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Sample records for cerro prieto hydrothermal

  1. Current state of the hydrothermal geochemistry studies at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Fausto L, J.J.; Jimenez S, M.E.; Esquer P, I.

    1981-01-01

    The current state of hydrothermal geochemistry studies being carried out at the field are reported. These studies are based on the results of chemical analysis of water samples collected during 1979 and 1980 at the geothermal wells of the area known as Cerro Prieto I, as well as from those located in the Cerro Prieto II and Cerro Prieto III areas, some of which have only recently started flowing. Data are presented on the chemical variations of the main chemical constituents dissolved in the waters, as well as on the Na/K and Na-K-Ca chemical relations and the temperatures calculated from them and from SiO/sub 2/. Fluid recharge into the reservoir and its direction of flow are interpreted from isotherm contour maps of the field prepared from Na/K and Na-K-Ca geothermometry and from concentration contour maps of some of the main chemical constituents. Well M-43 is discussed as an example of a well affected by well completion problems in its production casing. Its behavior is explained on the basis of the chemical characteristics of the produced water. The chemical changes that have taken place in some of the wells during production are explained by correlating the chemistry with the production mechanisms of the well (steam-water production rates).

  2. Hydrothermal alteration of sediments associated with surface emissions from the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N.; Esquer P., I.; Elders, W.A.; Collier, P.C.; Hoagland, J.R.

    1981-01-01

    A study of the mineralogical changes associated with these hydrothermal vents was initiated with the aim of developing possible exploration tools for geothermal resources. The Cerro Prieto reservoir has already been explored by extensive deep drilling so that relationships between surface manifestations and deeper hydrothermal processes could be established directly. Approximately 120 samples of surface sediments were collected both inside and outside of the vents. The mineralogy of the altered sediments studied appears to be controlled by the type of emission. A comparison between the changes in mineralogy due to low temperature hydrothermal activity in the reservoir, seen in samples from boreholes, and mineralogical changes in the surface emission samples shows similar general trends below 180 C: increase of quartz, feldspar and illite, with subsequent disappearance of kaolinite, montmorillonite, calcite and dolomite. These mineral assemblages seem to be characteristic products of the discharge from high intensity geothermal fields.

  3. Exploration and development of Cerro Prieto

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    Teilman, M.A.; Cordon, U.J.

    1981-01-01

    A brief retrospective of the exploration and field model development at Cerro Prieto are presented. Representative field models are presented for each of the work phases. These models demonstrate how the concept of the field evolved - from a small 2 km/sup 2/ area with a relatively unknown reservoir configuration - to a geothermal resource area over 20 km/sup 2/ where the hydrothermal processes and structural environment are being studied in detail. A model integrating information from these studies was developed.

  4. Geothermal drilling in Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A., Bernardo

    1982-08-10

    The number of characteristics of the different wells that have been drilled in the Cerro Prieto geothermal field to date enable one to summarize the basic factors in the applied technology, draw some conclusions, improve systems and procedures, and define some problems that have not yet been satisfactorily solved, although the existing solution is the best now available. For all practical purposes, the 100 wells drilled in the three areas or blocks into which the Cerro Prieto field has been divided have been completed. Both exploratory and production wells have been drilled; problems of partial or total lack of control have made it necessary to abandon some of these wells, since they were unsafe to keep in production or even to be used for observation and/or study. The wells and their type, the type of constructed wells and the accumulative meters that have been drilled for such wells are summarized.

  5. Model of the heat source of the Cerro Prieto magma-hydrothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Williams, A.E.; Schiffman, P.; Cox, B.

    1982-08-10

    Earlier studies at Cerro Prieto by UCR have led to the development of a qualitative model for field flow in the geothermal system before it was drilled and perturbed by production. Current efforts are directed towards numerical modelling of heat and mass transfer in the system in this undisturbed state. A two-dimensional model assumes that the heat sources were a single basalt/gabbro intrusion which provided heat to the system as it cooled. After compiling various information on the physical properties of the reservoir, the enthalpy contained in two 1cm thick section across the reservoir orthogonal to each other was calculated. Next various shapes, sizes and depths for the intrusion as initial conditions and boundary conditions for the calculation of heat transfer were considered. A family of numerical models which so far gives the best matches to the conditions observed in the field today have in common a funnel-shaped intrusion with a top 4km wide emplaced at a depth of 5km some 30,000 to 50,000 years ago, providing heat to the geothermal system. Numerical modelling is still in progress. Although none of the models so far computed may be a perfect match for the thermal history of the reservoir, they all indicate that the intrusive heat source is young, close and large.

  6. Geohydrology of the Cerro Prieto geothermal aquifer

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez R, J.; de la Pena L, A.

    1981-01-01

    The most recent information on the Cerro Prieto geothermal aquifer is summarized, with special emphasis on the initial production zone where the wells completed in the Alpha aquifer are located. These wells produce steam for power plant units 1 and 2. Brief comments also are made on the Beta aquifer, which underlies the Alpha aquifer in the Cerro Prieto I area and which extends to the east to what is known as the Cerro Prieto II and Cerro Prieto III areas. The location of the area studied is shown. The Alpha and Beta aquifers differ in their mineralogy and cementing mineral composition, temperatures, and piezometric levels. The difference in piezometric levels indicates that there is no local communication between the two aquifers. This situation has been verified by a well interference test, using well E-1 as a producer in the Beta aquifer and well M-46 as the observation well in the Alpha aquifer. No interference between them was observed. Information on the geology, geohydrology, and geochemistry of Cerro Prieto is presented.

  7. An integrated model for the natural flow regime in the Cerro Prieto hydrothermal system based upon petrological and isotope geochemical criteria

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Williams, A.E.; Hoagland, J..

    1981-01-01

    Studies of cuttings and cores at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced.

  8. Geochemistry of igneous rocks from the Cerro Prieto geothermal field, northern Baja California, Mexico

    Science.gov (United States)

    Herzig, C. T.

    1990-08-01

    Fractional crystallization of basaltic magma, derived from an oceanic affinity source region present beneath the Salton Trough and emplaced into a pull-apart basin of this continental rift regime, produced a tholeiitic suite of hypabyssal rocks consisting of basalt, andesite and dacite within the Cerro Prieto geothermal field, located in northern Baja California, Mexico. Higher light-rare-earth-element abundances for a basalt from the Cerro Prieto geothermal field in comparison to basalts from the Gulf of California and the East Pacific Rise suggest partial assimilation of crustal materials into the parental magmas generated beneath the Salton Trough. The crustal contaminant may be present near the surface today in the form of granitoids of the Peninsular Ranges batholith, at deeper levels as hydrothermally altered materials near the base of the Salton Trough, or may be a relict feature of Tertiary subduction contained within the upper mantle beneath the Salton Trough. The Sr isotopic compositions of dacites from the nearby Cerro Prieto volcano range from 0.7029 to 0.7036, indicating an oceanic affinity source for these rocks. The suite of hypabyssal rocks of tholeiitic affinity present within the Cerro Prieto geothermal field, related by fractional crystallization, link the dacite volcano of Cerro Prieto to gabbroic plutons inferred to exist beneath the Cerro Prieto geothermal field.

  9. Integrated model for the natural flow regime in the Cerro Prieto hydrothermal system, B. C. , Mexico, based upon petrological and isotope geochemical criteria

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Williams, A.E.; Hoagland, J.R.

    1981-01-01

    Studies of cuttings and core at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced. A map showing the first occurrence of hydrothermal epidote shows a dome-shaped top to the steam-producing zone. The hottest of the mapped mineral zones - the biotite vermiculite zone - shows a dome displaced to the northeast relative to the epidote zone. Patterns of mineral zones observed in wells are consistent with patterns of oxygen isotopic ratios in calcite and quartz. Using both criteria all of the boreholes so far studied were classified as belonging to one of four different regimes. These are: (a) the thermal plume of upward flowing water close to boiling, marked by a regular sequence of prograde mineral zones and large isotopic shifts; (b) the discharge system where fluid leaks to the surface, as indicated by the occurrence of only a few low temperature mineral zones, which extend over large depth intervals with little isotope exchange; (c) the horizontal flow zone, in which boreholes penetrate reversals of both mineral zones and isotope shifts with increasing depth; and (d) the recharge zone where cold water is descending. Plotting these four types of boreholes on a map reveals a simple, consistent, pattern. This is interpreted to have been produced by a thermal plume dipping at 45/sup 0/ to the northeast.

  10. Evaluation of geologic characteristics at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.H.; Halfman, S.E.; Vonder Haar, S.P.

    1981-01-01

    Computerized well-log analysis of Cerro Prieto has led to the identification of a relatively large and irregular low-density volume extending from near the surface in the vicinity of Laguna Volcano to greater depths toward the northeast. This low-density volume is located about a plane of symmetry of a self-potential anomaly and a group of northeast trending active faults. The presence of a volume of relatively high-density rock has been recognized at shallow depths in the initially developed part of the resource. It is believed to be due to minerals deposited by cooled, rising geothermal brine. Storativity calculated from well logs at the south end of the western part of the field shows acceptable comparison with storativity calculated from well tests. The amount of fluid produced from the field during the period 1973-1977 is greater than the amount in situ calculated from the completed interval thicknesses. Because this part of the field is still producing today, fluid must be recharging this part of the field.

  11. Hydrothermal alteration zones and present reservoir conditions: an approach to define production zones at the eastern portion of the Cerro Prieto geothermal field, BC; Zonas de alteracion hidrotermal y condiciones actuales del yacimiento: un enfoque para determinar zonas productoras al oriente del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Camacho Hernandez, Juan Manuel [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: juan.camacho02@cfe.gob.mx

    2009-07-15

    Geological factors are as essential for locating new wells as they are for defining the production zones of these wells. At the Cerro Prieto geothermal field (CGCP), one of the most important geological factors is identification of the hydrothermal alteration zones (ZAH). These are divided into silica and epidote mineralogical zones (ZMSE), without CaCO{sub 3}, and silica and epidote mineralogical transition zones (ZTMSE), with CaCO{sub 3}. It has been observed that the continuous variation of reservoir thermodynamic conditions (temperature, pressure and enthalpy) is due mainly to the exploitation of geothermal resources. The presence of new thermodynamic conditions recorded at the reservoir has led to the re-location of production wells originally located during the drilling campaign of 2004 to 2006. At the geological sections on the eastern part of the CGCP, adjustments made to the well completions lie on the limits between the ZMSE and ZTMSE zones. In turn, this is related to the current, superior, thermodynamic reservoir conditions. Based on this, a new geologic approach is proposed to define possible production zones for new wells, relating the ZAH zones to current thermodynamic reservoir conditions. [Spanish] Los factores geologicos son determinantes, tanto para establecer nuevos sitios de perforacion como para determinar el intervalo productor de un pozo nuevo. En el campo geotermico de Cerro Prieto (CGCP) una de los factores mas importantes es la determinacion de las zonas de alteracion hidrotermal (ZAH) que se dividen en dos: zona mineralogica de silice y epidota (ZMSE), sin presencia de CaCO{sub 3}, y zona de transicion mineralogica de silice y epidota (ZTMSE), con presencia de CaCO{sub 3}. Por otra parte, tambien se ha constatado que la continua variacion de las condiciones termodinamicas del yacimiento (temperatura, presion y entalpia) es originada en buena medida por la explotacion del recurso geotermico. La ocurrencia de nuevas condiciones

  12. Evolution of the Cerro Prieto geothermal system as interpreted from vitrinite reflectance under isothermal conditions

    Energy Technology Data Exchange (ETDEWEB)

    Barker, C.E. (US Geological Survey, Denver, CO); Pawlewicz, M.J.; Bostick, N.H.; Elders, W.A.

    1981-01-01

    Temperature estimates from reflectance data in the Cerro Prieto system correlate with modern temperature logs and temperature estimates from fluid inclusion and oxygen isotope geothermometry indicating that the temperature in the central portion of the Cerro Prieto System is now at its historical maximum. Isoreflectance lines formed by contouring vitrinite reflectance data for a given isothermal surface define an imaginary surface that indicates an apparent duration of heating in the system. The 250/sup 0/C isothermal surface has a complex dome-like form suggesting a localized heat source that has caused shallow heating in the central portion of this system. Isoreflectance lines relative to this 250/sup 0/C isothermal surface define a zone of low reflectance roughly corresponding to the crest of the isothermal surface. Comparison of these two surfaces suggest that the shallow heating in the central portion of Cerro Prieto is young relative to the heating (to 250/sup 0/C) on the system margins. Laboratory and theoretical models of hydrothermal convection cells suggest that the form of the observed 250/sup 0/C isothermal surface and the reflectance surface derived relative to it results from the convective rise of thermal fluids under the influence of a regional hydrodynamic gradient that induces a shift of the hydrothermal heating effects to the southwest.

  13. Criteria for determining casing depth in Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Olivas M., H.M.; Vaca S., J.M.E.

    1982-08-10

    On the basis of geological data obtained during drilling and its relation to electric logs, together with the problems that arose when drilling through formations until the production zone was reached, it is possible to establish the most suitable manner to line a well and thus formulate an optimum casings program. The main criteria to be taken into consideration in preparing such a program and its application in the drilling of wells programmed in Cerro Prieto to optimize and economize such drilling and achieve suitable techniques for well completion are presented. The criteria are based on the characteristics of the Cerro Prieto field and on casing design factors, as well as a experience gained during drilling in such a field.

  14. Dating thermal events at Cerro Prieto using fission track annealing

    Energy Technology Data Exchange (ETDEWEB)

    Sanford, S.J.; Elders, W..

    1981-01-01

    Data from laboratory experiments and geologic fading studies were compiled from published sources to produce lines of iso-annealing for apatite in time-temperature space. Fission track ages were calculated for samples from two wells at Cerro Prieto, one with an apparently simple and one with an apparently complex thermal history. Temperatures were estimated by empirical vitrinite reflectance geothermometry, fluid inclusion homogenization and oxygen isotope equilibrium. These estimates were compared with logs of measured borehole temperatures.

  15. Relationship between water chemistry and sediment mineralogy in the Cerro Prieto geothermal field: a preliminary report

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N. (Univ. de Perpignan, France); Thompson, J.M.; Ball, J.W.

    1981-01-01

    The chemical compositions of waters collected from the Cerro Prieto geothermal production wells and hydrothermal emanations are different. Compared to the Cerro Prieto well waters, the surficial waters generally contain significantly less potassium, slightly less calcium and chloride, and significantly more magnesium and sulfate. In comparison to the unaltered sediments, the changes in the mineralogy of the altered sediments appear to be controlled by the type of emanation (well, spring, mud pot, geyser, fumarole, or cold pool). However, an increase in quartz and potassium feldspar percentages seems to be characteristic of the majority of the sediments in contact with geothermal fluids. Preliminary attempts to model the chemical processes occurring in the Cerro Prieto geothermal field using chemical equilibrium calculations are reported. For this purpose the chemical compositions of thermal waters (well and surficial emanation) were used as input data to make calculations with SOLMNEQ and WATEQ2 computer programs. Then the theoretical mineral composition of altered sediments was predicted and compared to the mineralogy actually observed in the solid samples.

  16. Microfossils from Cerro Prieto geothermal wells, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cotton, M.L.; Vonder Haar, S.

    1980-01-01

    To aid in a paleoenvironmental and age reconstruction of the Cerro Prieto reservoir system, 59 samples of well cuttings were analyzed for microfossils. The cuttings were obtained at depths from 351 to 3495 m in 14 geothermal wells in the Cerro Prieto field, Baja California, Mexico. We found foraminifera in 6 samples, ostracodes in 19 samples, and nannoplankton as coccoliths in 24 samples. Other groups, such as molluscs, insects, fish skeletal parts, and plant material were occasionally present. Detailed interpretations are not possible at this time because of poor preservation of samples. This is primarily due to causes: dissolution by geothermal fluids that reach 350{sup 0}C, and the extensive mixing of filled Cretaceous forms (reworked from the Colorado Plateau region) with Tertiary species during drilling. Further studies of ostracodes and foraminifera from colder portions of the wells are needed. The abundant and well-preserved ostracodes indicate marine to brackish water environments that correspond, in part, to lagoonal or estuarine facies. The presence of the mid-Tertiary (15-My-old) marine foraminifera, Cassigerinela chipolensis, in wells M-11 and M-38, 350 to 500 m deep, is perplexing. These are not laboratory contaminates and, as yet, have not been found in the drilling mud. If further studies confirm their presence at Cerro Prieto, established ideas about the opening of the Gulf of California and about Pacific Coast mid-Tertiary history will need to be rewritten.

  17. Microfossils from Cerro Prieto geothermal wells, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cotton, M.L.; Haar, S.V.

    1982-08-10

    To aid in a paleonenvironmental and age reconstruction of the Cerro Prieto reservoir system, 59 samples of well cuttings were analyzed for microfossils. The cuttings were obtained at depths from 351 to 3495m in 14 geothermal wells in the Cerro Prieto field, Baja California, Mexico. Foraminifera was found in 6 samples, ostracodes in 19 samples and mannoplankton as coccoliths in 24 samples. Other groups, such as molluscus, insects, fish skeletal parts, and plant material were occasionally present. Detailed interpretations at this time cannot be made because of poor preservation of samples. This is primarily due to causes: dissolution by geothermal fluids that reach 350/sup 0/C, and the extensive mixing of filled Cretaceous forms (reworked from the Colorado Plateau region) with Tertiary species during drilling. Further studies of ostracodes and foraminifera from colder portions of the wells are needed. The abundant and well-preserved ostracodes indicate marine to backish water inviroments that correspond in part, to lagoonal or estuarine facies. The presence of the mid-Tertiary (15-m.y.-old) marine foraminifera, Cassigerinela chipolensis, in wells M-11 and M-38, 350 to 500m deep, is perplexing. These are not laboratory contaminates and, as yet have not been found in the drilling mud. If further studies confirm their presence at Cerro Prieto, established ideas about the opening of the Gulf of California and about Pacific Coast mid-Tertiary history will need to be rewritten.

  18. Seismotectonics of the Cerro Prieto Geothermal Field, Baja California, Mexico.

    Science.gov (United States)

    Rebollar, C. J.; Reyes, L. M.; Quintanar, L.; Arellano, J. F.

    2002-12-01

    We studied the background seismic activity in the Cerro Prieto geothermal field (CPGF) using a network of 21 digital stations. Earthquakes are located below the exploitation area of the CPGF, between 3 and 12 km depth, within the basement. Earthquakes follow roughly a N30°E trend perpendicular to the Cerro Prieto fault. This activity is located on a horst-like structure below the geothermal field and coincides with the zone of maximum subsidence in the CPGF. Two earthquake swarms occurred along the SE-NW strike of the Cerro Prieto fault and in the neighborhood of the Cerro Prieto volcano. Magnitudes range from -0.3 to 2.5. A Vp/Vs=1.91 ratio of the activity below the volcano suggests a water-saturated medium and/or a partial-melt medium. We calculated 76 focal mechanisms of individual events. On June 1 and September 10, 1999, two earthquakes of Mw 5.2 and 5.3 occurred in the basement at depths of 7.4 and 3.8 km below the CPGF. Maximum peak accelerations above the hypocenter ranged from 128.0 to 432.0 cm/s2. Waveform modeling results in a fault geometries given by strike=236°, dip=60°, rake=-58° (normal) and strike=10°, dip=90°, rake=159° (right lateral strike-slip) for the June and September events. Observed triangular source time function of 0.7 seconds and a double source with a total duration of 1.9 seconds for the June and September events were used to calculate the synthetics seismograms. Static stress drops and seismic moments for the June and September events are: Δ\\sigma=82.5 MPa (825 bars), Mo= 7.65x1016 Nm (7.65x1023 dyne-cm) and Δ\\sigma=31.3 MPa (313 bars) and Mo=1.27x1017 Nm (1.27x1024 dyne-cm). These stress drops are typical of continental events rather than stress drops of events originated in spreading centers. We concluded from the focal mechanisms of the background seismicity and June and September 1999 events, that a complex stress environment exits in the CPGF due to the continual thinning of the crust in the Cerro Prieto basin.

  19. Oxygen isotope exchange in rocks and minerals from the Cerro Prieto geothermal system: Indicators of temperature distribution and fluid flow

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.E.; Elders, W.A.

    1981-01-01

    Oxygen isotopic compositions have been measured in drill cuttings and core samples from more than 40 wells ranging in depth to more than 3.5 km in the Cerro Prieto geothermal field. Profiles of isotopic ratios versus sampling depths provide information on the three-dimensional distribution of temperature and fluid flow. These parameters also indicate variations in the history of hydrothermal processes in different areas of the geothermal field.

  20. Hydrocarbons emissions from Cerro Prieto Geothermal Power Plant, Mexico

    Science.gov (United States)

    Navarro, Karina; Navarro-González, Rafael; de la Rosa, José; Peralta, Oscar; Castro, Telma; Imaz, Mireya

    2014-05-01

    One of the most important environmental issues related to the use of geothermal fluids to generate electricity is the emission of non-condensable gases to the atmosphere. Mexico has one of the largest geothermal plants in the world. The facility is located at Cerro Prieto, Baja California, roughly 30 km south of Mexicali and the international boundary between Mexico and United States. The Cerro Prieto power plant has 13 units grouped on four individual powerhouses. Gas samples from 9 units of the four powerhouses were collected during 4 campaigns conducted in May-July, 2010, February, 2012, December, 2012, and May, 2013. Gas samples from the stacks were collected in 1000 ml Pyrex round flasks with Teflon stopcocks, and analyzed by gas chromatography-mass spectrometry. Methane was the most abundant aliphatic hydrocarbon, with a concentration that ranged from less than 1% up to 3.5% of the total gas mixture. Normal alkanes represented the second most abundant species, and displayed a decreasing abundance with increasing carbon number in the homologous series. Isoalkanes were also present as isobutane and isopentane. Cycloalkanes occurring as cyclopentane and cyclohexane, were detected only at trace level. Unsaturated hydrocarbons (alkenes and alkynes) were not detected. Benzene was detected at levels ranging from less than 1% up to 3.4% of the total gas mixture. Other aromatic hydrocarbons detected were toluene, and xylenes, and were present at lower concentrations (

  1. Properties of Cerro Prieto rock at simulated in situ conditions

    Energy Technology Data Exchange (ETDEWEB)

    Schatz, J.F.

    1981-01-01

    Rocks from the Cerro Prieto Geothermal Field were tested under simulated in situ conditions in the laboratory to determine their properties and response to pore pressure reduction as would be caused by reservoir production. The primary purpose of the project was to provide information on compaction and creep as they may contribute to surface subsidence. Results show typical compressibilities for reservoir rocks of about 1 x 10/sup -6/ psi/sup -1/ and creep compaction rates of about 1 x 10/sup -9/ sec/sup -1/ when triggered by 1000 psi pore pressure reduction. This creep rate would cause significant porosity reduction if it continued for several years. Therefore it becomes important to learn how to correctly extrapolate such data to long times.

  2. Progress on the biphase turbine at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Cerini, D.; Hays, L.; Studhalter, W. [Douglas Energy Company, Placentia, CA (United States)

    1997-12-31

    The status of a Biphase turbine power plant being installed at the Cerro Prieto geothermal field is presented. The major modules for the power plant are completed except for a back pressure steam turbine. The power plant will be started in April 1997 with the Biphase turbine alone followed by the addition of the steam turbine module two months later. The current power plant performance level is 2780 kWe due to a decline in the well. An increase in power output to 4060 kWe by adding the flow from another well is planned. The addition of five Biphase power plants with a total power output of 21.2 megawatts is described.

  3. Basic aspects of the Cerro Prieto reservoir water recharge; Aspectos basicos de la recarga de agua al reservorio de Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    The Cerro Prieto geothermal field, located 30 km South of Mexicali City, Baja California, has at present an installed capacity of 620 MW in geothermal power plants, that operating with endogenous steam, make use of the underground energy by means of deep wells, from which about 80 million cubic meters per year of high enthalpy water and steam mixture are extracted. During the exploitation physical an chemical changes in the hydrothermal fluids discharged by the wells have been detected, which shows, among other things, an elevated water recharge, located towards the West area of the field and a low recharge in the part of the east zone area. For this reason the hot brine waste re-injection is recommended, (previously treated to eliminate the silica excess) to thermally an hydraulically recharge the reservoir in that part of the field. [Espanol] El campo geotermico de Cerro Prieto, situado a 30 km al sur de la ciudad de Mexicali, Baja California, cuenta actualmente, despues de 18 anos en explotacion, con 620 MW de capacidad instalada en plantas geotermoelectricas que, operando con vapor endogeno, aprovechan la energia del subsuelo mediante pozos profundos de los que se extraen alrededor de 80 millones de metros cubicos por ano de una mezcla de agua vapor de elevada entalpia. Durante la explotacion se han percibido cambios fisicos y quimicos en los fluidos hidrotermales descargados por los pozos, lo que indica, entre otras cosas, una recarga elevada de agua localizada hacia el poniente del campo y una recarga baja en una zona de la parte oriental. Por ello se recomienda la reinyeccion de salmuera geotermica caliente de desecho (previamente tratada para eliminar el exceso de silice) para recargar termica e hidraulicamente el reservorio en esa parte del campo.

  4. Results from two years of resistivity monitoring at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Wilt, M.J.; Goldstein, N.E.

    1981-01-01

    Dipole-dipole resistivity measurements for the combined purposes of reservoir delineation and resistivity monitoring were first made at Cerro Prieto in 1978 and have continued on an annual basis since then. Two 20 km long dipole-dipole lines with permanently emplaced electrodes at one kilometer spacings were established over the field area; one of these lines is remeasured annually. Resistivity measurements are taken using a 25 kW generator capable of up to 80A output and a microprocessor controlled signal averaging receiver; this high power-low noise system is capable of highly accurate measurements even at large transmitter-receiver separations. Standard error calculations for collected data indicate errors less than 5% for all points, but 95% confidence intervals show error limits about 2 to 4 times higher. Analysis of collected data indicate little change in the apparent resistivity of the upper 300 m over the field production zone and that in this section measurements are relatively insensitive to the annual rainfall cycle. Apparent resistivity increases were observed over the older producing zone at Cerro Prieto at depths of 1 km and greater. Large zones of decreasing apparent resistivity were observed flanking the zone of increases on both sides. The increase in apparent resistivity in the production region may be due to an increasing fraction of steam in the reservoir resulting from a production related decline in reservoir pressure. Alternatively the increases may be the result of fresh water influx from the Colorado River. The zone of declining resistivity flanking the area of increase may be due to the movement of saline waters into the reservoir region as a result of the pressure decline. Quantitative modeling of observed changes is impractical owing to the high uncertainty in estimating apparent resistivity changes and the nonuniqueness of models.

  5. Update of the conceptual geological model for the geothermal reservoir in Cerro Prieto, BC; Actualizacion del modelo geologico conceptual del yacimiento geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Lira Herrera, Hector [Comision Federal de Electricidad, Mexicali, B.C., (Mexico)

    2005-06-01

    An updated, conceptual geologic model is presented for the geothermal reservoir in Cerro Prieto geothermal field. The tectonic extension that formed the Basin and Range Province of the Western United States and Northwestern Mexico during Upper Tertiary in the Cerro Prieto area resulted in the formation of a half graben tectonic basin between the Cerro Prieto and Imperial faults. Called the Cerro Prieto basin, it includes listric faults, predominately northwest-southwest trending, stepped generally to the northeast. The zone of cortical weakness, formed during the Tertiary, allowed an intrusion of basic rock associated with the magnetic anomaly know as Nuevo Leon. The intrusive rock has been fed by new magmatic intrusions originated by the present tectonic extension of the Gulf of California. The oldest rocks identified in the area are gneiss and biotite-schists of Permian-Jurassic age and tonalities of Jurassic-Cretaceous age in contact with Cretaceous granites, all representing the regional basement. The lithologic column in the subsurface of the Cerro Prieto basin in formed by a basement of Cretaceous granites; an argillaceous package resting on the basement composed of gray shales with interleaves of sandstone, Tertiary brown-shales and mudstone, with an average thickness of 2700 m; clastic sediments of the Quaternary age deposited mainly by the Colorado River and alluvial fans of the Cucapa Range, comprised of gravel, sands and clays with an average thickness of 2500 m, covering the shales. The fluids feeding the geothermal reservoir heat as they pass though the zone where the basic intrusive is located (the heat source) and migrate through the listric faults toward the permeable layers of sandstone located within the gray shales. [Spanish] Se presenta el modelo geologico conceptual actualizado del yacimiento geotermico de Cerro Prieto. La tectonica extensional que origino la Provincia de Cuencas y Cordilleras (Basin and Range) del oeste de Estados Unidos y

  6. Radon and ammonia transects across the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Semprini, L.; Kruger, P.

    1981-01-01

    Radon and ammonia transects, conducted at the Cerro Prieto geothermal field, involve measurement of concentration gradients at wells along lines of structural significance in the reservoir. Analysis of four transects showed radon concentrations ranging from 0.20 to 3.60 nCi/kg and ammonia concentrations from 17.6 to 59.3 mg/l. The data showed the lower concentrations in wells of lowest enthalpy fluid and the higher concentrations in wells of highest enthalpy fluid. Linear correlation analysis of the radon-enthalpy data indicated a strong relationship, with a marked influence by the two-phase conditions of the produced fluid. It appears that after phase separation in the reservoir, radon achieves radioactive equilibrium between fluid and rock, suggesting that the phase separation occurs well within the reservoir. A two-phase mixing model based on radon-enthalpy relations allows estimation of the fluid phase temperatures in the reservoir. Correlations of ammonia concentration with fluid enthalpy suggests an equilibrium partitioning model in which enrichment of ammonia correlates with higher enthalpy vapor.

  7. Performance of casings in Cerro Prieto production wells

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A, B.; Vital B, F.; Bermejo M, F.; Sanchez G, G.

    1981-01-01

    A careful evaluation of different production casings used at Cerro Prieto from 1964 to date has shown that the following casings have yielded particularly impressive results: 7 5/8-in. diameter, J-55, 26 lb/ft; 7 5/8-in. diameter, K-55, 45.3 lb/ft; and 5-in. diameter, K-55, 23.2 lb/ft. These casings differ from others of the same diameter but lighter weight which were also used at the field. The results are favorable in spite of severe construction problems, especially the loss of circulation during cementing operations, which we encountered in some of the wells where these casings were used. The use of gravity-fed fine sand as packing material and the arrangement of the production and intermediate casings were important in avoiding damage due to tension-compression stresses and, above all, damage due to internal or external corrosion over time. This situation is clearly evidenced if we compare the damage to the above casings with that experienced by grade N-80 production casings, especially in a corrosive environment.

  8. Measured ground-surface movements, Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Massey, B.L.

    1981-01-01

    The Cerro Prieto geothermal area in the Mexicali Valley, 30 kilometers southeast of Mexicali, Baja California, incurred slight deformation because of the extraction of hot water and steam, and probably, active tectonism. During 1977 to 1978, the US Geological Survey established and measured two networks of horizontal control in an effort to define both types of movement. These networks consisted of: (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from stations on an existing US Geological Survey crustal-strain network north of the international border; and (2) a local net tied to stations in the regional net and encompassing the present and planned geothermal production area. Electronic distance measuring instruments were used to measure the distances between stations in both networks in 1978, 1979 and 1981. Lines in the regional net averaged 25 km. in length and the standard deviation of an individual measurement is estimated to be approx. 0.3 part per million of line length. The local network was measured using different instrumentation and techniques. The average line length was about 5 km. and the standard deviation of an individual measurement approached 3 parts per million per line length. Ground-surface movements in the regional net, as measured by both the 1979 and 1981 resurveys, were small and did not exceed the noise level. The 1979 resurvey of the local net showed an apparent movement of 2 to 3 centimeters inward toward the center of the production area. This apparent movement was restricted to the general limits of the production area. The 1981 resurvey of the local net did not show increased movement attributable to fluid extraction.

  9. Fault Length Vs Fault Displacement Evaluation In The Case Of Cerro Prieto Pull-Apart Basin (Baja California, Mexico) Subsidence

    Science.gov (United States)

    Glowacka, E.; Sarychikhina, O.; Nava Pichardo, F. A.; Farfan, F.; Garcia Arthur, M. A.; Orozco, L.; Brassea, J.

    2013-05-01

    The Cerro Prieto pull-apart basin is located in the southern part of San Andreas Fault system, and is characterized by high seismicity, recent volcanism, tectonic deformation and hydrothermal activity (Lomnitz et al, 1970; Elders et al., 1984; Suárez-Vidal et al., 2008). Since the Cerro Prieto geothermal field production started, in 1973, significant subsidence increase was observed (Glowacka and Nava, 1996, Glowacka et al., 1999), and a relation between fluid extraction rate and subsidence rate has been suggested (op. cit.). Analysis of existing deformation data (Glowacka et al., 1999, 2005, Sarychikhina 2011) points to the fact that, although the extraction changes influence the subsidence rate, the tectonic faults control the spatial extent of the observed subsidence. Tectonic faults act as water barriers in the direction perpendicular to the fault, and/or separate regions with different compaction, and as effect the significant part of the subsidence is released as vertical displacement on the ground surface along fault rupture. These faults ruptures cause damages to roads and irrigation canals and water leakage. Since 1996, a network of geotechnical instruments has operated in the Mexicali Valley, for continuous recording of deformation phenomena. To date, the network (REDECVAM: Mexicali Valley Crustal Strain Measurement Array) includes two crackmeters and eight tiltmeters installed on, or very close to, the main faults; all instruments have sampling intervals in the 1 to 20 minutes range. Additionally, there are benchmarks for measuring vertical fault displacements for which readings are recorded every 3 months. Since the crackmeter measures vertical displacement on the fault at one place only, the question appears: can we use the crackmeter data to evaluate how long is the lenth of the fractured fault, and how quickly it grows, so we can know where we can expect fractures in the canals or roads? We used the Wells and Coppersmith (1994) relations between

  10. Case history report on East Mesa and Cerro Prieto geothermal fields

    Energy Technology Data Exchange (ETDEWEB)

    Davis, DG.; Sanyal, S.K.

    1979-06-01

    Well log analysis as applied to the geothermal industry is one of the areas of technology in great need of further development. One means of improving log analysis technology is to study case histories of the past uses of log analysis as applied to specific fields. The project described in this report involved case history studies on two well-known geothermal areas in North America: the East Mesa field in California and the Cerro Prieto field in Mexico. Since there was considerably more pertinent material available on East Mesa, a major part of the effort on this project was devoted to studying the East Mesa field. One particular problem that first came to attention when studying the Cerro Prieto data was the difficulty in determining actual formation temperature at the time of logging. Since the temperature can have a significant effect on well log readings, an accurate temperature determination was considered to be important.

  11. H2S and CO2 emissions from Cerro Prieto geothermal power plant, Mexico

    Science.gov (United States)

    Peralta, Oscar; Franco, Luis; Castro, Telma; Taran, Yuri; Bernard, Ruben; Inguaggiato, Salvatore; Navarro, Rafael; Saavedra, Isabel

    2014-05-01

    Cerro Prieto geothermal power plant has an operation capacity of 570 MW distributed in four powerhouses being the largest geothermal plant in Mexico. The geothermal field has 149 production wells. It is located in Cerro Prieto, Baja California, 30 km to the south of the Mexico-US border. Two sampling campaigns were performed in December 2012 and May 2013 where geothermal fluids from 46 production wells and 10 venting stacks were obtained and analyzed by gas chromatography coupled to mass spectrometry. Average CO2 and H2S composition of samples from venting stacks were 49.4% and 4.79%, respectively. Based on the chemical composition of samples, the geothermal power plant emits every day from venting stacks 869 tons of CO2, plus 68 tons of H2S, among other non-condensable gases.

  12. A review of the hydrogeologic-geochemical model for Cerro Prieto

    Science.gov (United States)

    Lippmann, M.J.; Truesdell, A.H.; Halfman-Dooley, S. E.; Mañónm, A.

    1991-01-01

    With continued exploitation of the Cerro Prieto, Mexico, geothermal field, there is increasing evidence that the hydrogeologic model developed by Halfman and co-workers presents the basic features controlling the movement of geothermal fluids in the system. In mid-1987 the total installed capacity at Cerro Prieto reached 620 MWc, requiring a large rate of fluid production (more than 10,500 tonnes/hr of a brine-steam mixture; August 1988). This significant mass extraction has led to changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. Pressure drawdown has caused an increase in cold water recharge in the southern and western edges of the field, and local and general reservoir boiling in parts of the geothermal system. After reviewing the hydrogeologic and geochemical models of Cerro Prieto, the exploitation-induced cold water recharge and reservoir boiling (and plugging) observed in different areas of the field, are discussed and interpreted on the basis of these models and schematic flow models that describe the hydrogeology. ?? 1991.

  13. Areas to explore surrounding the Cerro Prieto geothermal field, BC; Areas para exploracion en los alrededores del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

    2009-07-15

    Exploration plays an important role in tapping underground natural resources-whether water, oil, natural gas or minerals. Exploratory data allow us to learn reservoir conditions, increasing probable reserves and reservoir life span. Around the Cerro Prieto geothermal field, BC, and in the Mexicali Valley in general, exploration had almost stopped but recently was resumed by the Studies Division of Comision Federal de ELectricidad (CFE)'s Gerencia de Proyectos Geotermoelectricos. The division sent technical personnel to structurally map the northern and eastern portions of Laguna Salada. The paper offers a general outline of the main zones undergoing exploratory studies-studies perhaps culminating in siting exploratory wells to locate more geothermal resources (and ultimately producing them using binary power plants). CFE also wants to site injection wells west of the current production zone, and this is covered, as well. All activities are meant to increase the productive lifespan of the geothermal reservoir. [Spanish] Cuando se trata de la explotacion de recursos naturales del subsuelo, sea agua, gas, petroleo o minerales, la exploracion juega un papel muy importante, ya que permite conocer las condiciones del yacimiento que pudieran llevar a incrementar las reservas de los recursos explotados y extender su vida util. En las zonas aledanas al campo geotermico de Cerro Prieto, BC, y en general en el Valle de Mexicali, la exploracion estaba practicamente detenida habiendose reactivado a raiz de que la Subgerencia de Estudios de la Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad (CFE) envio personal para realizar mapeos estructurales en las porciones norte y oriente de la Laguna Salada. Este trabajo presenta un panorama general de las areas prioritarias para realizar estudios exploratorios y poder programar, con mas bases, pozos exploratorios enfocados a localizar mas recursos geotermicos, inclusive para generar energia por medio

  14. Hydraulic model and steam flow numerical simulation of the Cerro Prieto geothermal field, Mexico, pipeline network

    International Nuclear Information System (INIS)

    The development of a hydraulic model and numerical simulation results of the Cerro Prieto geothermal field (CPGF) steam pipeline network are presented. Cerro Prieto is the largest water-dominant geothermal field in the world and its transportation network has 162 producing wells, connected through a network of pipelines that feeds 13 power-generating plants with an installed capacity of 720 MWe. The network is about 125 km long and has parallel high- and low-pressure networks. Prior to this study, it was suspected that steam flow stagnated or reversed from its planned direction in some segments of the network. Yet, the network complexity and extension complicated the analysis of steam transport for adequate delivery to the power plants. Thus, a hydraulic model of the steam transportation system was developed and implemented numerically using an existing simulator, which allowed the overall analysis of the network in order to quantify the pressure and energy losses as well as the steam flow direction in every part of the network. Numerical results of the high-pressure network were obtained which show that the mean relative differences between measured and simulated pressures and flowrates are less than 10%, which is considered satisfactory. Analysis of results led to the detection of areas of opportunity and to the recommendation of changes for improving steam transport. A main contribution of the present work is having simulated satisfactorily the longest (to our knowledge), and probably the most complex, steam pipeline network in the world. - Highlights: • Extensive literature review of flow models of geothermal steam gathering networks. • Hydraulic model of the Cerro Prieto geothermal field steam network. • Selection and validation of the employed pressure-drop model. • Numerical flow simulation of the world's largest geothermal steam gathering network. • Detailed network pressure drop analysis and mapping of steam flow distribution

  15. Preliminary plasma spectrometric analyses for selected elements in some geothermal waters from Cerro Prieto, Mexico

    Science.gov (United States)

    Ball, J.W.; Jenne, E.A.

    1983-01-01

    As part of a cooperative study with Dr. Alfred Truesdell, water samples collected from geothermal power production wells at Cerro Prieto, Mexico, were analyzed for selected elements by d.c. argon plasma emission spectroscopy. Spectral interferences due to the presence of high concentrations of Ca, Si, Na and K in these water affected the apparent concentration values obtained. These effects were evaluated and correction techniques were developed and applied to the analytical values. Precipitates present in the samples at the time of analysis adversely affected the accuracy, precision and interpretability of the data. (USGS)

  16. Two-dimensional modeling of apparent resistivity pseudosections in the Cerro Prieto region

    Energy Technology Data Exchange (ETDEWEB)

    Vega, R.; Martinez, M.

    1981-01-01

    Using a finite-difference program (Dey, 1976) for two-dimensional modeling of apparent resistivity pseudosections obtained by different measuring arrays, four apparent resistivity pseudosections obtained at Cerro Prieto with a Schlumberger array by CFE personnel were modeled (Razo, 1978). Using geologic (Puente and de la Pena, 1978) and lithologic (Diaz, et al., 1981) data from the geothermal region, models were obtained which show clearly that, for the actual resistivity present in the zone, the information contained in the measured pseudosections is primarily due to the near-surface structure and does not show either the presence of the geothermal reservoir or the granitic basement which underlies it.

  17. Dating thermal events at Cerro Prieto using fission-track annealing

    Energy Technology Data Exchange (ETDEWEB)

    Sanford, S.J.; Elders, W.A.

    1981-01-01

    The duration of heating in the Cerro Prieto reservoir was estimated by relating the fading of spontaneous fission tracks in detrital apatite to observed temperatures. The rate of fading is a function of both time and temperature. The apparent fission track age of the detrital apatites then, is a function of both their source age and their time-temperature history. Data from laboratory experiments and geologic fading studies were compiled from published sources to produce lines of iso-annealing for apatite in time-temperature space. Fission track ages were calculated for samples from two wells at Cerro Prieto, one with an apparently simple and one with an apparently complex thermal history. Temperatures were estimated by empirical vitrinite reflectance geothermometry, fluid inclusion homogenization and oxygen isotope equilibrium. These estimates were compared with logs of measured borehole temperatures. The temperature in well T-366, where complete annealing first occurs, was estimated to be between 160 and 180{sup 0}C. Complete annealing at these temperatures requires 10{sup 4} and 10{sup 3} years, respectively. Well M-94 has an apparently complex thermal history. Geothermometers in this well indicate temperatures some 50 to 100{sup 0}C higher than those measured directly in the borehole. Fission tracks are partially preserved in M-94 where paleotemperatures were as high as 200{sup 0}C and are erased where geothermometers indicate temperatures of 250{sup 0}C. This implies a thermal event less than 10{sup 1} years and greater than 10{sup 0} years in duration.

  18. Extension of the Cerro Prieto field and zones in the Mexicali Valley with geothermal possibilities in the future

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca L, H.L.; de la Pena L, A.; Puente C, I.; Diaz C, E.

    1981-01-01

    This study concerns the possible extension of the Cerro Prieto field and identification of other zones in the Mexicali Valley with geothermal development potential by assessing the structural geologic conditions in relation to the regional tectonic framework and the integration of geologic and geophysical surveys carried out at Cerro Prieto. This study is based on data obtained from the wells drilled to date and the available geological and geophysical information. With this information, a geologic model of the field is developed as a general description of the geometry of what might be the geothermal reservoir of the Cerro Prieto field. In areas with geothermal potential within the Mexicali Valley, the location of irrigation wells with anomalous temperatures was taken as a point of departure for subsequent studies. Based on this initial information, gravity and magnetic surveys were made, followed by seismic reflection and refraction surveys and the drilling of 1200-m-deep multiple-use wells. Based on the results of the final integration of these studies with the geology of the region, it is suggested that the following areas should be explored further: east of Cerro Prieto, Tulecheck, Riito, Aeropuerto-Algodones, and San Luis Rio Colorado, Sonora.

  19. Minimal thermodynamic conditions in the reservoir to produce steam at the Cerro Prieto geothermal field, BC; Condiciones termodinamicas minimas del yacimiento para producir vapor en el campo geotermico de Cerro Prieto, B.C.

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez; Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2009-01-15

    Minimal thermodynamic conditions in the Cerro Prieto geothermal reservoir for steam production are defined, taking into account the minimal acceptable steam production at the surface, considering a rank of mixed-enthalpies for different well-depths, and allowing proper assessments for the impacts of the changes in fluid reservoir pressure and enthalpy. Factors able to influence steam production are discussed. They have to be considered when deciding whether or not to drill or repair a well in a particular area of the reservoir. These evaluations become much more relevant by considering the huge thermodynamic changes that have occurred at the Cerro Prieto geothermal reservoir from its development, starting in 1973, which has lead to abandoning some steam producing areas in the field. [Spanish] Las condiciones termodinamicas minimas del yacimiento geotermico de Cerro Prieto, BC, para producir vapor se determinan tomando en cuenta la minima produccion de vapor aceptable en superficie, considerando un rango de entalpias de la mezcla y para diferentes profundidades de pozos, lo que permite valorar adecuadamente el impacto de la evolucion de la presion y entalpia del fluido en el yacimiento. Se discuten los factores que pueden afectar la produccion de vapor, los cuales se deben tomar en cuenta para determinar la conveniencia o no de perforar o reparar un pozo en determinada zona del yacimiento. Estas evaluaciones adquieren gran relevancia al considerar los enormes cambios termodinamicos que ha presentado el yacimiento geotermico de Cerro Prieto, como resultado de su explotacion iniciada en 1973, lo que ha llevado a abandonar algunas zonas del campo para la produccion de vapor. Palabras Clave: Cerro Prieto, entalpia, evaluacion de yacimientos, politicas de explotacion, presion, produccion de vapor.

  20. Temperature distribution in the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Castillo B, F.; Bermejo M, F.J.; Domiguez A, B.; Esquer P, C.A.; Navarro O, F.J.

    1981-01-01

    A series of temperature and pressure logs and flow rate measurements was compiled for each of the geothermal wells drilled to different reservoir depths between October 1979 and December 1980. Based on the valuable information obtained, a series of graphs showing the thermal characteristics of the reservoir were prepared. These graphs clearly show the temperature distribution resulting from the movement of fluids from the deep regions toward the higher zones of the reservoir, thus establishing more reliable parameters for locating new wells with better production zones. Updated information based on data from new deep wells drilled in the geothermal field is presented here. This new information does not differ much from earlier estimates and theories. However, the influence of faulting and fracturing on the hydrothermal recharge of the geothermal reservoir is seen more clearly.

  1. Presence of cross flow in the Cerro Prieto geothermal field, BC; Presencia de flujo cruzado en el campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2011-01-15

    During the development of Cerro Prieto geothermal field, BC, exploitation has increased gradually, causing a continuous drop in pressure to almost 100 bars in the central and eastern parts of the field. This has occurred despite the high natural recharge induced by the reservoir exploitation and helped by the high permeability of the reservoir and the wide availability of natural recharge of low-temperature water in the vicinity. The strata above the production zones have significantly lower temperatures than these zones, but due to the particular characteristics of the reservoir, do not have pressure drops. As the pressure of producing strata declines, the hydraulic pressure differential between them and the overlying strata increases. Thus in recent years the phenomenon of cross flow occurs with greater frequency and severity. In this paper, this phenomenon is analyzed, detailing the specific mechanisms favoring it and identifying the stage (drilling or workover) in which it commonly occurs. Rigorous supervision during these stages is crucial to identifying cross flow and to taking necessary measures to save the well. Cross flow cases are presented at different stages in the history of a well: during drilling, repair, before and during the stimulation, and during production. [Spanish] Durante el desarrollo del campo geotermico de Cerro Prieto, BC, la explotacion se ha incrementado en forma gradual provocando una continua caida de presion, que en las porciones central y oriente ha sido de casi 100 bars. Esto ha ocurrido a pesar de la enorme recarga natural inducida por la explotacion, favorecida por la alta permeabilidad del yacimiento y la gran disponibilidad de recarga natural de agua de baja temperatura en los alrededores del mismo. Los estratos ubicados encima de las zonas productoras presentan temperaturas significativamente menores que estos, pero debido a las caracteristicas particulares del yacimiento, no han presentado abatimiento en su presion. En la

  2. Mineralogy of the silica-epidote mineralized zone (SEMZ) in the Cerro Prieto geothermal reservoir, B.C., Mexico; Mineralogia de la zona mineralizada de silice-epidota (ZMSE) del yacimiento geotermico de Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Izquierdo, Georgina; Aragon, Alfonso; Portugal, Enrique; Arellano; Victor M [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico)]. E-mail: gim@iie.org.mx; Leon, Jesus de; Alvarez, Julio [Comision Federal de Electricidad, B.C. (Mexico)

    2006-07-15

    The distribution of hydrothermal minerals, mineral assemblages and fluid inclusion data were taken from drill cuttings from the production zone of wells all over the Cerro Prieto geothermal field. The production zone has been termed the silica-epidote mineralized zone (SEMZ), and is located in the deep part of the gray shale where thick layers of sandstone are found. Common mineral assemblages show three temperature ranges in the SEMZ: <200 degrees Celsius, 200-250 degrees Celsius and 250-300 degrees Celsius. The first range is characterized by clays, calcite and quartz; the second by quartz, epidote, chlorite and mica, and the third by epidote, amphibole, illite and chlorite. The study of fluid inclusions in authigenic grain quartz has shown two-phase fluid inclusions (liquid + vapor) of different salinities. A wide range exists of homogenization temperatures (Th) and for some wells there is a good agreement between Th and direct temperature measurements. [Spanish] Se determino la distribucion de minerales hidrotermales y las asociaciones parageneticas y se realizo el estudio microtermometrico de inclusiones fluidas a partir de recortes de perforacion de pozos de las distintas areas del campo geotermico de Cerro Prieto. Las muestras de recortes y nucleos de perforacion estudiados provienen de la zona de produccion a la que se le ha denominado Zona Mineralizada de Silice-Epidota (ZMSE), que se encuentra en la parte profunda de la lutita gris con importantes horizontes de areniscas. En esta zona las asociaciones parageneticas mas comunes han mostrado tres intervalos de temperatura para la ZMSE: <200 degrees Celsius, 200-250 degrees Celsius, 250-300 degrees Celsius. El primer intervalo esta caracterizado principalmente por arcillas, calcita y cuarzo; el segundo por cuarzo, epidota, clorita y micas, y el tercero por epidota, anfiboles, illita y clorita. El estudio de inclusiones fluidas en fragmentos de cuarzo autigenico mostro la presencia de inclusiones de dos fases

  3. Active metasomatism in the Cerro Prieto geothermal system, Baja California, Mexico: A telescoped low-pressure, low-temperature metamorphic facies series

    Science.gov (United States)

    Schiffman, P.; Elders, W. A.; Williams, A. E.; McDowell, S. D.; Bird, D. K.

    1984-01-01

    In the Cerro Prieto geothermal field, carbonate-cemented, quartzofeldspathic sediments of the Colorado River delta are being actively metasomatized into calc-silicate metamorphic rocks by reaction with alkali chloride brines between 200 and 370 °C, at low fluid and lithostatic pressures and low oxygen fugacities. Our petrologic investigations of drill cores and cuttings from more than 50 wells in this field identified a prograde series of zones that include as index minerals wairakite, epidote, prehnite, and clinopyroxene. Associated divariant mineral assemblages are indicative of a very low pressure, low-temperature metamorphic facies series spanning the clay-carbonate, zeolite, greenschist, and amphibolite facies. This hydro-thermal facies series, which is now recognized in other active geothermal systems, is characterized by temperature-telescoped dehydration and decarbonation. Its equivalent can now be sought in fossil hydrothermal systems.

  4. Did stresses from the Cerro Prieto Geothermal Field influence the El Mayor-Cucapah rupture sequence?

    Science.gov (United States)

    Trugman, Daniel T.; Borsa, Adrian A.; Sandwell, David T.

    2014-12-01

    The Mw 7.2 El Mayor-Cucapah (EMC) earthquake ruptured a complex fault system in northern Baja California that was previously considered inactive. The Cerro Prieto Geothermal Field (CPGF), site of the world's second largest geothermal power plant, is located approximately 15 km to the northeast of the EMC hypocenter. We investigate whether anthropogenic fluid extraction at the CPGF caused a significant perturbation to the stress field in the EMC rupture zone. We use Advanced Land Observing Satellite interferometric synthetic aperture radar data to develop a laterally heterogeneous model of fluid extraction at the CPGF and estimate that this extraction generates positive Coulomb stressing rates of order 15 kPa/yr near the EMC hypocenter, a value which exceeds the local tectonic stressing rate. Although we cannot definitively conclude that production at the CPGF triggered the EMC earthquake, its influence on the local stress field is substantial and should not be neglected in local seismic hazard assessments.

  5. Comments on some of the drilling and completion problems in Cerro Prieto geothermal wells

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A, B.; Sanchez G, G.

    1981-01-01

    From 1960 to the present, 85 wells with a total drilling length exceeding 160,000 m have been constructed at Cerro Prieto, a modest figure compared to an oil field. This activity took place in five stages, each characterized by changes and modifications required by various drilling and well-completion problems. Initially, the technical procedures followed were similar to those used in the oil industry. However, several problems emerged as a result of the relatively high temperatures found in the geothermal reservoir. The various problems that have been encountered can be considered to be related to drilling fluids, cements and cementing operations, lithology, geothermal fluid characteristics, and casings and their accessories. As the importance of high temperatures and the characteristics of the geothermal reservoir fluids were better understood, the criteria were modified to optimize well-completion operations, and satisfactory results have been achieved to date.

  6. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    Science.gov (United States)

    Mazor, E.; Truesdell, A.H.

    1984-01-01

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He and 40Ar) and atmospheric noble gases (Ne, Ar and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water that penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic He and 40Ar formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 - 30%) and mixing with shallow cold water occurred (0 - 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 - 3% steam separation and complement other tracers, such as C1 or temperature, which are effective only beyond this range. ?? 1984.

  7. Results of the latest transient well pressure tests at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Abril G, A.; Vargas G, C.

    1981-01-01

    The equipment used in the interference and two-rate flow tests carried out at the Cerro Prieto geothermal field during 1980 are described. The results of two interference tests are presented, one between wells M-110 and M-104, and the other between wells M-7 and Q-757. The data was interpreted using type curve matching analysis. Results of two-rate flow tests carried out in wells M-102 and M-7 are also discussed. A technique for making two-rate flow tests is proposed. This approach, which attempts to avoid the uncertainty of present flow-rate measurements, makes use of devices for direct measurements of separated water and steam. Conclusions based on the above interpretations and recommendations for future tests are presented.

  8. Report of the seismic activity at the Cerro Prieto B.C., Mexico, geothermal field during 1996; Reporte de la actividad sismica registrada en el campo geotermico de Cerro Prieto, B.C., Mexico, durante 1996

    Energy Technology Data Exchange (ETDEWEB)

    Escamilla Hernandez, Abelardo [Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad, Morelia (Mexico)

    1997-05-01

    In February 1996 started the operation of the Seismic Network of Cerro Prieto Geothermal Field (RESICP). It is constituted by five digital stations with velocity sensors of three components and a natural period of one second. The network worked continuously until December 2, 1996. During this period, we located 270 events in the field area and its neighborhood, with coda-length magnitude 1Cerro Prieto Dos and Cerro Prieto Tres. The recorded activity is less than in Zone A, focal depths are between five and seven km, and the coda- length magnitude is 1Cerro Prieto volcano and to the NW of it. The activity was of swarm type mainly, and inside this zone was recorded the greater event for the region (M{sub c}=4.21, 30 August at 06:245 Universal Time), coda-length magnitude 1 Cerro Prieto (RESICP); consta de cinco estaciones de tipo digital, sensores de velocidad de tres componentes, y periodo natural de un segundo. Trabajo en forma ininterrumpida hasta el 2 de diciembre de 1996. Durante ese periodo se localizaron

  9. Corrosion in pipelines and well casings at the Cerro Prieto geothermal field, BC; Corrosion en tuberias de linea y de revestimiento de pozos del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Miranda Herrera, Carlos A.; Canchola Felix, Ismael; Raygoza Flores, Joaquin; Mora Perez, Othon [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: carlos.miranda02@cfe.gob.mx

    2009-07-15

    In the area called Poligono Hidalgo, inside the Cerro Prieto IV zone in the Cerro Prieto geothermal field, BC, corrosion has occurred in the last few years on well casings and pipelines used for geothermal fluids. Corrosion test results are presented here for pipes, type API L-80 and ASTM A-53 grade B, which were subjected to condensate from wells 403 and 424. These wells have thrown corroded material from their respective casings. With these data we pinpoint corrosive conditions in this field area and determine which pipes are adequate to case wells in similar chemical, production conditions to minimize adverse effects and extend the life of the well, allowing more efficient exploitation of the deepest production zones in the reservoir. [Spanish] En el campo geotermico de Cerro Prieto, BC, dentro del area del Poligono Hidalgo en el sector conocido como Cerro Prieto IV, algunos pozos han presentado en los ultimos anos desgastes en sus tuberias de revestimiento y en las tuberias de linea para el transporte del fluido geotermico. Se presentan resultados de pruebas de corrosion con tuberias tipo API L-80 y ASTM A-53 grado B al ser sometidas al condensado de los pozos 403 y 424, los cuales han estado arrojando material de sus respectivas tuberias de revestimiento. Con estos datos se pretende conocer las condiciones corrosivas de esa zona del campo y determinar cual seria la tuberia ideal a utilizar en pozos con condiciones quimicas de produccion semejantes a fin de minimizar este efecto adverso y prolongar la vida de los pozos, a la vez que se permita la explotacion eficiente de las zonas productoras mas profundas del yacimiento.

  10. Oxygen isotope exchange in rocks and minerals from the Cerro Prieto geothermal system: indicators of temperature distribution and fluid flow

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.E.; Elders, W.A.

    1981-01-01

    Oxygen isotopic compositions have been measured in drill cuttings and core samples from more than 40 wells ranging in depth to more than 3.5 km in the Cerro Prieto geothermal field. Oxygen isotopic profiles of pore-filling calcites in sandstones appear to be a reliable measure of the recent equilibrium temperature distribution in the field before production began. From these data, a detailed, three-dimensional map has been developed, showing the equilibrium temperatures in the geothermal field. A mass balance calculation has been performed using measured /sup 18/O enrichment of the geothermal brine. This calculation implies an overall water; rock volume ratio of approximately 3:1 during the history of the Cerro Prieto system. Paleotemperatures different from the present thermal regime have been studied by examining coexisting mineral systems which exchanged their oxygen with the geothermal brines at different rates.

  11. Relationshipe Between Self-potential Anomalies and Hydraulic Flow In A Geothermal System: Application To Cerro-prieto, Baja California

    Science.gov (United States)

    Saracco, G.; Revil, A.; Pessel, M.

    The Cerro Prieto geothermal field is located in the alluvial plain of the Mexicali Valley, northern Baja California, Mexico, at about 35 km southeast of the city of Mexicali. The Cerro Prieto geothermal field is one of several high temperature water-dominated geothermal fields within the Salton Trough. We analyze here the self-potential distri- bution at the ground surface in order to determine the pattern of fluid flow in te sub- surface of this geothermal field. Various methods of analysis of self-potential anoma- lies are employed to reach this purpose. We use density probability tomography of monopolar and dipolar electrical sources and an Euler-type analysis. The hydraulic flow pattern found in this geothermal field is in agreement with that detemined from the heat flux inside the structure.

  12. Soil mercury levels in the area surrounding the Cerro Prieto geothermal complex, MEXICO.

    Science.gov (United States)

    Pastrana-Corral, M A; Wakida, F T; García-Flores, E; Rodriguez-Mendivil, D D; Quiñonez-Plaza, A; Piñon-Colin, T D J

    2016-08-01

    Even though geothermal energy is a renewable energy source that is seen as cost-effective and environmentally friendly, emissions from geothermal plants can impact air, soil, and water in the vicinity of geothermal power plants. The Cerro Prieto geothermal complex is located 30 km southeast of the city of Mexicali in the Mexican state of Baja California. Its installed electricity generation capacity is 720 MW, being the largest geothermal complex in Mexico. The objective of this study was to evaluate whether the emissions generated by the geothermal complex have increased the soil mercury concentration in the surrounding areas. Fifty-four surface soil samples were collected from the perimeter up to an approximate distance of 7660 m from the complex. Additionally, four soil depth profiles were performed in the vicinity of the complex. Mercury concentration in 69 % of the samples was higher than the mercury concentration found at the baseline sites. The mercury concentration ranged from 0.01 to 0.26 mg/kg. Our results show that the activities of the geothermal complex have led to an accumulation of mercury in the soil of the surrounding area. More studies are needed to determine the risk to human health and the ecosystems in the study area. PMID:27418073

  13. Soil mercury levels in the area surrounding the Cerro Prieto geothermal complex, MEXICO.

    Science.gov (United States)

    Pastrana-Corral, M A; Wakida, F T; García-Flores, E; Rodriguez-Mendivil, D D; Quiñonez-Plaza, A; Piñon-Colin, T D J

    2016-08-01

    Even though geothermal energy is a renewable energy source that is seen as cost-effective and environmentally friendly, emissions from geothermal plants can impact air, soil, and water in the vicinity of geothermal power plants. The Cerro Prieto geothermal complex is located 30 km southeast of the city of Mexicali in the Mexican state of Baja California. Its installed electricity generation capacity is 720 MW, being the largest geothermal complex in Mexico. The objective of this study was to evaluate whether the emissions generated by the geothermal complex have increased the soil mercury concentration in the surrounding areas. Fifty-four surface soil samples were collected from the perimeter up to an approximate distance of 7660 m from the complex. Additionally, four soil depth profiles were performed in the vicinity of the complex. Mercury concentration in 69 % of the samples was higher than the mercury concentration found at the baseline sites. The mercury concentration ranged from 0.01 to 0.26 mg/kg. Our results show that the activities of the geothermal complex have led to an accumulation of mercury in the soil of the surrounding area. More studies are needed to determine the risk to human health and the ecosystems in the study area.

  14. Gas chemistry and thermometry of the Cerro Prieto, Mexico, geothermal field

    Science.gov (United States)

    Nehring, N.L.; D'Amore, F.

    1984-01-01

    Gas compositions of Cerro Prieto wells in 1977 reflected strong boiling in the reservoir around wells M-20 and M-25. This boiling zone appeared to be collapsing in 1982 when a number of wells in this area of the field were shut-in. In 1977 and 1982, gas compositions also showed boiling zones corresponding to faults H and L postulated by Halfman et al. (1982). Four gas geothermometers were applied, based on reservoir equilibria and calculated fugacities. The Fisher - Tropsch reaction predicted high temperatures and appeared to re-equilibrate slowly, whereas the H2S reaction predicted low temperatures and appeared to re-equilibrate rapidly. Hydrogen and NH3 reactions were intermediate. Like gas compositions, the geothermometers reflected reservoir processes, such as boiling. Surface gas compositions are related to well compositions, but contain large concentrations of N2 originating from air dissolved in groundwater. The groundwater appears to originate in the east and flow over the production field before mixing with reservoir gases near the surface. ?? 1984.

  15. Intersecting faults and sandstone stratigraphy at the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Vonder Haar, S.; Howard, J.H.

    1980-02-01

    The northwest-southeast trending Cerro Prieto fault is part of a major regional lineament that extends into Sonaro and has characteristics of both a wrench fault and an oceanic transform fault. The distribution of lithologies and temperature within the field was studied by comparing data from well cuttings, cores, well logs, and geochemical analyses. Across the earliest developed portion of the field, in particular along a 1.25-km northeast-southwest section from well M-9 to M-10, interesting correlations emerge that indicate a relationship among lithology, microfracturing, and temperature distribution. In the upper portion of Reservoir A of this stratigraphic section, between 1200 and 1400 m, the percentage of sandstones ranges from 20 to 55. Temperatures are 225/sup 0/ to 275/sup 0/C based on well logs, calcite isotope maxima, and Na-K-Ca indices. The study shows that an isothermal high in this vicinity corresponds to the lowest total percentage of sandstones. Scanning electron microphotographs of well cores and cuttings from sandstone and shale units reveal clogging, mineral dissolution, and mineral precipitation along microfractures. The working hypothesis is that these sandy shale and siltstone facies are most amenable to increased microfracturing and, in turn, such microfracturing allows for higher temperature fluid to rise to shallower depths in the reservoir.

  16. Criteria to determine the depth of the production interval in wells of the Cerro Prieto geothermal field, Mexico; Criterios para determinar la profundidad del intervalo productor en pozos del campo geotermico de Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Leon Vivar, Jesus Saul de [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: jesus.deleon@cfe.gob.mx

    2006-07-15

    Ways to select the depth of the production interval or to complete wells in the Cerro Prieto geothermal field have changed during the development of the field. From 1961 when drilling began to the middle of 2005, a total of 325 wells were drilled. The paper compares the approaches used in the past with those of the last ten years. The Cerro Prieto system has been classified as being of liquid-dominated and high-temperature. Today, after 33 years of commercial exploitation, it has experienced a series of thermal and geochemical fluid changes making it necessary to modify the ways to select the depth of the well production intervals, according to the observed behavior of the reservoir. The new criteria include the thermal approach, the geological approach, the geochemical approach and a comparative approach with neighboring wells. If most of these criteria are interpreted correctly, the success of a well is ensured. [Spanish] Los criterios para seleccionar la profundidad del intervalo productor o la terminacion de los pozos en el campo geotermico de Cerro Prieto han cambiado durante el desarrollo del mismo. De 1961, cuando se perforaron los primeros pozos, hasta mediados del 2005 se han perforado un total de 325 pozos. En el presente articulo se hara una breve revision de cuales han sido los criterios usados en el pasado y los que se han venido empleando en los ultimos diez anos. El yacimiento de Cerro Prieto ha sido clasificado como de liquido dominante, de alta temperatura, pero actualmente, despues de 33 anos de explotacion comercial, ha sufrido una serie de cambios termicos y geoquimicos en sus fluidos, por lo que ha sido necesario modificar los criterios para seleccionar la profundidad del intervalo productor de los pozos de acuerdo al comportamiento observado en el yacimiento. Los criterios actuales se dividen en cuatro: 1. Criterio termico, 2. Criterio geologico, 3. Criterio geoquimico y 4. Criterio comparativo de los pozos vecinos. Cuando la mayoria de estos

  17. Evolution of the CP-I sector of the Cerro Prieto geothermal reservoir, BC, and exploitation alternatives; Evolucion del sector CP-I del yacimiento geotermico de Cerro Prieto, BC, y alternativas de explotacion

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2010-01-15

    After 35 years of exploitation of the CP-I (Cerro Prieto I) sector of the Cerro Prieto geothermal field, its thermal conditions have been declined substantially; the number of production wells is reduced and exploitation has been abandoned in some zones. However with a binary cycle, it is still possible to generate electricity from the remaining reservoir energy. To do so, one needs to know a detailed reservoir history of the sector, identifying the best potential strata to be assessed. In this paper, the CP-I reservoir evolution is presented and its exploitation and main reservoir characteristics -which play important roles- are identified. The CP-I zones offering the best conditions for binary cycle exploitation are identified. Exploiting partially abandoned reservoir sections is crucial for the future of the field. If such sections can be made to produce, this will help reduce the progressive steam-production decline in the occurring since production began. The production decline had been mitigated by a large area available for drilling replacement production wells, but such an area is limited now, due to the vast number of operating wells. [Spanish] Despues de 35 anos de explotacion del yacimiento en el sector de CP-I (Cerro Prieto I) del campo geotermico de Cerro Prieto, BC, sus condiciones termicas han declinado considerablemente, por lo que el numero de pozos productores ha disminuido, dejando algunas zonas abandonadas a la explotacion. Sin embargo, aun es posible aprovechar la energia que contiene este sector del yacimiento para la generacion de electricidad mediante ciclo binario. Para ello primeramente se debe conocer en detalle cual ha sido la evolucion del yacimiento en este sector, identificando los estratos de mejor potencial para evaluarlos posteriormente. En este estudio se presenta la evolucion del yacimiento de CP-I como respuesta a su explotacion, identificando las principales caracteristicas del yacimiento que determinan su comportamiento. Asi

  18. Update of the basement model of the Cerro Prieto, B. C., geothermal field, Mexico; Actualizacion del modelo del basamento en el campo geotermico de Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Lopez, Macario [Residencia General de Cerro Prieto, Comision Federal de Electricidad, Mexicali, Baja California (Mexico)

    1999-04-01

    With the aim to actualize the basement model of the Cerro Prieto Geothermal Field, a gravity interpretation has been held. We modeled in 2.5 D, nine profiles traced over the Bouguer anomaly map. Well data concerning lithology and density changes were used to fit the gravity models. Results of this work confirm that the geometry of the basement of Cerro Prieto, corresponds to a structural sequence. From west to east it starts as a big depression, continues with a strong uplift of the basement in the middle sector and finally deepens eastward in steps. The basement model proposed in the present work, defines a similar trend to that established by Fonseca y Razo (1980), but there are differences in basement depth in some areas. In the present model we interpret basement depths between 200 and 400 m deeper than in previous models to the south and northwest of the actual exploitation zone. [Spanish] Con el fin de actualizar el modelo del basamento en el Campo Geotermico de Cerro Prieto, se realizo una reinterpretacion gravimetrica, modelando en 2.5 D, 9 perfiles trazados sobre el mapa de anomalia de Bouguer. Utilizando la informacion litologica obtenida a traves de numerosas perforaciones profundas, se hicieron coincidir, dentro de los mofelos gravimetricos, las principales variaciones litologicas con cambios en la densidad. Los resultados de este trabajo reiteran que la geometria del basamento del Campo de Cerro Prieto, vista de W a E, corresponde con una secuencia estructural que se inicia con una gran depresion en el W, continua con un fuerte levantamiento y finalmente se extiende con una tendencia a profundizarse hacia el E de forma escalonada. El modelo de basamento derivado del presente trabajo, define una tendencia muy similar al modelo de basamento establecido (Fonseca y Razo, 1980), pero difiere en cuanto a la profundidad en algunos sectores del campo. En el actual trabajo se interpreta una profundidad entre 200 y 400 m mayor hacia el sur y noroeste de la

  19. Production induced boiling and cold water entry in the Cerro Prieto geothermal reservoir indicated by chemical and physical measurements

    Energy Technology Data Exchange (ETDEWEB)

    Grant, M.A. (DSIR, Wellington, New Zealand); Truesdell, A.H.; Manon, A.

    1981-01-01

    Chemical and physical data suggest that the relatively shallow western part of the Cerro Prieto reservoir is bounded below by low permeability rocks, and above and at the sides by an interface with cooler water. There is no continuous permeability barrier around or immediately above the reservoir. Permeability within the reservoir is dominantly intergranular. Mixture with cooler water rather than boiling is the dominant cooling process in the natural state, and production causes displacement of hot water by cooler water, not by vapor. Local boiling occurs near most wells in response to pressure decreases, but no general vapor zone has formed.

  20. Vertical movement along the Cerro Prieto transform fault, Baja California, Mexico - a mechanism for geothermal energy renewal

    Energy Technology Data Exchange (ETDEWEB)

    Vonder Haar, S.; Noble, J.E.; Puente Cruz, I.

    1979-03-01

    Data from 53 geothermal wells to depths of 1 to 3 km on either side of the right-lateral Cerro Prieto fault, as well as geophysical data, indicate vertical displacements of this fault of 400 to 600 m. This episoidic vertical movement has offset deltaic sandstone reservoirs that are primarily at 1200 m and 1800 m depth and contain 250{sup 0} to 345{sup 0}C water. A major fracture system for convective fluid movement has been thus maintained, with production at 150 MW.

  1. Regional and local networks of horizontal control, Cerro Prieto geothermal area

    Science.gov (United States)

    Massey, B.L.

    1979-01-01

    The Cerro Prieto geothermal area in the Mexicali Valley 30 km southeast of Mexicali, Baja California, is probably deforming due to (1) the extraction of large volumes of steam and hot water, and (2) active tectonism. Two networks of precise horizontal control were established in Mexicali Valley by the U.S. Geological Survey in 1977 - 1978 to measure both types of movement as they occur. These networks consisted of (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from survey stations on an existing U.S. Geological Survey crustal-strain network north of the international border, and (2) a local net tied to stations in the regional net and encompassing the area of present and planned geothermal production. Survey lines in this net were selected to span areas of probable ground-surface movements in and around the geothermal area. Electronic distance measuring (EDM) instruments, operating with a modulated laser beam, were used to measure the distances between stations in both networks. The regional net was run using a highly precise long-range EDM instrument, helicopters for transportation of men and equipment to inaccessible stations on mountain peaks, and a fixed wing airplane flying along the line of sight. Precision of measurements with this complex long-range system approached 0-2 ppm of line length. The local net was measured with a medium-range EDM instrument requiring minimal ancillary equipment. Precision of measurements with this less complex system approached 3 ppm for the shorter line lengths. The detection and analysis of ground-surface movements resulting from tectonic strains or induced by geothermal fluid withdrawal is dependent on subsequent resurveys of these networks. ?? 1979.

  2. Carbon-13 variations in fluids from the Cerro Prieto geothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Janik, C.J.; Nehring, N.L.; Huebner, M.A.; Truesdell, A.H.

    1982-08-10

    The carbon isotope compositions of CO/sub 2/ in steam from Cerro Prieto production well have been measured for 1977, 1979, and 1982. Variations in the delta/sup 13/C values are caused by production-related changes in the chemical and physical parameters of the geothermal system. In 1977, most CO/sub 2/ in the reservoir was isotopically light (delta/sup 13/C = -6.4 +/- 0.4). Heavier CO/sub 2/ was produced from wells in the center of the field (M5,M26,M27) due to deposition of isotopically light calcite caused by near-well boiling. In 1979 nearly all well showed relatively heavy CO/sub 2/, probably due to expansion of aquifer boiling and calcite precipitation. In 1982, many wells in the central part of the field were shut in. The amount of drawndown decreased and as temperatures and pressures near the wells increased, the boiling zones collapsed. The CO/sub 2/ in the fluid then exchanged with the precipitated calcite and became isotopically lighter. The sensitivity of carbon isotopes to calcite precipitations caused by aquifer boiling and to reequilibration with this deposited calcite upon decrease of boiling suggests use as an indicator of these aquifer processes. Surficial CO/sub 2/ of thermal origin was collected in 1981. Generally, the carbon-13 contents were close to CO/sub 2/ from production wells except for high-temperature mud pots and fumaroles containing isotopically light CO/sub 2/ derived from near surface alteration of organic matter.

  3. Changes in steam production due to the reservoir conditions in Cerro Prieto, Baja California; Cambios en la produccion de vapor debido a las condiciones del yacimiento en Cerro Prieto, Baja California

    Energy Technology Data Exchange (ETDEWEB)

    Morales Cardenas, Ramon; Rodriguez Rodriguez, Marco H. [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: marco.rodriguez01@gfe.gob.mx

    2011-07-15

    In more than 35 years of exploitation, thermodynamic conditions have changed in the Cerro Prieto geothermal reservoir. The effects are analyzed of the changes to the reservoir and their consequences to steam production in different field zones. For steam production, the most important features of reservoir fluids are enthalpies and pressures. The evolution of these features is presented in an enthalpy-pressure diagram. Here it can be seen that some reservoir zones have almost reached abandonment conditions. [Spanish] En mas de 35 anos de explotacion el yacimiento geotermico de Cerro Prieto ha experimentado cambios en sus condiciones termodinamicas. En este trabajo se analiza el efecto de esos cambios del yacimiento y su repercusion en la produccion de vapor para las diferentes zonas en las que se ha dividido el campo. Las propiedades mas importantes del fluido en el yacimiento para la produccion de vapor son su entalpia y su presion, por lo que se presenta la evolucion de esas propiedades en un diagrama de presion-entalpia, en el que se observa que hay zonas del yacimiento que estan proximas a alcanzar condiciones de abandono.

  4. Land subsidence in the Cerro Prieto Geothermal Field, 1 Baja California, Mexico, from 1994 to 2005. An integrated analysis of DInSAR, levelingand geological data.

    Energy Technology Data Exchange (ETDEWEB)

    Sarychikhina, O; Glowacka, E; Mellors, R; Vidal, F S

    2011-03-03

    Cerro Prieto is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field. The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to infrastructure such as roads, irrigation canals and other facilities. In this paper, the technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) is applied using C-band ENVISAR ASAR data acquired between 2003 and 2006 to determine the extent and amount of land subsidence in the Mexicali Valley near Cerro Prieto Geothermal Field. The DInSAR results were compared with published data from precise leveling surveys (1994- 1997 and 1997-2006) and detailed geological information in order to improve the understanding of temporal and spatial distributions of anthropogenic subsidence in the Mexicali Valley. The leveling and DInSAR data were modeled to characterize the observed deformation in terms of fluid extraction. The results confirm that the tectonic faults control the spatial extent of the observed subsidence. These faults likely act as groundwater flow barriers for aquifers and reservoirs. The shape of the subsiding area coincides with the Cerro Prieto pull-apart basin. In addition, the spatial pattern of the subsidence as well as changes in rate are highly correlated with the development of the Cerro Prieto Geothermal Field.

  5. Land subsidence in the Cerro Prieto Geothermal Field, Baja California, Mexico, from 1994 to 2005: An integrated analysis of DInSAR, leveling and geological data

    Science.gov (United States)

    Sarychikhina, Olga; Glowacka, Ewa; Mellors, Robert; Vidal, Francisco Suárez

    2011-07-01

    Cerro Prieto is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field. The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to the local infrastructure such as roads, irrigation canals and other facilities. In this paper, the technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) is applied using C-band ENVISAR ASAR data acquired between 2003 and 2006 to determine the extent and amount of land subsidence in the Mexicali Valley near Cerro Prieto Geothermal Field. The DInSAR results were compared with published data from precise leveling surveys (1994-1997 and 1997-2006) and detailed geological information in order to improve understanding of the temporal and spatial distributions of anthropogenic subsidence in the Mexicali Valley. The leveling and DInSAR data were modeled to characterize the observed deformation in terms of fluid extraction. The results confirm that the tectonic faults control the spatial extent of the observed subsidence. These faults likely act as groundwater flow barriers for aquifers and reservoirs. The shape of the subsiding area coincides with the Cerro Prieto pull-apart basin. In addition, the changes in spatial pattern and rate of the subsidence are correlated with the development of the Cerro Prieto Geothermal Field.

  6. Hydraulic model of the steam-lines network of the Cerro Prieto, B.C., geothermal field; Modelo hidraulico de la red de vaporductos del campo geotermico de Cerro Prieto, B.C.

    Energy Technology Data Exchange (ETDEWEB)

    Salaices, E; Garcia, A; Martinez J I; Ovando, R; Cecenas, M; Hernandez A F [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: salaices@iie.org.mx; Canchola, I; Mora, O; Miranda, C; Herandez, M; Lopez, S; Murillo, I [Comision Federal de Electricidad, B.C (Mexico)

    2007-01-15

    The steam-line network of the Cerro Prieto geothermal field is composed of 184 wells, and 162 of the wells are integrated and connected by pipes. Thirteen power units, with an installed electrical capacity of 720 MW, are fed by that network. The network length is 120 km, including pipes of several diameters with branches and interconnections. The extension and complexity of the steam-line system make it difficult to analyze the transport and supply of steam to the power plants. For that it was necessary to have a tool capable of analyzing the system and the performance of the network as a whole, as well as the direction and flow volumes in each part of the system. In this paper, a hydraulic model of the Cerro Prieto steam-line network is presented. The model can determine the performance of the whole network by quantifying the pressure drops, flows and heat losses of the components. The model analyses the consequences of changes in operating conditions, steam production, maintenance activities and design (such as the integration of new wells). The model was developed using PIPEPHASE 9.0, a numeric simulator of multi-phase flow in steady state with heat transfer. It is used to model systems and pipe networks for steam- and condensate-transport. [Spanish] La red de vaporductos del campo geotermico de Cerro Prieto esta compuesta por un conjunto de 184 pozos, de los cuales 162 son pozos integrados, interconectados entre si a traves de una red de tuberias. Por medio de esta red se alimentan 13 unidades generadoras de electricidad con una capacidad total instalada de 720 MWe. La red tiene una longitud aproximada de 120 kilometros y esta compuesta por tuberias de diferentes diametros, ramales, interconexiones, etc. La complejidad y extension del sistema de vaporductos hace muy dificil el analisis del transporte y suministro de vapor a las plantas generadoras. Lo anterior creo la necesidad de contar con una herramienta que ayudara en el analisis del sistema con el fin de

  7. Noise reduction in steam-vent points at the Cerro Prieto geothermal field, BC; Reduccion del ruido en puntos de desfogue en el campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Miranda Herrera, Carlos A [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C (Mexico)]. E-mail: carlos.miranda02@cfe.gob.mx

    2008-01-15

    Steam silencers have been placed on the power units regulation system of the Cerro Prieto geothermal field, but not where the steam-pipes vent high-pressure steam (rupture disks). Moreover, the power-unit silencers are large and their abilities to reduce noise depend on an external, uncontrollable factor: pores sizes in the volcanic rocks they are made of. Thus a compact, economic and relatively easy to construct metallic silencer was designed to be used at several points of dry-steam venting to minimize the noise. The design was based on orifice-plate equations and a prototype was constructed and tested. It proved capable of reducing noise by 30 decibels for atmospheric discharges of primary steam at operating pressures. The size of the silencer can be adjusted to the particular needs of each vent case. [Spanish] En el campo geotermico de Cerro Prieto solo existen silenciadores de vapor en el sistema de regulacion de las plantas generadoras, pero no en los sitios de desfogue de vapor a alta presion en los vaporductos (discos de ruptura). Ademas, los silenciadores de las plantas son muy robustos y su capacidad de reduccion del ruido depende de un factor externo no controlable, como es el tamano del poro de la roca volcanica con el que estan construidos. Por lo tanto, se diseno un silenciador metalico compacto, economico y relativamente facil de fabricar, para utilizarse en diversos puntos de descarga de vapor seco a fin de minimizar el ruido. El diseno se realizo con base en las ecuaciones de la placa de orificio. Se construyo un prototipo cuyas pruebas demostraron que es capaz de reducir el ruido hasta en 30 decibeles, al descargar desde la presion de operacion de vapor primario hacia la presion atmosferica. Las dimensiones del silenciador pueden ajustarse a las necesidades particulares de cada caso de desfogue.

  8. Cost model for geothermal wells applied to the Cerro Prieto geothermal field case, BC Abstract; Modelo de costeo de pozos geotermicos aplicado para el caso del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Vaca Serrano, Jaime M.E [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)]. E-mail: jaime.vaca@cfe.gob.mx

    2008-01-15

    A project for drilling geothermal wells to produce electrical energy can be defined as a sequence of plans to get steam or geothermal fluids to satisfy a previously known demand, and, under the best possible conditions, to obtain payment. This paper presents a cost model for nine wells drilled at the Cerro Prieto geothermal field in 2005 and 2006 to supply steam to the power plants operating in the field. The cost model is based on the well cost, the initial steam production, the annual decline of steam, the drilling schedule and the break-even point for each well. The model shows the cost of steam by the ton and the sale price needed to determine the discount rate and the investment return time. [Spanish] Un proyecto de perforacion de pozos geotermicos puede definirse como una secuencia o sucesion de planes para obtener vapor o fluidos geotermicos destinados a satisfacer una demanda previamente determinada, que se emplearan principalmente para generar energia electrica, bajo las mejores condiciones para obtener un pago. Este trabajo presenta un modelo de costeo para nueve pozos en el campo geotermico de Cerro Prieto, que fueron perforados entre 2005 y 2006 como parte del suministro de vapor para las plantas generadoras que operan en este campo. El modelo de costeo se basa en el costo por pozo, la produccion inicial de vapor, la declinacion anual de vapor, los intereses de las obras de perforacion y el punto de equilibrio para cada pozo. Los resultados permiten conocer el costo de la tonelada de vapor y el precio de venta para determinar la tasa de descuento y el tiempo de retorno de la inversion.

  9. Curie point depth from spectral analysis of aeromagnetic data from Cerro Prieto geothermal area, Baja California, México

    Science.gov (United States)

    Espinosa-Cardeña, J. M.; Campos-Enriquez, J. O.

    2008-10-01

    Using aeromagnetic data acquired in the area from the Cerro Prieto geothermal field, we estimated the depth to the Curie point isotherm, interpreted as the base of the magnetic sources, following statistical spectral-based techniques. According to our results the Curie point isotherm is located at a depths ranging from 14 to 17 km. Our result is somewhat deeper than that obtained previously based only in 2-D and 3-D forward modeling of previous low-quality data. However, our results are supported by independent information comprising geothermal gradients, seismicity distribution in the crust, and gravity determined crustal thickness. Our results imply a high thermal gradient (ranging between 33 and 38 °C/km) and high heat flow (of about 100 mW/m 2) for the study area. The thermal regime for the area is inferred to be similar to that from the Salton trough.

  10. Results of the first order leveling surveys in the Mexicali Valley and at the Cerro Prieto field

    Energy Technology Data Exchange (ETDEWEB)

    de la Pena L, A.

    1981-01-01

    The results obtained from the third leveling survey carried out by the Direccion General de Geografia del Territorio Nacional (previously DETENAL) during November and December 1979 are presented. Calculations of the changes in field elevation and plots showing comparisons of the 1977, 1978, and 1979 surveys are also presented. Results from a second order leveling survey performed to ascertain the extent of ground motion resulting from the 8 June 1980 earthquake are presented. This magnitude ML = 6.7 earthquake with epicenter located 15 km southeast of the Guadalupe Victoria village, caused fissures on the surface, the formation of small sand volcanos, and the ejection of ground water in the vicinity of the Cerro Prieto field. This leveling survey was carried out between benchmark BN-10067 at the intersection of the Solfatara canal and the Sonora-Baja California railroad, and benchmark BN-10055 located at the Delta station.

  11. Studies for recovering injection capacity in wells of the Cerro Prieto, BC, geothermal field; Estudios para recuperar la capacidad de aceptacion en pozos inyectores del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez Rosales, Julio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: julio.alvarez@cfe.gob.mx

    2010-01-15

    As in geothermal fields around the world, at Cerro Prieto geothermal field, Baja California, former exploratory and production wells are used to inject residual brine. Since the 1980s, studies and activities have been carried out to find ways to recharge the reservoir and dispose of brine without harming the environment or underground aquifers. These include infiltration and cold-and-hot injection. Some of the studies are presented here, including analyses of litho-facies; core samples; pressure, temperature and spinner logs; well tests and injection rates-plus some studies on the shallow aquifer. All have been useful in fulfilling requirements made by environmental authorities. Because injection rates constantly decrease due to formation damage, it is proposed an additional technique be used to reduce such damages and prolong the lifetime of cold-and-hot injection wells-while ensuring the environment and shallow aquifers are not affected. [Spanish] Al igual que en diversos campos geotermicos en el mundo, en el de Cerro Prieto, Baja California se han utilizado tanto pozos inyectores perforados ex profeso como antiguos pozos exploratorios y productores para inyectar el fluido residual al subsuelo. Desde la decada de los 80 se han realizado diversos estudios y acciones en ese campo geotermico para recargar al yacimiento y para disponer del fluido residual, sin ocasionar danos al ambiente ni a los cuerpos hidricos del subsuelo, que van desde la infiltracion hasta la inyeccion en frio y en caliente. Este articulo presenta los diferentes estudios realizados con ese objetivo en el campo, incluyendo el analisis de litofacies, de nucleos de formacion, de registros de presion, temperatura y spinner, las pruebas en pozos y analisis de tasas de aceptacion, asi como los efectuados en el acuifero superficial. Todos ellos han sido de utilidad para atender los requerimientos de las autoridades ambientales. Finalmente, y en virtud de que las tasas de aceptacion de los pozos

  12. Two-phase characteristics of the feeding fluid of Cerro Prieto IV wells (Mexico) obtained by gas equilibrium; Caracteristicas bifasicas del fluido de alimentacion de pozos de Cerro Prieto IV (Mexico), obtenidas por equilibrio gaseoso

    Energy Technology Data Exchange (ETDEWEB)

    Barragan-Reyes, Rosa Maria; Arellano-Gomez, Victor Manuel; Portugal-Marin, Enrique [Instituto de Investigaciones Electricas (Mexico); De Leon-Vivar, Jesus [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)

    2008-10-15

    The gas composition of fluids produced by CP IV geothermal wells from the Cerro Prieto field was studied in order to identify different types of fluids entering the wells by estimating their temperature and excess steam. A method based on the Fischer Tropsch reaction and H2S equilibrium with pyrite-pyrrhotite as mineral buffer (FTHSH3) was used. The results for the reservoir natural state indicated the presence of fluids with heterogeneous reservoir temperature (between 275 and 310 degrees Celsius) and excess steam values, which were found from negative (boiled liquid that has lost steam when flowing to the well) to one (steam phase with zero liquid saturation). The study for individual wells in which boiling processes were identified, showed that through time, the feeding fluids consist of a two-phase mixture with different liquid/steam proportions. Also, the results suggested that a steam phase could occur at CP IV which is added to the feeding fluid, depending on the operation conditions of the wells. The origin of this steam could be the boiling of the deeper liquid due to a pressure drop. [Spanish] Se estudio la composicion gaseosa de los fluidos producidos por pozos geotermicos del sector CP IV del campo de Cerro Prieto para tratar de distinguir aportes de fluidos diferentes mediante la estimacion de su temperatura de yacimiento y del exceso de vapor. Se utilizo un metodo de equilibrio gaseoso basado en la reaccion de Fischer Tropsch y el equilibrio combinado pirita-pirrotita (FT-HSH3). Los resultados obtenidos indican que en el estado inicial del yacimiento existen fluidos que muestran heterogeneidad en los valores de temperatura de yacimiento (entre 275 y 310 grados Celsius), asi como en el exceso de vapor con valores desde negativos (liquido que despues de ebullir ha perdido vapor en su trayecto hacia el pozo) hasta uno (vapor con cero saturacion de liquido). El estudio individual de los pozos con fenomenos de ebullicion muestra que a traves del tiempo

  13. Geological and production analyses focused on exploration of the eastern part of the Cerro Prieto geothermal field, BC; Analisis geologico-productivo enfocado a la exploracion de la parte oriental del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

    2008-01-15

    The eastern part of the Cerro Prieto geothermal field (CGCP), known as Poligono Nuevo Leon, is an area with proven geothermal resources, as confirmed by seven directional wells located toward the east and by vertical well M-200 located inside the polygon. Well M-200 was drilled in 1984 and has produced about 4 million tons of steam to date. It is integrated into the CP-2 sector, producing 68 t/h of steam. Presently the eastern part of CGCP, representing 25% of the total field area, is producing over half of the steam for the entire field. In the last few years, the steam has come only after increasing the number of production wells located in the eastern zone of CGCP (Rodriguez, 2006), where pressure, enthalpy and temperature conditions are better than in other parts of the field. However in the long term it will be necessary to incorporate Poligono Nuevo Leon into the productive area to expand the productive life of CGCP. This paper includes a geological analysis, plus models for steam production, temperature and enthalpy for Poligono Nuevo Leon. [Spanish] La parte oriental del Campo Geotermico de Cerro Prieto (CGCP), conocida como Poligono Nuevo Leon, representa una area potencial con recursos geotermicos comprobados, lo que demuestran siete pozos direccionales que se han perforado hacia el este, asi como el pozo vertical M-200, localizado dentro del poligono. El pozo M-200 se perforo en 1984 y ha producido a la fecha alrededor de 4 millones de toneladas de vapor, estando integrado al sector CP-2 una produccion de 68 t/h de vapor. Actualmente la parte oriental del CGCP, que representa el 25% del area total del campo, produce mas de la mitad del total de vapor del campo. El suministro de vapor en los ultimos anos se ha logrado cubrir aumentando el numero de pozos en operacion localizados en la zona oriente del CGCP (Rodriguez, 2006), ya que es aqui donde hay condiciones de presion, entalpia y temperatura del yacimiento que son mejores que en otras areas del campo

  14. A preliminary interpretation of gas composition in the CP IV sector wells, Cerro Prieto geothermal field, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Barragan Reyes, Rosa Maria; Arellano Gomez, Victor M; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Morelos (Mexico)]. E-mail: rmb@iie.org.mx; Perez Hernandez, Alfredo; Rodriguez Rodriguez, Marco Helio; Leon Vivar, Jesus de [Comision Federal de Electricidad, Residencia General Cerro Prieto, B.C. (Mexico)

    2007-07-15

    To increase the electrical generation capacity of the Cerro Prieto geothermal field from 620 MW to 720 MW, the Cerro Prieto IV (CP IV) sector of the field was developed in the NE portion of the exploited field. Fourteen new wells have been drilled there since 2000. The wells in CP IV zone produce two-phase fluids at wellhead with heterogeneous steam fraction characteristics: at the central zone and towards the NW, the wells are liquid-dominated while those towards the E and S produce a relatively high steam fraction. This work studies the gas compositions of produced fluids to obtain reservoir parameters such as temperature and steam fraction and identify different sources of fluids in the wells. A method was used based on the Fischer Tropsch reaction and H{sub 2}S equilibria with pyrite-pyrrhotite as a mineral buffer (FT-HSH3). The results for the natural state showed the presence of fluids with reservoir temperatures from 275 to 310 degrees Celsius and excess steam values from -1 to 50%. Data are aligned in a FT-HSH3 trend, suggesting that the well discharges consist of a mixture in different proportions of the two end members. One seems to be a liquid with a temperature of over 300 degrees Celsius with negative or negligible excess steam. The other seems to be a two-phase fluid with a temperature of about 275 degrees Celsius and an excess steam fraction of about 0.5. According to the data for single wells and depending on the production conditions of the wells, reservoir fluid mixtures could occur in different proportions of liquid and steam. Data for 2005 that included wells drilled after 2000 suggest the presence of a steam phase in the reservoir. The steam could be generated with the boiling of deep reservoir fluid from a pressure drop. The mixing trend obtained for the natural state was also seen for 2005 data but lower temperatures (from 265 to 295 degrees Celsius) were obtained compared with those for natural conditions. The entry of lower

  15. Monitoring and modeling land subsidence at the Cerro Prieto Geothermal Field, Baja California, Mexico, using SAR interferometry

    Science.gov (United States)

    Carnec, Claudie; Fabriol, Hubert

    Images derived from repeat-pass spaceborne interferometric synthetic aperture radar (InSAR) systems offer the possibility of mapping surface deformation of small spatial extent and monitoring its spatio-temporal evolution. A slow local subsidence has been detected at the Cerro Prieto geothermal field from images acquired by the European Space Agency remote sensing satellites ERS-1/2 between 1993 and 1997. Although agricultural activity in the area limited the investigation, interferometric monitoring revealed that the ground deformation is associated with the withdrawal of geothermal fluid and agreed with the leveling data. Modeling of the subsidence was carried out assuming elastic deformation in a half-space from simple point sources, of which five were necessary to reproduce the fringe patterns observed on the interferograms. The depths and locations of three of the sources are compatible with the location of the known reservoir. The study improves prior knowledge of the displacement field and of the mecanisms involved in the subsidence phenomenon.

  16. Gaseous equilibrium in sector CP IV of the Cerro Prieto, B.C. Mexico geothermal field; Equilibrio gaseoso en el sector CP IV del campo geotermico Cerro Prieto, B.C., Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Barragan Reyes, Rosa Maria; Arellano Gomez, Victor Manuel; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); De Leon Vivar, Jesus [Comision Federal de Electricidad, Campo Geotermico Cerro Prieto, Cerro Prieto, B. C. (Mexico)

    2007-07-01

    Sector CP IV is located in the NE portion of the Cerrro Prieto geothermal field. The wells of this zone produce two-phase fluids, with different characteristics as far as their steam fraction content; in the central part and towards the NW the fluids are of dominant liquid type whereas towards the E and the S, the fluid contains a relatively higher steam fraction. The results of gaseous equilibrium FT- HSH3 showed that the fluids in the deposit are at temperatures between 275 Celsius degrees and 310 Celsius degrees and contain steam fractions between 0.01 and 0.5. The data found for the natural state are aligned in a tendency defined in the diagram FT- HSH3, that suggest the wells receive different proportions from preexisting steam in the deposit, which are mixed with the liquid phase to produce the observed discharges. The present data, besides showing the presence of deposit steam, also indicates the entrance of lower temperature fluid in the central part of sector CP IV. [Spanish] El sector CP IV se localiza en la porcion NE del campo geotermico Cerro Prieto. Los pozos de esta zona producen fluidos bifasicos, con diferentes caracteristicas en cuanto a su contenido de fraccion de vapor: en la parte central y hacia el NW los fluidos son de tipo liquido dominante mientras que hacia el E y hacia el S, el fluido contiene una fraccion relativamente alta de vapor. Los resultados de equilibrio gaseoso FT-HSH3 mostraron que los fluidos en el yacimiento se encuentran a temperaturas de entre 275 grados Celsius y 310 grados Celsius y contienen fracciones de vapor de entre -.01 y .5. Los datos hallados para el estado natural se alinean en una tendencia definida en el diagrama FT-HSH3, que sugiere que los pozos reciben diferentes proporciones de vapor pre-existente en el yacimiento, que se mezclan con fase liquida para producir las descargas que se observan. Los datos actuales, ademas de mostrar la presencia de vapor de yacimiento, tambien indican la entrada de fluidos de

  17. Analysis of productive evolution of well M-19A, Cerro Prieto geothermal field, BC; Analisis de la evolucion productiva del pozo M-19A del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Rodriguez, Marco H; Romero-Rios, Francisco [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

    2007-07-15

    Well M-19A has been the most productive in the Cerro Prieto field, producing around 40 million tons of fluid. The well went on line in February 1975 and was in continuous operation until June 2006. Monthly measurements for over 30 years of operating conditions and chemical and isotopic analyses of the fluids allow identification of the most significant processes occurring in the zone where the well is located. Three dominant recharge types have been identified, each lasting about 10 years. They are a) a recharge of fluids of lower temperature than the production fluids, even though the chemical and isotopic compositions are similar; b) a recharge of lower-temperature fluids with diluted chemical and isotopic compositions; and c) a progressive recharge of reinjected water with a higher chloride concentration and heavy isotopic composition. The production and reinjection rates for over 30 years of production history in the M-19A well zone allow for speculation of a reservoir pressure recovery, which is confirmed with a calculation using production data from well M-19A. The evolution of the reservoir pressure in the zone contrasts with the rest of the reservoir, where a constant pressure drop is observed, particularly toward the central and eastern parts of the field. [Spanish] El pozo M-19A ha sido el mas productivo del campo geotermico de Cerro Prieto, BC, alcanzando una extraccion de mas de 40 millones de toneladas de fluido. Fue integrado a produccion en febrero de 1975 y hasta junio de 2006 ha permanecido en produccion en forma continua. Las mediciones mensuales de sus condiciones operativas y los analisis quimicos e isotopicos del agua producida permiten identificar los procesos mas significativos que han ocurrido a lo largo de esos mas de 30 anos en la zona donde se localiza el pozo. Se han identificado tres tipos de recarga dominantes que se presentan durante un periodo cercano a 10 anos cada uno, los cuales son: a) una recarga de fluidos de menor temperatura

  18. Analysis of the automation and control of the well production conditions in the Cerro Prieto geothermal field, Mexico; Analisis de la automatizacion y del control de las condiciones de produccion de los pozos del campo geotermico de Cerro Prieto, BC, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Murillo Zamora, Isaac [Comision Federal de Electricidad, Mexicali, BC, (Mexico); Ocampo Diaz, Juan de Dios [Universidad Autonoma de Baja California, Mexicali, BC, (Mexico); De la Pena Reyna, Gilberto [Comision Federal de Electricidad, Morelia, Michoacan (Mexico)

    2005-12-01

    Through 31 years of development of the Cerro Prieto geothermal field, the number of wells in operation and the distances between them has been increasing. Now there are 150 wells producing a mixture of water and steam at different ratios, depending on the reservoir characteristics (pressure, temperature, depth, etc.) and the operation conditions in the superficial installations (obstructions in the orifice plates diameter, separator pressures, etc.). Therefore, Comision Federal de Electricidad (CFE) has started a pilot plan to handle the automation and control of the operating conditions of production wells, and to install a data production acquisition system. The initial results of the system are in this paper. [Spanish] A traves de los 31 anos de desarrollo del campo geotermico de Cerro Prieto el numero de pozos en operacion asi como la distancia entre ellos se ha estado incrementando. Ahora hay mas de 150 pozos produciendo una cantidad de mezcla de agua y vapor a diferentes rangos, dependiendo de las caracteristicas del yacimiento (presion, temperatura, profundidad, etc.) y de las condiciones de operacion de las instalaciones superficiales (diametros de placas de orificio obstruidos, presion de los separadores, etc.). Como resultado la Comision Federal de Electricidad (CFE) ha dado inicio a un plan de pruebas para llevar a cabo la automatizacion y control de las condiciones de operacion de los pozos productores, e instalar un sistema con equipos para recoleccion de datos del campo, cuyos primeros resultados se presentan en este articulo.

  19. Implications for organic maturation studies of evidence of a geologically rapid increase and stabilization of vitrinite reflectance at peak temperature: Cerro Prieto geothermal system, Mexico

    Science.gov (United States)

    Barker, C.E.

    1991-01-01

    A short-term rapid heating and cooling of the rock in well M-94 below 1300 m was caused by a pulse of hot water passing through the edge of the Cerro Prieto, Mexico, geothermal system. Below 1300 m, the peak paleotemperatures were about 225-250??C, but equilibrium well log temperatures indicate a decrease to 150-210??C at present. This hot water pulse sharply increased vitrinite reflectance to levels comparable to those measured in the central part of the system, even though studies of apatite fission-track annealing indicate that the duration of heating was only 100-101 yr in M-94, in contrast to 103-104 yr in the central part of the system. The quick change of the vitrinite reflectance geothermometer indicates that thermal maturation reactions can stabilize, after a geologically short period of heating, to a level consistent with peak temperature under moderate to high-temperature diagenesis in open, fluid-rich, geothermal systems. -from Author

  20. Comparative study of the amplification of ground motion using seismic noise and recent earthquakes adjacent to the Cerro Prieto volcano, Baja California

    Science.gov (United States)

    Vega, F. D.; Vidal-Villegas, A.

    2009-12-01

    We have chosen an area of approximately 79 km2, centered around the Cerro Prieto volcano, in the Mexicalli valley, Baja California, based on elevated registered acceleration data. The GEO station, located in the Cerro Prieto geothermal field has registered seismic accelerations on the order of 492 gales. The local residents near the study area have reported feeling numerous smaller magnitude earthquakes, compared to those of the nearby populated city of Mexicalli. Does there exist an amplified seismic signal in the area? If so, what is the cause of the amplification? The objective of our study is to answer these questions and determine the subsurface (0-50 m) structure in 4 specific sites. To obtain these answers, we registered seismic noise samples using short period seismometers (1 s), intermediate (5 s) and 16 bit recorders, along a linear profile which crosses the volcano with an 18 degree NE orientation. Furthermore, we analyzed ground-motion data (from 2004-2006), obtained from 24-bit accelerographs. Using both types of data (noise and accelegraphs) we calculated the H/V spectral ratios, and the relative ratios between both sites. To determine the subsurface structure, we used a unidimensional model of the H/V ratios, based on the methodology used by Huerta-Lopez et al., 2005. The H/V spectral ratios from the seismic noise adjacent to the volcano display amplitude of 1 in the frequency range (0.8 - 30 Hz). In contrast, the amplitude in the volcano crater (159 m.a.s.l.) was 6 in the frequency range (0.8 - 3 Hz). The average H/V relative ratio of the crater and the adjacent sites is 4, with frequencies between 0.8 and 1.2 Hz. The S-wave H/V ratios for the VCP acceleration station (110 m.a.s.l.), are near 8, with frequencies between 1 and 2. The H/V spectral ratios from the seismic noise for the geothermal field display amplitude of 4 for frequencies between 0.8 and 1.3 Hz, while the results from the S wave display amplitudes of 5 between 1.5 and 3 Hz. In the

  1. Heat losses estimation associated with the physical state of the thermal insulation of pipes vaporductos network in Cerro Prieto geothermal field; Estimacion de perdidas de calor asociadas al estado fisico del aislamiento termico de las tuberias de la red de vaporductos del campo geotermico Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Ovando Castelar, Rosember; Martinez Estrella, Juan Ignacio; Garcia Gutierrez, Alfonso [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; jime@iie.org.mx; aggarcia@iie.org.mx; Canchola Felix, Ismael; Miranda Herrera, Carlos; Jacobo Galvan, Paul [Campo Geotermico de Cerro Prieto, Comision Federal de Electricidad, Mexicali, B.C. (Mexico)

    2010-11-15

    The Cerro Prieto Geothermal Field (CPGF) steam transportation network is constituted by 140 km of pipes with diameters ranging from 8 to 48 inches, which transport the steam of 165 producing wells to 13 power plants which have a total installed capacity of 720 MWe. Originally, the pipes are thermally insulated with a mineral wool or fiber glass layer and an external aluminum or iron cover. Due to the insulation material has been exposed to weather conditions during the field operation it shows nowadays different grades of wear-out, or even it is lacking in some parts of the network, causing higher heat losses from the pipes to the environment. In this work, the magnitude of the heat losses related with the present condition of the thermal insulation throughout the pipeline network is assessed. This involved determining the longitude and diameter, as well as the insulation condition of each single pipeline section, and the calculation of the heat transfer coefficients for the different thermal insulation conditions defined for this study. [Spanish] La red de transporte de vapor del campo geotermico Cerro Prieto (CGCP) esta constituida por aproximadamente 140 km de tuberias de 8 a 48 pulgadas de diametro, las cuales conducen el vapor producido por 165 pozos hacia 13 plantas generadoras, cuya capacidad instalada es de 720 MWe. Originalmente, estas tuberias son aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion exterior de aluminio o hierro. Debido principalmente al impacto de las condiciones meteorologicas durante el tiempo de operacion del campo, en algunas porciones de la red el aislante presenta actualmente distintos grados de deterioro, o incluso se encuentra ausente, lo cual se traduce en una mayor perdida de calor desde las tuberias hacia el medio ambiente. En el presente trabajo se evalua la magnitud de las perdidas de calor asociadas al estado fisico del aislamiento termico de las

  2. The geochemistry and isotope hydrology of the Southern Mexicali Valley in the area of the Cerro Prieto, Baja California (Mexico) geothermal field

    Science.gov (United States)

    Portugal, Enrique; Izquierdo, Georgina; Truesdell, Alfred; Álvarez, Julio

    2005-11-01

    Groundwaters from the phreatic aquifer within and surrounding of the Cerro Prieto geothermal field were analyzed geochemically and isotopically in order to establish a hydrodynamic model of the study zone, which is located in the Mexicali Valley between 655,000-685,000 m E-W and 3,605,000-3,576,000 m N-S relative to UTM coordinates. Based on their chemical composition three types of water were recognized: chloride, sulfate and bicarbonate. However four groups of water were identified on a statistical multi-variable method of cluster analysis (A-D). The average temperature is 25 °C; with a few exceptions in the south where temperature can be as high as 47 °C. Stable isotope ratios for some waters plot close to the world meteoric line, corresponding to the original unaltered waters of the zone. The hydrogeochemistry varies in relation to three principal processes: evaporation, infiltration of water used in agriculture and rock interaction by reaction with evaporitic deposits. Major quartz, calcite and plagioclase and minor smectite, kaolinite, halite, sylvite and gypsum were identified by X-ray diffraction in lacustrine sediments of the central part of the zone. Chemical modeling indicates saturation with respect to calcite and undersaturation with respect to gypsum. By incorporating chemical and isotope data into geological and isopotential well information, a hydrodynamic model has been postulated. In this hydrodynamic model the water (A) enters the study zone from the east and it is originally of the old Colorado River water. The water samples on which the model is based were draw from agricultural wells that intersected two aquifers, a shallow and a deep one, representing the recharge to the zone. The salinity of the deep aquifer water (B) is lower than that of the shallow aquifer water (C) and so is the stable isotope ratio. The difference is though to be due to dissolution of evaporates, evaporation and possible infiltration of spent agriculture water. Both

  3. Determination of heat losses in the Cerro Prieto, Baja California, geothermal field steam transportation network based on the thermal insulation condition of the steam pipelines; Determinacion de perdidas de calor en la red de transporte de vapor del campo geotermico de Cerro Prieto, Baja California, con base en el estado fisico del aislamiento termico de vaporductos

    Energy Technology Data Exchange (ETDEWEB)

    Ovando Castelar, Rosember; Garcia Gutierrez, Alfonso; Martinez Estrella, Juan Ignacio [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; Canchola Felix, Ismael; Jacobo Galvan, Paul; Miranda Herrera, Carlos; Mora Perez, Othon [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)

    2011-07-15

    In Cerro Prieto Geothermal Field (CPGF), the steam from producing wells is transported to power plants through a large and complex system of pipes thermally insulated with a 2 inches thick mineral wool or a fiber glass layer and an external aluminum or iron cover. The insulation material has been exposed to weather conditions during the field operation and has suffered density and thickness changes. In some cases the insulation has been lost completely, increasing heat transfer from the pipes to the environment. This paper analyzes the impact of the conditions of thermal insulation on heat losses in the CPGF steam-pipeline network. The heat losses are calculated by applying an iterative method to determine the surface temperature based on a heat balance calculated from the three basic mechanisms of heat transfer: conduction, convection, and radiation. Finally, using length and diameter data corresponding to the condition of the thermal insulation of each pipeline-and field operation data, the overall heat losses are quantified for steam lines throughout the pipeline network in the field. The results allow us to evaluate the magnitude of the heat losses in comparison with the overall energy losses occurring during steam transport from wells to the power plants. [Spanish] En el Campo Geotermico de Cerro Prieto (CGCP), BC, el transporte de vapor desde los pozos hasta las plantas generadoras de electricidad se lleva a cabo mediante un extenso y complejo sistema de tuberias que tipicamente se encuentran aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion mecanica de aluminio o hierro galvanizado. Debido a la exposicion a las condiciones meteorologicas a traves del tiempo de operacion del campo, el aislamiento ha experimentado cambios en su densidad y espesor y en ocasiones se ha perdido por completo, lo cual repercute en una mayor transferencia de calor de las tuberias hacia el medio ambiente

  4. Spatio-temporal evolution of anthropogenic deformation around Cerro Prieto geothermal field in the Mexicali Valley, B.C., Mexico, between 1993 and 2009 from DInSAR and leveling.

    Science.gov (United States)

    Sarychikhina, Olga; Glowacka, Ewa; Robles, Braulio; Mojarro, Jose

    2014-05-01

    Land subsidence is an environmental hazard which could be caused by withdrawal of large amounts of fluid from beneath the earth's surface. Land subsidence is an issue in several geothermal fields worldwide (e.g., Geysers, USA (Mossop and Segall, 1997), Wairakei-Tauhara, New Zealand (Allis et al., 2009)). Cerro Prieto geothermal field (CPGF), located in the Mexicali Valley, northwest Mexico, is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field (e.g. Glowacka et al., 1996, 1999; Carnec and Fabriol, 1999; Sarychikhina et al., 2011). The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to the local infrastructure such as roads, irrigation canals and other facilities. Detection of land subsidence and monitoring of the spatial and temporal changes of its pattern and magnitude can provide important information about the dynamics of this process and controlling geological structures. The technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) has been demonstrated to be a very effective technique for measuring ground deformation. This study presents an application of DInSAR interferogram stacking technique to investigate the land subsidence in the Mexicali Valley near CPGF. C-band ENVISAR ASAR images acquired between 2003 and 2009 from the ascending (track 306, frame 639) and descending track (track 84, frame 2961), obtained from the European Space Agency (ESA), as part of ESA CAT-1 project (ID - C1P3508), were used. Gamma ISP and DIFF/GEO software packages were used to calculate differential interferograms from SLC data and for differential interferograms stacking (Wegmüller and Werner, 1997). Eight average annual deformation rate maps were generated for 2005 (descending

  5. Geothermal well drilling manual at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez P., A.; Flores S., M.

    1982-08-10

    The objective of the drilling manual is to solve all problems directly related to drilling during the construction of a well. In this case, the topics dealt which are drilling fluids and hydraulics to be applied in the field to improve drilling progress, eliminate risks and achieve good well-completion. There are other topics that are applicable such as drill bits and the drilling string, which are closely linked to drilling progress. On this occasion drilling fluid and hydraulics programs are presented, in addition to a computing program for a Casio FX-502P calculator to be applied in the field to optimize hydraulics and in the analysis of hydraulics for development and exploration wells at their different intervals.

  6. Cerro Prieto geothermal field: exploration during exploitation

    Energy Technology Data Exchange (ETDEWEB)

    1982-07-01

    Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. The description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field are presented. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development.

  7. Drilling rate for the Cerro Prieto stratigraphic sequence

    Energy Technology Data Exchange (ETDEWEB)

    Prian C, R.

    1981-01-01

    Drilling practice at the field has been modified in several ways as better information is being obtained. The stratigraphic sequence of the area is made up of three sedimentary rock units of deltaic origin having different densities. These units have been named non-consolidated, semi-consolidated, and consolidated rocks; the thermal reservoirs are located in the latter. To investigate how the drilling rates are affected by the three rock units, plots of drilling advance versus time were made for a large number of wells. A typical plot is shown and drilling rates are practically constant in three different zones; that is, the drilling rate has only two breaks or changes in slope.

  8. Magnetotelluric studies at the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Goubau, W.M. (Lawrence Berkeley Lab., CA); Goldstein, N.E.; Clarke, J.

    1981-01-01

    During three years of magnetotelluric surveying, data were acquired at 26 sites distributed over 190 km/sup 2/ around the production area. A relatively well-defined strike of N27W +- 1.5/sup 0/ (magnetic) was established. The simple model shown suggests a lateral discontinuity in the vicinity of Nueva Leon.

  9. Geophysical characterization of subaerial hydrothermal manifestations in Punta Banda, Baja California, Mexico.

    Science.gov (United States)

    Flores-Marquez, L.; Prol-Ledesma, R. M.; Arango, C.; Canet, C.

    2009-04-01

    Important growth of population in Baja California Peninsula has triggered the need for energy and fresh water. The most sustainable possibility for increasing the availability of fresh water is the use of renewable energy sources in desalination plants. The abundance of geothermal manifestations in the peninsula provides a reliable energy source for desalination purposes. Geothermal development of the Baja California Peninsula dates from the 70's, when the Cerro Prieto geothermal field started producing electricity. Two important cities, Tijuana and Ensenada, are located in the north-western area of Baja California. The city of Ensenada has a desalination plant that is due to be replaced and the geothermal resources of the area could be an option for the new desalination plant. Punta Banda, a region near Ensenada, was specially investigated to determine its geothermal potential. Subaerial springs and the submarine vents were sampled and studied in this work, also geological and geochemical studies were performed, moreover geoelectrical surveys were accomplished to characterize the hydrothermal system at depth. Even though saline intrusion is a severe problem in Ensenada (TDS higher than 3000), thermal springs away from the coast and coastal springs have salinities lower than sea water. According to the geoelectrical models obtained from profiles, the inferred conductive features can be related to thermal anomalies. The existence of hot springs located along a trend suggests that the dynamic of the thermal fluid is restricted by secondary faults.

  10. Analysis of exploratory wells in the Cerro Prieto Field and the Mexicali Valley

    Energy Technology Data Exchange (ETDEWEB)

    Cobo R., J.M.; Bermejo M., F.J.

    1982-08-10

    Agricultural development in the Mexicali Valley and in the high cost of electric power required to operate the irrigation wells in the Valley prompted the Mexican government to investigate the possibility of taking advantage of thermal manifestations in the area located 28 km southeast of the city of Mexicali to generate electric power and thereby partially decrease the flight of foreign exchange. In 1958, a geologic study of the southern and southeastern zone of Mexicali was conducted to identify the possibilities of tapping geothermal resources. The purpose of this study was to gain knowledge of the geologic conditions in this area and, if possible, to establish the location of exploratory and production wells and, on the basis of the results of the former, examine the geologic history in order to gain knowledge and understanding of the structural control of the steam. On the basis of this study, it was recommended that 3 exploratory wells should be drilled in order to locate weak zones that would easily allow for steam flow.

  11. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico

    Science.gov (United States)

    Des Marais, D. J.; Stallard, M. L.; Nehring, N. L.; Truesdell, A. H.

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

  12. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico.

    Science.gov (United States)

    Des Marais, D J; Stallard, M L; Nehring, N L; Truesdell, A H

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

  13. Proceedings: third symposium on the Cerro Prieto geothermal field, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    These proceedings include both English and Spanish versions of each paper presented at the symposium. Illustrations and tables, which have been placed between the two versions, include captions in both languages. Forty-one papers are included. Five papers were indexed for EDB previously. Separate abstracts were prepared for thirty-three papers and three were listed by title.

  14. Pressure changes and their effects on the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Bermejo M, F.J.; Navarro O, F.X.; Esquer P, C.A.; Castillo B, F.; de la Cruz D, F.C.

    1981-01-01

    Continuous extraction of the water-steam mixture at the field has been increasing to fulfill the steam requirements of the power plant. As a result, pressure declines have been observed in the producing strata in all of the wells, as well as in the geothermal reservoir as a whole. Anomalous behavior that has been observed in the wells' hydraulic columns in most cases is due to the interconnection of the various strata penetrated by the well. When this occurs, unbalanced hydraulic pressures cause the movement of fluids between the strata. As an example of this hydraulic imbalance causing the flow of fluids from an upper to a lower zone, well Nuevo Leon 1 where this effect occurs between regions 600 m apart was chosen.

  15. The degassing character of a young volcanic center: Cerro Negro, Nicaragua

    Science.gov (United States)

    Lucic, Gregor; Stix, John; Sherwood Lollar, Barbara; Lacrampe-Couloume, Georges; Muñoz, Angélica; Carcache, Martha Ibarra

    2014-09-01

    Cerro Negro volcano is a young basaltic cinder cone which is part of the Nicaraguan volcanic arc. Eruptive activity at Cerro Negro is characterized by explosive strombolian to subplinian eruptions driven by volatile-rich basaltic magma ascending rapidly from various crustal depths (>15 to 6 km) resulting in the onset of precursory activity only ˜30 min before an eruption. In this paper, we present a comprehensive degassing characterization of the volcano over a 4-year period aimed at improving our understanding of the magmatic plumbing network and its relationship with regional tectonics. A total of 124 individual soil gas samples were collected between 2010 and 2013 and analyzed for stable carbon isotopes (δ13C) from CO2. High temperature fumaroles were sampled for δ18O, δD, and 3He/4He isotope analysis, and major degassing zones were mapped using soil CO2 flux measurements. Gases at Cerro Negro are characterized by a strong 3He/4He mantle signature (6.3 to 7.3 RA), magmatic δ13C ratios (-2.3 to -3.0 ‰), meteoric δ18O and δD ratios, and stable CO2 fluxes (31 t d-1). The lack of δ13C fractionation and an increase in the relative mantle component from 2002 to 2012 suggest that the volatile flux at Cerro Negro originates from the mantle and ascends to the surface via a series of crustal fractures that act as permeable conduits. Despite the lack of new eruptions, the hydrothermal system of Cerro Negro continues to evolve due to seasonal inputs of meteoric water, slope failures that expose and bury sites of active degassing, and bursts of regional seismicity that have the potential to open up new conduits for gas release as well as magma. Continuing geophysical and geochemical monitoring of the main edifice and the recently formed south zone is essential, as the volcano remains overdue to erupt.

  16. Treatment of the Cerro Prieto I brines for use in reinjection. 2. Results of the pilot plant tests

    Energy Technology Data Exchange (ETDEWEB)

    Hurtado J, R. (Instituto de Investigaciones Electricas, Mexicali, Mexico); Mercado G, S.; Rocha C, E.; Gamino O, H.; Garibaldi P, F.

    1981-01-01

    Silica removal experiments have been carried out both in the laboratory and in pilot scale tests. The results obtained to date are presented, with special emphasis on the pilot tests with or without the use of flocculants. Previous studies on brine treatment are described briefly.

  17. Occurrences of alunite, prophyllite, and clays in the Cerro La Tiza area, Puerto Rico

    Science.gov (United States)

    Hildebrand, Fred Adelbert; Smith, Raymond J.

    1959-01-01

    A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7? kilometers long, has an average width of about 1? kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These

  18. Sedimentary rocks Uranium in Cerro Largo Province

    International Nuclear Information System (INIS)

    With the aim of the uranium minerals exploration has been carried out several studies by UTE technicians in Cerro Largo Province from 1968 to 1969. In uranium concentration has been found pyrite, phosphate, iron oxides and manganese in uranium. Furthermore in La Divisa Ore were studied concentration Uranium enrichment has been studied in La Divisa ore

  19. Optical atmospheric extinction over Cerro Paranal

    NARCIS (Netherlands)

    F. Patat; S. Moehler; K. O'Brien; E. Pompei; T. Bensby; G. Carraro; A. de Ugarte Postigo; A. Fox; I. Gavignaud; G. James; H. Korhonen; C. Ledoux; S. Randall; H.A.A. Sana; J. Smoker; S. Stefl; T. Szeifert

    2011-01-01

    Aims. The present study was conducted to determine the optical extinction curve for Cerro Paranal under typical clear-sky observing conditions, with the purpose of providing the community with a function to be used to correct the observed spectra, with an accuracy of 0.01 mag airmass-1. Additionally

  20. Cerro de Pasco and other massive sulfide deposits of central Peru

    Energy Technology Data Exchange (ETDEWEB)

    Cheney, E.S.

    1985-01-01

    The famous Cerro de Pasco Pb-Zn-Ag deposit historically has been considered to be hydrothermally derived from an adjacent Tertiary volcanic vent. However, texturally massive pyrite-chert and pyrite-sphalerite-galena in the deposit have the same strike and cross folds as the adjacent pre-Tertiary strata. Both the deposit and the strata are cut by one of the large Longitudinal Faults. Both dikes and pyrite-enargite veins associated with the vent cut the massive sulfides; fragments of massive pyrite occur in the vent. A few examples of laminated pyrite and chert, banded pyrite and chert, banded pyrite and sphalerite, and banded pyrite, sphalerite, and galena are preserved in the massive sulfide portion of the deposit. The deposit has the composition and zoning patterns typical of shale-hosted massive sulfides. Cerro de Pasco probably in part of the pelitic Devonian Excelsior formation. The Colquijirca deposit 8 km to the south and the San Cristobal district 110 km to the south likewise have been considered to be Tertiary volcanic hydrothermal deposits. Colquijirca consists of stratigraphically controlled mantos of layered pyrite, chert and tuff in the Tertiary Calera formation. The mantos of the San Cristobal district are along the upper contact of the pyritic, Permian, Catalina felsic volcanic rocks; some ore consists of laminated pyrite and sphalerite. Tertiary plutons are conspicuously absent at San Cristobal, and the ores are brecciated by Tertiary folding.

  1. Structure and age of the Cerro de Pasco Cu-Zn-Pb-Ag deposit, Peru

    Science.gov (United States)

    Cheney, E. S.

    1991-04-01

    The world-famous Cu-Zn-Pb-Ag deposit at Cerro de Pasco, Peru, consists of texturally massive pyrite, texturally massive sphalerite-galena-pyrite, and veins containing pyrite and enargite. Historically the deposit has been considered to be the hydrothermal product of the adjacent Miocene volcanic and intrusive complex (locally known as the “Vent”). However, both the texturally massive sulfides of the deposit and the pre-Miocene strata are cut by the Longitudinal fault, one of the largest faults in the district, but the Vent is not. Imbrication by the Longitudinal fault zone (duplex structures) has thickened the deposit so that it is amenable to open-pit mining. Dikes and pyrite-enargite veins pass from the Vent into the massive sulfides; fragments of massive pyrite occur in the Vent. Thus, no matter what their origin, the texturally massive sulfides are older and, therefore, genetically unrelated to the Vent.

  2. Optical atmospheric extinction over Cerro Paranal

    CERN Document Server

    Patat, F; O'Brien, K; Pompei, E; Bensby, T; Carraro, G; Postigo, A de Ugarte; Fox, A; Gavignaud, I; James, G; Korhonen, H; Ledoux, C; Randall, S; Sana, H; Smoker, J; Stefl, S; Szeifert, T

    2010-01-01

    Aims: The present study was conducted to determine the optical extinction curve for Cerro Paranal under typical clear-sky observing conditions, with an accuracy of 0.01 mag/airmass. Methods: The extinction curve of Paranal was obtained through low-resolution spectroscopy of 8 spectrophotometric standard stars observed with FORS1 mounted at the 8.2 m Very Large Telescope, covering a spectral range 3300-8000 A. A total of 600 spectra were collected on more than 40 nights distributed over six months, from October 2008 to March 2009. The average extinction curve was derived using a global fit algorithm, which allowed us to simultaneously combine all the available data. The main atmospheric parameters were retrieved using the LBLRTM radiative transfer code, which was also utilised to study the impact of variability of the main molecular bands of O2, O3, and H2O, and to estimate their column densities. Results: In general, the extinction curve of Paranal appears to conform to those derived for other astronomical si...

  3. Report of boring made in the South of Cerro Largo district (Cerro Largo) 1977-1978

    International Nuclear Information System (INIS)

    The present work are within the framework and compiles the data obtained by means of the study of the perforations executed in the District Cerro Largo Sur of the detailed prospection of uranium minerals. This study was carried out by technicians of Geologic ex--Institute of Uruguay (IGU) - at the moment National Direction of Mining and Geology. (DINAMIGE). The works began at the beginning of 1977 and continued until 1978 July; The headquarters of the program of prospection of uranium was carried out by Ing. Hector Goso. In this report the conclusions drawn at the time of the detection of the works in the District already published, as well as the litologicos cuts of all the executed perforations are included

  4. Herpetofauna del Cerro Guiengola, Istmo de Tehuantepec, Oaxaca

    OpenAIRE

    Cintia Natalia Martín-Regalado; Rosa Ma. Gómez-Ugalde; Ma. Emma Cisneros-Palacios

    2011-01-01

    Este estudio se realizó en el Cerro Guiengola, Tehuantepec, Oaxaca, con el objetivo de contribuir al conocimiento de la herpetofauna en dicha área. Se obtuvieron 602 registros visuales y se recolectaron 103 ejemplares de anfibios y reptiles durante 60 días de trabajo de campo. Se enlistan 40 especies, pertenecientes a 33 géneros y 18 familias. Se determinó la distribución de la herpetofauna en el Cerro Guiengola por microhábitat, tipo de vegetación y altitud. Usando el método de Jaccard se el...

  5. Volcanismo y mineralización asociada en el área del cerro Tiporco, provincia de San Luis, Argentina

    Directory of Open Access Journals (Sweden)

    Ibañes, Oscar D.

    2011-12-01

    Full Text Available Abstract: Volcanism and associated mineralization in the Cerro Tiporco area, San Luis province, Argentina. The Tiporco area is located west of the Cerros del Rosario volcanic field and 66 km northeast of San Luis city. In the Santa Isabel-Córdoba quarry, a pyroclastic sequence has been recognized (Volcaniclastitas Lomitas lying on sedimentary rocks which belong to the Miocene Santa Isabel Formation. The stratigraphic arrangement indicates a Pliocene age. Within the sequence, upper and lower units may be distinguished, encompassing co-ignimbrite lithic breccias, surges and ignimbrite deposits. The volcanism in this area is characterized by initial explosive activity, with recurrent ignimbritic eruptions and phreatomagmatic episodes (surges, ending with the emplacement of domes and associated lava flows (Tiporco and Lomita. Both the pyroclastics and the lavas represent near-vent facies. A well defined NW-SE fault system controlled the emplacement of the volcanics. The associated mineralization consists of calcareous onyx and aragonite veins, calcite veinlets and travertine manifestations. The latter indicate a paleosurface consistent with the superficial levels of an epithermal system and very scarce erosion. In consequence, it is possible to infer the presence of metalliferous manifestations at depth as part of the same hydrothermal system.

  6. Hydrothermal minerals

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.

    observations and robot controlled sampling 82 Table 1. A compilation of reported metallogenesis along the IORS (Soure: Banerjee & Ray, 2003... 31°04′S/58°58′E 31°11′S/58°30′E 18. 10°N to 11°40′N Anda- Evidence of hydrothermal activity in the Andaman Back arc Basin comprising broken parts of Man chimney structures and rocks with disseminated and vein type metal sulphides. Water depth...

  7. Early mineralization at Cerro de Pasco (central Peru) revisited

    OpenAIRE

    Rottier, Bertrand; Casanova, Vincent; Fontboté, Lluis; Kouzmanov, Kalin; Alvarez, Hugo; Bendezú, Ronner

    2013-01-01

    The large Cerro de Pasco Cordilleran base metal deposit in central Peru is located on the eastern margin of a Middle Miocene diatreme-dome complex. A striking characteristic is the presence of a N-S trending massive funnel-shape pyrite-quartz replacement ore body that contains pyrrhotite pipes grading outwards to lead-zinc replacement bodies, along the eastern contact of the diatreme-dome complex. Earlier workers interpreted the pyrrhotite pipes as postdating the pyritequartz body. This study...

  8. The Cerro LOS Calvos and La Banderia chondrites

    Science.gov (United States)

    Whitlock, Randall; Lewis, Charles F.; Clark, James C.; Moore, Carleton B.

    1991-06-01

    The Cerro los Calvos meteorite is a single stone of 68.5 g found in the Nuevo Mercurio strewn field of Zacatecas, (Mexico). It is an unusual H4 chondrite. Its olivine (Fa12.5) and orthopyroxene (Fs 11.7, Wo 0.8) are reduced relative to typical H chondrites. The La Banderia meteorite of 54.3 g from the same vicinity is an LL5 chondrite of shock classification e.

  9. Intense Seismic Activity at Chiles and Cerro Negro Volcanoes on the Colombia-Ecuador Border

    Science.gov (United States)

    Torres, R. A.; Cadena, O.; Gomez, D.; Ruiz, M. C.; Prejean, S. G.; Lyons, J. J.; White, R. A.

    2015-12-01

    The region of Chiles and Cerro Negro volcanoes, located on the Colombian-Ecuadorian border, has experienced an ongoing seismic swarm beginning in Aug. 2013. Based on concern for local residents and authorities, a cooperative broadband monitoring network was installed by the Servicio Geológico Colombiano in Colombia and the Instituto Geofísico of the Escuela Politécnica Nacional in Ecuador. Since November 2013 more than 538,000 earthquakes were recorded; although since May 2015 the seismicity has decreased significantly to an average of 70 events per day. Three large earthquake swarms with increasing energy occurred in Aug.-Oct. 2013, March-May 2014, and Sept.-Dec. 2014. By the end of 2014, roughly 400 earthquakes greater than M 3 had occurred with a maximum rate of 8000 earthquakes per day. The largest earthquake was a 5.6 ML on Oct. 20, 2014. This event produced an InSAR coseismic deformation of ~23 cm (S. Ebmeier, personal communication). Most events are typical brittle failure volcano-tectonic (VT) earthquakes that are located in a cluster beneath the southern flank of Chiles volcano, with depths between 1.5 and 10 km. Although the great majority of earthquakes are VT, some low-frequency (LF, ~0.5 Hz) and very-low-frequency (VLF) events have occurred. Particle motion analysis suggests that the VLF source migrated with time. While a VLF on Oct. 15, 2014 was located south of Chiles volcano, near the InSAR source, the VLF registered on Feb. 14, 2015 was likely located very close to Chiles Volcano. We infer that magma intrusion and resulting fluid exsolution at depths greater than 5 km are driving seismicity in the Chiles-Cerro Negro region. However earthquakes are failing in a manner consistent with regional tectonics. Relative relocations reveal a structure consistent with mapped regional faults. Thus seismicity is likely controlled by an interaction of magmatic and tectonic processes. Because the regional stress field is highly compressional and the volcanoes

  10. Hydrothermal Biogeochemistry

    Science.gov (United States)

    Shock, E.; Havig, J.; Windman, T.; Meyer-Dombard, D.; Michaud, A.; Hartnett, H.

    2006-12-01

    Life in hot spring ecosystems is confronted with diverse challenges, and the responses to those challenges have dynamic biogeochemical consequences over narrow spatial and temporal scales. Within meters along hot spring outflow channels at Yellowstone, temperatures drop from boiling, and the near-boiling conditions of hot chemolithotrophic communities, to those that permit photosynthesis and on down to conditions where nematodes and insects graze on the edges of photosynthetic mats. Many major and trace element concentrations change only mildly in the water that flows through the entire ecosystem, while concentrations of other dissolved constituents (oxygen, sulfide, ammonia, total organic carbon) increase or decrease dramatically. Concentrations of metals and micronutrients range from toxic to inadequate for enzyme synthesis depending on the choice of hot spring. Precipitation of minerals may provide continuous growth of microbial niches, while dissolution and turbulent flow sweeps them away. Consequently, microbial communities change at the meter scale, and even more abruptly at the photosynthetic fringe. Isotopic compositions of carbon and nitrogen in microbial biomass reflect dramatic and continuous changes in metabolic strategies throughout the system. Chemical energy sources that support chemolithotrophic communities can persist at abundant or useless levels, or change dramatically owing to microbial activity. The rate of temporal change depends on the selection of hot spring systems for study. Some have changed little since our studies began in 1999. Others have shifted by two or more units in pH over several years, with corresponding changes in other chemical constituents. Some go through daily or seasonal desiccation cycles, and still others exhibit pulses of changing temperature (up to 40°C) within minutes. Taken together, hydrothermal ecosystems provide highly manageable opportunities for testing how biogeochemical processes respond to the scale of

  11. Geophysical Investigations of Magma Plumbing Systems at Cerro Negro Volcano, Nicaragua

    Science.gov (United States)

    MacQueen, Patricia Grace

    Cerro Negro near Leon, Nicaragua is a very young (163 years), relatively small basaltic cinder cone volcano that has been unusually active during its short lifespan (recurrence interval 6--7 years), presenting a significant hazard to nearby communities. Previous studies have raised several questions as to the proper classification of Cerro Negro and its relation to neighboring Las Pilas-El Hoyo volcano. Analysis of Bouguer gravity data collected at Cerro Negro has revealed connected positive density anomalies beneath Cerro Negro and Las Pilas-El Hoyo. These findings suggest that eruptions at Cerro Negro may be tapping a large magma reservoir beneath Las Pilas-El Hoyo, implying that Cerro Negro should be considered the newest vent on the Las Pilas-El Hoyo volcanic complex. As such, it is possible that the intensity of volcanic hazards at Cerro Negro may eventually increase in the future to resemble those pertaining to a stratovolcano. Keywords: Cerro Negro; Las Pilas-El Hoyo; Bouguer gravity; magmatic plumbing systems; potential fields; volcano.

  12. Characterization of pottery from Cerro de Las Ventanas, Zacatecas, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-del-Rio, H.; Mireles-Garcia, F. [Unidad Academica de Estudios Nucleares, UAZ, Zacatecas (Mexico); Mendez-Cardona, R.Y. [Unidad Academica de Antropologia, UAZ, Zacatecas (Mexico); Nicolas-Caretta, M. [INAH Delegacion Zacatecas (Mexico); Coordinacion de Ciencias Sociales y Humanidades, UASLP, Fracc. Talleres, SLP (Mexico); Speakman, R.J. [Museum Conservation Inst., Smithsonian Institution, Suitland, MD (United States); Glascock, M.D. [Research Reactor Center, Univ. of Missouri, Columbia, MO (United States)

    2009-09-15

    With the aim of classifying prehispanic pottery from Cerro de Las Ventanas site, Juchipila, Zacatecas, Mexico, instrumental neutron activation analysis (INAA) was used to analyze ceramic samples at the University of Missouri Research Reactor Center. Thirty-two chemical elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Two multivariate statistical methods, cluster analysis and principal component analysis, were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Mesoamerican ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Malpaso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de Las Ventanas represent a new and unique chemical fingerprint in the region. (orig.)

  13. Characterization of pottery from Cerro de Las Ventanas, Zacatecas, Mexico

    International Nuclear Information System (INIS)

    With the aim of classifying prehispanic pottery from Cerro de Las Ventanas site, Juchipila, Zacatecas, Mexico, instrumental neutron activation analysis (INAA) was used to analyze ceramic samples at the University of Missouri Research Reactor Center. Thirty-two chemical elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Two multivariate statistical methods, cluster analysis and principal component analysis, were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Mesoamerican ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Malpaso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de Las Ventanas represent a new and unique chemical fingerprint in the region. (orig.)

  14. Geothermal exploration technology. Annual report, 1978

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    Progress is reported on the following programs: electrical and electromagnetic computer modeling techniques; minicomputer for in-field processing of magnetotelluric data; superconducting thin-film gradiometer and magnetometers for geophysical applications; magnetotellurics with SQUID magnetometers; controlled-source electromagnetic system; geothermal seismic field system development; Klamath Basin geothermal resource and exploration technique evaluation; Mt. Hood geothermal resource evaluation; East Mesa seismic study; seismological studies at Cerro Prieto; self-potential studies at Cerro Prieto; resistivity studies at Cerro Prieto; magnetotelluric survey at Cerro Prieto; and precision gravity studies at Cerro Prieto. (MHR)

  15. Hydrothermal organic synthesis experiments

    Science.gov (United States)

    Shock, Everett L.

    1992-01-01

    Ways in which heat is useful in organic synthesis experiments are described, and experiments on the hydrothermal destruction and synthesis of organic compounds are discussed. It is pointed out that, if heat can overcome kinetic barriers to the formation of metastable states from reduced or oxidized starting materials, abiotic synthesis under hydrothermal conditions is a distinct possibility. However, carefully controlled experiments which replicate the descriptive variables of natural hydrothermal systems have not yet been conducted with the aim of testing the hypothesis of hydrothermal organic systems.

  16. Report of mortmorilloniticas clay in the Medina swamp (Cerro Largo district)

    International Nuclear Information System (INIS)

    This report describes the prospect ion work for the montmorillonitics clay in the region of Medina swamp in Cerro Largo district. The existence of new deposits was detected by cartography and geological study.

  17. Hidrogeologic and geophysical studies into Agro school Melo UTU Cerro Largo province

    International Nuclear Information System (INIS)

    The technical University UTU of Uruguay requested and Hidrogeologic study with the aim to analyze the factibility to discover underground stream waters which supply groundwaters into agro school Ing Agr. Alcides E Pintos Melo, Cerro Largo province.

  18. Evidence of recent deep magmatic activity at Cerro Bravo-Cerro Machín volcanic complex, central Colombia. Implications for future volcanic activity at Nevado del Ruiz, Cerro Machín and other volcanoes

    Science.gov (United States)

    Londono, John Makario

    2016-09-01

    In the last nine years (2007-2015), the Cerro Bravo-Cerro Machín volcanic complex (CBCMVC), located in central Colombia, has experienced many changes in volcanic activity. In particular at Nevado del Ruiz volcano (NRV), Cerro Machin volcano (CMV) and Cerro Bravo (CBV) volcano. The recent activity of NRV, as well as increasing seismic activity at other volcanic centers of the CBCMVC, were preceded by notable changes in various geophysical and geochemical parameters, that suggests renewed magmatic activity is occurring at the volcanic complex. The onset of this activity started with seismicity located west of the volcanic complex, followed by seismicity at CBV and CMV. Later in 2010, strong seismicity was observed at NRV, with two small eruptions in 2012. After that, seismicity has been observed intermittently at other volcanic centers such as Santa Isabel, Cerro España, Paramillo de Santa Rosa, Quindío and Tolima volcanoes, which persists until today. Local deformation was observed from 2007 at NRV, followed by possible regional deformation at various volcanic centers between 2011 and 2013. In 2008, an increase in CO2 and Radon in soil was observed at CBV, followed by a change in helium isotopes at CMV between 2009 and 2011. Moreover, SO2 showed an increase from 2010 at NRV, with values remaining high until the present. These observations suggest that renewed magmatic activity is currently occurring at CBCMVC. NRV shows changes in its activity that may be related to this new magmatic activity. NRV is currently exhibiting the most activity of any volcano in the CBCMVC, which may be due to it being the only open volcanic system at this time. This suggests that over the coming years, there is a high probability of new unrest or an increase in volcanic activity of other volcanoes of the CBCMVC.

  19. Uranium and Molybdenum extraction from a Cerro Solo deposit ore

    International Nuclear Information System (INIS)

    Cerro Solo, located in Chubut, Argentina, is a sandstone type uranium-molybdenum deposit. Good recovery of both elements can be achieved by acid leaching of the ore but the presence of molybdenum in pregnant liquors is an inconvenient to uranium separation and purification. A two steps process is developed. A selective alkaline leaching of the ore with sodium hydroxide allows separating and recovering of molybdenum and after solid-liquid separation, the ore is acid leached to recover uranium. Several samples averaging 0,2% uranium and 0,1% molybdenum with variable U/Mo ratio have been used and in both steps, leaching and oxidant reagents concentration, temperature and residence time in a stirred tank leaching have been studied. In alkaline leaching molybdenum recoveries greater than 96% are achieved, with 1% uranium extraction. In acid leaching up to 93% of the uranium is extracted and Mo/U ratio in solvent extraction feed is between 0,013 and 0,025. (author)

  20. Investigating the subsurface connection beneath Cerro Negro volcano and the El Hoyo Complex, Nicaragua

    Science.gov (United States)

    Venugopal, Swetha; Moune, Séverine; Williams-Jones, Glyn

    2016-10-01

    Cerro Negro, the youngest volcano along the Central American Volcanic Belt (CAVB), is a polygenetic cinder cone with relatively frequent basaltic eruptions. The neighbouring El Hoyo complex, of which Las Pilas is the dominant edifice, is a much larger and older complex with milder and less frequent eruptions. Previous studies have suggested a deep link beneath these two closely spaced volcanoes (McKnight, 1995; MacQueen, 2013). Melt inclusions were collected from various tephra samples in order to determine whether a connection exists and to delineate the features of this link. Major, volatile, and trace elemental compositions reveal a distinct geochemical continuum with Cerro Negro defining the primitive endmember and El Hoyo representing the evolved endmember. Magmatic conditions at the time of melt inclusion entrapment were estimated with major and volatile contents: 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for El Hoyo melts with an overall oxygen fugacity at the NNO buffer. Trace element contents are distinct and suggest Cerro Negro magmas fractionally crystallise while El Hoyo magmas are a mix between primitive Cerro Negro melts and residual and evolved El Hoyo magma. Modelling of end member compositions with alphaMELTS confirms the unique nature of El Hoyo magmas as resulting from incremental mixing between Cerro Negro and residual evolved magma at 4 km depth. Combining all available literature data, this study presents a model of the interconnected subsurface plumbing system. This model considers the modern day analogue of the Lemptégy cinder cones in Massif Central, France and incorporates structurally controlled dykes. The main implications of this study are the classification of Cerro Negro as the newest conduit within the El Hoyo Complex as well as the potential re-activation of the El Hoyo edifice.

  1. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  2. Spatial and Temporal Variations of Diffuse Carbon Dioxide Emission From Cerro Negro Volcano, Nicaragua, Central America

    Science.gov (United States)

    Galindo, I.; Melián, G.; Salazar, J.; Hernández, P.; Pérez, N.; Strauch, W.

    2002-12-01

    Cerro Negro is a basaltic cinder cone that has erupted 22 times since its birth in 1850. It is part of a group of four young cinder cones NW of Las Pilas volcano. Cerro Negro's most recent activity was on 5 August 1999 when erupted ash clouds at heights of about 7 km. In December 1999, three months after the eruption, a surface flux survey was carried out at Cerro Negro. Soil CO2 efflux values ranged from 0.5 to 35,000 gm-2d-1 and the total diffuse CO2 output was estimated about 2,800 td-1. Soil temperature reached values above 300°C on the NE flank of the volcano (Salazar et al., 2001). The goal of this study is to evaluate how diffuse CO2 degassing rate at Cerro Negro changes through its eruptive cycle and improve its volcano monitoring program. From Febraury 26 to March 11, 2002, a new diffuse CO2 degassing survey was carried out at Cerro Negro. Sampling distribution was similar to the 1999 survey covering an area of (0.6 Km2). Diffuse CO2 emission rates for the 2002 survey showed a wide range of values from 0.3 to 26,500 gm-2d-1. Most of the study area showed soil CO2 efflux values above 110 gm-2d-1, and the highest CO2 efflux rate was observed in the Northeastern sector of the crater. Soil temperature was also recorded during the survey, and the highest value was observed in the NE flank reaching temperatures up to 450°C. The total diffuse CO2 output for the 2002 survey was estimated about 280 td-1, which is one order of magnitude lower than the estimated for the 1999 survey. This significant temporal variation on diffuse CO2 emission rate seems to be clearly related to the eruptive cycle of Cerro Negro. If we consider that the statistically eruptive cycle for Cerro Negro is less than a decade, it is obvious that the December 1999 survey was performed within its post-eruptive period, while the recent 2002 survey was carried out two years and a half after the most recent eruption of Cerro Negro, within its inter-eruptive period. These results suggest that

  3. Catalytic Hydrothermal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  4. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of Central Chile

    OpenAIRE

    Wes Hildreth; Brad Singer; Estanislao Godoy; Francisco Munizaga

    1998-01-01

    ABSTRACT Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km³ edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.La edad y formación del cerro Campanario, un estratovolcán má...

  5. Indios y blancos en la ciudad minera: Cerro de Pasco en el siglo XIX1

    OpenAIRE

    Contreras, Carlos

    2014-01-01

    En este artículo se presenta una descripción de las condiciones de vida, materiales y culturales en Cerro de Pasco durante el siglo pasado, cuando era una de las principales ciudades de la sierra peruana, tanto en lo económico como en lo demográfico.El autor discute las características de la estructura social de Cerro de Pasco, recalcando la yuxtaposición de elementos económicos y étnico-culturales y el tipo de relaciones sociales prevalecientes. Luego describe las características y condicion...

  6. The Lassen hydrothermal system

    Science.gov (United States)

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  7. Complexing and hydrothermal ore deposition

    CERN Document Server

    Helgeson, Harold C

    1964-01-01

    Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

  8. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica;

    2014-01-01

    into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

  9. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, Dragan

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of wat

  10. Evolución petrotectónica del distrito minero Cerro Áspero y modelo de emplazamiento de los depósitos wolframíferos, Córdoba Petrotectonic evolution of the Cerro Aspero mining district and emplacement model of the wolframiferous deposits, Córdoba

    Directory of Open Access Journals (Sweden)

    D. Mutti

    2005-03-01

    located in the eastern part of the Sierra de Comechingones. The region was affected by polimetamorphism during the Pampean and Famatinian cycles. At least two events of simple shearing (D3 and D4 and penetrative structures (S2, S3 and S4 were developed, favouring the anorogenic intrusion of Cerro Aspero batholith since late Devonian. This magmatic event was followed by a reactivation of deformation structures and circulation of hydrothermal fluids through rocks underlying a massive amphibolite level belonging to La Aguada formation, which mainly acted as an impermeable barrier in the area. A maximum stress s1 directed 330º promoted the development of mineralized systems following the fracturing pattern of Riedel's model, and also the development of a principal mineralized path related to a simple dextral shear belt, 285º in direction (S5. During the evolution of the magmatic-hydrothermal system, a high number of stages of fracturing and opening along rocks were registered, with sealing of cavities by mechanism of crack seal and pressure dissolution. By these mechanisms, fibrous habit silica was precipitated and metallic elements were concentrated, under a traction regime and a pore fluid pressure estimated in 195 MPa. The age of one of the mineralizing stages was determined in 343,8 ± 10,8 Ma through K/Ar dating in muscovite.

  11. Hydrothermal synthesis of hydroxyapatite

    Energy Technology Data Exchange (ETDEWEB)

    Earl, J S; Wood, D J; Milne, S J [Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (United Kingdom)

    2006-02-22

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO{sub 3}){sub 2}{center_dot}4H{sub 2}O and (NH{sub 4}){sub 2}HPO{sub 4} with distilled water, in a hydrothermal reactor at 200 deg. C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO{sub 4}). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  12. Hydrothermal conversion of biomass

    OpenAIRE

    Knezevic, Dragan

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of water and high energy consumption that it requires can be avoided. The main focus of this work was HTC process aiming at production of transportation fuel intermediates. For this study, a new experime...

  13. Dynamics of diffuse CO2 emission and eruptive cycle at Cerro Negro volcano, Nicaragua

    Science.gov (United States)

    Rodriguez, F.; Melian, G.; Barrancos, J.; Padilla, G.; Diaz, M.; Calvo, D.; Nolasco, D.; Perez, N.; Hernandez Perez, P. A.; Ibarra, M.; Strauch, W.; Muñoz, A.

    2009-12-01

    Cerro Negro volcano is the youngest of a group of cinder cones NW of Las Pilas at 25 km from León (Nicaragua) with 685 meters above sea level and one of the most active volcanoes of Nicaragua. It has erupted 21 times since its birth in 1850, with an eruptive cycle about 7-8 years. Since the last eruption, occurred on 5 August 1999, with erupted lava flows and ash clouds together with gas emissions, a research collaboration program between INETER and ITER was established for monitoring diffuse CO2 emissions from Cerro Negro. Since then, ten CO2 surface efflux surveys have been undertaken covering an area of 0,6 km2, in order to evaluate the spatial and temporal variations of CO2 degassing rate in relation with the eruptive cycle of Cerro Negro. Soil CO2 efflux measurements were performed always by means of a portable NDIR sensor according to the accumulation chamber method. A total diffuse CO2 emission output of 1869 t d-1 was estimated for the 1999 survey; just 3 months after the 1999 eruption which can be considered within the post-eruptive phase. For the 2002 and 2003 surveys, considered within the inter-eruptive phase, a clear decreasing tendency on the total diffuse CO2 output was observed, with estimates of 431 and 84 t d-1, respectively. However, during the 2004 a slightly increase on the total diffuse CO2 emission was observed, reaching up to 256 t d-1. The observed relatively increase was addressed to the occurrence of a seismic swarm at Cerro Negro during the survey. The yearly surveys performed at Cerro Negro from 2005 until present, have always shown background levels of CO2 emission, with 68, 38, 45, 10 and 12 t d-1, respectively. The temporal evolution of the diffuse CO2 emissions from Cerro Negro will allow us to determine the typical range of seasonal or other transient departures from its normal or “baseline” behaviour and its relation with the eruptive cycle.

  14. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of central Chile

    Science.gov (United States)

    Hildreth, W.; Singer, B.; Godoy, E.; Munizaga, F.

    1998-01-01

    Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km3 edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.

  15. New mammalian records in the Parque Nacional Cerros de Amotape, northwestern Peru

    OpenAIRE

    Cindy M. Hurtado; Víctor Pacheco

    2015-01-01

    The Pacific Tropical Rainforest and Equatorial Dry Forest are found only in southern Ecuador and northern Peru, and are among the most poorly known ecosystems of South America. Even though these forests are protected in Parque Nacional Cerros de Amotape (PNCA), they are threatened by fragmentation because of farming and agriculture. The aim of this study was to determine the medium and large mammalian species richness, using transect census, camera trapping, and specimen bone collection. Nine...

  16. Study of the atmospheric conditions at Cerro Armazones using astronomical data

    OpenAIRE

    Lakicevic, Masha; Kimeswenger, Stefan; Noll, Stefan; Kausch, Wolfgang; Unterguggenberger, Stefanie; Kerber, Florian

    2016-01-01

    Aims: We studied the precipitable water vapour (PWV) content near Cerro Armazones and discuss the potential use of our technique of modelling the telluric absorbtion lines for the investigation of other molecular layers. The site is designated for the European Extremely Large Telescope (E-ELT) and the nearby planned site for the Cherenkov Telescope Array (CTA). Methods: Spectroscopic data from the Bochum Echelle Spectroscopic Observer (BESO) instrument were investigated by using line-by-line ...

  17. El bronce final y la Edad del Hierro en "Cerro del Berrueco" (Ávila-Salamanca

    Directory of Open Access Journals (Sweden)

    J. Francisco FABIÁN GARCÍA

    2009-10-01

    Full Text Available El Cerro del Berrueco es un monte-isla enclavado en las inmediaciones del Sistema Central y, más concretamente, de las Sierras de Gredos y Béjar, en el sector Sur-Occidental de la Meseta Norte. Corresponde una parte de él a la provincia de Avila y otra, más extensa, a la de Salamanca.

  18. Hydrothermal Liquefaction of Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international

  19. Recycling of water, carbon, and sulfur during subduction of serpentinites: A stable isotope study of Cerro del Almirez, Spain

    Science.gov (United States)

    Alt, Jeffrey C.; Garrido, Carlos J.; Shanks, Wayne C.; Turchyn, Alexandra; Padrón-Navarta, José Alberto; López Sánchez-Vizcaíno, Vicente; Gómez Pugnaire, María Teresa; Marchesi, Claudio

    2012-01-01

    We use the concentrations and isotope compositions of water, carbon, and sulfur in serpentinites and their dehydration products to trace the cycling of volatiles during subduction. Antigorite serpentinites from the Cerro del Almirez complex, Spain, contain 9–12 wt.% H2O and 910 ± 730 ppm sulfur, and have bulk δ18O values of 8.6 ± 0.4‰, δD = − 54 ± 5‰, and δ34S = 5.0‰, consistent with serpentinization at temperatures of ~ 200 °C by seawater hydrothermal fluids in a seafloor setting. The serpentinites were dehydrated to chlorite–harzburgite (olivine + orthopyroxene + chlorite) at 700 °C and 1.6–1.9 GPa during subduction metamorphism, resulting in loss of water, and sulfur. The chlorite–harzburgites contain 5.7 ± 1.9 wt.% H2O, and have bulk δ18O = 8.0 ± 0.9‰, and δD = − 77 ± 11‰. The rocks contain 650 ± 620 ppm sulfur having δ34S = 1.2‰. Dehydration of serpentinite resulted in loss of 5 wt.% H2O having δ18O = 8–10‰ and δD = − 27 to − 65‰, and loss of 260 ppm sulfur as sulfate, having δ34S = 14.5‰. The contents and δ13C of total carbon in the two rock types overlap, with a broad trend of decreasing carbon contents and δ13C from ~ 1300 to 200 ppm and − 9.6 to − 20.2‰. This reflects mixing between reduced carbon in the rocks (210 ppm, δ13C ≈ − 26‰) and seawater-derived carbonate (δ13C ≈ − 1‰). Our results indicate: 1) Serpentinized oceanic peridotites carry significant amounts of isotopically fractionated water, carbon and sulfur into subduction zones; 2) Subduction of serpentinites to high P and T results in loss of water, and sulfur, which can induce melting and contribute to 18O, D, and 34S enrichments and oxidation of the sub-arc mantle wedge; and 3) Isotopically fractionated water, carbon, and sulfur in serpentinite dehydration products are recycled deeper into the mantle where they can contribute to isotope heterogeneities and may be significant for volatile budgets of the deep Earth.

  20. Burn Severities, Fire Intensities, and Impacts to Major Vegation Types from the Cerro Grande Fire

    International Nuclear Information System (INIS)

    The Cerro Grande Fire resulted in major impacts and changes to the ecosystems that were burned. To partially document these effects, we estimated the acreage of major vegetation types that were burned at selected burn severity levels and fire intensity levels. To accomplish this, we adopted independently developed burn severity and fire intensity maps, in combination with a land cover map developed for habitat management purposes, as a basis for the analysis. To provide a measure of confidence in the acreage estimates, the accuracies of these maps were also assessed. In addition, two other maps of comparable quality were assessed for accuracy: one that was developed for mapping fuel risk and a second map that resulted from a preliminary application of an evolutionary computation software system, called GENIE. According to the burn severity map and the fire intensity map, the Cerro Grande Fire is estimated to have covered 42,885.4 acres and 42,854.7 acres, respectively. Of this, 57.0 percent was burned at low severity and 34.7 percent was burned at high severity. Similarly, 40.0 percent of the Cerro Grande Fire burned at high fire intensity, greater than 70 percent mortality, while 33.1 percent burned at moderately low intensity, 10 to 40 percent mortality. The most frequently burned cover types over the entire Cerro Grande Fire were ponderosa pine forest and mixed conifer forest, at approximately 43 percent each. However, portions of the fire that burned on Los Alamos National Laboratory (LANL) property were predominantly in ponderosa pine forests, whereas the Cerro Grande Fire burned primarily in mixed conifer forests on lands managed by other agencies. Some of the polygons of burn severities and fire intensities were extensive. The two largest burn severity polygons were 10,111 acres and 10,903 acres and these were burned at low severity. The next two largest polygons were 8999 acres (14 square miles) and 1551 acres (2.4 square miles) and both of these polygons

  1. El recorrido al Cerro Gordo y el ritual tepehuano de las ofrendas en los cerros de la comunidad de San Bernardino de Milpillas

    Directory of Open Access Journals (Sweden)

    Chantal CRAMAUSSEL

    2014-01-01

    Full Text Available El ritual de las ofrendas es una ceremonia propiciatoria de la lluvia que se efectúa al terminar la estación seca en los cerros más altos de la comunidad de San Bernardino de Milpillas Chico, en la Sierra Tepehuana del estado de Durango. A esos rituales distintos de los cató- licos que forman parte del ciclo anual de costumbre concurren las autoridades civiles, los curanderos y miembros del Consejo de ancianos. Es un momento muy importante en el que se refuerza la cohesión de los tepehuanos que tienen un patrón de asentamiento muy disperso, como los demás grupos del norte, pero sus rituales presentan también similitudes con los mesoamericanos.

  2. Reconnaissance study of late quaternary faulting along cerro GoDen fault zone, western Puerto Rico

    Science.gov (United States)

    Mann, P.; Prentice, C.S.; Hippolyte, J.-C.; Grindlay, N.R.; Abrams, L.J.; Lao-Davila, D.

    2005-01-01

    The Cerro GoDen fault zone is associated with a curvilinear, continuous, and prominent topographic lineament in western Puerto Rico. The fault varies in strike from northwest to west. In its westernmost section, the fault is ???500 m south of an abrupt, curvilinear mountain front separating the 270- to 361-m-high La CaDena De San Francisco range from the Rio A??asco alluvial valley. The Quaternary fault of the A??asco Valley is in alignment with the bedrock fault mapped by D. McIntyre (1971) in the Central La Plata quadrangle sheet east of A??asco Valley. Previous workers have postulated that the Cerro GoDen fault zone continues southeast from the A??asco Valley and merges with the Great Southern Puerto Rico fault zone of south-central Puerto Rico. West of the A??asco Valley, the fault continues offshore into the Mona Passage (Caribbean Sea) where it is characterized by offsets of seafloor sediments estimated to be of late Quaternary age. Using both 1:18,500 scale air photographs taken in 1936 and 1:40,000 scale photographs taken by the U.S. Department of Agriculture in 1986, we iDentified geomorphic features suggestive of Quaternary fault movement in the A??asco Valley, including aligned and Deflected drainages, apparently offset terrace risers, and mountain-facing scarps. Many of these features suggest right-lateral displacement. Mapping of Paleogene bedrock units in the uplifted La CaDena range adjacent to the Cerro GoDen fault zone reveals the main tectonic events that have culminated in late Quaternary normal-oblique displacement across the Cerro GoDen fault. Cretaceous to Eocene rocks of the La CaDena range exhibit large folds with wavelengths of several kms. The orientation of folds and analysis of fault striations within the folds indicate that the folds formed by northeast-southwest shorTening in present-day geographic coordinates. The age of Deformation is well constrained as late Eocene-early Oligocene by an angular unconformity separating folDed, Deep

  3. Archaeological fieldwork in the Bronze Age site of Cerro de la Encina (Monachil, Granada

    Directory of Open Access Journals (Sweden)

    Aranda Jiménez, Gonzalo

    2005-06-01

    Full Text Available New archaeological fieldwork has been carried out from November 2003 to May 2004 in the Bronze Age site of Cerro de la Encina, due to the interest of the regional government of Andalusia in displaying the settlement for visitors. The aim of this fieldwork has been the systematic excavation of a large settlement area partially known thanks to the excavations developed at the beginning of 1980s. A first toccupation period belonging to the Argaric Culture has been documented, highlighting specially the funerary ritual characterized by individual inhumations located below dwellings. After a gap in the occupation of the settlement a new social group belonging to the Late Bronze Age Culture of Southeast of Spain inhabits the Cerro de la Encina.

    El interés de la Consejería de Cultura de la Junta de Andalucía por la musealización del yacimiento del Cerro de la Encina ha motivado el desarrollo de nuevas investigaciones arqueológicas cuya primera fase se ha desarrollado entre Noviembre de 2003 y Mayo de 2004. Los trabajos han consistido en la excavación sistemática de un área de poblado de grandes dimensiones parcialmente conocida por las investigaciones realizadas a principios de los años 80. Los resultados han sido del máximo interés documentándose un primer momento de ocupación perteneciente a la Cultura de El Argar en el que destaca su espectacular registro funerario integrado dentro de las áreas de habitación. Tras un periodo de abandono del yacimiento se produce una nueva ocupación correspondiente a una comunidad del Bronce Final del Sureste.

  4. The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au-Ag deposit in the Cerro Negro district, Deseado Massif, Patagonia, Argentina

    Science.gov (United States)

    Vidal, Conrado Permuy; Guido, Diego M.; Jovic, Sebastián M.; Bodnar, Robert J.; Moncada, Daniel; Melgarejo, Joan Carles; Hames, Willis

    2016-08-01

    The Cerro Negro district, within the Argentinian Deseado Massif province, has become one of the most significant recent epithermal discoveries, with estimated reserves plus resources of ˜6.7 Moz Au equivalent. The Marianas-San Marcos vein system contains about 70 % of the Au-Ag resources in the district. Mineralization consists of Upper Jurassic (155 Ma) epithermal Au- and Ag-rich veins of low to intermediate sulfidation style, hosted in and genetically related to Jurassic intermediate composition volcanic rocks (159-156 Ma). Veins have a complex infill history, represented by ten stages with clear crosscutting relationships that can be summarized in four main episodes: a low volume, metal-rich initial episode (E1), an extended banded quartz episode with minor mineralization (E2), a barren waning stage episode (E3), and a silver-rich late tectonic-hydrothermal episode (E4). The first three episodes are interpreted to have formed at the same time and probably from fluids of similar composition: a 290-230 °C fluid dominated by meteoric and volcanic waters (-3‰ to -0‰ δ18Owater), with <3 % NaCl equivalent salinity and with a magmatic source of sulfur (-1 to -2 ‰ δ34Swater). Metal was mainly precipitated at the beginning of vein formation (episode 1) due to a combination of boiling at ˜600 to 800 m below the paleowater table, and associated mixing/cooling processes, as evidenced by sulfide-rich bands showing crustiform-colloform quartz, adularia, and chlorite-smectite banding. During episodes 2 and 3, metal contents progressively decrease during continuing boiling conditions, and veins were filled by quartz and calcite during waning stages of the hydrothermal system, and the influx of bicarbonate waters (-6 to -8.5 ‰ δ18Owater). Hydrothermal alteration is characterized by proximal illite, adularia, and silica zone with chlorite and minor epidote, intermediate interlayered illite-smectite and a distal chlorite halo. This assemblage is in agreement with

  5. The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au-Ag deposit in the Cerro Negro district, Deseado Massif, Patagonia, Argentina

    Science.gov (United States)

    Vidal, Conrado Permuy; Guido, Diego M.; Jovic, Sebastián M.; Bodnar, Robert J.; Moncada, Daniel; Melgarejo, Joan Carles; Hames, Willis

    2016-01-01

    The Cerro Negro district, within the Argentinian Deseado Massif province, has become one of the most significant recent epithermal discoveries, with estimated reserves plus resources of ˜6.7 Moz Au equivalent. The Marianas-San Marcos vein system contains about 70 % of the Au-Ag resources in the district. Mineralization consists of Upper Jurassic (155 Ma) epithermal Au- and Ag-rich veins of low to intermediate sulfidation style, hosted in and genetically related to Jurassic intermediate composition volcanic rocks (159-156 Ma). Veins have a complex infill history, represented by ten stages with clear crosscutting relationships that can be summarized in four main episodes: a low volume, metal-rich initial episode (E1), an extended banded quartz episode with minor mineralization (E2), a barren waning stage episode (E3), and a silver-rich late tectonic-hydrothermal episode (E4). The first three episodes are interpreted to have formed at the same time and probably from fluids of similar composition: a 290-230 °C fluid dominated by meteoric and volcanic waters (-3‰ to -0‰ δ18Owater), with <3 % NaCl equivalent salinity and with a magmatic source of sulfur (-1 to -2 ‰ δ34Swater). Metal was mainly precipitated at the beginning of vein formation (episode 1) due to a combination of boiling at ˜600 to 800 m below the paleowater table, and associated mixing/cooling processes, as evidenced by sulfide-rich bands showing crustiform-colloform quartz, adularia, and chlorite-smectite banding. During episodes 2 and 3, metal contents progressively decrease during continuing boiling conditions, and veins were filled by quartz and calcite during waning stages of the hydrothermal system, and the influx of bicarbonate waters (-6 to -8.5 ‰ δ18Owater). Hydrothermal alteration is characterized by proximal illite, adularia, and silica zone with chlorite and minor epidote, intermediate interlayered illite-smectite and a distal chlorite halo. This assemblage is in agreement with

  6. Microestructuras de deformación en rocas granulíticas, Cerro La Crespa, Tandilia, Provincia de Buenos Aires

    OpenAIRE

    Lucrecia Jorgensen; María C. Frisicale; Luis V Dimieri

    2008-01-01

    El cerro La Crespa, localizado un kilómetro al sur de la megacizalla de Azul, integra las sierras de Azul, las cuales componen parte del Sistema de Tandilia. El presente trabajo trata sobre el estudio petrográfico-microestructural, donde se determina la composición modal y arreglos texturales a escala de grano y una primera caracterización geoquímica de rocas granulíticas aflorantes en el sector NO del cerro La Crespa. A partir de tales análisis, se intenta dilucidar los mecanismos de deforma...

  7. Textures, mineralogy and mineral chemistry of the Cerro de Maimón deposit (Dominican Republic): Weathering and metallurgical implications

    OpenAIRE

    Andreu Tàrrega, Eloi

    2010-01-01

    The aim of this thesis is to study the textures mineralogy, and mineral chemistry of the sulfide and oxide ores from the Cerro de Maimón deposit (a Cu-(Zn)-Au-Ag VMS deposit) in the Dominican Republic. The samples studied were collected by the author in June 2009 as part of an internship done at the Cerro de Maimón mine. The deposit is hosted in Maimón Formation, a metamorphosed and deformed volcanogenic bimodal suite formed in the first stages of the development of the primitive Caribbean is...

  8. SITE CHARACTERISTICS OF THE SUMMIT OF CERRO CHAJNANTOR AT THE 5640 M ALTITUDE

    Directory of Open Access Journals (Sweden)

    K. Motohara

    2011-01-01

    Full Text Available Instituto de Astronomía de la Universidad de Tokio está promoviendo el proyecto TAO (University of Tokyo Atacama Observatory; Yoshii et al. 2010 para construir un telescopio infrarrojo en la cima de Cerro Chajnantor (altitud 5640 m en el desierto de Atacama en el Norte de Chile. Para la evaluación de las características del sitio, primero se realizó el monitoreo del tiempo atmosférico, la emisividad de nubes y el seeing durante 2006. 2007. La fracción despejada fue alta (>80% y la mediana del seeing en la banda V fue de tan solo 0."69. Un telescopio explorador de 1 m llamado miniTAO fue instalado y comenzó a observar en 2009. Con éste se han obtenido imágenes satisfactorias de Paα de hidrógeno 1.875 μm como también imágenes de 30.40 μm por primera vez desde un telescopio en tierra. Estos resultados demuestran que la cima de Cerro Chajnantor es uno de los mejores sitios para la astronomía infrarroja en la Tierra.

  9. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  10. Elemental analysis of pottery from Cerro de las Ventanas, Zacatecas, by INAA

    Energy Technology Data Exchange (ETDEWEB)

    Lopez del Rio, H.; Mireles G, F. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Calle Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Mendez C, R. Y. [Universidad Autonoma de Zacatecas, Unidad Academica de Antropologia, Apdo. Postal 555 Suc. C, Zacatecas (Mexico); Nicolas C, M. [Universidad Autonoma de San Luis Potosi, Coordinacion de Ciencias Sociales y Humanidades, Av. Industrias 101-A, Fracc. Talleres, 78494 San Luis Potosi (Mexico); Speakman, R. J. [Museum Conservation Institute, Smithsonian Institution, Suitland, 20746 Maryland (United States); Glascock, M. D. [Reactor Center, University of Missouri, Columbia, 65211 Missouri (United States)

    2009-10-15

    Fifteen ceramic fragments samples from Cerro de las Ventanas site, Zacatecas, were analyzed by instrumental neutron activation analysis. Thirty-two elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Cluster analysis and principal component analysis were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Meso american ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Mal paso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de las Ventanas represent a new and unique chemical fingerprint in the region. (Author)

  11. A first shallow firn-core record from Glaciar La Ollada, Cerro Mercedario, central Argentine Andes

    Science.gov (United States)

    Bolius, David; Schwikowski, Margit; Jenk, Theo; Gäggeler, Heinz W.; Casassa, Gino; Rivera, Andrés

    In January 2003, shallow firn cores were recovered from Glaciar Esmeralda on Cerro del Plomo (33°14‧ S, 70°13‧ W; 5300 ma.s.l.), central Chile, and from Glaciar La Ollada on Cerro Mercedario (31°58‧ S, 70°07‧ W; 6070 ma.s.l.), Argentina, in order to find a suitable archive for paleoclimate reconstruction in a region strongly influenced by the El Niño-Southern Oscillation. In the area between 28° S and 35° S, the amount of winter precipitation is significantly correlated to the Southern Oscillation Index, with higher values during El Niño years. Glaciochemical analysis indicates that the paleo-record at Glaciar La Ollada is well preserved, whereas at Glaciar Esmeralda the record is strongly influenced by meltwater formation and percolation. A preliminary dating of the Mercedario core by annual-layer counting results in a time-span of 17 years (1986-2002), yielding an average annual net accumulation of 0.45 m w.e.

  12. Optical Sky Brightness at Cerro Tololo Inter-American Observatory from 1992 to 2006

    CERN Document Server

    Krisciunas, Kevin; Sanhueza, Pedro; Schwarz, Hugo E; Semler, Dylan R; Suntzeff, Nicholas B; Vera, Sergio

    2007-01-01

    We present optical UBVRI sky brightness measures from 1992 through 2006. The data are based on CCD imagery obtained with the CTIO 0.9-m, 1.3-m, and 1.5-m telescopes. The B- and V-band data are in reasonable agreement with measurements previously made at Mauna Kea, though on the basis of a small number of images per year there are discrepancies for the years 1992 through 1994. Our CCD-based data are not significantly different than values obtained at Cerro Paranal. We find that the yearly averages of V-band sky brightness are best correlated with the 10.7-cm solar flux taken 5 days prior to the sky brightness measures. This implies an average speed of 350 km/sec for the solar wind. While we can measure an enhancement of the night sky levels over La Serena 10 degrees above the horizon, at elevation angles above 45 degrees we find no evidence that the night sky brightness at Cerro Tololo is affected by artificial light of nearby towns and cities.

  13. Elemental analysis of pottery from Cerro de las Ventanas, Zacatecas, by INAA

    International Nuclear Information System (INIS)

    Fifteen ceramic fragments samples from Cerro de las Ventanas site, Zacatecas, were analyzed by instrumental neutron activation analysis. Thirty-two elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Cluster analysis and principal component analysis were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Meso american ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Mal paso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de las Ventanas represent a new and unique chemical fingerprint in the region. (Author)

  14. Comments on the Neolithic collective burial at Cerro Virtud (Cuevas de Almanzora, Almería

    Directory of Open Access Journals (Sweden)

    Montero Ruiz, Ignacio

    1999-06-01

    Full Text Available Different results from the collective burial of Cerro Virtud confirm the importance of this settlement for our understanding of the Neolithic in southeastern Iberian Peninsula. The site has both open air settlement and collective burial. It also has the first evidence of Neolithic metalworking in Western Europe. The article focuses on the collective burial. Anthropological analysis shows eleven individuals, some of them in primary positions and others displaced. A radiocarbon sequence of the burial is also pesented. The burial chronology is in the first half of V millennium cal EC.

    El estudio del enterramiento colectivo de Cerro Virtud confirma la importancia de este yacimiento en el desarrollo cronológico y cultural del Neolítico Medio en el Sureste de la Península Ibérica. Además de tratarse de un poblado al aire libre y contar con la primera evidencia de actividad metalúrgica de época neolítica documentada en el Occidente de Europa, presenta un enterramiento colectivo sobre el que se centra este artículo. Los resultados del análisis antropológico indican la presencia de, al menos, once individuos inhumados, unos en posición primaria y otros desplazados. Se aportan las nuevas dataciones de carbono 14 que sitúan cronológicamente al enterramiento en la primera mitad del V milenio cal AC.

  15. Models of Metabolic Community Structure in Martian Habitable Environments: Constraints from a Terrestrial Analog Acid-Sulfate Fumarole Environment, Cerro Negro Volcano, Nicaragua

    Science.gov (United States)

    Rogers, K. L.; McCollom, T. M.; Hynek, B. M.

    2014-12-01

    Microbial habitability in extreme environments on Earth is described by microscale geochemical conditions that constrain metabolic niches in concert with long-term habitat stability that is governed by dynamic geologic processes. Using terrestrial analogs to identify habitable martian environments requires correlating microscale geochemical constraints with reconstructions of past martian environments that are based on global-scale observations. While past martian environments can be characterized by primary parameters (e.g. pH, redox, mineralogy, thermal history), microbial habitability on Earth is a complex function of both primary and derived parameters (e.g. metabolic reaction energetics, chemical & thermal gradients, flow dynamics). In recent years we have been investigating acid-sulfate fumaroles at the Mars analog site, Cerro Negro Volcano, Nicaragua, where habitability is constrained by steep thermal gradients, spatially- and temporally-variable vent dynamics, and limited water and nutrient availability. The most common niche identified thus far is found in fumaroles that host mixed photosynthetic and chemosynthetic endolithic microbial communities. One such endolith is dominated by acidic red algae (Cyanidiales), aerobic bacterial heterotrophs (Ktedonobacteria), and archaeal thermoacidophiles (Hyperthermus, Caldisphaera, and Thermofilum). An analysis of the metabolic structure suggests that primary production by the red algae supports the growth of heterotrophic thermoacidophiles. Diversification among the chemoheterotrophs with respect to temperature and oxygen tolerance suggests community adaptation to environmental gradients or variable venting dynamics. Furthermore, individual cells within the endolith are silica-encrusted, providing the possibility for biosignature formation and preservation. Putative hydrothermal environments on early Mars with similar conditions could have supported endolithic communities with comparable metabolic strategies. Even

  16. Hydrothermal systems and volcano geochemistry

    Science.gov (United States)

    Fournier, R.O.

    2007-01-01

    The upward intrusion of magma from deeper to shallower levels beneath volcanoes obviously plays an important role in their surface deformation. This chapter will examine less obvious roles that hydrothermal processes might play in volcanic deformation. Emphasis will be placed on the effect that the transition from brittle to plastic behavior of rocks is likely to have on magma degassing and hydrothermal processes, and on the likely chemical variations in brine and gas compositions that occur as a result of movement of aqueous-rich fluids from plastic into brittle rock at different depths. To a great extent, the model of hydrothermal processes in sub-volcanic systems that is presented here is inferential, based in part on information obtained from deep drilling for geothermal resources, and in part on the study of ore deposits that are thought to have formed in volcanic and shallow plutonic environments.

  17. Hydrothermal Synthesis of Metal Silicates

    Institute of Scientific and Technical Information of China (English)

    Lii Kwang-Hwa

    2004-01-01

    Organically templated metal phosphates have been extensively studied because of interesting structural chemistry and potential applications in catalysis. However, in most cases the organic templates cannot be removed without collapse of the frameworks. This is in contrast to the high thermal stability and extensive applications of zeolites in refinery and petrochemical processes.Therefore, studies have been directed to the synthesis of transition metal silicates to produce more stable frameworks. Our synthetic methods are twofold, namely mild hydrothermal reactions in Teflon-lined autoclaves at 100-200 ℃ using organic amines as templates and high-temperature,high-pressure hydrothermal reactions in gold ampoules contained in a high-pressure reaction vessel at ca. 550 ℃ and 150 Mpa using alkali metal cations as templates. In this presentation I will report the high-temperature, high-pressure hydrothermal synthesis, crystal structures, and solid-state NMR spectroscopy of a number of new silicates of indium, uranium, and transition metals.

  18. Hydrothermalism in the Mediterranean Sea

    Science.gov (United States)

    Dando, P. R.; Stüben, D.; Varnavas, S. P.

    1999-08-01

    Hydrothermalism in the Mediterranean Sea results from the collision of the African and European plates, with the subduction of the oceanic part of the African plate below Europe. High heat flows in the resulting volcanic arcs and back-arc extensional areas have set-up hydrothermal convection systems. Most of the known hydrothermal sites are in shallow coastal waters, <200 m depth, so that much of the reported fluid venting is of the gasohydrothermal type. The hydrothermal liquids are of varying salinities, both because of phase separation as a result of seawater boiling at the low pressures and because of significant inputs of rainfall into the hydrothermal reservoirs at some sites. The major component of the vented gas is carbon dioxide, with significant quantities of sulphur dioxide, hydrogen sulphide, methane and hydrogen also being released. Acid leaching of the underlying rocks leads to the mobilisation of heavy metals, many of which are deposited sub-surface although there is a conspicuous enrichment of metals in surficial sediments in venting areas. Massive polymetalic sulphides have been reported from some sites. No extant vent-specific fauna have been described from Mediterranean sites. There is a reduced diversity of fauna within the sediments at the vents. In contrast, a high diversity of epifauna has been reported and the vent sites are areas of settlement for exotic thermophilic species. Large numbers of novel prokaryotes, especially hyperthermophilic crenarchaeota, have been isolated from Mediterranean hydrothermal vents. However, their distribution in the subsurface biosphere and their role in the biogeochemistry of the sites has yet to be studied.

  19. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza Geology of Cerro Guanaquero region, Diamante River, Mendoza

    Directory of Open Access Journals (Sweden)

    Federico Fuentes

    2008-03-01

    Full Text Available El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánicas pliocenas a recientes de composición intermedia a básica, y depósitos cuaternarios inconsolidados. El cerro Guanaquero, un estratovolcán pliocuaternario intensamente erosionado por glaciares pleistocenos, con sus 4.841 metros es el rasgo orográfico más prominente. Está constituido esencialmente por andesitas grises porfíricas, piroxénicas a biotíticas. Intercaladas con las coladas andesíticas se presentan depósitos piroclásticos, aglomerados volcánicos, ignimbritas y basaltos. La datación de una andesita por el método K-Ar en roca total arrojó una edad de 1,4 ± 0,1 Ma. La deformación ándica comenzó en forma de una faja plegada y corrida de piel fina, con pliegues por despegue en el sector occidental y por propagación de falla en el oriental. La compresión al oeste de los 69º47´O terminó por invertir la fallas normales del rift mesozoico. A lo largo de este meridiano se encuentra la falla más importante de la región, la que se ha correlacionado con la falla Malargüe, bien desarrollada en latitudes más australes. Esta falla limita la faja plegada y corrida del Aconcagua, de naturaleza epidérmica, y la faja plegada y corrida de Malargüe, controlada por la inversión tectónica del basamento. El volcanismo fue muy intenso en el Plioceno y el Cuaternario, correspondiendo a un período de empinamiento de la placa oceánica subducida, en el que la región ha sido levantada pasivamente. La alta resistencia a la erosión de

  20. Arterial oxygen saturation in healthy newborns delivered at term in Cerro de Pasco (4340 m and Lima (150 m

    Directory of Open Access Journals (Sweden)

    Gonzales Gustavo F

    2005-09-01

    Full Text Available Abstract Background High altitude is associated with both low pulse oxygen saturation at birth and more pre-term deliveries. The present study was performed to determine pulse oxygen saturation in newborns at term in Cerro de Pasco (4340 m and Lima (150 m to test the hypothesis that low pulse oxygen saturation at birth at high altitudes was not observed at term deliveries. Methods The present study was designed to determine pulse oxygen saturation values through 1 minute to 24 hours and values of Apgar score at 1 and 5 minutes in newborns delivered at term in Cerro de Pasco (4340 m and Lima (150 m. Pulse oxygen saturation was recorded in 39 newborns from Cerro de Pasco (4340 m and 131 from Lima (150 m at 1, 2, 3, 4, 5, 10, 15, 30 minutes and 1, 2, 8 and 24 hours after delivery. Apgar score was assessed at 1 and 5 minutes after birth. Neurological score was assessed at 24 h of birth by Dubowitz exam. Results Pulse oxygen saturation increased significantly from 1 to 15 min after birth at sea level and from 1 to 30 minutes at Cerro de Pasco. Thereafter, it increased slightly such that at 30 min at sea level and at 60 minutes in Cerro de Pasco it reached a plateau up to 24 hours after birth. At all times, pulse oxygen saturation was significantly higher at sea level than at high altitude (P Conclusion From these analyses may be concluded that pulse oxygen saturation at 4340 m was significantly low despite the fact that births occurred at term. Apgar scores at first minute and neurological scores were also lower at high altitudes.

  1. Microwave Hydrothermal Synthesis PZT of Nanometer Crystal

    Institute of Scientific and Technical Information of China (English)

    Hongxing LIU; Hong DENG; Yan LI; Yanrong LI

    2004-01-01

    It was focused on the applications and developments of microwave hydrothermal synthesis piezoelectric ceramic powder. The microwave hydrothermal vessel was designed and manufactured. The microwave hydrothermal synthesis system was established and the PZT piezoelectric ceramic powder was synthesized. XRD and TEM have been used to characterize the products in detail. The diameter of the PZT powder particle is from 40 to 60 nm.

  2. La secuencia ocupacional y cerámica del cerro barajas, Guanajuato y sus relaciones con el centro, el occidente y el norte de México

    OpenAIRE

    Migeon, Gérald; Pereira, Grégory

    2013-01-01

    Note portant sur l’auteur Note portant sur l’auteur Los sitios del Cerro Barajas, municipio de Pénjamo, se encuentran en el límite suroeste del estado de Guanajuato. Forman un conjunto de asentamientos prehispánicos que se extiende por la falda norte del cerro (figura 1). Dicho cerro domina el río Lerma del lado sur, el río Turbio del lado este y los valles y la Sierra de Pénjamo del lado norte; asentamientos fueron registrados por primera vez al inicio de la década los años 1980 en el marco ...

  3. Mid amphibolite facies metamorphism of harzburgites in the Neoproterozoic Cerro Mantiqueiras Ophiolite, southernmost Brazil

    Directory of Open Access Journals (Sweden)

    HARTMANN LÉO A.

    2003-01-01

    Full Text Available Valuable information is retrieved from the integrated investigation of the field relationships, microstructure and mineral compositions of harzburgites from the Neoproterozoic Cerro Mantiqueiras Ophiolite. This important tectonic marker of the geological evolution of southernmost Brazilian Shield was thoroughly serpentinized during progressive metamorphism, because the oldest mineral assemblage is: olivine + orthopyroxene + tremolite + chlorite + chromite. This M1 was stabilized in mid amphibolite facies - 550-600ºC as calculated from mineral equilibria. No microstructural (e.g. ductile deformation of olivine or chromite or compositional (e.g. mantle spinel remnant of mantle history was identified. A metamorphic event M2 occurred in the low amphibolite facies along 100 m-wide shear zones, followed by intense serpentinization (M3 and narrow 1-3 m-wide shear zones (M4 containing asbestos.

  4. A new MOS mask cutter facility at Gemini/Cerro Tololo observatories

    Science.gov (United States)

    Wyman, Robert T.; Trancho, Gelys; Tighe, Roberto

    2010-07-01

    The installation and commissioning of a new laser cutter facility in La Serena, Chile is a cooperative effort between Gemini Observatory and the Cerro Tololo Inter-American Observatory. This system enables the cutting of aluminum and carbon fiber slit masks for three multi-object spectrographs operating in Chile: GMOS-S, Flamingos-2, and Goodman spectrograph. Selection of the new laser cutter tool was based on slit mask specifications developed for two materials. Prior to the commissioning all slit mask production was performed at Gemini's Northern base facility with a similar laser cutter system. The new facility supports two observatories and enhances the capabilities for both. This paper will discuss the observatory arrangement with respect to mask data tracking and handling. The laser system and facility will be discussed along with mask cutting performance, process development and manufacturing methods.

  5. MOVIMIENTOS DE LADERA Y PLANEAMIENTO URBANÍSTICO: EL CONFLICTO DEL CERRO DEL OPE, ARCHENA (MURCIA

    Directory of Open Access Journals (Sweden)

    María Dolores Gómez Moreno

    2009-01-01

    Full Text Available Los desprendimientos son un proceso natural que afecta, de forma generalizada en el Valle de Ricote, a las laderas del tipo cantil-talud. Su peligrosidad radica en que los bloques desprendidos del escarpe ruedan con facilidad, talud abajo, cuando son descalzados por efecto de la escorrentía superfi cial o desestabilizados por movimientos sísmicos. El planeamiento urbanístico se convierte en factor inductor del riesgo al clasifi car como urbanizables y urbanos suelos que, por su ubicación en pie de ladera, deberían excluirse de cualquier proceso urbanizador. Este es el caso de Archena en el entorno inmediato del cerro del Ope.

  6. Study of the atmospheric conditions at Cerro Armazones using astronomical data

    CERN Document Server

    Lakicevic, Masha; Noll, Stefan; Kausch, Wolfgang; Unterguggenberger, Stefanie; Kerber, Florian

    2016-01-01

    Aims: We studied the precipitable water vapour (PWV) content near Cerro Armazones and discuss the potential use of our technique of modelling the telluric absorbtion lines for the investigation of other molecular layers. The site is designated for the European Extremely Large Telescope (E-ELT) and the nearby planned site for the Cherenkov Telescope Array (CTA). Methods: Spectroscopic data from the Bochum Echelle Spectroscopic Observer (BESO) instrument were investigated by using line-by-line radiative transfer model (LBLRTM) radiative transfer models for the Earths atmosphere with the telluric absorption correction tool molecfit. All observations from the archive in the period from December 2008 to the end of 2014 were investigated. The dataset completely covers the El Nino event registered in the period 2009-2010. Models of the 3D Global Data Assimilation System (GDAS) were used for further comparison. Moreover, for those days with coincidence of data from a similar study with VLT/X-shooter and microwave rad...

  7. Burn Severities, Fire Intensities, and Impacts to Major Vegetation Types from the Cerro Grande Fire

    Energy Technology Data Exchange (ETDEWEB)

    Balice, Randy G. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bennett, Kathryn D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wright, Marjorie A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2004-12-15

    The Cerro Grande Fire resulted in major impacts and changes to the ecosystems that were burned. To partially document these effects, we estimated the acreage of major vegetation types that were burned at selected burn severity levels and fire intensity levels. To accomplish this, we adopted independently developed burn severity and fire intensity maps, in combination with a land cover map developed for habitat management purposes, as a basis for the analysis. To provide a measure of confidence in the acreage estimates, the accuracies of these maps were also assessed. In addition, two other maps of comparable quality were assessed for accuracy: one that was developed for mapping fuel risk and a second map that resulted from a preliminary application of an evolutionary computation software system, called GENIE.

  8. [Reptiles from Cerro Colorado and its surroundings, Cumana, Sucre State, Venezuela].

    Science.gov (United States)

    Oliveros, O; Prieto, A; Comejo, P

    2000-01-01

    An inventory of the reptiles that inhabit in Cerro Colorado and its surroundings, was performed from March, 1994 to March, 1995. There were reported 8 species of snakes and 7 of lizards enclosed in 4 and 5 families repectively. Aspects observed were ecolology as habitat, activity, reproduction and relative abundance. The more abundant species of lizards were: Cnemidophorus femniscatus, Ameiva bifrontata, (Teiidae), Tropidurus hispidus (Tropiduridae), Gonatodes vittatus and Hemidactylus mabouia (Gekkonidae) and the ophidians: Leptodeira annulata and Mastigodryas amarali (Colubridae). It is believed that the changes occurred in the zone influenced the increase of the relative abundance of the species Leptotyphlops goudotii (Leptotyphlopidae) arid Gymnophthalmus speciosus(Gymnophthalmidae) and perhaps in the disappearance of others that have been reported at the xerophitic or semixerophitic zones of the Sucre State of Venezuela. PMID:11220219

  9. Ordenación de espacios naturales: Los Cerros de Escazú (Costa Rica)

    OpenAIRE

    Zúñiga Venegas, William

    2004-01-01

    La presente tesis doctoral se realizó en Costa Rica, país del Istmo Centroamericano que ocupa el tercer lugar en extensión entre los siete países que lo integran, con un territorio de 51.100km2 y una población de 3.824.593 habitantes. De su extensión terrestre, por lo menos el 26% (13 286km2), cuenta con algún tipo de figura legal de protección ya sea ambiental o de los recursos naturales. El área específica de la investigación se localiza en la Zona Protectora de los Cerros de Escazú; que c...

  10. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

  11. HYDROTHERMAL CRACKING OF RESIDUAL OILS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrothermal cracking of heavy oils, such as Canadian oil sand bitumen and Arabian heavy vacuum residue, as well as their model compound were performed over sulfided Ni/Al2O3 and NiMo/Al2O3 catalysts under 663~703 K and 6.0~8.0 MPa of hydrogen pressure in a batch autoclave reactor. According to the reaction mechanism of hydrothermal cracking, a small amount of free redical initiators, such as di-tert-peroxide, sulfur, etc., was added into the feed to generate free redicals at lower temperature, and obviously showed promotional effect on the conversion of hydrocarbons. The reaction mechanisms of hydrothermal cracking as well as the enhancing effect of initiators were studied by a probe reaction with 1-phenyldodecane as a model compound. The hydrothermal cracking of hydrocarbon proceeded via free redical mechanism and hydrogenating quench. The initiators might easily generate free redicals under reaction temperature, these redicals might abstract H from hydrocarbon molecule and reasonably initiate the chain reactions, therefore, promote the conversion of hydrocarbon even at lower reaction temperature.

  12. Miguel Prieto y la escenografía en la España de los años treinta

    Directory of Open Access Journals (Sweden)

    Cabañas Bravo, Miguel

    2011-12-01

    Full Text Available The artist Miguel Prieto (1907-1956 worked in three main areas: painting-drawing, graphic design and set design. The latter was the one in which he demonstrated most interest in avant-garde and political commitment during the thirties, but due to his subsequent Mexican exile, has not been dealt with in recent research. This article, focused on his years in Spain, analyses his contributions to scenic design. Prieto’s first professional period, when he worked for the puppet theatre, coincided with the young Second Republic and then the convulsion of the Civil War. This popular genre was utilized for agitation, propaganda and the revolutionary theatre, and adopted both the classical repertoire and modern works by Alberti, Dieste, Lorca and other committed youthful intellectuals.

    Las tres grandes vertientes en las que el pintor Miguel Prieto (1907-1956 plasmó su creatividad fueron la pintura-dibujo, el diseño gráfico y la escenografía. Esta última, que fue en la que más énfasis puso tanto en su acercamiento a la vanguardia y el compromiso socio-político de los años treinta, como en los años finales de su trayectoria en el exilio mexicano, no ha sido suficientemente atendida. Este artículo, centrado en esa etapa española, analiza y pone en valor la aportación a la escena de Prieto coincidente con esos momentos de construcción de la joven II República y la convulsión de la Guerra Civil, que principalmente se plasmó en la escenificación de espectáculos de guiñol (extraídos del repertorio clásico o expresamente escritos por Alberti, Dieste, Lorca y otros jóvenes inquietos, ya que su tradición y clara aceptación popular los convertían en adecuado instrumento para encauzar la agitación y propaganda que querían sembrar el teatro revolucionario y la creatividad más avanzada y comprometida.

  13. Reflexiones en torno a la vulnerabilidad social y residencial de los asentamiento informales de los cerros de Valparaíso, Chile

    OpenAIRE

    Bailey, Christine; Zenteno, Elizabeth

    2015-01-01

    El incendio del pasado abril del 2014 ha abierto una serie de reflexiones respecto a las condiciones y riesgos que viven miles de familias de asentamientos informales de los cerros de Valparaíso. Aplicando una serie de entrevistas en profundidad a mujeres residentes en los cerros y quebradas, el estudio apunta a comprender las condiciones que las llevaron a habitar en aquellas zonas, visualizando el lento e infinito proceso de construcción de sus viviendas y asentamiento ...

  14. Description of a New Galapagos Giant Tortoise Species (Chelonoidis; Testudines: Testudinidae from Cerro Fatal on Santa Cruz Island.

    Directory of Open Access Journals (Sweden)

    Nikos Poulakakis

    Full Text Available The taxonomy of giant Galapagos tortoises (Chelonoidis spp. is currently based primarily on morphological characters and island of origin. Over the last decade, compelling genetic evidence has accumulated for multiple independent evolutionary lineages, spurring the need for taxonomic revision. On the island of Santa Cruz there is currently a single named species, C. porteri. Recent genetic and morphological studies have shown that, within this taxon, there are two evolutionarily and spatially distinct lineages on the western and eastern sectors of the island, known as the Reserva and Cerro Fatal populations, respectively. Analyses of DNA from natural populations and museum specimens, including the type specimen for C. porteri, confirm the genetic distinctiveness of these two lineages and support elevation of the Cerro Fatal tortoises to the rank of species. In this paper, we identify DNA characters that define this new species, and infer evolutionary relationships relative to other species of Galapagos tortoises.

  15. Nueva edad de la base del grupo Chubut en la mena uranífera Cerro Solo, provincia del Chubut

    Directory of Open Access Journals (Sweden)

    Nilda Marveggio

    2013-09-01

    Full Text Available En este trabajo se analizan las características litológicas de la roca hospedante de la mineralización de uranio del yacimiento Cerro Solo, que corresponde al miembro inferior de la Formación Los Adobes, unidad basal del Grupo Chubut en su sector norte. Se analiza la asociación de polen angiospérmico de allí recuperada, y en base a ese análisis, se establece una edad albiana temprana para la asociación polínica, que determina una edad más joven que la considerada hasta el momento para el inicio de la depositación de las sedimentitas del Grupo Chubut en el depocentro del yacimiento Cerro Solo.

  16. Hydrothermal carbonization of waste biomass

    OpenAIRE

    Basso, Daniele

    2016-01-01

    Hydrothermal carbonization (in acronym, HTC) is a thermochemical conversion process through which it is possible to directly transform wet organic substrates into a carbonaceous material, referred as hydrochar. Hydrochar has chemical and physical characteristics that make it similar to fossil peats and lignite. Depending on the process conditions, mostly temperature and residence time, this material can be enriched in its carbon content, modifying its structure and providing it interesting ch...

  17. Salt effects in hydrothermal synthesis

    OpenAIRE

    Avola, Sabine

    2012-01-01

    This work focuses on hydrothermal water as solvent and reaction medium. Water is abundant, non-toxic and environmentally benign, but at room temperature it does not dissolve most of the materials used in organic chemistry. When raising the temperature, though, its strong hydrogen bonds are weakened. At supercritical conditions water behaves similar to an unpolar solvent. However, high pressure, temperature and corrosion are technical challenges when reaching supercritical conditions. Al...

  18. Los marsupiales (Mammalia) del Mioceno Superior de la Formación Cerro Azul (Provincia de La Pampa, Argentina)

    OpenAIRE

    Visconti, G; Montalvo, C. I.; Goin, F J

    2000-01-01

    We describe the most complete South American marsupial association of Huayquerian Age (late Miocene). Specimens were recovered from several new localities of central and northern La Pampa province (central Argentina), at levels assignable to Cerro Azul Fm.: Bajo Giuliani, Quehué, Telén, El Guanaco, and Laguna Chillhué. Loessoid sediments studied from this formation are indicative of lacustrine deposits overlaid by eolian levels bearing evidences of pedogenesis. A study of these...

  19. ‘Looking at risk with both eyes’: health and safety in the Cerro Rico of Potosí (Bolivia)

    OpenAIRE

    Lopez-Trueba, Mei

    2014-01-01

    This thesis is concerned with core assumptions and practices in dominant approaches to Occupational Health and Safety (hereafter, OHS). I critically evaluate these through an anthropological exploration of the everyday perceptions, experiences and practices related to OHS risks amongst the cooperative miners employed in the Cerro Rico of Potosi (Bolivian Highlands). Drawing on 17 months of ethnographic fieldwork conducted between 2009 and 2011, the thesis examines the lives and livelihood...

  20. Xenoliths of Cerro las Mercedes, Costa Rica: a Geochemical Record of Arc History?

    Science.gov (United States)

    Lindsay, F. N.; Gazel, E.; Herzberg, C. T.; Carr, M. J.; Feigenson, M. D.

    2006-12-01

    Over 70 ultramafic xenoliths, many with diameters of at least 3cm, open a window into the mantle beneath Cerro las Mercedes, Costa Rica. This quaternary vent is 70km behind the active volcanic front and near the northern boundary of the Caribbean Plateau. Both xenoliths and host lava remain well preserved in spite of substantial soil development in a rain forest environment. We analyzed the host lava and a subset of 30 rocks for bulk and mineral chemistry, which include both peridotite and pyroxenite populations. The host rock is Plio-Quaternary potassic alkaline basalt; depleted in SiO2 and Al2O3 and enriched in MgO and P2O5 relative to both present day and Miocene volcanics. In terms of trace elements, the host basalt has enriched LREEs and relative depletion of HFSEs, typical of island-arc basalt, both present and past. The coarse-grained pyroxenites have trace element chemistry akin to the volcanic front lavas of Costa Rica, although they are closer to chondritic values. Truly, they are more similar to basalts from Sarapiquí Miocene arc than to present day volcanic front basalts. Although there is enrichment in incompatible elements such as Ba and U and depletions in HFSEs, common in island arc basalts, the pyroxenites have a strong positive Pb anomaly that is characteristic only of the Miocene arc, not present day lavas. We interpret the pyroxenites as cumulates. The peridotite population includes dunites, spinel lherzolites and lherzolites. These rocks have Mg-numbers ranging from 87 to 92 and Cr-numbers ranging from 6 to 61. Whole rock geochemistry indicates that the peridotite xenoliths are fragments of mantle associated with the western Caribbean Plateau. SiO2, FeO, Al2O3 and MgO contents of several Cerro Mercedes peridotites are similar to those expected of hot residues that would form in a plume environment. Trace elements reveal some samples with enrichment of Ba and U, and depletion in Nb and Ta indicating variable extents of melt-rock reaction and

  1. Sustainable carbon materials from hydrothermal processes

    CERN Document Server

    Titirici, Maria-Magdalena

    2013-01-01

    The production of low cost and environmentally friendly high performing carbon materials is crucial for a sustainable future. Sustainable Carbon Materials from Hydrothermal Processes describes a sustainable and alternative technique to produce carbon from biomass in water at low temperatures, a process known as Hydrothermal Carbonization (HTC). Sustainable Carbon Materials from Hydrothermal Processes presents an overview of this new and rapidly developing field, discussing various synthetic approaches, characterization of the final products, and modern fields of application fo

  2. A Climatology of Ripple Instabilities in the OH Airglow at Cerro Pachon, Chile

    Science.gov (United States)

    Gelinas, L. J.; Hecht, J. H.; Walterscheid, R. L.; Rudy, R. J.

    2015-12-01

    Airglow imaging provides a unique means by which to study many wave-related phenomena in the 80 to 100 km altitude regime. Observations reveal quasi-monochromatic disturbances associated with atmospheric gravity waves (AGWs) as well as small-scale instabilities often called ripples. Ripples are wavelike features that resemble AGWs in appearance, but have short horizontal wavelengths (Corporation's Nightglow Imager (ANI) is located at the Andes Lidar Observatory near the crest of Cerro Pachon, Chile. ANI observes nighttime OH emission (near 1.6 microns) every 2 seconds over an approximate 73 degree field of view, which allows the study of AGW and ripple features over very short temporal and spatial scales. An automated wave detection algorithm is used to identify ripple and quasi monochromatic wave features in the ANI data. Ripples are characterized by their wavelength, orientation, drift speed and location in the image. Quasi-monochromatic waves are quantified by wavelength, wave period and propagation direction. We present a climatology of ripple instabilities at Chile, including comparisons to the background quasi-monochromatic wave field. Lidar and radar data are used to determine the background wind and temperatures, which allows comparisons between ripple observations and evanescent regions and potentially unstable regions identified by Richardson number.

  3. Research Experiences for Undergraduates at Cerro Tololo Inter-American Observatory

    Science.gov (United States)

    Hoard, D. W.; Smith, R. C.

    2000-12-01

    Each year, Cerro Tololo Inter-American Observatory (CTIO), located in La Serena, Chile, hosts a Research Experiences for Undergraduates (REU) Program funded by the National Science Foundation. In general, REU programs bring a group of undergraduate students to the host institute for 10 weeks, where they are teamed-up with staff members to perform research projects. Unlike REU programs at other U.S. institutions, the CTIO program takes place outside the United States and during the southern summer/northern winter months of January--March. This offers students not only a chance to perform research and participate in the day-to-day life at a major astronomical observatory, but also provides a unique exposure to a foreign culture and an option for students who can take advantage of a non-traditional work experience during the academic year. CTIO REU students also benefit from interaction with their Chilean counterparts participating in the Prácticas de Investigación en Astronomía, an REU-like program operated by CTIO for Chilean undergraduates. Since 1995, CTIO has hosted 20 REU students (with 4 more coming in 2001). Twenty (and counting) publications have resulted from CTIO REU projects. In addition, since 1999, 100% of the CTIO REU students have presented the results of their research projects at meetings of the American Astronomical Society. We present here an overview of the REU program at CTIO.

  4. Characterization of the sodium layer at Cerro Pachon, and impact on laser guide star performance

    CERN Document Server

    Neichel, Benoit; Callingham, Joseph; Rigaut, Francois; Winge, Claudia; Trancho, Gelys; 10.1093/mnras/sts631

    2013-01-01

    Detailed knowledge of the mesopheric sodium layer characteristics is crucial to estimate and optimize the performance of Laser Guide Star (LGS) assisted Adaptive Optics (AO) systems. In this paper, we present an analysis of two sets of data on the mesospheric sodium layer. The first set comes from a laser experiment that was carried out at Cerro Tololo to monitor the abundance and altitude of the mesospheric sodium in 2001, during six runs covering a period of one year. This data is used to derive the mesospheric sodium column density, the sodium layer thickness and the temporal behavior of the sodium layer mean altitude. The second set of data was gathered during the first year of the Gemini MCAO System (GeMS) commissioning and operations. GeMS uses five LGS to measure and compensate for atmospheric distortions. Analysis of the LGS wavefront sensor data provides information about the sodium photon return and the spot elongation seen by the WFS. All these parameters show large variations on a yearly, nightly ...

  5. New mammalian records in the Parque Nacional Cerros de Amotape, northwestern Peru

    Directory of Open Access Journals (Sweden)

    Cindy M. Hurtado

    2015-04-01

    Full Text Available The Pacific Tropical Rainforest and Equatorial Dry Forest are found only in southern Ecuador and northern Peru, and are among the most poorly known ecosystems of South America. Even though these forests are protected in Parque Nacional Cerros de Amotape (PNCA, they are threatened by fragmentation because of farming and agriculture. The aim of this study was to determine the medium and large mammalian species richness, using transect census, camera trapping, and specimen bone collection. Nine transects were established and 21 camera trap stations were placed along 16 km2 in three localities of PNCA, from August 2012 to April 2013. Total sampling effort was 215 km of transects and 4077 camera-days. We documented 22 species; including 17 with camera trapping, 11 with transect census, and 10 with specimen collection.  Camera traps were the most effective method, and four species (Dasyprocta punctata, Cuniculus paca, Leopardus wiedii and Puma concolor were documented only with this method. This comprised the first Peruvian record for Dasyprocta punctata, and the first record for the western slope of the Peruvian Andes for Cuniculus paca. Also, both specimen collections and sightings confirm the presence of Potos flavus, first record in the western slope of the Peruvian Andes. Panthera onca, Tremarctos ornatus and Saimiri sciureus are considered locally extinct, while several species are in need of further research. We highlight the importance of the high diversity of this rainforests and encourage local authorities to give the area the highest priority in conservation.

  6. Forecast of surface layer meteorological parameters at Cerro Paranal with a mesoscale atmospherical model

    CERN Document Server

    Lascaux, Franck; Fini, Luca

    2015-01-01

    This article aims at proving the feasibility of the forecast of all the most relevant classical atmospherical parameters for astronomical applications (wind speed and direction, temperature) above the ESO ground-base site of Cerro Paranal with a mesoscale atmospherical model called Meso-Nh. In a precedent paper we have preliminarily treated the model performances obtained in reconstructing some key atmospherical parameters in the surface layer 0-30~m studying the bias and the RMSE on a statistical sample of 20 nights. Results were very encouraging and it appeared therefore mandatory to confirm such a good result on a much richer statistical sample. In this paper, the study was extended to a total sample of 129 nights between 2007 and 2011 distributed in different parts of the solar year. This large sample made our analysis more robust and definitive in terms of the model performances and permitted us to confirm the excellent performances of the model. Besides, we present an independent analysis of the model p...

  7. Monitoring the atmospheric throughput at Cerro Tololo Inter-American Observatory with aTmCam

    CERN Document Server

    Li, Ting; Marshall, J L; Nagasawa, D Q; Carona, D W; Boada, S

    2014-01-01

    We have built an Atmospheric Transmission Monitoring Camera (aTmCam), which consists of four telescopes and detectors each with a narrow-band filter that monitors the brightness of suitable standard stars. Each narrowband filter is selected to monitor a different wavelength region of the atmospheric transmission, including regions dominated by the precipitable water vapor and aerosol optical depth. The colors of the stars are measured by this multi narrow-band imager system simultaneously. The measured colors, a model of the observed star, and the measured throughput of the system can be used to derive the atmospheric transmission of a site on sub-minute time scales. We deployed such a system to the Cerro Tololo Inter-American Observatory (CTIO) and executed two one-month-long observing campaigns in Oct-Nov 2012 and Sept-Oct 2013. We have determined the time and angular scales of variations in the atmospheric transmission above CTIO during these observing runs. We also compared our results with those from a G...

  8. Measurements of air contaminants during the Cerro Grande fire at Los Alamos National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Eberhart, Craig

    2010-08-01

    Ambient air sampling for radioactive air contaminants was continued throughout the Cerro Grande fire that burned part of Los Alamos National Laboratory. During the fire, samples were collected more frequently than normal because buildup of smoke particles on the filters was decreasing the air flow. Overall, actual sampling time was 96% of the total possible sampling time for the May 2000 samples. To evaluate potential human exposure to air contaminants, the samples were analyzed as soon as possible and for additional specific radionuclides. Analyses showed that the smoke from the fire included resuspended radon decay products that had been accumulating for many years on the vegetation and the forest floor that burned. Concentrations of plutonium, americium, and depleted uranium were also measurable, but at locations and concentrations comparable to non-fire periods. A continuous particulate matter sampler measured concentrations that exceeded the National Ambient Air Quality Standard for PM-10 (particles less than 10 micrometers in diameter). These high concentrations were caused by smoke from the fire when it was close to the sampler.

  9. 3-cerro y 4-mundo: los números del banquete en las ofrendas quechuas

    Directory of Open Access Journals (Sweden)

    David Lorente Fernández

    2010-12-01

    Full Text Available Las ofrendas quechuas del sur del Perú son platos alimenticios, banquetes destinados principalmente a la pachamama y los apus, pero también elaborados sistemas matemáticos regidos por operaciones sofisticadas. Sirviéndose de dos números fundamentales, el 3 y el 4, los especialistas rituales son capaces de transmitir mensajes polisémicos. Mediante el número 3 aglutinan clientes, parajes y cerros, en suma, «personas» capaces de interactuar entre sí. El 3 aparece en los k’intus de hojas de coca y en las oraciones que se recitan durante el proceso de realizar la ofrenda. Por el contrario, el número 4 no indica relaciones sino formas espaciales: es un operador geométrico que unifica la servilleta ceremonial (unk’uña, el papel envoltorio y el paquete acabado para representar las cuatro direcciones del mundo y hacer de la ofrenda un mundo en miniatura. Gracias a los dos números el ritualista puede recrear el cosmos, establecer convenios con los dioses y definir nuevas situaciones favorables para la vida de sus clientes.

  10. The Final Days of Paracas in Cerro del Gentil, Chincha Valley, Peru.

    Science.gov (United States)

    Tantaleán, Henry; Stanish, Charles; Rodríguez, Alexis; Pérez, Kelita

    2016-01-01

    This article describes and analyzes a highly significant archaeological context discovered in a late Paracas (400-200 BCE) sunken patio in the monumental platform mound of Cerro Gentil, located in the Chincha Valley, Peru. This patio area was used for several centuries for ritual activities, including large-scale feasting and other public gatherings. At one point late in this historical sequence people deposited a great deal of objects in what is demonstrably a single historical event. This was quickly followed by a series of minor events stratigraphically immediately above this larger event. This entire ritual process included the consumption of liquids and food, and involved the offering of whole pottery, pottery fragments, botanical remains, bone, lithics, baskets, pyro-engraved gourds, mummies, and other objects. We interpret these events as an "abandonment ceremony" or "termination ritual" during the late Paracas period, one that may have lasted for weeks or even months. The subsequent Topará occupation at the site (ca. 200 BCE- AD 100) involved the architectural enhancement of the mound area, but the pattern of use of the patio itself ended. Such a termination ritual signals a reorganization in the regional political structure of Paracas society. PMID:27144824

  11. Unrest of Chiles - Cerro Negro volcanic complex: A binational Ecuador - Colombia effort

    Science.gov (United States)

    Ruiz, M. C.; Gomez, D.; Torres, R.; Cadena, O.; Mothes, P. A.; Anzieta, J. C.; Pacheco, D. A.; Bernard, B.; Acero, W.; Hidalgo, S.; Enriquez, W.; Cordova, A.

    2014-12-01

    The increasing seismic activity at the area of Chiles - Cerro Negro volcanic complex, located at the Ecuador-Colombian border, has been jointly monitored by the Instituto Geofisico - Ecuador and the Observatorio Vulcanologico y Sismologico de Pasto OVSP, a division of the Servicio Geologico Colombiano. Since April 2013, three seismic swarms have been detected in this area and more than 100.000 events are recorded since November 2013. The largest and more recent swarm has a daily average of 676 events between March and June 2014. Currently a seismic network of 8 seismic stations (5 in the Colombian and 3 in Ecuadorean side) are deployed in this area. Epicenters of more than 315 seismic events with magnitudes Ml>2.0 and 10 or more phases are located in an area 1-4 km south of Chiles volcano with shallow depths (up to 14 km). Most of events have magnitudes between 1.0 to 4.0. Nine events have magnitudes larger than 4.0 and the largest event occurred on April 30. 2014 with a local magnitude of 4.7 and inverse-transcurrent component focal mechanism. Waveforms and spectral patterns define these events as volcano-tectonic. Events with large magnitudes (above 3.0) show a very long-period component. Hot spring and deformation measurements also show signals of volcanic unrest.

  12. Optical and infrared observations of SN 1987A from Cerro Tololo Inter-American Observatory

    International Nuclear Information System (INIS)

    Results from optical and infrared observations of SN 1987A obtained at Cerro Tololo Inter-American Observatory over the first seven months since core collapse are reviewed. Around 130 days after outburst, the bolometric light curve began to smoothly decline at a rate of ∼ 0.01 mag day-1, providing dramatic confirmation of the prediction that radioactivity had powered the optical display after the first month./ the peculiar color changes are kinks observed beginning on the 25th day probably signaled the initial release of trapped energy from mass 56 material. The bolometric luminosity of SN 1987A was unusually low at first, but reached a value more typical of other type II supernovae by the time that the final exponential decline had begun. Over much of the period covered by these observations, the optical and infrared spectra were characterized by strong absorption lines of Ba II and Sr II. Comparison with the spectra of other type II supernovae at similar stages of evolution supports the suggestion that s-processed elements were enriched in the hydrogen envelope of the progenitor, Sanduleak - 69 degrees 202

  13. Subsurface Connections and Magma Mixing as revealed by Olivine- and Pyroxene-Hosted Melt Inclusions from Cerro Negro Volcano and the Las Pilas-El Hoyo Complex, Nicaragua.

    Science.gov (United States)

    Venugopal, S.; Moune, S.; Williams-Jones, G.

    2015-12-01

    Cerro Negro, the youngest volcano in the Central American Volcanic Belt, is a polygenetic cinder cone with relatively frequent explosive basaltic eruptions. Las Pilas, on the other hand, is a much larger and older complex with milder and less frequent eruptions. Based on historical data, these two closely spaced volcanoes have shown concurrent eruptive behavior, suggesting a subsurface connection. To further investigate this link, melt inclusions, which are blebs of melt trapped in growing crystals, were the obvious choice for optimal comparison of sources and determination of pre-eruptive volatile contents and magmatic conditions. Olivine-hosted inclusions were chosen for both volcanoes and pyroxene-hosted inclusions were also sampled from Las Pilas to represent the evolved melt. Major, volatile and trace elements reveal a distinct geochemical continuum with Cerro Negro defining the primitive end member and Las Pilas representing the evolved end member. Volatile contents are high for Cerro Negro (up to 1260 ppm CO2, 4.27 wt% H2O and 1700 ppm S) suggesting that volatile exsolution is likely the trigger for Cerro Negro's explosive eruptions. Las Pilas volatile contents are lower but consistent with degassing and evolutionary trends shown by major oxides. Trace element contents are rather unique and suggest Cerro Negro magmas fractionally crystallize while Las Pilas magmas are the products of mixing. Magmatic conditions were estimated with major and volatile contents: at least 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for Las Pilas melts with an overall oxygen fugacity at the NNO buffer. In combination with available literature data, this study suggests an interconnected subsurface plumbing system and thus Cerro Negro should be considered as the newest vent within the Las Pilas-El Hoyo Complex.

  14. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  15. Validating numerical simulations of snow avalanches using dendrochronology: the Cerro Ventana event in Northern Patagonia, Argentina

    Science.gov (United States)

    Casteller, A.; Christen, M.; Villalba, R.; Martínez, H.; Stöckli, V.; Leiva, J. C.; Bartelt, P.

    2008-05-01

    The damage caused by snow avalanches to property and human lives is underestimated in many regions around the world, especially where this natural hazard remains poorly documented. One such region is the Argentinean Andes, where numerous settlements are threatened almost every winter by large snow avalanches. On 1 September 2002, the largest tragedy in the history of Argentinean mountaineering took place at Cerro Ventana, Northern Patagonia: nine persons were killed and seven others injured by a snow avalanche. In this paper, we combine both numerical modeling and dendrochronological investigations to reconstruct this event. Using information released by local governmental authorities and compiled in the field, the avalanche event was numerically simulated using the avalanche dynamics programs AVAL-1D and RAMMS. Avalanche characteristics, such as extent and date were determined using dendrochronological techniques. Model simulation results were compared with documentary and tree-ring evidences for the 2002 event. Our results show a good agreement between the simulated projection of the avalanche and its reconstructed extent using tree-ring records. Differences between the observed and the simulated avalanche, principally related to the snow height deposition in the run-out zone, are mostly attributed to the low resolution of the digital elevation model used to represent the valley topography. The main contributions of this study are (1) to provide the first calibration of numerical avalanche models for the Patagonian Andes and (2) to highlight the potential of textit{Nothofagus pumilio} tree-ring records to reconstruct past snow-avalanche events in time and space. Future research should focus on testing this combined approach in other forested regions of the Andes.

  16. Public health surveillance after a volcanic eruption: lessons from Cerro Negro, Nicaragua, 1992.

    Science.gov (United States)

    Malilay, J; Real, M G; Ramirez Vanegas, A; Noji, E; Sinks, T

    1996-09-01

    The eruption of the Cerro Negro volcano near León, Nicaragua, on 9 April 1992 distributed an estimated 1.7 million tons of ash over a 200 square kilometer area. An assessment was conducted to evaluate the health effects on approximately 300,000 residents, using routine data obtained by the national epidemiologic surveillance system. It was found that rates of visits to health care facilities for acute diarrheal and respiratory illnesses increased in two study communities, one within and one near the disaster zone. Specifically, visits for acute diarrhea were nearly 6 times more numerous than before the eruption in both communities, while visits for acute respiratory diseases were 3.6 times more frequent in Malpaisillo (the community near the disaster zone) and 6.0 times more frequent in Telica (the community within it). Most of the visits were for infants and children less than 5 years old. Increased diarrheal disease morbidity, which commonly occurs after volcanic eruptions, demands detailed investigation of the type and quality of water supplies following heavy ashfall. Ash-related respiratory problems should be further examined to determine the spectrum of such diseases and the timing of illness onsets among infants and other special population subgroups. Data collected on health conditions before and after an eruption by passive surveillance can be used to detect eruption-related morbidity. Systems already in place, such as Nicaragua's national epidemiologic surveillance system, can be modified or extended so as to increase their sensitivity to new cases and hence their ability to provide appropriate notification to medical relief agencies. PMID:8897722

  17. Validating numerical simulations of snow avalanches using dendrochronology: the Cerro Ventana event in Northern Patagonia, Argentina

    Directory of Open Access Journals (Sweden)

    A. Casteller

    2008-05-01

    Full Text Available The damage caused by snow avalanches to property and human lives is underestimated in many regions around the world, especially where this natural hazard remains poorly documented. One such region is the Argentinean Andes, where numerous settlements are threatened almost every winter by large snow avalanches. On 1 September 2002, the largest tragedy in the history of Argentinean mountaineering took place at Cerro Ventana, Northern Patagonia: nine persons were killed and seven others injured by a snow avalanche. In this paper, we combine both numerical modeling and dendrochronological investigations to reconstruct this event. Using information released by local governmental authorities and compiled in the field, the avalanche event was numerically simulated using the avalanche dynamics programs AVAL-1D and RAMMS. Avalanche characteristics, such as extent and date were determined using dendrochronological techniques. Model simulation results were compared with documentary and tree-ring evidences for the 2002 event. Our results show a good agreement between the simulated projection of the avalanche and its reconstructed extent using tree-ring records. Differences between the observed and the simulated avalanche, principally related to the snow height deposition in the run-out zone, are mostly attributed to the low resolution of the digital elevation model used to represent the valley topography. The main contributions of this study are (1 to provide the first calibration of numerical avalanche models for the Patagonian Andes and (2 to highlight the potential of Nothofagus pumilio tree-ring records to reconstruct past snow-avalanche events in time and space. Future research should focus on testing this combined approach in other forested regions of the Andes.

  18. Glacier mass balance reconstruction by sublimation induced enrichment of chemical species on Cerro Tapado (Chilean Andes

    Directory of Open Access Journals (Sweden)

    P. Ginot

    2006-01-01

    Full Text Available A 36 m long ice core down to bedrock from the Cerro Tapado glacier (5536 m a.s.l, 30°08' S, 69°55' W was analyzed to reconstruct past climatic conditions for Northern Chile. Because of the marked seasonality in the precipitation (short wet winter and extended dry summer periods in this region, major snow ablation and related post-depositional processes occur on the glacier surface during summer periods. They include predominantly sublimation and dry deposition. Assuming that, like measured during the field campaign, the enrichment of chloride was always related to sublimation, the chemical record along the ice core may be applied to reconstruct the history of such secondary processes linked to the past climatic conditions over northern Chile. For the time period 1962–1999, a mean annual net accumulation of 316 mm water equivalent (weq and 327 mm weq loss by sublimation was deduced by this method. This corresponds to an initial total annual accumulation of 539 mm weq. The annual variability of the accumulation and sublimation is related with the Southern Oscillation Index (SOI: higher net-accumulation during El-Niño years and more sublimation during La Niña years. The deepest part of the ice record shows a time discontinuity; with an ice body deposited under different climatic conditions: 290 mm higher precipitation but with reduced seasonal distribution (+470 mm in winter and –180 mm in summer and –3°C lower mean annual temperature. Unfortunately, its age is unknown. The comparison with regional proxy data however let us conclude that the glacier buildup did most likely occur after the dry mid-Holocene.

  19. Temporal Evolution of a Seismic Swarm at Chiles - Cerro Negro volcanic complex

    Science.gov (United States)

    Ruiz, Mario

    2015-04-01

    The increasing seismic activity in the area of the Chiles - Cerro Negro volcanic complex, located on the Ecuador-Colombian border, has been jointly monitored by the Instituto Geofisico - Ecuador and the Observatorio Vulcanologico y Sismologico de Pasto (OVSP), a division of the Servicio Geologico Colombiano. Since April 2013, three seismic swarms have been detected in this area, and more than 400.000 events have been recorded since November 2013. The largest and most recent swarm has a daily average of 3894 events between March and the 12th of December 2014. Currently a seismic network of 13 short- and broad-band stations (5 Colombian, 8 Ecuadorian) was deployed in this area. High quality epicenters of seismic events with magnitudes Ml>2.0, RMSChiles volcano with shallow depths (up to 14 km). Most events have magnitudes between 1.0 to 4.0. Fifteen events have magnitudes larger than 4.0 including an event that occurred on October 20, 2014. This event had a local magnitude of 5.7 and an oblique (strike-slip with some thrusting) focal mechanism. Waveforms and spectral patterns define these events as volcano-tectonic. However, events with moderate to large magnitudes (above 3.0) contain pronounced very-long-period components. Position time series recorded by a dual-frequency GPS receiver at the SE flank of Chiles show a slight departure from the normal tectonic trend beginning with the appearance of the last seismic swarm on or around September 30, 2014. This trend is subsequently punctuated by a sharp deformation transient related to the coseismic displacement of the October 20 event. After more than a year of very anomalous seismic activity and concurrent minor deformation, no evidence of surficial volcanic activity has been documented.

  20. Shallow earthquake inhibits unrest near Chiles-Cerro Negro volcanoes, Ecuador-Colombian border

    Science.gov (United States)

    Ebmeier, Susanna K.; Elliott, John R.; Nocquet, Jean-Mathieu; Biggs, Juliet; Mothes, Patricia; Jarrín, Paúl; Yépez, Marco; Aguaiza, Santiago; Lundgren, Paul; Samsonov, Sergey V.

    2016-09-01

    Magma movement or reservoir pressurisation can drive swarms of low-magnitude volcano-tectonic earthquakes, as well as occasional larger earthquakes (>M5) on local tectonic faults. Earthquakes >M5 near volcanoes are challenging to interpret in terms of evolving volcanic hazard, but are often associated with eruptions, and in some cases enhance the ascent of magma. We present geodetic observations from the first episode of unrest known to have occurred near Chiles and Cerro Negro de Mayasquer volcanoes on the Ecuador-Colombian border. A swarm of volcano-tectonic seismicity in October 2014 culminated in a Mw 5.6 earthquake south of the volcanoes. Satellite radar data spanning this earthquake detect displacements that are consistent with dextral oblique slip on a reverse fault at depths of 1.4-3.4 km within a SSW-NNE trending fault zone that last ruptured in 1886. GPS station measurements capture ∼20 days of uplift before the earthquake, probably originating from a pressure source ∼10-15 km south of Volcán Chiles, at depths exceeding 13 km. After the Mw 5.6 earthquake, uplift ceased and the rate of seismicity began to decrease. Potential mechanisms for this decline in activity include a decrease in the rate of movement of magma into the shallow crust, possibly caused by the restriction of fluid pathways. Our observations demonstrate that an earthquake triggered during volcanic unrest can inhibit magmatic processes, and have implications for the hazard interpretation of the interactions between earthquakes and volcanoes.

  1. Structural control on geothermal circulation in the Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Argentina)

    Science.gov (United States)

    Giordano, Guido; Pinton, Annamaria; Cianfarra, Paola; Baez, Walter; Chiodi, Agostina; Viramonte, José; Norini, Gianluca; Groppelli, Gianluca

    2013-01-01

    The reconstruction of the stratigraphical-structural framework and the hydrogeology of geothermal areas is fundamental for understanding the relationships between cap rocks, reservoir and circulation of geothermal fluids and for planning the exploitation of the field. The Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Central Andes, NW Argentina) has a high geothermal potential. It is crossed by the active NW-SE trans-Andean tectonic lineament known as the Calama-Olacapato-Toro (COT) fault system, which favours a high secondary permeability testified by the presence of numerous springs. This study presents new stratigraphic and hydrogeological data on the geothermal field, together with the analysis from remote sensed image analysis of morphostructural evidences associated with the structural framework and active tectonics. Our data suggest that the main geothermal reservoir is located within or below the Pre-Palaeozoic-Ordovician basement units, characterised by unevenly distributed secondary permeability. The reservoir is recharged by infiltration in the ridges above 4500 m a.s.l., where basement rocks are in outcrop. Below 4500 m a.s.l., the reservoir is covered by the low permeable Miocene-Quaternary units that allow a poor circulation of shallow groundwater. Geothermal fluids upwell in areas with more intense fracturing, especially where main regional structures, particularly NW-SE COT-parallel lineaments, intersect with secondary structures, such as at the Tocomar field. Away from the main tectonic features, such as at the Cerro Tuzgle field, the less developed network of faults and fractures allows only a moderate upwelling of geothermal fluids and a mixing between hot and shallow cold waters. The integration of field-based and remote-sensing analyses at the Cerro Tuzgle-Tocomar area proved to be effective in approaching the prospection of remote geothermal fields, and in defining the conceptual model for geothermal circulation.

  2. Estructura, composición y diversidad de la selva baja caducifolia del Cerro Verde, Nizanda (Oaxaca), México

    OpenAIRE

    José Antonio Gallardo Cruz; Meave, Jorge A.; Eduardo A. Pérez García

    2005-01-01

    En este estudio se describe la estructura, la composición florística y los patrones de diversidad de la selva baja caducifolia del Cerro Verde, localizado en Nizanda (Istmo de Tehuantepec, Oaxaca, México). En 30 parcelas de 100 m2 se censaron las plantas leñosas con DAP #8805; 1 cm (estrato alto), y en cinco subcuadros de 4 m2 dentro de cada una se censaron las plantas con DAP 1 cm, pero con altura 30 cm (estrato bajo). Se encontraron 194 especies distribuidas en 52 familias. La riqueza de...

  3. Dieta de murciélagos nectarívoros del Parque Nacional Cerros de Amotape, Tumbes

    OpenAIRE

    Edith Arias; Richard Cadenillas; Víctor Pacheco

    2011-01-01

    En el Perú se reporta la presencia de 18 especies de murciélagos nectarívoros, sin embargo se cuenta con poca información sobre la dieta de estas especies. En este estudio se reporta por primera vez la dieta de los nectarívoros Glossophaga soricina, Lonchophylla hesperia y Anoura geoffroyi en el bosque seco ecuatorial y del bosque tropical del Pacífico del Parque Nacional Cerros de Amotape, Tumbes. Analizamos 21 contenidos gastrointestinales e identificamos ocho morfotipos de polen pertenecie...

  4. Los marsupiales (Mammalia) del Mioceno Superior de la formación Cerro Azul (Provincia de la Pampa, Argentina)

    OpenAIRE

    Goin, Francisco Javier; Montalvo, Claudia; Visconti, G

    2000-01-01

    Se describe la asociación de marsupiales sudamericanos fósiles de edad Huayqueriense (Mioceno tardío) más completa hasta ahora conocida. Los ejemplares fueron exhumados de varias localidades fosilíferas nuevas del centro y norte de la provincia de La Pampa (Argentina central), en sedimentos asignables a la Formación Cerro Azul: Bajo Giuliani, Quehué, Telén, El Guanaco y Laguna Chillhué. El conjunto de las sedimentitas loessoides analizadas en los diferentes afloramientos de esta formación ind...

  5. Palaeoenvironment reconstruction, volcanic evolution and geochronology of the Cerro Blanco subcomplex, Nevados de Chillan volcanic complex, Central Chile

    OpenAIRE

    Mee, Katy; Gilbert, Jennie S.; McGarvie, David W.; Naranjo, Jose A.; Pringle, Malcolm S.

    2009-01-01

    Nevados de Chillán Volcanic Complex, central Chile, has been active for at least 640 ka—a period spanning a number of glacial and interglacial periods. Geologic mapping, radiometric dating and geochemical analysis have identified six new volcanic units and produced four new 40Ar/39Ar ages for Cerro Blanco, the northern subcomplex of Nevados de Chillán volcano. Compositions range from dacite to basaltic-andesite and a new geologic map is presented. Examination of lava fracture structures on bo...

  6. Arterial oxygen saturation in healthy newborns delivered at term in Cerro de Pasco (4340 m) and Lima (150 m)

    OpenAIRE

    Gonzales Gustavo F; Salirrosas Amelia

    2005-01-01

    Abstract Background High altitude is associated with both low pulse oxygen saturation at birth and more pre-term deliveries. The present study was performed to determine pulse oxygen saturation in newborns at term in Cerro de Pasco (4340 m) and Lima (150 m) to test the hypothesis that low pulse oxygen saturation at birth at high altitudes was not observed at term deliveries. Methods The present study was designed to determine pulse oxygen saturation values through 1 minute to 24 hours and val...

  7. Estudio de la líqueno flora encontrada en el Cerro de Quininí, Tibacuy, Cundinamarca

    OpenAIRE

    Hormaza Francisco; Vivas Oscar; Parra Alejandro

    2000-01-01

    Se realizó un muestreo de la liquen o flora del cerro de Quininí, Tibacuy, Cundinamarca para estudiar las características morfológicas externas de los géneros de líquenes encontrados en el. A su vez se hizo la revisión bibliográfica acerca de dichos géneros, datando así la riqueza de líquenes en la zona con 8 géneros en total y con respecto al papel de bioindicadores se mostró el grado de intervención para el lugar.

  8. TITAN2D simulations of pyroclastic flows at Cerro Machín Volcano, Colombia: Hazard implications

    Science.gov (United States)

    Murcia, H. F.; Sheridan, M. F.; Macías, J. L.; Cortés, G. P.

    2010-03-01

    Cerro Machín is a dacitic tuff ring located in the central part of the Colombian Andes. It lies at the southern end of the Cerro Bravo-Cerro Machín volcanic belt. This volcano has experienced at least six major explosive eruptions during the last 5000 years. These eruptions have generated pyroclastic flows associated with Plinian activity that have traveled up to 8 km from the crater, and pyroclastic flows associated with Vulcanian activity with shorter runouts of 5 km from the source. Today, some 21,000 people live within a 8 km radius of Cerro Machín. The volcano is active with fumaroles and has shown increasing seismic activity since 2004, and therefore represents a potentially increasing threat to the local population. To evaluate the possible effects of future eruptions that may generate pyroclastic density currents controlled by granular flow dynamics we performed flow simulations with the TITAN2D code. These simulations were run in all directions around the volcano, using the input parameters of the largest eruption reported. The results show that an eruption of 0.3 km 3 of pyroclastic flows from a collapsing Plinian column would travel up to 9 km from the vent, emplacing a deposit thicker than 60 m within the Toche River valley. Deposits >45 m thick can be expected in the valleys of San Juan, Santa Marta, and Azufral creeks, while 30 m thick deposits could accumulate within the drainages of the Tochecito, Bermellón, and Coello Rivers. A minimum area of 56 km 2 could be affected directly by this kind of eruption. In comparison, Vulcanian column-collapse pyroclastic flows of 0.1 km 3 would travel up to 6 km from the vent depositing >45 m thick debris inside the Toche River valley and more than 30 m inside the valleys of San Juan, Santa Marta, and Azufral creeks. The minimum area that could be affected directly by this kind of eruption is 33 km 2. The distribution and thickness of the deposits obtained by these simulations are consistent with the hazard

  9. Nitrogen-doped hydrothermal carbons

    Energy Technology Data Exchange (ETDEWEB)

    Titirici, Maria-Magdalena; White, Robin J. [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; Zhao, Li [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; National Center for Nanoscience and Technology, Beijing (China)

    2012-07-01

    Nitrogen doped carbon materials are now playing an important role in cutting edge innovations for energy conversion and storage technologies such as supercapacitors and proton exchange membrane fuel cells as well as in catalytic applications, adsorption and CO{sub 2} capture. The production of such materials using benign aqueous based processes, mild temperatures and renewable precursors is of great promise in addressing growing environmental concerns for cleaner power sources at a time of increasing global demand for energy. In this perspective, we show that nitrogen doped carbons prepared using sustainable processes such as ''Hydrothermal Carbonisation'' has advantages in many applications over the conventional carbons. We also summarize an array of synthetic strategies used to create such nitrogen doped carbons, and discuss the application of these novel materials. (orig.)

  10. Hyperbaric hydrothermal atomic force microscope

    Science.gov (United States)

    Knauss, Kevin G.; Boro, Carl O.; Higgins, Steven R.; Eggleston, Carrick M.

    2002-01-01

    A hyperbaric hydrothermal atomic force microscope (AFM) is provided to image solid surfaces in fluids, either liquid or gas, at pressures greater than normal atmospheric pressure. The sample can be heated and its surface imaged in aqueous solution at temperatures greater than 100.degree. C. with less than 1 nm vertical resolution. A gas pressurized microscope base chamber houses the stepper motor and piezoelectric scanner. A chemically inert, flexible membrane separates this base chamber from the sample cell environment and constrains a high temperature, pressurized liquid or gas in the sample cell while allowing movement of the scanner. The sample cell is designed for continuous flow of liquid or gas through the sample environment.

  11. Seawater bicarbonate removal during hydrothermal circulation

    Science.gov (United States)

    Proskurowski, G. K.; Seewald, J.; Sylva, S. P.; Reeves, E.; Lilley, M. D.

    2013-12-01

    High temperature fluids sampled at hydrothermal vents represent a complex alteration product of water-rock reactions on a multi-component mixture of source fluids. Sources to high-temperature hydrothermal samples include the 'original' seawater present in the recharge limb of circulation, magmatically influenced fluids added at depth as well as any seawater entrained during sampling. High-temperature hydrothermal fluids are typically enriched in magmatic volatiles, with CO2 the dominant species, characterized by concentrations of 10's-100's of mmol/kg (1, 2). Typically, the high concentration of CO2 relative to background seawater bicarbonate concentrations (~2.3 mmol/kg) obscures a full analysis of the fate of seawater bicarbonate during high-temperature hydrothermal circulation. Here we present data from a suite of samples collected over the past 15 years from high-temperature hydrothermal vents at 9N, Endeavour, Lau Basin, and the MAR that have endmember CO2 concentrations less than 10 mmol/kg. Using stable and radiocarbon isotope measurements these samples provide a unique opportunity to examine the balance between 'original' seawater bicarbonate and CO2 added from magmatic sources. Multiple lines of evidence from multiple hydrothermal settings consistently points to the removal of ~80% of the 'original' 2.3 mmol/kg seawater bicarbonate. Assuming that this removal occurs in the low-temperature, 'recharge' limb of hydrothermal circulation, this removal process is widely occurring and has important contributions to the global carbon cycle over geologic time. 1. Lilley MD, Butterfield DA, Lupton JE, & Olson EJ (2003) Magmatic events can produce rapid changes in hydrothermal vent chemistry. Nature 422(6934):878-881. 2. Seewald J, Cruse A, & Saccocia P (2003) Aqueous volatiles in hydrothermal fluids from the Main Endeavour Field, northern Juan de Fuca Ridge: temporal variability following earthquake activity. Earth and Planetary Science Letters 216(4):575-590.

  12. Catastrophic volcanic collapse: relation to hydrothermal processes.

    Science.gov (United States)

    López, D L; Williams, S N

    1993-06-18

    Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

  13. Cuerpos intrusivos asociados a las mineralizaciones polimetálicas del depósito Cerro León, área del anticlinal El Tranquilo, Santa Cruz: evidencias geofísicas Intrusive bodies associated with the polymetallic mineralization of the Cerro León deposit, area of Cerro Tranquilo anticline, Santa Cruz: Geophysical evidence

    OpenAIRE

    G. A Peñalva; S. M. Jovic; C. J. Chernicoff; D.M. Guido; I. Schalamuk

    2008-01-01

    Las características geológicas tales como presencia de cuerpos intrusivos y subvolcánicos someros básicos a intermedios y de las mineralizaciones con alto contenido de sulfuros del área del anticlinal El Tranquilo, son particulares y poco representadas en el macizo del Deseado. El depósito polimetálico vetiforme Cerro León presenta una signatura geoquímica-mineralógica que lo diferencia del clásico modelo epitermal de baja sulfuración característico del macizo del Deseado. Los datos aeromagné...

  14. Analisis neotectónico del área Cerro Salinas, departamento Sarmiento, provincia de San Juan Neotectonic analysis of the Cerro Salinas area, Sarmiento department, province of San Juan

    Directory of Open Access Journals (Sweden)

    Héctor Cisneros

    2010-12-01

    Full Text Available El cerro Salinas es una de las exposiciones más australes del basamento cristalino de las Sierras Pampeanas. Alrededor del mismo han sido reconocidos varios trazos de fallas caracterizados por escarpas rectilíneas de dirección submeridiana, que afectan a depósitos sedimentarios referidos al Terciario y Cuaternario. La actitud espacial de las fallas neotectónicas está controlada por la posición de la estratificación y de los contactos litológicos principales de las unidades terciarias, lo cual se ha interpretado preliminarmente como evidencia del flexodeslizamiento asociado al acortamiento andino. Esta situación guarda mucha similitud con el estilo de deformación de las principales zonas de fallamiento cuaternario de la Precordillera Oriental. Acorde con la distribución espacial de las deformaciones neotectónicas y de la geometría de las mismas, se dividió al área analizada en tres sectores. La principal estructura neotectónica, la falla Cerro Salinas, constituye el límite oeste tanto del cerro Salinas como de los afloramientos precuaternarios circundantes con una longitud reconocida de 15,77 km. Las observaciones realizadas en el área de estudio, principalmente al norte del mismo permiten indicar que la deformación en el frente de falla está vinculada a escarpas asociadas con fallas inversas propagantes. La discriminación cronológica de las unidades morfoestratigráficas cuaternarias se realizó en base a datos de multiparámetros y a la signatura de las superficies aluviales en imágenes Landsat ETM+ y ASTER, mediante procesamiento en base al método de componentes principales. En base a la sumatoria del desplazamiento vertical desarrollado por las escarpas de falla para el Pleistoceno tardío, se ha estimado una tasa de levantamiento mínima de 0,13 mm/año.The so called Cerro Salinas is one of the southernmost expressions of the Sierras Pampeanas crystalline basement. Several fault traces with N-S-trending rectilinear

  15. Paleomagnetism in the Determination of the Emplacement Temperature of Cerro Colorado Tuff Cone, El Pinacate Volcanic Field, Sonora, Mexico.

    Science.gov (United States)

    Rodriguez Trejo, A.; Alva-Valdivia, L. M.; Vidal Solano, J. R.; Garcia Amador, B.; Gonzalez-Rangel, J. A.

    2014-12-01

    Cerro Colorado Maar is located at the World Heritage Site, biosphere reserve El Pinacate and Gran Desierto del Altar, at the NNW region of Sonora, Mexico (in El Pinacate Volcanic Field). It is a tuff cone, about 1 km diameter, result of several phreatomagmatic episodes during the late Quaternary. We report paleomagnetic and rock magnetic properties from fusiform volcanic bombs obtained from the borders of Cerro Colorado. This study is based in the thermoremanent magnetization TRM normally acquired by volcanic rocks, which can be used to estimate the emplacement temperature range. We performed the experiments on 20 lithic fragments (10 cm to 20 cm approximately), taking 6-8 paleomagnetic cores from each. Rock magnetic experiments (magnetic susceptibility vs. temperature (k-T), hysteresis curves and FORC analysis, shows that the main magnetic mineral carriers of magnetization are titanomagnetite and titanohematite in different levels of intergrowth. The k-T curves suggest in many cases, only one magnetic phase, but also in other cases a second magnetic phase. Thermal demagnetization was used to demagnetize the specimens in detailed short steps and make a well-defined emplacement temperature determination ranges. We found that temperature emplacement determination range for these two magnetic phases is between 350-450 °C, and 550-580 °C, respectively. These results are consistent with those expected in an eruption of Surtsey type, showing a distinct volcanic activity compared to the other craters from El Pinacate volcanic field.

  16. Importaciones áticas del siglo V a.C. del Cerro del Prado (Algeciras, Cádiz

    Directory of Open Access Journals (Sweden)

    Cabrera, Paloma

    1996-12-01

    Full Text Available In this paper we analyze a group of Attic imports, found in the excavations of Cerro del Prado, a settlement situated in the Bahía de Algeciras (Cádiz. The great interest of this group lies in the fact that it belongs to a particular chronological period, the last third of the 5th century B.C., as we have not found later imports, and in the almost exclusive presence of black glazed vases, which gives US an idea of a very definitive demand of the punic society of the Iberian Peninsula regarding the trade of greek goods.

    Presentamos en este trabajo un conjunto de importaciones áticas halladas en las excavaciones del Cerro del Prado, situado en la bahía de Algeciras (Cádiz. El interés de este conjunto reside en su pertenencia a un momento cronológico muy concreto: el último tercio del siglo V a.C., no habiéndose hallado importaciones más modernas y en la presencia absoluta de vasos de barniz negro, lo que nos habla de una demanda muy determinada de la sociedad púnica peninsular frente al comercio de productos griegos.

  17. Analysis and simulatin of rock avalanche sequence in the Cerro Caquilluco landslide (Tacna, Peru)

    Science.gov (United States)

    Crosta, Giovanni B.; Frattini, Paolo; Valbuzzi, Elena; Hermanns, Reginald L.

    2014-05-01

    The Cerro Caquilluco (Tacna, Peru) rock avalanche complex has a total volume of about 15 km3 and a length of 43 km, extending from 3900 m a.s.l to 530 m a.s.l.. Based on geomorphological interpretation and lithological evidences, we reconstructed a possible rock-avalanches sequence consisting of at least nine major events. For each event, we calculated the mobilized volumes through the comparison of pre- and post-failure morphology. We argue that the first rock avalanche event corresponds to the Cerrillos Negros rock avalanche, characterized by a distal tongue shaped lobe, 11 km long, 3 km wide and 25 to 60 m thick (rough volume estimate 1.15 km3), deposited along the piedmont surface (average slope: 2° ). The reconstruction of pristine pre-failure morphology was accomplished by mimicking the preserved morphology close to the source area, and by removing the deposited volumes from the rock avalanche path. For this, we made the hypothesis that the old paleosurface was already eroded by valleys progressively moving upstream during a wetter climate, as suggested by Hoke et al (2007) for similar conditions in northern Chile. The reconstruction of the pre-event morphology required several attempts to fit the eroded and the deposited volumes. Finally, a total mobilized volume of about 10.2 km2 was obtained for this event. For the successive scenarios of slide retrogression, we used the morphologies obtained by previous scenarios as pre-failure morphologies, and we calculated, by difference with current topography, the lobe volumes. The volumes of single rock avalanche episodes decrease from the first to the last event, roughly following a power-law decay. This behavior is comparable to that described by Utili and Crosta (2011) for retrogressive instabilities in rocky cliffs. The rock-avalanche events have been simulated, to verify the different scenarios in terms of spreading area and maximum runout, by using SPH (Smooth Particle Hydrodynamics) and Finite Element codes

  18. El megadeslizamiento del cerro Uritorco, ladera occidental de la Sierra chica de Córdoba

    Directory of Open Access Journals (Sweden)

    Claudio A Carignano

    2014-03-01

    Full Text Available En el extremo norte de la Sierra Chica de Córdoba, sobre el flanco oeste del cerro Uritorco (1.949 m s.n.m., se ha identificado un megadeslizamiento (30°49'55,46"S y 64°29'50,31"O. Los materiales movilizados del frente del escarpe de la falla Sierra Chica, han cubierto parcialmente el granito de Capilla del Monte y los abanicos aluviales pleistocenos del piedemonte. El lóbulo y bloques rotados del deslizamiento conforman un alto topográfico que oficia de límite entre los valles de Punilla (al sur y de Charbonier (al noroeste. Mediante técnicas de procesamiento e interpretación de imágenes satelitales multiespectrales de media (Landsat-ETM y muy alta resolución (GeoEye-1, análisis digital del terreno a partir de modelos de elevación (SRTM y Aster-GDEM y el correspondiente control de campo, se ha delimitado y caracterizado esta megageoforma nunca antes advertida. Dada la elevada sismicidad actual e histórica de la zona y los indicios morfotectónicos que señalan como activas a las fallas Sierra Chica y Pajarillo-Copacabana-Masa, se estima que este deslizamiento posiblemente fue gatillado por un evento sísmico, acontecido en alguna de esas estructuras. Tanto el depósito del deslizamiento como su cicatriz de despegue presentan un significativo grado de erosión hídrica. Por análisis comparativos con otros deslizamientos ya datados y de características similares, situados en el escarpe occidental de las Sierras de San Luis, se le asigna una edad pleistocena medio-tardía. Por su volumen y características (2,1 x109 m³ se estableció que se trata de un megadeslizamiento único en las Sierras de Córdoba y constituye uno de los deslizamientos de mayor tamaño entre los registrados hasta el presente en Argentina.

  19. Dissolubility of Hydroxyapatite Powder under Hydrothermal Condition

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dissolubility of hydroxyapatite(HA) in the hydrothermal solution was investigated in Morey-type autoclave over a temperature range of 150 to 350 ℃ and the pH value range of 5 to 9. It is shown that the dissolubility of HA is determined as a function of temperature and time under a constant filling ratio of autoclave, and the temperature coefficient for the solubility of HA is positive. The equilibrium time attained in the hydrothermal solution is shortened with the increase of hydrothermal temperature, and the effect of temperature on the solubility is obviously stronger than that of pH value. The solubility data suggest that HA has higher dissolubility in the HA-H2O system under the hydrothermal condition than that under the normal temperature-pressure.

  20. Hydrothermal plumes and processes in Indian Ocean

    OpenAIRE

    Sands, Carla Marie

    2006-01-01

    The predicted cycling of the whole ocean through hydrothermal plumes is comparable to the mixing time of the oceans (few thousand years). Hence, understanding hydrothermal plume processes is crucial if their impact on the global geochemical cycles of elements is to be assessed. One of the most important processes that has been demonstrated to modify the gross chemical flux from venting to the oceans is the oxidative precipitation of dissolved Fe (II). It has been hypothesised t...

  1. Hydrothermal industrialization: direct heat development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  2. La «embajada oficiosa» de Indalecio Prieto en México durante la presidencia de Lázaro Cárdenas, 1939-1940

    Directory of Open Access Journals (Sweden)

    Mateos, Abdón

    2003-08-01

    Full Text Available The author tries to set Indalecio Prieto’s mission in Cárdenas’ Mexico within its political context, emphasizing the background of the relationship between the Spanish republican socialists and the Mexican leftist nationalists and its development from the 1920’s onwards. The present monograph is an account of the JARE’s management and of President L. Cárdenas’ policy towards the Spanish republican refugees until the beginning of Ávila Camacho’s presidency

    El autor contextualiza la misión de Indalecio Prieto en el México cardenista, destacando los antecedentes de las relaciones entre los republicanos-socialistas españoles y la izquierda nacionalista mexicana establecidas desde los años veinte. La monografía analiza la gestión de la JARE y la política de Lázaro Cárdenas hacia los refugiados republicanos españoles hasta el comienzo de la presidencia de Manuel Ávila Camacho.

  3. El frente de corrimiento andino al nivel de los cerros Penitentes y Visera (alta Cordillera de Mendoza: aspectos cronológicos y cartográficos

    Directory of Open Access Journals (Sweden)

    Jean-Claude Vicente

    2009-10-01

    Full Text Available El hallazgo de una iportante fauna de invertebrados marinos del Tithoniano superior a espaldas del cerro Penitentes en la secuencia carbonática basal de la primera escama del frente de corrimiento andino, confirma la lógica tectónica de un despegue de esta unidad a nivel del Yeso Principal y lleva a invalidar ciertas correlaciones litoestratigráficas y bosquejos paleogeográficos asignados a la Formación La Manga. Por otro lado, el análisis de algunos perfiles claves en torno al cerro Penitentes entre la quebrada Vargas y el cerro Visera permite presentar una reinterpretación tectónica del sector. Esta se sustenta en el reconocimiento y la diferenciación de las unidades terciarias básicas representadas por los Conglomerados Penitentes (Mioceno inferior y los Aglomerados Santa María (Mioceno superior en una relación muy similar a la descrita anteriormente al norte de Puente del Inca. El estudio permite seguir las interferencias, en un contexto polifásico, entre las reactivaciones del corrimiento Penitentes de piel fina y un cabalgamiento frontal de piel gruesa que repite la secuencia terciaria. La discordancia entre las secuencias terciarias y el emplazamiento de una klippe de Malm sobre los Conglomerados Penitentes del sinclinal del cerro Visera, conduce a otorgar cierta importancia a la fase del final del Mioceno inferior.

  4. The aggressiveness of the geothermal steam controlled; La agresividad del vapor geotermico controlada

    Energy Technology Data Exchange (ETDEWEB)

    Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1989-12-31

    The first two units of Cerro Prieto have generated electric energy since 1973; in 1988 completed 15 years of continuous operation, without corrosion problems in the turbines in spite of the utilization of geothermal steam. The experience and the good results obtained during the first years of operation of these two units of 37.5 MW each, were of great help for the Cerro Prieto extension, having as of this date an installed capacity of 620 MW. [Espanol] Las dos primeras unidades de Cerro Prieto han generado energia electrica desde 1973; cumplieron 15 anos de operacion continua en 1988, sin problemas de corrosion en las turbinas a pesar del uso de vapor geotermico. La experiencia y los buenos resultados obtenidos durante los primeros anos de operacion de estas dos unidades de 37.5 MW cada una fueron de gran apoyo para la aplicacion de Cerro Prieto, teniendose a la fecha 620 MW de capacidad instalada.

  5. Los granitos peraluminosos de las Sierras de Vinquis, Cerro Negro y Zapata (Sierras Pampeanas, provincia de Catamarca, Argentina

    Directory of Open Access Journals (Sweden)

    Medina, M. E.

    1992-12-01

    Full Text Available The studied plutons are close to several batholiths of this region, as Sierra de Mazán and other, but with some mineralogical peculiarities. The magmatic cordierite, common in proximate places, is scarce, as sillimanite, while the andalusite is very rare, with few tourmaline. Fluorite and allanite are also typical accasories only in the granites of the Sierra de Zapata. All plutons are peraluminous of potassic tendency, with cortical affinity.The interpretation of the geochemical values distinguishes between granites of different maturity, emplaced under a predominant influence of active margin for Cerro Negro and Vinquis, while the batholith of Zapata has, below these concepts, a marked feature of within plate.The mineralogical associations suggest that the granites of Cerro Negro and Vinquis were emplaced to pressures of 2 kb or less and temperature of 650º C, while the granites of Zapata had done under conditions of lesser pressure, between 1.5 and 2.0 kb and lower temperature, 600-650º C.A grandes rasgos, los plutones estudiados tienen semejanzas con otros del entorno regional, tal como los de la Sierra de Mazán, pero con peculiaridades mineralógicas. La cordierita magmática, que en lugares próximos es muy abundante, es aquí escasa, al igual que la sillimanita, mientras que la andalucita es muy rara y la turmalina poco frecuente. La fluorita y allanita son accesorios comunes y de cierta abundancia sólo en los granitos de la Sierra de Zapata.Todos los plutones son peralumínicos y de tendencia potásica, con neta afinidad cortical. El estudio estadístico de datos geoquímicos seleccionados, permite diferenciar agrupaciones que tienen un reflejo satisfactorio en los plutones caracterizados, por encima de las variaciones de facies. La interpretación de los valores geoquímicos distingue granitos de desigual madurez, emplazados bajo una influencia predominante de margen activo o intraplaca de características continentales, en

  6. A re-appraisal of the stratigraphy and volcanology of the Cerro Galán volcanic system, NW Argentina

    Science.gov (United States)

    Folkes, Christopher B.; Wright, Heather M.; Cas, Ray A.F.; de Silva, Shanaka L.; Lesti, Chiara; Viramonte, Jose G.

    2011-01-01

    From detailed fieldwork and biotite 40Ar/39Ar dating correlated with paleomagnetic analyses of lithic clasts, we present a revision of the stratigraphy, areal extent and volume estimates of ignimbrites in the Cerro Galán volcanic complex. We find evidence for nine distinct outflow ignimbrites, including two newly identified ignimbrites in the Toconquis Group (the Pitas and Vega Ignimbrites). Toconquis Group Ignimbrites (~5.60–4.51 Ma biotite ages) have been discovered to the southwest and north of the caldera, increasing their spatial extents from previous estimates. Previously thought to be contemporaneous, we distinguish the Real Grande Ignimbrite (4.68 ± 0.07 Ma biotite age) from the Cueva Negra Ignimbrite (3.77 ± 0.08 Ma biotite age). The form and collapse processes of the Cerro Galán caldera are also reassessed. Based on re-interpretation of the margins of the caldera, we find evidence for a fault-bounded trapdoor collapse hinged along a regional N-S fault on the eastern side of the caldera and accommodated on a N-S fault on the western caldera margin. The collapsed area defines a roughly isosceles trapezoid shape elongated E-W and with maximum dimensions 27 × 16 km. The Cerro Galán Ignimbrite (CGI; 2.08 ± 0.02 Ma sanidine age) outflow sheet extends to 40 km in all directions from the inferred structural margins, with a maximum runout distance of ~80 km to the north of the caldera. New deposit volume estimates confirm an increase in eruptive volume through time, wherein the Toconquis Group Ignimbrites increase in volume from the ~10 km3 Lower Merihuaca Ignimbrite to a maximum of ~390 km3 (Dense Rock Equivalent; DRE) with the Real Grande Ignimbrite. The climactic CGI has a revised volume of ~630 km3 (DRE), approximately two thirds of the commonly quoted value.

  7. Analisis neotectónico del área Cerro Salinas, departamento Sarmiento, provincia de San Juan

    Directory of Open Access Journals (Sweden)

    Héctor Cisneros

    2010-12-01

    Full Text Available El cerro Salinas es una de las exposiciones más australes del basamento cristalino de las Sierras Pampeanas. Alrededor del mismo han sido reconocidos varios trazos de fallas caracterizados por escarpas rectilíneas de dirección submeridiana, que afectan a depósitos sedimentarios referidos al Terciario y Cuaternario. La actitud espacial de las fallas neotectónicas está controlada por la posición de la estratificación y de los contactos litológicos principales de las unidades terciarias, lo cual se ha interpretado preliminarmente como evidencia del flexodeslizamiento asociado al acortamiento andino. Esta situación guarda mucha similitud con el estilo de deformación de las principales zonas de fallamiento cuaternario de la Precordillera Oriental. Acorde con la distribución espacial de las deformaciones neotectónicas y de la geometría de las mismas, se dividió al área analizada en tres sectores. La principal estructura neotectónica, la falla Cerro Salinas, constituye el límite oeste tanto del cerro Salinas como de los afloramientos precuaternarios circundantes con una longitud reconocida de 15,77 km. Las observaciones realizadas en el área de estudio, principalmente al norte del mismo permiten indicar que la deformación en el frente de falla está vinculada a escarpas asociadas con fallas inversas propagantes. La discriminación cronológica de las unidades morfoestratigráficas cuaternarias se realizó en base a datos de multiparámetros y a la signatura de las superficies aluviales en imágenes Landsat ETM+ y ASTER, mediante procesamiento en base al método de componentes principales. En base a la sumatoria del desplazamiento vertical desarrollado por las escarpas de falla para el Pleistoceno tardío, se ha estimado una tasa de levantamiento mínima de 0,13 mm/año.

  8. Eruptive history of the youngest Mexican Shield and Mexico's most voluminous Holocene eruption: Cerro El Metate

    Science.gov (United States)

    Oryaëlle Chevrel, Magdalena; Guilbaud, Marie-Noelle; Siebe, Claus

    2016-04-01

    Small to medium-sized shield volcanoes are an important component of many volcanic fields on Earth. The Trans-Mexican Volcanic Belt, one of the most complex and active continental arcs worldwide, displays a large number of such medium-sized volcanoes. In particular the Michoacán-Guanajuato Volcanic Field (MGVF) situated in central Mexico, is the largest monogenetic volcanic field in the world and includes more than 1000 scoria cones and about four hundred medium-sized volcanoes, also known as Mexican shields. The Mexican shields nevertheless represent nearly 70% of the total volume erupted since 1 Ma and hence played a considerable role in the formation of the MGVF. However, the source, storage, and transport as well as the physical properties (density, viscosity, volatile content, etc.) of the magmas involved in these eruptions remain poorly constrained. Here, we focus on Cerro El Metate, the youngest monogenetic andesite shield volcano of the field. New C14 dates for the eruption yield a young age (~AD 1250), which briefly precedes the initial rise of the Tarascan Empire (AD 1350-1521) in this region. This volcano has a minimum volume of ~9.2 km3 DRE, and its viscous lava flows were emplaced during a single eruption over a period of ~35 years covering an area of 103 km2. By volume, this is certainly the largest eruption during the Holocene in Mexico, and it is the largest andesitic effusive eruption known worldwide for this period. Such a large volume of lava erupted in a relatively short time had a significant impact on the environment (modification of the hydrological network, forest fires, etc.), and hence, nearby human populations probably had to migrate. Its eruptive history was reconstructed through detailed mapping, and geochemical and rheological analyses of its thick hornblende-bearing andesitic flows. Early and late flows have distinct morphologies, chemical and mineralogical compositions, and isotopic signatures which show that these lavas were fed by

  9. Hydrothermal processing of new fly ash cement

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, W.; Roy, D.M. (Materials Research Lab., Pennsylvania State Univ., University Park, PA (United States))

    1992-04-01

    The recent Mount Pinatubo volcanic eruption in the Philippines, in which at least 268 people died, shows that volcanic eruptions can be highly destructive. The eruption shot ash and debris over the countryside; six towns near the volcano faced a high risk of devastating mudslides, and nearly 2000 U.S. service members and their families were evacuated from two nearby military bases. However, this paper reports that not all the consequences of volcanic eruptions are bad. Under hydrothermal conditions, volcanic ash can be transformed into zeolitic tuff and, eventually, into clay minerals that constitute agricultural soils. The Materials Research Laboratory (MRL) has recently used some artificial pozzolanas (fly ash) that when mixed with lime, under hydrothermal conditions, also produced a new type of cementitious material. This was categorized as a new fly ash cement. The formation of a new hydrothermally treated wood-fiber-reinforced composite has also been demonstrated. It is apparent, however, that with respect to concerns about detailed knowledge of the reactivity of calcium silicate-based materials under hydrothermal conditions, the application of the technology far outweighs the understanding of the underlying principles of reactivity. It would seem that an understanding of reactions on the molecular level is just beginning, and that work on hydrothermal reactions is still a potentially lucrative area of research.

  10. The hydrothermal power of oceanic lithosphere

    Directory of Open Access Journals (Sweden)

    C. J. Grose

    2015-03-01

    Full Text Available We have estimated the power of ventilated hydrothermal heat transport, and its spatial distribution, using a set of recently developed plate models which highlight the effects of hydrothermal circulation and thermal insulation by oceanic crust. Testing lithospheric cooling models with these two effects, we estimate that global advective heat transport is about 6.6 TW, significantly lower than previous estimates, and that the fraction of that extracted by vigorous circulation on the ridge axes (<1 Ma is about 50% of the total, significantly higher than previous estimates. This low hydrothermal power estimate originates from the thermally insulating properties of oceanic crust in relation to the mantle. Since the crust is relatively insulating, the effective properties of the lithosphere are "crust dominated" near ridge axes (yielding lower heat flow, and gradually approach mantle values over time. Thus, cooling models with crustal insulation predict low heat flow over young seafloor, implying that the difference of modeled and measured heat flow is due to the heat transport properties of the lithosphere, in addition to ventilated hydrothermal circulation as generally accepted. These estimates may bear on important problems in the physics and chemistry of the Earth because the magnitude of hydrothermal power affects chemical exchanges between the oceans and the lithosphere, thereby affecting both thermal and chemical budgets in the oceanic crust and lithosphere, the subduction factory, and convective mantle.

  11. Cerro Colotlán: aproximación arqueo-lingüística para su estudio

    OpenAIRE

    Cabrero García, Ma. Teresa; Valiñas Coalla, Leopoldo

    2010-01-01

    Este trabajo se basa en los hallazgos arqueológicos y en los análisis etnohistórico y lingüístico hechos en la zona habitacional de Cerro Colotlán, cuyo centro ceremonial fue utilizado por los tepecanos hasta las primeras décadas del siglo XX. En las excavaciones realizadas al iniciar el año 2000 se descubrió un asentamiento más antiguo fechado entre 990 y 1275 d.C., con una arquitectura muy distinta a la de los restos de la superficie. Los análisis etnohistórico y lingüístico permiten postul...

  12. Evaluación integral del riesgo volcánico del Cerro Machín, Colombia

    OpenAIRE

    Leonel Vega Mora; Fernando Javier Díaz

    2013-01-01

    El volcán Cerro Machín (VCM) se encuentra situado en la Cordillera Central de Colombia. Por la com- posición química, magnitud y extensión de sus erupciones pasadas, se reconoce como un volcán explosivo de gran potencial de daño, cuya actividad futura podría afectar intensamente durante mucho tiempo (meses hasta años) una región muy estratégica para la economía del país, que cubre áreas pertenecientes a los departamentos de Tolima, Quindío, Valle del Cauca y Cundinamarca, en las cuales habita...

  13. Charnockitic ortho gneisses and mafic granulites of Cerro Olivo complex, proterozoic basement of SE Uruguay, Part 1: Geology

    International Nuclear Information System (INIS)

    Charnockitic ortho gneisses and mafic granulite s exposed in the Cerro Bori Block, in the center of Punta del Este terrain, were the first document occurrence of granulitic rocks from SE sector of the Uruguayan Shield. We present here their main geological features, with the purpose to suggest some petrologic and structural interesting problems for a future lithogeochemical, mineral chemistry, stable isotopes and fluid inclusion studies about these rocks. We propose some speculation form field-based studies considering a cognate magmatic origin of both kinds of rocks, previous to a homogeneous granulitic metamorphism. Some structural evidences indicate that after their uplift, these rocks were located on over thickened crust, at great to medium deepness. A cataclasis during anatexis and amphibolite-facies mineral association stabilization are common phenomena. Other evidences suggest a polycyclic character for the regional geologic evolution

  14. Estudio de la líqueno flora encontrada en el Cerro de Quininí, Tibacuy, Cundinamarca

    Directory of Open Access Journals (Sweden)

    Hormaza Francisco

    2000-12-01

    Full Text Available

    Se realizó un muestreo de la liquen o flora del cerro de Quininí, Tibacuy, Cundinamarca para estudiar las características morfológicas externas de los géneros de líquenes encontrados en el. A su vez se hizo la revisión bibliográfica acerca de dichos géneros, datando así la riqueza de líquenes en la zona con 8 géneros en total y con respecto al papel de bioindicadores se mostró el grado de intervención para el lugar.

  15. Microestructuras de deformación en rocas granulíticas, Cerro La Crespa, Tandilia, Provincia de Buenos Aires

    Directory of Open Access Journals (Sweden)

    Lucrecia Jorgensen

    2008-06-01

    Full Text Available El cerro La Crespa, localizado un kilómetro al sur de la megacizalla de Azul, integra las sierras de Azul, las cuales componen parte del Sistema de Tandilia. El presente trabajo trata sobre el estudio petrográfico-microestructural, donde se determina la composición modal y arreglos texturales a escala de grano y una primera caracterización geoquímica de rocas granulíticas aflorantes en el sector NO del cerro La Crespa. A partir de tales análisis, se intenta dilucidar los mecanismos de deformación actuantes y las condiciones metamórficas alcanzadas. Se reconocen rocas con texturas granoblásticas de composición básica e intermedia. Dichas rocas evidencian deformación frágil-dúctil heterogénea, con desarrollo de fábricas miloníticas, acaecida luego de que el evento metamórfico alcanzara su máximo desarrollo. Las texturas primitivas y la asociación de minerales anhidros presentes indicarían que dichas rocas podrían ser consideradas dentro de la serie de las granulitas. En las milonitas se aprecian significativos cambios mineralógicos, ya que al aumentar la deformación se incrementa la proporción de minerales hidratados y simultáneamente se reduce la cantidad de minerales anhidros. Estas modificaciones hacen suponer que la deformación actuó bajo condiciones metamórficas medias a altas, en facies de anfibolita superior-granulita inferior. Esta interpretación está apoyada por los mecanismos de deformación observados, a saber, recristalización dinámica de feldespatos, piroxenos, anfíboles, biotita y cuarzo; elongación de piroxenos y desarrollo de microboudinage.

  16. Los marsupiales (Mammalia del Mioceno Superior de la Formación Cerro Azul (Provincia de La Pampa, Argentina

    Directory of Open Access Journals (Sweden)

    Visconti, G.

    2000-04-01

    Full Text Available We describe the most complete South American marsupial association of Huayquerian Age (late Miocene. Specimens were recovered from several new localities of central and northern La Pampa province (central Argentina, at levels assignable to Cerro Azul Fm.: Bajo Giuliani, Quehué, Telén, El Guanaco, and Laguna Chillhué. Loessoid sediments studied from this formation are indicative of lacustrine deposits overlaid by eolian levels bearing evidences of pedogenesis. A study of these levels at each one of the new localities led to their correlation in an integrated profile of Cerro Azul Fm. This formation corresponds to «Epecuén Fm.», at least in Salinas Grandes de Hidalgo, and probably also to the upper levels of Arroyo Chasicá Fm. The studied marsupials are representative of almost all major lineages (orders of South American Neogene marsupials. The marmosine didelphid Zygolestes tatei sp. nov. differs from the type species of the genus in its larger size, unreduced third lower premolar, and in the less reduction of the metaconid in the last lower molar. Another marmosine, Thylamys pinei sp. nov., differs from other Marmosini in the twinning of the para- and metaconid in the lower molars, and in the wider talonid of the m4. The Monodelphini marmosines Thylatheridium hudsoni y T. dolgopolae are abundant in several localities of this formation; their study confirms close affinities between this genus and Monodelphis. The didelphines Hyperdidelphys pattersoni and an indeterminate species of Lutreolina are also represented by a few specimens. A mandibular fragment including part of the last molar may represent the oldest record of a Sparassocynidae in central Argentina. The Borhyaenidae and Thylacosmilidae (Sparassodonta are also recorded by a few, fragmentary specimens. Pliolestes venetus sp. nov. (Paucituberculata, Caenolestidae differs from the type species of the genus in its smaller size and in the larger, less displaced metaconid in the

  17. Constraining the Paleogene of South America: Magnetostratigraphy and paleoclimate proxy records from Cerro Bayo (Provincia de Salta, Argentina)

    Science.gov (United States)

    Hyland, E.; Cotton, J. M.; Sheldon, N. D.

    2012-12-01

    Records of rapid climatic and ecological shifts in the past are crucial for understanding global systems and for predicting future impacts of climate change. Transient and broad scale hyperthermal events during the Paleogene, such as the Paleocene-Eocene Thermal Maximum (PETM) and Early Eocene Climatic Optimum (EECO), have been studied extensively through both marine records and a significant terrestrial record from North America. Despite this, little evidence exists from the climatic and ecological histories of other major landmasses, which limits the effectiveness of global climate response predictions. Here we present an integrated paleoenvironmental reconstruction of the early Paleogene from a site in central South America (Cerro Bayo, Argentina), including a new magnetostratigraphic age model, pedological and sedimentological interpretation, whole rock geochemical climate proxies, isotopic environmental proxies, and microfloral assemblages. Cerro Bayo is a 235-meter terrestrial section that exposes the Tunal, Mealla, and Maiz Gordo Formations, and based on magnetostratigraphic interpolation spans roughly 58—50 Mya, including both the PETM and EECO events. These formations are composed primarily of reddish sandstone and siltstone, much of which exhibits features characteristic of a moderate degree of pedogenesis (i.e., Inceptisols and Alfisols). High-resolution climate proxies derived from paleosol geochemical compositions highlight rapid increases in mean annual temperature (>5°C) and precipitation (>300 mm yr-1) during the PETM, as well as more gradual increasing temperature and precipitation trends leading up to the EECO. Carbon isotope stratigraphy through the section also indicates a sizable negative excursion (~4‰) during the PETM, and generally positive isotopic trends during the early Eocene. Phytolith biostratigraphy also details changes in local vegetation composition during climatic events that corresponds to similar patterns seen in terrestrial

  18. Una fosa-vertedero de época vettona en el Cerro de la Mesa (Alcolea de Tajo, Toledo

    Directory of Open Access Journals (Sweden)

    Chapa Brunet, Teresa

    2013-06-01

    Full Text Available The existence of pits filled with earth, ashes, pottery fragments and fauna, usually known as ash pits, rubbish pits or dumps, has been recognized on many Second Iron Age settlements of the Spanish Northern Plateau, generally linked with Vaccean and Vettonian groups. However, its distribution should be extended to the west of the Southern Plateau and eastern Extremadura, as evidenced by the example of the Cerro de la Mesa village and indications coming from other western sites. We offer here a detailed study of part of a rubbish pit where certain domestic remains were withdrawn in connection with a new project of urbanisation of the Vettonian village held on the transition from the 3rd to the 2nd centuries BC.La existencia de fosas rellenas con tierra, cenizas, fragmentos cerámicos y fauna denominadas genéricamente como cenizales, basureros o vertederos, es un hecho bien conocido en la Meseta Norte durante la Segunda Edad del Hierro, vinculándose con los grupos Vacceos y Vettones. Sin embargo, su distribución debe ampliarse al occidente de la Meseta Sur y oriente extremeño, como se evidencia tanto en el Cerro de la Mesa como a través de indicios documentados en otros yacimientos más occidentales. Se presenta aquí un detallado estudio de un sector de la fosa que actuó como vertedero para la retirada de ciertos restos domésticos con ocasión de la reurbanización en profundidad del poblado vettón que tuvo lugar en la transición del siglo III al II a.C.

  19. Stress controlled magma-earthquake interaction during unrest at Chiles-Cerro Negro Volcanoes (Ecuador-Colombian border)

    Science.gov (United States)

    Ebmeier, S. K.; Elliott, J. R.; Nocquet, J. M.; Biggs, J.; Mothes, P. A.; Lundgren, P.; Samsonov, S. V.; Jarrin, P.; Yepez, M.; Aguaiza, S.

    2015-12-01

    The movement of fluids beneath a volcano can cause deformation, and therefore changes to the subsurface stress field that manifest in swarms of low magnitude (Chiles-Cerro Negro volcanoes on the Ecuador-Colombian border. These volcanoes were previously considered to be historically inactive, but between 2013 and early 2015 there were three episodes of unrest characterised by VT swarms of increasing energy and duration. GPS measurements at two stations near Volcán Chiles show inflation over a time period of approximately twenty days prior to the 20th October, consistent with the intrusion of magma at half space depths >13 km. This inflation took place during a swarm of VT seismicity with thousands of low magnitude events per day and culminated in a M 5.6 earthquake on the 20th October, when inflation abruptly ceased. We measure coseismic displacements from the M 5.6 earthquake with data from three independent InSAR platforms and find that they are consistent with shallow slip of 1.2 m on an oblique reverse fault. This fault plane would have experienced positive Coulomb stress changes from some of the range of potential sources consistent with the inflation. Magmatic intrusion could therefore have contributed to the loading on the fault directly through stress changes caused by pressurisation, and indirectly through the decrease in effective friction coefficient due to elevated pore fluid pressure. The cessation of inflation immediately after the moderate earthquake suggests a link between the two events. We expect slip on the fault plane identified from the InSAR data to have resulted in compression in the shallow crust south of Volcán Chiles, above the source that had previously been inflating. This would have inhibited further ascent of magma. The Chiles-Cerro Nego unrest provides rare observations of interaction between magmatic intrusion and a moderate earthquake during volcanic unrest.

  20. Characterization of advanced preprocessed materials (Hydrothermal)

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Garold Gresham

    2012-09-01

    The initial hydrothermal treatment parameters did not achieve the proposed objective of this effort; the reduction of intrinsic ash in the corn stover. However, liquid fractions from the 170°C treatments was indicative that some of the elements routinely found in the ash that negatively impact the biochemical conversion processes had been removed. After reviewing other options for facilitating ash removal, sodium-citrate (chelating agent) was included in the hydrothermal treatment process, resulting in a 69% reduction in the physiological ash. These results indicated that chelation –hydrothermal treatment is one possible approach that can be utilized to reduce the overall ash content of feedstock materials and having a positive impact on conversion performance.

  1. Hydrothermal treatment of electric arc furnace dust.

    Science.gov (United States)

    Yu, Bing-Sheng; Wang, Yuh-Ruey; Chang, Tien-Chin

    2011-06-15

    In this study, ZnO crystals were fabricated from electric arc furnace dust (EAFD) after alkaline leaching, purification and hydrothermal treatment. The effects of temperature, duration, pH, and solid/liquid ratio on ZnO crystal morphology and size were investigated. Results show a high reaction temperature capable of accelerating the dissolution of ZnO precursor, expediting the growth of 1D ZnO, and increasing the L/D ratio in the temperature range of 100-200°C. ZnO crystals with high purity can also be obtained, using the one-step hydrothermal treatment with a baffle that depends on the different solubility of zincite and franklinite in the hydrothermal conditions.

  2. The BGU/CERN solar hydrothermal reactor

    CERN Document Server

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  3. Cuerpos intrusivos asociados a las mineralizaciones polimetálicas del depósito Cerro León, área del anticlinal El Tranquilo, Santa Cruz: evidencias geofísicas Intrusive bodies associated with the polymetallic mineralization of the Cerro León deposit, area of Cerro Tranquilo anticline, Santa Cruz: Geophysical evidence

    Directory of Open Access Journals (Sweden)

    G. A Peñalva

    2008-03-01

    Full Text Available Las características geológicas tales como presencia de cuerpos intrusivos y subvolcánicos someros básicos a intermedios y de las mineralizaciones con alto contenido de sulfuros del área del anticlinal El Tranquilo, son particulares y poco representadas en el macizo del Deseado. El depósito polimetálico vetiforme Cerro León presenta una signatura geoquímica-mineralógica que lo diferencia del clásico modelo epitermal de baja sulfuración característico del macizo del Deseado. Los datos aeromagnéticos del área del anticlinal El Tranquilo permiten reconocer una conspicua anomalía subcircular que se interpreta como un intrusivo no aflorante, de aproximadamente 9 km de diámetro, que subyace al Grupo El Tranquilo y a la Formación Roca Blanca; su profundidad se estima en 1400 m. Este cuerpo intrusivo genera el domamiento regional del anticlinal El Tranquilo y el fracturamiento radial asociado. La interpretación de la presencia de pequeños cuerpos intrusivos y subvolcánicos o apófisis alimentados por el cuerpo intrusivo mayor, asociados con anomalías magnéticas de menor diámetro y mayor gradiente, está confirmada por datos de perforación. Las principales vetas del depósito Cerro León se ubican asociadas espacialmente con los cuerpos intrusivos y subvolcanicos someros no aflorantes. Esto, sumado al alto contenido de sulfuros y la signatura geoquímica y mineralógica de las vetas, sugiere que posiblemente estén asociadas genéticamente a los cuerpos intrusivos subyacentes y circundantes, y permite utilizar este modelo como una herramienta de prospección para este tipo de depósitos.The geologic characteristics such as presence of basic to intermediate intrusive and subvolcanic bodies, and the mineralization with high sulfide content of the El Tranquilo anticline area are peculiar and poorly represented in the Deseado Massif. The Cerro León polymetallic deposit presents a geochemical and mineralogical signature that is

  4. Decree 343/012. Is regulated the servitude established by Decree-Law 10,383, on several lines of electricity conduction -150 KV to be built in the departments of Florida, Cerro Largo, Maldonado, Flores, San Jose and Tacuarembo

    International Nuclear Information System (INIS)

    This decree regulates the establishment of electricity conduction in Florida, Cerro Largo, Maldonado, Flores, San Jose and Tacuarembo towns. These electrical lines are necessary to provide the public service by UTE

  5. The fate of lignin during hydrothermal pretreatment

    OpenAIRE

    Trajano, Heather L.; Engle, Nancy L.; Foston, Marcus; Ragauskas, Arthur J.; Tschaplinski, Timothy J; Wyman, Charles E

    2013-01-01

    Abstract Background Effective enzymatic hydrolysis of lignocellulosic biomass benefits from lignin removal, relocation, and/or modification during hydrothermal pretreatment. Phase transition, depolymerization/repolymerization, and solubility effects may all influence these lignin changes. To better understand how lignin is altered, Populus trichocarpa x P. deltoides wood samples and cellulolytic enzyme lignin (CEL) isolated from P. trichocarpa x P. de...

  6. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    DEFF Research Database (Denmark)

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric;

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  7. Formation of zirconia polymorphs under hydrothermal conditions

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHl; Erwei(施尔畏); Li; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HUXingfang(胡行方)

    2002-01-01

    Using zirconium oxychloride solution as precursor, monoclinic zirconia crystallites withnarrow distribution of nanosize were obtained in the hydrothermal reaction. However, when thereaction was in weak acidic medium or base medium, whether directly using the colloidal precipi-tate prepared from zirconium salt solutions with base solution as precursor added, or using theprecipitate after filtrating, washing and drying treatments as precursor, the product of the hydro-thermal reaction was the mixture of both monoclinic and tetragonal polymorphs. As the pH of themedium rises, the content of tetragonal phase in the product, the morphologies and size of thecrystallites all change. There are three types of formation mechanisms under hydrothermal condi-tion, which can be called as saturation-precipitation mechanism in homogeneous solution, dissolu-tion-crystallization mechanism and in-situ crystallization mechanism, respectively. The formationmechanism of crystallites varies with different hydrothermal conditions, such as the states of theprecursor and the pH of the medium, which lead to changes in the phases, morphologies andsizes of the resulting crystallites.

  8. Microestructuras de deformación en rocas granulíticas, Cerro La Crespa, Tandilia, Provincia de Buenos Aires Deformation microstructures in granulitic rocks, Cerro La Crespa, Tandilia, province of Buenos Aires

    Directory of Open Access Journals (Sweden)

    Lucrecia Jorgensen

    2008-06-01

    Full Text Available El cerro La Crespa, localizado un kilómetro al sur de la megacizalla de Azul, integra las sierras de Azul, las cuales componen parte del Sistema de Tandilia. El presente trabajo trata sobre el estudio petrográfico-microestructural, donde se determina la composición modal y arreglos texturales a escala de grano y una primera caracterización geoquímica de rocas granulíticas aflorantes en el sector NO del cerro La Crespa. A partir de tales análisis, se intenta dilucidar los mecanismos de deformación actuantes y las condiciones metamórficas alcanzadas. Se reconocen rocas con texturas granoblásticas de composición básica e intermedia. Dichas rocas evidencian deformación frágil-dúctil heterogénea, con desarrollo de fábricas miloníticas, acaecida luego de que el evento metamórfico alcanzara su máximo desarrollo. Las texturas primitivas y la asociación de minerales anhidros presentes indicarían que dichas rocas podrían ser consideradas dentro de la serie de las granulitas. En las milonitas se aprecian significativos cambios mineralógicos, ya que al aumentar la deformación se incrementa la proporción de minerales hidratados y simultáneamente se reduce la cantidad de minerales anhidros. Estas modificaciones hacen suponer que la deformación actuó bajo condiciones metamórficas medias a altas, en facies de anfibolita superior-granulita inferior. Esta interpretación está apoyada por los mecanismos de deformación observados, a saber, recristalización dinámica de feldespatos, piroxenos, anfíboles, biotita y cuarzo; elongación de piroxenos y desarrollo de microboudinage.This work deals with a petrographic- microstructural study in order to determine the modal composition and textural arrangement on a grain scale and the first geochemistry characterization of granulitic rocks on the NW of the cerro La Crespa, which is located about 1 km south of the Azul Megashear and forms part of the sierras de Azul in the Tandilia System

  9. Composición, estructura y diversidad del cerro El Águila, Michoacán, México Composition, structure and diversity of the cerro El Águila, Michoacán, Mexico

    Directory of Open Access Journals (Sweden)

    Luis Eduardo Zacarias-Eslava

    2011-09-01

    Full Text Available Se describe la composición, estructura y diversidad de la vegetación presente en el cerro El Águila, Michoacán. Se reconocieron fisonómicamente 5 tipos de vegetación y en cada uno se establecieron 16 parcelas circulares de 400 m² (3.2 ha para censar los individuos leñosos ≥ 10 cm d.a.p., con una parcela anidada de 100 m² (0.8 ha para los individuos entre 2.5 y 9.9 cm d.a.p. El muestreo incluyó 46 especies agrupadas en 33 géneros y 21 familias. Los bosques tropical caducifolio y de Quercus deserticola tuvieron los valores más bajos de altura promedio ( 11 m y área basal (> 40 m²/ha. La diversidad fue mayor en el bosque tropical caducifolio (S=23 y α =5.4 y menor en el de Quercus-Pinus (S= 13 y α= 2.71. En general, los tipos de vegetación mostraron diferentes especies dominantes y una alta diversidad beta. La composición y estructura de estas comunidades puede asociarse a cambios en altitud y a la perturbación por actividades humanas. No obstante, la zona de estudio aún presenta áreas en buen estado de conservación, particularmente los bosques templados hacia las zonas con mayor altitud, por lo que se sugiere que en un futuro cercano sea incluida dentro de alguna categoría de protección estatal.This study describes composition, structure and diversity of vegetation in the Cerro El Águila, Michoacán. Five plant communities were recognized and for each one all woody individuals ≥10 cm DBH were tallied in sixteen 400 m² circular plots, whereas individuals between 2.5 and 9.9 cm DBH were measured in a 100 m² circular sub-plot centered within each larger plot. A total of 46 species, 33 genera and 21 families were recorded. The tropical deciduous forest and Quercus deserticola forest had low values of mean plant height ( 11 m and basal area (> 40 m²/ha. Diversity was greater in the tropical deciduous forest (S= 23 and α= 5.4, respectively and lower in the oak-pine forest (S= 13 and α= 2.71. All communities displayed

  10. Anhydrite precipitation in seafloor hydrothermal systems

    Science.gov (United States)

    Theissen-Krah, Sonja; Rüpke, Lars H.

    2016-04-01

    The composition and metal concentration of hydrothermal fluids venting at the seafloor is strongly temperature-dependent and fluids above 300°C are required to transport metals to the seafloor (Hannington et al. 2010). Ore-forming hydrothermal systems and high temperature vents in general are often associated with faults and fracture zones, i.e. zones of enhanced permeabilities that act as channels for the uprising hydrothermal fluid (Heinrich & Candela, 2014). Previous numerical models (Jupp and Schultz, 2000; Andersen et al. 2015) however have shown that high permeabilities tend to decrease fluid flow temperatures due to mixing with cold seawater and the resulting high fluid fluxes that lead to short residence times of the fluid near the heat source. A possible mechanism to reduce the permeability and thereby to focus high temperature fluid flow are mineral precipitation reactions that clog the pore space. Anhydrite for example precipitates from seawater if it is heated to temperatures above ~150°C or due to mixing of seawater with hydrothermal fluids that usually have high Calcium concentrations. We have implemented anhydrite reactions (precipitation and dissolution) in our finite element numerical models of hydrothermal circulation. The initial results show that the precipitation of anhydrite efficiently alters the permeability field, which affects the hydrothermal flow field as well as the resulting vent temperatures. C. Andersen et al. (2015), Fault geometry and permeability contrast control vent temperatures at the Logatchev 1 hydrothermal field, Mid-Atlantic Ridge, Geology, 43(1), 51-54. M. D. Hannington et al. (2010), Modern Sea-Floor Massive Sulfides and Base Metal Resources: Toward an Estimate of Global Sea-Floor Massive Sulfide Potential, in The Challenge of Finding New Mineral Resources: Global Metallogeny, Innovative Exploration, and New Discoveries, edited by R. J. Goldfarb, E. E. Marsh and T. Monecke, pp. 317-338, Society of Economic Geologists

  11. Voltammetric Investigation Of Hydrothermal Iron Speciation

    Directory of Open Access Journals (Sweden)

    Charlotte eKleint

    2016-05-01

    Full Text Available Hydrothermal vent fluids are highly enriched in iron (Fe compared to ambient seawater, and organic ligands may play a role in facilitating the transport of some hydrothermal Fe into the open ocean. This is important since Fe is a limiting micronutrient for primary production in large parts of the world`s surface ocean. We have investigated the concentration and speciation of Fe in several vent fluid and plume samples from the Nifonea vent field, Coriolis Troughs, New Hebrides Island Arc, South Pacific Ocean using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV with salicylaldoxime (SA as the artificial ligand. Our results for total dissolved Fe (dFe in the buoyant hydrothermal plume samples showed concentrations up to 3.86 µM dFe with only a small fraction between 1.1% and 11.8% being chemically labile. Iron binding ligand concentrations ([L] were found in µM level with strong conditional stability constants up to log K[L],Fe3+ of 22.9. Within the non-buoyant hydrothermal plume above the Nifonea vent field, up to 84.7% of the available Fe is chemically labile and [L] concentrations up to 97 nM were measured. [L] was consistently in excess of Felab, indicating that all available Fe is being complexed, which in combination with high Felab values in the non-buoyant plume, signifies that a high fraction of hydrothermal dFe is potentially being transported away from the plume into the surrounding waters, contributing to the global oceanic Fe budget.

  12. The rules of urban planning and administrative responsibilities in protecting to the vulnerability and risk of Cerro Tapezco in Santa Ana

    International Nuclear Information System (INIS)

    An analysis of regulation is made of land use and administrative management of the Cerro Tapezco to show that as the years have passed it has been verified that the Costa Rican law on town planning has been inadequate for current problems due to lack of updating of various scientific and technical sources also dispersion and proliferation of competences of administrative authorities. The physical setting and planning rules is identified for CerroTapezco and surrounding towns. Local actions are explored in the elaboration of improvement and reform of the regulatory plan of Santa Ana. The administrative entities and institutions with competence in the development and implementation of plans have been identified, assessing deficiencies, inconsistencies and administrative omissions in urban planning of the city of Santa Ana and recommending changes necessary for the proper application of the Costa Rican law

  13. Effects of the Cerro Grande Fire (Smoke and Fallout Ash) on Soil Chemical Properties Within and Around Los Alamos National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Fresquez, P.R.; Velasquez, W.R.; Naranjo, L. Jr.

    2000-11-01

    Soil surface (0- to 2-in. depth) samples were collected from areas within and around Los Alamos National Laboratory (LANL) just after the Cerro Grande fire, analyzed for radionuclides, radioactivity, and trace elements (heavy metals), and compared to soil samples collected in 1999 from the same sites. In addition, many types of organic substances (volatile and semivolatile organic compounds, organochlorine pesticides, polychlorinated biphenyls, high explosives, and dioxin and dioxin-like compounds) were assessed in soils from LANL, perimeter, and regional sites after the fire. Results show that impacts to regional, perimeter, and on-site (mesa top) areas from smoke and fallout ash as a result of the Cerro Grande fire were minimal.

  14. Evaluation of the Cerro Solo nuclear ore, province of Chubut. Geological characteristics of the deposit and of the basin. Pt. 2

    International Nuclear Information System (INIS)

    The Cerro Solo uranium ore deposit, is located 420 km west from Trelew city, Chubut province, in the extra-andean. The geologic environment belongs to the northwest edge portion of the intracratonic San Jorge Gulf Basin. The uraniferous district is named Pichinanes Ridge district. The mineralization lies 25 to 130 m depth, and is hosted by Los Adobes formation aged Aptian-Albian, made up by conglomerates, sandstones, coarse-sandstones and less abundant siltstones and claystones. The Cerro Solo ore deposit that belongs to the sandstone type-uranium occurrences are lenticular or tabular shaped, associated with organic material and pyrite, generally roughly parallel to the bedding (Trend-Type). The uranium minerals are uraninite and coffinite associated with organic material and pyrite, and frequently hematite, goethite, calcite, siderite and barite are observed. (Author)

  15. Pucarilla-Cerro Tipillas volcanic complex: the oldest recognized caldera in the southeastern portion of central volcanic zone of Central Andes?

    Energy Technology Data Exchange (ETDEWEB)

    Guzman, Silvina; Petrinovic, Ivan [CONICET -IBIGEO. Museo de Cs. Naturales, Universidad de Salta, Mendoza 2 (4400), Salta (Argentina)], E-mail: guzmansilvina@gmail.com

    2008-10-01

    We recognize the most eastern and oldest collapse caldera structure in the southern portion of the Central Volcanic Zone of the Andes. A description of Middle-Upper Miocene successions related to explosive- effusive events is presented. The location of this centre close to Cerro Galn Caldera attests a recurrence in the volcanism between 12 and 2 Ma in this portion of the Altiplano - Puna Plateau.

  16. Moche social boundaries and settlement dynamics at Cerro Castillo (c. AD 600-1000), Nepeña Valley, Peru Volume 1

    OpenAIRE

    Rengifo, Carlos

    2014-01-01

    This dissertation explores the pre-Columbian occupation at Cerro Castillo, a coastal settlement in the Nepeña Valley, Peru. The study examines the site’s internal organisation as well as its relationship with regional cultural phenomena during its most important period of occupation (circa AD 600-1000). Characterising the Moche presence at the site is one of the main subjects of this investigation. Moche was one of the grandest civilisations that developed in the pre-Columbian ...

  17. Cerro Grande Fire Impact to Water Quality and Stream Flow near Los Alamos National Laboratory: Results of Four Years of Monitoring

    Energy Technology Data Exchange (ETDEWEB)

    B.M. Gallaher; R.J. Koch

    2004-09-15

    In May 2000, the Cerro Grande fire burned about 7400 acres of mixed conifer forest on the Los Alamos National Laboratory (LANL), and much of the 10,000 acres of mountainside draining onto LANL was severely burned. The resulting burned landscapes raised concerns of increased storm runoff and transport of contaminants by runoff in the canyons traversing LANL. The first storms after the fire produced runoff peaks that were more than 200 times greater than prefire levels. Total runoff volume for the year 2000 increased 50% over prefire years, despite a decline in total precipitation of 13% below normal and a general decrease in the number of monsoonal thunderstorms. The majority of runoff in 2000 occurred in the canyons at LANL south of Pueblo Canyon (70%), where the highest runoff volume occurred in Water Canyon and the peak discharge occurred in Pajarito Canyon. This report describes the observed effects of the Cerro Grande fire and related environmental impacts to watersheds at and near Los Alamos National Laboratory (LANL) for the first four runoff seasons after the fire, from 2000 through 2003. Spatial and temporal trends in radiological and chemical constituents that were identified as being associated with the Cerro Grande fire and those that were identified as being associated with historic LANL discharges are evaluated with regard to impacts to the Rio Grande and area reservoirs downstream of LANL. The results of environmental sampling performed by LANL, the New Mexico Environment Department (NMED), and U.S. Geological Survey (USGS) after the Cerro Grande fire are included in the evaluation. Effects are described for storm runoff, baseflow, stream sediments, and area regional reservoir sediment.

  18. Evaluación integral del riesgo volcánico del Cerro Machín, Colombia

    Directory of Open Access Journals (Sweden)

    Leonel Vega Mora

    2013-01-01

    Full Text Available El volcán Cerro Machín (VCM se encuentra situado en la Cordillera Central de Colombia. Por la com- posición química, magnitud y extensión de sus erupciones pasadas, se reconoce como un volcán explosivo de gran potencial de daño, cuya actividad futura podría afectar intensamente durante mucho tiempo (meses hasta años una región muy estratégica para la economía del país, que cubre áreas pertenecientes a los departamentos de Tolima, Quindío, Valle del Cauca y Cundinamarca, en las cuales habitan cerca de un millón de personas. En este artículo se muestra la metodología y resultados del estudio de “Evaluación Integral del Riesgo del Cerro Machín – Colombia”, realizado durante 2009 por el Grupo PIGA de Investigación en Política, Información y Gestión Ambiental de la Facultad de Ingeniería de la Universidad Nacional de Colombia, tomando como punto de partida el estudio de “Evaluación de la Amenaza Volcánica Potencial del Cerro Machín” adelantado en el 2002 por el Servicio Geológico Colombiano (SGC. En consecuencia, se genera y ajusta una nueva ecuación para la determinación del riesgo, basada en la valoración de índices de amenaza intrínseca e índices de vulnerabilidad, los primeros en función del grado de intensidad, duración, extensión y acumulación de las amenazas, y los segundos, en función del grado de exposición espacial y temporal de los elementos (sociales, económicos, institucionales y ecosisté- micos y de su capacidad de respuesta intrínseca y extrínseca ante las amenazas. Con estas ecuaciones y mediante el uso de sistemas de información geográfica (SIG, se realiza para cada escenario de análisis considerando la modelación geoespacial del riesgo a nivel de cada pixel cartográfico del área territorial de estudio. En esta modelación se integra toda la informa- ción territorial del área en estudio, lo que permite obtener, de acuerdo con el marco lógico de evaluación preestablecido

  19. Análisis litoestratigráfico de la Formación Cerro Azul (Mioceno Superior en la provincia de La Pampa

    Directory of Open Access Journals (Sweden)

    Graciela Visconti

    2010-10-01

    Full Text Available La Formación Cerro Azul fue definida en 1980 para incluir a las sedimentitas continentales pliocenas (limolitas arenosas y areniscas limosas que afloran de manera discontinua en casi todo el ámbito de la provincia de La Pampa. No obstante, varias investigaciones paleontológicas realizadas a partir de la segunda mitad de la década del 80' han permitido ubicar geocronológicamente a la unidad en el intervalo 10 Ma a 5,8-5,7 Ma. El objetivo del trabajo es realizar un análisis de las características litoestratigráficas de la Formación Cerro Azul de acuerdo al Código Argentino de Estratigrafía. Se propone un lectoestratotipo para la unidad, consistente en el perfil de Algarrobo del Águila y un perfil auxiliar en cerro El Morro. También se establecieron las relaciones estratigráficas con otras formaciones. Se interpreta un paleoambiente depositacional de llanura, donde alternan depósitos de loess con numerosos paleosuelos, detectándose escasos depósitos lacustres en la base y pocos cursos fluviales.

  20. Geographic Information System (GIS) Emergency Support for the May 2000 Cerro Grande Wildfire, Los Alamos, New Mexico, USA

    Energy Technology Data Exchange (ETDEWEB)

    C.R.Mynard; G.N.Keating; P.M.Rich; D.R. Bleakly

    2003-05-01

    In May 2000 the Cerro Grande wildfire swept through Los Alamos, New Mexico, burning approximately 17,400 ha (43,000 acres) and causing evacuation of Los Alamos National Laboratory (LANL) and the communities of Los Alamos and White Rock. An integral part of emergency response during the fire was the use of geographic information system (GIS) technology, which continues to be used in support of post-fire restoration and environmental monitoring. During the fire Laboratory GIS staff and volunteers from other organizations worked to produce maps and provide support for emergency managers, including at an emergency GIS facility in Santa Fe. Subsequent to the fire, Laboratory GIS teams supported the multiagency Burned Area Emergency Rehabilitation (BAER) team to provide GIS data and maps for planning mitigation efforts. The GIS teams continue to help researchers, operations personnel, and managers deal with the tremendous changes caused by the fire. Much of the work is under the auspices of the Cerro Grande Rehabilitation Project (CGRP) to promote recovery from fire damage, improve information exchange, enhance emergency management, and conduct mitigation activities. GIS efforts during the fire provided important lessons about institutional matters, working relationships, and emergency preparedness. These lessons include the importance of (1) an integrated framework for assessing natural and human hazards in a landscape context; (2) a strong GIS capability for emergency response; (3) coordinated emergency plans for GIS operations; (4) a method for employees to report their whereabouts and receive authoritative information during an evacuation; (5) GIS data that are complete, backed-up, and available during an emergency; (6) adaptation of GIS to the circumstances of the emergency; (7) better coordination in the GIS community; (8) better integration of GIS into LANL operations; and (9) a central data warehouse for data and metadata. These lessons are important for planning

  1. Evidence for Hydrothermal Vents as "Biogeobatteries" (Invited)

    Science.gov (United States)

    Nielsen, M. E.; Girguis, P. R.

    2010-12-01

    Hydrothermal vents are unique systems that play an important role in oceanic biogeochemical cycles. As chemically reduced hydrothermal fluid mixes with cold oxic seawater, minerals precipitate out of solution resulting in chimney structures composed largely of metal sulfides and anhydrite. Pyrite, which is a natural semi-conductor, is the primary sulfide mineral, but other minerals within chimneys are also conductive (e.g. chalcopyrite, wurtzite, and some iron oxides). Sulfide chimneys are also known to host an extensive endolithic microbial community. Accordingly, submarine hydrothermal systems appear to be examples of biogeobatteries, wherein conductive mineral assemblages span naturally occuring redox gradients and enable anaerobic microbes to access oxygen as an oxidant via extracellular electron transfer (or EET). To test this hypothesis, we ran a series of electrochemical laboratory experiments in which pyrite was used as an anode (in a vessel flushed with hydrothermal-like fluid). When placed in continuity with a carbon fiber cathode, pyrite was found to accept and conduct electrons from both abiotic and biological processes (microbial EET). Specifically, electrical current increased 4-fold (5 nA/m2 to 20 nA/m2) in response to inoculation with a slurry prepared from a hydrothermal vent sample. Inspection of the pyrite anode with SEM revealed ubiquitous coverage by microbes. DNA was extracted from the anodes and the inoculum, and was subjected to pyrosequencing to examine prokaryotic diversity. These data suggest that key microbial phylotypes were enriched upon the pyrite, implicating them in EET. In addition, we deployed an in situ experiment based on microbial fuel cell architecture with a graphite anode inserted into a vent wall coupled to a carbon fiber cathode outside the vent. We observed current production over the course of one year, implying microbial EET in situ. Via pyrosequencing, we observed that the microbial community on the anode was

  2. Pyrite Recrystallization Experiments With Circulating Hydrothermal Solution

    Science.gov (United States)

    Isobe, H.; Abe, A.; Tanaka, K.

    2007-12-01

    Pyrite is one of the most common sulfide minerals found in hydrothermal deposits and sea-floor sediments from hydrothermal fumaroles. Hydrothermal fluid flow plays an important role in crystallization of sulfide minerals. In this study, we tried to reproduce pyrite crystallization with one-way flowing hydrothermal fluid. We designed a circuit circulating hydrothermal fluid by thermal convection. A rectangular circuit (42.6 cm by 17.3 cm) of SUS316 pressure tubes with 5 mm in inner diameter was used as a reaction vessel. In the circuit, pyrite dissolves to acidic fluid in upstream region. Then, pyrite will crystallize again in downstream region as temperature decreases. The rectangular plane was held to be 20 degrees inclination to generate thermal convection. One of the long sides of the rectangular was heated by an electric furnace. Starting materials were put in a tube to be heated. Upper half, approximately 20 cm, of the tube was filled with quartz sand. Next quarter was filled with equivalent mass mixture of quartz sand and powdered pyrite crystals. The lowest quarter was filled with mixture of quartz sand, pyrite, anhydrite and sulfur, those mass are equivalent. The solution was a mixture of 0.5mol/l HCl and 3.0mol/l NaCl. Maximum temperature was controlled to approximately 350°C at the center of the heated tube. Experimental durations were up to 9 days. Fluid pressure increased to approximately 6 MPa as heating. After the experiments, the run products were fixed with resin in a sample tube, and vertical sections were observed by SEM. In the run products, pyrite dissolved at the lower part of the starting material. In the upper half of the sample tube, pyrite crystals precipitated on quartz surface. Crystallization density depends on temperature gradient of the fluid. Predominant morphology of the pyrite crystals consists (100) plains. Tiny framboidal aggregates and crystals with (210) plains also occur. In the run products of longer than 3 days run durations

  3. Evolving patterns of the fluids within the TAG hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The mixing of seawater/hydrothermal fluid within the large seafloor hydrothermal sulfide deposits plays a key role in the formation processes of the sulfide deposits.Some issues attract considerable attentions in the study of seafloor hydrothermal system in recent years,such as the relationships among different types of vent fluids,the characteristics of chemical compositions and mineral assemblages of the hydrothermal deposits and their governing factors.Combined with the measured data of hydrothermal fluid in the TAG field,the thermodynamic model of mixing processes of the heated seawater at different temperatures and the hydrothermal fluid is calculated to understand the precipitation mechanism of anhydrite and the genetic relationships between the black and white smoker fluids within the TAG mound.The results indicate that the heating of seawater and the mixing of hydrothermal fluid/seawater are largely responsible for anhydrite precipitation and the temperature of the heated seawater is not higher than 150 ℃ and the temperature of the end-member hydrothermal fluid is not lower than 400℃.Based on the simulated results,the evolving patterns of fluids within the TAG deposit are discussed.The mixed fluid of the end-member hydrothermal fluid and the seawater heated by wall rock undergoes conductive cooling during upflowing within the deposit and forms "White Smoker" eventually.In addition,the end-member hydrothermal fluid without mixed with seawater,but undergoing conductive cooling,vents out of the deposit and forms "Black Smoker".

  4. Hydrothermal synthesis of sodium titanate nanotubes

    International Nuclear Information System (INIS)

    From suspension of nanoparticles TiO2 in concentrated water solution of NaOH were prepared by hydrothermal synthesis sodium titanates particles with different shapes. Influence of synthesis duration under temperature 180 grad C on the change of particles shapes was observed. The result of experiment showed that one day synthesis resulted to obtained product with high content of nanotubes, but the extension of this period led to the transformation of product's shape into stripes. From the results of experiment follows that as a precursor for TiO2 nanotubes preparation may be used only products of hydrothermal synthesis, which duration of pressure synthesis was not longer than 24 hours. (authors)

  5. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  6. The Cerro Bitiche Andesitic Field: petrological diversity and implications for magmatic evolution of mafic volcanic centers from the northern Puna

    Science.gov (United States)

    Maro, Guadalupe; Caffe, Pablo J.

    2016-07-01

    The Cerro Bitiche Andesitic Field (CBAF) is one of the two largest mafic volcanic fields in northern Puna (22-24° S) and is spatially and temporally associated with ignimbrites erupted from some central Andean Altiplano-Puna Volcanic Complex calderas. The CBAF comprises seven scoria cones and widespread high-K calcalkaline lava flows that cover an area of 200 km2. Although all erupted rocks have a relatively narrow chemical range (56-62 % SiO2, 3-6 % MgO), there is a broad diversity of mineral compositions and textures. The least evolved lavas (˜58-61 % SiO2) are high-Mg andesites with scarce (<10 %) microphenocrysts of either olivine or orthopyroxene. The small compositional range and low phenocryst content indicate evolution controlled by low percentages (<10 %) of fractional crystallization of olivine and clinopyroxene of magmas similar to the least evolved rocks from the field, accompanied by assimilation during rapid ascent through the crust. Evolved andesites (˜62 wt% SiO2), on the other hand, are porphyritic rocks with plagioclase + orthopyroxene + biotite and ubiquitous phenocryst disequilibrium textures. These magmas were likely stored in crustal reservoirs, where they experienced convection caused by mafic magma underplating, magma mixing, and/or assimilation. Trace element and mineral compositions of CBAF lavas provide evidence for complex evolution of distinct magma batches.

  7. Dieta de murciélagos nectarívoros del Parque Nacional Cerros de Amotape, Tumbes

    Directory of Open Access Journals (Sweden)

    Edith Arias

    2011-07-01

    Full Text Available En el Perú se reporta la presencia de 18 especies de murciélagos nectarívoros, sin embargo se cuenta con poca información sobre la dieta de estas especies. En este estudio se reporta por primera vez la dieta de los nectarívoros Glossophaga soricina, Lonchophylla hesperia y Anoura geoffroyi en el bosque seco ecuatorial y del bosque tropical del Pacífico del Parque Nacional Cerros de Amotape, Tumbes. Analizamos 21 contenidos gastrointestinales e identificamos ocho morfotipos de polen pertenecientes a las familias Bombacaceae, Cactaceae, Fabaceae, Solanaceae, Rubiaceae, Myrtaceae, Malvaceae y Rosaceae. Encontramos evidencia del síndrome de quiropterofilia en Bombacaceae, Cactaceae, Fabaceae, Solanaceae y Rubiaceae. Observamos que A. geoffroyi consume polen de Ceiba trichistandra, Solanaceae y Rubiacea; G. soricina consume de Abutilon reflexum, Armathocereus cartwrightianus, C. trichistandra y Rubiaceae; y L. hesperia de A. cartwrightianus, Eriobotrya japonica, Fabaceae y Psidium sp.; sugiriendo una dieta generalista en estas especies. Los murciélagos G. soricina y A. geoffroyi comparten el consumo del ceibo C. trichistandra y de la Rubiaceae, mientras que G. soricina comparte con L. hesperia el consumo del cactus A. cartwrightianus. Los otros morfotipos de polen no fueron compartidos entre murciélagos. Se encuentra además que el ceibo C. trichistandra fue la especie más consumida, especialmente por G. soricina.

  8. Late Quaternary vegetation, fire and climate history reconstructed from two cores at Cerro Toledo, Podocarpus National Park, southeastern Ecuadorian Andes

    Science.gov (United States)

    Brunschön, Corinna; Behling, Hermann

    2009-11-01

    The last ca. 20,000 yr of palaeoenvironmental conditions in Podocarpus National Park in the southeastern Ecuadorian Andes have been reconstructed from two pollen records from Cerro Toledo (04°22'28.6"S, 79°06'41.5"W) at 3150 m and 3110 m elevation. Páramo vegetation with high proportions of Plantago rigida characterised the last glacial maximum (LGM), reflecting cold and wet conditions. The upper forest line was at markedly lower elevations than present. After ca. 16,200 cal yr BP, páramo vegetation decreased slightly while mountain rainforest developed, suggesting rising temperatures. The trend of increasing temperatures and mountain rainforest expansion continued until ca. 8500 cal yr BP, while highest temperatures probably occurred from 9300 to 8500 cal yr BP. From ca. 8500 cal yr BP, páramo vegetation re-expanded with dominance of Poaceae, suggesting a change to cooler conditions. During the late Holocene after ca. 1800 cal yr BP, a decrease in páramo indicates a change to warmer conditions. Anthropogenic impact near the study site is indicated for times after 2300 cal yr BP. The regional environmental history indicates that through time the eastern Andean Cordillera in South Ecuador was influenced by eastern Amazonian climates rather than western Pacific climates.

  9. El patrimonio industrial petrolero en la Patagonia: Comodoro Rivadavia (Argentina y Cerro Sombrero (Chile. Una perspectiva comparada

    Directory of Open Access Journals (Sweden)

    Pía Acevedo Méndez

    2016-01-01

    Full Text Available El hallazgo de petróleo en Comodoro Rivadavia (Chubut, Argentina y en Manantiales (Tierra del Fuego, lado chileno, motivó la construcción de espacios socioproductivos bajo el modelo de Company Towns. En el caso argentino la empresa estatal Yacimientos Petrolíferos Fiscales (Y.P.F creó el Campamento Central y la Empresa Nacional del Petróleo (ENAP creó Cerro Sombrero en Chile, los que en la década de 1970 formaron dos tejidos urbanos (barrio en el caso argentino y pueblo en el caso chileno. En esta dinámica se transformó el modo de habitar de ambos espacios, que se convirtieron en potenciales elementos turísticos, teniendo en cuenta que desde el año 2014 poseen reconocimiento patrimonial relacionado con su pasado petrolero y su arquitectura moderna. El objetivo es comparar cómo ambas empresas petroleras estatales construyeron dichos espacios “urbanos” y sus comunidades sociolaborales e indagar en la relación identidad/ patrimonio de ypefeanos y enapinos.

  10. U and Th Concentration and Isotopic Composition of Hydrothermal Fluids at the Lost City Hydrothermal Field

    Science.gov (United States)

    Ludwig, K. A.; Shen, C.; Cheng, H.; Edwards, R.; Kelley, D. S.; Butterfield, D. A.

    2006-12-01

    Uranium and Th concentration and isotopic composition of hydrothermal fluids at the Lost City Hydrothermal Field (LCHF) were determined using multi-collector inductively coupled plasma mass spectrometry (MC-ICP- MS). The LCHF is an off-axis, serpentinite-hosted hydrothermal system located at 30°N near the Mid- Atlantic Ridge. Carbonate chimneys reaching 60 m in height vent alkaline (pH~10), calcium-rich fluids at 40- 91°C and the towers are home to dense microbial communities. Vent fluid and seawater U and Th concentration and isotopic composition data provide critical information for constraining U-Th chimney ages. The increased sensitivity (1-2%) of MC-ICP-MS combined with an Aridus nebulization system allows the precise measurement of small quantities of sample (~150 ml) with low concentrations (Thorium concentrations of fluids are close to deep seawater values. U and Th isotopic compositions are reported at the permil level. These data may provide new insights into the role of serpentinite-hosted hydrothermal systems in the budgets of U and Th in the ocean. Techniques presented in this study may be applied to other hydrothermal and seep environments.

  11. Hydrothermal pretreatments of macroalgal biomass for biorefineries

    DEFF Research Database (Denmark)

    Ruiz, Héctor A.; Rodríguez-Jasso, Rosa M.; Aguedo, Mario;

    2015-01-01

    in accordance with the integrated biorefineries. Furthermore, biorefinery concept requires processes that allow efficient utilization of all components of the biomass. The pretreatment step in a biorefinery is often based on hydrothermal principles of high temperatures in aqueous solution. Therefore......ecently, macroalgal biomass is gaining wide attention as an alternative in the production of biofuels (as bioetanol and biogas) and compounds with high added value with specific properties (antioxidants, anticoagulants, anti–inflammatories) for applications in food, medical and energy industries...

  12. Stable light isotope biogeochemistry of hydrothermal systems

    Science.gov (United States)

    Des Marais, D. J.

    1996-01-01

    The stable isotopic composition of the elements O, H, S and C in minerals and other chemical species can indicate the existence, extent, conditions and the processes (including biological activity) of hydrothermal systems. Hydrothermal alteration of the 18O/16O and D/H values of minerals can be used to detect fossil systems and delineate their areal extent. Water-rock interactions create isotopic signatures which indicate fluid composition, temperature, water-rock ratios, etc. The 18O/16O values of silica and carbonate deposits tend to increase with declining temperature and thus help to map thermal gradients. Measurements of D/H values can help to decipher the origin(s) of hydrothermal fluids. The 34S/32S and 13C/12C values of fluids and minerals reflect the origin of the S and C as well as oxygen fugacities and key redox processes. For example, a wide range of 34S/32S values which are consistent with equilibration below 100 degrees C between sulfide and sulfate can be attributed to sulfur metabolizing bacteria. Depending on its magnitude, the difference in the 13C/12C value of CO2 and carbonates versus organic carbon might be attributed either to equilibrium at hydrothermal temperatures or, if the difference exceeds 1% (10/1000), to organic biosynthesis. Along the thermal gradients of thermal spring outflows, the 13C/12C value of carbonates and 13C-depleted microbial organic carbon increases, principally due to the outgassing of relatively 13C-depleted CO2.

  13. Surface roughened zirconia: towards hydrothermal stability.

    Science.gov (United States)

    Camposilvan, Erik; Flamant, Quentin; Anglada, Marc

    2015-07-01

    Surface roughness is needed in several yttria-stabilized zirconia components used in restorative dentistry for osseointegration or adhesion purposes. This can be achieved by different treatments, which may also modify the microstructure of the surface. Among them, sandblasting and chemical etching are widely used, but their effect on hydrothermal aging of zirconia is not fully understood. In the present work, the zirconia long-term stability of rough surfaces prepared by these techniques is analyzed and a method is proposed for preventing hydrothermal aging while maintaining the original surface appearance and mechanical properties. The method involves pressure infiltration of a Cerium salt solution on the roughened surfaces followed by a thermal treatment. The solution, trapped by surface defects and small pores, is decomposed during thermal treatment into Cerium oxide, which is diffused at high temperature, obtaining Ce co-doping in the near-surface region. In addition, the microstructural changes induced in the near-surface by sandblasting or chemical etching are removed by the thermal treatment together with surface defects. No color modification was observed and the final roughness parameters were in the range of existing implants of proved good osseointegration. The aging resistance of Ce co-doped materials was strongly enhanced, showing the absence of aging after artificial degradation, increasing in this way the surface mechanical integrity. The proposed treatment is easily applicable to the current manufacturing procedures of zirconia dental posts, abutments, crowns and dentures, representing a solution to hydrothermal aging in these and other biomedical applications.

  14. Hydrothermal synthesis of zeolites from natural stellerite

    Institute of Scientific and Technical Information of China (English)

    李酽; 汪信; 董元彩; 朱俊武

    2002-01-01

    Y and P zeolites were synthesized hydrothermally from natural stellerite under different conditions and were characterized via XRD and FT-IR.The results show that the higher crystallinity of Y zeolite can be obtained in hydrothermal system with low alkalinity,low Ca2+/Na+ ratio,and high SiO2/Al2O3 ratio.The lattice space of the samples decreases as crystallization time increases.P Zeolite is prompted under condition of higher alkalinity and higher Ca2+/Na+ ratio.The intensity and number of bands in the range of 400 cm-1~900 cm-1 increases with reaction time.Bands at 680 cm-1,760 cm-1 and 860 cm-1 corresponding to Y zeolite appear during the crystallization stage.Most of these bands shift to higher wavenumbers when SiO2/Al2O3 ratio increases generally.In the hydrothermal system with reverse condition above,bands at 600 cm-1,420 cm-1~470 cm-1 hardly change as the crystallization time increases and the main crystal phase of P zeolite is obtained.

  15. Surface roughened zirconia: towards hydrothermal stability.

    Science.gov (United States)

    Camposilvan, Erik; Flamant, Quentin; Anglada, Marc

    2015-07-01

    Surface roughness is needed in several yttria-stabilized zirconia components used in restorative dentistry for osseointegration or adhesion purposes. This can be achieved by different treatments, which may also modify the microstructure of the surface. Among them, sandblasting and chemical etching are widely used, but their effect on hydrothermal aging of zirconia is not fully understood. In the present work, the zirconia long-term stability of rough surfaces prepared by these techniques is analyzed and a method is proposed for preventing hydrothermal aging while maintaining the original surface appearance and mechanical properties. The method involves pressure infiltration of a Cerium salt solution on the roughened surfaces followed by a thermal treatment. The solution, trapped by surface defects and small pores, is decomposed during thermal treatment into Cerium oxide, which is diffused at high temperature, obtaining Ce co-doping in the near-surface region. In addition, the microstructural changes induced in the near-surface by sandblasting or chemical etching are removed by the thermal treatment together with surface defects. No color modification was observed and the final roughness parameters were in the range of existing implants of proved good osseointegration. The aging resistance of Ce co-doped materials was strongly enhanced, showing the absence of aging after artificial degradation, increasing in this way the surface mechanical integrity. The proposed treatment is easily applicable to the current manufacturing procedures of zirconia dental posts, abutments, crowns and dentures, representing a solution to hydrothermal aging in these and other biomedical applications. PMID:25867636

  16. Hydrothermal synthesis of xonotlite from carbide slag

    Institute of Scientific and Technical Information of China (English)

    Jianxin Cao; Fei Liu; Qian Lin; Yu Zhang

    2008-01-01

    Carbide slag was used as the calcareous materials for the first time to prepare xonotlite via dynamic hydrothermal synthesis.The effects of influential factors including different calcination temperatures,pretreatment methods of the carbide slag and process param-eters of hydrothermal synthesis on the microstructure and morphology of xonotlite were explored using XRD and SEM techniques.The results indicate that the carbide slag after proper calcination could be used to prepare pure xonotlite;and different calcination tern-peratures have little effect on the crystallinity of synthesized xonotlitc,but have great impact on the morphology of secondary particles.The different pretreatment methods of the carbide slag pose great impact on the crystallinity and morphology of secondary particles of xonotlite.Xonotlite was also synthesized from pure CaO under the salne experimental conditions as that prepared from calcined carbide slag for comparison.Little amount of impurities in carbide slag has no effect on the mechanism of hydrothermal synthesizing xonotlite from carbide slag.

  17. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems.

  18. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems. PMID:26684507

  19. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    Science.gov (United States)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  20. The Trans-Atlantic Geotraverse hydrothermal field: A hydrothermal system on an active detachment fault

    Science.gov (United States)

    Humphris, Susan E.; Tivey, Margaret K.; Tivey, Maurice A.

    2015-11-01

    Over the last ten years, geophysical studies have revealed that the Trans-Atlantic Geotraverse (TAG) hydrothermal field (26°08‧N on the Mid-Atlantic Ridge) is located on the hanging wall of an active detachment fault. This is particularly important in light of the recognition that detachment faulting accounts for crustal accretion/extension along a significant portion of the Mid-Atlantic Ridge, and that the majority of confirmed vent sites on this slow-spreading ridge are hosted on detachment faults. The TAG hydrothermal field is one of the largest sites of high-temperature hydrothermal activity and mineralization found to date on the seafloor, and is comprised of active and relict deposits in different stages of evolution. The episodic nature of hydrothermal activity over the last 140 ka provides strong evidence that the complex shape and geological structure of the active detachment fault system exerts first order, but poorly understood, influences on the hydrothermal circulation patterns, fluid chemistry, and mineral deposition. While hydrothermal circulation extracts heat from a deep source region, the location of the source region at TAG is unknown. Hydrothermal upflow is likely focused along the relatively permeable detachment fault interface at depth, and then the high temperature fluids leave the low-angle portion of the detachment fault and rise vertically through the highly fissured hanging wall to the seafloor. The presence of abundant anhydrite in the cone on the summit of the TAG active mound and in veins in the crust beneath provides evidence for a fluid circulation system that entrains significant amounts of seawater into the shallow parts of the mound and stockwork. Given the importance of detachment faulting for crustal extension at slow spreading ridges, the fundamental question that still needs to be addressed is: How do detachment fault systems, and the structure at depth associated with these systems (e.g., presence of plutons and/or high

  1. PATRONES DE CONSUMO FINAL DE CÉRVIDOS EN EL PARANÁ MEDIO: EL CASO DEL SITIO CERRO AGUARÁ / Cervids final consumption patterns in middle Paraná River: the case of Cerro Aguará archaeological site

    Directory of Open Access Journals (Sweden)

    Leonardo Mucciolo

    2015-06-01

    Full Text Available Los cérvidos fueron amplia y regularmente explotados por los cazadores-recolectores que habitaron la macroregión del Paraná-Plata durante el Holoceno tardío. En la cuenca media del Paraná, sin embargo, muy pocos estudios han enfocado sobre las estrategias empleadas para su obtención, procesamiento y consumo. Teniendo en cuenta esto, el objetivo de este trabajo es explorar dichos aspectos a partir del análisis de los conjuntos de cérvidos provenientes del sitio arqueológico Cerro Aguará, localizado en el departamento General Obligado (provincia de Santa Fe. La perspectiva seleccionada propone al consumo como factor preponderante en la configuración del registro zooarqueológico dentro del continuum de actividades que componen la explotación faunística. Desde esta perspectiva, y tomando en consideración que las carcasas de los cérvidos proveen distintos tipos de recursos alimenticios con diferentes costos de extracción (carne, médula y grasa ósea, se evalúan diferentes indicadores para establecer si existió diferente intensidad en su procesamiento. Los resultados indican que las dos especies de cérvidos identificadas en el sitio, Blastocerus dichotomus y Ozotoceros bezoarticus, ocuparon un rol preponderante en la dieta, aunque las carcasas del primero fueron empleadas más intensivamente probablemente en correlación con su mayor disponibilidad de nutrientes internos, tales como la médula y posiblemente la grasa ósea.  Abstract  Cervids were wide and regularly exploited by several Late Holocene hunter-gatherers inhabiting Paraná Plata macroregion. In the middle Paraná river, however, few research has been made on strategies involving their procurement, processing and consumption. The purpose of this article is to explore those aspects from the analysis of cervid assemblages of Cerro Aguará archaeological site (General Obligado, Santa Fe province. The selected perspective proposes final consumption as one of the most

  2. Control estructural de las mineralizaciones de fluorita del batolito Cerro Áspero, Sierras Pampeanas de Córdoba Structural control of vein-type fluorite deposits of Cerro Áspero batholith, Sierras Pampeanas of Córdoba

    Directory of Open Access Journals (Sweden)

    Jorge E Coniglio

    2010-12-01

    Full Text Available Con más de 1.000.000 t de reservas totales el batolito Cerro Áspero, magmatismo devónico de alto potasio, es portador de las mayores concentraciones de fluorita de las Sierras Pampeanas. Las vetas epitermales son de edad cretácica, subverticales, poseen potencias generalmente menores a 3 m y se extienden a profundidades mayores a 200 metros. Ocurren en un área de 440 km² con una distribución intrabatolítica predominante. La geometría y la cinemática de las estructuras mineralizadas son consistentes con deformación por cizalla simple, dextrógira, con el eje extensional principal (σ3 orientado hacia el NNO. Esta situación implantó en el área estructuras extensionales N70ºE ( 4 km de corrida, que presentan patrones de fallas transcurrentes, con bifurcaciones, deflexiones, aperturas, saltos, cierres y fracturas en échelon asociadas. Los estudios texturales y estructurales en las vetas han permitido distinguir cuatro estadios sucesivos de mineralización que fueron controlados por una actividad discontinua de la cupla dextral. Este modelo estructural es similar a aquéllos propuestos para mineralizaciones de fluorita emplazadas en otros sectores del continente durante el mismo período, los que vinculan el control tectónico con la apertura del océano Atlántico sur. El registro del relleno hidrotermal permitió reconstruir la historia de apertura de las estructuras y puede usarse como un criterio efectivo de prospección y exploración. Las mayores concentraciones de mineral ocurren en las estructuras extensionales y en las flexiones dilatantes de las estructuras asociadas con la zona de cizallamiento principal NNE-SSO, que registran la secuencia mineralizada completa.With over 1,000,000 t of total reserves, the high-K devonian granites of the Cerro Áspero batholith (440 km² are the most important fluorite-bearing granitic suite in the Sierras Pampeanas. The epithermal fluorite veins, of Cretaceous age, fill in steeply dipping

  3. Heat and mass flux estimation of modern seafloor hydrothermal activity

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; WANG Xingtao; YU Zenghui

    2006-01-01

    Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97.359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4.11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in-situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.

  4. Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza

    Directory of Open Access Journals (Sweden)

    Federico Fuentes

    2008-03-01

    Full Text Available El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánicas pliocenas a recientes de composición intermedia a básica, y depósitos cuaternarios inconsolidados. El cerro Guanaquero, un estratovolcán pliocuaternario intensamente erosionado por glaciares pleistocenos, con sus 4.841 metros es el rasgo orográfico más prominente. Está constituido esencialmente por andesitas grises porfíricas, piroxénicas a biotíticas. Intercaladas con las coladas andesíticas se presentan depósitos piroclásticos, aglomerados volcánicos, ignimbritas y basaltos. La datación de una andesita por el método K-Ar en roca total arrojó una edad de 1,4 ± 0,1 Ma. La deformación ándica comenzó en forma de una faja plegada y corrida de piel fina, con pliegues por despegue en el sector occidental y por propagación de falla en el oriental. La compresión al oeste de los 69º47´O terminó por invertir la fallas normales del rift mesozoico. A lo largo de este meridiano se encuentra la falla más importante de la región, la que se ha correlacionado con la falla Malargüe, bien desarrollada en latitudes más australes. Esta falla limita la faja plegada y corrida del Aconcagua, de naturaleza epidérmica, y la faja plegada y corrida de Malargüe, controlada por la inversión tectónica del basamento. El volcanismo fue muy intenso en el Plioceno y el Cuaternario, correspondiendo a un período de empinamiento de la placa oceánica subducida, en el que la región ha sido levantada pasivamente. La alta resistencia a la erosión de

  5. Targeting organic molecules in hydrothermal environments on Mars

    Science.gov (United States)

    Parnell, J.; Bowden, S. A.; Lindgren, P.; Wilson, R.; Cooper, J. M.

    2008-09-01

    Hydrothermal deposits on Mars Hydrothermal systems are proposed as environments that could support organic synthesis, the evolution of life or the maintenance of life [1,2,3]. They have therefore been suggested as primary targets for exploration on Mars [1,2,4,].There is now confidence that hydrothermal deposits occur at the martian surface. This is based on a range of criteria that could point towards hydrothermal activity, including volcanic activity, magmatic-driven tectonism, impact cratering in icy terrains, hydrous alteration of minerals and typical hydrothermal mineralogies [4]. The proposals to search for evidence of life at martian hydrothermal sites have been focussed on seeking morphological evidence of microbial activity [5]. Here we discuss the potential to seek a chemical signature of organic matter in hydrothermal systems. Organics in terrestrial hydrothermal systems Terrestrial hydrothermal systems can have large quantities of organic matter because they intersect organic-rich sedimentary rocks or oil reservoirs. Thus the signatures that they contain reflect some preexisting concentration of fossil organic compounds, rather than life which was active in the hydrothermal system. If any extant life was incorporated in these hydrothermal systems, it is swamped by the fossil molecules. Examples of environments where organic materials may become entrained include subsurface hydrothermal mineral deposits, generation of hydrothermal systems by igneous intrusions, and hot fluid venting at the seafloor. Nevertheless, there is value in studying the interactions of hydrothermal systems with fossil organic matter, for information about the survivability of organic compounds, phase relationships between carbonaceous and noncarbonaceous materials, and where in hydrothermal deposits to find evidence of organic matter. Microbial colonization of hot spring systems is feasible at depth within the systems and at the surface where the hydrothermal waters discharge

  6. Sedimentología y evolución paleoambiental de la Formación Patquía (Pérmico en el extremo sur de la sierra de Maz y cerro Bola, provincia de La Rioja, Argentina Sedimentology and palaeoenvironmental evolution of the Patquía Formation (Permian, in the Sierra de Maz and cerro Bola, La Rioja Province, Argentina

    Directory of Open Access Journals (Sweden)

    A. T. Caselli

    2002-12-01

    Full Text Available En este trabajo se analizan las características sedimentológicas de la Formación Patquía en la Sierra de Maz y en el Cerro Bola (perfiles de cerro Guandacol, La Cortadera, cerro Noqués y cerro Bola, donde fueron reconocidas siete asociaciones de facies. La facies A está compuesta por aglomerados, brechas y conglomerados depositados en pequeños abanicos aluviales. Areniscas gruesas y conglomerados integran la facies B, la que fue probablemente depositada en planicies fluviales entrelazadas. La facies C incluye conglomerados y areniscas gruesas correspondientes a sistemas fluviales de baja sinuosidad. La facies D es la más extendida regionalmente y está compuesta por sabulitas, areniscas, pelitas y tobas, interpretadas como cursos fluviales de elevada sinuosidad. Un episodio de sedimentación eólica está registrado en la facies E, constituida por areniscas finas a medianas mostrando estratificación entrecruzada de gran escala. La facies F, areniscas y pelitas interestratificadas, fue depositada en lagos clásticos, someros y permanentes. La facies G incluye areniscas blanquecinas y pelitas rosadas, con intercalaciones de areniscas finas con estratificación entrecruzada de gran escala, sedimentadas en sistemas fluviales sinuosos con migración de dunas eólicas en las planicies. La composición modal de las areniscas permite identificar tres petrofacies. La cuarzoféldica representa el aporte del basamento de las Sierras Pampeanas. La cuarzofeldlítica incluye fragmentos de volcanitas ácidas y mesosilícicas relacionadas a la faja volcánica Permo-Triásica ubicada al oeste. La litomíxtica está dominada por líticos sedimentarios y paleovolcánicos provenientes de la Precordillera. Finalmente, el análisis estratigráfico de las facies arriba descriptas permitió la identificación de dos secuencias depositacionales.The sedimentological characteristics of the Patquía Formation in the Sierra de Maz and Cerro Bola areas were analyzed

  7. Columnar jointing in vapor-phase-altered, non-welded Cerro Galán Ignimbrite, Paycuqui, Argentina

    Science.gov (United States)

    Wright, Heather M.; Lesti, Chiara; Cas, Ray A.F.; Porreca, Massimiliano; Viramonte, Jose G.; Folkes, Christopher B.; Giordano, Guido

    2011-01-01

    Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10−3–8.5 × 10−2°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.

  8. Columnar jointing in vapor-phase-altered, non-welded Cerro Galán Ignimbrite, Paycuqui, Argentina

    Science.gov (United States)

    Wright, Heather M. N.; Lesti, Chiara; Cas, Raymond A. F.; Porreca, Massimiliano; Viramonte, José G.; Folkes, Chris B.; Giordano, Guido

    2011-12-01

    Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10-3-8.5 × 10-2°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.

  9. Control estructural de las mineralizaciones de fluorita del batolito Cerro Áspero, Sierras Pampeanas de Córdoba

    Directory of Open Access Journals (Sweden)

    Jorge E Coniglio

    2010-12-01

    Full Text Available Con más de 1.000.000 t de reservas totales el batolito Cerro Áspero, magmatismo devónico de alto potasio, es portador de las mayores concentraciones de fluorita de las Sierras Pampeanas. Las vetas epitermales son de edad cretácica, subverticales, poseen potencias generalmente menores a 3 m y se extienden a profundidades mayores a 200 metros. Ocurren en un área de 440 km² con una distribución intrabatolítica predominante. La geometría y la cinemática de las estructuras mineralizadas son consistentes con deformación por cizalla simple, dextrógira, con el eje extensional principal (σ3 orientado hacia el NNO. Esta situación implantó en el área estructuras extensionales N70ºE ( 4 km de corrida, que presentan patrones de fallas transcurrentes, con bifurcaciones, deflexiones, aperturas, saltos, cierres y fracturas en échelon asociadas. Los estudios texturales y estructurales en las vetas han permitido distinguir cuatro estadios sucesivos de mineralización que fueron controlados por una actividad discontinua de la cupla dextral. Este modelo estructural es similar a aquéllos propuestos para mineralizaciones de fluorita emplazadas en otros sectores del continente durante el mismo período, los que vinculan el control tectónico con la apertura del océano Atlántico sur. El registro del relleno hidrotermal permitió reconstruir la historia de apertura de las estructuras y puede usarse como un criterio efectivo de prospección y exploración. Las mayores concentraciones de mineral ocurren en las estructuras extensionales y en las flexiones dilatantes de las estructuras asociadas con la zona de cizallamiento principal NNE-SSO, que registran la secuencia mineralizada completa.

  10. Proposed geologic model based on geophysical well logs

    Energy Technology Data Exchange (ETDEWEB)

    Diaz C, S.; Puente C, I.; de la Pena L, A.

    1981-01-01

    An investigation of the subsurface based on a qualitative interpretation of well logs was carried out at Cerro Prieto to obtain information on the distribution of the different lithofacies that make up a deltaic depositional system. The sedimentological interpretation derived from the resistivity and spontaneous potential are shown in several cross-sections of the field. In addition to the sedimentological interpretation, a map of the structural geology of the region based on well logs and available geophysical information was prepared, including the results of gravity and seismic refraction surveys. The depth to the zone of hydrothermal alteration described by Elders (1980) was found by means of temperature, electrical, and radioactive logs. Two maps showing the configuration of the top of this anomaly show a clear correlation with the gravity anomalies found in the area.

  11. First hydrothermal active vent discovered on the Galapagos Microplate

    Science.gov (United States)

    Tao, C.; Li, H.; Wu, G.; Su, X.; Zhang, G.; Chinese DY115-21 Leg 3 Scientific Party

    2011-12-01

    The Galapagos Microplate (GM) lies on the western Gaplapagos Spreading Center (GSC), representing one of the classic Ridge-Ridge-Ridge (R-R-R) plate boundaries of the Nazca, Cocos, and Pacific plates. The presence of the 'black smoke' and hydrothermal vent community were firstly confirmed on the GSC. Lots of hydrothermal fields were discovered on the center and eastern GSC, while the western GSC has not been well investigated. During 17th Oct. to 9th Nov. 2009, the 3rd leg of Chinese DY115-21 cruise with R/V Dayangyihao has been launched along 2°N-5°S near equatorial East Pacific Rise (EPR). Two new hydrothermal fields were confirmed. One is named 'Precious Stone Mountain', which is the first hydrothermal field on the GM. The other is found at 101.47°W, 0.84°S EPR. The 'Precious Stone Mountain' hydrothermal field (at 101.49°W, 1.22°N) is located at an off-axial seamount on the southern GM boundary, with a depth from 1,450 to 1,700m. Hydrothermal fluids emitting from the fissures and hydrothermal fauna were captured by deep-tow video. Few mineral clasts of pyrite and chalcopyrite were separated from one sediment sample, but no sulfide chimney was found yet. Hydrothermal fauna such as alive mussels, crabs, shrimps, tubeworms, giant clams, as well as rock samples were collected by TV-Grab. The study of the seafloor classification with Simrad EM120 multi-beam echosounder has been conducted on the 'Precious Stone Mountain' hydrothermal field. The result indicates that seafloor materials around the hydrothermal field can be characterized into three types, such as the fresh lava, hydrothermal sediment, and altered rock.

  12. Mixing from below in hydrothermal ore deposits

    Science.gov (United States)

    Bons, Paul D.; Gomez-Rivas, Enrique; Markl, Gregor; Walter, Bejamin

    2014-05-01

    Unconformity-related hydrothermal ore deposits typically show indications of mixing of two end-member fluids: (a) hot, deep, rock-buffered basement brines and (b) colder fluids derived from the surface or overlying sediments. The hydromechanics of bringing these fluids together from above and below remain unclear. Classical percolative Darcy-flow models are inconsistent with (1) fluid overpressure indicated by fracturing and brecciation, (2) fast fluid flow indicated by thermal disequilibrium, and (3) strong fluid composition variations on the mm-scale, indicated by fluid inclusion analyses (Bons et al. 2012; Fusswinkel et al. 2013). We propose that fluids first descend, sucked down by desiccation reactions in exhumed basement. Oldest fluids reach greatest depths, where long residence times and elevated temperatures allow them the extensively equilibrate with their host rock, reach high salinity and scavenge metals, if present. Youngest fluids can only penetrate to shallower depths and can (partially) retain signatures from their origin, for example high Cl/Br ratios from the dissolution of evaporitic halite horizons. When fluids are released from all levels of the crustal column, these fluids mix during rapid ascent to form hydrothermal ore deposits. Mixing from below provides a viable hydromechanical mechanism to explain the common phenomenon of mixed shallow and deep fluids in hydrothermal ore deposits. Bons, P.D., Elburg, M.A., Gomez-Rivas, E. 2012. A review of the formation of tectonic veins and their microstructures. J. Struct. Geol. doi:10.1016/j.jsg.2012.07.005 Fusswinkel, T., Wagner, T., Wälle, M., Wenzel, T., Heinrich, C.A., Markl, M. 2013. Fluid mixing forms basement-hosted Pb-Zn deposits: Insight from metal and halogen geochemistry of individual fluid inclusions. Geology. doi:10.1130/G34092.1

  13. Magmatismo ácido del mioceno superior-cuaternario en el área de Cerro Blanco-La Hoyada, Puna Austral

    Directory of Open Access Journals (Sweden)

    María Carolina Montero López

    2010-11-01

    Full Text Available El volcanismo de composición ácida desarrollado en la Puna Austral entre el Mioceno superior y el Holoceno está representado en el extremo oriental de la cordillera de San Buenaventura (26°25'-27°00'S y 67°25'-67°50' O por dos unidades: Ignimbrita Aguada Alumbrera y Complejo Volcánico Cerro Blanco. Hacia el norte y noroeste de esta área afloran flujos piroclásticos (Ignimbrita Rosada cuyo análisis se presenta aquí a fines comparativos. Estas rocas volcánicas apoyan sobre un basamento metamórfico de mediano a alto grado con intrusivos del Neoproterozoico-Paleozoico inferior y rocas volcánicas de composición intermedia de ca. 9-7 Ma. Las rocas estudiadas abarcan un lapso entre el Mioceno superior (Ignimbrita Aguada Alumbrera e Ignimbrita Rosada hasta el Holoceno (Complejo Volcánico Cerro Blanco, tienen afinidad calcoalcalina y son principalmente de composición riolítica. En este estudio se presentan nuevos datos de campo que permiten ordenar la estratigrafía del sector de estudio, así como resultados de geoquímica. Las ignimbritas del Mioceno Superior-Plioceno estudiadas presentan características similares a las rocas ácidas aflorantes al oeste del área de estudio, las cuales fueron relacionadas por diversos autores a un ambiente de subducción procedentes de fuentes mantélicas con altos porcentajes de contaminación cortical, mientras que el Complejo Volcánico Cerro Blanco podría estar reflejando su procedencia de la fusión directa de la corteza, si bien esta hipótesis debe ser corroborada con mayor cantidad de datos geoquímicos.

  14. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  15. Vertical Cable Seismic Survey for Hydrothermal Deposit

    Science.gov (United States)

    Asakawa, E.; Murakami, F.; Sekino, Y.; Okamoto, T.; Ishikawa, K.; Tsukahara, H.; Shimura, T.

    2012-04-01

    The vertical cable seismic is one of the reflection seismic methods. It uses hydrophone arrays vertically moored from the seafloor to record acoustic waves generated by surface, deep-towed or ocean bottom sources. Analyzing the reflections from the sub-seabed, we could look into the subsurface structure. This type of survey is generally called VCS (Vertical Cable Seismic). Because VCS is an efficient high-resolution 3D seismic survey method for a spatially-bounded area, we proposed the method for the hydrothermal deposit survey tool development program that the Ministry of Education, Culture, Sports, Science and Technology (MEXT) started in 2009. We are now developing a VCS system, including not only data acquisition hardware but data processing and analysis technique. Our first experiment of VCS surveys has been carried out in Lake Biwa, JAPAN in November 2009 for a feasibility study. Prestack depth migration is applied to the 3D VCS data to obtain a high quality 3D depth volume. Based on the results from the feasibility study, we have developed two autonomous recording VCS systems. After we carried out a trial experiment in the actual ocean at a water depth of about 400m and we carried out the second VCS survey at Iheya Knoll with a deep-towed source. In this survey, we could establish the procedures for the deployment/recovery of the system and could examine the locations and the fluctuations of the vertical cables at a water depth of around 1000m. The acquired VCS data clearly shows the reflections from the sub-seafloor. Through the experiment, we could confirm that our VCS system works well even in the severe circumstances around the locations of seafloor hydrothermal deposits. We have, however, also confirmed that the uncertainty in the locations of the source and of the hydrophones could lower the quality of subsurface image. It is, therefore, strongly necessary to develop a total survey system that assures a accurate positioning and a deployment techniques

  16. Perfil infectológico de poblaciones mapuche de Cerro Policía y Aguada Guzmán de la provincia de Río Negro

    OpenAIRE

    Rey, Jorge Alberto; Dejean, Cristina Beatriz; Niborski, Ricardo; Arrayago, Alicia M.; Kohan, Abraham I.; Carnese, Francisco R.

    1996-01-01

    Nuestro trabajo analiza la prevalencia de marcadores de algunas infecciones que afectan las poblaciones mapuche de Cerro Policía (CP) y Aguada Guzmán (AG) en la Prov. de Río Negro. Los estudios incluídos son: determinación de anticuerpos anti-Treponema pallidum, anti-Trypanosoma cruzii, anti-Echinococcus granulosus, antígeno de superficie de la Hepatitis B (HBsAg), anticuerpos contra el core de la Hepatitis B (anti-HBc), anticuerpos contra el virus de la Hepatitis A (anti-HAV). Se estudiaron ...

  17. Apresentacão do Projeto de extensão universitaria "Fortalecimento das Capacidades das Educadoras do Programa CAIF no estado de Cerro Largo-Uruguai"

    OpenAIRE

    Mariana Porta Galván

    2015-01-01

    Dentro de la línea de investigación Estado, políticas sociales y ciudadanía en frontera, es relevante conocer la realidad de las políticas sociales orientadas a la primera infancia y sus implementaciones. Esta ponencia presenta un proyecto de extensión universitaria realizada con los centros CAIF de Cerro Largo con el propósito de fortalecer las prácticas de los operadores sociales de estos centros, a partir de las siguientes preguntas: ¿Qué características asume la implementación de esta pol...

  18. Dos tumbas de Época Altoimperial documentadas en el entorno minero de Cerro Muriano (Córdoba): I.A.U. La Mocha

    OpenAIRE

    Moreno Garrido, María Jesús; Penco Valenzuela, Fernando

    2000-01-01

    The last archaeological explorations and other researches made at Cerro Muria­no come to corroborate the importance of this mining whole wich, according to all the vestiges, was already worked during Prehistory. Lower down, we show some outstanding aspects about two burials excavated on geological rock that must be produced about the transition from I B.C. to I A.C. century. Constitute the first two examples of funeral structures wich have been verified in this space, that has been continousl...

  19. NUEVOS APORTES AL CONOCIMIENTO DE LA HERPETOFAUNA DE LA FORMACIÓN CERRO AZUL (MIOCENO SUPERIOR), PROVINCIA DE LA PAMPA, ARGENTINA

    OpenAIRE

    AGUSTÍN SCANFERLA; Agnolín, Federico L.

    2015-01-01

    RESUMENSe describen nuevos materiales fósiles de anfibios y reptiles hallados en sedimentos referidos a la Formación Cerro Azul (Mioceno Superior), procedentes de numerosas localidades de la provincia de La Pampa, Argentina. Los nuevos registros se basan en un resto craneano de anuro asignado al géneroCeratophrys, restos de caparazón de tortugas terrestres del géneroChelonoidis, vértebras asignables al lagarto de la familia TeiidaeTupinambis, y una vértebra troncal de serpiente comparable a...

  20. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    @@ Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.

  1. Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

    Science.gov (United States)

    Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

    2014-06-01

    Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content.

  2. Nutritional strategies of the hydrothermal ecosystem bivalves

    Science.gov (United States)

    Le Pennec, Marcel; Donval, Anne; Herry, Angèle

    Studies of deep-sea hydrothermal bivalves have revealed that the species, which are strictly dependent upon the interstitial fluid emissions, derive their food indirectly via symbiotic relationships with chemosynthetic bacteria present in their gill tissues. As the gill plays the main trophic role, structural and ultrastructural modifications occur in the digestive tract. Scanning and transmission electron microscope studies reveal that the digestive system of species belonging to the genera Calyptogena, Bathymodiolus and Bathypecten have anatomical differences. In Calyptogena, the reduction of several parts of the digestive tract and the stomach content which is either empty or full, according to the various species examined indicate that the digestive system is hardly if at all functional. In Bathymodiolus, the labial palps are well developed, the stomach is always full with particles and the two cellular types, digestive and secretory, are present in the digestive gland. All these characteristics indicate that the digestive system is functional. In Bathypecten, the digestive tract is well developed and it seems that it plays the main trophic role. We conclude that the nutritional strategies of the hydrothermal vents bivalves are quite varied. They range from a normal trophic process, through a mixotrophic diet, to one based purely on chemoautotrophic bacteria. The strategy of each species is adapted to and influences its distribution.

  3. The Guaymas Basin Hiking Guide to Hydrothermal Mounds, Chimneys, and Microbial Mats: Complex Seafloor Expressions of Subsurface Hydrothermal Circulation.

    Science.gov (United States)

    Teske, Andreas; de Beer, Dirk; McKay, Luke J; Tivey, Margaret K; Biddle, Jennifer F; Hoer, Daniel; Lloyd, Karen G; Lever, Mark A; Røy, Hans; Albert, Daniel B; Mendlovitz, Howard P; MacGregor, Barbara J

    2016-01-01

    The hydrothermal mats, mounds, and chimneys of the southern Guaymas Basin are the surface expression of complex subsurface hydrothermal circulation patterns. In this overview, we document the most frequently visited features of this hydrothermal area with photographs, temperature measurements, and selected geochemical data; many of these distinct habitats await characterization of their microbial communities and activities. Microprofiler deployments on microbial mats and hydrothermal sediments show their steep geochemical and thermal gradients at millimeter-scale vertical resolution. Mapping these hydrothermal features and sampling locations within the southern Guaymas Basin suggest linkages to underlying shallow sills and heat flow gradients. Recognizing the inherent spatial limitations of much current Guaymas Basin sampling calls for comprehensive surveys of the wider spreading region.

  4. TECNOLOGÍA Y SUBSISTENCIA EN EL SITIO ARQUEOLÓGICO CERRO TAPERA VÁZQUEZ (PARQUE NACIONAL PRE-DELTA, REPÚBLICA ARGENTINA

    Directory of Open Access Journals (Sweden)

    Mariano Bonomo

    2014-10-01

    Full Text Available In this paper the results of the studies carried out on ceramic and bone materials recorded at Cerro Tapera Vázquez site (Argentinean Northeast are presented. Taxonomic, anatomic and taphonomic studies of bone assemblages and technological-decorative analysis and refitting of pottery were undertaken. The site is located on a mound next to El Ceibo Creek, where 16 m2 were excavated in 2008. Abundant smooth, incised and modeled pottery (handles and zoomorphic appendages and numerous bones remains of Myocastor coypus (most frequent taxon, Blastocerus dichotomus, Ozotoceros bezoarticus, Cavia aperea, Leopardus geoffroyi, Lycalopex gymnocercus, Hydrochaeris hydrochaeris, birds and fish (Siluriformes and Characiformes were recorded. Except Cavia aperea rodent and Dusicyon gimnocercus fox, all taxa show evidence of anthropic modification (cut marks, fresh fractures and burning. Two radiocarbon dates were obtained: 650 and 520 yrs. BP. The results reached in this study lead to the conclusion that the pre-Hispanic populations that occupied Cerro Tapera Vázquez by the end of the Late Holocene were riverine canoe peoples, with complex ceramic technology and subsistence based on hunting of coypu, capybara and cervids, fishing and small-scale horticulture.

  5. ANALISIS DEL CO-TRATAMIENTO PASIVO DE AGUAS RESIDUALES MUNICIPALES Y DRENAJE ACIDO DE MINAS EN CERRO RICO DE POTOSÍ, BOLIVIA

    Directory of Open Access Journals (Sweden)

    William H.J. Strosnider

    2015-01-01

    Full Text Available El drenaje acido de minas (DAM es un problema a nivel mundial. El co-tratamiento pasivo de DAM con aguas residuales municipales (ARM es una manera efectiva y de bajo costo que utiliza los nutrientes de ARM para tratar las concentraciones de metales y sulfato en DAM. Cerro Rico de Potosí, Bolivia es una de las grandes ciudades mineras en el mundo que tiene muchos problemas con el DAM. El objetivo de este estudio fue determinar velocidades de reacción de Al, Fe, Mn, Zn, y otros metales en DAM provenientes de un flujo de agua en Cerro Rico usando un sistema reactor de tres etapas. El DAM tenía un pH de 3.58, acidez de 1080 mg/L equivalente a CaCO3 conteniendo concentraciones de 12, 68, 17, y 550 mg/L de Al, Fe, Mn y Zn respectivamente. Las velocidades de reacción de Al, Fe, Mn y Zn fueron de 1.43, 2.09, 0.01 y 0.10 d-1, respectivamente.

  6. Edad, caracterización petrográfica y Geoquímica del Granitoide del Cerro Falkner, Neuquén

    Directory of Open Access Journals (Sweden)

    Sabrina Crosta

    2008-03-01

    Full Text Available El Cerro Falkner se halla constituido por rocas graníticas infrayacentes a las volcanitas de la Formación Ventana de edad paleógena. Dichos intrusivos son de composición granodiorítica, metaluminosos a peraluminosos, subalcalinos, con características de granitos de arco volcánico concordantes con otros granitoides del segmento norte de la Cordillera Patagónica Septentrional. La edad obtenida por el método K-Ar sobre anfíboles de composición tschermakítica (125 ± 20 Ma indica una edad mínima perteneciente al Cretácico inferior para la granodiorita del cerro Falkner, por lo que sería incorrecto utilizar la denominación Formación Los Machis (Cretácico superior para estas rocas. Esta edad, permite vincular las rocas graníticas del área de estudio con el volcanismo representado por el Grupo Divisadero de edad predominantemente cretácica inferior.

  7. Geochemistry of the Neoproterozoic (800-767 Ma) Cerro Bori orthogneisses, Dom Feliciano Belt in Uruguay: tectonic evolution of an ancient continental arc

    Science.gov (United States)

    Lenz, C.; Porcher, C. C.; Fernandes, L. A. D.; Masquelin, H.; Koester, E.; Conceição, R. V.

    2013-10-01

    The Cerro Bori orthogneisses, crystallized between ca. 800 and 767 Ma, are composed of a sequence of mafic gneisses, with dioritic-gabbroic and dioritic composition tectonically interleaved with a sequence of tonalitic and granodioritic gneisses. These rocks intruded the Chafalote paragneisses (metapelites, semipelites, carbonate and mafic rocks) and they were metamorphosed of high P-T conditions at ca. 676-654 Ma. This paper presents the first major and trace geochemical signatures, as well as Sm and Pb isotopic composition for the Cerro Bori orthogneisses, which allow distinguishing three different groups of rocks. Type I rocks are mafic gneisses with tholeiitic affinity, whereas the Type II rocks are tonalitic and granodioritic gneisses with calc-alkaline affinity. The third type is composed of biotite-rich mafic gneisses with potassic and ultrapotassic affinities. All the three types of rocks have negative ℰND values (between -2.12 and -6.67) and old TDM ages (between 1.2 and 2.0 Ga), indicating that the process of crustal assimilation/contamination was an important process, together with fractional crystallization. An continental arc tectonic setting is suggested to this association of rocks between 800 and 767 Ma. This subduction suggests the existence of an ocean between Rio de La Plata and adjacent cratons during the break up of the Rodinia supercontinent.

  8. Effect of artificial feeders on pollen loads of the hummingbirds of Cerro de la Muerte, Costa Rica.

    Science.gov (United States)

    Avalos, Gerardo; Soto, Alejandra; Alfaro, Willy

    2012-03-01

    Although sugar-water feeders are commonly used by enthusiasts to attract hummingbirds, little is known about how they affect hummingbird behavior and flower use. We studied the highland hummingbird assemblage of Cerro de La Muerte, Costa Rica, both at a site with permanent feeders (La Georgina Restaurant) and further from it. We examined how feeder use and monopolization affected seasonal changes in pollen loads during four sampling periods, including dry and wet seasons, from 2003-2005. We expected that species monopolizing the feeders would carry little or no pollen whatsoever, and would have pollen loads characterized by low floral diversity, in contrast with species less dependent on feeders. We obtained pollen samples from 183 individuals of four hummingbird species captured around the feeders using mist nets, which were compared with a pollen reference collection of plants with a pollination syndrome by hummingbirds. The same methods were implemented at a site 3km away from the feeders. Feeder usage was quantified by counting the number of times hummingbirds drank from the feeders in periods of 4min separated by 1min. The effects of hummingbird species and season on pollen load categories were assessed using a nominal logistic regression. The alpha species at the site, the Fiery-throated Hummingbird (Panterpe insignis), dominated the feeders during the dry season. Meanwhile, in the wet season, feeder usage was more evenly distributed across species, with the exception of the Volcano Hummingbird, Selasphorus flammula, which occupies the last place in the dominance hierarchy. Pollen loads of hummingbirds captured near feeders were low in abundance (more than 50% of captured individuals had zero or low pollen loads), and low in species richness (96% of the hummingbirds with pollen from only one plant genus, Centropogon). Overall pollen loads increased during the dry season coinciding with peaks in flower availability, although the majority of captured

  9. Effect of artificial feeders on pollen loads of the hummingbirds of Cerro de la Muerte, Costa Rica.

    Science.gov (United States)

    Avalos, Gerardo; Soto, Alejandra; Alfaro, Willy

    2012-03-01

    Although sugar-water feeders are commonly used by enthusiasts to attract hummingbirds, little is known about how they affect hummingbird behavior and flower use. We studied the highland hummingbird assemblage of Cerro de La Muerte, Costa Rica, both at a site with permanent feeders (La Georgina Restaurant) and further from it. We examined how feeder use and monopolization affected seasonal changes in pollen loads during four sampling periods, including dry and wet seasons, from 2003-2005. We expected that species monopolizing the feeders would carry little or no pollen whatsoever, and would have pollen loads characterized by low floral diversity, in contrast with species less dependent on feeders. We obtained pollen samples from 183 individuals of four hummingbird species captured around the feeders using mist nets, which were compared with a pollen reference collection of plants with a pollination syndrome by hummingbirds. The same methods were implemented at a site 3km away from the feeders. Feeder usage was quantified by counting the number of times hummingbirds drank from the feeders in periods of 4min separated by 1min. The effects of hummingbird species and season on pollen load categories were assessed using a nominal logistic regression. The alpha species at the site, the Fiery-throated Hummingbird (Panterpe insignis), dominated the feeders during the dry season. Meanwhile, in the wet season, feeder usage was more evenly distributed across species, with the exception of the Volcano Hummingbird, Selasphorus flammula, which occupies the last place in the dominance hierarchy. Pollen loads of hummingbirds captured near feeders were low in abundance (more than 50% of captured individuals had zero or low pollen loads), and low in species richness (96% of the hummingbirds with pollen from only one plant genus, Centropogon). Overall pollen loads increased during the dry season coinciding with peaks in flower availability, although the majority of captured

  10. Entropy Production in Convective Hydrothermal Systems

    Science.gov (United States)

    Boersing, Nele; Wellmann, Florian; Niederau, Jan

    2016-04-01

    Exploring hydrothermal reservoirs requires reliable estimates of subsurface temperatures to delineate favorable locations of boreholes. It is therefore of fundamental and practical importance to understand the thermodynamic behavior of the system in order to predict its performance with numerical studies. To this end, the thermodynamic measure of entropy production is considered as a useful abstraction tool to characterize the convective state of a system since it accounts for dissipative heat processes and gives insight into the system's average behavior in a statistical sense. Solving the underlying conservation principles of a convective hydrothermal system is sensitive to initial conditions and boundary conditions which in turn are prone to uncertain knowledge in subsurface parameters. There exist multiple numerical solutions to the mathematical description of a convective system and the prediction becomes even more challenging as the vigor of convection increases. Thus, the variety of possible modes contained in such highly non-linear problems needs to be quantified. A synthetic study is carried out to simulate fluid flow and heat transfer in a finite porous layer heated from below. Various two-dimensional models are created such that their corresponding Rayleigh numbers lie in a range from the sub-critical linear to the supercritical non-linear regime, that is purely conductive to convection-dominated systems. Entropy production is found to describe the transient evolution of convective processes fairly well and can be used to identify thermodynamic equilibrium. Additionally, varying the aspect ratio for each Rayleigh number shows that the variety of realized convection modes increases with both larger aspect ratio and higher Rayleigh number. This phenomenon is also reflected by an enlarged spread of entropy production for the realized modes. Consequently, the Rayleigh number can be correlated to the magnitude of entropy production. In cases of moderate

  11. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    Directory of Open Access Journals (Sweden)

    Jung Hyunjung

    2011-01-01

    Full Text Available Abstract Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene nanoparticles (NPs prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs.

  12. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    Science.gov (United States)

    2011-01-01

    Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene) nanoparticles (NPs) prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL) characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs. PMID:21711925

  13. Structure of the Wagner Basin in the Northern Gulf of California From Interpretation of Seismic Reflexion Data

    Science.gov (United States)

    Gonzalez, M.; Aguilar, C.; Martin, A.

    2007-05-01

    The northern Gulf of California straddles the transition in the style of deformation along the Pacific-North America plate boundary, from distributed deformation in the Upper Delfin and Wagner basins to localized dextral shear along the Cerro Prieto transform fault. Processing and interpretation of industry seismic data adquired by Petroleos Mexicanos (PEMEX) allow us to map the main fault structures and depocenters in the Wagner basin and to unravel the way strain is transferred northward into the Cerro Prieto fault system. Seismic data records from 0.5 to 5 TWTT. Data stacking and time-migration were performed using semblance coefficient method. Subsidence in the Wagner basin is controlled by two large N-S trending sub-parallel faults that intersect the NNW-trending Cerro Prieto transform fault. The Wagner fault bounds the eastern margin of the basin for more than 75 km. This fault dips ~50° to the west (up to 2 seconds) with distinctive reflectors displaced more than 1 km across the fault zone. The strata define a fanning pattern towards the Wagner fault. Northward the Wagner fault intersects the Cerro Prieto fault at 130° on map view and one depocenter of the Wagner basin bends to the NW adjacent to the Cerro Prieto fault zone. The eastern boundary of the modern depocenter is the Consag fault, which extends over 100 km in a N-S direction with an average dip of ~50° (up to 2s) to the east. The northern segment of the Consag fault bends 25° and intersects the Cerro Prieto fault zone at an angle of 110° on map view. The acoustic basement was not imaged in the northwest, but the stratigraphic succession increases its thickness towards the depocenter of the Wagner basin. Another important structure is El Chinero fault, which runs parallel to the Consag fault along 60 km and possibly intersects the Cerro Prieto fault to the north beneath the delta of the Colorado River. El Chinero fault dips at low-angle (~30°) to the east and has a vertical offset of about 0

  14. Deep-Sea Hydrothermal-Vent Sampler

    Science.gov (United States)

    Behar, Alberto E.; Venkateswaran, Kasthur; Matthews, Jaret B.

    2008-01-01

    An apparatus is being developed for sampling water for signs of microbial life in an ocean hydrothermal vent at a depth of as much as 6.5 km. Heretofore, evidence of microbial life in deep-sea hydrothermal vents has been elusive and difficult to validate. Because of the extreme conditions in these environments (high pressures and temperatures often in excess of 300 C), deep-sea hydrothermal- vent samplers must be robust. Because of the presumed low density of biomass of these environments, samplers must be capable of collecting water samples of significant volume. It is also essential to prevent contamination of samples by microbes entrained from surrounding waters. Prior to the development of the present apparatus, no sampling device was capable of satisfying these requirements. The apparatus (see figure) includes an intake equipped with a temperature probe, plus several other temperature probes located away from the intake. The readings from the temperature probes are utilized in conjunction with readings from flowmeters to determine the position of the intake relative to the hydrothermal plume and, thereby, to position the intake to sample directly from the plume. Because it is necessary to collect large samples of water in order to obtain sufficient microbial biomass but it is not practical to retain all the water from the samples, four filter arrays are used to concentrate the microbial biomass (which is assumed to consist of particles larger than 0.2 m) into smaller volumes. The apparatus can collect multiple samples per dive and is designed to process a total volume of 10 L of vent fluid, of which most passes through the filters, leaving a total possibly-microbe-containing sample volume of 200 mL remaining in filters. A rigid titanium nose at the intake is used for cooling the sample water before it enters a flexible inlet hose connected to a pump. As the water passes through the titanium nose, it must be cooled to a temperature that is above a mineral

  15. Hydraulic characterization of hydrothermally altered Nopal tuff

    International Nuclear Information System (INIS)

    Understanding the mechanics of variably saturated flow in fractured-porous media is of fundamental importance to evaluating the isolation performance of the proposed high-level radioactive waste repository for the Yucca Mountain site. Developing that understanding must be founded on the analysis and interpretation of laboratory and field data. This report presents an analysis of the unsaturated hydraulic properties of tuff cores from the Pena Blanca natural analog site in Mexico. The basic intent of the analysis was to examine possible trends and relationships between the hydraulic properties and the degree of hydrothermal alteration exhibited by the tuff samples. These data were used in flow simulations to evaluate the significance of a particular conceptual (composite) model and of distinct hydraulic properties on the rate and nature of water flow

  16. Hydrothermal pretreatment of biomass for pellet production

    Energy Technology Data Exchange (ETDEWEB)

    Tooyserkani, Z. [British Columbia Univ., Vancouver, BC (Canada). Clean Energy Research Centre, Biomass and Bioenergy Research Group

    2010-07-01

    This presentation discussed innovative technologies for the production of wood pellets using the hydrothermal pre-treatment of biomass. Conventional techniques use low-cost mill residues, such as saw dust and shavings, as feedstock to produce durable, low-ash pellets. However, mill residues are becoming less available as a result of fewer saw mills, increased pellet production, and increased competition for saw dust. Advanced techniques use mixed biomass such as logging residue as feedstock, creating pellets that are durable for handling and long-term storage, of a higher energy density for transport and mixing with coal for co-firing, and a choice feedstock for biofuels. Advanced pellet production uses steam explosion/pre-treatment in which biomass receives a short-term high-pressure steam treatment followed by sudden decompression. Mild torrefaction seems to have positive feedback, and steam-treated pellets are durable with superior hydrophobicity. 3 figs., 3 tabs.

  17. Evolutionary origins of hydrothermal vents metazoans

    Directory of Open Access Journals (Sweden)

    Samadi Sarah

    2015-01-01

    Full Text Available The discovery of the oases associated with hydrothermal vents in the deep sea, is probably the most fascinating discovery of oceanography of the last century. In this habitat, contrary to all expectations, a thriving development of unknown organisms was observed. At that time the knowledge about the deep sea organisms was very scarce and the accepted hypotheses about their evolutionary origins, their physiology or their ecology were very speculative. Almost forty years later, exploration of the deep-sea realm, but also of paleontological data together with the improvements in the phylogenetic methods, allowed the rejection of the hypothesis of an evolutionary history cut off the rest of the marine realm.

  18. Peptide synthesis under Enceladus hydrothermal condition

    Science.gov (United States)

    Fujishima, Kosuke; Takano, Yoshinori; Takai, Ken; Takahagi, Wataru; Adachi, Keito; Shibuya, Takazo; Tomita, Masaru

    2016-07-01

    Enceladus is one of the moons of Saturn, and it has been known to harbor interior ocean beneath the icy crust. The mass spectrometry data obtained by Cassini spacecraft indicates the presence of salty, and most likely alkaline ocean containing various organic compounds. While geochemical and other radiation related processes for in situ production of organics remain elusive, thermally unaltered carbonaceous chondrites, consisting the main body of Enceladus are known to be enriched with organic matters potentially including the building blocks of life (e.g., amino acids and amino acid precursors). Assuming that abiotic amino acids exist in the Enceladus alkaline seawater, we hypothesized that water-rock interaction may contribute to condensation of localized amino acids leading to peptide formation. In order to test this hypothesis, we have developed the Enceladus hydrothermal reactor based on the chemical constraints obtained through previous experimental and theoretical studies. We have added six different amino acids and introduced a thermal fluctuation system simulating the periodic tidal heating of the interior chondritic core. Total, eight sea water samples were obtained over the course of 147 days of experiment. While detection of peptide using Capillary Electrophoresis Time-of-Flight Mass Spectrometry (CE-TOF/MS) is still at the preliminary stage, so far pH monitoring and H2 and CO2 Gas Chromatography Mass Spectrometry (GC-MS) data clearly indicated the occurrence of serpentinization/carbonation reaction. Here, we discuss the interaction between aqueous alteration reactions and thermal cycling processes for the role of abiotic peptide formation under the Enceladus hydrothermal condition.

  19. Hydrothermal preparation and formation mechanism of titanium dioxide microcrystallites

    Institute of Scientific and Technical Information of China (English)

    郑燕青; 施尔畏; 元如林; 李汶军; 王步国; 仲维卓; 胡行方

    1999-01-01

    Hydrothermal preparation experiments of TiO2 microcrystallites were carried out. The formation of TiO2 microcrystallites of polymorpbic forms was related to the precursor types and the basicity or acidity of reaction mediums under hydrothermal conditions. Based on the "growth unit" model, the space lattice graphs of growth units responding to different polymorphs were established. The stable energy of growth unit was calculated for different basicity or acidity of reaction mediums. The formation of polymorphic TiO2 microcrystallites under hydrothermal conditions was discussed based on the experimental results.

  20. Chatkalita, nekrasovita y otros minerales del grupo de la estannita de Veta María Eugenia, Cerro Atajo, Catamarca Chatkalita, nekrasovita y otros minerales del grupo de la estannita de veta María Eugenia, Cerro Atajo, Catamarca

    Directory of Open Access Journals (Sweden)

    M. F. Márquez-Zavalía

    2007-06-01

    Full Text Available En veta María Eugenia, Cerro Atajo, Catamarca, se encontró una asociación de minerales de estaño integrada por: chatkalita Cu6Fe2+Sn2S8, nekrasovita Cu26V2(Sn,As,Sb6S32, colusita Cu26V2(As,Sn,Sb6S32, kësterita Cu2(Zn,FeSnS4 y estannoidita Cu8(Fe,Zn3Sn2S12. Estos minerales, incluidos en watanabeíta, están acompañados principalmente por pirita, esfalerita, calcopirita, tetraedrita, bornita y galena; aikinita, enargita, luzonita, marcasita, arsenopirita y pirrotina participan como minerales accesorios. Chatkalita se presenta en agregados irregulares de hasta 40 µm, asociados con kësterita y estannoidita, es de color rosa-anaranjado claro, birreflectante y anisótropa, con colores de polarización pardos; su composición química (% en peso es: S=29,76-30,37, Fe=4,53-7,92, Cu=39,13-43,21, Zn=0,75-5,53, As=0,19- 2,42, Sn=15,27-20,50 y Sb=0,00-0,32. Nekrasovita es isótropa, de color pardo con leve tinte rosa-violáceo y está asociada con estannoidita; su composición química es: S=30,29-30,63, Fe=3,41-4,75, Cu=44,26-45,70, Zn=0,56-1,00, As=4,18-4,71, Sn=12,53-13,64 y Sb=0,71- 0,77. Colusita es pardo amarillenta, isótropa, se presenta como parches irregulares y cintas discontinuas en tennantita; su composición química es: S=30,59-30,74, Fe=2,18-3,58, Cu=47,22-48,13, Zn=0,21-0,64, As=6,38-6,61, Sn=9,04-9,33 y Sb=0,49-1,66. Kësterita es pardo grisácea, con débil birreflectancia y anisotropía y colores de polarización pardos, a menudo se presenta bordeada por chatkalita; su composición química es: S=28,68-29,14, Fe=1,98-2,14, Cu=31,06-32,51, Zn=9,03-11,57 y Sn=26,39-27,03. Estannoidita es de color castaño, pleocroica (castaño-rosado a pardo-grisáceo y anisótropa con colores de polarización pardos y pardo-amarillentos, ocurre en parches irregulares y como bandas bordeando tennantita; su composición química es: S=29,11-29,83, Fe=8,45-10,30, Cu=38,05-41,01, Zn=3,18-4,90, y Sn=15,84-18,94. La reflectividad y dureza de pulido de

  1. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  2. Direct use of hydrothermal energy: a review of environmental aspects

    Energy Technology Data Exchange (ETDEWEB)

    O' Banion, K.; Layton, D.

    1981-08-28

    The potential environmental impacts of the exploration, development, and production of hydrothermal geothermal energy for direct use applications are reviewed and evaluated. Mitigation strategies and research and development needs are included. (MHR)

  3. Hydrothermal synthesis of vanadium oxide nanotubes by a facile route

    Institute of Scientific and Technical Information of China (English)

    HUANG Chunming; LIU Xueqin; KONG Lingbin; ZHOU Haijia; LIU Yaqiang; QIU Jiawen; WANG Yinyue

    2006-01-01

    Vanadium oxide nanotubes were synthesized by hydrothermal treatment from V2O5·nH2O sols as precursor and dodecylamine as structure-directing template. The morphology and structure of the nanotubes were characterized by SEM, TEM, XRD, TG-DTA and FTIR. The experimental results reveal that the duration of the hydrothermal treatment is of importance for obtaining Vox-NTs which have a layered structure. TG-DTA study indicates that V5+ cations in nanotubes are partially reduced to V4+ cations. The results from FTIR spectra indicate the difference in V-O vibrations between before and after hydrothermal treatment. From the results, it suggests that during hydrothermal treatment, the rearrangement of the vanadium oxide structure leads to the formation of VOx nanotubes from lamellar structure because of the presence of V4+ species.

  4. Radionuclides in hydrothermal systems as indicators of repository conditions

    International Nuclear Information System (INIS)

    Hydrothermal systems in tuffaceous and older sedimentary rocks contain evidence of the interaction of radionuclides in fluids with rock matrix minerals and with materials lining fractures, in settings somewhat analogous to the candidate repository site at Yucca Mountain, NV. Earlier studies encompassed the occurrences of U and Th in a ''fossil'' hydrothermal system in tuffaceous rock of the San Juan Mountains volcanic field, CO. More recent and ongoing studies examine active hydrothermal systems in calderas at Long Valley, CA and Valles, NM. At the Nevada Test Site, occurrences of U and Th in fractured and unfractured rhyolitic tuff that was heated to simulate the introduction of radioactive waste are also under investigation. Observations to date suggest that U is mobile in hydrothermal systems, but that localized reducing environments provided by Fe-rich minerals and/or carbonaceous material concentrate U and thus attenuate its migration. 11 refs., 6 figs., 1 tab

  5. Microbiological production and ecological flux of northwestern subduction hydrothermal systems

    Science.gov (United States)

    Sunamura, M.; Okamura, K.; Noguchi, T.; Yamamoto, H.; Fukuba, T.; Yanagawa, K.

    2012-12-01

    Deep-sea hydrothermal system is one of the most important sources for heat and chemical flux from the oceanic crust to the global ocean. The rich biological community around the hydrothermal vent shows chemolithoautotrophic microbial production are important in deep sea ecosystems. More than 99% of microbiological available chemical components in hydrothermal vent fluid, e.g. sulfide, methane, hydrogen, Fe2+, and Mn2+, is released into surrounding seawater to construct hydrothermal plume, suggesting that the chemolithoautotrophic-microbial primary production in the hydrothermal plume is huge and important in the whole hydrothermal ecosystems. To understand the impact of hydrothermal plume to a microbial ecosystem and a connectivity with zooplankton, we targeted and investigated a total of 16 hydrothermal fileds (7 sites in Okinawa trough, 3 sites in Ogasawara arc, and 6 sites in Mariana arc and back arc) and investigated in several cruises under the TAIGA project in Japan. Hydrothermal fluids in the subduction system are rich in sulfide. The hydrothermal fluids in the Okinawa trough, Ogasawara arc. and Mariana trough are characterized by rich in methane, poor in other reduced chemicals, and rich in iron, respectively. The major microbial composition was a potential sulfur oxidizing microbes SUP05 in the plume ecosystems, while an aerobic methanotrophic bacteria was secondary major member in methane-rich hydrothermal systems in Okinawa trough. Microbial quantitative and spatial distribution analyses of each plume site showed that the microbial population size and community structures are influenced by original chemical components of hydrothermal fluid, e.g. sulfide, methane and iron concentration. Microbial quantitative data indicated the removal/sedimentation of microbial cells from the plume and effect of phase separation in a same vent field through construction of gas-rich or gas-poor plumes. After the correlation of plume mixing effect, we estimates that the

  6. Mapping the edge of the Cerros del Rio volcanic field, New Mexico: a piece of the puzzle to understanding a potential geothermal resource

    Science.gov (United States)

    Pellerin, L.; Gallegos, M.; Goebel, M.; Murphy, B. S.; Smith, J.; Soto, D.; Swiatlowski, J.; Volk, C.; Welch, M.; Feucht, D. W.; Hollingshaus, B.; Bedrosian, P. A.; McPhee, D. K.

    2012-12-01

    The Cerros del Rio volcanic field located west of Santa Fe, New Mexico spans the southwestern part of the Espanola Basin with the Rio Grande to the west. Underlying the volcanics are the Santa Fe Group sediments, which contain the Ancha Formation, an important aquifer in the region. High temperature gradients in water wells reveal a potential geothermal prospect. In 2012 the Summer of Applied Geophysical Experience (SAGE) program acquired transient electromagnetic (TEM), audiomagnetotelluric (AMT), gravity and ground magnetic data to determine the buried eastern margin of the volcanic field and the connectivity related to the underlying sediments. The roughly EW 5-km long transect was sited from USGS aeromagnetic data to cross the boundary of the Cerros del Rio volcanic field. TEM data collected at ten stations, at 200-400 m spacing, along the transect employed an in-loop configuration with a square 100 m x 100 m transmitter loop and both a Zonge receiver coil and a 5 m square receiver loop. The 5 m loop allowed for the recovery of early-time data that was saturated when using the Zonge coil. AMT data were acquired at eight stations, at 400-500 m spacing, using the Geometric Stratagem system recording from 92 kHz to 10 Hz; a horizontal magnetic dipole transmitter was used to augment low signal strength at around 1 kHz. Gravity data along the profile were acquired using CG-3 and CG-5 Scintrex gravimeters with a station interval >250 m. Magnetic data were acquired with a Geometrics Cesium vapor G-858 magnetometer for about 3500 m along the profile at a 0.5 second sampling rate. Two volcanic flows interbedded with Ancha Formation and overlying Santa Fe Group sediments were identified in both the TEM and AMT modeling. High surface resistivity zones (>300 ohm-m) with depths ranging from ~100 to 300 m define the volcanic flows and correspond to high densities (2.3 to 2.55 g/cm3), while low resistivity zones (<30 ohm-m) correspond to lower densities (~2.1 g/cm3). High

  7. A data processing method for MAPR hydrothermal plume tur-bidity data and its application in the Precious Stone Mountain hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    CHEN Sheng; TAO Chunhui; LI Huaiming; CHEN Yongshun; ZHOU Jianping; WU Tao

    2014-01-01

    Hydrothermal plume is an important constituent of seabed hydrothermal circulation and is also one of the characteristics of active hydrothermal vents. Portable Miniature Autonomous Plume Recorders (MAPR) attached to a towed deep-sea instrument was used to search for hydrothermal plumes and hydrothermal vents. We introduced the basic principle of MAPR based on deep towing technology to detect plumes, then analyzed the factors affecting the quality of the MAPR data and presented a data correction method for MAPR, including instrument location correction, noise reduction processing, system error elimination and seawater background reduction. Finally we applied the method to analyze MAPR data obtained during the Chinese DY115-21 cruise on R/VDayang Iin the “Precious Stone Mountain” hydrothermal field on the Gala-pagos Microplate. The results provided a better understanding of the distribution of the hydrothermal activ-ity in this field, indicating the presence of a new hydrothermal vent.

  8. Chatkalita, nekrasovita y otros minerales del grupo de la estannita de Veta María Eugenia, Cerro Atajo, Catamarca

    Directory of Open Access Journals (Sweden)

    M. F. Márquez-Zavalía

    2007-06-01

    Full Text Available En veta María Eugenia, Cerro Atajo, Catamarca, se encontró una asociación de minerales de estaño integrada por: chatkalita Cu6Fe2+Sn2S8, nekrasovita Cu26V2(Sn,As,Sb6S32, colusita Cu26V2(As,Sn,Sb6S32, kësterita Cu2(Zn,FeSnS4 y estannoidita Cu8(Fe,Zn3Sn2S12. Estos minerales, incluidos en watanabeíta, están acompañados principalmente por pirita, esfalerita, calcopirita, tetraedrita, bornita y galena; aikinita, enargita, luzonita, marcasita, arsenopirita y pirrotina participan como minerales accesorios. Chatkalita se presenta en agregados irregulares de hasta 40 µm, asociados con kësterita y estannoidita, es de color rosa-anaranjado claro, birreflectante y anisótropa, con colores de polarización pardos; su composición química (% en peso es: S=29,76-30,37, Fe=4,53-7,92, Cu=39,13-43,21, Zn=0,75-5,53, As=0,19- 2,42, Sn=15,27-20,50 y Sb=0,00-0,32. Nekrasovita es isótropa, de color pardo con leve tinte rosa-violáceo y está asociada con estannoidita; su composición química es: S=30,29-30,63, Fe=3,41-4,75, Cu=44,26-45,70, Zn=0,56-1,00, As=4,18-4,71, Sn=12,53-13,64 y Sb=0,71- 0,77. Colusita es pardo amarillenta, isótropa, se presenta como parches irregulares y cintas discontinuas en tennantita; su composición química es: S=30,59-30,74, Fe=2,18-3,58, Cu=47,22-48,13, Zn=0,21-0,64, As=6,38-6,61, Sn=9,04-9,33 y Sb=0,49-1,66. Kësterita es pardo grisácea, con débil birreflectancia y anisotropía y colores de polarización pardos, a menudo se presenta bordeada por chatkalita; su composición química es: S=28,68-29,14, Fe=1,98-2,14, Cu=31,06-32,51, Zn=9,03-11,57 y Sn=26,39-27,03. Estannoidita es de color castaño, pleocroica (castaño-rosado a pardo-grisáceo y anisótropa con colores de polarización pardos y pardo-amarillentos, ocurre en parches irregulares y como bandas bordeando tennantita; su composición química es: S=29,11-29,83, Fe=8,45-10,30, Cu=38,05-41,01, Zn=3,18-4,90, y Sn=15,84-18,94. La reflectividad y dureza de pulido de

  9. Quaternary eruptive history and hazard-zone model at Nevado del Tolima and Cerro Machin volcanoes, Colombia

    Science.gov (United States)

    Thouret, J. C.; Cantagrel, J.-M.; Robin, C.; Murcia, A.; Salinas, R.; Cepeda, H.

    1995-07-01

    areas potentially affected by future eruptions both at Nevado del Tolima and at active Cerro Machin 12 km southward. The extent of areas likely to be affected by tephra-falls, debris flows, pyroclastic flows or surges, debris avalanches and lava flows is shown. Subplinian and plinian eruptions of Nevado del Tolima were used to represent the moderate and large events to be expected. 300,000 people live within a 35-km distance from those volcanoes, which have exhibited a behaviour more explosive than Nevado del Ruiz. Despite the small-sized ice cap, debris flows are the most probable hazard for even a minor eruption, because of the very steep slope gradient, and because of probable interactions of hot eruptive products with ice and snow. Additionally, scoria flows and debris avalanches can be directed toward the southeast and could be transformed into debris flows that would devastate the Combeima valley and suburbs of Ibaguécity, where about 50,000 people live

  10. The magnetic signature of hydrothermal systems in slow spreading environments

    Science.gov (United States)

    Tivey, Maurice A.; Dyment, Jérôme

    Slow spreading mid-ocean ridges like the Mid-Atlantic Ridge host a remarkable diversity of hydrothermal systems including vent systems located on the neovolcanic axis, large axial volcanoes, in transform faults and nontransform offsets, and associated with low-angle detachment faults, now recognized as a major tectonic feature of slow spreading environments. Hydrothermal systems are hosted in various lithologies from basalt to serpentinized peridotite and exposed lower oceanic crust. The substantial variations of hydrothermal processes active in these environments have important implications for the magnetic structure of oceanic crust and upper mantle. Hydrothermal processes can both destroy the magnetic minerals in basalt, diabase, and gabbro and create magnetic minerals by serpentinization of ultramafic rocks and deposition of magnetic minerals. We report on the diversity of magnetic anomaly signatures over the vent systems at slow spreading ridges and show that the lateral scale of hydrothermal alteration is fundamentally a local phenomenon. This highly focused process leads to magnetic anomalies on the scale of individual vent fields, typically a few hundreds of meters or less in size. To detect such features, high-resolution, near-bottom magnetic surveys are required rather than sea surface surveys. High-resolution surveys are now more tractable with deep-towed systems, dynamically positioned ships, and with the recent development of autonomous underwater vehicles, which allow detailed mapping of the seafloor on a scale relevant to hydrothermal activity. By understanding these present-day active hydrothermal systems, we can explore for yet to be discovered buried deposits preserved off-axis, both to determine past history of hydrothermal activity and for resource assessment.

  11. Hydrothermal monitoring data from the Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, Steven E.; Gelwick, Katrina D.; Randolph-Flagg, Noah G.; Crankshaw, Ilana M.; Lundstrom, Elizabeth A.; McCulloch, Callum L.; Murveit, Anna M.; Newman, Alice C.; Mariner, Robert H.; Bergfeld, D.; Tucker, Dave S.; Schmidt, Mariek E.; Spicer, Kurt R.; Mosbrucker, Adam; Evans, William C.

    2013-01-01

    This database serves as a repository for hydrothermal-monitoring data collected at 25 sites in the U.S. portion of the Cascade Range volcanic arc. These data are intended to quantify baseline hydrothermal variability at most (10 of 12) of the highest-risk volcanoes in the Cascades, as defined by the U.S. Geological Survey’s (USGS’) National Volcanic Early Warning System (NVEWS) report (Ewert and others, 2005).

  12. Accumulation of formamide in hydrothermal pores to form prebiotic nucleobases

    OpenAIRE

    Niether, Doreen; Afanasenkau, Dzmitry; Dhont, Jan K.G.; Wiegand, Simone

    2016-01-01

    Formamide is one of the important compounds from which prebiotic molecules can be synthesized, provided that its concentration is sufficiently high. For nucleotides and short DNA strands, it has been shown that a high degree of accumulation in hydrothermal pores occurs, so that temperature gradients might play a role in the origin of life [Baaske P, et al. (2007) Proc Natl Acad Sci USA 104(22):9346−9351]. We show that the same combination of thermophoresis and convection in hydrothermal pores...

  13. 峰与谷:两个牛仔的情感轨迹访《断背山》摄影罗德里戈·普瑞托%Interview with Rodrigo Prieto, Cinematographer of Brokeback Mountain

    Institute of Scientific and Technical Information of China (English)

    约翰·柯洪; 许斌

    2007-01-01

    @@ 引言 美国摄影师罗德里戈·普瑞托(Rodrigo Prieto)2007年与李安导演合作拍摄由张爱玲小说改编的电影,引起了国内电影制作者及媒体的广泛关注.作为当今好莱坞摄影师的中坚力量,罗德里戈·普瑞托的其他电影摄影作品均掷地有声,、、、、、、都是影迷们耳熟能详的作品,其中在今年各个电影节都有重大斩获,获得了多项大奖,更是在威尼斯电影节上获得金狮奖,并获得奥斯卡最佳导演、最佳改编剧本、最佳配乐三项大奖.于是我们从杂志上翻译了普瑞托关于的摄影访谈,来与读者共同了解这位摄影师与李安导演的工作细节,共同学习普瑞托的工作方法.

  14. Effect of hydrothermal treatment of coal on its associative structure

    Energy Technology Data Exchange (ETDEWEB)

    Shui Heng-fu; Wang Zhi-cai; Wang Gao-qiang; Niu Min-feng [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

    2006-10-15

    4 bituminous coals with different ranks were thermally and hydrothermally treated under different conditions, and the raw and treated coals were extracted with carbon disulfide/N-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent (1:1 by volume). It is found that the extraction yields of the thermal or hydrothermal treated coals at proper conditions increase in different extent. The increments of extraction yields for hydrothermal treated coals are higher than those of thermal treated coals. FT-IR shows that the adsorption peaks at 3410 cm{sup -1} attributed to OH group for the hydrothermal treated coals decrease, suggesting the dissociation of the coal aggregation structure due to the breakage of hydrogen bonds, resulting in the increase of extraction yields for the treated coals. For higher rank coal, the removal of minerals and the dissociation of {pi}-cation association after hydrothermal treatment of coal may be responsible for the increase of extraction yield. In addition, the mechanism of hydrothermal treatment of coal was discussed. 15 refs., 2 figs., 5 tabs.

  15. Hydrothermal processing of inorganic components of Hanford tank sludge

    International Nuclear Information System (INIS)

    Hydrothermal Processing (HTP) is an attractive approach for the treatment of Hanford tank sludge. Hydrothermal Processing refers to a waste treatment technique in which an aqueous waste stream is fed through a chemical reactor at elevated temperatures and pressures to effect desired chemical transformations and separations. Transformations such as organic and nitrate destruction and sludge reformulation have been demonstrated at pilot scale using simulants of Hanford tank wastes. At sufficiently high temperatures and pressures organics and nitrates are destroyed in seconds, producing primarily simple products such as CO32-, H2O, N2, N2O and OH-, and sludges are reduced in volume and reformulated as rapid settling oxides amenable to downstream separation, or in some cases reformulated as soluble products. This report describes the hydrothermal dissolution of chromium and chromium oxide; the hydrothermal oxidation of chromium with nitrate; hydrothermal dissolution of aluminum-bearing sludges; the solubility of aluminum compounds in caustic hydrothermal media; experimental techniques for the study of solubility and phase behavior; optical cell studies of basic aluminate solution solubilities; and high temperature, low density salt solubility in the packed-bed flow apparatus

  16. Hydrothermal iron flux variability following rapid sea level changes

    Science.gov (United States)

    Middleton, Jennifer L.; Langmuir, Charles H.; Mukhopadhyay, Sujoy; McManus, Jerry F.; Mitrovica, Jerry X.

    2016-04-01

    Sea level changes associated with Pleistocene glacial cycles have been hypothesized to modulate melt production and hydrothermal activity at ocean ridges, yet little is known about fluctuations in hydrothermal circulation on time scales longer than a few millennia. We present a high-resolution record of hydrothermal activity over the past 50 ka using elemental flux data from a new sediment core from the Mir zone of the TAG hydrothermal field at 26°N on the Mid-Atlantic Ridge. Mir sediments reveal sixfold to eightfold increases in hydrothermal iron and copper deposition during the Last Glacial Maximum, followed by a rapid decline during the sea level rise associated with deglaciation. Our results, along with previous observations from Pacific and Atlantic spreading centers, indicate that rapid sea level changes influence hydrothermal output on mid-ocean ridges. Thus, climate variability may discretize volcanic processing of the solid Earth on millennial time scales and subsequently stimulate variability in biogeochemical interactions with volcanic systems.

  17. Jurassic tetrapods and flora of Cañadón Asfalto Formation in Cerro Cóndor area, Chubut Province Flora y tetrápodos del Jurásico de la Formación Cañadón Asfalto en el área de Cerro Cóndor, provincia de Chubut

    OpenAIRE

    Ignacio H. Escapa; Juliana Sterli; Diego Pol; Laura Nicoli

    2008-01-01

    The plant and tetrapod fossil record of the Cañadón Asfalto Formation (Middle to Late Jurassic) found in Cerro Cóndor area (Chubut Province) is summarized here. The flora is dominated by conifers (Araucariaceae, Cupressaceae sensu lato) but also includes ferns and equisetaleans. The tetrapod fauna is composed of dinosaur taxa described in the 70's as well as other remains recently described and other vertebrate groups such as amphibians, turtles, and mammals. The amphibian remains have been i...

  18. Evolución petrotectónica del distrito minero Cerro Áspero y modelo de emplazamiento de los depósitos wolframíferos, Córdoba Petrotectonic evolution of the Cerro Aspero mining district and emplacement model of the wolframiferous deposits, Córdoba

    OpenAIRE

    D. Mutti; S. González Chiozza

    2005-01-01

    La geología relacionada con la intrusión granítica Cerro Áspero expone en el faldeo oriental de la sierra de Comechingones, mineralización metalífera diseminada y en brechas hidráulicas, conectada genéticamente a un grupo minero integrado por un sistema de enjambres de venas, vetas y mantos cuarzosos con direcciones NNO, ONO y N. La comarca presenta polimetamorfismo y al menos, dos eventos de cizallamiento simple (D3 y D4) y estructuras penetrativas (S2, S3 y S4) que se desarrollaron desde el...

  19. Health assessment for Lehigh Portland Cement Company, Mason City, Cerro Gordo County, Iowa, Region 10. CERCLIS No. IAD005288634. Preliminary report

    Energy Technology Data Exchange (ETDEWEB)

    1989-08-29

    The Lehigh Portland Cement Company Site is listed by the U.S. Environmental Protection Agency (EPA) on the National Priorities List (NPL). The site consists of approximately 150 acres and is located in the west side of U.S. Highway 65, in the northern section of Mason City, Cerro Gordo County, Iowa. Seven groundwater samples were analyzed together with 1 field blank (E E/FIT). No significant levels of contaminants were found in the private wells except for sodium (23 mg/1) from one residential well of unknown depth. The contaminants of concern are: arsenic, cadmium, lead, sodium, and sulfates. The site is considered to be of public health concern because of the risk resulting from potential exposure to hazardous substances via soil, surface water, groundwater and air.

  20. Zonificación ecológica del cerro "El Potosí", Galeana, Nuevo León, México

    Directory of Open Access Journals (Sweden)

    Mario A. García A.

    1999-01-01

    Full Text Available Como parte de la propuesta para definir al cerro "El Potosi" como Reserva Especial de la Biosfera, se elaboró un mapa de zonificacion que considera las zonas núcleo, de amortiguamiento y de recuperacion de habitat. Los criterios para la zonificación se consideraron la distribución de la vegetación y las poblaciones de fauna silvestre, derivada de la interpretacion cartográfica elaborada ad hoc, utilizand una imagen de stélite, además de la información sobre la biodiversidad. Se definiereon para la región diez tipos de vegetación y cuatro tipos de uso del suelo, en donde se distribuyen 45 especies bajo estatus de conservación: 19 de plantas y 26 de animales

  1. La minería hidráulica romana desarrollada en el Cerro del Sol (Granada) para explotar sus recursos auríferos

    OpenAIRE

    García-Pulido, Luis José

    2008-01-01

    [ES] La Alhambra se encuentra asentada en el extremo más occidental de un depósito aluvial con el nombre de Cerro del Sol. En este promontorio, que actúa como elemento separador entre las cuencas de los ríos Darro y Genil, está atestiguada la existencia de oro, encontrándose presente en el Conglomerado Alhambra. Con la romanización se inició la explotación a gran escala de los recursos auríferos del sudeste de la península Ibérica, haciendo uso de diversas técnicas propias de la minería hidrá...

  2. Approaching viscosity control: electrical heating of extra heavy oil as alternative to diluent injection in down hole in Cerro Negro Field, Faja Petrolifera del Orinoco

    Energy Technology Data Exchange (ETDEWEB)

    Salazar, Manuel [Petroleos de Venezuela SA, PDVSA (Venezuela)

    2011-07-01

    Electrical heating is a method used to enhance oil recovery in extra heavy oil reservoirs. This method can be used when diluent injection or other methods are not able to reduce oil viscosity sufficiently or when problems of product quality or quantity arise. The aim of this paper is to evaluate the performance of electrical heating, individually and simultaneously with injection of diluents. For this purpose, simulations were undertaken in one well with integrated electrical heating and diluent injection in Cerro Negro Field in the Orinoco oil belt, Venezuela. Results have shown that the application of both methods together is more profitable than the application of electrical heating alone. This paper demonstrated that the use of electrical heating and diluent injection combined is a valid alternative to diluent injection alone, reducing production loss.

  3. Justificación y diseño de falsa protección diferencial de barras para S.E Cerro de la Plata

    OpenAIRE

    Feliz Juárez, Javier Fernando

    2009-01-01

    La finalidad de nuestro proyecto es el diseño y justificación de un sistema de protección de barras de alimentación de 45 kV para la subestación eléctrica blindada de “Cerro de la Plata” (Madrid), propiedad de la compañía eléctrica Unión Fenosa Distribución. La particularidad de este diseño radica en la consecución de un sistema de protección de barras de subestación que cumpla las exigencias básicas de los sistemas de protección, sin la utilización de un relé de protección ded...

  4. Evolución magmática del Granito Peñón Rosado, Cerro Asperecito, flanco occidental de la sierra de Famatina

    Directory of Open Access Journals (Sweden)

    J.A. Dahlquist

    2006-03-01

    Full Text Available El granate es un mineral accesorio poco común en rocas ígneas y constituye un tema relevante de la petrología ígnea. Estudios combinados de petrología, química mineral, geoquímica de roca total y geoquímica isotópica en el cerro Asperecito indican que los granitoides con granate que forman el Granito Peñón Rosado (GPR fueron producidos por la fusión parcial de rocas metasedimentarias con subsecuente diferenciación durante su emplazamiento en el Ordovícico inferior-medio. En este sentido, la facies GPR1 representa un cristalizado temprano, la facies GPR2 representa un fundido diferenciado, y la facies GPR3 un fundido residual. El Granito Peñón Rosado, fue emplazado en condiciones de moderada temperatura (785ºC y presión media (4,4 kb en profundidades de la corteza media (~15 km. El emplazamiento casi sincrónico en la corteza media de una abundante suite metaluminosa durante el Ordovícico inferior-medio (468 Ma en el cerro Asperecito fue suficiente para inducir anatexis local de los metasedimentos circundantes. Los contenidos de elementos mayoritarios (CaO, Na2O y elementos traza (Rb, Sr, Ba en el Granito Peñón Rosado sugieren anatexis a partir de un material inmaduro acumulado en un plataforma continental. Así, el Granito Peñón Rosado es un típico granitoide tipo-S con granate y el modelo establecido aquí puede contribuir a un mejor entendimiento acerca de la cristalización del granate en rocas graníticas.

  5. Hydrothermal evolution of repository groundwaters in basalt

    International Nuclear Information System (INIS)

    Groundwaters in the near field of a radioactive waste repository in basalt will change their chemical composition in response to reactions with the basalt. These reactions will be promoted by the heat generated by the decaying waste. It is important to predict both the rate and the extent of these reactions, and the secondary minerals produced, because the alteration process controls the chemical environment affecting the corrosion of the canister, the solubility and complexation of migrating radionuclides, the reactivity of the alteration products to radionuclides sorption, and the porosity and permeability of the host rock. A comprehensive review of the literature leads to the preliminary finding that hydrothermally altering basalts in geothermal regions such as Iceland lead to a secondary mineralogy and groundwater composition similar to that expected to surround a repository. Furthermore, laboratory experiments replicating the alteration conditions approximate those observed in the field and expected in a repository. Preliminary estimates were made of the rate of hydration and devitrification of basaltic glass and the zero-order dissolution rate of basaltic materials. The rates were compared with those for rhyolitic glasses and silicate minerals. Preliminary calculations made of mixed process alteration kinetics, involving pore diffusion and surface reaction suggest that at temperatures greater than 1500C, alteration proceeds so rapidly as to become pervasive in normally fractured basalt exposed to higher temperatures in the field. 70 references

  6. Hydrothermal Gasification for Waste to Energy

    Science.gov (United States)

    Epps, Brenden; Laser, Mark; Choo, Yeunun

    2014-11-01

    Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

  7. Geomicrobiology of Deep-Sea Hydrothermal Vents

    Science.gov (United States)

    Jannasch, Holger W.; Mottl, Michael J.

    1985-08-01

    During the cycling of seawater through the earth's crust along the midocean ridge system, geothermal energy is transferred into chemical energy in the form of reduced inorganic compounds. These compounds are derived from the reaction of seawater with crustal rocks at high temperatures and are emitted from warm (bacteria use these reduced chemical species as sources of energy for the reduction of carbon dioxide (assimilation) to organic carbon. These bacteria form the base of the food chain, which permits copious populations of certain specifically adapted invertebrates to grow in the immediate vicinity of the vents. Such highly prolific, although narrowly localized, deep-sea communities are thus maintained primarily by terrestrial rather than by solar energy. Reduced sulfur compounds appear to represent the major electron donors for aerobic microbial metabolism, but methane-, hydrogen-, iron-, and manganese-oxidizing bacteria have also been found. Methanogenic, sulfur-respiring, and extremely thermophilic isolates carry out anaerobic chemosynthesis. Bacteria grow most abundantly in the shallow crust where upwelling hot, reducing hydrothermal fluid mixes with downwelling cold, oxygenated seawater. The predominant production of biomass, however, is the result of symbiotic associations between chemolithotrophic bacteria and certain invertebrates, which have also been found as fossils in Cretaceous sulfide ores of ophiolite deposits.

  8. Reconnaissance of the hydrothermal resources of Utah

    Energy Technology Data Exchange (ETDEWEB)

    Rush, F.E.

    1983-01-01

    Geologic factors in the Basin and Range province in Utah are more favorable for the occurrence of geothermal resources than in other areas on the Colorado Plateaus or in the Middle Rocky Mountains. These geologic factors are principally crustal extension and crustal thinning during the last 17 million years. Basalts as young as 10,000 years have been mapped in the area. High-silica volcanic and intrusive rocks of Quaternary age can be used to locate hydrothermal convection systems. Drilling for hot, high-silica, buried rock bodies is most promising in the areas of recent volcanic activity. Southwestern Utah has more geothermal potential than other parts of the Basin and Range province in Utah. The Roosevelt Hot Springs area, the Cove Fort-Sulphurdale area, and the area to the north as far as 60 kilometers from them probably have the best potential for geothermal development for generation of electricity. Other areas with estimated reservoir temperatures greater than 150/sup 0/C are Thermo, Monroe, Red Hill (in the Monroe-Joseph Known Geothermal Resource Area), Joseph Hot Springs, and the Newcastle area. The rates of heat and water discharge are high at Crater, Meadow, and Hatton Hot Springs, but estimated reservoir temperatures there are less than 150/sup 0/C. Additional exploration is needed to define the potential in three additional areas in the Escalante Desert. 28 figs., 18 tabs.

  9. Additive effects of acetic acid upon hydrothermal reaction of amylopectin

    International Nuclear Information System (INIS)

    It is well known that over 0.8 kg kg−1 of starch is consisted of amylopectin (AP). In this study, production of glucose for raw material of ethanol by hydrothermal reaction of AP as one of the model compound of food is discussed. Further, additive effects of acetic acid upon hydrothermal reactions of AP are also investigated. During hydrothermal reaction of AP, production of glucose occurred above 453 K, and the glucose yield increased to 0.48 kg kg−1 at 473 K. Upon hydrothermal reaction of AP at 473 K, prolongation of the holding time was not effective for the increase of the glucose yield. Upon hydrothermal reaction of AP at 473 K for 0 s, the glucose yield increased significantly by addition between 0.26 mol L−1 and 0.52 mol L−1 of acetic acid. However, the glucose yield decreased and the yield of the other constituents increased with the increases of concentration of acetic acid from 0.65 mol L−1 to 3.33 mol L−1. It was considered that hydrolysis of AP to yield glucose was enhanced due to the increase of the amount of proton derived from acetic acid during hydrothermal reaction with 0.52 mol L−1 of acetic acid. -- Highlights: ► Glucose production by hydrothermal reaction of amylopectin (AP) at 473 K. ► Glucose yield increased to 0.48 kg kg-1 at 473 K. ► Prolongation of holding time was not effective for glucose yield. ► Glucose yield increased significantly by acetic acid (0.26–0.52 mol L-1) addition. ► Hydrolysis of AP to glucose was enhanced due to increase of proton from acetic acid.

  10. Hydrothermal synthesis of pyrochlores and their characterization

    Science.gov (United States)

    Redkin, Alexander F.; Ionov, Andrey M.; Kotova, Nataliya P.

    2013-10-01

    Pyrochlores, microlites, and U-betafites of pyrochlore group minerals were obtained from mixing experiments of the corresponding oxides and fluorides by hydrothermal synthesis at T = 800 °C and P = 200 MPa in the solution of 1.0 M NaF. The presence of U4+ in pyrochlore does not affect the cell parameter, which for the phases of pyrochlore-microlite series is 10.42 ± 0.01 Å. In a system with an excess of UO2, pyrochlores and microlites, containing uranium up to 0.2-0.3 atoms per formula unit (apfu), are formed. In the uranium-free system of betafites composition, perovskites and Ti-bearing pyrochlores are formed. U-pyrochlores of betafite series, containing 2Ti = Nb + Ta in moles, have cubic cell parameters of 10.26 ± 0.02 Å and U4+ isomorphic capacity of 0.4-0.5 apfu. In the pyrochlore structure, U4+ may substitute for Ca2+ and Na+ cations in the eightfold site. In pyrochlores of pyrochlore-microlite series, Ca2+ is replaced by U4+, while in pyrochlores of betafite series, U4+ replaces Na+. Phases with pyrochlore structure, containing U5+ and U6+ in the sixfold site, usually occupied by Nb5+, Ta5+, and Ti4+, are formed under oxidizing conditions (Cu-Cu2O buffer). They are characterized by low content of Nb5+, Ta5+ (<0.1 apfu), and anomalous behavior of the crystal lattice (compression, instead of expansion). Under natural conditions, the formation of pyrochlores containing a significant amount of U5+ and U6+ is unlikely.

  11. Variability in the microbial communities and hydrothermal fluid chemistry at the newly discovered Mariner hydrothermal field, southern Lau Basin

    Science.gov (United States)

    Takai, Ken; Nunoura, Takuro; Ishibashi, Jun-Ichiro; Lupton, John; Suzuki, Ryohei; Hamasaki, Hiroshi; Ueno, Yuichiro; Kawagucci, Shinsuke; Gamo, Toshitaka; Suzuki, Yohey; Hirayama, Hisako; Horikoshi, Koki

    2008-06-01

    A newly discovered hydrothermal field called the Mariner field on the Valu Fa Ridge in the southern Lau Basin was explored and characterized with geochemical and microbiological analyses. The hydrothermal fluid discharging from the most vigorous vent (Snow Chimney, maximum discharge temperature 365°C) was boiling at the seafloor at a depth of 1908 m, and two distinct end-member hydrothermal fluids were identified. The fluid chemistry of the typical Cl-enriched and Cl-depleted hydrothermal fluids was analyzed, as was the mineralogy of the host chimney structures. The variability in the fluid chemistry was potentially controlled by the subseafloor phase-separation (vapor loss process) and the microbial community activities. Microbial community structures in three chimney structures were investigated using culture-dependent and -independent techniques. The small subunit (SSU) rRNA gene clone analysis revealed that both bacterial and archaeal rRNA gene communities on the chimney surfaces differed among three chimneys. Cultivation analysis demonstrated significant variation in the culturability of various microbial components among the chimneys, particularly of thermophilic H2-oxidizing (and S-oxidizing) chemolithoautotrophs such as the genera Aquifex and Persephonella. The physical and chemical environments of chimney surface habitats are still unresolved and do not directly extrapolate the environments of possible subseafloor habitats. However, the variability in microbial community found in the chimneys also provides an insight into the different biogeochemical interactions potentially affected by the phase separation of the hydrothermal fluids in the subseafloor hydrothermal habitats. In addition, comparison with other deep-sea hydrothermal systems revealed that the Mariner field microbial communities have unusual characteristics.

  12. Hydrothermal and magmatic couplings at mid-ocean ridges : controls on the locations of high-temperature hydrothermal vent fields

    Science.gov (United States)

    Fontaine, Fabrice; Rabinowicz, Michel; Cannat, Mathilde; Escartin, Javier

    2013-04-01

    The heat output and thermal regime of oceanic spreading centers are strongly controlled by boundary layer processes between the hydrothermal system and the underlying crustal magma chamber, which remain to be fully understood. In thermal models, the dynamical interactions between the hydrothermal system and the deeper part of the lithosphere affected by processes such as magma chamber convection, magma crystallization and latent heat release, or simple conduction, is usually not considered and a ad-hoc temperature or heat flux is prescribed at the base of the hydrothermal layer. In this work we develop original two-dimensional numerical models of the interactions between a shallow cellular hydrothermal (porous) system at temperatures hydrothermal fields such as those discovered along the East Pacific Rise at 9°50'N or along the Juan de Fuca ridge/Endeavour segment for example. One hypothesis is that these fields require the formation of "elongated" hydrothermal convection cells that cool the crust on 5-10 kms, but the processes controlling the formation of such large aspect ratio (length/height) are poorly constrain. Our models show that such cells naturally arise from the dynamical coupling between a « low-viscosity », convecting lower-crust and a low-permeability upper hydrothermal layer. They also predict along-axis variations in the depth of the axial magma lens (AMC) seismic reflector of fast- and intermediate-spreading axes, and constrain lower oceanic crust cooling rates. They also suggest a dynamic link between upper oceanic crust along-axis permeability variations and stresses due to lower crust magmatic flow. We discuss the likelihood of this range of viscosity and permeability using available oceanic and ophiolites constraints and suggest that our work can motivate and help design future deep-sea experiments (e.g., drilling…).

  13. Concerns of Hydrothermal Degradation in CAD/CAM Zirconia

    Science.gov (United States)

    Kim, J.-W.; Covel, N.S.; Guess, P.C.; Rekow, E.D.; Zhang, Y.

    2010-01-01

    Zirconia-based restorations are widely used in prosthetic dentistry; however, their susceptibility to hydrothermal degradation remains elusive. We hypothesized that CAD/CAM machining and subsequent surface treatments, i.e., grinding and/or grit-blasting, have marked effects on the hydrothermal degradation behavior of Y-TZP. CAD/CAM-machined Y-TZP plates (0.5 mm thick), both with and without subsequent grinding with various grit sizes or grit-blasting with airborne alumina particles, were subjected to accelerated aging tests in a steam autoclave. Results showed that the CAD/CAM-machined surfaces initially exhibited superior hydrothermal degradation resistance, but deteriorated at a faster rate upon prolonged autoclave treatment compared with ground and grit-blasted surfaces. The accelerated hydrothermal degradation of CAD/CAM surfaces is attributed to the CAD/CAM machining damage and the absence of surface compressive stresses in the fully sintered material. Clinical relevance for surface treatments of zirconia frameworks in terms of hydrothermal and structural stabilities is addressed. PMID:19966039

  14. Impact-generated Hydrothermal Activity at the Chicxulub Crater

    Science.gov (United States)

    Kring, D. A.; Zurcher, L.; Abramov, O.

    2007-05-01

    Borehole samples recovered from PEMEX exploration boreholes and an ICDP scientific borehole indicate the Chicxulub impact event generated hydrothermal alteration throughout a large volume of the Maya Block beneath the crater floor and extending across the bulk of the ~180 km diameter crater. The first indications of hydrothermal alteration were observed in the crater discovery samples from the Yucatan-6 borehole and manifest itself in the form of anhydrite and quartz veins. Continuous core from the Yaxcopoil-1 borehole reveal a more complex and temporally extensive alteration sequence: following a brief period at high temperatures, impact- melt-bearing polymict breccias and a thin, underlying unit of impact melt were subjected to metasomatism, producing alkali feldspar, sphene, apatite, and magnetite. As the system continued to cool, smectite-series phyllosilicates appeared. A saline solution was involved. Stable isotopes suggest the fluid was dominated by a basinal brine created mostly from existing groundwater of the Yucatan Peninsula, although contributions from down-welling water also occurred in some parts of the system. Numerical modeling of the hydrothermal system suggests circulation occurred for 1.5 to 2.3 Myr, depending on the permeability of the system. Our understanding of the hydrothermal system, however, is still crude. Additional core recovery projects, particularly into the central melt sheet, are needed to better evaluate the extent and duration of hydrothermal alteration.

  15. Magma to Microbe: Modeling Hydrothermal Processes at Ocean Spreading Centers

    Science.gov (United States)

    Lowell, Robert P.; Seewald, Jeffrey S.; Metaxas, Anna; Perfit, Michael R.

    Hydrothermal systems at oceanic spreading centers reflect the complex interactions among transport, cooling and crystallization of magma, fluid circulation in the crust, tectonic processes, water-rock interaction, and the utilization of hydrothermal fluids as a metabolic energy source by microbial and macro-biological ecosystems. The development of mathematical and numerical models that address these complex linkages is a fundamental part the RIDGE 2000 program that attempts to quantify and model the transfer of heat and chemicals from "mantle to microbes" at oceanic ridges. This volume presents the first "state of the art" picture of model development in this context. The most outstanding feature of this volume is its emphasis on mathematical and numerical modeling of a broad array of hydrothermal processes associated with oceanic spreading centers. By examining the state of model development in one volume, both cross-fertilization of ideas and integration across the disparate disciplines that study seafloor hydrothermal systems is facilitated. Students and scientists with an interest in oceanic spreading centers in general and more specifically in ridge hydrothermal processes will find this volume to be an up-to-date and indispensable resource.

  16. A NOVEL HYDROTHERMAL SYNTHESIS METHOD FOR BARIUM FERRITE

    Institute of Scientific and Technical Information of China (English)

    Kang Li; Hongchen Gu; Qun Wei

    2004-01-01

    In the present work, fine barium ferrite powder has been synthesized through a one-step hydrothermal process in an autoclave at [OH-]/[Cl-] ratio of 2:1 in the temperature range from 180 to 260 ℃ using barium chloride (BaCl2), ferrous chloride (FeCl2) and potassium nitrate (KNO3) as the starting materials. Both particle size and saturation magnetization (Ms) increase with increasing hydrothermal reaction temperature, while the intrinsic coercivity (iHc) peaks at 685 Oe at 230 ℃. Morphology progress from the barium ferrite precursor particles to the barium hexaferrite particles has been monitored with increasing hydrothermal reaction time at 230 ℃ in the autoclave.

  17. Hydrothermal electrocatalytic oxidation for the treatment of herbicides wastewater.

    Science.gov (United States)

    Xiao, Hanshuang; Lv, Baoying; Gao, Junxia; Zhao, Guohua

    2016-05-01

    A hydrothermal electrocatalytic oxidation (HTECO) method is adopted to treat the biorefractory and toxic 2,4-dichlorophenoxyacetic acid (2,4-D) herbicides wastewater on nano-Pt/Ti electrode in the existence of H2O2. Comparisons for the removal of 2,4-D and total organic carbon (TOC) have been carried out between HTECO with individual electrochemical oxidation (EO) and hydrothermal catalytic oxidation (HTCO), showing that high mineralization efficiency was obtained in HTECO process. The possible factors resulting in the high removal efficiency in HTECO process have been studied by investigating the properties of the electrode and solution in hydrothermal condition, the amount of active radicals, the decay kinetic, and evolution of main intermediates of 2,4-D. Thus, an enhanced mechanism for HTECO method for the treatment of herbicides wastewater has been obtained. PMID:26865489

  18. Fractionation of Boron Isotopes in Icelandic Hydrothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Aggarwal, J.K.; Palmer, M.R.

    1995-01-01

    Boron isotope ratios have been determined in a variety of different geothermal waters from hydrothermal systems across Iceland. Isotope ratios from the high temperature meteoric water recharged systems reflect the isotope ratio of the host rocks without any apparent fractionation. Seawater recharged geothermal systems exhibit more positive {delta}{sup 11}B values than the meteoric water recharged geothermal systems. Water/rock ratios can be assessed from boron isotope ratios in the saline hydrothermal systems. Low temperature hydrothermal systems also exhibit more positive {delta}{sup 11}B than the high temperature systems, indicating fractionation of boron due to adsorption of the lighter isotope onto secondary minerals. Fractionation of boron in carbonate deposits may indicate the level of equilibrium attained within the systems.

  19. Coordination Hydrothermal Interconnection Java-Bali Using Simulated Annealing

    Science.gov (United States)

    Wicaksono, B.; Abdullah, A. G.; Saputra, W. S.

    2016-04-01

    Hydrothermal power plant coordination aims to minimize the total cost of operating system that is represented by fuel costand constraints during optimization. To perform the optimization, there are several methods that can be used. Simulated Annealing (SA) is a method that can be used to solve the optimization problems. This method was inspired by annealing or cooling process in the manufacture of materials composed of crystals. The basic principle of hydrothermal power plant coordination includes the use of hydro power plants to support basic load while thermal power plants were used to support the remaining load. This study used two hydro power plant units and six thermal power plant units with 25 buses by calculating transmission losses and considering power limits in each power plant unit aided by MATLAB software during the process. Hydrothermal power plant coordination using simulated annealing plants showed that a total cost of generation for 24 hours is 13,288,508.01.

  20. Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

    Science.gov (United States)

    Plumlee, Geoffrey S.; Ridley, W. Ian

    1992-01-01

    Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

  1. Evidences for incipient hydrothermal event(s) in the Central Indian Basin: A review

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.

    of the basaltic glasses, (3) chemical variations in the ferromanganese crusts, and (4) abundance of volcanogenic-hydrothermal material (vhm) that includes ochrous sediments and magnetite spherules. The vhm suggests its origin by interaction of Fe-rich hydrothermal...

  2. Hydrothermal signature in ferromanganese oxide coatings on pumice from the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.; Mascarenhas-Pereira, M.B.L.; Nath, B.N.

    , hydrothermal and diagenetic inputs were assessed in terms of ternary mixing patterns using REE mass balance equations. Furthermore, the hypothetical Ce anomaly (Ce/Ce*) was calculated using ternary mixing calculations for hydrogenous, hydrothermal...

  3. Geología de la Formación Cerro Negro (Cretácico en Isla Livingston: aportes a su geocronología y contenido paleontológico

    Directory of Open Access Journals (Sweden)

    C.A. Parica

    2007-12-01

    Full Text Available La península Byers se encuentra en el extremo occidental de la isla Livingston, archipiélago de las islas Shetland del Sur. Geológicamente está caracterizada por depósitos marinos, continentales y volcanismo cretácico-terciario que son incluidos en la Formación Cerro Negro de la sección superior del Grupo Byers. Las secuencias magmáticas han sido divididas en dos grupos principales, el primero comprende a las rocas piroclásticas y reúne cinco unidades con un importante desarrollo y distribución en el área. Por su parte, el segundo grupo comprende lavas e intrusivos aflorantes en cerros Don Carlos, Usnea (Usnea Plug, Chester (Chester Cone, Sealer (Sealer Hill y Negro (Negro Hill. Los términos sedimentarios incluyen conglomerados, areniscas y pelitas, de color gris verdoso con estratificación entrecruzada (tanto tabular como en artesa, raramente estratos macizos, laminación horizontal (en algunos casos de naturaleza rítmica, y estructuras de deformación sinsedimentaria (principalmente laminación convoluta. Se propone un ambiente fluvial de depositación, con canales dominados por carga de lecho y barras areno-gravosas bien desarrolladas. En lo que corresponde al sector de planicie de inundación, predominó allí la depositación de material limo-arcilloso por corrientes tractivas débiles durante las crecientes. En las áreas deprimidas de las planicies habría tenido lugar la formación de cuerpos de aguas de poca profundidad en los que se vió favorecida la preservación de la macro y microflora. En las nuevas localidades fosilíferas de península Byers, Domo Rotch (Rotch Dome, cerro Don Carlos, Lomada de las Plantas y 904, ha sido reconocida la presencia de las especies: Araucarites sp., Archangelskya furcata Herbst, Cladophlebis sp., Dictyozamites sp., Elatocladus sp, Phyllopteroides sp., Pseudoctenis sp., Ptyllophyllum menendezii Cantrill, Sphenopteris sp., Eocyathea remesaliae Césari, Sergioa austrina Césari y

  4. Hydrothermal synthesis as a route to mineralogically-inspired structures.

    Science.gov (United States)

    McMillen, Colin D; Kolis, Joseph W

    2016-02-21

    The use of high temperature hydrothermal reactions to prepare crystals having mineralogically-related structures is described. Complex naturally occurring minerals can have fascinating structures and exhibit important features like low dimensionality, noncentrosymmetry, or ion channels that can provide excellent guideposts for the designed synthesis of new materials. Actual minerals, even though they may have intriguing physical properties, are often unsuitable for study because of the persistent impurities inevitably present in natural samples. Hydrothermal fluids at relatively high temperatures provide access to large, high quality single crystals of structures with mineral-like structures. This enables the study of physical properties like ionic conduction, magnetic spin frustration and non-linear optical behavior. Some fundamental considerations of the hydrothermal technique are discussed in the context of synthesizing mineralogically-inspired materials. The metal vanadates provide a surprisingly rich and diversified range of compounds and are selected to illustrate many of the concepts described here. A series of low dimensional mineral analogs featuring isolated units, chains, and layers have been prepared in the laboratory as large single crystals using a high temperature hydrothermal synthetic methods, and their physical properties are under investigation. The metal silicates are also highlighted as another promising field of exploration, since their hydrothermal synthesis surprisingly lags behind the enormous literature of the natural silicate minerals. The introduction of heteroelements, such as boron to make borosilicates, appears to also open the door to additional new materials. Many of these new materials have direct equivalents in the mineral kingdom, while others have no known analogs but are reminiscent of minerals and can be classified in the same ways. From these initial results there appears to be a very rich vein of synthetic minerals waiting

  5. Fate of Organic Micropollutants during Hydrothermal Carbonization

    Science.gov (United States)

    Weiner, B.; Baskyr, I.; Pörschmann, J.; Kopinke, F.-D.

    2012-04-01

    The hydrothermal carbonization (HTC) is an exothermic process, in which biomass in an aqueous suspension is transformed into a bituminous coal-like material (hydrochar) at temperatures between 180-250°C and under moderate pressure. With these process conditions, little gas is generated (1-5%), and a fraction of the organic carbon is dissolved in the aqueous phase (10-30%) but the largest part is obtained as solid char. The respective yields and the molecular composition depend on the choice of educts and the process conditions, such as temperature, pH-value, and reaction time. Various biomass-educts have recently been studied, such as waste materials from agriculture, brewer's spent grains, sewage sludge, as well as wood and paper materials. Besides their use for energy generation, the hydrochars have also been investigated as soil amendments. Prior to addition of the chars to soil, these should be free of toxic components that could be released into the environment as harmful organic pollutants. Herein, the potential for the degradation of trace organic pollutants, such as pesticides and pharmaceuticals, under typical HTC conditions will be presented. The degradation of selected organic pollutants with different polarity and hydrophobicity was investigated. Scope and limitations of the degradation potential of the HTC are discussed on examples of micro pollutants such as hormones, residues of pharmaceuticals and personal care products including their metabolites, and pesticides. We will show that the target analytes are partially and in some cases completely degraded. The degree of degradation depends on the HTC process conditions such as reaction temperature and time, the solution pH value, the presence of catalysts or additional reagents. The biotic and abiotic degradation of chlorinated organic compounds, in particular chlorinated aromatics, has been a well-known environmental problem and remains a challenging issue for the development of a HTC process for

  6. An improved hydrothermal diamond anvil cell.

    Science.gov (United States)

    Li, Jiankang; Bassett, W A; Chou, I-Ming; Ding, Xin; Li, Shenghu; Wang, Xinyan

    2016-05-01

    A new type of HDAC-V hydrothermal diamond anvil cell (HDAC-VT) has been designed to meet the demands of X-ray research including X-Ray Fluorescence, X-ray Absorption Spectroscopy, and small angle X-ray scattering. The earlier version of HDAC-V that offered a large rectangular solid angle used two posts and two driver screws on both sides of a rectangular body. The new version HDAC-VT in a triangular shape has two alternative guide systems, either three posts inserted into bushings suitable for small anvil faces or linear ball bearings suitable for large anvil faces. The HDAC-VT having three driver screws offers the advantage of greater control and stability even though it sacrifices some of the size of solid angle. The greater control allows better sealing of samples, while greater stability results in longer survival for anvils and ceramic parts. This improved design retains several beneficial features of the original HDAC-V as well. These include the small collar that surrounds the heater and sample chamber forming an Ar + H2 gas chamber to protect diamonds and their heating parts from being oxidized. Three linear ball bearings, when used, fit to the three posts prevent seizing that can result from deterioration of lubricant at high temperatures. Positioning the posts and bearings outside of the gas chamber as in HDAC-V also prevents seizing and possible deformation due to overheating. In order to control the heating rate precisely with computer software, we use Linkam T95 and have replaced the Linkam 1400XY heating stage with the HDAC-VT allowing the HDAC to be heated to 950 °C at a rate from 0.01 °C/min to 50 °C/min. We have used the HDAC-VT and Linkam T95 to observe in situ nucleation and growth of zabuyelite in aqueous fluid and to homogenize melt inclusions in quartz from three porphyry deposits in Shanxi, China. PMID:27250393

  7. Effect of hydrothermal heat treatment on magnetic properties of copper zinc ferrite rf sputtered films

    OpenAIRE

    Jasmeet Kaur; Thirupathi Gadipelly; Singh, R.

    2016-01-01

    The hydrothermal treatment to the nano-structured films can overcome the destruction of the films. The Cu-Zn Ferrite films were fabricated by RF-sputtering on quartz substrates. Subsequently, the as deposited films were heat treated using hydrothermal process. The X-ray diffraction pattern of the as-deposited and hydrothermal treated films indicate nano-crystalline cubic spinel structure. The amorphous nature of the films is removed after hydrothermal treatment with decreased crystallite size...

  8. Dynamic behavior of Kilauea Volcano and its relation to hydrothermal systems and geothermal energy

    Science.gov (United States)

    Kauhikaua, Jim; Moore, R.B.; ,

    1993-01-01

    Exploitation of hydrothermal systems on active basaltic volcanoes poses some unique questions about the role of volcanism and hydrothermal system evolution. Volcanic activity creates and maintains hydrothermal systems while earthquakes create permeable fractures that, at least temporarily, enhance circulation. Magma and water, possibly hydrothermal water, can interact violently to produce explosive eruptions. Finally, we speculate on whether volcanic behavior can be affected by high rates of heat extraction.

  9. Concerns of Hydrothermal Degradation in CAD/CAM Zirconia

    OpenAIRE

    Kim, J.-W.; Covel, N.S.; Guess, P.C.; Rekow, E.D.; Zhang, Y.

    2010-01-01

    Zirconia-based restorations are widely used in prosthetic dentistry; however, their susceptibility to hydrothermal degradation remains elusive. We hypothesized that CAD/CAM machining and subsequent surface treatments, i.e., grinding and/or grit-blasting, have marked effects on the hydrothermal degradation behavior of Y-TZP. CAD/CAM-machined Y-TZP plates (0.5 mm thick), both with and without subsequent grinding with various grit sizes or grit-blasting with airborne alumina particles, were subj...

  10. Hydrothermal liquefaction of microalgae's for bio oil production

    DEFF Research Database (Denmark)

    Toor, Saqib; Reddy, Harvind; Deng, Shuguang;

    process water for algae cultivation. GC-MS, elemental analyzer, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-oil yield of 46% was obtained on Nannochloropsis salina at 310 °C...... and 107 bar. For Spirulina platensis algae sample, the highest bio-oil yield is 38% at 350 °C and 195 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins...

  11. Fabrication Of Titania Nanotubes By A Modified Hydrothermal Method

    OpenAIRE

    Meor Yusoff M.S; Masliana M M; Wilfred Paulus; Parimala Devi; Mahdi E. Mahmoud

    2011-01-01

    The main setback of the fabrication of titania nanotubes by the hydrothermal method is the long dissolution time and the usage of highly concentrated NaOH. Our group has managed to develop a modified hydrothermal process that is capable of fabricating titania nanotubes in a shorter timespan while using a more dilute NaOH solution. The study shows that the titania nanotubes starts to form from 7 hours of dissolution, and more nanotubes is produced as the dissolution duration is extended. Simil...

  12. Hydrothermal systems on Mars: an assessment of present evidence.

    Science.gov (United States)

    Farmer, J D

    1996-01-01

    Hydrothermal processes have been suggested to explain a number of observations for Mars, including D/H ratios of water extracted from Martian meteorites, as a means for removing CO2 from the Martian atmosphere and sequestering it in the crust as carbonates, and as a possible origin for iron oxide-rich spectral units on the floors of some rifted basins (chasmata). There are numerous examples of Martian channels formed by discharges of subsurface water near potential magmatic heat sources, and hydrothermal processes have also been proposed as a mechanism for aquifer recharge needed to sustain long term erosion of sapping channels. The following geological settings have been identified as targets for ancient hydrothermal systems on Mars: channels located along the margins of impact crater melt sheets and on the slopes of ancient volcanoes; chaotic and fretted terranes where shallow subsurface heat sources are thought to have interacted with ground ice; and the floors of calderas and rifted basins (e.g. chasmata). On Earth, such geological environments are often a locus for hydrothermal mineralization. But we presently lack the mineralogical information needed for a definitive evaluation of hypotheses. A preferred tool for identifying minerals by remote sensing methods on Earth is high spatial resolution, hyperspectral, near-infrared spectroscopy, a technique that has been extensively developed by mineral explorationists. Future efforts to explore Mars for ancient hydrothermal systems would benefit from the application of methods developed by the mining industry to look for similar deposits on Earth. But Earth-based exploration models must be adapted to account for the large differences in the climatic and geological history of Mars. For example, it is likely that the early surface environment of Mars was cool, perhaps consistently below freezing, with the shallow portions of hydrothermal systems being dominated by magma-cryosphere interactions. Given the smaller

  13. Global Fluorine Flux Associated with Submarine Hydrothermal Fluids

    Science.gov (United States)

    Kagoshima, T.; Sano, Y.

    2015-12-01

    We estimated a fluorine flux associated with hydrothermal fluid emission at mid-ocean ridges (MOR) based on vent fluid chemistry and MORB vesicle compositions. Multiplication of fluorine concentrations in submarine hydrothermal fluids and the vent fluid flux at MOR may give us an estimate of fluorine flux at MOR. A worldwide vent chemistry research [1] suggested that submarine vent fluids are depleted in fluorine (Elsevier, London). [2] Coogan & Dosso (2012) EPSL 323-324, 92-101. [3] Kagoshima et al. (2014) Japan Geoscience Union Meeting 2014 Abstract #SGC56-P01. [4] Fischer (2008) Geochem. J. 42, 21-38.

  14. The characteristics of hydrothermal plumes observed in the Precious Stone Mountain hydrothermal field, the Galapagos spreading center

    Science.gov (United States)

    Chen, S.; Tao, C.; Li, H.; Zhou, J.; Deng, X.; Tao, W.; Zhang, G.; Liu, W.; He, Y.

    2014-12-01

    The Precious Stone Mountain hydrothermal field (PSMHF) is located on the southern rim of the Galapagos Microplate. It was found at the 3rd leg of the 2009 Chinese DY115-21 expedition on board R/V Dayangyihao. It is efficient to learn the distribution of hydrothermal plumes and locate the hydrothermal vents by detecting the anomalies of turbidity and temperature. Detecting seawater turbidity by MAPR based on deep-tow technology is established and improved during our cruises. We collected data recorded by MAPR and information from geological sampling, yielding the following results: (1)Strong hydrothermal turbidity and temperature anomalies were recorded at 1.23°N, southeast and northwest of PSMHF. According to the CTD data on the mooring system, significant temperature anomalies were observed over PSMHF at the depth of 1,470 m, with anomalies range from 0.2℃ to 0.4℃, which gave another evidence of the existence of hydrothermal plume. (2)At 1.23°N (101.4802°W/1.2305°N), the nose-shaped particle plume was concentrated at a depth interval of 1,400-1,600 m, with 200 m thickness and an east-west diffusion range of 500 m. The maximum turbidity anomaly (0.045 △NTU) was recorded at the depth of 1,500 m, while the background anomaly was about 0.01△NTU. A distinct temperature anomaly was also detected at the seafloor near 1.23°N. Deep-tow camera showed the area was piled up by hydrothermal sulfide sediments. (3) In the southeast (101.49°W/1.21°N), the thickness of hydrothermal plume was 300 m and it was spreading laterally at a depth of 1,500-1,800 m, for a distance about 800 m. The maximum turbidity anomaly of nose-shaped plume is about 0.04 △NTU at the depth of 1,600 m. Distinct temperature anomaly was also detected in the northwest (101.515°W/1.235°N). (4) Terrain and bottom current were the main factors controlling the distribution of hydrothermal plume. Different from the distribution of hydrothermal plumes on the mid-ocean ridges, which was mostly

  15. Living with the Heat. Submarine Ring of Fire--Grades 5-6. Hydrothermal Vent Ecology.

    Science.gov (United States)

    National Oceanic and Atmospheric Administration (DOC), Rockville, MD.

    This activity is designed to teach about hydrothermal vent ecology. Students are expected to describe how hydrothermal vents are formed and characterize the physical conditions at these sites, explain chemosynthesis and contrast this process with photosynthesis, identify autotrophic bacteria as the basis for food webs in hydrothermal vent…

  16. Characterization of post-fire surface cover, soils, and burn severity at the Cerro Grande Fire, New Mexico, using hyperspectral and multispectral remote sensing

    Science.gov (United States)

    Kokaly, R.F.; Rockwell, B.W.; Haire, S.L.; King, T.V.V.

    2007-01-01

    Forest fires leave behind a changed ecosystem with a patchwork of surface cover that includes ash, charred organic matter, soils and soil minerals, and dead, damaged, and living vegetation. The distributions of these materials affect post-fire processes of erosion, nutrient cycling, and vegetation regrowth. We analyzed high spatial resolution (2.4??m pixel size) Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data collected over the Cerro Grande fire, to map post-fire surface cover into 10 classes, including ash, soil minerals, scorched conifer trees, and green vegetation. The Cerro Grande fire occurred near Los Alamos, New Mexico, in May 2000. The AVIRIS data were collected September 3, 2000. The surface cover map revealed complex patterns of ash, iron oxide minerals, and clay minerals in areas of complete combustion. Scorched conifer trees, which retained dry needles heated by the fire but not fully combusted by the flames, were found to cover much of the post-fire landscape. These scorched trees were found in narrow zones at the edges of completely burned areas. A surface cover map was also made using Landsat Enhanced Thematic Mapper plus (ETM+) data, collected September 5, 2000, and a maximum likelihood, supervised classification. When compared to AVIRIS, the Landsat classification grossly overestimated cover by dry conifer and ash classes and severely underestimated soil and green vegetation cover. In a comparison of AVIRIS surface cover to the Burned Area Emergency Rehabilitation (BAER) map of burn severity, the BAER high burn severity areas did not capture the variable patterns of post-fire surface cover by ash, soil, and scorched conifer trees seen in the AVIRIS map. The BAER map, derived from air photos, also did not capture the distribution of scorched trees that were observed in the AVIRIS map. Similarly, the moderate severity class of Landsat-derived burn severity maps generated from the differenced Normalized Burn Ratio (dNBR) calculation

  17. Estudio de los fundentes utilizados en la metalurgia del cobre en Cerro Muriano (Córdoba durante el período Romano Altoimperial

    Directory of Open Access Journals (Sweden)

    Criado, A. J.

    1996-10-01

    Full Text Available There are no doubts that Hispania was, under the Roman Empire, the most profitable and abundant in resources of all the mining districts exploded by Rome -Hispania, Galia, Danubian Provinces, Dacia, Greece, Asia Minor, Syria, Egypt and North Africa-. Plinius gives the same data and hands many more in the passages dedicated to the mining and the working of the metals in his Natural History. Of all the many mining places that this author refers, the exploiting in copper at Cerro Muriano presents the main interest; of this he says that it was of an unbeatable quality, used, among other applications, to manufacture the very famous "Copper of Campania". The utilization of fusing agents, adapted to the process of copper obtainment, is fundamental for obtaining this high quality. The addition of these fusing agents was very important for the control of the work parameters and to reach the required temperatures. The high purity of the obtained copper shows a very close knowledge of the phenomena involved in the process.

    Durante el Imperio Romano, de todos los distritos mineros explotados por Roma -Hispania, Galia, las provincias danubianas, Dacia, Grecia, Asia Menor, Siria, Egipto y el Norte de África-, sin duda el más rentable y más abundante en recursos era Hispania. Plinio facilita muchos datos en los pasajes dedicados a la minería y el trabajo de los metales en su Historia Natural. Entre los muchos lugares mineros que este autor cita, nos interesa ahora la explotación de cobre en Cerro Muriano, del cual dice que era de una calidad inmejorable, utilizado, entre otras aplicaciones, para fabricar el famosísimo cobre de Campania. Para poder obtener esta elevada calidad, es fundamental la utilización de fundentes adecuados en el proceso de obtención de cobre. La adición de estos fundentes era vital para controlar los parámetros de trabajo y alcanzar las temperaturas requeridas. La elevada pureza del cobre obtenido demuestra un

  18. A Conceptual Model to Link Anomalously High Temperature Gradients in the Cerros del Rio Volcanic Field to Regional Flow in the Espanola Basin, New Mexico

    Science.gov (United States)

    Fillingham, E. J.; Keller, S. N.; McCullough, K. R.; Watters, J.; Weitering, B.; Wilce, A. M.; Folsom, M.; Kelley, S.; Pellerin, L.

    2015-12-01

    Temperature-depth well data along with electromagnetic (EM) data were collected by students of the Summer of Applied Geophysics Experience (SAGE) 2015 field season in the Espanola Basin, New Mexico. The data from this year, in addition to data acquired since 2013, were used to construct a conceptual east-west cross-section of the Espanola Basin and the adjacent highlands in order to evaluate the regional flow system. Vertical geothermal gradients from several monitoring wells were measured using a thermistor. Anomalously warm geothermal gradients were mapped in the Cerros del Rio volcanic field in the basin just east of the Rio Grande. Temperature gradients are up to 70℃/km, while the background geothermal gradients in the Rio Grande rift zone generally show 28℃-35℃/km. This anomaly extends to the Buckman well field, which supplies water to the city of Santa Fe. Overpumping of this well field has led to subsidence in the past. However, discharge temperature plots indicate that the temperature gradients of the Buckman field may be rebounding as pumping is reduced. Audiomagnetotelluric (AMT) and transient electromagnetic (TEM) data were acquired in the vicinity of three monitoring wells. TEM and AMT methods complement each other with the former having depths of investigation of less than ten to hundreds of meters and AMT having depths of investigation comparable to the wells deeper than 500m. These datasets were used collectively to image the subsurface stratigraphy and, more specifically, the hydrogeology related to shallow aquifers. The EM data collected at these wells showed a trend indicating a shallow aquifer with a shallower resistive layer of approximately 100 ohm-m at 70-100 meters depth. Beneath this resistive layer we resolved a more conductive, clay-rich layer of 10 ohm-m. These resistivity profiles compliment the electrical logs provided by Jet West, which indicate shallower sandstone interbedded with silt on top of more silt-dominant layers. Our

  19. Mecanismo de inserción del Laboratorio Tecnológico del Uruguay en el Parque Tecnológico Industrial del Cerro

    Directory of Open Access Journals (Sweden)

    Laura Márquez

    2011-05-01

    Full Text Available El Laboratorio Tecnológico del Uruguay, LATU, teniendo en cuenta su misión: "Impulsar el desarrollo sustentable del país y su inserción internacional a través de la innovación y transferencia de soluciones de valor, en servicios analíticos, metrológicos, tecnológicos, de gestión y evaluación de la conformidad de a cuerdo a la normativa aplicable", está trabajando en el apoyo a las micro, pequeñas y medianas empresas del país. Como estrategia para contribuir al logro de la misión, se ha iniciado una política de descentralización, eligiendo zonas de actividad con requerimientos similares, en cuanto a las necesidades de mejora de la competitividad de las empresas. En la zona de Montevideo llamada el Cerro, el gobierno municipal gestiona un Parque Tecnológico Industrial, PTIC, apoyando y alojando en su predio, 58 empresas. Este Parque se puede ver como un conglomerado de empresas, en una misma zona, con necesidades similares. El mecanismo de inserción del LATU en el PTIC, ha contado con una herramienta fundamental que es la instalación de una oficina en el propio Parque, cuyo objetivo principal es facilitar y asegurar la contribución del LATU al desarrollo y competitividad de las mipymes allí agrupadas.AbstractAttending to the Technological Laboratory of Uruguay (LATU's mission, to promote the sustainable development of the country and its international insertion through innovation and transfer of valuable solutions, it is working on support for micro, small and medium companies. As a management strategy to achieve the mission, a policy of decentralization, approaching to the enterprises, it's being implemented. In this context, it has been developed a methodology for insertion in the Industrial Technological Park of Cerro, PTIC. This park, which is managed by the municipal government, agglomerates a group of companies, in the same area with similar needs. The LATU's mechanism of insertion in the PTIC, has counted on with a

  20. Sulfur isotopic composition of modern seafloor hydrothermal sediment and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 秦蕴珊; 翟世奎

    2002-01-01

    A total of 1 264 sulfur isotopic values for modem seafloor hydrothermel sediments from different hydrothermal fidds have been collected. On this basis, combining our sulfur isotpic data for surface hydrothermal sediments from the Jade hydrohtermal field in the Okinawa Trough and the TAG hydrothermal field in the Mid-Atlantic Ridge, respectively, and comparing the sulfur isotopic compositions and analyzing their sources of sulfur in seafloor hydrothermal sediments from different geologic-tectonic setting, the results show that: ( 1 ) sulfur isotopic values of sulfides and sulfates in modern seafloor hydrothermal sediments are concentrated in a narrow range, δ34S values of sulfides vary from l × 10-3 to 9 × 10- 3, with a mean of 4.5 × 10- 3 ( n = 1 042), δ34S values of sulfates vary from 19 × 10- 3 to 24× 10-3, with a mean of 21.3× 10-3 (n =217); (2) comparing the sulfur isotopic compositions of hydrothermal sediments from the sediment-hosted hydrothermal fields, the range of sulfur isotopic values for hydrothermal sediments from the sediment-free hydrothermal fields is narrow relatively; (3) the differences of sulfur isotopic compositions in sulfides from different hydrothermal fields show the differences in the sources of sulfur. The sulfur of hydrothermal sulfides in the sediment-free mid-ocean ridges is mainly from mid-ocean ridge basalt, and partially from the reduced seawater sulfate, and it is the result of partially reduced seawater sulfate mixed with basaltic sulfur. In the sediment-hosted nid-ocean ridges and the back-arc basins, the volcanics, the sediments and the organic matters also can offer their sulfur for forming hydrothermal sulfides; (4) the variations of sulfur isotopic compositions and the different sources of sulfur for hydrothermal sediments may be attributed to the various physical-chemical characteristics of hydrothermal fluids, the magmatic evolution and the different geologic-tectonic settings of seafloor hydrothermal systems.

  1. Andesita Cerro Bola: Nueva unidad vinculada al magmatismo mioceno de la Cordillera de Olivares, San Juan, Argentina (30°35´S; 69°30´O Cerro Bola Andesite: New unit linked to the Miocene magmatism of the Olivares Cordillera, San Juan (30°35' S ; 68°30' W

    Directory of Open Access Journals (Sweden)

    A.F. Wetten

    2005-03-01

    Full Text Available El área de estudio se halla en la zona de Tocota, inmediatamente al este de la Cordillera de Olivares, en el borde oriental de la Cordillera Frontal, provincia de San Juan. En ella se encuentran unidades ígneas y sedimentarias del ciclo gondwánico, las que fueron intruidas y cubiertas en relación discordante por cuerpos subvolcánicos y volcánicos asignados anteriormente al ciclo ándico en sentido amplio, los cuales constituyen el principal objeto del presente estudio. Estos cuerpos han sido mapeados a fin de poder caracterizarlos adecuadamente, en el contexto estratigráfico de la región. Los afloramientos de interés han sido reconocidos en el cerro Bola y alrededores, donde se observan distribuidos irregularmente, cubriendo un área superior a 5 km². Las rocas, de coloración gris clara y composición andesítica - fenoandesítica, presentan estructuras de domo y colada. Estos afloramientos serían correlacionables con la unidad volcánica Pircas (Mioceno, la que aflora al oeste, y conformarían un evento magmático posterior al de pórfidos de diferente composición situados tanto en el arroyo Chita como en el cerro Divisadero. La extensión del área involucrada, la uniformidad litológica, el bajo grado de alteración y una edad radimétrica obtenida por el método K/Ar, fueron considerados para proponer a estas volcanitas como una unidad litoestratigráfica de edad miocena superior, con la denominación de Andesita Cerro Bola.The study area is located in the region of Tocota Creek, close to the Cordillera Olivares, eastern border of the Frontal Range, San Juan province. In this place, igneous and sedimentary units belonging to the Gondwanic cycle, were recognized. These units were intruded and unconformably covered by subvolcanic and volcanic bodies, which were commonly referred to the Tertiary or Andean cycle. The study of these bodies is the main proposal of this work. These bodies had been mapped in order to characterize them

  2. Edad y rasgos petrográficos y geoquímicos de cuerpos subvolcánicos asignables a la Formación Cerro León, este del Macizo del Deseado, Santa Cruz Age and petrography and geochemistry features of subvolcanic outcrops from Cerro León Formation, east of the Deseado Massif, Santa Cruz

    Directory of Open Access Journals (Sweden)

    D. Guido

    2004-12-01

    Full Text Available Se presentan nuevos afloramientos de cuerpos subvolcánicos correlacionables con la Formación Cerro León en el sector oriental del Macizo del Deseado. Esta unidad aflora en dos sectores, en el bajo Leonardo y en el afloramiento Bahía Laura del Complejo Río Deseado. El primer sector presenta trece diques y un filón capa intruyendo a las sedimentitas pérmicas de la Formación La Golondrina y el segundo sector comprende tres diques que intruyen a rocas del basamento. Se trata de rocas de color gris a negro, frecuentemente alteradas, con textura microgranuda a porfírica, con fenocristales de plagioclasa, diópsido (En42 Fs11 Wo47 y en menor medida de hornblendas ricas en Mg (magnesio hastingsita, en una matriz holocristalina de textura intergranular. Son rocas subalcalinas de composiciones basalto-andesita y con afinidades calcoalcalinas. La edad Ar/Ar obtenida en una de estas muestras (180,1±1,5 Ma representa la primer determinación realizada en esta unidad y es coherente con las relaciones estratigráficas observadas para esta formación. La comparación con rocas ígneas jurásicas de la provincia geológica Macizo del Deseado, favorece la vinculación temporal y genética con el evento volcánico-piroclástico del Jurásico medio a superior (Formación Bajo Pobre y Grupo Bahía Laura. Sin embargo, la diferencia en las edades Ar/Ar, sugieren una interrupción entre el evento subvolcánico (180 Ma y el volcanismo Jurásico medio a superior (177 a 150 Ma. Se considera, preliminarmente, que los cuerpos subvolcánicos de la Formación Cerro León representarían las primeras evidencias magmáticas del rift jurásico en el Macizo del Deseado.New subvolcanic outcrops, correlated with the Cerro León Formation and located in the eastern Deseado Massif, are presented. This unit outcrops in two sectors, the Leonardo depression and the Bahía Laura outcrop of the Río Deseado Complex. In the first sector there are thirteen dikes and a sill

  3. Zeolite ZSM-12: Hydrothermal synthesis and catalytic properties

    Energy Technology Data Exchange (ETDEWEB)

    Weitkamp, J.; Kumar, R.; Ernst, S.

    1987-02-01

    ZSM-12 was produced by hydrothermal synthesis. To obtain detailed information on the catalytic and type-selective properties of the bi-functional type (Pd/HZSM-12), the hydrocracking of butyl cyclohexane and the isomerisation and hydrocracking of long-chain n-alkanes were investigated as test reactions.

  4. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Science.gov (United States)

    Chown, Steven L

    2012-01-01

    The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  5. A Novel Dual-Stage Hydrothermal Flow Reactor

    DEFF Research Database (Denmark)

    Hellstern, Henrik Christian; Becker, Jacob; Hald, Peter;

    2015-01-01

    The dual-stage reactor is a novel continuous flow reactor with two reactors connected in series. It is designed for hydrothermal flow synthesis of nanocomposites, in which a single particle consists of multiple materials. The secondary material may protect the core nanoparticle from oxidation...

  6. Subcritical hydrothermal conversion of organic wastes and biomass. Reaction pathways

    Directory of Open Access Journals (Sweden)

    Alejandro Amadeus Castro Vega

    2010-04-01

    Full Text Available Hydrothermal conversion is a procedure which emulates organic matter’s natural conversion into bio-crude having physical and chemical properties analogous to petroleum. The artificial transformation of biomass requi- res previous knowledge of the main reaction routes and product availability. The main component of biomass (depolymerisation by hydrolysis is presented in hydrothermal cellulose conversion, producing oligosaccharides which exhibit dehydration and retro-aldol condensation reactions for transforming into furfurals and carboxylic acids. Other biomass components (such as lignin, proteins, and fat esters present both hydrolysis and pyrolysis reaction routes. As long as biomass mainly contains carbohydrates, subcritical hydrothermal conversion products and their wastes will be fundamentally analogous to those displaying cellulose. These substances have added- value by far surpassing raw material’s acquisition cost. When the main hydrothermal conversion products’ O/C, H/C molar ratios as reported in literature are plotted, an evolutionary tralectory for conversion products appears to be closely or even overlapped with fossil fuels’ geological evolution.

  7. Hydrothermal decomposition of liquid crystal in subcritical water

    International Nuclear Information System (INIS)

    Highlights: • Hydrothermal technology can effectively decompose the liquid crystal of 4-octoxy-4'-cyanobiphenyl. • The decomposition rate reached 97.6% under the optimized condition. • Octoxy-4'-cyanobiphenyl was mainly decomposed into simple and innocuous products. • The mechanism analysis reveals the decomposition reaction process. - Abstract: Treatment of liquid crystal has important significance for the environment protection and human health. This study proposed a hydrothermal process to decompose the liquid crystal of 4-octoxy-4′-cyanobiphenyl. Experiments were conducted with a 5.7 mL stainless tube reactor and heated by a salt-bath. Factors affecting the decomposition rate of 4-octoxy-4′-cyanobiphenyl were evaluated with HPLC. The decomposed liquid products were characterized by GC-MS. Under optimized conditions i.e., 0.2 mL H2O2 supply, pH value 6, temperature 275 °C and reaction time 5 min, 97.6% of 4-octoxy-4′-cyanobiphenyl was decomposed into simple and environment-friendly products. Based on the mechanism analysis and products characterization, a possible hydrothermal decomposition pathway was proposed. The results indicate that hydrothermal technology is a promising choice for liquid crystal treatment

  8. Chaotic thermohaline convection in low-porosity hydrothermal systems

    NARCIS (Netherlands)

    Schoofs, Stan; Spera, Frank J.; Hansen, Ulrich

    2001-01-01

    Fluids circulate through the Earth's crust perhaps down to depths as great as 5^15 km, based on oxygen isotope systematics of exhumed metamorphic terrains, geothermal fields, mesozonal batholithic rocks and analysis of obducted ophiolites. Hydrothermal flows are driven by both thermal and chemical b

  9. Where are the undiscovered hydrothermal vents on oceanic spreading ridges?

    Science.gov (United States)

    Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.

    2015-11-01

    In nearly four decades since the discovery of deep-sea vents, one-third of the length of global oceanic spreading ridges has been surveyed for hydrothermal activity. Active submarine vent fields are now known along the boundaries of 46 out of 52 recognized tectonic plates. Hydrothermal survey efforts over the most recent decade were sparked by national and commercial interests in the mineral resource potential of seafloor hydrothermal deposits, as well as by academic research. Here we incorporate recent data for back-arc spreading centers and ultraslow- and slow-spreading mid-ocean ridges (MORs) to revise a linear equation relating the frequency of vent fields along oceanic spreading ridges to spreading rate. We apply this equation globally to predict a total number of vent fields on spreading ridges, which suggests that ~900 vent fields remain to be discovered. Almost half of these undiscovered vent fields (comparable to the total of all vent fields discovered during 35 years of research) are likely to occur at MORs with full spreading rates less than 60 mm/yr. We then apply the equation regionally to predict where these hydrothermal vents may be discovered with respect to plate boundaries and national jurisdiction, with the majority expected to occur outside of states' exclusive economic zones. We hope that these predictions will prove useful to the community in the future, in helping to shape continuing ridge-crest exploration.

  10. Hydrothermal carbonization of tobacco stalk for fuel application.

    Science.gov (United States)

    Cai, Jiaxiao; Li, Bin; Chen, Chaoying; Wang, Jing; Zhao, Min; Zhang, Ke

    2016-11-01

    Tobacco stalks are an abundant biomass resource which are otherwise treated as waste. In this work, the effect of hydrothermal carbonization temperature and time on the structures, chemical compositions and combustion characteristics of hydrochars obtained from tobacco stalks were evaluated. The carbon content, higher heating value, and energy yield increased with accompanying decrease in hydrogen and oxygen contents with the increase of treatment temperature and time. The evolution of the H/C and O/C atomic ratios indicated dehydration and devolatilization processes occurred during hydrothermal carbonization. The weight loss, combustion range and characteristic temperatures of tobacco stalks were significantly modified after hydrothermal carbonization, resulting in higher ignition temperatures and higher energy density. The kinetics model, Coats-Redfern method revealed the activation energy of hydrochars in zone 2 and 3 were among 43.7-74.8kJ/mol and 46.7-85.8kJ/mol, respectively. Our results show that hydrothermal carbonization reaction can facilitate transforming tobacco stalks into energy-rich solid fuel. PMID:27589825

  11. Hydrothermal preparation and crystal habit of X-zeolite powder

    Institute of Scientific and Technical Information of China (English)

    SHEN Shao-hua; ZHANG Shu-gen; WANG Da-wei; FANG Ke-ming

    2005-01-01

    The preparation of X-zeolite powder was investigatedin hydrothermal system, the crystal growth process of X-zeolite in hydrothermal condition was characterized by means of X-ray diffraction, scanning electron microscope and infrared ray. The results show that X-zeolite powder with uniform granularity and intact crystal shape can be obtained in hydrothermal system of acid-treated stellerite-NaOH-NaAl(OH)4-H2O; the crystallite size is in the range of 2 - 3μm. The best reaction time of hydrothermal preparation is 6 h. The formation phases of X-zeolite crystal are as follows: dissolution of feedstocks → formation of [SiO4]4- and [AlO4]5- tetrahedron, many-membered ring,β cage → formation of crystal nucleus and nano-particle → aggregation growth of nano-particle → coalescence growth of crystallite. The crystal habits of X-zeolite are intimately related with crystallization orientation ofβ cage in crystal and with its coupling stability on every crystal face family.

  12. Hydrogen is an energy source for hydrothermal vent symbioses.

    Science.gov (United States)

    Petersen, Jillian M; Zielinski, Frank U; Pape, Thomas; Seifert, Richard; Moraru, Cristina; Amann, Rudolf; Hourdez, Stephane; Girguis, Peter R; Wankel, Scott D; Barbe, Valerie; Pelletier, Eric; Fink, Dennis; Borowski, Christian; Bach, Wolfgang; Dubilier, Nicole

    2011-08-11

    The discovery of deep-sea hydrothermal vents in 1977 revolutionized our understanding of the energy sources that fuel primary productivity on Earth. Hydrothermal vent ecosystems are dominated by animals that live in symbiosis with chemosynthetic bacteria. So far, only two energy sources have been shown to power chemosynthetic symbioses: reduced sulphur compounds and methane. Using metagenome sequencing, single-gene fluorescence in situ hybridization, immunohistochemistry, shipboard incubations and in situ mass spectrometry, we show here that the symbionts of the hydrothermal vent mussel Bathymodiolus from the Mid-Atlantic Ridge use hydrogen to power primary production. In addition, we show that the symbionts of Bathymodiolus mussels from Pacific vents have hupL, the key gene for hydrogen oxidation. Furthermore, the symbionts of other vent animals such as the tubeworm Riftia pachyptila and the shrimp Rimicaris exoculata also have hupL. We propose that the ability to use hydrogen as an energy source is widespread in hydrothermal vent symbioses, particularly at sites where hydrogen is abundant. PMID:21833083

  13. Aluminum speeds up the hydrothermal alteration of olivine

    Science.gov (United States)

    Andreani, Muriel; Daniel, Isabelle; Pollet-Villard, Marion

    2014-05-01

    The reactivity of ultramafic rocks toward hydrothermal fluids controls chemical fluxes at the interface between the internal and external reservoirs of silicate planets. On Earth, hydration of ultramafic rocks is ubiquitous and operates from deep subduction zones to shallow lithospheric environments where it considerably affects the physical and chemical properties of rocks and can interact with the biosphere. This process also has key emerging societal implications, such as the production of hydrogen as a source of carbon-free energy. To date, the chemical model systems used to reproduce olivine hydrothermal alteration lead to the formation of serpentine with sluggish reaction rates. Although aluminum is common in geological environments and in hydrothermal systems in particular, its role in serpentinization or olivine dissolution has not been investigated under hydrothermal conditions. Nevertheless, abundant Al supply is expected in fluids released from dehydration of metapelites in subduction zones as well as during the hydrothermal alteration of gabbros at mid-ocean ridges. Aluminum was also abundant in primitive environments of both the Earth and Mars, stored in either Al-rich minerals like plagioclase or Al-enriched ultramafic lavas. We have investigated the role of Al on the hydrothermal alteration of olivine in a series of experiments performed in a low-pressure diamond anvil cell while following the reaction progress in situ by optical imaging and Raman spectroscopy. Experiments were run for 4.5 to 7.5 days with two olivine grains reacted in saline water (0.5 molal NaCl) at 200°C and 300°C, and P=200 MPa. After two days, olivine crystals were fully transformed to an aluminous serpentine, also enriched in iron. The presence of Al in the hydrothermal fluid increases the rate of olivine serpentinization by more than one order of magnitude by enhancing olivine solubility and serpentine precipitation. The mechanism responsible for this increased solubility

  14. Hydrothermal mixing: Fuel for life in the deep-sea

    Science.gov (United States)

    Hentscher, M.; Bach, W.; Amend, J.; McCollom, T.

    2009-04-01

    Deep-sea hydrothermal vent systems show a wide range of fluid compositions and temperatures. They reach from highly alkaline and reducing, like the Lost City hydrothermal field, to acidic and reducing conditions, (e. g., the Logatchev hydrothermal field) to acidic and oxidizing conditions (e. g., island arc hosted systems). These apparently hostile vent systems are generally accompanied by high microbial activity forming the base of a food-web that often includes higher organisms like mussels, snails, or shrimp. The primary production is boosted by mixing of chemically reduced hydrothermal vent fluids with ambient seawater, which generates redox disequilibria that serve as energy source for chemolithoautotrophic microbial life. We used geochemical reaction path models to compute the affinities of catabolic (energy-harvesting) and anabolic (biosynthesis) reactions along trajectories of batch mixing between vent fluids and 2 °C seawater. Geochemical data of endmember hydrothermal fluids from 12 different vent fields (Lost City, Rainbow, Logatchev, TAG, EPR 21 °N, Manus Basin, Mariana Arc, etc.) were included in this reconnaissance study of the variability in metabolic energetics in global submarine vent systems. The results show a distinction between ultramafic-hosted and basalt-hosted hydrothermal systems. The highest energy yield for chemolithotrophic catabolism in ultramafic-hosted hydrothermal systems is reached at low temperature and under slightly aerobic to aerobic conditions. The dominant reactions, for example at Rainbow or Lost City, are the oxidation of H2, Fe2+ and methane. At temperatures >60 °C, anaerobic metabolic reactions, e. g., sulphate reduction and methanogenesis, become more profitable. In contrast, basalt-hosted systems, such as TAG and 21 °N EPR uniformly indicate H2S oxidation to be the catabolically dominant reaction over the entire microbial-relevant temperature range. Affinities were calculated for the formation of individual cellular

  15. ANÁLISIS DE MACRORRESTOS VEGETALES EN EL SITIO ARQUEOLÓGICO LOS TRES CERROS 1 (ISLA LAS MORAS, VICTORIA, ENTRE RÍOS / Macroremains plant analysis on the Tres Cerros 1 archaeological site (Las Moras island, Victoria, Entre Ríos.

    Directory of Open Access Journals (Sweden)

    María de los Milagros Colobig

    2015-06-01

    Full Text Available El presente trabajo es la primera aproximación al estudio de macrorrestos botánicos en el sitio Los Tres Cerros 1 (isla Las Moras, Victoria, Entre Ríos. Estos restos fueron recuperados mediante la técnica de flotación manual. A partir del material extraído, se exploró el rol de los recursos vegetales y su importancia en la subsistencia en los grupos humanos que habitaron el Delta Superior del río Paraná durante el Holoceno tardío. Se identificaron cinco familias: Solanaceae, Chenopodiaceae, Polygonaceae, Poaceae (Maideae y Oryzoideae y Amaranthaceae. Los estudios permitieron estimar que a partir de 700 ARCP hubo un incremento en la abundancia y variabilidad de recursos vegetales utilizados con respecto a períodos anteriores. La presencia de elementos oryzoides, y graminoides (específicamente Maideae evidenció la existencia de vegetales silvestres y domesticados, aportando nuevos registros sobre el aprovechamiento, manejo y cultivo de las plantas en el área de estudio en el Holoceno tardío.   Abstract  This paper entails the first approach to macrobotanical remains obtained from Los Tres Cerros 1 (Isla Las Moras, Victoria, Entre Ríos. The remains were recovered by means of manual flotation technique. The extracted material allowed us to explore the role played by vegetable resources role and their importance to the subsistence of human populations of Upper Paraná Delta during the late Holocene. Five botanical families were recognized: Solanaceae, Chenopodiaceae, Polygonaceae, Poaceae (Maideae and Ehrhartoideae and Amaranthaceae. Studies estimate that from 700 RCYBP, there was an increase in the abundance and variability of plant resources used, as compared to previous periods. The presence of oryzoides and graminoid elements (specifically Maideae showed the presence of wild and domesticated plants, providing new records on the use of plants in the area studied, in the late Holocene.

  16. El volcanismo bimodal del volcán cerro Corona, Alta Sierra de Somún Curá, provincia de Río Negro Bimodal volcanism of the Cerro Corona volcano in the Alta Sierra de Somún Curá (Río Negro province

    Directory of Open Access Journals (Sweden)

    Guadalupe Maro

    2012-03-01

    Full Text Available La Alta Sierra de Somún Curá es uno de los complejos volcánicos terciarios postplateau en el ambiente de la meseta basáltica de Somún Curá, en la Patagonia extrandina. En ella se encuentra el cerro Corona, un volcán en escudo que corresponde al centro de mayor altura en la región. Está construido por rocas efusivas y piroclásticas subordinadas, fundamentalmente traquiandesíticas-basálticas, con variaciones traquíticas tanto en sus flancos como en su cráter. A pesar de la bimodalidad compositional con una importante discontinuidad entre el 54 y 58 % en peso de SiO2, el presente trabajo propone que las traquitas son el producto de la evolución por cristalización fraccionada de las traquiandesitas basálticas, con cierta influencia de recargas máficas a la cámara magmática de acuerdo a la presencia de texturas de desequilibrio en los fenocristales, principalmente de las rocas félsicas.The Cerro Corona is a shield volcano situated in the Alta Sierra de Somún Curá, one of the tertiary volcanic complex that constitute the Meseta de Somún Curá, in the Extrandean Patagonia. It is the highest center in the region and it is compound mainly of basaltic trachyandesites, with trachytic variations on its flanks and crater. Despite the compositional bimodality with an important compositional gap between 54% and 58% in weight in SiO2, this work suggests that trachytes are the product of the evolution of basaltic trachyandesites through fractional crystallization, with some influence of mafic recharge to the magmatic chamber, in agreement with the presence of disequilibrium textures in fenocrystals, essentially in felsic rocks.

  17. Selenium Isotopes as Biosignatures in Seafloor Hydrothermal Systems

    Science.gov (United States)

    Rouxel, O.; Ludden, J.; Fouquet, Y.

    2001-12-01

    Chemically similar to sulphur, Se occurs as +6, +4, 0 and -2 valences in a variety of organic compounds and geological settings. This makes the study of Se stable isotope ratios a potential indicator of geological and biological processes. Se isotopes were first determined in the early 60's (Krouse and Thode, 1962; Rashid et al., 1978) using gas-source MS and recently by N-TIMS (Herbel et al., 2000; Johnson et al., 1999) using the double spike technique. The previous results showed that the 82Se/76Se ratio vary by as much as 15‰ and indicate that abiotic and bacterial reduction of soluble oxyanions is the dominant cause of Se isotope fractionation. Our isotopic analyses of Se were performed using a continuous flow hydride generation system coupled to a Micromass MC-ICP-MS after chemical purification. The estimated external precision of the 82Se/76Se isotope ratio is 0.25‰ (2σ ) for a quantity of Se per analysis as low as 50 ng and the data are reported relative to our internal standards (MERCK elemental standard solution). In this study we have used Se isotopes in conjunction with S isotopes to provide additional constraints on the fractionation processes in seafloor hydrothermal systems. Several fields were studied along the Mid Atlantic Ridge and include the Lucky Strike field where the setting is in a caldera system with abundant low-permeability layers of cemented breccia which result in fluid cooling and mixing below the hydrothermal vents. Based on vent structures, mineral abundance, and geochemistry, two types of hydrothermal deposits were identified: (1) high-T vents with δ 34S between 1.5 and 4.5‰ and Se values up to 2000 ppm; (2) low-T vents where pyrite and marcasite generally have lower δ 34S values (down to -1.0‰ ) and low concentration of Se (hydrothermal deposits is interpreted as a result of subsurface precipitation of sulfides (scavenging Se from the fluid) during the conductive cooling of the hydrothermal fluid beneath the impermeable

  18. Health assessment for Northwestern States Portland Cement Company, Mason City, Cerro Gordo County, Iowa, Region 7. CERCLIS No. IAD980852461. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-12-27

    The Northwestern States Portland Cement Company (NWSPCC) NPL site is situated in the northern section of Mason City, Cerro Gordo County, Iowa. The major concern at the site is contaminated surface water and ground water as a result of contact with waste cement kiln dust in the West Quarry. On-site surface water and ground water are contaminated with lead, sodium, sulfates, and reflects high pH. The waste kiln dust is in contact with both the surficial and Devonian aquifers on site; hence, there is a potential for contamination of the Devonian aquifer off-site. Potential exposure pathways of concern include ingestion of contaminated ground water; accidental ingestion and dermal contact with contaminated surface water, and accidental ingestion and dermal contact with contaminated soils and sediment; and inhalation of entrained dust. Under current conditions the NWSPCC NPL site poses no apparent public health hazard. However, potential risk to human health resulting from possible exposure to on-site and off-site hazardous substances exists in the future if the site is not remediated. The site is currently under remediation to mitigate the potential risk.

  19. Jurassic tetrapods and flora of Cañadón Asfalto Formation in Cerro Cóndor area, Chubut Province

    Directory of Open Access Journals (Sweden)

    Ignacio H. Escapa

    2008-12-01

    Full Text Available The plant and tetrapod fossil record of the Cañadón Asfalto Formation (Middle to Late Jurassic found in Cerro Cóndor area (Chubut Province is summarized here. The flora is dominated by conifers (Araucariaceae, Cupressaceae sensu lato but also includes ferns and equisetaleans. The tetrapod fauna is composed of dinosaur taxa described in the 70's as well as other remains recently described and other vertebrate groups such as amphibians, turtles, and mammals. The amphibian remains have been interpreted as representatives of a new species of Notobatrachus, considered one of the most basal members of the anuran lineage. Similarly, turtle remains have been recently recognized as a new species of basal turtle, bringing valuable information about the early evolution of this group. The dinosaur remains are largely dominated by saurischian taxa, represented by basal forms of Eusauropoda and Tetanurae. In addition, three different mammalian species have been identified and considered as early representatives of an endemic Gondwanan mammalian fauna. The fossil record of this formation represents the most completely known biota from the continental Middle to Late Jurassic of the Southern Hemisphere and one of the most complete of the entire world.

  20. NUEVOS APORTES AL CONOCIMIENTO DE LA HERPETOFAUNA DE LA FORMACIÓN CERRO AZUL (MIOCENO SUPERIOR, PROVINCIA DE LA PAMPA, ARGENTINA

    Directory of Open Access Journals (Sweden)

    AGUSTÍN SCANFERLA

    2015-01-01

    Full Text Available RESUMENSe describen nuevos materiales fósiles de anfibios y reptiles hallados en sedimentos referidos a la Formación Cerro Azul (Mioceno Superior, procedentes de numerosas localidades de la provincia de La Pampa, Argentina. Los nuevos registros se basan en un resto craneano de anuro asignado al géneroCeratophrys, restos de caparazón de tortugas terrestres del géneroChelonoidis, vértebras asignables al lagarto de la familia TeiidaeTupinambis, y una vértebra troncal de serpiente comparable al género de colubroideos actualesPhilodryas. Tanto los registros terciarios previos de géneros actuales de anfibios y reptiles en América del Sur, como así también la asociación recuperada en el Mioceno Superior de La Pampa sugieren que la mayoría de los géneros que componen la herpetofauna Neotropical estaban presentes en el Mioceno, patrón similar al observado en otras regiones del mundo.

  1. Charnockitic ortho gneisses and mafic granulite s of the Cerro Olivo complex, south-east Uruguay, Part 2: lithogeochemistry, mineral o chemistry and thermo barometry

    International Nuclear Information System (INIS)

    The Cerro Olivo complex in SE-Uruguay shows different kinds of orthogneisses containing biotite, amphibole and/or orthopyroxene-biotite (charnockitic gneisses). Minor occurrences of mafic granulites are associated. They include low and high pressure kinds. We present the lithogeochemistry and compared mineral chemistry analyses of both the charnockitic orthogneisses and the mafic rocks. Theres i a calc-alkaline geochemical affinity of the biotite-bearing and charnockitic gneisses, while the mafic rocks could derive from tholeitic gabbros. These results allow discrininatieg two kinds of mafic rocks: Low and hight MgO contents, both representing respectively garnet-bearing and garnet-free mafic granulites. The orthopyroxene in the Opx-Bt orthogneisses in FE-rich while MgO-rich mafic rocks show hypersthenes. The thermobarometric data of mafic granulites show temperatures higher than 850°C and two contrasting mineral assemblages, one formed by ∼ 1 Kbar and 770° - 800°C (pre-M). and the other by 5.5 Kbar and 680-700° (M). The mineral chemistry suggests the occurrence of contrasting protoliths to explain the stability of two different mineral associations

  2. El volcanismo bimodal del volcán cerro Corona, Alta Sierra de Somún Curá, provincia de Río Negro

    Directory of Open Access Journals (Sweden)

    Guadalupe Maro

    2012-03-01

    Full Text Available La Alta Sierra de Somún Curá es uno de los complejos volcánicos terciarios postplateau en el ambiente de la meseta basáltica de Somún Curá, en la Patagonia extrandina. En ella se encuentra el cerro Corona, un volcán en escudo que corresponde al centro de mayor altura en la región. Está construido por rocas efusivas y piroclásticas subordinadas, fundamentalmente traquiandesíticas-basálticas, con variaciones traquíticas tanto en sus flancos como en su cráter. A pesar de la bimodalidad compositional con una importante discontinuidad entre el 54 y 58 % en peso de SiO2, el presente trabajo propone que las traquitas son el producto de la evolución por cristalización fraccionada de las traquiandesitas basálticas, con cierta influencia de recargas máficas a la cámara magmática de acuerdo a la presencia de texturas de desequilibrio en los fenocristales, principalmente de las rocas félsicas.

  3. Sulfur isotopic composition of seafloor hydrothermal sediment from the Jade hydrothermal field in the central Okinawa Trough and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 翟世奎; 秦蕴珊; 侯增谦

    2002-01-01

    --Eighteen samples of hydrothermal sediments from the Jade hydrotherrnal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2 ×10-3to 7.2× 10-3, δ34S valUes for 7 sulfate samples vary from 16.3 × 10-3 to 22.3 × 10-3, and 1 native sulphur sample has a δ34S value of 8.2 × 10-3. The major sources of sulfur for hydrothermal sediment are intermediate to acid volcanic rocks and sea water sulfate, and it is possible that the partial sulfur of hydrothermal sediment is from the pelagic sediment by the interaction between hydrothermal fluid and sediment. The reasons of causing the distinct differences in sulfur isotopic values for sulfide samples from hydrothermal sediment ( compared with other hydrothermal fields), are the differences in the sources of sulfur, the magmatic activity and the tectonic evolution in different hydrothermal fields. The sulfur evolution is a long and complex process in the seafloor hydrothermal system, involving the ascending of heating sea water, the interaction between fluid and volcanic rocks, the mixing of sea water sulfate and sulfur from intermediate to acid volcanic rocks, and the fluid/pelagic-sediment interaction. And the interaction between sea water and intermediate to acid volcanic rocks is an important mechanism for the sulfur evolution in the Jade hydrothermal field.

  4. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity

    International Nuclear Information System (INIS)

    The surface wettability of implants is a crucial factor in their osteoconductivity because it influences the adsorption of cell-attached proteins onto the surface. In this study, a single-step hydrothermal surface treatment using distilled water at a temperature of 180 °C for 3 h was applied to titanium (Ti) and its alloys (Ti–6Al–4V, Ti–6Al–7Nb, Ti–29Nb–13Ta–4.6Zr, Ti–13Cr–1Fe–3Al; mass%) and compared with as-polished Ti implants and with implants produced by anodizing Ti in 0.1 M of H3PO4 with applied voltages from 0 V to 150 V at a scanning rate of 0.1 V s−1. The surface-treated samples were stored in a five time phosphate buffered saline (× 5 PBS(−)) solution to prevent increasing the water contact angle (WCA) with time. The surface characteristics were evaluated using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Auger electron spectroscopy, surface roughness, and contact angle measurement using a 2 μL droplet of distilled water. The relationship between WCA and osteoconductivity at various surface modifications was examined using in vivo tests. The results showed that a superhydrophilic surface with a WCA ≤ 10° and a high osteoconductivity (RB–I) of up to 50% in the cortical bone part, about four times higher than the as-polished Ti and Ti alloys, were provided by the combination of the hydrothermal surface treatment and storage in × 5 of PBS(−). - Highlights: • Hydrothermal treatment in distilled water was applied to titanium alloys. • Surface characteristics and osteoconductivity by in vivo test were evaluated. • Water contact angles of titanium alloys were decreased by hydrothermal treatment. • Osteoconductivity of titanium alloys improved notably by hydrothermal treatment after stored in × 5 of PBS (−)

  5. Energetics of Amino Acid Synthesis in Alkaline Hydrothermal Environments

    Science.gov (United States)

    Kitadai, Norio

    2015-12-01

    Alkaline hydrothermal systems have received considerable attention as candidates for the origin and evolution of life on the primitive Earth. Nevertheless, sufficient information has not yet been obtained for the thermodynamic properties of amino acids, which are necessary components for life, at high temperatures and alkaline pH. These properties were estimated using experimental high-temperature volume and heat capacity data reported in the literature for several amino acids, together with correlation algorithms and the revised Helgeson-Kirkham-Flowers (HKF) equations of state. This approach enabled determination of a complete set of the standard molal thermodynamic data and the revised HKF parameters for the 20 protein amino acids in their zwitterionic and ionization states. The obtained dataset was then used to evaluate the energetics of amino acid syntheses from simple inorganic precursors (CO2, H2, NH3 and H2S) in a simulated alkaline hydrothermal system on the Hadean Earth. Results show that mixing between CO2-rich seawater and the H2-rich hydrothermal fluid can produce energetically favorable conditions for amino acid syntheses, particularly in the lower-temperature region of such systems. Together with data related to the pH and temperature dependences of the energetics of amino acid polymerizations presented in earlier reports, these results suggest the following. Hadean alkaline hydrothermal settings, where steep pH and temperature gradients may have existed between cool, slightly acidic Hadean ocean water and hot, alkaline hydrothermal fluids at the vent-ocean interface, may be energetically the most suitable environment for the synthesis and polymerization of amino acids.

  6. Catalytic Diversity in Alkaline Hydrothermal Vent Systems on Ocean Worlds

    Science.gov (United States)

    Cameron, Ryan D.; Barge, Laura; Chin, Keith B.; Doloboff, Ivria J.; Flores, Erika; Hammer, Arden C.; Sobron, Pablo; Russell, Michael J.; Kanik, Isik

    2016-10-01

    Hydrothermal systems formed by serpentinization can create moderate-temperature, alkaline systems and it is possible that this type of vent could exist on icy worlds such as Europa which have water-rock interfaces. It has been proposed that some prebiotic chemistry responsible for the emergence of life on Earth and possibly other wet and icy worlds could occur as a result ofredox potential and pH gradients in submarine alkaline hydrothermal vents (Russell et al., 2014). Hydrothermal chimneys formed in laboratory simulations of alkaline vents under early Earth conditions have precipitate membranes that contain minerals such as iron sulfides, which are hypothesized to catalyze reduction of CO2 (Yamaguchi et al. 2014, Roldan et al. 2014) leading to further organic synthesis. This CO2 reduction process may be affected by other trace components in the chimney, e.g. nickel or organic molecules. We have conducted experiments to investigate catalytic properties of iron and iron-nickel sulfides containing organic dopants in slightly acidic ocean simulants relevant to early Earth or possibly ocean worlds. We find that the electrochemical properties of the chimney as well as the morphology/chemistry of the precipitate are affected by the concentration and type of organics present. These results imply that synthesis of organics in water-rock systems on ocean worlds may lead to hydrothermal precipitates which can incorporate these organic into the mineral matrix and may affect the role of gradients in alkaline vent systems.Therefore, further understanding on the electroactive roles of various organic species within hydrothermal chimneys will have important implications for habitability as well as prebiotic chemistry. This work is funded by NASA Astrobiology Institute JPL Icy Worlds Team and a NAI Director's Discretionary Fund award.Yamaguchi A. et al. (2014) Electrochimica Acta, 141, 311–318.Russell, M. J. et al. (2014), Astrobiology, 14, 308-43.Roldan, A. (2014) Chem. Comm

  7. Petrology and Geochemistry of Hydrothermally Altered Volcanic Rocks in the Iheya North Hydrothermal Field, Middle Okinawa Trough

    Science.gov (United States)

    Yamasaki, T.

    2015-12-01

    The Iheya North hydrothermal field is located in the middle Okinawa Trough, a young and actively spreading back-arc basin extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. In this hydrothermal field, two scientific drilling expeditions (IODP Exp 331 and SIP CK14-04) were conducted using a deep-sea drilling vessel "Chikyu," and samples from a total of 27 holes were taken. Through these expeditions, Kuroko-type volcanogenic massive sulfide deposits (VMS), hydrothermally altered volcanic rocks, and pumiceous and pelagic sediments were recovered. The recovered core provided important information about the relationship between hydrothermal activity, alteration, and ore mineralization. Whole-rock major element composition and trace element (TE) patterns of pumices were very similar to those of rhyolites in the middle Okinawa Trough (RMO). However, pumices were relatively enriched in chalcophile elements Sr and Nb, which suggest incipient mineralization. Volcanic rock generally demonstrated strong silicification and was greenish pale gray in color. Regardless of severe alteration, some rock displayed major element composition broadly similar to the RMO. Alteration was evidenced by an increase in the content of SiO2 and MgO, and decrease in Al2O3, Na2O, and K2O content. The most striking geochemical feature of altered volcanic rock was the discordance between texture and the degree of modification of TEs. Some samples showed decussate texture occupied by petal-like quartz with severe silicification, but no prominent disturbance of concentration and patterns of TEs were observed. In contrast, samples with well-preserved igneous porphyritic texture showed very low TE content and modification of TE patterns. These results suggest that the modification of texture and composition of TEs, as well as silicification, do not occur by a uniform process, but several processes. This may reflect the differences in temperature and the

  8. Application of Hydrothermal and Non-Hydrothermal TiO2 Nanoporous Materials as New Adsorbents for Removal of Heavy Metal Ions from Aqueous System

    Directory of Open Access Journals (Sweden)

    Mansoor Anbia

    2016-06-01

    Full Text Available Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD, scanning electron microscopy (SEM and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong pore size distribution peaks with average of 37.8 Å and pore volume of 0.41 cm3/g and the (Brunauer–Emmett–TellerBET specific surface area of 365 m2/g. Hydrothermal and non-hydrothermal spherical TiO2 nanoporous have been used as adsorbent to study of the adsorption behavior of Pb(II, Co(II and Ni(II ions from aqueous system in a batch system. Effect of equilibrium time on adsorption Pb(II, Co(II and Ni(II ions on these adsorbent was studied The results show that the shaking time 0.5 to 10h has no serious effect on the percentage of ions removal, and the adsorption is fast in all cases. The maximum uptake capacities of Hydrothermal and non-hydrothermal spherical TiO2 nanoporous was calculated. Both hydrothermal and non-hydrothermal TiO2 nanoporous materials were found to have very good potential as new adsorbents in removal of these ions. In batch systems the maximum uptake capacities of Pb(II, Ni(II and Co(II on the hydrothermal and non-hydrothermal TiO2 nanoporous materials was Co(II > Pb(II > Ni(II and Co(II > Ni(II > Pb(II, respectively.

  9. Hydrothermal vents is Lake Tanganyika, East African Rift system

    Energy Technology Data Exchange (ETDEWEB)

    Tiercelin, J.J. [Universite de Bretagne Occidentale, Brest (France); Pflumio, C.; Castrec, M. [Universite Paris VI, Paris (France)] [and others

    1993-06-01

    Sublacustrine hydrothermal vents with associated massive sulfides were discovered during April 1987 at Pemba and Cape Banza on the Zaire side of the northern basin of Lake Tanganyika, East African Rift system. New investigations by a team of ten scuba divers during the multinational (France, Zaire, Germany, and Burundi) TANGANYDRO expedition (August-October 1991) found hydrothermal vents down to a depth of 46 m along north-trending active faults bounding the Tanganyika rift on the western side. Temperatures from 53 to 103 {degrees}C were measured in hydrothermal fluids and sediments. Veins of massive sulfides 1-10 cm thick (pyrite and marcasite banding) were found associated with vents at the Pemba site. At Cape Banza, active vents are characterized by 1-70-cm-high aragonite chimneys, and there are microcrystalline pyrite coatings on the walls of hydrothermal pipes. Hydrothermal fluid end members show distinctive compositions at the two sites. The Pemba end member is a NaHCO{sub 3}-enriched fluid similar to the NaHCO{sub 3} thermal fluids form lakes Magadi and Bogoria in the eastern branch of the rift. The Cape Banza end member is a solution enriched in NaCl. Such brines may have a deep-seated basement origin, as do the Uvinza NaCl brines on the eastern flank of the Tanganyika basin. Geothermometric calculations have yielded temperatures of fluid-rock interaction of 219 and 179 {degrees}C in the Pemba and Cape Banza systems, respectively. Abundant white or reddish-brown microbial colonies resembling Beggiatoa mats were found surrounding the active vents. Thermal fluid circulation is permitted by opening of cracks related to 130{degrees}N normal-dextral faults that intersect the north-south major rift trend. The sources of heat for such hydrothermal systems may relate to the existence of magmatic bodies under the rift, which is suggested by the isotopic composition of carbon dioxide released at Pemba and Cape Banza. 21 refs., 2 figs.

  10. Hydrothermal plumes in the NE Lau basin: A regional perspective

    Science.gov (United States)

    Walker, S. L.; Baker, E. T.

    2013-12-01

    Exploration for mineral resources and the presence of an extensive plume of excess 3He centered at 1750 m water depth in the Samoa-Tonga-Fiji region (Lupton, 2004) have motivated exploration for active hydrothermal vent sites in the NE Lau basin during the past decade. The region is tectonically complex with back-arc spreading centers, rift zones, and volcanic centers, all of which potentially host active venting and/or active volcanism. To date, 400 km of the three back-arc spreading centers in the NE Lau basin (FRSC, Fonualei Rift and Spreading Center; MTJ, Mangatolu Triple Junction; and NELSC, Northeastern Lau Spreading Center) plus several volcanic centers have been systematically surveyed for hydrothermal plumes using towed CTD or MAPR arrays that include both optical backscatter and oxidation-reduction potential (ORP) sensors. The FRSC, where spreading rates range from 47 mm/a in the south to 85 mm/a in the north, has 5 active sites (plume depths ranging from 1300-2200 m) distributed one every ~40 km over its 200 km length. There is evidence for 4 active sites (plume depths range from 1950-2380 m) along the 150 km combined length of the MTJ segments, however plumes were optically weak (dNTU ORP anomalies were detected. Plumes were observed off-axis to the MTJ at a bathymetric high adjacent to the northeastern limb (1700 m) as well as over the summit of a cratered volcanic edifice east of the central junction (1200-1300 m). The southern segment of the NELSC was the site of an active eruption in 2008 which injected event plumes throughout the water column (900-1600 m depth range) in addition to the chronic plume from the Maka massive sulfide vent site (1500 m). There is evidence for at least two additional active areas along the northern segments of the NELSC (1800-1900 m). Several volcanoes in the region are hydrothermally active ranging from the northernmost volcano on the Tonga arc (Niua) with plumes centered at 600-1000 m, to the series of North Mata

  11. Elemental geochemical records of seafloor hydrothermal activities in the sediments from the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; YU Zenghui; DU Tongjun

    2007-01-01

    The major and minor element contents in the sediment core H9 from the hydrothermal fields of the Okinawa Trough show a sharp change at the depth of 80 cm. The elements enriched in the upper 80 cm core are those enriched in the hydrothermal deposits and in the surface sediments recovered from the hydrothermal fields in the trough, which indicates the input of hydrothermal materials. Comparing with other hydrothermal sediments from Mid-ocean Ridges or the Lau Basin, the degree of the enrichment of elements iron, copper, cobalt, and nickel is relatively low. However, the enrichment of elements manganese, lead, arsenic, antimony and mercury is remarkable. The average contents of these elements in the upper 80 cm core sediments are three to six times those in the lower section, and 3 ~ 12 times those in the surface sediments which are not influenced by hydrothermal activities. Hydrothermal activities have contributed significant manganese, lead, arsenic, antimony and mercury to the sediments, and these elements are distinct indicators for the hydrothermal activity in the Okinawa Trough. The significant enrichment of these elements in Core H9 upward from the depth 80 cm indicates the start or the significant enhancing of the hydrothermal activity in this area at about 5 740 aB. P. The average accumulation rate of manganese during this period is about 40 461 μg/( cm2 · ka), which is similar to the hydrothermal sediments in the Lau Basin or the East Pacific Rise.

  12. Hydrothermal Habitats: Measurements of Bulk Microbial Elemental Composition, and Models of Hydrothermal Influences on the Evolution of Dwarf Planets

    Science.gov (United States)

    Neveu, Marc Francois Laurent

    Finding habitable worlds is a key driver of solar system exploration. Many solar system missions seek environments providing liquid water, energy, and nutrients, the three ingredients necessary to sustain life. Such environments include hydrothermal systems, spatially-confined systems where hot aqueous fluid circulates through rock by convection. I sought to characterize hydrothermal microbial communities, collected in hot spring sediments and mats at Yellowstone National Park, USA, by measuring their bulk elemental composition. To do so, one must minimize the contribution of non-biological material to the samples analyzed. I demonstrate that this can be achieved using a separation method that takes advantage of the density contrast between cells and sediment and preserves cellular elemental contents. Using this method, I show that in spite of the tremendous physical, chemical, and taxonomic diversity of Yellowstone hot springs, the composition of microorganisms there is surprisingly ordinary. This suggests the existence of a stoichiometric envelope common to all life as we know it. Thus, future planetary investigations could use elemental fingerprints to assess the astrobiological potential of hydrothermal settings beyond Earth. Indeed, hydrothermal activity may be widespread in the solar system. Most solar system worlds larger than 200 km in radius are dwarf planets, likely composed of an icy, cometary mantle surrounding a rocky, chondritic core. I enhance a dwarf planet evolution code, including the effects of core fracturing and hydrothermal circulation, to demonstrate that dwarf planets likely have undergone extensive water-rock interaction. This supports observations of aqueous products on their surfaces. I simulate the alteration of chondritic rock by pure water or cometary fluid to show that aqueous alteration feeds back on geophysical evolution: it modifies the fluid antifreeze content, affecting its persistence over geological timescales; and the

  13. Tectonic and Hydrothermal Activities in Debagh, Guelma Basin (Algeria

    Directory of Open Access Journals (Sweden)

    Said Maouche

    2013-01-01

    Full Text Available Quaternary and Pliocene travertines, deposited from hot springs, can reveal much about neotectonic and hydrothermal activity. The aim of this work is the understanding of the actual tectonic activity in the Guelma Basin and in one of its spa structures. Gravity data were collected during a field study in the Hammam Debagh (HD area and then analyzed to better highlight the architecture of its subsurface underlying structures. This analysis was performed by means of a Bouguer anomaly, upward continuations, and residual and derivative maps. Comparison of gravity maps, field geology, geomorphic observations, and structural maps allowed us to identify the major structural features in the Hammam Debagh. As a result, we confirm the position of the Hammam Debagh active fault which is superimposed to the hydrothermal active source in the NW-SE direction characterized by a negative gravity anomaly.

  14. Hydrothermal synthesis and physicochemical properties of ruthenium(0) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Dikhtiarenko, A., E-mail: dikhtiarenkoalla@uniovi.es [Departamento de Quimica Organica e Inorganica, Universidad de Oviedo - CINN, 33006 Oviedo (Spain); Khainakov, S.A.; Garcia, J.R.; Gimeno, J. [Departamento de Quimica Organica e Inorganica, Universidad de Oviedo - CINN, 33006 Oviedo (Spain); Pedro, I. de; Fernandez, J. Rodriguez [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, 39005 Santander (Spain); Blanco, J.A. [Departamento de Fisica, Universidad de Oviedo, 33007 Oviedo (Spain)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer Ruthenium nanoparticles were synthesized by hydrothermal technique. Black-Right-Pointing-Pointer The average size of the nanoparticles are depend on the reducing agent used. Black-Right-Pointing-Pointer The magnetic response seems to be dominated by a paramagnetic contribution characteristic of the band electronic magnetism of the ruthenium(0) nanoparticles. - Abstract: The synthesis of ruthenium nanoparticles in hydrothermal conditions using mild reducing agents (succinic acid, ascorbic acid and sodium citrate) is reported. The shape of the nanoparticles depends on the type of the reducing agent, while the size is more influenced by the pH of the medium. The magnetic response seems to be dominated by a paramagnetic contribution characteristic of the band electronic magnetism of the nanoparticles.

  15. Artificial Bee Colony Optimization for Short-Term Hydrothermal Scheduling

    Science.gov (United States)

    Basu, M.

    2014-12-01

    Artificial bee colony optimization is applied to determine the optimal hourly schedule of power generation in a hydrothermal system. Artificial bee colony optimization is a swarm-based algorithm inspired by the food foraging behavior of honey bees. The algorithm is tested on a multi-reservoir cascaded hydroelectric system having prohibited operating zones and thermal units with valve point loading. The ramp-rate limits of thermal generators are taken into consideration. The transmission losses are also accounted for through the use of loss coefficients. The algorithm is tested on two hydrothermal multi-reservoir cascaded hydroelectric test systems. The results of the proposed approach are compared with those of differential evolution, evolutionary programming and particle swarm optimization. From numerical results, it is found that the proposed artificial bee colony optimization based approach is able to provide better solution.

  16. Fabrication Of Titania Nanotubes By A Modified Hydrothermal Method

    Directory of Open Access Journals (Sweden)

    Meor Yusoff M.S

    2011-09-01

    Full Text Available The main setback of the fabrication of titania nanotubes by the hydrothermal method is the long dissolution time and the usage of highly concentrated NaOH. Our group has managed to develop a modified hydrothermal process that is capable of fabricating titania nanotubes in a shorter timespan while using a more dilute NaOH solution. The study shows that the titania nanotubes starts to form from 7 hours of dissolution, and more nanotubes is produced as the dissolution duration is extended. Similarly, we are able to produce titania nanotubes from a more dilute NaOH solution than those reported earlier. By varying the parameters of the fabrication process, different nanostructures can be obtained such as single, branched nanowires and nanobelts.

  17. Stable Isotopic Composition for Hydrothermal Vein Deposits, Southeastern Korea

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@The southeast of Korea has attracted considerable attention in the geologic community because of its extensive igneous activity and associated mineralizations from the Late Cretaceous to the Early Tertiary (Cu, Pb-Zn, W-Mo, Bi and Au-Ag hydrothermal-vein deposits, porphyry, skarn and altered clay deposits). The southeast of Korea is composed of Cretaceous sedimentary Gyeongsan basin, volcanic and plutonic rocks. Most of the mines are either closed or incapable of producing more ores because of their poor reserves. The south of the Gyeongsang basin is famous for its hydrothermal altered clay deposits associated with volcanism. In order to locate more metal resources, many researches have been conducted into the gold-silver mineralization within hydrothermai-altered deposits in the past several years. The age of plutonism ranges from 112 Ma to 44 Ma, and that of volcanism from 74 Ma to 47 Ma.

  18. Naked in toxic fluids: A nudibranch mollusc from hydrothermal vents

    Science.gov (United States)

    Valdés, Ángel; Bouchet, Philippe

    1998-01-01

    A new species of the nudibranch genus Dendronotus (Mollusca, Opisthobranchia) is reported from a hydrothermal vent at the Lucky Strike area, on the Mid-Atlantic Ridge. This is the first species of nudibranch recorded with certainty from a vent site. Other species of Dendronotus are distributed in temperate waters on the continental shelf of the northern hemisphere. Two factors that probably account for the occurrence of a nudibranch in this hydrothermal field are that the Lucky Strike area presents potential hydroid prey, and that nudibranchs apparently inhabit a lower activity area. It is hypothesized that the new species, which lacks eyes, is a permanent resident of vent fields on the Mid-Atlantic Ridge, but is probably not restricted to that environment.

  19. Flow and permeability structure of the Beowawe, Nevada hydrothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Faulder, D.D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Johnson, S.D.; Benoit, W.R. [Oxbow Power Services, Inc., Reno, NV (United States)

    1997-05-01

    A review of past geologic, geochemical, hydrological, pressure transient, and reservoir engineering studies of Beowawe suggests a different picture of the reservoir than previously presented. The Beowawe hydrothermal contains buoyant thermal fluid dynamically balanced with overlying cold water, as shown by repeated temperature surveys and well test results. Thermal fluid upwells from the west of the currently developed reservoir at the intersection of the Malpais Fault and an older structural feature associated with mid-Miocene rifting. A tongue of thermal fluid rises to the east up the high permeability Malpais Fault, discharges at the Geysers area, and is in intimate contact with overlying cooler water. The permeability structure is closely related to the structural setting, with the permeability of the shallow hydrothermal system ranging from 500 to 1,000 D-ft, while the deeper system ranges from 200 to 400 D-ft.

  20. Controlled growth of silver nanoparticles in a hydrothermal process

    Institute of Scientific and Technical Information of China (English)

    Juan Zou; Yao Xu; Bo Hou; Dong Wu; Yuhan Sun

    2007-01-01

    A two-step synthesis was used to control the shape of silver nanoparticles. First, a few spherical silver nanoparticles, ~10 nm in size, were prepared via reduction of Ag+ ions in aqueous Ag(NH3)2NO3 by poly(N-vinyl-2-pyrrolidone) (PVP). Then, in a subsequent hydrothermal treatment,the remaining Ag+ ions were reduced by PVP into polyhedral nanoparticles, or larger spherical nanoparticles formed from the small spherical seed silver nanoparticles in the first step. The morphology and size of the resultant particles depend on the hydrothermal temperature, PVP/Ag molar ratio and concentration of Ag+ ions. By using UV-visible spectroscopy (UV-vis), transmission electron microscopy (TEM) and powder X-ray diffraction (XRD), the possible growth mechanism of the silver nanoparticles was discussed.

  1. The formation of titania polymorphs under hydrothermal condition

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHI; Erwei(施尔畏); LI; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HU; Xingfang(胡行方)

    2002-01-01

    The formation process of crystal polymorphs of titania under hydrothermal condition is studied.According to the experimental results and theoretic analysis,the formation process of crystal polymorphs can be described as a unit process.It includes the formation of growth units,the formation of nuclei through the polymerization of growth unit,and the growth of crystallites.The influence of the environmental phase and growth conditions on the formation of polymorphs is reflected in the changes of the structures of growth units.For example,when changing the pH of the reaction medium,the structure of growth unit with the highest stable energy in the hydrothermal system changes.Then different titania polymorphs can be prepared.The absorption,movement,crystallization or desorption of the growth unit are related to crystalline structure.On the other hand,the formation of crystal inner defects is related to the disturbance of the crystallizing process.``

  2. Understanding hydrothermal carbonization of mixed feedstocks for waste conversion

    Science.gov (United States)

    Lu, Xiaowei

    Hydrothermal carbonization (HTC) is an environmentally beneficial means to convert waste materials to value-added solid and liquid products with minimal greenhouse gas emission. Research is lacking on understanding the influence of critical process conditions on product formation and environmental implication associated with HTC of waste streams. This work was conducted to determine how reaction conditions and heterogeneous compound mixtures (representative of municipal wastes) influence hydrothermal carbonization processes. The specific experiments include: (1) determine how carbonization product properties are manipulated by controlling feedstock composition, process conditions, and catalyst addition; (2) determine if carbonization of heterogeneous mixtures follows similar pathways as that with pure feedstocks; and (3) evaluate and compare the carbon and energy-related implications associated with carbonization products with those associated with other common waste management processes for solid waste.

  3. Piezoelectric Materials Synthesized by the Hydrothermal Method and Their Applications

    Directory of Open Access Journals (Sweden)

    Takeshi Morita

    2010-12-01

    Full Text Available Synthesis by the hydrothermal method has various advantages, including low reaction temperature, three-dimensional substrate availability, and automatic polarization alignment during the process. In this review, powder synthesis, the fabrication of piezoelectric thin films, and their applications are introduced. A polycrystalline lead zirconate titanate (PZT thin film was applied to a micro ultrasonic motor, and an epitaxial lead titanate (PbTiO3 thin film was estimated as a ferroelectric data storage medium. Ferroelectric and piezoelectric properties were successfully obtained for epitaxial PbTiO3 films. As lead-free piezoelectric powders, KNbO3 and NaNbO3 powders were synthesized by the hydrothermal method and sintered together to form (K,NaNbO3 ceramics, from which reasonable piezoelectric performance was achieved.

  4. Sustainability and dynamics of outcrop-to-outcrop hydrothermal circulation

    Science.gov (United States)

    Winslow, Dustin M.; Fisher, Andrew T.

    2015-06-01

    Most seafloor hydrothermal circulation occurs far from the magmatic influence of mid-ocean ridges, driving large flows of water, heat and solutes through volcanic rock outcrops on ridge flanks. Here we create three-dimensional simulations of ridge-flank hydrothermal circulation, flowing between and through seamounts, to determine what controls hydrogeological sustainability, flow rate and preferred flow direction in these systems. We find that sustaining flow between outcrops that penetrate less-permeable sediment depends on a contrast in transmittance (the product of outcrop permeability and the area of outcrop exposure) between recharging and discharging sites, with discharge favoured through less-transmissive outcrops. Many simulations include local discharge through outcrops at the recharge end of an outcrop-to-outcrop system. Both of these characteristics are observed in the field. In addition, smaller discharging outcrops sustain higher flow rates than larger outcrops, which may help to explain how so much lithospheric heat is extracted globally by this process.

  5. Isotopic study of some fossil and actual hydrothermal systems

    International Nuclear Information System (INIS)

    Oxygen and hydrogen isotopic compositions of rocks from the INAG no 1 drillhole provide evidence of a fossil hydrothermal system in the Ceyssat region of the Massif Central. Oxygen isotope temperatures for the mineral paragenesis are about 2750C and the water is of marine origin. Measurements have also been made of delta13C values of dissolved carbon and gaseous CO2 from several hot springs in the Pyrenees and Massif Central. The carbon isotopic composition of the total systems have been calculated from the gas-liquid ratios at the emergence sites and these results are discussed in terms of the origin of the carbon. Most of the hydrothermal carbon is of deep origin. The observed variations in isotopic compositions may be explained by the behavior of the fluids during their ascent to the surface

  6. Formic acid production from carbohydrates biomass by hydrothermal reaction

    International Nuclear Information System (INIS)

    The formation of formic acid or formate salts by hydrothermal oxidation of model biomass materials (glucose, starch and cellulose) was investigated. All experiments were conducted in a batch reactor, made of SUS 316 tubing, providing an internal volume of 5.7 cm3. A 30 wt% hydrogen peroxide aqueous solution was used as an oxidant. The experiments were carried out with temperature of 2500C, reaction time varying from 0.5 min to 5 min, H2O2 supply of 240%, and alkaline concentration varying from 0 to 1.25 M. Similar to glucose, in the cases of the oxidation of hydrothermal starch and cellulose, the addition of alkaline can also improve the yield of formic acid. And the yield were glucose>starch> cellulose in cases of with or without of alkaline addition.

  7. Colorado's hydrothermal resource base: an assessment

    Energy Technology Data Exchange (ETDEWEB)

    Pearl, R.H.

    1981-01-01

    As part of its effort to more accurately describe the nations geothrmal resource potential, the US Department of Energy/Division of Geothermal Energy contracted with the Colorado Geological survey to appraise the hydrothermal (hot water) geothermal resources of Colorado. Part of this effort required that the amount of energy that could possibly be contained in the various hydrothermal systems in Colorado be estimated. The findings of that assessment are presented. To make these estimates the geothermometer reservoir temperatures estimated by Barrett and Pearl (1978) were used. In addition, the possible reservoir size and extent were estimated and used. This assessment shows that the total energy content of the thermal systems in Colorado could range from 4.872 x 10{sup 15} BTU's to 13.2386 x 10{sup 15} BTU's.

  8. Thermodynamic analysis of hydrogen production via hydrothermal gasification of hexadecane

    KAUST Repository

    Alshammari, Yousef M.

    2012-04-01

    This work reports the equilibrium behaviour of the hydrothermal gasification of hexadecane, a heavy saturate model compound, under non-oxidative isothermal and oxidative adiabatic conditions, using the Peng-Robinson equation of state and the direct minimisation of Gibbs free energy employed within the Aspen HYSYS. This modelling enabled establishing both the limits and optimum conditions at which the hydrogen molar yield may be theoretically maximised. The effects of parameters including the reactor isothermal temperature, pressure, water to carbon ratio, and oxygen to carbon ratio on the molar yields of produced gaseous species were analysed. The model has been validated by comparing its results with different reported modelling and experimental data under identical conditions which resulted in a good agreement. The results reported in this work show the potential of achieving economic yields of hydrogen and syngas from liquid hydrocarbons under downhole hydrothermal conditions. © 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights.

  9. Ecological Impacts of the Cerro Grande Fire: Predicting Elk Movement and Distribution Patterns in Response to Vegetative Recovery through Simulation Modeling October 2005

    Energy Technology Data Exchange (ETDEWEB)

    Rupp, Susan P. [Texas Tech Univ., Lubbock, TX (United States)

    2005-10-01

    In May 2000, the Cerro Grande Fire burned approximately 17,200 ha in north-central New Mexico as the result of an escaped prescribed burn initiated by Bandelier National Monument. The interaction of large-scale fires, vegetation, and elk is an important management issue, but few studies have addressed the ecological implications of vegetative succession and landscape heterogeneity on ungulate populations following large-scale disturbance events. Primary objectives of this research were to identify elk movement pathways on local and landscape scales, to determine environmental factors that influence elk movement, and to evaluate movement and distribution patterns in relation to spatial and temporal aspects of the Cerro Grande Fire. Data collection and assimilation reflect the collaborative efforts of National Park Service, U.S. Forest Service, and Department of Energy (Los Alamos National Laboratory) personnel. Geographic positioning system (GPS) collars were used to track 54 elk over a period of 3+ years and locational data were incorporated into a multi-layered geographic information system (GIS) for analysis. Preliminary tests of GPS collar accuracy indicated a strong effect of 2D fixes on position acquisition rates (PARs) depending on time of day and season of year. Slope, aspect, elevation, and land cover type affected dilution of precision (DOP) values for both 2D and 3D fixes, although significant relationships varied from positive to negative making it difficult to delineate the mechanism behind significant responses. Two-dimensional fixes accounted for 34% of all successfully acquired locations and may affect results in which those data were used. Overall position acquisition rate was 93.3% and mean DOP values were consistently in the range of 4.0 to 6.0 leading to the conclusion collar accuracy was acceptable for modeling purposes. SAVANNA, a spatially explicit, process-oriented ecosystem model, was used to simulate successional dynamics. Inputs to the

  10. Heterogeneous pumice populations in the 2.08-Ma Cerro Galán Ignimbrite: Implications for magma recharge and ascent preceding a large-volume silicic eruption

    Science.gov (United States)

    Wright, Heather M.; Folkes, Christopher B.; Cas, Ray A.F.; Cashman, Katharine V.

    2011-01-01

    Triggering mechanisms of large silicic eruptions remain a critical unsolved problem. We address this question for the ~2.08-Ma caldera-forming eruption of Cerro Galán volcano, Argentina, which produced distinct pumice populations of two colors: grey (5%) and white (95%) that we believe may hold clues to the onset of eruptive activity. We demonstrate that the color variations correspond to both textural and compositional variations between the clast types. Both pumice types have bulk compositions of high-K, high-silica dacite to low-silica rhyolite, but there are sufficient compositional differences (e.g., ~150 ppm lower Ba at equivalent SiO2 content and 0.03 wt.% higher TiO2 in white pumice than grey) to suggest that the two pumice populations are not related by simple fractionation. Trace element concentrations in crystals mimic bulk variations between clast types, with grey pumice containing elevated Ba, Cu, Pb, and Zn concentrations in both bulk samples (average Cu, Pb, and Zn concentrations are 27, 35, and 82 in grey pumice vs. 11, 19, and 60 in white pumice) and biotite phenocrysts and white pumice showing elevated Li concentrations in biotite and plagioclase phenocrysts. White and grey clasts are also texturally distinct: White pumice clasts contain abundant phenocrysts (44–57%), lack microlites, and have highly evolved groundmass glass compositions (76.4–79.6 wt.% SiO2), whereas grey pumice clasts contain a lower percentage of phenocrysts/microphenocrysts (35–49%), have abundant microlites, and have less evolved groundmass glass compositions (69.4–73.8 wt.% SiO2). There is also evidence for crystal transfer between magma producing white and grey pumice. Thin highly evolved melt rims surround some fragmental crystals in grey pumice clasts and appear to have come from magma that produced white pumice. Furthermore, based on crystal compositions, white bands within banded pumice contain crystals originating in grey magma. Finally, only grey

  11. Geochemical behavior of rare earth elements associated with hydrothermal alteration. Implication for the migration and retardation of Am and Cm in hydrothermal system

    International Nuclear Information System (INIS)

    Rare earth element (REE) contents of hydrothermally altered dacitic and basaltic rocks in the Kuroko mining area were analyzed. It was found that geochemical features of REE (Light REE/Total REE ratio, La/Sm ratio, Eu anomaly) are related to K2O index (=K2O/(K2O+Na2O+CaO+MgO)x100) and oxygen isotopic composition (δ18O). This relation indicates that LREE (light rare earth element) did not remove from the rocks to hydrothermal solution and were probably added to the rocks from hydrothermal solution at and near the site of hydrothermal ore deposition. This geochemical behavior of LREE which are considered to be chemical analogue elements for Am and Cm suggests that Am and Cm would not remove from the high level nuclear waste glass if the hydrothermal solution ascent to the disposal site and contacted with the high level nuclear waste. (author)

  12. Rapid Synthesis of Carbon Dots by Hydrothermal Treatment of Lignin

    OpenAIRE

    Wenxin Chen; Chaofan Hu; Yunhua Yang; Jianghu Cui; Yingliang Liu

    2016-01-01

    A rapid approach has been developed for the fluorescent carbon dots (CDs) by the hydrothermal treatment of lignin in the presence of H2O2. The as-synthesized CDs were found to emit blue photoluminescence with excellent photostability. Moreover, the CDs displayed biocompatibility, low cytotoxicity, and high water solubility properties. Finally, the as-resulted CDs were demonstrated to be excellent probes for bioimaging and biosensing applications.

  13. Rapid Synthesis of Carbon Dots by Hydrothermal Treatment of Lignin

    Directory of Open Access Journals (Sweden)

    Wenxin Chen

    2016-03-01

    Full Text Available A rapid approach has been developed for the fluorescent carbon dots (CDs by the hydrothermal treatment of lignin in the presence of H2O2. The as-synthesized CDs were found to emit blue photoluminescence with excellent photostability. Moreover, the CDs displayed biocompatibility, low cytotoxicity, and high water solubility properties. Finally, the as-resulted CDs were demonstrated to be excellent probes for bioimaging and biosensing applications.

  14. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Directory of Open Access Journals (Sweden)

    Steven L Chown

    2012-01-01

    Full Text Available The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  15. Hydrothermal synthesis and characterization of zirconia based catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Caillot, T., E-mail: Thierry.caillot@ircelyon.univ-lyon1.fr; Salama, Z.; Chanut, N.; Cadete Santos Aires, F.J.; Bennici, S.; Auroux, A.

    2013-07-15

    In this work, three equimolar mixed oxides ZrO{sub 2}/CeO{sub 2}, ZrO{sub 2}/TiO{sub 2}, ZrO{sub 2}/La{sub 2}O{sub 3} and a reference ZrO{sub 2} have been synthesized by hydrothermal method. The structural and surface properties of these materials have been fully characterized by X-ray diffraction, transmission electron microscopy, surface area measurement, chemical analysis, XPS, infrared spectroscopy after adsorption of pyridine and adsorption microcalorimetry of NH{sub 3} and SO{sub 2} probe molecules. All investigated mixed oxides are amphoteric and possess redox centers on their surface. Moreover, hydrothermal synthesis leads to catalysts with higher surface area and with better acid–base properties than classical coprecipitation method. Both Lewis and Brønsted acid sites are present on the surface of the mixed oxides. Compared to the other samples, the ZrO{sub 2}/TiO{sub 2} material appears to be the best candidate for further application in acid–base catalysis. - Graphical abstract: Mesoporous amorphous phase with a high surface area of titania zirconia mixed oxide obtained by hydrothermal preparation. - Highlights: • Three zirconia based catalysts and a reference were prepared by hydrothermal synthesis. • Mixed oxides present larger surface areas than the reference ZrO{sub 2}. • ZrO{sub 2}/TiO{sub 2} catalyst presents a mesoporous structure with high surface area. • ZrO{sub 2}/TiO{sub 2} catalyst presents simultaneously strong acidic and basic properties.

  16. NASA/JPL hydrothermal vent bio-sampler

    Science.gov (United States)

    Jonsson, J.; Behar, A.; Bruckner, J.; Matthews, J.

    pagestyle empty begin document On the bottom of the oceans with volcanic activity present hydrothermal vents can be found which spew out mineral rich superheated water from the porous seafloor crust Some of these vents are situated several thousands of meters below the surface where the sunlight never reaches Yet life thrives here on the minerals and chemical compounds that the vent water brings up with it This chemosynthetic microbial community forms the basis of some of the most interesting ecosystems on our planet and could possibly also be found on other water rich planets and moons in the solar system Perhaps under the icy surface of the moon Europa there exist hydrothermal vents with such biota thriving independently of the solar energy The Hydrothermal Vent Bio-sampler HVB is a system which will be used to collect pristine samples of the water emanating from hydrothermal vents An array of temperature and flow sensors will monitor the sampling conditions This will allow for the samples to be collected from defined locations within the plume and the diversity and distribution of the chemosynthetic communities that might live there can be accurately described The samples will have to be taken without any contamination from the surrounding water thus the pristine requirement Monitoring the flow will assure that enough water has been sampled to account for the low biomass of these environments The system will be using a series of filters down to 0 2 mu m in pore size and the samples can be directly collected from the system for both culture-

  17. Explosive properties of water in volcanic and hydrothermal systems

    OpenAIRE

    Thiery, Régis; Mercury, Lionel

    2009-01-01

    International audience This paper describes, from a thermodynamic point of view, the physicochemical conditions, under which water behaves as an explosive. This phenomenon occurs frequently in hydrothermal and volcanic systems when water is brutally shifted from its initial equilibrium state. Water (either liquid or gas) becomes metastable or unstable and reequilibrates by violent demixing of a liquid-gas mixture. In a first step, a phenomenological approach of metastability is given in a ...

  18. Fabrication of agglomerate-free nanopowders by hydrothermal chemical processing

    OpenAIRE

    Schmidt, Helmut K.; Nass, Rüdiger; Burgard, Detlef; Nonninger, Ralph

    1998-01-01

    A chemical processing technique for the fabrication of nanopowders has been developed. The route is based on precipitation processes in solutions, either within aqueous droplets in microemulsions in the presence of surface modifiers like surfactants or by direct precipitation in solutions in the presence of theses surface modifiers or small organic molecules directly bonded to the particle surface. In order to obtain well crystallized or densified particles, a continuous flow hydrothermal pro...

  19. Hydrothermal liquefaction of Nannochloropsis oceanica in different solvents.

    Science.gov (United States)

    Caporgno, M P; Pruvost, J; Legrand, J; Lepine, O; Tazerout, M; Bengoa, C

    2016-08-01

    Although the hydrothermal liquefaction is considered a promising technology for converting microalgae into liquid biofuels, there are still some disadvantages. This paper demonstrated that the bio-oil yield can be significantly improved by adding alcohols as co-solvents and carrying out the conversion at mild conditions (microalgae (∼75% moisture) and alcohol concentrations which avoid both drying the microalgae and decreasing the amount of microalgae loaded in the reactor. PMID:27155795

  20. Hydrothermal Synthesis of Ni/Al Layered Double Hydroxide Nanorods

    OpenAIRE

    Yun Zhao; Fenfei Xiao; Qingze Jiao

    2011-01-01

    Ni/Al layered double hydroxide (LDH) nanorods were successfully synthesized by the hydrothermal reaction. The crystal structure of the products was characterized by X-ray diffraction (XRD). The morphology of the products was observed using transmission electron microscopy (TEM) and field emission scanning electron microscopy (SEM). The influences of reaction time and pH value on the morphology of the Ni/Al LDHs were investigated. The result showed that the well-crystallized nanorods of Ni/Al ...

  1. Hydrothermal heat discharge in the Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, S.E.; Mariner, R.H.

    2010-01-01

    Hydrothermal heat discharge in the Cascade Range includes the heat discharged by thermal springs, by "slightly thermal" springs that are only a few degrees warmer than ambient temperature, and by fumaroles. Thermal-spring heat discharge is calculated on the basis of chloride-flux measurements and geothermometer temperatures and totals ~ 240 MW in the U.S. part of the Cascade Range, excluding the transient post-1980 discharge at Mount St. Helens (~80 MW as of 2004-5). Heat discharge from "slightly thermal" springs is based on the degree of geothermal warming (after correction for gravitational potential energy effects) and totals ~. 660. MW. Fumarolic heat discharge is calculated by a variety of indirect and direct methods and totals ~160 MW, excluding the transient mid-1970s discharge at Mount Baker (~80 MW) and transient post-1980 discharge at Mount St. Helens (>. 230. MW as of 2005). Other than the pronounced transients at Mount St. Helens and Mount Baker, hydrothermal heat discharge in the Cascade Range appears to be fairly steady over a ~25-year period of measurement. Of the total of ~. 1050. MW of "steady" hydrothermal heat discharge identified in the U.S. part of the Cascade Range, less than 50. MW occurs north of latitude 45??15' N (~0.1 MW per km arc length from 45??15' to 49??N). Much greater rates of hydrothermal heat discharge south of 45??15'N (~1.7 MW per km arc length from 40?? to 45??15'N) may reflect the influence of Basin and Range-style extensional tectonics (faulting) that impinges on the Cascades as far north as Mount Jefferson but is not evident farther north. ?? 2010.

  2. Near shore submarine hydrothermal activity in Bahia Banderas, western Mexico

    OpenAIRE

    F. J. Núñez Cornú; Rosa María Prol Ledesma; A. Cupul Magaña; C. Suárez Plascencia

    2000-01-01

    Shallow submarine hydrothermal activity was detected in the Bahía de Banderas area, Mexico. Volcanic-type tremors were recorded by portable seismological stations onshore. Vent samples suggest a depositional sequence dominated by carbonates in the first stage (calcite and dolomite), followed by apatite and late barite veins. Layers of sequential deposition of sulfides were also observed, and are interpreted as cyclic variations of sulphur fugacity.

  3. Coupling Magnetotellurics and Hydrothermal Modeling to Further Understand Geothermal Resources

    Science.gov (United States)

    Folsom, M.; Pepin, J.; Kelley, S.; Person, M. A.; Blom, L.; Love, D.

    2015-12-01

    A comprehensive knowledge of the groundwater flow patterns associated with geothermal resources is critical to sustainable resource management and to discovering blind geothermal systems. Magnetotellurics (MT), which provides subsurface electrical conductivity information to substantial depths, has the ability to image geothermal reservoir features, such as conductive clay caps and hot, saline groundwater circulating within geothermal systems. We have used MT data along with 2D hydrothermal modeling, constrained by temperature, salinity and carbon-14 data, to explore possible deep groundwater circulation scenarios near the Sevilleta National Wildlife Refuge, in the Rio Grande Rift, central New Mexico. The area is underlain by a 100 to 150-m thick molten sill emplaced approximately 19 km below the surface. This sill is referred to locally as the Socorro Magma Body (SMB). Previous studies by Mailloux et al. (1999) and Pepin et al. (2015) suggest that the crystalline basement rocks in this region of the Rio Grande Rift can be significantly fractured to depths of 4-8 km and have permeabilities as high as 10-14 to 10-12 m2. The combination of high permeability conditions and the presence of the SMB makes this particular region a promising candidate for discovering a blind geothermal system at depth. We constructed a 2D hydrothermal model that traverses a 64-km zone of active uplift that is associated with the SMB. We also completed a 12-km long, 9-station MT transect across a portion of this profile, where land access was permitted and electromagnetic noise was minimal. Preliminary results suggest a deep convection-dominated system is a possibility, although further analysis of the MT data is necessary and ongoing. We hypothesize that using hydrothermal modeling in conjunction with MT surveys may prove to be an effective approach to discovering and managing deep regional hydrothermal resources.

  4. Air Pollution by Hydrothermal Volcanism and Human Pulmonary Function

    OpenAIRE

    Diana Linhares; Patrícia Ventura Garcia; Fátima Viveiros; Teresa Ferreira; Armindo dos Santos Rodrigues

    2015-01-01

    The aim of this study was to assess whether chronic exposure to volcanogenic air pollution by hydrothermal soil diffuse degassing is associated with respiratory defects in humans. This study was carried in the archipelago of the Azores, an area with active volcanism located in the Atlantic Ocean where Eurasian, African, and American lithospheric plates meet. A cross-sectional study was performed on a study group of 146 individuals inhabiting an area where volcanic activity is marked by active...

  5. Hydrothermal Synthesis of SnO2 Nanoparticles

    Institute of Scientific and Technical Information of China (English)

    Shuping Gong; Cong Xu; Huan Liu

    2006-01-01

    SnO2 nanoparticles with the average size of 3.7 nm have been successfully synthesized by hydrothermal method.The particles were characterized by XRD, SEM and TEM. The XRD results show that the products are all at nanometer scale,and the crystallite size increases with increasing of the heat-treatment temperature. The SEM and TEM photographs indicate that the particles are all monodispersed with narrow size distribution.

  6. Tailored super magnetic nanoparticles synthesized via template free hydrothermal technique

    Science.gov (United States)

    Attallah, Olivia A.; Girgis, E.; Abdel-Mottaleb, Mohamed M. S. A.

    2016-01-01

    Magnetite nanoparticles of controlled shape and dimensions were synthesized using a modified hydrothermal technique. The influence of different synthesis conditions on the shape, size (length and diameter), structure and magnetic properties of the prepared nanoparticles is presented. The mineral phases, the morphologies, size distribution of the resulting magnetic nanoparticles and their magnetic properties were characterized using different characterization methods. We designed magnetite nanoparticles with different morphologies (nanospheres, nanorods, nanocubes and hexagons) and with improved saturation magnetization reaching 90 emu/g.

  7. Apresentacão do Projeto de extensão universitaria "Fortalecimento das Capacidades das Educadoras do Programa CAIF no estado de Cerro Largo-Uruguai"

    Directory of Open Access Journals (Sweden)

    Mariana Porta Galván

    2015-12-01

    Full Text Available Dentro de la línea de investigación Estado, políticas sociales y ciudadanía en frontera, es relevante conocer la realidad de las políticas sociales orientadas a la primera infancia y sus implementaciones. Esta ponencia presenta un proyecto de extensión universitaria realizada con los centros CAIF de Cerro Largo con el propósito de fortalecer las prácticas de los operadores sociales de estos centros, a partir de las siguientes preguntas: ¿Qué características asume la implementación de esta política pública en un departamento fronterizo? ¿Qué desafíos plantea a sus operadores? Consideramos que la implementación de una política social, más allá de la forma en que se concibe, diseña y expresa en sus documentos, implica un proceso de apropiación que conlleva interpretaciones y adaptaciones que se manifiestan en prácticas. Estas, a su vez, responden a disposiciones, hábitos y saberes (entendidos como conocimientos tácitos y explícitos de los operadores involucrados, en un vínculo directo con la cultura propia de los contextos en los que se desarrollan. En ese proceso de implementación y sus múltiples niveles de gestión, se encuentran los desafíos a los cuales pretendemos aportar desde una propuesta de capacitación de operadores, que responda a la diversidad de cada territorio y de cada contexto social.

  8. Perfil infectológico de poblaciones mapuche de Cerro Policía y Aguada Guzmán de la provincia de Río Negro

    Directory of Open Access Journals (Sweden)

    Rey, Jorge Alberto

    1996-01-01

    Full Text Available Nuestro trabajo analiza la prevalencia de marcadores de algunas infecciones que afectan las poblaciones mapuche de Cerro Policía (CP y Aguada Guzmán (AG en la Prov. de Río Negro. Los estudios incluídos son: determinación de anticuerpos anti-Treponema pallidum, anti-Trypanosoma cruzii, anti-Echinococcus granulosus, antígeno de superficie de la Hepatitis B (HBsAg, anticuerpos contra el core de la Hepatitis B (anti-HBc, anticuerpos contra el virus de la Hepatitis A (anti-HAV. Se estudiaron 160 muestras en CP y 83 en AG. Los resultados muestran alta prevalencia para anti-HAV en CP (89.2% y en AG (77.1% y para hidatidosis (10.6% y 9.6% respectivamente. Se hallaron valores nulos o bajos para sífilis (CP: 0.0 % y AG:2.4%. La prevalencia para Chagas fue del 10% en CP y 0.0% en AG. Los datos para Hepatitis B fueron nulos o bajos: HBsAg (CP:0.0% y AG:1.2% y anti-HBc(CP:0.6% y AG:0.0%. Los resultados indican que, aún estando estas dos poblaciones tan próximas muestran diferencias en los perfiles de los marcadores serológicos estudiados. Al comparar las tasas de prevalencia con las de otras poblaciones de América, cada una presenta un perfil diferente que depende de la población y del agente infeccioso considerado.

  9. Prácticas de sacrificio en el Cerro de la Mesa (Alcolea de Tajo, Toledo: el depósito ritual de la Casa 1

    Directory of Open Access Journals (Sweden)

    Ana CABRERA DÍEZ

    2014-06-01

    Full Text Available Los depósitos con restos óseos animales enterrados bajo el pavimento en ámbitos domésticos forman parte de prácticas rituales bien conocidas en la Protohistoria peninsular, tradicionalmente asociadas a la fundación o remodelación de nuevos edificios o a ritos vinculados a la propiciación y la fertilidad. Aunque los ejemplos mejor estudiados se encuentran en la zona levantina, el fenómeno también se conoce en yacimientos del interior. Este artículo tiene por objeto presentar un depósito ritual excavado en el poblado vetón del Cerro de la Mesa, en el valle medio del Tajo, cuyas características formales lo emparentan con las ofrendas domésticas de la zona ibérica. Se trata de un hoyo situado en el umbral de la Casa 1, que contiene los restos seleccionados de varios ovinos y un pequeño cuenco cerámico colocado en posición invertida. El análisis de los restos óseos, el contenido del cuenco y el estudio del contexto arqueológico en que se situaba el depósito han permitido relacionarlo con prácticas de sacrificio y libación dentro del marco de la religiosidad vetona. Este trabajo pretende igualmente contribuir a la formación de un corpus peninsular de inhumaciones rituales de animales en contextos domésticos, que impulse el adecuado estudio de la ritualidad protohistórica.

  10. Evaluación del estado de conservación de las microcuencas pertenecientes a los Cerros Orientales de Chía, Cundinamarca, Colombia

    Directory of Open Access Journals (Sweden)

    Arévalo Santos Carolina

    2006-06-01

    Full Text Available El trabajo se realizó en colaboración con la Alcaldía Municipal de Chía, Cundinamarca, Colombia, con el fin de
    aproximarnos al estado de conservación de las microcuencas localizadas sobre la cota de altitud 2.600-3.200 msnm, en las veredas de Yerbabuena y Fusca, donde se identificaron cuatro microcuencas de interés: Mana- Yerbabuena, Coseteja, Fusca y Honda-Pan de Azúcar. El documento final se presenta como un instrumento para el conocimiento de los cerros Orientales de Chía a una escala municipal, cuyo enfoque establece los diferentes tipos de cobertura de vegetación existentes como indicador del estado actual de las microcuencas y evidencia situaciones críticas que pueden propiciar su total degradación. Los resultados permiten concluir que los procesos de transformación son bastante intensos, debido básicamente a la acción antrópica que ha hecho de los procesos urbanísticos el factor de amenaza más significativo, que ha conducido a la pérdida acelerada de la vegetación, apertura de vías de acceso, uso inadecuado de las fuentes hídricas etc. El producto principal de este  análisis es la generación de un mapa de áreas de interés ambiental que proponemos deben ser proyectadas ya sea
    para fines de conservación, restauración, recuperación y áreas cuyo manejo de conflictos debe ser prioridad. La
    importancia de establecer el estado de conservación deriva de la necesidad de proporcionar bases para el desarrollo de planes de manejo ambiental.

  11. Hydrothermal synthesis of magnetite particles with uncommon crystal facets

    Directory of Open Access Journals (Sweden)

    Junki Sato

    2014-09-01

    Full Text Available Hydrothermal synthesis of Fe3O4 (magnetite particles was carried out using organic compounds as morphology control agents to obtain magnetite crystals with uncommon facets. It was established that the morphology of Fe3O4 crystals obtained by hydrothermal treatment of an aqueous solution containing Fe2+ and organic compounds depended on the organic compound used. The shape of the Fe3O4 particles obtained when no additives were used was quasi-octahedral. In contrast, the addition of picolinic acid, citric acid or pyridine resulted in the formation of polyhedral crystals, indicating the presence of not only {1 1 1}, {1 0 0} and {1 1 0} facets but also high-index facets including at least {3 1 1} and {3 3 1}. When citric acid was used as an additive, octahedral crystals with {1 1 1} facets also appeared, and their size decreased as the amount of citric acid was increased. Thus, control of Fe3O4 particle morphology was achieved by a simple hydrothermal treatment using additives.

  12. Accumulation of formamide in hydrothermal pores to form prebiotic nucleobases.

    Science.gov (United States)

    Niether, Doreen; Afanasenkau, Dzmitry; Dhont, Jan K G; Wiegand, Simone

    2016-04-19

    Formamide is one of the important compounds from which prebiotic molecules can be synthesized, provided that its concentration is sufficiently high. For nucleotides and short DNA strands, it has been shown that a high degree of accumulation in hydrothermal pores occurs, so that temperature gradients might play a role in the origin of life [Baaske P, et al. (2007)Proc Natl Acad Sci USA104(22):9346-9351]. We show that the same combination of thermophoresis and convection in hydrothermal pores leads to accumulation of formamide up to concentrations where nucleobases are formed. The thermophoretic properties of aqueous formamide solutions are studied by means of Infrared Thermal Diffusion Forced Rayleigh Scattering. These data are used in numerical finite element calculations in hydrothermal pores for various initial concentrations, ambient temperatures, and pore sizes. The high degree of formamide accumulation is due to an unusual temperature and concentration dependence of the thermophoretic behavior of formamide. The accumulation fold in part of the pores increases strongly with increasing aspect ratio of the pores, and saturates to highly concentrated aqueous formamide solutions of ∼85 wt% at large aspect ratios. Time-dependent studies show that these high concentrations are reached after 45-90 d, starting with an initial formamide weight fraction of[Formula: see text]wt % that is typical for concentrations in shallow lakes on early Earth. PMID:27044100

  13. Agro-industrial waste to solid biofuel through hydrothermal carbonization.

    Science.gov (United States)

    Basso, Daniele; Patuzzi, Francesco; Castello, Daniele; Baratieri, Marco; Rada, Elena Cristina; Weiss-Hortala, Elsa; Fiori, Luca

    2016-01-01

    In this paper, the use of grape marc for energy purposes was investigated. Grape marc is a residual lignocellulosic by-product from the winery industry, which is present in every world region where vine-making is addressed. Among the others, hydrothermal carbonization was chosen as a promising alternative thermochemical process, suitable for the treatment of this high moisture substrate. Through a 50 mL experimental apparatus, hydrothermal carbonization tests were performed at several temperatures (namely: 180, 220 and 250 °C) and residence times (1, 3, 8 h). Analyses on both the solid and the gaseous phases obtained downstream of the process were performed. In particular, solid and gas yields versus the process operational conditions were studied and the obtained hydrochar was evaluated in terms of calorific value, elemental analysis, and thermal stability. Data testify that hydrochar form grape marc presents interesting values of HHV (in the range 19.8-24.1 MJ/kg) and physical-chemical characteristics which make hydrochar exploitable as a solid biofuel. In the meanwhile, the amount of gases produced is very small, if compared to other thermochemical processes. This represents an interesting result when considering environmental issues. Statistical analysis of data allows to affirm that, in the chosen range of operational conditions, the process is influenced more by temperature than residence time. These preliminary results support the option of upgrading grape marc toward its energetic valorisation through hydrothermal carbonization.

  14. Ecology of deep-sea hydrothermal vent communities: A review

    Science.gov (United States)

    Lutz, Richard A.; Kennish, Michael J.

    1993-08-01

    Studies of the many active and inactive hydrothermal vents found during the past 15 years have radically altered views of biological and geological processes in the deep sea. The biological communities occupying the vast and relatively stable soft bottom habitats of the deep sea are characterized by low population densities, high species diversity, and low biomass. In contrast, those inhabiting the generally unstable conditions of hydrothermal vent environments exhibit high densities and biomass, low species diversity, rapid growth rates, and high metabolic rates. Biological processes, such as rates of metabolism and growth, in vent organisms are comparable to those observed in organisms from shallow-water ecosystems. An abundant energy source is provided by chemosynthetic bacteria that constitute the primary producers sustaining the lush communities at the hydrothermal sites. Fluxes in vent flow and fluid chemistry cause changes in growth rates, reproduction, mortality, and/or colonization of vent fauna, leading to temporal and spatial variation of the vent communities. Vent populations that cannot adapt to modified flow rates are adversely affected, as is evidenced by high mortality or lower rates of colonization, growth, or reproduction. Substantial changes in biota have been witnessed at several vents, and successional cycles have been proposed for the Galapagos vent fields. Dramatic temporal and spatial variations in vent community structure may also relate to variations in larval dispersal and chance recruitment, as well as biotic interactions.

  15. DESIGN OF NOVEL HIGH PRESSURE- RESISTANT HYDROTHERMAL FLUID SAMPLE VALVE

    Institute of Scientific and Technical Information of China (English)

    LIU Wei; YANG Canjun; WU Shijun; XIE Yingjun; CHEN Ying

    2008-01-01

    Sampling study is an effective exploration method, but the most extreme environments of hydrothermal vents pose considerable engineering challenges for sampling hydrothermal fluids. Moreover, traditional sampler systems with sample valves have difficulty in maintaining samples in situ pressure. However, decompression changes have effect on microorganisms sensitive to such stresses. To address the technical difficulty of collecting samples from hydrothermal vents, a new bidirectional high pressure-resistant sample valve with balanced poppet was designed. The sample valve utilizes a soft high performance plastic "PEEK" as poppet. The poppet with inapposite dimension is prone to occur to plastic deformation or rupture for high working pressure in experiments. To address this issue, based on the finite element model, simulated results on stress distribution of the poppet with different structure parameters and preload spring force were obtained. The static axial deformations on top of the poppet were experimented. The simulated results agree with the experimental results. The new sample valve seals well and it can withstand high working pressure.

  16. Rapid growth of mineral deposits at artificial seafloor hydrothermal vents.

    Science.gov (United States)

    Nozaki, Tatsuo; Ishibashi, Jun-Ichiro; Shimada, Kazuhiko; Nagase, Toshiro; Takaya, Yutaro; Kato, Yasuhiro; Kawagucci, Shinsuke; Watsuji, Tomoo; Shibuya, Takazo; Yamada, Ryoichi; Saruhashi, Tomokazu; Kyo, Masanori; Takai, Ken

    2016-01-01

    Seafloor massive sulphide deposits are potential resources for base and precious metals (Cu-Pb-Zn ± Ag ± Au), but difficulties in estimating precise reserves and assessing environmental impacts hinder exploration and commercial mining. Here, we report petrological and geochemical properties of sulphide chimneys less than 2 years old that formed where scientific boreholes vented hydrothermal fluids in the Iheya-North field, Okinawa Trough, in East China Sea. One of these infant chimneys, dominated by Cu-Pb-Zn-rich sulphide minerals, grew a height of 15 m within 25 months. Portions of infant chimneys are dominated by sulphate minerals. Some infant chimneys are sulphide-rich similar to high-grade Cu-Pb-Zn bodies on land, albeit with relatively low As and Sb concentrations. The high growth rate reaching the 15 m height within 25 months is attributed to the large hydrothermal vent more than 50 cm in diameter created by the borehole, which induced slow mixing with the ambient seawater and enhanced efficiency of sulphide deposition. These observations suggest the possibility of cultivating seafloor sulphide deposits and even controlling their growth and grades through manipulations of how to mix and quench hydrothermal fluids with the ambient seawater. PMID:26911272

  17. Experimental Investigation of Organic Synthesis in Hydrothermal Environments

    Science.gov (United States)

    Shock, Everett L.

    1998-01-01

    The results of the investigation were presented at a Astrobiology Institute General Meeting. Seafloor hydrothermal systems may be the most likely locations on the early Earth for the emergence of life. Because of the disequilibrium inherent in such dynamic, mixing environments, abundant chemical energy would have been available for formation of the building blocks of life. In addition, theoretical studies suggest that organic compounds in these conditions would reach metastable states, due to kinetic barriers to the formation of stable equilibrium products (CO2 and methane). The speciation of organic carbon in metastable states is highly dependent on the oxidation state, pH, temperature, pressure and bulk composition of the system. The goal of our research is to investigate the effects of a number external variables on the formation, transformation, and stability of organic compounds at hydrothermal conditions. We have begun experimental work to attempt to control the oxidation state of simulated hydrothermal systems by using buffers composed of mineral powders and gas mixtures. We are also beginning to test the stability of organic compounds under these conditions.

  18. Hydrothermal Solidification of Diatomite and Its Heat Insulating Property

    Institute of Scientific and Technical Information of China (English)

    TONG Yu; GAO Jian; XIA Feng; XU Dawei; SONG Lili; YANG Wenrui; ZENG You

    2012-01-01

    To meet the commercial requirements of inorganic heat insulators,the mixture of diatomite and Ca(OH) 2 are evenly dispersed,mold-compacted,and then hydrothermally solidified due to the formation of tobermorite under an autoclaved process.Systematic investigations of the preparation conditions (including mix ratio,autoclaved factors,mold pressure,etc)were carried out to optimize the serving properties of such toberrnorite-based products.As a result,a compressive strength of more than 30 MPa was realized for the specimen in high density( about 1.30( g·cm-3) ).On the contrary,the specimen in light weight for example 0.63 ( g ·cm-3 ) typically showed a thermal conductivity of around 0.12 ( W· m-1· K-1 ).The present work developed a feasible way to produce and to control the serving properties of diatomite-based heat insulators by a process of hydrothermal solidification,in which the optimized value of Ca/Si ratio was proposed to be 0.6 ~ 0.7,while the water content is 25 % in weight,and hydrothermal reaction is performed at 180 ℃ for no more than 24 hours.

  19. Polymer-Assisted Hydrothermal Synthesis of Hierarchically Arranged Hydroxyapatite Nanoceramic

    Directory of Open Access Journals (Sweden)

    A. Joseph Nathanael

    2013-01-01

    Full Text Available Flower-like hydroxyapatite (HA nanostructures were synthesized by a polymer-assisted hydrothermal method. The thickness of the petals/plates decreased from 200 nm to 40 nm as the polymer concentration increased. The thickness also decreased as the hydrothermal treatment time increased from 6 to 12 hr. The HRTEM and SAED patterns suggest that the floral-like HA nanostructures are single crystalline in nature. Structural analysis based on XRD and Raman experiments implied that the produced nanostructure is a pure form of HA without any other impurities. The possible formation mechanism was discussed for the formation of flower-like HA nanostructures during polymer-assisted hydrothermal synthesis. Finally, in vitro cellular analysis revealed that the hierarchically arranged HA nanoceramic had improved cell viability relative to other structures. The cells were actively proliferated over these nanostructures due to lower cytotoxicity. Overall, the size and the crystallinity of the nanostructures played a role in improving the cell proliferation.

  20. Accumulation of formamide in hydrothermal pores to form prebiotic nucleobases

    Science.gov (United States)

    Niether, Doreen; Afanasenkau, Dzmitry; Dhont, Jan K. G.

    2016-04-01

    Formamide is one of the important compounds from which prebiotic molecules can be synthesized, provided that its concentration is sufficiently high. For nucleotides and short DNA strands, it has been shown that a high degree of accumulation in hydrothermal pores occurs, so that temperature gradients might play a role in the origin of life [Baaske P, et al. (2007) Proc Natl Acad Sci USA 104(22):9346-9351]. We show that the same combination of thermophoresis and convection in hydrothermal pores leads to accumulation of formamide up to concentrations where nucleobases are formed. The thermophoretic properties of aqueous formamide solutions are studied by means of Infrared Thermal Diffusion Forced Rayleigh Scattering. These data are used in numerical finite element calculations in hydrothermal pores for various initial concentrations, ambient temperatures, and pore sizes. The high degree of formamide accumulation is due to an unusual temperature and concentration dependence of the thermophoretic behavior of formamide. The accumulation fold in part of the pores increases strongly with increasing aspect ratio of the pores, and saturates to highly concentrated aqueous formamide solutions of ˜85 wt% at large aspect ratios. Time-dependent studies show that these high concentrations are reached after 45-90 d, starting with an initial formamide weight fraction of 10-310-3 wt % that is typical for concentrations in shallow lakes on early Earth.

  1. Andesita Cerro Bola: Nueva unidad vinculada al magmatismo mioceno de la Cordillera de Olivares, San Juan, Argentina (30°35´S; 69°30´O

    Directory of Open Access Journals (Sweden)

    A.F. Wetten

    2005-03-01

    Full Text Available El área de estudio se halla en la zona de Tocota, inmediatamente al este de la Cordillera de Olivares, en el borde oriental de la Cordillera Frontal, provincia de San Juan. En ella se encuentran unidades ígneas y sedimentarias del ciclo gondwánico, las que fueron intruidas y cubiertas en relación discordante por cuerpos subvolcánicos y volcánicos asignados anteriormente al ciclo ándico en sentido amplio, los cuales constituyen el principal objeto del presente estudio. Estos cuerpos han sido mapeados a fin de poder caracterizarlos adecuadamente, en el contexto estratigráfico de la región. Los afloramientos de interés han sido reconocidos en el cerro Bola y alrededores, donde se observan distribuidos irregularmente, cubriendo un área superior a 5 km². Las rocas, de coloración gris clara y composición andesítica - fenoandesítica, presentan estructuras de domo y colada. Estos afloramientos serían correlacionables con la unidad volcánica Pircas (Mioceno, la que aflora al oeste, y conformarían un evento magmático posterior al de pórfidos de diferente composición situados tanto en el arroyo Chita como en el cerro Divisadero. La extensión del área involucrada, la uniformidad litológica, el bajo grado de alteración y una edad radimétrica obtenida por el método K/Ar, fueron considerados para proponer a estas volcanitas como una unidad litoestratigráfica de edad miocena superior, con la denominación de Andesita Cerro Bola.

  2. Two hydrothermal fields found on the Southern Mid-Atlantic Ridge

    Institute of Scientific and Technical Information of China (English)

    TAO ChunHui; LEI JiJiang; WANG YeJian; DY115-21 Leg 4 Science Party; LI HuaiMing; YANG YaoMin; NI JianYu; CUI RuYong; CHEN YongShun; LI JiaBiao; HE YongHua; HUANG Wei

    2011-01-01

    In recent years,a series of cruises have been launched by China Ocean Mineral Resources Research and Development Association (COMRA) to conduct hydrothermal activity investigation at mid-ocean ridges (MOR).Since the first active hydrothermal field at 49.6°E Southwest Indian Ridge (SWIR) was found in 2007 by Chinese scientists on board R/V Dayangyihao,more hydrothermal fields have been found on the SWIR and equatorial East Pacific Rise (EPR)[1-4].From November to December 2009,two new hydrothermal fields were discovered at 13°-14°S South MidAtlantic Ridge (SMAR) during Cruise DYl15-21,representing the first discovery of hydrothermal fields on the MAR for China.They are also the southernmost hydrothermal fields known on the MAR at that time.

  3. Geochronology of TAG and Snakepit hydrothermal fields, Mid-Atlantic Ridge: Witness to a long and complex hydrothermal history

    International Nuclear Information System (INIS)

    Geochronological studies of a large number of precipitates from the TAG hydrothermal field and of few samples from Snakepit hydrothermal field of the Mid-Atlantic Ridge show intermittent repeated hydrothermal events at both sites. 210Pb/Pb and 230Th/234U measurements of sulfides, iron and manganese oxides, and 14C measurements of carbonates combined with observations of hydrothermal events recorded as discrete layers in sediment cores provide the basis for unravelling the temporal history of the fields. The TAG field shows intermittent activity over the past 120,000 years as evidenced by ages of low-temperature Mn oxides. The presently active black smoker mound first formed about 40,000-50,000 years ago with precipitation of massive sulfides. It has had intermittent, pulsed high-temperature activity every 5000-6000 years over the past 20,000 years which may reflect renewed magmatic actvity at the ridge axis. Fluid flow is focussed at the mound site by structural and tectonic control suggested by the intersection of N-S ridge parallel lystric normal faults and an E-W transform fault. Periods of inactivity are marked by covering of the mound with pelagic carbonate ooze which is probably partially dissolved and reprecipiated as aragonite at the end of each high-temperature event. The Snakepit field had an initial event about 4000 years ago, probably shortly after the eruption of the volcanic ridge on which it sits. A recent renewal, still presently active, was probably initiated by recent fissuring of the volcanic pile. (orig.)

  4. Hydrothermal conversion of chrysotile asbestos using near supercritical conditions

    International Nuclear Information System (INIS)

    The present research investigates, develops and evaluates the transformation of chrysotile asbestos into a non-hazardous material, such as forsterite, using an economically viable and safe method. The aim of this study is to convert fibrous chrysotile asbestos into an anhydrous magnesium silicate with a non-hazardous lamellar morphology using supercritical steam. The treatment method is characterized as hydrothermal in a temperature and pressure range of 300-700 deg. C and 1.75-5.80 MPa, respectively. Small amounts of asbestos (2.5 g) were treated in each experiment. Deionised water was used as the treatment solution. The treatment duration varied from approximately 1-5 h. Additional experiments took place using solutions of distilled water and small amounts of acetic acid, with the aim of attaining optimal treatment conditions. Crystal phases of the samples were determined by X-ray diffraction (XRD). The main phases present in the treated samples were forsterite, enstatite, and chrysotile asbestos. Lizardite and periclase were also found. The morphology of the treated chrysotile asbestos fibers was identified by scanning electron microscope (SEM). The fibrous form of chrysotile asbestos was converted into non-fibrous form of forsterite. In fact, none of the fibrous-needle-like morphology, with length equal to or greater than 5 μm and diameter less than 3 μm, which was responsible for the toxicity of the original material, was visible in the solid phase. The dissolution of magnesium from chrysotile asbestos was measured using volumetric determination by titration with EDTA. Leaching of magnesium into the liquid phase was observed. Clearly, the highest concentrations of dissolved magnesium are observed after hydrothermal treatment of chrysotile asbestos using acetic acid 1% (8.4-14.6%). Lowest concentrations of dissolved magnesium are obtained after hydrothermal treatment of chrysotile asbestos without using additives. Observing the results of the hydrothermal

  5. Hydrothermal conversion of chrysotile asbestos using near supercritical conditions

    Energy Technology Data Exchange (ETDEWEB)

    Anastasiadou, Kalliopi; Axiotis, Dimosthenis [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, Chania, P.C. 73100 (Greece); Gidarakos, Evangelos, E-mail: gidarako@mred.tuc.gr [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, Chania, P.C. 73100 (Greece)

    2010-07-15

    The present research investigates, develops and evaluates the transformation of chrysotile asbestos into a non-hazardous material, such as forsterite, using an economically viable and safe method. The aim of this study is to convert fibrous chrysotile asbestos into an anhydrous magnesium silicate with a non-hazardous lamellar morphology using supercritical steam. The treatment method is characterized as hydrothermal in a temperature and pressure range of 300-700 deg. C and 1.75-5.80 MPa, respectively. Small amounts of asbestos (2.5 g) were treated in each experiment. Deionised water was used as the treatment solution. The treatment duration varied from approximately 1-5 h. Additional experiments took place using solutions of distilled water and small amounts of acetic acid, with the aim of attaining optimal treatment conditions. Crystal phases of the samples were determined by X-ray diffraction (XRD). The main phases present in the treated samples were forsterite, enstatite, and chrysotile asbestos. Lizardite and periclase were also found. The morphology of the treated chrysotile asbestos fibers was identified by scanning electron microscope (SEM). The fibrous form of chrysotile asbestos was converted into non-fibrous form of forsterite. In fact, none of the fibrous-needle-like morphology, with length equal to or greater than 5 {mu}m and diameter less than 3 {mu}m, which was responsible for the toxicity of the original material, was visible in the solid phase. The dissolution of magnesium from chrysotile asbestos was measured using volumetric determination by titration with EDTA. Leaching of magnesium into the liquid phase was observed. Clearly, the highest concentrations of dissolved magnesium are observed after hydrothermal treatment of chrysotile asbestos using acetic acid 1% (8.4-14.6%). Lowest concentrations of dissolved magnesium are obtained after hydrothermal treatment of chrysotile asbestos without using additives. Observing the results of the hydrothermal

  6. Hydrothermal circulation within the Endeavour Segment, Juan de Fuca Ridge

    Science.gov (United States)

    Johnson, H. Paul; Tivey, Maurice A.; Bjorklund, Tor A.; Salmi, Marie S.

    2010-05-01

    Areas of the seafloor at mid-ocean ridges where hydrothermal vents discharge are easily recognized by the dramatic biological, physical, and chemical processes that characterize such sites. Locations where seawater flows into the seafloor to recharge hydrothermal cells within the crustal reservoir are by contrast almost invisible but can be indirectly identified by a systematic grid of conductive heat flow measurements. An array of conductive heat flow stations in the Endeavour axial valley of the Juan de Fuca Ridge has identified recharge zones that appear to represent a nested system of fluid circulation paths. At the scale of an axial rift valley, conductive heat flow data indicate a general cross-valley fluid flow, where seawater enters the shallow subsurface crustal reservoir at the eastern wall of the Endeavour axial valley and undergoes a kilometer of horizontal transit beneath the valley floor, finally exiting as warm hydrothermal fluid discharge on the western valley bounding wall. Recharge zones also have been identified as located within an annular ring of very cold seafloor around the large Main Endeavour Hydrothermal Field, with seawater inflow occurring within faults that surround the fluid discharge sites. These conductive heat flow data are consistent with previous models where high-temperature fluid circulation cells beneath large hydrothermal vent fields may be composed of narrow vertical cylinders. Subsurface fluid circulation on the Endeavour Segment occurs at various crustal depths in three distinct modes: (1) general east to west flow across the entire valley floor, (2) in narrow cylinders that penetrate deeply to high-temperature heat sources, and (3) supplying low-temperature diffuse vents where seawater is entrained into the shallow uppermost crust by the adjacent high-temperature cylindrical systems. The systematic array of conductive heat flow measurements over the axial valley floor averaged ˜150 mW/m2, suggesting that only about 3% of

  7. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Zuldesmi, Mansjur, E-mail: mzuldesmi@yahoo.com [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Department of Mechanical Engineering, Manad State University (UNIMA) (Indonesia); Waki, Atsushi [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Kuroda, Kensuke; Okido, Masazumi [EcoTopia Science Institute, Nagoya University, Nagoya (Japan)

    2015-04-01

    The surface wettability of implants is a crucial factor in their osteoconductivity because it influences the adsorption of cell-attached proteins onto the surface. In this study, a single-step hydrothermal surface treatment using distilled water at a temperature of 180 °C for 3 h was applied to titanium (Ti) and its alloys (Ti–6Al–4V, Ti–6Al–7Nb, Ti–29Nb–13Ta–4.6Zr, Ti–13Cr–1Fe–3Al; mass%) and compared with as-polished Ti implants and with implants produced by anodizing Ti in 0.1 M of H{sub 3}PO{sub 4} with applied voltages from 0 V to 150 V at a scanning rate of 0.1 V s{sup −1}. The surface-treated samples were stored in a five time phosphate buffered saline (× 5 PBS(−)) solution to prevent increasing the water contact angle (WCA) with time. The surface characteristics were evaluated using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Auger electron spectroscopy, surface roughness, and contact angle measurement using a 2 μL droplet of distilled water. The relationship between WCA and osteoconductivity at various surface modifications was examined using in vivo tests. The results showed that a superhydrophilic surface with a WCA ≤ 10° and a high osteoconductivity (R{sub B–I}) of up to 50% in the cortical bone part, about four times higher than the as-polished Ti and Ti alloys, were provided by the combination of the hydrothermal surface treatment and storage in × 5 of PBS(−). - Highlights: • Hydrothermal treatment in distilled water was applied to titanium alloys. • Surface characteristics and osteoconductivity by in vivo test were evaluated. • Water contact angles of titanium alloys were decreased by hydrothermal treatment. • Osteoconductivity of titanium alloys improved notably by hydrothermal treatment after stored in × 5 of PBS (−)

  8. “La parte alta del cerro es para los pequeños mineros”. Sobre la vigencia del régimen minero especial para Marmato y su influencia en la construcción de territorialidad

    Directory of Open Access Journals (Sweden)

    Gloria Patricia Lopera Mesa

    2015-12-01

    Full Text Available Este artículo examina las circunstancias que motivaron la expedición de un régimen especial para las minas de Marmato a mediados del siglo XX, el cual reserva la parte alta del cerro para el ejercicio de la pequeña minería. Asimismo, explora la vigencia de dichas normas y la manera en que ellas han influido la construcción de territorialidad y el desarrollo de una forma de vida en torno al ejercicio de la pequeña minería tradicional.

  9. La avalancha de rocas del cerro Los Cardos (37°10´S,70°53´O) en la región norte de la provincia del Neuquén

    OpenAIRE

    E.F. González Díaz; Folguera, A.; Hermanns, R.

    2005-01-01

    Se describe una nueva e importante avalancha de rocas, no reconocida hasta ahora, localizada a unos 25 km al oeste de la población de Andacollo. Muestra dos cicatrices o muescas de desprendimiento, de las cuales la austral es interpretada como la muesca principal de su desprendimiento y se halla al pie del borde occidental de una planicie estructural lávica, sobre cuyo extremo norte se ubica el cerro Los Cardos. Es un complejo movimiento, con numerosas escarpas de arranque internas en la masa...

  10. Evolución petrotectónica del distrito minero Cerro Áspero y modelo de emplazamiento de los depósitos wolframíferos, Córdoba

    OpenAIRE

    D. Mutti; S. González Chiozza

    2005-01-01

    La geología relacionada con la intrusión granítica Cerro Áspero expone en el faldeo oriental de la sierra de Comechingones, mineralización metalífera diseminada y en brechas hidráulicas, conectada genéticamente a un grupo minero integrado por un sistema de enjambres de venas, vetas y mantos cuarzosos con direcciones NNO, ONO y N. La comarca presenta polimetamorfismo y al menos, dos eventos de cizallamiento simple (D3 y D4) y estructuras penetrativas (S2, S3 y S4) que se desarrollaron desde el...

  11. Cuerpos intrusivos asociados a las mineralizaciones polimetálicas del depósito Cerro León, área del anticlinal El Tranquilo, Santa Cruz: evidencias geofísicas

    OpenAIRE

    2008-01-01

    Las características geológicas tales como presencia de cuerpos intrusivos y subvolcánicos someros básicos a intermedios y de las mineralizaciones con alto contenido de sulfuros del área del anticlinal El Tranquilo, son particulares y poco representadas en el macizo del Deseado. El depósito polimetálico vetiforme Cerro León presenta una signatura geoquímica-mineralógica que lo diferencia del clásico modelo epitermal de baja sulfuración característico del macizo del Deseado. Los datos aeromagné...

  12. Hydrothermal alteration of the ocean crust: insights from Macquarie Island and drilled in situ ocean crust

    OpenAIRE

    Coggon, Rosalind Mary

    2006-01-01

    Hydrothermal circulation is a fundamental process in the formation and aging of the ocean crust, influencing its structure, physical and chemical properties, and the composition of the oceans and the mantle. The impact of hydrothermal circulation on mid-ocean ridge processes depends on the composition and volume of circulating hydrothermal fluids, and the extent of partitioning between high temperature axial- and low temperature ridge flank- systems, but these processes remain ...

  13. Constraints on mineralisation and hydrothermal alteration in the Nalunaq gold deposit, South Greenland

    DEFF Research Database (Denmark)

    Bell, Robin-Marie Fairbairn

    -and - medium grained amphibolite of the Nanortalik Nappe. Detailed petrographic and geochronological studies have revealed a multi-stage hydrothermal alteration system, with alteration pre-and post-dating gold mineralisation. The hydrothermal alteration records a transition from upper-amphibolite facies...... to lower greenschist facies metamorphic conditions, over a period of 40 million years. The development of the hydrothermal alteration can be correlated to deformation events in the wider Palaeoproterozoic Ketilidian Orogen. Petrographic thin section analysis has shown that sulphidation, saussuritization...

  14. GEOCHEMICAL CHARACTERISTICS OF STABLE ISOTOPES FROM HYDROTHERMAL CHIMNEYS IN THE MARIANA TROUGH, WEST PACIFIC OCEAN

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The determination of the stable isotopes, δD, δ18O and δ30Si, values from hydrothermal chimneys in the Mariana Trough, the West Pacific, indicated that the pure siliceous chimneys with gentle data variation were formed in low temperature environment. It reflects that the sea-floor hydrothermal activity of the Mariana Trough is primarily low-to-medium temperature hydrothermal eruption, and those chimneys with strong data variation and containing pyrite were formed in higher temperature environment.

  15. Dike-Driven Hydrothermal Processes on Mars and Sill Emplacement on Europa

    OpenAIRE

    Craft, Kathleen Liana

    2013-01-01

    Evidence of hydrothermal and tectonic activity is found throughout our solar system. Here I investigated hydrothermal and fracturing processes on three planetary bodies: Earth, Mars and Europa. For the first project, we set up a dike-driven hydrothermal system and calculated heat and water flow using boundary layer theory. Water flow rates and volumes were then compared to the requirements for surface feature formation. Results found that the water volumes produced were adequate to form At...

  16. Influence of Hydrothermal Temperature on Phosphorus Recovery Efficiency of Porous Calcium Silicate Hydrate

    OpenAIRE

    Wei Guan; Fangying Ji; Qingkong Chen; Peng Yan; Weiwei Zhou

    2013-01-01

    Porous calcium silicate hydrate (PCSH) was synthesized by carbide residue and white carbon black. The influence of hydrothermal temperature on phosphorus recovery efficiency was investigated by Field Emission Scanning Electron Microscopy (FESEM), Brunauer-Emmett-Teller (BET), and X-Ray Diffraction (XRD). Hydrothermal temperature exerted significant influence on phosphorus recovery performance of PCSH. Hydrothermal temperature 170°C for PCSH was more proper to recover phosphorus. PCSH could re...

  17. Influence of aluminum on the hydrothermal alteration rate of olivine

    Science.gov (United States)

    Andreani, M.; Daniel, I.; Pollet-Villard, M.

    2013-12-01

    The reactivity of ultramafic rocks under hydrothermal conditions controls chemical fluxes at the interface between the internal and external reservoirs of silicate planets. On Earth, hydration of ultramafic rocks is ubiquitous and operates from deep subduction zones to shallow lithospheric environments where it considerably affects the physical and chemical properties of rocks and can interact with the biosphere. This process also has key emerging societal implications, such as the production of hydrogen as a source of carbon-free energy. To date, the chemical model systems used to reproduce olivine hydrothermal alteration lead to the formation of serpentine with sluggish reaction rates. Although aluminum is common in geological environments and in hydrothermal systems in particular, its role in serpentinization or olivine dissolution has not been investigated under hydrothermal conditions. Nevertheless, abundant Al supply is expected in fluids released from dehydration of metapelites in subduction zones as well as during the hydrothermal alteration of gabbros at mid-ocean ridges. Aluminum was also abundant in primitive environments of both the Earth and Mars, stored in either Al-rich minerals like plagioclase or Al-enriched ultramafic lavas. We have investigated the role of Al on the hydrothermal alteration of olivine in a series of experiments performed in a low-pressure diamond anvil cell while following the reaction progress in situ by optical imaging and by confocal Raman spectroscopy. Experiments were run for 4.5 to 7.5 days with two olivine grains reacted in saline water (0.5 molal NaCl) at 200°C and 300°C, and P=200 MPa. After two days, olivine crystals were fully transformed to an aluminous serpentine, also enriched in iron. The very fast precipitation of serpentine may inhibit magnetite nucleation here. However, this does not rule out an H2 production since serpentines classically incorporate non negligible amount of ferric iron in their structure. The

  18. A high-temperature hydrothermal deposit on the East Pacific Rise near 70N

    International Nuclear Information System (INIS)

    A SEABEAM survey of the East Pacific Rise (EPR) led to the selection of several sites having structural characteristics favorable for hydrothermal activity. Dredging of such an area located at 70 N on the EPR resulted in the recovery of sulfides, oxides and fresh basalt. Chemical analyses and isotopic compositions showed that the recovered pyrites were probably precipitated directly from hot vent hydrothermal waters. Chemical analyses and isotopic composition of manganese-iron oxides indicated that they too were of hydrothermal origin. 210Pb/Pb measurements yielded ages of 90 +- 10 years for the deposits. This site may still be undergoing hydrothermal activity. (orig.)

  19. Spatial distribution of viruses associated with planktonic and attached microbial communities in hydrothermal environments.

    Science.gov (United States)

    Yoshida-Takashima, Yukari; Nunoura, Takuro; Kazama, Hiromi; Noguchi, Takuroh; Inoue, Kazuhiro; Akashi, Hironori; Yamanaka, Toshiro; Toki, Tomohiro; Yamamoto, Masahiro; Furushima, Yasuo; Ueno, Yuichiro; Yamamoto, Hiroyuki; Takai, Ken

    2012-03-01

    Viruses play important roles in marine surface ecosystems, but little is known about viral ecology and virus-mediated processes in deep-sea hydrothermal microbial communities. In this study, we examined virus-like particle (VLP) abundances in planktonic and attached microbial communities, which occur in physical and chemical gradients in both deep and shallow submarine hydrothermal environments (mixing waters between hydrothermal fluids and ambient seawater and dense microbial communities attached to chimney surface areas or macrofaunal bodies and colonies). We found that viruses were widely distributed in a variety of hydrothermal microbial habitats, with the exception of the interior parts of hydrothermal chimney structures. The VLP abundance and VLP-to-prokaryote ratio (VPR) in the planktonic habitats increased as the ratio of hydrothermal fluid to mixing water increased. On the other hand, the VLP abundance in attached microbial communities was significantly and positively correlated with the whole prokaryotic abundance; however, the VPRs were always much lower than those for the surrounding hydrothermal waters. This is the first report to show VLP abundance in the attached microbial communities of submarine hydrothermal environments, which presented VPR values significantly lower than those in planktonic microbial communities reported before. These results suggested that viral lifestyles (e.g., lysogenic prevalence) and virus interactions with prokaryotes are significantly different among the planktonic and attached microbial communities that are developing in the submarine hydrothermal environments. PMID:22210205

  20. La avalancha de rocas del cerro Los Cardos (37°10´S,70°53´O) en la región norte de la provincia del Neuquén The rock avalanche of Cerro Los Cardos (37° 10´S, 70° 53´ W) in the northern region of the province of Neuquén

    OpenAIRE

    E.F. González Díaz; Folguera, A.; Hermanns, R.

    2005-01-01

    Se describe una nueva e importante avalancha de rocas, no reconocida hasta ahora, localizada a unos 25 km al oeste de la población de Andacollo. Muestra dos cicatrices o muescas de desprendimiento, de las cuales la austral es interpretada como la muesca principal de su desprendimiento y se halla al pie del borde occidental de una planicie estructural lávica, sobre cuyo extremo norte se ubica el cerro Los Cardos. Es un complejo movimiento, con numerosas escarpas de arranque internas en la masa...

  1. Hydrothermal Vents at 5000m on the Mid-Cayman Rise: The Deepest and Hottest Hydrothermal Systems Yet Discovered!

    Science.gov (United States)

    Murton, B. J.; Connelly, D. P.; Copley, J. T.; Stansfield, K. L.; Tyler, P. A.; Cruise Jc044 Sceintific Party

    2010-12-01

    This contribution describes the geological setting of hydrothermal activity within the Mid- Cayman Rise (MCR) using data acquired during cruise JC044 (MAR-APR 2010) from the deep-towed sidescan sonar TOBI, AUV Autosub6000 and the ROTV HyBIS. The 110 km-long Mid- Cayman Rise (MCR), located within Caribbean Sea, is the deepest spreading centre known, reaching over 6000m. Hence it poses an end-member of extreme depth for hydrothermal circulation. Accretion of new volcanic crust is focused within two ridge segments, to the north and south of a centrally located massif of peridotite and gabbro. Following earlier indications of hydrothermal plumes (German et al., in 2009), we discovered two high-temperature hydrothermal system: one at a depth of 5000m in the neovolcanic zone of the northern segment, and another at 2300m on the flanks of the MCR. These sites show contrasting styles of fluid venting, mineralisation, geological setting and host rock interaction. At 5000m-depth, the ultra-deep vent site forms the deepest hydrothermal system known. Venting is focused at the western side of a 100m diameter, 30m high mound, while inactive sulphides extend eastwards for at least 800m. Fluids discharge from clusters of chimneys whose location is related to basement faults. Changes in salinity in the venting fluids indicate discharge of a low salinity phase and a brine phase. At 500bar, this is definitive evidence for supercritical fluid emission. We also found the sulphide mineralization to be copper-rich, giving a characteristic green hue to many of the deposits, probably a result of the super-critical state of the vent fluids. A prominent axial volcanic ridge nearby indicates a robust magma supply to the northern MCR segment. Thus it is likely the ultra-deep vent site derives its thermal energy from magmatic sources, similar to those thought to underlie other slow-spreading ridge volcanic-hosted vent sites (e.g. Broken Spur: MAR). The shallower (2300m) MCR hydrothermal vent

  2. 76 FR 58649 - Endangered and Threatened Wildlife and Plants; 12-Month Finding on a Petition To List Van Rossem...

    Science.gov (United States)

    2011-09-21

    ... (Cerro Prieto geothermal generation facility) in northeast Baja California. The facility started... also located at inland localities in northeastern Baja California, Mexico (Molina and Garrett 2001, p... Medium McCaskie 1987, p. 1488; Patton 2009, Table 2. Mexico......... Baja California... Campo Geot...

  3. In situ chemical sensing for hydrothermal plume mapping and modeling

    Science.gov (United States)

    Fukuba, T.; Kusunoki, T.; Maeda, Y.; Shitashima, K.; Kyo, M.; Fujii, T.; Noguchi, T.; Sunamura, M.

    2012-12-01

    Detection, monitoring, and mapping of biogeochemical anomalies in seawater such as temperature, salinity, turbidity, oxidation-reduction potential, and pH are essential missions to explore undiscovered hydrothermal sites and to understand distribution and behavior of hydrothermal plumes. Utilization of reliable and useful in situ sensors has been widely accepted as a promised approach to realize a spatiotemporally resolved mapping of anomalies without water sampling operations. Due to remarkable progresses of sensor technologies and its relatives, a number of highly miniaturized and robust chemical sensors have been proposed and developed. We have been developed, evaluated, and operated a compact ISFET (Ion-Sensitive Field-Effect Transistor)-based chemical sensors for ocean environmental sensing purposes. An ISFET has advantages against conventional glass-based electrodes on its faster response, robustness, and potential on miniaturization, and thus variety of chemical sensors has been already on the market. In this study, ISFET-based standalone pH sensors with a solid-state Cl-ISE as a reference electrode were mounted on various platforms and operated to monitor the pH anomalies in deep-sea environment at the Kairei, Edmond, and surrounding hydrothermal sites in the southern Central Indian Ridge area during KH10-06 scientific cruise (Nov. 2010), supported by project TAIGA (Trans-crustal Advection and In situ biogeochemical processes of Global sub-seafloor Aquifer). Up to three pH sensors were mounted on a wire-lined CTD/RMS (Rosette Multiple Sampler), dredge sampler, a series of MTD plankton nets, and VMPS (Vertical Multiple-operating Plankton Sampler). A standalone temperature sensor was bundled and operated with the pH sensor when they were mounted on the dredge sampler, MTD plankton nets, and VMPS. An AUV equipped with the pH sensor was also operated for hydrothermal activity survey operations. As a result of Tow-Yo intersect operations of the CTD

  4. Genome-resolved metagenomics reveals that sulfur metabolism dominates the microbial ecology of rising hydrothermal plumes

    Science.gov (United States)

    Anantharaman, K.; Breier, J. A., Jr.; Jain, S.; Reed, D. C.; Dick, G.

    2015-12-01

    Deep-sea hydrothermal plumes occur when hot fluids from hydrothermal vents replete with chemically reduced elements and compounds like sulfide, methane, hydrogen, ammonia, iron and manganese mix with cold, oxic seawater. Chemosynthetic microbes use these reduced chemicals to power primary production and are pervasive throughout the deep sea, even at sites far removed from hydrothermal vents. Although neutrally-buoyant hydrothermal plumes have been well-studied, rising hydrothermal plumes have received little attention even though they represent an important interface in the deep-sea where microbial metabolism and particle formation processes control the transformation of important elements and impact global biogeochemical cycles. In this study, we used genome-resolved metagenomic analyses and thermodynamic-bioenergetic modeling to study the microbial ecology of rising hydrothermal plumes at five different hydrothermal vents spanning a range of geochemical gradients at the Eastern Lau Spreading Center (ELSC) in the Western Pacific Ocean. Our analyses show that differences in the geochemistry of hydrothermal vents do not manifest in microbial diversity and community composition, both of which display only minor variance across ELSC hydrothermal plumes. Microbial metabolism is dominated by oxidation of reduced sulfur species and supports a diversity of bacteria, archaea and viruses that provide intriguing insights into metabolic plasticity and virus-mediated horizontal gene transfer in the microbial community. The manifestation of sulfur oxidation genes in hydrogen and methane oxidizing organisms hints at metabolic opportunism in deep-sea microbes that would enable them to respond to varying redox conditions in hydrothermal plumes. Finally, we infer that the abundance, diversity and metabolic versatility of microbes associated with sulfur oxidation impart functional redundancy that could allow it to persist in the dynamic settings of hydrothermal plumes.

  5. Crystallization conditions and petrogenesis of the lava dome from the ˜900 years BP eruption of Cerro Machín Volcano, Colombia

    Science.gov (United States)

    Laeger, Kathrin; Halama, Ralf; Hansteen, Thor; Savov, Ivan P.; Murcia, Hugo F.; Cortés, Gloria P.; Garbe-Schönberg, Dieter

    2013-12-01

    The last known eruption at Cerro Machín Volcano (CMV) in the Central Cordillera of Colombia occurred ˜900 years BP and ended with the formation of a dacitic lava dome. The dome rocks contain both normally and reversely zoned plagioclase (An24-54), unzoned and reversely zoned amphiboles of dominantly tschermakite and pargasite/magnesio-hastingsite composition and olivine xenocrysts (Fo = 85-88) with amphibole/clinopyroxene overgrowth, all suggesting interaction with mafic magma at depth. Plagioclase additionally exhibits complex oscillatory zoning patterns reflecting repeated replenishment, fractionation and changes in intrinsic conditions in the magma reservoir. Unzoned amphiboles and cores of the reversely zoned amphiboles give identical crystallization conditions of 910 ± 30 °C and 360 ± 70 MPa, corresponding to a depth of about 13 ± 2 km, at moderately oxidized conditions (f = +0.5 ± 0.2 ΔNNO). The water content in the melt, calculated based on amphibole chemistry, is 7.1 ± 0.4 wt.%. Rims of the reversely zoned amphiboles are relatively enriched in MgO and yield higher crystallization temperatures (T = 970 ± 25 °C), slightly lower melt H2O contents (6.1 ± 0.7 wt.%) and overlapping pressures (410 ± 100 MPa). We suggest that these rims crystallized following an influx of mafic melt into a resident magma reservoir at mid-crustal depths, further supported by the occurrence of xenocrystic olivine. Crystallization of biotite, albite-rich plagioclase and quartz occurred at comparatively low temperatures (probably rock chemistry of the CMV lava dome dacites is homogenous. They have elevated (La/Nb)N ratios of 3.8-4.5, typical for convergent margin magmas, and display several geochemical characteristics of adakites. Both Sr and Nd isotope compositions (87Sr/86Sr ˜0.70497, 143Nd/144Nd ˜0.51267) are among the most radiogenic observed for the Northern Volcanic Zone of the Andes. They are distinct from oceanic crust that has been subducted in the region

  6. Conductivity dependence on synthesis parameters in hydrothermally synthesized ceria nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Anis-ur-Rehman, M., E-mail: marehman@comsats.edu.pk; Saleemi, A.S.; Abdullah, A.

    2013-12-05

    Highlights: •Facile synthesis of CeO{sub 2} with composite mediated hydrothermal method is done. •Synthesis parameters significantly effect on conduction. •Enhanced dc electrical conductivity (0.3386 S cm{sup −1}) is observed at 700 °C. •Better ac conductivity is observed 2.661 S cm{sup −1} at 700 °C for 3 MHz. •Potential material for electrolyte in fuel cells for higher efficiencies. -- Abstract: Nanoparticles of cerium oxide were synthesized by Composite Mediated Hydrothermal Approach (CMHA). The synthesis conditions were optimized to enhance the conduction properties and for narrow range of nanocrystallites. The synthesis parameters like hydrothermal treatment temperature (at 180 °C and 220 °C) and time (for 45 min, 70 min and 90 min) were optimized. The structural properties of the prepared ceria were examined by X-ray diffraction (XRD) data. Scherrer’s formula was used to calculate the crystallite sizes of average and most intense peak. Temperature dependent dc conductivity was measured in temperature range 200–700 °C and found to be increasing with the increase in measuring temperature and controlling the other synthesis conditions. The frequency dependent ac conductivity and dielectric properties were measured in frequency range 20 Hz–3 MHz at different temperatures. The ac conductivity increased (from 0.00091 to 2.661 S cm{sup −1}) with the increase in temperature (from 200 to 700 °C). Raman spectrum was observed for the different bands of cerium oxide and oxygen vacancies at 514 nm excitation laser line.

  7. Pathways for abiotic organic synthesis at submarine hydrothermal fields.

    Science.gov (United States)

    McDermott, Jill M; Seewald, Jeffrey S; German, Christopher R; Sylva, Sean P

    2015-06-23

    Arguments for an abiotic origin of low-molecular weight organic compounds in deep-sea hot springs are compelling owing to implications for the sustenance of deep biosphere microbial communities and their potential role in the origin of life. Theory predicts that warm H2-rich fluids, like those emanating from serpentinizing hydrothermal systems, create a favorable thermodynamic drive for the abiotic generation of organic compounds from inorganic precursors. Here, we constrain two distinct reaction pathways for abiotic organic synthesis in the natural environment at the Von Damm hydrothermal field and delineate spatially where inorganic carbon is converted into bioavailable reduced carbon. We reveal that carbon transformation reactions in a single system can progress over hours, days, and up to thousands of years. Previous studies have suggested that CH4 and higher hydrocarbons in ultramafic hydrothermal systems were dependent on H2 generation during active serpentinization. Rather, our results indicate that CH4 found in vent fluids is formed in H2-rich fluid inclusions, and higher n-alkanes may likely be derived from the same source. This finding implies that, in contrast with current paradigms, these compounds may form independently of actively circulating serpentinizing fluids in ultramafic-influenced systems. Conversely, widespread production of formate by ΣCO2 reduction at Von Damm occurs rapidly during shallow subsurface mixing of the same fluids, which may support anaerobic methanogenesis. Our finding of abiogenic formate in deep-sea hot springs has significant implications for microbial life strategies in the present-day deep biosphere as well as early life on Earth and beyond.

  8. Potential benefits of geothermal electrical production from hydrothermal resources

    Energy Technology Data Exchange (ETDEWEB)

    Bloomster, C.H.; Engel, R.L.

    1976-06-01

    The potential national benefits of geothermal electric energy development from the hydrothermal resources in the West are estimated for several different scenarios. The U.S. electrical economy is simulated by computer using a linear programming optimization technique. Under most of the scenarios, benefits are estimated at $2 to $4 billion over the next 50 years on a discounted present value basis. The electricity production from hydrothermal plants reaches 2 to 4 percent of the national total, which will represent 10 to 20 percent of the installed capacity in the West. Installed geothermal capacity in 1990 is estimated to be 9,000 to 17,000 Mw(e). The geothermal capacity should reach 28,000 to 65,000 Mw(e) by year 2015. The ''most likely'' scenario yields the lower values in the above ranges. Under this scenario geothermal development would save the utility industry $11 billion in capital costs (undiscounted); 32 million separative work units; 64,000 tons of U/sub 3/O/sub 8/; and 700 million barrels of oil. The most favorable scenario for geothermal energy occurs when fossil fuel prices are projected to increase at 5 percent/year. The benefits of geothermal energy then exceed $8 billion on a discounted present value basis. Supply curves were developed for hydrothermal resources based on the recent U.S. Geological Survey (USGS) resource assessment, resource characteristics, and projected power conversion technology and costs. Geothermal plants were selected by the optimizing technique to fill a need for ''light load'' plants. This infers that geothermal plants may be used in the future primarily for load-following purposes.

  9. Lipid Adaptation of Shrimp Rimicaris exoculata in Hydrothermal Vent.

    Science.gov (United States)

    Zhu, Si; Ye, Mengwei; Yan, Xiaojun; Zhou, Yadong; Wang, Chunsheng; Xu, Jilin

    2015-12-01

    The shrimp Rimicaris exoculata is the most abundant species in hydrothermal vents. Lipids, the component of membranes, play an important role in maintaining their function normally in such extreme environments. In order to understand the lipid adaptation of R. exoculata (HV shrimp) to hydrothermal vents, we compared its lipid profile with the coastal shrimp Litopenaeus vannamei (EZ shrimp) which lives in the euphotic zone, using ultra performance liquid chromatography electrospray ionization-quadrupole time-of-flight mass spectrometry. As a result, the following lipid adaptation can be observed. (1) The proportion of 16:1 and 18:1, and non-methylene interrupted fatty acid (48.9 and 6.2 %) in HV shrimp was higher than that in EZ shrimp (12.7 and 0 %). While highly-unsaturated fatty acids were only present in the EZ shrimp. (2) Ceramide and sphingomyelin in the HV shrimp were enriched in d14:1 long chain base (96.5 and 100 %) and unsaturated fatty acids (67.1 and 57.7 %). While in the EZ shrimp, ceramide and sphingomyelin had the tendency to contain d16:1 long chain base (68.7 and 75 %) and saturated fatty acids (100 and 100 %). (3) Triacylglycerol content (1.998 ± 0.005 nmol/mg) in the HV shrimp was higher than that in the EZ shrimp (0.092 ± 0.005 nmol/mg). (4) Phosphatidylinositol and diacylglycerol containing highly-unsaturated fatty acids were absent from the HV shrimp. (5) Lysophosphatidylcholine and lysophosphatidylethanolamine were rarely detected in the HV shrimp. A possible reason for such differences was the result of food resources and inhabiting environments. Therefore, these lipid classes mentioned above may be the biomarkers to compare the organisms from different environments, which will be benefit for the further exploitation of the hydrothermal environment.

  10. Hydrothermal analysis in engineering using control volume finite element method

    CERN Document Server

    Sheikholeslami, Mohsen

    2015-01-01

    Control volume finite element methods (CVFEM) bridge the gap between finite difference and finite element methods, using the advantages of both methods for simulation of multi-physics problems in complex geometries. In Hydrothermal Analysis in Engineering Using Control Volume Finite Element Method, CVFEM is covered in detail and applied to key areas of thermal engineering. Examples, exercises, and extensive references are used to show the use of the technique to model key engineering problems such as heat transfer in nanofluids (to enhance performance and compactness of energy systems),

  11. Hydrothermal plumes over the Carlsberg Ridge, Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, D.; KameshRaju, K.A.; Baker, E.T.; Rao, A.S.; Mudholkar, A.V.; Lupton, J.E.; SuryaPrakash, L.; Gawas, R.B.; VijayaKumar, T.

    Institute, Hyderabad, India [1] Indian Ocean ridges north of the Rodriguez Triple Junction remain poorly explored for seafloor hydrothermal activity, with only two active sites confirmed north of 25°S. We conducted water column surveys and sampling... to the Rainbow and Logatchev fields on the Mid-Atlantic Ridge. 2 1. Introduction [2] The Central Indian, Carlsberg, and Sheba ridges bisect the Indian Ocean from the Rodriguez Triple Junction at 25°S to the entrance of the Gulf of Aden at 15°N...

  12. Hydrothermal plume anomalies along the Central Indian Ridge

    Institute of Scientific and Technical Information of China (English)

    ZHU Jian; LIN Jian; GUO ShiQin; CHEN YongShun

    2008-01-01

    Water column turbidity and temperature were investigated along the Central Indian Ridge (CIR) from 25°19'S to 23°48'S during a December 2005 cruise on board Chinese P/V DayangYihao.Measurements were made using NOAA's MAPR (Miniature Autonomous Plume Recorder) sensors during CTD casts,TV grabber operations,and tow-yo profiles,yielding the following results on hydrothermal plume anomalies:(1) Strong hydrothermal turbidity and temperature anomalies were recorded over the pre-viously discovered Kairei (25°19.2'S,70°02.4'E) and Edmond (23°52.7'S,69°35.8"E) vent fields,with the plume anomalies concentrated at depths of 2150-2300 m and 2700-2900 m,respectively.The maxi-mum height of the turbidity anomalies near the Kairei vent field recorded in December 2005 was slightly below 2100 m,which is consistent with the plume depth measured in June 2001,indicating that the Kairei plume may have maintained its buoyancy flux in the intervening 4.5 years.(2) The water column beneath the Kairei plume has background anomalies of about 0.005△NTU,whereas no such back-ground turbidity anomalies were observed below the Edmond hydrothermal plume.(3) No visible tur-bidity anomalies were detected from 24°42'S to 24°12'S including the Knorr Seamount.Thus 24°12'S marks the southern end of the hydrothermal plume.(4) Significant turbidity anomalies were observed at four individual sections from 24°12'S to 23°56'S at the depth of 2500-3000 m along the eastern rift valley wall.Whether the individual sections of anomalies are connected is still unknown due to the absence of data at the intervening gaps.If the four sections are connected with each other and are linked to the Edmond vent field farther to the north,the total along-axis length of the plume anomaly would be more than 37 km,implying a plume incidence value Ph of 0.38,greater than the predicted Ph of 0.21-0.25 based on the spreading rate of the Central Indian Ridge.

  13. In situ study of hydrothermal MnO2 formation

    DEFF Research Database (Denmark)

    Birgisson, Steinar; Shen, Yanbin; Iversen, Bo Brummerstedt

    -ray diffraction (PXRD) data or total scattering (TS) data. From PXRD data properties such as what crystalline phases are present and their weight fractions, structural parameters (e.g. unit cell parameters, site occupancies, bond lengths), crystallite sizes and morphologies are extracted as a function of reaction...... in supercapacitors and positive electrode material in lithium batteries (both primary and secondary) [4, 5]. In this study we investigate the hydrothermal formation of different phases of MnO2 in situ using the experimental setup described above. Alpha-, beta- and delta-MnO2 are synthesized from different aqueous...

  14. Sulfur Isotope Geochemistry of the Lost City Hydrothermal Vent Fluids

    Science.gov (United States)

    Frueh-Green, G. L.; Bernasconi, S. M.; Butterfield, D. A.; Kelley, D. S.

    2004-12-01

    At the Lost City Hydrothermal Vent Field (Mid-Atlantic Ridge, 30° N), reactions between seawater and ultramafic rocks produce high alkaline (pH 9 to 11) fluids that are venting at temperatures of 40 to 90° C and result in the formation of up to 60m tall carbonate-brucite structures. The fluids are enriched in hydrogen, methane and other hydrocarbons, and support dense microbial communities. We present sulfur isotope data of dissolved sulfate and coexisting sulfide in the fluids venting at Lost City, which together with C-isotope data provide constraints on the links between chemical and biological processes associated with serpentinization. The sulfur isotope composition of sulfate increases from seawater values of +21‰ (VCDT) in fluids with sulfate concentrations of 28 mM to values of up to +30‰ in the low sulfate-, high pH end-member hydrothermal fluids. Sulfide concentrations range between 50 and 2780 micromolar. Sulfur isotope compositions of the sulfides lie in a narrow range of +34 to +37‰ (VCDT) and show no clear correlation with concentrations. The isotopic compositions of dissolved inorganic carbon vary between -0.5‰ (VPDB) in the high sulfate samples and -18‰ in the low sulfate samples. This covariance indicates active sulfate reduction in the vent structures and/or in the shallow serpentinite subsurface. Sulfate reduction likely contributes to the variability of carbon isotope compositions observed in both the dissolved inorganic carbon and the carbonate minerals forming the structures. These data, together with C- and O-isotope data of the vent structures, provide evidence that methane oxidation coupled with sulfate reduction during mixing of the more pristine, hydrogen and methane-rich hydrothermal end-member fluids with seawater is an important process in hydrothermal carbonate precipitation at Lost City. Our results are consistent with previous microbiological and organic geochemical studies, which indicate a close association of methane

  15. Direct synthesis of thermochromic VO2 through hydrothermal reaction

    Science.gov (United States)

    Alie, David; Gedvilas, Lynn; Wang, Zhiwei; Tenent, Robert; Engtrakul, Chaiwat; Yan, Yanfa; Shaheen, Sean E.; Dillon, Anne C.; Ban, Chunmei

    2014-04-01

    Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

  16. Smooth germanium nanowires prepared by a hydrothermal deposition process

    Energy Technology Data Exchange (ETDEWEB)

    Pei, L.Z., E-mail: lzpei1977@163.com [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Zhao, H.S. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Tan, W. [Henkel Huawei Electronics Co. Ltd., Lian' yungang, Jiangsu 222006 (China); Yu, H.Y. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Chen, Y.W. [Department of Materials Science, Fudan University, Shanghai 200433 (China); Fan, C.G. [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China); Zhang, Qian-Feng, E-mail: zhangqf@ahut.edu.cn [School of Materials Science and Engineering, Institute of Molecular Engineering and Applied Chemistry, Key Laboratory of Materials Science and Processing of Anhui Province, Anhui University of Technology, Ma' anshan, Anhui 243002 (China)

    2009-11-15

    Smooth germanium nanowires were prepared using Ge and GeO{sub 2} as the starting materials and Cu sheet as the substrate by a simple hydrothermal deposition process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations show that the germanium nanowires are smooth and straight with uniform diameter of about 150 nm in average and tens of micrometers in length. X-ray diffraction (XRD) and Raman spectrum of the germanium nanowires display that the germanium nanowires are mainly composed of cubic diamond phase. PL spectrum shows a strong blue light emission at 441 nm. The growth mechanism is also discussed.

  17. Hydrothermal Synthesis of Indium Tin Oxide Nanoparticles without Chlorine Contamination

    International Nuclear Information System (INIS)

    Indium tin oxide (In2Sn1-xO5-y) nanoparticles were synthesized by hydrothermal method from stable indium tin acetylacetone complexes and post annealing at 600 .deg. C. The absence of chlorine ions shortened the synthesis process, decreased the particle agglomeration and improved the particle purity. The introduced complexing ligand acetylacetone decreased the obtained nanoparticle size. The improved powder properties accelerated the sintering of the In2Sn1-xO5-y nanoparticles and reached a relative density of 96.4% when pressureless sintered at 1400 .deg. C

  18. Microwave-assisted hydrothermal synthesis of lead zirconate fine powders

    Directory of Open Access Journals (Sweden)

    Apinpus Rujiwatra

    2011-01-01

    Full Text Available A rapid synthesis of lead zirconate fine powders by microwave-assisted hydrothermal technique is reported. The influences of type of lead precursor, concentration of potassium hydroxide mineraliser, applied microwave power and irradiation time are described. The synthesised powders were characterised by powder X-ray diffraction, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopic microanalysis and light scattering technique. The merits of the microwave application in reducing reaction time and improving particle mono-dispersion and size uniformity as well as the drawbacks, viz. low purity of the desired phase and increasing demand of mineraliser, are discussed in relation to conventional heating method.

  19. Splicing growth of zeolite 4A in hydrothermal system

    Institute of Scientific and Technical Information of China (English)

    李酽; 汪信; 杨绪杰; 张术根

    2002-01-01

    The morphology evolution of zeolite 4A in hydrothermal system was studied via XRD, TEM and electron diffractometry. A phenomenon of aggregation of nano-crystals of zeolite 4A exists in the crystallization process, and microcrystals are derived from nano-crystal aggregating directly. The splicing growth model of zeolite 4A is described as: 1)an induction period which exists at the beginning of crystallization, 2)followed by many nano-meter crystals initiating immediately, and 3)the nanocrystals congregated as slices and spliced with each other to form a larger crystal.

  20. Thermal stability of ESR signals in hydrothermal barites

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Fumihiro [Department of Applied Physics, Okayama University of Science, 1-1 Ridai-cho, Kita-ku, Okayama 700-0005 (Japan); Toyoda, Shin, E-mail: toyoda@dap.ous.ac.jp [Department of Applied Physics, Okayama University of Science, 1-1 Ridai-cho, Kita-ku, Okayama 700-0005 (Japan); Banerjee, Debabrata [Department of Applied Physics, Okayama University of Science, 1-1 Ridai-cho, Kita-ku, Okayama 700-0005 (Japan); Planetary Sciences Division, Physical Research Laboratory, Ahmedabad 380009 (India); Ishibashi, Jun-Ichiro [Department of Earth and Planetary Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan)

    2011-09-15

    Thermal stability of the ESR signals from barites in chimneys deposited from hydrothermal vents is investigated using isothermal and isochronal annealing experiments. A combination of first and second order kinetics is required to explain the results. The Arrhenius plots of the decay rate constants give the activation energies of 1.0-1.3 eV. From the estimated decay rate constants at the sea bottom (3 {sup o}C), the decay rate of the signal was calculated to be less than 2% for the period of 20 ka, suggesting the applicability of the ESR method for dating barites up to about twenty thousand years.