WorldWideScience

Sample records for cavity ring-down spectroscopy

  1. Sensitivity limits of continuous wave cavity ring-down spectroscopy.

    Science.gov (United States)

    Huang, Haifeng; Lehmann, Kevin K

    2013-12-19

    An optimized nonlinear least-squares fit algorithm for data processing in cavity ring-down spectroscopy (CRDS) is discussed, which improves the calculation efficiency substantially over using a general purpose fitting package. Theoretical absorption sensitivity limits for both the detector noise and the shot noise limited situations are derived and compared with experimental results. The effect of limiting the bandwidth of detection system on ring-down signal is discussed and compared with real ring-down data. The optimal trigger level and fitting interval are obtained for continuous wave cavity ring-down spectroscopy (cw-CRDS) in both the detector noise and shot noise limits, with the resulting sensitivity in units of cm(-1) per (Hz(1/2)) derived. Interestingly, it is found that the optimized shot noise limited sensitivity in cw-CRDS method is, in principle, comparable with the ultimate sensitivity of noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS). PMID:23978273

  2. Pulsed cavity ring-down spectroscopy in combustion environments

    OpenAIRE

    Evertsen, Rogier

    2002-01-01

    This thesis gives an introduction to pulsed cavity ring-down absorption spectroscopy (CRDS) and its application in combustion research. Experimental results have been compared to numerical simulations, providing a means to validate reaction mechanisms and numerical approaches. Up to now, the application of CRDS in the field of combustion research has mainly been focused on sub-atmospheric flames and quantitative investigations of atmospheric flames have been very limited. Here, it has been ap...

  3. Frequency-Agile Differential Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Reed, Zachary; Hodges, Joseph

    2015-06-01

    The ultimate precision of highly sensitive cavity-enhanced spectroscopic measurements is often limited by interferences (etalons) caused by weak coupled-cavity effects. Differential measurements of ring-down decay constants have previously been demonstrated to largely cancel these effects, but the measurement acquisition rates were relatively low [1,2]. We have previously demonstrated the use of frequency agile rapid scanning cavity ring-down spectroscopy (FARS-CRDS) for acquisition of absorption spectra [3]. Here, the method of rapidly scanned, frequency-agile differential cavity ring-down spectroscopy (FADS-CRDS) is presented for reducing the effect of these interferences and other shot-to-shot statistical variations in measured decay times. To this end, an electro-optic phase modulator (EOM) with a bandwidth of 20 GHz is driven by a microwave source, generating pairs of sidebands on the probe laser. The optical resonator acts as a highly selective optical filter to all laser frequencies except for one tunable sideband. This sideband may be stepped arbitrarily from mode-to-mode of the ring-down cavity, at a rate limited only by the cavity buildup/decay time. The ability to probe any cavity mode across the EOM bandwidth enables a variety of methods for generating differential spectra. The differential mode spacing may be changed, and the effect of this method on suppressing the various coupled-cavity interactions present in the system is discussed. Alternatively, each mode may also be differentially referenced to a single point, providing immunity to temporal variations in the base losses of the cavity while allowing for conventional spectral fitting approaches. Differential measurements of absorption are acquired at 3.3 kHz and a minimum detectable absorption coefficient of 5 x10-12 cm-1 in 1 s averaging time is achieved. 1. J. Courtois, K. Bielska, and J.T Hodges J. Opt. Soc. Am. B, 30, 1486-1495, 2013 2. H.F. Huang and K.K. Lehmann App. Optics 49, 1378

  4. Doppler broadening thermometry based on cavity ring-down spectroscopy

    CERN Document Server

    Cheng, C -F; Sun, Y R; Tan, Y; Kang, P; Hu, S -M

    2015-01-01

    A Doppler broadening thermometry (DBT) instrument is built based on cavity ring-down spectroscopy (CRDS) for precise determination of the Boltzmann constant. Compared with conventional direct absorption methods, the high-sensitivity of CRDS allows to reach a satisfied precision at lower sample pressures, which also reduces the influence due to collisions. By recording the spectrum of C$_2$H$_2$ at 787 nm, we demonstrate a statistical uncertainty of 6 ppm (part per million) in the determined linewidth values by several hours' measurement at a sample pressure of 1.5 Pa. The influence on the spectroscopy-determined temperatures has been investigated, including the "hidden" weak lines overlapped with the selected transition for DBT measurements. The reproducibility has also been examined to be better than 10 ppm, and it indicates that the instrument is feasible for DBT measurement toward a precision at the ppm level.

  5. Use of laser diodes in cavity ring-down spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zare, R.N.; Paldus, B.A.; Ma, Y.; Xie, J. [Stanford Univ., CA (United States)

    1997-12-31

    We have demonstrated that cavity ring-down spectroscopy (CRDS), a highly sensitive absorption technique, is versatile enough to serve as a complete diagnostic for materials process control. In particular, we have used CRDS in the ultraviolet to determine the concentration profile of methyl radicals in a hot-filament diamond reactor; we have applied CRDS in the mid-infrared to detect 50 ppb of methane in a N{sub 2} environment; and, we have extended CRDS so that we can use continuous-wave diode laser sources. Using a laser diode at 810 nm, we were able to achieve a sensitivity of 2 x 10{sup -8} cm{sup -1}. Thus, CRDS can be used not only as an in situ diagnostic for investigating the chemistry of diamond film deposition, but it can also be used as a gas purity diagnostic for any chemical vapor deposition system.

  6. Cavity ring down spectroscopy with a free-electron laser

    NARCIS (Netherlands)

    Engeln, R.; van den Berg, E.; Meijer, G.; Lin, L.; Knippels, G.M.H.; van der Meer, A. F. G.

    1997-01-01

    A cavity ring down (CRD) absorption experiment is performed with a free-electron laser (FEL) operating in the 10-11 mu m region. A short infrared pulse of approximately 20 ns, sliced from the much longer FEL pulse, is used to measure CRD spectra of ethylene in two different ways. First, ''

  7. A Cavity Ring-Down Spectroscopy Mercury Continuous Emission Monitor

    Energy Technology Data Exchange (ETDEWEB)

    Christopher C. Carter

    2004-12-15

    The Sensor Research & Development Corporation (SRD) has undertaken the development of a Continuous Emissions Monitor (CEM) for mercury based on the technique of Cavity Ring-Down Spectroscopy (CRD). The project involved building an instrument for the detection of trace levels of mercury in the flue gas emissions from coal-fired power plants. The project has occurred over two phases. The first phase concentrated on the development of the ringdown cavity and the actual detection of mercury. The second phase dealt with the construction and integration of the sampling system, used to carry the sample from the flue stack to the CRD cavity, into the overall CRD instrument. The project incorporated a Pulsed Alexandrite Laser (PAL) system from Light Age Incorporated as the source to produce the desired narrow band 254 nm ultra-violet (UV) radiation. This laser system was seeded with a diode laser to bring the linewidth of the output beam from about 150 GHz to less than 60 MHz for the fundamental beam. Through a variety of non-linear optics the 761 nm fundamental beam is converted into the 254 nm beam needed for mercury detection. Detection of the mercury transition was verified by the identification of the characteristic natural isotopic structure observed at lower cavity pressures. The five characteristic peaks, due to both natural isotopic abundance and hyperfine splitting, provided a unique identifier for mercury. SRD scientists were able to detect mercury in air down below 10 parts-per-trillion by volume (pptr). This value is dependent on the pressure and temperature within the CRD cavity at the time of detection. Sulfur dioxide (SO{sub 2}) absorbs UV radiation in the same spectral region as mercury, which is a significant problem for most mercury detection equipment. However, SRD has not only been able to determine accurate mercury concentrations in the presence of SO{sub 2}, but the CRD instrument can in fact determine the SO{sub 2} concentration as well. Detection of

  8. A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR

    Energy Technology Data Exchange (ETDEWEB)

    Christopher C. Carter

    2002-12-31

    SRD tested a number of different length cavities during this past quarter. Continuous transmission was observed with cavity lengths from 65 to 12 cm. The 65 cm cavity was replaced with a 39 cm cavity for work performed during this quarter. Flue gas components were tested for background absorptions and any interference with the determination of accurate mercury concentrations. Sulfur dioxide was found to absorb fairly strongly in the region of the mercury transition, but the Cavity Ring-Down (CRD) instrument was still able to detect mercury at subparts-per-billion by volume (ppb) levels. Additional flue gases tested included H{sub 2}O, CO, CO{sub 2}, NO, NO{sub 2}. None of these flue gas constituents showed any observable absorption in the ultraviolet region near the atomic mercury transition. Work was also initiated in speciation studies. In particular mercury chloride (HgCl{sub 2}) was tested. A mercury signal was detected from a gas stream containing HgCl{sub 2}. SRD was not able to determine definitively if there exists a spectral shift great enough to separate HgCl{sub 2} from elemental mercury in these initial tests.

  9. Dual-etalon, cavity-ring-down, frequency comb spectroscopy.

    Energy Technology Data Exchange (ETDEWEB)

    Strecker, Kevin E.; Chandler, David W.

    2010-10-01

    The 'dual etalon frequency comb spectrometer' is a novel low cost spectometer with limited moving parts. A broad band light source (pulsed laser, LED, lamp ...) is split into two beam paths. One travels through an etalon and a sample gas, while the second arm is just an etalon cavity, and the two beams are recombined onto a single detector. If the free spectral ranges (FSR) of the two cavities are not identical, the intensity pattern at the detector with consist of a series of heterodyne frequencies. Each mode out of the sample arm etalon with have a unique frequency in RF (radio-frequency) range, where modern electronics can easily record the signals. By monitoring these RF beat frequencies we can then determine when an optical frequencies is absorbed. The resolution is set by the FSR of the cavity, typically 10 MHz, with a bandwidth up to 100s of cm{sup -1}. In this report, the new spectrometer is described in detail and demonstration experiments on Iodine absorption are carried out. Further we discuss powerful potential next generation steps to developing this into a point sensor for monitoring combustion by-products, environmental pollutants, and warfare agents.

  10. Measurement of OH Radicals in Dielectric Barrier Discharge Plasmas by Cavity Ring-Down Spectroscopy

    International Nuclear Information System (INIS)

    Near-infrared continuous wave cavity ring-down spectroscopy was applied to measure the OH radicals in dielectric barrier discharge plasmas, which play an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non-thermal plasmas. The P-branches of OH X2Πi ν = 2 <- ν = 0) bands were used for number density measurements. The OH number density and plasma temperature were determined for different applied voltages, gas pressures and concentrations of both oxygen and water. The temporal evolution of the OH number density was obtained by using the 'time window' method, which was used to extract individual ring-down times at different times in a half period of the sine wave applied voltage in dielectric barrier discharge plasmas.

  11. Time resolved super continuum Cavity Ring-Down Spectroscopy for multicomponent gas detection

    International Nuclear Information System (INIS)

    In this work, we present a variation of the technique CRDS (Cavity Ring-Down Spectroscopy) to obtain simultaneously a multicomponent absorption spectrum in a broad visible range. This new approach uses the Supercontinuum (SC) spectrum (resulting from irradiation of nonlinear media by femtosecond lasers, or simply generated by compact sources) as a light source to illuminate the cavity. In this context it is described the features of the modules assembling a MC-SC-CRDS (Multicomponent Supercontinuum Cavity Ring-Down Spectroscopy): a set of high reflectivity mirrors, the resonant cavity and the detection system. Some problems related to the multimode excitation, stray light, effective use of the dynamic range of the detector, the poor resolution of the instrument to resolve narrow absorption lines are issued. We present the absorption spectra of H2O (polyads 4υ, 4υ + δ) and O2 (spin-forbidden b-X branch) measured simultaneously by this technique in the visible range and a comparison with the absorption lines based on HITRAN database is made to demonstrate the functionality of this method. (author)

  12. Hollow-core fiber based linear cavity ring-down spectroscopy for gaseous oxygen detection

    Science.gov (United States)

    Munzke, Dorit; Böhm, Michael; Reich, Oliver

    2014-05-01

    We present a spectroscopic technique that combines the benefits of cavity ring-down spectroscopy and a hollowcore photonic crystal fiber. The 10m fiber is placed inside an optical cavity and acts both as the sample cell (volume = 442 nL) and as a waveguide. Due to the high reflectivity of the cavity mirrors and rather small coupling losses, the effective optical path length can be increased up to 70m. Therefore, as a figure of merit the volume per optical interaction path length is calculated to 6.3 nL m-1. Oxygen detection is performed at 760 nm while scanning across an absorption line. The optical loss due to sample absorption is determined by measuring the ring-down time of light traveling inside the cavity. Results are compared to HITRAN database showing a discrepancy of only 2.5% of the absorption coefficient. This method is of interest for applications that require sensitive measurements on sample volumes of few nanoliters to microliters without the need of calibration.

  13. Miniature chemical sensor combining molecular recognition with evanescent wave cavity ring-down spectroscopy

    International Nuclear Information System (INIS)

    A new chemical detection technology has been realized that addresses DOE environmental management needs. The new technology is based on a variant of the sensitive optical absorption technique, cavity ring-down spectroscopy (CRDS). Termed evanescent-wave cavity ring-down spectroscopy (EW-CRDS), the technology employs a miniature solid-state optical resonator having an extremely high Q-factor as the sensing element, where the high-Q is achieved by using ultra-low-attenuation optical materials, ultra-smooth surfaces, and ultra-high reflectivity coatings, as well as low-diffraction-loss designs. At least one total-internal reflection (TIR) mirror is integral to the resonator permitting the concomitant evanescent wave to probe the ambient environment. Several prototypes have been designed, fabricated, characterized, and applied to chemical detection. Moreover, extensions of the sensing concept have been explored to enhance selectivity, sensitivity, and range of application. Operating primarily in the visible and near IR regions, the technology inherently enables remote detection by optical fiber. Producing 11 archival publications, 5 patents, 19 invited talks, 4 conference proceedings, a CRADA, and a patent-license agreement, the project has realized a new chemical detection technology providing >100 times more sensitivity than comparable technologies, while also providing practical advantages

  14. Miniature Chemical Sensor combining Molecular Recognition with Evanescent Wave Cavity Ring-Down Spectroscopy

    International Nuclear Information System (INIS)

    To address the chemical sensing needs of DOE, a new class of chemical sensors is being developed that enables qualitative and quantitative, remote, real-time, optical diagnostics of chemical species in hazardous gas, liquid, and semi-solid phases by employing evanescent wave cavity ring-down spectroscopy (EW-CRDS). The feasibility and sensitivity of EW-CRDS was demonstrated previously under Project No.60231. The objective of this project is to enhance the selectivity and domain of application of EW-CRDS. Selectivity is enhanced by using molecular recognition (MR) chemistry and polarized ''fingerprint'' near-IR spectroscopy, while the domain of application is expanded by combining EW-CRDS with the unique optical properties of nanoparticles and by extending the technique to liquids

  15. Toward a real-time measurement of atmospheric mercury concentrations using cavity ring-down spectroscopy

    Directory of Open Access Journals (Sweden)

    X. Faïn

    2009-10-01

    Full Text Available A new sensor based on cavity ring-down spectroscopy (CRDS has been developed for the measurement of gaseous elemental mercury (Hg0 mass concentration with sub-ng m−3 detection limit and high temporal resolution. Cavity ring-down spectroscopy is a direct absorption technique that utilizes path lengths of up to multiple kilometers in a compact absorption cell and has a significantly higher sensitivity than conventional absorption spectroscopy. Our prototype uses a frequency-doubled, tuneable dye laser emitting pulses at ~253.65 nm with a pulse repetition frequency of 50 Hz. The dye laser incorporates a unique piezo element attached to its tuning grating allowing it to tune the laser on and off the Hg0 absorption line on a pulse to pulse basis to facilitate differential absorption measurements. Hg0 absorption measurements with this CRDS laboratory prototype are highly linearly related to Hg0 concentrations determined by a Tekran 2537B analyzer over a Hg0 concentration range of four orders of magnitude, from 0.2 ng m−3 to 573 ng m−3 implying excellent linearity of both instruments. The current CRDS instrument has a~sensitivity of 0.10 ng m−3 at 10 s time resolution. This tool opens new prospects for the study of Hg0 because of its high temporal resolution and reduced limited sample volume requirements (<0.5 l of sample air. Future applications may include ambient Hg0 flux measurements with eddy covariance techniques, which require measurements of Hg0 concentrations with sub-ng m−3 sensitivity and sub-second time resolution.

  16. Double resonant absorption measurement of acetylene symmetric vibrational states probed with cavity ring down spectroscopy

    CERN Document Server

    Karhu, J; Vainio, M; Metsälä, M; Hoekstra, S; Halonen, L

    2016-01-01

    A novel mid-infrared/near-infrared double resonant absorption setup for studying infrared-inactive vibrational states is presented. A strong vibrational transition in the mid-infrared region is excited using an idler beam from a singly resonant continuous-wave optical parametric oscillator, to populate an intermediate vibrational state. High output power of the optical parametric oscillator and the strength of the mid-infrared transition result in efficient population transfer to the intermediate state, which allows measuring secondary transitions from this state with a high signal-to-noise ratio. A secondary, near-infrared transition from the intermediate state is probed using cavity ring down spectroscopy, which provides high sensitivity in this wavelength region. Due to the narrow linewidths of the excitation sources, the rovibrational lines of the secondary transition are measured with sub-Doppler resolution. The setup is used to access a previously unreported symmetric vibrational state of acetylene, $\

  17. Design of a cavity ring-down spectroscopy diagnostic for negative ion rf source SPIDER

    Energy Technology Data Exchange (ETDEWEB)

    Pasqualotto, R.; Alfier, A.; Lotto, L. [Consorzio RFX-Associazione Euratom-Enea sulla Fusione, corso Stati Uniti 4, I-35127 Padova (Italy)

    2010-10-15

    The rf source test facility SPIDER will test and optimize the source of the 1 MV neutral beam injection systems for ITER. Cavity ring-down spectroscopy (CRDS) will measure the absolute line-of-sight integrated density of negative (H{sup -} and D{sup -}) ions, produced in the extraction region of the source. CRDS takes advantage of the photodetachment process: negative ions are converted to neutral hydrogen atoms by electron stripping through absorption of a photon from a laser. The design of this diagnostic is presented with the corresponding simulation of the expected performance. A prototype operated without plasma has provided CRDS reference signals, design validation, and results concerning the signal-to-noise ratio.

  18. Birefringence-induced frequency beating in high-finesse cavities by continuous-wave cavity ring-down spectroscopy

    Science.gov (United States)

    Dupré, Patrick

    2015-11-01

    By analyzing the decaying intensity, leaking out a high-finesse cavity previously "filled" by a cw laser source (using the cavity ring-down spectroscopy technique), we observed frequency beating between what we think are two orthogonal eigenpolarization states of the intracavity electromagnetic field. The time decay (ring down) is analyzed by varying the angle of the polarization analyzer located in front of the detector. A full modeling of the observed signal is proposed. It is based on the Jones matrix formalism required for modeling the cavity behavior following a rotated phase shifter. The full transfer function is first established in the frequency domain, and then Fourier transformed to recover the temporal response. The same optical cavity, i.e., constituted of the same set of mirrors, is used at two different wavelengths (˜800 and ˜880 nm). It demonstrates the differences in behavior between a high-finesse cavity (˜400 000 ) and a lower finesse cavity (˜50 000 ). Beating frequency, characteristics time, and beat amplitude are mainly discussed versus the analyzer angle. A cavity birefringence of ˜1.6 ×10-5 rad, resulting from the mirror birefringence is suggested. If the current analysis is in agreement with pulsed CRDS experiments (polarimetry) obtained in an isotropic moderate-finesse cavity, it differs from a recent work report on a high-finesse cavity associated with a source mode locking [Phys. Rev. A 85, 013837 (2012), 10.1103/PhysRevA.85.013837].

  19. Development of a pulsed laser with emission at 1053 nm for Cavity Ring-Down Spectroscopy

    International Nuclear Information System (INIS)

    In this work, a pulsed and Q-switched laser resonator was developed using the double-beam mode-controlling technique. A Nd:LiYF4 crystal with 0,8mol% of doping concentration was used to generate a giant pulse with duration of 5,5 ns (FWHM), 1,2 mJ of energy and 220 kW peak power for the Cavity Ring-Down Spectroscopy (CRDS) technique. The CRDS technique is used to measure absorption spectra for gases, liquids and solids. With the CRDS technique it is possible to measure losses with high degree of accuracy, underscoring the sensitivity that is confirmed by the use of mirrors with high reflectivity. With this technique, the losses by reflection and scattering of transparent materials were evaluated. By calibrating the resonant cavity, it was possible to measure the losses in the samples with resolution of 0,045%, the maximum being reached by 0,18%. The calibration was possible because there was obtained to measure a decay time of approximately 20 μs with the empty cavity. Besides was obtained a method for determining the refractive index of transparent materials with accuracy of five decimals. (author)

  20. Novel use of cavity ring-down spectroscopy to investigate aquatic carbon cycling from microbial to ecosystem scales

    NARCIS (Netherlands)

    Maher, D.T.; Santos, I.S.; Leuven, J.R.F.W.; Oakes, J.M.; Erler, D.V.; Carvalho, M.C.; Eyre, B.D.

    2013-01-01

    Development of cavity ring-down spectroscopy (CRDS) has enabled real-time monitoring of carbon stable isotope ratios of carbon dioxide and methane in air. Here we demonstrate that CRDS can be adapted to assess aquatic carbon cycling processes from microbial to ecosystem scales. We first measured in

  1. Open-path cavity ring-down spectroscopy sensor for atmospheric ammonia

    Science.gov (United States)

    Shadman, Soran; Rose, Charles; Yalin, Azer P.

    2016-07-01

    An open-path cavity ring-down spectroscopy (CRDS) sensor has been developed for measurement of atmospheric ammonia (NH3) and represents the first use of open-path CRDS in the mid-infrared region. The sensor uses a continuous-wave distributed feedback quantum cascade laser at 10.33 μm to target strong absorption features. The optical cavity is constructed with two high-reflectivity mirrors ( R = 0.9995). The open-path configuration removes inlet effects, which are very challenging for closed-path instruments, and can be enabling for compact, low-power designs. Sensor performance was validated in the laboratory by measuring known concentrations in a closed-path configuration. The open-path configuration was validated by comparison against a commercial closed-path CRDS instrument for outdoor measurements at a small feed lot. Ammonia concentrations from the two instruments showed good agreement with slope of 0.990 ( R 2 = 0.92), for 5-min averages. The precision of the open-path instrument was found from Allan variance studies as 1.2 ppb (2-σ) for 3-s measurement durations.

  2. Cavity ring-down spectroscopy sensor for detection of hydrogen chloride

    Directory of Open Access Journals (Sweden)

    C. L. Hagen

    2013-08-01

    Full Text Available A laser-based cavity ring-down spectroscopy (CRDS sensor for measurement of hydrogen chloride (HCl has been developed and characterized. The instrument uses light from a distributed-feedback diode laser at 1742 nm coupled to a high finesse optical cavity to make sensitive and quantifiable concentration measurements of HCl based on optical absorption. The instrument has a (1σ limit of detection of < 20 pptv in 1 min and has high specificity to HCl. The measurement response time to changes in input HCl concentration is < 15 s. Validation studies with a previously calibrated permeation tube setup show an accuracy of better than 10%. The CRDS sensor was preliminarily tested in the field with two other HCl instruments (mist chamber and chemical ionization mass spectrometry, all of which were in broad agreement. The mist chamber and CRDS sensors both showed a 400 pptv plume within 50 pptv agreement. The sensor also allows simultaneous sensitive measurements of water and methane, and minimal hardware modification would allow detection of other near-infrared absorbers.

  3. Radiocarbon Dioxide detection based on Cavity Ring-Down Spectroscopy and a Quantum Cascade Laser

    CERN Document Server

    Genoud, Guillaume; Phillips, Hilary; Dean, Julian; Merimaa, Mikko

    2015-01-01

    Monitoring of radiocarbon ($^{14}$C) in carbon dioxide is demonstrated using mid-infrared spectroscopy and a quantum cascade laser. The measurement is based on cavity ring-down spectroscopy, and a high sensitivity is achieved with a simple setup. The instrument was tested using a standardised sample containing elevated levels of radiocarbon. Radiocarbon dioxide could be detected from samples with an isotopic ratio $^{14}$C/C as low as 50 parts-per-trillion, corresponding to an activity of 5 kBq/m$^3$ in pure CO$_2$, or 2 Bq/m$^3$ in air after extraction of the CO$_2$ from an air sample. The instrument is simple, compact and robust, making it the ideal tool for on-site measurements. It is aimed for monitoring of radioactive gaseous emissions in nuclear power environment, during the operation and decommissioning of nuclear power plants. Its high sensitivity also makes it the ideal tool for the detection of leaks in radioactive waste repositories.

  4. Investigation on an evanescent wave fiber-optic absorption sensor based on fiber loop cavity ring-down spectroscopy

    Science.gov (United States)

    Jiang, Meng; Zhang, Weigang; Zhang, Qi; Liu, Yaping; Liu, Bo

    2010-01-01

    An improved ring-down measurement principle for optical waveguides is presented. Fiber loop ring-down spectroscopy allows for measurement of minute optical losses in high-finesse fiber-optic cavities and immunity to the fluctuation of laser source. The evanescent wave absorption losses dependent on the absorption and the refractive index of ambient solution have been theoretically analyzed. The complex refractive index is introduced into our model and extinction coefficient can be calculated accurately through finite element analysis by setting the boundaries of the fiber and the ambient conditions. Using this method, the refractive index of environment can be taken into consideration. Our principle is validated by the highly-sensitive measurement of evanescent wave absorption loss. By chemically processing the surface of sensing segment along an extending ring-down cavity, the concentration of small volume Diethyl Sulphoxide solution where the etched fiber immersed into has been successfully measured and discussed.

  5. Note: A very simple circuit for piezo actuator pseudo-tracking for continuous-wave cavity ring-down spectroscopy.

    Science.gov (United States)

    Földes, T

    2013-01-01

    A very simple circuit for pseudo-tracking of the piezo actuator for continuous-wave cavity ring-down spectroscopy (cw-CRDS) is presented. The circuit is based on an ordinary positive-edge trigger D-type flip flop integrated circuit, has a low parts count, and can be easily assembled using only off the shelf components. The circuit can be straightforwardly incorporated into most cw-CRDS setups and, thanks to the increased ring-down event rate, higher sensitivity or lower data acquisition time can be achieved.

  6. Liquid-phase and evanescent-wave cavity ring-down spectroscopy in analytical chemistry.

    Science.gov (United States)

    van der Sneppen, L; Ariese, F; Gooijer, C; Ubachs, W

    2009-01-01

    Due to its simplicity, versatility, and straightforward interpretation into absolute concentrations, molecular absorbance detection is widely used in liquid-phase analytical chemistry. Because this method is inherently less sensitive than zero-background techniques such as fluorescence detection, alternative, more sensitive measurement principles are being explored. This review discusses one of these: cavity ring-down spectroscopy (CRDS). Advantages of this technique include its long measurement pathlength and its insensitivity to light-source-intensity fluctuations. CRDS is already a well-established technique in the gas phase, so we focus on two new modes: liquid-phase CRDS and evanescent-wave (EW)-CRDS. Applications of liquid-phase CRDS in analytical chemistry focus on improving the sensitivity of absorbance detection in liquid chromatography. Currently, EW-CRDS is still in early stages: It is used to study basic interactions between molecules and silica surfaces. However, in the future this method may be used to develop, for instance, biosensors with high specificity. PMID:20636052

  7. Cavity Ring-Down Spectroscopy for Gaseous Fission Products Trace Measurements in Sodium Fast Reactors

    International Nuclear Information System (INIS)

    Safety and availability are key issues of the generation IV reactors. Hence, the three radionuclide confinement barriers, including fuel cladding, must stay tight during the reactor operation. During the primary gaseous failure, fission products xenon and krypton are released. Their fast and sensitive detection guarantees the first confinement barrier tightness. In the frame of the French ASTRID project, an optical spectroscopy technique - Cavity Ring Down Spectroscopy (CRDS) - is investigated for the gaseous fission products measurement. A dedicated CRDS set-up is needed to detect the rare gases with a commercial laser. Indeed, the CRDS is coupled to a glow discharge plasma, which generates a population of metastable atoms. The xenon plasma conditions are optimized to 110 Pa and 1.3 W (3 mA). The production efficiency of metastable Xe is then 0.8 %, stable within 0.5% during hours. The metastable number density is proportional to the xenon over argon molar fraction. The spectroscopic parameters of the strong 823.16 nm xenon transition are calculated and/or measured in order to optimize the fit of the experimental spectra and make a quantitative measurement of the metastable xenon. The CRDS is coupled to the discharge cell. The laser intensity inside the cavity is limited by the optical saturation process, resulting from the strong optical pumping of the metastable state. The resulting weak CRDS signal requires a fast and very sensitive photodetector. A 600 ppt xenon molar fraction was measured by CRDS. With the present set-up, the detection limits are estimated from the baseline noise to approximately 20 ppt for each even isotope, 60 ppt for the 131Xe and 55 ppt for the 129Xe. This sensitivity matches the specifications required for gaseous leak measurement; approximately 100 ppt for 133Xe (4 GBq/m3) and 10 ppb for stable isotopes. The odd isotopes are selectively measured, whereas the even isotopes overlap, a spectroscopic feature that applies for stable or

  8. Chemical Sensing Using Infrared Cavity Enhanced Spectroscopy: Short Wave Infrared Cavity Ring Down Spectroscopy (SWIR CRDS) Sensor

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Richard M.; Harper, Warren W.; Aker, Pam M.; Thompson, Jason S.; Stewart, Timothy L.

    2003-10-01

    The principal goal of Pacific Northwest National Laboratory's (PNNL's) Remote Spectroscopy Project is to explore and develop the science and technology behind point and stand off infrared (IR) spectroscopic chemical sensors that are needed for detecting weapons proliferation activity and countering terrorism. Missions addressed include detecting chemical, biological, and nuclear weapons and their production; counter terrorism measures that involve screening luggage, personnel, and shipping containers for explosives, firearms, narcotics, chemical weapons and/or their residues; and mapping of contaminated areas. The science and technology developed in this program is dual use in that it additionally supports progress in a diverse set of agendas that include chemical weapons defense programs, air operations activities, emissions monitoring, law enforcement, and medical diagnostics. Sensors for these missions require extremely low limits of detection because many of the targeted signature species are either present in low concentrations or have extremely low vapor pressures. The sensors also need to be highly selective as the environments that they will be operated in will contain a variety of interferent species and false positive detection is not an option. PNNL has been working on developing a class of sensors that draw vapor into optical cavities and use laser-based spectroscopy to identify and quantify the vapor chemical content. The cavity enhanced spectroscopies (CES) afford extreme sensitivity, excellent selectivity, noise immunity, and rapid, real-time, in-situ chemical characterization. PNNL's CES program is currently focused on developing two types of sensors. The first one, which is based on cavity ring down spectroscopy (CRDS), uses short wave infrared (SWIR) lasers to interrogate species. The second sensor, which is based on noise immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE OHMS), uses long wave infrared (LWIR

  9. Double resonant absorption measurement of acetylene symmetric vibrational states probed with cavity ring down spectroscopy

    Science.gov (United States)

    Karhu, J.; Nauta, J.; Vainio, M.; Metsälä, M.; Hoekstra, S.; Halonen, L.

    2016-06-01

    A novel mid-infrared/near-infrared double resonant absorption setup for studying infrared-inactive vibrational states is presented. A strong vibrational transition in the mid-infrared region is excited using an idler beam from a singly resonant continuous-wave optical parametric oscillator, to populate an intermediate vibrational state. High output power of the optical parametric oscillator and the strength of the mid-infrared transition result in efficient population transfer to the intermediate state, which allows measuring secondary transitions from this state with a high signal-to-noise ratio. A secondary, near-infrared transition from the intermediate state is probed using cavity ring-down spectroscopy, which provides high sensitivity in this wavelength region. Due to the narrow linewidths of the excitation sources, the rovibrational lines of the secondary transition are measured with sub-Doppler resolution. The setup is used to access a previously unreported symmetric vibrational state of acetylene, ν 1 + ν 2 + ν 3 + ν4 1 + ν5 - 1 in the normal mode notation. Single-photon transitions to this state from the vibrational ground state are forbidden. Ten lines of the newly measured state are observed and fitted with the linear least-squares method to extract the band parameters. The vibrational term value was measured to be at 9775.0018(45) cm-1, the rotational parameter B was 1.162 222(37) cm-1, and the quartic centrifugal distortion parameter D was 3.998(62) × 10-6 cm-1, where the numbers in the parenthesis are one-standard errors in the least significant digits.

  10. Dual-etalon cavity ring-down frequency-comb spectroscopy with broad band light source

    Science.gov (United States)

    Chandler, David W; Strecker, Kevin E

    2014-04-01

    In an embodiment, a dual-etalon cavity-ring-down frequency-comb spectrometer system is described. A broad band light source is split into two beams. One beam travels through a first etalon and a sample under test, while the other beam travels through a second etalon, and the two beams are recombined onto a single detector. If the free spectral ranges ("FSR") of the two etalons are not identical, the interference pattern at the detector will consist of a series of beat frequencies. By monitoring these beat frequencies, optical frequencies where light is absorbed may be determined.

  11. Toward real-time measurement of atmospheric mercury concentrations using cavity ring-down spectroscopy

    Directory of Open Access Journals (Sweden)

    X. Faïn

    2010-03-01

    Full Text Available Cavity ring-down spectroscopy (CRDS is a direct absorption technique that utilizes path lengths up to multiple kilometers in a compact absorption cell and has a significantly higher sensitivity than conventional absorption spectroscopy. This tool opens new prospects for study of gaseous elemental mercury (Hg0 because of its high temporal resolution and reduced sample volume requirements (<0.5 l of sample air. We developed a new sensor based on CRDS for measurement of (Hg0 mass concentration. Sensor characteristics include sub-ng m−3 detection limit and high temporal resolution using a frequency-doubled, tuneable dye laser emitting pulses at ~253.65 nm with a pulse repetition frequency of 50 Hz. The dye laser incorporates a unique piezo element attached to its tuning grating allowing it to tune the laser on and off the Hg0 absorption line on a pulse-to-pulse basis to facilitate differential absorption measurements. Hg0 absorption measurements with this CRDS laboratory prototype are highly linearly related to Hg0 concentrations determined by a Tekran 2537B analyzer over an Hg0 concentration range from 0.2 ng m−3 to 573 ng m−3, implying excellent linearity of both instruments. The current CRDS instrument has a sensitivity of 0.10 ng Hg0 m−3 at 10-s time resolution. Ambient-air tests showed that background Hg0 levels can be detected at low temporal resolution (i.e., 1 s, but also highlight a need for high-frequency (i.e., pulse-to-pulse differential on/off-line tuning of the laser wavelength to account for instabilities of the CRDS system and variable background absorption interferences. Future applications may include ambient Hg0 flux measurements with eddy covariance techniques, which require measurements of Hg0 concentrations with sub-ng m−3 sensitivity and sub-second time

  12. Eddy covariance flux measurements of gaseous elemental mercury using cavity ring-down spectroscopy.

    Science.gov (United States)

    Pierce, Ashley M; Moore, Christopher W; Wohlfahrt, Georg; Hörtnagl, Lukas; Kljun, Natascha; Obrist, Daniel

    2015-02-01

    A newly developed pulsed cavity ring-down spectroscopy (CRDS) system for measuring atmospheric gaseous elemental mercury (GEM) concentrations at high temporal resolution (25 Hz) was used to successfully conduct the first eddy covariance (EC) flux measurements of GEM. GEM is the main gaseous atmospheric form, and quantification of bidirectional exchange between the Earth's surface and the atmosphere is important because gas exchange is important on a global scale. For example, surface GEM emissions from natural sources, legacy emissions, and re-emission of previously deposited anthropogenic pollution may exceed direct primary anthropogenic emissions. Using the EC technique for flux measurements requires subsecond measurements, which so far has not been feasible because of the slow time response of available instrumentation. The CRDS system measured GEM fluxes, which were compared to fluxes measured with the modified Bowen ratio (MBR) and a dynamic flux chamber (DFC). Measurements took place near Reno, NV, in September and October 2012 encompassing natural, low-mercury (Hg) background soils and Hg-enriched soils. During nine days of measurements with deployment of Hg-enriched soil in boxes within 60 m upwind of the EC tower, the covariance of GEM concentration and vertical wind speed was measured, showing that EC fluxes over an Hg-enriched area were detectable. During three separate days of flux measurements over background soils (without Hg-enriched soils), no covariance was detected, indicating fluxes below the detection limit. When fluxes were measurable, they strongly correlated with wind direction; the highest fluxes occurred when winds originated from the Hg-enriched area. Comparisons among the three methods showed good agreement in direction (e.g., emission or deposition) and magnitude, especially when measured fluxes originated within the Hg-enriched soil area. EC fluxes averaged 849 ng m(-2) h(-1), compared to DFC fluxes of 1105 ng m(-2) h(-1) and MBR fluxes

  13. Cavity Ring-down Spectroscopic System And Method

    KAUST Repository

    Alquaity, Awad Bin Saud

    2015-05-14

    A system and method for cavity ring-down spectroscopy can include a pulsed quantum cascade laser, an optical ring-down cavity, a photodetector, and an oscilloscope. The system and method can produce pulse widths of less than 200 ns with bandwidths greater than 300 pm, as well as provide temporal resolution of greater than 10 .mu.s.

  14. Noise caused by a finite extinction ratio of the light modulator in CW cavity ring-down spectroscopy

    Science.gov (United States)

    Huang, H.; Lehmann, K. K.

    2009-02-01

    A model is presented for the effect of a finite extinction ratio of the light modulator used in continuous wave cavity ring-down spectroscopy (CW-CRDS) experiments. We present a simple analytical expression for the minimum isolation required to prevent a significant increase in the fluctuations of the cavity decay rate, which determine the sensitivity of the method. We also present systematic measurements of the signal to noise in CW-CRDS as a function of the effective isolation of the light modulator, and excellent agreement with the model is found.

  15. Detection of in vitro S-Nitrosylated Compounds with Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Rad, Mary Lynn; Mezher, Monique Michele; Gaston, Benjamin M.; Lehmann, Kevin

    2016-06-01

    Nitric oxide has been of strong biological interest for nearly 40 years due to its role in cardiovascular and nervous signaling. It has been shown that S-nitrosocompounds are the main carrier molecule for nitric oxide in biological systems. These compounds are also of interest due to their relationship to several diseases including muscular dystrophy, stroke, myocardial infarction, Alzheimer's disease, Parkinson's disease, cystic fibrosis, asthma, and pulmonary arterial hypertension. Understanding the role of these S-nitrosocompounds in these diseases requires concentration studies in healthy and diseased tissues as well as metabolic studies using isotopically labeled S-nitroso precursors such at 15N-arginine. The current widely used techniques for these studies include chemiluminescence, which is blind to isotopic substitution, and mass spectrometry, which is known to artificially create and break S-NO bonds in the sample preparation stages. To this end we have designed and constructed a mid-IR cavity ring-down spectrometer for the detection of nitric oxide released from the target S-nitrosocompounds. Progress toward measuring S-NO groups in biological samples using the CRDS instrument will be presented.

  16. Radioactive Carbon Isotope Monitoring System Based on Cavity Ring-down Laser Spectroscopy for Decommissioning Process of Nuclear Facilities

    Science.gov (United States)

    Tomita, Hideki; Watanabe, Kenichi; Takiguchi, Yu; Kawarabayashi, Jun; Iguchi, Tetsuo

    In decommissioning process of nuclear facilities, large amount of radioactive isotopes are discharged as waste. Radioactive carbon isotope (14C) is one of the key nuclides to determine the upper limit of concentration in the waste disposal. In particular, 14C on the graphite reactor decommissioning should be separated from stable carbon isotopes (12C and 13C) and monitored for the public health and safety. We propose an isotope analysis system based on cavity ring-down laser spectroscopy (CRDS) to monitor the carbon isotopes (12C, 13C and 14C) in the isotope separation process for the graphite reactor decommissioning. This system is compact and suitable for a continuous monitoring, because the concentration of molecules including the carbon isotope is derived from its photo absorbance with ultra high sensitive laser absorption spectroscopy. Here are presented the necessary conditions of CRDS system for 14C isotope analysis through the preliminary experimental results of 13C isotope analysis with a prototype system.

  17. In situ measurements of OH radicals in dielectric barrier discharge plasmas with cw-cavity ring-down spectroscopy

    International Nuclear Information System (INIS)

    An apparatus of continuous wave cavity ring-down spectroscopy (cw-CRDS) has been constructed with the noise (RMS) equivalent absorption 3 x 10-9 cm-1. In situ quantitative measurements of OH radicals in dielectric barrier discharge (DBD) plasmas at low pressure using cw-CRDS are described. The influence of discharge voltage and pressure on number density of OH has been investigated. Results show that the OH production increases at low pressure with increasing discharge pressure; however, the number density of OH decreases due to electron attachment of H2O at higher pressure. The number density of OH radical increases with increasing discharge voltage and discharge frequency because of the increase of electron density and electron energy. (authors)

  18. Real-Tme Boron Nitride Erosion Measurements of the HiVHAc Thruster via Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Lee, Brian C.; Yalin, Azer P.; Gallimore, Alec; Huang, Wensheng; Kamhawi, Hani

    2013-01-01

    Cavity ring-down spectroscopy was used to make real-time erosion measurements from the NASA High Voltage Hall Accelerator thruster. The optical sensor uses 250 nm light to measure absorption of atomic boron in the plume of an operating Hall thruster. Theerosion rate of the High Voltage Hall Accelerator thruster was measured for discharge voltages ranging from 330 to 600 V and discharge powers ranging from 1 to 3 kW. Boron densities as high as 6.5 x 10(exp 15) per cubic meter were found within the channel. Using a very simple boronvelocity model, approximate volumetric erosion rates between 5.0 x 10(exp -12) and 8.2 x 10(exp -12) cubic meter per second were found.

  19. Evanescent-wave cavity ring-down spectroscopy for enhanced detection of surface binding under flow injection analysis conditions.

    Science.gov (United States)

    van der Sneppen, L; Buijs, J B; Gooijer, C; Ubachs, W; Ariese, F

    2008-06-01

    The feasibility of liquid-phase evanescent-wave cavity ring-down spectroscopy (EW-CRDS) for surface-binding studies under flow-injection analysis (FIA) conditions is demonstrated. The EW-CRDS setup consists of an anti-reflection coated Dove prism inside a linear cavity (with standard or super-polishing of the total internal reflective (TIR) surface). A teflon spacer with an elliptical hole clamped on this surface acts as a 20 muL sized flow cell. The baseline noise of this system is of the order of 10(-4) absorbance units; the baseline remains stable over a prolonged time and the prism surface does not become contaminated during repeated injections of the reversibly adsorbing test dyes Crystal Violet (CV) and Direct Red 10 (DR10). At typical FIA or liquid chromatography (LC) flow rates, the system has sufficient specificity to discriminate between species with different surface affinities. For CV a much stronger decrease in ring-down time is observed than calculated based on its bulk concentration and the effective depth probed by the evanescent wave, indicating binding of this positively charged dye to the negatively charged prism surface. The amount of adsorption can be influenced by adjusting the flow rate or the eluent composition. At a flow rate of 0.5 mL/min, an enrichment factor of 60 was calculated for CV; for the poorly adsorbing dye DR10 it is 5. Super-polishing of the already polished TIR surface works counter-productively. The adsorbing dye Crystal Violet has a detection limit of 3 muM for the standard polished surface; less binding occurs on the super-polished surface and the detection limit is 5 muM. Possible applications of EW-CRDS for studying surface binding or the development of bio-assays are discussed. PMID:18559152

  20. Effects of Particles on Trace-Gas Measurement Using Open-Path Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Mchale, L.; Shadman, S.; Yalin, A.

    2015-12-01

    Open-path Cavity Ring-down Spectroscopy offers many potential advantages over traditional closed-path configurations for the measurement of atmospheric trace gasses. Removal of the vacuum pump and flow system may enable more compact instruments suitable for remote and mobile deployments as well as real time measurement of 'sticky' gases. However, open path operation introduces new challenges including exposure of high reflectivity mirrors to ambient air and aerosols, the need to measure wider (pressure broadened) spectral peaks and possible signal interferences due to optical extinction by aerosol particles in the cavity laser beam. The present submission focuses on the effects of aerosol particles on open-path CRDS using a near-infrared (1742 nm) methane gas measurement system as a test bed. A simple purge enclosure system was developed to prevent aerosol deposition on the cavity high-reflectors. The purge uses ambient air pulled in with a micro-pump through a hepa filter and maintained mirror reflectivity R>0.99996 over 100 hours of use in the presence of high aerosol loading. Optical extinction due to ambient aerosols can change the cavity loss and influence the recorded ring-down times. We observed relatively large fluctuations due to supermicron particles and a near-constant baseline shift due to smaller submicron particles. The fluctuations correspond to absorption on the order of 10-8-10-7 cm-1, comparable to the amplitude of the targeted methane absorption features, causing significant interference. Simple software filter approaches were developed to counter these fluctuations without a priori knowledge of the ambient aerosols. The filters exploit the statistical distribution of signals as well as the expected absorption lineshape. Using these filters, noise-equivalent sensitivities within a factor of ~3 of closed-path systems were obtained (4x10-10cm-1Hz-1/2). Outdoor open-path measurements were validated with side-by-side measurements with a commercial

  1. High-accuracy continuous airborne measurements of greenhouse gases (CO2 and CH4) using the cavity ring-down spectroscopy (CRDS) technique

    NARCIS (Netherlands)

    Chen, H.; Winderlich, J.; Gerbig, C.; Hoefer, A.; Rella, C. W.; Crosson, E. R.; Van Pelt, A. D.; Steinbach, J.; Kolle, O.; Beck, V.; Daube, B. C.; Gottlieb, E. W.; Chow, V. Y.; Santoni, G. W.; Wofsy, S. C.

    2010-01-01

    High-accuracy continuous measurements of greenhouse gases (CO2 and CH4) during the BARCA (Balancao Atmosferico Regional de Carbono na Amazonia) phase B campaign in Brazil in May 2009 were accomplished using a newly available analyzer based on the cavity ring-down spectroscopy (CRDS) technique. This

  2. Simultaneous in situ detection of atmospheric NO3 and N2O5 via cavity ring-down spectroscopy

    Science.gov (United States)

    Brown, Steven S.; Stark, Harald; Ciciora, Steven J.; McLaughlin, Richard J.; Ravishankara, A. R.

    2002-09-01

    This article describes the application of cavity ring-down spectroscopy (CaRDS) to the simultaneous concentration measurement of nitrate radical, NO3, and dinitrogen pentoxide, N2O5, in the ambient atmosphere. The sensitivity for detection of both NO3 and N2O5 is 0.5 pptv (2σ) for a 5 s integration, comparable to or better than previous measurements of NO3 (e.g., via DOAS), but with significantly better time resolution. Furthermore, direct measurement of N2O5 represent a previously unavailable capability. Concentrations of both species are measured simultaneously in two separate flow systems and optical cavities pumped by the same pulsed dye laser at 662 nm. One of the flow systems remains at ambient temperature for detection of NO3, while the other is heated to 80 °C to induce thermal decomposition of N2O5 providing a measurement of the sum of the NO3 and N2O5 concentrations. This article outlines a series of laboratory and field tests of the instrument's performance. Important considerations include signal acquisition, zero measurements, aerosol interference, flow system losses, and the conversion efficiency for N2O5 thermolysis to NO3. We describe the limitations of this method and show how they can be quantified and accounted for in field measurements.

  3. Diode laser cavity ring-down spectroscopy for in situ measurement of NO3 radical in ambient air

    Science.gov (United States)

    Wang, Dan; Hu, Renzhi; Xie, Pinhua; Liu, Jianguo; Liu, Wenqing; Qin, Min; Ling, Liuyi; Zeng, Yi; Chen, Hao; Xing, XingBiao; Zhu, Guoliang; Wu, Jun; Duan, Jun; Lu, Xue; Shen, Lanlan

    2015-11-01

    A cavity ring-down spectroscopy (CRDS) instrument for measuring atmospheric NO3 radical developed in our laboratory is presented in detail. Light from a red laser diode (661.85 nm) is coupled on-axis into an optical cavity formed by a pair of high-reflectivity mirrors (R≥99.9985%) to achieve an effective absorption path length of approximately 20 km. The detection limit of the NO3 radical determined by Allan variance for the field observation with high particles is approximately 3.2 pptv (2σ, 10 s). The transmission efficiency of the NO3 radical in the system is calibrated, including the filter loss and surface loss. Moreover, measurable interferences from NO2, O3 and water vapor are also discussed. Considering the influence of inlet transmission efficiency and other factors, the instrument accuracy for NO3 radical measurement is approximately ±8% (1σ). The measurement of NO3 radical was performed at a suburb site in Beijing under the situation of high particles concentration (PM2.5 approximately several tens to 150 μg/m3) from October 26 to November 11, 2014. The NO3 radical concentration during the period is relatively low with the maximum value of 38 pptv. The observation results on October 29, combining NO2, O3 and NO data, are briefly analyzed. The experimental results demonstrate that this compact CRDS instrument has the potential for NO3 radical measurements in the field with high particles.

  4. Novel use of cavity ring-down spectroscopy to investigate aquatic carbon cycling from microbial to ecosystem scales.

    Science.gov (United States)

    Maher, Damien T; Santos, Isaac R; Leuven, Jasper R F W; Oakes, Joanne M; Erler, Dirk V; Carvalho, Matheus C; Eyre, Bradley D

    2013-11-19

    Development of cavity ring-down spectroscopy (CRDS) has enabled real-time monitoring of carbon stable isotope ratios of carbon dioxide and methane in air. Here we demonstrate that CRDS can be adapted to assess aquatic carbon cycling processes from microbial to ecosystem scales. We first measured in situ isotopologue concentrations of dissolved CO2 ((12)CO2 and (13)CO2) and CH4 ((12)CH4 and (13)CH4) with CRDS via a closed loop gas equilibration device during a survey along an estuary and during a 40 h time series in a mangrove creek (ecosystem scale). A similar system was also connected to an in situ benthic chamber in a seagrass bed (community scale). Finally, a pulse-chase isotope enrichment experiment was conducted by measuring real-time release of (13)CO2 after addition of (13)C enriched phytoplankton to exposed intertidal sediments (microbial scale). Miller-Tans plots revealed complex transformation pathways and distinct isotopic source values of CO2 and CH4. Calculations of δ(13)C-DIC based on CRDS measured δ(13)C-CO2 and published fractionation factors were in excellent agreement with measured δ(13)C-DIC using isotope ratio mass spectroscopy (IRMS). The portable CRDS instrumentation used here can obtain real-time, high precision, continuous greenhouse gas data in lakes, rivers, estuaries and marine waters with less effort than conventional laboratory-based techniques. PMID:24131451

  5. Time resolved super continuum Cavity Ring-Down Spectroscopy for multicomponent gas detection; Espectroscopia de cavidade ressonante tipo Ring-Down Supercontinuum resolvida no tempo para detecao de multicomponentes gasosos

    Energy Technology Data Exchange (ETDEWEB)

    Nakaema, Walter Morinobu

    2010-07-01

    In this work, we present a variation of the technique CRDS (Cavity Ring-Down Spectroscopy) to obtain simultaneously a multicomponent absorption spectrum in a broad visible range. This new approach uses the Supercontinuum (SC) spectrum (resulting from irradiation of nonlinear media by femtosecond lasers, or simply generated by compact sources) as a light source to illuminate the cavity. In this context it is described the features of the modules assembling a MC-SC-CRDS (Multicomponent Supercontinuum Cavity Ring-Down Spectroscopy): a set of high reflectivity mirrors, the resonant cavity and the detection system. Some problems related to the multimode excitation, stray light, effective use of the dynamic range of the detector, the poor resolution of the instrument to resolve narrow absorption lines are issued. We present the absorption spectra of H{sub 2}O (polyads 4{upsilon}, 4{upsilon} + {delta}) and O{sub 2} (spin-forbidden b-X branch) measured simultaneously by this technique in the visible range and a comparison with the absorption lines based on HITRAN database is made to demonstrate the functionality of this method. (author)

  6. Determination of the HO2 radical in dielectric barrier discharge plasmas using near-infrared cavity ring-down spectroscopy

    International Nuclear Information System (INIS)

    The hydroperoxyl radical (HO2) plays an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non-thermal plasmas. This work reports the determination of the hydroperoxyl radical in dielectric barrier discharge plasmas via near-infrared continuous wave cavity ring-down spectroscopy. HO2 radicals were observed in discharges of HCHO/O2/H2O/N2 mixtures around 6625.7 cm-1 in the first H-OO stretching overtone, (2, 0, 0)-(0, 0, 0), of its ground electronic state X-tilde2A''. At certain discharge conditions (ac frequency of 5 kHz, peak-to-peak voltage of 6.5 kV, 1900 ppm HCHO, 20% O2, 3.5% H2O in N2, Ptotal = 30 Torr), HO2 radical concentration was determined to be 1.0 x 1013 molecules cm-3. The temporary evolution of HO2 concentration was obtained using the 'time window' method. The effects of oxygen concentration, water concentration, the discharge voltage and discharge gas pressure on the concentration of HO2 radicals have been investigated. The detection limit of our setup for the HO2 radical is ∼1 x 1011 molecules cm-3

  7. Evanescent wave cavity ring-down spectroscopy (EW-CRDS) as a probe of macromolecule adsorption kinetics at functionalized interfaces.

    Science.gov (United States)

    O'Connell, Michael A; de Cuendias, Anne; Gayet, Florence; Shirley, Ian M; Mackenzie, Stuart R; Haddleton, David M; Unwin, Patrick R

    2012-05-01

    Evanescent wave cavity ring-down spectroscopy (EW-CRDS) has been employed to study the interfacial adsorption kinetics of coumarin-tagged macromolecules onto a range of functionalized planar surfaces. Such studies are valuable in designing polymers for complex systems where the degree of interaction between the polymer and surface needs to be tailored. Three tagged synthetic polymers with different functionalities are examined: poly(acrylic acid) (PAA), poly(3-sulfopropyl methacrylate, potassium salt) (PSPMA), and a mannose-modified glycopolymer. Adsorption transients at the silica/water interface are found to be characteristic for each polymer, and kinetics are deduced from the initial rates. The chemistry of the adsorption interfaces has been varied by, first, manipulation of silica surface chemistry via the bulk pH, followed by surfaces modified by poly(L-glutamic acid) (PGA) and cellulose, giving five chemically different surfaces. Complementary atomic force microscopy (AFM) imaging has been used for additional surface characterization of adsorbed layers and functionalized interfaces to allow adsorption rates to be interpreted more fully. Adsorption rates for PSPMA and the glycopolymer are seen to be highly surface sensitive, with significantly higher rates on cellulose-modified surfaces, whereas PAA shows a much smaller rate dependence on the nature of the adsorption surface. PMID:22489550

  8. Phase-shift Cavity Ring Down Spectroscopy Set-up for NO2 Sensing : Design and Fabrication

    Directory of Open Access Journals (Sweden)

    Cherry Dhiman

    2015-03-01

    Full Text Available An indigenously designed cavity ring down spectroscopy cell of 80 cm length of mild steel material was fabricated by attaching two 1″ diameter high reflecting concave mirrors with reflectivity 99.997 % at 405 nm and radius of curvature was 1 m in specially designed mirror holding assemblies to the cell at two ends. Fine alignment of the resonator is facilitated with three tip-tilt adjusting screws to the mirror-mounting plate assembly. The PS-CRDS experimental set-up is evaluated by measuring the phase shift values corresponding to the absorption of NO2 gas filled at low pressures in the cell. The limit of detection of pure NO2 using the set-up under given conditions of Ar @ 50 mbar is estimated to be 1.50 × 1011 cm-3 and @ 60 mbar as 2 × 1011 cm-3.Defence Science Journal, Vol. 65, No. 1, January 2015, pp.25-30, DOI:http://dx.doi.org/10.14429/dsj.65.7790

  9. Modification of a commercial cavity ring-down spectroscopy NO{sub 2} detector for enhanced sensitivity

    Energy Technology Data Exchange (ETDEWEB)

    Castellanos, Patricia; Ehrman, Sheryl H. [Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742 (United States); Luke, Winston T.; Kelley, Paul [National Oceanic and Atmospheric Administration, Air Resources Laboratory, SSMC3, Rm. 3316, 1315 East West Hwy., Silver Spring, Maryland 20910 (United States); Stehr, Jeffrey W.; Dickerson, Russell R. [Department of Atmospheric and Oceanic Science, University of Maryland, College Park, Maryland 20742 (United States)

    2009-11-15

    Nitrogen dioxide (NO{sub 2}) plays a central role in atmospheric chemistry, air pollution, and biogeochemical cycles. Many analytical techniques have been developed to detect NO{sub 2}, but only chemiluminescence-based instruments are commonly, commercially available. There remains a need for a fast, light, and simple method to directly measure NO{sub 2}. In this work we describe the modification and characterization of a small, commercially available cavity ring-down spectroscopy (CRDS) NO{sub 2} detector suitable for surface and aircraft monitoring. A metal oxide scrubber was added to remove NO{sub 2}, and provide a chemical zero, improving the detection limit (3{sigma} of the background noise) from several parts per billion by volume (ppbv) to 0.06 ppbv, integrated over 60 s. Known interferences by water and particles were removed using Nafion tubing and a 1 {mu}m Teflon filter, respectively. A 95% response time of 18{+-}1 s was observed for a step change in concentration. The CRDS detector was run in parallel to an ozone chemiluminescence device with photolytic conversion of NO{sub 2} to NO. The two instruments measured ambient air in suburban Maryland. A least-squares fit to the comparison data resulted a slope of 0.960{+-}0.002 and R of 0.995, showing agreement within experimental uncertainty.

  10. Detection of no and S-Nitrosocompounds Using Mid-Ir Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Stsiapura, Vitali; Shuali, Vincent K.; Ziegler, Angela; Lehmann, Kevin K.; Gaston, Benjamin M.

    2013-06-01

    Metabolic reactions of S-nitrosothiols have received much attention in biochemistry and medicine since S-nitrosocompounds can act not only as donors of nitric oxide (NO) in an organism but can themselves be involved in signal transduction. In the past few decades, the primary means of detecting S-nitrosocompounds in biological media has been through chemiluminescence detection of NO, a technique that limits the sensitivity to ppb levels and is not able to trace isotopologues of NO. Here we present a cw-CRD instrument for detection of NO isotopologues released from S-nitrosocompounds with a sensitivity of 27 pptv of NO in 100 torr He (after averaging of ˜400 ringdowns). A mid-IR ec-QCL laser (Daylight Solutions) is used to excite the ringdown cavity of finesse ˜10000 and probe the NO fundamental ro-vibrational band in the 5.2 - 5.3 μm range.

  11. Tritiated water detection in the 2.17 µM spectral region by cavity ring down spectroscopy

    International Nuclear Information System (INIS)

    Nuclear waste containers are intended to be stored in dedicated disposal sites. For the inside and environmental safety of the disposal sites, the tiny outgassing rates leaking out the containers are measured. Presently, the radioactive HT gas is measured by liquid scintillation. However an alternative method—cavity ring down spectroscopy, an isotopically selective laser technique based on molecular spectroscopy—is currently developed and evaluated for tritium measurement in its oxidized form, HTO. Applying this method, the number density of the gaseous HTO sample hold in the optical cavity cell, is derived from the laser beam absorption by vibrational symmetric stretching 2ν1 (R) HTO lines in the 4590 and 4600 cm−1 spectral range. To ensure a future accurate HTO measurement, the theoretical line intensities are confronted to the experiment: two tritiated water standards are measured with a dedicated CRDS set-up. Compared to the theoretical database, the line positions are correct (−0.067 to −0.128 cm−1), their relative intensities are in agreement with the database, but their absolute intensities are 20% weaker. Among the seven intense lines, the 4596.485 cm−1 line (intensity 8.22 10−22 cm/molecule) and the 4592.407 cm−1 line (intensity 9.83 10−22 cm/molecule) are isolated and intense for a sensitive detection. The HTO detection limit with the present set-up is 3 kBq (10 min), equivalent to 1.8 1012 molecules in the 111 cm3 CRDS cell. This detection limit could be improved by a factor 3 by reducing the detection noise

  12. Simultaneous and continuous multiple wavelength absorption spectroscopy on nanoliter volumes based on frequency-division multiplexing fiber-loop cavity ring-down spectroscopy.

    Science.gov (United States)

    Waechter, Helen; Munzke, Dorit; Jang, Angela; Loock, Hans-Peter

    2011-04-01

    We demonstrate a method for measuring optical loss simultaneously at multiple wavelengths with cavity ring-down spectroscopy (CRD). Phase-shift CRD spectroscopy is used to obtain the absorption of a sample from the phase lag of intensity modulated light that is entering and exiting an optical cavity. We performed dual-wavelength detection by using two different laser light sources and frequency-division multiplexing. Each wavelength is modulated at a separate frequency, and a broadband detector records the total signal. This signal is then demodulated by lock-in amplifiers at the corresponding two frequencies allowing us to obtain the phase-shift and therefore the optical loss at several wavelengths simultaneously without the use of a dispersive element. In applying this method to fiber-loop cavity ring-down spectroscopy, we achieve detection at low micromolar concentrations in a 100 nL liquid volume. Measurements at two wavelengths (405 and 810 nm) were performed simultaneously on two dyes each absorbing at mainly one of the wavelengths. The respective concentrations could be quantified independently in pure samples as well as in mixtures. No crosstalk between the two channels was observed, and a minimal detectable absorbance of 0.02 cm(-1) was achieved at 405 nm. PMID:21355542

  13. Isotopic analysis of dissolved organic carbon in produced water brines by wet chemical oxidation and cavity ring-down spectroscopy

    Science.gov (United States)

    Thomas, Randal; Conaway, Christopher; Saad, Nabil; Kharaka, Yousif

    2013-04-01

    Identification of fluid migration and escape from intentionally altered subsurface geologic systems, such as in hydraulic fracturing, enhanced oil recovery, and carbon sequestration activities, is an important issue for environmental regulators based on the traction that the "fracking" process is gathering across the United States. Given diverse injected fluid compositions and the potential for toxic or regulated compounds to be released, one of the most important steps in the process is accurately identifying evidence of injected fluid escape during and after injection processes. An important tool in identifying differences between the natural groundwater and injected fluid is the isotopic composition of dissolved constituents including inorganic components such as Sr and carbon isotopes of the dissolved organic compounds. Since biological processes in the mesothermal subsurface can rapidly alter the organic composition of a fluid, stable carbon isotopes of the dissolved organic compounds (DOC) are an effective means to identify differences in the origin of two fluids, especially when coupled with inorganic compound analyses. The burgeoning field of cavity ring-down spectroscopy (CRDS) for isotopic analysis presents an opportunity to obtain rapid, reliable and cost-effective isotopic measurements of DOC in potentially affected groundwater for the identification of leakage or the improvement of hydrogeochemical pathway models. Here we adapt the use of the novel hyphenated TOC-CRDS carbon isotope analyzer for the analysis of DOC in produced water by wet oxidation and describe the methods to evaluate performance and obtain useful information at higher salinities. Our methods are applied to a specific field example in a CO2-enhanced EOR field in Cranfield, Mississippi (USA) as a means to demonstrate the ability to distinguish natural and injected DOC using the stable isotopic composition of the dissolved organic carbon when employing the novel TOC-CRDS instrumentation

  14. A gas chromatograph for quantification of peroxycarboxylic nitric anhydrides calibrated by thermal dissociation cavity ring-down spectroscopy

    Directory of Open Access Journals (Sweden)

    T. W. Tokarek

    2014-06-01

    Full Text Available The peroxycarboxylic nitric anhydrides (PANs, molecular formula RC(OO2NO2 can readily be observed by gas chromatography coupled to electron capture detection (PAN-GC. Calibration of a PAN-GC remains a challenge because the response factors (RF's differ for each of the PANs and because their synthesis in sufficiently high purity is non-trivial, in particular for PANs containing unsaturated side chains. In this manuscript, a PAN-GC and its calibration using diffusion standards, whose output was quantified by blue diode laser thermal dissociation cavity ring-down spectroscopy (TD-CRDS, are described. The PAN-GC peak areas correlated linearly with total peroxy nitrate (ΣPN mixing ratios measured by TD-CRDS (r > 0.96. Accurate determination of RF's required the concentrations of PAN impurities in the synthetic standards to be subtracted from ΣPN. The PAN-GC and its TD-CRDS calibration method were deployed during ambient air measurement campaigns in Abbotsford, BC, from 20 July to 5 August, 2012, and during the Fort McMurray Oil Sands Strategic Investigation of Local Sources (FOSSILS campaign at the AMS13 ground site in Fort McKay, AB, from 10 August to 5 September 2013. For the Abbotsford data set, the PAN-GC mixing ratios were compared and agreed with those determined in parallel by thermal dissociation chemical ionization mass spectrometry (TD-CIMS. Advantages and disadvantages of the PAN measurement techniques used in this work and the utility of TD-CRDS as a PAN-GC calibration method are discussed.

  15. Ultra-Sensitive Elemental and Isotope Measurements with Compact Plasma Source Cavity Ring-Down Spectroscopy (CPS-CRDS)

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Yixiang; Wang, Chuji; Winstead, Christopher B.

    2005-06-01

    The proposed research is to develop a new class of instruments for actinide isotopes and hazardous element analysis through coupling highly sensitive cavity ring-down spectroscopy to a compact microwave plasma source. The research work will combine advantages of CRDS measurement with a low power, low flow rate, tubing-type microwave plasma source to reach breakthrough sensitivity for elemental analysis and unique capability of isotope measurement. The project has several primary goals: (1) Explore the feasibility of marrying CRDS with a new microwave plasma source; (2) Provide quantitative evaluation of CMP-CRDS for ultratrace elemental and actinide isotope analysis; (3) Approach a breakthrough detection limit of ca. 10{sup -13} g/ml or so, which are orders of magnitude better than currently available best values; (4) Demonstrate the capability of CMP-CRDS technology for isobaric measurements, such as {sup 238}U and {sup 238}Pu isotopes. (5) Design and assemble the first compact, field portable CMP-CRDS instrument with a high-resolution diode laser for DOE/EM on-site demonstration. With all these unique capabilities and sensitivities, we expect CMP-CRDS will bring a revolutionary change in instrument design and development, and will have great impact and play critical roles in supporting DOE's missions in environmental remediation, environmental emission control, waste management and characterization, and decontamination and decommissioning. The ultimate goals of the proposed project are to contribute to environmental management activities that would decrease risk for the public and workers, increase worker productivity with on-site analysis, and tremendously reduce DOE/EM operating costs.

  16. Measurements of methane emissions from landfills using mobile plume method with trace gas and cavity ring-down spectroscopy

    Science.gov (United States)

    Mønster, J.; Kjeldsen, P.; Scheutz, C.

    2012-04-01

    Methane is emitted to the atmosphere from both anthropogenic and natural sources. One of the major anthropogenic sources is methane produced by bacteria in anaerobic environments such as rice pads and landfills. Land filling has for many years been the preferred waste disposal method, resulting in a large methane production with a large contribution to the global increase in atmospheric green house gas concentration. Several steps have been taken to reduce the emission of methane from landfills. In order to validate the effect of these steps, a measurement method is needed to quantify methane emissions with a large spatial variation. One method is to use a highly sensitive and fast analytical method, capable of measuring the atmospheric concentration methane downwind from emission areas. Combined with down-wind measurements of a trace gas, emitted at a controlled mass flow rate, the methane emission can be calculated. This method is called the mobile plume method, as the whole plume is measured by doing several transects. In the current study a methane/acetylene analyzer with cavity ring-down spectroscopy detection (Picarro, G2203) was used to estimate methane from a number of Danish landfills. We measured at both active and closed landfills and investigated the difference in methane emission. At landfills where the emissions could have more than one origin, the source strength of the different emission areas was determined by accurate trace gas positioning and choosing appropriate wind speed and measurement distance. To choose these factors, we addressed the uncertainties and limitations of the method with respect to the configuration of the trace gas bottles and the distance between the emission area and the measurement points. Composting of organic material in large piles was done at several of the investigated landfills and where possible, the methane emission from this partly anaerobic digestion was measured as a separate emission.

  17. Accurate measurements of carbon monoxide in humid air using the cavity ring-down spectroscopy (CRDS technique

    Directory of Open Access Journals (Sweden)

    H. Chen

    2012-09-01

    Full Text Available Accurate measurements of carbon monoxide (CO in humid air have been made using the cavity ring-down spectroscopy (CRDS technique. The measurements of CO mole fractions are determined from the strength of its spectral absorption in the near infrared region (∼1.57 μm after removing interferences from adjacent carbon dioxide (CO2 and water vapor (H2O absorption lines. Water correction functions that account for the dilution and pressure-broadening effects as well as absorption line interferences from adjacent CO2 and H2O lines have been derived for CO2 mole fractions between 360–390 ppm. The line interference corrections are independent of CO mole fractions. The dependence of the line interference correction on CO2 abundance is estimated to be approximately −0.3 ppb/100 ppm CO2 for dry mole fractions of CO. Comparisons of water correction functions from different analyzers of the same type show significant differences, making it necessary to perform instrument-specific water tests for each individual analyzer. The CRDS analyzer was flown on an aircraft in Alaska from April to November in 2011, and the accuracy of the CO measurements by the CRDS analyzer has been validated against discrete NOAA/ESRL flask sample measurements made on board the same aircraft, with a mean difference between integrated in situ and flask measurements of −0.6 ppb and a standard deviation of 2.8 ppb. Preliminary testing of CRDS instrumentation that employs new spectroscopic analysis (available since the beginning of 2012 indicates a smaller water vapor dependence than the models discussed here, but more work is necessary to fully validate the performance. The CRDS technique provides an accurate and low-maintenance method of monitoring the atmospheric dry mole fractions of CO in humid air streams.

  18. Quantification of Alkyl Nitrates in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy with Preconcentration

    Science.gov (United States)

    Ye, C. Z.; Osthoff, H. D.; Taha, Y. M.; Pak, J. K.; Saowapon, M. T.

    2015-12-01

    Alkyl nitrates (AN, molecular formula RONO2) play a crucial role in the troposphere as temporary reservoirs of nitrogen oxides (NOx =NO +NO2) and by acting as chain terminators in the photochemical production of ozone. Mixing ratios of AN in ambient air are commonly quantified by gas chromatography with electron capture or mass spectrometric detection (GC-ECD or GC-MS) coupled to purge-and-trap preconcentration, usually on Tenax sorbent, to improve the detection limits. The analysis, however, is quite laborious as there are many alkyl nitrates that are low in individual abundance (often less than 1 parts-per-trillion by volume, pptv) and that exhibit different instrumental response factors. An alternative method is to determine alkyl nitrates as a sum (ΣAN) by thermal dissociation (TD) to a common fragment (NO2), which can then be quantified with a uniform response factor by optical absorption, for example by cavity ring-down spectroscopy (CRDS). However, the determination of ΣAN by TD-CRDS is hampered by its relatively high detection limits (several 100 pptv) and secondary chemistry following TD that results in both negative and positive interferences and depends on the composition of the ambient air sampled. In this work, a TD-CRDS equipped with a Tenax preconcentration unit is described. Matrix effects are minimized by desorbing the samples from the Tenax in a background of nitrogen. The performance of the instrument, in particular the recovery from the Tenax sorbent, was evaluated by sampling laboratory-generated mixtures of alkyl and peroxyacyl nitrates. Field data from a coastal site collected during the Ozone-depleting reactions in a coastal atmosphere (ORCA) campaign, which took place at the Amphitrite Point Observatory in Ucluelet, BC, from July 6 - 31, 2015, are presented. Advantages and disadvantages of the new method are discussed.

  19. Continuous Flow - Cavity RingDown Spectroscopy Using a Novel Universal Interface for High-Precision Bulk 13C Analysis

    Science.gov (United States)

    Saad, Nabil; Richman, Bruce

    2010-05-01

    We have developed the world's first optical spectroscopy-based system for bulk stable isotope analysis of 13C. The system is based on a novel universal interface, named LIAISON, capable of coupling to almost any CO2-generating sample preparation front-end ranging from an elemental analyzer to any dissolved carbon analysis module, which are of significant use in geochemical, ecological and food authentication studies. In one specific application, we have coupled LIAISON to an elemental analyzer (EA) and to a cavity ring-down spectrometer (CRDS) for 13C isotopic analysis of adulterated honey samples. Another application was developed to analyze dissolved inorganic carbon in water samples. LIAISON is suited for handling a high-throughput sample analysis process by running three different gas handling operations in parallel: Admitting combustion gas from the EA into a first gas bellows, analyzing the previous sample collected into a second gas bellows with CRDS, and flushing and purging a third gas bellows in preparation for the upcoming sample collection operation. The sample-to-sample analysis time is 10 minutes and the operation is completely automated for the whole front-end auto-sampler tray capacity, requiring no operator intervention. The CRDS data are collected, tabulated and saved into an output text file. The memory effect between the USGS L-Glutamic acid standard at natural abundance and the moderately enriched USGS L-Glutamic acid standard is excluded by the selection of the adequate number and duration of flush and purge cycles of the gas sample bags. The system's proven accuracy was cross-checked with EA-IRMS and its achieved precision was typically less than 0.2 permil, including the 13C-enriched tested samples. The LIAISON-CRDS system presented here provides a fully automated solution for 13C bulk stable isotope analysis with unprecedented ease-of-use and possible field portability and application with the availability of a compact front-end. In

  20. Accurate measurements of carbon monoxide in humid air using the cavity ring-down spectroscopy (CRDS technique

    Directory of Open Access Journals (Sweden)

    H. Chen

    2013-04-01

    Full Text Available Accurate measurements of carbon monoxide (CO in humid air have been made using the cavity ring-down spectroscopy (CRDS technique. The measurements of CO mole fractions are determined from the strength of its spectral absorption in the near-infrared region (~1.57 μm after removing interferences from adjacent carbon dioxide (CO2 and water vapor (H2O absorption lines. Water correction functions that account for the dilution and pressure-broadening effects as well as absorption line interferences from adjacent CO2 and H2O lines have been derived for CO2 mole fractions between 360–390 ppm and for reported H2O mole fractions between 0–4%. The line interference corrections are independent of CO mole fractions. The dependence of the line interference correction on CO2 abundance is estimated to be approximately −0.3 ppb/100 ppm CO2 for dry mole fractions of CO. Comparisons of water correction functions from different analyzers of the same type show significant differences, making it necessary to perform instrument-specific water tests for each individual analyzer. The CRDS analyzer was flown on an aircraft in Alaska from April to November in 2011, and the accuracy of the CO measurements by the CRDS analyzer has been validated against discrete NOAA/ESRL flask sample measurements made on board the same aircraft, with a mean difference between integrated in situ and flask measurements of −0.6 ppb and a standard deviation of 2.8 ppb. Preliminary testing of CRDS instrumentation that employs improved spectroscopic model functions for CO2, H2O, and CO to fit the raw spectral data (available since the beginning of 2012 indicates a smaller water vapor dependence than the models discussed here, but more work is necessary to fully validate the performance. The CRDS technique provides an accurate and low-maintenance method of monitoring the atmospheric dry mole fractions of CO in humid air streams.

  1. Miniaturized cavity ring-down detection in a liquid flow cell

    NARCIS (Netherlands)

    Bahnev, B.; Sneppen, van der L.; Wiskerke, A.E.; Ariese, F.; Gooijer, C.; Ubachs, W.M.G.

    2005-01-01

    A novel method for applying cavity ring-down spectroscopy in the liquid phase, compatible with LC analyses, is presented. The core of the setup is a home-built cavity ring-down flow cell (cell volume 12 muL) that is constructed using a silicon rubber spacer, which is clamped leak-tight between two h

  2. A free-flowing soap film combined with cavity ring-down spectroscopy as a detection system for liquid chromatography.

    Science.gov (United States)

    Vogelsang, Markus; Welsch, Thomas; Jones, Harold

    2010-05-01

    We have shown that a free-flowing soap film has sufficiently high-quality optical properties to allow it to be used in the cavity of a ring-down spectrometer (CRDS). The flow rates required to maintain a stable soap film were similar to those used in liquid chromatography and thus allowed interfacing with an HPLC system for use as an optical detector. We have investigated the properties of the system in a relevant analytical application. The soap film/CRDS combination was used at 355 nm as a detector for the separation of a mixture of nitroarenes. These compounds play a role in the residue analysis of areas contaminated with explosives and their decomposition products. In spite of the short absorption path length (9 microm) obtained by the soap film, the high-sensitivity of CRDS allowed a limit of detection of 4 x 10(-6) in absorption units (AU) or less than 17 fmol in the detection volume to be achieved.

  3. [INVITED] New advances in fiber cavity ring-down technology

    Science.gov (United States)

    Silva, S. O.; Magalhães, R.; Marques, M. B.; Frazão, O.

    2016-04-01

    A brief review in the cavity ring-down technique (CRD) is presented. In this review, there will only be considered the conventional fiber CRD configuration, i.e., there will only be presented researches involving cavities with two couplers with 99:1 ratios, due to the large amount of publications involving this spectroscopy method. The presented survey is divided in different topics related to the measurement of physical parameters, such as strain and temperature, curvature, pressure, refractive index, gas and biochemical sensing.

  4. Cavity ring-down spectroscopy for detection in liquid chromatography at UV wavelengths using standard cuvettes in a normal incidence geometry.

    Science.gov (United States)

    van der Sneppen, L; Ariese, F; Gooijer, C; Ubachs, W

    2007-05-01

    Liquid chromatography (LC) with cavity ring-down spectroscopy (CRDS) detection, using flow cuvettes (put under normal incidence inside the ring-down cavity), is demonstrated. Fresnel reflections are maintained within the capture range of a stable cavity of 4 cm length. This method circumvents the need for specific Brewster's angles and possible mirror degradation is avoided. The flow cuvettes are commercially available at low cost. At 355 nm (the frequency-tripled output of a Nd:YAG laser), the system surpasses the performance of conventional absorbance detectors; the baseline noise was 1.3 x 10(-5)AU and detection limits (injected concentrations) were between 40 and 80 nM for nitro-polyaromatic hydrocarbons with an extinction coefficient epsilon of 7.3-10.2 x 10(3)M(-1)cm(-1). The system was also tested at 273 nm, but in the deep UV the reflectivity of the currently best available mirrors (R>or=99.91%) is still too low to show a significant improvement as compared to conventional UV-vis detection. PMID:17383664

  5. Comprehensive laboratory and field testing of cavity ring-down spectroscopy analyzers measuring H2O, CO2, CH4 and CO

    Science.gov (United States)

    Yver Kwok, C.; Laurent, O.; Guemri, A.; Philippon, C.; Wastine, B.; Rella, C. W.; Vuillemin, C.; Truong, F.; Delmotte, M.; Kazan, V.; Darding, M.; Lebègue, B.; Kaiser, C.; Xueref-Rémy, I.; Ramonet, M.

    2015-09-01

    To develop an accurate measurement network of greenhouse gases, instruments in the field need to be stable and precise and thus require infrequent calibrations and a low consumption of consumables. For about 10 years, cavity ring-down spectroscopy (CRDS) analyzers have been available that meet these stringent requirements for precision and stability. Here, we present the results of tests of CRDS instruments in the laboratory (47 instruments) and in the field (15 instruments). The precision and stability of the measurements are studied. We demonstrate that, thanks to rigorous testing, newer models generally perform better than older models, especially in terms of reproducibility between instruments. In the field, we see the importance of individual diagnostics during the installation phase, and we show the value of calibration and target gases that assess the quality of the data. Finally, we formulate recommendations for use of these analyzers in the field.

  6. High-Precision Measurement of 13C/12C Isotopic Ratio Using Gas Chromatography-Combustion-Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Saad, N.; Kuramoto, D. S.; Haase, C.; Crosson, E.; Tan, S.; Zare, R. N.

    2009-12-01

    Light stable isotope analysis, and in particular, compound specific isotopic analysis (CSIA), is a valuable tool to elucidate pathways and provide a better insight into biological, ecological, and geological systems. We present here the results of compound-specific isotopic carbon analysis of short chain hydrocarbons using the world’s first combination of gas chromatography, combustion interface, and cavity ring-down spectroscopy (GC-C-CRDS). Cavity ring-down spectroscopy (CRDS) is a highly sensitive optical spectroscopy, one application of which is to measure the stable isotopic ratios in small molecules. Because it uses a highly reflective optical cavity with many kilometers effective path length, CRDS provides some of the most sensitive and precise optical absorption measurements. Most optical spectroscopy isotopic analysis measures the quantities of each isotopologue independently using their distinct ro-vibrational spectra. The most common isotopes measured with optical spectroscopy are 13C and 12C in carbon dioxide. However, the isotopes of hydrogen, oxygen, and sulfur have also been measured. Unlike isotope ratio mass spectrometry (IRMS), optical spectroscopy can distinguish among isobars, which have essentially identical m/z ratios. The combination of chemical separation, chemical conversion, and CRDS makes a nearly universal tool for isotopic analysis of mixtures. In addition, CRDS can tolerate a variety of compounds mixed with the target. For example, CRDS can measure carbon dioxide and its isotopic 13C/12C ratio in the presence of oxygen. Using the novel GC-C-CRDS system, we injected a 75-microliter mixture of approximately equal quantities of methane, ethane, and propane into a gas chromatograph using helium as carrier gas. The methane, ethane, and propane were separated in time by 100 to 200 seconds after the chromatograph. Oxygen gas was added, and the hydrocarbons were combusted in a catalytic combustor with platinum and nickel, held at 1150oC. The

  7. An Ultrahigh Precision, High-Frequency Dissolved Inorganic Carbon Analyzer Based on Dual Isotope Dilution and Cavity Ring-Down Spectroscopy.

    Science.gov (United States)

    Huang, Kuan; Cassar, Nicolas; Jonsson, Bror; Cai, Wei-jun; Bender, Michael L

    2015-07-21

    We present a novel method for continuous and automated shipboard measurements of dissolved inorganic carbon concentration ([DIC]) in surface water. The method is based on dual isotope dilution and cavity ring-down spectroscopy (DID-CRDS). In this method, seawater is continuously sampled and mixed with a flow of NaH(13)CO3 solution that is also enriched in deuterated water (the spike). The isotopic composition of CO2 (δ(13)C(spiked_sample)) derived from the DIC in the mixture, and the D/H ratio of the mixed water (δD(spiked_sample)), are measured by CRDS analyzers. The D/H of the water in the mixture allows accurate estimates of the mixing ratio of the sample and the spike. [DIC] of the sample is then calculated from the mixing ratio, [DI(13)C] of the spike, and δ(13)C(spiked_sample). In the laboratory, the precision of the method is test was conducted in the Delaware Bay and Estuary. For 2 min average [DIC], a precision of <0.03% was achieved. Measurements from the DID-CRDS showed good agreement with independent measurements of discrete samples using the well-established coulometric method (mean difference = -1.14 ± 1.68 μmol kg(-1)), and the nondispersive infrared(NDIR)-based methods (mean difference = -0.9 ± 4.73 μmol kg(-1)).

  8. High-accuracy measurements of N2O concentration and isotopic composition of low and high concentration samples with small volume injections using Cavity Ring-Down Spectroscopy

    Science.gov (United States)

    Saad, Nabil; Palmer, Melissa; Huang, Kuan

    2015-04-01

    Nitrous oxide (N2O) gas is among the major contributors to global warming and ozone depletion in stratosphere. Quantitative estimate of N2O production in various pathways and N2O fluxes across different reservoirs is the key to understanding the role of N2O in the global change. To achieve this goal, accurate and concurrent measurement of both N2O concentration ([N2O]) and its associated isotopic ratios (δ 15Nα , δ 15{N}β & δ 18O) is desired. Recent developments in Cavity Ring-Down Spectroscopy (CRDS) have enabled high-precision measurements of [N2O] and Site-Preference-δ 15N (SP-δ 15N) and δ 18O of a continuous gas flow. However, many N2O samples are discrete with limited volume ( 2 ppm), and are not suitable for direct continuous measurements by CRDS. Here we present results of a small sample introduction and handling device, labelled as Small Sample Isotope Module (SSIM), coupled to and automatically coordinated with a Picarro isotopic N2O CRDS analyzer to handle and measure high concentration and/or small volume samples. The SSIM requires 20 ml of sample volume per analysis at STP, and transfers the sample to the CRDS for high-precision concentration and isotope ratio measurements. When the injected sample is

  9. Effectiveness of charged noncovalent polymer coatings against protein adsorption to silica surfaces studied by evanescent-wave cavity ring-down spectroscopy and capillary electrophoresis.

    Science.gov (United States)

    Haselberg, Rob; van der Sneppen, Lineke; Ariese, Freek; Ubachs, Wim; Gooijer, Cees; de Jong, Gerhardus J; Somsen, Govert W

    2009-12-15

    Protein adsorption to silica surfaces is a notorious problem in analytical separations. Evanescent-wave cavity ring-down spectroscopy (EW-CRDS) and capillary electrophoresis (CE) were employed to investigate the capability of positively charged polymer coatings to minimize the adsorption of basic proteins. Adsorption of cytochrome c (cyt c) to silica coated with a single layer of polybrene (PB), or a triple layer of PB, dextran sulfate (DS), and PB, was studied and compared to bare silica. Direct analysis of silica surfaces by EW-CRDS revealed that both coatings effectively reduce irreversible protein adsorption. Significant adsorption was observed only for protein concentrations above 400 microM, whereas the PB-DS-PB coating was shown to be most effective and stable. CE analyses of cyt c were performed with and without the respective coatings applied to the fused-silica capillary wall. Monitoring of the electroosmotic flow and protein peak areas indicated a strong reduction of irreversible protein adsorption by the positively charged coatings. Determination of the electrophoretic mobility and peak width of cyt c revealed reversible protein adsorption to the PB coating. It is concluded that the combination of results from EW-CRDS and CE provides highly useful information on the adsorptive characteristics of bare and coated silica surfaces toward basic proteins. PMID:19921852

  10. High sensitivity cavity ring down spectroscopy of the 3ν1+3ν2+ν3 band of NO2 near 7587 cm-1

    Science.gov (United States)

    Lukashevskaya, A. A.; Naumenko, O. V.; Mondelain, D.; Kassi, S.; Campargue, A.

    2016-07-01

    The very weak 3ν1+3ν2+ν3 absorption band of the main isotopologue of nitrogen dioxide, 14N16O2, is investigated for the first time near 7587 cm-1. The absorption spectrum was recorded by high sensitivity Continuous Wave-Cavity Ring Down Spectroscopy with a noise equivalent absorption of αmin≈1×10-10 cm-1. 414 lines of the 3ν1+3ν2+ν3 band were assigned with rotational quantum numbers N and Ka as high as 32 and 6, respectively, what corresponds to 518 rotation-vibration transitions. The overall set of spin-rotation energy levels was modeled in the frame of the effective Hamiltonian approach and reproduced with an RMS of 6×10-3 cm-1 for the (obs.-calc.) deviations. The effective Hamiltonian includes interactions with three nearby dark states - (350), (062) and (312) - in Coriolis interaction with the (331) bright state. Using a selected set of experimental line intensities and the fitted values of the vibration-rotation Hamiltonian parameters, the principal parameter in the dipole moment operator expansion is determined for the 3ν1+3ν2+ν3 band. With maximum line intensity on the order of 2.5×10-27 cm/molecule at 296 K, the 3ν1+3ν2+ν3 band is the weakest band of the NO2 molecule rovibrationnally assigned so far.

  11. Determination of the HO{sub 2} radical in dielectric barrier discharge plasmas using near-infrared cavity ring-down spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Liu Zhongwei; Xu Yong; Yang Xuefeng; Zhu Aimin; Zhao Guoli; Wang Weiguo [Laboratory of Plasma Physical Chemistry, PO Box 288, Dalian University of Technology, Dalian 116024 (China)], E-mail: yongxu@dlut.edu.cn

    2008-02-21

    The hydroperoxyl radical (HO{sub 2}) plays an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non-thermal plasmas. This work reports the determination of the hydroperoxyl radical in dielectric barrier discharge plasmas via near-infrared continuous wave cavity ring-down spectroscopy. HO{sub 2} radicals were observed in discharges of HCHO/O{sub 2}/H{sub 2}O/N{sub 2} mixtures around 6625.7 cm{sup -1} in the first H-OO stretching overtone, (2, 0, 0)-(0, 0, 0), of its ground electronic state X-tilde{sup 2}A''. At certain discharge conditions (ac frequency of 5 kHz, peak-to-peak voltage of 6.5 kV, 1900 ppm HCHO, 20% O{sub 2}, 3.5% H{sub 2}O in N{sub 2}, P{sub total} = 30 Torr), HO{sub 2} radical concentration was determined to be 1.0 x 10{sup 13} molecules cm{sup -3}. The temporary evolution of HO{sub 2} concentration was obtained using the 'time window' method. The effects of oxygen concentration, water concentration, the discharge voltage and discharge gas pressure on the concentration of HO{sub 2} radicals have been investigated. The detection limit of our setup for the HO{sub 2} radical is {approx}1 x 10{sup 11} molecules cm{sup -3}.

  12. High-accuracy continuous airborne measurements of greenhouse gases (CO2 and CH4 using the cavity ring-down spectroscopy (CRDS technique

    Directory of Open Access Journals (Sweden)

    V. Y. Chow

    2010-03-01

    Full Text Available High-accuracy continuous measurements of greenhouse gases (CO2 and CH4 during the BARCA (Balanço Atmosférico Regional de Carbono na Amazônia phase B campaign in Brazil in May 2009 were accomplished using a newly available analyzer based on the cavity ring-down spectroscopy (CRDS technique. This analyzer was flown without a drying system or any in-flight calibration gases. Water vapor corrections associated with dilution and pressure-broadening effects for CO2 and CH4 were derived from laboratory experiments employing measurements of water vapor by the CRDS analyzer. Before the campaign, the stability of the analyzer was assessed by laboratory tests under simulated flight conditions. During the campaign, a comparison of CO2 measurements between the CRDS analyzer and a nondispersive infrared (NDIR analyzer on board the same aircraft showed a mean difference of 0.22±0.09 ppm for all flights over the Amazon rain forest. At the end of the campaign, CO2 concentrations of the synthetic calibration gases used by the NDIR analyzer were determined by the CRDS analyzer. After correcting for the isotope and the pressure-broadening effects that resulted from changes of the composition of synthetic vs. ambient air, and applying those concentrations as calibrated values of the calibration gases to reprocess the CO2 measurements made by the NDIR, the mean difference between the CRDS and the NDIR during BARCA was reduced to 0.05±0.09 ppm, with the mean standard deviation of 0.23±0.05 ppm. The results clearly show that the CRDS is sufficiently stable to be used in flight without drying the air or calibrating in flight and the water corrections are fully adequate for high-accuracy continuous airborne measurements of CO2 and CH4.

  13. Ring-Down Spectroscopy for Characterizing a CW Raman Laser

    Science.gov (United States)

    Matsko, Andrey; Savchenkov, Anatoliy; Maleki, Lute

    2007-01-01

    .A relatively simple technique for characterizing an all-resonant intracavity continuous-wave (CW) solid-state Raman laser involves the use of ring-down spectroscopy. As used here, characterizing signifies determining such parameters as threshold pump power, Raman gain, conversion efficiency, and quality factors (Q values) of the pump and Stokes cavity modes. Heretofore, in order to characterize resonant-cavity-based Raman lasers, it has usually been necessary to manipulate the frequencies and power levels of pump lasers and, in each case, to take several sets of measurements. In cases involving ultra-high-Q resonators, it also has been desirable to lock pump lasers to resonator modes to ensure the quality of measurement data. Simpler techniques could be useful. In the present ring-down spectroscopic technique, one infers the parameters of interest from the decay of the laser out of its steady state. This technique does not require changing the power or frequency of the pump laser or locking the pump laser to the resonator mode. The technique is based on a theoretical analysis of what happens when the pump laser is abruptly switched off after the Raman generation reaches the steady state. The analysis starts with differential equations for the evolution of the amplitudes of the pump and Stokes electric fields, leading to solutions for the power levels of the pump and Stokes fields as functions of time and of the aforementioned parameters. Among other things, these solutions show how the ring-down time depends, to some extent, on the electromagnetic energy accumulated in the cavity. The solutions are readily converted to relatively simple equations for the parameters as functions of quantities that can be determined from measurements of the time-dependent power levels. For example, the steady-state intracavity conversion efficiency is given by G1/G2 1 and the threshold power is given by Pin(G2/G1)2, where Pin is the steady-state input pump power immediately prior to

  14. Evanescent-wave cavity ring-down detection of cytochrome c on surface-modified prisms

    NARCIS (Netherlands)

    Sneppen, van der L.; Gooijer, C.; Ubachs, W.M.G.; Ariese, F.

    2009-01-01

    Adsorption kinetics and molecular interactions on different Surface interfaces are studied by means of evanescent-wave cavity ring-down spectroscopy, using total internal reflection surfaces Onto Which different self-assembled monolayers are covalently attached. The adsorption of cytochrome c (a pos

  15. Cavity Ring-Down Spectroscopy of Hydrogen in the 784-852 NM Region and Corresponding Line Shape Implementation Into HITRAN

    Science.gov (United States)

    Tan, Yan; Wang, Jin; Cheng, Cunfeng; Liu, An-Wen; Hu, Shui-Ming; Wcislo, Piotr; Kochanov, Roman V.; Gordon, Iouli E.; Rothman, Laurence S.

    2016-06-01

    The hydrogen molecule as the most abundant neutral molecule in the universe is an important object of studies in different areas of science, especially astrophysics. The precision spectroscopy of the hydrogen molecule is particularly useful to verify the quantum electrodynamics theory (QED) in a molecular system. The electric quadrupole transitions of the second overtone of H_2 have been recorded with a high precision cavity ring-down spectrometer. A total of eight lines including the extremely weak S3(5) line in the 784-852 nm range have been observed. The line positions have been determined to an accuracy of 3 × 10-4 cm-1 and the line intensities were determined with a relative accuracy of about 1%. The deviations between the experimental and theoretical frequencies are less than 5 × 10-4 cm-1, which is much smaller than the claimed theoretical uncertainty of 0.0025cm-1. The data from this experiment along with other high-quality H_2 spectra have also been analyzed by the Hartmann-Tran profile as a test case for incorporating parametrization of this profile in the HITRAN database. It was incorporated in the new relational structure of the HITRAN database (www.hitran.org) and into the HITRAN Application Programming Interface (HAPI) for the case of H_2 spectra. Tan Y, Wang J, Cheng C-F, Zhao X-Q, Liu A-W, Hu S-M, J Mol Spectrosc 2014;300:60-4; Tran H, Ngo NH, Hartmann J-M, J Quant Spectrosc Radiat Transf 2013;129:199-203; Wcislo P, Gordon IE, Tran H, Tan Y, Hu S-M, Campargue A, et al., Accepted J Quant Spectrosc Radiat Transf HighRus Special Issue, 2015 Rothman LS, Gordon IE, Babikov Y, Barbe A, Chris Benner D, Bernath PF, et al., J Quant Spectrosc Radiat Transf 2013;130:4-50; Kochanov RV, Gordon IE, Rothman LS, Wcislo P, Hill C, Wilzewski JS, Submitted to J Quant Spectrosc Radiat Transf HighRus Special Issue, 2015.

  16. Sub-MHz accuracy measurement of the S(2) 2-0 transition frequency of D2 by Comb-Assisted Cavity Ring Down spectroscopy

    Science.gov (United States)

    Mondelain, D.; Kassi, S.; Sala, T.; Romanini, D.; Gatti, D.; Campargue, A.

    2016-08-01

    The line position of the very weak S(2) transition of deuterium in the 2-0 band has been measured with a Comb-Assisted Cavity Ring Down spectrometer. The high sensitivity spectra were recorded at 5 and 10 mbar with a Noise Equivalent Absorption, αmin, of 8 × 10-11 cm-1. The line positions at 5 and 10 mbar were measured with sub-MHz accuracy (460 and 260 kHz, respectively). After correction of the line pressure-shift, the frequency at zero pressure of the S(2) transition of the first overtone band was determined to be 187 104 299.51 ± 0.50 MHz. This value agrees within 1.7 MHz with the frequency obtained from the best available ab initio calculations and corresponds to only 15% of the claimed theoretical uncertainty.

  17. Carbon isotope analysis of dissolved organic carbon in fresh and saline (NaCl) water via continuous flow cavity ring-down spectroscopy following wet chemical oxidation

    Science.gov (United States)

    Conaway, Christopher; Thomas, Randal B.; Saad, Nabil; Thordsen, James J.; Kharaka, Yousif K.

    2015-01-01

    This work examines the performance and limitations of a wet chemical oxidation carbon analyser interfaced with a cavity ring-down spectrometer (WCO-CRDS) in a continuous flow (CF) configuration for measuring δ13C of dissolved organic carbon (δ13C-DOC) in natural water samples. Low-chloride matrix (ratio, high-salinity samples with sufficient DOC (>22.5 µg C/aliquot) may be analysed. The WCO-CRDS approach requires more total carbon (µg C/aliquot) than conventional CF-isotope ratio mass spectrometer, but is nonetheless applicable to a wide range of DOC concentration and water types, including brackish water, produced water, and basinal brines.

  18. High-accuracy continuous airborne measurements of greenhouse gases (CO2 and CH4) using the cavity ring-down spectroscopy (CRDS) technique

    OpenAIRE

    H Chen; J. Winderlich; C. Gerbig; Hoefer, A.; Rella, C. W.; E. R. Crosson; Pelt, A. D.; Steinbach, J.; O. Kolle; Beck, V.; Daube, B. C.; Gottlieb, E. W.; V. Y. Chow; G. W. Santoni; Wofsy, S. C.

    2010-01-01

    High-accuracy continuous measurements of greenhouse gases (CO2 and CH4) during the BARCA (Balanço Atmosférico Regional de Carbono na Amazônia) phase B campaign in Brazil in May 2009 were accomplished using a newly available analyzer based on the cavity ring-down spectroscopy (CRDS) technique. This analyzer was flown without a drying system or any in-flight calibration gases. Water vapor corrections associated with dilution and pressure-broadening effects for CO2 and CH4 were derived from labo...

  19. First Continuous High Frequency in Situ Measurements of CO2 and CH4 in Rwanda Using Cavity Ring-down Spectroscopy

    Science.gov (United States)

    Gasore, J.; DeWitt, L. H.; Prinn, R. G.

    2015-12-01

    Recent IPCC reports emphasize the lack of ground measurements of greenhouse gases on the African continent, despite Africa's significant emissions from agriculture and biomass burning as well as ongoing land use changes. We have established a greenhouse gas monitoring station in northern Rwanda that will be part of the Advanced Global Atmospheric Gases Experiment (AGAGE), a global network of high frequency long-term remote atmospheric measurement stations. Using a Picarro G2401 cavity ring-down analyzer, continuous measurements of CO2, CH4, and CO at a frequency of five seconds are being captured at this equatorial East African site. The measurement site is located near the Virunga mountains, a volcanic range in North-West Rwanda, on the summit of Mt. Mugogo (2507 m above sea level). Mt. Mugogo is located in a rural area 70km away from Kigali, the capital of Rwanda, and about 13km from the nearest town. From HYSPLIT 7-day back-trajectory calculations, we have determined that the station measures air masses originating from East and Central Africa, the Indian Ocean and occasionally from Southern Asia. Depending on the wind direction and local boundary layer height, measurements taken at Mt Mugogo are occasionally influenced by local sources, including emissions from the nearby city and wood fires from small rural settlements around the station. Here we present the first greenhouse gas measurement data from this unique and understudied location in Africa. Using the lagrangian transport and dispersion model FLEXPART, we derive the relationship between the observed mole fractions of CO2 and CH4 and our current knowledge of their sources and sinks, across this large African footprint.

  20. Simultaneous measurement of quality factor and wavelength shift by phase shift microcavity ring down spectroscopy

    CERN Document Server

    Cheema, M Imran; Hayat, Ahmad A; Peter, Yves-Alain; Armani, Andrea M; Kirk, Andrew G

    2012-01-01

    Optical resonant microcavities with ultra high quality factors are widely used for biosensing. Until now, the primary method of detection has been based upon tracking the resonant wavelength shift as a function of biological events. One of the sources of noise in all resonant-wavelength shift measurements is the noise due to intensity fluctuations of the laser source. An alternative approach is to track the change in the quality factor of the optical cavity by using phase shift cavity ring down spectroscopy, a technique which is insensitive to the intensity fluctuations of the laser source. Here, using biotinylated microtoroid resonant cavities, we show simultaneous measurement of the quality factor and the wavelength shift by using phase shift cavity ring down spectroscopy. These measurements were performed for disassociation phase of biotin-streptavidin reaction. We found that the disassociation curves are in good agreement with the previously published results. Hence, we demonstrate not only the applicatio...

  1. Determination of inlet transmission and conversion efficiencies for in situ measurements of the nocturnal nitrogen oxides, NO3, N2O5 and NO2, via pulsed cavity ring-down spectroscopy.

    Science.gov (United States)

    Fuchs, Hendrik; Dubé, William P; Ciciora, Steven J; Brown, Steven S

    2008-08-01

    Pulsed cavity ring-down spectroscopy is a highly sensitive method for direct absorption spectroscopy that has been applied to in situ detection of NO3, N2O5 and NO2 in the atmosphere from a variety of platforms, including ships, aircraft, and towers. In this paper, we report the development of schemes to significantly improve the accuracy of these measurements. This includes the following: (1) an overall improvement in the inlet transmission efficiencies (92 +/- 2% for NO3 and 97 +/- 1% for N2O5) achieved primarily through a reduction in the inlet residence time; and (2) the development of a calibration procedure that allows regular determination of these efficiencies in the field by addition of NO3 or N2O5 to the inlet from a portable source followed by conversion of NO3 to NO2. In addition, the dependence of the instrument's sensitivity and accuracy to a variety of conditions encountered in the field, including variations in relative humidity, aerosol loading, and VOC levels, was systematically investigated. The rate of degradation of N2O5 transmission efficiency on the inlet and filter system due to the accumulation of inorganic aerosol was determined, such that the frequency of filter changes required for accurate measurements could be defined. In the absence of aerosol, the presence of varying levels of relative humidity and reactive VOC were found to be unimportant factors in the instrument's performance. The 1 sigma accuracy of the NO3, N2O5, and NO2 measured with this instrument are -9/+12, -8/+11, +/- 6%, respectively, where the -/+ signs indicate that the actual value is low/high relative to the measurement. The largest contribution to the overall uncertainty is now due to the NO3 absorption cross section rather than the inlet transmission efficiency.

  2. Molecular elimination of Br{sub 2} in photodissociation of CH{sub 2}BrC(O)Br at 248 nm using cavity ring-down absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fan He; Tsai, Po-Yu; Lin, King-Chuen [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan and Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Lin, Cheng-Wei; Yan, Chi-Yu; Yang, Shu-Wei; Chang, A. H. H. [Department of Chemistry, National Dong Hwa University, Shoufeng, Hualien 974, Taiwan (China)

    2012-12-07

    The primary elimination channel of bromine molecule in one-photon dissociation of CH{sub 2}BrC(O)Br at 248 nm is investigated using cavity ring-down absorption spectroscopy. By means of spectral simulation, the ratio of nascent vibrational population in v = 0, 1, and 2 levels is evaluated to be 1:(0.5 {+-} 0.1):(0.2 {+-} 0.1), corresponding to a Boltzmann vibrational temperature of 581 {+-} 45 K. The quantum yield of the ground state Br{sub 2} elimination reaction is determined to be 0.24 {+-} 0.08. With the aid of ab initio potential energy calculations, the obtained Br{sub 2} fragments are anticipated to dissociate on the electronic ground state, yielding vibrationally hot Br{sub 2} products. The temperature-dependence measurements support the proposed pathway via internal conversion. For comparison, the Br{sub 2} yields are obtained analogously from CH{sub 3}CHBrC(O)Br and (CH{sub 3}){sub 2}CBrC(O)Br to be 0.03 and 0.06, respectively. The trend of Br{sub 2} yields among the three compounds is consistent with the branching ratio evaluation by Rice-Ramsperger-Kassel-Marcus method. However, the latter result for each molecule is smaller by an order of magnitude than the yield findings. A non-statistical pathway so-called roaming process might be an alternative to the Br{sub 2} production, and its contribution might account for the underestimate of the branching ratio calculations.

  3. Cavity ring-down technique for measurement of reflectivity of high reflectivity mirrors with high accuracy

    Indian Academy of Sciences (India)

    G Sridhar; Sandeep K Agarwalla; Sunita Singh; L M Gantayet

    2010-12-01

    A simple, accurate and reliable method for measuring the reflectivity of laser-grade mirrors ( > 99.5 %) based on cavity ring-down (CRD) technique has been success-fully demonstrated in our laboratory using a pulsed Nd:YAG laser. A fast photomultiplier tube with an oscilloscope was used to detect and analyse the CRD signal. The cavity decay times were measured for three cavities formed by a combination of three mirror pairs. The absolute reflectivities 1, 2, 3 were determined to be 99.94%, 99.63%, 99.52% at normal incidence. The reflectivity of mirrors is measured to an accuracy of 0.01%.

  4. Chiral cavity ring down polarimetry: Chirality and magnetometry measurements using signal reversals

    Energy Technology Data Exchange (ETDEWEB)

    Bougas, Lykourgos; Sofikitis, Dimitris; Katsoprinakis, Georgios E.; Spiliotis, Alexandros K.; Rakitzis, T. Peter, E-mail: ptr@iesl.forth.gr [Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, 71110 Heraklion, Crete (Greece); Department of Physics, University of Crete, 71003 Heraklion, Crete (Greece); Tzallas, Paraskevas; Loppinet, Benoit [Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, 71110 Heraklion, Crete (Greece)

    2015-09-14

    We present the theory and experimental details for chiral-cavity-ring-down polarimetry and magnetometry, based on ring cavities supporting counterpropagating laser beams. The optical-rotation symmetry is broken by the presence of both chiral and Faraday birefringence, giving rise to signal reversals which allow rapid background subtractions. We present the measurement of the specific rotation at 800 nm of vapors of α-pinene, 2-butanol, and α-phellandrene, the measurement of optical rotation of sucrose solutions in a flow cell, the measurement of the Verdet constant of fused silica, and measurements and theoretical treatment of evanescent-wave optical rotation at a prism surface. Therefore, these signal-enhancing and signal-reversing methods open the way for ultrasensitive polarimetry measurements in gases, liquids and solids, and at surfaces.

  5. Cavity-enhanced spectroscopies

    CERN Document Server

    van Zee, Roger

    2003-01-01

    ""Cavity-Enhanced Spectroscopy"" discusses the use of optical resonators and lasers to make sensitive spectroscopic measurements. This volume is written by the researcchers who pioneered these methods. The book reviews both the theory and practice behind these spectroscopic tools and discusses the scientific discoveries uncovered by these techniques. It begins with a chapter on the use of optical resonators for frequency stabilization of lasers, which is followed by in-depth chapters discussing cavity ring-down spectroscopy, frequency-modulated, cavity-enhanced spectroscopy, intracavity spectr

  6. The application of a cavity ring-down spectrometer to measurements of ambient ammonia using traceable primary standard gas mixtures

    Science.gov (United States)

    Martin, Nicholas A.; Ferracci, Valerio; Cassidy, Nathan; Hoffnagle, John A.

    2016-08-01

    A correction for the undesirable effects of direct and indirect cross-interference from water vapour on ammonia (NH3) measurements was developed using an optical laser sensor based on cavity ring-down spectroscopy. This correction relied on new measurements of the collisional broadening due to water vapour of two NH3 spectral lines in the near infra-red (6548.6 and 6548.8 cm-1), and on the development of novel stable primary standard gas mixtures (PSMs) of ammonia prepared by gravimetry in passivated gas cylinders at 100 μmol mol-1. The PSMs were diluted dynamically to provide calibration mixtures of dry and humidified ammonia atmospheres of known composition in the nmol mol-1 range and were employed as part of establishing a metrological traceability chain to improve the reliability and accuracy of ambient ammonia measurements. The successful implementation of this correction will allow the extension of this rapid on-line spectroscopic technique to exposure chamber validation tests under controlled conditions and ambient monitoring in the field.

  7. An optic fiber sensor for multiple gases based on fiber loop ring-down spectroscopy and microring resonator arrays

    Science.gov (United States)

    Zhang, Xin; Jian, Jia-wen; Zheng, Yan-gong; Jin, Han; Zou, Jie

    2016-07-01

    A high-sensitivity sensor for multiple gases based on microring array filter and fiber loop ring-down spectroscopy system is proposed and demonstrated. The parameters of the resonators are designed so that the filtered signal from a broadband light source can be tuned with an absorption spectral line of gas. Therefore, through adding microring resonators horizontally and vertically, the number of target gases and filter range are increased. In this research, in the broad spectral range of about 0.9 μm, only the absorption spectral lines of target gases are filtered. The simulation results show that three target gases, CH4, CO2 and HF, can be simultaneously detected by the sensing system. Owing to the fiber loop ring-down spectroscopy, the whole system is optimized in mini-size and sensitivity, and we can choose different sensing methods to enhance the measurement accuracy for high and low concentration conditions.

  8. A continuous stream flash evaporator for the calibration of an IR cavity ring down spectrometer for isotopic analysis of water

    CERN Document Server

    Gkinis, Vasileios; Johnsen, Sigfus J; Blunier, Thomas

    2014-01-01

    A new technique for high resolution simultaneous isotopic analysis of $\\delta^{18}\\mathrm{O}$ and $\\delta\\mathrm{D}$ in liquid water is presented. A continuous stream flash evaporator has been designed that is able to vaporise a stream of liquid water in a continuous mode and deliver a stable and finely controlled water vapour sample to a commercially available Infra Red Cavity Ring Down Spectrometer. Injection of sub $\\mu l$ amounts of the liquid water is achieved by pumping liquid water sample through a fused silica capillary and instantaneously vaporising it with a 100% efficiency in a home made oven at a temperature of $170 ^{o}$C. The system's simplicity, low power consumption and low dead volume together with the possibility for automated unattended operation, provides a solution for the calibration of laser instruments performing isotopic analysis of water vapour. Our work is mainly driven by the possibility to perform high resolution on line water isotopic analysis on Continuous Flow Analysis systems ...

  9. Portable low power cavity ring-down spectrometer for precise measurement of carbon dioxide, methane and water vapor

    Science.gov (United States)

    Fleck, Derek; Hoffnagle, John; Tan, Sze; He, Yonggang

    2016-05-01

    The necessity for monitoring of changing levels of greenhouse gases (GHGs) is clearly evident now more than ever. This has led to large deployments of analytical devices to most remote locations as well as the most densely populated regions around the world. Both large and small scale projects have forced new and old technologies to be pushed to their limits to obtain the highest performing measurements while maintaining a cost effective way to remotely monitor changes in atmospheric concentrations. In order to accomplish these strict guidelines, we present a low-power cavity ring-down spectrometer that measures Carbon Dioxide, Methane and water vapor which can achieve measurements with precisions lower than 20ppb of CO2 and 50ppt of CH4. Comparing to hundreds of watts needed in conventional CRDS design, we demonstrate that the high performance can be achieved with less than 25W. Stability of these measurements has allowed for averaging times of up to 3hr, yielding measurements of methane concentrations with precisions down to 40ppt. This is accomplished utilizing an FSR based frequency scale to determine an absolute frequency scale for these absorption features. Taking advantage of this faster, and less costly measurement technique of CRDS shows future promise with applications spanning scientific and industrial analyses, from isotopes to trace gases.

  10. Determination of δ2H and δ18O in mineral water based on Cavity Ring-Down Spectrometry

    Science.gov (United States)

    Tonietto, G.; Godoy, J.; Godoy, M. L.

    2013-12-01

    Stable isotopes of water are proven indicators, tracers and recorders of processes that affect the hydrologic cycle. Measurements of the stable isotope ratios (δ2H, δ18O and δ17O) of both liquid water and water vapor are widely used in hydrology, atmospheric sciences, and biogeochemistry to determine the migration of water through an ecosystem. Application of the method to Brazilian bottled mineral water has shown that it is possible to trace the origin of the water to at least the state level within Brazilian geographical regions. National and regional meteoric water lines were constructed with substantial differences between geographical regions, in particular for the central region of the country, with a slope coefficient of approximately seven and no deuterium excess. The repeatability, reproducibility and accuracy of the direct measurement of δ2H and δ18O isotopes in water samples were evaluated using Cavity Ring-Down Spectrometry, and values comparable with the Isotopic Ratio Mass Spectrometry were obtained. Memory effect correction was negligible after five successive injections, and the time for each sample analysis was approximately 7 minutes. The new high throughput method measures isotopologues of water with a typical precision of better than 0.15‰ for δ18O and better than 0.6‰ for δ2H.

  11. H2S interference on CO2 isotopic measurements using a Picarro G1101-i cavity ring-down spectrometer

    Directory of Open Access Journals (Sweden)

    K. Malowany

    2015-06-01

    Full Text Available Cavity ring-down spectrometers (CRDS have the capacity to make isotopic measurements of CO2 where concentrations range from atmospheric (~ 400 ppm to 6000 ppm. Following field trials, it has come to light that the spectrographic lines used for CO2 have an interference with elevated (higher than ambient amounts of hydrogen sulfide (H2S, which causes significant depletions in the δ13C measurement by the CRDS. In order to deploy this instrument in environments with elevated H2S concentrations (i.e., active volcanoes, we require a robust method for eliminating this interference. Controlled experiments using a Picarro G1101-i optical spectrometer were done to characterize the H2S interference at varying CO2 and H2S concentrations. The addition of H2S to a CO2 standard gas reveals an increase in the 12CO2 concentration and a more significant decrease in the 13CO2 concentration, resulting in a depleted δ13C value. Reacting gas samples containing H2S with copper prior to analysis can eliminate this effect. However, experiments also revealed that the addition of H2S to CO2 results in the formation of carbonyl sulfide (OCS and carbon disulfide (CS2, causing a decrease in the overall CO2 concentration without affecting the δ13C value. It is important for future work with CRDS, particularly in volcanic regions where H2S is abundant, to be aware of the H2S interference on the CO2 spectroscopic lines and to remove all H2S prior to analysis. We suggest employing a scrub composed of copper to remove H2S from all gas samples that have concentrations in excess of 1 ppb.

  12. Methane Fingerprinting: Isotopic Methane and Ethane-to-Methane Ratio Analysis Using a Cavity Ring-Down Spectrometer

    Science.gov (United States)

    Saad, Nabil; Fleck, Derek; Hoffnagle, John

    2016-04-01

    Emissions of Natural gas, and methane (CH4) specifically, have come under increased scrutiny by virtue of methane's 28-36x greenhouse warming potential compared to carbon dioxide (CO2) while accounting for 10% of the total greenhouse gas emissions in the US. Large uncontrolled leaks, such as the recent Aliso Canyon leak, originating from uncapped wells, coal mines and storage facilities have increased the total global contribution of methane missions even further. Determining the specific fingerprint of methane sources, by quantifying δ13C values and C2:C1 ratios, provides the means to understand methane producing processes and allows for sources of methane to be mapped and classified through these processes; i.e. biogenic vs. thermogenic, wet vs dry. In this study we present a fully developed Cavity Ring-Down Spectrometer (CRDS) that precisely measures 12CH4 concentration and its 13CH4 isotope concentration, yielding δ13C measurements, C2H6 concentration, along with CO2 and H2O. This provides real-time continuous measurements without an upfront separation requirement or multiple analyses to derive the origin of the gas samples. The highly sensitive analyzer allows for measurements of scarce molecules down to sub-ppb 1-σ precision in 5 minutes of measurement: with CH4 <0.1ppb, δ13C <1‰ C2H6 <1ppb and CO2 <1ppm. To complement this work, we provide the analysis of different methane sources providing a 2-dimensional mapping of methane sources as functions of δ13C and C2:C1 ratios, which can be thought of as a modified Bernard Plot. This dual ratio mapping can be used to discriminate between naturally occurring biogenic methane sources, naturally occurring enriched thermogenic sources, and natural gas distribution sources. This also shows future promise in aiding gas and oil exploration, in distinguishing oil vs coal gases, as well as a valuable tool in the development of methane sequestration.

  13. A Mid-IR, Wavelength-Scanned, Cavity Ring-Down Spectrometer for Continuous Trace N2O and Nitrogen Isotope Measurements

    Science.gov (United States)

    Farinas, A. D.; Balslev-Clausen, D.; Crosson, E.

    2009-12-01

    Nitrous oxide (N2O) is an important trace atmospheric gas with both a greenhouse effect and a role in ozone depletion. The globally averaged surface abundance of N2O was 314 ppb in 1998, corresponding to a global burden of 1510 TgN. The atmospheric burden of nitrous oxide continues to increase by about 0.25%/yr. The detailed impact of N2O cannot, however, be accurately assessed or mitigated as there is currently no quantitative analysis tool for N2O (and isotopes of nitrogen) that combines the requisite precision (sub-ppbv) with the rugged simplicity, low-drift and hands-free operation necessary for real-time field studies at unattended monitoring stations. In fact, the only laboratory tool capable of delivering this sensitivity - gas chromatography - is slow, relatively complex and labor intensive. Further, the utility of in-situ atmospheric nitrogen isotope analysis is practically nonexistent due to the impracticality of using isotope ratio mass spectrometry equipment in the field. We are addressing these needs by extending the capabilities of Picarro’s wavelength-scanned, cavity ring-down spectroscopy (WS-CRDS) instrumentation to cover N2O and nitrogen isotopes. These portable gas and isotope analyzers currently utilize one or more tunable, narrowband, near-infrared lasers to provide ppbv-level detection of several gases including CO2, CH4, H2O and various isotopes. However, detection of N2O at the ppbv level requires the use of longer, mid-infrared wavelengths. The advent of compact, tunable, quantum cascade lasers (QCLs) operating at room temperature in the mid-IR has recently enabled analyzers incorporating them to reach these sensitivities. Moreover, the long effective optical path length - over 15km - of WS-CRDS and corresponding high signal-to-noise ratio inherent in this time-based measurement means that high precision can be achieved with simple thermoelectric cooling of the laser and detector. We report the performance of this first-generation WS

  14. Bulk Stable Isotope Analysis of Carbon from Solids and Liquids using an Elemental Analyzer Coupled to a Wavelength-Scanned Cavity Ring-Down Spectrophotometer

    Science.gov (United States)

    Saad, N.; Rella, C.; van Pelt, A.

    2009-04-01

    We report here on the novel employment of a small footprint Wavelength-Scanned Cavity Ring-Down Spectrometer (WS-CRDS) interfaced to an elemental analyzer for the measurement of the bulk isotopic carbon signature in plants and food products. The current system provides an inexpensive alternative with unparalleled ease-of-use as compared to standard methods using the more complex analytical instrumentation of isotope ratio mass spectrometry. A precision of carbon isotopic ratio measurements of less than 1 permil was achieved in minutes of measurement time. Such precision readily distinguishes the isotopic carbon signatures of a variety of environmental and agricultural products from different origins, providing information about food authenticity and climate changes effect on plant physiology.

  15. Development of a New N2O/CO Cavity Ring-Down Spectrometer for sub-ppb Ambient Gas Monitoring

    Science.gov (United States)

    Leggett, G. A.; Saad, N.; Zhou, J.; Hoffnagle, J.; Fleck, D.

    2015-12-01

    With a global warming potential of nearly 300, N2O is a critically important greenhouse gas, contributing about 5% of the US total GHG emissions. Agriculture soil management practices are the dominant source of anthropogenic N2O emissions, contributing nearly 3/4ths of US N2O emissions. In urban areas, vehicle tailpipe emissions and waste water treatment plants are significant sources of N2O. We report here a new mid-infrared laser-based cavity ring-down spectrometer that was recently developed to measure sub-ppb ambient concentrations of two key greenhouse gas species, N2O and CO, simultaneously. It combines a quantum cascade laser with a proprietary 3-mirror optical cavity. The new optical analyzer was set up to monitor nitrous oxide and carbon monoxide, along with CO2 and CH4, in ambient air obtained from a 10m tower in Santa Clara, California. In the data collected, the contribution from traffic and a nearby sewage treatment facility was evident.

  16. A new cavity ring-down instrument for airborne monitoring of N2O5, NO3, NO2 and O3 in the upper troposphere lower stratosphere

    Science.gov (United States)

    Ruth, Albert A.; Brown, Steven S.; Dinesan, Hemanth; Dubé, William P.; Goulette, Marc; Hübler, Gerhard; Orphal, Johannes; Zahn, Andreas

    2016-04-01

    The chemistry of NO3 and N2O5 is important to the regulation of both tropospheric and stratospheric ozone. In situ detection of NO3 and N2O5 in the upper troposphere lower stratosphere (UTLS) represents a new scientific direction as the only previous measurements of these species in this region of the atmosphere has been via remote sensing techniques. Because both the sources and the sinks for NO3 and N2O5 are potentially stratified spatially, their mixing ratios, and their influence on nitrogen oxide and ozone transport and loss at night can show large variability as a function of altitude. Aircraft-based measurements of heterogeneous N2O5 uptake in the lower troposphere have uncovered a surprising degree of variability in the uptake coefficient [1], but there are no corresponding high altitude measurements.The UTLS is routinely sampled by the IAGOS-CARIBIC program (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container, www.caribic-atmospheric.com), a European infrastructural program with the aim of studying the chemistry and transport across this part of the atmosphere. An airfreight container with 15 different automated instruments from 8 European research partners is utilized on board a commercial Lufthansa airbus 340-600 to monitor ~ 100 atmospheric species (trace gases and aerosol parameters) in the UTLS. The instrumentation in the CARIBIC container is now to be supplemented by a new cavity ring-down device for monitoring nitrogen oxides, jointly developed by researchers from Cork (Ireland), Boulder (USA) and Karlsruhe (Germany). The compact and light-weight instrument is designed to monitor not only NO3 and N2O5, but also NO2 and O3. The detection is based on 4 high-finesse optical cavities (cavity length ~ 44 cm). Two cavities are operated at 662 nm (maximum absorption of NO3), the other two at 405 nm (maximum absorption of NO2). The inlet to one of the (662)-cavities is heated in order to thermally decompose N2O5

  17. Diode laser-based cavity ring-down instrument for NO3, N2O5, NO, NO2 and O3 from aircraft

    Directory of Open Access Journals (Sweden)

    T. B. Ryerson

    2011-03-01

    Full Text Available This article presents a diode laser based, cavity ring-down spectrometer for simultaneous in situ measurements of four nitrogen oxide species, NO3, N2O5, NO, NO2, as well as O3, designed for deployment on aircraft. The instrument measures NO3 and NO2 by optical extinction at 662 nm and 405 nm, respectively; N2O5 is measured by thermal conversion to NO3, while NO and O3 are measured by chemical conversion to NO2. The instrument has several advantages over previous instruments developed by our group for measurement of NO2, NO3 and N2O5 alone, based on a pulsed Nd:YAG and dye laser. First, the use of continuous wave diode lasers reduces the requirements for power and weight and eliminates hazardous materials. Second, detection of NO2 at 405 nm is more sensitive than our previously reported 532 nm instrument, and does not have a measurable interference from O3. Third, the instrument includes chemical conversion of NO and O3 to NO2 to provide measurements of total NOx (= NO + NO2 and Ox (= NO2 + O3 on two separate channels; mixing ratios of NO and O3 are determined by subtraction of NO2. Finally, all five species are calibrated against a single standard based on 254 nm O3 absorption to provide high accuracy. Disadvantages include an increased sensitivity to water vapor on the 662 nm NO3 and N2O5 channels and a modest reduction in sensitivity for these species compared to the pulsed laser instrument. The measurement precision for both NO3 and N2O5 is below 1 pptv (2σ, 1 s and for NO, NO2 and O3 is 170, 46, and 56 pptv (2σ, 1 s respectively. The NO and NO2 measurements are less precise than research-grade chemiluminescence instruments. However, the combination of these five species in a single instrument, calibrated to a single analytical standard, provides a complete and accurate picture of nighttime nitrogen oxide chemistry. The instrument performance is demonstrated using data acquired during a recent field campaign in California.

  18. Diode laser-based cavity ring-down instrument for NO3, N2O5, NO, NO2 and O3 from aircraft

    Directory of Open Access Journals (Sweden)

    T. B. Ryerson

    2011-06-01

    Full Text Available This article presents a diode laser-based, cavity ring-down spectrometer for simultaneous in situ measurements of four nitrogen oxide species, NO3, N2O5, NO, NO2, as well as O3, designed for deployment on aircraft. The instrument measures NO3 and NO2 by optical extinction at 662 nm and 405 nm, respectively; N2O5 is measured by thermal conversion to NO3, while NO and O3 are measured by chemical conversion to NO2. The instrument has several advantages over previous instruments developed by our group for measurement of NO2, NO3 and N2O5 alone, based on a pulsed Nd:YAG and dye laser. First, the use of continuous wave diode lasers reduces the requirements for power and weight and eliminates hazardous materials. Second, detection of NO2 at 405 nm is more sensitive than our previously reported 532 nm instrument, and does not have a measurable interference from O3. Third, the instrument includes chemical conversion of NO and O3 to NO2 to provide measurements of total NOx (= NO + NO2 and Ox (= NO2 + O3 on two separate channels; mixing ratios of NO and O3 are determined by subtraction of NO2. Finally, all five species are calibrated against a single standard based on 254 nm O3 absorption to provide high accuracy. Disadvantages include an increased sensitivity to water vapor on the 662 nm NO3 and N2O5 channels and a modest reduction in sensitivity for these species compared to the pulsed laser instrument. The in-flight detection limit for both NO3 and N2O5 is 3 pptv (2 σ, 1 s and for NO, NO2 and O3 is 140, 90, and 120 pptv (2 σ, 1 s respectively. Demonstrated performance of the instrument in a laboratory/ground based environment is better by approximately a factor of 2–3. The NO and NO2 measurements are less precise than research-grade chemiluminescence instruments. However, the combination of these five species in a single instrument, calibrated to a single analytical standard, provides a complete and accurate picture of nighttime nitrogen oxide

  19. 光腔衰荡光谱方法探测痕量一氧化碳气体%Trace Carbon Monoxide Detection with a Cavity Ring-Down Spectrometer

    Institute of Scientific and Technical Information of China (English)

    陈兵; 周泽义; 康鹏; 刘安雯; 胡水明

    2015-01-01

    基于通讯波段的分布式反馈半导体激光器(DFB),搭建了一套光腔衰荡光谱仪(CRDS)。衰荡光腔由一对反射率高于99.997%的高反镜组成,衰荡腔长约为130 cm ,空腔衰荡时间约为150μs。当光谱平均次数达到1000次时,光谱仪灵敏度(最小可探测吸收系数)达到5×10-12 cm -1。利用热隔绝的方式稳定衰荡腔长,并使用衰荡光腔自身作为光学标准具,来标定光谱的频率:利用反馈式光谱扫描程序步进改变激光器频率,使之与衰荡腔的纵模频率逐一匹配,从而实现所测得光谱的自动标定。通过测量一氧化碳分子在1.565μm附近的吸收光谱,测定气体中一氧化碳的含量。将光谱测量结果和标准样品中的一氧化碳含量进行对比,对装置的定量精度进行了检验,表明其对一氧化碳的探测极限达4 ppbv。利用该装置对实际大气中一氧化碳的含量进行了实时监测。%A cavity ring‐down spectrometer (CRDS) was built based on telecom distributed feedback (DFB) diode lasers .The ring down cavity was formed by mirrors of 99.997% reflectivity with a separation of 130 cm ,with an empty ring down time of about 150 μs .A minimum detectable absorption coefficient of 5 × 10-12 cm -1 was obtained by averaging about 1 000 recorded spectra .The ring down cavity is thermo‐isolated ,and used as an interferometer to calibrate the recorded spectrum .A feedback control scheme was applied to step scan the laser frequency ,successively matching each of the longitudinal modes of the cavity . By measuring the CO contents in a standard gas sample ,the quantitative capability of the CRDS instrument was demonstrated , and a CO detection limit of 4 ppb was achieved .The instrument was applied to monitor the CO concentration in ambient air .

  20. Cavity Ring-Down Spectroscopy Lite: A Low Power Analyzer for measuring Carbon Dioxide, Methane and Water Vapor

    Science.gov (United States)

    Fleck, Derek; Hoffnagle, John; Tan, Sze; He, Yonggang

    2016-04-01

    Greenhouse gas accumulation has contributed to the changes in environments across the globe. Monitoring these fluctuations on global and local scales will allow scientists to better understand contributions that are made from nature and humans. This has led to the deployment of analytical instrumentation of all types to the most remote areas as well as the most densely populated areas. This however requires instruments to be precise, versatile, robust, and most importantly have power requirements that are as not limited by location, i.e. low enough power consumption to run off of batteries or even solar array. Here we present a full greenhouse gas analyzer that utilizes a new method of CRDS to measure carbon dioxide, methane and water vapor that consumes only 25W and still maintains long term stability to allow for averaging time of over 3 hours. Measurements have a 1-σ precision of 30 ppb for CO2 and 300 ppt of CH4 with 5 minutes of averaging; and with measurements of 3 hour averages reaching precisions down to 40ppt of methane. Additionally this new flavor of CRDS has allowed for an overall increase in measurement dynamic range from traditional CW-CRDS measuring methane up to 1000ppm and carbon dioxide up to several percent. We will present supplemental data acquired using this Santa Clara, CA.

  1. Cavity Ring-Down Spectroscopy Lite: A Low Power Analyzer for measuring Carbon Dioxide, Methane and Water Vapor

    Science.gov (United States)

    Fleck, Derek; Hoffnagle, John; Tan, Sze; He, Yonggang

    2016-04-01

    Greenhouse gas accumulation has contributed to the changes in environments across the globe. Monitoring these fluctuations on global and local scales will allow scientists to better understand contributions that are made from nature and humans. This has led to the deployment of analytical instrumentation of all types to the most remote areas as well as the most densely populated areas. This however requires instruments to be precise, versatile, robust, and most importantly have power requirements that are as not limited by location, i.e. low enough power consumption to run off of batteries or even solar array. Here we present a full greenhouse gas analyzer that utilizes a new method of CRDS to measure carbon dioxide, methane and water vapor that consumes only 25W and still maintains long term stability to allow for averaging time of over 3 hours. Measurements have a 1-σ precision of 30 ppb for CO2 and 300 ppt of CH4 with 5 minutes of averaging; and with measurements of 3 hour averages reaching precisions down to 40ppt of methane. Additionally this new flavor of CRDS has allowed for an overall increase in measurement dynamic range from traditional CW-CRDS measuring methane up to 1000ppm and carbon dioxide up to several percent. We will present supplemental data acquired using this <11 kg analyzer, including soil respirations using closed static chambers and 10m tower measurements from Santa Clara, CA.

  2. Precise and accurate d13C analysis of rock samples using Flash Combustion–Cavity Ring Down Laser Spectroscopy

    DEFF Research Database (Denmark)

    Balslev-Clausen, David Morten; Dahl, Tais Wittchen; Saad, Nabil;

    2013-01-01

    The ratio of 13C to 12C in marine sedimentary rocks holds important clues to the evolution of the carbon cycle through Earth history. Isotopic analyses are traditionally carried out using isotope ratio mass spectrometry (IRMS), but this technique is both labor-intensive, expensive and requires...

  3. Cavity-Enhanced Frequency-Agile Rapid Scanning (fars) Spectroscopy: Measurement Principles

    Science.gov (United States)

    Hodges, Joseph T.; Long, David A.; Truong, Gar-Wing; Douglass, Kevin O.; Maxwell, Stephen E.; Zee, Roger Van; Plusquellic, David F.

    2013-06-01

    We present the principles of frequency-agile, rapid scanning (FARS) spectroscopy, a new technique for high-bandwidth, cavity-enhanced, laser absorption measurements. This method enables a visible or near-infrared probe laser beam to be frequency tuned over several tens of GHz using a microwave source, a waveguide phase modulator and a filter cavity. For the types of cavity-enhanced methods discussed here, the optical resonator itself is used to select a single sideband of the modulated laser spectrum, obviating the need for a separate filter cavity. FARS offers several important advantages over conventional cw laser tuning methods based on thermal or mechanical methods. These include, high speed tuning with sub-ms switching times, the ability to select arbitrary frequency steps or chirp rates, and the realization of a spectrum detuning axis with sub-kHz level precision. We discuss how FARS can be applied to cavity ring-down spectroscopy and other cavity-enhanced methods to enable rapid and accurate measurements of line parameters and to give noise-equivalent absorption coefficients at the 10^{-12} cm^{-1} Hz^{-1/2} level.

  4. Line-Parameter Measurements and Stringent Tests of Line-Shape Models Based on Cavity-Enhanced Absorption Spectroscopy

    Science.gov (United States)

    Bielska, Katarzyna; Fleisher, Adam J.; Hodges, Joseph T.; Lin, Hong; Long, David A.; Reed, Zachary D.; Sironneau, Vincent; Truong, Gar-Wing; Wójtewicz, Szymon

    2014-06-01

    Laser methods that are based on cavity-enhanced absorption spectroscopy (CEAS) are well-suited for measuring molecular line parameters under conditions of low optical density, and as such they are complementary to broadband Fourier-transform spectroscopy (FTS) techniques. Attributes of CEAS include relatively low detection limits, accurate and precise detuning axes and high fidelity measurements of line shape. In many cases these performance criteria are superior to those obtained using direct laser absorption spectroscopy and FTS-based systems. In this presentation we will survey several examples of frequency-stabilized cavity ring-down spectroscopy (FS-CRDS)1 measurements obtained with laser spectrometers developed at the National Institute of Standards and Technology (NIST) in Gaithersburg Maryland. These experiments, which are motivated by atmospheric monitoring and remote-sensing applications that require high-precision and accuracy, involve nearinfrared transitions of carbon dioxide, water, oxygen and methane. We discuss spectra with signal-to-noise ratios exceeding 106, frequency axes with absolute uncertainties in the 10 kHz to 100 kHz range and linked to a Cs clock, line parameters with relative uncertainties at the 0.2 % level and isotopic ratios measured with a precision of 0.03 %. We also present FS-CRDS measurements of CO2 line intensities which are measured at atmospheric concentration levels and linked to gravimetric standards for CO2 in air, and we quantify pressure-dependent deviations between various theoretical line profiles and measured line shapes. Finally we also present recent efforts to increase data throughput and spectral coverage in CEAS experiments. We describe three new high-bandwidth CEAS techniques including frequency-agile, rapid scanning spectroscopy (FARS)2, which enables continuous-wave measurements of cavity mode linewidth and acquisition of ringdown decays with no dead time during laser frequency tuning, heterodyne

  5. Carbon isotopic analysis of dissolved organic carbon in produced water brines by wet chemical oxidation and cavity ring-down spectroscopy

    Science.gov (United States)

    Thomas, B.; Conaway, C.; Kharaka, Y. K.; Saad, N.

    2012-12-01

    We have adapted the Picarro iTOC CRDS isotope analyzer for analysis of produced water brines via wet chemical persulfate oxidation. In particular, we developed strategies and techniques for overcoming the limitation imposed by low oxidation efficiencies due to the chloride ion interference with persulfate oxidation. These techniques are important for understanding the origin of dissolved organic carbon in subsurface fluids from oilfields, as a tracer of fracking fluids in groundwater, and in interpreting changes in groundwater DOC as a result of microbial activity including oil biodegradation or microbially enhanced oil recovery. We describe the limitations of this new instrument for the analysis of DOC in brines including sample requirements, matrix effects, and the effect of DOC composition on reaction efficiency and isotopic measurements. We compare strategies including anion exchange cartridges, persulfate reactant concentrations, and reaction time. The CRDS analysis of DOC in brines is a useful tool for understanding the origin and fate of DOC and is a potentially powerful tool to identifiy evidence of contamination due to hydrofracturing chemicals that have a distinctive carbon isotopic signature relative to natural brine.

  6. The theory of measuring hydroperoxyl radical by cavity ring- down spectroscopy%衰荡光谱法测量OH自由基的理论研究

    Institute of Scientific and Technical Information of China (English)

    聂劲松; 张为俊; 杨顒; 王沛; 胡欢陵

    2000-01-01

    提出了一种用衰荡光谱法测量对流层OH自由基的新方法,并从理论上推导出OH自由基浓度与衰荡时间的关系,讨论了该方法的可行性和灵敏度,分析了各种干扰因素对测量的影响,认为该方法与传统测量OH自由基的方法相比优势较为明显.

  7. Performance assessment of a cavity ring-down laser spectrometer: achieving better precision and accuracy in the measurement of δ18O and δ2H in liquid water samples

    International Nuclear Information System (INIS)

    The development of new isotopic laser-based analyzers currently represents a clear alternative to conventional isotope ratio mass spectrometers. However, this analytical technique also suffers some disadvantages such as the memory effect, problems related to the overall stability of the equipment and other issues associated with the injection system, essentially regarding the syringe's longevity. This paper aims to minimize these disadvantages in order to increase the overall performance, in terms of precision and accuracy, of these kinds of analyzers. The main results of the experiments carried out in this paper have shown that: (i) the minimum number of discarded injections needed to eliminate the memory effect can be determined just considering the expected isotopic signature difference between two consecutive samples; (ii) both accuracy and precision of the isotopic measurements increase with increasing injection volume up to 2.1–2.2 µL; (iii) it is possible to extend the syringe lifetime by almost a factor of 6 by using n-methyl 2-pyrrolidone as a lubricant. Besides, it has been concluded that, by using the appropriate procedure, the main disadvantages associated with CRDS laser spectroscopy analyzers can be minimized, achieving measurement accuracy and precision of the order of ±0.05 ‰ for δ18O and ±0.3 ‰ for δ2H. (paper)

  8. Cavity-enhanced dual-comb spectroscopy

    CERN Document Server

    Bernhardt, Birgitta; Jacquet, Patrick; Jacquey, Marion; Kobayashi, Yohei; Udem, Thomas; Holzwarth, Ronald; Guelachvili, Guy; Hänsch, Theodor W; Picqué, Nathalie

    2009-01-01

    The sensitivity of molecular fingerprinting is dramatically improved when placing the absorbing sample in a high-finesse optical cavity, thanks to the large increase of the effective path-length. As demonstrated recently, when the equidistant lines from a laser frequency comb are simultaneously injected into the cavity over a large spectral range, multiple trace-gases may be identified within a few milliseconds. Analyzing efficiently the light transmitted through the cavity however still remains challenging. Here, a novel approach, cavity-enhanced frequency comb Fourier transform spectroscopy, fully overcomes this difficulty and measures ultrasensitive, broad-bandwidth, high-resolution spectra within a few tens of $\\mu$s. It could be implemented from the Terahertz to the ultraviolet regions without any need for detector arrays. We recorded, within 18 $\\mu$s, spectra of the 1.0 $\\mu$m overtone bands of ammonia spanning 20 nm with 4.5 GHz resolution and a noise-equivalent-absorption at one-second-averaging per ...

  9. Molecular Laser Spectroscopy as a Tool for Gas Analysis Applications

    OpenAIRE

    Javis Anyangwe Nwaboh; Thibault Desbois; Daniele Romanini; Detlef Schiel; Olav Werhahn

    2011-01-01

    We have used the traceable infrared laser spectrometric amount fraction measurement (TILSAM) method to perform absolute concentration measurements of molecular species using three laser spectroscopic techniques. We report results performed by tunable diode laser absorption spectroscopy (TDLAS), quantum cascade laser absorption spectroscopy (QCLAS), and cavity ring down spectroscopy (CRDS), all based on the TILSAM methodology. The measured results of the different spectroscopic techniques are ...

  10. Cavity-Enhanced Ultrafast Transient Absorption Spectroscopy

    CERN Document Server

    Reber, Melanie A R; Allison, Thomas K

    2015-01-01

    We present a new technique using a frequency comb laser and optical cavities for performing ultrafast transient absorption spectroscopy with improved sensitivity. Resonantly enhancing the probe pulses, we demonstrate a sensitivity of $\\Delta$OD $ = 1 \\times 10^{-9}/\\sqrt{\\mbox{Hz}}$ for averaging times as long as 30 s per delay point ($\\Delta$OD$_{min} = 2 \\times 10^{-10}$). Resonantly enhancing the pump pulses allows us to produce a high excitation fraction at high repetition-rate, so that signals can be recorded from samples with optical densities as low as OD $\\approx 10^{-8}$, or column densities $< 10^{10}$ molecules/cm$^2$. This high sensitivity enables new directions for ultrafast spectroscopy.

  11. Adsorption of cytochrome c to silica surfaces studied using evanescent wave broadband cavity-enhanced absorption spectroscopy

    Science.gov (United States)

    Moore, L. J.; van der Sneppen, L.; Peverall, R.; Hancock, G.; Ritchie, G. A. D.

    2010-08-01

    The adsorption of cytochrome c (cyt c) to a silica surface has been studied by use of evanescent wave broadband cavityenhanced absorption spectroscopy (EW-BBCEAS). Visible radiation from a supercontinuum source is coupled into an optical cavity consisting of a pair of broadband high reflectivity mirrors, and a total internal reflection (TIR) event at the prism/water interface. Aqueous solutions of cyt c are placed onto the TIR footprint on the prism surface and the subsequent protein adsorption is probed by the resulting evanescent wave. The time integrated cavity output is directed into a spectrometer, where it is dispersed and analysed. The high spectral brilliance of the SC affords a baseline noise comparable to evanescent wave cavity ring-down spectroscopy (EW-CRDS), and the broadband nature of the source allows observation of a wide spectral range (ca 250 nm in the visible). The system is calibrated by measuring the absorption spectra of dyes of a known absorbance. Absorption spectra of cyt c are obtained for both S and P polarized radiation, allowing information about the orientation of the adsorbed protein to be extracted.

  12. High sensitivity liquid phase measurements using broadband cavity enhanced absorption spectroscopy (BBCEAS) featuring a low cost webcam based prism spectrometer.

    Science.gov (United States)

    Qu, Zhechao; Engstrom, Julia; Wong, Donald; Islam, Meez; Kaminski, Clemens F

    2013-11-01

    Cavity enhanced techniques enable high sensitivity absorption measurements in the liquid phase but are typically more complex, and much more expensive, to perform than conventional absorption methods. The latter attributes have so far prevented a wide spread use of these methods in the analytical sciences. In this study we demonstrate a novel BBCEAS instrument that is sensitive, yet simple and economical to set up and operate. We use a prism spectrometer with a low cost webcam as the detector in conjunction with an optical cavity consisting of two R = 0.99 dielectric mirrors and a white light LED source for illumination. High sensitivity liquid phase measurements were made on samples contained in 1 cm quartz cuvettes placed at normal incidence to the light beam in the optical cavity. The cavity enhancement factor (CEF) with water as the solvent was determined directly by phase shift cavity ring down spectroscopy (PS-CRDS) and also by calibration with Rhodamine 6G solutions. Both methods yielded closely matching CEF values of ~60. The minimum detectable change in absorption (αmin) was determined to be 6.5 × 10(-5) cm(-1) at 527 nm and was limited only by the 8 bit resolution of the particular webcam detector used, thus offering scope for further improvement. The instrument was used to make representative measurements on dye solutions and in the determination of nitrite concentrations in a variation of the widely used Griess Assay. Limits of detection (LOD) were ~850 pM for Rhodamine 6G and 3.7 nM for nitrite, respectively. The sensitivity of the instrument compares favourably with previous cavity based liquid phase studies whilst being achieved at a small fraction of the cost hitherto reported, thus opening the door to widespread use in the community. Further means of improving sensitivity are discussed in the paper. PMID:24049768

  13. Theoretical analysis of cavity saturation spectroscopy of weak molecular absorbance

    Institute of Scientific and Technical Information of China (English)

    Ma Wei-Guang; Dong Lei; Yin Wang-Bao; Jia Suo-Tang

    2005-01-01

    A theoretical analysis of sub-Doppler molecular saturation spectroscopy by use of a confocal Fabry-Perot (CFP)cavity is presented. The effects of gas pressure, cavity length and mirror reflectivity on the saturation dip amplitude are analysed. Such a treatment can provide the optimum conditions and a guidance for the experiment of saturating the weak molecular absorption lines.

  14. Broadband cavity-enhanced absorption spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde

    Science.gov (United States)

    Washenfelder, R. A.; Attwood, A. R.; Flores, J. M.; Zarzana, K. J.; Rudich, Y.; Brown, S. S.

    2016-01-01

    Formaldehyde (CH2O) is the most abundant aldehyde in the atmosphere, and it strongly affects photochemistry through its photolysis. We describe simultaneous measurements of CH2O and nitrogen dioxide (NO2) using broadband cavity-enhanced absorption spectroscopy in the ultraviolet spectral region. The light source consists of a continuous-wave diode laser focused into a Xenon bulb to produce a plasma that emits high-intensity, broadband light. The plasma discharge is optically filtered and coupled into a 1 m optical cavity. The reflectivity of the cavity mirrors is 0.99930 ± 0.00003 (1- reflectivity = 700 ppm loss) at 338 nm, as determined from the known Rayleigh scattering of He and zero air. This mirror reflectivity corresponds to an effective path length of 1.43 km within the 1 m cell. We measure the cavity output over the 315-350 nm spectral region using a grating monochromator and charge-coupled device array detector. We use published reference spectra with spectral fitting software to simultaneously retrieve CH2O and NO2 concentrations. Independent measurements of NO2 standard additions by broadband cavity-enhanced absorption spectroscopy and cavity ring-down spectroscopy agree within 2 % (slope for linear fit = 1.02 ± 0.03 with r2 = 0.998). Standard additions of CH2O measured by broadband cavity-enhanced absorption spectroscopy and calculated based on flow dilution are also well correlated, with r2 = 0.9998. During constant mixed additions of NO2 and CH2O, the 30 s measurement precisions (1σ) of the current configuration were 140 and 210 pptv, respectively. The current 1 min detection limit for extinction measurements at 315-350 nm provides sufficient sensitivity for measurement of trace gases in laboratory experiments and ground-based field experiments. Additionally, the instrument provides highly accurate, spectroscopically based trace gas detection that may complement higher precision techniques based on non-absolute detection methods. In addition to

  15. Absolute absorption and fluorescence measurements over a dynamic range of 10$^6$ with cavity-enhanced laser-induced fluorescence

    CERN Document Server

    Sanders, Scott E; Nahler, N Hendrik; Wrede, Eckart

    2013-01-01

    We describe a novel experimental setup that combines the advantages of both laser-induced fluorescence and cavity ring-down techniques. The simultaneous measurement of the ring-down and fluorescence signals from the same sample in a single laser beam delivers the calibration of the fluorescence measurement to gain absolute quantities: absorption cross section, sample density and fluorescence quantum yield. At the same time, the fluorescence measurement extends the dynamic range of a stand-alone cavity ring-down setup from typically three to at least six orders of magnitude. The methodology of this combined cavity-enhanced laser-induced fluorescence (CELIF) technique is developed and rigorously tested against the spectroscopy of 1,4-bis(phenylethynyl)benzene in a molecular beam and density measurements in a cell.

  16. Optical re-injection in cavity-enhanced absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Leen, J. Brian, E-mail: b.leen@lgrinc.com; O’Keefe, Anthony [Los Gatos Research, 67 E. Evelyn Avenue, Suite 3, Mountain View, California 94041 (United States)

    2014-09-15

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10{sup −10} cm{sup −1}/√(Hz;) an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  17. Magnetic field sensor using the fiber loop ring-down technique and an etched fiber coated with magnetic fluid.

    Science.gov (United States)

    Shen, Tao; Feng, Yue; Sun, Binchao; Wei, Xinlao

    2016-02-01

    The fiber loop ring-down spectroscopy technique is introduced into the evanescent-field-based sensing scheme in order to create a new type of fiber-based magnetic field sensor. As a consequence, the sensitivity and stability of the magnetic field sensing system are significantly enhanced. The sensor head is constructed using a section of a single-mode fiber with its cladding partially etched. The process of fiber etching is described in detail, and the relationship between the diameter of the etched fiber and the etching time is experimentally investigated. After adopting the appropriate size of the etched fiber, the final experimental results show that the magnetic field strength has a well-defined linear relationship with the inverse of the ring-down time τ over a range of 30 mT with a sensitivity of 95.5 ns/mT. PMID:26836067

  18. High sensitivity CW-Cavity Ring Down Spectroscopy of N2O between 6950 and 7653 cm−1 (1.44–1.31 μm): II. Line intensities

    International Nuclear Information System (INIS)

    The room temperature absorption spectra of nitrous oxide, N2O, have been recorded in the 6950–7653 cm−1 spectral region at 2 and 10 Torr using a CW-CRDS spectrometer based on 24 fibered DFB lasers. The achieved sensitivity (noise equivalent absorption αmin≈5×10–11 cm−1) allowed detecting lines with intensities as low as 1×10–29 cm/molecule. In the preceding contribution (Lu Y, Mondelain D, Liu AW, Perevalov VI, Kassi S, Campargue A, J Quant Spectros and Radiat Transfer 2012;113:749–62), we reported the assignment of more than 7200 N2O lines in the region and the derivation of the corresponding spectroscopic parameters Gv, Bv, Dv and Hv. In the present work, more than 1300 14N216O absolute line intensities of cold and hot bands belonging to the ΔP=12, 13 and 14 series of transitions have been measured (P=2V1+V2+4V3 is the polyad number). The uncertainty of the obtained line intensity values varies from 4 to 7% for the majority of the lines. The obtained dataset extends importantly the set of measurements available in the literature, in particular for the ΔP =13 series for which previous data were very limited. The ΔP=12–14 effective dipole moment parameters were fitted to the intensity values measured in this work and available in the literature. The obtained sets of the dipole moment parameters allow reproducing the observed line intensities within their experimental uncertainties. The calculated intensities of the ΔP=12, 13 and 14 bands of 14N216O assigned by CRDS in the 6950–7653 cm−1 region are provided as supplementary material. -- Highlights: ► Line intensities of 13 bands of 14N216O in the 6950–7653 cm−1 region are measured. ► Effective dipole moment parameters for ΔP=12, 13, 14 series of bands are refined. ► List of the 14N216O transitions observed in the 6950–7653 cm−1 region is provided

  19. Determination of the Absolute Absorption Cross Section of Oxygen Forbidden Transition by Cavity Ring down Spectroscopy%腔衰荡光谱技术测量O2禁戒跃迁绝对吸收截面

    Institute of Scientific and Technical Information of China (English)

    王春梅; 李炯; 龚天林; 陈扬骎; 杨晓华

    2007-01-01

    腔衰荡光谱技术(CRDS)不仅具有较高的测量灵敏度,还可对样品的绝对吸收进行测量.采用连续激光腔衰荡光谱技术,通过测量O2分子三重禁戒跃迁b1Σ+g-X3Σ-g(3,0)带RQ(5)谱线(波数17266.090 cm-1)处,极限真空及不同气压下的衰荡时间,利用逼近法得到空腔寿命为2.9174 ms,由此拟合获得其绝对吸收截面为1.4998(±0.0967)×10-26 cm2,与先前的文献估计值一致.由空腔寿命获得的谐振腔高反镜的反射比为99.989(±0.001)%,较通常的测量方法更为精确,该实验条件下的等效吸收程长比几何程长增大了约9090倍.

  20. Deep-UV high resolution cavity ring-down spectroscopy of the Schumann-Runge bands in O-16(2) and O-18(2) at wavelengths 197-203 nm

    NARCIS (Netherlands)

    Hannemann, S.; Duijn, van E.J.; Ubachs, W.M.G.

    2005-01-01

    With the use of a novel titanium: sapphire laser source delivering, upon fourth harmonic generation, narrowband and tunable radiation in the deep-UV, spectroscopic studies were performed on weak Schumann-Runge bands of oxygen. Improved values for rotational and fine structure molecular parameters fo

  1. High resolution and high precision absorption spectroscopy using high finesse cavities: application to the study of molecules with atmospheric interest; Cavites de haute finesse pour la spectroscopie d'absorption haute sensibilite et haute precision: application a l'etude de molecules d'interet atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Motto-Ros, V.

    2005-12-15

    High finesse cavities are used to measure very weak absorption features. Two different methodologies are investigated and applied to the study of molecules with atmospheric interest. First, Continuous Wave - Cavity Ring Down Spectroscopy (CW-CRDS) is used to study the atmospheric spectra of water vapour in the near infrared range. These measurements are performed for temperature and pressure of atmospheric relevance for DIAL applications (Differential Absorption Lidar). This study, financed by the European Space Agency (ESA), goes with the WALES mission (Water Vapour Lidar Experiment in Space). The experimental setup was conceived in order to control pressure, temperature and relative humidity conditions. A particular attention is done to characterize and describe the spectrometer. Then, measurements of red Oxygen B band are performed to demonstrate the huge performance of Optical Feedback Cavity Enhanced Absorption Spectroscopy (OF-CEAS). The desired optical feedback is obtained by light injection into the high finesse cavity through a glass plate placed inside the cavity and closed to the Brewster angle. We show a measurement dynamical range of 5 orders of magnitude (10{sup -5} to 10{sup -10} /cm) and a sensitivity of 10{sup -10} /cm/{radical} Hz. Also, sampling absorption spectra by the super linear cavity frequency comb allows very precise frequency measurements. This is demonstrated by the determination of Oxygen pressure shifts with an absolute accuracy of around 5 x 10{sup -5} cm{sup -1}/atm. To our knowledge, we provide the highest accuracy ever reported for this parameter. (author)

  2. Cavity-enhanced ultrafast two-dimensional spectroscopy using higher-order modes

    CERN Document Server

    Allison, Thomas K

    2016-01-01

    We describe methods using frequency combs and optical resonators for recording two-dimensional (2D) ultrafast spectroscopy signals with high sensitivity. By coupling multiple frequency combs to higher-order modes of one or more optical cavities, background-free, cavity-enhanced 2D spectroscopy signals are naturally generated via phase cycling. As in cavity-enhanced ultrafast transient absorption spectroscopy (CE-TAS), the signal to noise is enhanced by a factor proportional to the cavity finesse squared, so even using cavities of modest finesse, a very high sensitivity is expected, enabling ultrafast 2D spectroscopy experiments in dilute molecular beams.

  3. Cavity-Enhanced Ultrafast Spectroscopy: Ultrafast Meets Ultrasensitive

    Science.gov (United States)

    Allison, Thomas K.; Reber, Melanie Roberts; Chen, Yuning

    2016-06-01

    Ultrafast optical spectroscopy methods, such as transient absorption spectroscopy and 2D-spectroscopy, are widely used across many disciplines. However, these techniques are typically restricted to optically thick samples, such as solids and liquid solutions. Using a frequency comb laser and optical cavities, we present a new technique for performing ultrafast optical spectroscopy with high sensitivity, enabling work in dilute gas-phase molecular beams. Resonantly enhancing the probe pulses, we demonstrate transient absorption measurements with a detection limit of ΔOD = 2 × 10-10 (1 × 10-9/√{Hz}). Resonantly enhancing the pump pulses allows us to produce a high excitation fraction at high repetition-rate, so that signals can be recorded from samples with optical densities as low as OD ≈ 10-8, or column densities green squares show the average of the Allan deviations obtained independently for each delay point. Error bars here are the standard deviation (not the uncertainty in the mean) of this ensemble, to represent the spread in the data. The blue diamond is the average of the error bars of (a), along with their standard deviation. The grey line has a slope of -1/2 on the log-log plot, the expected slope for white noise performance

  4. Coherent cavity-enhanced dual-comb spectroscopy

    CERN Document Server

    Fleisher, Adam J; Reed, Zachary D; Hodges, Joseph T; Plusquellic, David F

    2016-01-01

    Dual-comb spectroscopy allows for the rapid, multiplexed acquisition of high-resolution spectra without the need for moving parts or low-resolution dispersive optics. This method of broadband spectroscopy is most often accomplished via tight phase locking of two mode-locked lasers, or via sophisticated signal processing algorithms, and therefore long integration times are difficult to achieve. Here we demonstrate an alternative approach to dual-comb spectroscopy using two phase modulator combs originating from a single continuous-wave laser capable of > 2 hours of coherent real-time averaging. The combs of > 250 teeth and 203 MHz spacing were generated by driving the phase modulators with step-recovery diodes, passive devices that provided low-phase-noise harmonics for efficient coupling into an enhancement cavity at picowatt optical powers. With this approach, we demonstrate the sensitivity to simultaneously monitor ambient levels of CO$_2$, CO, HDO, and H$_2$O at a maximum acquisition rate of 150 kHz. Robus...

  5. Cavity ringdown spectroscopy with widely tunable swept-frequency lasers

    International Nuclear Information System (INIS)

    Full text: A novel approach to cavity ringdown (CRD) spectroscopy based on swept-frequency (SF) lasers enables rapid measurement of CRD absorption spectra. Our new SF CRD spectrometer incorporates a miniature widely-tunable continuous-wave SF laser and requires less than 1 s to record wide-ranging absorption spectra with high sensitivity in a single rapid sweep of the laser frequency. The spectrometer has a single-ended transmitter-receiver configuration based on retro-reflected optical-heterodyne detection, and yields a simple, compact, versatile instrument for efficient sensing of gases. The performance of the spectrometer is demonstrated by measuring weak absorption spectra of carbon dioxide gas at 1.5-1.6 μm. Copyright (2005) Australian Institute of Physics

  6. Feasibility Study of Using Short Wave Infrared Cavity Ringdown Spectroscopy (SWIR-CRDS) for Biological Agent Detection

    Energy Technology Data Exchange (ETDEWEB)

    Aker, Pam M.; Johnson, Timothy J.; Williams, Richard M.; Valentine, Nancy B.

    2007-10-01

    This project focused on determining the feasibility of using short wave infrared (SWIR) cavity ring down spectroscopy (CRDS) as a means for real-time detection of biological aerosols. The first part of the project involved identifying biological agent signatures that could be detected with SWIR CRDS. After an exhaustive search of the open literature it was determined that whole biological spores and/or cells would not be good candidates for direct SWIR CRDS probing because they have no unique SWIR signatures. It was postulated that while whole cells or spores are not good candidates for SWIR CRDS detection, their pyrolysis break-down products might be. A literature search was then conducted to find biological pyrolysis products with low molecular weights and high symmetry since these species most likely would have overtone and combination vibrational bands that can be detected in the SWIR. It was determined that pyrrole, pyridine and picolinamide were good candidates for evaluation. These molecules are formed when proteins and porphyrins, proteins and dipicolinic acid, and dipicolinic acid are pyrolyzed, respectively. The second part of the project involved measuring quantitative SWIR spectra of pyrrole, pyridine and picolinamide in PNNL’s FTIR Spectroscopy Laboratory. Spectral information about these molecules, in the vapor phase is sparse – there were only a few prior studies that measured line positions and no information on absorption cross sections. Absorption cross sections are needed in order to estimate the SWIR CRDS detection sensitivity, and line position determines what type of laser will be needed for the sensor. The results of the spectroscopy studies allowed us to estimate the SWIR CRDS detection sensitivity for pyrrole to be 3 x 1012 molec cm-3 or 0.1 ppmv, and for pyridine it was 1.5 x 1015 molec cm-3 or 0.6 ppmv. These detection sensitivity limits are close what we have measured for ammonia. Given these detection limits we then estimated the

  7. The Development of Cavity Ringdown Spectroscopy as a Toxic Metal Continuous Emission Monitor

    International Nuclear Information System (INIS)

    Innovative program to explore the viability of using Cavity Ringdown Spectroscopy (CRDS) for trace analysis and monitoring of remediation processes for hazardous and radioactive wastes. Cavity ringdown spectroscopy is a measurement of the rate of absorption of a sample within a closed optical cavity rather than the standard measurement of the absorbed signal strength over a given sample path. It is a technique capable of providing ultra-sensitive absorption measurements in hostile environments using commercially available easy-to-use pulsed lasers. The inherent high sensitivity stems from both the long effective sample pathlengths possible and the relaxed constraints on the accuracy of the measurement of the cavity decay time

  8. The Development of Cavity Ringdown Spectroscopy as a Toxic Metal Continuous Emission Monitor

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Goeroge P. Miller; Dr. Christopher B. Winstead

    2001-12-04

    Innovative program to explore the viability of using Cavity Ringdown Spectroscopy (CRDS) for trace analysis and monitoring of remediation processes for hazardous and radioactive wastes. Cavity ringdown spectroscopy is a measurement of the rate of absorption of a sample within a closed optical cavity rather than the standard measurement of the avsorved signal strength over a given sample path. It is a technique capable of providing ultra-sensitive absorption measurements in hostile environments using commercially available easy-to-use pulsed lasers. The inherent high sensitivity stems from both the long effective sample pathlengths possible and the relaxed constraints on the accuracy of the measurement of the cavity decay time.

  9. Spatial Resolution of Combined Wavelength Modulation Spectroscopy with Integrated Cavity Output Spectroscopy for Atomic Oxygen Detection

    Science.gov (United States)

    Matsui, Makoto; Nakajima, Daisuke

    2015-09-01

    For developments of thermal protection system, atomic oxygen plays important role. However, its measurement method has not been established because the pressure in front of TPS test materials is as high as a few kPa. Our group proposed combined wavelength modulation and integrated output spectroscopies based on the forbidden transition at OI 636 nm to measure the ground-state number densities. In this study, WM-ICOS system is developed and applied to a microwave oxygen plasma to evaluate measurable region. As a result, the estimated number density by ICOS could be measured as low as 1021 m21. For the condition, WM-ICOS was applied. The signal to noise ratio of the 2f signal was 40.4. Then, the sensitivity was improved about 26. This result corresponding to the measurement limit of the partial atomic oxygen pressure of 250 Pa. The sensitivity of WM-ICOS was found to enough to diagnose the shock layer in high enthalpy flows. However, the spatial resolution was as large as 8 mm. The size of the beam pattern depends on the cavity length, robust ness of the cavity and accuracy of the cavity alignment. In this presentation, the relationship among these parameters will be discussed.

  10. Molecular Laser Spectroscopy as a Tool for Gas Analysis Applications

    International Nuclear Information System (INIS)

    We have used the traceable infrared laser spectrometric amount fraction measurement (TILSAM) method to perform absolute concentration measurements of molecular species using three laser spectroscopic techniques. We report results performed by tunable diode laser absorption spectroscopy (TDLAS), quantum cascade laser absorption spectroscopy (QCLAS), and cavity ring down spectroscopy (CRDS), all based on the TILSAM methodology. The measured results of the different spectroscopic techniques are in agreement with respective gravimetric values, showing that the TILSAM method is feasible with all different techniques. We emphasize the data quality objectives given by traceability issues and uncertainty analyses.

  11. Molecular Laser Spectroscopy as a Tool for Gas Analysis Applications

    Directory of Open Access Journals (Sweden)

    Javis Anyangwe Nwaboh

    2011-01-01

    Full Text Available We have used the traceable infrared laser spectrometric amount fraction measurement (TILSAM method to perform absolute concentration measurements of molecular species using three laser spectroscopic techniques. We report results performed by tunable diode laser absorption spectroscopy (TDLAS, quantum cascade laser absorption spectroscopy (QCLAS, and cavity ring down spectroscopy (CRDS, all based on the TILSAM methodology. The measured results of the different spectroscopic techniques are in agreement with respective gravimetric values, showing that the TILSAM method is feasible with all different techniques. We emphasize the data quality objectives given by traceability issues and uncertainty analyses.

  12. Continuous Vernier filtering of an optical frequency comb for broadband cavity-enhanced molecular spectroscopy

    CERN Document Server

    Rutkowski, Lucile

    2016-01-01

    We have recently introduced the Vernier-based Direct Frequency Comb Cavity-Enhanced Spectroscopy technique and we present the corresponding formalism for quantitative broadband spectroscopy. We achieve high sensitivity and broadband performance by acquiring spectra covering more than 2000 cm$^{-1}$ around 12600 cm$^{-1}$ (800 nm), resolving the 3$\

  13. Effects of incomplete light extinction in frequency-agile, rapid scanning spectroscopy

    Science.gov (United States)

    Long, D. A.; Wójtewicz, S.; Hodges, J. T.

    2013-05-01

    The effect of finite beam extinction ratio on the precision and accuracy of cavity ring-down decay time constant measurements was examined using the frequency-agile, rapid scanning, cavity ring-down spectroscopy (FARS-CRDS) technique. This new approach to CRDS uses a waveguide-based electro-optic phase modulator (EOM) to provide a laser beam extinction ratio as high as 80 dB: a value that is ≍30 dB greater than that typically achieved with acousto-optic-modulator- based beam switches. We find that the observed measurement precision scales inversely with extinction ratio, such that an EOM enables measurement of the cavity ring-down decay time with a relative precision of ≍8×10-5. We demonstrate that insufficient extinction can be the dominant cause of statistical uncertainty for extinction ratios below 60 dB. Furthermore, insufficient extinction can result in non-exponential decays, which cause systematic measurement biases in cavity losses and absorption.

  14. Plasma-cavity ringdown spectroscopy for analytical measurement: Progress and prospectives

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Sida; Liu, Wei [Research Center of Analytical Instrumentation, Analytical and Testing Center, College of Chemistry, Sichuan University, Chengdu (China); Zhang, Xiaohe [College of Water Resources and Hydropower, Sichuan University, Chengdu (China); Duan, Yixiang, E-mail: yduan@scu.edu.cn [Research Center of Analytical Instrumentation, Analytical and Testing Center, College of Chemistry, Sichuan University, Chengdu (China)

    2013-07-01

    Plasma-cavity ringdown spectroscopy is a powerful absorption technique for analytical measurement. It combines the inherent advantages of high sensitivity, absolute measurement, and relative insensitivity to light source intensity fluctuations of the cavity ringdown technique with use of plasma as an atomization/ionization source. In this review, we briefly describe the background and principles of plasma-cavity ringdown spectroscopy(CRDS) technology, the instrumental components, and various applications. The significant developments of the plasma sources, lasers, and cavity optics are illustrated. Analytical applications of plasma-CRDS for elemental detection and isotopic measurement in atomic spectrometry are outlined in this review. Plasma-CRDS is shown to have a promising future for various analytical applications, while some further efforts are still needed in fields such as cavity design, plasma source design, instrumental improvement and integration, as well as potential applications in radical and molecular measurements. - Highlights: • Plasma-based cavity ringdown spectroscopy • High sensitivity and high resolution • Elemental and isotopic measurements.

  15. Non-linear Spectroscopy of Sr Atoms in an Optical Cavity for Laser Stabilization

    CERN Document Server

    Christensen, Bjarke T R; Schäffer, Stefan A; Westergaard, Philip G; Ye, Jun; Holland, Murray; Thomsen, Jan W

    2015-01-01

    We study the non-linear interaction of a cold sample of strontium-88 atoms coupled to a single mode of a low finesse optical cavity in the so-called bad cavity limit and investigate the implications for applications to laser stabilization. The atoms are probed on the weak inter-combination line $\\lvert 5s^{2} \\, ^1 \\textrm{S}_0 \\rangle \\,-\\, \\lvert 5s5p \\, ^3 \\textrm{P}_1 \\rangle$ at 689 nm in a strongly saturated regime. Our measured observables include the atomic induced phase shift and absorption of the light field transmitted through the cavity represented by the complex cavity transmission coefficient. We demonstrate high signal-to-noise-ratio measurements of both quadratures - the cavity transmitted phase and absorption - by employing FM spectroscopy (NICE-OHMS). We also show that when FM spectroscopy is employed in connection with a cavity locked to the probe light, observables are substantially modified compared to the free space situation where no cavity is present. Furthermore, the non-linear dynami...

  16. Linewidth measurement of external grating cavity quantum cascade laser using saturation spectroscopy

    Science.gov (United States)

    Mukherjee, Nandini; Go, Rowel; Patel, C. Kumar N.

    2008-03-01

    A room temperature external grating cavity (EGC) quantum cascade laser (QCL) is characterized using saturation spectroscopy of NO2. The presence of two strong EGC QCL waveguide modes is evident from the saturation spectra. A linewidth of 21MHz for each EGC-QCL mode is measured from the width of the saturation peak at 10mTorr pressure of NO2.

  17. Cavities

    Science.gov (United States)

    ... the bacteria produce acids that cause decay. Tooth pain occurs after decay reaches the inside of the tooth. Dentists can detect cavities by examining the teeth and taking x-rays periodically. Good oral hygiene and regular dental care plus a healthy diet can help prevent cavities. ...

  18. Broadband cavity enhanced spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde

    Science.gov (United States)

    Washenfelder, R. A.; Attwood, A. R.; Flores, J. M.; Rudich, Y.; Brown, S. S.

    2015-09-01

    Formaldehyde (CH2O) is the most abundant aldehyde in the atmosphere, and strongly affects photochemistry through its photolysis. We describe simultaneous measurements of CH2O and nitrogen dioxide (NO2) using broadband cavity enhanced spectroscopy in the ultraviolet spectral region. The light source consists of a continuous-wave diode laser focused into a Xenon bulb to produce a plasma that emits high-intensity, broadband light. The plasma discharge is optically filtered and coupled into a 1 m optical cavity. The reflectivity of the cavity mirrors is 0.99933 ± 0.00003 (670 ppm loss) at 338 nm, as determined from the known Rayleigh scattering of He and zero air. This mirror reflectivity corresponds to an effective path length of 1.49 km within the 1 m cell. We measure the cavity output over the 315-350 nm spectral region using a grating monochromator and charge-coupled device (CCD) array detector. We use published reference spectra with spectral fitting software to simultaneously retrieve CH2O and NO2 concentrations. Independent measurements of NO2 standard additions by broadband cavity enhanced spectroscopy and cavity ringdown spectroscopy agree within 2 % (slope for linear fit = 0.98 ± 0.03 with r2 = 0.998). Standard additions of CH2O measured by broadband cavity enhanced spectroscopy and calculated based on flow dilution are also well-correlated, with r2 = 0.9998. During constant, mixed additions of NO2 and CH2O, the 30 s measurement precisions (1σ) of the current configuration were 140 and 210 pptv, respectively. The current 1-min detection limit for extinction measurements at 315-350 nm provides sufficient sensitivity for measurement of trace gases in laboratory experiments and ground-based field experiments. Additionally, the instrument provides highly accurate, spectroscopically-based trace gas detection that may complement higher precision techniques based on non-absolute detection methods. In addition to trace gases, this approach will be appropriate for

  19. Broadband cavity enhanced spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde

    OpenAIRE

    Washenfelder, R. A.; A. R. Attwood; Flores, J. M.; Rudich, Y.; S. S. Brown

    2015-01-01

    Formaldehyde (CH2O) is the most abundant aldehyde in the atmosphere, and strongly affects photochemistry through its photolysis. We describe simultaneous measurements of CH2O and nitrogen dioxide (NO2) using broadband cavity enhanced spectroscopy in the ultraviolet spectral region. The light source consists of a continuous-wave diode laser focused into a Xenon bulb to produce a plasma that emits high-intensity, broadband light. The plasma discharge is optically filtered and ...

  20. Broadband Cavity Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) – applicability and corrections

    OpenAIRE

    U. Platt; J. Meinen; D. Pöhler; T. Leisner

    2008-01-01

    Atmospheric trace gas measurements by cavity assisted long-path absorption spectroscopy are an emerging technology. An interesting approach is the combination of CEAS with broadband light sources, the broadband CEAS (BB-CEAS). BB-CEAS lends itself to the application of the DOAS technique to analyse the derived absorption spectra. While the DOAS approach has enormous advantages in terms of sensitivity and specificity of the measurement, an important implication is the reduction of the light pa...

  1. Broadband Cavity Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS – applicability and corrections

    Directory of Open Access Journals (Sweden)

    D. Pöhler

    2008-12-01

    Full Text Available Atmospheric trace gas measurements by cavity assisted long-path absorption spectroscopy are an emerging technology. An interesting approach is the combination of CEAS with broad band light sources, the broad-band CEAS (BB-CEAS. BB-CEAS lends itself to the application of the DOAS technique to analyse the derived absorption spectra. While the DOAS approach has enormous advantages in terms of sensitivity and specificity of the measurement, an important implication is the reduction of the light path by the trace gas absorption, since cavity losses due to absorption by gases reduce the quality (Q of the cavity. In fact, at wavelength, where the quality of the BB-CEAS cavity is dominated by the trace gas absorption (esp. at very high mirror reflectivity, the light path will vary inversely with the trace gas concentration and the strength of the band will become nearly independent of the trace gas concentration c in the cavity, rendering the CEAS Method useless for trace gas measurements. Only in the limiting case where the mirror reflectivity determines Q at all wavelength, the strength of the band as seen by the BB-CEAS instrument becomes proportional to the concentration c. We investigate these relationships in detail and present methods to correct for the cases between the two above extremes, which are of course the important ones in practice.

  2. Broadband Cavity Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS – applicability and corrections

    Directory of Open Access Journals (Sweden)

    D. Pöhler

    2009-11-01

    Full Text Available Atmospheric trace gas measurements by cavity assisted long-path absorption spectroscopy are an emerging technology. An interesting approach is the combination of CEAS with broadband light sources, the broadband CEAS (BB-CEAS. BB-CEAS lends itself to the application of the DOAS technique to analyse the derived absorption spectra. While the DOAS approach has enormous advantages in terms of sensitivity and specificity of the measurement, an important implication is the reduction of the light path by the trace gas absorption, since cavity losses due to absorption by gases reduce the quality (Q of the cavity. In fact, at wavelength, where the quality of the BB-CEAS cavity is dominated by the trace gas absorption (especially at very high mirror reflectivity, the average light path will vary nearly inversely with the trace gas concentration and the strength of the band will become only weakly dependent on the trace gas concentration c in the cavity, (the differential optical density being proportional to the logarithm of the trace gas concentration. Only in the limiting case where the mirror reflectivity determines Q at all wavelength, the strength of the band as seen by the CE-DOAS instrument becomes directly proportional to the concentration c. We investigate these relationships in detail and present methods to correct for the cases between the two above extremes, which are of course the important ones in practice.

  3. Experimental studies on perturbed acoustic resonant spectroscopy by a small rock sample in a cylindrical cavity

    Institute of Scientific and Technical Information of China (English)

    CHEN; Dehua; WANG; Xiuming; CONG; Jiansheng; XU; Delong; SONG; Yanjie; MA; Shuilong

    2006-01-01

    A measurement system for acoustic resonant spectroscopy (ARS) is established,and the effects of resonant cavity geometry,inner perturbation samples and environmental temperature on the ARS are investigated.The ARSs of the small samples with various sizes and acoustic properties are measured.The results show that at the normal pressure,the resonant frequency decreases gradually with the increase of liquid temperature in the cylindrical cavity,while the resonant amplitude increases.At certain pressure and temperature,both the resonant frequency and the amplitude decrease greatly when there exist air bubbles inside the cavity fluid.The ARS is apparently affected by the sample porosity and the sample location in the resonant cavity.At the middle of the cavity,the resonant frequencies reach their maximum values for all of the measurement samples.The resonant frequencies of the porous rock samples are smaller than those of the compacted samples if other acoustic parameters are the same.As the sample is moved from the top to the middle of the cavity along its axis,the resonant amplitude increases gradually for the compacted rocks while decreases for the unconsolidated rocks.Furthermore,the resonant amplitude increases firstly and then decreases if the porosity of the rock sample is relatively small.In addition,through the comparisons between the experimental and theoretical results,it is found that the effects of the acoustic parameters and sizes of the samples and the size of the cylindrical cavity on the laboratory results agree well with the theoretical ones qualitatively.These results may provide basic reference for the experiment study of rock acoustic properties in a low frequency using ARS.

  4. Saturation dynamics and working limits of saturated absorption cavity ringdown spectroscopy.

    Science.gov (United States)

    Sadiek, Ibrahim; Friedrichs, Gernot

    2016-08-17

    Cavity ringdown spectroscopy (CRDS) in the linear absorption regime is a well-established method for sensitive trace gas detection, but only a few studies have addressed quantitative measurements in the presence of a saturated sample. In fact, saturation is usually avoided in order to escape from the required complex modeling of the saturation process that depends on the characteristics of the absorbing species, its interaction with the surrounding gas as well as on the temporal and spectral characteristics of the cavity excitation. Conversely, the novel saturated-absorption cavity ringdown spectroscopy approach (SCAR/Sat-CRDS) takes advantage of sample saturation in order to allow one to extract both the gas absorption and the empty cavity loss rates from a single ringdown event. Using a new continuous-wave infrared CRD spectrometer equipped with a tunable narrow-bandwidth high-power OPO laser system and a 18 bit digitizer, the transient dynamics of absorption saturation and the working limits of the Sat-CRDS approach in terms of its ability to extract reliable trace gas concentrations have been experimentally studied in this work. Using a strong methane transition as a test case, the excitation power P0 and saturation power PS have been systematically varied to explore a wide range of saturation regimes. At pressures 5 μbar γc, a pronounced coupling between the two parameters has been observed. Finally, a standard error analysis was performed revealing that the Sat-CRDS approach holds its advantages over conventional CRDS implementations in particular when the attainable ultimate detection sensitivity is limited by uncertainties in the empty cavity ringdown constant. PMID:27488884

  5. Signal line shapes of Fourier transform cavity-enhanced frequency modulation spectroscopy with optical frequency combs

    CERN Document Server

    Johansson, Alexandra C; Khodabakhsh, Amir; Foltynowicz, Aleksandra

    2016-01-01

    We present a thorough analysis of the signal line shapes of Fourier transform-based noise-immune cavity-enhanced optical frequency comb spectroscopy (NICE-OFCS). We discuss the signal dependence on the ratio of the modulation frequency, f${_m}$, to the molecular line width, {\\Gamma}. We compare a full model of the signals and a simplified absorption-like analytical model that has high accuracy for low f${_m}$/{\\Gamma} ratios and is much faster to compute. We verify the theory experimentally by measuring and fitting NICE-OFCS spectra of CO${_2}$ at 1575 nm using a system based on an Er:fiber femtosecond laser and a cavity with a finesse of ~11000.

  6. Ancillary qubit spectroscopy of vacua in cavity and circuit quantum electrodynamics.

    Science.gov (United States)

    Lolli, Jared; Baksic, Alexandre; Nagy, David; Manucharyan, Vladimir E; Ciuti, Cristiano

    2015-05-01

    We investigate theoretically how the spectroscopy of an ancillary qubit can probe cavity (circuit) QED ground states containing photons. We consider three classes of systems (Dicke, Tavis-Cummings, and Hopfield-like models), where nontrivial vacua are the result of ultrastrong coupling between N two-level systems and a single-mode bosonic field. An ancillary qubit detuned with respect to the boson frequency is shown to reveal distinct spectral signatures depending on the type of vacua. In particular, the Lamb shift of the ancilla is sensitive to both ground state photon population and correlations. Backaction of the ancilla on the cavity ground state is investigated, taking into account the dissipation via a consistent master equation for the ultrastrong coupling regime. The conditions for high-fidelity measurements are determined.

  7. Sensitive and ultra-fast species detection using pulsed cavity ringdown spectroscopy

    KAUST Repository

    Alquaity, Awad

    2015-01-01

    Pulsed cavity ringdown spectroscopy (CRDS) is used to develop a novel, ultra-fast, high-sensitivity diagnostic for measuring species concentrations in shock tube experiments. The diagnostic is demonstrated by monitoring trace concentrations of ethylene in the mid-IR region near 949.47 cm-1. Each ringdown measurement is completed in less than 1 μs and the time period between successive pulses is 10 μs. The high sensitivity diagnostic has a noise-equivalent detection limit of 1.08 x 10-5 cm-1 which enables detection of 15 ppm ethylene at fuel pyrolysis conditions (1845 K and 2 bar) and 294 ppb ethylene under ambient conditions (297 K and 1 bar). To our knowledge, this is the first successful application of the cavity ringdown method to the measurement of species time-histories in a shock tube. © 2015 OSA.

  8. An XUV source using a femtosecond enhancement cavity for photoemission spectroscopy

    Science.gov (United States)

    Mills, Arthur K.; Zhdanovich, Sergey; Sheyerman, Alex; Levy, Giorgo; Damascelli, Andrea; Jones, David J.

    2015-05-01

    Recent development of extreme ultraviolet (XUV) sources based on high harmonic generation (HHG) in femtosecond enhancement cavities (fsEC) has enabled generation of high photon ux ( ̴ 1013-1014 photons/sec) in the XUV, at high repetition rates (> 50 MHz) and spanning the spectral region from 40 nm - 120 nm. Here we demonstrate the potential offered by this approach for angle-resolved photoemission spectroscopy by measuring the photoemission spectrum of Au using 8.3 and 25 eV photons with excellent resolution at rapid data rates.

  9. New Developments of Broadband Cavity Enhanced Spectroscopic Techniques

    Science.gov (United States)

    Walsh, A.; Zhao, D.; Linnartz, H.; Ubachs, W.

    2013-06-01

    In recent years, cavity enhanced spectroscopic techniques, such as cavity ring-down spectroscopy (CRDS), cavity enhanced absorption spectroscopy (CEAS), and broadband cavity enhanced absorption spectroscopy (BBCEAS), have been widely employed as ultra-sensitive methods for the measurement of weak absorptions and in the real-time detection of trace species. In this contribution, we introduce two new cavity enhanced spectroscopic concepts: a) Optomechanical shutter modulated BBCEAS, a variant of BBCEAS capable of measuring optical absorption in pulsed systems with typically low duty cycles. In conventional BBCEAS applications, the latter substantially reduces the signal-to-noise ratio (S/N), consequently also reducing the detection sensitivity. To overcome this, we incorporate a fast optomechanical shutter as a time gate, modulating the detection scheme of BBCEAS and increasing the effective duty cycle reaches a value close to unity. This extends the applications of BBCEAS into pulsed samples and also in time-resolved studies. b) Cavity enhanced self-absorption spectroscopy (CESAS), a new spectroscopic concept capable of studying light emitting matter (plasma, flames, combustion samples) simultaneously in absorption and emission. In CESAS, a sample (plasma, flame or combustion source) is located in an optically stable cavity consisting of two high reflectivity mirrors, and here it acts both as light source and absorbing medium. A high detection sensitivity of weak absorption is reached without the need of an external light source, such as a laser or broadband lamp. The performance is illustrated by the first CESAS result on a supersonically expanding hydrocarbon plasma. We expect CESAS to become a generally applicable analytical tool for real time and in situ diagnostics. A. Walsh, D. Zhao, W. Ubachs, H. Linnartz, J. Phys. Chem. A, {dx.doi.org/10.1021/jp310392n}, in press, 2013. A. Walsh, D. Zhao, H. Linnartz Rev. Sci. Instrum. {84}(2), 021608 2013. A. Walsh, D. Zhao

  10. Cavity ring-up spectroscopy for ultrafast sensing with optical microresonators

    CERN Document Server

    Rosenblum, Serge; Arazi, Lior; Vollmer, Frank; Dayan, Barak

    2015-01-01

    Spectroscopy of whispering-gallery mode (WGM) microresonators has become a powerful scientific tool, enabling detection of single viruses, nanoparticles, and even single molecules. Yet the demonstrated timescale of these schemes has been limited so far to milliseconds or more. Here we introduce a novel scheme that is orders of magnitude faster, capable of capturing complete spectral snapshots of WGM resonances at nanosecond timescales: cavity ring-up spectroscopy (CRUS). Based on sharply-rising detuned probe pulses, CRUS combines the sensitivity of heterodyne measurements with the highest possible, transform-limited acquisition rate. As a demonstration we capture spectra of microtoroid resonators at time intervals as short as 16 ns, directly monitoring sub-microsecond dynamics of their optomechanical vibrations, thermorefractive response and Kerr nonlinearity. CRUS holds promise for the study of fast biological processes such as enzyme kinetics, protein folding and light harvesting, with applications in other...

  11. Insights on diagnosis of oral cavity pathologies by infrared spectroscopy: A review

    Science.gov (United States)

    Giorgini, Elisabetta; Balercia, Paolo; Conti, Carla; Ferraris, Paolo; Sabbatini, Simona; Rubini, Corrado; Tosi, Giorgio

    2013-11-01

    Fourier-Transform Infrared microspectroscopy, a largely used spectroscopic technique in basic and industrial researches, offers the possibility to analyze the vibrational features of molecular groups within a variety of environments. In the bioclinical field, and, in particular, in the study of cells, tissues and biofluids, it could be considered a supporting objective technique able to characterize the biochemical processes involved in relevant pathologies, such as tumoral diseases, highlighting specific spectral markers associable with the principal biocomponents (proteins, lipids and carbohydrates). In this article, we review the applications of infrared spectroscopy to the study of tumoral diseases of oral cavity compartments with the aim to improve understanding of biological processes involved during the onset of these lesions and to afford to an early diagnosis. Spectral studies on mouth, salivary glands and oral cystic lesions, objectively discriminate normal from dysplastic and cancer states characterizing also the grading.

  12. Time-resolved broadband cavity-enhanced absorption spectroscopy for chemical kinetics.

    Energy Technology Data Exchange (ETDEWEB)

    Sheps, Leonid; Chandler, David W.

    2013-04-01

    Experimental measurements of elementary reaction rate coefficients and product branching ratios are essential to our understanding of many fundamentally important processes in Combustion Chemistry. However, such measurements are often impossible because of a lack of adequate detection techniques. Some of the largest gaps in our knowledge concern some of the most important radical species, because their short lifetimes and low steady-state concentrations make them particularly difficult to detect. To address this challenge, we propose a novel general detection method for gas-phase chemical kinetics: time-resolved broadband cavity-enhanced absorption spectroscopy (TR-BB-CEAS). This all-optical, non-intrusive, multiplexed method enables sensitive direct probing of transient reaction intermediates in a simple, inexpensive, and robust experimental package.

  13. Cavity ring-up spectroscopy for dissipative and dispersive sensing in a whispering gallery mode resonator

    CERN Document Server

    Yang, Yong; Kasumie, Sho; Ward, Jonathan M; Chormaic, Síle Nic

    2016-01-01

    In whispering gallery mode resonator sensing applications, the conventional way to detect a change in the parameter to be measured is by observing the steady state transmission spectrum through the coupling waveguide. Alternatively, cavity ring-up spectroscopy (CRUS) sensing can be achieved transiently. In this work, we investigate CRUS using coupled mode equations and find analytical solutions with a large spectral broadening approximation of the input pulse. The relationships between the frequency detuning, coupling gap and ring-up peak height are determined and experimentally verified using an ultrahigh \\textit{Q}-factor silica microsphere. This work shows that distinctive dispersive and dissipative transient sensing can be realised by simply measuring the peak height of the CRUS signal, which might improve the data collection rate.

  14. Time-of-flight electron energy loss spectroscopy using TM110 deflection cavities

    Directory of Open Access Journals (Sweden)

    W. Verhoeven

    2016-09-01

    Full Text Available We demonstrate the use of two TM110 resonant cavities to generate ultrashort electron pulses and subsequently measure electron energy losses in a time-of-flight type of setup. The method utilizes two synchronized microwave cavities separated by a drift space of 1.45 m. The setup has an energy resolution of 12 ± 2 eV FWHM at 30 keV, with an upper limit for the temporal resolution of 2.7 ± 0.4 ps. Both the time and energy resolution are currently limited by the brightness of the tungsten filament electron gun used. Through simulations, it is shown that an energy resolution of 0.95 eV and a temporal resolution of 110 fs can be achieved using an electron gun with a higher brightness. With this, a new method is provided for time-resolved electron spectroscopy without the need for elaborate laser setups or expensive magnetic spectrometers.

  15. Time-of-flight electron energy loss spectroscopy using TM110 deflection cavities

    Science.gov (United States)

    Verhoeven, W.; van Rens, J. F. M.; van Ninhuijs, M. A. W.; Toonen, W. F.; Kieft, E. R.; Mutsaers, P. H. A.; Luiten, O. J.

    2016-01-01

    We demonstrate the use of two TM110 resonant cavities to generate ultrashort electron pulses and subsequently measure electron energy losses in a time-of-flight type of setup. The method utilizes two synchronized microwave cavities separated by a drift space of 1.45 m. The setup has an energy resolution of 12 ± 2 eV FWHM at 30 keV, with an upper limit for the temporal resolution of 2.7 ± 0.4 ps. Both the time and energy resolution are currently limited by the brightness of the tungsten filament electron gun used. Through simulations, it is shown that an energy resolution of 0.95 eV and a temporal resolution of 110 fs can be achieved using an electron gun with a higher brightness. With this, a new method is provided for time-resolved electron spectroscopy without the need for elaborate laser setups or expensive magnetic spectrometers. PMID:27704035

  16. Aspects of the Application of Cavity Enhanced Spectroscopy to Nitrogen Oxides Detection

    Directory of Open Access Journals (Sweden)

    Zbigniew Bielecki

    2013-06-01

    Full Text Available This article presents design issues of high-sensitive laser absorption spectroscopy systems for nitrogen oxides (NOx detection. Examples of our systems and their investigation results are also described. The constructed systems use one of the most sensitive methods, cavity enhanced absorption spectroscopy (CEAS. They operate at different wavelength ranges using a blue—violet laser diode (410 nm as well as quantum cascade lasers (5.27 µm and 4.53 µm. Each of them is configured as a one or two channel measurement device using, e.g., time division multiplexing and averaging. During the testing procedure, the main performance features such as detection limits and measurements uncertainties have been determined. The obtained results are 1 ppb NO2, 75 ppb NO and 45 ppb N2O. For all systems, the uncertainty of concentration measurements does not exceed a value of 13%. Some experiments with explosives are also discussed. A setup equipped with a concentrator of explosives vapours was used. The detection method is based either on the reaction of the sensors to the nitrogen oxides directly emitted by the explosives or on the reaction to the nitrogen oxides produced during thermal decomposition of explosive vapours. For TNT, PETN, RDX and HMX a detection limit better than 1 ng has been achieved.

  17. Noise-immune cavity-enhanced optical frequency comb spectroscopy: A sensitive technique for high-resolution broadband molecular detection

    CERN Document Server

    Khodabakhsh, Amir; Foltynowicz, Aleksandra

    2014-01-01

    Noise-immune cavity-enhanced optical frequency comb spectroscopy (NICE-OFCS) is a recently developed technique that utilizes phase modulation to obtain immunity to frequency-to-amplitude noise conversion by the cavity modes and yields high absorption sensitivity over a broad spectral range. We describe the principles of the technique and discuss possible comb-cavity matching solutions. We present a theoretical description of NICE-OFCS signals detected with a Fourier transform spectrometer (FTS), and validate the model by comparing it to experimental CO2 spectra around 1575 nm. Our system is based on an Er:fiber femtosecond laser locked to a cavity and phase-modulated at a frequency equal to a multiple of the cavity free spectral range (FSR). The NICE-OFCS signal is detected by a fast-scanning FTS equipped with a high-bandwidth commercial detector. We demonstrate a simple method of passive locking of the modulation frequency to the cavity FSR that significantly improves the long term stability of the system, a...

  18. Toroid cavity detectors for high-resolution NMR spectroscopy and rotating frame imaging: capabilities and limitations.

    Science.gov (United States)

    Momot, K I; Binesh, N; Kohlmann, O; Johnson, C S

    2000-02-01

    The capabilities of toroid cavity detectors for simultaneous rotating frame imaging and NMR spectroscopy have been investigated by means of experiments and computer simulations. The following problems are described: (a) magnetic field inhomogeneity and subsequent loss of chemical shift resolution resulting from bulk magnetic susceptibility effects, (b) image distortions resulting from off-resonance excitation and saturation effects, and (c) distortion of lineshapes and images resulting from radiation damping. Also, special features of signal analysis including truncation effects and the propagation of noise are discussed. B(0) inhomogeneity resulting from susceptibility mismatch is a serious problem for applications requiring high spectral resolution. Image distortions resulting from off-resonance excitation are not serious within the rather narrow spectral range permitted by the RF pulse lengths required to read out the image. Incomplete relaxation effects are easily recognized and can be avoided. Also, radiation damping produces unexpectedly small effects because of self-cancellation of magnetization and short free induction decay times. The results are encouraging, but with present designs only modest spectral resolution can be achieved. PMID:10648153

  19. Development of Broad Range Scan Capabilities with Jet Cooled Cavity Ringdown Spectroscopy

    Science.gov (United States)

    Codd, Terrance J.; Chen, Ming-Wei; Miller, Terry A.

    2011-06-01

    We have developed a technique for obtaining broad scans, >100 Cm-1, for jet cooled cavity ringdown spectroscopy (CRDS) spectra. Previously the scans of the jet cooled, CRDS apparatus were limited to <10 Cm-1 due to the use of a narrow linewidth radiation source. However, by coupling our jet cooled, CRDS apparatus with a moderate resolution (≃q 0.05 Cm-1) dye laser we are able to greatly increase our rate of data acquisition thereby gaining the capability to perform broad spectral surveys of jet cooled molecules. As a test of the capabilities of the technique we have scanned the tilde{A}-tilde{X} transition of NO_3 previously reported by Deev et al. at room temperature. We believe that this will be a very useful technique to search for transitions of cold molecules whose frequencies are not well known and which later can be studied using high resolution methods. A. Deev, J. Sommar, and M. Okumura, J. Chem. Phys. 122, 224305 (2005).

  20. Spectral contaminant identifier for off-axis integrated cavity output spectroscopy measurements of liquid water isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Brian Leen, J.; Berman, Elena S. F.; Gupta, Manish [Los Gatos Research, 67 East Evelyn Avenue, Suite 3, Mountain View, California 94041-1518 (United States); Liebson, Lindsay [Department of Mechanical Engineering, Stanford University, Stanford, California 94305 (United States)

    2012-04-15

    Developments in cavity-enhanced absorption spectrometry have made it possible to measure water isotopes using faster, more cost-effective field-deployable instrumentation. Several groups have attempted to extend this technology to measure water extracted from plants and found that other extracted organics absorb light at frequencies similar to that absorbed by the water isotopomers, leading to {delta}{sup 2}H and {delta}{sup 18}O measurement errors ({Delta}{delta}{sup 2}H and {Delta}{delta}{sup 18}O). In this note, the off-axis integrated cavity output spectroscopy (ICOS) spectra of stable isotopes in liquid water is analyzed to determine the presence of interfering absorbers that lead to erroneous isotope measurements. The baseline offset of the spectra is used to calculate a broadband spectral metric, m{sub BB}, and the mean subtracted fit residuals in two regions of interest are used to determine a narrowband metric, m{sub NB}. These metrics are used to correct for {Delta}{delta}{sup 2}H and {Delta}{delta}{sup 18}O. The method was tested on 14 instruments and {Delta}{delta}{sup 18}O was found to scale linearly with contaminant concentration for both narrowband (e.g., methanol) and broadband (e.g., ethanol) absorbers, while {Delta}{delta}{sup 2}H scaled linearly with narrowband and as a polynomial with broadband absorbers. Additionally, the isotope errors scaled logarithmically with m{sub NB}. Using the isotope error versus m{sub NB} and m{sub BB} curves, {Delta}{delta}{sup 2}H and {Delta}{delta}{sup 18}O resulting from methanol contamination were corrected to a maximum mean absolute error of 0.93 per mille and 0.25 per mille respectively, while {Delta}{delta}{sup 2}H and {Delta}{delta}{sup 18}O from ethanol contamination were corrected to a maximum mean absolute error of 1.22 per mille and 0.22 per mille . Large variation between instruments indicates that the sensitivities must be calibrated for each individual isotope analyzer. These results suggest that the

  1. High-sensitivity time-resolved intracavity laser Fourier transform spectroscopy with vertical cavity surface emitting multiple quantum well lasers

    CERN Document Server

    Picqué, N; Kachanov, A A; Picqu\\'e, Nathalie; Guelachvili, Guy; Kachanov, Alexander A.

    2003-01-01

    Spectra comprised of hundreds of time-components for absorption path lengths up to 130 km have been recorded around 1050 nm by combining two recent techniques, intracavity laser spectroscopy with vertical external cavity surface emitting multiple-quantum-well lasers and time-resolved Fourier transform spectroscopy. A sensitivity of 1 10^{-10} cm^{-1}.Hz^{-1/2} is achieved, for simultaneously acquired 10^4 spectral elements, three orders of magnitude better than the sensitivity obtained in previous similar experiments. Specific advantages of the method, especially for frequency and intensity metrology of weak absorption transitions, are discussed.

  2. Ultra-Stable Rubidium-Stabilized External-Cavity Diode Laser Based on the Modulation Transfer Spectroscopy Technique

    Institute of Scientific and Technical Information of China (English)

    QI Xiang-Hui; CHEN Wen-Lan; YI Lin; ZHOU Da-Wei; ZHOU Tong; XIAO Qin; DUAN Jun; ZHOU Xiao-Ji; CHEN Xu-Zong

    2009-01-01

    @@ We construct an ultra-stable external-cavity diode laser via modulation transfer spectroscopy referencing on a hyperfine component of the 87Rb D2 lines at 780 hm. The Doppler-free dispersion-like modulation transfer signal is obtained with high signal-to-noise-ratio. The instability of the laser frequency is measured by beating with an optical frequency comb which is phase-locked to an ultra-stable oven controlled crystal oscillator. The Allan deviation is 3.9×10-13 at 1s averaging time and 9.8×10-14 at 90s averaging time.

  3. Performance of an exhaled nitric oxide and carbon dioxide sensor using quantum cascade laser-based integrated cavity output spectroscopy.

    Science.gov (United States)

    McCurdy, Matthew R; Bakhirkin, Yury; Wysocki, Gerard; Tittel, Frank K

    2007-01-01

    Exhaled nitric oxide (NO) is an important biomarker in asthma and other respiratory disorders. The optical performance of a NOCO(2) sensor employing integrated cavity output spectroscopy (ICOS) with a quantum cascade laser operating at 5.22 microm capable of real-time NO and CO(2) measurements in a single breath cycle is reported. A NO noise-equivalent concentration of 0.4 ppb within a 1-sec integration time is achieved. The off-axis ICOS sensor performance is compared to a chemiluminescent NO analyzer and a nondispersive infrared (NDIR) CO(2) absorption capnograph. Differences between the gas analyzers are assessed by the Bland-Altman method to estimate the expected variability between the gas sensors. The off-axis ICOS sensor measurements are in good agreement with the data acquired with the two commercial gas analyzers. This work demonstrates the performance characteristics and merits of mid-infrared spectroscopy for exhaled breath analysis. PMID:17614742

  4. Non-linear Spectroscopy of Sr Atoms in an Optical Cavity for Laser Stabilization

    OpenAIRE

    Christensen, Bjarke T. R.; Henriksen, Martin R.; Schäffer, Stefan A.; Westergaard, Philip G.; Ye, Jun; Holland, Murray; Thomsen, Jan W.

    2015-01-01

    We study the non-linear interaction of a cold sample of strontium-88 atoms coupled to a single mode of a low finesse optical cavity in the so-called bad cavity limit and investigate the implications for applications to laser stabilization. The atoms are probed on the weak inter-combination line $\\lvert 5s^{2} \\, ^1 \\textrm{S}_0 \\rangle \\,-\\, \\lvert 5s5p \\, ^3 \\textrm{P}_1 \\rangle$ at 689 nm in a strongly saturated regime. Our measured observables include the atomic induced phase shift and abs...

  5. Diagnosis of Multiple Gases Separated from Transformer Oil Using Cavity-Enhanced Raman Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    LI Xiao-Yun; XIA Yu-Xing; HUANG Ju-Ming; ZHAN Li

    2008-01-01

    The Raman signal of gas molecules is very weak due to its small scattering cross section. Here, a near-confocal cavity-enhanced Raman detection system is demonstrated. In the cavity, a high power light of 9 W is achieved by using a cw 200mW 532nm laser, which greatly enhances the detection sensitivity of gas species. A photomultiplier tube connected to a spectrometer is used as the detection system. The Raman spectra of the mixed gases separated from transformer oil has been observed. The relationship of absolute Raman intensity and gas pressure is also obtained. To our knowledge, this is the first Raman system to detect the gases separated from transformer oil.

  6. Microwave spectral taxonomy: A semi-automated combination of chirped-pulse and cavity Fourier-transform microwave spectroscopy

    Science.gov (United States)

    Crabtree, Kyle N.; Martin-Drumel, Marie-Aline; Brown, Gordon G.; Gaster, Sydney A.; Hall, Taylor M.; McCarthy, Michael C.

    2016-03-01

    Because of its structural specificity, rotational spectroscopy has great potential as an analytical tool for characterizing the chemical composition of complex gas mixtures. However, disentangling the individual molecular constituents of a rotational spectrum, especially if many of the lines are entirely new or unknown, remains challenging. In this paper, we describe an empirical approach that combines the complementary strengths of two techniques, broadband chirped-pulse Fourier transform microwave spectroscopy and narrowband cavity Fourier transform microwave spectroscopy, to characterize and assign lines. This procedure, called microwave spectral taxonomy, involves acquiring a broadband rotational spectrum of a rich mixture, categorizing individual lines based on their relative intensities under series of assays, and finally, linking rotational transitions of individual chemical compounds within each category using double resonance techniques. The power of this procedure is demonstrated for two test cases: a stable molecule with a rich spectrum, 3,4-difluorobenzaldehyde, and products formed in an electrical discharge through a dilute mixture of C2H2 and CS2, in which spectral taxonomy has enabled the identification of propynethial, HC(S)CCH.

  7. Pump-probe differencing technique for cavity-enhanced, noise-canceling saturation laser spectroscopy

    CERN Document Server

    De Vine, G; Close, J D; Gray, M B; Vine, Glenn de; Clelland, David E. Mc; Close, John D.; Gray, Malcolm B.

    2004-01-01

    We present an experimental technique enabling mechanical-noise free, cavity-enhanced frequency measurements of an atomic transition and its hyperfine structure. We employ the 532nm frequency doubled output from a Nd:YAG laser and an iodine vapour cell. The cell is placed in a traveling-wave Fabry-Perot interferometer (FPI) with counter-propagating pump and probe beams. The FPI is locked using the Pound-Drever-Hall (PDH) technique. Mechanical noise is rejected by differencing pump and probe signals. In addition, this differenced error signal gives a sensitive measure of differential non-linearity within the FPI.

  8. On-chip spectroscopy with thermally-tuned high-Q photonic crystal cavities

    CERN Document Server

    Liapis, Andreas C; Siddiqui, Mahmudur R; Shi, Zhimin; Boyd, Robert W

    2015-01-01

    Spectroscopic methods are a sensitive way to determine the chemical composition of potentially hazardous materials. Here, we demonstrate that thermally-tuned high-Q photonic crystal cavities can be used as a compact high-resolution on-chip spectrometer. We have used such a chip-scale spectrometer to measure the absorption spectra of both acetylene and hydrogen cyanide in the 1550 nm spectral band, and show that we can discriminate between the two chemical species even though the two materials have spectral features in the same spectral region. Our results pave the way for the development of chip-size chemical sensors that can detect toxic substances.

  9. On-chip spectroscopy with thermally tuned high-Q photonic crystal cavities

    Energy Technology Data Exchange (ETDEWEB)

    Liapis, Andreas C., E-mail: andreas.liapis@gmail.com; Gao, Boshen; Siddiqui, Mahmudur R. [The Institute of Optics, University of Rochester, Rochester, New York 14627 (United States); Shi, Zhimin [Department of Physics, University of South Florida, Tampa, Florida 33620 (United States); Boyd, Robert W. [The Institute of Optics, University of Rochester, Rochester, New York 14627 (United States); Department of Physics and School of Electrical Engineering and Computer Science, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada)

    2016-01-11

    Spectroscopic methods are a sensitive way to determine the chemical composition of potentially hazardous materials. Here, we demonstrate that thermally tuned high-Q photonic crystal cavities can be used as a compact high-resolution on-chip spectrometer. We have used such a chip-scale spectrometer to measure the absorption spectra of both acetylene and hydrogen cyanide in the 1550 nm spectral band and show that we can discriminate between the two chemical species even though the two materials have spectral features in the same spectral region. Our results pave the way for the development of chip-size chemical sensors that can detect toxic substances.

  10. Ultrasensitive, real-time trace gas detection using a high-power, multimode diode laser and cavity ringdown spectroscopy.

    Science.gov (United States)

    Karpf, Andreas; Qiao, Yuhao; Rao, Gottipaty N

    2016-06-01

    We present a simplified cavity ringdown (CRD) trace gas detection technique that is insensitive to vibration, and capable of extremely sensitive, real-time absorption measurements. A high-power, multimode Fabry-Perot (FP) diode laser with a broad wavelength range (Δλlaser∼0.6  nm) is used to excite a large number of cavity modes, thereby reducing the detector's susceptibility to vibration and making it well suited for field deployment. When detecting molecular species with broad absorption features (Δλabsorption≫Δλlaser), the laser's broad linewidth removes the need for precision wavelength stabilization. The laser's power and broad linewidth allow the use of on-axis cavity alignment, improving the signal-to-noise ratio while maintaining its vibration insensitivity. The use of an FP diode laser has the added advantages of being inexpensive, compact, and insensitive to vibration. The technique was demonstrated using a 1.1 W (λ=400  nm) diode laser to measure low concentrations of nitrogen dioxide (NO2) in zero air. A sensitivity of 38 parts in 1012 (ppt) was achieved using an integration time of 128 ms; for single-shot detection, 530 ppt sensitivity was demonstrated with a measurement time of 60 μs, which opens the door to sensitive measurements with extremely high temporal resolution; to the best of our knowledge, these are the highest speed measurements of NO2 concentration using CRD spectroscopy. The reduced susceptibility to vibration was demonstrated by introducing small vibrations into the apparatus and observing that there was no measurable effect on the sensitivity of detection.

  11. Fixed-wavelength H2O absorption spectroscopy system enhanced by an on-board external-cavity diode laser

    International Nuclear Information System (INIS)

    We describe a system designed to perform fixed-wavelength absorption spectroscopy of H2O vapor in practical combustion devices. The system includes seven wavelength-stabilized distributed feedback (WSDFB) lasers, each with a spectral accuracy of  ±1 MHz. An on-board external cavity diode laser (ECDL) that tunes 1320–1365 nm extends the capabilities of the system. Five system operation modes are described. In one mode, a sweep of the ECDL is used to monitor each WSDFB laser wavelength with an accuracy of  ±30 MHz. Demonstrations of fixed-wavelength thermometry at 10 kHz bandwidth in near-room-temperature gases are presented; one test reveals a temperature measurement error of ∼0.43%. (paper)

  12. Widely tunable, narrow linewidth external-cavity gain chip laser for spectroscopy between 1.0 - 1.1 um

    CERN Document Server

    Shin, Dong K; Khakimov, Roman I; Ross, Jacob A; Dedman, Colin J; Hodgman, Sean S; Baldwin, Kenneth G H; Truscott, Andrew G

    2016-01-01

    We have developed and characterised a stable, narrow linewidth external-cavity laser (ECL) tunable over 100 nm around 1080 nm, using a single-angled-facet gain chip. We propose the ECL as a low-cost, high-performance alternative to fibre and diode lasers in this wavelength range and demonstrate its capability through the spectroscopy of metastable helium. Within the coarse tuning range, the wavelength can be continuously tuned over 30 pm (7.8 GHz) without mode-hopping and modulated with bandwidths up to 3 kHz (piezo) and 37(3) kHz (current). The spectral linewidth of the free-running ECL was measured to be 22(2) kHz (Gaussian) and 4.2(3) kHz (Lorentzian) over 22.5 ms, while a long-term frequency stability better than 40(20) kHz over 11 hours was observed when locked to an atomic reference.

  13. Backaction-limited cavity-sideband spectroscopy of quantum collective motion

    CERN Document Server

    Brahms, Nathan; Schreppler, Sydney; Brooks, Daniel W C; Stamper-Kurn, Dan M

    2011-01-01

    The motion of sub-atomic particles is characteristically quantum mechanical in nature. In contrast, quantum aspects of the motion of massive, many-atom objects are typically obscured by high phonon occupation and thermal noise. This contrast is now diminishing, owing to research efforts to bring the control and measurement of macroscopic motion fully into the quantum regime, using objects with masses from attograms to kilograms. This achievement will be critical for constructing force detectors sensitive to gravitational waves, verifying the correspondence principle at macroscopic scales, and realizing protocols that mechanically store and exchange quantum information. Here, we directly observe the quantization of the collective motion of an ultracold atomic ensemble by measuring the inability of a 0.6 attogram centre-of-mass mode to emit energy from its ground state. Moreover, the optical output of our strongly coupled cavity-optomechanical system contains a spectroscopic record of the energy exchanged betwe...

  14. Design and application of robust rf pulses for toroid cavity NMR spectroscopy

    CERN Document Server

    Skinner, Thomas E; Woelk, Klaus; Gershenzon, Naum I; Glaser, Steffen J

    2010-01-01

    We present robust radio frequency (rf) pulses that tolerate a factor of six inhomogeneity in the B1 field, significantly enhancing the potential of toroid cavity resonators for NMR spectroscopic applications. Both point-to-point (PP) and unitary rotation (UR) pulses were optimized for excitation, inversion, and refocusing using the gradient ascent pulse engineering (GRAPE) algorithm based on optimal control theory. In addition, the optimized parameterization (OP) algorithm applied to the adiabatic BIR-4 UR pulse scheme enabled ultra-short (50 microsec) pulses with acceptable performance compared to standard implementations. OP also discovered a new class of non-adiabatic pulse shapes with improved performance within the BIR-4 framework. However, none of the OP-BIR4 pulses are competitive with the more generally optimized UR pulses. The advantages of the new pulses are demonstrated in simulations and experiments. In particular, the DQF COSY result presented here represents the first implementation of 2D NMR sp...

  15. Mid-Infrared Quantum Cascade Laser Based Off-Axis Integrated Cavity Output Spectroscopy for Biogenic Nitric Oxide Detection

    Science.gov (United States)

    Bakhirkin, Yury A.; Kosterev, Anatoliy A.; Roller, Chad; Curl, Robert F.; Tittel, Frank K.

    2004-04-01

    Tunable-laser absorption spectroscopy in the mid-IR spectral region is a sensitive analytical technique for trace-gas quantification. The detection of nitric oxide (NO) in exhaled breath is of particular interest in the diagnosis of lower-airway inflammation associated with a number of lung diseases and illnesses. A gas analyzer based on a continuous-wave mid-IR quantum cascade laser operating at ~5.2 µm and on off-axis integrated cavity output spectroscopy (ICOS) has been developed to measure NO concentrations in human breath. A compact sample cell, 5.3 cm in length and with a volume of less than 80 cm3, that is suitable for on-line and off-line measurements during a single breath cycle, has been designed and tested. A noise-equivalent (signal-to-noise ratio of 1) sensitivity of 10 parts in 10 9 by volume (ppbv) of NO was achieved. The combination of ICOS with wavelength modulation resulted in a 2-ppbv noise-equivalent sensitivity. The total data acquisition and averaging time was 15 s in both cases. The feasibility of detecting NO in expired human breath as a potential noninvasive medical diagnostic tool is discussed.

  16. Ultrasensitive laser spectroscopy for breath analysis

    Science.gov (United States)

    Wojtas, J.; Bielecki, Z.; Stacewicz, T.; Mikołajczyk, J.; Nowakowski, M.

    2012-03-01

    At present there are many reasons for seeking new methods and technologies that aim to develop new and more perfect sensors for different chemical compounds. However, the main reasons are safety ensuring and health care. In the paper, recent advances in the human breath analysis by the use of different techniques are presented. We have selected non-invasive ones ensuring detection of pathogenic changes at a molecular level. The presence of certain molecules in the human breath is used as an indicator of a specific disease. Thus, the analysis of the human breath is very useful for health monitoring. We have shown some examples of diseases' biomarkers and various methods capable of detecting them. Described methods have been divided into non-optical and optical methods. The former ones are the following: gas chromatography, flame ionization detection, mass spectrometry, ion mobility spectrometry, proton transfer reaction mass spectrometry, selected ion flow tube mass spectrometry. In recent twenty years, the optical methods have become more popular, especially the laser techniques. They have a great potential for detection and monitoring of the components in the gas phase. These methods are characterized by high sensitivity and good selectivity. The spectroscopic sensors provide the opportunity to detect specific gases and to measure their concentration either in a sampling place or a remote one. Multipass spectroscopy, cavity ring-down spectroscopy, and photo-acoustic spectroscopy were characterised in the paper as well.

  17. Variable temperature spectroscopy of as-grown and passivated CdS nanowire optical waveguide cavities.

    Science.gov (United States)

    van Vugt, Lambert K; Piccione, Brian; Cho, Chang-Hee; Aspetti, Carlos; Wirshba, Aaron D; Agarwal, Ritesh

    2011-04-28

    Semiconductor nanowire waveguide cavities hold promise for nanophotonic applications such as lasers, waveguides, switches, and sensors due to the tight optical confinement in these structures. However, to realize their full potential, high quality nanowires, whose emission at low temperatures is dominated by free exciton emission, need to be synthesized. In addition, a proper understanding of their complex optical properties, including light-matter coupling in these subwavelength structures, is required. We have synthesized very high-quality wurztite CdS nanowires capped with a 5 nm SiO(2) conformal coating with diameters spanning 100-300 nm using physical vapor and atomic layer deposition techniques and characterized their spatially resolved photoluminescence over the 77-298 K temperature range. In addition to the Fabry-Pérot resonator modulated emission from the ends of the wires, the low temperature emission from the center of the wire shows clear free excitonic peaks and LO phonon replicas, persisting up to room-temperature in the passivated wires. From laser scanning measurements we determined the absorption in the vicinity of the excitonic resonances. In addition to demonstrating the high optical quality of the nanowire crystals, these results provide the fundamental parameters for strong light-matter coupling studies, potentially leading to low threshold polariton lasers, sensitive sensors and optical switches at the nanoscale. PMID:21214218

  18. Thermal dissociation cavity attenuated phase shift spectroscopy for continuous measurement of total peroxy and organic nitrates in the clean atmosphere

    Science.gov (United States)

    Sadanaga, Yasuhiro; Takaji, Ryo; Ishiyama, Ayana; Nakajima, Kazuo; Matsuki, Atsushi; Bandow, Hiroshi

    2016-07-01

    A thermal dissociation cavity attenuated phase shift spectroscopy (TD-CAPS) instrument was developed for measuring total peroxy nitrates (PNs) and organic nitrates (ONs) concentrations in the clean atmosphere. This instrument is easy to operate and can be applied to continuous measurement of PNs and ONs. A continuously measurable system is convenient to perform observations, especially in remote areas. Three lines (NO2, PNs, and ONs lines) were used for thermal dissociation. The NO2 line contains a quartz tube that is not heated, while the PN and ON lines contain quartz tubes that are heated at 433 K and 633 K, respectively. The concentrations of NO2, NO2 + PNs, and NO2 + PNs + ONs can be obtained from the NO2, PN, and ON lines, respectively. The lower limit values of the detection limit (3σ) for PNs and ONs were estimated to be 21 parts per trillion by volume with an integration time of 2 min. PNs were selectively thermally decomposed in the PNs line and formed NO2 quantitatively. In the ONs line, both PNs and ONs were thermally decomposed to produce NO2 quantitatively, but partial decomposition of HNO3 at 633 K interfered with the ONs measurement. Therefore, a HNO3 scrubber is required before the ONs line. Continuous observations were conducted with the TD-CAPS instrument in a remote area, and the instrument performed well for obtaining PNs and ONs concentrations.

  19. Water vapor δ2H and δ18O measurements using off-axis integrated cavity output spectroscopy

    Directory of Open Access Journals (Sweden)

    A. Knohl

    2009-08-01

    Full Text Available We present a detailed assessment of a commercially available water vapor isotope analyzer (WVIA, Los Gatos Research, Inc. for simultaneous in-situ measurements of δ2H and δ18O in water vapor. This method, based on off-axis integrated cavity output spectroscopy, is an alternative to the conventional water trap/isotope ratio mass spectrometry (IRMS techniques. We evaluate the analyzer in terms of precision, memory effects, concentration dependence, temperature sensitivity and long-term stability. A calibration system based on ink jet technology is used to characterize the performance and to calibrate the analyzer. Our results show that the precision at an averaging time of 15 s is 0.16‰ for δ2H and 0.08‰ for δ18O. The isotope ratios are strongly dependent on the water mixing ratio of the air. Taking into account this concentration dependence as well as the temperature sensitivity of the instrument we obtained a long-term stability of the water isotope measurements of 0.38‰ for δ2H and 0.25‰ for δ18O. The accuracy of the WVIA was further assessed by comparative measurements using IRMS and a dew point generator indicating a linear response in isotopic composition and H2O concentrations. The WVIA combined with a calibration system provides accurate high resolution water vapor isotope measurements and opens new possibilities for hydrological and ecological applications.

  20. An instrument for measurements of BrO with LED-based Cavity-Enhanced Differential Optical Absorption Spectroscopy

    Science.gov (United States)

    Hoch, D. J.; Buxmann, J.; Sihler, H.; Pöhler, D.; Zetzsch, C.; Platt, U.

    2014-01-01

    The chemistry of the troposphere and specifically the global tropospheric ozone budget is affected by reactive halogen species such as bromine monoxide (BrO) or chlorine monoxide (ClO). Especially BrO plays an important role in the processes of ozone destruction, disturbance of NOx and HOx chemistry, oxidation of dimethyl sulfide (DMS), and the deposition of elementary mercury. In the troposphere BrO has been detected in polar regions, at salt lakes, in volcanic plumes, and in the marine boundary layer. For a better understanding of these processes, field measurements as well as reaction chamber studies are performed. In both cases instruments with high spatial resolution and high sensitivity are necessary. A Cavity-Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) instrument with an open path measurement cell was designed and applied. For the first time, a CE-DOAS instrument is presented using an UV LED in the 325-365 nm wavelength range. In laboratory studies, BrO as well as HONO, HCHO, O3, and O4 could be reliably determined at detection limits of 20 ppt for BrO, 9.1 ppb for HCHO, 970 ppt for HONO, and 91 ppb for O3, for five minutes integration time. The best detection limits were achieved for BrO (11 ppt), HCHO (5.1 ppb), HONO (490 ppt), and O3 (59 ppb) for integration times of 81 minutes or less. Comparison with established White system (WS) DOAS and O3 monitor measurements demonstrate the reliability of the instrument.

  1. Defect detection inside superconducting 1.3 GHz cavities by means of x-ray fluorescence spectroscopy

    Science.gov (United States)

    Bertucci, M.; Michelato, P.; Moretti, M.; Navitski, A.; Pagani, C.

    2016-01-01

    X-ray fluorescence probe for detection of foreign material inclusions on the inner surface of superconducting cavities has been developed and tested. The setup detects trace element content such as a few micrograms of impurities responsible for thermal breakdown phenomena limiting the cavity performance. The setup has been customized for the geometry of 1.3 GHz TESLA-type niobium cavities and focuses on the surface of equator area at around 103 mm from the centre axis of the cavities with around 20 mm detection spot. More precise localization of inclusions can be reconstructed by means of angular or lateral displacement of the cavity. Preliminary tests confirmed a very low detection limit for elements laying in the high efficiency spectrum zone (from 5 to 10 keV), and a high angular resolution allowing an accurate localization of defects within the equator surface.

  2. Defect detection inside superconducting 1.3 GHz cavities by means of x-ray fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bertucci, M.; Michelato, P.; Moretti, M. [INFN Milano–LASA, Segrate, MI (Italy); Navitski, A. [DESY, Hamburg (Germany); Pagani, C. [INFN Milano–LASA, Segrate, MI (Italy); Dipartimento di Fisica, Università degli Studi di Milano, via Celoria 16, Milano (Italy)

    2016-01-15

    X-ray fluorescence probe for detection of foreign material inclusions on the inner surface of superconducting cavities has been developed and tested. The setup detects trace element content such as a few micrograms of impurities responsible for thermal breakdown phenomena limiting the cavity performance. The setup has been customized for the geometry of 1.3 GHz TESLA-type niobium cavities and focuses on the surface of equator area at around 103 mm from the centre axis of the cavities with around 20 mm detection spot. More precise localization of inclusions can be reconstructed by means of angular or lateral displacement of the cavity. Preliminary tests confirmed a very low detection limit for elements laying in the high efficiency spectrum zone (from 5 to 10 keV), and a high angular resolution allowing an accurate localization of defects within the equator surface.

  3. Light emitting diode cavity enhanced differential optical absorption spectroscopy (LED-CE-DOAS): a novel technique for monitoring atmospheric trace gases

    Science.gov (United States)

    Thalman, Ryan M.; Volkamer, Rainer M.

    2009-08-01

    The combination of Cavity Enhanced Absorption Spectroscopy (CEAS) with broad-band light sources (e.g. Light- Emitting Diodes, LEDs) lends itself to the application of cavity enhanced DOAS (CE-DOAS) to perform sensitive and selective point measurements of multiple trace gases with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e., does not require knowledge of the light intensity in the absence of trace gases and aerosols (I0). We have built a prototype LED-CE-DOAS instrument in the blue spectral range (420-490nm) to measure nitrogen dioxide (NO2), glyoxal (CHOCHO), iodine monoxide (IO), water (H2O) and oxygen dimers (O4). Aerosol extinction is retrieved at two wavelengths by means of observing water and O4 and measuring pressure, temperature and relative humidity independently. The instrument components are presented, and the approach to measure aerosol extinction is demonstrated by means of a set of experiments where laboratory generated monodisperse aerosols are added to the cavity. The aerosol extinction cross section agrees well with Mie calculations, demonstrating that our setup enables measurements of the above gases in open cavity mode.

  4. A compact and stable eddy covariance set-up for methane measurements using off-axis integrated cavity output spectroscopy

    Directory of Open Access Journals (Sweden)

    D. M. D. Hendriks

    2008-01-01

    Full Text Available A Fast Methane Analyzer (FMA is assessed for its applicability in a closed path eddy covariance field set-up in a peat meadow. The FMA uses off-axis integrated cavity output spectroscopy combined with a highly specific narrow band laser for the detection of CH4 and strongly reflective mirrors to obtain a laser path length of 2–20×103 m. Statistical testing and a calibration experiment showed high precision (7.8×10−3 ppb and accuracy (<0.30% of the instrument, while no drift was observed. The instrument response time was determined to be 0.10 s. In the field set-up, the FMA is attached to a scroll pump and combined with a 3-axis ultrasonic anemometer and an open path infrared gas analyzer for measurements of carbon dioxide and water vapour. The power-spectra and co-spectra of the instruments were satisfactory for 10 Hz sampling rates.

    Due to erroneous measurements, spikes and periods of low turbulence the data series consisted for 26% of gaps. Observed CH4 fluxes consisted mainly of emission, showed a diurnal cycle, but were rather variable over. The average CH4 emission was 29.7 nmol m−2 s−1, while the typical maximum CH4 emission was approximately 80.0 nmol m−2 s−1 and the typical minimum flux was approximately 0.0 nmol m−2 s−1. The correspondence of the measurements with flux chamber measurements in the footprint was good and the observed CH4 emission rates were comparable with eddy covariance CH4 measurements in other peat areas.

    Additionally, three measurement techniques with lower sampling frequencies were simulated, which might give the possibility to measure CH4 fluxes without an external pump and save energy. Disjunct eddy covariance appeared to be the most reliable substitute for 10 Hz eddy covariance, while relaxed eddy accumulation gave

  5. A compact and stable eddy covariance set-up for methane measurements using off-axis integrated cavity output spectroscopy

    Directory of Open Access Journals (Sweden)

    D. M. D. Hendriks

    2007-08-01

    Full Text Available A DLT-100 Fast Methane Analyser (FMA from Los Gatos Research (LGR Ltd. is assessed for its applicability in a closed path eddy covariance field set-up. The FMA uses off-axis integrated cavity output spectroscopy (ICOS combined with a highly specific narrow band laser for the detection of CH4 and strongly reflective mirrors to obtain a laser path length of 2×10³ to 20×10³ m. Statistical testing, a calibration experiment and comparison with high tower data showed high precision and very good stability of the instrument. The measurement cell response time was tested to be 0.10 s. In the field set-up, the FMA is attached to a scroll pump and combined with a Gill Windmaster Pro 3 axis Ultrasonic Anemometer and a Licor 7500 open path infrared gas analyzer. The power-spectra and co-spectra of the instrument are satisfactory for 10 Hz sampling rates. The correspondence with CH4 flux chamber measurements is good and the observed CH4 emissions are comparable with (eddy covariance CH4 measurements in other peat areas.

    CH4 emissions are rather variable over time and show a diurnal pattern. The average CH4 emission is 50±12.5 nmol m−2 s−1, while the typical maximum CH4 emission is 120±30 nmol m−2 s−1 (during daytime and the typical minimum flux is –20±2.5 nmol m−2 s−1 (uptake, during night time.

    Additionally, the set-up was tested for three measurement techniques with slower measurement rates, which could be used in the future to make the scroll pump superfluous and save energy. Both disjunct eddy covariance as well as slow 1 Hz eddy covariance showed results very similar to normal 10 Hz eddy covariance. Relaxed eddy accumulation (REA only matched with normal 10 Hz eddy covariance over an averaging period of at least several weeks.

  6. A CMOS millimeter-wave transceiver embedded in a semi-confocal Fabry-Perot cavity for molecular spectroscopy.

    Science.gov (United States)

    Drouin, Brian J; Tang, Adrian; Schlecht, Erich; Brageot, Emily; Gu, Q Jane; Ye, Y; Shu, R; Frank Chang, Mau-Chung; Kim, Y

    2016-08-21

    The extension of radio frequency complementary metal oxide semiconductor (CMOS) circuitry into millimeter wavelengths promises the extension of spectroscopic techniques in compact, power efficient systems. We are now beginning to use CMOS millimeter devices for low-mass, low-power instrumentation capable of remote or in situ detection of gas composition during space missions. We have chosen to develop a Flygare-Balle type spectrometer, with a semi-confocal Fabry-Perot cavity to amplify the pump power of a mm-wavelength CMOS transmitter that is directly coupled to the planar mirror of the cavity. We have built a pulsed transceiver system at 92-105 GHz inside a 3 cm base length cavity and demonstrated quality factor up to 4680, allowing for modes with 20 MHz bandwidth, with a sufficient cavity amplification factor for mW class transmitters. This work describes the initial gas measurements and outlines the challenges and next steps. PMID:27544098

  7. A CMOS millimeter-wave transceiver embedded in a semi-confocal Fabry-Perot cavity for molecular spectroscopy

    Science.gov (United States)

    Drouin, Brian J.; Tang, Adrian; Schlecht, Erich; Brageot, Emily; Gu, Q. Jane; Ye, Y.; Shu, R.; Frank Chang, Mau-chung; Kim, Y.

    2016-08-01

    The extension of radio frequency complementary metal oxide semiconductor (CMOS) circuitry into millimeter wavelengths promises the extension of spectroscopic techniques in compact, power efficient systems. We are now beginning to use CMOS millimeter devices for low-mass, low-power instrumentation capable of remote or in situ detection of gas composition during space missions. We have chosen to develop a Flygare-Balle type spectrometer, with a semi-confocal Fabry-Perot cavity to amplify the pump power of a mm-wavelength CMOS transmitter that is directly coupled to the planar mirror of the cavity. We have built a pulsed transceiver system at 92-105 GHz inside a 3 cm base length cavity and demonstrated quality factor up to 4680, allowing for modes with 20 MHz bandwidth, with a sufficient cavity amplification factor for mW class transmitters. This work describes the initial gas measurements and outlines the challenges and next steps.

  8. Frequency Modulated Integrated Cavity Output Spectroscopy: A General Technique for Trace Gas and Isotope Measurements with Unprecedented Sensitivity Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A new technique is proposed for improved trace gas detection and measurement that combines the high absorption depths afforded by mid-infrared Integrated Cavity...

  9. Fully reflective external-cavity setup for quantum-cascade lasers as a local oscillator in mid-infrared wavelength heterodyne spectroscopy.

    Science.gov (United States)

    Stupar, Dusan; Krieg, Jürgen; Krötz, Peter; Sonnabend, Guido; Sornig, Manuela; Giesen, Thomas F; Schieder, Rudolf

    2008-06-01

    To our knowledge we present the first experiments with a fully reflective external-cavity quantum-cascade laser system at mid-infrared wavelengths for use as a local oscillator in a heterodyne receiver. The performance of the presented setup was investigated using absorption spectroscopy as well as heterodyne techniques. Tunability over approximately 30 cm(-1) at 1130 cm(-1) was demonstrated using a grating spectrometer. A continuous tuning range of 0.28 cm(-1) was verified by observing the spectra of an internally coupled confocal Fabry-Pérot interferometer and the absorption lines of gas phase SO(2). In a second step the output from the system was used as a local oscillator signal for a heterodyne setup. We show that spectral stability and side mode suppression are excellent and that a compact external-cavity quantum-cascade laser system is well suited to be used as a local oscillator in infrared heterodyne spectrometers.

  10. Cavity-enhanced absorption spectroscopy with a ps-pulsed UV laser for sensitive, high-speed measurements in a shock tube.

    Science.gov (United States)

    Wang, Shengkai; Sun, Kai; Davidson, David F; Jeffries, Jay B; Hanson, Ronald K

    2016-01-11

    We report the first application of cavity-enhanced absorption spectroscopy (CEAS) with a ps-pulsed UV laser for sensitive and rapid gaseous species time-history measurements in a transient environment (in this study, a shock tube). The broadband nature of the ps pulses enabled instantaneous coupling of the laser beam into roughly a thousand cavity modes, which grants excellent immunity to laser-cavity coupling noise in environments with heavy vibrations, even with an on-axis alignment. In this proof-of-concept experiment, we demonstrated an absorption gain of 49, which improved the minimum detectable absorbance by ~20 compared to the conventional single-pass strategy at similar experimental conditions. For absorption measurements behind reflected shock waves, an effective time-resolution of ~2 μs was achieved, which enabled time-resolved observations of transient phenomena, such as the vibrational relaxation of O(2) demonstrated here. The substantial improvement in detection sensitivity, together with microsecond measurement resolution implies excellent potential for studies of transient physical and chemical processes in nonequilibrium situations, particularly via measurements of weak absorptions of trace species in dilute reactive systems. PMID:26832262

  11. Cavity-enhanced absorption spectroscopy with a ps-pulsed UV laser for sensitive, high-speed measurements in a shock tube.

    Science.gov (United States)

    Wang, Shengkai; Sun, Kai; Davidson, David F; Jeffries, Jay B; Hanson, Ronald K

    2016-01-11

    We report the first application of cavity-enhanced absorption spectroscopy (CEAS) with a ps-pulsed UV laser for sensitive and rapid gaseous species time-history measurements in a transient environment (in this study, a shock tube). The broadband nature of the ps pulses enabled instantaneous coupling of the laser beam into roughly a thousand cavity modes, which grants excellent immunity to laser-cavity coupling noise in environments with heavy vibrations, even with an on-axis alignment. In this proof-of-concept experiment, we demonstrated an absorption gain of 49, which improved the minimum detectable absorbance by ~20 compared to the conventional single-pass strategy at similar experimental conditions. For absorption measurements behind reflected shock waves, an effective time-resolution of ~2 μs was achieved, which enabled time-resolved observations of transient phenomena, such as the vibrational relaxation of O(2) demonstrated here. The substantial improvement in detection sensitivity, together with microsecond measurement resolution implies excellent potential for studies of transient physical and chemical processes in nonequilibrium situations, particularly via measurements of weak absorptions of trace species in dilute reactive systems.

  12. Following interfacial kinetics in real time using broadband evanescent wave cavity-enhanced absorption spectroscopy: a comparison of light-emitting diodes and supercontinuum sources.

    Science.gov (United States)

    van der Sneppen, Lineke; Hancock, Gus; Kaminski, Clemens; Laurila, Toni; Mackenzie, Stuart R; Neil, Simon R T; Peverall, Robert; Ritchie, Grant A D; Schnippering, Mathias; Unwin, Patrick R

    2010-01-01

    A white light-emitting diode (LED) with emission between 420 and 700 nm and a supercontinuum (SC) source with emission between 450 and 2500 nm have been compared for use in evanescent wave broadband cavity-enhanced absorption spectroscopy (EW-BB-CEAS). The method is calibrated using a dye with known absorbance. While the LED is more economic as an excitation source, the SC source is superior both in terms of baseline noise (noise equivalent absorbances lower than 10(-5) compared to 10(-4) absorbance units (a.u.)) and accuracy of the measurement; these baseline noise levels are comparable to evanescent wave cavity ringdown spectroscopy (EW-CRDS) studies while the accessible spectral region of EW-BB-CEAS is much larger (420-750 nm in this study, compared to several tens of nanometres for EW-CRDS). The improvements afforded by the use of an SC source in combination with a high sensitivity detector are demonstrated in the broadband detection of electrogenerated Ir(IV) complexes in a thin-layer electrochemical cell arrangement. Excellent signal to noise is achieved with 10 micros signal accumulation times at a repetition rate of 600 Hz, easily fast enough to follow, in real time, solution kinetics and interfacial processes. PMID:20024193

  13. Electronic absorption spectroscopy of PAHs in supersonic jets and ultracold liquid helium droplets

    Science.gov (United States)

    Huisken, Friedrich; Staicu, Angela; Krasnokutski, Serge; Henning, Thomas

    Neutral and cationic polycyclic aromatic hydrocarbons (PAHs) are discussed as possible carriers of the diffuse interstellar bands (DIBs), still unassigned astrophysical absorption features observed in the spectra of reddened stars (Salama et al. 1999). Despite the importance of this class of molecules for astrophysics and nanophysics (PAHs can be regarded as nanoscale fragments of a sheet of graphite), the spectroscopic characterization of PAHs under well-defined conditions (low temperature and collision-free environment) has remained a challenge. Recently we have set up a cavity ring-down spectrometer combined with a pulsed supersonic jet expansion to study neutral and cationic PAHs under astrophysical conditions. PAHs studied so far include the neutral molecules anthracene (Staicu et al. 2004) and pyrene (Rouillé et al. 2004) as well as the cationic species naphthalene+ and anthracene+ (Sukhorukov et al. 2004). Employing another molecular beam apparatus, the same molecules (except of the cationic species) were also studied in liquid helium droplets (Krasnokutski et al. 2005, Rouillé et al. 2004). This novel technique combines several advantages of conventional matrix spectroscopy with those of gas phase spectroscopy. Notable advantages are the possibility to study molecules with low vapor pressure and to use a mass spectrometer facilitating spectral assignments. The most recent studies were devoted to phenanthrene and the more complicated (2,3)-benzofluorene. These molecules were investigated in the gas phase by cavity ring-down spectroscopy and in liquid helium droplets using depletion spectroscopy. For benzofluorene the present studies constitute the first reported measurements both in the gas phase and in helium droplets. The origin of the S1 ← S0 gas phase transition could be located at 29 894.3 cm-1, and a series of vibronic bands was recorded below 31 500 cm-1. In contrast to previously studied PAHs, the shift induced by the helium droplets was very

  14. External cavity-quantum cascade laser infrared spectroscopy for secondary structure analysis of proteins at low concentrations

    Science.gov (United States)

    Schwaighofer, Andreas; Alcaráz, Mirta R.; Araman, Can; Goicoechea, Héctor; Lendl, Bernhard

    2016-09-01

    Fourier transform infrared (FTIR) and circular dichroism (CD) spectroscopy are analytical techniques employed for the analysis of protein secondary structure. The use of CD spectroscopy is limited to low protein concentrations (5 mg ml-1). Here we introduce a quantum cascade laser (QCL)-based IR transmission setup for analysis of protein and polypeptide secondary structure at concentrations as low as 0.25 mg ml-1 in deuterated buffer solution. We present dynamic QCL-IR spectra of the temperature-induced α-helix to β-sheet transition of poly-L-lysine. The concentration dependence of the α-β transition temperature between 0.25 and 10 mg ml-1 was investigated by QCL-IR, FTIR and CD spectroscopy. By using QCL-IR spectroscopy it is possible to perform IR spectroscopic analysis in the same concentration range as CD spectroscopy, thus enabling a combined analysis of biomolecules secondary structure by CD and IR spectroscopy.

  15. Near-ultraviolet Incoherent Broadband Cavity Enhanced Absorption Spectroscopy for OClO and CH20 in Cl-initiated Photooxidation Experiment

    Institute of Scientific and Technical Information of China (English)

    Mei-li Dong; Wei-xiong Zhao; Ming-qiang Huang; Wei-dong Chen; Chang-jin Hu; Xue-jun Gu; Shi-xin Pei

    2013-01-01

    Chlorine dioxide (OClO) is an important indicator for Cl-activation.The monitoring of OClO appears to be crucial for understanding the chemistry of Cl-initialed oxidation and its impact on air quality in polluted coastal regions and industrialized areas.We report the development of a Xe arc lamp based near-ultraviolet (335-375 nm) incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) spectrometer for quantitative assessment of OClO in an atmospheric simulation chamber.The important intermediate compound CH2O,and other key atmospheric trace species (NO2) were also simultaneously measured.The instrumental performance shows a strong potential of this kind of IBBCEAS instrument for field and laboratory studies of atmospheric halogen chemistry.

  16. Fluorescence spectroscopy for the detection of potentially malignant disorders of the oral cavity: analysis of 30 cases

    Science.gov (United States)

    Francisco, A. L. N.; Correr, W. R.; Azevedo, L. H.; Galletta, V. K.; Pinto, C. A. L.; Kowalski, L. P.; Kurachi, C.

    2014-01-01

    Oral cancer is a major health problem worldwide and although early diagnosis of potentially malignant and malignant diseases is associated with better treatment results, a large number of cancers are initially misdiagnosed, with unfortunate consequences for long-term survival. Fluorescence spectroscopy is a noninvasive modality of diagnostic approach using induced fluorescence emission in tumors that can improve diagnostic accuracy. The objective of this study was to determine the ability to discriminate between normal oral mucosa and potentially malignant disorders by fluorescence spectroscopy. Fluorescence investigation under 408 and 532 nm excitation wavelengths was performed on 60 subjects, 30 with potentially malignant disorders and 30 volunteers with normal mucosa. Data was analyzed to correlate fluorescence patterns with clinical and histopathological diagnostics. Fluorescence spectroscopy used as a point measurement technique resulted in a great variety of spectral information. In a qualitative analysis of the fluorescence spectral characteristics of each type of injury evaluated, it was possible to discriminate between normal and abnormal oral mucosa. The results show the potential use of fluorescence spectroscopy for an improved discrimination of oral disorders.

  17. Fluorescence spectroscopy for the detection of potentially malignant disorders of the oral cavity: analysis of 30 cases

    International Nuclear Information System (INIS)

    Oral cancer is a major health problem worldwide and although early diagnosis of potentially malignant and malignant diseases is associated with better treatment results, a large number of cancers are initially misdiagnosed, with unfortunate consequences for long-term survival. Fluorescence spectroscopy is a noninvasive modality of diagnostic approach using induced fluorescence emission in tumors that can improve diagnostic accuracy. The objective of this study was to determine the ability to discriminate between normal oral mucosa and potentially malignant disorders by fluorescence spectroscopy. Fluorescence investigation under 408 and 532 nm excitation wavelengths was performed on 60 subjects, 30 with potentially malignant disorders and 30 volunteers with normal mucosa. Data was analyzed to correlate fluorescence patterns with clinical and histopathological diagnostics. Fluorescence spectroscopy used as a point measurement technique resulted in a great variety of spectral information. In a qualitative analysis of the fluorescence spectral characteristics of each type of injury evaluated, it was possible to discriminate between normal and abnormal oral mucosa. The results show the potential use of fluorescence spectroscopy for an improved discrimination of oral disorders. (paper)

  18. Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hellman, Hal

    1968-01-01

    This booklet discusses spectroscopy, the study of absorption of radiation by matter, including X-ray, gamma-ray, microwave, mass spectroscopy, as well as others. Spectroscopy has produced more fundamental information to the study of the detailed structure of matter than any other tools.

  19. Spectroscopy

    CERN Document Server

    Walker, S

    1976-01-01

    The three volumes of Spectroscopy constitute the one comprehensive text available on the principles, practice and applications of spectroscopy. By giving full accounts of those spectroscopic techniques only recently introduced into student courses - such as Mössbauer spectroscopy and photoelectron spectroscopy - in addition to those techniques long recognised as being essential in chemistry teaching - sucha as e.s.r. and infrared spectroscopy - the book caters for the complete requirements of undergraduate students and at the same time provides a sound introduction to special topics for graduate students.

  20. A 23.75-GHz frequency comb with two low-finesse filtering cavities in series for high resolution spectroscopy

    Institute of Scientific and Technical Information of China (English)

    侯磊; 韩海年; 王薇; 张龙; 庞利辉; 李德华; 魏志义

    2015-01-01

    A laser frequency comb with several tens GHz level is demonstrated, based on an Yb-doped femtosecond fiber laser and two low-finesse Fabry–P´erot cavities (FPCs) in series. The original 250-MHz mode-line-spacing of the source comb is filtered to 4.75 GHz and 23.75 GHz, respectively. According to the multi-beam interferences theory of FPC, the side-mode suppression rate of FPC schemes is in good agreement with our own theoretical results from 27 dB of a single FPC to 43 dB of paired FPCs. To maintain long-term stable operation and determine the absolute frequency mode number in the 23.75-GHz comb, the Pound–Drever–Hall (PDH) locking technology is utilized. Such stable tens GHz frequency combs have important applications in calibrating astronomical spectrographs with high resolution.

  1. Liquid helium-free cryostat and hermetically sealed cryogenic microwave cavity for hyperfine spectroscopy of antiprotonic helium.

    Science.gov (United States)

    Massiczek, O; Friedreich, S; Juhász, B; Widmann, E; Zmeskal, J

    2011-12-11

    The design and properties of a new cryogenic set-up for laser-microwave-laser hyperfine structure spectroscopy of antiprotonic helium - an experiment performed at the CERN-Antiproton Decelerator (AD), Geneva, Switzerland - are described. Similar experiments for (4)He have been performed at the AD for several years. Due to the usage of a liquid helium operated cryostat and therefore necessary refilling of coolants, a loss of up to 10% beamtime occurred. The decision was made to change the cooling system to a closed-circuit cryocooler. New hermetically sealed target cells with minimised (3)He gas volume and different dimensions of the microwave resonator for measuring the (3)He transitions were needed. A new set-up has been designed and tested at Stefan Meyer Institute in Vienna before being used for the 2009 and 2010 beamtimes at the AD.

  2. Liquid helium-free cryostat and hermetically sealed cryogenic microwave cavity for hyperfine spectroscopy of antiprotonic helium

    Energy Technology Data Exchange (ETDEWEB)

    Massiczek, O., E-mail: oswald.massiczek@cern.ch [Stefan Meyer Institute for Subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Vienna (Austria); Friedreich, S.; Juhasz, B.; Widmann, E.; Zmeskal, J. [Stefan Meyer Institute for Subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Vienna (Austria)

    2011-12-11

    The design and properties of a new cryogenic set-up for laser-microwave-laser hyperfine structure spectroscopy of antiprotonic helium - an experiment performed at the CERN-Antiproton Decelerator (AD), Geneva, Switzerland - are described. Similar experiments for {sup 4}He have been performed at the AD for several years. Due to the usage of a liquid helium operated cryostat and therefore necessary refilling of coolants, a loss of up to 10% beamtime occurred. The decision was made to change the cooling system to a closed-circuit cryocooler. New hermetically sealed target cells with minimised {sup 3}He gas volume and different dimensions of the microwave resonator for measuring the {sup 3}He transitions were needed. A new set-up has been designed and tested at Stefan Meyer Institute in Vienna before being used for the 2009 and 2010 beamtimes at the AD.

  3. Calibration of δ13C and δ18O measurements in CO2 using Off-axis Integrated Cavity Output Spectrometer (ICOS)

    Science.gov (United States)

    Joseph, Jobin; Külls, Christoph

    2014-05-01

    The δ13C and δ18O of CO2 has enormous potential as tracers to study and quantify the interaction between the water and carbon cycles. Isotope ratio mass spectrometry (IRMS) being the conventional method for stable isotopic measurements, has many limitations making it impossible for deploying them in remote areas for online or in-situ sampling. New laser based absorption spectroscopy approaches like Cavity Ring Down Spectroscopy (CRDS) and Integrated Cavity Output Spectroscopy (ICOS) have been developed for online measurements of stable isotopes at an expense of considerably less power requirement but with precision comparable to IRMS. In this research project, we introduce a new calibration system for an Off- Axis ICOS (Los Gatos Research CCIA-36d) for a wide range of varying concentrations of CO2 (800ppm - 25,000ppm), a typical CO2 flux range at the plant-soil continuum. The calibration compensates for the concentration dependency of δ13C and δ18O measurements, and was performed using various CO2 standards with known CO2 concentration and δC13 and δO18 values. A mathematical model was developed after the calibration procedure as a correction factor for the concentration dependency of δ13C and δ18O measurements. Temperature dependency of δ13C and δ18O measurements were investigated and no significant influence was found. Simultaneous calibration of δ13C and δ18O is achieved using this calibration system with an overall accuracy of (~ 0.75±0.24 ‰ for δ13C, ~ 0.81 ±0.26‰ for δ18O). This calibration procedure is found to be appropriate for making Off-Axis ICOS suitable for measuring CO2 concentration and δ13C and δ18O measurements at atmosphere-plant-soil continuum.

  4. Short-lived species detection of nitrous acid by external-cavity quantum cascade laser based quartz-enhanced photoacoustic absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yi, Hongming [Laboratoire de Physicochimie de l' Atmosphère, Université du Littoral Côte d' Opale, 189A, Av. Maurice Schumann, 59140 Dunkerque (France); Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, P.O. Box 1125, 350 Shushanhu Road, Hefei, Anhui 230031 (China); Maamary, Rabih; Fertein, Eric; Chen, Weidong, E-mail: chen@univ-littoral.fr [Laboratoire de Physicochimie de l' Atmosphère, Université du Littoral Côte d' Opale, 189A, Av. Maurice Schumann, 59140 Dunkerque (France); Gao, Xiaoming [Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, P.O. Box 1125, 350 Shushanhu Road, Hefei, Anhui 230031 (China); Sigrist, Markus W. [ETH Zurich, Institute for Quantum Electronics, HPT H4.1, Auguste-Piccard-Hof 1, CH-8093 Zürich (Switzerland)

    2015-03-09

    Spectroscopic detection of short-lived gaseous nitrous acid (HONO) at 1254.85 cm{sup −1} was realized by off-beam coupled quartz-enhanced photoacoustic spectroscopy (QEPAS) in conjunction with an external cavity quantum cascade lasers (EC-QCL). High sensitivity monitoring of HONO was performed within a very small gas-sample volume (of ∼40 mm{sup 3}) allowing a significant reduction (of about 4 orders of magnitude) of air sampling residence time which is highly desired for accurate quantification of chemically reactive short-lived species. Calibration of the developed QEPAS-based HONO sensor was carried out by means of lab-generated HONO samples whose concentrations were determined by direct absorption spectroscopy involving a ∼109.5 m multipass cell and a distributed feedback QCL. A minimum detection limit (MDL) of 66 ppbv (1 σ) HONO was achieved at 70 mbar using a laser output power of 50 mW and 1 s integration time, which corresponded to a normalized noise equivalent absorption coefficient of 3.6 × 10{sup −8 }cm{sup −1} W/Hz{sup 1/2}. This MDL was down to 7 ppbv at the optimal integration time of 150 s. The corresponding 1σ minimum detected absorption coefficient is ∼1.1 × 10{sup −7 }cm{sup −1} (MDL ∼ 3 ppbv) in 1 s and ∼1.1 × 10{sup −8 }cm{sup −1} (MDL ∼ 330 pptv) in 150 s, respectively, with 1 W laser power.

  5. Spectroscopy

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules.......This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules....

  6. Mid-infrared concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy of a continuous supersonic expansion discharge source

    Science.gov (United States)

    Talicska, Courtney N.; Porambo, Michael W.; Perry, Adam J.; McCall, Benjamin J.

    2016-06-01

    Concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) is implemented for the first time on a continuous gas-flow pinhole supersonic expansion discharge source for the study of cooled molecular ions. The instrument utilizes a continuous-wave optical parametric oscillator easily tunable from 2.5 to 3.9 μm and demonstrates a noise equivalent absorption of ˜1 × 10-9 cm-1. The effectiveness of concentration-modulated NICE-OHMS is tested through the acquisition of transitions in the ν1 fundamental band of HN2+ centered near 3234 cm-1, with a signal-to-noise of ˜40 obtained for the strongest transitions. The technique is used to characterize the cooling abilities of the supersonic expansion discharge source itself, and a Boltzmann analysis determines a rotational temperature of ˜29 K for low rotational states of HN2+. Further improvements are discussed that will enable concentration-modulated NICE-OHMS to reach its full potential for the detection of molecular ions formed in supersonic expansion discharges.

  7. Cavity enhanced absorption spectroscopy for N2O detection at 2.86μm using a continuous tunable color center laser

    Institute of Scientific and Technical Information of China (English)

    Shaocheng Li(李少成); Qingxu Yu(于清旭); Maarten van Herpen; Sacco te Lintel Hekkert; Frans J. M. Harren

    2003-01-01

    The cavity enhanced absorption technique is applied to N2O detection around 2.86 μm using a continuouswave color center laser. A high-finesse triangular ring cavity is used in this technology. Transmission through the cavity is obtained by jittering the cavity-length with a piezo on one of the cavity mirrors.A minimum detectable absorption coefficient of 2 × 10-6 cm-1 is achieved with a mirror reflectivity of 99.24%, corresponding to a N2O detection limit of 600 parts per billion.

  8. Chiroptical Spectroscopy in the Vapor Phase

    Science.gov (United States)

    Lahiri, Priyanka; Long, Benjamin D.; Wiberg, Kenneth B.; Vaccaro, Patrick H.

    2011-06-01

    Electromagnetic radiation propagating through an isotropic chiral medium experiences a complex index of refraction that differs in both real (in-phase) and imaginary (in-quadrature) parts for the right-circular and left-circular polarization states that define the helicity basis. The resulting phenomena of circular birefringence (CB) and circular dichroism (CD) lead to observable effects in the form of dispersive rotation and absorptive elliptization for an impinging beam of plane-polarized light, which commonly are measured under conditions of nonresonant and resonant excitation, respectively. This talk will discuss ongoing efforts designed to elucidate the provenance of electronic optical activity under complementary solvated and isolated conditions, with the latter vapor-phase work made possible by our continuing development of Cavity Ring-Down Polarimetry (CRDP). Molecules of interest include the rigid bicyclic ketone (1R,4R)-norbornenone, where the spatial arrangement of distal alkene and carbonyl moeities gives rise to extraordinarily large specific rotation (CB) parameters that are predicted incongruously by different quantum-chemical methods; the monoterpene constitutional isomers (S)-2-carene and (S)-3-carene, which display surprisingly distinct chiroptical properties; and conjugated ketones such as (S)-verbenone, where CD probes of weak π*←n absorption bands have been performed at vibronic resolution. The disparate nature of gas-phase and condensed-phase optical activity will be highlighted, with complementary ab initio calculations serving to elucidate the structural, chemical, and electronic origins of observed behavior. T. Müller, K. B. Wiberg, P. H. Vaccaro, J. R. Cheeseman, and M. J. Frisch, J. Opt. Soc. Am. B 19, 125 (2002) P. H. Vaccaro, ``Chapter 1.II.10: Optical Rotation and Intrinsic Optical Activity'' in Comprehensive Chiroptical Spectroscopy, N. Berova, P. L. Polavarapu, K. Nakanishi, and R. W. Woody, eds. (John Wiley and Sons, Inc

  9. Measuring fast variations of δ^{18}O and δ^2H in atmospheric water vapour using laser spectroscopy: an instrument inter-comparison and characterisation study

    Science.gov (United States)

    Aemisegger, F.; Sturm, P.; Graf, P.; Sodemann, H.; Pfahl, S.; Knohl, A.; Wernli, H.

    2012-04-01

    Fast variations of stable water isotopes in water vapour have become measurable lately using novel laser spectroscopic techniques. This allows us to perform process-based investigations of the atmospheric water cycle at the time scales of significant weather events. An important prerequisite for such studies implying automatic field measurements lasting for several weeks or even months is a detailed knowledge about sources of uncertainty and instrument properties. We present a comprehensive characterisation and comparison study of two commercial laser spectroscopic systems based on cavity ring-down spectroscopy (Picarro) and off-axis integrated cavity output spectroscopy (Los Gatos Resarch). The old versions (L1115-i, WVIA) and the new versions (L2130-i, WVIA-EP) of both systems were tested. The uncertainty components of the measurements were assessed in laboratory experiments, focussing on effects of (i) water vapour mixing ratio, (ii) measurement stability, (iii) uncertainties due to calibration and (iv) response times of the isotope measurements due to adsorption-desorption processes on the tubing and measurement cavity walls. Knowledge from our laboratory experiments was used to setup a one-week field campaign for comparing measurements of the ambient isotope signals from the L1115-i and WVIA systems. The optimal calibration strategy determined for both instruments was applied as well as the correction functions for water vapour mixing ratio effects. Using this field measurement data we address the question of how well the deuterium excess (d=δ2H-8δ18O) of atmospheric water vapour can be determined with laser spectroscopy. The deuterium excess is an interesting parameter for process-based atmospheric water cycle studies, which depends on humidity and temperature conditions at source location of water vapour. Up to now only very few high-time-resolution measurements of deuterium excess exist. Our concurrent measurements of atmospheric isotopes in water vapour

  10. Remote sensing of atmospheric trace gases by diode laser spectroscopy

    Science.gov (United States)

    Liu, Jianguo; Kan, Ruifeng; He, Yabai; He, Ying; Zhang, Yujun; Xie, Pinhua; liu, Wenqing

    2016-04-01

    Gaseous ammonia is the most abundant alkaline trace gas in the atmosphere. In order to study its role in acid deposition and aerosol formation, as well as its influence on the regional air quality and atmospheric visibility, several instruments has been developed based on TDLAS (Tunable Diode Laser Absorption Spectroscopy) techniques. In this paper, a long open path TDLAS system and a continuous-wave CRDS (Cavity-Ring down Spectroscopy) system are presented. The long open path system has been developed for NH3 in-situ monitoring by combining wavelength modulation with harmonic detection techniques to obtain the necessary detection sensitivity. The prototype instrument has been used to monitor atmospheric NH3 concentration at an urban site near Beijing National Stadium during Beijing Olympics in 2008, and recently used to measure the fluxes of NH3 from farm fields by flux-gradient method. The detection limit for ammonia is proved approximately 3ppb for a total path length of 456m. The continuous-wave, rapidly swept CRDS system has been developed for localized atmospheric sensing of trace gases at remote sites. Passive open-path optical sensor units could be coupled by optical fiber over distances of >1 km to a single transmitter/receiver console incorporating a photodetector and a swept-frequency diode laser tuned to molecule-specific near-infrared wavelengths. A noise-limited minimum detectable mixing ratio of ~11 ppbv is attained for ammonia at atmospheric pressure. The developed instruments are deployable in agricultural, industrial, and natural atmospheric environments.

  11. Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by transmission electron microscopy and electron energy loss spectroscopy

    International Nuclear Information System (INIS)

    Nanoscale defect structure within the magnetic penetration depth of ~100 nm is key to the performance limitations of niobium superconducting radio frequency cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120°C baking. Furthermore, we demonstrate that adding 800°C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120°C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120°C bake

  12. Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by transmission electron microscopy and electron energy loss spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Trenikhina, Y., E-mail: yuliatr@fnal.gov [Physics Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States); Romanenko, A., E-mail: aroman@fnal.gov [Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States); Kwon, J.; Zuo, J.-M. [Materials Science and Engineering Department, University of Illinois, Urbana, Illinois 61801 (United States); Zasadzinski, J. F. [Physics Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States)

    2015-04-21

    Nanoscale defect structure within the magnetic penetration depth of ∼100 nm is key to the performance limitations of niobium superconducting radio frequency cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120 °C baking. Furthermore, we demonstrate that adding 800 °C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120 °C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120 °C bake.

  13. Measurement of OCS, CO2, CO and H2O aboard NASA's WB-57 High Altitude Platform Using Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS)

    Science.gov (United States)

    Leen, J. B.; Owano, T. G.; Du, X.; Gardner, A.; Gupta, M.

    2014-12-01

    Carbonyl sulfide (OCS) is the most abundant sulfur gas in the atmosphere and has been implicated in controlling the sulfur budget and aerosol loading of the stratosphere. In the troposphere, OCS is irreversibly consumed during photosynthesis and may serve as a tracer for gross primary production (GPP). Its primary sources are ocean outgassing, industrial processes, and biomass burning. Its primary sinks are vegetation and soils. Despite the importance of OCS in atmospheric processes, the OCS atmospheric budget is poorly determined and has high uncertainty. OCS is typically monitored using either canisters analyzed by gas chromatography or integrated atmospheric column measurements. Improved in-situ terrestrial flux and airborne measurements are required to constrain the OCS budget and further elucidate its role in stratospheric aerosol formation and as a tracer for biogenic volatile organics and photosynthesis. Los Gatos Research has developed a flight capable mid-infrared Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS) analyzer to simultaneously quantify OCS, CO2, CO, and H2O in ambient air at up to 2 Hz. The prototype was tested on diluted, certified samples and found to be precise (OCS, CO2, CO, and H2O to better than ±4 ppt, ±0.2 ppm, ±0.31 ppb, and ±3.7 ppm respectively, 1s in 1 sec) and linear (R2 > 0.9997 for all gases) over a wide dynamic range (OCS, CO2, CO, and H2O ranging from 0.2 - 70 ppb, 500 - 3000 ppm, 150 - 480 ppb, and 7000 - 21000 ppm respectively). Cross-interference measurements showed no appreciable change in measured OCS concentration with variations in CO2 (500 - 3500 ppm) or CO. We report on high altitude measurements made aboard NASA's WB-57 research aircraft. Two research flights were conducted from Houston, TX. The concentration of OCS, CO2, CO, and H2O were continuously recorded from sea level to approximately 60,000 feet. The concentration of OCS was observed to increase with altitude through the troposphere due to the

  14. Time-resolved in situ detection of CO in a shock tube using cavity-enhanced absorption spectroscopy with a quantum-cascade laser near 4.6 µm.

    Science.gov (United States)

    Sun, Kai; Wang, Shengkai; Sur, Ritobrata; Chao, Xing; Jeffries, Jay B; Hanson, Ronald K

    2014-10-01

    Cavity-enhanced absorption spectroscopy (CEAS) using a mid-infrared DFB quantum-cascade laser is reported for sensitive time-resolved (10 μs) in situ CO measurements in a shock tube. Off-axis alignment and fast scanning of the laser wavelength were used to minimize coupling noise in a low-finesse cavity. An absorption gain factor of 91 was demonstrated, which enabled sub-ppm detection sensitivity for gas temperatures of 1000-2100K in a 15 cm diameter shock tube. This substantial improvement in detection sensitivity compared to conventional single-pass absorption measurements, shows great potential for the study of reaction pathways of high-temperature combustion kinetics mechanisms in shock tubes.

  15. Cavity magnomechanics.

    Science.gov (United States)

    Zhang, Xufeng; Zou, Chang-Ling; Jiang, Liang; Tang, Hong X

    2016-03-01

    A dielectric body couples with electromagnetic fields through radiation pressure and electrostrictive forces, which mediate phonon-photon coupling in cavity optomechanics. In a magnetic medium, according to the Korteweg-Helmholtz formula, which describes the electromagnetic force density acting on a medium, magneostrictive forces should arise and lead to phonon-magnon interaction. We report such a coupled phonon-magnon system based on ferrimagnetic spheres, which we term as cavity magnomechanics, by analogy to cavity optomechanics. Coherent phonon-magnon interactions, including electromagnetically induced transparency and absorption, are demonstrated. Because of the strong hybridization of magnon and microwave photon modes and their high tunability, our platform exhibits new features including parametric amplification of magnons and phonons, triple-resonant photon-magnon-phonon coupling, and phonon lasing. Our work demonstrates the fundamental principle of cavity magnomechanics and its application as a new information transduction platform based on coherent coupling between photons, phonons, and magnons. PMID:27034983

  16. Dental cavities

    Science.gov (United States)

    ... leading to cavities. Treatment may involve: Fillings Crowns Root canals Dentists fill teeth by removing the decayed tooth ... gold, porcelain, or porcelain attached to metal. A root canal is recommended if the nerve in a tooth ...

  17. radiofrequency cavity

    CERN Multimedia

    1988-01-01

    The pulse of a particle accelerator. 128 of these radio frequency cavities were positioned around CERN's 27-kilometre LEP ring to accelerate electrons and positrons. The acceleration was produced by microwave electric oscillations at 352 MHz. The electrons and positrons were grouped into bunches, like beads on a string, and the copper sphere at the top stored the microwave energy between the passage of individual bunches. This made for valuable energy savings as it reduced the heat generated in the cavity.

  18. Time-resolved spectral characterization of ring cavity surface emitting and ridge-type distributed feedback quantum cascade lasers by step-scan FT-IR spectroscopy.

    Science.gov (United States)

    Brandstetter, Markus; Genner, Andreas; Schwarzer, Clemens; Mujagic, Elvis; Strasser, Gottfried; Lendl, Bernhard

    2014-02-10

    We present the time-resolved comparison of pulsed 2nd order ring cavity surface emitting (RCSE) quantum cascade lasers (QCLs) and pulsed 1st order ridge-type distributed feedback (DFB) QCLs using a step-scan Fourier transform infrared (FT-IR) spectrometer. Laser devices were part of QCL arrays and fabricated from the same laser material. Required grating periods were adjusted to account for the grating order. The step-scan technique provided a spectral resolution of 0.1 cm(-1) and a time resolution of 2 ns. As a result, it was possible to gain information about the tuning behavior and potential mode-hops of the investigated lasers. Different cavity-lengths were compared, including 0.9 mm and 3.2 mm long ridge-type and 0.97 mm (circumference) ring-type cavities. RCSE QCLs were found to have improved emission properties in terms of line-stability, tuning rate and maximum emission time compared to ridge-type lasers.

  19. accelerating cavity

    CERN Multimedia

    On the inside of the cavitytThere is a layer of niobium. Operating at 4.2 degrees above absolute zero, the niobium is superconducting and carries an accelerating field of 6 million volts per metre with negligible losses. Each cavity has a surface of 6 m2. The niobium layer is only 1.2 microns thick, ten times thinner than a hair. Such a large area had never been coated to such a high accuracy. A speck of dust could ruin the performance of the whole cavity so the work had to be done in an extremely clean environment.

  20. Computational Spectroscopy of Polycyclic Aromatic Hydrocarbons In Support of Laboratory Astrophysics

    Science.gov (United States)

    Tan, Xiaofeng; Salama, Farid

    2006-01-01

    Polycyclic aromatic hydrocarbons (PAHs) are strong candidates for the molecular carriers of the unidentified infrared bands (UIR) and the diffuse interstellar bands (DIBs). In order to test the PAH hypothesis, we have systematically measured the vibronic spectra of a number of jet-cooled neutral and ionized PAHs in the near ultraviolet (UV) to visible spectral ranges using the cavity ring-down spectroscopy. To support this experimental effort, we have carried out theoretical studies of the spectra obtained in our measurements. Ab initio and (time-dependent) density.functiona1 theory calculations are performed to obtain the geometries, energetics, vibrational frequencies, transition dipole moments, and normal coordinates of these PAH molecules. Franck-Condon (FC) calculations and/or vibronic calculations are then performed using the calculated normal coordinates and vibrational frequencies to simulate the vibronic spectra. It is found that vibronic interactions in these conjugated pi electron systems are often strong enough to cause significant deviations from the Born-Oppenheimer (BO) approximation. For vibronic transitions that are well described by the BO approximation, the vibronic band profiles are simulated by calculating the rotational structure of the vibronic transitions. Vibronic oscillator strength factors are calculated in the frame of the FC approximation from the electronic transition dipole moments and the FC factors. This computational effort together with our experimental measurements provides, for the first time, powerful tools for comparison with space-based data and, hence, a powerful approach to understand the spectroscopy of interstellar PAH analogs and the nature of the UIR and DIBs.

  1. Development of a cavity enhanced aerosol albedometer

    OpenAIRE

    Zhao, W.; Xu, X.; Dong, M.; Chen, W.; X. Gu; Hu, C; Huang, Y.; Gao, X; Huang, W.; Zhang, W

    2014-01-01

    We report on the development of a cavity enhanced aerosol single scattering albedometer incorporating incoherent broad-band cavity-enhanced spectroscopy (IBBCEAS) approach and an integrating sphere (IS) for simultaneous in situ measurements of aerosol scattering and extinction coefficients in the exact same sample volume. The cavity enhanced albedometer employed a blue light-emitting diode (LED) based IBBCEAS approach for the measurement of wavelength-resolv...

  2. Highly stable piezoelectrically tunable optical cavities

    CERN Document Server

    Möhle, Katharina; Döringshoff, Klaus; Nagel, Moritz; Peters, Achim

    2013-01-01

    We have implemented highly stable and tunable frequency references using optical high finesse cavities which incorporate a piezo actuator. As piezo material we used ceramic PZT, crystalline quartz, or PZN-PT single crystals. Lasers locked to these cavities show a relative frequency stability better than 1 x 10^{-14}, which is most likely not limited by the piezo actuators. The piezo cavities can be electrically tuned over more than one free spectral range (> 1.5 GHz) with only a minor decrease in frequency stability. Furthermore, we present a novel cavity design, where the piezo actuator is prestressed between the cavity spacer components. This design features a hermetically sealable intra cavity volume suitable for, e.g., cavity enhanced spectroscopy.

  3. 非相干宽带腔增强吸收光谱技术应用于实际大气亚硝酸的测量%Incoherent broadband cavity enhanced absorption spectroscopy for measurements of atmospheric HONO

    Institute of Scientific and Technical Information of China (English)

    段俊; 秦敏; 方武; 凌六一; 胡仁志; 卢雪; 沈兰兰; 王丹; 谢品华

    2015-01-01

    介绍了基于紫外发光二极管光源的非相干宽带腔增强吸收光谱技术,并用于实际大气亚硝酸(HONO)和二氧化氮(NO2 )的同时测量. 分析了腔内气体的瑞利散射对测量的影响,测试了紫外发光二极管光源的稳定性,使用氦气和氮气的瑞利散射差异性标定了镜片反射率随波长的变化曲线,在HONO吸收峰(368.2 nm)处镜片反射率约为0.99965. 应用Allan方差统计方法确定出测量光谱最佳采集时间为320 s, 对应的HONO和NO2的探测限(1σ)分别为0.22 ppb和0.45 ppb. 使用非相干宽带腔增强吸收光谱测量装置对大气HONO和NO2进行了连续三日的实际观测, 将测量得到的HONO浓度变化与差分吸收光谱测量装置的测量结果进行对比,线性相关系数R2为0.917.%We report the development of an incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) based on an ultraviolet light emitting diode (UV-LED), and the IBBCEAS instrument is used for simultaneously measuring of the atmospheric HONO and NO2. The cavity-enhanced method is characterized by high sensitivity and spatial resolution. The incoherent broadband light is focused into a high-finesse optical cavity, two highly reflecting mirrors form the ends of the cavity, and the light is then trapped between the two highly reflecting mirrors, resulting in long photon residence time and long optical path length. The effects of the Rayleigh scattering of the gases in the cavity and stability of the UV-LED light source were discussed in this paper. The reflectivity of the highly reflecting mirror was calibrated by the difference of Rayleigh scattering of He and N2, and the optimum averaging time of the IBBCEAS instrument was confirmed to be 320 s by the Allan variance analysis. Detection limits (1σ) of 0.22 ppb for HONO and 0.45 ppb for NO2 were achieved with an optimum acquisition time of 320 s. In order to test the accuracy of measured results by the IBBCEAS instrument

  4. Protein dynamics: hydration and cavities

    Directory of Open Access Journals (Sweden)

    Heremans K.

    2005-01-01

    Full Text Available The temperature-pressure behavior of proteins seems to be unique among the biological macromolecules. Thermodynamic as well as kinetic data show the typical elliptical stability diagram. This may be extended by assuming that the unfolded state gives rise to volume and enthalpy-driven liquid-liquid transitions. A molecular interpretation follows from the temperature and the pressure dependence of the hydration and cavities. We suggest that positron annihilation spectroscopy can provide additional quantitative evidence for the contributions of cavities to the dynamics of proteins. Only mature amyloid fibrils that form from unfolded proteins are very resistant to pressure treatment.

  5. Cavity magnomechanics

    Science.gov (United States)

    Zou, Chang-Ling; Zhang, Xufeng; Jiang, Liang; Tang, Hong

    2016-05-01

    Recently, cavity magnonics has attracted much attention for potential applications of coherent information transduction and hybrid quantum devices. The magnon is a collective spin wave excitation in ferromagnetic material. It is magnetically tunability, with long coherence time and non-reciprocical interaction with electro-magnetic fields. We report the coherent coupling between magnon, microwave photon and phonon. First, we demonstrate strong coupling and ultrastrong coupling between the magnon in YIG sphere and microwave photon in three-dimensional cavity. Then, based on the hybridized magnon-photon modes, we observe the triply resonant magnon-mcirowave photon-phonon coupling, where the ultrahigh-Q mechanical vibration of YIG sphere is dispersively coupled with the magnon via magnetostrictive interaction. We observe interesting phenomena, including electromagnetically induced transparency/absorption and parametric amplification. In particular, benefit from the large tunability of the magnon, we demonstrate a tunable microwave amplifier with gain as high as 30 dB. The single crystal YIG also has excellent optical properties, and thus provide a unique platform bridging MHz, GHz and THz information carriers. Finally, we present the latest progress towards coherent magnon to optical photon conversion.

  6. Investigation of GaInNAs/GaAs quantum wells and vertical-cavity surface-emitting laser structures using modulated reflectance spectroscopy

    CERN Document Server

    Choulis, S A

    2001-01-01

    study on a representative InGaAs/GaAs/AlAs/AIGaAs as-grown VCSEL structure, using PR spectroscopy as a function of position on a non-uniform wafer. We also show how temperature dependent PR and the appropriate lineshape model can be used to obtain a full picture of the relative movements between the gain and the CM over the full range of temperature. This information allows calculating the material gain in the temperature range of interest, independent from the effect of the CM and also provides an alternative method for characterising the growth, which can be applied to uniform wafers. PR and non-destructive ER can be used to identify regions suitable for fabrication into devices. For this reason modulation spectroscopy can be very useful for industry to reject wafers where good alignment between the CM and the QW does not occur and can thus save on the time consuming and expensive fabrication procedures. We investigate the electronic band structure of device relevant GaInNAs/GaAs multiple quantum wells (MQW...

  7. 2OH Overtone Spectroscopy of Water-Containing Van Der Waals Species

    Science.gov (United States)

    Vanfleteren, Thomas; Földes, Tomas; Herman, Michel; Liévin, Jacques; Loreau, Jérome; Coudert, L. H.

    2016-06-01

    We have used continuous-wave cavity ring-down spectroscopy to record part of the 2OH excitation range in an Ar/Kr supersonic expansion seeded with H_2O. Various bands were observed, and are being rotationally analyzed, of Ar-H_2O and Kr-H_2O. The analysis of experimental linewidths allowed us to determine the mean upper state predissociation lifetime to be 3 ns for Ar-H_2O and 4 ns for Kr-H_2O. In this talk, the latest results concerning Ar-H_2O will be presented. Several bands were identified and analyzed, highlighting some strong perturbations. The assignment of the many bands, as well as the perturbation processes, is complicated and is still in progress. The results of the analysis will be presented along with the perturbing effects of the dark states. Identification of these will be attempted using a multidimensional approach, based on the intramolecular potential energy surface of water monomer and on the intermolecular potential energy surface of the complex, allowing us to evaluate the rovibrational energy levels of H_2O perturbed by the argon atom. Although several such intermolecular potentials are already available, like those reported by Makarewicz and by Hou et al., none of them can be used in the present investigation as they were designed for vibrational states of the water monomer below the (101) state, involved in the present spectra. A 6D intermolecular potential energy surface is currently being computed through ab initio calculations to deal with high lying states of the water monomer like the (101) state. With the help of this new surface and of the multidimensional approach, we are hoping to assign the bright and the dark states of the complex, near 7 500 cm-1, involved in the present spectra. H. Partridge and D. W. Schwenke, J. Chem. Phys. 106 (1997) 4618. J. Makarewicz, J. Chem. Phys. 129 (2008) 184310.

  8. Near Infrared Cavity Enhanced Absorption Spectroscopy Study of N2 O%N2 O的近红外腔增强吸收光谱技术研究

    Institute of Scientific and Technical Information of China (English)

    吴志伟; 董燕婷; 周卫东

    2014-01-01

    Using a tunable near infrared external cavity diode laser and a 650mm long high finesse optical cavity consisting of two highly reflective (R= 99. 97% at 6 561. 39 cm-1 )plan-concave mirrors of curvature radius ~1 000 mm,a cavity enhanced ab-sorption spectroscopy (CEAS)system was made.The absorption spectra centered at 6 561. 39 cm-1 of pure N2 O gas and gas mixtures of N2 O and N2 were recorded.According to the absorption of N2 O at 6 561. 39 cm-1 in the cavity,the measured effec-tive absorption path was about 1 460 km.The spectra line intensity and line-width of N2 O centered at 6 561. 39 cm-1 were care-fully studied.The relationship between the line-width of absorption spectra and the gas pressure was derived.The pressure broadening parameter of N2 gas for N2O line centered at 6 561. 39 cm-1 was deduced and given a value of ~(0. 114±0. 004) cm-1 ·atm-1 .The possibility to detect trace N2 O gas in mixture using this CEAS system was investigated.By recording the ab-sorption spectra of N2 O gas mixtures at different concentration,the relationship between the line intensity and gas concentration was derived.The minimum detectable absorption was found to be 2. 34×10-7 cm-1 using this cavity enhanced absorption spec-troscopy system.And te measurement precision in terms of relative standard deviation (RSD)for N2 O is ~1. 73%,indicating the possibility of using the cavity enhanced absorption spectroscopy system for micro gas N2 O analysis in the future.%以外腔式可调谐、窄线宽近红外半导体激光为光源,以一对曲率半径r=1000 mm 的宽带高反射率平凹镜(反射率R=99.97%)构成的腔长为650 mm的对称高精度光学稳定腔,建立了腔增强吸收光谱系统。详细研究了纯净 N2 O 气体、以及 N2 O 和 N2的混合气体在不同浓度和不同气压下、中心波长位于6561.39 cm-1的腔增强吸收光谱、光谱强度和谱线宽度,该腔增强吸收光谱系统的有效吸收光程可达1460 km。

  9. Cavity magnomechanics

    Science.gov (United States)

    Zhang, Xufeng; Zou, Changling; Jiang, Liang; Tang, Hong X.

    Mechanical oscillators have been recently widely utilized to couple with optical and microwave photons in a variety of hybrid quantum systems, but they all lack the tunability. The magnetostrictive force provides an alternative mechanism to allow phonon to couple with a different type of information carrier-magnon, the collective excitation of magnetization whose frequency can be tuned by a bias magnetic field. Here, we demonstrate an intriguing hybrid system that consists of a magnonic, a mechanical, and a microwave resonator. The magnon-phonon interaction results in hallmark coherent phenomena such as magnomechanically induced transparency/absorption and magnomechanical parametric amplification. The magnetic field dependence of magnon provides our system with unprecedented tunability. Moreover, the great flexibility of our system allows us to achieve triple resonance among magnon, phonon and photon, which drastically enhances the magnomechanical interaction. Our work demonstrates the fundamental principle of cavity magnetomechanics, opening up great opportunities in various applications, such as tunable microwave filter and amplifier, long-lifetime quantum memories, microwave-to-optics conversion.

  10. Evaluation of continuous water vapor δD and δ18O measurements by off-axis integrated cavity output spectroscopy

    Science.gov (United States)

    Kurita, N.; Newman, B. D.; Araguas-Araguas, L. J.; Aggarwal, P.

    2012-08-01

    Recent commercially available laser spectroscopy systems enabled us to continuously and reliably measure the δD and δ18O of atmospheric water vapor. The use of this new technology is becoming popular because of its advantages over the conventional approach based on cold trap collection. These advantages include much higher temporal resolution/continuous monitoring and the ability to make direct measurements of both isotopes in the field. Here, we evaluate the accuracy and precision of the laser based water vapor isotope instrument through a comparison of measurements with those found using the conventional cold trap method. A commercially available water vapor isotope analyzer (WVIA) with the vaporization system of a liquid water standard (Water Vapor Isotope Standard Source, WVISS) from Los Gatos Research (LGR) Inc. was used for this study. We found that the WVIA instrument can provide accurate results if (1) correction is applied for time-dependent isotope drift, (2) normalization to the VSMOW/SLAP scale is implemented, and (3) the water vapor concentration dependence of the isotopic ratio is also corrected. In addition, since the isotopic value of water vapor generated by the WVISS is also dependent on the concentration of water vapor, this effect must be considered to determine the true water vapor concentration effect on the resulting isotope measurement. To test our calibration procedure, continuous water vapor isotope measurements using both a laser instrument and a cold trap system were carried out at the IAEA Isotope Hydrology Laboratory in Vienna from August to December 2011. The calibrated isotopic values measured using the WVIA agree well with those obtained via the cold trap method. The standard deviation of the isotopic difference between both methods is about 1.4‰ for δD and 0.28‰ for δ18O. This precision allowed us to obtain reliable values for d-excess. The day-to-day variation of d-excess measured by WVIA also agrees well with that found

  11. Evaluation of continuous water vapor δD and δ18O measurements by off-axis integrated cavity output spectroscopy

    Directory of Open Access Journals (Sweden)

    L. J. Araguas-Araguas

    2012-08-01

    Full Text Available Recent commercially available laser spectroscopy systems enabled us to continuously and reliably measure the δD and δ18O of atmospheric water vapor. The use of this new technology is becoming popular because of its advantages over the conventional approach based on cold trap collection. These advantages include much higher temporal resolution/continuous monitoring and the ability to make direct measurements of both isotopes in the field. Here, we evaluate the accuracy and precision of the laser based water vapor isotope instrument through a comparison of measurements with those found using the conventional cold trap method. A commercially available water vapor isotope analyzer (WVIA with the vaporization system of a liquid water standard (Water Vapor Isotope Standard Source, WVISS from Los Gatos Research (LGR Inc. was used for this study. We found that the WVIA instrument can provide accurate results if (1 correction is applied for time-dependent isotope drift, (2 normalization to the VSMOW/SLAP scale is implemented, and (3 the water vapor concentration dependence of the isotopic ratio is also corrected. In addition, since the isotopic value of water vapor generated by the WVISS is also dependent on the concentration of water vapor, this effect must be considered to determine the true water vapor concentration effect on the resulting isotope measurement. To test our calibration procedure, continuous water vapor isotope measurements using both a laser instrument and a cold trap system were carried out at the IAEA Isotope Hydrology Laboratory in Vienna from August to December 2011. The calibrated isotopic values measured using the WVIA agree well with those obtained via the cold trap method. The standard deviation of the isotopic difference between both methods is about 1.4‰ for δD and 0.28‰ for δ18O. This precision allowed us to obtain reliable values for d-excess. The day-to-day variation of d-excess measured by WVIA also agrees well

  12. Evaluation of continuous water vapor δD and δ18O measurements by off-axis integrated cavity output spectroscopy

    Directory of Open Access Journals (Sweden)

    L. J. Araguas-Araguas

    2012-04-01

    Full Text Available Recent commercially available laser spectroscopy systems enabled us to continuously and reliably measure the δD and δ18O of atmospheric water vapor. The use of this new technology is becoming popular because of its advantages over the conventional approach based on cold trap collection. These advantages include much higher temporal resolution/continuous monitoring and the ability to make direct measurements of both isotopes in the field. Here, we evaluate the accuracy and precision of the laser based water vapor isotope instrument through a comparison of measurements with those found using the conventional cold trap method. A commercially available water vapor isotope analyzer (WVIA with the vaporization system of a liquid water standard (Water Vapor Isotope Standard Source, WVISS from Los Gatos Research (LGR Inc. was used for this study. We found that the WVIA instrument can provide accurate results if: (1 correction is applied for time-dependent isotope drift, (2 normalization to the VSMOW/SLAP scale is implemented, and (3 the water vapor concentration dependence of the isotopic ratio is also corrected. In addition, since the isotopic value of water vapor generated by the WVISS is also dependent on the concentration of water vapor, this effect must be considered to determine the true water vapor concentration effect on the resulting isotope measurement. To test our calibration procedure, continuous water vapor isotope measurements using both a laser instrument and a cold trap system were carried out at the IAEA Isotope Hydrology Laboratory in Vienna from August to December 2011. The calibrated isotopic values measured using the WVIA agree well with those obtained via the cold trap method. The standard deviation of the isotopic difference between both methods is about 1.4‰ for δD and 0.28‰ for δ18O. This precision allowed us to obtain reliable values for d-excess. The day-to-day variation of d-excess measured by WVIA also agrees well

  13. Crab Cavity Development

    CERN Document Server

    Calaga, R; Burt, G; Ratti, A

    2015-01-01

    The HL-LHC upgrade will use deflecting (or crab) cavities to compensate for geometric luminosity loss at low β* and non-zero crossing angle. A local scheme with crab cavity pairs across the IPs is used employing compact crab cavities at 400 MHz. Design of the cavities, the cryomodules and the RF system is well advanced. The LHC crab cavities will be validated initially with proton beam in the SPS.

  14. High accuracy laboratory spectroscopy to support active greenhouse gas sensing

    Science.gov (United States)

    Long, D. A.; Bielska, K.; Cygan, A.; Havey, D. K.; Okumura, M.; Miller, C. E.; Lisak, D.; Hodges, J. T.

    2011-12-01

    Recent carbon dioxide (CO2) remote sensing missions have set precision targets as demanding as 0.25% (1 ppm) in order to elucidate carbon sources and sinks [1]. These ambitious measurement targets will require the most precise body of spectroscopic reference data ever assembled. Active sensing missions will be especially susceptible to subtle line shape effects as the narrow bandwidth of these measurements will greatly limit the number of spectral transitions which are employed in retrievals. In order to assist these remote sensing missions we have employed frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) [2], a high-resolution, ultrasensitive laboratory technique, to measure precise line shape parameters for transitions of O2, CO2, and other atmospherically-relevant species within the near-infrared. These measurements have led to new HITRAN-style line lists for both 16O2 [3] and rare isotopologue [4] transitions in the A-band. In addition, we have performed detailed line shape studies of CO2 transitions near 1.6 μm under a variety of broadening conditions [5]. We will address recent measurements in these bands as well as highlight recent instrumental improvements to the FS-CRDS spectrometer. These improvements include the use of the Pound-Drever-Hall locking scheme, a high bandwidth servo which enables measurements to be made at rates greater than 10 kHz [6]. In addition, an optical frequency comb will be utilized as a frequency reference, which should allow for transition frequencies to be measured with uncertainties below 10 kHz (3×10-7 cm-1). [1] C. E. Miller, D. Crisp, P. L. DeCola, S. C. Olsen, et al., J. Geophys. Res.-Atmos. 112, D10314 (2007). [2] J. T. Hodges, H. P. Layer, W. W. Miller, G. E. Scace, Rev. Sci. Instrum. 75, 849-863 (2004). [3] D. A. Long, D. K. Havey, M. Okumura, C. E. Miller, et al., J. Quant. Spectrosc. Radiat. Transfer 111, 2021-2036 (2010). [4] D. A. Long, D. K. Havey, S. S. Yu, M. Okumura, et al., J. Quant. Spectrosc

  15. Laser spectroscopy

    CERN Document Server

    Demtröder, Wolfgang

    2008-01-01

    Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., frequency doubling in external cavities, reliable cw-parametric oscillators, tunable narrow-band UV sources, more sensitive detection techniques, tunable femtosecond and sub-femtosecond lasers (X-ray region and the attosecond range), control of atomic and molecular excitations, frequency combs able to synchronize independent femtosecond lasers, coherent matter waves, and still more applications in chemical analysis, medical diagnostics, and engineering.

  16. RF Cavity Design

    CERN Document Server

    Jensen, E

    2014-01-01

    After a short overview of a general approach to cavity design, we sketch the derivation of waveguide modes from plane waves and of cavity fields from waveguide modes. The characteristic parameters describing cavities and their performance are defined and explained. An equivalent circuit is introduced and extended to explain beam loading and higher order modes. Finally travelling- and standing-wave multi-gap cavities are introduced using the Brillouin diagram.

  17. Dawn of Cavity Spintronics

    OpenAIRE

    Hu, Can-Ming

    2015-01-01

    Merging the progress of spintronics with the advancement in cavity quantum electrodynamics and cavity polaritons, a new field of Cavity Spintronics is forming, which connects some of the most exciting modern physics, such as quantum information and quantum optics, with one of the oldest science on the earth, the magnetism.

  18. Photonic crystal cavities with metallic Schottky contacts

    International Nuclear Information System (INIS)

    We report about the fabrication and analysis of high Q photonic crystal cavities with metallic Schottky-contacts. The structures are based on GaAs n-i membranes with an InGaAs quantum well in the i-region and nanostructured low ohmic metal top-gates. They are designed for photocurrent readout within the cavity and fast electric manipulations. The cavity structures are characterized by photoluminescence and photocurrent spectroscopy under resonant excitation. We find strong cavity resonances in the photocurrent spectra and surprisingly high Q-factors up to 6500. Temperature dependent photocurrent measurements in the region between 4.5 K and 310 K show an exponential enhancement of the photocurrent signal and an external quantum efficiency up to 0.26

  19. Real-time analysis of δ13C- and δD-CH4 in ambient air with laser spectroscopy: method development and first intercomparison results

    Directory of Open Access Journals (Sweden)

    S. Eyer

    2015-08-01

    Full Text Available In situ and simultaneous measurement of the three most abundant isotopologues of methane using mid-infrared laser absorption spectroscopy is demonstrated. A field-deployable, autonomous platform is realized by coupling a compact quantum cascade laser absorption spectrometer (QCLAS to a preconcentration unit, called TRace gas EXtractor (TREX. This unit enhances CH4 mole fractions by a factor of up to 500 above ambient levels and quantitatively separates interfering trace gases such as N2O and CO2. The analytical precision of the QCLAS isotope measurement on the preconcentrated (750 ppm, parts-per-million, μmole/mole methane is 0.1 and 0.5 ‰ for δ13C- and δD-CH4 at 10 min averaging time. Based on replicate measurements of compressed air during a two-week intercomparison campaign, the repeatability of the TREX-QCLAS was determined to be 0.19 and 1.9 ‰ for δ13C and δD-CH4, respectively. In this intercomparison campaign the new in situ technique is compared to isotope-ratio mass-spectrometry (IRMS based on glass flask and bag sampling and real time CH4 isotope analysis by two commercially available laser spectrometers. Both laser-based analyzers were limited to methane mole fraction and δ13C-CH4 analysis, and only one of them, a cavity ring down spectrometer, was capable to deliver meaningful data for the isotopic composition. After correcting for scale offsets, the average difference between TREX–QCLAS data and bag/flask sampling–IRMS values are within the extended WMO compatibility goals of 0.2 and 5 ‰ for δ13C- and δD-CH4, respectively. Thus, the intercomparison also reveals the need for reference air samples with accurately determined isotopic composition of CH4 to further improve the interlaboratory compatibility.

  20. New on-line method for water isotope analysis of fluid inclusions in speleothems using laser absorption spectroscopy: Application to stalagmites from Borneo and Switzerland

    Science.gov (United States)

    Affolter, Stéphane; Fleitmann, Dominik; Nele Meckler, Anna; Leuenberger, Markus

    2014-05-01

    Speleothems are recognised as key continental archives for paleoclimate reconstructions. They contain fluid inclusions representing past drip water trapped in the calcite structure. Speleothem can be precisely dated and therefore the oxygen (δ18O) and hydrogen (δD) isotopes of fluid inclusions constitute powerful proxies for paleotemperature or to investigate changes in the moisture source over several interglacial-glacial cycles. To liberate fluid inclusion water and to analyse its isotopic composition, a new online extraction method developed at Bern is used. The principle can be summarised as follows: Prior to crushing, the sample is placed into a copper tube, fixed to the line previously heated to 140° C and flushed with a nitrogen and standard water mixture. Thereafter, the speleothem sample is crushed using a simple hydraulic crushing device and the released water from fluid inclusions is transferred by the nitrogen-standard water mixture flow to a Picarro L1102-i isotopic liquid water and water vapor analyser. The measuring principle is based on wavelength-scanned cavity ring-down spectroscopy (WS-CRDS) technology that allows us to simultaneously monitor hydrogen and oxygen isotopes. Reproducibility of standard water measurements is typically better than 1.5 o for δD and 0.4 o for δ18O. With this method, we successfully analysed δD and δ18O isotopic composition of a stalagmite from Northern Borneo (tropical West Pacific) covering almost two glacial-interglacial cycles from MIS 12 to early MIS 9 (460-330 ka) as well as recent samples from Switzerland and Borneo. These results are used in combination with calcite δ18O to reconstruct paleotemperature. Currently, we are measuring a stalagmite from Milandre cave (Jura, Switzerland) covering the Bølling-Allerød, Younger Dryas cold phase and the Holocene.

  1. Complete Measurement of Stable Isotopes in N2O (δ15N, δ15Nα, δ15Nβ, δ18O, δ17O) Using Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS)

    Science.gov (United States)

    Leen, J. B.; Gupta, M.

    2014-12-01

    Nitrate contamination in water is a worldwide environmental problem and source apportionment is critical to managing nitrate pollution. Fractionation caused by physical, chemical and biological processes alters the isotope ratios of nitrates (15N/14N, 18O/16O and 17O/16O) and biochemical nitrification and denitrification impart different intramolecular site preference (15N14NO vs. 14N15NO). Additionally, atmospheric nitrate is anomalously enriched in 17O compared to other nitrate sources. The anomaly (Δ17O) is conserved during fractionation processes, providing a tracer of atmospheric nitrate. All of these effects can be used to apportion nitrate in soil. Current technology for measuring nitrate isotopes is complicated and costly - it involves conversion of nitrate to nitrous oxide (N2O), purification, preconcentration and measurement by isotope ratio mass spectrometer (IRMS). Site specific measurements require a custom IRMS. There is a pressing need to make this measurement simpler and more accessible. Los Gatos Research has developed a next generation mid-infrared Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS) analyzer to quantify all stable isotope ratios of N2O (δ15N, δ15Nα, δ15Nβ, δ18O, δ17O). We present the latest performance data demonstrating the precision and accuracy of the OA-ICOS based measurement. At an N2O concentration of 322 ppb, the analyzer quantifies [N2O], δ15N, δ15Na, δ15Nb, and δ18O with a precision of ±0.05 ppb, ±0.4 ‰, ±0.45 ‰, and ±0.6 ‰, and ±0.8 ‰ respectively (1σ, 100s; 1σ, 1000s for δ18O). Measurements of gas standards demonstrate accuracy better than ±1 ‰ for isotope ratios over a wide dynamic range (200 - 100,000 ppb). The measurement of δ17O requires a higher concentration (1 - 50 ppm), easily obtainable through conversion of nitrates in water. For 10 ppm of N2O, the instrument achieves a δ17O precision of ±0.05 ‰ (1σ, 1000s). This performance is sufficient to quantify atmospheric

  2. Beam cavity interaction

    CERN Document Server

    Gamp, A

    2011-01-01

    We begin by giving a description of the rf generator-cavity-beam coupled system in terms of basic quantities. Taking beam loading and cavity detuning into account, expressions for the cavity impedance as seen by the generator and as seen by the beam are derived. Subsequently methods of beam-loading compensation by cavity detuning, rf feedback, and feed-forward are described. Examples of digital rf phase and amplitude control for the special case of superconducting cavities are also given. Finally, a dedicated phase loop for damping synchrotron oscillations is discussed.

  3. Supersonic flows over cavities

    Institute of Scientific and Technical Information of China (English)

    Tianwen FANG; Meng DING; Jin ZHOU

    2008-01-01

    The characteristics of supersonic cold flows over cavities were investigated experimentally and numer-ically, and the effects of cavities of different sizes on super-sonic flow field were analyzed. The results indicate that the ratio of length to depth L/D within the range of 5-9 has little relevance to integral structures of cavity flow. The bevel angle of the rear wall does not alter the overall structure of the cavity flow within the range of 30°-60°, but it can exert obvious effect on the evolvement of shear layer and vortexes in cavities.

  4. Cavity turnover and equilibrium cavity densities in a cottonwood bottomland

    Science.gov (United States)

    Sedgwick, James A.; Knopf, Fritz L.

    1992-01-01

    A fundamental factor regulating the numbers of secondary cavity nesting (SCN) birds is the number of extant cavities available for nesting. The number of available cavities may be thought of as being in an approximate equilibrium maintained by a very rough balance between recruitment and loss of cavities. Based on estimates of cavity recruitment and loss, we ascertained equilibrium cavity densities in a mature plains cottonwood (Populus sargentii) bottomland along the South Platte River in northeastern Colorado. Annual cavity recruitment, derived from density estimates of primary cavity nesting (PCN) birds and cavity excavation rates, was estimated to be 71-86 new cavities excavated/100 ha. Of 180 active cavities of 11 species of cavity-nesting birds found in 1985 and 1986, 83 were no longer usable by 1990, giving an average instantaneous rate of cavity loss of r = -0.230. From these values of cavity recruitment and cavity loss, equilibrium cavity density along the South Platte is 238-289 cavities/100 ha. This range of equilibrium cavity density is only slightly above the minimum of 205 cavities/100 ha required by SCN's and suggests that cavity availability may be limiting SCN densities along the South Platte River. We submit that snag management alone does not adequately address SCN habitat needs, and that cavity management, expressed in terms of cavity turnover and cavity densities, may be more useful.

  5. Electromagnetic SCRF Cavity Tuner

    Energy Technology Data Exchange (ETDEWEB)

    Kashikhin, V.; Borissov, E.; Foster, G.W.; Makulski, A.; Pischalnikov, Y.; Khabiboulline, T.; /Fermilab

    2009-05-01

    A novel prototype of SCRF cavity tuner is being designed and tested at Fermilab. This is a superconducting C-type iron dominated magnet having a 10 mm gap, axial symmetry, and a 1 Tesla field. Inside the gap is mounted a superconducting coil capable of moving {+-} 1 mm and producing a longitudinal force up to {+-} 1.5 kN. The static force applied to the RF cavity flanges provides a long-term cavity geometry tuning to a nominal frequency. The same coil powered by fast AC current pulse delivers mechanical perturbation for fast cavity tuning. This fast mechanical perturbation could be used to compensate a dynamic RF cavity detuning caused by cavity Lorentz forces and microphonics. A special configuration of magnet system was designed and tested.

  6. LEP copper accelerating cavities

    CERN Multimedia

    Laurent Guiraud

    1999-01-01

    These copper cavities were used to generate the radio frequency electric field that was used to accelerate electrons and positrons around the 27-km Large Electron-Positron (LEP) collider at CERN, which ran from 1989 to 2000. The copper cavities were gradually replaced from 1996 with new superconducting cavities allowing the collision energy to rise from 90 GeV to 200 GeV by mid-1999.

  7. Cavity spin optodynamics

    CERN Document Server

    Brahms, N

    2010-01-01

    The dynamics of a large quantum spin coupled parametrically to an optical resonator is treated in analogy with the motion of a cantilever in cavity optomechanics. New spin optodynamic phenonmena are predicted, such as cavity-spin bistability, optodynamic spin-precession frequency shifts, coherent amplification and damping of spin, and the spin optodynamic squeezing of light.

  8. Superconducting cavities for LEP

    CERN Multimedia

    1983-01-01

    Above: a 350 MHz superconducting accelerating cavity in niobium of the type envisaged for accelerating electrons and positrons in later phases of LEP. Below: a small 1 GHz cavity used for investigating the surface problems of superconducting niobium. Albert Insomby stays on the right. See Annual Report 1983 p. 51.

  9. SPS accelerating cavity

    CERN Multimedia

    1980-01-01

    One of the SPS acceleration cavities (200 MHz, travelling wave structure). On the ceiling one sees the coaxial transmission line which feeds the power from the amplifier, located in a surface building above, to the upstream end of the cavity. See 7603195 for more details, 7411032 for the travelling wave structure, and also 8104138, 8302397.

  10. Superconducting RF cavities

    CERN Document Server

    Bernard, Philippe

    1999-01-01

    It was 20 years ago when the research and development programme for LEP superconducting cavities was initiated. It lasted about 10 years. Today, my aim is not to tell you in great detail about the many innovations made thanks to our research, but I would like to point out some milestones in the development of superconducting cavities where Emilio's influence was particularly important.

  11. SPS accelerating cavity

    CERN Multimedia

    CERN PhotoLab

    1981-01-01

    One of the SPS accelerating cavities (200 MHz, travelling wave structure). The power that is fed into the upstream end of the cavity is extracted at the downstream end and sent into a dump load. See 7603195 for more details, 7411032 for the travelling wave structure, and also 8011289, 8302397.

  12. Ferrite loaded rf cavity

    International Nuclear Information System (INIS)

    The mechanism of a ferrite-loaded rf cavity is explained from the point of view of its operation. Then, an analysis of the automatic cavity-tuning system is presented using the transfer function; and a systematic analysis of a beam-feedback system using transfer functions is also presented. (author)

  13. Passivated niobium cavities

    Science.gov (United States)

    Myneni, Ganapati Rao; Hjorvarsson, Bjorgvin; Ciovati, Gianluigi

    2006-12-19

    A niobium cavity exhibiting high quality factors at high gradients is provided by treating a niobium cavity through a process comprising: 1) removing surface oxides by plasma etching or a similar process; 2) removing hydrogen or other gases absorbed in the bulk niobium by high temperature treatment of the cavity under ultra high vacuum to achieve hydrogen outgassing; and 3) assuring the long term chemical stability of the niobium cavity by applying a passivating layer of a superconducting material having a superconducting transition temperature higher than niobium thereby reducing losses from electron (cooper pair) scattering in the near surface region of the interior of the niobium cavity. According to a preferred embodiment, the passivating layer comprises niobium nitride (NbN) applied by reactive sputtering.

  14. CRDS with a VECSEL for broad-band high sensitivity spectroscopy in the 2.3 μm window

    Science.gov (United States)

    Čermák, P.; Chomet, B.; Ferrieres, L.; Vasilchenko, S.; Mondelain, D.; Kassi, S.; Campargue, A.; Denet, S.; Lecocq, V.; Myara, M.; Cerutti, L.; Garnache, A.

    2016-08-01

    The integration of an industry ready packaged Sb-based Vertical-External-Cavity Surface-Emitting-Laser (VECSEL) into a Cavity Ring Down Spectrometer (CRDS) is presented. The instrument operates in the important 2.3 μm atmospheric transparency window and provides a high sensitivity (minimum detectable absorption of 9 × 10-11 cm-1) over a wide spectra range. The VECSEL performances combine a large continuous tunability over 120 cm-1 around 4300 cm-1 together with a powerful (˜5 mW) TEM00 diffraction limited beam and linewidth at MHz level (for 1 ms of integration time). The achieved performances are illustrated by high sensitivity recordings of the very weak absorption spectrum of water vapor in the region. The developed method gives potential access to the 2-2.7 μm range for CRDS.

  15. SPS RF Cavity

    CERN Multimedia

    1975-01-01

    The picture shows one of the two initially installed cavities. The main RF-system of the SPS comprises four cavities: two of 20 m length and two of 16.5 m length. They are all installed in one long straight section (LSS 3). These cavities are of the travelling-wave type operating at a centre frequency of 200.2 MHz. They are wideband, filling time about 700 ns and untuned. The power amplifiers, using tetrodes are installed in a surface building 200 m from the cavities. Initially only two cavities were installed, a third cavity was installed in 1978 and a forth one in 1979. The number of power amplifiers was also gradually increased: by end 1980 there were 8 500 kW units combined in pairs to feed each of the 4 cavities with up to about 1 MW RF power, resulting in a total accelerating voltage of about 8 MV. See also 7412017X, 7411048X, 7505074.

  16. SPS RF Accelerating Cavity

    CERN Multimedia

    1979-01-01

    This picture shows one of the 2 new cavities installed in 1978-1979. The main RF-system of the SPS comprises four cavities: two of 20 m length and two of 16.5 m length. They are all installed in one long straight section (LSS 3). These cavities are of the travelling-wave type operating at a centre frequency of 200.2 MHz. They are wideband, filling time about 700 ns and untuned. The power amplifiers, using tetrodes are installed in a surface building 200 m from the cavities. Initially only two cavities were installed, a third cavity was installed in 1978 and a forth one in 1979. The number of power amplifiers was also increased: to the first 2 MW plant a second 2 MW plant was added and by end 1979 there were 8 500 kW units combined in pairs to feed each of the 4 cavities with up to about 1 MW RF power, resulting in a total accelerating voltage of about 8 MV. See also 7412016X, 7412017X, 7411048X

  17. Hydroforming of elliptical cavities

    Science.gov (United States)

    Singer, W.; Singer, X.; Jelezov, I.; Kneisel, P.

    2015-02-01

    Activities of the past several years in developing the technique of forming seamless (weldless) cavity cells by hydroforming are summarized. An overview of the technique developed at DESY for the fabrication of single cells and multicells of the TESLA cavity shape is given and the major rf results are presented. The forming is performed by expanding a seamless tube with internal water pressure while simultaneously swaging it axially. Prior to the expansion the tube is necked at the iris area and at the ends. Tube radii and axial displacements are computer controlled during the forming process in accordance with results of finite element method simulations for necking and expansion using the experimentally obtained strain-stress relationship of tube material. In cooperation with industry different methods of niobium seamless tube production have been explored. The most appropriate and successful method is a combination of spinning or deep drawing with flow forming. Several single-cell niobium cavities of the 1.3 GHz TESLA shape were produced by hydroforming. They reached accelerating gradients Eacc up to 35 MV /m after buffered chemical polishing (BCP) and up to 42 MV /m after electropolishing (EP). More recent work concentrated on fabrication and testing of multicell and nine-cell cavities. Several seamless two- and three-cell units were explored. Accelerating gradients Eacc of 30 - 35 MV /m were measured after BCP and Eacc up to 40 MV /m were reached after EP. Nine-cell niobium cavities combining three three-cell units were completed at the company E. Zanon. These cavities reached accelerating gradients of Eacc=30 - 35 MV /m . One cavity is successfully integrated in an XFEL cryomodule and is used in the operation of the FLASH linear accelerator at DESY. Additionally the fabrication of bimetallic single-cell and multicell NbCu cavities by hydroforming was successfully developed. Several NbCu clad single-cell and double-cell cavities of the TESLA shape have been

  18. Long Wave Infrared Cavity Enhanced Sensors

    Energy Technology Data Exchange (ETDEWEB)

    Taubman, Matthew S.; Scott, David C.; Cannon, Bret D.; Myers, Tanya L.; Bonebrake, Christopher A.; Aker, Pam M.; Wojcik, Michael D.; Munley, John T.; Nguyen, Vinh T.; Schultz, John F.

    2004-10-01

    The principal goal of Pacific Northwest National Laboratory's (PNNL's) long wave infrared (LWIR) cavity enhanced sensor (CES) project is to explore ultra-sensitive spectroscopic techniques and apply them to the development of LWIR chemical sensors needed for detecting weapons proliferation. This includes detecting not only the weapons of mass destruction (WMDs) themselves, but also signatures of their production and/or detonation. The LWIR CES project is concerned exclusively with developing point sensors; other portions of PNNL's IR Sensors program address stand off detection. PNNL's LWIR CES research is distinguished from that done by others by the use quantum cascade lasers (QCLs) as the light source. QCLs are novel devices, and a significant fraction of our research has been devoted to developing the procedures and hardware required to implement them most effectively for chemical sensing. This report details the progress we have made on our LWIR CES sensor development. During FY02, PNNL investigated three LWIR CES implementations beginning with the easiest to implement, direct cavity-enhanced detection (simple CES), including a technique of intermediate difficulty, cavity-dithered phase-sensitive detection (FM recovery CES) through to the most complex technique, that of resonant sideband cavity-enhanced detection also known as noise-immune cavity-enhanced optical heterodyne molecular spectroscopy, or NICE-OHMS.

  19. Cavity Optomechanics at Millikelvin Temperatures

    Science.gov (United States)

    Meenehan, Sean Michael

    mechanical frequency of these systems allows for the possibility of using a dilution refrigerator to simultaneously achieve low thermal occupancy and long mechanical coherence time by passively cooling the device to the millikelvin regime. This thesis describes efforts to realize the measurement of OMC cavities inside a dilution refrigerator, including the development of fridge-compatible optical coupling schemes and the characterization of the heating dynamics of the mechanical resonator at sub-kelvin temperatures. We will begin by summarizing the theoretical framework used to describe cavity optomechanical systems, as well as a handful of the quantum applications envisioned for such devices. Then, we will present background on the design of the nanobeam OMC cavities used for this work, along with details of the design and characterization of tapered fiber couplers for optical coupling inside the fridge. Finally, we will present measurements of the devices at fridge base temperatures of Tf = 10 mK, using both heterodyne spectroscopy and time-resolved sideband photon counting, as well as detailed analysis of the prospects for future quantum applications based on the observed optically-induced heating.

  20. SPS accelerating cavity

    CERN Multimedia

    1983-01-01

    See photo 8202397: View towards the downstream end of one of the SPS accelerating cavities (200 MHz, travelling wave structure). See 7603195 and 8011289 for more details, 7411032 for the travelling wave structure, and also 8104138.

  1. SPS accelerating cavity

    CERN Multimedia

    1983-01-01

    View towards the downstream end of one of the SPS accelerating cavities (200 MHz, travelling wave structure). See 7603195 and 8011289 for more details, 7411032 for the travelling wave structure, and also 8104138.

  2. Moving Detectors in Cavities

    CERN Document Server

    Obadia, N

    2007-01-01

    We consider two-level detectors, coupled to a quantum scalar field, moving inside cavities. We highlight some pathological resonant effects due to abrupt boundaries, and decide to describe the cavity by switching smoothly the interaction by a time-dependent gate-like function. Considering uniformly accelerated trajectories, we show that some specific choices of non-adiabatic switching have led to hazardous interpretations about the enhancement of the Unruh effect in cavities. More specifically, we show that the emission/absorption ratio takes arbitrary high values according to the emitted quanta properties and to the transients undergone at the entrance and the exit of the cavity, {\\it independently of the acceleration}. An explicit example is provided where we show that inertial and uniformly accelerated world-lines can even lead to the same ``pseudo-temperature''.

  3. accelerating cavity from LEP

    CERN Multimedia

    This is an accelerating cavity from LEP, with a layer of niobium on the inside. Operating at 4.2 degrees above absolute zero, the niobium is superconducting and carries an accelerating field of 6 million volts per metre with negligible losses. Each cavity has a surface of 6 m2. The niobium layer is only 1.2 microns thick, ten times thinner than a hair. Such a large area had never been coated to such a high accuracy. A speck of dust could ruin the performance of the whole cavity so the work had to be done in an extremely clean environment. These challenging requirements pushed European industry to new achievements. 256 of these cavities are now used in LEP to double the energy of the particle beams.

  4. SPS accelerating cavity

    CERN Multimedia

    1976-01-01

    The SPS started up with 2 accelerating cavities (each consisting of 5 tank sections) in LSS3. They have a 200 MHz travelling wave structure (see 7411032 and 7802190) and 750 kW of power is fed to each of the cavities from a 1 MW tetrode power amplifier, located in a surface building above, via a coaxial transmission line. Clemens Zettler, builder of the SPS RF system, is standing at the side of one of the cavities. In 1978 and 1979 another 2 cavities were added and entered service in 1980. These were part of the intensity improvement programme and served well for the new role of the SPS as proton-antiproton collider. See also 7411032, 8011289, 8104138, 8302397.

  5. Hydroforming of Elliptical Cavities

    OpenAIRE

    W. Singer; Singer, X.; Jelezov, I.; Kneisel, P.

    2015-01-01

    Activities of the past several years in developing the technique of forming seamless (weldless) cavity cells by hydroforming are summarized. An overview of the technique developed at DESY for the fabrication of single cells and multicells of the TESLA cavity shape is given and the major rf results are presented. The forming is performed by expanding a seamless tube with internal water pressure while simultaneously swaging it axially. Prior to the expansion the tube is necked at the iris area ...

  6. Hybrid vertical cavity laser

    DEFF Research Database (Denmark)

    Chung, Il-Sug; Mørk, Jesper

    2010-01-01

    A new hybrid vertical cavity laser structure for silicon photonics is suggested and numerically investigated. It incorporates a silicon subwavelength grating as a mirror and a lateral output coupler to a silicon ridge waveguide.......A new hybrid vertical cavity laser structure for silicon photonics is suggested and numerically investigated. It incorporates a silicon subwavelength grating as a mirror and a lateral output coupler to a silicon ridge waveguide....

  7. Cavity-enhanced Raman Microscopy of Individual Carbon Nanotubes

    CERN Document Server

    Hümmer, Thomas; Hofmann, Matthias S; Hänsch, Theodor W; Högele, Alexander; Hunger, David

    2015-01-01

    Raman spectroscopy reveals chemically specific information, and combined with imaging provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here we use a tunable high-finesse optical microcavity to demonstrate Purcell enhancement of Raman scattering in combination with high-resolution scanning-cavity imaging. We detect cavity-enhanced Raman spectra of individual single-walled carbon nanotubes, expand the technique to hyperspectral imaging, and co-localize measurements with cavity-enhanced absorption microscopy. Direct comparison with confocal Raman microscopy yields a 550-times enhanced collectable Raman scattering spectral density and a 11-fold enhancement of the integrated count rate. The quantitative character, the inherent spectral filtering, and the absence of intrinsic background in cavity-vacuum stimulated Raman scattering renders our technique a promising tool for molecular imaging. Furthermore, cavity-enhanced Raman tran...

  8. Decreased vibrational susceptibility of Fabry-Perot cavities via designs of geometry and structural support

    Institute of Scientific and Technical Information of China (English)

    Yang Tao; Li Wen-Bo; Zang Er-Jun; Chen Li-Sheng

    2007-01-01

    Ultra-stable optical cavities are widely used for laser frequency stabilization. In these experiments the laser performance relies on the length stability of the Fabry-Perot cavities. Vibration-induced deformation is one of the dominant factors that affect the stability of ultra-stable optical cavities. We have quantitatively analysed the elastic deformation of Fabry-Perot cavities with various shapes and mounting configurations. Our numerical result facilitates a novel approach for the design of ultra-stable cavities that are insensitive to vibrational perturbations. This approach can be applied to many experiments such as laser frequency stabilization, high-precision laser spectroscopy, and optical frequency standards.

  9. Perturbative corrections to photon coincidence spectroscopy

    OpenAIRE

    Horvath, L.; Sanders, B. C.

    2000-01-01

    Photon coincidence spectroscopy is a promising technique for probing the nonlinear regime of cavity quantum electrodynamics in the optical domain, however its accuracy is mitigated by two factors: higher-order photon correlations, which contribute to an enhanced pair count rate, and non-simultaneity of emitted photon pairs from the optical cavity. We show that the technique of photon coincidence spectroscopy is effective in the presence of these effects if the quantitative predictions are adj...

  10. Metasurface external cavity laser

    Science.gov (United States)

    Xu, Luyao; Curwen, Christopher A.; Hon, Philip W. C.; Chen, Qi-Sheng; Itoh, Tatsuo; Williams, Benjamin S.

    2015-11-01

    A vertical-external-cavity surface-emitting-laser is demonstrated in the terahertz range, which is based upon an amplifying metasurface reflector composed of a sub-wavelength array of antenna-coupled quantum-cascade sub-cavities. Lasing is possible when the metasurface reflector is placed into a low-loss external cavity such that the external cavity—not the sub-cavities—determines the beam properties. A near-Gaussian beam of 4.3° × 5.1° divergence is observed and an output power level >5 mW is achieved. The polarized response of the metasurface allows the use of a wire-grid polarizer as an output coupler that is continuously tunable.

  11. Metasurface external cavity laser

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Luyao, E-mail: luyaoxu.ee@ucla.edu; Curwen, Christopher A.; Williams, Benjamin S. [Department of Electrical Engineering, University of California, Los Angeles, California 90095 (United States); California NanoSystems Institute, University of California, Los Angeles, California 90095 (United States); Hon, Philip W. C.; Itoh, Tatsuo [Department of Electrical Engineering, University of California, Los Angeles, California 90095 (United States); Chen, Qi-Sheng [Northrop Grumman Aerospace Systems, Redondo Beach, California 90278 (United States)

    2015-11-30

    A vertical-external-cavity surface-emitting-laser is demonstrated in the terahertz range, which is based upon an amplifying metasurface reflector composed of a sub-wavelength array of antenna-coupled quantum-cascade sub-cavities. Lasing is possible when the metasurface reflector is placed into a low-loss external cavity such that the external cavity—not the sub-cavities—determines the beam properties. A near-Gaussian beam of 4.3° × 5.1° divergence is observed and an output power level >5 mW is achieved. The polarized response of the metasurface allows the use of a wire-grid polarizer as an output coupler that is continuously tunable.

  12. New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)

    Science.gov (United States)

    Affolter, S.; Fleitmann, D.; Leuenberger, M.

    2014-07-01

    A new online method to analyse water isotopes of speleothem fluid inclusions using a wavelength scanned cavity ring down spectroscopy (WS-CRDS) instrument is presented. This novel technique allows us simultaneously to measure hydrogen and oxygen isotopes for a released aliquot of water. To do so, we designed a new simple line that allows the online water extraction and isotope analysis of speleothem samples. The specificity of the method lies in the fact that fluid inclusions release is made on a standard water background, which mainly improves the δ D robustness. To saturate the line, a peristaltic pump continuously injects standard water into the line that is permanently heated to 140 °C and flushed with dry nitrogen gas. This permits instantaneous and complete vaporisation of the standard water, resulting in an artificial water background with well-known δ D and δ18O values. The speleothem sample is placed in a copper tube, attached to the line, and after system stabilisation it is crushed using a simple hydraulic device to liberate speleothem fluid inclusions water. The released water is carried by the nitrogen/standard water gas stream directly to a Picarro L1102-i for isotope determination. To test the accuracy and reproducibility of the line and to measure standard water during speleothem measurements, a syringe injection unit was added to the line. Peak evaluation is done similarly as in gas chromatography to obtain &delta D; and δ18O isotopic compositions of measured water aliquots. Precision is better than 1.5 ‰ for δ D and 0.4 ‰ for δ18O for water measurements for an extended range (-210 to 0 ‰ for δ D and -27 to 0 ‰ for δ18O) primarily dependent on the amount of water released from speleothem fluid inclusions and secondarily on the isotopic composition of the sample. The results show that WS-CRDS technology is suitable for speleothem fluid inclusion measurements and gives results that are comparable to the isotope ratio mass

  13. New on-line method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)

    Science.gov (United States)

    Affolter, S.; Fleitmann, D.; Leuenberger, M.

    2014-01-01

    A new online method to analyse water isotopes of speleothem fluid inclusions using a wavelength scanned cavity ring down spectroscopy (WS-CRDS) instrument is presented. This novel technique allows us to simultaneously measure hydrogen and oxygen isotopes for a released aliquot of water. To do so, we designed a new simple line that allows the on-line water extraction and isotope analysis of speleothem samples. The specificity of the method lies in the fact that fluid inclusions release is made on a standard water background, which mainly improves the δD reliability. To saturate the line, a peristaltic pump continuously injects standard water into the line that is permanently heated to 140 °C and flushed with dry nitrogen gas. This permits instantaneous and complete vaporisation of the standard water resulting in an artificial water background with well-known δD and δ18O values. The speleothem sample is placed into a copper tube, attached to the line and after system stabilisation is crushed using a simple hydraulic device to liberate speleothem fluid inclusions water. The released water is carried by the nitrogen/standard water gas stream directly to a Picarro L1102-i for isotope determination. To test the accuracy and reproducibility of the line and to measure standard water during speleothem measurements a syringe injection unit was added to the line. Peak evaluation is done similarly as in gas chromatography to obtain δD and δ18O isotopic composition of measured water aliquots. Precision is better than 1.5‰ for δD and 0.4‰ for δ18O for water measurement for an extended range (-210 to 0‰ for δD and -27 to 0‰ for δ18O) primarily dependent on the amount of water released from speleothem fluid inclusions and secondarily on the isotopic composition of the sample. The results show that WS-CRDS technology is suitable for speleothem fluid inclusion measurements and gives results that are comparable to Isotope Ratio Mass Spectrometry (IRMS) technique.

  14. Experimental investigation of cavity flows

    Energy Technology Data Exchange (ETDEWEB)

    Loeland, Tore

    1998-12-31

    This thesis uses LDV (Laser Doppler Velocimetry), PIV (Particle Image Velocimetry) and Laser Sheet flow Visualisation to study flow inside three different cavity configurations. For sloping cavities, the vortex structure inside the cavities is found to depend upon the flow direction past the cavity. The shape of the downstream corner is a key factor in destroying the boundary layer flow entering the cavity. The experimental results agree well with numerical simulations of the same geometrical configurations. The results of the investigations are used to find the influence of the cavity flow on the accuracy of the ultrasonic flowmeter. A method to compensate for the cavity velocities is suggested. It is found that the relative deviation caused by the cavity velocities depend linearly on the pipe flow. It appears that the flow inside the cavities should not be neglected as done in the draft for the ISO technical report on ultrasonic flowmeters. 58 refs., 147 figs., 2 tabs.

  15. Cavity Optomechnics with 150nm-thick GaAs Membrane

    DEFF Research Database (Denmark)

    Usami, K.; Melholt Nielsen, B.; Naesby, A.;

    2010-01-01

    semiconductor integrated devices further. To investigate the optomechanical properties of a fabricated 150nm-thick intrinsic GaAs membrane (1.3mm1.9mm) a 975nm-laser (below band gap) is used to probe the mechanical resonances via beam deflection method. An 810nmlaser (above band gap), which is mode......Optomechanical properties of 150nm-thick GaAs membrane are studied for exploring its potential use in membranein- the-middle approach of cavity optomechanics [1, 2]. GaAs posseses many interesting properties [3]; direct band gap transition, high mobility of electrons, and strong piezoelectric...... temperature. Up to 150kHz the Q products are measured to be nearly constant (around 31010Hz). From the ratio of the extrapolated intrinsic ring down time to that at 50W the cooling factor can be evaluated for each mode. For the fundamental mode it is found to be as large as 12 meaning that the effective...

  16. Plasma processing of superconducting radio frequency cavities

    Science.gov (United States)

    Upadhyay, Janardan

    The development of plasma processing technology of superconducting radio frequency (SRF) cavities not only provides a chemical free and less expensive processing method, but also opens up the possibility for controlled modification of the inner surfaces of the cavity for better superconducting properties. The research was focused on the transition of plasma etching from two dimensional flat surfaces to inner surfaces of three dimensional (3D) structures. The results could be applicable to a variety of inner surfaces of 3D structures other than SRF cavities. Understanding the Ar/Cl2 plasma etching mechanism is crucial for achieving the desired modification of Nb SRF cavities. In the process of developing plasma etching technology, an apparatus was built and a method was developed to plasma etch a single cell Pill Box cavity. The plasma characterization was done with the help of optical emission spectroscopy. The Nb etch rate at various points of this cavity was measured before processing the SRF cavity. Cylindrical ring-type samples of Nb placed on the inner surface of the outer wall were used to measure the dependence of the process parameters on plasma etching. The measured etch rate dependence on the pressure, rf power, dc bias, temperature, Cl2 concentration and diameter of the inner electrode was determined. The etch rate mechanism was studied by varying the temperature of the outer wall, the dc bias on the inner electrode and gas conditions. In a coaxial plasma reactor, uniform plasma etching along the cylindrical structure is a challenging task due to depletion of the active radicals along the gas flow direction. The dependence of etch rate uniformity along the cylindrical axis was determined as a function of process parameters. The formation of dc self-biases due to surface area asymmetry in this type of plasma and its variation on the pressure, rf power and gas composition was measured. Enhancing the surface area of the inner electrode to reduce the

  17. LEP superconducting cavity

    CERN Document Server

    1995-01-01

    Engineers work in a clean room on one of the superconducting cavities for the upgrade to the LEP accelerator, known as LEP-2. The use of superconductors allow higher electric fields to be produced so that higher beam energies can be reached.

  18. Melatonin and oral cavity.

    Science.gov (United States)

    Cengiz, Murat İnanç; Cengiz, Seda; Wang, Hom-Lay

    2012-01-01

    While initially the oral cavity was considered to be mainly a source of various bacteria, their toxins and antigens, recent studies showed that it may also be a location of oxidative stress and periodontal inflammation. Accordingly, this paper focuses on the involvement of melatonin in oxidative stress diseases of oral cavity as well as on potential therapeutic implications of melatonin in dental disorders. Melatonin has immunomodulatory and antioxidant activities, stimulates the proliferation of collagen and osseous tissue, and acts as a protector against cellular degeneration associated with aging and toxin exposure. Arising out of its antioxidant actions, melatonin protects against inflammatory processes and cellular damage caused by the toxic derivates of oxygen. As a result of these actions, melatonin may be useful as a coadjuvant in the treatment of certain conditions of the oral cavity. However, the most important effect of melatonin seems to result from its potent antioxidant, immunomodulatory, protective, and anticancer properties. Thus, melatonin could be used therapeutically for instance, locally, in the oral cavity damage of mechanical, bacterial, fungal, or viral origin, in postsurgical wounds caused by tooth extractions and other oral surgeries. Additionally, it can help bone formation in various autoimmunological disorders such as Sjorgen syndrome, in periodontal diseases, in toxic effects of dental materials, in dental implants, and in oral cancers.

  19. Melatonin and Oral Cavity

    Directory of Open Access Journals (Sweden)

    Murat İnanç Cengiz

    2012-01-01

    Full Text Available While initially the oral cavity was considered to be mainly a source of various bacteria, their toxins and antigens, recent studies showed that it may also be a location of oxidative stress and periodontal inflammation. Accordingly, this paper focuses on the involvement of melatonin in oxidative stress diseases of oral cavity as well as on potential therapeutic implications of melatonin in dental disorders. Melatonin has immunomodulatory and antioxidant activities, stimulates the proliferation of collagen and osseous tissue, and acts as a protector against cellular degeneration associated with aging and toxin exposure. Arising out of its antioxidant actions, melatonin protects against inflammatory processes and cellular damage caused by the toxic derivates of oxygen. As a result of these actions, melatonin may be useful as a coadjuvant in the treatment of certain conditions of the oral cavity. However, the most important effect of melatonin seems to result from its potent antioxidant, immunomodulatory, protective, and anticancer properties. Thus, melatonin could be used therapeutically for instance, locally, in the oral cavity damage of mechanical, bacterial, fungal, or viral origin, in postsurgical wounds caused by tooth extractions and other oral surgeries. Additionally, it can help bone formation in various autoimmunological disorders such as Sjorgen syndrome, in periodontal diseases, in toxic effects of dental materials, in dental implants, and in oral cancers.

  20. SPS accelerating cavity

    CERN Multimedia

    1983-01-01

    See photo 8302397: View from the downstream end of one of the SPS accelerating cavities (200 MHz, travelling wave structure). See 7603195 and 8011289 for more details, 7411032 for the travelling wave structure, and also 8104138. Giacomo Primadei stands on the left.

  1. Statistical electromagnetics: Complex cavities

    NARCIS (Netherlands)

    Naus, H.W.L.

    2008-01-01

    A selection of the literature on the statistical description of electromagnetic fields and complex cavities is concisely reviewed. Some essential concepts, for example, the application of the central limit theorem and the maximum entropy principle, are scrutinized. Implicit assumptions, biased choic

  2. Laser cavity modelling

    OpenAIRE

    Damakoa, I.; Audounet, J.; Bouyssou, G.; Vassilieff, G.

    1993-01-01

    Two approachs of modelling nonhomogeneous cavity laser are presented. They are based on the beam propagation method which allows the use of fast Fourier transform (FFT). The resulting procedures provide selfconsistent solutions to the Maxwell and diffusion equations. Results are given to illustrate the two methods.


  3. Niobium superconducting cavity

    CERN Multimedia

    1980-01-01

    This 5-cell superconducting cavity, made from bulk-Nb, stems from the period of general studies, not all directed towards direct use at LEP. This one is dimensioned for 1.5 GHz, the frequency used at CEBAF and also studied at Saclay (LEP RF was 352.2 MHz). See also 7908227, 8007354, 8209255, 8210054, 8312339.

  4. Implosion of the small cavity and large cavity cannonball targets

    International Nuclear Information System (INIS)

    Recent results of cannonball target implosion research are briefly reviewed with theoretical predictions for GEKKO XII experiments. The cannonball targets are classified into two types according to the cavity size ; small cavity and large cavity. The compression mechanisms of the two types are discussed. (author)

  5. Teleportation of Cavity Field States via Cavity QED

    CERN Document Server

    Guerra, E S

    2004-01-01

    In this article we discuss two schemes of teleportation of cavity field states. In the first scheme we consider cavities prepared in a coherent state and in the second scheme we consider cavities prepared in a superposition of zero and one Fock states.

  6. Seamless/bonded niobium cavities

    Science.gov (United States)

    Singer, W.

    2006-07-01

    Technological aspects and performance of seamless cavities produced by hydroforming are presented. Problems related to the fabrication of seamless cavities from bulk niobium are mainly solved thanks to the progress of the last years. The highest achieved accelerating gradients are comparable for both seamless and welded versions (ca. 40 MV/m) Nevertheless further development of seamless cavities is desirable in order to avoid the careful preparation of parts for welding and get reliable statistic. Fabrication of NbCu clad cavities from bimetallic tubes is an interesting option that gives new opportunity to the seamless technique. On the one hand it allows reducing the niobium costs contribution; on the other hand it increases the thermal stability of the cavity. The highest accelerating gradient achieved on seamless NbCu clad single cell cavities (ca. 40 MV/m) is comparable to the one reached on bulk Nb cavities. Fabrication of multi-cell NbCu cavities by hydroforming was recently proven.

  7. Changeability of Oral Cavity Environment

    OpenAIRE

    Surdacka, Anna; Strzyka³a, Krystyna; Rydzewska, Anna

    2007-01-01

    Objectives In dentistry, the results of in vivo studies on drugs, dental fillings or prostheses are routinely evaluated based on selected oral cavity environment parameters at specific time points. Such evaluation may be confounded by ongoing changes in the oral cavity environment induced by diet, drug use, stress and other factors. The study aimed to confirm oral cavity environment changeability. Methods 24 healthy individuals aged 20–30 had their oral cavity environment prepared by having p...

  8. Deep-UV Rayleigh scattering of N2, CH4 and SF6

    NARCIS (Netherlands)

    Ityaksov, D.; Linnartz, H.V.J.; Ubachs, W.M.G.

    2008-01-01

    Rayleigh scattering room temperature cross-section values of N2, CH4 and SF6 have been obtained between 198 and 270 nm by combining cavity ring-down spectroscopy (CRDS) and pressure ramp measurements. The experimental data have been fitted to a functional representation, describing the 1/4 like beha

  9. The IAGOS-core greenhouse gas package : a measurement system for continuous airborne observations of CO2, CH4, H2O and CO

    NARCIS (Netherlands)

    Filges, Annette; Gerbig, Christoph; Chen, Huilin; Franke, Harald; Klaus, Christoph; Jordan, Armin

    2015-01-01

    Within the framework of IAGOS-ERI (In-service Aircraft for a Global Observing System - European Research Infrastructure), a cavity ring-down spectroscopy (CRDS)-based measurement system for the autonomous measurement of the greenhouse gases (GHGs) CO2 and CH4, as well as CO and water vapour was desi

  10. Quantification of methane emissions from 15 Danish landfills using the mobile tracer dispersion method

    DEFF Research Database (Denmark)

    Mønster, Jacob; Samuelsson, Jerker; Kjeldsen, Peter;

    2015-01-01

    Whole-site methane emissions from 15 Danish landfills were assessed using a mobile tracer dispersion method with either Fourier transform infrared spectroscopy (FFIR), using nitrous oxide as a tracer gas, or cavity ring-down spectrometry (CRDS), using acetylene as a tracer gas. The landfills were...

  11. Rotationally resolved A(3)Sigma(-)(u)-X-3 Sigma(-)(g) spectrum of HC7H

    NARCIS (Netherlands)

    Wehres, N.; Zhao, D.; Ubachs, W.; Linnartz, H.

    2010-01-01

    The A(3)Sigma X--(u)3 Sigma(-)(g) electronic spectrum of the linear carbon chain radical HC7H has been recorded fully rotationally resolved. Cavity ring-down spectroscopy is used to record the origin band transition in direct absorption through a supersonically expanding planar plasma, discharging a

  12. Contribution of carbonyl photochemistry to aging of atmospheric secondary organic aerosol

    DEFF Research Database (Denmark)

    Mang, Stephen A.; Henricksen, Dana K.; Bateman, Adam P.;

    2008-01-01

    in situ by infrared cavity ring-down spectroscopy. A number of additional gas-phase products of SOA photodegradation were observed by gas chromatography, including methane, ethene, acetaldehyde, acetone, methanol, and I-butene. The absorption spectrum of SOA material collected onto CaF, windows was...

  13. External cavity diode laser around 657 nm

    Institute of Scientific and Technical Information of China (English)

    Desheng Lǖ (吕德胜); Kaikai Huang (黄凯凯); Fengzhi Wang (王凤芝); DonghaiYang (杨东海)

    2003-01-01

    Operating a laser diode in an external cavity, which provides frequency-selective feedback, is a very effective method to tune the laser frequency to a range far from its free running frequency. For the Ca atomic Ramsey spectroscopy experiment, we have constructed a 657-nm laser system based on the LittmanMetcalf configuration with a 660-nm commercial laser diode. Continuously 10-GHz tuning range was achieved with about 100-kHz spectral linewidth, measured with beat-note spectrum of two identical laser systems.

  14. Plasma Treatment of Single-Cell Niobium SRF Cavities

    Energy Technology Data Exchange (ETDEWEB)

    J. Upadhyay, M. Nikolić, S. Popović, L. Vušković, H.L. Phillips, A-M. Valente-Feliciano

    2011-03-01

    Superconducting radio frequency cavities of bulk Niobium are integral components of particle accelerators based on superconducting technology. Wet chemical processing is the commonly used procedure for impurities and surface defects removal and surface roughness improvement , both required to improve the RF performance of the cavity. We are studying plasma etching as an alternate technique to process these cavities. The uniformity of the plasma sheath at the inner wall of the cavity is one prerequisite for its uniform etching. We are developing electro-optic diagnostic techniques to assess the plasma uniformity. Multiple electro-optical probes are placed at different locations of the single cell cavity to diagnose the electrical and optical properties of the plasma. The electrical parameters are required to understand the kinetic nature of the plasma and the optical emission spectroscopy provides the spatial distribution of radicals in the plasma. The spatial variation of the plasma parameters inside the cavity and their effect on the etching of niobium samples placed at different locations in the cavity will be presented.

  15. Access cavity preparation.

    Science.gov (United States)

    Adams, N; Tomson, P L

    2014-03-01

    Each stage of root canal treatment should be carried out to the highest possible standard. The access cavity is arguably the most important technical stage, as subsequent preparation of the root canal(s) can be severely comprised if this is not well executed. Inadequate access can lead to canals being left untreated, poorly disinfected, difficult to shape and obturate, and may ultimately lead to the failure of the treatment. This paper highlights common features in root canal anatomy and outlines basic principles for locating root canals and producing a good access cavity. It also explores each phase of the preparation in detail and offers suggestions of instruments that have been specifically designed to overcome potential difficulties in the process. Good access design and preparation will result in an operative environment which will facilitate cleaning, shaping and obturation of the root canal system in order to maximise success.

  16. Colloquium: cavity optomechanics

    CERN Multimedia

    2011-01-01

    Monday 14 November 2011, 17:00 Ecole de Physique, Auditoire Stueckelberg Université de Genève Cavity optomechanics: controlling micro mechanical oscillators with laser light Prof. Tobias Kippenberg EPFL, Lausanne Laser light can be used to cool and to control trapped ions, atoms and molecules at the quantum level. This has lead to spectacular advances such as the most precise atomic clocks. An outstanding frontier is the control with lasers of nano- and micro-mechancial systems. Recent advances in cavity optomechanics have allowed such elementary control for the first time, enabling mechanical systems to be ground state cooled leading to readout with quantum limited sensitivity and permitting to explore new device concepts resulting from radiation pressure.  

  17. RF superconducting cavities

    CERN Document Server

    Kojima, Y

    1980-01-01

    The history and present activity in research on RF superconducting cavities in various countries are reviewed. The program of the July 1980 Karlsruhe workshop is reproduced and research activity in this field at Stanford HEPL and SLAC, Cornell, Oregon, Brookhaven, KEK (Japan), Weismann (Israel), Genoa, CERN and Karlsruhe (KfK) listed. The theoretical basis of surface resistance and intracavity magnetic field, multipacing and non-resonant electron loading are outlined. (20 refs).

  18. Graphene intracavity spaser absorption spectroscopy

    Science.gov (United States)

    Lozovik, Yu. E.; Nechepurenko, I. A.; Dorofeenko, A. V.

    2016-09-01

    We propose an intracavity plasmon absorption spectroscopy method based on graphene active plasmonics. It is shown that the plasmonic cavity contribution to the sensitivity is proportional to the quality factor Q of the graphene plasmonic cavity and reaches two orders of magnitude. The addition of gain medium into the cavity increases the sensitivity of method. Maximum sensitivity is reached in the vicinity of the plasmon generation threshold. The gain contribution to the sensitivity is proportional to Q1/2. The giant amplification of sensitivity in the graphene plasmon generator is associated with a huge path length, limited only by the decoherence processes. An analytical estimation of the sensitivity to loss caused by analyzed particles (molecules, nanoparticles, etc.) normalized by the single pass plasmon scheme is derived. Usage of graphene nanoflakes as plasmonic cavity allows a high spatial resolution to be reached, in addition to high sensitivity.

  19. 非相干光宽带腔增强吸收光谱技术应用于SO2弱吸收的测量%An Incoherent Broadband Optical Cavity Spectroscopy for Measuring Weak Absorption Cross Section of Sulfur Dioxide

    Institute of Scientific and Technical Information of China (English)

    段俊; 秦敏; 方武; 胡仁志; 卢雪; 沈兰兰; 王丹; 谢品华; 刘建国

    2016-01-01

    As a highly sensitive detection technology ,incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) have successfully measured a variety of trace gases .According to the principle of cavity enhanced absorption spectroscopy ,if the accurate concentration of the target gas ,the curve of the mirror reflectance ,effective absorption path length ,the light intensity of the absorbing gas and non-absorbing gas are known ,the absorption cross section of the absorption gas can be measured .The accurate measurements of absorption cross section are necessary for satellite retrievals of atmospheric trace gases and the atmos-pheric research .This paper describes an incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) instrument with 365 nm LED as the light source for measuring absorption cross section of SO2 from 357 to 385 nm which is arising from the spin-forbidden a3 B1 — X1 A1 transition .In comparison to the literature absorption cross section of SO 2 ,and correlation coeffi-cient r is 0.997 3 .The result shows the potential of the IBBCEAS system for measuring weak absorption cross section .%非相干光宽带腔增强吸收光谱作为高灵敏检测技术 ,已成功应用于多种大气痕量气体浓度的测量.根据腔增强吸收光谱技术测量原理可知 ,若已知测量气体准确浓度 ,镜片反射率随波长的变化曲线、有效吸收长度、光学腔内有无测量气体吸收前后的光辐射变化 ,可测量出待测气体的吸收截面.SO2 由于 a 3 B1 —X1 A1 自旋禁阻跃迁 ,在345~420 nm波段吸收截面较低(~10-22 cm2/molecule) ,其测量有一定难度 ,而准确的弱吸收截面对于卫星反演大气痕量气体浓度以及大气研究等方面均有重要意义.采用365 nm L ED光源的宽带腔增强吸收光谱实验装置测量357~385 nm波段范围SO2 的弱吸收 ,获得该波段SO2 弱吸收截面 ,并与已公开发表的SO2 吸收截面进行对比 ,相关系数 r为0. 997 3 ,验证

  20. Crab Cavities for Linear Colliders

    Energy Technology Data Exchange (ETDEWEB)

    Burt, G.; Ambattu, P.; Carter, R.; Dexter, A.; Tahir, I.; /Cockcroft Inst. Accel. Sci. Tech. /Lancaster U.; Beard, C.; Dykes, M.; Goudket, P.; Kalinin, A.; Ma, L.; McIntosh, P.; /Daresbury; Shulte, D.; /CERN; Jones, Roger M.; /Cockcroft Inst. Accel. Sci. Tech. /Manchester U.; Bellantoni, L.; Chase, B.; Church, M.; Khabouline, T.; Latina, A.; /Fermilab; Adolphsen, C.; Li, Z.; Seryi, Andrei; /SLAC

    2011-11-08

    Crab cavities have been proposed for a wide number of accelerators and interest in crab cavities has recently increased after the successful operation of a pair of crab cavities in KEK-B. In particular crab cavities are required for both the ILC and CLIC linear colliders for bunch alignment. Consideration of bunch structure and size constraints favour a 3.9 GHz superconducting, multi-cell cavity as the solution for ILC, whilst bunch structure and beam-loading considerations suggest an X-band copper travelling wave structure for CLIC. These two cavity solutions are very different in design but share complex design issues. Phase stabilisation, beam loading, wakefields and mode damping are fundamental issues for these crab cavities. Requirements and potential design solutions will be discussed for both colliders.

  1. Crab cavities for linear colliders

    CERN Document Server

    Burt, G; Carter, R; Dexter, A; Tahir, I; Beard, C; Dykes, M; Goudket, P; Kalinin, A; Ma, L; McIntosh, P; Shulte, D; Jones, Roger M; Bellantoni, L; Chase, B; Church, M; Khabouline, T; Latina, A; Adolphsen, C; Li, Z; Seryi, Andrei; Xiao, L

    2008-01-01

    Crab cavities have been proposed for a wide number of accelerators and interest in crab cavities has recently increased after the successful operation of a pair of crab cavities in KEK-B. In particular crab cavities are required for both the ILC and CLIC linear colliders for bunch alignment. Consideration of bunch structure and size constraints favour a 3.9 GHz superconducting, multi-cell cavity as the solution for ILC, whilst bunch structure and beam-loading considerations suggest an X-band copper travelling wave structure for CLIC. These two cavity solutions are very different in design but share complex design issues. Phase stabilisation, beam loading, wakefields and mode damping are fundamental issues for these crab cavities. Requirements and potential design solutions will be discussed for both colliders.

  2. ISR RF cavities

    CERN Multimedia

    1983-01-01

    In each ISR ring the radiofrequency cavities were installed in one 9 m long straight section. The RF system of the ISR had the main purpose to stack buckets of particles (most of the time protons)coming from the CPS and also to accelerate the stacked beam. The installed RF power per ring was 18 kW giving a peak accelerating voltage of 20 kV. The system had a very fine regulation feature allowing to lower the voltage down to 75 V in a smooth and well controlled fashion.

  3. Stabilization of an optical frequency comb to an external cavity

    OpenAIRE

    Rydberg, Olof

    2014-01-01

    The subject of this master's thesis is stabilizing a frequency comb laser to an external cavity using a couple of servo controllers. The aim of the project was to build a pair of servo controllers, replacing parts of the existing commercial and proprietary solution already in use. The system under control is an optical frequency comb, which is locked to an external cavity and is used for trace gas detection and spectroscopy. The comb is a broadband light source and needs to be locked to the e...

  4. Oral cavity eumycetoma

    Directory of Open Access Journals (Sweden)

    Gisele Alborghetti Nai

    2011-06-01

    Full Text Available Mycetoma is a pathological process in which eumycotic (fungal or actinomycotic causative agents from exogenous source produce grains. It is a localized chronic and deforming infectious disease of subcutaneous tissue, skin and bones. We report the first case of eumycetoma of the oral cavity in world literature. CASE REPORT: A 43-year-old male patient, complaining of swelling and fistula in the hard palate. On examination, swelling of the anterior and middle hard palate, with fistula draining a dark liquid was observed. The panoramic radiograph showed extensive radiolucent area involving the region of teeth 21-26 and the computerized tomography showed communication with the nasal cavity, suggesting the diagnosis of periapical cyst. Surgery was performed to remove the lesion. Histopathological examination revealed purulent material with characteristic grain. Gram staining for bacteria was negative and Grocott-Gomori staining for the detection of fungi was positive, concluding the diagnosis of eumycetoma. The patient was treated with ketoconazole for nine months, and was considered cured at the end of treatment. CONCLUSION: Histopathological examination, using histochemical staining, and direct microscopic grains examination can provide the distinction between eumycetoma and actinomycetoma accurately.

  5. Applications of cavity optomechanics

    Science.gov (United States)

    Metcalfe, Michael

    2014-09-01

    "Cavity-optomechanics" aims to study the quantum properties of mechanical systems. A common strategy implemented in order to achieve this goal couples a high finesse photonic cavity to a high quality factor mechanical resonator. Then, using feedback forces such as radiation pressure, one can cool the mechanical mode of interest into the quantum ground state and create non-classical states of mechanical motion. On the path towards achieving these goals, many near-term applications of this field have emerged. After briefly introducing optomechanical systems and describing the current state-of-the-art experimental results, this article summarizes some of the more exciting practical applications such as ultra-sensitive, high bandwidth accelerometers and force sensors, low phase noise x-band integrated microwave oscillators and optical signal processing such as optical delay-lines, wavelength converters, and tunable optical filters. In this rapidly evolving field, new applications are emerging at a fast pace, but this article concentrates on the aforementioned lab-based applications as these are the most promising avenues for near-term real-world applications. New basic science applications are also becoming apparent such as the generation of squeezed light, testing gravitational theories and for providing a link between disparate quantum systems.

  6. Using a high finesse optical resonator to provide a long light path for differential optical absorption spectroscopy: CE-DOAS

    OpenAIRE

    J. Meinen; J. Thieser; U. Platt; T. Leisner

    2008-01-01

    Cavity enhanced methods in absorption spectroscopy have seen a considerable increase in popularity during the past decade. Especially Cavity Enhanced Absorption Spectroscopy (CEAS) established itself in atmospheric trace gas detection by providing tens of kilometers of effective light path length using a cavity as short as 1 m. In this paper we report on the construction and testing of a compact and power efficient light emitting diode based broadband Cavity Enhanced Differential Optical Abso...

  7. Cavity coalescence in superplastic deformation

    Energy Technology Data Exchange (ETDEWEB)

    Stowell, M.J.; Livesey, D.W.; Ridley, N.

    1984-01-01

    An analysis of the probability distribution function of particles randomly dispersed in a solid has been applied to cavitation during superplastic deformation and a method of predicting cavity coalescence developed. Cavity size distribution data were obtained from two microduplex nickel-silver alloys deformed superplastically to various extents at elevated temperature, and compared to theoretical predictions. Excellent agreement occurred for small void sizes but the model underestimated the number of voids in the largest size groups. It is argued that the discrepancy results from a combination of effects due to non-random cavity distributions and to enhanced growth rates and incomplete spheroidization of the largest cavities.

  8. Surface state photonic bandgap cavities

    OpenAIRE

    Rahachou, A. I.; Zozoulenko, I. V.

    2005-01-01

    We propose and analyze a new type of a resonant high-Q cavity for lasing, sensing or filtering applications, which is based on a surface states of a finite photonic crystal. We demonstrate that such the cavity can have a Q factor comparable with that one of conventional photonic band-gap defect mode cavities. At the same time, the distinguished feature of the surface mode cavity is that it is situated directly at the surface of the photonic crystal. This might open up new possibilities for de...

  9. Nanofriction in Cavity Quantum Electrodynamics.

    Science.gov (United States)

    Fogarty, T; Cormick, C; Landa, H; Stojanović, Vladimir M; Demler, E; Morigi, Giovanna

    2015-12-01

    The dynamics of cold trapped ions in a high-finesse resonator results from the interplay between the long-range Coulomb repulsion and the cavity-induced interactions. The latter are due to multiple scatterings of laser photons inside the cavity and become relevant when the laser pump is sufficiently strong to overcome photon decay. We study the stationary states of ions coupled with a mode of a standing-wave cavity as a function of the cavity and laser parameters, when the typical length scales of the two self-organizing processes, Coulomb crystallization and photon-mediated interactions, are incommensurate. The dynamics are frustrated and in specific limiting cases can be cast in terms of the Frenkel-Kontorova model, which reproduces features of friction in one dimension. We numerically recover the sliding and pinned phases. For strong cavity nonlinearities, they are in general separated by bistable regions where superlubric and stick-slip dynamics coexist. The cavity, moreover, acts as a thermal reservoir and can cool the chain vibrations to temperatures controlled by the cavity parameters and by the ions' phase. These features are imprinted in the radiation emitted by the cavity, which is readily measurable in state-of-the-art setups of cavity quantum electrodynamics.

  10. Nanofriction in Cavity Quantum Electrodynamics.

    Science.gov (United States)

    Fogarty, T; Cormick, C; Landa, H; Stojanović, Vladimir M; Demler, E; Morigi, Giovanna

    2015-12-01

    The dynamics of cold trapped ions in a high-finesse resonator results from the interplay between the long-range Coulomb repulsion and the cavity-induced interactions. The latter are due to multiple scatterings of laser photons inside the cavity and become relevant when the laser pump is sufficiently strong to overcome photon decay. We study the stationary states of ions coupled with a mode of a standing-wave cavity as a function of the cavity and laser parameters, when the typical length scales of the two self-organizing processes, Coulomb crystallization and photon-mediated interactions, are incommensurate. The dynamics are frustrated and in specific limiting cases can be cast in terms of the Frenkel-Kontorova model, which reproduces features of friction in one dimension. We numerically recover the sliding and pinned phases. For strong cavity nonlinearities, they are in general separated by bistable regions where superlubric and stick-slip dynamics coexist. The cavity, moreover, acts as a thermal reservoir and can cool the chain vibrations to temperatures controlled by the cavity parameters and by the ions' phase. These features are imprinted in the radiation emitted by the cavity, which is readily measurable in state-of-the-art setups of cavity quantum electrodynamics. PMID:26684118

  11. A Scanning Cavity Microscope

    CERN Document Server

    Mader, Matthias; Hänsch, Theodor W; Hunger, David

    2014-01-01

    Imaging of the optical properties of individual nanosystems beyond fluorescence can provide a wealth of information. However, the minute signals for absorption and dispersion are challenging to observe, and only specialized techniques requiring sophisticated noise rejection are available. Here we use signal enhancement in a scanning optical microcavity to demonstrate ultra-sensitive imaging. Harnessing multiple interactions of probe light with a sample within an optical resonator, we achieve a 1700-fold signal enhancement compared to diffraction-limited microscopy. We demonstrate quantitative imaging of the extinction cross section of gold nanoparticles with a sensitivity below 1 nm2, we show a method to improve spatial resolution potentially below the diffraction limit by using higher order cavity modes, and we present measurements of the birefringence and extinction contrast of gold nanorods. The demonstrated simultaneous enhancement of absorptive and dispersive signals promises intriguing potential for opt...

  12. Frequency Tuning for a DQW Crab Cavity

    CERN Document Server

    Verdú-Andrés, Silvia; Ben-Zvi, Ilan; Calaga, Rama; Capatina, Ofelia; Leuxe, Raphael; Skaritka, John; Wu, Qiong; Xiao, Binping; Zanoni, Carlo

    2016-01-01

    The nominal operating frequency for the HL-LHC crab cavities is 400.79 MHz within a bandwidth of ±60kHz. Attaining the required cavity tune implies a good understanding of all the processes that influence the cavity frequency from the moment when the cavity parts are being fabricated until the cavity is installed and under operation. Different tuning options will be available for the DQW crab cavity of LHC. This paper details the different steps in the cavity fabrication and preparation that may introduce a shift in the cavity frequency and introduces the different tuning methods foreseen to bring the cavity frequency to meet the specifications.

  13. Superconducting cavity model for LEP

    CERN Multimedia

    1979-01-01

    A superconducting cavity model is being prepared for testing in a vertical cryostat.At the top of the assembly jig is H.Preis while A.Scharding adjusts some diagnostic equipment to the cavity. See also photo 7912501X.

  14. Fiber cavities for atom chips

    OpenAIRE

    Klappauf, B.G.; Horak, P.; Kazansky, P. G.

    2003-01-01

    We present experimental realizations of several micro-cavities, constructed from standard fiber optic components, which meet the theoretical criteria for single atom detection from laser-cooled samples. We discuss integration of these cavities into state-of-the-art 'atom chips'.

  15. Technical tasks in superconducting cavities

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Kenji [High Energy Accelerator Research Organization, Tsukuba, Ibaraki (Japan)

    1997-11-01

    The feature of superconducting rf cavities is an extremely small surface resistance on the wall. It brings a large energy saving in the operation, even those are cooled with liquid helium. That also makes possible to operate themselves in a higher field gradient comparing to normal conducting cavities, and brings to make accelerators compact. These merits are very important for the future accelerator engineering which is planed at JAERI for the neutron material science and nuclear waste transmutation. This machine is a high intensity proton linac and uses sc cavities in the medium and high {beta} sections. In this paper, starting R and D of proton superconducting cavities, several important technical points which come from the small surface resistance of sc cavities, are present to succeed it and also differences between the medium and high - {beta} structures are discussed. (author)

  16. Mechanical Properties of Niobium Cavities

    Energy Technology Data Exchange (ETDEWEB)

    Ciovati, Gianluigi [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Dhakal, Pashupati [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Matalevich, Joseph R. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Myneni, Ganapati Rao [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)

    2015-09-01

    The mechanical stability of bulk Nb cavity is an important aspect to be considered in relation to cavity material, geometry and treatments. Mechanical properties of Nb are typically obtained from uniaxial tensile tests of small samples. In this contribution we report the results of measurements of the resonant frequency and local strain along the contour of single-cell cavities made of ingot and fine-grain Nb of different purity subjected to increasing uniform differential pressure, up to 6 atm. Measurements have been done on cavities subjected to different heat treatments. Good agreement between finite element analysis simulations and experimental data in the elastic regime was obtained with a single set of values of Young’s modulus and Poisson’s ratio. The experimental results indicate that the yield strength of medium-purity ingot Nb cavities is higher than that of fine-grain, high-purity Nb.

  17. Cavity-enhanced Raman microscopy of individual carbon nanotubes

    Science.gov (United States)

    Hümmer, Thomas; Noe, Jonathan; Hofmann, Matthias S.; Hänsch, Theodor W.; Högele, Alexander; Hunger, David

    2016-07-01

    Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement of Raman scattering in a tunable high-finesse microcavity, and utilize it for molecular diagnostics by combined Raman and absorption imaging. Studying individual single-wall carbon nanotubes, we identify crucial structural parameters such as nanotube radius, electronic structure and extinction cross-section. We observe a 320-times enhanced Raman scattering spectral density and an effective Purcell factor of 6.2, together with a collection efficiency of 60%. Potential for significantly higher enhancement, quantitative signals, inherent spectral filtering and absence of intrinsic background in cavity-vacuum stimulated Raman scattering render the technique a promising tool for molecular imaging. Furthermore, cavity-enhanced Raman transitions involving localized excitons could potentially be used for gaining quantum control over nanomechanical motion and open a route for molecular cavity optomechanics.

  18. H1 photonic crystal cavities for hybrid quantum information protocols

    Science.gov (United States)

    Hagemeier, Jenna; Bonato, Cristian; Truong, Tuan-Anh; Kim, Hyochul; Beirne, Gareth J.; Bakker, Morten; van Exter, Martin P.; Luo, Yunqiu; Petroff, Pierre; Bouwmeester, Dirk

    2012-10-01

    Hybrid quantum information protocols are based on local qubits, such as trapped atoms, NV centers, and quantum dots, coupled to photons. The coupling is achieved through optical cavities. Here we demonstrate far-field optimized H1 photonic crystal membrane cavities combined with an additional back reflection mirror below the membrane that meet the optical requirements for implementing hybrid quantum information protocols. Using numerical optimization we find that 80% of the light can be radiated within an objective numerical aperture of 0.8, and the coupling to a single-mode fiber can be as high as 92%. We experimentally prove the unique external mode matching properties by resonant reflection spectroscopy with a cavity mode visibility above 50%.

  19. Cavity-Enhanced Gas Analyzer for In-Situ Sampling of Biogenic Gases and Their Isotopes Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project concerns the novel application of cavity-enhanced absorption spectroscopy to quantify biogenic gases (CH4,...

  20. New developed cylindrical TM010 mode EPR cavity for X-band in vivo tooth dosimetry.

    Directory of Open Access Journals (Sweden)

    Guo Junwang

    Full Text Available EPR tooth in vivo dosimetry is an attractive approach for initial triage after unexpected nuclear events. An X-band cylindrical TM010 mode resonant cavity was developed for in vivo tooth dosimetry and used in EPR applications for the first time. The cavity had a trapezoidal measuring aperture at the exact position of the cavity's cylindrical wall where strong microwave magnetic field H1 concentrated and weak microwave electric field E1 distributed. Theoretical calculations and simulations were used to design and optimize the cavity parameters. The cavity features were evaluated by measuring DPPH sample, intact incisor samples embed in a gum model and the rhesus monkey teeth. The results showed that the cavity worked at designed frequency and had the ability to make EPR spectroscopy in relative high sensitivity. Sufficient modulation amplitude and microwave power could be applied into the aperture. Radiation induced EPR signal could be observed remarkably from 1 Gy irradiated intact incisor within only 30 seconds, which was among the best in scan time and detection limit. The in vivo spectroscopy was also realized by acquiring the radiation induced EPR signal from teeth of rhesus monkey whose teeth was irradiated by dose of 2 Gy. The results suggested that the cavity was sensitive to meet the demand to assess doses of significant level in short time. This cavity provided a very potential option for the development of X-band in vivo dosimetry.

  1. Development of a cavity enhanced aerosol albedometer

    Directory of Open Access Journals (Sweden)

    W. Zhao

    2014-03-01

    Full Text Available We report on the development of a cavity enhanced aerosol single scattering albedometer incorporating incoherent broad-band cavity-enhanced spectroscopy (IBBCEAS approach and an integrating sphere (IS for simultaneous in situ measurements of aerosol scattering and extinction coefficients in the exact same sample volume. The cavity enhanced albedometer employed a blue light-emitting diode (LED based IBBCEAS approach for the measurement of wavelength-resolved aerosol optical extinction over the spectral range of 445–480 nm. An integrating sphere nephelometer coupled to the IBBCEAS setup was used for the measurement of aerosol scattering. The scattering signal was measured with a single channel photomultiplier tube (PMT, providing an integrated value over a narrow bandwidth (FWHM ~ 9 nm in the spectral region of 465–474 nm. A scattering coefficient at a wavelength of 470 nm was deduced as an averaged scattering value and used for data analysis and instrumental performance comparison. Performance evaluation of the albedometer was carried out using laboratory-generated particles and ambient aerosol. The scattering and extinction measurements of monodisperse polystyrene latex (PSL spheres generated in laboratory proved excellent correlation between two channels of the albedometer. The retrieved refractive index (RI from the measured scattering and extinction efficiencies agreed well with the values reported in previously published papers. Aerosol light scattering and extinction coefficients, single scattering albedo (SSA and NO2 concentrations in an ambient sample were directly and simultaneously measured using the developed albedometer. The developed instrument was validated via an intercomparison of the measured aerosol scattering coefficient and NO2 trace concentration against a TSI 3563 integrating nephelometer and a chemiluminescence detector, respectively.

  2. Beam - cavity interaction beam loading

    International Nuclear Information System (INIS)

    The interaction of a beam with a cavity and a generator in cyclic accelerators or storage rings is investigated. Application of Maxwell's equations together with the nonuniform boundary condition allows one to get an equivalent circuit for a beam-loaded cavity. The general equation for beam loading is obtained on the basis of the equivalent circuit, and the beam admittance is calculated. Formulas for power consumption by a beam-loaded cavity are derived, and the optimal tuning and coupling factor are analyzed. (author)

  3. Geometry-Invariant Resonant Cavities

    CERN Document Server

    Liberal, Iñigo; Engheta, Nader

    2015-01-01

    Resonant cavities are one of the basic building blocks in various disciplines of science and technology, with numerous applications ranging from abstract theoretical modeling to everyday life devices. The eigenfrequencies of conventional cavities are a function of its geometry, and, thus, the size and shape of a resonant cavity is selected in order to operate at a specific frequency. Here, we demonstrate theoretically the existence of geometry-invariant resonant cavities, i.e., resonators whose eigenfrequency is invariant with respect to geometrical deformations. This effect is obtained by exploiting the unusual properties of zero-index metamaterials, which enable decoupling of the time and spatial field variations. This new class of resonators may inspire alternative design concepts, and it might lead to the first generation of deformable resonant devices.

  4. Vibration insensitive optical ring cavity

    Institute of Scientific and Technical Information of China (English)

    Miao Jin; Jiang Yan-Yi; Fang Su; Bi Zhi-Yi; Ma Long-Sheng

    2009-01-01

    The mounting configuration of an optical ring cavity is optimized for vibration insensitivity by finite element analysis. A minimum response to vertical accelerations is found by simulations made for different supporting positions.

  5. SRF Cavity Fabrication and Materials

    CERN Document Server

    Singer, W

    2014-01-01

    The technological and metallurgical requirements of material for highgradient superconducting cavities are described. High-purity niobium, as the preferred metal for the fabrication of superconducting accelerating cavities, should meet exact specifications. The content of interstitial impurities such as oxygen, nitrogen, and carbon must be below 10μg/g. The hydrogen content should be kept below 2μg/g to prevent degradation of the Q-value under certain cool-down conditions. The material should be free of flaws (foreign material inclusions or cracks and laminations) that can initiate a thermal breakdown. Defects may be detected by quality control methods such as eddy current scanning and identified by a number of special methods. Conventional and alternative cavity fabrication methods are reviewed. Conventionally, niobium cavities are fabricated from sheet niobium by the formation of half-cells by deep drawing, followed by trim machining and Electron-Beam Welding (EBW). The welding of half-cells is a delicate...

  6. Niobium LEP 2 accelerating cavities

    CERN Multimedia

    An accelerating cavity from LEP. This could be cut open to show the layer of niobium on the inside. Operating at 4.2 degrees above absolute zero, the niobium is superconducting and carries an accelerating field of 6 million volts per metre with negligible losses. Each cavity has a surface of 6 m2. The niobium layer is only 1.2 microns thick, ten times thinner than a hair. Such a large area had never been coated to such a high accuracy. A speck of dust could ruin the performance of the whole cavity so the work had to be done in an extremely clean environment. These challenging requirements pushed European industry to new achievements. 256 of these cavities were used in an upgrade of the LEP accelerator to double the energy of the particle beams.

  7. Miniaturization of Airborne Integrated Cavity Output Spectroscopy Instrument Project

    Data.gov (United States)

    National Aeronautics and Space Administration — New measurement technologies are required to support science campaigns to better quantify rapid changes in the Earth atmosphere system. A key factor in this...

  8. LEP Radio Frequency Copper Cavities

    CERN Multimedia

    The pulse of a particle accelerator. 128 of these radio frequency cavities were positioned around CERN's 27-kilometre LEP ring to accelerate electrons and positrons. The acceleration was produced by microwave electric oscillations at 352 MHz. The electrons and positrons were grouped into bunches, like beads on a string, and the copper sphere at the top stored the microwave energy between the passage of individual bunches. This made for valuable energy savings as it reduced the heat generated in the cavity.

  9. Technical Note: Using a high finesse optical resonator to provide a long light path for differential optical absorption spectroscopy: CE-DOAS

    OpenAIRE

    J. Meinen; J. Thieser; U. Platt; T. Leisner

    2010-01-01

    Cavity enhanced methods in absorption spectroscopy have seen a considerable increase in popularity during the past decade. Especially Cavity Enhanced Absorption Spectroscopy (CEAS) established itself in atmospheric trace gas detection by providing tens of kilometers of effective light path length using a cavity as short as 1 m. In this paper we report on the construction and testing of a compact and power efficient light emitting diode based broadband Cavity Enhanced Differential Optical Abso...

  10. TESLA superconducting RF cavity development

    Energy Technology Data Exchange (ETDEWEB)

    Koepke, K. [Fermi National Accelerator Lab., Batavia, IL (United States); TESLA Collaboration

    1995-05-01

    The TESLA collaboration has made steady progress since its first official meeting at Cornell in 1990. The infrastructure necessary to assemble and test superconducting rf cavities has been installed at the TESLA Test Facility (TTF) at DESY. 5-cell, 1.3 GHz cavities have been fabricated and have reached accelerating fields of 25 MV/m. Full sized 9-cell copper cavities of TESLA geometry have been measured to verify the higher order modes present and to evaluate HOM coupling designs. The design of the TESLA 9-cell cavity has been finalized and industry has started delivery. Two prototype 9-cell niobium cavities in their first tests have reached accelerating fields of 10 MV/m and 15 MV/m in a vertical dewar after high peak power (HPP) conditioning. The first 12 m TESLA cryomodule that will house 8 9-cell cavities is scheduled to be delivered in Spring 1995. A design report for the TTF is in progress. The TTF test linac is scheduled to be commissioned in 1996/1997. (orig.).

  11. Terahertz spectroscopy

    DEFF Research Database (Denmark)

    Jepsen, Peter Uhd

    2009-01-01

    In this presentation I will review methods for spectroscopy in the THz range, with special emphasis on the practical implementation of the technique known ad THz time-domain spectroscopy (THz-TDS). THz-TDS has revived the old field of far-infrared spectroscopy, and enabled a wealth of new...... activities that promise commercial potential for spectroscopic applications in the THz range. This will be illustrated with examples of spectroscopy of liquids inside their bottles as well as sensitive, quantitative spectroscopy in waveguides....

  12. Evaluation of MAX-DOAS aerosol retrievals by coincident observations using CRDS, lidar, and sky radiometer inTsukuba, Japan

    OpenAIRE

    Irie, H.; Nakayama, T.; Shimizu, A.; Yamazaki, A; Nagai, T; Uchiyama, A.; Y. Zaizen; Kagamitani, S.; Matsumi, Y.

    2015-01-01

    Coincident aerosol observations of multi-axis differential optical absorption spectroscopy (MAX-DOAS), cavity ring-down spectroscopy (CRDS), lidar, and sky radiometer were conducted in Tsukuba, Japan, on 5–18 October 2010. MAX-DOAS aerosol retrieval (for aerosol extinction coefficient and aerosol optical depth at 476 nm) was evaluated from the viewpoint of the need for a correction factor for oxygen collision complexes (O4 or O2–O2) absorption. The present study strongly sup...

  13. Evaluation of MAX-DOAS aerosol retrievals by coincident observations using CRDS, lidar, and sky radiometer in Tsukuba, Japan

    OpenAIRE

    Irie, H.; Nakayama, T.; Shimizu, A.; Yamazaki, A; Nagai, T; Uchiyama, A.; Y. Zaizen; Kagamitani, S.; Matsumi, Y.

    2015-01-01

    Coincident aerosol observations of Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), Cavity Ring Down Spectroscopy (CRDS), lidar, and sky radiometer were conducted in Tsukuba, Japan on 5–18 October 2010. MAX-DOAS aerosol retrieval (for aerosol extinction coefficient and aerosol optical depth at 476 nm) was evaluated from the viewpoint of the need for a correction factor for oxygen collision complexes (O4 or O2-O2) absorption. The present study strongly supp...

  14. 3D cavity detection technique and its application based on cavity auto scanning laser system

    Institute of Scientific and Technical Information of China (English)

    LIU Xi-ling; LI Xi-bing; LI Fa-ben; ZHAO Guo-yan; QIN Yu-hui

    2008-01-01

    Ground constructions and mines are severely threatened by underground cavities especially those unsafe or inaccessible ones. Safe and precise cavity detection is vital for reasonable cavity evaluation and disposal. The conventional cavity detection methods and their limitation were analyzed. Those methods cannot form 3D model of underground cavity which is used for instructing the cavity disposal; and their precisions in detection are always greatly affected by the geological circumstance. The importance of 3D cavity detection in metal mine for safe exploitation was pointed out; and the 3D cavity laser detection method and its principle were introduced. A cavity auto scanning laser system was recommended to actualize the cavity 3D detection after comparing with the other laser detection systems. Four boreholes were chosen to verify the validity of the cavity auto scanning laser system. The results show that the cavity auto scanning laser system is very suitable for underground 3D cavity detection, especially for those inaccessible ones.

  15. Normal Conducting RF Cavity for MICE

    International Nuclear Information System (INIS)

    Normal conducting RF cavities must be used for the cooling section of the international Muon Ionization Cooling Experiment (MICE), currently under construction at Rutherford Appleton Laboratory (RAL) in the UK. Eight 201-MHz cavities are needed for the MICE cooling section; fabrication of the first five cavities is complete. We report the cavity fabrication status including cavity design, fabrication techniques and preliminary low power RF measurements.

  16. Broadband Rotational Spectroscopy

    Science.gov (United States)

    Pate, Brooks

    2014-06-01

    The past decade has seen several major technology advances in electronics operating at microwave frequencies making it possible to develop a new generation of spectrometers for molecular rotational spectroscopy. High-speed digital electronics, both arbitrary waveform generators and digitizers, continue on a Moore's Law-like development cycle that started around 1993 with device bandwidth doubling about every 36 months. These enabling technologies were the key to designing chirped-pulse Fourier transform microwave (CP-FTMW) spectrometers which offer significant sensitivity enhancements for broadband spectrum acquisition in molecular rotational spectroscopy. A special feature of the chirped-pulse spectrometer design is that it is easily implemented at low frequency (below 8 GHz) where Balle-Flygare type spectrometers with Fabry-Perot cavity designs become technologically challenging due to the mirror size requirements. The capabilities of CP-FTMW spectrometers for studies of molecular structure will be illustrated by the collaborative research effort we have been a part of to determine the structures of water clusters - a project which has identified clusters up to the pentadecamer. A second technology trend that impacts molecular rotational spectroscopy is the development of high power, solid state sources in the mm-wave/THz regions. Results from the field of mm-wave chirped-pulse Fourier transform spectroscopy will be described with an emphasis on new problems in chemical dynamics and analytical chemistry that these methods can tackle. The third (and potentially most important) technological trend is the reduction of microwave components to chip level using monolithic microwave integrated circuits (MMIC) - a technology driven by an enormous mass market in communications. Some recent advances in rotational spectrometer designs that incorporate low-cost components will be highlighted. The challenge to the high-resolution spectroscopy community - as posed by Frank De

  17. Cavity as a source of conformational fluctuation and high-energy state: High-pressure NMR study of a cavity-enlarged mutant of T4 lysozyme

    CERN Document Server

    Maeno, Akihiro; Hirata, Fumio; Otten, Renee; Dahlquist, Frederick W; Yokoyama, Shigeyuki; Akasaka, Kazuyuki; Mulder, Frans A A; Kitahara, Ryo

    2014-01-01

    Although the structure, function, conformational dynamics, and controlled thermodynamics of proteins are manifested by their corresponding amino acid sequences, the natural rules for molecular design and their corresponding interplay remain obscure. In this study, we focused on the role of internal cavities of proteins in conformational dynamics. We investigated the pressure-induced responses from the cavity-enlarged L99A mutant of T4 lysozyme, using high-pressure NMR spectroscopy. The signal intensities of the methyl groups in the 1H/13C HSQC spectra, particularly those around the enlarged cavity, decreased with the increasing pressure, and disappeared at 200 MPa, without the appearance of new resonances, thus indicating the presence of heterogeneous conformations around the cavity within the ground state ensemble. Above 200 MPa, the signal intensities of more than 20 methyl groups gradually decreased with the increasing pressure, without the appearance of new resonances. Interestingly, these residues closel...

  18. RRR Characteristics for SRF Cavities

    CERN Document Server

    Jung, Yoochul; Joung, Mijoung

    2015-01-01

    The first heavy ion accelerator is being constructed by the rare isotope science project (RISP) launched by the Institute of Basic Science (IBS) in South Korea. Four different types of superconducting cavities were designed, and prototypes were fabricated such as a quarter wave resonator (QWR), a half wave resonator (HWR) and a single spoke resonator (SSR). One of the critical factors determining performances of the superconducting cavities is a residual resistance ratio (RRR). The RRR values essentially represent how much niobium is pure and how fast niobium can transmit heat as well. In general, the RRR degrades during electron beam welding due to the impurity incorporation. Thus it is important to maintain RRR above a certain value at which a niobium cavity shows target performance. In this study, RRR degradation related with electron beam welding conditions, for example, welding power, welding speed, and vacuum level will be discussed.

  19. RRR Characteristics for SRF cavities

    Science.gov (United States)

    Jung, Yoochul; Hyun, Myungook; Joung, Mijoung

    2015-10-01

    The first heavy ion accelerator is being constructed by the rare isotope science project (RISP) launched by the Institute of Basic Science (IBS) in South Korea. Four different types of superconducting cavities were designed, and prototypes such as a quarter-wave resonator (QWR), a half-wave resonator (HWR) and a single-spoke resonator (SSR) were fabricated. One of the critical factors determining the performances of superconducting cavities is the residual resistance ratio (RRR). The RRR values essentially represent how pure niobium is and how fast niobium can transmit heat. In general, the RRR degrades during electron beam welding due to impurity incorporation. Thus, it is important to maintain the RRR above a certain value at which a niobium cavity shows target performance. In this study, RRR degradation related with electron beam welding conditions, for example, the welding power, welding speed, and vacuum level, will be discussed.

  20. Cavity QED with atomic mirrors

    CERN Document Server

    Chang, D E; Gorhskov, A V; Kimble, H J

    2012-01-01

    A promising approach to merge atomic systems with scalable photonics has emerged recently, which consists of trapping cold atoms near tapered nanofibers. Here, we describe a novel technique to achieve strong, coherent coupling between a single atom and photon in such a system. Our approach makes use of collective enhancement effects, which allow a lattice of atoms to form a high-finesse cavity within the fiber. We show that a specially designated "impurity" atom within the cavity can experience strongly enhanced interactions with single photons in the fiber. Under realistic conditions, a "strong coupling" regime can be reached, wherein it becomes feasible to observe vacuum Rabi oscillations between the excited impurity atom and a cavity photon. This technique can form the basis for a scalable quantum information network using atom-nanofiber systems.

  1. Dual-cavity basket promotes encapsulation in water in an allosteric fashion.

    Science.gov (United States)

    Chen, Shigui; Yamasaki, Makoto; Polen, Shane; Gallucci, Judith; Hadad, Christopher M; Badjić, Jovica D

    2015-09-30

    We prepared dual-cavity basket 1 to carry six (S)-alanine residues at the entrance of its two juxtaposed cavities (289 Å(3)). With the assistance of (1)H NMR spectroscopy and calorimetry, we found that 1 could trap a single molecule of 4 (K1 = 1.45 ± 0.40 × 10(4) M(-1), ITC), akin in size (241 Å(3)) and polar characteristics to nerve agent VX (289 Å(3)). The results of density functional theory calculations (DFT, M06-2X/6-31G*) and experiments ((1)H NMR spectroscopy) suggest that the negative homotropic allosterism arises from the guest forming C-H···π contacts with all three of the aromatic walls of the occupied basket's cavity. In response, the other cavity increases its size and turns rigid to prevent the formation of the ternary complex. A smaller guest 6 (180 Å(3)), akin in size and polar characteristics to soman (186 Å(3)), was also found to bind to dual-cavity 1, although giving both binary [1⊂6] and ternary [1⊂62] complexes (K1 = 7910 M(-1) and K2 = 2374 M(-1), (1)H NMR spectroscopy). In this case, the computational and experimental ((1)H NMR spectroscopy) results suggest that only two aromatic walls of the occupied basket's cavity form C-H···π contacts with the guest to render the singly occupied host flexible enough to undergo additional structural changes necessary for receiving another guest molecule. The structural adaptivity of dual-cavity baskets of type 1 is unique and important for designing multivalent hosts capable of effectively sequestering targeted guests in an allosteric manner to give stable supramolecular polymers. PMID:26348904

  2. Sterility of the uterine cavity

    DEFF Research Database (Denmark)

    Møller, Birger R.; Kristiansen, Frank V.; Thorsen, Poul;

    1995-01-01

    In a prospective open study the sterility of the uterine cavity was evaluated in 99 women admitted for hysterectomy. The indications for hysterectomy were in most cases persistent irregular vaginal bleeding and fibromyomas of the uterus. Samples for both aerobic and anaerobic bacteria, Chlamydia...... trachomatis, yeasts and viruses were taken preoperatively from the apex of the vagina and cervical os. Immediately after hysterectomy the uterus was opened under sterile conditions and samples obtained from the isthmus and fundus of the uterine cavity for microbiological examination. Wet smears were taken...

  3. Nanobeam Cavities for Reconfigurable Photonics

    OpenAIRE

    Deotare, Parag

    2012-01-01

    We investigate the design, fabrication, and experimental characterization of high quality factor photonic crystal nanobeam cavities, with theoretical quality factors of \\(1.4 × 10^7\\) in silicon, operating at ~1550 nm. By detecting the cross-polarized resonantly scattered light from a normally incident laser beam, we measure a quality factor of nearly \\(7.5 × 10^5\\). We show on-chip integration of the cavities using waveguides and an inverse taper geometry based mode size converters, and also...

  4. Synchronization in an optomechanical cavity.

    Science.gov (United States)

    Shlomi, Keren; Yuvaraj, D; Baskin, Ilya; Suchoi, Oren; Winik, Roni; Buks, Eyal

    2015-03-01

    We study self-excited oscillations (SEO) in an on-fiber optomechanical cavity. Synchronization is observed when the optical power that is injected into the cavity is periodically modulated. A theoretical analysis based on the Fokker-Planck equation evaluates the expected phase space distribution (PSD) of the self-oscillating mechanical resonator. A tomography technique is employed for extracting PSD from the measured reflected optical power. Time-resolved state tomography measurements are performed to study phase diffusion and phase locking of the SEO. The detuning region inside which synchronization occurs is experimentally determined and the results are compared with the theoretical prediction. PMID:25871175

  5. Cavity Solitons in VCSEL Devices

    Directory of Open Access Journals (Sweden)

    S. Barbay

    2011-01-01

    Full Text Available We review advances on the experimental study of cavity solitons in VCSELs in the past decade. We emphasize on the design and fabrication of electrically or optically pumped broad-area VCSELs used for CSs formation and review different experimental configurations. Potential applications of CSs in the field of photonics are discussed, in particular the use of CSs for all-optical processing of information and for VCSELs characterization. Prospects on self-localization studies based on vertical cavity devices involving new physical mechanisms are also given.

  6. Entanglement swapping between atom and cavity and generation of entangled state of cavity fields

    Institute of Scientific and Technical Information of China (English)

    Chen Ai-Xi; Deng Li

    2007-01-01

    This paper proposes a scheme where entanglement swapping between atom and cavity can be realized. A-type three-level atoms interacting resonantly with cavity field are considered. By detecting atom and cavity field, it realizes entanglement swapping between atom and cavity. It uses the technique of entanglement swapping to generate an entangled state of two cavity fields by measuring on atoms. It discusses the experimental feasibility of the proposed scheme and application of entangled state of cavity fields.

  7. Frequency comb velocity-modulation spectroscopy.

    Science.gov (United States)

    Sinclair, Laura C; Cossel, Kevin C; Coffey, Tyler; Ye, Jun; Cornell, Eric A

    2011-08-26

    We have demonstrated a new technique that provides massively parallel comb spectroscopy sensitive specifically to ions through the combination of cavity-enhanced direct frequency comb spectroscopy with velocity-modulation spectroscopy. Using this novel system, we have measured electronic transitions of HfF⁺ and achieved a fractional absorption sensitivity of 3×10⁻⁷ recorded over 1500 simultaneous channels spanning 150  cm⁻¹ around 800 nm with an absolute frequency accuracy of 30 MHz (0.001  cm⁻¹). A fully sampled spectrum consisting of interleaved measurements is acquired in 30 min.

  8. Frequency Comb Velocity-Modulation Spectroscopy

    CERN Document Server

    Sinclair, Laura C; Coffey, Tyler; Ye, Jun; Cornell, Eric A

    2011-01-01

    We have demonstrated a new technique that provides massively parallel comb spectroscopy sensitive specifically to ions through the combination of cavity-enhanced direct frequency comb spectroscopy with velocity modulation spectroscopy. Using this novel system, we have measured electronic transitions of HfF+ and achieved a fractional absorption sensitivity of 3 x 10-7 recorded over 1500 simultaneous channels spanning 150 cm-1 around 800 nm with an absolute frequency accuracy of 30 MHz (0.001 cm-1). A fully sampled spectrum consisting of interleaved measurements is acquired in 30 minutes.

  9. Chemical spectroscopy

    International Nuclear Information System (INIS)

    The purpose of chemical spectroscopy with neutrons is to utilize the dependence of neutron scattering cross-sections on isotope and on momentum transfer (which probes the spatial extent of the excitation) to understand fundamental and applied aspects of the dynamics of molecules and fluids. Chemical spectroscopy is divided into three energy ranges: vibrational spectroscopy, 25-500 MeV, for which much of the work is done on Be-filter analyzer instruments; low energy spectroscopy, less than 25 MeV; and high resolution spectroscopy, less than 1 MeV, which typically is performed on backscattering spectrometers. Representative examples of measurements of the Q-depenence of vibrational spectra, higher energy resolution as well as extension of the Q-range to lower values at high energy transfers, and provisions of higher sensitivities in vibrational spectroscopy are discussed. High resolution, high sensitivity, and polarization analysis studies in low energy spectroscopy are discussed. Applications of very high resolution spectroscopy are also discussed

  10. Droplet based cavities and lasers

    DEFF Research Database (Denmark)

    Mølhave, Kristian; Kristensen, Anders; Mortensen, Asger

    2009-01-01

    The self-organized and molecularly smooth surface on liquid microdroplets makes them attractive as optical cavities with very high quality factors. This chapter describes the basic theory of optical modes in spherical droplets. The mechanical properties including vibrational excitation are also d...

  11. Cavity length below chute aerators

    Institute of Scientific and Technical Information of China (English)

    WU JianHua; RUAN ShiPing

    2008-01-01

    It is proved that air entrainment is one of the efficient measures dealing with cavitation control for the release works of hydropower projects. There are many factors to be considered in designing a chute aerator. One of the most important factors concerns the cavity length below the aerator, which has outstanding effects on air entrainment against cavitation damage. It is crucial to determine reasonable emergence angle for the calculation of the cavity length. In the present paper the overall effects of structural and hydraulic parameters on the emergence angle of the flow from the aerator were analyzed. Four improved expressions of the emergence angle with weight coefficient were investigated through experimental data of 68 points observed from 12 aerators of 6 hydropower projects, of both model and prototype, on the basis of error theory. A method to calculate the cavity length below aerators was suggested, which considers overall effects of the above mentioned parameters. Comparison between the method in this paper and the other five methods of calculating the cavity length showed that the present method is much more reliable than the existing methods while the mean error of the method is less than others.

  12. Cavity length below chute aerators

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    It is proved that air entrainment is one of the efficient measures dealing with cavi-tation control for the release works of hydropower projects. There are many factors to be considered in designing a chute aerator. One of the most important factors concerns the cavity length below the aerator,which has outstanding effects on air entrainment against cavitation damage. It is crucial to determine reasonable emergence angle for the calculation of the cavity length. In the present paper the overall effects of structural and hydraulic parameters on the emergence angle of the flow from the aerator were analyzed. Four improved expressions of the emer-gence angle with weight coefficient were investigated through experimental data of 68 points observed from 12 aerators of 6 hydropower projects,of both model and prototype,on the basis of error theory. A method to calculate the cavity length be-low aerators was suggested,which considers overall effects of the above men-tioned parameters. Comparison between the method in this paper and the other five methods of calculating the cavity length showed that the present method is much more reliable than the existing methods while the mean error of the method is less than others.

  13. Large-mode enhancement cavities.

    Science.gov (United States)

    Carstens, Henning; Holzberger, Simon; Kaster, Jan; Weitenberg, Johannes; Pervak, Volodymyr; Apolonski, Alexander; Fill, Ernst; Krausz, Ferenc; Pupeza, Ioachim

    2013-05-01

    In passive enhancement cavities the achievable power level is limited by mirror damage. Here, we address the design of robust optical resonators with large spot sizes on all mirrors, a measure that promises to mitigate this limitation by decreasing both the intensity and the thermal gradient on the mirror surfaces. We introduce a misalignment sensitivity metric to evaluate the robustness of resonator designs. We identify the standard bow-tie resonator operated close to the inner stability edge as the most robust large-mode cavity and implement this cavity with two spherical mirrors with 600 mm radius of curvature, two plane mirrors and a round trip length of 1.2 m, demonstrating a stable power enhancement of near-infrared laser light by a factor of 2000. Beam radii of 5.7 mm × 2.6 mm (sagittal × tangential 1/e(2) intensity radius) on all mirrors are obtained. We propose a simple all-reflective ellipticity compensation scheme. This will enable a significant increase of the attainable power and intensity levels in enhancement cavities. PMID:23670017

  14. Field emission in RF cavities

    Energy Technology Data Exchange (ETDEWEB)

    Bonin, B. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Astrophysique, de la Physique des Particules, de la Physique Nucleaire et de l`Instrumentation Associee

    1996-01-01

    Electron field emission limits the accelerating gradient in superconducting cavities. It is shown how and why it is an important problem. The phenomenology of field emission is then described, both in DC and RF regimes. Merits of a few plausible `remedies` to field emission are discussed. (author). 20 refs.

  15. Hybrid Vertical-Cavity Laser

    DEFF Research Database (Denmark)

    2010-01-01

    The present invention provides a light source (2) for light circuits on a silicon platform (3). A vertical laser cavity is formed by a gain region (101) arranged between a top mirror (4) and a bottom grating-mirror (12) in a grating region (11) in a silicon layer (10) on a substrate. A waveguide...

  16. A 200 MHz prebunching cavity

    CERN Multimedia

    1977-01-01

    This cavity was installed in the PS ring and proved very efficient in providing a modulation on the PS beam before it is injected into the SPS machine. Moreover it allowed longitudinal instabilities studies at high intensities. Roberto Cappi stands on the left.

  17. Toroid cavity/coil NMR multi-detector

    Science.gov (United States)

    Gerald, II, Rex E.; Meadows, Alexander D.; Gregar, Joseph S.; Rathke, Jerome W.

    2007-09-18

    An analytical device for rapid, non-invasive nuclear magnetic resonance (NMR) spectroscopy of multiple samples using a single spectrometer is provided. A modified toroid cavity/coil detector (TCD), and methods for conducting the simultaneous acquisition of NMR data for multiple samples including a protocol for testing NMR multi-detectors are provided. One embodiment includes a plurality of LC resonant circuits including spatially separated toroid coil inductors, each toroid coil inductor enveloping its corresponding sample volume, and tuned to resonate at a predefined frequency using a variable capacitor. The toroid coil is formed into a loop, where both ends of the toroid coil are brought into coincidence. Another embodiment includes multiple micro Helmholtz coils arranged on a circular perimeter concentric with a central conductor of the toroid cavity.

  18. Nanobeam cavities for Reconfigurable Photonics

    Science.gov (United States)

    Deotare, Parag B.

    We investigate the design, fabrication, and experimental characterization of high quality factor photonic crystal nanobeam cavities, with theoretical quality factors of 1.4 x 107 in silicon, operating at ˜ 1550 nm. By detecting the cross-polarized resonantly scattered light from a normally incident laser beam, we measure a quality factor of nearly 7.5 x 105. We show on-chip integration of the cavities using waveguides and an inverse taper geometry based mode size converters, and also demonstrate tuning of the optical resonance using thermo-optic effect. We also study coupled cavities and show that the single nanobeam cavity modes are coupled into even and odd superposition modes. Using electrostatic force and taking advantage of the highly dispersive nature of the even mode to the nanobeam separation, we demonstrate dynamically reconfigurable optical filters tunable continuously and reversibly over a 9.5 nm wavelength range. The electrostatic force, obtained by applying bias voltages directly to the nanobeams, is used to control the spacing between the nanobeams, which in turn results in tuning of the cavity resonance. The observed tuning trends were confirmed through simulations that modeled the electrostatic actuation as well as the optical resonances in our reconfigurable geometries. Finally we demonstrate reconfiguration of coupled cavities by using optical gradient force induced mechanical actuation. Propagating waveguide modes that exist over wide wavelength range are used to actuate the structures and in that way control the resonance of a localized cavity mode. Using this all-optical approach, more than 18 linewidths of tuning range is demonstrated. Using an on-chip temperature self-referencing method that we developed, we determined that 20% of the total tuning was due to optomechanical reconfiguration and the rest due to thermo-optic effects. By operating the device at frequencies higher than the thermal cut-off, we show high speed operation dominated by

  19. Surface analyses of electropolished niobium samples for superconducting radio frequency cavity

    International Nuclear Information System (INIS)

    The performance of superconducting radio frequency niobium cavities is sometimes limited by contaminations present on the cavity surface. In the recent years extensive research has been done to enhance the cavity performance by applying improved surface treatments such as mechanical grinding, electropolishing (EP), chemical polishing, tumbling, etc., followed by various rinsing methods such as ultrasonic pure water rinse, alcoholic rinse, high pressure water rinse, hydrogen per oxide rinse, etc. Although good cavity performance has been obtained lately by various post-EP cleaning methods, the detailed nature about the surface contaminants is still not fully characterized. Further efforts in this area are desired. Prior x-ray photoelectron spectroscopy (XPS) analyses of EPed niobium samples treated with fresh EP acid, demonstrated that the surfaces were covered mainly with the niobium oxide (Nb2O5) along with carbon, in addition a small quantity of sulfur and fluorine were also found in secondary ion mass spectroscopy (SIMS) analysis. In this article, the authors present the analyses of surface contaminations for a series of EPed niobium samples located at various positions of a single cell niobium cavity followed by ultrapure water rinsing as well as our endeavor to understand the aging effect of EP acid solution in terms of contaminations presence at the inner surface of the cavity with the help of surface analytical tools such as XPS, SIMS, and scanning electron microscope at KEK.

  20. Stages of Lip and Oral Cavity Cancer

    Science.gov (United States)

    ... common treatment for all stages of lip and oral cavity cancer. Surgery may include the following: Wide local excision : Removal ... cancer may have spread from the lip and oral cavity. Plastic surgery : An operation that restores or improves the appearance ...

  1. Optical cavity furnace for semiconductor wafer processing

    Science.gov (United States)

    Sopori, Bhushan L.

    2014-08-05

    An optical cavity furnace 10 having multiple optical energy sources 12 associated with an optical cavity 18 of the furnace. The multiple optical energy sources 12 may be lamps or other devices suitable for producing an appropriate level of optical energy. The optical cavity furnace 10 may also include one or more reflectors 14 and one or more walls 16 associated with the optical energy sources 12 such that the reflectors 14 and walls 16 define the optical cavity 18. The walls 16 may have any desired configuration or shape to enhance operation of the furnace as an optical cavity 18. The optical energy sources 12 may be positioned at any location with respect to the reflectors 14 and walls defining the optical cavity. The optical cavity furnace 10 may further include a semiconductor wafer transport system 22 for transporting one or more semiconductor wafers 20 through the optical cavity.

  2. What Are Oral Cavity and Oropharyngeal Cancers?

    Science.gov (United States)

    ... Research Get Involved Find Local ACS Learn About Cancer » Oral Cavity and Oropharyngeal Cancer » Detailed Guide » What are ... how cancers start and spread, see What Is Cancer? Oral cavity cancer, or just oral cancer, is cancer ...

  3. Laser spectroscopy

    CERN Document Server

    Demtröder, Wolfgang

    Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., ultrafast lasers (atto- and femto-second lasers) and parametric oscillators, coherent matter waves, Doppler-free Fourier spectroscopy with optical frequency combs, interference spectroscopy, quantum optics, the interferometric detection of gravitational waves and still more applications in chemical analysis, medical diagnostics, and engineering.

  4. Cavity-water interface is polar

    OpenAIRE

    Friesen, Allan D.; Matyushov, Dmitry V.

    2010-01-01

    We present the results of numerical simulations of the electrostatics and dynamics of water hydration shells surrounding Kihara cavities given by a Lennard-Jones (LJ) layer at the surface of a hard-sphere cavity. The local dielectric response of the hydration layer substantially exceeds that of bulk water, with the magnitude of the dielectric constant peak in the shell increasing with the growing cavity size. The polar shell propagates into bulk water to approximately the cavity radius. The s...

  5. Theory and technology for superconducting cavities

    CERN Document Server

    Lengeler, Herbert

    1993-01-01

    The course will address Physicist and Engineers who are newcomers in the field of accelerators and accelerating cavities. The elements of RF-Superconductivity will be presented with special relevance to accelerating cavities. The present ststus of achievable accelerating fields and RF losses will be given and their link to the special technologies for cavity fabrication and surface treatments will be stressed. Cavity auxiliaries like main couplers, higher order mode couplers and frequency tuners will be described.

  6. Prototype storage cavity for LEP accelerating RF

    CERN Multimedia

    1980-01-01

    The principle of an RF storage cavity was demonstrated with this prototype, working at 500 MHz. Ian Wilso seems to hold it in his hands. The storage cavities had 4 portholes, 1 each for: RF feed; tuning; connection to the accelerating cavity; vacuum pump. The final storage cavities were larger, to suit the lower LEP accelerating frequency of 352.2 MHz. See also 8002294, 8006510X, 8109346, 8407619X, and Annual Report 1980, p.115.

  7. Cavity QED experiments with ion Coulomb crystals

    DEFF Research Database (Denmark)

    Herskind, Peter Fønss; Dantan, Aurélien; Marler, Joan;

    2009-01-01

    Cavity QED experimental results demonstrating collective strong coupling between ensembles of atomic ions cooled into Coulomb crystals and optical cavity fields have been achieved. Collective Zeeman coherence times of milliseconds have furthermore been obtained.......Cavity QED experimental results demonstrating collective strong coupling between ensembles of atomic ions cooled into Coulomb crystals and optical cavity fields have been achieved. Collective Zeeman coherence times of milliseconds have furthermore been obtained....

  8. Nanometer cavities studied by positron annihilation

    International Nuclear Information System (INIS)

    Positronium (Ps) is trapped in cavities in insulating solids, and the lifetime of ortho Ps is determined by the size of the cavity. The information on the properties of the cavities obtained by use of the standard slow positron beam and the 'normal' positron annihilation techniques is compared for several selected cases. (author)

  9. Power coupler for the ILC crab cavity

    Energy Technology Data Exchange (ETDEWEB)

    Burt, G.; Dexter, A.; Jenkins, R.; /Lancaster U.; Beard, C.; Goudket, P.; McIntosh, P.A.; /Daresbury; Bellantoni, Leo; /Fermilab

    2007-06-01

    The ILC crab cavity will require the design of an appropriate power coupler. The beam-loading in dipole mode cavities is considerably more variable than accelerating cavities, hence simulations have been performed to establish the required external Q. Simulations of a suitable coupler were then performed and were verified using a normal conducting prototype with variable coupler tips.

  10. Investigation of carrier to envelope phase and repetition rate: fingerprints of mode-locked laser cavities

    International Nuclear Information System (INIS)

    We use mode locked lasers in a non-conventional way, as a sensor to perform intracavity measurements. To understand this new technique of intracavity phase interferometry (IPI), one should take a detailed look at the characteristics of the frequency comb and its sensitivity to its parent cavity. The laser cavity provides a means to perform phase interferometry while outside the cavity one can only observe amplitude interference. Many physical quantities such as nonlinear index, Earth rotation, magnetic field, Fresnel drag, etc are converted to phase. IPI is performed by designing laser cavities in which two pulses circulate independently, generating two pulse trains that can have a phase difference that will be converted to frequency. We also explore repetition rate spectroscopy in Rb87 by tailoring a laser wavelength, power and bandwidth. Coherent population trapping is observed when the laser repetition rate matches submultiples of hyperfine splitting. (phd tutorial)

  11. Inherent calibration of a blue LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode

    OpenAIRE

    Thalman, R; Volkamer, R.

    2010-01-01

    The combination of Cavity Enhanced Absorption Spectroscopy (CEAS) with broad-band light sources (e.g. Light-Emitting Diodes, LEDs) lends itself to the application of cavity enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) to perform sensitive and selective point measurements of multiple trace gases and aerosol extinction with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e. does not ...

  12. Fullerene photoemission time delay explores molecular cavity in attoseconds

    CERN Document Server

    Magrakvelidze, Maia; Dixit, Gopal; Madjet, Mohamed El-Amine; Chakraborty, Himadri S

    2014-01-01

    Time-resolved photoelectron spectroscopy can probe interference oscillations in C60 valence emissions that produce series of minima whose energy separation depends on the molecular size. We show that the quantum phase associated with these minima exhibits rapid variations due to electron correlations, causing rich structures in the photoemission time delay. These findings provide a way to utilize temporal information to access the fullerene cavity size, that is making the time to "see" the space, and can be generalized to photoemissions from clusters and nanostructures.

  13. Non-reacting flow visualization of supersonic combustor based on cavity and cavity-strut flameholder

    Science.gov (United States)

    Zhao, Yanhui; Liang, Jianhan; Zhao, Yuxin

    2016-04-01

    Nano-particle planer laser scattering and particle image velocimetry technology are employed to observe the flow field of scramjet combustors based on cavity and cavity-strut flameholder. Density field and velocity distribution inside combustors are obtained. Mainstream fluid enters into cavity nearby side wall in experimental observation because side wall shock waves interact with bottom wall boundary layer. Cavity fluid is entrained into mainstream in the middle of combustor meanwhile. Flow past cavity displays obvious three dimensional characteristics in both combustors. But cavity-strut combustor displays asymmetrical flow field because of strut configuration. Mass exchange between mainstream and cavity fluid is evaluated by statistic mass flow rate into cavity. Mass flow rate near side wall is raised to 6.62 times of the value in the middle of cavity combustor while it is 5.1 times in cavity-strut combustor. Further study is needed to injection strategies and realistic flow characteristics on condition of combustion.

  14. RF cavity vacuum interlock system

    Science.gov (United States)

    Jordan, K.; Crawford, K.; Bundy, R.; Dylla, H. F.; Heckman, J.; Marshall, J.; Nichols, R.; Osullivan, S.; Preble, J.; Robb, J.

    1992-03-01

    The Continuous Electron Beam Accelerator Facility (CEBAF), a continuous wave (CW) 4 GeV Electron Accelerator is undergoing construction in Newport News, Virginia. When completed in 1994, the accelerator will be the largest installation of radio-frequency superconductivity. Production of cryomodules, the fundamental building block of the machine, has started. A cryomodule consists of four sets of pairs of 1497 MHz, 5 cell niobium cavities contained in separate helium vessels and mounted in a cryostat with appropriate end caps for helium supply and return. Beam vacuum of the cavities, the connecting beam piping, the waveguides, and the cryostat insulating vacuum are crucial to the performance of the machine. The design and initial experience of the vacuum systems for the first 2 1/4 cryomodules that makeup the 45 MEV injector are discussed.

  15. A micropillar for cavity optomechanics

    Energy Technology Data Exchange (ETDEWEB)

    Kuhn, Aurélien; Neuhaus, Leonhard; Deléglise, Samuel; Briant, Tristan; Cohadon, Pierre-François; Heidmann, Antoine [Laboratoire Kastler Brossel, UPMC-ENS-CNRS, Paris (France); Van Brackel, Emmanuel [Département de Physique, ENS, Paris (France); Chartier, Claude; Ducloux, Olivier; Le Traon, Olivier [Département Mesures Physiques, ONERA, Châtillon (France); Michel, Christophe; Pinard, Laurent; Flaminio, Raffaele [Laboratoire des Matériaux Avancés, IN2P3-CNRS, Lyon (France)

    2014-12-04

    Demonstrating the quantum ground state of a macroscopic mechanical object is a major experimental challenge in physics, at the origin of the rapid emergence of cavity optomechanics. We have developed a new generation of optomechanical devices, based on a microgram quartz micropillar with a very high mechanical quality factor. The structure is used as end mirror in a Fabry-Perot cavity with a high optical finesse, leading to ultra-sensitive interferometric measurement of the resonator displacement. We expect to reach the ground state of this optomechanical resonator by combining cryogenic cooling in a dilution fridge at 30 mK and radiation-pressure cooling. We have already carried out a quantum-limited measurement of the micropillar thermal noise at low temperature.

  16. Cavity Voltage Phase Modulation MD

    CERN Document Server

    Mastoridis, Themistoklis; Molendijk, John; Timko, Helga; CERN. Geneva. ATS Department

    2016-01-01

    The LHC RF/LLRF system is currently configured for extremely stable RF voltage to minimize transient beam loading effects. The present scheme cannot be extended beyond nominal beam current since the demanded power would exceed the peak klystron power and lead to saturation. A new scheme has therefore been proposed: for beam currents above nominal (and possibly earlier), the cavity phase modulation by the beam will not be corrected (transient beam loading), but the strong RF feedback and One-Turn Delay feedback will still be active for loop and beam stability in physics. To achieve this, the voltage set point will be adapted for each bunch. The goal of this MD was to test a new algorithm that would adjust the voltage set point to achieve the cavity phase modulation that would minimize klystron forward power.

  17. Status of the ILC Crab Cavity Development

    Energy Technology Data Exchange (ETDEWEB)

    Burt, G.; Dexter, A.; /Cockcroft Inst. Accel. Sci. Tech.; Beard, C.; Goudket, P.; McIntosh, P.; /Daresbury; Bellantoni, L.; /Fermilab; Grimm, T.; Li, Z.; Xiao, L.; /SLAC

    2011-10-20

    The International Linear Collider (ILC) will require two dipole cavities to 'crab' the electron and positron bunches prior to their collision. It is proposed to use two 9 cell SCRF dipole cavities operating at a frequency of 3.9 GHz, with a transverse gradient of 3.8MV/m in order to provide the required transverse kick. Extensive numerical modelling of this cavity and its couplers has been performed. Aluminium prototypes have been manufactured and tested to measure the RF properties of the cavity and couplers. In addition single cell niobium prototypes have been manufactured and tested in a vertical cryostat. The International Collider (ILC) [1] collides bunches of electrons and positrons at a crossing angle of 14 mrad. The angle between these bunches causes a loss in luminosity due to geometric effects [2]. The luminosity lost from this geometric effect can be recovered by rotating the bunches into alignment prior to collision. One possible method of rotating the bunches is to use a crab cavity [3]. A crab cavity is a transverse defecting cavity, where the phase of the cavity is such that the head and tail of the bunch receive equal and opposite kicks. As the bunches are only 500 nm wide in the horizontal plane, the cavity phase must be strictly controlled to avoid the bunch centre being deflected too much. In order to keep the phase stability within the required limits it is required that the cavity be superconducting to avoid thermal effects in both the cavity and its RF source. At the location of the crab cavity in the ILC there is only 23 cm separation between the centre of the cavity and the extraction line, hence the cavity must be small enough to fit in this space. This, along with the difficulty of making high frequency SRF components, set the frequency of the cavity to 3.9 GHz.

  18. LHC crab cavity final report

    CERN Document Server

    Burt, G et al

    2013-01-01

    A compact 400 MHz SRF crab cavity is designed for LHC. The design has low surface fields, has no hard multipactor barriers and fits within the transverse space available on the HL-LHC. The structure has been designed to have a constant deflecting voltage across the beam-pipe aperture and this has been verified on an aluminium model. The structure includes designs for the input and lower order mode couplers.

  19. Retention proposal in complex cavities.

    Directory of Open Access Journals (Sweden)

    Pedro Alvarez Rodríguez

    2003-12-01

    Full Text Available Background: Dental Operatory is the main structure in which Odontology lies. It is not an easy discipline that gives enjoyable results with little effort due to the difficulties that a correct reconstruction of a destroyed dental element offers.The frequency with which pulpar injury occurs while anchoring additional retainers in complex cavities, the technical difficulties the lack of these devices cause and the need to simplify dental procedures lead this study to show the advantages to substitute additional retainers for a retainer surcus. Method: An observational descriptive study was applied to 53 patients(42% of the universe , sample which was selected by means of a simple randomized sample . From a proximal-occlusal cavity, the preparations were extended in a box-like shape towards the bucal or lingual region and the additional retainers were substituted for a surcus which was performed in the gingival wall of the preparation. Calcium Hydroxide of rapid dryness was used as a cavity cover and Policarboxilate cement as a base; then the amalgam restoration was performed. The number of restorations were studied taking into account the patient´s age and the failures due to fractures of amalgam, loss of vitality and periapical changes were assessed taking into consideration the patient´s age and a one- year follow up. Results: Most of the amalgam restorations were performed in patients aged from 35 to 59 years and the relative frequencies due to fractures of amalgam, loss of vitality and periapical changes were very low. Conclusion: The substitution of additional retainers for a retainer surcus in complex cavities of vital molars showed to be advantageous because it guarantees a less degree of pulpar damage and less pulpar damage.

  20. Retention proposal in complex cavities.

    OpenAIRE

    Pedro Alvarez Rodríguez; Eduardo M. Curbeira Hernández; Eduardo Duarte Marrero; Yisell Peláez Rivas; Aracelis Navarro Sánchez

    2003-01-01

    Background: Dental Operatory is the main structure in which Odontology lies. It is not an easy discipline that gives enjoyable results with little effort due to the difficulties that a correct reconstruction of a destroyed dental element offers.The frequency with which pulpar injury occurs while anchoring additional retainers in complex cavities, the technical difficulties the lack of these devices cause and the need to simplify dental procedures lead this study to show the advantages to subs...

  1. Botryomycosis in a lung cavity.

    Science.gov (United States)

    Vinay, D; Ramasubramanian, V; Gopalakrishnan, Ram; Jessani, Laxman G

    2016-01-01

    Botryomycosis is a rare pyogranulomatous disease characterized by suppurative and often granulomatous bacterial infection of the skin, soft tissues and viscera. Only about 90 cases have been reported in world literature till date: 75% of them are cases of cutaneous botryomycosis. Of the 18 reported cases of primary pulmonary botryomycosis, only one had histologically proven botryomycosis in a lung cavity. We report here a case of primary pulmonary botryomycosis occurring in a lung cavity, which is to the best of our knowledge first such case from India. The index case was a 62 year old female who presented to us with recurrent episodes of non-massive streaky hemoptysis with CT chest revealing 'Air Crescent' sign with a probable fungal ball in a left upper lobe cavity. Left upper pulmonary lobectomy was done and histopathology of the cavitary tissue revealed Splendore-Hoeppli phenomenon and features suggestive of Botryomycosis. Tissue culture from the cavitary specimen grew Pseudomonas aeruginosa. Botryomycosis can mimic Aspergilloma radiologically as was seen in our case, but therapy is often a combination of both medical and surgical measures unlike Aspergilloma. PMID:27625451

  2. LHC crab-cavity aspects and strategy

    Energy Technology Data Exchange (ETDEWEB)

    Calaga, R.; Tomas, R.; Zimmermann, F.

    2010-05-23

    The 3rd LHC Crab Cavity workshop (LHC-CC09) took place at CERN in October 2009. It reviewed the current status and identified a clear strategy towards a future crab-cavity implementation. Following the success of crab cavities in KEK-B and the strong potential for luminosity gain and leveling, CERN will pursue crab crossing for the LHC upgrade. We present a summary and outcome of the variousworkshop sessions which have led to the LHC crab-cavity strategy, covering topics like layout, cavity design, integration, machine protection, and a potential validation test in the SPS.

  3. Photonic sensing of the atmosphere by absorption spectroscopy

    International Nuclear Information System (INIS)

    Chemically reactive atmospheric species play a crucial role in tropospheric processes which affect regional air quality and global climate change. Contrary to long-lived species such as greenhouse gases, interference-free accurate and precise concentration assessments of strongly reactive short-lived species represent a real challenge. In this paper, we report on the recent progress in spectroscopic instrumental developments for monitoring of OH, NO3, HONO and NO2 by using modern photonic sources (Quantum Cascade Laser, distributed feedback diode laser, light emitting diode) in conjunction with high-sensitivity spectroscopic measurement techniques such as multi-pass cell based long optical path length absorption spectroscopy, wavelength-modulation enhanced off-axis integrated cavity output spectroscopy, Faraday rotation spectroscopy, incoherent broadband cavity enhanced absorption spectroscopy. The main techniques available for routine atmospheric measurements of OH, NO3 and HONO are overviewed, in comparison with the emerging modern photonic spectroscopy techniques.

  4. Control of Cavity Resonance Using Oscillatory Blowing

    Science.gov (United States)

    Scarfe, Alison Lamp; Chokani, Ndaona

    2000-01-01

    The near-zero net mass oscillatory blowing control of a subsonic cavity flow has been experimentally investigated. An actuator was designed and fabricated to provide both steady and oscillatory blowing over a range of blowing amplitudes and forcing frequencies. The blowing was applied just upstream of the cavity front Wall through interchangeable plate configurations These configurations enabled the effects of hole size, hole shape, and blowing angle to be examined. A significant finding is that in terms of the blowing amplitude, the near zero net mass oscillatory blowing is much more effective than steady blowing; momentum coefficients Lip two orders of magnitude smaller than those required for steady blowing are sufficient to accomplish the same control of cavity resonance. The detailed measurements obtained in the experiment include fluctuating pressure data within the cavity wall, and hot-wire measurements of the cavity shear layer. Spectral and wavelet analysis techniques are applied to understand the dynamics and mechanisms of the cavity flow with control. The oscillatory blowing, is effective in enhancing the mixing in the cavity shear layer and thus modifying the feedback loop associated with the cavity resonance. The nonlinear interactions in the cavity flow are no longer driven by the resonant cavity modes but by the forcing associated with the oscillatory blowing. The oscillatory blowing does not suppress the mode switching behavior of the cavity flow, but the amplitude modulation is reduced.

  5. CHECHIA cavity driving with FPGA controller

    Energy Technology Data Exchange (ETDEWEB)

    Czarski, T.; Koprek, W.; Pozniak, K.T.; Romaniuk, R.S. [Technical Univ. Warsaw (Poland). ELHEP Laboratory, ISE; Simrock, S. [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). TESLA

    2005-07-01

    The initial control of the superconductive cavity has recently been performed by applying the FPGA (Field Programmable Gate Array) technology system in DESY Hamburg. This first experiment turned attention to the general recognition of the cavity features and projected control methods. The electrical model of the cavity is taken as a consideration origin. The calibration of the signal channel is considered as a key preparation for an efficient cavity driving. The cavity parameters identification is confirmed as a proper approach for the required performance: driving on resonance during filling and field stabilization during flattop time with reasonable power consumption. The feed-forward and feedback modes were applied successfully for the CHECHIA cavity driving. Representative results of experiments are presented for different levels of the cavity field gradient. (orig.)

  6. Nuclear spectroscopy

    CERN Document Server

    Ajzenberg-Selove, Fay

    1960-01-01

    Nuclear Spectroscopy, Part A deals with the experimental and theoretical techniques involved in nuclear spectroscopy.This book discusses the interactions of charged particles with matter, gaseous ionization detectors, and particular mass attenuation coefficients. The magnetic gamma-ray spectrometers for photo or internal-conversion electrons, general characteristics of cross-section variation with energy, and measurement of fast neutron spectra are also elaborated. This text likewise covers the elastic scattering of photons by nuclei and measurement of widths of gamma-radiating levels.This pub

  7. Optogalvanic spectroscopy

    International Nuclear Information System (INIS)

    Laser induced optogalvanic spectroscopy in a hollow cathode-produced plasma has been used to resolve the isotopic structure of some absorption lines in uranium. We have shown that the optogalvanic signal associated with any isotope can be related to the concentration of that isotope in a multi-isotopic sample. From the results we have obtained, optogalvanic spectroscopy of sputtered samples appears to be an interesting approach to the isotopic analysis of both natural and enriched uranium and could easily be applied to the analysis of other fissile elements, such as the plutonium isotopes

  8. Broadband Tuning of Optomechanical Cavities

    CERN Document Server

    Wiederhecker, Gustavo S; Lee, Sunwoo; Lipson, Michal

    2010-01-01

    We demonstrate broadband tuning of an optomechanical microcavity optical resonance by exploring the large optomechanical coupling of a double-wheel microcavity and its uniquely low mechanical stiffness. Using a pump laser with only 13 mW at telecom wavelengths we show tuning of the silicon nitride microcavity resonances over 32 nm. This corresponds to a tuning power efficiency of only 400 $\\mu$W/nm. By choosing a relatively low optical Q resonance ($\\approx$18,000) we prevent the cavity from reaching the regime of regenerative optomechanical oscillations. The static mechanical displacement induced by optical gradient forces is estimated to be as large as 60 nm.

  9. Basketballs as spherical acoustic cavities

    Science.gov (United States)

    Russell, Daniel A.

    2010-06-01

    The sound field resulting from striking a basketball is found to be rich in frequency content, with over 50 partials in the frequency range of 0-12 kHz. The frequencies are found to closely match theoretical expectations for standing wave patterns inside a spherical cavity. Because of the degenerate nature of the mode shapes, explicit identification of the modes is not possible without internal investigation with a microphone probe. A basketball proves to be an interesting application of a boundary value problem involving spherical coordinates.

  10. Bioimpedance Spectroscopy

    DEFF Research Database (Denmark)

    Klösgen, Beate; Rümenapp, Christine; Gleich, Bernhard

    2011-01-01

    causes relaxation processes with characteristic contributions to the frequency-dependent complex dielectric constant. These dipolar relaxations were initially described by Debye (Polare Molekeln 1929). They are the basis of impedance spectroscopy (K’Owino and Sadik Electroanalysis 17(23):2101–2113, 2005...

  11. PLASMA SPECTROSCOPY

    NARCIS (Netherlands)

    Jaspers, R. J. E.

    2010-01-01

    A brief introduction into the spectroscopy of fusion plasmas is presented. Basic principles of the emission of ionic, atomic and molecular radiation is explained and a survey of the effects, which lead to the population of the respective excited levels, is given. Line radiation, continuum radiation,

  12. Rebuild of Capture Cavity 1 at Fermilab

    Energy Technology Data Exchange (ETDEWEB)

    Harms, E. [Fermilab; Arkan, T. [Fermilab; Borissov, E. [Fermilab; Dhanaraj, N. [Fermilab; Hocker, A. [Fermilab; Orlov, Y. [Fermilab; Peterson, T. [Fermilab; Premo, K. [Fermilab

    2014-01-01

    The front end of the proposed Advanced Superconducting Test Accelerator at Fermilab employs two single cavity cryomodules, known as 'Capture Cavity 1' and 'Capture Cavity 2', for the first stage of acceleration. Capture Cavity 1 was previously used as the accelerating structure for the A0 Photoinjector to a peak energy of ~14 MeV. In its new location a gradient of ~25 MV/m is required. This has necessitated a major rebuild of the cryomodule including replacement of the cavity with a higher gradient one. Retrofitting the cavity and making upgrades to the module required significant redesign. The design choices and their rationale, summary of the rebuild, and early test results are presented.

  13. Silicon Integrated Cavity Optomechanical Transducer

    Science.gov (United States)

    Zou, Jie; Miao, Houxun; Michels, Thomas; Liu, Yuxiang; Srinivasan, Kartik; Aksyuk, Vladimir

    2013-03-01

    Cavity optomechanics enables measurements of mechanical motion at the fundamental limits of precision imposed by quantum mechanics. However, the need to align and couple devices to off-chip optical components hinders development, miniaturization and broader application of ultrahigh sensitivity chip-scale optomechanical transducers. Here we demonstrate a fully integrated and optical fiber pigtailed optomechanical transducer with a high Q silicon micro-disk cavity near-field coupled to a nanoscale cantilever. We detect the motion of the cantilever by measuring the resonant frequency shift of the whispering gallery mode of the micro-disk. The sensitivity near the standard quantum limit can be reached with sub-uW optical power. Our on-chip approach combines compactness and stability with great design flexibility: the geometry of the micro-disk and cantilever can be tailored to optimize the mechanical/optical Q factors and tune the mechanical frequency over two orders of magnitudes. Electrical transduction in addition to optical transduction was also demonstrated and both can be used to effectively cool the cantilever. Moreover, cantilevers with sharp tips overhanging the chip edge were fabricated to potentially allow the mechanical cantilever to be coupled to a wide range of off-chip systems, such as spins, DNA, nanostructures and atoms on clean surfaces.

  14. Tunable Cavity Optomechanics with Ultracold Atoms

    CERN Document Server

    Purdy, T P; Botter, T; Brahms, N; Ma, Z -Y; Stamper-Kurn, D M

    2010-01-01

    We present an atom-chip-based realization of quantum cavity optomechanics with cold atoms localized within a Fabry-Perot cavity. Effective sub-wavelength positioning of the atomic ensemble allows for tuning the linear and quadratic optomechanical coupling parameters, varying the sensitivity to the displacement and strain of a compressible gaseous cantilever. We observe effects of such tuning on cavity optical nonlinearity and optomechanical frequency shifts, providing their first characterization in the quadratic-coupling regime.

  15. Dither Cavity Length Controller with Iodine Locking

    Directory of Open Access Journals (Sweden)

    Lawson Marty

    2016-01-01

    Full Text Available A cavity length controller for a seeded Q-switched frequency doubled Nd:YAG laser is constructed. The cavity length controller uses a piezo-mirror dither voltage to find the optimum length for the seeded cavity. The piezo-mirror dither also dithers the optical frequency of the output pulse. [1]. This dither in optical frequency is then used to lock to an Iodine absorption line.

  16. Ray splitting in paraxial optical cavities

    CERN Document Server

    Puentes, G; Woerdman, J P

    2003-01-01

    We present a numerical investigation of the ray dynamics in a paraxial optical cavity when a ray splitting mechanism is present. The cavity is a conventional two-mirror stable resonator and the ray splitting is achieved by inserting an optical beam splitter perpendicular to the cavity axis. We show that depending on the position of the beam splitter the optical resonator can become unstable and the ray dynamics displays a positive Lyapunov exponent.

  17. Effects of subsurface cavity expansion in clays

    OpenAIRE

    Au, SKA; Yeung, AT; Soga, K; Cheng, YM

    2007-01-01

    Subsurface cavity expansion in clay induced by compaction grouting can generate upward displacement of clay and/or increase in effective stress leading to consolidation, resulting in settlement compensation and/or shear strength enhancement respectively. However, the two potential benefits of subsurface cavity expansion may offset each other. Experiments and numerical simulations on the engineering behaviour of E-grade kaolin induced by subsurface pressure-controlled cavity expansion were con...

  18. The cavity electromagnetic field within the polarizable continuum model of solvation

    Energy Technology Data Exchange (ETDEWEB)

    Pipolo, Silvio, E-mail: silvio.pipolo@nano.cnr.it [Center S3, CNR Institute of Nanoscience, Modena (Italy); Department of Physics, University of Modena and Reggio Emilia, Modena (Italy); Corni, Stefano, E-mail: stefano.corni@nano.cnr.it [Center S3, CNR Institute of Nanoscience, Modena (Italy); Cammi, Roberto, E-mail: roberto.cammi@unipr.it [Department of Chemistry, Università degli studi di Parma, Parma (Italy)

    2014-04-28

    Cavity field effects can be defined as the consequences of the solvent polarization induced by the probing electromagnetic field upon spectroscopies of molecules in solution, and enter in the definitions of solute response properties. The polarizable continuum model of solvation (PCM) has been extended in the past years to address the cavity-field issue through the definition of an effective dipole moment that couples to the external electromagnetic field. We present here a rigorous derivation of such cavity-field treatment within the PCM starting from the general radiation-matter Hamiltonian within inhomogeneous dielectrics and recasting the interaction term to a dipolar form within the long wavelength approximation. To this aim we generalize the Göppert-Mayer and Power-Zienau-Woolley gauge transformations, usually applied in vacuo, to the case of a cavity vector potential. Our derivation also allows extending the cavity-field correction in the long-wavelength limit to the velocity gauge through the definition of an effective linear momentum operator. Furthermore, this work sets the basis for the general PCM treatment of the electromagnetic cavity field, capable to describe the radiation-matter interaction in dielectric media beyond the long-wavelength limit, providing also a tool to investigate spectroscopic properties of more complex systems such as molecules close to large nanoparticles.

  19. The cavity electromagnetic field within the polarizable continuum model of solvation

    Science.gov (United States)

    Pipolo, Silvio; Corni, Stefano; Cammi, Roberto

    2014-04-01

    Cavity field effects can be defined as the consequences of the solvent polarization induced by the probing electromagnetic field upon spectroscopies of molecules in solution, and enter in the definitions of solute response properties. The polarizable continuum model of solvation (PCM) has been extended in the past years to address the cavity-field issue through the definition of an effective dipole moment that couples to the external electromagnetic field. We present here a rigorous derivation of such cavity-field treatment within the PCM starting from the general radiation-matter Hamiltonian within inhomogeneous dielectrics and recasting the interaction term to a dipolar form within the long wavelength approximation. To this aim we generalize the Göppert-Mayer and Power-Zienau-Woolley gauge transformations, usually applied in vacuo, to the case of a cavity vector potential. Our derivation also allows extending the cavity-field correction in the long-wavelength limit to the velocity gauge through the definition of an effective linear momentum operator. Furthermore, this work sets the basis for the general PCM treatment of the electromagnetic cavity field, capable to describe the radiation-matter interaction in dielectric media beyond the long-wavelength limit, providing also a tool to investigate spectroscopic properties of more complex systems such as molecules close to large nanoparticles.

  20. Superconducting cavity driving with FPGA controller

    Science.gov (United States)

    Czarski, Tomasz; Koprek, Waldemar; Poźniak, Krzysztof T.; Romaniuk, Ryszard S.; Simrock, Stefan; Brandt, Alexander; Chase, Brian; Carcagno, Ruben; Cancelo, Gustavo; Koeth, Timothy W.

    2006-12-01

    A digital control of superconducting cavities for a linear accelerator is presented. FPGA-based controller, supported by Matlab system, was applied. Electrical model of a resonator was used for design of a control system. Calibration of the signal path is considered. Identification of cavity parameters has been carried out for adaptive control algorithm. Feed-forward and feedback modes were applied in operating the cavities. Required performance has been achieved; i.e. driving on resonance during filling and field stabilization during flattop time, while keeping reasonable level of the power consumption. Representative results of the experiments are presented for different levels of the cavity field gradient.

  1. Optically coupled cavities for wavelength switching

    International Nuclear Information System (INIS)

    An optical bistable device which presents hysteresis behavior is proposed and experimentally demonstrated. The system finds applications in wavelength switching, pulse reshaping and optical bistability. It is based on two optically coupled cavities named master and slave. Each cavity includes a semiconductor optical amplifier (SOA), acting as the gain medium of the laser, and two pair of fiber Bragg gratings (FBG) which define the lasing wavelength (being different in each cavity). Finally, a variable optical coupler (VOC) is employed to couple both cavities. Experimental characterization of the system performance is made analyzing the effects of the coupling coefficient between the two cavities and the driving current in each SOA. The properties of the hysteretic bistable curve and switching can be controlled by adjusting these parameters and the loss in the cavities. By selecting the output wavelength (λ1 or λ2) with an external filter it is possible to choose either the invert or non-invert switched signal. Experiments were developed employing both optical discrete components and a photonic integrated circuit. They show that for 8 m-long cavities the maximum switching frequency is about 500 KHz, and for 4 m-long cavities a minimum rise-time about 21 ns was measured. The switching time can be reduced by shortening the cavity lengths and using photonic integrated circuits.

  2. Optimization of a lasertron double output cavity

    International Nuclear Information System (INIS)

    Double output cavities have been used experimentally to increase the efficiency of high-power klystrons. We have used particle-in-cell simulations with the 2 + 1/2 dimensional code MASK to optimize the design of double output cavities for the lasertron under development at SLAC. We discuss design considerations for double output cavities (e.g., optimum choice of voltages and phases, efficiency, wall interception, breakdown). We describe how one calculates the cavity impedance matrix from the gap voltages and phases. Some results of the effect of varying voltage, perveance, and pulse are reported

  3. Single-mode cavity with HOMs absorber

    International Nuclear Information System (INIS)

    We present a new 500 MHz cavity which has a simple damped structure for the 1.5 GeV high-brilliant VUV ring. The feature of the cavity design is that higher-order modes (HOMs) propagate out from the cavity through the beam duct with a large diameter and are absorbed in resistive parts in the duct. A low power measurement on a prototype model of the cavity was carried out and the Q-values of HOMs were confirmed to strongly reduce. Thus the coupled-bunch instabilities due to HOMs are expected to be sufficiently suppressed. (author)

  4. Engineering topological materials in microwave cavity arrays

    CERN Document Server

    Anderson, Brandon M; Owens, Clai; Schuster, David I; Simon, Jonathan

    2016-01-01

    We present a scalable architecture for the exploration of interacting topological phases of photons in arrays of microwave cavities, using established techniques from cavity and circuit quantum electrodynamics. A time-reversal symmetry breaking (non-reciprocal) flux is induced by coupling the microwave cavities to ferrites, allowing for the production of a variety of topological band structures including the $\\alpha=1/4$ Hofstadter model. Effective photon-photon interactions are included by coupling the cavities to superconducting qubits, and are sufficient to produce a $\

  5. Mechanical Properties of Ingot Nb Cavities

    Energy Technology Data Exchange (ETDEWEB)

    Ciovati, Gianluigi; Dhakal, Pashupati; Kneisel, Peter; Mammosser, John; Matalevich, Joseph; Rao Myneni, Ganapati

    2014-07-01

    This contribution presents the results of measurements of the resonant frequency and of strain along the contour of a single-cell cavity made of ingot Nb subjected to increasing uniform differential pressure, up to 6 atm. The data were used to infer mechanical properties of this material after cavity fabrication, by comparison with the results from simulation calculations done with ANSYS. The objective is to provide useful information about the mechanical properties of ingot Nb cavities which can be used in the design phase of SRF cavities intended to be built with this material.

  6. Design of the ILC Crab Cavity System

    Energy Technology Data Exchange (ETDEWEB)

    Adolphsen, C.; Beard, C.; Bellantoni, L.; Burt, G.; Carter, R.; Chase, B.; Church, M.; Dexter, A.; Dykes, M.; Edwards, H.; Goudket, P; Jenkins, R.; Jones, R.M.; Kalinin,; Khabiboulline, T.; Ko, K.; Latina, A.; Li, Z.; Ma, L.; McIntosh, P.; Ng, C.; /SLAC /Daresbury /Fermilab /Cockcroft Inst. Accel. Sci. Tech. /CERN

    2007-08-15

    The International Linear Collider (ILC) has a 14 mrad crossing angle in order to aid extraction of spent bunches. As a result of the bunch shape at the interaction point, this crossing angle at the collision causes a large luminosity loss which can be recovered by rotating the bunches prior to collision using a crab cavity. The ILC baseline crab cavity is a 9-cell superconducting dipole cavity operating at a frequency of 3.9 GHz. In this paper the design of the ILC crab cavity and its phase control system, as selected for the RDR in February 2007 is described in fuller detail.

  7. Generation of Cluster States in Cavity QED

    Institute of Scientific and Technical Information of China (English)

    ZHOU Yan-Li; YANG Li-Jia; DAI Hong-Yi

    2007-01-01

    We propose two schemes for the generation of cluster states in the context of cavity quantum electrodynamics (QED).In the first scheme,we prepare multi-cavity cluster states with information encoded in the coherent states.The second scheme is to generate multi-atom cluster states,where qubits are represented by the states of cascade Rydberg atoms.Both the schemes are based on the atom-cavity interaction and the atomic spontaneous radiation can be effciently reduced since the cavity frequency is largely detuned from the atomic transition frequency.

  8. Introductory lecture on waveguides and cavities

    International Nuclear Information System (INIS)

    This lecture has two parts: waveguides and cavities. Basic topics are discussed which can serve as bases for the following lectures. Many of the results obtained in the first part concerning waveguides are applied in the second part in the discussion on cavity properties, since a cavity can be considered as a part of a waveguide, a cavity resonant mode being a superposition of two counter-travelling waves in the waveguide. In deriving most of the mathematical formulas, complex number representation - that is, phasor forms - are used. For the final results, however, real number representations are also provided as much as possible as an aid to a more intuitive understanding. (author)

  9. Optical Spectroscopy

    DEFF Research Database (Denmark)

    Thyrhaug, Erling

    containing systems using simple instrumentation and well-known and understood theoretical concepts. Overall it is attempted to achieve this goal by presenting five research projects that I have been involved in during my Ph.D. studies which collectively demonstrate some of the many possibilities of gaining...... containing systems and are characterized using techniques in optical spectroscopy. Of the standard techniques in optical spectroscopy, particular attention has been paid to those based on time-resolved measurements and polarization, which is reflected in the experiment design in the projects. Not all...... solution. In project 2 the intramolecular excited state association reaction between aniline and anthracene is characterized by both steady-state and time-resolved techniques, where the time resolved fluorescence measurements in particular allowed for the determination of the reaction rate constants...

  10. Controlling dipole squeezing of two atoms inside a cavity via manipulating an atom outside the cavity

    Institute of Scientific and Technical Information of China (English)

    Liu Tang-Kun; Wang Ji-Suo; Feng Jian; Zhan Ming-Sheng

    2004-01-01

    Considering that three two-level atoms are initially in the GHZ single state and two of the atoms are simultaneously put into a cavity initially in the coherent state, we investigate the dipole squeezing properties of the two atoms inside the cavity under the condition of resonant interaction. It is shown that dipole squeezing properties of the two atoms inside the cavity are strongly affected by rotation manipulating of the atom outside the cavity.

  11. Hydrodynamic Drag on Streamlined Projectiles and Cavities

    KAUST Repository

    Jetly, Aditya

    2016-04-19

    The air cavity formation resulting from the water-entry of solid objects has been the subject of extensive research due to its application in various fields such as biology, marine vehicles, sports and oil and gas industries. Recently we demonstrated that at certain conditions following the closing of the air cavity formed by the initial impact of a superhydrophobic sphere on a free water surface a stable streamlined shape air cavity can remain attached to the sphere. The formation of superhydrophobic sphere and attached air cavity reaches a steady state during the free fall. In this thesis we further explore this novel phenomenon to quantify the drag on streamlined shape cavities. The drag on the sphere-cavity formation is then compared with the drag on solid projectile which were designed to have self-similar shape to that of the cavity. The solid projectiles of adjustable weight were produced using 3D printing technique. In a set of experiments on the free fall of projectile we determined the variation of projectiles drag coefficient as a function of the projectiles length to diameter ratio and the projectiles specific weight, covering a range of intermediate Reynolds number, Re ~ 104 – 105 which are characteristic for our streamlined cavity experiments. Parallel free fall experiment with sphere attached streamlined air cavity and projectile of the same shape and effective weight clearly demonstrated the drag reduction effect due to the stress-free boundary condition at cavity liquid interface. The streamlined cavity experiments can be used as the upper bound estimate of the drag reduction by air layers naturally sustained on superhydrophobic surfaces in contact with water. In the final part of the thesis we design an experiment to test the drag reduction capacity of robust superhydrophobic coatings deposited on the surface of various model vessels.

  12. Superconducting cavities developments efforts at RRCAT

    International Nuclear Information System (INIS)

    Superconducting RE cavities are the work-horse for many existing and proposed linear accelerators. Raja Ramanna Centre for Advanced Technology (RRCAT) has initiated a comprehensive R and D program for development of Superconducting RF cavities suitable for high energy accelerator application like SNS and ADS. For the initial phase of technology demonstration several prototype 1.3 GHz single cell-cavities have been developed. The work began with development of prototype single cell cavities in aluminum and copper. This helped in development of cavity manufacturing process, proving various tooling and learning on various mechanical and RF qualification processes. The parts manufacturing was done at RRCAT and Electron beam welding was carried out at Indian industry. These cavities further served during commissioning trials for various cavity processing infrastructure being developed at RRCAT and are also a potential candidate for Niobium thin film deposition R and D. Based on the above experience, few single cell cavities were developed in fine grain niobium. The critical technology of forming and machining of niobium and the intermediate RF qualification were developed at RRCAT. The EB welding of bulk niobium cavities was carried out in collaboration with IUAC, New Delhi at their facility. As a next logical step efforts are now on for development of multicell cavities. The prototype dumbbells and end group made of aluminium, comprising of RF and HOM couplers ports have also been developed, with their LB welding done at Indian industry. In this paper we shall present the development efforts towards manufacturing of 1.3 GHz single cell cavities and their initial processing and qualification. (author)

  13. Laser spectroscopy of gas confined in nanoporous materials

    CERN Document Server

    Svensson, Tomas

    2009-01-01

    We show that high-resolution laser spectroscopy can probe surface interactions of gas confined in nano-cavities of porous materials. We report on strong line broadening and unfamiliar lineshapes due to tight confinement, as well as signal enhancement due to multiple photon scattering. This new domain of laser spectroscopy constitute a challenge for the theory of collisions and spectroscopic lineshapes, and open for new ways of analyzing porous materials and processes taking place therein.

  14. Leaky Modes of Dielectric Cavities

    CERN Document Server

    Mansuripur, Masud; Jakobsen, Per

    2016-01-01

    In the absence of external excitation, light trapped within a dielectric medium generally decays by leaking out (and also by getting absorbed within the medium). We analyze the leaky modes of a parallel-plate slab, a solid glass sphere, and a solid glass cylinder, by examining those solutions of Maxwell's equations (for dispersive as well as non-dispersive media) which admit of a complex-valued oscillation frequency. Under certain circumstances, these leaky modes constitute a complete set into which an arbitrary distribution of the electromagnetic field residing inside a dielectric body can be expanded. We provide completeness proofs, and also present results of numerical calculations that illustrate the relationship between the leaky modes and the resonances of dielectric cavities formed by a simple parallel-plate slab, a glass sphere, and a glass cylinder.

  15. Cavity Voltage Phase Modulation MD

    CERN Document Server

    Mastoridis, T; Butterworth, A; Molendijk, J; Tuckmantel, J

    2012-01-01

    The LHC RF/LLRF system is currently setup for extremely stable RF voltage to minimize transient beam loading eects. The present scheme cannot be extended beyond nominal beam current since the demanded power would push the klystrons to saturation. For beam currents above nominal (and possibly earlier), the cavity phase modulation by the beam will be not be corrected (transient beam loading), but the strong RF feedback and One-Turn Delay feedback will still be active for loop and beam stability in physics. To achieve this, the voltage set point will be adapted for each bunch. The goal of this MD was to test an iterative algorithm that would adjust the voltage set point to achieve the optimal phase modulation for klystron forward power considerations.

  16. Scheme for Implementation of Quantum Game in Cavity QED

    International Nuclear Information System (INIS)

    We propose an experimentally feasible scheme to implement two-player quantum game in cavity quantum electrodynamics (QED). During the process, the cavity is only virtually excited, thus our scheme is insensitive to the cavity field states and cavity decay. The scheme can be realized in the range of current cavity QED techniques.

  17. A scheme for implementing quantum game in cavity QED

    Institute of Scientific and Technical Information of China (English)

    CaoShuai; Fang Mao-Fa; Liu Jian-Bin; Wang Xin-Wen; Zheng Xiao-juan

    2009-01-01

    In this paper, we propose a scheme fot implementing quantum game (QG) in cavity quantum electrodynam-ics(QED). In the scheme, the cavity is only virtually excited and thus the proposal is insensitive to the cavity fields states and cavity decay. So our proposal can be experimentally realized in the range of current cavity QED techniques.

  18. Scheme for Implementation of Quantum Game in Cavity QED

    Institute of Scientific and Technical Information of China (English)

    ZHANG Li-Chun; CAO Shu-Ai; WU Yue-Qin; FANG Mao-Fa; LI Huai-Fan; ZHENG Xiao-Juan; ZHAO Ren; WANG Xin-Wen; LI Ze-Hua

    2008-01-01

    We propose an experimentally feasible scheme to implement two-player quantum game in cavity quantum electrodynamics (QED). During the process, the cavity is only virtually excited, thus our scheme is insensitive to the cavity field states and cavity decay. The scheme can be realized in the range of current cavity QED techniques.

  19. Cavity Pressure Behaviour in Micro Injection Moulding

    DEFF Research Database (Denmark)

    Griffiths, C.A.; Dimov, S.S.; Scholz, S.;

    2010-01-01

    as well as with the filling of the cavity by the polymer melt. In this paper, two parameters derived from cavity pressure over time (i.e. pressure work). The influence of four µIM parameters (melt temperature, mould temperature, injection speed, aand packing pressure) on the two pressure...

  20. Superconducting accelerating four-cell cavity

    CERN Multimedia

    1980-01-01

    A close view of the four-cell cavity. This was a prototype designed for LEP2 (LEP1 had warm copper cavities as accelerating elements). The first successful tests were made in December 1980 - reaching a Q = 10^6. (see photo 8012650X)

  1. Temperature stabilization of optofluidic photonic crystal cavities

    DEFF Research Database (Denmark)

    Kamutsch, Christian; Smith, Cameron L.C.; Graham, Alexandra;

    2009-01-01

    We present a principle for the temperature stabilization of photonic crystal (PhC) cavities based on optofluidics. We introduce an analytic method enabling a specific mode of a cavity to be made wavelength insensitive to changes in ambient temperature. Using this analysis, we experimentally...

  2. Continuous optical discharge in a laser cavity

    Science.gov (United States)

    Chivel', Yu. A.

    2016-08-01

    Optical discharge in a laser cavity is experimentally studied. A significant increase in the absorption of laser radiation (up to total absorption) is revealed. Optical schemes for initiation and maintaining of optical discharge in the cavity are proposed for technological applications of the optical discharge.

  3. Agent for roentgenocontrast examination of cavities

    International Nuclear Information System (INIS)

    The water-soluble agent, additionaly containing starch, agar, water, is suggested to increase accuracy of injured cavity diagnostics. The method for roentgenocontrast agent preparation on the base of starch-agar gel is described. Advantages of the agent suggested in comparison with those of roentgenologic cavity investigation used are shown

  4. A spherical cavity in an Einstein universe

    Energy Technology Data Exchange (ETDEWEB)

    Kofinti, N.K.

    1980-03-01

    Suitable metric forms for the regions and a outside a sperical cavity in an Einstein universe are derived by means of perturbation. It is shown that for low proper pressure, the cavity behaves like ''negative'' Schwarzchild mass. Finally, the possibility of carrying over to the exact theory a proposed definition of the gravitational field in a matter is examined.

  5. Dissipative preparation of entanglement in optical cavities

    DEFF Research Database (Denmark)

    Kastoryano, Michael James; Reiter, Florentin; Sørensen, Anders Søndberg

    2011-01-01

    We propose a novel scheme for the preparation of a maximally entangled state of two atoms in an optical cavity. Starting from an arbitrary initial state, a singlet state is prepared as the unique fixed point of a dissipative quantum dynamical process. In our scheme, cavity decay is no longer...

  6. Spallation neutron source RF cavity bias system

    International Nuclear Information System (INIS)

    The Spallation Neutron Source r.f. cavity bias system is described under the topic headings: bias system, r.f. cavity, cables, d.c. bias power supply, transistor regulator and control system. Calculation of 4 core 300 mm solid aluminium cable inductance, coaxial shunt frequency response and transistor regulator computed frequency response, are discussed in appendices 1-3. (U.K.)

  7. Large grain cavities from pure niobium ingot

    Science.gov (United States)

    Myneni, Ganapati Rao; Kneisel, Peter; Cameiro, Tadeu

    2012-03-06

    Niobium cavities are fabricated by the drawing and ironing of as cast niobium ingot slices rather than from cold rolled niobium sheet. This method results in the production of niobium cavities having a minimum of grain boundaries at a significantly reduced cost as compared to the production of such structures from cold rolled sheet.

  8. Air flow in a collapsing cavity

    CERN Document Server

    Peters, Ivo R; Lohse, Detlef; van der Meer, Devaraj

    2013-01-01

    We experimentally study the airflow in a collapsing cavity created by the impact of a circular disk on a water surface. We measure the air velocity in the collapsing neck in two ways: Directly, by means of employing particle image velocimetry of smoke injected into the cavity and indirectly, by determining the time rate of change of the volume of the cavity at pinch-off and deducing the air flow in the neck under the assumption that the air is incompressible. We compare our experiments to boundary integral simulations and show that close to the moment of pinch-off, compressibility of the air starts to play a crucial role in the behavior of the cavity. Finally, we measure how the air flow rate at pinch-off depends on the Froude number and explain the observed dependence using a theoretical model of the cavity collapse.

  9. TESLA cavity driving with FPGA controller

    Science.gov (United States)

    Czarski, Tomasz; Pozniak, Krzysztof; Romaniuk, Ryszard; Simrock, Stefan

    2005-09-01

    The digital control of the TESLA (TeV-Energy Superconducting Linear Accelerator) resonator is presented. The laboratory setup of the CHECHIA cavity in DESY-Hamburg has been driven by the FPGA (Field Programmable Gate Array) technology system. This experiment focused attention to the general recognition of the cavity features and projected control methods. The electrical model of the resonator is taken as a consideration origin. The calibration of the signal channel is considered as a key preparation for an efficient cavity driving. The identification of the resonator parameters is confirmed as a proper approach for the required performance: driving on resonance during filling and field stabilization during flattop time with reasonable power consumption. The feed-forward and feedback modes were applied successfully for the CHECHIA cavity driving. Representative results of experiments are presented for different levels of the cavity field gradient.

  10. Vertical external cavity surface emitting semiconductor lasers

    CERN Document Server

    Holm, M

    2001-01-01

    Active stabilisation showed a relative locked linewidth of approx 3 kHz. Coarse tuning over 7 nm was achieved using a 3-plate birefingent filter plate while fine-tuning using cavity length change allowed tuning over 250 MHz. Vertical external cavity semiconductor lasers have emerged as an interesting technology based on current vertical cavity semiconductor laser knowledge. High power output into a single transverse mode has attracted companies requiring good fibre coupling for telecommunications systems. The structure comprises of a grown semiconductor Bragg reflector topped with a multiple quantum well gain region. This is then included in an external cavity. This device is then optically pumped to promote laser action. Theoretical modelling of AIGaAs based VECSEL structures was undertaken, showing the effect of device design on laser characteristics. A simple 3-mirror cavity was constructed to assess the static characteristics of the structure. Up to 153 mW of output power was achieved in a single transver...

  11. Vertical-Cavity Surface-Emitting Lasers

    Science.gov (United States)

    Wilmsen, Carl W.; Temkin, Henryk; Coldren, Larry A.

    2002-01-01

    1. Introduction to VCSELs L. A. Coldren, C. W. Wilmsen and H. Temkin; 2. Fundamental issues in VCSEL design L. A. Coldren and Eric R. Hegblom; 3. Enhancement of spontaneous emission in microcavities E. F. Schubert and N. E. J. Hunt; 4. Epitaxy of vertical-cavity lasers R. P. Schneider Jr and Y. H. Young; 5. Fabrication and performance of vertical-cavity surface-emitting lasers Kent D. Choquette and Kent Geib; 6. Polarization related properties of vertical cavity lasers Dmitri Kuksenkov and Henryk Temkin; 7. Visible light emitting vertical cavity lasers Robert L. Thornton; 8. Long-wavelength vertical-cavity lasers Dubrakovo I. Babic, Joachim Piprek and John E. Bowers; 9. Overview of VCSEL applications Richard C. Williamson; 10. Optical interconnection applications and required characteristics Kenichi Kasahara; 11. VCSEL-based fiber-optic data communications Kenneth Hahn and Kirk Giboney; 12. VCSEL-based smart pixels for free space optoelectronic processing C. W. Wilmsen.

  12. Aspergillosis complicating a microwave ablation cavity.

    Science.gov (United States)

    Singh, Saurabh; Bandula, Steven; Brown, Jeremy; Whelan, Jeremy; Illing, Rowland

    2016-01-01

    We present a case of a patient who following chemotherapy developed semi-invasive pulmonary aspergillosis and an aspergilloma in a lung cavity previously formed by microwave ablation (MWA). A 55-year-old woman presented with cough and shortness of breath after finishing three cycles of chemotherapy for a metastatic nerve sheath tumour. She had been treated by MWA for pulmonary metastases 2 years previously which resulted in a residual right apical lung cavity. Postchemotherapy imaging showed that this cavity had enlarged, developed a thicker wall and contained lobulated soft tissue with a crescent sign on coronal reformats. In addition, the patient's Aspergillus-specific IgG was markedly raised. Treatment with itraconazole improved the symptoms and reduced the cavity size and wall thickness. This case shows that persisting lung cavities after MWA are a potential site for semi-invasive aspergillosis and has implications for the timing of chemotherapy in patient with metastatic lung disease. PMID:27624446

  13. Cavity cooling a single charged levitated nanosphere.

    Science.gov (United States)

    Millen, J; Fonseca, P Z G; Mavrogordatos, T; Monteiro, T S; Barker, P F

    2015-03-27

    Optomechanical cavity cooling of levitated objects offers the possibility for laboratory investigation of the macroscopic quantum behavior of systems that are largely decoupled from their environment. However, experimental progress has been hindered by particle loss mechanisms, which have prevented levitation and cavity cooling in a vacuum. We overcome this problem with a new type of hybrid electro-optical trap formed from a Paul trap within a single-mode optical cavity. We demonstrate a factor of 100 cavity cooling of 400 nm diameter silica spheres trapped in vacuum. This paves the way for ground-state cooling in a smaller, higher finesse cavity, as we show that a novel feature of the hybrid trap is that the optomechanical cooling becomes actively driven by the Paul trap, even for singly charged nanospheres. PMID:25860743

  14. Performance of 3-cell Seamless Niobium cavities

    Energy Technology Data Exchange (ETDEWEB)

    Kneisel, Peter K. [JLAB; Ciovati, Gianluigi [JLBA; Jelezov, I. [DESY, Hamburg; Singer, W. [DESY, Hamburg; Singer, X. [DESY, Hamburg

    2009-11-01

    In the last several months we have surface treated and cryogenically tested three TESLA-type 3-cell cavities, which had been manufactured at DESY as seamless assemblies by hydroforming. The cavities were completed at JLab with beam tube/flange assemblies. All three cavities performed very well after they had been post-purified with titanium at 1250C for 3 hrs. The cavities, two of which consisted of an end cell and 2 center cells and one was a center cell assembly, achieved gradients of Eacc = 32 MV/m, 34 MV/m and 35 MV/m without quenches. The performance was limited by the appearance of the “Q-drop” in the absence of field emission. This contribution reports about the various measurements undertaken with these cavities.

  15. Niobium Cavity Electropolishing Modelling and Optimisation

    CERN Document Server

    Ferreira, L M A; Forel, S; Shirra, J A

    2013-01-01

    It’s widely accepted that electropolishing (EP) is the most suitable surface finishing process to achieve high performance bulk Nb accelerating cavities. At CERN and in preparation for the processing of the 704 MHz high-beta Superconducting Proton Linac (SPL) cavities a new vertical electropolishing facility has been assembled and a study is on-going for the modelling of electropolishing on cavities with COMSOL® software. In a first phase, the electrochemical parameters were taken into account for a fixed process temperature and flow rate, and are presented in this poster as well as the results obtained on a real SPL single cell cavity. The procedure to acquire the data used as input for the simulation is presented. The modelling procedure adopted to optimise the cathode geometry, aimed at a uniform current density distribution in the cavity cell for the minimum working potential and total current is explained. Some preliminary results on fluid dynamics is also briefly described.

  16. Surface-plasmon-polariton hybridized cavity modes in submicrometer slits in a thin Au film

    Science.gov (United States)

    Walther, R.; Fritz, S.; Müller, E.; Schneider, R.; Maniv, T.; Cohen, H.; Matyssek, C.; Busch, K.; Gerthsen, D.

    2016-06-01

    The excitation of cavity standing waves in double-slit structures in thin gold films, with slit lengths between 400 and 2560 nm, was probed with a strongly focused electron beam in a transmission electron microscope. The energies and wavelengths of cavity modes up to the 11 th mode order were measured with electron energy loss spectroscopy to derive the corresponding dispersion relation. For all orders, a significant redshift of mode energies accompanied by a wavelength elongation relative to the expected resonator energies and wavelengths is observed. The resultant dispersion relation is found to closely follow the well-known dispersion law of surface-plasmon polaritons (SPPs) propagating on a gold/air interface, thus providing direct evidence for the hybridized nature of the detected cavity modes with SPPs.

  17. HIE-ISOLDE cavity production – results from thermal modelling of the cavity during sputtering

    CERN Document Server

    Kupiainen, P

    2013-01-01

    The HIE-ISOLDE project is in the phase of cavity production and optimization. Cavities are made of copper and sputtered niobium. We build an ANSYS model to model thermal distributions and heat flows in the cavity structure. We limited the analysis to handle the cavity during sputtering and investigated the effect of different coating power. The aim was to check how results compare to experimental data and vary boundary conditions to improve the model. With two boundary conditions (fixed room and cavity top temperatures), we observed a power loss due to fixed temperature, as expected. The temperature gradient between the bottom and top cavity did not reach the values of the experimental data. With one boundary condition (fixed temperature on sputtering chamber structure), the expected linear proportionality was observed clearly between the temperatures of the cavity and the power. The temperature gradients were also observed to increase with power. We observed an offset in the data compared to experimental dat...

  18. Prototype superconducting radio-frequency cavity for LEP

    CERN Multimedia

    1985-01-01

    This niobium superconducting cavity was part of the prototype stages for an upgrade to LEP, known as LEP-2. Superconducting cavities would eventually replace the traditional copper cavities and allow beam energies of 100 GeV.

  19. Present status of superconducting cavity developments

    Energy Technology Data Exchange (ETDEWEB)

    Ouchi, Nobuo; Kusano, Joichi; Hasegawa, Kazuo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment] [and others

    1997-11-01

    An R and D work of a superconducting (SC) cavity for the high intensity proton linac has begun at JAERI in collaboration with KEK. The RF field calculation and the structural analysis have been made to determine the cavity shape in the proton energy range between 100 and 1500 MeV. The results indicate the feasibility of a SC proton linac. A vertical test stand with clean room, water rinsing system, cavity evacuation pumping system, cryostat and data acquisition system has been installed to demonstrate the cavity performance. A single cell cavity of {beta}=0.5 has been fabricated and tested at the test stand to obtain the Q-value and the maximum surface electric field strength. The measured Q-values have been found to be high enough for our requirement while the field strength was limited to about 75% of the specification by the multipacting. We describe the preliminary design of the SC cavity, the overview of the vertical test stand and experimental results of the single cell cavity. (author)

  20. Superconducting cavity driving with FPGA controller

    International Nuclear Information System (INIS)

    The digital control of several superconducting cavities for a linear accelerator is presented. The laboratory setup of the CHECHIA cavity and ACC1 module of the VU-FEL TTF in DESY-Hamburg have both been driven by a Field Programmable Gate Array (FPGA) based system. Additionally, a single 9-cell TESLA Superconducting cavity of the FNPL Photo Injector at FERMILAB has been remotely controlled from WUT-ISE laboratory with the support of the DESY team using the same FPGA control system. These experiments focused attention on the general recognition of the cavity features and projected control methods. An electrical model of the resonator was taken as a starting point. Calibration of the signal path is considered key in preparation for the efficient driving of a cavity. Identification of the resonator parameters has been proven to be a successful approach in achieving required performance; i.e. driving on resonance during filling and field stabilization during flattop time while requiring reasonable levels of power consumption. Feed-forward and feedback modes were successfully applied in operating the cavities. Representative results of the experiments are presented for different levels of the cavity field gradient. (orig.)

  1. Optimized Multi-Ion Cavity Coupling

    Science.gov (United States)

    Begley, Stephen; Vogt, Markus; Gulati, Gurpreet Kaur; Takahashi, Hiroki; Keller, Matthias

    2016-06-01

    Recent technological advances in cavity quantum electrodynamics (CQED) are paving the way to utilize multiple quantum emitters confined in a single optical cavity. In such systems, it is crucially important to control the quantum mechanical coupling of individual emitters to the cavity mode. In this regard, combining ion trap technologies with CQED provides a particularly promising approach due to the well-established motional control over trapped ions. Here, we experimentally demonstrate coupling of up to five trapped ions in a string to a high-finesse optical cavity. By changing the axial position and spacing of the ions in a fully deterministic manner, we systematically characterize their coupling to the cavity mode through visibility measurements of the cavity emission. In good agreement with the theoretical model, the results demonstrate that the geometrical configuration of multiple trapped ions can be manipulated to obtain optimal cavity coupling. Our system presents a new ground for exploring CQED with multiple quantum emitters, enabled by the highly controllable collective light-matter interaction.

  2. A low-temperature external cavity diode laser for broad wavelength tuning

    OpenAIRE

    Tobias, William G.; Rosenberg, Jason S.; Hutzler, Nicholas R.; Ni, Kang-Kuen

    2016-01-01

    We report on the design and characterization of a low-temperature external cavity diode laser (ECDL) system for broad wavelength tuning. The performance achieved with multiple diode models addresses the scarcity of commercial red laser diodes below 633 nm, which is a wavelength range relevant to spectroscopy of many molecules and ions. Using a combination of multiple-stage thermoelectric cooling and water cooling, the operating temperature of a laser diode is lowered to -64{\\deg}C, more than ...

  3. Demonstration of superconducting micromachined cavities

    Science.gov (United States)

    Brecht, T.; Reagor, M.; Chu, Y.; Pfaff, W.; Wang, C.; Frunzio, L.; Devoret, M. H.; Schoelkopf, R. J.

    2015-11-01

    Superconducting enclosures will be key components of scalable quantum computing devices based on circuit quantum electrodynamics. Within a densely integrated device, they can protect qubits from noise and serve as quantum memory units. Whether constructed by machining bulk pieces of metal or microfabricating wafers, 3D enclosures are typically assembled from two or more parts. The resulting seams potentially dissipate crossing currents and limit performance. In this letter, we present measured quality factors of superconducting cavity resonators of several materials, dimensions, and seam locations. We observe that superconducting indium can be a low-loss RF conductor and form low-loss seams. Leveraging this, we create a superconducting micromachined resonator with indium that has a quality factor of two million, despite a greatly reduced mode volume. Inter-layer coupling to this type of resonator is achieved by an aperture located under a planar transmission line. The described techniques demonstrate a proof-of-principle for multilayer microwave integrated quantum circuits for scalable quantum computing.

  4. Demonstration of superconducting micromachined cavities

    Energy Technology Data Exchange (ETDEWEB)

    Brecht, T., E-mail: teresa.brecht@yale.edu; Reagor, M.; Chu, Y.; Pfaff, W.; Wang, C.; Frunzio, L.; Devoret, M. H.; Schoelkopf, R. J. [Department of Applied Physics, Yale University, New Haven, Connecticut 06511 (United States)

    2015-11-09

    Superconducting enclosures will be key components of scalable quantum computing devices based on circuit quantum electrodynamics. Within a densely integrated device, they can protect qubits from noise and serve as quantum memory units. Whether constructed by machining bulk pieces of metal or microfabricating wafers, 3D enclosures are typically assembled from two or more parts. The resulting seams potentially dissipate crossing currents and limit performance. In this letter, we present measured quality factors of superconducting cavity resonators of several materials, dimensions, and seam locations. We observe that superconducting indium can be a low-loss RF conductor and form low-loss seams. Leveraging this, we create a superconducting micromachined resonator with indium that has a quality factor of two million, despite a greatly reduced mode volume. Inter-layer coupling to this type of resonator is achieved by an aperture located under a planar transmission line. The described techniques demonstrate a proof-of-principle for multilayer microwave integrated quantum circuits for scalable quantum computing.

  5. FPGA based real time RF cavity simulator for superconducting RF cavity

    International Nuclear Information System (INIS)

    RF cavity is one of the most important component in an accelerator, it is used for producing appropriate electromagnetic fields to accelerate the charged particles. The response of RF cavity to an input RF signal depends on the various operating conditions. Actual operating conditions of RF cavity are difficult to create in lab and also RF cavity is not easily available which limits the study and testing of RF systems that involve RF cavity. This calls for the requirement of a real time hardware model of the RF cavity which can be integrated with other RF systems for their testing in lab. This limitation is even more severe for superconducting RF cavities which need to be operated with the required cryogenics. Thus a real time hardware model of the superconducting RF cavity has been realized on FPGA. Real time RF Cavity simulator can be used to study the response of RF cavity under various operating conditions and for testing and optimization of other RF sub-systems particularly the Low Level RF feedback control systems in lab

  6. Clamshell microwave cavities having a superconductive coating

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, D. Wayne (Los Alamos, NM); Arendt, Paul N. (Los Alamos, NM); Piel, Helmut (Wuppertal, DE)

    1994-01-01

    A microwave cavity including a pair of opposing clamshell halves, such halves comprised of a metal selected from the group consisting of silver, copper, or a silver-based alloy, wherein the cavity is further characterized as exhibiting a dominant TE.sub.011 mode is provided together with an embodiment wherein the interior concave surfaces of the clamshell halves are coated with a superconductive material. In the case of copper clamshell halves, the microwave cavity has a Q-value of about 1.2.times.10.sup.5 as measured at a temperature of 10K and a frequency of 10 GHz.

  7. Coherent cavity networks with complete connectivity

    OpenAIRE

    Kyoseva, Elica S.; Beige, Almut; Kwek, Leong Chuan

    2011-01-01

    When cavity photons couple to an optical fiber with a continuum of modes, they usually leak out within a finite amount of time. However, if the fiber is about one meter long and linked to a mirror, photons bounce back and forth within the fiber on a much faster time scale. As a result, {\\em dynamical decoupling} prevents the cavity photons from entering the fiber. In this paper we use the simultaneous dynamical decoupling of a large number of distant cavities from the fiber modes of linear op...

  8. Q degradations in superconducting niobium cavities

    International Nuclear Information System (INIS)

    In the past year, several laboratories around the world have observed degradations of the Q value of superconducting niobium cavities made from high thermal conductivity niobium under certain cooldown conditions. Especially under slow cooldown or warmup to temperatures < 200 K of larger systems severe degradations have been reported. A systematic study of the influence of the cooldown speed, warmup conditions, multiple cooldowns and chemical surface treatment on cavity performance of cavities manufactured from niobium of different purity has been conducted. Possible cures such as anodic oxidation are being explored and results of these investigations are reported

  9. Piezoelectric Voltage Coupled Reentrant Cavity Resonator

    CERN Document Server

    Carvalho, Natalia C; Floch, Jean-Michel Le; Tobar, Michael Edmund

    2014-01-01

    A piezoelectric voltage coupled microwave reentrant cavity has been developed. The central cavity post is bonded to a piezoelectric actuator allowing the voltage control of small post displacements over a high dynamic range. We show that such a cavity can be implemented as a voltage tunable resonator, a transducer for exciting and measuring mechanical modes of the structure and a transducer for measuring comparative sensitivity of the piezoelectric material. Experiments were conducted at room and cryogenic temperatures with results verified using Finite Element software.

  10. LHC Crab Cavity Coupler Test Boxes

    CERN Document Server

    Mitchell, James; Burt, Graeme; Calaga, Rama; Macpherson, Alick; Montesinos, Eric; Silva, Subashini; Tutte, Adam; Xiao, Binping

    2016-01-01

    The LHC double quarter wave (DQW) crab cavities have two different types of Higher Order Mode (HOM) couplers in addition to a fundamental power coupler (FPC). The FPC requires conditioning, so to achieve this we have designed a radio-frequency (RF) quarter wave resonator to provide high transmission between two opposing FPCs. For the HOM couplers we must ensure that the stop-band filter is positioned at the cavity frequency and that peak transmission occurs at the same frequencies as the strongest HOMs. We have designed two test boxes which preserve the cavity spectral response in order to test the couplers.

  11. RF cavity evaluation with the code SUPERFISH

    International Nuclear Information System (INIS)

    The computer code SUPERFISH calculates axisymmetric rf fields and is most applicable to re-entrant cavities of an Alvarez linac. Some sample results are shown for the first Alvarez's in NUMATRON project. On the other hand the code can also be effectivily applied to TE modes excited in an RFQ linac when the cavity is approximately considered as positioning at an infinite distance from the symmetry axis. The evaluation was made for several RFQ cavities, models I, II and a test linac named LITL, and useful results for the resonator design were obtained. (author)

  12. Cavity-Controlled Chemistry in Molecular Ensembles

    Science.gov (United States)

    Herrera, Felipe; Spano, Frank C.

    2016-06-01

    The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an electronic transition can effectively decouple collective electronic and nuclear degrees of freedom in a disordered molecular ensemble, even for molecules with high-frequency quantum vibrational modes having strong electron-vibration interactions. This type of polaron decoupling can be used to control chemical reactions. We show that the rate of electron transfer reactions in a cavity can be orders of magnitude larger than in free space for a wide class of organic molecular species.

  13. Tooth structure and fracture strength of cavities

    DEFF Research Database (Denmark)

    Mondelli, José; Sene, Fábio; Ramos, Renata Pereira;

    2007-01-01

    This study evaluated, in vitro, the loss of tooth substance after cavity preparation for direct and indirect restorations and its relationship with fracture strength of the prepared teeth. Sixty sound human maxillary first premolars were assigned to 6 groups (n=10). MOD direct composite cavities......) or 1/2 (Groups III and VI) of the intercuspal distance. Teeth were weighed (digital balance accurate to 0.001 g) before and after preparation to record tooth substance mass lost during cavity preparation. The prepared teeth were submitted to occlusal loading to determine their fracture strength using...

  14. Cavity-controlled chemistry in molecular ensembles

    CERN Document Server

    Herrera, Felipe

    2015-01-01

    The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an electronic transition can effectively decouple collective electronic and nuclear degrees of freedom in a disordered molecular ensemble, even for molecules with high-frequency quantum vibrational modes having strong electron-vibration interactions. This type of polaron decoupling can be used to control chemical reactions. We show that the rate of electron transfer reactions in a cavity can be orders of magnitude larger than in free space, for a wide class of organic molecular species.

  15. Micro-Cavity Fluidic Dye Laser

    DEFF Research Database (Denmark)

    Helbo, Bjarne; Kristensen, Anders; Menon, Aric Kumaran

    2003-01-01

    We have successfully designed, fabricated and characterized a micro-cavity fluidic dye laser with metallic mirrors, which can be integrated with polymer based lab-on-a-chip microsystems without further processing steps. A simple rate-equation model is used to predict the average pumping power...... threshold for lasing as function of cavity-mirror reflectance, laser dye concentration and cavity length. The laser device is characterized using the laser dye Rhodamine 6G dissolved in ethanol. Lasing is observed, and the influence of dye concentration is investigated....

  16. Shallow Cavities in Multiple-Planet Systems

    OpenAIRE

    Duffell, Paul C.; Dong, Ruobing

    2014-01-01

    Large cavities are often observed in protoplanetary disks, which might suggest the presence of planets opening gaps in the disk. Multiple planets are necessary to produce a wide cavity in the gas. However, multiple planets may also be a burden to the carving out of very deep gaps. When additional planets are added to the system, the time-dependent perturbations from these additional satellites can stir up gas in the gap, suppressing cavity opening. In this study, we perform two-dimensional nu...

  17. Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    The emission and absorption of photons taking place without changes in the frequency spectrum of the crystal lattice are known as the Moessbauer effect. It takes place in the low energy levels of heavy nuclei in solid lattices at low temperatures. On the basis of the hyperfine structure of Moessbauer spectra the notions are explained of isomer shift, quadrupole splitting and magnetic splitting. The principle and function are explained of Moessbauer spectrometers and the methods of graphical processing of spectra, also the use of the least square fit. Moessbauer spectroscopy is nondestructive, highly sensitive and selective and makes structural resolution possible. It is used for quantitative and qualitative analysis of compounds. Examples are given of the use of this method for mineralogical and crystallo-chemical analysis of lunar minerals and rocks, for analysis of corrosion products of iron and for phase analysis of alloys. (M.D.)

  18. High finesse optical cavity coupled with a quartz-enhanced photoacoustic spectroscopic sensor.

    Science.gov (United States)

    Patimisco, Pietro; Borri, Simone; Galli, Iacopo; Mazzotti, Davide; Giusfredi, Giovanni; Akikusa, Naota; Yamanishi, Masamichi; Scamarcio, Gaetano; De Natale, Paolo; Spagnolo, Vincenzo

    2015-02-01

    An ultra-sensitive and selective quartz-enhanced photoacoustic spectroscopy (QEPAS) combined with a high-finesse cavity sensor platform is proposed as a novel method for trace gas sensing. We call this technique Intra-cavity QEPAS (I-QEPAS). In the proposed scheme, a single-mode continuous wave quantum cascade laser (QCL) is coupled into a bow-tie optical cavity. The cavity is locked to the QCL emission frequency by means of a feedback-locking loop that acts directly on a piezoelectric actuator mounted behind one of the cavity mirrors. A power enhancement factor of ∼240 was achieved, corresponding to an intracavity power of ∼0.72 W. CO2 was selected as the target gas to validate our sensor. For the P(42) CO2 absorption line, located at 2311.105 cm(-1), a minimum detection limit of 300 parts per trillion by volume at a total gas pressure of 50 mbar was achieved with a 20 s integration time. This corresponds to a normalized noise equivalent absorption of 3.2 × 10(-10) W cm(-1) Hz(-1/2), comparable with the best results reported for the QEPAS technique on much faster relaxing gases. A comparison with standard QEPAS performed under the same experimental conditions confirms that the I-QEPAS sensitivity scales with the intracavity laser power enhancement factor. PMID:25465410

  19. Low cost integrating cavity for monitoring of environmental toxins

    Science.gov (United States)

    Bixler, Joel N.; Winkler, Chase A.; Mason, John D.; Yakovlev, Vladislav V.

    2015-03-01

    Contamination of the water source and air pollution are two major problems that must be faced in the coming years. The increasing worldwide contamination of freshwater systems with thousands of industrial and natural chemical compounds is one of the key environmental problems facing humanity today. It is estimated that pathogens in water cause more than 2 million deaths annually. Additionally, traditional water quality assessment methods, such as liquid chromatography and mass spectroscopy, are expensive and time consuming from sample collection to analysis. Low cost tools are needed which can provide high sensitivity in sensing, while remaining portable and providing near real time analysis. Here, we present a low cost integrating cavity that can be used for highly sensitive environmental sensing.

  20. Diagnostics of the ITER neutral beam test facility.

    Science.gov (United States)

    Pasqualotto, R; Serianni, G; Sonato, P; Agostini, M; Brombin, M; Croci, G; Dalla Palma, M; De Muri, M; Gazza, E; Gorini, G; Pomaro, N; Rizzolo, A; Spolaore, M; Zaniol, B

    2012-02-01

    The ITER heating neutral beam (HNB) injector, based on negative ions accelerated at 1 MV, will be tested and optimized in the SPIDER source and MITICA full injector prototypes, using a set of diagnostics not available on the ITER HNB. The RF source, where the H(-)∕D(-) production is enhanced by cesium evaporation, will be monitored with thermocouples, electrostatic probes, optical emission spectroscopy, cavity ring down, and laser absorption spectroscopy. The beam is analyzed by cooling water calorimetry, a short pulse instrumented calorimeter, beam emission spectroscopy, visible tomography, and neutron imaging. Design of the diagnostic systems is presented.

  1. Striped-double cavity fabry-perot interferometers using both glass and air cavities

    Energy Technology Data Exchange (ETDEWEB)

    Perry, S; Steinmetz, L

    1998-07-08

    We have used piezo-driven Fabry-Perot interferometers in the past far many continuous velocity-time measurements of fast moving surfaces. In order to avoid the annoying drift of some of these devices, we have developed and used inexpensive, solid glass, striped etalons with lengths up to 64 mm. Usable apertures are 35 mm by 80 mm with a finess of 25. A roundabout technique was devised for double cavity operation. We built a passive thermal housing for temperature stability, with tilt and height adjustments. We have also developed and used our first fixed etalon air-spaced cavity with a rotatable glass double- cavity insert. The rotation allows the referee cavity fractional order to be adjusted separately from that of the main cavity. It needs very little thermal protection, and eliminates the need for a roundabout scheme for double cavity operation, but is more costly than the solid glass version I

  2. Coupled Photonic Crystal Cavity Array Laser

    DEFF Research Database (Denmark)

    Schubert, Martin

    This thesis describes the design, fabrication and characterization of photonic crystal slab lasers. The main focus is on coupled photonic crystal cavity lasers which are examined in great detail. The cavity type which is mainly explored consists of a defect formed by a single missing hole...... are identified such as the size and material for the carrier wafer in the III-V etch and the importance of removing all remains of the e-beam lithography mask after the etch of the hard mask. Detailed simulations are shown for a simple system with two coupled cavities in different coupling directions....... The results are in good agreement with standard coupled mode theory. Also a novel type of photonic crystal structure is proposed called lambda shifted cavity which is a twodimensional photonic crystal laser analog of a VCSEL laser. Detailed measurements of the coupled modes in the photonic crystals...

  3. Degreasing and cleaning superconducting RF Niobium cavities

    Energy Technology Data Exchange (ETDEWEB)

    Rauchmiller, Michael; Kellett, Ron; /Fermilab

    2011-09-01

    The purpose and scope of this report is to detail the steps necessary for degreasing and cleaning of superconducting RF Niobium cavities in the A0 clean room. It lists the required equipment and the cleaning procedure.

  4. Nb3Sn for Radio Frequency Cavities

    Energy Technology Data Exchange (ETDEWEB)

    Godeke, A.

    2006-12-18

    In this article, the suitability of Nb3Sn to improve theperformance of superconducting Radio-Frequency (RF)cavities is discussed.The use of Nb3Sn in RF cavitiesis recognized as an enabling technology toretain a veryhigh cavity quality factor (Q0) at 4.2 K and tosignificantly improve the cavity accelerating efficiency per unitlength(Eacc). This potential arises through the fundamental properties ofNb3Sn. The properties that are extensively characterized in theliterature are, however, mainly related to improvements in currentcarrying capacity (Jc) in the vortex state. Much less is available forthe Meissner state, which is of key importance to cavities. Relevantdata, available for the Meissner state is summarized, and it is shown howthis already validates the use of Nb3Sn. In addition, missing knowledgeis highlighted and suggestions are given for further Meissner statespecific research.

  5. Plasma Treatment of Niobium SRF Cavity Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    J. Upadhyay, M. Raskovic, L. Vuskovic, S. Popovic, A.-M. Valente-Feliciano, L. Phillips

    2010-05-01

    Plasma based surface modification provides an excellent opportunity to eliminate non- superconductive pollutants in the penetration depth region of the SRF cavity surface and to remove mechanically damaged surface layer improving surface roughness. We have demonstrated on flat samples that plasma etching in Ar / Cl2 of bulk Nb is a viable alternative surface preparation technique to BCP and EP methods, with comparable etching rates. The geometry of SRF cavities made of bulk Nb defines the use of asymmetric RF discharge configuration for plasma etching. In a specially designed single cell cavity with sample holders, discharge parameters are combined with etched surface diagnostics to obtain optimum combination of etching rates, roughness and homogeneity in a variety of discharge types, conditions, and sequences. The optimized experimental conditions will ultimately be applied to single cell SRF cavities.

  6. Malignant melanoma of the oral cavity

    Directory of Open Access Journals (Sweden)

    Ebenezer Jagadish

    2006-01-01

    Full Text Available Oral malignant melanoma is a rare disease. The common sites of its occurrence are the palate and gingiva with the maxillary arch being affected 80% of the time. Because of their presence at relatively obscure areas in the oral cavity, most of the malignant melanomas of the oral cavity are diagnosed at a late stage. These lesions are associated with poor prognosis. The dental clinician must therefore carefully examine the head, neck, and oral cavity, and any pigmented lesion that may exhibit growth potential must be biopsied. This article describes a case of malignant melanoma that was present in the oral cavity and briefly reviews the relevant literature that explains the nature of this lesion.

  7. Working on an LHC superconducting cavity

    CERN Multimedia

    Laurent Guiraud

    2000-01-01

    The delicate superconducting equipment for CERN’s LHC collider has to be assembled in ultra-clean conditions to safeguard performance. Here we see the power supply being installed on one of the superconducting cavities.

  8. On Catastrophe and Cavitation for Spherical Cavity

    Institute of Scientific and Technical Information of China (English)

    MingJIN; KefuHUANG; 等

    1999-01-01

    This work deals with catastrophe of a spherical cavity and cavitation of a spherical cavity for Hooke material with 1/2 Poisson's ratio.A nonlinear problem.which is the Cauchy traction problem,is solved analytically.The governing equations are written on the deformed region or on the present configuration.And the conditions are described on moving boundary.A closed form solution is found.Furthermore,a bifurcation solution in closed form is given from the trivial homogeneous solution of a solid sphere.The results indicate that there is a tangent bifurcation on the displacement-load curve for a sphere with a cavity.On the tangent bifurcation point,the cavity grows up suddenly,which is a kind of catastrophe,And there is a pitchfork bifurcation on the displacement-load curve for a solid sphere.On the pitchfork bifurcation point.there is a cavitation in the solid sphere.

  9. LEP superconducting cavities go into storage

    CERN Multimedia

    Patrice Loïez

    2001-01-01

    Superconducting radio-frequency cavities from the LEP-2 phase (1996-2000) are put into storage in the tunnel that once housed the Intersecting Storage Rings (ISR), the world’s first proton collider, located at CERN.

  10. Photon filters in a microwave cavity

    CERN Document Server

    Larson, J

    2003-01-01

    In an earlier paper we have concluded that time-dependent parameters in atom-mode interaction can be utilized to modify the quantum field in a cavity. When an atom shoots through the cavity field, it is expected to experience a trigonometric time dependence of its coupling constant. We investigate the possibilities this offers to modify the field. As a point of comparison we use the solvable Rosen-Zener model, which has parameter dependencies roughly similar to the ones expected in a real cavity. We do confirm that by repeatedly sending atoms through the cavity, we can obtain filters on the photon states. Highly non-classical states can be obtained. We find that the Rosen-Zener model is more sensitive to the detuning than the case of a trigonometric coupling.

  11. section of an accelerating cavity from LEP

    CERN Multimedia

    This is a section of an accelerating cavity from LEP, cut in half to show the layer of niobium on the inside. Operating at 4.2 degrees above absolute zero, the niobium is superconducting and carries an accelerating field of 6 million volts per metre with negligible losses. Each cavity has a surface of 6 m2. The niobium layer is only 1.2 microns thick, ten times thinner than a hair. Such a large area had never been coated to such a high accuracy. A speck of dust could ruin the performance of the whole cavity so the work had to be done in an extremely clean environment. These challenging requirements pushed European industry to new achievements. 256 of these cavities are now used in LEP to double the energy of the particle beams.

  12. Reducing the convective losses of cavity receivers

    Science.gov (United States)

    Flesch, Robert; Grobbel, Johannes; Stadler, Hannes; Uhlig, Ralf; Hoffschmidt, Bernhard

    2016-05-01

    Convective losses reduce the efficiency of cavity receivers used in solar power towers especially under windy conditions. Therefore, measures should be taken to reduce these losses. In this paper two different measures are analyzed: an air curtain and a partial window which covers one third of the aperture opening. The cavity without modifications and the usage of a partial window were analyzed in a cryogenic wind tunnel at -173°C. The cryogenic environment allows transforming the results from the small model cavity to a large scale receiver with Gr≈3.9.1010. The cavity with the two modifications in the wind tunnel environment was analyzed with a CFD model as well. By comparing the numerical and experimental results the model was validated. Both modifications are capable of reducing the convection losses. In the best case a reduction of about 50 % was achieved.

  13. Wakefield Damping for the CLIC Crab Cavity

    Energy Technology Data Exchange (ETDEWEB)

    Ambattu, P.K.; Burt, G.; Dexter, A.C.; Carter, R.G.; /Cockcroft Inst. Accel. Sci. Tech. /Lancaster U.; Khan, V.; Jones, R.M.; /Cockcroft Inst. Accel. Sci. Tech. /Manchester U.; Dolgashev, V.; /SLAC

    2011-12-01

    A crab cavity is required in the CLIC to allow effective head-on collision of bunches at the IP. A high operating frequency is preferred as the deflection voltage required for a given rotation angle and the RF phase tolerance for a crab cavity are inversely proportional to the operating frequency. The short bunch spacing of the CLIC scheme and the high sensitivity of the crab cavity to dipole kicks demand very high damping of the inter-bunch wakes, the major contributor to the luminosity loss of colliding bunches. This paper investigates the nature of the wakefields in the CLIC crab cavity and the possibility of using various damping schemes to suppress them effectively.

  14. Wakefield damping for the CLIC crab cavity

    CERN Document Server

    Ambattu, P K; Dexter, A C; Carter, R G; Khan, V; Jones, R M; Dolgashev, V

    2009-01-01

    A crab cavity is required in the CLIC to allow effective head-on collision of bunches at the IP. A high operating frequency is preferred as the deflection voltage required for a given rotation angle and the RF phase tolerance for a crab cavity are inversely proportional to the operating frequency. The short bunch spacing of the CLIC scheme and the high sensitivity of the crab cavity to dipole kicks demand very high damping of the inter-bunch wakes, the major contributor to the luminosity loss of colliding bunches. This paper investigates the nature of the wakefields in the CLIC crab cavity and the possibility of using various damping schemes to suppress them effectively.

  15. WAKEFIELD DAMPING FOR THE CLIC CRAB CAVITY

    CERN Document Server

    Ambattu, P; Dexter, A; Carter, R; Khan, V; Jones, R; Dolgashev, V

    2009-01-01

    A crab cavity is required in the CLIC to allow effective head-on collision of bunches at the IP. A high operating frequency is preferred as the deflection voltage required for a given rotation angle and the RF phase tolerance for a crab cavity are inversely proportional to the operating frequency. The short bunch spacing of the CLIC scheme and the high sensitivity of the crab cavity to dipole kicks demand very high damping of the inter-bunch wakes, the major contributor to the luminosity loss of colliding bunches. This paper investigates the nature of the wakefields in the CLIC crab cavity and the possibility of using various damping schemes to suppress them effectively.

  16. Collapse of Non-Axisymmetric Cavities

    OpenAIRE

    Enriquez, Oscar R.; Peters, Ivo R.; Gekle, Stephan; Schmidt, Laura; Versluis, Michel; van der Meer, Devaraj; Lohse, Detlef

    2009-01-01

    A round disk with a harmonic disturbance impacts on a water surface and creates a non-axisymmetric cavity which collapses under the influence of hydrostatic pressure. We use disks deformed with mode m=2 to m=6. For all mode numbers we find clear evidence for a phase inversion of the cavity wall during the collapse. We present a fluid dynamics video showing high speed imaging of different modes, pointing out the characteristic features during collapse.

  17. Resonance control in SRF cavities at FNAL

    Energy Technology Data Exchange (ETDEWEB)

    Schappert, W.; Pischalnikov, Y.; /Fermilab; Scorrano, M.; /INFN, Pisa

    2011-03-01

    The Lorentz force can dynamically detune pulsed Superconducting RF cavities. Considerable additional RF power can be required to maintain the accelerating gradient if no effort is made to compensate for this detuning. Compensation systems using piezo actuators have been used successfully at DESY and elsewhere to control Lorentz Force Detuning (LFD). Recently, Fermilab has developed an adaptive compensation system for cavities in the Horizontal Test Stand, in the SRF Accelerator Test Facility, and for the proposed Project X.

  18. Electrically Pumped Vertical-Cavity Amplifiers

    DEFF Research Database (Denmark)

    Greibe, Tine

    2007-01-01

    In this work, the design of electrically pumped vertical cavity semiconductor optical amplifiers (eVCAs) for use in a mode-locked external-cavity laser has been developed, investigated and analysed. Four different eVCAs, one top-emitting and three bottom emitting structures, have been designed...... and discussed. The thesis concludes with recommendations for further work towards the realisation of compact electrically pumped mode-locked vertical externalcavity surface emitting lasers....

  19. The comet Halley diamagnetic cavity boundary

    Science.gov (United States)

    Cravens, T. E.; Lindgren, C. J.; Puhl, P.

    1995-01-01

    The magnetometer onboard the Giotto spacecraft observed a diamagnetic cavity surrounding the nucleus of comet Halley. A narrow transition layer with enhanced plasma density is formed at this shock-like boundary as a flux of cometary ions flowing into it from within the cavity is removed by electron-ion recombination. We examine the structure of this layer using both a two-dimensional magnetohydrodynamical model and a one- dimensional hybrid code.

  20. LHC Crab Cavity Progress and Outlook

    CERN Document Server

    Calaga, R

    2013-01-01

    Three novel superconducting RF crab cavity designs proposed for the LHC luminosity upgrade have rapidly progressed. First Niobium prototypes are reaching close to the design performance and beyond. The highlights of the RF test results from the prototypes along with design modifications for initial beam tests in the SPS are presented. The status of the cryomodule development, integration into the SPS and the beam tests in view of validating the crab cavity system for LHC upgrade are addressed.

  1. Cavity QED with Multiple Hyperfine Levels

    CERN Document Server

    Birnbaum, K M; Kimble, H J

    2006-01-01

    We calculate the weak-driving transmission of a linearly polarized cavity mode strongly coupled to the D2 transition of a single Cesium atom. Results are relevant to future experiments with microtoroid cavities, where the single-photon Rabi frequency g exceeds the excited-state hyperfine splittings, and photonic bandgap resonators, where g is greater than both the excited- and ground-state splitting.

  2. Cavity QED on a nanofiber using a composite photonic crystal cavity

    CERN Document Server

    Yalla, Ramachandrarao; Nayak, Kali P; Hakuta, Kohzo

    2014-01-01

    We demonstrate cavity QED conditions in the Purcell regime for single quantum emitters on the surface of an optical nanofiber. The cavity is formed by combining an optical nanofiber and a nanofabricated grating to create a composite photonic crystal cavity. Using this technique, significant enhancement of the spontaneous emission rate into the nanofiber guided modes is observed for single quantum dots. Our results pave the way for enhanced on-fiber light-matter interfaces with clear applications to quantum networks.

  3. Cavity quantum electrodynamics on a nanofiber using a composite photonic crystal cavity.

    Science.gov (United States)

    Yalla, Ramachandrarao; Sadgrove, Mark; Nayak, Kali P; Hakuta, Kohzo

    2014-10-01

    We demonstrate cavity QED conditions in the Purcell regime for single quantum emitters on the surface of an optical nanofiber. The cavity is formed by combining an optical nanofiber and a nanofabricated grating to create a composite photonic crystal cavity. By using this technique, significant enhancement of the spontaneous emission rate into the nanofiber guided modes is observed for single quantum dots. Our results pave the way for enhanced on-fiber light-matter interfaces with clear applications to quantum networks.

  4. The emission properties of an atom inside a cavity when manipulating the atoms outside the cavity

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wen; YE Liu; XIONG Kuang-wei; ZHANG Jin

    2003-01-01

    Considering three two-level atoms initially in the GHZ state, then one atom of them is put into an initially empty cavity and made resonant interaction. It is shown that the emission properties of the atom inside the cavity can be affected only when both of the atoms outside the cavity have been manipulated. This conclusion can also be generalized to n two-level atoms.

  5. "Fine grain Nb tube for SRF cavities"

    Energy Technology Data Exchange (ETDEWEB)

    Robert E. Barber

    2012-07-08

    Superconducting radio frequency (SRF) cavities used in charged particle linear accelerators, are currently fabricated by deep drawing niobium sheets and welding the drawn dishes together. The Nb sheet has a non-uniform microstructure, which leads to unpredictable cavity shape and surface roughness, and inconsistent "spring-back" during forming. In addition, weld zones cause hot spots during cavity operation. These factors limit linear accelerator performance and increase cavity manufacturing cost. Equal channel angular extrusion (ECAE) can be used to refine and homogenize the microstructure of Nb tube for subsequent hydroforming into SRF cavities. Careful selection of deformation and heat treatment conditions during the processing steps can give a uniform and consistent microstructure in the tube, leading to improved deformability and lower manufacturing costs. Favorable microstructures were achieved in short test samples of RRR Nb tube, which may be particularly suitable for hydroforming into SRF cavity strings. The approach demonstrated could be applicable to microstructure engineering of other tube materials including tantalum, titanium, and zirconium.

  6. Study of CSR longitudinal bunch compression cavity

    International Nuclear Information System (INIS)

    The scheme of longitudinal bunch compression cavity for the Cooling Storage Ring (CSR)is an important issue. Plasma physics experiments require high density heavy ion beam and short pulsed bunch,which can be produced by non-adiabatic compression of bunch implemented by a fast compression with 90 degree rotation in the longitudinal phase space. The phase space rotation in fast compression is initiated by a fast jump of the RF-voltage amplitude. For this purpose, the CSR longitudinal bunch compression cavity, loaded with FINEMET-FT-1M is studied and simulated with MAFIA code. In this paper, the CSR longitudinal bunch compression cavity is simulated and the initial bunch length of 238U72+ with 250 MeV/u will be compressed from 200 ns to 50 ns.The construction and RF properties of the CSR longitudinal bunch compression cavity are simulated and calculated also with MAFIA code. The operation frequency of the cavity is 1.15 MHz with peak voltage of 80 kV, and the cavity can be used to compress heavy ions in the CSR. (authors)

  7. Beam induced RF cavity transient voltage

    International Nuclear Information System (INIS)

    We calculate the transient voltage induced in a radio frequency (RF) cavity by the injection of a relativistic bunched beam into a circular accelerator. A simplified model of the beam induced voltage, using a single tone current signal, is generated and compared with the voltage induced by a more realistic model of a point-like bunched beam. The high Q limit of the bunched beam model is shown to be related simply to the simplified model. Both models are shown to induce voltages at the resonant frequency ωr of the cavity and at an integer multiple of the bunch revolution frequency (i.e. the accelerating frequency for powered cavity operation) hω0. The presence of two nearby frequencies in the cavity leads to a modulation of the carrier wave exp(jhω0t). A special emphasis is placed in this paper on studying the modulation function. These models prove useful for computing the transient voltage induced in superconducting RF cavities, which was the motivation behind this research. The modulation of the transient cavity voltage discussed in this paper is the physical basis of the recently observed and explained new kind of longitudinal rigid dipole mode which differs from the conventional Robinson mode

  8. Flux expulsion variation in SRF cavities

    CERN Document Server

    Posen, S; Romanenko, A; Melnychuk, O; Sergatskov, D A; Martinello, M; Checchin, M; Crawford, A C

    2015-01-01

    Treating a cavity with nitrogen doping significantly increases $Q_0$ at medium fields, reducing cryogenic costs for high duty factor linear accelerators such as LCLS II. N-doping also makes cavities more sensitive to increased residual resistance due to trapped magnetic flux, making it critical to either have extremely effective magnetic shielding, or to prevent flux from being trapped in the cavity during cooldown. In this paper, we report on results of a study of flux expulsion. We discuss possible ways in which flux can be pinned in the inner surface, outer surface, or bulk of a cavity, and we present experimental results studying these mechanisms. We show that grain structure appears to play a key role and that a cavity that expelled flux poorly changed to expelling flux well after a high temperature furnace treatment. We further show that after furnace treatment, this cavity exhibited a significant improvement in quality factor when cooled in an external magnetic field. We conclude with implications for ...

  9. Cavity Mode Frequencies and Large Optomechanical Coupling in Two-Membrane Cavity Optomechanics

    CERN Document Server

    Li, J; Malossi, N; Vitali, D

    2015-01-01

    We study the cavity mode frequencies of a Fabry-Perot cavity containing two vibrating dielectric membranes and the corresponding optomechanical coupling. Due to optical interference, extremely large optomechanical coupling of the membrane relative motion is achieved when the two membranes are placed very close to a resonance of the inner cavity formed by the two membranes, and in the limit of highly reflective membranes. The upper bound of the coupling strength is given by the optomechanical coupling associated with the much shorter inner cavity, consistently with the analysis of A. Xuereb et al., Phys. Rev. Lett. 109, 223601 (2012).

  10. Vector cavity solitons in broad area Vertical-Cavity Surface-Emitting Lasers.

    Science.gov (United States)

    Averlant, Etienne; Tlidi, Mustapha; Thienpont, Hugo; Ackemann, Thorsten; Panajotov, Krassimir

    2016-01-01

    We report the experimental observation of two-dimensional vector cavity solitons in a Vertical-Cavity Surface-Emitting Laser (VCSEL) under linearly polarized optical injection when varying optical injection linear polarization direction. The polarization of the cavity soliton is not the one of the optical injection as it acquires a distinct ellipticity. These experimental results are qualitatively reproduced by the spin-flip VCSEL model. Our findings open the road to polarization multiplexing when using cavity solitons in broad-area lasers as pixels in information technology. PMID:26847004

  11. Planetary spectroscopy

    International Nuclear Information System (INIS)

    The main goal of the research is charge coupled device (CCD) spectroscopic and imaging studies of the solar system in support of spacecraft investigations. Studies include the physical behavior of comets, the atmosphere of the gaseous planets, and the solid surfaces of satellites and asteroids. The major observing program consisted of approximately 50 nights of photometry of Comet Halley in order to resolve the controversy over this comet's rotation period. This data is presently being analyzed. Additional observing projects included the spectroscopic occultation of Charon by Pluto, reflection spectroscopy of Mercury, and a spectrum of the satellite Oberon. Mercury data does not corroborate the Fe(++) absorption feature reported by McCord and Clark at 8800 A but instead potentially shows a weaker feature at longer wavelengths. This position is in much closer accord with expectations for Mercury since a band center near 8800 A implies too little Fe(++) on Mercury, especially if band shifts with temperature are considered. The Pluto project proved that the deep methane absorptions visible in their combined specta are due soley to Pluto with Charon showing a flat and featureless spectrum. It appears that if Charon ever contained a substantial methane component, the satellite's low surface gravity could not hold it and the methane evaporated and escaped

  12. MHD Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Heeter, R F; Fasoli, A; Testa, D; Sharapov, S; Berk, H L; Breizman, B; Gondhalekar, A; Mantsinen, M

    2004-03-23

    Experiments are conducted on the JET tokamak to assess the diagnostic potential of MHD active and passive spectroscopy, for the plasma bulk and its suprathermal components, using Alfv{acute e}n Eigenmodes (AEs) excited by external antennas and by energetic particles. The measurements of AE frequencies and mode numbers give information on the bulk plasma. Improved equilibrium reconstruction, in particular in terms of radial profiles of density and safety factor, is possible from the comparison between the antenna driven spectrum and that calculated theoretically. Details of the time evolution of the non-monotonic safety factor profile in advanced scenarios can be reconstructed from the frequency of ICRH-driven energetic particle modes. The plasma effective mass can be inferred from the resonant frequency of externally driven AEs in discharges with similar equilibrium profiles. The stability thresholds and the nonlinear development of the instabilities can give clues on energy and spatial distribution of the fast particle population. The presence of unstable AEs provides lower limits in the energy of ICRH generated fast ion tails. Fast ion pressure gradients and their evolution can be inferred from the stability of AEs at different plasma radial positions. Finally, the details of the AE spectrum in the nonlinear stage can be used to obtain information about the fast particle velocity space diffusion.

  13. IMRT in oral cavity cancer

    International Nuclear Information System (INIS)

    Except for early T1,2 N0 stages, the prognosis for patients with oral cavity cancer (OCC) is reported to be worse than for carcinoma in other sites of the head and neck (HNC). The aim of this work was to assess disease outcome in OCC following IMRT. Between January 2002 and January 2007, 346 HNC patients have been treated with curative intensity modulated radiation therapy (IMRT) at the Department of Radiation Oncology, University Hospital Zurich. Fifty eight of these (16%) were referred for postoperative (28) or definitive (30) radiation therapy of OCC. 40 of the 58 OCC patients (69%) presented with locally advanced T3/4 or recurred lesions. Doses between 60 and 70 Gy were applied, combined with simultaneous cisplatin based chemotherapy in 78%. Outcome analyses were performed using Kaplan Meier curves. In addition, comparisons were performed between this IMRT OCC cohort and historic in-house cohorts of 33 conventionally irradiated (3DCRT) and 30 surgery only patients treated over the last 10 years. OCC patients treated with postoperative IMRT showed the highest local control (LC) rate of all assessed treatment sequence subgroups (92% LC at 2 years). Historic postoperative 3DCRT patients and patients treated with surgery alone reached LC rates of ~70–80%. Definitively irradiated patients revealed poorest LC rates with ~30 and 40% following 3DCRT and IMRT, respectively. T1 stage resulted in an expectedly significantly higher LC rate (95%, n = 19, p < 0.05) than T2-4 and recurred stages (LC ~50–60%, n = 102). Analyses according to the diagnosis revealed significantly lower LC in OCC following definitive IMRT than that in pharyngeal tumors treated with definitive IMRT in the same time period (43% vs 82% at 2 years, p < 0.0001), while the LC rate of OCC following postoperative IMRT was as high as in pharyngeal tumors treated with postoperative IMRT (>90% at 2 years). Postoperative IMRT of OCC resulted in the highest local control rate of the assessed treatment

  14. Teleportation of a Weak Coherent Cavity Field State

    Science.gov (United States)

    Cardoso, Wesley B.; Qiang, Wen-Chao; Avelar, Ardiley T.

    2016-07-01

    In this paper we propose a scheme to teleport a weak coherent cavity field state. The scheme relies on the resonant atom-field interaction inside a high-Q cavity. The mean photon-number of the cavity field is assumed much smaller than one, hence the field decay inside the cavity can be effectively suppressed.

  15. Cavity polaritons in an organic single-crystalline rubrene microcavity

    Science.gov (United States)

    Tsuchimoto, Yuta; Nagai, Hikaru; Amano, Masamitsu; Bando, Kazuki; Kondo, Hisao

    2014-06-01

    We fabricated a single-crystalline rubrene microcavity using a simple solution technique and observed cavity polaritons in the microcavity at room temperature (RT). Large Rabi splitting energies were obtained from dispersion of the cavity polaritons. Furthermore, photoluminescence from the cavity polaritons was observed at RT. The findings will be of importance for the application of cavity polaritons.

  16. Compound parabolic concentrator with cavity for tubular absorbers

    Science.gov (United States)

    Winston, Roland

    1983-01-01

    A compond parabolic concentrator with a V-shaped cavity is provided in which an optical receiver is emplaced. The cavity redirects all energy entering between the receiver and the cavity structure onto the receiver, if the optical receiver is emplaced a distance from the cavity not greater than 0.27 r (where r is the radius of the receiver).

  17. Teleportation of atomic states with a weak coherent cavity field

    Institute of Scientific and Technical Information of China (English)

    Zheng Shi-Biao

    2005-01-01

    A scheme is proposed for the teleportation of an unknown atomic state. The scheme is based on the resonant interaction of atoms with a coherent cavity field. The mean photon-number of the cavity field is much smaller than one and thus the cavity decay can be effectively suppressed. Another adwntage of the scheme is that only one cavity is required.

  18. Scheme for implementing quantum secret sharing via cavity QED

    Institute of Scientific and Technical Information of China (English)

    Chen Zhi-Hua; Lin Xiu-Min

    2005-01-01

    An experimentally feasible scheme for implementing quantum secret sharing via cavity quantum electrodynamics (QED) is proposed. The scheme requires the large detuning of the cavity field from the atomic transition, the cavity is only virtually excited, thus the requirement on the quality factor of the cavity is greatly loosened.

  19. Control of ring lasers by means of coupled cavities

    DEFF Research Database (Denmark)

    Abitan, Haim; Andersen, Ulrik Lund; Skettrup, Torben;

    2000-01-01

    Summary form only. Coupling of optical cavities offers a means of controlling the properties of one cavity (e.g. a laser) by making adjustments to another, external cavity. In this contribution we consider a unidirectional ring laser (bow-tie laser) coupled to an external ring cavity. Using...

  20. Soliton laser: A computational two-cavity model

    DEFF Research Database (Denmark)

    Berg, P.; If, F.; Christiansen, Peter Leth;

    1987-01-01

    An improved computational two-cavity model of the soliton laser proposed and designed by Mollenauer and Stolen [Opt. Lett. 9, 13 (1984)] is obtained through refinements of (i) the laser cavity model, (ii) the pulse propagation in the fiber cavity, and (iii) the coupling between the two cavities. As...