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Sample records for cerro prieto hydrothermal

  1. Current state of the hydrothermal geochemistry studies at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Fausto L, J.J.; Jimenez S, M.E.; Esquer P, I.

    1981-01-01

    The current state of hydrothermal geochemistry studies being carried out at the field are reported. These studies are based on the results of chemical analysis of water samples collected during 1979 and 1980 at the geothermal wells of the area known as Cerro Prieto I, as well as from those located in the Cerro Prieto II and Cerro Prieto III areas, some of which have only recently started flowing. Data are presented on the chemical variations of the main chemical constituents dissolved in the waters, as well as on the Na/K and Na-K-Ca chemical relations and the temperatures calculated from them and from SiO/sub 2/. Fluid recharge into the reservoir and its direction of flow are interpreted from isotherm contour maps of the field prepared from Na/K and Na-K-Ca geothermometry and from concentration contour maps of some of the main chemical constituents. Well M-43 is discussed as an example of a well affected by well completion problems in its production casing. Its behavior is explained on the basis of the chemical characteristics of the produced water. The chemical changes that have taken place in some of the wells during production are explained by correlating the chemistry with the production mechanisms of the well (steam-water production rates).

  2. Hydrothermal alteration of sediments associated with surface emissions from the Cerro Prieto geothermal field

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    Valette-Silver, J.N.; Esquer P., I.; Elders, W.A.; Collier, P.C.; Hoagland, J.R.

    1981-01-01

    A study of the mineralogical changes associated with these hydrothermal vents was initiated with the aim of developing possible exploration tools for geothermal resources. The Cerro Prieto reservoir has already been explored by extensive deep drilling so that relationships between surface manifestations and deeper hydrothermal processes could be established directly. Approximately 120 samples of surface sediments were collected both inside and outside of the vents. The mineralogy of the altered sediments studied appears to be controlled by the type of emission. A comparison between the changes in mineralogy due to low temperature hydrothermal activity in the reservoir, seen in samples from boreholes, and mineralogical changes in the surface emission samples shows similar general trends below 180 C: increase of quartz, feldspar and illite, with subsequent disappearance of kaolinite, montmorillonite, calcite and dolomite. These mineral assemblages seem to be characteristic products of the discharge from high intensity geothermal fields.

  3. Lithology and hydrothermal alteration determination from well logs for the Cerro Prieto Wells, Mexico

    Science.gov (United States)

    Ershaghi, I.; Ghaemian, S.; Abdassah, D.

    1981-10-01

    The characteristics of geophysical well logs are compared against the sand-shale series of the sedimentary column of the Cerro Prieto Geothermal Field, Mexico. It is shown that the changes in mineralogy of the rocks because of hydrothermal alteration are not easily detectable on the existing logs. However, if the behavior of clay minerals alone is monitored, the onset of the hydrothermally altered zones may be estimated from the well logs. The effective concentration of clay-exchange cations, Q/sub v/, is computed using the data available from conventional well logs. Zones indicating the disappearance of low temperature clays are considered hydrothermally altered formations with moderate to high permeability and temperature, and suitable for completion purposes.

  4. Hydrothermal flow regime and magmatic heat source of the Cerro Prieto geothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Schiffman, P.; Williams, A.E.

    1984-01-01

    This detailed three-dimensional model of the natural flow regime of the Cerro Prieto geothermal field, before steam production began, is based on patterns of hydrothermal mineral zones and light stable isotopic ratios observed in rock samples from more than 50 deep wells, together with temperature gradients, wireline logs and other data. At the level so far penetrated by drilling, this hydrothermal system was heated by a thermal plume of water close to boiling, inclined at 45/sup 0/, rising from the northeast and discharging to the west. To the east a zone of cold water recharge overlies the inclined thermal plume. Fission track annealing studies show the reservoir reached 170/sup 0/C only 10/sup 4/ years ago. Oxygen isotope exchange data indicate that a 12 km/sup 3/ volume of rock subsequently reacted with three times its volume of water hotter than 200/sup 0/C. Averaged over the duration of the heating event this would require a flow velocity through a typical cross-section of the reservoir of about 6 m/year. The heat in storage in that part of the reservoir hotter than 200/sup 0/C and shallower than 3 km depth is equivalent to that which would be released by the cooling of about 1 or 2 km/sup 3/ of basalt or gabbro magma.

  5. Seismological studies at Cerro Prieto

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    Majer, E.L.; McEvilly, T.V.; Albores, A.; Diaz, S.C.

    1980-01-01

    A radio-telemetered 12-station seismographic network was operated in a dense-array configuration over the Cerro Prieto field as shown in Fig. 1. Horizontal and vertical 4.5-Hz geophones were deployed with interstation distances of order 1 km in a multi-purpose survey for microearthquake occurrence and possible anomalies in P- and S-wave velocities and attenuation associated with the field. Although data obtained thus far are limited, attenuation and velocity studies at Cerro Prieto show anomalies related to the production area. This suggests that these data might be useful for delineating the field boundaries. 16 refs.

  6. Exploration and development of Cerro Prieto

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    Teilman, M.A.; Cordon, U.J.

    1981-01-01

    A brief retrospective of the exploration and field model development at Cerro Prieto are presented. Representative field models are presented for each of the work phases. These models demonstrate how the concept of the field evolved - from a small 2 km/sup 2/ area with a relatively unknown reservoir configuration - to a geothermal resource area over 20 km/sup 2/ where the hydrothermal processes and structural environment are being studied in detail. A model integrating information from these studies was developed.

  7. Overview of Cerro Prieto studies

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    Lippmann, M.J.

    1983-01-01

    The studies performed on the Cerro Prieto geothermal field, Mexico, since the late 1950's are summarized. Emphasis is given to those activities leading to the identification of the sources of heat and mass, the fluid flow paths, and the phenomena occurring in the field in its natural state and under exploitation.

  8. Model for the heat source of the Cerro Prieto magma-hydrothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Williams, A.E.; Schiffman, P.; Cox, B.

    1981-01-01

    Earlier studies at Cerro Prieto led to the development of a qualitative model for fluid flow in the geothermal system before it was drilled and perturbed by production. Current efforts are directed towards numerical modeling of heat and mass transfer in the system in this undisturbed state. This one-dimensional model assumes that the heat source was a single basalt/gabbro intrusion which provided heat to the system as it cooled. After compilation of various information of the physical properties of the reservoir, the enthalpy contained in two 1 cm thick sections across the reservoir orthogonal to each other was calculated. Various shapes, sizes and depths for the intrusion were considered as initial conditions and boundary conditions for the calculations of heat transfer. A family of numerical models which so far gives the best matches to the conditions observed in the field today have in common a funnel-shaped intrusion with a top 4 km wide emplaced at a depth of 5 km some 30,000 to 50,000 years ago, providing heat to the geothermal system.

  9. Model of the heat source of the Cerro Prieto magma-hydrothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Williams, A.E.; Schiffman, P.; Cox, B.

    1982-08-10

    Earlier studies at Cerro Prieto by UCR have led to the development of a qualitative model for field flow in the geothermal system before it was drilled and perturbed by production. Current efforts are directed towards numerical modelling of heat and mass transfer in the system in this undisturbed state. A two-dimensional model assumes that the heat sources were a single basalt/gabbro intrusion which provided heat to the system as it cooled. After compiling various information on the physical properties of the reservoir, the enthalpy contained in two 1cm thick section across the reservoir orthogonal to each other was calculated. Next various shapes, sizes and depths for the intrusion as initial conditions and boundary conditions for the calculation of heat transfer were considered. A family of numerical models which so far gives the best matches to the conditions observed in the field today have in common a funnel-shaped intrusion with a top 4km wide emplaced at a depth of 5km some 30,000 to 50,000 years ago, providing heat to the geothermal system. Numerical modelling is still in progress. Although none of the models so far computed may be a perfect match for the thermal history of the reservoir, they all indicate that the intrusive heat source is young, close and large.

  10. Geothermal drilling in Cerro Prieto

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    Dominguez A., Bernardo

    1982-08-10

    The number of characteristics of the different wells that have been drilled in the Cerro Prieto geothermal field to date enable one to summarize the basic factors in the applied technology, draw some conclusions, improve systems and procedures, and define some problems that have not yet been satisfactorily solved, although the existing solution is the best now available. For all practical purposes, the 100 wells drilled in the three areas or blocks into which the Cerro Prieto field has been divided have been completed. Both exploratory and production wells have been drilled; problems of partial or total lack of control have made it necessary to abandon some of these wells, since they were unsafe to keep in production or even to be used for observation and/or study. The wells and their type, the type of constructed wells and the accumulative meters that have been drilled for such wells are summarized.

  11. Hydrothermal-flow regime and magmatic heat source of the Cerro Prieto geothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Williams, A.E.; Schiffman, P.

    1982-01-01

    This detailed three-dimensional model of the natural flow regime of the Cerro Prieto geothermal field, before steam production began, is based on patterns of hydrothermal mineral zones and light stable isotopic ratios observed in rock samples from more than fifty deep wells, together with temperature gradients, wireline logs and other data. At the level so far penetrated by drilling, this hydrothermal system was heated by a thermal plume of water close to boiling, inclined at 45/sup 0/, rising from the northeast and discharging to the west. To the east a zone of cold water recharge overlies the inclined thermal plume. Fission track annealing studies shows that the reservoir reached 170/sup 0/C only 10/sup 4/ years ago. Oxygen isotope exchange data indicate that a 12 km/sup 3/ volume of rock subsequently reacted with three times its volume of water hotter than 200/sup 0/C. Averaged over the duration of the heating event this would require a flow velocity of about 6 m/year through the pores of a typical cross section of the reservoir having an average porosity of 10%. Although this is an extensional tectonic environment of leaky transform faulting in which repeated intrusions of basalt magma are likely, for simplicity of computation possible heat sources were modelled as simple two dimensional basalt intrusions of various sizes, shapes and locations. We have calculated a series of two-dimensional convective heat transfer models, with different heat sources and permeability distributions. The models which produce the best fit for the temperature distributions observed in the field today have in common a heat source which is a funnel-shaped basalt intrusion, 4 km wide at the top, emplaced at a depth of 5 km to 6 km about 40,000 to 50,000 years ago.

  12. Geohydrology of the Cerro Prieto geothermal aquifer

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    Sanchez R, J.; de la Pena L, A.

    1981-01-01

    The most recent information on the Cerro Prieto geothermal aquifer is summarized, with special emphasis on the initial production zone where the wells completed in the Alpha aquifer are located. These wells produce steam for power plant units 1 and 2. Brief comments also are made on the Beta aquifer, which underlies the Alpha aquifer in the Cerro Prieto I area and which extends to the east to what is known as the Cerro Prieto II and Cerro Prieto III areas. The location of the area studied is shown. The Alpha and Beta aquifers differ in their mineralogy and cementing mineral composition, temperatures, and piezometric levels. The difference in piezometric levels indicates that there is no local communication between the two aquifers. This situation has been verified by a well interference test, using well E-1 as a producer in the Beta aquifer and well M-46 as the observation well in the Alpha aquifer. No interference between them was observed. Information on the geology, geohydrology, and geochemistry of Cerro Prieto is presented.

  13. Recent activities at the Cerro Prieto field

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    Alonso, E. H.; Dominguez, A.B.; Lippmann, M.J.; Manon, M.A.; Schroeder, R.C.; Witherspoon, P.A.

    1978-01-01

    The purpose of this paper is to describe some of the latest activities of interest to reservoir engineers at the Cerro Prieto geothermal field. Special emphasis is given to the wells drilled in 1978 for exploration purposes and to provide steam to the existing and future power plants. The present power output is 75MW. Two additional 37.5MW units are scheduled to go on line in March and May 1979, while the total generating capacity at Cerro Prieto will reach about 400MW in 1985. Additional information is available in a number of papers in References 1 and 2.

  14. Analysis of the Nuevo Leon Magnetic Anomaly and its possible relation to the Cerro Prieto magmatic-hydrothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, N.E.; Corrigan, D.J.; Wilt, M.J.

    1984-01-01

    The broad dipolar magnetic anomaly whose positive peak is centered near Ejido Nuevo Leon, some 5 km east of the Cerro Prieto I power plant, has long been suspected to have a genetic relationship to the thermal source of the Cerro Prieto geothermal system. This suspicion was reinforced after several deep geothermal wells, drilled to depths of 3-3.5 km over the anomaly, intersected an apparent dike-sill complex consisting mainly of diabase but with minor rhyodacite. A detailed fit of the observed magnetic field to a computer model indicates that the source may be approximated by a tabular block 4 x 6 km in area, 3.7 km in depth, 2.3 km thick, and dipping slightly to the north. Mafic dike chips from one well, NL-1, were analysed by means of electron microprobe analyses which showed them to contain a titanomagnetite that is paramagnetic at in situ temperature conditions. As the dike mineralogy does not account for the magnetic anomaly, the magnetic source is believed to be a deeper, magnetite-rich assemblage of peridotite-gabbro plutons. The suite of igneous rocks was probably emplaced at a shallow depth in response to crustal extension and thinning brought on by en echelon strike-slip faulting. The bottom of the magnetic source body, at an estimated depth of 6 km, is presumed to be at or near that of the Curie isotherm (575/sup 0/C) for magnetite, the principal ferromagnetic mineral in peridotiticgabbroic rocks. The geological model derived from the magnetic study is generally supported by other geophysical data. In particular, earthquake data suggest dike injection is occurring at depths of 6-11 km in an area beneath the magnetic source. Thus, it is possible that heat for the geothermal field is being maintained by continuing crustal extension and magmatic activity.

  15. Analysis of the Nuevo Leon magnetic anomaly and its possible relation to the Cerro Prieto magmatic-hydrothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, N.E.; Wilt, M.J.; Corrigan, D.J.

    1982-10-01

    The broad dipolar magnetic anomaly whose positive peak is centered near Ejido Nuevo Leon, some 5 km east of the Cerro Prieto I Power Plant, has long been suspected to have a genetic relationship to the thermal source of the Cerro Prieto geothermal system. This suspicion was reinforced after several deep geothermal wells, drilled to depths of 3 to 3.5 km over the anomaly, intersected an apparent dike-sill complex consisting mainly of diabase but with minor rhyodacite. A detailed fit of the observed magnetic field to a computer model indicates that the source may be approximated by a tabular block 4 by 6 km in area, 3.7 km in depth, 2.3 km thick, and dipping slightly to the north. Mafic dike chips from one well, NL-1, were analyzed by means of electron microprobe analyses which showed tham to contain a titanomagnetite that is paramagnetic at in-situ temperature conditions. As the dike mineralogy does not account for the magnetic anomaly, the magnetic source is believed to be a deeper, magnetite-rich assemblage of peridotite-gabbro plutons. the suite of igneous rocks was probably passively emplaced at a shallow depth in response to crustal extension and thinning brought on by strike-slip faulting. The bottom of the magnetic source body, at an estimated depth of 6 km, is presumed to be at or near that of the Curie isotherm (575/sup 0/C) for magnetite, the principal ferromagnetic mineral in peridotitic-gabbroic rocks. The geological model derived from the magnetic study is generally supported by other geophysical data. In particular, earthquake data suggest dike injection is occurring at depths of 6 to 11 km in an area beneath the magnetic source. Thus, it is possible that heat for the geothermal field is being maintained by continuing crustal extension and magmatic activity.

  16. Material progress at Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Mercado, A.M.

    1978-01-01

    A brief general description is presented about the principal problems observed on the materials used in the Cerro Prieto geothermal project. These include those problems that have been observed in drill pipes, well casing separation equipment and conduction pipes for geothermal water and steam as well as the problems observed in geothermal power plant materials.

  17. Mexican-American Cooperative Program at the Cerro Prieto geothermal field: Analysis of the Nuevo Leon magnetic anomaly and its possible relation to the Cerro Prieto magmatic-hydrothermal system

    Science.gov (United States)

    Goldstein, N. E.; Wilt, M. J.; Corrigan, D. J.

    1982-10-01

    The broad dipolar magnetic anomaly whose positive peak is centered near Ejido Nuevo Leon, some 5 km east of the Cerro Prieto I Power Plant, has long been suspended to have a genetic relationship to the thermal source of the Cerro Prieto geothermal system. This suspicion was reinforced after several deep geothermal wells, drilled to depths of 3 to 3.5 km over the anomaly, intersected an apparent dike-sill complex consisting mainly of diabase but with minor rhyodacite. A detailed fit of the observed magnetic field to a computer model indicates that the source may be approximated by a tabular block 4 by 6 km in area, 3.7 km in depth, 2.3 km thick, and dipping slightly to the north. Mafic dike chips from one well, NL-1, were analyzed by means of electron microprobe analyses which showed them to contain a titanomagnetite that is paramagnetic at in-situ temperature conditions. As the dike mineralogy does not account for the magnetic anomaly, the magnetic source is believed to be a deeper, magnetite-rich assemblage of periodotite-gabbro plutons.

  18. An integrated model for the natural flow regime in the Cerro Prieto hydrothermal system based upon petrological and isotope geochemical criteria

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Williams, A.E.; Hoagland, J..

    1981-01-01

    Studies of cuttings and cores at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced.

  19. Geologic model of the Cerro Prieto geothermal field

    Science.gov (United States)

    Halfman, S. E.; Howard, J. H.; Vonderhaar, S. P.

    1982-09-01

    One of the tasks under the Mexican-American cooperative agreement is the comprehensive geologic study of the Cerro Prieto geothermal field. Using logs from over seventy deep wells as the basic source of information on the subsurface geology, a working model of the Cerro Prieto geothermal field is developed.

  20. Geochemistry of igneous rocks from the Cerro Prieto geothermal field, northern Baja California, Mexico

    Science.gov (United States)

    Herzig, C. T.

    1990-08-01

    Fractional crystallization of basaltic magma, derived from an oceanic affinity source region present beneath the Salton Trough and emplaced into a pull-apart basin of this continental rift regime, produced a tholeiitic suite of hypabyssal rocks consisting of basalt, andesite and dacite within the Cerro Prieto geothermal field, located in northern Baja California, Mexico. Higher light-rare-earth-element abundances for a basalt from the Cerro Prieto geothermal field in comparison to basalts from the Gulf of California and the East Pacific Rise suggest partial assimilation of crustal materials into the parental magmas generated beneath the Salton Trough. The crustal contaminant may be present near the surface today in the form of granitoids of the Peninsular Ranges batholith, at deeper levels as hydrothermally altered materials near the base of the Salton Trough, or may be a relict feature of Tertiary subduction contained within the upper mantle beneath the Salton Trough. The Sr isotopic compositions of dacites from the nearby Cerro Prieto volcano range from 0.7029 to 0.7036, indicating an oceanic affinity source for these rocks. The suite of hypabyssal rocks of tholeiitic affinity present within the Cerro Prieto geothermal field, related by fractional crystallization, link the dacite volcano of Cerro Prieto to gabbroic plutons inferred to exist beneath the Cerro Prieto geothermal field.

  1. Seismological studies at the Cerro Prieto field, 1978 - 1982

    Science.gov (United States)

    Majer, E. L.; McEvilly, T. V.

    1982-10-01

    Varied seismological studies were conducted to determine the static and dynamic properties of the Cerro Prieto geothermal field. Sought were the relation of wave propagation characteristics and microearthquake activity to such features as production boundaries, recharge zones, heat sources, fluid strata, lithology and structure. Discussed are the results of the studies carried out since 1978 in light of the current knowledge of the Cerro Prieto field. Also included are interpretations of the reflection surveys carried out in the immediate production areas.

  2. Parabolic trough Project in Cerro Prieto, Mexico

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    Lentz, A.; Cadenas, R.; Almanza, R.; Martinez, I.; Ruiz, V.

    2006-07-01

    Federal Electricity Commission (CFE), the most important electricity Company in Mexico wants to install a parabolic trough row in the Cerro Prieto Geothermal field. Cerro Prieto (CP) is the most important geothermal field in Mexico; this area has the highest levels of irradiance in the country. The levels of irradiance make it feasible to set up a solar collector field in the geothermal field to build a hybrid system in order to increase the steam and electricity production. There are several alternative in the hybrid system, depending where the solar field place is located. Two new options are presented in this paper. The first one uses water from the condenser in DSG with the solar field and steam is separated in the first separator. The second option (DSG), the steam produced is separated in an expansion vessel; the water is reinjected in the solar field and the steam goes to the turbine. This project plans to install an experimental facility to research and learning about the technology, CFE main objective will be the electricity generation; using steam from solar collectors using the existing turbines in CPIV; the second objective is to instruct the workers in the operation of the real facility. The third objective is to study the geothermal flow in the absorbers in Direct Steam Generation (DSG), which has salt and silica dissolved, and look for a possible solution for steam generation. The geothermal facilities have considerable experience using the brine flow, so it is not considered an impediment in the solar-geothermal hybrid system. (Author)

  3. Evaluation of geologic characteristics at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.H.; Halfman, S.E.; Vonder Haar, S.P.

    1981-01-01

    Computerized well-log analysis of Cerro Prieto has led to the identification of a relatively large and irregular low-density volume extending from near the surface in the vicinity of Laguna Volcano to greater depths toward the northeast. This low-density volume is located about a plane of symmetry of a self-potential anomaly and a group of northeast trending active faults. The presence of a volume of relatively high-density rock has been recognized at shallow depths in the initially developed part of the resource. It is believed to be due to minerals deposited by cooled, rising geothermal brine. Storativity calculated from well logs at the south end of the western part of the field shows acceptable comparison with storativity calculated from well tests. The amount of fluid produced from the field during the period 1973-1977 is greater than the amount in situ calculated from the completed interval thicknesses. Because this part of the field is still producing today, fluid must be recharging this part of the field.

  4. Geophysical monitoring at the Cerro Prieto geothermal field

    Science.gov (United States)

    Wilt, M.; Zelwer, R.; Majer, E. L.

    1982-09-01

    A program of reservoir monitoring at the Cerro Prieto geothermal field using surface geophysical methods with the objective of observing changes resulting from production is described. The three methods used, dipole-dipole resistivity, precision gravity, and passive seismic monitoring, are discussed.

  5. Hydrothermal alteration zones and present reservoir conditions: an approach to define production zones at the eastern portion of the Cerro Prieto geothermal field, BC; Zonas de alteracion hidrotermal y condiciones actuales del yacimiento: un enfoque para determinar zonas productoras al oriente del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Camacho Hernandez, Juan Manuel [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: juan.camacho02@cfe.gob.mx

    2009-07-15

    Geological factors are as essential for locating new wells as they are for defining the production zones of these wells. At the Cerro Prieto geothermal field (CGCP), one of the most important geological factors is identification of the hydrothermal alteration zones (ZAH). These are divided into silica and epidote mineralogical zones (ZMSE), without CaCO{sub 3}, and silica and epidote mineralogical transition zones (ZTMSE), with CaCO{sub 3}. It has been observed that the continuous variation of reservoir thermodynamic conditions (temperature, pressure and enthalpy) is due mainly to the exploitation of geothermal resources. The presence of new thermodynamic conditions recorded at the reservoir has led to the re-location of production wells originally located during the drilling campaign of 2004 to 2006. At the geological sections on the eastern part of the CGCP, adjustments made to the well completions lie on the limits between the ZMSE and ZTMSE zones. In turn, this is related to the current, superior, thermodynamic reservoir conditions. Based on this, a new geologic approach is proposed to define possible production zones for new wells, relating the ZAH zones to current thermodynamic reservoir conditions. [Spanish] Los factores geologicos son determinantes, tanto para establecer nuevos sitios de perforacion como para determinar el intervalo productor de un pozo nuevo. En el campo geotermico de Cerro Prieto (CGCP) una de los factores mas importantes es la determinacion de las zonas de alteracion hidrotermal (ZAH) que se dividen en dos: zona mineralogica de silice y epidota (ZMSE), sin presencia de CaCO{sub 3}, y zona de transicion mineralogica de silice y epidota (ZTMSE), con presencia de CaCO{sub 3}. Por otra parte, tambien se ha constatado que la continua variacion de las condiciones termodinamicas del yacimiento (temperatura, presion y entalpia) es originada en buena medida por la explotacion del recurso geotermico. La ocurrencia de nuevas condiciones

  6. Evolution of the Cerro Prieto geothermal system as interpreted from vitrinite reflectance under isothermal conditions

    Energy Technology Data Exchange (ETDEWEB)

    Barker, C.E. (US Geological Survey, Denver, CO); Pawlewicz, M.J.; Bostick, N.H.; Elders, W.A.

    1981-01-01

    Temperature estimates from reflectance data in the Cerro Prieto system correlate with modern temperature logs and temperature estimates from fluid inclusion and oxygen isotope geothermometry indicating that the temperature in the central portion of the Cerro Prieto System is now at its historical maximum. Isoreflectance lines formed by contouring vitrinite reflectance data for a given isothermal surface define an imaginary surface that indicates an apparent duration of heating in the system. The 250/sup 0/C isothermal surface has a complex dome-like form suggesting a localized heat source that has caused shallow heating in the central portion of this system. Isoreflectance lines relative to this 250/sup 0/C isothermal surface define a zone of low reflectance roughly corresponding to the crest of the isothermal surface. Comparison of these two surfaces suggest that the shallow heating in the central portion of Cerro Prieto is young relative to the heating (to 250/sup 0/C) on the system margins. Laboratory and theoretical models of hydrothermal convection cells suggest that the form of the observed 250/sup 0/C isothermal surface and the reflectance surface derived relative to it results from the convective rise of thermal fluids under the influence of a regional hydrodynamic gradient that induces a shift of the hydrothermal heating effects to the southwest.

  7. What lies beneath the Cerro Prieto geothermal field?

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Williams, A.E.; Biehler, S. [Univ. of California, Riverside, CA (United States)

    1997-12-31

    Although the Cerro Prieto geothermal reservoir is one of the world`s largest geothermal developments, conflicting ideas persist about the basement beneath it. The current plan to drill a 6 km deep exploratory well in the eastern part of the field has brought this controversy into sharper focus. This paper discusses criteria which any model of what lies beneath the reservoir must meet, in terms of regional tectonics and geophysics, of the metamorphic and igneous rocks thus far encountered in drilling, and of models of possible heat sources and coupling between the hydrothermal and magmatic systems. Our analysis confirms the interpretation that the crystalline basement beneath the sediments, rather than being granitic, is oceanic in character, resembling an ophiolite complex. The heat source is most likely a cooling gabbroic intrusion, several kilometers in diameter, overlain by a sheeted dike swarm. A 6 km deep bore-hole centered over such an intrusion would not only be one of the world`s deepest geothermal wells but could also be one of the hottest.

  8. Active hydrothermal metamorphism in the Cerro Prieto geothermal system, Baja California, Mexico: a telescoped low P/T facies series. [Abstract only

    Energy Technology Data Exchange (ETDEWEB)

    Schiffman, P. (Univ. of California, Riverside); Elders, W.A.; Williams, A.E.; McDowell, S.D.; Bird, D.K.

    1983-03-01

    In the Cerro Prieto geothermal system, carbonate-cemented, quartzo-feldspathic sediments of the Colorado River delta are being actively recrystallized into calc-silicate metamorphic rocks through intense fluid/rock interaction with alkali chloride brine (1.5 x 10/sup 4/ ppM TDS) at temperatures between 200/sup 0/ and 370/sup 0/C, fluid pressures <0.25 Kb, lithostatic pressures <1.0 Kb, and oxygen fugacities close to the QFM buffer. Petrologic investigations of cuttings and core from more than 50 wells in this field reveal a prograde series of calc-silicate mineral zones with index metamorphic minerals: wairakite (wr), epidote (ep), prehnite (pr), and calcic clinopyrosene (cpx). The compositions of these and other key phases: wr (Ca/Ca + Na + K + 0.97), ep (Fe/Fe + Al/sup vi/ = 0.11 to 0.31), pr (Fe/Fe + Al/sup vi/ = 0.01 to 0.28), cps (close to Wo/sub 50/ and Mg/Mg + Fe + Mn = 0.23 to 0.90), actinolite (0.20 Al/sup iv//15 cations and Mg/Mg + Fe + Mn = 0.67 to 0.82), biotite (Mg/Mg + Fe + Mn = 0.58 to 0.87) and microcline (Or/sub 96 to 100/) reflect recrystallization under low fluid pressures, relatively low f/sub O/sub 2//, and varying brine compositions. Divariant mineral assemblages in this system comprise a very low P/T facies series encompassing the clay-carbonate, zeolite, greenschist, and amphibolite facies and reflect equilibrium occurring in response to both increasing temperature and decreasing CO/sub 2/ pressure. Similar facies series, characterized by telescoped devolatization mineral reactions, are becoming increasingly recognized in other active geothermal systems above 300/sup 0/C. However, close analogues in the fossil geologic record are as yet unidentified.

  9. Brine treatment test for reinjection on Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Hurtado, R.; Mercado, S.; Gamino, H. (Departamento de Geotermia, Division de Fuentes de Energia, Instituto de Investigaciones Electricas, Justo Sierra y Herreros Sur 2098-Altos C.P. 21020, Mexicali, B.C. (MX))

    1989-01-01

    Reinjection of disposal brine from the Cerro Prieto Geothermal Power Plant System is attractive mainly because, on top of solving the brine disposal problem, it may significantly contribute to extend the reservoir useful lifetime, through thermal and hydraulic recharge. Because the high concentration of colloidal silica in the disposal brine, laboratory and pilot plant tests were conducted in order to develop the brine treatment process. Addition of 20-40 mg/1 lime to flashed and aged brine for 10-20 minutes yields a clarified brine relatively low in suspended solids (10-30 mg/1) when the over flow rate is 38.5 1/min-m/sup 2/. 1.1 mills/kWh was the estimated cost for treatment of 800 kg/s of separated brine from the Cerro Prieto I power station.

  10. Criteria for determining casing depth in Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Olivas M., H.M.; Vaca S., J.M.E.

    1982-08-10

    On the basis of geological data obtained during drilling and its relation to electric logs, together with the problems that arose when drilling through formations until the production zone was reached, it is possible to establish the most suitable manner to line a well and thus formulate an optimum casings program. The main criteria to be taken into consideration in preparing such a program and its application in the drilling of wells programmed in Cerro Prieto to optimize and economize such drilling and achieve suitable techniques for well completion are presented. The criteria are based on the characteristics of the Cerro Prieto field and on casing design factors, as well as a experience gained during drilling in such a field.

  11. Open file data on the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Lippman, M.J.; Aguirre, B.D.; Wollenberg, H.A.; Witherspoon, P.A.

    1977-04-01

    Some of the unpublished data presently available on open file at the Lawrence Berkeley Laboratory are listed and described. In addition, in the files are a number of internal memoranda of the Commission Federal de Electricidad of Mexico (CFE) on chemical characteristics of the produced fluids and incrustations; published papers on Cerro Prieto and the geologic setting of the Salton Trough; and data on the hydrogeology of the Mexicali Valley. (MHR)

  12. Dating thermal events at Cerro Prieto using fission track annealing

    Energy Technology Data Exchange (ETDEWEB)

    Sanford, S.J.; Elders, W..

    1981-01-01

    Data from laboratory experiments and geologic fading studies were compiled from published sources to produce lines of iso-annealing for apatite in time-temperature space. Fission track ages were calculated for samples from two wells at Cerro Prieto, one with an apparently simple and one with an apparently complex thermal history. Temperatures were estimated by empirical vitrinite reflectance geothermometry, fluid inclusion homogenization and oxygen isotope equilibrium. These estimates were compared with logs of measured borehole temperatures.

  13. Relationship between water chemistry and sediment mineralogy in the Cerro Prieto geothermal field: a preliminary report

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N. (Univ. de Perpignan, France); Thompson, J.M.; Ball, J.W.

    1981-01-01

    The chemical compositions of waters collected from the Cerro Prieto geothermal production wells and hydrothermal emanations are different. Compared to the Cerro Prieto well waters, the surficial waters generally contain significantly less potassium, slightly less calcium and chloride, and significantly more magnesium and sulfate. In comparison to the unaltered sediments, the changes in the mineralogy of the altered sediments appear to be controlled by the type of emanation (well, spring, mud pot, geyser, fumarole, or cold pool). However, an increase in quartz and potassium feldspar percentages seems to be characteristic of the majority of the sediments in contact with geothermal fluids. Preliminary attempts to model the chemical processes occurring in the Cerro Prieto geothermal field using chemical equilibrium calculations are reported. For this purpose the chemical compositions of thermal waters (well and surficial emanation) were used as input data to make calculations with SOLMNEQ and WATEQ2 computer programs. Then the theoretical mineral composition of altered sediments was predicted and compared to the mineralogy actually observed in the solid samples.

  14. Correlation between precision gravity and subsidence measurements at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Zelwer, R.; Grannell, R.B.

    1982-10-01

    Precision gravity measurements were made in the region of the Cerro Prieto geothermal field at yearly intervals from 1977 to 1981 to assess the feasibility of using gravity to determine subsurface reservoir changes with time. The extent of mass recharge in response to the continued production of fluids from this field was studied. Changes in gravity and ground elevation were observed throughout the region for the period of observation. Results indicate that the largest changes observed were the result of the Magnitude 6.1 (Caltech) Victoria earthquake of 8 June 1980. The epicenter of this earthquake was located 25 km southeast of the field on the Cerro Prieto Fault, which bounds the field on the southwest. Subsidence of up to 55 cm was measured east of the power plant, in the region between the northern end of the Cerro Prieto Fault and the southern end of the Imperial Fault. This area has been postulated to be the site of an active spreading center or pull-apart basin, and has been characterized by a high level of seismic activity during the last 10 years. Minor subsidence and small related gravity changes for the period preceeding the Victoria earthquake suggest that in spite of large fluid production rates, the reservoir is being almost completely recharged and that a measurable increase in subsurface density may be taking place. The results of measurements of horizontal ground motions made in this area are discussed in relation to the gravity and subsidence observations.

  15. Microfossils from Cerro Prieto geothermal wells, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cotton, M.L.; Haar, S.V.

    1982-08-10

    To aid in a paleonenvironmental and age reconstruction of the Cerro Prieto reservoir system, 59 samples of well cuttings were analyzed for microfossils. The cuttings were obtained at depths from 351 to 3495m in 14 geothermal wells in the Cerro Prieto field, Baja California, Mexico. Foraminifera was found in 6 samples, ostracodes in 19 samples and mannoplankton as coccoliths in 24 samples. Other groups, such as molluscus, insects, fish skeletal parts, and plant material were occasionally present. Detailed interpretations at this time cannot be made because of poor preservation of samples. This is primarily due to causes: dissolution by geothermal fluids that reach 350/sup 0/C, and the extensive mixing of filled Cretaceous forms (reworked from the Colorado Plateau region) with Tertiary species during drilling. Further studies of ostracodes and foraminifera from colder portions of the wells are needed. The abundant and well-preserved ostracodes indicate marine to backish water inviroments that correspond in part, to lagoonal or estuarine facies. The presence of the mid-Tertiary (15-m.y.-old) marine foraminifera, Cassigerinela chipolensis, in wells M-11 and M-38, 350 to 500m deep, is perplexing. These are not laboratory contaminates and, as yet have not been found in the drilling mud. If further studies confirm their presence at Cerro Prieto, established ideas about the opening of the Gulf of California and about Pacific Coast mid-Tertiary history will need to be rewritten.

  16. Correlation between precision gravity and subsidence measurements at Cerro Prieto

    Science.gov (United States)

    Zelwer, R.; Grannell, R. B.

    1982-10-01

    Precision gravity measurements were made in the region of the Cerro Prieto geothermal field at yearly intervals from 1977 to 1981 to assess the feasibility of using gravity to determine subsurface reservoir changes with time. The extent of mass recharge in response to the continued production of fluids from this field was studied. Changes in gravity and ground elevation were observed throughout the region for the period of observation. Results indicate that the largest changes observed were the result of the Magnitude 6.1 (Caltech) Victoria earthquake of 8 June 1980. The epicenter of this earthquake was located 25 km southeast of the field on the Cerro Prieto Fault, which bounds the field on the southwest. Subsidence of up to 55 cm was measured east of the power plant, in the region between the northern end of the Cerro Prieto Fault and the southern end of the Imperial Fault. This area has been postulated to be the site of an active spreading center or pull-apart basin, and has been characterized by a high level of seismic activity during the last 10 years.

  17. Microfossils from Cerro Prieto geothermal wells, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cotton, M.L.; Vonder Haar, S.

    1980-01-01

    To aid in a paleoenvironmental and age reconstruction of the Cerro Prieto reservoir system, 59 samples of well cuttings were analyzed for microfossils. The cuttings were obtained at depths from 351 to 3495 m in 14 geothermal wells in the Cerro Prieto field, Baja California, Mexico. We found foraminifera in 6 samples, ostracodes in 19 samples, and nannoplankton as coccoliths in 24 samples. Other groups, such as molluscs, insects, fish skeletal parts, and plant material were occasionally present. Detailed interpretations are not possible at this time because of poor preservation of samples. This is primarily due to causes: dissolution by geothermal fluids that reach 350{sup 0}C, and the extensive mixing of filled Cretaceous forms (reworked from the Colorado Plateau region) with Tertiary species during drilling. Further studies of ostracodes and foraminifera from colder portions of the wells are needed. The abundant and well-preserved ostracodes indicate marine to brackish water environments that correspond, in part, to lagoonal or estuarine facies. The presence of the mid-Tertiary (15-My-old) marine foraminifera, Cassigerinela chipolensis, in wells M-11 and M-38, 350 to 500 m deep, is perplexing. These are not laboratory contaminates and, as yet, have not been found in the drilling mud. If further studies confirm their presence at Cerro Prieto, established ideas about the opening of the Gulf of California and about Pacific Coast mid-Tertiary history will need to be rewritten.

  18. Seismotectonics of the Cerro Prieto Geothermal Field, Baja California, Mexico.

    Science.gov (United States)

    Rebollar, C. J.; Reyes, L. M.; Quintanar, L.; Arellano, J. F.

    2002-12-01

    We studied the background seismic activity in the Cerro Prieto geothermal field (CPGF) using a network of 21 digital stations. Earthquakes are located below the exploitation area of the CPGF, between 3 and 12 km depth, within the basement. Earthquakes follow roughly a N30°E trend perpendicular to the Cerro Prieto fault. This activity is located on a horst-like structure below the geothermal field and coincides with the zone of maximum subsidence in the CPGF. Two earthquake swarms occurred along the SE-NW strike of the Cerro Prieto fault and in the neighborhood of the Cerro Prieto volcano. Magnitudes range from -0.3 to 2.5. A Vp/Vs=1.91 ratio of the activity below the volcano suggests a water-saturated medium and/or a partial-melt medium. We calculated 76 focal mechanisms of individual events. On June 1 and September 10, 1999, two earthquakes of Mw 5.2 and 5.3 occurred in the basement at depths of 7.4 and 3.8 km below the CPGF. Maximum peak accelerations above the hypocenter ranged from 128.0 to 432.0 cm/s2. Waveform modeling results in a fault geometries given by strike=236°, dip=60°, rake=-58° (normal) and strike=10°, dip=90°, rake=159° (right lateral strike-slip) for the June and September events. Observed triangular source time function of 0.7 seconds and a double source with a total duration of 1.9 seconds for the June and September events were used to calculate the synthetics seismograms. Static stress drops and seismic moments for the June and September events are: Δ\\sigma=82.5 MPa (825 bars), Mo= 7.65x1016 Nm (7.65x1023 dyne-cm) and Δ\\sigma=31.3 MPa (313 bars) and Mo=1.27x1017 Nm (1.27x1024 dyne-cm). These stress drops are typical of continental events rather than stress drops of events originated in spreading centers. We concluded from the focal mechanisms of the background seismicity and June and September 1999 events, that a complex stress environment exits in the CPGF due to the continual thinning of the crust in the Cerro Prieto basin.

  19. Oxygen isotope exchange in rocks and minerals from the Cerro Prieto geothermal system: Indicators of temperature distribution and fluid flow

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.E.; Elders, W.A.

    1981-01-01

    Oxygen isotopic compositions have been measured in drill cuttings and core samples from more than 40 wells ranging in depth to more than 3.5 km in the Cerro Prieto geothermal field. Profiles of isotopic ratios versus sampling depths provide information on the three-dimensional distribution of temperature and fluid flow. These parameters also indicate variations in the history of hydrothermal processes in different areas of the geothermal field.

  20. Exploration and development of the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Lippmann, M.J.; Goldstein, N.E.; Halfman, S.E.; Witherspoon, P.A.

    1983-07-01

    A multidisciplinary effort to locate, delineate, and characterize the geothermal system at Cerro Prieto, Baja California, Mexico, began about 25 years ago. It led to the identification of an important high-temperature, liquid-dominated geothermal system which went into production in 1973. Initially, the effort was undertaken principally by the Mexican electric power agency, the Comision Federal de Electricidad (CFE). Starting in 1977 a group of US organizations sponsored by the US Department of Energy, joined CFE in this endeavor. An evaluation of the different studies carried out at Cerro Prieto has shown that: (1) surface electrical resistivity and seismic reflection surveys are useful in defining targets for exploratory drilling; (2) the mineralogical studies of cores and cuttings and the analysis of well logs are important in designing the completion of wells, identifying geological controls on fluid movement, determining thermal effects and inferring the thermal history of the field; (3) geochemical surveys help to define zones of recharge and paths of fluid migration; and (4) reservoir engineering studies are necessary in establishing the characteristics of the reservoir and in predicting its response to fluid production.

  1. Precision gravity studies at Cerro Prieto: a progress report

    Energy Technology Data Exchange (ETDEWEB)

    Grannell, R.B. (California State Univ., Long Beach); Kroll, R.C.; Wyman, R.M.; Aronstam, P.S.

    1981-01-01

    A third and fourth year of precision gravity data collection and reduction have now been completed at the Cerro Prieto geothermal field. In summary, 66 permanently monumented stations were occupied between December and April of 1979 to 1980 and 1980 to 1981 by a LaCoste and Romberg gravity meter (G300) at least twice, with a minimum of four replicate values obtained each time. Station 20 alternate, a stable base located on Cerro Prieto volcano, was used as the reference base for the third year and all the stations were tied to this base, using four to five hour loops. The field data were reduced to observed gravity values by (1) multiplication with the appropriate calibration factor; (2) removal of calculated tidal effects; (3) calculation of average values at each station, and (4) linear removal of accumulated instrumental drift which remained after carrying out the first three reductions. Following the reduction of values and calculation of gravity differences between individual stations and the base stations, standard deviations were calculated for the averaged occupation values (two to three per station). In addition, pooled variance calculations were carried out to estimate precision for the surveys as a whole.

  2. Hydrocarbons emissions from Cerro Prieto Geothermal Power Plant, Mexico

    Science.gov (United States)

    Navarro, Karina; Navarro-González, Rafael; de la Rosa, José; Peralta, Oscar; Castro, Telma; Imaz, Mireya

    2014-05-01

    One of the most important environmental issues related to the use of geothermal fluids to generate electricity is the emission of non-condensable gases to the atmosphere. Mexico has one of the largest geothermal plants in the world. The facility is located at Cerro Prieto, Baja California, roughly 30 km south of Mexicali and the international boundary between Mexico and United States. The Cerro Prieto power plant has 13 units grouped on four individual powerhouses. Gas samples from 9 units of the four powerhouses were collected during 4 campaigns conducted in May-July, 2010, February, 2012, December, 2012, and May, 2013. Gas samples from the stacks were collected in 1000 ml Pyrex round flasks with Teflon stopcocks, and analyzed by gas chromatography-mass spectrometry. Methane was the most abundant aliphatic hydrocarbon, with a concentration that ranged from less than 1% up to 3.5% of the total gas mixture. Normal alkanes represented the second most abundant species, and displayed a decreasing abundance with increasing carbon number in the homologous series. Isoalkanes were also present as isobutane and isopentane. Cycloalkanes occurring as cyclopentane and cyclohexane, were detected only at trace level. Unsaturated hydrocarbons (alkenes and alkynes) were not detected. Benzene was detected at levels ranging from less than 1% up to 3.4% of the total gas mixture. Other aromatic hydrocarbons detected were toluene, and xylenes, and were present at lower concentrations (

  3. A review of progress in understanding the fluid geochemistry of the Cerro Prieto geothermal system

    Science.gov (United States)

    Truesdell, A.H.; Nehring, N.L.; Thompson, J.M.; Janik, C.J.; Coplen, T.B.

    1984-01-01

    Fluid geochemistry has played a major role in our present understanding of the Cerro Prieto geothermal system. Fluid chemical and isotopic compositions have been used to indicate the origin of water, salts and gases, original subsurface temperature and fluid flow, fluid-production mechanisms, and production-induced aquifer boiling and cold-water entry. The extensive geochemical data and interpretations for Cerro Prieto published from 1964 to 1981 are reviewed and discussed. Fluid geochemistry must continue to play an important role in the further development of the Cerro Prieto field. ?? 1984.

  4. Vitrinite reflectance geothermometry and apparent heating duration in the Cerro Prieto geothermal field

    Science.gov (United States)

    Barker, C.E.; Elders, W.A.

    1981-01-01

    Vitrinite reflectance measured in immersion oil (Ro) on kerogen extracted from hydrothermally altered mudstones in borehole M-84 at the Cerro Prieto geothermal field exhibit an increase in mean reflectance (Ro) from 0.12 per cent at 0.24 km depth to 4.1 per cent at 1.7 km depth. Downhole temperatures measured over this interval increase from about 60?? to 340??C. These Ro data plotted against temperature fall along an exponential curve with a coefficient of determination of about 0.8. Other boreholes sampled in the field show similar relationships. A regression curve calculated for temperature and Ro in borehole M-105 correctly predicts temperatures in other boreholes within the central portion of the geothermal system. The correlation between the reflectance values and logged temperature, together with consistent temperature estimates from fluid inclusion and oxygen isotope geothermometry, indicates that changes in Ro are an accurate and sensitive recorder of the maximum temperature attained. Therefore, vitrinite reflectance can be used in this geothermal system to predict the undisturbed temperature in a geothermal borehole during drilling before it regains thermal equilibrium. Although existing theoretical functions which relate Ro to temperature and duration of heating are inaccurate, empirical temperature-Ro curves are still useful for geothermometry. A comparison of temperature-Ro regression curves derived from nine boreholes within the Cerro Prieto system suggests that heating across the central portion of the field occurred penecontemporaneously, but varies near margins. Boreholes M-93 and M-94 appear to have cooled from their maximum temperatures, whereas M-3 and Prian-1 have only recently been heated. Comparison of the temperature-Ro data from the Salton Sea, California, geothermal system indicates that the duration of heating has been longer there than at the Cerro Prieto field. ?? 1981.

  5. EFFECTS OF LOCALIZED AQUIFER BOILING ON FLUID PRODUCTION AT CERRO PRIETO.

    Science.gov (United States)

    Truesdell, Alfred H.; D'Amore, Franco; Nieva, David

    1984-01-01

    Localized aquifer boiling in the shallow two-phase reservoir of Cerro Prieto has produced excess steam and increased electrical output. Unfortunately it has also caused near-well mineral deposition that has decreased permeability and fluid flow. Inflow of cold water has limited the extent of aquifer boiling and permeability loss. The deeper reservoir at Cerro Prieto may need injection of cold water to decrease boiling and prevent loss of production. Refs.

  6. Basic aspects of the Cerro Prieto reservoir water recharge; Aspectos basicos de la recarga de agua al reservorio de Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    The Cerro Prieto geothermal field, located 30 km South of Mexicali City, Baja California, has at present an installed capacity of 620 MW in geothermal power plants, that operating with endogenous steam, make use of the underground energy by means of deep wells, from which about 80 million cubic meters per year of high enthalpy water and steam mixture are extracted. During the exploitation physical an chemical changes in the hydrothermal fluids discharged by the wells have been detected, which shows, among other things, an elevated water recharge, located towards the West area of the field and a low recharge in the part of the east zone area. For this reason the hot brine waste re-injection is recommended, (previously treated to eliminate the silica excess) to thermally an hydraulically recharge the reservoir in that part of the field. [Espanol] El campo geotermico de Cerro Prieto, situado a 30 km al sur de la ciudad de Mexicali, Baja California, cuenta actualmente, despues de 18 anos en explotacion, con 620 MW de capacidad instalada en plantas geotermoelectricas que, operando con vapor endogeno, aprovechan la energia del subsuelo mediante pozos profundos de los que se extraen alrededor de 80 millones de metros cubicos por ano de una mezcla de agua vapor de elevada entalpia. Durante la explotacion se han percibido cambios fisicos y quimicos en los fluidos hidrotermales descargados por los pozos, lo que indica, entre otras cosas, una recarga elevada de agua localizada hacia el poniente del campo y una recarga baja en una zona de la parte oriental. Por ello se recomienda la reinyeccion de salmuera geotermica caliente de desecho (previamente tratada para eliminar el exceso de silice) para recargar termica e hidraulicamente el reservorio en esa parte del campo.

  7. Progress on the biphase turbine at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Cerini, D.; Hays, L.; Studhalter, W. [Douglas Energy Company, Placentia, CA (United States)

    1997-12-31

    The status of a Biphase turbine power plant being installed at the Cerro Prieto geothermal field is presented. The major modules for the power plant are completed except for a back pressure steam turbine. The power plant will be started in April 1997 with the Biphase turbine alone followed by the addition of the steam turbine module two months later. The current power plant performance level is 2780 kWe due to a decline in the well. An increase in power output to 4060 kWe by adding the flow from another well is planned. The addition of five Biphase power plants with a total power output of 21.2 megawatts is described.

  8. Geochemical evidence of drawdown in the Cerro Prieto geothermal field

    Science.gov (United States)

    Truesdell, A.H.; Manon, M.A.; Jimenez, S.M.E.; Sanchez, A.A.; Fausto, L.J.J.

    1979-01-01

    Some wells of the Cerro Prieto geothermal field have undergone changes in the chemistry of fluids produced which reflect reservoir processes. Pressure decreases due to production in the southeastern part of the field have produced both drawdown of lower chloride fluids from an overlying aquifer and boiling in the aquifer with excess steam reaching the wells. These reservoir changes are indicated by changes in fluid chloride concentrations, Na/K ratios and measured enthalpies and by comparisons of aquifer fluid temperatures and chloride concentrations calculated from enthalpy and chemical measurements. Fluid temperatures have not been greatly affected by this drawdown because heat contained in the rock was transferred to the fluid. When this heat is exhausted, fluid temperatures may drop rapidly. ?? 1979.

  9. The origin of the Cerro Prieto geothermal brine

    Science.gov (United States)

    Truesdell, A.H.; Thompson, J.M.; Coplen, T.B.; Nehring, N.L.; Janik, C.J.

    1981-01-01

    The Cerro Prieto geothermal brine may have originated from mixing of Colorado River water with seawater evaporated to about six times its normal salinity. This mixture circulated deeply and was heated by magmatic processes. During deep circulation, Li, K, Ca, B, SiO2 and rare alkalis were transferred from rock minerals to the water, and Mg, SO4, and a minor quantity of Na were transferred to the rock. Similar alteration of seawater salt chemistry has been observed in coastal geothermal systems and produced in laboratory experiments. After heating and alteration the brine was further diluted to its present range of composition. Oxygen isotopes in the fluid are in equilibrium with reservoir calcite and have been affected by exploitation-induced boiling and dilution. ?? 1981.

  10. Reservoir engineering studies of the Cerro Prieto geothermal field

    Science.gov (United States)

    Goyal, K. P.; Lippmann, M. J.; Tsang, C. F.

    1982-09-01

    Reservoir engineering studies of the Cerro Prieto geothermal field began in 1978 under a five-year cooperative agreement between the US Department of Energy and the Comision Federal de Electricidad de Mexico, with the ultimate objective of simulating the reservoir to forecast its production capacity, energy longevity, and recharge capability under various production and injection scenarios. During the fiscal year 1981, attempts were made to collect information on the evolution history of the field since exploitation began; the information is to be used later to validate the reservoir model. To this end, wellhead production data were analyzed for heat and mass flow and also for changes in reservoir pressures, temperatures, and saturations for the period from March 1973 to November 1980.

  11. Geothermal emissions data base: Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Schwartz, S.R. (comp.)

    1978-04-01

    A new database subset on the gaseous emissions from the Cerro Prieto geothermal field is presented. Properties and states of the reservoir fluid such as flow rates, wellhead pressure, and enthalpy are included in the file along with the well name and constituent measurement. This subset is the result of an initial screening of the data covering 1967 to 1969, and new additions will be appended periodically to the file. The data are accessed by a database management system as are all other subsets in the file. Thereby, one may search the database for specific data requirements and print selective output. For example, one may wish to locate reservoir conditions for cases only when the level of the constituent exceeded a designated value. Data output is available in the form of numerical compilations such as the attached, or graphical displays disposed to paper, film, or magnetic tape.

  12. Results from two years of resistivity monitoring at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Wilt, M.J.; Goldstein, N.E.

    1981-01-01

    Dipole-dipole resistivity measurements for the combined purposes of reservoir delineation and resistivity monitoring were first made at Cerro Prieto in 1978 and have continued on an annual basis since then. Two 20 km long dipole-dipole lines with permanently emplaced electrodes at one kilometer spacings were established over the field area; one of these lines is remeasured annually. Resistivity measurements are taken using a 25 kW generator capable of up to 80A output and a microprocessor controlled signal averaging receiver; this high power-low noise system is capable of highly accurate measurements even at large transmitter-receiver separations. Standard error calculations for collected data indicate errors less than 5% for all points, but 95% confidence intervals show error limits about 2 to 4 times higher. Analysis of collected data indicate little change in the apparent resistivity of the upper 300 m over the field production zone and that in this section measurements are relatively insensitive to the annual rainfall cycle. Apparent resistivity increases were observed over the older producing zone at Cerro Prieto at depths of 1 km and greater. Large zones of decreasing apparent resistivity were observed flanking the zone of increases on both sides. The increase in apparent resistivity in the production region may be due to an increasing fraction of steam in the reservoir resulting from a production related decline in reservoir pressure. Alternatively the increases may be the result of fresh water influx from the Colorado River. The zone of declining resistivity flanking the area of increase may be due to the movement of saline waters into the reservoir region as a result of the pressure decline. Quantitative modeling of observed changes is impractical owing to the high uncertainty in estimating apparent resistivity changes and the nonuniqueness of models.

  13. Hydrogeophysics and Water Balance of Cerro Prieto Dam, NE Mexico

    Science.gov (United States)

    Yutsis, V.; de León Gómez, H.; Masuch Oesterreich, D.; Izaguirre, F.

    2007-05-01

    The geographical location of the State of Nuevo Leon, due to its physiographic features, has temperate and arid climate; undeveloped drainage, low precipitations, and high evapotranspiration rates, as well as rapid demographic growth. The hydrological data of the Pablillo basin, registered in the hydrometric station Cerro Prieto, showed an annual precipitation from 415 up to 1130 mm/a , the mean evaporation of 705 mm/a (up to 2460 mm/a in 1996). The maximum water storage of the Cerro Prieto reservoir is 395 millions m3 which corresponds to a water level of 295 meters. However, this level was reached only three times after the dam's construction. By the end of June 2006 the water level was at 276.2 m which corresponds to a water volume of about 127,806,300 m3 which is less than a third of maximum storage. Analysis of hydrological data showed sufficient misbalance between water recharge (by rain, river flow) and loss due to evaporation, filtration, extraction, discharge, etc. 160 gravity reading points, 400 onshore magnetic field readings as well as about 250 offshore magnetic points were carried out. The standard corrections as instrumental drift, latitude, elevation, IGRF, etc. were applied to obtained data. Data procession includes Fourier transformation, wavelength filters, upward continuation, vertical and horizontal derivates, etc. As a result a 2D geological-geophysical models and 3D maps were elaborated. The general trend of the magnetic field reduced to a pole is NW - SE on which background anomalies of northeast trend are obviously traced. The general trend of the gravity field received as a result of our works is the same. However, local magnetic and residual gravity anomalies have mosaic character and, being morphologically extended in a NE direction, grouped in chains of northwest trend. Potential data interpretation allows assuming a series of the superficial fractures focused in a NE direction, perpendicular (NW-SE) to the general deep fault. The

  14. Update of the conceptual geological model for the geothermal reservoir in Cerro Prieto, BC; Actualizacion del modelo geologico conceptual del yacimiento geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Lira Herrera, Hector [Comision Federal de Electricidad, Mexicali, B.C., (Mexico)

    2005-06-01

    An updated, conceptual geologic model is presented for the geothermal reservoir in Cerro Prieto geothermal field. The tectonic extension that formed the Basin and Range Province of the Western United States and Northwestern Mexico during Upper Tertiary in the Cerro Prieto area resulted in the formation of a half graben tectonic basin between the Cerro Prieto and Imperial faults. Called the Cerro Prieto basin, it includes listric faults, predominately northwest-southwest trending, stepped generally to the northeast. The zone of cortical weakness, formed during the Tertiary, allowed an intrusion of basic rock associated with the magnetic anomaly know as Nuevo Leon. The intrusive rock has been fed by new magmatic intrusions originated by the present tectonic extension of the Gulf of California. The oldest rocks identified in the area are gneiss and biotite-schists of Permian-Jurassic age and tonalities of Jurassic-Cretaceous age in contact with Cretaceous granites, all representing the regional basement. The lithologic column in the subsurface of the Cerro Prieto basin in formed by a basement of Cretaceous granites; an argillaceous package resting on the basement composed of gray shales with interleaves of sandstone, Tertiary brown-shales and mudstone, with an average thickness of 2700 m; clastic sediments of the Quaternary age deposited mainly by the Colorado River and alluvial fans of the Cucapa Range, comprised of gravel, sands and clays with an average thickness of 2500 m, covering the shales. The fluids feeding the geothermal reservoir heat as they pass though the zone where the basic intrusive is located (the heat source) and migrate through the listric faults toward the permeable layers of sandstone located within the gray shales. [Spanish] Se presenta el modelo geologico conceptual actualizado del yacimiento geotermico de Cerro Prieto. La tectonica extensional que origino la Provincia de Cuencas y Cordilleras (Basin and Range) del oeste de Estados Unidos y

  15. Detailed microearthquake studies at the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Majer, E.L. (Lawrence Berkeley Lab., CA); McEvilly, T.V.

    1981-01-01

    There appears to be an increase in seismic activity within the Cerro Prieto production zone since early 1978. The microearthquake activity is now more or less constant at a rate of 2 to 3 events per day. The b-values within the field are significantly higher inside the production zone than are those for events on faults outside of the production region. The earthquakes seem to be controlled by the Hidalgo fault, although slight clustering was observed in the center of the main production region. The earthquakes within the production zone may reflect the reservoir dynamics associated with heat and mass withdrawal. Mechanisms such as volume change, thermal stresses and weakening of materials associated with boiling (i.e., phase changes, dissolution) may all be responsible for the increased seismic activity. Although a small reinjection program has started, the pressure drawdown conditions existing within the field would imply that increased pore pressure resulting from the injection activities is not responsible for the increased seismic activity.

  16. Evolution of the Cerro Prieto reservoirs under exploitation

    Energy Technology Data Exchange (ETDEWEB)

    Truesdell, A.H.; Lippmann, M.J. [Lawrence Berkeley National Lab., CA (United States); Puente, H.G. [Comision Federal de Electricidad, Mexicali (Mexico)

    1997-07-01

    The Cerro Prieto Geothermal field of Baja California (Mexico) has been under commercial production to generate electricity since 1973. Over the years, the large amount of Geothermal fluids extracted (at present about 12,000 tons per hour) to supply steam to the power plants has resulted in a reduction of pressures, changes in reservoir processes, and increased flow of cooler groundwater into the geothermal system. The groundwater recharging the reservoir moves horizontally through permeable layers, as well as vertically through permeable fault zones. In addition, the supply of deep hot waters has continued unabated, and perhaps has increased as reservoir pressure decreased. Since 1989, this natural fluid recharge has been supplemented by injection which presently amounts to about 20% of the fluid produced. Changes in the chemical and physical characteristics of the reservoir fluids due to the drop in pressures and the inflow of cooler groundwaters and injectate have been detected on the basis of wellhead data. These changes point to reservoir processes like local boiling, phase segregation, steam condensation, mixing and dilution. Finally, the study identified areas where fluids are entering the reservoir, as well as indicated their source (i.e. natural Groundwater recharge versus injectate) and established the controlling geologic structures.

  17. Cerro Prieto cold water injection: effects on nearby production wells

    Energy Technology Data Exchange (ETDEWEB)

    Truesdell, A.H.; Lippmann, M.J.; De Leon, J.; Rodriguez, M.H.

    1999-07-01

    The liquid-dominated Cerro Prieto geothermal field of northern Baja California, Mexico has been under commercial exploitation since 1973. During the early years of operation, all waste brines were sent to an evaporation pond built west of the production area. In 1989, cooled pond brines began to be successfully injected into the reservoir along the western boundary of the geothermal system. The injection rate varied over the years, and is at present about 20% of the total fluid extracted. As expected under the continental desert conditions prevailing in the area, the temperature and salinity of the pond brines change with the seasons, being higher during the summer and lower during the winter. The chemistry of pond brines is also affected by precipitation of silica, oxidation of H{sub 2}S and reaction with airborne clays. Several production wells in the western part of the field (CP-I area) showed beneficial effects from injection. The chemical (chloride, isotopic) and physical (enthalpy, flow rate) changes observed in producers close to the injectors are reviewed. Some wells showed steam flow increases, in others steam flow decline rates flattened. Because of their higher density, injected brines migrated downward in the reservoir and showed up in deep wells.

  18. Performance of casings in Cerro Prieto production wells

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A, B.; Vital B, F.; Bermejo M, F.; Sanchez G, G.

    1981-01-01

    A careful evaluation of different production casings used at Cerro Prieto from 1964 to date has shown that the following casings have yielded particularly impressive results: 7 5/8-in. diameter, J-55, 26 lb/ft; 7 5/8-in. diameter, K-55, 45.3 lb/ft; and 5-in. diameter, K-55, 23.2 lb/ft. These casings differ from others of the same diameter but lighter weight which were also used at the field. The results are favorable in spite of severe construction problems, especially the loss of circulation during cementing operations, which we encountered in some of the wells where these casings were used. The use of gravity-fed fine sand as packing material and the arrangement of the production and intermediate casings were important in avoiding damage due to tension-compression stresses and, above all, damage due to internal or external corrosion over time. This situation is clearly evidenced if we compare the damage to the above casings with that experienced by grade N-80 production casings, especially in a corrosive environment.

  19. Interaction of cold-water aquifers with exploited reservoirs of the Cerro Prieto geothermal system

    Science.gov (United States)

    Truesdell, Alfred; Lippmann, Marcelo

    1990-01-01

    Cerro Prieto geothermal reservoirs tend to exhibit good hydraulic communication with adjacent cool groundwater aquifers. Under natural state conditions the hot fluids mix with the surrounding colder waters along the margins of the geothermal system, or discharge to shallow levels by flowing up fault L. In response to exploitation reservoir pressures decrease, leading to changes in the fluid flow pattern in the system and to groundwater influx. The various Cerro Prieto reservoirs have responded differently to production, showing localized near-well or generalized boiling, depending on their access to cool-water recharge. Significant cooling by dilution with groundwater has only been observed in wells located near the edges of the field. In general, entry of cool water at Cerro Prieto is beneficial because it tends to maintain reservoir pressures, restrict boiling, and lengthen the life and productivity of wells.

  20. SELF-POTENTIAL SURVEY AT THE CERRO PRIETO GEOTHERMAL FIELD, BAJA CALIFORNIA, MEXICO

    Energy Technology Data Exchange (ETDEWEB)

    Corwin, R.F.; Diaz C., S.; Rodriguez B., J.

    1978-06-01

    In December 1977, two self-potential survey lines were run across the producing area of the Cerro Prieto geothermal field, located about 30 km south of Mexicali, Baja California, Mexico. The purpose of the survey was to determine whether significant self-potential variations were related to the known geothermal activity. Large-amplitude, long-wavelength self-potential anomalies are seen in the Cerro Prieto geothermal field. The inflection points of the anomalies are roughly centered over two major faults thought to act as conduits for the thermal fluids, and the form of the anomalies indicates that they may be generated by electrical activity extending to a depth of several km along the fault zones. Thus, self-potential measurements may be helpful in tracing thermally active fault zones in the Cerro Prieto area.

  1. Gas equilibria in Cerro Prieto geothermal field, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Portugal, E.; Barragan, R.M.; Izquierdo, G. [Inst. de Investigaciones Electricas, Morelos (Mexico); Leon, J. de [Comision Federal de Electricidad, Mexicali B.C. (Mexico)

    2003-07-01

    Gas equlibria methods involving fischer-tropsch-pyrite-magnetite; and fischer-tropsch-pyrite-hematite-pyrite-magnetite reactions were used to evaluate reservoir temperature and a mass steam fraction in Cerro Prieto geothermal field. These approaches have been applied in some selected producing wells from four areas under exploitation. The results show good correlation for both equilibria methods; however fischer-tropsch; pyrite-magnetite reactions provide the best estimation of the physical reservoir parameters. The main processes found for Cerro Prieto IV area are lateral vapor contribution and the inflow of hotter and deeper fluid with high liquid saturation. (orig.)

  2. Measured ground-surface movements, Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Massey, B.L.

    1981-01-01

    The Cerro Prieto geothermal area in the Mexicali Valley, 30 kilometers southeast of Mexicali, Baja California, incurred slight deformation because of the extraction of hot water and steam, and probably, active tectonism. During 1977 to 1978, the US Geological Survey established and measured two networks of horizontal control in an effort to define both types of movement. These networks consisted of: (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from stations on an existing US Geological Survey crustal-strain network north of the international border; and (2) a local net tied to stations in the regional net and encompassing the present and planned geothermal production area. Electronic distance measuring instruments were used to measure the distances between stations in both networks in 1978, 1979 and 1981. Lines in the regional net averaged 25 km. in length and the standard deviation of an individual measurement is estimated to be approx. 0.3 part per million of line length. The local network was measured using different instrumentation and techniques. The average line length was about 5 km. and the standard deviation of an individual measurement approached 3 parts per million per line length. Ground-surface movements in the regional net, as measured by both the 1979 and 1981 resurveys, were small and did not exceed the noise level. The 1979 resurvey of the local net showed an apparent movement of 2 to 3 centimeters inward toward the center of the production area. This apparent movement was restricted to the general limits of the production area. The 1981 resurvey of the local net did not show increased movement attributable to fluid extraction.

  3. Fault Length Vs Fault Displacement Evaluation In The Case Of Cerro Prieto Pull-Apart Basin (Baja California, Mexico) Subsidence

    Science.gov (United States)

    Glowacka, E.; Sarychikhina, O.; Nava Pichardo, F. A.; Farfan, F.; Garcia Arthur, M. A.; Orozco, L.; Brassea, J.

    2013-05-01

    The Cerro Prieto pull-apart basin is located in the southern part of San Andreas Fault system, and is characterized by high seismicity, recent volcanism, tectonic deformation and hydrothermal activity (Lomnitz et al, 1970; Elders et al., 1984; Suárez-Vidal et al., 2008). Since the Cerro Prieto geothermal field production started, in 1973, significant subsidence increase was observed (Glowacka and Nava, 1996, Glowacka et al., 1999), and a relation between fluid extraction rate and subsidence rate has been suggested (op. cit.). Analysis of existing deformation data (Glowacka et al., 1999, 2005, Sarychikhina 2011) points to the fact that, although the extraction changes influence the subsidence rate, the tectonic faults control the spatial extent of the observed subsidence. Tectonic faults act as water barriers in the direction perpendicular to the fault, and/or separate regions with different compaction, and as effect the significant part of the subsidence is released as vertical displacement on the ground surface along fault rupture. These faults ruptures cause damages to roads and irrigation canals and water leakage. Since 1996, a network of geotechnical instruments has operated in the Mexicali Valley, for continuous recording of deformation phenomena. To date, the network (REDECVAM: Mexicali Valley Crustal Strain Measurement Array) includes two crackmeters and eight tiltmeters installed on, or very close to, the main faults; all instruments have sampling intervals in the 1 to 20 minutes range. Additionally, there are benchmarks for measuring vertical fault displacements for which readings are recorded every 3 months. Since the crackmeter measures vertical displacement on the fault at one place only, the question appears: can we use the crackmeter data to evaluate how long is the lenth of the fractured fault, and how quickly it grows, so we can know where we can expect fractures in the canals or roads? We used the Wells and Coppersmith (1994) relations between

  4. Active metasomatism in the Cerro Prieto geothermal system, Baja California, Mexico: a telescoped low pressure/temperature metamorphic facies series

    Energy Technology Data Exchange (ETDEWEB)

    Schiffman, P.; Elders, W.A.; Williams, A.E.; McDowell, S.D.; Bird, D.K.

    1983-01-01

    In the Cerro Prieto geothermal field, carbonate-cemented, quartzofeldspathic sediments of the Colorado River delta are being actively metasomatized into calc-silicate metamorphic rocks by reaction with alkali chloride brines between 200/sup 0/ and 370/sup 0/C, low fluid and lithostatic pressures, and low oxygen fugacities. Petrologic investigations of drill cores and cutting from over 50 wells in this field identified a prograde series of calc-silicate mineral zones which include as index minerals: wairakite, epidote, prehnite, and clinopyroxene. Associated divariant mineral assemblages are indicative of a very low pressure/temperature metamorphic facies series which encompasses the clay-carbonate, zeolite, greenschist, and amphibolite facies. This hydrothermal metamorphic facies series, which is becoming increasingly recognized in other active geothermal systems, is characterized by temperature-telescoped dehydration and decarbonation mineral equilibria. Its equivalent should now be sought in fossil hydrothermal systems.

  5. Application of oil-field well log interpretation techniques to the Cerro Prieto Geothermal Field

    Energy Technology Data Exchange (ETDEWEB)

    Ershaghi, I.; Phillips, L.B.; Dougherty, E.L.; Handy, L.L.

    1979-10-01

    An example is presented of the application of oil-field techniques to the Cerro Prieto Field, Mexico. The lithology in this field (sand-shale lithology) is relatively similar to oil-field systems. The study was undertaken as a part of the first series of case studies supported by the Geothermal Log Interpretation Program (GLIP) of the US Department of Energy. The suites of logs for individual wells were far from complete. This was partly because of adverse borehole conditions but mostly because of unavailability of high-temperature tools. The most complete set of logs was a combination of Dual Induction Laterolog, Compensated Formation Density Gamma Ray, Compensated Neutron Log, and Saraband. Temperature data about the wells were sketchy, and the logs had been run under pre-cooled mud condition. A system of interpretation consisting of a combination of graphic and numerical studies was used to study the logs. From graphical studies, evidence of hydrothermal alteration may be established from the trend analysis of SP (self potential) and ILD (deep induction log). Furthermore, the cross plot techniques using data from density and neutron logs may help in establishing compaction as well as rock density profile with depth. In the numerical method, R/sub wa/ values from three different resistivity logs were computed and brought into agreement. From this approach, values of formation temperature and mud filtrate resistivity effective at the time of logging were established.

  6. Case history report on East Mesa and Cerro Prieto geothermal fields

    Energy Technology Data Exchange (ETDEWEB)

    Davis, DG.; Sanyal, S.K.

    1979-06-01

    Well log analysis as applied to the geothermal industry is one of the areas of technology in great need of further development. One means of improving log analysis technology is to study case histories of the past uses of log analysis as applied to specific fields. The project described in this report involved case history studies on two well-known geothermal areas in North America: the East Mesa field in California and the Cerro Prieto field in Mexico. Since there was considerably more pertinent material available on East Mesa, a major part of the effort on this project was devoted to studying the East Mesa field. One particular problem that first came to attention when studying the Cerro Prieto data was the difficulty in determining actual formation temperature at the time of logging. Since the temperature can have a significant effect on well log readings, an accurate temperature determination was considered to be important.

  7. H2S and CO2 emissions from Cerro Prieto geothermal power plant, Mexico

    Science.gov (United States)

    Peralta, Oscar; Franco, Luis; Castro, Telma; Taran, Yuri; Bernard, Ruben; Inguaggiato, Salvatore; Navarro, Rafael; Saavedra, Isabel

    2014-05-01

    Cerro Prieto geothermal power plant has an operation capacity of 570 MW distributed in four powerhouses being the largest geothermal plant in Mexico. The geothermal field has 149 production wells. It is located in Cerro Prieto, Baja California, 30 km to the south of the Mexico-US border. Two sampling campaigns were performed in December 2012 and May 2013 where geothermal fluids from 46 production wells and 10 venting stacks were obtained and analyzed by gas chromatography coupled to mass spectrometry. Average CO2 and H2S composition of samples from venting stacks were 49.4% and 4.79%, respectively. Based on the chemical composition of samples, the geothermal power plant emits every day from venting stacks 869 tons of CO2, plus 68 tons of H2S, among other non-condensable gases.

  8. Progress report on LBL's numerical modeling studies on Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Halfman-Dooley, S.E.; Lippman, M.J.; Bodvarsson, G.S.

    1989-04-01

    An exploitation model of the Cerro Prieto geothermal system is needed to assess the energy capacity of the field, estimate its productive lifetime and develop an optimal reservoir management plan. The model must consider the natural state (i.e., pre-exploitation) conditions of the system and be able to predict changes in the reservoir thermodynamic conditions (and fluid chemistry) in response to fluid production (and injection). This paper discusses the results of a three-dimensional numerical simulation of the natural state conditions of the Cerro Prieto field and compares computed and observed pressure and temperature/enthalpy changes for the 1973--1987 production period. 16 refs., 24 figs., 2 tabs.

  9. Seismicity studies in the region of the Cerro Prieto Geothermal Field

    Energy Technology Data Exchange (ETDEWEB)

    Albores, A.; Reyes, A.; Brune, J.N.; Gonzalez, J.; Garcilazo, L.; Suarez, F.

    1980-01-01

    This paper reports results from seismicity studies in the region of the Cerro Prieto geothermal field. These studies were conducted with local short period seismic arrays during 1974-1975 and 1977-1978. During the latter period, horizontal seismometers were used for better control on the S-wave arrival times. Locations were obtained for about 200 events and composite fault plane solutions were obtained for five groups of events. 16 refs.

  10. Identification of fluid-flow paths in the Cerro Prieto geothermal field

    Science.gov (United States)

    Halfman, S. E.; Lippmann, M. J.; Zelwer, R.; Howard, J. H.

    1982-05-01

    A hydrogeologic model of the Cerro Prieto geothermal field has been developed based on geophysical and lithologic well logs, downhole temperature, and well completion data from about 90 deep wells. The hot brines seem to originate in the eastern part of the field, flowing in a westward direction and rising through gaps in the shaly layers which otherwise act as partial caprocks to the geothermal resource.

  11. A review of the hydrogeologic-geochemical model for Cerro Prieto

    Science.gov (United States)

    Lippmann, M.J.; Truesdell, A.H.; Halfman-Dooley, S. E.; Mañónm, A.

    1991-01-01

    With continued exploitation of the Cerro Prieto, Mexico, geothermal field, there is increasing evidence that the hydrogeologic model developed by Halfman and co-workers presents the basic features controlling the movement of geothermal fluids in the system. In mid-1987 the total installed capacity at Cerro Prieto reached 620 MWc, requiring a large rate of fluid production (more than 10,500 tonnes/hr of a brine-steam mixture; August 1988). This significant mass extraction has led to changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. Pressure drawdown has caused an increase in cold water recharge in the southern and western edges of the field, and local and general reservoir boiling in parts of the geothermal system. After reviewing the hydrogeologic and geochemical models of Cerro Prieto, the exploitation-induced cold water recharge and reservoir boiling (and plugging) observed in different areas of the field, are discussed and interpreted on the basis of these models and schematic flow models that describe the hydrogeology. ?? 1991.

  12. New data on the bottom topography, recent sedimentation and water balance of Cerro Prieto dam, Mexico

    Science.gov (United States)

    Yutsis, Vsevolod; Levchenko, Oleg; Lowag, Jens; Krivosheya, Konstantin; de León Gómez, Héctor; Kotsarenko, Anatolyi

    2010-05-01

    Cerro Prieto Dam, a small water reservoir in the NE Mexico, is characterized by very high velocity of recent sedimentation, high sub-bottom seepage and erosion, and as a result, nonlinear water balance. These phenomenons never were studied since construction of the dam in the beginning of 1980th. So the goal of our work was to investigate the bottom topography and also sub-bottom near surface structure using the parametric acoustical effect. High-resolution sub-bottom profiling, using the Innomar SES-2000 compact echosounder, was carried out in Cerro Prieto Dam during February-April of 2008. The survey was conducted onboard of a small motor boat. The SES transducer was mounted on the front side of the boat using light metal pipe, and all electronic equipment was installed on the deck. Accurate positioning of the boat was reached by GPS. Average speed was 8-10 km/h. Innomar's software tool ISE was provides near real-time post-processing of the collected SES data and operation procedure could be corrected on-line. Acoustic signal ensured vertical resolution of 10-15 cm at acceptable penetration up to 15 m. Bathymetry map was compiled assuming average sound velocity of 1450 m/s. The irregular bottom topography of Cerro Prieto dam was discovered. The present elevation of the water surface is about 181 m above see level, and the lake depth varies from 1-2 to 28 m. The SES records show a distinct bottom layer of recent sediments by 0.5 - 4 m thickness which follows reservoir floor topography. Very specific acoustic anomalies, which seem to be related with gas sediments, are observed. The integrated SES, gravity, magnetic and geoelectrical data interpretation allows assuming a series of the superficial fractures focused in a NW direction, perpendicular (NE-SW) to the general deep fault zone. Hydrological balance for the Cerro Prieto water reservoir has been analyzed for last two decades. There are three types of water level fluctuations on the Cerro Prieto dam: long

  13. Mexicali aquifer and its relation with the Colorado river and the Cerro Prieto geothermal reservoir

    Science.gov (United States)

    Ramirez-Hernandez, J.; Reyes-Lopez, J. A.; Carreon-Diazconti, C.; Lazaro-Mancilla, O.

    2008-05-01

    Until some years ago the Colorado River has been the main recharge source of the Mexicali and the Imperial Valley aquifers. River discharge interruption after the constructions of dams upstream (i.e. Parker, Davis and Hoover) and the creation of great irrigation systems in both Valleys have modified their dynamics. Currently, the distribution of water recharge is the network of irrigation and drainage channels that distribute water to more than 500.000 ha. The chemical quality of the recharge water also has changed because the irrigation run-off water has become more mineralized. On the other hand, the intense steam exploitation of the Cerro Prieto geothermal reservoir has inverted the flow direction from the Volcano Lagoon area that until the 60s constituted the discharge zone of the aquifer and the geothermal reservoir. In this work, changes in the aquifer water recharge regime, the phreatic level and the water chemical quality are analyzed. It was found that after the reduction of the annual water extraction from aquifer up to 750X106 m3, the static levels have reached a dynamic balance that could be altered if water seepage from the irrigation channels, specially from the All American Channel, is reduced. The total dissolved solids (TDS) concentration has increased from 1000 ppm in 1970 to 1800 ppm in 2005. The water of recent infiltration, the gradual cooling of the shallowest strata of the geothermal reservoir, and the almost total disappearance of the hydrothermal surface manifestations are evidences of groundwater flow inversion. The new source of groundwater recharge due to seepage of evaporation disposal geothermal brine pond is documented. This pond incorporates water with a very different chemical composition to the groundwater system. Therefore, mineralization of the shallow aquifer layers and the soil contamination process are identified. It was concluded that the aquifer hydrodynamics in the Valley of Mexicali depends on the irrigation system more

  14. Areas to explore surrounding the Cerro Prieto geothermal field, BC; Areas para exploracion en los alrededores del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

    2009-07-15

    Exploration plays an important role in tapping underground natural resources-whether water, oil, natural gas or minerals. Exploratory data allow us to learn reservoir conditions, increasing probable reserves and reservoir life span. Around the Cerro Prieto geothermal field, BC, and in the Mexicali Valley in general, exploration had almost stopped but recently was resumed by the Studies Division of Comision Federal de ELectricidad (CFE)'s Gerencia de Proyectos Geotermoelectricos. The division sent technical personnel to structurally map the northern and eastern portions of Laguna Salada. The paper offers a general outline of the main zones undergoing exploratory studies-studies perhaps culminating in siting exploratory wells to locate more geothermal resources (and ultimately producing them using binary power plants). CFE also wants to site injection wells west of the current production zone, and this is covered, as well. All activities are meant to increase the productive lifespan of the geothermal reservoir. [Spanish] Cuando se trata de la explotacion de recursos naturales del subsuelo, sea agua, gas, petroleo o minerales, la exploracion juega un papel muy importante, ya que permite conocer las condiciones del yacimiento que pudieran llevar a incrementar las reservas de los recursos explotados y extender su vida util. En las zonas aledanas al campo geotermico de Cerro Prieto, BC, y en general en el Valle de Mexicali, la exploracion estaba practicamente detenida habiendose reactivado a raiz de que la Subgerencia de Estudios de la Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad (CFE) envio personal para realizar mapeos estructurales en las porciones norte y oriente de la Laguna Salada. Este trabajo presenta un panorama general de las areas prioritarias para realizar estudios exploratorios y poder programar, con mas bases, pozos exploratorios enfocados a localizar mas recursos geotermicos, inclusive para generar energia por medio

  15. 222Radon Concentration Measurements biased to Cerro Prieto Fault for Verify its Continuity to the Northwest of the Mexicali Valley.

    Science.gov (United States)

    Lazaro-Mancilla, O.; Lopez, D. L.; Reyes-Lopez, J. A.; Carreón-Diazconti, C.; Ramirez-Hernandez, J.

    2009-05-01

    The need to know the exact location in the field of the fault traces in Mexicali has been an important affair due that the topography in this valley is almost flat and fault traces are hidden by plow zone, for this reason, the southern and northern ends of the San Jacinto and Cerro Prieto fault zones, respectively, are not well defined beneath the thick sequence of late Holocene Lake Cahuilla deposits. The purpose of this study was to verify if Cerro Prieto fault is the continuation to the southeast of the San Jacinto Fault proposed by Hogan in 2002 who based his analysis on pre-agriculture geomorphy, relocation and analysis of regional microseismicity, and trench exposures from a paleoseismic site in Laguna Xochimilco, Mexicali. In this study, four radon (222Rn) profiles were carried out in the Mexicali Valley, first, to the SW-NE of Cerro Prieto Volcano, second, to the W-E along the highway Libramiento San Luis Río Colorado-Tecate, third, to the W-E of Laguna Xochimilco and fourth, to the W-E of the Colonia Progreso. The Radon results allow us to identify in the Cerro Prieto profile four regions where the values exceed 100 picocuries per liter (pCi/L), these regions can be associated to fault traces, one of them associated to the Cerro Prieto Fault (200 pCi/L) and other related with Michoacán de Ocampo Fault (450 pCi/L). The profile Libramiento San Luis Río Colorado-Tecate, show three regions above 100 pCi/L, two of them related to the same faults. In spite of the results of the Laguna Xochimilco, site used by Hogan (2002), the profile permit us observe three regions above the 100 pCi/L, but we can associate only one of the regions above this level to the Michoacán de Ocampo Fault, but none region to the Cerro Prieto Fault. Finally in spite of the Colonia Progreso is the shortest profile with only five stations, it shows one region with a value of 270 pCi/L that we can correlate with the Cerro Prieto Fault. The results of this study allow us to think in the

  16. Numerical modeling of high-temperature deep wells in the Cerro Prieto geothermal field, Mexico

    OpenAIRE

    García, A.; F. Ascencio; Espinosa, G.; E. Santoyo; H. Gutiérrez; V. Arellano

    1999-01-01

    A numerical modeling study of three non-producing deep geothermal wells from Cerro Prieto is presented. We compute the expected production characteristics of these wells in order to determine if their inability to sustain flow was due to (i) heat loss effects in the well, (ii) the influence of production casing diameters, (iii) the transient heat loss during the first few days of well discharge, or (iv) the effect of secondary low-enthalpy inflows. A new version of the wellbore flow simulator...

  17. Two-dimensional modeling of apparent resistivity pseudosections in the Cerro Prieto region

    Energy Technology Data Exchange (ETDEWEB)

    Vega, R.; Martinez, M.

    1981-01-01

    Using a finite-difference program (Dey, 1976) for two-dimensional modeling of apparent resistivity pseudosections obtained by different measuring arrays, four apparent resistivity pseudosections obtained at Cerro Prieto with a Schlumberger array by CFE personnel were modeled (Razo, 1978). Using geologic (Puente and de la Pena, 1978) and lithologic (Diaz, et al., 1981) data from the geothermal region, models were obtained which show clearly that, for the actual resistivity present in the zone, the information contained in the measured pseudosections is primarily due to the near-surface structure and does not show either the presence of the geothermal reservoir or the granitic basement which underlies it.

  18. Overview of the Mexican-American cooperative program at the Cerro Prieto geothermal field

    Science.gov (United States)

    Lippmann, M. J.; Zelwer, R.

    1982-09-01

    The Lawrence Berkeley Laboratory is coordinating the US technical activities being carried out at Cerro Prieto under a five-year agreement between the US Department of Energy and the Comission Federal de Electricidad de Mexico. This agreement, signed in July 1977, is expected to expire in July 1982. Efforts are being made to continue some of the research beyond the formal termination of the agreement. A description of the program, which involves studies of geology, geophysics, hydrodynamics, subsidence, geothermal wells and reservoirs, and aquifers, is discussed.

  19. Preliminary plasma spectrometric analyses for selected elements in some geothermal waters from Cerro Prieto, Mexico

    Science.gov (United States)

    Ball, J.W.; Jenne, E.A.

    1983-01-01

    As part of a cooperative study with Dr. Alfred Truesdell, water samples collected from geothermal power production wells at Cerro Prieto, Mexico, were analyzed for selected elements by d.c. argon plasma emission spectroscopy. Spectral interferences due to the presence of high concentrations of Ca, Si, Na and K in these water affected the apparent concentration values obtained. These effects were evaluated and correction techniques were developed and applied to the analytical values. Precipitates present in the samples at the time of analysis adversely affected the accuracy, precision and interpretability of the data. (USGS)

  20. Reservoir Simulation on the Cerro Prieto Geothermal Field: A Continuing Study

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda, M.; Marquez, R.; Arellano, V.; Esquer, C.A.

    1983-12-15

    The Cerro Prieto geothermal field is a liquid-dominated geothermal reservoir of complex geological and hydrological structure. It is located at the southern end of the Salton-Mexicali trough which includes other geothermal anomalies as Heber and East Mesa. Although in 1973, the initial power plant installed capacity was 75 MW of electrical power, this amount increased to 180 MW in 1981 as field development continued. It is expected to have a generating capacity of 620 MW by the end of 1985, when two new plants will be completely in operation. Questions about field deliverability, reservoir life and ultimate recovery related to planned installations are being presently asked. Numerical modeling studies can give very valuable answers to these questions, even at the early stages in the development of a field. An effort to simulate the Cerro Prieto geothermal reservoir has been undergoing for almost two years. A joint project among Comision Federal de Electricidad (CFE), Instituto de Investigaciones Electricas (IIE) and Intercomp of Houstin, Texas, was created to perform reservoir engineering and simulation studies on this field. The final project objective is tosimulate the behavior of the old field region when production from additional wells located in the undeveloped field zones will be used for feeding the new power plants.

  1. Extension of the Cerro Prieto field and zones in the Mexicali Valley with geothermal possibilities in the future

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca L, H.L.; de la Pena L, A.; Puente C, I.; Diaz C, E.

    1981-01-01

    This study concerns the possible extension of the Cerro Prieto field and identification of other zones in the Mexicali Valley with geothermal development potential by assessing the structural geologic conditions in relation to the regional tectonic framework and the integration of geologic and geophysical surveys carried out at Cerro Prieto. This study is based on data obtained from the wells drilled to date and the available geological and geophysical information. With this information, a geologic model of the field is developed as a general description of the geometry of what might be the geothermal reservoir of the Cerro Prieto field. In areas with geothermal potential within the Mexicali Valley, the location of irrigation wells with anomalous temperatures was taken as a point of departure for subsequent studies. Based on this initial information, gravity and magnetic surveys were made, followed by seismic reflection and refraction surveys and the drilling of 1200-m-deep multiple-use wells. Based on the results of the final integration of these studies with the geology of the region, it is suggested that the following areas should be explored further: east of Cerro Prieto, Tulecheck, Riito, Aeropuerto-Algodones, and San Luis Rio Colorado, Sonora.

  2. Minimal thermodynamic conditions in the reservoir to produce steam at the Cerro Prieto geothermal field, BC; Condiciones termodinamicas minimas del yacimiento para producir vapor en el campo geotermico de Cerro Prieto, B.C.

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez; Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2009-01-15

    Minimal thermodynamic conditions in the Cerro Prieto geothermal reservoir for steam production are defined, taking into account the minimal acceptable steam production at the surface, considering a rank of mixed-enthalpies for different well-depths, and allowing proper assessments for the impacts of the changes in fluid reservoir pressure and enthalpy. Factors able to influence steam production are discussed. They have to be considered when deciding whether or not to drill or repair a well in a particular area of the reservoir. These evaluations become much more relevant by considering the huge thermodynamic changes that have occurred at the Cerro Prieto geothermal reservoir from its development, starting in 1973, which has lead to abandoning some steam producing areas in the field. [Spanish] Las condiciones termodinamicas minimas del yacimiento geotermico de Cerro Prieto, BC, para producir vapor se determinan tomando en cuenta la minima produccion de vapor aceptable en superficie, considerando un rango de entalpias de la mezcla y para diferentes profundidades de pozos, lo que permite valorar adecuadamente el impacto de la evolucion de la presion y entalpia del fluido en el yacimiento. Se discuten los factores que pueden afectar la produccion de vapor, los cuales se deben tomar en cuenta para determinar la conveniencia o no de perforar o reparar un pozo en determinada zona del yacimiento. Estas evaluaciones adquieren gran relevancia al considerar los enormes cambios termodinamicos que ha presentado el yacimiento geotermico de Cerro Prieto, como resultado de su explotacion iniciada en 1973, lo que ha llevado a abandonar algunas zonas del campo para la produccion de vapor. Palabras Clave: Cerro Prieto, entalpia, evaluacion de yacimientos, politicas de explotacion, presion, produccion de vapor.

  3. Temperature distribution in the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Castillo B, F.; Bermejo M, F.J.; Domiguez A, B.; Esquer P, C.A.; Navarro O, F.J.

    1981-01-01

    A series of temperature and pressure logs and flow rate measurements was compiled for each of the geothermal wells drilled to different reservoir depths between October 1979 and December 1980. Based on the valuable information obtained, a series of graphs showing the thermal characteristics of the reservoir were prepared. These graphs clearly show the temperature distribution resulting from the movement of fluids from the deep regions toward the higher zones of the reservoir, thus establishing more reliable parameters for locating new wells with better production zones. Updated information based on data from new deep wells drilled in the geothermal field is presented here. This new information does not differ much from earlier estimates and theories. However, the influence of faulting and fracturing on the hydrothermal recharge of the geothermal reservoir is seen more clearly.

  4. Presence of cross flow in the Cerro Prieto geothermal field, BC; Presencia de flujo cruzado en el campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2011-01-15

    During the development of Cerro Prieto geothermal field, BC, exploitation has increased gradually, causing a continuous drop in pressure to almost 100 bars in the central and eastern parts of the field. This has occurred despite the high natural recharge induced by the reservoir exploitation and helped by the high permeability of the reservoir and the wide availability of natural recharge of low-temperature water in the vicinity. The strata above the production zones have significantly lower temperatures than these zones, but due to the particular characteristics of the reservoir, do not have pressure drops. As the pressure of producing strata declines, the hydraulic pressure differential between them and the overlying strata increases. Thus in recent years the phenomenon of cross flow occurs with greater frequency and severity. In this paper, this phenomenon is analyzed, detailing the specific mechanisms favoring it and identifying the stage (drilling or workover) in which it commonly occurs. Rigorous supervision during these stages is crucial to identifying cross flow and to taking necessary measures to save the well. Cross flow cases are presented at different stages in the history of a well: during drilling, repair, before and during the stimulation, and during production. [Spanish] Durante el desarrollo del campo geotermico de Cerro Prieto, BC, la explotacion se ha incrementado en forma gradual provocando una continua caida de presion, que en las porciones central y oriente ha sido de casi 100 bars. Esto ha ocurrido a pesar de la enorme recarga natural inducida por la explotacion, favorecida por la alta permeabilidad del yacimiento y la gran disponibilidad de recarga natural de agua de baja temperatura en los alrededores del mismo. Los estratos ubicados encima de las zonas productoras presentan temperaturas significativamente menores que estos, pero debido a las caracteristicas particulares del yacimiento, no han presentado abatimiento en su presion. En la

  5. Microfaunal evidence of age and depositional environments of the Cerro Prieto section (Plio-Pleistocene), Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ingle, J.C. Jr.

    1982-01-01

    Microfossils including benthic and planktic foraminifera, ostracodes, calcareous algae, fish skeletal material, and fragments of pelecypods were found in 14 core samples from depths of 185 to 1952 m in the Cerro Prieto geothermal field, providing evidence of both the age and depositional history of sediments comprising the 3000-m-thick Pliocene and Pleistocene section in this area. Ostracodes of brackish water and marine origin constitute the most common microfossils present in this sequence occurring in 8 samples; in situ littoral and neritic species of benthic foraminifera occur in 5 samples with planktic species present in 2 samples. Distributional patterns of ostracodes and foraminifera together with previously analyzed lithofacies (Lyons and van de Kamp, 1980) indicate that the Cerro Prieto section represents an intertonguing complex of alluvial, deltaic, estuarine, and shallow marine environments deposited along the front of the Colorado River delta as it prograded across the Salton Trough during Pliocene and Pleistocene time. Foraminiferal evidence indicates that a sand and shale unit commonly present at depths between 700 and 1100 m represents a significant mid-Pleistocene marine incursion in the Cerro Prieto area. Tentative correlation of the Cerro Prieto section with the well dated Palm Springs Formation of the Imperial Valley, California area suggests that the Pliocene/Pleistocene boundary occurs at a depth of approximately 2000 m in the area of well M-93. Reworked specimens of Cretaceous foraminifera and fragments of the Cretaceous pelecypod Inoceramus were found in five samples further substantiating the Colorado Plateau provenance of a significant portion of the Colorado River deltaic sediments in the Cerro Prieto area.

  6. Active metasomatism in the Cerro Prieto geothermal system, Baja California, Mexico: A telescoped low-pressure, low-temperature metamorphic facies series

    Science.gov (United States)

    Schiffman, P.; Elders, W. A.; Williams, A. E.; McDowell, S. D.; Bird, D. K.

    1984-01-01

    In the Cerro Prieto geothermal field, carbonate-cemented, quartzofeldspathic sediments of the Colorado River delta are being actively metasomatized into calc-silicate metamorphic rocks by reaction with alkali chloride brines between 200 and 370 °C, at low fluid and lithostatic pressures and low oxygen fugacities. Our petrologic investigations of drill cores and cuttings from more than 50 wells in this field identified a prograde series of zones that include as index minerals wairakite, epidote, prehnite, and clinopyroxene. Associated divariant mineral assemblages are indicative of a very low pressure, low-temperature metamorphic facies series spanning the clay-carbonate, zeolite, greenschist, and amphibolite facies. This hydro-thermal facies series, which is now recognized in other active geothermal systems, is characterized by temperature-telescoped dehydration and decarbonation. Its equivalent can now be sought in fossil hydrothermal systems.

  7. Active metasomatism in the Cerro Prieto geothermal system, Baja California, Mexico: a telescoped low-pressure, low-temperature metamorphic facies series

    Energy Technology Data Exchange (ETDEWEB)

    Schiffman, P.; Elders, W.A.; Williams, A.E.; McDowell, S.D.; Bird, D.K.

    1984-01-01

    In the Cerro Prieto geothermal field, carbonate-cemented, quartzofeldspathic sediments of the Colorado River delta are being actively metasomatized into calc-silicate metamorphic rocks by reaction with alkali chloride brines between 200 and 370 C, at low fluid and lithostatic pressures and low oxygen fugacities. Their petrologic investigations of drill cores and cuttings from more than 50 wells in this field identified a prograde series of zones that include as index minerals wairakite, epidote, prehnite, and clinopyroxene. Associated divariant mineral assemblages are indicate of a very low pressure, low-temperature metamorphic facies series spanning the clay-carbonate, zeolite, greenschist, and amphibolite facies. This hydrothermal facies series, which is now recognized in other active geothermal systems, is characterized by temperature-telescoped dehydration and decarbonation. Its equivalent can now be sought in fossil hydrothermal systems.

  8. Mineralogy of the silica-epidote mineralized zone (SEMZ) in the Cerro Prieto geothermal reservoir, B.C., Mexico; Mineralogia de la zona mineralizada de silice-epidota (ZMSE) del yacimiento geotermico de Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Izquierdo, Georgina; Aragon, Alfonso; Portugal, Enrique; Arellano; Victor M [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico)]. E-mail: gim@iie.org.mx; Leon, Jesus de; Alvarez, Julio [Comision Federal de Electricidad, B.C. (Mexico)

    2006-07-15

    The distribution of hydrothermal minerals, mineral assemblages and fluid inclusion data were taken from drill cuttings from the production zone of wells all over the Cerro Prieto geothermal field. The production zone has been termed the silica-epidote mineralized zone (SEMZ), and is located in the deep part of the gray shale where thick layers of sandstone are found. Common mineral assemblages show three temperature ranges in the SEMZ: <200 degrees Celsius, 200-250 degrees Celsius and 250-300 degrees Celsius. The first range is characterized by clays, calcite and quartz; the second by quartz, epidote, chlorite and mica, and the third by epidote, amphibole, illite and chlorite. The study of fluid inclusions in authigenic grain quartz has shown two-phase fluid inclusions (liquid + vapor) of different salinities. A wide range exists of homogenization temperatures (Th) and for some wells there is a good agreement between Th and direct temperature measurements. [Spanish] Se determino la distribucion de minerales hidrotermales y las asociaciones parageneticas y se realizo el estudio microtermometrico de inclusiones fluidas a partir de recortes de perforacion de pozos de las distintas areas del campo geotermico de Cerro Prieto. Las muestras de recortes y nucleos de perforacion estudiados provienen de la zona de produccion a la que se le ha denominado Zona Mineralizada de Silice-Epidota (ZMSE), que se encuentra en la parte profunda de la lutita gris con importantes horizontes de areniscas. En esta zona las asociaciones parageneticas mas comunes han mostrado tres intervalos de temperatura para la ZMSE: <200 degrees Celsius, 200-250 degrees Celsius, 250-300 degrees Celsius. El primer intervalo esta caracterizado principalmente por arcillas, calcita y cuarzo; el segundo por cuarzo, epidota, clorita y micas, y el tercero por epidota, anfiboles, illita y clorita. El estudio de inclusiones fluidas en fragmentos de cuarzo autigenico mostro la presencia de inclusiones de dos fases

  9. Comments on some of the drilling and completion problems in Cerro Prieto geothermal wells

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A, B.; Sanchez G, G.

    1981-01-01

    From 1960 to the present, 85 wells with a total drilling length exceeding 160,000 m have been constructed at Cerro Prieto, a modest figure compared to an oil field. This activity took place in five stages, each characterized by changes and modifications required by various drilling and well-completion problems. Initially, the technical procedures followed were similar to those used in the oil industry. However, several problems emerged as a result of the relatively high temperatures found in the geothermal reservoir. The various problems that have been encountered can be considered to be related to drilling fluids, cements and cementing operations, lithology, geothermal fluid characteristics, and casings and their accessories. As the importance of high temperatures and the characteristics of the geothermal reservoir fluids were better understood, the criteria were modified to optimize well-completion operations, and satisfactory results have been achieved to date.

  10. Isotopic changes in the fluids of the Cerro Prieto {Beta} Reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Verma, Mahendra; Quijano, Luis; Gutierrez, Hector; Iglesias, Eduardo; Truesdell, Alfred

    1996-01-24

    Monitoring changes with time of the isotopes of water (18O and D) in wellhead fluids is an effective way of indicating reservoir changes and processes. Because 18O concentrations in water are altered by high-temperature exchange with rock oxygen and because both 18O and D are fractionated in vapor-liquid separation processes at the surface (separators and cooling towers), these isotopes are excellent indicators of inflow and distribution of fluids from outside the reservoir, either natural or injected. Studies of the isotopic compositions of fluids from the Cerro Prieto field in Baja California, Mexico show that pressure drawdown in the major β (beta) reservoir has caused intense boiling followed by inflow of water from outside the reservoir. A method of field exploitation based on this behavior is discussed.

  11. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Mazor, E. (Weizmann Inst. of Science, Rehovot, Israel); Truesdell, A.H.

    1981-01-01

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He, /sup 40/Ar) and atmospheric noble gases (Ne, Ar, and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic helium and argon-40 formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 to 3%) and mixing with shallow cold water occurred (0 to 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 to 3% steam separation and complement other tracers, such as Cl or temperature, which are effective only beyond this range.

  12. Bottom Topography, Recent Sedimentation and Water Volume of the Cerro Prieto Dam, NE Mexico

    Science.gov (United States)

    Yutsis, V. V.

    2012-12-01

    Cerro Prieto dam, relatively small water reservoir in the NE of Mexico, is characterized by a very high velocity of recent sedimentation, irregular bottom topography and sub-bottom seepage. Very high resolution seismic study using non-linear parametric echo sounder SES-2000 was carried out in this water reservoir, which is one of the main resources of potable water for the Monterrey, the city with a population of about four million inhabitants. A strong difference between water depth and hence the volume capacity calculated by National Commission of Water (Comision Nacional del Agua, CNA), Digital Elevation Model (DEM), and acoustic data was discovered. Very high rate of recent sedimentation due to damming is discussed. SES data interpretation shows that the thickness of recent sediments due to siltation of the reservoir reaches 3.5-4.0 m. Differences between the CNA and SES data indicate storage losses from 8-10 up to 30 million cubic meters due to sedimentation.

  13. Did stresses from the Cerro Prieto Geothermal Field influence the El Mayor-Cucapah rupture sequence?

    Science.gov (United States)

    Trugman, Daniel T.; Borsa, Adrian A.; Sandwell, David T.

    2014-12-01

    The Mw 7.2 El Mayor-Cucapah (EMC) earthquake ruptured a complex fault system in northern Baja California that was previously considered inactive. The Cerro Prieto Geothermal Field (CPGF), site of the world's second largest geothermal power plant, is located approximately 15 km to the northeast of the EMC hypocenter. We investigate whether anthropogenic fluid extraction at the CPGF caused a significant perturbation to the stress field in the EMC rupture zone. We use Advanced Land Observing Satellite interferometric synthetic aperture radar data to develop a laterally heterogeneous model of fluid extraction at the CPGF and estimate that this extraction generates positive Coulomb stressing rates of order 15 kPa/yr near the EMC hypocenter, a value which exceeds the local tectonic stressing rate. Although we cannot definitively conclude that production at the CPGF triggered the EMC earthquake, its influence on the local stress field is substantial and should not be neglected in local seismic hazard assessments.

  14. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    Science.gov (United States)

    Mazor, E.; Truesdell, A.H.

    1984-01-01

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He and 40Ar) and atmospheric noble gases (Ne, Ar and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water that penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic He and 40Ar formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 - 30%) and mixing with shallow cold water occurred (0 - 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 - 3% steam separation and complement other tracers, such as C1 or temperature, which are effective only beyond this range. ?? 1984.

  15. Results of the latest transient well pressure tests at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Abril G, A.; Vargas G, C.

    1981-01-01

    The equipment used in the interference and two-rate flow tests carried out at the Cerro Prieto geothermal field during 1980 are described. The results of two interference tests are presented, one between wells M-110 and M-104, and the other between wells M-7 and Q-757. The data was interpreted using type curve matching analysis. Results of two-rate flow tests carried out in wells M-102 and M-7 are also discussed. A technique for making two-rate flow tests is proposed. This approach, which attempts to avoid the uncertainty of present flow-rate measurements, makes use of devices for direct measurements of separated water and steam. Conclusions based on the above interpretations and recommendations for future tests are presented.

  16. Corrosion in pipelines and well casings at the Cerro Prieto geothermal field, BC; Corrosion en tuberias de linea y de revestimiento de pozos del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Miranda Herrera, Carlos A.; Canchola Felix, Ismael; Raygoza Flores, Joaquin; Mora Perez, Othon [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: carlos.miranda02@cfe.gob.mx

    2009-07-15

    In the area called Poligono Hidalgo, inside the Cerro Prieto IV zone in the Cerro Prieto geothermal field, BC, corrosion has occurred in the last few years on well casings and pipelines used for geothermal fluids. Corrosion test results are presented here for pipes, type API L-80 and ASTM A-53 grade B, which were subjected to condensate from wells 403 and 424. These wells have thrown corroded material from their respective casings. With these data we pinpoint corrosive conditions in this field area and determine which pipes are adequate to case wells in similar chemical, production conditions to minimize adverse effects and extend the life of the well, allowing more efficient exploitation of the deepest production zones in the reservoir. [Spanish] En el campo geotermico de Cerro Prieto, BC, dentro del area del Poligono Hidalgo en el sector conocido como Cerro Prieto IV, algunos pozos han presentado en los ultimos anos desgastes en sus tuberias de revestimiento y en las tuberias de linea para el transporte del fluido geotermico. Se presentan resultados de pruebas de corrosion con tuberias tipo API L-80 y ASTM A-53 grado B al ser sometidas al condensado de los pozos 403 y 424, los cuales han estado arrojando material de sus respectivas tuberias de revestimiento. Con estos datos se pretende conocer las condiciones corrosivas de esa zona del campo y determinar cual seria la tuberia ideal a utilizar en pozos con condiciones quimicas de produccion semejantes a fin de minimizar este efecto adverso y prolongar la vida de los pozos, a la vez que se permita la explotacion eficiente de las zonas productoras mas profundas del yacimiento.

  17. Study of the structural control of fluid flow within the Cerro Prieto Geothermal Field, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Noble, J.E.; Manon, M.A.; Lippmann, M.J.; Witherspoon, P.A.

    1977-10-01

    The Lawrence Berkeley Laboratory and the Comision Federal de Electricidad of Mexico are conducting a joint investigation of the Cerro Prieto Geothermal Field, located approximately 35 km south of Mexicali, Baja California, Mexico, in the Sea of Cortez-Salton Trough. Recent analyses of various geophysical/electrical logs, temperature logs, production and geochemical data and the subsequently developed preliminary model of the structure of the geothermal system and the distribution of geothermal fluids are presented. Techniques routinely applied to petroleum exploration were successfully used in the development of a preliminary model of this water-dominated system. The study indicates the upwelling of geothermal fluids along an east bounding fault from a deep, as yet unexplored source. The fluids dissipate into various sand horizons at various depths. The resulting stratigraphic and fluid flow model is of importance in planning additional developments of the Cerro Prieto Geothermal Field.

  18. Relationshipe Between Self-potential Anomalies and Hydraulic Flow In A Geothermal System: Application To Cerro-prieto, Baja California

    Science.gov (United States)

    Saracco, G.; Revil, A.; Pessel, M.

    The Cerro Prieto geothermal field is located in the alluvial plain of the Mexicali Valley, northern Baja California, Mexico, at about 35 km southeast of the city of Mexicali. The Cerro Prieto geothermal field is one of several high temperature water-dominated geothermal fields within the Salton Trough. We analyze here the self-potential distri- bution at the ground surface in order to determine the pattern of fluid flow in te sub- surface of this geothermal field. Various methods of analysis of self-potential anoma- lies are employed to reach this purpose. We use density probability tomography of monopolar and dipolar electrical sources and an Euler-type analysis. The hydraulic flow pattern found in this geothermal field is in agreement with that detemined from the heat flux inside the structure.

  19. Cerro prieto y su correlación con los centros de dispersión del Golfo de California

    OpenAIRE

    Francisco Suárez Vidal; Ana Luz Quintanilla Montoya

    1996-01-01

    The Cerro Prieto geothermal tield is located in the Mexicali Valley, Baia California. Tectonically, this northern part of the Gulf of California has been classitied as a spreadmg center, within a transitional area of oceanic to continental conditions. Thermal, geologic-tectonic and magnetic evidente has been used to postulate the existence of a heat source in the area that is associated with magmatic processes, similar to those that occur in a typical oceanic spreading center. Based on the pe...

  20. ANALYSIS OF RECHARGE COOLDOWN AT THE WESTERN BOUNDARY OF CERRO PRIETO I GEOTHERMAL FIELD

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, P.; Lam, S.; Hunsbedt, A.; Esquer, C.; Marquez, R.; Hernandez, L. Cobo, J.

    1985-01-22

    Extensive study of the Cerro Prieto geothermal field has provided much geologic and thermodynamic data of its structurally-complex, liquid-dominated reservoir. Several of the studies investigated the resource characteristics of fluid and energy flow. An early report by Mercado (1975) showed that the heat source for the part of the reservoir under development, now called Cerro Prieto I (CPI), originated in the eastern part of the field. Subsequent studies confirmed the flow of hot water from the east. A summary of several experimental and numerical studies of fluid and energy transport in the field was given by Lippmann and Bodvarsson (1983). The hydrogeologic model of Halfman et al. (1982) shows hot-water flow from the east divided into a shallow (alpha) aquifer at about 120Om and a deeper (beta) aquifer at about 170Om depth. A cross section along an east-west direction shows a central upflow to the two aquifers and uncertain geology beyond the western border of the field near well M-9. It also shows a fault dividing the line of border wells at M-29 from the inner wells at M-25 to the east. The hydrogeology of the field was described by Sanchez and de la Pena (1981) as an alluvial unit from the surface to about 700 m over the production zone and a shale-sandstone unit comprising an upper, shallow (alpha) aquifer bounded below by a basement horst overlying a deeper (beta) aquifer. To date, much of the cumulative production at Cerro Prieto I has been from the alpha aquifer. Piezometric level measurements over the first 5 years of operation showed a decline in the western zone beyond the production wells. Over the 10-year period of continuous production, a significant temperature decline has been observed along the westernmost line of wells. Several investigations of the recharge characteristics of the field have been reported. Mercado (1975) and Elders et al. (1984) indicated a flow of cold groundwater from the east. Mercado also noted that cold water was entering

  1. Intersecting faults and sandstone stratigraphy at the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Vonder Haar, S.; Howard, J.H.

    1980-02-01

    The northwest-southeast trending Cerro Prieto fault is part of a major regional lineament that extends into Sonaro and has characteristics of both a wrench fault and an oceanic transform fault. The distribution of lithologies and temperature within the field was studied by comparing data from well cuttings, cores, well logs, and geochemical analyses. Across the earliest developed portion of the field, in particular along a 1.25-km northeast-southwest section from well M-9 to M-10, interesting correlations emerge that indicate a relationship among lithology, microfracturing, and temperature distribution. In the upper portion of Reservoir A of this stratigraphic section, between 1200 and 1400 m, the percentage of sandstones ranges from 20 to 55. Temperatures are 225/sup 0/ to 275/sup 0/C based on well logs, calcite isotope maxima, and Na-K-Ca indices. The study shows that an isothermal high in this vicinity corresponds to the lowest total percentage of sandstones. Scanning electron microphotographs of well cores and cuttings from sandstone and shale units reveal clogging, mineral dissolution, and mineral precipitation along microfractures. The working hypothesis is that these sandy shale and siltstone facies are most amenable to increased microfracturing and, in turn, such microfracturing allows for higher temperature fluid to rise to shallower depths in the reservoir.

  2. Repetitive precision gravity studies at the Cerro Prieto and Heber geothermal fields

    Science.gov (United States)

    Grannell, R. B.

    1982-09-01

    To study subsidence and mass removal, a precise gravity network was established on 60 permanent monuments in the Cerro Prieto geothermal field in early 1978, and repeated annually through early 1981; the survey was tied to two bedrock sites outside the limits of the current production zone. The looping technique of station occupation was utilized, in which occupation of the base was followed by occupation of several stations, followed by a return to the base. Use of two LaCoste and Romberg gravity meters, and replication of values within loops as well as entire loops, enhanced precision such that the median standard deviations of the base-to-station differences, reduced to observed gravity values, ranged from 7 to 15 microgals for individual surveys. The smaller values were obtained as field and data reduction techniques were improved and experience was gained. A similar survey was initiated in the Heber area just north of the Mexican border in early 1980. It too was established on permanent monuments, was tied to bedrock stations outside the geothermal area, and used multiple repetitions of values with two meters to achieve high precision.

  3. Preliminary isotopic studies of fluids from the Cerro Prieto geothermal field

    Science.gov (United States)

    Truesdell, A.H.; Rye, R.O.; Pearson, F.J.; Olson, E.R.; Nehring, N.L.; Whelan, J.F.; Huebner, M.A.; Coplen, T.B.

    1979-01-01

    Preliminary isotopic studies of Cerro Prieto geothermal fluids and earlier studies of Mexicali Valley ground waters suggest local recharge of the geothermal system from the area immediately to the west. Oxygen isotope exchange of water with reservoir rock minerals at temperatures increasing with depth has produced fluids with oxygen-18 contents increasing with depth, and pressure drawdown in the southeastern part of the field has allowed lower oxygen-18 fluids to invade the production aquifer from above. The contents of tritium and carbon-14 in the fluid suggest only that the age of the fluid is between 50 and 10,000 years. The isotopic compositions of carbon and sulfur are consistent with a magmatic origin of these elements but a mixed sedimentary-organic origin appears more likely for carbon and is also possible for sulfur. Investigations of the isotopic compositions of geothermal and cold ground waters continue and are being expanded as fluids become available and as separation and analysis methods are improved. ?? 1979.

  4. Numerical Studies of the Heat and Mass Transport in the Cerro Prieto Geothermal Field, Mexico

    Science.gov (United States)

    Lippmann, M. J.; Bodavarsson, G. S.

    1983-06-01

    Numerical simulation techniques are employed in studies of the natural flow of heat and mass through the Cerro Prieto reservoir, Mexico and of the effects of exploitation on the field's behavior. The reservoir model is a two-dimensional vertical east to west-southwest cross section, which is based on a recent hydrogeologic model of this geothermal system. The numerical code MULKOM is used in the simulation studies. The steady state pressure and temperature distributions are computed and compared against observed preproduction pressures and temperatures; a reasonable match is obtained. A natural hot water recharge rate of about 1×10-2 kg/s per meter of field length (measured in a north-south direction) is obtained. The model is then used to simulate the behavior of the field during the 1973-1978 production period. The response of the model to fluid extraction agrees to what has been observed in the field or postulated by other authors. There is a decrease in temperatures and pressures in the produced region. No extensive two-phase zone develops in the reservoir because of the strong fluid recharge. Most of the fluid recharging the system comes from colder regions located above and west of the produced reservoir.

  5. Gas chemistry and thermometry of the Cerro Prieto, Mexico, geothermal field

    Science.gov (United States)

    Nehring, N.L.; D'Amore, F.

    1984-01-01

    Gas compositions of Cerro Prieto wells in 1977 reflected strong boiling in the reservoir around wells M-20 and M-25. This boiling zone appeared to be collapsing in 1982 when a number of wells in this area of the field were shut-in. In 1977 and 1982, gas compositions also showed boiling zones corresponding to faults H and L postulated by Halfman et al. (1982). Four gas geothermometers were applied, based on reservoir equilibria and calculated fugacities. The Fisher - Tropsch reaction predicted high temperatures and appeared to re-equilibrate slowly, whereas the H2S reaction predicted low temperatures and appeared to re-equilibrate rapidly. Hydrogen and NH3 reactions were intermediate. Like gas compositions, the geothermometers reflected reservoir processes, such as boiling. Surface gas compositions are related to well compositions, but contain large concentrations of N2 originating from air dissolved in groundwater. The groundwater appears to originate in the east and flow over the production field before mixing with reservoir gases near the surface. ?? 1984.

  6. Subsidence and Stress Change in the Cerro Prieto Geothermal Field, B. C., Mexico

    Science.gov (United States)

    Glowacka, E.; Sarychikhina, O.; Nava, F. A.

    2005-11-01

    Previous works have shown that ground deformation and seismicity in the Cerro Prieto geothermal field (CPGF) are due to both tectonics and field exploitation. Here, we use information about current tectonics and data from precision leveling surveys, to model tectonic and anthropogenic subsidence. Our results show that tectonic subsidence constitutes only ˜4% of the measured subsidence. Anthropogenic subsidence was evaluated using a model of rectangular tensional cracks, based on the hydrological model of the field, together with the Coulomb 2.0 program. From the resulting values of the fissure parameters and from extraction and injection data, we calculate that the volume changes caused by closure of the geothermal and cold water reservoirs account for only ˜3% and ˜7%, respectively, of the volume change which should occur due to extraction. Since 18% of the extracted fluids are reinjected, external recharge must compensate for about 72% of the expected volume reduction. An analysis of the changes in Coulomb stress caused by exploitation of the geothermal field suggest that even though the anthropogenic stresses account for only a fraction of tectonic stresses, they are large enough to trigger seismicity.

  7. Soil mercury levels in the area surrounding the Cerro Prieto geothermal complex, MEXICO.

    Science.gov (United States)

    Pastrana-Corral, M A; Wakida, F T; García-Flores, E; Rodriguez-Mendivil, D D; Quiñonez-Plaza, A; Piñon-Colin, T D J

    2016-08-01

    Even though geothermal energy is a renewable energy source that is seen as cost-effective and environmentally friendly, emissions from geothermal plants can impact air, soil, and water in the vicinity of geothermal power plants. The Cerro Prieto geothermal complex is located 30 km southeast of the city of Mexicali in the Mexican state of Baja California. Its installed electricity generation capacity is 720 MW, being the largest geothermal complex in Mexico. The objective of this study was to evaluate whether the emissions generated by the geothermal complex have increased the soil mercury concentration in the surrounding areas. Fifty-four surface soil samples were collected from the perimeter up to an approximate distance of 7660 m from the complex. Additionally, four soil depth profiles were performed in the vicinity of the complex. Mercury concentration in 69 % of the samples was higher than the mercury concentration found at the baseline sites. The mercury concentration ranged from 0.01 to 0.26 mg/kg. Our results show that the activities of the geothermal complex have led to an accumulation of mercury in the soil of the surrounding area. More studies are needed to determine the risk to human health and the ecosystems in the study area.

  8. Surface Deformation Associated with Geothermal Fluids Extraction at the Cerro Prieto Geothermal Field, Baja California, Mexico Revealed by DInSAR Technique

    Science.gov (United States)

    Sarychikhina, O.; Glowacka, E.; Mojarro, J.

    2016-08-01

    The Differential Synthetic Aperture Radar Interferometry (DInSAR) is widely used for surface deformation detection and monitoring.In this paper, ERS-1/2, ENVISAT and RADARSAT-2 synthetic aperture radar (SAR) images acquired between 1993 and 2014 were processed to investigate the evolution of surface deformation at the Cerro Prieto geothermal field, Baja California, Mexico. The conventional DInSAR together with the interferogram stacking method was applied. Average LOS (line of sight) displacement velocity maps were generated for different periods: 1993 - 1997, 1998 - 2000, 2004, 2005, 2007, 2009, and 2012 - 2014, revealing that the area corresponding to Cerro Prieto basin presented the important surface deformation (mainly subsidence) during the entire time of investigation. The changes in the surface deformation pattern and rate were identified. These changes have a good correlation in time with the changes of production in the Cerro Prieto geothermal field.

  9. Evolution of the CP-I sector of the Cerro Prieto geothermal reservoir, BC, and exploitation alternatives; Evolucion del sector CP-I del yacimiento geotermico de Cerro Prieto, BC, y alternativas de explotacion

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2010-01-15

    After 35 years of exploitation of the CP-I (Cerro Prieto I) sector of the Cerro Prieto geothermal field, its thermal conditions have been declined substantially; the number of production wells is reduced and exploitation has been abandoned in some zones. However with a binary cycle, it is still possible to generate electricity from the remaining reservoir energy. To do so, one needs to know a detailed reservoir history of the sector, identifying the best potential strata to be assessed. In this paper, the CP-I reservoir evolution is presented and its exploitation and main reservoir characteristics -which play important roles- are identified. The CP-I zones offering the best conditions for binary cycle exploitation are identified. Exploiting partially abandoned reservoir sections is crucial for the future of the field. If such sections can be made to produce, this will help reduce the progressive steam-production decline in the occurring since production began. The production decline had been mitigated by a large area available for drilling replacement production wells, but such an area is limited now, due to the vast number of operating wells. [Spanish] Despues de 35 anos de explotacion del yacimiento en el sector de CP-I (Cerro Prieto I) del campo geotermico de Cerro Prieto, BC, sus condiciones termicas han declinado considerablemente, por lo que el numero de pozos productores ha disminuido, dejando algunas zonas abandonadas a la explotacion. Sin embargo, aun es posible aprovechar la energia que contiene este sector del yacimiento para la generacion de electricidad mediante ciclo binario. Para ello primeramente se debe conocer en detalle cual ha sido la evolucion del yacimiento en este sector, identificando los estratos de mejor potencial para evaluarlos posteriormente. En este estudio se presenta la evolucion del yacimiento de CP-I como respuesta a su explotacion, identificando las principales caracteristicas del yacimiento que determinan su comportamiento. Asi

  10. Update of the basement model of the Cerro Prieto, B. C., geothermal field, Mexico; Actualizacion del modelo del basamento en el campo geotermico de Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Lopez, Macario [Residencia General de Cerro Prieto, Comision Federal de Electricidad, Mexicali, Baja California (Mexico)

    1999-04-01

    With the aim to actualize the basement model of the Cerro Prieto Geothermal Field, a gravity interpretation has been held. We modeled in 2.5 D, nine profiles traced over the Bouguer anomaly map. Well data concerning lithology and density changes were used to fit the gravity models. Results of this work confirm that the geometry of the basement of Cerro Prieto, corresponds to a structural sequence. From west to east it starts as a big depression, continues with a strong uplift of the basement in the middle sector and finally deepens eastward in steps. The basement model proposed in the present work, defines a similar trend to that established by Fonseca y Razo (1980), but there are differences in basement depth in some areas. In the present model we interpret basement depths between 200 and 400 m deeper than in previous models to the south and northwest of the actual exploitation zone. [Spanish] Con el fin de actualizar el modelo del basamento en el Campo Geotermico de Cerro Prieto, se realizo una reinterpretacion gravimetrica, modelando en 2.5 D, 9 perfiles trazados sobre el mapa de anomalia de Bouguer. Utilizando la informacion litologica obtenida a traves de numerosas perforaciones profundas, se hicieron coincidir, dentro de los mofelos gravimetricos, las principales variaciones litologicas con cambios en la densidad. Los resultados de este trabajo reiteran que la geometria del basamento del Campo de Cerro Prieto, vista de W a E, corresponde con una secuencia estructural que se inicia con una gran depresion en el W, continua con un fuerte levantamiento y finalmente se extiende con una tendencia a profundizarse hacia el E de forma escalonada. El modelo de basamento derivado del presente trabajo, define una tendencia muy similar al modelo de basamento establecido (Fonseca y Razo, 1980), pero difiere en cuanto a la profundidad en algunos sectores del campo. En el actual trabajo se interpreta una profundidad entre 200 y 400 m mayor hacia el sur y noroeste de la

  11. Criteria to determine the depth of the production interval in wells of the Cerro Prieto geothermal field, Mexico; Criterios para determinar la profundidad del intervalo productor en pozos del campo geotermico de Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Leon Vivar, Jesus Saul de [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: jesus.deleon@cfe.gob.mx

    2006-07-15

    Ways to select the depth of the production interval or to complete wells in the Cerro Prieto geothermal field have changed during the development of the field. From 1961 when drilling began to the middle of 2005, a total of 325 wells were drilled. The paper compares the approaches used in the past with those of the last ten years. The Cerro Prieto system has been classified as being of liquid-dominated and high-temperature. Today, after 33 years of commercial exploitation, it has experienced a series of thermal and geochemical fluid changes making it necessary to modify the ways to select the depth of the well production intervals, according to the observed behavior of the reservoir. The new criteria include the thermal approach, the geological approach, the geochemical approach and a comparative approach with neighboring wells. If most of these criteria are interpreted correctly, the success of a well is ensured. [Spanish] Los criterios para seleccionar la profundidad del intervalo productor o la terminacion de los pozos en el campo geotermico de Cerro Prieto han cambiado durante el desarrollo del mismo. De 1961, cuando se perforaron los primeros pozos, hasta mediados del 2005 se han perforado un total de 325 pozos. En el presente articulo se hara una breve revision de cuales han sido los criterios usados en el pasado y los que se han venido empleando en los ultimos diez anos. El yacimiento de Cerro Prieto ha sido clasificado como de liquido dominante, de alta temperatura, pero actualmente, despues de 33 anos de explotacion comercial, ha sufrido una serie de cambios termicos y geoquimicos en sus fluidos, por lo que ha sido necesario modificar los criterios para seleccionar la profundidad del intervalo productor de los pozos de acuerdo al comportamiento observado en el yacimiento. Los criterios actuales se dividen en cuatro: 1. Criterio termico, 2. Criterio geologico, 3. Criterio geoquimico y 4. Criterio comparativo de los pozos vecinos. Cuando la mayoria de estos

  12. Oxygen isotope exchange in rocks and minerals from the Cerro Prieto geothermal system: Indicators of temperature distribution and fluid flow

    Science.gov (United States)

    Williams, A. E.; Elders, W. A.

    1981-12-01

    Paleotemperatures different from the present thermal regime were studied by examining coexisting mineral systems which exchanged their oxygen with the geothermal brines at different rates. Oxygen isotopic compositions were measured in drill cuttings and core and core samples from more than 40 wells. Oxygen isotopic profiles of pore filling calcites in sandstones are a measure of the recent equilibrium temperature distribution. A three dimensional map was developed, showing the equilibrium temperatures in the geothermal field. A mass balance calculation was performed using measured 18O enrichment of the geothermal brine. This calculation implies an overall water; rock volume ratio of approximately 3:1 during the history of the Cerro Prieto system.

  13. Production induced boiling and cold water entry in the Cerro Prieto geothermal reservoir indicated by chemical and physical measurements

    Science.gov (United States)

    Grant, M.A.; Truesdell, A.H.; Manon, M.A.

    1984-01-01

    Chemical and physical data suggest that the relatively shallow, western part of the Cerro Prieto reservoir is bounded below by low permeability rocks, and above and at the sides by an interface with cooler water. There is no continuous permeability barrier around or immediately above the reservoir. Permeability within the reservoir is dominantly intergranular. Mixture with cooler water rather than boiling is the dominant cooling process in the natural state, and production causes displacement of hot water by cooler water, not by vapour. Local boiling occurs near most wells in response to pressure decreases, but no general vapour zone has formed. ?? 1984.

  14. Production induced boiling and cold water entry in the Cerro Prieto geothermal reservoir indicated by chemical and physical measurements

    Energy Technology Data Exchange (ETDEWEB)

    Grant, M.A. (DSIR, Wellington, New Zealand); Truesdell, A.H.; Manon, A.

    1981-01-01

    Chemical and physical data suggest that the relatively shallow western part of the Cerro Prieto reservoir is bounded below by low permeability rocks, and above and at the sides by an interface with cooler water. There is no continuous permeability barrier around or immediately above the reservoir. Permeability within the reservoir is dominantly intergranular. Mixture with cooler water rather than boiling is the dominant cooling process in the natural state, and production causes displacement of hot water by cooler water, not by vapor. Local boiling occurs near most wells in response to pressure decreases, but no general vapor zone has formed.

  15. Carbon-13 variations in fluids from the Cerro Prieto geothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Janik, C.J.; Nehring, N.L.; Huebner, M.A.; Truesdell, A.H.

    1982-08-10

    The carbon isotope compositions of CO/sub 2/ in steam from Cerro Prieto production well have been measured for 1977, 1979, and 1982. Variations in the delta/sup 13/C values are caused by production-related changes in the chemical and physical parameters of the geothermal system. In 1977, most CO/sub 2/ in the reservoir was isotopically light (delta/sup 13/C = -6.4 +/- 0.4). Heavier CO/sub 2/ was produced from wells in the center of the field (M5,M26,M27) due to deposition of isotopically light calcite caused by near-well boiling. In 1979 nearly all well showed relatively heavy CO/sub 2/, probably due to expansion of aquifer boiling and calcite precipitation. In 1982, many wells in the central part of the field were shut in. The amount of drawndown decreased and as temperatures and pressures near the wells increased, the boiling zones collapsed. The CO/sub 2/ in the fluid then exchanged with the precipitated calcite and became isotopically lighter. The sensitivity of carbon isotopes to calcite precipitations caused by aquifer boiling and to reequilibration with this deposited calcite upon decrease of boiling suggests use as an indicator of these aquifer processes. Surficial CO/sub 2/ of thermal origin was collected in 1981. Generally, the carbon-13 contents were close to CO/sub 2/ from production wells except for high-temperature mud pots and fumaroles containing isotopically light CO/sub 2/ derived from near surface alteration of organic matter.

  16. Regional and local networks of horizontal control, Cerro Prieto geothermal area

    Science.gov (United States)

    Massey, B.L.

    1979-01-01

    The Cerro Prieto geothermal area in the Mexicali Valley 30 km southeast of Mexicali, Baja California, is probably deforming due to (1) the extraction of large volumes of steam and hot water, and (2) active tectonism. Two networks of precise horizontal control were established in Mexicali Valley by the U.S. Geological Survey in 1977 - 1978 to measure both types of movement as they occur. These networks consisted of (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from survey stations on an existing U.S. Geological Survey crustal-strain network north of the international border, and (2) a local net tied to stations in the regional net and encompassing the area of present and planned geothermal production. Survey lines in this net were selected to span areas of probable ground-surface movements in and around the geothermal area. Electronic distance measuring (EDM) instruments, operating with a modulated laser beam, were used to measure the distances between stations in both networks. The regional net was run using a highly precise long-range EDM instrument, helicopters for transportation of men and equipment to inaccessible stations on mountain peaks, and a fixed wing airplane flying along the line of sight. Precision of measurements with this complex long-range system approached 0-2 ppm of line length. The local net was measured with a medium-range EDM instrument requiring minimal ancillary equipment. Precision of measurements with this less complex system approached 3 ppm for the shorter line lengths. The detection and analysis of ground-surface movements resulting from tectonic strains or induced by geothermal fluid withdrawal is dependent on subsequent resurveys of these networks. ?? 1979.

  17. Changes in steam production due to the reservoir conditions in Cerro Prieto, Baja California; Cambios en la produccion de vapor debido a las condiciones del yacimiento en Cerro Prieto, Baja California

    Energy Technology Data Exchange (ETDEWEB)

    Morales Cardenas, Ramon; Rodriguez Rodriguez, Marco H. [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: marco.rodriguez01@gfe.gob.mx

    2011-07-15

    In more than 35 years of exploitation, thermodynamic conditions have changed in the Cerro Prieto geothermal reservoir. The effects are analyzed of the changes to the reservoir and their consequences to steam production in different field zones. For steam production, the most important features of reservoir fluids are enthalpies and pressures. The evolution of these features is presented in an enthalpy-pressure diagram. Here it can be seen that some reservoir zones have almost reached abandonment conditions. [Spanish] En mas de 35 anos de explotacion el yacimiento geotermico de Cerro Prieto ha experimentado cambios en sus condiciones termodinamicas. En este trabajo se analiza el efecto de esos cambios del yacimiento y su repercusion en la produccion de vapor para las diferentes zonas en las que se ha dividido el campo. Las propiedades mas importantes del fluido en el yacimiento para la produccion de vapor son su entalpia y su presion, por lo que se presenta la evolucion de esas propiedades en un diagrama de presion-entalpia, en el que se observa que hay zonas del yacimiento que estan proximas a alcanzar condiciones de abandono.

  18. Stress orientation and anisotropy based on shear-wave splitting observations in the Cerro Prieto fault area, Baja California, Mexico

    Science.gov (United States)

    Zúñiga, F. R.; Castro, R. R.; Domínguez, T.

    1995-03-01

    Digital seismograms continuously recorded from 1988 to 1992 by two stations of the RESNOM seismic network in northern Baja California, Mexico, were used to search for probable shear-wave anisotropic characteristics in the region of the Cerro Prieto fault. Shear-wave splitting was identified in many of the three-component records analyzed. We measured the polarization direction of the leading S wave inside the S-wave window as well as the delay times between fast and slow phases on those records displaying shear-wave splitting. For station CPX, which is nearest the Imperial Valley region to the north, the preferred polarization direction found in this study (azimuth 180°±10°) coincides with the direction of the regional maximum compressive stress determined for the region. This polarization direction can be interpreted in terms of the “Extensive Dilatancy Anisotropy” model as the effect of vertical parallel aligned cracks. The preferred polarization direction measured at LMX, however, gives an azimuth of 45°±5°. Thus, it appears that faults and fractures aligned oblique to the main tectonic trend have a greater influence on the anisotropic characteristics of the crust south of Cerro Prieto volcano than that of the regional stress field. Time delays between slow and fast S waves observed at CPX appear constant from 1988 to 1992 while delays measured at LMX for the same interval indicate a small increase with time which cannot be attributed to azimuthal variations of paths.

  19. Gases in steam from Cerro Prieto geothermal wells with a discussion of steam/gas ratio measurements

    Science.gov (United States)

    Nehring, N.L.; Fausto, L.J.J.

    1979-01-01

    As part of a joint USGS-CFE geochemical study of Cerro Prieto, steam samples were collected for gas analyses in April, 1977. Analyses of the major gas components of the steam were made by wet chemistry (for H2O,CO2,H2S and NH3) and by gas chromatography (He,H2,Ar,O2,N2 and hydrocarbons). The hydrocarbon gases in Cerro Prieto steam closely resemble hydrocarbons in steam from Larderello, Italy and The Geysers, California which, although they are vapor-dominated rather than hot-water geothermal systems, also have sedimentary aquifer rocks. These sedimentary geothermal hydrocarbons are characterized by the presence of branched C4-6 compounds and a lack of unsaturated compounds other than benzene. Relatively large amounts of benzene may be characteristic of high-temperature geothermal systems. All hydrocarbons in these gases other than methane most probably originate from the thermal metamorphosis of organic matter contained in the sediments. ?? 1979.

  20. Paleomagnetism of the Quaternary Cerro Prieto, Crater Elegante, and Salton Buttes volcanic domes in the northern part of the Gulf of California rhombochasm

    Energy Technology Data Exchange (ETDEWEB)

    de Boer, J.

    1980-02-01

    Deviating thermomagnetic directions in volcanics representing the second and fifth or sixth pulse of volcanism suggest that the Cerro Prieto volcano originated about 110,000 years B.P. and continued to be active intermittently until about 10,000 years ago.

  1. Land subsidence in the Cerro Prieto Geothermal Field, Baja California, Mexico, from 1994 to 2005: An integrated analysis of DInSAR, leveling and geological data

    Science.gov (United States)

    Sarychikhina, Olga; Glowacka, Ewa; Mellors, Robert; Vidal, Francisco Suárez

    2011-07-01

    Cerro Prieto is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field. The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to the local infrastructure such as roads, irrigation canals and other facilities. In this paper, the technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) is applied using C-band ENVISAR ASAR data acquired between 2003 and 2006 to determine the extent and amount of land subsidence in the Mexicali Valley near Cerro Prieto Geothermal Field. The DInSAR results were compared with published data from precise leveling surveys (1994-1997 and 1997-2006) and detailed geological information in order to improve understanding of the temporal and spatial distributions of anthropogenic subsidence in the Mexicali Valley. The leveling and DInSAR data were modeled to characterize the observed deformation in terms of fluid extraction. The results confirm that the tectonic faults control the spatial extent of the observed subsidence. These faults likely act as groundwater flow barriers for aquifers and reservoirs. The shape of the subsiding area coincides with the Cerro Prieto pull-apart basin. In addition, the changes in spatial pattern and rate of the subsidence are correlated with the development of the Cerro Prieto Geothermal Field.

  2. Land subsidence in the Cerro Prieto Geothermal Field, 1 Baja California, Mexico, from 1994 to 2005. An integrated analysis of DInSAR, levelingand geological data.

    Energy Technology Data Exchange (ETDEWEB)

    Sarychikhina, O; Glowacka, E; Mellors, R; Vidal, F S

    2011-03-03

    Cerro Prieto is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field. The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to infrastructure such as roads, irrigation canals and other facilities. In this paper, the technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) is applied using C-band ENVISAR ASAR data acquired between 2003 and 2006 to determine the extent and amount of land subsidence in the Mexicali Valley near Cerro Prieto Geothermal Field. The DInSAR results were compared with published data from precise leveling surveys (1994- 1997 and 1997-2006) and detailed geological information in order to improve the understanding of temporal and spatial distributions of anthropogenic subsidence in the Mexicali Valley. The leveling and DInSAR data were modeled to characterize the observed deformation in terms of fluid extraction. The results confirm that the tectonic faults control the spatial extent of the observed subsidence. These faults likely act as groundwater flow barriers for aquifers and reservoirs. The shape of the subsiding area coincides with the Cerro Prieto pull-apart basin. In addition, the spatial pattern of the subsidence as well as changes in rate are highly correlated with the development of the Cerro Prieto Geothermal Field.

  3. Hydraulic model of the steam-lines network of the Cerro Prieto, B.C., geothermal field; Modelo hidraulico de la red de vaporductos del campo geotermico de Cerro Prieto, B.C.

    Energy Technology Data Exchange (ETDEWEB)

    Salaices, E; Garcia, A; Martinez J I; Ovando, R; Cecenas, M; Hernandez A F [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: salaices@iie.org.mx; Canchola, I; Mora, O; Miranda, C; Herandez, M; Lopez, S; Murillo, I [Comision Federal de Electricidad, B.C (Mexico)

    2007-01-15

    The steam-line network of the Cerro Prieto geothermal field is composed of 184 wells, and 162 of the wells are integrated and connected by pipes. Thirteen power units, with an installed electrical capacity of 720 MW, are fed by that network. The network length is 120 km, including pipes of several diameters with branches and interconnections. The extension and complexity of the steam-line system make it difficult to analyze the transport and supply of steam to the power plants. For that it was necessary to have a tool capable of analyzing the system and the performance of the network as a whole, as well as the direction and flow volumes in each part of the system. In this paper, a hydraulic model of the Cerro Prieto steam-line network is presented. The model can determine the performance of the whole network by quantifying the pressure drops, flows and heat losses of the components. The model analyses the consequences of changes in operating conditions, steam production, maintenance activities and design (such as the integration of new wells). The model was developed using PIPEPHASE 9.0, a numeric simulator of multi-phase flow in steady state with heat transfer. It is used to model systems and pipe networks for steam- and condensate-transport. [Spanish] La red de vaporductos del campo geotermico de Cerro Prieto esta compuesta por un conjunto de 184 pozos, de los cuales 162 son pozos integrados, interconectados entre si a traves de una red de tuberias. Por medio de esta red se alimentan 13 unidades generadoras de electricidad con una capacidad total instalada de 720 MWe. La red tiene una longitud aproximada de 120 kilometros y esta compuesta por tuberias de diferentes diametros, ramales, interconexiones, etc. La complejidad y extension del sistema de vaporductos hace muy dificil el analisis del transporte y suministro de vapor a las plantas generadoras. Lo anterior creo la necesidad de contar con una herramienta que ayudara en el analisis del sistema con el fin de

  4. Configuration of the mudstones, gray- and coffee-colored shale lithologic units, zones of silica and epidote, and their relation to the tectonics of the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Cobo R, J.M.

    1981-01-01

    Based on well cuttings, five lithological units have been recognized within the area of what is now the Cerro Prieto geothermal field. These five units are described. Differences in origin, mineralogy, grading, color, compaction, etc., are shown.

  5. Cost model for geothermal wells applied to the Cerro Prieto geothermal field case, BC Abstract; Modelo de costeo de pozos geotermicos aplicado para el caso del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Vaca Serrano, Jaime M.E [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)]. E-mail: jaime.vaca@cfe.gob.mx

    2008-01-15

    A project for drilling geothermal wells to produce electrical energy can be defined as a sequence of plans to get steam or geothermal fluids to satisfy a previously known demand, and, under the best possible conditions, to obtain payment. This paper presents a cost model for nine wells drilled at the Cerro Prieto geothermal field in 2005 and 2006 to supply steam to the power plants operating in the field. The cost model is based on the well cost, the initial steam production, the annual decline of steam, the drilling schedule and the break-even point for each well. The model shows the cost of steam by the ton and the sale price needed to determine the discount rate and the investment return time. [Spanish] Un proyecto de perforacion de pozos geotermicos puede definirse como una secuencia o sucesion de planes para obtener vapor o fluidos geotermicos destinados a satisfacer una demanda previamente determinada, que se emplearan principalmente para generar energia electrica, bajo las mejores condiciones para obtener un pago. Este trabajo presenta un modelo de costeo para nueve pozos en el campo geotermico de Cerro Prieto, que fueron perforados entre 2005 y 2006 como parte del suministro de vapor para las plantas generadoras que operan en este campo. El modelo de costeo se basa en el costo por pozo, la produccion inicial de vapor, la declinacion anual de vapor, los intereses de las obras de perforacion y el punto de equilibrio para cada pozo. Los resultados permiten conocer el costo de la tonelada de vapor y el precio de venta para determinar la tasa de descuento y el tiempo de retorno de la inversion.

  6. Noise reduction in steam-vent points at the Cerro Prieto geothermal field, BC; Reduccion del ruido en puntos de desfogue en el campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Miranda Herrera, Carlos A [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C (Mexico)]. E-mail: carlos.miranda02@cfe.gob.mx

    2008-01-15

    Steam silencers have been placed on the power units regulation system of the Cerro Prieto geothermal field, but not where the steam-pipes vent high-pressure steam (rupture disks). Moreover, the power-unit silencers are large and their abilities to reduce noise depend on an external, uncontrollable factor: pores sizes in the volcanic rocks they are made of. Thus a compact, economic and relatively easy to construct metallic silencer was designed to be used at several points of dry-steam venting to minimize the noise. The design was based on orifice-plate equations and a prototype was constructed and tested. It proved capable of reducing noise by 30 decibels for atmospheric discharges of primary steam at operating pressures. The size of the silencer can be adjusted to the particular needs of each vent case. [Spanish] En el campo geotermico de Cerro Prieto solo existen silenciadores de vapor en el sistema de regulacion de las plantas generadoras, pero no en los sitios de desfogue de vapor a alta presion en los vaporductos (discos de ruptura). Ademas, los silenciadores de las plantas son muy robustos y su capacidad de reduccion del ruido depende de un factor externo no controlable, como es el tamano del poro de la roca volcanica con el que estan construidos. Por lo tanto, se diseno un silenciador metalico compacto, economico y relativamente facil de fabricar, para utilizarse en diversos puntos de descarga de vapor seco a fin de minimizar el ruido. El diseno se realizo con base en las ecuaciones de la placa de orificio. Se construyo un prototipo cuyas pruebas demostraron que es capaz de reducir el ruido hasta en 30 decibeles, al descargar desde la presion de operacion de vapor primario hacia la presion atmosferica. Las dimensiones del silenciador pueden ajustarse a las necesidades particulares de cada caso de desfogue.

  7. Dry steam feed zones and silica scaling as major controls of total flow enthalpy at Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Beall, J.J. [Calpine Corp., Santa Rosa, CA (United States); Ledesma, A.P.; Dios Ocampo, J. de [Constructora y Perforadora Latina S.A., Baja California (Mexico)

    1997-12-31

    Enthalpy and chloride data for Cerro Prieto well fluids define a mixing line between original reservoir liquid (1,300-1,500 J/g, 9,000-11,000 ppm Cl) and superheated steam (2870 J/g, 0 ppm Cl). The mixing relationship establishes that dry steam feed zones contribute to the total fluid flow of many wells. Fluids produced from newly completed or worked over wells often show rapid movement in either direction along the enthalpy-chloride mixing line. The direction of movement along the enthalpy-chloride mixing line depends upon whether increased formation boiling (increasing the dry steam flow to the well) or silica scaling in the formation and on the surface of the well bore (which inhibits the flow of dry steam) is the dominant process.

  8. Results of the first order leveling surveys in the Mexicali Valley and at the Cerro Prieto field

    Energy Technology Data Exchange (ETDEWEB)

    de la Pena L, A.

    1981-01-01

    The results obtained from the third leveling survey carried out by the Direccion General de Geografia del Territorio Nacional (previously DETENAL) during November and December 1979 are presented. Calculations of the changes in field elevation and plots showing comparisons of the 1977, 1978, and 1979 surveys are also presented. Results from a second order leveling survey performed to ascertain the extent of ground motion resulting from the 8 June 1980 earthquake are presented. This magnitude ML = 6.7 earthquake with epicenter located 15 km southeast of the Guadalupe Victoria village, caused fissures on the surface, the formation of small sand volcanos, and the ejection of ground water in the vicinity of the Cerro Prieto field. This leveling survey was carried out between benchmark BN-10067 at the intersection of the Solfatara canal and the Sonora-Baja California railroad, and benchmark BN-10055 located at the Delta station.

  9. Curie point depth from spectral analysis of aeromagnetic data from Cerro Prieto geothermal area, Baja California, México

    Science.gov (United States)

    Espinosa-Cardeña, J. M.; Campos-Enriquez, J. O.

    2008-10-01

    Using aeromagnetic data acquired in the area from the Cerro Prieto geothermal field, we estimated the depth to the Curie point isotherm, interpreted as the base of the magnetic sources, following statistical spectral-based techniques. According to our results the Curie point isotherm is located at a depths ranging from 14 to 17 km. Our result is somewhat deeper than that obtained previously based only in 2-D and 3-D forward modeling of previous low-quality data. However, our results are supported by independent information comprising geothermal gradients, seismicity distribution in the crust, and gravity determined crustal thickness. Our results imply a high thermal gradient (ranging between 33 and 38 °C/km) and high heat flow (of about 100 mW/m 2) for the study area. The thermal regime for the area is inferred to be similar to that from the Salton trough.

  10. Seismic activity at the Cerro Prieto Geothermal Area (Mexico) from August 1994 to December 1995, and its relationship with tectonics and fluid exploitation

    Science.gov (United States)

    Fabriol, H.; Munguía, L.

    A continuous monitoring of the Cerro Prieto geothermal field was carried out from August 1994 to December 1995 to investigate the seismicity of tectonic origin and the seismicity triggered by exploitation activities. Hypocenters for 148 events were located mainly around the northern end of the Cerro Prieto fault and within the geothermal zone. The estimated focal depths range mostly from 1 to 6 km, for earthquakes with magnitudes from 0.5 to 4.6. It was difficult to distinguish between natural and triggered seismicity. We observed a single case of an earthquake for which a correlation in time and space seems plausible with a sharp increase of fluid injection in a well located at less than 1 km from the epicenter. Fault plane solutions of 26 events with magnitudes between 2.8 and 4.6 indicate right-lateral strike-slip motion for earthquakes that occur near the Cerro Prieto and Imperial faults. Inside the geothermal zone, events with normal components of motion were recorded, as expected from the extensional stress regime of the pull-apart basin laying between both faults.

  11. Studies for recovering injection capacity in wells of the Cerro Prieto, BC, geothermal field; Estudios para recuperar la capacidad de aceptacion en pozos inyectores del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez Rosales, Julio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: julio.alvarez@cfe.gob.mx

    2010-01-15

    As in geothermal fields around the world, at Cerro Prieto geothermal field, Baja California, former exploratory and production wells are used to inject residual brine. Since the 1980s, studies and activities have been carried out to find ways to recharge the reservoir and dispose of brine without harming the environment or underground aquifers. These include infiltration and cold-and-hot injection. Some of the studies are presented here, including analyses of litho-facies; core samples; pressure, temperature and spinner logs; well tests and injection rates-plus some studies on the shallow aquifer. All have been useful in fulfilling requirements made by environmental authorities. Because injection rates constantly decrease due to formation damage, it is proposed an additional technique be used to reduce such damages and prolong the lifetime of cold-and-hot injection wells-while ensuring the environment and shallow aquifers are not affected. [Spanish] Al igual que en diversos campos geotermicos en el mundo, en el de Cerro Prieto, Baja California se han utilizado tanto pozos inyectores perforados ex profeso como antiguos pozos exploratorios y productores para inyectar el fluido residual al subsuelo. Desde la decada de los 80 se han realizado diversos estudios y acciones en ese campo geotermico para recargar al yacimiento y para disponer del fluido residual, sin ocasionar danos al ambiente ni a los cuerpos hidricos del subsuelo, que van desde la infiltracion hasta la inyeccion en frio y en caliente. Este articulo presenta los diferentes estudios realizados con ese objetivo en el campo, incluyendo el analisis de litofacies, de nucleos de formacion, de registros de presion, temperatura y spinner, las pruebas en pozos y analisis de tasas de aceptacion, asi como los efectuados en el acuifero superficial. Todos ellos han sido de utilidad para atender los requerimientos de las autoridades ambientales. Finalmente, y en virtud de que las tasas de aceptacion de los pozos

  12. Geological and production analyses focused on exploration of the eastern part of the Cerro Prieto geothermal field, BC; Analisis geologico-productivo enfocado a la exploracion de la parte oriental del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

    2008-01-15

    The eastern part of the Cerro Prieto geothermal field (CGCP), known as Poligono Nuevo Leon, is an area with proven geothermal resources, as confirmed by seven directional wells located toward the east and by vertical well M-200 located inside the polygon. Well M-200 was drilled in 1984 and has produced about 4 million tons of steam to date. It is integrated into the CP-2 sector, producing 68 t/h of steam. Presently the eastern part of CGCP, representing 25% of the total field area, is producing over half of the steam for the entire field. In the last few years, the steam has come only after increasing the number of production wells located in the eastern zone of CGCP (Rodriguez, 2006), where pressure, enthalpy and temperature conditions are better than in other parts of the field. However in the long term it will be necessary to incorporate Poligono Nuevo Leon into the productive area to expand the productive life of CGCP. This paper includes a geological analysis, plus models for steam production, temperature and enthalpy for Poligono Nuevo Leon. [Spanish] La parte oriental del Campo Geotermico de Cerro Prieto (CGCP), conocida como Poligono Nuevo Leon, representa una area potencial con recursos geotermicos comprobados, lo que demuestran siete pozos direccionales que se han perforado hacia el este, asi como el pozo vertical M-200, localizado dentro del poligono. El pozo M-200 se perforo en 1984 y ha producido a la fecha alrededor de 4 millones de toneladas de vapor, estando integrado al sector CP-2 una produccion de 68 t/h de vapor. Actualmente la parte oriental del CGCP, que representa el 25% del area total del campo, produce mas de la mitad del total de vapor del campo. El suministro de vapor en los ultimos anos se ha logrado cubrir aumentando el numero de pozos en operacion localizados en la zona oriente del CGCP (Rodriguez, 2006), ya que es aqui donde hay condiciones de presion, entalpia y temperatura del yacimiento que son mejores que en otras areas del campo

  13. Two-phase characteristics of the feeding fluid of Cerro Prieto IV wells (Mexico) obtained by gas equilibrium; Caracteristicas bifasicas del fluido de alimentacion de pozos de Cerro Prieto IV (Mexico), obtenidas por equilibrio gaseoso

    Energy Technology Data Exchange (ETDEWEB)

    Barragan-Reyes, Rosa Maria; Arellano-Gomez, Victor Manuel; Portugal-Marin, Enrique [Instituto de Investigaciones Electricas (Mexico); De Leon-Vivar, Jesus [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)

    2008-10-15

    The gas composition of fluids produced by CP IV geothermal wells from the Cerro Prieto field was studied in order to identify different types of fluids entering the wells by estimating their temperature and excess steam. A method based on the Fischer Tropsch reaction and H2S equilibrium with pyrite-pyrrhotite as mineral buffer (FTHSH3) was used. The results for the reservoir natural state indicated the presence of fluids with heterogeneous reservoir temperature (between 275 and 310 degrees Celsius) and excess steam values, which were found from negative (boiled liquid that has lost steam when flowing to the well) to one (steam phase with zero liquid saturation). The study for individual wells in which boiling processes were identified, showed that through time, the feeding fluids consist of a two-phase mixture with different liquid/steam proportions. Also, the results suggested that a steam phase could occur at CP IV which is added to the feeding fluid, depending on the operation conditions of the wells. The origin of this steam could be the boiling of the deeper liquid due to a pressure drop. [Spanish] Se estudio la composicion gaseosa de los fluidos producidos por pozos geotermicos del sector CP IV del campo de Cerro Prieto para tratar de distinguir aportes de fluidos diferentes mediante la estimacion de su temperatura de yacimiento y del exceso de vapor. Se utilizo un metodo de equilibrio gaseoso basado en la reaccion de Fischer Tropsch y el equilibrio combinado pirita-pirrotita (FT-HSH3). Los resultados obtenidos indican que en el estado inicial del yacimiento existen fluidos que muestran heterogeneidad en los valores de temperatura de yacimiento (entre 275 y 310 grados Celsius), asi como en el exceso de vapor con valores desde negativos (liquido que despues de ebullir ha perdido vapor en su trayecto hacia el pozo) hasta uno (vapor con cero saturacion de liquido). El estudio individual de los pozos con fenomenos de ebullicion muestra que a traves del tiempo

  14. A preliminary interpretation of gas composition in the CP IV sector wells, Cerro Prieto geothermal field, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Barragan Reyes, Rosa Maria; Arellano Gomez, Victor M; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Morelos (Mexico)]. E-mail: rmb@iie.org.mx; Perez Hernandez, Alfredo; Rodriguez Rodriguez, Marco Helio; Leon Vivar, Jesus de [Comision Federal de Electricidad, Residencia General Cerro Prieto, B.C. (Mexico)

    2007-07-15

    To increase the electrical generation capacity of the Cerro Prieto geothermal field from 620 MW to 720 MW, the Cerro Prieto IV (CP IV) sector of the field was developed in the NE portion of the exploited field. Fourteen new wells have been drilled there since 2000. The wells in CP IV zone produce two-phase fluids at wellhead with heterogeneous steam fraction characteristics: at the central zone and towards the NW, the wells are liquid-dominated while those towards the E and S produce a relatively high steam fraction. This work studies the gas compositions of produced fluids to obtain reservoir parameters such as temperature and steam fraction and identify different sources of fluids in the wells. A method was used based on the Fischer Tropsch reaction and H{sub 2}S equilibria with pyrite-pyrrhotite as a mineral buffer (FT-HSH3). The results for the natural state showed the presence of fluids with reservoir temperatures from 275 to 310 degrees Celsius and excess steam values from -1 to 50%. Data are aligned in a FT-HSH3 trend, suggesting that the well discharges consist of a mixture in different proportions of the two end members. One seems to be a liquid with a temperature of over 300 degrees Celsius with negative or negligible excess steam. The other seems to be a two-phase fluid with a temperature of about 275 degrees Celsius and an excess steam fraction of about 0.5. According to the data for single wells and depending on the production conditions of the wells, reservoir fluid mixtures could occur in different proportions of liquid and steam. Data for 2005 that included wells drilled after 2000 suggest the presence of a steam phase in the reservoir. The steam could be generated with the boiling of deep reservoir fluid from a pressure drop. The mixing trend obtained for the natural state was also seen for 2005 data but lower temperatures (from 265 to 295 degrees Celsius) were obtained compared with those for natural conditions. The entry of lower

  15. Effects of pressure drawdown and recovery on the Cerro Prieto beta reservoir in the CP-III area

    Energy Technology Data Exchange (ETDEWEB)

    Truesdell, A.H. [Truesdell (Alfred H.), Menlo Park, CA (United States); Lippmann, M.J. [Lawrence Berkeley National Lab., CA (United States)

    1998-02-01

    The production characteristics of wells in the northwestern Cerro Prieto III area changed greatly when the Cp-III power plant went on line in 1986. Fluid extraction in the field more than doubled and reservoir-wide boiling started immediately, greatly increasing the enthalpy of produced fluids. Some well fluids showed a decrease in chloride due to adiabatic steam condensation in the well and separator, and others were enriched in chloride due to boiling. As reservoir drawdown increased, entrance of cooler and more dilute groundwaters into the reservoir became evident (i.e., condensation stopped, and there was a decrease in enthalpy and chloride in produced fluids). Although some groundwater inflow was from the leaky western margin of the reservoir, the majority is in the northeast, inferred to be local and downward, possibly through more permeable zones associated with the normal fault H. This natural recharge and some reinjection have slowed and possibly reversed pressure drawdown throughout CP-III. Enthalpy has decreased and liquid saturation has increased as the steam-rich zone in the upper part of the reservoir has either disappeared or become thinner.

  16. Monitoring and modeling land subsidence at the Cerro Prieto Geothermal Field, Baja California, Mexico, using SAR interferometry

    Science.gov (United States)

    Carnec, Claudie; Fabriol, Hubert

    Images derived from repeat-pass spaceborne interferometric synthetic aperture radar (InSAR) systems offer the possibility of mapping surface deformation of small spatial extent and monitoring its spatio-temporal evolution. A slow local subsidence has been detected at the Cerro Prieto geothermal field from images acquired by the European Space Agency remote sensing satellites ERS-1/2 between 1993 and 1997. Although agricultural activity in the area limited the investigation, interferometric monitoring revealed that the ground deformation is associated with the withdrawal of geothermal fluid and agreed with the leveling data. Modeling of the subsidence was carried out assuming elastic deformation in a half-space from simple point sources, of which five were necessary to reproduce the fringe patterns observed on the interferograms. The depths and locations of three of the sources are compatible with the location of the known reservoir. The study improves prior knowledge of the displacement field and of the mecanisms involved in the subsidence phenomenon.

  17. Gaseous equilibrium in sector CP IV of the Cerro Prieto, B.C. Mexico geothermal field; Equilibrio gaseoso en el sector CP IV del campo geotermico Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Barragan Reyes, Rosa Maria; Arellano Gomez, Victor Manuel; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); De Leon Vivar, Jesus [Comision Federal de Electricidad, Campo Geotermico Cerro Prieto, Cerro Prieto, B. C. (Mexico)

    2007-07-01

    Sector CP IV is located in the NE portion of the Cerrro Prieto geothermal field. The wells of this zone produce two-phase fluids, with different characteristics as far as their steam fraction content; in the central part and towards the NW the fluids are of dominant liquid type whereas towards the E and the S, the fluid contains a relatively higher steam fraction. The results of gaseous equilibrium FT- HSH3 showed that the fluids in the deposit are at temperatures between 275 Celsius degrees and 310 Celsius degrees and contain steam fractions between 0.01 and 0.5. The data found for the natural state are aligned in a tendency defined in the diagram FT- HSH3, that suggest the wells receive different proportions from preexisting steam in the deposit, which are mixed with the liquid phase to produce the observed discharges. The present data, besides showing the presence of deposit steam, also indicates the entrance of lower temperature fluid in the central part of sector CP IV. [Spanish] El sector CP IV se localiza en la porcion NE del campo geotermico Cerro Prieto. Los pozos de esta zona producen fluidos bifasicos, con diferentes caracteristicas en cuanto a su contenido de fraccion de vapor: en la parte central y hacia el NW los fluidos son de tipo liquido dominante mientras que hacia el E y hacia el S, el fluido contiene una fraccion relativamente alta de vapor. Los resultados de equilibrio gaseoso FT-HSH3 mostraron que los fluidos en el yacimiento se encuentran a temperaturas de entre 275 grados Celsius y 310 grados Celsius y contienen fracciones de vapor de entre -.01 y .5. Los datos hallados para el estado natural se alinean en una tendencia definida en el diagrama FT-HSH3, que sugiere que los pozos reciben diferentes proporciones de vapor pre-existente en el yacimiento, que se mezclan con fase liquida para producir las descargas que se observan. Los datos actuales, ademas de mostrar la presencia de vapor de yacimiento, tambien indican la entrada de fluidos de

  18. Analysis of productive evolution of well M-19A, Cerro Prieto geothermal field, BC; Analisis de la evolucion productiva del pozo M-19A del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Rodriguez, Marco H; Romero-Rios, Francisco [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2007-07-15

    Well M-19A has been the most productive in the Cerro Prieto field, producing around 40 million tons of fluid. The well went on line in February 1975 and was in continuous operation until June 2006. Monthly measurements for over 30 years of operating conditions and chemical and isotopic analyses of the fluids allow identification of the most significant processes occurring in the zone where the well is located. Three dominant recharge types have been identified, each lasting about 10 years. They are a) a recharge of fluids of lower temperature than the production fluids, even though the chemical and isotopic compositions are similar; b) a recharge of lower-temperature fluids with diluted chemical and isotopic compositions; and c) a progressive recharge of reinjected water with a higher chloride concentration and heavy isotopic composition. The production and reinjection rates for over 30 years of production history in the M-19A well zone allow for speculation of a reservoir pressure recovery, which is confirmed with a calculation using production data from well M-19A. The evolution of the reservoir pressure in the zone contrasts with the rest of the reservoir, where a constant pressure drop is observed, particularly toward the central and eastern parts of the field. [Spanish] El pozo M-19A ha sido el mas productivo del campo geotermico de Cerro Prieto, BC, alcanzando una extraccion de mas de 40 millones de toneladas de fluido. Fue integrado a produccion en febrero de 1975 y hasta junio de 2006 ha permanecido en produccion en forma continua. Las mediciones mensuales de sus condiciones operativas y los analisis quimicos e isotopicos del agua producida permiten identificar los procesos mas significativos que han ocurrido a lo largo de esos mas de 30 anos en la zona donde se localiza el pozo. Se han identificado tres tipos de recarga dominantes que se presentan durante un periodo cercano a 10 anos cada uno, los cuales son: a) una recarga de fluidos de menor temperatura

  19. Analysis of two catalogues of seismicity at the Cerro Prieto geothermal area (Baja California) from 1988 to 1995, relationship with reinjection; Analisis de dos catalogos de sismicidad en el area geotermica de Cerro Prieto (Baja California) de 1988 a 1995, relacion con la reinyeccion

    Energy Technology Data Exchange (ETDEWEB)

    Fabriol, Hubert [Centro de Investigacion y de Ensenanza Superior de Ensenada (CICESE), Ensenada (Mexico)

    1996-09-01

    In order to study the effects of fluid reinjection in the Cerro Prieto geothermal field, started in 1989, seismicity recorded in this area and included in the USGS-Caltech (California Technology) (US) and the Red Sismologica del Noreste de Mexico (RESNOM) of the Centro de Investigacion Cientifica y de Ensenanza Superior (CICESE, Mexico) catalogues is reviewed since 1988. The precision of determination of epicenters is compared with the location of moderate events recorded by a local array, setup around Cerro Prieto since August 1994. We note a bias in both catalogues, as events located by USGS-Caltech are shifted between 5 to 10 km towards south and events of RESNOM are shifted between 4 to 8 km towards northeast. That limits the use of these catalogues for precise studies of reinjection effects in the geothermal field. Seismic activity is low until 1991 and increases afterwards, particularly in 1993 and 1995. Comparison of USGS-Caltech catalogue with changes in reinjection flow rates show at beginning of 1995 only one example of short-range effect between reinjection and seismicity (but using the epicenter determination of the local network) and possibly several medium-range effects (between 6 and 8 months). In that case, the flow rate increase corresponding to the beginning of winter, could be followed by one or more events of magnitude ranging from Ml=3 to Ml=4 during midsummer. Taking into account the tectonic context of the area, it is also possible that those event could be associated either to Cerro Prieto fault or to the spreading center source of the thermal anomaly. The continuous monitoring with a local network will allow to precise those preliminary results, obtained with regional networks. [Espanol] Como parte del estudio sobre los efectos de la reinyeccion de fluido en el campo geotermico de Cerro Prieto, iniciado en 1989, se analiza de manera critica la sismicidad registrada en el area y reportada en los catalogos de USGS-Caltech (Tecnologico de

  20. Recent Vertical Deformation in Mexicali Valley and its Relationship with Tectonics, Seismicity, and the Exploitation of the Cerro Prieto Geothermal Field, Mexico

    Science.gov (United States)

    Glowacka, E.; González, J.; Fabriol, H.

    The interpretation of the results of regional and local leveling which began in 1977 in the Mexicali Valley and the local short profile precision leveling which started in 1994 are discussed. The relation of vertical deformations around the Cerro Prieto Geothermal Field (CPGF) and along the Imperial fault, with local tectonics and seismicity in the Mexicali Valley, is reviewed. Also the relation between vertical deformation and fluid operation in the CPGF is analyzed. The subsidence observed in the field seems to be induced by fluid extraction. The way in which fluid production influences surface changes along the Imperial fault is not clear. The possibility that seismicity is triggering subsidence in the area and vertical movement on the Imperial fault is discussed.

  1. Operation and Performance of a Biphase Turbine Power Plant at the Cerro Prieto Geothermal Field (Final Report)

    Energy Technology Data Exchange (ETDEWEB)

    Hays, Lance G. [Douglas Energy Company, Placentia, CA (United States)

    2000-09-01

    A full scale, wellhead Biphase turbine was manufactured and installed with the balance of plant at Well 103 of the Cerro Prieto geothermal resource in Baja, California. The Biphase turbine was first synchronized with the electrical grid of Comision Federal de Electricidad on August 20, 1997. The Biphase power plant was operated from that time until May 23, 2000, a period of 2 years and 9 months. A total of 77,549 kWh were delivered to the grid. The power plant was subsequently placed in a standby condition pending replacement of the rotor with a newly designed, higher power rotor and replacement of the bearings and seals. The maximum measured power output of the Biphase turbine, 808 kWe at 640 psig wellhead pressure, agreed closely with the predicted output, 840 kWe. When combined with the backpressure steam turbine the total output power from that flow would be increased by 40% above the power derived only from the flow by the present flash steam plant. The design relations used to predict performance and design the turbine were verified by these tests. The performance and durability of the Biphase turbine support the conclusion of the Economics and Application Report previously published, (Appendix A). The newly designed rotor (the Dual Pressure Rotor) was analyzed for the above power condition. The Dual Pressure Rotor would increase the power output to 2064 kWe by incorporating two pressure letdown stages in the Biphase rotor, eliminating the requirement for a backpressure steam turbine. The power plant availability was low due to deposition of solids from the well on the Biphase rotor and balance of plant problems. A great deal of plant down time resulted from the requirement to develop methods to handle the solids and from testing the apparatus in the Biphase turbine. Finally an online, washing method using the high pressure two-phase flow was developed which completely eliminated the solids problem. The availability of the Biphase turbine itself was 100

  2. Analysis of the automation and control of the well production conditions in the Cerro Prieto geothermal field, Mexico; Analisis de la automatizacion y del control de las condiciones de produccion de los pozos del campo geotermico de Cerro Prieto, BC, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Murillo Zamora, Isaac [Comision Federal de Electricidad, Mexicali, BC, (Mexico); Ocampo Diaz, Juan de Dios [Universidad Autonoma de Baja California, Mexicali, BC, (Mexico); De la Pena Reyna, Gilberto [Comision Federal de Electricidad, Morelia, Michoacan (Mexico)

    2005-12-01

    Through 31 years of development of the Cerro Prieto geothermal field, the number of wells in operation and the distances between them has been increasing. Now there are 150 wells producing a mixture of water and steam at different ratios, depending on the reservoir characteristics (pressure, temperature, depth, etc.) and the operation conditions in the superficial installations (obstructions in the orifice plates diameter, separator pressures, etc.). Therefore, Comision Federal de Electricidad (CFE) has started a pilot plan to handle the automation and control of the operating conditions of production wells, and to install a data production acquisition system. The initial results of the system are in this paper. [Spanish] A traves de los 31 anos de desarrollo del campo geotermico de Cerro Prieto el numero de pozos en operacion asi como la distancia entre ellos se ha estado incrementando. Ahora hay mas de 150 pozos produciendo una cantidad de mezcla de agua y vapor a diferentes rangos, dependiendo de las caracteristicas del yacimiento (presion, temperatura, profundidad, etc.) y de las condiciones de operacion de las instalaciones superficiales (diametros de placas de orificio obstruidos, presion de los separadores, etc.). Como resultado la Comision Federal de Electricidad (CFE) ha dado inicio a un plan de pruebas para llevar a cabo la automatizacion y control de las condiciones de operacion de los pozos productores, e instalar un sistema con equipos para recoleccion de datos del campo, cuyos primeros resultados se presentan en este articulo.

  3. Implications for organic maturation studies of evidence of a geologically rapid increase and stabilization of vitrinite reflectance at peak temperature: Cerro Prieto geothermal system, Mexico

    Science.gov (United States)

    Barker, C.E.

    1991-01-01

    A short-term rapid heating and cooling of the rock in well M-94 below 1300 m was caused by a pulse of hot water passing through the edge of the Cerro Prieto, Mexico, geothermal system. Below 1300 m, the peak paleotemperatures were about 225-250??C, but equilibrium well log temperatures indicate a decrease to 150-210??C at present. This hot water pulse sharply increased vitrinite reflectance to levels comparable to those measured in the central part of the system, even though studies of apatite fission-track annealing indicate that the duration of heating was only 100-101 yr in M-94, in contrast to 103-104 yr in the central part of the system. The quick change of the vitrinite reflectance geothermometer indicates that thermal maturation reactions can stabilize, after a geologically short period of heating, to a level consistent with peak temperature under moderate to high-temperature diagenesis in open, fluid-rich, geothermal systems. -from Author

  4. Comparative study of the amplification of ground motion using seismic noise and recent earthquakes adjacent to the Cerro Prieto volcano, Baja California

    Science.gov (United States)

    Vega, F. D.; Vidal-Villegas, A.

    2009-12-01

    We have chosen an area of approximately 79 km2, centered around the Cerro Prieto volcano, in the Mexicalli valley, Baja California, based on elevated registered acceleration data. The GEO station, located in the Cerro Prieto geothermal field has registered seismic accelerations on the order of 492 gales. The local residents near the study area have reported feeling numerous smaller magnitude earthquakes, compared to those of the nearby populated city of Mexicalli. Does there exist an amplified seismic signal in the area? If so, what is the cause of the amplification? The objective of our study is to answer these questions and determine the subsurface (0-50 m) structure in 4 specific sites. To obtain these answers, we registered seismic noise samples using short period seismometers (1 s), intermediate (5 s) and 16 bit recorders, along a linear profile which crosses the volcano with an 18 degree NE orientation. Furthermore, we analyzed ground-motion data (from 2004-2006), obtained from 24-bit accelerographs. Using both types of data (noise and accelegraphs) we calculated the H/V spectral ratios, and the relative ratios between both sites. To determine the subsurface structure, we used a unidimensional model of the H/V ratios, based on the methodology used by Huerta-Lopez et al., 2005. The H/V spectral ratios from the seismic noise adjacent to the volcano display amplitude of 1 in the frequency range (0.8 - 30 Hz). In contrast, the amplitude in the volcano crater (159 m.a.s.l.) was 6 in the frequency range (0.8 - 3 Hz). The average H/V relative ratio of the crater and the adjacent sites is 4, with frequencies between 0.8 and 1.2 Hz. The S-wave H/V ratios for the VCP acceleration station (110 m.a.s.l.), are near 8, with frequencies between 1 and 2. The H/V spectral ratios from the seismic noise for the geothermal field display amplitude of 4 for frequencies between 0.8 and 1.3 Hz, while the results from the S wave display amplitudes of 5 between 1.5 and 3 Hz. In the

  5. Heat losses estimation associated with the physical state of the thermal insulation of pipes vaporductos network in Cerro Prieto geothermal field; Estimacion de perdidas de calor asociadas al estado fisico del aislamiento termico de las tuberias de la red de vaporductos del campo geotermico Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Ovando Castelar, Rosember; Martinez Estrella, Juan Ignacio; Garcia Gutierrez, Alfonso [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; jime@iie.org.mx; aggarcia@iie.org.mx; Canchola Felix, Ismael; Miranda Herrera, Carlos; Jacobo Galvan, Paul [Campo Geotermico de Cerro Prieto, Comision Federal de Electricidad, Mexicali, B.C. (Mexico)

    2010-11-15

    The Cerro Prieto Geothermal Field (CPGF) steam transportation network is constituted by 140 km of pipes with diameters ranging from 8 to 48 inches, which transport the steam of 165 producing wells to 13 power plants which have a total installed capacity of 720 MWe. Originally, the pipes are thermally insulated with a mineral wool or fiber glass layer and an external aluminum or iron cover. Due to the insulation material has been exposed to weather conditions during the field operation it shows nowadays different grades of wear-out, or even it is lacking in some parts of the network, causing higher heat losses from the pipes to the environment. In this work, the magnitude of the heat losses related with the present condition of the thermal insulation throughout the pipeline network is assessed. This involved determining the longitude and diameter, as well as the insulation condition of each single pipeline section, and the calculation of the heat transfer coefficients for the different thermal insulation conditions defined for this study. [Spanish] La red de transporte de vapor del campo geotermico Cerro Prieto (CGCP) esta constituida por aproximadamente 140 km de tuberias de 8 a 48 pulgadas de diametro, las cuales conducen el vapor producido por 165 pozos hacia 13 plantas generadoras, cuya capacidad instalada es de 720 MWe. Originalmente, estas tuberias son aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion exterior de aluminio o hierro. Debido principalmente al impacto de las condiciones meteorologicas durante el tiempo de operacion del campo, en algunas porciones de la red el aislante presenta actualmente distintos grados de deterioro, o incluso se encuentra ausente, lo cual se traduce en una mayor perdida de calor desde las tuberias hacia el medio ambiente. En el presente trabajo se evalua la magnitud de las perdidas de calor asociadas al estado fisico del aislamiento termico de las

  6. The geochemistry and isotope hydrology of the Southern Mexicali Valley in the area of the Cerro Prieto, Baja California (Mexico) geothermal field

    Science.gov (United States)

    Portugal, Enrique; Izquierdo, Georgina; Truesdell, Alfred; Álvarez, Julio

    2005-11-01

    Groundwaters from the phreatic aquifer within and surrounding of the Cerro Prieto geothermal field were analyzed geochemically and isotopically in order to establish a hydrodynamic model of the study zone, which is located in the Mexicali Valley between 655,000-685,000 m E-W and 3,605,000-3,576,000 m N-S relative to UTM coordinates. Based on their chemical composition three types of water were recognized: chloride, sulfate and bicarbonate. However four groups of water were identified on a statistical multi-variable method of cluster analysis (A-D). The average temperature is 25 °C; with a few exceptions in the south where temperature can be as high as 47 °C. Stable isotope ratios for some waters plot close to the world meteoric line, corresponding to the original unaltered waters of the zone. The hydrogeochemistry varies in relation to three principal processes: evaporation, infiltration of water used in agriculture and rock interaction by reaction with evaporitic deposits. Major quartz, calcite and plagioclase and minor smectite, kaolinite, halite, sylvite and gypsum were identified by X-ray diffraction in lacustrine sediments of the central part of the zone. Chemical modeling indicates saturation with respect to calcite and undersaturation with respect to gypsum. By incorporating chemical and isotope data into geological and isopotential well information, a hydrodynamic model has been postulated. In this hydrodynamic model the water (A) enters the study zone from the east and it is originally of the old Colorado River water. The water samples on which the model is based were draw from agricultural wells that intersected two aquifers, a shallow and a deep one, representing the recharge to the zone. The salinity of the deep aquifer water (B) is lower than that of the shallow aquifer water (C) and so is the stable isotope ratio. The difference is though to be due to dissolution of evaporates, evaporation and possible infiltration of spent agriculture water. Both

  7. Determination of heat losses in the Cerro Prieto, Baja California, geothermal field steam transportation network based on the thermal insulation condition of the steam pipelines; Determinacion de perdidas de calor en la red de transporte de vapor del campo geotermico de Cerro Prieto, Baja California, con base en el estado fisico del aislamiento termico de vaporductos

    Energy Technology Data Exchange (ETDEWEB)

    Ovando Castelar, Rosember; Garcia Gutierrez, Alfonso; Martinez Estrella, Juan Ignacio [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; Canchola Felix, Ismael; Jacobo Galvan, Paul; Miranda Herrera, Carlos; Mora Perez, Othon [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)

    2011-07-15

    In Cerro Prieto Geothermal Field (CPGF), the steam from producing wells is transported to power plants through a large and complex system of pipes thermally insulated with a 2 inches thick mineral wool or a fiber glass layer and an external aluminum or iron cover. The insulation material has been exposed to weather conditions during the field operation and has suffered density and thickness changes. In some cases the insulation has been lost completely, increasing heat transfer from the pipes to the environment. This paper analyzes the impact of the conditions of thermal insulation on heat losses in the CPGF steam-pipeline network. The heat losses are calculated by applying an iterative method to determine the surface temperature based on a heat balance calculated from the three basic mechanisms of heat transfer: conduction, convection, and radiation. Finally, using length and diameter data corresponding to the condition of the thermal insulation of each pipeline-and field operation data, the overall heat losses are quantified for steam lines throughout the pipeline network in the field. The results allow us to evaluate the magnitude of the heat losses in comparison with the overall energy losses occurring during steam transport from wells to the power plants. [Spanish] En el Campo Geotermico de Cerro Prieto (CGCP), BC, el transporte de vapor desde los pozos hasta las plantas generadoras de electricidad se lleva a cabo mediante un extenso y complejo sistema de tuberias que tipicamente se encuentran aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion mecanica de aluminio o hierro galvanizado. Debido a la exposicion a las condiciones meteorologicas a traves del tiempo de operacion del campo, el aislamiento ha experimentado cambios en su densidad y espesor y en ocasiones se ha perdido por completo, lo cual repercute en una mayor transferencia de calor de las tuberias hacia el medio ambiente

  8. Spatio-temporal evolution of anthropogenic deformation around Cerro Prieto geothermal field in the Mexicali Valley, B.C., Mexico, between 1993 and 2009 from DInSAR and leveling.

    Science.gov (United States)

    Sarychikhina, Olga; Glowacka, Ewa; Robles, Braulio; Mojarro, Jose

    2014-05-01

    Land subsidence is an environmental hazard which could be caused by withdrawal of large amounts of fluid from beneath the earth's surface. Land subsidence is an issue in several geothermal fields worldwide (e.g., Geysers, USA (Mossop and Segall, 1997), Wairakei-Tauhara, New Zealand (Allis et al., 2009)). Cerro Prieto geothermal field (CPGF), located in the Mexicali Valley, northwest Mexico, is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field (e.g. Glowacka et al., 1996, 1999; Carnec and Fabriol, 1999; Sarychikhina et al., 2011). The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to the local infrastructure such as roads, irrigation canals and other facilities. Detection of land subsidence and monitoring of the spatial and temporal changes of its pattern and magnitude can provide important information about the dynamics of this process and controlling geological structures. The technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) has been demonstrated to be a very effective technique for measuring ground deformation. This study presents an application of DInSAR interferogram stacking technique to investigate the land subsidence in the Mexicali Valley near CPGF. C-band ENVISAR ASAR images acquired between 2003 and 2009 from the ascending (track 306, frame 639) and descending track (track 84, frame 2961), obtained from the European Space Agency (ESA), as part of ESA CAT-1 project (ID - C1P3508), were used. Gamma ISP and DIFF/GEO software packages were used to calculate differential interferograms from SLC data and for differential interferograms stacking (Wegmüller and Werner, 1997). Eight average annual deformation rate maps were generated for 2005 (descending

  9. Cerro Prieto geothermal field: exploration during exploitation

    Energy Technology Data Exchange (ETDEWEB)

    1982-07-01

    Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. The description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field are presented. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development.

  10. Geothermal well drilling manual at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez P., A.; Flores S., M.

    1982-08-10

    The objective of the drilling manual is to solve all problems directly related to drilling during the construction of a well. In this case, the topics dealt which are drilling fluids and hydraulics to be applied in the field to improve drilling progress, eliminate risks and achieve good well-completion. There are other topics that are applicable such as drill bits and the drilling string, which are closely linked to drilling progress. On this occasion drilling fluid and hydraulics programs are presented, in addition to a computing program for a Casio FX-502P calculator to be applied in the field to optimize hydraulics and in the analysis of hydraulics for development and exploration wells at their different intervals.

  11. Miguel Prieto Anguita

    OpenAIRE

    Cabañas Bravo, Miguel

    2013-01-01

    Miguel Cabañas Bravo: "Miguel Prieto Anguita". En: Gonzalo Anes (dir.): Diccionario Biográfico Español, tomo XLII; Madrid, Real Academia de la Historia, 2013, pp. 260-263 (ISBN: 978-84-96849-56-3 O.C., 978-84-15069-04-1 vol. XLII)

  12. Magnetotelluric studies at the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Goubau, W.M. (Lawrence Berkeley Lab., CA); Goldstein, N.E.; Clarke, J.

    1981-01-01

    During three years of magnetotelluric surveying, data were acquired at 26 sites distributed over 190 km/sup 2/ around the production area. A relatively well-defined strike of N27W +- 1.5/sup 0/ (magnetic) was established. The simple model shown suggests a lateral discontinuity in the vicinity of Nueva Leon.

  13. Drilling rate for the Cerro Prieto stratigraphic sequence

    Energy Technology Data Exchange (ETDEWEB)

    Prian C, R.

    1981-01-01

    Drilling practice at the field has been modified in several ways as better information is being obtained. The stratigraphic sequence of the area is made up of three sedimentary rock units of deltaic origin having different densities. These units have been named non-consolidated, semi-consolidated, and consolidated rocks; the thermal reservoirs are located in the latter. To investigate how the drilling rates are affected by the three rock units, plots of drilling advance versus time were made for a large number of wells. A typical plot is shown and drilling rates are practically constant in three different zones; that is, the drilling rate has only two breaks or changes in slope.

  14. Indalecio Prieto, en Hacienda

    Directory of Open Access Journals (Sweden)

    Juan VELARDE FUERTES

    2010-02-01

    Full Text Available Entre las sorpresas que se tienen al estudiar el tema, se encuentra la escasa bibliografía existe sobre el mismo. Unas veces porque el material es deleznable desde un punto de vista científico. Otras, porque se decide ignorarlo, tal como sucede, por ejemplo, en el trabajo histórico de Juan Sendí sobre el Banco de España. Está disponible el material básico: los discursos parlamentarios; las colecciones de periódicos; los libros de memorias de los protagonistas de aquel momento, encabezados por el muy bien escrito Diario de Azaña; trabajos y libros del propio Prieto, tanto en Hacienda como en Obras Públicas.

  15. Geophysical characterization of subaerial hydrothermal manifestations in Punta Banda, Baja California, Mexico.

    Science.gov (United States)

    Flores-Marquez, L.; Prol-Ledesma, R. M.; Arango, C.; Canet, C.

    2009-04-01

    Important growth of population in Baja California Peninsula has triggered the need for energy and fresh water. The most sustainable possibility for increasing the availability of fresh water is the use of renewable energy sources in desalination plants. The abundance of geothermal manifestations in the peninsula provides a reliable energy source for desalination purposes. Geothermal development of the Baja California Peninsula dates from the 70's, when the Cerro Prieto geothermal field started producing electricity. Two important cities, Tijuana and Ensenada, are located in the north-western area of Baja California. The city of Ensenada has a desalination plant that is due to be replaced and the geothermal resources of the area could be an option for the new desalination plant. Punta Banda, a region near Ensenada, was specially investigated to determine its geothermal potential. Subaerial springs and the submarine vents were sampled and studied in this work, also geological and geochemical studies were performed, moreover geoelectrical surveys were accomplished to characterize the hydrothermal system at depth. Even though saline intrusion is a severe problem in Ensenada (TDS higher than 3000), thermal springs away from the coast and coastal springs have salinities lower than sea water. According to the geoelectrical models obtained from profiles, the inferred conductive features can be related to thermal anomalies. The existence of hot springs located along a trend suggests that the dynamic of the thermal fluid is restricted by secondary faults.

  16. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico

    Science.gov (United States)

    Des Marais, D. J.; Stallard, M. L.; Nehring, N. L.; Truesdell, A. H.

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

  17. Two-dimensional inversion of resistivity monitoring data from the Cerro Prieto geothermal field

    Science.gov (United States)

    Goldstein, N. E.; Sasaki, Y.; Wilt, M. J.

    1985-03-01

    Two dimensional iterative, least-squares inversions were performed on dc resistivity data obtained over the geothermal field at five successive times during the 1979-1983 period. The solutions gave the percent change in resistivity within each of 47 rectangular blocks representing the reservoir and recharge regions. The changes are consistent with hydrogeologic and recharge models, on the basis of geophysical well logs, well cuttings, well production, geochemical and reservoir engineering data. The solutions support the model of a reservoir that is recharged mainly by cooler, less saline water, causing changes in both pore fluid resistivity and the extent of boiling near the wells. There may be a component of high-temperature recharge from below and to the east, but flow may be impeded by a two-phase zone. Notwithstanding the various sources of error and uncertainty in the data acquisition and 2-D inversions, repetitive, high precision dc resistivity monitoring seems to be a useful method for assessing reservoir conditions when used in conjunction with production and reservoir engineering data and analysis.

  18. Analysis of exploratory wells in the Cerro Prieto Field and the Mexicali Valley

    Energy Technology Data Exchange (ETDEWEB)

    Cobo R., J.M.; Bermejo M., F.J.

    1982-08-10

    Agricultural development in the Mexicali Valley and in the high cost of electric power required to operate the irrigation wells in the Valley prompted the Mexican government to investigate the possibility of taking advantage of thermal manifestations in the area located 28 km southeast of the city of Mexicali to generate electric power and thereby partially decrease the flight of foreign exchange. In 1958, a geologic study of the southern and southeastern zone of Mexicali was conducted to identify the possibilities of tapping geothermal resources. The purpose of this study was to gain knowledge of the geologic conditions in this area and, if possible, to establish the location of exploratory and production wells and, on the basis of the results of the former, examine the geologic history in order to gain knowledge and understanding of the structural control of the steam. On the basis of this study, it was recommended that 3 exploratory wells should be drilled in order to locate weak zones that would easily allow for steam flow.

  19. Proceedings: third symposium on the Cerro Prieto geothermal field, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    These proceedings include both English and Spanish versions of each paper presented at the symposium. Illustrations and tables, which have been placed between the two versions, include captions in both languages. Forty-one papers are included. Five papers were indexed for EDB previously. Separate abstracts were prepared for thirty-three papers and three were listed by title.

  20. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico.

    Science.gov (United States)

    Des Marais, D J; Stallard, M L; Nehring, N L; Truesdell, A H

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

  1. Cerro Prieto Geothermal Field, Proceedings of the Symposium, 1st, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Barbier, E. (ed.)

    1979-01-01

    This conference is published in two volumes and contains 35 papers, 31 of which are abstracted separately. The subject matter is primarily concerned with the understanding of geology, hydrogeology, geophysics, reservoir engineering, geochemistry and electric power generation associated with the procurement of geothermal energy.

  2. Prieto receives 2010 Keiiti Aki Young Scientist Award

    Science.gov (United States)

    Berozar, Gregory C.; Prieto, Germán A.

    2011-06-01

    Germán Prieto received the 2010 Keiiti Aki Young Scientist Award at the 2010 AGU Fall Meeting, held 13-17 December in San Francisco, Calif. The award recognizes the scientific accomplishments of a young scientist who makes outstanding contributions to the advancement of seismology.

  3. Occurrences of alunite, prophyllite, and clays in the Cerro La Tiza area, Puerto Rico

    Science.gov (United States)

    Hildebrand, Fred Adelbert; Smith, Raymond J.

    1959-01-01

    A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7? kilometers long, has an average width of about 1? kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These

  4. Effect of Measured Wellhead Parameters and Well Scaling on the Computed Downhole Conditions in Cerro Prieto Wells

    Energy Technology Data Exchange (ETDEWEB)

    Goyal, K.P.; Miller, C.W.; Lippmann, M.J.

    1980-12-16

    This paper is devoted to the discussion of the wellbore model and its describing equations, comparison between the computed and measured pressures and the effect of measured wellhead parameters on the downhole pressures in the well. Finally a wellbore model with multiple inside diameters is discussed and the effect of well scaling on the bottom hole pressures is studied.

  5. Cerro de Pasco and other massive sulfide deposits of central Peru

    Energy Technology Data Exchange (ETDEWEB)

    Cheney, E.S.

    1985-01-01

    The famous Cerro de Pasco Pb-Zn-Ag deposit historically has been considered to be hydrothermally derived from an adjacent Tertiary volcanic vent. However, texturally massive pyrite-chert and pyrite-sphalerite-galena in the deposit have the same strike and cross folds as the adjacent pre-Tertiary strata. Both the deposit and the strata are cut by one of the large Longitudinal Faults. Both dikes and pyrite-enargite veins associated with the vent cut the massive sulfides; fragments of massive pyrite occur in the vent. A few examples of laminated pyrite and chert, banded pyrite and chert, banded pyrite and sphalerite, and banded pyrite, sphalerite, and galena are preserved in the massive sulfide portion of the deposit. The deposit has the composition and zoning patterns typical of shale-hosted massive sulfides. Cerro de Pasco probably in part of the pelitic Devonian Excelsior formation. The Colquijirca deposit 8 km to the south and the San Cristobal district 110 km to the south likewise have been considered to be Tertiary volcanic hydrothermal deposits. Colquijirca consists of stratigraphically controlled mantos of layered pyrite, chert and tuff in the Tertiary Calera formation. The mantos of the San Cristobal district are along the upper contact of the pyritic, Permian, Catalina felsic volcanic rocks; some ore consists of laminated pyrite and sphalerite. Tertiary plutons are conspicuously absent at San Cristobal, and the ores are brecciated by Tertiary folding.

  6. THE PEDAGOGICAL IDEAS OF LUIS BELTRÁN PRIETO FIGUEROA

    Directory of Open Access Journals (Sweden)

    Elsa Fuenmayor

    2009-07-01

    Full Text Available The present work is a synthesis, where describe to the Pedagogical Ideas of Luis Beltrán Prieto Figueroa. The investigation is based on texts of its works: Principios generales de la educación, El Estado y la Educación en América Latina; in the theoretical arguments of Corrientes del Pensamiento Pedagógico of the Upel (1989, among others. In conclusion, the Teacher, knew to understand that the materialization of a society and a democratic government had necessarily to happen through the creation of an educative system without exclusions, able to offer equality of opportunities to all the citizens

  7. Refined localization of the Prieto-syndrome locus

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, F.; Prieto, F. [Unidad de Genetica, Valencia (Spain); Gal, A. [Universitaets-Krankenhaus Eppendorf, Hamburg (Germany)

    1996-07-12

    PRS designates the locus for a syndromal form of X-linked mental retardation (Prieto syndrome) characterized by minor facial anomalies, ear malformation, abnormal growth of teeth, clinodactyly, sacral dimple, patellar luxation, malformation of lower limbs, abnormalities of the fundus of the eye, and subcortical cerebral atrophy. Linkage analysis localized the disease locus between DXS84 (Xp21.1) and DXS255. Here we present additional linkage data that provide further support and refinement of this localization. Individual III-18 gave birth to a male, currently aged 2 7/12 years, who clearly shows delayed psychomotor development. He began to walk at 23 months and his speech is delayed. In addition, he shows the characteristic facial anomalies, {open_quotes}dysplastic{close_quotes} ears, sacral dimple, and clinodactyly, as do all other affected males in this family. 7 refs., 1 tab.

  8. Structure and age of the Cerro de Pasco Cu-Zn-Pb-Ag deposit, Peru

    Science.gov (United States)

    Cheney, E. S.

    1991-04-01

    The world-famous Cu-Zn-Pb-Ag deposit at Cerro de Pasco, Peru, consists of texturally massive pyrite, texturally massive sphalerite-galena-pyrite, and veins containing pyrite and enargite. Historically the deposit has been considered to be the hydrothermal product of the adjacent Miocene volcanic and intrusive complex (locally known as the “Vent”). However, both the texturally massive sulfides of the deposit and the pre-Miocene strata are cut by the Longitudinal fault, one of the largest faults in the district, but the Vent is not. Imbrication by the Longitudinal fault zone (duplex structures) has thickened the deposit so that it is amenable to open-pit mining. Dikes and pyrite-enargite veins pass from the Vent into the massive sulfides; fragments of massive pyrite occur in the Vent. Thus, no matter what their origin, the texturally massive sulfides are older and, therefore, genetically unrelated to the Vent.

  9. Hydrothermal minerals

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.

    in the Indian Ocean. In both fields, hydrothermalism has ceased between 11.000 and 13.000 years ago. The first occurrence (Sonne Field, 2850 m water depth) is located in the 4th segment of the Central Indian Ridge, north of the Rodriguez Triple Junction... structures are composed of sulfides arising out from deep beneath the Earth' crust. These minerals have been dissolved in hot water (350ºC) under great pressures and temperatures. When the water that flows out through the mantle ejects at the mid ocean...

  10. Transport of Cerro Hudson SO2 clouds

    Science.gov (United States)

    Doiron, Scott D.; Bluth, Gregg J. S.; Schnetzler, Charles C.; Krueger, Arlin J.; Walter, Louis S.

    The Cerro Hudson volcano in southern Chile (45.92°S, 73.0°W) emitted large ash and sulfur dioxide clouds on August 12-15, following several days of minor activity [Global Volcanism Network Bulletin, 1991]. The SO2 clouds were observed using (preliminary) near real-time data from the Total Ozone Mapping Spectrometer (TOMS) as they encircled the south polar region. The injection of SO2 into the stratosphere has essentially created a gigantic chemical tracer that could provide new insights into the wind patterns and seasonal circulation around the Antarctic region.around the Antarctic region. The TOMS instrument, on board the National Aeronautic and Space Administration's Nimbus 7 satellite, measures the ratio of backscattered Earth radiance to incoming solar irradiance in the ultraviolet spectrum. Although originally designed to measure ozone, it was later discovered that the TOMS instrument could also detect and quantify SO2 [Krueger, 1985]. After this discovery, measurements from TOMS were examined for SO2 emissions for all recorded volcanic eruptions since Nimbus-7 was launched in October 1978, and current data are analyzed as new eruptions occur. The satellite is in a polar, Sun-synchronous orbit so that it crosses the equator at local noon and observes the whole sunlit Earth in approximately 14 orbits each day. Total column amounts of SO2 are determined that represent the amount of gas affecting the reflection of ultraviolet light through a column of the atmosphere from the satellite to the reflecting surface, Earth, given in terms of milli atmospheres centimeter (1000 milli atm cm = a gas layer 1-cm thick at STP). The mass of SO2 is calculated by integrating over the cloud area to obtain a volume, then converting to tons.

  11. Calc-silicate mineralization in active geothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Bird, D.K.; Schiffman, P.; Elders, W.A.; Williams, A.E.; McDowell, S.D.

    1983-01-01

    The detailed study of calc-silicate mineral zones and coexisting phase relations in the Cerro Prieto geothermal system were used as examples for thermodynamic evaluation of phase relations among minerals of variable composition and to calculate the chemical characteristics of hydrothermal solutions compatible with the observed calc-silicate assemblages. In general there is a close correlation between calculated and observed fluid compositions. Calculated fugacities of O{sub 2} at about 320{degrees}C in the Cerro Prieto geothermal system are about five orders of magnitude less than that at the nearby Salton Sea geothermal system. This observation is consistent with the occurrence of Fe{sup 3+} rich epidotes in the latter system and the presence of prehnite at Cerro Prieto.

  12. Del valle al cerro: el sitio del Cerro Zapotecas durante el Epiclásico

    OpenAIRE

    Salomón Salazar, María Teresa

    2008-01-01

    El objetivo de esta tesis es definir qué tipo de asentamiento era el Cerro Zapotecas durante el periodo Epiclásico (600-900 d.C.), ubicado a escasos tres kilómetros de Cholula. Los antecedentes de investigación en este sitio lo señalan como un centro focal de las actividades del valle de Puebla-Tlaxcala durante la transición del Clásico al Posclásico. Esta investigación llevó a cabo un nuevo recorrido de superficie con el cual se documentó la composición arquitectónica y ...

  13. Hydrothermal Biogeochemistry

    Science.gov (United States)

    Shock, E.; Havig, J.; Windman, T.; Meyer-Dombard, D.; Michaud, A.; Hartnett, H.

    2006-12-01

    Life in hot spring ecosystems is confronted with diverse challenges, and the responses to those challenges have dynamic biogeochemical consequences over narrow spatial and temporal scales. Within meters along hot spring outflow channels at Yellowstone, temperatures drop from boiling, and the near-boiling conditions of hot chemolithotrophic communities, to those that permit photosynthesis and on down to conditions where nematodes and insects graze on the edges of photosynthetic mats. Many major and trace element concentrations change only mildly in the water that flows through the entire ecosystem, while concentrations of other dissolved constituents (oxygen, sulfide, ammonia, total organic carbon) increase or decrease dramatically. Concentrations of metals and micronutrients range from toxic to inadequate for enzyme synthesis depending on the choice of hot spring. Precipitation of minerals may provide continuous growth of microbial niches, while dissolution and turbulent flow sweeps them away. Consequently, microbial communities change at the meter scale, and even more abruptly at the photosynthetic fringe. Isotopic compositions of carbon and nitrogen in microbial biomass reflect dramatic and continuous changes in metabolic strategies throughout the system. Chemical energy sources that support chemolithotrophic communities can persist at abundant or useless levels, or change dramatically owing to microbial activity. The rate of temporal change depends on the selection of hot spring systems for study. Some have changed little since our studies began in 1999. Others have shifted by two or more units in pH over several years, with corresponding changes in other chemical constituents. Some go through daily or seasonal desiccation cycles, and still others exhibit pulses of changing temperature (up to 40°C) within minutes. Taken together, hydrothermal ecosystems provide highly manageable opportunities for testing how biogeochemical processes respond to the scale of

  14. Early mineralization at Cerro de Pasco (central Peru) revisited

    OpenAIRE

    Rottier, Bertrand; Casanova, Vincent; Fontboté, Lluis; Kouzmanov, Kalin; Alvarez, Hugo; Bendezú, Ronner

    2013-01-01

    The large Cerro de Pasco Cordilleran base metal deposit in central Peru is located on the eastern margin of a Middle Miocene diatreme-dome complex. A striking characteristic is the presence of a N-S trending massive funnel-shape pyrite-quartz replacement ore body that contains pyrrhotite pipes grading outwards to lead-zinc replacement bodies, along the eastern contact of the diatreme-dome complex. Earlier workers interpreted the pyrrhotite pipes as postdating the pyritequartz body. This study...

  15. Estratigrafia e estrutura do Cerro do Jarau: nova proposta

    Directory of Open Access Journals (Sweden)

    Joana Paula Sánchez

    Full Text Available A estrutura do Cerro do Jarau está localizada no Estado do Rio Grande do Sul, nas proximidades de Quarai, divisa com o Uruguai. É uma estrutura circular de aproximadamente 8 km de diâmetro, cujos dados geológicos apontam para uma origem por impacto meteorítico. Está situada na Bacia do Paraná e compreende uma área de afloramento de arenitos na porção central, circundada por basaltos da Formação Serra Geral. Nos trabalhos publicados, o arenito da porção central é interpretado como pertencente à Formação Botucatu, soerguido em meio aos basaltos da Formação Serra Geral, correspondendo, para muitos autores, a uma feição dômica. O objetivo do presente trabalho é apresentar novos dados sobre a estratigrafia e estrutura do Cerro do Jarau, que mostram que os arenitos estão estrutural e estratigraficamente sobrepostos aos basaltos e ambas unidades exibem mergulhos centrípetos. A estrutura do Cerro do Jarau é, portanto, uma bacia com a porção central rebaixada, e não um domo como antes admitido.

  16. Panama Canal Zone. Cerro Tigre, Fort Gulick, Gamboa Met Van No. 1.

    Science.gov (United States)

    The report contains the following meteorological data collected at sites within Fort Gulick and Cerro Tigre , Panama during December 1970: Atmospheric precipitation; Atmospheric temperature; Wind; Atmospheric pressure.

  17. Intense Seismic Activity at Chiles and Cerro Negro Volcanoes on the Colombia-Ecuador Border

    Science.gov (United States)

    Torres, R. A.; Cadena, O.; Gomez, D.; Ruiz, M. C.; Prejean, S. G.; Lyons, J. J.; White, R. A.

    2015-12-01

    The region of Chiles and Cerro Negro volcanoes, located on the Colombian-Ecuadorian border, has experienced an ongoing seismic swarm beginning in Aug. 2013. Based on concern for local residents and authorities, a cooperative broadband monitoring network was installed by the Servicio Geológico Colombiano in Colombia and the Instituto Geofísico of the Escuela Politécnica Nacional in Ecuador. Since November 2013 more than 538,000 earthquakes were recorded; although since May 2015 the seismicity has decreased significantly to an average of 70 events per day. Three large earthquake swarms with increasing energy occurred in Aug.-Oct. 2013, March-May 2014, and Sept.-Dec. 2014. By the end of 2014, roughly 400 earthquakes greater than M 3 had occurred with a maximum rate of 8000 earthquakes per day. The largest earthquake was a 5.6 ML on Oct. 20, 2014. This event produced an InSAR coseismic deformation of ~23 cm (S. Ebmeier, personal communication). Most events are typical brittle failure volcano-tectonic (VT) earthquakes that are located in a cluster beneath the southern flank of Chiles volcano, with depths between 1.5 and 10 km. Although the great majority of earthquakes are VT, some low-frequency (LF, ~0.5 Hz) and very-low-frequency (VLF) events have occurred. Particle motion analysis suggests that the VLF source migrated with time. While a VLF on Oct. 15, 2014 was located south of Chiles volcano, near the InSAR source, the VLF registered on Feb. 14, 2015 was likely located very close to Chiles Volcano. We infer that magma intrusion and resulting fluid exsolution at depths greater than 5 km are driving seismicity in the Chiles-Cerro Negro region. However earthquakes are failing in a manner consistent with regional tectonics. Relative relocations reveal a structure consistent with mapped regional faults. Thus seismicity is likely controlled by an interaction of magmatic and tectonic processes. Because the regional stress field is highly compressional and the volcanoes

  18. Atmospheric conditions at Cerro Armazones derived from astronomical data

    Science.gov (United States)

    Lakićević, Maša; Kimeswenger, Stefan; Noll, Stefan; Kausch, Wolfgang; Unterguggenberger, Stefanie; Kerber, Florian

    2016-04-01

    Aims: We studied the precipitable water vapour (PWV) content near Cerro Armazones and discuss the potential use of our technique of modelling the telluric absorbtion lines for the investigation of other molecular layers. The site is designated for the European Extremely Large Telescope (E-ELT) and the nearby planned site for the Čerenkov Telescope Array (CTA). Methods: Spectroscopic data from the Bochum Echelle Spectroscopic Observer (BESO) instrument were investigated by using a line-by-line radiative transfer model (LBLRTM) for the Earth's atmosphere with the telluric absorption correction tool molecfit. All observations from the archive in the period from December 2008 to the end of 2014 were investigated. The dataset completely covers the El Niño event registered in the period 2009-2010. Models of the 3D Global Data Assimilation System (GDAS) were used for further comparison. Moreover, we present a direct comparison for those days for which data from a similar study with VLT/X-Shooter and microwave radiometer LHATPRO at Cerro Paranal are available. Results: This analysis shows that the site has systematically lower PWV values, even after accounting for the decrease in PWV expected from the higher altitude of the site with respect to Cerro Paranal, using the average atmosphere found with radiosondes. We found that GDAS data are not a suitable basis for predicting local atmospheric conditions - they usually systematically overestimate the PWV values. The large sample furthermore enabled us to characterize the site with respect to symmetry across the sky and variation with the years and within the seasons. This technique of studying the atmospheric conditions is shown to be a promising step into a possible monitoring equipment for the CTA. Based on archival observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile and of the Cerro Armazones Observatory facilities of the Ruhr Universität Bochum.Full Table 1

  19. Hydrothermal organic synthesis experiments

    Science.gov (United States)

    Shock, Everett L.

    1992-01-01

    Ways in which heat is useful in organic synthesis experiments are described, and experiments on the hydrothermal destruction and synthesis of organic compounds are discussed. It is pointed out that, if heat can overcome kinetic barriers to the formation of metastable states from reduced or oxidized starting materials, abiotic synthesis under hydrothermal conditions is a distinct possibility. However, carefully controlled experiments which replicate the descriptive variables of natural hydrothermal systems have not yet been conducted with the aim of testing the hypothesis of hydrothermal organic systems.

  20. Connected magma plumbing system between Cerro Negro and El Hoyo Complex, Nicaragua revealed by gravity survey

    Science.gov (United States)

    MacQueen, Patricia; Zurek, Jeffrey; Williams-Jones, Glyn

    2016-11-01

    Cerro Negro, near León, Nicaragua is a young, relatively small basaltic cinder cone volcano that has been unusually active during its short lifespan. Multiple explosive eruptions have deposited significant amounts of ash on León and the surrounding rural communities. While a number of studies investigate the geochemistry and stress regime of the volcano, subsurface structures have only been studied by diffuse soil gas surveys. These studies have raised several questions as to the proper classification of Cerro Negro and its relation to neighboring volcanic features. To address these questions, we collected 119 gravity measurements around Cerro Negro volcano in an attempt to delineate deep structures at the volcano. The resulting complete Bouguer anomaly map revealed local positive gravity anomalies (wavelength 0.5 to 2 km, magnitude +4 mGal) and regional positive (10 km wavelength, magnitudes +10 and +8 mGal) and negative (12 and 6 km wavelength, magnitudes -18 and -13 mGal) Bouguer anomalies. Further analysis of these gravity data through inversion has revealed both local and regional density anomalies that we interpret as intrusive complexes at Cerro Negro and in the Nicaraguan Volcanic Arc. The local density anomalies at Cerro Negro have a density of 2700 kg m-3 (basalt) and are located between -250 and -2000 m above sea level. The distribution of recovered density anomalies suggests that eruptions at Cerro Negro may be tapping an interconnected magma plumbing system beneath El Hoyo, Cerro La Mula, and Cerro Negro, and more than seven other proximal volcanic features, implying that Cerro Negro should be considered the newest cone of a Cerro Negro-El Hoyo volcanic complex.

  1. Characterization of pottery from Cerro de Las Ventanas, Zacatecas, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-del-Rio, H.; Mireles-Garcia, F. [Unidad Academica de Estudios Nucleares, UAZ, Zacatecas (Mexico); Mendez-Cardona, R.Y. [Unidad Academica de Antropologia, UAZ, Zacatecas (Mexico); Nicolas-Caretta, M. [INAH Delegacion Zacatecas (Mexico); Coordinacion de Ciencias Sociales y Humanidades, UASLP, Fracc. Talleres, SLP (Mexico); Speakman, R.J. [Museum Conservation Inst., Smithsonian Institution, Suitland, MD (United States); Glascock, M.D. [Research Reactor Center, Univ. of Missouri, Columbia, MO (United States)

    2009-09-15

    With the aim of classifying prehispanic pottery from Cerro de Las Ventanas site, Juchipila, Zacatecas, Mexico, instrumental neutron activation analysis (INAA) was used to analyze ceramic samples at the University of Missouri Research Reactor Center. Thirty-two chemical elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Two multivariate statistical methods, cluster analysis and principal component analysis, were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Mesoamerican ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Malpaso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de Las Ventanas represent a new and unique chemical fingerprint in the region. (orig.)

  2. Geothermal exploration technology. Annual report, 1978

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    Progress is reported on the following programs: electrical and electromagnetic computer modeling techniques; minicomputer for in-field processing of magnetotelluric data; superconducting thin-film gradiometer and magnetometers for geophysical applications; magnetotellurics with SQUID magnetometers; controlled-source electromagnetic system; geothermal seismic field system development; Klamath Basin geothermal resource and exploration technique evaluation; Mt. Hood geothermal resource evaluation; East Mesa seismic study; seismological studies at Cerro Prieto; self-potential studies at Cerro Prieto; resistivity studies at Cerro Prieto; magnetotelluric survey at Cerro Prieto; and precision gravity studies at Cerro Prieto. (MHR)

  3. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  4. Geotechnical Applications of the Self-Potential Method. Report 3. Development of Self-Potential Interpretation Techniques for Seepage Detection

    Science.gov (United States)

    1989-02-01

    D. V., and Corwin, R. F. 1982. Inversion of Self-Potential Data from the Cerro Prieto Geothermal Field, Mexico: Geophysics, Vol 47, No. 6, pp 938...movement of geothermal fluids in the vicinity of fault or fracture zones, similar anomalies also have been observed above vertical or nearly vertical...Hydrothermal Convection in the Crust: A Possible Mechanism of Self-Potential Anomalies in Geothermal Areas (in Japanese): Journal of the Geothermal Research

  5. Evidence of recent deep magmatic activity at Cerro Bravo-Cerro Machín volcanic complex, central Colombia. Implications for future volcanic activity at Nevado del Ruiz, Cerro Machín and other volcanoes

    Science.gov (United States)

    Londono, John Makario

    2016-09-01

    In the last nine years (2007-2015), the Cerro Bravo-Cerro Machín volcanic complex (CBCMVC), located in central Colombia, has experienced many changes in volcanic activity. In particular at Nevado del Ruiz volcano (NRV), Cerro Machin volcano (CMV) and Cerro Bravo (CBV) volcano. The recent activity of NRV, as well as increasing seismic activity at other volcanic centers of the CBCMVC, were preceded by notable changes in various geophysical and geochemical parameters, that suggests renewed magmatic activity is occurring at the volcanic complex. The onset of this activity started with seismicity located west of the volcanic complex, followed by seismicity at CBV and CMV. Later in 2010, strong seismicity was observed at NRV, with two small eruptions in 2012. After that, seismicity has been observed intermittently at other volcanic centers such as Santa Isabel, Cerro España, Paramillo de Santa Rosa, Quindío and Tolima volcanoes, which persists until today. Local deformation was observed from 2007 at NRV, followed by possible regional deformation at various volcanic centers between 2011 and 2013. In 2008, an increase in CO2 and Radon in soil was observed at CBV, followed by a change in helium isotopes at CMV between 2009 and 2011. Moreover, SO2 showed an increase from 2010 at NRV, with values remaining high until the present. These observations suggest that renewed magmatic activity is currently occurring at CBCMVC. NRV shows changes in its activity that may be related to this new magmatic activity. NRV is currently exhibiting the most activity of any volcano in the CBCMVC, which may be due to it being the only open volcanic system at this time. This suggests that over the coming years, there is a high probability of new unrest or an increase in volcanic activity of other volcanoes of the CBCMVC.

  6. Catalytic Hydrothermal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  7. Investigating the subsurface connection beneath Cerro Negro volcano and the El Hoyo Complex, Nicaragua

    Science.gov (United States)

    Venugopal, Swetha; Moune, Séverine; Williams-Jones, Glyn

    2016-10-01

    Cerro Negro, the youngest volcano along the Central American Volcanic Belt (CAVB), is a polygenetic cinder cone with relatively frequent basaltic eruptions. The neighbouring El Hoyo complex, of which Las Pilas is the dominant edifice, is a much larger and older complex with milder and less frequent eruptions. Previous studies have suggested a deep link beneath these two closely spaced volcanoes (McKnight, 1995; MacQueen, 2013). Melt inclusions were collected from various tephra samples in order to determine whether a connection exists and to delineate the features of this link. Major, volatile, and trace elemental compositions reveal a distinct geochemical continuum with Cerro Negro defining the primitive endmember and El Hoyo representing the evolved endmember. Magmatic conditions at the time of melt inclusion entrapment were estimated with major and volatile contents: 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for El Hoyo melts with an overall oxygen fugacity at the NNO buffer. Trace element contents are distinct and suggest Cerro Negro magmas fractionally crystallise while El Hoyo magmas are a mix between primitive Cerro Negro melts and residual and evolved El Hoyo magma. Modelling of end member compositions with alphaMELTS confirms the unique nature of El Hoyo magmas as resulting from incremental mixing between Cerro Negro and residual evolved magma at 4 km depth. Combining all available literature data, this study presents a model of the interconnected subsurface plumbing system. This model considers the modern day analogue of the Lemptégy cinder cones in Massif Central, France and incorporates structurally controlled dykes. The main implications of this study are the classification of Cerro Negro as the newest conduit within the El Hoyo Complex as well as the potential re-activation of the El Hoyo edifice.

  8. The Lassen hydrothermal system

    Science.gov (United States)

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  9. Complexing and hydrothermal ore deposition

    CERN Document Server

    Helgeson, Harold C

    1964-01-01

    Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

  10. Petrological and Geochemical Studies of the Igneous Rocks at Cerro EL Borrego, Chihuahua, Mexico

    Science.gov (United States)

    Estrada, V. M.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.

    2013-05-01

    Cerro El Borrego, which is a hill composed of igneous rocks, is located 13.7 km to the SW of Chihuahua city, in northern Mexico. The coordinates of the hill are 28° 11' 07'' N latitude and 105° 33' 23'' W longitude. The study area is within the Basin and Range Physiographic Province, characterized by a complex tectonic-structural pattern, such as elongated ranges with folds and igneous rock formations of Paleogene age. A lava flow of Oligocene age is part of the large volcanic and plutonic activity at the early times of the Cenozoic, which occurred to the NW portion of Mexico. In Cerro El Borrego, the rocks that outcrop are middle Oligocene's rhyolitic tuff to the NW of the hill, while to its SE there is a Pleistocene polymictic conglomerate. Previous work shows different interpretations about the origin and composition of the igneous rocks at Cerro El Borrego. This project includes whole rock and textural analyses, which helped to discern the petrogenesis of these rocks. Preliminary petrographic analyses indicate that the Cerro El Borrego, is a structural dome, and its feldspar-rich rocks contain large crystals that can be appreciated without a microscope. The presence of a porphyritic texture, suggest a sallow intrusion origin. A preliminary conclusion is that Cerro El Borrego is a shallow depth intrusive body with a syenitic composition derived from the Oligocene plutonic activity.

  11. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, Dragan

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of wat

  12. Hydrothermal Reactivity of Amines

    Science.gov (United States)

    Robinson, K.; Shock, E.; Hartnett, H. E.; Williams, L. B.; Gould, I.

    2013-12-01

    The reactivity of aqueous amines depends on temperature, pH, and redox state [1], all of which are highly variable in hydrothermal systems. Temperature and pH affect the ratio of protonated to unprotonated amines (R-NH2 + H+ = R-NH3+), which act as nucleophiles and electrophiles, respectively. We hypothesize that this dual nature can explain the pH dependence of reaction rates, and predict that rates will approach a maximum at pH = pKa where the ratio of protonated and unprotonated amines approaches one and the two compounds are poised to react with one another. Higher temperatures in hydrothermal systems allow for more rapid reaction rates, readily reversible reactions, and unique carbon-nitrogen chemistry in which water acts as a reagent in addition to being the solvent. In this study, aqueous benzylamine was used as a model compound to explore the reaction mechanisms, kinetics, and equilibria of amines under hydrothermal conditions. Experiments were carried out in anoxic silica glass tubes at 250°C (Psat) using phosphate-buffered solutions to observe changes in reaction rates and product distributions as a function of pH. The rate of decomposition of benzylamine was much faster at pH 4 than at pH 9, consistent with the prediction that benzylamine acts as both nucleophile and an electrophile, and our estimate that the pKa of benzylamine is ~5 at 250°C and Psat. Accordingly, dibenzylamine is the primary product of the reaction of two benzylamine molecules, and this reaction is readily reversible under hydrothermal conditions. Extremely acidic or basic pH can be used to suppress dibenzylamine production, which also suppresses the formation of all other major products, including toluene, benzyl alcohol, dibenzylimine, and tribenzylamine. This suggests that dibenzylamine is the lone primary product that then itself reacts as a precursor to produce the above compounds. Analog experiments performed with ring-substituted benzylamine derivatives and chiral

  13. Indios y blancos en la ciudad minera: Cerro de Pasco en el siglo XIX1

    OpenAIRE

    Contreras, Carlos

    2014-01-01

    En este artículo se presenta una descripción de las condiciones de vida, materiales y culturales en Cerro de Pasco durante el siglo pasado, cuando era una de las principales ciudades de la sierra peruana, tanto en lo económico como en lo demográfico.El autor discute las características de la estructura social de Cerro de Pasco, recalcando la yuxtaposición de elementos económicos y étnico-culturales y el tipo de relaciones sociales prevalecientes. Luego describe las características y condicion...

  14. Santuarios prehispánicos identificados sobre cimas de cerros en Aguascalientes, México

    OpenAIRE

    Macías Quintero, Juan Ignacio; Villagrana Prieto, Citlallitl Selene

    2016-01-01

    Este trabajo considera la presencia de estructuras arqueológicas dispuestas sobre la cima de cerros en la región Centro-Norte de México, con énfasis en el valle del río Verde-San Pedro, Aguascalientes. Regularmente, los sitios dispuestos en cerros aislados y cimas escarpadas se han contemplado como fortificaciones que reflejaban conflictos e inestabilidad. Sin embargo, hemos identificado que estos asentamientos podrían ser de santuarios que, junto con otros elementos naturales y culturales (p...

  15. Origin and evolution of mineralizing fluids and exploration of the Cerro Quema Au-Cu deposit (Azuero Peninsula, Panama) from a fluid inclusion and stable isotope perspective

    Science.gov (United States)

    Corral, Isaac; Cardellach, Esteve; Corbella, Merce; Canals, Angels; Griera, Albert; Gomez-Gras, David; Johnson, Craig A.

    2017-01-01

    Cerro Quema is a high sulfidation epithermal Au-Cu deposit with a measured, indicated and inferred resource of 35.98 Mt. @ 0.77 g/t Au containing 893,600 oz. Au (including 183,930 oz. Au equiv. of Cu ore). It is characterized by a large hydrothermal alteration zone which is interpreted to represent the lithocap of a porphyry system. The innermost zone of the lithocap is constituted by vuggy quartz with advanced argillic alteration locally developed on its margin, enclosed by a well-developed zone of argillic alteration, grading to an external halo of propylitic alteration. The mineralization occurs in the form of disseminations and microveinlets of pyrite, chalcopyrite, enargite, tennantite, and trace sphalerite, crosscut by quartz, barite, pyrite, chalcopyrite, sphalerite and galena veins.Microthermometric analyses of two phase (L + V) secondary fluid inclusions in igneous quartz phenocrysts in vuggy quartz and advanced argillically altered samples indicate low temperature (140–216 °C) and low salinity (0.5–4.8 wt% NaCl eq.) fluids, with hotter and more saline fluids identified in the east half of the deposit (Cerro Quema area).Stable isotope analyses (S, O, H) were performed on mineralization and alteration minerals, including pyrite, chalcopyrite, enargite, alunite, barite, kaolinite, dickite and vuggy quartz. The range of δ34S of sulfides is from − 4.8 to − 12.7‰, whereas δ34S of sulfates range from 14.1 to 17.4‰. The estimated δ34SΣS of the hydrothermal fluid is − 0.5‰. Within the advanced argillic altered zone the δ34S values of sulfides and sulfates are interpreted to reflect isotopic equilibrium at temperatures of ~ 240 °C. The δ18O values of vuggy quartz range from 9.0 to 17.5‰, and the δ18O values estimated for the vuggy quartz-forming fluid range from − 2.3 to 3.0‰, indicating that it precipitated from mixing of magmatic fluids with surficial fluids. The δ18O of kaolinite ranges from 12.7 to 18.1‰ and

  16. Hydrothermal synthesis of hydroxyapatite

    Science.gov (United States)

    Earl, J. S.; Wood, D. J.; Milne, S. J.

    2006-02-01

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO3)2bold dot4H2O and (NH4)2HPO4 with distilled water, in a hydrothermal reactor at 200 °C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO4). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  17. Hydrothermal synthesis of hydroxyapatite

    Energy Technology Data Exchange (ETDEWEB)

    Earl, J S; Wood, D J; Milne, S J [Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (United Kingdom)

    2006-02-22

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO{sub 3}){sub 2}{center_dot}4H{sub 2}O and (NH{sub 4}){sub 2}HPO{sub 4} with distilled water, in a hydrothermal reactor at 200 deg. C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO{sub 4}). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  18. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...

  19. Rock-magnetism and ore microscopy of the magnetite-apatite ore deposit from Cerro de Mercado, Mexico

    Science.gov (United States)

    Alva-Valdivia, L. M.; Goguitchaichvili, A.; Urrutia-Fucugauchi, J.; Caballero-Miranda, C.; Vivallo, W.

    2001-03-01

    Rock-magnetic and microscopic studies of the iron ores and associated igneous rocks in the Cerro de Mercado, Mexico, were carried out to determine the magnetic mineralogy and origin of natural remanent magnetization (NRM), related to the thermo-chemical processes due to hydrothermalism. Chemical remanent magnetization (CRM) seems to be present in most of investigated ore and wall rock samples, replacing completely or partially an original thermoremanent magnetization (TRM). Magnetite (or Ti-poor titanomagnetite) and hematite are commonly found in the ores. Although hematite may carry a stable CRM, no secondary components are detected above 580°, which probably attests that oxidation occurred soon enough after the extrusion and cooling of the ore-bearing magma. NRM polarities for most of the studied units are reverse. There is some scatter in the cleaned remanence directions of the ores, which may result from physical movement of the ores during faulting or mining, or from perturbation of the ambient field during remanence acquisition by inhomogeneous internal fields within these strongly magnetic ore deposits. The microscopy study under reflected light shows that the magnetic carriers are mainly titanomagnetite, with significant amounts of ilmenite-hematite minerals, and goethite-limonite resulting from alteration processes. Magmatic titanomagnetites, which are found in igneous rocks, show trellis, sandwich, and composite textures, which are compatible with high temperature (deuteric) oxy-exsolution processes. Hydrothermal alteration in ore deposits is mainly indicated by martitization in oxide minerals. Grain sizes range from a few microns to >100 mm, and possible magnetic state from single to multidomain, in agreement with hysteresis measurements. Thermal spectra, continuous susceptibility measurements, and IRM (isothermal remanent magnetization) acquisition suggest a predominance of spinels as magnetic carriers, most probably titanomagnetites with low

  20. The Cerro Grande Fire - From Wildlife Modeling Through the Fire Aftermath

    Energy Technology Data Exchange (ETDEWEB)

    Rudell, T. M. (Theresa M.); Gille, R. W. (Roland W.)

    2001-01-01

    The Cerro Grande Fire developed from a prescribed burn by the National Park Service at Bandelier National Monument near Los Alamos, New Mexico. When the burn went out of control and became a wildfire, it attracted worldwide attention because it threatened the birthplace of the atomic bomb, Los Alamos National Laboratory (LANL). Was LANL prepared for a fire? What lessons have been learned?

  1. Evolución petrotectónica del distrito minero Cerro Áspero y modelo de emplazamiento de los depósitos wolframíferos, Córdoba Petrotectonic evolution of the Cerro Aspero mining district and emplacement model of the wolframiferous deposits, Córdoba

    Directory of Open Access Journals (Sweden)

    D. Mutti

    2005-03-01

    located in the eastern part of the Sierra de Comechingones. The region was affected by polimetamorphism during the Pampean and Famatinian cycles. At least two events of simple shearing (D3 and D4 and penetrative structures (S2, S3 and S4 were developed, favouring the anorogenic intrusion of Cerro Aspero batholith since late Devonian. This magmatic event was followed by a reactivation of deformation structures and circulation of hydrothermal fluids through rocks underlying a massive amphibolite level belonging to La Aguada formation, which mainly acted as an impermeable barrier in the area. A maximum stress s1 directed 330º promoted the development of mineralized systems following the fracturing pattern of Riedel's model, and also the development of a principal mineralized path related to a simple dextral shear belt, 285º in direction (S5. During the evolution of the magmatic-hydrothermal system, a high number of stages of fracturing and opening along rocks were registered, with sealing of cavities by mechanism of crack seal and pressure dissolution. By these mechanisms, fibrous habit silica was precipitated and metallic elements were concentrated, under a traction regime and a pore fluid pressure estimated in 195 MPa. The age of one of the mineralizing stages was determined in 343,8 ± 10,8 Ma through K/Ar dating in muscovite.

  2. Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

    Science.gov (United States)

    Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

    2009-01-01

    Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

  3. Geothermal Energy in the Pacific Region

    Science.gov (United States)

    1975-05-01

    verted to electricity at the present time at eight sites, briefly descr: in the Pacific region: The Geysers, California; Cerro Prieto , Mexico...New Zealand, the Geysers in California, Lardarello, in Ttaly, and Cerro Prieto , in Mexico, very high temperatures have been hrought close to the...Mexico es The Mexicali-Imperial valley geothermal province extends into north- ern Mexico in the vicinity of Mexicali, and here, at Cerro Prieto , the

  4. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza Geology of Cerro Guanaquero region, Diamante River, Mendoza

    OpenAIRE

    Federico Fuentes; Ramos,Victor A.

    2008-01-01

    El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánic...

  5. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of central Chile

    Science.gov (United States)

    Hildreth, W.; Singer, B.; Godoy, E.; Munizaga, F.

    1998-01-01

    Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km3 edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.

  6. Materiales del Poblado de las Paredejas en el Cerro del Berrueco. Una Nueva Arracada

    Directory of Open Access Journals (Sweden)

    Carlos PIÑEL

    2009-10-01

    Full Text Available Queremos dar a conocer con esta nota el interesante hallazgo de una arracada de oro en el yacimiento de «Las Paredejas» o «Santa Lucía», en el Cerro del Berrueco, así como de otros objetos, procedentes del mismo lugar, que quizá nos acerquen a un conocimiento de la joyería occidental durante la 2.a Edad del Hierro en la Península y por otra parte a una mayor aclaración del conjunto arqueológico que constituye el Cerro del Berrueco, dos de cuyos poblados fueron estudiados por Maluquer: el yacimiento de «La Mariselva», situado en la ladera meridional del Berroquillo, perteneciente al Bronce I y II y el del «Canoho Enamorado», situado este último en la parte alta del Cerro y desarrollándose durante la 1.a Edad del Hierro, a partir de cuya fecha surgen los poblados que se localizan en la base.

  7. Recycling of water, carbon, and sulfur during subduction of serpentinites: A stable isotope study of Cerro del Almirez, Spain

    Science.gov (United States)

    Alt, Jeffrey C.; Garrido, Carlos J.; Shanks, Wayne C.; Turchyn, Alexandra; Padrón-Navarta, José Alberto; López Sánchez-Vizcaíno, Vicente; Gómez Pugnaire, María Teresa; Marchesi, Claudio

    2012-01-01

    We use the concentrations and isotope compositions of water, carbon, and sulfur in serpentinites and their dehydration products to trace the cycling of volatiles during subduction. Antigorite serpentinites from the Cerro del Almirez complex, Spain, contain 9–12 wt.% H2O and 910 ± 730 ppm sulfur, and have bulk δ18O values of 8.6 ± 0.4‰, δD = − 54 ± 5‰, and δ34S = 5.0‰, consistent with serpentinization at temperatures of ~ 200 °C by seawater hydrothermal fluids in a seafloor setting. The serpentinites were dehydrated to chlorite–harzburgite (olivine + orthopyroxene + chlorite) at 700 °C and 1.6–1.9 GPa during subduction metamorphism, resulting in loss of water, and sulfur. The chlorite–harzburgites contain 5.7 ± 1.9 wt.% H2O, and have bulk δ18O = 8.0 ± 0.9‰, and δD = − 77 ± 11‰. The rocks contain 650 ± 620 ppm sulfur having δ34S = 1.2‰. Dehydration of serpentinite resulted in loss of 5 wt.% H2O having δ18O = 8–10‰ and δD = − 27 to − 65‰, and loss of 260 ppm sulfur as sulfate, having δ34S = 14.5‰. The contents and δ13C of total carbon in the two rock types overlap, with a broad trend of decreasing carbon contents and δ13C from ~ 1300 to 200 ppm and − 9.6 to − 20.2‰. This reflects mixing between reduced carbon in the rocks (210 ppm, δ13C ≈ − 26‰) and seawater-derived carbonate (δ13C ≈ − 1‰). Our results indicate: 1) Serpentinized oceanic peridotites carry significant amounts of isotopically fractionated water, carbon and sulfur into subduction zones; 2) Subduction of serpentinites to high P and T results in loss of water, and sulfur, which can induce melting and contribute to 18O, D, and 34S enrichments and oxidation of the sub-arc mantle wedge; and 3) Isotopically fractionated water, carbon, and sulfur in serpentinite dehydration products are recycled deeper into the mantle where they can contribute to isotope heterogeneities and may be significant for volatile budgets of the deep Earth.

  8. Hydrothermal pretreatment of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of OH'' seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  9. El recorrido al Cerro Gordo y el ritual tepehuano de las ofrendas en los cerros de la comunidad de San Bernardino de Milpillas

    Directory of Open Access Journals (Sweden)

    Chantal CRAMAUSSEL

    2014-01-01

    Full Text Available El ritual de las ofrendas es una ceremonia propiciatoria de la lluvia que se efectúa al terminar la estación seca en los cerros más altos de la comunidad de San Bernardino de Milpillas Chico, en la Sierra Tepehuana del estado de Durango. A esos rituales distintos de los cató- licos que forman parte del ciclo anual de costumbre concurren las autoridades civiles, los curanderos y miembros del Consejo de ancianos. Es un momento muy importante en el que se refuerza la cohesión de los tepehuanos que tienen un patrón de asentamiento muy disperso, como los demás grupos del norte, pero sus rituales presentan también similitudes con los mesoamericanos.

  10. Reconnaissance study of late quaternary faulting along cerro GoDen fault zone, western Puerto Rico

    Science.gov (United States)

    Mann, P.; Prentice, C.S.; Hippolyte, J.-C.; Grindlay, N.R.; Abrams, L.J.; Lao-Davila, D.

    2005-01-01

    The Cerro GoDen fault zone is associated with a curvilinear, continuous, and prominent topographic lineament in western Puerto Rico. The fault varies in strike from northwest to west. In its westernmost section, the fault is ???500 m south of an abrupt, curvilinear mountain front separating the 270- to 361-m-high La CaDena De San Francisco range from the Rio A??asco alluvial valley. The Quaternary fault of the A??asco Valley is in alignment with the bedrock fault mapped by D. McIntyre (1971) in the Central La Plata quadrangle sheet east of A??asco Valley. Previous workers have postulated that the Cerro GoDen fault zone continues southeast from the A??asco Valley and merges with the Great Southern Puerto Rico fault zone of south-central Puerto Rico. West of the A??asco Valley, the fault continues offshore into the Mona Passage (Caribbean Sea) where it is characterized by offsets of seafloor sediments estimated to be of late Quaternary age. Using both 1:18,500 scale air photographs taken in 1936 and 1:40,000 scale photographs taken by the U.S. Department of Agriculture in 1986, we iDentified geomorphic features suggestive of Quaternary fault movement in the A??asco Valley, including aligned and Deflected drainages, apparently offset terrace risers, and mountain-facing scarps. Many of these features suggest right-lateral displacement. Mapping of Paleogene bedrock units in the uplifted La CaDena range adjacent to the Cerro GoDen fault zone reveals the main tectonic events that have culminated in late Quaternary normal-oblique displacement across the Cerro GoDen fault. Cretaceous to Eocene rocks of the La CaDena range exhibit large folds with wavelengths of several kms. The orientation of folds and analysis of fault striations within the folds indicate that the folds formed by northeast-southwest shorTening in present-day geographic coordinates. The age of Deformation is well constrained as late Eocene-early Oligocene by an angular unconformity separating folDed, Deep

  11. The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au-Ag deposit in the Cerro Negro district, Deseado Massif, Patagonia, Argentina

    Science.gov (United States)

    Vidal, Conrado Permuy; Guido, Diego M.; Jovic, Sebastián M.; Bodnar, Robert J.; Moncada, Daniel; Melgarejo, Joan Carles; Hames, Willis

    2016-08-01

    The Cerro Negro district, within the Argentinian Deseado Massif province, has become one of the most significant recent epithermal discoveries, with estimated reserves plus resources of ˜6.7 Moz Au equivalent. The Marianas-San Marcos vein system contains about 70 % of the Au-Ag resources in the district. Mineralization consists of Upper Jurassic (155 Ma) epithermal Au- and Ag-rich veins of low to intermediate sulfidation style, hosted in and genetically related to Jurassic intermediate composition volcanic rocks (159-156 Ma). Veins have a complex infill history, represented by ten stages with clear crosscutting relationships that can be summarized in four main episodes: a low volume, metal-rich initial episode (E1), an extended banded quartz episode with minor mineralization (E2), a barren waning stage episode (E3), and a silver-rich late tectonic-hydrothermal episode (E4). The first three episodes are interpreted to have formed at the same time and probably from fluids of similar composition: a 290-230 °C fluid dominated by meteoric and volcanic waters (-3‰ to -0‰ δ18Owater), with <3 % NaCl equivalent salinity and with a magmatic source of sulfur (-1 to -2 ‰ δ34Swater). Metal was mainly precipitated at the beginning of vein formation (episode 1) due to a combination of boiling at ˜600 to 800 m below the paleowater table, and associated mixing/cooling processes, as evidenced by sulfide-rich bands showing crustiform-colloform quartz, adularia, and chlorite-smectite banding. During episodes 2 and 3, metal contents progressively decrease during continuing boiling conditions, and veins were filled by quartz and calcite during waning stages of the hydrothermal system, and the influx of bicarbonate waters (-6 to -8.5 ‰ δ18Owater). Hydrothermal alteration is characterized by proximal illite, adularia, and silica zone with chlorite and minor epidote, intermediate interlayered illite-smectite and a distal chlorite halo. This assemblage is in agreement with

  12. Archaeological fieldwork in the Bronze Age site of Cerro de la Encina (Monachil, Granada

    Directory of Open Access Journals (Sweden)

    Aranda Jiménez, Gonzalo

    2005-06-01

    Full Text Available New archaeological fieldwork has been carried out from November 2003 to May 2004 in the Bronze Age site of Cerro de la Encina, due to the interest of the regional government of Andalusia in displaying the settlement for visitors. The aim of this fieldwork has been the systematic excavation of a large settlement area partially known thanks to the excavations developed at the beginning of 1980s. A first toccupation period belonging to the Argaric Culture has been documented, highlighting specially the funerary ritual characterized by individual inhumations located below dwellings. After a gap in the occupation of the settlement a new social group belonging to the Late Bronze Age Culture of Southeast of Spain inhabits the Cerro de la Encina.

    El interés de la Consejería de Cultura de la Junta de Andalucía por la musealización del yacimiento del Cerro de la Encina ha motivado el desarrollo de nuevas investigaciones arqueológicas cuya primera fase se ha desarrollado entre Noviembre de 2003 y Mayo de 2004. Los trabajos han consistido en la excavación sistemática de un área de poblado de grandes dimensiones parcialmente conocida por las investigaciones realizadas a principios de los años 80. Los resultados han sido del máximo interés documentándose un primer momento de ocupación perteneciente a la Cultura de El Argar en el que destaca su espectacular registro funerario integrado dentro de las áreas de habitación. Tras un periodo de abandono del yacimiento se produce una nueva ocupación correspondiente a una comunidad del Bronce Final del Sureste.

  13. Hydrothermal Synthesis of Metal Silicates

    Institute of Scientific and Technical Information of China (English)

    Lii Kwang-Hwa

    2004-01-01

    Organically templated metal phosphates have been extensively studied because of interesting structural chemistry and potential applications in catalysis. However, in most cases the organic templates cannot be removed without collapse of the frameworks. This is in contrast to the high thermal stability and extensive applications of zeolites in refinery and petrochemical processes.Therefore, studies have been directed to the synthesis of transition metal silicates to produce more stable frameworks. Our synthetic methods are twofold, namely mild hydrothermal reactions in Teflon-lined autoclaves at 100-200 ℃ using organic amines as templates and high-temperature,high-pressure hydrothermal reactions in gold ampoules contained in a high-pressure reaction vessel at ca. 550 ℃ and 150 Mpa using alkali metal cations as templates. In this presentation I will report the high-temperature, high-pressure hydrothermal synthesis, crystal structures, and solid-state NMR spectroscopy of a number of new silicates of indium, uranium, and transition metals.

  14. Hydrothermalism in the Mediterranean Sea

    Science.gov (United States)

    Dando, P. R.; Stüben, D.; Varnavas, S. P.

    1999-08-01

    Hydrothermalism in the Mediterranean Sea results from the collision of the African and European plates, with the subduction of the oceanic part of the African plate below Europe. High heat flows in the resulting volcanic arcs and back-arc extensional areas have set-up hydrothermal convection systems. Most of the known hydrothermal sites are in shallow coastal waters, <200 m depth, so that much of the reported fluid venting is of the gasohydrothermal type. The hydrothermal liquids are of varying salinities, both because of phase separation as a result of seawater boiling at the low pressures and because of significant inputs of rainfall into the hydrothermal reservoirs at some sites. The major component of the vented gas is carbon dioxide, with significant quantities of sulphur dioxide, hydrogen sulphide, methane and hydrogen also being released. Acid leaching of the underlying rocks leads to the mobilisation of heavy metals, many of which are deposited sub-surface although there is a conspicuous enrichment of metals in surficial sediments in venting areas. Massive polymetalic sulphides have been reported from some sites. No extant vent-specific fauna have been described from Mediterranean sites. There is a reduced diversity of fauna within the sediments at the vents. In contrast, a high diversity of epifauna has been reported and the vent sites are areas of settlement for exotic thermophilic species. Large numbers of novel prokaryotes, especially hyperthermophilic crenarchaeota, have been isolated from Mediterranean hydrothermal vents. However, their distribution in the subsurface biosphere and their role in the biogeochemistry of the sites has yet to be studied.

  15. Cerro Papayo: an astronomical, calendrical and traditional landmark in Ancient Mexico.

    Science.gov (United States)

    Galindo Trejo, J.; Aguilera, T.; Montero García, I. A.

    Cerro Papayo is a peculiar formed hill (almost perfect semisphere, 3,630 m) situated at the east side of the Valley of Mexico. According to surface reconnaissance there is on its cusp a prehispanic site and a modern shrine dedicated to the Virgin of Guadalupe. Its striking appearance and its unobstructed visibility from anyplace in the Valley were used, since preclassic up to postclassic periods, to mark at sunrise the moment of precise astronomical, calendrical and traditional events. The present work shows observational evidence from Cuicuilco, the Templo Mayor of Tenochtitlan and Tepeyacac.

  16. Goldgroup矿业公司Cerro Prieto金矿投入商业化生产

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    Goldgroup矿业公司(Goldgroup Mining Inc.)日前宣布,公司所属墨西哥Sonora地区Cerro Prieto金矿从6月1日起正式投入商业化生产。此前从2013年12月起该金矿就一直在进行小规模中试,预计2016年该金矿黄金产量将达到15000盎司。

  17. Microwave Hydrothermal Synthesis PZT of Nanometer Crystal

    Institute of Scientific and Technical Information of China (English)

    Hongxing LIU; Hong DENG; Yan LI; Yanrong LI

    2004-01-01

    It was focused on the applications and developments of microwave hydrothermal synthesis piezoelectric ceramic powder. The microwave hydrothermal vessel was designed and manufactured. The microwave hydrothermal synthesis system was established and the PZT piezoelectric ceramic powder was synthesized. XRD and TEM have been used to characterize the products in detail. The diameter of the PZT powder particle is from 40 to 60 nm.

  18. Comentarios a las ponencias de Lourenzo Fernández Prieto y Marcela Sabaté Sort

    Directory of Open Access Journals (Sweden)

    Ricardo ROBLEDO HERNÁNDEZ

    2010-02-01

    Full Text Available La ponencia de Lorenzo Fernández Prieto empieza por reivindicar los problemas del presente como punto de partida en la construcción de la historia aconsejando tener en cuenta como referente la crisis del modelo de modernización y el fin de la ideología del progreso. Resulta llamativo que al mismo tiempo, aunque sea de forma marginal, eche una lanza a favor de Fukuyama, tildado habitualmente de ideología conservadora. Pero esto, por decirlo de algún modo, es casi una anécdota puesto que el principal foco de atención es la historia rural como el ámbito más pertinente de historia transnacional. Su ponencia es un alegato más que engrosa la corriente de opinión cada vez más caudalosa en contra de la tesis del fracaso o del excepcionalismo hispánicos. Casi hace treinta años que se está hablando en esta dirección, desde que Martínez Alier y Naredo descartaron que existiera una evolución muy diferente de la agricultura española y que el comportamiento de los grandes labradores o el carácter de las instituciones fueran factores explicativos relevantes en esa supuesta diferenciación.

  19. Models of Metabolic Community Structure in Martian Habitable Environments: Constraints from a Terrestrial Analog Acid-Sulfate Fumarole Environment, Cerro Negro Volcano, Nicaragua

    Science.gov (United States)

    Rogers, K. L.; McCollom, T. M.; Hynek, B. M.

    2014-12-01

    Microbial habitability in extreme environments on Earth is described by microscale geochemical conditions that constrain metabolic niches in concert with long-term habitat stability that is governed by dynamic geologic processes. Using terrestrial analogs to identify habitable martian environments requires correlating microscale geochemical constraints with reconstructions of past martian environments that are based on global-scale observations. While past martian environments can be characterized by primary parameters (e.g. pH, redox, mineralogy, thermal history), microbial habitability on Earth is a complex function of both primary and derived parameters (e.g. metabolic reaction energetics, chemical & thermal gradients, flow dynamics). In recent years we have been investigating acid-sulfate fumaroles at the Mars analog site, Cerro Negro Volcano, Nicaragua, where habitability is constrained by steep thermal gradients, spatially- and temporally-variable vent dynamics, and limited water and nutrient availability. The most common niche identified thus far is found in fumaroles that host mixed photosynthetic and chemosynthetic endolithic microbial communities. One such endolith is dominated by acidic red algae (Cyanidiales), aerobic bacterial heterotrophs (Ktedonobacteria), and archaeal thermoacidophiles (Hyperthermus, Caldisphaera, and Thermofilum). An analysis of the metabolic structure suggests that primary production by the red algae supports the growth of heterotrophic thermoacidophiles. Diversification among the chemoheterotrophs with respect to temperature and oxygen tolerance suggests community adaptation to environmental gradients or variable venting dynamics. Furthermore, individual cells within the endolith are silica-encrusted, providing the possibility for biosignature formation and preservation. Putative hydrothermal environments on early Mars with similar conditions could have supported endolithic communities with comparable metabolic strategies. Even

  20. Electricity generation from hydrothermal vents

    Science.gov (United States)

    Aryadi, Y.; Rizal, I. S.; Fadhli, M. N.

    2016-09-01

    Hydrothermal vent is a kind of manifestation of geothermal energy on seabed. It produces high temperature fluid through a hole which has a diameter in various range between several inches to tens of meters. Hydrothermal vent is mostly found over ocean ridges. There are some 67000 km of ocean ridges, 13000 of them have been already studied discovering more than 280 sites with geothermal vents. Some of them have a thermal power of up to 60 MWt. These big potential resources of energy, which are located over subsea, have a constraint related to environmental impact to the biotas live around when it becomes an object of exploitation. Organic Rankine Cycle (ORC) is a method of exploiting heat energy to become electricity using organic fluid. This paper presents a model of exploitation technology of hydrothermal vent using ORC method. With conservative calculation, it can give result of 15 MWe by exploiting a middle range diameter of hydrothermal vent in deep of 2000 meters below sea level. The technology provided here really has small impact to the environment. With an output energy as huge as mentioned before, the price of constructing this technology is low considering the empty of cost for drilling as what it should be in conventional exploitation. This paper also presents the comparison in several equipment which is more suitable to be installed over subsea.

  1. HYDROTHERMAL CRACKING OF RESIDUAL OILS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrothermal cracking of heavy oils, such as Canadian oil sand bitumen and Arabian heavy vacuum residue, as well as their model compound were performed over sulfided Ni/Al2O3 and NiMo/Al2O3 catalysts under 663~703 K and 6.0~8.0 MPa of hydrogen pressure in a batch autoclave reactor. According to the reaction mechanism of hydrothermal cracking, a small amount of free redical initiators, such as di-tert-peroxide, sulfur, etc., was added into the feed to generate free redicals at lower temperature, and obviously showed promotional effect on the conversion of hydrocarbons. The reaction mechanisms of hydrothermal cracking as well as the enhancing effect of initiators were studied by a probe reaction with 1-phenyldodecane as a model compound. The hydrothermal cracking of hydrocarbon proceeded via free redical mechanism and hydrogenating quench. The initiators might easily generate free redicals under reaction temperature, these redicals might abstract H from hydrocarbon molecule and reasonably initiate the chain reactions, therefore, promote the conversion of hydrocarbon even at lower reaction temperature.

  2. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

  3. A first shallow firn-core record from Glaciar La Ollada, Cerro Mercedario, central Argentine Andes

    Science.gov (United States)

    Bolius, David; Schwikowski, Margit; Jenk, Theo; Gäggeler, Heinz W.; Casassa, Gino; Rivera, Andrés

    In January 2003, shallow firn cores were recovered from Glaciar Esmeralda on Cerro del Plomo (33°14‧ S, 70°13‧ W; 5300 ma.s.l.), central Chile, and from Glaciar La Ollada on Cerro Mercedario (31°58‧ S, 70°07‧ W; 6070 ma.s.l.), Argentina, in order to find a suitable archive for paleoclimate reconstruction in a region strongly influenced by the El Niño-Southern Oscillation. In the area between 28° S and 35° S, the amount of winter precipitation is significantly correlated to the Southern Oscillation Index, with higher values during El Niño years. Glaciochemical analysis indicates that the paleo-record at Glaciar La Ollada is well preserved, whereas at Glaciar Esmeralda the record is strongly influenced by meltwater formation and percolation. A preliminary dating of the Mercedario core by annual-layer counting results in a time-span of 17 years (1986-2002), yielding an average annual net accumulation of 0.45 m w.e.

  4. Optical Sky Brightness at Cerro Tololo Inter-American Observatory from 1992 to 2006

    CERN Document Server

    Krisciunas, Kevin; Sanhueza, Pedro; Schwarz, Hugo E; Semler, Dylan R; Suntzeff, Nicholas B; Vera, Sergio

    2007-01-01

    We present optical UBVRI sky brightness measures from 1992 through 2006. The data are based on CCD imagery obtained with the CTIO 0.9-m, 1.3-m, and 1.5-m telescopes. The B- and V-band data are in reasonable agreement with measurements previously made at Mauna Kea, though on the basis of a small number of images per year there are discrepancies for the years 1992 through 1994. Our CCD-based data are not significantly different than values obtained at Cerro Paranal. We find that the yearly averages of V-band sky brightness are best correlated with the 10.7-cm solar flux taken 5 days prior to the sky brightness measures. This implies an average speed of 350 km/sec for the solar wind. While we can measure an enhancement of the night sky levels over La Serena 10 degrees above the horizon, at elevation angles above 45 degrees we find no evidence that the night sky brightness at Cerro Tololo is affected by artificial light of nearby towns and cities.

  5. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  6. Elemental analysis of pottery from Cerro de las Ventanas, Zacatecas, by INAA

    Energy Technology Data Exchange (ETDEWEB)

    Lopez del Rio, H.; Mireles G, F. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Calle Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Mendez C, R. Y. [Universidad Autonoma de Zacatecas, Unidad Academica de Antropologia, Apdo. Postal 555 Suc. C, Zacatecas (Mexico); Nicolas C, M. [Universidad Autonoma de San Luis Potosi, Coordinacion de Ciencias Sociales y Humanidades, Av. Industrias 101-A, Fracc. Talleres, 78494 San Luis Potosi (Mexico); Speakman, R. J. [Museum Conservation Institute, Smithsonian Institution, Suitland, 20746 Maryland (United States); Glascock, M. D. [Reactor Center, University of Missouri, Columbia, 65211 Missouri (United States)

    2009-10-15

    Fifteen ceramic fragments samples from Cerro de las Ventanas site, Zacatecas, were analyzed by instrumental neutron activation analysis. Thirty-two elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Cluster analysis and principal component analysis were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Meso american ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Mal paso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de las Ventanas represent a new and unique chemical fingerprint in the region. (Author)

  7. SITE CHARACTERISTICS OF THE SUMMIT OF CERRO CHAJNANTOR AT THE 5640 M ALTITUDE

    Directory of Open Access Journals (Sweden)

    K. Motohara

    2011-01-01

    Full Text Available Instituto de Astronomía de la Universidad de Tokio está promoviendo el proyecto TAO (University of Tokyo Atacama Observatory; Yoshii et al. 2010 para construir un telescopio infrarrojo en la cima de Cerro Chajnantor (altitud 5640 m en el desierto de Atacama en el Norte de Chile. Para la evaluación de las características del sitio, primero se realizó el monitoreo del tiempo atmosférico, la emisividad de nubes y el seeing durante 2006. 2007. La fracción despejada fue alta (>80% y la mediana del seeing en la banda V fue de tan solo 0."69. Un telescopio explorador de 1 m llamado miniTAO fue instalado y comenzó a observar en 2009. Con éste se han obtenido imágenes satisfactorias de Paα de hidrógeno 1.875 μm como también imágenes de 30.40 μm por primera vez desde un telescopio en tierra. Estos resultados demuestran que la cima de Cerro Chajnantor es uno de los mejores sitios para la astronomía infrarroja en la Tierra.

  8. Cerro Negro field, Venezuela: geological images from a high resolution 3-D survey

    Energy Technology Data Exchange (ETDEWEB)

    Woller, Kevin L. [Mobil Technology Co. (WEC)

    1999-07-01

    Following a pilot 3-D survey, Petrolera Cerro Negro acquired and processed a 3-D dynamite survey over the Cerro Negro Field in Venezuela. We designed the survey to achieve high frequency imaging at the relatively shallow (< 1000 m) objectives in the Morichal formation. The data exhibits usable frequencies in the 10-120 Hz range after migration. The results of the survey have satisfied the original objective of imaging the faults and basement structure in the field. Use of continuity measurements on the data has resulted in a photographic quality image of the faults at the basement level. The pattern of the faults indicates an unexpected degree of complexity, indicating a richer structural history than originally thought. The continuity data also shows depositional details in the Morichal, which in accordance with geological history of the area. The operatorship is currently in the process of drilling many horizontal development wells. The patterns of the wells bores and variations in the rock types present a challenge to the usage of the 3-D seismic. The operatorship is working to raise the understanding and utility of the seismic data to another plateau. (author)

  9. Geothermal Resource Verification for Air Force Bases,

    Science.gov (United States)

    1981-06-01

    680OF (3600 C) in the Salton Sea, California, and the nearby Cerro Prieto region of Mexico. Liquid water can exist underground in nature to a maxi...northwest Mexico’s Cerro Prieto field and southcentral California’s Imperial Valley area [banwell (1970)]. The Baca field in New Mexico’s Jemez Mountains

  10. La campaña del sur (1813-1816) en las telas de josé maría espinosa prieto

    OpenAIRE

    Chicangana-Bayona,Yobenj Aucardo

    2011-01-01

    Este artículo aborda el estudio de una de las nuevas temáticas de la pintura republicana después de la independencia: la representación de batallas. Específicamente, se analizan la serie de ocho pinturas dedicadas a batallas y acciones sobre la Campaña del Sur (1813-1816), pintadas por José María Espinosa Prieto (1796-1883) y compradas por el gobierno de Manuel Murillo Toro durante su segundo período (1872-1874).

  11. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza Geology of Cerro Guanaquero region, Diamante River, Mendoza

    Directory of Open Access Journals (Sweden)

    Federico Fuentes

    2008-03-01

    Full Text Available El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánicas pliocenas a recientes de composición intermedia a básica, y depósitos cuaternarios inconsolidados. El cerro Guanaquero, un estratovolcán pliocuaternario intensamente erosionado por glaciares pleistocenos, con sus 4.841 metros es el rasgo orográfico más prominente. Está constituido esencialmente por andesitas grises porfíricas, piroxénicas a biotíticas. Intercaladas con las coladas andesíticas se presentan depósitos piroclásticos, aglomerados volcánicos, ignimbritas y basaltos. La datación de una andesita por el método K-Ar en roca total arrojó una edad de 1,4 ± 0,1 Ma. La deformación ándica comenzó en forma de una faja plegada y corrida de piel fina, con pliegues por despegue en el sector occidental y por propagación de falla en el oriental. La compresión al oeste de los 69º47´O terminó por invertir la fallas normales del rift mesozoico. A lo largo de este meridiano se encuentra la falla más importante de la región, la que se ha correlacionado con la falla Malargüe, bien desarrollada en latitudes más australes. Esta falla limita la faja plegada y corrida del Aconcagua, de naturaleza epidérmica, y la faja plegada y corrida de Malargüe, controlada por la inversión tectónica del basamento. El volcanismo fue muy intenso en el Plioceno y el Cuaternario, correspondiendo a un período de empinamiento de la placa oceánica subducida, en el que la región ha sido levantada pasivamente. La alta resistencia a la erosión de

  12. Mineral assemblages and oxygen and sulphur fugacities in natural water-rock interaction processes

    Science.gov (United States)

    D'Amore, F.; Gianelli, G.

    1984-04-01

    Several mineral assemblages capable of buffering oxygen and sulphur fugacity and theoretical calculations were used to determine the fugacities of these two gas species over a temperature range between 150° and 350°C. Computed values were compared with those calculated from the composition of the geothermal fluids of Larderello, Travale, Bagnore and Piancastagnaio (Italy), The Geysers (USA) and Cerro Prieto (Mexico). The possible hydrothermal mineral assemblages that best fit the field data are those containing minerals frequently found in many geothermal fields: epidote, chlorite, K-feldspar, quartz and pyrite. These assemblages can be used in place of the classical buffers based on iron oxides and sulphides.

  13. Arterial oxygen saturation in healthy newborns delivered at term in Cerro de Pasco (4340 m and Lima (150 m

    Directory of Open Access Journals (Sweden)

    Gonzales Gustavo F

    2005-09-01

    Full Text Available Abstract Background High altitude is associated with both low pulse oxygen saturation at birth and more pre-term deliveries. The present study was performed to determine pulse oxygen saturation in newborns at term in Cerro de Pasco (4340 m and Lima (150 m to test the hypothesis that low pulse oxygen saturation at birth at high altitudes was not observed at term deliveries. Methods The present study was designed to determine pulse oxygen saturation values through 1 minute to 24 hours and values of Apgar score at 1 and 5 minutes in newborns delivered at term in Cerro de Pasco (4340 m and Lima (150 m. Pulse oxygen saturation was recorded in 39 newborns from Cerro de Pasco (4340 m and 131 from Lima (150 m at 1, 2, 3, 4, 5, 10, 15, 30 minutes and 1, 2, 8 and 24 hours after delivery. Apgar score was assessed at 1 and 5 minutes after birth. Neurological score was assessed at 24 h of birth by Dubowitz exam. Results Pulse oxygen saturation increased significantly from 1 to 15 min after birth at sea level and from 1 to 30 minutes at Cerro de Pasco. Thereafter, it increased slightly such that at 30 min at sea level and at 60 minutes in Cerro de Pasco it reached a plateau up to 24 hours after birth. At all times, pulse oxygen saturation was significantly higher at sea level than at high altitude (P Conclusion From these analyses may be concluded that pulse oxygen saturation at 4340 m was significantly low despite the fact that births occurred at term. Apgar scores at first minute and neurological scores were also lower at high altitudes.

  14. Zinc stannate nanostructures: hydrothermal synthesis

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2011-01-01

    Full Text Available Nanostructured binary semiconducting metal oxides have received much attention in the last decade owing to their unique properties rendering them suitable for a wide range of applications. In the quest to further improve the physical and chemical properties, an interest in ternary complex oxides has become noticeable in recent times. Zinc stannate or zinc tin oxide (ZTO is a class of ternary oxides that are known for their stable properties under extreme conditions, higher electron mobility compared to its binary counterparts and other interesting optical properties. The material is thus ideal for applications from solar cells and sensors to photocatalysts. Among the different methods of synthesizing ZTO nanostructures, the hydrothermal method is an attractive green process that is carried out at low temperatures. In this review, we summarize the conditions leading to the growth of different ZTO nanostructures using the hydrothermal method and delve into a few of its applications reported in the literature.

  15. BESO échelle spectroscopy of solar-type stars at Cerro Armazones

    Science.gov (United States)

    Fuhrmann, K.; Chini, R.; Hoffmeister, V. H.; Lemke, R.; Murphy, M.; Seifert, W.; Stahl, O.

    2011-03-01

    The Bochum Échelle Spectroscopic Observer BESO is a fibre-fed high-resolution spectrograph for the 1.5-m Hexapod Telescope at the Cerro Armazones Observatory in the Atacama desert in Chile. Here we report on the first BESO observations and model atmosphere analyses of solar-type stars secured in 2010 April. The quality of the data is first tested with a reflected sunlight spectrum as well as the standard G-type subgiant 70 Vir. We then investigate the bright and supposedly single F-type star ξ Gem and present the spectroscopic evidence that instead favours an equal-mass binary. We present also the first composite synthetic modelling of the G-type visual binary HR 3430 and discuss the spectroscopic observations that identify this as a triple system. We conclude with another triple, the famous and very nearby α Cen, and the basic stellar parameters of its inner, solar-type visual binary.

  16. Study of the atmospheric conditions at Cerro Armazones using astronomical data

    CERN Document Server

    Lakicevic, Masha; Noll, Stefan; Kausch, Wolfgang; Unterguggenberger, Stefanie; Kerber, Florian

    2016-01-01

    Aims: We studied the precipitable water vapour (PWV) content near Cerro Armazones and discuss the potential use of our technique of modelling the telluric absorbtion lines for the investigation of other molecular layers. The site is designated for the European Extremely Large Telescope (E-ELT) and the nearby planned site for the Cherenkov Telescope Array (CTA). Methods: Spectroscopic data from the Bochum Echelle Spectroscopic Observer (BESO) instrument were investigated by using line-by-line radiative transfer model (LBLRTM) radiative transfer models for the Earths atmosphere with the telluric absorption correction tool molecfit. All observations from the archive in the period from December 2008 to the end of 2014 were investigated. The dataset completely covers the El Nino event registered in the period 2009-2010. Models of the 3D Global Data Assimilation System (GDAS) were used for further comparison. Moreover, for those days with coincidence of data from a similar study with VLT/X-shooter and microwave rad...

  17. Mathematical Modeling of the Dynamics of Salmonella Cerro Infection in a US Dairy Herd

    Science.gov (United States)

    Chapagain, Prem; van Kessel, Jo Ann; Karns, Jeffrey; Wolfgang, David; Schukken, Ynte; Grohn, Yrjo

    2006-03-01

    Salmonellosis has been one of the major causes of human foodborne illness in the US. The high prevalence of infections makes transmission dynamics of Salmonella in a farm environment of interest both from animal and human health perspectives. Mathematical modeling approaches are increasingly being applied to understand the dynamics of various infectious diseases in dairy herds. Here, we describe the transmission dynamics of Salmonella infection in a dairy herd with a set of non-linear differential equations. Although the infection dynamics of different serotypes of Salmonella in cattle are likely to be different, we find that a relatively simple SIR-type model can describe the observed dynamics of the Salmonella enterica serotype Cerro infection in the herd.

  18. MOVIMIENTOS DE LADERA Y PLANEAMIENTO URBANÍSTICO: EL CONFLICTO DEL CERRO DEL OPE, ARCHENA (MURCIA

    Directory of Open Access Journals (Sweden)

    María Dolores Gómez Moreno

    2009-01-01

    Full Text Available Los desprendimientos son un proceso natural que afecta, de forma generalizada en el Valle de Ricote, a las laderas del tipo cantil-talud. Su peligrosidad radica en que los bloques desprendidos del escarpe ruedan con facilidad, talud abajo, cuando son descalzados por efecto de la escorrentía superfi cial o desestabilizados por movimientos sísmicos. El planeamiento urbanístico se convierte en factor inductor del riesgo al clasifi car como urbanizables y urbanos suelos que, por su ubicación en pie de ladera, deberían excluirse de cualquier proceso urbanizador. Este es el caso de Archena en el entorno inmediato del cerro del Ope.

  19. Burning down the brewery: establishing and evacuating an ancient imperial colony at Cerro Baul, Peru.

    Science.gov (United States)

    Moseley, Michael E; Nash, Donna J; Williams, Patrick Ryan; DeFrance, Susan D; Miranda, Ana; Ruales, Mario

    2005-11-29

    Before the Inca reigned, two empires held sway over the central Andes from anno Domini 600 to 1000: the Wari empire to the north ruled much of Peru, and Tiwanaku to the south reigned in Bolivia. Face-to-face contact came when both colonized the Moquegua Valley sierra in southern Peru. The state-sponsored Wari incursion, described here, entailed large-scale agrarian reclamation to sustain the occupation of two hills and the adjacent high mesa of Cerro Baúl. Monumental buildings were erected atop the mesa to serve an embassy-like delegation of nobles and attendant personnel that endured for centuries. Final evacuation of the Baúl enclave was accompanied by elaborate ceremonies with brewing, drinking, feasting, vessel smashing, and building burning.

  20. Volcanic hazard map for Telica, Cerro Negro and El Hoyo volcanoes, Nicaragua

    Science.gov (United States)

    Asahina, T.; Navarro, M.; Strauch, W.

    2007-05-01

    A volcano hazard study was conducted for Telica, Cerro Negro and El Hoyo volcanoes, Nicaragua, based on geological and volcanological field investigations, air photo analyses, and numerical eruption simulation. These volcanoes are among the most active volcanoes of the country. This study was realized 2004-2006 through technical cooperation of Japan International Cooperation Agency (JICA) with INETER, upon the request of the Government of Nicaragua. The resulting volcanic hazard map on 1:50,000 scale displays the hazards of lava flow, pyroclastic flows, lahars, tephra fall, volcanic bombs for an area of 1,300 square kilometers. The map and corresponding GIS coverage was handed out to Central, Departmental and Municipal authorities for their use and is included in a National GIS on Georisks developed and maintained by INETER.

  1. Mid amphibolite facies metamorphism of harzburgites in the Neoproterozoic Cerro Mantiqueiras Ophiolite, southernmost Brazil

    Directory of Open Access Journals (Sweden)

    HARTMANN LÉO A.

    2003-01-01

    Full Text Available Valuable information is retrieved from the integrated investigation of the field relationships, microstructure and mineral compositions of harzburgites from the Neoproterozoic Cerro Mantiqueiras Ophiolite. This important tectonic marker of the geological evolution of southernmost Brazilian Shield was thoroughly serpentinized during progressive metamorphism, because the oldest mineral assemblage is: olivine + orthopyroxene + tremolite + chlorite + chromite. This M1 was stabilized in mid amphibolite facies - 550-600ºC as calculated from mineral equilibria. No microstructural (e.g. ductile deformation of olivine or chromite or compositional (e.g. mantle spinel remnant of mantle history was identified. A metamorphic event M2 occurred in the low amphibolite facies along 100 m-wide shear zones, followed by intense serpentinization (M3 and narrow 1-3 m-wide shear zones (M4 containing asbestos.

  2. Burn Severities, Fire Intensities, and Impacts to Major Vegetation Types from the Cerro Grande Fire

    Energy Technology Data Exchange (ETDEWEB)

    Balice, Randy G. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bennett, Kathryn D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wright, Marjorie A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2004-12-15

    The Cerro Grande Fire resulted in major impacts and changes to the ecosystems that were burned. To partially document these effects, we estimated the acreage of major vegetation types that were burned at selected burn severity levels and fire intensity levels. To accomplish this, we adopted independently developed burn severity and fire intensity maps, in combination with a land cover map developed for habitat management purposes, as a basis for the analysis. To provide a measure of confidence in the acreage estimates, the accuracies of these maps were also assessed. In addition, two other maps of comparable quality were assessed for accuracy: one that was developed for mapping fuel risk and a second map that resulted from a preliminary application of an evolutionary computation software system, called GENIE.

  3. La necrópolis medieval del Cerro de la Horca de Toledo

    Directory of Open Access Journals (Sweden)

    Ruiz Taboada, Arturo

    2009-06-01

    Full Text Available The archaeological excavation of part of a medieval necropolis at the Cerro de la Horca (Toledo has provided new information regarding burial traditions in Toledo. One formal aspect is common to the broad range of graves that have been brought to light, namely the pit that was dug for the burial, being of considerable depth in a number of cases. Because little is known of the funerary practices in Toledo during the Middle Ages and hardly any objects have been recovered in the excavation, it is difficult to identify the religious community to which it belonged. Whereas the location of Muslim and Christian cemeteries have been known through documentary and archaeological sources, only popular traditions quoted so far the Jewish necropolis, its location remaining thus a mystery.

    La excavación arqueológica desarrollada en un sector del Cerro de La Horca ha permitido conocer aspectos inéditos del ritual de enterramiento medieval en Toledo. Se ha documentado una amplia tipología de tumbas con un único elemento constructivo común para todas ellas, la excavación previa de una fosa que, en numerosos casos, alcanza gran profundidad. El desconocimiento sobre el mundo funerario medieval toledano y la falta de materiales arqueológicos representativos en esta necrópolis han obligado a reflexionar sobre la comunidad religiosa a la que pertenecen estos enterramientos. Por fuentes históricas y excavaciones previas, conocemos la localización de necrópolis musulmanas y cristianas. La localización de la(s judía(s había sido, al menos hasta ahora, una incógnita.

  4. Sustainable carbon materials from hydrothermal processes

    CERN Document Server

    Titirici, Maria-Magdalena

    2013-01-01

    The production of low cost and environmentally friendly high performing carbon materials is crucial for a sustainable future. Sustainable Carbon Materials from Hydrothermal Processes describes a sustainable and alternative technique to produce carbon from biomass in water at low temperatures, a process known as Hydrothermal Carbonization (HTC). Sustainable Carbon Materials from Hydrothermal Processes presents an overview of this new and rapidly developing field, discussing various synthetic approaches, characterization of the final products, and modern fields of application fo

  5. Edad, caracterización petrográfica y Geoquímica del Granitoide del Cerro Falkner, Neuquén Age, petrography and geochemistry of Cerro Falkner's granitoid

    Directory of Open Access Journals (Sweden)

    Sabrina Crosta

    2008-03-01

    Full Text Available El Cerro Falkner se halla constituido por rocas graníticas infrayacentes a las volcanitas de la Formación Ventana de edad paleógena. Dichos intrusivos son de composición granodiorítica, metaluminosos a peraluminosos, subalcalinos, con características de granitos de arco volcánico concordantes con otros granitoides del segmento norte de la Cordillera Patagónica Septentrional. La edad obtenida por el método K-Ar sobre anfíboles de composición tschermakítica (125 ± 20 Ma indica una edad mínima perteneciente al Cretácico inferior para la granodiorita del cerro Falkner, por lo que sería incorrecto utilizar la denominación Formación Los Machis (Cretácico superior para estas rocas. Esta edad, permite vincular las rocas graníticas del área de estudio con el volcanismo representado por el Grupo Divisadero de edad predominantemente cretácica inferior.Cerro Falkner is composed of granitic rocks underlying volcanic rocks of the Ventana Formation of Paleogene age. Those intrusives are granodioritic in composition, metaluminous to peraluminous, subalkaline, with characteristics of volcanic arc granites that are concordant with other granitoids of the Cordillera Patagónica Septentrional's northern segment. The age obtained by the K-Ar method on tschemakitic amphiboles (125 ± 20 Ma points out a minimun age from the lower Cretaceous for the Cerro Falkner's granodiorite. Therefore the use of the term Los Machis Formation (Upper Cretaceous would be incorrect for these rocks. This age, allows us to relate the granitic rocks on the study area to the lower Cretaceous, coeval with the volcanism of the Divisadero Group.

  6. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  7. CATÁLOGO COMENTADO DE LAS HEPÁTICAS DEL CERRO DE MAMAPACHA, MUNICIPIO DE CHINAVITA-BOYACÁ, COLOMBIA

    Directory of Open Access Journals (Sweden)

    WILSON RICARDO ÁLVARO ALBA

    2007-01-01

    Full Text Available Se presenta el catálogo comentado de 77 especies de hepáticas presentes en el cerro de Mamapacha en donde se organizan alfabéticamente las familias, géneros y es- pecies. Se proporciona información sobre la forma de crecimiento, abundancia, hábitat y distribución. Se resalta la presencia de 23 especies como nuevos registros para Boyacá.

  8. Miguel Prieto y la escenografía en la España de los años treinta

    Directory of Open Access Journals (Sweden)

    Cabañas Bravo, Miguel

    2011-12-01

    Full Text Available The artist Miguel Prieto (1907-1956 worked in three main areas: painting-drawing, graphic design and set design. The latter was the one in which he demonstrated most interest in avant-garde and political commitment during the thirties, but due to his subsequent Mexican exile, has not been dealt with in recent research. This article, focused on his years in Spain, analyses his contributions to scenic design. Prieto’s first professional period, when he worked for the puppet theatre, coincided with the young Second Republic and then the convulsion of the Civil War. This popular genre was utilized for agitation, propaganda and the revolutionary theatre, and adopted both the classical repertoire and modern works by Alberti, Dieste, Lorca and other committed youthful intellectuals.

    Las tres grandes vertientes en las que el pintor Miguel Prieto (1907-1956 plasmó su creatividad fueron la pintura-dibujo, el diseño gráfico y la escenografía. Esta última, que fue en la que más énfasis puso tanto en su acercamiento a la vanguardia y el compromiso socio-político de los años treinta, como en los años finales de su trayectoria en el exilio mexicano, no ha sido suficientemente atendida. Este artículo, centrado en esa etapa española, analiza y pone en valor la aportación a la escena de Prieto coincidente con esos momentos de construcción de la joven II República y la convulsión de la Guerra Civil, que principalmente se plasmó en la escenificación de espectáculos de guiñol (extraídos del repertorio clásico o expresamente escritos por Alberti, Dieste, Lorca y otros jóvenes inquietos, ya que su tradición y clara aceptación popular los convertían en adecuado instrumento para encauzar la agitación y propaganda que querían sembrar el teatro revolucionario y la creatividad más avanzada y comprometida.

  9. Xenoliths of Cerro las Mercedes, Costa Rica: a Geochemical Record of Arc History?

    Science.gov (United States)

    Lindsay, F. N.; Gazel, E.; Herzberg, C. T.; Carr, M. J.; Feigenson, M. D.

    2006-12-01

    Over 70 ultramafic xenoliths, many with diameters of at least 3cm, open a window into the mantle beneath Cerro las Mercedes, Costa Rica. This quaternary vent is 70km behind the active volcanic front and near the northern boundary of the Caribbean Plateau. Both xenoliths and host lava remain well preserved in spite of substantial soil development in a rain forest environment. We analyzed the host lava and a subset of 30 rocks for bulk and mineral chemistry, which include both peridotite and pyroxenite populations. The host rock is Plio-Quaternary potassic alkaline basalt; depleted in SiO2 and Al2O3 and enriched in MgO and P2O5 relative to both present day and Miocene volcanics. In terms of trace elements, the host basalt has enriched LREEs and relative depletion of HFSEs, typical of island-arc basalt, both present and past. The coarse-grained pyroxenites have trace element chemistry akin to the volcanic front lavas of Costa Rica, although they are closer to chondritic values. Truly, they are more similar to basalts from Sarapiquí Miocene arc than to present day volcanic front basalts. Although there is enrichment in incompatible elements such as Ba and U and depletions in HFSEs, common in island arc basalts, the pyroxenites have a strong positive Pb anomaly that is characteristic only of the Miocene arc, not present day lavas. We interpret the pyroxenites as cumulates. The peridotite population includes dunites, spinel lherzolites and lherzolites. These rocks have Mg-numbers ranging from 87 to 92 and Cr-numbers ranging from 6 to 61. Whole rock geochemistry indicates that the peridotite xenoliths are fragments of mantle associated with the western Caribbean Plateau. SiO2, FeO, Al2O3 and MgO contents of several Cerro Mercedes peridotites are similar to those expected of hot residues that would form in a plume environment. Trace elements reveal some samples with enrichment of Ba and U, and depletion in Nb and Ta indicating variable extents of melt-rock reaction and

  10. Requiem en México por un exiliado español. La muerte de don Indalecio Prieto en 1962 y su tratamiento en la prensa mexicana

    OpenAIRE

    Carlos Sola Ayape

    2015-01-01

    El largo exilio español, una de las consecuencias directas del régimen franquista, provocó la progresiva e implacable pérdida de la mayor parte de los líderes políticos republicanos, muchos de ellos en México, país que convirtieron en su patria de adopción. Así sucedió con el líder socialista Indalecio Prieto Tuero, residente en la capital mexicana, donde la muerte le sorprendió en aquella madrugada del 12 de febrero de 1962. De este modo, y dada la gran resonancia de su trayectoria política ...

  11. Subsurface Connections and Magma Mixing as revealed by Olivine- and Pyroxene-Hosted Melt Inclusions from Cerro Negro Volcano and the Las Pilas-El Hoyo Complex, Nicaragua.

    Science.gov (United States)

    Venugopal, S.; Moune, S.; Williams-Jones, G.

    2015-12-01

    Cerro Negro, the youngest volcano in the Central American Volcanic Belt, is a polygenetic cinder cone with relatively frequent explosive basaltic eruptions. Las Pilas, on the other hand, is a much larger and older complex with milder and less frequent eruptions. Based on historical data, these two closely spaced volcanoes have shown concurrent eruptive behavior, suggesting a subsurface connection. To further investigate this link, melt inclusions, which are blebs of melt trapped in growing crystals, were the obvious choice for optimal comparison of sources and determination of pre-eruptive volatile contents and magmatic conditions. Olivine-hosted inclusions were chosen for both volcanoes and pyroxene-hosted inclusions were also sampled from Las Pilas to represent the evolved melt. Major, volatile and trace elements reveal a distinct geochemical continuum with Cerro Negro defining the primitive end member and Las Pilas representing the evolved end member. Volatile contents are high for Cerro Negro (up to 1260 ppm CO2, 4.27 wt% H2O and 1700 ppm S) suggesting that volatile exsolution is likely the trigger for Cerro Negro's explosive eruptions. Las Pilas volatile contents are lower but consistent with degassing and evolutionary trends shown by major oxides. Trace element contents are rather unique and suggest Cerro Negro magmas fractionally crystallize while Las Pilas magmas are the products of mixing. Magmatic conditions were estimated with major and volatile contents: at least 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for Las Pilas melts with an overall oxygen fugacity at the NNO buffer. In combination with available literature data, this study suggests an interconnected subsurface plumbing system and thus Cerro Negro should be considered as the newest vent within the Las Pilas-El Hoyo Complex.

  12. Dynamics of the Yellowstone hydrothermal system

    Science.gov (United States)

    Hurwitz, Shaul; Lowenstern, Jacob B.

    2014-01-01

    The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

  13. The Final Days of Paracas in Cerro del Gentil, Chincha Valley, Peru.

    Directory of Open Access Journals (Sweden)

    Henry Tantaleán

    Full Text Available This article describes and analyzes a highly significant archaeological context discovered in a late Paracas (400-200 BCE sunken patio in the monumental platform mound of Cerro Gentil, located in the Chincha Valley, Peru. This patio area was used for several centuries for ritual activities, including large-scale feasting and other public gatherings. At one point late in this historical sequence people deposited a great deal of objects in what is demonstrably a single historical event. This was quickly followed by a series of minor events stratigraphically immediately above this larger event. This entire ritual process included the consumption of liquids and food, and involved the offering of whole pottery, pottery fragments, botanical remains, bone, lithics, baskets, pyro-engraved gourds, mummies, and other objects. We interpret these events as an "abandonment ceremony" or "termination ritual" during the late Paracas period, one that may have lasted for weeks or even months. The subsequent Topará occupation at the site (ca. 200 BCE- AD 100 involved the architectural enhancement of the mound area, but the pattern of use of the patio itself ended. Such a termination ritual signals a reorganization in the regional political structure of Paracas society.

  14. Forecast of surface layer meteorological parameters at Cerro Paranal with a mesoscale atmospherical model

    CERN Document Server

    Lascaux, Franck; Fini, Luca

    2015-01-01

    This article aims at proving the feasibility of the forecast of all the most relevant classical atmospherical parameters for astronomical applications (wind speed and direction, temperature) above the ESO ground-base site of Cerro Paranal with a mesoscale atmospherical model called Meso-Nh. In a precedent paper we have preliminarily treated the model performances obtained in reconstructing some key atmospherical parameters in the surface layer 0-30~m studying the bias and the RMSE on a statistical sample of 20 nights. Results were very encouraging and it appeared therefore mandatory to confirm such a good result on a much richer statistical sample. In this paper, the study was extended to a total sample of 129 nights between 2007 and 2011 distributed in different parts of the solar year. This large sample made our analysis more robust and definitive in terms of the model performances and permitted us to confirm the excellent performances of the model. Besides, we present an independent analysis of the model p...

  15. A simulation of the Cerro Hudson SO[sub 2] cloud

    Energy Technology Data Exchange (ETDEWEB)

    Schoeberl, M.R.; Lait, L.R.; Newman, P.A.; Krueger, A.J. (NASA Goddard Space Flight Center, Greenbelt, MD (United States)); Doiron, S.D. (Hughes STX Corp., Lanham, MD (United States))

    1993-02-20

    An isentropic trajectory model is used to simulate the evolution of the southern hemisphere SO[sub 2] cloud associated with the eruption of Cerro Hudson. By matching the parcel trajectories with total ozone mapping spectrometer SO[sub 2] retrievals, the principal stratospheric injection region is determined to be between 11 and 16 km in altitude. This region is characterized by weak wind shears and is located just poleward of the subtropical jet in the outer fringe of the stratospheric polar vortex. The lack of wind shear in the injection region explains the slow zonal dispersal of the SO[sub 2] cloud which was still clearly observed 19 days after the eruption. The trajectory model simulation of the SO[sub 2] cloud shows good agreement with observations for 7 days after the eruption. Using the potential vorticity and potential temperature estimates of the initial eruption cloud, the cloud position relative to the polar night jet is shown to be nearly fixed up to September 2, 1991, which was as long as the cloud was observed. This result suggests that the lower stratopsheric polar and mid-latitude regions are nearly isolated from each other during the late August period. 9 refs., 5 figs.

  16. New mammalian records in the Parque Nacional Cerros de Amotape, northwestern Peru

    Directory of Open Access Journals (Sweden)

    Cindy M. Hurtado

    2015-04-01

    Full Text Available The Pacific Tropical Rainforest and Equatorial Dry Forest are found only in southern Ecuador and northern Peru, and are among the most poorly known ecosystems of South America. Even though these forests are protected in Parque Nacional Cerros de Amotape (PNCA, they are threatened by fragmentation because of farming and agriculture. The aim of this study was to determine the medium and large mammalian species richness, using transect census, camera trapping, and specimen bone collection. Nine transects were established and 21 camera trap stations were placed along 16 km2 in three localities of PNCA, from August 2012 to April 2013. Total sampling effort was 215 km of transects and 4077 camera-days. We documented 22 species; including 17 with camera trapping, 11 with transect census, and 10 with specimen collection.  Camera traps were the most effective method, and four species (Dasyprocta punctata, Cuniculus paca, Leopardus wiedii and Puma concolor were documented only with this method. This comprised the first Peruvian record for Dasyprocta punctata, and the first record for the western slope of the Peruvian Andes for Cuniculus paca. Also, both specimen collections and sightings confirm the presence of Potos flavus, first record in the western slope of the Peruvian Andes. Panthera onca, Tremarctos ornatus and Saimiri sciureus are considered locally extinct, while several species are in need of further research. We highlight the importance of the high diversity of this rainforests and encourage local authorities to give the area the highest priority in conservation.

  17. Research Experiences for Undergraduates at Cerro Tololo Inter-American Observatory

    Science.gov (United States)

    Hoard, D. W.; Smith, R. C.

    2000-12-01

    Each year, Cerro Tololo Inter-American Observatory (CTIO), located in La Serena, Chile, hosts a Research Experiences for Undergraduates (REU) Program funded by the National Science Foundation. In general, REU programs bring a group of undergraduate students to the host institute for 10 weeks, where they are teamed-up with staff members to perform research projects. Unlike REU programs at other U.S. institutions, the CTIO program takes place outside the United States and during the southern summer/northern winter months of January--March. This offers students not only a chance to perform research and participate in the day-to-day life at a major astronomical observatory, but also provides a unique exposure to a foreign culture and an option for students who can take advantage of a non-traditional work experience during the academic year. CTIO REU students also benefit from interaction with their Chilean counterparts participating in the Prácticas de Investigación en Astronomía, an REU-like program operated by CTIO for Chilean undergraduates. Since 1995, CTIO has hosted 20 REU students (with 4 more coming in 2001). Twenty (and counting) publications have resulted from CTIO REU projects. In addition, since 1999, 100% of the CTIO REU students have presented the results of their research projects at meetings of the American Astronomical Society. We present here an overview of the REU program at CTIO.

  18. Prototype of a Space Fluorescence Detector at Cerro La Negra Mountain Site

    Science.gov (United States)

    Cordero, A.; Robledo, C.; Moreno, E.; Salazar, H.; Martinez, O.; Villaseñor, L.; Zepeda, A.; Khrenov, B.; Garipov, G.

    2003-07-01

    The prototype of space fluorescence detector TUS (see V. Alexandrov et al., this conference) is begin prepared for operation at the mountain site Cerro La Negra (atmosphere depth 600g /cm2). The fluorescence detector (FD) field of view cover the atmosphere above the EAS array at the Pico de Orizaba site (see O. Martinez et al., this conference), separated from the FD by ˜ 5k m. At night at energies E0 > 0.05EeV both FD and EAS array will operate as an "hybrid detector." The range of atmosphere depths available for observation of EAS tracks by FD in hybrid mode is 200g /cm2. FD will also observe EAS tracks at energies of about 1 EeV at distances R=25-50 km, at zenith angles > 450 (when the atmosphere depth is more than 850g /cm2 ) with direction of tracks perpendicular to the FD axis. The FD design and preliminary data of the FD performance will be presented.

  19. Unrest of Chiles - Cerro Negro volcanic complex: A binational Ecuador - Colombia effort

    Science.gov (United States)

    Ruiz, M. C.; Gomez, D.; Torres, R.; Cadena, O.; Mothes, P. A.; Anzieta, J. C.; Pacheco, D. A.; Bernard, B.; Acero, W.; Hidalgo, S.; Enriquez, W.; Cordova, A.

    2014-12-01

    The increasing seismic activity at the area of Chiles - Cerro Negro volcanic complex, located at the Ecuador-Colombian border, has been jointly monitored by the Instituto Geofisico - Ecuador and the Observatorio Vulcanologico y Sismologico de Pasto OVSP, a division of the Servicio Geologico Colombiano. Since April 2013, three seismic swarms have been detected in this area and more than 100.000 events are recorded since November 2013. The largest and more recent swarm has a daily average of 676 events between March and June 2014. Currently a seismic network of 8 seismic stations (5 in the Colombian and 3 in Ecuadorean side) are deployed in this area. Epicenters of more than 315 seismic events with magnitudes Ml>2.0 and 10 or more phases are located in an area 1-4 km south of Chiles volcano with shallow depths (up to 14 km). Most of events have magnitudes between 1.0 to 4.0. Nine events have magnitudes larger than 4.0 and the largest event occurred on April 30. 2014 with a local magnitude of 4.7 and inverse-transcurrent component focal mechanism. Waveforms and spectral patterns define these events as volcano-tectonic. Events with large magnitudes (above 3.0) show a very long-period component. Hot spring and deformation measurements also show signals of volcanic unrest.

  20. Measurements of air contaminants during the Cerro Grande fire at Los Alamos National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Eberhart, Craig

    2010-08-01

    Ambient air sampling for radioactive air contaminants was continued throughout the Cerro Grande fire that burned part of Los Alamos National Laboratory. During the fire, samples were collected more frequently than normal because buildup of smoke particles on the filters was decreasing the air flow. Overall, actual sampling time was 96% of the total possible sampling time for the May 2000 samples. To evaluate potential human exposure to air contaminants, the samples were analyzed as soon as possible and for additional specific radionuclides. Analyses showed that the smoke from the fire included resuspended radon decay products that had been accumulating for many years on the vegetation and the forest floor that burned. Concentrations of plutonium, americium, and depleted uranium were also measurable, but at locations and concentrations comparable to non-fire periods. A continuous particulate matter sampler measured concentrations that exceeded the National Ambient Air Quality Standard for PM-10 (particles less than 10 micrometers in diameter). These high concentrations were caused by smoke from the fire when it was close to the sampler.

  1. 3-cerro y 4-mundo: los números del banquete en las ofrendas quechuas

    Directory of Open Access Journals (Sweden)

    David Lorente Fernández

    2010-12-01

    Full Text Available Las ofrendas quechuas del sur del Perú son platos alimenticios, banquetes destinados principalmente a la pachamama y los apus, pero también elaborados sistemas matemáticos regidos por operaciones sofisticadas. Sirviéndose de dos números fundamentales, el 3 y el 4, los especialistas rituales son capaces de transmitir mensajes polisémicos. Mediante el número 3 aglutinan clientes, parajes y cerros, en suma, «personas» capaces de interactuar entre sí. El 3 aparece en los k’intus de hojas de coca y en las oraciones que se recitan durante el proceso de realizar la ofrenda. Por el contrario, el número 4 no indica relaciones sino formas espaciales: es un operador geométrico que unifica la servilleta ceremonial (unk’uña, el papel envoltorio y el paquete acabado para representar las cuatro direcciones del mundo y hacer de la ofrenda un mundo en miniatura. Gracias a los dos números el ritualista puede recrear el cosmos, establecer convenios con los dioses y definir nuevas situaciones favorables para la vida de sus clientes.

  2. Characterization of the sodium layer at Cerro Pachon, and impact on laser guide star performance

    CERN Document Server

    Neichel, Benoit; Callingham, Joseph; Rigaut, Francois; Winge, Claudia; Trancho, Gelys; 10.1093/mnras/sts631

    2013-01-01

    Detailed knowledge of the mesopheric sodium layer characteristics is crucial to estimate and optimize the performance of Laser Guide Star (LGS) assisted Adaptive Optics (AO) systems. In this paper, we present an analysis of two sets of data on the mesospheric sodium layer. The first set comes from a laser experiment that was carried out at Cerro Tololo to monitor the abundance and altitude of the mesospheric sodium in 2001, during six runs covering a period of one year. This data is used to derive the mesospheric sodium column density, the sodium layer thickness and the temporal behavior of the sodium layer mean altitude. The second set of data was gathered during the first year of the Gemini MCAO System (GeMS) commissioning and operations. GeMS uses five LGS to measure and compensate for atmospheric distortions. Analysis of the LGS wavefront sensor data provides information about the sodium photon return and the spot elongation seen by the WFS. All these parameters show large variations on a yearly, nightly ...

  3. The hydrothermal system of the Domuyo volcanic complex (Argentina): A conceptual model based on new geochemical and isotopic evidences

    Science.gov (United States)

    Tassi, F.; Liccioli, C.; Agusto, M.; Chiodini, G.; Vaselli, O.; Calabrese, S.; Pecoraino, G.; Tempesti, L.; Caponi, C.; Fiebig, J.; Caliro, S.; Caselli, A.

    2016-12-01

    The Domuyo volcanic complex (Neuquén Province, Argentina) hosts one of the most promising geothermal systems of Patagonia, giving rise to thermal manifestations discharging hot and Cl--rich fluids. This study reports a complete geochemical dataset of gas and water samples collected in three years (2013, 2014 and 2015) from the main fluid discharges of this area. The chemical and isotopic composition (δD-H2O and δ18O-H2O) of waters indicates that rainwater and snow melting are the primary recharge of a hydrothermal reservoir located at relative shallow depth (400-600 m) possibly connected to a second deeper (2-3 km) reservoir. Reactive magmatic gases are completely scrubbed by the hydrothermal aquifer(s), whereas interaction of meteoric waters at the surface causes a significant air contamination and dilution of the fluid discharges located along the creeks at the foothill of the Cerro Domuyo edifice. Thermal discharges located at relatively high altitude ( 3150 m a.s.l.), namely Bramadora, are less affected by this process, as also shown by their relatively high R/Ra values (up to 6.91) pointing to the occurrence of an actively degassing magma batch located at an unknown depth. Gas and solute geothermometry suggests equilibrium temperatures up to 220-240 °C likely referred to the shallower hydrothermal reservoir. These results, confirming the promising indications of the preliminary surveys carried out in the 1980‧s, provide useful information for a reliable estimation of the geothermal potential of this extinct volcanic system, although a detailed geophysical measurements is required for the correct estimation of depth and dimensions of the fluid reservoir(s).

  4. Nitrogen-doped hydrothermal carbons

    Energy Technology Data Exchange (ETDEWEB)

    Titirici, Maria-Magdalena; White, Robin J. [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; Zhao, Li [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; National Center for Nanoscience and Technology, Beijing (China)

    2012-07-01

    Nitrogen doped carbon materials are now playing an important role in cutting edge innovations for energy conversion and storage technologies such as supercapacitors and proton exchange membrane fuel cells as well as in catalytic applications, adsorption and CO{sub 2} capture. The production of such materials using benign aqueous based processes, mild temperatures and renewable precursors is of great promise in addressing growing environmental concerns for cleaner power sources at a time of increasing global demand for energy. In this perspective, we show that nitrogen doped carbons prepared using sustainable processes such as ''Hydrothermal Carbonisation'' has advantages in many applications over the conventional carbons. We also summarize an array of synthetic strategies used to create such nitrogen doped carbons, and discuss the application of these novel materials. (orig.)

  5. Catastrophic volcanic collapse: relation to hydrothermal processes.

    Science.gov (United States)

    López, D L; Williams, S N

    1993-06-18

    Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

  6. Hydrothermal system of Long Valley caldera, California

    Energy Technology Data Exchange (ETDEWEB)

    Sorey, M.L.; Lewis, R.E.; Olmsted, F.H.

    1978-01-01

    The geologic and hydrologic setting of the hydrothermal system are described. The geochemical and thermal characteristics of the system are presented. A mathematical model of the Long Valley caldera is analyzed. (MHR)

  7. Dissolubility of Hydroxyapatite Powder under Hydrothermal Condition

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dissolubility of hydroxyapatite(HA) in the hydrothermal solution was investigated in Morey-type autoclave over a temperature range of 150 to 350 ℃ and the pH value range of 5 to 9. It is shown that the dissolubility of HA is determined as a function of temperature and time under a constant filling ratio of autoclave, and the temperature coefficient for the solubility of HA is positive. The equilibrium time attained in the hydrothermal solution is shortened with the increase of hydrothermal temperature, and the effect of temperature on the solubility is obviously stronger than that of pH value. The solubility data suggest that HA has higher dissolubility in the HA-H2O system under the hydrothermal condition than that under the normal temperature-pressure.

  8. Hydrothermal Manganese Mineralization Near the Samoan Hotspot

    Science.gov (United States)

    Hein, J. R.; Staudigel, H.; Koppers, A.; Hart, S. R.; Dunham, R.

    2006-12-01

    The thickest beds of hydrothermal manganese oxides recovered to date from the global ocean were collected from a volcanic cone in the south Pacific. In April 2005, samples were dredged aboard the R.V. Kilo Moana from a volcanic cone on the lower flank of Tulaga seamount (about 2,700 m water depth; 14° 39.222' S; 170° 1.730' W), located 115 km SW of Vailulu'u, the volcanically and hydrothermally active center of the Samoan hotspot. Additional hydrothermal manganese samples were collected off Ofu Island (dredge Alia 107), 72 km to the WSW of Vailulu'u. Manganese-oxide beds up to 9 cm thick are composed of birnessite and 10 Å manganates. Some layers consist of Mn-oxide columnar structures 4 cm long and 1 cm wide, which have not been described previously. The mean Mn and Fe contents of 18 samples are 51 weight percent and 0.76 weight percent, respectively. Elevated concentrations of Li (mean 0.11 wt. percent) are indicators of a hydrothermal origin, and distinguishes these samples, along with the high Mn and low Fe contents, from hydrogenetic Fe-Mn crusts. Other enriched elements include Ba (mean 0.14 percent), Cu (249 ppm), Mo (451 ppm), Ni (400 ppm), Zn (394 ppm), V (214 ppm), and W (132 ppm). Chondrite-normalized REE patterns show large negative Ce anomalies and LREE enrichments, both characteristic of hydrothermal Mn deposits. Small negative Eu anomalies are not typical of hydrothermal deposits and can be explained either by the absence of leaching of plagioclase by the hydrothermal fluids or by the precipitation of Eu-rich minerals, such as barite and anhydrite, at depth. The high base-metal contents indicate that sulfides are not forming deeper in the hydrothermal system or that such deposits are being leached by the ascending fluids. Textures of the thickest Mn deposits indicate that the Mn oxides formed below the seabed from ascending fluids during multiple phases of waxing and waning hydrothermal pulses. The deposits were later exposed at the seafloor by

  9. Hydrothermal industrialization: direct heat development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  10. Validating numerical simulations of snow avalanches using dendrochronology: the Cerro Ventana event in Northern Patagonia, Argentina

    Directory of Open Access Journals (Sweden)

    A. Casteller

    2008-05-01

    Full Text Available The damage caused by snow avalanches to property and human lives is underestimated in many regions around the world, especially where this natural hazard remains poorly documented. One such region is the Argentinean Andes, where numerous settlements are threatened almost every winter by large snow avalanches. On 1 September 2002, the largest tragedy in the history of Argentinean mountaineering took place at Cerro Ventana, Northern Patagonia: nine persons were killed and seven others injured by a snow avalanche. In this paper, we combine both numerical modeling and dendrochronological investigations to reconstruct this event. Using information released by local governmental authorities and compiled in the field, the avalanche event was numerically simulated using the avalanche dynamics programs AVAL-1D and RAMMS. Avalanche characteristics, such as extent and date were determined using dendrochronological techniques. Model simulation results were compared with documentary and tree-ring evidences for the 2002 event. Our results show a good agreement between the simulated projection of the avalanche and its reconstructed extent using tree-ring records. Differences between the observed and the simulated avalanche, principally related to the snow height deposition in the run-out zone, are mostly attributed to the low resolution of the digital elevation model used to represent the valley topography. The main contributions of this study are (1 to provide the first calibration of numerical avalanche models for the Patagonian Andes and (2 to highlight the potential of Nothofagus pumilio tree-ring records to reconstruct past snow-avalanche events in time and space. Future research should focus on testing this combined approach in other forested regions of the Andes.

  11. The CCAT-prime Extreme Field-of-View Submillimeter Telescope on Cerro Chajnantor

    Science.gov (United States)

    Koopman, Brian; Bertoldi, Frank; Chapman, Scott; Fich, Michel; Giovanelli, Riccardo; Haynes, Martha P.; Herter, Terry L.; Murray, Norman W.; Niemack, Michael D.; Riechers, Dominik; Schilke, Peter; Stacey, Gordon J.; Stutzki, Juergen; CCAT-prime Collaboration

    2017-01-01

    CCAT-prime is a six meter aperture off-axis submillimeter telescope that we plan to build at 5600m elevation on Cerro Chajnantor in Chile. The CCAT-prime optics are based on a cross-Dragone design with high throughput and a wide field-of-view optimized to increase the mapping speed of next generation cosmic microwave background (CMB) observations. These characteristics make CCAT-prime an excellent platform for a wide range of next generation millimeter and submillimeter science goals, and a potential platform for CMB stage-IV measurements. Here we present the telescope design for CCAT-prime and review the science goals.Taking advantage of the high elevation site, the first generation instrument for CCAT-prime will measure seven different frequency bands from 350um to 3mm. These seven bands will enable precise measurements of the Sunyaev-Zel’dovich effects (SZE) by separating contributions from CMB, thermal SZE, kinetic SZE, bright submm galaxies, and radio sources with a goal of extracting the peculiar velocities from a large number of galaxy clusters. Additional science priorities for CCAT-prime include: Galactic Ecology studies of the dynamic intersteller medium by mapping the fine structure lines [CI], [CII] and [NII] as well as high-excitation CO lines at the shortest wavelength bands; high redshift intensity mapping of [CII] emission from star-forming galaxies that likely dominates cosmic reionization at z~5-9 to probe the Epoch of Reionization; and next generation CMB polarization measurements to constrain inflation and cosmological models. The CCAT-prime facility will further our understanding of astrophysical processes from moments after the Big Bang to the present-day evolution of the Milky Way.

  12. Planning and Analysis of Fractured Rock Injection Tests in the Cerro Brillador Underground Laboratory, Northern Chile

    Science.gov (United States)

    Fairley, J. P., Jr.; Oyarzún L, R.; Villegas, G.

    2015-12-01

    Early theories of fluid migration in unsaturated fractured rock hypothesized that matrix suction would dominate flow up to the point of matrix saturation. However, experiments in underground laboratories such as the ESF (Yucca Mountain, NV) have demonstrated that liquid water can migrate significant distances through fractures in an unsaturated porous medium, suggesting limited interaction between fractures and unsaturated matrix blocks and potentially rapid transmission of recharge to the sat- urated zone. Determining the conditions under which this rapid recharge may take place is an important factor in understanding deep percolation processes in arid areas with thick unsaturated zones. As part of an on-going, Fondecyt-funded project (award 11150587) to study mountain block hydrological processes in arid regions, we are plan- ning a series of in-situ fracture flow injection tests in the Cerro Brillador/Mina Escuela, an underground laboratory and teaching facility belonging to the Universidad la Serena, Chile. Planning for the tests is based on an analytical model and curve-matching method, originally developed to evaluate data from injection tests at Yucca Mountain (Fairley, J.P., 2010, WRR 46:W08542), that uses a known rate of liquid injection to a fracture (for example, from a packed-off section of borehole) and the observed rate of seepage discharging from the fracture to estimate effective fracture aperture, matrix sorptivity, fracture/matrix flow partitioning, and the wetted fracture/matrix interac- tion area between the injection and recovery points. We briefly review the analytical approach and its application to test planning and analysis, and describe the proposed tests and their goals.

  13. Validating numerical simulations of snow avalanches using dendrochronology: the Cerro Ventana event in Northern Patagonia, Argentina

    Science.gov (United States)

    Casteller, A.; Christen, M.; Villalba, R.; Martínez, H.; Stöckli, V.; Leiva, J. C.; Bartelt, P.

    2008-05-01

    The damage caused by snow avalanches to property and human lives is underestimated in many regions around the world, especially where this natural hazard remains poorly documented. One such region is the Argentinean Andes, where numerous settlements are threatened almost every winter by large snow avalanches. On 1 September 2002, the largest tragedy in the history of Argentinean mountaineering took place at Cerro Ventana, Northern Patagonia: nine persons were killed and seven others injured by a snow avalanche. In this paper, we combine both numerical modeling and dendrochronological investigations to reconstruct this event. Using information released by local governmental authorities and compiled in the field, the avalanche event was numerically simulated using the avalanche dynamics programs AVAL-1D and RAMMS. Avalanche characteristics, such as extent and date were determined using dendrochronological techniques. Model simulation results were compared with documentary and tree-ring evidences for the 2002 event. Our results show a good agreement between the simulated projection of the avalanche and its reconstructed extent using tree-ring records. Differences between the observed and the simulated avalanche, principally related to the snow height deposition in the run-out zone, are mostly attributed to the low resolution of the digital elevation model used to represent the valley topography. The main contributions of this study are (1) to provide the first calibration of numerical avalanche models for the Patagonian Andes and (2) to highlight the potential of textit{Nothofagus pumilio} tree-ring records to reconstruct past snow-avalanche events in time and space. Future research should focus on testing this combined approach in other forested regions of the Andes.

  14. Temporal Evolution of a Seismic Swarm at Chiles - Cerro Negro volcanic complex

    Science.gov (United States)

    Ruiz, Mario

    2015-04-01

    The increasing seismic activity in the area of the Chiles - Cerro Negro volcanic complex, located on the Ecuador-Colombian border, has been jointly monitored by the Instituto Geofisico - Ecuador and the Observatorio Vulcanologico y Sismologico de Pasto (OVSP), a division of the Servicio Geologico Colombiano. Since April 2013, three seismic swarms have been detected in this area, and more than 400.000 events have been recorded since November 2013. The largest and most recent swarm has a daily average of 3894 events between March and the 12th of December 2014. Currently a seismic network of 13 short- and broad-band stations (5 Colombian, 8 Ecuadorian) was deployed in this area. High quality epicenters of seismic events with magnitudes Ml>2.0, RMSChiles volcano with shallow depths (up to 14 km). Most events have magnitudes between 1.0 to 4.0. Fifteen events have magnitudes larger than 4.0 including an event that occurred on October 20, 2014. This event had a local magnitude of 5.7 and an oblique (strike-slip with some thrusting) focal mechanism. Waveforms and spectral patterns define these events as volcano-tectonic. However, events with moderate to large magnitudes (above 3.0) contain pronounced very-long-period components. Position time series recorded by a dual-frequency GPS receiver at the SE flank of Chiles show a slight departure from the normal tectonic trend beginning with the appearance of the last seismic swarm on or around September 30, 2014. This trend is subsequently punctuated by a sharp deformation transient related to the coseismic displacement of the October 20 event. After more than a year of very anomalous seismic activity and concurrent minor deformation, no evidence of surficial volcanic activity has been documented.

  15. Shallow earthquake inhibits unrest near Chiles-Cerro Negro volcanoes, Ecuador-Colombian border

    Science.gov (United States)

    Ebmeier, Susanna K.; Elliott, John R.; Nocquet, Jean-Mathieu; Biggs, Juliet; Mothes, Patricia; Jarrín, Paúl; Yépez, Marco; Aguaiza, Santiago; Lundgren, Paul; Samsonov, Sergey V.

    2016-09-01

    Magma movement or reservoir pressurisation can drive swarms of low-magnitude volcano-tectonic earthquakes, as well as occasional larger earthquakes (>M5) on local tectonic faults. Earthquakes >M5 near volcanoes are challenging to interpret in terms of evolving volcanic hazard, but are often associated with eruptions, and in some cases enhance the ascent of magma. We present geodetic observations from the first episode of unrest known to have occurred near Chiles and Cerro Negro de Mayasquer volcanoes on the Ecuador-Colombian border. A swarm of volcano-tectonic seismicity in October 2014 culminated in a Mw 5.6 earthquake south of the volcanoes. Satellite radar data spanning this earthquake detect displacements that are consistent with dextral oblique slip on a reverse fault at depths of 1.4-3.4 km within a SSW-NNE trending fault zone that last ruptured in 1886. GPS station measurements capture ∼20 days of uplift before the earthquake, probably originating from a pressure source ∼10-15 km south of Volcán Chiles, at depths exceeding 13 km. After the Mw 5.6 earthquake, uplift ceased and the rate of seismicity began to decrease. Potential mechanisms for this decline in activity include a decrease in the rate of movement of magma into the shallow crust, possibly caused by the restriction of fluid pathways. Our observations demonstrate that an earthquake triggered during volcanic unrest can inhibit magmatic processes, and have implications for the hazard interpretation of the interactions between earthquakes and volcanoes.

  16. Structural control on geothermal circulation in the Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Argentina)

    Science.gov (United States)

    Giordano, Guido; Pinton, Annamaria; Cianfarra, Paola; Baez, Walter; Chiodi, Agostina; Viramonte, José; Norini, Gianluca; Groppelli, Gianluca

    2013-01-01

    The reconstruction of the stratigraphical-structural framework and the hydrogeology of geothermal areas is fundamental for understanding the relationships between cap rocks, reservoir and circulation of geothermal fluids and for planning the exploitation of the field. The Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Central Andes, NW Argentina) has a high geothermal potential. It is crossed by the active NW-SE trans-Andean tectonic lineament known as the Calama-Olacapato-Toro (COT) fault system, which favours a high secondary permeability testified by the presence of numerous springs. This study presents new stratigraphic and hydrogeological data on the geothermal field, together with the analysis from remote sensed image analysis of morphostructural evidences associated with the structural framework and active tectonics. Our data suggest that the main geothermal reservoir is located within or below the Pre-Palaeozoic-Ordovician basement units, characterised by unevenly distributed secondary permeability. The reservoir is recharged by infiltration in the ridges above 4500 m a.s.l., where basement rocks are in outcrop. Below 4500 m a.s.l., the reservoir is covered by the low permeable Miocene-Quaternary units that allow a poor circulation of shallow groundwater. Geothermal fluids upwell in areas with more intense fracturing, especially where main regional structures, particularly NW-SE COT-parallel lineaments, intersect with secondary structures, such as at the Tocomar field. Away from the main tectonic features, such as at the Cerro Tuzgle field, the less developed network of faults and fractures allows only a moderate upwelling of geothermal fluids and a mixing between hot and shallow cold waters. The integration of field-based and remote-sensing analyses at the Cerro Tuzgle-Tocomar area proved to be effective in approaching the prospection of remote geothermal fields, and in defining the conceptual model for geothermal circulation.

  17. Arterial oxygen saturation in healthy newborns delivered at term in Cerro de Pasco (4340 m) and Lima (150 m)

    OpenAIRE

    Gonzales Gustavo F; Salirrosas Amelia

    2005-01-01

    Abstract Background High altitude is associated with both low pulse oxygen saturation at birth and more pre-term deliveries. The present study was performed to determine pulse oxygen saturation in newborns at term in Cerro de Pasco (4340 m) and Lima (150 m) to test the hypothesis that low pulse oxygen saturation at birth at high altitudes was not observed at term deliveries. Methods The present study was designed to determine pulse oxygen saturation values through 1 minute to 24 hours and val...

  18. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza

    OpenAIRE

    Federico Fuentes; Ramos,Victor A.

    2008-01-01

    El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánic...

  19. The Use of Geothermal Energy at Military Installations.

    Science.gov (United States)

    1976-10-01

    1973 at 4.8 MWe . Otake. Japan 13 1 FS 200 ? 5 3000 7~ Growth: Operation began in 1967 at 12 MWe . 60 — expected by 1980 Cerro Prieto , Mexico 75 2...of power plant operati on is infl uenced by one or more of the chemical constituents. In the V Cerro Prieto and Wairakei fields the water ‘In the well...Geothermal Province Source: Austin and Pringle , 1974 Salton Sea Cerro Prieto geothermal field geotherma l field I.I.D. No. 1a I.I.D. No. 2b M_ SC M_ 8C Sodium

  20. Peptide synthesis in early earth hydrothermal systems

    Science.gov (United States)

    Lemke, K.H.; Rosenbauer, R.J.; Bird, D.K.

    2009-01-01

    We report here results from experiments and thermodynamic calculations that demonstrate a rapid, temperature-enhanced synthesis of oligopeptides from the condensation of aqueous glycine. Experiments were conducted in custom-made hydrothermal reactors, and organic compounds were characterized with ultraviolet-visible procedures. A comparison of peptide yields at 260??C with those obtained at more moderate temperatures (160??C) gives evidence of a significant (13 kJ ?? mol-1) exergonic shift. In contrast to previous hydrothermal studies, we demonstrate that peptide synthesis is favored in hydrothermal fluids and that rates of peptide hydrolysis are controlled by the stability of the parent amino acid, with a critical dependence on reactor surface composition. From our study, we predict that rapid recycling of product peptides from cool into near-supercritical fluids in mid-ocean ridge hydrothermal systems will enhance peptide chain elongation. It is anticipated that the abundant hydrothermal systems on early Earth could have provided a substantial source of biomolecules required for the origin of life. Astrobiology 9, 141-146. ?? 2009 Mary Ann Liebert, Inc. 2009.

  1. ANALYSIS OF MUNICIPAL WASTEWATER AND ACID MINE DRAINAGE PASSIVE CO-TREATMENT AT CERRO RICO DE POTOSÍ, BOLIVIA

    Directory of Open Access Journals (Sweden)

    William H.J. Strosnider

    2015-06-01

    Full Text Available Acid mine drainage (AMD is a worldwide environmental problem. The passive co-treatment of AMD with municipal waste water (MWW is a cost effective approach that uses nutrients in MWW in order to treat high concentrations of metals and sulfate found in AMD. Cerro Rico de Potosí in Bolivia is one of the biggest mining cities in the world, and it is constantly facing problems with AMD. The goal of this study was to determine the reaction rates of Al, Fe, Mn, Zn, and other metals found in an AMD discharge from Cerro Rico by a three-stage reactor system. The AMD had a pH of 3.58 and acidity of 1080 mg/L as CaCO3 equivalent containing 12, 68, 17 and 550 mg/L of dissolved Al, Fe, Mn, and Zn respectively. The reaction rates of Al, Fe, Mn, and Zn were 1.43, 2.09, 0.01, and 0.10 d-1, respectively.

  2. Importaciones áticas del siglo V a.C. del Cerro del Prado (Algeciras, Cádiz

    Directory of Open Access Journals (Sweden)

    Cabrera, Paloma

    1996-12-01

    Full Text Available In this paper we analyze a group of Attic imports, found in the excavations of Cerro del Prado, a settlement situated in the Bahía de Algeciras (Cádiz. The great interest of this group lies in the fact that it belongs to a particular chronological period, the last third of the 5th century B.C., as we have not found later imports, and in the almost exclusive presence of black glazed vases, which gives US an idea of a very definitive demand of the punic society of the Iberian Peninsula regarding the trade of greek goods.

    Presentamos en este trabajo un conjunto de importaciones áticas halladas en las excavaciones del Cerro del Prado, situado en la bahía de Algeciras (Cádiz. El interés de este conjunto reside en su pertenencia a un momento cronológico muy concreto: el último tercio del siglo V a.C., no habiéndose hallado importaciones más modernas y en la presencia absoluta de vasos de barniz negro, lo que nos habla de una demanda muy determinada de la sociedad púnica peninsular frente al comercio de productos griegos.

  3. Paleomagnetism in the Determination of the Emplacement Temperature of Cerro Colorado Tuff Cone, El Pinacate Volcanic Field, Sonora, Mexico.

    Science.gov (United States)

    Rodriguez Trejo, A.; Alva-Valdivia, L. M.; Vidal Solano, J. R.; Garcia Amador, B.; Gonzalez-Rangel, J. A.

    2014-12-01

    Cerro Colorado Maar is located at the World Heritage Site, biosphere reserve El Pinacate and Gran Desierto del Altar, at the NNW region of Sonora, Mexico (in El Pinacate Volcanic Field). It is a tuff cone, about 1 km diameter, result of several phreatomagmatic episodes during the late Quaternary. We report paleomagnetic and rock magnetic properties from fusiform volcanic bombs obtained from the borders of Cerro Colorado. This study is based in the thermoremanent magnetization TRM normally acquired by volcanic rocks, which can be used to estimate the emplacement temperature range. We performed the experiments on 20 lithic fragments (10 cm to 20 cm approximately), taking 6-8 paleomagnetic cores from each. Rock magnetic experiments (magnetic susceptibility vs. temperature (k-T), hysteresis curves and FORC analysis, shows that the main magnetic mineral carriers of magnetization are titanomagnetite and titanohematite in different levels of intergrowth. The k-T curves suggest in many cases, only one magnetic phase, but also in other cases a second magnetic phase. Thermal demagnetization was used to demagnetize the specimens in detailed short steps and make a well-defined emplacement temperature determination ranges. We found that temperature emplacement determination range for these two magnetic phases is between 350-450 °C, and 550-580 °C, respectively. These results are consistent with those expected in an eruption of Surtsey type, showing a distinct volcanic activity compared to the other craters from El Pinacate volcanic field.

  4. A process for fire-related debris flow initiation, Cerro Grande fire, New Mexico

    Science.gov (United States)

    Cannon, S.H.; Bigio, E.R.; Mine, E.

    2001-01-01

    In this study we examine factors that pertain to the generation of debris flows from a basin recently burned by wildfire. Throughout the summer 2000 thunderstorm season, we monitored rain gauges, channel cross-sections, hillslope transects, and nine sediment-runoff traps deployed in a steep, 0??15 km2 basin burned by the May 2000 Cerro Grande fire in New Mexico. Debris flows were triggered in the monitored basin during a rainstorm on July 16, 2000, in response to a maximum 30 min rainfall intensity of 31 mm h-1 (return period of approximately 2 years). Eleven other storms occurred before and after the July storm; these storms resulted in significant runoff, but did not generate debris flows. The debris flows generated by the July 16 storm initiated on a broad, open hillslope as levee-lined rills. The levees were composed of gravel- and cobble-sized material supported by an abundant fine-grained matrix. Debris-flow deposits were observed only on the hillslopes and in the first and second-order drainages of the monitored basin. No significant amounts of channel incision were measured following the passage of the debris flows, indicating that most of the material in the flows originated from the hillslopes. Sediment-runoff concentrations of between 0??23 and 0??81 kg 1-1 (with a mean of 0-42 kg 1-1) were measured from the hillslope traps following the debris-flow-producing storm. These concentrations, however, were not unique to the July 16 storm. The materials entrained by the July 16 storm contained a higher proportion of silt- plus clay-sized materials in the debris flows. The difference in materials demonstrates the critical role of the availability of fine-grained wood ash mantling the hillslopes in the runoff-dominated generation of post-wildfire debris flows. The highest sediment-runoff concentrations, again not unique to debris-flow production, were produced from maximum 30 min rainfall intensities greater than 20 mm h-1. Copyright ?? 2001 John Wiley and Sons

  5. El megadeslizamiento del cerro Uritorco, ladera occidental de la Sierra chica de Córdoba

    Directory of Open Access Journals (Sweden)

    Claudio A Carignano

    2014-03-01

    Full Text Available En el extremo norte de la Sierra Chica de Córdoba, sobre el flanco oeste del cerro Uritorco (1.949 m s.n.m., se ha identificado un megadeslizamiento (30°49'55,46"S y 64°29'50,31"O. Los materiales movilizados del frente del escarpe de la falla Sierra Chica, han cubierto parcialmente el granito de Capilla del Monte y los abanicos aluviales pleistocenos del piedemonte. El lóbulo y bloques rotados del deslizamiento conforman un alto topográfico que oficia de límite entre los valles de Punilla (al sur y de Charbonier (al noroeste. Mediante técnicas de procesamiento e interpretación de imágenes satelitales multiespectrales de media (Landsat-ETM y muy alta resolución (GeoEye-1, análisis digital del terreno a partir de modelos de elevación (SRTM y Aster-GDEM y el correspondiente control de campo, se ha delimitado y caracterizado esta megageoforma nunca antes advertida. Dada la elevada sismicidad actual e histórica de la zona y los indicios morfotectónicos que señalan como activas a las fallas Sierra Chica y Pajarillo-Copacabana-Masa, se estima que este deslizamiento posiblemente fue gatillado por un evento sísmico, acontecido en alguna de esas estructuras. Tanto el depósito del deslizamiento como su cicatriz de despegue presentan un significativo grado de erosión hídrica. Por análisis comparativos con otros deslizamientos ya datados y de características similares, situados en el escarpe occidental de las Sierras de San Luis, se le asigna una edad pleistocena medio-tardía. Por su volumen y características (2,1 x109 m³ se estableció que se trata de un megadeslizamiento único en las Sierras de Córdoba y constituye uno de los deslizamientos de mayor tamaño entre los registrados hasta el presente en Argentina.

  6. Hydrothermal treatment of electric arc furnace dust.

    Science.gov (United States)

    Yu, Bing-Sheng; Wang, Yuh-Ruey; Chang, Tien-Chin

    2011-06-15

    In this study, ZnO crystals were fabricated from electric arc furnace dust (EAFD) after alkaline leaching, purification and hydrothermal treatment. The effects of temperature, duration, pH, and solid/liquid ratio on ZnO crystal morphology and size were investigated. Results show a high reaction temperature capable of accelerating the dissolution of ZnO precursor, expediting the growth of 1D ZnO, and increasing the L/D ratio in the temperature range of 100-200°C. ZnO crystals with high purity can also be obtained, using the one-step hydrothermal treatment with a baffle that depends on the different solubility of zincite and franklinite in the hydrothermal conditions.

  7. Characterization of advanced preprocessed materials (Hydrothermal)

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Garold Gresham

    2012-09-01

    The initial hydrothermal treatment parameters did not achieve the proposed objective of this effort; the reduction of intrinsic ash in the corn stover. However, liquid fractions from the 170°C treatments was indicative that some of the elements routinely found in the ash that negatively impact the biochemical conversion processes had been removed. After reviewing other options for facilitating ash removal, sodium-citrate (chelating agent) was included in the hydrothermal treatment process, resulting in a 69% reduction in the physiological ash. These results indicated that chelation –hydrothermal treatment is one possible approach that can be utilized to reduce the overall ash content of feedstock materials and having a positive impact on conversion performance.

  8. Production of biofuels via hydrothermal conversion

    DEFF Research Database (Denmark)

    Biller, Patrick; Ross, Andrew

    2016-01-01

    Hydrothermal processing has evolved as an alternative processing technology for wet biomass and waste materials in recent years. Using hot-compressed water as a reaction medium at temperatures of 200–500°C, materials with increased energy density can be obtained. The technology is particularly......). Each of these hydrothermal routes results in energy densification by removal of oxygen to produce hydrochar (HTC), biocrude (HTL), or syngas (HTG). The process chemistry and reactions in hydrothermal media are described for each process. Suitable feedstocks and their considerations are reviewed...... as the quality of targeted biofuel is a function of feedstock and operating conditions. The quality of hydrochar influences its uses as a solid fuel while biocrude quality affects its use as a liquid fuel and feedstock for upgrading to drop-in replacement fuels, while HTG produces a syngas rich in either H2...

  9. Hydrothermal processing of radioactive combustible waste

    Energy Technology Data Exchange (ETDEWEB)

    Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

    1998-09-01

    Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO{sub 2} and H{sub 2}O, with 30 wt.% H{sub 2}O{sub 2} as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture.

  10. Depolymerization of sulfated polysaccharides under hydrothermal conditions.

    Science.gov (United States)

    Morimoto, Minoru; Takatori, Masaki; Hayashi, Tetsuya; Mori, Daiki; Takashima, Osamu; Yoshida, Shinichi; Sato, Kimihiko; Kawamoto, Hitoshi; Tamura, Jun-ichi; Izawa, Hironori; Ifuku, Shinsuke; Saimoto, Hiroyuki

    2014-01-30

    Fucoidan and chondroitin sulfate, which are well known sulfated polysaccharides, were depolymerized under hydrothermal conditions (120-180°C, 5-60min) as a method for the preparation of sulfated polysaccharides with controlled molecular weights. Fucoidan was easily depolymerized, and the change of the molecular weight values depended on the reaction temperature and time. The degree of sulfation and IR spectra of the depolymerized fucoidan did not change compared with those of untreated fucoidan at reaction temperatures below 140°C. However, fucoidan was partially degraded during depolymerization above 160°C. Nearly the same depolymerization was observed for chondroitin sulfate. These results indicate that hydrothermal treatment is applicable for the depolymerization of sulfated polysaccharides, and that low molecular weight products without desulfation and deformation of the initial glycan structures can be obtained under mild hydrothermal conditions.

  11. Hydrothermally reduced graphene oxide as a supercapacitor

    Science.gov (United States)

    Johra, Fatima Tuz; Jung, Woo-Gwang

    2015-12-01

    The supercapacitance behavior of hydrothermally reduced graphene oxide (RGO) was investigated for the first time. The capacitive behavior of RGO was characterized by using cyclic voltammetry and galvanostatic charge-discharge methods. The specific capacitance of hydrothermally reduced RGO at 1 A/g was 367 F/g in 1 M H2SO4 electrolyte, which was higher than that of RGO synthesized via the hydrazine reduction method. The RGO-modified glassy carbon electrode showed excellent stability. After 1000 cycles, the supercapacitance was 107.7% of that achieved in the 1st cycle, which suggests that RGO has excellent electrochemical stability as a supercapacitor electrode material. The energy density of hydrothermal RGO reached 44.4 W h/kg at a power density of 40 kW/kg.

  12. The BGU/CERN solar hydrothermal reactor

    CERN Document Server

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  13. La «embajada oficiosa» de Indalecio Prieto en México durante la presidencia de Lázaro Cárdenas, 1939-1940

    Directory of Open Access Journals (Sweden)

    Mateos, Abdón

    2003-08-01

    Full Text Available The author tries to set Indalecio Prieto’s mission in Cárdenas’ Mexico within its political context, emphasizing the background of the relationship between the Spanish republican socialists and the Mexican leftist nationalists and its development from the 1920’s onwards. The present monograph is an account of the JARE’s management and of President L. Cárdenas’ policy towards the Spanish republican refugees until the beginning of Ávila Camacho’s presidency

    El autor contextualiza la misión de Indalecio Prieto en el México cardenista, destacando los antecedentes de las relaciones entre los republicanos-socialistas españoles y la izquierda nacionalista mexicana establecidas desde los años veinte. La monografía analiza la gestión de la JARE y la política de Lázaro Cárdenas hacia los refugiados republicanos españoles hasta el comienzo de la presidencia de Manuel Ávila Camacho.

  14. El sistema de yacimientos de mamíferos miocenos del Cerro de los Batallones, Cuenca de Madrid: estado actual y perspectivas

    NARCIS (Netherlands)

    Morales, J.; Pozo, M.; Silva, P.G.; Domingo, M.S.; López-Antoñanzas, R.; Álvarez Sierra, A.; Antón, M.; Martín Escorza, C.; Quiralte, V.; Salesa, M.J.; Sánchez, I.M.; Azanza, B.; Calvo, J.P.; Carrasco, P.; García-Paredes, I.; Knoll, F.; Hernández Fernández, M.; Hoek Ostende, van den L.W.; Merino, L.; Meulen, van der A.J.; Montoya, P.; Peigné, S.; Peláez-Campomanes, P.; Sánchez-Marco, A.; Turner, A.; Abella, J.; Alcalde, G.M.; Andrés, M.; DeMiguel, D.; Cantalapiedra, J.L.; Fraile, S.; García Yelo, B.A.; Gómez Cano, A.R.; López Guerrero, P.; Oliver Pérez, A.; Siliceo, G.

    2008-01-01

    The Cerro de los Batallones (Los Batallones Butte) is located in the central-northern area of the Madrid Basin, central Spain. Nine vertebrates localities containing a large variety of mammals of Upper Vallesian Age (Late Miocene) have been found associated with the sediments forming the butte. From

  15. El frente de corrimiento andino al nivel de los cerros Penitentes y Visera (alta Cordillera de Mendoza: aspectos cronológicos y cartográficos

    Directory of Open Access Journals (Sweden)

    Jean-Claude Vicente

    2009-10-01

    Full Text Available El hallazgo de una iportante fauna de invertebrados marinos del Tithoniano superior a espaldas del cerro Penitentes en la secuencia carbonática basal de la primera escama del frente de corrimiento andino, confirma la lógica tectónica de un despegue de esta unidad a nivel del Yeso Principal y lleva a invalidar ciertas correlaciones litoestratigráficas y bosquejos paleogeográficos asignados a la Formación La Manga. Por otro lado, el análisis de algunos perfiles claves en torno al cerro Penitentes entre la quebrada Vargas y el cerro Visera permite presentar una reinterpretación tectónica del sector. Esta se sustenta en el reconocimiento y la diferenciación de las unidades terciarias básicas representadas por los Conglomerados Penitentes (Mioceno inferior y los Aglomerados Santa María (Mioceno superior en una relación muy similar a la descrita anteriormente al norte de Puente del Inca. El estudio permite seguir las interferencias, en un contexto polifásico, entre las reactivaciones del corrimiento Penitentes de piel fina y un cabalgamiento frontal de piel gruesa que repite la secuencia terciaria. La discordancia entre las secuencias terciarias y el emplazamiento de una klippe de Malm sobre los Conglomerados Penitentes del sinclinal del cerro Visera, conduce a otorgar cierta importancia a la fase del final del Mioceno inferior.

  16. The chemistry of hydrothermal magnetite: a review

    Science.gov (United States)

    Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

    2014-01-01

    Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

  17. Los granitos peraluminosos de las Sierras de Vinquis, Cerro Negro y Zapata (Sierras Pampeanas, provincia de Catamarca, Argentina

    Directory of Open Access Journals (Sweden)

    Medina, M. E.

    1992-12-01

    Full Text Available The studied plutons are close to several batholiths of this region, as Sierra de Mazán and other, but with some mineralogical peculiarities. The magmatic cordierite, common in proximate places, is scarce, as sillimanite, while the andalusite is very rare, with few tourmaline. Fluorite and allanite are also typical accasories only in the granites of the Sierra de Zapata. All plutons are peraluminous of potassic tendency, with cortical affinity.The interpretation of the geochemical values distinguishes between granites of different maturity, emplaced under a predominant influence of active margin for Cerro Negro and Vinquis, while the batholith of Zapata has, below these concepts, a marked feature of within plate.The mineralogical associations suggest that the granites of Cerro Negro and Vinquis were emplaced to pressures of 2 kb or less and temperature of 650º C, while the granites of Zapata had done under conditions of lesser pressure, between 1.5 and 2.0 kb and lower temperature, 600-650º C.A grandes rasgos, los plutones estudiados tienen semejanzas con otros del entorno regional, tal como los de la Sierra de Mazán, pero con peculiaridades mineralógicas. La cordierita magmática, que en lugares próximos es muy abundante, es aquí escasa, al igual que la sillimanita, mientras que la andalucita es muy rara y la turmalina poco frecuente. La fluorita y allanita son accesorios comunes y de cierta abundancia sólo en los granitos de la Sierra de Zapata.Todos los plutones son peralumínicos y de tendencia potásica, con neta afinidad cortical. El estudio estadístico de datos geoquímicos seleccionados, permite diferenciar agrupaciones que tienen un reflejo satisfactorio en los plutones caracterizados, por encima de las variaciones de facies. La interpretación de los valores geoquímicos distingue granitos de desigual madurez, emplazados bajo una influencia predominante de margen activo o intraplaca de características continentales, en

  18. Formation of zirconia polymorphs under hydrothermal conditions

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHl; Erwei(施尔畏); Li; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HUXingfang(胡行方)

    2002-01-01

    Using zirconium oxychloride solution as precursor, monoclinic zirconia crystallites withnarrow distribution of nanosize were obtained in the hydrothermal reaction. However, when thereaction was in weak acidic medium or base medium, whether directly using the colloidal precipi-tate prepared from zirconium salt solutions with base solution as precursor added, or using theprecipitate after filtrating, washing and drying treatments as precursor, the product of the hydro-thermal reaction was the mixture of both monoclinic and tetragonal polymorphs. As the pH of themedium rises, the content of tetragonal phase in the product, the morphologies and size of thecrystallites all change. There are three types of formation mechanisms under hydrothermal condi-tion, which can be called as saturation-precipitation mechanism in homogeneous solution, dissolu-tion-crystallization mechanism and in-situ crystallization mechanism, respectively. The formationmechanism of crystallites varies with different hydrothermal conditions, such as the states of theprecursor and the pH of the medium, which lead to changes in the phases, morphologies andsizes of the resulting crystallites.

  19. Anhydrite precipitation in seafloor hydrothermal systems

    Science.gov (United States)

    Theissen-Krah, Sonja; Rüpke, Lars H.

    2016-04-01

    The composition and metal concentration of hydrothermal fluids venting at the seafloor is strongly temperature-dependent and fluids above 300°C are required to transport metals to the seafloor (Hannington et al. 2010). Ore-forming hydrothermal systems and high temperature vents in general are often associated with faults and fracture zones, i.e. zones of enhanced permeabilities that act as channels for the uprising hydrothermal fluid (Heinrich & Candela, 2014). Previous numerical models (Jupp and Schultz, 2000; Andersen et al. 2015) however have shown that high permeabilities tend to decrease fluid flow temperatures due to mixing with cold seawater and the resulting high fluid fluxes that lead to short residence times of the fluid near the heat source. A possible mechanism to reduce the permeability and thereby to focus high temperature fluid flow are mineral precipitation reactions that clog the pore space. Anhydrite for example precipitates from seawater if it is heated to temperatures above ~150°C or due to mixing of seawater with hydrothermal fluids that usually have high Calcium concentrations. We have implemented anhydrite reactions (precipitation and dissolution) in our finite element numerical models of hydrothermal circulation. The initial results show that the precipitation of anhydrite efficiently alters the permeability field, which affects the hydrothermal flow field as well as the resulting vent temperatures. C. Andersen et al. (2015), Fault geometry and permeability contrast control vent temperatures at the Logatchev 1 hydrothermal field, Mid-Atlantic Ridge, Geology, 43(1), 51-54. M. D. Hannington et al. (2010), Modern Sea-Floor Massive Sulfides and Base Metal Resources: Toward an Estimate of Global Sea-Floor Massive Sulfide Potential, in The Challenge of Finding New Mineral Resources: Global Metallogeny, Innovative Exploration, and New Discoveries, edited by R. J. Goldfarb, E. E. Marsh and T. Monecke, pp. 317-338, Society of Economic Geologists

  20. The aggressiveness of the geothermal steam controlled; La agresividad del vapor geotermico controlada

    Energy Technology Data Exchange (ETDEWEB)

    Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1989-12-31

    The first two units of Cerro Prieto have generated electric energy since 1973; in 1988 completed 15 years of continuous operation, without corrosion problems in the turbines in spite of the utilization of geothermal steam. The experience and the good results obtained during the first years of operation of these two units of 37.5 MW each, were of great help for the Cerro Prieto extension, having as of this date an installed capacity of 620 MW. [Espanol] Las dos primeras unidades de Cerro Prieto han generado energia electrica desde 1973; cumplieron 15 anos de operacion continua en 1988, sin problemas de corrosion en las turbinas a pesar del uso de vapor geotermico. La experiencia y los buenos resultados obtenidos durante los primeros anos de operacion de estas dos unidades de 37.5 MW cada una fueron de gran apoyo para la aplicacion de Cerro Prieto, teniendose a la fecha 620 MW de capacidad instalada.

  1. Voltammetric Investigation Of Hydrothermal Iron Speciation

    Directory of Open Access Journals (Sweden)

    Charlotte eKleint

    2016-05-01

    Full Text Available Hydrothermal vent fluids are highly enriched in iron (Fe compared to ambient seawater, and organic ligands may play a role in facilitating the transport of some hydrothermal Fe into the open ocean. This is important since Fe is a limiting micronutrient for primary production in large parts of the world`s surface ocean. We have investigated the concentration and speciation of Fe in several vent fluid and plume samples from the Nifonea vent field, Coriolis Troughs, New Hebrides Island Arc, South Pacific Ocean using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV with salicylaldoxime (SA as the artificial ligand. Our results for total dissolved Fe (dFe in the buoyant hydrothermal plume samples showed concentrations up to 3.86 µM dFe with only a small fraction between 1.1% and 11.8% being chemically labile. Iron binding ligand concentrations ([L] were found in µM level with strong conditional stability constants up to log K[L],Fe3+ of 22.9. Within the non-buoyant hydrothermal plume above the Nifonea vent field, up to 84.7% of the available Fe is chemically labile and [L] concentrations up to 97 nM were measured. [L] was consistently in excess of Felab, indicating that all available Fe is being complexed, which in combination with high Felab values in the non-buoyant plume, signifies that a high fraction of hydrothermal dFe is potentially being transported away from the plume into the surrounding waters, contributing to the global oceanic Fe budget.

  2. Hydrothermal systems in small ocean planets.

    Science.gov (United States)

    Vance, Steve; Harnmeijer, Jelte; Kimura, Jun; Hussmann, Hauke; Demartin, Brian; Brown, J Michael

    2007-12-01

    We examine means for driving hydrothermal activity in extraterrestrial oceans on planets and satellites of less than one Earth mass, with implications for sustaining a low level of biological activity over geological timescales. Assuming ocean planets have olivine-dominated lithospheres, a model for cooling-induced thermal cracking shows how variation in planet size and internal thermal energy may drive variation in the dominant type of hydrothermal system-for example, high or low temperature system or chemically driven system. As radiogenic heating diminishes over time, progressive exposure of new rock continues to the current epoch. Where fluid-rock interactions propagate slowly into a deep brittle layer, thermal energy from serpentinization may be the primary cause of hydrothermal activity in small ocean planets. We show that the time-varying hydrostatic head of a tidally forced ice shell may drive hydrothermal fluid flow through the seafloor, which can generate moderate but potentially important heat through viscous interaction with the matrix of porous seafloor rock. Considering all presently known potential ocean planets-Mars, a number of icy satellites, Pluto, and other trans-neptunian objects-and applying Earth-like material properties and cooling rates, we find depths of circulation are more than an order of magnitude greater than in Earth. In Europa and Enceladus, tidal flexing may drive hydrothermal circulation and, in Europa, may generate heat on the same order as present-day radiogenic heat flux at Earth's surface. In all objects, progressive serpentinization generates heat on a globally averaged basis at a fraction of a percent of present-day radiogenic heating and hydrogen is produced at rates between 10(9) and 10(10) molecules cm(2) s(1).

  3. Minería, conflicto y mediadores locales: Minera San Xavier en Cerro de San Pedro, México Mineira, conflito e mediadores locais: Minera San Xavier em Cerro de San Pedro Mining, conflict and local brokers: Minera San Xavier in Cerro de San Pedro

    Directory of Open Access Journals (Sweden)

    Hernán Horacio Schiaffini

    2011-12-01

    Full Text Available Este trabajo indaga en las instancias de mediación que intervienen en la articulación de procesos económicos de gran escala y su puesta en práctica local. Basándonos en el conflicto que se produjo en el Municipio de Cerro de San Pedro (San Luis Potosí, México entre la empresa Minera San Xavier y el Frente Amplio Opositor (FAO a la misma, aplicamos el método etnográfico con el objetivo de describir las estructuras locales de mediación política y analizar sus prácticas y racionalidad. Intentamos demostrar así la importancia de los factores políticos locales en las vinculaciones entre estado, empresa y población.Este trabalho indaga nas instâncias de mediação que intervêm em processos econômicos de grande escala e sua posta em prática local. Baseando-nos no conflito no Cerro de San Pedro (San Luis Potosí, México entre a empresa Minera San Xavier e a Frente Amplio Opositor (FAO aplicamos o método etnográfico pra descrever as estruturas de mediação política locais e analisar suas práticas e racionalidade. Tenta-se demonstrar assim a importância dos fatores políticos locais nas vinculações entre estado, empresa e população.This paper investigates in instances of mediation involved in large-scale economic processes and local implementation. Analyzing the conflict in Cerro de San Pedro (San Luis Potosí, México among San Xavier mining company and the Frente Amplio Opositor (FAO, it applies an ethnographic approach to describe the local structures of political mediation and its practices and rationality. The work shows the relevance of local factors in the relationships between State, company and people.

  4. Notes on the ecology of Phyllodactylus reissi (Phyllodactylidae: Sauria in Parque Nacional Cerros de Amotape (Tumbes, Peru

    Directory of Open Access Journals (Sweden)

    Juan Carlos Jordán Arizmendi

    2012-02-01

    Full Text Available Some basics aspects on the ecology of the nocturnal gecko Phyllodactylus reissi from Parque Nacional Cerros de Amotape (Tumbes, Peru are described. This species used rock boulders (57,4% and trees (31,9% as microhabitats primarily, exhibiting a nocturnal activity pattern, with a peak between 2100-2200 hours, remaining active until midnight. Body temperature (mean 24,4 ºC was correlated with both air and substrate temperature, with the last variable affecting in higher degree (47% the body temperature of this species. The slightly high body temperature of Phyllodactylus reissi, compared to other Phyllodactylus geckos, could be related to nocturnal microhabitat use and diurnal retreat site selection. More studies on lizard ecology from this endangered ecosystem are needed.

  5. Estudio de la líqueno flora encontrada en el Cerro de Quininí, Tibacuy, Cundinamarca

    Directory of Open Access Journals (Sweden)

    Hormaza Francisco

    2000-12-01

    Full Text Available

    Se realizó un muestreo de la liquen o flora del cerro de Quininí, Tibacuy, Cundinamarca para estudiar las características morfológicas externas de los géneros de líquenes encontrados en el. A su vez se hizo la revisión bibliográfica acerca de dichos géneros, datando así la riqueza de líquenes en la zona con 8 géneros en total y con respecto al papel de bioindicadores se mostró el grado de intervención para el lugar.

  6. Burning down the brewery: Establishing and evacuating an ancient imperial colony at Cerro Baúl, Peru

    Science.gov (United States)

    Moseley, Michael E.; Nash, Donna J.; Williams, Patrick Ryan; deFrance, Susan D.; Miranda, Ana; Ruales, Mario

    2005-01-01

    Before the Inca reigned, two empires held sway over the central Andes from anno Domini 600 to 1000: the Wari empire to the north ruled much of Peru, and Tiwanaku to the south reigned in Bolivia. Face-to-face contact came when both colonized the Moquegua Valley sierra in southern Peru. The state-sponsored Wari incursion, described here, entailed large-scale agrarian reclamation to sustain the occupation of two hills and the adjacent high mesa of Cerro Baúl. Monumental buildings were erected atop the mesa to serve an embassy-like delegation of nobles and attendant personnel that endured for centuries. Final evacuation of the Baúl enclave was accompanied by elaborate ceremonies with brewing, drinking, feasting, vessel smashing, and building burning. PMID:16293691

  7. IMPACT OF ADDITIONALS CONTAMINANTS DUE TO ACID MINE DRAINAGE IN TRIBUTARIES OF THE PILCOMAYO RIVER FROM CERRO RICO, POTOSÍ, BOLIVIA

    Directory of Open Access Journals (Sweden)

    William H.J. Strosnider

    2014-09-01

    Full Text Available Intensive mining and processing of the polymetallic sulfide ore body of Cerro Rico de Potosí (Bolivia has occurred since 1545. To further investigate acid mine drainage (AMD discharges and their link to downstream contamination, data were gathered during two sampling events during the most extreme periods of the dry and wet seasons of one year. Concentrations of Ag, B, Ba, Mo, Sb, Se, Sn and V in AMD and receiving streams were greater than Bolivian discharge limits and receiving water body guidelines as well as international agricultural use standards. High concentrations of rare earth metals have been documented in this area. Results indicate that contamination from mining has a larger scope than previously thought and underscore the importance of remediation.

  8. The ash deposits of the 4200 BP Cerro Blanco eruption: the largest Holocene eruption of the Central Andes

    Science.gov (United States)

    Fernandez-Turiel, Jose-Luis; Saavedra, Julio; Perez-Torrado, Francisco-Jose; Rodriguez-Gonzalez, Alejandro; Carracedo, Juan-Carlos; Lobo, Agustin; Rejas, Marta; Gallardo, Juan-Fernando; Osterrieth, Margarita; Carrizo, Julieta; Esteban, Graciela; Martinez, Luis-Dante; Gil, Raul-Andres; Ratto, Norma; Baez, Walter

    2015-04-01

    We present new data about a major eruption -spreading approx. 110 km3 ashes over 440.000 km2- long thought to have occurred around 4200 years ago in the Cerro Blanco Volcanic Complex (CBVC) in the Central Andes of NW Argentina (Southern Puna, 26°45' S, 67°45' W). This eruption may be the biggest during the past five millennia in the Central Volcanic Zone of the Andes, and possibly one of the largest Holocene eruptions in the world. Discrimination and correlation of pyroclastic deposits of this eruption of Cerro Blanco was conducted comparing samples of proximal (domes, pyroclastic flow and fall deposits) with distal ash fall deposits (up to 400 km from de vent). They have been characterized using optical and electron microscopy (SEM), X-ray diffraction, particle-size distribution by laser diffraction and electron microprobe and HR-ICP-MS with laser ablation for major and trace element composition of glass, feldspars and biotite. New and published 14C ages were calibrated using Bayesian statistics. An one-at-a-time inversion method was used to reconstruct the eruption conditions using the Tephra2 code (Bonadonna et al. 2010, https://vhub.org/resources/tephra2). This method allowed setting the main features of the eruption that explains the field observations in terms of thickness and grain size distributions of the ash fall deposit. The main arguments that justify the correlation are four: 1) Compositional coincidence for glass, feldspars, and biotite in proximal and distal materials; 2) Stratigraphic and geomorphological relationships, including structure and thickness variation of the distal deposits; 3) Geochronological consistency, matching proximal and distal ages; and 4) Geographical distribution of correlated outcrops in relation to the eruption centre at the coordinates of Cerro Blanco. With a magnitude of 7.0 and a volcanic explosivity index or VEI 7, this eruption of ~4200 BP at Cerro Blanco is the largest in the last five millennia known in the Central

  9. Una fosa-vertedero de época vettona en el Cerro de la Mesa (Alcolea de Tajo, Toledo

    Directory of Open Access Journals (Sweden)

    Chapa Brunet, Teresa

    2013-06-01

    Full Text Available The existence of pits filled with earth, ashes, pottery fragments and fauna, usually known as ash pits, rubbish pits or dumps, has been recognized on many Second Iron Age settlements of the Spanish Northern Plateau, generally linked with Vaccean and Vettonian groups. However, its distribution should be extended to the west of the Southern Plateau and eastern Extremadura, as evidenced by the example of the Cerro de la Mesa village and indications coming from other western sites. We offer here a detailed study of part of a rubbish pit where certain domestic remains were withdrawn in connection with a new project of urbanisation of the Vettonian village held on the transition from the 3rd to the 2nd centuries BC.La existencia de fosas rellenas con tierra, cenizas, fragmentos cerámicos y fauna denominadas genéricamente como cenizales, basureros o vertederos, es un hecho bien conocido en la Meseta Norte durante la Segunda Edad del Hierro, vinculándose con los grupos Vacceos y Vettones. Sin embargo, su distribución debe ampliarse al occidente de la Meseta Sur y oriente extremeño, como se evidencia tanto en el Cerro de la Mesa como a través de indicios documentados en otros yacimientos más occidentales. Se presenta aquí un detallado estudio de un sector de la fosa que actuó como vertedero para la retirada de ciertos restos domésticos con ocasión de la reurbanización en profundidad del poblado vettón que tuvo lugar en la transición del siglo III al II a.C.

  10. Constraining the Paleogene of South America: Magnetostratigraphy and paleoclimate proxy records from Cerro Bayo (Provincia de Salta, Argentina)

    Science.gov (United States)

    Hyland, E.; Cotton, J. M.; Sheldon, N. D.

    2012-12-01

    Records of rapid climatic and ecological shifts in the past are crucial for understanding global systems and for predicting future impacts of climate change. Transient and broad scale hyperthermal events during the Paleogene, such as the Paleocene-Eocene Thermal Maximum (PETM) and Early Eocene Climatic Optimum (EECO), have been studied extensively through both marine records and a significant terrestrial record from North America. Despite this, little evidence exists from the climatic and ecological histories of other major landmasses, which limits the effectiveness of global climate response predictions. Here we present an integrated paleoenvironmental reconstruction of the early Paleogene from a site in central South America (Cerro Bayo, Argentina), including a new magnetostratigraphic age model, pedological and sedimentological interpretation, whole rock geochemical climate proxies, isotopic environmental proxies, and microfloral assemblages. Cerro Bayo is a 235-meter terrestrial section that exposes the Tunal, Mealla, and Maiz Gordo Formations, and based on magnetostratigraphic interpolation spans roughly 58—50 Mya, including both the PETM and EECO events. These formations are composed primarily of reddish sandstone and siltstone, much of which exhibits features characteristic of a moderate degree of pedogenesis (i.e., Inceptisols and Alfisols). High-resolution climate proxies derived from paleosol geochemical compositions highlight rapid increases in mean annual temperature (>5°C) and precipitation (>300 mm yr-1) during the PETM, as well as more gradual increasing temperature and precipitation trends leading up to the EECO. Carbon isotope stratigraphy through the section also indicates a sizable negative excursion (~4‰) during the PETM, and generally positive isotopic trends during the early Eocene. Phytolith biostratigraphy also details changes in local vegetation composition during climatic events that corresponds to similar patterns seen in terrestrial

  11. Microestructuras de deformación en rocas granulíticas, Cerro La Crespa, Tandilia, Provincia de Buenos Aires

    Directory of Open Access Journals (Sweden)

    Lucrecia Jorgensen

    2008-06-01

    Full Text Available El cerro La Crespa, localizado un kilómetro al sur de la megacizalla de Azul, integra las sierras de Azul, las cuales componen parte del Sistema de Tandilia. El presente trabajo trata sobre el estudio petrográfico-microestructural, donde se determina la composición modal y arreglos texturales a escala de grano y una primera caracterización geoquímica de rocas granulíticas aflorantes en el sector NO del cerro La Crespa. A partir de tales análisis, se intenta dilucidar los mecanismos de deformación actuantes y las condiciones metamórficas alcanzadas. Se reconocen rocas con texturas granoblásticas de composición básica e intermedia. Dichas rocas evidencian deformación frágil-dúctil heterogénea, con desarrollo de fábricas miloníticas, acaecida luego de que el evento metamórfico alcanzara su máximo desarrollo. Las texturas primitivas y la asociación de minerales anhidros presentes indicarían que dichas rocas podrían ser consideradas dentro de la serie de las granulitas. En las milonitas se aprecian significativos cambios mineralógicos, ya que al aumentar la deformación se incrementa la proporción de minerales hidratados y simultáneamente se reduce la cantidad de minerales anhidros. Estas modificaciones hacen suponer que la deformación actuó bajo condiciones metamórficas medias a altas, en facies de anfibolita superior-granulita inferior. Esta interpretación está apoyada por los mecanismos de deformación observados, a saber, recristalización dinámica de feldespatos, piroxenos, anfíboles, biotita y cuarzo; elongación de piroxenos y desarrollo de microboudinage.

  12. Volcanismo máfico terciario de la Puna jujeña, los Cerros Negros de Jama.

    Directory of Open Access Journals (Sweden)

    Caffe, Pablo, J.

    2011-12-01

    Full Text Available Tertiary mafic volcanism of the Jujuy Puna, the Cerros Negros de Jama. The Cerros Negros de Jama (23°29’ S – 66°56’ W monogenetic volcanoes belong to a group of eruptive centers that are representative of the most mafic magmatism in the northern Puna during the Cenozoic. They comprise scoria cones and associated lava flows erupted during coeval strombolian and effusive volcanic activity.Aphyric to microporphyritic skeletal textures and microphenocryst assemblages dominated by olivine and/or orthopyroxene suggest inexistent or short residence times in supracrustal magma chambers, as well as magma temperatures higher than 1000º C and near to water saturation conditions. The frequent occurrence of magmatic quartz xenocrysts with different degrees of reaction suggests assimilation of silicic magmas/igneous rocks under variable P-T conditions. A combination of large ascent rates and strong turbulence, together with an overheating of the magmas would have been crucial for this in-route contamination process.The Jama volcanic rocks are basaltic andesites and andesites to trachyandesites which belong to the high-K calcalkaline series. The observed geochemical signature is typical of continental arc magmas, showing negative anomalies of Nb, Ta and P, La/Ta > 30 and Ba/Nb > 25. Two main groups of rocks with different evolution patterns can be distinguished from major and trace element diagrams. Different concentrations of some elements at intermediate degrees of evolution point to variable degrees of incompatibility for them, which in turn may have been caused by magma evolution at different depths from the same or different primary magmas.

  13. Los marsupiales (Mammalia del Mioceno Superior de la Formación Cerro Azul (Provincia de La Pampa, Argentina

    Directory of Open Access Journals (Sweden)

    Visconti, G.

    2000-04-01

    Full Text Available We describe the most complete South American marsupial association of Huayquerian Age (late Miocene. Specimens were recovered from several new localities of central and northern La Pampa province (central Argentina, at levels assignable to Cerro Azul Fm.: Bajo Giuliani, Quehué, Telén, El Guanaco, and Laguna Chillhué. Loessoid sediments studied from this formation are indicative of lacustrine deposits overlaid by eolian levels bearing evidences of pedogenesis. A study of these levels at each one of the new localities led to their correlation in an integrated profile of Cerro Azul Fm. This formation corresponds to «Epecuén Fm.», at least in Salinas Grandes de Hidalgo, and probably also to the upper levels of Arroyo Chasicá Fm. The studied marsupials are representative of almost all major lineages (orders of South American Neogene marsupials. The marmosine didelphid Zygolestes tatei sp. nov. differs from the type species of the genus in its larger size, unreduced third lower premolar, and in the less reduction of the metaconid in the last lower molar. Another marmosine, Thylamys pinei sp. nov., differs from other Marmosini in the twinning of the para- and metaconid in the lower molars, and in the wider talonid of the m4. The Monodelphini marmosines Thylatheridium hudsoni y T. dolgopolae are abundant in several localities of this formation; their study confirms close affinities between this genus and Monodelphis. The didelphines Hyperdidelphys pattersoni and an indeterminate species of Lutreolina are also represented by a few specimens. A mandibular fragment including part of the last molar may represent the oldest record of a Sparassocynidae in central Argentina. The Borhyaenidae and Thylacosmilidae (Sparassodonta are also recorded by a few, fragmentary specimens. Pliolestes venetus sp. nov. (Paucituberculata, Caenolestidae differs from the type species of the genus in its smaller size and in the larger, less displaced metaconid in the

  14. Stress controlled magma-earthquake interaction during unrest at Chiles-Cerro Negro Volcanoes (Ecuador-Colombian border)

    Science.gov (United States)

    Ebmeier, S. K.; Elliott, J. R.; Nocquet, J. M.; Biggs, J.; Mothes, P. A.; Lundgren, P.; Samsonov, S. V.; Jarrin, P.; Yepez, M.; Aguaiza, S.

    2015-12-01

    The movement of fluids beneath a volcano can cause deformation, and therefore changes to the subsurface stress field that manifest in swarms of low magnitude (Chiles-Cerro Negro volcanoes on the Ecuador-Colombian border. These volcanoes were previously considered to be historically inactive, but between 2013 and early 2015 there were three episodes of unrest characterised by VT swarms of increasing energy and duration. GPS measurements at two stations near Volcán Chiles show inflation over a time period of approximately twenty days prior to the 20th October, consistent with the intrusion of magma at half space depths >13 km. This inflation took place during a swarm of VT seismicity with thousands of low magnitude events per day and culminated in a M 5.6 earthquake on the 20th October, when inflation abruptly ceased. We measure coseismic displacements from the M 5.6 earthquake with data from three independent InSAR platforms and find that they are consistent with shallow slip of 1.2 m on an oblique reverse fault. This fault plane would have experienced positive Coulomb stress changes from some of the range of potential sources consistent with the inflation. Magmatic intrusion could therefore have contributed to the loading on the fault directly through stress changes caused by pressurisation, and indirectly through the decrease in effective friction coefficient due to elevated pore fluid pressure. The cessation of inflation immediately after the moderate earthquake suggests a link between the two events. We expect slip on the fault plane identified from the InSAR data to have resulted in compression in the shallow crust south of Volcán Chiles, above the source that had previously been inflating. This would have inhibited further ascent of magma. The Chiles-Cerro Nego unrest provides rare observations of interaction between magmatic intrusion and a moderate earthquake during volcanic unrest.

  15. Minería, conflicto y mediadores locales: Minera San Xavier en Cerro de San Pedro, México Mineira, conflito e mediadores locais: Minera San Xavier em Cerro de San Pedro Mining, conflict and local brokers: Minera San Xavier in Cerro de San Pedro

    OpenAIRE

    Hernán Horacio Schiaffini

    2011-01-01

    Este trabajo indaga en las instancias de mediación que intervienen en la articulación de procesos económicos de gran escala y su puesta en práctica local. Basándonos en el conflicto que se produjo en el Municipio de Cerro de San Pedro (San Luis Potosí, México) entre la empresa Minera San Xavier y el Frente Amplio Opositor (FAO) a la misma, aplicamos el método etnográfico con el objetivo de describir las estructuras locales de mediación política y analizar sus prácticas y racionalidad. Intenta...

  16. Evolving patterns of the fluids within the TAG hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The mixing of seawater/hydrothermal fluid within the large seafloor hydrothermal sulfide deposits plays a key role in the formation processes of the sulfide deposits.Some issues attract considerable attentions in the study of seafloor hydrothermal system in recent years,such as the relationships among different types of vent fluids,the characteristics of chemical compositions and mineral assemblages of the hydrothermal deposits and their governing factors.Combined with the measured data of hydrothermal fluid in the TAG field,the thermodynamic model of mixing processes of the heated seawater at different temperatures and the hydrothermal fluid is calculated to understand the precipitation mechanism of anhydrite and the genetic relationships between the black and white smoker fluids within the TAG mound.The results indicate that the heating of seawater and the mixing of hydrothermal fluid/seawater are largely responsible for anhydrite precipitation and the temperature of the heated seawater is not higher than 150 ℃ and the temperature of the end-member hydrothermal fluid is not lower than 400℃.Based on the simulated results,the evolving patterns of fluids within the TAG deposit are discussed.The mixed fluid of the end-member hydrothermal fluid and the seawater heated by wall rock undergoes conductive cooling during upflowing within the deposit and forms "White Smoker" eventually.In addition,the end-member hydrothermal fluid without mixed with seawater,but undergoing conductive cooling,vents out of the deposit and forms "Black Smoker".

  17. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  18. 230Th/238U dating of hydrothermal sulfides from Duanqiao hydrothermal field, Southwest Indian Ridge

    Science.gov (United States)

    Yang, Weifang; Tao, Chunhui; Li, Huaiming; Liang, Jin; Liao, Shili; Long, Jiangping; Ma, Zhibang; Wang, Lisheng

    2016-11-01

    Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones at the central volcano, at 50°28'E in the ultraslow-spreading Southwest Indian Ridge (SWIR). Twenty-eight subsamples from a relict chimney and massive sulfides were dated using the 230Th/238U method. Four main episodes of hydrothermal activity were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. The periodic character of hydrothermal activity may be related to the heat source provided by the interaction of local magmatism and tectonism. The estimated mean growth rate of the sulfide chimney is Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. The preliminarily estimated reserves of sulfide ores of Duanqiao are approximately 0.5-2.9 million tons.

  19. The hydrothermal reaction kinetics of aspartic acid

    Science.gov (United States)

    Cox, Jenny S.; Seward, Terry M.

    2007-02-01

    Experimental data on the hydrothermal reaction kinetics of aspartic acid were acquired using a custom-built spectrophotometric reaction cell which permits in situ observation under hydrothermal conditions. The results of this study indicate that the reaction kinetics of dilute aspartic acid solutions are significantly different depending on the presence or absence of catalytic surfaces such as standard metal alloys. The spectroscopic data presented here represent the first direct observations, in situ and in real time, of an amino acid reacting in a hydrothermal solution. Quantitative kinetic information, including rate constants, concentration versus time profiles, and calculations of the individual component spectra, was obtained from the data using a chemometric approach based on factor analysis/principle component analysis which treats the rate expressions simultaneously as a system of differential algebraic equations (DAE) of index 1. Identification of the products was confirmed where possible by high pressure anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). The reaction kinetics of aspartic acid under hydrothermal conditions was observed to be highly complex, in contrast to previous studies which indicated almost exclusively deamination. At lower temperatures (120-170 °C), several different reaction pathways were observed, including decarboxylation and polymerization, and the catalytic effects of reactor surfaces on the aspartic acid system were clearly demonstrated. At higher temperatures (above 170 °C), aspartic acid exhibited highly complex behaviour, with evidence indicating that it can simultaneously dimerize and cyclize, deaminate (by up to two pathways), and decarboxylate (by up to two pathways). These higher temperature kinetics were not fully resolvable in a quantitative manner due to the complexity of the system and the constraints of UV spectroscopy. The results of this study provide strong evidence that the reaction

  20. Hydrothermal synthesis of xonotlite from carbide slag

    Institute of Scientific and Technical Information of China (English)

    Jianxin Cao; Fei Liu; Qian Lin; Yu Zhang

    2008-01-01

    Carbide slag was used as the calcareous materials for the first time to prepare xonotlite via dynamic hydrothermal synthesis.The effects of influential factors including different calcination temperatures,pretreatment methods of the carbide slag and process param-eters of hydrothermal synthesis on the microstructure and morphology of xonotlite were explored using XRD and SEM techniques.The results indicate that the carbide slag after proper calcination could be used to prepare pure xonotlite;and different calcination tern-peratures have little effect on the crystallinity of synthesized xonotlitc,but have great impact on the morphology of secondary particles.The different pretreatment methods of the carbide slag pose great impact on the crystallinity and morphology of secondary particles of xonotlite.Xonotlite was also synthesized from pure CaO under the salne experimental conditions as that prepared from calcined carbide slag for comparison.Little amount of impurities in carbide slag has no effect on the mechanism of hydrothermal synthesizing xonotlite from carbide slag.

  1. Hydrothermal synthesis of zeolites from natural stellerite

    Institute of Scientific and Technical Information of China (English)

    李酽; 汪信; 董元彩; 朱俊武

    2002-01-01

    Y and P zeolites were synthesized hydrothermally from natural stellerite under different conditions and were characterized via XRD and FT-IR.The results show that the higher crystallinity of Y zeolite can be obtained in hydrothermal system with low alkalinity,low Ca2+/Na+ ratio,and high SiO2/Al2O3 ratio.The lattice space of the samples decreases as crystallization time increases.P Zeolite is prompted under condition of higher alkalinity and higher Ca2+/Na+ ratio.The intensity and number of bands in the range of 400 cm-1~900 cm-1 increases with reaction time.Bands at 680 cm-1,760 cm-1 and 860 cm-1 corresponding to Y zeolite appear during the crystallization stage.Most of these bands shift to higher wavenumbers when SiO2/Al2O3 ratio increases generally.In the hydrothermal system with reverse condition above,bands at 600 cm-1,420 cm-1~470 cm-1 hardly change as the crystallization time increases and the main crystal phase of P zeolite is obtained.

  2. Numerical simulation of magmatic hydrothermal systems

    Science.gov (United States)

    Ingebritsen, S.E.; Geiger, S.; Hurwitz, S.; Driesner, T.

    2010-01-01

    The dynamic behavior of magmatic hydrothermal systems entails coupled and nonlinear multiphase flow, heat and solute transport, and deformation in highly heterogeneous media. Thus, quantitative analysis of these systems depends mainly on numerical solution of coupled partial differential equations and complementary equations of state (EOS). The past 2 decades have seen steady growth of computational power and the development of numerical models that have eliminated or minimized the need for various simplifying assumptions. Considerable heuristic insight has been gained from process-oriented numerical modeling. Recent modeling efforts employing relatively complete EOS and accurate transport calculations have revealed dynamic behavior that was damped by linearized, less accurate models, including fluid property control of hydrothermal plume temperatures and three-dimensional geometries. Other recent modeling results have further elucidated the controlling role of permeability structure and revealed the potential for significant hydrothermally driven deformation. Key areas for future reSearch include incorporation of accurate EOS for the complete H2O-NaCl-CO2 system, more realistic treatment of material heterogeneity in space and time, realistic description of large-scale relative permeability behavior, and intercode benchmarking comparisons. Copyright 2010 by the American Geophysical Union.

  3. Surface roughened zirconia: towards hydrothermal stability.

    Science.gov (United States)

    Camposilvan, Erik; Flamant, Quentin; Anglada, Marc

    2015-07-01

    Surface roughness is needed in several yttria-stabilized zirconia components used in restorative dentistry for osseointegration or adhesion purposes. This can be achieved by different treatments, which may also modify the microstructure of the surface. Among them, sandblasting and chemical etching are widely used, but their effect on hydrothermal aging of zirconia is not fully understood. In the present work, the zirconia long-term stability of rough surfaces prepared by these techniques is analyzed and a method is proposed for preventing hydrothermal aging while maintaining the original surface appearance and mechanical properties. The method involves pressure infiltration of a Cerium salt solution on the roughened surfaces followed by a thermal treatment. The solution, trapped by surface defects and small pores, is decomposed during thermal treatment into Cerium oxide, which is diffused at high temperature, obtaining Ce co-doping in the near-surface region. In addition, the microstructural changes induced in the near-surface by sandblasting or chemical etching are removed by the thermal treatment together with surface defects. No color modification was observed and the final roughness parameters were in the range of existing implants of proved good osseointegration. The aging resistance of Ce co-doped materials was strongly enhanced, showing the absence of aging after artificial degradation, increasing in this way the surface mechanical integrity. The proposed treatment is easily applicable to the current manufacturing procedures of zirconia dental posts, abutments, crowns and dentures, representing a solution to hydrothermal aging in these and other biomedical applications.

  4. Hydrothermal Formation of Calcium Copper Tetrasilicate.

    Science.gov (United States)

    Johnson-McDaniel, Darrah; Comer, Sara; Kolis, Joseph W; Salguero, Tina T

    2015-12-01

    We describe the first hydrothermal synthesis of CaCuSi4 O10 as micron-scale clusters of thin platelets, distinct from morphologies generated under salt-flux or solid-state conditions. The hydrothermal reaction conditions are surprisingly specific: too cold, and instead of CaCuSi4 O10 , a porous calcium copper silicate forms; too hot, and calcium silicate (CaSiO3 ) forms. The precursors also strongly impact the course of the reaction, with the most common side product being sodium copper silicate (Na2 CuSi4 O10 ). Optimized conditions for hydrothermal CaCuSi4 O10 formation from calcium chloride, copper(II) nitrate, sodium silicate, and ammonium hydroxide are 350 °C at 3000 psi for 72 h; at longer reaction times, competitive delamination and exfoliation causes crystal fragmentation. These results illustrate that CaCuSi4 O10 is an even more unique material than previously appreciated.

  5. Microestructuras de deformación en rocas granulíticas, Cerro La Crespa, Tandilia, Provincia de Buenos Aires Deformation microstructures in granulitic rocks, Cerro La Crespa, Tandilia, province of Buenos Aires

    Directory of Open Access Journals (Sweden)

    Lucrecia Jorgensen

    2008-06-01

    Full Text Available El cerro La Crespa, localizado un kilómetro al sur de la megacizalla de Azul, integra las sierras de Azul, las cuales componen parte del Sistema de Tandilia. El presente trabajo trata sobre el estudio petrográfico-microestructural, donde se determina la composición modal y arreglos texturales a escala de grano y una primera caracterización geoquímica de rocas granulíticas aflorantes en el sector NO del cerro La Crespa. A partir de tales análisis, se intenta dilucidar los mecanismos de deformación actuantes y las condiciones metamórficas alcanzadas. Se reconocen rocas con texturas granoblásticas de composición básica e intermedia. Dichas rocas evidencian deformación frágil-dúctil heterogénea, con desarrollo de fábricas miloníticas, acaecida luego de que el evento metamórfico alcanzara su máximo desarrollo. Las texturas primitivas y la asociación de minerales anhidros presentes indicarían que dichas rocas podrían ser consideradas dentro de la serie de las granulitas. En las milonitas se aprecian significativos cambios mineralógicos, ya que al aumentar la deformación se incrementa la proporción de minerales hidratados y simultáneamente se reduce la cantidad de minerales anhidros. Estas modificaciones hacen suponer que la deformación actuó bajo condiciones metamórficas medias a altas, en facies de anfibolita superior-granulita inferior. Esta interpretación está apoyada por los mecanismos de deformación observados, a saber, recristalización dinámica de feldespatos, piroxenos, anfíboles, biotita y cuarzo; elongación de piroxenos y desarrollo de microboudinage.This work deals with a petrographic- microstructural study in order to determine the modal composition and textural arrangement on a grain scale and the first geochemistry characterization of granulitic rocks on the NW of the cerro La Crespa, which is located about 1 km south of the Azul Megashear and forms part of the sierras de Azul in the Tandilia System

  6. Composición, estructura y diversidad del cerro El Águila, Michoacán, México Composition, structure and diversity of the cerro El Águila, Michoacán, Mexico

    Directory of Open Access Journals (Sweden)

    Luis Eduardo Zacarias-Eslava

    2011-09-01

    Full Text Available Se describe la composición, estructura y diversidad de la vegetación presente en el cerro El Águila, Michoacán. Se reconocieron fisonómicamente 5 tipos de vegetación y en cada uno se establecieron 16 parcelas circulares de 400 m² (3.2 ha para censar los individuos leñosos ≥ 10 cm d.a.p., con una parcela anidada de 100 m² (0.8 ha para los individuos entre 2.5 y 9.9 cm d.a.p. El muestreo incluyó 46 especies agrupadas en 33 géneros y 21 familias. Los bosques tropical caducifolio y de Quercus deserticola tuvieron los valores más bajos de altura promedio ( 11 m y área basal (> 40 m²/ha. La diversidad fue mayor en el bosque tropical caducifolio (S=23 y α =5.4 y menor en el de Quercus-Pinus (S= 13 y α= 2.71. En general, los tipos de vegetación mostraron diferentes especies dominantes y una alta diversidad beta. La composición y estructura de estas comunidades puede asociarse a cambios en altitud y a la perturbación por actividades humanas. No obstante, la zona de estudio aún presenta áreas en buen estado de conservación, particularmente los bosques templados hacia las zonas con mayor altitud, por lo que se sugiere que en un futuro cercano sea incluida dentro de alguna categoría de protección estatal.This study describes composition, structure and diversity of vegetation in the Cerro El Águila, Michoacán. Five plant communities were recognized and for each one all woody individuals ≥10 cm DBH were tallied in sixteen 400 m² circular plots, whereas individuals between 2.5 and 9.9 cm DBH were measured in a 100 m² circular sub-plot centered within each larger plot. A total of 46 species, 33 genera and 21 families were recorded. The tropical deciduous forest and Quercus deserticola forest had low values of mean plant height ( 11 m and basal area (> 40 m²/ha. Diversity was greater in the tropical deciduous forest (S= 23 and α= 5.4, respectively and lower in the oak-pine forest (S= 13 and α= 2.71. All communities displayed

  7. Geophysical imaging of shallow degassing in a Yellowstone hydrothermal system

    Science.gov (United States)

    Pasquet, S.; Holbrook, W. S.; Carr, B. J.; Sims, K. W. W.

    2016-12-01

    The Yellowstone Plateau Volcanic Field, which hosts over 10,000 thermal features, is the world's largest active continental hydrothermal system, yet very little is known about the shallow "plumbing" system connecting hydrothermal reservoirs to surface features. Here we present the results of geophysical investigations of shallow hydrothermal degassing in Yellowstone. We measured electrical resistivity, compressional-wave velocity from refraction data, and shear wave velocity from surface-wave analysis to image shallow hydrothermal degassing to depths of 15-30 m. We find that resistivity helps identify fluid pathways and that Poisson's ratio shows good sensitivity to saturation variations, highlighting gas-saturated areas and the local water table. Porosity and saturation predicted from rock physics modeling provide critical insight to estimate the fluid phase separation depth and understand the structure of hydrothermal systems. Finally, our results show that Poisson's ratio can effectively discriminate gas- from water-saturated zones in hydrothermal systems.

  8. Hydrothermal pretreatment of palm oil empty fruit bunch

    Science.gov (United States)

    Simanungkalit, Sabar Pangihutan; Mansur, Dieni; Nurhakim, Boby; Agustin, Astrid; Rinaldi, Nino; Muryanto, Fitriady, Muhammad Ariffudin

    2017-01-01

    Hydrothermal pretreatment methods in 2nd generation bioethanol production more profitable to be developed, since the conventional pretreatment, by using acids or alkalis, is associated with the serious economic and environmental constraints. The current studies investigate hydrothermal pretreatment of palm oil empty fruit bunch (EFB) in a batch tube reactor system with temperature and time range from 160 to 240 C and 15 to 30 min, respectively. The EFB were grinded and separated into 3 different particles sizes i.e. 10 mesh, 18 mesh and 40 mesh, prior to hydrothermal pretreatment. Solid yield and pH of the treated EFB slurries changed over treatment severities. The chemical composition of EFB was greatly affected by the hydrothermal pretreatment especially hemicellulose which decreased at higher severity factor as determined by HPLC. Both partial removal of hemicellulose and migration of lignin during hydrothermal pretreatment caused negatively affect for enzymatic hydrolysis. This studies provided important factors for maximizing hydrothermal pretreatment of EFB.

  9. Cerro Grande Fire Impact to Water Quality and Stream Flow near Los Alamos National Laboratory: Results of Four Years of Monitoring

    Energy Technology Data Exchange (ETDEWEB)

    B.M. Gallaher; R.J. Koch

    2004-09-15

    In May 2000, the Cerro Grande fire burned about 7400 acres of mixed conifer forest on the Los Alamos National Laboratory (LANL), and much of the 10,000 acres of mountainside draining onto LANL was severely burned. The resulting burned landscapes raised concerns of increased storm runoff and transport of contaminants by runoff in the canyons traversing LANL. The first storms after the fire produced runoff peaks that were more than 200 times greater than prefire levels. Total runoff volume for the year 2000 increased 50% over prefire years, despite a decline in total precipitation of 13% below normal and a general decrease in the number of monsoonal thunderstorms. The majority of runoff in 2000 occurred in the canyons at LANL south of Pueblo Canyon (70%), where the highest runoff volume occurred in Water Canyon and the peak discharge occurred in Pajarito Canyon. This report describes the observed effects of the Cerro Grande fire and related environmental impacts to watersheds at and near Los Alamos National Laboratory (LANL) for the first four runoff seasons after the fire, from 2000 through 2003. Spatial and temporal trends in radiological and chemical constituents that were identified as being associated with the Cerro Grande fire and those that were identified as being associated with historic LANL discharges are evaluated with regard to impacts to the Rio Grande and area reservoirs downstream of LANL. The results of environmental sampling performed by LANL, the New Mexico Environment Department (NMED), and U.S. Geological Survey (USGS) after the Cerro Grande fire are included in the evaluation. Effects are described for storm runoff, baseflow, stream sediments, and area regional reservoir sediment.

  10. Pucarilla-Cerro Tipillas volcanic complex: the oldest recognized caldera in the southeastern portion of central volcanic zone of Central Andes?

    Energy Technology Data Exchange (ETDEWEB)

    Guzman, Silvina; Petrinovic, Ivan [CONICET -IBIGEO. Museo de Cs. Naturales, Universidad de Salta, Mendoza 2 (4400), Salta (Argentina)], E-mail: guzmansilvina@gmail.com

    2008-10-01

    We recognize the most eastern and oldest collapse caldera structure in the southern portion of the Central Volcanic Zone of the Andes. A description of Middle-Upper Miocene successions related to explosive- effusive events is presented. The location of this centre close to Cerro Galn Caldera attests a recurrence in the volcanism between 12 and 2 Ma in this portion of the Altiplano - Puna Plateau.

  11. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    Science.gov (United States)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  12. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems.

  13. Evaluación integral del riesgo volcánico del Cerro Machín, Colombia

    Directory of Open Access Journals (Sweden)

    Leonel Vega Mora

    2013-01-01

    Full Text Available El volcán Cerro Machín (VCM se encuentra situado en la Cordillera Central de Colombia. Por la com- posición química, magnitud y extensión de sus erupciones pasadas, se reconoce como un volcán explosivo de gran potencial de daño, cuya actividad futura podría afectar intensamente durante mucho tiempo (meses hasta años una región muy estratégica para la economía del país, que cubre áreas pertenecientes a los departamentos de Tolima, Quindío, Valle del Cauca y Cundinamarca, en las cuales habitan cerca de un millón de personas. En este artículo se muestra la metodología y resultados del estudio de “Evaluación Integral del Riesgo del Cerro Machín – Colombia”, realizado durante 2009 por el Grupo PIGA de Investigación en Política, Información y Gestión Ambiental de la Facultad de Ingeniería de la Universidad Nacional de Colombia, tomando como punto de partida el estudio de “Evaluación de la Amenaza Volcánica Potencial del Cerro Machín” adelantado en el 2002 por el Servicio Geológico Colombiano (SGC. En consecuencia, se genera y ajusta una nueva ecuación para la determinación del riesgo, basada en la valoración de índices de amenaza intrínseca e índices de vulnerabilidad, los primeros en función del grado de intensidad, duración, extensión y acumulación de las amenazas, y los segundos, en función del grado de exposición espacial y temporal de los elementos (sociales, económicos, institucionales y ecosisté- micos y de su capacidad de respuesta intrínseca y extrínseca ante las amenazas. Con estas ecuaciones y mediante el uso de sistemas de información geográfica (SIG, se realiza para cada escenario de análisis considerando la modelación geoespacial del riesgo a nivel de cada pixel cartográfico del área territorial de estudio. En esta modelación se integra toda la informa- ción territorial del área en estudio, lo que permite obtener, de acuerdo con el marco lógico de evaluación preestablecido

  14. Theoretical constraints of physical and chemical properties of hydrothermal fluids on variations in chemolithotrophic microbial communities in seafloor hydrothermal systems

    Science.gov (United States)

    Nakamura, Kentaro; Takai, Ken

    2014-12-01

    In the past few decades, chemosynthetic ecosystems at deep-sea hydrothermal vents have received attention as plausible analogues to the early ecosystems of Earth, as well as to extraterrestrial ecosystems. These ecosystems are sustained by chemical energy obtained from inorganic redox substances (e.g., H2S, CO2, H2, CH4, and O2) in hydrothermal fluids and ambient seawater. The chemical and isotope compositions of the hydrothermal fluid are, in turn, controlled by subseafloor physical and chemical processes, including fluid-rock interactions, phase separation and partitioning of fluids, and precipitation of minerals. We hypothesized that specific physicochemical principles describe the linkages among the living ecosystems, hydrothermal fluids, and geological background in deep-sea hydrothermal systems. We estimated the metabolic energy potentially available for productivity by chemolithotrophic microorganisms at various hydrothermal vent fields. We used a geochemical model based on hydrothermal fluid chemistry data compiled from 89 globally distributed hydrothermal vent sites. The model estimates were compared to the observed variability in extant microbial communities in seafloor hydrothermal environments. Our calculations clearly show that representative chemolithotrophic metabolisms (e.g., thiotrophic, hydrogenotrophic, and methanotrophic) respond differently to geological and geochemical variations in the hydrothermal systems. Nearly all of the deep-sea hydrothermal systems provide abundant energy for organisms with aerobic thiotrophic metabolisms; observed variations in the H2S concentrations among the hydrothermal fluids had little effect on the energetics of thiotrophic metabolism. Thus, these organisms form the base of the chemosynthetic microbial community in global deep-sea hydrothermal environments. In contrast, variations in H2 concentrations in hydrothermal fluids significantly impact organisms with aerobic and anaerobic hydrogenotrophic metabolisms

  15. Heat and mass flux estimation of modern seafloor hydrothermal activity

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; WANG Xingtao; YU Zenghui

    2006-01-01

    Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97.359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4.11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in-situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.

  16. Simple model for fault-charged hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Bodvarsson, G.S.; Miller, C.W.; Benson, S.M.

    1981-06-01

    A two-dimensional transient model of fault-charged hydrothermal systems has been developed. The model can be used to analyze temperature data from fault-charged hydrothermal systems, estimate the recharge rate from the fault, and determine how long the system has been under natural development. The model can also be used for theoretical studies of the development of fault-controlled hydrothermal systems. The model has been tentatively applied to the low-temperature hydrothermal system at Susanville, California. A resonable match was obtained with the observed temperature data, and a hot water recharge rate of 9 x 10{sup -6} m{sup 3}s/m was calculated.

  17. Chemical variations in the Cerro de Mercado (Durango, Mexico) fluorapatite: Assessing the effect of heterogeneity on a geochronologic standard.

    Science.gov (United States)

    Boyce, J. W.; Hodges, K. V.

    2001-12-01

    Despite the lack of an official pronouncement, the fluorapatite of Cerro de Mercado, Durango, Mexico has become the de facto standard for (U-Th)/He geochronology. In addition to being relatively inclusion-free and easily obtained, these crystals are commonly in excess of 5mm in diameter, permitting the removal of the outer skin of the crystal, theoretically eliminating the alpha-ejection correction. However, bulk analyses of the Durango fluorapatite indicate a substantial variation in U and Th concentrations from aliquot to aliquot (167-238 ppm Th; 9.7-12.3 ppm U, [1]). If similar variations were to occur on the sub-grain scale, small fragments of single crystals could contain helium excesses or deficiencies due to alpha-ejection exchange between zones with varying parent element content. We have performed a series of experiments to quantify the intra-grain variation in U and Th, in order to model the effect of this variation on ages determined on Durango fluorapatite. X-ray maps show concentric zonation in U and Th, with similar, but more apparently pronounced zonation in Si and Cl. Preliminary laser-ablation ICPMS data indicate, not surprisingly, that intra-grain variations in U and Th concentrations obtained by analysis of ~35 μ m spots are larger than that which had been previously obtained by bulk analytical techniques (with overall concentrations greater than for bulk analyses). Thus far, analyses yield U concentrations varying from 11 to 16 ppm, and Th concentrations ranging from 220 to 340 ppm. Modeling underway suggests that parent element variations on the order of 50%, such as those observed, and the resulting differential alpha-exchange could lead to several percent error in age, for ~100 μ m fragments. The effect scales inversely with fragment size, with 300 μ m fragments (roughly the size of a large, single grain analysis) having only ~1% error. This may offer an explanation for the previously observed inability to reproduce ages for the Durango

  18. Geographic Information System (GIS) Emergency Support for the May 2000 Cerro Grande Wildfire, Los Alamos, New Mexico, USA

    Energy Technology Data Exchange (ETDEWEB)

    C.R.Mynard; G.N.Keating; P.M.Rich; D.R. Bleakly

    2003-05-01

    In May 2000 the Cerro Grande wildfire swept through Los Alamos, New Mexico, burning approximately 17,400 ha (43,000 acres) and causing evacuation of Los Alamos National Laboratory (LANL) and the communities of Los Alamos and White Rock. An integral part of emergency response during the fire was the use of geographic information system (GIS) technology, which continues to be used in support of post-fire restoration and environmental monitoring. During the fire Laboratory GIS staff and volunteers from other organizations worked to produce maps and provide support for emergency managers, including at an emergency GIS facility in Santa Fe. Subsequent to the fire, Laboratory GIS teams supported the multiagency Burned Area Emergency Rehabilitation (BAER) team to provide GIS data and maps for planning mitigation efforts. The GIS teams continue to help researchers, operations personnel, and managers deal with the tremendous changes caused by the fire. Much of the work is under the auspices of the Cerro Grande Rehabilitation Project (CGRP) to promote recovery from fire damage, improve information exchange, enhance emergency management, and conduct mitigation activities. GIS efforts during the fire provided important lessons about institutional matters, working relationships, and emergency preparedness. These lessons include the importance of (1) an integrated framework for assessing natural and human hazards in a landscape context; (2) a strong GIS capability for emergency response; (3) coordinated emergency plans for GIS operations; (4) a method for employees to report their whereabouts and receive authoritative information during an evacuation; (5) GIS data that are complete, backed-up, and available during an emergency; (6) adaptation of GIS to the circumstances of the emergency; (7) better coordination in the GIS community; (8) better integration of GIS into LANL operations; and (9) a central data warehouse for data and metadata. These lessons are important for planning

  19. Targeting organic molecules in hydrothermal environments on Mars

    Science.gov (United States)

    Parnell, J.; Bowden, S. A.; Lindgren, P.; Wilson, R.; Cooper, J. M.

    2008-09-01

    Hydrothermal deposits on Mars Hydrothermal systems are proposed as environments that could support organic synthesis, the evolution of life or the maintenance of life [1,2,3]. They have therefore been suggested as primary targets for exploration on Mars [1,2,4,].There is now confidence that hydrothermal deposits occur at the martian surface. This is based on a range of criteria that could point towards hydrothermal activity, including volcanic activity, magmatic-driven tectonism, impact cratering in icy terrains, hydrous alteration of minerals and typical hydrothermal mineralogies [4]. The proposals to search for evidence of life at martian hydrothermal sites have been focussed on seeking morphological evidence of microbial activity [5]. Here we discuss the potential to seek a chemical signature of organic matter in hydrothermal systems. Organics in terrestrial hydrothermal systems Terrestrial hydrothermal systems can have large quantities of organic matter because they intersect organic-rich sedimentary rocks or oil reservoirs. Thus the signatures that they contain reflect some preexisting concentration of fossil organic compounds, rather than life which was active in the hydrothermal system. If any extant life was incorporated in these hydrothermal systems, it is swamped by the fossil molecules. Examples of environments where organic materials may become entrained include subsurface hydrothermal mineral deposits, generation of hydrothermal systems by igneous intrusions, and hot fluid venting at the seafloor. Nevertheless, there is value in studying the interactions of hydrothermal systems with fossil organic matter, for information about the survivability of organic compounds, phase relationships between carbonaceous and noncarbonaceous materials, and where in hydrothermal deposits to find evidence of organic matter. Microbial colonization of hot spring systems is feasible at depth within the systems and at the surface where the hydrothermal waters discharge

  20. Porosity evolution in Icelandic hydrothermal systems

    Science.gov (United States)

    Thien, B.; Kosakowski, G.; Kulik, D. A.

    2014-12-01

    Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced hydrothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems, grant number CRSII2_141843/1) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. These are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. These shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. Field observations suggest that active and fossil Icelandic hydrothermal systems are built from a superposition of completely altered and completely unaltered layers. With help of 1D and 2D reactive transport models (OpenGeoSys-GEM code), we investigate the reasons for this finding, by studying the mineralogical evolution of protoliths with different initial porosities at different temperatures and pressures, different leaching water composition and gas content, and different porosity geometries (i.e. porous medium versus fractured medium). From this study, we believe that the initial porosity of protoliths and volume changes due to their transformation into secondary minerals are key factors to explain the different alteration extents observed in field studies. We also discuss how precipitation and dissolution kinetics can influence the alteration time scales.

  1. Hydrothermal synthesis of bismuth germanium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Boyle, Timothy J.

    2016-12-13

    A method for the hydrothermal synthesis of bismuth germanium oxide comprises dissolving a bismuth precursor (e.g., bismuth nitrate pentahydrate) and a germanium precursor (e.g., germanium dioxide) in water and heating the aqueous solution to an elevated reaction temperature for a length of time sufficient to produce the eulytite phase of bismuth germanium oxide (E-BGO) with high yield. The E-BGO produced can be used as a scintillator material. For example, the air stability and radioluminescence response suggest that the E-BGO can be employed for medical applications.

  2. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  3. EMPLEO DEL PROGRAMA VOLCFLOW PARA SIMULAR FLUJOS PIROCLÁSTICOS DEL VOLCÁN CERRO MACHÍN, TOLIMA, COLOMBIA

    Directory of Open Access Journals (Sweden)

    Elsa Adriana Cárdenas Quiroga

    2013-01-01

    Full Text Available Se presentan los resultados de simular futuros flujos piroclásticos que podría producir el Volcán Cerro Machín, ubicado en la Cordillera Central de Colombia. Esta simulación se realizó con el programa VolcFlow desarrollado por el Laboratorio de Magmas y Volcanes de la Universidad Blaise Pascal, Francia, diseñado especialmente para modelar el comportamiento de este tipo de productos volcánicos, ya que está basado en las características reológicas de esos flujos. Se comparan las áreas que serían potencialmente afectadas por una erupción de ese tipo y los espesores del material que se depositaría con resultados obtenidos de simulaciones realizadas con un Model Builder desarrollado en ARC GIS por el Grupo de Investigación Geomática Aplicada de la Universidad Militar Nueva Granada en Colombia, obteniéndose resultados similares.

  4. Babel en la mina. El campamento minero como modelo de asentamiento en el mundo industrializado: Cerro Muriano (Córdoba.

    Directory of Open Access Journals (Sweden)

    Cano Sanchiz, J.M.

    2012-01-01

    Full Text Available El campamento minero contemporáneo es un tipo de asentamiento muy concreto, configurado bajo unos cánones que, con matices, suelen repetirse a escala internacional. Se trata de un lugar de convergencia, de fricción de clases. También, de un espacio heterogéneo desde el punto de vista cultural donde, sin embargo, el grupo humano formado por los obreros suele aparecer cohesionado por unas circunstancias comunes. Estas características se acentúan allí donde la inversión procede de un país distinto al de la mina. Hablamos, muchas veces, de territorios ocupados en el marco de una actividad económica de corte colonialista. Estas páginas recogen un análisis arqueológico del asentamiento surgido en torno a las minas de Cerro Muriano (Córdoba durante su explotación inglesa a principios del siglo XX. El ejemplo seleccionado nos sirve para ilustrar cómo fueron aquellos campamentos, muchos de los cuales sobrevivieron a la desaparición de la actividad minera y evolucionaron hacia núcleos de población consolidados, como es el caso.

  5. Dieta de murciélagos nectarívoros del Parque Nacional Cerros de Amotape, Tumbes

    Directory of Open Access Journals (Sweden)

    Edith Arias

    2011-07-01

    Full Text Available En el Perú se reporta la presencia de 18 especies de murciélagos nectarívoros, sin embargo se cuenta con poca información sobre la dieta de estas especies. En este estudio se reporta por primera vez la dieta de los nectarívoros Glossophaga soricina, Lonchophylla hesperia y Anoura geoffroyi en el bosque seco ecuatorial y del bosque tropical del Pacífico del Parque Nacional Cerros de Amotape, Tumbes. Analizamos 21 contenidos gastrointestinales e identificamos ocho morfotipos de polen pertenecientes a las familias Bombacaceae, Cactaceae, Fabaceae, Solanaceae, Rubiaceae, Myrtaceae, Malvaceae y Rosaceae. Encontramos evidencia del síndrome de quiropterofilia en Bombacaceae, Cactaceae, Fabaceae, Solanaceae y Rubiaceae. Observamos que A. geoffroyi consume polen de Ceiba trichistandra, Solanaceae y Rubiacea; G. soricina consume de Abutilon reflexum, Armathocereus cartwrightianus, C. trichistandra y Rubiaceae; y L. hesperia de A. cartwrightianus, Eriobotrya japonica, Fabaceae y Psidium sp.; sugiriendo una dieta generalista en estas especies. Los murciélagos G. soricina y A. geoffroyi comparten el consumo del ceibo C. trichistandra y de la Rubiaceae, mientras que G. soricina comparte con L. hesperia el consumo del cactus A. cartwrightianus. Los otros morfotipos de polen no fueron compartidos entre murciélagos. Se encuentra además que el ceibo C. trichistandra fue la especie más consumida, especialmente por G. soricina.

  6. Reproductive structures of Rhamnaceae from the Cerro del Pueblo (Late Cretaceous, Coahuila) and Coatzingo (Oligocene, Puebla) Formations, Mexico.

    Science.gov (United States)

    Calvillo-Canadell, Laura; Cevallos-Ferriz, Sergio R S

    2007-10-01

    Recently discovered fossil flowers from the Cretaceous Cerro del Pueblo and flowers and fruits from the Oligocene Coatzingo Formations are assigned to the Rhamnaceae. The Cretaceous flower, Coahuilanthus belindae Calvillo-Canadell and Cevallos-Ferriz, gen. et sp. nov., is actinomorphic with fused perianth parts forming a slightly campanulate to cupulate floral cup, with sepals slightly keeled and spatulate clawed petals. The Oligocene fossils include Nahinda axamilpensis Calvillo-Canadell and Cevallos-Ferriz, gen. et sp. nov. (characterized by its campanulate bisexual flower with stamens opposite, adnate to and enfolded by petals; and with the ovary ripening into a drupe), and a winged fruit assigned to Ventilago engoto Calvillo-Canadell and Cevallos-Ferriz, sp. nov. The flowers and drupe features indicate closer affinity to Zizipheae and/or Rhamneae, while the single samaroid fruit suggests the presence of Ventilagineae. However, the unique character combination in the fossil flowers precludes placing them in extant genera. Nevertheless, the history of the family is long and can be traced back to the Campanian. A detailed phylogenetic revision of the group that uses morphological characters from both extant and fossil plants is needed to better understand the significance of these records as well as other important fossils of the family.

  7. Palynological analysis of camelid coprolites: seasonality in the use of the site Cerro Casa de Piedra 7 (Santa Cruz, Argentina)

    Science.gov (United States)

    Velázquez, Nadia Jimena; Burry, Lidia Susana; Fugassa, Martín Horacio; Civalero, María Teresa; Aschero, Carlos Alberto

    2014-01-01

    Palynological, palaeoparasitological and paleobotanical studies of coprolites found in archaeological sites from Perito Moreno National Park (47°57‧S72°05‧W) yielded information on diet, palaeoenvironment and health. These studies allowed adding evidence to the reconstruction of life history of the hunter-gatherers that inhabited Patagonia during the Holocene. We examined the season of the year when camelid Lama guanicoe coprolites (5400 ± 64 yr 14C BP to 9640 ± 190 yr 14C BP) were deposited at Cerro Casa de Piedra 7 (site CCP7). The study used palynological evidence and comparison with pollen spectra of modern feces collected during summer, fall, winter and spring of 2010. The dominant types were: pollen of Nothofagus, Empetrum rubrum, Asteraceae subfam. Asteroideae, Nassauvia, Caryophyllaceae and Poaceae; fern spores; remains of Eimeria macusaniensis; and plant remains of Poaceae, Festuca pallescens, Stipa speciosa, Armeria maritima, Gaultheria mucronata and E. rubrum. Pollen spectra of modern and fossil feces were used for multivariate analysis. Coprolites associated to fall and winter modern feces. These results and those obtained from pollen concentration values and the presence of pollen types indicators of seasonality, allowed the determination of summer, fall and winter coprolites. However, caution must be taken with the seasonality results of coprolites dated earlier than 9000 years BP since the environmental conditions differed from now. The site was probably a camelid shelter during the unfavorable seasons.

  8. The Cerro Bitiche Andesitic Field: petrological diversity and implications for magmatic evolution of mafic volcanic centers from the northern Puna

    Science.gov (United States)

    Maro, Guadalupe; Caffe, Pablo J.

    2016-07-01

    The Cerro Bitiche Andesitic Field (CBAF) is one of the two largest mafic volcanic fields in northern Puna (22-24° S) and is spatially and temporally associated with ignimbrites erupted from some central Andean Altiplano-Puna Volcanic Complex calderas. The CBAF comprises seven scoria cones and widespread high-K calcalkaline lava flows that cover an area of 200 km2. Although all erupted rocks have a relatively narrow chemical range (56-62 % SiO2, 3-6 % MgO), there is a broad diversity of mineral compositions and textures. The least evolved lavas (˜58-61 % SiO2) are high-Mg andesites with scarce (andesites (˜62 wt% SiO2), on the other hand, are porphyritic rocks with plagioclase + orthopyroxene + biotite and ubiquitous phenocryst disequilibrium textures. These magmas were likely stored in crustal reservoirs, where they experienced convection caused by mafic magma underplating, magma mixing, and/or assimilation. Trace element and mineral compositions of CBAF lavas provide evidence for complex evolution of distinct magma batches.

  9. El patrimonio industrial petrolero en la Patagonia: Comodoro Rivadavia (Argentina y Cerro Sombrero (Chile. Una perspectiva comparada

    Directory of Open Access Journals (Sweden)

    Pía Acevedo Méndez

    2016-01-01

    Full Text Available El hallazgo de petróleo en Comodoro Rivadavia (Chubut, Argentina y en Manantiales (Tierra del Fuego, lado chileno, motivó la construcción de espacios socioproductivos bajo el modelo de Company Towns. En el caso argentino la empresa estatal Yacimientos Petrolíferos Fiscales (Y.P.F creó el Campamento Central y la Empresa Nacional del Petróleo (ENAP creó Cerro Sombrero en Chile, los que en la década de 1970 formaron dos tejidos urbanos (barrio en el caso argentino y pueblo en el caso chileno. En esta dinámica se transformó el modo de habitar de ambos espacios, que se convirtieron en potenciales elementos turísticos, teniendo en cuenta que desde el año 2014 poseen reconocimiento patrimonial relacionado con su pasado petrolero y su arquitectura moderna. El objetivo es comparar cómo ambas empresas petroleras estatales construyeron dichos espacios “urbanos” y sus comunidades sociolaborales e indagar en la relación identidad/ patrimonio de ypefeanos y enapinos.

  10. Astronomical orientations in the Iberian oppidum of Cerro de las Cabezas (Valdepeñas, Ciudad Real

    Directory of Open Access Journals (Sweden)

    César Esteban

    2017-01-01

    Full Text Available We present an archaeoastronomical analysis of the orientations observed in the entrance-sanctuary and other enclosures at the Iberian oppidum Cerro de las Cabezas (Valdepeñas, Ciudad Real, Spain, located in the northern Oretania. The most important result of this work is that two of the perimeter walls of the entrance-sanctuary are oriented towards the sunrise, one at the equinoxes and the other at the summer solstice. As in other Iberian sanctuaries, an equinoctial marker is also found. This coincides with the top of one of the most distant mountains of the horizon. The possibility that other walls of the entrance-sanctuary may be oriented to the rising of several of the brightest stars in the sky is also discussed. Moreover, it is found that the east-west axis of the southern part of the oppidum (where an enclosure that some authors have interpreted as a possible sanctuary is located is oriented approximately toward the sunrise at the winter solstice. Finally a possible alignment between the entrance-sanctuary, a necropolis located at the east and the point of the horizon where the sunrise of the winter solstice occurs is also reported.

  11. Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

    Science.gov (United States)

    Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

    1994-01-01

    The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems

  12. Hydrothermal Processes in the Archean - New Insights from Imaging Spectroscopy

    NARCIS (Netherlands)

    Ruitenbeek, F.J.A. van

    2007-01-01

    The aim of this research was to gain new insights in fossil hydrothermal systems using airborne imaging spectroscopy. Fossil submarine hydrothermal systems in Archean greenstone belts and other geologic terranes are important because of their relationship with volcanic massive sulfide (VMS) mineral

  13. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    @@ Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.

  14. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO; Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.……

  15. El frente de corrimiento andino al nivel de los cerros Penitentes y Visera (alta Cordillera de Mendoza: aspectos cronológicos y cartográficos The Andean thrust front in the Cerros Penitentes and Visera (High Cordillera of Mendoza: chronological and cartographic aspects

    Directory of Open Access Journals (Sweden)

    Jean-Claude Vicente

    2009-10-01

    Full Text Available El hallazgo de una iportante fauna de invertebrados marinos del Tithoniano superior a espaldas del cerro Penitentes en la secuencia carbonática basal de la primera escama del frente de corrimiento andino, confirma la lógica tectónica de un despegue de esta unidad a nivel del Yeso Principal y lleva a invalidar ciertas correlaciones litoestratigráficas y bosquejos paleogeográficos asignados a la Formación La Manga. Por otro lado, el análisis de algunos perfiles claves en torno al cerro Penitentes entre la quebrada Vargas y el cerro Visera permite presentar una reinterpretación tectónica del sector. Esta se sustenta en el reconocimiento y la diferenciación de las unidades terciarias básicas representadas por los Conglomerados Penitentes (Mioceno inferior y los Aglomerados Santa María (Mioceno superior en una relación muy similar a la descrita anteriormente al norte de Puente del Inca. El estudio permite seguir las interferencias, en un contexto polifásico, entre las reactivaciones del corrimiento Penitentes de piel fina y un cabalgamiento frontal de piel gruesa que repite la secuencia terciaria. La discordancia entre las secuencias terciarias y el emplazamiento de una klippe de Malm sobre los Conglomerados Penitentes del sinclinal del cerro Visera, conduce a otorgar cierta importancia a la fase del final del Mioceno inferior.The finding of an important marine invertebrate fauna of Upper Tithonian age at the shoulders of the Penitentes hill, in the basal carbonatic sequence of the first Andean wedge confirms the tectonic logic of a detachment of this unit at the level of the Yeso Principal. This allows invalidating certain lithostratigraphic correlations and paleogeographic sketches ascribed to the La Manga Formation. On the other hand, the analysis of some key sections around the Penitentes hill area between the Quebrada de Vargas and the Cerro Visera, allows presenting a tectonic reinterpretation of the sector. This is based on the

  16. Nutritional strategies of the hydrothermal ecosystem bivalves

    Science.gov (United States)

    Le Pennec, Marcel; Donval, Anne; Herry, Angèle

    Studies of deep-sea hydrothermal bivalves have revealed that the species, which are strictly dependent upon the interstitial fluid emissions, derive their food indirectly via symbiotic relationships with chemosynthetic bacteria present in their gill tissues. As the gill plays the main trophic role, structural and ultrastructural modifications occur in the digestive tract. Scanning and transmission electron microscope studies reveal that the digestive system of species belonging to the genera Calyptogena, Bathymodiolus and Bathypecten have anatomical differences. In Calyptogena, the reduction of several parts of the digestive tract and the stomach content which is either empty or full, according to the various species examined indicate that the digestive system is hardly if at all functional. In Bathymodiolus, the labial palps are well developed, the stomach is always full with particles and the two cellular types, digestive and secretory, are present in the digestive gland. All these characteristics indicate that the digestive system is functional. In Bathypecten, the digestive tract is well developed and it seems that it plays the main trophic role. We conclude that the nutritional strategies of the hydrothermal vents bivalves are quite varied. They range from a normal trophic process, through a mixotrophic diet, to one based purely on chemoautotrophic bacteria. The strategy of each species is adapted to and influences its distribution.

  17. Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.

    2016-10-16

    Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

  18. Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

    Science.gov (United States)

    Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

    2014-06-01

    Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content.

  19. Characteristics of Hydrothermal Mineralization in Ultraslow Spreading Ridges

    Science.gov (United States)

    Zhou, H.; Yang, Q.; Ji, F.; Dick, H. J.

    2014-12-01

    Hydrothermal activity is a major component of the processes that shape the composition and structure of the ocean crust, providing a major pathway for the exchange of heat and elements between the Earth's crust and oceans, and a locus for intense biological activity on the seafloor and underlying crust. In other hand, the structure and composition of hydrothermal systems are the result of complex interactions between heat sources, fluids, wall rocks, tectonic controls and even biological processes. Ultraslow spreading ridges, including the Southwest Indian Ridge, the Gakkel Ridge, are most remarkable end member in plate-boundary structures (Dick et al., 2003), featured with extensive tectonic amagmatic spreading and frequent exposure of peridotite and gabbro. With intensive surveys in last decades, it is suggested that ultraslow ridges are several times more effective than faster-spreading ridges in sustaining hydrothermal activities. This increased efficiency could attributed to deep mining of heat and even exothermic serpentinisation (Baker et al., 2004). Distinct from in faster spreading ridges, one characteristics of hydrothermal mineralization on seafloor in ultraslow spreading ridges, including the active Dragon Flag hydrothermal field at 49.6 degree of the Southwest Indian Ridge, is abundant and pervasive distribution of lower temperature precipitated minerals ( such as Fe-silica or silica, Mn (Fe) oxides, sepiolite, pyrite, marcasite etc. ) in hydrothermal fields. Structures formed by lower temperature activities in active and dead hydrothermal fields are also obviously. High temperature precipitated minerals such as chalcopyrite etc. are rare or very limited in hydrothermal chimneys. Distribution of diverse low temperature hydrothermal activities is consistence with the deep heating mechanisms and hydrothermal circulations in the complex background of ultraslow spreading tectonics. Meanwhile, deeper and larger mineralization at certain locations along the

  20. ESTRATEGIA DE REMONTAJE APLICADA SOBRE EL REGISTRO CERÁMICO DEL SITIO LOS TRES CERROS 1 (DELTA SUPERIOR DEL RÍO PARANÁ / Refitting applied to pottery from Los Tres Cerros 1 site (Upper Delta of Paraná River

    Directory of Open Access Journals (Sweden)

    Violeta Soledad Di Prado

    2014-12-01

    Full Text Available El sitio arqueológico Los Tres Cerros 1 se encuentra ubicado en el departamento Victoria, Entre Ríos, y consiste en una estructura monticular con una compleja historia ocupacional. La abundancia y fragmentación del registro cerámico del sitio, llevaron a aplicar la estrategia de remontajes, con el propósito de reconstruir la historia de vida de las vasijas e identificar las prácticas humanas y los agentes naturales que actuaron en la configuración del depósito. Sobre una muestra del total de tiestos recuperados en la cuadrícula 1, se realizaron 43 remontajes, que unen fragmentos del mismo nivel y de diferentes niveles. Se identificaron semejanzas en las elecciones técnicas similares (i.e., agregado de tiesto molido, aplicación de pigmento y de surco rítmico efectuadas en distintas etapas del proceso de elaboración del número mínimo de vasijas estimado (NMV= 49. Se reconocieron contenedores utilizados sobre el fuego, posiblemente para la cocción, y piezas probablemente empleadas para servir. Por último, se propusieron hipótesis en torno a la integridad del registro y, al menos para el sector superior de la secuencia estratigráfica, se infirió un evento de ocupación que no fue mayormente disturbado en momentos posteriores al descarte.   Palabras clave: alfarería, remontajes, elecciones tecnológicas, prácticas de uso, procesos de formación de sitio.   Abstract Los Tres Cerros 1 archaeological site is located in Victoria department, Entre Ríos province, and it is a mound with a complex occupational history. The abundance and fragmentation of the ceramic record recovered from this site, led to apply the refitting strategy in order to reconstruct the vessels’ life history and identify human practices and natural agents that took part in the site configuration. From a ceramic sample of the whole recovered in grid 1, 43 reassemblies were made, joining sherds from the same level, as well as from different levels. Similar

  1. PATRONES DE CONSUMO FINAL DE CÉRVIDOS EN EL PARANÁ MEDIO: EL CASO DEL SITIO CERRO AGUARÁ / Cervids final consumption patterns in middle Paraná River: the case of Cerro Aguará archaeological site

    Directory of Open Access Journals (Sweden)

    Leonardo Mucciolo

    2015-06-01

    Full Text Available Los cérvidos fueron amplia y regularmente explotados por los cazadores-recolectores que habitaron la macroregión del Paraná-Plata durante el Holoceno tardío. En la cuenca media del Paraná, sin embargo, muy pocos estudios han enfocado sobre las estrategias empleadas para su obtención, procesamiento y consumo. Teniendo en cuenta esto, el objetivo de este trabajo es explorar dichos aspectos a partir del análisis de los conjuntos de cérvidos provenientes del sitio arqueológico Cerro Aguará, localizado en el departamento General Obligado (provincia de Santa Fe. La perspectiva seleccionada propone al consumo como factor preponderante en la configuración del registro zooarqueológico dentro del continuum de actividades que componen la explotación faunística. Desde esta perspectiva, y tomando en consideración que las carcasas de los cérvidos proveen distintos tipos de recursos alimenticios con diferentes costos de extracción (carne, médula y grasa ósea, se evalúan diferentes indicadores para establecer si existió diferente intensidad en su procesamiento. Los resultados indican que las dos especies de cérvidos identificadas en el sitio, Blastocerus dichotomus y Ozotoceros bezoarticus, ocuparon un rol preponderante en la dieta, aunque las carcasas del primero fueron empleadas más intensivamente probablemente en correlación con su mayor disponibilidad de nutrientes internos, tales como la médula y posiblemente la grasa ósea.  Abstract  Cervids were wide and regularly exploited by several Late Holocene hunter-gatherers inhabiting Paraná Plata macroregion. In the middle Paraná river, however, few research has been made on strategies involving their procurement, processing and consumption. The purpose of this article is to explore those aspects from the analysis of cervid assemblages of Cerro Aguará archaeological site (General Obligado, Santa Fe province. The selected perspective proposes final consumption as one of the most

  2. Control estructural de las mineralizaciones de fluorita del batolito Cerro Áspero, Sierras Pampeanas de Córdoba Structural control of vein-type fluorite deposits of Cerro Áspero batholith, Sierras Pampeanas of Córdoba

    Directory of Open Access Journals (Sweden)

    Jorge E Coniglio

    2010-12-01

    Full Text Available Con más de 1.000.000 t de reservas totales el batolito Cerro Áspero, magmatismo devónico de alto potasio, es portador de las mayores concentraciones de fluorita de las Sierras Pampeanas. Las vetas epitermales son de edad cretácica, subverticales, poseen potencias generalmente menores a 3 m y se extienden a profundidades mayores a 200 metros. Ocurren en un área de 440 km² con una distribución intrabatolítica predominante. La geometría y la cinemática de las estructuras mineralizadas son consistentes con deformación por cizalla simple, dextrógira, con el eje extensional principal (σ3 orientado hacia el NNO. Esta situación implantó en el área estructuras extensionales N70ºE ( 4 km de corrida, que presentan patrones de fallas transcurrentes, con bifurcaciones, deflexiones, aperturas, saltos, cierres y fracturas en échelon asociadas. Los estudios texturales y estructurales en las vetas han permitido distinguir cuatro estadios sucesivos de mineralización que fueron controlados por una actividad discontinua de la cupla dextral. Este modelo estructural es similar a aquéllos propuestos para mineralizaciones de fluorita emplazadas en otros sectores del continente durante el mismo período, los que vinculan el control tectónico con la apertura del océano Atlántico sur. El registro del relleno hidrotermal permitió reconstruir la historia de apertura de las estructuras y puede usarse como un criterio efectivo de prospección y exploración. Las mayores concentraciones de mineral ocurren en las estructuras extensionales y en las flexiones dilatantes de las estructuras asociadas con la zona de cizallamiento principal NNE-SSO, que registran la secuencia mineralizada completa.With over 1,000,000 t of total reserves, the high-K devonian granites of the Cerro Áspero batholith (440 km² are the most important fluorite-bearing granitic suite in the Sierras Pampeanas. The epithermal fluorite veins, of Cretaceous age, fill in steeply dipping

  3. The Guaymas Basin hiking guide to hydrothermal mounds, chimneys and microbial mats: complex seafloor expressions of subsurface hydrothermal circulation

    Directory of Open Access Journals (Sweden)

    Andreas eTeske

    2016-02-01

    Full Text Available The hydrothermal mats, mounds and chimneys of the southern Guaymas Basin are the surface expression of complex subsurface hydrothermal circulation patterns. In this overview we document the most frequently visited features of this hydrothermal area with photographs, temperature measurements, and selected geochemical data; many of these distinct habitats await characterization of their microbial communities and activities. Microprofiler deployments on microbial mats and hydrothermal sediments show their steep geochemical and thermal gradients at millimeter-scale vertical resolution. Mapping these hydrothermal features and sampling locations within the southern Guaymas Basin suggest linkages to underlying shallow sills and heatflow gradients. Recognizing the inherent spatial limitations of much current Guaymas Basin sampling calls for a wider survey of the entire spreading region.

  4. Entropy Production in Convective Hydrothermal Systems

    Science.gov (United States)

    Boersing, Nele; Wellmann, Florian; Niederau, Jan

    2016-04-01

    Exploring hydrothermal reservoirs requires reliable estimates of subsurface temperatures to delineate favorable locations of boreholes. It is therefore of fundamental and practical importance to understand the thermodynamic behavior of the system in order to predict its performance with numerical studies. To this end, the thermodynamic measure of entropy production is considered as a useful abstraction tool to characterize the convective state of a system since it accounts for dissipative heat processes and gives insight into the system's average behavior in a statistical sense. Solving the underlying conservation principles of a convective hydrothermal system is sensitive to initial conditions and boundary conditions which in turn are prone to uncertain knowledge in subsurface parameters. There exist multiple numerical solutions to the mathematical description of a convective system and the prediction becomes even more challenging as the vigor of convection increases. Thus, the variety of possible modes contained in such highly non-linear problems needs to be quantified. A synthetic study is carried out to simulate fluid flow and heat transfer in a finite porous layer heated from below. Various two-dimensional models are created such that their corresponding Rayleigh numbers lie in a range from the sub-critical linear to the supercritical non-linear regime, that is purely conductive to convection-dominated systems. Entropy production is found to describe the transient evolution of convective processes fairly well and can be used to identify thermodynamic equilibrium. Additionally, varying the aspect ratio for each Rayleigh number shows that the variety of realized convection modes increases with both larger aspect ratio and higher Rayleigh number. This phenomenon is also reflected by an enlarged spread of entropy production for the realized modes. Consequently, the Rayleigh number can be correlated to the magnitude of entropy production. In cases of moderate

  5. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza

    Directory of Open Access Journals (Sweden)

    Federico Fuentes

    2008-03-01

    Full Text Available El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánicas pliocenas a recientes de composición intermedia a básica, y depósitos cuaternarios inconsolidados. El cerro Guanaquero, un estratovolcán pliocuaternario intensamente erosionado por glaciares pleistocenos, con sus 4.841 metros es el rasgo orográfico más prominente. Está constituido esencialmente por andesitas grises porfíricas, piroxénicas a biotíticas. Intercaladas con las coladas andesíticas se presentan depósitos piroclásticos, aglomerados volcánicos, ignimbritas y basaltos. La datación de una andesita por el método K-Ar en roca total arrojó una edad de 1,4 ± 0,1 Ma. La deformación ándica comenzó en forma de una faja plegada y corrida de piel fina, con pliegues por despegue en el sector occidental y por propagación de falla en el oriental. La compresión al oeste de los 69º47´O terminó por invertir la fallas normales del rift mesozoico. A lo largo de este meridiano se encuentra la falla más importante de la región, la que se ha correlacionado con la falla Malargüe, bien desarrollada en latitudes más australes. Esta falla limita la faja plegada y corrida del Aconcagua, de naturaleza epidérmica, y la faja plegada y corrida de Malargüe, controlada por la inversión tectónica del basamento. El volcanismo fue muy intenso en el Plioceno y el Cuaternario, correspondiendo a un período de empinamiento de la placa oceánica subducida, en el que la región ha sido levantada pasivamente. La alta resistencia a la erosión de

  6. Control estructural de las mineralizaciones de fluorita del batolito Cerro Áspero, Sierras Pampeanas de Córdoba

    Directory of Open Access Journals (Sweden)

    Jorge E Coniglio

    2010-12-01

    Full Text Available Con más de 1.000.000 t de reservas totales el batolito Cerro Áspero, magmatismo devónico de alto potasio, es portador de las mayores concentraciones de fluorita de las Sierras Pampeanas. Las vetas epitermales son de edad cretácica, subverticales, poseen potencias generalmente menores a 3 m y se extienden a profundidades mayores a 200 metros. Ocurren en un área de 440 km² con una distribución intrabatolítica predominante. La geometría y la cinemática de las estructuras mineralizadas son consistentes con deformación por cizalla simple, dextrógira, con el eje extensional principal (σ3 orientado hacia el NNO. Esta situación implantó en el área estructuras extensionales N70ºE ( 4 km de corrida, que presentan patrones de fallas transcurrentes, con bifurcaciones, deflexiones, aperturas, saltos, cierres y fracturas en échelon asociadas. Los estudios texturales y estructurales en las vetas han permitido distinguir cuatro estadios sucesivos de mineralización que fueron controlados por una actividad discontinua de la cupla dextral. Este modelo estructural es similar a aquéllos propuestos para mineralizaciones de fluorita emplazadas en otros sectores del continente durante el mismo período, los que vinculan el control tectónico con la apertura del océano Atlántico sur. El registro del relleno hidrotermal permitió reconstruir la historia de apertura de las estructuras y puede usarse como un criterio efectivo de prospección y exploración. Las mayores concentraciones de mineral ocurren en las estructuras extensionales y en las flexiones dilatantes de las estructuras asociadas con la zona de cizallamiento principal NNE-SSO, que registran la secuencia mineralizada completa.

  7. Proposed geologic model based on geophysical well logs

    Energy Technology Data Exchange (ETDEWEB)

    Diaz C, S.; Puente C, I.; de la Pena L, A.

    1981-01-01

    An investigation of the subsurface based on a qualitative interpretation of well logs was carried out at Cerro Prieto to obtain information on the distribution of the different lithofacies that make up a deltaic depositional system. The sedimentological interpretation derived from the resistivity and spontaneous potential are shown in several cross-sections of the field. In addition to the sedimentological interpretation, a map of the structural geology of the region based on well logs and available geophysical information was prepared, including the results of gravity and seismic refraction surveys. The depth to the zone of hydrothermal alteration described by Elders (1980) was found by means of temperature, electrical, and radioactive logs. Two maps showing the configuration of the top of this anomaly show a clear correlation with the gravity anomalies found in the area.

  8. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    Directory of Open Access Journals (Sweden)

    Jung Hyunjung

    2011-01-01

    Full Text Available Abstract Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene nanoparticles (NPs prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs.

  9. Magmatismo ácido del mioceno superior-cuaternario en el área de Cerro Blanco-La Hoyada, Puna Austral

    Directory of Open Access Journals (Sweden)

    María Carolina Montero López

    2010-11-01

    Full Text Available El volcanismo de composición ácida desarrollado en la Puna Austral entre el Mioceno superior y el Holoceno está representado en el extremo oriental de la cordillera de San Buenaventura (26°25'-27°00'S y 67°25'-67°50' O por dos unidades: Ignimbrita Aguada Alumbrera y Complejo Volcánico Cerro Blanco. Hacia el norte y noroeste de esta área afloran flujos piroclásticos (Ignimbrita Rosada cuyo análisis se presenta aquí a fines comparativos. Estas rocas volcánicas apoyan sobre un basamento metamórfico de mediano a alto grado con intrusivos del Neoproterozoico-Paleozoico inferior y rocas volcánicas de composición intermedia de ca. 9-7 Ma. Las rocas estudiadas abarcan un lapso entre el Mioceno superior (Ignimbrita Aguada Alumbrera e Ignimbrita Rosada hasta el Holoceno (Complejo Volcánico Cerro Blanco, tienen afinidad calcoalcalina y son principalmente de composición riolítica. En este estudio se presentan nuevos datos de campo que permiten ordenar la estratigrafía del sector de estudio, así como resultados de geoquímica. Las ignimbritas del Mioceno Superior-Plioceno estudiadas presentan características similares a las rocas ácidas aflorantes al oeste del área de estudio, las cuales fueron relacionadas por diversos autores a un ambiente de subducción procedentes de fuentes mantélicas con altos porcentajes de contaminación cortical, mientras que el Complejo Volcánico Cerro Blanco podría estar reflejando su procedencia de la fusión directa de la corteza, si bien esta hipótesis debe ser corroborada con mayor cantidad de datos geoquímicos.

  10. Hydrothermal carbonization of anaerobically digested maize silage.

    Science.gov (United States)

    Mumme, Jan; Eckervogt, Lion; Pielert, Judith; Diakité, Mamadou; Rupp, Fabian; Kern, Jürgen

    2011-10-01

    Hydrochars were prepared by hydrothermal carbonization (HTC) of maize silage previously treated at 55 °C in a two-stage solid-state reactor system. The HTC was carried out in a 1-L stirred pressure reactor with pH regulation by citric acid. The treated silage carbonized at relatively mild conditions (190 °C, 2 h), and the hydrochars showed mainly amorphous macro-size features with a carbon content of 59-79% (ash-free, dry) and a higher heating value of 25-36 MJ kg⁻¹. Temperature was the main influencing factor. The surface area according to Brunauer-Emmett-Teller (BET) analysis was highest at 190 °C (12.3 m²) g⁻¹). Based on these results, the hydrochars are potentially interesting for applications such as an alternative fuel or a soil conditioner.

  11. Hydrothermal pretreatment of biomass for pellet production

    Energy Technology Data Exchange (ETDEWEB)

    Tooyserkani, Z. [British Columbia Univ., Vancouver, BC (Canada). Clean Energy Research Centre, Biomass and Bioenergy Research Group

    2010-07-01

    This presentation discussed innovative technologies for the production of wood pellets using the hydrothermal pre-treatment of biomass. Conventional techniques use low-cost mill residues, such as saw dust and shavings, as feedstock to produce durable, low-ash pellets. However, mill residues are becoming less available as a result of fewer saw mills, increased pellet production, and increased competition for saw dust. Advanced techniques use mixed biomass such as logging residue as feedstock, creating pellets that are durable for handling and long-term storage, of a higher energy density for transport and mixing with coal for co-firing, and a choice feedstock for biofuels. Advanced pellet production uses steam explosion/pre-treatment in which biomass receives a short-term high-pressure steam treatment followed by sudden decompression. Mild torrefaction seems to have positive feedback, and steam-treated pellets are durable with superior hydrophobicity. 3 figs., 3 tabs.

  12. Hydraulic characterization of hydrothermally altered Nopal tuff

    Energy Technology Data Exchange (ETDEWEB)

    Green, R.T.; Meyer-James, K.A. [Southwest Research Institute, San Antonio, TX (United States); Rice, G. [George Rice and Associates, San Antonio, TX (United States)

    1995-07-01

    Understanding the mechanics of variably saturated flow in fractured-porous media is of fundamental importance to evaluating the isolation performance of the proposed high-level radioactive waste repository for the Yucca Mountain site. Developing that understanding must be founded on the analysis and interpretation of laboratory and field data. This report presents an analysis of the unsaturated hydraulic properties of tuff cores from the Pena Blanca natural analog site in Mexico. The basic intent of the analysis was to examine possible trends and relationships between the hydraulic properties and the degree of hydrothermal alteration exhibited by the tuff samples. These data were used in flow simulations to evaluate the significance of a particular conceptual (composite) model and of distinct hydraulic properties on the rate and nature of water flow.

  13. Efficiencies of Power Plants Using Hydrothermal Oxidation

    Science.gov (United States)

    Hirosaka, Kazuma; Yuvamitra, Korakot; Ishikawa, Akira; Hasegawa, Tatsuya

    Wet biomass is hard to handle as a fuel for power plants because it contains high moisture and its drying process needs more energy input than it produces. Hydrothermal oxidation could be one of the promising technologies to overcome this problem because this process does not need drying process at all. We focus on recovery of thermal energy produced by hydrothermal oxidation of wet biomass. Two kinds of power plant are investigated, a direct type and an indirect type. In the direct type power plant, reactant is oxidized in a reactor and directly flowed into a turbine. In the indirect type power plant, reactant is oxidized in a reactor and the reaction heat is conveyed to the main water, which is flowed into a turbine. The amount of electric power and the energy conversion efficiency are calculated by using ethanol, glucose and peat solutions as reactants. In both type of power plant, one steam turbine is employed for generating electricity with the maximum turbine inlet temperature of 650 °C. As ethanol concentration increased, the amount of electric power and the energy conversion efficiency become higher. The maximum efficiency for the direct type power plant using ethanol solution is about 26.4 % for 17.6 wt% at the reactor pressure of 10 MPa. The efficiency of the indirect type power plant is much lower than that of the direct type, but by pressurizing main water up to 4 MPa, the efficiency becomes higher up to 20.9 %. For glucose solution, the maximum efficiency for the direct type is about 25.5 % for 34.5 wt% at the reactor pressure of 5 MPa. The maximum efficiency of the indirect type at the main water pressure of 4 MPa is about 21.1 % for 40.7 wt%. For peat solution, only the indirect type is investigated. The maximum efficiency at the main water pressure of 4 MPa is about 20.8 % for 36.8 wt%.

  14. Peptide synthesis under Enceladus hydrothermal condition

    Science.gov (United States)

    Fujishima, Kosuke; Takano, Yoshinori; Takai, Ken; Takahagi, Wataru; Adachi, Keito; Shibuya, Takazo; Tomita, Masaru

    2016-07-01

    Enceladus is one of the moons of Saturn, and it has been known to harbor interior ocean beneath the icy crust. The mass spectrometry data obtained by Cassini spacecraft indicates the presence of salty, and most likely alkaline ocean containing various organic compounds. While geochemical and other radiation related processes for in situ production of organics remain elusive, thermally unaltered carbonaceous chondrites, consisting the main body of Enceladus are known to be enriched with organic matters potentially including the building blocks of life (e.g., amino acids and amino acid precursors). Assuming that abiotic amino acids exist in the Enceladus alkaline seawater, we hypothesized that water-rock interaction may contribute to condensation of localized amino acids leading to peptide formation. In order to test this hypothesis, we have developed the Enceladus hydrothermal reactor based on the chemical constraints obtained through previous experimental and theoretical studies. We have added six different amino acids and introduced a thermal fluctuation system simulating the periodic tidal heating of the interior chondritic core. Total, eight sea water samples were obtained over the course of 147 days of experiment. While detection of peptide using Capillary Electrophoresis Time-of-Flight Mass Spectrometry (CE-TOF/MS) is still at the preliminary stage, so far pH monitoring and H2 and CO2 Gas Chromatography Mass Spectrometry (GC-MS) data clearly indicated the occurrence of serpentinization/carbonation reaction. Here, we discuss the interaction between aqueous alteration reactions and thermal cycling processes for the role of abiotic peptide formation under the Enceladus hydrothermal condition.

  15. [R_Arnedo_SanMiguel] Documentación geométrica de las excavaciones arqueológicas del Cerro de San Miguel (Arnedo, La Rioja)

    OpenAIRE

    2007-01-01

    [ES] El cerro de San Miguel de Arnedo alberga un importante asentamiento plenamente adscrito a la cultura celtibérica. Los restos documentados corresponden a dos conjuntos de viviendas y una estructura defensiva compuesta por un foso y restos de muralla. La documentación se ha realizado mediante estación total. Además, la muralla se ha documentado mediante fotogrametría estereoscópica. [EN] San Miguel’s hill houses an important archaeological site which dates back to the Celtiberian cul...

  16. IMPACTO EN AFLUENTES DEL RÍO PILCOMAYO POR CONTAMINANTES ADICIONALES DE DRENAJE ÁCIDO DE MINAS DESDE CERRO RICO, POTOSÍ-BOLIVIA

    OpenAIRE

    William H.J. Strosnider; Freddy S. Llanos; Cristina E. Marcillo; Ruben R. Callapa; Robert W. Nairn

    2014-01-01

    La minería intensiva y el procesamiento del cuerpo mineralizado del Cerro Rico de Potosí (Bolivia) ha ocurrido desde 1545. Para avanzar la investigación sobre descargas de drenaje acido de minas (DAM) y su conexión a la contaminación río abajo, se generaron datos en dos muestreos durante la temporada más extrema de lluvia y sequía. Las concentraciones en el DAM y arroyos receptores de Ag, B, Ba, Mo, Sb, Se, Sn, y V fueron superiores a los límites de descarga permitidos por la legislación Boli...

  17. Chemical and mineralogical analyses of a weathering mantle developing on peridotite of the mining area for nickel in Cerro Matoso, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, C.M.; Fabris, J.D. [Departamento de Quimica, UFMG (Brazil)], E-mail: claudiag@dedalus.lcc.ufmg.br, E-mail: fabris@dedalus.lcc.ufmg.br; Pacheco Serrano, W.A. [Departamento de Fisica (Colombia)], E-mail: wpacheco@donato.uptc.edu.co

    1999-11-15

    Four samples were collected at several depths in a weathering mantle developing on peridotite, found in a mining area for nickel of Cerro Matoso, about 20 km southwest of Monte Libano, Department of Cordoba, Colombia. Samples represent the main stratigraphy of the mantle. Powder X-ray diffractometry, RT Moessbauer spectroscopy, saturation magnetization measurements and conventional chemical analysis on the whole and chemically treated samples, and on some of their magnetic extracts, were used to give some details of the main occurring mineralogical phases in the mantle, particular of the magnetic iron oxides.

  18. Tecnología, subsistencia y cronología del sitio El Cerro, Departamento de Río Negro,Uruguaya

    OpenAIRE

    Gascue, Andrés; Loponte, Daniel M.; Moreno, Federica; Bortolotto, Noelia; Rodríguez, Ximena; Figueiro, Gonzalo; Teixeira, Franco; de Acosta, Alejandro

    2016-01-01

    En este trabajo se efectúa una revisión de los materiales obtenidos en El Cerro, excavado por Boretto y colaboradores en la segunda mitad del siglo pasado. El sitio se ubica sobre una suave colina natural en la margen derecha del Río Negro (República Oriental del Uruguay). La estratigrafía observada en sondeos recientemente efectuados en el sitio, indican que se trata de una elevación natural constituida por un albardón de arena edafizada. El conjunto arqueológico fue generado por grupos de c...

  19. Procesos históricos y ambientales en Cerro de San Pedro, San Luis Potosí, México, 1948-1997

    OpenAIRE

    Paula Andrea Martínez Chaves; Alexander Betancourt Mendieta; Miguel Nicolás Caretta; Miguel Aguilar Robledo

    2010-01-01

    Los estudios sobre el municipio Cerro de San Pedro enfatizan la continuidad ambiental aparente que estimula la minería; sin embargo, esta lectura subvalora otras dinámicas que ocurren en la zona. Con base en observaciones directas de trabajo en campo, para realizar análisis de coberturas vegetales, entrevistas con los habitantes de la zona, revisión de cartografía e investigación de archivo, el presente trabajo muestra procesos como la explotación de recursos vegetales y el pastoreo, como act...

  20. Hydrothermal growth of ZnO nanostructures - revew article

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2009-01-01

    Full Text Available One-dimensional nanostructures exhibit interesting electronic and optical properties due to their low dimensionality leading to quantum confinement effects. ZnO has received lot of attention as a nanostructured material because of unique properties rendering it suitable for various applications. Amongst the different methods of synthesis of ZnO nanostructures, the hydrothermal method is attractive for its simplicity and environment friendly conditions. This review summarizes the conditions leading to the growth of different ZnO nanostructures using hydrothermal technique. Doping of ZnO nanostructures through hydrothermal method are also highlighted.

  1. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  2. Direct use of hydrothermal energy: a review of environmental aspects

    Energy Technology Data Exchange (ETDEWEB)

    O' Banion, K.; Layton, D.

    1981-08-28

    The potential environmental impacts of the exploration, development, and production of hydrothermal geothermal energy for direct use applications are reviewed and evaluated. Mitigation strategies and research and development needs are included. (MHR)

  3. Microbiological production and ecological flux of northwestern subduction hydrothermal systems

    Science.gov (United States)

    Sunamura, M.; Okamura, K.; Noguchi, T.; Yamamoto, H.; Fukuba, T.; Yanagawa, K.

    2012-12-01

    Deep-sea hydrothermal system is one of the most important sources for heat and chemical flux from the oceanic crust to the global ocean. The rich biological community around the hydrothermal vent shows chemolithoautotrophic microbial production are important in deep sea ecosystems. More than 99% of microbiological available chemical components in hydrothermal vent fluid, e.g. sulfide, methane, hydrogen, Fe2+, and Mn2+, is released into surrounding seawater to construct hydrothermal plume, suggesting that the chemolithoautotrophic-microbial primary production in the hydrothermal plume is huge and important in the whole hydrothermal ecosystems. To understand the impact of hydrothermal plume to a microbial ecosystem and a connectivity with zooplankton, we targeted and investigated a total of 16 hydrothermal fileds (7 sites in Okinawa trough, 3 sites in Ogasawara arc, and 6 sites in Mariana arc and back arc) and investigated in several cruises under the TAIGA project in Japan. Hydrothermal fluids in the subduction system are rich in sulfide. The hydrothermal fluids in the Okinawa trough, Ogasawara arc. and Mariana trough are characterized by rich in methane, poor in other reduced chemicals, and rich in iron, respectively. The major microbial composition was a potential sulfur oxidizing microbes SUP05 in the plume ecosystems, while an aerobic methanotrophic bacteria was secondary major member in methane-rich hydrothermal systems in Okinawa trough. Microbial quantitative and spatial distribution analyses of each plume site showed that the microbial population size and community structures are influenced by original chemical components of hydrothermal fluid, e.g. sulfide, methane and iron concentration. Microbial quantitative data indicated the removal/sedimentation of microbial cells from the plume and effect of phase separation in a same vent field through construction of gas-rich or gas-poor plumes. After the correlation of plume mixing effect, we estimates that the

  4. Geología de la Formación Cerro Negro (Cretácico en Isla Livingston: aportes a su geocronología y contenido paleontológico Geology of the Cerro Negro Formation (Cretaceous in Livingston Island: contributions to its geochronology and paleontological content

    Directory of Open Access Journals (Sweden)

    C.A. Parica

    2007-12-01

    Full Text Available La península Byers se encuentra en el extremo occidental de la isla Livingston, archipiélago de las islas Shetland del Sur. Geológicamente está caracterizada por depósitos marinos, continentales y volcanismo cretácico-terciario que son incluidos en la Formación Cerro Negro de la sección superior del Grupo Byers. Las secuencias magmáticas han sido divididas en dos grupos principales, el primero comprende a las rocas piroclásticas y reúne cinco unidades con un importante desarrollo y distribución en el área. Por su parte, el segundo grupo comprende lavas e intrusivos aflorantes en cerros Don Carlos, Usnea (Usnea Plug, Chester (Chester Cone, Sealer (Sealer Hill y Negro (Negro Hill. Los términos sedimentarios incluyen conglomerados, areniscas y pelitas, de color gris verdoso con estratificación entrecruzada (tanto tabular como en artesa, raramente estratos macizos, laminación horizontal (en algunos casos de naturaleza rítmica, y estructuras de deformación sinsedimentaria (principalmente laminación convoluta. Se propone un ambiente fluvial de depositación, con canales dominados por carga de lecho y barras areno-gravosas bien desarrolladas. En lo que corresponde al sector de planicie de inundación, predominó allí la depositación de material limo-arcilloso por corrientes tractivas débiles durante las crecientes. En las áreas deprimidas de las planicies habría tenido lugar la formación de cuerpos de aguas de poca profundidad en los que se vió favorecida la preservación de la macro y microflora. En las nuevas localidades fosilíferas de península Byers, Domo Rotch (Rotch Dome, cerro Don Carlos, Lomada de las Plantas y 904, ha sido reconocida la presencia de las especies: Araucarites sp., Archangelskya furcata Herbst, Cladophlebis sp., Dictyozamites sp., Elatocladus sp, Phyllopteroides sp., Pseudoctenis sp., Ptyllophyllum menendezii Cantrill, Sphenopteris sp., Eocyathea remesaliae Césari, Sergioa austrina Césari y

  5. A data processing method for MAPR hydrothermal plume tur-bidity data and its application in the Precious Stone Mountain hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    CHEN Sheng; TAO Chunhui; LI Huaiming; CHEN Yongshun; ZHOU Jianping; WU Tao

    2014-01-01

    Hydrothermal plume is an important constituent of seabed hydrothermal circulation and is also one of the characteristics of active hydrothermal vents. Portable Miniature Autonomous Plume Recorders (MAPR) attached to a towed deep-sea instrument was used to search for hydrothermal plumes and hydrothermal vents. We introduced the basic principle of MAPR based on deep towing technology to detect plumes, then analyzed the factors affecting the quality of the MAPR data and presented a data correction method for MAPR, including instrument location correction, noise reduction processing, system error elimination and seawater background reduction. Finally we applied the method to analyze MAPR data obtained during the Chinese DY115-21 cruise on R/VDayang Iin the “Precious Stone Mountain” hydrothermal field on the Gala-pagos Microplate. The results provided a better understanding of the distribution of the hydrothermal activ-ity in this field, indicating the presence of a new hydrothermal vent.

  6. Hydrothermal monitoring data from the Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, Steven E.; Gelwick, Katrina D.; Randolph-Flagg, Noah G.; Crankshaw, Ilana M.; Lundstrom, Elizabeth A.; McCulloch, Callum L.; Murveit, Anna M.; Newman, Alice C.; Mariner, Robert H.; Bergfeld, D.; Tucker, Dave S.; Schmidt, Mariek E.; Spicer, Kurt R.; Mosbrucker, Adam; Evans, William C.

    2013-01-01

    This database serves as a repository for hydrothermal-monitoring data collected at 25 sites in the U.S. portion of the Cascade Range volcanic arc. These data are intended to quantify baseline hydrothermal variability at most (10 of 12) of the highest-risk volcanoes in the Cascades, as defined by the U.S. Geological Survey’s (USGS’) National Volcanic Early Warning System (NVEWS) report (Ewert and others, 2005).

  7. TECNOLOGÍA Y SUBSISTENCIA EN EL SITIO ARQUEOLÓGICO CERRO TAPERA VÁZQUEZ (PARQUE NACIONAL PRE-DELTA, REPÚBLICA ARGENTINA

    Directory of Open Access Journals (Sweden)

    Mariano Bonomo

    2014-10-01

    Full Text Available In this paper the results of the studies carried out on ceramic and bone materials recorded at Cerro Tapera Vázquez site (Argentinean Northeast are presented. Taxonomic, anatomic and taphonomic studies of bone assemblages and technological-decorative analysis and refitting of pottery were undertaken. The site is located on a mound next to El Ceibo Creek, where 16 m2 were excavated in 2008. Abundant smooth, incised and modeled pottery (handles and zoomorphic appendages and numerous bones remains of Myocastor coypus (most frequent taxon, Blastocerus dichotomus, Ozotoceros bezoarticus, Cavia aperea, Leopardus geoffroyi, Lycalopex gymnocercus, Hydrochaeris hydrochaeris, birds and fish (Siluriformes and Characiformes were recorded. Except Cavia aperea rodent and Dusicyon gimnocercus fox, all taxa show evidence of anthropic modification (cut marks, fresh fractures and burning. Two radiocarbon dates were obtained: 650 and 520 yrs. BP. The results reached in this study lead to the conclusion that the pre-Hispanic populations that occupied Cerro Tapera Vázquez by the end of the Late Holocene were riverine canoe peoples, with complex ceramic technology and subsistence based on hunting of coypu, capybara and cervids, fishing and small-scale horticulture.

  8. Geochemistry of the Neoproterozoic (800-767 Ma) Cerro Bori orthogneisses, Dom Feliciano Belt in Uruguay: tectonic evolution of an ancient continental arc

    Science.gov (United States)

    Lenz, C.; Porcher, C. C.; Fernandes, L. A. D.; Masquelin, H.; Koester, E.; Conceição, R. V.

    2013-10-01

    The Cerro Bori orthogneisses, crystallized between ca. 800 and 767 Ma, are composed of a sequence of mafic gneisses, with dioritic-gabbroic and dioritic composition tectonically interleaved with a sequence of tonalitic and granodioritic gneisses. These rocks intruded the Chafalote paragneisses (metapelites, semipelites, carbonate and mafic rocks) and they were metamorphosed of high P-T conditions at ca. 676-654 Ma. This paper presents the first major and trace geochemical signatures, as well as Sm and Pb isotopic composition for the Cerro Bori orthogneisses, which allow distinguishing three different groups of rocks. Type I rocks are mafic gneisses with tholeiitic affinity, whereas the Type II rocks are tonalitic and granodioritic gneisses with calc-alkaline affinity. The third type is composed of biotite-rich mafic gneisses with potassic and ultrapotassic affinities. All the three types of rocks have negative ℰND values (between -2.12 and -6.67) and old TDM ages (between 1.2 and 2.0 Ga), indicating that the process of crustal assimilation/contamination was an important process, together with fractional crystallization. An continental arc tectonic setting is suggested to this association of rocks between 800 and 767 Ma. This subduction suggests the existence of an ocean between Rio de La Plata and adjacent cratons during the break up of the Rodinia supercontinent.

  9. ANALISIS DEL CO-TRATAMIENTO PASIVO DE AGUAS RESIDUALES MUNICIPALES Y DRENAJE ACIDO DE MINAS EN CERRO RICO DE POTOSÍ, BOLIVIA

    Directory of Open Access Journals (Sweden)

    William H.J. Strosnider

    2015-01-01

    Full Text Available El drenaje acido de minas (DAM es un problema a nivel mundial. El co-tratamiento pasivo de DAM con aguas residuales municipales (ARM es una manera efectiva y de bajo costo que utiliza los nutrientes de ARM para tratar las concentraciones de metales y sulfato en DAM. Cerro Rico de Potosí, Bolivia es una de las grandes ciudades mineras en el mundo que tiene muchos problemas con el DAM. El objetivo de este estudio fue determinar velocidades de reacción de Al, Fe, Mn, Zn, y otros metales en DAM provenientes de un flujo de agua en Cerro Rico usando un sistema reactor de tres etapas. El DAM tenía un pH de 3.58, acidez de 1080 mg/L equivalente a CaCO3 conteniendo concentraciones de 12, 68, 17, y 550 mg/L de Al, Fe, Mn y Zn respectivamente. Las velocidades de reacción de Al, Fe, Mn y Zn fueron de 1.43, 2.09, 0.01 y 0.10 d-1, respectivamente.

  10. Edad, caracterización petrográfica y Geoquímica del Granitoide del Cerro Falkner, Neuquén

    Directory of Open Access Journals (Sweden)

    Sabrina Crosta

    2008-03-01

    Full Text Available El Cerro Falkner se halla constituido por rocas graníticas infrayacentes a las volcanitas de la Formación Ventana de edad paleógena. Dichos intrusivos son de composición granodiorítica, metaluminosos a peraluminosos, subalcalinos, con características de granitos de arco volcánico concordantes con otros granitoides del segmento norte de la Cordillera Patagónica Septentrional. La edad obtenida por el método K-Ar sobre anfíboles de composición tschermakítica (125 ± 20 Ma indica una edad mínima perteneciente al Cretácico inferior para la granodiorita del cerro Falkner, por lo que sería incorrecto utilizar la denominación Formación Los Machis (Cretácico superior para estas rocas. Esta edad, permite vincular las rocas graníticas del área de estudio con el volcanismo representado por el Grupo Divisadero de edad predominantemente cretácica inferior.

  11. Hydrothermal iron flux variability following rapid sea level changes

    Science.gov (United States)

    Middleton, Jennifer L.; Langmuir, Charles H.; Mukhopadhyay, Sujoy; McManus, Jerry F.; Mitrovica, Jerry X.

    2016-04-01

    Sea level changes associated with Pleistocene glacial cycles have been hypothesized to modulate melt production and hydrothermal activity at ocean ridges, yet little is known about fluctuations in hydrothermal circulation on time scales longer than a few millennia. We present a high-resolution record of hydrothermal activity over the past 50 ka using elemental flux data from a new sediment core from the Mir zone of the TAG hydrothermal field at 26°N on the Mid-Atlantic Ridge. Mir sediments reveal sixfold to eightfold increases in hydrothermal iron and copper deposition during the Last Glacial Maximum, followed by a rapid decline during the sea level rise associated with deglaciation. Our results, along with previous observations from Pacific and Atlantic spreading centers, indicate that rapid sea level changes influence hydrothermal output on mid-ocean ridges. Thus, climate variability may discretize volcanic processing of the solid Earth on millennial time scales and subsequently stimulate variability in biogeochemical interactions with volcanic systems.

  12. Impact of hydrothermalism on the ocean iron cycle

    Science.gov (United States)

    Tagliabue, Alessandro; Resing, Joseph

    2016-11-01

    As the iron supplied from hydrothermalism is ultimately ventilated in the iron-limited Southern Ocean, it plays an important role in the ocean biological carbon pump. We deploy a set of focused sensitivity experiments with a state of the art global model of the ocean to examine the processes that regulate the lifetime of hydrothermal iron and the role of different ridge systems in governing the hydrothermal impact on the Southern Ocean biological carbon pump. Using GEOTRACES section data, we find that stabilization of hydrothermal iron is important in some, but not all regions. The impact on the Southern Ocean biological carbon pump is dominated by poorly explored southern ridge systems, highlighting the need for future exploration in this region. We find inter-basin differences in the isopycnal layer onto which hydrothermal Fe is supplied between the Atlantic and Pacific basins, which when combined with the inter-basin contrasts in oxidation kinetics suggests a muted influence of Atlantic ridges on the Southern Ocean biological carbon pump. Ultimately, we present a range of processes, operating at distinct scales, that must be better constrained to improve our understanding of how hydrothermalism affects the ocean cycling of iron and carbon. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

  13. Effect of hydrothermal treatment of coal on its associative structure

    Energy Technology Data Exchange (ETDEWEB)

    Shui Heng-fu; Wang Zhi-cai; Wang Gao-qiang; Niu Min-feng [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

    2006-10-15

    4 bituminous coals with different ranks were thermally and hydrothermally treated under different conditions, and the raw and treated coals were extracted with carbon disulfide/N-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent (1:1 by volume). It is found that the extraction yields of the thermal or hydrothermal treated coals at proper conditions increase in different extent. The increments of extraction yields for hydrothermal treated coals are higher than those of thermal treated coals. FT-IR shows that the adsorption peaks at 3410 cm{sup -1} attributed to OH group for the hydrothermal treated coals decrease, suggesting the dissociation of the coal aggregation structure due to the breakage of hydrogen bonds, resulting in the increase of extraction yields for the treated coals. For higher rank coal, the removal of minerals and the dissociation of {pi}-cation association after hydrothermal treatment of coal may be responsible for the increase of extraction yield. In addition, the mechanism of hydrothermal treatment of coal was discussed. 15 refs., 2 figs., 5 tabs.

  14. Effect of artificial feeders on pollen loads of the hummingbirds of Cerro de la Muerte, Costa Rica.

    Science.gov (United States)

    Avalos, Gerardo; Soto, Alejandra; Alfaro, Willy

    2012-03-01

    Although sugar-water feeders are commonly used by enthusiasts to attract hummingbirds, little is known about how they affect hummingbird behavior and flower use. We studied the highland hummingbird assemblage of Cerro de La Muerte, Costa Rica, both at a site with permanent feeders (La Georgina Restaurant) and further from it. We examined how feeder use and monopolization affected seasonal changes in pollen loads during four sampling periods, including dry and wet seasons, from 2003-2005. We expected that species monopolizing the feeders would carry little or no pollen whatsoever, and would have pollen loads characterized by low floral diversity, in contrast with species less dependent on feeders. We obtained pollen samples from 183 individuals of four hummingbird species captured around the feeders using mist nets, which were compared with a pollen reference collection of plants with a pollination syndrome by hummingbirds. The same methods were implemented at a site 3km away from the feeders. Feeder usage was quantified by counting the number of times hummingbirds drank from the feeders in periods of 4min separated by 1min. The effects of hummingbird species and season on pollen load categories were assessed using a nominal logistic regression. The alpha species at the site, the Fiery-throated Hummingbird (Panterpe insignis), dominated the feeders during the dry season. Meanwhile, in the wet season, feeder usage was more evenly distributed across species, with the exception of the Volcano Hummingbird, Selasphorus flammula, which occupies the last place in the dominance hierarchy. Pollen loads of hummingbirds captured near feeders were low in abundance (more than 50% of captured individuals had zero or low pollen loads), and low in species richness (96% of the hummingbirds with pollen from only one plant genus, Centropogon). Overall pollen loads increased during the dry season coinciding with peaks in flower availability, although the majority of captured

  15. Hydrothermal Gasification for Waste to Energy

    Science.gov (United States)

    Epps, Brenden; Laser, Mark; Choo, Yeunun

    2014-11-01

    Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

  16. Complexation of Si in Hydrothermal Systems

    Institute of Scientific and Technical Information of China (English)

    樊文苓; 王声远; 田弋夫; 陈紫新

    2001-01-01

    The Au-SiO2 and Sn-SiO2 complexes have been experimentally calibrated at varying temperature, silica concentration and pH:Au+ + H3SiO4-=AuH3SiO4 lgK = - 1. 65436 + 9611.21/TSn4 + + 4H3SiO4-=Sn(H3SiO4)4 lgK200℃ = 42.73Compared with Au-Cl, Au-HS and Sn-OH complexes, AuH3SiO4 and Sn(H3SiO4)4 complexes can be recognized as the dominant transport forms in Si-bearing solutions under pH and Eh con ditions of general interest. The decrease of SiO2 concentration and oxygen fugacity would re verse the direction of dissolution-complexing reactions, resulting in the precipitation of gold and silica, as well as cassiterite and silica. This study illustrates the significance of SiO2-complexa tion in hydrothermal solutions for gold, tin and other metallizations.

  17. Structure of the Wagner Basin in the Northern Gulf of California From Interpretation of Seismic Reflexion Data

    Science.gov (United States)

    Gonzalez, M.; Aguilar, C.; Martin, A.

    2007-05-01

    The northern Gulf of California straddles the transition in the style of deformation along the Pacific-North America plate boundary, from distributed deformation in the Upper Delfin and Wagner basins to localized dextral shear along the Cerro Prieto transform fault. Processing and interpretation of industry seismic data adquired by Petroleos Mexicanos (PEMEX) allow us to map the main fault structures and depocenters in the Wagner basin and to unravel the way strain is transferred northward into the Cerro Prieto fault system. Seismic data records from 0.5 to 5 TWTT. Data stacking and time-migration were performed using semblance coefficient method. Subsidence in the Wagner basin is controlled by two large N-S trending sub-parallel faults that intersect the NNW-trending Cerro Prieto transform fault. The Wagner fault bounds the eastern margin of the basin for more than 75 km. This fault dips ~50° to the west (up to 2 seconds) with distinctive reflectors displaced more than 1 km across the fault zone. The strata define a fanning pattern towards the Wagner fault. Northward the Wagner fault intersects the Cerro Prieto fault at 130° on map view and one depocenter of the Wagner basin bends to the NW adjacent to the Cerro Prieto fault zone. The eastern boundary of the modern depocenter is the Consag fault, which extends over 100 km in a N-S direction with an average dip of ~50° (up to 2s) to the east. The northern segment of the Consag fault bends 25° and intersects the Cerro Prieto fault zone at an angle of 110° on map view. The acoustic basement was not imaged in the northwest, but the stratigraphic succession increases its thickness towards the depocenter of the Wagner basin. Another important structure is El Chinero fault, which runs parallel to the Consag fault along 60 km and possibly intersects the Cerro Prieto fault to the north beneath the delta of the Colorado River. El Chinero fault dips at low-angle (~30°) to the east and has a vertical offset of about 0

  18. The potential hydrothermal systems unexplored in the Southwest Indian Ocean

    Science.gov (United States)

    Suo, Yanhui; Li, Sanzhong; Li, Xiyao; Zhang, Zhen; Ding, Dong

    2017-01-01

    Deep-sea hydrothermal vents possess complex ecosystems and abundant metallic mineral deposits valuable to human being. On-axial vents along tectonic plate boundaries have achieved prominent results and obtained huge resources, while nearly 90% of the global mid-ocean ridge and the majority of the off-axial vents buried by thick oceanic sediments within plates remain as relatively undiscovered domains. Based on previous detailed investigations, hydrothermal vents have been mapped along five sections along the Southwest Indian Ridge (SWIR) with different bathymetry, spreading rates, and gravity features, two at the western end (10°-16°E Section B and 16°-25°E Section C) and three at the eastern end (49°-52°E Section D, 52°-61°E Section E and 61°-70°E Section F). Hydrothermal vents along the Sections B, C, E and F with thin oceanic crust are hosted by ultramafic rocks under tectonic-controlled magmatic-starved settings, and hydrothermal vents along the Section D are associated with exceed magmatism. Limited coverage of investigations is provided along the 35°-47°E SWIR (between Marion and Indomed fracture zones) and a lot of research has been done around the Bouvet Island, while no hydrothermal vents has been reported. Analyzing bathymetry, gravity and geochemical data, magmatism settings are favourable for the occurrence of hydrothermal systems along these two sections. An off-axial hydrothermal system in the southern flank of the SWIR that exhibits ultra-thin oceanic crust associated with an oceanic continental transition is postulated to exist along the 100-Ma slow-spreading isochron in the Enderby Basin. A discrete, denser enriched or less depleted mantle beneath the Antarctic Plate is an alternative explanation for the large scale thin oceanic crust concentrated on the southern flank of the SWIR.

  19. Chatkalita, nekrasovita y otros minerales del grupo de la estannita de Veta María Eugenia, Cerro Atajo, Catamarca Chatkalita, nekrasovita y otros minerales del grupo de la estannita de veta María Eugenia, Cerro Atajo, Catamarca

    Directory of Open Access Journals (Sweden)

    M. F. Márquez-Zavalía

    2007-06-01

    Full Text Available En veta María Eugenia, Cerro Atajo, Catamarca, se encontró una asociación de minerales de estaño integrada por: chatkalita Cu6Fe2+Sn2S8, nekrasovita Cu26V2(Sn,As,Sb6S32, colusita Cu26V2(As,Sn,Sb6S32, kësterita Cu2(Zn,FeSnS4 y estannoidita Cu8(Fe,Zn3Sn2S12. Estos minerales, incluidos en watanabeíta, están acompañados principalmente por pirita, esfalerita, calcopirita, tetraedrita, bornita y galena; aikinita, enargita, luzonita, marcasita, arsenopirita y pirrotina participan como minerales accesorios. Chatkalita se presenta en agregados irregulares de hasta 40 µm, asociados con kësterita y estannoidita, es de color rosa-anaranjado claro, birreflectante y anisótropa, con colores de polarización pardos; su composición química (% en peso es: S=29,76-30,37, Fe=4,53-7,92, Cu=39,13-43,21, Zn=0,75-5,53, As=0,19- 2,42, Sn=15,27-20,50 y Sb=0,00-0,32. Nekrasovita es isótropa, de color pardo con leve tinte rosa-violáceo y está asociada con estannoidita; su composición química es: S=30,29-30,63, Fe=3,41-4,75, Cu=44,26-45,70, Zn=0,56-1,00, As=4,18-4,71, Sn=12,53-13,64 y Sb=0,71- 0,77. Colusita es pardo amarillenta, isótropa, se presenta como parches irregulares y cintas discontinuas en tennantita; su composición química es: S=30,59-30,74, Fe=2,18-3,58, Cu=47,22-48,13, Zn=0,21-0,64, As=6,38-6,61, Sn=9,04-9,33 y Sb=0,49-1,66. Kësterita es pardo grisácea, con débil birreflectancia y anisotropía y colores de polarización pardos, a menudo se presenta bordeada por chatkalita; su composición química es: S=28,68-29,14, Fe=1,98-2,14, Cu=31,06-32,51, Zn=9,03-11,57 y Sn=26,39-27,03. Estannoidita es de color castaño, pleocroica (castaño-rosado a pardo-grisáceo y anisótropa con colores de polarización pardos y pardo-amarillentos, ocurre en parches irregulares y como bandas bordeando tennantita; su composición química es: S=29,11-29,83, Fe=8,45-10,30, Cu=38,05-41,01, Zn=3,18-4,90, y Sn=15,84-18,94. La reflectividad y dureza de pulido de

  20. Phreatic and Hydrothermal Explosions: A Laboratory Approach

    Science.gov (United States)

    Scheu, B.; Dingwell, D. B.

    2010-12-01

    Phreatic eruptions are amongst the most common eruption types on earth. They might be precursory to another type of volcanic eruption but often they stand on their one. Despite being the most common eruption type, they also are one of the most diverse eruptions, in appearance as well as on eruption mechanism. Yet steam is the common fuel behind all phreatic eruptions. The steam-driven explosions occur when water beneath the ground or on the surface is heated by magma, lava, hot rocks, or fresh volcanic deposits (such as ignimbrites, tephra and pyroclastic-flow deposits) and result in crater, tuff rings and debris avalanches. The intense heat of such material may cause water to boil and flash to steam, thereby generating an explosion of steam, water, ash, blocks, and bombs. Another wide and important field affected by phreatic explosions are hydrothermal areas; here phreatic explosions occur every few months creating explosion craters and resemble a significant hazard to hydrothermal power plants. Despite of their hazard potential, phreatic explosions have so far been overlooked by the field of experimental volcanology. A part of their hazard potential in owned by the fact that phreatic explosions are hardly predictable in occurrence time and size as they have manifold triggers (variances in groundwater and heat systems, earthquakes, material fatigue, water level, etc..) A new set of experiments has been designed to focus on this phreatic type of steam explosion, whereas classical phreatomagmatic experiments use molten fuel-coolant interaction (e.g., Zimanowski, et al., 1991). The violent transition of the superheated water to vapour adds another degree of explosivity to the dry magmatic fragmentation, driven mostly by vesicle bursting due to internal gas overpressure. At low water fractions the fragmentation is strongly enforced by the mixture of these two effects and a large fraction of fine pyroclasts are produced, whereas at high water fraction in the sample the

  1. Hydrothermal synthesis of pyrochlores and their characterization

    Science.gov (United States)

    Redkin, Alexander F.; Ionov, Andrey M.; Kotova, Nataliya P.

    2013-10-01

    Pyrochlores, microlites, and U-betafites of pyrochlore group minerals were obtained from mixing experiments of the corresponding oxides and fluorides by hydrothermal synthesis at T = 800 °C and P = 200 MPa in the solution of 1.0 M NaF. The presence of U4+ in pyrochlore does not affect the cell parameter, which for the phases of pyrochlore-microlite series is 10.42 ± 0.01 Å. In a system with an excess of UO2, pyrochlores and microlites, containing uranium up to 0.2-0.3 atoms per formula unit (apfu), are formed. In the uranium-free system of betafites composition, perovskites and Ti-bearing pyrochlores are formed. U-pyrochlores of betafite series, containing 2Ti = Nb + Ta in moles, have cubic cell parameters of 10.26 ± 0.02 Å and U4+ isomorphic capacity of 0.4-0.5 apfu. In the pyrochlore structure, U4+ may substitute for Ca2+ and Na+ cations in the eightfold site. In pyrochlores of pyrochlore-microlite series, Ca2+ is replaced by U4+, while in pyrochlores of betafite series, U4+ replaces Na+. Phases with pyrochlore structure, containing U5+ and U6+ in the sixfold site, usually occupied by Nb5+, Ta5+, and Ti4+, are formed under oxidizing conditions (Cu-Cu2O buffer). They are characterized by low content of Nb5+, Ta5+ (<0.1 apfu), and anomalous behavior of the crystal lattice (compression, instead of expansion). Under natural conditions, the formation of pyrochlores containing a significant amount of U5+ and U6+ is unlikely.

  2. Properties and degradability of hydrothermal carbonization products.

    Science.gov (United States)

    Eibisch, Nina; Helfrich, Mirjam; Don, Axel; Mikutta, Robert; Kruse, Andrea; Ellerbrock, Ruth; Flessa, Heinz

    2013-09-01

    Biomass carbonized via hydrothermal carbonization (HTC) yields a liquid and a carbon (C)-rich solid called hydrochar. In soil, hydrochars may act as fertilizers and promote C sequestration. We assumed that the chemical composition of the raw material (woodchips, straw, grass cuttings, or digestate) determines the properties of the liquid and solid HTC products, including their degradability. Additionally, we investigated whether easily mineralizable organic components adsorbed on the hydrochar surface influence the degradability of the hydrochars and could be removed by repetitive washing. Carbon mineralization was measured as CO production over 30 d in aerobic incubation experiments with loamy sand. Chemical analysis revealed that most nutrients were preferably enriched in the liquid phase. The C mineralization of hydrochars from woodchips (2% of total C added), straw (3%), grass (6%), and digestate (14%) were dependent on the raw material carbonized and were significantly lower (by 60-92%; < 0.05) than the mineralization of the corresponding raw materials. Washing of the hydrochars significantly decreased mineralization of digestate-hydrochar (up to 40%) but had no effect on mineralization rates of the other three hydrochars. Variations in C mineralization between different hydrochars could be explained by multiple factors, including differences in the O/C-H/C ratios, C/N ratios, lignin content, amount of oxygen-containing functional groups, and pH. In contrast to the solids, the liquid products were highly degradable, with 61 to 89% of their dissolved organic C being mineralized within 30 d. The liquids may be treated aerobically (e.g., for nutrient recovery).

  3. Mapping the edge of the Cerros del Rio volcanic field, New Mexico: a piece of the puzzle to understanding a potential geothermal resource

    Science.gov (United States)

    Pellerin, L.; Gallegos, M.; Goebel, M.; Murphy, B. S.; Smith, J.; Soto, D.; Swiatlowski, J.; Volk, C.; Welch, M.; Feucht, D. W.; Hollingshaus, B.; Bedrosian, P. A.; McPhee, D. K.

    2012-12-01

    The Cerros del Rio volcanic field located west of Santa Fe, New Mexico spans the southwestern part of the Espanola Basin with the Rio Grande to the west. Underlying the volcanics are the Santa Fe Group sediments, which contain the Ancha Formation, an important aquifer in the region. High temperature gradients in water wells reveal a potential geothermal prospect. In 2012 the Summer of Applied Geophysical Experience (SAGE) program acquired transient electromagnetic (TEM), audiomagnetotelluric (AMT), gravity and ground magnetic data to determine the buried eastern margin of the volcanic field and the connectivity related to the underlying sediments. The roughly EW 5-km long transect was sited from USGS aeromagnetic data to cross the boundary of the Cerros del Rio volcanic field. TEM data collected at ten stations, at 200-400 m spacing, along the transect employed an in-loop configuration with a square 100 m x 100 m transmitter loop and both a Zonge receiver coil and a 5 m square receiver loop. The 5 m loop allowed for the recovery of early-time data that was saturated when using the Zonge coil. AMT data were acquired at eight stations, at 400-500 m spacing, using the Geometric Stratagem system recording from 92 kHz to 10 Hz; a horizontal magnetic dipole transmitter was used to augment low signal strength at around 1 kHz. Gravity data along the profile were acquired using CG-3 and CG-5 Scintrex gravimeters with a station interval >250 m. Magnetic data were acquired with a Geometrics Cesium vapor G-858 magnetometer for about 3500 m along the profile at a 0.5 second sampling rate. Two volcanic flows interbedded with Ancha Formation and overlying Santa Fe Group sediments were identified in both the TEM and AMT modeling. High surface resistivity zones (>300 ohm-m) with depths ranging from ~100 to 300 m define the volcanic flows and correspond to high densities (2.3 to 2.55 g/cm3), while low resistivity zones (<30 ohm-m) correspond to lower densities (~2.1 g/cm3). High

  4. Impact-generated Hydrothermal Activity at the Chicxulub Crater

    Science.gov (United States)

    Kring, D. A.; Zurcher, L.; Abramov, O.

    2007-05-01

    Borehole samples recovered from PEMEX exploration boreholes and an ICDP scientific borehole indicate the Chicxulub impact event generated hydrothermal alteration throughout a large volume of the Maya Block beneath the crater floor and extending across the bulk of the ~180 km diameter crater. The first indications of hydrothermal alteration were observed in the crater discovery samples from the Yucatan-6 borehole and manifest itself in the form of anhydrite and quartz veins. Continuous core from the Yaxcopoil-1 borehole reveal a more complex and temporally extensive alteration sequence: following a brief period at high temperatures, impact- melt-bearing polymict breccias and a thin, underlying unit of impact melt were subjected to metasomatism, producing alkali feldspar, sphene, apatite, and magnetite. As the system continued to cool, smectite-series phyllosilicates appeared. A saline solution was involved. Stable isotopes suggest the fluid was dominated by a basinal brine created mostly from existing groundwater of the Yucatan Peninsula, although contributions from down-welling water also occurred in some parts of the system. Numerical modeling of the hydrothermal system suggests circulation occurred for 1.5 to 2.3 Myr, depending on the permeability of the system. Our understanding of the hydrothermal system, however, is still crude. Additional core recovery projects, particularly into the central melt sheet, are needed to better evaluate the extent and duration of hydrothermal alteration.

  5. Chatkalita, nekrasovita y otros minerales del grupo de la estannita de Veta María Eugenia, Cerro Atajo, Catamarca

    Directory of Open Access Journals (Sweden)

    M. F. Márquez-Zavalía

    2007-06-01

    Full Text Available En veta María Eugenia, Cerro Atajo, Catamarca, se encontró una asociación de minerales de estaño integrada por: chatkalita Cu6Fe2+Sn2S8, nekrasovita Cu26V2(Sn,As,Sb6S32, colusita Cu26V2(As,Sn,Sb6S32, kësterita Cu2(Zn,FeSnS4 y estannoidita Cu8(Fe,Zn3Sn2S12. Estos minerales, incluidos en watanabeíta, están acompañados principalmente por pirita, esfalerita, calcopirita, tetraedrita, bornita y galena; aikinita, enargita, luzonita, marcasita, arsenopirita y pirrotina participan como minerales accesorios. Chatkalita se presenta en agregados irregulares de hasta 40 µm, asociados con kësterita y estannoidita, es de color rosa-anaranjado claro, birreflectante y anisótropa, con colores de polarización pardos; su composición química (% en peso es: S=29,76-30,37, Fe=4,53-7,92, Cu=39,13-43,21, Zn=0,75-5,53, As=0,19- 2,42, Sn=15,27-20,50 y Sb=0,00-0,32. Nekrasovita es isótropa, de color pardo con leve tinte rosa-violáceo y está asociada con estannoidita; su composición química es: S=30,29-30,63, Fe=3,41-4,75, Cu=44,26-45,70, Zn=0,56-1,00, As=4,18-4,71, Sn=12,53-13,64 y Sb=0,71- 0,77. Colusita es pardo amarillenta, isótropa, se presenta como parches irregulares y cintas discontinuas en tennantita; su composición química es: S=30,59-30,74, Fe=2,18-3,58, Cu=47,22-48,13, Zn=0,21-0,64, As=6,38-6,61, Sn=9,04-9,33 y Sb=0,49-1,66. Kësterita es pardo grisácea, con débil birreflectancia y anisotropía y colores de polarización pardos, a menudo se presenta bordeada por chatkalita; su composición química es: S=28,68-29,14, Fe=1,98-2,14, Cu=31,06-32,51, Zn=9,03-11,57 y Sn=26,39-27,03. Estannoidita es de color castaño, pleocroica (castaño-rosado a pardo-grisáceo y anisótropa con colores de polarización pardos y pardo-amarillentos, ocurre en parches irregulares y como bandas bordeando tennantita; su composición química es: S=29,11-29,83, Fe=8,45-10,30, Cu=38,05-41,01, Zn=3,18-4,90, y Sn=15,84-18,94. La reflectividad y dureza de pulido de

  6. Jurassic tetrapods and flora of Cañadón Asfalto Formation in Cerro Cóndor area, Chubut Province Flora y tetrápodos del Jurásico de la Formación Cañadón Asfalto en el área de Cerro Cóndor, provincia de Chubut

    OpenAIRE

    2008-01-01

    The plant and tetrapod fossil record of the Cañadón Asfalto Formation (Middle to Late Jurassic) found in Cerro Cóndor area (Chubut Province) is summarized here. The flora is dominated by conifers (Araucariaceae, Cupressaceae sensu lato) but also includes ferns and equisetaleans. The tetrapod fauna is composed of dinosaur taxa described in the 70's as well as other remains recently described and other vertebrate groups such as amphibians, turtles, and mammals. The amphibian remains have been i...

  7. Al Este del Cerro Pampa: ampliación del área de disponibilidad de obsidiana de la Pampa del Asador (Provincia de Santa Cruz East of the Cerro Pampa: enlargement of the obsidian availability area from Pampa del Asador (Santa Cruz Province

    Directory of Open Access Journals (Sweden)

    Juan Bautista Belardi

    2006-12-01

    Full Text Available La Pampa del Asador ha sido identificada como el lugar de proveniencia de distintos tipos de obsidiana, mayoritariamente negra, y el Cerro Pampa, ubicado en el extremo suroeste de la pampa, ha sido un punto central a partir del cual se ha medido la dispersión de los artefactos confeccionados en esta materia prima. Sobre la base de la interpretación de imágenes satelitales, análisis químicos y trabajos de campo se presenta y discute la evidencia provista por nódulos y artefactos de obsidiana recuperados en paleocauces y un abanico aluvial que se origina en la Pampa del Asador. Los resultados muestran la ampliación del área de disponibilidad de obsidiana 65 km hacia el este y 75 km al noreste del Cerro Pampa y, aunque presentando menor frecuencia relativa de nódulos y el decrecimiento de sus tamaños, el área se amplía a lo largo de la Pampa La Chispa. Estos resultados tienen implicaciones tanto en términos de la distribución de frecuencias de artefactos de obsidiana en el registro arqueológico regional como en los costos de aprovisionamiento de la roca.Pampa del Asador has been identified as the source of distinct types of obsidian (generally black, and Cerro Pampa, located in the extreme southwest of the Pampas, has been the central point from which the dispersal of artifacts fashioned from this obsidian has been measured. Based on the interpretation of satellite images, geochemical analysis, and field work, we present and discuss evidence provided by nodules and artifacts of obsidian recovered from paleo-drainage channels and an alluvial fan which originates in Pampa del Asador. The results expand the area of availability of obsidian 65 km east and 75 km northeast of Cerro Pampa, and also across Pampa La Chispa, although the relative frequency of nodules decreases and smaller size increases. These results have implications both in terms of the distribution and frequency of obsidian artifacts in the regional archaeological record

  8. Contrasting compositional trends of rocks and olivine-hosted melt inclusions from Cerro Negro volcano (Central America): implications for decompression-driven fractionation of hydrous magmas

    Science.gov (United States)

    Portnyagin, Maxim V.; Hoernle, Kaj; Mironov, Nikita L.

    2014-10-01

    Melt inclusions in olivine Fo83-72 from tephras of 1867, 1971 and 1992 eruptions of Cerro Negro volcano represent a series of basaltic to andesitic melts of narrow range of MgO (5.6-8 wt %) formed by ~46 wt % fractional crystallization of olivine (~6 wt %), plagioclase (~27 wt %), pyroxene (~13 wt %) and magnetite (high-Mg basalts reflects the process of phenocryst re-distribution in progressively evolving melt. The crystallization scenario is anticipated to operate everywhere in dykes feeding basaltic volcanoes and can explain the predominance of plagioclase-rich high-Al basalts in island arc as well as typical compositional variations of magmas during single eruptions.

  9. Procesos históricos y ambientales en Cerro de San Pedro, San Luis Potosí, México, 1948-1997

    Directory of Open Access Journals (Sweden)

    Paula Andrea Martínez Chaves

    2010-01-01

    Full Text Available Los estudios sobre el municipio Cerro de San Pedro enfatizan la continuidad ambiental aparente que estimula la minería; sin embargo, esta lectura subvalora otras dinámicas que ocurren en la zona. Con base en observaciones directas de trabajo en campo, para realizar análisis de coberturas vegetales, entrevistas con los habitantes de la zona, revisión de cartografía e investigación de archivo, el presente trabajo muestra procesos como la explotación de recursos vegetales y el pastoreo, como actividades económicas paralelas a las labores mineras, y que no habían sido tratados hasta ahora.

  10. Zonificación ecológica del cerro "El Potosí", Galeana, Nuevo León, México

    Directory of Open Access Journals (Sweden)

    Mario A. García A.

    1999-01-01

    Full Text Available Como parte de la propuesta para definir al cerro "El Potosi" como Reserva Especial de la Biosfera, se elaboró un mapa de zonificacion que considera las zonas núcleo, de amortiguamiento y de recuperacion de habitat. Los criterios para la zonificación se consideraron la distribución de la vegetación y las poblaciones de fauna silvestre, derivada de la interpretacion cartográfica elaborada ad hoc, utilizand una imagen de stélite, además de la información sobre la biodiversidad. Se definiereon para la región diez tipos de vegetación y cuatro tipos de uso del suelo, en donde se distribuyen 45 especies bajo estatus de conservación: 19 de plantas y 26 de animales

  11. Approaching viscosity control: electrical heating of extra heavy oil as alternative to diluent injection in down hole in Cerro Negro Field, Faja Petrolifera del Orinoco

    Energy Technology Data Exchange (ETDEWEB)

    Salazar, Manuel [Petroleos de Venezuela SA, PDVSA (Venezuela)

    2011-07-01

    Electrical heating is a method used to enhance oil recovery in extra heavy oil reservoirs. This method can be used when diluent injection or other methods are not able to reduce oil viscosity sufficiently or when problems of product quality or quantity arise. The aim of this paper is to evaluate the performance of electrical heating, individually and simultaneously with injection of diluents. For this purpose, simulations were undertaken in one well with integrated electrical heating and diluent injection in Cerro Negro Field in the Orinoco oil belt, Venezuela. Results have shown that the application of both methods together is more profitable than the application of electrical heating alone. This paper demonstrated that the use of electrical heating and diluent injection combined is a valid alternative to diluent injection alone, reducing production loss.

  12. Fractionation of Boron Isotopes in Icelandic Hydrothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Aggarwal, J.K.; Palmer, M.R.

    1995-01-01

    Boron isotope ratios have been determined in a variety of different geothermal waters from hydrothermal systems across Iceland. Isotope ratios from the high temperature meteoric water recharged systems reflect the isotope ratio of the host rocks without any apparent fractionation. Seawater recharged geothermal systems exhibit more positive {delta}{sup 11}B values than the meteoric water recharged geothermal systems. Water/rock ratios can be assessed from boron isotope ratios in the saline hydrothermal systems. Low temperature hydrothermal systems also exhibit more positive {delta}{sup 11}B than the high temperature systems, indicating fractionation of boron due to adsorption of the lighter isotope onto secondary minerals. Fractionation of boron in carbonate deposits may indicate the level of equilibrium attained within the systems.

  13. A NOVEL HYDROTHERMAL SYNTHESIS METHOD FOR BARIUM FERRITE

    Institute of Scientific and Technical Information of China (English)

    Kang Li; Hongchen Gu; Qun Wei

    2004-01-01

    In the present work, fine barium ferrite powder has been synthesized through a one-step hydrothermal process in an autoclave at [OH-]/[Cl-] ratio of 2:1 in the temperature range from 180 to 260 ℃ using barium chloride (BaCl2), ferrous chloride (FeCl2) and potassium nitrate (KNO3) as the starting materials. Both particle size and saturation magnetization (Ms) increase with increasing hydrothermal reaction temperature, while the intrinsic coercivity (iHc) peaks at 685 Oe at 230 ℃. Morphology progress from the barium ferrite precursor particles to the barium hexaferrite particles has been monitored with increasing hydrothermal reaction time at 230 ℃ in the autoclave.

  14. Coordination Hydrothermal Interconnection Java-Bali Using Simulated Annealing

    Science.gov (United States)

    Wicaksono, B.; Abdullah, A. G.; Saputra, W. S.

    2016-04-01

    Hydrothermal power plant coordination aims to minimize the total cost of operating system that is represented by fuel costand constraints during optimization. To perform the optimization, there are several methods that can be used. Simulated Annealing (SA) is a method that can be used to solve the optimization problems. This method was inspired by annealing or cooling process in the manufacture of materials composed of crystals. The basic principle of hydrothermal power plant coordination includes the use of hydro power plants to support basic load while thermal power plants were used to support the remaining load. This study used two hydro power plant units and six thermal power plant units with 25 buses by calculating transmission losses and considering power limits in each power plant unit aided by MATLAB software during the process. Hydrothermal power plant coordination using simulated annealing plants showed that a total cost of generation for 24 hours is 13,288,508.01.

  15. Chalcophile Siderophile Trace Element Systematics of Hydrothermal Pyrite from Martian Regolith Breccia NWA 7533

    Science.gov (United States)

    Lorand, J.-P.; Hewins, R. H.; Humayun, M.; Remusat, L.; Zanda, B.; La, C.; Pont, S.

    2016-08-01

    Martian impact breccia NWA 7533 contains hydrothermal pyrite. Laser ablation ICPMS analyses show that its chalcophile siderophile element content was inherited from both early meteorite bombardment and later hydrothermal inputs from H2S fluids.

  16. Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

    Science.gov (United States)

    Plumlee, Geoffrey S.; Ridley, W. Ian

    1992-01-01

    Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

  17. El Cerro de los Santos: paisaje, negociación social y ritualidad entre el mundo ibérico y el hispano

    Directory of Open Access Journals (Sweden)

    García Cardiel, Jorge

    2015-12-01

    Full Text Available The Iberian shrine of Cerro de los Santos is located next to one of the main roads in the Southeast of the Meseta, in the middle of an area without any town of some entity. This paper aims to highlight its status as a shrine of passage, i.e. as a sacred, safe point where voyagers could rest overnight under the protection of the god. The creation of a statio by the Romans in such a place and its dedication to the goddess Pales provide more circumstantial evidence for this theory. Furthermore, some domestic material contexts can be defined, probably connected with this activity, and clearly different from the well-known ritual contexts of the shrine.La ubicación del santuario ibérico del Cerro de los Santos junto a una de las principales vías de comunicación del sureste meseteño y en el centro de una comarca desprovista de núcleos urbanos de cierta entidad permite subrayar en este artículo su uso continuado como santuario de paso, lugar sacro y seguro al que los caminantes podrían acogerse para pernoctar bajo la protección de la divinidad. La creación de una statio en el enclave en época romana y su dedicación a la diosa Pales no son sino argumentos ulteriores en este sentido. Se identifican además contextos materiales domésticos, distintos de los espacios de culto bien conocidos del santuario, relacionables con esta otra actividad.

  18. Evolución magmática del Granito Peñón Rosado, Cerro Asperecito, flanco occidental de la sierra de Famatina

    Directory of Open Access Journals (Sweden)

    J.A. Dahlquist

    2006-03-01

    Full Text Available El granate es un mineral accesorio poco común en rocas ígneas y constituye un tema relevante de la petrología ígnea. Estudios combinados de petrología, química mineral, geoquímica de roca total y geoquímica isotópica en el cerro Asperecito indican que los granitoides con granate que forman el Granito Peñón Rosado (GPR fueron producidos por la fusión parcial de rocas metasedimentarias con subsecuente diferenciación durante su emplazamiento en el Ordovícico inferior-medio. En este sentido, la facies GPR1 representa un cristalizado temprano, la facies GPR2 representa un fundido diferenciado, y la facies GPR3 un fundido residual. El Granito Peñón Rosado, fue emplazado en condiciones de moderada temperatura (785ºC y presión media (4,4 kb en profundidades de la corteza media (~15 km. El emplazamiento casi sincrónico en la corteza media de una abundante suite metaluminosa durante el Ordovícico inferior-medio (468 Ma en el cerro Asperecito fue suficiente para inducir anatexis local de los metasedimentos circundantes. Los contenidos de elementos mayoritarios (CaO, Na2O y elementos traza (Rb, Sr, Ba en el Granito Peñón Rosado sugieren anatexis a partir de un material inmaduro acumulado en un plataforma continental. Así, el Granito Peñón Rosado es un típico granitoide tipo-S con granate y el modelo establecido aquí puede contribuir a un mejor entendimiento acerca de la cristalización del granate en rocas graníticas.

  19. Cambio del uso de la tierra y pérdida de la cobertura boscosa, comunidades agrarias Sechina, La Ensenada y Cerro San Gil, Izabal Guatemala

    Directory of Open Access Journals (Sweden)

    Eddi Alejandro Vanegas Chacón

    2016-07-01

    Full Text Available En Guatemala, pocas temáticas son abordadas con tanta pasión como el acceso a la tierra y sus relaciones de productividad. Ante el juicio histórico y la evidencia de las estadísticas se deslumbra que las políticas agrarias de los últimos cincuenta años, si bien mitigaron la pobreza en el agro rural conllevaron con ellas daños ambientales irreversibles y deudas agrarias millonarias. Se estudió la dinámica del cambio de uso de la tierra y la pérdida de la cobertura boscosa en las comunidades agrarias beneficiadas por la Ley de Transformación Agraria, Sechina, La Ensenada y Cerro San Gil ubicadas en el departamento de Izabal. Se utilizó fotointerpretación y se realizaron estudios semidetallados de la intensidad de la tierra para el periodo 1958 a 2010. Se concluyó que bajo las premisas de “mejora a la tierra” de la Ley de Transformación Agraria ocurrió cambio de uso y cobertura de la tierra, de forestal a agropecuaria, en las comunidades agrarias Sechina 42%, La Ensenada 46,2% y Cerro San Gil 48,6%, donde se promovieron sistemas de aprovechamiento agrícola que conllevaron al sobre-uso de las tierras en 42%, 78% y 30%, respectivamente. Esto sugiere, que la adquisición de la tierra no es el fin, más bien es el medio, para promover desarrollo rural sostenible, a través de acompañamiento técnico agropecuario, monitoreo y evaluación tanto económica como ambiental.

  20. Entre el sueño del proyecto y la lógica del lugar. La arquitectura imposible de los cerros de Valparaíso

    Directory of Open Access Journals (Sweden)

    Pablo M. Millán-Millán

    2016-04-01

    Full Text Available Valparaíso es el resultado de la unión de dos ciudades en una: la ciudad vertical de los cerros y la ciudad horizontal del Plan –parte plana–. Esta doble naturaleza ha ido configurando una dualidad obligada a convivir y a establecer un continuo diálogo, acabando en la mayoría de los casos en conflicto. Si por un lado está la ciudad global y ortogonal como resultado de la ocupación europea, por otro lado estará la ciudad onírica agarrada a los acantilados ajena a cualquier orden preestablecido. Cada una de estas dos ciudades irá materializando su propia arquitectura: una real y estandarizada, propia de cualquier periferia de ciudad, y otra imposible. Será esta segunda la que vaya evolucionando en un intento continuo de adaptación y será el propio lugar el encargado de rechazar cualquier construcción que no le sea propia. Esta dicotomía quedará plasmada en numerosos proyectos que nunca verán la luz. El objetivo del artículo será mostrar, a partir de numerosos proyectos inéditos descubiertos en Valparaíso, cómo la arquitectura pensada para los cerros nunca llegó a construirse y fue dando paso a unas construcciones a medio camino entre lo real y lo imaginario, entre la lógica y el sueño.

  1. 峰与谷:两个牛仔的情感轨迹访《断背山》摄影罗德里戈·普瑞托%Interview with Rodrigo Prieto, Cinematographer of Brokeback Mountain

    Institute of Scientific and Technical Information of China (English)

    约翰·柯洪; 许斌

    2007-01-01

    @@ 引言 美国摄影师罗德里戈·普瑞托(Rodrigo Prieto)2007年与李安导演合作拍摄由张爱玲小说改编的电影,引起了国内电影制作者及媒体的广泛关注.作为当今好莱坞摄影师的中坚力量,罗德里戈·普瑞托的其他电影摄影作品均掷地有声,、、、、、、都是影迷们耳熟能详的作品,其中在今年各个电影节都有重大斩获,获得了多项大奖,更是在威尼斯电影节上获得金狮奖,并获得奥斯卡最佳导演、最佳改编剧本、最佳配乐三项大奖.于是我们从杂志上翻译了普瑞托关于的摄影访谈,来与读者共同了解这位摄影师与李安导演的工作细节,共同学习普瑞托的工作方法.

  2. Integrated analysis of hydrothermal flow through pretreatment

    Directory of Open Access Journals (Sweden)

    Archambault-Leger Veronique

    2012-07-01

    Full Text Available Abstract Background The impact of hydrothermal flowthrough (FT pretreatment severity on pretreatment and solubilization performance metrics was evaluated for three milled feedstocks (corn stover, bagasse, and poplar and two conversion systems (simultaneous saccharification and fermentation using yeast and fungal cellulase, and fermentation by Clostridium thermocellum. Results Compared to batch pretreatment, FT pretreatment consistently resulted in higher XMG recovery, higher removal of non-carbohydrate carbon and higher glucan solubilization by simultaneous saccharification and fermentation (SSF. XMG recovery was above 90% for FT pretreatment below 4.1 severity but decreased at higher severities, particularly for bagasse. Removal of non-carbohydrate carbon during FT pretreatment increased from 65% at low severity to 80% at high severity for corn stover, and from 40% to 70% for bagasse and poplar. Solids obtained by FT pretreatment were amenable to high conversion for all of the feedstocks and conversion systems examined. The optimal time and temperature for FT pretreatment on poplar were found to be 16 min and 210°C. At these conditions, SSF glucan conversion was about 85%, 94% of the XMG was removed, and 62% of the non carbohydrate mass was solubilized. Solubilization of FT-pretreated poplar was compared for C. thermocellum fermentation (10% inoculum, and for yeast-fungal cellulase SSF (5% inoculum, cellulase loading of 5 and 10 FPU/g glucan supplemented with β-glucosidase at 15 and 30 U/g glucan. Under the conditions tested, which featured low solids concentration, C. thermocellum fermentation achieved faster rates and more complete conversion of FT-pretreated poplar than did SSF. Compared to SSF, solubilization by C. thermocellum was 30% higher after 4 days, and was over twice as fast on ball-milled FT-pretreated poplar. Conclusions XMG removal trends were similar between feedstocks whereas glucan conversion trends were significantly

  3. An improved hydrothermal diamond anvil cell

    Science.gov (United States)

    Li, Jiankang; Bassett, W. A.; Chou, I.-Ming; Ding, Xin; Li, Shenghu; Wang, Xinyan

    2016-05-01

    A new type of HDAC-V hydrothermal diamond anvil cell (HDAC-VT) has been designed to meet the demands of X-ray research including X-Ray Fluorescence, X-ray Absorption Spectroscopy, and small angle X-ray scattering. The earlier version of HDAC-V that offered a large rectangular solid angle used two posts and two driver screws on both sides of a rectangular body. The new version HDAC-VT in a triangular shape has two alternative guide systems, either three posts inserted into bushings suitable for small anvil faces or linear ball bearings suitable for large anvil faces. The HDAC-VT having three driver screws offers the advantage of greater control and stability even though it sacrifices some of the size of solid angle. The greater control allows better sealing of samples, while greater stability results in longer survival for anvils and ceramic parts. This improved design retains several beneficial features of the original HDAC-V as well. These include the small collar that surrounds the heater and sample chamber forming an Ar + H2 gas chamber to protect diamonds and their heating parts from being oxidized. Three linear ball bearings, when used, fit to the three posts prevent seizing that can result from deterioration of lubricant at high temperatures. Positioning the posts and bearings outside of the gas chamber as in HDAC-V also prevents seizing and possible deformation due to overheating. In order to control the heating rate precisely with computer software, we use Linkam T95 and have replaced the Linkam 1400XY heating stage with the HDAC-VT allowing the HDAC to be heated to 950 °C at a rate from 0.01 °C/min to 50 °C/min. We have used the HDAC-VT and Linkam T95 to observe in situ nucleation and growth of zabuyelite in aqueous fluid and to homogenize melt inclusions in quartz from three porphyry deposits in Shanxi, China.

  4. Fate of Organic Micropollutants during Hydrothermal Carbonization

    Science.gov (United States)

    Weiner, B.; Baskyr, I.; Pörschmann, J.; Kopinke, F.-D.

    2012-04-01

    The hydrothermal carbonization (HTC) is an exothermic process, in which biomass in an aqueous suspension is transformed into a bituminous coal-like material (hydrochar) at temperatures between 180-250°C and under moderate pressure. With these process conditions, little gas is generated (1-5%), and a fraction of the organic carbon is dissolved in the aqueous phase (10-30%) but the largest part is obtained as solid char. The respective yields and the molecular composition depend on the choice of educts and the process conditions, such as temperature, pH-value, and reaction time. Various biomass-educts have recently been studied, such as waste materials from agriculture, brewer's spent grains, sewage sludge, as well as wood and paper materials. Besides their use for energy generation, the hydrochars have also been investigated as soil amendments. Prior to addition of the chars to soil, these should be free of toxic components that could be released into the environment as harmful organic pollutants. Herein, the potential for the degradation of trace organic pollutants, such as pesticides and pharmaceuticals, under typical HTC conditions will be presented. The degradation of selected organic pollutants with different polarity and hydrophobicity was investigated. Scope and limitations of the degradation potential of the HTC are discussed on examples of micro pollutants such as hormones, residues of pharmaceuticals and personal care products including their metabolites, and pesticides. We will show that the target analytes are partially and in some cases completely degraded. The degree of degradation depends on the HTC process conditions such as reaction temperature and time, the solution pH value, the presence of catalysts or additional reagents. The biotic and abiotic degradation of chlorinated organic compounds, in particular chlorinated aromatics, has been a well-known environmental problem and remains a challenging issue for the development of a HTC process for

  5. Hydrothermal plumes over the Carlsberg Ridge, Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, D.; KameshRaju, K.A.; Baker, E.T.; Rao, A.S.; Mudholkar, A.V.; Lupton, J.E.; SuryaPrakash, L.; Gawas, R.B.; VijayaKumar, T.

    -isotopes, the most definitive chemical tracer for hydrothermal activity. Hydrothermal venting is considered to be the source of this excess 3 He in the deep ocean as part of the processes generating new oceanic crust [Craig and Lupton, 1981; Jean-Baptiste et al... Spreading Center: No evidence for discharge beyond the neovolcanic zone, Geochem. Geophys. Geosyst., 11, Q08004, doi: 10.1029/2010GC003106. Bougault, H., J. L. Charlou, Y. Fouquet, H. D. Needham, N. Vaslet, P.,Appriou, P. Jean-Baptiste, P. A. Rona, L...

  6. Hydrothermal liquefaction of microalgae's for bio oil production

    DEFF Research Database (Denmark)

    Toor, Saqib; Reddy, Harvind; Deng, Shuguang

    Hydrothermal liquefaction experiments on Nannochloropsis salina and Spirulina platensis at subcritical and supercritical water conditions were carried out to explore the feasibility of extracting lipids from wet algae, preserving nutrients in lipid-extracted algae solid residue, and recycling...... and 107 bar. For Spirulina platensis algae sample, the highest bio-oil yield is 38% at 350 °C and 195 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins...

  7. Dynamic behavior of Kilauea Volcano and its relation to hydrothermal systems and geothermal energy

    Science.gov (United States)

    Kauhikaua, Jim; Moore, R.B.; ,

    1993-01-01

    Exploitation of hydrothermal systems on active basaltic volcanoes poses some unique questions about the role of volcanism and hydrothermal system evolution. Volcanic activity creates and maintains hydrothermal systems while earthquakes create permeable fractures that, at least temporarily, enhance circulation. Magma and water, possibly hydrothermal water, can interact violently to produce explosive eruptions. Finally, we speculate on whether volcanic behavior can be affected by high rates of heat extraction.

  8. Living with the Heat. Submarine Ring of Fire--Grades 5-6. Hydrothermal Vent Ecology.

    Science.gov (United States)

    National Oceanic and Atmospheric Administration (DOC), Rockville, MD.

    This activity is designed to teach about hydrothermal vent ecology. Students are expected to describe how hydrothermal vents are formed and characterize the physical conditions at these sites, explain chemosynthesis and contrast this process with photosynthesis, identify autotrophic bacteria as the basis for food webs in hydrothermal vent…

  9. Hydrothermal Alteration in the PACMANUS Hydrothermal Field: Implications From Secondary Mineral Assemblages and Mineral Chemistry, OPD Leg 193

    Science.gov (United States)

    Lackschewitz, K. S.; Kummetz, M.; Kummetz, M.; Ackermand, D.; Botz, R.; Devey, C. W.; Singer, A.; Stoffers, P.

    2001-12-01

    Leg 193 of the Ocean Drilling Program investigated the subsurface nature of the active PACMANUS hydrothermal field in the Manus backarc basin near Papua New Guinea. Drilling in different areas on the felsic neovolcanic Pual Ridge, including the high-temperature black smoker complex of Roman Ruins and the low-temperature Snowcap site with diffusive discharge yielded a complex alteration history with a regional primary alteration being overprinted by a secondary mineralogy. The intense hydrothermal alteration at both sites shows significant differences in the secondary mineralogy. At Roman Ruins, the upper 25 m of hydrothermally altered rocks are characterized by a rapid change from secondary cristobalite to quartz, implying a high temperature gradient. From 10 to 120 mbsf the clay mineralogy is dominated by illite and chlorite. The chlorite formation temperature calculated from oxygen isotope data lies at 250° C in 116 mbsf which is similar to the present fluid outflow temperatures of 240-250° C (Douville et al., 1999, Geochim. Cosmochim. Acta, 63, 627-643). Drilling in the Snowcap field recovered evidence for several stages of hydrothermal alteration. Between 50 and 150 mbsf, cristobalite and chlorite are the most abundant alteration minerals while hydrothermal pyrophyllite becomes abundant in some places At 67 mbsf, the isotopic composition of pyrophyllite gives a temperature for ist formation at 260° C whereas at 77 and 116 mbsf the pyrophyllite displays the highest temperatures of formation (>300° C). These temperatures are close to the maximum measured borehole temperatures of 313° C. The appearance of assemblages of chlorite, chlorite-vermiculite, chlorite-vermiculite-smectite and illite-smectite as well as the local development of corrensite below 150 mbsf suggests that the alteration at Snowcap may be more complex than that beneath Roman Ruins. Detailed geochemical studies of the authigenic clay mineral phases will provide further insights into the

  10. Sulfur isotopic composition of modern seafloor hydrothermal sediment and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 秦蕴珊; 翟世奎

    2002-01-01

    A total of 1 264 sulfur isotopic values for modem seafloor hydrothermel sediments from different hydrothermal fidds have been collected. On this basis, combining our sulfur isotpic data for surface hydrothermal sediments from the Jade hydrohtermal field in the Okinawa Trough and the TAG hydrothermal field in the Mid-Atlantic Ridge, respectively, and comparing the sulfur isotopic compositions and analyzing their sources of sulfur in seafloor hydrothermal sediments from different geologic-tectonic setting, the results show that: ( 1 ) sulfur isotopic values of sulfides and sulfates in modern seafloor hydrothermal sediments are concentrated in a narrow range, δ34S values of sulfides vary from l × 10-3 to 9 × 10- 3, with a mean of 4.5 × 10- 3 ( n = 1 042), δ34S values of sulfates vary from 19 × 10- 3 to 24× 10-3, with a mean of 21.3× 10-3 (n =217); (2) comparing the sulfur isotopic compositions of hydrothermal sediments from the sediment-hosted hydrothermal fields, the range of sulfur isotopic values for hydrothermal sediments from the sediment-free hydrothermal fields is narrow relatively; (3) the differences of sulfur isotopic compositions in sulfides from different hydrothermal fields show the differences in the sources of sulfur. The sulfur of hydrothermal sulfides in the sediment-free mid-ocean ridges is mainly from mid-ocean ridge basalt, and partially from the reduced seawater sulfate, and it is the result of partially reduced seawater sulfate mixed with basaltic sulfur. In the sediment-hosted nid-ocean ridges and the back-arc basins, the volcanics, the sediments and the organic matters also can offer their sulfur for forming hydrothermal sulfides; (4) the variations of sulfur isotopic compositions and the different sources of sulfur for hydrothermal sediments may be attributed to the various physical-chemical characteristics of hydrothermal fluids, the magmatic evolution and the different geologic-tectonic settings of seafloor hydrothermal systems.

  11. Evidence for recent hydrothermal activity in the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; ShyamPrasad, M.; Gupta, S.M.; Charan, S.N.

    with the VHM suggest approx 10 ka age for the hydrothermal episode. The metalliferous sediments are semi-indurated, yellow to orange colored Fe-Si oxyhroxides with Fe and SiO sub(2) contents between 54 - 73% and 16 - 30%, respectively, and have been derived...

  12. Subcritical hydrothermal conversion of organic wastes and biomass. Reaction pathways

    Directory of Open Access Journals (Sweden)

    Alejandro Amadeus Castro Vega

    2010-04-01

    Full Text Available Hydrothermal conversion is a procedure which emulates organic matter’s natural conversion into bio-crude having physical and chemical properties analogous to petroleum. The artificial transformation of biomass requi- res previous knowledge of the main reaction routes and product availability. The main component of biomass (depolymerisation by hydrolysis is presented in hydrothermal cellulose conversion, producing oligosaccharides which exhibit dehydration and retro-aldol condensation reactions for transforming into furfurals and carboxylic acids. Other biomass components (such as lignin, proteins, and fat esters present both hydrolysis and pyrolysis reaction routes. As long as biomass mainly contains carbohydrates, subcritical hydrothermal conversion products and their wastes will be fundamentally analogous to those displaying cellulose. These substances have added- value by far surpassing raw material’s acquisition cost. When the main hydrothermal conversion products’ O/C, H/C molar ratios as reported in literature are plotted, an evolutionary tralectory for conversion products appears to be closely or even overlapped with fossil fuels’ geological evolution.

  13. Where are the undiscovered hydrothermal vents on oceanic spreading ridges?

    Science.gov (United States)

    Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.

    2015-11-01

    In nearly four decades since the discovery of deep-sea vents, one-third of the length of global oceanic spreading ridges has been surveyed for hydrothermal activity. Active submarine vent fields are now known along the boundaries of 46 out of 52 recognized tectonic plates. Hydrothermal survey efforts over the most recent decade were sparked by national and commercial interests in the mineral resource potential of seafloor hydrothermal deposits, as well as by academic research. Here we incorporate recent data for back-arc spreading centers and ultraslow- and slow-spreading mid-ocean ridges (MORs) to revise a linear equation relating the frequency of vent fields along oceanic spreading ridges to spreading rate. We apply this equation globally to predict a total number of vent fields on spreading ridges, which suggests that ~900 vent fields remain to be discovered. Almost half of these undiscovered vent fields (comparable to the total of all vent fields discovered during 35 years of research) are likely to occur at MORs with full spreading rates less than 60 mm/yr. We then apply the equation regionally to predict where these hydrothermal vents may be discovered with respect to plate boundaries and national jurisdiction, with the majority expected to occur outside of states' exclusive economic zones. We hope that these predictions will prove useful to the community in the future, in helping to shape continuing ridge-crest exploration.

  14. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Science.gov (United States)

    Chown, Steven L

    2012-01-01

    The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  15. Origin of Magnetism in Hydrothermally Aged 2-Line Ferrihydrite Suspensions.

    Science.gov (United States)

    Cao, Liang; Jiang, Zhao-Xia; Du, Yong-Hua; Yin, Xin-Mao; Xi, Shi-Bo; Wen, Wen; Roberts, Andrew P; Wee, Andrew T S; Xiong, Yi-Min; Liu, Qing-Song; Gao, Xing-Yu

    2017-03-07

    As an iron oxyhydroxide, nanosized ferrihydrite (Fh) is important in Earth science, biology, and industrial applications. However, its basic structure and origin of its magnetism have long been debated. We integrate synchrotron-based techniques to explore the chemical structures of 2-line ferrihydrite and to determine the origin of its magnetism during hydrothermal aging in air. Our results demonstrate that both the magnetism and X-ray magnetic circular dichroism (XMCD) signal of 2-line ferrihydrite are enhanced with aging time, and that XMCD spectral patterns resemble that of maghemite (γ-Fe2O3) rather than magnetite (Fe3O4). Fe L-edge and K-edge X-ray absorption spectroscopy (XAS) further indicate formation of both maghemite and hematite (α-Fe2O3) with increasing concentrations with longer hydrothermal aging time. Thus, magnetic enhancement with longer hydrothermal aging time is attributed to increasing maghemite concentration instead of a magnetically ordered ferrihydrite as previously reported. Moreover, L-edge and K-edge XAS spectra with different probing depths yield different ratios of these Fe oxides, which suggest the formation of a core (ferrihydrite-rich)-shell (with a mixture of both allotropes; α-Fe2O3 and γ-Fe2O3) structure during hydrothermal aging. Our results provide insights into the chemical evolution of 2-line ferrihydrite that reveal unambiguously the origin of its magnetism.

  16. Hydrothermal synthesis and photoluminescent properties of stacked indium sulfide superstructures.

    Science.gov (United States)

    Xing, Yan; Zhang, Hongjie; Song, Shuyan; Feng, Jing; Lei, Yongqian; Zhao, Lijun; Li, Meiye

    2008-03-28

    Unusual hierarchical stacked superstructures of cubic beta-In2S3 were fabricated via a facile hydrothermal process in the presence of a surfactant cetyltrimethylammonium bromide CTAB; the 3D superstructures were developed by helical propagation of surface steps from microflakes of 10-20 nm thickness.

  17. The deep structure of a sea-floor hydrothermal deposit

    Science.gov (United States)

    Zierenberg, R.A.; Fouquet, Y.; Miller, D.J.; Bahr, J.M.; Baker, P.A.; Bjerkgard, T.; Brunner, C.A.; Duckworth, R.C.; Gable, R.; Gieskes, J.; Goodfellow, W.D.; Groschel-Becker, H. M.; Guerin, G.; Ishibashi, J.; Iturrino, G.; James, R.H.; Lackschewitz, K.S.; Marquez, L.L.; Nehlig, P.; Peter, J.M.; Rigsby, C.A.; Schultheiss, P.; Shanks, Wayne C.; Simoneit, B.R.T.; Summit, M.; Teagle, D.A.H.; Urbat, M.; Zuffa, G.G.

    1998-01-01

    Hydrothermal circulation at the crests of mid-ocean ridges plays an important role in transferring heat from the interior of the Earth. A consequence of this hydrothermal circulation is the formation of metallic ore bodies known as volcanic-associated massive sulphide deposits. Such deposits, preserved on land, were important sources of copper for ancient civilizations and continue to provide a significant source of base metals (for example, copper and zinc). Here we present results from Ocean Drilling Program Leg 169, which drilled through a massive sulphide deposit on the northern Juan de Fuca spreading centre and penetrated the hydrothermal feeder zone through which the metal-rich fluids reached the sea floor. We found that the style of feeder-zone mineralization changes with depth in response to changes in the pore pressure of the hydrothermal fluids and discovered a stratified zone of high-grade copper-rich replacement mineralization below the massive sulphide deposit. This copper-rich zone represents a type of mineralization not previously observed below sea-floor deposits, and may provide new targets for land-based mineral exploration.

  18. Chaotic thermohaline convection in low-porosity hydrothermal systems

    NARCIS (Netherlands)

    Schoofs, Stan; Spera, Frank J.; Hansen, Ulrich

    2001-01-01

    Fluids circulate through the Earth's crust perhaps down to depths as great as 5^15 km, based on oxygen isotope systematics of exhumed metamorphic terrains, geothermal fields, mesozonal batholithic rocks and analysis of obducted ophiolites. Hydrothermal flows are driven by both thermal and chemical b

  19. Inversion Approach For Thermal Data From A Convecting Hydrothermal System

    Energy Technology Data Exchange (ETDEWEB)

    Kasameyer, P.; Younker, L.; Hanson, J.

    1985-01-01

    Hydrothermal systems are often studied by collecting thermal gradient data and temperature depth curves. These data contain important information about the flow field, the evolution of the hydrothermal system, and the location and nature of the ultimate heat sources. Thermal data are conventionally interpreted by the ''forward'' method; the thermal field is calculated based on selected initial conditions and boundary conditions such as temperature and permeability distributions. If the calculated thermal field matches the data, the chosen conditions are inferred to be possibly correct. Because many sets of initial conditions may produce similar thermal fields, users of the ''forward'' method may inadvertently miss the correct set of initial conditions. Analytical methods for ''inverting'' data also allow the determination of all the possible solutions consistent with the definition of the problem. In this paper we suggest an approach for inverting thermal data from a hydrothermal system, and compare it to the more conventional approach. We illustrate the difference in the methods by comparing their application to the Salton Sea Geothermal Field by Lau (1980a) and Kasameyer, et al. (1984). In this particular example, the inverse method was used to draw conclusions about the age and total rate of fluid flow into the hydrothermal system.

  20. Phase transformation of zirconia ceramics by hydrothermal degradation.

    Science.gov (United States)

    Kawai, Yohei; Uo, Motohiro; Wang, Yongming; Kono, Sayaka; Ohnuki, Somei; Watari, Fumio

    2011-01-01

    Zirconia has found wide application in dentistry because of its high mechanical strength and superior esthetic properties. However, zirconia degradation caused by phase transformation occurring in a hydrothermal environment is of concern. In the present study, phase transformation and microstructure of tetragonal zirconia polycrystal partially stabilized with yttrium oxide (Y-TZP) and alumina-toughened zirconia (ATZ) sintered at different temperatures were estimated. On grazing angle X-ray diffraction analysis, ATZ showed less phase transformation to the monoclinic phase during hydrothermal treatment and this transformation appeared to occur within a few micrometers below the surface. At a higher sintering temperature the monoclinic phase content of ATZ was found to be lesser than that of Y-TZP, indicating that the alumina in ATZ was effective in suppressing hydrothermal degradation. Examination by transmission electron microscopy and studying of electron backscatter diffraction patterns indicated that grain growth in ATZ was slightly suppressed compared with that in Y-TZP at higher sintering temperatures. The present study demonstrated the effect of adding alumina to zirconia for suppressing hydrothermal degradation and studied the effect of this addition on grain growth in zirconia.

  1. Submarine barite-opal rocks of hydrothermal origin.

    Science.gov (United States)

    Bertine, K K; Keene, J B

    1975-04-11

    Unusual submarine rocks consisting of barite, opal, and volcanic detritus were recovered from the Lau Basin northeast of Australia. It is proposed that these rocks were formed when hydrothermal solutions emanating from a fracture zone offsetting the active spreading center in the Lau Basin came into contact with cooler ocean waters.

  2. Sustainable biomass-derived hydrothermal carbons for energy applications

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    C. Falco

    2012-09-01

    Full Text Available The hydrothermal carbonisation of carbohydrate and protein-rich biomass was systematically investigated, in order to obtain more insights on the potentials of this thermochemical processing technique in relation to the production of functional carbon materials from crude biomass.

  3. Hydrothermal preparation and crystal habit of X-zeolite powder

    Institute of Scientific and Technical Information of China (English)

    SHEN Shao-hua; ZHANG Shu-gen; WANG Da-wei; FANG Ke-ming

    2005-01-01

    The preparation of X-zeolite powder was investigatedin hydrothermal system, the crystal growth process of X-zeolite in hydrothermal condition was characterized by means of X-ray diffraction, scanning electron microscope and infrared ray. The results show that X-zeolite powder with uniform granularity and intact crystal shape can be obtained in hydrothermal system of acid-treated stellerite-NaOH-NaAl(OH)4-H2O; the crystallite size is in the range of 2 - 3μm. The best reaction time of hydrothermal preparation is 6 h. The formation phases of X-zeolite crystal are as follows: dissolution of feedstocks → formation of [SiO4]4- and [AlO4]5- tetrahedron, many-membered ring,β cage → formation of crystal nucleus and nano-particle → aggregation growth of nano-particle → coalescence growth of crystallite. The crystal habits of X-zeolite are intimately related with crystallization orientation ofβ cage in crystal and with its coupling stability on every crystal face family.

  4. Air Pollution by Hydrothermal Volcanism and Human Pulmonary Function

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    Diana Linhares

    2015-01-01

    Full Text Available The aim of this study was to assess whether chronic exposure to volcanogenic air pollution by hydrothermal soil diffuse degassing is associated with respiratory defects in humans. This study was carried in the archipelago of the Azores, an area with active volcanism located in the Atlantic Ocean where Eurasian, African, and American lithospheric plates meet. A cross-sectional study was performed on a study group of 146 individuals inhabiting an area where volcanic activity is marked by active fumarolic fields and soil degassing (hydrothermal area and a reference group of 359 individuals inhabiting an area without these secondary manifestations of volcanism (nonhydrothermal area. Odds ratio (OR and 95% confidence intervals (CIs were adjusted for age, gender, fatigue, asthma, and smoking. The OR for restrictive defects and for exacerbation of obstructive defects (COPD in the hydrothermal area was 4.4 (95% CI 1.78–10.69 and 3.2 (95% CI 1.82–5.58, respectively. Increased prevalence of restrictions and all COPD severity ranks (mild, moderate, and severe was observed in the population from the hydrothermal area. These findings may assist health officials in advising and keeping up with these populations to prevent and minimize the risk of respiratory diseases.

  5. Aluminum speeds up the hydrothermal alteration of olivine

    Science.gov (United States)

    Andreani, Muriel; Daniel, Isabelle; Pollet-Villard, Marion

    2014-05-01

    The reactivity of ultramafic rocks toward hydrothermal fluids controls chemical fluxes at the interface between the internal and external reservoirs of silicate planets. On Earth, hydration of ultramafic rocks is ubiquitous and operates from deep subduction zones to shallow lithospheric environments where it considerably affects the physical and chemical properties of rocks and can interact with the biosphere. This process also has key emerging societal implications, such as the production of hydrogen as a source of carbon-free energy. To date, the chemical model systems used to reproduce olivine hydrothermal alteration lead to the formation of serpentine with sluggish reaction rates. Although aluminum is common in geological environments and in hydrothermal systems in particular, its role in serpentinization or olivine dissolution has not been investigated under hydrothermal conditions. Nevertheless, abundant Al supply is expected in fluids released from dehydration of metapelites in subduction zones as well as during the hydrothermal alteration of gabbros at mid-ocean ridges. Aluminum was also abundant in primitive environments of both the Earth and Mars, stored in either Al-rich minerals like plagioclase or Al-enriched ultramafic lavas. We have investigated the role of Al on the hydrothermal alteration of olivine in a series of experiments performed in a low-pressure diamond anvil cell while following the reaction progress in situ by optical imaging and Raman spectroscopy. Experiments were run for 4.5 to 7.5 days with two olivine grains reacted in saline water (0.5 molal NaCl) at 200°C and 300°C, and P=200 MPa. After two days, olivine crystals were fully transformed to an aluminous serpentine, also enriched in iron. The presence of Al in the hydrothermal fluid increases the rate of olivine serpentinization by more than one order of magnitude by enhancing olivine solubility and serpentine precipitation. The mechanism responsible for this increased solubility

  6. Hydrothermal mixing: Fuel for life in the deep-sea

    Science.gov (United States)

    Hentscher, M.; Bach, W.; Amend, J.; McCollom, T.

    2009-04-01

    Deep-sea hydrothermal vent systems show a wide range of fluid compositions and temperatures. They reach from highly alkaline and reducing, like the Lost City hydrothermal field, to acidic and reducing conditions, (e. g., the Logatchev hydrothermal field) to acidic and oxidizing conditions (e. g., island arc hosted systems). These apparently hostile vent systems are generally accompanied by high microbial activity forming the base of a food-web that often includes higher organisms like mussels, snails, or shrimp. The primary production is boosted by mixing of chemically reduced hydrothermal vent fluids with ambient seawater, which generates redox disequilibria that serve as energy source for chemolithoautotrophic microbial life. We used geochemical reaction path models to compute the affinities of catabolic (energy-harvesting) and anabolic (biosynthesis) reactions along trajectories of batch mixing between vent fluids and 2 °C seawater. Geochemical data of endmember hydrothermal fluids from 12 different vent fields (Lost City, Rainbow, Logatchev, TAG, EPR 21 °N, Manus Basin, Mariana Arc, etc.) were included in this reconnaissance study of the variability in metabolic energetics in global submarine vent systems. The results show a distinction between ultramafic-hosted and basalt-hosted hydrothermal systems. The highest energy yield for chemolithotrophic catabolism in ultramafic-hosted hydrothermal systems is reached at low temperature and under slightly aerobic to aerobic conditions. The dominant reactions, for example at Rainbow or Lost City, are the oxidation of H2, Fe2+ and methane. At temperatures >60 °C, anaerobic metabolic reactions, e. g., sulphate reduction and methanogenesis, become more profitable. In contrast, basalt-hosted systems, such as TAG and 21 °N EPR uniformly indicate H2S oxidation to be the catabolically dominant reaction over the entire microbial-relevant temperature range. Affinities were calculated for the formation of individual cellular

  7. Catalytic Diversity in Alkaline Hydrothermal Vent Systems on Ocean Worlds

    Science.gov (United States)

    Cameron, Ryan D.; Barge, Laura; Chin, Keith B.; Doloboff, Ivria J.; Flores, Erika; Hammer, Arden C.; Sobron, Pablo; Russell, Michael J.; Kanik, Isik

    2016-10-01

    Hydrothermal systems formed by serpentinization can create moderate-temperature, alkaline systems and it is possible that this type of vent could exist on icy worlds such as Europa which have water-rock interfaces. It has been proposed that some prebiotic chemistry responsible for the emergence of life on Earth and possibly other wet and icy worlds could occur as a result ofredox potential and pH gradients in submarine alkaline hydrothermal vents (Russell et al., 2014). Hydrothermal chimneys formed in laboratory simulations of alkaline vents under early Earth conditions have precipitate membranes that contain minerals such as iron sulfides, which are hypothesized to catalyze reduction of CO2 (Yamaguchi et al. 2014, Roldan et al. 2014) leading to further organic synthesis. This CO2 reduction process may be affected by other trace components in the chimney, e.g. nickel or organic molecules. We have conducted experiments to investigate catalytic properties of iron and iron-nickel sulfides containing organic dopants in slightly acidic ocean simulants relevant to early Earth or possibly ocean worlds. We find that the electrochemical properties of the chimney as well as the morphology/chemistry of the precipitate are affected by the concentration and type of organics present. These results imply that synthesis of organics in water-rock systems on ocean worlds may lead to hydrothermal precipitates which can incorporate these organic into the mineral matrix and may affect the role of gradients in alkaline vent systems.Therefore, further understanding on the electroactive roles of various organic species within hydrothermal chimneys will have important implications for habitability as well as prebiotic chemistry. This work is funded by NASA Astrobiology Institute JPL Icy Worlds Team and a NAI Director's Discretionary Fund award.Yamaguchi A. et al. (2014) Electrochimica Acta, 141, 311-318.Russell, M. J. et al. (2014), Astrobiology, 14, 308-43.Roldan, A. (2014) Chem. Comm. 51

  8. Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling

    Science.gov (United States)

    Pierazzo, E.; Artemieva, N. A.; Ivanov, B. A.

    2004-01-01

    Mars is the most Earth-like of the Solar System s planets, and the first place to look for any sign of present or past extraterrestrial life. Its surface shows many features indicative of the presence of surface and sub-surface water, while impact cratering and volcanism have provided temporary and local surface heat sources throughout Mars geologic history. Impact craters are widely used ubiquitous indicators for the presence of sub-surface water or ice on Mars. In particular, the presence of significant amounts of ground ice or water would cause impact-induced hydrothermal alteration at Martian impact sites. The realization that hydrothermal systems are possible sites for the origin and early evolution of life on Earth has given rise to the hypothesis that hydrothermal systems may have had the same role on Mars. Rough estimates of the heat generated in impact events have been based on scaling relations, or thermal data based on terrestrial impacts on crystalline basements. Preliminary studies also suggest that melt sheets and target uplift are equally important heat sources for the development of a hydrothermal system, while its lifetime depends on the volume and cooling rate of the heat source, as well as the permeability of the host rocks. We present initial results of two-dimensional (2D) and three-dimensional (3D) simulations of impacts on Mars aimed at constraining the initial conditions for modeling the onset and evolution of a hydrothermal system on the red planet. Simulations of the early stages of impact cratering provide an estimate of the amount of shock melting and the pressure-temperature distribution in the target caused by various impacts on the Martian surface. Modeling of the late stage of crater collapse is necessary to characterize the final thermal state of the target, including crater uplift, and distribution of the heated target material (including the melt pool) and hot ejecta around the crater.

  9. Energetics of Amino Acid Synthesis in Alkaline Hydrothermal Environments

    Science.gov (United States)

    Kitadai, Norio

    2015-12-01

    Alkaline hydrothermal systems have received considerable attention as candidates for the origin and evolution of life on the primitive Earth. Nevertheless, sufficient information has not yet been obtained for the thermodynamic properties of amino acids, which are necessary components for life, at high temperatures and alkaline pH. These properties were estimated using experimental high-temperature volume and heat capacity data reported in the literature for several amino acids, together with correlation algorithms and the revised Helgeson-Kirkham-Flowers (HKF) equations of state. This approach enabled determination of a complete set of the standard molal thermodynamic data and the revised HKF parameters for the 20 protein amino acids in their zwitterionic and ionization states. The obtained dataset was then used to evaluate the energetics of amino acid syntheses from simple inorganic precursors (CO2, H2, NH3 and H2S) in a simulated alkaline hydrothermal system on the Hadean Earth. Results show that mixing between CO2-rich seawater and the H2-rich hydrothermal fluid can produce energetically favorable conditions for amino acid syntheses, particularly in the lower-temperature region of such systems. Together with data related to the pH and temperature dependences of the energetics of amino acid polymerizations presented in earlier reports, these results suggest the following. Hadean alkaline hydrothermal settings, where steep pH and temperature gradients may have existed between cool, slightly acidic Hadean ocean water and hot, alkaline hydrothermal fluids at the vent-ocean interface, may be energetically the most suitable environment for the synthesis and polymerization of amino acids.

  10. Hydrothermal impacts on trace element and isotope ocean biogeochemistry

    Science.gov (United States)

    German, C. R.; Casciotti, K. A.; Dutay, J.-C.; Heimbürger, L. E.; Jenkins, W. J.; Measures, C. I.; Mills, R. A.; Obata, H.; Schlitzer, R.; Tagliabue, A.; Turner, D. R.; Whitby, H.

    2016-11-01

    Hydrothermal activity occurs in all ocean basins, releasing high concentrations of key trace elements and isotopes (TEIs) into the oceans. Importantly, the calculated rate of entrainment of the entire ocean volume through turbulently mixing buoyant hydrothermal plumes is so vigorous as to be comparable to that of deep-ocean thermohaline circulation. Consequently, biogeochemical processes active within deep-ocean hydrothermal plumes have long been known to have the potential to impact global-scale biogeochemical cycles. More recently, new results from GEOTRACES have revealed that plumes rich in dissolved Fe, an important micronutrient that is limiting to productivity in some areas, are widespread above mid-ocean ridges and extend out into the deep-ocean interior. While Fe is only one element among the full suite of TEIs of interest to GEOTRACES, these preliminary results are important because they illustrate how inputs from seafloor venting might impact the global biogeochemical budgets of many other TEIs. To determine the global impact of seafloor venting, however, requires two key questions to be addressed: (i) What processes are active close to vent sites that regulate the initial high-temperature hydrothermal fluxes for the full suite of TEIs that are dispersed through non-buoyant hydrothermal plumes? (ii) How do those processes vary, globally, in response to changing geologic settings at the seafloor and/or the geochemistry of the overlying ocean water? In this paper, we review key findings from recent work in this realm, highlight a series of key hypotheses arising from that research and propose a series of new GEOTRACES modelling, section and process studies that could be implemented, nationally and internationally, to address these issues. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

  11. Sulfur isotopic composition of seafloor hydrothermal sediment from the Jade hydrothermal field in the central Okinawa Trough and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 翟世奎; 秦蕴珊; 侯增谦

    2002-01-01

    --Eighteen samples of hydrothermal sediments from the Jade hydrotherrnal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2 ×10-3to 7.2× 10-3, δ34S valUes for 7 sulfate samples vary from 16.3 × 10-3 to 22.3 × 10-3, and 1 native sulphur sample has a δ34S value of 8.2 × 10-3. The major sources of sulfur for hydrothermal sediment are intermediate to acid volcanic rocks and sea water sulfate, and it is possible that the partial sulfur of hydrothermal sediment is from the pelagic sediment by the interaction between hydrothermal fluid and sediment. The reasons of causing the distinct differences in sulfur isotopic values for sulfide samples from hydrothermal sediment ( compared with other hydrothermal fields), are the differences in the sources of sulfur, the magmatic activity and the tectonic evolution in different hydrothermal fields. The sulfur evolution is a long and complex process in the seafloor hydrothermal system, involving the ascending of heating sea water, the interaction between fluid and volcanic rocks, the mixing of sea water sulfate and sulfur from intermediate to acid volcanic rocks, and the fluid/pelagic-sediment interaction. And the interaction between sea water and intermediate to acid volcanic rocks is an important mechanism for the sulfur evolution in the Jade hydrothermal field.

  12. Geología de la Formación Cerro Negro (Cretácico en Isla Livingston: aportes a su geocronología y contenido paleontológico

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    C.A. Parica

    2007-12-01

    Full Text Available La península Byers se encuentra en el extremo occidental de la isla Livingston, archipiélago de las islas Shetland del Sur. Geológicamente está caracterizada por depósitos marinos, continentales y volcanismo cretácico-terciario que son incluidos en la Formación Cerro Negro de la sección superior del Grupo Byers. Las secuencias magmáticas han sido divididas en dos grupos principales, el primero comprende a las rocas piroclásticas y reúne cinco unidades con un importante desarrollo y distribución en el área. Por su parte, el segundo grupo comprende lavas e intrusivos aflorantes en cerros Don Carlos, Usnea (Usnea Plug, Chester (Chester Cone, Sealer (Sealer Hill y Negro (Negro Hill. Los términos sedimentarios incluyen conglomerados, areniscas y pelitas, de color gris verdoso con estratificación entrecruzada (tanto tabular como en artesa, raramente estratos macizos, laminación horizontal (en algunos casos de naturaleza rítmica, y estructuras de deformación sinsedimentaria (principalmente laminación convoluta. Se propone un ambiente fluvial de depositación, con canales dominados por carga de lecho y barras areno-gravosas bien desarrolladas. En lo que corresponde al sector de planicie de inundación, predominó allí la depositación de material limo-arcilloso por corrientes tractivas débiles durante las crecientes. En las áreas deprimidas de las planicies habría tenido lugar la formación de cuerpos de aguas de poca profundidad en los que se vió favorecida la preservación de la macro y microflora. En las nuevas localidades fosilíferas de península Byers, Domo Rotch (Rotch Dome, cerro Don Carlos, Lomada de las Plantas y 904, ha sido reconocida la presencia de las especies: Araucarites sp., Archangelskya furcata Herbst, Cladophlebis sp., Dictyozamites sp., Elatocladus sp, Phyllopteroides sp., Pseudoctenis sp., Ptyllophyllum menendezii Cantrill, Sphenopteris sp., Eocyathea remesaliae Césari, Sergioa austrina Césari y

  13. Petrology and Geochemistry of Hydrothermally Altered Volcanic Rocks in the Iheya North Hydrothermal Field, Middle Okinawa Trough

    Science.gov (United States)

    Yamasaki, T.

    2015-12-01

    The Iheya North hydrothermal field is located in the middle Okinawa Trough, a young and actively spreading back-arc basin extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. In this hydrothermal field, two scientific drilling expeditions (IODP Exp 331 and SIP CK14-04) were conducted using a deep-sea drilling vessel "Chikyu," and samples from a total of 27 holes were taken. Through these expeditions, Kuroko-type volcanogenic massive sulfide deposits (VMS), hydrothermally altered volcanic rocks, and pumiceous and pelagic sediments were recovered. The recovered core provided important information about the relationship between hydrothermal activity, alteration, and ore mineralization. Whole-rock major element composition and trace element (TE) patterns of pumices were very similar to those of rhyolites in the middle Okinawa Trough (RMO). However, pumices were relatively enriched in chalcophile elements Sr and Nb, which suggest incipient mineralization. Volcanic rock generally demonstrated strong silicification and was greenish pale gray in color. Regardless of severe alteration, some rock displayed major element composition broadly similar to the RMO. Alteration was evidenced by an increase in the content of SiO2 and MgO, and decrease in Al2O3, Na2O, and K2O content. The most striking geochemical feature of altered volcanic rock was the discordance between texture and the degree of modification of TEs. Some samples showed decussate texture occupied by petal-like quartz with severe silicification, but no prominent disturbance of concentration and patterns of TEs were observed. In contrast, samples with well-preserved igneous porphyritic texture showed very low TE content and modification of TE patterns. These results suggest that the modification of texture and composition of TEs, as well as silicification, do not occur by a uniform process, but several processes. This may reflect the differences in temperature and the

  14. Application of Hydrothermal and Non-Hydrothermal TiO2 Nanoporous Materials as New Adsorbents for Removal of Heavy Metal Ions from Aqueous System

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    Mansoor Anbia

    2016-06-01

    Full Text Available Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD, scanning electron microscopy (SEM and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong pore size distribution peaks with average of 37.8 Å and pore volume of 0.41 cm3/g and the (Brunauer–Emmett–TellerBET specific surface area of 365 m2/g. Hydrothermal and non-hydrothermal spherical TiO2 nanoporous have been used as adsorbent to study of the adsorption behavior of Pb(II, Co(II and Ni(II ions from aqueous system in a batch system. Effect of equilibrium time on adsorption Pb(II, Co(II and Ni(II ions on these adsorbent was studied The results show that the shaking time 0.5 to 10h has no serious effect on the percentage of ions removal, and the adsorption is fast in all cases. The maximum uptake capacities of Hydrothermal and non-hydrothermal spherical TiO2 nanoporous was calculated. Both hydrothermal and non-hydrothermal TiO2 nanoporous materials were found to have very good potential as new adsorbents in removal of these ions. In batch systems the maximum uptake capacities of Pb(II, Ni(II and Co(II on the hydrothermal and non-hydrothermal TiO2 nanoporous materials was Co(II > Pb(II > Ni(II and Co(II > Ni(II > Pb(II, respectively.

  15. Geophysical image of the hydrothermal system of Merapi volcano

    Science.gov (United States)

    Byrdina, S.; Friedel, S.; Vandemeulebrouck, J.; Budi-Santoso, A.; Suhari; Suryanto, W.; Rizal, M. H.; Winata, E.; Kusdaryanto

    2017-01-01

    We present an image of the hydrothermal system of Merapi volcano based on results from electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT models identify two distinct low-resistivity bodies interpreted as two parts of a probably interconnected hydrothermal system: at the base of the south flank and in the summit area. In the summit area, a sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20-50 Ω m) from the resistive andesite lava flows and pyroclastic deposits (2000-50,000 Ω m). The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The significative diffuse CO2 degassing (with a median value of 400 g m-2 d-1) is observed in a narrow vicinity of the active crater rim and close to the ancient rim of Pasar-Bubar. The total CO2 degassing across the accessible summital area with a surface of 1.4 ṡ 105 m2 is around 20 t d-1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200-230 t d-1). This drop in the diffuse degassing from the summit area can be related to the decrease in the magmatic activity, to the change of the summit morphology, to the approximations used by Toutain et al. (2009), or, more likely, to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100,000 Ω m, resistivity as low as 10 Ω m has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. No evidence of the hydrothermal system is found on the basis of the north flank at the same depth. This asymmetry might be caused by the asymmetry of the heat supply source of Merapi whose activity is moving south or/and to the asymmetry in

  16. Petrological evolution of subducted rodingite from seafloor metamorphism to dehydration of enclosing antigorite-serpentinite (Cerro del Almirez massif, southern Spain)

    Science.gov (United States)

    Laborda-López, Casto; López Sánchez-Vizcaíno, Vicente; Marchesi, Claudio; Gómez-Pugnaire, María Teresa; Garrido, Carlos J.; Jabaloy-Sánchez, Antonio; Padrón-Navarta, José Alberto

    2016-04-01

    Rodingites are common rocks associated with serpentinites in exhumed terrains that experienced subduction and high pressure metamorphism. However, the response of these rocks to devolatilization and redox reactions in subduction settings is not well constrained. In the Cerro del Almirez ultramafic massif (southern Spain) rodingites constitute about 1-2% of the total volume of exposed rocks. Metarodingites are enclosed in antigorite-serpentinite and chlorite-harzburgite separated by a transitional zone that represents the front of prograde serpentinite-dehydration in a paleo-subduction setting (Padrón-Navarta et al., 2011). Metarodingites occur as boudin lenses, 1 to 20 m in length and 30 cm to 2 m in thickness. During serpentinization of peridotite host rocks, dolerites and basalts precursor of rodingites underwent intense seafloor metasomatism, causing the enrichment in Ca and remobilization of Na and K. Subsequent metamorphism during subduction transformed the original igneous and seafloor metamorphic mineralogy into an assemblage of garnet (Ti-rich hydrogrossular), diopside, chlorite, and epidote. During prograde metamorphism, garnet composition changed towards higher andradite contents. High-pressure transformation of enclosing antigorite-serpentinite to chlorite-harzburgite released fluids which induced breakdown of garnet to epidote in metarodingites. Ti liberation by this latter reaction produced abundant titanite. Released fluids also triggered the formation of amphibole by alkalis addition. Highly recrystallized metarodingites in chlorite-harzburgite present a new generation of idiomorphic garnet with composition equal to 10-30% pyrope, 30-40% grossular and 35-55% almandine + spessartine. This garnet has titanite inclusions in the core and rutile inclusions in the rim. The contact between metarodingites and ultramafic rocks consists of a metasomatic zone (blackwall) with variable thickness (7 to 40 cm) constituted by chlorite, diopside, and titanite

  17. Estudio metalográfico de la calidad del cobre producido en las fundiciones de Cerro Muriano (Córdoba durante el Período Romano Altoimperial

    Directory of Open Access Journals (Sweden)

    Calabrés, R.

    1995-10-01

    Full Text Available The copper obtaining process depends on a great quantity of variables and presents complex controlling. The mentioned obtaining process was well known since the Roman Age. The knowledge of copper of the casting process was higher than expected, taking account of the studies with first melting copper samples localized at an archaeological deposit in Cerro Muriano (Córdoba, Spain and dated at the 1st Century B.C. and 1st Century A.C. The existence of a cellular and dendritic-cellular solidification in the studied samples, together with other realized analysis, show a production of copper with high purity. Present work allows to conclude that the three basic processes on copper casting (roasting, smelting, slagging and conversion were well known. This knowledge was due to the experience, although they did not know the chemical and physical phenomena.

    El proceso de obtención de un cobre, más o menos puro, depende de gran cantidad de variables y es difícil de controlar. Antes de la romanización, dicho proceso de obtención ya era conocido. Utilizando cobres de primera fusión localizados en un yacimiento arqueológico sito en Cerro Muriano (Córdoba datados en los siglos I a.C. y I d.C., se ha determinado que sus elaboradores tenían un conocimiento del proceso de fundición de cobre superior al esperado. La existencia de una solidificación celular y celular dendrítica en las muestras estudiadas, así como los análisis realizados, indican una producción de cobre de alta pureza. El estudio permite concluir que, en época romana, ya se conocían los tres procesos básicos de la obtención de cobre: tostación, fusión y escorificación y conversión. Dicho proceso era conocido gracias a la gran experiencia acumulada, aunque estos metalurgistas desconocían las causas que originaban los resultados finales obtenidos.

  18. Las mineralizaciones de barita de Cerro del Hierro (Sevilla. Características mineralógicas y geoquímica

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    Galán Huertos, E.

    1992-08-01

    Full Text Available Different barite deposits (stratabound, vein and karstic types are occurring in the Lower Cambrian carbonatic materials of the Cerro del Hierro, Sevilla (Ossa-Morena Zone. Calcite, hematite, goethite and minor chalcopyrite are common associated minerals, with limonite and malachite as alterations. The content of barite can be as high as 98 %. There is a close relationship between barite type and Sr content (vein 34S ranges between 32,7 ‰ (stratiform barites and 20,7 ‰ (epigenetic barites. The 87Sr/86Sr ratio for the epigenetic barites oscillates between 0.70873 and 0.71112 which could be the result of the infiuence of different mineralization solutions. A primary origin for the stratabound barites is proposed, in relation with the diagenesis of the limestones occurred during the Lower Cambrian. Epigenetic barites were formed after the Hercynian Orogenesis by remobilization of the stratiform ores, with Ba and Sr supplied from the lixiviation of the host rocks. The last process could be much more important for the karstic barite formation.En los materiales carbonatados del Cámbrico inferior del Cerro del Hierro (Zona de Ossa-Morena existen diversos tipos de mineralizaciones de barita (estratoligadas, filonianas y kársticas. La barita está acompañada de calcita, hematites, goethita, y calcopirita accesoria, y limonitas y malaquita como fases tardías de alteración, y presenta una gran pureza química [ > 98% SO4(Ba,Sr]. Existe una relación entre la tipología de la barita y el contenido en Sr, en el sentido de filonianas 34S en las baritas oscila entre 32,7 ‰ para las estratoligadas y 20,7 ‰ para las epigenéticas. Las razones 87Sr/86Sr determinadas sobre baritas epigenéticas varían entre 0.70873 y 0.71112, lo que puede interpretarse como consecuencia de la participación de diversos tipos de soluciones mineralizantes. Se propone un origen primario de las baritas estratoligadas, en relación con la diagénesis de los

  19. Estudio de los fundentes utilizados en la metalurgia del cobre en Cerro Muriano (Córdoba durante el período Romano Altoimperial

    Directory of Open Access Journals (Sweden)

    Criado, A. J.

    1996-10-01

    Full Text Available There are no doubts that Hispania was, under the Roman Empire, the most profitable and abundant in resources of all the mining districts exploded by Rome -Hispania, Galia, Danubian Provinces, Dacia, Greece, Asia Minor, Syria, Egypt and North Africa-. Plinius gives the same data and hands many more in the passages dedicated to the mining and the working of the metals in his Natural History. Of all the many mining places that this author refers, the exploiting in copper at Cerro Muriano presents the main interest; of this he says that it was of an unbeatable quality, used, among other applications, to manufacture the very famous "Copper of Campania". The utilization of fusing agents, adapted to the process of copper obtainment, is fundamental for obtaining this high quality. The addition of these fusing agents was very important for the control of the work parameters and to reach the required temperatures. The high purity of the obtained copper shows a very close knowledge of the phenomena involved in the process.

    Durante el Imperio Romano, de todos los distritos mineros explotados por Roma -Hispania, Galia, las provincias danubianas, Dacia, Grecia, Asia Menor, Siria, Egipto y el Norte de África-, sin duda el más rentable y más abundante en recursos era Hispania. Plinio facilita muchos datos en los pasajes dedicados a la minería y el trabajo de los metales en su Historia Natural. Entre los muchos lugares mineros que este autor cita, nos interesa ahora la explotación de cobre en Cerro Muriano, del cual dice que era de una calidad inmejorable, utilizado, entre otras aplicaciones, para fabricar el famosísimo cobre de Campania. Para poder obtener esta elevada calidad, es fundamental la utilización de fundentes adecuados en el proceso de obtención de cobre. La adición de estos fundentes era vital para controlar los parámetros de trabajo y alcanzar las temperaturas requeridas. La elevada pureza del cobre obtenido demuestra un

  20. A Conceptual Model to Link Anomalously High Temperature Gradients in the Cerros del Rio Volcanic Field to Regional Flow in the Espanola Basin, New Mexico

    Science.gov (United States)

    Fillingham, E. J.; Keller, S. N.; McCullough, K. R.; Watters, J.; Weitering, B.; Wilce, A. M.; Folsom, M.; Kelley, S.; Pellerin, L.

    2015-12-01

    Temperature-depth well data along with electromagnetic (EM) data were collected by students of the Summer of Applied Geophysics Experience (SAGE) 2015 field season in the Espanola Basin, New Mexico. The data from this year, in addition to data acquired since 2013, were used to construct a conceptual east-west cross-section of the Espanola Basin and the adjacent highlands in order to evaluate the regional flow system. Vertical geothermal gradients from several monitoring wells were measured using a thermistor. Anomalously warm geothermal gradients were mapped in the Cerros del Rio volcanic field in the basin just east of the Rio Grande. Temperature gradients are up to 70℃/km, while the background geothermal gradients in the Rio Grande rift zone generally show 28℃-35℃/km. This anomaly extends to the Buckman well field, which supplies water to the city of Santa Fe. Overpumping of this well field has led to subsidence in the past. However, discharge temperature plots indicate that the temperature gradients of the Buckman field may be rebounding as pumping is reduced. Audiomagnetotelluric (AMT) and transient electromagnetic (TEM) data were acquired in the vicinity of three monitoring wells. TEM and AMT methods complement each other with the former having depths of investigation of less than ten to hundreds of meters and AMT having depths of investigation comparable to the wells deeper than 500m. These datasets were used collectively to image the subsurface stratigraphy and, more specifically, the hydrogeology related to shallow aquifers. The EM data collected at these wells showed a trend indicating a shallow aquifer with a shallower resistive layer of approximately 100 ohm-m at 70-100 meters depth. Beneath this resistive layer we resolved a more conductive, clay-rich layer of 10 ohm-m. These resistivity profiles compliment the electrical logs provided by Jet West, which indicate shallower sandstone interbedded with silt on top of more silt-dominant layers. Our

  1. Mecanismo de inserción del Laboratorio Tecnológico del Uruguay en el Parque Tecnológico Industrial del Cerro

    Directory of Open Access Journals (Sweden)

    Laura Márquez

    2011-05-01

    Full Text Available El Laboratorio Tecnológico del Uruguay, LATU, teniendo en cuenta su misión: "Impulsar el desarrollo sustentable del país y su inserción internacional a través de la innovación y transferencia de soluciones de valor, en servicios analíticos, metrológicos, tecnológicos, de gestión y evaluación de la conformidad de a cuerdo a la normativa aplicable", está trabajando en el apoyo a las micro, pequeñas y medianas empresas del país. Como estrategia para contribuir al logro de la misión, se ha iniciado una política de descentralización, eligiendo zonas de actividad con requerimientos similares, en cuanto a las necesidades de mejora de la competitividad de las empresas. En la zona de Montevideo llamada el Cerro, el gobierno municipal gestiona un Parque Tecnológico Industrial, PTIC, apoyando y alojando en su predio, 58 empresas. Este Parque se puede ver como un conglomerado de empresas, en una misma zona, con necesidades similares. El mecanismo de inserción del LATU en el PTIC, ha contado con una herramienta fundamental que es la instalación de una oficina en el propio Parque, cuyo objetivo principal es facilitar y asegurar la contribución del LATU al desarrollo y competitividad de las mipymes allí agrupadas.AbstractAttending to the Technological Laboratory of Uruguay (LATU's mission, to promote the sustainable development of the country and its international insertion through innovation and transfer of valuable solutions, it is working on support for micro, small and medium companies. As a management strategy to achieve the mission, a policy of decentralization, approaching to the enterprises, it's being implemented. In this context, it has been developed a methodology for insertion in the Industrial Technological Park of Cerro, PTIC. This park, which is managed by the municipal government, agglomerates a group of companies, in the same area with similar needs. The LATU's mechanism of insertion in the PTIC, has counted on with a

  2. Elemental geochemical records of seafloor hydrothermal activities in the sediments from the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; YU Zenghui; DU Tongjun

    2007-01-01

    The major and minor element contents in the sediment core H9 from the hydrothermal fields of the Okinawa Trough show a sharp change at the depth of 80 cm. The elements enriched in the upper 80 cm core are those enriched in the hydrothermal deposits and in the surface sediments recovered from the hydrothermal fields in the trough, which indicates the input of hydrothermal materials. Comparing with other hydrothermal sediments from Mid-ocean Ridges or the Lau Basin, the degree of the enrichment of elements iron, copper, cobalt, and nickel is relatively low. However, the enrichment of elements manganese, lead, arsenic, antimony and mercury is remarkable. The average contents of these elements in the upper 80 cm core sediments are three to six times those in the lower section, and 3 ~ 12 times those in the surface sediments which are not influenced by hydrothermal activities. Hydrothermal activities have contributed significant manganese, lead, arsenic, antimony and mercury to the sediments, and these elements are distinct indicators for the hydrothermal activity in the Okinawa Trough. The significant enrichment of these elements in Core H9 upward from the depth 80 cm indicates the start or the significant enhancing of the hydrothermal activity in this area at about 5 740 aB. P. The average accumulation rate of manganese during this period is about 40 461 μg/( cm2 · ka), which is similar to the hydrothermal sediments in the Lau Basin or the East Pacific Rise.

  3. Andesita Cerro Bola: Nueva unidad vinculada al magmatismo mioceno de la Cordillera de Olivares, San Juan, Argentina (30°35´S; 69°30´O Cerro Bola Andesite: New unit linked to the Miocene magmatism of the Olivares Cordillera, San Juan (30°35' S ; 68°30' W

    Directory of Open Access Journals (Sweden)

    A.F. Wetten

    2005-03-01

    Full Text Available El área de estudio se halla en la zona de Tocota, inmediatamente al este de la Cordillera de Olivares, en el borde oriental de la Cordillera Frontal, provincia de San Juan. En ella se encuentran unidades ígneas y sedimentarias del ciclo gondwánico, las que fueron intruidas y cubiertas en relación discordante por cuerpos subvolcánicos y volcánicos asignados anteriormente al ciclo ándico en sentido amplio, los cuales constituyen el principal objeto del presente estudio. Estos cuerpos han sido mapeados a fin de poder caracterizarlos adecuadamente, en el contexto estratigráfico de la región. Los afloramientos de interés han sido reconocidos en el cerro Bola y alrededores, donde se observan distribuidos irregularmente, cubriendo un área superior a 5 km². Las rocas, de coloración gris clara y composición andesítica - fenoandesítica, presentan estructuras de domo y colada. Estos afloramientos serían correlacionables con la unidad volcánica Pircas (Mioceno, la que aflora al oeste, y conformarían un evento magmático posterior al de pórfidos de diferente composición situados tanto en el arroyo Chita como en el cerro Divisadero. La extensión del área involucrada, la uniformidad litológica, el bajo grado de alteración y una edad radimétrica obtenida por el método K/Ar, fueron considerados para proponer a estas volcanitas como una unidad litoestratigráfica de edad miocena superior, con la denominación de Andesita Cerro Bola.The study area is located in the region of Tocota Creek, close to the Cordillera Olivares, eastern border of the Frontal Range, San Juan province. In this place, igneous and sedimentary units belonging to the Gondwanic cycle, were recognized. These units were intruded and unconformably covered by subvolcanic and volcanic bodies, which were commonly referred to the Tertiary or Andean cycle. The study of these bodies is the main proposal of this work. These bodies had been mapped in order to characterize them

  4. Edad y rasgos petrográficos y geoquímicos de cuerpos subvolcánicos asignables a la Formación Cerro León, este del Macizo del Deseado, Santa Cruz Age and petrography and geochemistry features of subvolcanic outcrops from Cerro León Formation, east of the Deseado Massif, Santa Cruz

    Directory of Open Access Journals (Sweden)

    D. Guido

    2004-12-01

    Full Text Available Se presentan nuevos afloramientos de cuerpos subvolcánicos correlacionables con la Formación Cerro León en el sector oriental del Macizo del Deseado. Esta unidad aflora en dos sectores, en el bajo Leonardo y en el afloramiento Bahía Laura del Complejo Río Deseado. El primer sector presenta trece diques y un filón capa intruyendo a las sedimentitas pérmicas de la Formación La Golondrina y el segundo sector comprende tres diques que intruyen a rocas del basamento. Se trata de rocas de color gris a negro, frecuentemente alteradas, con textura microgranuda a porfírica, con fenocristales de plagioclasa, diópsido (En42 Fs11 Wo47 y en menor medida de hornblendas ricas en Mg (magnesio hastingsita, en una matriz holocristalina de textura intergranular. Son rocas subalcalinas de composiciones basalto-andesita y con afinidades calcoalcalinas. La edad Ar/Ar obtenida en una de estas muestras (180,1±1,5 Ma representa la primer determinación realizada en esta unidad y es coherente con las relaciones estratigráficas observadas para esta formación. La comparación con rocas ígneas jurásicas de la provincia geológica Macizo del Deseado, favorece la vinculación temporal y genética con el evento volcánico-piroclástico del Jurásico medio a superior (Formación Bajo Pobre y Grupo Bahía Laura. Sin embargo, la diferencia en las edades Ar/Ar, sugieren una interrupción entre el evento subvolcánico (180 Ma y el volcanismo Jurásico medio a superior (177 a 150 Ma. Se considera, preliminarmente, que los cuerpos subvolcánicos de la Formación Cerro León representarían las primeras evidencias magmáticas del rift jurásico en el Macizo del Deseado.New subvolcanic outcrops, correlated with the Cerro León Formation and located in the eastern Deseado Massif, are presented. This unit outcrops in two sectors, the Leonardo depression and the Bahía Laura outcrop of the Río Deseado Complex. In the first sector there are thirteen dikes and a sill

  5. INFLUENCE OF REACTION CONDITIONS ON LIGNIN HYDROTHERMAL TREATMENT

    Directory of Open Access Journals (Sweden)

    Xabier eErdocia

    2014-04-01

    Full Text Available Organosolv lignin, obtained from olive tree pruning under optimised conditions, was subjected to a hydrothermal depolymerisation process catalysed by sodium hydroxide. The depolymerisation of lignin was carried out at 300 ºC using different reaction times (20, 40, 60, 70, 80, 90 and 100 min in order to study the influence of this parameter on lignin depolymerisation. The resulting products (oil and residual lignin were measured and analysed by different techniques (GC/MS, HPSEC and pyrolysis-GC/MS in order to determine their nature and composition. Coke was also formed, at a lower quantity, incompetitive repolymerisation reactions during the lignin hydrothermal treatment. The maximum oil yield and concentration of monomeric phenolic compounds was obtained after80 min of reaction time. The highest reaction time studied (100 min had the worst results with the lowest oil yield and highest coke production.

  6. Formic acid production from carbohydrates biomass by hydrothermal reaction

    Energy Technology Data Exchange (ETDEWEB)

    Yun, J; Kishita, A; Tohji, K; Enomoto, H [Graduate School of Environmental Studies, Tohoku University, Sendai, Miyagi 980-8579 (Japan); Jin, F, E-mail: yun@bucky1.kankyo.tohoku.ac.j [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai, 200091 (China)

    2010-03-01

    The formation of formic acid or formate salts by hydrothermal oxidation of model biomass materials (glucose, starch and cellulose) was investigated. All experiments were conducted in a batch reactor, made of SUS 316 tubing, providing an internal volume of 5.7 cm{sup 3}. A 30 wt% hydrogen peroxide aqueous solution was used as an oxidant. The experiments were carried out with temperature of 250{sup 0}C, reaction time varying from 0.5 min to 5 min, H{sub 2}O{sub 2} supply of 240%, and alkaline concentration varying from 0 to 1.25 M. Similar to glucose, in the cases of the oxidation of hydrothermal starch and cellulose, the addition of alkaline can also improve the yield of formic acid. And the yield were glucose>starch> cellulose in cases of with or without of alkaline addition.

  7. Tectonic and Hydrothermal Activities in Debagh, Guelma Basin (Algeria

    Directory of Open Access Journals (Sweden)

    Said Maouche

    2013-01-01

    Full Text Available Quaternary and Pliocene travertines, deposited from hot springs, can reveal much about neotectonic and hydrothermal activity. The aim of this work is the understanding of the actual tectonic activity in the Guelma Basin and in one of its spa structures. Gravity data were collected during a field study in the Hammam Debagh (HD area and then analyzed to better highlight the architecture of its subsurface underlying structures. This analysis was performed by means of a Bouguer anomaly, upward continuations, and residual and derivative maps. Comparison of gravity maps, field geology, geomorphic observations, and structural maps allowed us to identify the major structural features in the Hammam Debagh. As a result, we confirm the position of the Hammam Debagh active fault which is superimposed to the hydrothermal active source in the NW-SE direction characterized by a negative gravity anomaly.

  8. Flow and permeability structure of the Beowawe, Nevada hydrothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Faulder, D.D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Johnson, S.D.; Benoit, W.R. [Oxbow Power Services, Inc., Reno, NV (United States)

    1997-05-01

    A review of past geologic, geochemical, hydrological, pressure transient, and reservoir engineering studies of Beowawe suggests a different picture of the reservoir than previously presented. The Beowawe hydrothermal contains buoyant thermal fluid dynamically balanced with overlying cold water, as shown by repeated temperature surveys and well test results. Thermal fluid upwells from the west of the currently developed reservoir at the intersection of the Malpais Fault and an older structural feature associated with mid-Miocene rifting. A tongue of thermal fluid rises to the east up the high permeability Malpais Fault, discharges at the Geysers area, and is in intimate contact with overlying cooler water. The permeability structure is closely related to the structural setting, with the permeability of the shallow hydrothermal system ranging from 500 to 1,000 D-ft, while the deeper system ranges from 200 to 400 D-ft.

  9. The formation of titania polymorphs under hydrothermal condition

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHI; Erwei(施尔畏); LI; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HU; Xingfang(胡行方)

    2002-01-01

    The formation process of crystal polymorphs of titania under hydrothermal condition is studied.According to the experimental results and theoretic analysis,the formation process of crystal polymorphs can be described as a unit process.It includes the formation of growth units,the formation of nuclei through the polymerization of growth unit,and the growth of crystallites.The influence of the environmental phase and growth conditions on the formation of polymorphs is reflected in the changes of the structures of growth units.For example,when changing the pH of the reaction medium,the structure of growth unit with the highest stable energy in the hydrothermal system changes.Then different titania polymorphs can be prepared.The absorption,movement,crystallization or desorption of the growth unit are related to crystalline structure.On the other hand,the formation of crystal inner defects is related to the disturbance of the crystallizing process.``

  10. Thermodynamic analysis of hydrogen production via hydrothermal gasification of hexadecane

    KAUST Repository

    Alshammari, Yousef M.

    2012-04-01

    This work reports the equilibrium behaviour of the hydrothermal gasification of hexadecane, a heavy saturate model compound, under non-oxidative isothermal and oxidative adiabatic conditions, using the Peng-Robinson equation of state and the direct minimisation of Gibbs free energy employed within the Aspen HYSYS. This modelling enabled establishing both the limits and optimum conditions at which the hydrogen molar yield may be theoretically maximised. The effects of parameters including the reactor isothermal temperature, pressure, water to carbon ratio, and oxygen to carbon ratio on the molar yields of produced gaseous species were analysed. The model has been validated by comparing its results with different reported modelling and experimental data under identical conditions which resulted in a good agreement. The results reported in this work show the potential of achieving economic yields of hydrogen and syngas from liquid hydrocarbons under downhole hydrothermal conditions. © 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights.

  11. Characterization of biochar from hydrothermal carbonization of bamboo

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Daniel; Escala, Marina [Institute of Natural Resource Sciences, School of Life Sciences and Facility Management, Zurich University of Applied Sciences, Waedenswil (Switzerland); Supawittayayothin, Kawin; Tippayawong, Nakorn [Department of Mechanical Engineering, Chiang Mai University, Ching Mai (Thailand)

    2011-07-01

    This paper presents a preliminary investigation on producing biochar from bamboo using a technique of hydrothermal carbonization. Laboratory scale experimentation to produce carbonaceous materials was carried out. The suspended biomass samples in water were subjected to hydrothermal carbonization at 220 C, 2.2 MPa in a closed vessel for six hours. The resulting products were in solid and liquid phase. The coal-like biochar was found to have rough surface and porous structure. The aqueous solution was found to contain a high concentration of nutrients, especially nitrogen, phosphorus, and potassium. The study shows that bamboo is an interesting and adequate biomass for the production of biochar with several applications including carbon sequestration.

  12. Characterization of biochar from hydrothermal carbonization of bamboo

    Directory of Open Access Journals (Sweden)

    Daniel Schneider, Marina Escala, Kawin Supawittayayothin, Nakorn Tippayawong

    2011-07-01

    Full Text Available This paper presents a preliminary investigation on producing biochar from bamboo using a technique of hydrothermal carbonization. Laboratory scale experimentation to produce carbonaceous materials was carried out. The suspended biomass samples in water were subjected to hydrothermal carbonization at 220 C, 2.2 MPa in a closed vessel for six hours. The resulting products were in solid and liquid phase. The coal-like biochar was found to have rough surface and porous structure. The aqueous solution was found to contain a high concentration of nutrients, especially nitrogen, phosphorus, and potassium. The study shows that bamboo is an interesting and adequate biomass for the production of biochar with several applications including carbon sequestration.

  13. Hydrothermal synthesis and physicochemical properties of ruthenium(0) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Dikhtiarenko, A., E-mail: dikhtiarenkoalla@uniovi.es [Departamento de Quimica Organica e Inorganica, Universidad de Oviedo - CINN, 33006 Oviedo (Spain); Khainakov, S.A.; Garcia, J.R.; Gimeno, J. [Departamento de Quimica Organica e Inorganica, Universidad de Oviedo - CINN, 33006 Oviedo (Spain); Pedro, I. de; Fernandez, J. Rodriguez [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, 39005 Santander (Spain); Blanco, J.A. [Departamento de Fisica, Universidad de Oviedo, 33007 Oviedo (Spain)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer Ruthenium nanoparticles were synthesized by hydrothermal technique. Black-Right-Pointing-Pointer The average size of the nanoparticles are depend on the reducing agent used. Black-Right-Pointing-Pointer The magnetic response seems to be dominated by a paramagnetic contribution characteristic of the band electronic magnetism of the ruthenium(0) nanoparticles. - Abstract: The synthesis of ruthenium nanoparticles in hydrothermal conditions using mild reducing agents (succinic acid, ascorbic acid and sodium citrate) is reported. The shape of the nanoparticles depends on the type of the reducing agent, while the size is more influenced by the pH of the medium. The magnetic response seems to be dominated by a paramagnetic contribution characteristic of the band electronic magnetism of the nanoparticles.

  14. Colorado's hydrothermal resource base: an assessment

    Energy Technology Data Exchange (ETDEWEB)

    Pearl, R.H.

    1981-01-01

    As part of its effort to more accurately describe the nations geothrmal resource potential, the US Department of Energy/Division of Geothermal Energy contracted with the Colorado Geological survey to appraise the hydrothermal (hot water) geothermal resources of Colorado. Part of this effort required that the amount of energy that could possibly be contained in the various hydrothermal systems in Colorado be estimated. The findings of that assessment are presented. To make these estimates the geothermometer reservoir temperatures estimated by Barrett and Pearl (1978) were used. In addition, the possible reservoir size and extent were estimated and used. This assessment shows that the total energy content of the thermal systems in Colorado could range from 4.872 x 10{sup 15} BTU's to 13.2386 x 10{sup 15} BTU's.

  15. Controlled growth of silver nanoparticles in a hydrothermal process

    Institute of Scientific and Technical Information of China (English)

    Juan Zou; Yao Xu; Bo Hou; Dong Wu; Yuhan Sun

    2007-01-01

    A two-step synthesis was used to control the shape of silver nanoparticles. First, a few spherical silver nanoparticles, ~10 nm in size, were prepared via reduction of Ag+ ions in aqueous Ag(NH3)2NO3 by poly(N-vinyl-2-pyrrolidone) (PVP). Then, in a subsequent hydrothermal treatment,the remaining Ag+ ions were reduced by PVP into polyhedral nanoparticles, or larger spherical nanoparticles formed from the small spherical seed silver nanoparticles in the first step. The morphology and size of the resultant particles depend on the hydrothermal temperature, PVP/Ag molar ratio and concentration of Ag+ ions. By using UV-visible spectroscopy (UV-vis), transmission electron microscopy (TEM) and powder X-ray diffraction (XRD), the possible growth mechanism of the silver nanoparticles was discussed.

  16. Piezoelectric Materials Synthesized by the Hydrothermal Method and Their Applications

    Directory of Open Access Journals (Sweden)

    Takeshi Morita

    2010-12-01

    Full Text Available Synthesis by the hydrothermal method has various advantages, including low reaction temperature, three-dimensional substrate availability, and automatic polarization alignment during the process. In this review, powder synthesis, the fabrication of piezoelectric thin films, and their applications are introduced. A polycrystalline lead zirconate titanate (PZT thin film was applied to a micro ultrasonic motor, and an epitaxial lead titanate (PbTiO3 thin film was estimated as a ferroelectric data storage medium. Ferroelectric and piezoelectric properties were successfully obtained for epitaxial PbTiO3 films. As lead-free piezoelectric powders, KNbO3 and NaNbO3 powders were synthesized by the hydrothermal method and sintered together to form (K,NaNbO3 ceramics, from which reasonable piezoelectric performance was achieved.

  17. Stable Isotopic Composition for Hydrothermal Vein Deposits, Southeastern Korea

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@The southeast of Korea has attracted considerable attention in the geologic community because of its extensive igneous activity and associated mineralizations from the Late Cretaceous to the Early Tertiary (Cu, Pb-Zn, W-Mo, Bi and Au-Ag hydrothermal-vein deposits, porphyry, skarn and altered clay deposits). The southeast of Korea is composed of Cretaceous sedimentary Gyeongsan basin, volcanic and plutonic rocks. Most of the mines are either closed or incapable of producing more ores because of their poor reserves. The south of the Gyeongsang basin is famous for its hydrothermal altered clay deposits associated with volcanism. In order to locate more metal resources, many researches have been conducted into the gold-silver mineralization within hydrothermai-altered deposits in the past several years. The age of plutonism ranges from 112 Ma to 44 Ma, and that of volcanism from 74 Ma to 47 Ma.

  18. Hydrothermal Habitats: Measurements of Bulk Microbial Elemental Composition, and Models of Hydrothermal Influences on the Evolution of Dwarf Planets

    Science.gov (United States)

    Neveu, Marc Francois Laurent

    Finding habitable worlds is a key driver of solar system exploration. Many solar system missions seek environments providing liquid water, energy, and nutrients, the three ingredients necessary to sustain life. Such environments include hydrothermal systems, spatially-confined systems where hot aqueous fluid circulates through rock by convection. I sought to characterize hydrothermal microbial communities, collected in hot spring sediments and mats at Yellowstone National Park, USA, by measuring their bulk elemental composition. To do so, one must minimize the contribution of non-biological material to the samples analyzed. I demonstrate that this can be achieved using a separation method that takes advantage of the density contrast between cells and sediment and preserves cellular elemental contents. Using this method, I show that in spite of the tremendous physical, chemical, and taxonomic diversity of Yellowstone hot springs, the composition of microorganisms there is surprisingly ordinary. This suggests the existence of a stoichiometric envelope common to all life as we know it. Thus, future planetary investigations could use elemental fingerprints to assess the astrobiological potential of hydrothermal settings beyond Earth. Indeed, hydrothermal activity may be widespread in the solar system. Most solar system worlds larger than 200 km in radius are dwarf planets, likely composed of an icy, cometary mantle surrounding a rocky, chondritic core. I enhance a dwarf planet evolution code, including the effects of core fracturing and hydrothermal circulation, to demonstrate that dwarf planets likely have undergone extensive water-rock interaction. This supports observations of aqueous products on their surfaces. I simulate the alteration of chondritic rock by pure water or cometary fluid to show that aqueous alteration feeds back on geophysical evolution: it modifies the fluid antifreeze content, affecting its persistence over geological timescales; and the

  19. El volcanismo bimodal del volcán cerro Corona, Alta Sierra de Somún Curá, provincia de Río Negro Bimodal volcanism of the Cerro Corona volcano in the Alta Sierra de Somún Curá (Río Negro province

    Directory of Open Access Journals (Sweden)

    Guadalupe Maro

    2012-03-01

    Full Text Available La Alta Sierra de Somún Curá es uno de los complejos volcánicos terciarios postplateau en el ambiente de la meseta basáltica de Somún Curá, en la Patagonia extrandina. En ella se encuentra el cerro Corona, un volcán en escudo que corresponde al centro de mayor altura en la región. Está construido por rocas efusivas y piroclásticas subordinadas, fundamentalmente traquiandesíticas-basálticas, con variaciones traquíticas tanto en sus flancos como en su cráter. A pesar de la bimodalidad compositional con una importante discontinuidad entre el 54 y 58 % en peso de SiO2, el presente trabajo propone que las traquitas son el producto de la evolución por cristalización fraccionada de las traquiandesitas basálticas, con cierta influencia de recargas máficas a la cámara magmática de acuerdo a la presencia de texturas de desequilibrio en los fenocristales, principalmente de las rocas félsicas.The Cerro Corona is a shield volcano situated in the Alta Sierra de Somún Curá, one of the tertiary volcanic complex that constitute the Meseta de Somún Curá, in the Extrandean Patagonia. It is the highest center in the region and it is compound mainly of basaltic trachyandesites, with trachytic variations on its flanks and crater. Despite the compositional bimodality with an important compositional gap between 54% and 58% in weight in SiO2, this work suggests that trachytes are the product of the evolution of basaltic trachyandesites through fractional crystallization, with some influence of mafic recharge to the magmatic chamber, in agreement with the presence of disequilibrium textures in fenocrystals, essentially in felsic rocks.

  20. ANÁLISIS DE MACRORRESTOS VEGETALES EN EL SITIO ARQUEOLÓGICO LOS TRES CERROS 1 (ISLA LAS MORAS, VICTORIA, ENTRE RÍOS / Macroremains plant analysis on the Tres Cerros 1 archaeological site (Las Moras island, Victoria, Entre Ríos.

    Directory of Open Access Journals (Sweden)

    María de los Milagros Colobig

    2015-06-01

    Full Text Available El presente trabajo es la primera aproximación al estudio de macrorrestos botánicos en el sitio Los Tres Cerros 1 (isla Las Moras, Victoria, Entre Ríos. Estos restos fueron recuperados mediante la técnica de flotación manual. A partir del material extraído, se exploró el rol de los recursos vegetales y su importancia en la subsistencia en los grupos humanos que habitaron el Delta Superior del río Paraná durante el Holoceno tardío. Se identificaron cinco familias: Solanaceae, Chenopodiaceae, Polygonaceae, Poaceae (Maideae y Oryzoideae y Amaranthaceae. Los estudios permitieron estimar que a partir de 700 ARCP hubo un incremento en la abundancia y variabilidad de recursos vegetales utilizados con respecto a períodos anteriores. La presencia de elementos oryzoides, y graminoides (específicamente Maideae evidenció la existencia de vegetales silvestres y domesticados, aportando nuevos registros sobre el aprovechamiento, manejo y cultivo de las plantas en el área de estudio en el Holoceno tardío.   Abstract  This paper entails the first approach to macrobotanical remains obtained from Los Tres Cerros 1 (Isla Las Moras, Victoria, Entre Ríos. The remains were recovered by means of manual flotation technique. The extracted material allowed us to explore the role played by vegetable resources role and their importance to the subsistence of human populations of Upper Paraná Delta during the late Holocene. Five botanical families were recognized: Solanaceae, Chenopodiaceae, Polygonaceae, Poaceae (Maideae and Ehrhartoideae and Amaranthaceae. Studies estimate that from 700 RCYBP, there was an increase in the abundance and variability of plant resources used, as compared to previous periods. The presence of oryzoides and graminoid elements (specifically Maideae showed the presence of wild and domesticated plants, providing new records on the use of plants in the area studied, in the late Holocene.

  1. Hydrothermal system in Southern Grass Valley, Pershing County, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Welch, A.H.; Sorey, M.L.; Olmsted, F.H.

    1981-01-01

    Southern Grass Valley is a fairly typical extensional basin in the Basin and Range province. Leach Hot Springs, in the southern part of the valley, represents the discharge end of an active hydrothermal flow system with an estimated deep aquifer temperature of 163 to 176/sup 0/C. Results of geologic, hydrologic, geophysical and geochemical investigations are discussed in an attempt to construct an internally consistent model of the system.

  2. Hydrothermal heat discharge in the Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, S.E.; Mariner, R.H.

    2010-01-01

    Hydrothermal heat discharge in the Cascade Range includes the heat discharged by thermal springs, by "slightly thermal" springs that are only a few degrees warmer than ambient temperature, and by fumaroles. Thermal-spring heat discharge is calculated on the basis of chloride-flux measurements and geothermometer temperatures and totals ~ 240 MW in the U.S. part of the Cascade Range, excluding the transient post-1980 discharge at Mount St. Helens (~80 MW as of 2004-5). Heat discharge from "slightly thermal" springs is based on the degree of geothermal warming (after correction for gravitational potential energy effects) and totals ~. 660. MW. Fumarolic heat discharge is calculated by a variety of indirect and direct methods and totals ~160 MW, excluding the transient mid-1970s discharge at Mount Baker (~80 MW) and transient post-1980 discharge at Mount St. Helens (>. 230. MW as of 2005). Other than the pronounced transients at Mount St. Helens and Mount Baker, hydrothermal heat discharge in the Cascade Range appears to be fairly steady over a ~25-year period of measurement. Of the total of ~. 1050. MW of "steady" hydrothermal heat discharge identified in the U.S. part of the Cascade Range, less than 50. MW occurs north of latitude 45??15' N (~0.1 MW per km arc length from 45??15' to 49??N). Much greater rates of hydrothermal heat discharge south of 45??15'N (~1.7 MW per km arc length from 40?? to 45??15'N) may reflect the influence of Basin and Range-style extensional tectonics (faulting) that impinges on the Cascades as far north as Mount Jefferson but is not evident farther north. ?? 2010.

  3. Sourcing hydrocarbons in CO2-rich in hydrothermal systems

    OpenAIRE

    Fiebig, J; F. Tassi; D'Alessandro, W.; A. B. Woodland

    2009-01-01

    Methane (CH4) emanating from a continental volcanichydrothermal system in Nisyros, Greece, is processed through the abiogenic reduction of mantle- and marine limestonederived CO2 [1]. Evidence for the occurrence of abiogenic hydrothermal reduction of CO2 is from the chemical and carbon isotopic equilibrium patterns. We have further characterized this abiogenic methane (C1) source for the concentrations of ethane (C2) and propane (C3), as well as for the hydrogen isotop...

  4. HYDROTHERMAL SYNTHESIS OF NANO-METER MICROPOROUS ZINC FERRITE

    Institute of Scientific and Technical Information of China (English)

    Xiaoling Hu; Ping Guan; Xin Yan

    2004-01-01

    Nano-meter microporous zinc ferrite was prepared by a hydrothermal method, using triethylamine as a template. Adsorption curves showed that the product had a microporous structure. The effects of precursor pH, reaction temperature and reaction time on the preparation were studied, yielding optimal conditions: pH=11,448 K, 360 min. The morphology of zinc ferrite as observed by TEM, showed that zinc ferrite was well-crystallized and well-dispersed with little conglomeration.

  5. Hydrothermal liquefaction of barley straw to bio-crude oil

    DEFF Research Database (Denmark)

    Zhu, Zhe; Rosendahl, Lasse; Toor, Saqib;

    2015-01-01

    Hydrothermal liquefaction (HTL) of barley straw with K2CO3 at different temperatures (280–400 C) was conducted and compared to optimize its process conditions; the aqueous phase as a co-product from this process was recycled to explore the feasibility of implementing wastewater reuse for bio...... a detailed insight into the HTL behavior of barley straw, and offers potential opportunities and benefits for bio-crude oil production through the reuse of aqueous phase....

  6. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Directory of Open Access Journals (Sweden)

    Steven L Chown

    2012-01-01

    Full Text Available The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  7. Hydrothermal synthesis and characterization of zirconia based catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Caillot, T., E-mail: Thierry.caillot@ircelyon.univ-lyon1.fr; Salama, Z.; Chanut, N.; Cadete Santos Aires, F.J.; Bennici, S.; Auroux, A.

    2013-07-15

    In this work, three equimolar mixed oxides ZrO{sub 2}/CeO{sub 2}, ZrO{sub 2}/TiO{sub 2}, ZrO{sub 2}/La{sub 2}O{sub 3} and a reference ZrO{sub 2} have been synthesized by hydrothermal method. The structural and surface properties of these materials have been fully characterized by X-ray diffraction, transmission electron microscopy, surface area measurement, chemical analysis, XPS, infrared spectroscopy after adsorption of pyridine and adsorption microcalorimetry of NH{sub 3} and SO{sub 2} probe molecules. All investigated mixed oxides are amphoteric and possess redox centers on their surface. Moreover, hydrothermal synthesis leads to catalysts with higher surface area and with better acid–base properties than classical coprecipitation method. Both Lewis and Brønsted acid sites are present on the surface of the mixed oxides. Compared to the other samples, the ZrO{sub 2}/TiO{sub 2} material appears to be the best candidate for further application in acid–base catalysis. - Graphical abstract: Mesoporous amorphous phase with a high surface area of titania zirconia mixed oxide obtained by hydrothermal preparation. - Highlights: • Three zirconia based catalysts and a reference were prepared by hydrothermal synthesis. • Mixed oxides present larger surface areas than the reference ZrO{sub 2}. • ZrO{sub 2}/TiO{sub 2} catalyst presents a mesoporous structure with high surface area. • ZrO{sub 2}/TiO{sub 2} catalyst presents simultaneously strong acidic and basic properties.

  8. Rapid Synthesis of Carbon Dots by Hydrothermal Treatment of Lignin

    Directory of Open Access Journals (Sweden)

    Wenxin Chen

    2016-03-01

    Full Text Available A rapid approach has been developed for the fluorescent carbon dots (CDs by the hydrothermal treatment of lignin in the presence of H2O2. The as-synthesized CDs were found to emit blue photoluminescence with excellent photostability. Moreover, the CDs displayed biocompatibility, low cytotoxicity, and high water solubility properties. Finally, the as-resulted CDs were demonstrated to be excellent probes for bioimaging and biosensing applications.

  9. Phase transformation of zirconia ceramics by hydrothermal degradation

    OpenAIRE

    Kawai, Yohei; Uo, Motohiro; Wang, Yong ming; Kono, Sayaka; Ohnuki, Somei; Watari, Fumio

    2011-01-01

    Zirconia has found wide application in dentistry because of its high mechanical strength and superior esthetic properties. However, zirconia degradation caused by phase transformation occurring in a hydrothermal environment is of concern. In the present study, phase transformation and microstructure of tetragonal zirconia polycrystal partially stabilized with yttrium oxide (Y-TZP) and alumina-toughened zirconia (ATZ) sintered at different temperatures were estimated. On grazing angle X-ray di...

  10. Hydrothermal synthesis of zeolites from coal fly ash

    OpenAIRE

    Kotova, OB; Shabalin, Igor L; Shushkov, DA; Kocheva, LS

    2015-01-01

    The fly ash, from the combustion of coal to produce energy and heat, is an industrial waste, in which large accumulations represent a serious environmental threat. To reduce the environmental burden and improve the economic benefits of energy production, the science and industry focus on the transformation of coal combustion byproducts into new functional materials. The fly ash was studied by modern analytical methods. As a result of the hydrothermal reaction, several types of zeolites were s...

  11. The hydrothermal system in southern Grass Valley, Pershing County, Nevada

    Science.gov (United States)

    Welch, Alan H.; Sorey, M.L.; Olmsted, F.H.

    1981-01-01

    Southern Grass Valley is typical extensional basin in the Basin and Range province. Leach Hot Springs, in the southern part of the valley, represents the discharge end of an active hydrothermal flow system with an estimated deep aquifer temperature of 163-173C. This report discusses results of geologic, hydrologic, geophysical and geochemical investigations used in an attempt to construct an internally consistent model of the system. (USGS)

  12. Hydrothermal Synthesis of Ni/Al Layered Double Hydroxide Nanorods

    OpenAIRE

    Yun Zhao; Fenfei Xiao; Qingze Jiao

    2011-01-01

    Ni/Al layered double hydroxide (LDH) nanorods were successfully synthesized by the hydrothermal reaction. The crystal structure of the products was characterized by X-ray diffraction (XRD). The morphology of the products was observed using transmission electron microscopy (TEM) and field emission scanning electron microscopy (SEM). The influences of reaction time and pH value on the morphology of the Ni/Al LDHs were investigated. The result showed that the well-crystallized nanorods of Ni/Al ...

  13. Tailored super magnetic nanoparticles synthesized via template free hydrothermal technique

    Science.gov (United States)

    Attallah, Olivia A.; Girgis, E.; Abdel-Mottaleb, Mohamed M. S. A.

    2016-01-01

    Magnetite nanoparticles of controlled shape and dimensions were synthesized using a modified hydrothermal technique. The influence of different synthesis conditions on the shape, size (length and diameter), structure and magnetic properties of the prepared nanoparticles is presented. The mineral phases, the morphologies, size distribution of the resulting magnetic nanoparticles and their magnetic properties were characterized using different characterization methods. We designed magnetite nanoparticles with different morphologies (nanospheres, nanorods, nanocubes and hexagons) and with improved saturation magnetization reaching 90 emu/g.

  14. Coupling Magnetotellurics and Hydrothermal Modeling to Further Understand Geothermal Resources

    Science.gov (United States)

    Folsom, M.; Pepin, J.; Kelley, S.; Person, M. A.; Blom, L.; Love, D.

    2015-12-01

    A comprehensive knowledge of the groundwater flow patterns associated with geothermal resources is critical to sustainable resource management and to discovering blind geothermal systems. Magnetotellurics (MT), which provides subsurface electrical conductivity information to substantial depths, has the ability to image geothermal reservoir features, such as conductive clay caps and hot, saline groundwater circulating within geothermal systems. We have used MT data along with 2D hydrothermal modeling, constrained by temperature, salinity and carbon-14 data, to explore possible deep groundwater circulation scenarios near the Sevilleta National Wildlife Refuge, in the Rio Grande Rift, central New Mexico. The area is underlain by a 100 to 150-m thick molten sill emplaced approximately 19 km below the surface. This sill is referred to locally as the Socorro Magma Body (SMB). Previous studies by Mailloux et al. (1999) and Pepin et al. (2015) suggest that the crystalline basement rocks in this region of the Rio Grande Rift can be significantly fractured to depths of 4-8 km and have permeabilities as high as 10-14 to 10-12 m2. The combination of high permeability conditions and the presence of the SMB makes this particular region a promising candidate for discovering a blind geothermal system at depth. We constructed a 2D hydrothermal model that traverses a 64-km zone of active uplift that is associated with the SMB. We also completed a 12-km long, 9-station MT transect across a portion of this profile, where land access was permitted and electromagnetic noise was minimal. Preliminary results suggest a deep convection-dominated system is a possibility, although further analysis of the MT data is necessary and ongoing. We hypothesize that using hydrothermal modeling in conjunction with MT surveys may prove to be an effective approach to discovering and managing deep regional hydrothermal resources.

  15. Experimental Investigation of Organic Synthesis in Hydrothermal Environments

    Science.gov (United States)

    Shock, Everett L.

    1998-01-01

    The results of the investigation were presented at a Astrobiology Institute General Meeting. Seafloor hydrothermal systems may be the most likely locations on the early Earth for the emergence of life. Because of the disequilibrium inherent in such dynamic, mixing environments, abundant chemical energy would have been available for formation of the building blocks of life. In addition, theoretical studies suggest that organic compounds in these conditions would reach metastable states, due to kinetic barriers to the formation of stable equilibrium products (CO2 and methane). The speciation of organic carbon in metastable states is highly dependent on the oxidation state, pH, temperature, pressure and bulk composition of the system. The goal of our research is to investigate the effects of a number external variables on the formation, transformation, and stability of organic compounds at hydrothermal conditions. We have begun experimental work to attempt to control the oxidation state of simulated hydrothermal systems by using buffers composed of mineral powders and gas mixtures. We are also beginning to test the stability of organic compounds under these conditions.

  16. Controlling the visible luminescence in hydrothermal ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Lem, Laurent L.C.; Phillips, Matthew R.; Ton-That, Cuong, E-mail: Cuong.Ton-That@uts.edu.au

    2014-10-15

    Cathodoluminescence spectra have been measured in hydrothermal and hydrogen-doped ZnO at different excitation densities and temperatures to investigate the emission efficiencies of near-band-edge (NBE), green and yellow luminescence bands. The NBE intensity depends linearly on the electron beam excitation as expected for excitonic recombination character. The intensities of the green and yellow bands are highly dependent not only on the excitation density but also on temperature. At high excitation densities ZnO exhibits dominant green emission at room temperature; the intensity of the green band can be further controlled by doping ZnO with hydrogen, which passivates green luminescence centers. Conversely at small excitation densities (< 0.1 nA) and low temperatures the visible luminescence from ZnO is predominantly yellow due to the abundance of Li in hydrothermal ZnO. The results are explained by differences in the recombination kinetics and the relative concentrations of the green and yellow centers, and illustrate that single-color emission can be achieved in ZnO by adjusting the excitation power and temperature. - Highlights: • Hydrothermal ZnO crystals are analyzed by cathodoluminescence spectroscopy. • Intensities of luminescence bands are highly dependent on excitation density. • Visible luminescence is influenced by temperature and hydrogen dopants. • Emission efficiencies are explained by recombination kinetics of defects.

  17. Hydrothermal synthesis of magnetite particles with uncommon crystal facets

    Directory of Open Access Journals (Sweden)

    Junki Sato

    2014-09-01

    Full Text Available Hydrothermal synthesis of Fe3O4 (magnetite particles was carried out using organic compounds as morphology control agents to obtain magnetite crystals with uncommon facets. It was established that the morphology of Fe3O4 crystals obtained by hydrothermal treatment of an aqueous solution containing Fe2+ and organic compounds depended on the organic compound used. The shape of the Fe3O4 particles obtained when no additives were used was quasi-octahedral. In contrast, the addition of picolinic acid, citric acid or pyridine resulted in the formation of polyhedral crystals, indicating the presence of not only {1 1 1}, {1 0 0} and {1 1 0} facets but also high-index facets including at least {3 1 1} and {3 3 1}. When citric acid was used as an additive, octahedral crystals with {1 1 1} facets also appeared, and their size decreased as the amount of citric acid was increased. Thus, control of Fe3O4 particle morphology was achieved by a simple hydrothermal treatment using additives.

  18. DESIGN OF NOVEL HIGH PRESSURE- RESISTANT HYDROTHERMAL FLUID SAMPLE VALVE

    Institute of Scientific and Technical Information of China (English)

    LIU Wei; YANG Canjun; WU Shijun; XIE Yingjun; CHEN Ying

    2008-01-01

    Sampling study is an effective exploration method, but the most extreme environments of