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Sample records for chain nonlinearity influence

  1. NONLINEAR EXPECTATIONS AND NONLINEAR MARKOV CHAINS

    Institute of Scientific and Technical Information of China (English)

    PENG SHIGE

    2005-01-01

    This paper deals with nonlinear expectations. The author obtains a nonlinear generalization of the well-known Kolmogorov's consistent theorem and then use it to construct filtration-consistent nonlinear expectations via nonlinear Markov chains. Compared to the author's previous results, i.e., the theory of g-expectations introduced via BSDE on a probability space, the present framework is not based on a given probability measure. Many fully nonlinear and singular situations are covered. The induced topology is a natural generalization of Lp-norms and L∞-norm in linear situations.The author also obtains the existence and uniqueness result of BSDE under this new framework and develops a nonlinear type of von Neumann-Morgenstern representation theorem to utilities and present dynamic risk measures.

  2. High Power Amplifiers Chain nonlinearity influence on the accelerating beam stability in free electron laser (FLASH)

    CERN Document Server

    Cichalewski, w

    2010-01-01

    The high power amplifiers transfer characteristics nonlinearities can have a negative influence on the overall system performance. This is also true for the TESLA superconducting cavities accelerating field parameters control systems. This Low Level Radio Frequency control systems uses microwave high power amplifiers (like 10 MW klystrons) as actuators in the mentioned feedback loops. The amplitude compression and phase deviations phenomena introduced to the control signals can reduce the feedback performance and cause electron beam energy instabilities. The transfer characteristics deviations in the Free Electron Laser in Hamburg experiment have been investigated. The outcome of this study together with the description of the developed linearization method based on the digital predistortion approach have been described in this paper. Additionally, the results from the linearization tool performance tests in the FLASH's RF systems have been placed.

  3. On nonlinear Markov chain Monte Carlo

    CERN Document Server

    Andrieu, Christophe; Doucet, Arnaud; Del Moral, Pierre; 10.3150/10-BEJ307

    2011-01-01

    Let $\\mathscr{P}(E)$ be the space of probability measures on a measurable space $(E,\\mathcal{E})$. In this paper we introduce a class of nonlinear Markov chain Monte Carlo (MCMC) methods for simulating from a probability measure $\\pi\\in\\mathscr{P}(E)$. Nonlinear Markov kernels (see [Feynman--Kac Formulae: Genealogical and Interacting Particle Systems with Applications (2004) Springer]) $K:\\mathscr{P}(E)\\times E\\rightarrow\\mathscr{P}(E)$ can be constructed to, in some sense, improve over MCMC methods. However, such nonlinear kernels cannot be simulated exactly, so approximations of the nonlinear kernels are constructed using auxiliary or potentially self-interacting chains. Several nonlinear kernels are presented and it is demonstrated that, under some conditions, the associated approximations exhibit a strong law of large numbers; our proof technique is via the Poisson equation and Foster--Lyapunov conditions. We investigate the performance of our approximations with some simulations.

  4. Nonlinear Excitation in a Ferrimagnetic Zigzag Chain

    Institute of Scientific and Technical Information of China (English)

    王为忠

    2003-01-01

    We study the nonlinear excitation(solitons)in a ferrimagnetic polymer chain by using a total Hamiltonian consisting of Su-Schrieffer-Heeger Hamiltonian and a Hubbard term.At half-filling,the distortion of lattices forms domain wall solitons,while the spin configuration forms envelope solitons.The soliton pair is obtained in a range of the electron-electron(e-e)interaction U,which depends on the electron-phonon(e-ph)interaction.The spin solitons corresponding to the left domain wall and the right domain wall of the displacement are quite different.

  5. Nonlinear dynamics of zigzag molecular chains (in Russian)

    DEFF Research Database (Denmark)

    Savin, A. V.; Manevitsch, L. I.; Christiansen, Peter Leth;

    1999-01-01

    Nonlinear, collective, soliton type excitations in zigzag molecular chains are analyzed. It is shown that the nonlinear dynamics of a chain dramatically changes in passing from the one-dimensional linear chain to the more realistic planar zigzag model-due, in particular, to the geometry-dependent...

  6. Short Pulse Dynamics in Strongly Nonlinear Dissipative Granular Chains

    OpenAIRE

    Rosas, Alexandre; Romero, Aldo H.; Nesterenko, Vitali F.; Lindenberg, Katja

    2008-01-01

    We study the energy decay properties of a pulse propagating in a strongly nonlinear granular chain with damping proportional to the relative velocity of the grains. We observe a wave disturbance that at low viscosities consists of two parts exhibiting two entirely different time scales of dissipation. One part is an attenuating solitary wave, is dominated by discreteness and nonlinearity effects as in a dissipationless chain, and has the shorter lifetime. The other is a purely dissipative sho...

  7. Towards chains of tunable and nonlinear superconducting microwave resonators

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Michael; Wulschner, Friedrich; Schaumburger, Udo; Haeberlein, Max; Fedorov, Kirill; Goetz, Jan; Xie, Edwar [Walther-Meissner-Institut, Bayerische Akademie der Wissenschaften, Garching (Germany); Physik-Department, TU Muenchen, Garching (Germany); Schwarz, Manuel; Eder, Peter; Menzel, Edwin; Zhong, Ling; Deppe, Frank; Gross, Rudolf [Walther-Meissner-Institut, Bayerische Akademie der Wissenschaften, Garching (Germany); Physik-Department, TU Muenchen, Garching (Germany); Nanosystems Initiative Munich (NIM), Muenchen (Germany); Marx, Achim [Walther-Meissner-Institut, Bayerische Akademie der Wissenschaften, Garching (Germany)

    2015-07-01

    We present an experimental feasibility study of chains of tunable and nonlinear superconducting microwave resonators within the realm of circuit QED. We describe the fabrication and experimental characterization of the components required to realize nonlinear resonators with tunable anharmonicity, capacitively coupled resonator chains and on-chip parallel plate capacitors. We discuss possible error sources in the fabrication and characterization processes. Furthermore, simulations based on existing theories are performed to identify accessible parameter ranges.

  8. Wavepacket delocalization, self-trapping and fragmentation in discrete chains with relaxing nonlinearity

    Science.gov (United States)

    Lima, R. P. A.; Gléria, Iram; Cícero, C. H.; Lyra, M. L.; de Moura, F. A. B. F.

    2017-03-01

    The discrete nonlinear Schrodinger equation (DNSE) describes wave phenomena in several physical contexts, ranging from electronic transport in crystalline chains to light propagation in nonlinear media and Bose-Einstein condensates. Here, we study the influence of the nonlinear response time on the temporal evolution of a wavepacket initially localized in a single site of a finite closed chain. Distinct long-time wavepacket distributions are identified as a function of the nonlinear strength χ and the characteristic relaxation time τ. Besides the more standard delocalized and self-trapped regimes, we report the occurrence of intermediate phases. In one of them the wavepacket self-focus in the opposite chain site. A phase with asymptotically fragmented wavepackets also develops. A crossover regime on which the ultimate wavepacket distribution is strongly dependent on the precise set of model parameters is also identified. We provide the full phase diagram related to the long-time wavepacket distribution in the (χ, τ) space.

  9. Short-pulse dynamics in strongly nonlinear dissipative granular chains.

    Science.gov (United States)

    Rosas, Alexandre; Romero, Aldo H; Nesterenko, Vitali F; Lindenberg, Katja

    2008-11-01

    We study the energy decay properties of a pulse propagating in a strongly nonlinear granular chain with damping proportional to the relative velocity of the grains. We observe a wave disturbance that at low viscosities consists of two parts exhibiting two entirely different time scales of dissipation. One part is an attenuating solitary wave, dominated by discreteness and nonlinearity effects as in a dissipationless chain, and has the shorter lifetime. The other is a purely dissipative shocklike structure with a much longer lifetime and exists only in the presence of dissipation. The range of viscosities and initial configurations that lead to this complex wave disturbance are explored.

  10. Low-frequency band gaps in chains with attached non-linear oscillators

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Jensen, Jakob Søndergaard

    2007-01-01

    in structures with periodic or random inclusions are located mainly in the high frequency range, as the wavelength has to be comparable with the distance between the alternating parts. Band gaps may also exist in structures with locally attached oscillators. In the linear case the gap is located around......The aim of this article is to investigate the wave propagation in one-dimensional chains with attached non-linear local oscillators by using analytical and numerical models. The focus is on the influence of non-linearities on the filtering properties of the chain in the low frequency range...

  11. Recombination Processes and Nonlinear Markov Chains.

    Science.gov (United States)

    Pirogov, Sergey; Rybko, Alexander; Kalinina, Anastasia; Gelfand, Mikhail

    2016-09-01

    Bacteria are known to exchange genetic information by horizontal gene transfer. Since the frequency of homologous recombination depends on the similarity between the recombining segments, several studies examined whether this could lead to the emergence of subspecies. Most of them simulated fixed-size Wright-Fisher populations, in which the genetic drift should be taken into account. Here, we use nonlinear Markov processes to describe a bacterial population evolving under mutation and recombination. We consider a population structure as a probability measure on the space of genomes. This approach implies the infinite population size limit, and thus, the genetic drift is not assumed. We prove that under these conditions, the emergence of subspecies is impossible.

  12. Wave propagation properties in oscillatory chains with cubic nonlinearities via nonlinear map approach

    Energy Technology Data Exchange (ETDEWEB)

    Romeo, Francesco [Dipartimento di Ingegneria Strutturale e Geotecnica, Universita di Roma ' La Sapienza' , Via Gramsci 53, 00197 Rome (Italy)] e-mail: francesco.romeo@uniromal.it; Rega, Giuseppe [Dipartimento di Ingegneria Strutturale e Geotecnica, Universita di Roma ' La Sapienza' , Via Gramsci 53, 00197 Rome (Italy)] e-mail: giuseppe.rega@uniromal.it

    2006-02-01

    Free wave propagation properties in one-dimensional chains of nonlinear oscillators are investigated by means of nonlinear maps. In this realm, the governing difference equations are regarded as symplectic nonlinear transformations relating the amplitudes in adjacent chain sites (n, n + 1) thereby considering a dynamical system where the location index n plays the role of the discrete time. Thus, wave propagation becomes synonymous of stability: finding regions of propagating wave solutions is equivalent to finding regions of linearly stable map solutions. Mechanical models of chains of linearly coupled nonlinear oscillators are investigated. Pass- and stop-band regions of the mono-coupled periodic system are analytically determined for period-q orbits as they are governed by the eigenvalues of the linearized 2D map arising from linear stability analysis of periodic orbits. Then, equivalent chains of nonlinear oscillators in complex domain are tackled. Also in this case, where a 4D real map governs the wave transmission, the nonlinear pass- and stop-bands for periodic orbits are analytically determined by extending the 2D map analysis. The analytical findings concerning the propagation properties are then compared with numerical results obtained through nonlinear map iteration.

  13. Thermal conductivity of nonlinear waves in disordered chains

    Indian Academy of Sciences (India)

    Sergej Flach; Mikhail Ivanchenko; Nianbei Li

    2011-11-01

    We present computational data on the thermal conductivity of nonlinear waves in disordered chains. Disorder induces Anderson localization for linear waves and results in a vanishing conductivity. Cubic nonlinearity restores normal conductivity, but with a strongly temperature-dependent conductivity (). We find indications for an asymptotic low-temperature ∼ 4 and intermediate temperature ∼ 2 laws. These findings are in accord with theoretical studies of wave packet spreading, where a regime of strong chaos is found to be intermediate, followed by an asymptotic regime of weak chaos (Laptyeva et al, Europhys. Lett. 91, 30001 (2010)).

  14. Effects of intrinsic decoherence on the entanglement of a two-qutrit 1D optical lattice chain with nonlinear coupling

    Institute of Scientific and Technical Information of China (English)

    Song Wei

    2009-01-01

    We have investigated the intrinsic decoherence on the entanglement of a two-qutrit one-dimensional (1D) optical lattice chain with nonlinear coupling.As a measure of the entanglement,the negativity of the system is calculated.It is shown that the influence of intrinsic decoherence on the entanglement varies in different initial systems.

  15. The quasi-equilibrium phase of nonlinear chains

    Indian Academy of Sciences (India)

    T R Krishna Mohan; Surajit Sen

    2005-03-01

    We show that time evolution initiated via kinetic energy perturbations in conservative, discrete, spring-mass chains with purely nonlinear, non-integrable, algebraic potentials of the form ( − +1 ∼ $(_{} − _{+1})^{2}$, ≥ 2 and an integer, occurs via discrete solitary waves (DSWs) and discrete antisolitary waves (DASWs). Presence of reflecting and periodic boundaries in the system leads to collisions between the DSWs and DASWs. Such collisions lead to the breakage and subsequent reformation of (different) DSWs and DASWs. Our calculations show that the system eventually reaches a stable `quasi-equilibrium' phase that appears to be independent of initial conditions, possesses Gaussian velocity distribution, and has a higher mean kinetic energy and larger range of kinetic energy fluctuations as compared to the pure harmonic system with = 1; the latter indicates possible violation of equipartition.

  16. Nonlinear dynamics of a friction-limited drive: Application to a chain continuously variable transmission (CVT) system

    Science.gov (United States)

    Srivastava, Nilabh; Haque, Imtiaz

    2009-03-01

    Over the past two decades, extensive research has been conducted on developing vehicle transmissions that meet the goals of reduced exhaust emissions and increased vehicle efficiency. A continuously variable transmission is an emerging automotive transmission technology that offers a continuum of gear ratios between desired limits. A chain CVT is a friction-limited drive whose dynamic performance and torque capacity rely significantly on the friction characteristic of the contact patch between the chain and the pulley. Although a CVT helps to maximize the vehicle fuel economy, its complete potential has not been accomplished in a mass-production vehicle. The present research focuses on developing models to analyze friction-induced nonlinear dynamics of a chain CVT drive and identify possible mechanisms that cause degradation of the overall dynamic performance by inducing chaos and self-sustained vibrations in the system. Two different mathematical models of friction, which characterize different operating or loading conditions, are embedded into a detailed planar multibody model of chain CVT in order to capture the various friction-induced effects in the system. Tools such as stick-slip oscillator dynamics, Lyapunov exponents, phase-space reconstruction, and recurrence plotting are incorporated to characterize the nonlinear dynamics of such a friction-limited system. The mathematical models, the computational scheme, and the results corresponding to different loading scenarios are discussed. The results discuss the influence of friction characteristics on the nonlinear dynamics and torque transmitting capacity of a chain CVT drive.

  17. The nonlinear Schroedinger equation on a disordered chain

    Energy Technology Data Exchange (ETDEWEB)

    Scharf, R.; Bishop, A.R.

    1990-01-01

    The integrable lattice nonlinear Schroedinger equation is a unique model with which to investigate the effects of disorder on a discrete integrable dynamics, and its interplay with nonlinearity. We first review some features of the lattice nonlinear Schroedinger equation in the absence of disorder and introduce a 1- and 2-soliton collective variable approximation. Then we describe the effect of different types of disorder: attractive and repulsive isolated impurities, spatially periodic potentials, random potentials, and time dependent (kicked) long wavelength perturbations. 18 refs., 15 figs.

  18. Quantum Solitons and Localized Modes in a One-Dimensional Lattice Chain with Nonlinear Substrate Potential

    Institute of Scientific and Technical Information of China (English)

    LI De-Jun; MI Xian-Wu; DENG Ke; TANG Yi

    2006-01-01

    In the classical lattice theory, solitons and locaLized modes can exist in many one-dimensional nonlinear lattice chains, however, in the quantum lattice theory, whether quantum solitons and localized modes can exist or not in the one-dimensional lattice chains is an interesting problem. By using the number state method and the Hartree approximation combined with the method of multiple scales, we investigate quantum solitons and localized modes in a one-dimensional lattice chain with the nonlinear substrate potential. It is shown that quantum solitons do exist in this nonlinear lattice chain, and at the boundary of the phonon Brillouin zone, quantum solitons become quantum localized modes, phonons are pinned to the lattice of the vicinity at the central position j = j0.

  19. Local Influence Analysis for Semiparametric Reproductive Dispersion Nonlinear Models

    Institute of Scientific and Technical Information of China (English)

    Xue-dong CHEN; Nian-sheng TANG; Xue-ren WANG

    2012-01-01

    The present paper proposes a semiparametric reproductive dispersion nonlinear model (SRDNM)which is an extension of the nonlinear reproductive dispersion models and the semiparameter regression models.Maximum penalized likelihood estimates (MPLEs) of unknown parameters and nonparametric functions in SRDNM are presented.Assessment of local influence for various perturbation schemes are investigated.Some local influence diagnostics are given.A simulation study and a real example are used to illustrate the proposed methodologies.

  20. Ground-state energies of the nonlinear sigma model and the Heisenberg spin chains

    Science.gov (United States)

    Zhang, Shoucheng; Schulz, H. J.; Ziman, Timothy

    1989-01-01

    A theorem on the O(3) nonlinear sigma model with the topological theta term is proved, which states that the ground-state energy at theta = pi is always higher than the ground-state energy at theta = 0, for the same value of the coupling constant g. Provided that the nonlinear sigma model gives the correct description for the Heisenberg spin chains in the large-s limit, this theorem makes a definite prediction relating the ground-state energies of the half-integer and the integer spin chains. The ground-state energies obtained from the exact Bethe ansatz solution for the spin-1/2 chain and the numerical diagonalization on the spin-1, spin-3/2, and spin-2 chains support this prediction.

  1. Third-order nonlinear optical characterization of side-chain copolymers

    Science.gov (United States)

    Norwood, Robert A.; Sounik, James R.; Popolo, J.; Holcomb, Douglas P.

    1991-12-01

    Third order nonlinear optical properties of side-chain methacrylate copolymers incorporating 4-amino-4'-nitrostilbene, 4-oxy-4'nitrostilbene, and functionalized silicon phthalocyanine chromophores are measured by picosecond degenerate four wave mixing at 598 nm. The nonresonant stilbene system exhibits a pulse limited ultrafast response, while the resonant phthalocyanine system has a large excited state nonlinearity. Comparison of silicon phthalocyanine copolymers with solubilized guest/host systems dispersed in polymethylmethacrylate illustrate the importance of aggregation and phthalocyanine ring interaction in determining the linear optical properties and the magnitude and speed of the nonlinear optical response.

  2. Intrinsic localized modes and nonlinear impurity modes in curved Fermi-Pasta-Ulam chain

    Indian Academy of Sciences (India)

    Ranja Sarkar; Bishwajyoti Dey

    2008-06-01

    We explore the nature of intrinsic localized modes (ILMs) in a curved FermiPasta-Ulam (FPU) chain and the effects of geometry and second-neighbor interaction on the localization and movability properties of such modes. We determine analytically the structure of the localized modes induced by an isotopic light-mass impurity in this chain. We further demonstrate that a nonlinear impurity mode may be treated as a bound state of an ILM with the impurity.

  3. Excited state nonlinear integral equations for an integrable anisotropic spin-1 chain

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, J [Department of Physics, Faculty of Science, Shizuoka University, Ohya 836, Shizuoka (Japan)

    2004-12-17

    We propose a set of nonlinear integral equations to describe the excited states of an integrable the spin-1 chain with anisotropy. The scaling dimensions, evaluated numerically in previous studies, are recovered analytically by using the equations. This result may be relevant to the study of the supersymmetric sine-Gordon model.

  4. Complex statistics and diffusion in nonlinear disordered particle chains

    Energy Technology Data Exchange (ETDEWEB)

    Antonopoulos, Ch. G., E-mail: chris.antonopoulos@abdn.ac.uk [Institute for Complex Systems and Mathematical Biology (ICSMB), Department of Physics, University of Aberdeen, AB24 3UE Aberdeen (United Kingdom); Bountis, T., E-mail: bountis@math.upatras.gr [Center for Research and Applications of Nonlinear Systems (CRANS), Department of Mathematics, University of Patras, 26500 Patras (Greece); Skokos, Ch., E-mail: haris.skokos@uct.ac.za [Department of Mathematics and Applied Mathematics, University of Cape Town, Rondebosch, Cape Town 7701 (South Africa); Department of Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Drossos, L., E-mail: ldrossos@teimes.gr [High Performance Computing Systems Lab (HPCS lab), Department of Computer and Informatics Engineering, Technological Educational Institute of Western Greece, 30300 Antirion (Greece)

    2014-06-15

    We investigate dynamically and statistically diffusive motion in a Klein-Gordon particle chain in the presence of disorder. In particular, we examine a low energy (subdiffusive) and a higher energy (self-trapping) case and verify that subdiffusive spreading is always observed. We then carry out a statistical analysis of the motion, in both cases, in the sense of the Central Limit Theorem and present evidence of different chaos behaviors, for various groups of particles. Integrating the equations of motion for times as long as 10{sup 9}, our probability distribution functions always tend to Gaussians and show that the dynamics does not relax onto a quasi-periodic Kolmogorov-Arnold-Moser torus and that diffusion continues to spread chaotically for arbitrarily long times.

  5. Local Influence Analysis of Nonlinear Structural Equation Models

    Science.gov (United States)

    Lee, Sik-Yum; Tang, Nian-Sheng

    2004-01-01

    By regarding the latent random vectors as hypothetical missing data and based on the conditional expectation of the complete-data log-likelihood function in the EM algorithm, we investigate assessment of local influence of various perturbation schemes in a nonlinear structural equation model. The basic building blocks of local influence analysis…

  6. Thermal rectification and negative differential thermal conductance in harmonic chains with nonlinear system-bath coupling

    Science.gov (United States)

    Ming, Yi; Li, Hui-Min; Ding, Ze-Jun

    2016-03-01

    Thermal rectification and negative differential thermal conductance were realized in harmonic chains in this work. We used the generalized Caldeira-Leggett model to study the heat flow. In contrast to most previous studies considering only the linear system-bath coupling, we considered the nonlinear system-bath coupling based on recent experiment [Eichler et al., Nat. Nanotech. 6, 339 (2011), 10.1038/nnano.2011.71]. When the linear coupling constant is weak, the multiphonon processes induced by the nonlinear coupling allow more phonons transport across the system-bath interface and hence the heat current is enhanced. Consequently, thermal rectification and negative differential thermal conductance are achieved when the nonlinear couplings are asymmetric. However, when the linear coupling constant is strong, the umklapp processes dominate the multiphonon processes. Nonlinear coupling suppresses the heat current. Thermal rectification is also achieved. But the direction of rectification is reversed compared to the results of weak linear coupling constant.

  7. Thermal rectification and negative differential thermal conductance in harmonic chains with nonlinear system-bath coupling.

    Science.gov (United States)

    Ming, Yi; Li, Hui-Min; Ding, Ze-Jun

    2016-03-01

    Thermal rectification and negative differential thermal conductance were realized in harmonic chains in this work. We used the generalized Caldeira-Leggett model to study the heat flow. In contrast to most previous studies considering only the linear system-bath coupling, we considered the nonlinear system-bath coupling based on recent experiment [Eichler et al., Nat. Nanotech. 6, 339 (2011)]. When the linear coupling constant is weak, the multiphonon processes induced by the nonlinear coupling allow more phonons transport across the system-bath interface and hence the heat current is enhanced. Consequently, thermal rectification and negative differential thermal conductance are achieved when the nonlinear couplings are asymmetric. However, when the linear coupling constant is strong, the umklapp processes dominate the multiphonon processes. Nonlinear coupling suppresses the heat current. Thermal rectification is also achieved. But the direction of rectification is reversed compared to the results of weak linear coupling constant.

  8. Quantum correlations and entanglement in a model comprised of a short chain of nonlinear oscillators

    Science.gov (United States)

    Kalaga, J. K.; Kowalewska-Kudłaszyk, A.; Leoński, W.; Barasiński, A.

    2016-09-01

    We discuss a model comprised of a chain of three Kerr-like nonlinear oscillators pumped by two modes of external coherent field. We show that the system can be treated as nonlinear quantum scissors and behave as a three-qubit model. For such situation, different types of tripartite entangled states can be generated, even when damping effects are present in the system. Some amount of such entanglement can survive even in a long-time limit. The flow of bipartite entanglement between subsystems of the model and relations among first-order correlations, second-order correlations, and the entanglement are discussed.

  9. Thermal entanglement in 1D optical lattice chains with nonlinear coupling

    Institute of Scientific and Technical Information of China (English)

    Zhou Ling; Yi Xue-Xi; Song He-Shan; Guo Yan-Qing

    2005-01-01

    he thermal entanglement of spin-1 atoms with nonlinear coupling in an optical lattice chain is investigated for two-particle and multi-particle systems. It is found that the relation between linear coupling and nonlinear coupling is the key to determine thermal entanglement, which shows in what kinds of atoms thermal entanglement exists. This result is true both for two-particle and multi-particle systems. For multi-particle systems, the thermal entanglement does not decrease greatly, and the critical temperature decreases only slightly.

  10. Influence of Nonlinear Absorption on Z-Scan Measurements of Nonlinear Refraction

    Institute of Scientific and Technical Information of China (English)

    刘智波; 田建国; 臧维平; 周文远; 张春平; 张光寅

    2003-01-01

    A simple division of close-aperture Z-scan curve by open-aperture Z-scan is conveniently used to obtain the nonlinear refractive index. It usually causes an error, which even reaches up to over 50% for Z-scan measurements with a pinhole or a medium with a high nonlinear absorption. Here the influence of nonlinear absorption on the determination of nonlinear refraction by Z-scan is analysed. We suggest that the error can be reduced greatly by a simple analysis of the symmetric features (symmetric method) of Z-scan curves from the closed-aperture Z-scan curve. As an example, experiments were carried out on CS2 solution of Ceo derivative, symmetric method agrees well with exact simulation.

  11. Investigating important factors influencing purchasing from chains

    Directory of Open Access Journals (Sweden)

    Naser Azad

    2012-04-01

    Full Text Available In this paper, we survey important factors, influencing customers to buy more from one of well known food market operating in capital city of Iran named Shahrvand. The survey studies the effects of six factors including customer's perception, persuasive factors, brand, customers' expectations, product's characteristics and special features of store on attracting more customers. We have distributed questionnaire among 196 customers who regularly visit stores and analyzed details of the data. The results indicate that customers' perception is the most important item, which includes eight components. Years of experience is the most important item in our survey followed by impact of color and working hours. Diversity of services is another factor, which plays the most important role followed by quality of services. Next, fidelity and brand are other most important factors and the name of store and risk are in lower degree of importance.

  12. THE DEMAND DISRUPTION MANAGEMENT PROBLEM FOR A SUPPLY CHAIN SYSTEM WITH NONLINEAR DEMAND FUNCTIONS

    Institute of Scientific and Technical Information of China (English)

    Minghui XU; Xiangtong QI; Gang YU; Hanqin ZHANG; Chengxiu GAO

    2003-01-01

    This paper addresses the problem of handling the uncertainty of demand in aone-supplier-one-retailer supply chain system. Demand variation often makes the real productiondifferent from what is originally planned, causing a deviation cost from the production plan. Assumethe market demand is sensitive to the retail price in a nonlinear form, we show how to effectivelyhandle the demand uncertainty in a supply chain, both for the case of centralized-decision-makingsystem and the case of decentralized-decision-making system with perfect coordination.

  13. Light-switching-light optical transistor based on metallic nanoparticle cross-chains geometry incorporating Kerr nonlinearity

    Energy Technology Data Exchange (ETDEWEB)

    AbdelMalek, Fathi; Aroua, Walid [National Institute of Applied Science and Technology, University of Carthage, Tunis (Tunisia); Haxha, Shyqyri [Computer Science and Technology Department, Bedfordshire University, Luton (United Kingdom); Flint, Ian [Selex ES Ltd, Luton, Bedfordshire (United Kingdom)

    2016-08-15

    In this research work, we propose all-optical transistor based on metallic nanoparticle cross-chains geometry. The geometry of the proposed device consists of two silver nanoparticle chains arranged along the x- and z-axis. The x-chain contains a Kerr nonlinearity, the source beam is set at the left side of the later, while the control beam is located at the top side of the z-chain. The control beam can turn ON and OFF the light transmission of an incoming light. We report a theoretical model of a very small all-optical transistor proof-of-concept made of optical 'light switching light' concept. We show that the transmission efficiency strongly depends on the control beam and polarization of the incoming light. We investigate the influence of a perfect reflector and reflecting substrate on the transmission of the optical signal when the control beam is turned ON and OFF. These new findings make our unique design a potential candidate for future highly-integrated optical information processing chips. (copyright 2016 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Exact Solutions of Nonlinear Dynamics Equation in a New Double-Chain Model of DNA

    Institute of Scientific and Technical Information of China (English)

    QIAN Xian-Min; LOU Sen-Yue

    2003-01-01

    The exact solutions of the general nonlinear dynamic system in a new double-chain model of DNA are studiedkink shape excitations can be found in both the Conte's truncation expansion and the Pickering's truncation expansion.Three types of new localized excitations, the asymmetric kink-kink excitations, the soliton-kink excitation, and thekink-soliton excitations, are found by using the Pickering's nonstandard truncation expansion.

  15. Do horizontal propulsive forces influence the nonlinear structure of locomotion?

    Directory of Open Access Journals (Sweden)

    Stergiou Nicholas

    2007-08-01

    Full Text Available Abstract Background Several investigations have suggested that changes in the nonlinear gait dynamics are related to the neural control of locomotion. However, no investigations have provided insight on how neural control of the locomotive pattern may be directly reflected in changes in the nonlinear gait dynamics. Our simulations with a passive dynamic walking model predicted that toe-off impulses that assist the forward motion of the center of mass influence the nonlinear gait dynamics. Here we tested this prediction in humans as they walked on the treadmill while the forward progression of the center of mass was assisted by a custom built mechanical horizontal actuator. Methods Nineteen participants walked for two minutes on a motorized treadmill as a horizontal actuator assisted the forward translation of the center of mass during the stance phase. All subjects walked at a self-select speed that had a medium-high velocity. The actuator provided assistive forces equal to 0, 3, 6 and 9 percent of the participant's body weight. The largest Lyapunov exponent, which measures the nonlinear structure, was calculated for the hip, knee and ankle joint time series. A repeated measures one-way analysis of variance with a t-test post hoc was used to determine significant differences in the nonlinear gait dynamics. Results The magnitude of the largest Lyapunov exponent systematically increased as the percent assistance provided by the mechanical actuator was increased. Conclusion These results support our model's prediction that control of the forward progression of the center of mass influences the nonlinear gait dynamics. The inability to control the forward progression of the center of mass during the stance phase may be the reason the nonlinear gait dynamics are altered in pathological populations. However, these conclusions need to be further explored at a range of walking speeds.

  16. INFLUENCE ANALYSIS ON EXPONENTIAL NONLINEAR MODELS WITH RANDOM EFFECTS

    Institute of Scientific and Technical Information of China (English)

    宗序平; 赵俊; 王海斌; 韦博成

    2003-01-01

    This paper presents a unified diagnostic method for exponential nonlinear models with random effects based upon the joint likelihood given by Robinson in 1991.The authors show that the case deletion model is equivalent to mean shift outlier model.From this point of view,several diagnostic measures,such as Cook distance,score statistics are derived.The local influence measure of Cook is also presented.Numerical example illustrates that our method is available.

  17. BAND GAP EFFECTS IN PERIODIC CHAIN WITH LOCAL LINEAR OR NON-LINEAR OSCILLATORS

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Jensen, Jakob Søndergaard

    2007-01-01

    attached linear oscillators. The stop band is located around the resonant frequency of the local oscillators, and thus a stop band can be created in the lower frequency range. In this paper, wave propagation in one-dimensional infinite periodic chains with attached linear and non-linear local oscillators...... within bands of frequencies called stop bands. Stop bands in structures with periodic or random inclusions are located mainly in the high frequency range, as the wave length has to be comparable with the distance between the alternating parts. Wave attenuation is also possible in structures with locally...

  18. Designing a Fresh Food Supply Chain Network: An Application of Nonlinear Programming

    Directory of Open Access Journals (Sweden)

    Yu-Chung Tsao

    2013-01-01

    Full Text Available In today’s business environment, many fresh food companies have complex supply networks to distribute their products. For example, agricultural products are distributed through a multiechelon supply chain which includes agricultural association, agricultural produce marketing corporations (APMCs, markets, and so forth. In this paper a fresh produce supply network model is designed to determine the optimal service area for APMCs, the replenishment cycle time of APMCs, and the freshness-keeping effort, while maximizing the total profit. The objective is to address the integrated facility location, inventory allocation, and freshness-keeping effort problems. This paper develops an algorithm to solve the nonlinear problem, provides numerical analysis to illustrate the proposed solution procedure, and discusses the effects of various system parameters on the decisions and total profits. A real case of an agricultural product supply chain in Taiwan is used to verify the model. Results of this study can serve as a reference for business managers and administrators.

  19. A force-level theory of the rheology of entangled rod and chain polymer liquids. I. Tube deformation, microscopic yielding, and the nonlinear elastic limit

    Science.gov (United States)

    Schweizer, Kenneth S.; Sussman, Daniel M.

    2016-12-01

    We employ a first-principles-based, force-level approach to construct the anharmonic tube confinement field for entangled fluids of rigid needles, and also for chains described at the primitive-path (PP) level in two limiting situations where chain stretch is assumed to either be completely equilibrated or unrelaxed. The influence of shear and extensional deformation and polymer orientation is determined in a nonlinear elastic limit where dissipative relaxation processes are intentionally neglected. For needles and PP-level chains, a self-consistent analysis of transverse polymer harmonic dynamical fluctuations predicts that deformation-induced orientation leads to tube weakening or widening. In contrast, for deformed polymers in which chain stretch does not relax, we find tube strengthening or compression. For all three systems, a finite maximum transverse entanglement force localizing the polymers in effective tubes is predicted. The conditions when this entanglement force can be overcome by an externally applied force associated with macroscopic deformation can be crisply defined in the nonlinear elastic limit, and the possibility of a "microscopic absolute yielding" event destroying the tube confinement can be analyzed. For needles and contour-relaxed PP chains, this force imbalance occurs at a stress of order the equilibrium shear modulus and a strain of order unity, corresponding to a mechanically fragile entanglement tube field. However, for unrelaxed stretched chains, tube compression stabilizes transverse polymer confinement, and there appears to be no force imbalance. These results collectively suggest that the crossover from elastic to irreversible viscous response requires chain retraction to initiate disentanglement. We qualitatively discuss comparisons with existing phenomenological models for nonlinear startup shear, step strain, and creep rheology experiments.

  20. Structural Health Monitoring under Nonlinear Environmental or Operational Influences

    Directory of Open Access Journals (Sweden)

    Jyrki Kullaa

    2014-01-01

    Full Text Available Vibration-based structural health monitoring is based on detecting changes in the dynamic characteristics of the structure. It is well known that environmental or operational variations can also have an influence on the vibration properties. If these effects are not taken into account, they can result in false indications of damage. If the environmental or operational variations cause nonlinear effects, they can be compensated using a Gaussian mixture model (GMM without the measurement of the underlying variables. The number of Gaussian components can also be estimated. For the local linear components, minimum mean square error (MMSE estimation is applied to eliminate the environmental or operational influences. Damage is detected from the residuals after applying principal component analysis (PCA. Control charts are used for novelty detection. The proposed approach is validated using simulated data and the identified lowest natural frequencies of the Z24 Bridge under temperature variation. Nonlinear models are most effective if the data dimensionality is low. On the other hand, linear models often outperform nonlinear models for high-dimensional data.

  1. Experimental evidence of ion acoustic soliton chain formation and validation of nonlinear fluid theory

    Energy Technology Data Exchange (ETDEWEB)

    Kakad, Amar [Research Institute for Sustainable Humanosphere, Kyoto University, Uji, Kyoto 611-0011 (Japan); Indian Institute of Geomagnetism, New Panvel, Navi Mumbai 410-218 (India); Omura, Yoshiharu [Research Institute for Sustainable Humanosphere, Kyoto University, Uji, Kyoto 611-0011 (Japan); Kakad, Bharati [Indian Institute of Geomagnetism, New Panvel, Navi Mumbai 410-218 (India)

    2013-06-15

    We perform one-dimensional fluid simulation of ion acoustic (IA) solitons propagating parallel to the magnetic field in electron-ion plasmas by assuming a large system length. To model the initial density perturbations (IDP), we employ a KdV soliton type solution. Our simulation demonstrates that the generation mechanism of IA solitons depends on the wavelength of the IDP. The short wavelength IDP evolve into two oppositely propagating identical IA solitons, whereas the long wavelength IDP develop into two indistinguishable chains of multiple IA solitons through a wave breaking process. The wave breaking occurs close to the time when electrostatic energy exceeds half of the kinetic energy of the electron fluid. The wave breaking amplitude and time of its initiation are found to be dependent on characteristics of the IDP. The strength of the IDP controls the number of IA solitons in the solitary chains. The speed, width, and amplitude of IA solitons estimated during their stable propagation in the simulation are in good agreement with the nonlinear fluid theory. This fluid simulation is the first to confirm the validity of the general nonlinear fluid theory, which is widely used in the study of solitary waves in laboratory and space plasmas.

  2. Applying nonlinear MODM model to supply chain management with quantity discount policy under complex fuzzy environment

    Directory of Open Access Journals (Sweden)

    Zhe Zhang

    2014-06-01

    Full Text Available Purpose: The aim of this paper is to deal with the supply chain management (SCM with quantity discount policy under the complex fuzzy environment, which is characterized as the bi-fuzzy variables. By taking into account the strategy and the process of decision making, a bi-fuzzy nonlinear multiple objective decision making (MODM model is presented to solve the proposed problem.Design/methodology/approach: The bi-fuzzy variables in the MODM model are transformed into the trapezoidal fuzzy variables by the DMs's degree of optimism ?1 and ?2, which are de-fuzzified by the expected value index subsequently. For solving the complex nonlinear model, a multi-objective adaptive particle swarm optimization algorithm (MO-APSO is designed as the solution method.Findings: The proposed model and algorithm are applied to a typical example of SCM problem to illustrate the effectiveness. Based on the sensitivity analysis of the results, the bi-fuzzy nonlinear MODM SCM model is proved to be sensitive to the possibility level ?1.Practical implications: The study focuses on the SCM under complex fuzzy environment in SCM, which has a great practical significance. Therefore, the bi-fuzzy MODM model and MO-APSO can be further applied in SCM problem with quantity discount policy.Originality/value: The bi-fuzzy variable is employed in the nonlinear MODM model of SCM to characterize the hybrid uncertain environment, and this work is original. In addition, the hybrid crisp approach is proposed to transferred to model to an equivalent crisp one by the DMs's degree of optimism and the expected value index. Since the MODM model consider the bi-fuzzy environment and quantity discount policy, so this paper has a great practical significance.

  3. Bright and dark small amplitude nonlinear localized modes in a quantum one-dimensional Klein-Gordon chain

    Institute of Scientific and Technical Information of China (English)

    Liu Yang; Tang Yi

    2008-01-01

    By means of the Glauber's coherent state method combined with multiple-scale method,this paper investigates the localized modes in a quantum one-dimensional Klein-Gordon chain and finds that the equation of motion of annihilation operator is reduced to the nonlinear Schr(o)dinger equation.Interestingly,the model can support both bright and dark small amplitude travelling and non-travelling nonlinear localized modes in different parameter spaces.

  4. On asymptotic stabilisation of a chain of integrators with nonlinearity and an uncertain input delay by output feedback

    Science.gov (United States)

    Choi, Ho-Lim

    2014-12-01

    In this paper, we provide an output feedback solution over one given by Choi and Lim [Systems & Control Letters, 59(6), 374-379 (2010)] under more generalised system set-up. More specifically, we consider a stabilisation problem of a chain of integrators that has nonlinearity and an uncertain delay in the input by output feedback. The nonlinearity is classified into four types. Then, we propose a memoryless output feedback controller which contains a gain-scaling factor to adjust controller gains depending on the given nonlinearity type. Our stability analysis shows that the controlled system has unique stabilisation result associated with each type of nonlinearity. Our result provides a new aspect to the stabilisation problem of nonlinear time-delay systems and broadens the existing control results of time-delay systems. Two examples are given for illustration.

  5. The influence of power in supply chain innovation; a case study of the Dutch wheat chain

    NARCIS (Netherlands)

    Pol, Hanneke; Visscher, Klaasjan

    2010-01-01

    The purpose of this article is to clarify the relation between the power structure of a supply chain and the possibilities to realize supply chain innovations. In an in-depth case study of the faltering start of an innovation trajectory in the Dutch wheat supply chain, we show that supply chain inno

  6. Waterborne polyurethanes: influence of chain extender in ftir spectra profiles

    Science.gov (United States)

    Delpech, Marcia; Miranda, Gisele

    2012-06-01

    Non-polluting systems based on waterborne polyurethanes (wPU) and poly(urethane-urea)s (wPUU) were synthesized employing poly(propylene glycol) (PPG), dimethylolpropionic acid (DMPA) and 4,4'-dicyclohexylmethane diisocyanate (HMDI) as monomers. In the formulations, the length and the proportion of the soft segments were varied. Three types of chain extenders were employed: ethylene glycol (EG), producing urethane linkages; and ethylenediamine (EDA) and hydrazine (HYD), forming urea linkages. Cast films obtained from wPU and wPUU, monomers and prepolymers were analyzed by Fourier transform infrared spectrometry (FTIR). The profile of carbonyl absorption bands obtained for the films showed some remarkable differences depending on the formulation. The bands were split into two parts, which were directly related to the tendency of hydrogen bond formation. The length of soft segment, the amount of rigid portions and the presence of urea linkages showed a marked influence in both intensity and frequency absorption of the bands.

  7. Mixed mono- and multilayers of poly(isocyanide)s with non-linear optically active side chains

    NARCIS (Netherlands)

    Teerenstra, M.N.; Hagting, J.G.; Oostergetel, G.T.; Schouten, A.J.; Devillers, M.A.C.; Nolte, R.J.M.

    1994-01-01

    The properties and structure of Langmuir-Blodgett mono- and multilayers of several poly(isocyanide)s with non-linear optically active side-chains were studied. These polymers formed very rigid layers or layers which appeared to be unstable. To circumvent this problem they were mixed with other poly(

  8. Antibody elbow angles are influenced by their light chain class

    Energy Technology Data Exchange (ETDEWEB)

    Stanfield, R; Zemla, A; Wilson, I; Rupp, B

    2006-01-12

    We have examined the elbow angles for 365 different Fab fragments, and observe that Fabs with lambda light chains have adopted a wider range of elbow angles than their kappa-chain counterparts, and that the lambda light chain Fabs are frequently found with very large (>195{sup o}) elbow angles. This apparent hyperflexibility of lambda-chain Fabs may be due to an insertion in their switch region, which is one residue longer than in kappa chains, with glycine occurring most frequently at the insertion position. A new, web-based computer program that was used to calculate the Fab elbow angles is also described.

  9. Do film soundtracks contain nonlinear analogues to influence emotion?

    OpenAIRE

    Daniel T. Blumstein; Davitian, Richard; Kaye, Peter D.

    2010-01-01

    A variety of vertebrates produce nonlinear vocalizations when they are under duress. By their very nature, vocalizations containing nonlinearities may sound harsh and are somewhat unpredictable; observations that are consistent with them being particularly evocative to those hearing them. We tested the hypothesis that humans capitalize on this seemingly widespread vertebrate response by creating nonlinear analogues in film soundtracks to evoke particular emotions. We used lists of highly rega...

  10. Influence Strategies in South African Wine Value Chains

    Directory of Open Access Journals (Sweden)

    Joachim Ewert

    2015-11-01

    Drawing on a number of detailed case studies, in this paper we investigate this conclusion in more depth. By doing so, we try to explain which paths South African producer cellars have or have not chosen, and why. As global value chain theory posits that the governance structure of value chains are of crucial importance, we will pay particular interest to the design of the chains as a success factor.

  11. Complex spatiotemporal behavior in a chain of one-way nonlinearly coupled elements

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Berkemer, Rainer; Gorria, C.;

    2011-01-01

    The dynamics of asymmetrically coupled nonlinear elements is considered. It is shown that there are two distinctive regimes of oscillatory behavior of one-way nonlinearly coupled elements depending on the relaxation time and the strength of the coupling. In the subcritical regime when...... nonlinear model....

  12. Influence of storm magnitude and watershed size on runoff nonlinearity

    Indian Academy of Sciences (India)

    Kwan Tun Lee; Jen-Kuo Huang

    2016-06-01

    The inherent nonlinear characteristics of the watershed runoff process related to storm magnitude andwatershed size are discussed in detail in this study. The first type of nonlinearity is referred to rainfallrunoffdynamic process and the second type is with respect to a Power-law relation between peakdischarge and upstream drainage area. The dynamic nonlinearity induced by storm magnitude was firstdemonstrated by inspecting rainfall-runoff records at three watersheds in Taiwan. Then the derivation ofthe watershed unit hydrograph (UH) using two linear hydrological models shows that the peak dischargeand time to peak discharge that characterize the shape of UH vary event-to-event. Hence, the intentionof deriving a unique and universal UH for all rainfall-runoff simulation cases is questionable. In contrast,the UHs by the other two adopted nonlinear hydrological models were responsive to rainfall intensitywithout relying on linear proportion principle, and are excellent in presenting dynamic nonlinearity.Based on the two-segment regression, the scaling nonlinearity between peak discharge and drainagearea was investigated by analyzing the variation of Power-law exponent. The results demonstrate thatthe scaling nonlinearity is particularly significant for a watershed having larger area and subjecting toa small-size of storm. For three study watersheds, a large tributary that contributes relatively greatdrainage area or inflow is found to cause a transition break in scaling relationship and convert the scalingrelationship from linearity to nonlinearity.

  13. Influence of storm magnitude and watershed size on runoff nonlinearity

    Science.gov (United States)

    Lee, Kwan Tun; Huang, Jen-Kuo

    2016-06-01

    The inherent nonlinear characteristics of the watershed runoff process related to storm magnitude and watershed size are discussed in detail in this study. The first type of nonlinearity is referred to rainfall-runoff dynamic process and the second type is with respect to a Power-law relation between peak discharge and upstream drainage area. The dynamic nonlinearity induced by storm magnitude was first demonstrated by inspecting rainfall-runoff records at three watersheds in Taiwan. Then the derivation of the watershed unit hydrograph (UH) using two linear hydrological models shows that the peak discharge and time to peak discharge that characterize the shape of UH vary event-to-event. Hence, the intention of deriving a unique and universal UH for all rainfall-runoff simulation cases is questionable. In contrast, the UHs by the other two adopted nonlinear hydrological models were responsive to rainfall intensity without relying on linear proportion principle, and are excellent in presenting dynamic nonlinearity. Based on the two-segment regression, the scaling nonlinearity between peak discharge and drainage area was investigated by analyzing the variation of Power-law exponent. The results demonstrate that the scaling nonlinearity is particularly significant for a watershed having larger area and subjecting to a small-size of storm. For three study watersheds, a large tributary that contributes relatively great drainage area or inflow is found to cause a transition break in scaling relationship and convert the scaling relationship from linearity to nonlinearity.

  14. The influence of business conditions on supply chain information-sharing mechanisms : A study among supply chain links of SMEs

    NARCIS (Netherlands)

    Welker, Gera A.; van der Vaart, Taco; van Donk, Dirk Pieter

    2008-01-01

    The literature acknowledges that the type and the level of supply chain integration differ in various situations. This paper investigates the influence of business conditions on internal and external information sharing and the role of ICT in order processing, using a multi-case study among SMEs. Th

  15. Non-Linear Dependence of the Height of a Chain Fountain on Drop Height

    Science.gov (United States)

    Andrew, Y.; Kearns, F.; Mustafa, T.; Salih, R.; Ioratim-Uba, A.; Udall, I.; Usama, M.

    2015-01-01

    If the end of a long chain, which is contained in an elevated beaker, is dropped over the edge of the beaker and falls, it is observed that as the speed of the chain increases the chain rises to form a loop well above the top of the beaker. The name "chain fountain" has been applied to this phenomenon. In this study the dependence of the…

  16. Influence of Relationship Commitment and Trust on Collaborative Behaviour in Supply Chains

    Directory of Open Access Journals (Sweden)

    Sonja Mlaker Kač

    2015-03-01

    Full Text Available The paper discusses theoretically and examines empirically the influence of the relationship commitment on collaborative behaviour in supply chains. In today’s unstable business environment companies should collaborate to achieve mutual goals and competitive advantage. Defining relationship commitment and collaboration in supply chains (from social exchange theory point of view is the basis of the research of this paper. Our aim is to examine the influence of relationship commitment on collaboration in supply chains in Slovenian economy. The qualitative research part discusses if the relationship commitment between partners in supply chain influences the collaborative behaviour between partners and which are the antecedents of relationship commitment. The research is based on a quantitative analysis of the online questionnaire survey made on the Slovenian economy. The research results show strong influence of trust and relationship commitment on collaboration between partners in supply chains.

  17. Do film soundtracks contain nonlinear analogues to influence emotion?

    Science.gov (United States)

    Blumstein, Daniel T; Davitian, Richard; Kaye, Peter D

    2010-12-23

    A variety of vertebrates produce nonlinear vocalizations when they are under duress. By their very nature, vocalizations containing nonlinearities may sound harsh and are somewhat unpredictable; observations that are consistent with them being particularly evocative to those hearing them. We tested the hypothesis that humans capitalize on this seemingly widespread vertebrate response by creating nonlinear analogues in film soundtracks to evoke particular emotions. We used lists of highly regarded films to generate a set of highly ranked action/adventure, dramatic, horror and war films. We then scored the presence of a variety of nonlinear analogues in these film soundtracks. Dramatic films suppressed noise of all types, contained more abrupt frequency transitions and musical sidebands, and fewer noisy screams than expected. Horror films suppressed abrupt frequency transitions and musical sidebands, but had more non-musical sidebands, and noisy screams than expected. Adventure films had more male screams than expected. Together, our results suggest that film-makers manipulate sounds to create nonlinear analogues in order to manipulate our emotional responses.

  18. Lean, green and resilient practices influence on supply chain performance

    DEFF Research Database (Denmark)

    Govindan, K.; Azevedo, S. G.; Carvalho, H.

    2015-01-01

    Nowadays, companies are struggling to find an appropriate supply chain strategy to achieve competitiveness. Among the available strategies lean, green and resilient are considered as a new management strategies for the supply chain management to achieve competitiveness. The major issues with theses...... strategies are the integration and identification of critical issues related to the strategies. This paper aims to identify the critical lean, green and resilient practices on which top management should focus in order to improve the performance of automotive supply chains. The systematic analysis...... performance and to classify them according to their driving or dependence power. According to this research, the practices with the main driving power are just-in-time (lean practice), flexible transportation (resilient practice) and environmentally friendly packaging (green practice). Customer satisfaction...

  19. Water environmental planning considering the influence of non-linear characteristics

    Institute of Scientific and Technical Information of China (English)

    ZENG Guang-ming; QIN Xiao-sheng; WANG Wei; HUANG Guo-he; LI Jian-bing; B. Statzner

    2003-01-01

    In practical water environmental planning, the influence of the non-linear characteristics on the benefit of environmental investment was seldom taken into consideration. This paper demonstrates that there exist a lot of non-linear behaviors in water environment by emphatically analyzing the influence of the non-linear characteristics of the economic scale, the meandering river and the model on water environmental planning, which will make a certain impact on the water environmental planning that sometimes cannot be neglected. This paper also preliminarily explores how to integrate the non-linear characteristics into water environmental planning. The results showed that compared with traditional methods, water environmental planning considering non-linear characteristics has its prevalence and it is necessary to develop the relevant planning theories and methods.

  20. The Influence of Supply Chain Integration on the Intrapreneurship in Supply Chain Management (SCM

    Directory of Open Access Journals (Sweden)

    FatemehAshrafganjouei,

    2015-12-01

    Full Text Available These days, SMEs pay a lot of attention to concept of Supply Chain Management (SCM in order to achieve competitiveness. The logic behind such act is integrating the activities of value creation within any kind of organizational context. Such integrity would collaborate with managers to accomplish the competitive edge that they are aiming to achieve. The goal of current research is to identify scopes of a unique construct which is known as Entrepreneurial Supply Chain Management competency. Therefore, the notions of SCM and entrepreneurship are being aligned together for evaluating the organizational performance. The outcomes demonstrate that SCM in fact is a critical issue that can alter the organizational performance, thus, through consideration of SCM, we should focus on supply chain integration and its impacts on intrapreneurship and innovation of an organization. In order to be successful in such competitive context, SMEs need to provide novel competences which are not imitable and to increase their application in supply chain and also to improve their total performance.

  1. 测度链上具有变号非线性项微分方程的正解%POSITIVE SOLUTIONS FOR NONLINEAR DIFFERENTIAL EQUATIONS WITH SIGN CHANGING NONLINEARITY ON A MEASURE CHAIN

    Institute of Scientific and Technical Information of China (English)

    李红玉; 代丽美

    2012-01-01

    本文研究了测度链上具有变号非线性项微分方程的问题.利用拓扑方法,获得了此微分方程的正解存在性结果,推广和改进了一些文献中相应的结果.%In this paper,we study nonlinear differential equations on a measure chain.By topological methods,the existence of positive solutions of nonlinear differential equations with sign changing nonlinearity on a measure chain is discussed.The results generalize and improve the known results.

  2. Investigation on ultrafast third-order nonlinear optical properties of benzothiadiazole copolymer with triphenylamine derivative side chain

    Science.gov (United States)

    Gong, Weixiang; Yang, Junyi; Qin, Yuan-cheng; Wu, Xing-zhi; Jin, Xiao; Song, Yinglin

    2016-10-01

    The third-order nonlinear optical properties of benzothiadiazole copolymer with triphenylamine derivative side chain (BCT) dissolved in chloroform are investigated by top-hat Z-scan and time-resolved pump-probe techniques with a picoseconds pulses laser at wavelength of 532nm. Organic polymers of triphenylamine have been widely applied to optoelectronic devices owing to its outstanding physics and chemistry characteristic. So its nonlinear optical characteristic is worth studying. The sample's excited-state dynamics can be detected by the pump-probe with phase object device with/without an aperture in the far field. We can determine the sample's nonlinear absorptive and refractive coefficient by the top-hot Z-scan device with/without an aperture in the far field. The experimental results show that the BCT has a good reverse saturation absorption and negative refraction. At the same time, the BCT showed up long excited-state lifetimes. By means of a five-level model and analyzing the experimental curves, all nonlinear optical parameters are obtained. With the proper lifetime and intersystem crossing time, this sample can be a candidate for optical limiting.

  3. Influence of credit scoring on the dynamics of Markov chain

    Science.gov (United States)

    Galina, Timofeeva

    2015-11-01

    Markov processes are widely used to model the dynamics of a credit portfolio and forecast the portfolio risk and profitability. In the Markov chain model the loan portfolio is divided into several groups with different quality, which determined by presence of indebtedness and its terms. It is proposed that dynamics of portfolio shares is described by a multistage controlled system. The article outlines mathematical formalization of controls which reflect the actions of the bank's management in order to improve the loan portfolio quality. The most important control is the organization of approval procedure of loan applications. The credit scoring is studied as a control affecting to the dynamic system. Different formalizations of "good" and "bad" consumers are proposed in connection with the Markov chain model.

  4. INFLUENCE ANALYSIS IN NONLINEAR MODELS WITH RANDOM EFFECTS

    Institute of Scientific and Technical Information of China (English)

    WeiBocheng; ZhongXuping

    2001-01-01

    Abstract. In this paper,a unified diagnostic method for the nonlinear models with random ef-fects based upon the joint likelihood given by Robinson in 1991 is presented. It is shown that thecase deletion model is equivalent to the mean shift outlier model. From this point of view ,sever-al diagnostic measures, such as Cook distance, score statistics are derived. The local influencemeasure of Cook is also presented. A numerical example illustrates that the method is avail-able

  5. Influence of nonlinear chemical reactions on the transport coefficients in oscillatory Couette flow

    Science.gov (United States)

    Barik, Swarup; Dalal, D. C.

    2016-10-01

    A multiple-scale method of averaging is applied to the study of transport of a chemical species in oscillatory Couette flow where the species may undergoes a reversible phase exchange with the boundary wall and nonlinear chemical reactions both within the fluid and at the boundary wall. Analytical expressions are obtained for transport coefficients. The results shows how the transport coefficients are influenced by the reversible phase exchange reaction kinetics and the rate and degree of the nonlinear decay chemical reaction.

  6. Intelligence and Personal Influence in Groups: Four Nonlinear Models.

    Science.gov (United States)

    Simonton, Dean Keith

    1985-01-01

    Four models are developed to provide a conceptual basis for a curvilinear relation between intelligence and an individual's influence over group members. The models deal with influence and percentile placement in intelligence, comprehension by potential followers, vulnerability to rival intellects, and correlation between mean group IQ and the…

  7. Influence of Harmonics in Laboratory due to Nonlinear Loads

    Directory of Open Access Journals (Sweden)

    Risnidar Chan

    2012-03-01

    Full Text Available This research was focused on the customer’s side of the meter which is the effect of harmonics on a laboratory in Electrical System Engineering School at K.Wai Perlis. Harmonic currents in equipments can cause them to experience overheating and increased losses, while harmonic voltage produces magnetic fields rotating at a speed corresponding to the harmonic frequency. This also results in equipments heating, mechanical vibrations and noise, reduced efficiency, reduced life, and voltage stress on insulation of equipment windings. The loads in this research are computers, Compact Fluorescent Lamps CFLs, Air Conditions and printers,which all of the loads are harmonic significant The instrument to measure and monitoring is Fluke 435 Power Quality Analyzer. With the operation of varying nonlinear loads, the injected harmonic current magnitudes and phase angles vary in a random way. This research offers the advantage of providing the utility a wealth of information on the effects of harmonics in their equipments. This will subsequently make them aware of the causes of increased cost and reduced efficiency that may be experienced by using these equipments. This paper describes the investigation cost of harmonic effect as THD, and harmonic energy losses cost.   Keywords: harmonics, nonlinear loads, Energy losses cost, THD.

  8. Determination of an Unknown Radiation Term in a Nonlinear Inverse Problem using Simulation of Markov Chains

    Directory of Open Access Journals (Sweden)

    Morteza Ebrahimi

    2012-01-01

    Full Text Available The purpose of the present study is to provide a fast and accurate algorithm for identifying the medium temperature and the unknown radiation term from an overspecified condition on the boundary in an inverse problem of linear heat equation with nonlinear boundary condition. The design of the paper is to employ Taylor’s series expansion for linearize nonlinear term and then finite-difference approximation to discretize the problem domain. Owing to the application of the finite difference scheme, a large sparse system of linear algebraic equations is obtained. An approach of Monte Carlo method is employed to solve the linear system and estimate unknown radiation term. The Monte Carlo optimization is adopted to modify the estimated values. Results show that a good estimation on the radiation term can be obtained within a couple of minutes CPU time at pentium IV-2.4 GHz PC.

  9. Influence of Chain Rigidity on the Phase Behavior of Wormlike Diblock Copolymers

    Science.gov (United States)

    Jiang, Ying; Chen, Jeff Z. Y.

    2013-03-01

    We utilize the wormlike chain model in the framework of the self-consistent field theory to investigate the influence of chain rigidity on the phase diagram of AB diblock copolymers in the full three-dimensional space. We develop an efficient numerical scheme that can be used to calculate the physical properties of ordered microstructures self-assembled from semiflexible block copolymers. The calculation describes the entire physical picture of the phase diagram, crossing from the flexible over to rodlike polymer behavior.

  10. Differential Light Chain Assembly Influences Outer Arm Dynein Motor Function

    Science.gov (United States)

    DiBella, Linda M.; Gorbatyuk, Oksana; Sakato, Miho; Wakabayashi, Ken-ichi; Patel-King, Ramila S.; Pazour, Gregory J.; Witman, George B.; King, Stephen M.

    2005-01-01

    Tctex1 and Tctex2 were originally described as potential distorters/sterility factors in the non-Mendelian transmission of t-haplotypes in mice. These proteins have since been identified as subunits of cytoplasmic and/or axonemal dyneins. Within the Chlamydomonas flagellum, Tctex1 is a subunit of inner arm I1. We have now identified a second Tctex1-related protein (here termed LC9) in Chlamydomonas. LC9 copurifies with outer arm dynein in sucrose density gradients and is missing only in those strains completely lacking this motor. Zero-length cross-linking of purified outer arm dynein indicates that LC9 interacts directly with both the IC1 and IC2 intermediate chains. Immunoblot analysis revealed that LC2, LC6, and LC9 are missing in an IC2 mutant strain (oda6-r88) that can assemble outer arms but exhibits significantly reduced flagellar beat frequency. This defect is unlikely to be due to lack of LC6, because an LC6 null mutant (oda13) exhibits only a minor swimming abnormality. Using an LC2 null mutant (oda12-1), we find that although some outer arm dynein components assemble in the absence of LC2, they are nonfunctional. In contrast, dyneins from oda6-r88, which also lack LC2, retain some activity. Furthermore, we observed a synthetic assembly defect in an oda6-r88 oda12-1 double mutant. These data suggest that LC2, LC6, and LC9 have different roles in outer arm assembly and are required for wild-type motor function in the Chlamydomonas flagellum. PMID:16195342

  11. A solution procedure for mixed-integer nonlinear programming formulation of supply chain planning with quantity discounts under demand uncertainty

    Science.gov (United States)

    Yin, Sisi; Nishi, Tatsushi

    2014-11-01

    Quantity discount policy is decision-making for trade-off prices between suppliers and manufacturers while production is changeable due to demand fluctuations in a real market. In this paper, quantity discount models which consider selection of contract suppliers, production quantity and inventory simultaneously are addressed. The supply chain planning problem with quantity discounts under demand uncertainty is formulated as a mixed-integer nonlinear programming problem (MINLP) with integral terms. We apply an outer-approximation method to solve MINLP problems. In order to improve the efficiency of the proposed method, the problem is reformulated as a stochastic model replacing the integral terms by using a normalisation technique. We present numerical examples to demonstrate the efficiency of the proposed method.

  12. Effects of delayed nonlinear response on wave packet dynamics in one-dimensional generalized Fibonacci chains

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jianxin; Zhang, Zhenjun [Department of Physics and Institute of Theoretical Physics, Nanjing Normal University, Nanjing 210023 (China); Tong, Peiqing, E-mail: pqtong@njnu.edu.cn [Department of Physics and Institute of Theoretical Physics, Nanjing Normal University, Nanjing 210023 (China); Jiangsu Key Laboratory for Numerical Simulation of Large Scale Complex Systems, Nanjing Normal University, Nanjing 210023 (China)

    2013-07-15

    We investigate the spreading of an initially localized wave packet in one-dimensional generalized Fibonacci (GF) lattices by solving numerically the discrete nonlinear Schrödinger equation (DNLSE) with a delayed cubic nonlinear term. It is found that for short delay time, the wave packet is self-trapping in first class of GF lattices, that is, the second moment grows with time, but the corresponding participation number does not grow. However, both the second moment and the participation number grow with time for large delay time. This illuminates that the wave packet is delocalized. For the second class of GF lattices, the dynamic behaviors of wave packet depend on the strength of on-site potential. For a weak on-site potential, the results are similar to the case of the first class. For a strong on-site potential, both the second moment and the participation number does not grow with time in the regime of short delay time. In the regime of large delay time, both the second moment and the participation number exhibit stair-like growth.

  13. Influence of group—velocity mismatch on soliton switching in a nonlinear fibre coupler

    Institute of Scientific and Technical Information of China (English)

    LiHong; HuangDe-Xiu; WangDong-Ning

    2003-01-01

    In this work, the influence of group-velocity mismatch on soliton self-routing pulse switching in a nonlinear fibre coupler is discussed in detail by the use of both variational approach and numerical simulation. The results obtained show that the group-velocity mismatch leads to the relative displacement between the two orthogonal polarization modes, increase of the critical power, and reduction of the elimination-light ratio. For sub-ps pulse, the influence cannot be neglected.

  14. Influence of group-velocity mismatch on soliton switching in a nonlinear fibre coupler

    Institute of Scientific and Technical Information of China (English)

    李宏; 黄德修; 王东宁

    2003-01-01

    In this work, the influence of group-velocity mismatch on soliton self-routing pulse switching in a nonlinear fibrecoupler is discussed in detail by the use of both variational approach and numerical simulation. The results obtainedshow that the group-velocity mismatch leads to the relative displacement between the two orthogonal polarizationmodes, increase of the critical power, and reduction of the elimination-light ratio. For sub-ps pulse, the influence cannot be neglected.

  15. 非线性强度任意二聚的非线性链的透射性质%Transport properties of nonlinear chains with random dimer nonlinearity parameters

    Institute of Scientific and Technical Information of China (English)

    胡冬生; 张艳玲; 尹小刚; 徐江

    2012-01-01

    By using the recursion relation of discrete Schrodinger equation we investigate the transport properties of nonlinear chains with random dimer nonlinearity parameters. It is shown that there is a resonance state, which is just the product of the nonlinearity and the square of the incident wave amplitude modulus. The transmission coefficients are calculated in two conditions. One is that the transmission wave amplitude is a certain value, the other is that the incident wave amplitude modulus is a certain value. There are obvious differences in non-resonant states between the two kinds of conditions. The transmission is a single value function of the electronic energy for the former. However, it will be multi-stability for the latter. It is pointed out that the influence of the nonlinearity parameters on the transport properties can be exactly reflected only when the modulus of incident wave is set to be a certain value.%用离散的非线性薛定谔的递推关系研究了非线性强度任意二聚的非线性链的透射性质.结果表明该链存在一个共振透射态,共振态的能量为非线性强度与入射波振幅模平方的乘积;取出射波振幅为定值和取入射波振幅模为定值来计算透射系数,其结果在非共振态有明显的差别:取出射波振幅为定值时电子的透射随能量为单值函数,而取入射波振幅模为定值时电子的透射呈现多稳态.并指出只有取入射波振幅模为定值时才能真正反映非线性强度对电子透射性质的影响.

  16. Existence of positive solutions for nonlinear dynamic systems with a parameter on a measure chain

    Directory of Open Access Journals (Sweden)

    Shuang-Hong Ma

    2007-05-01

    Full Text Available In this paper, we consider the following dynamic system with parameter on a measure chain $mathbb{T}$, $$displaylines{ u^{DeltaDelta}_{i}(t+lambda h_{i}(tf_{i}(u_{1}(sigma(t, u_{2}(sigma(t,dots ,u_{n}(sigma(t=0,quad tin[a,b], cr alpha u_{i}(a-eta u^{Delta}_{i}(a=0,quad gamma u_{i}(sigma(b+delta u^{Delta}_{i}(sigma(b=0, }$$ where $i=1,2,dots ,n$. Using fixed-point index theory, we find sufficient conditions the existence of positive solutions.

  17. Antigen nature and complexity influence human antibody light chain usage and specificity.

    Science.gov (United States)

    Smith, Kenneth; Shah, Hemangi; Muther, Jennifer J; Duke, Angie L; Haley, Kathleen; James, Judith A

    2016-05-27

    Human antibodies consist of a heavy chain and one of two possible light chains, kappa (κ) or lambda (λ). Here we tested how these two possible light chains influence the overall antibody response to polysaccharide and protein antigens by measuring light chain usage in human monoclonal antibodies from antibody secreting cells obtained following vaccination with Pneumovax23. Remarkably, we found that individuals displayed restricted light chain usage to certain serotypes and that lambda antibodies have different specificities and modes of cross-reactivity than kappa antibodies. Thus, at both the monoclonal (7 kappa, no lambda) and serum levels (145μg/mL kappa, 2.82μg/mL lambda), antibodies to cell wall polysaccharide were nearly always kappa. The pneumococcal reference serum 007sp was analyzed for light chain usage to 12 pneumococcal serotypes for which it is well characterized. Similar to results at the monoclonal level, certain serotypes tended to favor one of the light chains (14 and 19A, lambda; 6A and 23F, kappa). We also explored differences in light chain usage at the serum level to a variety of antigens. We examined serum antibodies to diphtheria toxin mutant CRM197 and Epstein-Barr virus protein EBNA-1. These responses tended to be kappa dominant (average kappa-to-lambda ratios of 4.52 and 9.72 respectively). Responses to the influenza vaccine were more balanced with kappa-to-lambda ratio averages having slight strain variations: seasonal H1N1, 1.1; H3N2, 0.96; B, 0.91. We conclude that antigens with limited epitopes tend to produce antibodies with restricted light chain usage and that in most individuals, antibodies with lambda light chains have specificities different and complementary to kappa-containing antibodies.

  18. A non-linear approach to the structure-mobility relationship in protein main chains

    Energy Technology Data Exchange (ETDEWEB)

    Morariu, V.V. [Department of Molecular and Biomolecular Physics, National R and D Institute for Isotopic and Molecular Technology, P.O. Box 700, 400293 Cluj-Napoca (Romania); Isvoran, Adriana [Department of Chemistry, West University of Timisoara, Str. Pestalozzi 16, 300115 Timisoara (Romania)]. E-mail: aisvoran@yahoo.com; Zainea, Oana [Department of Molecular and Biomolecular Physics, National R and D Institute for Isotopic and Molecular Technology, P.O. Box 700, 400293 Cluj-Napoca (Romania)

    2007-05-15

    A correlation investigation was carried out on the series of atomic coordinates (MPV) and temperature factor (T {sub f}), respectively for human hemoglobin and HIV-1 protease protein main chains. The MPV series revealed resemblances to the corresponding T {sub f} series. Each minor or major peak in a series had a corresponding peak in the related series. This brings a qualitative evidence for the connection of the two parameters. The series were further subjected to spectral and detrended fluctuation analysis which all revealed long-range correlation properties. This combined analysis revealed that the data were controlled both by the correlation of stationary fluctuation and trends or non-stationary contribution to correlation. The correlation of all MPV series was found to be much less sensitive to ligand binding than the corresponding T {sub f} series. Thus the long-range correlation properties of the protein main chain structure and mobility revealed two complementary properties of protein molecules. While structure imparts constancy to the system, the atomic mobility represents function yet they are intimately connected.

  19. The influence of intertrial interval food on extinction and devaluation in chain schedules.

    Science.gov (United States)

    Bell, Matthew C; Goldenberg, Matthew; McDevitt, Margaret A

    2007-04-01

    The authors exposed pigeons to 2 equal 3-link chains by using variable-interval schedules of reinforcement. An intertrial interval (ITI) bisected by free food separated the chains. After baseline training, the authors presented terminal links in a successive discrimination to devalue 1 terminal link: The authors reinforced responses to 1 terminal link and extinguished responses to the other. The authors then presented full chains in extinction, except that they continued to deliver free food during the midpoint of the ITI. There were 2 principal findings. First, across all extinction conditions, responding decreased but did not extinguish. Second, when extinction testing revealed a terminal link devaluation effect in the 3rd condition, responding to the initial link was affected, but not middle-link responding. Overall, the results suggested that ITI food presentations can exert a substantial effect on responding in 3-link chain schedules, and they appear to influence both the pattern of extinction and devaluation effects.

  20. Influence of Temporal Context on Value in the Multiple-Chains and Successive-Encounters Procedures

    Science.gov (United States)

    O'Daly, Matthew; Angulo, Samuel; Gipson, Cassandra; Fantino, Edmund

    2006-01-01

    This set of studies explored the influence of temporal context across multiple-chain and multiple-successive-encounters procedures. Following training with different temporal contexts, the value of stimuli sharing similar reinforcement schedules was assessed by presenting these stimuli in concurrent probes. The results for the multiple-chain…

  1. Factors Influencing Industry Uptake of Marketing & Supply Chain Innovations within the Australian Seafood Cooperative Research Centre

    NARCIS (Netherlands)

    Dentoni, D.; English, F.

    2012-01-01

    This study identifies factors influencing the Australian seafood industry’s adoption of marketing and supply chain innovations created from public-private funded research and development (R&D). A grounded theory approach was followed by comparing and contrasting the evidence from 35 projects fun

  2. Lattice model of linear telechelic polymer melts. II. Influence of chain stiffness on basic thermodynamic properties

    Science.gov (United States)

    Xu, Wen-Sheng; Freed, Karl F.

    2015-07-01

    The lattice cluster theory (LCT) for semiflexible linear telechelic melts, developed in Paper I, is applied to examine the influence of chain stiffness on the average degree of self-assembly and the basic thermodynamic properties of linear telechelic polymer melts. Our calculations imply that chain stiffness promotes self-assembly of linear telechelic polymer melts that assemble on cooling when either polymer volume fraction ϕ or temperature T is high, but opposes self-assembly when both ϕ and T are sufficiently low. This allows us to identify a boundary line in the ϕ-T plane that separates two regions of qualitatively different influence of chain stiffness on self-assembly. The enthalpy and entropy of self-assembly are usually treated as adjustable parameters in classical Flory-Huggins type theories for the equilibrium self-assembly of polymers, but they are demonstrated here to strongly depend on chain stiffness. Moreover, illustrative calculations for the dependence of the entropy density of linear telechelic polymer melts on chain stiffness demonstrate the importance of including semiflexibility within the LCT when exploring the nature of glass formation in models of linear telechelic polymer melts.

  3. Lattice model of linear telechelic polymer melts. II. Influence of chain stiffness on basic thermodynamic properties

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Wen-Sheng, E-mail: wsxu@uchicago.edu [James Franck Institute, The University of Chicago, Chicago, Illinois 60637 (United States); Freed, Karl F., E-mail: freed@uchicago.edu [James Franck Institute, The University of Chicago, Chicago, Illinois 60637 (United States); Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 (United States)

    2015-07-14

    The lattice cluster theory (LCT) for semiflexible linear telechelic melts, developed in Paper I, is applied to examine the influence of chain stiffness on the average degree of self-assembly and the basic thermodynamic properties of linear telechelic polymer melts. Our calculations imply that chain stiffness promotes self-assembly of linear telechelic polymer melts that assemble on cooling when either polymer volume fraction ϕ or temperature T is high, but opposes self-assembly when both ϕ and T are sufficiently low. This allows us to identify a boundary line in the ϕ-T plane that separates two regions of qualitatively different influence of chain stiffness on self-assembly. The enthalpy and entropy of self-assembly are usually treated as adjustable parameters in classical Flory-Huggins type theories for the equilibrium self-assembly of polymers, but they are demonstrated here to strongly depend on chain stiffness. Moreover, illustrative calculations for the dependence of the entropy density of linear telechelic polymer melts on chain stiffness demonstrate the importance of including semiflexibility within the LCT when exploring the nature of glass formation in models of linear telechelic polymer melts.

  4. Analysis of the Evolution and Influence on the Industrial Value Chain in Telecommunications

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao-ming; LI Shi-ming; TAN Yang

    2006-01-01

    This paper discusses the evolution of telecommunication industrial value chain(TIVC), analyzes the influence of technical innovation and customer demand on TIVC, and establishes the model. The appearance of the circuit switching technology and packet switching technology together with the diversity of the demand of customers change the structure of TIVC,causing vibration in value creation and distribution systems. With changes of the TIVC,enterprises in the chain will accordingly alter their business models, products (services) and the internal organizational structures. All these changes will lead to the reconstruction and optimization of the TIVC, and consequently, promote the development of the telecommunication industry.

  5. Unreliable gut feelings can lead to correct decisions: The somatic marker hypothesis in non-linear decision chains

    Directory of Open Access Journals (Sweden)

    Manuel eBedia

    2012-10-01

    Full Text Available Dual system approaches of decision making examine the interaction between affective/intuitive and deliberative processes underlying value judgment. Decisions are arise from a combination of relatively explicit capabilities for abstract reasoning and relatively implicit evolved domain-general as well as learned domain-specific affective responses. One such approach, the somatic markers hypothesis (SMH, expresses these processes as a system of evolved primary emotions supplemented by associations between affect and experience that accrue over lifetime, or somatic markers (SMs. In this view, SMs are useful only if their local capability to predict the value of an action is above a baseline equal to the predictive capability of the combined rational and primary emotional subsystems. We argue that decision making has often been conceived of as a linear process: the effect of decision sequences is additive, local utility is cumulative, and there is no strong environmental feedback. This widespread assumption has consequences for answering questions regarding the relative weight between the systems and their interaction within a cognitive architecture. We introduce a mathematical formalization of the SMH and study it in situations of dynamic, nonlinear decision chains using a discrete-time stochastic model. We find, contrary to expectations, that decision making events can interact non-additively with the environment in apparently paradoxical ways. We find that primary emotions are represented globally over and above their local weight, showing a tendency for overcaution in situated decision chains. We also show that because they tend to counteract this trend, poorly attuned somatic markers that by themselves do not locally enhance decision making, can still produce an overall positive effect. This result has developmental and evolutionary implications since, by promoting exploratory behavior, SMs are beneficial even at early stages when experiential

  6. Influence of the demand information quality on planning process accuracy in supply chain. Case studies

    Directory of Open Access Journals (Sweden)

    Natalia Szozda

    2013-06-01

    Full Text Available Background: Identification and analysis of factors that affect the accuracy of demand planning process across the supply chain is one of the most important problems which influence the effectiveness of its material and information flows. Material and methods: On the basis of demand planning process investigation authors define the main elements affecting the right supply chain performance level and investigate the possible connections between demand information quality and demand planning process accuracy. Later, an overview of some recent developments in the analyzed research area is provided. Results: Based on the literature review, there is described the defined factors impact on the accuracy of demand plan in each echelon for case companies. There are considered three cases. The examples illustrate supply chains of different manufacturing companies. The focus is placed on demand planning across the supply chains. The issue of determining the accuracy of future sales plans in each echelon of supply chains and factors affecting it are raised. Taking into account the case companies demand planning process analyses, there are defined possible quality measures, that are possible to be used when forecasting the customer demand. Conclusions: One of the most important and difficult planning area in the companies is becoming planning demand. Errors in planning are reflected not just in the business resource planning but also in the entire supply chain. Presented cases show that many factors affect the proper demand planning process in the supply chain, like e.g.  information technologies, lead-time, or number of supplied materials. As it can be seen from the case studies, the model of collecting information from the market plays an important role in the demand planning process.

  7. Influence of annealing on chain entanglement and molecular dynamics in weak dynamic asymmetry polymer blends.

    Science.gov (United States)

    Lin, Yu; Tan, Yeqiang; Qiu, Biwei; Shangguan, Yonggang; Harkin-Jones, Eileen; Zheng, Qiang

    2013-01-17

    The influence of annealing above the glass transition temperature (T(g)) on chain entanglement and molecular dynamics of solution-cast poly(methyl methacrylate)/poly(styrene-co-maleic anhydride) (PMMA/SMA) blends was investigated via a combination of dynamic rheological measurement and broadband dielectric spectroscopy. Chain entanglement density increases when the annealing temperature and/or time increases, resulting from the increased efficiency of chain packing and entanglement recovery. The results of the annealing treatment without cooling revealed that the increase of the entanglement density occurred during the annealing process instead of the subsequent cooling procedure. Annealing above T(g) exerts a profound effect on segmental motion, including the transition temperature and dynamics. Namely, T(g) shifts to higher temperatures and the relaxation time (τ(max)) increases due to the increased entanglement density and decreased molecular mobility. Either T(g) or τ(max) approaches an equilibrium value gradually, corresponding to the equilibrium entanglement density that might be obtained through the theoretical predictions. However, no obvious distribution broadening is observed due to the unchanged heterogeneous dynamics. Furthermore, side group rotational motion could be freely achieved without overcoming the chain entanglement resistance. Hence, neither the dynamics nor the distribution width of the subglass relaxation (β- and γ-relaxation) processes is affected by chain entanglement resulting from annealing, indicating that the local environment of the segments is unchanged.

  8. Carbohydrate conformation and lipid condensation in monolayers containing glycosphingolipid Gb3: influence of acyl chain structure.

    Science.gov (United States)

    Watkins, Erik B; Gao, Haifei; Dennison, Andrew J C; Chopin, Nathalie; Struth, Bernd; Arnold, Thomas; Florent, Jean-Claude; Johannes, Ludger

    2014-09-01

    Globotriaosylceramide (Gb3), a glycosphingolipid found in the plasma membrane of animal cells, is the endocytic receptor of the bacterial Shiga toxin. Using x-ray reflectivity (XR) and grazing incidence x-ray diffraction (GIXD), lipid monolayers containing Gb3 were investigated at the air-water interface. XR probed Gb3 carbohydrate conformation normal to the interface, whereas GIXD precisely characterized Gb3's influence on acyl chain in-plane packing and area per molecule (APM). Two phospholipids, 1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC) and 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine (DPPE), were used to study Gb3 packing in different lipid environments. Furthermore, the impact on monolayer structure of a naturally extracted Gb3 mixture was compared to synthetic Gb3 species with uniquely defined acyl chain structures. XR results showed that lipid environment and Gb3 acyl chain structure impact carbohydrate conformation with greater solvent accessibility observed for smaller phospholipid headgroups and long Gb3 acyl chains. In general, GIXD showed that Gb3 condensed phospholipid packing resulting in smaller APM than predicted by ideal mixing. Gb3's capacity to condense APM was larger for DSPC monolayers and exhibited different dependencies on acyl chain structure depending on the lipid environment. The interplay between Gb3-induced changes in lipid packing and the lipid environment's impact on carbohydrate conformation has broad implications for glycosphingolipid macromolecule recognition and ligand binding.

  9. The Influence of Dust on the Farley-Buneman instability. Nonlinear regimes.

    Science.gov (United States)

    Atamaniuk, Barbara

    In the lower ionosphere in the E-region, a complex process transforms wind energy into currents creating the E-region electrojet. If these currents exceed a certain critical amplitude, a streaming instability called the Farley-Buneman or a collisional two-stream instability develops. This instability grows more rapidly at shorter wavelengths and the waves propagate nearly perpendicular to the magnetic field. It is well known that even system with finite number of interacting waves can realize a turbulent state in active media. In such cases, when the number of cooperating waves remains small due to a competition of processes of their instability and attenuation, the turbulence appears in the result of their stochastic behavior. The perturbed ionospheric plasma is one of important example of such active media. The regimes of nonlinear stabilization of instability of low frequency waves in magnetized, weakly ionized and inhomogeneous ionospheric dusty plasma are considered. We make assumptions that the Earth magnetic field has no influence on the ions and on the dust particles so only the electrons are magnetized. If characteristic time of plasma density oscillations exceeds an electron collision frequency the basic is drift motion of electrons and, accordingly, the vector nonlinearity is the strongest. We study of nonlinear stabilization and influence of the dust component, conditions of stochasticity and the different regimes in the conditions when the number of interacting waves keeps small by the strong competition of processes wave damping and instabilities are considered. *This research is supported by KBN grant 0TOOA 01429 1. Meers Oppenheim and Niels Otani, Hybrid Simulations of the Saturated Farley-Buneman Instability in the Ionosphere, Geophysical Research Letters, 22, pp. 353-356, 1995 2. Meers Oppenheim and Niels Otani and Corrado Ronchi, Saturation of the Farley-Buneman instability via nonlinear electron ExB drifts, Journal of Geophysical Research, 101

  10. Influence of resonator shape on nonlinear acoustic field in a thermoacoustic engine

    Institute of Scientific and Technical Information of China (English)

    LIU Danxiao; ZHOU Chengguang; LIU Ke

    2012-01-01

    The influence of the resonator shape on nonlinear acoustic field in a thermoacous- tic engine is studied. The resonator of themoacoustic engine is boundary driving by a piston at one end, and the other end of it is rigid closed. A one-dimensional wave equation that accounts for gas dynamic nonlinearities and viscous dissipation in the resonator is established based on the governing equations of viscous hydromechanics. The nonlinear wave equation is solved using approximate Galerkin method. The nonlinear acoustic field in four different types of shaped resonators including hyperbolical, exponential, conical and sinusoidal are obtained and compared with that of a cylindrical resonator. It is found that the amplitude and wave- form of the pressure are strongly affected by the resonator shape, the driving amplitude and the oscillation frequency of the piston. Waveform distortion, resonance frequency shift and hysteresis are observed, when the piston oscillation amplitude is large enough. The advantages of shaped resonator for thermoacoustic engine lie in inhibition of higher order harmonics and improvement of pressure ratio, etc.

  11. Thermoelectric transport through a zigzag like chain: Influence of the chain length, the interdot tunneling and the intradot Coulomb interaction

    Energy Technology Data Exchange (ETDEWEB)

    Li, Rui-Xue, E-mail: li19851025@126.com [School of Science, Henan Institute of Engineering, Zhengzhou 451191 (China); Ni, Yun [Wenhua College, Huazhong University of Science and Technology, Wuhan 430074 (China); Li, Hai-Dong; Tian, Xing-Ling [School of Science, Henan Institute of Engineering, Zhengzhou 451191 (China); Yao, Kai-Lun; Fu, Hua-Hua [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2016-07-15

    We have studied the thermoelectric transport through a zigzaglike chain in the linear response regime using the non-equilibrium Green's function method. This model consists of the main zigzaglike chain and the side radicals coupled with the main chain at the next-near-neighbor sites. The finite-scale effect on the thermoelectric properties has been studied, our results show that thermoelectric efficiency can be enhanced by increasing the chain length. The thermopower and the figure of merit can be enhanced by strengthening the interdot tunneling coupling between the main chain and the side radicals. However, increase of the interdot tunneling coupling in the main chain can weaken the thermoelectric efficiency. Moreover, the thermoelectric efficiency is also strongly dependent on the intradot Coulomb interaction. These results can provide a guidance for the synthesis of thermal devices with high thermoelectric efficiency.

  12. Influence of chain length and double bond on the aqueous behavior of choline carboxylate soaps.

    Science.gov (United States)

    Rengstl, Doris; Diat, Olivier; Klein, Regina; Kunz, Werner

    2013-02-26

    In preceding studies, we demonstrated that choline carboxylates ChC(m) with alkyl chain lengths of m = 12 - 18 are highly water-soluble (for m = 12, soluble up to 93 wt % soap and 0 °C). In addition, choline soaps are featured by an extraordinary lyotropic phase behavior. With decreasing water concentration, the following phases were found: micellar phase (L(1)), discontinuous cubic phase (I(1)' and I(1)"), hexagonal phase (H(1)), bicontinuous cubic phase (V(1)), and lamellar phase (L(α)). The present work is also focused on the lyotropic phase behavior of choline soaps but with shorter alkyl chains or different alkyl chain properties. We have investigated the aqueous phase behavior of choline soaps with C(8) and C(10) chain-lengths (choline octanoate and choline decanoate) and with a C(18) chain-length with a cis-double bond (choline oleate). We found that choline decanoate follows the lyotropic phase behavior of the longer-chain homologues mentioned above. Choline octanoate in water shows no discontinuous cubic phases, but an extended, isotropic micellar solution phase. In addition, choline octanoate is at the limit between a surfactant and a hydrotrope. The double bond in choline oleate leads also to a better solubility in water and a decrease of the solubilization temperature. It also influences the Gaussian curvature of the aggregates which results in a loss of discontinuous cubic phases in the binary phase diagram. The different lyotropic mesophases were identified by the penetration scan technique with polarizing light microscope and visual observations. To clarify the structural behavior small (SAXS) and wide (WAXS) angle X-ray scattering were performed. To further characterize the extended, isotropic micellar solution phase in the binary phase diagram of choline octanoate viscosity and conductivity measurements were also carried out.

  13. Unreliable gut feelings can lead to correct decisions: the somatic marker hypothesis in non-linear decision chains.

    Science.gov (United States)

    Bedia, Manuel G; Di Paolo, Ezequiel

    2012-01-01

    Dual-process approaches of decision-making examine the interaction between affective/intuitive and deliberative processes underlying value judgment. From this perspective, decisions are supported by a combination of relatively explicit capabilities for abstract reasoning and relatively implicit evolved domain-general as well as learned domain-specific affective responses. One such approach, the somatic markers hypothesis (SMH), expresses these implicit processes as a system of evolved primary emotions supplemented by associations between affect and experience that accrue over lifetime, or somatic markers. In this view, somatic markers are useful only if their local capability to predict the value of an action is above a baseline equal to the predictive capability of the combined rational and primary emotional subsystems. We argue that decision-making has often been conceived of as a linear process: the effect of decision sequences is additive, local utility is cumulative, and there is no strong environmental feedback. This widespread assumption can have consequences for answering questions regarding the relative weight between the systems and their interaction within a cognitive architecture. We introduce a mathematical formalization of the SMH and study it in situations of dynamic, non-linear decision chains using a discrete-time stochastic model. We find, contrary to expectations, that decision-making events can interact non-additively with the environment in apparently paradoxical ways. We find that in non-lethal situations, primary emotions are represented globally over and above their local weight, showing a tendency for overcautiousness in situated decision chains. We also show that because they tend to counteract this trend, poorly attuned somatic markers that by themselves do not locally enhance decision-making, can still produce an overall positive effect. This result has developmental and evolutionary implications since, by promoting exploratory behavior

  14. Electrochemical survey of the chain length influence in phytochelatins competitive binding by cadmium.

    Science.gov (United States)

    Gusmão, Rui; Ariño, Cristina; Díaz-Cruz, José Manuel; Esteban, Miquel

    2010-11-01

    Multivariate curve resolution with alternating least squares (MCR-ALS) was applied to voltammetric data obtained in the analysis of the competitive binding of glutathione (GSH) and phytochelatins [(gammaGlu-Cys)(n)-Gly, PC(n), n=2-5] by Cd(2+). The displacements between ligands and chain length influence on the competitive binding of PC(n) toward Cd(2+) were investigated. The analysis of the resulting pure voltammograms and concentration profiles of the resolved components suggests that ligands containing more thiol groups are able to displace the shortest chain ligands from their metal complexes, whereas the opposite does not happen. However, when the length of the chain surpasses that of PC(3), the binding capacity of the molecule still increases (i.e., it can bind more metal ions), but the position and shape of the voltammetric signals practically rest unchanged. This suggests that at this level, the stability of metal binding could depend more on the nature of the binding sites separately than on the quantity of the sites (i.e., the chain length).

  15. Influence of backbone rigidness on single chain conformation of thiophene-based conjugated polymers.

    Science.gov (United States)

    Hu, Zhongjian; Liu, Jianhua; Simón-Bower, Lauren; Zhai, Lei; Gesquiere, Andre J

    2013-04-25

    Structural order of conjugated polymers at different length scales directs the optoelectronic properties of the corresponding materials; thus it is of critical importance to understand and control conjugated polymer morphology for successful application of these materials in organic optoelectronics. Herein, with the aim of probing the dependence of single chain folding properties on the chemical structure and rigidness of the polymer backbones, single molecule fluorescence spectroscopy was applied to four thiophene-based conjugated polymers. These include regioregular poly(3-hexylthiophene) (RR-P3HT), poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene) (PBTTT-14), poly(2,5-bis(3-tetradecylthiophen-2-yl)thiophene-2-yl)thiophen-2-ylthiazolo[5,4-d]thiazole) (PTzQT-12), and poly(3,3-didodecylquaterthiophene)] (PQT-12). Our previous work has shown that RR-P3HT and PBTTT-14 polymer chains fold in their nanostructures, whereas PQT-12 and PTzQT-12 do not fold in their nanostructures. At the single molecule level, it was found that RR-P3HT single chains almost exclusively fold into loosely and strongly aggregated conformations, analogous to the folding properties in nanostructures. PQT-12 displays significant chain folding as well, but only into loosely aggregated conformations, showing an absence of strongly aggregated polymer chains. PBTTT-14 exhibits a significant fraction of rigid polymer chain. The findings made for single molecules of PQT-12 and PBTTT-14 are thus in contrast with the observations made in their corresponding nanostructures. PTzQT-12 appears to be the most rigid and planar conjugated polymer of these four polymers. However, although the presumably nonfolding polymers PQT-12 and PTzQT-12 exhibit less folding than RR-P3HT, there is still a significant occurrence of chain folding for these polymers at the single molecule level. These results suggest that the folding properties of conjugated polymers can be influenced by the architecture of the

  16. Influence of chain topology and bond potential on the glass transition of polymer chains simulated with the bond fluctuation model

    Energy Technology Data Exchange (ETDEWEB)

    Freire, J J [Departamento de Ciencias y Tecnicas FisicoquImicas, Facultad de Ciencias, Universidad Nacional de Educacion a Distancia (UNED), Senda del Rey 9, 28040 Madrid (Spain)], E-mail: jfreire@invi.uned.es

    2008-07-16

    The bond fluctuation model with a bond potential has been applied to investigation of the glass transition of linear chains and chains with a regular disposition of small branches. Cooling and subsequent heating curves are obtained for the chain energies and also for the mean acceptance probability of a bead jump. In order to mimic different trends to vitrification, a factor B gauging the strength of the bond potential with respect to the long-range potential (i.e. the intramolecular or intermolecular potential between indirectly bonded beads) has been introduced. (A higher value of B leads to a preference for the highest bond lengths and a higher total energy, implying a greater tendency to vitrify.) Different cases have been considered for linear chains: no long-range potential, no bond potential and several choices for B. Furthermore, two distinct values of B have been considered for alternate bonds in linear chains. In the case of the branched chains, mixed models with different values of B for bonds in the main chain and in the branches have also been investigated. The possible presence of ordering or crystallization has been characterized by calculating the collective light scattering function of the different samples after annealing at a convenient temperature below the onset of the abrupt change in the curves associated with a thermodynamic transition. It is concluded that ordering is inherited more efficiently in the systems with branched chains and also for higher values of B. The branched molecules with the highest B values in the main chain bonds exhibit two distinct transitions in the heating curves, which may be associated with two glass transitions. This behavior has been detected experimentally for chains with relatively long flexible branches.

  17. Nonlinear supratransmission

    Energy Technology Data Exchange (ETDEWEB)

    Geniet, F; Leon, J [Physique Mathematique et Theorique, CNRS-UMR 5825, 34095 Montpellier (France)

    2003-05-07

    A nonlinear system possessing a natural forbidden band gap can transmit energy of a signal with a frequency in the gap, as recently shown for a nonlinear chain of coupled pendulums (Geniet and Leon 2002 Phys. Rev. Lett. 89 134102). This process of nonlinear supratransmission, occurring at a threshold that is exactly predictable in many cases, is shown to have a simple experimental realization with a mechanical chain of pendulums coupled by a coil spring. It is then analysed in more detail. First we go to different (nonintegrable) systems which do sustain nonlinear supratransmission. Then a Josephson transmission line (a one-dimensional array of short Josephson junctions coupled through superconducting wires) is shown to also sustain nonlinear supratransmission, though being related to a different class of boundary conditions, and despite the presence of damping, finiteness, and discreteness. Finally, the mechanism at the origin of nonlinear supratransmission is found to be a nonlinear instability, and this is briefly discussed here.

  18. Influence of dispersants on petroleum bioavailability to primary producers in a brackish water food chain

    Energy Technology Data Exchange (ETDEWEB)

    Younghans-Haug, C.O.; Wolfe, M.F.; Tjeerdema, R.S. [Univ. of California, Santa Cruz, CA (United States). Dept. of Chemistry and Biochemistry; Sowby, M.L. [Office of Oil Spill Prevention and Response, Sacramento, CA (United States)

    1994-12-31

    Petroleum is transported and processed within biologically rich brackish environments worldwide. Past research has investigated disposition of chemically dispersed oil in mammals, fish, and higher invertebrates, yet little is known about how chemical dispersion influences petroleum behavior within primary producers within brackish water food chains. One concern is whether chemical dispersion influences petroleum bioavailability to primary producers and the potential for increased petroleum bioaccumulation. This research examines changes in petroleum bioavailability to the euryhaline phytoplankton Isochrysis galbana by measuring bioconcentration factors (BCFS) including uptake and deputation rates for dispersed and undispersed brackish water oil spills. Isochrysis is a major food source for zooplankton which are consumed by a multitude of larval fish having both ecological and commercial importance. Prudhoe Bay Crude oil, Corexit 9527, and {sup 14}C-naphthalene were used for these studies. Constant-concentration flow-through exposures were employed for the uptake and BCF experiments. Work was performed below the ``no observable effect concentration`` to eliminate stress-induced metabolic altercations that could in themselves influence petroleum behavior. Exposure chamber and experimental design will be discussed, and study results presented. Understanding how chemical dispersion alters petroleum behavior within the lowest levels of the food chain leads to better delineation of consumer risks.

  19. How the choice of the observable may influence the analysis of nonlinear dynamical systems

    Science.gov (United States)

    Letellier, Christophe; Aguirre, Luis; Maquet, Jean

    2006-08-01

    A great number of techniques developed for studying nonlinear dynamical systems start with the embedding, in a d-dimensional space, of a scalar time series, lying on an m-dimensional object, d > m. In general, the main results reached at are valid regardless of the observable chosen. In a number of practical situations, however, the choice of the observable does influence our ability to extract dynamical information from the embedded attractor. This may arise in standard problems in nonlinear dynamics such as model building, control theory and synchronization. To some degree, ease of success will thus depend on the choice of observable simply because it is related to the observability of the dynamics. Investigating the Rössler system, we show that the observability matrix is related to the map between the original phase space and the differential embedding induced by the observable. This paper investigates a form for the observability matrix for nonlinear system which is more general than the previous one used. The problem of controllability is also mentioned.

  20. Competitive advantage in the ERP system's value-chain and its influence on future development

    Science.gov (United States)

    Johansson, Björn; Newman, Mike

    2010-02-01

    Using the resource-based view, we present a set of propositions related to enterprise resource planning (ERP) development, reflections on competitive advantage and the different roles that stakeholders play in the value-chain. This has the goal of building a foundation for future research on ERPs and how stakeholders' desire to achieve competitive advantage influence ERP development, especially when it comes to development of a more standardised or pre-customised ERP system. The propositions also act as a foundation for increasing our knowledge concerning the difficulty in developing improved ERP systems.

  1. Discrete nonlinear Schrödinger approximation of a mixed Klein Gordon/Fermi Pasta Ulam chain: Modulational instability and a statistical condition for creation of thermodynamic breathers

    Science.gov (United States)

    Johansson, Magnus

    2006-04-01

    We analyze certain aspects of the classical dynamics of a one-dimensional discrete nonlinear Schrödinger model with inter-site as well as on-site nonlinearities. The equation is derived from a mixed Klein-Gordon/Fermi-Pasta-Ulam chain of anharmonic oscillators coupled with anharmonic inter-site potentials, and approximates the slow dynamics of the fundamental harmonic of discrete small-amplitude modulational waves. We give explicit analytical conditions for modulational instability of travelling plane waves, and find in particular that sufficiently strong inter-site nonlinearities may change the nature of the instabilities from long-wavelength to short-wavelength perturbations. Further, we describe thermodynamic properties of the model using the grand-canonical ensemble to account for two conserved quantities: norm and Hamiltonian. The available phase space is divided into two separated parts with qualitatively different properties in thermal equilibrium: one part corresponding to a normal thermalized state with exponentially small probabilities for large-amplitude excitations, and another part typically associated with the formation of high-amplitude localized excitations, interacting with an infinite-temperature phonon bath. A modulationally unstable travelling wave may exhibit a transition from one region to the other as its amplitude is varied, and thus modulational instability is not a sufficient criterion for the creation of persistent localized modes in thermal equilibrium. For pure on-site nonlinearities the created localized excitations are typically pinned to particular lattice sites, while for significant inter-site nonlinearities they become mobile, in agreement with well-known properties of localized excitations in Fermi-Pasta-Ulam-type chains.

  2. LMI-based Research on Stability of Leagile Supply Chain with Grey Non-linear Characteristics%基于LMI的灰色非线性精敏供应链稳定性判定方法

    Institute of Scientific and Technical Information of China (English)

    张学龙; 王云峰

    2014-01-01

    平稳运行是精敏供应链管理的重要基础,针对具有区间灰色非线性特征的精敏供应链系统波动性的难题,以非线性时滞精敏供应链系统为研究基础,建立了灰色非线性精敏供应链系统,采用线性矩阵不等式算法分析其稳定性问题,并获取了一种灰色非线性精敏供应链系统的稳定性判定方法。为验证该方法的有效性和可行性,以医药行业YL集团核心产品的供应链系统为案例分析对象,通过观测两个时点的运行数据,使用Matlab7.0计算工具,得出[0,20]和[20,40]2个时间段供应链系统的稳定性状态变化图。并假设当客户订货分离点( CODP)下移时,运用同样的观测数据,模拟系统稳定性状态的变化。对比案例分析的结果得出结论:随着CODP从精敏供应链的上游端在下移至下游端时,不仅仅体现的是供应链系统类型的改变,而且更重要的是揭示了精益供应链和敏捷供应链稳定性的影响因素不同,前者受订单量大小程度的影响,而后者由市场需求预测的准确性程度决定。%In leagile supply chain management , it is important to operate a supply chain smoothly .Howev-er, with grey and non-linearity, it is very challenging to model and control such a supply chain .On the basis of non-linear and time delay leagile supply chain systems , a grey and non-linear model is developed for a leagile supply chain .Then, a linear matrix inequality method is used to analyze its stability and an effective stability criterion is obtained .In order to verify the feasibility and effectiveness of the proposed method, a core product supply chain systems of YL Group in the medicine industry is used as a case stud -y.By using Matlab 7.0, the stability of the system state diagram is drawn before and after customer order decoupling point ( CODP) .Results show that when CODP moves down , not only the supply chain type is changed but

  3. Entanglement of conjugated polymer chains influences molecular self-assembly and carrier transport

    KAUST Repository

    Zhao, Kui

    2013-06-26

    The influence of polymer entanglement on the self-assembly, molecular packing structure, and microstructure of low-Mw (lightly entangled) and high-Mw (highly entangled) poly (3-hexylthiophene) (P3HT), and the carrier transport in thin-film transistors, are investigated. The polymer chains are gradually disentangled in a marginal solvent via ultrasonication of the polymer solution, and demonstrate improved diffusivity of precursor species (coils, aggregates, and microcrystallites), enhanced nucleation and crystallization of P3HT in solution, and self-assembly of well-ordered and highly textured fibrils at the solid-liquid interface. In low-Mw P3HT, reducing chain entanglement enhances interchain and intrachain ordering, but reduces the interconnectivity of ordered domains (tie molecules) due to the presence of short chains, thus deteriorating carrier transport even in the face of improving crystallinity. Reducing chain entanglement in high-Mw P3HT solutions increases carrier mobility up to ≈20-fold, by enhancing interchain and intrachain ordering while maintaining a sufficiently large number of tie molecules between ordered domains. These results indicate that charge carrier mobility is strongly governed by the balancing of intrachain and interchain ordering, on the one hand, and interconnectivity of ordered domains, on the other hand. In high-Mw P3HT, intrachain and interchain ordering appear to be the key bottlenecks to charge transport, whereas in low-Mw P3HT, the limited interconnectivity of the ordered domains acts as the primary bottleneck to charge transport. Conjugated polymer chains of poly(3-hexylthiophene) (P3HT) are gradually disentangled in solution and trends in carrier transport mechanisms in organic thin film transistors for low- and high-molecular weight P3HT are investigated. While intrachain and interchain ordering within ordered domains are the key bottlenecks to charge transport in high-Mw P3HT films, the limited interconnectivity of ordered

  4. On applying safety archetypes to the Fukushima accident to identify nonlinear influencing factors

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, A.L., E-mail: alsousa@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil); Ribeiro, A.C.O., E-mail: antonio.ribeiro@bayer.com [Bayer Crop Science Brasil S.A., Belford Roxo, RJ (Brazil); Duarte, J.P., E-mail: julianapduarte@poli.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola Politecnica. Departamento de Engenharia Nuclear; Frutuoso e Melo, P.F., E-mail: frutuoso@nuclear.ufrj.br [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COOPE/UFRJ), RJ (Brazil). Programa de Engenharia Nuclear

    2013-07-01

    Nuclear power plants are typically characterized as high reliable organizations. In other words, they are organizations defined as relatively error free over a long period of time. Another relevant characteristic of the nuclear industry is that safety efforts are credited to design. However, major accidents, like the Fukushima accident, have shown that new tools are needed to identify latent deficiencies and help improve their safety level. Safety archetypes proposed elsewhere (e. g., safety issues stalled in the face of technological advances and eroding safety) consonant with International Atomic Energy Agency (IAEA) efforts are used to examine different aspects of accidents in a systemic perspective of the interaction between individuals, technology and organizational factors. Safety archetypes can help consider nonlinear interactions. Effects are rarely proportional to causes and what happens locally in a system (near the current operating point) often does not apply to distant regions (other system states), so that one has to consider the so-called nonlinear interactions. This is the case, for instance, with human probability failure estimates and safety level identification. In this paper, we discuss the Fukushima accident in order to show how archetypes can highlight nonlinear interactions of factors that influenced it and how to maintain safety levels in order to prevent other accidents. The initial evaluation of the set of archetypes suggested in the literature showed that at least four of them are applicable to the Fukushima accident, as is inferred from official reports on the accident. These are: complacency (that is, the effects of complacency on safety), decreased safety awareness, fixing on symptoms and not the real causes and eroding safety. (author)

  5. Influence of Bearing Stiffness on the Nonlinear Dynamics of a Shaft-Final Drive System

    Directory of Open Access Journals (Sweden)

    Xu Jinli

    2016-01-01

    Full Text Available The bearing stiffness has a considerable influence on the nonlinear coupling vibration characteristics of the shaft-final drive system. A 14-DOF nonlinear coupled vibration model was established by employing the lumped mass method so as to identify the coupling effects of the bearing stiffness to the vibration response of the shaft-final drive system. The engine’s torque ripple, the alternating load from the universal joint (U-joint, and the time-varying mesh parameters of hypoid gear of the shaft-final drive system were also considered for accurate quantitative analysis. The numerical analysis of the vibration response of the coupled system was performed and the experimental measurements were carried out for the validation test. Results show that, at the given driving speed, improving the bearing stiffness can reduce the vibration response of the given coupled system; however, when the bearing stiffness increases to a critical value, the effects of bearing stiffness on the vibration reduction become insignificant; when the driving speed changes, the resonance regions of the coupled system vary with the bearing stiffness. The results are helpful to determine the proper bearing stiffness and the optimum control strategy for the shaft-final drive system. It is hoped that the optimal shaft-final drive system can provide good vibration characteristics to achieve the energy saving and noise reduction for the vehicle application.

  6. A pilot, short-term dietary manipulation of branched chain amino acids has modest influence on fasting levels of branched chain amino acids

    OpenAIRE

    Cavallaro, Nicole Landa; Garry, Jamie; Shi, Xu; Gerszten, Robert E.; Anderson, Ellen J.; Walford, Geoffrey A.

    2016-01-01

    Background: Elevated fasting levels of branched chain amino acids (BCAAs: valine, isoleucine, leucine) in venous blood are associated with a variety of metabolic impairments, including increased risk of type 2 diabetes (T2D). Fasting BCAA levels are influenced by non-dietary factors. However, it is unknown whether fasting BCAAs can be altered through manipulation of dietary intake alone. Objective: To test whether a specific dietary intervention, using differences in BCAA intake, alters fasti...

  7. Image divide in destination marketing: an exploration of the chain of influence in South African tourism marketing

    OpenAIRE

    Cronje, Paul; Kokkranikal, Jithendran

    2008-01-01

    Tourism marketers including Destination Marketing Organisations (DMOs) and international tour operators play a pivotal role in the creation of induced images of destinations. These images, apparent in tourist brochures, are designed to influence tourist decision-making. This paper propose the concept of a Chain of Influence in induced imaging, suggesting that the content of marketing material is influenced by the priorities of those who design these materials. \\ud \\ud A content analysis of 2,...

  8. Nonlinear behavior of saturated porous crust under the influence of internal fluid source

    Science.gov (United States)

    Suetnova, Elena; Cherniavski, Vladimir

    2010-05-01

    We consider the effective stress evolution inside high porosity fault zone as a result of local dehydration due to heating. The rock is assumed to be a two-velocity medium; it consists of a deformable porous matrix (with Maxwell's rheology) and a Newtonian liquid that saturates this matrix. Nonlinear behavior of liquid saturated porous media in gravity filed under the influence of internal fluid source is modeled. The elaborated non-isothermal mathematical model is a thermodynamically consistent and closed model. The original scheme was used for computer simulation; the method implies numerical simulation for effective stress, deformation and flux time- space evolution. Deformation spreading through the saturated porous matrix occurs with pressure distortions. Calculations show that the peculiarity of effective stress evolution is dependent not only upon the volume of supplementary fluids, but upon the viscosity and elastic modules of matrix.

  9. Hyperbilirubinemia Influences Sleep-Wake Cycles of Term Newborns in a Non-Linear Manner

    Science.gov (United States)

    Zhang, Lian; Zhou, Yanxia; Li, Xufang; Cheng, Tingting

    2017-01-01

    Hyperbilirubinemia is a common cause for irreversible neuronal influence in the brain of term newborns, while the feature of neurological symptoms associated with hyperbilirubinemia has not been well characterized yet. In the present study, we examined a total of 203 neonates suffering from hyperbilirubinemia with a bedside amplitude-integrated Electroencephalography (aEEG) device, in order to determine whether there is any special change in sleep-wake cycles (SWCs). Among these patients, 14 cases showed no recognizable SWCs with the total serum bilirubin (TSB) level at 483.9–996.2 μmol/L; 75 cases exhibited reduced SWCs with the TSB level at 311.2–688.5 μmol/L; and the rest cases had the normal SWCs. The number of the normal SWCs occurrence had a significant negative correlation with the increased TSB level in a non-linear manner (r = -0.689, p <0.001). In addition, the increased TSB reshaped the structure of SWC by narrowing down the broadband and broadening the narrowband. Spearman’s correlation analysis indicated a significant negative correlation between the TSB level and the ratio of broadband (r = -0.618, p < 0.001), a significant positive correlation between the TSB level and the narrowband ratio (r = 0.618, p < 0.001), respectively. Furthermore, the change of SWC seemed like a continuous phenomenon, and the hyperbilirubinemia caused SWC changes was fit into a loess model in this paper. In summary, the hyperbilirubinemia influenced SWC of term newborns significantly at a non-linear manner, and these results revealed the feature of the neurological sequela that is associated with TSB. PMID:28072860

  10. The Influence of Chain Dynamics on the Far Infrared Spectrum of Liquid Methanol-Water Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Woods, K.N.; /Stanford U., Phys. Dept.; Wiedemann, H.; /SLAC, SSRL

    2005-07-12

    Far-infrared absorption spectroscopy has been used to study the low frequency ({center_dot} 100 cm{sup -1}) intermolecular modes of methanol in mixtures with water. With the aid of a first principles molecular dynamics simulation on an equivalent system, a detailed understanding about the origin of the low frequency IR modes has been established. The total dipole spectrum from the simulation suggests that the bands appearing in the experimental spectra at approximately 55 cm{sup -1} and 70 cm{sup -1} in methanol and methanol-rich mixtures arise from both fluctuations and torsional motions occurring within the methanol hydrogen-bonded chains. The influence of these modes on both the solvation dynamics and the relaxation mechanisms in the liquid are discussed within the context of recent experimental and theoretical results that have emerged from studies focusing on the short time dynamics in the methanol hydrogen bond network.

  11. Influence of heart rate in nonlinear HRV indices as a sampling rate effect evaluated on supine and standing

    Directory of Open Access Journals (Sweden)

    Juan Bolea

    2016-11-01

    Full Text Available The purpose of this study is to characterize and attenuate the influence of mean heart rate (HR on nonlinear heart rate variability (HRV indices (correlation dimension, sample and approximate entropy as a consequence of being the HR the intrinsic sampling rate of HRV signal. This influence can notably alter nonlinear HRV indices and lead to biased information regarding autonomic nervous system (ANS modulation.First, a simulation study was carried out to characterize the dependence of nonlinear HRV indices on HR assuming similar ANS modulation. Second, two HR-correction approaches were proposed: one based on regression formulas and another one based on interpolating RR time series. Finally, standard and HR-corrected HRV indices were studied in a body position change database.The simulation study showed the HR-dependence of non-linear indices as a sampling rate effect, as well as the ability of the proposed HR-corrections to attenuate mean HR influence. Analysis in a body position changes database shows that correlation dimension was reduced around 21% in median values in standing with respect to supine position (p < 0.05, concomitant with a 28% increase in mean HR (p < 0.05. After HR-correction, correlation dimension decreased around 18% in standing with respect to supine position, being the decrease still significant. Sample and approximate entropy showed similar trends.HR-corrected nonlinear HRV indices could represent an improvement in their applicability as markers of ANS modulation when mean HR changes.

  12. The influence of chain defects on the crystallisation behaviour of isotactic polypropylene

    Directory of Open Access Journals (Sweden)

    D. W. van der Meer

    2015-03-01

    Full Text Available The crystallization characteristics of the α-, β-and γ-phases of isotactic polypropylene were studied for welldefined and fully characterized polymers with varying amounts of stereo- and regio-defects. The specimens enabled us to study separately the influence of the type of chain defect and the concentration of defects on the parameters of interest. A combined defect fraction (CDF was introduced to describe arbitrary iPP samples with a varying amount of stereo- and regio-defects and a combination thereof. Crystal growth rates were found to decrease linearly with the defect fraction and were substantially stronger influenced by regio-defects as compared with stereo-defects. The deceleration of the growth rate of the β-phase is higher compared to the α-phase with increasing defect fraction. We also found a critical defect fraction, (Xcrit for which the growth rates of the α- and β-phases are equal. Analysis of the crystallization was performed using the model of Sanchez and Eby. Results of the analysis are in good agreement with the results found for the samples with a variation in the number of stereo-defects. The excess free energy for incorporating a stereo-defect into the trigonal crystal lattice of the β-phase is lower as compared with the α-phase. The theory correctly predicts the critical defect fraction, for which the growth rate of the α- and β-phase is equal.

  13. Experimental investigation on the influence of instrument settings on pixel size and nonlinearity in SEM image formation

    DEFF Research Database (Denmark)

    Carli, Lorenzo; Genta, Gianfranco; Cantatore, Angela;

    2010-01-01

    The work deals with an experimental investigation on the influence of three Scanning Electron Microscope (SEM) instrument settings, accelerating voltage, spot size and magnification, on the image formation process. Pixel size and nonlinearity were chosen as output parameters related to image....... Optimal instrument settings were also identified....

  14. Influence of hydrodynamic thrust bearings on the nonlinear oscillations of high-speed rotors

    Science.gov (United States)

    Chatzisavvas, Ioannis; Boyaci, Aydin; Koutsovasilis, Panagiotis; Schweizer, Bernhard

    2016-10-01

    This paper investigates the effect of hydrodynamic thrust bearings on the nonlinear vibrations and the bifurcations occurring in rotor/bearing systems. In order to examine the influence of thrust bearings, run-up simulations may be carried out. To be able to perform such run-up calculations, a computationally efficient thrust bearing model is mandatory. Direct discretization of the Reynolds equation for thrust bearings by means of a Finite Element or Finite Difference approach entails rather large simulation times, since in every time-integration step a discretized model of the Reynolds equation has to be solved simultaneously with the rotor model. Implementation of such a coupled rotor/bearing model may be accomplished by a co-simulation approach. Such an approach prevents, however, a thorough analysis of the rotor/bearing system based on extensive parameter studies. A major point of this work is the derivation of a very time-efficient but rather precise model for transient simulations of rotors with hydrodynamic thrust bearings. The presented model makes use of a global Galerkin approach, where the pressure field is approximated by global trial functions. For the considered problem, an analytical evaluation of the relevant integrals is possible. As a consequence, the system of equations of the discretized bearing model is obtained symbolically. In combination with a proper decomposition of the governing system matrix, a numerically efficient implementation can be achieved. Using run-up simulations with the proposed model, the effect of thrust bearings on the bifurcations points as well as on the amplitudes and frequencies of the subsynchronous rotor oscillations is investigated. Especially, the influence of the magnitude of the axial force, the geometry of the thrust bearing and the oil parameters is examined. It is shown that the thrust bearing exerts a large influence on the nonlinear rotor oscillations, especially to those related with the conical mode of the

  15. Myosin Light Chain Kinase (MLCK) Gene Influences Exercise Induced Muscle Damage during a Competitive Marathon.

    Science.gov (United States)

    Del Coso, Juan; Valero, Marjorie; Lara, Beatriz; Salinero, Juan José; Gallo-Salazar, César; Areces, Francisco

    2016-01-01

    Myosin light chain kinase (MLCK) phosphorylates the regulatory light chain (RLC) of myosin producing increases in force development during skeletal muscle contraction. It has been suggested that MLCK gene polymorphisms might alter RLC phosphorylation thereby decreasing the ability to produce force and to resist strain during voluntary muscle contractions. Thus, the genetic variations in the MLCK gene might predispose some individuals to higher values of muscle damage during exercise, especially during endurance competitions. The aim of this investigation was to determine the influence of MLCK genetic variants on exercise-induced muscle damage produced during a marathon. Sixty-seven experienced runners competed in a marathon race. The MLCK genotype (C37885A) of these marathoners was determined. Before and after the race, a sample of venous blood was obtained to assess changes in serum myoglobin concentrations and leg muscle power changes were measured during a countermovement jump. Self-reported leg muscle pain and fatigue were determined by questionnaires. A total of 59 marathoners (88.1%) were CC homozygotes and 8 marathoners (11.9%) were CA heterozygotes. The two groups of participants completed the race with a similar time (228 ± 33 vs 234 ± 39 min; P = 0.30) and similar self-reported values for fatigue (15 ± 2 vs 16 ± 2 A.U.; P = 0.21) and lower-limb muscle pain (6.2 ± 1.7 vs 6.6 ± 1.8 cm; P = 0.29). However, CC marathoners presented higher serum myoglobin concentrations (739 ± 792 vs 348 ± 144 μg·mL-1; P = 0.03) and greater pre-to-post- race leg muscle power reduction (-32.7 ± 15.7 vs -21.2 ± 21.6%; P = 0.05) than CA marathoners. CA heterozygotes for MLCK C37885A might present higher exercise-induced muscle damage after a marathon competition than CC counterparts.

  16. Influence of nonlinear waves on sandbar migrations using Monte Carlo simulations

    Science.gov (United States)

    Abreu, Tiago; Figueiredo, Fábio; Silva, Paulo A.

    2014-05-01

    Coastal systems typically involve a variety of natural processes working together. Understanding the interaction between waves and currents and its influence on long-term geomorphological evolution of coastlines and sandbar features is of great importance for coastal managers and policy makers. Our knowledge and understanding of these processes has undergone significant developments in the last decades but this issue still remains a challenge to researchers. The modelling of the sea bed topography changes in the coastal zone can be obtained from numerical simulation of hydrodynamic and sediment transport processes. In the present work, one adopts a morphodynamic model that considers an intra-wave approach. The sediment transport processes are resolved for each individual wave cycle in conjunction with a sediment continuity equation, enabling to calculate morphological changes through time. In this work, we investigate the performance of the morphodynamic model to simulate sandbar migration. The numerical results are compared against the observed beach profile evolutions obtained during the European project "Large Installations Plan" (LIP) (Arcilla et al., 1994). The LIP 1B case is investigated, corresponding to an erosive case, typical of storm events, where a breaker bar in the surf zone migrates offshore. The large-scale laboratory experiments were performed in the Delta flume of Deltares, resulting into a two-dimensional analysis (2D). Consequently, this work contributes to the cross-shore transport problem, particularly, for the modelling of nearshore sandbars. The ability of practical sediment transport models, recognized to capture the interaction between non-linear waves and undertow currents, is assessed (e.g., Hoefel and Elgar, 2003; Silva et al., 2006; Nielsen, 2006; Abreu et al., 2013). Local values for the non-linear parameters (wave asymmetry and skewness) are computed in the model according to Ruessink et al. (2012). In particular, this study

  17. A Nonlinear Finite Element Method for Magnetoelectric Composite and the Study on the Influence of Interfacial Bonding

    Directory of Open Access Journals (Sweden)

    He-Ling Wang

    2013-01-01

    Full Text Available Magnetoelectric composite material is effective in transferring magnetic field into electric signal. In this paper, a nonlinear finite element method is present to model the magnetoelectric composite of ferroelectric and magnetostrictive material. In the method, the nonlinear and coupling behavior of magnetostrictive material such as Terfenol-D is considered. The nonuniform magnetic, electric, and mechanical field distributions are present. An interfacial transferring coefficient is defined to investigate the performance of interfacial mechanical coupling quantitatively, and the influence of the properties of interfacial bonding material and interfacial cracks on magnetoelectric coefficient is discussed. A new laminate ME composite of curved interface is proposed to overcome weak interfacial bonding.

  18. Influence of strain/stress on the nonlinear-optical properties of sprayed deposited ZnO:Al thin films

    Energy Technology Data Exchange (ETDEWEB)

    Bahedi, K., E-mail: bahedikhadija@yahoo.fr [Laboratoire Optoelectronique et Physico-chimie des Materiaux.Unite de recherche associe au CNRST-URAC-14. Universite Ibn Tofail, Faculte des Sciences BP 133 Kenitra 14000 (Morocco); Addou, M.; Jouad, M. El; Sofiani, Z. [Laboratoire Optoelectronique et Physico-chimie des Materiaux.Unite de recherche associe au CNRST-URAC-14. Universite Ibn Tofail, Faculte des Sciences BP 133 Kenitra 14000 (Morocco); Oauzzani, H. EL; Sahraoui, B. [Institute of Sciences and Molecular Technologies of Angers, MOLTECH Anjou - UMR CNRS 6200, 2 bd Lavoisier 49045 ANGERS cedex2 (France)

    2011-07-01

    Nanocrystalline ZnO:Al thin films were deposited by reactive chemical pulverization spray pyrolysis technique on heated glass substrates at 450 deg. C to study their crystalline structure, composition, strain, stress, roughness characteristics and nonlinear optical susceptibility as a function of Al concentration (0, 2, 3, 5 at.%). The films were characterized by X-ray diffractometer (XRD), EDAX 9100 analyser, atomic force microscopy (AFM) and third harmonic generation (THG). The Al (3 at.%) doped ZnO thin films exhibited the lower strain/stress than undoped films. The nonlinear properties of the ZnO:Al thin films have been found to be influenced by the films strain/stress.

  19. The influence of interleukin-7 receptor α-chain haplotypes on outcome after allogeneic hematopoietic cell transplantation

    DEFF Research Database (Denmark)

    Broux, B; Shamim, Z; Wang, T;

    2014-01-01

    We investigated the influence of IL-7 receptor α-chain (IL-7Rα) gene haplotypes in donors on the outcome of haematopoietic cell transplantation (HCT). Unlike the association between single donor SNPs and HCT outcome found previously, only trends towards association were found here, due to 'diluti...

  20. Evaluation of the Influence of the Logistic Operations Reliability on the Total Costs of a Supply Chain

    Directory of Open Access Journals (Sweden)

    Lukinskiy Valery

    2016-12-01

    Full Text Available Nowadays in logistics integral processes between the material and related flows in supply chains are getting developed more and more. However, in spite of increasing volume of statistical data which reflect the integral processes, the influence evaluation issues of the logistic operations reliability indexes on the total logistics costs remain open and require the corresponding researches implementation.

  1. The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells

    DEFF Research Database (Denmark)

    Heckler, Ilona Maria; Kesters, Jurgen; Defour, Maxime

    2016-01-01

    The stability of polymer solar cells (PSCs) can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyl)dialkoxybenzene donor and benzo[c][1,2,5]thiadiazole (BT) or thiazolo[5,4-d...

  2. Influence of forced respiration on nonlinear dynamics in heart rate variability

    DEFF Research Database (Denmark)

    Kanters, J K; Højgaard, M V; Agner, E;

    1997-01-01

    of this study was to test whether the known nonlinear input from spontaneous respiration is a source for the nonlinearities in heart rate variability. Twelve healthy subjects were examined in supine position with 3-h electrocardiogram recordings during both spontaneous and forced respiration in accordance...... expressed as the nonlinear prediction error did not differ between spontaneous respiration, 32.3 +/- 3.4 ms, and forced respiration, 31.9 +/- 5.7. It is concluded that the origin of the nonlinear dynamics in heart rate variability is not a nonlinear input from the respiration into the cardiovascular...... oscillator. Additional studies are needed to elucidate the mechanisms behind the nonlinear dynamics in heart rate variability....

  3. Influence of alkyl chain length on the surface activity of antibacterial polymers derived from ROMP.

    Science.gov (United States)

    Altay, Esra; Yapaöz, Melda Altıkatoğlu; Keskin, Bahadır; Yucesan, Gundoğ; Eren, Tarik

    2015-03-01

    The purpose of this study is to understand the antibacterial properties of cationic polymers on solid surfaces by investigating the structure-activity relationships. The polymer synthesis was carried via ring opening metathesis polymerization (ROMP) of oxanorbornene derivatives. Modulation of molecular weights and alkyl chain lengths of the polymers were studied to investigate the antibacterial properties on the glass surface. Fluorescein (Na salt) staining contact angle measurements were used to characterize the positive charge density and hydrophobicity on the polymer coated surfaces. Positive charge density for the surface coated polymers with molecular weights of 3000 and 10,000 g mol(-1) is observed to be in the range of 2.3-28.5 nmol cm(-2). The ROMP based cationic pyridinium polymer with hexyl unit exhibited the highest bactericidal efficiency against Escherichia coli on solid surface killing 99% of the bacteria in 5 min. However, phenyl and octyl functionalized quaternary pyridinium groups exhibited lower biocidal properties on the solid surfaces compared to their solution phase biocidal properties. Studying the effect of threshold polymer concentrations on the antibacterial properties indicated that changing the concentrations of polymer coatings on the solid surface dramatically influences antibacterial efficiency.

  4. Investigating nonlinear dynamics from time series: The influence of symmetries and the choice of observables

    Science.gov (United States)

    Letellier, Christophe; Aguirre, Luis A.

    2002-09-01

    When a dynamical system is investigated from a time series, one of the most challenging problems is to obtain a model that reproduces the underlying dynamics. Many papers have been devoted to this problem but very few have considered the influence of symmetries in the original system and the choice of the observable. Indeed, it is well known that there are usually some variables that provide a better representation of the underlying dynamics and, consequently, a global model can be obtained with less difficulties starting from such variables. This is connected to the problem of observing the dynamical system from a single time series. The roots of the nonequivalence between the dynamical variables will be investigated in a more systematic way using previously defined observability indices. It turns out that there are two important ingredients which are the complexity of the coupling between the dynamical variables and the symmetry properties of the original system. As will be mentioned, symmetries and the choice of observables also has important consequences in other problems such as synchronization of nonlinear oscillators.

  5. Linear and weakly nonlinear aspects of free shear layer instability, roll-up, subharmonic interaction and wall influence

    Science.gov (United States)

    Cain, A. B.; Thompson, M. W.

    1986-01-01

    The growth of the momentum thickness and the modal disturbance energies are examined to study the nature and onset of nonlinearity in a temporally growing free shear layer. A shooting technique is used to find solutions to the linearized eigenvalue problem, and pseudospectral weakly nonlinear simulations of this flow are obtained for comparison. The roll-up of a fundamental disturbance follows linear theory predictions even with a 20 percent disturbance amplitude. A weak nonlinear interaction of the disturbance creates a finite-amplitude mean shear stress which dominates the growth of the layer momentum thickness, and the disturbance growth rate changes until the fundamental disturbance dominates. The fundamental then becomes an energy source for the harmonic, resulting in an increase in the growth rate of the subharmonic over the linear prediction even when the fundamental has no energy to give. Also considered are phase relations and the wall influence.

  6. Analysis of factors influencing fire damage to concrete using nonlinear resonance vibration method

    Energy Technology Data Exchange (ETDEWEB)

    Park, Gang Kyu; Park, Sun Jong; Kwak, Hyo Gyoung [Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology, KAIST, Daejeon (Korea, Republic of); Yim, Hong Jae [Dept. of Construction and Disaster Prevention Engineering, Kyungpook National University, Sangju (Korea, Republic of)

    2015-04-15

    In this study, the effects of different mix proportions and fire scenarios (exposure temperatures and post-fire-curing periods) on fire-damaged concrete were analyzed using a nonlinear resonance vibration method based on nonlinear acoustics. The hysteretic nonlinearity parameter was obtained, which can sensitively reflect the damage level of fire-damaged concrete. In addition, a splitting tensile strength test was performed on each fire-damaged specimen to evaluate the residual property. Using the results, a prediction model for estimating the residual strength of fire-damaged concrete was proposed on the basis of the correlation between the hysteretic nonlinearity parameter and the ratio of splitting tensile strength.

  7. Nonlinear calibration transfer based on hierarchical Bayesian models and Lagrange Multipliers: Error bounds of estimates via Monte Carlo - Markov Chain sampling.

    Science.gov (United States)

    Seichter, Felicia; Vogt, Josef; Radermacher, Peter; Mizaikoff, Boris

    2017-01-25

    The calibration of analytical systems is time-consuming and the effort for daily calibration routines should therefore be minimized, while maintaining the analytical accuracy and precision. The 'calibration transfer' approach proposes to combine calibration data already recorded with actual calibrations measurements. However, this strategy was developed for the multivariate, linear analysis of spectroscopic data, and thus, cannot be applied to sensors with a single response channel and/or a non-linear relationship between signal and desired analytical concentration. To fill this gap for a non-linear calibration equation, we assume that the coefficients for the equation, collected over several calibration runs, are normally distributed. Considering that coefficients of an actual calibration are a sample of this distribution, only a few standards are needed for a complete calibration data set. The resulting calibration transfer approach is demonstrated for a fluorescence oxygen sensor and implemented as a hierarchical Bayesian model, combined with a Lagrange Multipliers technique and Monte-Carlo Markov-Chain sampling. The latter provides realistic estimates for coefficients and prediction together with accurate error bounds by simulating known measurement errors and system fluctuations. Performance criteria for validation and optimal selection of a reduced set of calibration samples were developed and lead to a setup which maintains the analytical performance of a full calibration. Strategies for a rapid determination of problems occurring in a daily calibration routine, are proposed, thereby opening the possibility of correcting the problem just in time.

  8. Influence of the sterol aliphatic side chain on membrane properties: a molecular dynamics study.

    Science.gov (United States)

    Robalo, João R; Ramalho, J P Prates; Huster, Daniel; Loura, Luís M S

    2015-09-21

    Following a recent experimental investigation of the effect of the length of the alkyl side chain in a series of cholesterol analogues (Angew. Chem., Int. Ed., 2013, 52, 12848-12851), we report here an atomistic molecular dynamics characterization of the behaviour of methyl-branched side chain sterols (iso series) in POPC bilayers. The studied sterols included androstenol (i-C0-sterol) and cholesterol (i-C8-sterol), as well as four other derivatives (i-C5, i-C10, i-C12 and i-C14-sterol). For each sterol, both subtle local effects and more substantial differential alterations of membrane properties along the iso series were investigated. The location and orientation of the tetracyclic ring system is almost identical in all compounds. Among all the studied sterols, cholesterol is the sterol that presents the best matching with the hydrophobic length of POPC acyl chains, whereas longer-chained sterols interdigitate into the opposing membrane leaflet. In accordance with the experimental observations, a maximal ordering effect is observed for intermediate sterol chain length (i-C5, cholesterol, i-C10). Only for these sterols a preferential interaction with the saturated sn-1 chain of POPC (compared to the unsaturated sn-2 chain) was observed, but not for either shorter or longer-chained derivatives. This work highlights the importance of the sterol alkyl chain in the modulation of membrane properties and lateral organization in biological membranes.

  9. The influence of and the identification of nonlinearity in flexible structures

    Science.gov (United States)

    Zavodney, Lawrence D.

    1988-01-01

    Several models were built at NASA Langley and used to demonstrate the following nonlinear behavior: internal resonance in a free response, principal parametric resonance and subcritical instability in a cantilever beam-lumped mass structure, combination resonance in a parametrically excited flexible beam, autoparametric interaction in a two-degree-of-freedom system, instability of the linear solution, saturation of the excited mode, subharmonic bifurcation, and chaotic responses. A video tape documenting these phenomena was made. An attempt to identify a simple structure consisting of two light-weight beams and two lumped masses using the Eigensystem Realization Algorithm showed the inherent difficulty of using a linear based theory to identify a particular nonlinearity. Preliminary results show the technique requires novel interpretation, and hence may not be useful for structural modes that are coupled by a guadratic nonlinearity. A literature survey was also completed on recent work in parametrically excited nonlinear system. In summary, nonlinear systems may possess unique behaviors that require nonlinear identification techniques based on an understanding of how nonlinearity affects the dynamic response of structures. In this was, the unique behaviors of nonlinear systems may be properly identified. Moreover, more accutate quantifiable estimates can be made once the qualitative model has been determined.

  10. Influence of the higher-order nonlinearities in embodying the second-order holographic associative memories

    Science.gov (United States)

    Polyanskii, Peter V.; Felde, Christina V.; Konovchuk, Alexey V.; Oleksyuk, Maxim V.

    2015-11-01

    Recording nonlinearity is conventionally considered as the source of noise in holographic imaging. Important exclusion from this general statement is nonlinear holographic associative memory, where the quadratic recording nonlinearity causes true brightness rendering and the possibility for associative coupling and reconstructing optical signals of arbitrary complexity which are stored at the same carrier without interference. In this paper we discuss the role of nonlinearities of an amplitude response of a hologram of the orders higher than the quadratic one in implementing the second-ordered holographic associative memory. We show that higher-order nonlinearities are also involved in implementing this type of memory. This conclusion may be of importance for interpretation of biological/human memory also. The highlight of our study is the conclusion that reconstruction of the complex conjugate heteroassociative response is provided directly, viz. by the set of specified by us pseudogratings, rather than by the mechanism of sequential diffractions.

  11. Does ICT influence supply chain management and performance? A review of survey-based research

    NARCIS (Netherlands)

    Zhang, Xuan; van Donk, Dirk Pieter; van der Vaart, Taco

    2011-01-01

    Purpose - The purpose of this paper is to review and classify survey-based research connecting information and communication technology (ICT), supply chain management (SCM), and supply chain (SC) performance. The review evaluates present empirical results and aims at detecting explanations for simil

  12. Teaching Teachers about Supply Chain Management to Influence Students' Career and Education Choices

    Science.gov (United States)

    Gardner, Leslie L.

    2013-01-01

    Since teachers are influential in high school students' career choices, enabling high school teachers to introduce educational and career opportunities in supply chain management is a viable strategy for reaching high school students about these opportunities. This article presents a pilot program of supply chain workshops to educate high school…

  13. Influence of acyl chain lengths in mono- and diacyl-sn-glycerophosphatidylcholine on gelatinization and retrogradation of starch.

    Science.gov (United States)

    Siswoyo, T A; Morita, N

    2001-10-01

    The influence of starch with 1- or 2-monoacyl-sn-glycerophosphatidylcholine (GPC) having various chain lengths of fatty acids on gelatinization and retrogradation of starch was studied by the measurement of starch-GPC complex formation, complexing index, and differential scanning calorimetry. The addition of GPC to the starch sample slightly increased the blue value and lambda(max) with increasing chain length of GPC but decreased the phosphorus content and complexing index. The gelatinization onset and peak temperatures of starch complexes increased significantly with increasing chain length, but the enthalpies were statistically lower, except for the treatment with 1,2-distearoyl-sn-GPC when compared with that of the control. Among GPC (di and mono), 1- and 2-monomyristoyl-sn-GPC showed the highest complexing ability, whereas the complexing ability of the GPC decreased with the increasing chain length. According to the Avrami equation, the retrogradation rate (k, day(-1)) of starch was slower than that of the control, whereas the retrogradation rates of 1- and 2-monomyristoyl-sn-GPC were slowest among the GPCs. The positive linear relationship between k and the number of acyl groups of GPC suggests that a GPC with a shorter chain length could retard the retrogradation of starch during storage.

  14. Identifying and prioritizing factors that influence reapeted patronage of Etka chain-stores customers: a neural network approach

    Directory of Open Access Journals (Sweden)

    Behrouz Jahandideh

    2013-03-01

    Full Text Available Nowadays, chain stores are experiencing a severe competitive environment. In such an environment, a growing number of customers are equipped by high volumes of information and are more risk-taking. As they tend to switch their store based on the higher value that they might receive elsewhere, as customers switching behavior has become so commonplace and has become a challenge for retailers. Thus, factors that influence the willingness of customers to repurchase will play a critical role in the performance and success of chain stores. This paper aimed to identify and prioritize the determinative factors that cause customers repeat patronage in Etka chain stores. Factors were extracted based on a thorough literature review and then these factors were modified using pre-test and interview methods. In this study, questionnaires were used for data collection. Respectively, to identify and prioritize determinative factors, correlation analysis and artificial neural networks were used. Results showed that in order of importance, quality, price loyalty program, number of service counters, store staff, shelf labels, product selection, parking facilities, home delivery, store brand, and store atmosphere are factors that determine customers’ repeat patronage of Etka chain stores. Meanwhile, young, educated and wealthy customers showed lower store repeat patronage. Finally, the paper concludes with suggestions for increasing consumer repeat-patronage of Etka chain-stores and directions for future research.

  15. Influence of Monomer Types on the Designability of a Protein-Model Chain

    Institute of Scientific and Technical Information of China (English)

    梁好均; 王元元

    2002-01-01

    In a three-dimensional off-lattice model, the method of Shakhnovich and Gutin for minimizing the Hamiltonian is applied to the design of a protein-model chain. The effect of the number of hydrophobic and hydrophilic monomer types on the designability ora protein-model chain is investigated. The simulation results reveal that the number of hydrophobic monomer types is a much more important factor than that of the polar monomer types in the design of a protein-model chain.

  16. Systematic investigation of zinc aminoalkylphosphonates: influence of the alkyl chain lengths on the structure formation.

    Science.gov (United States)

    Schmidt, Corinna; Stock, Norbert

    2012-03-05

    With the high-throughput (HT) methodology, the bifunctional aminoalkylphosphonic acids (AAPA) linker molecules 2-aminoethyl- (AEPA), 3-aminopropyl- (APPA), and 4-aminobutylphosphonic acid (ABPA) [HO(3)P-C(n)H(2n)-NH(2) (n = 2-4)] and zinc nitrate were used to synthesize new metal phosphonates in order to investigate the influence of the alkyl chain length on the structure formation. The systematic investigations led to one known (ZnO(3)PC(2)H(4)NH(2)) and six new compounds: one using AEPA, three using APPA, and two using ABPA. The crystal structures of five compounds were determined by single crystal X-ray diffraction, using X-ray powder diffraction (XRPD) data as well as structure modeling employing force field methods. For compound 1, Zn(O(3)P-C(2)H(4)-NH(3))(NO(3))(H(2)O) (monoclinic, Cc, a = 4.799(1) Å, b = 29.342(6) Å, c = 5.631(1) Å, β = 91.59(3)°, V = 792.7(3) Å(3), Z = 4), and compound 2, Zn(2)(OH)(O(3)P-C(3)H(6)-NH(3))(NO(3)) (monoclinic, P2/c, a = 12.158(2) Å, b = 5.0315(10) Å, c = 13.952(3) Å, β = 113.23(3)°, V = 784.3(3) Å(3), Z = 2), the structures were determined using single crystal X-ray diffraction data. The crystal structures of [Zn(O(3)P-C(3)H(6)-NH(2))]·H(2)O (3) (monoclinic, P2(1)/c, a = 9.094(2) Å, b = 5.0118(7) Å, c = 16.067(4) Å, β = 90.38(2)°, V = 732.3(2) Å(3), Z = 4) and Zn(O(3)P-C(4)H(8)-NH(2)) (5) (monoclinic, P2(1)/c, a = 8.570(7) Å, b = 8.378(4) Å, c = 9.902(6) Å, β = 90.94(5)°, V = 710.9(8) Å(3), Z = 4) were determined using XRPD data. The structural model for compound 6, Zn(O(3)P-C(4)H(8)-NH(3))(NO(3))(H(2)O), was established using lattice parameters from XRPD data and following crystal structure modeling employing force field methods. The structures depend strongly on the alkyl chain length n. For n = 2 and 4 isoreticular compounds are observed, while n = 3 leads to new structures. Larger amounts of all compounds were obtained employing scale-up syntheses in a conventional oven as well as in a microwave

  17. The influence of nonlinear effects on the spectral efficiency of multiinput antenna systems

    Directory of Open Access Journals (Sweden)

    Vishniakova J. V.

    2015-08-01

    Full Text Available The analysis technique and design algorithm are proposed for multiinput antenna systems, based on the mathematical model developed. The technique and algorithm described allow the analysis of a wide class of multiinput systems, in particular, MIMO systems, reconfigurable multiantenna systems, multiinput systems with nonlinear components and devices. The paper presents numerical analysis results of the intermodulation interference effect on the spectral efficiency of a multiinput system with nonlinear elements in receiving antennas, obtained using the methods, algorithms and software products developed. It is shown that in the nonlinear system intermodulation interferences appear, and the spectral efficiency of the data transmission system decays near the operating frequency due to the appearance of additional combinational components in the frequency response of the system. This effect depends on the degree of nonlinearity, radiated power, the level of interfering signals. Based on the results obtained, it was concluded that the presence of nonlinear elements and devices must be taken into account in the design and analysis processes of multiinput multiantenna systems, considering the specific types of those nonlinearities.

  18. Systematic study of the structure of alternate pyromellitimide-PEO copolymers: Influence of the chain flexibility

    Energy Technology Data Exchange (ETDEWEB)

    Djurado, David [Laboratoire d' Electronique Moleculaire Organique and Hybride, DRFMC/SPrAM/CEA Grenoble, UMR CEA-CNRS-UJF 5819, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9 (France); Curtet, Jean Pierre; Bee, Marc [Laboratoire de Spectrometrie Physique (UMR CNRS-UJF-5588) Universite J. Fourier, Grenoble I, Domaine Universitaire, B.P. 87 38402 St Martin d' Heres Cedex (France); Michot, Christophe [Department of Chemistry, University of Montreal, C.P. 6128, Succursale Centre-Ville, Montreal, Quebec H3C JJ7 (Canada); Armand, Michel [Department of Chemistry, University of Montreal, C.P. 6128, Succursale Centre-Ville, Montreal, Quebec H3C JJ7 (Canada); Laboratoire de Reactivite et de Chimie des Solides, Universite de Picardie Jules Verne, UMR 6007 CNRS, 33 rue Saint-Leu, 80039 Amiens (France)

    2007-12-31

    The structure of a family of copolyimides in which are alternating stiff/redox pyromellitimide units and flexible/solvating polyethyleneoxide (PEO) strands were studied by using wide angle and small angle X-ray scattering techniques and is fully discussed. It is shown that the rich variety of structures exhibited by these compounds can be understood by considering the dramatic change of flexibility of the chain induced by the variation of the length of the PEO strand compared to that of the pyromellimide segment. In this respect, concerning the compounds which exhibit fully amorphous structures a better understanding of their structural behavior can be obtained in the framework of Flory's theory of semi-rigid polymers. In this approach, the degree of flexibility of the chain is mainly resulting from the relative amount of flexible units constituting the repetition unit of the polymer chain. The final structural mode adopted by each compound in the solid state is then directly a consequence of this intrinsic property of the chain. The introduction of a lithium salt in contact with the copolymer chains induces some structure changes which can also be explained by the modification of the degree of flexibility of the chain. It is found that the best performances in terms of electroactivity and mixed conduction are precisely obtained with the only compound which keeps full amorphicity in absence and in presence of the lithium salt. (author)

  19. ERROR ESTIMATE FOR INFLUENCE OF MODEL REDUCTION OF NONLINEAR DISSIPATIVE AUTONOMOUS DYNAMICAL SYSTEM ON LONG-TERM BEHAVIOURS

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jia-zhong; LIU Yan; CHEN Dang-min

    2005-01-01

    From viewpoint of nonlinear dynamics, the model reduction and its influence on the long-term behaviours of a class of nonlinear dissipative autonomous dynamical system with higher dimension are investigated theoretically under some assumptions. The system is analyzed in the state space with an introduction of a distance definition which can be used to describe the distance between the full system and the reduced system, and the solution of the full system is then projected onto the complete space spanned by the eigenvectors of the linear operator of the governing equations. As a result, the influence of mode series tnncation on the long-term behaviours and the error estimate are derived, showing that the error is dependent on the first products of frequencies and damping ratios in the subspace spanned by the eigenvectors with higher modal damping. Furthermore, the fundamental understanding for the topological change of the solution due to the application of different model reduction is interpreted in a mathematically precise way, using the qualitative theory of nonlinear dynamics.

  20. Bilinear forms and soliton solutions for a fourth-order variable-coefficient nonlinear Schrödinger equation in an inhomogeneous Heisenberg ferromagnetic spin chain or an alpha helical protein

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Jin-Wei; Gao, Yi-Tian, E-mail: gaoyt163@163.com; Wang, Qi-Min; Su, Chuan-Qi; Feng, Yu-Jie; Yu, Xin

    2016-01-15

    In this paper, a fourth-order variable-coefficient nonlinear Schrödinger equation is studied, which might describe a one-dimensional continuum anisotropic Heisenberg ferromagnetic spin chain with the octuple–dipole interaction or an alpha helical protein with higher-order excitations and interactions under continuum approximation. With the aid of auxiliary function, we derive the bilinear forms and corresponding constraints on the variable coefficients. Via the symbolic computation, we obtain the Lax pair, infinitely many conservation laws, one-, two- and three-soliton solutions. We discuss the influence of the variable coefficients on the solitons. With different choices of the variable coefficients, we obtain the parabolic, cubic, and periodic solitons, respectively. We analyse the head-on and overtaking interactions between/among the two and three solitons. Interactions between a bound state and a single soliton are displayed with different choices of variable coefficients. We also derive the quasi-periodic formulae for the three cases of the bound states.

  1. Influence of geometric and physical nonlinearities on the internal resonances of a finite continuous rod with a microstructure

    Science.gov (United States)

    Andrianov, Igor V.; Awrejcewicz, Jan; Danishevskyy, Vladyslav V.; Markert, Bernd

    2017-01-01

    In this work, nonlinear longitudinal vibrations of a finite composite rod are studied including geometric and physical nonlinearities. An original boundary value problem for a heterogeneous rod yielded by the macroscopic approximation obtained earlier by the higher-order asymptotic homogenization method is used. The effects of internal resonances and modes coupling are predicted, validated and analyzed. The defined novel continuous problem governed by PDEs is solved using space-discretization and the method of multiple time scales. We are aimed at understanding and analyzing how the presence of the microstructure influences the processes of mode interaction. It is shown that, depending on a scaling relation between the amplitude of the vibrations and the size of the unit cell, different scenarios of the modes coupling can be realized. Additionally to the asymptotic solution, numerical simulation of the modes coupling is performed by means of the Runge-Kutta fourth-order method. The obtained numerical and analytical results demonstrate good qualitative agreement.

  2. Dynamical soil-structure interactions: influence of soil behaviour nonlinearities; Interaction Dynamique Sol-Structure: Influence des Nonlinearites de Comportement du Sol

    Energy Technology Data Exchange (ETDEWEB)

    Gandomzadeh, Ali

    2011-02-08

    the soil and the response of the soil-structure system. Through these parametric studies we show that depending on the soil properties, frequency content of the soil response could change significantly due to the soil nonlinearity. The peaks of the transfer function between free field and outcropping responses shift to lower frequencies and amplification happens at this frequency range. Amplification reduction for the high frequencies and even de-amplification may happen for high level input motions. These changes influence the structural response. We show that depending on the combination of the fundamental frequency of the structure and the the natural frequency of the soil, the effect of soil-structure interaction could be significant or negligible. However, the effect of structure weight and rocking of the superstructure could change the results. Finally, the basin of Nice is used as an example of wave propagation on a heterogeneous nonlinear media and dynamic soil-structure interaction. The basin response is strongly dependent on the combination of soil nonlinearity, topographic effects and impedance contrast between soil layers. For the selected structures and soil profiles of this work, the performed numerical simulations show that the shift of the fundamental frequency is not a good index to discriminate linear from nonlinear soil behavior. (author)

  3. Influence of nonlinearities on the power output of the Self-Oscillating Fluidic Heat Engine (SOFHE)

    Science.gov (United States)

    Tessier-Poirier, A.; Monin, T.; Léveillé, E.; Formosa, F.; Monfray, S.; Fréchette, L. G.

    2016-11-01

    In this paper, it is shown that two non-linearities drive the oscillations amplitude and the potential power density of the Self-Oscillating Fluidic Heat Engine (SOFHE). This new type of engine converts thermal energy into mechanical energy by producing self-sustained oscillations of a liquid column from a continuous heat source to power wireless sensors from waste heat. The underlying theoretical modeling shows that the pressure and the temperature nonlinearities limit the final oscillations amplitude, hence its achievable power density.

  4. The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells

    Directory of Open Access Journals (Sweden)

    Ilona M. Heckler

    2016-03-01

    Full Text Available The stability of polymer solar cells (PSCs can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyldialkoxybenzene donor and benzo[c][1,2,5]thiadiazole (BT or thiazolo[5,4-d]thiazole (TzTz acceptor units, were selected toward effective device scalability by roll-coating. The influence of the partial exchange (5% or 10% of the solubilizing 2-hexyldecyloxy by alternative 2-phenylethoxy groups on efficiency and stability was investigated. With an increasing 2-phenylethoxy ratio, a decrease in solar cell efficiency was observed for the BT-based series, whereas the efficiencies for the devices based on the TzTz polymers remained approximately the same. The photochemical degradation rate for PSCs based on the TzTz polymers decreased with an increasing 2-phenylethoxy ratio. Lifetime studies under constant sun irradiance showed a diminishing initial degradation rate for the BT-based devices upon including the alternative side chains, whereas the (more stable TzTz-based devices degraded at a faster rate from the start of the experiment upon partly exchanging the side chains. No clear trends in the degradation behavior, linked to the copolymer structural changes, could be established at this point, evidencing the complex interplay of events determining PSCs’ lifetime.

  5. The Influence of Environmental Management Practices and Supply Chain Integration on Technological Innovation Performance—Evidence from China’s Manufacturing Industry

    Directory of Open Access Journals (Sweden)

    Jiehui Yang

    2015-11-01

    Full Text Available How to effectively implement environmental management practices and supply chain integration to enhance technological innovation performance has become crucial in both research and practice. Based on resource-based view (RBV theory, a theoretical model to determine the relationship between environmental management practices, supply chain integration, supply chain knowledge sharing, and technological innovation performance was proposed. Based on data collected from one hundred and twelve Chinese manufacturing enterprises, the empirical results show that environmental management practices have a significantly positive influence on technological innovation performance, and supply chain integration plays a moderating role on the relationship. In addition, the results indicate that supply chain integration is also a predictive variable of technological innovation performance and supply chain knowledge sharing. Our findings suggest that practitioners should couple environmental management practices with supply chain integration to improve technological innovation performance in addition to environmental performance, which has been substantiated in literature.

  6. Influence of structures of polymer backbones on cooperative photoreorientation behavior of p-cyanoazobenzene side chains

    DEFF Research Database (Denmark)

    Han, Mina; Kidowaki, Masatoshi; Ichimura, Kunihiro;

    2001-01-01

    Photoinduced orientational behavior of a polymethacrylate (CN6) and a polyester (p6a12) with p-cyanoazobenzene side chains was studied to reveal the structural effect of the liquid crystalline polymer backbones. Irradiation with linearly polarized W light resulted in the reorientation of the azob...

  7. Influence of alkane chain length on adsorption on an α-alumina surface by MD simulations

    Energy Technology Data Exchange (ETDEWEB)

    Turgut, C. [Department of Science and Analysis of Materials (SAM), CRP-Gabriel Lippmann, L-4422 Belvaux (Luxembourg); Institut Jean Lamour (IJL) CNRS UMR 7198, Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Pandiyan, S. [Department of Science and Analysis of Materials (SAM), CRP-Gabriel Lippmann, L-4422 Belvaux (Luxembourg); Mether, L. [Department of Physics, University of Helsinki, P.O. Box 43, FI-00014 (Finland); Belmahi, M. [Institut Jean Lamour (IJL) CNRS UMR 7198, Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Nordlund, K. [Department of Physics, University of Helsinki, P.O. Box 43, FI-00014 (Finland); Philipp, P., E-mail: philipp@lippmann.lu [Department of Science and Analysis of Materials (SAM), CRP-Gabriel Lippmann, L-4422 Belvaux (Luxembourg)

    2015-06-01

    Plasma surface techniques provide both an efficient and ecological tool for the functionalization of surfaces. Hence, a proper understanding of the plasma–surface interactions of precursors and radicals during the deposition process is of great importance. Especially during the initial deposition process, the deposition of molecules and fragments is difficult to investigate by experimental techniques and import insights can be obtained by molecular dynamics simulations. In this work, the reactive force field developed by the group of Kieffer at the University of Michigan was used to study the adsorption of single linear alkane chains on an α-alumina surface. The chain length was changed from 6 backbone carbon atoms to 16 carbon atoms, the deposition energy from 0.01 to 10 eV and the incidence angle from 0° to 60° with respect to the surface normal. Results show that the adsorption depends a lot on the ratio of deposition energy to alkane chain length and the incidence angle. More grazing incidence reduces the adsorption probability and a low ratio of energy to chain length increases it.

  8. Microbial adhesion to poly(ethylene oxide) brushes: Influence of polymer chain length and temperature

    NARCIS (Netherlands)

    Roosjen, A.; Mei, van der H.C.; Busscher, H.J.; Norde, W.

    2004-01-01

    Glass surfaces were modified by end-grafting poly(ethylene oxide) (PEO) chains having molecular weights of 526, 2000, or 9800 Da. Characterization using water contact angles, ellipsometry, and X-ray photoelectron spectroscopy confirmed the presence of the PEO brushes on the surface with estimated le

  9. Microbial adhesion to poly(ethylene oxide) brushes : Influence of polymer chain length and temperature

    NARCIS (Netherlands)

    Roosjen, A; van der Mei, HC; Busscher, HJ; Norde, W

    2004-01-01

    Glass surfaces were modified by end-grafting poly(ethylene oxide) (PEO) chains having molecular weights of 526,2000, or 9800 Da. Characterization using water contact angles, ellipsometry, and X-ray photoelectron spectroscopy confirmed the presence of the PEO brushes on the surface with estimated len

  10. The influence of the network topology on the agility of a supply chain

    CERN Document Server

    Hernández, Juan M

    2016-01-01

    The right performance of a supply chain depends on the pattern of relationships among firms. Although there is not a general consensus among researchers yet, many studies point that scale-free topologies, where few highly related firms are combined with many low-related firms, assure the highest efficiency of a supply chain. This paper studies the network topology that leads to the highest agility of the supply chain when sudden demand changes occur. To do this, an agent-based model of a supply chain with restricted relationship between agents is built. The model includes three tiers, where the flow of material is distributed from the bottom supplier to the final customer passing necessarily through firms in every tier. Agility is measured in the model simulations through the order fulfillment rate. Unlike to previous theoretical and lab results, the simulation of the model shows that the highest levels of agility are not obtained with a scale-free topology. Instead, homogeneous distribution of links, such as...

  11. Data Science in Supply Chain Management: Data-Related Influences on Demand Planning

    Science.gov (United States)

    Jin, Yao

    2013-01-01

    Data-driven decisions have become an important aspect of supply chain management. Demand planners are tasked with analyzing volumes of data that are being collected at a torrential pace from myriad sources in order to translate them into actionable business intelligence. In particular, demand volatilities and planning are vital for effective and…

  12. Modification with alkyl chains and the influence on thermal and mechanical properties of aromatic hyperbranched polyesters

    NARCIS (Netherlands)

    Schmaljohann, Dirk; Häußler, Liane; Pötschke, Petra; Voit, Brigitte I.; Loontjens, Ton J.A.

    2000-01-01

    All-aromatic hyperbranched polyesters with hydroxy endgroups were functionalized with aliphatic n-alkyl carboxylic acids. The length of the n-alkyl chain as well as the degree of modification were varied and the resulting, partially amphiphilic polymers were characterized by differential scanning ca

  13. Influence of boron concentration on nonlinear absorption and ultrafast dynamics in GaSe crystals

    Science.gov (United States)

    Karatay, Ahmet; Yuksek, Mustafa; Ertap, Hüseyin; Mak, Ali Kemal; Karabulut, Mevlüt; Elmali, Ayhan

    2016-10-01

    The nonlinear absorption properties and ultrafast dynamics of pure and boron doped GaSe crystals have been studied by open aperture Z-scan and ultrafast pump probe spectroscopy techniques. All of the studied crystals showed nonlinear absorption under 100 fs pulse duration and 1200 nm wavelength excitations. Nonlinear absorption coefficients increase with increasing the doping ratio of boron atoms in crystals. These findings indicate that free carrier density increase with boron doping and this behavior leads to excited state absorption. Second harmonic generation signals of crystals were detected with the help of fiber optic spectrometer. The blue shift in the energy of the second harmonic generation signals was observed in boron doped crystals. Ultrafast pump probe experiments indicate that the excited state absorption signal with long lifetime observed for undoped GaSe crystal switches to bleach signal for boron doped GaSe crystals at 625 nm probe wavelength. The effects of increasing doping ratio were observed on ultrafast dynamics as a switching time changes. Our experimental results indicate that it is possible to control nonlinear absorption properties, frequency conversion and ultrafast dynamics of GaSe crystal by changing boron doping ratio.

  14. Influence of Architecture, Concentration, and Thermal History on the Poling of Nonlinear Optical Chromophores in Block Copolymer Domains

    Energy Technology Data Exchange (ETDEWEB)

    Leolukman, Melvina; Paoprasert, Peerasak; Wang, Yao; Makhija, Varun; McGee, David J.; Gopalan, Padma (UW)

    2008-10-02

    Factors affecting the electric-field-induced poling of nonlinear optical chromophores in block copolymer domains were investigated by encapsulating the chromophores in a linear-diblock copolymer [poly(styrene-b-4-vinylpyridine)] and linear-dendritic (poly(methyl methacrylate)-dendron) block copolymer via hydrogen bonding. Temperature-dependent Fourier transform infrared spectroscopy and morphology evaluation by X-ray scattering and transmission electron microscopy were used with in situ second harmonic generation to correlate domain architectures, processing conditions such as thermal history, and chromophore concentrations with poling efficiency. Poling of chromophores encapsulated in the minority domain (spheres or cylinders) of a linear-diblock copolymer was inhibited by the increasing chromophore concentration within the domain and the chemical nature of the majority domain. Chromophore encapsulation in the majority domain produced the most favorable conditions for poling as measured by in situ second harmonic generation. Thermal annealing of the linear-diblock copolymer/chromophore composites resulted in chromophore aggregation with a corresponding decrease in nonlinear optical activity. The linear-dendron/chromophore system presented the most effective architecture for spatially dispersing chromophores. These findings suggest that while well-ordered phase-separated systems such as block copolymers enhance chromophore isolation over homopolymer systems, a more effective approach is to explore polymer chains end functionalized with chromophores.

  15. Sustainable supply chain management : The influence of local stakeholder expectations in China's agri-food industry

    OpenAIRE

    Kao, Pao T.; Redekop, William; Mark-Herbert, Cecilia

    2012-01-01

    Multinational food processing corporations are facing rapid growth in emerging markets like China and a concurrent need for sustainable supply chain management (SSCM). These firms attempt to address supply risk and threat to the triple bottom line through managing suppliers and inputs, and at the same time need to overcome the uncertainty raised by the unfamiliar host environment. An exploratory qualitative case study of two multinational food processing corporations in China finds their SSCM...

  16. Productivity, disturbance and ecosystem size have no influence on food chain length in seasonally connected rivers.

    Directory of Open Access Journals (Sweden)

    Danielle M Warfe

    Full Text Available The food web is one of the oldest and most central organising concepts in ecology and for decades, food chain length has been hypothesised to be controlled by productivity, disturbance, and/or ecosystem size; each of which may be mediated by the functional trophic role of the top predator. We characterised aquatic food webs using carbon and nitrogen stable isotopes from 66 river and floodplain sites across the wet-dry tropics of northern Australia to determine the relative importance of productivity (indicated by nutrient concentrations, disturbance (indicated by hydrological isolation and ecosystem size, and how they may be affected by food web architecture. We show that variation in food chain length was unrelated to these classic environmental determinants, and unrelated to the trophic role of the top predator. This finding is a striking exception to the literature and is the first published example of food chain length being unaffected by any of these determinants. We suggest the distinctive seasonal hydrology of northern Australia allows the movement of fish predators, linking isolated food webs and potentially creating a regional food web that overrides local effects of productivity, disturbance and ecosystem size. This finding supports ecological theory suggesting that mobile consumers promote more stable food webs. It also illustrates how food webs, and energy transfer, may function in the absence of the human modifications to landscape hydrological connectivity that are ubiquitous in more populated regions.

  17. Influence of water solubility, side chain degradability and side chain configuration on the degradation of phthalic acid esters under methanogenic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Alnervik, M.

    1996-12-31

    Water solubility and degradability of side chains estrifying phthalic acid are factors possible to influence the degradation of phthalic acid esters (PAEs). To investigate the importance of these factors degradation of butyl 2-ethylhexyl phthalate (BEHP), bis(2-ethylhexyl) phthalate (DEHP), dibutyl phthalate (DBP), dihexyl phthalate (DHP), dioctyl phthalate (DOP) and didecyl phthalate (DDP) were examined under methanogenic conditions as well as was the degradability of the alcohols estrifying these PAEs. We also investigated if the degradation of resistant PAEs could be stimulated by the addition of a degradable PAE. Synthesis of degradation intermediates and two methods for PAE analyses are presented. The investigation showed that all alcohols were degraded to methane and carbon dioxide and that the degradation of PAE occurred in incubations amended with BBP, BEHP, DHP and DBP, whilst DEHP, DOP and DDP were unaffected throughout the experimental period. BBP added to incubations with DEHP, could not stimulate DEHP degradation. In conclusion, the degradability of alcohols estrifying phthalic acid in this study does not affect the anaerobic degradability of PAEs. Water solubility of a PAE can not be rejected as a factor limiting phthalate degradation under methanogenic conditions. Anaerobic degradation of persistent PAEs can not be stimulated by mixing it with a degradable phthalate. 23 refs, 11 figs, 2 tabs

  18. Influence of Temperature and Pressure on Dispersion Properties of Nonlinear Single Mode Optical Fibers

    Directory of Open Access Journals (Sweden)

    Mostafa H. Ali, Ahmed E. Elsamahy, Maher A. Farhoud and Taymour A. Hamdalla

    2012-10-01

    Full Text Available Near field distribution, propagation constant and dispersion characteristics of nonlinear single-mode optical fibers have been investigated. Shooting-method technique is used and implemented into a computer code for both profiles of step-index and graded-index fibers. An error function is defined to estimate the discrepancy between the expected electric-field radial derivative at the core-cladding interface and that obtained by numerically integrating the wave equation through the use of Runge-Kutta method. All of the above calculations done under the ocean depth in which the depth will affect the refractive index that have a direct effect on all the optical fiber parameters.KeyWords: Nonlinear refractive index, Normalized propagation constant, Mode delay factor, Material dispersion, Waveguide dispersion.

  19. The Influence of the Balance of Dispersion and Nonlinearity on the Transmission Quality in Fiber

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    This article analyzes the effect of the balance of dispersion and nonlinearity on the quality of a transmission system with super Gauss pulse input by altering the input power and adding a section of dispersion compensation fiber (DCF). The same mechanisms are applied to a 2-channel wave divide multiplex system(WDM) as well. DCF is proved to be a good solution in both situations.

  20. Influence of combined fundamental potentials in a nonlinear vibration energy harvester

    Science.gov (United States)

    Podder, Pranay; Mallick, Dhiman; Amann, Andreas; Roy, Saibal

    2016-11-01

    Ambient mechanical vibrations have emerged as a viable energy source for low-power wireless sensor nodes aiming the upcoming era of the ‘Internet of Things’. Recently, purposefully induced dynamical nonlinearities have been exploited to widen the frequency spectrum of vibration energy harvesters. Here we investigate some critical inconsistencies between the theoretical formulation and applications of the bistable Duffing nonlinearity in vibration energy harvesting. A novel nonlinear vibration energy harvesting device with the capability to switch amidst individually tunable bistable-quadratic, monostable-quartic and bistable-quartic potentials has been designed and characterized. Our study highlights the fundamentally different large deflection behaviors of the theoretical bistable-quartic Duffing oscillator and the experimentally adapted bistable-quadratic systems, and underlines their implications in the respective spectral responses. The results suggest enhanced performance in the bistable-quartic potential in comparison to others, primarily due to lower potential barrier and higher restoring forces facilitating large amplitude inter-well motion at relatively lower accelerations.

  1. Existence of global weak solutions to compressible isentropic finitely extensible nonlinear bead-spring chain models for dilute polymers: The two-dimensional case

    Science.gov (United States)

    Barrett, John W.; Süli, Endre

    2016-07-01

    We prove the existence of global-in-time weak solutions to a general class of models that arise from the kinetic theory of dilute solutions of nonhomogeneous polymeric liquids, where the polymer molecules are idealized as bead-spring chains with finitely extensible nonlinear elastic (FENE) type spring potentials. The class of models under consideration involves the unsteady, compressible, isentropic, isothermal Navier-Stokes system in a bounded domain Ω in Rd, d = 2, for the density ρ, the velocity u ˜ and the pressure p of the fluid, with an equation of state of the form p (ρ) =cpργ, where cp is a positive constant and γ > 1. The right-hand side of the Navier-Stokes momentum equation includes an elastic extra-stress tensor, which is the classical Kramers expression. The elastic extra-stress tensor stems from the random movement of the polymer chains and is defined through the associated probability density function that satisfies a Fokker-Planck-type parabolic equation, a crucial feature of which is the presence of a centre-of-mass diffusion term. This extends the result in our paper J.W. Barrett and E. Süli (2016) [9], which established the existence of global-in-time weak solutions to the system for d ∈ { 2 , 3 } and γ >3/2, but the elastic extra-stress tensor required there the addition of a quadratic interaction term to the classical Kramers expression to complete the compactness argument on which the proof was based. We show here that in the case of d = 2 and γ > 1 the existence of global-in-time weak solutions can be proved in the absence of the quadratic interaction term. Our results require no structural assumptions on the drag term in the Fokker-Planck equation; in particular, the drag term need not be corotational. With a nonnegative initial density ρ0 ∈L∞ (Ω) for the continuity equation; a square-integrable initial velocity datum u˜0 for the Navier-Stokes momentum equation; and a nonnegative initial probability density function ψ0

  2. An empirical investigation on factors influencing on customer loyalty: A case study of Shahrvand food chain in Tehran

    Directory of Open Access Journals (Sweden)

    Seyed Valiollah Tabatabaee Hanzaee

    2013-06-01

    Full Text Available In today's competitive business environment, consumers are exposed to make their choice from different alternatives. Customer loyalty has never been an easy task and many business owners may lose their customer as soon as new products appear on the market. This paper presents a study to find important factors influencing on sales force using factor analysis. The proposed study designed a questionnaire and distributed among 180 customers of a well-known food chain named Shahrvand in different regions in city of Tehran, Iran and managed to collect 156 filled ones. The questionnaire consists of 68 questions Cronbach alpha was calculated as 0.847, which is well above the minimum acceptable limit and validates the results. The results of our survey indicate that five major factors including multi-sensory brand experience, brand engagement, pleasing brand, brand communications and brand effectiveness influence brand loyalty, significantly.

  3. Influence of incipient chain dimension of EVA flow improver on the rheological behaviour of crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Qian, J.W.; Qi, G.R.; Han, D.L.; Yang, S.L. [Zhejiang University, Hangzhou (China). Dept. of Polymer Science and Engineering

    1996-01-01

    The rheological behaviour of Daqing crude oil with different incipient chain dimensions of the same ethylene-vinyl acetate copolymer, prepared with different solvents, solution concentrations and temperatures was studied. It was shown that the EVA flow improver with a compact incipient shape before addition to the oil is preferable for reduction of apparent viscosity, pour point and wax crystallization temperature of crude oil. The compact dimension effect is probably due to strongly selective action in the flow of crude oil. 10 refs., 4 figs., 1 tab.

  4. Z-Selective olefin metathesis on peptides: investigation of side-chain influence, preorganization, and guidelines in substrate selection.

    Science.gov (United States)

    Mangold, Shane L; O'Leary, Daniel J; Grubbs, Robert H

    2014-09-01

    Olefin metathesis has emerged as a promising strategy for modulating the stability and activity of biologically relevant compounds; however, the ability to control olefin geometry in the product remains a challenge. Recent advances in the design of cyclometalated ruthenium catalysts has led to new strategies for achieving such control with high fidelity and Z selectivity, but the scope and limitations of these catalysts on substrates bearing multiple functionalities, including peptides, remained unexplored. Herein, we report an assessment of various factors that contribute to both productive and nonproductive Z-selective metathesis on peptides. The influence of sterics, side-chain identity, and preorganization through peptide secondary structure are explored by homodimerization, cross metathesis, and ring-closing metathesis. Our results indicate that the amino acid side chain and identity of the olefin profoundly influence the activity of cyclometalated ruthenium catalysts in Z-selective metathesis. The criteria set forth for achieving high conversion and Z selectivity are highlighted by cross metathesis and ring-closing metathesis on diverse peptide substrates. The principles outlined in this report are important not only for expanding the scope of Z-selective olefin metathesis to peptides but also for applying stereoselective olefin metathesis in general synthetic endeavors.

  5. Z-Selective Olefin Metathesis on Peptides: Investigation of Side-Chain Influence, Preorganization, and Guidelines in Substrate Selection

    Science.gov (United States)

    2015-01-01

    Olefin metathesis has emerged as a promising strategy for modulating the stability and activity of biologically relevant compounds; however, the ability to control olefin geometry in the product remains a challenge. Recent advances in the design of cyclometalated ruthenium catalysts has led to new strategies for achieving such control with high fidelity and Z selectivity, but the scope and limitations of these catalysts on substrates bearing multiple functionalities, including peptides, remained unexplored. Herein, we report an assessment of various factors that contribute to both productive and nonproductive Z-selective metathesis on peptides. The influence of sterics, side-chain identity, and preorganization through peptide secondary structure are explored by homodimerization, cross metathesis, and ring-closing metathesis. Our results indicate that the amino acid side chain and identity of the olefin profoundly influence the activity of cyclometalated ruthenium catalysts in Z-selective metathesis. The criteria set forth for achieving high conversion and Z selectivity are highlighted by cross metathesis and ring-closing metathesis on diverse peptide substrates. The principles outlined in this report are important not only for expanding the scope of Z-selective olefin metathesis to peptides but also for applying stereoselective olefin metathesis in general synthetic endeavors. PMID:25102124

  6. Sustainable Supply Chain Management: The Influence of Disposal Scenarios on the Environmental Impact of a 2400 L Waste Container

    Directory of Open Access Journals (Sweden)

    José Eduardo Galve

    2016-06-01

    Full Text Available This paper analyzes the influence of the supply chain management on the environmental impact of a 2400 L waste disposal container used in most cities of Spain. The studied functional unit, a waste disposal container, made up mostly of plastic materials and a metallic structure, and manufactured in Madrid (Spain, is distributed to several cities at an average distance of 392 km. A life cycle assessment of four different scenarios (SC has been calculated with the software EcoTool v4.0 (version 4.0; i+: Zaragoza, Spain, 2015 and using Ecoinvent v3.0 database (version 3.0; Swiss Centre for Life Cycle Inventories: St. Gallen, Switzerland, 2013. The environmental impact has been characterized with two different methodologies, recipe and carbon footprint. In order to reduce the environmental impact, several end of life scenarios have been performed, analyzing the influence of the supply chain on a closed-looped system that increases recycling. Closed loop management of the waste and reuse of parts allows companies to stop selling products and start selling the service that their products give to the consumers.

  7. Influence of dispersants on trophic transfer of petroleum hydrocarbons in a marine food chain

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, M.; Tjeerdema, R. [Univ. of California, Santa Cruz, CA (United States). Dept. of Chemistry and Biochemistry; Sowby, M. [California Dept. of Fish and Game, Sacramento, CA (United States)

    1995-12-31

    When crude oil is accidentally released into the ocean, it threatens many levels of marine life. Intervention, in the form of chemical dispersing agents, alters the normal behavior of petroleum hydrocarbons (PH) by increasing their functional water solubility and the extent of their exposure to sub-surface organisms. Dispersing agents may modify bioavailability as a result of altered interactions between dispersed PH droplets and organismal cell membranes.The objective of this research was to determine the impact of dispersing agents on PH bioavailability and trophic transfer in primary levels of a marine food chain. Uptake, bioaccumulation, depuration, and metabolic transformation of a model PH, {sup 14}C-naphthalene, were measured and compared for Prudhoe Bay Crude Oil (PBCO) dispersed with Corexit 9527 and undispersed preparations of the water-accommodated fractions (WAF) of PBCO at two salinities and temperatures. The model food chain consisted of Isochrysis galbana and Brachionus plicatilis. Direct aqueous exposure was compared with combined aqueous and dietary exposure. Fractionation and identification of metabolites was done by HPLC co-chromatography with analytical standards, and quantitation was done by liquid scintillation counting. GC-FID characterization of WAF and dispersed oil (DO) preparations shows higher concentrations of petroleum hydrocarbons and a greater number of individual constituents in the dispersed oil preparations.

  8. Using high-frequency vibrations and non-linear inclusions to create metamaterials with adjustable effective properties

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel

    2009-01-01

    We investigate how high-frequency (HF) excitation combined with strongly non-linear elasticity may influence the effective properties for low-frequency wave propagation. The HF effects are demonstrated for linear spring-mass chains with embedded non-linear parts. The investigated mechanical systems...

  9. A pilot, short-term dietary manipulation of branched chain amino acids has modest influence on fasting levels of branched chain amino acids

    Directory of Open Access Journals (Sweden)

    Nicole Landa Cavallaro

    2016-01-01

    Full Text Available Background: Elevated fasting levels of branched chain amino acids (BCAAs: valine, isoleucine, leucine in venous blood are associated with a variety of metabolic impairments, including increased risk of type 2 diabetes (T2D. Fasting BCAA levels are influenced by non-dietary factors. However, it is unknown whether fasting BCAAs can be altered through manipulation of dietary intake alone. Objective: To test whether a specific dietary intervention, using differences in BCAA intake, alters fasting BCAA levels independent of other factors. Design: Five healthy male volunteers underwent 4 days of a low and 4 days of a high BCAA content dietary intervention (ClinicalTrials.gov [NCT02110602]. All food and supplements were provided. Fasting BCAAs were measured from venous blood samples by mass spectrometry at baseline and after each intervention. Results: Diets were isocaloric; contained equal percentages of calories from carbohydrate, fats, and protein; and differed from each other in BCAA content (1.5±0.1 vs. 14.0±0.6 g for valine; 4.5±0.9 g vs. 13.8±0.5 g for isoleucine; 2.1±0.2 g vs. 27.1±1.0 g for leucine; p<0.0001 for all. Fasting valine was significantly lower (p=0.02 and fasting isoleucine and leucine were numerically lower following the low BCAA content vs. the high BCAA content diet levels. The inter-individual response to the dietary interventions was variable and not explained by adherence. Conclusion: Short-term dietary manipulation of BCAA intake led to modest changes in fasting levels of BCAAs. The approach from our pilot study can be expanded to test the metabolic implications of dietary BCAA manipulation.

  10. Influence of unbalance levels on nonlinear dynamics of a rotor-backup rolling bearing system

    Science.gov (United States)

    Fonseca, Cesar A.; Santos, Ilmar F.; Weber, Hans I.

    2017-04-01

    Rotor drops in magnetic bearing and unbalance in rotors have been objective of study for many years. The combination of these two well-known phenomena led to an interesting chaotic response, when the rotor touches the inner race of the back-up bearing. The present work explores the nonlinear rotor backup bearing dynamics both theoretically and experimentally using a fully instrumented test rig, where the position of shaft, its angular velocity and the contact forces between the shaft and the backup bearing are sampled at 25 kHz. The test rig is built by a removable passive magnetic bearing, which allows for simulation of magnetic bearing failure (loss of carrying capacity and rotor fall). The rotor is studied numerically as well as experimentally. A theoretical approach is given beforehand and supplies the basis of the study. Finally the presented results are commented on the point of view of nonlinear dynamics applied to the practical use. The theoretical and numerical analyses are shown through orbit plots, phase plans, Poincaré maps, force response in time and double sided spectrum. The latter is important to characterize the condition at different levels of unbalance between forward and backward whirl. Our preliminary results indicate that for smaller amount of unbalance the rotor swings at the bottom of the bearing, the more the unbalance increases, other dynamical behavior occur and some can be extremely harmful, since the rotor can be lifted from the contact state and return, starting to impact innumerable times without reaching a steady state.

  11. Effective market influence. An effect chain analysis of NUTEK`s high-frequency lighting campaign

    Energy Technology Data Exchange (ETDEWEB)

    Goeransson, C.; Faugert, S. [SIPU Utvaerdering, Stockholm (Sweden); Baeckman, B.; Arndt, J. [B2B AB, Stockholm (Sweden)

    1994-12-31

    This report is an evaluation of NUTEK`s `Better lighting and more energy-efficient high-frequency fluorescent tube luminaries` campaign. It is concerned with the ways in which NUTEK can influence the spread and use of high-frequency (HF) lighting devices. It also shows that NUTEK actually has affected (contributed to) development in the area. The report analyses and quantifies (as far as possible) how much NUTEK has influenced the various parties concerned in the sector, their attitudes and their actions. 14 figs, 5 tabs

  12. Dynamics of shock induced ignition in Fickett's model with chain-branching kinetics: influence of $\\chi$

    CERN Document Server

    Tang, Justin

    2012-01-01

    The problem of shock induced ignition by a piston is addressed in the framework of Fickett's model for reactive compressible flows, i.e., the reactive form of Burgers' equation. An induction-reaction two-step chain-branching model is used to study the coupling between the energy release and the compressible hydrodynamics occurring during the shock ignition transient leading to a detonation. Owing to the model's simplicity, the ignition and acceleration mechanism is explained using the two families of characteristics admitted by the model. The energy release along the particle paths provides the amplification of forward-travelling pressure waves. These waves pre-compress the medium in the induction layer ahead of the reaction zone, therefore changing the induction delays of successive particles. The variation of the induction delay provides the modulation of the amplification of the forward travelling pressure waves by controlling the residence time of the pressure waves in the reaction zone. A closed form ana...

  13. Influence of dispersants on petroleum bioavailability in a marine food chain

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, M.; Tjeerdema, R. [Univ. of California, Santa Cruz, CA (United States). Dept. of Chemistry and Biochemistry; Sowby, M. [California Dept. of Fish and Game, Sacramento, CA (United States)

    1995-12-31

    When crude oil is accidentally released into the ocean it threatens many levels of marine life. Intervention, in the form of chemical dispersing agents, may alter the normal behavior of petroleum hydrocarbons (PH) by increasing their functional water solubility and the extent of their exposure to sub-surface marine organisms. Further, the dispersing agent may modify bioavailability as a result of altered interactions between dispersed PH droplets and organismal cell membranes, To date, little information exists on the sub-lethal effects of dispersants and factors modifying their role in the bioavailability and disposition of PH in marine food chains. The objective of the current research was to determine the impact of dispersing agents on PH bioavailability to primary levels of a marine food chain. Uptake, bioaccumulation, deputation, and metabolic transformation of a model PH, {sup 14}C-naphthalene, were measured and compared for dispersed Prudhoe Bay Crude Oil (PBCO) vs. undispersed preparations of the water-accommodated fractions (WAF) of PBCO at two salinities (22 and 34 ppt) employing Isochrysis galbana, a primary producer, and Brachionus plicatilis, a primary consumer. Fractionation and identification of metabolites was done by HPLC co-chromatography with analytical standards, and quantitation was done by liquid scintillation counting. GC-FID characterization of WAF and dispersed oil preparations shows higher concentrations of petroleum hydrocarbons and a greater number of individual constituents in the dispersed oil preparations. However, short term (eight hour) and long term (two week) static exposure studies indicate the uptake of{sup 14}C-naphthalene from WAF preparations is inhibited by up to 50% from dispersed oil preparations. Results of comparative static and flow-through chamber exposure studies will be presented.

  14. Interaction between two solid surfaces across PDMS : influence of chain length and end group

    NARCIS (Netherlands)

    Sun, G.X.; Stark, R.; Kappl, M.; Leermakers, F.A.M.; Butt, H.J.

    2005-01-01

    Forces between solid surfaces across polymer melts are poorly understood despite their importance for adhesion and composite materials. Using an atomic force microscope (AFM) this force was measured for poly(dimethyl siloxane) (PDMS) on silicon oxide. The influence of molecular weight (4.0-40 kDa) w

  15. The influence of the chain and network information and communication structure on sustainable business development

    NARCIS (Netherlands)

    Bremmers, H.J.; Haverkamp, D.J.; Omta, S.W.F.

    2005-01-01

    This article links the public-private information and communication structure (IC-structure) and Ajzen¿s model of planned behaviour to explain the development of environmental management systems (EMSs). The structure of the IC-system, especially the public-private information exchange, can influence

  16. Analysis of key properties for optical power limiting and the influence of nonlinear scattering

    Science.gov (United States)

    Koerber, M.; Azarian, A.; Schwarz, B.; Eberle, B.

    2014-10-01

    In this paper, we propose ways to study the optical limiting behavior of dissolved nanoparticles. We want to present two different approaches. First, we identify the key properties responsible for the critical fluence threshold using a principal component analysis. For metallic nanoparticles, we found that the real part of the complex dielectric function must have a negative value as low as possible, while the imaginary part must be close to zero. Additionally, the solvent should have a low refractive index as well as a low absorption. Furthermore, nonlinear scattering seems to be an important limiting mechanism for nanoparticle limiters. Here, we present a thermal finite element model to predict the temporal evolution of the temperature profile in the nanoparticles and their vicinity. The temperature profile leads to vapor bubbles around the nanoparticles and Mie theory is used to calculate the induced scattering. We demonstrate the functionality of the model by simulating an Au-nanoparticle in an ethanol solution.

  17. Nonlinear longitudinal current in degenerate plasma, arising under the influence of the transversal electromagnetic field

    CERN Document Server

    Latyshev, A V

    2015-01-01

    Kinetic Vlasov-Boltzmann equation for degenerate collisional plasmas with integral of collisions of relaxation type BGK (Bhatnagar, Gross and Krook) is used. Square-law expansion on size of intensity of electric field for kinetic equation, Lorentz's force and integral of collisions is considered. It is shown, that nonlinearity leads to generation of the longitudinal electric current directed along a wave vector. Longitudinal current is perpendicular to the known transversal classical current received at the linear analysis. The case of small values of wave number is considered. When frequency of collisions tends to the zero, all received results for collisional pass plasmas in corresponding results for collisionless plasmas. Graphic research of the real and imaginary part current density is carried out.

  18. On the influence of Gribov ambiguities in a class of nonlinear covariant gauges

    CERN Document Server

    Serreau, Julien; Tresmontant, Andréas

    2015-01-01

    We consider Yang-Mills theories in a recently proposed family of nonlinear covariant gauges that consistently deals with the issue of Gribov ambiguities. Such gauges provide a generalization of the Curci-Ferrari-Delbourgo-Jarvis gauges which can be formulated as an extremization procedure and might be implemented in numerical calculations. This would allow for nonperturbative studies of Yang-Mills correlators in a broad class of covariant gauges continuously connected to the well studied Landau gauge. We compute the ghost and gluon propagators in the continuum formulation at one-loop order in perturbation theory and we study their momentum dependence down to the deep infrared regime, with and without renormalization group improvement. In particular, we show that the theory admits infrared safe renormalization group trajectories with no Landau pole. Both the gluon and the ghost behave as massive fields at low energy, and the gluon propagator is transverse even away from the Landau gauge limit. We compare our r...

  19. The influence of sodium-polyacrilic macromolecular chain length to the powder detergents secondary washing performances

    OpenAIRE

    Milojević Vladimir S.; Nikolić Ljubiša B.; Nikolić Goran; Stamenković Jakov

    2013-01-01

    In order to investigate the influence of sodium-polyacrylate polymer as a co-builder in addition to the carbonate/zeolite builders in detergent builder system, secondary washing performances of powder laundry detergent containing equal percentage of sodium polyacrylate with the different weight average molar mass, Mw, have been examined. The value of the degree of whiteness, elongation at break, and total residue content are the most important secondary washing performances that signifi...

  20. The influence of maternal early to mid-gestation nutrient restriction on long chain polyunsaturated fatty acids in fetal sheep.

    Science.gov (United States)

    Zhou, Yunhua; Nijland, Mark; Miller, Myrna; Ford, Stephen; Nathanielsz, Peter W; Brenna, J Thomas

    2008-06-01

    The early to mid-gestational period (days 28-78) in sheep is the period of most rapid placental development. Maternal nutrient restriction (MNR) in this phase has negative consequences on fetal growth and development, predisposing the fetus to disease in adult life. The influence of MNR on fetal tissue fatty acids has not been reported. Ewes were fed to 50% (MNR) or 100% (control fed) of total digestible nutrients from days 28 to 78 of gestation. At 78 days, fetuses were sacrificed and the fatty acids in fetal liver, lung and muscle as well as maternal and fetal plasma were analyzed. Most fatty acids were not influenced by MNR. The n-3 long chain PUFA eicosapentaenoic acid (20:5n-3, EPA) concentration (microg/mg) was low and more than doubled in the MNR sheep. Similarly, docosapentaenoic acid (22:5n-3, DPA) increased by 60, 19, and 38% in liver, lung, and muscle, respectively. Neither docosahexaenoic acid (22:6n-3, DHA) nor any of n-6 PUFA changed. Arachidonic acid (20:4n-6; ARA) increased in MNR maternal plasma as a percent of total fatty acids only, while in MNR fetal plasma only EPA increased. These results provide the first indication that MNR in early to mid-gestation influences the profiles of LCPUFA in fetal tissues, and suggest that metabolic processes involving LCPUFA should be considered in evaluations of the impact of maternal nutriture on perinatal health.

  1. Cerium Biomagnification in a Terrestrial Food Chain: Influence of Particle Size and Growth Stage.

    Science.gov (United States)

    Majumdar, Sanghamitra; Trujillo-Reyes, Jesica; Hernandez-Viezcas, Jose A; White, Jason C; Peralta-Videa, Jose R; Gardea-Torresdey, Jorge L

    2016-07-01

    Mass-flow modeling of engineered nanomaterials (ENMs) indicates that a major fraction of released particles partition into soils and sediments. This has aggravated the risk of contaminating agricultural fields, potentially threatening associated food webs. To assess possible ENM trophic transfer, cerium accumulation from cerium oxide nanoparticles (nano-CeO2) and their bulk equivalent (bulk-CeO2) was investigated in producers and consumers from a terrestrial food chain. Kidney bean plants (Phaseolus vulgaris var. red hawk) grown in soil contaminated with 1000-2000 mg/kg nano-CeO2 or 1000 mg/kg bulk-CeO2 were presented to Mexican bean beetles (Epilachna varivestis), which were then consumed by spined soldier bugs (Podisus maculiventris). Cerium accumulation in plant and insects was independent of particle size. After 36 days of exposure to 1000 mg/kg nano- and bulk-CeO2, roots accumulated 26 and 19 μg/g Ce, respectively, and translocated 1.02 and 1.3 μg/g Ce, respectively, to shoots. The beetle larvae feeding on nano-CeO2 exposed leaves accumulated low levels of Ce since ∼98% of Ce was excreted in contrast to bulk-CeO2. However, in nano-CeO2 exposed adults, Ce in tissues was higher than Ce excreted. Additionally, Ce content in tissues was biomagnified by a factor of 5.3 from the plants to adult beetles and further to bugs.

  2. Uptake, transport and peroral absorption of fatty glyceride grafted chitosan copolymer-enoxaparin nanocomplexes: influence of glyceride chain length.

    Science.gov (United States)

    Wang, Linlin; Sun, Yujiao; Shi, Chenjun; Li, Liang; Guan, Jian; Zhang, Xin; Ni, Rui; Duan, Xiaopin; Li, Yaping; Mao, Shirui

    2014-08-01

    The objective of this paper is to elucidate the influence of fatty glyceride chain length in chitosan copolymers on the peroral absorption of enoxaparin. First of all, a series of chitosan copolymers with glyceryl monocaprylate (GM8), glyceryl monolaurate (GM12) and glyceryl monostearate (GM18) as the hydrophobic part were synthesized. The structure of the copolymers was characterized using proton nuclear magnetic resonance. 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay demonstrated that all the copolymers were non-toxic. Enoxaparin nanocomplexes were prepared by self-assembly. Mucoadhesion of the nanocomplexes was characterized using the mucin particle method. Nanocomplex uptake and transport were quantified in Caco-2 cells and cellular localization was visualized by confocal laser scanning microscopy. Enoxaparin uptake was enhanced by nanocomplex formation, and was dependent on incubation time, concentration, temperature and glyceride chain length. The GM8 grafted chitosan-enoxaparin nanocomplex exhibited the strongest bioadhesion and the best uptake and transport in both cell culture and in vivo absorption in rats. The uptake mechanism was assumed to be adsorptive endocytosis via clathrin- and caveolae-mediated processes. In conclusion, oral absorption of enoxaparin can be further enhanced by using GM8 grafted chitosan copolymer as the carrier to form nanocomplexes.

  3. Palladium Catalysts for Fatty Acid Deoxygenation: Influence of the Support and Fatty Acid Chain Length on Decarboxylation Kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Ford, JP; Immer, JG; Lamb, HH

    2012-03-29

    Supported metal catalysts containing 5 wt% Pd on silica, alumina, and activated carbon were evaluated for liquid-phase deoxygenation of stearic (octadecanoic), lauric (dodecanoic), and capric (decanoic) acids under 5 % H-2 at 300 A degrees C and 15 atm. On-line quadrupole mass spectrometry (QMS) was used to measure CO + CO2 yield, CO2 selectivity, H-2 consumption, and initial decarboxylation rate. Post-reaction analysis of liquid products by gas chromatography was used to determine n-alkane yields. The Pd/C catalyst was highly active and selective for stearic acid (SA) decarboxylation under these conditions. In contrast, SA deoxygenation over Pd/SiO2 occurred primarily via decarbonylation and at a much slower rate. Pd/Al2O3 exhibited high initial SA decarboxylation activity but deactivated under the test conditions. Similar CO2 selectivity patterns among the catalysts were observed for deoxygenation of lauric and capric acids; however, the initial decarboxylation rates tended to be lower for these substrates. The influence of alkyl chain length on deoxygenation kinetics was investigated for a homologous series of C-10-C-18 fatty acids using the Pd/C catalyst. As fatty acid carbon number decreases, reaction time and H-2 consumption increase, and CO2 selectivity and initial decarboxylation rate decrease. The increase in initial decarboxylation rates for longer chain fatty acids is attributed to their greater propensity for adsorption on the activated carbon support.

  4. Influence of Belousov-Zhabotinsky substrate concentrations on autonomous oscillation of polymer chains with Fe(bpy)3 catalyst.

    Science.gov (United States)

    Hara, Yusuke; Mayama, Hiroyuki; Fujimoto, Kenji

    2014-06-19

    We studied the effect of initial substrate concentrations in the Belousov-Zhabotinsky (BZ) reaction on the optical transmittance self-oscillation behavior of a polymer chain consisting of N-isopropylacrylamide (NIPAAm) and a Fe catalyst ([Fe(bpy)3]). The driving force of this transmittance self-oscillation was the solubility difference between the reduced and oxidized states of the [Fe(bpy)3] moiety in the polymer chain. The amplitude of the soluble-insoluble self-oscillation of poly(NIPAAm-co-[Fe(bpy)3]) was significantly smaller than that of poly(NIPAAm-co-[Ru(bpy)3]). Theoretical simulation results attributed this behavior to the small difference in the solvent qualities, C*, of the reduced and oxidized states. Furthermore, we clarified that poly(NIPAAm-co-[Fe(bpy)3]) required a narrower concentration range of HNO3 to exhibit self-oscillation than poly(NIPAAm-co-[Ru(bpy)3]), since transmittance self-oscillation occurred only for [HNO3] = 0.3 M. The period of self-oscillation of poly(NIPAAm-co-[Fe(bpy)3]) in solution was controlled mainly by NaBrO3 concentration and was hardly influenced by the initial concentration of malonic acid.

  5. Influence of LC Content on the Phase Structures of Side-Chain Liquid

    Energy Technology Data Exchange (ETDEWEB)

    Tenneti, K.; Chen, X; Li, C; Shen, Z; Wan, X; Fan, X; Zhou, Q; Rong, L; Hsiao, B

    2009-01-01

    We report the phase structures of a series of poly(styrene-block-{l_brace}3'-[4-(4-n-dodecyloxybenzoyloxy)benzoyloxy]-4-(12-methacryloyloxydodecyloxy)benzoyloxybiphenyl{r_brace}) (PS-b-PMAC) side-chain liquid crystalline block copolymers (SC LCBCP). The SC liquid crystalline polymer was formed by side attaching a bent-core mesogen to the polymer backbone using a 12-carbon spacer. The phase structure of the high and low fPMAC samples were investigated using differential scanning calorimetry, small-angle and wide-angle X-ray scattering, and transmission electron microscopy techniques. The PS coil block and PMAC LC block phase separate into a lamellar morphology in all of the samples investigated (volume fraction of PMAC fPMAC 0.31-0.65). However, both the LC phase and the orientation of the hierarchical structure under mechanical shear showed strong dependence on the LC content. Samples having a high fPMAC (0.5-0.65) showed a SmC2 LC phase (Smectic C denotes the LC molecules are tilted with respect to the layer normal, and 2 represents a bilayered structure), similar to that observed in PMAC homopolymers. Upon mechanical shear, these smectic layers oriented parallel to the shear plane and the BCP lamellae oriented perpendicular to the shear plane with the layer normal parallel to the vorticity direction. In samples having a lower fPMAC, the BCP lamellae laid parallel to the shear plane and the LC phase structure in these samples was columnar rectangular. A detailed structural and morphological study will be reported.

  6. Influence of C18 long chain fatty acids on hydrogen metabolism.

    Science.gov (United States)

    Templer, Jennifer; Lalman, Jerald A; Jing, Nin; Ndegwa, Pius M

    2006-01-01

    During anaerobic treatment, several microorganisms mediate a series of reactions to convert reduced compounds (electron donors) into methane. Inhibitors such as long chain fatty acids (LCFAs) can affect several anaerobic microbial populations and decrease the treatment efficiency. The effects of three C18 LCFAs on hydrogenotrophic methanogens in a flocculated mixed anaerobic culture were assessed in this study. The reaction half-life and the hydrogen versus time profiles were used to characterize the inhibition process. The half-life values and profiles were similar for controls and cultures exposed to LCFAs for 1 h. The hydrogen inhibition was a function of the exposure time and the LCFA concentration except for cultures exposed to stearic acid (SA). A statistical analysis of the reaction half-life for cultures incubated with 1,500 and 2,000 mg L(-1) LCFAs for 48 h, revealed the following inhibition trend: linoleic acid (LA) > oleic acid (OA) > SA. After 48 h of exposure, no clear inhibition trend was observed for cultures inoculated with LCFA mixtures; however, at levels of 1,500 and 2,000 mg L(-1), the reaction half-life values were less than that observed for cultures fed with only LA. Based on the reaction half-life data, all of the LCFAs except SA at threshold levels of approximately 1,500 mg L(-1) inhibited hydrogen metabolism. The greatest inhibition and, hence, the largest amount of accumulated hydrogen was observed in cultures fed with 2,000 mg L(-1) LA and incubated for 48 h.

  7. Ischemic postconditioning influences electron transport chain protein turnover in Langendorff-perfused rat hearts

    Directory of Open Access Journals (Sweden)

    Song Cao

    2016-02-01

    Full Text Available Ischemia postconditioning (IPo is a promising strategy in reducing myocardial ischemia reperfusion (I/R injury (MIRI, but its specific molecular mechanism is incompletely understood. Langendorff-perfused isolated rat hearts were subjected to global I/R and received IPo in the absence or presence of the mitochondrial ATP-sensitive potassium channel (mitoKATP blocker 5-hydroxydecanoate (5-HD. Myocardial mitochondria were extracted and mitochondrial comparative proteomics was analyzed. IPo significantly reduces post-ischemic myocardial infarction and improved cardiac function in I/R rat hearts, while 5-HD basically cancelled IPo’s myocardial protective effect. Joint application of two-dimensional polyacrylamide gel electrophoresis (2DE and MALDI-TOF MS identified eight differentially expressed proteins between groups. Expression of cardiac succinate dehydrogenase (ubiquinone flavoprotein subunit (SDHA increased more than two-fold after I/R, while IPo led to overexpression of dihydrolipoyl dehydrogenase (DLD, NADH dehydrogenase (ubiquinone flavoprotein 1 and isoform CRA_b (NDUFV1. When the mitoKATP was blocked, MICOS complex subunit Mic60 (IMMT and Stress-70 protein (Grp75 were over expressed, while DLDH, ATPase subunit A (ATPA and rCG44606 were decreased. Seven of the differential proteins belong to electron transport chain (ETC or metabolism regulating proteins, and five of them were induced by closing mitoKATP in I/R hearts. We thus conclude that IPo’s myocardial protective effect relies on energy homeostasis regulation. DLD, SDHA, NDUFV1, Grp75, ATPA and rCG44606 may contribute to IPo’s cardial protective effect.

  8. Ischemic postconditioning influences electron transport chain protein turnover in Langendorff-perfused rat hearts.

    Science.gov (United States)

    Cao, Song; Liu, Yun; Wang, Haiying; Mao, Xiaowen; Chen, Jincong; Liu, Jiming; Xia, Zhengyuan; Zhang, Lin; Liu, Xingkui; Yu, Tian

    2016-01-01

    Ischemia postconditioning (IPo) is a promising strategy in reducing myocardial ischemia reperfusion (I/R) injury (MIRI), but its specific molecular mechanism is incompletely understood. Langendorff-perfused isolated rat hearts were subjected to global I/R and received IPo in the absence or presence of the mitochondrial ATP-sensitive potassium channel (mitoKATP) blocker 5-hydroxydecanoate (5-HD). Myocardial mitochondria were extracted and mitochondrial comparative proteomics was analyzed. IPo significantly reduces post-ischemic myocardial infarction and improved cardiac function in I/R rat hearts, while 5-HD basically cancelled IPo's myocardial protective effect. Joint application of two-dimensional polyacrylamide gel electrophoresis (2DE) and MALDI-TOF MS identified eight differentially expressed proteins between groups. Expression of cardiac succinate dehydrogenase (ubiquinone) flavoprotein subunit (SDHA) increased more than two-fold after I/R, while IPo led to overexpression of dihydrolipoyl dehydrogenase (DLD), NADH dehydrogenase (ubiquinone) flavoprotein 1 and isoform CRA_b (NDUFV1). When the mitoKATP was blocked, MICOS complex subunit Mic60 (IMMT) and Stress-70 protein (Grp75) were over expressed, while DLDH, ATPase subunit A (ATPA) and rCG44606 were decreased. Seven of the differential proteins belong to electron transport chain (ETC) or metabolism regulating proteins, and five of them were induced by closing mitoKATP in I/R hearts. We thus conclude that IPo's myocardial protective effect relies on energy homeostasis regulation. DLD, SDHA, NDUFV1, Grp75, ATPA and rCG44606 may contribute to IPo's cardial protective effect.

  9. Influence of nonlinear sorption kinetics on the slow-desorbing organic contaminant fraction in soil

    NARCIS (Netherlands)

    Schlebaum, W.; Schraa, G.; Riemsdijk, van W.H.

    1999-01-01

    Release rates of hydrophobic organic compounds (HOCs) from the soil matrix influence the availability of HOCs in soils or sediments for microbial degradation or removal by physical means (e.g., soil washing or soil venting). In this study it was shown that the initial contaminant concentration influ

  10. Influence of chain ordering on frictional properties of self-assembled monolayers (SAMs) in nano-lubrication.

    Science.gov (United States)

    Cheng, Hefa; Hu, Yuanan

    2012-01-01

    Adhesion of organic films to substrates is important in applications that involve solid surfaces in sliding contact. Although the thickness of self-assembled monolayers (SAMs) is only a few nanometers, they can drastically modify the frictional properties of the underlying substrate, and thus have great potential for serving as boundary lubricants on micro- and nano-scales. This review focuses on the relationship between the structural and compositional properties of SAMs and their frictional response. Adhesion of SAMs to the substrate surface usually occurs through chemisorption of the head groups on the constituent molecules, with molecular interactions such as van der Waals interactions playing important roles in organizing the molecules into surface films, and in controlling their tribological behavior. The durability and wear resistance of SAMs depend on the nature and strength of the binding forces between the head groups and the substrate surfaces, while the adhesion and friction forces are strongly influenced by the interactions of the terminal groups with the counterfaces. Results from both experimental measurements and molecular dynamics simulations consistently indicate that structural ordering of alkyl chains in SAMs reduces their frictional response, and that SAMs formed by molecules with alkyl chains longer than 8 to 10 methylene units are well organized, exhibiting low levels of friction. Less densely packed or more disordered monolayers inherently possess greater numbers of conformational defects at room temperature and present lower barriers to defect creation under the action of a contacting surface, and thus exhibit higher friction. Cross-linking of the spacer chains can reduce the frictional response of disordered films by increasing the chain ordering, but has little impact on SAMs that are already well ordered. On the other hand, introduction of sterically demanding terminal groups and dissimilar molecules reduces molecular ordering in SAMs

  11. INFLUENCE OF TRANSPORT FACTOR ON STOCKS IN LOGISTICS CHAINS OF RESOURCE BEHAVIOU

    Directory of Open Access Journals (Sweden)

    I. A. Lebedeva

    2011-01-01

    Full Text Available The paper considers behaviour of material flows at stages of complicated  logistic industrial and transport systems. Key parameters of logistic delivery schemes are analyzed in the paper. The paper estimates an influence of a time parameter on the level of transport and logistics costs and, as a consequence, on  a final finished product.While determining a stock level it is necessary to know not only an intensity of material resource consumption by manufacturing process  for a concrete period of time, but also a probability of non-observance of   transport service terms and cost of stock storage. Stocks of mass cargoes are basically formed at first stages of industrial and transport system and cost of their storage is relatively insignificant. However deficit presence of the given resources influences on functioning of all subsequent interrelated stages of the industrial and transport system.Thus, a risk of deficit occurrence of the given resources can be probably reduced by creating a high stock rate. There is a processing of hi-tech component items (or half-finished products at last stages of the industrial and transport system. Expenses on storage of such resources  are usually high and possibility of their substitution by analogous ones is insignificant. At last stages a mobilization of facilities for provision of on-time delivery is more profitable that allows to save on stock arrangement.

  12. The Influence of Spatial Resolution on Nonlinear Force-Free Modeling

    CERN Document Server

    DeRosa, M L; Leka, K D; Barnes, G; Amari, T; Canou, A; Gilchrist, S A; Thalmann, J K; Valori, G; Wiegelmann, T; Schrijver, C J; Malanushenko, A; Sun, X; Régnier, S

    2015-01-01

    The nonlinear force-free field (NLFFF) model is often used to describe the solar coronal magnetic field, however a series of earlier studies revealed difficulties in the numerical solution of the model in application to photospheric boundary data. We investigate the sensitivity of the modeling to the spatial resolution of the boundary data, by applying multiple codes that numerically solve the NLFFF model to a sequence of vector magnetogram data at different resolutions, prepared from a single Hinode/SOT-SP scan of NOAA Active Region 10978 on 2007 December 13. We analyze the resulting energies and relative magnetic helicities, employ a Helmholtz decomposition to characterize divergence errors, and quantify changes made by the codes to the vector magnetogram boundary data in order to be compatible with the force-free model. This study shows that NLFFF modeling results depend quantitatively on the spatial resolution of the input boundary data, and that using more highly resolved boundary data yields more self-c...

  13. Controllability in nonlinear systems

    Science.gov (United States)

    Hirschorn, R. M.

    1975-01-01

    An explicit expression for the reachable set is obtained for a class of nonlinear systems. This class is described by a chain condition on the Lie algebra of vector fields associated with each nonlinear system. These ideas are used to obtain a generalization of a controllability result for linear systems in the case where multiplicative controls are present.

  14. OPTIMAL CONTRACTS IN TWO-ECHELON SUPPLY CHAIN UNDER ASYMMETRIC INFORMATION AND NONLINEAR DEMAND%不对称信息和非线性需求下两级供应链优化契约

    Institute of Scientific and Technical Information of China (English)

    庄品; 赵林度

    2008-01-01

    The challenge for supply chain management is to create appropriate supply chain contracts so as to optimize the system performance. To examine the role of asymmetric information in a two-echelon supply chain system and derive supply chain contracts to deal with existing asymmetric information, a two level supply chain model including one supplier and one retailer under the demand of price elasticity is developed. By using the principal-agent principle and the optimal control theory, three types of supply chain contract, i.e., a wholesale pricing contract, a two-parameter linear and a two-parameter nonlinear contracts are obtained. In these contracts, the supplier has asymmetric information about the retailer cost structure. Simulation results show that the two-parameter contracts are more effective strategies to achieve supply chain coordination.%为研究两级供应链系统中不对称信息的作用,并设计供应链契约有效地解决信息不对称问题,文中建立了市场需求为价格弹性需求,包含一个供应商和一个零售商的两级供应链模型.当零售商成本结构为非对称信息时,利用委托-代理理论和最优控制原理设计了3种不对称信息和非线性需求下供应链契约:批发价契约、双参数线性契约和双参数非线性契约,并对上述3种契约模型进行数值仿真分析.研究显示双参数契约模型能够更有效地达到供应链协调.

  15. Influence of Guided Waves in Tibia on Non-linear Scattering of Contrast Agents.

    Science.gov (United States)

    Wang, Diya; Zhong, Hui; Zhai, Yu; Hu, Hong; Jin, Bowen; Wan, Mingxi

    2016-02-01

    The aim of this study was to elucidate the linear and non-linear responses of ultrasound contrast agent (UCA) to frequency-dispersive guided waves from the tibia cortex, particularly two individual modes, S0 (1.23 MHz) and A1 (2.06 MHz). The UCA responses to guided waves were illustrated through the Marmottant model derived from measured guided waves, and then verified by continuous infusion experiments in a vessel-tibia flow phantom. These UCA responses were further evaluated by the enhanced ratio of peak values and the resolutions of UCA backscattered echoes. Because of the individual modes S0 and A1 in the tibia, the peak values of the UCA backscattered echoes were enhanced by 83.57 ± 7.35% (p < 0.05) and 80.77 ± 6.60% (p < 0.01) in the UCA subharmonic frequency and subharmonic imaging, respectively. However, corresponding resolutions were 0.78 ± 0.07 (p < 0.05) and 0.72 ± 0.12 (p < 0.01) times those without guided wave disturbances, respectively. Even though the resolution was partly degenerated, the subharmonic detection sensitivity of UCA was improved by the guided waves. Thus, UCA responses to the double-frequency guided waves should be further explored to benefit the detection of capillary perfusion in tissue layers near the bone cortex, particularly for perfusion imaging in the free flaps and skeletal muscles.

  16. Antagonism influences assembly of a Bacillus guild in a local community and is depicted as a food-chain network.

    Science.gov (United States)

    Pérez-Gutiérrez, Rocío-Anaís; López-Ramírez, Varinia; Islas, África; Alcaraz, Luis David; Hernández-González, Ismael; Olivera, Beatriz Carely Luna; Santillán, Moisés; Eguiarte, Luis E; Souza, Valeria; Travisano, Michael; Olmedo-Alvarez, Gabriela

    2013-03-01

    Understanding the principles that govern community assemblages is a central goal of ecology. There is limited experimental evidence in natural settings showing that microbial assembly in communities are influenced by antagonistic interactions. We, therefore, analyzed antagonism among bacterial isolates from a taxonomically related bacterial guild obtained from five sites in sediments from a fresh water system. We hypothesized that if antagonistic interactions acted as a shaping force of the community assembly, then the frequency of resistance to antagonism among bacterial isolates originating from a given site would be higher than the resistance to conspecifics originating from a different assemblage. Antagonism assays were conducted between 78 thermoresistant isolates, of which 72 were Bacillus spp. Sensitive, resistant and antagonistic isolates co-occurred at each site, but the within-site frequency of resistance observed was higher than that observed when assessed across-sites. We found that antagonism results from bacteriocin-like substances aimed at the exclusion of conspecifics. More than 6000 interactions were scored and described by a directed network with hierarchical structure that exhibited properties that resembled a food chain, where the different Bacillus taxonomic groups occupied specific positions. For some tested interacting pairs, the unidirectional interaction could be explained by competition that inhibited growth or completely excluded one of the pair members. This is the first report on the prevalence and specificity of Bacillus interactions in a natural setting and provides evidence for the influence of bacterial antagonist interactions in the assemblage of a taxonomically related guild in local communities.

  17. Influence of dispersants on petroleum bioavailability in a marine food chain

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, M.F.; Younghans-Haug, C.O.; Tjeerdema, R.S. [Univ. of California, Santa Cruz, CA (United States); Sowby, M.L. [Office of Oil Spill Prevention and Response, Sacramento, CA (United States)

    1994-12-31

    Oil spills represent a serious threat to marine organisms. Crude oil consists of numerous compounds with a wide range of physicochemical properties critical in determining those organisms at greatest risk. Surface inhabitants may benefit from the application of dispersing agents, yet little is understood of the disposition of the dispersed components of a spill. As the functional water solubility of petroleum hydrocarbons increases in the water column, the portion that is available for uptake may also increase, placing another group of organisms at risk. Potential increases in adsorption and bioaccumulation may extend the threat of oil spills from marine organisms to human consumers. Studies to date have focused on the acute toxicity of oil and dispersants. The objective of this research was to determine the influence of a dispersant on the bioavailability of crude oil components at concentrations below the no observable effect level (NOEL). Flow-through chambers were used to expose the algae, Isochrysis galbana, to ``undispersed`` Prudhoe Bay Crude Oil (PBCO) spiked with {sup 14}C naphthalene and ``dispersed`` spiked PBCO/Corexit 9527 sea water preparations. Bioavailability to Isochrysis was assessed as uptake, bioconcentration, and deputation of {sup 14}C naphthalene and its metabolites. Results of exposure studies will be presented.

  18. The influence of sodium-polyacrilic macromolecular chain length to the powder detergents secondary washing performances

    Directory of Open Access Journals (Sweden)

    Milojević Vladimir S.

    2013-01-01

    Full Text Available In order to investigate the influence of sodium-polyacrylate polymer as a co-builder in addition to the carbonate/zeolite builders in detergent builder system, secondary washing performances of powder laundry detergent containing equal percentage of sodium polyacrylate with the different weight average molar mass, Mw, have been examined. The value of the degree of whiteness, elongation at break, and total residue content are the most important secondary washing performances that significantly depend on sodium polyacrylates efficiency used as crystal inhibitors, stabilizers for suspended soil, and agents for soil redisposition prevention on fabric surface. The values of the whiteness and elongation at break for cotton fabrics increase with the increase of average weight molecular mass, Mw, up to the value of 70000 g/mol, while in the case of further increase of weight average molar mass up to the 250000 g/mol value of these characteristics begin to decline. The values of the total residue content after combustion indicate an increase in its content with the increase of weight average molar mass of 3000 to 70000 g/mol, while the highest value has been reached in the sample of detergent containing sodiumpolyacrilic with the weight average molar mass of 250000 g/mol. All detergent samples show no significant dependence of the secondary washing characteristics on the number of washing cycles.

  19. Influences of hydraulic gradient, surface roughness, intersecting angle, and scale effect on nonlinear flow behavior at single fracture intersections

    Science.gov (United States)

    Li, Bo; Liu, Richeng; Jiang, Yujing

    2016-07-01

    Fluid flow tests were conducted on two crossed fracture models for which the geometries of fracture segments and intersections were measured by utilizing a visualization technique using a CCD (charged coupled device) camera. Numerical simulations by solving the Navier-Stokes equations were performed to characterize the fluid flow at fracture intersections. The roles of hydraulic gradient, surface roughness, intersecting angle, and scale effect in the nonlinear fluid flow behavior through single fracture intersections were investigated. The simulation results of flow rate agreed well with the experimental results for both models. The experimental and simulation results showed that with the increment of the hydraulic gradient, the ratio of the flow rate to the hydraulic gradient, Q/J, decreases and the relative difference of Q/J between the calculation results employing the Navier-Stokes equations and the cubic law, δ, increases. When taking into account the fracture surface roughness quantified by Z2 ranging 0-0.42 for J = 1, the value of δ would increase by 0-10.3%. The influences of the intersecting angle on the normalized flow rate that represents the ratio of the flow rate in a segment to the total flow rate, Ra, and the ratio of the hydraulic aperture to the mechanical aperture, e/E, are negligible when J 10-2. Based on the regression analysis on simulation results, a mathematical expression was proposed to quantify e/E, involving variables of J and Rr, where Rr is the radius of truncating circles centered at an intersection. For E/Rr > 10-2, e/E varies significantly and the scale of model has large impacts on the nonlinear flow behavior through intersections, while for E/Rr < 10-3, the scale effect is negligibly small. Finally, a necessary condition to apply the cubic law to fluid flow through fracture intersections is suggested as J < 10-3, E/Rr < 10-3, and Z2 = 0.

  20. Influence of ionization on ultrafast gas-based nonlinear fiber optics.

    Science.gov (United States)

    Chang, W; Nazarkin, A; Travers, J C; Nold, J; Hölzer, P; Joly, N Y; Russell, P St J

    2011-10-10

    We numerically investigate the effect of ionization on ultrashort high-energy pulses propagating in gas-filled kagomé-lattice hollow-core photonic crystal fibers by solving an established uni-directional field equation. We consider the dynamics of two distinct regimes: ionization induced blue-shift and resonant dispersive wave emission in the deep-UV. We illustrate how the system evolves between these regimes and the changing influence of ionization. Finally, we consider the effect of higher ionization stages.

  1. Perception of human-derived risk influences choice at top of the food chain.

    Science.gov (United States)

    Cristescu, Bogdan; Stenhouse, Gordon B; Boyce, Mark S

    2013-01-01

    On human-used landscapes, animal behavior is a trade-off between maximizing fitness and minimizing human-derived risk. Understanding risk perception in wildlife can allow mitigation of anthropogenic risk, with benefits to long-term animal fitness. Areas where animals choose to rest should minimize risk from predators, which for large carnivores typically equate to humans. We hypothesize that high human activity leads to selection for habitat security, whereas low activity enables trading security for forage. We investigated selection of resting (bedding) sites by GPS radiocollared adult grizzly bears (n = 10) in a low density population on a multiple-use landscape in Canada. We compared security and foods at resting and random locations while accounting for land use, season, and time of day. On reclaimed mines with low human access, bears selected high horizontal cover far from trails, but did not avoid open (herbaceous) areas, resting primarily at night. In protected areas bears also bedded at night, in areas with berry shrubs and Hedysarum spp., with horizontal cover selected in the summer, during high human access. On public lands with substantial human recreation, bears bedded at day, selected resting sites with high horizontal cover in the summer and habitat edges, with bedding associated with herbaceous foods. These spatial and temporal patterns of selection suggest that bears perceive human-related risk differentially in relation to human activity level, season and time of day, and employ a security-food trade-off strategy. Although grizzly bears are presently not hunted in Alberta, their perceived risks associated with humans influence resting-site selection.

  2. Perception of human-derived risk influences choice at top of the food chain.

    Directory of Open Access Journals (Sweden)

    Bogdan Cristescu

    Full Text Available On human-used landscapes, animal behavior is a trade-off between maximizing fitness and minimizing human-derived risk. Understanding risk perception in wildlife can allow mitigation of anthropogenic risk, with benefits to long-term animal fitness. Areas where animals choose to rest should minimize risk from predators, which for large carnivores typically equate to humans. We hypothesize that high human activity leads to selection for habitat security, whereas low activity enables trading security for forage. We investigated selection of resting (bedding sites by GPS radiocollared adult grizzly bears (n = 10 in a low density population on a multiple-use landscape in Canada. We compared security and foods at resting and random locations while accounting for land use, season, and time of day. On reclaimed mines with low human access, bears selected high horizontal cover far from trails, but did not avoid open (herbaceous areas, resting primarily at night. In protected areas bears also bedded at night, in areas with berry shrubs and Hedysarum spp., with horizontal cover selected in the summer, during high human access. On public lands with substantial human recreation, bears bedded at day, selected resting sites with high horizontal cover in the summer and habitat edges, with bedding associated with herbaceous foods. These spatial and temporal patterns of selection suggest that bears perceive human-related risk differentially in relation to human activity level, season and time of day, and employ a security-food trade-off strategy. Although grizzly bears are presently not hunted in Alberta, their perceived risks associated with humans influence resting-site selection.

  3. An Improved Empirical Model for Evaluating the Influence of Agricultural Supply Chain on Food Processing Enterprise Performance

    OpenAIRE

    XiaoFei Zhao

    2015-01-01

    Agriculture supply chain has much economic benefits, it can promote the product circulation, provide cooperation opportunity for both the upstream and downstream enterprises. In order to analyze how the agriculture supply chain effect on the business performance in food processing industry, we make a statistical analysis about the effect of agriculture supply chain on food processing industry by using data from 1990 to 2013. The result shows that: First, Agriculture supply chain development w...

  4. Influence of the abdominal wall on the nonlinear propagation of focused therapeutic ultrasound

    Institute of Scientific and Technical Information of China (English)

    Liu Zhen-Bo; Fan Ting-Bo; Zhang Dong; Gong Xiu-Fen

    2009-01-01

    y This article theoretically studies the influence of inhomogeneous abdominal walls on focused therapeutic ultrasound based on the phase screen model. An inhomogeneous tissue is considered as a combination of a homogeneous medium and a phase aberration screen. Variations of acoustic parameters such as peak positive pressure, peak negative pressure, and acoustic intensity are discussed with respect to the phase screen statistics of human abdominal walls. Results indicate that the abdominal wall can result in energy loss of the sound in the focal plane. For a typical human abdominal wall with correlation length of 7.9 mm and variance of 0.36, the peak acoustic intensity radiated from a 1 MHz transmitter with a radius of 30 mm can be reduced by about 14% at the focal plane.

  5. A technique for determining the optimum mix of logistics service providers of a make-to-order supply chain by formulating and solving a constrained nonlinear cost optimization problem

    Directory of Open Access Journals (Sweden)

    Mrityunjoy Roy

    2013-04-01

    Full Text Available In this paper, a technique has been developed to determine the optimum mix of logistic service providers of a make-to-order (MTO supply chain. A serial MTO supply chain with different stages/ processes has been considered. For each stage different logistic service providers with different mean processing lead times, but same lead time variances are available. A realistic assumption that for each stage, the logistic service provider who charges more for his service consumes less processing lead time and vice-versa has been made in our study. Thus for each stage, for each service provider, a combination of cost and mean processing lead time is available. Using these combinations, for each stage, a polynomial curve, expressing cost of that stage as a function of mean processing lead time is fit. Cumulating all such expressions of cost for the different stages along with incorporation of suitable constraints arising out of timely delivery, results in the formulation of a constrained nonlinear cost optimization problem. On solving the problem using mathematica, optimum processing lead time for each stage is obtained. Using these optimum processing lead times and by employing a simple technique the optimum logistic service provider mix of the supply chain along with the corresponding total cost of processing is determined. Finally to examine the effect of changes in different parameters on the optimum total processing cost of the supply chain, sensitivity analysis has been carried out graphically.

  6. Third-order nonlinear optical responses in derivatives of phenylhydrazone by Z-scan and optical limiting studies-influence of noble metal nanoparticles

    Science.gov (United States)

    Sudheesh, P.; Siji Narendran, N. K.; Chandrasekharan, K.

    2013-12-01

    Here we report a study on the third-order nonlinear optical properties of a new class of phenylhydrazones and the influence of silver and gold metal nanoparticles on their nonlinear response. Metal nanoparticles were prepared by laser ablation method. Single beam Z-scan technique with a 7 ns, 10 Hz Nd: YAG laser pulses at 532 nm were employed for the measurements. The compounds exhibit well optical limiting properties. Hence, these compounds are a promising class of materials for the optical device applications.

  7. Influence of Ossicular Chain Damage on Hearing After Chronic Otitis Media and Cholesteatoma Surgery : A Systematic Review and Meta-analysis

    NARCIS (Netherlands)

    Blom, Erik F; Gunning, Marlise; Kleinrensink, Nienke J; Lokin, Alexander S H J; Bruijnzeel, Hanneke; Smit, Adriana L; Grolman, Wilko

    2015-01-01

    IMPORTANCE: Physicians should ideally be able to provide patients with chronic otitis media and/or cholesteatoma specific information about postoperative hearing outcome, based on their level of preoperative ossicular chain damage (OCD). OBJECTIVE: To identify the influence of preoperative OCD on he

  8. Analysis of the Influencing Factors and Key Driving Force concerning the Efficiency of Green Supply Chain of Fruits and Vegetables

    Institute of Scientific and Technical Information of China (English)

    Yingtang; LI; Zhong; QIAO

    2014-01-01

    Like the general green supply chain,the green supply chain of fruits and vegetables also requires low negative effects of the environment and high resource utilization rate,as well as the healthiness and freshness of fruits and vegetables.Currently,the level of development of the green supply chain of fruits and vegetables is low in China,and the freshness of fruits and vegetables can not be well maintained,so there is an urgent need to improve the operational efficiency of the green supply chain of fruits and vegetables.The operational efficiency of the green supply chain of fruits and vegetables is affected by many factors,and the most important factor is the incomplete consistency between the individual interests of supply chain members and the overall interests of supply chain.Therefore,the key driving force to improve the efficiency of green supply chain of fruits and vegetables is to build the scientific and rational collaborative decision-making mechanism of supply chain,in order to solve the problems concerning the green supply chain of fruits and vegetables,such as risk sharing,cost control and revenue allocation,thereby achieving the coordinated development of the green supply chain of fruits and vegetables.

  9. Smoking among construction workers: the nonlinear influence of the economy, cigarette prices, and antismoking sentiment.

    Science.gov (United States)

    Okechukwu, Cassandra; Bacic, Janine; Cheng, Kai-Wen; Catalano, Ralph

    2012-10-01

    Little research has been conducted on the influence of macroeconomic environments on smoking among blue-collar workers, a group with high smoking prevalence and that is especially vulnerable to the effects of changing economic circumstances. Using data from 52,418 construction workers in the Tobacco Use Supplement to the United States Current Population Survey, we examined the association of labor market shock, cigarette prices, and state antismoking sentiments with smoking status and average number of cigarettes smoked daily. Data analysis included the use of multiple linear and logistic regressions, which employed the sampling and replicate weights to account for sampling design. Unemployed, American-Indian, lower-educated and lower-income workers had higher smoking rates. Labor market shock had a quadratic association, which was non-significant for smoking status and significant for number of cigarettes. The association of cigarette prices with smoking status became non-significant after adjusting for state-level antismoking sentiment. State-level antismoking sentiment had significant quadratic association with smoking status among employed workers and significant quadratic association with number of cigarettes for all smokers. The study highlights how both workplace-based smoking cessation interventions and antismoking sentiments could further contribute to disparities in smoking by employment status.

  10. An analysis of the influence of logistics activities on the export cold chain of temperature sensitive fruit through the Port of Cape Town

    Directory of Open Access Journals (Sweden)

    Leila L. Goedhals-Gerber

    2015-02-01

    Full Text Available Background: South Africa exports a large variety of different fruit types and cultivars worldwide. Yet, there is concern in the South African fruit industry that too much fruit and money is lost each year due to breaks along the fresh fruit export cold chain.Objective: The objective of this article was to identify the influence of logistics activities on breaks along the South African fruit export cold chain. The focus is specifically on temperature sensitive fruit, exported in refrigerated containers to Europe and the United Kingdom through the Port of Cape Town. This supply chain was selected as this was the most accessible supply chain in terms of retrieving the necessary temperature data.Method: The cold chain was investigated from the cold store, through all segments, until the Port of Cape Town. Temperature data collected with temperature monitoring devices from different fruit export supply chains of grapes, plums and pome fruit (apples and pears were analysed to identify the percentage of temperature breaks and the length of temperature breaks that occur at each segment of the cold chain.Results: The results show that a large number of breaks are experienced along South Africa’s fruit export cold chain, specifically at the interface between the cold store and the truck. In addition, the findings also show that there has been an improvement in the number of breaks experienced in the Port of Cape Town following the implementation of the NAVIS and Refcon systems.Conclusion: This article concludes by providing the fruit industry with areas that require addressing to improve operational procedures along the fruit export cold chain to help ensure that the fruit arrives at its final destination at optimal quality.

  11. The influence of fully nonlinear wave forces on aero-hydro-elastic calculations of monopile wind turbines

    DEFF Research Database (Denmark)

    Schløer, Signe; Bredmose, Henrik; Bingham, Harry B.

    2016-01-01

    and nonlinear irregular wave realizations are calculated using the fully nonlinear potential flow wave model OceanWave3D [1]. The linear and nonlinear wave realizations are compared using both a static analysis on a fixed monopile and dynamic calculations with the aeroelastic code Flex5 [2]. The conclusion from...... this analysis is that linear wave theory is generally sufficient for estimating the fatigue loading, but wave nonlinearity is important in determining the ultimate design loads.......The response of an offshore wind turbine tower and its monopile foundation has been investigated when exposed to linear and fully nonlinear irregular waves on four different water depths. The investigation focuses on the consequences of including full nonlinearity in the wave kinematics. The linear...

  12. A study on important factors influencing customers’ impulsive buying behavior: A case study of Shahrvand food chain

    Directory of Open Access Journals (Sweden)

    Hamed Asgari

    2013-05-01

    Full Text Available Customer purchasing behavior plays an essential role on marketing planning in today’s competitive environment. Immediate purchasing behavior is one of the most important components of purchasing behavior. In this paper, we use factor analysis to extract important factors influencing immediate purchasing behavior.The proposed study of this paper designs a questionnaire including 35 questions and through basic investigation, the questions are reduced to 21 ones. The questionnaire is distributed among 200 regular customers and 149 questionnaires have been collected. Cronbach alpha has been calculated as 0.804, which is well above the minimum desirable level of 0.7. The survey is conducted among regular customers who normally make purchases from Shahrvand food chains in city of Tehran, Iran. The results of factor analysis reveals four major factors including intelligence pricing strategy, involvement, promotion margin and consumer behavior. The proposed study of this paper considers “intelligence pricing strategy” for the first time as an important factor in consumer’s purchasing behavior.

  13. Influence of the dietary intake of medium chain triglycerides on body composition, energy expenditure and satiety: a systematic review

    Directory of Open Access Journals (Sweden)

    A. C. Rego Costa

    Full Text Available Increased prevalence of obesity is associated with the growth of chronic degenerative diseases. One of the main factors associated with this increase is the change in nutritional status of individuals. Medium chain triglycerides (MCT are rapidly metabolized and less stored in the adipose tissue, being a possible tool for weight control. In order to analyze the influence of consumption of this lipid on satiety, body composition and energy expenditure (EE, a literature review was performed of controlled clinical studies reported in PUBMED and ELSEVIER between the years 2000 and 2010. Fourteen articles were selected presenting short and long-term intervention. Among these, six showed a decrease in body mass of individuals, with consequent loss of weight. Only one showed a positive effect on satiation and four showed an increase in EE. Thus the results are inconclusive and there is a need for further controlled studies with standardized amounts of MCT, so that its use can become an alternative for obesity nutritional treatment.

  14. Influence of lysolecithin and Tween 80 on the colloidal stability of branched chain amino acids in a nanosuspension system.

    Science.gov (United States)

    Hong, Chi Rac; Lee, Gyu Whan; Paik, Hyun-Dong; Chang, Pahn-Shick; Choi, Seung Jun

    2017-04-15

    This study examined the influence of stabilizers on the solubility and colloidal stability of branched chain amino acids (BCAAs) nanosuspended through high pressure homogenization at 70°C. Although homogenization increased the initial BCAA solubility, irrespective of pH (pH 3 or 6), homogenization alone was not sufficient to increase their long-term solubility. The incorporation of stabilizers into nanosuspensions increased the saturation concentration of BCAAs but the effect of stabilizers on the increase in the saturation concentration of BCAAs was more pronounced at pH 6.0. At pH 6, Tween 80 dramatically increased the colloidal stability of the BCAA nanosuspensions, independent of the BCAA:stabilizer ratio but not at pH 3. However, the effect of lysolecithin on the colloidal stability of nanosuspended BCAAs varied depending on pH and BCAA:lysolecithin ratio. In lysolecithin-related nanosuspensions, there was no clear relationship between the colloidal stability and nanosuspension conditions including pH and BCAA:lysolecithin ratio. This study could provide a useful information on stabilizer selection for the development of liquid or colloidal products with improved solubility and colloidal stability of nanosuspended BCAAs.

  15. Influence of Dynamic Properties of Nonlinear Over-Voltage Limiter on Over-Voltage Limitation in Distribution Networks

    Directory of Open Access Journals (Sweden)

    A. N. Bokhan

    2009-01-01

    Full Text Available One of the most efficient means of over-voltage reduction in arcing ground short-circuits is an application of   a nonlinear over-voltage limiter. It is necessary to take into account dynamic properties of the nonlinear over-voltage limiter in order to ensure authentic simulation of  over-voltage in the network A dynamic model of  the non-linear over-voltage limiter which takes a time lag constant   τ  into account during transition of the nonlinear over-voltage limiter into conducting state has been developed in the paper.

  16. Analysis of the Influencing Factors and Key Driving Force concerning the Efficiency of Green Supply Chain of Fruits and Vegetables

    OpenAIRE

    Li,Yingtang; Qiao, Zhong

    2014-01-01

    Like the general green supply chain, the green supply chain of fruits and vegetables also requires low negative effects of the environment and high resource utilization rate, as well as the healthiness and freshness of fruits and vegetables. Currently, the level of development of the green supply chain of fruits and vegetables is low in China, and the freshness of fruits and vegetables can not be well maintained, so there is an urgent need to improve the operational efficiency of the green su...

  17. Influence of intrapulse Raman scattering on the stationary pulses in the presence of linear and nonlinear gain as well as spectral filtering

    Science.gov (United States)

    Uzunov, Ivan M.; Georgiev, Zhivko D.; Arabadzhev, Todor N.

    2015-01-01

    In this paper we present numerical investigation of the influence of intrapulse Raman scattering (IRS) on the stable stationary pulses. Our basic equation, namely cubic-quintic Ginzburg-Landau equation describes the propagation of ultra-short optical pulses under the effect of IRS in the presence of linear and nonlinear gain as well as spectral filtering. Our aim is to examine numerically the influence of IRS, on the stable stationary pulses in the presence of constant linear and nonlinear gain as well as spectral filtering. Numerical solution of our basic equation is performed by means of the "fourth-order Runge-Kutta method in the interaction picture method" method. We found that the small change of the value of the parameter which describes IRS leads to qualitatively different behavior of the evolution of pulse amplitudes. In order to study the observed strong dependence on the IRS, the perturbation method of conserved quantities of the nonlinear Schrodinger equation is applied. The numerical analysis of the derived nonlinear system of ordinary differential equations has shown that our numerical findings are related to the existence of the Poincare-Andronov-Hopf bifurcation.

  18. Theoretical study on second-order nonlinear optical properties of unsymmetric bis (phenylethynyl) benzene series derivatives

    Institute of Scientific and Technical Information of China (English)

    FU, Wei; FENG, Ji-Kang; YU, Kun-Qian; REN, Ai-Min; CUI, Meng

    2000-01-01

    On the basis of Z1NDO methods, according to the sum-overstates (SOS) expression, the progran for the calculation of the second-order nonlinear optical susceptibilities βuk and βμ ofmolecules was devised, and the structures and nonlinear optical properties of unsymmetric bis (phenylethynyl) benzene series derivatives were studied. The influence of the molecular conjugated chain lengths, the donor and the acceptor on βμwas examined.

  19. Standing waves for discrete nonlinear Schrodinger equations

    OpenAIRE

    Ming Jia

    2016-01-01

    The discrete nonlinear Schrodinger equation is a nonlinear lattice system that appears in many areas of physics such as nonlinear optics, biomolecular chains and Bose-Einstein condensates. By using critical point theory, we establish some new sufficient conditions on the existence results of standing waves for the discrete nonlinear Schrodinger equations. We give an appropriate example to illustrate the conclusion obtained.

  20. 带随机效应非线性模型的影响分析%INFLUENCE ANALYSIS IN NONLINEAR MODELS WITH RANDOM EFFECTS

    Institute of Scientific and Technical Information of China (English)

    韦博成; 宗序平

    2001-01-01

    In this paper,a unified diagnostic method for the nonlinear models with random effects based upon the joint likelihood given by Robinson in 1991 is presented.It is shown that the case deletion model is equivalent to the mean shift outlier model.From this point of view,several diagnostic measures,such as Cook distance,score statistics are derived.The local influence measure of Cook is also presented. A numerical example illustrates that the method is available.

  1. 3D打印对供应链的影响%Influence of 3D Printing on Supply Chain

    Institute of Scientific and Technical Information of China (English)

    马国伟

    2014-01-01

    3D打印广泛应用于医疗、原型模型、替代零件等领域,美国3D打印市场仅2011年就达17亿美元,全球3D产业平均利润平均每年增长26%,引起了《经济学人》与中国工信部的高度关注,然而国内管理学界却对其研究甚少。本文综述了3D打印从供应链视角可能产生的变革,并且提出在科技创新洪流涌现的今天,学界应该加强研究关于破坏性创新技术对组织以及相关产业的影响。%With the widespread application of 3D printing in the fields of medical system, prototype model and replacement parts, its market in the U.S. amounted to$1.71 billion in 2011. And the relative industry profit of it witnessed an average annual growth by 26%globally. This kind of rapid development trend caused the concern from Ministry of Industry and Information Technology of the P.R.China, as well as the journal The Economist. However, relevant research lacks in management circles in China. This paper first introduces the potential changes to 3D printing in supply chain, and then suggests researches on the influences of disruptive innovation to organiza-tions and related industries in the current of technology innovation.

  2. Analysis of Influence of Supply Chain Finance on TPL Industry%供应链金融对第三方物流业的影响分析

    Institute of Scientific and Technical Information of China (English)

    王燕; 孙江斌

    2013-01-01

    在分析供应链金融概念及其在我国发展状况的基础上,对国内外第三方物流企业供应链金融业务的差别进行了归纳,重点从技术发展、管理水平提升和行业整合三方面论述了供应链金融对第三方物流业的影响。%In this paper, on the basis of an analysis of the concept and current developmental status of supply chain finance in China, we summarized the difference between the supply chain finance businesses of TPL enterprises from China and the ones from overseas and then discussed the influence supply chain finance had on the third party logistics industry from the aspects of technical development, management level and industrial integration.

  3. Bond-length-alternation and the hyperpolarizabilities of a charged soliton in polyenic chains

    Science.gov (United States)

    An, Z.; Wong, K. Y.

    2003-07-01

    Nonlinear optical responses of a charged soliton were studied using a model charged polyenic chain. It was found that simple derivative relations exist between the spatial profile of the bond-length-alternation and the profiles of the real-space description of the linear polarizability and the first and second hyperpolarizabilities of the chain. These relations can be understood if the soliton is assumed to undergo a sliding translational motion under the influence of an external electric field.

  4. Influence of polyethylene glycol chain length on compatibility and release characteristics of ternary solid dispersions of itraconazole in polyethylene glycol/hydroxypropylmethylcellulose 2910 E5 blends.

    Science.gov (United States)

    Janssens, Sandrien; Denivelle, Samgar; Rombaut, Patrick; Van den Mooter, Guy

    2008-10-02

    The present study aims to elucidate the influence of the polyethylene glycol chain length on the miscibility of PEG/HPMC 2910 E5 polymer blends, the influence of polymer compatibility on the degree of molecular dispersion of itraconazole, and in vitro dissolution. PEG 2000, 6000, 10,000 and 20,000 were included in the study. Solid dispersions were prepared by spray drying and characterized with MDSC, XRPD and in vitro dissolution testing. The polymer miscibility increased with decreasing chain length due to a decrease in the Gibbs free energy of mixing. Recrystallization of itraconazole occurred as soon as a critical temperature of ca. 75 degrees C was reached for the glass transition that represents the ternary amorphous phase. Due to the lower miscibility degree between the longer PEG types and HPMC 2910 E5, the ternary amorphous phase was further separated, leading to a more rapid decrease of the ternary amorphous phase glass transition as a function of PEG and itraconazole weight percentage and hence, itraconazole recrystallization. In terms of release, an advantage of the shorter chain length PEG types (2000, 6000) over the longer chain length PEG types (10,000, 20,000) was observed for the polymer blends with 5% of PEG with respect to the binary itraconazole/HPMC 2910 E5 solid dispersion. Among the formulations with a 15/85 (w/w) PEG/HPMC 2910 E5 ratio on the other hand, there was no difference in the release profile.

  5. Influence of fast and slow alkali myosin light chain isoforms on the kinetics of stretch-induced force transients of fast-twitch type IIA fibres of rat.

    Science.gov (United States)

    Andruchov, Oleg; Galler, Stefan

    2008-03-01

    This study contributes to understand the physiological role of slow myosin light chain isoforms in fast-twitch type IIA fibres of skeletal muscle. These isoforms are often attached to the myosin necks of rat type IIA fibres, whereby the slow alkali myosin light chain isoform MLC1s is much more frequent and abundant than the slow regulatory myosin light chain isoform MLC2s. In the present study, single-skinned rat type IIA fibres were maximally Ca(2+) activated and subjected to stepwise stretches for causing a perturbation of myosin head pulling cycles. From the time course of the resulting force transients, myosin head kinetics was deduced. Fibres containing MLC1s exhibited slower kinetics independently of the presence or absence of MLC2s. At the maximal MLC1s concentration of about 75%, the slowing was about 40%. The slowing effect of MLC1s is possibly due to differences in the myosin heavy chain binding sites of the fast and slow alkali MLC isoforms, which changes the rigidity of the myosin neck. Compared with the impact of myosin heavy chain isoforms in various fast-twitch fibre types, the influence of MLC1s on myosin head kinetics of type IIA fibres is much smaller. In conclusion, the physiological role of fast and slow MLC isoforms in type IIA fibres is a fine-tuning of the myosin head kinetics.

  6. Bacterial membrane activity of a-peptide/b-peptoid chimeras: Influence of amino acid composition and chain length on the activity against different bacterial strains

    DEFF Research Database (Denmark)

    Hein-Kristensen, Line; Knapp, Kolja M; Franzyk, Henrik;

    2011-01-01

    , and this was parallel by the largest reduction in number of viable bacteria. CONCLUSION: We found that chain length but not type of cationic amino acid influenced the antibacterial activity of a series of synthetic α-peptide/β-peptoid chimeras. The synthetic chimeras exert their killing effect by permeabilization......BACKGROUND: Characterization and use of antimicrobial peptides (AMPs) requires that their mode of action is determined. The interaction of membrane-active peptides with their target is often established using model membranes, however, the actual permeabilization of live bacterial cells...... acid only had a minor effect on MIC values, whereas chain length had a profound influence on activity. All chimeras were less active against Serratia marcescens (MICs above 46 μM). The chimeras were bactericidal and induced leakage of ATP from Staphylococcus aureus and S. marcescens with similar time...

  7. Short communication: Influence of long-chain inulin and Lactobacillus paracasei subspecies paracasei on the sensory profile and acceptance of a traditional yogurt.

    Science.gov (United States)

    Pimentel, T C; Cruz, A G; Prudencio, S H

    2013-10-01

    The objectives of this study were to evaluate the influence of the addition of long-chain inulin as a fat replacer and prebiotic agent (20g/L) and (or) probiotic Lactobacillus paracasei ssp. paracasei on the sensory profile and acceptance of yogurts, and to assess the influence of descriptive attributes on the sensory acceptance of the products. The addition of inulin to low-fat yogurt improved its brightness and firmness, which was similar to the full-fat yogurt. However, the use of long-chain inulin increased the separation of serum and no influence on creaminess was observed. Regarding the product's acceptability, the low-fat yogurt with added inulin presented similar acceptance compared with the full-fat yogurt. The addition of Lb. paracasei ssp. paracasei did not affect the sensory profile and acceptance of the low-fat yogurt. Using external preference mapping, it was possible to verify that the sensory acceptance was driven positively by the sweetness and creaminess and negatively driven by firmness (appearance and texture) and homogeneity (appearance). It was possible to formulate low-fat yogurts with added probiotics that presented similar sensory characteristics to those of full-fat yogurts, and this was due to the addition of the long-chain inulin as a fat replacer.

  8. Integrability and soliton solutions for an inhomogeneous generalized fourth-order nonlinear Schrödinger equation describing the inhomogeneous alpha helical proteins and Heisenberg ferromagnetic spin chains

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Pan [State Key Laboratory of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications, Beijing 100876 (China); School of Science, Beijing University of Posts and Telecommunications, P.O. Box 122, Beijing 100876 (China); Tian, Bo, E-mail: tian.bupt@yahoo.com.cn [State Key Laboratory of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications, Beijing 100876 (China); School of Science, Beijing University of Posts and Telecommunications, P.O. Box 122, Beijing 100876 (China); Jiang, Yan; Wang, Yu-Feng [State Key Laboratory of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications, Beijing 100876 (China); School of Science, Beijing University of Posts and Telecommunications, P.O. Box 122, Beijing 100876 (China)

    2013-02-15

    For describing the dynamics of alpha helical proteins with internal molecular excitations, nonlinear couplings between lattice vibrations and molecular excitations, and spin excitations in one-dimensional isotropic biquadratic Heisenberg ferromagnetic spin with the octupole–dipole interactions, we consider an inhomogeneous generalized fourth-order nonlinear Schrödinger equation. Based on the Ablowitz–Kaup–Newell–Segur system, infinitely many conservation laws for the equation are derived. Through the auxiliary function, bilinear forms and N-soliton solutions for the equation are obtained. Interactions of solitons are discussed by means of the asymptotic analysis. Effects of linear inhomogeneity on the interactions of solitons are also investigated graphically and analytically. Since the inhomogeneous coefficient of the equation h=α x+β, the soliton takes on the parabolic profile during the evolution. Soliton velocity is related to the parameter α, distance scale coefficient and biquadratic exchange coefficient, but has no relation with the parameter β. Soliton amplitude and width are only related to α. Soliton position is related to β.

  9. THE INFLUENCE OF HUMAN SINGLE CHAIN INTELEUKIN-12 GENE TRANSDUCTION ON THE BIOLOGICAL BEHAVIOR OF HEPATOMA 7721 CELLS

    Institute of Scientific and Technical Information of China (English)

    金莉; 来保长; 耿宜萍; 王一理; 司履生

    2001-01-01

    Objective. To investigate the anti-tumor effects of human single chain interleukin-12 (hscIL-12). Method. pcDNA/hscIL-12 recombinant was transfected into human hepatic carcinoma cells (7721 cells) by lipofectin method. The 7721/hscIL-12 cells which secrete hscIL-12 stably, were obtained via G418 selection, and in vitro the influence of hscIL-12 gene transduction on the growth of tumor cells was evaluated by cellcycle analysis. In vivo, genetically engineered 7721 cells (7721/hscIL-12, 7721/pcDNA) and parental cells were implanted into BALB/c nude mice, respectively. 7721/pcDNA and 7721/hscIL-12 groups were divided into two sub-groups on day 8: one was administered with hPBL twice, 6 days at interval; the other was given equalvolume of PBS. Mice were sacrificed on day 26, and spleens and tumors were taken out for histologic assay. Results. hscIL-12 produced stably by 7721/hscIL-12 cells had bioactivity, and it was proved by Western blot, immunocytochemistry, and in situ hybridization. In vitro, compared with 7721 and 7721/pcDNA, the7721/hscIL-12 grew much more slowly. FACS assay showed apparent G1 arrest of 7721/hscIL-12 cells. In ani-mal experiment, on day 8 after inoculation, the tumors of 7721 and 7721/pcDNA group were up to 5 -7mm,while those of 7721/hscIL-12 group were 2 -4mm. When treated with hPBL, the tumor of 7721/hscIL-12 groupdisappeared completely. Histologically, the tumors from 7721/hscIL-12 without hPBL treatment had numerouslymphocyte infiltration, the tumor cells displayed depression looking, atrophy, focal necrosis and apoptosis, whereas the tumors of 7721 and 772l/pcDNA groups grew thrivingly.Conclusion. hsclL-12 transduced 7721 cells could induced significant antitumor immune response which resulted in tumor regression totally when the hPBL was inoculated, and also hscIL-12 has certain effects on mice immune system. These findings suggest that hscIL-12 and hscIL-12 gene therapy might have promising prospects in clinical application.

  10. Distributed nonlinear optical response

    DEFF Research Database (Denmark)

    Nikolov, Nikola Ivanov

    2005-01-01

    The purpose of the research presented here is to investigate basic physical properties in nonlinear optical materials with delayed or nonlocal nonlinearity. Soliton propagation, spectral broadening and the influence of the nonlocality or delay of the nonlinearity are the main focusses in the work....... The research presented in Chapter 3 and papers B and C is concerned with the properties and the stable dark soliton propagation and their bound states in nonlocal nonlinear optical media. It is shown that nonlocality of the nonlinearity induces attractive forces between solitons, that leads to the formation...... of bound states of out of phase bright solitons and dark solitons. Also, the newly introduced analogy between the nonlocal cubic nonlinear and the quadratic nonlinear media, presented in paper B and Chapter 3 is discussed. In particular it supplies intuitive physical meaning of the formation of solitons...

  11. Double bond stereochemistry influences the susceptibility of short-chain isoprenoids and polyprenols to decomposition by thermo-oxidation.

    Science.gov (United States)

    Molińska, Ewa; Klimczak, Urszula; Komaszyło, Joanna; Derewiaka, Dorota; Obiedziński, Mieczysław; Kania, Magdalena; Danikiewicz, Witold; Swiezewska, Ewa

    2015-04-01

    Isoprenoid alcohols are common constituents of living cells. They are usually assigned a role in the adaptation of the cell to environmental stimuli, and this process might give rise to their oxidation by reactive oxygen species. Moreover, cellular isoprenoids may also undergo various chemical modifications resulting from the physico-chemical treatment of the tissues, e.g., heating during food processing. Susceptibility of isoprenoid alcohols to heat treatment has not been studied in detail so far. In this study, isoprenoid alcohols differing in the number of isoprene units and geometry of the double bonds, β-citronellol, geraniol, nerol, farnesol, solanesol and Pren-9, were subjected to thermo-oxidation at 80 °C. Thermo-oxidation resulted in the decomposition of the tested short-chain isoprenoids as well as medium-chain polyprenols with simultaneous formation of oxidized derivatives, such as hydroperoxides, monoepoxides, diepoxides and aldehydes, and possible formation of oligomeric derivatives. Oxidation products were monitored by GC-FID, GC-MS, ESI-MS and spectrophotometric methods. Interestingly, nerol, a short-chain isoprenoid with a double bond in the cis (Z) configuration, was more oxidatively stable than its trans (E) isomer, geraniol. However, the opposite effect was observed for medium-chain polyprenols, since Pren-9 (di-trans-poly-cis-prenol) was more susceptible to thermo-oxidation than its all-trans isomer, solanesol. Taken together, these results experimentally confirm that both short- and long-chain polyisoprenoid alcohols are prone to thermo-oxidation.

  12. Synthesis and characterization of thermally stable second-order nonlinear optical side-chain polyimides containing thiazole and benzothiazole push-pull chromophores

    Science.gov (United States)

    Tambe, S. M.; Kittur, A. A.; Inamdar, S. R.; Mitchell, G. R.; Kariduraganavar, M. Y.

    2009-04-01

    Push-pull nonlinear optical (NLO) chromophores containing thiazole and benzothiazole acceptors were synthesized and characterized. Using these chromophores a series of second-order NLO polyimides were successfully prepared from 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA), pyromellitic dianhydride (PMDA) and 3,3'4,4'-benzophenone tetracarboxylic dianhydride (BTDA) by a standard condensation polymerization technique. These polyimides exhibit high glass transition temperatures ranging from 160 to 188 °C. UV-vis spectrum of polyimide exhibited a slight blue shift and decreases in absorption due to birefringence. From the order parameters, it was found that chromophores were aligned effectively. Using in situ poling and temperature ramping technique, the optical temperatures for corona poling were obtained. It was found that the optimal temperatures of polyimides approach their glass transition temperatures. These polyimides demonstrate relatively large d33 values range between 35.15 and 45.20 pm/V at 532 nm.

  13. Influence of surface roughness on nonlinear flow behaviors in 3D self-affine rough fractures: Lattice Boltzmann simulations

    Science.gov (United States)

    Wang, Min; Chen, Yi-Feng; Ma, Guo-Wei; Zhou, Jia-Qing; Zhou, Chuang-Bing

    2016-10-01

    This study investigates the impacts of surface roughness on the nonlinear fluid flow through three-dimensional (3D) self-affine rock fractures, whose original surface roughness is decomposed into primary roughness (i.e. the large-scale waviness of the fracture morphology) and secondary roughness (i.e. the small-scale unevenness) with a wavelet analysis technique. A 3D Lattice Boltzmann method (LBM) is adopted to predict the flow physics in rock fractures numerically created with and without consideration of the secondary roughness, respectively. The simulation results show that the primary roughness mostly controls the pressure distribution and fracture flow paths at a large scale, whereas the secondary roughness determines the nonlinear properties of the fluid flow at a local scale. As the pressure gradient increases, the secondary roughness enhances the local complexity of velocity distribution by generating and expanding the eddy flow and back flow regions in the vicinity of asperities. It was found that the Forchheimer's law characterizes well the nonlinear flow behavior in fractures of varying roughness. The inertial effects induced by the primary roughness differ only marginally in fractures with the roughness exponent varying from 0.5 to 0.8, and it is the secondary roughness that significantly enhances the nonlinear flow and leads to earlier onset of nonlinearity. Further examined were the effects of surface roughness on the transmissivity, hydraulic aperture and the tortuosity of flow paths, demonstrating again the dominant role of the secondary roughness, especially for the apparent transmissivity and the equivalent hydraulic aperture at high pressure gradient or high Reynolds number. The results may enhance our understanding of the role of surface roughness in the nonlinear flow behaviors in natural rock fractures.

  14. The haven of the self-service store: A study of the fruit and vegetable department's influence on chain equity

    DEFF Research Database (Denmark)

    Bech-Larsen, Tino

    In the Danish language "haven" means "the garden": A tranquil place with beautiful colours and vegetables where one can relax and prepare for the more stressful activities of modern life. Similarly, the chain store´s fruit and vegetable department can be the haven of the stressed self-service cus......In the Danish language "haven" means "the garden": A tranquil place with beautiful colours and vegetables where one can relax and prepare for the more stressful activities of modern life. Similarly, the chain store´s fruit and vegetable department can be the haven of the stressed self...... perception of the fruit & vegetable department can lead to an increased chain-equity and c) the factors in the fruit & vegetable department that determine the perception of this department....

  15. The Influence of Nonlinearity, Noise and Extinction Ratio on the Cascading Properties of 2R-Regenerators

    DEFF Research Database (Denmark)

    Öhman, Filip; Mørk, Jesper

    2005-01-01

    We have derived an expression for the BER of a cascade of 2R-regenerators including the effects of nonlinearity, noise and extinction-ratio. The best choice of threshold and the interplay bet1-55752-770-9ween device parameters are investigated.......We have derived an expression for the BER of a cascade of 2R-regenerators including the effects of nonlinearity, noise and extinction-ratio. The best choice of threshold and the interplay bet1-55752-770-9ween device parameters are investigated....

  16. Influence of the nonlinear phase and ASE noise on DPSK balanced optical receiver in optical fiber communication system

    Institute of Scientific and Technical Information of China (English)

    李蔚; 梅君瑶; 韩庆生; 王腾

    2009-01-01

    The analytical expression of bit error probability in a balanced differential phase-shift keying(DPSK) optical receiver considering nonlinear phase noise and EDFA ASE noise is given,which is very useful to estimate the performance of DPSK balanced and unbalanced receiver in optical communication system.Through analysis,if only nonlinear phase noise is considered,both the balance and unbalanced receivers have the same performances.But if adding the ASE noise of EDFA,the balanced receiver is better.

  17. Length of hydrocarbon chain influences location of curcumin in liposomes: Curcumin as a molecular probe to study ethanol induced interdigitation of liposomes.

    Science.gov (United States)

    El Khoury, Elsy; Patra, Digambara

    2016-05-01

    Using fluorescence quenching of curcumin in 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) liposomes by brominated derivatives of fatty acids, the location of curcumin has been studied, which indicates length of hydrocarbon chain has an effect on the location of curcumin in liposomes. Change of fluorescence intensity of curcumin with temperature in the presence of liposomes helps to estimate the phase transition temperature of these liposomes, thus, influence of cholesterol on liposome properties has been studied using curcumin as a molecule probe. The cooperativity due to the interactions between the hydrocarbon chains during melting accelerates the phase transition of DPPC liposomes in the presence of high percentage of cholesterol whereas high percentage of cholesterol generates a rather rigid DMPC liposome over a wide range of temperatures. We used ethanol to induce interdigitation between the hydrophobic chains of the lipids and studied this effect using curcumin as fluorescence probe. As a result of interdigitation, curcumin fluorescence is quenched in liposomes. The compact arrangement of the acyl chains prevents curcumin from penetrating deep near the midplane. In the liquid crystalline phase ethanol introduces a kind of order to the more fluid liposome, and does not leave space for curcumin to be inserted away from water.

  18. Influence of the germline sequence on the thermodynamic stability and fibrillogenicity of human lambda 6 light chains.

    Science.gov (United States)

    del Pozo Yauner, Luis; Ortiz, Ernesto; Sánchez, Rosalba; Sánchez-López, Rosana; Güereca, Leopoldo; Murphy, Charles L; Allen, Amy; Wall, Jonathan S; Fernández-Velasco, D Alejandro; Solomon, Alan; Becerril, Baltazar

    2008-08-01

    Light chain-associated amyloidosis is a fatal disease characterized by the aggregation and pathologic deposition of monoclonal light chain-related fragments as amyloid fibrils in organs or tissues throughout the body. Notably, it has been observed that proteins encoded by the lambda variable light chain (V(L)) gene segment 6a are invariably associated with amyloid deposition; however, the contribution of the gene to this phenomenon has not been established. In this regard, we have determined the thermodynamic stability and kinetics of in vitro fibrillogenesis of a recombinant (r) V(L) protein, designated 6aJL2, which contains the predicted sequences encoded by the 6a and JL2 germline genes. Additionally, we studied a 6a mutant (6aJL2-Arg25Gly), that is present in approximately 25% of all amyloid-associated lambda6 light chains. Remarkably, the wild-type 6aJL2 protein was more stable than were all known amyloidogenic kappa and lambda light chains for which stability parameters are available; more importantly, it was even more so (and less fibrillogenic) than the only clinically proven nonamyloidogenic lambda6 protein, Jto. Conversely, the mutated 6aJL2-R25G molecule was considerably less stable and more fibrillogenic than was the native 6aJL2. Our data indicate that the propensity of lambda6 light chains to form amyloid can not be attributed to thermodynamic instability of the germline-encoded Vlambda6 domain, but rather, is dependent on sequence alterations that render such proteins amyloidogenic.

  19. Mesomorphism and Optical Properties of Peripherally Substituted Phthalocyanines: Influence of Chain Length, Linking Group and Central Metal Ion

    OpenAIRE

    Sleven, Jurgen

    2002-01-01

    Phthalocyanines form a colourful class of macrocyclic compounds, attracting the attention of many scientists. Some of these compounds – especially the metal containing phthalocyanines – play an important role in industrial activity and in society. Applications for phthalocyanines are found in the fields of non-linear optics, catalysis, electronic (bio)sensors, photovoltaic solar cells, optical data storage, lubricants, photo- and radiosensitizers for treatment of cancer, protein inhibitors … ...

  20. The haven of the self-service store: A study of the fruit and vegetable department's influence on customer attitudes towards food chain stores

    DEFF Research Database (Denmark)

    Bech-Larsen, Tino

    2000-01-01

    As a result of the increased competition between self-service chains, retail managers try to strengthen store identity and customer loyalty to an increasing degree. In this respect a number of measures, as for example service management and direct marketing programmes, have been instigated. Most...... of these developments have concentrated on the peripheral spheres of the purchase decision situation. More recently retail managers have concentrated their efforts on the departments believed to be most important to customers' overall shopping experience and attitudes towards the store. So far, academic studies...... of which departments are the most important ones to customer attitudes, and how these attitudes are influenced by department specific factors, have been scarce, however. Unlike most other departments of a self-service chain store, the fruit and vegetable department gives ample opportunity...

  1. Nonlinear Dynamic Force Spectroscopy

    CERN Document Server

    Björnham, Oscar

    2016-01-01

    Dynamic force spectroscopy (DFS) is an experimental technique that is commonly used to assess information of the strength, energy landscape, and lifetime of noncovalent bio-molecular interactions. DFS traditionally requires an applied force that increases linearly with time so that the bio-complex under investigation is exposed to a constant loading rate. However, tethers or polymers can modulate the applied force in a nonlinear regime. For example, bacterial adhesion pili and polymers with worm-like chain properties are examples of structures that show nonlinear force responses. In these situations, the theory for traditional DFS cannot be readily applied. In this work we expand the theory for DFS to also include nonlinear external forces while still maintaining compatibility with the linear DFS theory. To validate the theory we modeled a bio-complex expressed on a stiff, an elastic and a worm-like chain polymer, using Monte Carlo methods, and assessed the corresponding rupture force spectra. It was found th...

  2. DETERMINATION OF THE FOREST ROAD NETWORK INFLUENCE ON THE SUPPLY CHAIN FOR FIREWOOD PRODUCTION BY DISCRETE EVENT SIMULATION

    Directory of Open Access Journals (Sweden)

    Raffaele Cavalli

    2012-06-01

    Full Text Available In this study a Discrete-event simulation (D-es has been developed to analyze the wood supply chain for firewood production in a mountain area in North-eastern Italy. The D-es is applied in the modeling of extraction (Full Tree System, processing of roundwood into wood assortments (cross-cut and sorting, offroad and on-road transport. In order to estimate the productivity functions and parameters, field studies were conducted to gather data about the different operations linked in the model. Also a GIS network analysis was developed to integrate the spatial information onthe covered distance to the D-es model for each of the supposed Scenarios. The results indicats that an increment of 5 m ha-1 of the forest road network could significantly increase the productivity of the wood supply chain up to 2%.

  3. The softer and more hydrophobic the better: influence of the side chain of polymethacrylate nanoparticles for cellular uptake.

    Science.gov (United States)

    Lorenz, Steffen; Hauser, Christoph P; Autenrieth, Benjamin; Weiss, Clemens K; Landfester, Katharina; Mailänder, Volker

    2010-09-09

    Intracellular uptake of nanoparticles is highly interesting for labeling of cells, drug delivery, or non-viral gene delivery. In this study we have synthesized a wide variety of poly(alkyl methacrylate) nanoparticles with the same size and investigated their uptake into cells. The nanoparticles were prepared from alkylmethacrylates with different linear and branched ester chains as well as from benzylmethacrylate using the miniemulsion polymerizaiton technique. By adding a fluorescent dye as a marker, the internalization of the nanoparticles could be investigated quantitatively with flow cytometry and qualitatively with confocal laser scanning microscopy. With increasing side chain of the ester and therefore increasing hydrophobicity and at glass transition temperature (T(g)), below the incubation temperature of 37 degrees C the uptake of the nanoparticles into cells is favored.

  4. Influence of Ion Nonlinear Polarization Drift and Warm Ions on Solitary Kinetic Alfvén Wave

    Institute of Scientific and Technical Information of China (English)

    DUAN Su-Ping; LI Zhong-Yuan

    2003-01-01

    Considering the effects of ion nonlinear polarization drift and warm ions, we adopt two-fluid model to results derived in this paper indicate that dip SKAW and hump SKAW both exist in a wide range in magnetosphere(for the pressure parameter β ~ 10-5 ~ 0.01, where βis the ratio of thermal pressure to magnetic pressure, i.e.region 1 > β > me/mi. These results are different from previous ones. That indicates that the effects of ion nonlinear polarization drift and warm ions are important and they cannot be neglected. The SKAW has an electric field parallel to the ambient magnetic field, which makes the SKAW take an important role in the acceleration and energization of field-aligned charged particles in magnetic plasmas. And the SKAW is also important for the heating of a local plasma.So it makes a novel physical mechanism of energy transmission possible.

  5. Influence of nanoscale temperature rises on photoacoustic generation: discrimination between optical absorbers based on nonlinear photoacoustics at high frequency

    CERN Document Server

    Simandoux, Oliver; Gâteau, Jérôme; Bossy, Emmanuel

    2013-01-01

    In the thermoelastic regime, photoacoustic sensing of optical absorption relies on conversion from light to acoustic energy via the coefficient of thermal expansion \\beta. In this work, we confront confront experimental measurements to theoretical predictions of nonlinear photoacoustic generation based on the dynamic variation of \\beta(T) during the optical excitation of absorbers in aqueous solution. The photoacoustic generation from solutions of organic dye and gold nanospheres (with same optical densities), illuminated with 532 nm nanosecond pulses, was detected using a high frequency ultrasound transducer (center frequency 20 MHz). Photoacoustic emission was observed with gold nanospheres at low fluence (a few mJ/cm2) for an equilibrium temperature around 4{\\deg}C, where the linear photoacoustic effect in water vanishes, highlighting the nonlinear emission from the solution of nanospheres. Under the same condition, no emission was observed with the absorbing organic dye. At a fixed fluence of 5 mJ/cm2, th...

  6. The change in cholesterol content of long chain fatty acid egg during processing and its influence to the Rattus norvegicus L. blood cholesterol content

    OpenAIRE

    Dini Hardini; Tri Yuwanta; Zuprizal (Zuprizal); Supadmo (Supadmo)

    2006-01-01

    Egg containing long chain unsaturated fatty acids is a functional food, because it is highly nutritious and could prevent diseases, (omega 3 and 6) such as coronary heart attack. The research was aimed to measure the change of egg cholesterol content during proceesing: frying, oiless frying and boiling and their influence to the blood plasma cholesterol of normal and hypercholesterolemia rat. Seven treatments of egg yolk were frying at 170°C for 3 min (welldone = GM), and 1min (half medium f...

  7. The influence of poly(phenyleneethynylene) side chain structure on single-walled carbon nanotubes hybrid photovoltaic cells.

    Science.gov (United States)

    Mao, Jie; Liu, Qian; Wang, Shujing; Lv, Xin; Huang, Yi; Ma, Yanfeng; Chen, Yongsheng; Yin, Shougen

    2008-07-01

    A novel poly(phenyleneethynylene)/single walled carbon nanotubes (SWNTs) donor-acceptor nanohybrid system was constructed based on the bulk heterojunction concept, and their photovoltaic (PV) properties were studied. Comparing with that of the pristine polymer poly(phenyleneethynylene) (PPE) device, the PV performance of the SWNTs/PPE hybrid is dramatically improved. The origin of open-circuit voltage (V(oc)) of the pristine polymer PPE device and SWNTs/PPE device was explained by metal-insulator-metal (MIM) diode model and pinning mechanism, respectively. Furthermore, incorporation of sensitizing groups to the side chain of PPE has great effect on the photovoltaic cell performance based on these hybrid materials and both the short-circuit current density (I(sc)) and power conversion efficiency are significantly enhanced. It is proposed that the main reason for the increase of short circuit current is due to efficient transfer of holes by sensitizer to PPE backbone and the transfer of electrons to the SWNTs. The power conversion efficiency is enhanced by approximately 1 order magnitude to 0.031% for the device based on the PPE3 with anthracene sensitizer group on the side chain compared with that (4.2 x 10(-3)% for SWNTs/PPE1 and 6.2 x 10(-3)% for SWNTs/PPE2) of the device without anthracene sensitizer on the side chain.

  8. Influence of the branches width on the nonlinear output characteristics of InAlAs/InGaAs-based three-terminal junctions

    Science.gov (United States)

    Iñiguez-de-la-Torre, I.; González, T.; Pardo, D.; Gardès, C.; Roelens, Y.; Bollaert, S.; Mateos, J.

    2009-05-01

    In this work, the influence of the geometry of the different branches on the output characteristics of InAlAs/InGaAs three-branch junctions is analyzed. At room temperature experimental measurements show that when increasing the width of the horizontal branches, the nonlinear behavior persists, even if less pronounced. This implies a reduction in the (typically high) impedance of these nanodevices, which is quite interesting in order to minimize the influence of parasitic capacitances on their cutoff frequency and to decrease the reflected power due to the mismatch with the 50 Ω standard equipment. The width of the vertical branch is also a relevant parameter, nonlinear effects being more important for narrow branches. In both cases surface charges at the etched boundaries of the branches play a key role. Monte Carlo simulations (performed with a self-consistent surface charge model recently proposed by the authors) are used to explain the physical origin of the observed behavior and to improve the device performance. We focus on the enhancement of their efficiency as a way to develop their promising functionalities in various analog and digital circuits.

  9. Uncovering a Nuisance Influence of a Phenological Trait of Plants Using a Nonlinear Structural Equation: Application to Days to Heading and Culm Length in Asian Cultivated Rice (Oryza Sativa L.).

    Science.gov (United States)

    Onogi, Akio; Ideta, Osamu; Yoshioka, Takuma; Ebana, Kaworu; Yamasaki, Masanori; Iwata, Hiroyoshi

    2016-01-01

    Phenological traits of plants, such as flowering time, are linked to growth phase transition. Thus, phenological traits often influence other traits through the modification of the duration of growth period. This influence is a nuisance in plant breeding because it hampers genetic evaluation of the influenced traits. Genetic effects on the influenced traits have two components, one that directly affects the traits and one that indirectly affects the traits via the phenological trait. These cannot be distinguished by phenotypic evaluation and ordinary linear regression models. Consequently, if a phenological trait is modified by introgression or editing of the responsible genes, the phenotypes of the influenced traits can change unexpectedly. To uncover the influence of the phenological trait and evaluate the direct genetic effects on the influenced traits, we developed a nonlinear structural equation (NSE) incorporating a nonlinear influence of the phenological trait. We applied the NSE to real data for cultivated rice (Oryza sativa L.): days to heading (DH) as a phenological trait and culm length (CL) as the influenced trait. This showed that CL of the cultivars that showed extremely early heading was shortened by the strong influence of DH. In a simulation study, it was shown that the NSE was able to infer the nonlinear influence and direct genetic effects with reasonable accuracy. However, the NSE failed to infer the linear influence in this study. When no influence was simulated, an ordinary bi-trait linear model (OLM) tended to infer the genetic effects more accurately. In such cases, however, by comparing the NSE and OLM using an information criterion, we could assess whether the nonlinear assumption of the NSE was appropriate for the data analyzed. This study demonstrates the usefulness of the NSE in revealing the phenotypic influence of phenological traits.

  10. Flow behaviour of inulin-milk beverages: Influence of inulin chain length and of milk fat content

    OpenAIRE

    Villegas, Beatriz; Costell, Elvira

    2003-01-01

    Inulin is used either as a macronutrient substitute or as a supplement added in foods mainly for its nutritional properties. Chemically, inulin consists of a long chain made up of fructose molecules and one glucose molecule at one end. The fructose molecules are connected by β-(2-1) bonds and the last fructose is linked with a glucose by an α-(1-2) bond as in sucrose [1, 2]. The average molecular weight and degree of polymerisation of inulin depend on the source of inulin, the time of harvest...

  11. Influence of the side chain next to C-terminal benzimidazole in opioid pseudopeptides containing the Dmt-Tic pharmacophore.

    Science.gov (United States)

    Balboni, Gianfranco; Trapella, Claudio; Sasaki, Yusuke; Ambo, Akihiro; Marczak, Ewa D; Lazarus, Lawrence H; Salvadori, Severo

    2009-09-10

    To improve the structure-activity studies of the lead delta opioid agonist H-Dmt-Tic-Asp*-Bid, we synthesized and pharmacologically characterized a series of analogues in which the side chain next to 1H-benzimidazole-2-yl (Bid) was substituted by those endowed with different chemical properties. Interesting results were obtained: (1) only Gly, Ala, and Asp resulted in delta agonism, (2) Phe yielded delta antagonism, (3) and all other residues except Glu (devoid of any activity) gave mu agonism.

  12. The influence of environmental parameters on the catabolism of branched-chain amino acids by Staphylococcus xylosus and Staphylococcus carnosus

    DEFF Research Database (Denmark)

    Olesen, Pelle Thonning; Stahnke, Louise Heller

    2004-01-01

    detection (GC/FID). Main volatile catabolic products of leucine, isoleucine and valine were 3-methylbutanoic, 2-methylbutanoic and 2-methylpropanoic acids, respectively. The generation of branched flavour compounds was influenced significantly by most of the investigated environmental parameters...

  13. The Factors Influencing the Development of Radio Frequency Identification Technology in E-Supply Chain Management (Case study: Iran Khodro Industrial Group (IKCO

    Directory of Open Access Journals (Sweden)

    Ali Sanayei

    2011-07-01

    The application of Radio Frequency Identification (RFID for the purpose of tracking each single part in the automotive supply chain management has become very crucial in recent years. In this study, the factors influencing the development of RFID in Iran Khodro Industrial Group as well as their weight and ranking are evaluated. It is notewothy that the Lin framework factors have been used as the basis of this research. The Fuzzy Delphi, Delphi, and Fuzzy Analytic Hierarchy Process (FAHP methods were applied for the research three stages. In the first stage, three of the Lin framework factors were rejected and replaced with seven more new factors. In the second stage, after three times performance of Delphi method, the dimension of each of the new seven factors was recognized, and finally in the third stage, the weight and ranking of factors and dimensions which influence the RFID development in supply chain management in our case study, Iran Khodro Company, was calculated. The results of the research have shown that the International Standard and Specification dimension has the highest weight among other influential dimensions. Also, the dimensions of Security, Cost, Infrastructure, Technology, and other factors have respectively the next highest weight after the International Standard and Specification dimension

  14. The influence of loyalty programs on customer's loyalty with a focus on food supply chains

    OpenAIRE

    Denemarková, Martina

    2014-01-01

    This bachelor thesis deals with the loyalty programs and their influence on customer's loyalty. In the introductory part, important terms such as marketing communication, customer loyalty, dedication, customer's decision-making process as well as loyalty programs are defined. Practical part defines course of marketing research and presents its results. Specific aims of my thesis include finding out whether or not customer's loyalty is influenced by loyalty programs. The thesis also includes e...

  15. Influence of chain microstructure on thermodegradative behavior of furfuryl methacrylate-N-vinylpyrrolidone random copolymers by thermogravimetry

    Energy Technology Data Exchange (ETDEWEB)

    Peniche, C.; Zaldivar, D. (Univ. de la Habana, Havana (Cuba). Centro de Biomateriales); Bulay, A. (Plastmassi, Moscow (Russian Federation)); Roman, J.S. (CSIC, Madrid (Spain). Inst. de Ciencia y Tecnologia de Polimeros)

    1993-12-20

    The thermal behavior of random copolymers of furfuryl methacrylate (F) and N-vinyl-pyrrolidone (P) was studied by means of dynamic thermogravimetric analysis (TGA) in the range 100--600 C. The dynamic experiments show that these copolymers exhibit two degradation steps in the intervals 260--320 C and 350--520 C, respectively. The normalized weight loss in the low temperature interval increases as the mole fraction of F in the copolymer m[sub F] increases, whereas an inverted trend in the high temperature interval is observed. The apparent activation energy E[sub a] of the first degradation step for copolymers prepared with different composition, was obtained according to the treatment suggested by Broido. A plot of the values of E[sub a] versus the F dead molar fraction in the copolymer chains m[sub FF] gave a straight line that indicates that there is a direct relationship between the thermogravimetric behavior of these systems and their corresponding microstructure, that is, the distribution of comonomeric units along the copolymers chains. The first decomposition step was also studied by isothermal TGA and a good linearity for the variation of the weight loss percentage [Delta]W versus m[sub F] at least during the first 30 min of treatment was obtained.

  16. Influence of nanoscale temperature rises on photoacoustic generation: Discrimination between optical absorbers based on thermal nonlinearity at high frequency.

    Science.gov (United States)

    Simandoux, Olivier; Prost, Amaury; Gateau, Jérôme; Bossy, Emmanuel

    2015-03-01

    In this work, we experimentally investigate thermal-based nonlinear photoacoustic generation as a mean to discriminate between different types of absorbing particles. The photoacoustic generation from solutions of dye molecules and gold nanospheres (same optical densities) was detected using a high frequency ultrasound transducer (20 MHz). Photoacoustic emission was observed with gold nanospheres at low fluence for an equilibrium temperature around 4 °C, where the linear photoacoustic effect in water vanishes, highlighting the nonlinear emission from the solution of nanospheres. The photoacoustic amplitude was also studied as a function of the equilibrium temperature from 2 °C to 20 °C. While the photoacoustic amplitude from the dye molecules vanished around 4 °C, the photoacoustic amplitude from the gold nanospheres remained significant over the whole temperature range. Our preliminary results suggest that in the context of high frequency photoacoustic imaging, nanoparticles may be discriminated from molecular absorbers based on nanoscale temperature rises.

  17. Influence of spacer chain lengths and polar terminal groups on the mesomorphic properties of tethered 5-phenylpyrimidines

    Directory of Open Access Journals (Sweden)

    Gundula F. Starkulla

    2009-11-01

    Full Text Available Based on 5-(4-hydroxyphenyl-2-octylpyrimidine 8, 5-phenylpyrimidine derivatives 3–7, 9 with different spacer chain lengths (C2 up to C6 and different terminal polar groups (Br, Cl, N3, OH, CN were synthesized by etherification and nucleophilic substitution. The mesomorphic behaviour of these compounds was investigated by differential scanning calorimetry (DSC, polarizing optical microscopy (POM and X-ray diffraction (WAXS and SAXS and revealed smectic A mesophases for bromides, chlorides and azides 3, 4 and 6. For these compounds a maximum phase width was observed for the C5 spacer regardless of the terminal group, whereas the hydroxy- and cyano-substituted derivatives 5 and 7, respectively, were non mesomorphic and showed only melting transitions.

  18. Surface structures of poly(methyl methacrylate) films influenced by chain entanglement in the corresponding film-formation solution.

    Science.gov (United States)

    Xu, Jianquan; Liu, Yingjun; He, Jinsheng; Zhang, Rongping; Zuo, Biao; Wang, Xinping

    2014-11-28

    The effects of the properties of casting solution on the surface structure of poly(methyl methacrylate) (PMMA) films were systematically investigated. It was observed that the hydrophobicity of PMMA films increased with increasing viscosity of the corresponding polymer solution regardless of the film-formation techniques that were utilized. The ratio of the C-H symmetric stretching vibrations of methylene groups (hydrophobic components, with a peak at 2910 cm(-1)) to those of the ester methyl groups (relative hydrophilic components, with a peak at 2955 cm(-1)) from sum frequency generation (SFG) vibrational spectra, A2910/A2955, was used as a parameter to evaluate the structure on the film surface, which was related to the surface wettability of the films. The results showed that A2910/A2955 of cast PMMA films increased linearly with ηsp(0.3) (ηsp, the specific viscosity of the casting solution), whereas that of the corresponding spin-coated films showed a linear relationship defined as ηsp(0.3)E(0.26), where E is the average number of entanglement points per molecule (E = Mw/Me). These results indicate that a relative equilibrium conformation on the PMMA film surface, adopted from the perspective of thermodynamics, was easily achieved during film formation, when the conformation of the polymer chains in the corresponding casting solution was close to that in the bulk. For the spin-coated films, the chain entanglement structure in the casting solution was a more important factor for the resulting film to reach a relative equilibrium state, since this structure was in favor of maintaining the pristine conformation in casting solution under centrifugal force during spin-coating. This work may help to enhance the fundamental understanding of the formation of the film surface structure from polymer solution to the resulting solid film, which will affect not only the corresponding surface properties, but also the dynamics of the resulting thin films.

  19. Standing waves for discrete nonlinear Schrodinger equations

    Directory of Open Access Journals (Sweden)

    Ming Jia

    2016-07-01

    Full Text Available The discrete nonlinear Schrodinger equation is a nonlinear lattice system that appears in many areas of physics such as nonlinear optics, biomolecular chains and Bose-Einstein condensates. By using critical point theory, we establish some new sufficient conditions on the existence results of standing waves for the discrete nonlinear Schrodinger equations. We give an appropriate example to illustrate the conclusion obtained.

  20. Influence of PEGylation with linear and branched PEG chains on the adsorption of glucagon to hydrophobic surfaces

    NARCIS (Netherlands)

    Pinholt, Charlotte; Bukrinsky, Jens Thostrup; Hostrup, Susanne; Frokjaer, Sven; Norde, Willem; Jorgensen, Lene

    2011-01-01

    PEGylation has proven useful for prolonging the plasma half lives of proteins, and since approval of the first PEGylated protein drug product by the FDA in 1990, several PEGylated protein drug products have been marketed. However, the influence of PEGylation on the behavior of proteins at interfaces

  1. Supercontinuum generation based on all-normal-dispersion Yb-doped fiber laser mode-locked by nonlinear polarization rotation: Influence of seed's output port

    Science.gov (United States)

    Xiao, Xiaosheng; Hua, Yi

    2016-10-01

    All-normal-dispersion (ANDi) mode-locked Yb-doped fiber laser is a promising seed source for supercontinuum (SC) generation, due to its compact structure and broadband output. The influences of output ports of the ANDi laser mode-locked by nonlinear polarization rotation (NPR), on the generated SC are investigated. Two output ports of ANDi laser are considered, one of which is the conventional nonlinear polarization rotation (NPR) port and the other is extracted from a coupler after the NPR port. It is found that, the SC originated from the coupler port is much broader than that from the NPR port, which is validated by lots of experiments with different output parameters. Furthermore, the conclusion is verified and generalized to general ANDi lasers by numerical simulations, because the output pulse from coupler port could be cleaner than that from NPR port. Besides, there are no significant differences in the phase coherence and temporal stability between the SCs generated from both ports. Hence for the SC generation based on ANDi laser, it is preferred to use the pulse of coupler port (i.e. pulse after NPR port) serving as the seed source.

  2. Influence of formic acid on electrical, linear and nonlinear optical properties of potassium dihydrogen phosphate (KDP) crystals

    Energy Technology Data Exchange (ETDEWEB)

    Anis, Mohd [Crystal Growth Laboratory, Department of Physics, Milliya Arts, Science and Management Science College, Beed 431122, Maharashtra (India); Shirsat, M.D. [Intelligent Material Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431005,Maharashtra (India); Muley, Gajanan [Department of Physics, Sant Gadge Baba Amravati University, Amravati 444602, Maharashtra (India); Hussaini, S.S., E-mail: Shuakionline@yahoo.co.in [Crystal Growth Laboratory, Department of Physics, Milliya Arts, Science and Management Science College, Beed 431122, Maharashtra (India)

    2014-09-15

    In present investigation 0.5 and 1 mol% formic acid (FA) added potassium dihydrogen phosphate (KDP) crystals have been grown by a slow evaporation technique. The cell parameters of the grown crystals were determined using single crystal X-ray diffraction analysis. The presence of different functional groups has been qualitatively analyzed by the FT-IR spectral analysis. The optical transparency and optical constants were assessed employing UV–visible studies in the range of 200–900 nm. The wide optical band gap of 1 mol% FA added KDP has been found to be 5 eV. The frequency dependent dielectric measurements were studied for pure and KDP added FA crystals. The enhanced second harmonic generation (SHG) efficiency of grown crystals was determined by a classical Kurtz–Perry powder technique. The encouraging third order nonlinear properties were examined employing a Z-scan technique using He–Ne laser, at 632.8 nm. The effective negative index of refraction and high figure of merit (FOM) essential for laser stabilization were determined for grown crystals. - Highlights: • Study on electrical and optical properties of formic acid (FA) added KDP was reported for the first time. • Optical properties were found to be enhanced with increasing concentration of FA. • The SHG efficiency of 1 mol% FA added KDP was 1.13 times that of KDP. • The high concentration of FA contributed lower dielectric properties to KDP suitable for microelectronics applications. • The improved third order nonlinear parameters were ascertained with addition of FA in KDP crystal.

  3. Seasonal flows of international British Columbia-Alaska rivers: The nonlinear influence of ocean-atmosphere circulation patterns

    Science.gov (United States)

    Fleming, Sean W.; Hood, Eran; Dalhke, Helen; O'Neel, Shad

    2016-01-01

    The northern portion of the Pacific coastal temperate rainforest (PCTR) is one of the least anthropogenically modified regions on earth and remains in many respects a frontier area to science. Rivers crossing the northern PCTR, which is also an international boundary region between British Columbia, Canada and Alaska, USA, deliver large freshwater and biogeochemical fluxes to the Gulf of Alaska and establish linkages between coastal and continental ecosystems. We evaluate interannual flow variability in three transboundary PCTR watersheds in response to El Niño-Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), Arctic Oscillation (AO), and North Pacific Gyre Oscillation (NPGO). Historical hydroclimatic datasets from both Canada and the USA are analyzed using an up-to-date methodological suite accommodating both seasonally transient and highly nonlinear teleconnections. We find that streamflow teleconnections occur over particular seasonal windows reflecting the intersection of specific atmospheric and terrestrial hydrologic processes. The strongest signal is a snowmelt-driven flow timing shift resulting from ENSO- and PDO-associated temperature anomalies. Autumn rainfall runoff is also modulated by these climate modes, and a glacier-mediated teleconnection contributes to a late-summer ENSO-flow association. Teleconnections between AO and freshet flows reflect corresponding temperature and precipitation anomalies. A coherent NPGO signal is not clearly evident in streamflow. Linear and monotonically nonlinear teleconnections were widely identified, with less evidence for the parabolic effects that can play an important role elsewhere. The streamflow teleconnections did not vary greatly between hydrometric stations, presumably reflecting broad similarities in watershed characteristics. These results establish a regional foundation for both transboundary water management and studies of long-term hydroclimatic and environmental change.

  4. Three dimensional non-linear evolution of a magnetic flux tube in a spherical shell: Influence of turbulent convection and associated mean flows

    CERN Document Server

    Jouve, Laurene

    2009-01-01

    We present the first 3D MHD study in spherical geometry of the non-linear dynamical evolution of magnetic flux tubes in a turbulent rotating convection zone. We study numerically the rise of magnetic toroidal flux ropes from the base of a modelled convection zone up to the top of our computational domain where bipolar patches are formed. We compare the dynamical behaviour of flux tubes in a fully convective shell possessing self-consistently generated mean flows such as meridional circulation and differential rotation, with reference calculations done in a quiet isentropic zone. We find that two parameters influence the tubes during their rise through the convection zone: the initial field strength and amount of twist, thus confirming previous findings in Cartesian geometry. Further, when the tube is sufficiently strong with respect to the equipartition field, it rises almost radially independently of the initial latitude (either low or high). By contrast, weaker field cases indicate that downflows and upflow...

  5. Antagonism influences assembly of a Bacillus guild in a local community and is depicted as a food-chain network

    OpenAIRE

    Pérez-Gutiérrez, Rocío-Anaís; López-Ramírez, Varinia; Islas, África; Alcaraz, Luis David; Hernández-González, Ismael; Olivera, Beatriz Carely Luna; Santillán, Moisés; Luis E Eguiarte; Souza, Valeria; Travisano, Michael; Olmedo-Alvarez, Gabriela

    2012-01-01

    Understanding the principles that govern community assemblages is a central goal of ecology. There is limited experimental evidence in natural settings showing that microbial assembly in communities are influenced by antagonistic interactions. We, therefore, analyzed antagonism among bacterial isolates from a taxonomically related bacterial guild obtained from five sites in sediments from a fresh water system. We hypothesized that if antagonistic interactions acted as a shaping force of the c...

  6. On the vibron nature in the system of two parallel macromolecular chains: The influence of interchain coupling

    Science.gov (United States)

    Čevizović, Dalibor; Ivić, Zoran; Galović, Slobodanka; Reshetnyak, Alexander; Chizhov, Alexei

    2016-06-01

    We studied the properties of the intramolecular vibrational excitation (vibron) at finite temperature in a system which consists of two parallel macromolecular chains. It was assumed that vibron interacts exclusively with dispersionless optical phonons and the whole system is considered to be in thermal equilibrium. Particular attention has been paid to the examination of the impact of the temperature and strength of the interchain coupling on the small polaron crossover. For that purpose we employed partial dressing method which enables the study of the degree of the phonon dressing of the vibron excitations in a wide area of system parameter space. We found that in the non-adiabatic regime the degree of dressing as a function of coupling constant continuously increases reflecting the smooth transition of the slightly dressed, practically free vibron, to a heavily dressed one: small polaron. As "adiabaticity" rises this transition becomes increasingly steeper, and finally, in the adiabatic limit, a discontinuous "jump" of the degree of dressing is observed. The interchain coupling manifests itself through the increase of the effective adiabatic parameter of the system.

  7. Metal compound-mediated hydrolytic cleavage of oxidized insulin B chain: Regioselectivity and influence of peptide secondary structure

    Institute of Scientific and Technical Information of China (English)

    罗雪梅; 何卫江; 张宇; 郭子建; 朱龙根

    2000-01-01

    The interaction of oxidized insulin B chain (B) with cis-[Pd-(en) Cl2] (en= ethylendiamine), cis-[Pd-(dtco-3-OH)Cl2](dtc o-3-OH= dithiacyclooctan-3-ol) and CuCl2 was studied by electrospray mass spectrometry. It is discovered that the binding of Pd(Ⅱ) complexes and the sites of cleavage are highly dependent on the secondary structure and local e nvironment of B. The hydrolytic cleavage of denatured B by Pd (Ⅱ) complexes was monitored by HPLC. The reaction is regioselective and follows first order kinetics with half-life of 4.8 days at 40°C. Two a mide bonds, i.e. at Leu6-Cys7 and at Gly8-Ser9, which are close to the two potential Pd(Ⅱ) binding sites His5 and His10, are selectively cleaved. In the case of Cu(Ⅱ) ion as promoter, only one cleavage site was observed which is located at Gly8-Ser9 bond. These results provide improved understanding on the deign of artificial metallopeptidase.

  8. The influence of alternative pathways of respiration that utilize branched-chain amino acids following water shortage in Arabidopsis.

    Science.gov (United States)

    Pires, Marcel V; Pereira Júnior, Adilson A; Medeiros, David B; Daloso, Danilo M; Pham, Phuong Anh; Barros, Kallyne A; Engqvist, Martin K M; Florian, Alexandra; Krahnert, Ina; Maurino, Veronica G; Araújo, Wagner L; Fernie, Alisdair R

    2016-06-01

    During dark-induced senescence isovaleryl-CoA dehydrogenase (IVDH) and D-2-hydroxyglutarate dehydrogenase (D-2HGDH) act as alternate electron donors to the ubiquinol pool via the electron-transfer flavoprotein/electron-transfer flavoprotein:ubiquinone oxidoreductase (ETF/ETFQO) pathway. However, the role of this pathway in response to other stresses still remains unclear. Here, we demonstrated that this alternative pathway is associated with tolerance to drought in Arabidopsis. In comparison with wild type (WT) and lines overexpressing D-2GHDH, loss-of-function etfqo-1, d2hgdh-2 and ivdh-1 mutants displayed compromised respiration rates and were more sensitive to drought. Our results demonstrated that an operational ETF/ETFQO pathway is associated with plants' ability to withstand drought and to recover growth once water becomes replete. Drought-induced metabolic reprogramming resulted in an increase in tricarboxylic acid (TCA) cycle intermediates and total amino acid levels, as well as decreases in protein, starch and nitrate contents. The enhanced levels of the branched-chain amino acids in loss-of-function mutants appear to be related to their increased utilization as substrates for the TCA cycle under water stress. Our results thus show that mitochondrial metabolism is highly active during drought stress responses and provide support for a role of alternative respiratory pathways within this response.

  9. Influences of bracket bonding on mutans streptococcus in plaque detected by real time fluorescence-quantitative polymerase chain reaction

    Institute of Scientific and Technical Information of China (English)

    AI Hong; LU Hong-fei; LIANG Huan-you; WU Jian; LI Ruo-lan; LIU Guo-ping; XI Yun

    2005-01-01

    Background Enamel demineralization occurs frequently during orthodontic treatment. In this study, we evaluated the changes of the density of mutans streptococcus (MS) in plaque after bracket bonding and using fluoride adhesive on maxillary incisors by real time fluorescence-quantitative polymerase chain reaction (RT-FQ PCR).Methods The study was designed as a self-paired test. Brackets were bonded with fluoride adhesive on the left side, while non-fluoride adhesive on the right side for each patient. Plaque samples were taken from the surfaces around the brackets of four maxillary incisors before brackets bonding and after the bonding 4 weeks later. The amount of MS was measured by RT-FQ PCR. The data obtained were analyzed statistically using the SPSS 11.5 version and the alpha level was set at 0.05 (2-tailed).Results The amount of MS in plaque increased significantly after bracket bonding (P0.05), and among the incisors using and not using fluoride adhesive (P>0.05).Conclusions The increase of the density of MS in plaque after bracket bonding is one of the etiological factors for enamel demineralization in orthodontic patients. The result of this study did not support what we observed clinically that the incidence of enamel demineralization for lateral incisors was higher than that for central incisors. Using fluoride adhesive for bonding did not affect the amount of MS in plaque in our study. Further study is needed.

  10. Synthesis of unsymmetric triphenylene discotic liquid crystals with a semi-fluorinated chain and the influence of fluorophobic effect on mesogenic behavior

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The fluorophobic effect of the semi-fluorinated chain of discotic molecules efficiently improves the stability of columnar mesophase.Low symmetric discogens exhibit decreased melting points and wide mesophase ranges.A series of triphenylene derivatives 1,C18H6(OCnH2n+1)4(OMe)(O2CC2H4C6F13),and their hydrocarbon analogues 2,C18H6(OCnH2n+1)4(OMe)(O2CC8H17),n = 4―8,were synthesized for the investigation of the influence of semi-fluorinated peripheral chain and molecular symmetry on mesomorphism.The structures were characterized with 1H NMR and MS.The mesomorphism was studied with differential scanning calorimetry(DSC) and polarizing optical microscopy(POM).The results showed that all triphenylene derivatives exhibited enantiotropic columnar mesophase.The semifluorinated triphenylenes 1a―1e displayed higher melting points and clearing points than their hydrocarbon analogies 2a―2e.Most of them were in columnar mesophase at room temperature.

  11. AN EMPIRICAL ANALYSIS OF THE INFLUENCE OF RISK FACTORS ON THE FREQUENCY AND IMPACT OF SEVERE EVENTS ON THE SUPPLY CHAIN IN THE CZECH REPUBLIC

    Directory of Open Access Journals (Sweden)

    José María Caridad

    2014-12-01

    Full Text Available Purpose: This paper is focused on an analysis and evaluation of severe events according to their frequency of occurrence and their impact on the company's manufacturing and distribution supply chains performance in the Czech Republic. Risk factors are introduced for critical events.Design/methodology: An identification and classification of severe events are realized on the basis of median mapping and mapping of ordinal variability acquired through the questionnaire survey of 82 companies. Analysis of 46 risk factors was sorted into 5 groups. We used asymmetric Somers's d statistics for testing the dependence of frequency and impact of a severe event on selected risk sources. The hierarchical cluster analysis is performed to identify relatively homogeneous groups of critical severe events according to their dependency on risk factors and its strength.Findings: Results showed that ‘a lack of contracts’ is considered to be the most critical severe event. Groups of demand and supply side and an external risk factor group were identified to be the most significant sources of risk factors. The worst cluster encompasses 11% of examined risk factors which should be prevented. We concluded that organizations need to adopt appropriate precautions and risk management methods in logistics.Originality: In this paper, the methodology for severe events evaluation in supply chain is designed. This methodology involves assessing the critical factors which influence the critical events and which should be prevented.

  12. Influence of trehalose 6,6'-diester (TDX) chain length on the physicochemical and immunopotentiating properties of DDA/TDX liposomes

    DEFF Research Database (Denmark)

    Kallerup, Rie Selchau; Madsen, Cecilie Maria; Schiøth, Mikkel Lohmann;

    2015-01-01

    Linking physicochemical characterization to functional properties is crucial for defining critical quality attributes during development of subunit vaccines toward optimal safety and efficacy profiles. We investigated how the trehalose 6,6'-diester (TDX) chain length influenced the physicochemical......, immunization of mice with the recombinant tuberculosis fusion antigen Ag85B-ESAT-6-Rv2660c (H56) and the physicochemically most optimal formulations (DDA/TDB, DDA/TDS and DDA/TDP) induced comparable T-cell responses. In conclusion, of the investigated TDB analogues, incorporation of 11mol% TDS or TDP into DDA...... liposomes resulted in an adjuvant system with the most favorable physicochemical properties and an immunological profile comparable to that of DDA/TDB....

  13. 互联网对供应链管理的影响机制研究%Influence of the Internet upon Supply Chain Management

    Institute of Scientific and Technical Information of China (English)

    李晶

    2011-01-01

    The paper analyzes the influence of the intemet upon enterprise practice for the management of both intra- and inter-enterprise supply chains, the findings of which could enable the enterprise to take full advantage of the opportunities brought by the internet while tackling the accompanying challenges to form sustainable competitive strength.%从企业内部供应链到企业与企业之间的供应链来分析互联网对企业供应链管理的影响机制,利于企业充分利用互联网带来的机遇、应对其带来的挑战,从而形成持续的竞争优势.

  14. Influence of fibrinogen β-chain gene variations on risk of myocardial infarction in a Chinese Han population

    Institute of Scientific and Technical Information of China (English)

    LU Xiang-feng; YU Hong-jiang; ZHOU Xiao-yang; WANG Lai-yuan; HUANG Jian-feng; GU Dong-feng

    2008-01-01

    Background Although the role of fibrinogen as a predictor of acute myocardial infarction(MI)has been well-established,the association of genetic polymorphisms in the fibrinogen gene with MI is still controversial.This study was conducted to elucidate the association between the genetic polymorphisms of the fibrinogen β-chain(FGB)gene and MI in Chinese Han population.Methods The occurrence of 3 common polymorphisms(i.e.-455G/A,R448K and 8558C/G)in a case-control study including 508 patients with MI and 503 healthy controls was investigated. Results Analyses of single polymorphisms showed that individuals carrying the rare alleles for the 3 polymorphisms were significantly associated with a decreased risk of MI.Logistic regression analysis indicated that R448K remained independently associated with MI after adjustment for environmental risk factors(adjusted odds ratio(OR)=0.71 for KK/RK versus RR.P=0.023).The three polymorphisms were found to be in strong linkage disequilibrium.Haplotype analyses showed that the A-K-G haplotype(-455A,448K,8558G)was associated with a protective effect against MI.Compared with the common haplotype G-R-C,the adjusted OR for A-K-G was 0.68(95% CI,0.51-0.90;P=0.006). Conclusion These data indicate that individuals carrying the FGB 448K allele may be protective against having MI in this population.

  15. Breatherlike excitations in discrete lattices with noise and nonlinear damping

    DEFF Research Database (Denmark)

    Christiansen, Peter Leth; Gaididei, Yuri B.; Johansson, Magnus

    1997-01-01

    We discuss the stability of highly localized, ''breatherlike,'' excitations in discrete nonlinear lattices under the influence of thermal fluctuations. The particular model considered is the discrete nonlinear Schrodinger equation in the regime of high nonlinearity, where temperature effects...

  16. The influence of the directional energy distribution on the nonlinear dispersion relation in a random gravity wave field

    Science.gov (United States)

    Huang, N. E.; Tung, C.-C.

    1977-01-01

    The influence of the directional distribution of wave energy on the dispersion relation is calculated numerically using various directional wave spectrum models. The results indicate that the dispersion relation varies both as a function of the directional energy distribution and the direction of propagation of the wave component under consideration. Furthermore, both the mean deviation and the random scatter from the linear approximation increase as the energy spreading decreases. Limited observational data are compared with the theoretical results. The agreement is favorable.

  17. Nitrate and the Origin of Saliva Influence Composition and Short Chain Fatty Acid Production of Oral Microcosms.

    Science.gov (United States)

    Koopman, Jessica E; Buijs, Mark J; Brandt, Bernd W; Keijser, Bart J F; Crielaard, Wim; Zaura, Egija

    2016-08-01

    Nitrate is emerging as a possible health benefactor. Especially the microbial conversion of nitrate to nitrite in the oral cavity and the subsequent conversion to nitric oxide in the stomach are of interest in this regard. Yet, how nitrate influences the composition and biochemistry of the oral ecosystem is not fully understood. To investigate the effect of nitrate on oral ecology, we performed a 4-week experiment using the multiplaque artificial mouth (MAM) biofilm model. This model was inoculated with stimulated saliva of two healthy donors. Half of the microcosms (n = 4) received a constant supply of nitrate, while the other half functioned as control (n = 4). Additionally, all microcosms received a nitrate and sucrose pulse, each week, on separate days to measure nitrate reduction and acid formation. The bacterial composition of the microcosms was determined by 16S rDNA sequencing. The origin of the saliva (i.e., donor) showed to be the strongest determinant for the development of the microcosms. The supplementation of nitrate was related to a relatively high abundance of Neisseria in the microcosms of both donors, while Veillonella was highly abundant in the nitrate-supplemented microcosms of only one of the donors. The lactate concentration after sucrose addition was similarly high in all microcosms, irrespective of treatment or donor, while the concentration of butyrate was lower after nitrate addition in the nitrate-receiving microcosms. In conclusion, nitrate influences the composition and biochemistry of oral microcosms, although the result is strongly dependent on the inoculum.

  18. Falling chains

    Science.gov (United States)

    Wong, Chun Wa; Yasui, Kosuke

    2006-06-01

    The one-dimensional fall of a folded chain with one end suspended from a rigid support and a chain falling from a resting heap on a table is studied. Because their Lagrangians contain no explicit time dependence, the falling chains are conservative systems. Their equations of motion are shown to contain a term that enforces energy conservation when masses are transferred between subchains. We show that Cayley's 1857 energy nonconserving solution for a chain falling from a resting heap is incorrect because it neglects the energy gained when a link leaves a subchain. The maximum chain tension measured by Calkin and March for the falling folded chain is given a simple if rough interpretation. Other aspects of the falling folded chain are briefly discussed.

  19. Inhibition mechanism of P-glycoprotein mediated efflux by mPEG-PLA and influence of PLA chain length on P-glycoprotein inhibition activity.

    Science.gov (United States)

    Li, Wenjing; Li, Xinru; Gao, Yajie; Zhou, Yanxia; Ma, Shujin; Zhao, Yong; Li, Jinwen; Liu, Yan; Wang, Xinglin; Yin, Dongdong

    2014-01-06

    The present study aimed to investigate the effect of monomethoxy poly(ethylene glycol)-block-poly(D,L-lactic acid) (mPEG-PLA) on the activity of P-glycoprotein (P-gp) in Caco-2 cells and further unravel the relationship between PLA chain length in mPEG-PLA and influence on P-gp efflux and the action mechanism. The transport results of rhodamine 123 (R123) across Caco-2 cell monolayers suggested that mPEG-PLA unimers were responsible for its P-gp inhibitory effect. Furthermore, transport studies of R123 revealed that the inhibitory potential of P-gp efflux by mPEG-PLA analogues was strongly correlated with their structural features and showed that the hydrophilic mPEG-PLA copolymers with an intermediate PLA chain length and 10.20 of hydrophilic-lipophilic balance were more effective at inhibiting P-gp efflux in Caco-2 cells. The fluorescence polarization measurement results ruled out the plasma membrane fluidization as a contributor for inhibition of P-gp by mPEG-PLA. Concurrently, mPEG-PLA inhibited neither basal P-gp ATPase (ATP is adenosine triphosphate) activity nor substrate stimulated P-gp ATPase activity, suggesting that mPEG-PLA seemed not to be a substrate of P-gp and a competitive inhibitor. No evident alteration in P-gp surface level was detected by flow cytometry upon exposure of the cells to mPEG-PLA. The depletion of intracellular ATP, which was likely to be a result of partial inhibition of cellular metabolism, was directly correlated with inhibitory potential for P-gp mediated efflux by mPEG-PLA analogues. Hence, intracellular ATP-depletion appeared to be possible explanation to the inhibition mechanism of P-gp by mPEG-PLA. Taken together, the establishment of a relationship between PLA chain length and impact on P-gp efflux activity and interpretation of action mechanism of mPEG-PLA on P-gp are of fundamental importance and will facilitate future development of mPEG-PLA in the drug delivery area.

  20. Dark Solitons in FPU Lattice Chain

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Based on multiple scales method, we study the nonlinear properties of a new Fermi-Pasta-Ulam lattice model analytically. It is found that the lattice chain exhibits a novel nonlinear elementary excitation, i.e. a dark soliton.Moreover, the modulation depth of dark soliton is increasing as the anharmonic parameter increases.

  1. Nonlinear oscillations

    CERN Document Server

    Nayfeh, Ali Hasan

    1995-01-01

    Nonlinear Oscillations is a self-contained and thorough treatment of the vigorous research that has occurred in nonlinear mechanics since 1970. The book begins with fundamental concepts and techniques of analysis and progresses through recent developments and provides an overview that abstracts and introduces main nonlinear phenomena. It treats systems having a single degree of freedom, introducing basic concepts and analytical methods, and extends concepts and methods to systems having degrees of freedom. Most of this material cannot be found in any other text. Nonlinear Oscillations uses sim

  2. Nonlinear analysis

    CERN Document Server

    Nanda, Sudarsan

    2013-01-01

    "Nonlinear analysis" presents recent developments in calculus in Banach space, convex sets, convex functions, best approximation, fixed point theorems, nonlinear operators, variational inequality, complementary problem and semi-inner-product spaces. Nonlinear Analysis has become important and useful in the present days because many real world problems are nonlinear, nonconvex and nonsmooth in nature. Although basic concepts have been presented here but many results presented have not appeared in any book till now. The book could be used as a text for graduate students and also it will be useful for researchers working in this field.

  3. Unwrapping Chains

    CERN Document Server

    Cambou, A D; Hamm, E; Hanna, J A; Menon, N; Santangelo, C D; Walsh, L

    2012-01-01

    A loop of chain can move along its own tangents, maintaining a steady shape. An open-ended chain undergoing a nontrivial motion must change its shape. One consequence is that chains pulled around objects will fail to follow the contours of the objects, unwrapping themselves instead. This short note accompanies a fluid dynamics video submission (83068) to the APS DFD Gallery of Fluid Motion 2012.

  4. Falling chains

    CERN Document Server

    Wong, C W; Wong, Chun Wa; Yasui, Kosuke

    2006-01-01

    The one-dimensional falling motion of a bungee chain suspended from a rigid support and of a chain falling from a resting heap on a table is studied. Their Lagrangians are found to contain no explicit time dependence. As a result, these falling chains are conservative systems. Each of their Lagrange's equations of motion is shown to contain a term that enforces energy conservation when masses are transferred between subchains. We show in particular that Cayley's 1857 energy nonconserving solution for a chain falling from a resting heap is incorrect because it neglects the energy gained when the transferred link is emitted by the emitting subchain. The maximum chain tension measured by Calkin and March for the falling bungee chain is given a simple if rough interpretation. In the simplified one-dimensional treatment, the kinetic energy of the center of mass of the falling bungee chain is found to be converted by the chain tension at the rigid support into the internal kinetic energy of the chain. However, as t...

  5. Parametrically Driven Nonlinear Oscillators with an Impurity

    Institute of Scientific and Technical Information of China (English)

    张卓; 唐翌

    2002-01-01

    By virtue of the method of multiple scales, we study a chain of parametrically driven nonlinear oscillators with a mass impurity. An equation is presented to describe the nonlinear wave of small amplitude in the chain.In our derivation, the equation is applicable to any eigenmode of coupled pendulum. Our result shows that a nonpropagation soliton emerges as the lowest or highest eigenmode of coupled pendulum is excited, and the impurity tends to pin the nonpropagation soliton excitation.

  6. ENSO influence on the North Atlantic European climate: a non-linear and non-stationary approach

    Science.gov (United States)

    López-Parages, Jorge; Rodríguez-Fonseca, Belén; Dommenget, Dietmar; Frauen, Claudia

    2016-10-01

    El Niño Southern Oscillation (ENSO) impact on the North Atlantic European sector (NAE) is still under discussion. Recent studies have found a non stationary feature of this teleconnection, suggesting an effective modulating role of the ocean mean state. Nevertheless, physical explanations about the underlying mechanisms have been little studied in the available literature. In addition, ENSO events show different SST spatial patterns, phases, and amplitudes, which can also influence on the related remote impacts. In view of all this, in the present study a set of partially coupled experiments have been performed with a global atmospheric general circulation model in which different SST ENSO patterns are superimposed over distinct Pacific and Atlantic SST mean states. These SST background conditions are constructed according to the observational difference between periods with a distinct impact of ENSO on the leading Euro-Mediterranean rainfall mode in late winter-early spring. Our results point to two distinct mechanisms associated with ENSO that can be modulated by the SST mean state: (1) the thermally driven direct circulation (Walker and Hadley cells) connecting the Atlantic and Pacific basins, and (2) the Rossby wave propagation from the tropical Pacific to the North Atlantic. The former elucidates that the positive NAO-like pattern usually related to La Niña events could be only valid for selected decades. The latter explains a reinforced signature of Eastern Pacific Niños on the Euro-Mediterranean rainfall when the tropical Pacific is warmer than usual and the North Atlantic is colder than usual. This feature is consistent with the changing ENSO impact identified in previous studies and demonstrates how the ENSO teleconnection with the NAE climate at interannual timecales could be modulated by multidecadal changes in the SST. According to our results, the assumption of stationarity which is still common to many studies of ENSO teleconnections clearly has to

  7. The influence of non-linear frequency compression on the perception of music by adults with a moderate to severe hearing loss: Subjective impressions

    Directory of Open Access Journals (Sweden)

    Marinda Uys

    2012-12-01

    Full Text Available Objective: To date, the main direction in frequency-lowering hearing aid studies has been in relation to speech perception abilities. With improvements in hearing aid technology, interest in musical perception as a dimension that could improve hearing aid users’ quality of life has grown. The purpose of this study was to determine the influence of non-linear frequency compression (NFC on hearing aid users’ subjective impressions of listening to music. Design & sample: A survey research design was implemented to elicit participants’ (N=40 subjective impressions of musical stimuli with and without NFC. Results: The use of NFC significantly improved hearing aid users’ perception of the musical qualities of overall fidelity, tinniness and reverberance. Although participants preferred to listen to the loudness, fullness, crispness, naturalness and pleasantness of music with the use of NFC, these benefits were not significant. Conclusion: The use of NFC can increase hearing aid users’ enjoyment and appreciation of music. Given that a relatively large percentage of hearing aid users express a loss of enjoyment of music, audiologists should not ignore the possible benefits of NFC, especially if one takes into account that previous research indicates speech perception benefits with this technology.

  8. Influence of the combined effect of magnetic field and rotation on the onset of a non-Newtonian viscoelastic nanofluid layer: Linear and nonlinear analyses

    Science.gov (United States)

    Khurana, Meenakshi; Rana, Puneet; Srivastava, Sangeet

    2016-12-01

    In the present paper, we present both linear and nonlinear analyses to investigate thermal instability on a rotating non-Newtonian viscoelastic nanofluid layer under the influence of a magnetic field. In the linear stability analysis, the stationary and oscillatory modes of convection are obtained for various controlling parameters using the normal mode technique. Both Nusselt and Sherwood numbers are calculated after employing the minimal truncated Fourier series to steady and unsteady state. The main findings conclude that rotation and strain retardation parameter increase the value of the critical Rayleigh number in the neutral stability curve which delays the onset of convection in the nanofluid layer while the stress relaxation parameter enhances the convection. The magnetic field stabilizes the system for low values of the Taylor number (rotation) but an inverse trend is observed for high Taylor number. Both Nusselt and Sherwood numbers initially oscillate with time until the steady state prevails and they decrease with both Chandrasekhar and Taylor numbers. The magnitude of the streamlines and the contours of both isotherms and iso-nanohalines concentrate near the boundaries for large values of Ra, indicating an increase in convection.

  9. Some remarks on the influence of temperature-variations, non-linearities, repeatability and ageing on modal-analysis for structural health monitoring of real bridges

    Directory of Open Access Journals (Sweden)

    Maas Stefan

    2015-01-01

    Full Text Available Structural Health Monitoring (SHM intends to identify damage by changes of characteristics as for instance the modal parameters. The eigenfrequencies, mode-shapes and damping-values are either directly used as damage indicators or the changes of derived parameters are analysed, such as e.g. flexibilities or updated finite element models. One common way is a continuous monitoring under environmental excitation forces, such as wind or traffic, i.e. the so-called output-only modal analysis. Alternatively, a forced measured external excitation in distinct time-intervals may be used for input-output modal analysis. Both methods are limited by the precision or the repeatability under real-life conditions at site. The paper will summarize several field tests of artificially step-by-step damaged bridges prior to their final demolishment and it will show the changes of eigenfrequencies due to induced artificial damage. Additionally, some results of a monitoring campaign of a healthy bridge in Luxembourg are presented. Reinforced concrete shows non-linear behaviour in the sense that modal parameters depend on the excitation force amplitude, i.e. higher forces lead often to lower eigenfrequencies than smaller forces. Furthermore, the temperature of real bridges is neither constant in space nor in time, while for instance the stiffness of asphalt is strongly dependant on it. Finally, ageing as such can also change a bridge’s stiffness and its modal parameters, e.g. because creep and shrinkage of concrete or ageing of elastomeric bearing pads influence their modulus of elasticity. These effects cannot be considered as damage, though they influence the measurement of modal parameters and hinder damage detection.

  10. Investigations on the adsorbents for uremic middle molecular toxins (II) —Influences of crosslinking agent chain length on the adsorption capacities of crosslinked chitosan adsorbents

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Chitosan resins, which clinically served as adsorbents in hemoperfusion therapy, were prepared with reversed-phase suspension methodology using three differently structured crosslinking agents, methanal, glyoxal and glutaraldehyde. And the glyoxal and glutaraldehyde crosslinked chitosan resins were reduced with NaBH4 afterwards. By analyzing the results from FTIR and SEM, it was found that the reduction treatment to the adsorbents efficiently improved the chemical stability of these chitosan resins, and the shifts in crosslinking agents exerted influences over the morphologies of the adsorbents obviously. After being put to use in the adsorption tests upon some model uremic middle molecular toxins and BSA in vitro, all three adsorbents demon- strated a fairly realistic adsorption capability to the model toxins but little to BSA. And the adsorp- tion process reached the equilibrium in a clinically qualified short time. But the adsorption capaci- ties of these adsorbents to the model toxins were quite different. It had been found that with the growing of fatty chain length of crosslinking agent, these adsorbents showed a gradually increased adsorption capacity to the model toxins, and the glutaraldehyde crosslinked chitosan resin be- haved best.

  11. The change in cholesterol content of long chain fatty acid egg during processing and its influence to the Rattus norvegicus L. blood cholesterol content

    Directory of Open Access Journals (Sweden)

    Dini Hardini

    2006-12-01

    Full Text Available Egg containing long chain unsaturated fatty acids is a functional food, because it is highly nutritious and could prevent diseases, (omega 3 and 6 such as coronary heart attack. The research was aimed to measure the change of egg cholesterol content during proceesing: frying, oiless frying and boiling and their influence to the blood plasma cholesterol of normal and hypercholesterolemia rat. Seven treatments of egg yolk were frying at 170°C for 3 min (welldone = GM, and 1min (half medium fried = GSM using deep fryer , oilless frying at 70°C for10 min (fried = TM, and 6 min (half fried = TSM using Teflon pan, and boiling at 100°C for 10’ (boiled = RM dan 4 min (half boiled = RSM using pan provided with thermoregulator and a fresh omega egg as a control. The Completely randomized design was apllied for 4 weeks research period. The data from different treatments were analyzed by Orthogonal Contrast. Fifty 2 months old male rats Rattus norvegicus L. separated in 2 groups; normal and hypercholesterolemia (blood cholesterol > 200 mg dl-1. The rats were placed in individual cage, fed 15 g h-1 day-1 and water drinking ad libitum. The ration was composed of 90% basal commercial feed BR II and 10% egg yolk was given to each animal at 20% of live weight. Factorial 2 x 7 of completely randomized design was applied. The data were analyzed by ANOVA and Duncan’s Multiple Range Test. Processsing method of egg affected to cholesterol content of egg, The lowest and the highest cholesterol contents were observed in TSM (0.30 g/100g and GM (0.37 g/100g, respectively. Biological test using Rattus norvegicus L rat showed that either fresh and processed long chain fatty acid egg decreased plasma cholesterol. The highest and the lowest decreases of cholesterol content were found in the group consumed RSM (8.64% and GM (1.77% for normal rat; and control (46.3% followed by RSM (44.53% and GM (24.86%, respectively. To maintain normal cholesterol and decrease

  12. Nonlinear optics

    CERN Document Server

    Boyd, Robert W

    2013-01-01

    Nonlinear Optics is an advanced textbook for courses dealing with nonlinear optics, quantum electronics, laser physics, contemporary and quantum optics, and electrooptics. Its pedagogical emphasis is on fundamentals rather than particular, transitory applications. As a result, this textbook will have lasting appeal to a wide audience of electrical engineering, physics, and optics students, as well as those in related fields such as materials science and chemistry.Key Features* The origin of optical nonlinearities, including dependence on the polarization of light* A detailed treatment of the q

  13. Nonlinear Reconstruction

    CERN Document Server

    Zhu, Hong-Ming; Pen, Ue-Li; Chen, Xuelei; Yu, Hao-Ran

    2016-01-01

    We present a direct approach to non-parametrically reconstruct the linear density field from an observed non-linear map. We solve for the unique displacement potential consistent with the non-linear density and positive definite coordinate transformation using a multigrid algorithm. We show that we recover the linear initial conditions up to $k\\sim 1\\ h/\\mathrm{Mpc}$ with minimal computational cost. This reconstruction approach generalizes the linear displacement theory to fully non-linear fields, potentially substantially expanding the BAO and RSD information content of dense large scale structure surveys, including for example SDSS main sample and 21cm intensity mapping.

  14. SUPPLY CHAIN MANAGEMENT – KEY FACTORS

    OpenAIRE

    Magdalena Daniela DINU

    2014-01-01

    This paper exposes Supply Chain Management by its key factors. Briefly, where the Supply Chain Management is treated as strategic part of a company then maintaining both control and influence throughout the entire supply chain are key factors and critical to success. On the other hand, finding the right partner to manage the non-strategic Supply Chains would be another key factor too. To define the most important key factors within Supply Chain Management means a deeply understanding of bot...

  15. Nonlinear optimization

    CERN Document Server

    Ruszczynski, Andrzej

    2011-01-01

    Optimization is one of the most important areas of modern applied mathematics, with applications in fields from engineering and economics to finance, statistics, management science, and medicine. While many books have addressed its various aspects, Nonlinear Optimization is the first comprehensive treatment that will allow graduate students and researchers to understand its modern ideas, principles, and methods within a reasonable time, but without sacrificing mathematical precision. Andrzej Ruszczynski, a leading expert in the optimization of nonlinear stochastic systems, integrates t

  16. Nonlinear Analysis of Buckling

    Directory of Open Access Journals (Sweden)

    Psotný Martin

    2014-06-01

    Full Text Available The stability analysis of slender web loaded in compression was presented. To solve this problem, a specialized computer program based on FEM was created. The nonlinear finite element method equations were derived from the variational principle of minimum of potential energy. To obtain the nonlinear equilibrium paths, the Newton-Raphson iteration algorithm was used. Corresponding levels of the total potential energy were defined. The peculiarities of the effects of the initial imperfections were investigated. Special attention was focused on the influence of imperfections on the post-critical buckling mode. The stable and unstable paths of the nonlinear solution were separated. Obtained results were compared with those gained using ANSYS system.

  17. Influencing Factors Analysis of Green Supply Chain Based on the ISM%基于解释结构模型法的绿色供应链影响因素分析

    Institute of Scientific and Technical Information of China (English)

    刘玫

    2011-01-01

    在阐述绿色供应链研究现状的基础上,利用解释结构模型找出影响绿色供应链实施效果各因素之间的层级关系,并提出提高实施效果的对策和措施,以期为科学系统地发展绿色供应链提供一些启示.%Based on the research status of green supply chain, the relationship among the influencing factors of the green supply chain has been found and some suggestions for improving implement have been put forward in this paper by using the Interpretive Structure Modeling (ISM) so that some enlightenment for scientific and systematic development of green supply chain can be provided.

  18. Influence of polarization state, baud rate and PMD on non-linear impairments in WDM systems with mixed PM (D)QPSK and OOK channels.

    Science.gov (United States)

    Chughtai, Mohsan Niaz; Forzati, Marco; Mårtensson, Jonas; Rafique, Danish

    2012-03-26

    In this paper we numerically investigate nonlinear impairments in a WDM system with mixed PM (D)QPSK and OOK channels. First we analyze the dependence of XPM and XPolM on SOP and baud rate in absence of PMD. In this case we find that the nonlinear impairments are highly dependent on relative SOP between the PM (D)QPSK and neighbouring OOK channels. The dependence on relative SOP is more pronounced in differential detection than in coherent detection. However, with increasing values of PMD this dependence decreases, and non-linear tolerance improves.

  19. Nonlinear signal mixing in a three-terminal molecular wire

    Science.gov (United States)

    Liu, Christopher; Speyer, Joe; Ovchinnikov, Igor V.; Neuhauser, Daniel

    2007-01-01

    The authors study the electronic response of two simple molecular devices to a bichromatic field, where the device acts as a mixer. Two closely related model systems are considered: one is a benzene molecule and the other is a single grapheme sheet, and in both cases the systems are connected to three polyacetylene chains. The electronic response to the dichromatic alternating electric fields is studied by following the electron density fluctuation along the chain lengths. In both cases the electron transfer follows the field frequency at low electric fields. At higher amplitude, a significant amount of nonlinear mixing resulting in new combinations of the input frequencies is found in the spectrum. The influence of gating on the output frequencies is also shown.

  20. Bayesian system identification of a nonlinear dynamical system using a novel variant of Simulated Annealing

    Science.gov (United States)

    Green, P. L.

    2015-02-01

    This work details the Bayesian identification of a nonlinear dynamical system using a novel MCMC algorithm: 'Data Annealing'. Data Annealing is similar to Simulated Annealing in that it allows the Markov chain to easily clear 'local traps' in the target distribution. To achieve this, training data is fed into the likelihood such that its influence over the posterior is introduced gradually - this allows the annealing procedure to be conducted with reduced computational expense. Additionally, Data Annealing uses a proposal distribution which allows it to conduct a local search accompanied by occasional long jumps, reducing the chance that it will become stuck in local traps. Here it is used to identify an experimental nonlinear system. The resulting Markov chains are used to approximate the covariance matrices of the parameters in a set of competing models before the issue of model selection is tackled using the Deviance Information Criterion.

  1. Nonlinear channelizer

    Science.gov (United States)

    In, Visarath; Longhini, Patrick; Kho, Andy; Neff, Joseph D.; Leung, Daniel; Liu, Norman; Meadows, Brian K.; Gordon, Frank; Bulsara, Adi R.; Palacios, Antonio

    2012-12-01

    The nonlinear channelizer is an integrated circuit made up of large parallel arrays of analog nonlinear oscillators, which, collectively, serve as a broad-spectrum analyzer with the ability to receive complex signals containing multiple frequencies and instantaneously lock-on or respond to a received signal in a few oscillation cycles. The concept is based on the generation of internal oscillations in coupled nonlinear systems that do not normally oscillate in the absence of coupling. In particular, the system consists of unidirectionally coupled bistable nonlinear elements, where the frequency and other dynamical characteristics of the emergent oscillations depend on the system's internal parameters and the received signal. These properties and characteristics are being employed to develop a system capable of locking onto any arbitrary input radio frequency signal. The system is efficient by eliminating the need for high-speed, high-accuracy analog-to-digital converters, and compact by making use of nonlinear coupled systems to act as a channelizer (frequency binning and channeling), a low noise amplifier, and a frequency down-converter in a single step which, in turn, will reduce the size, weight, power, and cost of the entire communication system. This paper covers the theory, numerical simulations, and some engineering details that validate the concept at the frequency band of 1-4 GHz.

  2. Effect of Hydrogen Bonding on Linear and Nonlinear Rheology of Entangled Polymer Melts

    DEFF Research Database (Denmark)

    Shabbir, Aamir; Goldansaz, Hadi; Hassager, Ole

    2015-01-01

    to AA along the backbone. Assuming superposition holds and subtracting out the linear chain rheology from LVE, the hydrogen bonding contribution to LVE is exposed. Hydrogen bonding affects linear viscoelasticity at frequencies below the inverse reptation time. More specifically, the presence of hydrogen...... bonds causes G′ and G″ as a function of frequency to shift to a power law scaling of 0.5. Furthermore, the magnitude of G′ and G″ scales linearly with the number of hydrogen-bonding groups. The nonlinear extensional rheology shows extreme strain hardening. The magnitude of extensional stress has...... a strongly nonlinear dependence on the number of hydrogenbonding groups. These results are aimed at uncovering the molecular influence of hydrogen bonding on linear and nonlinear rheology to aid future molecular synthesis and model development....

  3. The influence of post-growth annealing on the optical properties of InAs quantum dot chains grown on pre-patterned GaAs(100).

    Science.gov (United States)

    Hakkarainen, T V; Polojärvi, V; Schramm, A; Tommila, J; Guina, M

    2012-03-23

    We report on the effect of post-growth thermal annealing of [011]- ,[011(-)]-, and [010]-oriented quantum dot chains grown by molecular beam epitaxy on GaAs(100) substrates patterned by UV-nanoimprint lithography. We show that the quantum dot chains experience a blueshift of the photoluminescence energy, spectral narrowing, and a reduction of the intersubband energy separation during annealing. The photoluminescence blueshift is more rapid for the quantum dot chains than for self-assembled quantum dots that were used as a reference. Furthermore, we studied polarization resolved photoluminescence and observed that annealing reduces the intrinsic optical anisotropy of the quantum dot chains and the self-assembled quantum dots.

  4. Analysis on the Influence Factors of the Implementation of the Sensitive Supply Chain Based on ISM%基于ISM的精敏供应链实施的影响因素分析

    Institute of Scientific and Technical Information of China (English)

    裴小兵; 刘孟英

    2015-01-01

    针对精敏供应链实施效果不明显的现象,文章找出了影响其实施的因素,建立精敏供应链实施影响因素关系的ISM模型,并运用ISM模型对各影响因素进行分层解释,分析各影响因素之间的内在关系,为企业降低成本,提高经济绩效和客户满意度,以及更好的实施精敏供应链提供指导。%In view of the phenomenon that the effect of sensitive supply chain is not obvious, this article found out the factors that affect its implementation, built an ISM model of the relationship of the influence factors of the sensitive supply chain implementation and used the ISM model for layered interpretation of the various influence factors to analyze the intrinsic relations between the influence factors. It can provide guidance for enterprises to reduce costs, improve economic performance and customer satisfaction, and better implement the sensitive supply chain.

  5. Nonlinear Waves in Complex Systems

    DEFF Research Database (Denmark)

    2007-01-01

    The study of nonlinear waves has exploded due to the combination of analysis and computations, since the discovery of the famous recurrence phenomenon on a chain of nonlinearly coupled oscillators by Fermi-Pasta-Ulam fifty years ago. More than the discovery of new integrable equations, it is the ...... in Fourier space and equipartition, the role of inhomogeneities and complex geometry and the importance of coupled systems.......The study of nonlinear waves has exploded due to the combination of analysis and computations, since the discovery of the famous recurrence phenomenon on a chain of nonlinearly coupled oscillators by Fermi-Pasta-Ulam fifty years ago. More than the discovery of new integrable equations......, it is the universality and robustness of the main models with respect to perturbations that developped the field. This is true for both continuous and discrete equations. In this volume we keep this broad view and draw new perspectives for nonlinear waves in complex systems. In particular we address energy flow...

  6. Chain Gang

    Science.gov (United States)

    2006-01-01

    6 August 2006 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a chain of clustered and battered craters. These were formed by secondary impact. That is, somewhere to the south (beyond the bottom of this image), a large impact crater formed. When this occurred, material ejected from the crater was thrown tens to hundreds of kilometers away. This material then impacted the martian surface, forming clusters and chains of smaller craters. Location near: 15.8oN, 35.6oW Image width: 3 km (1.9 mi) Illumination from: upper left Season: Northern Spring

  7. Nonlinear dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Turchetti, G. (Bologna Univ. (Italy). Dipt. di Fisica)

    1989-01-01

    Research in nonlinear dynamics is rapidly expanding and its range of applications is extending beyond the traditional areas of science where it was first developed. Indeed while linear analysis and modelling, which has been very successful in mathematical physics and engineering, has become a mature science, many elementary phenomena of intrinsic nonlinear nature were recently experimentally detected and investigated, suggesting new theoretical work. Complex systems, as turbulent fluids, were known to be governed by intrinsically nonlinear laws since a long time ago, but received purely phenomenological descriptions. The pioneering works of Boltzmann and Poincare, probably because of their intrinsic difficulty, did not have a revolutionary impact at their time; it is only very recently that their message is reaching a significant number of mathematicians and physicists. Certainly the development of computers and computer graphics played an important role in developing geometric intuition of complex phenomena through simple numerical experiments, while a new mathematical framework to understand them was being developed.

  8. Influence of electron beam irradiation on nonlinear optical properties of Al doped ZnO thin films for optoelectronic device applications in the cw laser regime

    Science.gov (United States)

    Antony, Albin; Pramodini, S.; Poornesh, P.; Kityk, I. V.; Fedorchuk, A. O.; Sanjeev, Ganesh

    2016-12-01

    We present the studies on third-order nonlinear optical properties of Al doped ZnO thin films irradiated with electron beam at different dose rate. Al doped ZnO thin films were deposited on a glass substrate by spray pyrolysis deposition technique. The thin films were irradiated using the 8 MeV electron beam from microtron ranging from 1 kG y to 5 kG y. Nonlinear optical studies were carried out by employing the single beam Z-scan technique to determine the sign and magnitude of absorptive and refractive nonlinearities of the irradiated thin films. Continuous wave He-Ne laser operating at 633 nm was used as source of excitation. The open aperture Z-scan measurements indicated the sample displays reverse saturable absorption (RSA) process. The negative sign of the nonlinear refractive index n2 was noted from the closed aperture Z-scan measurements indicates, the films exhibit self-defocusing property due to thermal nonlinearity. The third-order nonlinear optical susceptibility χ(3) varies from 8.17 × 10-5 esu to 1.39 × 10-3 esu with increase in electron beam irradiation. The present study reveals that the irradiation of electron beam leads to significant changes in the third-order optical nonlinearity. Al doped ZnO displays good optical power handling capability with optical clamping of about ∼5 mW. The irradiation study endorses that the Al doped ZnO under investigation is a promising candidate photonic device applications such as all-optical power limiting.

  9. Influence of the aircraft crash induced local nonlinearities on the overall dynamic response of a RC structure through a parametric study

    Energy Technology Data Exchange (ETDEWEB)

    Rouzaud, C., E-mail: crouzaud@adm.estp.fr [LMT (ENS Cachan, CNRS, Université Paris Saclay) 61 avenue du Président Wilson, 94235 Cachan (France); Université Paris-Est, Institut de Recherche en Constructibilité, ESTP 28 avenue du Président Wilson, 94230 Cachan (France); AREVA, 10 rue Juliette Récamier, 69006 Lyon (France); Gatuingt, F. [LMT (ENS Cachan, CNRS, Université Paris Saclay) 61 avenue du Président Wilson, 94235 Cachan (France); Hervé, G. [Université Paris-Est, Institut de Recherche en Constructibilité, ESTP 28 avenue du Président Wilson, 94230 Cachan (France); Moussallam, N. [AREVA, 10 rue Juliette Récamier, 69006 Lyon (France); Dorival, O. [Icam, Site de Toulouse, 75 avenue de Grande-Bretagne, 31076 Toulouse Cedex 3 (France); Université de Toulouse, Institut Clément Ader (ICA), INSA, UPS, Mines Albi, ISAE 135 avenue de Rangueil, 31077 Toulouse Cedex (France)

    2016-03-15

    Highlights: • Structures could resist to the induced accelerations which they might undergo. • The characterization of non-linearities in the signal of an aircraft impact. • The non linear impact area are studied through a sensitivity analysis. • This analysis should allow to achieve a link between aircraft impact parameters. - Abstract: In the process of nuclear power plant design, the safety of structures is an important aspect. Civil engineering structures have to resist the accelerations induced by, for example, seismic loads or shaking loads resulting from the aircraft impact. This is even more important for the in-structures equipments that have also to be qualified against the vibrations generated by this kind of hazards. In the case of aircraft crash, as a large variety of scenarios has to be envisaged, it is necessary to use methods that are less CPU-time consuming and that consider appropriately the nonlinearities. The analysis presented in this paper deals with the problem of the characterization of nonlinearities (damaged area, transmitted force) in the response of a structure subjected to an aircraft impact. The purpose of our study is part of the development of a new decoupled nonlinear and elastic way for calculating the shaking of structures following an aircraft impact which could be very numerically costly if studied with classical finite element methods. The aim is to identify which parameters control the dimensions of the nonlinear zone and so will have a direct impact on the induced vibrations. In a design context, several load cases (and simulations) are analyzed in order to consider a wide range of impact (different loading surfaces, momentum) and data sets of the target (thickness, reinforcements). In this work, the nonlinear area generated by the impact is localized and studied through a parametric analysis associated with a sensitivity analysis to identify the boundaries between the elastic domain and this nonlinear area.

  10. Subcritical localization in the discrete nonlinear Schrödinger equation with arbitrary power nonlinearity

    DEFF Research Database (Denmark)

    Bang, O.; Juul Rasmussen, J.; Christiansen, P.L.

    1994-01-01

    Discretizing the continuous nonlinear Schrodinger equation with arbitrary power nonlinearity influences the time evolution of its ground state solitary solution. In the subcritical case, for grid resolutions above a certain transition value, depending on the degree of nonlinearity, the solution w...

  11. Design of a medical non-linear drilling device: the influence of twist and wear on the fatigue behaviour of NiTi wires subjected to bending rotation

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, M.; Frenzel, J.; Eggeler, G. [Lehrstuhl Werkstoffwissenschaften, Ruhr-Universitaet Bochum, 44780 Bochum (Germany); Richter, J.; Groenemeyer, D. [Institut fuer Mikrotherapie, Universitaet Witten/ Herdecke (Germany)

    2004-05-01

    This paper considers fundamental and experimental aspects associated with the engineering design of a medical, non-linear drilling device which exploits shape memory pseudoelasticity of NiTi wires. For this application it is important that the NiTi wires have a good fatigue resistance. This is why the present authors have previously determined the influence of various parameters on cyclic life, crack growth and stress state of pseudoelastic wires subjected to bending rotation fatigue. The actual drilling device has to withstand twist in addition to bending rotation because the free rotation is constrained by friction between the drill head and the bone material. In addition, friction between the wire and a NiTi guiding tube results in wear and this may well promote fatigue crack nucleation. In this paper, we explain the function of the medical drill. We then report results on the effect of the additional parameters (1) twist and (2) wear on the fatigue life of thin pseudoelastic NiTi wires. We finally discuss the implications of our experimental results for the design process of the medical drilling device. (Abstract Copyright [2004], Wiley Periodicals, Inc.) [German] Dieser Artikel behandelt Voruntersuchungen fuer die Entwicklung eines medizinischen nicht-linearen Bohrsystems. Aus materialwissenschaftlicher Sicht spielt die Ermuedung der mechanischen Komponenten aus NiTi eine wichtige Rolle. Die Autoren haben in bisherigen Studien den Einfluss verschiedener Parameter auf Lebensdauer, Risswachstum und Spannungszustand in pseudoelastischen Draehten waehrend Umlaufbiegung ermittelt. Der Draht im eigentlichen Bohrsystem wird jedoch nicht ausschliesslich durch reine Umlaufbiegung, sondern zusaetzlich durch eine Verdrillung aufgrund der Reibung zwischen Bohrkopf und Knochengewebe, belastet. Ausserdem bewirkt die Reibung zwischen dem Draht und einem Fuehrungsrohr aus NiTi Verschleiss; diese Materialschaedigung stellt einen weiteren Mechanismus zur Risseinleitung dar. In

  12. Nonlinear airship aeroelasticity

    Science.gov (United States)

    Bessert, N.; Frederich, O.

    2005-12-01

    The aeroelastic derivatives for today's aircraft are calculated in the concept phase using a standard procedure. This scheme has to be extended for large airships, due to various nonlinearities in structural and aerodynamic behaviour. In general, the structural model of an airship is physically as well as geometrically nonlinear. The main sources of nonlinearity are large deformations and the nonlinear material behaviour of membranes. The aerodynamic solution is also included in the nonlinear problem, because the deformed airship influences the surrounding flow. Due to these nonlinearities, the aeroelastic problem for airships can only be solved by an iterative procedure. As one possibility, the coupled aerodynamic and structural dynamic problem was handled using linked standard solvers. On the structural side, the Finite-Element program package ABAQUS was extended with an interface to the aerodynamic solver VSAERO. VSAERO is based on the aerodynamic panel method using potential flow theory. The equilibrium of the internal structural and the external aerodynamic forces leads to the structural response and a trimmed flight state for the specified flight conditions (e.g. speed, altitude). The application of small perturbations around a trimmed state produces reaction forces and moments. These constraint forces are then transferred into translational and rotational acceleration fields by performing an inertia relief analysis of the disturbed structural model. The change between the trimmed flight state and the disturbed one yields the respective aeroelastic derivatives. By including the calculated derivatives in the linearised equation of motion system, it is possible to judge the stability and controllability of the investigated airship.

  13. Nonlinear Systems.

    Science.gov (United States)

    Seider, Warren D.; Ungar, Lyle H.

    1987-01-01

    Describes a course in nonlinear mathematics courses offered at the University of Pennsylvania which provides an opportunity for students to examine the complex solution spaces that chemical engineers encounter. Topics include modeling many chemical processes, especially those involving reaction and diffusion, auto catalytic reactions, phase…

  14. Nonlinear phononics using atomically thin membranes

    Science.gov (United States)

    Midtvedt, Daniel; Isacsson, Andreas; Croy, Alexander

    2014-09-01

    Phononic crystals and acoustic metamaterials are used to tailor phonon and sound propagation properties by utilizing artificial, periodic structures. Analogous to photonic crystals, phononic band gaps can be created, which influence wave propagation and, more generally, allow engineering of the acoustic properties of a system. Beyond that, nonlinear phenomena in periodic structures have been extensively studied in photonic crystals and atomic Bose-Einstein condensates in optical lattices. However, creating nonlinear phononic crystals or nonlinear acoustic metamaterials remains challenging and only few examples have been demonstrated. Here, we show that atomically thin and periodically pinned membranes support coupled localized modes with nonlinear dynamics. The proposed system provides a platform for investigating nonlinear phononics.

  15. The effect of chain flexibility and chain mobility on radiation crosslinking of polymers

    Energy Technology Data Exchange (ETDEWEB)

    Jia Zhen, Sun

    2001-07-01

    Radiation crosslinking of polymers mainly depends on the structure of polymer chain. The flexibility and mobility of chain directly influence the possibility of the reactive radicals recombination. Flexible chain is easier to crosslink than rigid-chain polymer. The latter must be crosslinked at high temperature, as most polymers can only crosslink above their melting point. Structural effect also influences the mechanism of radiation crosslinking of polymers. We find from the results in literature and in our laboratory that, the flexibility chain polymer mainly crosslinked with H type, but the rigid chain polymer mainly crosslinked with Y type. (author)

  16. The effect of chain flexibility and chain mobility on radiation crosslinking of polymers

    Science.gov (United States)

    Jia Zhen, Sun

    2001-01-01

    Radiation crosslinking of polymers mainly depends on the structure of polymer chain. The flexibility and mobility of chain directly influence the possibility of the reactive radicals recombination. Flexible chain is easier to crosslink than rigid-chain polymer. The latter must be crosslinked at high temperature, as most polymers can only crosslink above their melting point. Structural effect also influences the mechanism of radiation crosslinking of polymers. We find from the results in literature and in our laboratory that, the flexibility chain polymer mainly crosslinked with H type, but the rigid chain polymer mainly crosslinked with Y type.

  17. Weakly nonlinear analysis of Rayleigh-Bénard convection in a non-Newtonian fluid between plates of finite conductivity: Influence of shear-thinning effects.

    Science.gov (United States)

    Bouteraa, Mondher; Nouar, Chérif

    2015-12-01

    Finite-amplitude thermal convection in a shear-thinning fluid layer between two horizontal plates of finite thermal conductivity is considered. Weakly nonlinear analysis is adopted as a first approach to investigate nonlinear effects. The rheological behavior of the fluid is described by the Carreau model. As a first step, the critical conditions for the onset of convection are computed as a function of the ratio ξ of the thermal conductivity of the plates to the thermal conductivity of the fluid. In agreement with the literature, the critical Rayleigh number Ra(c) and the critical wave number k(c) decrease from 1708 to 720 and from 3.11 to 0, when ξ decreases from infinity to zero. In the second step, the critical value α(c) of the shear-thinning degree above which the bifurcation becomes subcritical is determined. It is shown that α(c) increases with decreasing ξ. The stability of rolls and squares is then investigated as a function of ξ and the rheological parameters. The limit value ξ(c), below which squares are stable, decreases with increasing shear-thinning effects. This is related to the fact that shear-thinning effects increase the nonlinear interactions between sets of rolls that constitute the square patterns [M. Bouteraa et al., J. Fluid Mech. 767, 696 (2015)]. For a significant deviation from the critical conditions, nonlinear convection terms and nonlinear viscous terms become stronger, leading to a further diminution of ξ(c). The dependency of the heat transfer on ξ and the rheological parameters is reported. It is consistent with the maximum heat transfer principle. Finally, the flow structure and the viscosity field are represented for weakly and highly conducting plates.

  18. Liposome encapsulation of lipophilic N-alkyl-propanediamine platinum complexes: impact on their cytotoxic activity and influence of the carbon chain length

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Heveline; Fontes, Ana Paula S. [Universidade Federal de Juiz de Fora (UFJF), MG (Brazil). Dept. de Quimica; Lopes, Miriam Teresa P. [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Farmacologia; Frezard, Frederic, E-mail: frezard@icb.ufmg.b [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Fisiologia e Biofisica

    2010-07-01

    Antitumor platinum(II) complexes derived from N-alkyl-propanediamine differing in the length of their carbon chain (C8, C10, C12 and C14) were incorporated in liposomes and the cytotoxic activity of these formulations was evaluated against tumor (A{sub 549}, MDA-MB-231, B16-F1 and B16-F10) and non-tumor (BHK-21 and CHO) cell lines. Stable and monodisperse liposome suspensions incorporating the platinum complexes were obtained from the lipid composition consisting of distearoyl-sn-glycero-3-phosphocholine, cholesterol and 1,2-distearoyl-sn-glycero- 3-phosphoethanolamine-N-(methoxy(polyethylene glycol)-2000) at 5:3:0.3 molar ratio. The entrapment efficiency (EE%) of the platinum complexes in liposomes increased with the carbon chain length. EE% was higher than 80% in C12- and C14-derivatives. The effect of liposome encapsulation on the cytotoxic activity of the complexes was found to depend on the carbon chain length. These data indicate that the highest drug bioavailability from liposome formulations was achieved with the complex showing intermediate carbon chain length and partition between the liposome membrane and aqueous phase. (author)

  19. Theoretical investigation on the kinetics and mechanisms of hydroxyl radical-induced transformation of parabens and its consequences for toxicity: Influence of alkyl-chain length.

    Science.gov (United States)

    Gao, Yanpeng; Ji, Yuemeng; Li, Guiying; An, Taicheng

    2016-03-15

    As emerging organic contaminants (EOCs), the ubiquitous presence of preservative parabens in water causes a serious environmental concern. Hydroxyl radical ((•)OH) is a strong oxidant that can degrade EOCs through photochemistry in surface water environments as well as in advanced oxidation processes (AOPs). To better understand the degradation mechanisms, kinetics, and products toxicity of the preservative parabens in aquatic environments and AOPs, the (•)OH-initiated degradation reactions of the four parabens were investigated systematically using a computational approach. The four studied parabens with increase of alkyl-chain length were methylparaben (MPB), ethylparaben (EPB), propylparaben (PPB), and dibutylparaben (BPB). Results showed that the four parabens can be initially attacked by (•)OH through (•)OH-addition and H-abstraction routes. The (•)OH-addition route was more important for the degradation of shorter alkyl-chain parabens like MPB and EPB, while the H-abstraction route was predominant for the degradation of parabens with longer alkyl-chain for example PPB and BPB. In assessing the aquatic toxicity of parabens and their degradation products using the model calculations, the products of the (•)OH-addition route were found to be more toxic to green algae than original parabens. Although all degradation products were less toxic to daphnia and fish than corresponding parental parabens, they could be still harmful to these aquatic organisms. Furthermore, as alkyl-chain length increased, the ecotoxicity of parabens and their degradation products was found to be also increased.

  20. Influence of acid chain length on the properties of TiO2 prepared by sol-gel method and LC-MS studies of methylene blue photodegradation.

    Science.gov (United States)

    Bakre, Pratibha V; Volvoikar, Prajesh S; Vernekar, Amit A; Tilve, S G

    2016-07-15

    Nano-sized titanium dioxide photocatalysts were synthesized by hybrid hydrolytic nonhydrolytic sol-gel method using aliphatic organic acid templates to study the effect of chain length on their properties. X-ray diffraction pattern indicated crystalline anatase phase. The Barrett-Joyner-Halenda surface area measurement gave surface area ranging from 98.4 to 205.5m(2)/g and was found to be dependent on the chain length of the aliphatic acid. The longer chain acids rendered the material with high surface area. The organic acids acted as bidentate ligand and a surfactant in controlling the size and the mesoporosity. The size of the TiO2 nanoparticulate was found to be in the range of 10-18nm. The catalyst prepared by employing long chain acids octanoic acid and palmitic acid had smaller size, narrow pore radius, higher surface area and showed better photocatalytic activity than the commercially available Degussa P25 catalyst for the degradation of methylene blue dye. A new intermediate was identified by tandem liquid chromatography mass spectrometry studies during the degradation of methylene blue solution.

  1. Long-chain polyunsaturated fatty acids (LCPUFA) from genesis to senescence: the influence of LCPUFA on neural development, aging, and neurodegeneration.

    NARCIS (Netherlands)

    Janssen, C.I.F.; Kiliaan, A.J.

    2014-01-01

    Many clinical and animal studies demonstrate the importance of long-chain polyunsaturated fatty acids (LCPUFA) in neural development and neurodegeneration. This review will focus on involvement of LCPUFA from genesis to senescence. The LCPUFA docosahexaenoic acid and arachidonic acid are important c

  2. Nonlinear PDEs

    OpenAIRE

    2015-01-01

    From the Back Cover: The emphasis throughout the present volume is on the practical application of theoretical mathematical models helping to unravel the underlying mechanisms involved in processes from mathematical physics and biosciences. It has been conceived as a unique collection of abstract methods dealing especially with nonlinear partial differential equations (either stationary or evolutionary) that are applied to understand concrete processes involving some important applications re...

  3. Geomorphological evidence of the influence of pre-volcanic basement structure on emplacement and deformation of volcanic edifices at the Cofre de Perote Pico de Orizaba chain and implications for avalanche generation

    Science.gov (United States)

    Concha-Dimas, Aline; Cerca, Mariano; Rodríguez, Sergio R.; Watters, Robert J.

    2005-12-01

    Pre-volcanic structure of the basement influences volcanism distribution and avalanche generation in volcanic edifices. Therefore, systematic studies of basement structure below volcanic chains are necessary to understand the deformation effects observed in the surface and vice versa. Based on a compilation of pre-existing data, interpretation of aerial photographs and satellite images, and a collection of structural data we analyzed morphological and structural features of the Cofre de Perote-Pico de Orizaba (CP-PO) volcanic chain and its basement. We have identified three sets of regional lineaments that are related to basement trends. (1) NW 55° SE fractures are parallel to anticline folds observed in Cretaceous rocks that originated during Laramide shortening. These folds present an abrupt morphology observed only in the eastern flank but that is likely to continue below the volcanic chain. (2) NE 55° SW fractures are parallel to normal faults at the basement. We infer that these basement faults confine the CP-PO chain within a stepped graben with a total normal displacement of about 400 m. These faults have been active through time since they have affected volcanic deposits and induced the emplacement of monogenetic vents. Notably, lineaments of monogenetic vents concentrate where the basement is relatively shallow. (3) Another set of faults, oriented N-S, has been observed affecting the scarce basement outcrops at the western flank of the chain covered by lacustrine deposits. Lineaments measured in the volcanic edifice of Pico de Orizaba correlate with the regional trends. In particular, the NE 55° SW alignment of monogenetic vents and fractures at Pico de Orizaba suggest that the same dike trend exists within the volcanic edifice. A normal fault with similar orientation was documented at the NE continuation of an alignment crossing the volcanic edifice along the Jamapa canyon. In the absence of magmatic activity related to collapses, the displacement of

  4. Empirical Research on the Influencing Factors of Information Transmission Efficiency of Supply Chain Information Ecological Chain%供应链信息生态链信息传递效率影响因素的实证研究

    Institute of Scientific and Technical Information of China (English)

    霍明奎; 张向先; 李爽

    2016-01-01

    [目的/意义]为了更深入地把握供应链信息生态链的发展规律和运行机制,同时为供应链信息管理提供更具实践意义的帮助。[方法/过程]在理论分析供应链信息生态链信息传递内涵的基础上,归纳了5项信息传递效率指标,并提出21项关于影响因素的研究假设,调查并整理了247份有效数据,利用结构方程模型进行实证检验。[结果/结论]研究表明信息化标准程度、信息发送能力和发送意愿、信息接收意愿和接收能力与供应链信息生态链的信息传递效率正相关;关系强度、信息势差、网络密度、网络中心度与信息发送意愿和信息接收意愿正相关;信息生态位重叠度与信息发送意愿和信息接收意愿负相关;关系强度、网络中心度、网络范围与信息发送能力和信息接收能力正相关。%Purpose/Significance] In order to grasp the law of supply chain information ecological chain development more deeply and provide more practical help to the information management of supply chain, [ Method/Process] this article summed up 5 index, put for-ward 21 hypotheses, sorted out 247 copies of the survey data, and used structural equation model to carry out an empirical test. [ Result/Conclusion] The results show that the degree of informatization standards, the ability and the willingness to send information, the ability and willingness to receive information are positively related to the information transmission efficiency; the relationship strength, informa-tion potential difference, network density and network centrality are positively related to the information transmitting and receiving inten-tion;information niche overlap is negatively related to willingness to send and receive information;relationship strength, network centrali-ty, network coverage are positively related to the information receiving and transmitting ability.

  5. CALCULATION OF CONFORMATIONAL ENTROPY AND FREE ENERGY OF POLYSILANE CHAIN

    Institute of Scientific and Technical Information of China (English)

    Meng-bo Luo; Ying-cai Chen; Jian-hua Huang; Jian-min Xu

    2001-01-01

    The conformational entropy S and free energy F were calculated by exact enumeration of polysilane chain up to 23 segments with excluded volume (EV) and long-range van der Waals (VW) interaction. A nonlinear relation between SEV+VW and chain length n was found though SEV was found to vary linearly with n. We found that the second-order transition temperature of polysilane chain with VW interaction increases with the increase of chain length, while that of polysilane chain without VW interaction is chain length independent. Moreover, the free energies FEV+VW and FEV are both linearly related with n, and FEV+VW<FEV for all temperatures.``

  6. Hotspots for Vitamin-Steroid-Thyroid Hormone Response Elements Within Switch Regions of Immunoglobulin Heavy Chain Loci Predict a Direct Influence of Vitamins and Hormones on B Cell Class Switch Recombination.

    Science.gov (United States)

    Hurwitz, Julia L; Penkert, Rhiannon R; Xu, Beisi; Fan, Yiping; Partridge, Janet F; Maul, Robert W; Gearhart, Patricia J

    2016-03-01

    Vitamin A deficiencies are common throughout the world and have a significant negative influence on immune protection against viral infections. Mouse models demonstrate that the production of IgA, a first line of defense against viruses at mucosal sites, is inhibited in the context of vitamin A deficiency. In vitro, the addition of vitamin A to activated B cells can enhance IgA expression, but downregulate IgE. Previous reports have demonstrated that vitamin A modifies cytokine patterns, and in so doing may influence antibody isotype expression by an indirect mechanism. However, we have now discovered hundreds of potential response elements among Sμ, Sɛ, and Sα switch sites within immunoglobulin heavy chain loci. These hotspots appear in both mouse and human loci and include targets for vitamin receptors and related proteins (e.g., estrogen receptors) in the nuclear receptor superfamily. Full response elements with direct repeats are relatively infrequent or absent in Sγ regions although half-sites are present. Based on these results, we pose a hypothesis that nuclear receptors have a direct effect on the immunoglobulin heavy chain class switch recombination event. We propose that vitamin A may alter S site accessibility to activation-induced deaminase and nonhomologous end-joining machinery, thereby influencing the isotype switch, antibody production, and protection against viral infections at mucosal sites.

  7. 锚链直径对船舶锚泊能力的影响%Influence of Diameter of Anchor Chains on the Anchoring Capability of Ships

    Institute of Scientific and Technical Information of China (English)

    胡晓芳; 丁德勇

    2014-01-01

    In order to meet the demand of anchor system using thinner anchor chains,this paper deduces the catenary equation by taking every anchor chain link as an infinitesimal. Based on the equation,the length of anchor chains and the maximum environmental forces and water depth are calculated for anchor chains with different diameters. According to the calculation result and actual practices,it is concluded that though the thicker the anchor chain,the better the anchoring capability,the applications of thinner chains are more reasonable when not using anchors with high holding power,or when the situation does not demand any special request of the mooring region or water depth.%从减轻船总体负担、采用链径更小的海洋系泊链的设计需求出发,以单个链环为微元对锚链在锚泊状态所形成悬链线方程进行推导,建立锚链在典型锚泊状态下的悬链线方程,并以此为基础完成不同链径锚链在抛锚长度、最大可承受环境力、最大抛锚深度等方面的计算分析。结合计算结果和船舶实际使用情况,对采用不同链径锚链的锚泊能力进行综合分析后认为,虽然链径较粗的锚链的理论锚泊能力较强,但若采用霍尔锚等非大抓力锚,或对锚泊水域面积无明确要求、没有在深水中抛锚的特殊需求等,则可以选用链径相对较细的海洋系泊链代替目前规范中规定的电焊锚链。

  8. Influence of the nonlinearity parameter on the solar-wind sub-ion magnetic energy spectrum: FLR-Landau fluid simulations

    CERN Document Server

    Sulem, P L; Laveder, D; Borgogno, D

    2015-01-01

    The cascade of kinetic Alfv\\'en waves (KAWs) at the sub-ion scales in the solar wind is numerically simulated using a fluid approach that retains ion and electron Landau damping, together with ion finite Larmor radius corrections. Assuming initially equal and isotropic ion and electron temperatures, and an ion beta equal to unity, different simulations are performed by varying the propagation direction and the amplitude of KAWs that are randomly driven at a transverse scale of about one fifth of the proton gyroradius in order to maintain a prescribed level of turbulent fluctuations. The resulting turbulent regimes are characterized by the nonlinearity parameter, defined as the ratio of the characteristic times of Alfv\\'en wave propagation and of the transverse nonlinear dynamics. The corresponding transverse magnetic energy spectra display power laws with exponents spanning a range of values consistent with spacecraft observations. The meandering of the magnetic field lines together with the ion temperature h...

  9. Crystal Structure of the 5-Chloro Salicylamides: Three Different Types of the H-bonding Influenced Linear Chain Formation in the Solid State

    Directory of Open Access Journals (Sweden)

    Jiří Hanusek

    2012-05-01

    Full Text Available Three N-substituted 5-chlorosalicylamides (4-chlorophenyl, 2a; benzyl, 2b; phenethyl 2c differing in the length of the 'linker' between the benzene ring and the amide moiety were prepared in order to compare their supramolecular architecture. The intramolecular NH···O(H hydrogen bond and the intermolecular C=O···H–O hydrogen bond were found in the crystal structure of 2a and 2c thus forming an infinite linear chain. Compound 2b had a different arrangement with the intramolecular C=O···H–O hydrogen bond and another intermolecular NH···O(H hydrogen forming a linear infinite chain.

  10. Proposal of a bootstrap procedure using measures of influence in non-linear regression models with outliers - doi: 10.4025/actascitechnol.v36i1.17564

    Directory of Open Access Journals (Sweden)

    Larissa Ribeiro de Andrade

    2014-01-01

    Full Text Available The bootstrap method is generally performed by presupposing that each sample unit would show the same probability of being re-sampled. However, when a sample with outliers is taken into account, the empirical distribution generated by this method may be influenced, or rather, it may not accurately represent the original sample. Current study proposes a bootstrap algorithm that allows the use of measures of influence in the calculation of re-sampling probabilities. The method was reproduced in simulation scenarios taking into account the logistic growth curve model and the CovRatio measurement to evaluate the impact of an influential observation in the determinacy of the matrix of the co-variance of parameter estimates. In most cases, bias estimates were reduced. Consequently, the method is suitable to be used in non-linear models and allows the researcher to apply other measures for better bias reductions.

  11. Synthesis and Properties of A Nonlinear Optical Polyimide with Stilbazolium-Like Dye Side-Chain%侧链含类杂芪生色团的光学非线性聚酰亚胺的合成与性质研究

    Institute of Scientific and Technical Information of China (English)

    廖海星; 黄浸; 张爱清; 青志保

    2011-01-01

    In this article,a new nonlinear optical polyimide with trans-4-[p-(pyrrolidinyl) oxygen ]-N-meth-ylpyridinium iodide dye unit as side-chain(CMPI-O-PSI) had been prepared through grafting reaction of a stiba-zolium-like dye(HOPSI) and polyimide (PI). The structure of CMPI-OPSI was characterized by 1HNMR and FTIR. The grafting rate of chromophore was 56%. The Z-scan analysis showed that CMPI-OPSI had obvious nonlinear absorption for 1064 nm of laser,so it was prospective to be applied to laser power limiting materials.%成功地通过类杂芪染料(HOPSI)与氯甲基化的含氟聚酰亚胺(CMPI)反应制备了接枝的聚酰亚胺(CMPI-O-PSI),并采用1 HNMR和FTIR对其结构进行表征.CMPI-O-PSI的生色团接枝率为56%,其显示了和CMPI相似的良好溶解性能.Z-扫描分析表明,CMPI-O-PSI对1064nm的激光有明显的非线性吸收,有望应用于激光限幅材料.

  12. A GM (1, 1 Markov Chain-Based Aeroengine Performance Degradation Forecast Approach Using Exhaust Gas Temperature

    Directory of Open Access Journals (Sweden)

    Ning-bo Zhao

    2014-01-01

    Full Text Available Performance degradation forecast technology for quantitatively assessing degradation states of aeroengine using exhaust gas temperature is an important technology in the aeroengine health management. In this paper, a GM (1, 1 Markov chain-based approach is introduced to forecast exhaust gas temperature by taking the advantages of GM (1, 1 model in time series and the advantages of Markov chain model in dealing with highly nonlinear and stochastic data caused by uncertain factors. In this approach, firstly, the GM (1, 1 model is used to forecast the trend by using limited data samples. Then, Markov chain model is integrated into GM (1, 1 model in order to enhance the forecast performance, which can solve the influence of random fluctuation data on forecasting accuracy and achieving an accurate estimate of the nonlinear forecast. As an example, the historical monitoring data of exhaust gas temperature from CFM56 aeroengine of China Southern is used to verify the forecast performance of the GM (1, 1 Markov chain model. The results show that the GM (1, 1 Markov chain model is able to forecast exhaust gas temperature accurately, which can effectively reflect the random fluctuation characteristics of exhaust gas temperature changes over time.

  13. Bayesian inference of nonlinear unsteady aerodynamics from aeroelastic limit cycle oscillations

    Energy Technology Data Exchange (ETDEWEB)

    Sandhu, Rimple [Department of Civil and Environmental Engineering, Carleton University, Ottawa, Ontario (Canada); Poirel, Dominique [Department of Mechanical and Aerospace Engineering, Royal Military College of Canada, Kingston, Ontario (Canada); Pettit, Chris [Department of Aerospace Engineering, United States Naval Academy, Annapolis, MD (United States); Khalil, Mohammad [Department of Civil and Environmental Engineering, Carleton University, Ottawa, Ontario (Canada); Sarkar, Abhijit, E-mail: abhijit.sarkar@carleton.ca [Department of Civil and Environmental Engineering, Carleton University, Ottawa, Ontario (Canada)

    2016-07-01

    A Bayesian model selection and parameter estimation algorithm is applied to investigate the influence of nonlinear and unsteady aerodynamic loads on the limit cycle oscillation (LCO) of a pitching airfoil in the transitional Reynolds number regime. At small angles of attack, laminar boundary layer trailing edge separation causes negative aerodynamic damping leading to the LCO. The fluid–structure interaction of the rigid, but elastically mounted, airfoil and nonlinear unsteady aerodynamics is represented by two coupled nonlinear stochastic ordinary differential equations containing uncertain parameters and model approximation errors. Several plausible aerodynamic models with increasing complexity are proposed to describe the aeroelastic system leading to LCO. The likelihood in the posterior parameter probability density function (pdf) is available semi-analytically using the extended Kalman filter for the state estimation of the coupled nonlinear structural and unsteady aerodynamic model. The posterior parameter pdf is sampled using a parallel and adaptive Markov Chain Monte Carlo (MCMC) algorithm. The posterior probability of each model is estimated using the Chib–Jeliazkov method that directly uses the posterior MCMC samples for evidence (marginal likelihood) computation. The Bayesian algorithm is validated through a numerical study and then applied to model the nonlinear unsteady aerodynamic loads using wind-tunnel test data at various Reynolds numbers.

  14. Bayesian inference of nonlinear unsteady aerodynamics from aeroelastic limit cycle oscillations

    Science.gov (United States)

    Sandhu, Rimple; Poirel, Dominique; Pettit, Chris; Khalil, Mohammad; Sarkar, Abhijit

    2016-07-01

    A Bayesian model selection and parameter estimation algorithm is applied to investigate the influence of nonlinear and unsteady aerodynamic loads on the limit cycle oscillation (LCO) of a pitching airfoil in the transitional Reynolds number regime. At small angles of attack, laminar boundary layer trailing edge separation causes negative aerodynamic damping leading to the LCO. The fluid-structure interaction of the rigid, but elastically mounted, airfoil and nonlinear unsteady aerodynamics is represented by two coupled nonlinear stochastic ordinary differential equations containing uncertain parameters and model approximation errors. Several plausible aerodynamic models with increasing complexity are proposed to describe the aeroelastic system leading to LCO. The likelihood in the posterior parameter probability density function (pdf) is available semi-analytically using the extended Kalman filter for the state estimation of the coupled nonlinear structural and unsteady aerodynamic model. The posterior parameter pdf is sampled using a parallel and adaptive Markov Chain Monte Carlo (MCMC) algorithm. The posterior probability of each model is estimated using the Chib-Jeliazkov method that directly uses the posterior MCMC samples for evidence (marginal likelihood) computation. The Bayesian algorithm is validated through a numerical study and then applied to model the nonlinear unsteady aerodynamic loads using wind-tunnel test data at various Reynolds numbers.

  15. McMC-based nonlinear EIVAZ inversion driven by rock physics

    Science.gov (United States)

    Pan, Xinpeng; Zhang, Guangzhi; Chen, Huaizhen; Yin, Xingyao

    2017-03-01

    A single set of vertically aligned fractures embedded in a purely isotropic background medium may be considered as a long-wavelength effective transversely isotropic medium with a horizontal symmetry axis (HTI). The estimation of fracture weaknesses is essential for characterizing the anisotropy in HTI media. Using the fractured anisotropic rock-physics models and the wide-azimuth seismic data, elastic impedance inversion variation with incident angle and azimuth, or simply ‘EIVAZ’ for short, can be carried out for the estimation of the normal and tangential fracture weaknesses with the nonlinear Markov chain Monte Carlo (McMC) strategy. Firstly, an inversion method of nonlinear anisotropic elastic impedance (AEI) with the McMC algorithm was proposed, which is used for the inversion of nonlinear AEI information with different angles of incidence and azimuth. Then we extracted the normal and tangential fracture weaknesses directly using the ratio differences of inverted nonlinear AEI data. So we can eliminate the influence of the isotropic background elastic impedance on the anisotropic perturbation elastic impedance and obtain the normal and tangential fracture weaknesses more stably. A test on a 2D over-thrust model shows that the fracture weaknesses are still estimated reasonably with moderate noise. A test on a real data set demonstrates that the estimated results are in good agreement with the results of the well log interpretation, and our McMC-based nonlinear AEI approach appears to be a stable method for predicting fracture weaknesses.

  16. Binding of estrogen receptors to switch sites and regulatory elements in the immunoglobulin heavy chain locus of activated B cells suggests a direct influence of estrogen on antibody expression.

    Science.gov (United States)

    Jones, Bart G; Penkert, Rhiannon R; Xu, Beisi; Fan, Yiping; Neale, Geoff; Gearhart, Patricia J; Hurwitz, Julia L

    2016-09-01

    Females and males differ in antibody isotype expression patterns and in immune responses to foreign- and self-antigens. For example, systemic lupus erythematosus is a condition that associates with the production of isotype-skewed anti-self antibodies, and exhibits a 9:1 female:male disease ratio. To explain differences between B cell responses in males and females, we sought to identify direct interactions of the estrogen receptor (ER) with the immunoglobulin heavy chain locus. This effort was encouraged by our previous identification of estrogen response elements (ERE) in heavy chain switch (S) regions. We conducted a full-genome chromatin immunoprecipitation analysis (ChIP-seq) using DNA from LPS-activated B cells and an ERα-specific antibody. Results revealed ER binding to a wide region of DNA, spanning sequences from the JH cluster to Cδ, with peaks in Eμ and Sμ sites. Additional peaks of ERα binding were coincident with hs1,2 and hs4 sites in the 3' regulatory region (3'RR) of the heavy chain locus. This first demonstration of direct binding of ER to key regulatory elements in the immunoglobulin locus supports our hypothesis that estrogen and other nuclear hormone receptors and ligands may directly influence antibody expression and class switch recombination (CSR). Our hypothesis encourages the conduct of new experiments to evaluate the consequences of ER binding. A better understanding of ER:DNA interactions in the immunoglobulin heavy chain locus, and respective mechanisms, may ultimately translate to better control of antibody expression, better protection against pathogens, and prevention of pathologies caused by auto-immune disease.

  17. Influence of the ordered structure of short-chain polymer molecule all-trans-β-carotene on Raman scattering cross section in liquid

    Institute of Scientific and Technical Information of China (English)

    Qu Guan-Nan; OuYang Shun-Li; Wang Wei-Wei; Li Zuo-Wei; Sun Cheng-Lin; Men Zhi-Wei

    2011-01-01

    We measured the resonant Raman spectra of all-trans-β-carotene in solvents with different densities and concentrations at different temperatures. The results demonstrated that the Raman scattering cross section (RSCS) of short-chain polymer all-trans-β-carotene is extremely high in liquid. Resonance and strong coherent weakly damped CC bond vibrating properties play important roles under these conditions. Coherent weakly damped CC bond vibration strength is associated with molecular ordered structure. All-trans-β-carotene has highly ordered structure and strong coherent weakly damped CC bond vibrating properties, which lead to large RSCS in the solvent with large density and low concentration at low temperature.

  18. Photo-Induced Phase Transitions to Liquid Crystal Phases: Influence of the Chain Length from C8E4 to C14E4

    Directory of Open Access Journals (Sweden)

    Simone Techert

    2009-09-01

    Full Text Available Photo-induced phase transitions are characterized by the transformation from phase A to phase B through the absorption of photons. We have investigated the mechanism of the photo-induced phase transitions of four different ternary systems CiE4/alkane (i with n = 8, 10, 12, 14; cyclohexane/H2O. We were interested in understanding the effect of chain length increase on the dynamics of transformation from the microemulsion phase to the liquid crystal phase. Applying light pump (pulse/x-ray probe (pulse techniques, we could demonstrate that entropy and diffusion control are the driving forces for the kind of phase transition investigated.

  19. SUPPLY CHAIN MANAGEMENT – KEY FACTORS

    Directory of Open Access Journals (Sweden)

    Magdalena Daniela DINU

    2014-06-01

    Full Text Available This paper exposes Supply Chain Management by its key factors. Briefly, where the Supply Chain Management is treated as strategic part of a company then maintaining both control and influence throughout the entire supply chain are key factors and critical to success. On the other hand, finding the right partner to manage the non-strategic Supply Chains would be another key factor too. To define the most important key factors within Supply Chain Management means a deeply understanding of both Supply Chain’ s components, procedures, workflow, processes and the importance of Supply Chain Management into maximizing company's value. SCORE model able to provide solid information about measuring performance and identifying priorities within Supply Chain Management will help us to understand the key factors by analyzing its elements: Plan, Source, Make, Deliver,Return, Enable. These elements covers all the challenging areas from first to third tier of Supply Chain Management.

  20. 绿色供应链管理对中国汽车生产企业绩效的影响%Influence of Green Supply Chain Management on Performance of Chinese Auto-making Enterprises

    Institute of Scientific and Technical Information of China (English)

    牟方舟

    2016-01-01

    In this paper, we introduced the background for the researches on the influence of the green supply chain management practices on the performance of the Chinese auto-making enterprises, then reviewed the relevant literatures both from home and abroad, next, using questionnaire survey, multiple regression analysis and a typical case analysis, studied in the influence of green supply chain management on the environmental, economic and operational performance of these enterprises, and at the end, built a model to describe the relationship between the two.%简述了绿色供应链管理对中国汽车生产企业绩效影响研究的背景,对国内外相关研究文献进行了回顾,并采用问卷调查、多元回归分析和典型相关分析方法,从环境绩效、经济绩效和运作绩效几方面分析了绿色供应链管理对中国汽车生产企业绩效的影响,最后建立了二者的关系模型。

  1. Influence of bonded-phase coverage in reversed-phase liquid chromatography via molecular simulation I. Effects on chain conformation and interfacial properties.

    Science.gov (United States)

    Rafferty, Jake L; Siepmann, J Ilja; Schure, Mark R

    2008-09-12

    Particle-based Monte Carlo simulations were employed to examine the effects of bonding density on molecular structure in reversed-phase liquid chromatography. Octadecylsilane stationary phases with five different bonding densities (1.6, 2.3, 2.9, 3.5, and 4.2 micromol/m(2)) in contact with a water/methanol (50/50 mol%) mobile phase were simulated at a temperature of 323 K. The simulations indicate that the alkyl chains become more aligned and form a more uniform alkyl layer as coverage is increased. However, this does not imply that the chains are highly ordered (e.g., all-trans conformation or uniform tilt angle), but rather exhibit a broad distribution of conformations and tilt angles at all bonding densities. At lower densities, significant amounts of the silica surface are exposed leading to an enhanced wetting of the stationary phase. At high densities, the solvent is nearly excluded from the bonded phase and persists only near the residual silanols. An enrichment in the methanol concentration and a disruption in the mobile phase's hydrogen bond network are observed at the interface as bonding density is increased.

  2. Influence of the long-chain/short-chain amphiphile ratio on lateral diffusion of PEG-lipid in magnetically aligned lipid bilayers as measured via pulsed-field-gradient NMR.

    Science.gov (United States)

    Soong, Ronald; Macdonald, Peter M

    2005-09-01

    Lateral diffusion measurements of polyethylene glycol(PEG)-lipid incorporated into magnetically aligned lipid bilayers, composed of dimyristoyl phosphatidylcholine (DMPC) plus dihexanoyl phosphatidylcholine (DHPC) plus 1 mol % (relative to DMPC) dimyristoyl phosphatidylethanolamine-n-[methoxy(polyethylene glycol)-2000] (DMPE-PEG 2000), were performed using stimulated-echo pulsed-field-gradient proton ((1)H) nuclear magnetic resonance spectroscopy. The DMPE-PEG 2000 (1 mol %, 35 degrees C) lateral diffusion coefficient D varied directly with the mole fraction of DMPC, X(DMPC) = q/(1+q) where q = DMPC/DHPC molar ratio, decreasing progressively from D = 1.65 x 10(-11) m(2) s(-1) at q approximately 4.7 to D = 0.65 x 10(-11) m(2) s(-1) at q approximately 2.5. Possible sources of this dependence, including orientational disorder, obstruction, and PEG-lipid sequestration, were simulated using, respectively, a diffusion-in-a-cone model, percolation theory, and a two-phase PEG distribution model. Orientational disorder alone was not capable of reproducing the observations, but in combination with either obstruction or PEG-lipid two-phase distribution models did so satisfactorily. A combination of all three models yielded the most reasonable fit to the observed dependence of lateral diffusion on q. These same effects would be expected to influence lateral diffusion of any bilayer-associating species in such systems.

  3. Curvature-induced symmetry breaking in nonlinear Schrodinger models

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Mingaleev, S. F.; Christiansen, Peter Leth

    2000-01-01

    We consider a curved chain of nonlinear oscillators and show that the interplay of curvature and nonlinearity leads to a symmetry breaking when an asymmetric stationary state becomes energetically more favorable than a symmetric stationary state. We show that the energy of localized states decrea...

  4. Nonlinear resonances

    CERN Document Server

    Rajasekar, Shanmuganathan

    2016-01-01

    This introductory text presents the basic aspects and most important features of various types of resonances and anti-resonances in dynamical systems. In particular, for each resonance, it covers the theoretical concepts, illustrates them with case studies, and reviews the available information on mechanisms, characterization, numerical simulations, experimental realizations, possible quantum analogues, applications and significant advances made over the years. Resonances are one of the most fundamental phenomena exhibited by nonlinear systems and refer to specific realizations of maximum response of a system due to the ability of that system to store and transfer energy received from an external forcing source. Resonances are of particular importance in physical, engineering and biological systems - they can prove to be advantageous in many applications, while leading to instability and even disasters in others. The book is self-contained, providing the details of mathematical derivations and techniques invo...

  5. Nonlinear Dynamics

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    3.1 A Unified Nonlinear Feedback Functional Method for Study Both Control and Synchronization of Spatiotemporal Chaos Fang Jinqing Ali M. K. (Department of Physics, The University of Lethbridge,Lethbridge, Alberta T1K 3M4,Canada) Two fundamental questions dominate future chaos control theories.The first is the problem of controlling hyperchaos in higher dimensional systems.The second question has yet to be addressed:the problem of controlling spatiotemporal chaos in a spatiotemporal system.In recent years, control and synchronization of spatiotemporal chaos and hyperchaos have became a much more important and challenging subject. The reason for this is the control and synchronism of such behaviours have extensive and great potential of interdisciplinary applications, such as security communication, information processing, medicine and so on. However, this subject is not much known and remains an outstanding open.

  6. Innovation Trajectories in Honduras' Coffee Value Chain. Public and Private Influence on the Use of New Knowledge and Technology among Coffee Growers

    Directory of Open Access Journals (Sweden)

    Frank Hartwich

    2010-10-01

    Full Text Available  In this paper, results from a study on the use of improved coffee production technology schemes among smallholder coffee producers in three prominent coffee producing regions in Honduras are presented. The impact of various schemes (trajectories in which different agents influence the producers’ decision to use new technologies was analyzed. In particular, there are differences in the influence of a private coffee buying organizations and b government and public development agencies on the innovation behavior of coffee growers. Drawing from network data that depict the internal and outbound connectedness of producers in three village communities in main coffee producing zones in Honduras, tools of social network analysis were applied to find out how interactions with certain agents, separately and cumulatively, has influenced their use of improved methods in coffee production and marketing. The results suggest that there are significant differences in the way that various providers of knowledge and technology, especially private buyers and development agencies, influence the farmers’ behavior towards innovation. The influence of buyers, according to the data, is focused on certification and quality aspects, whereas development agents focus on improved agronomic practices. Farmers who communicate with the extension branch of input providers tend to be more innovative. These results suggest that development programs should take more seriously into account the role of private actors in innovation among agricultural producers and, hence, design development programs in such a way to allow for collaboration with these agents.

  7. Discrete gap breathers in a diatomic Klein-Gordon chain: stability and mobility.

    Science.gov (United States)

    Gorbach, Andrey V; Johansson, Magnus

    2003-06-01

    A one-dimensional diatomic chain with harmonic intersite potential and nonlinear external potential is considered (the Klein-Gordon model). Localized solutions of the corresponding nonlinear differential equations with frequencies inside the gap of the linear wave spectrum--"gap breathers"--are studied numerically. The linear stability analysis for these solutions is performed while changing the system parameters from the anticontinuous to the continuous limit. Two different types of solutions are considered: symmetric centered at a heavy atom and antisymmetric centered at a light atom, respectively. Different mechanisms of instability, oscillatory as well as nonoscillatory, of the gap breathers are studied, and the influence of the instabilities on the breather solutions is investigated in the dynamics simulations. In particular, the presence of an "inversion of stability" regime, with simultaneous nonoscillatory instabilities of symmetric and antisymmetric solutions with respect to antisymmetric perturbations, is found, yielding practically radiationless mobility.

  8. 非饱和土强度非线性及对被动土压力的影响%Nonlinearity of unsaturated soils strength and its influence on passive earth pressure

    Institute of Scientific and Technical Information of China (English)

    张常光; 赵均海; 张冬芳

    2012-01-01

    In order to investigate the nonlinearity of unsaturated soil strength and its influence on passive earth pressure, the advances in the study of nonlinearity of unsaturated soil shear strength are reviewed, and based on the piecewise shear strength formula for unsaturated soil, a shear strength parameter under high matric suction is derived. Then, the parameter is applied to the calculation of passive earth pressure of unsaturated soil. The results show that high matric suction has a dual effect which can be divided into three situations according to the relationship between reducing and strengthening. As matric suction increases, the corresponding passive earth pressure decreases gradually and stabilizes, or increases slightly, or increases significantly, which actually reflects the nonlinearity of unsaturated soils strength under high matric suction.%为研究非饱和土强度的非线性及其对被动土压力的影响,文中在介绍非饱和土强度非线性研究进展的基础上,结合分段抗剪强度公式拟合了一个高吸力抗剪强度参数,并将这一参数应用于非饱和土被动土压力的计算.研究结果表明:高基质吸力具有双重影响,按减小影响和增大效应间的相对关系可分为3种情况,所对应的被动土压力随着基质吸力的增大,或逐渐减小并最终趋于稳定,或略有增加,或大幅度增加,这实际反映的是高基质吸力下非饱和土强度的非线性规律.

  9. Thermodynamics of a dilute XX chain in a field

    Science.gov (United States)

    Timonin, P. N.

    2016-06-01

    Gapless phases in ground states of low-dimensional quantum spin systems are rather ubiquitous. Their peculiarity is a remarkable sensitivity to external perturbations due to permanent criticality of such phases manifested by a slow (power-low) decay of pair correlations and the divergence of the corresponding susceptibility. A strong influence of various defects on the properties of the system in such a phase can then be expected. Here, we consider the influence of vacancies on the thermodynamics of the simplest quantum model with a gapless phase, the isotropic spin-1/2 XX chain. The existence of the exact solution of this model gives a unique opportunity to describe in detail the dramatic effect of dilution on the gapless phase—the appearance of an infinite series of quantum phase transitions resulting from level crossing under the variation of a longitudinal magnetic field. We calculate the jumps in the field dependences of the ground-state longitudinal magnetization, susceptibility, entropy, and specific heat appearing at these transitions and show that they result in a highly nonlinear temperature dependence of these parameters at low T. Also, the effect of enhancement of the magnetization and longitudinal correlations in the dilute chain is established. The changes of the pair spin correlators under dilution are also analyzed. The universality of the mechanism of the quantum transition generation suggests that similar effects of dilution can also be expected in gapless phases of other low-dimensional quantum spin systems.

  10. Freezing of nonlinear Bloch oscillations in the generalized discrete nonlinear Schrödinger equation.

    Science.gov (United States)

    Cao, F J

    2004-09-01

    The dynamics in a nonlinear Schrödinger chain in a homogeneous electric field is studied. We show that discrete translational invariant integrability-breaking terms can freeze the Bloch nonlinear oscillations and introduce new faster frequencies in their dynamics. These phenomena are studied by direct numerical integration and through an adiabatic approximation. The adiabatic approximation allows a description in terms of an effective potential that greatly clarifies the phenomena.

  11. Influence of Side Chain Position on the Electrical Properties of Organic Solar Cells Based on Dithienylbenzothiadiazole-alt-phenylene Conjugated Polymers

    DEFF Research Database (Denmark)

    Livi, Francesco; Zawacka, Natalia Klaudia; Angmo, Dechan

    2015-01-01

    backbone for polymer solar cells. All the polymers were roll slot die coated under ambient conditions on flexible ITO-free plastic substrates to give inverted polymer solar cell devices with an upscaled active area of 1 cm2. The best characteristics were found for the polymer carrying alkoxy side chains...... on the benzene ring where power conversion efficiencies of up to 3.6% were achieved. All studied materials were prepared with an objective of low-cost starting materials, simple synthesis, and simple processing conditions which was most successful for the polymer P5. The polymer P7 containing fluorine atoms...... showed excellent performance under constant illumination and high temperature (exhibiting stable photovoltaic properties even after 670 h under conditions similar to ISOS-L-2 lifetime protocol). This makes P7 a good candidate for further upscaling and device optimization. The photovoltaic performance...

  12. Foldamers to nanotubes: influence of amino acid side chains in the hierarchical assembly of α,γ(4)-hybrid peptide helices.

    Science.gov (United States)

    Jadhav, Sandip V; Misra, Rajkumar; Gopi, Hosahudya N

    2014-12-08

    Supramolecular assembly of various artificially folded 12-helical architectures composed of γ(4) -Val, γ(4) -Leu and γ(4) -Phe residues is investigated. In contrast to the 12-helices composed of γ(4) -Val and γ(4) -Leu residues, the helices with γ(4) -Phe residues displayed unique elongated nanotubular architectures. The elongated nanotube assembly was further explored as a template for biomineralization of silver ions to silver nanowires. A comparative study using an analogous α-peptide helix reveals the importance of the spatial arrangement of aromatic side chains along the helical cylinder in a 12-helix. These results suggested that the proteolytically and structurally stable α,γ(4) -hybrid peptide 12-helices may serve as a new generation of potential templates in the design of functional biomaterials.

  13. TBA for the Toda chain

    Energy Technology Data Exchange (ETDEWEB)

    Kozlowski, K.K.; Teschner, J.

    2010-06-15

    We give a direct derivation of a proposal of Nekrasov-Shatashvili concerning the quantization conditions of the Toda chain. The quantization conditions are formulated in terms of solutions to a nonlinear integral equation similar to the ones coming from the thermodynamic Bethe ansatz. This is equivalent to extremizing a certain function called Yang's potential. It is shown that the Nekrasov-Shatashvili formulation of the quantization conditions follows from the solution theory of the Baxter equation, suggesting that this way of formulating the quantization conditions should indeed be applicable to large classes of quantized algebraically integrable models. (orig.)

  14. Quantum state transfer in a q-deformed chain

    Energy Technology Data Exchange (ETDEWEB)

    L' Innocente, Sonia [Dipartimento di Matematica ed Informatica, Universita di Camerino, 62032 Camerino (Italy); Lupo, Cosmo; Mancini, Stefano [Dipartimento di Fisica, Universita di Camerino, 62032 Camerino (Italy)], E-mail: sonia.linnocente@unicam.it, E-mail: cosmo.lupo@unicam.it, E-mail: stefano.mancini@unicam.it

    2009-11-27

    We investigate the quantum state transfer in a chain of particles satisfying the q-deformed oscillators algebra. This general algebraic setting includes the spin chain and the bosonic chain as limiting cases. We study conditions for perfect state transfer depending on the number of sites and excitations on the chain. They are formulated by means of irreducible representations of a quantum algebra realized through Jordan-Schwinger maps. Playing with deformation parameters, we can study the effects of nonlinear perturbations or interpolate between the spin and bosonic chains.

  15. Nonlinear Materials Characterization Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Nonlinear Materials Characterization Facility conducts photophysical research and development of nonlinear materials operating in the visible spectrum to protect...

  16. Interaction of bovine serum albumin and human blood plasma with PEO-tethered surfaces : influence of PEO chain length, grafting density and temperature

    NARCIS (Netherlands)

    Norde, W.; Gage, R.A.

    2004-01-01

    Solid surfaces are modified by grafting poly(ethylene oxide), PEO, to influence their interaction with indwelling particles, in particular molecules of bovine serum albumin and human plasma proteins. As a rule, the grafted PEO layers suppress protein adsorption. The suppression is most effective whe

  17. Nonlinear analysis of wind-induced vibration of high-speed railway catenary and its influence on pantograph-catenary interaction

    Science.gov (United States)

    Song, Yang; Liu, Zhigang; Wang, Hongrui; Lu, Xiaobing; Zhang, Jing

    2016-06-01

    The wind-induced vibration of the high-speed catenary and the dynamic behaviour of the pantograph-catenary under stochastic wind field are firstly analysed. The catenary model is established based on nonlinear cable and truss elements, which can fully describe the nonlinearity of each wire and the initial configuration. The model of the aerodynamic forces acting on the messenger/contact wire is deduced by considering the effect of the vertical and horizontal fluctuating winds. The vertical and horizontal fluctuating winds are simulated by employing the Davenport and Panofsky spectrums, respectively. The aerodynamic coefficients of the contact/messenger wire are calculated through computational fluid dynamics. The wind-induced vibration response of catenary is analysed with different wind speeds and angles. Its frequency-domain characteristics are discussed using Auto Regression model. Finally, a pantograph model is introduced and the contact force of the pantograph-catenary under stochastic wind is studied. The results show that both the wind speed and the attack angle exert a significant effect on the wind-induced vibration. The existence of the groove on the contact wire cross-section leads to a significant change of the aerodynamic coefficient, which affects largely the aerodynamic forces applied on the catenary wires, as well as the vibration response. The vibration frequency with high spectral power mainly concentrates on the predominant frequency of the fluctuating wind and the natural frequency of catenary. The increase in the wind speed results in a significant deterioration of the current collection. The numerical example shows that a relatively stable current collection can be ensured when the wind flows at the relatively horizontal direction.

  18. Nonlinear excitations in two-dimensional molecular structures with impurities

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Rasmussen, Kim; Christiansen, Peter Leth

    1995-01-01

    We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence of the imp......We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence...... excitations. Analytical results are in good agreement with numerical simulations of the nonlinear Schrodinger equation....

  19. Graphs: Associated Markov Chains

    OpenAIRE

    2012-01-01

    In this research paper, weighted / unweighted, directed / undirected graphs are associated with interesting Discrete Time Markov Chains (DTMCs) as well as Continuous Time Markov Chains (CTMCs). The equilibrium / transient behaviour of such Markov chains is studied. Also entropy dynamics (Shannon entropy) of certain structured Markov chains is investigated. Finally certain structured graphs and the associated Markov chains are studied.

  20. Solute Transport in a Heterogeneous Aquifer: A Nonlinear Deterministic Dynamical Analysis

    Science.gov (United States)

    Sivakumar, B.; Harter, T.; Zhang, H.

    2003-04-01

    Stochastic approaches are widely used for modeling and prediction of uncertainty in groundwater flow and transport processes. An important reason for this is our belief that the dynamics of the seemingly complex and highly irregular subsurface processes are essentially random in nature. However, the discovery of nonlinear deterministic dynamical theory has revealed that random-looking behavior could also be the result of simple deterministic mechanisms influenced by only a few nonlinear interdependent variables. The purpose of the present study is to introduce this theory to subsurface solute transport process, in an attempt to investigate the possibility of understanding the transport dynamics in a much simpler, deterministic, manner. To this effect, salt transport process in a heterogeneous aquifer medium is studied. Specifically, time series of arrival time of salt particles are analyzed. These time series are obtained by integrating a geostatistical (transition probability/Markov chain) model with a groundwater flow model (MODFLOW) and a salt transport (Random Walk Particle) model. The (dynamical) behavior of the transport process (nonlinear deterministic or stochastic) is identified using standard statistical techniques (e.g. autocorrelation function, power spectrum) as well as specific nonlinear deterministic dynamical techniques (e.g. phase-space diagram, correlation dimension method). The sensitivity of the salt transport dynamical behavior to the hydrostratigraphic parameters (i.e. number, volume proportions, mean lengths, and juxtapositional tendencies of facies) used in the transition probability/Markov chain model is also studied. The results indicate that the salt transport process may exhibit very simple (i.e. deterministic) to very complex (i.e. stochastic) dynamical behavior, depending upon the above parameters (i.e. characteristics of the aquifer medium). Efforts towards verification and strengthening of the present results and prediction of salt

  1. Finding gold in the supply chain.

    Science.gov (United States)

    Caudle, Allen

    2009-12-01

    To optimize supply chain performance and achieve savings that enhance the bottom line, hospitals should: Generate purchase orders for every item purchased. Ensure the organization is protected from undue vendor influence. Keep track of where supply chain dollars are going. Review contracts regularly to ensure competitiveness. Have a contract for each product category. Buy only what the organization is sure to use. Get rid of excess inventory. Develop a strategic plan for continued supply chain savings.

  2. Nonlinear singular vectors and nonlinear singular values

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A novel concept of nonlinear singular vector and nonlinear singular value is introduced, which is a natural generalization of the classical linear singular vector and linear singular value to the nonlinear category. The optimization problem related to the determination of nonlinear singular vectors and singular values is formulated. The general idea of this approach is demonstrated by a simple two-dimensional quasigeostrophic model in the atmospheric and oceanic sciences. The advantage and its applications of the new method to the predictability, ensemble forecast and finite-time nonlinear instability are discussed. This paper makes a necessary preparation for further theoretical and numerical investigations.

  3. Solitonlike solutions of the generalized discrete nonlinear Schrödinger equation

    DEFF Research Database (Denmark)

    Rasmussen, Kim; Henning, D.; Gabriel, H.

    1996-01-01

    We investigate the solution properties oi. a generalized discrete nonlinear Schrodinger equation describing a nonlinear lattice chain. The generalized equation interpolates between the integrable discrete Ablowitz-Ladik equation and the nonintegrable discrete Schrodinger equation. Special interest...... nonlinear Schrodinger equation. In this way eve are able to construct coherent solitonlike structures of profile determined by the map parameters....

  4. Nonlinear properties of a graded-index photonic heterostructure

    Indian Academy of Sciences (India)

    B Tavakkoly Moghaddam; S Roshan Entezar; H Pashei Adl

    2013-05-01

    The optical properties of a one-dimensional (1D) photonic heterostructure with gradedindex nonlinear materials are demonstrated theoretically. The influence of the gradation profile of the graded-index nonlinear layers on the linear and nonlinear responses of the structure are analysed. It is shown that the -factor of the defect mode and the threshold input intensity to achieve the optical bistability in the used photonic heterostructure depend on the gradation profile of the gradedindex nonlinear layers.

  5. 可持续发展及其对物流服务供应链运营模式的影响%Influence of Sustainable Development on Operational Mode of Logistics Service Supply Chains

    Institute of Scientific and Technical Information of China (English)

    魏婉莹

    2016-01-01

    以可持续发展理念和现有物流服务供应链运营模式为基础,从三重底线的观点出发,从经济、社会以及环境三方面分析了可持续发展对物流服务供应链运营模式的影响。经济方面,可持续发展会给物流服务供应链运营带来新的成本分配问题,资源合理利用将成为供应链长期盈利的基础。社会方面,可持续发展让社会舆论成为影响供应链运营模式选择的重要因素。同时供应链可以通过增加社会价值来实现供应链的长期价值。环境方面,绿色运营和清洁运营将成为物流服务供应链模式的发展方向,选择供应链伙伴的原则也因此转变。面对可持续发展带来的影响,物流服务供应链运营应加强自身企业整合;建立合理的成本分配制度来克服经济上的困难;从提升企业内部可持续发展意识出发,创造更大的社会价值;选择绿色合作伙伴;落实物流各个环节的绿色运营来做到环境的可持续发展。%In this paper, based on the definition of the sustainable development and the current operational modes of the logistics service supply chains and from the angle of the triple bottom line, we analyzed the influence of the sustainable development on the operational modes from the aspects of economy, society and environment. Economically, the sustainable development will bring new cost allocation problem for the logistics service supply chain and reasonably resources utilization will because the basis for the long-term profitability of the supply chain. Socially, the sustainable development will make public opinion an important factor in the selection of the supply chain operation model. Meanwhile, the long-term value of the supply chain can be realized in the form of the increased social value. Environmentally, green operation and clean operation will be the new direction for the logistics service supply chain and at the same time, the

  6. Synthesis, characterization and third-order nonlinear optical properties of polydiacetylene nanostructures, silver nanoparticles and polydiacetylene–silver nanocomposites

    Indian Academy of Sciences (India)

    B BHUSHAN; S S TALWAR; T KUNDU; B P SINGH

    2016-10-01

    We have synthesized, characterized and studied the third-order nonlinear optical properties of two different nanostructures of polydiacetylene (PDA), PDA nanocrystals and PDA nanovesicles, along with silver nanoparticles-decorated PDA nanovesicles. The second molecular hyperpolarizability $\\gamma (−\\omega; \\omega,−\\omega,\\omega$) of the samples has been investigated by antiresonant ring interferometric nonlinear spectroscopic (ARINS) technique using femtosecond mode-locked Ti:sapphire laser in the spectral range of 720–820 nm. The observed spectral dispersion of $\\gamma$ has been explained in the framework of three-essential states model and a correlation between the electronic structure and optical nonlinearity of the samples has been established. The energy of two-photon state, transition dipole moments and linewidth of the transitions have been estimated. We have observed that the nonlinear optical properties of PDA nanocrystals and nanovesicles are different because of the influence of chain coupling effects facilitated by the chain packing geometry of the monomers. On the other hand, our investigation reveals that the spectral dispersion characteristic of $\\gamma$ for silver nanoparticles-coated PDA nanovesicles is qualitatively similar to that observed for the uncoated PDA nanovesicles but bears no resemblance to that observed in silver nanoparticles. The presence of silver nanoparticles increases the $\\gamma$ values of the coated nanovesicles slightly as compared to that of the uncoated nanovesicles, suggesting a definite but weak coupling between the free electrons of the metal nanoparticles and $\\pi$ electrons of the polymer in the composite system. Our comparative studies show that the arrangement of polymer chains in polydiacetylene nanocrystals is more favourable for higher nonlinearity.

  7. On the Influence of Contextual Factors on the Meaning Construction of Chained Metonymy%论连锁转喻的语境取义

    Institute of Scientific and Technical Information of China (English)

    李克; 李淑康

    2011-01-01

    连锁转喻是一种特殊的语言现象,是转喻现象无所不在的表现。连锁转喻是两个甚至更多的转喻操作有规律地出现在同一个语段甚至是同一个句子中等分析层面上的现象。研究表明,连锁转喻的意义依赖于语境。言内语境、情景语境、认知语境对连锁转喻意义的推理起着重要的作用。%Chained metonymy,a special linguistic phenomenon,shows the ubiquity feature of metonymy.It is a linguistic phenomenon that at least two metonymic operations regularly appear in the same text or sentence.Researches have shown the dependence of the meaning

  8. Long-chain polyunsaturated fatty acids (LCPUFA) from genesis to senescence: the influence of LCPUFA on neural development, aging, and neurodegeneration.

    Science.gov (United States)

    Janssen, Carola I F; Kiliaan, Amanda J

    2014-01-01

    Many clinical and animal studies demonstrate the importance of long-chain polyunsaturated fatty acids (LCPUFA) in neural development and neurodegeneration. This review will focus on involvement of LCPUFA from genesis to senescence. The LCPUFA docosahexaenoic acid and arachidonic acid are important components of neuronal membranes, while eicosapentaenoic acid, docosahexaenoic acid, and arachidonic acid also affect cardiovascular health and inflammation. In neural development, LCPUFA deficiency can lead to severe disorders like schizophrenia and attention deficit hyperactivity disorder. Perinatal LCPUFA supplementation demonstrated beneficial effects in neural development in humans and rodents resulting in improved cognition and sensorimotor integration. In normal aging, the effect of LCPUFA on prevention of cognitive impairment will be discussed. LCPUFA are important for neuronal membrane integrity and function, and also contribute in prevention of brain hypoperfusion. Cerebral perfusion can be compromised as result of obesity, cerebrovascular disease, hypertension, or diabetes mellitus type 2. Last, we will focus on the role of LCPUFA in most common neurodegenerative diseases like Alzheimer's disease and Parkinson's disease. These disorders are characterized by impaired cognition and connectivity and both clinical and animal supplementation studies have shown the potential of LCPUFA to decrease neurodegeneration and inflammation. This review shows that LCPUFA are essential throughout life.

  9. Overexpression of Arabidopsis ECERIFERUM1 promotes wax very-long-chain alkane biosynthesis and influences plant response to biotic and abiotic stresses.

    Science.gov (United States)

    Bourdenx, Brice; Bernard, Amélie; Domergue, Frédéric; Pascal, Stéphanie; Léger, Amandine; Roby, Dominique; Pervent, Marjorie; Vile, Denis; Haslam, Richard P; Napier, Johnathan A; Lessire, René; Joubès, Jérôme

    2011-05-01

    Land plant aerial organs are covered by a hydrophobic layer called the cuticle that serves as a waterproof barrier protecting plants against desiccation, ultraviolet radiation, and pathogens. Cuticle consists of a cutin matrix as well as cuticular waxes in which very-long-chain (VLC) alkanes are the major components, representing up to 70% of the total wax content in Arabidopsis (Arabidopsis thaliana) leaves. However, despite its major involvement in cuticle formation, the alkane-forming pathway is still largely unknown. To address this deficiency, we report here the characterization of the Arabidopsis ECERIFERUM1 (CER1) gene predicted to encode an enzyme involved in alkane biosynthesis. Analysis of CER1 expression showed that CER1 is specifically expressed in the epidermis of aerial organs and coexpressed with other genes of the alkane-forming pathway. Modification of CER1 expression in transgenic plants specifically affects VLC alkane biosynthesis: waxes of TDNA insertional mutant alleles are devoid of VLC alkanes and derivatives, whereas CER1 overexpression dramatically increases the production of the odd-carbon-numbered alkanes together with a substantial accumulation of iso-branched alkanes. We also showed that CER1 expression is induced by osmotic stresses and regulated by abscisic acid. Furthermore, CER1-overexpressing plants showed reduced cuticle permeability together with reduced soil water deficit susceptibility. However, CER1 overexpression increased susceptibility to bacterial and fungal pathogens. Taken together, these results demonstrate that CER1 controls alkane biosynthesis and is highly linked to responses to biotic and abiotic stresses.

  10. Structure-Function Analysis of the Non-Muscle Myosin Light Chain Kinase (nmMLCK) Isoform by NMR Spectroscopy and Molecular Modeling: Influence of MYLK Variants.

    Science.gov (United States)

    Shen, Kui; Ramirez, Benjamin; Mapes, Brandon; Shen, Grace R; Gokhale, Vijay; Brown, Mary E; Santarsiero, Bernard; Ishii, Yoshitaka; Dudek, Steven M; Wang, Ting; Garcia, Joe G N

    2015-01-01

    The MYLK gene encodes the multifunctional enzyme, myosin light chain kinase (MLCK), involved in isoform-specific non-muscle and smooth muscle contraction and regulation of vascular permeability during inflammation. Three MYLK SNPs (P21H, S147P, V261A) alter the N-terminal amino acid sequence of the non-muscle isoform of MLCK (nmMLCK) and are highly associated with susceptibility to acute lung injury (ALI) and asthma, especially in individuals of African descent. To understand the functional effects of SNP associations, we examined the N-terminal segments of nmMLCK by 1H-15N heteronuclear single quantum correlation (HSQC) spectroscopy, a 2-D NMR technique, and by in silico molecular modeling. Both NMR analysis and molecular modeling indicated SNP localization to loops that connect the immunoglobulin-like domains of nmMLCK, consistent with minimal structural changes evoked by these SNPs. Molecular modeling analysis identified protein-protein interaction motifs adversely affected by these MYLK SNPs including binding by the scaffold protein 14-3-3, results confirmed by immunoprecipitation and western blot studies. These structure-function studies suggest novel mechanisms for nmMLCK regulation, which may confirm MYLK as a candidate gene in inflammatory lung disease and advance knowledge of the genetic underpinning of lung-related health disparities.

  11. An Assessment of the Influence of the Industry Distribution Chain on the Oxygen Levels in Commercial Modified Atmosphere Packaged Cheddar Cheese Using Non-Destructive Oxygen Sensor Technology

    Directory of Open Access Journals (Sweden)

    Karen A.M. O’ Callaghan

    2016-06-01

    Full Text Available The establishment and control of oxygen levels in packs of oxygen-sensitive food products such as cheese is imperative in order to maintain product quality over a determined shelf life. Oxygen sensors quantify oxygen concentrations within packaging using a reversible optical measurement process, and this non-destructive nature ensures the entire supply chain can be monitored and can assist in pinpointing negative issues pertaining to product packaging. This study was carried out in a commercial cheese packaging plant and involved the insertion of 768 sensors into 384 flow-wrapped cheese packs (two sensors per pack that were flushed with 100% carbon dioxide prior to sealing. The cheese blocks were randomly assigned to two different storage groups to assess the effects of package quality, packaging process efficiency, and handling and distribution on package containment. Results demonstrated that oxygen levels increased in both experimental groups examined over the 30-day assessment period. The group subjected to a simulated industrial distribution route and handling procedures of commercial retailed cheese exhibited the highest level of oxygen detected on every day examined and experienced the highest rate of package failure. The study concluded that fluctuating storage conditions, product movement associated with distribution activities, and the possible presence of cheese-derived contaminants such as calcium lactate crystals were chief contributors to package failure.

  12. An Assessment of the Influence of the Industry Distribution Chain on the Oxygen Levels in Commercial Modified Atmosphere Packaged Cheddar Cheese Using Non-Destructive Oxygen Sensor Technology.

    Science.gov (United States)

    O' Callaghan, Karen A M; Papkovsky, Dmitri B; Kerry, Joseph P

    2016-06-20

    The establishment and control of oxygen levels in packs of oxygen-sensitive food products such as cheese is imperative in order to maintain product quality over a determined shelf life. Oxygen sensors quantify oxygen concentrations within packaging using a reversible optical measurement process, and this non-destructive nature ensures the entire supply chain can be monitored and can assist in pinpointing negative issues pertaining to product packaging. This study was carried out in a commercial cheese packaging plant and involved the insertion of 768 sensors into 384 flow-wrapped cheese packs (two sensors per pack) that were flushed with 100% carbon dioxide prior to sealing. The cheese blocks were randomly assigned to two different storage groups to assess the effects of package quality, packaging process efficiency, and handling and distribution on package containment. Results demonstrated that oxygen levels increased in both experimental groups examined over the 30-day assessment period. The group subjected to a simulated industrial distribution route and handling procedures of commercial retailed cheese exhibited the highest level of oxygen detected on every day examined and experienced the highest rate of package failure. The study concluded that fluctuating storage conditions, product movement associated with distribution activities, and the possible presence of cheese-derived contaminants such as calcium lactate crystals were chief contributors to package failure.

  13. Influence of the Extinction Ratio on the Intrachannel Nonlinear Distortion of 40-Gb/s Return-to-Zero Transmission Systems Over Standard Fiber

    Science.gov (United States)

    Fonseca, Daniel; Cartaxo, Adolfo V. T.; Monteiro, Paulo P.

    2007-06-01

    The impact of the extinction ratio (ER) on the performance of a 40-Gb/s return-to-zero transmission system over standard single-mode fiber (SSMF) is presented. Several dispersion maps are analyzed in order to minimize the distortion due to the intrachannel nonlinear effects, namely, intrachannel cross-phase modulation and intrachannel four wave mixing (IFWM). The decrease of the ER until a specific value leads to an increase of the intensity distortion, which is mainly due to IFWM. As a consequence, two distinct transmission regimes are identified, depending on the input average power of each section and the ER of the optical signals. The first regime has previously been called the pseudolinear regime in the literature and occurs when high ERs are considered. The optimum dispersion map of this regime has a given optical precompensation and a total residual dispersion near zero. The second regime occurs with the decrease of the ER. Under such a circumstance, the optimum dispersion map obtained in the pseudolinear regime leads to significant degradation, which is mainly due to ghost pulses appearing in the symbol “0.” This effect can be reduced by a system with residual dispersion that is significantly different from zero, leading to a detected eye pattern with low degradation in the symbol “0” but high timing jitter, which limits the use of such signals in feasible transmission systems. We call this new regime pseudosolitonic as the intrachannel nonlinear effects are apparently reduced by the residual group velocity dispersion (as it is observed in the solitonic regime occurring at lower bit rates), but strong waveform degradation occurs along the SSMF transmission. The exact value of ER for which the change between the two transmission regimes is observed depends on the optical average power at the input of each section. A simple expression to predict the system conditions (namely, ER, input average power of each section, and number of sections) for which

  14. Nonlinear photoacoustic spectroscopy of hemoglobin

    Energy Technology Data Exchange (ETDEWEB)

    Danielli, Amos; Maslov, Konstantin; Favazza, Christopher P.; Xia, Jun; Wang, Lihong V., E-mail: LHWANG@WUSTL.EDU [Optical Imaging Laboratory, Department of Biomedical Engineering, Washington University in St. Louis, One Brookings Drive, St. Louis, Missouri 63130 (United States)

    2015-05-18

    As light intensity increases in photoacoustic imaging, the saturation of optical absorption and the temperature dependence of the thermal expansion coefficient result in a measurable nonlinear dependence of the photoacoustic (PA) signal on the excitation pulse fluence. Here, under controlled conditions, we investigate the intensity-dependent photoacoustic signals from oxygenated and deoxygenated hemoglobin at varied optical wavelengths and molecular concentrations. The wavelength and concentration dependencies of the nonlinear PA spectrum are found to be significantly greater in oxygenated hemoglobin than in deoxygenated hemoglobin. These effects are further influenced by the hemoglobin concentration. These nonlinear phenomena provide insights into applications of photoacoustics, such as measurements of average inter-molecular distances on a nm scale or with a tuned selection of wavelengths, a more accurate quantitative PA tomography.

  15. The influence of design characteristics on statistical inference in nonlinear estimation: A simulation study based on survival data and hazard modeling

    DEFF Research Database (Denmark)

    Andersen, J.S.; Bedaux, J.J.M.; Kooijman, S.A.L.M.;

    2000-01-01

    This paper describes the influence of design characteristics on the statistical inference for an ecotoxicological hazard-based model using simulated survival data. The design characteristics of interest are the number and spacing of observations (counts) in time, the number and spacing of exposure...

  16. Iodine release and recovery, influence of polyiodide anions on electrical conductivity and nonlinear optical activity in an interdigitated and interpenetrated bipillared-bilayer metal-organic framework.

    Science.gov (United States)

    Yin, Zheng; Wang, Qiang-Xin; Zeng, Ming-Hua

    2012-03-14

    {[Cu6(pybz)8(OH)2]·I5(–)·I7(–)}n (1), obtained hydrothermally by using iodine molecules as a versatile precursor template, consists of a cationic framework with two types of zigzag channels, which segregate I5(–) and I7(–) anions. The framework exhibits the first observed bipillared-bilayer structure featuring both interdigitation and interpenetration. 1 displays high framework stability in both acidic (HCl) and alkaline (NaOH) solutions. 1 slowly releases iodine in dry methanol to give [Cu6(pybz)8(OH)2](I–)2·3.5CH3OH (1′) and partially recovers iodine from cyclohexane to form [Cu6(pybz)8(OH)2](I–)2·xI2 (1″). Differences of up to 100 times in electrical conductivity and of 4 times in nonlinear optical activity (NLO) have been measured between 1 and 1′. This compound is one of few displaying multifunctionality, electrical conductivity, NLO, and crystal–crystal stability upon release and recovery of iodine. It is also unique in the iodine release from polyiodide anions in a metal–organic framework.

  17. Sterile DJH rearrangements reveal that distance between gene segments on the human Ig H chain locus influences their ability to rearrange

    DEFF Research Database (Denmark)

    Hansen, Tina Østergaard; Lange, Anders Blaabjerg; Barington, Torben

    2015-01-01

    Rearrangement of the Ig locus occurs in two steps. First, a JH gene is rearranged to a D gene followed by a VH gene rearranging to the DJH rearrangement. By next generation sequencing, we analyzed 9969 unique DJH rearrangements and 5919 unique VHDJH rearrangements obtained from peripheral blood B...... frequently than JH locus distal D genes, whereas VH locus proximal D genes were observed more frequently in nonproductive VHDJH rearrangements. We further demonstrate that the distance between VH, D, and JH gene segments influence their ability to rearrange within the human Ig locus....

  18. Influence of sodium chloride on the regulation of Krebs cycle intermediates and enzymes of respiratory chain in mungbean (Vigna radiata L. Wilczek) seedlings.

    Science.gov (United States)

    Saha, Papiya; Kunda, Pranamita; Biswas, Asok K

    2012-11-01

    The effect of common salt (NaCl) on ion contents, Krebs cycle intermediates and its regulatory enzymes was investigated in growing mungbean (Vigna radiata L. Wilczek, B 105) seedlings. Sodium and chloride ion contents increased in both root and shoot whereas potassium ion content decreased in shoot of test seedlings with increasing concentrations of NaCl. Organic acids like pyruvate and citrate levels increased whereas malate level decreased under stress in both roots and shoots. Salt stress also variedly affected the activities of different enzymes of respiratory chain. The activity of pyruvate dehydrogenase (E.C. 1.2.4.1) decreased in 50 mM NaCl but increased in 100 mM and 150 mM concentrations, in both root and shoot samples. Succinate dehydrogenase (E.C. 1.3.5.1) activity was reduced in root whereas stimulated in shoot under increasing concentrations of salt. The activity of isocitrate dehydrogenase (E.C. 1.1.1.41) and malate dehydrogenase (E.C. 1.1.1.37) decreased in both root and shoot samples under salt stress. On the contrary, pretreatment of mungbean seeds with sublethal dose of NaCl was able to overcome the adverse effects of stress imposed by NaCl to variable extents with significant alterations of all the tested parameters, resulting in better growth and efficient respiration in mungbean seedlings. Thus, plants can acclimate to lethal level of salinity by pretreatment of seeds with sublethal level of NaCl, which serves to improve their health and production under saline condition, but the sublethal concentration of NaCl should be carefully chosen.

  19. Influence Study of After-sale Warranty Period on Supply Chain Benefits%售后质保期对供应链效益的影响研究

    Institute of Scientific and Technical Information of China (English)

    施冰燕; 申开凤

    2016-01-01

    产品售后质保服务已经成为影响供应链收益的重要因素.我们旨在研究二级单渠道供应链下,以质保期为决策变量的最优决策问题.研究将质保期对产品需求量的影响,以及随着产品上市时间推移,质保期对产品需求量影响减弱的情况纳入考虑范围.质保使用免费维修质保策略,并假设产品故障率随时间变化服从威布尔分布.在完整建模的基础上,使用最大化原理,对模型进行求解并进行数值分析,最后对研究结论和未来研究方向进行讨论.研究发现,制造商制定变动质保期时,收益达到最大化.因此,制造商有积极性依据质保期对产品需求量的影响规律分阶段制定质保期.%After-sale quality assurance services of products have been an important factor which has influ-ences on supply chain benefits.We are aimed to study the optimal decisions by taking warranty period as decision variable in the two-stage single channel supply chain.The influences of warranty period on product demands are studied.Besides,the weakened influences of warranty period on product demands over time af-ter the products are in the market are also taken into consideration.Quality assurance uses the strategy of free maintenance and quality assurance by assuming changes of failure rate of products obey Weibull distri-bution over time.Based on a complete model,solutions and numerical analysis on the model are conducted by using maximization principles.At last,this thesis discusses the research conclusion and the future re-search direction.The research finds out that manufactures can formulate variable warranty period to achieve maximized benefits.Therefore,manufactures have motivation to formulate warranty period by stages based on the influence rules of warranty period on product demands.

  20. Modelling proton transfer in water molecule chains

    CERN Document Server

    Korzhimanov, Artem; Shutova, Tatiana; Samuelsson, Goran

    2011-01-01

    The process of protons transport in molecular water chains is of fundamental interest for many biological systems. Although many features of such systems can be analyzed using large-scale computational modeling, other features are better understood in terms of simplified model problems. Here we have tested, analytically and numerically, a model describing the classical proton hopping process in molecular water chains. In order to capture the main features of the proton hopping process in such molecular chains, we use a simplified model for our analysis. In particular, our discrete model describes a 1D chain of water molecules situated in an external protein channel structure, and each water molecule is allowed to oscillate around its equilibrium point in this system, while the protons are allowed to move along the line of neighboring oxygen atoms. The occurrence and properties of nonlinear solitary transport structures, allowing for much faster proton transport, are discussed, and the possible implications of...

  1. Microbial community adaptation influences long-chain fatty acid conversion during anaerobic codigestion of fats, oils, and grease with municipal sludge.

    Science.gov (United States)

    Ziels, Ryan M; Karlsson, Anna; Beck, David A C; Ejlertsson, Jörgen; Yekta, Sepehr Shakeri; Bjorn, Annika; Stensel, H David; Svensson, Bo H

    2016-10-15

    Codigesting fats, oils, and greases with municipal wastewater sludge can greatly improve biomethane recovery at wastewater treatment facilities. Process loading rates of fats, oils, and greases have been previously tested with little knowledge of the digester microbial community structure, and high transient fat loadings have led to long chain fatty acid (LCFA) accumulation and digester upsets. This study utilized recently-developed quantitative PCR assays for syntrophic LCFA-degrading bacteria along with 16S amplicon sequencing to relate changes in microbial community structure to LCFA accumulation during transient loading increases to an anaerobic codigester receiving waste restaurant oil and municipal wastewater sludge. The 16S rRNA gene concentration of the syntrophic β-oxidizing genus Syntrophomonas increased to ∼15% of the Bacteria community in the codigester, but stayed below 3% in the control digester that was fed only wastewater sludge. Methanosaeta and Methanospirillum were the dominant methanogenic genera enriched in the codigester, and together comprised over 80% of the Archaea community by the end of the experimental period. Constrained ordination showed that changes in the codigester Bacteria and Archaea community structures were related to measures of digester performance. Notably, the effluent LCFA concentration in the codigester was positively correlated to the specific loading rate of waste oil normalized to the Syntrophomonas 16S rRNA concentration. Specific loading rates of 0-1.5 × 10(-12) g VS oil/16S gene copies-day resulted in LCFA concentrations below 30 mg/g TS, whereas LCFA accumulated up to 104 mg/g TS at higher transient loading rates. Based on the community-dependent loading limitations found, enhanced biomethane production from high loadings of fats, oils and greases can be achieved by promoting a higher biomass of slow-growing syntrophic consortia, such as with longer digester solids retention times. This work also

  2. Electronic properties of aperiodic quantum dot chains

    Science.gov (United States)

    Korotaev, P. Yu.; Vekilov, Yu. Kh.; Kaputkina, N. E.

    2012-04-01

    The electronic spectral and transport properties of aperiodic quantum dot chains are investigated. The systems with singular continuous energy spectrum are considered: Thue-Morse chain, double-periodic chain, Rudin-Shapiro chain. The influence of electronic energy in quantum dot on the spectral properties, band structure, density of states and spectral resistivity, is discussed. Low resistivity regions correspond to delocalized states and these states could be current states. Also we discuss the magnetic field application as the way to tune electronic energy in quantum dot and to obtain metallic or insulating conducting states of the systems.

  3. Nonlinear organic plasmonics

    CERN Document Server

    Fainberg, B D

    2015-01-01

    Purely organic materials with negative and near-zero dielectric permittivity can be easily fabricated. Here we develop a theory of nonlinear non-steady-state organic plasmonics with strong laser pulses. The bistability response of the electron-vibrational model of organic materials in the condensed phase has been demonstrated. Non-steady-state organic plasmonics enable us to obtain near-zero dielectric permittivity during a short time. We have proposed to use non-steady-state organic plasmonics for the enhancement of intersite dipolar energy-transfer interaction in the quantum dot wire that influences on electron transport through nanojunctions. Such interactions can compensate Coulomb repulsions for particular conditions. We propose the exciton control of Coulomb blocking in the quantum dot wire based on the non-steady-state near-zero dielectric permittivity of the organic host medium.

  4. Energy localization in weakly dissipative resonant chains

    Science.gov (United States)

    Kovaleva, Agnessa

    2016-08-01

    Localization of energy in oscillator arrays has been of interest for a number of years, with special attention paid to the role of nonlinearity and discreteness in the formation of localized structures. This work examines a different type of energy localization arising due to the presence of dissipation in nonlinear resonance arrays. As a basic model, we consider a Klein-Gordon chain of finite length subjected to a harmonic excitation applied at an edge of the chain. It is shown that weak dissipation may be a key factor preventing the emergence of resonance in the entire chain, even if its nondissipative analog is entirely captured into resonance. The resulting process in the dissipative oscillator array represents large-amplitude resonant oscillations in a part of the chain adjacent to the actuator and small-amplitude oscillations in the distant part of the chain. The conditions of the emergence of resonance as well as the conditions of energy localization are derived. An agreement between the obtained analytical results and numerical simulations is demonstrated.

  5. TERMINATION AND TRANSFER OF THE CHAIN RADICALS IN THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY VANADIUM(V)-THIOUREA REDOX SYSTEM

    Institute of Scientific and Technical Information of China (English)

    WU Jinyuan; YANG Chaoxiong; WU Yuxian

    1990-01-01

    The dependence of the molecular weights on the concentration of reactants in the polymerization of acrylonitrile initiated by vanadium (V)-thiourea red ox system has been investigated. It was found that the molecular weights of the polymer change nonlinearly with increasing concentrations of nitric acid and thiourea. Probably, the composition of the complexes exert a great influence on the chain initiation and termination. The reaction of "complextermination " gives rise to the decrease of the molecular weights markedly while the concentrations of thiourea and vanadium (V)in the range from one to three molar ratios.

  6. Logistic chain modelling

    NARCIS (Netherlands)

    Slats, P.A.; Bhola, B.; Evers, J.J.M.; Dijkhuizen, G.

    1995-01-01

    Logistic chain modelling is very important in improving the overall performance of the total logistic chain. Logistic models provide support for a large range of applications, such as analysing bottlenecks, improving customer service, configuring new logistic chains and adapting existing chains to n

  7. Health supply chain management.

    Science.gov (United States)

    Zimmerman, Rolf; Gallagher, Pat

    2010-01-01

    This chapter gives an educational overview of: * The actual application of supply chain practice and disciplines required for service delivery improvement within the current health environment. * A rationale for the application of Supply Chain Management (SCM) approaches to the Health sector. * The tools and methods available for supply chain analysis and benchmarking. * Key supply chain success factors.

  8. Multiplicity of ground state solutions for discrete nonlinear Schrodinger equations with unbounded potentials

    Directory of Open Access Journals (Sweden)

    Xia Liu

    2017-02-01

    Full Text Available The discrete nonlinear Schrodinger equation is a nonlinear lattice system that appears in many areas of physics such as nonlinear optics, biomolecular chains and Bose-Einstein condensates. In this article, we consider a class of discrete nonlinear Schrodinger equations with unbounded potentials. We obtain some new sufficient conditions on the multiplicity results of ground state solutions for the equations by using the symmetric mountain pass lemma. Recent results in the literature are greatly improved.

  9. Nonlinear electronic transport behavior in Indium Nitride

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Cloves G., E-mail: cloves@pucgoias.edu.br [Departamento de Fisica, Pontificia Universidade Catolica de Goias, CP 86, 74605-010 Goiania, Goias (Brazil)

    2012-11-15

    A theoretical study on the nonlinear transport of electrons and of the nonequilibrium temperature in n-doped Indium Nitride under influence of moderate to high electric fields (in this nonlinear domain) is presented. It is based on a nonlinear quantum kinetic theory which provides a description of the dissipative phenomena developing in the system. The electric current and the mobility in the steady state are obtained, and their dependence on the electric field strength and on the concentration (that is, a mobility dependent nonlinearly on field and concentration) is obtained and analyzed. -- Highlights: Black-Right-Pointing-Pointer We have reported on the topic of nonlinear transport (electron mobility) in n-doped InN. Black-Right-Pointing-Pointer The results evidence the presence of two distinctive regimes. Black-Right-Pointing-Pointer The dependence of the mobility on the electric field is manifested through of the relaxation times.

  10. Network science, nonlinear science and infrastructure systems

    CERN Document Server

    2007-01-01

    Network Science, Nonlinear Science and Infrastructure Systems has been written by leading scholars in these areas. Its express purpose is to develop common theoretical underpinnings to better solve modern infrastructural problems. It is felt by many who work in these fields that many modern communication problems, ranging from transportation networks to telecommunications, Internet, supply chains, etc., are fundamentally infrastructure problems. Moreover, these infrastructure problems would benefit greatly from a confluence of theoretical and methodological work done with the areas of Network Science, Dynamical Systems and Nonlinear Science. This book is dedicated to the formulation of infrastructural tools that will better solve these types of infrastructural problems. .

  11. Nonlinear Phononic Periodic Structures and Granular Crystals

    Science.gov (United States)

    2012-02-10

    of the advanced delay equation (13) and they compared the numerically obtained solutions with those of approximated PDEs. Recently, Starosvetsky... KdV ), a nonlinear partial differential equation , and have been discovered in myriad systems and discrete nonlinear lattices of all the above types...granular chain, and derived the following KdV equation : t 0 0 1/2 2 2 2 2 0 0 0 0 0 0, 2 6 , , . 6 xx x xc uc A R c R c Rc m σξ ξ γξ ξξ ξ δ γ σ δ

  12. MARKOV CHAIN PORTFOLIO LIQUIDITY OPTIMIZATION MODEL

    Directory of Open Access Journals (Sweden)

    Eder Oliveira Abensur

    2014-05-01

    Full Text Available The international financial crisis of September 2008 and May 2010 showed the importance of liquidity as an attribute to be considered in portfolio decisions. This study proposes an optimization model based on available public data, using Markov chain and Genetic Algorithms concepts as it considers the classic duality of risk versus return and incorporating liquidity costs. The work intends to propose a multi-criterion non-linear optimization model using liquidity based on a Markov chain. The non-linear model was tested using Genetic Algorithms with twenty five Brazilian stocks from 2007 to 2009. The results suggest that this is an innovative development methodology and useful for developing an efficient and realistic financial portfolio, as it considers many attributes such as risk, return and liquidity.

  13. Kinetic Chain Rehabilitation: A Theoretical Framework

    Directory of Open Access Journals (Sweden)

    Aaron Sciascia

    2012-01-01

    Full Text Available Sequenced physiologic muscle activations in the upper and lower extremity result in an integrated biomechanical task. This sequencing is known as the kinetic chain, and, in upper extremity dominant tasks, the energy development and output follows a proximal to distal sequencing. Impairment of one or more kinetic chain links can create dysfunctional biomechanical output leading to pain and/or injury. When deficits exist in the preceding links, they can negatively affect the shoulder. Rehabilitation of shoulder injuries should involve evaluation for and restoration of all kinetic chain deficits that may hinder kinetic chain function. Rehabilitation programs focused on eliminating kinetic chain deficits, and soreness should follow a proximal to distal rationale where lower extremity impairments are addressed in addition to the upper extremity impairments. A logical progression focusing on flexibility, strength, proprioception, and endurance with kinetic chain influence is recommended.

  14. Kinetic chain rehabilitation: a theoretical framework.

    Science.gov (United States)

    Sciascia, Aaron; Cromwell, Robin

    2012-01-01

    Sequenced physiologic muscle activations in the upper and lower extremity result in an integrated biomechanical task. This sequencing is known as the kinetic chain, and, in upper extremity dominant tasks, the energy development and output follows a proximal to distal sequencing. Impairment of one or more kinetic chain links can create dysfunctional biomechanical output leading to pain and/or injury. When deficits exist in the preceding links, they can negatively affect the shoulder. Rehabilitation of shoulder injuries should involve evaluation for and restoration of all kinetic chain deficits that may hinder kinetic chain function. Rehabilitation programs focused on eliminating kinetic chain deficits, and soreness should follow a proximal to distal rationale where lower extremity impairments are addressed in addition to the upper extremity impairments. A logical progression focusing on flexibility, strength, proprioception, and endurance with kinetic chain influence is recommended.

  15. INVESTIGATION ON THE JOB BURNOUT OF EMPLOYEES FROM SUPERMARKET CHAINS AND ITS INFLUENCING FACTORS%连锁超市员工职业倦怠现状与影响因素研究

    Institute of Scientific and Technical Information of China (English)

    贾凤芹; 葛晓娜; 冯成志

    2011-01-01

    [目的] 了解连锁超市员工职业倦怠现状与影响因素.[方法] 采用Maslach职业倦怠量表通用版(MBI-GS)对连云港市360名连锁超市员工进行调查,通过Logistic回归分析筛选出职业倦怠的主要影响因素.[结果]①总体上连锁超市员工存在中等程度的职业倦怠.② 20岁以下、工作1年以内员工的情感耗竭、消极怠慢程度高于其他员工;离异或丧偶员工职业倦怠程度最高,其次为已婚员工;与超市其他工作岗位相比,促销员职业倦怠程度最高.③Logistic回归分析显示年龄、工龄、婚姻状况与工作岗位与超市员工职业倦怠有关.[结论]连锁超市员工存在中等程度的职业倦怠;职业与岗位特征、年龄、婚姻状况等人口学变量以及个体认知与组织因素对连锁超市员工职业倦怠程度有重要影响.应从组织和个人两个层面采用有效的干预策略来预防或缓解连锁超市员工的职业倦怠.%[Objective] To investigate the job burnout status of employees from supermarker chains.[Methods]360 supermarket staff in Lianyungang was assessde by MBI-GS.[Results]①Overall employees from supermarket chains had mediun serious degree of job vurnout.②Employess who were younger than 20 years old and worked for 0-1 rears experienced higher emorional exhaustion and depersonalization;Unmarried supermarker staff experienced the loest emorional exhaustion; The job burmout of salesman was significantly higher than other groups.③Logistic regtession analysis indicated that the major factors contributed to the job burnout were characterisitics of job,personal understanding of job,management style,age and marriage Status.[Conclusion]Emplyess from supermarker chains have medium serious degeree of job burnout.The characteristics of job,age,marriage Status,personal uderstanding of job and management style influenced the degree of job burnout.Therefore,supermarket chains and employees should use some measures to

  16. On the influence of local fluctuations in volume fraction of constituents on the effective properties of nonlinear composites. Application to porous materials

    Science.gov (United States)

    Gărăjeu, M.; Suquet, P.

    2007-04-01

    Composite materials often exhibit local fluctuations in the volume fraction of their individual constituents. This paper studies the influence of such small fluctuations on the effective properties of composites. A general asymptotic expansion of these properties in terms of powers of the amplitude of the fluctuations is given first. Then, this general result is applied to porous materials. As is well-known, the effective yield surface of ductile voided materials is accurately described by Gurson's criterion. Suitable extensions for viscoplastic solids have also been proposed. The question addressed in the present study pertains to nonuniform distributions of voids in a typical volume element or in other words to the presence of matrix-rich and pore-rich zones in the material. It is shown numerically and analytically that such deviations from a uniform distribution result in a weakening of the macroscopic carrying capacity of the material.

  17. Third-order nonlinear optical properties of spin-coating films containing benzo[α]phenoxazinium: from reverse saturated to saturated absorptions

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fei [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Fang, Yu [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Sun, Ru; Guo, Xiao-Zhi [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Song, Ying-Lin [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Ge, Jian-Feng, E-mail: ge_jianfeng@hotmail.com [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Jiangsu Key Laboratory of Medical Optics, Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China)

    2015-08-31

    The optical films based on poly(4-vinylphenol) and benzo[α]phenoxazinium dye with a long alkyl chain were obtained by spin-coating, and their optical properties are reported in this paper. UV–vis absorptions of the optical films showed that the absorption maxima were shifted about 40 nm by the influence of dye aggregation with increasing dye ratio. The third-order nonlinear optical properties of films were tested by Z-scan technique with a picosecond laser beam at 532 nm. The third-order nonlinear optical susceptibilities and second hyperpolarizabilities were up to 10{sup −10} and 10{sup −32} esu respectively. Meanwhile, the third-order nonlinear absorptions transformed from reverse saturated absorptions to saturated absorptions with increasing ratios of dye in doped films. The result of aggregation induced adjustable third-order nonlinear absorption can be confirmed from their TEM images. - Highlights: • Benzo[α]phenoxazinium containing optical films with poly(4-vinylphenol). • Optical property was influenced by dye aggregation. • The third-order nonlinear absorptions transformed from reverse saturated absorptions to saturated absorptions with increasing ratios of dye.

  18. Nonlinear modeling of an aerospace object dynamics

    Science.gov (United States)

    Davydov, I. E.; Davydov, E. I.

    2017-01-01

    Here are presented the scientific results, obtained by motion modeling of complicated technical systems of aerospace equipment with consideration of nonlinearities. Computerized panel that allows to measure mutual influence of the system's motion and stabilization device with consideration of its real characteristics has been developed. Analysis of motion stability of a system in general has been carried out and time relationships of the system's motion taking in account nonlinearities are presented.

  19. Influence of Transportation Conditions and Postharvest Disinfection Treatments on Microbiological Quality of Fresh Market Tomatoes (cv. Nemo-Netta) in a South African Supply Chain.

    Science.gov (United States)

    Sibomana, M S; Ziena, L W; Schmidt, S; Workneh, T S

    2017-02-01

    Postharvest microbial spoilage due to suboptimal transportation and packaging conditions is a key concern for the South African tomato industry. This study investigated the influence of washing with tap water or aqueous disinfectant solutions (chlorinated and anolyte water) on the microbiological quality of tomatoes during storage after transportation in nonrefrigerated trucks along two supply routes when packaged in crates and boxes. Route 1 was 1,093 km from field to storage site, while route 2 was 1,057 km. During transport, the temperature in the trucks fluctuated between 16 and 28°C and the relative humidity between 25 and 94% for route 1, while for route 2, the temperature was between 16 and 30°C and the relative humidity between 28 and 71%. Tomatoes at the pink maturity stage were sampled, treated, and stored for 28 days (11°C). The tomato firmness before treatment was 24.8 N (box samples) and 17.4 N (crate samples) for route 1, whereas it was 22.1 N (box samples) and 20.2 N (crate samples) for route 2. Temperature fluctuation during transportation led to water condensation on tomato surfaces. Tomatoes treated with anolyte water showed the lowest microbial surface burden during storage, with mean aerobic plate counts (APC) of 2.9 log CFU/cm(2), coliform counts (CC) of 1.1 log CFU/cm(2), and fungal counts (FC) of 2.3 log CFU/cm(2). Overall, of the total APC recorded during storage, anolyte-treated samples contributed 9% while chlorinated water-treated samples contributed 30%. Of the total CC, anolyte samples presented 3% while chlorinated water samples made up 12%, and of the total recorded FC, anolyte samples contributed 7% while chlorinated water samples made up 22%. Scanning electron microscopy imaging showed surface cracks, which enable microbial colonization in crate-transported tomatoes. A combination of anolyte treatment and box packaging during transport resulted in the best microbiological quality during storage. The findings of this investigation

  20. Structure of polymer chains under confinement

    Indian Academy of Sciences (India)

    Jyotsana Lal

    2008-11-01

    We observe by SANS the structure of neutral polystyrene and charged polystyrene sulphonate chains in semi-dilute solutions confined in a model nanoporous glass, Vycor. The size of the free chains in solution is always larger than the pore diameter, 70. The use of a suitable mixture of hydrogenated and deuterated solvents and polymers enables us to measure directly the form factor of one single chain among the others. Single chain form factor was observed both for bulk and confined chains using the condition of zero average contrast. Our measurements on neutral polymer chains are in agreement with the theoretical predictions established by Daoud and de Gennes for chains confined in a cylindrical pore when the chains are entangled and laterally squeezed but remain ideal at large scale along the cylinder axis because of the screening of the excluded volume interactions (so-called regime of ``semi-dilute cigars"). For confined charged polymers, a peak is observed whose intensity increases with molecular weight and the asymptotic 1/ scattering region is extended compared to the bulk. We infer that the chains are sufficiently extended, under the influence of confinement, to highlight the large scale disordered structure of Vycor even under contrast matched conditions. The asymptotic behaviour of the observed interchain structure factor is ≈ 1/2 and ≈ 1/ for free and confined chains respectively.

  1. Influence of resonator shape on nonlinear acoustic field in a thermoacoustic engine%谐振管形状对热声发动机内非线性声场的影响

    Institute of Scientific and Technical Information of China (English)

    刘丹晓; 周城光; 刘克

    2012-01-01

    The influence of the resonator shape on nonlinear acoustic field in a thermoacoustic engine is studied. The resonator of themoacoustic engine is boundary driving by a piston at one end, and the other end of it is rigid closed. A one-dimensional wave equation that accounts for gas dynamic nonlinearities and viscous dissipation in the resonator is established based on the governing equations of viscous hydromechanics. The nonlinear wave equation is solved using approximate Galerkin method. The nonlinear acoustic field in four different types of varying cross section resonators including hyperbolical, exponential, conical and sinusoidal are obtained and compared with that of a cylindrical resonator. It is found that the amplitude and waveform of pressure oscillations are strongly affected by the resonator shape, the driving amplitude and frequency of the piston. Waveform distortion, resonance frequency shift and hysteresis are observed, when the piston oscillation amplitude is large enough. The advantages of varying cross section resonator in thermoacoustic engine are revealed in inhibition of higher order harmonics, improvement of pressure ratio, etc.%研究了谐振管一端受活塞声源激励,另一端刚性封闭条件下,管道形状对热声发动机谐振管内部非线性声场的影响.基于流体力学基本方程建立了渐变截面谐振管内一维非线性声场的模型,考虑了黏性耗散及非线性效应的影响.利用伽辽金法数值求解了该模型的速度势方程,分析了谐振管形状、活塞振动速度及激励频率对管内声场的影响.将双曲形、指数形、锥形、正弦形等四种变截面谐振管内的非线性声场与圆柱形直管的情况进行了比较.结果反映了谐振管内声场的压力波动受活塞振动速度及谐振管形状的影响;显示了当活塞振动幅度较大时,谐振管内出现的波形畸变、频率曲线偏移、共振频率滞后等非线性现象;揭示了变截面谐

  2. Sustainable Supply Chain Design

    DEFF Research Database (Denmark)

    Bals, Lydia; Tate, Wendy

    to implement TBL goals across the supply chain. In supply chain design, the classic economic perspective still dominates, although the idea of the TBL is more widely disseminated. The purpose of this research is to add to the sustainable supply chain management literature (SSCM) research agenda......A significant conceptual and practical challenge is how to integrate triple bottom line (TBL; including economic, social and environmental) sustainability into global supply chains. Although this integration is necessary to slow down global resource depletion, understanding is limited of how...... by incorporating the physical chain, and the (information and financial) support chains into supply chain design. This manuscript tackles issues of what the chains are designed for and how they are designed structurally. Four sustainable businesses are used as illustrative case examples of innovative supply chain...

  3. Quality assurance in functioning of the supply chain

    OpenAIRE

    ЧУХРАЙ, Наталя Іванівна

    2012-01-01

    The influence of conception of total quality management (TQM) on functioning of supply chain is explained. The place of quality of processes and products in the supply chain is identified. Dependence of logistic effects on the level of quality in the supply chain is well-proven.

  4. Transport of nonlinearly biodegradable contaminants in aquifers

    OpenAIRE

    Keijzer, H.

    2001-01-01

    This thesis deals with the transport behavior of nonlinearly biodegradable contaminants in aquifers. Such transport occurs during in situ bioremediation which is based on the injection of an electron acceptor or electron donor. The main interests in this thesis are the mutual influences of underlying processes, i.e. transport, adsorption and biodegradation, and their influence on in situ bioremediation performance. To gain insight in these influences, the processes in a homogeneous aquifer ar...

  5. 磁悬浮运动中电磁铁磁滞特性的非线性影响研究%Study on the nonlinear influence of hysteresis characteristics of electromagnet in maglev movement

    Institute of Scientific and Technical Information of China (English)

    王文祝; 金丰; 周海波

    2013-01-01

    During the controlling of the ultra-precision maglev movement ,the hysteresis existed in the iron core and the armature guide is an important reason of making it hard to control precisely . It is significant to study the law of the hysteresis characteristics'nonlinear influence on the elec-tromagnetic force and build its nonlinear model .Through studying the hysteresis characteristics'influence on the air-gap magnetic flux density in the maglev precision movement and analyzing the hysteresis modeling theory of the magnetic circuit with an air gap ,the nonlinear electromagnetic force model including the Jiles-Atherton model was established and then its parameters were test-ed by the particle swarm optimization .Results show that the electromagnet hysteresis in the ma-glev precision movement should not be neglected .The air-gap magnetic flux density calculated by the identified new model is more precise and closer to the measured value than that calculated by the traditional model .These results provide an important reference for improving control preci-sion of the maglev precision movement .%  超精密磁悬浮运动控制中,电磁铁铁心及衔铁导轨中存在的磁滞特性是导致电磁力难以实现精确控制的重要原因之一。研究磁滞特性对电磁力的非线性影响规律并建立其非线性模型具有重要意义。通过研究磁悬浮精密运动中电磁铁磁滞特性对气隙处磁感应强度的影响,分析了带气隙磁路磁滞特性建模原理,建立了包含Jiles-Atherton模型的电磁铁磁浮力非线性模型,并采用粒子群优化算法对该模型参数进行实验验证。结果表明,磁悬浮精密运动中电磁铁磁滞特性不容忽视,采用经参数辨识得到的新模型比采用传统模型计算得到的气隙磁感应强度值更精确、更接近实测值。研究结果为提高磁悬浮精密运动中电磁力的精确控制提供了重要参考价值。

  6. Fiber Nonlinearities: A Tutorial

    Institute of Scientific and Technical Information of China (English)

    Govind P. Agrawal

    2003-01-01

    Fiber nonlinearities have long been regarded as being mostly harmful for fiber-optic communication systems. Over the last few years, however, the nonlinear effects are increasingly being used for practical telecommunications applications,the Raman amplification being only one of the recent examples. In this tutorial I review the vario us nonlinear effects occurring in optical fibers from both standpoints..

  7. Fiber Nonlinearities: A Tutorial

    Institute of Scientific and Technical Information of China (English)

    Govind; P.; Agrawal

    2003-01-01

    Fiber nonlinearities have long been regarded as being mostly harmful for fiber-optic communication systems. Over the last few years, however, the nonlinear effects are increasingly being used for practical telecommunications applications, the Raman amplification being only one of the recent examples. In this tutorial I review the various nonlinear effects occurring in optical fibers from both standpoints..

  8. Advances in nonlinear optics

    CERN Document Server

    Chen, Xianfeng; Zeng, Heping; Guo, Qi; She, Weilong

    2015-01-01

    This book presents an overview of the state of the art of nonlinear optics from weak light nonlinear optics, ultrafast nonlinear optics to electro-optical theory and applications. Topics range from the fundamental studies of the interaction between matter and radiation to the development of devices, components, and systems of tremendous commercial interest for widespread applications in optical telecommunications, medicine, and biotechnology.

  9. Noncommutative Nonlinear Supersymmetry

    CERN Document Server

    Nishino, H; Nishino, Hitoshi; Rajpoot, Subhash

    2002-01-01

    We present noncommutative nonlinear supersymmetric theories. The first example is a non-polynomial Akulov-Volkov-type lagrangian with noncommutative nonlinear global supersymmetry in arbitrary space-time dimensions. The second example is the generalization of this lagrangian to Dirac-Born-Infeld lagrangian with nonlinear supersymmetry realized in dimensions D=2,3,4 and 6 (mod 8).

  10. Transmission through metallic chains: Role of distortions and contact geometry

    Energy Technology Data Exchange (ETDEWEB)

    Wunderlich, Thomas; Akgenc, Berna; Schuster, Cosima; Eckern, Ulrich [Institut fuer Physik, Universitaet Augsburg, 86135 (Germany)

    2010-07-01

    We present results of electronic structure and transport calculations for metallic chains, based on density functional theory and scattering theory combined with the the non-equilibrium Green's function technique. Starting from a simple model system of monovalent metallic chains we investigate the influence of distortions on the electronic structure and the transport properties of H and Li chains. Furthermore we calculate the electronic structure of Au chains which are contacted to leads via different geometries, and study the influence of the contact geometry on the transmission coefficient. In particular, we compare chains, pyramides and planes in the contact region. A comparison with analytical results is given.

  11. PBH tests for nonlinear systems

    NARCIS (Netherlands)

    Kawano, Yu; Ohtsuka, Toshiyuki

    2017-01-01

    Recently, concepts of nonlinear eigenvalues and eigenvectors are introduced. In this paper, we establish connections between the nonlinear eigenvalues and nonlinear accessibility/observability. In particular, we provide a generalization of Popov- Belevitch-Hautus (PBH) test to nonlinear accessibilit

  12. Nonlinear dynamics and complexity

    CERN Document Server

    Luo, Albert; Fu, Xilin

    2014-01-01

    This important collection presents recent advances in nonlinear dynamics including analytical solutions, chaos in Hamiltonian systems, time-delay, uncertainty, and bio-network dynamics. Nonlinear Dynamics and Complexity equips readers to appreciate this increasingly main-stream approach to understanding complex phenomena in nonlinear systems as they are examined in a broad array of disciplines. The book facilitates a better understanding of the mechanisms and phenomena in nonlinear dynamics and develops the corresponding mathematical theory to apply nonlinear design to practical engineering.

  13. Blow-up of a hyperbolic equation of viscoelasticity with supercritical nonlinearities

    Science.gov (United States)

    Guo, Yanqiu; Rammaha, Mohammad A.; Sakuntasathien, Sawanya

    2017-02-01

    We investigate a hyperbolic PDE, modeling wave propagation in viscoelastic media, under the influence of a linear memory term of Boltzmann type, and a nonlinear damping modeling friction, as well as an energy-amplifying supercritical nonlinear source:

  14. Disordered ground states in a quantum frustrated spin chain with side chains

    Science.gov (United States)

    Takano, Ken'Ichi; Hida, Kazuo

    2008-04-01

    We study a frustrated mixed spin chain with side chains, where the spin species and the exchange interactions are spatially varied. A nonlinear σ model method is formulated for this model, and a phase diagram with two disordered spin-gap phases is obtained for typical cases. Among them, we examine the case with a main chain, which consists of an alternating array of spin-1 and spin- (1)/(2) sites, and side chains, each of which consists of a single spin- (1)/(2) site, in great detail. Based on numerical, perturbational, and variational approaches, we propose a singlet cluster solid picture for each phase, where the ground state is expressed as a tensor product of local singlet states.

  15. Optical nonlinearities in semiconductor-doped glasses near and below the band edge

    Science.gov (United States)

    Bindra, K. S.; Oak, S. M.; Rustagi, K. C.

    1998-03-01

    We present a brief review of our recent experimental results on optical nonlinearities in semiconductor-doped glasses. It is shown that even below the absorption edge the nonlinearities are determined by nonlinear absorption. The optical Kerr effect is found to have a susceptibility which is comparable to that for nonlinear refraction. We also find that in degenerate four-wave mixing the observed intensity dependence can be strongly influenced by nonlinear absorption.

  16. 基于ISM的供应链零售商低碳行为影响因素研究%Study on Influence Factors of Supply Chain Vendors Low Carbon Behavior Based on ISM

    Institute of Scientific and Technical Information of China (English)

    朱连毅

    2015-01-01

    Global climate change is a common problem of all human beings, reducing emissions of greenhouse gases is a common sense for this problem. This paper selects vendors in the supply chain to analyze its factors by the method of Stakeholders, and evaluates the influence factors by interpretative structural modeling method, finally gets the conclusions about the policy of vendors low carbon behavior.%全球气候变化是全人类需要共同面对的问题,如何减少温室气体排放已经成为全社会共同关注的问题。本文选取供应链中零售商角色,基于利益相关者理论对其低碳行为的影响因素进行分析,并利用解析结构模型对影响因素进行评估,最终得到零售商低碳行为推进政策。

  17. The Limit Behaviour of Imprecise Continuous-Time Markov Chains

    Science.gov (United States)

    De Bock, Jasper

    2016-08-01

    We study the limit behaviour of a nonlinear differential equation whose solution is a superadditive generalisation of a stochastic matrix, prove convergence, and provide necessary and sufficient conditions for ergodicity. In the linear case, the solution of our differential equation is equal to the matrix exponential of an intensity matrix and can then be interpreted as the transition operator of a homogeneous continuous-time Markov chain. Similarly, in the generalised nonlinear case that we consider, the solution can be interpreted as the lower transition operator of a specific set of non-homogeneous continuous-time Markov chains, called an imprecise continuous-time Markov chain. In this context, our convergence result shows that for a fixed initial state, an imprecise continuous-time Markov chain always converges to a limiting distribution, and our ergodicity result provides a necessary and sufficient condition for this limiting distribution to be independent of the initial state.

  18. Resilient model approximation for Markov jump time-delay systems via reduced model with hierarchical Markov chains

    Science.gov (United States)

    Zhu, Yanzheng; Zhang, Lixian; Sreeram, Victor; Shammakh, Wafa; Ahmad, Bashir

    2016-10-01

    In this paper, the resilient model approximation problem for a class of discrete-time Markov jump time-delay systems with input sector-bounded nonlinearities is investigated. A linearised reduced-order model is determined with mode changes subject to domination by a hierarchical Markov chain containing two different nonhomogeneous Markov chains. Hence, the reduced-order model obtained not only reflects the dependence of the original systems but also model external influence that is related to the mode changes of the original system. Sufficient conditions formulated in terms of bilinear matrix inequalities for the existence of such models are established, such that the resulting error system is stochastically stable and has a guaranteed l2-l∞ error performance. A linear matrix inequalities optimisation coupled with line search is exploited to solve for the corresponding reduced-order systems. The potential and effectiveness of the developed theoretical results are demonstrated via a numerical example.

  19. The Global Value Chain

    DEFF Research Database (Denmark)

    Sørensen, Olav Jull

    The conference paper aims to develop the global value chain concept by including corporate internal value adding activities and competition to the basic framework in order to turn the global value chain into a strategic management tool......The conference paper aims to develop the global value chain concept by including corporate internal value adding activities and competition to the basic framework in order to turn the global value chain into a strategic management tool...

  20. Discrete kink dynamics in hydrogen-bonded chains: The one-component model

    DEFF Research Database (Denmark)

    Karpan, V. M.; Zolotaryuk, Yaroslav; Christiansen, Peter Leth

    2002-01-01

    We study topological solitary waves (kinks and antikinks) in a nonlinear one-dimensional Klein-Gordon chain with the on-site potential of a double-Morse type. This chain is used to describe the collective proton dynamics in quasi-one-dimensional networks of hydrogen bonds, where the on-site poten......We study topological solitary waves (kinks and antikinks) in a nonlinear one-dimensional Klein-Gordon chain with the on-site potential of a double-Morse type. This chain is used to describe the collective proton dynamics in quasi-one-dimensional networks of hydrogen bonds, where the on...

  1. Serum Free Light Chains

    Science.gov (United States)

    ... or of one of its component parts – a kappa or lambda light chain, or rarely, a heavy chain. Traditionally, plasma cell ... protein (M-protein) production and to calculate a kappa/lambda free light chain ratio. If the protein electrophoresis test is abnormal, ...

  2. Effect of gain nonlinearity in semiconductor lasers

    DEFF Research Database (Denmark)

    Jensen, Niels H.; Christiansen, Peter Leth; Skovgaard, Ove

    1988-01-01

    Semiconductor lasers are modeled by single-mode rate equations with Langevin noise terms and the influence of nonlinear gain is investigated. For cw operation the probability distribution for the carrier number and the photon number in the laser cavity is obtained. The corresponding (2+1)-dimensi......Semiconductor lasers are modeled by single-mode rate equations with Langevin noise terms and the influence of nonlinear gain is investigated. For cw operation the probability distribution for the carrier number and the photon number in the laser cavity is obtained. The corresponding (2...

  3. Distribution of Vibrational Energy Levels of Protein Molecular Chains

    Institute of Scientific and Technical Information of China (English)

    PANG Xiao-Feng; CHEN Xiang-Rong

    2001-01-01

    The distributions of the quantum vibrational energy levels of the protein molecular chain are found by the discretely nonlinear Schrodinger equation appropriate to protein obtained from the Davydov theory. The results calculated by this method are basically consistent with the experimental values. Furthermore, the energy spectra at high excited states have also been obtained for the molecular chain which is helpful in researching the properties of infrared absorption and Raman scattering of the protein molecules.

  4. Studies on Single Chain Structure of Konjac Glucomannan

    Institute of Scientific and Technical Information of China (English)

    PANG Jie; SUN Yu-Jing; SUN Yuan-Ming

    2006-01-01

    The simulation is carried out by employing the method of molecular dynamics with the single chain of konjac glucomannan (KGM) in vacuum as the structural model to discuss the factors that affect the single chain structure, the dynamic structure of the chain and the acting forces that maintain the chain structure. The results show that the shape and stability of the chain are affected by the degree of polymerization. As for the KGM with high degree of polymerization, its chain presents random coiling state and its stability declines. Both before and after deacetylation in the process of dynamic motion, the chain of KGM presents random coiling state with periodic variation of extension and coil and demonstrates favorable flexibility, indicating acetyl is not the main factor that affects the shape of chain, whereas dihedral angle and static actions are respectively the key bonding and nonbonding acting forces that influence the single chain conformations in vacuum.

  5. SIMULATING THE SUPPLY DISRUPTION FOR THE COORDINATED SUPPLY CHAIN

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    There are many disruptive accidents in the supply chain operations system and achieving the coordination of supply chain is main objective for supply chain research. While disruptive accidents have increasingly influenced the coordinated operation of the supply chain, existing research literature on the supply chain coordination is setting in a stationary environment. The answer for how the disruptive accidents affect the coordinated supply chain is given in this paper. Based on the benchmark supply chain which is coordinated by the negative incentive mechanism, we study the impacts of supply disruption on the supply chain system by using simulation approach in which two different distribution function of random variable are used to express the supply disruption. Comparison between these two simulation results and possible coordination mechanism under the supply disruption are proposed. From the perspective of supply chain risk management, we provide the inspiration for the manager.

  6. Interaction nonlinearity in asphalt binders

    Science.gov (United States)

    Motamed, Arash; Bhasin, Amit; Liechti, Kenneth M.

    2012-05-01

    Asphalt mixtures are complex composites that comprise aggregate, asphalt binder, and air. Several research studies have shown that the mechanical behavior of the asphalt mixture is strongly influenced by the matrix, i.e. the asphalt binder. Characterization and a thorough understanding of the binder behavior is the first and crucial step towards developing an accurate constitutive model for the composite. Accurate constitutive models for the constituent materials are critical to ensure accurate performance predictions at a material and structural level using micromechanics. This paper presents the findings from a systematic investigation into the nature of the linear and nonlinear response of asphalt binders subjected to different types of loading using the Dynamic Shear Rheometer (DSR). Laboratory test data show that a compressive normal force is generated in an axially constrained specimen subjected to torsional shear. This paper investigates the source of this normal force and demonstrates that the asphalt binder can dilate when subjected to shear loads. This paper also presents the findings from a study conducted to investigate the source of the nonlinearity in the asphalt binder. Test results demonstrate that the application of cyclic shear loads results in the development of a normal force and a concomitant reduction in the dynamic shear modulus. This form of nonlinear response is referred to as an "interaction nonlinearity". A combination of experimental and analytical tools is used to demonstrate and verify the presence of this interaction nonlinearity in asphalt binders. The findings from this study highlight the importance of modeling the mechanical behavior of asphalt binders based on the overall stress state of the material.

  7. Nonlinear optical characterization of colloidal solutions containing dye and Ag2S quantum dot associates

    Science.gov (United States)

    Boltaev, G. S.; Sobirov, B.; Reyimbaev, S.; Sherniyozov, H.; Usmanov, T.; Smirnov, M. S.; Ovchinnikov, O. V.; Grevtseva, I. G.; Kondratenko, T. S.; Shihaliev, H. S.; Ganeev, R. A.

    2016-12-01

    We analyzed the nonlinear absorption and refraction in the dyes and silver sulfide quantum dot (QD) associates. The nonlinear refractive indices, nonlinear absorption coefficients, and third-order nonlinear susceptibilities of the Ag2S QDs associated with various dyes (xanthenes, thiazines, carbocyanines, quinolines) were measured. The influence of dyes nonlinearities on the whole pattern of the z-scans of colloidal QD solutions, as well as the application of different molar fractions of dyes and intensities of probe radiation (40 ps, 1064 nm and 532 nm), were analyzed and discussed in the contest of the influence of various nonlinear absorption processes.

  8. Extended models of nonlinear waves in liquid with gas bubbles

    CERN Document Server

    Kudryashov, Nikolay A

    2016-01-01

    In this work we generalize the models for nonlinear waves in a gas--liquid mixture taking into account an interphase heat transfer, a surface tension and a weak liquid compressibility simultaneously at the derivation of the equations for nonlinear waves. We also take into consideration high order terms with respect to the small parameter. Two new nonlinear differential equations are derived for long weakly nonlinear waves in a liquid with gas bubbles by the reductive perturbation method considering both high order terms with respect to the small parameter and the above mentioned physical properties. One of these equations is the perturbation of the Burgers equation and corresponds to main influence of dissipation on nonlinear waves propagation. The other equation is the perturbation of the Burgers--Korteweg--de Vries equation and corresponds to main influence of dispersion on nonlinear waves propagation.

  9. Nonlinear Elliptic Differential Equations with Multivalued Nonlinearities

    Indian Academy of Sciences (India)

    Antonella Fiacca; Nikolaos Matzakos; Nikolaos S Papageorgiou; Raffaella Servadei

    2001-11-01

    In this paper we study nonlinear elliptic boundary value problems with monotone and nonmonotone multivalued nonlinearities. First we consider the case of monotone nonlinearities. In the first result we assume that the multivalued nonlinearity is defined on all $\\mathbb{R}$. Assuming the existence of an upper and of a lower solution, we prove the existence of a solution between them. Also for a special version of the problem, we prove the existence of extremal solutions in the order interval formed by the upper and lower solutions. Then we drop the requirement that the monotone nonlinearity is defined on all of $\\mathbb{R}$. This case is important because it covers variational inequalities. Using the theory of operators of monotone type we show that the problem has a solution. Finally in the last part we consider an eigenvalue problem with a nonmonotone multivalued nonlinearity. Using the critical point theory for nonsmooth locally Lipschitz functionals we prove the existence of at least two nontrivial solutions (multiplicity theorem).

  10. Geometrically nonlinear behavior of piezoelectric laminated plates

    Science.gov (United States)

    Rabinovitch, Oded

    2005-08-01

    The geometrically nonlinear behavior of piezo-laminated plates actuated with isotropic or anisotropic piezoelectric layers is analytically investigated. The analytical model is derived using the variational principle of virtual work along with the lamination and plate theories, the von Karman large displacement and moderate rotation kinematic relations, and the anisotropic piezoelectric constitutive laws. A solution strategy that combines the approach of the method of lines, the advantages of the finite element concept, and the variational formulation is developed. This approach yields a set of nonlinear ordinary differential equations with nonlinear boundary conditions, which are solved using the multiple-shooting method. Convergence and verification of the model are examined through comparison with linear and nonlinear results of other approximation methods. The nonlinear response of two active plate structures is investigated numerically. The first plate is actuated in bending using monolithic piezoceramic layers and the second one is actuated in twist using macro-fiber composites. The results quantitatively reveal the complicated in-plane stress state associated with the piezoelectric actuation and the geometrically nonlinear coupling of the in-plane and out-of-plane responses of the plate. The influence of the nonlinear effects ranges from significant stiffening in certain combinations of electrical loads and boundary conditions to amplifications of the induced deflections in others. The paper closes with a summary and conclusions.

  11. Labour in Global Value Chains

    DEFF Research Database (Denmark)

    Lund-Thomsen, Peter; Nadvi, Khalid; Chan, Anita

    2012-01-01

    A critical challenge facing developing country producers is to meet international labour standards and codes of conduct in order to engage in global value chains. Evidence of gains for workers from compliance with such standards and codes remains limited and patchy. This article focuses on the gl......A critical challenge facing developing country producers is to meet international labour standards and codes of conduct in order to engage in global value chains. Evidence of gains for workers from compliance with such standards and codes remains limited and patchy. This article focuses...... on the global football industry, a sector dominated by leading global brands that manage dispersed global value chains. It assesses the working conditions for football stitchers engaged in different forms of work organization, factories, stitching centres and home-based settings in Pakistan, India and China...... production contexts that influence work conditions. In doing so, it argues that current debates on the role of labour in global value chains have to go beyond a narrow focus on labour standards and corporate social responsibility compliance and engage with economic, technological and social upgrading...

  12. A Nonlinear Restoring Effect Study of Mooring System and its Application

    Institute of Scientific and Technical Information of China (English)

    Jian Zhang; Huilong Ren; Lijie Zhang

    2012-01-01

    Mooring system plays an important role in station keeping of floating offshore structures.Coupled analysis on mooring-buoy interactions has been increasingly studied in recent years.At present,chains and wire ropes are widely used in offshore engineering practice.On the basis of mooring line statics,an explicit formulation of single mooring chain/wire rope stiffness coefficients and mooring stiffness matrix of the mooring system were derived in this article,taking into account the horizontal restoring force,vertical restoring force and their coupling terms.The nonlinearity of mooring stiffness was analyzed,and the influences of various parameters,such as material,displacement,pre-tension and water depth,were investigated.Finally some application cases of the mooring stiffness in hydrodynamic calculation were presented.Data shows that this kind of stiffness can reckon in linear and nonlinear forces of mooring system.Also,the stiffness can be used in hydrodynamic analysis to get the eigenfrequency of slow drift motions.

  13. Gushing metal chain

    Science.gov (United States)

    Belyaev, Alexander; Sukhanov, Alexander; Tsvetkov, Alexander

    2016-03-01

    This article addresses the problem in which a chain falls from a glass from some height. This phenomenon demonstrates a paradoxical rise of the chain over the glass. To explain this effect, an initial hypothesis and an appropriate theory are proposed for calculating the steady fall parameters of the chain. For this purpose, the modified Cayley's problem of falling chain given its rise due to the centrifugal force of upward inertia is solved. Results show that the lift caused by an increase in linear density at the part of chain where it is being bent (the upper part) is due to the convergence of the chain balls to one another. The experiments confirm the obtained estimates of the lifting chain.

  14. Weakly nonlinear stability of ultra-thin slipping films

    Institute of Scientific and Technical Information of China (English)

    HU Guohui

    2005-01-01

    A weakly nonlinear theory is presented to study the effects of slippage on the stability of the ultra-thin polymer films.The nonlinear mathematical model is constructed for perturbations of small finite amplitude based on hydrodynamic equations with the long wave approximation. Results reveal that the nonlinearity always accelerates the rupture of the films. The influences of the slip length, film thickness, and initial amplitude of perturbations on the rupture of the films are investigated.

  15. Testing of Nonlinear Filters For Coloured Noise

    Science.gov (United States)

    Macek, Wieslaw M.; Redaelli, Stefano; Plewczynski, Dariusz

    We focus on nonlinearity and deterministic behaviour of classical model systems cor- rupted by white or coloured noise. Therefore, we use nonlinear filters to give a faith- ful representation of nonlinear behaviour of the systems. We also analyse time series of a real system, namely, we study velocities of of the solar wind plasma including Alfvénic fluctuations measured in situ by the Helios spacecraft in the inner helio- sphere. We demonstrate that the influence of white and coloured noise in the data records can be efficiently reduced by a nonlinear filter. We show that due to this non- linear noise reduction we get with much reliability estimates of the largest Lyapunov exponent and the Kolmogorov entropy.

  16. Interactive optomechanical coupling with nonlinear polaritonic systems

    CERN Document Server

    Bobrovska, N; Liew, T C H; Kyriienko, O

    2016-01-01

    We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective nonlinearity. Its strength is influenced by the presence of the mechanical mode and depends on the resonance frequency of the cavity. This leads to an interactive type of optomechanical coupling, being distinct from the previously studied dispersive and dissipative couplings in optomechanical systems. The emergent interactive coupling is shown to generate effective optical nonlinearity terms of high order, being quartic in the polariton number. We consider particular systems of exciton-polaritons and dipolaritons, and show that the induced effective optical nonlinearity due to the interactive coupling can exceed in magnitude the strength of Kerr nonlinear terms, such as those arising from polariton-polariton interactions. As applications, we show that the higher order terms give...

  17. Kinematics and Dynamics of Roller Chain Drives

    DEFF Research Database (Denmark)

    Fuglede, Niels

    with a clear derivation of the seating and release configurations, as well as the driven sprocket angular position, velocity and discontinuous acceleration. The approximate analysis allows for simple expressions describing the seating and release configurations and shows the influence of main design parameters...... is presented, which also allows for exact sprocket center positions for a chain with a given number of links. Results show that the total chain wrapping length varies periodically with the tooth frequency. These results are of practical importance to both the design, installation and operation of roller chain...

  18. Nonlinear Dirac Equations

    Directory of Open Access Journals (Sweden)

    Wei Khim Ng

    2009-02-01

    Full Text Available We construct nonlinear extensions of Dirac's relativistic electron equation that preserve its other desirable properties such as locality, separability, conservation of probability and Poincaré invariance. We determine the constraints that the nonlinear term must obey and classify the resultant non-polynomial nonlinearities in a double expansion in the degree of nonlinearity and number of derivatives. We give explicit examples of such nonlinear equations, studying their discrete symmetries and other properties. Motivated by some previously suggested applications we then consider nonlinear terms that simultaneously violate Lorentz covariance and again study various explicit examples. We contrast our equations and construction procedure with others in the literature and also show that our equations are not gauge equivalent to the linear Dirac equation. Finally we outline various physical applications for these equations.

  19. Nonlinear Electrodynamics and QED

    OpenAIRE

    2003-01-01

    The limits of linear electrodynamics are reviewed, and possible directions of nonlinear extension are explored. The central theme is that the qualitative character of the empirical successes of quantum electrodynamics must be used as a guide for understanding the nature of the nonlinearity of electrodynamics at the subatomic level. Some established theories of nonlinear electrodynamics, namely, those of Mie, Born, and Infeld are presented in the language of the modern geometrical and topologi...

  20. Nonlinear functional analysis

    Directory of Open Access Journals (Sweden)

    W. L. Fouché

    1983-03-01

    Full Text Available In this article we discuss some aspects of nonlinear functional analysis. It included reviews of Banach’s contraction theorem, Schauder’s fixed point theorem, globalising techniques and applications of homotopy theory to nonlinear functional analysis. The author emphasises that fundamentally new ideas are required in order to achieve a better understanding of phenomena which contain both nonlinear and definite infinite dimensional features.

  1. VALUE CHAINS IN EMERGING MARKETS

    Directory of Open Access Journals (Sweden)

    Abdyramanova, Z.

    2016-11-01

    Full Text Available The textiles sector is one of the main industry sectors in Kyrgyzstan in terms of output, employment and increasingly exports. Textile clusters are developing and patterns in cluster formations are emerging that reflect the differing economic conditions of the regions, demonstrating particular influences on the value chain. These differences are both depicted in the two regions of Kyrgyzstan-south and north. In the north of the Republic the infrastructure is more developed, there is greater facility to access international markets (exports. In the south the infrastructure is less developed, and garment producers in the region serve mainly local niche and near-neighbour markets. The research objective is to assess the key drivers of the value chain and profitability in the textiles sector in Kyrgyzstan, by comparing the garment sewing sector in the two contrasting regions of south and north Kyrgyzstan.

  2. Nonlinear Physics of Plasmas

    CERN Document Server

    Kono, Mitsuo

    2010-01-01

    A nonlinearity is one of the most important notions in modern physics. A plasma is rich in nonlinearities and provides a variety of behaviors inherent to instabilities, coherent wave structures and turbulence. The book covers the basic concepts and mathematical methods, necessary to comprehend nonlinear problems widely encountered in contemporary plasmas, but also in other fields of physics and current research on self-organized structures and magnetized plasma turbulence. The analyses make use of strongly nonlinear models solved by analytical techniques backed by extensive simulations and available experiments. The text is written for senior undergraduates, graduate students, lecturers and researchers in laboratory, space and fusion plasmas.

  3. Nonlinearity-reduced interferometer

    Science.gov (United States)

    Wu, Chien-ming

    2007-12-01

    Periodic nonlinearity is a systematic error limiting the accuracy of displacement measurements at the nanometer level. It results from many causes such as the frequency mixing, polarization mixing, polarization-frequency mixing, and the ghost reflections. An interferometer having accuracy in displacement measurement of less than one-nanometer is necessary in nanometrology. To meet the requirement, the periodic nonlinearity should be less than deep sub-nanometer. In this paper, a nonlinearity-reduced interferometry has been proposed. Both the linear- and straightness-interferometer were tested. The developed interferometer demonstrated of a residual nonlinearity less than 25 pm.

  4. Wave-packet dynamics in one-dimensional nonlinear Schroedinger lattices: local vs. nonlocal nonlinear effects

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Phi [Central University of Construction, Tuy Hoa (Viet Nam); Kim, Ki Hong [Ajou University, Suwon (Korea, Republic of)

    2014-02-15

    We study numerically the dynamics of an initially localized wave packet in one-dimensional nonlinear Schroedinger lattices with both local and nonlocal nonlinearities. Using the discrete nonlinear Schroedinger equation generalized by including a nonlocal nonlinear term, we calculate four different physical quantities as a function of time, which are the return probability to the initial excitation site, the participation number, the root-mean-square displacement from the excitation site and the spatial probability distribution. We investigate the influence of the nonlocal nonlinearity on the delocalization to self-trapping transition induced by the local nonlinearity. In the non-self-trapping region, we find that the nonlocal nonlinearity compresses the soliton width and slows down the spreading of the wave packet. In the vicinity of the delocalization to self-trapping transition point and inside the self-trapping region, we find that a new kind of self-trapping phenomenon, which we call partial self-trapping, takes place when the nonlocal nonlinearity is sufficiently strong.

  5. The Nonlinear Field Space Theory

    Energy Technology Data Exchange (ETDEWEB)

    Mielczarek, Jakub, E-mail: jakub.mielczarek@uj.edu.pl [Institute of Physics, Jagiellonian University, ul. Łojasiewicza 11, 30-348 Kraków (Poland); Trześniewski, Tomasz, E-mail: tbwbt@ift.uni.wroc.pl [Institute of Physics, Jagiellonian University, ul. Łojasiewicza 11, 30-348 Kraków (Poland); Institute for Theoretical Physics, University of Wrocław, pl. Borna 9, 50-204 Wrocław (Poland)

    2016-08-10

    In recent years the idea that not only the configuration space of particles, i.e. spacetime, but also the corresponding momentum space may have nontrivial geometry has attracted significant attention, especially in the context of quantum gravity. The aim of this letter is to extend this concept to the domain of field theories, by introducing field spaces (i.e. phase spaces of field values) that are not affine spaces. After discussing the motivation and general aspects of our approach we present a detailed analysis of the prototype (quantum) Nonlinear Field Space Theory of a scalar field on the Minkowski background. We show that the nonlinear structure of a field space leads to numerous interesting predictions, including: non-locality, generalization of the uncertainty relations, algebra deformations, constraining of the maximal occupation number, shifting of the vacuum energy and renormalization of the charge and speed of propagation of field excitations. Furthermore, a compact field space is a natural way to implement the “Principle of finiteness” of physical theories, which once motivated the Born–Infeld theory. Thus the presented framework has a variety of potential applications in the theories of fundamental interactions (e.g. quantum gravity), as well as in condensed matter physics (e.g. continuous spin chains), and can shed new light on the issue of divergences in quantum field theories.

  6. The Nonlinear Field Space Theory

    Directory of Open Access Journals (Sweden)

    Jakub Mielczarek

    2016-08-01

    Full Text Available In recent years the idea that not only the configuration space of particles, i.e. spacetime, but also the corresponding momentum space may have nontrivial geometry has attracted significant attention, especially in the context of quantum gravity. The aim of this letter is to extend this concept to the domain of field theories, by introducing field spaces (i.e. phase spaces of field values that are not affine spaces. After discussing the motivation and general aspects of our approach we present a detailed analysis of the prototype (quantum Nonlinear Field Space Theory of a scalar field on the Minkowski background. We show that the nonlinear structure of a field space leads to numerous interesting predictions, including: non-locality, generalization of the uncertainty relations, algebra deformations, constraining of the maximal occupation number, shifting of the vacuum energy and renormalization of the charge and speed of propagation of field excitations. Furthermore, a compact field space is a natural way to implement the “Principle of finiteness” of physical theories, which once motivated the Born–Infeld theory. Thus the presented framework has a variety of potential applications in the theories of fundamental interactions (e.g. quantum gravity, as well as in condensed matter physics (e.g. continuous spin chains, and can shed new light on the issue of divergences in quantum field theories.

  7. The Nonlinear Field Space Theory

    Science.gov (United States)

    Mielczarek, Jakub; Trześniewski, Tomasz

    2016-08-01

    In recent years the idea that not only the configuration space of particles, i.e. spacetime, but also the corresponding momentum space may have nontrivial geometry has attracted significant attention, especially in the context of quantum gravity. The aim of this letter is to extend this concept to the domain of field theories, by introducing field spaces (i.e. phase spaces of field values) that are not affine spaces. After discussing the motivation and general aspects of our approach we present a detailed analysis of the prototype (quantum) Nonlinear Field Space Theory of a scalar field on the Minkowski background. We show that the nonlinear structure of a field space leads to numerous interesting predictions, including: non-locality, generalization of the uncertainty relations, algebra deformations, constraining of the maximal occupation number, shifting of the vacuum energy and renormalization of the charge and speed of propagation of field excitations. Furthermore, a compact field space is a natural way to implement the "Principle of finiteness" of physical theories, which once motivated the Born-Infeld theory. Thus the presented framework has a variety of potential applications in the theories of fundamental interactions (e.g. quantum gravity), as well as in condensed matter physics (e.g. continuous spin chains), and can shed new light on the issue of divergences in quantum field theories.

  8. Influence of polyethylene glycol (PEG) chain length on the thermal behavior of spin-coated thin films of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/PEG blends

    Science.gov (United States)

    Chen, Yujing; Park, Yeonju; Noda, Isao; Jung, Young Mee

    2016-11-01

    The influence of the polyethylene glycol (PEG, Mn = 400, 1500, and 3400) chain length on the miscibility and thermal properties of spin-coated films of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHx, HHx = 6.9 mol %)/PEG blends was elucidated by using differential scanning calorimetry (DSC) and temperature-dependent infrared (IR) spectroscopy. To extract more detailed information about the spectral variations induced by the temperature, 2D correlation spectroscopy was applied to the temperature-dependent IR spectra of PHBHx/PEG blends. It was found that PEG 400 was completely miscible with PHBHx while PEG 1500 and 3400 were only partially miscible, reflecting that PHBHx/PEG miscibility decreased with the increasing molecular weight of PEG. The amorphous band of carbonyl group of 70/30 PHBHx/PEG 400 blend is resolved into two bands at 1744 and 1754 cm-1 in the asynchronous spectrum, which is not observed in the corresponding asynchronous 2D correlation spectra of PHBHx and its blend with PEG 1500 and 3400. This observation suggests that we captured the possible existence of two different types of amorphous state in 70/30 PHBHx/PEG 400 blend and the band at 1744 cm-1 is related to the amorphous mixture of PHBHx and PEG 400. Furthermore, 2D correlation analysis and the normalized peak height trends demonstrate that PEG 400 disrupts the crystalline structure of PHBHx, indicating low molecular weight PEG 400 has a clear effect on the thermal properties of PHBHx as well as depressing its melting temperature.

  9. The Nonlinear Rheology of Electrorheological Fluids

    Science.gov (United States)

    Martin, James E.

    1998-03-01

    When a colloidal suspension is exposed to a uniaxial electric field the polarized particles chain along field lines causing a macroscopic "solidification" of the fluid, the basis of the so-called electrorheological (ER) effect. Likewise, in a rotating electric field particles form sheets in the plane of the field, which we call the rotary ER effect. Both of these fluids exhibit a nonlinear, shear thinning rheology, due to shear-induced structural relaxations. Because the fluid stress can be controlled by the applied field, a number of applications are possible, including electromechanical actuators, clutches, and active vibration dampers. To design these devices, and to develop effective control loop algorithms, it is necessary to understand the strongly nonlinear rheology of these fluids. We have used time-resolved, two-dimensional light scattering on a concentrated colloidal silica fluid in steady and oscillatory shear to demonstrate that the fragmentation and aggregation of chain-like particle microstructures is the cause of flow nonlinearities. We show that the light scattering is an indirect measure of the fluid stress. These observations form the basis of a kinetic chain model we developed to describe the nonlinear dynamics of the microstructures in ER fluids in nonstationary shear flows. Understanding the microstructural dynamics then leads us to a theory of the macroscopic rheology of these fluids in nonstationary, low Reynolds number flows. Finally, we have conducted extensive large-scale (1000-10000 particles) simulations of these fluids in steady and oscillatory shear, and will compare these results to theory and experiment.

  10. Supply Chain Collaboration under Uncertainty in the Albanian Beer Market

    Directory of Open Access Journals (Sweden)

    Denisa MAMILLO

    2015-03-01

    Full Text Available Today supply chain uncertainty is higher due to the global crisis, the fast changing technology and the increasing vulnerability of supply chains. Companies use different strategies to reduce uncertainty, like building agile supply chains, increasing resilience, postponement, etc. All these strategies require strong supply chain collaboration. Although research interest in supply chain collaboration is growing, no research has been done in Albania. This paper is one of the first to investigate supply chain management practices and the extent of supply chain collaboration in the Albanian beer industry. The aim of this research is twofold: first, to investigate how supply chain uncertainty influences the extent of collaboration with the supply chain members, and second, to analyze how organizational culture facilitates the collaboration process. Semi-structured interviews were conducted with the managers of the main beer companies. A guide questionnaire was prepared. It consisted of open and rate-scale questions about supply chain collaboration, supply chain uncertainty, supply chain management practices and organizational culture. The research will show that a high level of supply chain uncertainty does not always lead to a high degree of collaboration with the supply chain members. Organizational culture is the key driver of a successful collaboration. Not all types of culture can facilitate collaboration but only the ones with an external orientation.

  11. Supply Chain Management og Supply Chain costing

    DEFF Research Database (Denmark)

    Nielsen, Steen; Mortensen, Ole

    2002-01-01

    Formålet med denne artikel er at belyse de muligheder som ligger i at integrere virksomhedens økonomiske styring med begrebet Supply Chain Management (SCM). Dette søges belyst ved først at beskrive den teoretiske ramme, hvori SCM indgår. Herefter analyseres begrebet Supply Chain Costing (SCC) som...... Århus. Et resultat er, at via begrebet Supply Chain Costing skabes der mulighed for at måle logistikkædens aktiviteter i kr./øre. Anvendelsen af denne information har også strategisk betydning for at kunne vælge kunde og leverandør. Ved hjælp af integrationen skabes der også helt nye mulighed...

  12. Understanding the Chain Fountain

    CERN Document Server

    Biggins, John Simeon

    2013-01-01

    If a chain is initially at rest in a beaker at a height h1 above the ground, and the end of the chain is pulled over the rim of the beaker and down towards the ground and then released, the chain will spontaneously "flow" out of the beaker under gravity. Furthermore, if h1 is sufficient, the beads do not simply drag over the edge of the beaker but form a fountain reaching a height h2 above it. We show that the formation of a fountain requires that the beads come into motion not only by being pulled upwards by the part of the chain immediately above the pile, but also by being pushed upwards by an anomalous reaction force from the pile of stationary chain. We propose possible origins for this force, argue that its magnitude will be proportional to the square of the chain velocity, and predict and verify experimentally that h2 is proportional to h1.

  13. Equilibrium distribution of the wave energy in a carbyne chain

    Science.gov (United States)

    Kovriguine, D. A.; Nikitenkova, S. P.

    2016-03-01

    The steady-state energy distribution of thermal vibrations at a given ambient temperature has been investigated based on a simple mathematical model that takes into account central and noncentral interactions between carbon atoms in a one-dimensional carbyne chain. The investigation has been performed using standard asymptotic methods of nonlinear dynamics in terms of the classical mechanics. In the first-order nonlinear approximation, there have been revealed resonant wave triads that are formed at a typical nonlinearity of the system under phase matching conditions. Each resonant triad consists of one longitudinal and two transverse vibration modes. In the general case, the chain is characterized by a superposition of similar resonant triplets of different spectral scales. It has been found that the energy equipartition of nonlinear stationary waves in the carbyne chain at a given temperature completely obeys the standard Rayleigh-Jeans law due to the proportional amplitude dispersion. The possibility of spontaneous formation of three-frequency envelope solitons in carbyne has been demonstrated. Heat in the form of such solitons can propagate in a chain of carbon atoms without diffusion, like localized waves.

  14. Developing green supply chain management strategies: A taxonomic approach

    Directory of Open Access Journals (Sweden)

    Michael Mutingi

    2013-06-01

    Full Text Available Purpose: The objective of this research is to explore the empirical green supply chain activities found in literature, and to develop a taxonomic framework that can be used for formulating appropriate strategies for green supply chains, based on characteristic dimensions for the green supply chain. Design/methodology/approach: The taxonomic framework is developed through (i analysis of green supply chain activities found in existing empirical work or case studies recorded in literature, (ii identification of key dimensions that influence green supply chain management strategies, and (iii development of a taxonomic scheme for selecting or developing green strategies. Findings: The paper finds that this study yielded: a set of three characteristic dimensions that influence strategic green supply chain management, and a guided structured approach selecting appropriate green strategies, providing managerial insights. Research limitations/implications: This paper shows that future work includes development of specific performance management indices according to the taxonomy of green strategies developed in this study. Practical implications: This research provided a practical guided approach that enhances appropriate formulation of green strategies for green supply chain management, while providing sound managerial insights for the supply chain decision maker. The choice of supply chain strategy directly impacts the overall environmental, economic and operations performance of the supply chain. Originality/value: This study presents to supply chain decision makers a new taxonomic framework that simplifies and enhances the formulation of green strategies, and to researchers a comparative understanding of various strategies applicable to green supply chains.

  15. Nonlinear Kinetic Dynamics of Magnetized Weibel Instability

    CERN Document Server

    Palodhi, L; Pegoraro, F

    2010-01-01

    Kinetic numerical simulations of the evolution of the Weibel instability during the full nonlinear regime are presented. The formation of strong distortions in the electron distribution function resulting in formation of strong peaks in it and their influence on the resulting electrostatic waves are shown.

  16. Transport of nonlinearly biodegradable contaminants in aquifers

    NARCIS (Netherlands)

    Keijzer, H.

    2001-01-01

    This thesis deals with the transport behavior of nonlinearly biodegradable contaminants in aquifers. Such transport occurs during in situ bioremediation which is based on the injection of an electron acceptor or electron donor. The main interests in this thesis are the mutual influences of underlyin

  17. Nonlinear peltier effect in quantum point contacts

    Science.gov (United States)

    Bogachek, E. N.; Scherbakov, A. G.; Landman, Uzi

    1998-11-01

    A theoretical analysis of the Peltier effect in two-dimensional quantum point contacts, in field-free conditions and under the influence of applied magnetic fields, is presented. It is shown that in the nonlinear regime (finite applied voltage) new peaks in the Peltier coefficient appear leading to violation of Onsager's relation. Oscillations of the Peltier coefficient in a magnetic field are demonstrated.

  18. Soil-structure interaction including nonlinear soil

    OpenAIRE

    Gicev, Vlado

    2008-01-01

    There are two types of models of soil-structure system depending upon the rigidity of foundation: models with rigid and models with flexible foundation. Main features of the soil-structure interaction phenomenon: -wave scattering, -radiation damping, -reduction of the system frequencies. In this presentation, the influence of interaction on the development of nonlinear zones in the soil is studied.

  19. Food supply chains

    OpenAIRE

    Zhou, Qian

    2011-01-01

    The dissertation analyses food waste in global supply chain. From the related managerial literature, the process of supply chain operation, from agriculture, manufacturing, warehouses, retailers to customers are explained clearly. Then the reasons and characteristics of food wastes in any point of food supply chain are analyzed. From some case studies and questionnaire investigation, some corresponding methods to reduce food waste are put forward in the following. Lastly, in terms of method s...

  20. Supply chain components

    Directory of Open Access Journals (Sweden)

    Vieraşu, T.

    2011-01-01

    Full Text Available In this article I will go through three main logistics components, which are represented by: transportation, inventory and facilities, and the three secondary logistical components: information, production location, price and how they determine performance of any supply chain. I will discuss then how these components are used in the design, planning and operation of a supply chain. I will also talk about some obstacles a supply chain manager may encounter.

  1. Breathers in oscillator chains with Hertzian interactions

    CERN Document Server

    James, Guillaume; Cuevas, Jesus

    2011-01-01

    We prove nonexistence of breathers (spatially localized and time-periodic oscillations) for a class of Fermi-Pasta-Ulam lattices representing an uncompressed chain of beads interacting via Hertz's contact forces. We then consider the setting in which an additional on-site potential is present, motivated by the Newton's cradle under the effect of gravity. Using both direct numerical computations and a simplified asymptotic model of the oscillator chain, the so-called discrete p-Schr\\"odinger (DpS) equation, we show the existence of discrete breathers and study their spectral properties and mobility. Due to the fully nonlinear character of Hertzian interactions, breathers are found to be much more localized than in classical nonlinear lattices and their motion occurs with less dispersion. In addition, we study numerically the excitation of a traveling breather after an impact at one end of a semi-infinite chain. This case is well described by the DpS equation when local oscillations are faster than binary colli...

  2. Stochastic seismic tomography by interacting Markov chains

    Science.gov (United States)

    Bottero, Alexis; Gesret, Alexandrine; Romary, Thomas; Noble, Mark; Maisons, Christophe

    2016-10-01

    Markov chain Monte Carlo sampling methods are widely used for non-linear Bayesian inversion where no analytical expression for the forward relation between data and model parameters is available. Contrary to the linear(ized) approaches, they naturally allow to evaluate the uncertainties on the model found. Nevertheless their use is problematic in high-dimensional model spaces especially when the computational cost of the forward problem is significant and/or the a posteriori distribution is multimodal. In this case, the chain can stay stuck in one of the modes and hence not provide an exhaustive sampling of the distribution of interest. We present here a still relatively unknown algorithm that allows interaction between several Markov chains at different temperatures. These interactions (based on importance resampling) ensure a robust sampling of any posterior distribution and thus provide a way to efficiently tackle complex fully non-linear inverse problems. The algorithm is easy to implement and is well adapted to run on parallel supercomputers. In this paper, the algorithm is first introduced and applied to a synthetic multimodal distribution in order to demonstrate its robustness and efficiency compared to a simulated annealing method. It is then applied in the framework of first arrival traveltime seismic tomography on real data recorded in the context of hydraulic fracturing. To carry out this study a wavelet-based adaptive model parametrization has been used. This allows to integrate the a priori information provided by sonic logs and to reduce optimally the dimension of the problem.

  3. Supply chain planning classification

    Science.gov (United States)

    Hvolby, Hans-Henrik; Trienekens, Jacques; Bonde, Hans

    2001-10-01

    Industry experience a need to shift in focus from internal production planning towards planning in the supply network. In this respect customer oriented thinking becomes almost a common good amongst companies in the supply network. An increase in the use of information technology is needed to enable companies to better tune their production planning with customers and suppliers. Information technology opportunities and supply chain planning systems facilitate companies to monitor and control their supplier network. In spite if these developments, most links in today's supply chains make individual plans, because the real demand information is not available throughout the chain. The current systems and processes of the supply chains are not designed to meet the requirements now placed upon them. For long term relationships with suppliers and customers, an integrated decision-making process is needed in order to obtain a satisfactory result for all parties. Especially when customized production and short lead-time is in focus. An effective value chain makes inventory available and visible among the value chain members, minimizes response time and optimizes total inventory value held throughout the chain. In this paper a supply chain planning classification grid is presented based current manufacturing classifications and supply chain planning initiatives.

  4. Nonlinear elasticity of alginate gels

    Science.gov (United States)

    Hashemnejad, Seyed Meysam; Kundu, Santanu

    Alginate is a naturally occurring anionic polysaccharide extracted from brown algae. Because of biocompatibility, low toxicity, and simple gelation process, alginate gels are used in biomedical and food applications. Here, we report the rheological behavior of ionically crosslinked alginate gels, which are obtained by in situ gelation of alginates with calcium salts, in between two parallel plates of a rheometer. Strain stiffening behavior was captured using large amplitude oscillatory shear (LAOS) experiments. In addition, negative normal stress was observed for these gels, which has not been reported earlier for any polysaccharide networks. The magnitude of negative normal stress increases with applied strain and can exceed that of the shear stress at large strain. Rheological results fitted with a constitutive model that considers both stretching and bending of chains indicate that nonlinearity is likely related to the stretching of the chains between the crosslink junctions. The results provide an improved understanding of the deformation mechanism of ionically crosslinked alginate gel and the results will be important in developing synthetic extracellular matrix (ECM) from these materials.

  5. The Profit Distribution of Supply Chain under E-Commerce

    Directory of Open Access Journals (Sweden)

    Jiang-Hua Zhang

    2014-01-01

    Full Text Available With the development of e-commerce, its influence on supply chain and supply chain management is becoming increasingly significant too. In this paper, the literature on the supply chain profit is reviewed first, and then a two-level and four-party supply chain which consists of a supplier, an e-commerce platform, third-party logistics, and demander is taken into consideration. The profit function of supply chain under e-commerce is formulated by taking the price of product and the maximum supply amount under certain investment as decision-making variables and taking the expected value of random variables of price as the setting sales quantity. Finally, the existence of maximum profit in the supply chain is proved in the model, and the coordination of supply chain under e-commerce environment can be achieved by setting coordination parameters when the relevant cost parameters of supply chain members satisfy certain conditions.

  6. Solitons in a chain of PT-invariant dimers

    CERN Document Server

    Suchkov, Sergey V; Dmitriev, Sergey V; Kivshar, Yuri S

    2011-01-01

    Dynamics of a chain of interacting parity-time invariant nonlinear dimers is investigated. A dimer is built as a pair of coupled elements with equal gain and loss. A relation between stationary soliton solutions of the model and solitons of the discrete nonlinear Schrodinger (DNLS) equation is demonstrated. Approximate solutions for solitons whose width is large in comparison to the lattice spacing are derived, using a continuum counterpart of the discrete equations. These solitons are mobile, featuring nearly elastic collisions. Stationary solutions for narrow solitons, which are immobile due to the pinning by the effective Peierls-Nabarro potential, are constructed numerically, starting from the anti-continuum limit. The solitons with the amplitude exceeding a certain critical value suffer an instability leading to blowup, which is a specific feature of the nonlinear PT-symmetric chain, making it dynamically different from DNLS lattices. A qualitative explanation of this feature is proposed. The instability...

  7. Applying the means-end chain concept to product development

    DEFF Research Database (Denmark)

    Søndergaard, Helle Alsted

    This paper proposes that the means-end chain (MEC) approach can influence the use of market information and inter-functional communication in new product development (NPD). The central question is whether market information represented by means-end chain data can be a vehicle for inter-functional......This paper proposes that the means-end chain (MEC) approach can influence the use of market information and inter-functional communication in new product development (NPD). The central question is whether market information represented by means-end chain data can be a vehicle for inter...

  8. Lasers for nonlinear microscopy.

    Science.gov (United States)

    Wise, Frank

    2013-03-01

    Various versions of nonlinear microscopy are revolutionizing the life sciences, almost all of which are made possible because of the development of ultrafast lasers. In this article, the main properties and technical features of short-pulse lasers used in nonlinear microscopy are summarized. Recent research results on fiber lasers that will impact future instruments are also discussed.

  9. Engineered nonlinear lattices

    DEFF Research Database (Denmark)

    Clausen, Carl A. Balslev; Christiansen, Peter Leth; Torner, L.

    1999-01-01

    We show that with the quasi-phase-matching technique it is possible to fabricate stripes of nonlinearity that trap and guide light like waveguides. We investigate an array of such stripes and find that when the stripes are sufficiently narrow, the beam dynamics is governed by a quadratic nonlinear...

  10. Nonlinear Maneuver Autopilot

    Science.gov (United States)

    Menon, P. K. A.; Badgett, M. E.; Walker, R. A.

    1992-01-01

    Trajectory-control laws based on singular-perturbation theory and nonlinear dynamical modeling. Nonlinear maneuver autopilot commands flight-test trajectories of F-15 airplane. Underlying theory of controller enables separation of variables processed in fast and slow control loops, reducing amount of computation required.

  11. Numerical Analysis of Nonlinear Rotor-bearing-seal System

    Institute of Scientific and Technical Information of China (English)

    CHENG Mei; MENG Guang; JING Jian-ping

    2008-01-01

    The system state trajectory, Poincaré maps, largest Lyapunov exponents, frequency spectra and bifurcation diagrams were used to investigate the non-linear dynamic behaviors of a rotor-bearing-seal coupled system and to analyze the influence of the seal and bearing on the nonlinear characteristics of the rotor system. Various nonlinear phenomena in the rotor-bearing-seal system, such as periodic motion, double-periodicmotion, multi-periodic motion and quasi-periodic motion were investigated. The results may contribute to a further understanding of the non-linear dynamics of the rotor-bearing-seal coupled system.

  12. Nonlinear Damping Identification in Nonlinear Dynamic System Based on Stochastic Inverse Approach

    Directory of Open Access Journals (Sweden)

    S. L. Han

    2012-01-01

    Full Text Available The nonlinear model is crucial to prepare, supervise, and analyze mechanical system. In this paper, a new nonparametric and output-only identification procedure for nonlinear damping is studied. By introducing the concept of the stochastic state space, we formulate a stochastic inverse problem for a nonlinear damping. The solution of the stochastic inverse problem is designed as probabilistic expression via the hierarchical Bayesian formulation by considering various uncertainties such as the information insufficiency in parameter of interests or errors in measurement. The probability space is estimated using Markov chain Monte Carlo (MCMC. The applicability of the proposed method is demonstrated through numerical experiment and particular application to a realistic problem related to ship roll motion.

  13. Nonlinear optics and photonics

    CERN Document Server

    He, Guang S

    2015-01-01

    This book provides a comprehensive presentation on most of the major topics in nonlinear optics and photonics, with equal emphasis on principles, experiments, techniques, and applications. It covers many major new topics including optical solitons, multi-photon effects, nonlinear photoelectric effects, fast and slow light , and Terahertz photonics. Chapters 1-10 present the fundamentals of modern nonlinear optics, and could be used as a textbook with problems provided at the end of each chapter. Chapters 11-17 cover the more advanced topics of techniques and applications of nonlinear optics and photonics, serving as a highly informative reference for researchers and experts working in related areas. There are also 16 pages of color photographs to illustrate the visual appearances of some typical nonlinear optical effects and phenomena. The book could be adopted as a textbook for both undergraduates and graduate students, and serve as a useful reference work for researchers and experts in the fields of physics...

  14. Nonlinear optical systems

    CERN Document Server

    Lugiato, Luigi; Brambilla, Massimo

    2015-01-01

    Guiding graduate students and researchers through the complex world of laser physics and nonlinear optics, this book provides an in-depth exploration of the dynamics of lasers and other relevant optical systems, under the umbrella of a unitary spatio-temporal vision. Adopting a balanced approach, the book covers traditional as well as special topics in laser physics, quantum electronics and nonlinear optics, treating them from the viewpoint of nonlinear dynamical systems. These include laser emission, frequency generation, solitons, optically bistable systems, pulsations and chaos and optical pattern formation. It also provides a coherent and up-to-date treatment of the hierarchy of nonlinear optical models and of the rich variety of phenomena they describe, helping readers to understand the limits of validity of each model and the connections among the phenomena. It is ideal for graduate students and researchers in nonlinear optics, quantum electronics, laser physics and photonics.

  15. Independent sets in chain cacti

    CERN Document Server

    Sedlar, Jelena

    2011-01-01

    In this paper chain cacti are considered. First, for two specific classes of chain cacti (orto-chains and meta-chains of cycles with h vertices) the recurrence relation for independence polynomial is derived. That recurrence relation is then used in deriving explicit expressions for independence number and number of maximum independent sets for such chains. Also, the recurrence relation for total number of independent sets for such graphs is derived. Finaly, the proof is provided that orto-chains and meta-chains are the only extremal chain cacti with respect to total number of independent sets (orto-chains minimal and meta-chains maximal).

  16. Markov chain approach to identifying Wiener systems

    Institute of Scientific and Technical Information of China (English)

    ZHAO WenXiao; CHEN HanFu

    2012-01-01

    Identification of the Wiener system composed of an infinite impulse response (IIR) linear subsystem followed by a static nonlinearity is considered.The recursive estimates for unknown coefficients of the linear subsystem and for the values of the nonlinear function at any fixed points are given by the stochastic approximation algorithms with expanding truncations (SAAWET).With the help of properties of the Markov chain connected with the linear subsystem,all estimates derived in the paper are proved to be strongly consistent.In comparison with the existing results on the topic,the method presented in the paper simplifies the convergence analysis and requires weaker conditions.A numerical example is given,and the simulation results are consistent with the theoretical analysis.

  17. Virtualization of work in global supply chains

    Directory of Open Access Journals (Sweden)

    Sabina Wyrwich-Płotka

    2016-12-01

    Full Text Available Background: The paper is devoted to the notion and benefits of implementing virtual work in global supply chains. Virtual work must be understood as an intentional activity of a human being, aimed at rendering services (tangible and intangible, by means of ITC tools, performed in a distance from the traditional place of work, in a mobile manner. The empirical research were conducted on the basis of 4 case studies of global leaders of supply chains, which in accordance with M. Fisher's classification, represent two types. The case studies confirmed the positive influence of virtual work both in effective and flexible supply chains. Favourable market and technological conditions and increasing awareness of benefits of virtual work will make it more and more widespread in companies comprising global supply chains. The aim of the study is to demonstrate the cause and effect relationships between virtual work and competitiveness of efficient and flexible supply chain. Methods: The paper is based on the available recent scientific-theoretical research and publication.  The authors analyzed 4 enterprises in Poland. The enterprises representing a flexible or an effective supply chain, either using or not a virtual work. The study carried out the authors had the form of individual interviews. The authors used case studies to show that virtual work brings notable benefits in an effective and flexible supply chain.  Results: Based on these case studies, the authors demonstrated reasons to implement virtual work in selected enterprises. The reasons to implement virtual work are determinants of possible achieve economies in effective and flexible supply chain Conclusions: The examined case studies show that virtual work brings different benefits. In the effective supply chain, virtual workers enable to increase effectiveness and financial results for example. In the flexible supply chain the virtual work can be a way to maintain and build long

  18. Supratransmission in a disordered nonlinear periodic structure

    Science.gov (United States)

    Yousefzadeh, B.; Phani, A. Srikantha

    2016-10-01

    We study the interaction among dispersion, nonlinearity, and disorder effects in the context of wave transmission through a discrete periodic structure, subjected to continuous harmonic excitation in its stop band. We consider a damped nonlinear periodic structure of finite length with disorder. Disorder is introduced throughout the structure by small changes in the stiffness parameters drawn from a uniform statistical distribution. Dispersion effects forbid wave transmission within the stop band of the linear periodic structure. However, nonlinearity leads to supratransmission phenomenon, by which enhanced wave transmission occurs within the stop band of the periodic structure when forced at an amplitude exceeding a certain threshold. The frequency components of the transmitted waves lie within the pass band of the linear structure, where disorder is known to cause Anderson localization. There is therefore a competition between dispersion, nonlinearity, and disorder in the context of supratransmission. We show that supratransmission persists in the presence of disorder. The influence of disorder decreases in general as the forcing frequency moves away from the pass band edge, reminiscent of dispersion effects subsuming disorder effects in linear periodic structures. We compute the dependence of the supratransmission force threshold on nonlinearity and strength of coupling between units. We observe that nonlinear forces are confined to the driven unit for weakly coupled systems. This observation, together with the truncation of higher-order nonlinear terms, permits us to develop closed-form expressions for the supratransmission force threshold. In sum, in the frequency range studied here, disorder does not influence the supratransmission force threshold in the ensemble-average sense, but it does reduce the average transmitted wave energy.

  19. Exact Haldane mapping for all S and super universality in spin chains

    NARCIS (Netherlands)

    Pruisken, A.M.M.; Shankar, R.; Surendran, N.

    2008-01-01

    The low-energy dynamics of the anti-ferromagnetic Heisenberg spin S chain in the semiclassical limit S -> infinity is known to map onto the O(3) nonlinear alpha-model with a theta term in 1 + 1 dimension. Guided by the underlying dual symmetry of the spin chain, as well as by the recently establishe

  20. Decisive Markov Chains

    CERN Document Server

    Abdulla, Parosh Aziz; Mayr, Richard

    2007-01-01

    We consider qualitative and quantitative verification problems for infinite-state Markov chains. We call a Markov chain decisive w.r.t. a given set of target states F if it almost certainly eventually reaches either F or a state from which F can no longer be reached. While all finite Markov chains are trivially decisive (for every set F), this also holds for many classes of infinite Markov chains. Infinite Markov chains which contain a finite attractor are decisive w.r.t. every set F. In particular, this holds for probabilistic lossy channel systems (PLCS). Furthermore, all globally coarse Markov chains are decisive. This class includes probabilistic vector addition systems (PVASS) and probabilistic noisy Turing machines (PNTM). We consider both safety and liveness problems for decisive Markov chains, i.e., the probabilities that a given set of states F is eventually reached or reached infinitely often, respectively. 1. We express the qualitative problems in abstract terms for decisive Markov chains, and show...

  1. Fields From Markov Chains

    DEFF Research Database (Denmark)

    Justesen, Jørn

    2005-01-01

    A simple construction of two-dimensional (2-D) fields is presented. Rows and columns are outcomes of the same Markov chain. The entropy can be calculated explicitly.......A simple construction of two-dimensional (2-D) fields is presented. Rows and columns are outcomes of the same Markov chain. The entropy can be calculated explicitly....

  2. REVERSE SUPPLY CHAIN

    Directory of Open Access Journals (Sweden)

    Tomasz DOMAGAŁA

    2013-10-01

    Full Text Available The paper focuses on the presentation of the reverse supply chain, of which the role in the modern business grows along with the increasing number of environmental regulations and possibilities of reducing an operating cost. The paper also describes main problems in developing the profitable chain and possibilities to take an action in order to overcome them.

  3. Value Chain Engineering

    DEFF Research Database (Denmark)

    Wæhrens, Brian Vejrum; Slepniov, Dmitrij

    2015-01-01

    This workbook is recommended for the attention of students of and managers in Danish small and medium sized enterprises (SMEs). Danish SMEs are currently facing a number of key challenges related to their position in global value chains. This book provides an insight into value chain management...

  4. Supply Chain Management

    DEFF Research Database (Denmark)

    Wieland, Andreas; Handfield, Robert B.

    Supply chain management has made great strides in becoming a discipline with a standalone body of theories. As part of this evolution, researchers have sought to embed and integrate observed supply chain management phenomena into theoretical statements. In our review, we explore where we have been...

  5. pi-Selective stationary phases: (I) Influence of the spacer chain length of phenyl type phases on the aromatic and methylene selectivity of aromatic compounds in reversed phase high performance liquid chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Mayfield, Kirsty [University of Western Sydney, Australia; Dennis, Gary [University of Western Sydney, Australia; Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL; Shalliker, R. Andrew [University of Western Sydney, Australia

    2010-01-01

    Phenyl type stationary phases of increasing spacer chain length (phenyl, methyl phenyl, ethyl phenyl, propyl phenyl and butyl phenyl, with 0-4 carbon atoms in the spacer chain, respectively) were synthesized and packed in house to determine the impact that the spacer chain length has on the retention process. Two trends in the aromatic selectivity, q{sub aromatic}, were observed, depending on whether the number of carbon atoms in the spacer chain is even or odd. Linear log k' vs {phi} plots were obtained for each stationary phase and the S coefficient was determined from the gradient of these plots. For the phenyl type phases, the S vs n{sub c} plots of the retention factors of linear polycyclic aromatic hydrocarbons vs the number of rings exhibit a distinct discontinuity that between 3 and 4 rings, which increases with increasing spacer chain length for even phases but decreases for odd phases. Accordingly, we suggest that the retention factors depend differently on the number of carbon atoms in the spacer chain depending on whether this number is even or odd and that this effect is caused by different orientations of the aromatic ring relative to the silica surface.

  6. Search on the Influence Factors and Promotion Countermeasures of the Information Sharing Level in Supply Chain Management%供应链信息共享水平影响因素及提升对策研究

    Institute of Scientific and Technical Information of China (English)

    安寅平

    2014-01-01

    In this paper, the connotation of the supply chain and supply chain management were defined, and from Standard-ization of information and technical talent, incentives, information sharing security in three areas of supply chain analysis of the factors affecting the level of information sharing on this basis, finally proposed countermeasures and recommendations aimed at strengthening the supply chain management, improve its information sharing, improve the stability and efficiency of the whole supply chain, enhance the competitive advantage of supply chain members.%对供应链及供应链管理的内涵进行了界定,并在此基础上从信息标准化及技术人才、激励机制、信息共享安全三方面分析了对供应链信息共享水平的影响,最后提出相关对策及建议,旨在加强供应链管理,提升其信息共享水平,提高供应链整体稳定性及效率,增强供应链企业成员的竞争优势。

  7. Supply Chain Connectivity: Enhancing Participation in the Global Supply Chain

    OpenAIRE

    Epictetus E. Patalinghug

    2015-01-01

    Supply chain connectivity is vital for the efficient flow of trade among APEC economies. This paper reviews the literature and supply chain management, describes the barriers to enhancing participation in global supply chain, analyzes the various measures of supply chain performance, and suggests steps for the Philippines to fully reap the benefits of the global value chain.

  8. Nonlinear cochlear mechanics.

    Science.gov (United States)

    Zweig, George

    2016-05-01

    An earlier paper characterizing the linear mechanical response of the organ of Corti [J. Acoust. Soc. Am. 138, 1102-1121 (2015)] is extended to the nonlinear domain. Assuming the existence of nonlinear oscillators nonlocally coupled through the pressure they help create, the oscillator equations are derived and examined when the stimuli are modulated tones and clicks. The nonlinearities are constrained by the requirements of oscillator stability and the invariance of zero crossings in the click response to changes in click amplitude. The nonlinear oscillator equations for tones are solved in terms of the fluid pressure that drives them, and its time derivative, presumably a proxy for forces created by outer hair cells. The pressure equation is reduced to quadrature, the integrand depending on the oscillators' responses. The resulting nonlocally coupled nonlinear equations for the pressure, and oscillator amplitudes and phases, are solved numerically in terms of the fluid pressure at the stapes. Methods for determining the nonlinear damping directly from measurements are described. Once the oscillators have been characterized from their tone and click responses, the mechanical response of the cochlea to natural sounds may be computed numerically. Signal processing inspired by cochlear mechanics opens up a new area of nonlocal nonlinear time-frequency analysis.

  9. Nonlinear Quantum Optics in Optomechanical Nanoscale Waveguides

    CERN Document Server

    Zoubi, Hashem

    2016-01-01

    We explore the possibility of achieving a significant nonlinear phase shift among photons propagating in nanoscale waveguides exploiting interactions among photons that are mediated by vibrational modes and induced through Stimulated Brillouin Scattering (SBS). We introduce a configuration that allows slowing down the photons by several orders of magnitude via SBS involving sound waves and two pump fields. We extract the conditions for maintaining vanishing amplitude gain or loss for slowly propagating photons while keeping the influence of thermal phonons to the minimum. The nonlinear phase among two counter-propagating photons can be used to realize a deterministic phase gate.

  10. Will Nonlinear Backcalculation Help?

    DEFF Research Database (Denmark)

    Ullidtz, Per

    2000-01-01

    demonstrates, that treating the subgrade as a nonlinear elastic material, can result in more realistic moduli and a much better agreement between measured and calculated stresses and strains.The response of nonlinear elastic materials can be calculated using the Finite Element Method (FEM). A much simpler...... approach is to use the Method of Equivalent Thicknesses (MET), modified for a nonlinear subgrade. The paper includes an example where moduli backcalculated using FEM, linear elastic theory and MET are compared. Stresses and strains predicted by the three methods are also compared to measured values...

  11. Nonlinear graphene metamaterial

    CERN Document Server

    Nikolaenko, Andrey E; Atmatzakis, Evangelos; Luo, Zhiqiang; Shen, Ze Xiang; De Angelis, Francesco; Boden, Stuart A; Di Fabrizio, Enzo; Zheludev, Nikolay I

    2012-01-01

    We demonstrate that the broadband nonlinear optical response of graphene can be resonantly enhanced by more than an order of magnitude through hybridization with a plasmonic metamaterial,while retaining an ultrafast nonlinear response time of ~1 ps. Transmission modulation close to ~1% is seen at a pump uence of ~0.03 mJ/cm^2 at the wavelength of ~1600 nm. This approach allows to engineer and enhance graphene's nonlinearity within a broad wavelength range enabling applications in optical switching, mode-locking and pulse shaping.

  12. Nonlinear fiber optics

    CERN Document Server

    Agrawal, Govind P

    2001-01-01

    The Optical Society of America (OSA) and SPIE - The International Society for Optical Engineering have awarded Govind Agrawal with an honorable mention for the Joseph W. Goodman Book Writing Award for his work on Nonlinear Fiber Optics, 3rd edition.Nonlinear Fiber Optics, 3rd Edition, provides a comprehensive and up-to-date account of the nonlinear phenomena occurring inside optical fibers. It retains most of the material that appeared in the first edition, with the exception of Chapter 6, which is now devoted to the polarization effects relevant for light propagation in optical

  13. Order preserving contact transformations and dynamical symmetries of scalar and coupled Riccati and Abel chains

    Science.gov (United States)

    Gladwin Pradeep, R.; Chandrasekar, V. K.; Mohanasubha, R.; Senthilvelan, M.; Lakshmanan, M.

    2016-07-01

    We identify contact transformations which linearize the given equations in the Riccati and Abel chains of nonlinear scalar and coupled ordinary differential equations to the same order. The identified contact transformations are not of Cole-Hopf type and are new to the literature. The linearization of Abel chain of equations is also demonstrated explicitly for the first time. The contact transformations can be utilized to derive dynamical symmetries of the associated nonlinear ODEs. The wider applicability of identifying this type of contact transformations and the method of deriving dynamical symmetries by using them is illustrated through two dimensional generalizations of the Riccati and Abel chains as well.

  14. 短链氯化石蜡急性暴露对SD雄性大鼠的组织病理学影响%Influence on Rats' Histopathology Under Exposing of Short Chain Chlorinated Paraffins

    Institute of Scientific and Technical Information of China (English)

    李勋; 刘钰晨; 陈敏杰; 李佳; 梁勇

    2013-01-01

    Objective:Chooses two chlorinated paraffins products which contain different con-tent of short chain chlorinated paraffins(SCCP)as model compound(CPsⅠ,38.22% and CPsⅡ, 0.08%),compares their influence on SD male rats after continuously 14 days being exposed through oral intragastric administration,according to that,to explore whether there is special toxicity of SC-CP or not. Methods:The exposing concentration are 10,50,100(CPsⅠ),100(CPsⅡ)mg/kg,re-spectively. Results:After being exposed under two chlorinated paraffins,there is no obvious influ-ence on food intaking and weight. CPsⅠand CPsⅡ acute exposing,can cause hepatocyte swelling, hydropic degeneration,cytoplast loosen;and renal tubule swelling,glomerulus atrophy,glomerulus hyalinosis;and alveolar septum incrassation,inflammatory cell infiltration;and so on histopatholo-gy changes. Conclusion:Acute chlorinated paraffines exposing has toxicity to SD male rats,the ef-fect has no significant relationship with the content of SCCP.%目的:选择短链氯化石蜡含量不同的两种氯化石蜡产品(CPsⅠ,38.22%和CPsⅡ,0.08%)作为模式化合物,比较它们经口连续灌胃暴露14 d后对SD雄性大鼠的影响,借以探讨短链氯化石蜡是否存在特殊的毒性效应。方法:CPsⅠ和CPsⅡ的暴露浓度分别为10、50、100 mg/kg(CPsⅠ)和100 mg/kg (CPsⅡ)。结果:两种氯化石蜡产品暴露后,对大鼠的摄食、体重无明显影响。CPsⅠ和CPsⅡ急性暴露,均可造成大鼠的肝脏中肝细胞肿胀、水样变性及胞质疏散;肾脏中肾小管肿胀,肾小球萎缩、肾小球玻璃样变;肺部中肺泡隔增厚,炎症细胞浸润等明显的组织病理学改变。结论:氯化石蜡急性暴露对SD雄性大鼠所产生的毒性效应,与样品中短链氯化石蜡的含量并无显著性关联。

  15. Project Decision Chain

    DEFF Research Database (Denmark)

    Rolstadås, Asbjørn; Pinto, Jeffrey K.; Falster, Peter

    2015-01-01

    To add value to project performance and help obtain project success, a new framework for decision making in projects is defined. It introduces the project decision chain inspired by the supply chain thinking in the manufacturing sector and uses three types of decisions: authorization, selection......, and plan decision. A primitive decision element is defined where all the three decision types can be accommodated. Each task in the primitive element can in itself contain subtasks that in turn will comprise new primitive elements. The primitive elements are nested together in a project decision chain....

  16. Plastic value chains

    DEFF Research Database (Denmark)

    Baxter, John; Wahlstrom, Margareta; Zu Castell-Rüdenhausen, Malin

    2014-01-01

    Optimizing plastic value chains is regarded as an important measure in order to increase recycling of plastics in an efficient way. This can also lead to improved awareness of the hazardous substances contained in plastic waste, and how to avoid that these substances are recycled. As an example......, plastics from WEEE is chosen as a Nordic case study. The project aims to propose a number of improvements for this value chain together with representatives from Nordic stakeholders. Based on the experiences made, a guide for other plastic value chains shall be developed....

  17. Design of supply chain in fuzzy environment

    Science.gov (United States)

    Rao, Kandukuri Narayana; Subbaiah, Kambagowni Venkata; Singh, Ganja Veera Pratap

    2013-05-01

    Nowadays, customer expectations are increasing and organizations are prone to operate in an uncertain environment. Under this uncertain environment, the ultimate success of the firm depends on its ability to integrate business processes among supply chain partners. Supply chain management emphasizes cross-functional links to improve the competitive strategy of organizations. Now, companies are moving from decoupled decision processes towards more integrated design and control of their components to achieve the strategic fit. In this paper, a new approach is developed to design a multi-echelon, multi-facility, and multi-product supply chain in fuzzy environment. In fuzzy environment, mixed integer programming problem is formulated through fuzzy goal programming in strategic level with supply chain cost and volume flexibility as fuzzy goals. These fuzzy goals are aggregated using minimum operator. In tactical level, continuous review policy for controlling raw material inventories in supplier echelon and controlling finished product inventories in plant as well as distribution center echelon is considered as fuzzy goals. A non-linear programming model is formulated through fuzzy goal programming using minimum operator in the tactical level. The proposed approach is illustrated with a numerical example.

  18. Multipolar nonlinear nanophotonics

    CERN Document Server

    Smirnova, Daria

    2016-01-01

    Nonlinear nanophotonics is a rapidly developing field with many useful applications for a design of nonlinear nanoantennas, light sources, nanolasers, sensors, and ultrafast miniature metadevices. A tight confinement of the local electromagnetic fields in resonant photonic nanostructures can boost nonlinear optical effects, thus offering versatile opportunities for subwavelength control of light. To achieve the desired functionalities, it is essential to gain flexible control over the near- and far-field properties of nanostructures. Thus, both modal and multipolar analyses are widely exploited for engineering nonlinear scattering from resonant nanoscale elements, in particular for enhancing the near-field interaction, tailoring the far-field multipolar interference, and optimization of the radiation directionality. Here, we review the recent advances in this recently emerged research field ranging from metallic structures exhibiting localized plasmonic resonances to hybrid metal-dielectric and all-dielectric...

  19. Optimization under Nonlinear Constraints

    OpenAIRE

    1982-01-01

    In this paper a timesaving method is proposed for maximizing likelihood functions when the parameter space is subject to nonlinear constraints, expressible as second order polynomials. The suggested approach is especially attractive when dealing with systems with many parameters.

  20. Nonlinear plasmonic antennas

    Directory of Open Access Journals (Sweden)

    Shakeeb Bin Hasan

    2014-12-01

    Full Text Available Contrary to traditional optical elements, plasmonic antennas made from nanostructured metals permit the localization of electromagnetic fields on length scales much smaller than the wavelength of light. This results in huge amplitudes for the electromagnetic field close to the antenna being conducive for the observation of nonlinear effects already at moderate pump powers. Thus, these antennas exhibit a promising potential to achieve optical frequency conversion and all-optical control of light at the nano-scale. This opens unprecedented opportunities for ultrafast nonlinear spectroscopy, sensing devices, on-chip optical frequency conversion, nonlinear optical metamaterials, and novel photon sources. Here, we review some of the recent advances in exploiting the potential of plasmonic antennas to realize robust nonlinear applications.