WorldWideScience

Sample records for caustics

  1. [Caustic ingestions].

    Science.gov (United States)

    Adukauskiene, Dalia; Mazeikiene, Sandra; Rumba, Arvydas; Vizgirdaite, Venta

    2009-01-01

    Caustic ingestions (alkalis, acids) may cause severe chemical burns and lifelong complications, which worsen life quality. Approximately 80% of caustic ingestions occur in children. They mostly intoxicate because of chemical substances kept insecurely or in inappropriate containers. Until now, there is no general opinion about diagnostics and management of caustic ingestions. Therefore, the main aim of this article is accurately represent diagnostic and treatment options believing that this information would help physicians to diagnose caustic ingestions easier and faster, to provide emergency management correctly, and to avoid acute and chronic complications.

  2. Caustics for Spherical Waves

    CERN Document Server

    de Rham, Claudia

    2016-01-01

    We study the development of caustics in shift-symmetric scalar field theories by focusing on simple waves with an $SO(p)$-symmetry in an arbitrary number of space dimensions. We show that the Galileon and the DBI-Galileon naturally emerge as the unique set of caustic-free theories, highlighting a link between the caustic-free condition for simple $SO(p)$-waves and the existence of either a global galilean symmetry or a global relativistic galilean symmetry.

  3. Space-time caustics

    Directory of Open Access Journals (Sweden)

    Arthur D. Gorman

    1986-01-01

    Full Text Available The Lagrange manifold (WKB formalism enables the determination of the asymptotic series solution of linear differential equations modelling wave propagation in spatially inhomogeneous media at caustic (turning points. Here the formalism is adapted to determine a class of asymptotic solutions at caustic points for those equations modelling wave propagation in media with both spatial and temporal inhomogeneities. The analogous Schrodinger equation is also considered.

  4. Caustics in dark matter haloes

    CERN Document Server

    Mohayaee, R; Mohayaee, Roya; Colombi, Stephane; Fort, Bernard; Gavazzi, Raphael; Shandarin, Sergei; Touma, Jihad

    2005-01-01

    Cold dark matter haloes are populated by high-density structures with sharply-peaked profiles known as caustics which have not yet been resolved by 3-dimensional numerical simulations. Here, we derive semi-analytic expressions for the density profiles near caustics in haloes which form by self-similar accretions of dark matter with infinitesimal velocity dispersion. A simple rescaling shows that these profiles are universal: they are valid for all caustics and irrespective of physical parameters of the halo. We derive the maximum density of the caustics and show that it depends on the velocity dispersion and the caustic location. Finally, we demonstrate that there can be a significant contribution to the emission measure from dark matter particle annihilation in the caustics.

  5. Causticizing for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  6. In-situ caustic generation from sewage: the impact of caustic strength and sewage composition.

    Science.gov (United States)

    Pikaar, Ilje; Rozendal, René A; Rabaey, Korneel; Yuan, Zhiguo

    2013-10-01

    Periodic caustic dosage is a commonly used method by the water industry to elevate pH levels and deactivate sewer biofilms responsible for hydrogen sulfide generation. Caustic (NaOH) can be generated in-situ from sewage using a divided electrochemical cell, which avoids the need for transport, handling and storage of concentrated caustic solutions. In this study, we investigated the impact of caustic strength in the cathode compartment and the impact of sodium concentration in sewage on the Coulombic efficiency (CE) for caustic generation. The CE was found to be independent of the caustic strength produced in the range of up to ~3 wt%. Results showed that a caustic solution of ~3 wt% could be produced directly from sewage at a CE of up to 75 ± 0.5%. The sodium concentration in sewage had a significant impact on the CE for caustic generation as well as on the energy requirements of the system, with a higher sodium concentration leading to a higher CE and lower energy consumption. The proton, calcium, magnesium and ammonium concentrations in sewage affected the CE for caustic generation, especially at low sodium concentrations. Economical assessment based on the experimental results indicated that sulfide control in sewers using electrochemically-generated caustic from sewage is an economically attractive strategy.

  7. 27 CFR 21.102 - Caustic soda, liquid.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Caustic soda, liquid. 21....102 Caustic soda, liquid. (a) The liquid caustic soda may consist of either 50 percent or 73 percent by weight sodium hydroxide in aqueous solution. The amount of caustic soda used shall be such...

  8. Caustic ingestion and esophageal function

    Energy Technology Data Exchange (ETDEWEB)

    Cadranel, S.; Di Lorenzo, C.; Rodesch, P.; Piepsz, A.; Ham, H.R. (Children University Hospital, Brussels (Belgium))

    1990-02-01

    The aim of the present study was to investigate esophageal motor function by means of krypton-81m esophageal transit scintigraphy and to compare the results with the functional and morphological data obtained by means of triple lumen manometry and endoscopy. In acute and subacute stages of the disease, all clinical, anatomical, and functional parameters were in good agreement, revealing significant impairment. In chronic stages, the severity of the dysphagia was not correlated to the importance of the residual stenosis. Conversely, 81mKr esophageal transit and manometric's findings were in good agreement with the clinical symptoms, during the entire follow-up period ranging between 3 months to 7 years. The 81mKr test is undoubtedly the easiest and probably the most physiological technique currently available for long-term functional evaluation of caustic esophagitis.

  9. Caustic Soda Will Be Oversupply in 2007

    Institute of Scientific and Technical Information of China (English)

    Yao Liqin

    2007-01-01

    @@ Rapid output increase There are more than 220 caustic soda producers in China today. At the end of 2006 the capacity of caustic soda in China was 17.61 million t/a. The output of caustic soda was 15.118 million tons in 2006, an increase of 19.0% over 2005 and 1.331 million tons were exported, an increase of 55.8%. Production increased fastest in Northwest China, with growth 51.9% faster than 2005. The output in East China grew 22.9% and 22.3% in Southwest China, both higher than the national average level.

  10. Caustic graphene plasmons with Kelvin angle

    CERN Document Server

    Shi, Xihang; Gao, Fei; Xu, Hongyi; Yang, Zhaoju; Zhang, Baile

    2015-01-01

    A century-long argument made by Lord Kelvin that all swimming objects have an effective Mach number of 3, corresponding to the Kelvin angle of 19.5 degree for ship waves, has been recently challenged with the conclusion that the Kelvin angle should gradually transit to the Mach angle as the ship velocity increases. Here we show that a similar phenomenon can happen for graphene plasmons. By analyzing the caustic wave pattern of graphene plasmons stimulated by a swift charged particle moving uniformly above graphene, we show that at low velocities of the charged particle, the caustics of graphene plasmons form the Kelvin angle. At large velocities of the particle, the caustics disappear and the effective semi-angle of the wave pattern approaches the Mach angle. Our study introduces caustic wave theory to the field of graphene plasmonics, and reveals a novel physical picture of graphene plasmon excitation during electron energy-loss spectroscopy measurement.

  11. Tunable caustic phenomena in electron wavefields

    Energy Technology Data Exchange (ETDEWEB)

    Tavabi, Amir Hossein, E-mail: a.tavabi@fz-juelich.de [Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons (ER-C) and Peter Grünberg Institute (PGI), Forschungszentrum Jülich, D-52425 Jülich (Germany); Migunov, Vadim; Dwyer, Christian; Dunin-Borkowski, Rafal E. [Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons (ER-C) and Peter Grünberg Institute (PGI), Forschungszentrum Jülich, D-52425 Jülich (Germany); Pozzi, Giulio [Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons (ER-C) and Peter Grünberg Institute (PGI), Forschungszentrum Jülich, D-52425 Jülich (Germany); Department of Physics and Astronomy, University of Bologna, Viale B. Pichat 6/2, 40127 Bologna (Italy)

    2015-10-15

    Novel caustic phenomena, which contain fold, butterfly and elliptic umbilic catastrophes, are observed in defocused images of two approximately collinear oppositely biased metallic tips in a transmission electron microscope. The observed patterns depend sensitively on defocus, on the applied voltage between the tips and on their separation and lateral offset. Their main features are interpreted on the basis of a projected electrostatic potential model for the electron-optical phase shift. - Highlights: • Electron-optical caustics are observed in defocused images of biased metallic tips. • The caustics depend on defocus, on the bias between the tips and on their separation. • The setup offers the flexibility to study a wide variety of caustic phenomena.

  12. Pigging ends freezeups in caustic piping system

    Energy Technology Data Exchange (ETDEWEB)

    Gros, R.; Gaines, A.

    1985-03-01

    Convent Chemical Corporation in Convent, LA produces and ships bulk quantities of chlorine and caustic soda (NaOH). The caustic soda is available in various grades, including a 50% aqueous solution that freezes at 56/sup 0/F. An extensive network of chemical-resistant polypropylene-lined steel pipe (without heat tracing) is used to transfer the caustic soda from the production area to storage tanks and to the loading facilities for tank trucks, rail tank cars and barges. A sudden drop in ambient temperature can cause freezeup of the caustic transfer pipes which may result in downtime of as much as a week. Convent plant engineers designed a pigging system for the outdoor caustic transfer lines in the tank farm and to the loading stations. The patented design pig, (internal pipeline cleaner) consists of a flexible, bullet-shaped cylinder of chemical-resistant polyurethane foam with strips of urethane rubber on the surface, or with a solid coating of the tough material. Fluid or gas pressure on the sealed concave base propels the flexible pig through the pipe, valves, elbows, and other fittings, and material ahead of the pig is discharged into an appropriate receiver. The pigging system has eliminated the caustic freezing and plugging problems since it was installed in the summer of 1981. The flexible pig, propelled by 80 psi air, is used to clear the pipelines whenever caustic is transferred during the winter months. The air-propelled pig is designed and sized to easily pass through restrictions in the piping system, such as reduced port plug valves, but was once stuck when it reached a section of pipe that had collapsed. A pig containing the Cobalt 60 nuclear element was inserted into the line to quickly locate the stuck pig with the Geiger counter. The faulty section of pipe was replaced with a new polypropylene lined spool piece.

  13. Probing dark matter caustics with weak lensing

    CERN Document Server

    Gavazzi, R; Fort, B; Gavazzi, Raphael; Mohayaee, Roya; Fort, Bernard

    2006-01-01

    Caustics are high-density structures that form frequently in collisionless media. Under self-gravity, cold dark matter flows focus onto caustics which are yet to be resolved in numerical simulations and or observed in the real world. If detected, caustics would provide a strong evidence for dark matter and would rule out alternative models such as those with modified dynamics. Here, we demonstrate how they might be observed in the weak lensing data. We evaluate the shear distortion and show that its radial profile is marked by a characteristic sawtooth pattern due to the caustics in dark matter haloes that form by selfsimilar accretion. We discuss the observational complications, mainly due to the poor knowledge of the virial radii of the haloes and demonstrate that a superposition of about 600 cluster-size haloes would give a signal-to-noise ratio which is sufficiently large for the detection of caustics with ground-based observations. This number is reduced to 200 for space-based observations. These bounds ...

  14. Line Caustic Microlensing and Limb Darkening

    CERN Document Server

    Rhie, S H; Rhie, Sun Hong; Bennett, David P.

    1999-01-01

    In a line caustic crossing microlensing event, the caustic line moving across the surface of the source star provides a direct method to measure the integrated luminosity profile of the star. Combined with the enormous brightening at the caustic crossings, microlensing offers a promising tool for studying stellar luminosity profiles. We derive the amplification behavior of the two extra images that become partial images conjoined across the critical curve at a line caustic crossing. We identify the multiplicative factors that depend on the caustic crossing point and the relative size of the star, and the shape function that depends on the stellar luminosity profile. We examine the analytic limb-darkening models -- linear, square root, and square -- using the analytic form of the shape function. We find that the microlensing lightcurves must be determined to an accuracy of better than 0.3-0.8% in order to be able to determine the linear limb-darkening parameter $c_1$ with precision of binaries as reported by P...

  15. Interaction of aqueous caustic with acidic oils

    Energy Technology Data Exchange (ETDEWEB)

    Chiwetelu, C.I.; Hornof, V.; Neale, G.H. (Univ. of Ottawa, Ottawa, ON (Canada))

    High content of native carboxylic acids make heavy oils acidic. It is generally accepted that these acids react with caustic reagents present in floodwater, resulting in the in-situ formation of surface active soap anions. When these adsorb at the oil-water interface, they can drastically lower the interfacial tension to the point where residual oil is mobilized. The most intriguing aspect of these acid/caustic interactions is the dynamic nature of the interfacial tension. Given a sufficiently long time, the dynamic tension would attain an equilibrium state. Measurements were made of the equilibrium interfacial tensions of acidified oleic phases contacted with a wide range of caustic concentrations in the aqueous phase. A novel measurement technique (photomicropendography) was used, and data analysis was carried out by nonlinear regression. The present approach utilizes pre-selected fatty acids in a defined oleic phase, enabling quantification of relevant model parameters and facilitating evaluation of key variables influencing interfacial activity. The acid ionization constant and the equilibrium constant governing the formation of inactive soap species were found to be the most important parameters for systems of oleic and lauric acids dissolved in hexadecane. Regression analysis showed that the acid dissociation constant (pKa) of oleic acid ranged from 6.2 to 6.9 and was dependent on the working acid concentration. For lauric acid, the pKa values were in the range of 9 to 11 depending on the caustic concentration of the aqueous phase. Species aggregation in both the oleic and aqueous phases is mostly responsible for the variations in pKa values. 30 refs., 10 figs., 4 tabs.

  16. In Situ Causticizing for Black Liquor Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Scott Alan Sinquefield

    2005-10-01

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  17. Caustics and Caustic-Diffraction in Laser Shadowgraphy of a Sessile Drop and Identification of Profile Near Contact Line

    Science.gov (United States)

    Zhang, Neng-Li; Chao, David F.

    2003-01-01

    This paper presents an optical method based on the caustics and caustic-difraction in laser shadowgaphy of a sessile drop to identify and estimate the drop profile near the contact line. A parallel laser beam passes through a liquid sessile drop placed on a transparent substrate to produce a shadowgraphic image of the drop on the screen far from the substrate. Along the inflection line of the drop the Gaussian curvature of the wavefront deformed by the drop vanishes, and therefore the inflection line gives caustics in the far field of the wave, which can be seen on the screen. The neighboring light rays at both sides of the inflection line interfere with each other to form interference fringes at the inner side of the caustics. According to the pattern of the caustics, the drop-profile shape can be identified and estimated.

  18. Preconceptual Design Description for Caustic Recycle Facility

    Energy Technology Data Exchange (ETDEWEB)

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.; Kurath, Dean E.

    2008-04-12

    The U.S. Department of Energy plans to vitrify both high-level and low-activity waste at the Hanford Site in southeastern Washington State. One aspect of the planning includes a need for a caustic recycle process to separate sodium hydroxide for recycle. Sodium is already a major limitation to the waste-oxide loading in the low-activity waste glass to be vitrified at the Waste Treatment Plant, and additional sodium hydroxide will be added to remove aluminum and to control precipitation in the process equipment. Aluminum is being removed from the high level sludge to reduce the number of high level waste canisters produced. A sodium recycle process would reduce the volume of low-activity waste glass produced and minimize the need to purchase new sodium hydroxide, so there is a renewed interest in investigating sodium recycle. This document describes an electrochemical facility for recycling sodium for the WTP.

  19. Caustic ingestion-a forensic overview.

    Science.gov (United States)

    Byard, Roger W

    2015-05-01

    The ingestion of corrosive substances may produce severe burns to the upper aerodigestive tract and stomach, particularly if the pH is greater than 12 or less than two. There is a biphasic age grouping with adult cases most often involving self-harm and pediatric cases accidental ingestion. Three cases are reported to demonstrate characteristic features following the ingestion of potassium hydroxide, glacial acetic acid and Lysol(®) , respectively. All deaths were due to the effects of caustic burns to the upper aerodigestive tract, esophagus and stomach with perforation and/or hemorrhage. The extent of injuries in these cases depends on the nature, amount, and concentration of the agent and on the exposure time. A point to note at autopsy is that tissue damage may also occur from postmortem exposure. Typical injuries involve perioral, limb, and trunk burns, with extensive aerodigestive liquefactive/coagulative necrosis causing hemorrhage and perforation.

  20. Photon Differential Splatting for Rendering Caustics

    DEFF Research Database (Denmark)

    Frisvad, Jeppe Revall; Schjøth, Lars; Erleben, Kenny;

    2014-01-01

    We present a photon splatting technique which reduces noise and blur in the rendering of caustics. Blurring of illumination edges is an inherent problem in photon splatting, as each photon is unaware of its neighbours when being splatted. This means that the splat size is usually based...... on heuristics rather than knowledge of the local flux density. We use photon differentials to determine the size and shape of the splats such that we achieve adaptive anisotropic flux density estimation in photon splatting. As compared to previous work that uses photon differentials, we present the first method...... where no photons or beams or differentials need to be stored in a map. We also present improvements in the theory of photon differentials, which give more accurate results and a faster implementation. Our technique has good potential for GPU acceleration, and we limit the number of parameters requiring...

  1. Formation of caustics in k-essence and Horndeski theory

    CERN Document Server

    Babichev, Eugeny

    2016-01-01

    We study propagation of waves and appearance of caustics in k-essence and galileon theories. First we show that previously known solutions for travelling waves in k-essence and galileon models correspond to very specific fine-tuned initial conditions. On the contrary, as we demonstrate by the method of characteristics, a generic wave in k-essence ends up with formation of caustics. Finally, we find that any wave solution in pure k-essence is also a solution for a galileon theory with the same k-essence term. Thus in the Horndeski theory formation of caustics is generic. We discuss physical consequences of the caustics formation and possible ways to cure the problem.

  2. Tracking nanoparticles in an optical microscope using caustics

    Energy Technology Data Exchange (ETDEWEB)

    Patterson, Eann A [Department of Mechanical Engineering, Michigan State University, East Lansing, MI 48824 (United States); Whelan, Maurice P [Nanotechnology and Molecular Imaging Unit, Institute for Health and Consumer Protection, European Commission DG Joint Research Center, 21021 Ispra (Vatican City State, Holy See,) (Italy)

    2008-03-12

    An elegant method is proposed and demonstrated for tracking the location and movement of nanoparticles in an optical microscope using the optical phenomenon of caustics. A simple and reversible adjustment to the microscope generates caustics several orders of magnitude larger than the particles. The method offers a simple and relatively inexpensive method for visualizing such phenomena as the formation of self-assembled monolayers and the interaction of nanoparticles with chemically functionalized surfaces.

  3. Test report - 241-AN-274 Caustic Pump Control Building

    Energy Technology Data Exchange (ETDEWEB)

    Paintner, G.P.

    1995-05-01

    This Acceptance Test Report documents the test results of test procedure WHC-SD-WM-ATP-135 `Acceptance Test Procedure for the 241-AN- 274 Caustic Pump Control Building.` The objective of the test was to verify that the 241-AN-274 Caustic Pump Control Building functions properly based on design specifications per applicable H-2-85573 drawings and associated ECN`s. The objective of the test was met.

  4. Engineering wavefront caustics trajectories in ${\\cal PT}$-symmetric lattices

    CERN Document Server

    Bender, Nicholas; Kottos, Tsampikos

    2015-01-01

    We utilize caustic theory in ${\\cal PT}-$symmetric lattices to design focusing and curved beam dynamics. We show that the gain and loss parameter in these systems provides an addition degree of freedom which allows for the design of the same caustics trajectories with different intensity distribution in the individual waveguides. Moreover we can create aberration-free focal points at any paraxial distance $z_f$, with anomalously large focal intensity.

  5. Illuminating Hot Jupiters in caustic crossing

    CERN Document Server

    Sajadian, Sedighe

    2010-01-01

    In recent years a large number of Hot Jupiters orbiting in a very close orbit around the parent stars have been explored with the transit and doppler effect methods. Here in this work we study the gravitational microlensing effect of a binary lens on a parent star with a Hot Jupiter revolving around it. Caustic crossing of the planet makes enhancements on the light curve of the parent star in which the signature of the planet can be detected by high precision photometric observations. We use the inverse ray shooting method with tree code algorithm to generate the combined light curve of the parent star and the planet. In order to investigate the probability of observing the planet signal, we do a Monte-Carlo simulation and obtain the observational optical depth of $\\tau \\sim 10^{-8}$. We show that about ten years observations of Galactic Bulge with a network of telescopes will enable us detecting about ten Hot Jupiter with this method. Finally we show that the observation of the microlensing event in infra-re...

  6. Critical Curves and Caustics of Triple-lens Models

    Science.gov (United States)

    Daněk, Kamil; Heyrovský, David

    2015-06-01

    Among the 25 planetary systems detected up to now by gravitational microlensing, there are two cases of a star with two planets, and two cases of a binary star with a planet. Other, yet undetected types of triple lenses include triple stars or stars with a planet with a moon. The analysis and interpretation of such events is hindered by the lack of understanding of essential characteristics of triple lenses, such as their critical curves and caustics. We present here analytical and numerical methods for mapping the critical-curve topology and caustic cusp number in the parameter space of n-point-mass lenses. We apply the methods to the analysis of four symmetric triple-lens models, and obtain altogether 9 different critical-curve topologies and 32 caustic structures. While these results include various generic types, they represent just a subset of all possible triple-lens critical curves and caustics. Using the analyzed models, we demonstrate interesting features of triple lenses that do not occur in two-point-mass lenses. We show an example of a lens that cannot be described by the Chang-Refsdal model in the wide limit. In the close limit we demonstrate unusual structures of primary and secondary caustic loops, and explain the conditions for their occurrence. In the planetary limit we find that the presence of a planet may lead to a whole sequence of additional caustic metamorphoses. We show that a pair of planets may change the structure of the primary caustic even when placed far from their resonant position at the Einstein radius.

  7. Wavefronts and caustic associated with Durnin’s beams

    Science.gov (United States)

    de Jesús Cabrera-Rosas, Omar; Espíndola-Ramos, Ernesto; Alejandro Juárez-Reyes, Salvador; Julián-Macías, Israel; Ortega-Vidals, Paula; Silva-Ortigoza, Gilberto; Silva-Ortigoza, Ramón; Sosa-Sánchez, Citlalli Teresa

    2017-01-01

    The aim of the present work is to give a geometrical characterization of Durnin’s beams. That is, we compute the wavefronts and caustic associated with the nondiffracting solutions to the scalar wave equation introduced by Durnin. To this end, first we show that in an isotropic optical medium \\psi ({r},t)={{{e}}}{{i}[{k}0S({r})-ω t]} is an exact solution of the wave equation, if and only if, S is a solution of both the eikonal and Laplace equations, then from one and two-parameter families of this type of solution and the superposition principle we define new solutions of the wave equation, in particular we show that the ideal nondiffracting beams are one example of this type of construction in free space. Using this fact, the wavefronts and caustic associated with those beams are computed. We find that their caustic has only one branch, which is invariant under translations along the direction of evolution of the beam. Finally, the Bessel beam of order m is worked out explicitly and we find that it is characterized by wavefronts that are deformations of conical ones and the caustic is an infinite cylinder of radius proportional to m. In the case m = 0, the wavefronts are cones and the caustic degenerates into an infinite line.

  8. Effect of asphericity in caustic mass estimates of galaxy clusters

    CERN Document Server

    Svensmark, Jacob; Hansen, Steen H

    2014-01-01

    The caustic technique of mass estimation of galaxy clusters relies on the assumption of spherical symmetry, which is not always a valid assumption. Here we demonstrate the effect of spatial anisotropy of galaxy clusters on the inferred caustic mass profiles by considering particle data from dark matter N-body simulations. We find a factor of ~3 discrepancy between major and minor axis mass estimates in ellipsoidal clusters within the virial radius Rv, and up to ~5 within 3 Rv. We also find filaments to influence caustic mass estimates at a comparable magnitude. By stacking halos to align their principal axes we find that a line of sight along the major axis overestimates the caustic mass of galaxy clusters, as well as a line of sight along the minor axis underestimates it. The mass discrepancy between the major and minor axis is a factor of 2.47, 2.97 and 3.95 at 1, 2 and 3 Rv for virial masses Mv = [1,2] x 10^{14} Msun/h, and $(30-35)\\%$ larger for Mv > 2 x 10^{14} Msun/h. Furthermore, the caustic mass is ov...

  9. Caustics and Rogue Waves in an Optical Sea

    CERN Document Server

    Mathis, Amaury; Toenger, Shanti; Dias, Frederic; Genty, Goery; Dudley, John M

    2015-01-01

    There are many examples in physics of systems showing rogue wave behaviour, the generation of high amplitude events at low probability. Although initially studied in oceanography, rogue waves have now been seen in many other domains, with particular recent interest in optics. Although most studies in optics have focussed on how nonlinearity can drive rogue wave emergence, purely linear effects have also been shown to induce extreme wave amplitudes. In this paper, we report a detailed experimental study of linear rogue waves in an optical system, using a spatial light modulator to impose random phase structure on a coherent optical field. After free space propagation, different random intensity patterns are generated, including partially-developed speckle, a broadband caustic network, and an intermediate pattern with characteristics of both speckle and caustic structures. Intensity peaks satisfying statistical criteria for rogue waves are seen especially in the case of the caustic network, and are associated w...

  10. Wavefield extrapolation in caustic-free normal ray coordinates

    KAUST Repository

    Ma, Xuxin

    2012-11-04

    Normal ray coordinates are conventionally constructed from ray tracing, which inherently requires smooth velocity profiles. To use rays as coordinates, the velocities have to be smoothed further to avoid caustics, which is detrimental to the mapping process. Solving the eikonal equation numerically for a line source at the surface provides a platform to map normal rays in complex unsmoothed velocity models and avoid caustics. We implement reverse-time migration (RTM) and downward continuation in the new ray coordinate system, which allows us to obtain efficient images and avoid some of the dip limitations of downward continuation.

  11. 21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing...

  12. Electrochemical generation of Fenton's reagent to treat spent caustic wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, H. K.; Nunez, P.; Rodriguez, N.; Guzman, J.

    2009-07-01

    An important wastewater stream from oil refineries is the spent caustic. Caustic solutions are used as scrubbing agent during the desulphurization process to eliminate sulphur an mercaptans from oil and gasses. Spent caustic is classified as DOO3 (reactive sulphide) hazardous waste under the US Resource Conservation and Recovery Act (RCRA). (Author)

  13. Stress corrosion cracking of duplex stainless steels in caustic solutions

    Science.gov (United States)

    Bhattacharya, Ananya

    Duplex stainless steels (DSS) with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and paper mills, de-salination plants, marine environments, and others. However, many DSS grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfide-containing caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the SCC mechanisms for DSS in caustic solutions were not known. Microstructural changes during fabrication processes affect the overall SCC susceptibility of these steels in caustic solutions. Other environmental factors, like pH of the solution, temperature, and resulting electrochemical potential also influence the SCC susceptibility of duplex stainless steels. In this study, the role of material and environmental parameters on corrosion and stress corrosion cracking of duplex stainless steels in caustic solutions were investigated. Changes in the DSS microstructure by different annealing and aging treatments were characterized in terms of changes in the ratio of austenite and ferrite phases, phase morphology and intermetallic precipitation using optical micrography, SEM, EDS, XRD, nano-indentation and microhardness methods. These samples were then tested for general and localized corrosion susceptibility and SCC to understand the underlying mechanisms of crack initiation and propagation in DSS in the above-mentioned environments. Results showed that the austenite phase in the DSS is more susceptible to crack initiation and propagation in caustic solutions, which is different from that in the low pH chloride environment where the ferrite phase is the more susceptible phase. This study also showed that microstructural changes in duplex stainless steels due to different heat treatments could affect their SCC

  14. Laser Beam Caustic Measurement with Focal Spot Analyser

    DEFF Research Database (Denmark)

    Olsen, Flemming Ove; Gong, Hui; Bagger, Claus

    2005-01-01

    In industrial applications of high power CO2-lasers the caustic characteristics of the laser beam have great effects on the performance of the lasers. A welldefined high intense focused spot is essential for reliable production results. This paper presents a focal spot analyser that is developed...... for measuring the beam profiles of focused high power CO2-lasers....

  15. Critical Curves and Caustics of Triple-lens Models

    CERN Document Server

    Danek, Kamil

    2015-01-01

    Among the 25 planetary systems detected up to now by gravitational microlensing, there are two cases of a star with two planets, and two cases of a binary star with a planet. Other, yet undetected types of triple lenses include triple stars or stars with a planet with a moon. The analysis and interpretation of such events is hindered by the lack of understanding of essential characteristics of triple lenses, such as their critical curves and caustics. We present here analytical and numerical methods for mapping the critical-curve topology and caustic cusp number in the parameter space of $n$-point-mass lenses. We apply the methods to the analysis of four symmetric triple-lens models, and obtain altogether 9 different critical-curve topologies and 32 caustic structures. While these results include various generic types, they represent just a subset of all possible triple-lens critical curves and caustics. Using the analyzed models, we demonstrate interesting features of triple lenses that do not occur in two-p...

  16. Ingestion of Caustic Substances in Adults: A Review Article

    Directory of Open Access Journals (Sweden)

    Andon Chibishev

    2013-02-01

    Full Text Available Background: Ingestion of caustic agents can cause serious damages of the upper gastrointestinal tract and in some cases this kind of poisoning may have fatal outcomes. Acute caustic intoxications are one of the main problems in the modern clinical toxicology since they mainly affect young people with psychic disorders, suicidal intent, and alcohol addiction. Text: In diagnostic evaluation of this kind of poisoning, different procedures are used. Today’s golden standard for determination of the grade and extent of the lesion is esophagogastroduodenoscopy (EGD performed in the first 12-24 hours following corrosive ingestion. In some patients, some late complications, such as esophageal stenosis and gastric stenosis, which are the most common, as well as carcinoma of the upper gastrointestinal tract, which is rarely seen, can be detected. Acute caustic poisonings are treated with specific kinds of protocols. According to them, first, an attempt is made to neutralize the poison. Combinations of antibiotics, anti-secretory drugs, and collagen synthesis inhibitors are used. As a support therapy, nutritional liquids can be utilized, and in the most unmanageable cases, esophageal dilatation, stent placement and surgery are used. Conclusion: In the future, caustic poisonings will remain a serious socio-medical issue, due to the difficult clinical presentation, expensive diagnostic protocol, extended hospitalization, and possible permanent disability.

  17. Statistics of Caustics in Large-Scale Structure Formation

    CERN Document Server

    Feldbrugge, Job; van de Weygaert, Rien

    2014-01-01

    The cosmic web is a complex spatial pattern of walls, filaments, cluster nodes and underdense void regions. It emerged through gravitational amplification from the Gaussian primordial density field. Here we infer analytical expressions for the spatial statistics of caustics in the evolving large-scale mass distribution. In our analysis, following the quasi-linear Zeldovich formalism and confined to the 1D and 2D situation, we compute number density and correlation properties of caustics in cosmic density fields that evolve from Gaussian primordial conditions. The analysis can be straightforwardly extended to the 3D situation. We moreover, are currently extending the approach to the non-linear regime of structure formation by including higher order Lagrangian approximations and Lagrangian effective field theory.

  18. Statistics of Caustics in Large-Scale Structure Formation

    Science.gov (United States)

    Feldbrugge, Job L.; Hidding, Johan; van de Weygaert, Rien

    2016-10-01

    The cosmic web is a complex spatial pattern of walls, filaments, cluster nodes and underdense void regions. It emerged through gravitational amplification from the Gaussian primordial density field. Here we infer analytical expressions for the spatial statistics of caustics in the evolving large-scale mass distribution. In our analysis, following the quasi-linear Zel'dovich formalism and confined to the 1D and 2D situation, we compute number density and correlation properties of caustics in cosmic density fields that evolve from Gaussian primordial conditions. The analysis can be straightforwardly extended to the 3D situation. We moreover, are currently extending the approach to the non-linear regime of structure formation by including higher order Lagrangian approximations and Lagrangian effective field theory.

  19. Spectral caustics in laser assisted Breit–Wheeler process

    OpenAIRE

    Nousch, T.; Seipt, D.; Kämpfer, B.; Titov, A. I.

    2016-01-01

    Electron–positron pair production by the Breit–Wheeler process embedded in a strong laser pulse is analyzed. The transverse momentum spectrum displays prominent peaks which are interpreted as caustics, the positions of which are accessible by the stationary phases. Examples are given for the superposition of an XFEL beam with an optical high-intensity laser beam. Such a configuration is available, e.g., at LCLS at present and at European XFEL in near future. It requires a counter propagating ...

  20. Caustics in Tachyon Matter and Other Born-Infeld Scalars

    CERN Document Server

    Felder, G; Starobinsky, A A; Felder, Gary; Kofman, Lev; Starobinsky, Alexei

    2002-01-01

    We consider scalar Born-Infeld type theories with arbitrary potentials V(T) of a scalar field T. We find that for models with runaway potentials V(T) the generic inhomogeneous solutions after a short transient stage can be very well approximated by the solutions of a Hamilton-Jacobi equation that describes free streaming wave front propagation. The analytic solution for this wave propagation shows the formation of caustics with multi-valued regions beyond them. We verified that these caustics appear in numerical solutions of the original scalar BI non-linear equations. Our results include the scalar BI model with an exponential potential, which was recently proposed as an effective action for the string theory tachyon in the approximation where high-order spacetime derivatives of T are truncated. Since the actual string tachyon dynamics contain derivatives of all orders, the tachyon BI model with an exponential potential becomes inadequate when the caustics develop because high order spatial derivatives of T ...

  1. A middle age addicted man with caustic stomach

    Directory of Open Access Journals (Sweden)

    Gholamreza Nouri Broujerdi

    2014-06-01

    Full Text Available Background: The term caustic generally refers to alkaline and the term corrosive generally refers to acidic agents' injury; however, in medical literature caustic is frequently a term applied to both substances. Ingested alkali typically damage the esophagus more than stomach or duodenum, whereas acids usually cause more severe gastric injury. Since esophagus has a slightly alkaline pH, its epithelium is more resistant to acids, so that only 6 to 20% of those who ingest these substances present lesions in this organ. Case : A middle-aged addicted man who drunk hydrochloric acid accidentally had extensive necrosis of the stomach with remarkable sparing of the esophagus on second look exploration. A total gastrectomy with a Roux-en-Y esophago-jejunostomy with feeding jejunostomy was performed. Conclusion : In caustic GI injury, patients who are operated on and found to have no evidence of extensive esophago-gastric necrosis, a biopsy of the posterior gastric wall should be performed to exclude occult injury. If histologically there is a question of viability, a second look operation should be performed within 36 hours.

  2. Caustics and Rogue Waves in an Optical Sea.

    Science.gov (United States)

    Mathis, Amaury; Froehly, Luc; Toenger, Shanti; Dias, Frédéric; Genty, Goëry; Dudley, John M

    2015-08-06

    There are many examples in physics of systems showing rogue wave behaviour, the generation of high amplitude events at low probability. Although initially studied in oceanography, rogue waves have now been seen in many other domains, with particular recent interest in optics. Although most studies in optics have focussed on how nonlinearity can drive rogue wave emergence, purely linear effects have also been shown to induce extreme wave amplitudes. In this paper, we report a detailed experimental study of linear rogue waves in an optical system, using a spatial light modulator to impose random phase structure on a coherent optical field. After free space propagation, different random intensity patterns are generated, including partially-developed speckle, a broadband caustic network, and an intermediate pattern with characteristics of both speckle and caustic structures. Intensity peaks satisfying statistical criteria for rogue waves are seen especially in the case of the caustic network, and are associated with broader spatial spectra. In addition, the electric field statistics of the intermediate pattern shows properties of an "optical sea" with near-Gaussian statistics in elevation amplitude, and trough-to-crest statistics that are near-Rayleigh distributed but with an extended tail where a number of rogue wave events are observed.

  3. Analysis of ray stability and caustic formation in a layered moving fluid medium

    CERN Document Server

    Bergman, David R

    2015-01-01

    Caustic formation occurs within a ray skeleton as optical or acoustic fields propagate in a medium with variable refractive properties and are unphysical, their presence being an artifact of the ray approximation of the field, and methods of correcting the field near a caustic are well known. Differential geometry provides a novel approach to calculating acoustic intensity, assessing ray stability and locating caustics in acoustic ray traces when the properties of medium are completely arbitrary by identifying points on the caustic with conjugate points along various rays. The method of geodesic deviation is applied to the problem of determining ray stability and locating caustics in 2-dimensional acoustic ray traces in a layered moving medium. Specifically, a general treatment of caustic formation in sound ducts and in piecewise continuous media is presented and applied to various idealized and realistic scenarios.

  4. Effects of an expanding caustic ring on a distribution of stars

    Science.gov (United States)

    Chakrabarty, Sankha Subhra; Sikivie, Pierre

    2017-01-01

    In self-similar axially symmetric model of galactic halo, caustic rings lie on the galactic disk and expand on cosmological time scale. We study the motion of a distribution of stars under the gravitational field of an expanding caustic ring. We investigate how the bulk velocities of the stars are affected by the caustic. This work was supported in part by the Heising-Simons Foundation.

  5. Spectral caustics in laser assisted Breit-Wheeler process

    Science.gov (United States)

    Nousch, T.; Seipt, D.; Kämpfer, B.; Titov, A. I.

    2016-04-01

    Electron-positron pair production by the Breit-Wheeler process embedded in a strong laser pulse is analyzed. The transverse momentum spectrum displays prominent peaks which are interpreted as caustics, the positions of which are accessible by the stationary phases. Examples are given for the superposition of an XFEL beam with an optical high-intensity laser beam. Such a configuration is available, e.g., at LCLS at present and at European XFEL in near future. It requires a counter propagating probe photon beam with high energy which can be generated by synchronized inverse Compton backscattering.

  6. Spectral caustics in laser assisted Breit-Wheeler process

    CERN Document Server

    Nousch, T; Kämpfer, B; Titov, A I

    2015-01-01

    Electron-positron pair production by the Breit-Wheeler process embedded in a strong laser pulse is analyzed. The transverse momentum spectrum displays prominent peaks which are interpreted as caustics, the positions of which are accessible by the stationary phases. Examples are given for the superposition of an XFEL beam with an optical high-intensity laser beam. Such a configuration is available, e.g., at LCLS at present and at European XFEL in near future. It requires a counter propagating probe photon beam with high energy which can be generated by synchronized inverse Compton backscattering.

  7. Spectral caustics in laser assisted Breit–Wheeler process

    Directory of Open Access Journals (Sweden)

    T. Nousch

    2016-04-01

    Full Text Available Electron–positron pair production by the Breit–Wheeler process embedded in a strong laser pulse is analyzed. The transverse momentum spectrum displays prominent peaks which are interpreted as caustics, the positions of which are accessible by the stationary phases. Examples are given for the superposition of an XFEL beam with an optical high-intensity laser beam. Such a configuration is available, e.g., at LCLS at present and at European XFEL in near future. It requires a counter propagating probe photon beam with high energy which can be generated by synchronized inverse Compton backscattering.

  8. Caustic-based approach to understanding bunching dynamics and current spike formation in particle bunches

    Science.gov (United States)

    Charles, T. K.; Paganin, D. M.; Dowd, R. T.

    2016-10-01

    Current modulations, current spikes, and current horns, are observed in a range of accelerator physics applications including strong bunch compression in Free Electron Lasers and linear colliders, trains of microbunching for terahertz radiation, microbunching instability and many others. This paper considers the fundamental mechanism that drives intense current modulations in dispersive regions, beyond the common explanation of nonlinear and higher-order effects. Under certain conditions, neighboring electron trajectories merge to form caustics, and often result in characteristic current spikes. Caustic lines and surfaces are regions of maximum electron density, and are witnessed in accelerator physics as folds in phase space of accelerated bunches. We identify the caustic phenomenon resulting in cusplike current profiles and derive an expression which describes the conditions needed for particle-bunch caustic formation in dispersive regions. The caustic expression not only reveals the conditions necessary for caustics to form but also where in longitudinal space the caustics will form. Particle-tracking simulations are used to verify these findings. We discuss the broader implications of this work including how to utilize the caustic expression for manipulation of the longitudinal phase space to achieve a desired current profile shape.

  9. 16 CFR 1500.129 - Substances named in the Federal Caustic Poison Act.

    Science.gov (United States)

    2010-01-01

    ... Poison Act. 1500.129 Section 1500.129 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FEDERAL... REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those substances covered by the Federal Caustic Poison Act (44 Stat. 1406), the requirements of section 2(p)(1)...

  10. Biological treatment of sulfidic spent caustics under haloalkaline conditions using soda lake bacteria

    NARCIS (Netherlands)

    Graaff, de C.M.

    2012-01-01

    In this thesis, the development of a newbiotechnological process for the treatment of undiluted sulfidic spent caustics (SSC’s) using soda lake bacteria is described. SSC’s are waste solutions that are formed in the oil and gas industry due to the caustic (NaOH) scrubbing of hydrocarbon

  11. Biases and caustics in long-range acoustic tomography

    Science.gov (United States)

    Munk, Walter; Wunsch, Carl

    1985-11-01

    We consider the travel time perturbation δt of acoustic rays in an ocean sound channel. The perturbations arom a straining e(x,z) of the water column. An expansion to second order gives δt ≈ τ + ατ , where and are suitably weighted strain wverages, α is a number of order 1 (except near caustics), and τ is the phase integral (the 'reduced travel time' in the seismic literature); τ is a function of ray steepness and range, and varies from zero for axial rays to order 10 s for steep rays at 1000 km range. The quadratic bais ατ changes sign at the caustics; generally it is negative (warm bias) for a range-dependent ocean as compared to a range-independent ocean with the same average properties. We consider two separate problems: (a) linear inversions for the range-averaged profile in soundspeed (temperature) introduces 0.5 m s -1 (0.1 °C) systematic errors arising from horizontal ocean variability (mesoscal activity), but these errors can be reduced by making corrections for . (b) In the problem of monitoring for climatic changes of large-scale ocean features, the quadratic bias is negligible compared to the sample variability, and there is an inherent advantage to the long-range horizontal integration in acoustic tomography over the traditional local measurements.

  12. Testing the Caustic Ring Dark Matter Halo Model Against Observations in the Milky Way

    Science.gov (United States)

    Dumas, Julie; Newberg, Heidi Jo; Niedzielski, Bethany; Susser, Adam; Thompson, Jeffery M.; Weiss, Jake; Lewis, Kim M.

    2016-06-01

    One prediction of axion dark matter models is they can form Bose-Einstein condensates and rigid caustic rings as a halo collapses in the non-linear regime. In this thesis, we undertake the first study of a caustic ring model for the Milky Way halo (Duffy & Sikivie 2008), paying particular attention to observational consequences. We first present the formalism for calculating the gravitational acceleration of a caustic ring halo. The caustic ring dark matter theory reproduces a roughly logarithmic halo, with large perturbations near the rings. We show that this halo can reasonably match the known Galactic rotation curve. We are not able to confirm or rule out an association between the positions of the caustic rings and oscillations in the observed rotation curve, due to insufficient rotation curve data. We explore the effects of dark matter caustic rings on dwarf galaxy tidal disruption with N-body simulations. Simulations of the Sagittarius (Sgr) dwarf galaxy in a caustic ring halo potential, with disk and bulge parameters that are tuned to match the Galactic rotation curve, match observations of the Sgr trailing tidal tails as far as 90 kpc from the Galactic center. Like the Navarro-Frenk-White (NFW) halo, they are, however, unable to match the leading tidal tail. None of the caustic, NFW, or triaxial logarithmic halos are able to simultaneously match observations of the leading and trailing arms of the Sagittarius stream. We further show that simulations of dwarf galaxies that move through caustic rings are qualitatively similar to those moving in a logarithmic halo. This research was funded by NSF grant AST 10-09670, the NASA-NY Space Grant, and the American Fellowship from AAUW.

  13. Epidemiology and prevention of caustic ingestion in children

    DEFF Research Database (Denmark)

    Christesen, H B

    1994-01-01

    A total of 102 children less than 16 years of age admitted for caustic ingestion in the period 1976-1991 were registered. The annual incidence rate of hospitalization was 10.8:100,000 for the city of Aarhus, Denmark. Esophageal burns occurred with a frequency of 5.0:100,000 per year. Ninety......-four percent of the children were less than 5 years old. For this age group, the incidence rates of admission and esophageal burns were 34.6:100,000 and 15.8:100,000, respectively. All ingestions were accidental. The incidence rates of esophageal burns in children 0-4 years old (p = 0.019) decreased...

  14. Studying the microlenses mass function from statistical analysis of the caustic concentration

    Energy Technology Data Exchange (ETDEWEB)

    Mediavilla, T; Ariza, O [Departamento de Estadistica e Investigacion Operativa, Universidad de Cadiz, Avda de Ramon Puyol, s/n 11202 Algeciras (Spain); Mediavilla, E [Instituto de Astrofisica de Canarias, Avda Via Lactea s/n, La Laguna (Spain); Munoz, J A, E-mail: teresa.mediavilla@ca.uca.es, E-mail: octavio.ariza@uca.es, E-mail: emg@iac.es [Departamento de Astrofisica y Astronomia, Universidad de Valencia, Burjassot, Valencia (Spain)

    2011-09-22

    The statistical distribution of caustic crossings by the images of a lensed quasar depends on the properties of the distribution of microlenses in the lens galaxy. We use a procedure based in Inverse Polygon Mapping to easily identify the critical and caustic curves generated by a distribution of stars in the lens galaxy. We analyze the statistical distributions of the number of caustic crossings by a pixel size source for several projected mass densities and different mass distributions. We compare the results of simulations with theoretical binomial distributions. Finally we apply this method to the study of the stellar mass distribution in the lens galaxy of QSO 2237+0305.

  15. Industrial Experience on the Caustic Cracking of Stainless Steels and Nickel Alloys - A Review

    Energy Technology Data Exchange (ETDEWEB)

    Rebak, R B

    2005-10-09

    Caustic environments are present in several industries, from nuclear power generation to the fabrication of alkalis and alumina. The most common material of construction is carbon steel but its application is limited to a maximum temperature of approximately 80 C. The use of Nickel (Ni) alloys is recommended at higher temperatures. Commercially pure Ni is the most resistant material for caustic applications both from the general corrosion and the stress corrosion cracking (SCC) perspectives. Nickel rich alloys also offer a good performance. The most important alloying elements are Ni and chromium (Cr). Molybdenum (Mo) is not a beneficial alloying element and it dissolves preferentially from the alloy in presence of caustic environments. Austenitic stainless steels such as type 304 and 316 seem less resistant to caustic conditions than even plain carbon steel. Experimental evidence shows that the most likely mechanism for SCC is anodic dissolution.

  16. Caustics, pseudocaustics and the related illuminated and dark regions with the computational method of quantifier elimination

    Science.gov (United States)

    Ioakimidis, Nikolaos I.

    2017-01-01

    The method of caustics is a powerful experimental method in elasticity and particularly in fracture mechanics for crack problems. The related method of pseudocaustics is also of interest. Here we apply the computational method of quantifier elimination implemented in the computer algebra system Mathematica in order to determine (i) the non-parametric equation and two properties of the caustic at a crack tip and especially (ii) the illuminated and the dark regions related to caustics and pseudocaustics in plane elasticity and plate problems. The present computations concern: (i) The derivation of the non-parametric equation of the classical caustic about a crack tip through the elimination of the parameter involved (here the polar angle) as well as two geometrical properties of this caustic. (ii) The derivation of the inequalities defining the illuminated region on the screen in the problem of an elastic half-plane loaded normally by a concentrated load with the boundary of this illuminated region related to some extent to the caustic formed. (iii) Similarly for the problem of a clamped circular plate under a uniform loading with respect to the caustic and the pseudocaustic formed. (iv) Analogously for the problem of an equilateral triangular plate loaded by uniformly distributed moments along its whole boundary, which defines the related pseudocaustic. (v) The determination of quantities of interest in mechanics from the obtained caustics or pseudocaustics. The kind of computations in the applications (ii) to (iv), i.e. the derivation of inequalities defining the illuminated region on the screen, seems to be completely new independently of the use here of the method of quantifier elimination. Additional applications are also possible, but some of them require the expansion of the present somewhat limited power of the quantifier elimination algorithms in Mathematica. This is expected to take place in the future.

  17. Structured caustic vector vortex optical field: manipulating optical angular momentum flux and polarization rotation.

    Science.gov (United States)

    Chen, Rui-Pin; Chen, Zhaozhong; Chew, Khian-Hooi; Li, Pei-Gang; Yu, Zhongliang; Ding, Jianping; He, Sailing

    2015-05-29

    A caustic vector vortex optical field is experimentally generated and demonstrated by a caustic-based approach. The desired caustic with arbitrary acceleration trajectories, as well as the structured states of polarization (SoP) and vortex orders located in different positions in the field cross-section, is generated by imposing the corresponding spatial phase function in a vector vortex optical field. Our study reveals that different spin and orbital angular momentum flux distributions (including opposite directions) in different positions in the cross-section of a caustic vector vortex optical field can be dynamically managed during propagation by intentionally choosing the initial polarization and vortex topological charges, as a result of the modulation of the caustic phase. We find that the SoP in the field cross-section rotates during propagation due to the existence of the vortex. The unique structured feature of the caustic vector vortex optical field opens the possibility of multi-manipulation of optical angular momentum fluxes and SoP, leading to more complex manipulation of the optical field scenarios. Thus this approach further expands the functionality of an optical system.

  18. Wavefields Near Transverse Cusp Caustics Produced by Reflecting Ultrasonic Transients and Tone Bursts from Curved Surfaces.

    Science.gov (United States)

    Frederickson, Carl King

    Ultrasonic wavefields reflected from curved surfaces were studied in the vicinity of caustics. Acoustical and optical transverse cusp diffraction catastrophes produced by reflections from a curved metal surface in water were imaged by displaying the amplitude or intensity in an observation plane transverse to the general direction of propagation. The optical image was used to locate the cusp point in the observation plane. Acoustical diffraction patterns for sine waves, described by the Pearcey function, were calculated with the parameters determined by the experimental setup leaving no adjustable scaling parameters. The calculated and experimental acoustical diffraction patterns showed good agreement near the cusp point. The acoustical diffraction pattern showed the expected mirror symmetry about an axis. The pattern was shown to scale properly with frequency. The transverse cusp caustic separates space into a region with three rays and a region with one ray. Inside the caustic there are three rays, on the curve two of the rays merge and disappear leaving one ray outside. Transient signals reflected from curved surfaces exhibited the merging and disappearance of rays on the caustic. Relative arrival times for signals in calculated and recorded time traces agree well. The relation to the wavefront parameters of the temporal orientation of the travel time surface is discussed. The general shape of the travel time surface is that of the swallow tail caustic surface. The temporal shape of the transient echoes was seen to be generally that of the incident signal or of its Hilbert transform. The Hilbert transform shape identifies the signals that have touched the caustic. The observed arrival sequence of the transient signals was shh inside the caustic and one h outside, where s stands for a signal with the general shape of the incident signal and h for its Hilbert transform. The relation between the surface and wavefront parameters and the arrival sequence is given.

  19. Faraday caustics: Singularities in the Faraday spectrum and their utility as probes of magnetic field properties

    CERN Document Server

    Bell, M R; Enßlin, T A

    2011-01-01

    We describe singularities in the distribution of polarized intensity as a function of Faraday depth (i.e. the Faraday spectrum) that arise due to line of sight (LOS) magnetic field reversals. We call these features Faraday caustics due to their similarity to optical caustics. They appear sharply spiked in the Faraday spectrum with a tail that extends to one side. The direction in which the tail extends depends on the way in which the LOS magnetic field reversal occurs (either changing from oncoming to retreating or vice versa). We describe how surfaces of Faraday caustics relate to boundaries between regions where the LOS magnetic field has opposite polarity. Examples from simulations of the polarized synchrotron emission from the Milky Way are provided. We derive the probability or luminosity distribution of Faraday caustics produced in a Gaussian magnetic field distribution as a function of their strength, F, and find that for strong Faraday caustics P(F) ~ F^(-3). If fully resolved, this distribution is al...

  20. Caustic Ingestion in Children: a Systematic Review and Meta-Analysis

    Science.gov (United States)

    Rafeey, Mandana; Ghojazadeh, Morteza; Sheikhi, Saeede; Vahedi, Leila

    2016-01-01

    Introduction:Caustic ingestion that occurs accidently is one of the most common problems in children. Methods: This systematic review has been performed by searching the databases including Science Direct, ProQuest, Google Scholar, and PubMed. A strategic search was performed with keywords including caustic, corrosive, ingestion, and children, and was limited to articles in English and Persian. Data were analyzed using Comprehensive Meta-Analysis2 and PASW Statistics 18. Results: We selected 64 articles regarding caustic ingestion with a total sample of 11,345 cases. The data analysis indicated a higher consumption in young boys (age range 2.78 (2.02) years (OR=0.53 with a 95% confidence interval of 0.49-0.57 (P=0.08)). The most common caustic substances were household cleaning agents, particularly bleaches and cleaners. Esophageal cancer and death were reported as well as digestive and respiratory complications. Invasive and expensive techniques are frequently used for diagnosis, treatment and follow up. Conclusion: The results demonstrated that although caustic ingestion is a serious problem among children, it is a preventable and manageable issue. Therefore, appropriate efforts by families, government, factories, health team and media should be made to handle adequately this matter.

  1. MECHANISTIC UNDERSTANDING OF CAUSTIC CRACKING OF CARBON STEELS

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Diaz, B.; Roy, A.

    2009-10-19

    Liquid waste generated by the PUREX process for separation of nuclear materials is concentrated and stored in Type IV single-shell carbon steel tanks at the Savannah River Site (SRS). The Type IV tanks for this waste do not have cooling coils and have not undergone heat treatment to stress-relieve the tanks. After the waste is concentrated by evaporation, it becomes very alkaline and can cause stress corrosion cracking (SCC) and pitting corrosion of the tank materials. SRS has experienced leakage from non-stress-relieved waste tanks constructed of A285 carbon steel and pitting of A212 carbon steel tanks in the vapor space. An investigation of tank materials has been undertaken at SRS to develop a basic understanding of caustic SCC of A285 and A212 grade carbon steels exposed to aqueous solutions, primarily containing sodium hydroxide (NaOH), sodium nitrate (NaNO{sub 3}), and sodium nitrite (NaNO{sub 2}) at temperatures relevant to the operating conditions of both the F and H area plants. This report presents the results of this corrosion testing program. Electrochemical tests were designed using unstressed coupons in a simulated tank environment. The purpose of this testing was to determine the corrosion susceptibility of the tank materials as a function of chemical concentration, pH, and temperature. A285 and A516 (simulates A212 carbon steel) coupons were used to investigate differences in the corrosion of these carbon steels. Electrochemical testing included measurement of the corrosion potential and polarization resistance as well as cyclic potentiodynamic polarization (CPP) testing of coupons. From the CPP experiments, corrosion characteristics were determined including: corrosion potential (E{sub corr}), pitting or breakdown potential (E{sub pit}), and repassivation potential (E{sub prot}). CPP results showed no indications of localized corrosion, such as pitting, and all samples showed the formation of a stable passive layer as evidenced by the positive

  2. New strategies for treatment and reuse of spent sulfidic caustic stream from petroleum industry

    Directory of Open Access Journals (Sweden)

    Jéssica Frontino Paulino

    2012-01-01

    Full Text Available This work examines traditional and new routes for removal of H2S and other sulfur compounds from spent sufidic caustic (SSC. SH- (hydrogenosulfide and S2- (sulfide ions were quantitatively oxidized at 25 ºC using H2O2, NaOCl or a spent sulfochromic mixture. SH-/S2- ions were also removed via reaction with freshly prepared iron or manganese hydroxides, or after passing the SSC through strong basic anion exchange resins (OH- form. The treated caustic solution, as well as iron/manganese hydroxides, removed H2S from diesel samples at 25 ºC. SSC treatment via strong basic anion-exchange resins produced the treated caustic solution with the highest free alkalinity.

  3. INTER-CONTACT FORCE ANALYSIS OF IMPACTED DISK ASSEMBLY BY DYNAMIC CAUSTICS

    Institute of Scientific and Technical Information of China (English)

    LI Ming(李明); ZHANG Jue; FANG Jing(方竞)

    2003-01-01

    The caustic method was utilized to study the contact force transmission in disk assemblies under impact load. The mapping equations were obtained based on the first invariant of the stress components in the disk subject to a normal concentrated force, and a characteristic dimension of the maximum size in the caustic curve was proposed to evaluate the contact force between the disks.Transient patterns of the caustic shadows were recorded by means of a high-speed camera of off-focus imaging, then the histories of the inter-contact forces among the disks were obtained with respect to the conditions of different masses and heights of the falling hammers. The influence of the impact loading and impulsive velocity was analyzed with respect to the force responses of the disk assembly,the double-peak phenomenon with comparison to the initial masses, and the energy dissipation of the systems under impact of different momentums.

  4. Superboom Caustic Analysis and Measurement Program (SCAMP) Final Report

    Science.gov (United States)

    Page, Juliet; Plotkin, Ken; Hobbs, Chris; Sparrow, Vic; Salamone, Joe; Cowart, Robbie; Elmer, Kevin; Welge, H. Robert; Ladd, John; Maglieri, Domenic; Piacsek, Andrew

    2015-01-01

    The objectives of the Superboom Caustic Analysis and Measurement (SCAMP) Program were to develop and validate, via flight-test measurements, analytical models for sonic boom signatures in and around focal zones as they are expected to occur during commercial aircraft transition from subsonic to supersonic flight, and to apply these models to focus boom prediction of low-boom aircraft designs. The SCAMP program has successfully investigated sonic boom focusing both analytically and experimentally, while gathering a comprehensive empirical flight test and acoustic dataset, and developing a suite of focused sonic boom prediction tools. An experimental flight and acoustic measurement test was designed during the initial year of the SCAMP program, with execution of the SCAMP flight test occurring in May 2011. The current SCAMP team, led by Wyle, includes partners from the Boeing Company, Pennsylvania State University, Gulfstream Aerospace, Eagle Aeronautics, and Central Washington University. Numerous collaborators have also participated by supporting the experiment with human and equipment resources at their own expense. The experiment involved precision flight of a McDonnell Douglas (now Boeing) F-18B executing different maneuvers that created focused sonic booms. The maneuvers were designed to center on the flight regime expected for commercial supersonic aircraft transonic transition, and also span a range of caustic curvatures in order to provide a variety of conditions for code validations. The SCAMP experiment was designed to capture concurrent F-18B on-board flight instrumentation data, high-fidelity ground-based and airborne acoustic data, and surface and upper air meteorological data. Close coordination with NASA Dryden resulted in the development of new experimental instrumentation and techniques to facilitate the SCAMP flight-test execution, including the development of an F-18B Mach rate cockpit display, TG-14 powered glider in-flight sonic boom measurement

  5. Curvilinear wave-equation angle transform: Caustics, turning rays, absence of kinematic artifacts

    NARCIS (Netherlands)

    Stolk, C.C.; De Hoop, M.V.

    2007-01-01

    Migration of seismic reflection data to common image-point gathers is an integral part of both migration velocity analysis (MVA) and amplitude (AVA) analysis. Its applicability in complex geology depends on whether these gathers will be artifact free, and is related to the formation of caustics and

  6. Structural evaluation of mixer pump installed in Tank 241-AN-107 for caustic addition project

    Energy Technology Data Exchange (ETDEWEB)

    Leshikar, G.A.

    1995-06-16

    This report documents the structural analysis and evaluation of a mixer pump and caustic addition system to be used in Tank 107-AN. This pump will be installed in the central pump pit of this double- shell tank for the purpose of bringing the hydroxide ion concentration into compliance with Tank Farm operating specifications.

  7. Biological treatment of refinery spent caustics under halo-alkaline conditions

    NARCIS (Netherlands)

    Graaff, de M.; Bijmans, M.F.M.; Abbas, B.; Euverink, G.J.W.; Muyzer, G.; Janssen, A.J.H.

    2011-01-01

    The present research demonstrates the biological treatment of refinery sulfidic spent caustics in a continuously fed system under halo-alkaline conditions (i.e. pH 9.5; Na(+)= 0.8M). Experiments were performed in identical gas-lift bioreactors operated under aerobic conditions (80-90% saturation) at

  8. Prediction of complications following unintentional caustic ingestion in children. Is endoscopy always necessary?

    DEFF Research Database (Denmark)

    Christesen, H B

    1995-01-01

    The records of 115 children hospitalized following caustic ingestion over an 18.5-year period from 1976 to 1994 were reviewed. The relationship between types of product ingested, signs and symptoms, degree of esophageal injury and complications was analyzed. All complications were the result of s...

  9. Novel Electrochemical Treatment of Spent Caustic from the Hydrocarbon Industry Using Ti/BDD

    Directory of Open Access Journals (Sweden)

    Alejandro Medel

    2015-01-01

    Full Text Available During the crude oil refining process, NaOH solutions are used to remove H2S, H2Saq, and sulfur compounds from different hydrocarbon streams. The residues obtained are called “spent caustics.” These residues can be mixed with those obtained in other processes, adding to its chemical composition naphthenic acids and phenolic compounds, resulting in one of the most dangerous industrial residues. In this study, the use of electrochemical technology (ET, using BDD with Ti as substrate (Ti/BDD, is evaluated in electrolysis of spent caustic mixtures, obtained through individual samples from different refineries. In this way, the Ti/BDD’s capability of carrying out the electrochemical destruction of spent caustics in an acidic medium is evaluated having as key process a chemical pretreatment phase. The potential production of •OHs, as the main reactive oxygen species electrogenerated over Ti/BDD surface, was evaluated in HCl and H2SO4 through fluorescence spectroscopy, demonstrating the reaction medium’s influence on its production. The results show that the hydrocarbon industry spent caustics can be mineralized to CO2 and water, driving the use of ET and of the Ti/BDD to solve a real problem, whose potential and negative impact on the environment and on human health is and has been the environmental agencies’ main focus.

  10. Topical mitomycin C can effectively alleviate dysphagia in children with long-segment caustic esophageal strictures.

    Science.gov (United States)

    El-Asmar, K M; Hassan, M A; Abdelkader, H M; Hamza, A F

    2015-07-01

    Caustic ingestion in children and the resulting long esophageal strictures are usually difficult to be managed, and eventually, esophageal replacement was required for cases refractory to frequent dilatation sessions. Topical mitomycin C (MMC) application has been used recently to improve the results of endoscopic dilatation for short esophageal strictures. The study aims to assess the role of MMC application in management of long-segment caustic esophageal strictures. From January 2009 to June December 2013, patients presented with long caustic esophageal stricture (>3 cm in length) were included in this study and subjected to topical MMC application after endoscopic esophageal dilatation on multiple sessions. Regular follow-up and re-evaluation were done. A dysphagia score was used for close follow-up clinically; verification was done radiologically and endoscopically. During the specified follow-up period, 21 patients with long caustic esophageal stricture were subjected to topical MMC application sessions. Clinical, radiological, and endoscopic resolution of strictures occurred in 18 patients (85.7% cure rate). Number of dilatation sessions to achieve resolution of dysphagia was (n = 14.3 ± 5.7) with application of mitomycin two to six times. There was no recurrence in short- and mid-term follow-up. No complications were encountered related to topical MMC application. MMC is a promising agent in management of long-segment caustic esophageal strictures. Long-term follow-up is needed to prove its efficacy and to evaluate potential long-term side-effects of MMC application.

  11. EFRT M-12 Issue Resolution: Caustic Leach Rate Constants from PEP and Laboratory-Scale Tests

    Energy Technology Data Exchange (ETDEWEB)

    Mahoney, Lenna A.; Rassat, Scot D.; Eslinger, Paul W.; Aaberg, Rosanne L.; Aker, Pamela M.; Golovich, Elizabeth C.; Hanson, Brady D.; Hausmann, Tom S.; Huckaby, James L.; Kurath, Dean E.; Minette, Michael J.; Sundaram, S. K.; Yokuda, Satoru T.

    2009-08-14

    Testing Summary Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP-2, the slurry is

  12. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    Energy Technology Data Exchange (ETDEWEB)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below

  13. Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

    Energy Technology Data Exchange (ETDEWEB)

    Pendleton, Justin; Bhavaraju, Sai; Priday, George; Desai, Aditya; Duffey, Kean; Balagopal, Shekar [Ceramatec Inc., Salt Lake City, UT 84119 (United States)

    2012-07-01

    As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodium management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent

  14. Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, Caustic Wash Tank And Caustic Storage Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 6 Operations

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T. B.

    2014-01-02

    Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Caustic Storage Tank (CST) samples from the Interim Salt Disposition Project (ISDP) Salt Batch (“Macrobatch”) 6 have been analyzed for 238Pu, 90Sr, 137Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The Pu, Sr, and Cs results from the current Macrobatch 6 samples are similar to those from comparable samples in previous Macrobatch 5. In addition the SEHT and DSSHT heel samples (i.e. ‘preliminary’) have been analyzed and reported to meet NGS Demonstration Plan requirements. From a bulk chemical point of view, the ICPES results do not vary considerably between this and the previous samples. The titanium results in the DSSHT samples continue to indicate the presence of Ti, when the feed material does not have detectable levels. This most likely indicates that leaching of Ti from MST has increased in ARP at the higher free hydroxide concentrations in the current feed.

  15. Galaxy And Mass Assembly: Estimating galaxy group masses via caustic analysis

    CERN Document Server

    Alpaslan, Mehmet; Driver, Simon; Norberg, Peder; Peacock, John A; Baldry, Ivan; Bland-Hawthorn, Joss; Brough, Sarah; Hopkins, Andrew M; Kelvin, Lee S; Liske, Jochen; Loveday, Jon; Merson, Alexander; Nichol, Robert C; Pimbblet, Kevin

    2012-01-01

    We have generated complementary halo mass estimates for all groups in the Galaxy And Mass Assembly Galaxy Group Catalogue (GAMA G3Cv1) using a modified caustic mass estimation algorithm, originally developed by Diaferio & Geller (1997). We calibrate the algorithm by applying it on a series of 9 GAMA mock galaxy light cones and investigate the effects of using different definitions for group centre and size. We select the set of parameters that provide median-unbiased mass estimates when tested on mocks, and generate mass estimates for the real group catalogue. We find that on average, the caustic mass estimates agree with dynamical mass estimates within a factor of 2 in 90.8 +/- 6.1% groups and compares equally well to velocity dispersion based mass estimates for both high and low multiplicity groups over the full range of masses probed by the G3Cv1.

  16. K-Area Acid/Caustic Basin groundwater monitoring report: First quarter 1992

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, C.Y.

    1992-06-01

    During first quarter 1992, samples from the seven KAC monitoring wells at the K-Area Acid/Caustic Basin of Savannah River Plant were analyzed for herbicides, indicator parameters, major ions, pesticides, radionuclides, turbidity, volatile organic compounds, and other constituents. Monitoring results that exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) and the Savannah River Site (SRS) flagging criteria and turbidity standards during the quarter are discussed in this report. No constituent exceeded the PDWS in the KAC wells at the K-Area Acid/Caustic Basin during first quarter 1992. Total organic halogens exceeded the Flag 2 criterion in wells KAC 6, and 7, and iron exceeded the Flag 2 criterion in well KAC 6. Well KAC 2 was the only well in the KAC well series to exceed the SRS turbidity standard.

  17. K-Area Acid/Caustic Basin groundwater monitoring report. Second quarter 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    During second quarter 1994, samples from the KAC-monitoring wells at the K-Area Acid/Caustic Basin were collected and analyzed for herbicides/pesticides, indicator parameters, metals, nitrate, radionuclide indicators, and other constituents. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS), other Savannah River Site (SRS) Flag 2 criteria, of the SRS turbidity standard are provided in this report. No constituents exceeded the final PDWS in the KAC wells. Aluminum, iron, and specific conductance exceeded other SRS flagging criteria in one or more of the downgradient wells. Total organic halogens was elevated in upgradient well KAC 3. Groundwater flow direction and rate in the water table beneath the K-Area Acid/Caustic Basin were similar to past quarters.

  18. Detecting stellar spots through polarimetry observations of microlensing events in caustic-crossing

    CERN Document Server

    Sajadian, Sedighe

    2015-01-01

    In this work, we investigate if gravitational microlensing can magnify the polarization signal of a stellar spot and make it be observable. A stellar spot on a source star of microlensing makes polarization signal through two channels of Zeeman effect and breaking circular symmetry of the source surface brightness due to its temperature contrast. We first explore the characteristics of perturbations in polarimetric microlensing during caustic-crossing of a binary lensing as follows: (a) The cooler spots over the Galactic bulge sources have the smaller contributions in the total flux, although they have stronger magnetic fields. (b) The maximum deviation in the polarimetry curve due to the spot happens when the spot is located near the source edge and the source spot is first entering the caustic whereas the maximum photometric deviation occurs for the spots located at the source center. (c) There is a (partial) degeneracy for indicating spot's size, its temperature contrast and its magnetic induction from the...

  19. SPHERICAL NONLINEAR PULSES FOR THE SOLUTIONS OF NONLINEAR WAVE EQUATIONS Ⅱ, NONLINEAR CAUSTIC

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    This article discusses spherical pulse like solutions of the system of semilinear wave equations with the pulses focusing at a point and emerging outgoing in three space variables. In small initial data case, it shows that the nonlinearities have a strong effect at the focal point. Scattering operator is introduced to describe the caustic crossing. With the aid of the L∞ norms, it analyzes the relative errors in approximate solutions.

  20. Caustic Injury In Adults – A Study For 3 Year Period

    OpenAIRE

    2016-01-01

    The aim of the study is to present the results of a 3-year clinico-epidemiological investigation of caustic injury in adults. The study includes 43 patients with acute corrosive ingestion, hospitalized in the Toxicology Clinic, University Hospital “N. I. Pirogov”, Sofia, Bulgaria, for the period 01.01. 2010-31.12.2012. The methods used include: clinical observation and examination, clinical laboratory, imaging, and psychiatric methods and tests. 43 patients between the ages of 22 and 82 with ...

  1. Washing and caustic leaching of Hanford tank sludge: Results of FY 1997 studies

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, G.J.; Burgeson, I.E.; Wagner, M.J.; Liu, J.; Chen, Y.L.

    1997-08-01

    The current plan for remediating the Hanford tank farms consists of waste retrieval, pretreatment, treatment (immobilization), and disposal. The tank wastes will be partitioned into high-level and low-level fractions. The HLW will be immobilized in a borosilicate glass matrix; the resulting glass canisters will then be disposed of in a geologic repository. Because of the expected high cost of HLW vitrification and geologic disposal, pretreatment processes will be implemented to reduce the volume of immobilized high-level waste (IHLW). Caustic leaching (sometimes referred to as enhanced sludge washing or ESW) represents the baseline method for pretreating Hanford tank sludges. Caustic leaching is expected to remove a large fraction of the Al, which is present in large quantities in Hanford tank sludges. A significant portion of the P is also expected to be removed from the sludge by metathesis of water-insoluble metal phosphates to insoluble hydroxides and soluble Na{sub 3}PO{sub 4}. Similar metathesis reactions can occur for insoluble sulfate salts, allowing the removal of sulfate from the HLW stream. This report describes the sludge washing and caustic leaching tests performed at the Pacific Northwest National Laboratory in FY 1996. The sludges used in this study were taken from Hanford tanks AN-104, BY-108, S-101, and S-111.

  2. The Efficacy of Mesenchymal Stem Cell Transplantation in Caustic Esophagus Injury: An Experimental Study

    Directory of Open Access Journals (Sweden)

    Murat Kantarcioglu

    2014-01-01

    Full Text Available Introduction. Ingestion of corrosive substances may lead to stricture formation in esophagus as a late complication. Full thickness injury seems to exterminate tissue stem cells of esophagus. Mesenchymal stem cells (MSCs can differentiate into specific cell lineages and have the capacity of homing in sites of injury. Aim and Methods. We aimed to investigate the efficacy of MSC transplantation, on prevention of esophageal damage and stricture formation after caustic esophagus injury in rats. 54 rats were allocated into four groups; 4 rats were sacrificed for MSC production. Group 1, untreated controls (n: 10. Group 2, membrane labeled MSCs-treated rats (n: 20. Group 3, biodistribution of fluorodeoxyglucose labeled MSCs via positron emission tomography (PET imaging (n: 10. Group 4, sham operated (n: 10. Standard caustic esophageal burns were created and MSCs were transplanted 24 hours after. All rats were sacrificed at the 21st days. Results. PET scan images revealed the homing behavior of MSCs to the injury site. The histopathology damage score was not significantly different from controls. However, we demonstrated Dil labeled epithelial and muscle cells which were originating from transplanted MSCs. Conclusion. MSC transplantation after caustic esophageal injury may be a helpful treatment modality; however, probably repeated infusions are needed.

  3. Caustic ingestion in adults: The role of endoscopic classification in predicting outcome

    Directory of Open Access Journals (Sweden)

    Tang Jui-Hsiang

    2008-07-01

    Full Text Available Abstract Background The ingestion of caustic substances induces an extensive spectrum of injuries to the aerodigestive tract which include extensive necrosis and perforation of the esophagus and stomach. The gold standard of safely assessing depth, extent of injury, and appropriate therapeutic regimen is esophagogastroduodenoscopy (EGD. The objective of this study was to report our clinical experience and to evaluate the role of a 6-point EGD classification system of injury in predicting outcomes in adult patients diagnosed with caustic agent ingestion. Methods The study was a retrospective medical chart review from 273 patients admitted to the Chang Gung Memorial Hospital in Tao-Yuan, Taiwan between June 1999 and July 2006 for treatment of caustic ingestion. The patients underwent EGD within 24 hours of admission and mucosal damage was graded using Zagar's modified endoscopic classification scheme. After treatment, patients were followed in the outpatient clinic for a minimum of 6 months. Results A total of 273 patients were included for analysis. Grade 3b injury was the most common caustic injury (n = 82, 30.03%, followed by grade 2b injuries (n = 62, 22.71%. Stricture was the most common complication (n = 66, 24.18%, followed by aspiration pneumonia (n = 31, 11.36%, and respiratory failure (n = 21, 7.69%. Compared to grade 3a mucosal injury, grade 3b mucosal injuries were at greater risk of prolonged hospital stay (odds ratio [OR]: 2.44; 95% confidence interval [CI]: 1.25–4.80, ICU admission (OR: 10.82; 95% CI: 2.05–200.39, and gastrointestinal (OR: 4.15; 95% CI: 1.55–13.29 and systemic complications (OR: 4.07; 95% CI: 1.81–14.07. Conclusion In patients with caustic ingestion, EGD should be performed within 12 to 24 hours and categorized according to a 6-point scale. Patients with grade 3b burns identified on endoscopy have high rates of morbidity. The 6-point scale is useful for predicting immediate and long-term complications, and

  4. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Adriaan van Heiningen

    2007-06-30

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and

  5. Test Results for Caustic Demand Measurements on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples

    Energy Technology Data Exchange (ETDEWEB)

    Doll, Stephanie R. [Washington River Protection Solutions, Richland, WA (United States); Bolling, Stacie D. [Washington River Protection Solutions, Richland, WA (United States)

    2016-07-14

    Caustic demand testing is used to determine the necessary amount of caustic required to neutralize species present in the Hanford tank waste and obtain a target molarity of free hydroxide for tank corrosion control. The presence and quantity of hydroxide-consuming analytes are just as important in determining the caustic demand as is the amount of free hydroxide present. No single data point can accurately predict whether a satisfactory hydroxide level is being met, as it is dependent on multiple factors (e.g., free hydroxide, buffers, amphoteric metal hydroxides, bicarbonate, etc.). This enclosure contains the caustic demand, scanning electron microscopy (SEM), polarized light microscopy (PLM), and X-ray diffraction (XRD) analysis for the tank 241-AX-101 (AX-101) and 241-AX-103 (AX-103) samples. The work was completed to fulfill a customer request outlined in the test plan, WRPS-1505529, “Test Plan and Procedure for Caustic Demand Testing on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples.” The work results will provide a baseline to support planned retrieval of AX-101 and AX-103.

  6. Test Results for Caustic Demand Measurements on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples

    Energy Technology Data Exchange (ETDEWEB)

    Doll, Stephanie R. [Washington River Protection Solutions, Richland, WA (United States); Bolling, Stacie D. [Washington River Protection Solutions, Richland, WA (United States)

    2016-07-14

    Caustic demand testing is used to determine the necessary amount of caustic required to neutralize species present in the Hanford tank waste and obtain a target molarity of free hydroxide for tank corrosion control. The presence and quantity of hydroxide-consuming analytes are just as important in determining the caustic demand as is the amount of free hydroxide present. No single data point can accurately predict whether a satisfactory hydroxide level is being met as it is dependent on multiple factors (e.g., free hydroxide, buffers, amphoteric metal hydroxides, bicarbonate, etc.). This enclosure contains the caustic demand, scanning electron microscopy (SEM), polarized light microscopy (PLM), and X-ray diffraction (XRD) analysis for the tank 241-AX-101 (AX-101) and 241-AX-103 (AX-103) samples. The work was completed to fulfill a customer request outlined in the test plan, WRPS-1505529, “Test Plan and Procedure for Caustic Demand Testing on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples.” The work results will provide a baseline to support planned retrieval of AX-101 and AX-103.

  7. Caustic leaching of high-level radioactive tank sludge: A critical literature review

    Energy Technology Data Exchange (ETDEWEB)

    McGinnis, C.P.; Welch, T.D.; Hunt, R.D.

    1997-12-31

    The Department of Energy (DOE) must treat and safely dispose of its radioactive tank contents, which can be separated into high-level waste (HLW) and low-level waste (LLW) fractions. Since the unit costs of treatment and disposal are much higher for HLW than for LLW, technologies to reduce the amount of HLW are being developed. A key process currently being studied to reduce the volume of HLW sludges is called enhanced sludge washing (ESW). This process removes, by water washes, soluble constituents such as sodium salts, and the washed sludge is then leached with 2--3 M NaOH at 60--100 C to remove nonradioactive metals such as aluminum. The remaining solids are considered to be HLW while the solutions are LLW after radionuclides such as {sup 137}Cs have been removed. Results of bench-scale tests have shown that the ESW will probably remove the required amounts of inert constituents. While both experimental and theoretical results have shown that leaching efficiency increases as the time and temperature of the leach are increased, increases in the caustic concentration above 2--3 M will only marginally improve the leach factors. However, these tests were not designed to validate the assumption that the caustic used in the ESW process will generate only a small increase (10 Mkg) in the amount of LLW; instead, the test conditions were selected to maximize leaching in a short period and used more water and caustic than is planned during full-scale operations. Even though calculations indicate that the estimate for the amount of LLW generated by the ESW process appears to be reasonable, a detailed study of the amount of LLW from the ESW process is still required. If the LLW analysis indicates that sodium management is critical, then a more comprehensive evaluation of the clean salt process or caustic recycle would be needed. Finally, experimental and theoretical studies have clearly demonstrated the need for the control of solids formation during and after leaching.

  8. Caustic leaching of high-level radioactive tank sludge: A critical literature review

    Energy Technology Data Exchange (ETDEWEB)

    McGinnis, C.P.; Welch, T.D.; Hunt, R.D.

    1998-08-01

    The Department of Energy (DOE) must treat and safely dispose of its radioactive tank contents, which can be separated into high-level waste (HLW) and low-level waste (LLW) fractions. Since the unit costs of treatment and disposal are much higher for HLW than for LLW, technologies to reduce the amount of HLW are being developed. A key process currently being studied to reduce the volume of HLW sludges is called enhanced sludge washing (ESW). This process removes, by water washes, soluble constituents such as sodium salts, and the washed sludge is then leached with 2--3 M NaOH at 60--100 C to remove nonradioactive metals such as aluminum. The remaining solids are considered to be HLW while the solutions are LLW after radionuclides such as {sup 137}Cs have been removed. Results of bench-scale tests have shown that the ESW will probably remove the required amounts of inert constituents. While both experimental and theoretical results have shown that leaching efficiency increases as the time and temperature of the leach are increased, increases in the caustic concentration above 2--3 M will only marginally improve the leach factors. However, these tests were not designed to validate the assumption that the caustic used in the ESW process will generate only a small increase (10 Mkg) in the amount of LLW; instead the test conditions were selected to maximize leaching in a short period and used more water and caustic than is planned during full-scale operations. Even though calculations indicate that the estimate for the amount of LLW generated by the ESW process appears to be reasonable, a detailed study of the amount of LLW from the ESW process is still required. If the LLW analysis indicates that sodium management is critical, then a more comprehensive evaluation of the clean salt process or caustic recycle would be needed. Finally, experimental and theoretical studies have clearly demonstrated the need for the control of solids formation during and after leaching.

  9. Characterization of irregular seeds on gibbsites precipitated from caustic aluminate solutions

    Institute of Scientific and Technical Information of China (English)

    CHEN Guo-hui; CHEN Qi-yuan; YIN Zhou-lan; YIN Zhi-min

    2006-01-01

    The irregular surface of seeds on which gibbsites are precipitated from caustic aluminate solutions, was investigated according to the fractal theory. Two kinds of fractal dimensions were used to characterize these irregularity. Box-dimension and spectral dimension are based on the SEM images of seeds and diffusive dynamic equation ofthe precipitation respectively. Both these two dimensions are affected by the reaction temperature, evolved with different reaction conditions and can reflect the influence of irregularity of seeds on the precipitation rate. Box dimension is fit for the characterization of the irregular morphology of seeds, while spectral dimension can explain the fractal dynamic behavior.

  10. Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products

    Science.gov (United States)

    Barney, Gary S.; Brownell, Lloyd E.

    1977-01-01

    A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

  11. Demonstration of Caustic-Side Solvent Extraction with Savannah River Site High Level Waste

    Energy Technology Data Exchange (ETDEWEB)

    Walker, D.D.

    2001-08-27

    Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet for the decontamination of high level waste using a 33-stage, 2-cm centrifugal contactor apparatus at the Savannah River Technology Center. This represents the first CSSX process demonstration using Savannah River Site (SRS) high level waste. Three tests lasting 6, 12, and 48 hours processed simulated average SRS waste, simulated Tank 37H/44F composite waste, and Tank 37H/44F high level waste, respectively.

  12. Caustic waterflooding demonstration project: Ranger Zone, Long Beach Unit, Wilmington Field, California. Third annual report, June 1978-May 1979

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, E.H.

    1979-12-01

    A caustic-enhanced waterflooding pilot test is being conducted in the Ranger Reservoir of the Long Beach Unit, Wilmington Field, California. Evaluation of entrapment and entrainment caustic flooding in Ranger Zone cores was continued. The caustic-only (entrapment) core floods failed to demonstrate improved behavior. Based on the unfavorable results of all tests of the entrapment mechanism, further laboratory work and flooding in the pilot with caustic alone have been eliminated from the project's plans. Some of the year's caustic-salt (entrainment) core floods in contrast showed both substantial recovery and WOR improvement. The poorer overall entrainment core flood results obtained in the year may be due to the core material, a smaller preflush volume used or the crude oil employed. Core flood testing where sodium silicate is substituted for some of the sodium hydroxide, was continued. The primary set of caustic water-oil dehydration tests was completed. The test softening of produced waters was completed and the results evaluated; produced water softening was found to be an economically feasible alternative to the use of fresh water. The preflush injection facilities became operational in January 1979 with the pilot's preflush officially begun April 15, 1979. The alkaline injection facility was expanded in scope to permit use of both sodium silicate and sodium hydroxide; its completion in late 1979 is anticipated with the alkaline-salt injection scheduled to begin at that time. The base case reservoir simulator prediction of the pilot under continued waterflooding was completed. This prediction provided the base line from which incremental alkaline flood production will be determined, as the test has now been declared a qualified tertiary enhanced recovery project by DOE's Economic Regulatory Administration. Major well repair/redrill work continued to be necessary exceeding earlier increased cost estimates.

  13. Origami constraints on the initial-conditions arrangement of dark-matter caustics and streams

    CERN Document Server

    Neyrinck, Mark C

    2012-01-01

    In a cold-dark-matter universe, cosmological structure formation proceeds in rough analogy to origami folding. Dark matter occupies a three-dimensional 'sheet,' non-intersecting in six-dimensional velocity-position phase space. At early times, the sheet was flat like an origami sheet, i.e. velocities were essentially zero. The present paper further illustrates this analogy, and identifies a result of origami mathematics that applies to cosmology. We define caustics in the initial conditions Lagrangian space) as surfaces in this sheet, along which the sheet has folded. The regions outlined by these caustics, which we call streams, may be colored according to the two possible orientations of initial basis vectors, a two-coloring such that adjacent streams are not colored the same. While this may not have clear observational consequences, it is a severe restriction on connectivity, since there are no bounds on the number of colors required to color a general arrangement of three-dimensional regions. Then, measur...

  14. Direct anodic hydrochloric acid and cathodic caustic production during water electrolysis

    Science.gov (United States)

    Lin, Hui-Wen; Cejudo-Marín, Rocío; Jeremiasse, Adriaan W.; Rabaey, Korneel; Yuan, Zhiguo; Pikaar, Ilje

    2016-02-01

    Hydrochloric acid (HCl) and caustic (NaOH) are among the most widely used chemicals by the water industry. Direct anodic electrochemical HCl production by water electrolysis has not been successful as current commercially available electrodes are prone to chlorine formation. This study presents an innovative technology simultaneously generating HCl and NaOH from NaCl using a Mn0.84Mo0.16O2.23 oxygen evolution electrode during water electrolysis. The results showed that protons could be anodically generated at a high Coulombic efficiency (i.e. ≥ 95%) with chlorine formation accounting for 3 ~ 5% of the charge supplied. HCl was anodically produced at moderate strengths at a CE of 65 ± 4% together with a CE of 89 ± 1% for cathodic caustic production. The reduction in CE for HCl generation was caused by proton cross-over from the anode to the middle compartment. Overall, this study showed the potential of simultaneous HCl and NaOH generation from NaCl and represents a major step forward for the water industry towards on-site production of HCl and NaOH. In this study, artificial brine was used as a source of sodium and chloride ions. In theory, artificial brine could be replaced by saline waste streams such as Reverse Osmosis Concentrate (ROC), turning ROC into a valuable resource.

  15. Additives effects on crystallization and morphology in a novel caustic aluminate solution decomposition process

    Institute of Scientific and Technical Information of China (English)

    Ying ZHANG; Sbili ZHENG; Yifei ZHANG; Hongbin XU; Yi ZHANG

    2009-01-01

    A novel process of caustic aluminate solution decomposition by alcohol medium was developed by the Institute of Process Engineering, Chinese Academy of Sciences in order to solve the problem of low decomposi-tion ratio in the traditional Bayer seeded hydrolysis process. In this research, effects of additives on the crystallization ratio, secondary particle size and morphol-ogy of aluminum hydroxide in the new process were studied to obtain high-quality products. On the basis of primary selection of additives, an orthogonal design L9(34)was used as a chemometric method to investigate the effects of additives. The studied parameters include the reaction style, quantity of additives, caustic soda concen-tration, as well as the combination manner. The crystal-lization ratios of sodium aluminate solution and crystal size of aluminum hydroxide, determined by ICP-OES, SEM and MLPSA (Malvern Laser Particle Size Analyzer), were used to evaluate the effects of the additives. The results showed that different combination manners could promote agglomeration or dispersion. An additive composed by Tween 80 and PEG 200 could promote agglomeration,while a spot of PEG species had a relatively strong dispersion effect. However, the additives had little effects on the crystallization ratios. According to the Raman spectra result, the added alcohol medium might serve as a kind of solvent.

  16. Cuspidal caustic and focusing of acoustical waves generated by a parametric array onto a concave reflecting surface

    Science.gov (United States)

    Castagnède, Bernard; Sahraoui, Sohbi; Tournat, Vincent; Tahani, Najat

    2009-09-01

    The present Note is devoted to the study of the so-called cuspidal caustic at the surface of a hemi-cylindrical reflector illuminated with plane waves. In order to generate low frequency (e.g. in the range of 4 kHz) acoustical plane waves, a commercially available parametric array has been used. It produces powerful ultrasonic carrier waves at 40 kHz which can be electronically modulated between 200 Hz and 10 kHz. Further self-demodulation process during propagation in air generates an ultra-directive acoustical field (i.e. quasi-planar wavefronts) enabling to accurately study the focusing process occurring along the cuspidal caustic. The focusing coefficient can be computed locally by using two numerical tools, on one hand by computing the density of tangent rays to the caustic, and on the other hand by using some numerical results provided by a ray tracing algorithm. Some preliminary experimental data are then provided in order to validate the numerical predictions (spatial position of the caustic and focusing coefficient). To cite this article: B. Castagnède et al., C. R. Mecanique 337 (2009).

  17. THE CHEMICAL AND RADIATION RESISTANCE OF POLYPHENYLENE SULFIIDE AS ENCOUNTERED IN THE MODULAR CAUSTIC SIDE SOLVENT EXTRACTION PROCESSES

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F.; Herman, D.; Poirier, M.; Fink, S.

    2011-06-30

    Polyphenylene sulfide (PPS) is a semicrystalline polymer with excellent engineering plastic properties and suitable processing temperatures. PPS can also be made containing branches (using a trifunctional monomer) and with crosslinked microstructure (when curing the monomer at high temperature in the presence of oxygen). PPS is made from the condensation reaction between para-dichlorobenzene and sodium sulfide with the assistance of a catalyst (to lower the activation barrier). The synthesis conditions for making PPS has evolved since its invention in the 1960's to the optimal conditions developed by the Philips Corporation in the 1970's. The resulting polymer consists of chemically stable molecular moieties such as benzene rings and ether like sulfur linkages between the aromatic rings. Polyphenylene sulfide (PPS) is extremely resistant to gamma irradiation, caustic solution, and dilute nitric acid. PPS is the material of construction for the coalescers used in the Modular Caustic-Side Solvent Extraction Unit (MCU). After applying the equivalent of 3.3 E8 rad (330 Mrad), or the equivalent of 11 years of gamma irradiation (assuming a stripping solution concentration of 7.5 Ci/gal), and several months of exposures to 3M caustic solution and caustic salt simulant, no dimensional changes nor chemical changes were detected in PPS whether the PPS was in fiber form or in a composite with E-glass fibers. However, PPS acts as a media for heterogeneous nucleation. In particular, PPS appears to favor aluminosilicate formation in saturated solutions of aluminum and silicon in caustic environments. Parallel testing, in progress, is examining the stability of PPS when exposed to the new solvent formulation under development for MCU. Preliminary data, after two months of exposure, demonstrates PPS is stable to the new solvent.

  18. EFRT M-12 Issue Resolution: Caustic-Leach Rate Constants from PEP and Laboratory-Scale Tests

    Energy Technology Data Exchange (ETDEWEB)

    Mahoney, Lenna A.; Rassat, Scot D.; Eslinger, Paul W.; Aaberg, Rosanne L.; Aker, Pamela M.; Golovich, Elizabeth C.; Hanson, Brady D.; Hausmann, Tom S.; Huckaby, James L.; Kurath, Dean E.; Minette, Michael J.; Sundaram, S. K.; Yokuda, Satoru T.

    2010-01-01

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. The work described in this report addresses caustic leaching under WTP conditions, based on tests performed with a Hanford waste simulant. Because gibbsite leaching kinetics are rapid (gibbsite is expected to be dissolved by the time the final leach temperature is reached), boehmite leach kinetics are the main focus of the caustic-leach tests. The tests were completed at the laboratory-scale and in the PEP, which is a 1/4.5-scale mock-up of key PTF process equipment. Two laboratory-scale caustic-leach tests were performed for each of the PEP runs. For each PEP run, unleached slurry was taken from the PEP caustic-leach vessel for one batch and used as feed for both of the corresponding laboratory-scale tests.

  19. The Caustic Alkali-free Water Extraction Agents for Treating Inner Mongolia Oil Sands

    Institute of Scientific and Technical Information of China (English)

    Shen Zhibing; Zhang Juntao; Zhang Jie; Liang Shengrong

    2014-01-01

    The caustic alkali-free water extraction agents were studied for treating the oil sands excavated from Inner Mon-golia, China. Several kinds of chemical reagents were evaluated, among which sodium carbonate (SC), sodium dodecyl benzene sulfonate (SD) and sodium chloride were conifrmed as composite solutes. Their proportion was optimized by an orthogonal test. The optimum proportion of the composite agent covered 0.03%of SD, 0.50%of sodium chloride, 3.00%of SC, with the rest composed of water. The optimal operating condition was also conifrmed. The oil sands were extracted at the following optimized conditions:a treating time of 15 min, a temperature of 80℃and an extraction agent/feed ratio of 1:1, with the bitumen yield reaching more than 96%. The extraction agent after separation from the bitumen product can be recycled for reuse to carve out a good environmentally friendly route.

  20. Predictive Factors of Gastrointestinal Caustic Injury According to Clinical and Endoscopic Findings

    Directory of Open Access Journals (Sweden)

    Cherie Quingking

    2013-03-01

    Full Text Available Background: Ingestion of caustic substances is the main reason for referral to Philippines National Poison Management and Control Center among other causes of acute poisoning. Rapid assessment of severity of injury is important for treatment and prognosis of these cases. This study was aimed to investigate the correlation of clinical factors with severity of gastrointestinal (GI mucosal injury. Methods: In this retrospective study, a total of 105 patients were included. Patients were categorized into two groups including 35 patients with low grade and 70 patients with high grade GI injury to compare the predictive value of clinical findings. Results: Mean (SD age of patients was 27 (10 and 47% of patients were male. Oral burns (P

  1. Probe of Multi-electron Dynamics in Xenon by Caustics in High Order Harmonic Generation

    CERN Document Server

    Faccialà, Davide; Bruner, Barry D; Ciriolo, Anna G; De Silvestri, Sandro; Devetta, Michele; Negro, Matteo; Soifer, Hadas; Stagira, Salvatore; Dudovich, Nirit; Vozzi, Caterina

    2016-01-01

    We investigated the giant resonance in Xenon by high-order harmonic generation spectroscopy driven by a two-color field. The addition of a non-perturbative second harmonic component parallel to the driving field breaks the symmetry between neighboring sub-cycles resulting in the appearance of spectral caustics at two distinct cut-off energies. By controlling the phase delay between the two color components it is possible to tailor the harmonic emission in order to amplify and isolate the spectral feature of interest. In this paper we demonstrate how this control scheme can be used to investigate the role of electron correlations that give birth to the giant resonance in Xenon. The collective excitations of the giant dipole resonance in Xenon combined with the spectral manipulation associated with the two color driving field allow to see features that are normally not accessible and to obtain a quantitative good agreement between the experimental results and the theoretical predictions.

  2. Probe of Multielectron Dynamics in Xenon by Caustics in High-Order Harmonic Generation

    Science.gov (United States)

    Faccialà, D.; Pabst, S.; Bruner, B. D.; Ciriolo, A. G.; De Silvestri, S.; Devetta, M.; Negro, M.; Soifer, H.; Stagira, S.; Dudovich, N.; Vozzi, C.

    2016-08-01

    We investigated the giant resonance in xenon by high-order harmonic generation spectroscopy driven by a two-color field. The addition of a nonperturbative second harmonic component parallel to the driving field breaks the symmetry between neighboring subcycles resulting in the appearance of spectral caustics at two distinct cutoff energies. By controlling the phase delay between the two color components it is possible to tailor the harmonic emission in order to amplify and isolate the spectral feature of interest. In this Letter we demonstrate how this control scheme can be used to investigate the role of electron correlations that give birth to the giant resonance in xenon. The collective excitations of the giant dipole resonance in xenon combined with the spectral manipulation associated with the two-color driving field allow us to see features that are normally not accessible and to obtain a good agreement between the experimental results and the theoretical predictions.

  3. K-Area/Caustic Basin Groundwater Monitoring Report. Second quarter 1993

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, C.Y.

    1993-09-01

    During second quarter 1993, samples from the KAC monitoring wells at the K-Area Acid/Caustic Basin were collected and analyzed for indicator parameters, groundwater quality parameters, parameters indicating suitability as drinking water, and other constituents. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standard during the quarter are discussed in this report. No analytes exceeded the final PDWS during second quarter 1993. Aluminum exceeded its Flag 2 criterion in wells KAC 6, 7, and 9. Iron exceeded the Flag 2 criterion in wells KAC 6 and 7, and specific conductance exceeded the Flag 2 criterion in well KAC 9. No samples exceeded the SRS turbidity standard.

  4. Free-fall accretion and emitting caustics in wind-fed X-ray sources

    Science.gov (United States)

    Illarionov, Andrei F.; Beloborodov, Andrei M.

    2001-05-01

    In wind-fed X-ray binaries the accreting matter is Compton-cooled and falls freely on to the compact object. The matter has a modest angular momentum l and accretion is quasi-spherical at large distances from the compact object. Initially small non-radial velocities grow in the converging supersonic flow and become substantial in the vicinity of the accretor. The streamlines with l>(GMR*)1/2 (where M and R* are the mass and radius of the compact object) intersect outside R* and form a two-dimensional caustic which emits X-rays. The streamlines with low angular momentum, lorbital phase of the binary. The accretor then appears as a `Moon-like' X-ray source.

  5. Effect of solvent addition sequence on lycopene extraction efficiency from membrane neutralized caustic peeled tomato waste.

    Science.gov (United States)

    Phinney, David M; Frelka, John C; Cooperstone, Jessica L; Schwartz, Steven J; Heldman, Dennis R

    2017-01-15

    Lycopene is a high value nutraceutical and its isolation from waste streams is often desirable to maximize profits. This research investigated solvent addition order and composition on lycopene extraction efficiency from a commercial tomato waste stream (pH 12.5, solids ∼5%) that was neutralized using membrane filtration. Constant volume dilution (CVD) was used to desalinate the caustic salt to neutralize the waste. Acetone, ethanol and hexane were used as direct or blended additions. Extraction efficiency was defined as the amount of lycopene extracted divided by the total lycopene in the sample. The CVD operation reduced the active alkali of the waste from 0.66 to lycopene efficiently from tomato processing byproducts.

  6. Synthesis of ZnS thin films from aqueous caustic of trisodium citrate and their properties

    Directory of Open Access Journals (Sweden)

    Martyn A. Sozanskyi

    2015-12-01

    Full Text Available Zinc sulfide (ZnS thin films due to their properties are widely used in various electronic optical devices. They are produced by several methods, among which – vacuum sublimation, high frequency sputtering method, quasiclosed volume method, sol-gel method, electrodeposition. These methods have high energy consumption which increases the price of ZnS thin films. Aim: The aim of this work is to establish the optimal parameters of the synthesis of ZnS thin films of the aqueous caustic and the correlation between content of zinc in the synthesized films determined by the method of stripping voltammetry and thickness, structural, morphological and optical parameters. Materials and Methods: The ZnS thin films were obtained from aqueous caustics of zinc-containing salt using chemical deposition. Fresh solution of zinc-containing salt, trisodium citrate (Na3C6H5O7 as a complexing agent, thiourea ((NH22CS and ammonium hydroxide (NH4OH was used for the synthesis of ZnS films by chemical deposition. The deposition was performed on prepared glass substrates with the area of 5,76 cm2. Results: The phase mixture of the films has been determined. It showed the presence of ZnS compounds in the cubic modification (sphalerite. Stripping voltammetry was used to determine the mass of zinc in the ZnS films on various conditions of synthesis, namely on the concentration of the initial zinc-containing salt, trisodium citrate, thiourea, deposition time and temperature. The surface morphology, optical properties, the thickness of the ZnS resulting films have been studied. Conclusions: The optimal conditions for the synthesis of ZnS films were found based on these data. Three-dimensional surface morphology of ZnS film studies showed its smoothness, uniformity, integrity and confirmed the correctness of determining the optimal synthesis parameters.

  7. Next Generation Solvent Development for Caustic-Side Solvent Extraction of Cesium

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, Bruce A. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Birdwell, Joseph F. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Bonnesen, Peter V. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Bruffey, Stephanie [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

    2014-03-01

    This report summarizes the FY 2010 and 2011 accomplishments at Oak Ridge National Laboratory (ORNL) in developing the Next Generation Caustic-Side Solvent Extraction (NG-CSSX) process, referred to commonly as the Next Generation Solvent (NGS), under funding from the U.S. Department of Energy, Office of Environmental Management (DOE-EM), Office of Technology Innovation and Development. The primary product of this effort is a process solvent and preliminary flowsheet capable of meeting a target decontamination factor (DF) of 40,000 for worst-case Savannah River Site (SRS) waste with a concentration factor of 15 or higher in the 18-stage equipment configuration of the SRS Modular Caustic-Side Solvent Extraction Unit (MCU). In addition, the NG-CSSX process may be readily adapted for use in the SRS Salt Waste Processing Facility (SWPF) or in supplemental tank-waste treatment at Hanford upon appropriate solvent or flowsheet modifications. Efforts in FY 2010 focused on developing a solvent composition and process flowsheet for MCU implementation. In FY 2011 accomplishments at ORNL involved a wide array of chemical-development activities and testing up through single-stage hydraulic and mass-transfer tests in 5-cm centrifugal contactors. Under subcontract from ORNL, Argonne National Laboratory (ANL) designed a preliminary flowsheet using ORNL cesium distribution data, and Tennessee Technological University confirmed a chemical model for cesium distribution ratios (DCs) as a function of feed composition. Inter laboratory efforts were coordinated with complementary engineering tests carried out (and reported separately) by personnel at Savannah River National Laboratory (SRNL) and Savannah River Remediation (SRR) with helpful advice by Parsons Engineering and General Atomics on aspects of possible SWPF implementation.

  8. Next Generation Solvent (NGS): Development for Caustic-Side Solvent Extraction of Cesium

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, Bruce A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Birdwell, Jr, Joseph F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bonnesen, Peter V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Delmau, Laetitia Helene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Duncan, Nathan C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ensor, Dale [Tennessee Technological Univ., Cookeville, TN (United States); Hill, Talon G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lee, Denise L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Rajbanshi, Arbin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Roach, Benjamin D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Szczygiel, Patricia L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sloop, Jr., Frederick V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stoner, Erica L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Williams, Neil J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-03-01

    This report summarizes the FY 2010 and 2011 accomplishments at Oak Ridge National Laboratory (ORNL) in developing the Next Generation Caustic-Side Solvent Extraction (NG-CSSX) process, referred to commonly as the Next Generation Solvent (NGS), under funding from the U.S. Department of Energy, Office of Environmental Management (DOE-EM), Office of Technology Innovation and Development. The primary product of this effort is a process solvent and preliminary flowsheet capable of meeting a target decontamination factor (DF) of 40,000 for worst-case Savannah River Site (SRS) waste with a concentration factor of 15 or higher in the 18-stage equipment configuration of the SRS Modular Caustic-Side Solvent Extraction Unit (MCU). In addition, the NG-CSSX process may be readily adapted for use in the SRS Salt Waste Processing Facility (SWPF) or in supplemental tank-waste treatment at Hanford upon appropriate solvent or flowsheet modifications. Efforts in FY 2010 focused on developing a solvent composition and process flowsheet for MCU implementation. In FY 2011 accomplishments at ORNL involved a wide array of chemical-development activities and testing up through single-stage hydraulic and mass-transfer tests in 5-cm centrifugal contactors. Under subcontract from ORNL, Argonne National Laboratory (ANL) designed a preliminary flowsheet using ORNL cesium distribution data, and Tennessee Technological University confirmed a chemical model for cesium distribution ratios (DCs) as a function of feed composition. Interlaboratory efforts were coordinated with complementary engineering tests carried out (and reported separately) by personnel at Savannah River National Laboratory (SRNL) and Savannah River Remediation (SRR) with helpful advice by Parsons Engineering and General Atomics on aspects of possible SWPF implementation.

  9. Next Generation Solvent Performance in the Modular Caustic Side Solvent Extraction Process - 15495

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Tara E. [Savannah River Remediation, LLC., Aiken, SC (United States); Scherman, Carl [Savannah River Remediation, LLC., Aiken, SC (United States); Martin, David [Savannah River Remediation, LLC., Aiken, SC (United States); Suggs, Patricia [Savannah River Site (SRS), Aiken, SC (United States)

    2015-01-14

    Changes to the Modular Caustic Side Solvent Extraction Unit (MCU) flow-sheet were implemented in the facility. Implementation included changing the scrub and strip chemicals and concentrations, modifying the O/A ratios for the strip, scrub, and extraction contactor banks, and blending the current BoBCalixC6 extractant-based solvent in MCU with clean MaxCalix extractant-based solvent. During the successful demonstration period, the MCU process was subject to rigorous oversight to ensure hydraulic stability and chemical/radionuclide analysis of the key process tanks (caustic wash tank, solvent hold tank, strip effluent hold tank, and decontaminated salt solution hold tank) to evaluate solvent carryover to downstream facilities and the effectiveness of cesium removal from the liquid salt waste. Results indicated the extraction of cesium was significantly more effective with an average Decontamination Factor (DF) of 1,129 (range was 107 to 1,824) and that stripping was effective. The contactor hydraulic performance was stable and satisfactory, as indicated by contactor vibration, contactor rotational speed, and flow stability; all of which remained at or near target values. Furthermore, the Solvent Hold Tank (SHT) level and specific gravity was as expected, indicating that solvent integrity and organic hydraulic stability were maintained. The coalescer performances were in the range of processing results under the BOBCalixC6 flow sheet, indicating negligible adverse impact of NGS deployment. After the Demonstration period, MCU began processing via routine operations. Results to date reiterate the enhanced cesium extraction and stripping capability of the Next Generation Solvent (NGS) flow sheet. This paper presents process performance results of the NGS Demonstration and continued operations of MCU utilizing the blended BobCalixC6-MaxCalix solvent under the NGS flowsheet.

  10. PEP Integrated Test D Run Report Caustic and Oxidative Leaching in UFP-VSL-T02A

    Energy Technology Data Exchange (ETDEWEB)

    Sevigny, Gary J.; Bredt, Ofelia P.; Burns, Carolyn A.; Kurath, Dean E.; Geeting, John GH; Golovich, Elizabeth C.; Guzman-Leong, Consuelo E.; Josephson, Gary B.

    2009-12-11

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes" of the External Flowsheet Review Team (EFRT) issue response plan. The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario (Test B and D) has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario (Test A) has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP VSL-00001A and B in the WTP PTF). In Test D, 19M sodium hydroxide (NaOH, caustic) was added to the waste slurry in the UFP VSL T02 vessel after the solids were concentrated to ~20% undissolved solids. The NaOH was added to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by heating to 85°C using direct injection of steam to accelerate the leach process. The main difference of Test D compared to Test B is that the leach temperature is 85°C for 24 hrs as compared to 100°C for 12 hours. The other difference is the Test D simulant had Cr in the

  11. Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Susan Kay; Orchard, B. J.

    2002-01-01

    This Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about the project description, project organization, and quality assurance and quality control procedures, is to be used in conjunction with the Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System. This Quality Assurance Project Plan specifies the procedures for obtaining the data of known quality required by the closure activities for the TRA-731 caustic and acid storage tank system.

  12. Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    Energy Technology Data Exchange (ETDEWEB)

    Evans, S.K.

    2002-01-31

    This Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA- 731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about the project description, project organization, and quality assurance and quality control procedures, is to be used in conjunction with the Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System. This Quality Assurance Project Plan specifies the procedures for obtaining the data of known quality required by the closure activities for the TRA-731 caustic and acid storage tank system.

  13. Synthesis and characterization of TiO2 from ilmenite by caustic fusion process for photocatalytic application

    Science.gov (United States)

    Mulyono, J. E.; Soepriyanto, S.

    2017-01-01

    In this research, the use of TiO2 from Indonesian ilmenite will be developed using caustic fusion process and made into photocatalyst product that will be applied for water treatment applications. The research procedures include caustic fusion process involving the mixing of NaOH and ilmenite with a ratio of 1 : 4 at 650°C for 120 minutes. The result from this caustic fusion process, i.e. frit, was then washed with water and followed by acid leaching using sulfuric acid 45% to obtain precursor TiOSO4. This precursor was then hydrolyzed to produce white precipitates in the form of sol TiO(OH)2 which was then condensed for 24 hours. The precipitate was washed and dried before calcined at a temperature of 500°C for 1 hour. X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDX) analysis is included to show the phases, morphology and the final composition of the synthesized TiO2 powder. UV-Vis Spectrometry was also used to calculate the band-gap energy and the photocatalytic ability of the synthesized TiO2 in the purification process of rhodamin-B.

  14. Simulations of sonic boom ray tube area fluctuations for propagation through atmospheric turbulence including caustics via a Monte Carlo method

    Science.gov (United States)

    Sparrow, Victor W.; Pierce, Allan D.

    1992-01-01

    A theory which gives statistical predictions for how often sonic booms propagating through the earth's turbulent boundary layer will encounter caustics, given the spectral properties of the atmospheric turbulence, is outlined. The theory is simple but approximately accounts for the variation of ray tube areas along ray paths. This theory predicts that the variation of ray tube areas is determined by the product of two similar area factors, psi (x) and phi (x), each satisfying a generic harmonic oscillator equation. If an area factor increases the peak acoustic pressure decreases, and if the factor decreases the peak acoustic pressure increases. Additionally, if an area factor decreases to zero and becomes negative, the ray has propagated through a caustic, which contributes a phase change of 90 degrees to the wave. Thus, it is clear that the number of times that a sonic boom wave passes through a caustic should be related to the distorted boom waveform received on the ground. Examples are given based on a characterization of atmospheric turbulence due to the structure function of Tatarski as modified by Crow.

  15. STATISTICS OF MICROLENSING CAUSTIC CROSSINGS IN Q 2237+0305: PECULIAR VELOCITY OF THE LENS GALAXY AND ACCRETION DISK SIZE

    Energy Technology Data Exchange (ETDEWEB)

    Mediavilla, E. [Instituto de Astrofísica de Canarias, Vía Láctea S/N, La Laguna E-38200 Tenerife (Spain); Jimenez-Vicente, J. [Departamento de Física Teórica y del Cosmos, Universidad de Granada, Campus de Fuentenueva E-18071 Granada (Spain); Muñoz, J. A. [Departamento de Astronomía y Astrofísica, Universidad de Valencia E-46100 Burjassot, Valencia (Spain); Mediavilla, T.; Ariza, O. [Departamento de Estadística e Investigación Operativa, Universidad de Cádiz, Avda Ramón Puyol s/n E-11202, Algeciras, Cádiz (Spain)

    2015-01-10

    We use the statistics of caustic crossings induced by microlensing in the lens system Q 2237+0305 to study the lens galaxy peculiar velocity. We calculate the caustic crossing rates for a comprehensive family of stellar mass functions and find a dependence of the average number of caustic crossings with the effective transverse velocity and the average mass, 〈n〉∝v{sub eff}/√(〈m〉), equivalent to the theoretical prediction for the case of microlenses with identical masses. We explore the possibilities of the method to measure v {sub eff} using the ∼12 yr of Optical Gravitational Lensing Experiment monitoring of the four images of Q 2237+0305. To determine a lower limit for v {sub eff}, we count, conservatively, a single caustic crossing for each one of the four high magnification events identified in the literature (plus one additional proposed by us) obtaining v{sub eff}≳240√(〈m〉/0.17 M{sub ⊙}) km s{sup −1} at 68% of confidence. From this value and the average FWHM of the four high magnification events, we obtain a lower limit of r{sub s}≳1.4√(〈m〉/0.17 M{sub ⊙}) light-days for the radius of the source (r{sub s} = FWHM/2.35). Tentative identification of three additional caustic crossing events leads to estimates of v{sub eff}≃(493±246)√(〈m〉/0.17 M{sub ⊙}) km s{sup −1} for the effective transverse velocity and of r{sub s}≃(2.7±1.3)√(〈m〉/0.17 M{sub ⊙}) light-days for the source size. The estimated transverse peculiar velocity of the galaxy is v{sub t}≃(429±246)√(〈m〉/0.17 M{sub ⊙}) km s{sup −1}.

  16. Caustic Hydrogen Peroxide Treatment of Effluent from Cassava Processing Industry: Prospects and Limitations

    Directory of Open Access Journals (Sweden)

    Olayinka Omotosho

    2015-04-01

    Full Text Available Cassava has been described as a major part of diet in most African countries. Its processing usually requires the release of polluted effluent which has been found to be toxic, carcinogenic as well as mutagenic to some extent. In this study, the treatment process comprised of a combination of peroxide oxidation at caustic range and filtration which ensured that the key pollutant, Cyanide was converted to cyanate. Metal and other non-metal pollutants were filtered off with the aid of a graded sand filter after undergoing hydroxide formation and precipitation. Results from the study shows that an optimum dosage of 0.3mg/l was adequate for Cyanide destruction and hydroxide precipitation reactions. A comparison of the effluent from the treatment process with FEPA standards for waste water discharge shows that most of the pollutant parameters were within acceptable limits after the treatment with the exception of PO4 and BOD5. However when compared with Canadian Water Quality Guidelines for Irrigation the only parameter outstanding was the BOD5. As a result of the inadequacy of the process in handling the phosphate and biological load content of the wastewater, It is proposed that an additional treatment method such as sorption using activated carbon or use of a combined baffle flocculation and aeration techniques will be appropriate if the water is to be discharged safely into water courses or even for irrigation purposes.

  17. Caustic Injury In Adults – A Study For 3 Year Period

    Directory of Open Access Journals (Sweden)

    Radenkova-Saeva J.

    2016-10-01

    Full Text Available The aim of the study is to present the results of a 3-year clinico-epidemiological investigation of caustic injury in adults. The study includes 43 patients with acute corrosive ingestion, hospitalized in the Toxicology Clinic, University Hospital “N. I. Pirogov”, Sofia, Bulgaria, for the period 01.01. 2010-31.12.2012. The methods used include: clinical observation and examination, clinical laboratory, imaging, and psychiatric methods and tests. 43 patients between the ages of 22 and 82 with acute corrosive ingestions have been observed. Eleven were male (25.6% and 32 female (74.4%. All ingestions were intentional. Alkaline agents were used by all of the patients. The severity of poisonings varied from moderate to extremely severe. Different complications were seen in 82% of the cases - severe bleeding, perforation, fistula or/and stricture formation. Two of the patients have undergone surgical intervention - coloesophagoplastic - and have recovered completely. The motivation in different age groups was also studied. Psychiatric comorbidity occurred in patients as depressive and schizoaffective disorder, as well as existential crises. Acute corrosive ingestions by alkaline agents cause severe pathology. The severity and complex character of the injuries require good coordination between different medical specialists.

  18. Free-fall accretion and emitting caustics in wind-fed X-ray sources

    CERN Document Server

    Illarionov, A F; Illarionov, Andrei F.; Beloborodov, Andrei M.

    2000-01-01

    In wind-fed X-ray binaries, the accreting matter is Compton cooled and falls freely onto the compact object. The matter has a modest angular momentum, $l$, and accretion is quasi-spherical at large distances from the compact object. Initially small non-radial velocities grow in the converging supersonic flow and become substantial in the vicinity of the accretor. The streamlines with $l>(GMR_*)^{1/2}$ (where $M$ and $R_*$ are the mass and radius of the compact object) intersect outside $R_*$ and form a two-dimensional caustic which emits X-rays. The streamlines with low angular momentum, $l<(GMR_*)^{1/2}$, run into the accretor. If the accretor is a neutron star, a large X-ray luminosity results. We show that the distribution of accretion rate/luminosity over the star surface is sensitive to the angular momentum distribution of the accreting matter. The apparent luminosity depends on the side from which the star is observed and can change periodically with the orbital phase of the binary. The accretor then...

  19. Recommended Guanidine Suppressor for the Next-Generation Caustic-Side Solvent Extraction Process

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, Bruce A [ORNL; Delmau, Laetitia Helene [ORNL; Duncan, Nathan C [ORNL; Ensor, Dale [Tennessee Technological University; Hill, Talon G [ORNL; Lee, Denise L [ORNL; Roach, Benjamin D [ORNL; Sloop Jr, Frederick {Fred} V [ORNL; Williams, Neil J [ORNL

    2013-01-01

    The guanidine recommended for the Next-Generation Caustic-Side is N,N ,N -tris(3,7-dimethyloctyl)guanidine (TiDG). Systematic testing has shown that it is significantly more lipophilic than the previously recommended guanidine DCiTG, the active extractant in the commercial guanidine product LIX -79, while not otherwise changing the solvent performance. Previous testing indicated that the extent of partitioning of the DCiTG suppressor to the aqueous strip solution is significantly greater than expected, potentially leading to rapid depletion of the suppressor from the solvent and unwanted organic concentrations in process effluents. Five candidate guanidines were tested as potential replacements for DCiTG. The tests included batch extraction with simulated waste and flowsheet solutions, third-phase formation, emulsion formation, and partition ratios of the guanidine between the solvent and aqueous strip solution. Preliminary results of a thermal stability test of the TiDG solvent at one month duration indicated performance approximately equivalent to DCiTG. Two of the guanidines proved adequate in all respects, and the choice of TiDG was deemed slightly preferable vs the next best guanidine BiTABG.

  20. MODULAR CAUSTIC SIDE SOLVENT EXTRACTION UNIT GAMMA MONITORS SYSTEM FINAL REPORT

    Energy Technology Data Exchange (ETDEWEB)

    Casella, V

    2007-06-25

    The Department of Energy (DOE) selected Caustic-Side Solvent Extraction (CSSX) as the preferred technology for the removal of radioactive cesium from High-Level Waste (HLW) at the Savannah River Site (SRS). Before the full-scale Salt Waste Processing Facility (SWPF) becomes operational, the liquid Waste Organization (LWO) plans to process a portion of dissolved saltcake waste through a Modular CSSX Unit (MCU). This work was derived from Technical Task Request SP-TTR-2004-00013, ''Gamma Monitor for MCU.'' The deliverables for this task are the hardware and software for the gamma monitors and a report summarizing the testing and acceptance of this equipment for use in the MCU. Revision of this report is a deliverable in Technical Task Report SP-TTR-2006-00010, ''NaI Shield Box Testing.'' Gamma-ray monitors were developed to: {lg_bullet} Measure the Cs-137 concentration in the decontaminated salt solution before entering the DSS (Decontaminated Salt Solution) Hold Tank, {lg_bullet} Measure the Cs-137 concentration in the strip effluent before entering the Strip Effluent Hold Tank, {lg_bullet} Verify proper operation of the solvent extraction system by verifying material balance within the process (The DSS Hold Tank Cs-137 concentration will be very low and the Cs-137 concentration in the Strip Effluent Hold Tank will be approximately fifteen times higher than the Cs-137 concentration in the Feed Tank.)

  1. Washing and caustic leaching of Hanford tank sludges: Results of FY 1995 studies

    Energy Technology Data Exchange (ETDEWEB)

    Rapko, B.M.; Lumetta, G.J.; Wagner, M.J.

    1995-08-11

    During the past few years, the primary mission at the US Department of Energy`s Hanford Site has changed from producing plutonium to environmental restoration. Large volumes of high-level radioactive wastes (HLW), generated during past Pu production and other operations, are stored in underground tanks on site. The current plan for remediating the Hanford tank farms consists of waste retrieval, pretreatment, treatment (immobilization), and disposal. The HLW will be immobilized in a borosilicate glass matrix; the resulting glass canisters will then be disposed of in a geologic repository. Because of the expected high cost of HLW immobilization and disposal, pretreatment processes will be implemented to reduce the volume of borosilicate glass produced in processing the tank wastes. This document describes sludge washing and caustic leaching tests conducted in FY 1995 at the Pacific Northwest Laboratory (PNL) at the request of Westinghouse Hanford Company. These tests were performed using sludges from seven Hanford waste tanks -- B-111, BX-107, C-103, S-104, SY-103, T-104, and T-111. The primary and secondary types of waste stored in each of these tanks are given in Table 1. 1. The data collected in this effort will be used to support the March 1998 Tri-Party Agreement decision on the extent of pretreatment to be performed on the Hanford tank sludges (Ecology, EPA, and DOE 1994).

  2. CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F.; Fink, S.

    2011-12-08

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

  3. Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste

    Energy Technology Data Exchange (ETDEWEB)

    Fiskum, Sandra K.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Snow, Lanee A.

    2009-01-01

    This report describes the bench-scale pretreatment processing of actual tank waste materials through the entire baseline WTP pretreatment flowsheet in an effort to demonstrate the efficacy of the defined leaching processes on actual Hanford tank waste sludge and the potential impacts on downstream pretreatment processing. The test material was a combination of reduction oxidation (REDOX) tank waste composited materials containing aluminum primarily in the form of boehmite and dissolved S saltcake containing Cr(III)-rich entrained solids. The pretreatment processing steps tested included • caustic leaching for Al removal • solids crossflow filtration through the cell unit filter (CUF) • stepwise solids washing using decreasing concentrations of sodium hydroxide with filtration through the CUF • oxidative leaching using sodium permanganate for removing Cr • solids filtration with the CUF • follow-on solids washing and filtration through the CUF • ion exchange processing for Cs removal • evaporation processing of waste stream recycle for volume reduction • combination of the evaporated product with dissolved saltcake. The effectiveness of each process step was evaluated by following the mass balance of key components (such as Al, B, Cd, Cr, Pu, Ni, Mn, and Fe), demonstrating component (Al, Cr, Cs) removal, demonstrating filterability by evaluating filter flux rates under various processing conditions (transmembrane pressure, crossflow velocities, wt% undissolved solids, and PSD) and filter fouling, and identifying potential issues for WTP. The filterability was reported separately (Shimskey et al. 2008) and is not repeated herein.

  4. Electrochemical studies on stress corrosion cracking of incoloy-800 in caustic solution. Part II: Precracking samples

    Directory of Open Access Journals (Sweden)

    Dinu Alice

    2006-01-01

    Full Text Available Stress corrosion cracking (SCC in a caustic medium may affect the secondary circuit tubing of a CANDU NPP cooled with river water, due to an accidental formation of a concentrated alkaline environment in the areas with restricted circulation, as a result of a leakage of cooling water from the condenser. To evaluate the susceptibility of Incoloy-800 (used to manufacture steam generator tubes for CANDU NPP to SCC, some accelerated corrosion tests were conducted in an alkaline solution (10% NaOH, pH = 13. These experiments were performed at ambient temperature and 85 °C. We used the potentiodynamic method and the potentiostatic method, simultaneously monitoring the variation of the open circuit potential during a time period (E corr/time curve. The C-ring method was used to stress the samples. In order to create stress concentrations, mechanical precracks with a depth of 100 or 250 μm were made on the outer side of the C-rings. Experimental results showed that the stressed samples were more susceptible to SCC than the unstressed samples whereas the increase in temperature and crack depth lead to an increase in SCC susceptibility. Incipient micro cracks of a depth of 30 μm were detected in the area of the highest peak of the mechanical precrack.

  5. A comparative study between the use of artificial neural networks and multiple linear regression for caustic concentration prediction in a stage of alumina production

    Directory of Open Access Journals (Sweden)

    Giovanni Leopoldo Rozza

    2015-09-01

    Full Text Available With world becoming each day a global village, enterprises continuously seek to optimize their internal processes to hold or improve their competitiveness and make better use of natural resources. In this context, decision support tools are an underlying requirement. Such tools are helpful on predicting operational issues, avoiding cost risings, loss of productivity, work-related accident leaves or environmental disasters. This paper has its focus on the prediction of spent liquor caustic concentration of Bayer process for alumina production. Caustic concentration measuring is essential to keep it at expected levels, otherwise quality issues might arise. The organization requests caustic concentration by chemical analysis laboratory once a day, such information is not enough to issue preventive actions to handle process inefficiencies that will be known only after new measurement on the next day. Thereby, this paper proposes using Multiple Linear Regression and Artificial Neural Networks techniques a mathematical model to predict the spent liquor´s caustic concentration. Hence preventive actions will occur in real time. Such models were built using software tool for numerical computation (MATLAB and a statistical analysis software package (SPSS. The models output (predicted caustic concentration were compared with the real lab data. We found evidence suggesting superior results with use of Artificial Neural Networks over Multiple Linear Regression model. The results demonstrate that replacing laboratorial analysis by the forecasting model to support technical staff on decision making could be feasible.

  6. Caustic-Side Solvent Extraction Chemical and Physical Properties Progress in FY 2000 and FY 2001.

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, BA

    2002-04-17

    The purpose of this work was to provide chemical- and physical-property data addressing the technical risks of the Caustic-Side Solvent Extraction (CSSX) process as applied specifically to the removal of cesium from alkaline high-level salt waste stored at the US Department of Energy Savannah River Site. As part of the overall Salt Processing Project, this effort supported decision-making in regards to selecting a preferred technology among three alternatives: (1) CSSX, (2) nonelutable ion-exchange with an inorganic silicotitanate material and (3) precipitation with tetraphenylborate. High risks, innate to CSSX, that needed specific attention included: (1) chemical stability of the solvent matrix, (2) radiolytic stability of the solvent matrix, (3) proof-of-concept performance of the proposed process flowsheet with simulated waste, and (4) performance of the CSSX flowsheet with actual SRS high-level waste. This body of work directly addressed the chemical-stability risk and additionally provided supporting information that served to plan, carry out, and evaluate experiments conducted by other CSSX investigators addressing the other high risks. Information on cesium distribution in extraction, scrubbing, and stripping served as input for flowsheet design, provided a baseline for evaluating solvent performance under numerous stresses, and contributed to a broad understanding of the effects of expected process variables. In parallel, other measurements were directed toward learning how other system components distribute in the flowsheet. Such components include the solvent components themselves, constituents of the waste, and solvent-degradation products. Upon understanding which components influence flowsheet performance, it was then possible to address in a rational fashion how to clean up the solvent and maintain its stable function.

  7. Caustic-Side Solvent Extraction: Chemical and Physical Properties of the Optimized Solvent

    Energy Technology Data Exchange (ETDEWEB)

    Delmau, L.H.

    2002-10-08

    This work was undertaken to optimize the solvent used in the Caustic Side Solvent Extraction (CSSX) process and to measure key chemical and physical properties related to its performance in the removal of cesium from the alkaline high-level salt waste stored in tanks at the Savannah River Site. The need to adjust the solvent composition arose from the prior discovery that the previous baseline solvent was supersaturated with respect to the calixarene extractant. The following solvent-component concentrations in Isopar{reg_sign} L diluent are recommended: 0.007 M calix[4]arene-bis(tert-octylbenzo-crown-6) (BOBCalixC6) extractant, 0.75 M 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB) phase modifier, and 0.003 M tri-n-octylamine (TOA) stripping aid. Criteria for this selection included BOBCalixC6 solubility, batch cesium distribution ratios (D{sub Cs}), calculated flowsheet robustness, third-phase formation, coalescence rate (dispersion numbers), and solvent density. Although minor compromises within acceptable limits were made in flowsheet robustness and solvent density, significant benefits were gained in lower risk of third-phase formation and lower solvent cost. Data are also reported for the optimized solvent regarding the temperature dependence of D{sub Cs} in extraction, scrubbing, and stripping (ESS); ESS performance on recycle; partitioning of BOBCalixC6, Cs-7SB, and TOA to aqueous process solutions; partitioning of organic anions; distribution of metals; solvent phase separation at low temperatures; solvent stability to elevated temperatures; and solvent density and viscosity. Overall, the technical risk of the CSSX process has been reduced by resolving previously identified issues and raising no new issues.

  8. 离子膜法烧碱工艺改进%Process improvement of exchange membrane caustic soda production

    Institute of Scientific and Technical Information of China (English)

    许琼武

    2012-01-01

    Through addition of titanium heat exchanger, the steam condensed water recovery and utilization, vacuum dechlorination pipe renovation measures,the ionic membrane caustic soda device stable operation. Reduces energy consumption, improves the economic benefit.%通过新增钛换热器、蒸汽冷凝水回收利用、真空脱氯氯水管改造等措施,保证了离子膜烧碱生产装置的平稳运行,降低了能耗,提高了经济效益。

  9. MODULAR CAUSTIC SIDE SOLVENT EXTRACTION UNIT (MCU) GAMMA MONITORS SYSTEM FINAL REPORT

    Energy Technology Data Exchange (ETDEWEB)

    Casella, V

    2005-12-15

    The Department of Energy (DOE) selected Caustic-Side Solvent Extraction (CSSX) as the preferred technology for the removal of radioactive cesium from High-Level Waste (HLW) at the Savannah River Site (SRS). Before the full-scale Salt Waste Processing Facility (SWPF) becomes operational, the Closure Business Unit (CBU) plans to process a portion of dissolved saltcake waste through a Modular CSSX Unit (MCU). This work was derived from Technical Task Request SP-TTR-2004-00013, ''Gamma Monitor for MCU''. The deliverables for this task are the hardware and software for the gamma monitors and a report summarizing the testing and acceptance of this equipment for use in the MCU. Gamma-ray monitors are required to: (1) Measure the Cs-137 concentration in the decontaminated salt solution before entering the DSS (Decontaminated Salt Solution) Hold Tank, (2) Measure the Cs-137 concentration in the strip effluent before entering the Strip Effluent Hold Tank, (3) Verify proper operation of the solvent extraction system by verifying material balance within the process (The DSS Hold Tank Cs-137 concentration will be very low and the Cs-137 concentration in the Strip Effluent Hold Tank will be fifteen times higher than the Cs-137 concentration in the Feed Tank.) Sodium iodide monitors are used to measure the Cs-137 concentration in the piping before the DSS Hold tank, while GM monitors are used for Cs-137 measurements before the Strip Effluent Hold Tank. Tungsten shields were designed using Monte Carlo calculations and fabricated to reduce the process background radiation at the detector positions. These monitors were calibrated with NIST traceable standards that were specially made to be the same as the piping being monitored. Since this gamma ray monitoring system is unique, specially designed software was written and acceptance tested by Savannah River National Laboratory personnel. The software is a LabView-based application that serves as a unified

  10. Caustic-Side Solvent-Extraction Modeling for Hanford Interim Pretreatment System

    Energy Technology Data Exchange (ETDEWEB)

    Moyer, B.A.; Birdwell, J.F.; Delmau, L. H.; McFarlane, J.

    2008-06-01

    The purpose of this work is to examine the applicability of the Caustic-Side Solvent Extraction (CSSX) process for the removal of cesium from Hanford tank-waste supernatant solutions in support of the Hanford Interim Pretreatment System (IPS). The Hanford waste types are more challenging than those at the Savannah River Site (SRS) in that they contain significantly higher levels of potassium, the chief competing ion in the extraction of cesium. It was confirmed by use of the CSSX model that the higher levels of potassium depress the cesium distribution ratio (DCs), as validated by measurement of DCs values for four of eight specified Hanford waste-simulant compositions. The model predictions were good to an apparent standard error of ±11%. It is concluded from batch distribution experiments, physical-property measurements, equilibrium modeling, flowsheet calculations, and contactor sizing that the CSSX process as currently employed for cesium removal from alkaline salt waste at the SRS is capable of treating similar Hanford tank feeds. For the most challenging waste composition, 41 stages would be required to provide a cesium decontamination factor (DF) of 5000 and a concentration factor (CF) of 5. Commercial contacting equipment with rotor diameters of 10 in. for extraction and 5 in. for stripping should have the capacity to meet throughput requirements, but testing will be required to confirm that the needed efficiency and hydraulic performance are actually obtainable. Markedly improved flowsheet performance was calculated for a new solvent formulation employing the more soluble cesium extractant BEHBCalixC6 used with alternative scrub and strip solutions, respectively 0.1 M NaOH and 10 mM boric acid. The improved system can meet minimum requirements (DF = 5000 and CF = 5) with 17 stages or more ambitious goals (DF = 40,000 and CF = 15) with 19 stages. Potential benefits of further research and development are identified that would lead to reduced costs, greater

  11. Rectifying systems of ionic membrane caustic soda synchronized debugging%离子膜烧碱整流系统同步调试

    Institute of Scientific and Technical Information of China (English)

    朱琦; 孔强; 王小红

    2011-01-01

    论述了离子膜烧碱整流系统同步调试的原理、步骤和注意事项。%Discusses of rectifying systems for ionic membrane caustic soda synchronized debugging principles, steps and considerations.

  12. Application of injection of spent caustic sludge into sour water stripper%酸性水汽提塔注废碱渣工艺技术应用

    Institute of Scientific and Technical Information of China (English)

    刘静翔; 黄占修; 耿庆光; 孙宁飞

    2013-01-01

    中国石油化工股份有限公司洛阳分公司液态烃脱硫醇装置废碱渣年产量超过1 kt,原采用碱渣湿式氧化装置脱硫、浓硫酸中和、酸性水限流排放至炼油污水处理场处理工艺.该工艺存在浓硫酸中和碱渣作业风险大、酸性水低温盐结晶堵塞管线,作业过程恶臭气体环境污染大等问题.通过实施酸性水汽提塔注废碱渣技术改造,停用了碱渣湿式氧化装置,不再进行碱渣酸化处理.工业实践表明:废碱渣注入汽提塔后,净化水中约70%的固定铵可去除,酸性水汽提塔蒸汽单耗下降约10 kg/t,对总外排水水质几乎没有影响,取得了良好的经济效益和社会效益.%The liquid hydrocarbon sweetening unit in Sinopec Luoyang Company produced more than 1000 tons of caustic sludge each year.In the original design,the process of wet oxidation desulfurization,sulfuric acid neutralization and controlled sour water drainage to refinery waste water plant for treatment was applied to treat the caustic sludge.This process had the problems of higher operating risk in neutralization of caustic sludge by sulfuric acid and easy plugging of pipelines by low-temperature salt crystallization of sour water and air pollution by foul gas from operation,etc.To solve these problems,the injection of spent caustic sludge was implemented,caustic sludge wet oxidation unit was shutdown and caustic sludge acidification operation was stopped.The above practices in commercial operation show that,after injection of spent caustic sludge into the sour water stripper,70% of fixed ammonium is removed,steam consumption of sour water stripper is reduced by 10 kg/t,there is no impact on the quality of discharge water,and good economic and social benefits have been achieved.

  13. POTENTIAL FOR STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS CONTAINING HIGHLY CAUSTIC SOLUTIONS

    Energy Technology Data Exchange (ETDEWEB)

    Lam, P.; Stripling, C.; Fisher, D.; Elder, J.

    2010-04-26

    The evaporator recycle streams of nuclear waste tanks may contain waste in a chemistry and temperature regime that exceeds the current corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history found that two of these A537 carbon steel tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved tanks of similar construction. Therefore, it appears that the efficacy of stress relief of welding residual stress is the primary corrosion-limiting mechanism. The objective of this experimental program is to test A537 carbon steel small scale welded U-bend specimens and large welded plates (30.48 x 30.38 x 2.54 cm) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in these nuclear waste tanks. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test was completed after 12 weeks of immersion in a similar solution at 125 C except that the aluminate concentration was reduced to 0.3 M. Visual inspection of the plate revealed that stress corrosion cracking had not initiated from the machined crack tips in the weld or in the heat affected zone. NDE ultrasonic testing also confirmed subsurface cracking did not occur. Based on these results, it can be concluded that the environmental condition of these tests was unable to develop stress corrosion cracking within the test periods for the small welded U-bends and for the large plates, which were welded with an identical procedure as used in the construction of the actual nuclear waste tanks in the 1960s. The

  14. INVESTIGATION OF THE POTENTIAL FOR CAUSTIC STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS

    Energy Technology Data Exchange (ETDEWEB)

    Lam, P.

    2009-10-15

    The evaporator recycle streams contain waste in a chemistry and temperature regime that may be outside of the current waste tank corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history (1998-2008) of Tanks 30 and 32 showed that these tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved F-Area tanks. Therefore, for the Type III/IIIA waste tanks the efficacy of the stress relief of welding residual stress is the only corrosion-limiting mechanism. The objective of this experimental program is to test carbon steel small scale welded U-bend specimens and large welded plates (12 x 12 x 1 in.) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in Tanks 30 and 32. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test is currently in progress, but no cracking has been observed after 9 weeks of immersion. Based on the preliminary results, it appears that the environmental conditions of the tests are unable to develop stress corrosion cracking within the duration of these tests.

  15. Demonstration of Caustic-Side Solvent Extraction with Optimized Solvent in the 2-cm Centrifugal Contactor Apparatus Using Dissolved Salt Cake from Tank 37H

    Energy Technology Data Exchange (ETDEWEB)

    Norato, M.A.

    2003-01-06

    Researchers successfully demonstrated the chemistry of the Caustic-Side Solvent Extraction (CSSX) flow sheet with optimized solvent. This represents the third such process demonstration using actual Savannah River Site (SRS) high level waste (HLW). The present test differed from previous studies in the use of radioactive waste derived from Tank 37H dissolved salt cake, as opposed to supernate solutions used in previous demonstrations.

  16. Electro chemical studies on stress corrosion cracking of Incoloy-800 in caustic solution, part I: As received samples

    Directory of Open Access Journals (Sweden)

    Dinu Alice

    2005-01-01

    Full Text Available Many non-volatile impurities accidentally introduced into the steam generator tend to Concentrate on its surface in restricted flow areas. In this way these impurities can lead to stress corrosion cracking (SCC on stressed tubes of the steam generator. Such impurities can be strong alkaline or acid solutions. To evaluate the effect of alkaline concentrated environments on SCC of steam generator tubes, the tests were con ducted on stressed samples of Incoloy-800 in 10% NaOH solution. To accelerate the SCC process, stressed specimens were anodically polarised in a caustic solution in an electro chemical cell. The method of stressing of Incoloy-800 tubes used in our experiments was the C-ring. Using the cathodic zone of the potentiodynamic curves it was possible to calculate the most important electrochemical parameters: the corrosion current, the corrosion rate, and the polarization resistance. We found that the value of the corrosion potential to initiate the SCC microcracks was -100 mV. The tested samples were examined using the metallographic method. The main experimental results showed that the in crease of the stress state promoted the in crease of the SCC susceptibility of Incoloy-800 samples tested under the same conditions, and that the length of the SCC-type microcracks in creased with the growth of the stress value.

  17. A study of the electrochemical behavior in tungsten and caustic solutions and platinum/iridium in chloride solutions, informal report

    Energy Technology Data Exchange (ETDEWEB)

    Vitus, C.M.; Isaacs, H.S. [Brookhaven National Lab., Upton, NY (United States); Schroeder, V. [Univ. of California, Berkeley, CA (United States). College of Engineering

    1994-11-22

    Platinum/iridium and tungsten wires were electronically etched in chloride and caustic solution, respectively, to produce tips with high aspect ratio. A direct relationship between the meniscus and the aspect ratio of etched tips was established. Scanning electron micrographs indicated that higher aspect ratios were obtained by changing the geometry of the meniscus during the etch either by an increase in the applied a.c. voltage or with the addition of a nonpolar layer above the electrolytic solution during the etching process. Above the breakdown voltage, two possible mechanisms appeared to control the etching process by expediting chemical dissolution: cavitation and sparking. Cavitation caused erosion due to the force of evolved gases against the electrode and sparking attacked the surface by vaporizing the metal. Sparking commenced on both wires near 24V. This voltage corresponded to a minimum in the plot of total etch time versus voltage. From light emission studies, sparking on Pt/Ir was associated with the ionization of Pt, Ir, Ca, and Cl. A compositional analysis of insoluble black particles produced during a.c. and d.c. etching of Pt/Ir revealed Pt and Ir as the major constituents of the product. The sparking process was shown to have a potential use in micromachining.

  18. Experimental Study on Wing Crack Behaviours in Dynamic-Static Superimposed Stress Field Using Caustics and High-Speed Photography

    Directory of Open Access Journals (Sweden)

    L.Y. Yang

    2014-07-01

    Full Text Available During the drill-and-blast progress in rock tunnel excavation of great deep mine, rock fracture is evaluated by both blasting load and pre-exiting earth stress (pre-compression. Many pre-existing flaws in the rock mass, like micro-crack, also seriously affect the rock fracture pattern. Under blasting load with pre-compression, micro-cracks initiate, propagate and grow to be wing cracks. With an autonomous design of static-dynamic loading system, dynamic and static loads were applied on some PMMA plate specimen with pre-existing crack, and the behaviour of the wing crack was tested by caustics corroding with a high-speed photography. Four programs with different static loading modes that generate different pre-compression fields were executed, and the length, velocity of the blasting wing crack and dynamic stress intensity factor (SIF at the wing crack tip were analyzed and discussed. It is found that the behaviour of blasting-induced wing crack is affected obviously by blasting and pre-compression. And pre-compression, which is vertical to the direction of the wing crack propagation, hinders the crack propagation. Furthermore, the boundary constraint condition plays an important role on the behaviour of blasting induced crack during the experiment.

  19. Characterizing Low-Mass Binaries From Observation of Long Time-scale Caustic-crossing Gravitational Microlensing Events

    CERN Document Server

    Shin, I -G; Choi, J -Y; Udalski, A; Sumi, T; Gould, A; Bozza, V; Dominik, M; Fouqué, P; Horne, K; \\, M; Szymański, K; Kubiak, M; Soszyński, I; Pietrzyński, G; Poleski, R; Ulaczyk, K; Pietrukowicz, P; Kozłowski, S; Skowron, J; Wyrzykowski, Ł; Abe, F; Bennett, D P; Bond, I A; Botzler, C S; Chote, P; Freeman, M; Fukui, A; Furusawa, K; Itow, Y; Kobara, S; Ling, C H; Masuda, K; Matsubara, Y; Miyake, N; Muraki, Y; Ohmori, K; Ohnishi, K; Rattenbury, N J; Saito, To; Sullivan, D J; Suzuki, D; Suzuki, K; Sweatman, W L; Takino, S; Tristram, P J; Wada, K; Yock, P C M; Bramich, D M; Snodgrass, C; Steele, I A; Street, R A; Tsapras, Y; Alsubai, K A; Browne, P; Burgdorf, M J; Novati, S Calchi; Dodds, P; Dreizler, S; Fang, X -S; Grundahl, F; Gu, C -H; Hardis, S; Harpsøe, K; Hinse, T C; Hornstrup, A; Hundertmark, M; Jessen-Hansen, J; Jørgensen, U G; Kains, N; Kerins, E; Liebig, C; Lund, M; Lunkkvist, M; Mancini, L; Mathiasen, M; Penny, M T; Rahvar, S; Ricci, D; Scarpetta, G; Skottfelt, J; Southworth, J; Surdej, J; Tregloan-Reed, J; Wambsganss, J; Wertz, O; Almeida, L A; Batista, V; Christie, G; DePoy, D L; Dong, Subo; Gaudi, B S; Henderson, C; Jablonski, F; Lee, C -U; McCormick, J; McGregor, D; Moorhouse, D; Natusch, T; Ngan, H; Park, S -Y; Pogge, R W; Tan, T -G; Thornley, G; Yee, J C; Albrow, M D; Bachelet, E; Beaulieu, J -P; Brillant, S; Cassan, A; Cole, A A; Corrales, E; Coutures, C; Dieters, S; Prester, D Dominis; Donatowicz, J; Greenhill, J; Kubas, D; Marquette, J -B; Menzies, J W; Sahu, K C; Zub, M

    2012-01-01

    Despite astrophysical importance of binary star systems, detections are limited to those located in small ranges of separations, distances, and masses and thus it is necessary to use a variety of observational techniques for a complete view of stellar multiplicity across a broad range of physical parameters. In this paper, we report the detections and measurements of 2 binaries discovered from observations of microlensing events MOA-2011-BLG-090 and OGLE-2011-BLG-0417. Determinations of the binary masses are possible by simultaneously measuring the Einstein radius and the lens parallax from analyses of the well-resolved caustic-crossing parts of the light curve and the long-term deviation induced by the orbital motion of the Earth around the Sun, respectively. The measured masses of the binary components are 0.43 $M_{\\odot}$ and 0.39 $M_{\\odot}$ for MOA-2011-BLG-090 and 0.57 $M_{\\odot}$ and 0.17 $M_{\\odot}$ for OGLE-2011-BLG-0417 and thus both lens components of MOA-2011-BLG-090 and one component of OGLE-2011...

  20. Final Report: Caustic Waste-Soil Weathering Reactions and Their Impacts on Trace Contaminant Migration and Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    O' Day, Peggy A.; Chorover, J.; Mueller, K.T.; Serne, R.J.

    2006-12-11

    The principal goal of this project was to assess the molecular nature and stability of radionuclide (137-Cs, 90-Sr, and 129-I) immobilization during weathering reactions in bulk Hanford sediments and their high surface area clay mineral constituents. We focused on the unique aqueous geochemical conditions that are representative of waste-impacted locations in the Hanford site vadose zone: high ionic strength, high pH and high Al concentrations. The specific objectives of the work were to (i) measure the coupling of clay mineral weathering and contaminant uptake kinetics of Cs+, Sr2+ and I-; (ii) determine the molecular structure of contaminant binding sites and their change with weathering time during and after exposure to synthetic tank waste leachate (STWL); (iii) establish the stability of neoformed weathering products and their sequestered contaminants upon exposure of the solids to more “natural” soil solutions (i.e., after removal of the caustic waste source); and (iv) integrate macroscopic, microscopic and spectroscopic data to distinguish labile from non-labile contaminant binding environments, including their dependence on system composition and weathering time. During this funding period, we completed a large set of bench-scale collaborative experiments and product characterization aimed at elucidating the coupling between mineral transformation reactions and contaminant sequestration/stabilization. Our experiments included three representative Hanford sediments: course and fine sediments collected from the Hanford Formation and Ringold Silt, in addition to investigations with specimen clay minerals illite, vermiculite, smectite and kaolinite. These experiments combined macroscopic measurements of element release, contaminant uptake and subsequent neoformed mineral dissolution behavior, with detailed studies of solid phase products using SEM and TEM microscopy, NMR, XAS and FTIR spectroscopy. Our studies have shown direct coupling between mineral

  1. Terapia nutricional en pacientes adultos con quemaduras del tracto gastrointestinal por cáusticos Nutrition therapy for adult patients with caustic injuries to gastrointestinal tract

    Directory of Open Access Journals (Sweden)

    N. A. Muñoz Botero

    2010-04-01

    Full Text Available Objetivos: Presentar la experiencia del Grupo de Terapia Nutricional del Hospital El Tunal, en el manejo nutricional de pacientes adultos con quemaduras por cáusticos del tracto gastrointestinal. Materiales y métodos: Es un estudio retrospectivo, descriptivo de pacientes manejados por el Grupo de Terapia Nutricional por quemaduras por cáusticos del tracto gastrointestinal en un periodo comprendido entre Enero de 2000 y Diciembre de 2007. Se revisaron las historias clínicas de los pacientes que tenían diagnóstico de quemaduras por cáusticos. Se analizaron los datos pertinentes al manejo nutricional, la evolución y el resultado final dedichos pacientes. Resultados: Se atendieron 30 pacientes, 17 hombres y 13 mujeres con edad promedio 34,4 ± 17,2 años. La ingesta del cáustico fue por intento de suicidio en 22 (73,3% pacientes y accidental en 8 (26,7%. La mortalidad global fue alta (43,3%. El 46,9% de los pacientes mostró perdida de peso y balance nitrogenado negativo el 62,5%. Diez y siete pacientes (53,12% recibieron nutrición mixta (enteral y/o parenteral por un tiempo promedio de 24 ± 22 días. Al comparar dos grupos clasificados como quemadura del TGI Grave vs Moderada se encontró que fue significativamente diferente la mortalidad, la estancia hospitalaria y el valor final de albúmina. Conclusiones: La quemadura del tracto gastrointestinal por cáusticos es una entidad poco frecuente, sucede principalmente en jóvenes por intento de suicidio y se asocia a alta mortalidad, sobre todo en quemaduras graves. Esta agresión lleva a catabolismo importante que produce balance nitrogenado negativo y perdida de peso. Estos pacientes requieren intervención nutricional temprana que puede extenderse por varios meses.Objectives: To present here the experience of our Nutrition Therapy Team of the Hospital El Tunal, for the nutritional management of adult patients with caustic injuries to gastrointestinal tract. Materials and methods: This is

  2. [Evaluating risk of health disorders in workers engaged into polyvinyl chloride, vinyl chloride and caustic soda production (according to data collected by polls)].

    Science.gov (United States)

    D'iakovich, O A

    2014-01-01

    The authors represent data of automated system for quantitative risk evaluation of main pathologic syndromes in workers engaged into polyvinyl chloride, vinyl chloride and caustic soda production. Vinyl chloride and mercury levels at the investigation time corresponded with MAC. Relationship was seen between value of arterial hypertension risk and duration of contact with both vinyl chloride and mercury. Risk values for functional disorders of liver, endocrine system and nervous system were in weak correlation with length of exposure to mercury at work. Workers exposed to mercury appeared to have lower self-estimation of health state and higher dissatisfaction with the work.

  3. Application of oxidative technique for organic matter remove from a petroleum refinery spent caustic stream; Aplicacao de tecnicas oxidativas para a remocao do teor de materia organica de uma corrente de soda gasta de refinaria de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcante, Aline M.; Sant' Anna Junior, Geraldo L.; Dezzotti, Marcia [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica

    2004-07-01

    Spent caustic is a hazardous wastewater produced in several petroleum refineries. After the specific treatment for toxicity reduction, performed in the industrial site, this stream still presents high organic matter content. Thus, many times a further treatment is required. In this work, the removal of dissolved organic carbon (DOC) from the spent caustic stream, previously submitted to wet air oxidation (WAO), was investigated. This softening process is required to reduce the impact of the spent caustic effluent on the downstream industrial wastewater biological treatment plant. Among the softening techniques tested, Fenton and photo-Fenton processes were the most efficient. The combination of these processes led to 49% of DOC removal in time intervals of 85 min, using molars ratios H{sub 2}O{sub 2}/DOC=1.34 and H{sub 2}O{sub 2}/Fe{sup 2+}=10. (author)

  4. Stability of the Caustic-Side Solvent Extraction (CSSX) Process Solvent: Effect of High Nitrite on Solvent Nitration

    Energy Technology Data Exchange (ETDEWEB)

    Bonnesen, P.V.

    2002-06-26

    The purpose of this investigation was to determine whether nitrated organic compounds could be formed during operation of the Caustic-Side Solvent Extraction (CSSX) process, and whether such compounds would present a safety concern. The CSSX process was developed to remove cesium from alkaline high-level salt waste stored at the US Department of Energy Savannah River Site (SRS). The solvent is composed of the cesium extractant calix[4]arene-bis-(4-tert-octylbenzo-crown-6) (BOBCalixC6), a fluorinated alcohol phase modifier, tri-n-octylamine (TOA), and an isoparaffinic diluent (Iospar{reg_sign}). During the CSSX process, the solvent is expected to be exposed to high concentrations of nitrate and nitrite dissolved in the alkaline waste feed. The solvent will also be exposed to dilute (50 mM) nitric acid solutions containing low concentrations of nitrite during scrubbing, followed by stripping with 1 mM nitric acid. The solvent is expected to last for one year of plant operation, and the temperatures the solvent may experience during the process could range from as low as 15 C to as high as 35 C. Excursions from standard process conditions could result in the solvent experiencing higher temperatures, as well as concentrations of nitrate, nitrite, and most importantly nitric acid, that exceed normal operating conditions. Accordingly, conditions may exist where nitration reactions involving the solvent components, possibly leading to other chemical reactions stemming from nitration reactions, could occur. To model such nitration reactions, the solvent was exposed to the types of nitrate- and nitrite-containing solutions that might be expected to be encountered during the process (even under off-normal conditions), as a function of time, temperature, and concentration of nitrate, nitrite, and nitric acid. The experiments conducted as part of this report were designed to examine the more specific effect that high nitrite concentrations could have on forming nitrated

  5. Curious case of gravitational lensing by binary black holes: A tale of two photon spheres, new relativistic images, and caustics

    Science.gov (United States)

    Patil, Mandar; Mishra, Priti; Narasimha, D.

    2017-01-01

    Binary black holes have been in the limelight of late due to the detection of gravitational waves from coalescing compact binaries in the events GW150914 and GW151226. In this paper we study gravitational lensing by the binary black holes modeled as an equal mass Majumdar-Papapetrou dihole metric and show that this system displays features that are quite unprecedented and absent in any other lensing configuration investigated so far in the literature. We restrict our attention to the light rays which move on the plane midway between the two identical black holes, which allows us to employ various techniques developed for the equatorial lensing in the spherically symmetric spacetimes. If distance between the two black holes is below a certain threshold value, then the system admits two photon spheres. As in the case of a single black hole, infinitely many relativistic images are formed due to the light rays which turn back from the region outside the outer (unstable) photon sphere, all of which lie beyond a critical angular radius with respect to the lens. However, in the presence of the inner (stable) photon sphere, the effective potential after admitting minimum turns upwards and blows up for the smaller values of radii and the light rays that enter the outer photon sphere can turn back, leading to the formation of a new set of infinitely many relativistic images, all of which lie below the critical radius from the lens mentioned above. As the distance between the two black holes is increased, two photon spheres approach one another, merge and eventually disappear. In the absence of the photon sphere, apart from the formation of a finite number of discrete relativistic images, the system remarkably admits a radial caustic, which has never been observed in the context of relativistic lensing before. Thus the system of the binary black hole admits novel features both in the presence and absence of photon spheres. We discuss possible observational signatures and

  6. Extraction of Zinc from Electric Arc Furnace Dust by Alkaline Leaching Followed by Fusion of the Leaching Residue with Caustic Soda

    Institute of Scientific and Technical Information of China (English)

    赵由才; R.Stanforth

    2004-01-01

    Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5mol·L-1 NaOH solution for 42h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts wit hvarious contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.

  7. Harm of superheated steam to caustic soda evaporation and coutermeasures against it%过热蒸汽对烧碱蒸发的危害及对策

    Institute of Scientific and Technical Information of China (English)

    贺续安; 莫春阳

    2001-01-01

    The harm of super heated steam to caustic soda evaporation wasanalysed. The special methods to increase humidity of steam and decrease its temprature were introduced. Good results were achieved, which included consumption of steam was reduced from 5.1 t/t to 3.8 t/t so that about ten thousand tons of steam can be saved per year and expences of over 0.5 million RMB ¥/a could be reduced, output of caustic soda was increased largely and running condition was improved. Some problems still need to be solved.%概述了过热蒸汽对烧碱蒸发的危害,和采取特殊方式的增湿减温措施取得的良好效果:汽耗由5.1t/t降到3.8t/t,节汽约1万t/a,节约资金50万元/a,产量得到很大提高,使烧碱的运行状态得到改善。但仍存在一定问题尚需改进。

  8. 麦草氨法制浆工艺及动力学%Pulping of Wheat Straw with Caustic Potash-Ammonia Aqueous Solutions and Its Kinetics

    Institute of Scientific and Technical Information of China (English)

    黄国林; 张成芳; 陈中胜

    2006-01-01

    A pulping technology of wheat straw with aqueous ammonia and diluent caustic potash was investigated.Because its strong alkalinity, the addition of caustic potash not only reduced the quantity of NH3 consumed and cooking time, but also enriched the black liquor with nutrients such as potassium and nitrogen, which could be used as fertilizer for agriculture. Various pulping conditions including composition of cooking liquor, liquor-to-solid ratio,maximum cooking temperature, time to reach the maximum temperature and time at the maximum temperature were studied systematically to determine the suitable pulping conditions. Results of the cooking course showed that there were three distinct delignification phases, namely, the bulk delignification phase from the beginning of cooking to 100 ℃, the supplementary delignification phase from 100 ℃ to 155 ℃ for 45min and the third delignification phase till the end of cooking. The rate of delignification was found to be first order with respect to residual lignin and 0.34 order with respect to [OH-]. The activation energy of the delignification reaction was 29.75 kJ·mol-1 and the rate equation of delignification was also obtained.

  9. 膜法除硝在离子膜烧碱盐水精制中的应用%Application of sulfate removed by membrane method in the ionic membrane caustic soda brine refined

    Institute of Scientific and Technical Information of China (English)

    杨国稳

    2012-01-01

    阐述了MRO膜法除硝的设计原理、除硝生产工艺及其在离子膜烧碱装置中的应用情况。%Described the design principles of sulfate removed by MRO-membrane ,productive process, and its effect in the ionic membrane caustic soda installation.

  10. NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F.; Peters, T.; Fink, S.

    2012-01-17

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and

  11. Characterization of solids deposited on the modular caustic-side solvent extraction unit (MCU) coalescer media removed in May and October 2014

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F. F. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-01

    During routine maintenance, the coalescers utilized in the Modular Caustic-Side Solvent Extraction Unit (MCU) processing of Salt Batch 6 and a portion of Salt Batch 7 were sampled and submitted to the Savannah River National Laboratory (SRNL) for characterization, for the purpose of identifying solid phase constituents that may be accumulating in these coalescers. Specifically, two samples were received and characterized: A decontaminated salt solution (DSS) coalescer sample and a strip effluent (SE) coalescer sample. Aliquots of the samples were analyzed by XRD, Fourier Transform Infrared (FTIR) Spectroscopy, SEM, and EDS. Other aliquots of the samples were leached in acid solution, and the leachates were analyzed by ICP-AES. In addition, modeling was performed to provide a basis for comparison of the analytical results.

  12. Pretreatment Engineering Platform (PEP) Integrated Test B Run Report--Caustic and Oxidative Leaching in UFP-VSL-T02A

    Energy Technology Data Exchange (ETDEWEB)

    Geeting, John GH; Bredt, Ofelia P.; Burns, Carolyn A.; Golovich, Elizabeth C.; Guzman-Leong, Consuelo E.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Aaberg, Rosanne L.

    2009-12-10

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  13. PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A

    Energy Technology Data Exchange (ETDEWEB)

    Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.; Daniel, Richard C.; Su, Yin-Fong; Geeting, John GH; Golovich, Elizabeth C.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Smith, Dennese M.; Valdez, Patrick LJ; Yokuda, Satoru T.; Young, Joan K.

    2009-12-04

    Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.”(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  14. Determination of sodium chloride in ion - exchange membrane caustic soda%离子膜碱中氯化钠的测定

    Institute of Scientific and Technical Information of China (English)

    宋昕; 孙士娟; 邱雪松

    2000-01-01

    The determination of sodium chloride in ion- exchange membrane caustic soda by potentiometry and by spectrophotometry are introduced, and the results obtained by the above two methods are compared. It is concluded that potentiometry is suitable to macro analysis with characteristics of simple operation, rapid analysis and accurate measurement.%介绍了用电位滴定法和分光光度法测定离子膜碱中氯化钠含量的方法,并对这2种方法的测试结果进行了比较。电位滴定法适用于常量分析,具有操作简便、分析速度快、测量结果准确等特点。

  15. O esôfago de Barrett associado à estenose cáustica do esôfago Barrett's esophagus associated to caustic stenosis of the esophagus

    Directory of Open Access Journals (Sweden)

    Nelson Adami Andreollo

    2003-09-01

    Full Text Available RACIONAL: A estenose esofágica secundária à ingestão de produtos cáusticos é freqüente no Brasil, principalmente como tentativa de suicídio. O esôfago de Barrett surge como conseqüência do refluxo gastroesofágico crônico. A literatura pesquisada mostrou que esta associação é muito rara. CASUÍSTICA E MÉTODOS: De 1981 a 2000 foram admitidos e tratados no Gastrocentro-UNICAMP (Universidade Estadual de Campinas, SP. 120 doentes com estenose cáustica do esôfago e durante o seguimento destes, foram encontrados 9 casos associados com o esôfago de Barrett (7,5%. O tempo de ingestão do cáustico variou de 4 a 54 anos (média de 29 anos e eram quatro homens e cinco mulheres, oito brancos e um negro, com idade média de 57,7 anos (43 a 72 anos. RESULTADOS: Todos os casos apresentavam disfagia e a endoscopia digestiva alta flexível mostrou áreas de estenose e seqüelas de esofagite cáustica. Três pacientes referiram sintomas de refluxo gastroesofágico, mas hérnia de hiato foi encontrada em apenas um caso. O esôfago de Barrett foi encontrado no terço médio do esôfago em três casos, acima das áreas de estenose, e nos demais, no terço distal. A disfagia foi tratada com dilatações esofágicas periódicas. Dois pacientes apresentando sintomas de refluxo grave foram submetidos a fundoplicatura à Nissen modificado através de videolaparoscopia, com bons resultados. CONCLUSÕES: O esôfago de Barrett nesses doentes poderia estar associado com a ingestão de cáustico, porque nem sempre esteve associado à esofagite por refluxo. É muito importante o seguimento desses doentes e realização periódica de endoscopias digestivas com biopsias do esôfago de Barrett, devido à possibilidade de malignização.BACKGROUND: The esophageal stenosis secondary to the ingestion of caustic products is frequent in Brazil, mainly due to an attempt suicide. The Barrett's esophagus is consequence of the chronic gastroesophageal reflux. The

  16. 试述小苏打系统加液碱生产工艺%Discussion on Manufacturing Technique of Adding Liquid Caustic Soda in Baking Soda System

    Institute of Scientific and Technical Information of China (English)

    林戌梅

    2016-01-01

    将离子膜液碱加入小苏打生产系统进行探索试验,通过不断优化生产条件,对离子膜液碱加入小苏打系统技术进行研究,得出其生产工艺的可行性。%It has been experimented that adds ionic membrane liquid caustic soda in the production system of baking soda. With the increasing improvement of production conditions, the technique of adding ionic membrane liquid caustic soda in baking soda system has been researched. Finally, the feasibility of this technique can be obtained.

  17. 离子膜烧碱生产中盐水脱碘新技术的研究%Iodine removing new technology research of ion-exchange membrane caustic soda brine

    Institute of Scientific and Technical Information of China (English)

    毛晓军; 白丽慧; 鲍中秀

    2012-01-01

    探讨了对离子膜烧碱生产电解用盐水的除碘新技术,该技术能降低碘对离子膜的负面影响,延长使用寿命。%Discussed the ionic membrane caustic soda produce electrolysis ofalkali method except with salt water.It can remove part of iodine ion membrane to reduce high iodine the negative impact prolong service life.

  18. 卧式燃氢蒸汽锅炉在烧碱生产中的应用%Applications of horizontal steam boiler burning hydrogen in the production of caustic soda

    Institute of Scientific and Technical Information of China (English)

    王荣欣; 王凯

    2015-01-01

    Introduced 8 t/h horizontal steam boiler burning hydrogen successfully applied in caustic soda production, the boiler designed, safe and stable operation, low capital investment costs.%介绍了8t/h卧式燃氢蒸汽锅炉在烧碱生产中的成功应用,该锅炉设计完善、运行安全平稳、建设投资费用低。

  19. Caustic Soda Industry Promotion in 2011 and Trend Analysis in the Future%我国烧碱提振2011及未来趋势分析

    Institute of Scientific and Technical Information of China (English)

    朱国梁

    2012-01-01

    2011年,作为“十二五”的开局之年,氯碱主要产品的市场环境和行业状况变化被赋予了更为丰富的涵义.价格攀升至历史高位的烧碱与大幅下滑的液氯、PVC产品的对比,使得氯碱行业短期内“以碱补氯”的盈利模式已基本确立.由此,氯碱行业传统的“碱氯平衡”引发的企业耗氯产品选择问题再次成为业界关注的焦点.氯碱行业不断提高的综合盈利水平似乎增加了业界对市场向好的信心,而政策层面的包括节能减排、电力、信贷、融资等一系列直接或间接作用于耗能行业的政策导向,都预示着产业结构调整及节能减排机制将继续发挥作用,也加重了2012年市场走向的不确定性.%A. D. 2011 is the first year of "the Twelfth - Five Plan". The market conditions and industry status for the main product in ehlor - alkali industry are given with rich meaning. The price of caustic soda is highest in histtory but the price of liquid chlorine and PVC decreased greatly. Therefore, the profit model of caustic soda compensating for chlorine is set up in chlor - alkali industry. The conditions of chlor - alkali balance in tradition have been changed and the choice of chlorine consumption product will be focused agani. The market seems to be good with the improvement of level of integration profitability. Some policy, for example energy saving and emission decreasing, electrical power, loan and financing etc. , guides the energy consumption industry. It indicates that the adjusting of industry structure, the mechanism of energy saving and emission decreasing will continue to play a role. The market direction is uncertain in 2012 because of these.

  20. Thermal And Spectroscopic Analyses Of Next Generation Caustic Side Solvent Extraction Solvent Contacted With 3, 8, And 16 Molar Nitric Acid

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F. F.; Fink, S. D.

    2011-12-07

    A new solvent system referred to as Next Generation Solvent or NGS, has been developed at Oak Ridge National Laboratory for the removal of cesium from alkaline solutions in the Caustic Side Solvent Extraction process. The NGS is proposed for deployment at MCU{sup a} and at the Salt Waste Processing Facility. This work investigated the chemical compatibility between NGS and 16 M, 8 M, and 3 M nitric acid from contact that may occur in handling of analytical samples from MCU or, for 3 M acid, which may occur during contactor cleaning operations at MCU. This work shows that reactions occurred between NGS components and the high molarity nitric acid. Reaction rates are much faster in 8 M and 16 M nitric acid than in 3 M nitric acid. In the case of 16 M and 8 M nitric acid, the nitric acid reacts with the extractant to produce initially organo-nitrate species. The reaction also releases soluble fluorinated alcohols such as tetrafluoropropanol. With longer contact time, the modifier reacts to produce a tarry substance with evolved gases (NO{sub x} and possibly CO). Calorimetric analysis of the reaction product mixtures revealed that the organo-nitrates reaction products are not explosive and will not deflagrate.

  1. Hazardous Materials Verification and Limited Characterization Report on Sodium and Caustic Residuals in Materials and Fuel Complex Facilities MFC-799/799A

    Energy Technology Data Exchange (ETDEWEB)

    Gary Mecham

    2010-08-01

    This report is a companion to the Facilities Condition and Hazard Assessment for Materials and Fuel Complex Sodium Processing Facilities MFC-799/799A and Nuclear Calibration Laboratory MFC-770C (referred to as the Facilities Condition and Hazards Assessment). This report specifically responds to the requirement of Section 9.2, Item 6, of the Facilities Condition and Hazards Assessment to provide an updated assessment and verification of the residual hazardous materials remaining in the Sodium Processing Facilities processing system. The hazardous materials of concern are sodium and sodium hydroxide (caustic). The information supplied in this report supports the end-point objectives identified in the Transition Plan for Multiple Facilities at the Materials and Fuels Complex, Advanced Test Reactor, Central Facilities Area, and Power Burst Facility, as well as the deactivation and decommissioning critical decision milestone 1, as specified in U.S. Department of Energy Guide 413.3-8, “Environmental Management Cleanup Projects.” Using a tailored approach and based on information obtained through a combination of process knowledge, emergency management hazardous assessment documentation, and visual inspection, this report provides sufficient detail regarding the quantity of hazardous materials for the purposes of facility transfer; it also provides that further characterization/verification of these materials is unnecessary.

  2. Application of ultrasound and air stripping for the removal of aromatic hydrocarbons from spent sulfidic caustic for use in autotrophic denitrification as an electron donor.

    Science.gov (United States)

    Lee, Jae-Ho; Park, Jeung-Jin; Choi, Gi-Choong; Byun, Im-Gyu; Park, Tae-Joo; Lee, Tae-Ho

    2013-01-01

    Spent sulfidic caustic (SSC) produced from petroleum industry can be reused to denitrify nitrate-nitrogen via a biological nitrogen removal process as an electron donor for sulfur-based autotrophic denitrification, because it has a large amount of dissolved sulfur. However, SSC has to be refined because it also contains some aromatic hydrocarbons, typically benzene, toluene, ethylbenzene, xylene (BTEX) and phenol that are recalcitrant organic compounds. In this study, laboratory-scale ultrasound irradiation and air stripping treatment were applied in order to remove these aromatic hydrocarbons. In the ultrasound system, both BTEX and phenol were exponentially removed by ultrasound irradiation during 60 min of reaction time to give the greatest removal efficiency of about 80%. Whereas, about 95% removal efficiency of BTEX was achieved, but not any significant phenol removal, within 30 min in the air stripping system, indicating that air stripping was a more efficient method than ultrasound irradiation. However, since air stripping did not remove any significant phenol, an additional process for degrading phenol was required. Accordingly, we applied a combined ultrasound and air stripping process. In these experiments, the removal efficiencies of BTEX and phenol were improved compared to the application of ultrasound and air stripping alone. Thus, the combined ultrasound and air stripping treatment is appropriate for refining SSC.

  3. Utilizing of Multiple-effect Evaporator Method in Caustic Soda%浅析多效蒸发在烧碱浓缩中的应用

    Institute of Scientific and Technical Information of China (English)

    张雷; 麻翠云

    2012-01-01

    Energy conservation is imperative measures in petrochemical industry,the evaporator is a high energy chemical unit operations,in order to reduce energy consumption,we can use the multi-effect evaporation.Multi-effect evaporation or solution concentration is an important energy use and recycling processes,its biggest advantage is that multiple use of secondary steam vaporization and condensation,can significantly reduce the consumption of fresh steam.this departure from the energy-saving mechanism briefly introduce the utilizing of multi-effect evaporation in caustic soda.%节能减排是石化行业势在必行的措施,蒸发是一个能耗很高的化工单元操作,为了降低能耗,可采用多效蒸发。多效蒸发在溶液浓缩是一种重要的能量利用与回收工艺,其最大的优点是多次利用二次蒸汽的汽化和冷凝,可以显著减少新鲜蒸汽消耗量。文章从节能机理出发,简要介绍了多效蒸发在烧碱蒸发工艺中的应用。

  4. Performance of NiB inhibitor for PbSCC of alloy 600 in Pb-contaminated water and caustic solutions

    Science.gov (United States)

    Kim, Joung Soo; Yi, Yong-Sun; Kwon, Oh Chul; Kim, Mi-Ae; Kim, Hong Pyo

    2008-06-01

    Nickel-based iron-chromium alloys are used as steam generator (SG) tubing materials in nuclear power plants (NPPs) but experience intergranular stress corrosion cracking (IGSCC) and lead stress corrosion cracking (PbSCC) due to the harsh operating conditions of NPPs. In order to improve the integrity of SGs, many studies have sought suitable inhibitors for IGSCC, while those for PbSCC have been sought to a limited extent. In this study, the performance of nickel boride (NiB) as an inhibitor for PbSCC was evaluated. Nickel boride has been shown to be a good inhibitor for IGSCC of Alloy (or Inconel) 600 in a caustic aqueous solution containing no lead (Pb). No significant SCC was observed to occur in Alloy 600 tested in pure water under the slow strain rate test (SSRT) condition in this study. A mixed mode of IGSCC and TGSCC, however, occurred relatively easily in Alloy 600 tested in pure water containing lead oxide (PbO) at 315 °C. The susceptibility of Alloy 600 to SCC decreased with the addition of NiB, implying that NiB can be used as an inhibitor for PbSCC in Pb-contaminated water.

  5. Optimization Process in Ionic Membrane Caustic Soda Production%离子膜烧碱生产工艺的优化

    Institute of Scientific and Technical Information of China (English)

    王志勇; 李和平; 尹志刚

    2011-01-01

    针对传统离子膜烧碱工艺原材料消耗大、能耗高的缺点,取消原脱氯塔后亚硫酸钠处理装置与一次盐水生产中的加次氯酸钠装置,使脱氯后淡盐水保留5~50 mg·L-1游离氯送去一次盐水化盐,并通过改造原有离子膜烧碱生产系统的相关设备、增加在线监测、改进部分工艺操作方法以及优化工艺控制指标和自动控制参数等措施,实现了生产系统稳定运行,工程操作和维修强度明显减少,且产品质量达到了国际优等品的标准要求.生产1万t烧碱时亚硫酸钠、氯化钡、次氯酸钠的消耗分别下降57.1%、18.5%、100%,节电约1 600 kW·h,外排硫酸盐沉泥减少28.6%(干基).%To reduce the huge consumption of raw materials and the high energy consumption, the diluted brine to preserve 5 to 50 mg· L-1 free chlorine is removed to salt dissolving through cancellation of sodium sulfite process unit after the dechlorinating tower and sodium hypochlorite unit in the first brine. After equipment innoration in the ionic membrane caustic soda production system, the steady operation of production system is improved and product quality too up to the superior quality of national standard. These innovations provide better online monitoring, improve some technological operations, optimize technological guideposts and autocontrol parameters. To produce 10 000 tons of sodium hydroxide, the consumption of raw materials decreases to sodium sulfite 57. 1%, sodium hypochlorite 18.5%, barium chloride 100% respectively, saving power 1 600 kW·h. The strength of operation and maintenance would decrease efflux sulfate silt 28.6% (drybasis).

  6. DWPF Flowsheet Studies with Simulants to Determine Modular Caustic Side Solvent Extraction Unit Solvent Partitioning and Verify Actinide Removal Process Incorporation Strategy

    Energy Technology Data Exchange (ETDEWEB)

    Herman, C

    2006-04-21

    The Actinide Removal Process (ARP) facility and the Modular Caustic Side Solvent Extraction Unit (MCU) are scheduled to begin processing salt waste in fiscal year 2007. A portion of the streams generated in the salt processing facilities will be transferred to the Defense Waste Processing Facility (DWPF) to be incorporated in the glass matrix. Before the streams are introduced, a combination of impact analyses and research and development studies must be performed to quantify the impacts on DWPF processing. The Process Science & Engineering (PS&E) section of the Savannah River National Laboratory (SRNL) was requested via Technical Task Request (TTR) HLW/DWPF/TTR-2004-0031 to evaluate the impacts on DWPF processing. Simulant Chemical Process Cell (CPC) flowsheet studies have been performed using previous composition and projected volume estimates for the ARP sludge/monosodium titanate (MST) stream. Due to changes in the flammability control strategy for DWPF for salt processing, the incorporation strategy for ARP has changed and additional ARP flowsheet tests were necessary to validate the new processing strategy. The last round of ARP testing included the incorporation of the MCU stream and identified potential processing issues with the MCU solvent. The identified issues included the potential carry-over and accumulation of the MCU solvent components in the CPC condensers and in the recycle stream to the Tank Farm. Therefore, DWPF requested SRNL to perform additional MCU flowsheet studies to better quantify the organic distribution in the CPC vessels. The previous MCU testing used a Sludge Batch 4 (SB4) simulant since it was anticipated that both of these facilities would begin salt processing during SB4 processing. The same sludge simulant recipe was used in this round of ARP and MCU testing to minimize the number of changes between the two phases of testing so a better comparison could be made. ARP and MCU stream simulants were made for this phase of testing

  7. Conceptual Design of a Simplified Skid-Mounted Caustic-Side Solvent Extraction Process for Removal of Cesium from Savannah Rive Site High-Level Waste

    Energy Technology Data Exchange (ETDEWEB)

    Birdwell, JR.J.F.

    2004-05-12

    This report presents the results of a conceptual design of a solvent extraction process for the selective removal of {sup 137}Cs from high-level radioactive waste currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site (SRS). This study establishes the need for and feasibility of deploying a simplified version of the Caustic-Side Solvent Extraction (CSSX) process; cost/benefit ratios ranging from 33 to 55 strongly support the considered deployment. Based on projected compositions, 18 million gallons of dissolved salt cake waste has been identified as having {sup 137}Cs concentrations that are substantially lower than the worst-case design basis for the CSSX system that is to be deployed as part of the Salt Waste Processing Facility (SWPF) but that does not meet the waste acceptance criteria for immobilization as grout in the Saltstone Manufacturing and Disposal Facility at SRS. Absent deployment of an alternative cesium removal process, this material will require treatment in the SWPF CSSX system, even though the cesium decontamination factor required is far less than that provided by that system. A conceptual design of a CSSX processing system designed for rapid deployment and having reduced cesium decontamination factor capability has been performed. The proposed accelerated-deployment CSSX system (CSSX-A) has been designed to have a processing rate of 3 million gallons per year, assuming 90% availability. At a more conservative availability of 75% (reflecting the novelty of the process), the annual processing capacity is 2.5 million gallons. The primary component of the process is a 20-stage cascade of centrifugal solvent extraction contactors. The decontamination and concentration factors are 40 and 15, respectively. The solvent, scrub, strip, and wash solutions are to have the same compositions as those planned for the SWPF CSSX system. As in the SWPF CSSX system, the solvent and scrub flow rates are equal. The system

  8. 高效生物处理技术在碱渣处理装置的工业应用%Commercial application of new high-efficiency biological treatment technology in caustic sludge treatment

    Institute of Scientific and Technical Information of China (English)

    高瑞民; 张书勤; 黄勇; 周东彦

    2012-01-01

    The process principles and technical features of the conventional caustic sludge treatment and high-efficient biological treatment technologies are studied and compared. The high-efficiency biological treatment technology uses MERION partial oxidation and neutralization extraction process to oxidize sulfides into thiosulfate to separate sulfide in the form of gaseous state so as to recover phenol and oil from caustic sludge. With the principles of biological metabolism oxidation, the organisms and sulfides in sewage are oxidized and decomposed into CO2, H2O and sulfate respectively. Through microbial decomposition, oxidation and conversion, VOC, H2O and exhaust gas are oxidized and decomposed into C02, H2O, NO32- , SO4 2-etc to remove other chemical substances, like alcohol, aldehyde and acetic acid to complete the harmless treatment. The technology is high in removal rate of harmful substances like COD, sulfide and phenol in caustic sludge ( >99%). The stable water quality (100% on specification) meets the standard of cooling water. The annual saving of water is 600 dam3, and the annual saving of cost for treatment to meet environmental protection is 10 million Yuan RMB.%分析对比传统碱渣处理和高效生物处理技术的工艺原理和技术特点.高效生物处理技术采用MERI-CON部分氧化和中和萃取工艺,将硫化物氧化成硫代硫酸盐,使硫化物以气态形式分离,回收碱渣中的酚和油;利用生物代谢氧化原理,将污水中有机物氧化分解成CO2和H2O,使硫化物转化成硫酸盐;利用微生物的分解、氧化和转化功能,将VOC,H2S和废气氧化分解成CO2,H2O,NO32-,SO42-等,去除醇、醛和酸等化学物质,完成无害化处理.该技术对碱渣中COD、硫化物和挥发酚等去除率高(>99%),处理后水质稳定(合格率100%),达到循环冷却用水要求,年节省用水600 dam3,累计节约环保处理费用1 000×104 RMB¥.

  9. 氯盐型融雪剂碳钢腐蚀性的测定新方法%Determination for Chloride Salt -Type of Deicing Salt Carbon Steel Causticity

    Institute of Scientific and Technical Information of China (English)

    王树轩; 李宁; 李波; 李玉龙

    2012-01-01

    文章考虑了融雪剂使用过程的通气状态,提出测定氯盐型融雪剂碳钢腐蚀率的新方法—充氧测定法.并比较了充氧与非充氧条件下,NaCl、MgCl2和CaCl2三种融雪剂对碳钢的腐蚀性.在充氧条件下,141 h三种融雪剂的失重率相差不大,普遍大于非充氧状态下553 h的失重率,553 h时,当浓度低于4%,失重率CaCl2> MgCl2> NaCl,浓度大于4%时,失重率NaCl> CaCl2> MgCl2.并利用灰色系统理论建模,预测分析CaCl2对碳钢腐蚀性.在553 h时,非充氧条件下,灰色预测效果好,误差<±10.%In this paper, after considering the aeration state of using deicing salt, we proposed a new method of measuring for chloride salt - type of deicing salt carbon steel causticity by oxygenizing mensuration. And compare with the condition of oxygenation and dis - oxygenation. The causticity for carbon steel from the three kind of deicing salt were NaCl, MgCl2 and CaCl2- In general , the rate of weight loss of these kind of deicing salt have less difference in the condition of oxygenation with 141 h, greater than the condition of dis - oxygenation with 553 h. When the time is 553 h and the conch is lower than 4% , the rate of weight loss is: CaCl2 > MgCl2 > NaCl; and when the conch is higher than 4% , the rate of weight loss is: NaCl > CaCl, > MgCl2. We predicted and analyzed the carbon steel causticity from CaCl2 with Grey system theory model. In the condition of dis - oxygenation with 553 h, the impact of grey predicting is very good, and the inaccuracy is lower than ± 10.

  10. 离子膜法烧碱扩能后电解槽温度的控制%Control of electrolyzer temperature after capacity expansion of ion-membrane caustic soda

    Institute of Scientific and Technical Information of China (English)

    张金豹; 付秦生

    2013-01-01

    介绍离子膜电解槽槽温控制的重要性。介绍了扩能后槽温对电流效率、槽压和碱中含盐量的影响。提出采用蒸汽预热盐水、降低阳极液温度、降低原水加热温度等方式,将槽温控制在合理范围。%The importance of controlling electrolyzer temperature in ion-membrane electrolysis is explained .The influences of electrolyzer temperature on current efficiency , eletrolyzer voltage and salt content of caustic soda after capacity expansion are related .Methods such as using steam to preheat brine, lowering the temperature of anode liquid and lowering the temperature of heated raw water are proposed to control the electrolyzer temperature in a proper range .

  11. Conceptual Design of a Simplified Skid-Mounted Caustic-Side Solvent Extraction Process for Removal of Cesium from Savannah Rive Site High-Level Waste

    Energy Technology Data Exchange (ETDEWEB)

    Birdwell, JR.J.F.

    2004-05-12

    This report presents the results of a conceptual design of a solvent extraction process for the selective removal of {sup 137}Cs from high-level radioactive waste currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site (SRS). This study establishes the need for and feasibility of deploying a simplified version of the Caustic-Side Solvent Extraction (CSSX) process; cost/benefit ratios ranging from 33 to 55 strongly support the considered deployment. Based on projected compositions, 18 million gallons of dissolved salt cake waste has been identified as having {sup 137}Cs concentrations that are substantially lower than the worst-case design basis for the CSSX system that is to be deployed as part of the Salt Waste Processing Facility (SWPF) but that does not meet the waste acceptance criteria for immobilization as grout in the Saltstone Manufacturing and Disposal Facility at SRS. Absent deployment of an alternative cesium removal process, this material will require treatment in the SWPF CSSX system, even though the cesium decontamination factor required is far less than that provided by that system. A conceptual design of a CSSX processing system designed for rapid deployment and having reduced cesium decontamination factor capability has been performed. The proposed accelerated-deployment CSSX system (CSSX-A) has been designed to have a processing rate of 3 million gallons per year, assuming 90% availability. At a more conservative availability of 75% (reflecting the novelty of the process), the annual processing capacity is 2.5 million gallons. The primary component of the process is a 20-stage cascade of centrifugal solvent extraction contactors. The decontamination and concentration factors are 40 and 15, respectively. The solvent, scrub, strip, and wash solutions are to have the same compositions as those planned for the SWPF CSSX system. As in the SWPF CSSX system, the solvent and scrub flow rates are equal. The system

  12. 炼油厂高浓度含酚碱渣碳化液萃取脱酚的研究1.脱酚萃取剂的开发%EXTRACTION DEPHENOL FOR CAUSTIC PHENOLIC SLUDGE IN REFINERY——Development of Dephenol Extractor

    Institute of Scientific and Technical Information of China (English)

    江燕斌; 李秀喜; 钱宇; 温艳芹

    2001-01-01

    Based on comparison tests,a complex extractor,30% TBP kerosene solution with high extraction power and suitable to carbonized weak caustic ambient was selected.Under weak caustic conditions of pH 8.5,the percent of single-stage extraction dephenol is higher than 99%.%碱渣碳化液最突出的问题之一是酚的脱除。通过对比实验,选择了适合于碳化液弱碱性环境的高效、高萃取容量的络合萃取剂30% TBP煤油溶液。该萃取剂在pH值为8.5的弱碱性条件下单级萃取脱酚率仍高于99%。

  13. Discussion on central control analysis method for determination of sodium shloride content in caustic soda production%烧碱中控分析中氯化钠含量测定方法的探讨

    Institute of Scientific and Technical Information of China (English)

    邵月庆; 孙海英

    2012-01-01

    对汞量法、银量法和改进的银量法对烧碱中控分析中氯化钠含量的测定方法的优缺点进行了对比实验,并进行了讨论。实验结果表明,汞量法和改进的银量法能够降低大量材料成本(年节约10-18万元)、灵敏度高、终点变色敏锐,更适合中控分析。%This paper compared the central control analysis methods of mercurimetric titration and argentometry for determination of sodium chloride content in caustic soda production, discussed their advantages and disadvantages. The results show that the mercurimetcic titration method and argentometry method compiled and improved by the anthor are cost-effective (about 0.1 to 0.18 million yuan per year), sensitivity high, equivalent point acute for color transformation and more suitable for central control analysis.

  14. 高浓含酚炼油碱渣碳化液萃取脱酚的研究2.连续逆流萃取实验%EXTRACTION DEPHENOL FOR CAUSTIC PHENOLIC SLUDGE IN REFINERY ——2.Continuous Counterflow Extraction Test

    Institute of Scientific and Technical Information of China (English)

    江燕斌; 钱宇; 李秀喜; 宋光均; 谢晋巧; 孙智华

    2001-01-01

    针对碱渣碳化液突出的酚浓度高问题,选择了30%磷酸三丁酯煤油溶液作为络合萃取脱酚剂。在此基础上,进行了多级连续逆流离心萃取脱酚及萃取剂反萃再生的研究,确定了适宜的工艺操作参数。结果表明,在弱碱性条件下,采用30%磷酸三丁酯煤油溶液处理碳化液,可在不调节温度和pH值的情况下实现高效络合萃取脱酚,脱除率大于99%,且萃取剂易于碱洗反萃再生,有利于工业实施。%In view of the high concentration of phenol in caustic carbonized sludge,a complexing dephenol extractor,30% TBP(tributyl phosphate) kerosene solution was selected.Continuous multistage counterflow centrifugal dephenol extraction and reextraction regeneration of the extractor were studied and proper operating parameters determined.The results showed that under weak caustic conditions,using 30% TBP kerosene solution to treat carbonized sludge,high efficiency complexing extraction dephenol can be realized without adjusting the temperature and the pH value.The removel percentage of phenol is more than 99% and the extractor is easily regenerated via caustic reextraction.

  15. Extraction of Zinc from Electric Arc Furnace Dust by Alkaline Leaching Followed by Fusion of the Leaching Residue with Caustic Soda%氢氧化钠浸取-浸取渣熔融法从炼钢厂烟尘中提取锌的研究

    Institute of Scientific and Technical Information of China (English)

    赵由才; R. Stanforth

    2004-01-01

    Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8%of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5 mol. L-1 NaOH solution for 42 h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts with various contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.

  16. Computing Fourier integral operators with caustics

    Science.gov (United States)

    Caday, Peter

    2016-12-01

    Fourier integral operators (FIOs) have widespread applications in imaging, inverse problems, and PDEs. An implementation of a generic algorithm for computing FIOs associated with canonical graphs is presented, based on a recent paper of de Hoop et al. Given the canonical transformation and principal symbol of the operator, a preprocessing step reduces application of an FIO approximately to multiplications, pushforwards and forward and inverse discrete Fourier transforms, which can be computed in O({N}n+(n-1)/2{log}N) time for an n-dimensional FIO. The same preprocessed data also allows computation of the inverse and transpose of the FIO, with identical runtime. Examples demonstrate the algorithm’s output, and easily extendible MATLAB/C++ source code is available from the author.

  17. Morphological and functional evaluation of distal esophagus of rabbits submitted to esophageal infusion with caustic soda Avaliações morfológica e funcional do esôfago distal de coelhos submetidos a infusão esofágica com soda cáustica

    Directory of Open Access Journals (Sweden)

    Maria Aparecida Coelho de Arruda Henry

    2008-02-01

    Full Text Available The ingestion of caustic substances is an important emergency situation, because of its serious consequences. PURPOSE: To study morphological and functional alterations of the esophagus in rabbits submitted to esophageal infusion of caustic soda (NaOH. METHODS: The 88 rabbits studied were divided into 4 groups: G1 (n=22 were submitted to esophageal infusion with distilled water. G2, G3, and G4 were submitted to esophageal infusion of 2%, 4% and 6% NaOH respectively. Morphological alterations were studied in 12 animals from each group and manometric alterations in the remaining 10. An analysis was made of lower esophageal sphincter (LES pressure, number and amplitude of contractions in the distal third of the esophagus. These studies were performed before (moment M1 and at 30 minutes, 6 hours, and 24 hours after (moments M2, M3, and M4, respectively esophageal infusion. RESULTS: Morphological evaluation: G1 - no alterations; G2 - edema, hyperemia, and ecdysis; G3 - enlarged calibre of esophagus, ulcers, ecdysis of mucosa; G4 - lesions similar to G3, but more intense, areas of extensive hemorrhage at M3 and M4. Functional evaluation: LES was higher at M2; the number of distal third lower esophageal contractions in G3, and G4 was lower; and the contraction amplitude was lower in G4. CONCLUSIONS: 1 Esophageal infusion with caustic soda in rabbits is a good experimental model for studying caustic esophagites. 2 Esophageal infusion with NaOH caused lesions in the esophageal wall, with gravity proportional to solution concentration; 3 Infusion caused LES spasm at M2, and reduced both contraction number and amplitude in the distal third of the esophagus.A ingestão de substâncias cáusticas constitui importante situação de emergência, tendo em vista a gravidade de suas seqüelas. OBJETIVO: Estudar as alterações morfológicas e funcionais do esôfago de coelhos submetidos à infusão esofágica com soda cáustica (NaOH. MÉTODOS: 88 coelhos foram

  18. Caustic esophageal injury by impaction of cell batteries.

    Science.gov (United States)

    García Fernández, Francisco José; León Montañés, Rafael; Bozada Garcia, Juan Manuel

    2016-12-01

    The ingestion of cell batteries can cause serious complications (fistula, perforation or stenosis) at the esophageal level. The damage starts soon after ingestion (approximately 2 hours) and is directly related to the amount of time the battery is lodged in said location, the amount of electrical charge remaining in the battery, and the size of the battery itself. Injury is produced by the combination of electrochemical and chemical mechanisms and pressure necrosis. The ingestion of multiple cells and a size > = 20 mm are related with more severe and clinically significant outcomes. A female patient, 39 years old, with a history of previous suicide attempts, was admitted to the Emergency Room with chest pain and dysphagia after voluntary ingestion of 2 cell batteries. Two cell batteries are easily detected in a routine chest X-ray, presenting a characteristic double-ring shadow, or peripheral halo. Urgent oral endoscopy was performed 10 hours after ingestion, showing a greenish-gray lumpy magma-like consistency due to leakage of battery contents. The 2 batteries were sequentially removed with alligator-jaw forceps. After flushing and aspiration of the chemical material, a broad and circumferential injury with denudation of the mucosa and two deep ulcerations with necrosis were observed where the batteries had been. The batteries' seals were eroded, releasing chemical contents. Despite the severity of the injuries, the patient progressed favorably and there was no esophageal perforation. Esophageal impaction of cell batteries should always be considered an endoscopic urgency.

  19. Investigations in CO2 laser beam caustics measuring techniques

    DEFF Research Database (Denmark)

    Olsen, Flemming Ove; Bagger, Claus

    2004-01-01

    The performance of an industrial laser is very much depending upon the characteristics of the laser beam. The ISO standards 11146 and 11154 which are describing test methods for laser beam parameters have been approved.......The performance of an industrial laser is very much depending upon the characteristics of the laser beam. The ISO standards 11146 and 11154 which are describing test methods for laser beam parameters have been approved....

  20. Seen and Unseen Tidal Caustics in the Andromeda Galaxy

    NARCIS (Netherlands)

    Sanderson, R. E.; Bertschinger, E.

    2010-01-01

    Indirect detection of high-energy particles from dark matter interactions is a promising avenue for learning more about dark matter, but is hampered by the frequent coincidence of high-energy astrophysical sources of such particles with putative high-density regions of dark matter. We calculate the

  1. RESEARCH OF INTERACTION BETWEEN CAUSTIC MAGNESITE AND A MICROSILICA ADDITIVE

    Directory of Open Access Journals (Sweden)

    Ustinova Yuliya Valerevna

    2012-10-01

    Compressive strength of the dry mix containing 10 % of microsilica has been measured. In the event of hydraulic hardening, the compressive strength of the dry mix is 11.5 MPa, while the compressive strength of the water-saturated mix is equal to 12.0 MPa. In the aftermath of the air-setting procedure, the compressive strength of the dry mix is 10.0 MPa, while the compressive strength of the water-saturated mix is 21.0 MPa. The IR spectra of the specimen exhibit vibrations at 1100-400 cm-1 that correspond to the area of Si-O and Si-O-Me stretching vibrations, a peak at 1121-1119 cm-1 that can be assigned to Si-O-Si bond vibrations, and a peak at 474-472 characteristic of Si-O-Mg stretching vibrations. The areas of 3700-3000 cm-1 and 1650-1600 cm-1 are assigned to stretching and deformational vibrations of OH groups, respectively.

  2. Prediction of complications following caustic ingestion in adults

    DEFF Research Database (Denmark)

    Christesen, H B

    1995-01-01

    submucosal, circumferential oesophageal injuries (P = 0.003). The study suggests that only adults with symptoms or signs following strong alkali or strong acid ingestion are at risk of complications. In adults who are symptomatic following ingestion of strong acid or alkali, oesophagoscopy is important...

  3. Acceptance test report: Field test of mixer pump for 241-AN-107 caustic addition project

    Energy Technology Data Exchange (ETDEWEB)

    Leshikar, G.A.

    1997-05-16

    The field acceptance test of a 75 HP mixer pump (Hazleton serial number N-20801) installed in Tank 241-AN-107 was conducted from October 1995 thru February 1996. The objectives defined in the acceptance test were successfully met, with two exceptions recorded. The acceptance test encompassed field verification of mixer pump turntable rotation set-up and operation, verification that the pump instrumentation functions within established limits, facilitation of baseline data collection from the mixer pump mounted ultrasonic instrumentation, verification of mixer pump water flush system operation and validation of a procedure for its operation, and several brief test runs (bump) of the mixer pump.

  4. RESULTS OF PHYSICOCHEMICAL CHARACTERIZATION AND CAUSTIC DISSOLUTION TESTS ON TANK 241-C-108 HEEL SOLIDS

    Energy Technology Data Exchange (ETDEWEB)

    CALLAWAY WS; HUBER HJ

    2010-07-01

    Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

  5. Caustics as an Alternate of Ray Tracing to Evaluate Heliostat Mirrors

    OpenAIRE

    Georgiou, Marios D.; Bonanos, Aristides M.; Georgiadis, John G.

    2013-01-01

    Solar thermal power generation is based on the concept of concentrating solar radiation to provide high temperature heat for electricity generation via conventional power cycles. The high relative cost of optical subsystems necessitates a careful study of their components. The capital cost of the heliostat field in central receiver power plants is significant, reaching up to 50% of the capital investment. Therefore, it is essential to maximize the energy yield from a heliostat with a given mi...

  6. Caustic Waste-Soil Weathering Reactions and Their Impacts on Trace Contaminant Migration and Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Jon Chorover; Dr. Karl T. Mueller; Dr. Peggy O' Day; R. Jeff Serne

    2006-12-11

    The principal goal of this project was to assess the molecular nature and stability of radionuclide immobilization during weathering reactions in bulk Hanford sediments and their high surface area clay mineral constitutents.

  7. Caustic Recycle from Hanford Tank Waste Using NaSICON Ceramic Membrane Salt Splitting Process

    Energy Technology Data Exchange (ETDEWEB)

    Fountain, Matthew S.; Kurath, Dean E.; Sevigny, Gary J.; Poloski, Adam P.; Pendleton, J.; Balagopal, S.; Quist, M.; Clay, D.

    2009-02-20

    A family of inorganic ceramic materials, called sodium (Na) Super Ion Conductors (NaSICON), has been studied at Pacific Northwest National Laboratory (PNNL) to investigate their ability to separate sodium from radioactively contaminated sodium salt solutions for treating U.S. Department of Energy (DOE) tank wastes. Ceramatec Inc. developed and fabricated a membrane containing a proprietary NAS-GY material formulation that was electrochemically tested in a bench-scale apparatus with both a simulant and a radioactive tank-waste solution to determine the membrane performance when removing sodium from DOE tank wastes. Implementing this sodium separation process can result in significant cost savings by reducing the disposal volume of low-activity wastes and by producing a NaOH feedstock product for recycle into waste treatment processes such as sludge leaching, regenerating ion exchange resins, inhibiting corrosion in carbon-steel tanks, or retrieving tank wastes.

  8. Caustic Recycle from Hanford Tank Waste Using Large Area NaSICON Structures (LANS)

    Energy Technology Data Exchange (ETDEWEB)

    Fountain, Matthew S.; Sevigny, Gary J.; Balagopal, S.; Bhavaraju, S.

    2009-03-31

    This report presents the results of a 5-day test of an electrochemical bench-scale apparatus using a proprietary (NAS-GY) material formulation of a (Na) Super Ion Conductor (NaSICON) membrane in a Large Area NaSICON Structures (LANS) configuration. The primary objectives of this work were to assess system performance, membrane seal integrity, and material degradation while removing Na from Group 5 and 6 tank waste from the Hanford Site.

  9. Pad ultrasonic batch dyeing of causticized lyocell fabric with reactive dyes.

    Science.gov (United States)

    Babar, Aijaz Ahmed; Peerzada, Mazhar Hussain; Jhatial, Abdul Khalique; Bughio, Noor-Ul-Ain

    2017-01-01

    Conventionally, cellulosic fabric dyed with reactive dyes requires significant amount of salt. However, the dyeing of a solvent spun regenerated cellulosic fiber is a critical process. This paper presents the dyeing results of lyocell fabrics dyed with conventional pad batch (CPB) and pad ultrasonic batch (PUB) processes. The dyeing of lyocell fabrics was carried out with two commercial dyes namely Drimarine Blue CL-BR and Ramazol Blue RGB. Dyeing parameters including concentration of sodium hydroxide, sodium carbonate and dwell time were compared for the two processes. The outcomes show that PUB dyed samples offered reasonably higher color yield and dye fixation than CPB dyed samples. A remarkable reduction of 12h in batching time, 18ml/l in NaOH and 05g/l in Na2CO3 quantity was observed for PUB processed samples producing similar results compared to CPB process, making PUB a more economical, productive and an environment friendly process. Color fastness examination witnessed identical results for both PUB and CPB methods. No significant change in surface morphology of PUB processed samples was observed through scanning electron microscope (SEM) analysis.

  10. Removal of Copper and Iron Contamination from Chromic Acid Electroplating Baths Using Electrodialysis with Caustic Catholyte

    Science.gov (United States)

    1991-06-01

    and other membrane processes have been applied to wastewater treatment. Some of these industrial applications for electrodialysis have been the...removal of salts from cheese whey , treatment of boiler feed waters, acid recovery in steel processing, and phosphoric acid concentration (19,20,22). In

  11. Mathematical Modelling of a Reduced Thermal Energy Consuming Spray Dryer for Evaporating Caustic Soda Solution

    Directory of Open Access Journals (Sweden)

    Babatope Olufemi

    2012-06-01

    Full Text Available Experimental demonstration, mathematical modelling and simulation of a technique for reducing thermal energy consumption in the diaphragm cell process using a techno-economically viable process to produce 73% wt. NaOH from electrolytic diaphragm cell catholytes of about 10% wt. NaOH was carried out in this work. The technique completely eradicated the use of thermal energy in concentrating catholyte effluents from about 10% wt. NaOH solution to 50% wt. NaOH solution. This resulted in a specific energy savings of about 2.68×106 J/kg NaOH. The use of a spray dryer for increasing the concentration of 50% wt. NaOH solution to 73% wt. NaOH solution further improved the energy savings compared to that of multiple effect evaporators by 1.41×106 J/kg of solution, which corresponds to about 61.05% specific energy savings. The deviation of all simulated results from experimental data was between -0.062 and +0.084, portraying a good predictive tool for probing into the spray dryer operations. This work is expected to reduce considerably the total energy consumption of the diaphragm cell process through process integration or new processing methodology, with improved equipment designs.

  12. 应大力开发的耗碱产品%Developing caustic soda consumption products

    Institute of Scientific and Technical Information of China (English)

    王林祥; 于家振; 周开明; 王冬松

    2002-01-01

    介绍了几种耗碱量大的精细化工产品,包括氯化橡胶、氯化聚丙烯、氯化聚氯乙烯、异氰尿酸衍生物(氯代异氰尿酸类系列、异氰尿酸缩水甘油酯及三烯丙基异氰尿酸酯)、烯丙醇、邻苯二甲酸二烯丙酯、漂粉精,通过对其生产工艺、耗碱量、市场等方面进行分析,确认这些产品值得国内氯碱企业关注.

  13. Gaia16aye is a binary microlensing event and is crossing the caustic again

    Science.gov (United States)

    Wyrzykowski, L.; Leto, G.; Altavilla, G.; Bakis, V.; Britavskiy, N.; Burgaz, U.; Butterley, T.; Carrasco, J. M.; Dhillon, V. S.; Dominik, M.; Gomboc, A.; Hardy, L. K.; Littlefair, S. P.; Maund, J. R.; Piascik, A.; Rhodes, L.; Sanchez, R. Z.; Sokolovsky, K. V.; Steele, I.; Wilson, R. W.; Hamanowicz, A.; Mroz, P.; Pawlak, M.; Rybicki, K.; Sitek, M.; Mikolajczyk, P.; Kolaczkowski, Z.; Street, R.; Bendjoya, P.; Bozza, V.; Dziedzic, J.; Niczyj, K.; Nowicki, R.; Porebski, M.

    2016-09-01

    Galactic Plane (Cygnus) transient, Gaia16aye, nicknamed Ayers Rock (19:40:01.13 +30:07:53.4, J2000), was discovered by Gaia Science Alerts, http://gsaweb.ast.cam.ac.uk/alerts/alert/Gaia16aye, on 2016-08-05 as a flare on an otherwise quiet star.

  14. Characterization of solids deposited on the modular caustic-side solvent extraction unit (MCU) coalescer media removed in October 2014

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-03-01

    In February 2015, Savannah River National Laboratory (SRNL) received a Strip Effluent (SE) coalescer (FLT-304) from MCU. That coalescer was first installed at MCU in July 2014 and removed in October 2014. While processing approximately 31,400 gallons of strip solution, the pressure drop steadily increased from 1 psi to beyond the administrative limit of 20 psi. The physical and chemical analysis was conducted on this coalescer to determine the mechanism that led to the plugging of this coalescer. Characterization of this coalescer revealed the adsorption of organic containing amines as well as MCU modifier. The amines are probably from the decomposition of the suppressor (TiDG) as well as from bacteria. This adsorption may have changed the surface energetics (characteristics) of the coalescer fibers and therefore, their wetting behavior. A very small amount of inorganic solids were found to have deposited on this coalescer (possibly an artifact of cleaning the coalescer with Boric acid. However, we believe that inorganic precipitation, as has been seen in the past, did not play a role in the high pressure drop rise of this coalescer. With regards to the current practice of reducing the radioactive content of the SE coalescer, it is recommended that future SE coalescer should be flushed with 10 mM boric acid which is currently used at MCU. Plugging of the SE coalescer was most likely due to the formation and accumulation of a water-in-oil emulsion that reduced the overall porosity of the coalescer. There is also evidence that a bimodal oil particle distribution may have entered and deposited in the coalescer and caused the initial increase in pressure drop.

  15. Final Report: Evaluation of Alternative Technologies for Ethylene, Caustic-Chlorine, Ethylene Oxide, Ammonia, and Terephthalic Acid

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2007-12-01

    This report evaluates alternative technologies for chemicals manufacturing which may present energy efficiency improvements compared to existing technologies. It is an extension of the Chemical Bandwidth Study, which evaluates energy and exergy losses in the U.S. chemicals industry.

  16. Pulsed Gamma Rays from the Original Millisecond and Black Widow Pulsars: a case for Caustic Radio Emission?

    CERN Document Server

    Guillemot, L; Venter, C; Kerr, M; Pancrazi, B; Livingstone, M; Janssen, G H; Jaroenjittichai, P; Kramer, M; Cognard, I; Stappers, B W; Harding, A K; Camilo, F; Espinoza, C M; Freire, P C C; Gargano, F; Grove, J E; Johnston, S; Michelson, P F; Noutsos, A; Parent, D; Ransom, S M; Ray, P S; Shannon, R; Smith, D A; Theureau, G; Thorsett, S E; Webb, N

    2011-01-01

    We report the detection of pulsed gamma-ray emission from the fast millisecond pulsars (MSPs) B1937+21 (also known as J1939+2134) and B1957+20 (J1959+2048) using 18 months of survey data recorded by the \\emph{Fermi} Large Area Telescope (LAT) and timing solutions based on radio observations conducted at the Westerbork and Nan\\c{c}ay radio telescopes. In addition, we analyzed archival \\emph{RXTE} and \\emph{XMM-Newton} X-ray data for the two MSPs, confirming the X-ray emission properties of PSR B1937+21 and finding evidence ($\\sim 4\\sigma$) for pulsed emission from PSR B1957+20 for the first time. In both cases the gamma-ray emission profile is characterized by two peaks separated by half a rotation and are in close alignment with components observed in radio and X-rays. These two pulsars join PSRs J0034-0534 and J2214+3000 to form an emerging class of gamma-ray MSPs with phase-aligned peaks in different energy bands. The modeling of the radio and gamma-ray emission profiles suggests co-located emission regions...

  17. Pulsed Gamma Rays from the Original Millisecond and Black Widow Pulsars: A Case for Caustic Radio Emission?

    Science.gov (United States)

    Guillemot, L.; Johnson, T. J.; Venter, C.; Kerr, M.; Pancrazi, B.; Livingstone, M.; Janssen, G. H.; Jaroenjittichai, P.; Kramer, M.; Cognard, I.; Stappers, B. W.; Harding, A. K.; Camilo, F.; Espinoza, C. M.; Freire, P. C. C.; Gargano, F.; Grove, J. E.; Johnston, S.; Michelson, P. F.; Noutsos, A.; Parent, D.; Ransom, S. M.; Ray, P. S.; Shannon, R.; Smith, D. A.; Theureau, G.; Thorsett, S. E.; Webb, N.

    2012-01-01

    We report the detection of pulsed gamma-ray emission from the fast millisecond pulsars (MSPs) B1937+21 (also known as J1939+2134) and B1957+20 (J1959+2048) using 18 months of survey data recorded by the Fermi Large Area Telescope and timing solutions based on radio observations conducted at the Westerbork and Nançay radio telescopes. In addition, we analyzed archival Rossi X-ray Timing Explorer and XMM-Newton X-ray data for the two MSPs, confirming the X-ray emission properties of PSR B1937+21 and finding evidence (~4σ) for pulsed emission from PSR B1957+20 for the first time. In both cases the gamma-ray emission profile is characterized by two peaks separated by half a rotation and are in close alignment with components observed in radio and X-rays. These two pulsars join PSRs J0034-0534 and J2214+3000 to form an emerging class of gamma-ray MSPs with phase-aligned peaks in different energy bands. The modeling of the radio and gamma-ray emission profiles suggests co-located emission regions in the outer magnetosphere.

  18. SALTSTONE VAULT CLASSIFICATION SAMPLES MODULAR CAUSTIC SIDE SOLVENT EXTRACTION UNIT/ACTINIDE REMOVAL PROCESS WASTE STREAM APRIL 2011

    Energy Technology Data Exchange (ETDEWEB)

    Eibling, R.

    2011-09-28

    Savannah River National Laboratory (SRNL) was asked to prepare saltstone from samples of Tank 50H obtained by SRNL on April 5, 2011 (Tank 50H sampling occurred on April 4, 2011) during 2QCY11 to determine the non-hazardous nature of the grout and for additional vault classification analyses. The samples were cured and shipped to Babcock & Wilcox Technical Services Group-Radioisotope and Analytical Chemistry Laboratory (B&W TSG-RACL) to perform the Toxic Characteristic Leaching Procedure (TCLP) and subsequent extract analysis on saltstone samples for the analytes required for the quarterly analysis saltstone sample. In addition to the eight toxic metals - arsenic, barium, cadmium, chromium, mercury, lead, selenium and silver - analytes included the underlying hazardous constituents (UHC) antimony, beryllium, nickel, and thallium which could not be eliminated from analysis by process knowledge. Additional inorganic species determined by B&W TSG-RACL include aluminum, boron, chloride, cobalt, copper, fluoride, iron, lithium, manganese, molybdenum, nitrate/nitrite as Nitrogen, strontium, sulfate, uranium, and zinc and the following radionuclides: gross alpha, gross beta/gamma, 3H, 60Co, 90Sr, 99Tc, 106Ru, 106Rh, 125Sb, 137Cs, 137mBa, 154Eu, 238Pu, 239/240Pu, 241Pu, 241Am, 242Cm, and 243/244Cm. B&W TSG-RACL provided subsamples to GEL Laboratories, LLC for analysis for the VOCs benzene, toluene, and 1-butanol. GEL also determines phenol (total) and the following radionuclides: 147Pm, 226Ra and 228Ra. Preparation of the 2QCY11 saltstone samples for the quarterly analysis and for vault classification purposes and the subsequent TCLP analyses of these samples showed that: (1) The saltstone waste form disposed of in the Saltstone Disposal Facility in 2QCY11 was not characteristically hazardous for toxicity. (2) The concentrations of the eight RCRA metals and UHCs identified as possible in the saltstone waste form were present at levels below the UTS. (3) Most of the inorganic species measured in the leachate do not exceed the MCL, SMCL or TW limits. (4) The inorganic waste species that exceeded the MCL by more than a factor of 10 were nitrate, nitrite and the sum of nitrate and nitrite. (5) Analyses met all quality assurance specifications of US EPA SW-846. (6) The organic species (benzene, toluene, 1-butanol, phenol) were either not detected or were less than reportable for the vault classification samples. (7) The gross alpha and radium isotopes could not be determined to the MCL because of the elevated background which raised the detection limits. (8) Most of the beta/gamma activity was from 137Cs and its daughter 137mBa. (9) The concentration of 137Cs and 90Sr were present in the leachate at concentrations 1/40th and 1/8th respectively than in the 2003 vault classification samples. The saltstone waste form placed in the Saltstone Disposal Facility in 2QCY11 met the SCHWMR R.61-79.261.24(b) RCRA metals requirements for a nonhazardous waste form. The TCLP leachate concentrations for nitrate, nitrite and the sum of nitrate and nitrite were greater than 10x the MCLs in SCDHEC Regulations R.61-107.19, Part I A, which confirms the Saltstone Disposal Facility classification as a Class 3 Landfill. The saltstone waste form placed in the Saltstone Disposal Facility in 2QCY11 met the R.61-79.268.48(a) non wastewater treatment standards.

  19. Ultrasonic Methods to Study Shadow Boundaries of Diffracting Cracks. Ultrasonic Caustics in NDE (Non-Destructive Evaluation).

    Science.gov (United States)

    1984-02-01

    structure was held together with waterproof cement . The edges of the structure were machined to form a sharp edge around the periphery. A small stainless...air gap. The composite structure was held together with waterproof cement . The edges of the L - structure were machined to form a sharp edge around

  20. Characterizing low-mass binaries from observation of long-timescale caustic-crossing gravitational microlensing events

    DEFF Research Database (Denmark)

    Shin, I.-G; Han, C.; Choi, J.-Y

    2012-01-01

    Despite the astrophysical importance of binary star systems, detections are limited to those located in small ranges of separations, distances, and masses and thus it is necessary to use a variety of observational techniques for a complete view of stellar multiplicity across a broad range of phys...

  1. Measures to decrease power consumption in caustic soda production%降低烧碱电耗的措施

    Institute of Scientific and Technical Information of China (English)

    赵晓涛; 宋晋华

    2006-01-01

    哈尔滨华尔化工有限公司采用降低槽电压和提高电流效率的措施后,电解槽完好率为100%,氯气产品纯度达到96.1%,氢气产品纯度达到98.6%,电解槽液面合格率达96.9%,电解液质量浓度稳定在115~140g/L.

  2. Curious case of gravitational lensing by binary black holes: a tale of two photon spheres, new relativistic images and caustics

    CERN Document Server

    Patil, Mandar; Narasimha, D

    2016-01-01

    Binary black holes have been in limelight off late due to the detection of gravitational waves from coalescing compact binaries in the events GW150914 and GW151226. In this paper we study gravitational lensing by the binary black holes modeled as equal mass Majumdar-Papapetrou dihole metric and show that this system displays features that are quite unprecedented and absent in any other lensing configuration investigated so far. We restrict our attention to the light rays which move on the plane midway between the two identical black holes, which allows us to employ techniques developed for the equatorial lensing in spherically symmetric spacetimes. If distance between the two black holes is below a certain threshold value, the system admits two photon spheres. As in the case of single black hole, infinitely many relativistic images are formed due to the light rays which turn back from the region outside the outer (unstable) photon sphere, all of which lie beyond a critical angular radius with respect to the l...

  3. Pulsed Gamma Rays from the Original Millisecond and Black Widow Pulsars: A Case for Caustic Radio Emission?

    Science.gov (United States)

    Guillemot, L.; Johnson, T. J.; Venter, C.; Kerr, M.; Pancrazi, B.; Livingstone, M.; Janssen, G. H.; Jaroenjittichai, P.; Kramer, M.; Cognard, I.; Stappers, B. W.; Harding, A. K.; Camilo, F.; Espinoza, C. M.; Freire, P. C. C.; Gargano, F.; Grove, J. E.; Johnston, S.; Michelson, P. F.; Noutsos, A.; Parent, D.; Ransom, S. M.; Ray, P. S.; Shannon, R.; Smith, D. A.

    2011-01-01

    We report the detection of pulsed gamma-ray emission from the fast millisecond pulsars (MSPs) B1937+21 (also known as J1939+2134) and B1957+20 (J1959+2048) using 18 months of survey data recorded by the Fermi Large Area Telescope (LAT) and timing solutions based on radio observations conducted at the Westerbork and Nancay radio telescopes. In addition, we analyzed archival RXTE and XMM-Newton X-ray data for the two MSPs, confirming the X-ray emission properties of PSR B1937+21 and finding evidence (approx. 4(sigma)) for pulsed emission from PSR B1957+20 for the first time. In both cases the gamma-ray emission profile is characterized by two peaks separated by half a rotation and are in close alignment with components observed in radio and X-rays. These two pulsars join PSRs J0034..0534 and J2214+3000 to form an emerging class of gamma-ray MSPs with phase-aligned peaks in different energy bands. The modeling of the radio and gamma-ray emission pro les suggests co-located emission regions in the outer magnetosphere.

  4. Hubble Space Telescope Discovery of a Probable Caustic-Crossing Event in the MACS1149 Galaxy Cluster Field

    Science.gov (United States)

    Kelly, Patrick L.; Rodney, Steven; Diego, Jose Maria; Zitrin, Adi; Broadhurst, Tom; Selsing, Jonatan; Balestra, Italo; Benito, Alberto Molino; Bradac, Marusa; Bradley, Larry; Brammer, Gabriel; Cenko, Brad; Christensen, Lise; Coe, Dan; Filippenko, Alexei V.; Foley, Ryan; Frye, Brenda; Graham, Melissa; Graur, Or; Grillo, Claudio; Hjorth, Jens; Howell, Andy; Jauzac, Mathilde; Jha, Saurabh; Kaiser, Nick; Kawamata, Ryota; Kneib, Jean-Paul; Lotz, Jennifer; Matheson, Thomas; McCully, Curtis; Merten, Julian; Nonino, Mario; Oguri, Masamune; Richard, Johan; Riess, Adam; Rosati, Piero; Schmidt, Kasper Borello; Sharon, Keren; Smith, Nathan; Strolger, Lou; Treu, Tommaso; Wang, Xin; Weiner, Ben; Williams, Liliya; Zheng, Weikang

    2016-05-01

    While monitoring the MACS1149 (z = 0.54) galaxy cluster as part of the RefsdalRedux program (PID 14199; PI Kelly) with the Hubble Space Telescope (HST) WFC3 IR camera, we have detected a rising transient that appears to be coincident ( Target-of-opportunity optical follow-up imaging in several ACS and WFC3 bands with the FrontierSN program (PID 14208; PI Rodney) has revealed that its rest-frame ultraviolet through optical spectrum may be reasonably well fit with that of a B star at z=1.49 exhibiting a strong Balmer break.

  5. Inorganic Chemicals Went Up

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ Caustic soda In August 2007, due to the increase of exported amount, the supply of caustic soda was tense in some local regions. The demand for caustic soda in the provinces including Shandong, Shanxi and Henan was brisk.

  6. Effects of Surface State and Applied Stress on Stress Corrosion Cracking of Alloy 690TT in Lead-containing Caustic Solution

    Institute of Scientific and Technical Information of China (English)

    Zhiming Zhang; Jianqiu Wang; En-Hou Han; Wei Ke

    2012-01-01

    The effects of surface state and applied stress on the stress corrosion cracking (SCC) behaviors of thermally treated (TT) Alloy 690 in 10 wt% NaOH solution with 100 mg/L litharge at 330 ℃ were investigated using C-ring samples with four kinds of surface states and two different stress levels. Sample outer surfaces of the first three kinds were ground to 400 grit (ground), shot-peened (SP) and electro-polished (EP) and the last one was used as the as-received state. Two samples of every kind were stressed to 100% and 200% yield stress of Alloy 690TT, respectively. The results showed that the oxide film consisted of three layers whereas continuous layer rich in Cr was not found. The poor adhesive ability indicated that the oxide film could not protect the matrix from further corrosion. Lead was found in the oxide film and the oxides at the crack paths and accelerated the dissolution of thermodynamically unstable Cr in these locations and also in the matrix. The crack initiation and propagation on Alloy 690TT were effectively retarded by SP and EP treatments but were enhanced by grinding treatment, compared with the cracks on the as-received surface. The cracking severity was also enhanced by increasing the externally applied stress. The accelerated dissolution of Cr and the local tensile stress concentration in the near-surface layer caused by cold-working and higher applied stress reduced the SCC-resistance of Alloy 690TT in the studied solution.

  7. Design of Pipe Material around Ionic Membrane Caustic Soda Electrolyzer%离子膜烧碱电解槽附近管道材质的设计

    Institute of Scientific and Technical Information of China (English)

    郅红虹

    2012-01-01

    To assure the long -term stability running properties Of the pipe matefiais around electrolyzer are highly ionic membrane electrolyzer licensors at home and abroad,analyzes their advantages and disadvantages, and it could provide reference for design.%为保证电解槽离子膜的长期稳定运行,电解槽附近的工艺介质管道对材质的耐腐蚀性要求非常高。综合比较了目前国际常用的离子膜电解槽专利厂家的选材及其优缺点,以供设计参考。

  8. Demonstration of Caustic-Side Solvent Extraction with Optimized Solvent in the 2-cm Centrifugal Contactor Apparatus Using Dissolved Salt Cake from Tank 37H

    Energy Technology Data Exchange (ETDEWEB)

    Norato, M.A.

    2002-10-21

    A solvent extraction process for removal of cesium from alkaline solutions has been developed utilizing a novel solvent invented at the Oak Ridge National Laboratory (ORNL). This solvent consists of a calix[4]arene-crown-6 extractant (BOBCalix) dissolved in an inert hydrocarbon matrix (Isopar(R) L). An alkylphenoxy alcohol modifier added to the solvent enhances the extraction power of the calixarene and prevents the formation of a third phase. An additional additive, trioctylamine (TOA), improves stripping performance and mitigates the effects of any surfactants present in the feed stream. The solvent extraction process was successfully demonstrated with actual SRS HLW supernate during testing performed at SRTC in FY-2001. However, the solvent system has recently been optimized to enhance extractant solubility in the diluent and increase suppressor concentration. The results of the optimized solvent performance in tests using the same SRS composite waste supernate as was used FY-20 01 are described in another report.

  9. Terapia nutricional en pacientes adultos con quemaduras del tracto gastrointestinal por cáusticos Nutrition therapy for adult patients with caustic injuries to gastrointestinal tract

    OpenAIRE

    N. A. Muñoz Botero; A. M.ª Pérez Cano; R. Rodríguez Herrera; M. P. Rojas Gómez; F. A. Soler Páez

    2010-01-01

    Objetivos: Presentar la experiencia del Grupo de Terapia Nutricional del Hospital El Tunal, en el manejo nutricional de pacientes adultos con quemaduras por cáusticos del tracto gastrointestinal. Materiales y métodos: Es un estudio retrospectivo, descriptivo de pacientes manejados por el Grupo de Terapia Nutricional por quemaduras por cáusticos del tracto gastrointestinal en un periodo comprendido entre Enero de 2000 y Diciembre de 2007. Se revisaron las historias clínicas de los pacientes qu...

  10. Discussion on reduction in vapor consumption in film evaporation of caustic soda%烧碱膜式蒸发降低汽耗探讨

    Institute of Scientific and Technical Information of China (English)

    李春江

    2016-01-01

    分析升降膜法生产粒片碱过程中蒸汽消耗的影响因素,提出降低蒸汽消耗的措施:保证入料碱液成膜均匀性,及时排放蒸发器中的不凝气体,有效利用生蒸汽冷凝液,提高二次蒸汽利用率,合理采用蒸汽伴热,避免 蒸汽泄漏,减少碱损.

  11. 降低烧碱盐耗的有效措施%Effective Measures to Reduce NaCi Consumption in Caustic Soda Production

    Institute of Scientific and Technical Information of China (English)

    朱恪松; 李森; 高爱军

    2002-01-01

    从降低商品液碱的含盐量、减少设备跑冒滴漏、提高盐泥洗涤效率、控制废泥排出浓度和降低碱损等方面,论述降低烧碱盐耗的几项技术措施.措施实施后,效果良好.

  12. 优化蒸发工艺降低烧碱汽耗%Optimizing evaporation process to decrease the consumption of steam in the production of caustic soda

    Institute of Scientific and Technical Information of China (English)

    唐文军; 程静川; 刘凤仙

    2001-01-01

    为满足6万t/a烧碱生产规模的要求,山东滩坊亚星化学股份有限公司改造了原5万t/a烧碱蒸发装置:淡碱预热采用板式换热器二级预热工艺;Ⅱ效加热室加热面积由原来的284m2增到384m2;Ⅲ效抽真空管道直径增大;喷射冷凝器规格由Ф1 200增大到Ф1 600;I效加料泵扬程增高了30m.改造后的蒸发系统完全满足6万t/a烧碱生产要求,而且蒸发综合汽耗由原来的3.6t/(t@NaOH)降到3t/(t@NaOH).

  13. Element affected the escalation of the caustic soda power consumption in our plant%影响我厂烧碱电耗升高的因素

    Institute of Scientific and Technical Information of China (English)

    田粤海

    2001-01-01

    四平联合化工股份有限公司烧碱电耗升高因素主要表现在电流效率低、电压效率低,碱损失高.影响"两低一高"是多方面的,但突出的是电解负反应多,耗电和蒸发碱流失严重所致.

  14. Strengthening management to decrease electricity consumption in caustic soda production%加强管理力度降低烧碱电耗

    Institute of Scientific and Technical Information of China (English)

    崔长根; 侯素青; 赵贵成

    2001-01-01

    随着氯碱工业的迅速发展,中国烧碱产量已位居世界第2位。虽然离子膜法电解技术得到广泛应用,1999年生产能力已达200万t/a,但隔膜法烧碱仍占全国烧碱总量的76.4%,是国内生产烧碱的主要方法。对于如何降低烧碱成本是每个氯碱企业最关心的问题,而占烧碱成本近70%的电能消耗是这个问题的重中之重。……

  15. 采取有效措施努力降低烧碱吨碱电耗%Taking effective measures to reduce the power consumption of caustic soda

    Institute of Scientific and Technical Information of China (English)

    董兴; 李素改; 陈建科

    2000-01-01

    @@ 前言 近年来,我公司和全国多数企业一样陷入了需求不足、市场疲软、产品降价等重重困难之中.为了企业的生存和发展,使企业在竞争中立于不败之地,在生产活动中突出"节约挖潜,提质降耗"显得尤为重要.

  16. Brief discussion about energy conservation and consumption decrease in the production of diaphragm caustic soda%浅谈隔膜烧碱的节能降耗

    Institute of Scientific and Technical Information of China (English)

    牛宝云

    2001-01-01

    通过降低电极反应过电位、隔膜压降、溶液压降和接触电压降,达到降低槽电压的目的.保持电解液单槽浓度稳定性,提高槽温,保证隔膜吸附质量及入槽盐水质量,达到提高电流效率的目的.同时降低碱损失,确保隔膜烧碱生产过程中节能降耗.

  17. Inquiry of energy conservation and decrease of consumption of diaphragm caustic soda%隔膜碱节能降耗的探讨

    Institute of Scientific and Technical Information of China (English)

    陆涛

    2002-01-01

    @@ 我公司是以生产氯碱产品为主的化工企业,其中包括3万t/a隔膜烧碱和2万t/a离子膜烧碱.其中主要消耗包括电耗、汽耗、盐耗等.近几年,我们的隔膜烧碱电耗一直徘徊在2460 kW·h/t.为此,公司组织技术人员对电耗高的原因进行认真剖析,并采取相应的措施解决问题,降低电耗.

  18. 加强管理降低隔膜法烧碱电耗%Improving management to decrease power consumption in diaphragm caustic soda production

    Institute of Scientific and Technical Information of China (English)

    赵峰

    2007-01-01

    分析山东大成农药股份有限公司氯碱厂电耗突然升高的原因是精盐水质量差、石棉绒有问题,从精盐水质量和石棉绒两方面采取措施,提高了电流效率,降低了电耗.

  19. Discussion on methods for decreasing electricity consumption of diaphragm caustic soda%隔膜法烧碱降低电耗方法探讨

    Institute of Scientific and Technical Information of China (English)

    付为

    2010-01-01

    分析了影响烧碱电耗的诸多因素,从降低槽电压、选择运行电流密度和强化电解槽管理等角度介绍了降低烧碱电耗的技术措施.经改造,烧碱电耗由2 420 kW·ICt降至2 300 kW·h/t.

  20. An Evaluation of the Method and a Study of the Factors Involved in Using Fused Caustic Alkali for Preparing Metal Surfaces for Enameling

    Science.gov (United States)

    1946-01-01

    a. UM of Iroa •f effeeta at «ill at either or tha «athede -lthl* tha eleotrolr tic oaJl by alaply traUiag tk« dlreetioa of »lo«, far tha of...aoadiUoaa that atal to to aatotoa «an fall/ aUla Ito pr 1« la aparailaa. "to flrai «autiaa la •tar af acattorlag. totor aaa aaaar aaaa In contact...tNfttaMrt •"Ultt M >***1—«Ijr afe. irf^ ti*p ""•I««— tic «teaped by tio •»«lirtteal • «*tal <tt« u **1* •*fc«r»U«d ttr --•• "•• *° —* Pte

  1. Characterization of Solids Deposited on the Modular Caustic-Side Solvent Extraction Unit (MCU) Strip Effluent (SE) Coalescer Media Removed in April 2015

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F. F. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-06-13

    On June 2015, Savannah River National Laboratory (SRNL) received a Strip Effluent (SE) coalescer (FLT-304) from MCU. That coalescer was first installed at MCU in late October 2014 and removed in April 2015. While processing approximately 48,700 gallons of strip solution, the pressure drop steadily increased linearly from 1 psi to near 16 psi (the administrative limit is 17 psi) with the total filtrate volume (2.1E-4 psi/gal of filtrate). The linear behavior is due to the combined effect of a constant deposition of material that starts from the closed-end to the mid-section of the coalescer reducing the available surface area of the coalescer for fluid passage (linearly with filtrate volume) and the formation of a secondary emulsion (water in NG-CSSX) on the fibers of the coalescer media. Both effects reduced the coalescer porosity by at least 13% (after processing 48,700 gallons). Before the coalescer was removed, it was flushed with a 10 mM boric acid solution to reduce the dose level. To determine the nature of the deposited material, a physical and chemical analysis of the coalescer was conducted. Characterization of this coalescer revealed the adsorption of organic containing amines (secondary amides and primary amines), TiDG, degraded modifier (with no hydroxyl group), MaxCalix, and oxidized hydrocarbon (possibly from Isopar™L or from lubricant used at MCU) onto the coalescer media. The amide and amines are possibly from the decomposition of the suppressor (TiDG). The modifier and MaxCalix were the largest components of the deposited organic material, as determined from leaching the coalescer with dichloromethane. Both the Fourier-Transformed Infrared (FTIR) and Fourier-Transformed Hydrogen Nuclear Magnetic Resonance (FT-HNMR) results indicated that some of the modifier was degraded (missing their OH groups). The modifier was observed everywhere in the examined coalescer pieces (FTIR), while the TiDG and its decomposition products were observed at the entrance discs of the coalescer. A solvent trim (a cocktail of solvent components with a high concentration of modifier) was added to the solvent on 2/22/2015. It is believed that the trim did not mix completely with the solvent and that it was subsequently spread around the MCU components including the coalescers, where it may have deposited. Chronologically, the modifier, the TiDG’s decomposition products and silicates deposited on the entrance discs first and after the pressure drop increased significantly, parts of the coalescer media detached itself from the central porous steel mandrel and a significant amount of steel debris, mercury, titanium, and additional aluminum and silicates deposited on the coalescer.

  2. Recovery of kraft black liquor using the titanate process:kinetics of the direct causticization reaction between sodium tri-titanate and sodium carbonate

    OpenAIRE

    Nohlgren, Ingrid

    1999-01-01

    The solid state reaction between sodium tri-titanate and sodium carbonate, forming mainly sodium penta-titanate, was investigated. Experiments were carried out in a micro-differential reactor made of quartz glass at various temperatures between 800°C and 880°C and in a pilot fluidized bed reactor operated in a semi-batch mode. In the micro-differential reactor, basic kinetic data was obtained by measuring the release of carbon dioxide during the reaction. Different kinetic models were conside...

  3. 21 CFR 184.1763 - Sodium hydroxide.

    Science.gov (United States)

    2010-04-01

    ... HUMAN CONSUMPTION (CONTINUED) DIRECT FOOD SUBSTANCES AFFIRMED AS GENERALLY RECOGNIZED AS SAFE Listing of.... 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye....

  4. GEOMETRIC OPTICS FOR 3D-HARTREE-TYPE EQUATION WITH COULOMB POTENTIAL

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This article considers a family of 3D-Hartree-type equation with Coulomb potential |x|-1, whose initial data oscillates so that a caustic appears. In the linear geometric optics case, by using the Lagrangian integrals, a uniform description of the solution outside the caustic, and near the caustic are obtained.

  5. Causticity and Anti-corrosion Measures for Soil in Northwest Gobi Region%西北戈壁地区岩土腐蚀性与防腐措施分析

    Institute of Scientific and Technical Information of China (English)

    任治军; 任亚群; 宋志远

    2013-01-01

      本文针对±800kV哈密南-郑州特高压直流输电线路工程的岩土工程勘测实践,对西北戈壁地区特高压送电线路工程的场地土腐蚀性评价工作方法进行了论述,主要包括样本采取原则、取样点布置、试验结果分析等。在分析试验成果的基础上,根据规范对线路地基土的腐蚀性进行了综合评价,并提出了相应的防腐处理建议。%This thesis focuses on the geotechnical engineering practice of the 800kV direct-current (DC) transmission line project from south of Hami to Zhengzhou. Corrosive evaluation methods for site soil of the ultra-high voltage transmission line engineering in Northwest Gobi region are discussed, mainly including sampling principle, sampling point layout and test result analysis, etc. Based on the analysis of test results, comprehensive foundation soil corrosive evaluation is conducted and corresponding suggestions on anti-corrosive treatment are put forward according to relevant codes.

  6. DEMONSTRATION EXPERIMENT OF REMOVING SULFIDES FROM CAUSTIC SLUDGE BY CATALYTIC OXIDATION PROCESS AND COMMERCIAL APPLICATION%催化氧化法脱除碱渣中硫化物的实验研究与工业应用

    Institute of Scientific and Technical Information of China (English)

    郭克雄; 薛永红

    2007-01-01

    采用一种催化剂,用空气对汽油和液化石油气脱硫精制产生的含硫碱渣进行氧化脱硫处理.实验室实验和工业应用表明,当碱渣中加入适量该种催化剂时,在一定条件下用空气可将碱渣中毒性强的硫化物氧化转换成无毒的硫酸盐,脱硫效率达到90%以上.

  7. Cu(Ⅱ)ADSORPTION BY BAKERS YEAST BIOMASS: THE EFFECT OF ETHANOL AND CAUSTIC PRETREATMENT%乙醇和氢氧化钠预处理对面包酵母菌吸附Cu2+的影响

    Institute of Scientific and Technical Information of China (English)

    张云松; 王仁国; 陈沿利; 童冬梅; 雷三忠

    2008-01-01

    研究了面包酵母菌及由无水乙醇和氢氧化钠分别处理的面包酵母菌对Cu2+的生物吸附作用.结果表明,菌样在pH 5,菌量1g·1-1,吸附时间20min,Cu2+25mg·1-1时,最大吸附量分别为2.42,3.3和5.73mg·g-1,吸附过程符合Langmuir等温吸附模型.菌主要依靠表面活性基团吸附Cu2+.预处理作用增加了菌表面活性基团的数量及活性.在吸附过程中静电作用可能对吸附有一定的影响.另外,菌样对Cu2+的吸附以可逆吸附为主,并不同程度地存在不可逆吸附.

  8. 反渗透+混床纯水工艺在离子膜法制碱生产中的应用%Application of Inverse Penetration + Mixed Bed Pure Water Process in Ionic Membrane Caustic Soda Production

    Institute of Scientific and Technical Information of China (English)

    闫健; 王亚军

    2009-01-01

    纯水即去离子水,是将水中的金属离子和非金属离子进行去除,提高水的电阻率,降低电导率。离子膜法制碱生产中,二次盐水精制树脂塔的再生,进电解槽盐水和阴极液的稀释都需要用纯水,如果纯水中钙、镁等金属离子含量高、电导率大就会造成槽电压升高,直流电耗高,影响到离子膜的使用寿命。

  9. Treatment of 0-Phenylphenol by Liquid Caustic Soda: Counter-current Extraction and Purification%邻苯基苯酚的碱液处理-逆流萃取提纯

    Institute of Scientific and Technical Information of China (English)

    陈业强; 袁慎峰; 陈志荣

    2010-01-01

    研究了1种碱液处理结合二级逆流萃取提纯邻苯基苯酚的方法,通过理论推导,得到了影响邻苯基苯酚收率的主要因素;对萃取剂进行了筛选,实验优化了影响邻苯基苯酚收率各因素.结果表明,选择萃取剂C最为适宜;最佳操作条件是:NaOH和OPP的摩尔比为1.01:1.00,萃取剂C和NaOH溶液的体积比为0.35:1.00.NaOH的质量分数为11%.采用优化后的工艺,能将邻苯基苯酚的纯度提高到99.5%,收率为97.4%.该方法能耗低、收率高.

  10. Method of reducing electric consumption of caustic soda production at unstable running current%运行电流不稳时降低烧碱电耗的途径

    Institute of Scientific and Technical Information of China (English)

    李伟成

    2002-01-01

    分析了烧碱生产中影响电耗的原因,建议:合理改造工艺,加强盐水质量管理,确保入槽盐水质量;并在停车期间采用保护措施,降低碱损失,建立健全电解槽管理工作,以期降低电耗.

  11. 采用扩张阳极与改性隔膜技术降低隔膜法烧碱电耗%Reducing the electricity consumption in diaphragm caustic soda production by anode expansion and diaphragm modification techniques

    Institute of Scientific and Technical Information of China (English)

    高自建; 丁晓玲

    2006-01-01

    对改性隔膜与扩张阳极电解槽技术的理论依据、技术特点进行了简要介绍,阐述了制作改性隔膜所用的石棉绒及改性剂.采用改性隔膜扩张阳极技术的电解槽比普通隔膜电解槽单槽电压可降低0.15 V左右,生产1 t烧碱可节电105 kW·h.

  12. 三效四体烧碱蒸发汽耗最少的操作压力%Operation Pressure to Attain to Minimal Steam Consumption of Three-effect/Four-part Caustic Soda Evaporation

    Institute of Scientific and Technical Information of China (English)

    孙波; 兰集明

    2005-01-01

    利用数学模型,通过计算机模拟,针对三效四体烧碱蒸发过程,在相同的生产量下计算一效、末效一系列的生蒸汽压力,找到蒸汽消耗最少的压力组合,结果符合实际,对生产有指导意义.

  13. The optimal pressure to minimize steam consumption during caustic soda evaporation in a three -effect four- body evaporator%三效四体烧碱蒸发中汽耗最少的操作压力

    Institute of Scientific and Technical Information of China (English)

    孙波

    2006-01-01

    利用数学模型,通过计算机模拟,针对三效四体烧碱蒸发过程,在生产量相同的情况下计算Ⅰ效、末效一系列的生蒸汽压力,找到蒸汽消耗最少的压力组合,结果符合实际.

  14. Study of lime adding points to reduce consumption of caustic soda in Bayer digestion of bauxite%改变石灰添加点降低铝土矿拜耳法溶出碱耗的研究

    Institute of Scientific and Technical Information of China (English)

    陈文汨; 黄伟光; 陈学刚

    2008-01-01

    拜耳法生产氧化铝过程中的碱耗在生产成本中占很大比例.引起碱耗的主要因素是大部分含硅矿物在溶出过程中生成钠硅渣.根据赤泥的钠硅比(N/S)可以判断碱耗的高低.石灰对铝土矿溶出赤泥N/S有着重大影响.本文试图改变石灰添加点来降低溶出赤泥N/S.试验研究结果表明,在溶出温度下添加石灰乳对降低碱耗效果比较明显,在预热温度区添加石灰乳对降低碱耗有效果,但降低幅度不大,在闪蒸温度区添加石灰乳对降低碱耗没效果,甚至增加碱耗.

  15. Brief discussion about energy conservation and consumption decrease in the production of diaphragm caustic soda%SZ-4型氢气泵与2BE1-303型氢气压缩机组比较

    Institute of Scientific and Technical Information of China (English)

    董锦萍; 杨桐年

    2001-01-01

    锦化化工(集团)有限责任公司8万t/a离子膜装置采用SZ-4氢气泵,12万t/a离子膜装置采用2BE1-303型氢气压缩机.文中对这两种设备进行了对比,认为氢气压缩机比SZ-4氢气泵先进,且投资低.

  16. Study and Commercial Test on Technology for Deacidification of Distillate Oils

    Institute of Scientific and Technical Information of China (English)

    Tang Xiaodong; An Rong; Cui Yingxian; Du Hongyong

    2005-01-01

    A new kind of solvent for deacidification of distillate oils was introduced in this paper. After successful laboratory study this technology had been applied in commercial scale successfully. Compared to traditional caustic wash of distillate oils, this technology has a lot of merits, such as the broad range of distillates to be processed, low caustic consumption, recycle of deacidifying agent, absence of waste caustic discharge, and low equipment revamp expenses, which can have promising perspectives for exploitation and application of this technology.

  17. 46 CFR 151.12-5 - Equipment for Category D NLS.

    Science.gov (United States)

    2010-10-01

    ... Adiponitrile Aminoethylethanolamine Ammonium bisulfite solution Butyl methacrylate Caustic soda solution Coal tar pitch Cyclohexanone Cyclohexanone, Cychexanol mixture Dichloromethane 2,2-Dichloropropionic...

  18. Commercial Test of Two Diesel Demulsifiers

    Institute of Scientific and Technical Information of China (English)

    Wang Xiaohong

    2003-01-01

    PetroChina Lanzhou Petrochemical Company conducted commercial tests for application of two types of diesel demulsifiers, the HPL-2 and GX-02 demulsifiers, in order to solve the emulsion problem arising from caustic washing of straight-run diesel fraction obtained from atmospheric and vacuum distillation unit at the Lanzhou refinery. After addition of each demulsifier into the diesel fraction the oil content in caustic residue was apparently decreased, and discharge of waste caustic was reduced, resulting in the elimination of emulsification and a significant increase of economic benefits. When 70 ppm of the HPL-2 demulsifier was added to diesel fraction, the oil content in waste caustic exiting the second-stage caustic wash settling tank was reduced to 2.45% from 7.90 %, whereas this value was reduced to 2.81% from 5.96% with addition of the GX-02 demulsifier.

  19. 爆炸载荷下动态焦散图像的自动化处理

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Base on the theory of caustics method and the technology of digital image processing,a system of image automatic processing for dynamic caustic was developed. Aiming at dynamic stress intensity factor (SIF)of the model I crack, the formula adapting to image processing was deduced. This system can deal with transmitted dynamic caustic image under the blast loading measuring model. Not only the model I stress intensity factor but also the crack propagation distance and velocity can be calculated. The case studies were carried out to verify the validity and reliability of the system. Fig. 6 Ref. 10

  20. Sodium hydroxide poisoning

    Science.gov (United States)

    Sodium hydroxide is a very strong chemical. It is also known as lye and caustic soda. This ... poisoning from touching, breathing in (inhaling), or swallowing sodium hydroxide. This article is for information only. Do ...

  1. Biocide Susceptibility of Staphylococcus aureus CC398 and CC30 Isolates from Pigs and Identification of the Biocide Resistance Genes, qacG and qacC

    DEFF Research Database (Denmark)

    Seier-Petersen, Maria Amalie; Nielsen, Lene Nørby; Ingmer, Hanne

    2015-01-01

    farming (benzalkonium chloride, hydrogen peroxide, formaldehyde, sodium hypochlorite, and caustic soda). Furthermore, efflux pump activity, antimicrobial resistance profiles, hemolysis properties, and the presence of toxic shock syndrome toxin-1 (TSST-1) and Panton-Valentine Leukocidin (PVL...

  2. The Absorption Characteristics of Inhomogeneous Double-Clad Fibers

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The absorption characteristics of radially inhomogeneous double-clad fiber (DCF) are investigated firstly with the method of caustic radius, combined with the method of WKBJ. The results are significant for double-clad optical fiber lasers and amplifiers.

  3. 21 CFR 1230.13 - Labeling of “poison”.

    Science.gov (United States)

    2010-04-01

    ... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than...

  4. Environ: E00579 [KEGG MEDICUS

    Lifescience Database Archive (English)

    Full Text Available E00579 Processed aconitum japonicum tuberous root Crude drug Aconitum japonicum, Ac...t with caustic lime (dried) Crude drugs [BR:br08305] Dicot plants: others Ranunculaceae (buttercup family) E00579 Processed aconitum japonicum tuberous root ...

  5. Chemical milling solution produces smooth surface finish on aluminum

    Science.gov (United States)

    Lorenzen, H. C.

    1966-01-01

    Elementary sulfur mixed into a solution of caustic soda and salts produces an etchant which will chemically mill end-grain surfaces on aluminum plate. This composition results in the least amount of thickness variation and pitting.

  6. 77 FR 17012 - Foreign-Trade Zone 158-Vicksburg/Jackson, MS; Application for Manufacturing Authority; Morgan...

    Science.gov (United States)

    2012-03-23

    ... caustic soda wash process, which the applicant indicates are not produced by U.S. mills. The application... formed into covering sets, at which time they would be entered for consumption from the zone....

  7. THE CHEMICAL AND RADIATION RESISTANCE OF POLYPHENYLENE SULFIDE AS ENCOUNTERED IN THE NUCLEAR WASTE CLEANING PROCESSES

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F.

    2011-10-20

    Polyphenylene sulfide (PPS) is extremely resistant to gamma irradiation, caustic solution, and dilute nitric acid. PPS is the material of construction for the coalescers used in the Modular Caustic-Side Solvent Extraction Unit (MCU). After applying the equivalent of 16 years of gamma irradiation and several months of exposures to caustic solution, no dimensional changes nor chemical changes were detected in PPS whether the PPS was in fiber form or in a composite with E-glass fibers. However, PPS acts as a media for heterogeneous nucleation. In particular, PPS appears to favor aluminosilicate formation in saturated solutions of aluminum and silicon in caustic environments. Parallel testing, in progress, is examining the stability of PPS when exposed to the new solvent formulation under development for MCU. Preliminary data, after two months of exposure, PPS is remarkably stable to the new solvent.

  8. General Information about Melanoma

    Science.gov (United States)

    ... or cauterized (destroyed with a hot instrument, an electric current, or a caustic substance) because cancer cells ... or being studied in the treatment of melanoma: Signal transduction inhibitor therapy: Signal transduction inhibitors block signals ...

  9. Status report on solid control in leachates

    Energy Technology Data Exchange (ETDEWEB)

    Beahm, E.C.; Weber, C.F.; Lee, D.D.; Dillow, T.A.; Hunt, R.D. [Oak Ridge National Lab., TN (United States); Keswa, C.M.; Osseo-Asare, K.; Spear, K.E. [Pennsylvania State Univ., University Park, PA (United States)

    1998-07-01

    Sludge pretreatment will involve some combination of washing and leaching with sodium hydroxide solutions to remove soluble salts and amphoteric material such as alumina. It is of paramount importance to prevent gelation and uncontrolled solid formation in tanks, transfer lines, and process equipment. An evaluation of results of washing and caustic leaching indicates that washing is more effective in dissolving sludge solids than subsequent sodium hydroxide treatment. Only aluminum and chromium were removed more effectively by caustic leaching than by water washing.

  10. Oil refinery hazardous effluents minimization by membrane filtration: An on-site pilot plant study.

    Science.gov (United States)

    Santos, Bruno; Crespo, João G; Santos, Maria António; Velizarov, Svetlozar

    2016-10-01

    Experiments for treating two different types of hazardous oil refinery effluents were performed in order to avoid/minimize their adverse impacts on the environment. First, refinery wastewater was subjected to ultrafiltration using a ceramic membrane, treatment, which did not provide an adequate reduction of the polar oil and grease content below the maximal contaminant level allowed. Therefore the option of reducing the polar oil and grease contamination at its main emission source point in the refinery - the spent caustic originating from the refinery kerosene caustic washing unit - using an alkaline-resistant nanofiltration polymeric membrane treatment was tested. It was found that at a constant operating pressure and temperature, 99.9% of the oil and grease and 97.7% of the COD content were rejected at this emission point. Moreover, no noticeable membrane fouling or permeate flux decrease were registered until a spent caustic volume concentration factor of 3. These results allow for a reuse of the purified permeate in the refinery operations, instead of a fresh caustic solution, which besides the improved safety and environmentally related benefits, can result in significant savings of 1.5 M€ per year at the current prices for the biggest Portuguese oil refinery. The capital investment needed for nanofiltration treatment of the spent caustic is estimated to be less than 10% of that associated with the conventional wet air oxidation treatment of the spent caustic that is greater than 9 M€. The payback period was estimated to be 1.1 years. The operating costs for the two treatment options are similar, but the reuse of the nanofiltration spent caustic concentrate for refinery pH control applications can further reduce the operating expenditures. Overall, the pilot plant results obtained and the process economics evaluation data indicate a safer, environmentally friendly and highly competitive solution offered by the proposed nanofiltration treatment, thus

  11. Electrical Activation Studies of Silicon Implanted Al(x)Ga(1-x)N

    Science.gov (United States)

    2005-03-01

    AlxGa1-xN has high cohesion energy which gives this semiconductor the ability to function in caustic environments and reduces its vulnerability to...in caustic or radioactive environments. Finally, group III-nitrides are desirable for use in optoelectronic devices because they have direct band...which sample is which throughout the process. 19. Visually examine the AlN surface for signs of Ga droplets, cracking/ peeling etc. (A good AlN

  12. Final Report on Contract N00014-76-C-0288, 1 September 1975 - 15 January 1986.

    Science.gov (United States)

    1986-03-14

    spreading are derived which are valid for very general types of sound-speed distributions of importance in ocean acoustics. Ray turning and caustic -contact...points are shown to either interlace or coincide. For periodic rays, the separations between adjacent turning or caustic -contact points are shown to...8217 Fleet Nu.merical Weather Central Attn% Dr. M. Sovik Monterey, California 93940 Se.nAttn. I. Peel Stevens I Superintendent Attn: W . lS n(s ) I Naval

  13. WKB Analysis of Bohmian Dynamics

    KAUST Repository

    Figalli, Alessio

    2013-10-18

    We consider a semiclassically scaled Schrödinger equation with WKB initial data. We prove that in the classical limit the corresponding Bohmian trajectories converge (locally in measure) to the classical trajectories before the appearance of the first caustic. In a second step we show that after caustic onset this convergence in general no longer holds. In addition, we provide numerical simulations of the Bohmian trajectories in the semiclassical regime that illustrate the above results. © 2014 Wiley Periodicals, Inc.

  14. PEP Support: Laboratory Scale Leaching and Permeate Stability Tests

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Buchmiller, William C.

    2010-05-21

    This report documents results from a variety of activities requested by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The activities related to caustic leaching, oxidative leaching, permeate precipitation behavior of waste as well as chromium (Cr) leaching are: • Model Input Boehmite Leaching Tests • Pretreatment Engineering Platform (PEP) Support Leaching Tests • PEP Parallel Leaching Tests • Precipitation Study Results • Cr Caustic and Oxidative Leaching Tests. Leaching test activities using the PEP simulant provided input to a boehmite dissolution model and determined the effect of temperature on mass loss during caustic leaching, the reaction rate constant for the boehmite dissolution, and the effect of aeration in enhancing the chromium dissolution during caustic leaching. Other tests were performed in parallel with the PEP tests to support the development of scaling factors for caustic and oxidative leaching. Another study determined if precipitate formed in the wash solution after the caustic leach in the PEP. Finally, the leaching characteristics of different chromium compounds under different conditions were examined to determine the best one to use in further testing.

  15. Using GC-FID to Quantify the Removal of 4-sec-Butylphenol from NGS Solvent by NaOH

    Energy Technology Data Exchange (ETDEWEB)

    Sloop, Jr., Frederick V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Moyer, Bruce A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-12-01

    A caustic wash of the solvent used in the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process was found to remove the modifier breakdown product 4-sec-butylphenol (SBP) with varying efficiency depending on the aqueous NaOH concentration. Recent efforts at ORNL have aimed at characterizing the flowsheet chemistry and reducing the technical uncertainties of the NG-CSSX process. One technical uncertainty has been the efficacy of caustic washing of the solvent for the removal of lipophilic anions, in particular, the efficient removal of SBP, an important degradation product of the solvent modifier, Cs-7SB. In order to make this determination, it was necessary to develop a sensitive and reliable analytical technique for the detection and quantitation of SBP. This report recounts the development of a GC-FID-based (Gas Chromatography Flame Ionization Detection) technique for analyzing SBP and the utilization of the technique to subsequently confirm the ability of the caustic wash to efficiently remove SBP from the Next Generation Solvent (NGS) used in NG-CSSX. In particular, the developed technique was used to monitor the amount of SBP removed from a simple solvent and the full NGS by contact with sodium hydroxide wash solutions over a range of concentrations. The results show that caustic washing removes SBP with effectively the same efficiency as it did in the original Caustic-Side Solvent Extraction (CSSX) process.

  16. Synthesis and reaction behavior of calcium silicate hydrate in basic system

    Institute of Scientific and Technical Information of China (English)

    刘桂华; 贺强; 李小斌; 彭志宏; 周秋生

    2004-01-01

    At the molar ratio of CaO to SiO2 of 1, with calcium hydroxide and sodium silicate, calcium silicate hydrate was synthesized at 50, 100, 170 ℃, respectively. The results show that temperature favors the formation of calcium silicate hydrate with perfect structure. When calcium silicate hydrate reacts with caustic solution, the decomposition rate of calcium silicate hydrate increases with the increasing caustic concentration and decreases with the raising synthesis temperature and the prolongation of reaction time. The decomposition rate is all less than 1.2 % in caustic solution, and XRD pattern of the residue after reaction with caustic solution is found as the same as that of original calcium silicate hydrate, which indicates the stable existence of calcium silicate hydrate in caustic solution.When reacted with soda solution, the decomposition rate increases with the increasing soda concentration and reaction time, while decreases with the synthesis temperature. The decomposition rate is more than 2% because CaO · SiO2 · H2O(CSH( Ⅰ )), except Ca5 (OH)2Si6O16 · 4H2O and Ca6Si6O17 (OH)2, is decomposed. So the synthesis temperature and soda concentration should be controlled in the process of transformation of sodium aluminosilicate hydrate into calcium silicate hydrate.

  17. Identification of members in the central and outer regions of galaxy clusters

    CERN Document Server

    Serra, Ana Laura

    2012-01-01

    The caustic technique measures the mass of galaxy clusters in both their virial and infall regions and, as a byproduct, yields the list of cluster galaxy members. Here we use 100 galaxy clusters with mass M200>=1E14 Msun/h extracted from a cosmological N-body simulation of a LambdaCDM universe to test the ability of the caustic technique to identify the cluster galaxy members. We identify the true three-dimensional members as the gravitationally bound galaxies. The caustic technique uses the caustic location in the redshift diagram to separate the cluster members from the interlopers. We apply the technique to mock catalogues containing 1000 galaxies in the field of view of 12 Mpc/h on a side at the cluster location. On average, this sample size roughly corresponds to 180 real galaxy members within 3r200, similar to recent redshift surveys of cluster regions. The caustic technique yields a completeness, the fraction of identified true members, fc=0.95 (+- 0.03) within 3r200. The contamination increases from f...

  18. A study of three techniques used in the diffraction analysis of shaped dual-reflector antennas

    Science.gov (United States)

    Cwik, Tom A.; Kildal, Per-Simon

    1989-01-01

    An examination is presented of three techniques used for the efficient computation of fields diffracted by a subreflector that has been shaped by geometrical optics synthesis. It is found that these techniques, which are based on the geometrical theory of diffraction (GTD), produce errors in the computed fields that are specific to shaped reflectors. These errors are examined for a reflector system shaped to produce maximum gain from a tapered feed illumination. The discrepancies are directly related to the caustic being located near an observation point of the GTD calculations. The errors found are localized, and they increase in magnitude as the caustic approaches the main reflector. In a general offset geometry, the location of the caustic may be located arbitrarily close to the main reflector given a prescribed output aperture distribution. For the specific case considered here-the common situation of shaping to produce maximum gain-the caustic is located near the edge of the main reflector and on the reflection shadow boundary. A local correction is derived which creates a uniform solution through the caustic and across the reflection shadow boundary. Away from this point the calculation receeds to the standard GTD solution.

  19. Semiclassical asymptotics for the scattering amplitude in the presence of focal points at infinity

    Energy Technology Data Exchange (ETDEWEB)

    Hohberger, H.

    2006-10-16

    We consider scattering in R{sup n}, n{>=}2, described by the Schroedinger operator P(h)=-h{sup 2}{delta}+V, where V is a short-range potential. With the aid of Maslov theory, we give a geometrical formula for the semiclassical asymptotics as h{yields}0 of the scattering amplitude f({omega}{sub -},{omega}{sub +};{lambda},h) ({omega}{sub +}{ne}{omega}{sub -}) which remains valid in the presence of focal points at infinity (caustics). Crucial for this analysis are precise estimates on the asymptotics of the classical phase trajectories and the relationship between caustics in euclidean phase space and caustics at infinity. (orig.)

  20. Alkaline Waterflooding Demonstration Project, Ranger Zone, Long Beach Unit, Wilmington Field, California. Fourth annual report, June 1979-May 1980. Volume 3. Appendices II-XVII

    Energy Technology Data Exchange (ETDEWEB)

    Carmichael, J.D.

    1981-03-01

    Volume 3 contains Appendices II through XVII: mixing instructions for sodium orthosilicate; oil displacement studies using THUMS C-331 crude oil and extracted reservoir core material from well B-110; clay mineral analysis of B-827-A cores; sieve analysis of 4 Fo sand samples from B-110-IA and 4 Fo sand samples from B-827-A; core record; delayed secondary caustic consumption tests; long-term alkaline consumption in reservoir sands; demulsification study for THUMS Long Beach Company, Island White; operating plans and instructions for DOE injection demonstration project, alkaline injection; caustic pilot-produced water test graphs; well test irregularities (6/1/79-5/31/80); alkaline flood pump changes (6/1/79-5/31/80); monthly DOE pilot chemical waterflood injection reports (preflush injection, alkaline-salt injection, and alkaline injection without salt); and caustic safety procedures-alkaline chemicals.

  1. Reducing operating costs for struvite formation with a carbon dioxide stripper.

    Science.gov (United States)

    Fattah, K P; Sabrina, N; Mavinic, D S; Koch, F A

    2008-01-01

    One of the major operational costs of phosphorus recovery as struvite is the cost of caustic chemical that is added to maintain a desired level of operative pH. A study was conducted at the Lulu Island Wastewater Treatment Plant (LIWWTP), Richmond, BC, using a struvite crystallizer and a cascade stripper designed at the University of British Columbia (UBC). The stripper was tested under different operating conditions to determine the effectiveness of CO(2) stripping in increasing the pH of the water matrix and thereby reducing caustic chemical use. This reduction is expected to reduce the operational costs of struvite production. Throughout the project, a high percentage (90%) of phosphorus removal was achieved under each condition. The cascade stripper was very effective in saving caustic usage, ranging from 35% to 86%, depending on the operating conditions. However, the stripper showed relatively poor performance regarding ammonia stripping.

  2. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    Energy Technology Data Exchange (ETDEWEB)

    HARRINGTON SJ

    2011-01-06

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  3. Survey of electrochemical production of inorganic compounds. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-10-01

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  4. A NEw Type of Ambiguity in the Planet and Binary Interpretations of Central Perturbations of High-Magnification Gravitational Microlensing Events

    CERN Document Server

    Choi, J -Y; Han, C; Udalski, A; Sumi, T; Gould, A; Bozza, V; Dominik, M; Fouqué, P; Horne, K; \\, M; Szymański, K; Kubiak, M; Soszyński, I; Pietrzyński, G; Poleski, R; Ulaczyk, K; Pietrukowicz, P; Kozłowski, S; Skowron, J; Wyrzykowski, Ł; Abe, F; Bennett, D P; Bond, I A; Botzler, C S; Chote, P; Freeman, M; Fukui, A; Furusawa, K; Itow, Y; Kobara, S; Ling, C H; Masuda, K; Matsubara, Y; Miyake, N; Muraki, Y; Ohmori, K; Ohnishi, K; Rattenbury, N J; Saito, To; Sullivan, D J; Suzuki, D; Suzuki, K; Sweatman, W L; Takino, S; Tristram, P J; Wada, K; Yock, P C M; Bramich, D M; Snodgrass, C; Steele, I A; Street, R A; Tsapras, Y; Alsubai, K A; Browne, P; Burgdorf, M J; Novati, S Calchi; Dodds, P; Dreizler, S; Fang, X -S; Grundahl, F; Gu, C -H; Hardis, S; Harpsøe, K; Hinse, T C; Hornstrup, A; Hundertmark, M; Jessen-Hansen, J; Jørgensen, U G; Kains, N; Kerins, E; Liebig, C; Lund, M; Lunkkvist, M; Mancini, L; Mathiasen, M; Penny, M T; Rahvar, S; Ricci, D; Scarpetta, G; Skottfelt, J; Southworth, J; Surdej, J; Tregloan-Reed, J; Wambsganss, J; Wertz, O; Almeida, L A; Batista, V; Christie, G; DePoy, D L; Dong, Subo; Gaudi, B S; Henderson, C; Jablonski, F; Lee, C -U; McCormick, J; McGregor, D; Moorhouse, D; Natusch, T; Ngan, H; Park, S -Y; Pogge, R W; Tan, T -G; Thornley, G; Yee, J C; Albrow, M D; Bachelet, E; Beaulieu, J -P; Brillant, S; Cassan, A; Cole, A A; Corrales, E; Coutures, C; Dieters, S; Prester, D Dominis; Donatowicz, J; Greenhill, J; Kubas, D; Marquette, J -B; Menzies, J W; Sahu, K C; Zub, M

    2012-01-01

    High-magnification microlensing events provide an important channel to detect planets. Perturbations near the peak of a high-magnification event can be produced either by a planet or a binary companion. It is known that central perturbations induced by both types of companions can be generally distinguished due to the basically different magnification pattern around caustics. In this paper, we present a case of central perturbations for which it is difficult to distinguish the planetary and binary interpretations. The peak of a lensing light curve affected by this perturbation appears to be blunt and flat. For a planetary case, this perturbation occurs when the source trajectory passes the negative perturbation region behind the back end of an arrowhead-shaped central caustic. For a binary case, a similar perturbation occurs for a source trajectory passing through the negative perturbation region between two cusps of an astroid-shaped caustic. We demonstrate the degeneracy for 2 high-magnification events of O...

  5. Modeling, simulation, and analysis of a reactor system for the generation of white liquor of a pulp and paper industry

    Directory of Open Access Journals (Sweden)

    Ricardo Andreola

    2011-02-01

    Full Text Available An industrial system for the production of white liquor of a pulp and paper industry, Klabin Paraná Papéis, formed by ten reactors was modeled, simulated, and analyzed. The developed model considered possible water losses by the evaporation and reaction, in addition to variations in the volumetric flow of lime mud across the reactors due to the composition variations. The model predictions agreed well with the process measurements at the plant and the results showed that the slaking reaction was nearly complete at the third causticizing reactor, while causticizing ends by the seventh reactor. Water loss due to slaking reaction and evaporation occurred more pronouncedly in the slaker reactor than in the final causticizing reactors; nevertheless, the lime mud flow remained nearly constant across the reactors.

  6. Modelling the Propagation of a Weak Fast-Mode MHD Shock Wave near a 2D Magnetic Null Point Using Nonlinear Geometrical Acoustics

    Science.gov (United States)

    Afanasyev, A. N.; Uralov, A. M.

    2012-10-01

    We present the results of analytical modelling of fast-mode magnetohydrodynamic wave propagation near a 2D magnetic null point. We consider both a linear wave and a weak shock and analyse their behaviour in cold and warm plasmas. We apply the nonlinear geometrical acoustics method based on the Wentzel-Kramers-Brillouin approximation. We calculate the wave amplitude, using the ray approximation and the laws of solitary shock wave damping. We find that a complex caustic is formed around the null point. Plasma heating is distributed in space and occurs at a caustic as well as near the null point due to substantial nonlinear damping of the shock wave. The shock wave passes through the null point even in a cold plasma. The complex shape of the wave front can be explained by the caustic pattern.

  7. Modelling the light curves of Fermi LAT millisecond pulsars

    CERN Document Server

    Venter, C; Harding, AK; Grove, JE

    2014-01-01

    We modelled the radio and gamma-ray light curves of millisecond pulsars using outer gap, two-pole caustic, low-altitude slot gap, and pair-starved polar cap geometric models, combined with a semi-empirical conal radio model. We find that no model fits all cases, with the outer gap and two-pole caustic models providing best fits for comparable numbers of millisecond pulsar light curves. We find a broad distribution of best-fit inclination angles as well as a clustering at large observer angles. The outer gap model furthermore seems to require relatively larger inclination angles, while the two-pole caustic model hints at an inverse trend between inclination angle and pulsar spin-down luminosity.

  8. Preparation of Al(OH)3 by ion membrane electrolysis and precipitation of sodium aluminate solution with seeds

    Institute of Scientific and Technical Information of China (English)

    LI Yuan-gao; CHEN Qi-yuan; WANG Song-sen; YIN Zhou-lan; ZHANG Ping-min

    2008-01-01

    The preparation of Al(OH)3 by the ion exchange membrane electrolysis followed by the precipitation of sodium aluminate solution with seeds was made. During the process of ion membrane electrolysis, the sodium aluminate solution is rapidly acidified and the caustic ratio (aK) is decreased due to oxygen evolution in the anodic region. And the causticity of solution is increased due to hydrogen evolution in the cathode region, producing the high concentration of caustic soda solution. Regulating the acidity of the anodic solution by controlling the electric quantity in the electrolysis and subsequent decomposing the solution, Al(OH)3 could yield with very large rate and high efficiency. The experiments also indicate that the quality of aluminum hydroxide product is greatly affected by the impurity silicon.

  9. Modelling the Propagation of a Weak Fast-Mode MHD Shock Wave near a 2D Magnetic Null Point Using Nonlinear Geometrical Acoustics

    CERN Document Server

    Afanasyev, Andrey N

    2012-01-01

    We present the results of analytical modelling of fast-mode magnetohydrodynamic wave propagation near a 2D magnetic null point. We consider both a linear wave and a weak shock and analyse their behaviour in cold and warm plasmas. We apply the nonlinear geometrical acoustics method based on the Wentzel-Kramers-Brillouin approximation. We calculate the wave amplitude, using the ray approximation and the laws of solitary shock wave damping. We find that a complex caustic is formed around the null point. Plasma heating is distributed in space and occurs at a caustic as well as near the null point due to substantial nonlinear damping of the shock wave. The shock wave passes through the null point even in a cold plasma. The complex shape of the wave front can be explained by the caustic pattern.

  10. Bitumen recovery from surface mined oil sands recycle water ponds

    Energy Technology Data Exchange (ETDEWEB)

    Mikula, R.J.; Munoz, V.A.; Elliott, G. L. [Natural Resources Canada, CanmetENERGY, Devon, Alberta (Canada)

    2011-07-01

    In surface mined oil sands, high bitumen recovery can be achieved but tailings have accumulated over the years. Several technologies have been proposed for recovering bitumen from tailings, but because this bitumen carries high surfactant concentrations there have been processing problems. This paper presents the application of oxidized ore characterization and processing methods to process tailings pond bitumen. Laboratory tests were carried out to characterize bitumen samples coming from four different tailings sources and tests were run with caustic additive. Results showed that high caustic additions can be applied to surfactant rich tailings pond bitumen to avoid downstream froth treatment emulsion problems; the oxidation degree should be carefully monitored. This study demonstrated that the use of caustic additive, already used for oxidized ores, can be applied to treat the bitumen recovered from tailings streams.

  11. PEP Run Report for Simulant Shakedown/Functional Testing

    Energy Technology Data Exchange (ETDEWEB)

    Josephson, Gary B.; Geeting, John GH; Bredt, Ofelia P.; Burns, Carolyn A.; Golovich, Elizabeth C.; Guzman-Leong, Consuelo E.; Kurath, Dean E.; Sevigny, Gary J.

    2009-12-29

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Waste Treatment Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes." The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-1, the 19-M NaOH is added to un-concentrated waste slurry (3-8 wt% solids), while for leaching in UFP-2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration

  12. Arbitrary non-paraxial accelerating periodic beams and spherical shaping of light

    CERN Document Server

    Mathis, A; Giust, R; Furfaro, L; Jacquot, M; Froehly, L; Dudley, J M

    2013-01-01

    We report the observation of arbitrary accelerating beams designed using a non-paraxial description of optical caustics. We use a spatial light modulator-based setup and techniques of Fourier optics to generate circular and Weber beams subtending over 95 degrees of arc. Applying a complementary binary mask also allows the generation of periodic accelerating beams taking the forms of snake-like trajectories, and the application of a rotation to the caustic allows the first experimental synthesis of optical accelerating beams upon the surface of a sphere in three dimensions.

  13. A method for preventing filters being blocked by clay in a well

    Energy Technology Data Exchange (ETDEWEB)

    Boldin, B.N.; Borodkina, N.I.; Kodzhoglyan, G.A.; Petrov, A.I.

    1983-01-01

    A method is proposed for eliminating claying of filters in wells, which includes the application of an easily removed protective coating on the filter and its subsequent destruction by the stratum fluid. It is distinguished by the fact that in order to increase the reliability of coverage through increasing the terms for solution, an acetonformaldehyde resin, hardened by a 35 percent aqueous solution of caustic soda, is used as the protective coating in the following relationship of components, in percent by mass: acetonformaldehyde resin, 94.0 to 97.0 and 35 percent solution of caustic soda, 3.0 to 6.0.

  14. A sealing mixture

    Energy Technology Data Exchange (ETDEWEB)

    Khayrullin, S.R.; Firsov, I.A.; Ongoyev, V.M.; Shekhtman, E.N.; Taskarin, B.T.

    1983-01-01

    A plugging mixture is proposed which contains triethanolamine, caustic soda, water and an additive. It is distinguished by the fact that in order to reduce the cost of the mixture while preserving its operational qualities, it additionally contains clay powder and as the additive, ground limestone with the following component ratio in percent by mass: ground limestone, 50 to 60; triethanolamine, 0.1 to 0.15; caustic soda, 2 to 3; clay powder, 8 to 10 and water the remainder. The mixture is distinguished by the fact that the ground limestone has a specific surface of 2,000 to 3,000 square centimeters per gram.

  15. Large fluctuations and singular behavior of nonequilibrium systems

    Science.gov (United States)

    Pinna, D.; Kent, A. D.; Stein, D. L.

    2016-01-01

    We present a general geometrical approach to the problem of escape from a metastable state in the presence of noise. The accompanying analysis leads to a simple condition, based on the norm of the drift field, for determining whether caustic singularities alter the escape trajectories when detailed balance is absent. We apply our methods to systems lacking detailed balance, including a nanomagnet with a biaxial magnetic anisotropy and subject to a spin-transfer torque. The approach described within allows determination of the regions of experimental parameter space that admit caustics.

  16. Waterproofing of thermally insulating products based on caustic dolomite ПОВЫШЕНИЕ ВОДОСТОЙКОСТИ ТЕПЛОИЗОЛЯЦИОННЫХ ИЗДЕЛИЙ НА ОСНОВЕ КАУСТИЧЕСКОГО ДОЛОМИТА

    Directory of Open Access Journals (Sweden)

    Zvezdina Yevgeniya Vasilevna

    2011-07-01

    Full Text Available The Constructional materials production based on magnesia cement, the waterproofing and the cold endurance of these materials is described. The composition and the hardening kinetics of magnesia cement is investigated.Рассмотрены получение строительных материалов на основе магнезиальных вяжущих; повышение водо- и морозостойкости этих материалов. Исследованы состав и кинетика твердения магнезиальных вяжущих.

  17. Evaluation on SCC behavior of alloy 690 using CERT

    Energy Technology Data Exchange (ETDEWEB)

    Sung, Jin Kyung; Jun, Jae Ho [Research Institute of Industrial Science and Technology, Pohang (Korea)

    1998-03-01

    CER tests were conducted to evaluated the effect of heat treatment on IGSCC susceptibility in 140 deg C 50% caustic solution at -900mVSCE. The results are as follows: 1) Heat treatment at low temperature for long time (600 deg C for 260hr) does not induce any caustic IG cracking, 2) grain boundaries appear to act as a preferential crack path when grain boundary carbon segregation is likely, 3) IGSCC in caustic solution does not seem to be caused by chromium depletion, 4) it is unlikely that grain boundary IG carbides play a role in caustic IGSCC susceptibility, and 5) carbon in solution enhanced the dissolution rate of alloy 600 significantly in 140 deg C 50% NaOH solution at -900mVSCE. Reverse U-bend test were conducted to evaluate IGSCC susceptibility of alloy 690 TT in 400 deg C 120bar steam for 1500hr. The results show that a tube from Inco ingot showed 100 {mu}m crack whereas a tube made by Chang Won Steel Co. does not show any crack at all. 16 refs., 30 figs., 3 tabs. (Author)

  18. State of the Art in Photon-Density Estimation

    DEFF Research Database (Denmark)

    Hachisuka, Toshiya; Jarosz, Wojciech; Georgiev, Iliyan

    2013-01-01

    Photon-density estimation techniques are a popular choice for simulating light transport in scenes with complicated geometry and materials. This class of algorithms can be used to accurately simulate inter-reflections, caustics, color bleeding, scattering in participating media, and subsurface sc...

  19. Thermal decomposition behaviour of polyacrylamidomethyltrimethyl ammonium chloride in red mud separation process

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    In order to provide references for selecting highly efficient red mud flocculants,the behaviour of polyacrylamidomethyltrimethyl ammonium chloride (PATAC) in red mud separation process was investigated.PATAC was employed as a flocculant for red mud separation from the caustic aluminate liquor at 95 ℃.The used red mud was generated from Chinese diaspore bauxite in Bayer process of alumina production.And the changes of PATAC before or after being treated in caustic solution at 95 ℃ were studied by thermogravimetry (TG) and Fourier transform infrared (FTIR) spectral analysis.The results show that PATAC fails in effectively flocculating red mud and PATAC is readily converted to a quaternary ammonium hydroxide (PATAH) in caustic solution.PATAH can be decomposed to a new polymer (HPATAH) even at 95 ℃.Furthermore,there is an intramolecular hydrogen bond formed in the HPATAH polymer chain with two functional groups of -CH2-OH and -CONH2.Therefore,the poor flocculation property of PATAC for red mud separation can be attributed to the thermal decomposition of PATAC in the caustic red mud slurry at 95 ℃ and the formation of intramolecular hydrogen bond in the polymer chain of HPATAH during the thermal decomposition,which causes the absorbable functional groups of PATAC to decrease greatly.

  20. Savannah River Site Salt Processing Project: FY2002 Research and Development Program Plan

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, Harry D.; Leugemors, Robert K.; Schlahta, Stephan N.; Fink, Samuel D.; Thompson, Major C.; Walker, Darrell D.

    2001-10-31

    This Plan describes the technology development program for alpha/strontium removal and Caustic Side Solvent Extraction cesium removal in FY2002. Crystalline Silicotitanate and Small Tank Tetratphenylborate Precipitation are discussed as possible backup technologies. Previous results are summarized in the Savannah River Site Salt Processing Project Research and Development Summary Report

  1. Brain Abscess after Esophageal Dilatation

    DEFF Research Database (Denmark)

    Gaïni, S; Grand, M; Michelsen, J

    2007-01-01

    with malaise, progressive lethargy, fever, aphasia and hemiparesis. Six days before she had been treated with esophageal dilatation for a stricture caused by accidental ingestion of caustic soda. The brain abscess was treated with surgery and antibiotics. She recovered completely. This clinical case...

  2. Development of bacterial resistance to biocides and antimicrobial agents as a consequence of biocide usage

    DEFF Research Database (Denmark)

    Seier-Petersen, Maria Amalie

    determined (Manuscript III). The biocides comprised benzalkonium chloride (BC), hydrogen peroxide (HP), sodium hypochlorite (SH), formaldehyde (FH), and caustic soda (NaOH). S. aureus isolates did in general not show reduced susceptibility to the biocides tested. However, a quaternary ammonium compound (QAC...

  3. [Colon cancer: a rare complication in a colonic esophageal segment after coloesophagoplasty].

    Science.gov (United States)

    Martín, Miguel Angel; Ferrás, Albio

    2005-01-01

    We report the case of a 65-year-old woman who presented to the Hermanos Ameijeiras Hospital in Cuba due to dysphagia for the previous 5 months. Forty years previously, she had undergone esophagocoloplasty for caustic esophagitis. Adenocarcinoma was diagnosed in the colonic interposition. The tumor was resected with oncologic margins and food transit was successfully restored.

  4. 19 CFR 12.4 - Exportation.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Exportation. 12.4 Section 12.4 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF HOMELAND SECURITY; DEPARTMENT OF THE TREASURY SPECIAL CLASSES... Caustic Or Corrosive Substances § 12.4 Exportation. The exportation of merchandise, the subject of §...

  5. Phase I Focused Corrective Measures Study/Feasibility Study for the L-Area Oil and Chemical Basin (904-83G)

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, E. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1997-02-01

    This report presents the completed Resource Conservation and Recovery Act (RCRA) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Focused Corrective Measures Study/Feasibility Study (CMS/FS) for the L-Area Oil and Chemical Basin (LAOCB)/L-Area Acid Caustic Basin (9LAACB) Solid Waste Management Unit/Operable Unit (SWMU/OU) at the Savannah River Site (SRS).

  6. The National Shipbuilding Research Program. Trailer Mounted Water Recovery and Reuse System

    Science.gov (United States)

    2000-11-30

    electrostatic ppt. Zn, TSS Sewer NASSCO 5,700 gal/yr (1998) Zn WWTF Note: Blank cells indicate that data was not available at this time. Key: gal...volume reduced in a period of time. Primarily, rinsing baths need to be of low conductivity to be good rinsers . Caustic drag out due to work-piece

  7. ATM-WPCC技术的开发应用及前景展望%Application and prospects of ATM-WPCC technology

    Institute of Scientific and Technical Information of China (English)

    俞正千; 胡楠; 王桂林

    2013-01-01

    阐述了碱回收苛化及白泥回收传统生产模式和工业碳酸钙生产原理与方法,比较分析了工业碳酸钙的大型工业生产方法与传统碱回收的苛化及白泥回收的异同,通过介绍ATM-WPCC技术(新型苛化及白泥资源化技术)生产WPCC(晶体白泥碳酸钙),阐明了实现碱回收苛化白泥处置与工业沉淀碳酸钙生产行业整合的技术可行性和整合的效益。%The traditional production process of causticizing and lime mud recovery in alkali recovery systems and industrial calcium carbonate production principle and method were explained, and comparative analysis on large scale industrial production method of industrial calcium carbonate with the similarities and differences of the traditional alkali recovery causticizing and lime mud recovery was conducted in this paper. The feasibility and integrated beneifts of integration of disposal of lime mud from alkali recovery causticizing and industrial precipitated calcium carbonate production technology were illustrated with introducing ATM-WPCC new causticizing process and the comprehensive utilization technology of lime mud to be used to produce calcium carbonate.

  8. Estimates for oscillatory integrals with convex phase

    Energy Technology Data Exchange (ETDEWEB)

    Chakhkiev, M A [Moscow State Social University, Moscow (Russian Federation)

    2006-02-28

    We consider methods for estimating one-dimensional oscillatory integrals with convex phase and amplitudes of bounded variation or Lipschitz class amplitudes. In particular, we improve the estimate for the Piercey integral with near-caustic parameter values, and also consider estimation methods for n-dimensional oscillatory integrals.

  9. 40 CFR Table 6 to Subpart IIIii of... - Examples of Techniques for Equipment Problem Identification, Leak Detection and Mercury Vapor

    Science.gov (United States)

    2010-07-01

    ...; cracks or spalling in cell room floors, pillars, or beams; caustic leaks; liquid mercury accumulations or... Problem Identification, Leak Detection and Mercury Vapor 6 Table 6 to Subpart IIIII of Part 63 Protection... Hazardous Air Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali Plants Pt. 63, Subpt....

  10. A New Colorimetric Assay of Tabletop Sweeteners Using a Modified Biuret Reagent: An Analytical Chemistry Experiment for the Undergraduate Curriculum

    Science.gov (United States)

    Fenk, Christopher J.; Kaufman, Nathan; Gerbig, Donald G., Jr.

    2007-01-01

    A new, fast and effective colorimetric analysis of the artificial sweetener aspartame is presented for application in undergraduate laboratory courses. This new method incorporates the use of a modified biuret reagent for selective detection and analysis of aspartame in aqueous solutions. The modified reagent is less caustic than the traditional…

  11. 21 CFR 1230.32 - Analyzing of samples.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Analyzing of samples. 1230.32 Section 1230.32 Food... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.32 Analyzing of samples. Samples collected by an authorized agent shall be analyzed at the laboratory designated by the Food and...

  12. Reflective and refractive objects for mixed reality.

    Science.gov (United States)

    Knecht, Martin; Traxler, Christoph; Winklhofer, Christoph; Wimmer, Michael

    2013-04-01

    In this paper, we present a novel rendering method which integrates reflective or refractive objects into a differential instant radiosity (DIR) framework usable for mixed-reality (MR) applications. This kind of objects are very special from the light interaction point of view, as they reflect and refract incident rays. Therefore they may cause high-frequency lighting effects known as caustics. Using instant-radiosity (IR) methods to approximate these high-frequency lighting effects would require a large amount of virtual point lights (VPLs) and is therefore not desirable due to real-time constraints. Instead, our approach combines differential instant radiosity with three other methods. One method handles more accurate reflections compared to simple cubemaps by using impostors. Another method is able to calculate two refractions in real-time, and the third method uses small quads to create caustic effects. Our proposed method replaces parts in light paths that belong to reflective or refractive objects using these three methods and thus tightly integrates into DIR. In contrast to previous methods which introduce reflective or refractive objects into MR scenarios, our method produces caustics that also emit additional indirect light. The method runs at real-time frame rates, and the results show that reflective and refractive objects with caustics improve the overall impression for MR scenarios.

  13. Extended characterization of M-Area settling basin and vicinity. Technical data summary. Revision

    Energy Technology Data Exchange (ETDEWEB)

    Pickett, J B

    1985-10-01

    The Savannah River Plant M-Area settling basin, an unlined surface impoundment, has received process effluents from the M-Area fuel and target fabrication facilities since 1958. The waste effluents have contained metal degreasing agents (chlorinated hydrocarbons), acids, caustics, and heavy metals. Data analyses are provided.

  14. Mental Ray特效渲染经典案例(下)

    Institute of Scientific and Technical Information of China (English)

    袁蕊

    2002-01-01

    @@ Mental Ray制造这一效果的实质是从灯光中产生光子(Photons).应用Mental Ray的ReflectiveCaustics,材质必须在Reflection贴图方式上有一个Raytrace或FlatMirror或Reflect/Refract贴图,并指定反射物体以产生聚光.

  15. 16 CFR 1209.5 - Test procedures for corrosiveness.

    Science.gov (United States)

    2010-01-01

    ... specimens. Thoroughly wash the metal coupons under running water and lightly brush them using a soft nylon... during the fabrication, cleaning or testing shall the metal coupons be touched by ungloved hands. (ii... minutes. Following vapor degreasing, subject the coupons to caustic and/or detergent washing...

  16. 40 CFR 407.20 - Applicability; description of the apple products subcategory.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Applicability; description of the apple... SOURCE CATEGORY Apple Products Subcategory § 407.20 Applicability; description of the apple products... apples into apple products. The processing of apples into caustic peeled or dehydrated products...

  17. New examples of sandwich gravitational waves and their impulsive limit

    CERN Document Server

    Podolsky, J

    1998-01-01

    Non-standard sandwich gravitational waves are constructed from the homogeneous pp vacuum solution and the motions of free test particles in the space-times are calculated explicitly. They demonstrate the caustic property of sandwich waves. By performing limits to impulsive gravitational wave it is demonstrated that the resulting particle motions are identical regardless of the ''initial'' sandwich.

  18. 21 CFR 1230.12 - Manufacturer; distributor.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Manufacturer; distributor. 1230.12 Section 1230.12... FEDERAL CAUSTIC POISON ACT Labeling § 1230.12 Manufacturer; distributor. If the name on the label or sticker is other than that of the manufacturer, it shall be qualified by such words as “packed...

  19. Development of a Water Treatment Plant Operation Manual Using an Algorithmic Approach.

    Science.gov (United States)

    Counts, Cary A.

    This document describes the steps to be followed in the development of a prescription manual for training of water treatment plant operators. Suggestions on how to prepare both flow and narrative prescriptions are provided for a variety of water treatment systems, including: raw water, flocculation, rapid sand filter, caustic soda feed, alum feed,…

  20. Internal structure of an optical null Ronchi grating test for a plano-parabolic lens.

    Science.gov (United States)

    Ortega-Vidals, Paula; Juárez-Reyes, Salvador Alejandro; Silva-Ortigoza, Gilberto; Cabrera-Rosas, Omar de J

    2016-01-01

    In this work we use geometrical optics and the caustic touching theorem, introduced by Berry, to describe the internal structure of the null Ronchi grating for a plano-parabolic lens illuminated by a point light source placed on the optical axis. The aim of this work is to explain the role of the caustic region in the process of morphology change between image and object in computing the null Ronchi grating. To this end, we obtain the analytic expression of the null Ronchi grating, and after that we deeply study the change in morphology between a single straight fringe image at the Ronchigram and the multiple curve rulings that can generate it (one open and one closed). We analyze exactly how multiple rulings generate the same straight image fringe, or how an entire ruling collapses into a single point image. For this analysis, we take different observation planes at different positions with respect to the caustic region. Finally, we characterize this topological change as one of two possible kinds depending on the relative position between the observation plane and the caustic region.

  1. Deposition of grids on plastic detectors

    CERN Document Server

    Birabeau, J P; Mendola, Onofrio

    1972-01-01

    In order to facilitate the locating of tracks of charged particles in cellulose-nitrate and polycarbonate (Makrofol, Lexan) foils, a method has been developed for the photo-deposition of translucent coordinate grids on these materials. The grids are resistant to the strongly caustic solutions used in developing tracks in plastic foils. (9 refs) .

  2. Production of grids in plastic detectors

    CERN Document Server

    Birabeau, J P; Brun, R; Cordaillat, A; Mendola, Onofrio

    1972-01-01

    In order to facilitate the locating of tracks of charged particles in cellulose nitrate and polycarbonate (makrofol, lexan) foils, a method has been developed for the photo-deposition of translucent coordinate grids on this materials. The grids are resistant to the strongly caustic solutions used in developing tracks in plastic foils. (9 refs) .

  3. Savannah River Site Salt Processing Project: FY2002 Research and Development Program Plan, Rev. 1

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, Harry D.; Leugemors, Robert K.; Schlahta, Stephan N.; Fink, Samuel D.; Thompson, Major C.; Walker, Darrell D.

    2001-12-10

    This Plan describes the technology development program for alpha/strontium removal and Caustic Side Solvent Extraction cesium removal in FY2002. Crystalline Silicotitanate and Small Tank Tetratphenylborate Precipitation are discussed as possible backup technologies. Previous results are summarized in the Savannah River Site Salt Processing Project Research and Development Summary Report.

  4. Washing of the AW-101 entrained solids

    Energy Technology Data Exchange (ETDEWEB)

    GJ Lumetta

    2000-03-31

    BNFL Inc. (BNFL) is under contract with the US Department of Energy, River Protection Project (DOE-RPP) to design, construct, and operate facilities for treating wastes stored in the single-shell and double-shell tanks at the Hanford Site, Richland, Washington. The DOE-BNFL RPP contract identifies two feeds to the waste treatment plant: (1) primarily liquid low-activity waste (LAW) consisting of less than 2 wt% entrained solids and (2) high-level waste (HLW) consisting of 10 to 200 g/L solids slurry. This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing on the composition of the entrained solids in the diluted AW-101 low-activity waste (LAW) sample. The objective of this work was to gather data on the solubility of the AW-101 entrained solids in 0.01 M NaOH, so that BNFL can evaluate whether these solids require caustic leaching. The work was conducted according to test plan BNFL-TP-29953-9, Rev. 0, LAW Entrained Solids Water Wash and Caustic Leach Testing. The test went according to plan, with no deviations from the test plan. Based on the results of the 0.01 M NaOH washing, a decision was made by BNFL to not proceed with the caustic leaching test. The composition of the washed solids was such that caustic leaching would not result in significant reduction in the immobilized HLW volume.

  5. Feasibility Study of Using Infrared Radiation Heating as a Sustainable Tomato Peeling Method

    Science.gov (United States)

    The yye peeling technique is putting both environmental and economic pressure on California tomato processing industry due to its associated salinity issues and wastewater disposal problems. This study is aimed at developing alternative peeling methods with reduced or no caustic usage to produce hi...

  6. The Relevance of Sarcasm in Resolving Ambiguous References in Spoken Discourse

    Science.gov (United States)

    Peters, Sara

    2013-01-01

    Sarcasm, or sarcastic irony, involves expressing a message that is often opposite of the literal meaning of what is being said, in a way that may sound bitter, or caustic (Gibbs, 1986). In the past, sarcasm has been viewed as a method of introducing the possibility of alternative interpretations of a discourse, by creating ambiguity as to the…

  7. First microlens mass measurement : Planet photometry of EROS BLG-2000-5

    NARCIS (Netherlands)

    An, JH; Albrow, MD; Beaulieu, JP; Caldwell, JAR; DePoy, DL; Dominik, M; Gaudi, BS; Gould, A; Greenhill, J; Hill, K; Kane, S; Martin, R; Menzies, J; Pogge, RW; Pollard, KR; Sackett, PD; Sahu, KC; Vermaak, P; Watson, R; Williams, A

    2002-01-01

    We analyze PLANET photometric observations of the caustic-crossing binary lens microlensing event, EROS BLG-2000-5, and find that modeling the observed light curve requires incorporation of the microlens parallax and the binary orbital motion. The projected Einstein radius ((r) over tilde (E) = 3.61

  8. Write it right a little blacklist of literary faults

    CERN Document Server

    Bierce, Ambrose

    2014-01-01

    American satirist and critic Ambrose Bierce may be best remembered for his caustic wit, but he was also a first-rate prose stylist who put a lot of effort into shaping the next generation of journalists and writers. Write it Right is Bierce's tough-love compendium of unforgivable literary sins.

  9. 40 CFR 437.2 - General definitions.

    Science.gov (United States)

    2010-07-01

    ... wastewater directly to waters of the United States or introduces wastewater to a publicly-owned treatment... treatment employing acid, caustic, solvent, clay and/or chemicals in order to produce high quality base... STANDARDS THE CENTRALIZED WASTE TREATMENT POINT SOURCE CATEGORY § 437.2 General definitions. As used in...

  10. Remembering Zinn: Confessions of a Radical Historian

    Science.gov (United States)

    Snodgrass, Michael

    2009-01-01

    Professor Howard Zinn was arguably America's best-known historian, despite the dismissive if not caustic response his book, "A People's History of the United States," elicited from historians. In Zinn's narrative the protagonists of history are "blacks, Indians, women, and working people of all kinds ... ordinary people trying to…

  11. 77 FR 21870 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Science.gov (United States)

    2012-04-12

    ... federal holidays. Greenup City Clerk's Office, Greenup Municipal Building, 115 Cumberland Avenue, Greenup... railroad right-of-way west of the Site and east of the municipal wastewater treatment plant. The local... a recycling plant. The facility processed waste materials such as oil, sludge, caustics,...

  12. Development and Testing of a Two-Stage Hybrid Launcher.

    Science.gov (United States)

    1979-10-31

    cracks occur in tungsten they will occur at the same place in the tantalum carbide, and that the tantalum carbide will not peel from the tungsten...the oil ano washed at 710C (IbOOF) in a caustic solition. The first temper was in air at 510uC (9050 F) for 8 hours and was preceded by a preheat at

  13. West Europe Report

    Science.gov (United States)

    2007-11-02

    related a number of examples in a provocative and caustic manner to show that the Europeans in the alliance always took the Russian side. Every...purposes of peat mining the scientists advise peeling off the upper cesium-containing layer. Future Very Uncertain in Forests In thin and

  14. The role of chemical peeling in the treatment of photodamaged skin.

    Science.gov (United States)

    Matarasso, S L; Salman, S M; Glogau, R G; Rogers, G S

    1990-10-01

    Management of the aging face involves evaluation of the degree of solar elastosis, rhytidosis, and the structural changes associated with senescent skin. Chemical facial exfoliation is divided into deep, medium, and superficial based upon depth of penetration of the caustic agent used. Knowledge of the appropriate indications and technique are essential in obtaining optimal clinical results.

  15. 76 FR 16379 - Foreign-Trade Zone 177-Evansville, IN; Application for Manufacturing Authority, Best Chair, Inc...

    Science.gov (United States)

    2011-03-23

    ..., 6005, 6006; duty rate range: 2.7-17.2%) finished with a caustic soda wash process, which the applicant... they are entered for consumption from the zone. Best Home would also have the option to elect the... domestic consumption. The application indicates that the savings from FTZ procedures would help improve...

  16. About the optical approximation of a laser beam; Sur l'approximation optique d'un faisceau laser

    Energy Technology Data Exchange (ETDEWEB)

    Solliec, I

    2000-01-01

    This paper deals with the numerical simulation of the laser absorption in a plasma. The aim of the study is the calculus of the energy deposit along the rays, in order to control the plasma temperature. In this framework, the asymptotical development of the Maxwell equation and the two-characteristics method are presented and the caustic is determined. (A.L.B.)

  17. Jinchuan Group Breaks Ground for a 300,000-ton Copper Deep Processing Project

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>According to Jinchang Municipal Government of Gansu,on August 21,Jinchuan Group broke ground for its 400,000-ton ionic membrane caustic soda project,300,000-ton PVC project,300,000-ton copper deep processing project,

  18. Water Quality Conditions in the Missouri River Mainstem System. 2010 Report

    Science.gov (United States)

    2011-11-01

    phosphorus, metals, sulfides , etc.) as the reduced conditions intensify and result in the production of toxic and caustic substances (e.g., hydrogen ...measures for the assessment of the Primary Contact Recreation Beneficial Use using cyanobacteria toxins data... sulfide , etc.). Most fish and other intolerant aquatic life cannot inhabit water with less than 4 to 5 mg/l dissolved oxygen for extended periods

  19. 75 FR 13786 - Biweekly Notice; Applications and Amendments to Facility Operating Licenses Involving No...

    Science.gov (United States)

    2010-03-23

    .... Upon receipt of a transmission, the E-Filing system time-stamps the document and sends the submitter an... . Carolina Power and Light Company, et al., Docket No. 50-400, Shearon Harris Nuclear Power Plant, Unit 1... caustic stress corrosion on mechanical systems and components. The proposed range of flow rate from...

  20. Rinsing Processes in Open-width Washing Machines

    NARCIS (Netherlands)

    Kroezen, A.B.J.; Linden, van der H.J.L.J.; Groot Wassink, J.

    1986-01-01

    A simulator is described for rinsing processes carried out on open-width washing machines. In combination with a theoretical model, a simple method is given for testing rinsing processes. The method has been used to investigate the extraction of caustic soda from a cotton fabric, varying the tempera

  1. Stability of calcium silicate in basic solution

    Institute of Scientific and Technical Information of China (English)

    刘桂华; 李小斌; 彭志宏; 周秋生

    2003-01-01

    Mixture of CaO and SiO2 was sintered at 1 200 or 1 400 ℃ according to the mole ratio of CaO/SiO2 of 1 or 2, and then calcium silicate was leached in pure caustic or soda solution. The results indicated that calcium silicate exists much more stably in caustic solution than that in soda solution, and CaO*SiO2 is more stable than β-2CaO*SiO2 whether in caustic solution or in soda solution. The increase of sintering temperature favored the stability of calcium silicate in the leaching process. When β-2CaO*SiO2 was leached in soda solution, the increase of leaching temperature and time resulted in decomposing of more calcium silicate. And when β-2CaO*SiO2 was leached in caustic solution at high temperature, much 2CaO*SiO2*H2O but little CaO*SiO2*H2O appeared in slag.

  2. PEP Support Laboratory Leaching and Permeate Stability Tests

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Buchmiller, William C.

    2009-09-25

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-VSL-T01A and B, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in

  3. EFRT M12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    Energy Technology Data Exchange (ETDEWEB)

    Rapko, Brian M.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2009-08-14

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to dissolve solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct steam injection to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP2, the slurry is concentrated to nominally

  4. Recycling of sludge with the Aqua Reci process.

    Science.gov (United States)

    Stendahl, K; Jäfverström, S

    2004-01-01

    Supercritical Water Oxidation (SCWO) is an innovative and effective destruction method for organics in sewage sludge. The SCWO process leaves a slurry of inorganic ash in a pure water phase free from organic contaminants, which opens possibilities for a simple process to recover components like phosphates and/or coagulants from the sewage sludge, a process marketed as the Aqua Reci. In a continuous pilot plant for the SCWO process digested sludge has been treated. The ash has been extracted in lab- and pilot scale with both caustic and acids in order to recover phosphates and coagulants. The particle size of the inorganic contaminants in the water after the SCWO process is between 1-10 microm, which means that it is very reactive. The phosphate, and partly the aluminium, can be extracted with caustic as iron and heavy metals are completely insoluble in caustic. This is a method to separate the phosphates from the rest of the contaminants. However, high calcium content will bind the phosphate as calcium phosphate insoluble in caustic. In most cases the calcium content is too high and the best solution is to dissolve phosphates and all metals with sulphuric acid. From this solution first iron phosphate can be separated and thereafter in a second step aluminium and finally heavy metals in a third step. Iron can be separated from the phosphate, either by leaching the phosphate with caustic off to sodium phosphate leaving a precipitate consisting of iron hydroxide, or the iron phosphate can be dissolved in hydrochloric acid followed by a liquid extraction process where ferric chloride can be separated leaving a phosphoric acid. By the acid dissolving process it is possible to recover phosphate, iron, aluminium, and heavy metals from the inorganic since the Aqua Reci process only leaves a silica residue representing about 10% of the DS content in the original sludge.

  5. Dynamic interfacial tension of finite reactive systems related to enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Chiwetelu, C.I.

    1988-01-01

    In enhanced oil recovery by caustic flooding, carboxylic acids in the crude oil react with the caustic reagents to form active soap species, which form at the interface and desorb to the bulk oleic and aqueous phases. Such reactive systems exhibit the dynamic interfacial tension phenomenon. In order to understand the mechanisms of carboxylic acid/caustic reagent interaction, a novel experimental scheme called photo-micropendography has been developed to measure dynamic interfacial tension. This method has been shown to give more reliable and consistent results than those obtained by spinning drop and ring tensiometries. An equilibrium model is proposed for interaction of single acids with various caustic solutions to enable important ionization properties to be determined with the aid of regression analysis. A diffusive kinetic model is also proposed to explain the dynamic interfacial behavior associated with single acids reacting with a range of aqueous caustic solutions. Good estimates of the adsorption rate constants which were the model parameters were obtained by correlating the experimental interfacial tension data with the aid of a sensitivity analysis of the problem. A generalized dynamic model has been advanced in order to rationalize the interaction of a multicomponent acid mixture contacting a spectrum of NaOH solutions. A detailed analysis for binary oleic/lauric acid mixtures was carried out to demonstrate the model's validity. Using parameter values for each acid determined from separate single-component studies, it was possible to obtain theoretical values for dynamic interfacial tension of the mixture. Generally satisfactory agreement was obtained between model predictions and experimental data. 115 refs., 89 figs., 91 tabs.

  6. IDENTIFICATION OF MEMBERS IN THE CENTRAL AND OUTER REGIONS OF GALAXY CLUSTERS

    Energy Technology Data Exchange (ETDEWEB)

    Serra, Ana Laura [Istituto Nazionale di Astrofisica (INAF), Osservatorio Astronomico di Torino, Strada Osservatorio 20, I-10025 Pino Torinese, Torino (Italy); Diaferio, Antonaldo, E-mail: serra@ph.unito.it [Dipartimento di Fisica, Universita di Torino, Via P. Giuria 1, I-10125 Torino (Italy)

    2013-05-10

    The caustic technique measures the mass of galaxy clusters in both their virial and infall regions and, as a byproduct, yields the list of cluster galaxy members. Here we use 100 galaxy clusters with mass M{sub 200} {>=} 10{sup 14} h {sup -1} M{sub Sun} extracted from a cosmological N-body simulation of a {Lambda}CDM universe to test the ability of the caustic technique to identify the cluster galaxy members. We identify the true three-dimensional members as the gravitationally bound galaxies. The caustic technique uses the caustic location in the redshift diagram to separate the cluster members from the interlopers. We apply the technique to mock catalogs containing 1000 galaxies in the field of view of 12 h {sup -1} Mpc on a side at the cluster location. On average, this sample size roughly corresponds to 180 real galaxy members within 3r{sub 200}, similar to recent redshift surveys of cluster regions. The caustic technique yields a completeness, the fraction of identified true members, f{sub c} = 0.95 {+-} 0.03, within 3r{sub 200}. The contamination, the fraction of interlopers in the observed catalog of members, increases from f{sub i}=0.020{sup +0.046}{sub -0.015} at r{sub 200} to f{sub i}=0.08{sup +0.11}{sub -0.05} at 3r{sub 200}. No other technique for the identification of the members of a galaxy cluster provides such large completeness and small contamination at these large radii. The caustic technique assumes spherical symmetry and the asphericity of the cluster is responsible for most of the spread of the completeness and the contamination. By applying the technique to an approximately spherical system obtained by stacking the individual clusters, the spreads decrease by at least a factor of two. We finally estimate the cluster mass within 3r{sub 200} after removing the interlopers: for individual clusters, the mass estimated with the virial theorem is unbiased and within 30% of the actual mass; this spread decreases to less than 10% for the spherically

  7. Potassium permanganate ingestion as a suicide attempt

    Directory of Open Access Journals (Sweden)

    Tuba Cimilli Ozturk

    2012-01-01

    Full Text Available Potassium permanganate is a highly corrosive, water-soluble oxidizing antiseptic. A 68- year-old female patient was admitted to our Emergency Department after ingestion of 3 tablets of 250 mg potassium permanganate as a suicide attempt. The physical exam revealed brown stained lesions in the oropharynx. Emergency endoscopy was performed by the gastroenterologist after the third hour of ingestion. Emergency endoscopy revealed multiple superficial (Grade I-II lesions on the esophagus and cardia, which were considered secondary to the caustic substance. The mainstay in the treatment of potassium permanganate is supportive and the immediate priority is to secure the airway. Emergency endoscopy is an important tool used to evaluate the location and severity of injury to the esophagus, stomach and duodenum after caustic ingestion. Patients with signs and symptoms of intentional ingestion should undergo endoscopy within 12 to 24 h to define the extent of the disease.

  8. A new type of Ambiguity in the Planet and Binary Interpretations of Central Perturbations of High-magnification Gravitational Microlensing Events

    DEFF Research Database (Denmark)

    Choi, J.-Y; Shin, I.-G; Han, C.;

    2012-01-01

    High-magnification microlensing events provide an important channel to detect planets. Perturbations near the peak of a high-magnification event can be produced either by a planet or a binary companion. It is known that central perturbations induced by both types of companions can be generally...... distinguished due to the essentially different magnification pattern around caustics. In this paper, we present a case of central perturbations for which it is difficult to distinguish the planetary and binary interpretations. The peak of a lensing light curve affected by this perturbation appears to be blunt...... and flat. For a planetary case, this perturbation occurs when the source trajectory passes the negative perturbation region behind the back end of an arrowhead-shaped central caustic. For a binary case, a similar perturbation occurs for a source trajectory passing through the negative perturbation region...

  9. INFLUENCE OF LOADING RATE ON DYNAMIC FRACTURE BEHAVIOR OF FIBER-REINFORCED COMPOSITES

    Institute of Scientific and Technical Information of China (English)

    Kezhuang Gong; Zheng Li; Weizhong Qin

    2008-01-01

    The effect of loading rate on the dynamic fracture properties and the failure mechanisms of glass fiber-reinforced composite materials under mode I fracture is studied.Dynamic reflective caustic experiments are carried out for two loading rates.By measuring the characteristic dimensions of the shadow spots during the caustic experiments,the dynamic SIFs are calculated for different loading rates.The experimental results indicate that the dynamic fracture toughness KId increases remarkably with increasing loading rate,and the crack grows faster under the high-velocity impact.Moreover,by examining the crack growth routes and the fracture surfaces,it is shown that the loading rate also greatly affects the failure mechanisms at micro-scale.

  10. Plutonium Speciation in Support of Oxidative-Leaching Demonstration Test

    Energy Technology Data Exchange (ETDEWEB)

    Sinkov, Sergey I.

    2007-10-31

    Bechtel National, Inc. (BNI) is evaluating the plutonium speciation in caustic solutions that reasonably represent the process streams from the oxidative-leaching demonstration test. Battelle—Pacific Northwest Division (PNWD) was contracted to develop a spectrophotometric method to measure plutonium speciation at submicromolar (< 10-6 M) concentrations in alkaline solutions in the presence of chromate and carbonate. Data obtained from the testing will be used to identify the oxidation state of Pu(IV), Pu(V), and Pu(VI) species, which potentially could exist in caustic leachates. Work was initially conducted under contract number 24590-101-TSA-W000-00004 satisfying the needs defined in Appendix C of the Research and Technology Plan TSS A-219 to evaluate the speciation of chromium, plutonium, and manganese before and after oxidative leaching. In February 2007, the contract mechanism was switched to Pacific Northwest National Laboratory (PNNL) Operating Contract MOA: 24590-QL-HC9-WA49-00001.

  11. Aluminum Target Dissolution in Support of the Pu-238 Program

    Energy Technology Data Exchange (ETDEWEB)

    McFarlane, Joanna [ORNL; Benker, Dennis [ORNL; DePaoli, David W [ORNL; Felker, Leslie Kevin [ORNL; Mattus, Catherine H [ORNL

    2014-09-01

    Selection of an aluminum alloy for target cladding affects post-irradiation target dissolution and separations. Recent tests with aluminum alloy 6061 yielded greater than expected precipitation in the caustic dissolution step, forming up to 10 wt.% solids of aluminum hydroxides and aluminosilicates. We present a study to maximize dissolution of aluminum metal alloy, along with silicon, magnesium, and copper impurities, through control of temperature, the rate of reagent addition, and incubation time. Aluminum phase transformations have been identified as a function of time and temperature, using X-ray diffraction. Solutions have been analyzed using wet chemical methods and X-ray fluorescence. These data have been compared with published calculations of aluminum phase diagrams. Temperature logging during the transients has been investigated as a means to generate kinetic and mass transport data on the dissolution process. Approaches are given to enhance the dissolution of aluminum and aluminosilicate phases in caustic solution.

  12. Three-dimensional collimated self-accelerating beam through acoustic metascreen

    Science.gov (United States)

    Li, Yong; Assouar, M. Badreddine

    2015-12-01

    We report the generation of three-dimensional acoustic collimated self-accelerating beam in non-paraxial region with sourceless metascreen. Acoustic metascreen with deep subwavelength spatial resolution, composed of hybrid structures combining four Helmholtz resonators and a straight pipe, transmitting sound efficiently and shifting fully the local phase is evidenced. With an extra phase profile provided by the metascreen, the transmitted sound can be tuned to propagate along arbitrary caustic curvatures to form a focused spot. Due to the caustic nature, the formed beam possesses the capacities of bypassing obstacles and holding the self-healing feature, paving then a new way for wave manipulations and indicating various potential applications, especially in the fields of ultrasonic imaging, diagnosis and treatment.

  13. Influence of viscosity on acoustic streaming in sessile droplets: an experimental and a numerical study with a Streaming Source Spatial Filtering (SSSF) method

    CERN Document Server

    Riaud, Antoine; Matar, Oliver Bou; Thomas, Jean-Louis; Brunet, Philippe

    2016-01-01

    When an acoustic wave travels in a lossy medium such as a liquid, it progressively transfers its pseudo-momentum to the fluid, which results in a steady acoustic streaming. Remarkably, the phenomenon involves a balance between sound attenuation and shear, such that viscosity vanishes in the final expression of the velocity field. For this reason, the effect of viscosity has long been ignored in acoustic streaming experiments. Here, we show experimentally that the viscosity plays a major role in cavities such as the streaming induced by surface acoustic waves in sessile droplets. We develop a numerical model based on the spatial filtering of the streaming source term to compute the induced flow motion with dramatically reduced computational requirements. We evidence that acoustic fields in droplets are a superposition of a chaotic field and a few powerful caustics. It appears that the caustics drive the flow, which allows a qualitative prediction of the flow structure. Finally, we reduce the problem to two dim...

  14. Measuring the growth of galaxy clusters

    CERN Document Server

    Diaferio, Antonaldo

    2015-01-01

    We suggest how we can use the mass profile of galaxy clusters beyond their virial radius to measure their mass accretion rate, a key prediction of structure formation models. The mass profile can be estimated by applying the caustic technique to dense redshift surveys of clusters and their outskirts, where dynamical equilibrium does not necessarily hold. An additional probe of the mass growth of clusters is their mass fraction in substructures. We show that the caustic technique, that identifies cluster substructures as a by-product, returns catalogs of substructures with mass larger than a few $10^{13}h^{-1}M_\\odot$ that are between 60% and 80% complete, depending on the density of the redshift survey.

  15. Winding light beams along elliptical helical trajectories

    CERN Document Server

    Wen, Yuanhui; Zhang, Yanfeng; Chen, Hui; Yu, Siyuan

    2016-01-01

    Conventional caustic methods in real or Fourier space produced accelerating optical beams only with convex trajectories. We develop a superposition caustic method capable of winding light beams along non-convex trajectories. We ascertain this method by constructing a one-dimensional (1D) accelerating beam moving along a sinusoidal trajectory, and subsequently extending to two-dimensional (2D) accelerating beams along arbitrarily elliptical helical trajectories. We experimentally implement the method with a compact and robust integrated optics approach by fabricating micro-optical structures on quartz glass plates to perform the spatial phase and amplitude modulation to the incident light, generating beam trajectories highly consistent with prediction. The theoretical and implementation methods can in principle be extended to the construction of accelerating beams with a wide variety of non-convex trajectories, thereby opening up a new route of manipulating light beams for fundamental research and practical ap...

  16. Environmental Cracking of Corrosion Resistant Alloys in the Chemical Process Industry - A Review

    Energy Technology Data Exchange (ETDEWEB)

    Rebak, R B

    2006-12-04

    A large variety of corrosion resistant alloys are used regularly in the chemical process industry (CPI). The most common family of alloys include the iron (Fe)-based stainless steels, nickel (Ni) alloys and titanium (Ti) alloys. There also other corrosion resistant alloys but their family of alloys is not as large as for the three groups mentioned above. All ranges of corrosive environments can be found in the CPI, from caustic solutions to hot acidic environments, from highly reducing to highly oxidizing. Stainless steels are ubiquitous since numerous types of stainless steels exist, each type tailored for specific applications. In general, stainless steels suffer stress corrosion cracking (SCC) in hot chloride environments while high Ni alloys are practically immune to this type of attack. High nickel alloys are also resistant to caustic cracking. Ti alloys find application in highly oxidizing solutions. Solutions containing fluoride ions, especially acid, seem to be aggressive to almost all corrosion resistant alloys.

  17. Axionic dark matter signatures in various halo models

    Science.gov (United States)

    Vergados, J. D.; Semertzidis, Y. K.

    2017-02-01

    In the present work we study possible signatures in the Axion Dark Matter searches. We focus on the dependence of the expected width in resonant cavities for various popular halo models, leading to standard velocity distributions, e.g. Maxwell-Boltzmann, as well as phase-mixed and non-virialized axionic dark matter (flows, caustic rings). We study, in particular, the time dependence of the resonance width (modulation) arising from such models. We find that the difference between the maximum (in June) and the minimum (in December) can vary by about 10% in the case of standard halos. In the case of mixed phase halos the variation is a bit bigger and for caustic rings the maximum is expected to occur a bit later. Experimentally such a modulation is observable with present technology.

  18. Tailoring Accelerating Beams in Phase Space

    CERN Document Server

    Wen, Yuanhui; Zhang, Yanfeng; Chen, Hui; Yu, Siyuan

    2016-01-01

    An appropriate design of wavefront will enable light fields propagating along arbitrary trajectories thus forming accelerating beams in free space. Previous ways of designing such accelerating beams mainly rely on caustic methods, which start from diffraction integrals and only deal with two-dimensional fields. Here we introduce a new perspective to construct accelerating beams in phase space by designing the corresponding Wigner distribution function (WDF). We find such a WDF-based method is capable of providing both the initial field distribution and the angular spectrum in need by projecting the WDF into the real space and the Fourier space respectively. Moreover, this approach applies to the construction of both two- and three-dimensional fields, greatly generalizing previous caustic methods. It may therefore open up a new route to construct highly-tailored accelerating beams and facilitate applications ranging from particle manipulation and trapping to optical routing as well as material processing.

  19. Study on melting available silicone from coal gangue

    Energy Technology Data Exchange (ETDEWEB)

    Chen-tao Hou; Sheng-quan Wang; Xiao-fei Xie [Xi' an University of Science and Technology, Xi' an (China). College of Geology and Environment

    2009-12-15

    Available silicone was melted from coal gangue samples from Hancheng diggings through calcination, digestion, and other means. The best calcination temperature was determined from a range of 550-1150{sup o}C; and the best time, from a range of 0.5-5 h by colorimetry method. The proper ratio of coal gangue, limestone, sodium carbonate, and caustic soda was then determined through orthogonal experiment. The results show that the proper extraction condition for available silicone is the ratio of coal gangue, limestone, sodium carbonate, and caustic soda at 1:0.5:0.1:0.05, calcination temperature at 700{sup o}C, and calcination time at 2 h. In this condition, the available silicone content can be more than 19.65%. 10 refs., 2 figs., 3 tabs.

  20. Study on melting available silicone from coal gangue

    Institute of Scientific and Technical Information of China (English)

    HOU Chen-tao; WANG Sheng-quan; XIE Xiao-fei

    2009-01-01

    Available silicone was melted from coal gangue samples from Hancheng diggings through calcination, digestion, and other means. The best calcination temperature was determined from a range of 550~1 150 ℃; and the best time, from a range of 0.5-5 h by colorimetry method. The proper ratio of coal gangue, limestone, sodium carbonate, and caustic soda was then determined through orthogonal experiment. The results show that the proper extraction condition for available silicone is the ratio of coal gangue, limestone, sodium carbonate, and caustic soda at 1:0.5:0.1:0.05, calcination temperature at 700℃,and calcination time at 2 h. In this condition, the available silicone content can be more than 19.65%.

  1. Axionic dark matter signatures in various halo models

    Directory of Open Access Journals (Sweden)

    J.D. Vergados

    2017-02-01

    Full Text Available In the present work we study possible signatures in the Axion Dark Matter searches. We focus on the dependence of the expected width in resonant cavities for various popular halo models, leading to standard velocity distributions, e.g. Maxwell–Boltzmann, as well as phase-mixed and non-virialized axionic dark matter (flows, caustic rings. We study, in particular, the time dependence of the resonance width (modulation arising from such models. We find that the difference between the maximum (in June and the minimum (in December can vary by about 10% in the case of standard halos. In the case of mixed phase halos the variation is a bit bigger and for caustic rings the maximum is expected to occur a bit later. Experimentally such a modulation is observable with present technology.

  2. Achieving hemostasis in dermatology-Part II: Topical hemostatic agents

    Directory of Open Access Journals (Sweden)

    Jaimie B Glick

    2013-01-01

    Full Text Available Bleeding is a common occurrence during any dermatologic surgery that disrupts blood vessels. The complications of excess bleeding can include delayed wound healing, hematoma formation, infection, dehiscence, and necrosis. In part one of this review, we discussed the pre-operative, intra-operative, and post-operative management of patients undergoing dermatologic surgery. In Part two, we discuss traditional and new topical hemostatic agents used to achieve hemostasis in dermatological procedures and surgery. We will evaluate the caustic and non-caustic hemostatic agents as well as hemostatic dressings. The mechanisms of action, side effect profile, and advantages and disadvantages of the topical hemostatic agents are provided. Sources for this article were found searching the English literature in PubMed for the time period 1940 to March 2012. A thorough bibliography search was also performed and key references examined.

  3. Effect of Solid Loading on Carbon Dioxide Absorptionin Bubble Column

    Directory of Open Access Journals (Sweden)

    Alyaa Khadhier Mageed

    2011-01-01

    Full Text Available In the present work experiments were conducted to study the effect of solid loading (1,5 and 9 vol.% on the enhancement of carbon dioxide absorption in bubble column at various volumetric gas flow rate (0.75, 1 and 1.5 m3/h and absorbent concentration (caustic soda( 0.1,0.5 and 1 M . Activated carbon and alumina oxide (Al2O3 are used as solid particles. The Danckwerts method was used to calculate interfacial area and individual mass transfer coefficients during absorption of carbon dioxide in a bubble column. The results show that the absorption rate was increased with increasing volumetric gas flow rate, caustic soda concentration and solid loading. Mass transfer coefficient and interfacial area were increased with increasing volumetric gas flow rate, and solid loading.

  4. Bench-Scale Filtration Testing in Support of the Pretreatment Engineering Platform (PEP)

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.; Daniel, Richard C.; Kurath, Dean E.; Peterson, Reid A.

    2009-09-28

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP testing program specifies that bench-scale testing is to be performed in support of specific operations, including filtration, caustic leaching, and oxidative leaching.

  5. Aluminate solution decomposition new technology development

    Energy Technology Data Exchange (ETDEWEB)

    Abramov, V.Ya.; Stelmakova, G.D. [Scientific Technical Centre Reactor, Moscow (Russian Federation)

    1996-10-01

    Scientific Technical Centre Reactor together with SC Aluminy carried out the number of investigations in the field of aluminum solution decomposition new technology development. It was based on large prime ratio on one hand, and liquid-solid countercurrent flow movement on the other hand. Practically the suggested technology was considered to be the result of unstationary, mass-transfer theory, which had been checked up at 100 m3 plot scale plant. Hydrate washing was accomplished at the first stage under the condition of countercurrent flow and less than 1 m3 water discharge. The experiments of 3.2--3.3 caustic module aluminate solution decomposition were carried out at the second stage. While full reactor 20 hour regime operation the caustic module increased till 4.1. Usually it accounts 3.7 under the analogous conditions and time.

  6. Recovery of volatile fatty acids from fermentation of sewage sludge in municipal wastewater treatment plants.

    Science.gov (United States)

    Longo, S; Katsou, E; Malamis, S; Frison, N; Renzi, D; Fatone, F

    2015-01-01

    This work investigated the pilot scale production of short chain fatty acids (SCFAs) from sewage sludge through alkaline fermentation and the subsequent membrane filtration. Furthermore, the impact of the fermentation liquid on nutrient bioremoval was examined. The addition of wollastonite in the fermenter to buffer the pH affected the composition of the carbon source produced during fermentation, resulting in higher COD/NH4-N and COD/PO4-P ratios in the liquid phase and higher content of propionic acid. The addition of wollastonite decreased the capillary suction time (CST) and the time to filter (TTF), resulting in favorable dewatering characteristics. The sludge dewatering characteristics and the separation process were adversely affected from the use of caustic soda. When wollastonite was added, the permeate flux increased by 32%, compared to the use of caustic soda. When fermentation liquid was added as carbon source for nutrient removal, higher removal rates were obtained compared to the use of acetic acid.

  7. Suicide case due to phosphoric acid ingestion: case report and review of literature.

    Science.gov (United States)

    Aquila, Isabella; Pepe, Francesca; Di Nunzio, Ciro; Ausania, Francesco; Serra, Arianna; Ricci, Pietrantonio

    2014-11-01

    Ingesting caustic substances represents a common event which may result in serious injuries of the gastrointestinal system. Severity of injury depends on the type of ingested substance: Caustic burns are more frequently associated with acid ingestion and their severity depends on type, concentration, time of exposure, and amount of the ingested substance. We report a case of phosphoric acid ingestion leading to death in a patient with depressive disorder. While reports ingestion of other acids and organophosphates can be found in the literature, there are no reports detailing a death due to phosphoric acid ingestion. We hope that presenting the findings in this case can aid death investigators in future cases that may involve ingestion of such a substance. After autopsy pH, phosphate and calcium ions concentration in the blood were analyzed. The cause of death was due to systemic effects: metabolic acidosis, hypophosphatemia, hypocalcemia, and hyperkalemia.

  8. An analysis of corrosive substance ingestion of children in eastern Turkey

    OpenAIRE

    Melek, Mehmet; Edirne, Yeşim; Çobanoğlu, Ufuk; CEYLAN, Abdullah; Can, Muhammet

    2013-01-01

    Abstract. In this study, we aimed at describing corrosive substance  ingestion and related problems in Eastern Turkey. This type of injury is still a serious problem to be given a careful attention in our country like the other developing countries. The charts of children managed in our hospital with corrosive substance ingestion in the period of 1996- 2008 were evaluated retrospectively. Gender, age, ingested substance and the volume, symptoms, morbidity of caustic injury were considered in ...

  9. A model for the ultrasonic field radiated by an immersed transducer into an anisotropic and heterogeneous medium; Modelisation du champ ultrasonore rayonne dans un solide anisotrope et heterogene par un traducteur immerge

    Energy Technology Data Exchange (ETDEWEB)

    Gengembre, N

    2000-07-01

    A model for the field radiated by an ultrasonic transducer into anisotropic and heterogeneous media is developed in this thesis. This work aims at improving the settings and interpretations of non destructive tests in welded structures. Since the shape of the transducer is assumed arbitrary, its emitting surface is divided into small elementary sources. The overall field at an observation point in the medium is derived by a summation of the elementary contributions of these point sources. An accurate and numerically efficient model is developed using the Geometrical Optics approximation to evaluate these elementary contributions. Two different forms of this approximation are used: The stationary phase method and the pencil method. The first one is based on an exact formulation of the field and is used for fields into anisotropic and homogeneous media. It allows to emphasize specific configurations for which additional developments are required; this need arises for calculation points in the vicinity of caustics (zones of high intensity). This problem is solved for both harmonic and transient fields, for points laying on caustics or in their neighborhood. The pencil method is used for the calculation of fields in heterogeneous media, although it does not permit to overcome the problem of caustics. It is also advantageous for the implementation of the model. A comparison of both above-mentioned methods is drawn, and their equivalence is proved for some cases. The calculation of fields in anisotropic and heterogeneous media is performed using both methods together, and then the problem of caustics is also treated. Calculated fields into welded components are shown and compared with experiments or with a numerical model, in order to validate the developments. (author)

  10. Hot iron branding--not a reasonable requirement for international trade in live ruminants.

    Science.gov (United States)

    Whiting, Terry L.

    2005-01-01

    "Brand" means a permanent identification mark of which the letters, numbers and figures used are each three (3) inches or more in length or diameter and are humanely burned into the hide of a live animal with a hot iron or tattoo or caustic chemical substance and is to be considered in relation to its location on the animal and the term relates to both the mark and location. PMID:16363334

  11. Chaotic ray propagation in corrugated layers

    Directory of Open Access Journals (Sweden)

    M. Bottiglieri

    2005-01-01

    Full Text Available The aim of this paper is to study the effects of a corrugated wall on the behaviour of propagating rays. Different types of corrugation are considered, using different distributions of the corrugation heights: white Gaussian, power law, self-affine perturbation. In phase space, a prevalent chaotic behaviour of rays, and the presence of a lot of caustics, are observed. These results entail that the KAM theorem is not fulfilled.

  12. Installation Restoration Program Phase 1: Records Search of Hanscom Air Force Base, Massachusetts

    Science.gov (United States)

    1984-08-01

    Parachute, Leather , Solvents, caustic cleaners, naptha, methyl ethyl - Rubber and Textile ketone, toluene, ethylene dichloride 8. Sheet Metal 9...sediments that fill a large-scale depression in crystalline bedrock (Delaney and Cotton , 1972.) In addition to the glacial sand deposits, there are...the parameters included in List B of Table 6-2. If contaminants are detected, GC /MS scans should be conducted on the suspect samples to identify

  13. Rapid synthesis of beta zeolites

    Science.gov (United States)

    Fan, Wei; Chang, Chun -Chih; Dornath, Paul; Wang, Zhuopeng

    2015-08-18

    The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.

  14. Washing of the AN-107 entrained solids

    Energy Technology Data Exchange (ETDEWEB)

    GJ Lumetta; FV Hoopes

    2000-03-31

    This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing on the composition of the entrained solids in the diluted AN-107 low-activity waste (LAW) sample. The objective of this work was to gather data on the solubility of the AN-107 entrained solids in 0.01 M NaOH, so that BNFL can evaluate whether these solids require caustic leaching.

  15. Stainless steel anodes for alkaline water electrolysis and methods of making

    Science.gov (United States)

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  16. Non-Thermal, On-Site Decontamination and Destruction of Practice Bombs

    Science.gov (United States)

    2006-06-12

    propellants in BDU’s that had mud, dirt or rocks blocking the path for caustic to enter the unit, and the number of BDU’s that could be processed per load...Materiel HBV Hepatitis B Virus HCV Hepatitis C Virus HIV Human Immunodeficiency Virus HTRW Hazardous, Toxic, and Radiological Waste IDHL...Watch where you sit, and where you put your hands and feet. • Avoid rock piles, stacks of old boards, and brush in wooded areas. If movement is

  17. Management of Munitions Constituents in Soil Using Alkaline Hydrolysis: A Guide for Practitioners

    Science.gov (United States)

    2011-10-01

    Santiago et al. 2007 12.00 25 858 0.8 Santiago et al. 2007 ERDC/EL TR-11-16 5 Propellant residues have to date been studied less than secondary...explosives. Studies have shown the susceptibility of nitrocellulose to alkaline degradation (Kenyon and Gray 1936). Kim et al. (1998) have demonstrated...the ability of high strength caustic solutions to render nitrocellulose biodegradable. In summary, alkaline conditions are sufficient to degrade a

  18. Integrated development and industrial application of high sour natural gas purification technology

    Institute of Scientific and Technical Information of China (English)

    Sun Lili

    2013-01-01

    Aiming at acute characteristics of flammability,explosibility,causticity and leakiness of high sour nat-ural gas,giving full consideration to local natural conditions in Sichuan Province and starting with purification pro-cess,the paper analyzed process configurations,energy utilization and conservation,safety and environment pro-tection measures. The integrated technology and engineering scheme for high sour natural gas purification was es-tablished and successfully used in industrial application.

  19. Endoscopic pyloroplasty for severe gastric outlet obstruction due to alkali ingestion in a child

    OpenAIRE

    Dehghani, Seyed Mohsen; Aldaghi, Mitra; Javaherizadeh, Hazhir

    2016-01-01

    A common belief is that alkali ingestion causes severe esophageal damage and limited gastric injury due to the buffering action of acid. Gastric injury has been observed in patients who ingested alkali. Gastric outlet obstruction (GOO) secondary to caustic ingestion occurs due to fibrosis after resolution of the acute injury and inflammation, most commonly 6 to 12 weeks after initial ingestion. The traditional treatment for GOO related to ingestion of corrosive agents is surgery. Experience w...

  20. Industrial Water Treatment Primer

    Science.gov (United States)

    1992-03-01

    2040) Gallic Acid Powder (item 2063) METHOD: It is necessary to follow the instructions furnished with the conductivity meter that is being used . The...reduces CO. Caustic soda raises pH to desired level. (Courtesy of Power: McGraw-Hill Publications) (2) A hydrogen zeolite softener (Figure 9) uses acid ...a) The acid used in the regeneration process makes the effluent water more corrosive (lower pH on effluent). (b) The hazards that exist in handling

  1. China Report, Economic Affairs

    Science.gov (United States)

    2007-11-02

    order to "collect all the cream of the world to foster our domestic strong point." As for the plan for conducting digestion and assimilation of the...of coal, crude °il» Pig iron, power generation, cement, plate glass, soda ash, machine tools, trucks, locomotives, boilers, and other major heavy...1,060,000 9.9 Coal Crude oil Electricity Pig Iron Steel Rolled steel Coke Timber Cement Plate glass Sulphuric acid Caustic soda Soda ash

  2. Examination of Treatment Methods for Cyanide Wastes.

    Science.gov (United States)

    1979-05-15

    Treatment Ozonation and Electrolysis ", Metal Finishing, Metals and Plastics Publications, Inc., Hackensack, N.J., February 1958, pp. 71 - 74. 80. Serota, L...and Caldwell, M.R., "Destruction of Cyanide Copper Solutions by Hot Electrolysis ", Plating, American Electroplaters Society, Inc., East Orange, N.J...volume of 2,200 gallons. Salt was stored in a brine tank in liquid form and injected into the system. No caustic was necessary since the system is

  3. The American economist Martin Bronfenbrenner (1914-1997) and the reconstruction of the Japanese economy (1947-1952): (a version for presentation in East Asia)

    OpenAIRE

    Ikeo, Aiko

    2011-01-01

    Martin Bronfenbrenner (1914-1997) was an American economist who was conversant with Japanese counterparts and well informed in Japan's economics and economy. This paper aims to examine how he managed to communicate with Japanese economists when he visited Japan (three times) during the period immediately after the conclusion of the Pacific War (1941-1945). It also discusses his caustic criticism of the monetary expansion policy started by Japanese Finance Minister Tanzan Ishibashi to bolster ...

  4. Polymer Claw: Instant Underwater Adhesive

    Science.gov (United States)

    2012-04-24

    tubes filled with a moisture-cured polyurethane -urea (MCPU). When scratched, the foaming action of a propellant ejects the resin from the broken tubes...and completely fills the crack. No catalysts or curing agents are needed since the polymerization is driven by ambient humidity. 15. SUBJECT TERMS...OBIECTIVES 2 KEY ACCOMPLISHMENTS 3.1 AMINE MICROENCAPSULATION 3 3.2 ALTERNATIVE CAUSTIC INGREDIENTS 4 3.3 LOAD-DISPLACEMENT TESTING OF METAL BRUSH 5 4

  5. Capillary floating and the billiard ball problem

    OpenAIRE

    Gutkin, Eugene

    2010-01-01

    We establish a connection between capillary floating in neutral equilibrium and the billiard ball problem. This allows us to reduce the question of floating in neutral equilibrium at any orientation with a prescribed contact angle for infinite homogeneous cylinders to a question about billiard caustics for their orthogonal cross-sections. We solve the billiard problem. As an application, we characterize the possible contact angles and exhibit an infinite family of real analytic non-round cyli...

  6. JPRS Report Near East & South Asia

    Science.gov (United States)

    2007-11-02

    the production of many dairy products, especially fresh lightly salted creamy white cheese, ice cream , yoghurt, and confec- tions, which has...land use designation of a mountain of ice , so that it then becomes possible to build on it ten houses for a small Jewish outlook that receives water...willingness to offer its expertise for the manufacture of items like window glasses, caustic soda , cement and HDP [expansion unknown] bags. In a brief

  7. How I treat. . . evanescent youth. Dating back using chemical peels.

    OpenAIRE

    Xhauflaire, Emmanuelle; Marcq, V.; Pierard, Claudine; Pierard, Gérald

    2005-01-01

    Chemical peels induce the destruction and exfoliation of the epidermis using selected caustic substances. The specific properties of these agents result in a limited and controlled destruction of epidermal layers and of the superficial dermis. The choice of the appropriate method, the preparatory phase and the post-peeling care are very important to reach optimal results. Some types of peeling are routinely used. We briefly report those designed for the superficial and medium depth peelings. ...

  8. St. Juliens Creek Ocean Construction Equipment Inventory Support Facility Five Year Plan. Volume 1. Results and Discussion.

    Science.gov (United States)

    1983-08-01

    present use has been as a paint locker The nearest fire hydrant is 30 feet to the south and the for storage of paint and caustic materials. The 81...to these repairs, the entire interior No vertical storage, of the building requires repainting, as it is peeling badly over 75% of the wall and...1,955 power deteriorated windows 86/OMN Interior paint Scrape & paint 10,260 peeling 86/OMN Floor planks Replace 3,260 broken 86/OMN Heat exchanger

  9. Evaluation of the Wedge Cleavage Test for Assessment of Durability of Adhesive Bonded Joints.

    Science.gov (United States)

    1980-07-01

    applied to the adherends. Exposures of hundreds or thousands of hours are necessary to discriminate between pretreatments if conventional lap shear or peel ...was preceded by additional degreasing in a conventional non- caustic proprietary alkaline cleaning solution. Pickling was for 30 minutes at 62-65°C in...consistent with the lower peel strength given by anodised surfaces5 (c) Adhesive FMIOOO Crack lengths are shown in Table 3 and Fig 5. Fracture energies were

  10. Method of Matched Expansions & the Singularity Structure of the Green Function

    CERN Document Server

    Casals, Marc; Ottewill, Adrian C; Wardell, Barry

    2010-01-01

    We present the first successful application of the method of Matched Expansions for the calculation of the self-force on a point particle in a curved spacetime. We investigate the case of a scalar charge in the Nariai spacetime, which serves as a toy model for a point mass moving in the Schwarzschild black hole background. We discuss the singularity structure of the Green function beyond the normal neighbourhood and the interesting effect of caustics on null wave propagation.

  11. Equilibrium studies of oxalate and aluminum containing solutions

    Energy Technology Data Exchange (ETDEWEB)

    Hay, M. S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); King, W. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Peters, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Jones, D. H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-11-01

    The Savannah River National Laboratory (SRNL) was tasked to develop data on the solubility and conditions leading to precipitation of sodium oxalate, sodium nitrate, Bayerite (a polymorph of gibbsite, Al(OH)3), and sodium aluminosilicate solids recently found in the Modular Caustic Side Solvent Extraction Unit (MCU). The data generated will be used to improve the OLI Systems thermodynamic database for these compounds allowing better prediction of solids formation by the modeling software in the future.

  12. Water Quality Conditions at Tributary Projects in the Omaha District

    Science.gov (United States)

    2012-02-01

    e.g., hydrogen sulfide , methane, etc.). Most fish and other intolerant aquatic life cannot inhabit water with less than 4 to 5 mg/l dissolved...substances (e.g., phosphorus, metals, sulfides , etc.) as the reduced conditions intensify and result in the production of toxic and caustic substances...Chlorophyll-a, Total Phosphorus, Total Nitrogen) No No TMDL to be developed Conestoga Reservoir Yes Aquatic Life, Aesthetics, Recreation Algae Toxins

  13. China and Proliferation of Weapons of Mass Destruction and Missiles: Policy Issues

    Science.gov (United States)

    2012-11-07

    hundreds of tons of anhydrous hydrogen fluoride (AHF), or hydrofluoric acid, under falsified documents about end-users. (The AHF chemical could be used to...glass-lined vessels for mixing the caustic precursors and special air filtration equipment to prevent poison gas leaks. Iran was also reportedly...China Northern Chemical and Minerals Company shipped a chemical, sodium sulfide , to Iran, but the PRC claimed that the shipment went to Armenia

  14. Covariant constraints for generic massive gravity and analysis of its characteristics

    CERN Document Server

    Deser, S; Waldron, A; Zahariade, G

    2014-01-01

    We perform a covariant constraint analysis of massive gravity valid for its entire parameter space, demonstrating that the model generically propagates five degrees of freedom; this is also verified by a new and streamlined Hamiltonian description. The constraint's covariant expression permits computation of the model's caustics. Although new features such as the dynamical Riemann tensor appear in the characteristic matrix, the model still exhibits the pathologies uncovered in earlier work: superluminality and likely acausalities.

  15. Effects of Interfacial Reaction on the Radial Displacement of Oil by Alkaline Solutions Effets des réactions interfaciales sur le déplacement radial de l'huile par les solutions alcalines

    OpenAIRE

    2006-01-01

    Caustic flooding is frequently used to recover acidic oils in secondary and tertiary recovery modes. This study examines the secondary recovery of an acidic oil by alkaline solutions in a water-wet porous medium using a radial geometry. A model porous medium consisting of sintered glass beads sandwiched between two glass plates was employed to visualize the displacement process. The medium was originally saturated with the oil phase, namely paraffin oil (non-reacting system) or paraffin oil d...

  16. HVEPS Scramjet-Driven MHD Power Demonstration Test Results (Preprint)

    Science.gov (United States)

    2007-06-01

    seeding for the scramjet- driven MHD demonstration test was accomplished by the injection of liquid NaK into the backplate of the UTRC pre-heater... NaK is a eutectic consisting of approximately 80% potassium and 20% sodium. It exists in liquid form at room temperature and has flow properties...quite similar to water. However, there are materials handling safety issues with use of NaK since it is highly caustic alkali metal and burns on

  17. Pulping and paper properties of Palmyra palm fruit fibers

    OpenAIRE

    Waranyou Sridach

    2010-01-01

    Palmyra palm fruit fibers have the properties to be used as an alternative raw material of cellulosic pulps for papermaking.Acid and alkali pulping were investigated by using nitric acid and caustic soda on a laboratory scale, with the purpose of producing printing or writing grade pulp. The chemical composition of fiber strands from palmyra palm fruits were examined, such as holocellulose, cellulose, pentosan, lignin and extractives. The yields of acid and soda pulps were below 40%. The main...

  18. Mineral resource of the month: lime

    Science.gov (United States)

    ,

    2009-01-01

    The article presents facts about lime, which is said to be a caustic chemical manufactured from limestone or other calcium carbonates in a kiln at temperatures ranging from 935 to 1,350 degrees Celsius. It states that lime is widely used in industries such as steelmaking, paper production and chemical manufacturing. It also mentions that global lime production amounts up to 280 million metric tons annually. However, it notes that international trade in lime is limited.

  19. Uncovering stellar atmospheres with gravitational microlensing telescopes

    CERN Document Server

    Dominik, M

    2003-01-01

    A strong differential magnification over the face of the source star passing the caustic created by a binary lens star allows to measure its radial intensity profile with an angular resolution of 20-60 nas from broad-band photometric observations for ~15 stars per year and to study its chemical composition from time-resolved high-resolution spectroscopy for ~2 stars per year.

  20. Mercury Phase II Study - Mercury Behavior across the High-Level Waste Evaporator System

    Energy Technology Data Exchange (ETDEWEB)

    Bannochie, C. J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Crawford, C. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Jackson, D. G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Shah, H. B. [Savannah River Remediation, LLC., Aiken, SC (United States); Jain, V. [Savannah River Remediation, LLC., Aiken, SC (United States); Occhipinti, J. E. [Savannah River Remediation, LLC., Aiken, SC (United States); Wilmarth, W. R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-06-17

    The Mercury Program team’s effort continues to develop more fundamental information concerning mercury behavior across the liquid waste facilities and unit operations. Previously, the team examined the mercury chemistry across salt processing, including the Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU), and the Defense Waste Processing Facility (DWPF) flowsheets. This report documents the data and understanding of mercury across the high level waste 2H and 3H evaporator systems.

  1. Process Development for Permanganate Addition During Oxidative Leaching of Hanford Tanks Sludges

    Energy Technology Data Exchange (ETDEWEB)

    Rapko, Brian M.; Lumetta, Gregg J.; Deschane, Jaquetta R.; Peterson, Reid A.; Blanchard, David L.

    2007-10-30

    Previous Bechtel National, Incorporated (BNI)-sponsored studies have targeted optimizing sodium permanganate for the selective oxidation of chromium from washed Hanford tank sludges (Rapko et al. 2004; Rapko et al. 2005). The recommendation from previous work was that contact with sodium permanganate in a minimally caustic solution, i.e., 0.1 to 0.25 M [OH-] initially, provided maximum Cr dissolution while minimizing concomitant Pu dissolution. At the request of BNI, further work on oxidative alkaline leaching was performed.

  2. Development of Ray Tracing Algorithms for Scanning Plane and Transverse Plane Analysis for Satellite Multibeam Application

    Directory of Open Access Journals (Sweden)

    N. H. Abd Rahman

    2014-01-01

    Full Text Available Reflector antennas have been widely used in many areas. In the implementation of parabolic reflector antenna for broadcasting satellite applications, it is essential for the spacecraft antenna to provide precise contoured beam to effectively serve the required region. For this purpose, combinations of more than one beam are required. Therefore, a tool utilizing ray tracing method is developed to calculate precise off-axis beams for multibeam antenna system. In the multibeam system, each beam will be fed from different feed positions to allow the main beam to be radiated at the exact direction on the coverage area. Thus, detailed study on caustics of a parabolic reflector antenna is performed and presented in this paper, which is to investigate the behaviour of the rays and its relation to various antenna parameters. In order to produce accurate data for the analysis, the caustic behaviours are investigated in two distinctive modes: scanning plane and transverse plane. This paper presents the detailed discussions on the derivation of the ray tracing algorithms, the establishment of the equations of caustic loci, and the verification of the method through calculation of radiation pattern.

  3. Characterization and Leach Testing for PUREX Cladding Waste Sludge (Group 3) and REDOX Cladding Waste Sludge (Group 4) Actual Waste Sample Composites

    Energy Technology Data Exchange (ETDEWEB)

    Snow, Lanee A.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Fiskum, Sandra K.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

    2009-02-13

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.(a) The testing program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual wastetesting program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR)—are the subjects of this report. Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, requiring caustic leaching. Characterization of the composite Group 3 and Group 4 waste samples confirmed them to be high in gibbsite. The focus of the Group 3 and 4 testing was on determining the behavior of gibbsite during caustic leaching. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

  4. Is DBI as fragile as other $k$-essence fields?

    CERN Document Server

    Mukohyama, Shinji; Watanabe, Yota

    2016-01-01

    Caustic singularity formations in shift-symmetric $k$-essence and Horndeski theories on a fixed Minkowski spacetime were recently argued. In $n$ dimensions this singularity is the $(n-2)$-dimensional plane in spacetime at which second derivatives of a field diverge and the field loses single-valued description for its evolution. This does not necessarily imply a pathological behavior of the system but rather invalidates the effective description. The effective theory would thus have to be replaced by another to describe the evolution thereafter. In this paper, adopting the planar-symmetric $1$+$1$-dimensional approach employed in the original analysis, we seek all $k$-essence theories in which generic simple wave solutions are free from such caustic singularities. Contrary to the previous claim, we find that not only the standard canonical scalar but also the DBI scalar are free from caustics, as far as planar-symmetric simple wave solutions are concerned. Addition of shift-symmetric Horndeski terms does not ...

  5. Corrosion of two kinds of cast steels containing chromium in hot concentrated alkaline

    Directory of Open Access Journals (Sweden)

    LI Wei

    2007-02-01

    Full Text Available A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.

  6. Corrosion of two kinds of cast steels containing chromium in hot concentrated alkaline

    Institute of Scientific and Technical Information of China (English)

    LI Wei; LIU Jun-quan; TU Xiao-hui

    2007-01-01

    A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303 g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.

  7. Spectra of sodium aluminate solutions

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The UV spectra of sodium aluminate solutions were obtained in the sodium oxide concentration range from 59 to 409 g/L and the caustic ratio range from 1.5 to 4.0 to reveal the structure characteristics of them. It is found that a new peak appears at about 370 nm besides peaks at about 220 and 266 nm in all solutions. The new peak is strongly favored by high hydroxide concentration and high caustic ratio. And it only appears when the solutions are prepared by dissolving sodium hydroxide and aluminum hydroxide.In addition, the IR and Raman spectra of sodium aluminate solutions with high alkali concentration and high caustic ratio were measured, and the UV spectra of aqueous solutions of Al(H2O)63+ and AlF63- were measured as well. According to the crystal field theory in coordination chemistry as well as the above spectra characteristics, this new peak at about 370 nm is determined as the evidence of a new species of aluminate ion with a coordination number of 6.

  8. Axions and the Galactic Angular Momentum Distribution

    CERN Document Server

    Banik, N

    2013-01-01

    We analyze the behavior of axion dark matter before it falls into a galactic gravitational potential well. The axions thermalize sufficiently fast by gravitational self-interactions that almost all go to their lowest energy state consistent with the total angular momentum acquired from tidal torquing. That state is a state of rigid rotation on the turnaround sphere. It predicts the occurrence and detailed properties of the caustic rings of dark matter for which observational evidence had been found earlier. We show that the vortices in the axion Bose-Einstein condensate (BEC) are attractive, unlike those in superfluid $^4$He and dilute gases. We expect that a large fraction of the vortices in the axion BEC join into a single big vortex along the rotation axis of the galaxy. The resulting enhancement of caustic rings explains the typical size of the rises in the Milky Way rotation curve attributed to caustic rings. We show that baryons and ordinary cold dark matter particles are entrained by the axion BEC and ...

  9. Laboratory Tests on Post-Filtration Precipitation in the WTP Pretreatment Process

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.; Crum, Jarrod V.

    2009-11-20

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan (Barnes et al. 2006). The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF).

  10. Integrated hydrometallurgical process for production of zinc from electric arc furnace dust in alkaline medium.

    Science.gov (United States)

    Youcai, Z; Stanforth, R

    2000-12-30

    In this study, a novel and integrated hydrometallurgical process for the production of zinc powder from electric arc furnace (EAF) dust in alkaline medium is reported. The dust is firstly hydrolysed in water, and then fused in caustic soda at 350 degrees C for 1h, followed by leaching in alkaline solution in which both zinc and lead are effectively extracted. Zinc powder is then produced by electrowinning from the leach solution after the lead is selectively removed by precipitation using sodium sulphide as precipitant. The EAF dust tested contained 25% Zn, 1.8% Pb and 33% Fe. It was found that 38% of zinc and 68% of lead could be extracted from the dust when leached directly in caustic soda solution. Leaching of zinc increased to 80% when dust was directly fused with caustic soda followed by alkaline leaching. However, the leaching further increased to 95% when the dust was hydrolysed first with water before fusion. Zinc powder with a purity of 99.95% was then produced by electrowinning from the lead depleted solution. Stainless electrodes were used as both anode and cathode.

  11. Hard X-ray view of microlensing events in RX J1131-1231

    CERN Document Server

    Neronov, A; Walter, R

    2016-01-01

    RX J1131-1231 is a gravitationally lensed system which includes four images of a quasar lensed by an elliptical galaxy. The flux in the individual images is known to be affected by microlensing effect in the visible and X-ray bands. We study the multi-wavelength properties of RX J1131-1231 over a broad energy range, from optical to hard X-ray, during the periods of the microlensing caustic crossings. We aim to constrain the spatial extent of the X-ray emission region at different energies. We combine the data of the source monitoring in the visible band with the X-ray data of the Burst Alert Telescope (BAT) on board of SWIFT satellite and Chandra X-ray observatory. Inspecting the broad band spectrum and lightcurves of the source we identify several microlensing caustic crossing events, and study the details of variability of the source during these events. The caustic crossings of image A on MJD 55150 and 55500 produce strong variations of the overall X-ray flux from the source. In the soft X-ray band, the ca...

  12. Process modification of centrifuge system in evaporation procedure%蒸发离心机系统的工艺改造

    Institute of Scientific and Technical Information of China (English)

    吴素芳

    2001-01-01

    福建东南电化股份有限公司原烧碱蒸发装置因存在碱泥高位槽经常处于满料溢流状态,使盐在蒸发系统中恶性循环,进而造成物料损失,降低了生产能力,增加了蒸汽消耗。改进工艺后,解决了上述问题,使烧碱产量得到提高,蒸汽消耗得到降低。%In the old caustic soda evaporation equiptment in Dongnan Electrochemical Inc. of Fujian Province, the high- level tank of caustic slurry was always in the status of overflow, which caused thevicious circulation of salt in the system, resulting in loss of materials, reduction of production capacity,and increase of steam consumption. After rnodifying process, the above problems were solved,and thusoutputs of caustic soda were increased and steam consumption was decreased.

  13. MULTIPOLE GRAVITATIONAL LENSING AND HIGH-ORDER PERTURBATIONS ON THE QUADRUPOLE LENS

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Z.; Lin, W. P. [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, 80 Nandan Road, Shanghai 200030 (China); Li, G. L. [Purple Mountain Observatory, 2 West Beijing Road, Nanjing 210008 (China); Kang, X., E-mail: chuzhe@shao.ac.cn, E-mail: linwp@shao.ac.cn [Partner Group of MPI for Astronomy, Purple Mountain Observatory, 2 West Beijing Road, Nanjing 210008 (China)

    2013-03-10

    An arbitrary surface mass density of the gravitational lens can be decomposed into multipole components. We simulate the ray tracing for the multipolar mass distribution of the generalized Singular Isothermal Sphere model based on deflection angles, which are analytically calculated. The magnification patterns in the source plane are then derived from an inverse shooting technique. As has been found, the caustics of odd mode lenses are composed of two overlapping layers for some lens models. When a point source traverses this kind of overlapping caustics, the image numbers change by {+-}4, rather than {+-}2. There are two kinds of caustic images. One is the critical curve and the other is the transition locus. It is found that the image number of the fold is exactly the average value of image numbers on two sides of the fold, while the image number of the cusp is equal to the smaller one. We also focus on the magnification patterns of the quadrupole (m = 2) lenses under the perturbations of m = 3, 4, and 5 mode components and found that one, two, and three butterfly or swallowtail singularities can be produced, respectively. With the increasing intensity of the high-order perturbations, the singularities grow up to bring sixfold image regions. If these perturbations are large enough to let two or three of the butterflies or swallowtails make contact, then eightfold or tenfold image regions can be produced as well. The possible astronomical applications are discussed.

  14. Synergistic evaluation of a complex conglomerate reservoir for enhanced oil recovery, Barrancas Formation, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Simlote, V.N.; Ebanks, W.J.; Eslinger, E.V.

    1982-09-01

    An Engineering-geological study of the Top Red Conglomerate (TRC) portions of the Barrancas formation, Mendoza area, Argentina, was conducted to evaluate waterflood performance and develop a predictive model for use in evaluating reservoir response to caustic flooding. Initial oil in place of the TRC reservoir was approximately 400 million STB. The field has produced 154 million STB through 1980, and it is being considered for enhanced recovery processes. The TRC has large variations in permeability, owing to its origin as the uppermost part of a thick alluvial fan-braided channel sequence of sediments. Porosity and permeability development in these rocks are governed mainly by the abundance of detrital clay, and are reduced somewhat by calcite and zeolite cements and authigenic clays. Chemically reactive components are potential causes of formation damage by reactions with injected chemicals. A geological model of layering and areal variability in the reservoir was used to guide the application of a black oil simulator to two cross-sections. This simulation of waterflooded performance indicated good vertical sweep efficiency near injection wells but less efficient sweep farther away because of gravity segregation. The relative merits of several enhanced recovery processes were evaluated for recovering the oil left after waterflooding. Caustic flooding appears to be the most feasible; therefore, the chemical reactivity of representative core samples were evaluated. The mineralogy and cation exchange capacity (CEC) results are presented. CEC values were compared with short term caustic consumption measurements.

  15. DEVELOPMENT OF PROTOTYPE TITANATE ION EXCHANGE LOADED MEMBRANES FOR STRONTIUM, CESIUM AND ACTINIDE DECONTAMINATION FROM AQUEOUS MEDIA

    Energy Technology Data Exchange (ETDEWEB)

    Oji, L; Keisha Martin, K; David Hobbs, D

    2008-05-30

    We have successfully incorporated high surface area particles of titanate ion exchange materials (monosodium titanate and crystalline silicotitanate) with acceptable particle size distribution into porous and inert support membrane fibrils consisting of polytetrafluoroethylene (Teflon{reg_sign}), polyethylene and cellulose materials. The resulting membrane sheets, under laboratory conditions, were used to evaluate the removal of surrogate radioactive materials for cesium-137 and strontium-90 from high caustic nuclear waste simulants. These membrane supports met the nominal requirement for nonchemical interaction with the embedded ion exchange materials and were porous enough to allow sufficient liquid flow. Some of this 47-mm size stamped out prototype titanium impregnated ion exchange membrane discs was found to remove more than 96% of dissolved cesium-133 and strontium-88 from a caustic nuclear waste salt simulants. Since in traditional ion exchange based column technology monosodium titanate (MST) is known to have great affinity for the sorbing of other actinides like plutonium, neptunium and even uranium, we expect that the MST-based membranes developed here, although not directly evaluated for uptake of these three actinides because of costs associated with working with actinides which do not have 'true' experimental surrogates, would also show significant affinity for these actinides in aqueous media. It was also observed that crystalline silicotitanate impregnated polytetrafluoroethylene or polyethylene membranes became less selective and sorbed both cesium and strontium from the caustic aqueous salt simulants.

  16. Analysis of decontamination solutions of G agents to detect reformation of agent. Final report, December 1991-March 1992

    Energy Technology Data Exchange (ETDEWEB)

    Beaudry, W.T.; Buchanan, J.H.; Rohrbaugh, D.K.; Samuel, J.B.; Szafraniec, L.L.

    1993-01-01

    Agents from a full scale binary munition test were decontaminated with caustic in a 300 gal holding tank. Analysis of the contents by standard methods revealed a trace amount of G agent present despite the highly caustic solution. A technical review of the analytical methods was carried out to determine if the G agent was actually present or an artifact of the analysis. A literature search revealed similar concerns when brine solutions from nerve agent decontamination were analyzed using similar analytical methods. This study concluded that nerve agents reformed at reduced PH or in chloroform extracts of the neutralized or slightly acidic brines. Experiments using nuclear magnetic resonance (NMR), gas chromatography (GC), and GC/mass spectrometry (GC/MS) were used to see where, if any, G agent was present during the analysis. Results obtained confirmed G agent reforming in either the neutral aqueous solution or in the chloroform extract but not in chloroform extracts of the caustic solution. No agent was detected using methylene chloride as the extraction solvent as recommended by the earlier study.

  17. EFRT M-12 Issue Resolution: Comparison of Filter Performance at PEP and CUF Scale

    Energy Technology Data Exchange (ETDEWEB)

    Daniel, Richard C.; Billing, Justin M.; Bontha, Jagannadha R.; Brown, Christopher F.; Eslinger, Paul W.; Hanson, Brady D.; Huckaby, James L.; Karri, Naveen K.; Kimura, Marcia L.; Kurath, Dean E.; Minette, Michael J.

    2009-08-13

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, Undemonstrated Leaching Processes. The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed-preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP2, the slurry is concentrated to nominally 20 wt

  18. Results of Characterization and Retrieval Testing on Tank 241-C-109 Heel Solids

    Energy Technology Data Exchange (ETDEWEB)

    Callaway, William S.

    2013-09-26

    Eight samples of heel solids from tank 241-C-109 were delivered to the 222-S Laboratory for characterization and dissolution testing. After being drained thoroughly, one-half to two-thirds of the solids were off-white to tan solids that, visually, were fairly evenly graded in size from coarse silt (30-60 μm) to medium pebbles (8-16 mm). The remaining solids were mostly strongly cemented aggregates ranging from coarse pebbles (16-32 mm) to fine cobbles (6-15 cm) in size. Solid phase characterization and chemical analysis indicated that the air-dry heel solids contained ≈58 wt% gibbsite [Al(OH){sub 3}] and ≈37 wt% natrophosphate [Na{sub 7}F(PO{sub 4}){sub 2}·19H{sub 2}O]. The strongly cemented aggregates were mostly fine-grained gibbsite cemented with additional gibbsite. Dissolution testing was performed on two test samples. One set of tests was performed on large pieces of aggregate solids removed from the heel solids samples. The other set of dissolution tests was performed on a composite sample prepared from well-drained, air-dry heel solids that were crushed to pass a 1/4-in. sieve. The bulk density of the composite sample was 2.04 g/mL. The dissolution tests included water dissolution followed by caustic dissolution testing. In each step of the three-step water dissolution tests, a volume of water approximately equal to 3 times the initial volume of the test solids was added. In each step, the test samples were gently but thoroughly mixed for approximately 2 days at an average ambient temperature of 25 °C. The caustic dissolution tests began with the addition of sufficient 49.6 wt% NaOH to the water dissolution residues to provide ≈3.1 moles of OH for each mole of Al estimated to have been present in the starting composite sample and ≈2.6 moles of OH for each mole of Al potentially present in the starting aggregate sample. Metathesis of gibbsite to sodium aluminate was then allowed to proceed over 10 days of gentle mixing of the

  19. Characterization, Washing, Leaching, and Filtration of C-104 Sludge

    Energy Technology Data Exchange (ETDEWEB)

    KP Brooks; PR Bredt; GR Golcar; SA Hartley; LK Jagoda; KG Rappe; MW Urie

    2000-06-09

    Approximately 1,400 g of wet Hanford Tank C-104 Sludge was evaluated by Battelle for the high-level waste (HLW) pretreatment processes of ultrafiltration, dilute caustic washing, and elevated-temperature caustic leaching. The filterability of diluted C-104 sludge was measured with a 0.1-{micro}m sintered metal Mott filter using a 24-inch-long, single-element, crossflow filtration system (cells unit filter [CUF]). While the filtrate was being recirculated prior to washing and leaching, a 6.9 wt% solids slurry was evaluated with a matrix of seven 1-hour conditions of varying trans-membrane pressure (30 to 70 psid) and axial velocity (9 to 15 ft/s). The filtrate flux and backpulse efficiency were determined for each condition. The slurry was concentrated to 23 wt% solids, a second matrix of six 1-hour conditions was performed, and data analogous to that recorded in the first matrix were obtained. The low-solids-concentration matrix produced filtrate flux rates that ranged from 0.038 to 0.083 gpm/ft{sup 2}. The high-solids-concentration matrix produced filtrate flux rates that ranged from 0.0095 to 0.0172 gpm/ft{sup 2}. In both cases, the optimum filtrate flux was at the highest axial velocity (15 ft/s) and transmembrane pressure had little effect. Nearly all of the measured filtrate fluxes were more than an order of magnitude greater than the required plant flux for C-104 of 0.00126 gpm/ft{sup 2}. In both matrices, the filtrate flux appeared to be proportional to axial velocity, and the permeability appeared to be inversely proportional to the trans-membrane pressure. The first test condition was repeated as the last test condition for each matrix. In both cases, there was a significant decrease in filtrate flux, indicating some filter fouling during the test matrix that could not be removed by backpulsing alone, although the backpulse number and duration were not optimized. Following testing of these two matrices, the material was washed within the CUF by

  20. NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA

    Energy Technology Data Exchange (ETDEWEB)

    Steimke, J.

    2011-02-01

    This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves

  1. Investigation of flammable gas and thermal safety issues for retrieval of waste from Tank 241-AN-105

    Energy Technology Data Exchange (ETDEWEB)

    Caley, S.M.; Stewart, C.W.; Antoniak, Z.I.; Cuta, J.M.; Mahoney, L.A.; Panisko, F.E.

    1998-09-01

    The primary purpose of this report is to identify and resolve some of the flammable gas and thermal safety issues potentially associated with the retrieval of waste from Tank 241-AN-105 (AN-105), which is the first double-shell tank scheduled for waste retrieval at Hanford. The planned retrieval scenario includes the following steps in AN-105: (1) degas the tank using two submerged mixing pumps, (2) turn off the mixer pump(s) and allow any suspended solids to settle, (3) decant the supernatant to the intermediate feed staging tank(s) (IFSTs) (AP-102 and/or AP-104) using water/caustic dilution at the transfer pump inlet, (4) add the remaining dilution water/caustic to the slurry remaining in AN-105, (5) mix the tank with the mixer pump(s) until the soluble solids dissolve, (6) turn off the mixer pump(s) and let the insoluble solids settle, and (7) decant the new supernatant to the IFST(s), leaving the insoluble solids behind. Three waste retrieval safety issues are addressed in this report. They are (1) the controlled degassing of AN-105 to ensure that the headspace remains <25% of the lower flammability limit (LFL), (2) an assessment of how dissolved gas (mainly ammonia) released during the transfer of the supernatant in AN-105 to the IFSTs and the water/caustic dilution of the remaining slurry in AN-105 will affect the flammability in these tanks; and (3) an assessment of the maximum waste temperatures that might occur in AN-105 during retrieval operations.

  2. Chemical and radiation stability of a proprietary cesium ion exchange material manufactured from WWL membrane and SuperLig{reg_sign} 644

    Energy Technology Data Exchange (ETDEWEB)

    Brown, G.N.; Carson, K.J.; DesChane, J.R.; Elovich, R.J.; Berry, P.K.

    1996-09-01

    Pretreatment of nuclear process wastes for ion exchange removal of Cs and other radionuclides is one way to minimize amount of high-level radioactive waste at Hanford. This study evaluated Cs-selective SuperLig{reg_sign}644 (IBC Advanced Technologies, American Fork UT) entrapped in a proprietary WWL web membrane (3M) for chemical/radiation stability in simulated caustic neutralized current acid waste (NCAW), 0.5M HNO{sub 3}, water, and air. After exposure up to 2.0E+09 rad, the material was evaluated for Cs uptake in 5M sodium NCAW simulants with varying Cs contents. Radiolytic stability appears to be sufficient for ion exchange pretreatment of radioactive Cs: essentially no decrease in Cs selectivity or loading (Kd) was observed during {sup 60}Cs gamma irradiation in water or 0.5M HNO{sub 3} up to 1.0E+09 rad. Cs Kd decreased by a factor of 2 after 2.0E+09 rad exposure. Cs Kd did not change during irradiation in 5M NCAW or ambient air up to 1.0E+08 rad, but decreased by more than an order of magnitude between 1.0E+08 and 2.0E+09 rad (not typical of process conditions). Chemical stability under caustic conditions is lower than in air or under neutral/acidic conditions. Results indicate that this material is less stable in caustic solution irrespective of radiation exposure. Samples of the membrane retained their physical form throughout the entire experiment and were only slightly brittle after exposure to 2.0E+09 rad. (The material evaluated was a finely ground (400 mesh) particulate engineered to form a polymeric fiber (WWL), not the macroscopic form of SuperLig{reg_sign} 644 resin (20 to 50 mesh).)

  3. Properties of Microlensing Events by Wide-separation Planets with a Moon

    Science.gov (United States)

    Chung, Sun-Ju; Ryu, Yoon-Hyun

    2016-07-01

    We investigate the properties of microlensing events caused by planetary systems where planets with a moon are widely separated from their host stars. From this investigation, we find that the moon feature generally appears as a very short-duration perturbation on the smooth asymmetric light curve of the lensing event induced by the wide-separation planet; thus it can be easily discriminated from the planet feature responsible for the overall asymmetric light curve. For typical Galactic lensing events with an Einstein radius of ˜2 au, the asymmetry of the light curves due to bound planets can be noticed up to ˜20 au. We also find that the perturbations of wide planetary systems become dominated by the moon as the projected star-planet separation increases, and eventually the light curves of events produced by such systems appear as the single lensing light curve of the planet itself with a very short-duration perturbation induced by the moon, which is a representative light curve of the event induced by a star and a planet, except on the Einstein timescale of the planet. We also study the effect of a finite source star on the moon feature in wide planetary lensing events. From this study, we find that when the lunar caustic is sufficiently separated from the planetary caustic, the lower limit on the ratio of the size of the lunar caustic to the source radius causing a ≥5% lunar deviation depends mostly on the projected planet-moon separation regardless of the moon/star mass ratio, and it decreases as the planet-moon separation becomes smaller or larger than the planetary Einstein radius.

  4. STRESS CORROSION CRACKING SUSCEPTIBILITY OF HIGH LEVEL WASTE TANKS DURING SLUDGE MASS REDUCTION

    Energy Technology Data Exchange (ETDEWEB)

    Subramanian, K

    2007-10-18

    Aluminum is a principal element in alkaline nuclear sludge waste stored in high level waste (HLW) tanks at the Savannah River Site. The mass of sludge in a HLW tank can be reduced through the caustic leaching of aluminum, i.e. converting aluminum oxides (gibbsite) and oxide-hydroxides (boehmite) into soluble hydroxides through reaction with a hot caustic solution. The temperature limits outlined by the chemistry control program for HLW tanks to prevent caustic stress corrosion cracking (CSCC) in concentrated hydroxide solutions will potentially be exceeded during the sludge mass reduction (SMR) campaign. Corrosion testing was performed to determine the potential for CSCC under expected conditions. The experimental test program, developed based upon previous test results and expected conditions during the current SMR campaign, consisted of electrochemical and mechanical testing to determine the susceptibility of ASTM A516 carbon steel to CSCC in the relevant environment. Anodic polarization test results indicated that anodic inhibition at the temperatures and concentrations of interest for SMR is not a viable, consistent technical basis for preventing CSCC. However, the mechanical testing concluded that CSCC will not occur under conditions expected during SMR for a minimum of 35 days. In addition, the stress relief for the Type III/IIIA tanks adds a level of conservatism to the estimates. The envelope for corrosion control is recommended during the SMR campaign is shown in Table 1. The underlying assumption is that solution time-in-tank is limited to the SMR campaign. The envelope recommends nitrate/aluminate intervals for discrete intervals of hydroxide concentrations, although it is recognized that a continuous interval may be developed. The limits also sets temperature limits.

  5. Exploratory studies on some electrochemical cell systems

    Science.gov (United States)

    Chaudhuri, Srikumar; Guha, D.

    Exploratory studies were conducted on cell systems with different metal anodes, and iodine and sulphur mixed with graphite powder in a polymer matrix as cathodes, using different electrolytes in non-aqueous and aqueous media as ionic charge carriers. The electrical conductance of the electrolyte solutions in aqueous and non-aqueous solvents, the open circuit voltage (OCV) and short circuit current (SCC) for the different cell systems were measured. To date, the non-aqueous solvents used in our studies were dimethylformamide, formamide, dioxan, and nitrobenzene, and the electrolytes used were potassium iodide, caustic potash, cetyltrimethylammonium bromide (CTAB), sodium lauryl sulphate (SLS) and calcium chloride. These electrolytes were used in both non-aqueous and aqueous media. In general, aqueous electrolyte solutions gave a better performance than non-aqueous electrolyte solutions. Of the aqueous electrolytes, the highest conductance was shown by potassium chloride solution in water (conductance=0.0334 mho). However, the best OCV and SCC were shown by aluminium as anode and iodine as cathode with a saturated solution of caustic potash in water. The OCV was 1.85 V and the SCC was 290 mA cm -2. The highest conductance among the non-aqueous systems was shown by caustic potash in formamide. (Conductance=0.013 mho.) The best OCV and SCC, however, were shown by a zinc anode and iodine cathode with saturated potassium chloride in formamide, having an OCV of 1.55 V and an SCC of 150 mA cm -2. Further studies are in progress to obtain detailed performance data and recharging characteristics of some of the more promising systems reported here.

  6. Can Cr( iii ) substitute for Al( iii ) in the structure of boehmite?

    Energy Technology Data Exchange (ETDEWEB)

    Chatterjee, Sayandev; Conroy, Michele A.; Smith, Frances N.; Jung, Hee-Joon; Wang, Zheming; Peterson, Reid A.; Huq, Ashfia; Burtt, David G.; Ilton, Eugene S.; Buck, Edgar C.

    2016-01-01

    The dissolution of boehmite is a technical issue for the Al industry because of its recalcitrant nature. In fact, a similar problem exists with boehmite in nuclear waste sludge at the Hanford site in eastern Washington State, USA. Dissolution of Al phases is required to reduce the waste loadings in the final borosilicate glass waste form. Although not the most common Al-bearing species in the sludge, boehmite may become a rate limiting step in the processing of the wastes. Hanford boehmite is an order of magnitude more resistant to dissolution in hot caustic solutions than expected from surface-normalized rates. We are exploring potential intrinsic and extrinsic effects that may limit boehmite reactivity; one clue comes from microstructural analyses that indicate an association of Cr with Al in the Hanford nuclear waste. Hence, in this first paper, we investigated the potential role of chromium on the reactivity of boehmite in caustic solution. An important finding was that irrespective of the synthesis pathway, amount of Cr(III), or the resultant morphology, there was no evidence for Cr incorporation in the bulk structure, in agreement with QM calculations. In fact, electron microscopic (EM) and spectroscopic analyses showed that Cr was enriched at the (101) edges of the boehmite. However, Cr had no measurable effect on the morphology during the synthesis step. In contrast, comparison of the morphologies of the synthetic Cr-doped and pure boehmite samples after exposure to caustic solutions provided evidence that Cr inhibited the corrosion. TEM showed that Cr was not homogeneously distributed at the surface. Consequently, Cr may have partially passivated the surface by blocking discrete energetic sites on the lateral surfaces of boehmite.

  7. C-104 high-level waste solids: Washing/leaching and solubility versus temperature studies

    Energy Technology Data Exchange (ETDEWEB)

    GJ Lumetta; DJ Bates; JP Bramson; LP Darnell; OT Farmer III; SK Fiskum; LR Greenwood; FV Hoopes; CZ Soderquist; MJ Steele; RT Steele; MW Urie; JJ Wagner

    2000-05-17

    This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing and caustic leaching on the composition of the C-104 HLW solids. The objective of this work was to determine the composition of the C-104 solids remaining after washing with 0.01 M NaOH or leaching with 3 M NaOH. Another objective of this test was to determine the solubility of the C-104 solids as a function of temperature. The work was conducted according to test plan BNFL-TP-29953-8, Rev. 0, ``Determination of the Solubility of HLW Sludge Solids.

  8. Methods of producing adsorption media including a metal oxide

    Science.gov (United States)

    Mann, Nicholas R; Tranter, Troy J

    2014-03-04

    Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

  9. Light capsules shaped by curvilinear meta-surfaces

    CERN Document Server

    Naserpour, Mahin; Zakery, A; Miret, Juan J

    2015-01-01

    We propose a simple yet efficient method for generating in-plane hollow beams with a nearly-full circular light shell without the contribution of backward propagating waves. The method relies on modulating the phase in the near field of a centro-symmetric optical wavefront, such as that from a high-numericalaperture focused wave field. We illustrate how beam acceleration may be carried out by using an ultranarrow non-flat meta-surface formed by engineered plasmonic nanoslits. A mirrorsymmetric, with respect to the optical axis, circular caustic surface is numerically demonstrated that can be used as an optical bottle.

  10. Horizons in 2+1-dimensional collapse of particles

    Indian Academy of Sciences (India)

    Dieter Brill; Puneet Khetarpal; Vijay Kaul

    2007-07-01

    A simple, geometrical construction is given for three-dimensional spacetimes with negative cosmological constant that contain two particles colliding head-on. Depending on parameters like particle masses and distance, the combined geometry will be that of a particle, or of a black hole. In the black hole case the horizon is calculated. It is found that the horizon typically starts at a point and spreads into a closed curve with corners, which propagate along spacelike caustics and disappear as the horizon passes the particles.

  11. Nonsequential modeling of laser diode stacks using Zemax: simulation, optimization, and experimental validation.

    Science.gov (United States)

    Coluccelli, Nicola

    2010-08-01

    Modeling a real laser diode stack based on Zemax ray tracing software that operates in a nonsequential mode is reported. The implementation of the model is presented together with the geometric and optical parameters to be adjusted to calibrate the model and to match the simulated intensity irradiance profiles with the experimental profiles. The calibration of the model is based on a near-field and a far-field measurement. The validation of the model has been accomplished by comparing the simulated and experimental transverse irradiance profiles at different positions along the caustic formed by a lens. Spot sizes and waist location are predicted with a maximum error below 6%.

  12. 离子膜电解盐水中氯酸盐含量的测定%Determination of chlorate content in brine for ion-exchange membrane electrolyzsis

    Institute of Scientific and Technical Information of China (English)

    李志平

    2015-01-01

    提出用双氧水测定离子膜法烧碱生产用的盐水中的氯酸盐含量。试验结果表明:采用该法检测,相对标准偏差低于0.4%,回收率在99%以上。%A method of using hydrogen peroxide to determine chlorate content in brine used for production of ion-exchange membrane caustic soda was proposed.Test results showed that relative standard deviation was lower than 0 .4%, and recovery rate was more than 99%.

  13. INITIAL VALUE TECHNIQUES FOR THE HELMHOLTZ AND MAXWELL EQUATIONS

    Institute of Scientific and Technical Information of China (English)

    Frank Natterer; Olga Klyubina

    2007-01-01

    We study the initial value problem of the Helmholtz equation with spatially variable wave number. We show that it can be stabilized by suppressing the evanescent waves. The stabilized Helmholtz equation can be solved numerically by a marching scheme combined with FFT. The resulting algorithm has complexity n2 log n on a n x n grid. We demonstrate the efficacy of the method by numerical examples with caustics. For the Maxwell equation the same treatment is possible after reducing it to a second order system. We show how the method can be used for inverse problems arising in acoustic tomography and microwave imaging.

  14. Development and optimization of a standard method for extraction of microplastics in mussels by enzyme digestion of soft tissues.

    Science.gov (United States)

    Catarino, Ana I; Thompson, Richard; Sanderson, William; Henry, Theodore B

    2017-04-01

    The authors compared procedures for digestion of mussel soft tissues and extraction of microplastics. Complete tissue digestion was achieved with 1M NaOH, 35% HNO3 , and protease at 9.6 UHb/mL (unit hemoglobin per mL); but use of HNO3 caused unacceptable destruction of some microplastics. Recovery of microplastics spiked into mussels was similar (93 ± 10%) for NaOH and enzyme digestions. The authors recommend use of industrial enzymes based on digestion efficiency, microplastic recovery, and avoidance of caustic chemicals. Environ Toxicol Chem 2017;36:947-951. © 2016 SETAC.

  15. Detection of Chlorophenolic Compounds in Bleaching Effluents of Chemical Pulps

    Institute of Scientific and Technical Information of China (English)

    Chhaya Sharma; S.Mohanty; S.Kumar; N.J.Rao; li qian

    2008-01-01

    Laboratory bleaching effluents from the chlorination and caustic extraction stages of mixed wood kraft pulp processing have been analysed both qualitatively and quantitatively for various chlorophenolics by using GC.A number of chlorinated derivaties of phenols,catechols,guaiacols and syringaldehydes have been detected and their concentrations are estimated.The results are compared with that of different agriculture residue / hardwood pulps,which were reported in literature.The concentrations of various compounds detected have also been compared with their reported 96LC50 values.

  16. Clinical and forensic signs related to chemical burns: a mechanistic approach.

    Science.gov (United States)

    Dinis-Oliveira, Ricardo Jorge; Carvalho, Félix; Moreira, Roxana; Proença, Jorge Brandão; Santos, Agostinho; Duarte, José Alberto; Bastos, Maria de Lourdes; Magalhães, Teresa

    2015-06-01

    This manuscript highlights and critically analyses clinical and forensic signs related to chemical burns. Signs that may lead to suspicion of a particular chemical are thoroughly discussed regarding its underlying mechanisms. Burns due to sulfuric, hydrofluoric, nitric, hydrochloric (muriatic) and acetic (including derivatives) acids, hydrogen sulphide, sodium (caustic soda) and calcium (cement) hydroxides, paraquat, burns after inflation and rupture of airbags, povidone-iodine, chlorhexidine/alcohol (in preterm infants), laxatives, and vesicants (warfare agents), will be reviewed since these are the most common agents found in daily practice, for which relevant and timed information may be helpful in formulating an emergency treatment protocols and toxicological analysis.

  17. On the notion of phase in mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Gosson, Maurice A de [Department of Mathematics, Blekinge Institute of Technology, SE-371 79 Karlskrona (Sweden)

    2004-07-23

    The notion of phase plays an essential role in both semiclassical and quantum mechanics. But what is exactly a phase, and how does it change with time? It turns out that the most universal definition of a phase can be given in terms of Lagrangian manifolds by exploiting the properties of the Poincare-Cartan form. Such a phase is defined, not in configuration space, but rather in phase-space and is thus insensitive to the appearance of caustics. Surprisingly enough, this approach allows us to recover the Heisenberg-Weyl formalism without invoking commutation relations for observables.

  18. Rotating gravitational lenses: a kinematic approach

    CERN Document Server

    Walters, Steve

    2014-01-01

    This paper uses the Kerr geodesic equations for massless particles to derive an acceleration vector in both Boyer-Lindquist and Cartesian coordinates. As a special case, the Schwarzschild acceleration due to a non-rotating mass has a particularly simple and elegant form in Cartesian coordinates. Using forward integration, these equations are used to plot the caustic pattern due to a system consisting of a rotating point mass with a smaller non-rotating planet. Additionally, first and second order approximations to the paths are identified, which allows for fast approximations of paths, deflection angles and travel-time delays.

  19. Tessellating the cosmological dark-matter sheet: origami creases in the universe and ways to find them

    CERN Document Server

    Neyrinck, Mark C

    2012-01-01

    Tessellations are valuable both conceptually and for analysis in the study of the large-scale structure of the universe. They provide a conceptual model for the 'cosmic web,' and are of great use to analyze cosmological data. Here we describe tessellations in another set of coordinates, of the initially flat sheet of dark matter that gravity folds up in rough analogy to origami. The folds that develop are called caustics, and they tessellate space into stream regions. Tessellations of the dark-matter sheet are also useful in simulation analysis, for instance for density measurement, and to identify structures where streams overlap.

  20. 影响黄油生成量因素及黄油的外送方法%Factors affecting output of butter and butter delivery

    Institute of Scientific and Technical Information of China (English)

    宋建东

    2015-01-01

    烯烃生产过程中碱洗塔中会生成黄油。本文针对黄油产生的危害性,介绍了黄油生成的机理,并提出了减少黄油生成的优化方法及黄油外送方法。%The mechanism of butter generated in caustic tower during olefin production is introduced in this paper to provide solutions for reduction of the output and delivery methods of the butter.

  1. Approaches to Computer Modeling of Phosphate Hide-Out.

    Science.gov (United States)

    1984-06-28

    phosphate acts as a buffer to keep pH at a value above which acid corrosion occurs . and below which caustic corrosion becomes significant. Difficulties are...ionization of dihydrogen phosphate : HIPO - + + 1PO, K (B-7) H+ + - £Iao 1/1, (B-8) H , PO4 - + O- - H0 4 + H20 K/Kw (0-9) 19 * Such zero heat...OF STANDARDS-1963-A +. .0 0 0 9t~ - 4 NRL Memorandum Report 5361 4 Approaches to Computer Modeling of Phosphate Hide-Out K. A. S. HARDY AND J. C

  2. EXPERIMENTAL STUDY ON CRACK CURVING PROPAGATION IN BENDING BEAMS UNDER IMPULSIVE LOAD

    Institute of Scientific and Technical Information of China (English)

    Fang Jing; Yao Xuefeng; Xiong Chunyang

    2000-01-01

    Dynamic fracture behaviour of crack curving in bent beams has been investigated.In order to understand the propagation mechanism of such cracks under impact,an experimental method is used that combines dynamic photoelasticity with dynamic caustics to study the interaction of the flexural waves and the crack.From the state change of the transient stresses in polymer specimen,the curving fracture in the impulsively loaded beams is analyzed.The dynamic responses of crack tips are evaluated by the stress intensity factors for the cracks running in varying curvature paths under bending stress wave.

  3. Searching for signals of magnetic lensing in ultra-high energy cosmic rays

    Energy Technology Data Exchange (ETDEWEB)

    Golup, Geraldina; Harari, Diego; Mollerach, Silvia; Roulet, Esteban, E-mail: golupg@ib.cnea.gov.ar, E-mail: harari@cab.cnea.gov.ar, E-mail: mollerach@cab.cnea.gov.ar, E-mail: roulet@cab.cnea.gov.ar [CONICET and Centro Atómico Bariloche, Av. Bustillo 9500, 8400, S. C. de Bariloche (Argentina)

    2011-07-01

    Ultra-high energy cosmic rays are mostly charged particles and they are therefore deflected by magnetic fields on their path from their sources to Earth. An interesting phenomenon arising from these deflections is the appearance of multiple images of a source, i.e. cosmic rays with the same energy coming from the same source that can arrive to the Earth from different directions. In this work we present a technique to identify secondary images, produced by the regular component of the galactic magnetic field, benefiting from the fact that near caustics the flux is significantly magnified.

  4. From Zn-Al layered double hydroxide to ZnO nanostructure:Gradually etching by sodium hydroxide

    Institute of Scientific and Technical Information of China (English)

    Gang Qiang Wan; Dong Xiang Li; Chun Fang Li; Jie Xu; Wan Guo Hou

    2012-01-01

    Zn-Al layered double hydroxide (LDH) was used as precursor to produce ZnO nanostructures through dissolution of aluminum hydroxide in caustic soda.The Zn-Al LDH could transform into different nanostructures of ZnO on LDH nanosheets and even pure ZnO nanorods under various NaOH concentration.The formed ZnO nanorods vertically aligned on both LDH sides.UV-vis diverse reflectance spectra show that the obtained ZnO nanorods have a band gap of approximately 3.05 eV.Such ZnO/LDH nanostructures might be used as photocatalyst in the organic pollutant decomposition.

  5. Reconfigurable heat-induced spin wave lenses

    Science.gov (United States)

    Dzyapko, O.; Borisenko, I. V.; Demidov, V. E.; Pernice, W.; Demokritov, S. O.

    2016-12-01

    We study the control and manipulation of propagating spin waves in yttrium iron garnet films using a local laser-induced heating. We show that, due to the refraction of spin waves in the thermal gradients, the heated region acts as a defocusing lens for Damon-Eshbach spin waves and as a focusing lens for backward volume waves enabling collimation of spin-wave beams in the latter case. In addition to the focusing/defocusing functionality, the local heating allows one to manipulate the propagation direction of the spin-wave beams and to efficiently suppress their diffraction spreading by utilizing caustic effects.

  6. Results of initial analyses of the salt (macro) batch 9 tank 21H qualification samples

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 9 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 9 composite sample indicates that the material does not display any unusual characteristics or observations, such as floating solids, the presence of large amount of solids, or unusual colors. Further results on the chemistry and other tests will be issued in the future.

  7. Results Of Initial Analyses Of The Salt (Macro) Batch 9 Tank 21H Qualification Samples

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-08

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 9 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 9 composite sample indicates that the material does not display any unusual characteristics. Further results on the chemistry and other tests will be issued in the future.

  8. Transportation of hazardous goods

    CERN Multimedia

    TS Department

    2008-01-01

    A general reminder: any transportation of hazardous goods by road is subject to the European ADR rules. The goods concerned are essentially the following: Explosive substances and objects; Gases (including aerosols and non-flammable gases such as helium and nitrogen); Flammable substances and liquids (inks, paints, resins, petroleum products, alcohols, acetone, thinners); Toxic substances (acids, thinners); Radioactive substances; Corrosive substances (paints, acids, caustic products, disinfectants, electrical batteries). Any requests for the transport of hazardous goods must be executed in compliance with the instructions given at this URL: http://ts-dep.web.cern.ch/ts-dep/groups/he/HH/adr.pdf Heavy Handling Section TS-HE-HH 73793 - 160364

  9. A decomposing technique for scheelite concentrate and low-grade scheelite concentrate

    Institute of Scientific and Technical Information of China (English)

    HUO Guangsheng; SUN Peimei; LI Honggui; LI Yunjiao; ZHAO Zhongwei; SUN Zhaoming; LIU Maosheng

    2004-01-01

    The effect of different decomposition conditions on tungsten recovery for scheelite concentrate has been examined. The results show that tungsten recovery can be more than 98% under decomposing conditions as follows: the amount of caustic soda is 2.2 and 3.2 times of theoretical respectively, ratio of water and ore is 0.7-0.8, temperature is 160℃, and preservation time is 2.0 h for scheelite concentrate (63.21% WO3) and low grade scheelite concentrate (55.17% WO3).

  10. Gravitational lensing by black holes: The case of Sgr A*

    Energy Technology Data Exchange (ETDEWEB)

    Bozza, V. [Dipartimento di Fisica E.R. Caianiello, Università di Salerno, Italy. Istituto Nazionale di Fisica Nucleare, Sezione di Napoli (Italy)

    2014-01-14

    The strong gravitational fields created by black holes dramatically affect the propagation of photons by bending their trajectories. Gravitational lensing thus stands as the main source of information on the space-time structure in such extreme regimes. We will review the theory and phenomenology of gravitational lensing by black holes, with the generation of higher order images and giant caustics by rotating black holes. We will then focus on Sgr A*, the black hole at the center of the Milky Way, for which next-to-come technology will be able to reach resolutions of the order of the Schwarzschild radius and ultimately test the existence of an event horizon.

  11. Image Consultancy with Yang Qingqing

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    IN a classroom of the Costume Schoolwith the Textile University of China inShanghai,a young female teacher drewseven faces on the blackboard.She pointedto a rhomboid face and asked her students,“If someone with this shaped face raisedtheir eyes,what woud they look like?” “A fox,”burst out a student. “Yes.This shape,with a thin foreheadand a pointed chin,appears very caustic.Ihave this face.”

  12. Semiclassical partition function for the double-well potential

    Science.gov (United States)

    Kroff, D.; Bessa, A.; de Carvalho, C. A. A.; Fraga, E. S.; Jorás, S. E.

    2014-07-01

    We compute the partition function and specific heat for a quantum-mechanical particle under the influence of a quartic double-well potential nonperturbatively, using the semiclassical method. Near the region of bounded motion in the inverted potential, the usual quadratic approximation fails due to the existence of multiple classical solutions and caustics. Using the tools of catastrophe theory, we identify the relevant classical solutions, showing that at most two have to be considered. This corresponds to the first step towards the study of spontaneous symmetry breaking and thermal phase transitions in the nonperturbative framework of the boundary effective theory.

  13. Semiclassical partition function for the double-well potential

    CERN Document Server

    Kroff, D; de Carvalho, C A A; Fraga, E S; Jorás, S E

    2013-01-01

    We compute the partition function and specific heat for a quantum mechanical particle under the influence of a quartic double-well potential non-perturbatively, using the semiclassical method. Near the region of bounded motion in the inverted potential, the usual quadratic approximation fails due to the existence of multiple classical solutions and caustics. Using the tools of catastrophe theory, we identify the relevant classical solutions, showing that at most two have to be considered. This corresponds to the first step towards the study of spontaneous symmetry breaking and thermal phase transitions in the non-perturbative framework of the boundary effective theory.

  14. Reaction Kinetic Studies of Waste Polymer and Hydrolytic Chlorine in EOCN Production

    Institute of Scientific and Technical Information of China (English)

    Koyo Murakami

    2005-01-01

    @@ 1Results and Discussion EOCNs are widely used by electric and electronics industries and coating and adhesive fields(see Tab. 1 ). EOCNs( =Epoxy O-Cresol Novolac)can be produced commercially in a two-step reaction, which consistsmainly of a novolac reaction step of o-cresol with formalin and an epoxidising step of the the novolac resins with epichlorohydrine in the presence of alkari hydroxide such as caustic soda, byproducing waste polymers which affect adversely fromthe viewpoint of process economy.

  15. The Rethermalizing Bose-Einstein Condensate of Dark Matter Axions

    CERN Document Server

    Banik, Nilanjan; Sikivie, Pierre; Todarello, Elisa Maria

    2015-01-01

    The axions produced during the QCD phase transition by vacuum realignment, string decay and domain wall decay thermalize as a result of their gravitational self-interactions when the photon temperature is approximately 500 eV. They then form a Bose-Einstein condensate (BEC). Because the axion BEC rethermalizes on time scales shorter than the age of the universe, it has properties that distinguish it from other forms of cold dark matter. The observational evidence for caustic rings of dark matter in galactic halos is explained if the dark matter is axions, at least in part, but not if the dark matter is entirely WIMPs or sterile neutrinos.

  16. Historical insights in the progression and development of gingivectomy.

    Science.gov (United States)

    Dokou, Panagiota; Tsami, Alexandra; Vrotsos, John A

    2014-01-01

    During the last three centuries since the identification of periodontal disease, various non-surgical and surgical forms of periodontal therapy have been described and documented in the dental literature. The main objective of periodontal treatment has been initially the removal of "diseased gingiva," either through the implementation of various surgical techniques, or through the application of caustic drugs or pressing patches. Although the differences in the suggested techniques created significant controversies between some of the greatest clinicians and researchers in dentistry, their main goals remained the rehabilitation of the oral cavity and the therapeutic management of the problems sustained from periodontal disease.

  17. A Highly Adjustable Helical Beam: Design and Propagation Characteristic

    CERN Document Server

    Wen, Yuanhui; Yu, Siyuan

    2016-01-01

    Light fields with extraordinary propagation behaviours such as nondiffracting and self-bending are useful in optical delivery for energy, information, and even objects. A kind of helical beams is constructed here based on the caustic method. With appropriate design, the main lobe of these helical beams can be both well-confined and almost nondiffracting while moving along a helix with its radius, period, the number of rotations and main lobes highly adjustable. In addition, the main lobe contains almost half of the optical power and the peak intensity fluctuates below 15% during propagation. These promising characteristics may enable a variety of potential applications based on these beams.

  18. A model for gyrotactic pattern formation of motile micro-organisms in turbulence

    CERN Document Server

    Gustavsson, K; Jonsson, P R; Mehlig, B

    2015-01-01

    Recent studies show that the dynamics of motile organisms subject to gravitational torques in turbulence gives rise to patchiness. Spherical motile organisms gather in down-welling regions of the turbulent flow. We determine how shape affects preferential sampling and small-scale spatial clustering (determining local encounter rates) by analysing a statistical model in two and three spatial dimensions. By recursively refining approximations for the paths the organisms take through the flow we determine analytically how preferential sampling and small-scale clustering in the model depend upon the dimensionless parameters of the problem. We show that singularities ("caustics") occur in the dynamics and discuss how these singularities affect spatial patterns.

  19. Modification of averaging process in GR: Case study flat LTB

    CERN Document Server

    Khosravi, Shahram; Mansouri, Reza

    2007-01-01

    We study the volume averaging of inhomogeneous metrics within GR and discuss its shortcomings such as gauge dependence, singular behavior as a result of caustics, and causality violations. To remedy these shortcomings, we suggest some modifications to this method. As a case study we focus on the inhomogeneous model of structured FRW based on a flat LTB metric. The effect of averaging is then studied in terms of an effective backreaction fluid. This backreaction fluid turns out to behave like a dark matter component, instead of dark energy as claimed in literature.

  20. Capillary floating and the billiard ball problem

    CERN Document Server

    Gutkin, Eugene

    2010-01-01

    We establish a connection between capillary floating in neutral equilibrium and the billiard ball problem. This allows us to reduce the question of floating in neutral equilibrium at any orientation with a prescribed contact angle for infinite homogeneous cylinders to a question about billiard caustics for their orthogonal cross-sections. We solve the billiard problem. As an application, we characterize the possible contact angles and exhibit an infinite family of real analytic non-round cylinders that float in neutral equilibrium at any orientation with constant contact angles.

  1. Preoperational test report, cross-site transfer water flush system (POTP-001)

    Energy Technology Data Exchange (ETDEWEB)

    Parsons, G.L.

    1998-02-20

    This report documents the results of the testing performed per POTP-001, for the Cross-Site Transfer Water Flush System. (HNF-1552, Rev. 0) The Flush System consists of a 47,000 gallon tank (302C), a 20 hp pump, two 498kW heaters, a caustic addition pump, various valves, instruments, and piping. The purpose of this system is to provide flush water at 140 F, 140gpm, and pH 11-12 for the Cross-Site Transfer System operation.

  2. [Cicatrization effect of Jatropha curcas latex (Angiospermae: Euforbiaceae)].

    Science.gov (United States)

    Salas, J; Tello, V; Zavaleta, A; Villegas, L; Salas, M; Fernández, I; Vaisberg, A

    1994-01-01

    The wound healing effects of Jathopha curcas latex upon surgical wound produced in Balb/c mice skin, were studied with a modification of the Hoowes-Sooy-Harvey method. The effects of topical treatment using single 50 ul doses of latex at different dilutions (10% to 100%) was compared with a multiple dose treatment (four 25 ul/dose q12h, latex 5% to 100%). The single dose treatment with 10%, 50% or 100% latex and the multiple dose treatment with dilutions between 5% and 10%, have a healing effect but only on males. The multiple dose treatment with 50% or pure undiluted latex produced caustic lesions to treated skin.

  3. Optimizing evaporation process to decrease vapour consumption%优化蒸发工艺 降低蒸汽消耗

    Institute of Scientific and Technical Information of China (English)

    王世荣

    2001-01-01

    对近几年山东大成农药股份有限公司氯碱厂烧碱蒸发工艺中存在的问题和采取的相应措施,及取得的效果进行了总结,并对现系统中仍存在的一些不足进行了探讨。%The present problems, measures to solve them, and results obtained in the caustic soda evaporation process of Chlor- Alkali Plant of Shangdonng Dacheng Pesticide Co. Ltd. in recent years were summarized. The shortcomings remained in the present system were investigated.

  4. 氯碱生产中节能减排的措施%Measures to save energy and reduce discharge during chlor-alkali production

    Institute of Scientific and Technical Information of China (English)

    张金豹; 尹睿; 付秦生; 席引尚

    2013-01-01

    Measures to save energy and reduce discharge during the production of caustic soda and PVC were introduced , including the reduction of consumption of raw and auxiliary materials , the recovery of waste heat , waste water and waste gas , and the application of advanced techniques .%介绍烧碱和PVC生产过程中节能减排的措施,包括:降低原辅材料消耗,余热、废水及废气的回收,先进技术的应用。

  5. On the classical limit of the Schrödinger equation

    KAUST Repository

    Bardos, Claude

    2015-05-01

    This paper provides an elementary proof of the classical limit of the Schrödinger equation with WKB type initial data and over arbitrary long finite time intervals. We use only the stationary phase method and the Laptev-Sigal simple and elegant construction of a parametrix for Schrödinger type equations [A. Laptev, I. Sigal, Review of Math. Phys. 12 (2000), 749-766]. We also explain in detail how the phase shifts across caustics obtained when using the Laptev-Sigal parametrix are related to the Maslov index. © 2015, Southwest Missouri State University. All rights reserved.

  6. Gas Chromatography Analysis of Resin and Fatty Acids from Laboratory Generated Bleach Plant Effluents

    Institute of Scientific and Technical Information of China (English)

    Chhaya Sharma; S. Mohanty; S. Kumar; N.J. Rao

    2007-01-01

    Laboratory generated spent bleached liquor from the chlorination, caustic extraction stage of mixed wood kraft pulp processing has been analyzed both qualitatively and quantitatively for various resin & fatty acids by using GC. A number of resin acids,saturated and unsaturated fatty acids, chloro fatty and resin acid have been detected and their concentrations are estimated. The results are compared with results on different agriculture residue/hardwood pulps, which were reported earlier. The concentrations of various compounds detected have also been compared with their reported LC50 values.

  7. Amazonian açai and food dyes for staining arbuscular- micorrhizal fungi

    Directory of Open Access Journals (Sweden)

    Aline Lourdes Martins Silva

    2015-12-01

    Full Text Available Arbuscular mycorrhizae microscopy requires differential staining of typical structures. Dyes employed, such as trypan blue, pose risks to health and environment. Alternative dyes such as pen ink and aniline have variable coloring efficiency. In this work, Brachiaria decumbens roots, discolored with caustic soda (NaOH, were stained with açai, annatto, saffron, trypan blue and pen inks. There were significant differences among dyes regarding stained mycorrhizal structures and pictures quality. Acai was considered the best alternative dye, with similar results to trypan blue.

  8. Advances in the research of scar stricture after esophageal burn%食管烧伤导致瘢痕狭窄的研究进展

    Institute of Scientific and Technical Information of China (English)

    赵士磊; 顾春东

    2013-01-01

    Caustic esophageal burn is a common ailment in clinical practice.In some patients,scar stricture was formed in the late stage of injury,and it seriously undermined quality of life of the patients.We adopted various clinical interventions at an early stage in order to relieve and alleviate the formation and development of corrosive esophageal stricture as a result of chemical injury as well as to avoid invasive operations to make it more acceptable for the patients.This article summarized the progress in etiology,pathological changes,identification,early prevention,and surgical management of corrosive esophageal stricture.

  9. Drug: D05840 [KEGG MEDICUS

    Lifescience Database Archive (English)

    Full Text Available D05840 Drug Silver nitrate, toughened (USP) 2Ag. NO3. Cl 310.7669 313.1943 D05840.g...if Caustic ATC code: D08AL01 S01AX02 A mixture of Silver nitrate [DR:D01730] and Silver chloride Anatomical ...08A ANTISEPTICS AND DISINFECTANTS D08AL Silver compounds D08AL01 Silver nitrate D05840 Silver... antiinfectives S01AX02 Silver compounds D05840 Silver nitrate, toughened (USP) CAS: 8007-31-6 PubChem: 4720... nitrate, toughened (USP) S SENSORY ORGANS S01 OPHTHALMOLOGICALS S01A ANTIINFECTIVES S01AX Other

  10. Mid-Esophagus Columnar Metaplasia: What Is the Biopathogenic Pathway?

    Science.gov (United States)

    Rolim, Inês; Rodrigues, Rita Vale; Bettencourt, António; Barros, Rita; Camilo, Vânia; Dias Pereira, António; Almeida, Raquel; Chaves, Paula

    2016-10-05

    We report a case of metaplastic columnar epithelium in the mid-esophagus in a patient with history of caustic ingestion. A cardiac-type gastric phenotype, with early signs of intestinalization, was confirmed by immunohistochemistry studies (MUC5AC, MUC6, SOX2, and CDX2). Nonmetaplastic mucosa had histologic evidence of gastroesophageal reflux. In this case, esophageal reepithelization seems to have been modulated by acidic gastroesophageal reflux, which might activate transcription factors leading to phenotypic reprogramming of the regenerative epithelium. Most interestingly, it is a clinical example showcasing the origin of columnar metaplasia from stem cells located within the esophageal epithelium.

  11. THERMODYNAMIC STUDY OF CHROMITE CAUSTICFUSION PROCESS

    Institute of Scientific and Technical Information of China (English)

    S.L. Zheng; Y. Zhang

    2001-01-01

    A new method for chromate cleaning production named chromite caustic fusion pro-cess, is advanced by Institute of Chemical Metallurgy, the Chinese Academy of Sci-ences. With sodium hydroxide as reaction medium, the new process is composed ofthree procedures: liquid phase oxidation of chromite - metastable phase separation -carbonation ammonium transition. Generally illustrating the new process and its fea-tures, this paper mainly studies the thermodynamics of chromite oxidation. The newprocess has much better practical results than the conventional chromate productionprocess in which sodium carbonate is used as reaction medium. The superiority is alsoshown through thermodynamic studies.``

  12. 应力腐蚀

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    STRESS CORROSION CRACKING OF 304L STAINLESS STEEL IN SODIUM SULFIDE-CONTAINING CAUSTIC SOLUTIONS,STRESS CORROSION CRACKING OF H.C.P.METALS AND ALLOYS IN IODINE-METHANOL SOLUTIONS,STRESS CORROSION CRACKING (SCC) AND CORROSION FATIGUE CRACKING (CFC) OF A DUPLEX STAINLESS STEEL IN WHITE WATER ENVIRONMENTS,EFFECT OF PROTECTIVE COATINGS ON THE STRESS CORROSION CRACKING OF API 5L-X52 LOW CARBON STEEL IN SOIL AND NS4 SOLUTIONS,CORROSION FATIGUE AND NEAR-NEUTRAL pH STRESS CORROSION CRACKING OF PIPELINE STEEL IN VERY DILUTE CARBONATE/BICARBONATE WITH AND WITHOUT THE PRESENCE OF HYDROGEN SULFIDE USING THE COMPLIANCE TECHNIQUE.

  13. Gamma Radiation Detectors of the TA-55 Waste Line Monitoring System

    Energy Technology Data Exchange (ETDEWEB)

    Jack E. Malcom

    1999-06-01

    This report covers the gamma detectors, measurement instrumentation, and testing results of a system developed at Los Alamos National Laboratory. This system monitors the process liquid waste streams at the Plutonium Facility (TA-55) for the presence of radioactive contamination. The detectors are at various points on the acid, caustic, and industrial waste lines. Two of the detectors are on the sanitary sewer lines from the facility. A custom interface unit associated with these two detectors furnishes the facility operation center with a notification of the detection of material. All of the detectors furnish measurement information to a central computer system for storage and trending.

  14. Measurement of the mass of mercury in electrolytic cells of Chemical Industry of the Istmo s. a. of c. v. Coatzacoalcos Plant, Ver. (Mexico); Determinacion de la masa de mercurio en celdas electroliticas de Industria Quimica del Istmo s. a. de c. v. Planta Coatzacoalcos, Ver

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Herrera M, J. M.; Flores M, J

    2001-01-15

    For the industry of the production of caustic soda and chlorine is commonly use electrolytic cells with mobile electrode of mercury; in the process it gets lost mass, and there is necessity to know the quantity of mercury that exists in each cell. To know the periodic levels of mercury in the 40 electrolytic cells of the Plant of Coatzacoalcos, in the State of Veracruz (Mexico), the investigators of the ININ used the technique of isotopic dilution by mean of the radioactive injection of a radioactive tracer.(Author)

  15. Application of the geometrical theory of diffraction to Cassegrain subreflectors with laterally defocused feeds

    DEFF Research Database (Denmark)

    Sørensen, O.; Rusch, W.

    1975-01-01

    The geometrical theory of diffraction (GTD) as formulated by R. G. Kouyoumjian has been applied to predict the radiation characteristics of hyperboloidal subreflectors with laterally defocused feeds. In caustic or multicaustic directions the scattered fields are determined using an equivalent ring...... current placed along the edge of the subreflector. The theoretical results are compared to measured amplitude and phase data. In order to improve the agreement, the blocking effects of the feed horn have been accounted for using the geometrical theory of diffraction. The calculated subreflector fields...

  16. Effect of turbulent atmosphere on the on-axis average intensity of Pearcey-Gaussian beam

    Science.gov (United States)

    F, Boufalah; L, Dalil-Essakali; H, Nebdi; A, Belafhal

    2016-06-01

    The propagation characteristics of the Pearcey-Gaussian (PG) beam in turbulent atmosphere are investigated in this paper. The Pearcey beam is a new kind of paraxial beam, based on the Pearcey function of catastrophe theory, which describes diffraction about a cusp caustic. By using the extended Huygens-Fresnel integral formula in the paraxial approximation and the Rytov theory, an analytical expression of axial intensity for the considered beam family is derived. Some numerical results for PG beam propagating in atmospheric turbulence are given by studying the influences of some factors, including incident beam parameters and turbulence strengths.

  17. GPU-Based Techniques for Global Illumination Effects

    CERN Document Server

    Szirmay-Kalos, László; Sbert, Mateu

    2008-01-01

    This book presents techniques to render photo-realistic images by programming the Graphics Processing Unit (GPU). We discuss effects such as mirror reflections, refractions, caustics, diffuse or glossy indirect illumination, radiosity, single or multiple scattering in participating media, tone reproduction, glow, and depth of field. This book targets game developers, graphics programmers, and also students with some basic understanding of computer graphics algorithms, rendering APIs like Direct3D or OpenGL, and shader programming. In order to make this book self-contained, the most important c

  18. A brown dwarf orbiting an M-dwarf

    DEFF Research Database (Denmark)

    Bachelet, E.; Fouqué, P.; Albrow, M.D.

    2012-01-01

    Context. Caustic crossing is the clearest signature of binary lenses in microlensing. In the present context, this signature is diluted by the large source star but a detailed analysis has allowed the companion signal to be extracted. Aims. MOA 2009-BLG-411 was detected on August 5, 2009 by the MOA-Collaboration....... Alerted as a high-magnification event, it was sensitive to planets. Suspected anomalies in the light curve were not confirmed by a real-time model, but further analysis revealed small deviations from a single lens extended source fit. Methods. Thanks to observations by all the collaborations, this event...

  19. Semi-classical analysis for nonlinear Schrödinger equations

    CERN Document Server

    Carles, Remi

    2008-01-01

    These lecture notes review recent results on the high-frequency analysis of nonlinear Schrödinger equations in the presence of an external potential. The book consists of two relatively independent parts: WKB analysis, and caustic crossing. In the first part, the basic linear WKB theory is constructed and then extended to the nonlinear framework. The most difficult supercritical case is discussed in detail, together with some of its consequences concerning instability phenomena. Applications of WKB analysis to functional analysis, in particular to the Cauchy problem for nonlinear Schrödinger e

  20. WKB propagators in position and momentum space for a linear potential with a ‘ceiling’ boundary

    Science.gov (United States)

    Zapata, T. A.; Fulling, S. A.

    2017-03-01

    As a model for the semiclassical analysis of quantum-mechanical systems with both potentials and boundary conditions, we construct the WKB propagator for a linear potential sloping away from an impenetrable boundary. First, we find all classical paths from point y to point x in time t and calculate the corresponding action and amplitude functions. A large part of space-time turns out to be classically inaccessible, and the boundary of this region is a caustic of an unusual type, where the amplitude vanishes instead of diverging. We show that this curve is the limit of caustics in the usual sense when the reflecting boundary is approximated by steeply rising smooth potentials. Then, to improve the WKB approximation we construct the propagator for initial data in momentum space; this requires classifying the interesting variety of classical paths with initial momentum p arriving at x after time t. The two approximate propagators are compared by applying them to Gaussian initial packets by numerical integration; the results show physically expected behavior, with advantages to the momentum-based propagator in the classically forbidden regime (large t).

  1. Measuring the Innermost Stable Circular Orbits of Supermassive Black Holes

    CERN Document Server

    Chartas, G; Zalesky, L; Kochanek, C S; Dai, X; Morgan, C W; Mosquera, A

    2016-01-01

    We present a promising new technique, the g-distribution method, for measuring the inclination angle (i), the innermost stable circular orbit (ISCO), and the spin of a supermassive black hole. The g-distribution method uses measurements of the energy shifts in the relativistic iron line emitted by the accretion disk of a supermassive black hole due to microlensing by stars in a foreground galaxy relative to the g-distribution shifts predicted from microlensing caustic calculations. We apply the method to the gravitationally lensed quasars RX J1131-1231 (z_s=0.658, z_l=0.295), QJ 0158-4325 (z_s=1.294, z_l=0.317), and SDSS 1004+4112 (z_s=1.734, z_l=0.68). For RX J1131-1231 our initial results indicate that r_ISCO 76 degrees. We detect two shifted Fe lines, in several observations, as predicted in our numerical simulations of caustic crossings. The current DeltaE-distribution of RX J1131-1231 is sparsely sampled but further X-ray monitoring of RX J1131-1231 and other lensed quasars will provide improved constrai...

  2. OGLE-2015-BLG-0479LA,B: Binary Gravitational Microlens Characterized by Simultaneous Ground-based and Space-based Observation

    CERN Document Server

    Han, C; Gould, A; Zhu, Wei; Street, R A; Yee, J C; Beichman, C; Bryden, C; Novati, S Calchi; Carey, S; Fausnaugh, M; Gaudi, B S; Henderson, Calen B; Shvartzvald, Y; Wibking, B; Szymański, M K; Soszyński, I; Skowron, J; Mróz, P; Poleski, R; Pietrukowicz, P; Kozłowski, S; Ulaczyk, K; Wyrzykowski, Ł; Pawlak, M; Tsapras, Y; Hundertmark, M; Bachelet, E; Dominik, M; Bramich, D M; Cassan, A; Jaimes, R Figuera; Horne, K; Ranc, C; Schmidt, R; Snodgrass, C; Wambsganss, J; Steele, I A; Menzies, J; Mao, S; Bozza, V; Jørgensen, U G; Alsubai, K A; Ciceri, S; D'Ago, G; Haugbølle, T; Hessman, F V; Hinse, T C; Juncher, D; Korhonen, H; Mancini, L; Popovas, A; Rabus, M; Rahvar, S; Scarpetta, G; Skottfelt, J; Southworth, J; Starkey, D; Surdej, J; Wertz, O; Zarucki, M; Pogge, R W; DePoy, D L

    2016-01-01

    We present a combined analysis of the observations of the gravitational microlensing event OGLE-2015-BLG-0479 taken both from the ground and by the {\\it Spitzer Space Telescope}. The light curves seen from the ground and from space exhibit a time offset of $\\sim 13$ days between the caustic spikes, indicating that the relative lens-source positions seen from the two places are displaced by parallax effects. From modeling the light curves, we measure the space-based microlens parallax. Combined with the angular Einstein radius measured by analyzing the caustic crossings, we determine the mass and distance of the lens. We find that the lens is a binary composed of two G-type stars with masses $\\sim 1.0\\ M_\\odot$ and $\\sim 0.9\\ M_\\odot$ located at a distance $\\sim 3$ kpc. In addition, we are able to constrain the complete orbital parameters of the lens thanks to the precise measurement of the microlens parallax derived from the joint analysis. In contrast to the binary event OGLE-2014-BLG-1050, which was also ob...

  3. Spitzer as Microlens Parallax Satellite: Mass and Distance Measurements of Binary Lens System OGLE-2014-BLG-1050L

    CERN Document Server

    Zhu, Wei; Gould, A; Dominik, M; Bozza, V; Han, C; Yee, J C; Novati, S Calchi; Beichman, C A; Carey, S; Poleski, R; Skowron, J; Kozlowski, S; Mroz, P; Pietrukowicz, P; Pietrzynski, G; Szymanski, M K; Soszynski, I; Ulaczyk, K; Wyrzykowski, L; Han, C; Gaudi, B S; Pogge, R W; DePoy, D L; Jung, Y K; Choi, J -Y; Hwang, K -H; Shin, I -G; Park, H; Jeong, J

    2015-01-01

    We report the first mass and distance measurement of a caustic-crossing binary system OGLE-2014-BLG-1050L using the space-based microlens parallax method. \\emph{Spitzer} captured the second caustic-crossing of the event, which occurred $\\sim$10 days before that seen from Earth. Due to the coincidence that the source-lens relative motion was almost parallel to the direction of the binary-lens axis, the four-fold degeneracy, which was known before only to occur in single-lens events, persists in this case, leading to either a lower-mass (0.2 $M_\\odot$ and 0.07 $M_\\odot$) binary at $\\sim$1.1 kpc or a higher-mass (0.9 $M_\\odot$ and 0.35 $M_\\odot$) binary at $\\sim$3.5 kpc. However, the latter solution is strongly preferred for reasons including blending and lensing probability. OGLE-2014-BLG-1050L demonstrates the power of microlens parallax in probing stellar and substellar binaries.

  4. Predictions for microlensing planetary events from core accretion theory

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Wei; Mao, Shude [National Astronomical Observatories, Chinese Academy of Sciences, 20A Datun Road, Chaoyang District, Beijing 100012 (China); Penny, Matthew; Gould, Andrew [Department of Astronomy, The Ohio State University, 140 W. 18th Avenue, Columbus, OH 43210 (United States); Gendron, Rieul, E-mail: weizhu@astronomy.ohio-state.edu [Jodrell Bank Centre for Astrophysics, University of Manchester, Alan Turing Building, Manchester M13 9PL (United Kingdom)

    2014-06-10

    We conduct the first microlensing simulation in the context of a planet formation model. The planet population is taken from the Ida and Lin core accretion model for 0.3 M {sub ☉} stars. With 6690 microlensing events, we find that for a simplified Korea Microlensing Telescopes Network (KMTNet), the fraction of planetary events is 2.9%, out of which 5.5% show multiple-planet signatures. The numbers of super-Earths, super-Neptunes, and super-Jupiters detected are expected to be almost equal. Our simulation shows that high-magnification events and massive planets are favored by planet detections, which is consistent with previous expectation. However, we notice that extremely high-magnification events are less sensitive to planets, which is possibly because the 10 minute sampling of KMTNet is not intensive enough to capture the subtle anomalies that occur near the peak. This suggests that while KMTNet observations can be systematically analyzed without reference to any follow-up data, follow-up observations will be essential in extracting the full science potential of very high magnification events. The uniformly high-cadence observations expected for KMTNet also result in ∼55% of all detected planets not being caustic crossing, and more low-mass planets even down to Mars mass being detected via planetary caustics. We also find that the distributions of orbital inclinations and planet mass ratios in multiple-planet events agree with the intrinsic distributions.

  5. Wild capuchin monkeys adjust stone tools according to changing nut properties.

    Science.gov (United States)

    Luncz, Lydia V; Falótico, Tiago; Pascual-Garrido, Alejandra; Corat, Clara; Mosley, Hannah; Haslam, Michael

    2016-09-14

    Animals foraging in their natural environments need to be proficient at recognizing and responding to changes in food targets that affect accessibility or pose a risk. Wild bearded capuchin monkeys (Sapajus libidinosus) use stone tools to access a variety of nut species, including otherwise inaccessible foods. This study tests whether wild capuchins from Serra da Capivara National Park in Brazil adjust their tool selection when processing cashew (Anacardium spp.) nuts. During the ripening process of cashew nuts, the amount of caustic defensive substance in the nut mesocarp decreases. We conducted field experiments to test whether capuchins adapt their stone hammer selection to changing properties of the target nut, using stones of different weights and two maturation stages of cashew nuts. The results show that although fresh nuts are easier to crack, capuchin monkeys used larger stone tools to open them, which may help the monkeys avoid contact with the caustic hazard in fresh nuts. We demonstrate that capuchin monkeys are actively able to distinguish between the maturation stages within one nut species, and to adapt their foraging behaviour accordingly.

  6. Fire and explosion hazards related to the industrial use of potassium and sodium methoxides.

    Science.gov (United States)

    Kwok, Q; Acheson, B; Turcotte, R; Janès, A; Marlair, G

    2013-04-15

    Sodium and potassium methoxides are used as an intermediary for a variety of products in several industrial applications. For example, current production of so called "1G-biodiesel" relies on processing a catalytic reaction called "transesterification". This reaction transforms lipid resources from biomass materials into fatty acid methyl and ethyl esters. 1-G biodiesel processes imply the use of methanol, caustic potash (KOH), and caustic soda (NaOH) for which the hazards are well characterized. The more recent introduction of the direct catalysts CH3OK and CH3ONa may potentially introduce new process hazards. From an examination of existing MSDSs concerning these products, it appears that no consensus currently exists on their intrinsic hazardous properties. Recently, l'Institut National de l'Environnement Industriel et des Risques (France) and the Canadian Explosives Research Laboratory (Canada) have embarked upon a joint effort to better characterize the thermal hazards associated with these catalysts. This work employs the more conventional tests for water reactivity as an ignition source, fire and dust explosion hazards, using isothermal nano-calorimetry, isothermal basket tests, the Fire Propagation Apparatus and a standard 20 L sphere, respectively. It was found that these chemicals can become self-reactive close to room temperature under specific conditions and can generate explosible dusts.

  7. Microlensing of the Fe K$\\alpha$ line and the X-ray continuum

    CERN Document Server

    Popovic, L C; Mediavilla, E; Zakharov, A F; Abajas, C; Muñoz, J A; Chartas, G

    2005-01-01

    The observed enhancement of the Fe K$\\alpha$ line in three gravitationally lensed QSOs (MG J0414+0534, QSO 2237+0305, H1413+117) is interpreted in terms of microlensing, even when equivalent X-ray continuum amplification is not observed. In order to interpret these observations, first we studied the effects of microlensing on quasars spectra, produced by straight fold caustic crossing over standard relativistic accretion disk. The disk emission was analyzed using the ray tracing method, considering Schwarzschild and Kerr metrics. When the emission is separated in two regions (an inner disk corresponding to the Fe K$\\alpha$ line and an outer annulus corresponding to the continuum, or vice-versa) we find microlensing events which enhance the Fe K$\\alpha$ line without noticeable amplification of the X-ray continuum, but only during a limited time interval. Continuum amplification is expected if a complete microlensing event is monitored. Second, we studied a more realistic case of amplification by caustic magnif...

  8. Extracting Vanadium from Stone Coal by a Cyclic Alkaline Leaching Method

    Science.gov (United States)

    Hu, Kailong; Liu, Xuheng; Li, Qinggang

    2017-01-01

    In order to achieve an efficient and economical approach on extracting vanadium from stone coal, a cyclic alkaline leaching method was studied in this work. The effects of operating parameters, including the NaOH concentration, temperature, reaction time, and liquid-solid ratio, on vanadium leaching efficiency were investigated. Also, we studied the influence of caustic soda dosage on the cyclic leaching process as well as the effect of increasing ionic strength in leachates and wash water. The results show that this method achieved a 51 pct decrease of the dosage of caustic soda under the optimized conditions compared with the single-step alkaline leaching. The average leaching yield of vanadium reached 82.28 pct. The leachates and wash water in each leaching cycle were utilized for the next leaching cycle, achieving the recycling of alkali as well as waste water. During the cyclic process, the volume of water was not increased, which markedly reduces the discharge of waste water and is also beneficial in terms of cost reduction.

  9. Corrosion leaking of preheater weldment in alumina factories

    Institute of Scientific and Technical Information of China (English)

    ZHANG Li; CHEN Wen-mi; GONG Zhu-qing; LIU Hong-zhao

    2005-01-01

    Stress corrosion cracking (SCC) and anticorrosion measures of TU42C weld-joint were studied by constant load experiments and pickling experiments. The results show that in 40%(mass fraction) NaOH solution at 110 ℃, caustic SCC occurs in TU42C weld-joints at the applied potential of -1 020 mV(vs SCE) for 3 d while at the potential of -950 mV(vs SCE) for 10 d. All the cracks are intergranular. In the 10% sulfuric acid, the cracks have the most negative self-corrosion potential -432.5 mV(vs SCE) and are active to be further corroded by the acid. Because of the same corrosion behaviour as the lab weldment, preheater's cracking in alumina factories is attributed to the combining actions of previous caustic SCC in Bayer solutions and continuous acid corrosion by pickling with the addition of RD. The following measures are effective to prevent the corrosion failure of preheater, such as postweld heat treatment at 620 ℃ to relax the residual weld stress, addition of CC3 and L826 as the corrosion inhibitors to improve the pickling and cleaning by the high pressure water instead of by pickling.

  10. On cosmological observables in a swiss-cheese universe

    CERN Document Server

    Marra, Valerio; Matarrese, Sabino; Riotto, Antonio

    2007-01-01

    Photon geodesics are calculated in a swiss-cheese model, where the cheese is made of the usual Friedmann-Robertson-Walker solution and the holes are constructed from a Lemaitre-Tolman-Bondi solution of Einstein's equations. The observables on which we focus are the changes in the redshift, in the angular-diameter--distance relation, in the luminosity-distance--redshift relation, and in the corresponding distance modulus. We find that redshift effects are suppressed when the hole is small because of a compensation effect acting on the scale of half a hole resulting from the special case of spherical symmetry. However, we find interesting effects in the calculation of the angular distance: strong evolution of the inhomogeneities (as in the approach to caustic formation) causes the photon path to deviate from that of the FRW case. Therefore, the inhomogeneities are able to partly mimic the effects of a dark-energy component. Our results also suggest that the nonlinear effects of caustic formation in cold dark ma...

  11. Cosmological observables in a Swiss-cheese universe

    Science.gov (United States)

    Marra, Valerio; Kolb, Edward W.; Matarrese, Sabino; Riotto, Antonio

    2007-12-01

    Photon geodesics are calculated in a Swiss-cheese model, where the cheese is made of the usual Friedmann-Robertson-Walker (FRW) solution and the holes are constructed from a Lemaître-Tolman-Bondi solution of Einstein’s equations. The observables on which we focus are the changes in the redshift, in the angular-diameter-distance relation, in the luminosity-distance-redshift relation, and in the corresponding distance modulus. We find that redshift effects are suppressed when the hole is small because of a compensation effect acting on the scale of half a hole resulting from the special case of spherical symmetry. However, we find interesting effects in the calculation of the angular distance: strong evolution of the inhomogeneities (as in the approach to caustic formation) causes the photon path to deviate from that of the FRW case. Therefore, the inhomogeneities are able to partly mimic the effects of a dark-energy component. Our results also suggest that the nonlinear effects of caustic formation in cold dark matter models may lead to interesting effects on photon trajectories.

  12. Separation of technetium from nuclear waste stream simulants. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Strauss, S.H. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Chemistry

    1995-09-11

    The author studied liquid anion exchangers, such as Aliquat-336 nitrate, various pyridinium nitrates, and related salts, so that they may be applied toward a specific process for extracting (partitioning) and recovering {sup 99}TcO{sub 4}{sup {minus}} from nuclear waste streams. Many of the waste streams are caustic and contain a variety of other ions. For this reason, the author studied waste stream simulants that are caustic and contain appropriate concentrations of selected, relevant ions. Methods of measuring the performance of the exchangers and extractant systems included contact experiments. Batch contact experiments were used to determine the forward and reverse extraction parameters as a function of temperature, contact time, phase ratio, concentration, solvent (diluent), and other physical properties. They were also used for stability and competition studies. Specifically, the author investigated the solvent extraction behavior of salts of perrhenate (ReO{sub 4}{sup {minus}}), a stable (non-radioactive) chemical surrogate for {sup 99}TcO{sub 4}{sup {minus}}. Results are discussed for alternate organic solvents; metalloporphyrins, ferrocenes, and N-cetyl pyridium nitrate as alternate extractant salts; electroactive polymers; and recovery of ReO{sub 4}{sup {minus}} and TcO{sub 4}{sup {minus}}.

  13. Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation

    Energy Technology Data Exchange (ETDEWEB)

    W Um; H Chang; J Icenhower; W Lukens; R Serne; N Qafoku; J Westsik Jr.; E Buck; S Smith

    2011-12-31

    During the nuclear waste vitrification process volatilized {sup 99}Tc will be trapped by melter off-gas scrubbers and then washed out into caustic solutions, and plans are currently being contemplated for the disposal of such secondary waste. Solutions containing pertechnetate [{sup 99}Tc(VII)O{sub 4}{sup -}] were mixed with precipitating goethite and dissolved Fe(II) to determine if an iron (oxy)hydroxide-based waste form can reduce Tc(VII) and isolate Tc(IV) from oxygen. The results of these experiments demonstrate that Fe(II) with goethite efficiently catalyzes the reduction of technetium in deionized water and complex solutions that mimic the chemical composition of caustic waste scrubber media. Identification of the phases, goethite + magnetite, was performed using XRD, SEM and TEM methods. Analyses of the Tc-bearing solid products by XAFS indicate that all of the Tc(VII) was reduced to Tc(IV) and that the latter is incorporated into goethite or magnetite as octahedral Tc(IV). Batch dissolution experiments, conducted under ambient oxidizing conditions for more than 180 days, demonstrated a very limited release of Tc to solution (2-7 {micro}g Tc/g solid). Incorporation of Tc(IV) into the goethite lattice thus provides significant advantages for limiting reoxidation and curtailing release of Tc disposed in nuclear waste repositories.

  14. Electro-osmotic-based catholyte production by Microbial Fuel Cells for carbon capture.

    Science.gov (United States)

    Gajda, Iwona; Greenman, John; Melhuish, Chris; Santoro, Carlo; Li, Baikun; Cristiani, Pierangela; Ieropoulos, Ioannis

    2015-12-01

    In Microbial Fuel Cells (MFCs), the recovery of water can be achieved with the help of both active (electro-osmosis), and passive (osmosis) transport pathways of electrolyte through the semi-permeable selective separator. The electrical current-dependent transport, results in cations and electro-osmotically dragged water molecules reaching the cathode. The present study reports on the production of catholyte on the surface of the cathode, which was achieved as a direct result of electricity generation using MFCs fed with wastewater, and employing Pt-free carbon based cathode electrodes. The highest pH levels (>13) of produced liquid were achieved by the MFCs with the activated carbon cathodes producing the highest power (309 μW). Caustic catholyte formation is presented in the context of beneficial cathode flooding and transport mechanisms, in an attempt to understand the effects of active and passive diffusion. Active transport was dominant under closed circuit conditions and showed a linear correlation with power performance, whereas osmotic (passive) transport was governing the passive flux of liquid in open circuit conditions. Caustic catholyte was mineralised to a mixture of carbonate and bicarbonate salts (trona) thus demonstrating an active carbon capture mechanism as a result of the MFC energy-generating performance. Carbon capture would be valuable for establishing a carbon negative economy and environmental sustainability of the wastewater treatment process.

  15. Simulations of Strong Gravitational Lensing with Substructure

    CERN Document Server

    Amara, A; Cox, T J; Ostriker, J P; Amara, Adam; Cox, Thomas J.; Ostriker, Jeremiah P.

    2004-01-01

    Galactic sized gravitational lenses are simulated by combining a cosmological N-body simulation and models for the baryonic component of the galaxy. The lens caustics, critical curves, image locations and magnification ratios are calculated by ray-shooting on an adaptive grid. It is found that the simulations do not cause the observed number of violations of the cusp caustic magnification relation. A part of this may be due to an insufficient amount of substructure but even for unsmoothed simulations (with maximal substructure) the factor of three increase in the number of violations still did not match the data. This suggests that other factors play an important role. These may include lensing by structure outside the halo, selection bias and the possibility that a randomly selected galaxy halo may be more irregular, for example due to recent mergers, than the isolated halo used in this study. It is also shown that, with the computed level of substructure, the image magnifications of the Einstein cross type ...

  16. Dyeing of Organic Cotton Fabric using Conventional and Ultrasonic Exhaust Dyeing Method

    Directory of Open Access Journals (Sweden)

    Uzma Syed

    2013-04-01

    Full Text Available In this research dyeing behavior of organic cotton woven fabric using ultrasonic technique and conventional dyeing method has been compared. The fabric samples were dyed with reactive dyes Drimarene Red Cl-5B and Drimarene Blue Cl-BR (0.5% owf using exhaust dyeing method. The samples were ultrasonically dyed at varied temperature (60, 50 and 40oC for 60, 50, 40 and 30 minutes and for conventional method at varied temperature but at recommended time, 60 minutes. For optimizing the dyeing behavior, the samples were causticized by pad-batch method and then dyed with ultrasonic technique at varied temperature and time. It has been observed organic cotton fabric dyed using ultrasonic exhaust method at 60oC for 50 minutes gives highest (K/S?max value, excellent fastness property, deeper dye diffusion and less surface deterioration compared to the conventional dyeing method. Moreover, causticized and dyed sample with ultrasonic technique at 60oC for 30 minutes gives colour strength value almost equal to the conventional recommended dyeing method. Hence, dyeing of organic material using ultrasonic exhaust method saves energy and time

  17. Recovering limonite from Australia iron ores by flocculation-high intensity magnetic separation

    Institute of Scientific and Technical Information of China (English)

    LUO Li-qun; ZHANG Jing-sheng; YU Yong-fu

    2005-01-01

    Successful recovery of limonite from iron fines was achieved by using flocculation-high intensity magnetic separation (FIMS) and adding hydrolyzed and causticized flocculants according to the characteristic of iron fines. The separation results of the three iron samples are as follows: iron grade 66.77%-67.98% and the recovery of iron 69.26%-70.70% by the FIMS process with flocculants. The comparative results show that under the same separation conditions the FIMS process can effectively increase the recovery of iron by 10.97%-15.73%. The flowsheet results confirm the reliability of the process in a SHP high intensity magnetic separator. The concentrate product can be used as raw materials for direct reduction iron-smelting. The hydrolyzed and causticized flocculants can selectively flocculate fine feebly-magnetic iron mineral particles to increase their apparent separation sizes. The larger the separation size, the stronger the magnetic force. By comparing the separation results of the three samples it is found that among the three samples the higher the limonite content, the better the separation result. This means that the separation result relates closely to the flocculation process and the adding pattern of the flocculant.

  18. Penetration through a wall: Is it reality?

    CERN Document Server

    Ivlev, B

    2011-01-01

    A tennis ball is not expected to penetrate through a brick wall since a motion under a barrier is impossible in classical mechanics. With quantum effects a motion of a particle through a barrier is allowed due to quantum tunneling. According to usual theories of tunneling, the particle density decays inside a classical barrier resulting in an extremely slow pentration process. However, there are no general laws forbidding fast motion through classical barriers. The problem addressed is investigation of unusual features o quantum tunneling through a classic static barrier which is at least two-dimensional. Here we show that penetration through such barrier can be not slow. When the barrier satisfies the certain conditions, a regime of quantum lens is possible with formation of caustics. De Broglie waves are reflected from the caustics, interfere, and result in a not small flux from under the barrier. This strongly contrasts to the usual scenario with a decaying under-barrier density. We construct a particular ...

  19. Chemicals for enhanced oil recovery. Quarterly report, October 1-December 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, J.S. Jr.

    1980-10-01

    Studies on the salinity range in which three liquid phases are observed for systems containing a tall oil ethoxylate or related nonionic surfactant, a cosurfactant, aqueous NaCl, and a hydrocarbon were extended. Increasing hydrophile-lipophile balance, HLB, causes an increase in the salinity needed to effect the transition of the surfactant from the lower to the upper phase. However, other factors besides HLB seem to be involved. Addition of the nonionic surfactant increases optimal salinity by an amount which depends on its hydrophilic character. Sodium-2-methyloleate,-2-butyloleate, -2-hexyloleate, -2,2-dimethyloleate, and -2,2-diethyloleate were synthesized and its phase behavior in aqueous/hydrocarbon systems studied. Adsorption of a commercial petroleum sulfonate from 0.1 M NaCl on the sodium form of montmorillonite was reduced a factor of ten by caustic extract from bleaching of wood pulp. In a comparison of several pulping wastes or byproducts as sacrificial agents, caustic extract and weak black liquor appeared most effective, and lignosulfonate only slightly less effective. Plugging tests of the filtrates obtained in the biomass-polymer separations indicated that polish filtration probably would be required. The microscreen is the most economical of the biomass separation methods. Small fermenter tests indicate that Sclerotium rolfsii cultures are able to tolerate salinity of 2 to 4% w/v NaCl in the fermentation broth makeup water; however, the organism was unable to grow in 6% w/v NaCl.

  20. An Alternative to Clay in Building Materials: Red Mud Sintering Using Fly Ash via Taguchi’s Methodology

    Directory of Open Access Journals (Sweden)

    Suchita Rai

    2013-01-01

    Full Text Available “Red mud” or “bauxite residue” is a highly alkaline waste generated from alumina refinery with a pH of 10.5–12.5 which poses serious environmental problems. Neutralization or its treatment by sintering in presence of additives is one of the methods for overcoming the caustic problem as it fixes nearly all the leachable free caustic soda present in red mud. In the present study, feasibility of reducing the alkaline nature of red mud by sintering using fly ash as an additive via Taguchi methodology and its use for brick production, as an alternative to clay, is investigated. The analysis of variance (ANOVA shows that sintering temperature is the most significant parameter in the process. A pH of 8.9 was obtained at 25–50% of red mud and 50–75% fly ash with water and temperature of . Alternatively 50% of red mud can be mixed with 50% of fly ash with water at temperature of to get a pH of about 8.4. The mechanism of this process has been explained with also emphasis on chemical, mineralogical, and morphological analysis of the sintered red mud. The results would be extremely useful in utilization of red mud in building and construction industry.

  1. Phosphorus Recovery from Ashes of Sewage Sludge

    Energy Technology Data Exchange (ETDEWEB)

    Cornel, Peter; Schaum, Peter

    2003-07-01

    About 90% of the incoming phosphorus load of waste water is eliminated by waste water treatment and transferred into the sewage sludge. Considerable amounts of sewage sludge can not be used agriculturally but are incinerated. Thus the ash from mono sludge incineration plants contains significant amounts of phosphorus (up to 25% P{sub 2}O{sub 5}) and could be used as raw material in fertilizer industry. The ash is hygienically harmless and free of organic substances. The ratio of phosphorus to heavy metals is basically the same as in the sewage sludge. The first step in separating phosphorus from heavy metals is to dissolve phosphorus by extraction. The most promising way seems to be the release of phosphorus with acids or bases. With 1 m sulphuric acid it is possible to release phosphorus completely. By use of acid most of the heavy metals dissolve, too. With caustic soda as solvent, only 30-40% of the phosphorus can be dissolved but the eluate is almost free of heavy metals. The amount of phosphorus which can be released with caustic soda, depends on the applied precipitant (Al or Fe salts) for phosphorus elimination at the waste water treatment. (author)

  2. Rare earth elements recycling from waste phosphor by dual hydrochloric acid dissolution.

    Science.gov (United States)

    Liu, Hu; Zhang, Shengen; Pan, Dean; Tian, Jianjun; Yang, Min; Wu, Maolin; Volinsky, Alex A

    2014-05-15

    This paper is a comparative study of recycling rare earth elements from waste phosphor, which focuses on the leaching rate and the technical principle. The traditional and dual dissolution by hydrochloric acid (DHA) methods were compared. The method of dual dissolution by hydrochloric acid has been developed. The Red rare earth phosphor (Y0.95Eu0.05)2O3 in waste phosphor is dissolved during the first step of acid leaching, while the Green phosphor (Ce0.67Tb0.33MgAl11O19) and the Blue phosphor (Ba0.9Eu0.1MgAl10O17) mixed with caustic soda are obtained by alkali sintering. The excess caustic soda and NaAlO2 are removed by washing. The insoluble matter is leached by the hydrochloric acid, followed by solvent extraction and precipitation (the DHA method). In comparison, the total leaching rate of the rare earth elements was 94.6% by DHA, which is much higher than 42.08% achieved by the traditional method. The leaching rate of Y, Eu, Ce and Tb reached 94.6%, 99.05%, 71.45%, and 76.22%, respectively. DHA can decrease the consumption of chemicals and energy. The suggested DHA method is feasible for industrial applications.

  3. Measuring the Innermost Stable Circular Orbits of Supermassive Black Holes

    Science.gov (United States)

    Chartas, G.; Krawczynski, H.; Zalesky, L.; Kochanek, C. S.; Dai, X.; Morgan, C. W.; Mosquera, A.

    2017-03-01

    We present a promising new technique, the g-distribution method, for measuring the inclination angle (i), the innermost stable circular orbit (ISCO), and the spin of a supermassive black hole. The g-distribution method uses measurements of the energy shifts in the relativistic iron line emitted by the accretion disk of a supermassive black hole due to microlensing by stars in a foreground galaxy relative to the g-distribution shifts predicted from microlensing caustic calculations. We apply the method to the gravitationally lensed quasars RX J1131–1231 (z s = 0.658, z l = 0.295), QJ 0158–4325 (z s = 1.294, z l = 0.317), and SDSS 1004+4112 (z s = 1.734, z l = 0.68). For RX J1131‑1231, our initial results indicate that r ISCO ≲ 8.5 gravitational radii (r g) and i ≳ 55° (99% confidence level). We detect two shifted Fe lines in several observations, as predicted in our numerical simulations of caustic crossings. The current ΔE distribution of RX J1131–1231 is sparsely sampled, but further X-ray monitoring of RX J1131–1231 and other lensed quasars will provide improved constraints on the inclination angles, ISCO radii, and spins of the black holes of distant quasars.

  4. Evaluation of Foaming and Antifoam Effectiveness During the WTP Oxidative Leaching Process

    Energy Technology Data Exchange (ETDEWEB)

    Burket, P. R.; Jones, T. M.; White, T. L.; Crawford, C. L.; Calloway, T. B

    2005-10-11

    The River Protection Project-Waste Treatment Plant (RPP-WTP) requested Savannah River National Laboratory (SRNL) to conduct small-scale foaming and antifoam testing using a Hanford waste simulant subjected to air sparging during oxidative leaching. The foaminess of Hanford tank waste solutions was previously demonstrated by SRNL during WTP evaporator foaming studies and in small scale air sparger studies. The commercial antifoam, Dow Corning Q2-3183A was recommended to mitigate the foam in the evaporators and in vessel equipped with pulse jet mixers and air spargers. Currently, WTP is planning to use air spargers in the HLW Lag Storage Vessels (HLP-VSL-00027A/B), the Ultrafiltration Vessels (UFP-VSL-00002A&B), and the HLW Feed Blend Vessel (HLPVSL-00028) to assist the performance of the Pulse Jet Mixers (PJM). The previous air sparger antifoam studies conducted by SRNL researchers did not evaluate the hydrogen generation rate expected from antifoam additions or the effectiveness of the antifoam during caustic leaching or oxidative leaching. The fate of the various antifoam components and breakdown products in the WTP process under prototypic process conditions (temperature & radiation) was also not investigated. The effectiveness of the antifoam during caustic leaching, expected hydrogen generation rate associated with antifoam addition, and the fate of various antifoam components are being conducted under separate SRNL research tasks.

  5. Probing the dynamical and X-ray mass proxies of the cluster of galaxies Abell S1101

    CERN Document Server

    Rabitz, Andreas; Schwope, Axel; Verdugo, Miguel; Reiprich, Thomas H; Klein, Matthias

    2016-01-01

    Context: The galaxy cluster Abell S1101 (S1101 hereafter) deviates significantly from the X-ray luminosity versus velocity dispersion relation (L-sigma) of galaxy clusters in our previous study. Given reliable X-ray luminosity measurement combining XMM-Newton and ROSAT, this could most likely be caused by the bias in the velocity dispersion due to interlopers and low member statistic in the previous sample of member galaxies, which was solely based on 20 galaxy redshifts drawn from the literature. Aims: We intend to increase the galaxy member statistic to perform a precision measurement of the velocity dispersion and dynamical mass of S1101. We aim for a detailed substructure and dynamical state characterization of this cluster, and a comparison of mass estimates derived from (i) the velocity dispersion (M_vir), (ii) the caustic mass computation (M_caustic), and (iii) mass proxies from X-ray observations and the Sunyaev-Zeldovich (SZ) effect. Methods: We carried out new optical spectroscopic observations of t...

  6. Temporal frequency probing for 5D transient analysis of global light transport

    KAUST Repository

    O'Toole, Matthew

    2014-07-27

    We analyze light propagation in an unknown scene using projectors and cameras that operate at transient timescales. In this new photography regime, the projector emits a spatio-temporal 3D signal and the camera receives a transformed version of it, determined by the set of all light transport paths through the scene and the time delays they induce. The underlying 3D-to-3D transformation encodes scene geometry and global transport in great detail, but individual transport components (e.g., direct reflections, inter-reflections, caustics, etc.) are coupled nontrivially in both space and time. To overcome this complexity, we observe that transient light transport is always separable in the temporal frequency domain. This makes it possible to analyze transient transport one temporal frequency at a time by trivially adapting techniques from conventional projector-to-camera transport. We use this idea in a prototype that offers three never-seen-before abilities: (1) acquiring time-of-flight depth images that are robust to general indirect transport, such as interreflections and caustics; (2) distinguishing between direct views of objects and their mirror reflection; and (3) using a photonic mixer device to capture sharp, evolving wavefronts of "light-in-flight".

  7. Ionospheric heating with oblique HF waves

    Science.gov (United States)

    Field, Edward C., Jr.; Bloom, Ron M.

    1990-10-01

    Calculations of ionospheric electron density perturbations and ground-level signal changes produce by intense oblique high frequency (HF) transmitters are presented. This analysis considers radio field focusing at caustics, the consequent joule-heating of the surrounding plasma, heat conduction, diffusion, and recombination processes: these being the effects of a powerful oblique 'modifying' wave. It neglects whatever plasma instabilities might occur. Then effects on a secondary 'test' wave that is propagated along the same path as the first are investigated. Calculations predict ground-level field-strength reductions of several dB in the test wave for modifying waves having ERP in the 85 to 90 dBW range. These field-strength changes are similar in sign, magnitude, and location to ones measured in Soviet experiments. The results are sensitive to the model ionosphere assumed, so future experiments should employ the widest possible range of frequencies and propagation conditions. An effective power of 90 dBW seems to be a sort of threshold that, if exceeded, results in substantial rather than small signal changes. The conclusions are based solely on joule-heating and subsequent defocusing of waves passing through caustic regions.

  8. Radio and Gamma-Ray Constraints on the Emission Geometry and Birthplace of PSR J2043+2740

    CERN Document Server

    Noutsos, A; Ackermann, M; Ajello, M; Ballet, J; Barbiellini, G; Baring, M G; Bastieri, D; Bechtol, K; Bellazzini, R; Berenji, B; Bonamente, E; Borgland, A W; Bregeon, J; Brez, A; Brigida, M; Bruel, P; Buehler, R; Busetto, G; Caliandro, G A; Cameron, R A; Camilo, F; Caraveo, P A; Casandjian, J M; Cecchi, C; Celik, O; Chaty, S; Chekhtman, A; Chiang, J; Ciprini, S; Claus, R; Cognard, I; Cohen-Tanugi, J; Colafrancesco, S; Cutini, S; Dermer, C D; de Palma, F; Drell, P S; Dumora, D; Espinoza, C M; Favuzzi, C; Ferrara, E C; Focke, W B; Frailis, M; Freire, P C C; Fukazawa, Y; Funk, S; Fusco, P; Gargano, F; Germani, S; Giglietto, N; Giordano, F; Giroletti, M; Godfrey, G; Grandi, P; Grenier, I A; Grove, J E; Guillemot, L; Guiriec, S; Harding, A K; Hughes, R E; Jackson, M S; Johannesson, G; Johnson, A S; Johnson, T J; Johnson, W N; Johnston, S; Kamae, T; Katagiri, H; Kataoka, J; Knoedlseder, J; Kramer, M; Kuss, M; Lande, J; Lee, S -H; Longo, F; Loparco, F; Lovellette, M N; Lubrano, P; Lyne, A G; Makeev, A; Marelli, M; Mazziotta, M N; McEnery, J E; Mehault, J; Michelson, P F; Mizuno, T; Monte, C; Monzani, M E; Morselli, A; Moskalenko, I V; Murgia, S; Naumann-Godo, M; Nolan, P L; Nuss, E; Ohsugi, T; Okumura, A; Omodei, N; Orlando, E; Ormes, J F; Panetta, J H; Parent, D; Pelassa, V; Pepe, M; Persic, M; Pesce-Rollins, M; Piron, F; Porter, T A; Rain, S; Ray, P S; Razzano, M; Reimer, A; Reimer, O; Reposeur, T; Romani, R W; Sadrozinski, H F -W; Sander, A; Parkinson, P M Saz; Sgro, C; Siskind, E J; Smith, D A; Smith, P D; Spandre, G; Spinelli, P; Stappers, B W; Strickman, M S; Suson, D J; Takahashi, H; Tanaka, T; Theureau, G; Thompson, D J; Thorsett, S E; Tibolla, O; Torres, D F; Tramacere, A; Usher, T L; Vandenbroucke, J; Vianello, G; Vilchez, N; Villata, M; Vitale, V; von Kienlin, A; Waite, A P; Wang, P; Watters, K; Weltevrede, P; Winer, B L; Wood, K S; Ziegler, M

    2010-01-01

    We report on the first year of Fermi gamma-ray observations of pulsed high-energy emission from the old PSR J2043+2740. The study of the gamma-ray efficiency of such old pulsars gives us an insight into the evolution of pulsars' ability to emit in gammma rays as they age. The gamma-ray lightcurve of this pulsar above 0.1 GeV is clearly defined by two sharp peaks, 0.353+/-0.035 periods apart. We have combined the gamma-ray profile characteristics of PSR J2043+2740 with the geometrical properties of the pulsar's radio emission, derived from radio polarization data, and constrained the pulsar-beam geometry in the framework of a Two Pole Caustic and an Outer Gap model. The ranges of magnetic inclination and viewing angle were determined to be {alpha,zeta}~{52-57,61-68} for the Two Pole Caustic model, and {alpha,zeta}~{62-73,74-81} and {alpha,zeta}~{72-83,60-75} for the Outer Gap model. Based on this geometry, we assess possible birth locations for this pulsar and derive a likely proper motion, sufficiently high t...

  9. Hydrodynamic simulations of the growth of cosmological structure summary and comparisons among scenarios

    CERN Document Server

    Ostriker, J P; Ostriker, Jeremiah P; Cen, Renyue

    1996-01-01

    We compute, including a current state-of-the-art treatment of hydrodynamical processes, heating and cooling, a variety of cosmological models into the extreme nonlinear phase to enable comparisons with observations. First, we note the common, model independent results. All have a mean (z=0) temperature of 10^{4.5}-10^{5.5}\\Kel, set essentially by photoheating processes. Most gas is in one of two components: either at the photoheating floor 10^{4.5}\\Kel and primarily in low density regions or else shock heated to 10^5-10^6\\Kel and in regions of moderate overdensity (in caustics and near groups and clusters). It presents a major observational challenge to observationally detect this second, abundant component as it is neither an efficient radiator nor absorber. About 2\\% to 10\\% of the baryons cool and collapse into galaxies forming on caustics and migrating to clusters. About 1\\%-2\\% of baryons are in the very hot X-ray emitting gas near cluster cores, in good agreement with observations. These correspondances...

  10. SUPPLEMENTAL ANALYSES FOR SOLVENT HOLD TANK SAMPLES MCU-11-314, MCU-11-315, MCU-11-316, MCU-11-317, MCU-11-318 AND MCU-11-319

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T.; Washington, A; . Fondeur, F.; Fink, S.

    2011-09-29

    Savannah River National Laboratory (SRNL) periodically analyses solvent samples from Modular Caustic-Side Solvent Extraction Unit (MCU) in support of continuing operations. A quarterly analysis of the solvent is required to maintain solvent composition within specifications. Analytical results of the analyses of Solvent Hold Tank (SHT) samples MCU-11-314, MCU-11-315, MCU-11-316, MCU-11-317, MCU-11-318 and MCU-11-319 have been previously reported. MCU has experienced a modest decline in cesium removal efficiency while processing the current feed, 'Macrobatch 3'. While the target decontamination factor (DF) is 200, the fiscal year 2011 DF average is 161. The results of the prior solvent analysis report did not identify a specific factor that would correlate with the poor cesium decontamination beyond a low concentration of the suppressor, trioctylamine. New analyses of the quarterly sample are reported in this document, as well as a cross-check of {sup 137}Cs measurements for SRNL and F/H lab. Furthermore, in an attempt to discover the reason for the decline in DF at MCU, SRNL was tasked with analyzing numerous Caustic Wash Tank (CWT) and chemical feed samples.

  11. 亚麻/棉混纺针织物的丝光工艺优化%Mercerizing Process Optimization of Linen/Cotton Knitted Fabric

    Institute of Scientific and Technical Information of China (English)

    汤根娣; 龙海如

    2012-01-01

    The orthogonal experiment was conducted to determine the optimal mercerizing process of 45/55 linen/cotton 19. 7 tex knitted fabric using concentration of caustic soda, processing time and tension as mercerizing factor and loss rate of bursting strength, adsorption of barium value, shrinkage and flexural stiffness as evaluation index. The caustic soda concentration of 135 g/L, processing time of 45 s and tension of 2% were the optimal mercerizing process.%为确定亚麻/棉(45/55)19.7tex混纺针织物丝光处理的最佳工艺,以烧碱浓度、处理时间和张力三个因素作因子进行正交试验,以顶破强力损失率、吸附钡值、缩水率和抗弯刚度为评价指标,优化出了最佳工艺条件为烧碱浓度135g/n,时间45S,张力2%。

  12. Solution of the equations for one-dimensional, two-phase, immiscible flow by geometric methods

    Science.gov (United States)

    Ivan, Boronin; Andrey, Shevlyakov

    2016-12-01

    Buckley-Leverett equations describe non viscous, immiscible, two-phase filtration, which is often of interest in modelling of oil production. For many parameters and initial conditions, the solutions of these equations exhibit non-smooth behaviour, namely discontinuities in form of shock waves. In this paper we obtain a novel method for the solution of Buckley-Leverett equations, which is based on geometry of differential equations. This method is fast, accurate, stable, and describes non-smooth phenomena. The main idea of the method is that classic discontinuous solutions correspond to the continuous surfaces in the space of jets - the so-called multi-valued solutions (Bocharov et al., Symmetries and conservation laws for differential equations of mathematical physics. American Mathematical Society, Providence, 1998). A mapping of multi-valued solutions from the jet space onto the plane of the independent variables is constructed. This mapping is not one-to-one, and its singular points form a curve on the plane of the independent variables, which is called the caustic. The real shock occurs at the points close to the caustic and is determined by the Rankine-Hugoniot conditions.

  13. IMPROVED ANTIFOAM AGENT STUDY END OF YEAR REPORT, EM PROJECT 3.2.3

    Energy Technology Data Exchange (ETDEWEB)

    Lambert, D.; Koopman, D.; Newell, J.

    2011-09-30

    Antifoam 747 is added to minimize foam produced by process gases and water vapor during chemical processing of sludge in the Defense Waste Processing Facility (DWPF). This allows DWPF to maximize acid addition and evaporation rates to minimize the cycle time in the Chemical Processing Cell (CPC). Improvements in DWPF melt rate due to the addition of bubblers in the melter have resulted in the need for further reductions in cycle time in the CPC. This can only be accomplished with an effective antifoam agent. DWPF production was suspended on March 22, 2011 as the result of a Flammable Gas New Information/(NI) Potential Inadequacy in the Safety Analysis (PISA). The issue was that the DWPF melter offgas flammability strategy did not take into account the H and C in the antifoam, potentially flammable components, in the melter feed. It was also determined the DWPF was using much more antifoam than anticipated due to a combination of longer processing in the CPC due to high Hg, longer processing due to Actinide Removal Process (ARP)/Modular Caustic Side Solvent Extraction Unit (MCU) additions, and adding more antifoam than recommended. The resolution to the PISA involved and assessment of the impact of the antifoam on melter flammability and the implementation of a strategy to control additions within acceptable levels. This led to the need to minimize the use of Antifoam 747 in processing beginning in May 2011. DWPF has had limited success in using Antifoam 747 in caustic processing. Since starting up the ARP facility, the ARP product (similar chemically to caustic sludge) is added to the Sludge Receipt and Adjustment Tank (SRAT) at boiling and evaporated to maintain a constant SRAT volume. Although there is very little offgas generated during caustic boiling, there is a large volume of water vapor produced which can lead to foaming. High additions and more frequent use of antifoam are used to mitigate the foaming during caustic boiling. The result of these three

  14. Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites

    Energy Technology Data Exchange (ETDEWEB)

    Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

    2009-03-02

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form

  15. Study on Three Cases of Corrosion Failures of Refinery Equipment%炼油厂设备腐蚀故障失效分析三例

    Institute of Scientific and Technical Information of China (English)

    孙亮; 黄梓友; 郑明光

    2012-01-01

    In the study of 3 corrosion failure cases of refinery equipment, i.e. corrosion leakage of recycle oil/crude oil heat exchanger in atmospheric - vacuum distillation unit overhead, failure of pipeline upstream of inlet mixer of caustic wash drum of reactor effluent of sulfuric acid alkylation unit and corrosion leakage of steam generator in gasoline and diesel hydrotreating unit, the causes of corrosion failures of refinery equipment were analyzed. The results demonstrated that, the corrosion leakage of atmospheric -vacuum distillation unit overhead recycle oil/crude oil heat exchanger was caused by tube side media (overhead recycle oil) ; The corrosion was the result of H20 - HC1 system produced by HC1 dew formation. The pipeline upstream of inlet mixer of caustic wash drum of reactor effluent of sulfuric acid alkylation unit failed because of accelerated flow velocity caused by Ca vaporization in the low - pressure zone in the mixing of reactor effluent and hot caustic water due to the inappropriate ways of caustic addition. In addition, the water in caustic liquid diluted the sulfuric acid carried over with the reactor effluent, leading to serious corrosion of 20 alloy steel. The leakage of steam generator in gasoline and diesel hydrotreating unit was mainly caused by shell side media, water or fabrication defects of connection of heat exchanger tubes and shell plates. Prevention measures are recommended based upon different corrosion conditions.%结合炼油厂常减压蒸馏装置顶循环油/原油换热器管束泄漏;硫酸烷基化单元反应流出物碱洗罐入口混合器前管段穿孔和汽柴油加氢精制单元柴油蒸汽发生器泄漏等三例设备腐蚀案例进行了失效原因分析。分析结果表明:常减压蒸馏装置顶循环油/原油换热器管束泄漏由管程介质即顸循环引起,为HCl结露产生的H,0-HCl体系腐蚀所致;硫酸烷基化单元反应流出物碱洗罐入口混合器前管段穿孔由

  16. EFRT M-12 Issue Resolution: Solids Washing

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, David L.; Schonewill, Philip P.; Toth, James J.; Huckaby, James L.; Eslinger, Paul W.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2009-08-14

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. Two operating scenarios were evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-VSL-T01A/B ultrafiltration feed vessels, identified as Integrated Test A. The second scenario has caustic leaching conducted in the UFP-VSL-T02A ultrafiltration feed preparation vessel, identified as Integrated Test B. Washing operations in PEP Integrated Tests A and B were conducted successfully as per the approved run sheets. However, various minor instrumental problems occurred, and some of the process conditions specified in the run sheet were not met during the wash operations, such as filter-loop flow-rate targets not being met. Five analytes were selected based on full solubility and monitored in the post-caustic-leach wash as successful indicators of washing efficiency. These were aluminum, sulfate, nitrate, nitrite, and free hydroxide. Other analytes, including sodium, oxalate, phosphate, and total dissolved solids, showed indications of changing solubility; therefore, they were unsuitable for monitoring washing efficiency. In the post-oxidative-leach wash, two analytes with full solubility were selected as suitable indicators of washing

  17. 硼化物陶瓷基涂层制备技术的研究进展%Research Progress of Preparation Technology on the Boride Ceramic-based Coating

    Institute of Scientific and Technical Information of China (English)

    贾成科; 张鑫; 任先京; 冀晓鹃; 彭浩然

    2012-01-01

    Boride cermet is a new cermet with many excellent properties such as high melting temperature, bulk hardness, high chemical stability, high wearable property, and good anti-causticity, which is used in the fields such as fire-resistant material, engineering cermet, nuclear industry, and space navigation. The same excellent properties of the boride ceramic based coating prepared by many kinds of techniques, which are play important roles in many fields such as ultra high-temperature components, high wearable property units,good anti-causticity parts, anti-liquid metal-causticity component, and neutron-ratiant guard etc. The preparation methods of the boride ceramic- based coating with the strongpoint and disadvantage are introduced. The advances and the application of boride ceramic- based coating, mostly including duality boride ceramic based coatings and ternary ones, are also summarized as well as the existing problems and the prospects are analyzed.%硼化物陶瓷是一种新型陶瓷材料,具有诸如高熔点、高硬度、高化学稳定性以及高耐磨、抗腐蚀性等优异的综合性能,在耐火材料、工程陶瓷、核工业、宇航等领域有着广泛应用,而通过多种工艺制备的硼化物陶瓷基涂层同样具有很好的性质和功能,这些优异的特性使得目前硼化物涂层在很多工程领域发挥着极其重要的作用,如超高温部件、高耐磨蚀性部件以及抗金属液腐蚀性的部件、中子辐射防护装置等。本文介绍了硼化物陶瓷基涂层的制备方法,指出了各种方法的优缺点,综述了硼化物陶瓷基涂层的研究进展及其涂层的应用情况,主要包括二元硼化物陶瓷基涂层、多元硼化物基金属涂层等,总结了目前该领域存在的问题,并对今后的发展前景进行了展望。

  18. High frequency asymptotic solutions of the reduced wave equation on infinite regions with non-convex boundaries

    Directory of Open Access Journals (Sweden)

    Bloom Clifford O.

    1996-01-01

    Full Text Available The asymptotic behavior as λ → ∞ of the function U ( x , λ that satisfies the reduced wave equation L λ [ U ] = ∇ ⋅ ( E ( x ∇ U + λ 2 N 2 ( x U = 0 on an infinite 3-dimensional region, a Dirichlet condition on ∂ V , and an outgoing radiation condition is investigated. A function U N ( x , λ is constructed that is a global approximate solution as λ → ∞ of the problem satisfied by U ( x , λ . An estimate for W N ( x , λ = U ( x , λ − U N ( x , λ on V is obtained, which implies that U N ( x , λ is a uniform asymptotic approximation of U ( x , λ as λ → ∞ , with an error that tends to zero as rapidly as λ − N ( N = 1 , 2 , 3 , ... . This is done by applying a priori estimates of the function W N ( x , λ in terms of its boundary values, and the L 2 norm of r L λ [ W N ( x , λ ] on V . It is assumed that E ( x , N ( x , ∂ V and the boundary data are smooth, that E ( x − I and N ( x − 1 tend to zero algebraically fast as r → ∞ , and finally that E ( x and N ( x are slowly varying; ∂ V may be finite or infinite. The solution U ( x , λ can be interpreted as a scalar potential of a high frequency acoustic or electromagnetic field radiating from the boundary of an impenetrable object of general shape. The energy of the field propagates through an inhomogeneous, anisotropic medium; the rays along which it propagates may form caustics. The approximate solution (potential derived in this paper is defined on and in a neighborhood of any such caustic, and can be used to connect local “geometrical optics” type approximate solutions that hold on caustic free subsets of V .The result of this paper generalizes previous work of Bloom and Kazarinoff [C. O. BLOOM and N. D. KAZARINOFF, Short Wave Radiation Problems in Inhomogeneous Media: Asymptotic Solutions, SPRINGER VERLAG, NEW YORK, NY, 1976].

  19. Study on Technological Characteristic of Process of Calcining and Decomposing Dolomite Ore%白云石煅烧离解过程的工艺特性研究

    Institute of Scientific and Technical Information of China (English)

    蒋述兴

    2011-01-01

    对不同温度下煅烧成的苛性白云石进行了X射线粉晶分析,结合热分析结果,得出在750~800℃温度下煅烧成的苛性白云石镁质胶凝材料,其中的Mgo水化活性较大.在煅烧白云石的过程中,是结晶--化学反应为限制步骤,因此,要尽可能创设条件,加速化学反应的进行,并要尽可能控制好煅烧时间,以便抑制氧化镁的完全结晶.另外,分析计算了在利用临桂县白云石生产苛性白云石镁质胶凝材料时,不同粒度(5~250mm的多种粒度)的块状白云石在不同温度下完全离解所需要的煅烧时间.%The work of the XRD of the caustic dolomite prepared by different calcining temperatures had been done.According to the results of the XRD and DTA of the dolomite in the atmosphere of the CO2, we reached a conclusion that the MgO of the magnesia cementitious material of the caustic dolomite calcined at the temperature condition from 750℃ to 800℃ possessed larger hydration activity. In the process of calcining and decomposing the dolomite ore, the restrictive step was the crystallization and chemical reaction. The condition to quicken the chemical reaction should be consequently created as far as possible, and the calcining time should be controlled as far as possible to restrain the complete crystallization of the MgO in the caustic dolomite. In addition,the required calcining times to fully decompose the MgCOj in the big lump dolomites which were the paticles from 5mm to 250 mm had been obtained by the methods of the experiments,analysis and computations.

  20. CoMaLit - II. The scaling relation between mass and Sunyaev-Zel'dovich signal for Planck selected galaxy clusters

    CERN Document Server

    Sereno, Mauro; Moscardini, Lauro

    2014-01-01

    We discuss the scaling relation between mass and the integrated Compton parameter of a sample of galaxy clusters from the all-sky Planck Sunyaev-Zel'dovich catalogue. Masses were measured with either weak lensing, caustics techniques or assuming hydrostatic equilibrium. According to the calibration sample, the slope of the M_{500}-Y_{500} relation is 1.2-1.6, shallower than self-similar predictions, with an intrinsic scatter of 20+-10 per cent. The regression method employed accounts for intrinsic scatter in the mass measurements too. The absolute calibration of the relation is most difficult to ascertain due to systematic differences of ~ 20-40 per cent in mass estimates reported by separate groups. We find that Planck cluster mass estimates suffer from a mass dependent bias.