of Antidumping Duty Administrative Review, 76 FR..., pens, non-cased crayons (wax), pastels, charcoals, chalks, and pencils produced under U.S....

  4. Пираты третьего тысячелетия / коммент. Питер Чалк, Гордан Ван Хук

    Index Scriptorium Estoniae

    2009-01-01

    Piraatlusest Somaalia piirkonnas ja rahvusvahelistest alusdokumentidest piraatluse vastu võitlemiseks 21. sajandil. Kommenteerivad uurimiskeskuse RAND Corporation vanempoliitanalüütik Peter Chalk ja transpordikompanii Maersk Line innovatsiooni ja arenduse vanemdirektor Gordan Van Hook

  5. New Clues to Age-Related Hearing Loss

    Science.gov (United States)

    ... fullstory_161359.html New Clues to Age-Related Hearing Loss Older people's brains have a harder time processing ... conversation, many older people chalk it up to hearing loss. But a new, small study finds that the ...

  6. Methamphetamine (Meth)

    Science.gov (United States)

    ... Enter Search Term(s): Teens / Drug Facts / Methamphetamine (Meth) Methamphetamine (Meth) Street names: Crank, Crystal, Speed Print What is methamphetamine (meth)? Also known as: Meth, Speed, Chalk, and ...

  7. Neutralisation of acid quarry water; Neutralisation de l'acide des eaux de carriere

    Energy Technology Data Exchange (ETDEWEB)

    Ladnorg, U. [WBB Fuchs GmbH and Co. KG, Salzerstrabe, Ransbach-Baumbach (Germany); Brendl, H.G. [Schaefer Kalk KG, Louise-Seher-Strabe, Diez (Germany)

    2003-01-01

    To neutralize acid quarry water, linked to the existing brown coal seam, WBB Fuchs developed a system based on a highly reactive chalk lime with the Schaefer Kalk company. This system is described in the following article. (author)

  8. Rõõm muusikast / Mati Märtin

    Index Scriptorium Estoniae

    Märtin, Mati

    2005-01-01

    Ülestõusmispühade-kontsertidest Tallinna kirikutes: Päästearmee Londoni puhkpilliorkestri Chalk Farm Band kontserdist Kaarli kirikus, Eesti Muusikaakadeemia õpilaste kontserdist Jaani kirikus, Leedsi Filharmoonia Segakoori kontserdist Kaarli kirikus

  9. Proceedings: TRIAGE of Irradiated Personnel, 25-27 September 1996

    Science.gov (United States)

    1998-03-01

    Social Medicine , University of Ulm, Ulm, Germany * Dose Estimation Using Lymphocyte Depletion Kinetics Ronald E. Goans, Elizabeth C. Holloway, Mary...Fliedner eral times below 0.5 x 100 per 1 and platelet Institute of Occupational and Social Medicine counts dropping several times below 50 x 109...Institute for Occupational and Social Medicine Chalk River Nuclear Lab University of Ulm Chalk River, ON KOJ IJO, Canada D-89070 Ulm (Donau), Germany Sharon

  10. Fractures and rock mechanics, Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Knowledge of fracture occurrence and orientation in chalk is important for optimum field development planning and evaluation of well-bore stability. The combined geological and geotechnical studies carried out under the EFP-96 and EFP-98 programmes have investigated the influence of fractures on rock mechanics properties for chalk. Data for quantifying the effect of natural fractures in chalk have been supplied by triaxial testing in normal scale and large scale on samples from three chalk types, namely from Valhall Tor and Tyra Maastrichtian and an outcrop locality at Hillerslev. >From the latter locality special big cylindrical specimens were sampled for the large scale triaxial testing (500x500 mm) in order to get at true representation of the natural fracturing in the Hillerslev chalk. By comparing test results from normal scale to large scale on fractured and non fractured specimens it was found that the stiffness of the chalk is dependent on scale while the shear strength generally seems to depend on fractures and not on scale. Furthermore the studies revealed, that fractures have a significant reducing effect on the shear strength, that characterisation by the Geological Strength Index, GSI, on fractured test specimens igve a very good prediction of shear, that shear failure and yield surface characteristics for fractued and intact chalk can be provided using GSI, that up-scaling influence the elastic deformation properties in the low stress regime and that fractures influence the compressibility in the elastic stress regime, but not in the plastic stress regime. Finally, the practical application of some of the results on reservoir chalk has been addressed, especially the up-scaling of strength and deformation properties from normal scale tests to reservoir conditions. The up-scaling laws are relevant for borehole stability problems but not for compaction. Generally, the observations in the study are relevant for quantifying the effect of fracturing and

  11. The impact of broadleaved woodland on water resources in lowland UK: III. The results from Black Wood and Bridgets Farm compared with those from other woodland and grassland sites

    Directory of Open Access Journals (Sweden)

    J. Roberts

    2005-01-01

    Full Text Available In the United Kingdom the planting of broadleaved woodland has led to concerns about the impact on water resources. Comparative studies, typically using soil water measurements, have been established to compare water use of broadleaved woodland and grassland. The diversity of outcomes from these studies makes it difficult to make any consistent prediction of the hydrological impact of afforestation. Most studies have shown greater drying of soils under broadleaved woodland than under grass. However, two studies in a beech wood growing on shallow soils above chalk at Black Wood, Micheldever, Hampshire showed little overall difference between broadleaved woodland and grass, either in soil water abstraction or in evaporation. Two factors are thought to contribute to the different results from Black Wood. It is known that evaporation can be considerably enhanced at the edges of woodlands or in small areas of woodlands. The studies at Black Wood were made well within a large area of fairly uniform woodland. Other studies in which a difference occurred in soil drying between broadleaved woodland and grass used measurements made in small areas of woodlands or at woodland edges. Another important difference between comparison of woodland at Black Wood and grassland growing nearby, also on shallow soils above Chalk, compared to other broadleaved woodland/grass comparisons, growing on other geologies, is the influence of the Chalk. Although vegetation such as grass (and woodland does not populate the chalk profusely with roots, water can be removed from the Chalk by the roots which proliferate at the soil/chalk interface and which can generate upward water movement within the Chalk. Published work showed that only in a very dry summer did the evaporation from grass growing on shallow soils above chalk fall below potential. In broadleaved woodland/grass comparisons on non-chalky soils it is possible that moisture deficits in the soil below the grass may

  12. Adsorption of Carboxylic Acids on Reservoir Minerals from Organic and Aqueous Phase

    DEFF Research Database (Denmark)

    Madsen, Lene; Lind, Ida

    1998-01-01

    Adsorption of organic acids onto North Sea chalk and pure minerals from a hydrocarbon phase and an aqueous phase show that the maximum adsorption is larger for calcite than for silicate surfaces in the hydrocarbon phase. The opposite is observed, however, in the aqueous phase. This suggests that ...... that the available silicate surfaces and oil/water ratio may play a role in the wettability of chalk....

  13. Adaptive methylation regulation of p53 pathway in sympatric speciation of blind mole rats, Spalax.

    Science.gov (United States)

    Zhao, Yang; Tang, Jia-Wei; Yang, Zhi; Cao, Yi-Bin; Ren, Ji-Long; Ben-Abu, Yuval; Li, Kexin; Chen, Xue-Qun; Du, Ji-Zeng; Nevo, Eviatar

    2016-02-23

    Epigenetic modifications play significant roles in adaptive evolution. The tumor suppressor p53, well known for controlling cell fate and maintaining genomic stability, is much less known as a master gene in environmental adaptation involving methylation modifications. The blind subterranean mole rat Spalax eherenbergi superspecies in Israel consists of four species that speciated peripatrically. Remarkably, the northern Galilee species Spalax galili (2n = 52) underwent adaptive ecological sympatric speciation, caused by the sharply divergent chalk and basalt ecologies. This was demonstrated by mitochondrial and nuclear genomic evidence. Here we show that the expression patterns of the p53 regulatory pathway diversified between the abutting sympatric populations of S. galili in sharply divergent chalk-basalt ecologies. We identified higher methylation on several sites of the p53 promoter in the population living in chalk soil (chalk population). Site mutagenesis showed that methylation on these sites linked to the transcriptional repression of p53 involving Cut-Like Homeobox 1 (Cux1), paired box 4 (Pax 4), Pax 6, and activator protein 1 (AP-1). Diverse expression levels of p53 between the incipiently sympatrically speciating chalk-basalt abutting populations of S. galili selectively affected cell-cycle arrest but not apoptosis. We hypothesize that methylation modification of p53 has adaptively shifted in supervising its target genes during sympatric speciation of S. galili to cope with the contrasting environmental stresses of the abutting divergent chalk-basalt ecologies.

  14. Musculoskeletal demands of progressions for the longswing on high bar.

    Science.gov (United States)

    Irwin, Gareth; Kerwin, David G

    2007-09-01

    Kinetic analyses of the chalked bar longswing on high bar and its associated progressions were used to explain musculoskeletal contributions during the performance of these skills. Data on four international male gymnasts performing three series of chalked bar longswings and eight progressions were recorded. Customized body segment inertia parameters, two-dimensional kinematics (50 Hz), and bar forces (1000 Hz) were used as input to inverse dynamic modelling. The analysis focused on the relative contributions of the knees, hips, and shoulders with root mean squared differences between the chalked bar longswing and the progressions being used to rank the progressions. Seventy per cent of the total work occurred between 200 degrees and 240 degrees of angular rotation in the longswing, 67% of which was contributed by the shoulders. The shoulders were also dominant in all progressions, with the largest such contribution occurring in the looped bar longswing with "no action". The least similar progression was the looped bar pendulum swing, while the most similar was the chalked bar bent knee longswing. This study provides a useful means for ranking progressions based on their kinetic similarity to the chalked bar longswing and builds on earlier research in identifying that progressions can be classified into those similar in physical demand (kinetics) and those similar in geometry (kinematics).

  15. POWERPOINT PRESENTATION VS BLACKBOARD TEACHING: A COMPARATIVE STUDY AND EVALUATION IN GOVERNMENT MEDICAL COLLEGE, ANANTHAPURAMU, ANDHRA PRADESH FOR II M.B.B.S STUDENTS: A QUESTIONNAIRE BASED STUDY

    Directory of Open Access Journals (Sweden)

    Ramachandrudu

    2016-03-01

    Full Text Available Chalk talk lecture is the oldest and most commonly used teaching technique. However, it is also common to use PowerPoint presentations after the introduction of digitalized teaching in medical colleges. This study is done to compare effectiveness of PowerPoint lecture with Conventional chalk talk lecture. AIM This study is designed to determine effectiveness of Chalk Talk Teaching vs. PowerPoint Teaching in medical education. METHODS This study was done on three successive batches of II M.B.B.S students from the year August 2013–December 2015 (Total 300 students in Government Medical College, Ananthapuramu, Andhra Pradesh, after getting approved by Institutional Ethical committee and informed consent from the students. During regular Pharmacology Lectures, the students were divided into 2 classes. One class (150 had a chalk talk lecture, while the other class (150 had PowerPoint lecture. At the end of each lecture, a questionnaire (Containing 10 open ended Questions is given to all the students of the class. STATISTICS Descriptive statistics was used to analyse data and results were expressed in terms of percentage. RESULTS Students of both the groups answered questions related to memory and calculations well. However, the students of PowerPoint group answered in a better way to questions related to “Understanding and memorizing.” In this study, 85% of the students preferred PowerPoint and only 15% preferred conventional chalk talk.

  16. Smaller calcite lattice deformation caused by occluded organic material in coccoliths than in mollusk shell

    DEFF Research Database (Denmark)

    Frølich, Simon; Sørensen, Henning Osholm; Hakim, Sepideh Sadat

    2015-01-01

    The growth and nucleation of biominerals are directed and affected by associated biological molecules. In this paper, we investigate the influence of occluded biomolecules on biogenic calcite from the coccolithophorid Pleurochrysis carterae and from chalk, a rock composed predominantly of fossil....... Two heating cycles allow us to differentiate the effects of thermal agitation and organic molecules. Single peak analysis and Rietveld refinement were combined to show significant differences resulting from the occluded biomolecules on the mineral phase in biogenic calcite in the mollusk shell....... This suggests that the interaction between biomolecules and calcite is not as tight in the coccoliths as in the shell. Although the shape of chalk has been preserved over millions of years, no major influence on the crystal lattice was observed in the chalk samples....

  17. The Skælskør structure in eastern Denmark – wrench-related anticline or primary Late Cretaceous sea-floor topography?

    DEFF Research Database (Denmark)

    Surlyk, Finn; Boldreel, Lars Ole; Lykke-Andersen, Holger;

    2010-01-01

    Sorgenfrei (1951) identified a number of NW–SE oriented highs in the Upper Cretaceous – Danian Chalk Group in eastern Denmark, including the Skælskør structure and interpreted them as anticlinal folds formed by wrenching along what today is known as the Ringkøbing-Fyn High. Recent reflection...... seismic studies of the Chalk Group in Øresund and Kattegat have shown that similar highs actually represent topographic highs on the Late Cretaceous – Danian seafloor formed by strong contourparallel bottom currents. Reflection seismic data collected over the Skælskør structure in order to test...... the hypothesis of Sorgenfrei show that the Base Chalk reflection is relatively flat with only very minor changes in inclination and cut by only a few minor faults. The structure is situated along the northern margin of a high with roots in a narrow basement block, projecting towards the northwest from...

  18. Trace elements in a North Sea drill core

    DEFF Research Database (Denmark)

    Kunzendorf, Helmar; Gwozdz, R.; Svendsen, N.

    1986-01-01

    , V, Sr, Dy, Mg, Ti, Ba and Eu. The major elements Ca and Al could be related to petrophysical parameters, particularly Al which shows a correlation with the silicification/argillaceous content. Na (and Cl) has a low content in the hydrocarbon-bearing section of the drill core suggesting that the pore...... space is filled mainly by hydrocarbons. A significant decrease of Mn with depth probably suggests diagenesis of chalk prior to, or with, hydrocarbon emplacement. Investigations of drilling fluids and cuttings reveal a strong contamination of the latter, mainly by Ba. Chalk data from comparable onshore...

  19. Preventing Health Damaging Behaviors in Male and Female Army Recruits

    Science.gov (United States)

    2009-01-01

    Saturday Night” handout, five pieces of self-adhesive flip chart paper that states, “Working Together To Drink Safely: Things I Can Do to Stay...chalk board/rolled paper (or four to eight pieces of flip chart paper on the wall in the shape of square or rectangle), different color markers

  20. Changing climate and microbial resources in polar realms

    Digital Repository Service at National Institute of Oceanography (India)

    LokaBharathi, P.A.

    of a varied compounds with wide ranging applications in many fields. It would be pertinent to examine their role in polar climate and appreciate the products that are already being harnessed from these regions. Then it would be possible to chalk out...

  1. Teaching Design in the First Years of a Traditional Mechanical Engineering Degree: Methods, Issues and Future Perspectives

    Science.gov (United States)

    Silva, Arlindo; Fontul, Mihail; Henriques, Elsa

    2015-01-01

    Engineering design is known as an answer to an ill-defined problem. As any answer to an ill-defined problem, it can never be completely right or absolutely wrong. The methods that universities use to teach engineering design, as a consequence of this, suffer from the same fate. However, the accumulated experience with the "chalk and…

  2. Empirical Estimation of Computer Animation as a Self-Study Material for Science Learning

    Science.gov (United States)

    Tannu, Kirti

    2009-01-01

    The advent of technology is almost in the field of education for teaching -- learning and cannot be ignored. Students are exposed to superior quality product of advance technologies in other fields around them. In such a scenario whether chalk and black board education is relevant in today's multicoloured and multidimensional digital age? The…

  3. Powerpoint Presentation in Learning Physiology by Undergraduates with Different Learning Styles

    Science.gov (United States)

    Ankad, Roopa B.; Shashikala, G. V.; Herur, Anita; Manjula, R.; Chinagudi, Surekharani; Patil, Shailaja

    2015-01-01

    PowerPoint presentations (PPTs) have become routine in medical colleges because of their flexible and varied presentation capabilities. Research indicates that students prefer PPTs over the chalk-and-talk method, and there is a lot of debate over advantages and disadvantages of PPTs. However, there is no clear evidence that PPTs improve student…

  4. LABORATORY INVESTIGATIONS OF SILICATE MUD CONTAMINATION WITH CALCIUM

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2004-12-01

    Full Text Available The silicate-based drilling fluid is a low solids KCl/polymer system with the addition of soluble sodium or potassium silicate to enhance inhibition and wellbore stability. Silicate-based drilling fluids exhibit remarkable shale and chalk stabilizing properties, resulting in gauge hole and the formation of firm cuttings when drilling reactive shales and soft chalks. Silicates protect shales by in-situ gellation when exposed to the neutral pore fluid and precipitation, which occurs on contact with divalent ions present at the surface of the shale. Also, silicates prevent the dispersion and washouts when drilling soft chalk by reacting with the Ca2+ ions present on chalk surfaces of cutting and wellbore to form a protective film. The silicate-based drilling fluid can be used during drilling hole section through shale interbeded anhydrite formations because of its superior shale stabilizing characteristics. However, drilling through the anhydrite can decrease the silicate concentration and change rheological and filtration fluid properties. So, the critical concentration of calcium ions should be investigated by lab tests. This paper details the mechanism of shale inhibition using silicate-based drilling fluid, and presents results of lab tests conducted to ascertain the effect of Ca2+ ions on silicate level in the fluid and the fluid properties.

  5. Spectacular Skies

    Science.gov (United States)

    Nickerson, Jessica

    2008-01-01

    Marbling paper is a favorite in many elementary classrooms. The marbling project described in this article, using a sunset and silhouette concept, is foolproof, inexpensive, and engaging. After looking at images of incredible sunsets for inspiration, each student uses marbling paper, black construction paper, three colors of chalk, and a tub of…

  6. Overhauling Technical Handouts for Active Student Participation: A Model for Improving Lecture Efficiency and Increasing Attendance

    Science.gov (United States)

    Jakee, Keith

    2011-01-01

    This instructional paper is intended to provide an alternative approach to developing lecture materials, including handouts and PowerPoint slides, successfully developed over several years. The principal objective is to aid in the bridging of traditional "chalk and talk" lecture approaches with more active learning techniques, especially in more…

  7. Determining optimum aging time using novel core flooding equipment

    DEFF Research Database (Denmark)

    Ahkami, Mehrdad; Chakravarty, Krishna Hara; Xiarchos, Ioannis;

    2016-01-01

    to consistently investigate the change of wettability during aging. At 60°C and 100 bars a homogeneous sandstone coreplug attained optimized wettability after 5 days, a heterogeneous coreplug required 30 days of aging. Chalk coreplugs needed 45 days of aging. This shows that coreplugs originating from the same...

  8. A Survey of Hardware and Software Technologies for the Rapid Development of Multimedia Instructional Modules

    Science.gov (United States)

    Ganesan, Nanda

    2008-01-01

    A survey of hardware and software technologies was conducted to identify suitable technologies for the development of instructional modules representing various instructional approaches. The approaches modeled were short PowerPoint presentations, chalk-and-talk type of lectures and software tutorials. The survey focused on identifying application…

  9. Technical Evaluation Report 29: Integrated Learning Management Systems

    Directory of Open Access Journals (Sweden)

    Linda Schwartz

    2004-04-01

    Full Text Available Four integrated learning management packages were reviewed: CentraOne, IntraLearn, Lyceum, and Silicon Chalk. These products provide different combinations of synchronous and asynchronous tools. The current report examines the products in relation to their specific value for distance educators and students.

  10. Diagenetic Quartz Morphologies and Zeolite formation

    DEFF Research Database (Denmark)

    Kazerouni, Afsoon Moatari; Hansen, Rikke Weibel; Friis, Henrik

    The Siri Canyon is a submarine canyon system eroded into the uppermost Chalk deposits and filled in with Palaeogene hemipelagic and turbiditic marls and mudstones interbedded with sandstones deposited from sandy mass-flows and turbidites.  Core samples from 7 wells were studied.  The reservoir sa...

  11. The Impact of Virtual Reality Programs in Career and Technical Education

    Science.gov (United States)

    Catterson, Anna J.

    2013-01-01

    Instructional technology has evolved from blackboards with chalk to in some cases three-dimensional virtual reality environments in which students are interacting and engaging with other students worldwide. The use of this new instructional methodology, known as "virtual reality," has experienced substantial growth in higher education…

  12. Normal and Reversed-Phase Thin Layer Chromatography of Green Leaf Extracts

    Science.gov (United States)

    Sjursnes, Birte Johanne; Kvittingen, Lise; Schmid, Rudolf

    2015-01-01

    Introductory experiments of chromatography are often conducted by separating colored samples, such as inks, dyes, and plant extracts, using filter paper, chalk, or thin layer chromatography (TLC) plates with various solvent systems. Many simple experiments have been reported. The relationship between normal chromatography and reversed-phase…

  13. Access, Consider, Teach: ACT in Your Classroom

    Science.gov (United States)

    Stanford, Pokey; Reeves, Stacy

    2007-01-01

    University teachers who are teacher educators cannot connect to "The Millennial Generation" of today's preservice learners by using chalk and dull outdated textbooks. When university professionals access the technology available, consider the curriculum, and teach with technology (ACT) undergraduate teacher candidates acquire the vision of…

  14. Embedding Digital Pedagogy in Pre-Service Higher Education to Better Prepare Teachers for the Digital Generation

    Science.gov (United States)

    Kivunja, Charles

    2013-01-01

    In preparing pre-service teachers for their professional practice in the information age, we need to impress upon them that the children in their classrooms will be Digital Natives, with skills for digital fluency rather than skills in the orthodoxy 3Rs developed with talk, chalk and board; paper, pencil and pen. Since most of our pre-service…

  15. Tree Coring as a Complement to Soil Gas Screening to Locate PCE and TCE Source Zones and Hot Spots

    DEFF Research Database (Denmark)

    Nielsen, Mette Algreen; Trapp, Stefan; Rehne Jensen, Pernille

    2015-01-01

    ) or trichloroethylene (TCE) to evaluate their ability to locate source zones and contaminant hot spots. One test site represented a relatively homogeneous sandy soil and aquifer, and the second a more heterogeneous geology with both sandy and less permeable clay till layers overlying a chalk aquifer. Tree cores from...

  16. University Students' Conceptions of Bonding in Melting and Dissolving Phenomena

    Science.gov (United States)

    Smith, K. Christopher; Nakhleh, Mary B.

    2011-01-01

    Undergraduate and graduate students' predictions and submicroscopic level explanations for the melting of four materials (salt, chalk, sugar, and butter), and for the mixing of these solutes in two solvents (water and cooking oil) were collected. Twenty-three undergraduate students and seven graduate students participated in the study, and data…

  17. Clicks and Bricks: How School Buildings Influence Future Practice and Technology Adoption

    Science.gov (United States)

    McIntosh, Ewan

    2011-01-01

    Digital land knows no boundaries of space, time or geography. The effect on learning in the past three years, in particular, has been profound, though not necessarily on learning in schools. More have arguably expanded their horizons through 20 minutes of TED Talks than 20 minutes of most chalk and talks or classroom activities.

  18. The Chinese Association For International Understanding(CAFIU) and the cooperation with The Australian Rotary

    Institute of Scientific and Technical Information of China (English)

    Bjrn; Kollberg

    2011-01-01

    Friendship Exchange The origin of our long cooperation dates back to 1987 when CAFIU invited the Liberal Party of Australia to visit China. The then past Tasmanian State President of the Liberal Party Mr. Ian Chalk was one of the first to join the delegation to visit China.

  19. Use of Group Tasks in Teaching English

    OpenAIRE

    Bharti Rathore

    2012-01-01

    In the modern education system, there have been revolutionary changes in education. Technology has changed the overall outlook of schooling. Now teacher is acting as resource person rather than a traditional classroom teacher with chalk and blackboard. Ne Key words: Group task, teaching method, English teaching

  20. Bacteria in ice may record climate change

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    @@ To many people, bacteria and climate change are like chalk and cheese: the srnallest creature versus one of the biggest phenomena on Earth. Not really.Scientists with the CAS Institute of Tibetan Plateau Research (ITP) and coworkers recently reported that small bugs deposited in ice and snow might tell how our climate has been changing.

  1. 75 FR 38980 - Certain Cased Pencils From the People's Republic of China: Final Results of the Antidumping Duty...

    Science.gov (United States)

    2010-07-07

    ...), pastels, charcoals, chalks, and pencils produced under U.S. patent number 6,217,242, from paper infused with scents by the means covered in the above-referenced patent, thereby having odors distinct from... May 28, 2010. \\1\\ ``Pencil Industry in India--A Robust Future,'' Divya Jha, in ``Paper &...

  2. Using Visualisations in Secondary School Physics Teaching and Learning: Evaluating the Efficacy of an Instructional Program to Facilitate Understanding of Gas and Liquid Pressure Concepts

    Science.gov (United States)

    Oh, Elisabeth Yian Yian; Treagust, David F.; Koh, Thiam Seng; Phang, Wei Lian; Ng, Shuh Lit; Sim, Gary; Chandrasegaran, A. L.

    2012-01-01

    An instructional program using four simulation applets was used to facilitate understanding of gas and liquid pressure concepts among twenty-two students in a Year 9 class from an independent secondary school in Singapore. A comparison group consisting of twenty-two students was taught using traditional didactic, chalk-and-talk instruction.…

  3. Palaeoenvironmental changes across the Danian–Selandian boundary in the North Sea Basin

    DEFF Research Database (Denmark)

    Clemmensen, Anne; Thomsen, Erik

    2005-01-01

    and eastern part of the North Sea Basin resulted in a huge influx of reworked Cretaceous chalk and an almost complete stop of carbonate production. Finally, later in the early Selandian, in connection to a general sea-level rise and a reduction in the gateway between the North Sea Basin and the Tethys Sea...

  4. Oil Recovery Enhancement from Fractured, Low Permeability Reservoirs. [Carbonated Water

    Science.gov (United States)

    Poston, S. W.

    1991-01-01

    The results of the investigative efforts for this jointly funded DOE-State of Texas research project achieved during the 1990-1991 year may be summarized as follows: Geological Characterization - Detailed maps of the development and hierarchical nature the fracture system exhibited by Austin Chalk outcrops were prepared. The results of these efforts were directly applied to the development of production decline type curves applicable to a dual-fracture-matrix flow system. Analysis of production records obtained from Austin Chalk operators illustrated the utility of these type curves to determine relative fracture/matrix contributions and extent. Well-log response in Austin Chalk wells has been shown to be a reliable indicator of organic maturity. Shear-wave splitting concepts were used to estimate fracture orientations from Vertical Seismic Profile, VSP data. Several programs were written to facilitate analysis of the data. The results of these efforts indicated fractures could be detected with VSP seismic methods. Development of the EOR Imbibition Process - Laboratory displacement as well as Magnetic Resonance Imaging, MRI and Computed Tomography, CT imaging studies have shown the carbonated water-imbibition displacement process significantly accelerates and increases recovery from oil saturated, low permeability rocks. Field Tests - Two operators amenable to conducting a carbonated water flood test on an Austin Chalk well have been identified. Feasibility studies are presently underway.

  5. 计算机辅助设计

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Mating-models: a key to an efficient, parametric-associative design; Research on an ultrasonic NDT system for complex surface parts; Web-based design and manufacturing systems for automobile components: architectures and usability studies; Conversion of wet-process flue gas desulphurisation plants from quicklime (CaO) to chalk (CaCO{sub}3);

  6. Hydrogeology in Clay Tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian; Klint, Knud Erik; Nilsson, Bertel;

    2012-01-01

    Low-permeability soils such as clayey tills constitute geological boundaries to underlying chalk aquifers that are commonly used as a drinking water resource. Fractures and sand lenses within till sequences represent hydraulic avenues with high hydraulic conductivites limiting the protective func...

  7. Calm, Cool, and Comfortable in Clay

    Science.gov (United States)

    Stylianou, Xanthippi Cynthia

    2010-01-01

    The author's fourth-grade students had just finished a drawing unit that focused on the human figure. Projects included charcoal gesture drawings and chalk manikin drawings in chiaroscuro. She wanted to integrate a new medium for students to continue their study of the human figure. Since students are always excited to work with clay, making clay…

  8. Effects of Full and Quasi-Participatory Learning Strategies on Nigerian Senior Secondary Students' Environmental Knowledge: Implications for Classroom Practice

    Science.gov (United States)

    Ajiboye, Josiah O.; Ajitoni, S. O.

    2008-01-01

    Environmental education is considered an appropriate intervention for creating awareness of, and an understanding of the challenges of environmental degradation. The introduction of EE into the Nigerian school curricular creates a challenge of how to teach it. A majority of the teachers still employ the old, traditional "chalk and talk"…

  9. Modelling of N2O Reduction in a Circulating Fluidized Bed Boiler

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Åmand, Lars Erik; Dam-Johansen, Kim;

    1996-01-01

    The addition of limestone for sulphur retention in Fluidized Bed Combustion (FBC) has been observed to influence the emission of N2O, and in many cases a lower emission was observed. The catalytic activity of a Danish limestone (Stevns Chalk) for decomposition of N2O in a laboratory fixed bed...

  10. Decomposition and Reduction of N2O over Limestone under FBC Conditions

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Jensen, Anker; Vaaben, Rikke;

    1997-01-01

    The addition of limestone for sulfur retention in fluidized bed combustion (FBC) has in many cases been observed to influence the emission of N2O. The catalytic activity of N2O over calcined Stevns Chalk for decomposition of N2O in a laboratory fixed bed quartz reactor was measured. It was found...

  11. Botulism

    Science.gov (United States)

    ... N.Y.: The McGraw-Hill Companies; 2012. http://accessmedicine.com. Accessed May 5, 2015. Goldsmith LA, et ... Y.: The McGraw-Hill Companies; 2012. http://www.accessmedicine.com. Accessed May 11, 2015. Chalk C, et ...

  12. Lower Miocene echinoderms of Jamaica, West Indies

    NARCIS (Netherlands)

    Donovan, S.K.; Portell, R.W.; Veltkamp, C.J.

    2005-01-01

    Despite being diverse globally, Miocene echinoids are poorly known from Jamaica. Moderately diverse echinoids and other echinoderms have been identified mainly from fragmentary specimens collected from chalks and mass-flow deposits of the Lower Miocene Montpelier Formation, White Limestone Group, ne

  13. Facing the challenges of the Eu emissions trading scheme; Relever les defis poses par le marche de quotas de CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Bryers, S. [carbon capital Markets Ltd (United Kingdom)

    2006-10-15

    Carbon Capital Markets, a specialist trader in the EU ETS has helped a number of cement and chalk producers in Europe manage their CO{sub 2} (or EU Allowance (EUA)) position. From its experience with working with these companies, it recommends ways in which manufacturers can manage their CO{sub 2} position more effectively. (author)

  14. Methamphetamine Use and Oral Health

    Science.gov (United States)

    FOR THE DENTAL PATIENT ... Methamphetamine use and oral health M ethamphetamine is an inexpensive, easy-to-make illicit drug. It is known by several street names: “meth,” “speed,” “ice,” “chalk,” “crank,” “fire,” “ ...

  15. In-situ observation of nucleated polymer crystallization in polyoxymethylene sandwich composites

    Directory of Open Access Journals (Sweden)

    Miroslav eSlouf

    2015-03-01

    Full Text Available We introduce a dynamic sandwich method, which can be used for in-situ observation and quantification of polymer crystallization nucleated by micro/nanoparticles. The method was applied on polyoxymethylene (POM composites with three nucleating agents: talc micropowder (POM/mTalc, chalk nanopowder (POM/nChalk and titanate nanotubes (POM/TiNT. The nucleating agents were deposited between polymer films, the resulting sandwich samples were consolidated by thermal treatment, and their microtomed cross-sections were observed during isothermal crystallization by polarized light microscopy. As the intensity of polarized light was shown to be proportional to the relative crystallinity, the PLM results could be fitted to Avrami equation and the nucleating activity of all investigated particles could be quantified by means of Avrami parameters (n, k. The crystallization half-times increased reproducibly in the following order: POM/nChalk < POM/mTalc < POM/TiNT ~ POM. For strong nucleating agents (mTalc, nChalk, the crystallization kinetics corresponded to spontaneous crystallization starting from central nucleating layer, which was verified by computer simulations. The results were also confirmed by DSC. We concluded that the sandwich method is an efficient microscopic technique for detailed evaluation of nucleating activity of arbitrary micro/nanoparticles in polymer systems.

  16. Notes on a drawing of Indian elephants in red crayon by Petrus Camper in the archives of the Rijksmuseum van Natuurlijke Historie

    NARCIS (Netherlands)

    Bruggen, van A.C.; Pieters, F.F.J.M.

    1990-01-01

    A drawing of two Indian elephants, signed "P. Camper f. 10 Sept. 1786", in red chalk or crayon, was found in the archives of the Rijksmuseum van Natuurlijke Historie in a manuscript by T.G. van Lidth de Jeude (1788-1863). Van Lidth de Jeude, professor at Utrecht university, obviously intended to use

  17. Cover Story: Different Strokes

    Science.gov (United States)

    Guhin, Paula

    2009-01-01

    The author and her class used chalk pastels before, in the typical manner with much blending and mixing of color. She felt her high-school class needed to try another technique with no smudging with tissues, no using tortillons (blending stumps), no soft color merging. All too often, young artists blend too many colors together and lose the…

  18. Levels of lead, arsenic, mercury and cadmium in clays for oral use on the Dutch market and estimation of associated risks

    NARCIS (Netherlands)

    Reeuwijk, N.M.; Klerx, W.N.M.; Kooijman, M.; Hoogenboom, L.A.P.; Rietjens, I.M.C.M.; Martena, M.J.

    2013-01-01

    Pregnant women in Africa, Asia and Suriname, and some immigrants in Western societies, traditionally consume clay products known by a variety of names such as mabele, calabash chalk, sikor and pimba. Furthermore, clay is used for health purposes in Western societies. Because certain clays can contai

  19. Brine Distribution after Vacuum Saturation

    DEFF Research Database (Denmark)

    Hedegaard, Kathrine; Andersen, Bertel Lohmann

    1999-01-01

    Experiments with the vacuum saturation method for brine in plugs of chalk showed that a homogeneous distribution of brine cannot be ensured at saturations below 20% volume. Instead of a homogeneous volume distribution the brine becomes concentrated close to the surfaces of the plugs...

  20. Learning through Equity Trading Simulation

    Science.gov (United States)

    Moffit, Timothy; Stull, Charles; McKinney, Hannah

    2010-01-01

    Over the past several decades, colleges and universities have moved away from the traditional chalk-and-talk lecture. Professors have experimented with a myriad of methods to engage students more fully. Some of the innovations that have been used have succeeded in improving student performance and satisfaction. In this paper we report the learning…

  1. Transcriptome, genetic editing, and microRNA divergence substantiate sympatric speciation of blind mole rat, Spalax.

    Science.gov (United States)

    Li, Kexin; Wang, Liuyang; Knisbacher, Binyamin A; Xu, Qinqin; Levanon, Erez Y; Wang, Huihua; Frenkel-Morgenstern, Milana; Tagore, Satabdi; Fang, Xiaodong; Bazak, Lily; Buchumenski, Ilana; Zhao, Yang; Lövy, Matěj; Li, Xiangfeng; Han, Lijuan; Frenkel, Zeev; Beiles, Avigdor; Cao, Yi Bin; Wang, Zhen Long; Nevo, Eviatar

    2016-07-05

    Incipient sympatric speciation in blind mole rat, Spalax galili, in Israel, caused by sharp ecological divergence of abutting chalk-basalt ecologies, has been proposed previously based on mitochondrial and whole-genome nuclear DNA. Here, we present new evidence, including transcriptome, DNA editing, microRNA, and codon usage, substantiating earlier evidence for adaptive divergence in the abutting chalk and basalt populations. Genetic divergence, based on the previous and new evidence, is ongoing despite restricted gene flow between the two populations. The principal component analysis, neighbor-joining tree, and genetic structure analysis of the transcriptome clearly show the clustered divergent two mole rat populations. Gene-expression level analysis indicates that the population transcriptome divergence is displayed not only by soil divergence but also by sex. Gene ontology enrichment of the differentially expressed genes from the two abutting soil populations highlights reproductive isolation. Alternative splicing variation of the two abutting soil populations displays two distinct splicing patterns. L-shaped FST distribution indicates that the two populations have undergone divergence with gene flow. Transcriptome divergent genes highlight neurogenetics and nutrition characterizing the chalk population, and energetics, metabolism, musculature, and sensory perception characterizing the abutting basalt population. Remarkably, microRNAs also display divergence between the two populations. The GC content is significantly higher in chalk than in basalt, and stress-response genes mostly prefer nonoptimal codons. The multiple lines of evidence of ecological-genomic and genetic divergence highlight that natural selection overrules the gene flow between the two abutting populations, substantiating the sharp ecological chalk-basalt divergence driving sympatric speciation.

  2. Potentiometric Surface of the Magothy Aquifer in Southern Maryland, September 2002

    Science.gov (United States)

    Curtin, Stephen E.; Andreasen, David C.; Wheeler, Judith C.

    2003-01-01

    This report presents a map showing the potentiometric surface of the Magothy aquifer in the Magothy Formation of Upper Cretaceous age in Southern Maryland during September 2002. The map is based on water-level measurements in 79 wells. The highest measured water level was 83 feet above sea level near the northern boundary and outcrop area of the aquifer in the north-central part of Anne Arundel County. The potentiometric surface declined towards the south and east. Local gradients were directed toward the centers of two cones of depression that developed in response to pumping. These cones of depression were centered around well fields in the Waldorf area and at the Chalk Point power plant. Measured ground-water levels were as low as 81 feet below sea level in the Waldorf area and 75 feet below sea level at Chalk Point.

  3. Potentiometric surface map of the Magothy aquifer in southern Maryland, September, 2003

    Science.gov (United States)

    Curtin, Stephen E.; Andreasen, David C.; Wheeler, Judith C.

    2005-01-01

    This report presents a map showing the potentiometric surface of the Magothy aquifer in the Magothy Formation of Upper Cretaceous age in Southern Maryland during September 2002. The map is based on water-level measurements in 79 wells. The highest measured water level was 83 feet above sea level near the northern boundary and outcrop area of the aquifer in the north-central part of Anne Arundel County. The potentiometric surface declined towards the south and east. Local gradients were directed toward the centers of two cones of depression that developed in response to pumping. These cones of depression were centered around well fields in the Waldorf area and at the Chalk Point power plant. Measured ground-water levels were as low as 81 feet below sea level in the Waldorf area and 75 feet below sea level at Chalk Point.

  4. A rigorous method for quantifying recharge using simple and complex models

    Science.gov (United States)

    Ireson, A. M.; Butler, A. P.

    2012-04-01

    One of the fundamental challenges for quantifying the timing and magnitude of groundwater recharge is that there remains no direct, non-destructive method for measuring this flux. As a result, recharge is indirectly inferred, requiring a conceptual model (that is a set of assumptions about the system processes), a mathematical model (providing quantitative estimates) and some indirect observations. For physical approaches, observations will typically include rainfall, potential evaporation and either soil/unsaturated moisture status, or water table fluctuations. Some limitations with conventional modelling approaches include: inadequate representation of the deep unsaturated zone; inadequate representation of unsaturated zone-saturated zone interactions (for example, changing unsaturated zone thickness in areas where water table fluctuations are significant); inadequate representation of lateral flows within the saturated zone which influence water table fluctuations (an example being the erroneous assumption that a sustained failing water table is indicative of an absence of recharge). In groundwater models, errors in recharge estimates may be masked by calibration of the saturated zone parameters (specific yield and hydraulic conductivity). Validation of the modelled recharge is therefore not rigorous. This paper presents a detailed physically based model for unsaturated-saturated zone flow processes applied to a dual permeability Chalk hillslope transect. This is a fairly well constrained natural field site in a highly studied catchment. The Chalk is a complex fractured porous medium. A detailed model based on Richards' equation explicitly simulates the (observable) water table response to recharge, with none of the limitations listed above. This model is able to reproduce observed field behaviour. This provides us with a benchmark with which to test conventional recharge models in a more rigorous manner than has been done previously. In particular we focus on

  5. Cooper Lake and Channels, Texas.

    Science.gov (United States)

    1977-04-01

    Chalk :. 0 Lower IM Ozan Gober Tongue 5 ~~Aus tin - P I !!rewns town Marl , Austin Chalk f • I Blossom Sand I I ’I I Bonham Marl Tokio Sand -ctor...0.80 5.4 0.45 Carp 11 0.80 17.4 1.44 Golden s~iiner 9 0.65 1.6 0.13 Channel catfish 31 2.25 36.8 3.04 Blue catfish 2 0.15 1.4 0.12 Black bullhead 57...in the basin but also nests there. Other waterfowl which winter in the area include the northern pintail, green-winged teal, cinnamon teal, blue

  6. Novel Application of the Flotation Technique To Measure the Wettability Changes by Ionically Modified Water for Improved Oil Recovery in Carbonates

    DEFF Research Database (Denmark)

    Sohal, Muhammad Adeel Nassar; Thyne, Geoffrey; Søgaard, Erik Gydesen

    2016-01-01

    imbibition tests take months, and chromatographic separation is feasible only for core flooding in sulfate free carbonates at low temperature. A novel application of the well-established technique known as flotation was used in this study to measure the oil-wet and water-wet percent of pure biogenic chalk (Dan...... Chalk from Denmark). It is an accurate, fast, and most reliable method to quantitatively measure the water-wet and oil-wet fractions of a reservoir rock. It determines the potential of advanced water to improve wettability within days, instead of measurements that can take months and require expensive...... alteration and the amount of oil attached to the water-wet percent of rock was also determined....

  7. Transformation of Heavy Metal Compounds during the Remediation of Contaminated Soils

    Directory of Open Access Journals (Sweden)

    Tatiana Minkina

    2011-03-01

    Full Text Available The effect of ameliorants, chalk, glauconite and semidecomposed cattle manure, on ordinary chernozem contaminated with Zn and Pb was studied in a long-term field experiment. The application of ameliorants significantly decreased the mobility of metals. Their effect depended on the ameliorant and was most significant at the simultaneous application of chalk and manure. This effect was presumably due to the strong binding of metals by carbonates through chemisorption and formation of lowsoluble Zn and Pb compounds and to the additional fixation in the form of complexes at the addition of organic material. The share of loosely bound metal compounds in the contaminated soils decreased to the level typical for the clean soils or even below. The general evolution of the transformation of metal compounds (from less to more firmly bound compounds accelerated by ameliorants remained for both metals.

  8. Automated extraction of faults and porous reservoir bodies. Examples from the Vallhall Field

    Energy Technology Data Exchange (ETDEWEB)

    Barkved, Olav Inge; Whitman, Doug; Kunz, Tim

    1998-12-31

    The Norwegian Vahall field is located 250 km South-West of Stavanger. The production is primarily from the highly porous and fractured chalk, the Tor formation. Fractures, evidently play a significant role in enhancing flow properties as well as production rates, are significantly higher than expected from matrix permeability alone. The fractures are primarily tectonically induced and related to faulting. Syn-depositional faulting is believed to be a controlling factor on reservoir thickness variations observed across the field. Due to the low acoustic contrast and weak appearance of the highly porous chalk, direct evidence of faulting in well bore logs is limited. The seismic data quality in the most central area of the field is very poor due to tertiary gas charging, but in the flank area of the field, the quality is excellent. 1 ref., 5 figs.

  9. Particle diffusion in complex nanoscale pore networks

    DEFF Research Database (Denmark)

    Müter, Dirk; Sørensen, Henning Osholm; Bock, H.

    2015-01-01

    We studied the diffusion of particles in the highly irregular pore networks of chalk, a very fine-grained rock, by combining three-dimensional X-ray imaging and dissipative particle dynamics (DPD) simulations. X-ray imaging data were collected at 25 nm voxel dimension for two chalk samples...... with very different porosities (4% and 26%). The three-dimensional pore systems derived from the tomograms were imported into DPD simulations and filled with spherical particles of variable diameter and with an optional attractive interaction to the pore surfaces. We found that diffusion significantly...... decreased to as much as 60% when particle size increased from 1% to 35% of the average pore diameter. When particles were attracted to the pore surfaces, even very small particles, diffusion was drastically inhibited, by as much as a factor of 100. Thus, the size of particles and their interaction...

  10. Sedimentologic and tectonic evolution of the Upper Cretaceous-Lower Tertiary succession at Wadi Qena, Egypt

    Science.gov (United States)

    Soliman, Mohamed A.; Habib, Mohamed E.; Ahmed, Ezzat A.

    1986-01-01

    The Upper Cretaceous-Lower Tertiary rocks around Wadi Qena, Egypt, represent a mixed siliciclastic-carbonate-phosphorite succession including (from base to top) the Nubia Sandstone, Quseir Shale, Duwi Formation, Dakhla Shale, Tarawan Chalk, Esna Shale and Thebes Formation. Facies and microfacies investigations were carried out. The Nubia Sandstone was deposited by a fluviatile system, whereas the Quseir Shale was laid down by deltaic sedimentation. The Dakhla Shale, Esna Shale and Tarawan Chalk were formed in open marine (pelagic) realms. The Thebes Formation is a shallowing carbonate facies. Phosphorites were accumulated as lag deposits by reworking and winnowing of pre-existing phosphatic materials. The sedimentation of the Upper Cretaceous-Lower Tertiary rocks were affected by regional and local tectonics (i.e., faulting). The latter played a substantial role in the distribution of the different facies particularly the siliciclastic-carbonate facies.

  11. Modeling of the pressure propagation due to CO2 injection and the effect of fault permeability in a case study of the Vedsted structure, Northern Denmark

    DEFF Research Database (Denmark)

    Mbia, Ernest Ncha; Frykman, Peter; Nielsen, Carsten M.;

    2014-01-01

    of the structure shows the presence of northwest-southeast trending faults of which some originate in the upper layer of the Gassum reservoir and some reach the base Chalk Group layer. Two faults in the upper Gassum reservoir have been interpreted to be connected to the base Chalk Group. In order to evaluate...... potential risks associated with vertical pressure transmission via the faults through the caprock, a number of simulation cases have been run with various fault permeabilities spanning orders of magnitude to represent both the worst and best case scenarios. Fault rock permeability data were obtained from...... a literature study and range from 1000mD (maximum value reported from sedimentary rock environment) for the worst case scenario down to 0.001mD (sealing faults in sedimentary rock environment) for the best case scenario. The results show that after injecting 60 million tons (Mt) of CO2 at a rate of 1.5Mt...

  12. Installation of the Canadian Muon Cargo Inspection System at CRL

    Science.gov (United States)

    2014-04-01

    Installation of the Canadian Muon Cargo Inspection System at CRL Prepared by: Guy Jonkmans Atomic Energy of Canada Limited Chalk River ON...INSTALLATION OF THE CANADIAN MUON CARGO INSPECTION SYSTEM AT CRL 153-30100-REPT-001 Revision 0 2013/02/19 UNRESTRICTED 2013/02/19 ILLIMITÉ 153...30100-REPT-001 2013/02/19 Report, General Installation of the Canadian Muon Cargo Inspection System at CRL Research and Development 153-30100

  13. Isotope shortage triggers delays for patients

    Science.gov (United States)

    Gould, Paula

    2009-07-01

    An unplanned shutdown of a nuclear reactor in Canada is disrupting the supply of medical isotopes across North America and forcing some hospitals to cancel or postpone patients' tests. The closure of the National Research Universal (NRU) reactor in Chalk River, Ontario, has also embarrassed Canadian officials, including a senior government minister who was forced to apologize after calling the isotope shortage a "sexy" career challenge.

  14. Environmental Assessment: Construction Projects at the 189th Airlift Wing, Arkansas Air National Guard

    Science.gov (United States)

    2003-09-12

    bellied Woodpecker (Melanerpes carolinus), Downy Woodpecker (Picoides pudescens), Blue Jay (Cyanocitta cristata), Carolina Chickadee (Parus...were the Eastern Towhee (Pipilo erythrophthalmus), Carolina Wren, and Blue Jay. Twenty-four species were recorded in grassland habitats on Little...WILCOX GROUP MIDWAY GROUP ANNONA CHALK OZAN FORli.ATION BROWNSTOWN KARL TOKIO FORMATION WOODBINE FORMA’rlON KIAMICHI F’ORMATJON AND GOODLAND

  15. Proceedings of the fifth international conference on CANDU fuel. V.1,2

    Energy Technology Data Exchange (ETDEWEB)

    Lau, J.H. [ed.

    1997-07-01

    The First International Conference on CANDU Fuel was held in Chalk River in 1986. The CANDU Fuel community has gathered every three years since. The papers presented include topics on international experience, CANFLEX fuel bundles, Fuel design, Fuel modelling, Manufacturing and Quality assurance, Fuel performance and Safety, Fuel cycles and Spent Fuel management. Volume One was published in advance of the conference and Volume Two was printed after the conference.

  16. Pesticide sorption by low organic carbon sediments: A sceening for seven herbicides

    DEFF Research Database (Denmark)

    Madsen, Lene; Lindhardt, Bo; Rosenberg, Per;

    2000-01-01

    The sorption of seven pesticides in 10 Danish aquifer sediments has been studied. These sediments all have a total organic carbon (TOC) content below 1 g kg(-1), and include carbonate-bearing and carbonate-free Quatenary sand deposits and a Cretaceous chalk aquifer. Batch experiments were carried...... by the specific surface area (SSA) and TOC. The present results illustrate the importance of choosing sediments of different geological origin in order to describe the influence of sediment properties on pesticide sorption....

  17. Automated Controlled-Potential Coulometric Determination of Uranium (Determination de l’Uranium par Coulometre Automatise a Potentiel Controle),

    Science.gov (United States)

    1982-06-01

    CPC) is an analytical technique commonly used in the nuclear industry for determination of electroactive metals (1). At Chalk River Nuclear...removed from the samples (by fuming), it can be tolerated in concentrations up to 5 M as long as sufficient sulphamic acid is added to destroy any...used and the mercury used in the coulometer cell was triple-distilled grade. Saturated sulphamic acid was prepared by the dissolution of =15 g of

  18. ‘Good Building’: Bertolt Brecht’s Utopian Historical Optimism at the End of World War II

    OpenAIRE

    Gerhard Fischer

    2011-01-01

    The article focuses on the works of Bertolt Brecht which depicts his insights regarding the reconstruction of Germany. Such works include the story "The City Builder" and the plays "Caucasian Chalk Circle" and "The Days of the Commune." It discusses his principles of what he considers as good building as well as the three criteria addressed in good building which include size, time, and beauty.

  19. CTC Sentinel. Volume 6, Issue 11-12, November 2013

    Science.gov (United States)

    2013-11-01

    Jami Forbes and Brian Dudley 15 The Bangsamoro Islamic Freedom Fighters: The Newest Obstacles to Peace in the Southern Philippines ? By peter...August 15, 2013. 20 See, for example, Bruce Hoffman’s quote: “They want to carve out a jihadi state or a jihadi territory and obvi- ously anything...Bangsamoro Islamic Freedom Fighters: The Newest Obstacles to Peace in the Southern Philippines ? By peter Chalk in september 2013, approximately 150

  20. Sympatric speciation revealed by genome-wide divergence in the blind mole rat Spalax.

    Science.gov (United States)

    Li, Kexin; Hong, Wei; Jiao, Hengwu; Wang, Guo-Dong; Rodriguez, Karl A; Buffenstein, Rochelle; Zhao, Yang; Nevo, Eviatar; Zhao, Huabin

    2015-09-22

    Sympatric speciation (SS), i.e., speciation within a freely breeding population or in contiguous populations, was first proposed by Darwin [Darwin C (1859) On the Origins of Species by Means of Natural Selection] and is still controversial despite theoretical support [Gavrilets S (2004) Fitness Landscapes and the Origin of Species (MPB-41)] and mounting empirical evidence. Speciation of subterranean mammals generally, including the genus Spalax, was considered hitherto allopatric, whereby new species arise primarily through geographic isolation. Here we show in Spalax a case of genome-wide divergence analysis in mammals, demonstrating that SS in continuous populations, with gene flow, encompasses multiple widespread genomic adaptive complexes, associated with the sharply divergent ecologies. The two abutting soil populations of S. galili in northern Israel habituate the ancestral Senonian chalk population and abutting derivative Plio-Pleistocene basalt population. Population divergence originated ∼0.2-0.4 Mya based on both nuclear and mitochondrial genome analyses. Population structure analysis displayed two distinctly divergent clusters of chalk and basalt populations. Natural selection has acted on 300+ genes across the genome, diverging Spalax chalk and basalt soil populations. Gene ontology enrichment analysis highlights strong but differential soil population adaptive complexes: in basalt, sensory perception, musculature, metabolism, and energetics, and in chalk, nutrition and neurogenetics are outstanding. Population differentiation of chemoreceptor genes suggests intersoil population's mate and habitat choice substantiating SS. Importantly, distinctions in protein degradation may also contribute to SS. Natural selection and natural genetic engineering [Shapiro JA (2011) Evolution: A View From the 21st Century] overrule gene flow, evolving divergent ecological adaptive complexes. Sharp ecological divergences abound in nature; therefore, SS appears to be an

  1. What Should Be Classified? A Framework with Application to the Global Force Management Data Initiative

    Science.gov (United States)

    2010-01-01

    did so at the request of the Joint Staff to determine whether and to what extent the information that the ini- 6 In Gary Klein , Sources of Power: How...Parachini, William Rosenau, Erin M. Simpson, Melanie Sisson, and Donald Temple, Breaching the Fortress Wall: Understanding Terrorist Efforts to Overcome...briefing, May 30, 2008. Jackson, Brian A., Peter Chalk, R. Kim Cragin, Bruce Newsome, John V. Parachini, William Rosenau, Erin M. Simpson, Melanie Sisson

  2. Perception and preferences of teaching and learning methods among second year medical students: a cross sectional survey in a rural tertiary care teaching hospital

    Directory of Open Access Journals (Sweden)

    Manu G

    2016-06-01

    Conclusions: Chalk and board teaching remains the best preferred teaching aid which can be supplemented with PPT and OHP to improve medical teaching. Small group discussion is the most preferred learning method when compared with tutorial, student's seminar and lectures indicating that students are more interested in active teaching and learning methods. [Int J Basic Clin Pharmacol 2016; 5(3.000: 1006-1010

  3. ‘Good Building’: Bertolt Brecht’s Utopian Historical Optimism at the End of World War II

    Directory of Open Access Journals (Sweden)

    Gerhard Fischer

    2011-04-01

    Full Text Available The article focuses on the works of Bertolt Brecht which depicts his insights regarding the reconstruction of Germany. Such works include the story "The City Builder" and the plays "Caucasian Chalk Circle" and "The Days of the Commune." It discusses his principles of what he considers as good building as well as the three criteria addressed in good building which include size, time, and beauty.

  4. Stealing the Sword: Limiting Terrorist Use of Advanced Conventional Weapons

    Science.gov (United States)

    2007-01-01

    sniper rifles and their accessories and advanced ammunition. For those weapons, only awareness and the precautions taken by security forces can...Qa’idat AI-Jihad fi Bilad al-Rafidayn Revolutionary Armed Forces of Colombia (FARC) al-Fatah Moro Islamic Liberation Front (MILF) Liberation Tigers of...a small terrorist cell that had to raise operational funds on its own. 14 For additional discussion of counterstrategies, see Jackson, Chalk, et al

  5. Properties of rotational bands at the spin limit in A {approximately} 50, A {approximately} 65 and A {approximately} 110 nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Janzen, V.P.; Andrews, H.R.; Ball, G.C. [Chalk River Labs., Ontario (Canada)] [and others

    1996-12-31

    There is now widespread evidence for the smooth termination of rotational bands in A {approx_equal} 110 nuclei at spins of 40-to-50{Dirac_h}s. The characteristics of these bands are compared to those of bands recently observed to high spin in {sup 64}Zn and {sup 48}Cr, studied with the 8{pi} {gamma}-ray spectrometer coupled to the Chalk River miniball charged-particle-detector array.

  6. An Ever Present Danger: A Concise History of British Military Operations on the North-West Frontier, 1849-1947 (Occasional Paper, Number 33)

    Science.gov (United States)

    2010-06-01

    against their villages and, as the official order stated; “Bomb any persons and livestock seen in those areas.”16 With an eye toward ultimate conciliation...promptly by destroy- ing villages, crops and livestock , and killing the fighters and scattering the traditional Pashtun fighting forces which were...Tank Zam 3264 3584 Nai Kach Shekhzt Mandanna Hill Broken Hill Pink Bowl Chalk Hill Black Hill Sagarzai Mandanna Kach Spinkai Ghash PALOSINA Kotkai 0

  7. A self-portrait of young Leonardo

    CERN Document Server

    Sparavigna, Amelia Carolina

    2011-01-01

    One of the most famous drawings by Leonardo da Vinci is a self-portrait in red chalk, where he looks quite old. In fact, there is a sketch in one of his notebooks, partially covered by written notes, that can be a self-portrait of the artist when he was young. The use of image processing, to remove the handwritten text and improve the image, allows a comparison of the two portraits.

  8. 可擦性无尘笔用水性白墨水

    Institute of Scientific and Technical Information of China (English)

    陈登龙; 郑昌辉

    2003-01-01

    Chalk is the ordinary cheap writing material. The dust it produces in using does a great harm to teachers and students. The dust pollutes the environment. To solve the problem, an erasable dust-free pen ink has been invented. It has a wide choice of colour. The ink is consist of an organic solvent and some other dyestuffs. The ink enables users to keep away from pollution.

  9. Oil recovery enhancement from fractured, low permeability reservoirs. Annual report 1990--1991, Part 1

    Energy Technology Data Exchange (ETDEWEB)

    Poston, S.W.

    1991-12-31

    Joint funding by the Department of Energy and the State of Texas has Permitted a three year, multi-disciplinary investigation to enhance oil recovery from a dual porosity, fractured, low matrix permeability oil reservoir to be initiated. The Austin Chalk producing horizon trending thru the median of Texas has been identified as the candidate for analysis. Ultimate primary recovery of oil from the Austin Chalk is very low because of two major technological problems. The commercial oil producing rate is based on the wellbore encountering a significant number of natural fractures. The prediction of the location and frequency of natural fractures at any particular region in the subsurface is problematical at this time, unless extensive and expensive seismic work is conducted. A major portion of the oil remains in the low permeability matrix blocks after depletion because there are no methods currently available to the industry to mobilize this bypassed oil. The following multi-faceted study is aimed to develop new methods to increase oil and gas recovery from the Austin Chalk producing trend. These methods may involve new geological and geophysical interpretation methods, improved ways to study production decline curves or the application of a new enhanced oil recovery technique. The efforts for the second year may be summarized as one of coalescing the initial concepts developed during the initial phase to more in depth analyses. Accomplishments are predicting natural fractures; relating recovery to well-log signatures; development of the EOR imbibition process; mathematical modeling; and field test.

  10. Mechanical stratigraphic controls on natural fracture spacing and penetration

    Science.gov (United States)

    McGinnis, Ronald N.; Ferrill, David A.; Morris, Alan P.; Smart, Kevin J.; Lehrmann, Daniel

    2017-02-01

    Fine-grained low permeability sedimentary rocks, such as shale and mudrock, have drawn attention as unconventional hydrocarbon reservoirs. Fracturing - both natural and induced - is extremely important for increasing permeability in otherwise low-permeability rock. We analyze natural extension fracture networks within a complete measured outcrop section of the Ernst Member of the Boquillas Formation in Big Bend National Park, west Texas. Results of bed-center, dip-parallel scanline surveys demonstrate nearly identical fracture strikes and slight variation in dip between mudrock, chalk, and limestone beds. Fracture spacing tends to increase proportional to bed thickness in limestone and chalk beds; however, dramatic differences in fracture spacing are observed in mudrock. A direct relationship is observed between fracture spacing/thickness ratio and rock competence. Vertical fracture penetrations measured from the middle of chalk and limestone beds generally extend to and often beyond bed boundaries into the vertically adjacent mudrock beds. In contrast, fractures in the mudrock beds rarely penetrate beyond the bed boundaries into the adjacent carbonate beds. Consequently, natural bed-perpendicular fracture connectivity through the mechanically layered sequence generally is poor. Fracture connectivity strongly influences permeability architecture, and fracture prediction should consider thin bed-scale control on fracture heights and the strong lithologic control on fracture spacing.

  11. Enhanced Oil Recovery from Oil-wet Carbonate Rock by Spontaneous Imbibition of Aqueous Surfactant Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Standnes, Dag Chun

    2001-09-01

    The main theme of this thesis is an experimental investigation of spontaneous imbibition (SI) of aqueous cationic surfactant solution into oil-wet carbonate (chalk- and dolomite cores). The static imbibition process is believed to represent the matrix flow of oil and water in a fractured reservoir. It was known that aqueous solution of C{sub 12}-N(CH{sub 3}){sub 3}Br (C12TAB) was able to imbibe spontaneously into nearly oil-wet chalk material, but the underlying mechanism was not understood. The present work was therefore initiated, with the following objectives: (1) Put forward a hypothesis for the chemical mechanism underlying the SI of C12TAB solutions into oil-wet chalk material based on experimental data and (2) Perform screening tests of low-cost commercially available surfactants for their ability to displace oil by SI of water into oil-wet carbonate rock material. It is essential for optimal use of the surfactant in field application to have detailed knowledge about the mechanism underlying the SI process. The thesis also discusses some preliminary experimental results and suggests mechanisms for enhanced oil recovery from oil-wet carbonate rock induced by supply of thermal energy.

  12. Soil treatment to remove uranium and related mixed radioactive contaminants. Final report September 1992--October 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    A research and development project to remove uranium and related radioactive contaminants from soil by an ultrasonically-aided chemical leaching process began in 1993. The project objective was to develop and design, on the basis of bench-scale and pilot-scale experimental studies, a cost-effective soil decontamination process to produce a treated soil containing less than 35 pCi/g. The project, to cover a period of about thirty months, was designed to include bench-scale and pilot-scale studies to remove primarily uranium from the Incinerator Area soil, at Fernald, Ohio, as well as strontium-90, cobalt-60 and cesium-137 from a Chalk River soil, at the Chalk River Laboratories, Ontario. The project goal was to develop, design and cost estimate, on the basis of bench-scale and pilot-scale ex-situ soil treatment studies, a process to remove radionuclides form the soils to a residual level of 35 pCi/g of soil or less, and to provide a dischargeable water effluent as a result of soil leaching and a concentrate that can be recovered for reuse or solidified as a waste for disposal. In addition, a supplementary goal was to test the effectiveness of in-situ soil treatment through a field study using the Chalk River soil.

  13. Cliff stability assessment using electrical resistivity tomography at the historic WWII D-Day invasion site, Pointe du Hoc, France

    Science.gov (United States)

    Everett, M. E.; Udphuay, S.; Warden, R.

    2007-05-01

    The 1944 D-Day invasion site at Pointe du Hoc, Normandy, France is an important WWII battlefield and cultural resource but is at risk from chalk cliff collapse. The American Battle Monuments Commission tasked us to evaluate the geohazard to the observation post and other cliff-side buildings of historical significance. Geophysical multi-electrode resistivity profiling is used to study cliff stability and the condition of the observation- post foundations. Preliminary 2-D geological interpretations are provided of individual profiles. The copious steel, concrete and void spaces at the site renders hydrogeological interpretation challenging but tractable. The cliff face appears to be relatively intact and well-drained. Several routes taken by groundwater into fractures within the chalk were identified mainly on the western side of the site. The eastern side is drier and somewhat sheltered from the Atlantic storms but may contain large void spaces that could efficiently transmit groundwater flow during heavy precipitation events, thereby imperiling the major antiaircraft gun emplacement occupied by Col. Rudder in the early days of the Allied invasion. The forward German observation post perched close to the sea stack, which now hosts the U.S. Ranger memorial, may be moving with the soil and not securely anchored to bedrock. A complex failure mechanism is identified as a combination of groundwater dissolution of the fractured chalk and sea wave attack at the cliff base.

  14. Relationship between hand-skill exercises and other admissions criteria and students' performance in dental school.

    Science.gov (United States)

    Ballard, Richard W; Hagan, Joseph L; Cheramie, Toby

    2015-05-01

    The aim of this study was to investigate the existence of correlations between dental admissions criteria, including a chalk carving exercise, and students' subsequent academic performance. The retrospective cohort study examined the records of dental students at Louisiana State University Health Science Center School of Dentistry for the years 1998 to 2008. Only those students who could be categorized into the following four groups were included: 1) those who graduated in the top 10% of their class, 2) those who graduated in the bottom 10% of their class, 3) those who repeated a year of dental school, and 4) those who were dismissed or resigned. The study sample consisted of 176 students: 62 in the first group, 62 in the second group, 25 in the third group, and 27 in the fourth group. Data collected were each student's undergraduate grade point average (GPA); chalk carving score; undergraduate biology, chemistry, physics (BCP) GPA; Dental Admission Test (DAT) Academic Average; Perceptual Ability Test (PAT) score of the DAT; total DAT score; grade in preclinical operative dentistry class; grade in morphology and occlusion class; and dental school GPA at graduation. The results showed that only the undergraduate GPA and BCP GPA were significantly higher for students in the top 10% of their class than for other groups. The only positive correlation involving the chalk carving scores was with the preclinical operative dentistry course grade. This study thus found limited correlations between this institution's admissions criteria and its students' success in dental school.

  15. Some aspects of nanomodification of mineral dispersions by oligomers based on trifunctional oxyphenyl

    Directory of Open Access Journals (Sweden)

    : Shapovalov Nikolay Afanasyevich

    2016-12-01

    Full Text Available te size of the dispersion phase and other colloid-chemical characteristics of suspensions used in the building industry are determined by the peculiarities of the boundary layer structure. The authors have identified the adsorption parameters of resole oligomers synthesized on the base of trifunctionl oxyphenyls on the following adsorbents: CaCO3, ZnO. The most potential adsorption pattern of phloroglucinefurfural nanomodificator molecules on the surface of chalk particles have been suggested in the work. It has been stated that the molecules of oxyphenyl oligomers are adsorbed on the surface of disperse material particles forming monomolecular layer. The adsorption on the particles surface is provided by the ionic interaction of negative oxy groups of the phloroglicine unit or resocine with positively charged active centers of dispersion phase surface and dispersion forces of interaction between the system of oligomer aromatic rings and particles surface. It has been proved that the injection of optimal dose of phloroglucinefurfural nanomodificator into the chalk and zink oxide suspensions decreases the number average radius of nanomodified particles to the size of initial particles of the dispersions under study – from 7 to 1 mcm for chalk and from 5 mcm to 50 nm for zink oxide. It demonstrates the peptizing effect of the nanomodificator.

  16. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2001-07-01

    Mechanically weak formations, such as chalks, high porosity sandstones, and marine sediments, pose significant problems for oil and gas operators. Problems such as compaction, subsidence, and loss of permeability can affect reservoir production operations. For example, the unexpected subsidence of the Ekofisk chalk in the North Sea required over one billion dollars to re-engineer production facilities to account for losses created during that compaction (Sulak 1991). Another problem in weak formations is that of shallow water flows (SWF). Deep water drilling operations sometimes encounter cases where the marine sediments, at shallow depths just below the seafloor, begin to uncontrollably flow up and around the drill pipe. SWF problems created a loss of $150 million for the Ursa development project in the U.S. Gulf Coast SWF (Furlow 1998a,b; 1999a,b). The goal of this project is to provide a database on both the rock mechanical properties and the geophysical properties of weak rocks and sediments. These could be used by oil and gas companies to detect, evaluate, and alleviate potential production and drilling problems. The results will be useful in, for example, pre-drill detection of events such as SWF's by allowing a correlation of seismic data (such as hazard surveys) to rock mechanical properties. The data sets could also be useful for 4-D monitoring of the compaction and subsidence of an existing reservoir and imaging the zones of damage. During the second quarter of the project the research team has: (1) completed acoustic sensor construction, (2) conducted reconnaissance tests to map the deformational behaviors of the various rocks, (3) developed a sample assembly for the measurement of dynamic elastic and poroelastic parameters during triaxial testing, and (4) conducted a detailed review of the scientific literature and compiled a bibliography of that review. During the first quarter of the project the research team acquired several rock types for

  17. Groundwater and surface-water interaction and potential for underground water storage in the Buena Vista-Salida Basin, Chaffee County, Colorado, 2011

    Science.gov (United States)

    Watts, Kenneth R.; Ivahnenko, Tamara I.; Stogner, Robert W.; Bruce, James F.

    2014-01-01

    By 2030, the population of the Arkansas Headwaters Region, which includes all of Chaffee and Lake Counties and parts of Custer, Fremont, and Park Counties, Colorado, is forecast to increase about 73 percent. As the region’s population increases, it is anticipated that groundwater will be used to meet much of the increased demand. In September 2009, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District and with support from the Colorado Water Conservation Board; Chaffee, Custer, and Fremont Counties; Buena Vista, Cañon City, Poncha Springs, and Salida; and Round Mountain Water and Sanitation District, began a 3-year study of groundwater and surface-water conditions in the Buena Vista-Salida Basin. This report presents results from the study of the Buena Vista-Salida Basin including synoptic gain-loss measurements and water budgets of Cottonwood, Chalk, and Browns Creeks, changes in groundwater storage, estimates of specific yield, transmissivity and hydraulic conductivity from aquifer tests and slug tests, an evaluation of areas with potential for underground water storage, and estimates of stream-accretion response-time factors for hypothetical recharge and selected streams in the basin. The four synoptic measurements of flow of Cottonwood, Chalk, and Browns Creeks, suggest quantifiable groundwater gains and losses in selected segments in all three perennial streams. The synoptic measurements of flow of Cottonwood and Browns Creeks suggest a seasonal variability, where positive later-irrigation season values in these creeks suggest groundwater discharge, possibly as infiltrated irrigation water. The overall sum of gains and losses on Chalk Creek does not indicate a seasonal variability but indicates a gaining stream in April and August/September. Gains and losses in the measured upper segments of Chalk Creek likely are affected by the Chalk Cliffs Rearing Unit (fish hatchery). Monthly water budgets were estimated for

  18. Quantifying Preferential Flow and Seasonal Storage in an Unsaturated Fracture-Facial Domain

    Science.gov (United States)

    Nimmo, J. R.; Malek-Mohammadi, S.

    2012-12-01

    Preferential flow through deep unsaturated zones of fractured rock is hydrologically important to a variety of contaminant transport and water-resource issues. The unsaturated zone of the English Chalk Aquifer provides an important opportunity for a case study of unsaturated preferential flow in isolation from other flow modes. The chalk matrix has low hydraulic conductivity and stays saturated, owing to its fine uniform pores and the wet climate of the region. Therefore the substantial fluxes observed in the unsaturated chalk must be within fractures and interact minimally with matrix material. Price et al. [2000] showed that irregularities on fracture surfaces provide a significant storage capacity in the chalk unsaturated zone, likely accounting for volumes of water required to explain unexpected dry-season water-table stability during substantial continuing streamflow observed by Lewis et al. [1993] In this presentation we discuss and quantify the dynamics of replenishment and drainage of this unsaturated zone fracture-face storage domain using a modification of the source-responsive model of Nimmo [2010]. This model explains the processes in terms of two interacting flow regimes: a film or rivulet preferential flow regime on rough fracture faces, active on an individual-storm timescale, and a regime of adsorptive and surface-tension influences, resembling traditional diffuse formulations of unsaturated flow, effective mainly on a seasonal timescale. The modified model identifies hydraulic parameters for an unsaturated fracture-facial domain lining the fractures. Besides helping to quantify the unsaturated zone storage described by Price et al., these results highlight the importance of research on the topic of unsaturated-flow relations within a near-fracture-surface domain. This model can also facilitate understanding of mechanisms for reinitiation of preferential flow after temporary cessation, which is important in multi-year preferential flow through deep

  19. CT gas lift captures last of field reserves

    Energy Technology Data Exchange (ETDEWEB)

    Tran, T.B.; Miller, J.; Woodell, M.E.; Johnson, H.

    1996-06-01

    Texaco Exploration and Production Inc.`s (TEPI) Brookeland Field in Newton County, Texas, produces from 30, mostly dual-horizontal, wells in the Austin Chalk reservoir. The wells are typically drilled vertically and casing is set to the top of the Austin Chalk at about 10,000 ft. Building at 15{degree}/100 ft, 4,000-ft laterals are drilled to the northwest and southeast to intersect the natural fractures of the Austin Chalk. The horizontal sections of the wellbore are openhole completions that average 700 b/d of oil and 5 MMcfd of gas. Within 1 year of initial production, the wells require compression to sustain flow and conventional gas lift is used when the wells load up with fluid. Typically, when production declines to 200 Mcfd and 100 b/d of fluid, the gas lift injection point is at 8,000 ft and average gas lift usage is 500 Mcfd. Coiled tubing-conveyed artificial lift was suggested, but first other concerns had to be addressed. The long, horizontal lateral sections functioned as a natural gas and fluid separator, resulting in a distinct slug flow pattern. During a 24-hour period, slug flow caused the wells to produce 100% gas or 100% fluid. For cost reasons TEPI chose conventional, field-installed coiled tubing (CT) gas lift equipment over spoolable equipment. Texaco then formed a team alliance with McMurry-Macco Lift Systems and Dowell to evaluate and complete trial wells with coiled tubing gas lift equipment. This paper reviews the case history of the field, the design considerations of the coiled tubing gas lift, and the surface support equipment used.

  20. Experimental study of the effect of damage on rocks permeability; Etude experimentale de l'effet de l'endommagement sur la permeabilite des roches

    Energy Technology Data Exchange (ETDEWEB)

    Bounenni, A

    2002-05-01

    The effect of the cracking of rocks on their permeabilities arouses a growing interest by its consequences on the safety of radioactive waste disposal, and its applications to some problems of oil prospecting. This thesis is devoted to the experimental study of this phenomenon on some varieties of porous rocks. The adopted method consists in examining the evolution of the permeability with damage. Two varieties of clays, known as of the East and Gard varieties, were studied for applications to the problems of waste disposal, as well as a variety of chalk coming from the North Sea for oil applications. The major difficulties of the study of clays consist of a very low permeability and of the brittleness of these materials which make them difficult to create a diffuse damage or cracking in them. We however managed to show for example that the permeability of these materials can multiplied by a factor 100 for 4 per cent irreversible voluminal strain. The chalk is more porous and more permeable, and presents non difficulty for the measurement of the permeability. But the difficulty of creating a state of diffuse damage in this material remains. However, by ways of complex loading paths, we could in some cases make evolve the damage and the permeability and establish a phenomenological relation between these two quantities. Creation of crack in these material by thermal damage, using a microwave oven, proved to be a much simpler way and more promising than the mechanical way. The observation of the damaged clay samples by the electron microscope enabled us to determine the size scale of the microscopic cracks. On the damaged chalk samples, the acoustic velocity measurement made it possible to establish a simple relation between the permeability and the damage. (author)

  1. Climate change: implications for the yield of edible rice.

    Science.gov (United States)

    Zhao, Xiangqian; Fitzgerald, Melissa

    2013-01-01

    Global warming affects not only rice yield but also grain quality. A better understanding of the effects of climate factors on rice quality provides information for new breeding strategies to develop varieties of rice adapted to a changing world. Chalkiness is a key trait of physical quality, and along with head rice yield, is used to determine the price of rice in all markets. In the present study, we show that for every ∼1% decrease in chalkiness, an increase of ∼1% in head rice yield follows, illustrating the dual impact of chalk on amount of marketable rice and its value. Previous studies in controlled growing conditions report that chalkiness is associated with high temperature. From 1980-2009 at IRRI, Los Baños, the Philippines, annual minimum and mean temperatures, and diurnal variation changed significantly. The objective of this study was to determine how climate impacts chalkiness in field conditions over four wet and dry seasons. We show that low relative humidity and a high vapour pressure deficit in the dry season associate with low chalk and high head rice yield in spite of higher maximum temperature, but in the opposite conditions of the wet season, chalk is high and head rice yield is low. The data therefore suggest that transpirational cooling is a key factor affecting chalkiness and head rice yield, and global warming per se might not be the major factor that decreases the amount and quality of rice, but other climate factors in combination, that enable the crop to maintain a cool canopy.

  2. Climate change: implications for the yield of edible rice.

    Directory of Open Access Journals (Sweden)

    Xiangqian Zhao

    Full Text Available Global warming affects not only rice yield but also grain quality. A better understanding of the effects of climate factors on rice quality provides information for new breeding strategies to develop varieties of rice adapted to a changing world. Chalkiness is a key trait of physical quality, and along with head rice yield, is used to determine the price of rice in all markets. In the present study, we show that for every ∼1% decrease in chalkiness, an increase of ∼1% in head rice yield follows, illustrating the dual impact of chalk on amount of marketable rice and its value. Previous studies in controlled growing conditions report that chalkiness is associated with high temperature. From 1980-2009 at IRRI, Los Baños, the Philippines, annual minimum and mean temperatures, and diurnal variation changed significantly. The objective of this study was to determine how climate impacts chalkiness in field conditions over four wet and dry seasons. We show that low relative humidity and a high vapour pressure deficit in the dry season associate with low chalk and high head rice yield in spite of higher maximum temperature, but in the opposite conditions of the wet season, chalk is high and head rice yield is low. The data therefore suggest that transpirational cooling is a key factor affecting chalkiness and head rice yield, and global warming per se might not be the major factor that decreases the amount and quality of rice, but other climate factors in combination, that enable the crop to maintain a cool canopy.

  3. The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique

    OpenAIRE

    S.N. Danilchenko; V.D. Chіvanov; A.G. Ryabishev; S.V. Novіkov; A.A. Stepanenko; V.N. Kuznetsov; E.V. Mironets; A.V. Marіychuk; A.A. Yanovska; O.G. Bordunova; A.N. Bugay

    2016-01-01

    The experiments have shown that the heating range for quantitative evolution of carbon dioxide gas (CO2) from natural calcium carbonates (e.g., chalk, corals, shells of the Anadara clams (Anadara inaequivalvis), shell of bird eggs) is from 500 to 850 C with a total heating time of 30-50 minutes. The only exception is the sample of a mortar from a masonry of Saint Sophia Cathedral (the architectural monument of XI century), in which the lowest border of the heating range for carbon dioxide ev...

  4. Comparison of beam simulations with measurements for a 1.25-MeV, CW RFQ

    Energy Technology Data Exchange (ETDEWEB)

    Smith, H.V. Jr.; Bolme, G.O.; Sherman, J.D.; Stevens, R.R. Jr.; Young, L.M.; Zaugg, T.J.

    1998-12-31

    The Low-Energy Demonstration Accelerator (LEDA) injector is tested using the Chalk River Injector Test Stand (CRITS) radio-frequency quadrupole (RFQ) as a diagnostic instrument. Fifty-keV, dc proton beams are injected into the 1.25-MeV, CW RFQ and transported to a beamstop. Computer-simulation-code predictions of the expected beam performance are compared with the measured beam currents and beam profiles. Good agreement is obtained between the measurements and the simulations at the 75-mA design RFQ output current.

  5. Determination of Minimum Miscibility Pressure in supercritical extractor using oil saturated sample

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Abbasi, Waqas A.

    2009-01-01

    , in order to investigate the MMP, we suggest another method by using a supercritical extractor. Spe-ed SFE equipment with oil saturated natural rock samples were used for the purpose. The clean chalk samples were saturated with oil from the Dan field under vacuum. The CO2 gas was injected into the extractor...... vessel containing the sample at different increasing pressure levels. The oil displaced in such a way was collected and measured. The volume of extracted oil was plotted against the increasing pressure. The form of the graph is similar to that typically obtained from a slim tube experiment.  Following...

  6. The difference between the potentiometric surfaces of the Upper Patasco Aquifer, September 1990 and September 2003 in southern Maryland

    Science.gov (United States)

    Curtin, Stephen E.; Andreasen, David C.; Wheeler, Judith C.

    2005-01-01

    This report presents a map showing the change in the potentiometric surface of the Upper Patapsco aquifer in the Upper Patapsco Formation of Cretaceous age in Southern Maryland for September 1990 and September 2003. The map, based on water level measurements in 32 wells, shows that during the 13-year period, the potentiometric surface changed from an increase of 6 feet at Arnold, which is located just north of Annapolis, to a decline of 25 feet at Waldorf and Lexington Park and 20 feet at LaPlata and the Chalk Point powerplant.

  7. Study of the Recombination of H2 and O2 at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrophobic catalysts was developed at Chalk River Nuclear Laboratories and was used in the recombiner operated at ambient conditions. The advantage of operating a recombiner at ambient temperature were recognized by several researchers. It is clear that significant savings can be realized if the recombiner is operated at ambient temperature without the need for costly heaters and coolers. And the process is safer and more uncomplicated than conventional processes.The experimental conditions as followings: carrier gas is Ar; concentration of H2 is 1%;

  8. Miliarial gout: a rare presentation of extensive cutaneous tophi.

    Science.gov (United States)

    Hung, T-L; Wang, W-M; Chiang, C-P

    2016-12-01

    Gout is a systemic disorder characterized by hyperuricemia and recurrent arthritis, most involvement of ankles, midfoot joint and first metatarsophalangeal joint, with monosodium urate crystals deposition in synovial fluid and other tissues. We present a case of 53-year-old male, who had several nontender, white-yellow papules and plaques over his elbows, knees and arms with chalk-like substances and crust on inflammatory base wax and wane in the past 2 years. Upon histopathology examination of the skin lesions, it reported as intradermal urate tophi and miliarial gout was diagnosed. This case highlights the importance of considering unusual cutaneous tophi in the differential diagnosis of deposition disorders.

  9. 自动无尘黑板关键技术的研究%Research on Key Technologies of Automatic Dust-f ree Blackboard

    Institute of Scientific and Technical Information of China (English)

    夏凡; 李铭; 张融; 张成; 梅志敏

    2015-01-01

    The automatic dust‐free blackboard can electronically remove and collect the dust to protect human health .It consists of four parts:the operation of special soft blackboard belt ,the fixation and transmission of brushes ,the dust extraction and the control system .The automatic dust‐free blackboard changes the traditional cleaning method through the following ways:Firstly ,the flexible soft cloth with some chalk is to be turned back;Then the chalk would be eliminated by the brush on the back of the automatic dust‐free blackboard ,and the chalk dust would be absorbed by the extraction system into the dust box ;Finally ,the cleaned part would be turned out .The automatic dust‐free blackboard not only retains traditional blackboard’s character of using chalks ,but also protects teachers and students from the dust .It enjoys the advantages of low cost and low energy consumption ,which is in accord with the ergonomic principles .%介绍了自动无尘黑板的组成,重点介绍了特殊软体黑板带的运转、分层毛刷的固定与传动、吸尘装置和控制系统。自动无尘黑板改变传统黑板的去字模式,先将写了粉笔字的挠性软布转向后方,然后自动无尘黑板后方的毛刷清除粉笔字,再将粉笔灰用吸尘器吸入粉尘盒内,最后将清干的部分旋转到正面。这样既保留了传统黑板使用粉笔的特点,又解决了粉尘给师生带来的危害。具有低成本、低能耗等特点,符合人机工程学原理。

  10. The history of ZED-2

    Energy Technology Data Exchange (ETDEWEB)

    Jones, R. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2010-07-01

    This presentation gives the history of ZED-2 reactor at the Chalk River Laboratories. It traces the genealogy from Fermi Pile (1942) and ZEEP (1945) to the present ZED-2 reactor. ZED-2 is larger than ZEEP to allow larger critical lattices of larger CANDU type channels. There are two basic types of measurements made in ZED-2: critical size (buckling) of lattice and detailed reaction rate distribution in a cell. The presentation goes on to discuss research activities on ZED-2 from 1960 to the present.

  11. MANAGING NON-REPAYMENT RISK THROUGH GROUP-BASED LENDING IN MFIs

    OpenAIRE

    2009-01-01

    To analyze how MFIs are managing their non-repayment risk by using GBL approach. The deductive approach has been used in this study and the case study method is deployed. Khushhali Bank Limited, Pakistan has been taken for the subject MFI. The four inter-related theories have been taken into consideration, namely Portfolio, Principal-Agent, Contract and Transaction Cost Theories, to have a detailed literature review about the threat of non-repayment risk through GBL. The study chalked out a r...

  12. Areeni aasta albumid 2004. Personaalsed tipud / Erkki Tero

    Index Scriptorium Estoniae

    Tero, Erkki

    2007-01-01

    Heliplaatidest: Vaiko Eplik ja Eliit "2: Aastaajad", LCD Soundsystem "Sound of Silver", Arcade Fire "Neon Bible", M.I.A "Kala", Burial "Untrue", Chalice "Taevas ja Perse", Panda Bear "Person Pitch", Ans. Andur "Topeltvikerkaar", Animal Collective "Strawberry Jam", PJ Harvey "White Chalk", Devendra Banhart "Smokey Rolls Down The Thunder Canyon", Kreatiivmootor "Irratsionaalne", Holy Fuck "LP", 3 Pead "Ilusaim heli", Throbbing Gristle "Part Two: The Endless Not", Battles "Mirrored", Kings Of Leon "Because of the Times", Robert Wyatt "Comicopera", National "Boxer", Simian Mobile Disco "Attack Decay Sustain Release"

  13. Cliff Collapse Hazard from Repeated Multicopter Uav Acquisitions: Return on Experience

    Science.gov (United States)

    Dewez, T. J. B.; Leroux, J.; Morelli, S.

    2016-06-01

    Cliff collapse poses a serious hazard to infrastructure and passers-by. Obtaining information such as magnitude-frequency relationship for a specific site is of great help to adapt appropriate mitigation measures. While it is possible to monitor hundreds-of-meter-long cliff sites with ground based techniques (e.g. lidar or photogrammetry), it is both time consuming and scientifically limiting to focus on short cliff sections. In the project SUAVE, we sought to investigate whether an octocopter UAV photogrammetric survey would perform sufficiently well in order to repeatedly survey cliff face geometry and derive rock fall inventories amenable to probabilistic rock fall hazard computation. An experiment was therefore run on a well-studied site of the chalk coast of Normandy, in Mesnil Val, along the English Channel (Northern France). Two campaigns were organized in January and June 2015 which surveyed about 60 ha of coastline, including the 80-m-high cliff face, the chalk platform at its foot, and the hinterland in a matter of 4 hours from start to finish. To conform with UAV regulations, the flight was flown in 3 legs for a total of about 30 minutes in the air. A total of 868 and 1106 photos were respectively shot with a Sony NEX 7 with fixed focal 16mm. Three lines of sight were combined: horizontal shots for cliff face imaging, 45°-oblique views to tie plateau/platform photos with cliff face images, and regular vertical shots. Photogrammetrically derived dense point clouds were produced with Agisoft Photoscan at ultra-high density (median density is 1 point every 1.7cm). Point cloud density proved a critical parameter to reproduce faithfully the chalk face's geometry. Tuning down the density parameter to "high" or "medium", though efficient from a computational point of view, generated artefacts along chalk bed edges (i.e. smoothing the sharp gradient) and ultimately creating ghost volumes when computing cloud to cloud differences. Yet, from a hazard point of

  14. CLIFF COLLAPSE HAZARD FROM REPEATED MULTICOPTER UAV ACQUISITIONS: RETURN ON EXPERIENCE

    Directory of Open Access Journals (Sweden)

    T. J. B. Dewez

    2016-06-01

    Full Text Available Cliff collapse poses a serious hazard to infrastructure and passers-by. Obtaining information such as magnitude-frequency relationship for a specific site is of great help to adapt appropriate mitigation measures. While it is possible to monitor hundreds-of-meter-long cliff sites with ground based techniques (e.g. lidar or photogrammetry, it is both time consuming and scientifically limiting to focus on short cliff sections. In the project SUAVE, we sought to investigate whether an octocopter UAV photogrammetric survey would perform sufficiently well in order to repeatedly survey cliff face geometry and derive rock fall inventories amenable to probabilistic rock fall hazard computation. An experiment was therefore run on a well-studied site of the chalk coast of Normandy, in Mesnil Val, along the English Channel (Northern France. Two campaigns were organized in January and June 2015 which surveyed about 60 ha of coastline, including the 80-m-high cliff face, the chalk platform at its foot, and the hinterland in a matter of 4 hours from start to finish. To conform with UAV regulations, the flight was flown in 3 legs for a total of about 30 minutes in the air. A total of 868 and 1106 photos were respectively shot with a Sony NEX 7 with fixed focal 16mm. Three lines of sight were combined: horizontal shots for cliff face imaging, 45°-oblique views to tie plateau/platform photos with cliff face images, and regular vertical shots. Photogrammetrically derived dense point clouds were produced with Agisoft Photoscan at ultra-high density (median density is 1 point every 1.7cm. Point cloud density proved a critical parameter to reproduce faithfully the chalk face’s geometry. Tuning down the density parameter to “high” or “medium”, though efficient from a computational point of view, generated artefacts along chalk bed edges (i.e. smoothing the sharp gradient and ultimately creating ghost volumes when computing cloud to cloud differences. Yet

  15. Proteomics of Rice Grain under High Temperature Stress

    Directory of Open Access Journals (Sweden)

    Toshiaki eMitsui

    2013-03-01

    Full Text Available Recent proteomic analyses revealed dynamic changes of metabolisms during rice grain development. Interestingly, proteins involved in glycolysis, citric acid cycle, lipid metabolism, and proteolysis were accumulated at higher levels in mature grain than those of developing stages. High temperature stress in rice ripening period causes damaged (chalky grains which have loosely packed round shape starch granules. The high temperature stress response on protein expression is complicated, and the molecular mechanism of the chalking of grain is obscure yet. Here, the current state on the proteomics research of rice grain grown under high temperature stress is briefly overviewed.

  16. Recharge Response Functions

    Directory of Open Access Journals (Sweden)

    A. Calver

    1997-01-01

    Full Text Available This paper explores the establishment of transfer functions for describing the annual oscillation of unconfined aquifer water levels in response to effective precipitation. A simple saturated zone representation is developed to accompany the unsaturated zone mechanism. Practical examples are drawn from a sample of sites from the chalk and the Permo-Triassic sandstones of England and Wales. Modelled water levels are in many cases good. The technique is most appropriate within the usual range of fluctuation of aquifer water level, with no great change in influence of abstractions, and when it is acceptable to approximate the complexity of unsaturated zone processes in practical analysis.

  17. Aerosol Formation during the Combustion of Straw with Addition of Sorbents

    DEFF Research Database (Denmark)

    Zeuthen, Frederik Jacob; Jensen, Peter Arendt; Jensen, Jørgen P.;

    2007-01-01

    The influence of six sorbents on aerosol formation during the combustion of straw in a 100 MW boiler on a Danish power plant has been studied in full-scale. The following sorbents were studied: ammonium sulfate, monocalcium phosphate, Bentonite, ICA5000, clay, and chalk. Bentonite and ICA5000...... are mixtures of clay minerals and consist mainly of the oxides from Fe, Al, and Si. The straw used was Danish wheat and seed grass. Measurements were also made with increased flow of primary air. The experiments showed between 46% and 70% reduction in particle mass concentrations when adding ammonium sulfate...

  18. Modelling of catalytic oxidation of NH3 and reduction of NO on limestone during sulphur capture

    DEFF Research Database (Denmark)

    Kiil, Søren; Bhatia, Suresh K.; Dam-Johansen, Kim

    1996-01-01

    for the catalytic chemistry of NH3 during simultaneous sulphur capture on a Stevns Chalk particle. The reduction of NO by NH3 over CaSO4 (which is the product of the reaction between SO2, O2 and limestone) was found to be important because this reaction could explain the change in selectivity with increased solid...... conversion observed experimentally. Simulations also suggested that it may be advantageous with respect to the emission of NO to use smallinstead of big limestone particles for desulphurisation in fluidised bed combustors due to the ways different sized particles capture SO2....

  19. Laboratory and field scale modelling of two-phase flow in fractured structures

    Energy Technology Data Exchange (ETDEWEB)

    Lindgaard, Hanne Foss [The Geological Survey of Denmark and Greenland, Copenhagen (Denmark); Reffstrup, Jan [Technical Univ. of Denmark, Lyngby (Denmark); Kaae Olsen, Niels [Danish Hydraulic Institute, Hoersholm (Denmark)

    1996-12-31

    The imbibition of water in matrix blocks plays a significant role in oil recovery from certain types of fractured reservoirs with a low permeable, porous matrix. These types of fractured reservoirs have a water-wet matrix, strong capillary forces and an inflow of water: either from an aquifer or as a result of forced water injection. Several chalk reservoirs in the North Sea correspond to this description. This paper presents a comparison between laboratory scale experiments, and numerical studies of water imbibition in a fractured porous media. Both the single and the double porosity/permeability approach have been used to simulate the experiments. (au) EFP-96. 11 refs.

  20. Full-Length High-Temperature Severe Fuel Damage Test No. 5: Final safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Lanning, D.D.; Lombardo, N.J.; Panisko, F.E.

    1993-09-01

    This report presents the final safety analysis for the preparation, conduct, and post-test discharge operation for the Full-Length High Temperature Experiment-5 (FLHT-5) to be conducted in the L-24 position of the National Research Universal (NRU) Reactor at Chalk River Nuclear Laboratories (CRNL), Ontario, Canada. The test is sponsored by an international group organized by the US Nuclear Regulatory Commission. The test is designed and conducted by staff from Pacific Northwest Laboratory with CRNL staff support. The test will study the consequences of loss-of-coolant and the progression of severe fuel damage.

  1. The balanced scorecard advantage: Driving strategic change into Canada's nuclear laboratory site operations

    Energy Technology Data Exchange (ETDEWEB)

    Lafreniere, P. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada); Weeks, D. [Haggarty' s Cove Ventures (2001 Ltd.) St. Stephen, New Brunswick (Canada)

    2001-07-01

    The challenges presented by the size, diversity, complexity and history of the Facilities and Nuclear Operations (FNO) Group at AECL's Chalk River Laboratories (CRL) required a change to the traditional management approach. As a result, a strategy was adopted that focused on integrating contemporary business practices such as process mapping, activity based management and use of the Balanced Scorecard methodology into the operational culture at CRL. In addition, revitalization of the performance management methods process was undertaken to provide a tool for assessment of business and individual performance. performance. (author)

  2. Shear moduli in bcc-fcc structure transition of colloidal crystals.

    Science.gov (United States)

    Zhou, Hongwei; Xu, Shenghua; Sun, Zhiwei; Zhu, Ruzeng

    2015-10-14

    Shear moduli variation in the metastable-stable structure transition of charged colloidal crystals was investigated by the combination techniques of torsional resonance spectroscopy and reflection spectrometer. Modulus of the system increases with the proceeding of the transition process and it finally reaches the maximum value at the end of the transition. For colloidal crystals in stable state, the experimental moduli show good consistence with theoretical expectations. However, in the transition process, the moduli are much smaller than theoretical ones and this can be chalked up to crystalline imperfection in the transition state.

  3. Shear moduli in bcc-fcc structure transition of colloidal crystals

    Science.gov (United States)

    Zhou, Hongwei; Xu, Shenghua; Sun, Zhiwei; Zhu, Ruzeng

    2015-10-01

    Shear moduli variation in the metastable-stable structure transition of charged colloidal crystals was investigated by the combination techniques of torsional resonance spectroscopy and reflection spectrometer. Modulus of the system increases with the proceeding of the transition process and it finally reaches the maximum value at the end of the transition. For colloidal crystals in stable state, the experimental moduli show good consistence with theoretical expectations. However, in the transition process, the moduli are much smaller than theoretical ones and this can be chalked up to crystalline imperfection in the transition state.

  4. Esthetic and functional rehabilitation of mutilated dentition and loss of vertical dimension due to amelogenesis imperfecta.

    Science.gov (United States)

    Mittal, Shweta; Tewari, Sanjay; Goel, Rajat

    2014-04-01

    Cases of severe attrition are a common finding. Among the congenital anomalies, amelogenesis imperfecta and dentinogenesis imperfecta are important conditions that may cause accelerated wear of teeth. The following case report describes the complete oral rehabilitation of a patient diagnosed with amelogenesis imperfecta. A detailed treatment plan was chalked out which included proper oral hygiene measures, restoration of carious teeth and endodontic treatment followed by foundation restorations of teeth that were crucial for the final prostheses. Patient was given transitional restorations for about 6 weeks with the aim of regaining the lost vertical dimensions. Final rehabilitation was done by fixed dental prostheses.

  5. Latest European coelacanth shows Gondwanan affinities.

    Science.gov (United States)

    Cavin, Lionel; Forey, Peter L; Buffetaut, Eric; Tong, Haiyan

    2005-06-22

    The last European fossil occurrence of a coelacanth is from the Mid-Cretaceous of the English Chalk (Turonian, 90 million years ago). Here, we report the discovery of a coelacanth from Late Cretaceous non-marine rocks in southern France. It consists of a left angular bone showing structures that imply close phylogenetic affinities with some extinct Mawsoniidae. The closest relatives are otherwise known from Cretaceous continental deposits of southern continents and suggest that the dispersal of freshwater organisms from Africa to Europe occurred in the Late Cretaceous.

  6. JPRS Report West Europe

    Science.gov (United States)

    2007-11-02

    the European left, the same kind of thing is happening. In Spain, Felipe Gonzales throws out of the cabinet a union leader who accuses him of "left...Negative Views 35480005 Madrid CAMBIO 16 in Spanish 19 Sep 88 pp 16-22 [Article by Juan Gomez and Luis Rubio: "Of What Use Is This Army?"] [Text...cake," and Great Britain chalked up another victory in its war history. Nevertheless, there are some who, like Jose Luis Buhigas, ex-chairman of

  7. Constructing ’The Other’: Ethno-Religious Identity in Separatist Movements in Southeast Asia

    Science.gov (United States)

    2005-01-01

    Press, 1992), 169. 9 Ibid., 170. 10 Ibid., 169-70. 11 Also spelled Melaka . 12 Andaya and Ishii, “Religious Developments,” 172-3. 13 Ibid. 14 CIA...Aceh‟s Case: Possible Solution to a Festering Conflict,” Journal of Muslim Minority Affairs 20, no. 1 (April 2000): 107. 35 John Gee, “As a Result...War on Terrorism,” RUSI Journal 148, no. 1, (February 2003): 26. 69 Chalk, (Islamic Factor), 243. 70 Ibid., 245. 71 Ibid., 246. 72 Office of the

  8. Vibrational motions in rotating nuclei studied by Coulomb excitations

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, Yoshifumi R. [Kyushu Univ., Fukuoka (Japan). Dept. of Physics

    1998-03-01

    As is well-known Coulomb excitation is an excellent tool to study the nuclear collective motions. Especially the vibrational excitations in rotating nuclei, which are rather difficult to access by usual heavy-ion fusion reactions, can be investigated in detail. Combined with the famous 8{pi}-Spectrometer, which was one of the best {gamma}-ray detector and had discovered some of superdeformed bands, such Coulomb excitation experiments had been carried out at Chalk River laboratory just before it`s shutdown of physics division. In this meeting some of the experimental data are presented and compared with the results of theoretical investigations. (author)

  9. Assessment of the National Research Universal Reactor Proposed New Stack Sampling Probe Location for Compliance with ANSI/HPS N13.1-1999

    Energy Technology Data Exchange (ETDEWEB)

    Glissmeyer, John A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Antonio, Ernest J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Flaherty, Julia E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-02-29

    This document reports on a series of tests conducted to assess the proposed air sampling location for the National Research Universal reactor (NRU) complex exhaust stack, located in Chalk River, Ontario, Canada, with respect to the applicable criteria regarding the placement of an air sampling probe. Due to the age of the equipment in the existing monitoring system, and the increasing difficulty in acquiring replacement parts to maintain this equipment, a more up-to-date system is planned to replace the current effluent monitoring system, and a new monitoring location has been proposed. The new sampling probe should be located within the exhaust stack according to the criteria established by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999, Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities. These criteria address the capability of the sampling probe to extract a sample that represents the effluent stream. The internal Pacific Northwest National Laboratory (PNNL) project for this task was 65167, Atomic Energy Canada Ltd. Chalk River Effluent Duct Flow Qualification. The testing described in this document was guided by the Test Plan: Testing of the NRU Stack Air Sampling Position (TP-STMON-032).

  10. Use of clinical practice as a motivating tool of radioprotection teaching and radiopharmacology in early semesters of pharmacy course; Uso da pratica clinica como ferramenta motivadora de ensino de radioprotecao e radiofarmacologia em semestres iniciais em cursos de farmacia

    Energy Technology Data Exchange (ETDEWEB)

    Andrighetto, Daniela; Lüdke, Everton, E-mail: daniela.andrighetto@hotmail.com, E-mail: evertonludke@gmail.com [Universidade Federal de Santa Maria (CCNE/DEFIS/UFSM), RS (Brazil). Departamento de Fisica

    2014-07-01

    The research teaching methods aimed at the success of the higher education student in pharmacology and medicine courses in technical expertise in the fields of radiological protection, radiopharmacology and interventional radiology is extremely important in view of the progress of these sectors. The objective of this work is to propose a methodological sequence of teaching work with first-year students of pharmacy and medicine courses within a biophysical discipline where the integrated knowledge to clinical practice can be used for this purpose. The methodology was to assess individual learning of a group of N = 49 students of the first half in the age group of 17-19 years through conceptual acquisition by the traditional method of 'blackboard and chalk' and developed method that includes four pedagogical moments focused on the area health. An analysis of the evaluation student performance through Variance Analysis of a pathway showed improved scores with respect to the performance of application issues of knowledge concerning radiation protection and biological mechanisms of radiation with respect to the method of 'blackboard and chalk' with p < 0.05. Therefore, work with students with respect to the content in the form of six steps of clinical interest are a promising technique for radiation protection education in the early grades of college courses with experimental effectiveness.

  11. Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

    Energy Technology Data Exchange (ETDEWEB)

    Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

    2003-11-15

    The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

  12. Geometrical Studies of Complex Geological Media Using Scaling Laws

    Energy Technology Data Exchange (ETDEWEB)

    Huseby, O.K. [Institutt for Energiteknikk, Kjeller (Norway)

    1996-12-31

    This doctoral thesis applies scaling concepts to characterize the morphology of geological porous media and fracture networks and relates scaling exponents to the sample`s physical properties. The first part of the thesis applies multifractal scaling (MS) to the study of the morphology of random porous media. MS is used to characterize scanning electron microscope (SEM) images of chalk samples from the North Sea, and dipmeter micro resistivity signals from several wells in different North Sea reservoirs. The second part of the thesis develops and characterizes a model of a stochastic fracture network. Here, the application of the scaling concept differs from that in the first part, since the scaling concept is applied to percolation structures and not used as a characterization tool based on MS. Several methods and concepts must be introduced to characterize geological data and to understand the fracture model and some of them are described in four enclosed research papers. Paper 1, on the SEM images, suggests that pore space of sedimentary chalk is multifractal. Papers 2 and 3, on the dipmeter signals from reservoir wells, present a new method for extracting information about geological formations from a micro resistivity log. The main conclusion of Paper 4 on fracture networks, is that the influence of fracture shapes on percolation thresholds, block densities and topology could be explained using the concept of excluded volume. 114 refs., 48 figs., 6 tabs.

  13. The Neogene and Quaternary Clay-with-flints north and south of the English Channel: comparisons of distribution, age, genetic processes and geodynamics

    Science.gov (United States)

    Quesnel, Florence; Catt, John; Laignel, Benoît; Bourdillon, Chantal; Meyer, Robert

    2003-02-01

    Weathered residual accumulations termed Clay-with-flints (Argiles à silex) overlying Cretaceous deposits are widespread in southern England and northwestern France. Geological and pedological studies and some field surveys indicate their distribution, nature, age and origin. In France, the microfaunas preserved in the hollow flints of the Clay-with-flints demonstrate the preservation of the parent Chalk stratigraphy in the sections studied, i.e. the Clay-with-flints corresponds to in situ weathering profiles. However, in England and in France, an important part of the clay component is derived from a thin veneer of basal Tertiary sediment overlying sub-Tertiary marine erosion surfaces of various Palaeogene transgressions. In England as in France, the youngest generation of Clay-with-flints can be dated from Late Pliocene to Quaternary. It formed after removal of different Cenozoic deposits on many plateaus and during the downcutting of Pleistocene rivers. The most visible effect of subsequent weathering profile development is irregular dissolution of the underlying Chalk to produce deep karstic pipes into which the Clay-with-flints has slumped; other pedological processes include rubification, clay illuviation and cryoturbation. Clay-with-flints also provides evidence of Quaternary palaeoenvironments, Cenozoic continental palaeosurfaces, and their vertical deformation.

  14. Recent acceleration in coastal cliff retreat rates on the south coast of Great Britain.

    Science.gov (United States)

    Hurst, Martin D; Rood, Dylan H; Ellis, Michael A; Anderson, Robert S; Dornbusch, Uwe

    2016-11-22

    Rising sea levels and increased storminess are expected to accelerate the erosion of soft-cliff coastlines, threatening coastal infrastructure and livelihoods. To develop predictive models of future coastal change we need fundamentally to know how rapidly coasts have been eroding in the past, and to understand the driving mechanisms of coastal change. Direct observations of cliff retreat rarely extend beyond 150 y, during which humans have significantly modified the coastal system. Cliff retreat rates are unknown in prior centuries and millennia. In this study, we derived retreat rates of chalk cliffs on the south coast of Great Britain over millennial time scales by coupling high-precision cosmogenic radionuclide geochronology and rigorous numerical modeling. Measured (10)Be concentrations on rocky coastal platforms were compared with simulations of coastal evolution using a Monte Carlo approach to determine the most likely history of cliff retreat. The (10)Be concentrations are consistent with retreat rates of chalk cliffs that were relatively slow (2-6 cm⋅y(-1)) until a few hundred years ago. Historical observations reveal that retreat rates have subsequently accelerated by an order of magnitude (22-32 cm⋅y(-1)). We suggest that acceleration is the result of thinning of cliff-front beaches, exacerbated by regional storminess and anthropogenic modification of the coast.

  15. Soiling and degradation analysis of solar mirrors

    Science.gov (United States)

    Delord, Christine; Blaise, Anthony; Fernandez-García, Aránzazu; Martínez-Arcos, Lucía; Sutter, Florian; Reche-Navarro, Tomás Jesús

    2016-05-01

    The degradation and the soiling of the mirrors are dependent of the solar field and the mirrors technologies, the local climate, the meteorological events, the O&M tasks and the human activities around the site. In the frame of the European project SFERA II, the SODAM project has been the opportunity to compare the soiling and the degradation mechanisms on a Fresnel solar field installed in the South of France and on a parabolic-through solar field installed in the South of Spain. The analysis of the soiling has shown equivalent maximum weekly reflectance loss due to soiling in both sites but a double mean weekly reflectance loss in Spain respect to France, as well as typical meteorological events to be taken into account to adapt the cleaning strategies. Among the meteorological parameters mainly influencing the soiling, the study has revealed the effect of the rain and of the DNI. In parallel, the analysis of the degradation mechanisms has highlighted a common chalking of the protective back paint layers due to the irradiation. This chalking being associated to a leaching of the paint layers in the site of Cadarache due to the high presence of liquid water. A difference in the speed of corrosion of the silver layer has been also noticed, leading to a difference in the mechanisms of delamination of the paints layers.

  16. LOSS-OF-COOLANT ACIDENT SIMULATIONS IN THE NATIONAL RESEARCH UNIVERSAL REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, W D; Goodman, R L; Heaberlin, S W; Hesson, G M; Nealley, C; Kirg, L L; Marshall, R K; McNair, G W; Meitzler, W D; Neally, G W; Parchen, L J; Pilger, J P; Rausch, W N; Russcher, G E; Schreiber, R E; Wildung, N J

    1981-02-01

    Pressurized water reactor loss-of-coolant accident (LOCA) phenomena are being simulated with a series of experiments in the U-2 loop of the National Research Universal Reactor at Chalk River, Ontario, Canada. The first of these experiments includes up to 45 parametric thermal-hydraulic tests to establish the relationship among the reflood delay time of emergency coolant, the reflooding rate, and the resultant fuel rod cladding peak temperature. Subsequent experiments establish the fuel rod failure characteristics at selected peak cladding temperatures. Fuel rod cladding pressurization simulates high burnup fission gas pressure levels of modern PWRs. This document contains both an experiment overview of the LOCA simulation program and a review of the safety analyses performed by Pacific Northwest Laboratory (PNL) to define the expected operating conditions as well as to evaluate the worst case operating conditions. The primary intent of this document is to supply safety information required by the Chalk River Nuclear Laboratories (CRNL), to establish readiness to proceed from one test phase to the next and to establish the overall safety of the experiment. A hazards review summarizes safety issues, normal operation and three worst case accidents that have been addressed during the development of the experiment plan.

  17. Chemical and isotopic tracing of underground water in relation with leaching of mine spoils, Nord-Pas-de-Calais Coal Basin (France); Tracage chimique et isotopique des eaux souterraines en relation avec les eaux de lixiviation de terrils, bassin minier du Nord-Pas-de-Calais (France)

    Energy Technology Data Exchange (ETDEWEB)

    Denimal, S.; Tribovillard, N.; Meilliez, F. [Lille-1 Univ., Lab. de Sedimentologie et Geodynamique, UMR 8577, 59 - Villeneuve-d' Ascq (France); Barbecot, F.; Dever, L. [Paris-11 Univ., Lab. d' Hydrologie et de Geochimie Isotopique, UMR 8616, 91 - Orsay (France)

    2001-07-01

    Coal mining activity in the Nord-Pas-de-Calais region (Northern France) has generated many mine spoils. The oxidation of the pyrite content of such coal shales and their leaching can be a source of sulfate pollution for the underlying chalk aquifer, i.e. the main drinking water resource of the region. Two sites of study have been retained: one in the free water table zone and the other in the confined water table zone. Samples from both mine spoils have been analyzed with respect to their carbon and sulfur content and a superficial leaching of these elements has been evidenced. Water has been sampled in piezometers and boreholes close to the mine spoils and also along natural flux lines. The use of sulfur isotopes as markers of the different sulfate sources has confirmed the spoils source but has permitted to identify another source in the second site which is the Tertiary gypsum-bearing Ostricourt sands. This study has shown also that in the confined water table zone, part of the exported sulfates is reduced. This bacterial reduction of sulfates is due to a joint leaching of both carbon and sulfur in the mine spoils. A self-purification phenomenon occurs when the chalk aquifer is confined beneath the Cenozoic cover. (J.S.)

  18. Upper bounds on a two-term exponential sum

    Institute of Scientific and Technical Information of China (English)

    Todd; Cochrane

    2001-01-01

    [1]Davenport, H. , Heibronn, H., On an exponential sum, Proc. Lond. Math. Soc., 1936, 41(2): 449-453.[2]Hua, L. K., On exponential sums, Sci. Record (Peking) (N.S.), 1957, 1: 1-4.[3]Vaughan, R. C. , The Hardy-Littlewood Method, 2nd ed. , Cambridge Tracts in Math. , Cambridge: Cambridge Univ. Press, 1997, 125.[4]Weil, A., On some exponential sums, Proc. Nat. Acad. Sci. USA, 1948, 34: 204-207.[5]Cochrane, T., Zheng, Z., Pure and mixed exponential sums, Acta Arith. , 1999, 91(3): 249-278.[6]Chalk, J. H. H., On Hua's estimate for exponential sums, Mathematika, 1987, 34: 115-123.[7]Loh, W. K. A. , Hua's Lemma, Bull. Australian Math. Soc., 1994, 50(3): 451-458.[8]Ding, P., An improvement to Chalk's estimation of exponential sums, Acta Arith. , 1991, 59(2): 149-155.

  19. Improving the method of low-temperature anisotropy of magnetic susceptibility (LT-AMS) measurements in air

    Science.gov (United States)

    Issachar, R.; Levi, T.; Lyakhovsky, V.; Marco, S.; Weinberger, R.

    2016-07-01

    This study examines the limitations of the method of low-temperature anisotropy of magnetic susceptibility (LT-AMS) measurements in air and presents technical improvements that significantly reduce the instrumental drift and measurement errors. We analyzed the temperature profile of porous chalk core after cooling in liquid nitrogen and found that the average temperature of the sample during the LT-AMS measurement in air is higher than 77K and close to 92K. This analysis indicates that the susceptibility of the paramagnetic minerals are amplified by a factor ˜3.2 relative to that of room temperature AMS (RT-AMS). In addition, it was found that liquid nitrogen was absorbed in the samples during immersing and contributed diamagnetic component of ˜-9 × 10-6 SI to the total mean susceptibility. We showed that silicone sheet placed around and at the bottom of the measuring coil is an effective thermal protection, preventing instrument drift by the cold sample. In this way, the measuring errors of LT-AMS reduced to the level of RT-AMS, allowing accurate comparison with standard AMS measurements. We examined the applicability of the LT-AMS measurements on chalk samples that consist weight) of paramagnetic minerals and showed that it helps to efficiently enhance the paramagnetic fabric. The present study offers a practical approach, which can be applied to various types of rocks to better delineate the paramagnetic phase using conventional equipment.

  20. Stratigraphy and sedimentology of the Upper Cretaceous (Campanian) Anacacho Limestone, Texas, USA

    Science.gov (United States)

    Swezey, C.S.; Sullivan, E.C.

    2004-01-01

    The Upper Cretaceous Anacacho Limestone is exposed in outcrops between the cities of San Antonio and Del Rio, Texas. A detailed study of four outcrops (Blanco Creek section, Sabinal River section, Seco Creek section, Hondo Creek section) shows that the Anacacho Limestone rests on the Upson Clay (which contains fauna of early Campanian age) and is overlain by the Corsicana Marl (which contains fauna of early Maastrichtian age). An unconformity within the Anacacho Limestone is used herein to separate the limestone into a lower member and an upper member. The lower Anacacho member contains fauna of early Campanian age, whereas the upper Anacacho member contains fauna of middle Campanian age. The lower Anacacho member consists predominantly of wackestones to packstones, which are overlain by packstones to grainstones capped by the unconformity. This unconformity is interpreted as a marine flooding surface, delineating a transition from carbonate grainstones deposited in shallow water (<30 m depth) to a chalk deposited in deeper water. Above the unconformity, the upper Anacacho member is characterized by a chalk, overlain by wackestones and packstones. The uppermost section of the Anacacho Limestone consists of packstones and grainstones with abundant and diverse fossils. Most of the Anacacho Limestone developed in relatively shallow water (<50 m depth) leeward of a large carbonate build-up (possibly a rudistid reef) that now comprises the Anacacho Mountains. The environment, however, was open to marine water throughout deposition of the Anacacho Limestone. ?? 2004 Elsevier Ltd. All rights reserved.

  1. Characterisation of hydraulic head changes and aquifer properties in the London Basin using Persistent Scatterer Interferometry ground motion data

    Science.gov (United States)

    Bonì, R.; Cigna, F.; Bricker, S.; Meisina, C.; McCormack, H.

    2016-09-01

    In this paper, Persistent Scatterer Interferometry was applied to ERS-1/2 and ENVISAT satellite data covering 1992-2000 and 2002-2010 respectively, to analyse the relationship between ground motion and hydraulic head changes in the London Basin, United Kingdom. The integration of observed groundwater levels provided by the Environment Agency and satellite-derived displacement time series allowed the estimation of the spatio-temporal variations of the Chalk aquifer storage coefficient and compressibility over an area of ∼1360 km2. The average storage coefficient of the aquifer reaches values of 1 × 10-3 and the estimated average aquifer compressibility is 7.7 × 10-10 Pa-1 and 1.2 × 10-9 Pa-1 for the periods 1992-2000 and 2002-2010, respectively. Derived storage coefficient values appear to be correlated with the hydrogeological setting, where confined by the London Clay the storage coefficient is typically an order of magnitude lower than where the chalk is overlain by the Lambeth Group. PSI-derived storage coefficient estimates agree with the values obtained from pumping tests in the same area. A simplified one-dimensional model is applied to simulate the ground motion response to hydraulic heads changes at nine piezometers. The comparison between simulated and satellite-observed ground motion changes reveals good agreement, with errors ranging between 1.4 and 6.9 mm, and being 3.2 mm on average.

  2. An age-calibrated record of upper Campanian – Maastrichtian climate change in the Boreal Realm

    DEFF Research Database (Denmark)

    Thibault, Nicolas Rudolph; Schovsbo, Niels; Harlou, Rikke;

    nannofossil chalk is in agreement with planktic biotic events of the latest Cretaceous and matches well with climatic trends of intermediate- and deep-waters from other oceanic basins recorded through benthic foraminiferal d18O (Barrera and Savin, 1999). However, most planktic foraminiferal d18O data do......The latest Cretaceous climate of the Boreal Realm was recorded through high-resolution bulk carbon- and oxygen-stable isotopes and a nannofossil temperature index (NTI) on the Stevns-1 core (Denmark) which recovered 456 m of upper Campanian to basal Danian chalk with ~100% recovery and an excellent...... temperatures (SSTs) in the Boreal Realm. Three warming events punctuate the overall cooling trend of the latest Cretaceous: (1) the late Campanian climatic optimum (73.9–71.6 Ma) is characterized by maximum SSTs of 20°C, (2) the mid-Maastrichtian warming (69.7–68 Ma) is characterized by stable SSTs around 17°C...

  3. Methods for Neutron Spectrometry

    Science.gov (United States)

    Brockhouse, Bertram N.

    1961-01-09

    The appropriate theories and the general philosophy of methods of measurement and treatment of data neutron spectrometry are discussed. Methods of analysis of results for liquids using the Van Hove formulation, and for crystals using the Born-von Karman theory, are reviewed. The most useful of the available methods of measurement are considered to be the crystal spectrometer methods and the pulsed monoenergetic beam/time-of-flight method. Pulsed-beam spectrometers have the advantage of higher counting rates than crystal spectrometers, especially in view of the fact that simultaneous measurements in several counters at different angles of scattering are possible in pulsed-beam spectrometers. The crystal spectrometer permits several valuable new types of specialized experiments to be performed, especially energy distribution measurements at constant momentum transfer. The Chalk River triple-axis crystal-spectrometer is discussed, with reference to its use in making the specialized experiments. The Chalk River rotating crystal (pulsed-beam) spectrometer is described, and a comparison of this type instrument with other pulsed-beam spectrometers is made. A partial outline of the theory of operation of rotating-crystal spectrometers is presented. The use of quartz-crystal filters for fast neutron elimination and for order elimination is discussed. (auth)

  4. Recent acceleration in coastal cliff retreat rates on the south coast of Great Britain

    Science.gov (United States)

    Hurst, Martin D.; Rood, Dylan H.; Ellis, Michael A.; Anderson, Robert S.; Dornbusch, Uwe

    2016-11-01

    Rising sea levels and increased storminess are expected to accelerate the erosion of soft-cliff coastlines, threatening coastal infrastructure and livelihoods. To develop predictive models of future coastal change we need fundamentally to know how rapidly coasts have been eroding in the past, and to understand the driving mechanisms of coastal change. Direct observations of cliff retreat rarely extend beyond 150 y, during which humans have significantly modified the coastal system. Cliff retreat rates are unknown in prior centuries and millennia. In this study, we derived retreat rates of chalk cliffs on the south coast of Great Britain over millennial time scales by coupling high-precision cosmogenic radionuclide geochronology and rigorous numerical modeling. Measured 10Be concentrations on rocky coastal platforms were compared with simulations of coastal evolution using a Monte Carlo approach to determine the most likely history of cliff retreat. The 10Be concentrations are consistent with retreat rates of chalk cliffs that were relatively slow (2-6 cmṡy-1) until a few hundred years ago. Historical observations reveal that retreat rates have subsequently accelerated by an order of magnitude (22-32 cmṡy-1). We suggest that acceleration is the result of thinning of cliff-front beaches, exacerbated by regional storminess and anthropogenic modification of the coast.

  5. Fiscal 1997 report on the results of the international standardization R and D. Quantification of the sensory evaluation and international standardization in the paint field; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Toryo bun`ya ni okeru kanno hyoka no teiryoka to kokusai hyojunka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Japanese paint users demand products of higher-quality than users in the U.S. and Europe, and therefore, paint makeres in Japan are making strenuous efforts to improve the product quality in terms of homogeneity, appearence and durability of the surface of paint films. However, the evaluation of paint surfaces is conducted by the qualitative sensory evaluation, resulting in obtaining no appropriate evaluation. Accordingly, the following were developed as new evaluation methods which give rational and economical indicators, contribute to shortening of the period for development of new products, and aim at the international standardization: 1) quantitative evaluation of the paint drying process; 2) image analysis of the degraded part of paint films; 3) surface analysis of paint films. In 1), a kinetic friction measuring quantitative evaluation of the surface of paint films was developed. In 2), the development of an exclusive program by the image analysis made the quantitative evaluation with high accuracy/reliability possible. In 3), an evaluation method was developed in which differences among the specimens can be detected by the chemiluminescent measurement in an extremely early stage of exposure when the gloss change just begins. As to the chalking, a new evaluation was developed in which the degree of chalking can quantitatively be evaluated by attaching a special adhesion tape to the degraded part of paint films and by the optical measurement of the degree of transparency. 101 refs., 341 figs., 118 tabs.

  6. Extreme Rainfall Impacts in Fractured Permeable Catchments

    Science.gov (United States)

    Ireson, A. M.; Butler, A. P.

    2009-12-01

    Serious groundwater flooding events have occurred on Chalk catchments in both the UK and north west Europe in the last decade, causing substantial amounts of disruption and economic damage. These fractured, permeable catchments are characterized by low surface runoff, high baseflow indices and strongly attenuated streamflow hydrographs. They have a general resilience to drought and pluvial/fluvial flooding. The small pore size of the Chalk matrix (~ 1 µm) exerts a high suction, such that dynamic storage is primarily due to the fractures, and amounts to ~ 1% of the total volume. As a result, under sustained rainfall the water table can rise up to exceptional levels leading to surface water emergence from springs and valleys. Floodwater may slowly drain with the topography, or, in localized depressions, it may simply pond until the groundwater levels decline. In winter 2000/1, a sequence of individually unexceptional rainfall events over several months led to large scale flooding in the Pang catchment, Berkshire, UK. By contrast, an extreme rainfall event on 20th July 2007 in the same catchment caused a very rapid response at the water table, but due to the antecedent conditions did not lead to flooding. The objective of this study is to quantify how the water table in a fractured permeable catchment responds to different types of rainfall, and the implications of this for groundwater flooding. We make use of measurements from the Pang catchment, including: rainfall (tipping bucket gauges); actual evaporation (eddy flux correlation); soil water content (profile probes and neutron probes); near surface matric potential (tensiometers and equitensiometers); deep (>10m) matric potential (deep jacking tensiometers); and water table elevation (piezometers). Conventional treatment of recharge in Chalk aquifers considers a fixed bypass component of rainfall, normally 15%, to account for the role of the fractures. However, interpretation of the field data suggest three modes

  7. Nondestructive Methods to Characterize Rock Mechanical Properties at Low-Temperature: Applications for Asteroid Capture Technologies

    Science.gov (United States)

    Savage, Kara A.

    Recent government initiatives and commercial activities have targeted asteroids for in situ material characterization, manipulation, and possible resource extraction. Most of these activities and missions have proposed significant robotic components, given the risks and costs associated with manned missions. To successfully execute these robotic activities, detailed mechanical characteristics of the target space bodies must be known prior to contact, in order to appropriately plan and direct the autonomous robotic protocols. Unfortunately, current estimates of asteroid mechanical properties are based on limited direct information, and significant uncertainty remains specifically concerning internal structures, strengths, and elastic properties of asteroids. One proposed method to elucidate this information is through in situ, nondestructive testing of asteroid material immediately after contact, but prior to any manipulation or resource extraction activities. While numerous nondestructive rock characterization techniques have been widely deployed for terrestrial applications, these methods must be adapted to account for unique properties of asteroid material and environmental conditions of space. For example, asteroid surface temperatures may range from -100°C to 30°C due to diurnal cycling, and these low temperatures are especially noteworthy due to their deleterious influence on non-destructive testing. As a result, this thesis investigates the effect of low temperature on the mechanical characteristics and nondestructive technique responses of rock material. Initially, a novel method to produce low temperature rock samples was developed. Dry ice and methanol cooling baths of specific formulations were used to decrease rock to temperatures ranging from -60°C to 0°C. At these temperatures, shale, chalk, and limestone rock samples were exposed to several nondestructive and conventional mechanical tests, including Schmidt hammer, ultrasonic pulse velocity, point

  8. Protecting coastal abstraction boreholes from seawater intrusion using self-potential data

    Science.gov (United States)

    Graham, Malcolm; Butler, Adrian; MacAllister, Donald John; Vinogradov, Jan; Ijioma, Amadi; Jackson, Matthew

    2016-04-01

    We investigate whether the presence and transport of seawater can influence self-potentials (SPs) measured within coastal groundwater boreholes, with a view to using SP monitoring as part of an early warning system for saline intrusion. SP data were collected over a period of 18 months from a coastal groundwater borehole in the fractured Chalk of England. Spectral analysis of the results shows semi-diurnal fluctuations that are several orders of magnitude higher than those observed from monitoring of the Chalk more than 60 km inland, indicating a strong influence from oceanic tides. Hydrodynamic and geoelectric modelling of the coastal aquifer suggests that observed pressure changes (giving rise to the streaming potential) are not sufficient to explain the magnitude of the observed SP fluctuations. Simulation of the exclusion-diffusion potential, produced by changes in concentration across the saline front, is required to match the SP data from the borehole, despite the front being located some distance away. In late summer of 2013 and 2014, seawater intrusion occurred in the coastal monitoring borehole. When referenced to the shallowest borehole electrode, there was a characteristic increase in SP within the array, several days before any measurable increase in salinity. The size of this precursor increased steadily with depth, typically reaching values close to 0.3 mV in the deepest electrode. Numerical modelling suggests that the exclusion-diffusion potential can explain the magnitude of the precursor, but that the polarity of the change in SP cannot be replicated assuming a homogeneous aquifer. Small-scale models of idealised Chalk blocks were used to simulate the effects of discrete fractures on the distribution of SP. Initial results suggest that comparatively large reductions in voltage can develop in the matrix ahead of the front, in conjunction with a reduced or absent precursor in the vicinity of a fracture. Geophysical logging indicates the presence of a

  9. Physical properties, chemical composition, sources, spatial distribution and sinks of indoor aerosol particles in a university lecture hall

    Science.gov (United States)

    Salma, I.; Dosztály, K.; Borsós, T.; Söveges, B.; Weidinger, T.; Kristóf, G.; Péter, N.; Kertész, Zs.

    2013-01-01

    PM10 mass, particle number (N) and CO2 concentrations, particle number size distributions and meteorological parameters were determined with high time resolution, and daily aerosol samples were collected in the PM10-2.0 and PM2.0 size fractions for chemical analysis in the middle of a university lecture hall for one week. Median concentrations for the PM10 mass and N of 15.3 μg m-3 and 3.7 × 103 cm-3, respectively were derived. The data are substantially smaller than the related outdoor levels or typical values for residences. There were considerable concentration differences for workdays, weekends and various lectures. Main sources of PM10 mass include the usage of chalk sticks for writing, wiping the blackboard, ordinary movements and actions of students and cleaning. High PM10 mass concentration levels up to 100 μg m-3 were realised for short time intervals after wiping the blackboard. The mass concentrations decreased rapidly after the emission source ceased to be active. Two classes of coarse particles were identified. General indoor dust particles exhibited a residence time of approximately 35 min, while the residence time for the chalk dust particles was approximately 20 min as lower estimates. Emission source rate for wiping the blackboard was estimated to be between 8 and 14 mg min-1. This represents a substantial emission rate but the source is active only up to 1 min. Suspension of the chalk (made mainly of gypsum) dust particles was confirmed by enrichment of Ca and S in the hall with respect to ambient urban aerosol. Contribution of ambient aerosol via the heating, ventilation and air conditioning (HVAC) facility was considerable for time intervals when the indoor sources of PM10 mass were not intensive. The HVAC facility introduces, however, the major amount of aerosol particles from the outdoors as far as their number concentration is regarded. Mean contribution of ultrafine particles to the total particle number was (69 ± 7)%, which is smaller

  10. Catchment scale tracer testing from karstic features in a porous limestone

    Science.gov (United States)

    Maurice, L.; Atkinson, T. C.; Williams, A. T.; Barker, J. A.; Farrant, A. R.

    2010-07-01

    SummaryTracer testing was undertaken from sinking streams feeding the Chalk, a porous limestone aquifer characterised by frequent small-scale surface karst features. The objective was to investigate the nature and extent of sub-surface karstic development in the aquifer. Previous tracer testing has demonstrated rapid flow combined with low attenuation of tracer. In this study, at two sites rapid groundwater flow was combined with very high attenuation and at two other sites no tracer was detected at springs within the likely catchment area of the stream sinks tested, suggesting that tracer was totally attenuated along the flowpath. It is proposed that the networks beneath stream sinks in the Chalk and other mildly karstic aquifers distribute recharge into multiple enlarged fractures that divide and become smaller at each division whereas the networks around springs have a predominantly tributary topology that concentrates flow into a few relatively large cavities, a morphology with similarities to that of the early stages of karstification. Tracer attenuation is controlled by the degree to which the two networks are directly connected. In the first state, there is no direct linkage and flow between the two networks is via primary fractures in which tracer attenuation is extreme. The second state is at a percolation threshold in which a single direct link joins the two networks. A very small proportion of tracer reaches the spring rapidly but overall attenuation is very high. In the third state, the recharge and discharge networks are integrated therefore a large fraction of tracer reaches the spring and peak concentrations are relatively high. Despite the large number of stream sinks that recharge the Chalk aquifer, these results suggest that sub-surface conduit development may not always be continuous, with flow down smaller fissures and fractures causing high attenuation of solutes and particulates providing a degree of protection to groundwater outlets that is

  11. Variable pattern contamination control under positive pressure

    Energy Technology Data Exchange (ETDEWEB)

    Philippi, H.M. [Chalk River Labs., Ontario (Canada)

    1997-08-01

    Airborne contamination control in nuclear and biological laboratories is traditionally achieved by directing the space ventilation air at subatmospheric pressures in one fixed flow pattern. However, biological and nuclear contamination flow control in the new Biological Research Facility, to be commissioned at the Chalk River Laboratories in 1996, will have the flexibility to institute a number of contamination control patterns, all achieved at positive (above atmospheric) pressures. This flexibility feature, made possible by means of a digitally controlled ventilation system, changes the facility ventilation system from being a relatively rigid building service operated by plant personnel into a flexible building service which can be operated by the facility research personnel. This paper focuses on and describes the application of these unique contamination control features in the design of the new Biological Research Facility. 3 refs., 7 figs.

  12. Piltdown Man: Combining the Instruction of Scientific Ethics and Qualitative Analysis

    Science.gov (United States)

    Vincent, John B.

    1999-11-01

    In combination with lectures on scientific method and the problems of scientific misconduct in a freshman chemistry course at The University of Alabama, a laboratory experiment was developed to allow students to feel some of the sense of scientific discovery associated with the exposure of the Piltdown Man fraud. This is accomplished by modifying a commonly performed freshman chemistry laboratory experiment, qualitative analysis of group III metal ions. Pieces of chalk are treated with chromium, manganese, and iron to simulate the treatment used to forge the Piltdown "fossils"; students can use techniques in qualitative analysis schemes for the group III ions to determine whether the samples are "forgeries" and if so which metal ion(s) were used.

  13. Towards a representative periphytic diatom sample

    Directory of Open Access Journals (Sweden)

    2007-01-01

    Full Text Available The need to acquire a representative periphytic diatom sample for river water quality monitoring has been recognised in the development of existing diatom indices, important in the development and employment of diatom monitoring tools for the Water Framework Directive. In this study, a nested design with replication is employed to investigate the magnitude of variation in diatom biomass, composition and Trophic Diatom Index at varying scales within a small chalk river. The study shows that the use of artificial substrates may not result in diatom communities that are typical of the surrounding natural substrates. Periphytic diatom biomass and composition varies between artificial and natural substrates, riffles and glides and between two stretches of the river channel. The study also highlights the existence of high variation in diatom frustule frequency and biovolume at the individual replicate scale which may have implications for the use of diatoms in routine monitoring.

  14. FACTAR 2.0 code validation

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, P.B.; Rock, R.C.K.; Wadsworth, S.L. [Ontario Hydro, Reactor Safety and Operational Analysis Dept., Toronto, Ontario (Canada)

    1997-07-01

    The FACTAR code models the thermal and mechanical behaviour of a CANDU fuel channel under degraded cooling conditions. FACTAR is currently undergoing a process of validation against various data sets in order to qualify its use in nuclear safety analysis. This paper outlines the methodology being followed in this effort. The BTF-104 and BTF-105A tests, conducted at Chalk River Laboratories, have been chosen as the first in reactor tests to be used for FACTAR validation. The BTF experiments were designed to represent CANDU fuel behaviour under typical large LOCA conditions. The two tests are summarized briefly, and the results of code comparisons to experimental data are outlined. The comparisons demonstrate that FACTAR is able to accurately predict the values of selected key parameters. As anticipated in the validation plan, further work is required to fully quantify simulation biases for all parameters of interest. (author)

  15. The risk of shortage of radioelements at medical use must not lead to overlook the reactors safety that produce them; Le risque de penurie de radioelements a usage medical ne doit pas conduire a faire l'impasse sur la surete des reacteurs qui les produisent

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    As the reactors supplying the world production of radioelements for medical use have over 40 years of operation, the nuclear safety authority alerts the stake holders on the necessity to prevent the conflicts between public health and nuclear safety in the production of these elements; Asn estimates that the solution is not to extend the lifetime of the reactors but goes for a new international concerted approach. The most of the present production comes from five old reactors: N.R.U. at Chalk river (Canada, 40%), H.F.R. at Petten (Netherlands, 30%), Safari at Pelindaba (South Africa, 10%) B.R.2 at Mol (Belgium, 9%) and Osiris at Saclay (France, 5%). In this context, Asn organised in january 2009 a seminar on the safety-availability of facilities of radio-isotopes production with safety authorities of the concerned countries. Nea organised a seminar on the radiopharmaceuticals supply at the end of january 2009. (N.C.)

  16. Integrated plant for treatment of liquid radwaste

    Energy Technology Data Exchange (ETDEWEB)

    Sen Gupta, S.K. [Chalk River Laboratories, Ontario (Canada)

    1995-05-01

    In the early 1980`s, AECL Research, at its Chalk River Laboratories (CRL) site, built a Waste Treatment Centre for managing low-level radioactive aqueous liquid wastes. At present, two industrial liquid waste streams are being routinely treated. One stream originates from the central Decontamination Centre (DC), where reactor components, protective plastic clothing, and respirators are cleaned. The other Active Drain (AD) stream is produced from a large and diverse number of research laboratories and radioisotope production facilities. The two waste streams, totalling about 2500 m per year (0.66 million US gallons), are volume reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO), and tubular reverse osmosis (TRO) membrane technologies; two thin-film evaporators (TFE) are employed for (i) the final volume reduction step, and (ii) the subsequent solidification of evaporator bottom with bitumen for containment of the radioactivity.

  17. ZEEP: Canada's first nuclear reactor

    Energy Technology Data Exchange (ETDEWEB)

    Green, R.E.; Okazaki, A. [retired, Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2015-09-15

    In 1905 Albert Einstein published his historic paper on special relativity, which contained the equation E=mc 2. The significance of this mass-energy relationship became evident with the discovery of nuclear fission in 1939, when it was realized that large amounts of energy would be released in a fission chain reaction. Canadian scientists were involved in this field from the beginning and their efforts resulted in the startup in September 1945 of the ZEEP reactor at Chalk River, the first reactor to go critical outside the USA. In this paper we recall some of the events that led to the construction of ZEEP, and describe the role it played in the development of the Canadian nuclear energy program. (author)

  18. The Painleve paradox in contact mechanics

    CERN Document Server

    Champneys, Alan R

    2016-01-01

    The 120-year old so-called Painleve paradox involves the loss of determinism in models of planar rigid bodies in point contact with a rigid surface, subject to Coulomb-like dry friction. The phenomenon occurs due to coupling between normal and rotational degrees-of-freedom such that the effective normal force becomes attractive rather than repulsive. Despite a rich literature, the forward evolution problem remains unsolved other than in certain restricted cases in 2D with single contact points. Various practical consequences of the theory are revisited, including models for robotic manipulators, and the strange behaviour of chalk when pushed rather than dragged across a blackboard. Reviewing recent theory, a general formulation is proposed, including a Poisson or energetic impact law. The general problem in 2D with a single point of contact is discussed and cases or inconsistency or indeterminacy enumerated. Strategies to resolve the paradox via contact regularisation are discussed from a dynamical systems po...

  19. A particle assembly/constrained expansion (PACE) model for the formation and structure of porous metal oxide deposits on nuclear fuel rods in pressurized light water reactors

    Science.gov (United States)

    Brenner, Donald W.; Lu, Shijing; O'Brien, Christopher J.; Bucholz, Eric W.; Rak, Zsolt

    2015-02-01

    A new model is proposed for the structure and properties of porous metal oxide scales (aka Chalk River Unidentified Deposits (CRUD)) observed on the nuclear fuel rod cladding in Pressurized Water Reactors (PWR). The model is based on the thermodynamically-driven expansion of agglomerated octahedral nickel ferrite particles in response to pH and temperature changes in the CRUD. The model predicts that porous nickel ferrite with internal {1 1 1} surfaces is a thermodynamically stable structure under PWR conditions even when the free energy of formation of bulk nickel ferrite is positive. This explains the pervasive presence of nickel ferrite in CRUD, observed CRUD microstructures, why CRUD maintains its porosity, and variations in porosity within the CRUD observed experimentally. This model is a stark departure from decades of conventional wisdom and detailed theoretical analysis of CRUD chemistry, and defines new research directions for model validation, and for understanding and ultimately controlling CRUD formation.

  20. Decrease in coccolithophore calcification and CO2 since the middle Miocene

    Science.gov (United States)

    Bolton, Clara T.; Hernández-Sánchez, María T.; Fuertes, Miguel-Ángel; González-Lemos, Saúl; Abrevaya, Lorena; Mendez-Vicente, Ana; Flores, José-Abel; Probert, Ian; Giosan, Liviu; Johnson, Joel; Stoll, Heather M.

    2016-01-01

    Marine algae are instrumental in carbon cycling and atmospheric carbon dioxide (CO2) regulation. One group, coccolithophores, uses carbon to photosynthesize and to calcify, covering their cells with chalk platelets (coccoliths). How ocean acidification influences coccolithophore calcification is strongly debated, and the effects of carbonate chemistry changes in the geological past are poorly understood. This paper relates degree of coccolith calcification to cellular calcification, and presents the first records of size-normalized coccolith thickness spanning the last 14 Myr from tropical oceans. Degree of calcification was highest in the low-pH, high-CO2 Miocene ocean, but decreased significantly between 6 and 4 Myr ago. Based on this and concurrent trends in a new alkenone εp record, we propose that decreasing CO2 partly drove the observed trend via reduced cellular bicarbonate allocation to calcification. This trend reversed in the late Pleistocene despite low CO2, suggesting an additional regulator of calcification such as alkalinity.

  1. A forward modeling approach for interpreting impeller flow logs.

    Science.gov (United States)

    Parker, Alison H; West, L Jared; Odling, Noelle E; Bown, Richard T

    2010-01-01

    A rigorous and practical approach for interpretation of impeller flow log data to determine vertical variations in hydraulic conductivity is presented and applied to two well logs from a Chalk aquifer in England. Impeller flow logging involves measuring vertical flow speed in a pumped well and using changes in flow with depth to infer the locations and magnitudes of inflows into the well. However, the measured flow logs are typically noisy, which leads to spurious hydraulic conductivity values where simplistic interpretation approaches are applied. In this study, a new method for interpretation is presented, which first defines a series of physical models for hydraulic conductivity variation with depth and then fits the models to the data, using a regression technique. Some of the models will be rejected as they are physically unrealistic. The best model is then selected from the remaining models using a maximum likelihood approach. This balances model complexity against fit, for example, using Akaike's Information Criterion.

  2. [Infrared spectroscopic studies of the effect of hydrotalcite on the capability of agricultural film].

    Science.gov (United States)

    Wang, Liang-yu; Cui, Hai-long; Jiao, Hong-wen

    2007-02-01

    Different kinds of hydrotalcite and their effects on the optic capability, transmittance, infrared anti-transmittance and heat preservation of agriculture film were studied by IR spectroscopy. It was found that the haze degree of the film decreased about 1.5% because the diameter of the hydrotalcite made in Dalian was bigger than those made in Japan. Compared to the french chalk, the hydrotalcite had much better capability of infrared anti-transmittance. But from the spectra of hydrotalcite, whichever made in Dalian or in Japan, there was no infrared absorption in the region of 1100-1200 cm(-1). Compared with the wavelength of 9-11 microm, the absorbance band at 1360 cm(-1) had a little shift. Hence, the capability of heat preservation of hydrotalcite-added agriculture film would be studied in the future work.

  3. Advances in inspection automation

    Science.gov (United States)

    Weber, Walter H.; Mair, H. Douglas; Jansen, Dion; Lombardi, Luciano

    2013-01-01

    This new session at QNDE reflects the growing interest in inspection automation. Our paper describes a newly developed platform that makes the complex NDE automation possible without the need for software programmers. Inspection tasks that are tedious, error-prone or impossible for humans to perform can now be automated using a form of drag and drop visual scripting. Our work attempts to rectify the problem that NDE is not keeping pace with the rest of factory automation. Outside of NDE, robots routinely and autonomously machine parts, assemble components, weld structures and report progress to corporate databases. By contrast, components arriving in the NDT department typically require manual part handling, calibrations and analysis. The automation examples in this paper cover the development of robotic thickness gauging and the use of adaptive contour following on the NRU reactor inspection at Chalk River.

  4. What is the essential neurological examination?

    Directory of Open Access Journals (Sweden)

    Marco A. Lima

    2012-12-01

    Full Text Available In order to determine which aspects would be essential to the neurological examination (NE in a given specific situation (a patient referred with a potential neurological complaint, but the history suggests that a neurological problem is unlikely, we presented the same questionnaire used by Moore and Chalk in Canada to 19 neurologists in Rio de Janeiro, Brazil. We considered significant aspects of NE, whose average responses were greater than or equal to 3.5: visual fields, fundoscopy, pursuit eye movements, facial muscle power testing, gait, pronator drift or rapid arm movement in upper limbs, finger-nose, tone in arms and legs, five tendon reflexes, and plantar responses. We concluded that, despite geographical and economical differences between Brazil and Canada, neurologists from both countries agree about the essential NE in the proposed scenario.

  5. Petrophysical and rock-mechanics effects of CO2 injection for enhanced oil recovery

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged

    2014-01-01

    reservoirs. North Sea chalk is characterized by high porosity but also high specific surface causing low permeability. A high porosity provides room for CO2 storage, while a high specific surface causes a high risk for chemical reaction and consequently for mechanical weakening. In order to address...... to the injection of CO2 at supercritical state. We analyzed these changes with respect to the differences in porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical strength. We observed a 2–3% increase in porosity, a minor decrease of specific surface and consequently a small increase...... in permeability. A decrease in elastic stiffness is indicated by an increase of Biot׳s effective stress coefficient (α) by 1–2%. Nuclear Magnetic Resonance (NMR) data indicated no change in wettability and the samples remained water wet. We found that the effect of CO2 injection on both petrophysical...

  6. Mediated Teaching for Information Presenting and Understanding

    Directory of Open Access Journals (Sweden)

    Konstantinas Danaitis

    2011-04-01

    Full Text Available Nowadays media is readily moving into various spheres of life. The computer, projector and screen replace trivial chalk and board. Slides are used in various designated areas: promotional presentations at meetings as a form of communication between participants and also as visual presentation of lecture material content of the report. It was found that a human catches up and remembers only about 10% of what he has read, 20% of what he has heard and even 50% of what he heard and saw. Therefore, high-quality and Professional presentation of information in the slide form has a significant impact on the uptake. The authors present a solution how to present the study material qualitatively and use the media system effectively for teaching computer graphics course. This course is taught for VGTU first or second year students of almost all specialities. This presentation of study materials facilitates the teacher's work and improves the readability and solutions of study materials.

  7. Mapping radon-prone areas - a geophysical approach

    Energy Technology Data Exchange (ETDEWEB)

    Shirav, M. [Geological Survey of Israel, Jerusalem (Israel); Vulkan, U. [Soreq Nuclear Research Center, Yavne (Israel)

    1997-06-01

    Radon-prone areas in Israel were mapped on the basis of direct measurements of radon ({sup 222}Rn) in the soil/rock gas of all exposed geological units, supported by the accumulated knowledge of local stratigraphy and sub-surface geology. Measurements were carried out by a modified alpha-track detection system, resulting in high radon levels mainly in rocks of the Senonian-Paleocene-aged Mount Scopus Group, comprised of chert-bearing marly chalks, rich in phosphorite which acts as the major uranium source. Issues of source depth, seasonal variations and comparison with indoor radon levels are addressed as well. This approach could be applied to other similar terrains, especially the Mediterranean Phosphate Belt. (orig.)

  8. Minimal invasive control of paintings cleaning by LIBS

    Science.gov (United States)

    Staicu, A.; Apostol, I.; Pascu, A.; Urzica, I.; Pascu, M. L.; Damian, V.

    2016-03-01

    In cultural heritage restoration and conservation, it has been proved that LIBS is an appropriate technique for pigments identification, analysis of multilayered paintings, and quantitative analysis of ancient materials. Generally, experiments involving the use of laser for paint cleaning and LIBS in order to identify the composition of the removed material are made. Here, we report LIBS studies on mastic and dammar varnishes removal using visible (532 nm) and UV (266 nm) laser pulses (5 ns) with fluences in the range 0.6-4.4 J/cm2. The studied varnish layers were on-purpose painted on glass supports or were part of several mock-up samples having dammar or mastic as final layer - gold foil, yellow ochre or cobalt blue egg tempera as painting layer - chalk or acrylic ground as link to an wooden support. LIBS was used to monitor the laser induced stepwise selective removal of the layers and to analyze their composition.

  9. Pica responding to SSRI: an OCD spectrum disorder?

    Science.gov (United States)

    Bhatia, Manjeet S; Gupta, Ravi

    2009-01-01

    Pica is a common disorder in childhood, however, in adults it is associated with mental retardation, psychosis and pregnancy. A few case reports have described it being associated with obsessive compulsive disorder in adults. We describe the case of an adult female patient who developed an impulse to ingest chalk only in stressful situations. These thoughts were ego-dystonic and kept on hammering her mind until she ate it. She was diagnosed as having Major Depressive Disorder with relational problems and pica. We prescribed her escitalopram with clonazepam and asked her to ventilate her feelings during stressful situations. Her depression improved within three weeks, with remarkable improvement in pica symptoms. We concluded that stress may induce the pica in some adults and that such feelings have impulsive/compulsive characters. In addition, appropriate management of stress may help to alleviate the symptoms of pica.

  10. How to set the language context

    Institute of Scientific and Technical Information of China (English)

    高淑玲

    2007-01-01

    <正>A.Use all kinds of teaching aids In the classroom,students should be provided with a chance to experience the language in meaningful ways and try out their skills,so the teachers should try to use all kinds of teaching aids to set the language context for the students.And we should not only be acquainted with the use of flash cards and wall pictures,but also we need to learn to collect and make visual aids,such as pictures from magazines,used objects like can and boxes,flannel board,and stick-figures.So with a piece of chalk,objects,people,animals,settings are created on the blackboard and the students’interest and attention are aroused.

  11. Efficient data analysis and travel time picking methods for crosshole GPR experiments

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Moreau, Julien; Nielsen, Lars

    2013-01-01

    to the source position, and the vertical axis to the travel time. Using OpendTect (dGB Earth Sciences), this data cube is then displayed and inspected in a 3D environment, which allows for effective and efficient data analysis. Quality control and data editing of the individual transmitter gathers can be rapidly......-attribute analyses. We believe that this approach to 3D representation and analysis of GPR crosshole data greatly improves consistency in travel time picking and reduces the time needed for the picking process. Moreover, the approach is well suited for generation of high quality input data for tomographic inversion...... methods. Future time-lapse GPR studies of different types of chalk aim at characterizing the flow characteristics of these economically important lithologies. In the framework of the current study, we have collected new crosshole GPR data from a site located in a former quarry in Eastern Denmark, where...

  12. Preparation of calcium sulphoaluminate cement using fertiliser plant wastes.

    Science.gov (United States)

    Singh, Maneesh; Kapur, P C; Pradip

    2008-08-30

    Phosphochalks from fertiliser plants contain significant amount of calcium sulphate along with P(2)O(5) and fluorine. The presence of these impurities makes them unsuitable for most applications and, hence its availability in millions of tons. We demonstrate that it is possible to prepare calcium sulphoaluminate-aluminoferrite based special cements having strength values comparable to ordinary Portland cement (OPC) using these waste chalks. Such cements are insensitive to the presence of impurities in the raw mixture, clinker at low temperatures (1,230 degrees C) and the clinkers produced are soft and friable. An empirical technique has been developed to predict the phase composition of the clinkers given the chemical composition of the starting raw mixture. The proposed low temperature clinkering route appears to be a promising method for converting waste phosphochalks into construction grade cements.

  13. Horizontal oil well applications and oil recovery assessment. Volume 2: Applications overview, Final report

    Energy Technology Data Exchange (ETDEWEB)

    Deskins, W.G.; McDonald, W.J.; Knoll, R.G.; Springer, S.J.

    1995-03-01

    Horizontal technology has been applied in over 110 formations in the USA. Volume 1 of this study addresses the overall success of horizontal technology, especially in less-publicized formations, i.e., other than the Austin Chalk, Bakken, and Niobrara. Operators in the USA and Canada were surveyed on a formation-by-formation basis by means of a questionnaire. Response data were received describing horizontal well projects in 58 formations in the USA and 88 in Canada. Operators` responses were analyzed for trends in technical and economic success based on lithology (clastics and carbonates) and resource type (light oil, heavy oil, and gas). The potential impact of horizontal technology on reserves was also estimated. A forecast of horizontal drilling activity over the next decade was developed.

  14. EL USO DE SITUACIONES-PROBLEMA PARA LA ENSEÑANZA SUPERIOR DE ISOMERIA EN LA QUÍMICA INORGÁNICA

    Directory of Open Access Journals (Sweden)

    Jose E. Simões Neto

    2013-01-01

    Full Text Available This study investigated the understanding of isomerism by students of Bachellor degree in Chemistry exposed to a situation-problem (SP teaching approach. The methodology involved the following stages: elaboration of two SPs as proposed by Meirieu; creation of a text and selection of molecular models for spatial visualization of the chemical structures; students’ written reports respect to SPs and an interview with some of the students. Experience, in terms of development and use of SPs, demonstrated their potential in the teaching of isomerism, for both conceptual training and to modification of traditional view (teaching by transmission-reception that predominates at university-level chemistry teaching, which is commonly restricted to the whiteboard, transparencies, chalk and markers.

  15. Integrated geophysical interpretation of the Valhall 4C OBS survey

    Energy Technology Data Exchange (ETDEWEB)

    Thomsen, Leon A.; Barkved, Olav I; Mueller, Michael C.; Haggard, Bill W.; Kommedal, Jan H.; Rosland, Boerge O.

    1998-12-31

    This presentation gives a brief classic example of a North Sea reservoir which cannot be imaged by conventional P-wave techniques. In two-dimensional P-wave sections, extending across the crest of the structure, the top of the chalk reservoir is depressed in time, and has low amplitude and coherency so that even its identification is uncertain. The classical interpretation of these effects is that, over geologic time, gas has leaked from the reservoir into the overburden, in the zone above the reservoir. This gas, while present in uneconomic concentrations, has the effect of lowering seismic velocities and increasing seismic attenuation. Efficient methods of seismic surveying were used for oil prediction in the reservoir. 6 refs.

  16. New Green Polymeric Composites Based on Hemp and Natural Rubber Processed by Electron Beam Irradiation

    Directory of Open Access Journals (Sweden)

    Maria-Daniela Stelescu

    2014-01-01

    Full Text Available A new polymeric composite based on natural rubber reinforced with hemp has been processed by electron beam irradiation and characterized by several methods. The mechanical characteristics: gel fraction, crosslink density, water uptake, swelling parameters, and FTIR of natural rubber/hemp fiber composites have been investigated as a function of the hemp content and absorbed dose. Physical and mechanical properties present a significant improvement as a result of adding hemp fibres in blends. Our experiments showed that the hemp fibers have a reinforcing effect on natural rubber similar to mineral fillers (chalk, carbon black, silica. The crosslinking rates of samples, measured using the Flory-Rehner equation, increase as a result of the amount of hemp in blends and the electron beam irradiation dose increasing. The swelling parameters of samples significantly depend on the amount of hemp in blends, because the latter have hydrophilic characteristics.

  17. Lacquerware Pigment Identification with Fixed and Mobile Raman Microspectrometers: A Potential Technique to Differentiate Original/Fake Artworks

    Directory of Open Access Journals (Sweden)

    Philippe Colomban

    2013-07-01

    Full Text Available (FT Raman spectroscopy is used for the first time to identify pigments used in 19th & 20th century Japanese and Vietnamese Lacquerwares. IR spectroscopy is used to assess the Lacquer matrix. Different operative conditions and parameters were experimented with on a limited number of lacquerwares in order to determine the optimal procedure for the identification of pigments/dyes as potential chronological or technological markers. The test was then performed in the collector’s rooms with a mobile Raman set-up. Different pigments (vermilion, Prussian Blue, Naples Yellow, Phtalocyanine Blue, anatase, rutile, chalk, carbon black were identified despite a strong fluorescence and a rapid degradation of both pigments and binder under increasing laser power. Better spectra were obtained on older lacquerwares.

  18. AECL hot-cell facilities and post-irradiation examination services

    Energy Technology Data Exchange (ETDEWEB)

    Schankula, M.H.; Plaice, E.L. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada); Woodworth, L.G. [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada)

    1998-04-01

    This paper presents an overview of the post-irradiation examination (PIE) services available at AECL's hot-cell facilities (HCF). The HCFs are used primarily to provide PIE support for operating CANDU power reactors in Canada and abroad, and for the examination of experimental fuel bundles and core components irradiated in research reactors at the Chalk River Laboratories (CRL) and off-shore. A variety of examinations and analyses are performed ranging from non-destructive visual and dimensional inspections to detailed optical and scanning electron microscopic examinations. Several hot cells are dedicated to mechanical property testing of structural materials and to determine the fitness-for-service of reactor core components. Facility upgrades and the development of innovative examination techniques continue to improve AECL's PIE capabilities. (author)

  19. Experimental studies of low salinity water flooding in carbonate reservoirs: A new promising approach

    DEFF Research Database (Denmark)

    Zahid, Adeel; Shapiro, Alexander; Skauge, Arne

    2012-01-01

    additional oil recovery can be achieved when successively flooding composite carbonate core plugs with various diluted versions of seawater. The experimental data on carbonates is very limited, so more data and better understanding of the mechanisms involved is needed to utilize this method for carbonate...... reservoirs. In this paper, we have experimentally investigated the oil recovery potential of low salinity water flooding for carbonate rocks. We used both reservoir carbonate and outcrop chalk core plugs. The flooding experiments were carried out initially with the seawater, and afterwards additional oil...... of experimental results, discussions are made about possible mechanisms for improving oil recovery in carbonate reservoir as a function of change in brine salinity. Copyright 2012, Society of Petroleum Engineers....

  20. Grain coarsening of calcite: Fundamental mechanisms and biogenic inhibition

    DEFF Research Database (Denmark)

    Schultz, Logan Nicholas

    In a saturated solution, submicrometer calcite (CaCO3) crystals recrystallize and coarsen to minimize surface area. The thermodynamic driving force is described by the Gibbs-Thomson equation, but the rates and mechanism are poorly understood. Calcite grain coarsening has many implications...... in industry and nature, but the specific focus of this research project was to understand how small, biogenic calcite particles in chalk have resisted grain coarsening for over 60 million years in saturated reservoir fluids. A new method was developed to produce pure calcite powder that has submicrometer...... coarsening – small grains coarsen by aggregation at high temperatures, followed by Ostwald ripening. Alginate, a model for the acidic polysaccharides produced by coccolithiphores, inhibited coarsening at a steady rate. A Pseudomonas aeruginosa biofilm preserved particles for at least 60 days before...

  1. Experimental research on the behavior of the pneumatic transport of fine-grained iron

    Science.gov (United States)

    Andrei, V.; Hritac, M.; Constantin, N.; Dobrescu, C.

    2017-01-01

    Mixed injection of fine-grained iron ore and pulverized coal in the furnace, involves determining the behavior of these materials during pneumatic transport in a dense state through the pipe and setting possibilities for adjusting the flow rate of material transported with the corresponding values of the process. Parameters of the pneumatic transport were determined for the main types of iron ore and chalk used in Arcelor Mittal Galati. Outside the intended purpose of injecting iron ore and flux, it was considered also the experimental check of the possibility for injecting ilmenite in the furnace for crucible protection purpose. The possibility of injecting cinder mill into the furnace was also considered. Injecting cinder could be taken into account for the recycling of ferrous waste in the furnace, also as additive for intensifying the combustion process around the tuyeres.

  2. Laboratory tests of a modified {sup 3}He detector for use with startup instrumentation

    Energy Technology Data Exchange (ETDEWEB)

    Qian, T.; Tonner, P.; Keller, N. [Atomic Eerngy of Canada Limited, Chalk River, ON (Canada)] [and others

    1997-07-01

    Boron trifluoride (BF{sub 3}) detectors are currently used in all CANDU stations as startup instrumentation (SUI) detectors for monitoring neutron flux during extended outages and startups. Experience at some CANDU stations has shown that some models of BF{sub 3} detectors degrade quickly, even in moderate neutron and gamma fields. Degradation and life expectancy tests for five models of BF{sub 3} detectors from different manufacturers were performed at Chalk River Laboratories (CRL) to investigate the problem. The test results reveal that most BF{sub 3} detectors have low neutron and gamma durability, and some exhibit an undesirable time-dependent degradation followed by recovery. As a result of this finding, other detector options including a modified helium ({sup 3}He) detector described herein were investigated. Modified {sup 3}He detectors were procured from an established supplier and were found to perform without degradation in neutron and gamma fields. (author)

  3. Drama in the classroom: fitness to practise.

    Science.gov (United States)

    Bates, Karen

    2013-01-01

    The fitness to practise hearing was brought to students at the University of East Anglia. The day was a mock up, as close to real events as possible, with interim orders and substantive hearings. It enabled students to engage with aspects of practice in a different way from the traditional 'chalk and talk' methods. The cases chosen reflected all disciplines. Electronic voting systems were used to determine what the students felt outcomes should have been, and then they had an opportunity to hear what outcome the panel decided upon. Evaluative data were obtained following the event to see what impact this approach had on students' learning and their appreciation of the importance of professional practice. The comments we received were overwhelmingly positive and as a result we shall be repeating the day for students, supervisors of midwives and post registration nurses and midwives.

  4. Self Regulation through Art and Chocolate

    Directory of Open Access Journals (Sweden)

    Lydia Royeen

    2015-04-01

    Full Text Available Josh Banks provided the cover art for the spring 2015 issue of The Open Journal of Occupational Therapy. The cover art is titled “Birthday Party” because the piece resembles images involved in a birthday party: multicolored balloons, napkins, cakes, and icing. Josh created the piece using oil crayons on watercolor paper. Josh is sensory seeking and has difficulty using various types of materials, which include crayons, street chalk, and markers. After much experimentation, Josh is able to use nibs, a type of marker that does not have a cap. Josh is able to sit for 5-10 minute periods and participate in his artistic endeavors. His normally bright and charming demeanor suddenly turns to one of concentration and focus on his work. He uses short, intense strokes in his artwork. Vicki, his mother, has noted seasonal undertones in some of Josh’s artwork and has named his pieces of art according to the season

  5. Hydro mechanical coupling for non linear behaviour laws. Application to petroleum problems; Couplage hydromecanique pour des lois de comportement non lineaires Application a des problemes petroliers

    Energy Technology Data Exchange (ETDEWEB)

    Longuemare, P.

    1996-11-28

    The aim of this study is to provide a better description of the rock contribution to fluid flows in sedimentary basins and petroleum reservoirs. After a study of the mechanical behaviour of high porosity chalks and shales, we present the elaboration of an elastoplastic constitutive model for the description of their behaviour under various strain and stress paths. This model is introduced in a coupled poro-mechanical approach and used to study the advantages of a good description of strain and stress paths in petroleum reservoirs and sedimentary basins studies. Hydro-mechanical modelling of the behaviour of petroleum reservoir allowed us to analyse the influence of boundary limit conditions on stress paths recovery rates. The study of sedimentary basins showed the importance of the consideration of the evolution of the porosity with time due to the time-scale difference between the laboratory and the field data. (author) 58 refs.

  6. Biology and Medicine Division annual report, 1985

    Energy Technology Data Exchange (ETDEWEB)

    1986-04-01

    This book briefly describes the activities of the Biology and Medicine Division of the Lawrence Berkeley Laboratory. During the past year the Donner Pavilion program on the treatment of arteriovenous malformations in the brain has chalked up very significant successes. The disease control rate has been high and objective measures of success using cerebral angiography have been established. The new high resolution positron emitting tomographic imager has been demonstrated to operate successfully. In the Radiation Biophysics program, the availability of higher mass ions up to uranium has allowed us cell and tissue studies in a radiation domain that is entirely new. Using uranium beams, investigators have already made new and exciting findings that are described in the body of the report.

  7. Installation Restoration Program. Phase 1 - Records Search, Robins AFB, Georgia.

    Science.gov (United States)

    1982-04-01

    users$ gravel -Used I a pit of water 172 6 Coarse whaite sand *1?? 5 Chalk and gravel 4,0 1 %a I Ilr Is? leone 6"".1 . . 215 .1 Coarse whtet 8"ad (1...t;10 L £ t in. PW I ’I 9 ft._______ _ TESI DAlI A AIR LINI.S . 1) ,,IS J’Clt(AII I. W #- I cpi..CI P wping l ev l T n~ I ~(l~ 9es NF,1A~~~. WELL...The direction or movement of ground water and any contaminants that may be contained therein, as governed principally by the hydraulic gra- dient

  8. Comparison Between Different Teaching Methods to Increase Performance of Students in Biochemistry

    Directory of Open Access Journals (Sweden)

    Mrinal Pal

    2014-08-01

    RESULTS: The results of the study showed that as per the subjective assessment of the lectures concern, students preferred PPT teaching the most. As far as the students and #8217; performance was concerned the impact of traditional Chalk and Talk teaching was more than the lectures using transparency and overhead projector (TOHP and PowerPoint presentations (PPT. But when supplementing chalkboard with PPT or TOHP, the enhancement of the student and #8217;s preference and performance was much better. This fact was true about teacher and #8217;s preference also. CONCLUSION: This observation may probably be due to the fact that, inherent deficiency of each teaching aid was compensated by the other. With regard to teaching method, the combination of teaching methods was more effective when compared to didactic lectures. [TAF Prev Med Bull 2014; 13(4.000: 281-288

  9. Insights into Contaminant Leaching Through An Intensive Field Monitoring Program

    Science.gov (United States)

    Keim, D.; Ireson, A. M.; Ali, M.; Steele, C.; Penrod, D.

    2014-12-01

    Risks to groundwater quality from mobile contaminants in the unsaturated zone associated with active or legacy mines present significant challenges for land managers and policy makers worldwide. Unsaturated zone flow processes are a dominant control on contaminant loading. However, the presence of unsaturated zone heterogeneity results in spatially and temporally variable flow pathways, due to capillary breaks and hydraulic barriers forming in various locations. This can result in the development of focused flow paths from where rapid contaminant transport to the water table may occur. In this study we designed an intensive monitoring program to attempt to characterise time-varying flow paths through a highly heterogeneous unsaturated zone through a dense network of combined soil moisture, electric conductivity and temperature probes. Estimations of surface fluxes and soil drainage along with observed water table response at a waste management site in Chalk River, Canada are presented providing insights into flow and transport processes.

  10. Caprock compressibility and permeability and the consequences for pressure development in CO2 storage sites

    DEFF Research Database (Denmark)

    Mbia, Ernest Ncha; Frykman, Peter; Nielsen, Carsten Møller;

    2014-01-01

    Large scale CO2 storage has previously been considered for the Vedsted structure located in the Northern part of Jylland in Denmark. Pressure buildup in the Gassum reservoir and transmission to the shallower Chalk Group where the brine-fresh water interface resides need to be investigated as part...... Formation from the samples measured. The sensitivity of pressure development for the caprock permeability has been studied by varying from one to three orders of magnitude higher and one to two orders of magnitude lower than the measured permeability of 0.1μD. Injecting 60 million tons (Mt) of CO2 at a rate...... study and the results indicate that higher overpressure is created in the reservoir and the caprock. Overestimating caprock compressibility can therefore underestimate overpressure within the storage and sealing formations and this can have significant implication in the presence of highly permeable...

  11. "Clay grounds” in Denmark: from soil to canvas

    DEFF Research Database (Denmark)

    Buti, David; Vila, Anna; Haack Christensen, Anne;

    Poster Presentation Abstract: “Clay grounds” in Denmark: from soil to canvas In the framework of the CATS’ project to study the painting technique and materials in Dutch and Danish 17th Century paintings, with a key interest on the materials, techniques and trade of artists’ practice in Denmark...... decorative scheme showed that at least two grounds from those paintings consist mainly of clay mixed with iron and magnesium-containing compounds. Furthermore, both SEM-EDX and µRaman measurements clearly highlighted the presence of a large amount of quartz particles. It is well known that clay is a sheet...... from Rembrandt’s workshop after 1640. Written sources from outside the Netherlands -such as Francisco Pacheco and Pierre Lebrun- mention this practice, also before Rembrandt's time. It was known that clay was cheaper than chalk or earth pigments and it gave more flexibility to the painting support...

  12. Ground water heat pumps and cooling with ground water basins as seasonal storage; Grundvandsvarmepumper og -koeling med grundvandsmagasiner som saesonlager

    Energy Technology Data Exchange (ETDEWEB)

    2008-04-15

    Ground water temperature is constant all the year round, in Denmark approximately 9 deg. C, which is ideal for a number of cooling purposes including cooling of buildings. The structures in which the ground water flows (sand, gravel and chalk) are efficient for storing coldness and heat over longer periods. By using seasonal storage of low-temperature heat and coldness in ground water layers close to the terrain it is feasible to reach profitable energy savings of up to 90% for cooling and heating of e.g. hotels, airports, shopping malls, office buildings and other larger buildings. At the same time the large energy savings means major reduction of CO{sub 2} emissions. (BA)

  13. New green polymeric composites based on hemp and natural rubber processed by electron beam irradiation.

    Science.gov (United States)

    Stelescu, Maria-Daniela; Manaila, Elena; Craciun, Gabriela; Dumitrascu, Maria

    2014-01-01

    A new polymeric composite based on natural rubber reinforced with hemp has been processed by electron beam irradiation and characterized by several methods. The mechanical characteristics: gel fraction, crosslink density, water uptake, swelling parameters, and FTIR of natural rubber/hemp fiber composites have been investigated as a function of the hemp content and absorbed dose. Physical and mechanical properties present a significant improvement as a result of adding hemp fibres in blends. Our experiments showed that the hemp fibers have a reinforcing effect on natural rubber similar to mineral fillers (chalk, carbon black, silica). The crosslinking rates of samples, measured using the Flory-Rehner equation, increase as a result of the amount of hemp in blends and the electron beam irradiation dose increasing. The swelling parameters of samples significantly depend on the amount of hemp in blends, because the latter have hydrophilic characteristics.

  14. Portable X-ray Fluorescence and Infrared Fluorescence Imaging Studies of Cadmium Yellow Alteration in Paintings by Edward Munch and Henri matisse in Oslo, Copenhagen, and San Francisco

    DEFF Research Database (Denmark)

    Mass, Jennifer; Uffelman, Erich; Buckley, Barbara

    2016-01-01

    of their chemical degradation, is of particular concern. The alteration of these pigments causes chalking, flaking, fading, and darkening of the yellow paints, leading to irreversible changes in the physical and chemical structure of the paint layer and dramatically altering the appearance of the work. Standoff...... of the pigment? Does it reliably discriminate among intact versus altered cadmium yellow pigments? To answer these questions, the methods were tested on Henri Matisse’s Le Bonheur de vivre (1905–1906, the Barnes Foundation, Philadelphia) and oil sketches for this work in the San Francisco Museum of Modern Art...... and the Statens Museum for Kunst, Copenhagen. They were also tested on Edvard Munch’s The Scream (ca. 1910?, Munch Museum, Oslo). It was found that ultraviolet-induced visible fluorescence has the best ability to discriminate between altered and unaltered cadmium yellow paints (even before alteration is visible...

  15. pXRF and IR Fluorescence Imaging Studies of CdS Alteration in Paintings by Edvard Munch and Henri Matisse in Oslo, Copenhagen, and San Francisco

    DEFF Research Database (Denmark)

    Vila, Anna; Wadum, Jørgen; Mass, Jennifer

    2014-01-01

    of their chemical degradation, is of particular concern. The alteration of these pigments causes chalking, flaking, fading, and darkening of the yellow paints, leading to irreversible changes in the physical and chemical structure of the paint layer, and dramatically altering the appearance of the work. Standoff...... it reliably discriminate among intact versus altered cadmium yellow pigments? To answer these questions, the methods were tested on Henri Matisse’s Le Bonheur de vivre (1905-6 The Barnes Foundation, Philadelphia) and oil sketches for this work in The Museum of Modern Art, San Francisco, and The Statens Museum...... for Kunst, Copenhagen. They were also tested on Edvard Munch’s The Scream (c. 1910, Munch Museum, Oslo). It was found that ultraviolet-induced visible fluorescence has the best ability to discriminate between altered and unaltered cadmium yellow paints (even before alteration is visible to the unaided eye...

  16. Fracturing tests on reservoir rocks: Analysis of AE events and radial strain evolution

    CERN Document Server

    Pradhan, S; Fjær, E; Stenebråten, J; Lund, H K; Sønstebø, E F; Roy, S

    2015-01-01

    Fracturing in reservoir rocks is an important issue for the petroleum industry - as productivity can be enhanced by a controlled fracturing operation. Fracturing also has a big impact on CO2 storage, geothermal installation and gas production at and from the reservoir rocks. Therefore, understanding the fracturing behavior of different types of reservoir rocks is a basic need for planning field operations towards these activities. In our study, the fracturing of rock sample is monitored by Acoustic Emission (AE) and post-experiment Computer Tomography (CT) scans. The fracturing experiments have been performed on hollow cylinder cores of different rocks - sandstones and chalks. Our analysis show that the amplitudes and energies of acoustic events clearly indicate initiation and propagation of the main fractures. The amplitudes of AE events follow an exponential distribution while the energies follow a power law distribution. Time-evolution of the radial strain measured in the fracturing-test will later be comp...

  17. Understanding the State of Quality of Software on the basis of Time Gap, Quality Gap and Difference with Standard Model

    Directory of Open Access Journals (Sweden)

    Ekbal Rashid

    2013-06-01

    Full Text Available This paper tries to introduce a new mathematical model to understand the state of quality of software by calculating parameters such as the time gap and quality gap with relation to some predefinedstandard software quality or in relation to some chalked out software quality plan. The paper also suggests methods to calculate the difference in quality of the software being developed and the modelsoftware which has been decided upon as the criteria for comparison. These methods can be employed to better understand the state of quality as compared to other standards. In order to obtain the graphical representation of data we have used Microsoft office 2007 graphical chart. Which facilitate easy simulation of time and quality gap.

  18. Full-length high-temperature severe fuel damage test No. 1

    Energy Technology Data Exchange (ETDEWEB)

    Rausch, W.N.; Hesson, G.M.; Pilger, J.P.; King, L.L.; Goodman, R.L.; Panisko, F.E.

    1993-08-01

    This report describes the first full-length high-temperature test (FLHT-1) performed by Pacific Northwest Laboratory (PNL) in the National Research Universal (NRU) reactor at Chalk River, Ontario, Canada. The test is part of a series of experiments being performed for the NRC as a part of their Severe Fuel Damage Program and is one of several planned for PNL`s Coolant Boilaway and Damage Progression Program. The report summarizes the test design and test plan. it also provides a summary and discussion of the data collected during the test and of the photos taken during the post-test examination. All objectives for the test were met. The key objective was to demonstrate that severe fuel damage tests on full-length fuel bundles can be safely conducted in the NRU reactor.

  19. Palaeoenvironment and Shark Evolution across the K/T-boundary on Southern Zealand

    DEFF Research Database (Denmark)

    Adolfssen, Jan Schulz

    The chondrichthyan faunal evolution across the Cretaceous/Tertiary-boundary, have been analysed from collected fossil shark teeth from Stevns Klint, Faxe Kalkbrud and a few other localities in Denmark. The teeth have been collected from the upper Maastrichtian Chalk, the K/T-boundary clay Fiskeler...... isotopes extracted from the shark teeth have revealed that the sea surface temperature fell slightly prior to the boundary and may have declined almost four degrees centigrade across the K/T-boundary. Subsequently the temperature rose during the deposition the upper layer of Fiskeler and the Cerithium...... Limestone. The striking fall in shark diversity prior to the boundary cannot be explained by a bolide impact and must have another explanation. This could have been caused by a sudden change in bathymetry. The calculated temperature range between sea surface and bottom water temperatures could suggest so...

  20. Photostability Characterization of Wood Polymer Composites of Polyvinyl Chloride and Rice Husk to Ultra-Violet Irradiation Exposure

    Directory of Open Access Journals (Sweden)

    Jais Farhana Hazwanee M.

    2016-01-01

    Full Text Available In this study, the photostability of wood polymer composites (WPC was assessed by using ultra-violet accelerated weathering test. Meanwhile, the mechanical properties of WPC show strength improvement at prolonged UV irradiation exposure with 43.21 MPa and maximum strain of 4.08 % at 5000 hours and 1000 hours UV irradiation exposure respectively. The colour stability of WPC was improved by addition of Ultraviolet (UV stabilizer during pre-mixing process which shows positive effect on the colour stability and prevented chalking of the composites for external use. Generally, discolourations of WPC during test exposure were caused by degradation of both wood and plastic. Therefore, incorporation with pigments and other additives gives improvement to the photostability of WPC. This is based on the increment of WPCs mechanical property while the morphological fracture surface of dumbbell test specimens revealed the pull out rice husk fiber which contributed to the distribution of load in the WPC samples.

  1. Progress report - Physical and Environmental Sciences - Physics Division, 1996 January 1 to December 31

    Energy Technology Data Exchange (ETDEWEB)

    Powell, B.M. (ed.)

    1997-04-01

    This document is the last Progress Report for the Neutron and Condensed Matter Science Branch, at Chalk River Labs of Atomic Energy of Canada Limited. The materials science program continued to include measurements of stress as a major component, but the determination of phase diagrams for specific alloys was also a prominent activity. Studies were made of two types of unusual magnetic materials. The magnetic properties of several oxide pyrochlore were investigated and spin waves were measured in the magnetic semiconductor, chalcopyrite. The crystal structures of the deuterated anti fluorite were determined and the reorientation of the ammonium ion was refined in detail. Differential scanning calorimetry measurements were used to investigate whether spontaneous phase separation into chiral domains occurs for mixtures of DPPC of opposite chirality. A new Neutron Velocity Selector was commissioned.

  2. Biot's coefficient as an indicator of strength and porosity reduction: Calcareous sediments from Kerguelen Plateau

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Borre, Mai Kirstine; Fabricius, Ida Lykke;

    2010-01-01

    Biot's coefficient, β. In calcareous ooze, β is one. Mechanical compaction reduces porosity, but only leads to a minor decrease in β. Recrystallization renders particles smoother, but does not lead to reduction in β unless it gives rise to pore stiffening cementation. Pore stiffening cementation causes......Chalk develops as a result of diagenesis of pelagic calcareous ooze. In a newly deposited ooze sediment, porosity ranges from 60% to 80% but porosity reduces with burial. We studied how different porosity reduction mechanisms change the strength of these deep sea carbonate-rich sediments and effect...... β to fall, even when porosity remains constant. Biot's coefficient correlates with strength-indicating properties: compressional and shear modulus, oedometer modulus, yield strength, strain from direct loading and creep strain. Our data indicate that β may be used for predicting the diagenetic...

  3. The potential for phosphorus pollution remediation by calcite precipitation in UK freshwaters

    Directory of Open Access Journals (Sweden)

    C. Neal

    2001-01-01

    Full Text Available This paper examines the potential for calcium carbonate to reduce phosphate pollution in freshwaters by co-precipitation, a process known as a "self cleansing mechanism". Calcium carbonate saturation levels and phosphate concentrations (SRP - soluble reactive phosphate across the major eastern UK river basins are examined to test for solubility controls. The study shows that calcite saturation varies for each catchment as a function of flow and biological activity rather than by direct regulation by SRP. Indeed, there is no evidence, for any of the rivers studied, that calcite solubility controls hold. However, for groundwater and groundwater-fed springs in the Chalk of the Thames basin, calcite saturation is observed with associated low SRP levels. A self-cleansing mechanism may well be operative within the Chalk due to two factors. Firstly, there is a high potential for nucleation on the calcite micro-crystals in the aquifer. Secondly, there are within aquifer reactions that remove the calcite nucleating inhibitors (SRP and dissolved organic carbon, DOC to levels lower than those occurring within the rivers do. These inhibitors enter the catchment at very high concentrations in association with agricultural pollution (fertilizer application and animal slurry and household contamination (e.g. sewage sources from septic tanks. Under low flow conditions, when the saturation index for calcite is at its highest, so too is the concentration of the nucleation inhibitor SRP. Companion work shows that calcite precipitation can occur at the water-sediment interface of the river and this may involve SRP removal. The data, as a whole, define an apparent bound for calcite solubility control where in the presence of nucleating centres, SRP must be less than 4 mM-P l-1 and DOC must be less than 150 mM-C l-1: a condition that does not seem to pertain within most UK rivers. Keywords: calcite, calcium carbonate, phosphate, soluble reactive phosphate, dissolved

  4. How stress and temperature conditions affect rock-fluid chemistry and mechanical deformation

    Directory of Open Access Journals (Sweden)

    Anders eNermoen

    2016-02-01

    Full Text Available We report the results from a series of chalk flow-through-compaction experiments performed at three effective stresses (0.5 MPa, 3.5 MPa and 12.3 MPa and two temperatures (92℃ and and 130℃. The results show that both stress and temperature are important to both chemical alteration and mechanical deformation. The experiments were conducted on cores drilled from the same block of outcrop chalks from the Obourg quarry within the Saint Vast formation (Mons, Belgium. The pore pressure was kept at 0.7 MPa for all experiments with a continuous flow of 0.219 M MgCl2 brine at a constant flow rate; 1 original pore volume (PV per day. The experiments have been performed in tri-axial cells with independent control of the external stress (hydraulic pressure in the confining oil, pore pressure, temperature, and the injected flow rate. Each experiment consists of two phases; a loading phase where stress-strain dependencies are investigated (approx. 2 days, and a creep phase that lasts for more than 150-160 days. During creep, the axial deformation was logged, and the effluent samples were collected for ion chromatography analyses. Any difference between the injected and produced water chemistry gives insight into the rock-fluid interactions that occur during flow through of the core. The observed effluent concentration shows a reduction in Mg2+, while the Ca2+ concentration is increased. This, together with SEM-EDS analysis, indicates that magnesium-bearing mineral phases are precipitated leading to dissolution of calcite, an observation . This is in-line with other flow-through experiments reported earlier. The observed dissolution and precipitation are sensitive to the effective stress and test temperature. Typically. H, higher stress and temperature lead to increased concentration differences of Mg2+ and Ca2+ concentration changes.. The observed strain can be partitioned additively into a mechanical and chemical driven component.

  5. Is it worth protecting groundwater from diffuse pollution with agri-environmental schemes? A hydro-economic modeling approach.

    Science.gov (United States)

    Hérivaux, Cécile; Orban, Philippe; Brouyère, Serge

    2013-10-15

    In Europe, 30% of groundwater bodies are considered to be at risk of not achieving the Water Framework Directive (WFD) 'good status' objective by 2015, and 45% are in doubt of doing so. Diffuse agricultural pollution is one of the main pressures affecting groundwater bodies. To tackle this problem, the WFD requires Member States to design and implement cost-effective programs of measures to achieve the 'good status' objective by 2027 at the latest. Hitherto, action plans have mainly consisted of promoting the adoption of Agri-Environmental Schemes (AES). This raises a number of questions concerning the effectiveness of such schemes for improving groundwater status, and the economic implications of their implementation. We propose a hydro-economic model that combines a hydrogeological model to simulate groundwater quality evolution with agronomic and economic components to assess the expected costs, effectiveness, and benefits of AES implementation. This hydro-economic model can be used to identify cost-effective AES combinations at groundwater-body scale and to show the benefits to be expected from the resulting improvement in groundwater quality. The model is applied here to a rural area encompassing the Hesbaye aquifer, a large chalk aquifer which supplies about 230,000 inhabitants in the city of Liege (Belgium) and is severely contaminated by agricultural nitrates. We show that the time frame within which improvements in the Hesbaye groundwater quality can be expected may be much longer than that required by the WFD. Current WFD programs based on AES may be inappropriate for achieving the 'good status' objective in the most productive agricultural areas, in particular because these schemes are insufficiently attractive. Achieving 'good status' by 2027 would demand a substantial change in the design of AES, involving costs that may not be offset by benefits in the case of chalk aquifers with long renewal times.

  6. Development of a risk assessment for BSE in the aquatic environment.

    Science.gov (United States)

    Gale, P; Young, C; Stanfield, G; Oakes, D

    1998-04-01

    Bovine spongiform encephalopathy (BSE) is believed to be transmitted by the ingestion of proteinaceous agents called prions which accumulate in the brain and spinal cord of infected bovines. Concern has been expressed about the risks of transmission of BSE to humans through BSE prions discharged to the aquatic environment from rendering plants, abattoirs and landfills. The disease-related form of the prion protein is relatively resistant to degradation, and infectivity decays rather slowly in the environment. Levels of disinfection used for drinking water treatment would have little effect. This paper presents the assumptions which were used to model the risks from a rendering plant disposing of cull cattle carcasses in the catchment of a chalk aquifer which is used for a drinking water abstraction. The risk assessment approach focused on identifying the hydrogeological and physical barriers which would contribute to preventing BSE infectivity gaining entry to the aquifer. These barriers included inactivation of BSE agent by the rendering process, removal from the effluent by treatment at the plant, filtration and adsorption in the clay and chalk, and dilution in the ground water. The importance in environmental risk assessment of the cow-to-man species barrier is considered. Two key conclusions about the environmental behaviour of the BSE agent are that prion proteins are 'sticky' and bind to particulates, and that the millions of BSE prion molecules comprising a human oral ID50 are subject to some degree of dispersion and hence dilution in the environment. Assuming the rendering plant processes 2000 cull cattle carcasses per week, the risks to drinking water consumers were estimated to be remote. Indeed, even using worst case assumptions an individual would have to consume 21 d-1 of tap water for 45 million years to have a 50% chance of infection through drinking water drawn from the aquifer.

  7. How stress and temperature conditions affect rock-fluid chemistry and mechanical deformation

    Science.gov (United States)

    Nermoen, Anders; Korsnes, Reidar; Aursjø, Olav; Madland, Merete; Kjørslevik, Trygve Alexander; Østensen, Geir

    2016-02-01

    We report the results from a series of chalk flow-through-compaction experiments performed at three effective stresses (0.5 MPa, 3.5 MPa and 12.3 MPa) and two temperatures (92° and and 130°). The results show that both stress and temperature are important to both chemical alteration and mechanical deformation. The experiments were conducted on cores drilled from the same block of outcrop chalks from the Obourg quarry within the Saint Vast formation (Mons, Belgium). The pore pressure was kept at 0.7 MPa for all experiments with a continuous flow of 0.219 M MgCl2 brine at a constant flow rate; 1 original pore volume (PV) per day. The experiments have been performed in tri-axial cells with independent control of the external stress (hydraulic pressure in the confining oil), pore pressure, temperature, and the injected flow rate. Each experiment consists of two phases; a loading phase where stress-strain dependencies are investigated (approx. 2 days), and a creep phase that lasts for more than 150-160 days. During creep, the axial deformation was logged, and the effluent samples were collected for ion chromatography analyses. Any difference between the injected and produced water chemistry gives insight into the rock-fluid interactions that occur during flow through of the core. The observed effluent concentration shows a reduction in Mg2+, while the Ca2+ concentration is increased. This, together with SEM-EDS analysis, indicates that magnesium-bearing mineral phases are precipitated leading to dissolution of calcite, an observation . This is in-line with other flow-through experiments reported earlier. The observed dissolution and precipitation are sensitive to the effective stress and test temperature. Typically. H, higher stress and temperature lead to increased concentration differences of Mg2+ and Ca2+ concentration changes.. The observed strain can be partitioned additively into a mechanical and chemical driven component.

  8. Processes and rate of retreat of the clay and sandstone sea cliffs of the northern Boulonnais (France)

    Science.gov (United States)

    Pierre, Guillaume

    2006-01-01

    Retreat of the clay and sandstone cliffs of the northern Boulonnais (France) has been quantified using stereophotogrammetry. The low retreat rate of this coastal strip — 0.08 m/yr between 1939 and 2003 — is far less than that encountered on chalk and clay-chalk cliffs of either side of the Channel, and even less than a previous estimate of 0.17 m/yr regularly quoted in management studies. The retreat rate is closely related to shore platform morphology and dynamics. The shore platform presents 1) a steeply sloping ramp due to the accumulation of flat calcareous megaclasts that reduce marine erosion; 2) upstanding bare platform surfaces, related to tectonic deformation; and 3) thick platform-beaches trapped in troughs. In all three cases, the reflective behaviour of the nearshore protects the cliff foot from the incoming waves. Two critical eroding segments are the result of changes in the platform sedimentary budget. Around Cran Poulet, and between Plage de la Sirène and Pointe de la Courte Dune, the retreat rate is up to 0.25 and 0.15 m/yr, respectively. At Cran Poulet, recession has been facilitated by the extraction of pebble for more than half a century, whereas erosion of the beach at la Sirène is probably linked to severe erosion of the coastline in the adjacent Wissant Bay. Mass movements on the cliff face are essentially shallow-seated translational slides along with small debris falls and mudflows. The instability of the Argiles de Châtillon is greatly diminished by their sandy and silty texture and by the presence of interstratified solid shelly limestone beds that allow steep slopes to develop in rather weak material. The 'vertical erosion antecedent' is the erosional mode of the cliff, and its reduced efficiency explains the slow recession of the cliff. This study will help to determine the long term evolution of the Boulonnais coast.

  9. Nearshore human interventions reverse patterns of decline in lake calcium budgets in central Ontario as demonstrated by mass-balance analyses

    Science.gov (United States)

    Yao, Huaxia; McConnell, Christopher; Somers, Keith M.; Yan, Norman D.; Watmough, Shaun; Scheider, Wolfgang

    2011-06-01

    Calcium (Ca) has declined to levels threatening aquatic biota in lakes on the eastern Canadian Shield. Predictive models for future changes in lake Ca are generally based on catchment-scale studies, but these models rarely account for unmeasured sources of Ca supply that are common in the nearshore areas of developed lakes. In this study we utilize up to 29 years of hydrological and water chemistry data for three lakes in central Ontario that differ in degree of human intervention to demonstrate that shoreline development may exert large effects on Ca mass balances. In the relative absence of shoreline development, Red Chalk Lake exhibited what we consider to be the normal response, a reduction in Ca load from the catchment over the last three decades, leading to a reduction in lake export and lake Ca concentration. Calcium load, export, and lake water Ca concentration also fell in Harp Lake, but less than in Red Chalk Lake, because Ca loads were elevated by human activities in Harp Lake's moderately developed shoreline area. By contrast, Dickie Lake experienced an exceptional change in Ca dynamics: both export and lake concentrations rose because of elevated load from the shoreline area linked to the use of dust suppressants on gravel roads. Reductions in both stream Ca concentration and flow volume have led to calcium decline in streams and lakes. Long-term soil acidification processes and climatic variability with its link to hydrology can explain the general pattern of Ca decline in lakes on the south-central Canadian Shield. However, given the widespread lakeshore development and use of dust suppressants on gravel roads, predictions of lake Ca levels need to take into account nearshore activities, especially those that augment rates of Ca supply.

  10. Some influences of rock strength and strain rate on propagation of rock avalanches

    Science.gov (United States)

    Bowman, Elisabeth; Rait, Kim

    2016-04-01

    Rock avalanches are extreme and destructive mass movements in which large volumes of rock (typically >1 million cubic metres) travel at high speeds, covering large distances, and the occurrence of which is highly unpredictable. The "size effect" in rock avalanches, whereby those with larger volumes produce greater spreading efficiency (as defined by an increase in normalised runout) or lower farboschung angle (defined as the tangent of the ratio of fall height to runout length), is well known. Studies have shown that rock strength is a controlling factor in the mobility of rock avalanches - that is, mass movements involving lower strength rock are generally found to produce greater mobility as evidenced by the spread of deposits or low farboschung angle. However, there are conflicting ideas as to how and why this influence is manifested. This paper discusses different theories of rock comminution in light of numerical simulations of rock clasts undergoing normal and shear induced loading, experimental work on rock avalanche behaviour, and dynamic fracture mechanics. In doing so, we introduce the idea of thresholds of strain rate for the production of dynamic fragmentation (as opposed to pseudo-static clast crushing) that are based, inter alia, on static rock strength. To do this, we refer to data from physical models using rock analogue materials, field data on chalk cliff collapses, and field statistics from documented rock avalanches. The roles of normal and shear loading and loading rate within a rock avalanche are examined numerically using 3D Discrete Element Method models of rock clasts loaded to failure. Results may help to reconcile the observations that large rock avalanches in stronger materials tend not to fragment as much as those in weaker materials and also possess lower mobility, while small cliff collapses (typically > 1000 cubic metres) in weak chalk can exhibit rock avalanche-like behaviour at much smaller volumes.

  11. Permeability-porosity relationships of subduction zone sediments

    Science.gov (United States)

    Gamage, K.; Screaton, E.; Bekins, B.; Aiello, I.

    2011-01-01

    Permeability-porosity relationships for sediments from the northern Barbados, Costa Rica, Nankai, and Peru subduction zones were examined based on sediment type, grain size distribution, and general mechanical and chemical compaction history. Greater correlation was observed between permeability and porosity in siliciclastic sediments, diatom oozes, and nannofossil chalks than in nannofossil oozes. For siliciclastic sediments, grouping of sediments by percentage of clay-sized material yields relationships that are generally consistent with results from other marine settings and suggests decreasing permeability as percentage of clay-sized material increases. Correction of measured porosities for smectite content improved the correlation of permeability-porosity relationships for siliciclastic sediments and diatom oozes. The relationship between permeability and porosity for diatom oozes is very similar to the relationship in siliciclastic sediments, and permeabilities of both sediment types are related to the amount of clay-size particles. In contrast, nannofossil oozes have higher permeability values by 1.5 orders of magnitude than siliciclastic sediments of the same porosity and show poor correlation between permeability and porosity. More indurated calcareous sediments, nannofossil chalks, overlap siliciclastic permeabilities at the lower end of their measured permeability range, suggesting similar consolidation patterns at depth. Thus, the lack of correlation between permeability and porosity for nannofossil oozes is likely related to variations in mechanical and chemical compaction at shallow depths. This study provides the foundation for a much-needed global database with fundamental properties that relate to permeability in marine settings. Further progress in delineating controls on permeability requires additional carefully documented permeability measurements on well-characterized samples. ?? 2010 Elsevier B.V.

  12. Late persistence of the Acheulian in southern Britain in an MIS 8 interstadial: evidence from Harnham, Wiltshire

    Science.gov (United States)

    Bates, M. R.; Wenban-Smith, F. F.; Bello, S. M.; Bridgland, D. R.; Buck, L. T.; Collins, M. J.; Keen, D. H.; Leary, J.; Parfitt, S. A.; Penkman, K.; Rhodes, E.; Ryssaert, C.; Whittaker, J. E.

    2014-10-01

    This paper presents evidence of the discovery of a new Middle Pleistocene site in central southern England, with undisturbed evidence of hominin occupation well-dated to an interstadial towards the end of Marine Isotope Stage 8, c. 250,000 BP. The site consists of a preserved remnant of a river terrace and its alluvial floodplain overlain by chalk-rich bankside deposits, all abutting a Chalk bedrock riverbank. It preserves an area of occupation with activity focused on the riverbank, complemented by occasional activity on a palaeo-landsurface developed on the surface of the alluvial floodplain. Lithic technology at the site consists almost entirely of handaxe manufacture, allowing attribution to an Acheulian industrial tradition. Mammalian and other palaeo-environmental remains are present and associated with the occupation horizons, including large mammal bones showing signs of hominin interference. Dating was based on OSL determinations on the sediments and amino acid racemisation of molluscan remains, supported by biostratigraphic indications. Besides being a rare instance of an undisturbed Palaeolithic palaeo-landscape covering several hectares, the site contributes to wider Quaternary research concerns over the ability of Middle Pleistocene hominins to tolerate colder climatic episodes in higher latitudes, and over settlement history and changing lithic industrial traditions of northwest Europe in relation to climate change and British peninsularity. It is suggested that the Harnham evidence may represent an insular population that had persisted in southern Britain since MIS 10/9, which became locally extinct during the glacial maximum 8.2 marking the end of MIS 8.

  13. The efficiency of micro-Raman spectroscopy in the analysis of complicated mixtures in modern paints: Munch's and Kupka's paintings under study

    Science.gov (United States)

    Košařová, Veronika; Hradil, David; Hradilová, Janka; Čermáková, Zdeňka; Němec, Ivan; Schreiner, Manfred

    2016-03-01

    Twenty one mock-up samples containing inorganic pigments primarily used at the turn of the 19th and 20th century were selected for comparative study and measured by micro-Raman and portable Raman spectrometers. They included pure grounds (chalk-based, earth-based and lithopone-based), grounds covered by resin-based varnish, and different paint layers containing mixtures of white, yellow, orange, red, green, blue and black pigments, usually in combination with white pigments (titanium, zinc and barium whites or chalk). In addition, ten micro-samples obtained from seven paintings of two world-famous modern painters Edvard Munch and František Kupka have been investigated. Infrared reflection spectroscopy (FTIR), portable X-ray fluorescence (XRF) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) were used as supplementary methods. The measurements showed that blue pigments (ultramarine, Prussian blue and azurite), vermilion and ivory black in mixture with whites provided characteristic Raman spectra, while Co-, Cd- and Cr- pigments' bands were suppressed by fluorescence. The best success rate of micro-Raman spectroscopy has been achieved using the 780 nm excitation, however, the sensitivity of this excitation laser in a portable Raman instrument significantly decreased. The analyses of micro-samples of paintings by E. Munch and F. Kupka showed that micro-Raman spectroscopy identified pigments which would remain unidentified if analyzed only by SEM-EDS (zinc yellow, Prussian blue). On the other hand, chromium oxide green and ultramarine were not detected together in a sample due to overlap of their main bands. In those cases, it is always necessary to complement Raman analysis with other analytical methods.

  14. A numerical modelling and neural network approach to estimate the impact of groundwater abstractions on river flows

    Science.gov (United States)

    Parkin, G.; Birkinshaw, S. J.; Younger, P. L.; Rao, Z.; Kirk, S.

    2007-06-01

    SummaryEvaluation of the impacts of groundwater abstractions on surface water systems is a necessary task in integrated water resources management. A range of hydrological, hydrogeological, and geomorphological factors influence the complex processes of interaction between groundwater and rivers. This paper presents an approach which uses numerical modeling of generic river-aquifer systems to represent the interaction processes, and neural networks to capture the impacts of the different controlling factors. The generic models describe hydrogeological settings representing most river-aquifer systems in England and Wales: high diffusivity (e.g. Chalk) and low diffusivity (e.g. Triassic Sandstone) aquifers with flow to rivers mediated by alluvial gravels; the same aquifers where they are in direct connection with the river; and shallow alluvial aquifers which are disconnected from regional aquifers. Numerical model simulations using the SHETRAN integrated catchment modeling system provided outputs including time-series and spatial variations in river flow depletion, and spatially distributed groundwater levels. Artificial neural network models were trained using input parameters describing the controlling factors and the outputs from the numerical model simulations, providing an efficient tool for representing the impacts of groundwater abstractions across a wide range of conditions. There are very few field data sets of accurately quantified river flow depletion as a result of groundwater abstraction under controlled conditions. One such data set from an experimental study carried out in 1967 on the Winterbourne stream in the Lambourne catchment over a Chalk aquifer was used successfully to test the modeling tool. This modeling approach provides a general methodology for rapid simulations of complex hydrogeological systems which preserves the physical consistency between multiple and diverse model outputs.

  15. Acoustically-Induced Electrical Signals

    Science.gov (United States)

    Brown, S. R.

    2014-12-01

    We have observed electrical signals excited by and moving along with an acoustic pulse propagating in a sandstone sample. Using resonance we are now studying the characteristics of this acousto-electric signal and determining its origin and the controlling physical parameters. Four rock samples with a range of porosities, permeabilities, and mineralogies were chosen: Berea, Boise, and Colton sandstones and Austin Chalk. Pore water salinity was varied from deionized water to sea water. Ag-AgCl electrodes were attached to the sample and were interfaced to a 4-wire electrical resistivity system. Under computer control, the acoustic signals were excited and the electrical response was recorded. We see strong acoustically-induced electrical signals in all samples, with the magnitude of the effect for each rock getting stronger as we move from the 1st to the 3rd harmonics in resonance. Given a particular fluid salinity, each rock has its own distinct sensitivity in the induced electrical effect. For example at the 2nd harmonic, Berea Sandstone produces the largest electrical signal per acoustic power input even though Austin Chalk and Boise Sandstone tend to resonate with much larger amplitudes at the same harmonic. Two effects are potentially responsible for this acoustically-induced electrical response: one the co-seismic seismo-electric effect and the other a strain-induced resistivity change known as the acousto-electric effect. We have designed experimental tests to separate these mechanisms. The tests show that the seismo-electric effect is dominant in our studies. We note that these experiments are in a fluid viscosity dominated seismo-electric regime, leading to a simple interpretation of the signals where the electric potential developed is proportional to the local acceleration of the rock. Toward a test of this theory we have measured the local time-varying acoustic strain in our samples using a laser vibrometer.

  16. Using boreholes as windows into groundwater ecosystems.

    Directory of Open Access Journals (Sweden)

    James P R Sorensen

    Full Text Available Groundwater ecosystems remain poorly understood yet may provide ecosystem services, make a unique contribution to biodiversity and contain useful bio-indicators of water quality. Little is known about ecosystem variability, the distribution of invertebrates within aquifers, or how representative boreholes are of aquifers. We addressed these issues using borehole imaging and single borehole dilution tests to identify three potential aquifer habitats (fractures, fissures or conduits intercepted by two Chalk boreholes at different depths beneath the surface (34 to 98 m. These habitats were characterised by sampling the invertebrates, microbiology and hydrochemistry using a packer system to isolate them. Samples were taken with progressively increasing pumped volume to assess differences between borehole and aquifer communities. The study provides a new conceptual framework to infer the origin of water, invertebrates and microbes sampled from boreholes. It demonstrates that pumping 5 m(3 at 0.4-1.8 l/sec was sufficient to entrain invertebrates from five to tens of metres into the aquifer during these packer tests. Invertebrates and bacteria were more abundant in the boreholes than in the aquifer, with associated water chemistry variations indicating that boreholes act as sites of enhanced biogeochemical cycling. There was some variability in invertebrate abundance and bacterial community structure between habitats, indicating ecological heterogeneity within the aquifer. However, invertebrates were captured in all aquifer samples, and bacterial abundance, major ion chemistry and dissolved oxygen remained similar. Therefore the study demonstrates that in the Chalk, ecosystems comprising bacteria and invertebrates extend from around the water table to 70 m below it. Hydrogeological techniques provide excellent scope for tackling outstanding questions in groundwater ecology, provided an appropriate conceptual hydrogeological understanding is applied.

  17. Palynology of the Upper Maastrichtian, Danish Central Graben. M-10X (Dan Field), E-5X (Tyra SE Field)

    Energy Technology Data Exchange (ETDEWEB)

    Schioeler, P.

    2004-07-01

    A biostratigraphic and palynofacies analysis of a closely-spaced sample succession from cored sections through the Maastrichtian to Danian chalks in the wells M-10X and E-5X shows that the Maastrichtian part of the cores correlate with the Upper Maastrichtian Isabelidinium cooksoniae to Palynodinium grallator dinoflagellate Zones. The base of the core from M-10X is biostratigraphically somewhat lower than that of the E-5X core. Due to the absence of dinoflagellates from samples above the P. grallator Zone the uppermost Maastrichtian to Danian interval could not be correlated to any dinoflagellate zones. The chalks were deposited in a relatively stable, low-productivity, oligotrophic, marine environment relatively far from terrestrial source areas. The lower two-thirds of the cores, from core base to the basal P. grallator Zone was deposited under stable marine conditions during a slight and gradual sea-level lowering with a sea-level minimum reached at the base of the P. grallator Zone. Throughout this interval, productivity was in an overall decline from a maximum near the base of the M-10X core, in the basal Palaeocystodinium denticulatum Zone, to a minimum in the Hystrichostrogylon borisii and basal P. grallator Zones. Sea level rose abruptly again in the lower part of the P. grallator Zone and remained high to the top of that zone. A productivity rise followed this sea-level rise. The second sea-level high was possibly punctuated by a second, short-lived sea-level lowering that took place in the middle part of the P. grallatorZone. Based on correlation with the Maastrichtian type section in the ENCI Quarry, Limburg, The Netherlands, the sea-level low at the base of the P. grallator Zone can be correlated with the sequence boundary at the Horizon van Kanne in the ENCI Quarry section and dated to 65.5 Ma. (au)

  18. Release of beryllium from mineral ores in artificial lung and skin surface fluids.

    Science.gov (United States)

    Duling, Matthew G; Stefaniak, Aleksandr B; Lawrence, Robert B; Chipera, Steve J; Virji, M Abbas

    2012-06-01

    Exposure to some manufactured beryllium compounds via skin contact or inhalation can cause sensitization. A portion of sensitized persons who inhale beryllium may develop chronic beryllium disease (CBD). Little is understood about exposures to naturally occurring beryllium minerals. The purpose of this study was to assess the bioaccessibility of beryllium from bertrandite ore. Dissolution of bertrandite from two mine pits (Monitor and Blue Chalk) was evaluated for both the dermal and inhalation exposure pathways by determining bioaccessibility in artificial sweat (pH 5.3 and pH 6.5), airway lining fluid (SUF, pH 7.3), and alveolar macrophage phagolysosomal fluid (PSF, pH 4.5). Significantly more beryllium was released from Monitor pit ore than Blue Chalk pit ore in artificial sweat buffered to pH 5.3 (0.88 ± 0.01% vs. 0.36 ± 0.00%) and pH 6.5 (0.09 ± 0.00% vs. 0.03 ± 0.01%). Rates of beryllium released from the ores in artificial sweat were faster than previously measured for manufactured forms of beryllium (e.g., beryllium oxide), known to induce sensitization in mice. In SUF, levels of beryllium were below the analytical limit of detection. In PSF, beryllium dissolution was biphasic (initial rapid diffusion followed by latter slower surface reactions). During the latter phase, dissolution half-times were 1,400 to 2,000 days, and rate constants were ~7 × 10(-10) g/(cm(2)·day), indicating that bertrandite is persistent in the lung. These data indicate that it is prudent to control skin and inhalation exposures to bertrandite dusts.

  19. Modèle de compaction élastoplastique et viscoplastique pour simulateur de bassins sédimentaires Elastoplastic and Viscoplastic Compaction Model for the Simulation of Sedimentary Basins

    Directory of Open Access Journals (Sweden)

    Schneider F.

    2006-11-01

    stress reached by the sediment during its burial. The elastoplastic parameters (Ee, Ea, Eb, phi index (a, phi index (b, phi index (r of function Beta can be easily calibrated from experimental data or from well logs data (Hamilton, 1959; Schneider et al, 1993. The viscoplastic parameters (µ index b, phi to the power of (min of function alpha can be calibrated from well logs data as shown in this study. They can also be extrapolated, for a given lithology, from experimental data (Gratier and Guiguet, 1986. A sensitivity analysis has been carried out with different values of extrapolated viscous coefficients. The viscous deformation is important (50% of the total strain for basins older than 1 Ma when the viscous coefficient is lower than a critical value of 10 MPa. Ma This critical value is equal to 100 MPa. M for basin older than 10 Ma and is equal to 1000 MPa. Ma for basin older than 100 Ma. With field data from Scholle (1977, it is possible to estimate the elastoplastic and viscoplastic parameters which define a chalk rheology. Assuming that chalk which had no suffer diagenesis, has been compacted along an elastoplastic path, it is possible to calibrate easily the elastoplasic parameters. Such a calibration can be also performed with laboratory measurements as suggested by Hamilton (1959. When chalk has suffered diagenesis, we assume that the present-day porosity versus effective-stress relationships, extracted from well logs, result both from elastoplastic deformation and viscoplastic deformation. With this assumption, chalk viscosity is evaluated around 2. 5 GPa. Ma. According to the sensitivity analysis, chalk pressure solution (viscoplastic deformation is noteworthy (10% of the total strain for basin older than 20 Ma. In conclusion, this model allow to take into account, in a realistic way, pressure solution phenomena which participate to sediments compaction. The major hypotheses are : (1 the transport of species in solution can be neglected in regard to the size

  20. Impacts on oil recovery from capillary pressure and capillary heterogeneities

    Energy Technology Data Exchange (ETDEWEB)

    Bognoe, Thomas

    2008-07-01

    The main conclusions drawn from this thesis are; 7 scientific papers are published on a broad variety of subjects, and describes in detail the experiments and research treated in this thesis. Scientific research has been performed, investigating the subjects of capillary pressure and capillary heterogeneities from different angles. This thesis discusses the findings in this study and aims to illustrate the benefits of the results obtained for further development of other experiments, and/or even the industrial benefits in field development. The methods for wettability alteration have developed throughout the work. From producing heterogeneous wettability alterations, the methods have improved to giving both radial and lateral uniform wettability alterations, which also remains unaltered throughout the duration of the experimental work. The alteration of wettability is dependent on initial water saturation, flow rate, aging time and crude oil composition. Capillary pressure and relative permeability curves have been measured for core plugs at different wettabilities using conventional centrifuge methods. The trends observed are mostly consistent with theory. The production mechanisms of strongly and moderately water wet chalk has been investigated. At strongly water wet conditions in fractured chalk; the flow is governed by capillary forces, showing strong impact from the fractures. At moderately water wet conditions, the impact of the fractures are absent, and a dispersed water front is observed during the displacement. The oil recovery is about the same, at the two wettabilities. Fracture crossing mechanisms at the same wettability conditions have been mapped. And the observations are consistent with those of the water floods. During strongly water wet displacement, the fracture crossing is occurring once the inlet core has reached endpoint of spontaneous imbibition. At moderately water wet conditions the fracture crossing is less abrupt, and creation of wetting

  1. Longshore Sediment Transport on a Macrotidal Mixed Sediment Beach, Birling Gap, United Kingdom.

    Science.gov (United States)

    Curoy, J.; Moses, C. A.; Robinson, D. A.

    2012-04-01

    Mixed beaches (MBs), with sediment sizes ranging over three orders of magnitude, are an increasingly important coastal defence on > 1/3 of the shoreline of England and Wales. In East Sussex, the combined effect of coastal defence management schemes (extensive groyning and sea wall construction) has reduced beach sediment supply. Local authorities counteract the increased flood risk by recycling or artificially recharging beaches on the most vulnerable and populated areas. Beaches lose sediment predominantly via longshore transport (LST) whose accurate quantification is critical to calculating recharge amounts needed for effective beach management. Industry does this by using sediment transport modelling which depends on reliable input data and modelling assumptions. To improve understanding of processes and quantification of LST on MBs, this study has accurately measured sediment transport on a natural, macrotidal, MB. The 1.2 km natural MB at Birling Gap, East Sussex here is located on the downdrift end of an 80 km long sub-sedimentary cell and is oriented WNW-ESE. The beach lies on a low gradient chalk shore platform backed by sub-vertical chalk cliffs. It is composed primarily of flint gravel with a peak grain size distribution of 30 to 50 mm, and a sand content of up to 30%. Sediment transport was measured using pebble tracers and GPS surface surveys during three survey periods of three to five consecutive days in March, May and December 2006. Tracer pebbles, matching the beach pebbles' D50, were made of an epoxy resin with a copper core allowing their detection and recovery to a depth of 40 cm using a metal detector. Tracers were deployed on the upper, middle and lower beach, from the surface into the beach to depths of up to 40 cm. They were collected on the low tide following deployment. The wave conditions were recorded on a Valeport DWR wave recorder located seaward of the beach on the chalk platform. Over the three study periods a large spectrum of wave

  2. Cenomanian-Turonian Bentonites of the Boquillas Formation, Texas, USA: keys to understanding Carbonate Shelf deposition in a Greenhouse Climate

    Science.gov (United States)

    Bergman, Steve; Eldrett, James; Ma, Chao; Minisini, Daniel; Macaulay, Calum; Ozkan, Aysen; Kelly, Amy

    2016-04-01

    The Boquillas Formation (Fm.) (equivalent to the Eagle Ford Group) was deposited at the Southern end of the Cretaceous Western Interior Seaway (KWIS) and the northwestern margin of the Gulf of Mexico Carbonate Shelf (passive margin) in a starved retroarc foreland basin setting during part of the Cenomanian and Turonian Stages (CT; 97-90 Ma). The Boquillas Fm. includes several Oceanic Anoxic Events (OAE) marked by global Carbon Isotope Excursions (CIE) and trace metal anomalies. Here we provide a robust zircon U/Pb geochronologic framework used to accurately interpret and predict variability in facies distribution. The Boquillas Fm. consists of a succession of cyclic marlstone and limestone beds and over 300 bentonites deposited in a distal, restricted, suboxic setting mostly below storm wave base. Bentonites are generally homogenous clay-rich layers 1-10 cm thick (average 5 cm, up to 1 m) showing sharp contacts and strong yellow-orange mineral fluorescence under UV light. In addition to detailed logging of roadcuts, two research wells drilled behind outcrops, Shell IONA-1 and Shell INNES-1, recovered >330 m of continuous core from the Austin Chalk at surface through the Boquillas and Buda Limestone Fm. The bentonites form ~5% of the 60-111 m thick Boquillas Fm. intervals and are interpreted as distal pyroclastic fall deposits from large volume (>10-100 km3) Plinian eruptions from calderas associated with the subduction-related Western North American Cordilleran magmatic arc. Some of the Boquillas Fm. bentonites can be correlated using cores, petrophysical logs, geochemistry, and biostratigraphy for more than 1000 km to the north within the Western Interior Seaway at the CT global stratotype (GSSP) section at Pueblo, CO as well as many other sections in the KWIS. This contribution integrates new high-precision zircon U/Pb TIMs age data (2σ as low as 0.05 Myr) from both core and outcrop samples with independent proxies derived from sedimentology, biostratigraphy

  3. Models for evolution of reactive surface area during dissolution and precipitation

    Science.gov (United States)

    Pedersen, Janne; Jettestuen, Espen; Hildebrand-Habel, Tania; Vinningland, Jan Ludvig; Vadla Madland, Merete; Korsnes, Reidar Inge; Hiorth, Aksel

    2014-05-01

    During water flooding of a reservoir, minerals can dissolve and/or precipitate if the injected water is out of equilibrium with the formation. A net mass transfer between solid and fluid will result in a dynamically changing pore space, which in turn may change the permeability and/or the porosity of the reservoir. When secondary minerals precipitate from solution they will form on top of the primary minerals on the pore walls, and hence the reactive surface area of the individual minerals constituting the porous medium will change. This will in turn affect the dissolution/precipitation rates. In this work we study three different models for the evolution of reactive surface areas during flooding of a core with a brine that is in disequilibrium with the rock. The three models differ in the way secondary minerals are distributed on the solid surface: In model I the whole surface area of both primary and secondary minerals is reactive; hence there will be no screening effect when secondary minerals form. In model II secondary minerals form as a monolayer on the primary minerals that will screen primary minerals from the flow. Model I and II represent two extremes regarding the screening effect; namely no screening (model I) and full screening (model II). Model III is motivated from observations of unflooded and flooded chalk using scanning electron microscopy (SEM). In this model secondary minerals are assumed to form preferentially near crystal defects, being e.g. dislocations in crystallographic pattern or grain contacts. Also the rate of precipitation for forming minerals varies for precipitation onto primary (dissimilar) minerals and precipitation onto secondary (similar) minerals. The three models are implemented into a lattice Boltzmann (LB) based geochemical simulator, and simulation results are compared to results from a 3 years long core flooding experiment with outcrop chalk flooded with 0.219M MgCl2 at 130°C, as well as SEM studies. Before flooding 98wt

  4. I/Ca records of local redox history for contrasting depositional environments during Cenomanian-Turonian OAE2

    Science.gov (United States)

    Lu, Z.; Zhou, X.; Junium, C. K.; Sageman, B. B.; Jenkyns, H.

    2012-12-01

    Periods of catastrophic marine oxygen-depletion are known as Oceanic Anoxic Events (OAEs). The most severe OAE intervals in the geological record can be recognized by both positive and negative δ13C excursions, indicating major changes in the global carbon cycle. However, such geochemical expressions only mark the most significant periods of the OAE, characterized by massive carbon burial and/or injection of isotopically light carbon into the ocean-atmosphere system, effects that typically developed after the initial build-up of anoxic/euxinic conditions in many different basins worldwide. Iodide (I-) and iodate (IO3-) are the thermodynamically stable inorganic forms of iodine in seawater. Iodate is almost completely reduced to iodide in all investigated anoxic basins and OMZs. In a pilot study (Lu et al., 2010, Geology), I/Ca in synthetic calcite recorded iodate concentrations in the medium. This established the potential for I/Ca as a novel redox proxy and it was applied in two carbonate-rich sections recording the early Toarcian OAE (shallow-water carbonate platform site) and the Cenomanian-Turonian OAE 2 (pelagic chalk, Eastbourne, UK). Here we report preliminary I/Ca data from three more Cretaceous OAE 2 sections: Raia del Pedale (Italy), South Ferriby (UK), and Denver (USA) representing the Western Interior Seaway. Raia del Pedale is a shallow-water carbonate platform site. It has lower I/Ca values compared to those of the pelagic sites and the reducing condition lasted relatively longer. I/Ca data from the South Ferriby section have baseline values similar to those at Eastbourne (both are in chalk facies), while positive spikes on the profile may record upwelling episodes. The Western Interior Seaway site shows unique trends in redox conditions during the OAE, consistent with changes in TOC content. These preliminary data indicate that the development of reducing conditions was not synchronous on a global scale and that local environmental factors modified

  5. Potential for horizontal well technology in the U.S

    Energy Technology Data Exchange (ETDEWEB)

    Biglarbigi, K.; Mohan, H. [Intek Inc., Fairfax, VA (United States); Ray, R.M. [USDOE, National Petroleum Technology Office, Tulsa, OK (United States); Meehan, D.N. [Union Pacific Resources Inc., Fort Worth, TX (United States)

    2000-11-01

    In the past decade, the use of horizontal well technology has increased significantly in the U.S., contributing to the drilling of 600 to 1000 horizontal oil wells annually. A total of 86 per cent of the existing horizontal wells have been drilled in three formations, the Austin chalk in Texas, the Bakken shale in North Dakota, and the Niobrara in Colorado and Wyoming. A unique analytical system has been developed by the United States Department of Energy, National Petroleum Technology Office (USDOE/NPTO) to assess the potential for greater use of horizontal well technology for other oil resources in other geological formations. The analytical system is designed to be used in association with other enhanced recovery methods that make up the DOE's Total Oil Recovery Information System (TORIS). The DOE/NPTO collaborated with industry to identify the target resource for horizontal well technology and to evaluate its future recovery potential under different economic and technological conditions. This paper provides a national summary of the potential for additional production and reserves with more diverse application of horizontal wells in various types of U.S. oil resources, including the rest of the fractured reservoirs in the Austin chalk, other fractured reservoirs in the north and northwestern states, thin-bed reservoirs, and mature waterflood field. The results were presented in terms of production, reserves and national economic benefits with a full cash-flow analysis at oil prices in the range of $16 to $24 U.S. per bbl. It is estimated that 541 million to 1 billion bbls of new reserves are economically producible at these prices. The reserves estimates pertain to future horizontal wells in known fields only and are in addition to the reserves for the existing wells as of 1 January 1998. Potential production is substantial, ranging from 50 million to 85 million bbl per year by 2004 and then declining at a rate of 8 per cent per year in the following

  6. Potential for horizontal well technology in the U.S.

    Energy Technology Data Exchange (ETDEWEB)

    Biglarbigi, K.; Mohan, H. [Intek Inc., Fairfax, VA (United States); Ray, R.M. [USDOE, National Petroleum Technology Office, Tulsa, OK (United States); Meehan, D.N. [Union Pacific Resources Inc., Fort Worth, TX (United States)

    2000-11-01

    In the past decade, the use of horizontal well technology has increased significantly in the U.S., contributing to the drilling of 600 to 1000 horizontal oil wells annually. A total of 86 per cent of the existing horizontal wells have been drilled in three formations, the Austin chalk in Texas, the Bakken shale in North Dakota, and the Niobrara in Colorado and Wyoming. A unique analytical system has been developed by the United States Department of Energy, National Petroleum Technology Office (USDOE/NPTO) to assess the potential for greater use of horizontal well technology for other oil resources in other geological formations. The analytical system is designed to be used in association with other enhanced recovery methods that make up the DOE's Total Oil Recovery Information System (TORIS). The DOE/NPTO collaborated with industry to identify the target resource for horizontal well technology and to evaluate its future recovery potential under different economic and technological conditions. This paper provides a national summary of the potential for additional production and reserves with more diverse application of horizontal wells in various types of U.S. oil resources, including the rest of the fractured reservoirs in the Austin chalk, other fractured reservoirs in the north and northwestern states, thin-bed reservoirs, and mature waterflood field. The results were presented in terms of production, reserves and national economic benefits with a full cash-flow analysis at oil prices in the range of $16 to $24 U.S. per bbl. It is estimated that 541 million to 1 billion bbls of new reserves are economically producible at these prices. The reserves estimates pertain to future horizontal wells in known fields only and are in addition to the reserves for the existing wells as of 1 January 1998. Potential production is substantial, ranging from 50 million to 85 million bbl per year by 2004 and then declining at a rate of 8 per cent per year in the following

  7. Tectonic origin for polygonal normal faults in pelagic limestones of the Cingoli anticline hinge (Italy)

    Science.gov (United States)

    Petracchini, Lorenzo; Antonellini, Marco; Billi, Andrea; Scrocca, Davide

    2016-04-01

    Polygonal faults are a relatively-recent new class of normal faults which are thought to be formed during early burial and diagenesis as a consequence of heterogeneous lateral volume changes. Polygonal faults are non-systematically oriented and, in map view, they form rhombus-, pentagon-, or hexagon-like pattern, suggesting a non-tectonic origin. Furthermore, polygonal faults are layer bound and they are restricted to particular stratigraphic level. Predicting the pattern of polygonal normal fault results crucial for geofluid exploration and exploitation, but, despite the large number of studies, the origin of these faults remains still largely controversial. One of the main reason for this uncertainty is that they are poorly known in outcrops. Polygonal faults have been identified in few localities within Mesozoic chalk (United Kingdom, France, and Egypt), in Paleogene claystone (Belgium), and in the Cretaceous Khoman Formation (Egypt) where polygonal faults have been observed in an extensive exposure of chalk. In this study, we describe an outcrop in the Cingoli anticline hinge, which is located at external front of the northern Apennines fold-thrust belt (Italy), showing normal faults that we interpreted as syn-tectonically (syn-thrusting) polygonal faults. The outcrop shows three vertical exposures of sub-horizontal fine-grained marly limestones with chert interlayers of Albian-Turonian age. Intraformational short normal faults affect the carbonate and chert beds. These faults are poorly-systematic and they cut through the carbonate beds whereas usually stop against the chert layers. The fault surfaces are often characterized by slickolites, clayey residue, and micro-breccias including clasts of chert and carbonate. Fault displacement is partly or largely accommodated by pressure solution. At the fault tips, the displacement is generally transferred, via a lateral step, to an adjacent similar fault segment. The aim of our study is to understand the nucleation

  8. Cenozoic evolution of the eastern Danish North Sea

    Energy Technology Data Exchange (ETDEWEB)

    Huuse, M.; Lykke-Andersen, H.; Michelsen, O.

    2003-12-01

    This paper provides a review of recent high-resolution and conventional seismic investigations in the eastern Danish North Sea and destribes their implications for the development of the eastern North Sea Basin. The results tomprise detailed timestructure maps of four major unconformities in the eastern Danish North Sea: the Top Chalk surface (mid-Paleogene), near top Oligocene, the mid-Miocene unconformity, and base Quatemary. The maps show that the eastem Danish North Sea has been affected by fauldng and salt diapirism throughout the Cenozoic. Carbonate mounds, erosional valleys and pockmark- or karstlike struttures were identitied at the top of the Upper Cretaceous-Danian Chalk Group. Strike-parallel erosional features and depositional geometries observed at near top Oligocene and at the mid-Miocene unconformity indicate that these major sequence boundarics tan be attributed to large-scale lateral changes in sediment supply directions. Increases in sediment flux to the southeastern North Sea at the Eocene/Oligocene transition and in the post-Middle Miocene appear to correlate with similar events world wide and with long term {delta} {sup 18} O increases, indicating forting by global factors, i.e. eustasy and climate. Stratal geometries observed on the seismic data indicate that the socalled `Neogene uplift' of the Bastern Danish North Sea may have been hundreds of metres less than previously suggested. lt is argued that late Cenozoic uplift of the basin margin and of mountain peaks in southern Norway may have been caused entirely by isostatic uplift of the trust in response to accelerated late Cenozoic denudation and dissection of topography created in the Paleogene. The late Cenozoic periods of accelerated denudation and incision rates were most likely driven by climatic deterioration and long term eustatic lowering rather than active late Cenozoic tectonics, the cause of which is conjectural. A series of shallow thrust struttures and an associated system

  9. Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl(pyridyl)silane.

    Science.gov (United States)

    Itami, Kenichiro; Mitsudo, Koichi; Nishino, Akira; Yoshida, Jun-ichi

    2002-04-19

    Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl(pyridyl)silane is described. The hydrosilylation of alkenes using dimethyl(2-pyridyl)silane (2-PyMe(2)SiH) proceeded well in the presence of a catalytic amount of RhCl(PPh(3))(3) with virtually complete regioselectivity. By taking advantage of the phase tag property of the 2-PyMe(2)Si group, hydrosilylation products were isolated in greater than 95% purity by simple acid-base extraction. Strategic catalyst recovery was also demonstrated. The hydrosilylation of alkynes using 2-PyMe(2)SiH proceeded with a Pt(CH(2)=CHSiMe(2))(2)O/P(t-Bu)(3) catalyst to give alkenyldimethyl(2-pyridyl)silanes in good yield with high regioselectivity. A reactivity comparison of 2-PyMe(2)SiH with other related hydrosilanes (3-PyMe(2)SiH, 4-PyMe(2)SiH, and PhMe(2)SiH) was also performed. In the rhodium-catalyzed reaction, the reactivity order of hydrosilane was 2-PyMe(2)SiH > 3-PyMe(2)SiH, 4-PyMe(2)SiH, PhMe(2)SiH, indicating a huge rate acceleration with 2-PyMe(2)SiH. In the platinum-catalyzed reaction, the reactivity order of hydrosilane was PhMe(2)SiH, 3-PyMe(2)SiH > 4-PyMe(2)SiH > 2-PyMe(2)SiH, indicating a rate deceleration with 2-PyMe(2)SiH and 4-PyMe(2)SiH. It seems that these reactivity differences stem primarily from the governance of two different mechanisms (Chalk-Harrod and modified Chalk-Harrod mechanisms). From the observed reactivity order, coordination and electronic effects of dimethyl(pyridyl)silanes have been implicated.

  10. Integrated stratigraphy of the Cenomanian-Turonian boundary interval: improving understanding of Oceanic Anoxic Events

    Science.gov (United States)

    Jarvis, Ian

    2014-05-01

    The Cenomanian-Turonian boundary (CTB) interval ~ 94 Ma represented a period of major global palaeoenvironmental change. Increasingly detailed multidisciplinary studies integrating sedimentological, palaeontological and geochemical data from multiple basins, are enabling the development of refined but complex models that aid understanding of the mechanisms driving changes in ocean productivity and climate. This paper reviews some of the exciting new developments in this field. Facies change characterizes the CTB interval in most areas. In the Chalk seas of northern Europe, a widespead hiatus was followed by the deposition of clay-rich organic-lean beds of the Plenus Marl and its equivalents, and then nodular chalks. In the North Sea basin and its onshore extension in eastern England and northern Germany, black shales of the Black Band (Blodøks Formation, Hasseltal Formation) occur. Similarly, in northern Tethys, a brief interval of black shale accumulation within a predominantly carbonate succession, is exemplified by the Niveau Thomel in the Vocontian Basin (SE France), and the Livello Bonarelli in Italy. Widespread deposition of organic-rich marine sediments during CTB times led to 12C depletion in surface carbon reservoirs (oceans, atmosphere, biosphere), and a large positive global δ13C excursion preserved in marine carbonates and both marine and terrestrial organic matter (Oceanic Anoxic Event 2). Significant biotic turnover characterises the boundary interval, and inter-regional correlation may be achieved at high resolution using integrated biostratigraphy employing macrofossils (ammonites, inoceramid bivalves), microfossils (planktonic foraminifera, dinoflagellate cysts) and calcareous nannofossils. Correlations can be tested against those based on comparison of δ13C profiles - carbon isotope chemostratigraphy, supplemented by oxygen isotope and elemental data. Interpretation of paired carbonate - organic matter δ13C data from multiple CTB sections

  11. Two Catacombs of Late Sarmatian Time From Pashkovsky Burial Mound no. 2

    Directory of Open Access Journals (Sweden)

    Limberis Natalya Yuryevna

    2015-12-01

    Full Text Available The article deals with two burials from the Kuban basin region excavated in Pashkovsky burial mound no. 2 belonging to Maeotian Pashkovskoe ancient settlement. The burials were made in catacombs of similar construction and orientation. The narrow grave entrances and grave chambers are situated in-line. The grave chambers of the catacombs adjoin one other that probably was the reason for plunder of a little earlier burial no. 2. There were the complete horse skeleton, the cow skull and the sheep chap in the grave entrance ofthe catacomb no. 2. A skeleton of a man (about 50 years old was in extended supine position diagonally across the grave chamber, his scull had SSW orientation. Grave goods found near the buried man include the gray-clay bowl and the mug-jar, the iron spearhead, the long sword and the dagger, the bit with wheel-shaped cheek-pieces, the sickle, the knives and the shoe buckles, the glass bead, the chalk rock bead, the bronze buckle and fibula. The catacomb no. 2 plundered in ancient times situated north-ward of the first one, the southern border of the grave chamber is partially cutted by catacomb no. 1. In the grave entrance of the catacomb no. 1 there were the remains of the horse skeleton and the sheep skull. Grave goods scattered in grave chamber included the gray-clay bowl, pieces of chalk, the bronze ring, fragments of the iron buckle, rod, hasp, silver temple ring, bronze escutcheon for the box lock, the iron snap-up loop and fragments of silver flacon with a cover. Late Sarmatian burial rites and grave goods give evidence of the belonging these burials to spokesmen of the equestrian order. The chronological range of the burials stays within terms from the second half of 2nd to the middle of 3rd century A.D. The lower date of the catacomb no. 1 turns toward the end of the 2nd century A.D., the upper date is limited by the first half of the 3rd century A.D. The catacomb no. 2 is stratigraphically older. The eques status of

  12. The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique

    Directory of Open Access Journals (Sweden)

    S.N. Danilchenko

    2016-11-01

    Full Text Available The experiments have shown that the heating range for quantitative evolution of carbon dioxide gas (CO2 from natural calcium carbonates (e.g., chalk, corals, shells of the Anadara clams (Anadara inaequivalvis, shell of bird eggs is from 500 to 850 C with a total heating time of 30-50 minutes. The only exception is the sample of a mortar from a masonry of Saint Sophia Cathedral (the architectural monument of XI century, in which the lowest border of the heating range for carbon dioxide evolution is 400 C. The shape of the CO2 evolution curves for every sample is significantly different in width and intensity as compared to the standard sample (chemically pure synthetic CaCO3. The results, which were obtained on the thermoprogrammed mass-spectrometry (TP‑MS unit, designed and produced by the authors of the current paper, are of great importance for the development of a gas input technique for radiocarbon dating with accelerator mass-spectrometry.

  13. The prevalence and intensity of the main dental diseases in children of Simferopol

    Directory of Open Access Journals (Sweden)

    Bushma N.V.

    2013-06-01

    Full Text Available At present, despite the availability of modern effective oral hygiene means and prevention of dental diseases, which reduced their intensity, disease prevalence remains high. One method of dental caries preventing in children aged 6-7 years is a fissure sealing of molars, the most vulnerable areas of the newly erupted teeth, having a number of problems associated with a complex fissures relief. The purpose of this study was to investigate the prevalence and intensity of dental diseases and their development trends, as well as indicators of electrometric fissures of teeth in children aged 6-7 years of Simferopol. 87 children aged 6-7 years (first classes schools in Simferopol were examined. In this case, assessed the state of hard dental tissues (CFt, CFf, CFDt, CFDf, cavities, fillings, chalk spots, depigmentation, complications in the structure of lesions, the state of periodontal tissue (PMA%, bleeding, Schiller-Pisarev test, CPITN and oral hygiene (Silness-Loe, Stallard were examined. For diagnosing electrometry of hard tissues of dental fissures DentEst apparatus was used. Studies of major dental diseases and electrometric indicators of hard tissues of molars fissures in children under study testifies to a high caries incidence in temporary and permanent teeth and a tendency to increase of caries prevalence of permanent occlusion in these children, poor oral hygiene and the need to develop and implement treatment and preventive measures that not allow the development of caries process in the teeth of permanent occlusion.

  14. Analysis of the fault geometry of a Cenozoic salt-related fault close to the D-1 well, Danish North Sea

    Energy Technology Data Exchange (ETDEWEB)

    Roenoe Clausen, O.; Petersen, K.; Korstgaard, A.

    1995-12-31

    A normal detaching fault in the Norwegian-Danish Basin around the D-1 well (the D-1 faults) has been mapped using seismic sections. The fault has been analysed in detail by constructing backstripped-decompacted sections across the fault, contoured displacement diagrams along the fault, and vertical displacement maps. The result shows that the listric D-1 fault follows the displacement patterns for blind normal faults. Deviations from the ideal displacement pattern is suggested to be caused by salt-movements, which is the main driving mechanisms for the faulting. Zechstein salt moves primarily from the hanging wall to the footwall and is superposed by later minor lateral flow beneath the footwall. Back-stripping of depth-converted and decompacted sections results in an estimation of the salt-surface and the shape of the fault through time. This procedure then enables a simple modelling of the hanging wall deformation using a Chevron model with hanging wall collapse along dipping surfaces. The modelling indicates that the fault follows the salt surface until the Middle Miocene after which the offset on the fault also may be accommodated along the Top Chalk surface. (au) 16 refs.

  15. Geomorphological Prerequisites of Recreation and Tourism Development in the Basin of Bolshaya Golubaya River

    Directory of Open Access Journals (Sweden)

    Vishnyakov Nikolay Vladimirovich

    2014-12-01

    Full Text Available The basin of the Bolshaya Golubaya river is a promising region for the development of recreation, due to the unique natural conditions and rich historical and cultural heritage of this territory. The article demonstrates geomorphological features of the basin of Bolshaya Golubaya and their influence on the prospects of recreational use of this area. The author analyses the literature data on the geomorphology of the region and supplements it with his own field studies. The nature of this region is picturesque and multifarious. There are a lot of ravines, gullies, terraces, chalk cliffs and other landforms here. The author discovers the opportunities of organization of different recreational types in the study area in light of its geomorphological features. Recreational characteristics of this territory make it suitable for hiking, skiing and cycling tourism, horse riding. The results of this research can be used at the stage of creating of tourist-recreational projects, when designing and conducting excursion trips, sports and health touristic events. These studies contribute to the expansion of practical knowledge about the geography of the territory which has a positive effect on the possibility of carrying out mentioned above recreational projects.

  16. Estimation of longitudinal and transverse dispersivities in the Twin Lake natural gradient tracer tests

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, Seiji [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Moltyaner, G.L.

    1998-06-01

    The field scale tracer tests were carried out with a non-reactive tracer of {sup 131}I at Twin Lake on the Chalk River Laboratory (CRL) site in Atomic Energy of Canada Limited (AECL). The natural gradient dispersion test such as the Twin Lake tracer test is very few and useful for evaluating mass transport parameters and testing groundwater flow and transport models. In this report, mass transport parameters, velocity, longitudinal and transverse dispersivities, were estimated from the Twin Lake 40 m tracer tests. This estimation was performed to provide dispersion data for 3-D transport modelling in the Lake 233 site scale (600 m in east-west direction and 1400 m in north-south direction). Two different methods were applied to the measured breakthrough curves of {sup 131}I in order to evaluate velocity and longitudinal dispersivity. The first method is the fitting procedure of the 1-D advection-dispersion solution, and the second one is the temporal moments analysis. The effect of applying these methods to field data on transport parameters was discussed in this study. The vertical profiles of {sup 131}I were used in the estimation of transverse dispersivity by fitting the 3-D advection-dispersion solution. This report refereed to the effect of variable velocity on the estimated dispersivities. The correlation between magnitude of both dispersivities and the travel distance up to 40 m was also investigated. (author)

  17. Proceedings of the 1999 Oil and Gas Conference: Technology Options for Producer Survival

    Energy Technology Data Exchange (ETDEWEB)

    None available

    2000-04-12

    The 1999 Oil & Gas Conference was cosponsored by the U.S. Department of Energy (DOE), Office of Fossil Energy, Federal Energy Technology Center (FETC) and National Petroleum Technology Office (NPTO) on June 28 to 30 in Dallas, Texas. The Oil & Gas Conference theme, Technology Options for Producer Survival, reflects the need for development and implementation of new technologies to ensure an affordable, reliable energy future. The conference was attended by nearly 250 representatives from industry, academia, national laboratories, DOE, and other Government agencies. Three preconference workshops (Downhole Separation Technologies: Is it Applicable for Your Operations, Exploring and developing Naturally Fractured Low-Permeability Gas Reservoirs from the Rocky Mountains to the Austin Chalk, and Software Program Applications) were held. The conference agenda included an opening plenary session, three platform sessions (Sessions 2 and 3 were split into 2 concurrent topics), and a poster presentation reception. The platform session topics were Converting Your Resources Into Reserves (Sessions 1 and 2A), Clarifying Your Subsurface Vision (Session 2B), and High Performance, Cost Effective Drilling, Completion, Stimulation Technologies (Session 3B). In total, there were 5 opening speakers, 30 presenters, and 16 poster presentations.

  18. One-sided muon tomography - A portable method for imaging critical infrastructure with a single muon detector

    CERN Document Server

    Boniface, K; Erlandson, A; Jonkmans, G; Thompson, M; Livingstone, S

    2016-01-01

    High-energy muons generated from cosmic-ray particle showers have been shown to exhibit properties ideal for imaging the interior of large structures. This paper explores the possibility of using a single portable muon detector in conjunction with image reconstruction methods used in nuclear medicine to reconstruct a 3D image of the interior of critical infrastructure such as the Zero Energy Deuterium (ZED-2) research reactor at Canadian Nuclear Laboratories' Chalk River site. The ZED-2 reactor core and muon detector arrangement are modeled in GEANT4 and Monte Carlo measurements of the resultant muon throughput and angular distribution at several angles of rotation around the reactor are generated. Statistical analysis is then performed on these measurements based on the well-defined flux and angular distribution of muons expected near the surface of the earth. The results of this analysis are shown to produce reconstructed images of the spatial distribution of nuclear fuel within the core for multiple fuel c...

  19. 石骨症的X线诊断

    Institute of Scientific and Technical Information of China (English)

    张海潮; 周治虎

    2006-01-01

    石骨症(Osteopetrosis)又称大理石骨(Marble bonedisease)。周身性骨质硬化症(Osteoclerosis generalisata),粉笔样骨(chalk bone)等,是一种罕见的泛发性骨质硬化性病变。本症Albers—Schonbarg氏于1904年首先报导,1926年Karshner根据其骨骼特点将其命名为石骨症,该名一直沿用至今。本病X线表现比较特异,诊断一般不难。但因本症相当罕见,不少X线医生多年甚至终生难遇一例,因而影响了对该症的深入观察和认识,尤其当单照一张X线局部骨片,影像欠典型时,鉴别诊断仍有困难,为了提高对本症的认识,现结合我院两例石骨症病例进行一些探讨。

  20. Improved Flow Property Determination from Nanotomography of Porous Media

    DEFF Research Database (Denmark)

    Jha, Diwaker

    The pore scale morphology of a porous medium determines the fluid transport through that medium. It can be described by parameters, such as porosity, pore size distribution and surface area, which can be computationally determined from synchrotron based X-ray tomography (SXCT) data. The uncertain......The pore scale morphology of a porous medium determines the fluid transport through that medium. It can be described by parameters, such as porosity, pore size distribution and surface area, which can be computationally determined from synchrotron based X-ray tomography (SXCT) data...... methods, the results can become unreliable if the structural disparity between a reconstructed tomogram and a real sample is large. In this thesis, I attempted to decrease this disparity, especially because the samples were natural porous media, such as Bryozoan limestone and North Sea Basin chalk, where...... errors in a small scale study can have profound implications when the results are applied to larger scale systems. The sources of the disparity between a physical sample and tomography data already begin with imaging. As most imaging systems, tomograms are prone to various artifacts. A reconstructed...

  1. Isotopic signature of selected lanthanides for nuclear activities profiling using cloud point extraction and ICP-MS/MS.

    Science.gov (United States)

    Labrecque, Charles; Lebed, Pablo J; Larivière, Dominic

    2016-05-01

    The presence of fission products, which include numerous isotopes of lanthanides, can impact the isotopic ratios of these elements in the environment. A cloud point extraction (CPE) method was used as a preconcentration/separation strategy prior to measurement of isotopic ratios of three lanthanides (Nd, Sm, and Eu) by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). To minimise polyatomic interference, the combination of interferents removal by CPE, reaction/collision cell conditions in He and NH3 mode and tandem quadrupole configuration was investigated and provided optimal results for the determination of isotopic ratio in environmental samples. Isotopic ratios were initially measured in San Joaquin soil (NIST-2709a), an area with little contamination of nuclear origin. Finally, samples collected from three sites with known nuclear activities (Fangataufa Lagoon in French Polynesia, Chernobyl and the Ottawa River near Chalk River Laboratory) were analysed and all exhibited altered isotopic ratios for (143/145)Nd, (147/149)Sm, and (151/153)Eu. These results demonstrate the potential of CPE and ICP-MS/MS for the detection of altered isotopic ratio in environmental samples collected in area subjected to nuclear anthropogenic contamination. The detection of variations in these isotopic ratios of fission products represents the first application of CPE in nuclear forensic investigations of environmental samples.

  2. Influence of Intrinsic Colloid Formation on Migration of Cerium through Fractured Carbonate Rock.

    Science.gov (United States)

    Tran, Emily L; Klein-BenDavid, Ofra; Teutsch, Nadya; Weisbrod, Noam

    2015-11-17

    Migration of colloids may facilitate the transport of radionuclides leaked from near surface waste sites and geological repositories. Intrinsic colloids are favorably formed by precipitation with carbonates in bicarbonate-rich environments, and their migration may be enhanced through fractured bedrock. The mobility of Ce(III) as an intrinsic colloid was studied in an artificial rainwater solution through a natural discrete chalk fracture. The results indicate that at variable injection concentrations (between 1 and 30 mg/L), nearly all of the recovered Ce takes the form of an intrinsic colloid of >0.45 μm diameter, including in those experiments in which the inlet solution was first filtered via 0.45 μm. In all experiments, these intrinsic colloids reached their maximum relative concentrations prior to that of the Br conservative tracer. Total Ce recovery from experiments using 0.45 μm filtered inlet solutions was only about 0.1%, and colloids of >0.45 μm constituted the majority of recovered Ce. About 1% of Ce was recovered when colloids of >0.45 μm were injected, indicating the enhanced mobility and recovery of Ce in the presence of bicarbonate.

  3. From rockstar researcher to selfless mentor: a daughter's perspective.

    Science.gov (United States)

    Castillo-Garsow, Melissa

    2013-01-01

    Carlos Castillo-Chavez's tenure at Cornell University with Simon Levine, also marks the beginning of my life as his daughter. I was nine months old when I arrived to Ithaca, and my recollections of my father in elementary school and middle school were of him furiously writing equations at his desk, or outside on the chalk board in our shed, or on napkins, notepads or anything he could get his hands on at restaurants; but more likely than not, away. When I was young, my father was becoming the researcher that today makes him a three-time Presidential honoree, a member of Barak Obama's Presidential Committee on the National Medal of Science, and of course, the purpose of this volume. Even in those early days, he was away a lot--either traveling to conferences or increasingly as an invited lecturer, or at the office. Of course, I was still (and am) a daddy's little girl, bonded forever by a shared obsession with the same movies (The Godfather, My Name is Nobody, The Man from Snowy River); the same TV shows (Law and Order); and all things sports related, but I also knew that my father was a very busy man and his time was limited. So I would watch him work, often with my own little extra homework he would give me to keep me entertained, peck him on the check and let him know that I would take over his job when I was old enough.

  4. FORSPAN Model Users Guide

    Science.gov (United States)

    Klett, T.R.; Charpentier, Ronald R.

    2003-01-01

    The USGS FORSPAN model is designed for the assessment of continuous accumulations of crude oil, natural gas, and natural gas liquids (collectively called petroleum). Continuous (also called ?unconventional?) accumulations have large spatial dimensions and lack well defined down-dip petroleum/water contacts. Oil and natural gas therefore are not localized by buoyancy in water in these accumulations. Continuous accumulations include ?tight gas reservoirs,? coalbed gas, oil and gas in shale, oil and gas in chalk, and shallow biogenic gas. The FORSPAN model treats a continuous accumulation as a collection of petroleumcontaining cells for assessment purposes. Each cell is capable of producing oil or gas, but the cells may vary significantly from one another in their production (and thus economic) characteristics. The potential additions to reserves from continuous petroleum resources are calculated by statistically combining probability distributions of the estimated number of untested cells having the potential for additions to reserves with the estimated volume of oil and natural gas that each of the untested cells may potentially produce (total recovery). One such statistical method for combination of number of cells with total recovery, used by the USGS, is called ACCESS.

  5. Solid-phase photocatalytic degradation of polyethylene film with manganese oxide OMS-2

    Science.gov (United States)

    Liu, Guanglong; Liao, Shuijiao; Zhu, Duanwei; Cui, Jingzhen; Zhou, Wenbing

    2011-01-01

    Solid-phase photocatalytic degradation of polyethylene (PE) film with cryptomelane-type manganese oxide (OMS-2) as photocatalyst was investigated in the ambient air under ultraviolet and visible light irradiation. The properties of the composite films were compared with those of the pure PE film through performing weight loss monitoring, IR spectroscopy, scanning electron microscopic (SEM) and X-ray photoelectron spectroscopy (XPS). The photoinduced degradation of PE-OMS-2 composite films was higher than that of the pure films, while there has been little change under the visible light irradiation. The weight loss of PE-OMS-2 (1.0 wt%) composite films steadily decreased and reached 16.5% in 288 h under UV light irradiation. Through SEM observation there were some cavities on the surface of composite films, but few change except some surface chalking phenomenon occurred in pure PE film. The degradation rate with ultraviolet irradiation is controllable by adjusting the content of OMS-2 particles in PE plastic. Finally, the mechanism of photocatalytic degradation of the composite films was briefly discussed.

  6. A laboratory assessment of the Waveband Integrated Bioaerosol Sensor (WIBS-4) using individual samples of pollen and fungal spore material

    Science.gov (United States)

    Healy, David A.; O'Connor, David J.; Burke, Aoife M.; Sodeau, John R.

    2012-12-01

    A Bioaerosol sensing instrument referred to as WIBS-4, designed to continuously monitor ambient bioaerosols on-line, has been used to record a multiparameter “signature” from each of a number of Primary Biological Aerosol Particulate (PBAP) samples found in air. These signatures were obtained in a controlled laboratory environment and are based on the size, asymmetry (“shape”) and auto-fluorescence of the particles. Fifteen samples from two separate taxonomic ranks (kingdoms), Plantae (×8) and Fungi (×7) were individually introduced to the WIBS-4 for measurement along with two non-fluorescing chemical solids, common salt and chalk. Over 2000 individual-particle measurements were recorded for each sample type and the ability of the WIBS spectroscopic technique to distinguish between chemicals, pollen and fungal spore material was examined by identifying individual PBAP signatures. The results obtained show that WIBS-4 could potentially be a very useful analytical tool for distinguishing between natural airborne PBAP samples, such as the fungal spores and may potentially play an important role in detecting and discriminating the toxic fungal spore, Aspergillus fumigatus, from others in real-time. If the sizing range of the commercial instrument was customarily increased and permitted to operate simultaneously in its two sizing ranges, pollen and spores could potentially be discriminated between. The data also suggest that the gain setting sensitivity on the detector would also have to be reduced by a factor >5, to routinely detect, in-range fluorescence measurements for pollen samples.

  7. First-principles investigation of boron incorporation into CRUD under Pressurized Water Reactor conditions

    Science.gov (United States)

    Rak, Zs.; O'Brien, C. J.; Brenner, D. W.

    2014-03-01

    CRUD (Chalk River Unidentified Deposit) is predominately a nickel-ferrite deposit on hot surfaces of nuclear fuel rods during reactor operation. The presence of CRUD modifies the core-coolant heat transfer and can induce localized corrosion on the cladding surface. Besides these unwanted effects boron, which is a neutron absorber, can accumulate within the CRUD, triggering shifts in the neutron flux and fluctuations in the reactor power level. Therefore, it is crucial to understand and predict the mechanisms by which B is trapped into the CRUD. As a first step, the incorporation of B defect into the crystal structure of NiFe2O4 has been investigated using the DFT framework. To obtain the formation energies of various interstitial and substitutional B-defects, theoretical results have been combined with experimental thermo-chemical data. Assuming solid-solid equilibrium conditions, the main factors that limit the incorporation of B are (i) the narrow stability domain of the host NiFe2O4 and (ii) the formation of ternary Fe-B-O and Ni-B-O compounds. The study also investigates the incorporation of B assuming solid-liquid equilibrium between NiFe2O4 and the surrounding aqueous solution under conditions of pressure, temperature, and pH characteristic to pressurized water reactors.

  8. Lithostratigraphy of the Palaeogene – Lower Neogene succession of the Danish North Sea

    Directory of Open Access Journals (Sweden)

    Rasmussen, Jan A.

    2007-06-01

    Full Text Available As a result of a lithological, sedimentological and biostratigraphic study of well sections from the Danish sector of the North Sea, including some recently drilled exploration wells on the Ringkøbing–Fyn High, the lithostratigraphic framework for the siliciclastic Palaeogene to Lower Neogene sediments of the Danish sector of the North Sea is revised. The sediment package from the top of the Chalk Group to the base of the Nordland Group is subdivided into seven formations containing eleven new members. The existing Våle, Lista, Sele, Fur, Balder, Horda and Lark Formations of previously published lithostratigraphic schemes are adequate for a subdivision of the Danish sector at formation level. Bor is a new sandstone member of the Våle Formation. The Lista Formation is subdivided into three new mudstone members: Vile, Ve and Bue, and three new sandstone members: Tyr, Idun and Rind. Kolga is a new sandstone member of the Sele Formation. Hefring is a new sandstone member of the Horda Formation. Freja and Dufa are two new sandstone members of the Lark Formation. Danish reference sections are established for the formations, and the descriptions of their lithology, biostratigraphy, age and palaeoenvironmental setting are updated.

  9. Importance and controls of anaerobic ammonium oxidation influenced by riverbed geology

    Science.gov (United States)

    Lansdown, K.; McKew, B. A.; Whitby, C.; Heppell, C. M.; Dumbrell, A. J.; Binley, A.; Olde, L.; Trimmer, M.

    2016-05-01

    Rivers are an important global sink for excess bioavailable nitrogen: they convert approximately 40% of terrestrial N runoff per year (~47 Tg) to biologically unavailable N2 gas and return it to the atmosphere. At present, riverine N2 production is conceptualized and modelled as denitrification. Anaerobic ammonium oxidation, known as anammox, is an alternative pathway of N2 production important in marine environments, but its contribution to riverine N2 production is not well understood. Here we use in situ and laboratory measurements of anammox activity using 15N tracers and molecular analyses of microbial communities to evaluate anammox in clay-, sand- and chalk-dominated river beds in the Hampshire Avon catchment, UK during summer 2013. Abundance of the hzo gene, which encodes an enzyme central to anammox metabolism, varied across the contrasting geologies. Anammox rates were similar across geologies but contributed different proportions of N2 production because of variation in denitrification rates. In spite of requiring anoxic conditions, anammox, most likely coupled to partial nitrification, contributed up to 58% of in situ N2 production in oxic, permeable riverbeds. In contrast, denitrification dominated in low-permeability clay-bed rivers, where anammox contributes roughly 7% to the production of N2 gas. We conclude that anammox can represent an important nitrogen loss pathway in permeable river sediments.

  10. A spectroscopic study of Brazilwood paints in medieval books of hours.

    Science.gov (United States)

    Melo, Maria João; Otero, Vanessa; Vitorino, Tatiana; Araújo, Rita; Muralha, Vânia S F; Lemos, Ana; Picollo, Marcello

    2014-01-01

    In this work, microspectrofluorimetry was for the first time applied to the identification of the red organic lakes that are characteristic of the lavish illuminations found in 15(th) century books of hours. Microspectrofluorimetry identified those red paints, ranging from opaque pink to dark red glazes, as brazilwood lakes. An unequivocal characterization was achieved by comparison with reference paints produced following recipes from the medieval treatise The Book on How to Make Colours, and was further confirmed by fiber optic reflectance spectroscopy (FORS). For these treasured cultural objects, microspectrofluorimetry and FORS proved to be the only techniques that could identify, in situ or in microsamples, the chromophore responsible for the pinkish hues: a brazilein-Al(3+) complex. Additionally, a multi-analytical approach provided a full characterization of the color paints, including pigments, additives, and binders. Microspectroscopic techniques, based on infrared and X-ray radiation, enabled us to disclose the full palette of these medieval manuscripts, including the elusive greens, for which, besides malachite, basic copper sulfates were found; Raman microscopy suggested a mixture of brochantite and langite. Infrared analysis proved invaluable for a full characterization of the additives that were applied as fillers or whites (chalk, gypsum, and white lead) as well as the proteinaceous and polysaccharide binders that were found pure or in mixture.

  11. Integrating research & teaching: the Queen Mary, University of London module in Geodiversity & Geoconservation

    Science.gov (United States)

    Gray, M.

    2012-04-01

    The School of Geography at Queen Mary, University of London has been running a Level 6 (undergraduate) module in "Geodiversity & Geoconservation" since 2004. The course is based around the book Geodiversity: valuing and conserving abiotic nature (John Wiley, 2004) but lectures are used to update each topic based on the latest research. The course is divided into 5 parts: 1. Defining and describing geodiversity - which discusses the concept of geodiversity, its definition and the nature of the geodiversity of Planet Earth; 2. Values of, and threats to, geodiversity - a lecture on valuing geodiversity is now based around important research on the role of geodiversity in "ecosystem services" assessments. A second lecture covers the major threats to geodiversity; 3. The protected area approach - lectures here cover geological World Heritage Sites, Global Geoparks, GSSPs, and national geoconservation systems in the UK, USA and other parts of the world; 4. Protecting geodiversity in the wider landscape - the contribution of geology and geomorphology to landscape character are described, together with the role of land-use planning and policy-making in protecting geodiversity. 5. Putting it all together - lectures here emphasize that geodiversity is an important basis for geoconservation, that different geoconservation methods are appropriate to different elements of geodiversity, and that integrated geo/bio conservation is essential. A field trip to three Chalk/Quaternary Sites of Special Scientific Interest in East Sussex is included which discusses some of the planning issues that have arisen at these sites, a theme that is expanded in the lectures.

  12. Progress report - Physical and Environmental Sciences - Physics Division, 1995 January 1 to December 31

    Energy Technology Data Exchange (ETDEWEB)

    Harvey, M. (ed.)

    1996-05-01

    This document is a Progress Report for the Physical and Environmental Sciences, Physics Division, for the period 1995 January 1 to December 31, at the Chalk River nuclear Labs. The condensed matter science group continued to operate a multi-faceted program involving collaborative basic and applied research with external scientists in the fields of materials science, physics, chemistry and biology. The Applied Neutron Diffraction for Industry (And) program gained strength with ever wider applications for the nuclear, aerospace, and manufacturing programs. Steps continued towards making neutron scattering facilities at NRU reactor more user friendly. The neutrino physics group, as part of the Sudbury Neutrino Observatory (SNO) Institute, collaborating with scientists from Canada, USA and UK. The accelerator physics group spent considerable effort working with materials and fuels scientists to show the value of accelerators as an out-reactor source of radiation. Specific research activities have included the demonstration of laser plasma deposition of diamond coating, which has potential application for high-wear components in reactors, and the study for a Free Electron Laser upgrade for the IMPELA accelerator. As a result of funding reduction all programs of the Division were dissolved as of 1997 March 31.

  13. Photogrammetric Measurements of an EH-60L Brownout Cloud

    Science.gov (United States)

    Wong, Oliver D.; Tanner, Philip E.

    2010-01-01

    There is a critical lack of quantitative data regarding the mechanism of brownout cloud formation. Recognizing this, tests were conducted during the Air Force Research Lab 3D-LZ Brownout Test at the US Army Yuma Proving Ground. Photogrammetry was utilized during two rounds of flight tests with an instrumented EH-60L Black Hawk to determine if this technique could quantitatively measure the formation and evolution of a brownout cloud. Specific areas of interest include the location, size, and average convective velocity of the cloud, along with the characteristics of any defined structures within it. Following the first flight test, photogrammetric data were validated through comparison with onboard vehicle data. Lessons learned from this test were applied to the development of an improved photogrammetry system. A second flight test, utilizing the improved system, demonstrated that obtaining quantitative measurements of the brownout cloud are possible. Results from these measurements are presented in the paper. Flow visualization with chalk dust seeding was also tested. It was observed that pickup forces of the brownout cloud appear to be very low. Overall, these tests demonstrate the viability of photogrammetry as a means for quantifying brownout cloud formation and evolution.

  14. Engaging the audience: developing presentation skills in science students.

    Science.gov (United States)

    Stuart, Ann E

    2013-01-01

    This article describes a graduate class in presentation skills ("PClass") as a model for how a class with similar objectives, expectations and culture might be mounted for undergraduates. The required class is given for students in neuroscience and physiology programs at the University of North Carolina at Chapel Hill; I describe the class in the years I led it, from 2003-2012. The class structure centered on peer rehearsal, critiquing of PowerPoint, and chalk talks by the students; video-recording of student talks for later review by the student with the instructor; and presentation of polished talks in a formal setting. A different faculty visitor to the class each week gave the students a variety of perspectives. The students also gained insight into their own evolving skills by discussing the strengths and weaknesses of seminars given by visitors to the campus. A unique feature of the class was collaboration with a professional actor from the University's Department of Dramatic Arts, who helped the students develop techniques for keeping the attention of an audience, for speaking with confidence, and for controlling nervousness. The undergraduate campus would be expected to lend itself to this sort of interdisciplinary faculty cooperation. In addition, students worked on becoming adept at designing and presenting posters, introducing speakers graciously and taking charge of the speaker's question session, and speaking to a lay audience.

  15. Determination of early warning signs for photocatalytic degradation of titanium white oil paints by means of surface analysis

    Science.gov (United States)

    van Driel, B. A.; Wezendonk, T. A.; van den Berg, K. J.; Kooyman, P. J.; Gascon, J.; Dik, J.

    2017-02-01

    Titanium white (TiO2) has been widely used as a pigment in the 20th century. However, its most photocatalytic form (anatase) can cause severe degradation of the oil paint in which it is contained. UV light initiates TiO2-photocatalyzed processes in the paint film, degrading the oil binder into volatile components resulting in chalking of the paint. This will eventually lead to severe changes in the appearance of a painting. To date, limited examples of degraded works of art containing titanium white are known due to the relatively short existence of the paintings in question and the slow progress of the degradation process. However, UV light will inevitably cause degradation of paint in works of art containing photocatalytic titanium white. In this work, a method to detect early warning signs of photocatalytic degradation of unvarnished oil paint is proposed, using atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). Consequently, a four-stage degradation model was developed through in-depth study of TiO2-containing paint films in various stages of degradation. The XPS surface analysis proved very valuable for detecting early warning signs of paint degradation, whereas the AFM results provide additional confirmation and are in good agreement with bulk gloss reduction.

  16. Reactive flow simulations: one-to-one comparison with experiments

    Science.gov (United States)

    Vinningland, Jan Ludvig; Neuville, Amelie; Pedersen, Janne; Jettestuen, Espen; Dysthe, Dag Kristian; Hiorth, Aksel

    2014-05-01

    Direct in-situ observations of structural changes in the pore space of porous rocks during reactive flow provide valuable insights into the pore scale mechanisms that govern mineral growth, changes in wetting properties and increased oil recovery. We present simulations of single-phase reactive flow in micrometer sized channels in a calcite (CaCO3) crystal and compare mineralogical and geometrical changes in the numerical results to experimental in-situ observations made with the same flow geometry and reactive fluids. This enables a rigorous test of the numerical model and a method for determining kinetic rate constants that will be used in simulations of reactive flow in chalk geometries. The numerical model is a lattice Boltzmann model (LBM) that moves a set of chemical basis species through the pore space by advection and diffusion. A chemical solver with general kinetic expressions is coupled to the LBM via mass fluxes at the solid-fluid interface. The mineralogy of the solid is described by scalar fields, each representing a mineral phase. The rate of dissolution or precipitation of a mineral depends on the local chemical disequilibrium and on a kinetic rate constant specific to each mineral.

  17. Biotechnology of intensive aerobic conversion of sewage sludge and food waste into fertilizer

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.-Y.; Stabnikova, O.; Show, K.-Y.; Ding, H.-B.; Tay, S.T.-L.; Ivanov, V.; Tay, J.-H.

    2003-07-01

    Biotechnology for intensive aerobic bioconversion of sewage sludge and food waste into fertilizer was developed. The wastes were treated in a closed reactor under controlled aeration, stirring, pH, and temperature at 60{sup o}C, after addition of starter bacterial culture Bacillus thermoamylovorans. The biodegradation of sewage sludge was studied by decrease of volatile solids (VS), content of organic carbon and autofluorescence of coenzyme F{sub 420}. The degradation of anaerobic biomass was faster than biodegradation of total organic matter. The best fertilizer was obtained when sewage sludge was thermally pre-treated, mixed with food waste, chalk, and artificial bulking agent. The content of volatile solid and the content of organic carbon decreased at 24.8% and 13.5% of total solids, respectively, during ten days of bioconversion. The fertilizer was a powder with moisture content of 5%. It was stable, and not toxic for the germination of plant seeds. Addition of 1.0 to 1.5% of this fertilizer to the subsoil increased the growth of different plants tested by 113 to 164 %. The biotechnology can be applied in larger scale for the recycling of sewage sludge and food wastes in Singapore. (author)

  18. Evaluation of the accuracy and precision three-dimensional sterotactic breast biopsy

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Mi Hwa [Dept. of Health Care, Hanseo University, Seosan (Korea, Republic of)

    2015-09-15

    This research was study the accuracy of three dimensional stereotactic breast biopsy, using a core Needle Biopsy and to assess the accuracy of Stereotactic biopsy and Sono guided biopsy. Using Stereotactic QC phantom to measure the accuracy of the 3D sterotactic machine. CT Scan and equipment obtained in the measured X, Y, Z and compares the accuracy of the length. Using Agar power phantom compare the accuracy of the 3D sterotactic machine and 2D ultrasound machine. Z axis measured by the equipment to compare the accuracy and reliability. Check the accuracy by using visual inspection and Specimen Medical application phantom. The accuracy of the 3D sterotactic machine measured by Stereotactic QC phantom was 100%. Accuracy as compared to CT, all of X, Y, Z axis is p > 0.05. The accuracy of the two devices was 100% as measured by Agar powder phantom. There was no difference between the two devices as CT and p > 0.05. 3D sterotactic machine of the ICC was 0.954, 2D ultrasound machine was 0.785. 2D ultrasound machine was different according to the inspector. Medical application phantom experiments in 3D sterotactic machine could not find the Sliced boneless ham. 2D ultrasound machine has not been able to find a small chalk powder group. The reproducibility of the three dimensional stereotactic breast biopsy was better than effect of Sono guided biopsy.

  19. 浅谈体验式教学在小学数学课中的运用%Application of the Experience Teaching in the Elementary School Maths Class

    Institute of Scientific and Technical Information of China (English)

    姚遥

    2012-01-01

    For a long time, the elementary school maths teachers basically take the "chalk and talk" approach. Faced with this situation, we must vigorously strengthen the launching of experience teaching elementary school mathematics classroom. In this paper, the analysis of the definition of experiential teaching, theoretical basis, based on model construction, combined with the author's the frontline teaching practice experience, to summarize experience teaching in primary school mathematics curriculum practices, such as hands, to experience, the creation of scenarios, and stimulate imagine.%长期以来,小学数学课的教师基本上采取“满堂灌”的方式。面对这一现状,我们必须大力加强体验式教学在小学数学课堂中的开展。本文在分析体验式教学的定义、理论依据、模式建构的基础上,并结合笔者一线的教学实践经验。总结体验式教学在小学数学课程的实践方法,例如亲手操作、亲身体验,创立情景、激发想象。

  20. Radium contamination in the Nizzana-1 water well, Negev Desert, Israel

    Energy Technology Data Exchange (ETDEWEB)

    Minster, T. E-mail: tsevi.minster@mail.gsi.gov.il; Ilani, S.; Kronfeld, J.; Even, O.; Godfrey-Smith, D.I

    2004-07-01

    In a search for fresh groundwater reserves in the northwestern Negev Desert of Israel, the Nizzana-1 water well drilled into the Judea Group aquifer encountered water that exhibits an anomalously high {sup 226}Ra activity of 2.4 Bq/l, along with 133 Bq/l {sup 222}Rn. The exploited well water is a mixture of the original Judea Group aquifer water and the underlying more saline artesian water of the Kurnub Group (or Nubian Sandstone) aquifer that is currently intruding via faults. Both aquifers elsewhere contain intrinsically low radioactivity. A study of the sedimentary sequence transected by the borehole revealed that much of the bituminous sequence of the Mount Scopus Group of Upper Cretaceous age is substantially depleted in {sup 226}Ra. During its ascent, the Nubian Sandstone water flushes the moderately uranium enriched bituminous sediments, selectively leaching radium and/or receiving alpha-recoil additions of radium. These bituminous chalks and marls are regionally widespread. It is thus suggested that radium should be monitored where faulting allows for inter-aquiferial connections across uranium enriched bituminous sections.

  1. Innovative methods of knowledge transfer by multimedia library

    Science.gov (United States)

    Goanta, A. M.

    2016-08-01

    The present situation of teaching and learning new knowledge taught in the classroom is highly variable depending on the specific topics concerned. If we analyze the manifold ways of teaching / learning at university level, we can notice a very good combination between classical and modern methods. The first category includes the classic chalk blackboard teaching, followed by the also classical learning based on paper reference material. The second category includes books published in PDF or PPT [1], which are printed on the type backing CD / DVD. Since 2006 the author was concerned about the transfer of information and knowledge through video files like AVI, FLV or MPEG using various means of transfer, from the free ones (via Internet) and continuing with those involving minimal costs, i.e. on CD / DVD support. Encouraged by the students’ interest in this kind of teaching material as proved by monitoring [2] the site http://www.cursuriuniversitarebraila.ugal.ro, the author has managed to publish with ISBN the first video book in Romania, which has a non conformist content in that the chapters are located not by paging but by the hour or minutes of shooting when they were made.

  2. Class Explorations in Space: From the Blackboard and History to the Outdoors and Future

    Science.gov (United States)

    Cavicchi, Elizabeth

    2011-11-01

    Our everyday activities occur so seamlessly in the space around us as to leave us unawares of space, its properties, and our use of it. What might we notice, wonder about and learn through interacting with space exploratively? My seminar class took on that question as an opening for personal and group experiences during this semester. In the process, they observe space locally and in the sky, read historical works of science involving space, and invent and construct forms in space. All these actions arise responsively, as we respond to: physical materials and space; historical resources; our seminar participants, and future learners. Checks, revisions and further developments -- on our findings, geometrical constructions, shared or personal inferences---come about observationally and collaboratively. I teach this seminar as an expression of the research pedagogy of critical exploration, developed by Eleanor Duckworth from the work of Jean Piaget, B"arbel Inhelder and the Elementary Science Study. This practice applies the quest for understanding of a researcher to spontaneous interactions evolving within a classroom. The teacher supports students in satisfying and developing their curiosities, which often results in exploring the subject matter by routes that are novel to both teacher and student. As my students ``mess about'' with geometry, string and chalk at the blackboard, in their notebooks, and in response to propositions in Euclid's Elements, they continually imagine further novel venues for using geometry to explore space. Where might their explorations go in the future? I invite you to hear from them directly!

  3. Guidelines for random excitation forces due to cross flow in steam generators

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, C.E.; Pettigrew, M.J. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    1998-07-01

    Random excitation forces can cause low-amplitude tube motion that will result in long-term fretting-wear or fatigue. To prevent these tube failures in steam generators and other heat exchangers, designers and trouble-shooters must have guidelines that incorporate random or turbulent fluid forces. Experiments designed to measure fluid forces have been carried out at Chalk River Laboratories and at other labs around the world. The data from these experiments have been studied and collated to determine suitable guidelines for random excitation forces. In this paper, a guideline for random excitation forces in single-phase cross flow is presented in the form of normalised spectra that are applicable to a wide range of flow conditions and tube frequencies. In particular, the experimental results used in this study were carried out over the full range of flow conditions found in a nuclear steam generator. The proposed guidelines are applicable to steam generators, condensers, reheaters and other shell-and-tube heat exchangers. They may be used for flow-induced vibration analysis of new or existing components, as input to vibration analysis computer codes and as specifications in procurement documents. (author)

  4. Reconstructing 3D coastal cliffs from airborne oblique photographs without ground control points

    Science.gov (United States)

    Dewez, T. J. B.

    2014-05-01

    Coastal cliff collapse hazard assessment requires measuring cliff face topography at regular intervals. Terrestrial laser scanner techniques have proven useful so far but are expensive to use either through purchasing the equipment or through survey subcontracting. In addition, terrestrial laser surveys take time which is sometimes incompatible with the time during with the beach is accessible at low-tide. By comparison, structure from motion techniques (SFM) are much less costly to implement, and if airborne, acquisition of several kilometers of coastline can be done in a matter of minutes. In this paper, the potential of GPS-tagged oblique airborne photographs and SFM techniques is examined to reconstruct chalk cliff dense 3D point clouds without Ground Control Points (GCP). The focus is put on comparing the relative 3D point of views reconstructed by Visual SFM with their synchronous Solmeta Geotagger Pro2 GPS locations using robust estimators. With a set of 568 oblique photos, shot from the open door of an airplane with a triplet of synchronized Nikon D7000, GPS and SFM-determined view point coordinates converge to X: ±31.5 m; Y: ±39.7 m; Z: ±13.0 m (LE66). Uncertainty in GPS position affects the model scale, angular attitude of the reference frame (the shoreline ends up tilted by 2°) and absolute positioning. Ground Control Points cannot be avoided to orient such models.

  5. A Novel Architecture for Intrusion Detection in Mobile Ad hoc Network

    Directory of Open Access Journals (Sweden)

    Atul Patel

    2011-08-01

    Full Text Available Today’s wireless networks are vulnerable in many ways including illegal use, unauthorized access, denial of service attacks, eavesdropping so called war chalking. These problems are one of the main issues for wider uses of wireless network. On wired network intruder can access by wire but in wireless it has possibilities to access the computer anywhere in neighborhood. However, securing MANETs is highly challenging issue due to their inherent characteristics. Intrusion detection is an important security mechanism, but little effort has been directed towards efficient and effective architectures for Intrusion Detection System in the context of MANETs. We investigate existing Intrusion Detection Architecture design Issues, challenges and proposed a novel architecture based on a conceptual model for an IDS agent that lead to a secure collaboration environment integrating mobile ad hoc network and the wired backbone. In wireless/mobile ad hoc network, the limited power, weak computation capabilities of mobile nodes, and restricted bandwidth of the open media impede the establishment of a secure collaborative environment.

  6. Technological foundations of processing tomato pomace in feed additives

    Directory of Open Access Journals (Sweden)

    B. Yegorov

    2015-05-01

    Full Text Available Introduction. Search for new types of alternative raw material for the efficient development of poultry industry and problem of waste disposal of canning industry made it necessary to develop a method of processing tomato pomace in feed additives. Materials and methods. Sampling, preparation and testing were carried out by general and specific organ oleptic and physical-technological methods of assessment and analysis of the properties of raw materials and finished products. Results. Incorporation of tomato pomace in the feed additive reduces the cost of raw materials and expenses associated with moistening of the mixture before extrusion and incorporation of chalk feed will solve the problem of calcium imbalance of laying hens. It was found that extrusion process has improved the physical properties of feed additive and showed the possibility of its use as a feed component: moisture content decreased by 34.5 %, the angle of repose increased by 11.4 %, flowability decreased by 39.7 % and bulk density decreased by 32.3 %. Conclusions. The resulting feed additive will solve the problem of diversification of raw materials, waste, calcium imbalance of laying hens and reduce expenses on compound animal feedstuff production.

  7. [Pica--a historical "eating disorder"].

    Science.gov (United States)

    Zedlitz, Kathrin

    2010-01-01

    Pica, or the intentional consumption of things commonly considered as inedible, is a very old phenomenon. Between the 16th and 18th centuries it aroused widespread popular interest. It also was the subject of numerous medical treaties and intensive scientific research. At that time cravings for substances like chalk, soil or paper were discussed as a medical condition typically affecting young girls and pregnant women. Contemporary doctors developed theories about the disease and its genesis. Their publications reflect the commonly accepted medical knowledge of that time, religious beliefs and prevailing ideas as to possible therapies. In the course of time the view of Pica changed. There were new perceptions of this eating disorder among the doctors and its importance declined. Contrary to former times, today the medical and social interest in strange cravings is almost insignificant. The consumption of things commonly considered as inedible is seen as a very rare symptom that can be found mainly with people with psychological problems or mental deficiencies. This paper gives an overview of Pica as a typical disease of women between the 16th and 18th centuries. Besides it shows the historical development of a medical phenomenon up to the present, which has been strongly influenced by the cultural conditions of the respective societies.

  8. Characteristics of pica practice during pregnancy in a sample of Argentine women.

    Science.gov (United States)

    López, L B; Marigual, M; Martín, N; Mallorga, M; Villagrán, E; Zadorozne, M E; Martín De Portela, M L P; Ortega Soler, C R

    2012-02-01

    The purpose of this study was to describe the practice of pica during pregnancy in Argentine women. Maternal and fetal characteristics as well as the practice of pica were evaluated during the puerperium in a sample of 1,014 women from five different geographical areas. Pica prevalence for the total sample was 23.2% (95% CI 20.6-25.8). Pagophagia (ice consumption) was the main type of pica practice, followed by geophagia (earth intake) and the ingestion of soap, toothpaste and chalk. The onset of the practice was mainly in the first months of pregnancy. A total of 49.8% of women revealed a family history of pica; 30.6% had pica in childhood and 13.2% suffered from polypica. Women with pica during pregnancy had similar age, pre-pregnancy body mass index (BMI), parity, neonatal birth weight and gestational age compared with non-pica mothers, although maternal haemoglobin concentration was lower in women with pica than in non-pica mothers (p = 0.0001).

  9. Diachronism between extinction time of terrestrial and marine dinosaurs

    Science.gov (United States)

    Hansen, H. J.

    1988-01-01

    The dinosaur eggs of southern France occur in continental, fine-grained red-beds, rich in carbonate. The last eggs in the region occur in the magnetic polarity interval 30 normal. Estimates of the accumulation rate of these sediments on the basis of the magneto-stratigraphy leads to placement of the time of disappearance of the dinosaurs in this region of 200,000 to 400,000 years earlier than the Cretaceous-Tertiary boundary. In the Red Deer Valley, Canada, estimates of average accumulation rate lead to a time of disappearance of the dinosaurs of 135,000 to 157,000 years earlier than the Cretaceous-Tertiary boundary. In the central part of Poland, in the Nasilow Quarry, the paleomagnetic pattern shows 7 m of chalk of reversed polarity containing in its upper part the marine Cretaceous-Tertiary biostratigraphic boundary. A greensand deposit contains numerous re-deposited Maastrichtian fossils. The fossils show no signs of wear and are of very different sizes including 1 mm thick juvenile belemnites. The deposit was described as a lag-sediment. Among the various fossils are teeth of mosasaurs. Thus there is coincidence in time between the extinction of mosasaurs and other Cretaceous organisms. This leads to the conclusion, that extinction of terrestrial dinosaurs took place earlier than extinction of marine dinosaurs at the Cretaceous-Tertiary boundary.

  10. First principles model of carbonate compaction creep

    Science.gov (United States)

    Keszthelyi, Daniel; Dysthe, Dag Kristian; Jamtveit, Bjørn

    2016-05-01

    Rocks under compressional stress conditions are subject to long-term creep deformation. From first principles we develop a simple micromechanical model of creep in rocks under compressional stress that combines microscopic fracturing and pressure solution. This model was then upscaled by a statistical mechanical approach to predict strain rate at core and reservoir scale. The model uses no fitting parameter and has few input parameters: effective stress, temperature, water saturation porosity, and material parameters. Material parameters are porosity, pore size distribution, Young's modulus, interfacial energy of wet calcite, the dissolution, and precipitation rates of calcite, and the diffusion rate of calcium carbonate, all of which are independently measurable without performing any type of deformation or creep test. Existing long-term creep experiments were used to test the model which successfully predicts the magnitude of the resulting strain rate under very different effective stress, temperature, and water saturation conditions. The model was used to predict the observed compaction of a producing chalk reservoir.

  11. A combined Raman microscopy, XRF and SEM-EDX study of three valuable objects - A large painted leather screen and two illuminated title pages in 17th century books of ordinances of the Worshipful Company of Barbers, London

    Science.gov (United States)

    Chaplin, Tracey D.; Clark, Robin J. H.; Martinón-Torres, Marcos

    2010-07-01

    Raman microscopy has been used to identify the pigments decorating three valuable items owned by the Worshipful Company of Barbers (established in 1308 in London), one being a large leather screen dating to before 1712, the other two being illuminated title pages of books of ordinances of the Company dating to 1605 and 1658. Pigments which could not be fully characterised by this technique (particularly the green paints) have also been subject to XRF or SEM-EDX analysis. The combined analytical approach has shown that the pigments identified on all three items are typical of those in use as artists' pigments in the 17th C and include azurite, indigo, vermilion, red lead, pink and yellow lakes, verdigris, lead white, calcite (and chalk), gypsum, carbon-based black, and gold and silver leaf. However in the case of the screen alone, restoration in the 1980s has been carried out with different pigments - haematite, phthalocyanine green, rutile, and a mixture of azurite, malachite and barium sulfate. This work constitutes the first in-depth study of painted leatherwork and demonstrates that the palette used for this purpose is similar to that used on other works of art of the same date. It has also allowed the original colour schemes of the decorations to be determined where pigment degradation has occurred. The combined analysis has also provided a more complete understanding of the materials used for, or on, objects to which access is limited.

  12. Investigation on laser accelerators. Plasma beat wave accelerators

    Energy Technology Data Exchange (ETDEWEB)

    Miura, Akihiko; Miyamoto, Yasuaki; Hagiwara, Masayoshi; Suzuki, Mitsutoshi; Sudo, Osamu [Power Reactor and Nuclear Fuel Development Corp., Tokai, Ibaraki (Japan). Tokai Works

    1998-04-01

    Laser accelerator technology has characteristics of high energy, compact, short pulse and high luminescence{center_dot}low emittance. This means potential many applications in wide ranges of fields as well as high energy and nuclear physics. High power short laser pulses are injected to a plasma in the typical example of laser accelerators. Large electric fields are induced in the plasma. Electrons in the plasma are accelerated with the ponderomotive force of the electric field. The principles of interaction on beat wave, wakefield accelerators, inverse free electron laser and inverse Cherenkov radiation are briefly introduced. The overview of plasma beat wave accelerator study is briefly described on the programs at Chalk River Laboratories(Canada), UCLA(USA), Osaka Univ. (Japan) and Ecole Polytechnique (France). Issues of the plasma beat wave accelerator are discussed from the viewpoint of application. Existing laser technologies of CO{sub 2}, YAG and YFL are available for the present day accelerator technology. An acceleration length of beat wave interaction is limited due to its phase condition. Ideas on multi-staged acceleration using the phasing plasma fiber are introduced. (Y. Tanaka)

  13. A constitutive model for bonded geomaterials subject to mechanical and/or chemical degradation

    Science.gov (United States)

    Nova, R.; Castellanza, R.; Tamagnini, C.

    2003-08-01

    The mechanical behaviour of bonded geomaterials is described by means of an elastoplastic strain-hardening model. The internal variables, taking into account the history of the material, depend on the plastic strains experienced and on a conveniently defined scalar measure of damage induced by weathering and/or chemical degradation.For the sake of simplicity, it is assumed that only internal variables are affected by mechanical and chemical history of the material. Despite this simplifying assumption, it can be shown that many interesting phenomena exhibited by weathered bonded geomaterials can be successfully described. For instance, (i) the transition from brittle to ductile behaviour with increasing pressure of a calcarenite with collapsing internal structure, (ii) the complex behaviour of chalk and other calcareous materials in oedometric tests, (iii) the chemically induced variation of the stress and strain state of such kind of materials, are all phenomena that can be qualitatively reproduced. Several comparisons with experimental data show that the model can capture the observed behaviour also quantitatively.

  14. Cause of Corrosion Failure in Coated Steels and Protection%涂层钢腐蚀破坏的原因与防护

    Institute of Scientific and Technical Information of China (English)

    余存烨

    2014-01-01

    本文论述了工业环境下设备、管道与钢结构的涂层腐蚀破坏的各种类型,诸如粉化、变色、开裂、脱层、鼓泡、起皱、锈蚀等原因分析。并对涂层钢腐蚀破坏原因和防腐措施从环境介质因素、涂料选用因素、表面处理与涂敷施工因素等方面作了综合分析。%In this article, coating corrosion failure type in equipments、pipelines and steel structure in industry environment were described. Chalking, color, change, cracking, delaminating, blistering, wrinkling, rusting etc. were discussed. Cause of corrosion failure in coated steels and protection from environmental medium, coater selected using, surface treatment and coating technique etc factors were synthesize analyzed.

  15. Annual report 1997-1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    Atomic Energy of Canada Limited (AECL) was established in 1952 as a Crown Corporation and reports to parliament through the Minister of Natural Resources. As an annual report, financial statements are an integral element, financial analysis and review are also ongoing. AECL is very active in marketing the science culture which is key to public understanding and acceptance of the nuclear industry. In commercial operations, the CANDU is still the flagship to be marketed in many countries. AECL is the main producer of medical isotopes for the global market. AECL and MDS Nordion signed agreements to secure the ongoing supply of isotopes and to build and operate two MAPLE reactors at the Chalk River site. Activities at AECL are focused on improved economics, further enhanced safety systems and fuel cycle flexibility in the research and product development programs. Waste management and nuclear sciences i e. health and environmental sciences are ongoing studies. Site refurbishment focuses on replacing and refurbishing major facilities to meet business needs.

  16. Simulation studies to evaluate the effect of fracture closure on the performance of naturally fractured reservoirs. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    The first of a three-year research program to evaluate the effect of fracture closure on the recovery of oil and gas from naturally fractured reservoirs has been completed. The objectives of the study are to (1) evaluate the reservoir conditions where fracture closure is significant, and (2) evaluate innovative fluid injection techniques capable of maintaining pressure within the reservoir. Simulation studies were conducted with a dual porosity simulator capable of simulating the performance of vertical and horizontal wells. Each simulator was initialized using properties typical of the Austin Chalk reservoir in Pearsall Field, Texas. Simulations of both vertical and horizontal well performance were made assuming that fracture permeability was insensitive to pressure change. Sensitivity runs indicate that the simulator is predicting the effects of critical reservoir parameters in a logical and consistent manner. The results to-date confirm that horizontal wells can increase both oil recovery rate and total oil recovery from naturally fractured reservoirs. The year one simulation results will provide the baseline for the ongoing study which will evaluate the performance degradation caused by the sensitivity of fracture permeability to pressure change, and investigate fluid injection pressure maintenance as a means to improve oil recovery performance. The study is likely to conclude that fracture closure decreases oil recovery and that pressure support achieved through fluid injection could be beneficial in improving recovery.

  17. Predictions regarding the supply of 99Mo and 99mTc when NRU ceases production in 2018

    CERN Document Server

    Ross, C K

    2015-01-01

    The NRU reactor in Chalk River had been scheduled to stop producing medical isotopes by the end of 2016 but the Government of Canada recently announced that it will remain available to support isotope production until its operating license expires on 31 March, 2018. NRU has the capability of producing up to 80 % of the world's requirements for 99Mo but is presently producing less than 20 %. There are a number of initiatives underway, both within Canada and around the world, to find alternative ways of producing 99Mo or its daughter, 99mTc. We examine the status of the main proposals and conclude that it will be challenging for any of them to meet the required demand by the end of 2016. An additional year should be enough time for some of the proposals to complete the development of manufacturing facilities and achieve regulatory approval. It is likely that these operators will have enough production capability to make up for the shortfall when the NRU operating license expires.

  18. Reactivity impact of {sup 16}O thermal elastic-scattering nuclear data for some numerical and critical benchmark systems

    Energy Technology Data Exchange (ETDEWEB)

    Kozier, K. S.; Roubtsov, D. [AECL, Chalk River Laboratories, Chalk River, ON (Canada); Plompen, A. J. M.; Kopecky, S. [EC-JRC, Inst. for Reference Materials and Measurements, Retieseweg 111, 2440 Geel (Belgium)

    2012-07-01

    The thermal neutron-elastic-scattering cross-section data for {sup 16}O used in various modern evaluated-nuclear-data libraries were reviewed and found to be generally too high compared with the best available experimental measurements. Some of the proposed revisions to the ENDF/B-VII.0 {sup 16}O data library and recent results from the TENDL system increase this discrepancy further. The reactivity impact of revising the {sup 16}O data downward to be consistent with the best measurements was tested using the JENDL-3.3 {sup 16}O cross-section values and was found to be very small in MCNP5 simulations of the UO{sub 2} and reactor-recycle MOX-fuel cases of the ANS Doppler-defect numerical benchmark. However, large reactivity differences of up to about 14 mk (1400 pcm) were observed using {sup 16}O data files from several evaluated-nuclear-data libraries in MCNP5 simulations of the Los Alamos National Laboratory HEU heavy-water solution thermal critical experiments, which were performed in the 1950's. The latter result suggests that new measurements using HEU in a heavy-water-moderated critical facility, such as the ZED-2 zero-power reactor at the Chalk River Laboratories, might help to resolve the discrepancy between the {sup 16}O thermal elastic-scattering cross-section values and thereby reduce or better define its uncertainty, although additional assessment work would be needed to confirm this. (authors)

  19. Impact of ENDF/B-VII.0 for AECL applications

    Energy Technology Data Exchange (ETDEWEB)

    Kozier, Ken S.; Altiparmakov, Dimitar V. [AECL - Chalk River Laboratories, Chalk River (Canada)

    2008-07-01

    This paper examines the impact of the new evaluated nuclear data library ENDF/B-VII.0 on selected reactor physics applications at AECL. The twin objectives are to provide feedback to the nuclear data community concerning the practical impact of their work and preliminary guidance to end-users. This work is based on comparison of the results of MCNP simulations with critical measurements involving both the ZED-2 zero power reactor and the MAPLE dedicated isotope production reactors at the Chalk River Laboratories. Significant improvement in the reactivity agreement with the measurements is obtained with ENDF/B-VII.0 for the specific ZED-2 measurements analysed; however, improvements associated with the thermal scattering law data for UO{sub 2} that had been observed initially were subsequently determined to be fortuitous, due to the inadvertent omission of the elastic neutron scattering component. Additionally, the net reactivity impact of major changes to the {sup 90}Zr and {sup 91}Zr capture cross sections with ENDF/B-VII.0 is examined in the MAPLE reactor context and found to be modest due primarily to the offsetting effects of the specific nuclides involved. (authors)

  20. Assessment of evaluated (n,d) energy-angle elastic scattering distributions using MCNP simulations of critical measurements and simplified calculation benchmarks

    Energy Technology Data Exchange (ETDEWEB)

    Kozier, K.S. [Atomic Energy of Canada Limited, Chalk River Laboratories, Chalk River, Ontario (Canada)

    2008-07-01

    Different evaluated (n,d) energy-angle elastic scattering distributions produce k-effective differences in MCNP5 simulations of critical experiments involving heavy water (D{sub 2}O) of sufficient magnitude to suggest a need for new (n,d) scattering measurements and/or distributions derived from modern theoretical nuclear models, especially at neutron energies below a few MeV. The present work focuses on the small reactivity change of < 1 mk that is observed in the MCNP5 D{sub 2}O coolant-void-reactivity calculation bias for simulations of two pairs of critical experiments performed in the ZED-2 reactor at the Chalk River Laboratories when different nuclear data libraries are used for deuterium. The deuterium data libraries tested include Endf/B-VII.0, Endf/B-VI.4, JENDL-3.3 and a new evaluation, labelled Bonn-B, which is based on recent theoretical nuclear-model calculations. Comparison calculations were also performed for a simplified, two-region, spherical model having an inner, 250-cm radius, homogeneous sphere of UO{sub 2}, without and with deuterium, and an outer 20-cm-thick deuterium reflector. A notable observation from this work is the reduction of about 0.4 mk in the MCNP5 ZED-2 CVR calculation bias that is obtained when the O-in-UO{sub 2} thermal scattering data comes from Endf-B-VII.0. (author)