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Sample records for catalytic converter core

  1. Catalytic converter

    Energy Technology Data Exchange (ETDEWEB)

    Liber, B.

    1991-08-22

    A catalytic converter is provided which is economical to manufacture and is not readily poisoned by contaminants in a gas stream such as would be encountered in the operation of an internal combustion engine, whereby an improved life expectancy of the unit can be achieved. The converter of the invention comprises a sintered porous body including molybdenum or a molybdenum-containing compound or a molybdenum complex. A method of forming a catlytic converter unit comprises forming a slurry including molybdenum or a molybdenum compound, forming the slurry into a sintered body member, and hardening or curing the same to form a self-sustaining body member. A method for treating an exhaust gas using the above catalytic converter is also disclosed. A preferred embodiment for an internal combustion engine is described. Examples of different catalytic compositions are included. 13 figs.

  2. Catalytic converters as a source of platinum

    Directory of Open Access Journals (Sweden)

    A. Fornalczyk

    2011-10-01

    Full Text Available The increase of Platinum Group Metals demand in automotive industry is connected with growing amount of cars equipped with the catalytic converters. The paper presents the review of available technologies during recycling process. The possibility of removing platinum from the used catalytic converters applying pyrometallurgical and hyrdometallurgical methods were also investigated. Metals such as Cu, Pb, Ca, Mg, Cd were used in the pyrometallurgical research (catalytic converter was melted with Cu, Pb and Ca or Mg and Cd vapours were blown through the whole carrier. In hydrometallurgical research catalytic converters was dissolved in aqua regia. Analysis of Pt contents in the carrier before and after the process was performed by means of atomic absorption spectroscopy. Obtained result were discussed.

  3. Platinum recovery from used auto catalytic converters in electrorefining process

    Directory of Open Access Journals (Sweden)

    A. Fornalczyk

    2013-04-01

    Full Text Available This paper presents possibility of removing platinum from the used catalytic converters applying copper as a metal collector in pyrometallurgical methods. The catalytic converter carrier was grinded and melted with copper. During the research obtained Cu-Pt alloy was casted as an anode. Such anode was electrically refined in order to recover platinum. Obtained results were discussed.

  4. Use of Electrically Heated Metal Catalytic Converter in Cold Starting ...

    African Journals Online (AJOL)

    The easiest way to preheat the converter is to use electric resistance heaters. The electrical systems on most cars provide enough energy or power to heat the catalytic converter fast enough. So, in this research the main converter remains its usual position, whereas the heated catalyst is placed close to the exhaust manifold ...

  5. Advanced Catalytic Converter in Gasoline Enginer Emission Control: A Review

    OpenAIRE

    Leman A.M.; Jajuli Afiqah; Feriyanto Dafit; Rahman Fakhrurrazi; Zakaria Supaat

    2017-01-01

    Exhaust emission from automobile source has become a major contributor to the air pollution and environmental problem. Catalytic converter is found to be one of the most effective tools to reduce the overwhelming exhaust pollutants in our environment. The development of sustainable catalytic converter still remains a critical issue due to the stringent exhaust emission regulations. Another issue such as price and availability of the precious metal were also forced the automotive industry to i...

  6. Advanced Catalytic Converter in Gasoline Enginer Emission Control: A Review

    Directory of Open Access Journals (Sweden)

    Leman A.M.

    2017-01-01

    Full Text Available Exhaust emission from automobile source has become a major contributor to the air pollution and environmental problem. Catalytic converter is found to be one of the most effective tools to reduce the overwhelming exhaust pollutants in our environment. The development of sustainable catalytic converter still remains a critical issue due to the stringent exhaust emission regulations. Another issue such as price and availability of the precious metal were also forced the automotive industry to investigate the alternatives for producing a better replacement for the material used in catalytic converter. This paper aims at reviewing the present development and improvement on the catalytic converter used on the reduction of exhaust emission in order to meet the regulations and market demand. The use of new catalyst such as to replace the noble metal material of Platinum (Pt, Palladium (Pd and Rhodium (Rh has been reviewed. Material such as zeolite, nickel oxide and metal oxide has been found to effectively reduce the emission than the commercial converter. The preparation method of the catalyst has also evolved through the years as it is to ensure a good characteristic of a good monolith catalyst. Ultrasonic treatment with combination of electroplating technique, citrate method and Plasma Electrolytic Oxidation (PEO has been found as the latest novel preparation method on producing an effective catalyst in reducing the exhaust emission.

  7. Flow in axisymmetric expansion in a catalytic converter

    OpenAIRE

    Gotfredsen, Erik; Meyer, Knud Erik

    2017-01-01

    The flow in an axisymmetric expansion (circular diffusor) is used in many different engineering applications, such as heat exchangers, catalytic converters and filters. These applications require a relatively uniform flow at the inlet. To minimise the pressure loss, an ideal solution would be to use a quite long expansion, but this is often not possible due to space restrictions. Therefore a short expansion combined with e.g. guide vanes is often used. The present study will use a Selective C...

  8. The use of Phoenics in the design of catalytic converters

    Energy Technology Data Exchange (ETDEWEB)

    Luoma, M. [Kemira Metalkat Oy, Oulu (Finland); Smith, A.G. [S and C Thermofluids Ltd, Bath (United Kingdom)

    1996-12-31

    Manufacturers of automotive catalytic converters are constrained to design a system which is mechanically reliable, puts low back pressure on the engine, has adequate conversion performance, is low cost and of minimum size. In recent years, computational fluid dynamics (CFD) has been widely examined as a means of predicting the performance of catalytic converters to aid with the design process. Kemira Metalkat and S and C Thermofluids have put together and developed a number of existing CFD techniques in order to create a tool which is integrated within the design process. PHOENICS is used in the heart of the system in order to produce predictions of transient (light-off) and steady state catalyst performance. Grid generation tools have been provided to allow simplified and rapid geometry definition with suitable integration (via FEMGEN) within other parts of the catalyst design process. Simplified input techniques have been provided along with associated translators to create specification of the model for PHOENICS. Post-processing software has been provided through FEMVIEW to allow visualisation of catalyst monolith variables and transient performance animation. The whole system is controlled via a menu. The system have been use to study the effects of the catalyst design parameters on the converter performance. The results obtained using the system have so far been more qualitative than quantitative. However, validation studies have been carried out to check pressure drop prediction. A new model for the pressure drop over a metallic monolith has been developed. (author)

  9. Flow in axisymmetric expansion in a catalytic converter

    DEFF Research Database (Denmark)

    Gotfredsen, Erik; Meyer, Knud Erik

    is to investigate flow phenomena in sudden pipe expansions similar to design used for catalytic converters with different upstream conditions and flow conditioning devices like guide vanes. This is done to provide a set of data that can be used to validate the use of CFD to such flows. For the present study, a down...... for a specific local flow rate and a non-uniform inflow to the catalyst will severely reduce the efficiency of the process. Since each ship will have a unique design the flow system, it is desirable to be able to design the system using Computational Fluid Dynamics (CFD). However, CFD fails to predict flow...... Velocimetry (PIV) is a unique method that resolve the entire cross flow. This type of flow is expected to have a fluctuating ‘jet’-like structure from the smaller inlet pipe into the larger converter. The fluctuations of the jet are difficult, if not impossible, to capture with standard time averaged models...

  10. Retrofit catalytic converter for wood-burning stoves

    Energy Technology Data Exchange (ETDEWEB)

    None

    1983-01-01

    The major purpose of this project was to design, fabricate, test, and evaluate a retrofit catalytic converter for woodburning stoves. In the interim between our date of application March 5, 1981 and the beginning of the grant period December 1, 1981, several such devices became commercially available. Therefore, we decided to modify the purpose and direction of our project. In summary, we designed and constructed a calorimeter room in a building located on the campus of Northern Kentucky University. We equipped this room with a woodburning stove and a metal chimney extending through the roof. We designed and constructed the appropriate instrumentation for monitoring the heat output of the stove. We observed and recorded the operating characteristics of this stove over a period of several days. We then equipped the stove with a barometric damper and repeated the experiment. We are now in the process of equipping the stove with a catalytic converter. Thus the major emphasis of the project currently is to test and evaluate several commercial retrofit devices which are purported to reduce creosote and/or increase the efficiency of a woodburning stove.

  11. Simulation on Toxic Gases in Vehicle Exhaust Equipped with Modified Catalytic Converter : A Review

    Directory of Open Access Journals (Sweden)

    Leman A.M.

    2016-01-01

    Full Text Available Air pollution and global warming is a major issue nowadays. One of the main contributors to be the emission of harmful gases produced by vehicle exhausts lines. The harmful gases like NOx, CO, unburned HC and particulate matter increases the global warming, so catalytic converter plays a vital role in reducing harmful gases. Catalytic converters are used on most vehicles on the road today. This research deals with the gas emission flow in the catalytic converter involving the heat transfer, velocity flow, back pressure and others chemical reaction in the modified catalytic converter by using FeCrAl as a substrate that is treated using the ultrasonic bath and electroplating techniques. The objective of this study is to obtain a quantitative description of the gas emission in the catalytic converter system of automobile exhaust gas using ANSYS Software. The description of the gas emission in the catalytic converter system of automobile exhaust gas using ANSYS Software was simulated in this research in order to provide better efficiency and ease the reusability of the catalytic converter by comparing experimental data with software analysing data. The result will be expected to demonstrate a good approximation of gas emission in the modified catalytic converter simulation data compared to experimental data in order to verify the effectiveness of modified catalytic converter. Therefore studies on simulation of flow through the modified catalytic converter are very important to increase the accuracy of the obtained emission result.

  12. On the effects of flow pulsation upon the performance of flow deflector for catalytic converter

    National Research Council Canada - National Science Library

    HIRATA, Katsuya; TANAKA, Shinya; OTA, Masaya; INOUE, Taishi; OZAKI, Tomohiro; TANIGAWA, Hirochika

    2017-01-01

    ... catalytic-conversion efficiency. The authors have reported that a flow deflector placed inside a catalytic-converter diffuser part can drastically reduce the pressure loss and improve the velocity-profile uniformity in comparison...

  13. Moving core beam energy absorber and converter

    Science.gov (United States)

    Degtiarenko, Pavel V.

    2012-12-18

    A method and apparatus for the prevention of overheating of laser or particle beam impact zones through the use of a moving-in-the-coolant-flow arrangement for the energy absorbing core of the device. Moving of the core spreads the energy deposition in it in 1, 2, or 3 dimensions, thus increasing the effective cooling area of the device.

  14. Automated X-ray quality control of catalytic converters

    Science.gov (United States)

    Shashishekhar, N.; Veselitza, D.

    2017-02-01

    Catalytic converters are devices attached to the exhaust system of automobile or other engines to eliminate or substantially reduce polluting emissions. They consist of coated substrates enclosed in a stainless steel housing. The substrate is typically made of ceramic honeycombs; however stainless steel foil honeycombs are also used. The coating is usually a slurry of alumina, silica, rare earth oxides and platinum group metals. The slurry also known as the wash coat is applied to the substrate in two doses, one on each end of the substrate; in some cases multiple layers of coating are applied. X-ray imaging is used to inspect the applied coating depth on a substrate to confirm compliance with quality requirements. Automated image analysis techniques are employed to measure the coating depth from the X-ray image. Coating depth is assessed by analysis of attenuation line profiles in the image. Edge detection algorithms with noise reduction and outlier rejection are used to calculate the coating depth at a specified point along an attenuation line profile. Quality control of the product is accomplished using several attenuation line profile regions for coating depth measurements, with individual pass or fail criteria specified for each region.

  15. Potential for recovery of cerium contained in automotive catalytic converters

    Science.gov (United States)

    Bleiwas, Donald I.

    2013-01-01

    Catalytic converters (CATCONs) are required by Federal law to be installed in nearly all gasoline- and diesel-fueled onroad vehicles used in the United States. About 85 percent of the light-duty vehicles and trucks manufactured worldwide are equipped with CATCONs. Portions of the CATCONs (called monoliths) are recycled for their platinum-group metal (PGM) content and for the value of the stainless steel they contain. The cerium contained in the monoliths, however, is disposed of along with the slag produced from the recycling process. Although there is some smelter capacity in the United States to treat the monoliths in order to recover the PGMs, a great percentage of monoliths is exported to Europe and South Africa for recycling, and a lesser amount is exported to Japan. There is presently no commercial-scale capacity in place domestically to recover cerium from the monoliths. Recycling of cerium or cerium compounds from the monoliths could help ensure against possible global supply shortages by increasing the amount that is available in the supply chain as well as the number and geographic distribution of the suppliers. It could also reduce the amount of material that goes into landfills. Also, the additional supply could lower the price of the commodity. This report analyzes how much cerium oxide is contained in CATCONs and how much could be recovered from used CATCONs.

  16. Possibilities Of Metals Extracton From Spent Metallic Automotive Catalytic Converters By Using Biometallurgical Method

    Directory of Open Access Journals (Sweden)

    Willner J.

    2015-09-01

    Full Text Available The main task of automotive catalytic converters is reducing the amount of harmful components of exhaust gases. Metallic catalytic converters are an alternative to standard ceramic catalytic converters. Metallic carriers are usually made from FeCrAl steel, which is covered by a layer of Precious Group Metals (PGMs acting as a catalyst. There are many methods used for recovery of platinum from ceramic carriers in the world, but the issue of platinum and other metals recovery from metallic carriers is poorly described. The article presents results of preliminary experiments of metals biooxidation (Fe, Cr and Al from spent catalytic converters with metallic carrier, using bacteria of the Acidithiobacillus genus.

  17. The influence of platinum washing-out time on its recovery from used auto catalytic converters

    Directory of Open Access Journals (Sweden)

    A. Fornalczyk

    2014-07-01

    Full Text Available The used catalytic converters contain small amounts of precious metals. Recovery of these metals is essential for environmental and economic reasons. This work presents a method of Platinum Group Metals (PGM recovery from auto catalytic converters in which they are washed out by a liquid metal. The magneto-hydro-dynamic pump was used to force circulation of liquid metal under the influence of electromagnetic fields The influence of process time on platinum recovery was also carried out.

  18. Accurate Modeling of Buck Converters with Magnetic-Core Inductors

    DEFF Research Database (Denmark)

    Astorino, Antonio; Antonini, Giulio; Swaminathan, Madhavan

    2015-01-01

    In this paper, a modeling approach for buck converters with magnetic-core inductors is presented. Due to the high nonlinearity of magnetic materials, the frequency domain analysis of such circuits is not suitable for an accurate description of their behaviour. Hence, in this work, a timedomain mo...... hysteretic behavior to be thoroughly taken into account....

  19. A comparative evaluation on the emission characteristics of ceramic and metallic catalytic converter in internal combustion engine

    Science.gov (United States)

    Leman, A. M.; Jajuli, Afiqah; Rahman, Fakhrurrazi; Feriyanto, Dafit; Zakaria, Supaat

    2017-09-01

    Enforcement of a stricter regulation on exhaust emission by many countries has led to utilization of catalytic converter to reduce the harmful pollutant emission. Ceramic and metallic catalytic converters are the most common type of catalytic converter used. The purpose of this study is to evaluate the performance of the ceramic and metallic catalytic converter on its conversion efficiency using experimental measurement. Both catalysts were placed on a modified exhaust system equipped with a Mitshubishi 4G93 single cylinder petrol engine that was tested on an eddy current dynamometer under steady state conditions for several engine speeds. The experimental results show that the metallic catalytic converter reduced a higher percentage of CO up to 98.6% reduction emissions while ceramic catalytic converter had a better reduction efficiency of HC up to 85.4% and 87.2% reduction of NOx.

  20. Development and test of a new catalytic converter for natural gas ...

    Indian Academy of Sciences (India)

    nausea, increased hair loss, increased spontaneous abortion, dermatitis and other serious health problems in humans (Kielhorn et al 2002; Merget & Rosner 2001; Ravindra et al 2004;. Whitely & Murray 2003). In this investigation, a new type of catalytic converter based on CoO/TiO2 materials has been developed with wire ...

  1. Development of a model-based controller for a three-way catalytic converter

    NARCIS (Netherlands)

    Bie, T. de; Balenovic, M.; Backx, T.

    2002-01-01

    The performance of a three-way catalytic converter under transient operation can be improved by controlling the level of oxygen stored on ceria at some optimal level. A model-based controller with the model estimating the level of ceria coverage by oxygen, can achieve this goal. A simple, dynamic

  2. Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered Vehicles Flue Gas

    Directory of Open Access Journals (Sweden)

    Mohammad Nasikin

    2010-10-01

    Full Text Available Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel soot that can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension of catalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along the catalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic condition based on a kinetic study that has been  reported previously. Calculation of developed equations in this model uses Polymath 5.X solver with Range Kutta Method. The simulation result shows that temperature profile along catalytic converter increases with the decrease of soot weight,  while pressure profile decreases. The increase of soot weight in entering gas increases the needed converter length. On the other hand, the increase of catalyst diameter does not affect to soot weight along converter and temperature profile, but results a less pressure drop. For 2.500 c diesel engine, packed bed catalytic converter with ellipse's cross sectional of 14,5X7,5 cm diagonal and 0,8 cm catalyst particle diameter, needs 4,1 cm length.

  3. Using heat pipe to make isotherm condition in catalytic converters of sulfuric acid plants

    Science.gov (United States)

    Yousefi, M.; Pahlavanzadeh, H.; Sadrameli, S. M.

    2017-08-01

    In this study, for the first time, it is tried to construct a pilot reactor, for surveying the possibility of creating isothermal condition in the catalytic convertors where SO2 is converted to SO3 in the sulfuric acid plants by heat pipe. The thermodynamic and thermo-kinetic conditions were considered the same as the sulfuric acid plants converters. Also, influence of SO2 gas flow rate on isothermal condition, has been studied. A thermo-siphon type heat pipe contains the sulfur + 5% iodine as working fluid, was used for disposing the heat of reaction from catalytic bed. Our results show that due to very high energy-efficiency, isothermal and passive heat transfer mechanism of heat pipe, it is possible to reach more than 95% conversion in one isothermal catalytic bed. As the results, heat pipe can be used as a certain piece of equipment to create isothermal condition in catalytic convertors of sulphuric acid plants. With this work a major evaluation in design of sulphuric acid plants can be taken place.

  4. Experimental and computational analysis of behavior of three-way catalytic converter under axial and radial flow conditions

    National Research Council Canada - National Science Library

    Taibani, Arif Zakaria; Kalamkar, Vilas

    2012-01-01

    .... This paper describes the development of a comprehensive practical model based on experiments for simulating the performance of automotive three-way catalytic converters, which are employed to reduce...

  5. Experimental investigation on emission reduction in neem oil biodiesel using selective catalytic reduction and catalytic converter techniques.

    Science.gov (United States)

    Viswanathan, Karthickeyan

    2018-03-01

    In the present study, non-edible seed oil namely raw neem oil was converted into biodiesel using transesterification process. In the experimentation, two biodiesel blends were prepared namely B25 (25% neem oil methyl ester with 75% of diesel) and B50 (50% neem oil methyl ester with 50% diesel). Urea-based selective catalytic reduction (SCR) technique with catalytic converter (CC) was fixed in the exhaust tail pipe of the engine for the reduction of engine exhaust emissions. Initially, the engine was operated with diesel as a working fluid and followed by refilling of biodiesel blends B25 and B50 to obtain the baseline readings without SCR and CC. Then, the same procedure was repeated with SCR and CC technique for emission reduction measurement in diesel, B25 and B50 sample. The experimental results revealed that the B25 blend showed higher break thermal efficiency (BTE) and exhaust gas temperature (EGT) with lower break-specific fuel consumption (BSFC) than B50 blend at all loads. On comparing with biodiesel blends, diesel experiences increased BTE of 31.9% with reduced BSFC of 0.29 kg/kWh at full load. A notable emission reduction was noticed for all test fuels in SCR and CC setup. At full load, B25 showed lower carbon monoxide (CO) of 0.09% volume, hydrocarbon (HC) of 24 ppm, and smoke of 14 HSU and oxides of nitrogen (NOx) of 735 ppm than diesel and B50 in SCR and CC setup. On the whole, the engine with SCR and CC setup showed better performance and emission characteristics than standard engine operation.

  6. Effects of a catalytic converter on PCDD/F, chlorophenol and PAH emissions in residential wood combustion.

    Science.gov (United States)

    Kaivosoja, T; Virén, A; Tissari, J; Ruuskanen, J; Tarhanen, J; Sippula, O; Jokiniemi, J

    2012-07-01

    Catalytic converters can be used to decrease carbon monoxide, organic compounds and soot from small-scale wood-fired appliances. The reduction is based on the oxidation of gaseous and particulate pollutants promoted by catalytic transition metal surfaces. However, many transition metals have also strong catalytic effect on PCDD/F formation. In this study birch logs were burned in a wood-fired stove (18 kW) with and without a catalytic converter with palladium and platinum as catalysts. PCDD/F, chlorophenol and PAH concentrations were analyzed from three phases of combustion (ignition, pyrolysis and burnout) and from the whole combustion cycle. PCDD/F emissions without the catalytic converter were at a level previously measured for wood combustion (0.15-0.74 ng N m(-3)). PAH emissions without the catalytic converter were high (47-85 mg N m(-3)) which is typical for batch combustion of wood logs. Total PAH concentrations were lower (on average 0.8-fold), and chlorophenol and PCDD/F levels were substantially higher (4.3-fold and 8.7-fold, respectively) when the catalytic converter was used. Increase in the chlorophenol and PCDD/F concentrations was most likely due to the catalytic effect of the platinum and palladium. Platinum and palladium may catalyze chlorination of PCDD/Fs via the Deacon reaction or an oxidation process. The influence of emissions from wood combustion to human health and the environment is a sum of effects caused by different compounds formed in the combustion. Therefore, the usage of platinum and palladium based catalytic converters to reduce emissions from residential wood combustion should be critically evaluated before wide-range utilization of the technology. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. Single‐molecule mechanochemical characterization of E. coli pol III core catalytic activity

    Science.gov (United States)

    Naufer, M. Nabuan; Murison, David A.; Rouzina, Ioulia; Beuning, Penny J.

    2017-01-01

    Abstract Pol III core is the three‐subunit subassembly of the E. coli replicative DNA polymerase III holoenzyme. It contains the catalytic polymerase subunit α, the 3′ → 5′ proofreading exonuclease ε, and a subunit of unknown function, θ. We employ optical tweezers to characterize pol III core activity on a single DNA substrate. We observe polymerization at applied template forces F  30 pN. Both polymerization and exonucleolysis occur as a series of short bursts separated by pauses. For polymerization, the initiation rate after pausing is independent of force. In contrast, the exonucleolysis initiation rate depends strongly on force. The measured force and concentration dependence of exonucleolysis initiation fits well to a two‐step reaction scheme in which pol III core binds bimolecularly to the primer‐template junction, then converts at rate k 2 into an exo‐competent conformation. Fits to the force dependence of k init show that exo initiation requires fluctuational opening of two base pairs, in agreement with temperature‐ and mismatch‐dependent bulk biochemical assays. Taken together, our results support a model in which the pol and exo activities of pol III core are effectively independent, and in which recognition of the 3′ end of the primer by either α or ε is governed by the primer stability. Thus, binding to an unstable primer is the primary mechanism for mismatch recognition during proofreading, rather than an alternative model of duplex defect recognition. PMID:28263430

  8. Emission Treatment towards Cold Start and Back Pressure in Internal Combustion Engine against Performance of Catalytic Converter: A Review

    Directory of Open Access Journals (Sweden)

    Leman A.M.

    2017-01-01

    Full Text Available Nowadays, regulation for the vehicles emissions has becoming more stringent in order to reduce the effect of pollutant gases that was being released by the vehicles exhaust. The development of catalytic converter is to resolve the pollution emission aspect. There are lots of improvements done by the researchers towards improving catalytic converter, yet there are still key issues which give negative impact to the environment. One of the problems that are being concern by among of researchers is the cold-start and back pressure problems that usually occur in the composition of catalytic converter. Presented here is a review of cold-starts and back pressure problems together with several alternatives taken by not affecting the performance of vehicles engine and fuel consumption. The review also includes alternative system development and selection of materials to resolve these problems.

  9. Possible ways of refining precious group metals (PGM obtained from recycling of the used auto catalytic converters

    Directory of Open Access Journals (Sweden)

    M. Saternus

    2013-04-01

    Full Text Available Used auto catalytic converters contain PGM metals. There are many methods of recovering these metals from used auto catalytic converters, e.g. Rose method, cyanide extraction, chlorination, segregation, melting methods, blowing with metal vapours and metal collector method. They are based on pyro- and hydrometallurgical processes. As a result of such treatment the solution or metal collector with PGM metals is obtained. Then the important task is to separate the particular precious metals. In the paper review of such methods and short characteristics are presented. To those methods belong: classical precipitation method, solvent extraction method, solid–phase extraction method, chromatographic separation.

  10. Case Study of the Innovation Process Characterizing the Development of the Three-Way Catalytic Converter System

    Science.gov (United States)

    1979-11-01

    This report traces the development of the three-way catalytic converter system from its origins in automaker and chemical firm research in the 1950s, to present plans preparing the system to be the auto exhaust emission control device most widely use...

  11. Evaluation and development of measurement components for a catalytic converter test system

    Energy Technology Data Exchange (ETDEWEB)

    Chan, A.K.

    1997-08-01

    The purpose of this research and development project was to evaluate and configure the components of a test system designed for the analysis of full-scale vehicle-aged automobile catalytic converters. The components tested included an exhaust gas analyzer for measuring hydrocarbon, CO, CO{sub 2} and O{sub 2} contents and a chemiluminescence detector (CLD) for measuring NO{sub x}, as well as thermocouples and pressure meters. A software package (TestPoint vers.2.Ob, Capital Equipment) was used to develop a computer-based data sampling and acquisition interface with the components and sensors connected to the test system. Tests of the Sun MGA-1200, a non-dispersive infrared (NDIR) analyzer, with CO, CO{sub 2} and various hydrocarbons (propane and octane) revealed sensitivity to large pressure changes (greater than 500 mbar). There was no significant cross-sensitivity between the gases except for the slight response of the hydrocarbon (HC) register to water vapor and CO. However, the low range of HC(5-30 vppm) expected in car exhaust after the converter means any cross-sensitivity could have an effect on the measurement, depending on measurement conditions. Tests of the EcoPhysics CLD 700 NO{sub x} meter also indicated sensitivity to pressure. An executable TestPoint run-time application was created to allow near real-time monitoring of the test system using a desktop computer. Nine channels of analog data are fed to a desktop computer via an A/D board and seven exhaust gas parameters through an RS-232C interface with the MGA-1200 23 refs, 32 figs, 10 tabs. Examination paper

  12. Emission reduction from a diesel engine fueled by pine oil biofuel using SCR and catalytic converter

    Science.gov (United States)

    Vallinayagam, R.; Vedharaj, S.; Yang, W. M.; Saravanan, C. G.; Lee, P. S.; Chua, K. J. E.; Chou, S. K.

    2013-12-01

    In this work, we propose pine oil biofuel, a renewable fuel obtained from the resins of pine tree, as a potential substitute fuel for a diesel engine. Pine oil is endowed with enhanced physical and thermal properties such as lower viscosity and boiling point, which enhances the atomization and fuel/air mixing process. However, the lower cetane number of the pine oil hinders its direct use in diesel engine and hence, it is blended in suitable proportions with diesel so that the ignition assistance could be provided by higher cetane diesel. Since lower cetane fuels are prone to more NOX formation, SCR (selective catalyst reduction), using urea as reducing agent, along with a CC (catalytic converter) has been implemented in the exhaust pipe. From the experimental study, the BTE (brake thermal efficiency) was observed to be increased as the composition of pine oil increases in the blend, with B50 (50% pine oil and 50% diesel) showing 7.5% increase over diesel at full load condition. The major emissions such as smoke, CO, HC and NOX were reduced by 70.1%, 67.5%, 58.6% and 15.2%, respectively, than diesel. Further, the average emissions of B50 with SCR and CC assembly were observed to be reduced, signifying the positive impact of pine oil biofuel on atmospheric environment. In the combustion characteristics front, peak heat release rate and maximum in-cylinder pressure were observed to be higher with longer ignition delay.

  13. Dissolution of Ceramic Monolith of Spent Catalytic Converters by Using Hydrometallurgical Methods / Rozpuszczanie Monolitu Ceramicznego Zużytych Katalizatorów Na Drodze Hydrometalurgicznej

    Directory of Open Access Journals (Sweden)

    Willner J.

    2015-12-01

    Full Text Available Catalytic converters contain the catalytic substance in their structure, which is a mixture of Platinum Group Metals (PGMs: platinum, palladium and rhodium. The prices of these metals and a growing demand for them in the market, make it necessary to recycle spent catalytic converters and recovery of PGMs. The ceramic monolith of catalytic converters is still a predominant material in its construction among of multitude of catalytic converters which are in circulation. In this work attempts were made to leach additional metals (excluding Pt from comminuted ceramic monolith. Classic leachant oxidizing media 10M H2SO4, HCl and H3PO4 were used considering the possibility of dissolution of the ceramic monolith.

  14. Gate-to-Gate Life Cycle Assessment for Determining Carbon Footprint of Catalytic Converter Assembly Process

    Directory of Open Access Journals (Sweden)

    A. N. Mustfizul Karim

    2017-03-01

    Full Text Available With the pursuit of embracing the circular economy, having upward trend in vehicle sales and environmental concern, sustainability has become an imperative part of the global automotive manufacturing strategies. One of the tactics to achieve this sustainable goal is to conserve and enhance the resource base by salvaging the embedded values from end-of-life product and for which, the remanufacturing can be considered as one of the most prominent epitome. Even though many of the auto parts like engine, transmissions, starters, alternators and etc. have been assessed for remanufacturability since last few decades, being a major component of a car body the Catalytic Converter (CC still remains unfocused in literature. However, to examine the remanufacturability of CC, a comprehensive study for assessing its economic, social, and environmental impact is inevitable. Therefore, with an underlying aim of designing the remanufacturable CC, in this endeavour an attempt has made to evaluate the environmental impact of its welding operations by means of energy consumption through gate-to-gate life cycle assessment. Real life data are collected from a Local Malaysian CC manufacturer. The obtained results show that the welding section has a carbon footprint of 0.203 kgCO2e/unit with major emission coming from the plasma arc welding. In addition to that, it is also observed that the value of carbon footprint is not only sensitive to the emission factor and processing time, but also it is responsive to the nature of the processing operations. Certainly, this observation will motivate to change the product design from the prospect of remanufacturing.

  15. A Comparative Life Cycle Assessment of Recycling the Platinum Group Metals from Automobile Catalytic Converter: An Australian Perspective

    Science.gov (United States)

    Ghodrat, Maryam; Rhamdhani, M. Akbar; Sharafi, Pezhman; Samali, Bijan

    2017-12-01

    This study provides a comparison between environmental impacts of the recovery of platinum group metals (PGMs) from the end-of-life catalytic converters by hydrometallurgical and pyrometallurgical methods. A gate to grave life cycle assessment of a typical three-way catalytic converter manufactured for an Australian passenger car was carried out using GaBi professional environmental package. Recovery rates, as well as qualities, quantities, losses, and fugitive emissions for all materials and elements used in both methods were calculated based on the developed flowsheets. A life cycle impact assessment was then made by carrying out a mass balance calculation. Inventory data show that the hydrometallurgical route for recycling of the platinum group metals out of catalytic converter scrap has lower impacts on the environment compared with the pyrometallurgical method. In terms of emission effects, the hydrometallurgical process was found to be highly advantageous since it causes insignificant emissions to air, sea water, and fresh water. It is also found that the hydrometallurgical route performs comparatively superior in terms of acidification, eutrophication, fossil depletion, and human toxicity. The obtained results are applicable only to the Australian setting.

  16. (Gold core) at (ceria shell) nanostructures for plasmon-enhanced catalytic reactions under visible light

    KAUST Repository

    Wang, Jianfang

    2014-08-26

    Driving catalytic reactions with sunlight is an excellent example of sustainable chemistry. A prerequisite of solar-driven catalytic reactions is the development of photocatalysts with high solar-harvesting efficiencies and catalytic activities. Herein, we describe a general approach for uniformly coating ceria on monometallic and bimetallic nanocrystals through heterogeneous nucleation and growth. The method allows for control of the shape, size, and type of the metal core as well as the thickness of the ceria shell. The plasmon shifts of the Au@CeO2 nanostructures resulting from the switching between Ce(IV) and Ce(III) are observed. The selective oxidation of benzyl alcohol to benzaldehyde, one of the fundamental reactions for organic synthesis, performed under both broad-band and monochromatic light, demonstrates the visible-light-driven catalytic activity and reveals the synergistic effect on the enhanced catalysis of the Au@CeO2 nanostructures. © 2014 American Chemical Society.

  17. Microfabricated Air-core Toroidal Inductor In Very High Frequency Power Converters

    DEFF Research Database (Denmark)

    Lê Thanh, Hoà; Nour, Yasser; Han, Anpan

    2018-01-01

    Miniaturization of power supplies is required for future intelligent electronic systems e.g. internet of things devices. Inductors play an essential role, and they are by far the most bulky and expensive components in power supplies. This paper presents a miniaturized microelectromechanical systems...... of 9 at 20 MHz. A DC-DC class-E boost converter is designed and implemented using the fabricated MEMS air-core inductor and a highperformance 65 V gallium nitride field effect transistor. The VHF converter achieved a peak efficiency of 78 % at the input voltage of 6.5 VDC. The MEMS inductor can carry 1...

  18. Catalytic Converter Developed By Washcoat Of γ-Alumina On Nickel Oxide (Nio) Catalyst In FeCrAl Substrate For Exhaust Emission Control : A Review

    OpenAIRE

    Leman A.M.; Afiqah J.; Rahman Fakhrurrazi; Feriyanto Dafit; Zakaria Supa’at; Rahmad R.

    2016-01-01

    Automobile exhaust emission control is one of the trending issues in automobile research field. The existing catalytic converter using the noble metals of platinum (Pt), palladium (Pd) and rhodium (Rd) recently were in limited supply and higher in cost. There is a need for the automotive industry to produce ultra-low emitting vehicles at a reasonable cost. The objective of this study is to investigate the effectiveness of methods of fabrication of modified catalytic converter by approaching F...

  19. Reduction of NOx Emission of a Diesel Engine with a Multiple Injection Pump by SCR Catalytic Converter

    Directory of Open Access Journals (Sweden)

    Vít Marek

    2016-01-01

    Full Text Available This paper deals with reduction of NOx-emission of a diesel engine with multiple injection pump by SCR catalytic converter. Main aim of the measurement was the detection of SCR catalyst converter efficiency. Tests were realized at the Research and Development workplace of Zetor Tractor a.s. Used engine was equipped with a multiple injection pump with electromagnetic regulator of a fuel charge. During the experiment selective catalytic reduction and diesel particulate filter were used as an after treatment of harmful pollutants reduction. Testing cycle of the eight-point test was chosen and Non-Road Steady Cycle (NRSC was maintained according to 97/68/EC directive. Results confirmed the dependencies between temperatures of SCR catalyst and exhaust gases and the volume of exhaust gases on efficiency of SCR catalyst. During the operation load of the engine, selective catalytic reduction reached efficiency over 90 %. Used after treatment system is suitable for reduction of harmful pollutants according to the Tier 4f norm.

  20. Comparison of catalytic converter performance in internal combustion engine fueled with Ron 95 and Ron 97 gasoline

    Science.gov (United States)

    Leman, A. M.; Rahman, Fakhrurrazi; Jajuli, Afiqah; Feriyanto, Dafit; Zakaria, Supaat

    2017-09-01

    Generating ideal stability between engine performance, fuel consumption and emission is one of the main challenges in the automotive industry. The characteristics of engine combustion and creation of emission might simply change with different types of operating parameters. This study aims in investigating the relationship between two types of fuels on the performance and exhaust emission of internal combustion engine using ceramic and metallic catalytic converters. Experimental tests were performed on Mitsubishi 4G93 engine by applying several ranges of engine speeds to determine the conversion of pollutant gases released by the engine. The obtained results specify that the usage of RON 97 equipped with metallic converters might increase the conversion percentage of 1.31% for CO and 126 ppm of HC gases. The metallic converters can perform higher conversion compared to ceramic because in the high space velocities, metallic has higher surface geometry area and higher amount of transverse Peclet number (Pi). Ceramic converters achieved conversion at 2496 ppm of NOx gas, which is higher than the metallic converter.

  1. Research on Integration of an Automotive Exhaust-Based Thermoelectric Generator and a Three-Way Catalytic Converter

    Science.gov (United States)

    Deng, Y. D.; Chen, Y. L.; Chen, S.; Xianyu, W. D.; Su, C. Q.

    2015-06-01

    A key research topic related to thermoelectric generators (TEGs) for automotive applications is to improve their compatibility with the original vehicle exhaust system, which determines the quality of the exhaust gas treatment and the realization of energy conservation and emission reduction. A new TEG integrated with a three-way catalytic converter (CTEG) by reshaping the converter as the heat exchanger is proposed. A heat-flux coupling simulation model of the integrated TEG is established at the light-off stage of the original three-way catalytic converter (TWC). Temperature distribution maps of the integrated heat exchanger, thermoelectric modules, and cooling-water tank are obtained to present the process of energy flow among the parts of the CTEG. Based on the simulation results, the output power of the CTEG is calculated by a mathematical model. A minimum output power of 31.93 W can be obtained by conversion when the TWC starts working at steady conditions. Theoretically, this case study demonstrates the great potential for use of CTEGs in vehicles.

  2. Differential catalytic promiscuity of the alkaline phosphatase superfamily bimetallo core reveals mechanistic features underlying enzyme evolution.

    Science.gov (United States)

    Sunden, Fanny; AlSadhan, Ishraq; Lyubimov, Artem; Doukov, Tzanko; Swan, Jeffrey; Herschlag, Daniel

    2017-12-22

    Members of enzyme superfamilies specialize in different reactions but often exhibit catalytic promiscuity for one another's reactions, consistent with catalytic promiscuity as an important driver in the evolution of new enzymes. Wanting to understand how catalytic promiscuity and other factors may influence evolution across a superfamily, we turned to the well-studied alkaline phosphatase (AP) superfamily, comparing three of its members, two evolutionarily distinct phosphatases and a phosphodiesterase. We mutated distinguishing active-site residues to generate enzymes that had a common Zn 2+ bimetallo core but little sequence similarity and different auxiliary domains. We then tested the catalytic capabilities of these pruned enzymes with a series of substrates. A substantial rate enhancement of ∼10 11 -fold for both phosphate mono- and diester hydrolysis by each enzyme indicated that the Zn 2+ bimetallo core is an effective mono/di-esterase generalist and that the bimetallo cores were not evolutionarily tuned to prefer their cognate reactions. In contrast, our pruned enzymes were ineffective sulfatases, and this limited promiscuity may have provided a driving force for founding the distinct one-metal-ion branch that contains all known AP superfamily sulfatases. Finally, our pruned enzymes exhibited 10 7 -10 8 -fold phosphotriesterase rate enhancements, despite absence of such enzymes within the AP superfamily. We speculate that the superfamily active-site architecture involved in nucleophile positioning prevents accommodation of the additional triester substituent. Overall, we suggest that catalytic promiscuity, and the ease or difficulty of remodeling and building onto existing protein scaffolds, have greatly influenced the course of enzyme evolution. Uncovering principles and properties of enzyme function, promiscuity, and repurposing provides lessons for engineering new enzymes. © 2017 by The American Society for Biochemistry and Molecular Biology, Inc.

  3. Catalytic Converter Developed By Washcoat Of γ-Alumina On Nickel Oxide (Nio Catalyst In FeCrAl Substrate For Exhaust Emission Control : A Review

    Directory of Open Access Journals (Sweden)

    Leman A.M.

    2016-01-01

    Full Text Available Automobile exhaust emission control is one of the trending issues in automobile research field. The existing catalytic converter using the noble metals of platinum (Pt, palladium (Pd and rhodium (Rd recently were in limited supply and higher in cost. There is a need for the automotive industry to produce ultra-low emitting vehicles at a reasonable cost. The objective of this study is to investigate the effectiveness of methods of fabrication of modified catalytic converter by approaching FeCrAl as a substrate which treated using ultrasonic bath technique to improve the exhaust emission control. The modified catalytic converter preparation will involve the ultrasonic bath process of FeCrAl foil which has fabricated as metallic monolith coated by γ-Al2O3 powder. Nickel as catalyst material will be prepared using electroplating process. The oxidation test will be conducted using a tube and automatic furnace in temperature of 1100°C for 100 hours. Mitsubishi 4G93 1800cc Petrol E.F.I with a multi -gas analyzer equipped with a hydraulic dynamometer will be used for emission measurements of HC, CO, and NOx in varying speed and load for both conditions with and without catalytic converter. The result will expect the γ-Al2O3 as the washcoat material that fully embedded to FeCrAl substrate with the combination of ultrasonic and electroplating technique will effectively convert the CO, NOx and HC to CO2, NO2 and H2O which means that catalytic converter is effective to improve exhaust emission control of diesel engine. The FeCrAl substrate as a metallic catalytic converter which coated by γ-Al2O3 using ultrasonic and nickelelectroplating technique may improve the exhaust emission control.

  4. The stability and catalytic activity of W13@Pt42 core-shell structure.

    Science.gov (United States)

    Huo, Jin-Rong; Wang, Xiao-Xu; Li, Lu; Cheng, Hai-Xia; Su, Yan-Jing; Qian, Ping

    2016-10-19

    This paper reports a study of the electronic properties, structural stability and catalytic activity of the W13@Pt42 core-shell structure using the First-principles calculations. The degree of corrosion of W13@Pt42 core-shell structure is simulated in acid solutions and through molecular absorption. The absorption energy of OH for this structure is lower than that for Pt55, which inhibits the poison effect of O containing intermediate. Furthermore we present the optimal path of oxygen reduction reaction catalyzed by W13@Pt42. Corresponding to the process of O molecular decomposition, the rate-limiting step of oxygen reduction reaction catalyzed by W13@Pt42 is 0.386 eV, which is lower than that for Pt55 of 0.5 eV. In addition by alloying with W, the core-shell structure reduces the consumption of Pt and enhances the catalytic efficiency, so W13@Pt42 has a promising perspective of industrial application.

  5. Catalytic

    Directory of Open Access Journals (Sweden)

    S.A. Hanafi

    2014-03-01

    Full Text Available A series of dealuminated Y-zeolites impregnated by 0.5 wt% Pt catalysts promoted by different amounts of Ni, Pd or Cr (0.3 and 0.6 wt% were prepared and characterized as hydrocracking catalysts. The physicochemical and structural characterization of the solid catalysts were investigated and reported through N2 physisorption, XRD, TGA-DSC, FT-IR and TEM techniques. Solid catalysts surface acidities were investigated through FT-IR spectroscopy aided by pyridine adsorption. The solid catalytic activities were evaluated through hydroconversion of n-hexane and n-heptane employing micro-catalytic pulse technique directly connected to a gas chromatograph analyzer. The thermal stability of the solids was also investigated up to 800 °C. Crystallinity studies using the XRD technique of all modified samples proved analogous to the parent Y-zeolite, exhibiting nearly an amorphous and microcrystalline character of the second metal oxides. Disclosure of bimetallic catalysts crystalline characterization, through XRD, was not viable. The nitrogen adsorption–desorption isotherms for all samples concluded type I adsorption isotherms, without any hysteresis loop, indicating that the entire pore system is composed of micropores. TEM micrographs of the solid catalysts demonstrate well-dispersed Pt, Ni and Cr nanoparticles having sizes of 2–4 nm and 7–8 nm, respectively. The catalytic activity results indicate that the bimetallic (0.5Pt–0.3Cr/D18H–Y catalyst is the most active towards n-hexane and n-heptane isomerization while (0.5Pt–0.6Ni/D18H–Y catalyst can be designed as most suitable as a cracking catalyst.

  6. Pt@Ag and Pd@Ag core/shell nanoparticles for catalytic degradation of Congo red in aqueous solution.

    Science.gov (United States)

    Salem, Mohamed A; Bakr, Eman A; El-Attar, Heba G

    2018-01-05

    Platinum/silver (Pt@Ag) and palladium/silver (Pd@Ag) core/shell NPs have been synthesized in two steps reaction using the citrate method. The progress of nanoparticle formation was followed by the UV/Vis spectroscopy. Transmission electron microscopy revealed spherical shaped core/shell nanoparticles with average particle diameter 32.17nm for Pt@Ag and 8.8nm for Pd@Ag. The core/shell NPs were further characterized by FT-IR and XRD. Reductive degradation of the Congo red dye was chosen to demonstrate the excellent catalytic activity of these core/shell nanostructures. The nanocatalysts act as electron mediators for the transfer of electrons from the reducing agent (NaBH4) to the dye molecules. Effect of reaction parameters such as nanocatalyst dose, dye and NaBH4 concentrations on the dye degradation was investigated. A comparison between the catalytic activities of both nanocatalysts was made to realize which of them the best in catalytic performance. Pd@Ag was the higher in catalytic activity over Pt@Ag. Such greater activity is originated from the smaller particle size and larger surface area. Pd@Ag nanocatalyst was catalytically stable through four subsequent reaction runs under the utilized reaction conditions. These findings can thus be considered as possible economical alternative for environmental safety against water pollution by dyes. Copyright © 2017. Published by Elsevier B.V.

  7. Pt@Ag and Pd@Ag core/shell nanoparticles for catalytic degradation of Congo red in aqueous solution

    Science.gov (United States)

    Salem, Mohamed A.; Bakr, Eman A.; El-Attar, Heba G.

    2018-01-01

    Platinum/silver (Pt@Ag) and palladium/silver (Pd@Ag) core/shell NPs have been synthesized in two steps reaction using the citrate method. The progress of nanoparticle formation was followed by the UV/Vis spectroscopy. Transmission electron microscopy revealed spherical shaped core/shell nanoparticles with average particle diameter 32.17 nm for Pt@Ag and 8.8 nm for Pd@Ag. The core/shell NPs were further characterized by FT-IR and XRD. Reductive degradation of the Congo red dye was chosen to demonstrate the excellent catalytic activity of these core/shell nanostructures. The nanocatalysts act as electron mediators for the transfer of electrons from the reducing agent (NaBH4) to the dye molecules. Effect of reaction parameters such as nanocatalyst dose, dye and NaBH4 concentrations on the dye degradation was investigated. A comparison between the catalytic activities of both nanocatalysts was made to realize which of them the best in catalytic performance. Pd@Ag was the higher in catalytic activity over Pt@Ag. Such greater activity is originated from the smaller particle size and larger surface area. Pd@Ag nanocatalyst was catalytically stable through four subsequent reaction runs under the utilized reaction conditions. These findings can thus be considered as possible economical alternative for environmental safety against water pollution by dyes.

  8. Networked Pd (core) @ polyaniline (shell) composite: Highly electro-catalytic ability and unique selectivity

    Science.gov (United States)

    Xia, Youyi; Liu, Ning; Sun, Ling; Xu, Hao; Gao, Hong; Lu, Taofeng

    2018-01-01

    A networked composite (Pd@PANI), which is self-assemblied freely from Pd (core) @polyaniline (shell) nanoparticles, has been prepared successfully by a facilely one-step approach. Owing to the conductive environment and acid-doped behavior provided by PANI, the composite exhibits highly catalytic ability in the reaction involving acidic reactants. For instance, in the HCOOH electro-oxidation, 9.16 times of specific activity (comparing with that when using commercial Pd/C catalyst) is observed. Meanwhile, the as-prepared product is unable to catalyze some other systems like the electro-oxidation of C2H5OH, showing novel and unique selectivity. Those would open up new routes for synthesizing high-performance Pd-based catalysts, and could also shed some light on synthesizing new types of selective catalysts.

  9. Crystal Structure of Deinococcus radiodurans RecQ Helicase Catalytic Core Domain: The Interdomain Flexibility

    Directory of Open Access Journals (Sweden)

    Sheng-Chia Chen

    2014-01-01

    Full Text Available RecQ DNA helicases are key enzymes in the maintenance of genome integrity, and they have functions in DNA replication, recombination, and repair. In contrast to most RecQs, RecQ from Deinococcus radiodurans (DrRecQ possesses an unusual domain architecture that is crucial for its remarkable ability to repair DNA. Here, we determined the crystal structures of the DrRecQ helicase catalytic core and its ADP-bound form, revealing interdomain flexibility in its first RecA-like and winged-helix (WH domains. Additionally, the WH domain of DrRecQ is positioned in a different orientation from that of the E. coli RecQ (EcRecQ. These results suggest that the orientation of the protein during DNA-binding is significantly different when comparing DrRecQ and EcRecQ.

  10. Analytical Switching Cycle Modeling of Bidirectional High Voltage Flyback Converter for Capacitive Load Considering Core Loss Effect

    DEFF Research Database (Denmark)

    Huang, Lina; Zhang, Zhe; Andersen, Michael A. E.

    2015-01-01

    With the advancement of material science, various smart materials with intrinsic capacitive property are emerging. The high voltage (HV) power electronics converters with bidirectional energy flow functionality for supplying the capacitive load are highly demanded. A switching cycle based...... of configuration and working principle. Considering the parasitic elements as well as the core loss effect, the converter is modeled with analytical formulas for one switching cycle. The comparison between the model based calculation results and prototype experiments based measurement results are used to validate...... analytical model of HV bidirectional converter driving capacitive load is beneficial in thoroughly understanding the operational behavior, investigating the energy efficiency and optimizing the design. In this paper, a HV bidirectional flyback converter for capacitive load is generally discussed in terms...

  11. How to Close the Loop of Platinum from Heavy Vehicles Catalytic Converters? : Framework to Evaluate the Impact of Several Promising Action Levers

    OpenAIRE

    Saidani, Michael; Yannou, Bernard; Leroy, Yann; Cluzel, François

    2017-01-01

    International audience; The issue of recovering platinum from catalytic converter of heavy vehicles, arises for economic (high valuable component due to the non-negligible presence of platinum that costs around 30 €/g), environmental (low platinum concentration in mines (below 10 g/t) required large consumption of energy), social (ore mining conditions are increasingly drastic) and geostrategic (more than 90% of platinum stock is located in South Africa and Russia) reasons. Even if some margi...

  12. Diffusion and Bonding Mechanism of Protective γ-Al2O3 on FeCrAl Foil for Metallic Three-Way Catalytic Converter

    Directory of Open Access Journals (Sweden)

    Feriyanto Dafit

    2017-01-01

    Full Text Available High pollutant level contributed by mobile sources/land transportation that become main problems for the human health. Improving exhaust emission system by improving catalytic converter properties is one of the most effective way to produce healthy air in our environment. It is conducted by two methods i.e. ultrasonic during electroplating (UBDEL and electroplating process (EL which are not fully investigated yet as catalytic converter coating process. UBDEL is conducted using sulphamate types electrolyte solution, Frequency of 35 kHz, current of 1.28A, Voltage of 12 V, and various time of 15, 30, 45, 60 and 75 minutes. Meanwhile El method is conducted using parameters of current of 1.28A, Voltage of 12 V, stirrer speed of 60 rpm and various time of 15, 30, 45, 60 and 75 minutes. Fully γ-Al2O3 bonding to the FeCrAl substrate is shown by UBDEL 75 minutes samples proved by SEM images and Ra and Rq are 4.01 μm and 5.64 μm, respectively. Ni present on the FeCrAl substrate as other protective layer generated by Ni electroplating process that will improve thermal stability of FeCrAl at high temperature of 1000 °C. From the results, can summarized that UBDEL technique is promoted as an effective catalytic converter coating technique.

  13. Rice Cellulose SynthaseA8 Plant-Conserved Region Is a Coiled-Coil at the Catalytic Core Entrance

    Energy Technology Data Exchange (ETDEWEB)

    Rushton, Phillip S.; Olek, Anna T.; Makowski, Lee; Badger, John; Steussy, C. Nicklaus; Carpita, Nicholas C.; Stauffacher, Cynthia V. (NEU); (Purdue)

    2016-11-22

    The crystallographic structure of a rice (Oryza sativa) cellulose synthase, OsCesA8, plant-conserved region (P-CR), one of two unique domains in the catalytic domain of plant CesAs, was solved to 2.4 Å resolution. Two antiparallel α-helices form a coiled-coil domain linked by a large extended connector loop containing a conserved trio of aromatic residues. The P-CR structure was fit into a molecular envelope for the P-CR domain derived from small-angle X-ray scattering data. The P-CR structure and molecular envelope, combined with a homology-based chain trace of the CesA8 catalytic core, were modeled into a previously determined CesA8 small-angle X-ray scattering molecular envelope to produce a detailed topological model of the CesA8 catalytic domain. The predicted position for the P-CR domain from the molecular docking models places the P-CR connector loop into a hydrophobic pocket of the catalytic core, with the coiled-coil aligned near the entrance of the substrate UDP-glucose into the active site. In this configuration, the P-CR coiled-coil alone is unlikely to regulate substrate access to the active site, but it could interact with other domains of CesA, accessory proteins, or other CesA catalytic domains to control substrate delivery.

  14. The DExD/H-box ATPase Prp2p destabilizes and proofreads the catalytic RNA core of the spliceosome.

    Science.gov (United States)

    Wlodaver, Alissa M; Staley, Jonathan P

    2014-03-01

    After undergoing massive RNA and protein rearrangements during assembly, the spliceosome undergoes a final, more subtle, ATP-dependent rearrangement that is essential for catalysis. This rearrangement requires the DEAH-box protein Prp2p, an RNA-dependent ATPase. Prp2p has been implicated in destabilizing interactions between the spliceosome and the protein complexes SF3 and RES, but a role for Prp2p in destabilizing RNA-RNA interactions has not been explored. Using directed molecular genetics in budding yeast, we have found that a cold-sensitive prp2 mutation is suppressed not only by mutations in SF3 and RES components but also by a range of mutations that disrupt the spliceosomal catalytic core element U2/U6 helix I, which is implicated in juxtaposing the 5' splice site and branch site and in positioning metal ions for catalysis within the context of a putative catalytic triplex; indeed, mutations in this putative catalytic triplex also suppressed a prp2 mutation. Remarkably, we also found that prp2 mutations rescue lethal mutations in U2/U6 helix I. These data provide evidence that RNA elements that comprise the catalytic core are already formed at the Prp2p stage and that Prp2p destabilizes these elements, directly or indirectly, both to proofread spliceosome activation and to promote reconfiguration of the spliceosome to a fully competent, catalytic conformation.

  15. Dependence of Localized Electronic Structure on Ligand Configuration in the [2Fe] Hydrogenase Catalytic Core^*

    Science.gov (United States)

    Chang, Christopher H.; Kim, Kwiseon

    2007-03-01

    The [FeFe] hydrogenase enzyme is found in a variety of organisms, including Archaea, Eubacteria, and green algae^1,2, and crystallographically determined atomic position data is available for two examples. The biologically unusual catalytic H-cluster, responsible for proton reduction to H2 in vivo, is conserved in the known structures and includes two bis-thiolato bridged iron ions with extensive cyano- and carbonyl ligation. To address the configurational specificity of the diatomic ligand ligation, density functional theoretical calculations were done on [2Fe] core models of the active center, with varying CO and CN^- ligation patterns. Bonding in each complex has been characterized within the Natural Bond Orbital formalism. The effect of ligand configuration on bonding and charge distribution as well as Kohn-Sham orbital structure will be presented. [1] M. Forestier, P. King, L. Zhang, M. Posewitz, S. Schwarzer, T. Happe, M.L. Ghirardi, and M. Seibert, Eur. J. Biochem. 270, 2750 (2003). [2] Posewitz, M.C., P.W. King, S.L. Smolinski, R.D. Smith, II, A.R. Ginley, M.L. Ghirardi, and M. Seibert, Biochem. Soc. Trans. 33, 102 (2005). ^*This work was supported by the US DOE-SC-BES Hydrogen Fuels Initiative, and done in collaboration with the NREL Chemical and Biosciences Center.

  16. Fabrication of ammonium perchlorate/copper-chromium oxides core-shell nanocomposites for catalytic thermal decomposition of ammonium perchlorate

    Energy Technology Data Exchange (ETDEWEB)

    Eslami, Abbas, E-mail: eslami@umz.ac.ir [Department of Inorganic Chemistry, Faculty of Chemistry, University of Mazandaran, P.O.Box 47416-95447, Babolsar (Iran, Islamic Republic of); Juibari, Nafise Modanlou [Department of Inorganic Chemistry, Faculty of Chemistry, University of Mazandaran, P.O.Box 47416-95447, Babolsar (Iran, Islamic Republic of); Hosseini, Seyed Ghorban [Department of Chemistry, Malek Ashtar University of Technology, P.O. Box 16765-3454, Tehran (Iran, Islamic Republic of)

    2016-09-15

    The ammonium perchlorate/Cu(II)-Cr(III)-oxides(AP/Cu-Cr-O) core-shell nanocomposites were in-situ prepared by deposition of copper and chromium oxides on suspended ammonium perchlorate particles in ethyl acetate as solvent. The results of differential scanning calorimetery (DSC) and thermal gravimetric analysis (TGA) experiments showed that the nanocomposites have excellent catalytic effect on the thermal decomposition of AP, so that the released heat increases up to about 3-fold over initial values, changing from 450 J/g for pure AP to 1510 J/g for most appropriate mixture. For better comparison, single metal oxide/AP core-shell nanocomposite have also been prepared and the results showed that they have less catalytic effect respect to mixed metal oxides system. Scanning electron microscopy (SEM) results revealed homogenous deposition of nanoparticles on the surface of AP and fabrication of core-shell structures. The kinetic parameters of thermal decomposition of both pure AP and AP/Cu-Cr-O samples have been calculated by Kissinger method and the results showed that the values of pre-exponential factor and activation energy are higher for AP/Cu-Cr-O nanocomposite. The better catalytic effect of Cu-Cr-O nanocomposites is probably attributed to the synergistic effect between Cu{sup 2+} and Cr{sup 3+} in the nanocomposites, smaller particle size and more crystal defect. - Highlights: • The Cu-Cr-O nanoparticles were synthesized by chemical liquid deposition method. • Then, the AP/Cu-Cr-O core-shell nanocomposites were prepared. • The core-shell samples showed high catalytic activity for AP decomposition. • Thermal decomposition of samples occurs at lower temperature range.

  17. The deposition of Au-Pt core-shell nanoparticles on reduced graphene oxide and their catalytic activity.

    Science.gov (United States)

    Cui, Xiu; Wu, Shengnan; Jungwirth, Scott; Chen, Zhibing; Wang, Zhenghua; Wang, Lun; Li, Yongxin

    2013-07-26

    Au-Pt core-shell nanoparticles have been synthesized on a reduced graphene oxide (RGO) surface by an under-potential deposition (UPD) redox replacement technique, which involves redox replacement of a copper UPD monolayer by PtCl₄²⁻ that could be reduced and deposited simultaneously. Scanning electron microscopy (SEM) and electrochemical methods have been used to characterize the graphene decorated with Au-Pt core-shell nanoparticles. The electrochemical experiments show that the materials exhibit excellent catalytic activity towards the oxygen reduction reaction and the methanol oxidation reaction. It is believed that the high-performance of this new catalyst is due to the ultrathin Pt shell on the Au nanoparticles surface and the oxygen-containing functional groups on the RGO surface.

  18. EMISSION REDUCTION FROM A DIESEL ENGINE FUELED BY CERIUM OXIDE NANO-ADDITIVES USING SCR WITH DIFFERENT METAL OXIDES COATED CATALYTIC CONVERTER

    Directory of Open Access Journals (Sweden)

    B. JOTHI THIRUMAL

    2015-11-01

    Full Text Available This paper reports the results of experimental investigations on the influence of the addition of cerium oxide in nanoparticle form on the major physiochemical properties and the performance of diesel. The fuel is modified by dispersing the catalytic nanoparticle by ultrasonic agitation. The physiochemical properties of sole diesel fuel and modified fuel are tested with ASTM standard procedures. The effects of the additive nanoparticles on the individual fuel properties, the engine performance, and emissions are studied, and the dosing level of the additive is optimized. Cerium oxide acts as an oxygen-donating catalyst and provides oxygen for the oxidation of CO during combustion. The active energy of cerium oxide acts to burn off carbon deposits within the engine cylinder at the wall temperature and prevents the deposition of non-polar compounds on the cylinder wall which results in reduction in HC emission by 56.5%. Furthermore, a low-cost metal oxide coated SCR (selective catalyst reduction, using urea as a reducing agent, along with different types of CC (catalytic converter, has been implemented in the exhaust pipe to reduce NOx. It was observed that a reduction in NOx emission is 50–60%. The tests revealed that cerium oxide nanoparticles can be used as an additive in diesel to improve complete combustion of the fuel and reduce the exhaust emissions significantly.

  19. Oxidative leaching process with cupric ion in hydrochloric acid media for recovery of Pd and Rh from spent catalytic converters

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, C.A., E-mail: carlos.nogueira@lneg.pt [Laboratório Nacional de Energia e Geologia, I.P., Campus do Lumiar, 1649-038 Lisboa (Portugal); Paiva, A.P., E-mail: appaiva@fc.ul.pt [Centro de Química e Bioquímica, Departamento de Química e Bioquímica, Faculdade de Ciências da Universidade de Lisboa, 1749-016 Lisboa (Portugal); Oliveira, P.C. [Laboratório Nacional de Energia e Geologia, I.P., Campus do Lumiar, 1649-038 Lisboa (Portugal); Costa, M.C., E-mail: mcorada@ualg.pt [Centro de Ciências do Mar, Departamento de Química e Farmácia, Faculdade de Ciências e de Tecnologia, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, A.M. Rosa da, E-mail: amcosta@ualg.pt [Centro de Investigação em Química do Algarve, Departamento de Química e Farmácia, Faculdade de Ciências e de Tecnologia, Campus de Gambelas, 8005-139 Faro (Portugal)

    2014-08-15

    Highlights: • A new leaching process based on Cu{sup 2+}/HCl media for recovering Pd and Rh from spent autocatalytic converters is presented. • Palladium and rhodium were efficiently leached, with attained maximum yields of 95% and 86%, respectively. • Temperature, time, and HCl and Cu{sup 2+} concentrations were found to be significant factors in the leaching of Pd and Rh. - Abstract: The recycling of platinum-group metals from wastes such as autocatalytic converters is getting growing attention due to the scarcity of these precious metals and the market pressure originated by increase of demand in current and emerging applications. Hydrometallurgical treatment of such wastes is an alternative way to the most usual pyrometallurgical processes based on smelter operations. This paper focuses on the development of a leaching process using cupric chloride as oxidising agent, in HCl media, for recovery of palladium and rhodium from a spent catalyst. The chloride media allows the adequate conditions for oxidising and solubilising the metals, as demonstrated by equilibrium calculations based on thermodynamic data. The experimental study of the leaching process revealed that Pd solubilisation is clearly easier than that of Rh. The factors temperature, time, and HCl and Cu{sup 2+} concentrations were significant regarding Pd and Rh leaching, the latter requiring higher factor values to achieve the same results. Leaching yields of 95% Pd and 86% Rh were achieved under optimised conditions (T = 80 °C, t = 4 h, [HCl] = 6 M, [Cu{sup 2+}] = 0.3 M)

  20. Pyrolysis of marine biomass to produce bio-oil and its upgrading using a novel multi-metal catalyst prepared from the spent car catalytic converter.

    Science.gov (United States)

    Sabegh, Mahzad Yaghmaei; Norouzi, Omid; Jafarian, Sajedeh; Khosh, Akram Ghanbari; Tavasoli, Ahmad

    2018-02-01

    In order to reduce the economic and environmental consequences caused by spent car catalyst, we herein report for the first time a novel promising multi-metal catalyst prepared from spent car catalytic converters to upgrade the pyrolysis bio-oils. The physico-chemical properties of prepared catalyst were characterized by XRD, EDS, FESEM, and FT-IR analyses. The thermal stability of the multi-metal catalyst was studied with TGA. To investigate the activity of the catalyst, Conversion of Cladophora glomerata (C. glomerata) into bio-products was carried out via a fixed bed reactor with and without catalyst at the temperature of 500°C. Although the catalyst didn't catalyze the gasification reaction, bio-oil was upgraded over the catalyst. The main effect of the catalyst on the bio-oil components is deoxygenating of nitrogen compounds and promotion the ketonization reaction, which converts acid to ketone and declines the corrosive nature of bio-oil. Copyright © 2017. Published by Elsevier Ltd.

  1. Oxidative leaching process with cupric ion in hydrochloric acid media for recovery of Pd and Rh from spent catalytic converters.

    Science.gov (United States)

    Nogueira, C A; Paiva, A P; Oliveira, P C; Costa, M C; da Costa, A M Rosa

    2014-08-15

    The recycling of platinum-group metals from wastes such as autocatalytic converters is getting growing attention due to the scarcity of these precious metals and the market pressure originated by increase of demand in current and emerging applications. Hydrometallurgical treatment of such wastes is an alternative way to the most usual pyrometallurgical processes based on smelter operations. This paper focuses on the development of a leaching process using cupric chloride as oxidising agent, in HCl media, for recovery of palladium and rhodium from a spent catalyst. The chloride media allows the adequate conditions for oxidising and solubilising the metals, as demonstrated by equilibrium calculations based on thermodynamic data. The experimental study of the leaching process revealed that Pd solubilisation is clearly easier than that of Rh. The factors temperature, time, and HCl and Cu(2+) concentrations were significant regarding Pd and Rh leaching, the latter requiring higher factor values to achieve the same results. Leaching yields of 95% Pd and 86% Rh were achieved under optimised conditions (T = 80 °C, t = 4h, [HCl] = 6M, [Cu(2+)] = 0.3M). Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Au@PdOx with a PdOx-rich shell and Au-rich core embedded in Co3O4 nanorods for catalytic combustion of methane.

    Science.gov (United States)

    Yang, Nating; Liu, Jingwei; Sun, Yuhan; Zhu, Yan

    2017-02-09

    Au@PdOx with a PdOx-rich shell and Au-rich core nested in Co3O4 nanorods exhibited enhanced catalytic performance in the reaction of methane catalytic combustion, compared to monometallic Pd or Au/Co3O4 nanorods as well as conventional PdAu/Co3O4 nanorods. The superior catalysis of Au@PdOx/Co3O4 nanorods is mainly due to the architectural style of the PdOx-rich shell and Au-rich core, which shows strong interaction of Pd, Au, and Co3O4.

  3. The Metabolic Core and Catalytic Switches Are Fundamental Elements in the Self-Regulation of the Systemic Metabolic Structure of Cells

    Science.gov (United States)

    De la Fuente, Ildefonso M.; Cortes, Jesus M.; Perez-Pinilla, Martin B.; Ruiz-Rodriguez, Vicente; Veguillas, Juan

    2011-01-01

    Background Experimental observations and numerical studies with dissipative metabolic networks have shown that cellular enzymatic activity self-organizes spontaneously leading to the emergence of a metabolic core formed by a set of enzymatic reactions which are always active under all environmental conditions, while the rest of catalytic processes are only intermittently active. The reactions of the metabolic core are essential for biomass formation and to assure optimal metabolic performance. The on-off catalytic reactions and the metabolic core are essential elements of a Systemic Metabolic Structure which seems to be a key feature common to all cellular organisms. Methodology/Principal Findings In order to investigate the functional importance of the metabolic core we have studied different catalytic patterns of a dissipative metabolic network under different external conditions. The emerging biochemical data have been analysed using information-based dynamic tools, such as Pearson's correlation and Transfer Entropy (which measures effective functionality). Our results show that a functional structure of effective connectivity emerges which is dynamical and characterized by significant variations of bio-molecular information flows. Conclusions/Significance We have quantified essential aspects of the metabolic core functionality. The always active enzymatic reactions form a hub –with a high degree of effective connectivity- exhibiting a wide range of functional information values being able to act either as a source or as a sink of bio-molecular causal interactions. Likewise, we have found that the metabolic core is an essential part of an emergent functional structure characterized by catalytic modules and metabolic switches which allow critical transitions in enzymatic activity. Both, the metabolic core and the catalytic switches in which also intermittently-active enzymes are involved seem to be fundamental elements in the self-regulation of the Systemic

  4. The metabolic core and catalytic switches are fundamental elements in the self-regulation of the systemic metabolic structure of cells.

    Directory of Open Access Journals (Sweden)

    Ildefonso M De la Fuente

    Full Text Available BACKGROUND: Experimental observations and numerical studies with dissipative metabolic networks have shown that cellular enzymatic activity self-organizes spontaneously leading to the emergence of a metabolic core formed by a set of enzymatic reactions which are always active under all environmental conditions, while the rest of catalytic processes are only intermittently active. The reactions of the metabolic core are essential for biomass formation and to assure optimal metabolic performance. The on-off catalytic reactions and the metabolic core are essential elements of a Systemic Metabolic Structure which seems to be a key feature common to all cellular organisms. METHODOLOGY/PRINCIPAL FINDINGS: In order to investigate the functional importance of the metabolic core we have studied different catalytic patterns of a dissipative metabolic network under different external conditions. The emerging biochemical data have been analysed using information-based dynamic tools, such as Pearson's correlation and Transfer Entropy (which measures effective functionality. Our results show that a functional structure of effective connectivity emerges which is dynamical and characterized by significant variations of bio-molecular information flows. CONCLUSIONS/SIGNIFICANCE: We have quantified essential aspects of the metabolic core functionality. The always active enzymatic reactions form a hub--with a high degree of effective connectivity--exhibiting a wide range of functional information values being able to act either as a source or as a sink of bio-molecular causal interactions. Likewise, we have found that the metabolic core is an essential part of an emergent functional structure characterized by catalytic modules and metabolic switches which allow critical transitions in enzymatic activity. Both, the metabolic core and the catalytic switches in which also intermittently-active enzymes are involved seem to be fundamental elements in the self

  5. A novel structural Fenton-like nanocatalyst with highly improved catalytic performance for generalized preparation of iron oxide@organic dye polymer core-shell nanospheres.

    Science.gov (United States)

    Zhao, Guanghui; Peng, Xiaomen; Li, Hongping; Wang, Jianzhi; Zhou, Lincheng; Zhao, Tianqi; Huang, Zhihao; Jiang, Haifei

    2015-05-01

    FexOy@FexOy/C nanoparticles with a soap-bubble-like shell have been synthesized, and the materials exhibit excellent Fenton catalytic performance. More importantly, FexOy@FexOy/C nanoparticles as catalysts and precursors could catalyze organic dye molecules to form iron oxide@organic dye polymer core-shell nanospheres.

  6. First-principles investigation on Au n @(ZnO)42 (n = 6-16) core-shell nanoparticles: structure stability and catalytic activity

    Science.gov (United States)

    Hu, Yaowen; Huo, Jinrong; Wang, Xiaoxu; Wang, Rongming

    2017-11-01

    A family of Au n @(ZnO)42 (n = 6 -16) cluster-assembled nanoparticles are studied by density-functional theory calculations. Different sizes, up to 100 atoms, are considered for several compositions. For each n, we design and construct a converged model for Au n @(ZnO)42 to analyze the coupling effect of adding Au atoms into ZnO outer shell. Among the optimized geometrical structures, we find that Au13 @(ZnO)42 has the most stable structure. The electronic properties, optical properties and catalytic activity of the Au13 @(ZnO)42 core-shell have been systematically investigated, which also shows consistency with the experimental results. It is found that forming a core-shell structure enhances the visible-light photocatalytic ability and Au13 @(ZnO)42 core-shell structure has a high catalytic efficiency for the reaction CO oxidation.

  7. Seed-assisted synthesis of Pd@Au core-shell nanotetrapods and their optical and catalytic properties

    Science.gov (United States)

    Zhao, Ruopeng; Gong, Mingxing; Zhu, Huimin; Chen, Yu; Tang, Yawen; Lu, Tianhong

    2014-07-01

    The synthesis of noble metal nanostructures with special morphology, structure, composition, and size has been an attractive research area because of their valuable applications in various fields, including optics, electronics, sensing and catalysis. In this work, the first Pd@Au core-shell nanotetrapods (Pd@Au CSNTPs) were synthesized through a facile seeded growth method. Specifically, Pd nanotetrapods were utilized as the substrate for Au coating through chemically reducing HAuCl4 with ascorbic acid (AA) in the presence of polyvinylpyrrolidone (PVP). The morphology, composition, and structure of Pd@Au CSNTPs were fully characterized by scanning and transmission electron microscopy, energy dispersive spectroscopy element mapping, X-ray powder diffraction, X-ray photoelectron spectroscopy techniques, etc. Different from conventional spherical Au nanoparticles, the Pd@Au CSNTPs had a very wide surface plasmon resonance (SPR) absorption band in the visible and near-infrared regions (500-1400 nm), showing special SPR absorption features. Meanwhile, the Pd@Au CSNTPs exhibited remarkably enhanced catalytic activity for the hydrogenation reduction of nitro functional groups and the C&z.dbd;N bond because of their specific structural characteristics.The synthesis of noble metal nanostructures with special morphology, structure, composition, and size has been an attractive research area because of their valuable applications in various fields, including optics, electronics, sensing and catalysis. In this work, the first Pd@Au core-shell nanotetrapods (Pd@Au CSNTPs) were synthesized through a facile seeded growth method. Specifically, Pd nanotetrapods were utilized as the substrate for Au coating through chemically reducing HAuCl4 with ascorbic acid (AA) in the presence of polyvinylpyrrolidone (PVP). The morphology, composition, and structure of Pd@Au CSNTPs were fully characterized by scanning and transmission electron microscopy, energy dispersive spectroscopy element

  8. Highly catalytic hollow palladium nanoparticles derived from silver@silver-palladium core-shell nanostructures for the oxidation of formic acid

    Science.gov (United States)

    Chen, Dong; Cui, Penglei; He, Hongyan; Liu, Hui; Yang, Jun

    2014-12-01

    Hollow Palladium (hPd) nanoparticles (NPs) are prepared via a simple and mild successive method. Firstly, core-shell NPs with silver (Ag) cores and silver-palladium (Ag-Pd) alloy shells are synthesized in aqueous phase by galvanic replacement reaction (GRR) between Ag NPs and Pd2+ ion precursors. Saturated aqueous sodium chloride (NaCl) solution was then employed to remove the Ag component from the core and shell regions of core-shell Ag@Ag-Pd NPs, resulting in the formation of hPd NPs with shrunk sizes in comparison with their core-shell parents. Specifically, the hPd NPs exhibit superior catalytic activity and durability for catalyzing the oxidation of formic acid, compared with the Pd NPs reduced by NaBH4 in aqueous solution and commercial Pd/C catalyst from Johnson Matthey, mainly due to the large electrochemically active surface areas of the hollow particles. In addition, The Ag component in core-shell Ag@Ag-Pd NPs has an unfavorable influence on catalytic activity of NPs for formic acid oxidation. However, the durability could be improved due to the electron donating effect from Ag to Pd atoms in the core-shell NPs.

  9. Liquid-phase pulsed laser ablation synthesis of graphitized carbon-encapsulated palladium core-shell nanospheres for catalytic reduction of nitrobenzene to aniline

    Science.gov (United States)

    Kim, Yu-jin; Ma, Rory; Reddy, D. Amaranatha; Kim, Tae Kyu

    2015-12-01

    Graphitized carbon-encapsulated palladium (Pd) core-shell nanospheres were produced via pulsed laser ablation of a solid Pd foil target submerged in acetonitrile. The microstructural features and optical properties of these nanospheres were characterized via high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV-visible spectroscopy. Microstructural analysis indicated that the core-shell nanostructures consisted of single-crystalline cubic metallic Pd spheres that serve as the core material, over which graphitized carbon was anchored as a heterogeneous shell. The absorbance spectrum of the synthesized nanostructures exhibited a broad (absorption) band at ∼264 nm; this band corresponded to the typical inter-band transition of a metallic system and resulted possibly from the absorbance of the ionic Pd2+. The catalytic properties of the Pd and Pd@C core-shell nanostructures were investigated using the reduction of nitrobenzene to aniline by an excess amount of NaBH4 in an aqueous solution at room temperature, as a model reaction. Owing to the graphitized carbon-layered structure and the high specific surface area, the resulting Pd@C nanostructures exhibited higher conversion efficiencies than their bare Pd counterparts. In fact, the layered structure provided access to the surface of the Pd nanostructures for the hydrogenation reaction, owing to the synergistic effect between graphitized carbon and the nanostructures. Their unique structure and excellent catalytic performance render Pd@C core-shell nanostructures highly promising candidates for catalysis applications.

  10. Fabrication of Core-Shell Structural SiO2@H3[PM12O40] Material and Its Catalytic Activity

    Directory of Open Access Journals (Sweden)

    Xin Yang

    2014-01-01

    Full Text Available Through a natural tree grain template and sol-gel technology, the heterogeneous catalytic materials based on polyoxometalate compounds H3[PM12O40] encapsulating SiO2: SiO2@H3[PM12O40] (SiO2@PM12, M = W, Mo with core-shell structure had been prepared. The structure and morphology of the core-shell microspheres were characterized by the XRD, IR spectroscopy, UV-Vis absorbance, and SEM. These microsphere materials can be used as heterogeneous catalysts with high activity and stability for catalytic wet air oxidation of pollutant dyes safranine T (ST at room condition. The results show that the catalysts have excellent catalytic activity in treatment of wastewater containing 10 mg/L ST, and 94% of color can be removed within 60 min. Under different cycling runs, it is shown that the catalysts are stable under such operating conditions and the leaching tests show negligible leaching effect owing to the lesser dissolution.

  11. Contribution of the C-terminal region within the catalytic core domain of HIV-1 integrase to yeast lethality, chromatin binding and viral replication

    Directory of Open Access Journals (Sweden)

    Belhumeur Pierre

    2008-11-01

    Full Text Available Abstract Background HIV-1 integrase (IN is a key viral enzymatic molecule required for the integration of the viral cDNA into the genome. Additionally, HIV-1 IN has been shown to play important roles in several other steps during the viral life cycle, including reverse transcription, nuclear import and chromatin targeting. Interestingly, previous studies have demonstrated that the expression of HIV-1 IN induces the lethal phenotype in some strains of Saccharomyces cerevisiae. In this study, we performed mutagenic analyses of the C-terminal region of the catalytic core domain of HIV-1 IN in order to delineate the critical amino acid(s and/or motif(s required for the induction of the lethal phenotype in the yeast strain HP16, and to further elucidate the molecular mechanism which causes this phenotype. Results Our study identified three HIV-1 IN mutants, V165A, A179P and KR186,7AA, located in the C-terminal region of the catalytic core domain of IN that do not induce the lethal phenotype in yeast. Chromatin binding assays in yeast and mammalian cells demonstrated that these IN mutants were impaired for the ability to bind chromatin. Additionally, we determined that while these IN mutants failed to interact with LEDGF/p75, they retained the ability to bind Integrase interactor 1. Furthermore, we observed that VSV-G-pseudotyped HIV-1 containing these IN mutants was unable to replicate in the C8166 T cell line and this defect was partially rescued by complementation with the catalytically inactive D64E IN mutant. Conclusion Overall, this study demonstrates that three mutations located in the C-terminal region of the catalytic core domain of HIV-1 IN inhibit the IN-induced lethal phenotype in yeast by inhibiting the binding of IN to the host chromatin. These results demonstrate that the C-terminal region of the catalytic core domain of HIV-1 IN is important for binding to host chromatin and is crucial for both viral replication and the promotion of

  12. Epitaxial Growth of Multimetallic Pd@PtM (M = Ni, Rh, Ru) Core-Shell Nanoplates Realized by in Situ-Produced CO from Interfacial Catalytic Reactions.

    Science.gov (United States)

    Yan, Yucong; Shan, Hao; Li, Ge; Xiao, Fan; Jiang, Yingying; Yan, Youyi; Jin, Chuanhong; Zhang, Hui; Wu, Jianbo; Yang, Deren

    2016-12-14

    Pt-based multimetallic core-shell nanoplates have received great attention as advanced catalysts, but the synthesis is still challenging. Here we report the synthesis of multimetallic Pd@PtM (M = Ni, Rh, Ru) nanoplates including Pd@Pt nanoplates, in which Pt or Pt alloy shells with controlled thickness epitaxially grow on plate-like Pd seeds. The key to achieve high-quality Pt-based multimetallic nanoplates is in situ generation of CO through interfacial catalytic reactions associated with Pd nanoplates and benzyl alcohol. In addition, the accurate control in a trace amount of CO is also of great importance for conformal growth of multimetallic core-shell nanoplates. The Pd@PtNi nanoplates exhibit substantially improved activity and stability for methanol oxidation reaction (MOR) compared to the Pd@Pt nanoplates and commercial Pt catalysts due to the advantages arising from plate-like, core-shell, and alloy structures.

  13. Magnetic Co@g-C3N4 Core-Shells on rGO Sheets for Momentum Transfer with Catalytic Activity toward Continuous-Flow Hydrogen Generation.

    Science.gov (United States)

    Duan, Shasha; Han, Guosheng; Su, Yongheng; Zhang, Xiaoyu; Liu, Yanyan; Wu, Xianli; Li, Baojun

    2016-06-28

    Magnetic core-shell structures provide abundant opportunities for the construction of multifunctional composites. In this article, magnetic core-shells were fabricated with Co nanoparticles (NPs) as cores and g-C3N4 as shells. In the fabrication process, the Co@g-C3N4 core-shells were anchored onto the rGO nanosheets to form a Co@g-C3N4-rGO composite (CNG-I). For hydrogen generation from the hydrolysis of NaBH4 or NH3BH3, the Co NP cores act as catalytic active sites. The g-C3N4 shells protect Co NPs cores from aggregating or growing. The connection between Co NPs and rGO was strengthened by the g-C3N4 shells to prevent them from leaching or flowing away. The g-C3N4 shells also work as a cocatalyst for hydrogen generation. The magnetism of Co NPs and the shape of rGO nanosheets achieve effective momentum transfer in the external magnetic field. In the batch reactor, a higher catalytic activity was obtained for CNG-I in self-stirring mode than in magneton stirring mode. In the continuous-flow process, stable hydrogen generation was carried out with CNG-I being fixed and propelled by the external magnetic field. The separation film is unnecessary because of magnetic momentum transfer. This idea of the composite design and magnetic momentum transfer will be useful for the development of both hydrogen generation and multifunctional composite materials.

  14. A graphene-based smart catalytic system with superior catalytic performances and temperature responsive catalytic behaviors.

    Science.gov (United States)

    Qi, Junjie; Lv, Weipeng; Zhang, Guanghui; Li, Yang; Zhang, Guoliang; Zhang, Fengbao; Fan, Xiaobin

    2013-07-21

    We have successfully developed a unique graphene-based smart catalytic system which consists of the graphene supported Au-Pt bimetallic nanocatalyst with a well-defined core-shell structure and a dextran-based temperature-responsive polymer. The unique catalytic system possesses excellent catalytic performances and the catalytic activities could be readily switched on or off at different temperature windows.

  15. Novel CeO2@TiO2 core-shell nanostructure catalyst for selective catalytic reduction of NOx with NH3.

    Science.gov (United States)

    Huang, Bingjie; Yu, Danqing; Sheng, Zhongyi; Yang, Liu

    2017-05-01

    The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction (SCR) of NOx with NH3 in this study. The catalyst presented the obvious core-shell structure, and the shell was amorphous TiO2 which could protect the active center from the SO2 erosion. The catalyst showed high activity and stability, excellent N2 selectivity and superior SO2 resistance and H2O tolerance. Characterizations such as TEM, HR-TEM, XRD, BET, XPS, NH3-TPD, and H2-TPR were carried out. The results indicated that the catalyst had large surface area and the active sites were well dispersed on the surface. The NH3-TPD, H2-TPR and XPS results implied that its increased SCR activity might be due to the enhancement of NH3 chemisorption and the increase of active oxygen species, both of which were conductive to NH3 activation. The excellent catalytic performance suggests that it is a promising candidate for SCR catalyst. Copyright © 2016. Published by Elsevier B.V.

  16. Occurrence of dead core in catalytic particles containing immobilized enzymes: analysis for the Michaelis-Menten kinetics and assessment of numerical methods.

    Science.gov (United States)

    Pereira, Félix Monteiro; Oliveira, Samuel Conceição

    2016-11-01

    In this article, the occurrence of dead core in catalytic particles containing immobilized enzymes is analyzed for the Michaelis-Menten kinetics. An assessment of numerical methods is performed to solve the boundary value problem generated by the mathematical modeling of diffusion and reaction processes under steady state and isothermal conditions. Two classes of numerical methods were employed: shooting and collocation. The shooting method used the ode function from Scilab software. The collocation methods included: that implemented by the bvode function of Scilab, the orthogonal collocation, and the orthogonal collocation on finite elements. The methods were validated for simplified forms of the Michaelis-Menten equation (zero-order and first-order kinetics), for which analytical solutions are available. Among the methods covered in this article, the orthogonal collocation on finite elements proved to be the most robust and efficient method to solve the boundary value problem concerning Michaelis-Menten kinetics. For this enzyme kinetics, it was found that the dead core can occur when verified certain conditions of diffusion-reaction within the catalytic particle. The application of the concepts and methods presented in this study will allow for a more generalized analysis and more accurate designs of heterogeneous enzymatic reactors.

  17. Exchange-coupled fct-FePd/α-Fe nanocomposite magnets converted from Pd/Fe3O4 core/shell nanoparticles.

    Science.gov (United States)

    Liu, Fei; Dong, Yunhe; Yang, Wenlong; Yu, Jing; Xu, Zhichuan; Hou, Yanglong

    2014-11-10

    We report the controlled synthesis of exchange-coupled face-centered tetragonal (fct) FePd/α-Fe nanocomposite magnets with variable Fe concentration. The composite was converted from Pd/Fe3O4 core/shell nanoparticles through a high-temperature annealing process in a reducing atmosphere. The shell thickness of core/shell Pd/Fe3O4 nanoparticles could be readily tuned, and subsequently the concentration of Fe in nanocomposite magnets was controlled. Upon annealing reduction, the hard magnetic fct-FePd phase was formed by the interdiffusion between reduced α-Fe and face-centered cubic (fcc) Pd, whereas the excessive α-Fe remained around the fct-FePd grains, realizing exchange coupling between the soft magnetic α-Fe and hard magnetic fct-FePd phases. Magnetic measurements showed variation in the magnetic properties of the nanocomposite magnets with different compositions, indicating distinct exchange coupling at the interfaces. The coercivity of the exchange-coupled nanocomposites could be tuned from 0.7 to 2.8 kOe and the saturation magnetization could be controlled from 93 to 160 emu g(-1). This work provides a bottom-up approach using exchange-coupled nanocomposites for engineering advanced permanent magnets with controllable magnetic properties. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Peptides present in the non-digestible fraction of common beans (Phaseolus vulgaris L.) inhibit the angiotensin-I converting enzyme by interacting with its catalytic cavity independent of their antioxidant capacity.

    Science.gov (United States)

    Luna-Vital, Diego A; González de Mejía, Elvira; Mendoza, Sandra; Loarca-Piña, Guadalupe

    2015-05-01

    The aim was to evaluate the angiotensin-I converting enzyme (ACE) inhibitory potential and the antioxidant capacity of pure synthesized peptides (GLTSK, LSGNK, GEGSGA, MPACGSS and MTEEY) originally identified in the non-digestible fraction (NDF) of common beans (P. vulgaris L.) that had previously demonstrated antiproliferative activity against human colorectal cancer cells. The five peptides were able to inhibit ACE with half maximal inhibitory concentration (IC50) values ranging from 65.4 (GLTSK) to 191.5 μM (MPACGSS). The combination of GLTSK and MTEEY increased the ACE inhibition by 30% compared to equieffective doses of the single peptides. According to molecular docking analysis, the five peptides had lower estimated free energy values (-6.47 to -9.34 kcal mol(-1)) when they interacted with the catalytic site of ACE than that of the substrate hippuryl-histidyl-leucine (-5.41 kcal mol(-1)), thus inhibiting the enzymatic activity. According to molecular docking analysis, the five peptides interacted with four (His353, Ala354, Glu411 and Tyr523) out of 6 catalytic residues. Moreover, MPACGSS had the highest antioxidant activity according to Ferric reducing antioxidant power (FRAP) (421.58 μmol FeSO4 mg(-1)), Fe(2+) chelation (2.01 μmol Na2EDTA mg(-1)) assays, and also in DPPH (748.39 μmol Trolox per mg of dry peptide) and ABTS (561.42 μmol Trolox mg(-1)) radical scavenging assays. The results support the hypothesis that peptides present in the non-digestible fraction of common beans (Phaseolus vulgaris L.) may exert their physiological benefits independent of their antioxidant capacity, by ACE inhibition through interaction with its catalytic cavity.

  19. CORE

    DEFF Research Database (Denmark)

    Krigslund, Jeppe; Hansen, Jonas; Hundebøll, Martin

    2013-01-01

    different flows. Instead of maintaining these approaches separate, we propose a protocol (CORE) that brings together these coding mechanisms. Our protocol uses random linear network coding (RLNC) for intra- session coding but allows nodes in the network to setup inter- session coding regions where flows...... intersect. Routes for unicast sessions are agnostic to other sessions and setup beforehand, CORE will then discover and exploit intersecting routes. Our approach allows the inter-session regions to leverage RLNC to compensate for losses or failures in the overhearing or transmitting process. Thus, we...... increase the benefits of XORing by exploiting the underlying RLNC structure of individual flows. This goes beyond providing additional reliability to each individual session and beyond exploiting coding opportunistically. Our numerical results show that CORE outperforms both forwarding and COPE...

  20. Sonochemical synthesis of Fe3O4@NH2-mesoporous silica@Polypyrrole/Pd: A core/double shell nanocomposite for catalytic applications.

    Science.gov (United States)

    Snoussi, Youssef; Bastide, Stéphane; Abderrabba, Manef; Chehimi, Mohamed M

    2018-03-01

    There is a growing interest in sonochemistry for either the controlled design of nanostructured materials or for the synthesis of polymers and polymer composites. It is fast and highly efficient method that provides materials with exceptional and enhanced structural and chemical properties. Herein, we take advantage of the versatile sonochemical process in order to design core/double layered shell nanocomposite denoted by Fe3O4@NH2-mesoporous silica@ PPy/Pd. This magnetic, multicomponent material was designed in a three-step sono-process: (i) synthesis of magnetic core, (ii) cure of mesoporous silica, and (iii) sonochemical deposition of PPy/Pd. This last step was achieved within 1 h, a much shorter duration compared to conventional routes which usually take several hours to few days. The final nanocomposite can be recovered with a simple magnetic stick. X-ray diffraction patterns highlighted the presence of zerovalent palladium on the surface of the magnetic nanocomposite. The catalytic activity of the solid support was investigated by the study of the p-nitrophenol (p-NP) reduction and the Methyl Orange (MO) degradation in aqueous media. Results showed a very high catalytic efficiency, a high conversion yield of p-NP into 4-aminophenol (more than 94%) and an almost entire degradation of MO (99%) with a fast kinetics fitting to the first order model. This work demonstrates conclusively the benefits of sonochemistry in the design of metal nanoparticle-decorated inorganic/polymer hybrid system with outstanding performances. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. 2008CoreFieldDescriptions: PDF converted hand-written descriptions of 20 cores from offshore Puerto Rico and the U.S. Virgin Islands for cores collected by the U.S. Geological Survey in 2008.

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — In 2008, as a collaborative effort between Woods Hole Oceanographic Institution and the U.S. Geological Survey, 20 giant gravity cores were collected from areas...

  2. Preparation, characterization, and catalytic activity of core/shell Fe3O4@polyaniline@au nanocomposites.

    Science.gov (United States)

    Xuan, Shouhu; Wang, Yi-Xiang J; Yu, Jimmy C; Leung, Ken Cham-Fai

    2009-10-06

    We report a new method to synthesize magnetically responsive Fe3O4@polyaniline@Au nanocomposites. The superparamagnetic Fe3O4@polyaniline with well-defined core/shell nanostructure has been synthesized via an ultrasound-assisted in situ surface polymerization method. The negatively charged Au nanoparticles with a diameter of about 4 nm have been effectively assembled onto the positively charged surface of the as-synthesized Fe3O4@polyaniline core/shell microspheres via electrostatic attraction. The morphology, phase composition, and crystallinity of the as-prepared nanocomposites have been characterized by transmission electron microscopy (TEM) and powder X-ray diffraction (XRD). The central Fe3O4 cores are superparamagnetic at room temperature with strong magnetic response to externally applied magnetic field, thus providing a convenient means for separating the nanocomposite from solution. As-prepared inorganic/organic nanocomposite can be used as a magnetically recoverable nanocatalyst for the reduction of a selected substrate.

  3. Design of single-winding energy-storage reactors for dc-to-dc converters using air-gapped magnetic-core structures

    Science.gov (United States)

    Ohri, A. K.; Wilson, T. G.; Owen, H. A., Jr.

    1977-01-01

    A procedure is presented for designing air-gapped energy-storage reactors for nine different dc-to-dc converters resulting from combinations of three single-winding power stages for voltage stepup, current stepup and voltage stepup/current stepup and three controllers with control laws that impose constant-frequency, constant transistor on-time and constant transistor off-time operation. The analysis, based on the energy-transfer requirement of the reactor, leads to a simple relationship for the required minimum volume of the air gap. Determination of this minimum air gap volume then permits the selection of either an air gap or a cross-sectional core area. Having picked one parameter, the minimum value of the other immediately leads to selection of the physical magnetic structure. Other analytically derived equations are used to obtain values for the required turns, the inductance, and the maximum rms winding current. The design procedure is applicable to a wide range of magnetic material characteristics and physical configurations for the air-gapped magnetic structure.

  4. Hybrids of Gold Nanoparticles with Core-Shell Hyperbranched Polymers: Synthesis, Characterization, and Their High Catalytic Activity for Reduction of 4-Nitrophenol

    Directory of Open Access Journals (Sweden)

    Yi Liu

    2015-12-01

    Full Text Available Hyperbranched core-shell structure can be constructed by the modification of hyperbranched polyethylenimine (HPEI with different amide shells. Functionalized HPEI with acetic amide (HPEI-ACAm, propionic amide (HPEI-PRAm, butyric amide (HPEI-BUAm and isobutyric amide (HPEI-IBAm shells have been successfully prepared and used as protectors for gold nanoparticles (AuNPs. Novel AuNP composites were obtained through the non-covalent interaction between HPEI-XXAm and gold nanoparticles (XXAm represents ACAm, PRAm, BUAm or IBAm. The resulted AuNP composites can catalyze the reduction reaction of 4-nitrophenol by NaBH4. Interestingly, the catalytic activity of the AuNPs mainly depends on the structure of protectors and the degree of carbon chain arrangement denseness, which should affect the diffusivity of the reactants. In addition, the order of reaction rate is HPEI10K-IBAm0.80 > HPEI10K-ACAm0.80 > HPEI10K-PRAm0.82 > HPEI10K-BUAm0.83. It was found that the increase of the concentrations of the capping HPEI-XXAm polymers can enhance both the reaction rate and the turnover frequency (TOF values. Furthermore, the reaction rate was accelerated with increasing the reaction temperature for AuNPs-HPEI10K-ACAm0.80 and AuNPs-HPEI10K-PRAm0.82 systems. Interestingly, the reaction rate was accelerated with elevating reaction temperature at the beginning but reached a plateau or decreased sharply for AuNPs-HPEI10K-IBAm0.80 and AuNPs-HPEI10K-BUAm0.82 systems, owing to the thermoresponsivity of the corresponding AuNP composites. As a consequence, the catalytic activity could be controlled by adjusting the different shells of the hyperbranched polyethylenimine.

  5. Bushy sphere dendrites with husk-shaped branches axially spreading out from the core for photo-catalytic oxidation/remediation of toxins.

    Science.gov (United States)

    Shenashen, Mohamed A; Kawada, Satoshi; Selim, Mahmoud M; Morsy, Wafaa M; Yamaguchi, Hitoshi; Alhamid, Abdulaziz A; Ohashi, Naoki; Ichinose, Izumi; El-Safty, Sherif A

    2017-06-14

    This work describes densely interlinked bushy "tree-like chains" characterized by neatly branched sphere dendrites (bushy sphere dendrites, BSD) with long fan-like, husk-shaped branching paths that extend longitudinally from the core axis of the {110}-exposed plane. We confirmed that the hierarchical dendrite surfaces created bowls of swirled caves along the tree-tube in the mat-like branches. These surfaces had high-index catalytic site facets associated with the formation of ridges/defects on the dominant {110}-top-cover surface. These swirled caves along the branches were completely filled with 50-100 nm poly-CN nano-sphere-fossils with orb-like appearance. Such structural features are key issues of the inherent surface reactivity of a powerful catalyst/trapper, enabling photocatalytic oxidation and trapping of extremely toxic arsenite (AsO 3 3- ) species and photo-induced recovery of arsenate (AsO 4 3- ) products from catalyst surfaces. The light-induced release of produced AsO 4 3- from BSD indicates (i) highly controlled waste collection/management (i.e., recovery), (ii) low cost and ecofriendly photo-adsorbent, (iii) selective trapping of real sample water to produce water-free arsenite species; (iv) multiple reuse cycles of catalysts (i.e., reduced waste volume). Matrixed dendrites, covered with 3D microscopic sphere cores that capture solar-light, trap toxins, and are triggered by light, were designed. These dendrites can withstand indoor and outdoor recovery of toxins from water sources.

  6. Measuring the effects of platinum from catalytic converter equipped vehicles by means of plant indicators (food and fodder plants); Wirkungsmessungen von Platin aus katalysatorbetriebenen Kraftfahrzeugen mit pflanzlichen Bioindikatoren (Nahrungs- und Futterpflanzen)

    Energy Technology Data Exchange (ETDEWEB)

    Maier-Reiter, W.; Sommer, B. [TUEV Energie und Umwelt GmbH, Filderstadt (Germany). Niederlassung Stuttgart

    1997-12-31

    The essential aim of the present R and D project, titled ``Measuring the effects of platinum from catalytic converter equipped vehicles by means of plant indicators - food and fodder plants (VPT 02)``, was to obtain first orienting results on the potential effects of platinum pollution on plants by means of short-time, high-dose exposure experiments. The most important effect criterion in assessing potential hazards to humans and animals via the food chain, beside any outwardly visible changes (reaction), was the analytical detection of platinum accumulation in the plants. The project was also intended as a first contribution to the ecotoxicology of platinum, in particular the behaviour of metallic platinum and water-soluble platinum compounds in the soil-plant system. [Deutsch] Die wesentliche Zielsetzung des F and E-Vorhabens `Wirkungsmessungen von Platin und Platinverbindungen mit pflanzlichen Bioindikatoren - Nahrungs- und Futterpflanzen (VPT 02)` war es, im Rahmen von Kurzzeit-Belastungsexperimenten im hohen Dosisbereich erste orientierende Ergebnisse zu den moeglichen Auswirkungen von Platin-Belastungen auf Pflanzen abzuleiten. Neben aeusserlich sichtbaren Veraenderungen der Pflanzen (Reaktion) wurde als Wirkungskriterium insbesondere die chemisch-analytisch erfassbare Platin-Anreicherung in den Pflanzen (Akkumulation) betrachtet, die eine Abschaetzung moeglicher Gefaehrdungen von Mensch und Tier ueber die Nahrungskette ermoeglicht. Zudem sollte ein erster Beitrag zur Oekotoxikologie des Platins, insbesondere zum Verhalten von metallischem Platin und wasserloeslichen Platinverbindungen im System Boden-Pflanzen, erarbeitet werden. (orig.)

  7. Domain movements during CCA-addition: a new function for motif C in the catalytic core of the human tRNA nucleotidyltransferases.

    Science.gov (United States)

    Ernst, Felix G M; Rickert, Christian; Bluschke, Alexander; Betat, Heike; Steinhoff, Heinz-Jürgen; Mörl, Mario

    2015-01-01

    CCA-adding enzymes are highly specific RNA polymerases that synthesize and maintain the sequence CCA at the tRNA 3'-end. This nucleotide triplet is a prerequisite for tRNAs to be aminoacylated and to participate in protein biosynthesis. During CCA-addition, a set of highly conserved motifs in the catalytic core of these enzymes is responsible for accurate sequential nucleotide incorporation. In the nucleotide binding pocket, three amino acid residues form Watson-Crick-like base pairs to the incoming CTP and ATP. A reorientation of these templating amino acids switches the enzyme's specificity from CTP to ATP recognition. However, the mechanism underlying this essential structural rearrangement is not understood. Here, we show that motif C, whose actual function has not been identified yet, contributes to the switch in nucleotide specificity during polymerization. Biochemical characterization as well as EPR spectroscopy measurements of the human enzyme reveal that mutating the highly conserved amino acid position D139 in this motif interferes with AMP incorporation and affects interdomain movements in the enzyme. We propose a model of action, where motif C forms a flexible spring element modulating the relative orientation of the enzyme's head and body domains to accommodate the growing 3'-end of the tRNA. Furthermore, these conformational transitions initiate the rearranging of the templating amino acids to switch the specificity of the nucleotide binding pocket from CTP to ATP during CCA-synthesis.

  8. Molecular dynamics simulations and structure-guided mutagenesis provide insight into the architecture of the catalytic core of the ectoine hydroxylase.

    Science.gov (United States)

    Widderich, Nils; Pittelkow, Marco; Höppner, Astrid; Mulnaes, Daniel; Buckel, Wolfgang; Gohlke, Holger; Smits, Sander H J; Bremer, Erhard

    2014-02-06

    Many bacteria amass compatible solutes to fend-off the detrimental effects of high osmolarity on cellular physiology and water content. These solutes also function as stabilizers of macromolecules, a property for which they are referred to as chemical chaperones. The tetrahydropyrimidine ectoine is such a compatible solute and is widely synthesized by members of the Bacteria. Many ectoine producers also synthesize the stress protectant 5-hydroxyectoine from the precursor ectoine, a process that is catalyzed by the ectoine hydroxylase (EctD). The EctD enzyme is a member of the non-heme-containing iron(II) and 2-oxoglutarate-dependent dioxygenase superfamily. A crystal structure of the EctD protein from the moderate halophile Virgibacillus salexigens has previously been reported and revealed the coordination of the iron catalyst, but it lacked the substrate ectoine and the co-substrate 2-oxoglutarate. Here we used this crystal structure as a template to assess the likely positioning of the ectoine and 2-oxoglutarate ligands within the active site by structural comparison, molecular dynamics simulations, and site-directed mutagenesis. Collectively, these approaches suggest the positioning of the iron, ectoine, and 2-oxoglutarate ligands in close proximity to each other and with a spatial orientation that will allow the region-selective and stereo-specific hydroxylation of (4S)-ectoine to (4S,5S)-5-hydroxyectoine. Our study thus provides a view into the catalytic core of the ectoine hydroxylase and suggests an intricate network of interactions between the three ligands and evolutionarily highly conserved residues in members of the EctD protein family. © 2013.

  9. High-temperature catalytic reforming of n-hexane over supported and core-shell Pt nanoparticle catalysts: role of oxide-metal interface and thermal stability.

    Science.gov (United States)

    An, Kwangjin; Zhang, Qiao; Alayoglu, Selim; Musselwhite, Nathan; Shin, Jae-Youn; Somorjai, Gabor A

    2014-08-13

    Designing catalysts with high thermal stability and resistance to deactivation while simultaneously maintaining their catalytic activity and selectivity is of key importance in high-temperature reforming reactions. We prepared Pt nanoparticle catalysts supported on either mesoporous SiO2 or TiO2. Sandwich-type Pt core@shell catalysts (SiO2@Pt@SiO2 and SiO2@Pt@TiO2) were also synthesized from Pt nanoparticles deposited on SiO2 spheres, which were encapsulated by either mesoporous SiO2 or TiO2 shells. n-Hexane reforming was carried out over these four catalysts at 240-500 °C with a hexane/H2 ratio of 1:5 to investigate thermal stability and the role of the support. For the production of high-octane gasoline, branched C6 isomers are more highly desired than other cyclic, aromatic, and cracking products. Over Pt/TiO2 catalyst, production of 2-methylpentane and 3-methylpentane via isomerization was increased selectively up to 420 °C by charge transfer at Pt-TiO2 interfaces, as compared to Pt/SiO2. When thermal stability was compared between supported catalysts and sandwich-type core@shell catalysts, the Pt/SiO2 catalyst suffered sintering above 400 °C, whereas the SiO2@Pt@SiO2 catalyst preserved the Pt nanoparticle size and shape up to 500 °C. The SiO2@Pt@TiO2 catalyst led to Pt nanoparticle sintering due to incomplete protection of the TiO2 shells during the reaction at 500 °C. Interestingly, over the Pt/TiO2 catalyst, the average size of Pt nanoparticles was maintained even after 500 °C without sintering. In situ ambient pressure X-ray photoelectron spectroscopy demonstrated that the Pt/TiO2 catalyst did not exhibit TiO2 overgrowth on the Pt surface or deactivation by Pt sintering up to 600 °C. The extraordinarily high stability of the Pt/TiO2 catalyst promoted high reaction rates (2.0 μmol · g(-1) · s(-1)), which was 8 times greater than other catalysts and high isomer selectivity (53.0% of C6 isomers at 440 °C). By the strong metal-support interaction

  10. Evidence for Posttranslational Protein Flavinylation in the Syphilis Spirochete Treponema pallidum: Structural and Biochemical Insights from the Catalytic Core of a Periplasmic Flavin-Trafficking Protein.

    Science.gov (United States)

    Deka, Ranjit K; Brautigam, Chad A; Liu, Wei Z; Tomchick, Diana R; Norgard, Michael V

    2015-05-05

    The syphilis spirochete Treponema pallidum is an important human pathogen but a highly enigmatic bacterium that cannot be cultivated in vitro. T. pallidum lacks many biosynthetic pathways and therefore has evolved the capability to exploit host-derived metabolites via its periplasmic lipoprotein repertoire. We recently reported a flavin-trafficking protein in T. pallidum (Ftp_Tp; TP0796) as the first bacterial metal-dependent flavin adenine dinucleotide (FAD) pyrophosphatase that hydrolyzes FAD into AMP and flavin mononucleotide (FMN) in the spirochete's periplasm. However, orthologs of Ftp_Tp from other bacteria appear to lack this hydrolytic activity; rather, they bind and flavinylate subunits of a cytoplasmic membrane redox system (Nqr/Rnf). To further explore this dichotomy, biochemical analyses, protein crystallography, and structure-based mutagenesis were used to show that a single amino acid change (N55Y) in Ftp_Tp converts it from an Mg(2+)-dependent FAD pyrophosphatase to an FAD-binding protein. We also demonstrated that Ftp_Tp has a second enzymatic activity (Mg(2+)-FMN transferase); it flavinylates protein(s) covalently with FMN on a threonine side chain of an appropriate sequence motif using FAD as the substrate. Moreover, mutation of a metal-binding residue (D284A) eliminates Ftp_Tp's dual activities, thereby underscoring the role of Mg(2+) in the enzyme-catalyzed reactions. The posttranslational flavinylation activity that can target a periplasmic lipoprotein (TP0171) has not previously been described. The observed activities reveal the catalytic flexibility of a treponemal protein to perform multiple functions. Together, these findings imply mechanisms by which a dynamic pool of flavin cofactor is maintained and how flavoproteins are generated by Ftp_Tp locally in the T. pallidum periplasm. Treponema pallidum, the syphilis spirochete, exploits its periplasmic lipoproteins for a number of essential physiologic processes. One of these, flavin

  11. Preparation of Ag{sub core}/Au{sub shell} bimetallic nanoparticles from physical mixtures of Au clusters and Ag ions under dark conditions and their catalytic activity for aerobic glucose oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haijun, E-mail: zhanghaijun@wust.edu.cn [College of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei Province 430081 (China); Toshima, Naoki; Takasaki, Kanako [Department of Applied Chemistry, Tokyo University of Science Yamaguchi, SanyoOnoda-shi, Yamaguchi 756-0884 (Japan); Okumura, Mitsutaka [Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-0043 (Japan)

    2014-02-15

    Graphical abstract: The synthesis, characterization and catalytic activities for glucose oxidation of AgAu bimetallic nanoparticles (BNPs) with size of less than 2 nm are reported. The catalytic activity of Ag{sub 10}Au{sub 90} BNPs was about two times higher than that of Au NPs, even the BNPs have a larger particle size than that of Au NPs. -- Highlights: • Ag{sub core}/Au{sub shell} BNPs with size of less than 2.0 nm were prepared. • No any reducing reagents and lights were used for the preparation of the BNPs. • The catalytic activity of the BNPs is about two times higher than that of Au NPs. -- Abstract: AgAu bimetallic nanoparticles (BNPs), one of the most extensively studied bimetallic systems in the literatures, could have various structures and compositions depending on their preparation conditions. In the present work, catalytically highly active PVP-protected Ag{sub core}/Au{sub shell} BNPs of about 2.5 nm in diameter were fabricated from physical mixtures of aqueous dispersions of Au nanoparticles and Ag{sup +} ions under dark conditions without using any reducing agents. The prepared Ag{sub core}/Au{sub shell} BNP colloidal catalysts, which possessed a high activity for aerobic glucose oxidation, were characterized by Ultraviolet–visible spectrophotometry (UV–Vis), Inductive coupled plasma emission spectrometer (ICP), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and Energy disperse spectroscopy (EDS) in High-resolution scanning transmission electron microscopy (HR-STEM). The highest activity (11,360 mol-glucose h{sup −1} mol-metal{sup −1}) was observed for the BNPs with the Ag/Au atomic ratio of 1/9, the TOF value of which is about two times higher than that of Au nanoparticles with the particle size of 1.3 nm. The enhanced catalytic activity of the prepared Ag{sub core}/Au{sub shell} BNPs compared to Au NPs can be ascribed to the presence of negatively charged Au atoms resulted from electron donations

  12. A crystal structure of the catalytic core domain of an avian sarcoma and leukemia virus integrase suggests an alternate dimeric assembly.

    Science.gov (United States)

    Ballandras, Allison; Moreau, Karen; Robert, Xavier; Confort, Marie-Pierre; Merceron, Romain; Haser, Richard; Ronfort, Corinne; Gouet, Patrice

    2011-01-01

    Integrase (IN) is an important therapeutic target in the search for anti-Human Immunodeficiency Virus (HIV) inhibitors. This enzyme is composed of three domains and is hard to crystallize in its full form. First structural results on IN were obtained on the catalytic core domain (CCD) of the avian Rous and Sarcoma Virus strain Schmidt-Ruppin A (RSV-A) and on the CCD of HIV-1 IN. A ribonuclease-H like motif was revealed as well as a dimeric interface stabilized by two pairs of α-helices (α1/α5, α5/α1). These structural features have been validated in other structures of IN CCDs. We have determined the crystal structure of the Rous-associated virus type-1 (RAV-1) IN CCD to 1.8 Å resolution. RAV-1 IN shows a standard activity for integration and its CCD differs in sequence from that of RSV-A by a single accessible residue in position 182 (substitution A182T). Surprisingly, the CCD of RAV-1 IN associates itself with an unexpected dimeric interface characterized by three pairs of α-helices (α3/α5, α1/α1, α5/α3). A182 is not involved in this novel interface, which results from a rigid body rearrangement of the protein at its α1, α3, α5 surface. A new basic groove that is suitable for single-stranded nucleic acid binding is observed at the surface of the dimer. We have subsequently determined the structure of the mutant A182T of RAV-1 IN CCD and obtained a RSV-A IN CCD-like structure with two pairs of buried α-helices at the interface. Our results suggest that the CCD of avian INs can dimerize in more than one state. Such flexibility can further explain the multifunctionality of retroviral INs, which beside integration of dsDNA are implicated in different steps of the retroviral cycle in presence of viral ssRNA.

  13. A crystal structure of the catalytic core domain of an avian sarcoma and leukemia virus integrase suggests an alternate dimeric assembly.

    Directory of Open Access Journals (Sweden)

    Allison Ballandras

    Full Text Available Integrase (IN is an important therapeutic target in the search for anti-Human Immunodeficiency Virus (HIV inhibitors. This enzyme is composed of three domains and is hard to crystallize in its full form. First structural results on IN were obtained on the catalytic core domain (CCD of the avian Rous and Sarcoma Virus strain Schmidt-Ruppin A (RSV-A and on the CCD of HIV-1 IN. A ribonuclease-H like motif was revealed as well as a dimeric interface stabilized by two pairs of α-helices (α1/α5, α5/α1. These structural features have been validated in other structures of IN CCDs. We have determined the crystal structure of the Rous-associated virus type-1 (RAV-1 IN CCD to 1.8 Å resolution. RAV-1 IN shows a standard activity for integration and its CCD differs in sequence from that of RSV-A by a single accessible residue in position 182 (substitution A182T. Surprisingly, the CCD of RAV-1 IN associates itself with an unexpected dimeric interface characterized by three pairs of α-helices (α3/α5, α1/α1, α5/α3. A182 is not involved in this novel interface, which results from a rigid body rearrangement of the protein at its α1, α3, α5 surface. A new basic groove that is suitable for single-stranded nucleic acid binding is observed at the surface of the dimer. We have subsequently determined the structure of the mutant A182T of RAV-1 IN CCD and obtained a RSV-A IN CCD-like structure with two pairs of buried α-helices at the interface. Our results suggest that the CCD of avian INs can dimerize in more than one state. Such flexibility can further explain the multifunctionality of retroviral INs, which beside integration of dsDNA are implicated in different steps of the retroviral cycle in presence of viral ssRNA.

  14. Discussion of risks of platinum resources based on a function orientated criticality assessment. Shown by cytostatic drugs and automotive catalytic converters; Diskussion der Risiken der Ressource Platin auf Basis eines um funktionale Faktoren erweiterten Kritikalitaetsassessments. Dargestellt am Beispiel platinhaltiger Zytostatika und Autoabgaskatalysatoren

    Energy Technology Data Exchange (ETDEWEB)

    Thorenz, Andrea; Reller, Armin [University of Augsburg, Chair of Resource Strategy, Environment Science Center, Augsburg (Germany)

    2011-12-15

    The purpose of the study is the enhancement of criticality assessments for resources in order to address function specific factors like dissipation, recycling, bio-activity and toxicity. The developed methodology is applied to platinum-containing cytostatic drugs and automotive catalytic converters. Methods: The study is methodically based on an analysis of resource specific factors like exploration rates, reserves-to-production ratio and regional distribution of exploration areas as well as on the investigation of product/functional depending factors like recycling rates, dissipation rates, bio-diversity and toxicity. Taking into account that economic and ecological risks may occur at any stage of the supply, consumption and dissipation processes, the whole life cycles of the two analyzed products (cytostatic drugs and automotive catalytic converters) are considered. As an approach to reduce potential economic and ecological risks the study is especially focused on recycling strategies. In order to get a better understanding of platinum as an essential resource for the development of our society the history and the cultural impact of the term ''resource'' are introduced. The availability of platinum is crucial for several products of our modern society. Areas of application are e.g. jewellery, automotive catalytic converters, investments (coins, bars), computers, mobile devices, fertilizers and cytostatic drugs. Economic risks are caused by limited sources and dynamic demand of new application areas like fuel cells and drugs. Platinum-containing drugs are used for the treatment of several kinds of cancer such as testicular, breast, colon and prostate. Currently the pharmaceutical industry requires 6,9 tons per year (3 percent of the total demand of platinum). Due to the improvement of medical standards and the ageing society, especially in developing countries, the demand of platinum-containing drugs will rise significantly. The dissipation of

  15. Nuclear safety analyses and core design calculations to convert the Texas A & M University Nuclear Science Center reactor to low enrichment uranium fuel. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Parish, T.A.

    1995-03-02

    This project involved performing the nuclear design and safety analyses needed to modify the license issued by the Nuclear Regulatory Commission to allow operation of the Texas A& M University Nuclear Science Center Reactor (NSCR) with a core containing low enrichment uranium (LEU) fuel. The specific type of LEU fuel to be considered was the TRIGA 20-20 fuel produced by General Atomic. Computer codes for the neutronic analyses were provided by Argonne National Laboratory (ANL) and the assistance of William Woodruff of ANL in helping the NSCR staff to learn the proper use of the codes is gratefully acknowledged. The codes applied in the LEU analyses were WIMSd4/m, DIF3D, NCTRIGA and PARET. These codes allowed full three dimensional, temperature and burnup dependent calculations modelling the NSCR core to be performed for the first time. In addition, temperature coefficients of reactivity and pulsing calculations were carried out in-house, whereas in the past this modelling had been performed at General Atomic. In order to benchmark the newly acquired codes, modelling of the current NSCR core with highly enriched uranium fuel was also carried out. Calculated results were compared to both earlier licensing calculations and experimental data and the new methods were found to achieve excellent agreement with both. Therefore, even if an LEU core is never loaded at the NSCR, this project has resulted in a significant improvement in the nuclear safety analysis capabilities established and maintained at the NSCR.

  16. Mechanisms of mono- and poly-ubiquitination: Ubiquitination specificity depends on compatibility between the E2 catalytic core and amino acid residues proximal to the lysine

    Directory of Open Access Journals (Sweden)

    Sadowski Martin

    2010-08-01

    Full Text Available Abstract Ubiquitination involves the attachment of ubiquitin to lysine residues on substrate proteins or itself, which can result in protein monoubiquitination or polyubiquitination. Ubiquitin attachment to different lysine residues can generate diverse substrate-ubiquitin structures, targeting proteins to different fates. The mechanisms of lysine selection are not well understood. Ubiquitination by the largest group of E3 ligases, the RING-family E3 s, is catalyzed through co-operation between the non-catalytic ubiquitin-ligase (E3 and the ubiquitin-conjugating enzyme (E2, where the RING E3 binds the substrate and the E2 catalyzes ubiquitin transfer. Previous studies suggest that ubiquitination sites are selected by E3-mediated positioning of the lysine toward the E2 active site. Ultimately, at a catalytic level, ubiquitination of lysine residues within the substrate or ubiquitin occurs by nucleophilic attack of the lysine residue on the thioester bond linking the E2 catalytic cysteine to ubiquitin. One of the best studied RING E3/E2 complexes is the Skp1/Cul1/F box protein complex, SCFCdc4, and its cognate E2, Cdc34, which target the CDK inhibitor Sic1 for K48-linked polyubiquitination, leading to its proteasomal degradation. Our recent studies of this model system demonstrated that residues surrounding Sic1 lysines or lysine 48 in ubiquitin are critical for ubiquitination. This sequence-dependence is linked to evolutionarily conserved key residues in the catalytic region of Cdc34 and can determine if Sic1 is mono- or poly-ubiquitinated. Our studies indicate that amino acid determinants in the Cdc34 catalytic region and their compatibility to those surrounding acceptor lysine residues play important roles in lysine selection. This may represent a general mechanism in directing the mode of ubiquitination in E2 s.

  17. Data Converter

    NARCIS (Netherlands)

    Schinkel, Daniel; Nuijten, Petrus A.C.M.

    2005-01-01

    A data converter comprises a discrete- time sigma delta modulator e.g. for driving a Class-D power amplifier. The low-pass filter of the sigma delta modulator is modified by adding a suitably positioned pole to lower the oscillation frequency (limit cycle) of the sigma delta modulator in order to

  18. Data Converter

    NARCIS (Netherlands)

    Schinkel, Daniel

    2005-01-01

    A data converter comprises a discrete-time sigma delta modulator e.g. for driving a Class-D power amplifier. The low-pass filter of the sigma delta modulator is modified by adding a suitably positioned pole to lower the oscillation frequency (limit cycle) of the sigma delta modulator in order to

  19. Data Converter

    NARCIS (Netherlands)

    Schinkel, Daniel

    2006-01-01

    A data converter comprises a discrete-time sigma delta modulator e.g. for driving a Class-D power amplifier. The low-pass filter of the sigma delta modulator is modified by adding a suitably positioned pole to lower the oscillation frequency (limit cycle) of the sigma delta modulator in order to

  20. Wavelength Converters

    DEFF Research Database (Denmark)

    Kloch, Allan; Hansen, Peter Bukhave; Wolfson, David

    1999-01-01

    . It is predicted that jitter accumulation can be minimised by using a 9-10 dB ratio between the signal and CW power also assuring a high extinction ratio. Using this guideline simulations show that 20 cross-gain modulation converters can be cascaded at 10 Gbit/s with only ~20 ps of accumulated jitter...... and an extinction ratio of ~10 dB.The regenerative capabilities of the cross-phase converters are described and verified experimentally at 20 Gbit/s, where the noise redistribution and improvement of the signal-to-noise ratio clearly is demonstrated by controlling the input power to an EDFA. In a similar experiment...... at 2.5 Gbit/s, the regeneration causes a reduction of the required input power to an in-line EDFA of ~6 dB for a power penalty of 1 dB at a bit error rate of 10-9. If two converters are concatenated the power requirement is reduced ~8 dB. Obviously, the power reduction allows for longer spans between...

  1. Convertible barge

    Energy Technology Data Exchange (ETDEWEB)

    Howson, R.E.

    1988-08-23

    This patent describes a convertible barge, comprising: a. a deck; b. modules positioned on the deck in end to end relation and at least some of which contain pipeline processing equipment. The modules being removably attached to the deck, each module comprising a floor, ceiling, and a pair of side walls extending longitudinally of the barge between the ends; and c. means defining a closable opening comprising a roll-up door in at least one end of the modules for passing a pipeline portion from the module to a respectively adjacent module as the pipeline is being processed, for sealing the module during storage and for providing passageways between the modules and a view of pipe laying operations during use. A method for converting a barge to a lay barge, comprising: a. positioning on a deck of the barge in end to end relation of modules each of which has a floor, ceiling, and a pair of sidewalls extending longitudinally of the barge between the ends; b. providing pipeline process stations in at least some of the modules; c. removably attaching the modules to the deck; and d. providing a roll-up door in at least one of the modules ends of each module for passing a pipeline portion from the module to a respectively adjacent module as the pipeline is being processed and for providing passageways between the modules and a view of pipe laying operations during use.

  2. BcsA and BcsB form the catalytically active core of bacterial cellulose synthase sufficient for in vitro cellulose synthesis

    Science.gov (United States)

    Omadjela, Okako; Narahari, Adishesh; Strumillo, Joanna; Mélida, Hugo; Mazur, Olga; Bulone, Vincent; Zimmer, Jochen

    2013-01-01

    Cellulose is a linear extracellular polysaccharide. It is synthesized by membrane-embedded glycosyltransferases that processively polymerize UDP-activated glucose. Polymer synthesis is coupled to membrane translocation through a channel formed by the cellulose synthase. Although eukaryotic cellulose synthases function in macromolecular complexes containing several different enzyme isoforms, prokaryotic synthases associate with additional subunits to bridge the periplasm and the outer membrane. In bacteria, cellulose synthesis and translocation is catalyzed by the inner membrane-associated bacterial cellulose synthase (Bcs)A and BcsB subunits. Similar to alginate and poly-β-1,6 N-acetylglucosamine, bacterial cellulose is implicated in the formation of sessile bacterial communities, termed biofilms, and its synthesis is likewise stimulated by cyclic-di-GMP. Biochemical studies of exopolysaccharide synthesis are hampered by difficulties in purifying and reconstituting functional enzymes. We demonstrate robust in vitro cellulose synthesis reconstituted from purified BcsA and BcsB proteins from Rhodobacter sphaeroides. Although BcsA is the catalytically active subunit, the membrane-anchored BcsB subunit is essential for catalysis. The purified BcsA-B complex produces cellulose chains of a degree of polymerization in the range 200–300. Catalytic activity critically depends on the presence of the allosteric activator cyclic-di-GMP, but is independent of lipid-linked reactants. Our data reveal feedback inhibition of cellulose synthase by UDP but not by the accumulating cellulose polymer and highlight the strict substrate specificity of cellulose synthase for UDP-glucose. A truncation analysis of BcsB localizes the region required for activity of BcsA within its C-terminal membrane-associated domain. The reconstituted reaction provides a foundation for the synthesis of biofilm exopolysaccharides, as well as its activation by cyclic-di-GMP. PMID:24127606

  3. DFT study of Fe-Ni core-shell nanoparticles: stability, catalytic activity, and interaction with carbon atom for single-walled carbon nanotube growth.

    Science.gov (United States)

    Yang, Zhimin; Wang, Qiang; Shan, Xiaoye; Li, Wei-qi; Chen, Guang-hui; Zhu, Hongjun

    2015-02-21

    Metal catalysts play an important role in the nucleation and growth of single-walled carbon nanotubes (SWCNTs). It is essential for probing the nucleation and growth mechanism of SWCNTs to fundamentally understand the properties of the metal catalysts and their interaction with carbon species. In this study, we systematically studied the stability of 13- and 55-atom Fe and Fe-Ni core-shell particles as well as these particles interaction with the carbon atoms using the density functional theory calculations. Icosahedral 13- and 55-atom Fe-Ni core-shell bimetallic particles have higher stability than the corresponding monometallic Fe and Ni particles. Opposite charge transfer (or distribution) in these particles leads to the Fe surface-shell displays a positive charge, while the Ni surface-shell exhibits a negative charge. The opposite charge transfer would induce different chemical activities. Compared with the monometallic Fe and Ni particles, the core-shell bimetallic particles have weaker interaction with C atoms. More importantly, C atoms only prefer staying on the surface of the bimetallic particles. In contrast, C atoms prefer locating into the subsurface of the monometallic particles, which is more likely to form stable metal carbides. The difference of the mono- and bimetallic particles on this issue may result in different nucleation and growth mechanism of SWCNTs. Our findings provide useful insights for the design of bimetallic catalysts and a better understanding nucleation and growth mechanism of SWCNTs.

  4. Convertible Stadium

    Science.gov (United States)

    1978-01-01

    Air flotation technology used in NASA's Apollo program has found an interesting application in Hawaii's Aloha Stadium near Honolulu. The stadium's configuration can be changed, by moving entire 7,000-seat sections on a cushion of air, for best accommodation of spectators and participants at different types of events. In most stadiums, only a few hundred seats can be moved, by rolling sections on wheels or rails. At Aloha Stadium, 28,000 of the 50,000 seats can be repositioned for better spectator viewing and, additionally, for improved playing conditions. For example, a stadium designed primarily for football may compromise the baseball diamond by providing only a shallow outfield. Aloha's convertibility allows a full-size baseball field as well as optimum configurations for many other types of sports and special events. The photos show examples. The stadium owes its versatility to air flotation technology developed by General Motors. Its first large-scale application was movement of huge segments of the mammoth Saturn V moonbooster during assembly operations at Marshall Space Flight Center.

  5. Transformer Isolated Buck-Boost Converters

    Directory of Open Access Journals (Sweden)

    Barry W. Williams

    2016-12-01

    Full Text Available Of the single-switch dc-to-dc converters, those with the buck-boost voltage transfer function offer most potential for transformer coupling, hence isolation, at the kilowatt level. This paper highlights the limitations of the traditional magnetic coupled, buck-boost topology. Then four split-capacitor transformer-coupled topologies (specifically the Cuk, sepic, zeta, and a new, converters with a common ac equivalent circuit are explored, that do not temporarily store core magnetic energy as does the traditional isolated buck-boost converter nor have a core dc magnetizing current bias, as with the sepic and zeta transformer coupled topologies. Core dc bias capacitive voltage compensation is a practical design constraint in three of the four topologies, while all four must cater for stray and leakage inductance effects. Simulations and experimental results for the new converter at 408W support the transformer-coupled, single-switch dc-to-dc converter concepts investigated.

  6. A facile approach to fabrication of novel CeO{sub 2}-TiO{sub 2} core-shell nanocomposite leads to excellent UV-shielding ability and lower catalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Bahadur, Newaz Mohammed, E-mail: nmbahadur@yahoo.com [Utsunomiya University, Laboratory of Powder Technology, Graduate School of Engineering, Venture Business Laboratry (Japan); Kurayama, Fumio [Utsunomiya University, Center for Optical Research and Education (Japan); Furusawa, Takeshi; Sato, Masahide [Utsunomiya University, Department of Advanced Interdisciplinary Sciences (Japan); Siddiquey, Iqbal Ahmed [Utsunomiya University, Laboratory of Powder Technology, Graduate School of Engineering, Venture Business Laboratry (Japan); Hossain, Md. Mufazzal [University of Dhaka, Department of Chemistry (Bangladesh); Suzuki, Noboru [Utsunomiya University, Laboratory of Powder Technology, Graduate School of Engineering, Venture Business Laboratry (Japan)

    2013-01-15

    This study reports the development of a fast and facile route for the synthesis of novel CeO{sub 2}-TiO{sub 2} core-shell nanocomposite particles using microwave (MW) irradiation of the mixture of commercial CeO{sub 2}, titanium-tetra-n-butoxide (TBOT) and aqueous ammonia. Solutions of TBOT in ethanol and ammonia were mixed with dispersed CeO{sub 2} nanoparticles in ethanol, and the mixture was rapidly MW irradiated at 70 Degree-Sign C for 2 min. The resulting nanocomposite particles were characterized in terms of phase, shell thickness, composition, surface charge, morphology, and chemical state of the elements by XRD, TEM, XPS, SEM, Zeta potential analyzer, XRF, and FT-IR. Conventional methods of the synthesis of CeO{sub 2}-TiO{sub 2} nanocomposite require a long time, and TiO{sub 2} is rarely found as a coated material. In contrast, the MW method was able to synthesize CeO{sub 2}-TiO{sub 2} core-shell nanocompsite particles within a very short time. CeO{sub 2}-TiO{sub 2} nanocomposite particles were fairly unaggregated with an average titania layer thickness of 2-5 nm. The obtained nanocomposites retained the crystalline cubic phase of CeO{sub 2}, and the phase of coated TiO{sub 2} was amorphous. The catalytic activities of uncoated and TiO{sub 2}-coated CeO{sub 2} nanoparticles for the oxidation of organic compounds were evaluated by the degradation study of methylene blue in air atmosphere at 403 K. The enhanced UV-shielding ability and visible transparency of the nanocomposite obtained by UV visible spectroscopic measurements suggested that the core-shell material has novel characteristics for using as a sunscreen material.

  7. The FA Core Complex Contains a Homo-dimeric Catalytic Module for the Symmetric Mono-ubiquitination of FANCI-FANCD2

    Directory of Open Access Journals (Sweden)

    Paolo Swuec

    2017-01-01

    Full Text Available Activation of the main DNA interstrand crosslink repair pathway in higher eukaryotes requires mono-ubiquitination of FANCI and FANCD2 by FANCL, the E3 ligase subunit of the Fanconi anemia core complex. FANCI and FANCD2 form a stable complex; however, the molecular basis of their ubiquitination is ill defined. FANCD2 mono-ubiquitination by FANCL is stimulated by the presence of the FANCB and FAAP100 core complex components, through an unknown mechanism. How FANCI mono-ubiquitination is achieved remains unclear. Here, we use structural electron microscopy, combined with crosslink-coupled mass spectrometry, to find that FANCB, FANCL, and FAAP100 form a dimer of trimers, containing two FANCL molecules that are ideally poised to target both FANCI and FANCD2 for mono-ubiquitination. The FANCC-FANCE-FANCF subunits bridge between FANCB-FANCL-FAAP100 and the FANCI-FANCD2 substrate. A transient interaction with FANCC-FANCE-FANCF alters the FANCI-FANCD2 configuration, stabilizing the dimerization interface. Our data provide a model to explain how equivalent mono-ubiquitination of FANCI and FANCD2 occurs.

  8. Metallic Sn spheres and SnO2@C core-shells by anaerobic and aerobic catalytic ethanol and CO oxidation reactions over SnO2 nanoparticles

    Science.gov (United States)

    Kim, Won Joo; Lee, Sung Woo; Sohn, Youngku

    2015-01-01

    SnO2 has been studied intensely for applications to sensors, Li-ion batteries and solar cells. Despite this, comparatively little attention has been paid to the changes in morphology and crystal phase that occur on the metal oxide surface during chemical reactions. This paper reports anaerobic and aerobic ethanol and CO oxidation reactions over SnO2 nanoparticles (NPs), as well as the subsequent changes in the nature of the NPs. Uniform SnO2@C core-shells (10 nm) were formed by an aerobic ethanol oxidation reaction over SnO2 NPs. On the other hand, metallic Sn spheres were produced by an anaerobic ethanol oxidation reaction at 450 °C, which is significantly lower than that (1200 °C) used in industrial Sn production. Anaerobic and aerobic CO oxidation reactions were also examined. The novelty of the methods for the production of metallic Sn and SnO2@C core-shells including other anaerobic and aerobic reactions will contribute significantly to Sn and SnO2-based applications. PMID:26300041

  9. Amperometric glucose sensor based on enhanced catalytic reduction of oxygen using glucose oxidase adsorbed onto core-shell Fe3O4@silica@Au magnetic nanoparticles.

    Science.gov (United States)

    Wang, Ai-Jun; Li, Yong-Fang; Li, Zhong-Hua; Feng, Jiu-Ju; Sun, Yan-Li; Chen, Jian-Rong

    2012-08-01

    Monodisperse Fe3O4 magnetic nanoparticles (NPs) were prepared under facile solvothermal conditions and successively functionalized with silica and Au to form core/shell Fe3O4@silica@Au NPs. Furthermore, the samples were used as matrix to construct a glucose sensor based on glucose oxidase (GOD). The immobilized GOD retained its bioactivity with high protein load of 3.92×10(-9) mol·cm(-2), and exhibited a surface-controlled quasi-reversible redox reaction, with a fast heterogeneous electron transfer rate of 7.98±0.6 s(-1). The glucose biosensor showed a broad linear range up to 3.97 mM with high sensitivity of 62.45 μA·mM(-1) cm(-2) and fast response (less than 5s). Copyright © 2012 Elsevier B.V. All rights reserved.

  10. Catalytic devices

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ming; Zhang, Xiang

    2018-01-23

    This disclosure provides systems, methods, and apparatus related to catalytic devices. In one aspect, a device includes a substrate, an electrically insulating layer disposed on the substrate, a layer of material disposed on the electrically insulating layer, and a catalyst disposed on the layer of material. The substrate comprises an electrically conductive material. The substrate and the layer of material are electrically coupled to one another and configured to have a voltage applied across them.

  11. A novel label-free electrochemical immunosensor for ultra-sensitively detecting prostate specific antigen based on the enhanced catalytic currents of oxygen reduction catalyzed by core-shell Au@Pt nanocrystals.

    Science.gov (United States)

    Wang, Rui; Wang, Ai-Jun; Liu, Wei-Dong; Yuan, Pei-Xin; Xue, Yadong; Luo, Xiliang; Feng, Jiu-Ju

    2018-04-15

    Herein, bimetallic core-shell Au@Pt nanocrystals (Au@Pt NCs) were prepared by a simple one-pot aqueous method using 2-pyrrolidone-5-carboxylic acid sodium salt (PCA-Na) as a new and green growth-directing agent. The obtained architectures displayed excellent catalytic activity towards oxygen reduction reaction (ORR) compared with commercial Pt/C catalyst. A novel immunosensor was constructed via assembly prostate specific antibody on the surface of Au@Pt NCs. It was found that the ORR currents were significantly suppressed due to the specific antigen-antibody reaction. The ultra-sensitive determination of prostate specific antigen (PSA) was realized on account of the immunocomplex impeding the redox probe accessible to the electrode. The immunosensor exhibited good analytical performance for the assay of PSA with the wide linear range of 0.1 ~ 50ngmL-1 and low detection limit of 0.018ngmL-1 (S/N = 3), coupled with the improved stability, reproducibility and selectivity. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Docking and Molecular Dynamics Calculations of Some Previously Studied and newly Designed Ligands to Catalytic Core Domain of HIV-1 Integrase and an Investigation to Effects of Conformational Changes of Protein on Docking Results

    Directory of Open Access Journals (Sweden)

    Selami Ercan

    2016-10-01

    Full Text Available Nowadays, AIDS still remains as a worldwide pandemic and continues to cause many death which arise from HIV-1 virus. For nearly 35 years, drugs that target various steps of virus life cycle have been developed. HIV-1 integrase is the one of these steps which is essential for virus life cycle. Computer aided drug design is being used in many drug design studies as also used in development of the first HIV-1 integrase inhibitor Raltegravir. In this study 3 ligands which are used as HIV-1 integrase inhibitors and 4 newly designed ligands were docked to catalytic core domain of HIV-1 integrase. Each of ligands docked to three different conformations of protein. Prepared complexes (21 item were carried out by 50 ns MD simulations and results were analyzed. Finally, the binding free energies of ligands were calculated. Hereunder, it was determined that designed ligands L01 and L03 gave favorable results. The questions about the ligands which have low docking scores in a conformation of protein could give better scores in another conformation of protein and if the MD simulations carry the different oriented and different localized ligands in same position at the end of simulation were answered.

  13. Catalytic reaction in confined flow channel

    Energy Technology Data Exchange (ETDEWEB)

    Van Hassel, Bart A.

    2016-03-29

    A chemical reactor comprises a flow channel, a source, and a destination. The flow channel is configured to house at least one catalytic reaction converting at least a portion of a first nanofluid entering the channel into a second nanofluid exiting the channel. The flow channel includes at least one turbulating flow channel element disposed axially along at least a portion of the flow channel. A plurality of catalytic nanoparticles is dispersed in the first nanofluid and configured to catalytically react the at least one first chemical reactant into the at least one second chemical reaction product in the flow channel.

  14. Zeolitic catalytic conversion of alochols to hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Narula, Chaitanya K.; Davison, Brian H.; Keller, Martin

    2017-01-03

    A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100.degree. C. and up to 550.degree. C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.

  15. Catalytic production of biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Theilgaard Madsen, A.

    2011-07-01

    The focus of this thesis is the catalytic production of diesel from biomass, especially emphasising catalytic conversion of waste vegetable oils and fats. In chapter 1 an introduction to biofuels and a review on different catalytic methods for diesel production from biomass is given. Two of these methods have been used industrially for a number of years already, namely the transesterification (and esterification) of oils and fats with methanol to form fatty acid methyl esters (FAME), and the hydrodeoxygenation (HDO) of fats and oils to form straight-chain alkanes. Other possible routes to diesel include upgrading and deoxygenation of pyrolysis oils or aqueous sludge wastes, condensations and reductions of sugars in aqueous phase (aqueous-phase reforming, APR) for monofunctional hydrocarbons, and gasification of any type of biomass followed by Fischer-Tropsch-synthesis for alkane biofuels. These methods have not yet been industrialised, but may be more promising due to the larger abundance of their potential feedstocks, especially waste feedstocks. Chapter 2 deals with formation of FAME from waste fats and oils. A range of acidic catalysts were tested in a model fat mixture of methanol, lauric acid and trioctanoin. Sulphonic acid-functionalised ionic liquids showed extremely fast convertion of lauric acid to methyl laurate, and trioctanoate was converted to methyl octanoate within 24 h. A catalyst based on a sulphonated carbon-matrix made by pyrolysing (or carbonising) carbohydrates, so-called sulphonated pyrolysed sucrose (SPS), was optimised further. No systematic dependency on pyrolysis and sulphonation conditions could be obtained, however, with respect to esterification activity, but high activity was obtained in the model fat mixture. SPS impregnated on opel-cell Al{sub 2}O{sub 3} and microporous SiO{sub 2} (ISPS) was much less active in the esterification than the original SPS powder due to low loading and thereby low number of strongly acidic sites on the

  16. Molecular catalytic coal liquid conversion

    Energy Technology Data Exchange (ETDEWEB)

    Stock, L.M.; Yang, Shiyong [Univ. of Chicago, IL (United States)

    1995-12-31

    This research, which is relevant to the development of new catalytic systems for the improvement of the quality of coal liquids by the addition of dihydrogen, is divided into two tasks. Task 1 centers on the activation of dihydrogen by molecular basic reagents such as hydroxide ion to convert it into a reactive adduct (OH{center_dot}H{sub 2}){sup {minus}} that can reduce organic molecules. Such species should be robust withstanding severe conditions and chemical poisons. Task 2 is focused on an entirely different approach that exploits molecular catalysts, derived from organometallic compounds that are capable of reducing monocyclic aromatic compounds under very mild conditions. Accomplishments and conclusions are discussed.

  17. Catalytic Combustion of Ethyl Acetate

    OpenAIRE

    ÖZÇELİK, Tuğba GÜRMEN; ATALAY, Süheyda; ALPAY, Erden

    2014-01-01

    The catalytic combustion of ethyl acetate over prepared metal oxide catalysts was investigated. CeO, Co2O3, Mn2O3, Cr2O3, and CeO-Co2O3 catalysts were prepared on monolith supports and they were tested. Before conducting the catalyst experiments, we searched for the homogeneous gas phase combustion reaction of ethyl acetate. According to the homogeneous phase experimental results, 45% of ethyl acetate was converted at the maximum reactor temperature tested (350 °C). All the prepare...

  18. Wavelength converter technology

    DEFF Research Database (Denmark)

    Kloch, Allan; Hansen, Peter Bukhave; Poulsen, Henrik Nørskov

    1999-01-01

    Wavelength conversion is important since it ensures full flexibility of the WDM network layer. Progress in optical wavelength converter technology is reviewed with emphasis on all-optical wavelength converter types based on semiconductor optical amplifiers.......Wavelength conversion is important since it ensures full flexibility of the WDM network layer. Progress in optical wavelength converter technology is reviewed with emphasis on all-optical wavelength converter types based on semiconductor optical amplifiers....

  19. Wavelength converter technology

    DEFF Research Database (Denmark)

    Kloch, Allan; Hansen, Peter Bukhave; Poulsen, Henrik Nørskov

    1999-01-01

    Wavelength conversion is important since it ensures full flexibility of the WDM network layer. Progress in optical wavelength converter technology is reviewed with emphasis on air-optical wavelength converter types based on semiconductor optical amplifiers.......Wavelength conversion is important since it ensures full flexibility of the WDM network layer. Progress in optical wavelength converter technology is reviewed with emphasis on air-optical wavelength converter types based on semiconductor optical amplifiers....

  20. Technologies for converter topologies

    Science.gov (United States)

    Zhou, Yan; Zhang, Haiyu

    2017-02-28

    In some embodiments of the disclosed inverter topologies, an inverter may include a full bridge LLC resonant converter, a first boost converter, and a second boost converter. In such embodiments, the first and second boost converters operate in an interleaved manner. In other disclosed embodiments, the inverter may include a half-bridge inverter circuit, a resonant circuit, a capacitor divider circuit, and a transformer.

  1. Power Converters for Accelerators

    CERN Document Server

    Visintini, R.

    2015-06-15

    Particle accelerators use a great variety of power converters for energizing their sub-systems; while the total number of power converters usually depends on the size of the accelerator or combination of accelerators (including the experimental setup), the characteristics of power converters depend on their loads and on the particle physics requirements: this paper aims to provide an overview of the magnet power converters in use in several facilities worldwide.

  2. Monitoring of Basic Parameters for Selective Catalytic Reduction System Used in an Agricultural Tractor

    Directory of Open Access Journals (Sweden)

    Antonín Skřivánek

    2014-01-01

    Full Text Available Presented paper describes monitoring of basic parameters for selective catalytic reduction (SCR system used in an agricultural tractor. SCR systems are used to reduce emissions of nitrogen oxides (NOx produced by combustion of fuel. The usage of SCR catalytic converters entails certain disadvantages in the use of reducing agent and the necessity of suitable operating conditions to achieve optimum efficiency of the catalytic converter. This paper aims to predict consumption of AdBlue depending on the temperature of SCR catalytic converter, which reflects the engine load and monitoring the effectiveness of SCR catalytic converter when operating a tractor engine with a maximum dose of fuel. To fulfill those aims, the measurements have been performed on the Case Puma 185 CVX agricultural tractor. As the measurement results indicate, the lowest NOx emissions correspond to high consumption of AdBlue. Other studies imply that the catalytic converter operates at optimal operating temperature and with the highest efficiency of NOx emission reduction. The effectiveness of NOx emission reduction is thus affected not only by quantity of injected reagent but also by catalytic converter thermal load. Further measurement results indicate that the lowest amount of emissions of NOx (and the highest efficiency rate is achieved by catalytic converter in a range in which the engine operates with the highest engine efficiency.

  3. Investigation into the Possibilities of Functioning Catalytic Converter

    Directory of Open Access Journals (Sweden)

    Saugirdas Pukalskas

    2012-11-01

    Full Text Available The paper considers the principles of catalyst operations and chemical reactions proceeding within. Also, the modes used for defining the efficiency of the catalyst are reviewed. Experimental investigation has been carried out to help with assessing the efficacy of the catalyst according to the concentration of noxious fractions and differences in temperature before and behind the catalyst. Nine Otto engine vehicles have been tested. The applicable contamination level and efficiency of catalyst performance of the vehicles have been set. The conclusion reveals that flowing gas temperature within the vehicle having an effectively performing catalyst is always lower than out flowing gas temperature.

  4. Power converters definitions, classification and converter topologies

    CERN Document Server

    Bordry, Frederick

    2006-01-01

    This paper introduces power conversion principles and defines the terminology. The concepts of sources and switches are defined and classified. From the basic laws of source interconnections, a generic method of power converter synthesis is presented. Some examples illustrate this systematic method. Finally, the notions of commutation cell and soft commutation are introduced and discussed.

  5. High efficiency thermionic converter studies

    Science.gov (United States)

    Huffman, F. N.; Sommer, A. H.; Balestra, C. L.; Briere, D. P.; Oettinger, P. E.

    1976-01-01

    The objective is to improve thermionic converter performance by means of reduced interelectrode losses, greater emitter capabilities, and lower collector work functions until the converter performance level is suitable for out-of-core space reactors and radioisotope generators. Electrode screening experiments have identified several promising collector materials. Back emission work function measurements of a ZnO collector in a thermionic diode have given values less than 1.3 eV. Diode tests were conducted over the range of temperatures of interest for space power applications. Enhanced mode converter experiments have included triodes operated in both the surface ionization and plasmatron modes. Pulsed triodes were studied as a function of pulse length, pulse potential, inert gas fill pressure, cesium pressure, spacing, emitter temperature and collector temperature. Current amplifications (i.e., mean output current/mean grid current) of several hundred were observed up to output current densities of one amp/sq cm. These data correspond to an equivalent arc drop less than 0.1 eV.

  6. High speed data converters

    CERN Document Server

    Ali, Ahmed MA

    2016-01-01

    This book covers high speed data converters from the perspective of a leading high speed ADC designer and architect, with a strong emphasis on high speed Nyquist A/D converters. For our purposes, the term 'high speed' is defined as sampling rates that are greater than 10 MS/s.

  7. Electrical Power Converter

    NARCIS (Netherlands)

    Ferreira, J.A.

    2014-01-01

    Electrical power converter for converting electrical power of a power source connected or connectable at an input to electrical DC-power at an output, wherein between the input and the output a first circuit of submodules is provided, wherein said first circuit of submodules and the power source

  8. Digital to Analog Converter

    NARCIS (Netherlands)

    Westra, Jan R.; Annema, Anne J.; van den Boom, Jeroen M.; Dijkmans, Eise C.

    2001-01-01

    A digital to analog converter (DAC) for converting a digital signal (DS) having a maximum voltage range which corresponds to a first supply voltage (UL) into an analog signal (UOUT) having a maximum voltage range which corresponds to a second supply voltage (UH). The first supply voltage (UL) is

  9. Digital to Analog Converter

    NARCIS (Netherlands)

    Westra, Jan R.; Annema, Anne J.; van den Boom, Jeroen M.; Dijkmans, Eise C.

    2006-01-01

    A digital to analog converter (DAC) for converting a digital signal (DS) having a maximum voltage range which corresponds to a first supply voltage (UL) into an analog signal (UOUT) having a maximum voltage range which corresponds to a second supply voltage (UH). The first supply voltage (UL) is

  10. CO2 Activation over Catalytic Surfaces.

    Science.gov (United States)

    Álvarez, Andrea; Borges, Marta; Corral-Pérez, Juan José; Olcina, Joan Giner; Hu, Lingjun; Cornu, Damien; Huang, Rui; Stoian, Dragos; Urakawa, Atsushi

    2017-11-17

    This article describes the main strategies to activate and convert carbon dioxide (CO2 ) into valuable chemicals over catalytic surfaces. Coherent elements such as common intermediates are identified in the different strategies and concisely discussed based on the reactivity of CO2 with the aim to understand the decisive factors for selective and efficient CO2 conversion. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Porous media for catalytic renewable energy conversion

    Science.gov (United States)

    Hotz, Nico

    2012-05-01

    A novel flow-based method is presented to place catalytic nanoparticles into a reactor by sol-gelation of a porous ceramic consisting of copper-based nanoparticles, silica sand, ceramic binder, and a gelation agent. This method allows for the placement of a liquid precursor containing the catalyst into the final reactor geometry without the need of impregnating or coating of a substrate with the catalytic material. The so generated foam-like porous ceramic shows properties highly appropriate for use as catalytic reactor material, e.g., reasonable pressure drop due to its porosity, high thermal and catalytic stability, and excellent catalytic behavior. The catalytic activity of micro-reactors containing this foam-like ceramic is tested in terms of their ability to convert alcoholic biofuel (e.g. methanol) to a hydrogen-rich gas mixture with low concentrations of carbon monoxide (up to 75% hydrogen content and less than 0.2% CO, for the case of methanol). This gas mixture is subsequently used in a low-temperature fuel cell, converting the hydrogen directly to electricity. A low concentration of CO is crucial to avoid poisoning of the fuel cell catalyst. Since conventional Polymer Electrolyte Membrane (PEM) fuel cells require CO concentrations far below 100 ppm and since most methods to reduce the mole fraction of CO (such as Preferential Oxidation or PROX) have CO conversions of up to 99%, the alcohol fuel reformer has to achieve initial CO mole fractions significantly below 1%. The catalyst and the porous ceramic reactor of the present study can successfully fulfill this requirement.

  12. Saturation current spikes eliminated in saturable core transformers

    Science.gov (United States)

    Schwarz, F. C.

    1971-01-01

    Unsaturating composite magnetic core transformer, consisting of two separate parallel cores designed so impending core saturation causes signal generation, terminates high current spike in converter primary circuit. Simplified waveform, demonstrates transformer effectiveness in eliminating current spikes.

  13. Microminiature thermionic converters

    Science.gov (United States)

    King, Donald B.; Sadwick, Laurence P.; Wernsman, Bernard R.

    2001-09-25

    Microminiature thermionic converts (MTCs) having high energy-conversion efficiencies and variable operating temperatures. Methods of manufacturing those converters using semiconductor integrated circuit fabrication and micromachine manufacturing techniques are also disclosed. The MTCs of the invention incorporate cathode to anode spacing of about 1 micron or less and use cathode and anode materials having work functions ranging from about 1 eV to about 3 eV. Existing prior art thermionic converter technology has energy conversion efficiencies ranging from 5-15%. The MTCs of the present invention have maximum efficiencies of just under 30%, and thousands of the devices can be fabricated at modest costs.

  14. Improving Power Converter Reliability

    DEFF Research Database (Denmark)

    Ghimire, Pramod; de Vega, Angel Ruiz; Beczkowski, Szymon

    2014-01-01

    The real-time junction temperature monitoring of a high-power insulated-gate bipolar transistor (IGBT) module is important to increase the overall reliability of power converters for industrial applications. This article proposes a new method to measure the on-state collector?emitter voltage...... of a high-power IGBT module during converter operation, which may play a vital role in improving the reliability of the power converters. The measured voltage is used to estimate the module average junction temperature of the high and low-voltage side of a half-bridge IGBT separately in every fundamental...

  15. Galvanic replacement synthesis of Ag x Au1?x @CeO2 (0 ? x ? 1) core@shell nanospheres with greatly enhanced catalytic performance? ?Electronic supplementary information (ESI) available: Detailed synthesis, XRD patterns, EDX and XPS spectra of Ag x Au1?x @CeO2 core@shell nanospheres. TEM images of Ag@CeO2, and Ag x Au1?x @CeO2 prepared with addition of NaCl. See DOI: 10.1039/c5sc02774h Click here for additional data file. Click here for additional data file.

    OpenAIRE

    Liu, Dapeng; Li, Wang; Feng, Xilan; Zhang, Yu

    2015-01-01

    A galvanic replacement strategy has been successfully adopted to design Ag x Au1?x @CeO2 core@shell nanospheres derived from Ag@CeO2 ones. After etching using HAuCl4, the Ag core was in situ replaced with Ag x Au1?x alloy nanoframes, and void spaces were left under the CeO2 shell. Among the as-prepared Ag x Au1?x @CeO2 catalysts, Ag0.64Au0.36@CeO2 shows the optimal catalytic performance, whose catalytic efficiency reaches even 2.5 times higher than our previously reported Pt@CeO2 nanospheres ...

  16. Microsatellite CONVERT Input File

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Microsatellite data formatted for the software CONVERT, which includes dataset numerical IDs, sampling site names, and locus identifiers. Rows 291-294 provides...

  17. Advanced converter technology

    Science.gov (United States)

    Banic, C. V.; Eckhouse, S. A.; Kornbrust, F. J.; Lifman, K.; Peterson, J. L.; Rosati, R. W.; Young, D.

    An advanced converter system for use in electrochemical energy storge was defined. Improved and experimental apparatus are designed to measure these characteristics and to enable better definition of the battery power conditioner interface. Improvement of energy storage system performance through modification of battery converter characteristics is investigated. Power conditioning based on fuel cell use was evaluated. It is concluded that this high switching frequency concept has the potential for significantly reducing the size and cost of battery plant power conditioners.

  18. Rich catalytic injection

    Science.gov (United States)

    Veninger, Albert [Coventry, CT

    2008-12-30

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  19. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    Science.gov (United States)

    Shore, Lawrence [Edison, NJ; Matlin, Ramail [Berkeley Heights, NJ; Heinz, Robert [Ludwigshafen, DE

    2012-06-26

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  20. Novel Catalytic Reactor for CO2 Reduction via Sabatier Process Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Precision Combustion, Inc. (PCI) proposes to develop a novel, efficient, and lightweight catalytic Sabatier CO2 methanation unit, capable of converting a mixture of...

  1. Catalytic conversion of light alkanes

    Energy Technology Data Exchange (ETDEWEB)

    Lyons, J.E.

    1992-06-30

    The second Quarterly Report of 1992 on the Catalytic Conversion of Light Alkanes reviews the work done between April 1, 1992 and June 31, 1992 on the Cooperative Agreement. The mission of this work is to devise a new catalyst which can be used in a simple economic process to convert the light alkanes in natural gas to oxygenate products that can either be used as clean-burning, high octane liquid fuels, as fuel components or as precursors to liquid hydrocarbon uwspomdon fuel. During the past quarter we have continued to design, prepare, characterize and test novel catalysts for the mild selective reaction of light hydrocarbons with air or oxygen to produce alcohols directly. These catalysts are designed to form active metal oxo (MO) species and to be uniquely active for the homolytic cleavage of the carbon-hydrogen bonds in light alkanes producing intermediates which can form alcohols. We continue to investigate three molecular environments for the active catalytic species that we are trying to generate: electron-deficient macrocycles (PHASE I), polyoxometallates (PHASE II), and regular oxidic lattices including zeolites and related structures as well as other molecular surface structures having metal oxo groups (PHASE I).

  2. SSG Wave Energy Converter

    DEFF Research Database (Denmark)

    Margheritini, Lucia; Vicinanza, Diego; Frigaard, Peter

    2008-01-01

    The SSG (Sea Slot-cone Generator) is a wave energy converter of the overtopping type. The structure consists of a number of reservoirs one on the top of each others above the mean water level, in which the water of incoming waves is stored temporary. In each reservoir, expressively designed low...... head hydroturbines are converting the potential energy of the stored water into power. A key to success for the SSG will be the low cost of the structure and its robustness. The construction of the pilot plant is scheduled and this paper aims to describe the concept of the SSG wave energy converter...... and the studies behind the process that leads to its construction. The pilot plant is an on-shore full scale module in 3 levels with an expected power production of 320 MWh/y in the North Sea. Location, wave climate and laboratory tests results will be used here to describe the pilot plant and its characteristics....

  3. Angiotensin-converting enzyme

    DEFF Research Database (Denmark)

    Sørensen, P G; Rømer, F K; Cortes, D

    1984-01-01

    In order to evaluate bleomycin-associated lung damage in humans, lung function parameters and serum levels of the endothelial-bound angiotensin-converting enzyme (ACE) were determined by serial measurements in 11 patients who were treated for testicular cancer. None developed clinical or radiolog...

  4. Thermionic energy converters

    Science.gov (United States)

    Monroe, Jr., James E.

    1977-08-09

    A thermionic device for converting nuclear energy into electrical energy comprising a tubular anode spaced from and surrounding a cylindrical cathode, the cathode having an outer emitting surface of ruthenium, and nuclear fuel on the inner cylindrical surface. The nuclear fuel is a ceramic composition of fissionable material in a metal matrix. An axial void is provided to collect and contain fission product gases.

  5. Definition of Power Converters

    CERN Document Server

    Bordry, F

    2015-01-01

    The paper is intended to introduce power conversion principles and to define common terms in the domain. The concept s of sources and switches are defined and classified. From the basic laws of source interconnections, a generic method of power converter synthesis is presented. Some examples illustrate this systematic method. Finally, the commutation cell and soft commuta tion are introduced and discussedd.

  6. An Electromagnetic Beam Converter

    DEFF Research Database (Denmark)

    2009-01-01

    The present invention relates to an electromagnetic beam converter and a method for conversion of an input beam of electromagnetic radiation having a bell shaped intensity profile a(x,y) into an output beam having a prescribed target intensity profile l(x',y') based on a further development...

  7. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  8. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  9. Catalytic asymmetric fluorinations.

    Science.gov (United States)

    Bobbio, Carla; Gouverneur, Véronique

    2006-06-07

    The appearance of structurally diverse fluorinating reagents displaying a large spectrum of reactivity has been critical to the development of the catalytic asymmetric fluorination processes known to date. In this article, we discuss how this area of research emerged and which strategies have allowed for the successful development of both nucleophilic and electrophilic catalytic enantioselective fluorinations. We also present the fundamental understanding of catalytic activity and enantioselectivity for the most efficient processes and highlight the first synthetic application with the preparation of a complex fluorinated target.

  10. Integration of Magnetic Components in a Step-Up Converter for Fuel Cell

    DEFF Research Database (Denmark)

    Klimczak, Pawel; Munk-Nielsen, Stig

    2009-01-01

    converter is a critical part. The input voltage of the converter decreases while the output power increases. It creates challenges in design of the converter's magnetic components. Scope of this paper is integration of the dc inductor and the transformer on a single core. Such integration improve...

  11. Boost Converter with Three-State Switching Cell and Integrated Magnetics

    DEFF Research Database (Denmark)

    Klimczak, Pawel; Munk-Nielsen, Stig

    2009-01-01

    Fuel cell systems often require high voltage gain and dc-dc step-up converter is a critical part. Scope of this paper is integration of inductor and transformer on a single core. Usage of integrated magnetics improves utilization of magnetic core and thus size and weight of the converter may...

  12. Analog-to-digital converter has increased reliability and reduced power consumption

    Science.gov (United States)

    Thornwall, J. C.

    1965-01-01

    Eight-bit analog-to-digital converter decreases average power consumption and increases component reliability. The converter uses solid-state components in pulse operation and magnetic core components for minimizing power consumption. The magnetic core components also increase reliability.

  13. Catalytic distillation process

    Science.gov (United States)

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  14. Catalytic distillation structure

    Science.gov (United States)

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  15. The microminiature thermionic converter

    Science.gov (United States)

    King, Donald B.; Luke, James R.; Zavadil, Kevin R.

    2001-02-01

    A new generation of thermionic converter, the microminiature thermionic converter (MTC) has been fabrication using semiconductor integrated circuit (IC) fabrication methods and micromachining manufacturing (MM) techniques. The use of IC and MM techniques allows the fabrication of MTCs with micron scale cathode to anode spacing and with anode and cathode materials which will have work functions ranging from 1 eV to 2.5 eV. The use of small cathode to anode spacing and variable electrode work functions gives the MTC the potential to convert heat energy to relatively large current densities (up to 10s of Amps/cm2) at relatively high conversion efficiencies (~25%), well within the range of high end conventional electrical generation equipment. Tests of prototype MTCs have demonstrated energy conversion at several emitter and collector temperatures. Power generated by the prototype MTC is less than expected because of less than optimal emission characteristics encountered with the low work function materials used for the first MTC prototypes. Work is in progress to improve the thermionic emission characteristics of the low work function electrodes. .

  16. Catalytic fast pyrolysis of lignocellulosic biomass.

    Science.gov (United States)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M; Sun, Junming; Wang, Yong

    2014-11-21

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel-bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating value, high corrosiveness, high viscosity, and instability; they also greatly limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  17. Multilevel converters -- A new breed of power converters

    Energy Technology Data Exchange (ETDEWEB)

    Lai, J.S. [Oak Ridge National Lab., TN (United States). Engineering Technology Div.; Peng, F.Z. [Univ. of Tennessee, Knoxville, TN (United States)]|[Oak Ridge National Lab., TN (United States)

    1995-09-01

    Multilevel voltage source converters are emerging as a new breed of power converter options for high-power applications. The multilevel voltage source converters typically synthesize the staircase voltage wave from several levels of dc capacitor voltages. One of the major limitations of the multilevel converters is the voltage unbalance between different levels. The techniques to balance the voltage between different levels normally involve voltage clamping or capacitor charge control. There are several ways of implementing voltage balance in multilevel converters. Without considering the traditional magnetic coupled converters, this paper presents three recently developed multilevel voltage source converters: (1) diode-clamp, (2) flying-capacitors, and (3) cascaded-inverters with separate dc sources. The operating principle, features, constraints, and potential applications of these converters will be discussed.

  18. Core-shell nanostructured catalysts.

    Science.gov (United States)

    Zhang, Qiao; Lee, Ilkeun; Joo, Ji Bong; Zaera, Francisco; Yin, Yadong

    2013-08-20

    Novel nanotechnologies have allowed great improvements in the syn-thesis of catalysts with well-controlled size, shape, and surface properties. Transition metal nanostructures with specific sizes and shapes, for instance, have shown great promise as catalysts with high selectivities and relative ease of recycling. Researchers have already demonstrated new selective catalysis with solution-dispersed or supported-metal nanocatalysts, in some cases applied to new types of reactions. Several challenges remain, however, particularly in improving the structural stability of the catalytic active phase. Core-shell nanostructures are nanoparticles encapsulated and protected by an outer shell that isolates the nanoparticles and prevents their migration and coalescence during the catalytic reactions. The synthesis and characterization of effective core-shell catalysts has been at the center of our research efforts and is the focus of this Account. Efficient core-shell catalysts require porous shells that allow free access of chemical species from the outside to the surface of nanocatalysts. For this purpose, we have developed a surface-protected etching process to prepare mesoporous silica and titania shells with controllable porosity. In certain cases, we can tune catalytic reaction rates by adjusting the porosity of the outer shell. We also designed and successfully applied a silica-protected calcination method to prepare crystalline shells with high surface area, using anatase titania as a model system. We achieved a high degree of control over the crystallinity and porosity of the anatase shells, allowing for the systematic optimization of their photocatalytic activity. Core-shell nanostructures also provide a great opportunity for controlling the interaction among the different components in ways that might boost structural stability or catalytic activity. For example, we fabricated a SiO₂/Au/N-doped TiO₂ core-shell photocatalyst with a sandwich structure that showed

  19. Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2017-09-12

    A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

  20. Atomically Precise Metal Nanoclusters for Catalytic Application

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Rongchao [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2016-11-18

    The central goal of this project is to explore the catalytic application of atomically precise gold nanoclusters. By solving the total structures of ligand-protected nanoclusters, we aim to correlate the catalytic properties of metal nanoclusters with their atomic/electronic structures. Such correlation unravel some fundamental aspects of nanocatalysis, such as the nature of particle size effect, origin of catalytic selectivity, particle-support interactions, the identification of catalytically active centers, etc. The well-defined nanocluster catalysts mediate the knowledge gap between single crystal model catalysts and real-world conventional nanocatalysts. These nanoclusters also hold great promise in catalyzing certain types of reactions with extraordinarily high selectivity. These aims are in line with the overall goals of the catalytic science and technology of DOE and advance the BES mission “to support fundamental research to understand, predict, and ultimately control matter and energy at the level of electrons, atoms, and molecules”. Our group has successfully prepared different sized, robust gold nanoclusters protected by thiolates, such as Au25(SR)18, Au28(SR)20, Au38(SR)24, Au99(SR)42, Au144(SR)60, etc. Some of these nanoclusters have been crystallographically characterized through X-ray crystallography. These ultrasmall nanoclusters (< 2 nm diameter) exhibit discrete electronic structures due to quantum size effect, as opposed to quasicontinuous band structure of conventional metal nanoparticles or bulk metals. The available atomic structures (metal core plus surface ligands) of nanoclusters serve as the basis for structure-property correlations. We have investigated the unique catalytic properties of nanoclusters (i.e. not observed in conventional nanogold catalysts) and revealed the structure-selectivity relationships. Highlights of our

  1. Performance Evaluation of Waste Plastic Oil Converter

    Directory of Open Access Journals (Sweden)

    Elmo C. Rapsing, Jr.

    2017-05-01

    Full Text Available This research aimed to evaluate the performance of the waste plastic oil converter. The equipment is a prototype model powered by electricity and utilizes a non-catalytic pyrolysis process of converting waste plastic to oil. The primary objective of the study is to identify the type of waste plastic that the equipment can process and determine its performance in terms of conversion efficiency (wt %, waste reduction efficiency (wt % and oil recovery (ml oil/kg waste plastic. The equipment was initially tested for Type 1-Polyethylene Terephthalate, Type 2-High Density Polyethylene, Type 4-Low Density Polyethylene, Type 5-Polypropylene and Type 6 -Polystyrene. It was observed that the equipment is only capable of converting Type 5 and 6 waste plastic into oil. For the performance evaluation of the equipment, 1000g Type 5 and 1000g Type 6 waste plastic were used as feedstock. The experiments were performed separately for each of them. Five trials using 200g per trial for each type of plastic was conducted to test the equipment. The temperature at the bottom of the reactor was set to 4000C and the operating time was 2 hour per trial with 15 minutes cracking time, 1 minute vapor residence time and 1 minute vapor evacuation time. Results show that the conversion efficiency of the equipment for Type 5 was 60.90% and for Type 6 was 83.6%. Waste reduction efficiency was 94.8% for Type 5 and 95.6% for Type 6. The oil recovery of the equipment was 766 ml/kg for Type 5 and 919 ml/kg for Type 6. Thus, the waste plastic oil converter is a potential solution in reducing the amount of plastic waste due to its capability of producing oil out ofwaste Type 5 and Type 6 plastics.

  2. Integrated magnetics design for HF-link power converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, Michael A.E.

    2005-07-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the two integrated magnetic components on the same core do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs. (au)

  3. Proteomics Core

    Data.gov (United States)

    Federal Laboratory Consortium — Proteomics Core is the central resource for mass spectrometry based proteomics within the NHLBI. The Core staff help collaborators design proteomics experiments in a...

  4. X-Y Converter Family

    DEFF Research Database (Denmark)

    Bhaskar, Mahajan Sagar; Sanjeevikumar, Padmanaban; Wheeler, Patrick

    2016-01-01

    A New breed of a buck boost converter, named as the XY converter family is proposed in this article. In the XY family, 16 topologies are presented which are highly suitable for renewable energy applications which require a high ratio of DC-DC converter; such as a photovoltaic multilevel inverter...... system, high voltage automotive applications and industrial drives. Compared to the traditional boost converter and existing recent converters, the proposed XY converter family has the ability to provide a higher output voltage by using less number of power devices and reactive components. Other distinct...... features of the XY converter family are i) Single control switch ii) Provide negative output voltage iii) Non-isolated topologies iv) High conversion ratio without making the use of high duty cycle and v) modular structure. XY family is compared with the recent high step-up converters and the detailed...

  5. Cycloidal Wave Energy Converter

    Energy Technology Data Exchange (ETDEWEB)

    Stefan G. Siegel, Ph.D.

    2012-11-30

    This program allowed further advancing the development of a novel type of wave energy converter, a Cycloidal Wave Energy Converter or CycWEC. A CycWEC consists of one or more hydrofoils rotating around a central shaft, and operates fully submerged beneath the water surface. It operates under feedback control sensing the incoming waves, and converts wave power to shaft power directly without any intermediate power take off system. Previous research consisting of numerical simulations and two dimensional small 1:300 scale wave flume experiments had indicated wave cancellation efficiencies beyond 95%. The present work was centered on construction and testing of a 1:10 scale model and conducting two testing campaigns in a three dimensional wave basin. These experiments allowed for the first time for direct measurement of electrical power generated as well as the interaction of the CycWEC in a three dimensional environment. The Atargis team successfully conducted two testing campaigns at the Texas A&M Offshore Technology Research Center and was able to demonstrate electricity generation. In addition, three dimensional wave diffraction results show the ability to achieve wave focusing, thus increasing the amount of wave power that can be extracted beyond what was expected from earlier two dimensional investigations. Numerical results showed wave cancellation efficiencies for irregular waves to be on par with results for regular waves over a wide range of wave lengths. Using the results from previous simulations and experiments a full scale prototype was designed and its performance in a North Atlantic wave climate of average 30kW/m of wave crest was estimated. A full scale WEC with a blade span of 150m will deliver a design power of 5MW at an estimated levelized cost of energy (LCOE) in the range of 10-17 US cents per kWh. Based on the new results achieved in the 1:10 scale experiments these estimates appear conservative and the likely performance at full scale will

  6. Resonant power converters

    CERN Document Server

    Kazimierczuk, Marian K

    2012-01-01

    This book is devoted to resonant energy conversion in power electronics. It is a practical, systematic guide to the analysis and design of various dc-dc resonant inverters, high-frequency rectifiers, and dc-dc resonant converters that are building blocks of many of today's high-frequency energy processors. Designed to function as both a superior senior-to-graduate level textbook for electrical engineering courses and a valuable professional reference for practicing engineers, it provides students and engineers with a solid grasp of existing high-frequency technology, while acquainting them wit

  7. Straight studs from southern pine veneer cores and cordwood

    Science.gov (United States)

    Peter Koch

    1968-01-01

    An economically feasible system has been developed for converting southern pine veneer cores into straight 8-foot studs (2). Prototype studs - two per core - were 100 percent SPIB stud grade and better.

  8. New active load voltage clamp for HF-link converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, M.A.E.

    2005-07-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core. (au)

  9. Conducted EMI Evaluation and Reduction in a Forward Switching Converter

    Directory of Open Access Journals (Sweden)

    Mohammad Rouhollah Yazdani

    2012-04-01

    Full Text Available In switching power converters, electromagnetic interference (EMI is produced due to the fast changes of the voltage and current. Among switching topologies used in low and medium powers, forward converter is vastly employed which needs resetting transformer core. In this paper, a forward converter with reset winding is modeled to predict conducted EMI. To evaluate the EMI model, EMI measurement results are presented. To select an optimum reset scheme from EMI viewpoint, three reset techniques are compared using experimental results. After selecting the proper reset scheme, two EMI mitigation methods are proposed and the practical EMI reduction is presented.

  10. Ag-Sn Bimetallic Catalyst with a Core-Shell Structure for CO2 Reduction.

    Science.gov (United States)

    Luc, Wesley; Collins, Charles; Wang, Siwen; Xin, Hongliang; He, Kai; Kang, Yijin; Jiao, Feng

    2017-02-08

    Converting greenhouse gas carbon dioxide (CO2) to value-added chemicals is an appealing approach to tackle CO2 emission challenges. The chemical transformation of CO2 requires suitable catalysts that can lower the activation energy barrier, thus minimizing the energy penalty associated with the CO2 reduction reaction. First-row transition metals are potential candidates as catalysts for electrochemical CO2 reduction; however, their high oxygen affinity makes them easy to be oxidized, which could, in turn, strongly affect the catalytic properties of metal-based catalysts. In this work, we propose a strategy to synthesize Ag-Sn electrocatalysts with a core-shell nanostructure that contains a bimetallic core responsible for high electronic conductivity and an ultrathin partially oxidized shell for catalytic CO2 conversion. This concept was demonstrated by a series of Ag-Sn bimetallic electrocatalysts. At an optimal SnOx shell thickness of ∼1.7 nm, the catalyst exhibited a high formate Faradaic efficiency of ∼80% and a formate partial current density of ∼16 mA cm-2 at -0.8 V vs RHE, a remarkable performance in comparison to state-of-the-art formate-selective CO2 reduction catalysts. Density-functional theory calculations showed that oxygen vacancies on the SnO (101) surface are stable at highly negative potentials and crucial for CO2 activation. In addition, the adsorption energy of CO2- at these oxygen-vacant sites can be used as the descriptor for catalytic performance because of its linear correlation to OCHO* and COOH*, two critical intermediates for the HCOOH and CO formation pathways, respectively. The volcano-like relationship between catalytic activity toward formate as a function of the bulk Sn concentration arises from the competing effects of favorable stabilization of OCHO* by lattice expansion and the electron conductivity loss due to the increased thickness of the SnOx layer.

  11. Nanocarbons for Catalytic Desulfurization.

    Science.gov (United States)

    Gu, Qingqing; Lin, Yangming; Heumann, Saskia; Su, Dangsheng

    2017-08-24

    Nanocarbon catalysts are green and sustainable alternatives to metal-based catalysts for numerous catalytic transformations. The application of nanocarbons for environmental catalysis is an emerging research discipline and has undergone rapid development in recent years. In this focus review, we provide a critical analysis of state-of-the-art nanocarbon catalysts for three different catalytic desulfurization processes. In particular, we focus on the advantages and limitations as well as the reaction mechanisms of the nanocarbon catalysts at the molecular level. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. An Experimental Study of Flow and Thermal Transient Response in a Race-Track Monolith Catalytic Converter Etude expérimentale de l'écoulement et de la réponse thermique en régime transitoire dans un pot catalytique muni d'un monolithe de forme ovale

    Directory of Open Access Journals (Sweden)

    Leclerc J. P.

    2006-11-01

    Full Text Available A model for the pressure drop was proposed and compared to experimental results. Global flow characteristics and velocity distribution were studied from residence time distribution measurements in a race-trackmonolith. Significant dead volumes were detected and the velocity distribution was determined. The effect of flow-rate, inlet tube diameter and flow deflector was investigated. Study of the time evolution of outlet temperature and temperature distribution in a monolith coated or not with catalyst makes it possible to determine the thermal characteristics of heat-up. The influence of flow rate, velocity distribution and developing laminar flow regime in the channel were qualitatively estimated. Theses results allow one to determine the hydrodynamic and thermal behavior of the catalytic converter and to propose reliable and realistic assumptions for subsequent modeling. Chaque année, un véhicule de moyenne cylindrée rejette dans l'atmosphère 240 kg de monoxyde de carbone, 40 kg d'oxyde d'azote et 77 kg d'hydrocarbures [1]. Si le moteur propre semble être la meilleure solution pour l'avenir, le pot catalytique est aujourd'hui la seule solution envisageable. Le fonctionnement du pot catalytique est satisfaisant lorsque la voiture roule à une vitesse constante. Cependant, il n'en est pas de même lors du démarrage à froid pendant lequel de nombreux problèmes subsistent, comme le montre la figure 1. Plusieurs modèles ont été développés afin de comprendre et d'améliorer les performances du pot catalytique [2, 3, 11, 12 et 13]. Cependant, suivant les hypothèses faites, ces modèles fournissent des résultats plus ou moins contradictoires. Une étude expérimentale a donc été effectuée afin de mieux cerner les processus qui gouvernent le fonctionnement du pot catalytique et de proposer des hypothèses réalistes pour la modélisation. Un modèle d'estimation de la perte de charge a été proposé et comparé aux résultats exp

  13. Bidirectional DC/DC Converter

    Science.gov (United States)

    Pedersen, F.

    2008-09-01

    The presented bidirectional DC/DC converter design concept is a further development of an already existing converter used for low battery voltage operation.For low battery voltage operation a high efficient low parts count DC/DC converter was developed, and used in a satellite for the battery charge and battery discharge function.The converter consists in a bidirectional, non regulating DC/DC converter connected to a discharge regulating Buck converter and a charge regulating Buck converter.The Bidirectional non regulating DC/DC converter performs with relatively high efficiency even at relatively high currents, which here means up to 35Amps.This performance was obtained through the use of power MOSFET's with on- resistances of only a few mille Ohms connected to a special transformer allowing paralleling several transistor stages on the low voltage side of the transformer. The design is patent protected. Synchronous rectification leads to high efficiency at the low battery voltages considered, which was in the range 2,7- 4,3 Volt DC.The converter performs with low switching losses as zero voltage zero current switching is implemented in all switching positions of the converter.Now, the drive power needed, to switch a relatively large number of low Ohm , hence high drive capacitance, power MOSFET's using conventional drive techniques would limit the overall conversion efficiency.Therefore a resonant drive consuming considerable less power than a conventional drive circuit was implemented in the converter.To the originally built and patent protected bidirectional non regulating DC/DC converter, is added the functionality of regulation.Hereby the need for additional converter stages in form of a Charge Buck regulator and a Discharge Buck regulator is eliminated.The bidirectional DC/DC converter can be used in connection with batteries, motors, etc, where the bidirectional feature, simple design and high performance may be useful.

  14. Fluorescent radiation converter

    Science.gov (United States)

    Viehmann, W. (Inventor)

    1981-01-01

    A fluorescence radiation converter is described which includes a substantially undoped optically transparent substrate and a waveshifter coating deposited on at least one portion of the substrate for absorption of radiation and conversion of fluorescent radiation. The coating is formed to substantially 1000 g/liter of a solvent, 70 to 200 g/liter of an organic polymer, and 0.2 to 25 g/liter of at least one organic fluorescent dye. The incoming incident radiation impinges on the coating. Radiation is absorbed by the fluorescent dye and is re-emitted as a longer wavelength radiation. Radiation is trapped within the substrate and is totally internally reflected by the boundary surface. Emitted radiation leaves the substrate ends to be detected.

  15. Electromagnetic wave energy converter

    Science.gov (United States)

    Bailey, R. L. (Inventor)

    1973-01-01

    Electromagnetic wave energy is converted into electric power with an array of mutually insulated electromagnetic wave absorber elements each responsive to an electric field component of the wave as it impinges thereon. Each element includes a portion tapered in the direction of wave propagation to provide a relatively wideband response spectrum. Each element includes an output for deriving a voltage replica of the electric field variations intercepted by it. Adjacent elements are positioned relative to each other so that an electric field subsists between adjacent elements in response to the impinging wave. The electric field results in a voltage difference between adjacent elements that is fed to a rectifier to derive dc output power.

  16. CATALYTIC KINETIC SPECTROPHOTOMETRIC DETERMINATION ...

    African Journals Online (AJOL)

    Based on the property that in 0.12 M sulfuric acid medium titanium(IV) catalyzes the discoloring reaction of DBS-arsenazo oxidized by potassium bromate, a new catalytic kinetic spectrophotometric method for the determination of trace titanium (IV) was developed. The linear range of the determination of titanium is

  17. CATALYTIC KINETIC SPECTROPHOTOMETRIC DETERMINATION ...

    African Journals Online (AJOL)

    Preferred Customer

    Research Center for Nanotechnology, Changchun University of Science and Technology,. Changchun 130022 ... Although catalytic kinetic spectrophotometry has been used in the determination of copper, the selectivity ... In this paper CPApA was used as the chromogenic agent, H2O2 as the oxidant, Cu(II) as the catalyst.

  18. Integrated power electronic converters and digital control

    CERN Document Server

    Emadi, Ali; Nie, Zhong

    2009-01-01

    Non-isolated DC-DC ConvertersBuck ConverterBoost ConverterBuck-Boost ConverterIsolated DC-DC ConvertersFlyback ConverterForward ConverterPush-Pull ConverterFull-Bridge ConverterHalf-Bridge ConverterPower Factor CorrectionConcept of PFCGeneral Classification of PFC CircuitsHigh Switching Frequency Topologies for PFCApplication of PFC in Advanced Motor DrivesIntegrated Switched-Mode Power ConvertersSwitched-Mode Power SuppliesThe Concept of Integrated ConverterDefinition of Integrated Switched-Mode Power Supplies (ISMPS)Boost-Type Integrated TopologiesGeneral Structure of Boost-Type Integrated T

  19. Advanced power electronics converters PWM converters processing AC voltages

    CERN Document Server

    dos Santos, Euzeli

    2014-01-01

    This book covers power electronics, in depth, by presenting the basic principles and application details, which can be used both as a textbook and reference book.  Introduces a new method to present power electronics converters called Power Blocks Geometry. Applicable for courses focusing on power electronics, power electronics converters, and advanced power converters. Offers a comprehensive set of simulation results to help understand the circuits presented throughout the book

  20. Bimetallic Nanoparticles in Alternative Solvents for Catalytic Purposes

    Directory of Open Access Journals (Sweden)

    Trung Dang-Bao

    2017-07-01

    Full Text Available Bimetallic nanoparticles represent attractive catalytic systems thanks to the synergy between both partners at the atomic level, mainly induced by electronic effects which in turn are associated with the corresponding structures (alloy, core-shell, hetero-dimer. This type of engineered material can trigger changes in the kinetics of catalyzed processes by variations on the electrophilicity/nucleophilicity of the metal centers involved and also promote cooperative effects to foster organic transformations, including multi-component and multi-step processes. Solvents become a crucial factor in the conception of catalytic processes, not only due to their environmental impact, but also because they can preserve the bimetallic structure during the catalytic reaction and therefore increase the catalyst life-time. In this frame, the present review focuses on the recent works described in the literature concerning the synthesis of bimetallic nanoparticles in non-conventional solvents, i.e., other than common volatile compounds, for catalytic applications.

  1. Impedance source power electronic converters

    CERN Document Server

    Liu, Yushan; Ge, Baoming; Blaabjerg, Frede; Ellabban, Omar; Loh, Poh Chiang

    2016-01-01

    Impedance Source Power Electronic Converters brings together state of the art knowledge and cutting edge techniques in various stages of research related to the ever more popular impedance source converters/inverters. Significant research efforts are underway to develop commercially viable and technically feasible, efficient and reliable power converters for renewable energy, electric transportation and for various industrial applications. This book provides a detailed understanding of the concepts, designs, controls, and application demonstrations of the impedance source converters/inverters. Key features: Comprehensive analysis of the impedance source converter/inverter topologies, including typical topologies and derived topologies. Fully explains the design and control techniques of impedance source converters/inverters, including hardware design and control parameter design for corresponding control methods. Presents the latest power conversion solutions that aim to advance the role of pow...

  2. Impedance Source Power Electronic Converters

    DEFF Research Database (Denmark)

    Liu, Yushan; Abu-Rub, Haitham; Ge, Baoming

    control methods. Presents the latest power conversion solutions that aim to advance the role of power electronics into industries and sustainable energy conversion systems. Compares impedance source converter/inverter applications in renewable energy power generation and electric vehicles as well......Impedance Source Power Electronic Converters brings together state of the art knowledge and cutting edge techniques in various stages of research related to the ever more popular impedance source converters/inverters. Significant research efforts are underway to develop commercially viable...

  3. Integrated Current Balancing Transformer for Primary Parallel Isolated Boost Converter

    DEFF Research Database (Denmark)

    Sen, Gökhan; Ouyang, Ziwei; Thomsen, Ole Cornelius

    2011-01-01

    A simple, PCB compatible integrated solution is proposed for the current balancing requirement of the primary parallel isolated boost converter (PPIBC). Input inductor and the current balancing transformer are merged into the same core, which reduces the number of components allowing a cheaper...

  4. Ice cores

    DEFF Research Database (Denmark)

    Svensson, Anders

    2014-01-01

    Ice cores from Antarctica, from Greenland, and from a number of smaller glaciers around the world yield a wealth of information on past climates and environments. Ice cores offer unique records on past temperatures, atmospheric composition (including greenhouse gases), volcanism, solar activity......, dustiness, and biomass burning, among others. In Antarctica, ice cores extend back more than 800,000 years before present (Jouzel et al. 2007), whereas. Greenland ice cores cover the last 130,000 years...

  5. Les procédés ASVAHL thermiques et catalytiques sous pression d'hydrogène pour la conversion des bruts lourds et des résidus de bruts classiques Thermal and Catalytic Asvahl Processes under Hydrogen Pressure for Converting Heavy Crudes and Conventional Residues

    Directory of Open Access Journals (Sweden)

    Peries J. P.

    2006-11-01

    Full Text Available Cet article décrit les performances comparées des procédés ASVAHL thermiques (TERVAHL T, TERVAHL H, TERVAHL HC et catalytiques (HYVAHL F, HYVAHL C dans deux cas de traitement: - brut désessencié Boscan (base des études objectif Transport; - résidu sous vide Safaniya (base des études Raffinage de résidu. A travers ces résultats, l'importance de la quantité d'hydrogène fixée est mise en évidence. Elle joue sur la conversion obtenue et sur la qualité des résidus. L'introduction de catalyseur soluble ou en suspension catalytique TERVAHL HC (hydroviscoréduction catalytique ou l'utilisation d'un catalyseur supporté (hydrotraiternent HYVAHL favorisent l'activation de l'hydrogène. C'est la combinaison des réactions de craquage, de polycondensation et d'hydrogénation, et les conditions opératoires (températures, temps de séjour et pression qui définiront les limites de la conversion pour une stabilité donnée des résidus. This article describes the comparative performances of thermal ASVAHL processes (TERVAHL T, TERVAHL H, TERVAHL HQ and catalytic ASVAHL processes (HYVAHL F, HYVAHL C for two types of processing: (1 degasolined Boscan crude (basis of studies for transportation feasibility, and (2 Safaniya vacuum residue (basis of studies for residue refining. The results reveal the importance of the amount of fixed hydrogen, which affects the conversion obtained and the quality of the residues. The introduction of a TERVAHL HC soluble catalyst or one in catalytic suspension (catalytic hydrovisbreaking or the use of a supported catalyst (HYVAHL hydrotreatment enhances the activation of hydrogen. The combination of cracking, polycondensation and hydrogen reactions together with the operating conditions (temperatures, residence time and pressure are what will define the conversion limits for a given stability of residues.

  6. Selective Catalytic Reduction Study with Alternative Reducing Agents

    OpenAIRE

    Lourenco, AAD; Martins, CA; Lacava, PT; Ferreira, MA

    2013-01-01

    Diesel engine technology has been driven by increasingly stringent environmental legislation. To comply with these laws, emissions-control systems are being rapidly improved. Within this context, development of exhaust gas after-treatment systems undertakes a significant role. Among the techniques used is selective catalytic reduction (SCR), which converts nitrogen oxides (NOx) into diatomic nitrogen (N-2) and water (H2O). A reducing agent containing ammonia (NH3) is added to the flow and abs...

  7. A critical view on catalytic pyrolysis of biomass.

    Science.gov (United States)

    Venderbosch, R H

    2015-04-24

    The rapid heating of biomass in an oxygen-free environment optimizes the yield of fast-pyrolysis liquids. This liquid comprises a mix of acids, (dehydrated) carbohydrates, aldehydes, ketones, lignin fragments, aromatics, and alcohols, limiting its use. Deoxygenation of these liquids to replace hydrocarbons represents significant challenges. Catalytic pyrolysis is seen as a promising route to yield liquids with a higher quality. In this paper, literature data on catalytic fast pyrolysis of biomass are reviewed and deoxygenation results correlated with the overall carbon yield. Evidence is given that in an initial stage of the catalytic process reactive components are converted to coke, gas, and water, and only to a limited extent to a liquid product. Catalysts are not yet good enough, and an appropriate combination of pyrolysis conditions, reactive products formed, and different reactions to take place to yield improved quality liquids may be practically impossible. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Catalytic partial oxidation of methanol and ethanol for hydrogen generation.

    Science.gov (United States)

    Hohn, Keith L; Lin, Yu-Chuan

    2009-01-01

    Hydrogen-powered fuel cell vehicles feature high energy efficiency and minor environmental impact. Liquid fuels are ideal hydrogen carriers, which can catalytically be converted into syngas or hydrogen to power vehicles. Among the potential liquid fuels, alcohols have several advantages. The hydrogen/carbon ratio is higher than that of other liquid hydrocarbons or oxygenates, especially in the case of methanol. In addition, alcohols can be derived from renewable biomass resources. Catalytic partial oxidation of methanol or ethanol offers immense potential for onboard hydrogen generation due to its rapid reaction rate and exothermic nature. These benefits stimulate a burgeoning research community in catalyst design, reaction engineering, and mechanistic investigation. The purpose of this Minireview is to provide insight into syngas and hydrogen production from methanol and ethanol partial oxidation, particularly highlighting catalytic chemistry.

  9. Uncovering Biphasic Catalytic Mode of C5-epimerase in Heparan Sulfate Biosynthesis*

    Science.gov (United States)

    Sheng, Juzheng; Xu, Yongmei; Dulaney, Steven B.; Huang, Xuefei; Liu, Jian

    2012-01-01

    Heparan sulfate (HS), a highly sulfated polysaccharide, is biosynthesized through a pathway involving several enzymes. C5-epimerase (C5-epi) is a key enzyme in this pathway. C5-epi is known for being a two-way catalytic enzyme, displaying a “reversible” catalytic mode by converting a glucuronic acid to an iduronic acid residue, and vice versa. Here, we discovered that C5-epi can also serve as a one-way catalyst to convert a glucuronic acid to an iduronic acid residue, displaying an “irreversible” catalytic mode. Our data indicated that the reversible or irreversible catalytic mode strictly depends on the saccharide substrate structures. The biphasic mode of C5-epi offers a novel mechanism to regulate the biosynthesis of HS with the desired biological functions. PMID:22528493

  10. Impedance Source Power Electronic Converters

    DEFF Research Database (Denmark)

    Liu, Yushan; Abu-Rub, Haitham; Ge, Baoming

    control methods. Presents the latest power conversion solutions that aim to advance the role of power electronics into industries and sustainable energy conversion systems. Compares impedance source converter/inverter applications in renewable energy power generation and electric vehicles as well......Impedance Source Power Electronic Converters brings together state of the art knowledge and cutting edge techniques in various stages of research related to the ever more popular impedance source converters/inverters. Significant research efforts are underway to develop commercially viable...... and technically feasible, efficient and reliable power converters for renewable energy, electric transportation and for various industrial applications. This book provides a detailed understanding of the concepts, designs, controls, and application demonstrations of the impedance source converters/inverters. Key...

  11. Impedance Source Power Electronic Converters

    DEFF Research Database (Denmark)

    Liu, Yushan; Abu-Rub, Haitham; Ge, Baoming

    and technically feasible, efficient and reliable power converters for renewable energy, electric transportation and for various industrial applications. This book provides a detailed understanding of the concepts, designs, controls, and application demonstrations of the impedance source converters/inverters. Key......Impedance Source Power Electronic Converters brings together state of the art knowledge and cutting edge techniques in various stages of research related to the ever more popular impedance source converters/inverters. Significant research efforts are underway to develop commercially viable...... control methods. Presents the latest power conversion solutions that aim to advance the role of power electronics into industries and sustainable energy conversion systems. Compares impedance source converter/inverter applications in renewable energy power generation and electric vehicles as well...

  12. Radiation tolerant power converter controls

    CERN Document Server

    Todd, B; King, Q; Uznanski, S

    2012-01-01

    The Large Hadron Collider (LHC) at the European Organisation for Nuclear Research (CERN) is the world's most powerful particle collider. The LHC has several thousand magnets, both warm and super-conducting, which are supplied with current by power converters. Each converter is controlled by a purpose-built electronic module called a Function Generator Controller (FGC). The FGC allows remote control of the power converter and forms the central part of a closed-loop control system where the power converter voltage is set, based on the converter output current and magnet-circuit characteristics. Some power converters and FGCs are located in areas which are exposed to beam-induced radiation. There are numerous radiation induced effects, some of which lead to a loss of control of the power converter, having a direct impact upon the accelerator's availability. Following the first long shut down (LS1), the LHC will be able to run with higher intensity beams and higher beam energy. This is expected to lead to signifi...

  13. New fault tolerant matrix converter

    Energy Technology Data Exchange (ETDEWEB)

    Ibarra, Edorta; Andreu, Jon; Kortabarria, Inigo; Ormaetxea, Enekoitz; Alegria, Inigo Martinez de; Martin, Jose Luis [Department of Electronics and Telecommunications, University of the Basque Country, Alameda de Urquijo s/n, E-48013 Bilbao (Spain); Ibanez, Pedro [TECNALIA, Energy Unit, Parque Tecnologico de Zamudio, E-48170 Bizkaia (Spain)

    2011-02-15

    The matrix converter (MC) presents a promising topology that will have to overcome certain barriers (protection systems, durability, the development of converters for real applications, etc.) in order to gain a foothold in the industry. In some applications, where continuous operation must be insured in the case of a system failure, improved reliability of the converter is of particular importance. In this sense, this article focuses on the study of a fault tolerant MC. The fault tolerance of a converter is characterized by its total or partial response in the case of a breakage of any of its components. Taking into consideration that virtually no work has been done on fault tolerant MCs, this paper describes the most important studies in this area. Moreover, a new method is proposed for detecting the breakage of MC semiconductors. Likewise, a new variation of SVM modulation with failure tolerance capacity is presented. This guarantees the continuous operation of the converter and the pseudo-optimum control of a PMSM. This paper also proposes a novel MC topology, which allows the flexible reconfiguration of this converter, when one or several of its semiconductors are damaged. In this way, the MC can continue operating at 100% of its performance without having to double its resources. In this way, it can be said that the solution described in this article represents a step forward towards the development of reliable matrix converters for real applications. (author)

  14. Wideband Monolithic Microwave Integrated Circuit Frequency Converters with GaAs mHEMT Technology

    DEFF Research Database (Denmark)

    Krozer, Viktor; Johansen, Tom Keinicke; Djurhuus, Torsten

    2005-01-01

    We present monolithic microwave integrated circuit (MMIC) frequency converter, which can be used for up and down conversion, due to the large RF and IF port bandwidth. The MMIC converters are based on commercially available GaAs mHEMT technology and are comprised of a Gilbert mixer cell core...

  15. Catalytic reforming methods

    Science.gov (United States)

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  16. Multilevel converters for industrial applications

    CERN Document Server

    Gonzalez, Sergio Alberto

    2013-01-01

    Modern semiconductor devices have reached high current and voltage levels, and their power-handling limits can be extended if they are used in multilevel converter configurations. To create high-performance and reliable control designs, however, engineers need in-depth understanding of the characteristics and operation of these topologies. Multilevel Converters for Industrial Applications presents a thorough and comprehensive analysis of multilevel converters with a common DC voltage source. The book offers a novel perspective to help readers understand the principles of the operation of volta

  17. Impedance Source Power Electronic Converters

    DEFF Research Database (Denmark)

    Liu, Yushan; Abu-Rub, Haitham; Ge, Baoming

    and technically feasible, efficient and reliable power converters for renewable energy, electric transportation and for various industrial applications. This book provides a detailed understanding of the concepts, designs, controls, and application demonstrations of the impedance source converters/inverters. Key...... control methods. Presents the latest power conversion solutions that aim to advance the role of power electronics into industries and sustainable energy conversion systems. Compares impedance source converter/inverter applications in renewable energy power generation and electric vehicles as well...... as different industrial applications. Provides an overview of existing challenges, solutions and future trends. Supported by calculation examples, simulation models and results....

  18. Processes for converting lignocellulosics to reduced acid pyrolysis oil

    Science.gov (United States)

    Kocal, Joseph Anthony; Brandvold, Timothy A

    2015-01-06

    Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.

  19. Urinary catalytic iron in obesity

    National Research Council Canada - National Science Library

    Thethi, Tina K; Parsha, Kaushik; Rajapurkar, Mohan; Mukhopadhyay, Banibrata; Shah, Sudhir; Yau, C Lillian; Japa, Shanker; Fonseca, Vivian

    2011-01-01

    ...), hypertension, and chronic kidney disease. Catalytic iron, which has been associated with these chronic diseases, may be one of the links between obesity and these multifactorial diverse disorders...

  20. Catalytic combustion in small wood burning appliances

    Energy Technology Data Exchange (ETDEWEB)

    Oravainen, H. [VTT Energy, Jyvaeskylae (Finland)

    1996-12-31

    There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

  1. Wind/water energy converter

    Science.gov (United States)

    Paulkovich, J.

    1979-01-01

    Device will convert wind, water, tidal or wave energy into electrical or mechanical energy. Is comprised of windmill-like paddles or blades synchronously geared to orient themselves to wind direction for optimum energy extraction.

  2. Time-to-digital converters

    CERN Document Server

    Henzler, Stephan

    2010-01-01

    This text covers the fundamentals of time-to-digital converters on analog and digital conversion principles. It includes a theoretical investigation into quantization, linearity, noise and variability, and it details a range of advanced TDC architectures.

  3. Analog-to-digital converter

    Science.gov (United States)

    Lewyn, L. L. (Inventor)

    1965-01-01

    An analog to digital converter circuit arrangement is reported that is suitable for use in ultra fast pulse height analysis. The circuit uses series connected tunnel diodes to quantize a voltage signal into discrete levels.

  4. Laser system with wavelength converter

    DEFF Research Database (Denmark)

    2012-01-01

    The present invention relates to an apparatus comprising a diode laser (10) providing radiation in a first wavelength interval, a radiation conversion unit (12) having an input and an output, the radiation converter configured to receive the radiation in the first wavelength interval from the diode...... laser at the input, the radiation conversion unit configured to convert the radiation in the first wavelength interval to radiation in a second wavelength interval and the output configured to output the converted radiation, the second wavelength interval having one end point outside the first...... wavelength interval. Further, the invention relates to a method of optically pumping a target laser (14) in a laser system, the laser system comprising a laser source providing radiation at a first frequency, the laser source being optically connected to an input of a frequency converter, the frequency...

  5. Novel Catalytic Membrane Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Stuart Nemser, PhD

    2010-10-01

    There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

  6. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2008-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  7. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2010-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  8. Radiation tolerant power converter controls

    Science.gov (United States)

    Todd, B.; Dinius, A.; King, Q.; Uznanski, S.

    2012-11-01

    The Large Hadron Collider (LHC) at the European Organisation for Nuclear Research (CERN) is the world's most powerful particle collider. The LHC has several thousand magnets, both warm and super-conducting, which are supplied with current by power converters. Each converter is controlled by a purpose-built electronic module called a Function Generator Controller (FGC). The FGC allows remote control of the power converter and forms the central part of a closed-loop control system where the power converter voltage is set, based on the converter output current and magnet-circuit characteristics. Some power converters and FGCs are located in areas which are exposed to beam-induced radiation. There are numerous radiation induced effects, some of which lead to a loss of control of the power converter, having a direct impact upon the accelerator's availability. Following the first long shut down (LS1), the LHC will be able to run with higher intensity beams and higher beam energy. This is expected to lead to significantly increased radiation induced effects in materials close to the accelerator, including the FGC. Recent radiation tests indicate that the current FGC would not be sufficiently reliable. A so-called FGClite is being designed to work reliably in the radiation environment in the post-LS1 era. This paper outlines the concepts of power converter controls for machines such as the LHC, introduces the risks related to radiation and a radiation tolerant project flow. The FGClite is then described, with its key concepts and challenges: aiming for high reliability in a radiation field.

  9. Boron nitride converted carbon fiber

    Science.gov (United States)

    Rousseas, Michael; Mickelson, William; Zettl, Alexander K.

    2016-04-05

    This disclosure provides systems, methods, and apparatus related to boron nitride converted carbon fiber. In one aspect, a method may include the operations of providing boron oxide and carbon fiber, heating the boron oxide to melt the boron oxide and heating the carbon fiber, mixing a nitrogen-containing gas with boron oxide vapor from molten boron oxide, and converting at least a portion of the carbon fiber to boron nitride.

  10. Current status of converter steelmaking

    Energy Technology Data Exchange (ETDEWEB)

    Oghbasialasie, H.; Holappa, L.

    1995-12-31

    This literature work is mainly focusing on the mechanisms of modern converter steelmaking and related with the evaluation of converter technology applied during the last decades and further to the future. The history of steelmaking has been briefly reviewed from bloomeries and early-steelmaking processes to the progress of modern converter process. The pneumatic converter processes were developed in the 1850`s and thereafter the basis for the rapid growth of steel industries was established for the next 100 years. The world production of steel has not continuously grown but fluctuating quite much. It reached 723 Mt in 1994. The production is believed to grow the forecast for the year 2003 being approximately 800 Mt. Electric arc furnace production is estimated to reach 280 Mt by 2003, and BOFIOH will reach 520 Mt by 2003. The current status of the converter steelmaking process is briefly described both on its theoretical bases and practical technological progresses. Developments which significantly improve the process are briefly discussed. Several more recent developments such as combined oxygen blowing process, increased scrap melting, post combustion and hot metal pretreatment are discussed. The future progress will be in further development of these process characteristics as well as in eventual emerging of the continuous converter process. (author)

  11. Loss of collectrin, an angiotensin-converting enzyme 2 homolog, uncouples endothelial nitric oxide synthase and causes hypertension and vascular dysfunction

    DEFF Research Database (Denmark)

    Cechova, Sylvia; Zeng, Qing; Billaud, Marie

    2013-01-01

    Collectrin is an orphan member of the renin-angiotensin system and is a homolog of angiotensin-converting enzyme 2, sharing ≈50% sequence identity. Unlike angiotensin-converting enzyme 2, collectrin lacks any catalytic domain. Collectrin has been shown to function as a chaperone of amino acid tra...

  12. Converting energy from fusion into useful forms

    CERN Document Server

    Kovari, M; Jenkins, I; Kiely, C

    2014-01-01

    If fusion power reactors are to be feasible, it will still be necessary to convert the energy of the nuclear reaction into usable form. The heat produced will be removed from the reactor core by a primary coolant, which might be water, helium, molten lithium-lead, molten lithium-containing salt, or CO2. The heat could then be transferred to a conventional Rankine cycle or Brayton (gas turbine) cycle. Alternatively it could be used for thermochemical processes such as producing hydrogen or other transport fuels. Fusion presents new problems because of the high energy neutrons released. These affect the selection of materials and the operating temperature, ultimately determining the choice of coolant and working cycle. The limited temperature ranges allowed by present day irradiated structural materials, combined with the large internal power demand of the plant, will limit the overall thermal efficiency. The operating conditions of the fusion power source, the materials, coolant, and energy conversion system w...

  13. Engineering reactors for catalytic reactions

    Indian Academy of Sciences (India)

    Extensive studies have been conducted to establish sound basis for design and engineering of reactors for practising such catalytic reactions and for realizing improvements in reactor performance. In this article, application of recent (and not so recent) developments in engineering reactors for catalytic reactions is ...

  14. The Simulation of DFIG Grid Side Converter

    National Research Council Canada - National Science Library

    LU Yan-Ling; LU Jian-qiang; BAO Jie

    2017-01-01

    Firstly,DFIG basic structure of grid side converter was analyzed according to basic principles of voltage converter, and a mathematical model of grid side converter was established in the three-phase...

  15. Evolution of random catalytic networks

    Energy Technology Data Exchange (ETDEWEB)

    Fraser, S.M. [Santa Fe Inst., NM (United States); Reidys, C.M. [Santa Fe Inst., NM (United States)]|[Los Alamos National Lab., NM (United States)

    1997-06-01

    In this paper the authors investigate the evolution of populations of sequences on a random catalytic network. Sequences are mapped into structures, between which are catalytic interactions that determine their instantaneous fitness. The catalytic network is constructed as a random directed graph. They prove that at certain parameter values, the probability of some relevant subgraphs of this graph, for example cycles without outgoing edges, is maximized. Populations evolving under point mutations realize a comparatively small induced subgraph of the complete catalytic network. They present results which show that populations reliably discover and persist on directed cycles in the catalytic graph, though these may be lost because of stochastic effects, and study the effect of population size on this behavior.

  16. Catalytic Combustion of Gasified Waste

    Energy Technology Data Exchange (ETDEWEB)

    Kusar, Henrik

    2003-09-01

    This thesis concerns catalytic combustion for gas turbine application using a low heating-value (LHV) gas, derived from gasified waste. The main research in catalytic combustion focuses on methane as fuel, but an increasing interest is directed towards catalytic combustion of LHV fuels. This thesis shows that it is possible to catalytically combust a LHV gas and to oxidize fuel-bound nitrogen (NH{sub 3}) directly into N{sub 2} without forming NO{sub x} The first part of the thesis gives a background to the system. It defines waste, shortly describes gasification and more thoroughly catalytic combustion. The second part of the present thesis, paper I, concerns the development and testing of potential catalysts for catalytic combustion of LHV gases. The objective of this work was to investigate the possibility to use a stable metal oxide instead of noble metals as ignition catalyst and at the same time reduce the formation of NO{sub x} In paper II pilot-scale tests were carried out to prove the potential of catalytic combustion using real gasified waste and to compare with the results obtained in laboratory scale using a synthetic gas simulating gasified waste. In paper III, selective catalytic oxidation for decreasing the NO{sub x} formation from fuel-bound nitrogen was examined using two different approaches: fuel-lean and fuel-rich conditions. Finally, the last part of the thesis deals with deactivation of catalysts. The various deactivation processes which may affect high-temperature catalytic combustion are reviewed in paper IV. In paper V the poisoning effect of low amounts of sulfur was studied; various metal oxides as well as supported palladium and platinum catalysts were used as catalysts for combustion of a synthetic gas. In conclusion, with the results obtained in this thesis it would be possible to compose a working catalytic system for gas turbine application using a LHV gas.

  17. Modeling of asymmetrical boost converters

    Directory of Open Access Journals (Sweden)

    Eliana Isabel Arango Zuluaga

    2014-01-01

    Full Text Available The asymmetrical interleaved dual boost (AIDB is a fifth-order DC/DC converter designed to interface photovoltaic (PV panels. The AIDB produces small current harmonics to the PV panels, reducing the power losses caused by the converter operation. Moreover, the AIDB provides a large voltage conversion ratio, which is required to step-up the PV voltage to the large dc-link voltage used in grid-connected inverters. To reject irradiance and load disturbances, the AIDB must be operated in a closed-loop and a dynamic model is required. Given that the AIDB converter operates in Discontinuous Conduction Mode (DCM, classical modeling approaches based on Continuous Conduction Mode (CCM are not valid. Moreover, classical DCM modeling techniques are not suitable for the AIDB converter. Therefore, this paper develops a novel mathematical model for the AIDB converter, which is suitable for control-pur-poses. The proposed model is based on the calculation of a diode current that is typically disregarded. Moreover, because the traditional correction to the second duty cycle reported in literature is not effective, a new equation is designed. The model accuracy is contrasted with circuital simulations in time and frequency domains, obtaining satisfactory results. Finally, the usefulness of the model in control applications is illustrated with an application example.

  18. Modeling of asymmetrical boost converters

    Directory of Open Access Journals (Sweden)

    Eliana Isabel Arango Zuluaga

    2014-03-01

    Full Text Available The asymmetrical interleaved dual boost (AIDB is a fifth-order DC/DC converter designed to interface photovoltaic (PV panels. The AIDB produces small current harmonics to the PV panels, reducing the power losses caused by the converter operation. Moreover, the AIDB provides a large voltage conversion ratio, which is required to step-up the PV voltage to the large dc-link voltage used in grid-connected inverters. To reject irradiance and load disturbances, the AIDB must be operated in a closed-loop and a dynamic model is required. Given that the AIDB converter operates in Discontinuous Conduction Mode (DCM, classical modeling approaches based on Continuous Conduction Mode (CCM are not valid. Moreover, classical DCM modeling techniques are not suitable for the AIDB converter. Therefore, this paper develops a novel mathematical model for the AIDB converter, which is suitable for control-pur-poses. The proposed model is based on the calculation of a diode current that is typically disregarded. Moreover, because the traditional correction to the second duty cycle reported in literature is not effective, a new equation is designed. The model accuracy is contrasted with circuital simulations in time and frequency domains, obtaining satisfactory results. Finally, the usefulness of the model in control applications is illustrated with an application example.

  19. Core BPEL

    DEFF Research Database (Denmark)

    Hallwyl, Tim; Højsgaard, Espen

    extensions. Combined with the fact that the language definition does not provide a formal semantics, it is an arduous task to work formally with the language (e.g. to give an implementation). In this paper we identify a core subset of the language, called Core BPEL, which has fewer and simpler constructs......, does not allow omissions, and does not contain ignorable elements. We do so by identifying syntactic sugar, including default values, and ignorable elements in WS-BPEL. The analysis results in a translation from the full language to the core subset. Thus, we reduce the effort needed for working...... formally with WS-BPEL, as one, without loss of generality, need only consider the much simpler Core BPEL. This report may also be viewed as an addendum to the WS-BPEL standard specification, which clarifies the WS-BPEL syntax and presents the essential elements of the language in a more concise way...

  20. Ice Cores

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Records of past temperature, precipitation, atmospheric trace gases, and other aspects of climate and environment derived from ice cores drilled on glaciers and ice...

  1. Core benefits

    National Research Council Canada - National Science Library

    Keith, Brian W

    2010-01-01

    This SPEC Kit explores the core employment benefits of retirement, and life, health, and other insurance -benefits that are typically decided by the parent institution and often have significant governmental regulation...

  2. Conceptual study of advanced PWR core design

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Jin; Chang, Moon Hee; Kim, Keung Ku; Joo, Hyung Kuk; Kim, Young Il; Noh, Jae Man; Hwang, Dae Hyun; Kim, Taek Kyum; Yoo, Yon Jong

    1997-09-01

    The purpose of this project is for developing and verifying the core design concepts with enhanced safety and economy, and associated methodologies for core analyses. From the study of the sate-of-art of foreign advanced reactor cores, we developed core concepts such as soluble boron free, high convertible and enhanced safety core loaded semi-tight lattice hexagonal fuel assemblies. To analyze this hexagonal core, we have developed and verified some neutronic and T/H analysis methodologies. HELIOS code was adopted as the assembly code and HEXFEM code was developed for hexagonal core analysis. Based on experimental data in hexagonal lattices and the COBRA-IV-I code, we developed a thermal-hydraulic analysis code for hexagonal lattices. Using the core analysis code systems developed in this project, we designed a 600 MWe core and studied the feasibility of the core concepts. Two additional scopes were performed in this project : study on the operational strategies of soluble boron free core and conceptual design of large scale passive core. By using the axial BP zoning concept and suitable design of control rods, this project showed that it was possible to design a soluble boron free core in 600 MWe PWR. The results of large scale core design showed that passive concepts and daily load follow operation could be practiced. (author). 15 refs., 52 tabs., 101 figs.

  3. Hollow Core?

    Science.gov (United States)

    Qiao, G. J.; Liu, J. F.; Wang, Yang; Wu, X. J.; Han, J. L.

    We carried out the Gaussian fitting to the profile of PSR B1237+25 and found that six components rather than five are necessary to make a good fit. In the central part, we found that the core emission is not filled pencil beam but is a small hollow cone. This implies that the impact angle could be $\\beta<0.5^\\circ$. The ``hollow core'' is in agreement with Inverse Compton Scattering model of radio pulsars.

  4. The Boost Converter – Revisited

    Directory of Open Access Journals (Sweden)

    Barry W. Williams

    2015-12-01

    Full Text Available The dc-to-dc boost converter is a single-switch, single-inductor, switching circuit used to efficiently transform energy from one dc voltage level to a greater voltage level of the same relative polarity. For a specific resistive load range, as the duty cycle decreases, the boost converter inductor enters a discontinuous current mode of operation - the output load current having decreased to a definable level. This paper analyses the fact that a further reduction of load current, as the duty cycle decreases towards zero, will always result in the re-emergence of a continuous inductor current condition. Further, at the other load extreme, high-current, progressively for increasing load current, starting at low duty cycle conditions, the minimum inductor current always increases from a fixed normalised current level, for a specific load range. These and other hitherto unexplored boost converter properties are analysed and verified mathematically and with PSpice simulations. 

  5. Catalytic Mechanism and Mode of Action of the Periplasmic Alginate Epimerase AlgG

    NARCIS (Netherlands)

    Wolfram, Francis; Kitova, Elena N.; Robinson, Howard; Walvoort, Marthe T. C.; Codee, Jeroen D. C.; Klassen, John S.; Howell, P. Lynne

    2014-01-01

    Background: The alginate epimerase AlgG converts mannuronate to its C5 epimer guluronate at the polymer level. Results: The structure of Pseudomonas syringae AlgG has been determined, and the protein has been functionally characterized. Conclusion: His(319) acts as the catalytic base, whereas

  6. The Influence of Palladium on the Structure and Catalytic Activity of ...

    African Journals Online (AJOL)

    NJD

    nations exhausted from motor vehicles, catalytic converters are the industry's standard technology.1 Therefore, the ... two portions, one portion was reduced in 10 % hydrogen balanced with nitrogen gas at 850 °C for 1 h, ... hydrogen were carried out at 400 °C. Energy regions of the photoelectrons were scanned at a pass ...

  7. Simplified design of data converters

    CERN Document Server

    Lenk, John

    1997-01-01

    Simplified Design of Data Converters shows how to design and experiment with data converters, both analog-to-digital and digital to analog. The design approach here is the same one used in all of John Lenk's best-selling books on simplified and practical design. Throughout the book, design problems start with guidelines for selecting all components on a trial-value basis, assuming a specific design goal and set of conditions. Then, using the guideline values in experimental circuits, the desired results are produced by varying the experimental component values, if needed.If you are a w

  8. Catalytic cracking with deasphalted oil

    Energy Technology Data Exchange (ETDEWEB)

    Beaton, W.I.; Taylor, J.L.; Peck, L.B.; Mosby, J.F.

    1990-07-10

    This patent describes a catalytic cracking process. It comprises: hydrotreating resid; thereafter deasphalting the hydrotreated resid to produce substantially deasphalted oil; catalytically cracking the hydrotreated oil in a catalytic cracking unit in the presence of a cracking catalyst to produce upgraded oil leaving coked catalyst; and regenerating the coked catalyst in the presence of a combustion-supporting gas comprising excess molecular oxygen in an amount greater than the stoichiometric amount required for substantially completely combusting the coke on the catalyst to carbon dioxide.

  9. Rediscovering ACE: Novel insights into the many roles of the angiotensin-converting enzyme

    Science.gov (United States)

    Gonzalez-Villalobos, Romer A.; Shen, Xiao Z.; Bernstein, Ellen A.; Janjulia, Tea; Taylor, Brian; Giani, Jorge F.; Blackwell, Wendell-Lamar B.; Shah, Kandarp H.; Shi, Peng D.; Fuchs, Sebastien; Bernstein, Kenneth E.

    2013-01-01

    Angiotensin converting enzyme (ACE) is best known for the catalytic conversion of angiotensin I to angiotensin II. However, the use of gene-targeting techniques has led to mouse models highlighting many other biochemical properties and actions of this enzyme. This review discusses recent studies examining the functional significance of ACE tissue-specific expression and the presence in ACE of two independent catalytic sites with distinct substrates and biological effects. It is these features which explain why ACE makes important contributions to many different physiological processes including renal development, blood pressure control, inflammation and immunity. PMID:23686164

  10. Catalytic cracking of lignites

    Energy Technology Data Exchange (ETDEWEB)

    Seitz, M.; Nowak, S.; Naegler, T.; Zimmermann, J. [Hochschule Merseburg (Germany); Welscher, J.; Schwieger, W. [Erlangen-Nuernberg Univ. (Germany); Hahn, T. [Halle-Wittenberg Univ., Halle (Germany)

    2013-11-01

    A most important factor for the chemical industry is the availability of cheap raw materials. As the oil price of crude oil is rising alternative feedstocks like coal are coming into focus. This work, the catalytic cracking of lignite is part of the alliance ibi (innovative Braunkohlenintegration) to use lignite as a raw material to produce chemicals. With this new one step process without an input of external hydrogen, mostly propylene, butenes and aromatics and char are formed. The product yield depends on manifold process parameters. The use of acid catalysts (zeolites like MFI) shows the highest amount of the desired products. Hydrogen rich lignites with a molar H/C ratio of > 1 are to be favoured. Due to primary cracking and secondary reactions the ratio between catalyst and lignite, temperature and residence time are the most important parameter to control the product distribution. Experiments at 500 C in a discontinuous rotary kiln reactor show yields up to 32 wt-% of hydrocarbons per lignite (maf - moisture and ash free) and 43 wt-% char, which can be gasified. Particularly, the yields of propylene and butenes as main products can be enhanced four times to about 8 wt-% by the use of catalysts while the tar yield decreases. In order to develop this innovative process catalyst systems fixed on beads were developed for an easy separation and regeneration of the used catalyst from the formed char. (orig.)

  11. Charge-pump voltage converter

    Science.gov (United States)

    Brainard, John P [Albuquerque, NM; Christenson, Todd R [Albuquerque, NM

    2009-11-03

    A charge-pump voltage converter for converting a low voltage provided by a low-voltage source to a higher voltage. Charge is inductively generated on a transfer rotor electrode during its transit past an inductor stator electrode and subsequently transferred by the rotating rotor to a collector stator electrode for storage or use. Repetition of the charge transfer process leads to a build-up of voltage on a charge-receiving device. Connection of multiple charge-pump voltage converters in series can generate higher voltages, and connection of multiple charge-pump voltage converters in parallel can generate higher currents. Microelectromechanical (MEMS) embodiments of this invention provide a small and compact high-voltage (several hundred V) voltage source starting with a few-V initial voltage source. The microscale size of many embodiments of this invention make it ideally suited for MEMS- and other micro-applications where integration of the voltage or charge source in a small package is highly desirable.

  12. A digital to analog converter

    NARCIS (Netherlands)

    Westra, Jan R.; Annema, Anne J.

    2000-01-01

    A digital to analog converter for a multibit digital input signal has a set of conversion elements for the positive signal excursions and a set of conversion elements for the negative signal excursions. In each set the conversion elements are selected according to a dynamic element matching

  13. A digital to analog converter

    NARCIS (Netherlands)

    Westra, Jan R.; Annema, Anne J.

    2006-01-01

    A digital to analog converter for a multibit digital input signal has a set of conversion elements for the positive signal excursions and a set of conversion elements for the negative signal excursions. In each set the conversion elements are selected according to a dynamic element matching

  14. XML Docbook to Mediawiki Converter

    Directory of Open Access Journals (Sweden)

    Maria Chiara Pievatolo

    2013-05-01

    Full Text Available A Perl script, based on the work of Stefano Selleri, to migrate XML-Docbook 4.X documents to Wiki markup. I added some lines to meet my need to convert my Kant translations from Docbook to MediaWiki. A sample of the output can be...

  15. Multilevel converters for power system applications

    Energy Technology Data Exchange (ETDEWEB)

    Lai, J.S.; Stovall, J.P. [Oak Ridge National Lab., TN (United States); Peng, F.Z. [Univ. of Tennessee, Knoxville, TN (United States)]|[Oak Ridge National Lab., TN (United States)

    1995-09-01

    Multilevel converters are emerging as a new breed of power converter options for power system applications. These converters are most suitable for high voltage high power applications because they connect devices in series without the need for component matching. One of the major limitations of the multilevel converters is the voltage unbalance between different levels. To avoid voltage unbalance between different levels, several techniques have been proposed for different applications. Excluding magnetic-coupled converters, this paper introduces three multilevel voltage source converters: (1) diode-clamp, (2) flying-capacitors, and (3) cascaded inverters with separate dc sources. The operation principle, features, constraints, and potential applications of these converters will be discussed.

  16. Catalytic pyrolysis of lignocellulosic biomass

    NARCIS (Netherlands)

    Seshan, Kulathuiyer; Sa, Jacinto

    2014-01-01

    This chapter reports on the latest developments of biomass catalytic pyrolysis for the production of fuels. The primary focus is on the role of catalysts in the process, namely, their influence in the liquefaction of lignocellulosic biomass.

  17. Engineering reactors for catalytic reactions

    Indian Academy of Sciences (India)

    Chemical Engineering and Process Development Division, CSIR - National Chemical Laboratory,. Pune 411 008, India ... Abstract. Catalytic reactions are ubiquitous in chemical and allied industries. ... strategies and recent advances in process intensification/ multifunctional reactors are discussed to illustrate the approach.

  18. Catalytic Fast Pyrolysis: A Review

    OpenAIRE

    Theodore Dickerson; Juan Soria

    2013-01-01

    Catalytic pyrolysis is a promising thermochemical conversion route for lignocellulosic biomass that produces chemicals and fuels compatible with current, petrochemical infrastructure. Catalytic modifications to pyrolysis bio-oils are geared towards the elimination and substitution of oxygen and oxygen-containing functionalities in addition to increasing the hydrogen to carbon ratio of the final products. Recent progress has focused on both hydrodeoxygenation and hydrogenation of bio-oil using...

  19. Fuel-Rich Catalytic Combustion

    Science.gov (United States)

    Brabbs, Theodore A.; Olson, Sandra L.

    1987-01-01

    Two-stage combustion system reduces particulate emissions. Program on catalytic oxidation of iso-octane demonstrates feasibility of two-stage combustion system for reducing particulate emissions. With fuel-rich (fuel/air equivalence ratios of 4.8 to 7.8) catalytic-combustion preburner as first stage, combustion process free of soot at reactor-outlet temperatures of 1,200 K or less.

  20. Catalytic organometallic anticancer complexes

    Science.gov (United States)

    Dougan, Sarah J.; Habtemariam, Abraha; McHale, Sarah E.; Parsons, Simon; Sadler, Peter J.

    2008-01-01

    Organometallic complexes offer chemistry that is not accessible to purely organic molecules and, hence, potentially new mechanisms of drug action. We show here that the presence of both an iodido ligand and a σ-donor/π-acceptor phenylazopyridine ligand confers remarkable inertness toward ligand substitution on the half-sandwich “piano-stool” ruthenium arene complexes [(η6-arene)Ru(azpy)I]+ (where arene = p-cymene or biphenyl, and azpy = N,N-dimethylphenyl- or hydroxyphenyl-azopyridine) in aqueous solution. Surprisingly, despite this inertness, these complexes are highly cytotoxic to human ovarian A2780 and human lung A549 cancer cells. Fluorescence-trapping experiments in A549 cells suggest that the cytotoxicity arises from an increase in reactive oxygen species. Redox activity of these azopyridine RuII complexes was confirmed by electrochemical measurements. The first one-electron reduction step (half-wave potential −0.2 to −0.4 V) is assignable to reduction of the azo group of the ligand. In contrast, the unbound azopyridine ligands are not readily reduced. Intriguingly the ruthenium complex acted as a catalyst in reactions with the tripeptide glutathione (γ-l-Glu-l-Cys-Gly), a strong reducing agent present in cells at millimolar concentrations; millimolar amounts of glutathione were oxidized to glutathione disulfide in the presence of micromolar ruthenium concentrations. A redox cycle involving glutathione attack on the azo bond of coordinated azopyridine is proposed. Such ligand-based redox reactions provide new concepts for the design of catalytic drugs. PMID:18687892

  1. Understanding the mechanism of catalytic fast pyrolysis by unveiling reactive intermediates in heterogeneous catalysis

    Science.gov (United States)

    Hemberger, Patrick; Custodis, Victoria B. F.; Bodi, Andras; Gerber, Thomas; van Bokhoven, Jeroen A.

    2017-01-01

    Catalytic fast pyrolysis is a promising way to convert lignin into fine chemicals and fuels, but current approaches lack selectivity and yield unsatisfactory conversion. Understanding the pyrolysis reaction mechanism at the molecular level may help to make this sustainable process more economic. Reactive intermediates are responsible for product branching and hold the key to unveiling these mechanisms, but are notoriously difficult to detect isomer-selectively. Here, we investigate the catalytic pyrolysis of guaiacol, a lignin model compound, using photoelectron photoion coincidence spectroscopy with synchrotron radiation, which allows for isomer-selective detection of reactive intermediates. In combination with ambient pressure pyrolysis, we identify fulvenone as the central reactive intermediate, generated by catalytic demethylation to catechol and subsequent dehydration. The fulvenone ketene is responsible for the phenol formation. This technique may open unique opportunities for isomer-resolved probing in catalysis, and holds the potential for achieving a mechanistic understanding of complex, real-life catalytic processes. PMID:28660882

  2. Understanding the mechanism of catalytic fast pyrolysis by unveiling reactive intermediates in heterogeneous catalysis

    Science.gov (United States)

    Hemberger, Patrick; Custodis, Victoria B. F.; Bodi, Andras; Gerber, Thomas; van Bokhoven, Jeroen A.

    2017-06-01

    Catalytic fast pyrolysis is a promising way to convert lignin into fine chemicals and fuels, but current approaches lack selectivity and yield unsatisfactory conversion. Understanding the pyrolysis reaction mechanism at the molecular level may help to make this sustainable process more economic. Reactive intermediates are responsible for product branching and hold the key to unveiling these mechanisms, but are notoriously difficult to detect isomer-selectively. Here, we investigate the catalytic pyrolysis of guaiacol, a lignin model compound, using photoelectron photoion coincidence spectroscopy with synchrotron radiation, which allows for isomer-selective detection of reactive intermediates. In combination with ambient pressure pyrolysis, we identify fulvenone as the central reactive intermediate, generated by catalytic demethylation to catechol and subsequent dehydration. The fulvenone ketene is responsible for the phenol formation. This technique may open unique opportunities for isomer-resolved probing in catalysis, and holds the potential for achieving a mechanistic understanding of complex, real-life catalytic processes.

  3. Trash-to-Gas: Converting Space Trash into Useful Products

    Science.gov (United States)

    Caraccio, Anne J.; Hintze, Paul E.

    2013-01-01

    NASA's Logistical Reduction and Repurposing (LRR) project is a collaborative effort in which NASA is determined to reduce total logistical mass through reduction, reuse and recycling of various wastes and components of long duration space missions and habitats. LRR is focusing on four distinct advanced areas of study: Advanced Clothing System, Logistics-to-Living, Heat Melt Compactor and Trash to Supply Gas (TtSG). The objective of TtSG is to develop technologies that convert material waste, human waste and food waste into high-value products. High-value products include life support oxygen and water, rocket fuels, raw material production feedstocks, and other energy sources. There are multiple pathways for converting waste to products involving single or multi-step processes. This paper discusses thermal oxidation methods of converting waste to methane. Different wastes, including food, food packaging, Maximum Absorbent Garments (MAGs), human waste simulants, and cotton washcloths have been evaluated in a thermal degradation reactor under conditions promoting pyrolysis, gasification or incineration. The goal was to evaluate the degradation processes at varying temperatures and ramp cycles and to maximize production of desirable products and minimize high molecular weight hydrocarbon (tar) production. Catalytic cracking was also evaluated to minimize tar production. The quantities of CO2, CO, CH4, and H2O were measured under the different thermal degradation conditions. The conversion efficiencies of these products were used to determine the best methods for producing desired products.

  4. Trash to Gas: Converting Space Trash into Useful Products

    Science.gov (United States)

    Nur, Mononita

    2013-01-01

    NASA's Logistical Reduction and Repurposing (LRR) project is a collaborative effort in which NASA is determined to reduce total logistical mass through reduction, reuse and recycling of various wastes and components of long duration space missions and habitats. LRR is focusing on four distinct advanced areas of study: Advanced Clothing System, Logistics-to-Living, Heat Melt Compactor and Trash to Supply Gas (TtSG). The objective of TtSG is to develop technologies that convert material waste, human waste and food waste into high-value products. High-value products include life support oxygen and water, rocket fuels, raw material production feedstocks, and other energy sources. There are multiple pathways for converting waste to products involving single or multi-step processes. This paper discusses thermal oxidation methods of converting waste to methane. Different wastes, including food, food packaging, Maximum Absorbent Garments (MAGs), human waste simulants, and cotton washcloths have been evaluated in a thermal degradation reactor under conditions promoting pyrolysis, gasification or incineration. The goal was to evaluate the degradation processes at varying temperatures and ramp cycles and to maximize production of desirable products and minimize high molecular weight hydrocarbon (tar) production. Catalytic cracking was also evaluated to minimize tar production. The quantities of C02, CO, CH4, and H20 were measured under the different thermal degradation conditions. The conversion efficiencies of these products were used to determine the best methods for producing desired products.

  5. Synthesis and catalytic performance of SiO2@Ni and hollow Ni microspheres

    Science.gov (United States)

    Liu, Xin; Liu, Yanhua; Shi, Xueting; Yu, Zhengyang; Feng, Libang

    2016-11-01

    Nickel (Ni) catalyst has been widely used in catalytic reducing reactions such as catalytic hydrogenation of organic compounds and catalytic reduction of organic dyes. However, the catalytic efficiency of pure Ni is low. In order to improve the catalytic performance, Ni nanoparticle-loaded microspheres can be developed. In this study, we have prepared Ni nanoparticle-loaded microspheres (SiO2@Ni) and hollow Ni microspheres using two-step method. SiO2@Ni microspheres with raspberry-like morphology and core-shell structure are synthesized successfully using SiO2 microsphere as a template and Ni2+ ions are adsorbed onto SiO2 surfaces via electrostatic interaction and then reduced and deposited on surfaces of SiO2 microspheres. Next, the SiO2 cores are removed by NaOH etching and the hollow Ni microspheres are prepared. The NaOH etching time does no have much influence on the crystal structure, shape, and surface morphology of SiO2@Ni; however, it can change the phase composition evidently. The hollow Ni microspheres are obtained when the NaOH etching time reaches 10 h and above. The as-synthesized SiO2@Ni microspheres exhibit much higher catalytic performance than the hollow Ni microspheres and pure Ni nanoparticles in the catalytic reduction of methylene blue. Meanwhile, the SiO2@Ni catalyst has high stability and hence it can be recycled for reuse.

  6. Multilevel push pull power converter

    DEFF Research Database (Denmark)

    2007-01-01

    A power converter for converting an input voltage (Vin) into an output voltage (Vout), comprising a first supply potential and a second supply potential established by the input voltage, and at least one primary winding having two terminals, a center tap arranged between the two terminals...... and connected to the first supply potential, and at least one secondary winding magnetically coupled to the primary winding for providing at least one output voltage (Vout); and a first controllable switch connected between the second supply potential and one terminal of the primary winding and a second...... controllable switch connected between the second supply potential and the other terminal of the primary winding and a third controllable switch connected between the second supply potential and the one terminal of the primary winding and a fourth controllable switch connected between the second supply...

  7. Efficiency of Capacitively Loaded Converters

    DEFF Research Database (Denmark)

    Andersen, Thomas; Huang, Lina; Andersen, Michael A. E.

    2012-01-01

    This paper explores the characteristic of capacitance versus voltage for dielectric electro active polymer (DEAP) actuator, 2kV polypropylene film capacitor as well as 3kV X7R multi layer ceramic capacitor (MLCC) at the beginning. An energy efficiency for capacitively loaded converters...... is introduced as a definition of efficiency. The calculated and measured efficiency curves for charging DEAP actuator, polypropylene film capacitor and X7R MLCC are provided and compared. The attention has to be paid for the voltage dependent capacitive load, like X7R MLCC, when evaluating the charging...... efficiency of converter. Based on the capacitancevoltage curve, the correct capacitance should be chosen when calculating the stored energy; otherwise misleading optimistic efficiency can always be obtained. Actually, when DEAP actuator is not available at the early developing stage, the voltage independent...

  8. Radiated EMI from power converters

    Directory of Open Access Journals (Sweden)

    Arnautovski-Toševa Vesna

    2005-01-01

    Full Text Available With the continuous increase of switching frequency together with the ongoing trend to higher complexity and functionality, power converters as a part of electronic systems have raised more and more electromagnetic energy pollution to the local system environment. In the same time, stringent demands are imposed on the designers of new circuits that electromagnetic interference (EMI has to be suppressed at its source before it is allowed to propagate into other circuits and systems. In this paper, the authors present a full-wave numerical method for calculation and simulation of electromagnetic field radiated by power converter circuitry. The main objective is to analyze the layout geometry in order to obtain competitive PCB layout that will enable suitably attenuated level of the radiated electric field to safe level. By this it would be possible to ensure reliable operation of the sensitive electronic components in the proximity.

  9. A digital to analog converter

    OpenAIRE

    Westra, Jan R.; Annema, Anne J.

    2000-01-01

    A digital to analog converter for a multibit digital input signal has a set of conversion elements for the positive signal excursions and a set of conversion elements for the negative signal excursions. In each set the conversion elements are selected according to a dynamic element matching algorithm. To improve the mismatch-noise shaping of these algorithms, excess conversion elements may be additionally selected.

  10. Development of a Compact Matrix Converter

    Directory of Open Access Journals (Sweden)

    J. Bauer

    2009-01-01

    Full Text Available This paper deals with the development of a matrix converter. Matrix converters belong to the category of direct frequency converters. A converter does not contain DC-link and the output voltage is provided by direct switching of voltage from the input phases. This is enabled by 9 bidirectional switches, which are provided by anti-serial connection of 18 IGBT transistors. The absence of a DC-link is great advantage of the matrix converter, but it also increases the requirements on the converter control. For this reason a new prototype of a matrix converter is being developed with sophisticated modern components (FPGA, Power PC equipped in the control part of the converter. The converter will be used for testing new control algorithms and commutation methods. 

  11. Computerized simulation of converter process

    Energy Technology Data Exchange (ETDEWEB)

    Jalkanen, H.; Suomi, M.L.; Wallgren, M. [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Metallurgy

    1996-12-31

    Converter process is essentially an oxidising refining process aiming in addition to (1) the primary refining action, decarburisation of high carbon iron melt, also to (2) maximal elimination of impurity elements, especially silicon, phosphorus and sulphur, (3) melting of substantial amounts of scrap using the extra heat released in oxidation reactions and (4) to exact final steel temperature control, optimal for further treatments. `Quantitative modelling of such a complex non-stationary chemical process as oxygen converting necessitates extensive formulation of chemical and thermal evolution of the process in connection with the technological properties of the reactor and the process control measures. A comprehensive converter simulation program like CONSIM-3. 1 and its preceding versions that is based on the theoretical and practical knowledge on the process can be used for (1) educating specialists and smelter personnel, (2) planning of the blowing programs, (3) developing and testing of process control systems and after some elaboration and restructuring (4) it can be integrated to static or dynamic process control systems. (orig.) SULA 2 Research Programme; 10 refs.

  12. The angiotensin-converting enzyme (ACE) gene family of Bombyx mori.

    Science.gov (United States)

    Yan, Hai-Yan; Mita, Kazuei; Zhao, Xia; Tanaka, Yoshikazu; Moriyama, Minoru; Wang, Huabin; Iwanaga, Masashi; Kawasaki, Hideki

    2017-04-15

    We previously reported regarding an ecdysone-inducible angiotensin-converting enzyme (ACE) gene. We found another four ACE genes in the Bombyx genome. The present study was undertaken to clarify the evolutionally changed function of the ACE of Bombyx mori. Core regions of deduced amino acid sequences of ACE genes were compared with those of other insect ACE genes. Five Bombyx genes have the conserved Zn2+-binding-site motif (HEXXH); however, BmAcer4 has only one and BmAcer3 has no catalytic ligand. BmAcer1 and BmAcer2 were expressed in several organs. BmAcer3 was expressed in testes, and BmAcer4 and BmAcer5 were expressed in compound eyes; however, the transcription levels of these three genes were very low. Quantitative RT-PCR and Western analysis were conducted to determine the tissue distribution and developmental expression of BmAcer1and BmAcer2. Transcripts of BmAcer1 and BmAcer2 were found in the reproductive organs during the larval and pupal stages. BmAcer1 was dominant in fat bodies during the feeding stage and showed high expression in the epidermis, wing discs, and pupal wing tissues after the wandering stage. Its expression patterns in epidermis, wing discs, and wing tissues resembled the hemolymph ecdysteroid titer in the larval and pupal stages. Acer1 was observed in the hemolymph at all stages, appearing to be the source of it are fat bodies, wings, and epidermis, and functioning after being secreted into the hemolymph. BmAcer2 was abundant in the midgut during the feeding stage and after the wandering stage and in silk glands after the pupal stage. We conclude that the evolution of BmAcer occurred through duplication, and, thereafter, functional diversification developed. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Green technology for conversion of renewable hydrocarbon based on plasma-catalytic approach

    Science.gov (United States)

    Fedirchyk, Igor; Nedybaliuk, Oleg; Chernyak, Valeriy; Demchina, Valentina

    2016-09-01

    The ability to convert renewable biomass into fuels and chemicals is one of the most important steps on our path to green technology and sustainable development. However, the complex composition of biomass poses a major problem for established conversion technologies. The high temperature of thermochemical biomass conversion often leads to the appearance of undesirable byproducts and waste. The catalytic conversion has reduced yield and feedstock range. Plasma-catalytic reforming technology opens a new path for biomass conversion by replacing feedstock-specific catalysts with free radicals generated in the plasma. We studied the plasma-catalytic conversion of several renewable hydrocarbons using the air plasma created by rotating gliding discharge. We found that plasma-catalytic hydrocarbon conversion can be conducted at significantly lower temperatures (500 K) than during the thermochemical ( 1000 K) and catalytic (800 K) conversion. By using gas chromatography, we determined conversion products and found that conversion efficiency of plasma-catalytic conversion reaches over 85%. We used obtained data to determine the energy yield of hydrogen in case of plasma-catalytic reforming of ethanol and compared it with other plasma-based hydrogen-generating systems.

  14. Simulation Results of Double Forward Converter

    Directory of Open Access Journals (Sweden)

    P. Vijaya KUMAR

    2009-12-01

    Full Text Available This work aims to find a better forward converter for DC to DC conversion.Simulation of double forward converter in SMPS system is discussed in this paper. Aforward converter with RCD snubber to synchronous rectifier and/or to current doubleris also discussed. The evolution of the forward converter is first reviewed in a tutorialfashion. Performance parameters are discussed including operating principle, voltageconversion ratio, efficiency, device stress, small-signal dynamics, noise and EMI. Itscircuit operation and its performance characteristics of the forward converter with RCDsnubber and double forward converter are described and the simulation results arepresented.

  15. A method of Modelling and Simulating the Back-to-Back Modular Multilevel Converter HVDC Transmission System

    Science.gov (United States)

    Wang, Lei; Fan, Youping; Zhang, Dai; Ge, Mengxin; Zou, Xianbin; Li, Jingjiao

    2017-09-01

    This paper proposes a method to simulate a back-to-back modular multilevel converter (MMC) HVDC transmission system. In this paper we utilize an equivalent networks to simulate the dynamic power system. Moreover, to account for the performance of converter station, core components of model of the converter station gives a basic model of simulation. The proposed method is applied to an equivalent real power system.

  16. Planar Integrated Magnetics (PIM) Module in Hybrid Bidirectional DC-DC Converter for Fuel Cell Application

    DEFF Research Database (Denmark)

    Ouyang, Ziwei; Zhang, Zhe; Thomsen, Ole Cornelius

    2011-01-01

    , hereby increasing the power density of converters. In this paper, a new planar integrated magnetics (PIM) module for a phase-shift plus duty cycle controlled hybrid bi-directional dc-dc converter is proposed, which assembles one boost inductor and two transformers into an E-I-E core geometry, reducing......In most power electronics converters, the overall volume is mainly determined by the number of parts and the size of passive components. Integrated magnetics and planar magnetics techniques therefore have been an excellent option in order to reduce the counts and the size of magnetic components...... the number of parts, the total volume of converter, as well as the total core loss of the magnetic components. AC losses in the windings and leakage inductance of the transformers are kept low by interleaving the primary and secondary turns of the transformers. To verify the validity of the design approach...

  17. Catalytic bioreactors and methods of using same

    Energy Technology Data Exchange (ETDEWEB)

    Worden, Robert Mark; Liu, Yangmu Chloe

    2017-07-25

    Various embodiments provide a bioreactor for producing a bioproduct comprising one or more catalytically active zones located in a housing and adapted to keep two incompatible gaseous reactants separated when in a gas phase, wherein each of the one or more catalytically active zones may comprise a catalytic component retainer and a catalytic component retained within and/or thereon. Each of the catalytically active zones may additionally or alternatively comprise a liquid medium located on either side of the catalytic component retainer. Catalytic component may include a microbial cell culture located within and/or on the catalytic component retainer, a suspended catalytic component suspended in the liquid medium, or a combination thereof. Methods of using various embodiments of the bioreactor to produce a bioproduct, such as isobutanol, are also provided.

  18. Catalytic distillation extends its reach

    Energy Technology Data Exchange (ETDEWEB)

    Rock, K.; McGuirk, T. [Catalytic Distillation Technologies, Houston, TX (United States); Gildert, G.R. [Catalytic Distillation Technologies, Pasadena, TX (United States)

    1997-07-01

    Since the early 1980s, catalytic distillation processes have been selected by more than a hundred operators for various applications. Since such a unit performs both reaction and distillation simultaneously, a combined column can replace a separate, fixed-bed reactor and distillation column, thereby eliminating equipment and reducing capital costs. And, compared to the conventional approach, catalytic distillation may also improve other factors, such as reactant conversion, selectivity, mass transfer, operating pressure, oligomer formation and catalyst fouling. The constant washing of the catalyst by liquid flowing down the column and the distillation of high-boiling foulants results in extended catalyst life. Four selective hydrogenation applications of catalytic distillation are discussed: Butadiene selective hydrogenation combined within an MTBE unit; Pentadiene selective hydrogenation; C{sub 4} acetylene conversion; and Benzene saturation.

  19. Catalytic activity of Au nanoparticles

    DEFF Research Database (Denmark)

    Larsen, Britt Hvolbæk; Janssens, Ton V.W.; Clausen, Bjerne

    2007-01-01

    Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with par......Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change...... with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the catalytic activity, suggesting that atoms on the corners and edges of Au nanoparticles are the active sites. This effect is explained using density functional calculations....

  20. Electromechanical converters for electric vehicles

    Science.gov (United States)

    Ambros, T.; Burduniuc, M.; Deaconu, S. I.; Rujanschi, N.

    2018-01-01

    The paper presents the analysis of various constructive schemes of synchronous electromechanical converters with permanent magnets fixed on the rotor and asynchronous with the short-circuit rotor. Various electrical stator winding schemes have also been compared, demonstrating the efficiency of copper utilization in toroidal windings. The electromagnetic calculus of the axial machine has particularities compared to the cylindrical machine, in the paper is presented the method of correlating the geometry of the cylindrical and axial machines. In this case the method and recommendations used in the design of such machines may be used.

  1. OAM mode converter in twisted fibers

    DEFF Research Database (Denmark)

    Usuga Castaneda, Mario A.; Beltran-Mejia, Felipe; Cordeiro, Cristiano

    2014-01-01

    We analyze the case of an OAM mode converter based on a twisted fiber, through finite element simulations where we exploit an equivalence between geometric and material transformations. The obtained converter has potential applications in MDM. © 2014 OSA.......We analyze the case of an OAM mode converter based on a twisted fiber, through finite element simulations where we exploit an equivalence between geometric and material transformations. The obtained converter has potential applications in MDM. © 2014 OSA....

  2. Catalytic Decoupling of Quantum Information

    DEFF Research Database (Denmark)

    Majenz, Christian; Berta, Mario; Dupuis, Frédéric

    2017-01-01

    The decoupling technique is a fundamental tool in quantum information theory with applications ranging from quantum thermodynamics to quantum many body physics to the study of black hole radiation. In this work we introduce the notion of catalytic decoupling, that is, decoupling in the presence...... of an uncorrelated ancilla system. This removes a restriction on the standard notion of decoupling, which becomes important for structureless resources, and yields a tight characterization in terms of the max-mutual information. Catalytic decoupling naturally unifies various tasks like the erasure of correlations...

  3. High efficiency control of a grid-connected PV converter

    Energy Technology Data Exchange (ETDEWEB)

    Balogh, A.; Varjasi, I. [Budapest Univ. of Technology and Economics, Budapest (Hungary). Dept. of Automation and Applied Informatics; Bilau, Z.T. [Budapest Goldmann Gy, Budapest (Hungary)

    2007-07-01

    Core losses in photovoltaic (PV) grid-connected systems are often caused by ripple currents that decrease efficiency at low power rates. This paper discussed a control method designed to decrease the ripple current in the AC inductance of DC-AC converter filters. The control method used a 3-state control method with high on, low on, and off channels. The method used an algorithm developed for single phase converters and only required a modification of existing 2-state control methods. The 3-state control was applied when the stationary-state current of the output inductance reached zero. Degrees of freedom were then added to the control system. The insulated gate bipolar transistor (IGBT) was controlled only in relation to the direction of the current reference in order to create a discontinuous current mode. The rippled current increased according to a square root function of time until the current of the continuous mode was reached. The harmonic content of the output current became significant at smaller loads. Experiments were conducted on an frequency converter with a nominal power of 10 kW and a switching frequency of 16.5 kHz. Results of the experiments were compared with results obtained using a traditional current control device. The proposed control method increased the efficiency of the converter during periods of low radiation. 17 refs., 1 tab., 11 figs.

  4. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    Science.gov (United States)

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  5. Impact analysis of tap switch out of step for converter transformer

    Science.gov (United States)

    Hong-yue, ZHANG; Zhen-hua, ZHANG; Zhang-xue, XIONG; Gao-wang, YU

    2017-06-01

    AC transformer load regulation is mainly used to adjust the load side voltage level, improve the quality of power supply, the voltage range is relatively narrow. In DC system, converter transformer is the core equipment of AC and DC power converter and inverter. converter transformer tap adjustment can maintain the normal operation of the converter in small angle range control, the absorption of reactive power, economic operation, valve less stress, valve damping circuit loss, AC / DC harmonic component is also smaller. In this way, the tap switch action is more frequent, and a large range of the tap switch adjustment is required. Converter transformer with a more load voltage regulation switch, the voltage regulation range of the switch is generally 20~30%, the adjustment of each file is 1%~2%. Recently it is often found that the tap switch of Converter Transformers is out of step in Converter station. In this paper, it is analyzed in detail the impact of tap switch out of step for differential protection, overexcitation protection and zero sequence over current protection. Analysis results show that: the tap switch out of step has no effect on the differential protection and the overexcitation protection including the tap switch. But the tap switch out of step has effect on zero sequence overcurrent protection of out of step star-angle converter transformer. The zero sequence overcurrent protection will trip when the tap switch out of step is greater than 3 for out of step star-angle converter transformer.

  6. 12 CFR 1.6 - Convertible securities.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 1 2010-01-01 2010-01-01 false Convertible securities. 1.6 Section 1.6 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY INVESTMENT SECURITIES § 1.6 Convertible securities. A national bank may not purchase securities convertible into stock at the option of...

  7. Convertible Subspaces of Hessenberg-Type Matrices

    Directory of Open Access Journals (Sweden)

    Henrique F. da Cruz

    2017-12-01

    Full Text Available We describe subspaces of generalized Hessenberg matrices where the determinant is convertible into the permanent by affixing ± signs. An explicit characterization of convertible Hessenberg-type matrices is presented. We conclude that convertible matrices with the maximum number of nonzero entries can be reduced to a basic set.

  8. Ecologically Optimal Solution of Power Semiconductors Converters

    Directory of Open Access Journals (Sweden)

    Pavol Spanik

    2003-01-01

    Full Text Available One of the relevant scientific programs of Department of Power Electrical Systems is research of ecologically optimal topologies main circuits of power converters. This paper presents some methods how to reduce unfavourable influences of power converters on the grid. The achieved results were applieed in praxis, especially in the power converters produced by Electrotechnical Research and Projecting Institute in Nova Dubnica.

  9. A novel converter topology for TEM applications

    Indian Academy of Sciences (India)

    and energy levels of the TEM system, require special type of excitation technique. Power converters for ... This paper proposes a novel converter topology to meet these excitation current require- ments. A novel ... The converter control system is given a square wave current reference of required amplitude,. ON duration TS ...

  10. Catalytic Gasification of Lignocellulosic Biomass

    NARCIS (Netherlands)

    Chodimella, Pramod; Seshan, Kulathuiyer; Schlaf, Marcel; Zhang, Z. Conrad

    2015-01-01

    Gasification of lignocellulosic biomass has attracted substantial current research interest. Various possible routes to convert biomass to fuels have been explored. In the present chapter, an overview of the gasification processes and their possible products are discussed. Gasification of solid

  11. Optimum catalytic process for alcohol fuels from syngas: Seventh quarterly technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1988-10-29

    The objectives of this contract are to discover and evaluate the catalytic properties of novel homogeneous, heterogeneous, or combination catalytic systems for the production of alcohol fuel extenders from syngas, to evaluate analytically and on the bench scale novel reactor concepts for use in converting syngas to liquid fuel products, and to develop on the bench scale the best combination of chemistry, reactor, and total process configuration to achieve the minimum product cost for conversion of syngas to liquid fuel products. Catalysts investigated include: ruthenium and molybdenum sulfides impregnated with cobalt. 7 figs., 9 tabs.

  12. Hybrid thermionic-photovoltaic converter

    Science.gov (United States)

    Datas, A.

    2016-04-01

    A conceptual device for the direct conversion of heat into electricity is presented. This concept hybridizes thermionic (TI) and thermophotovoltaic (TPV) energy conversion in a single thermionic-photovoltaic (TIPV) solid-state device. This device transforms into electricity both the electron and photon fluxes emitted by an incandescent surface. This letter presents an idealized analysis of this device in order to determine its theoretical potential. According to this analysis, the key advantage of this converter, with respect to either TPV or TI, is the higher power density in an extended temperature range. For low temperatures, TIPV performs like TPV due to the negligible electron flux. On the contrary, for high temperatures, TIPV performs like TI due to the great enhancement of the electron flux, which overshadows the photon flux contribution. At the intermediate temperatures, ˜1650 K in the case of this particular study, I show that the power density potential of TIPV converter is twice as great as that of TPV and TI. The greatest impact concerns applications in which the temperature varies in a relatively wide range, for which averaged power density enhancement above 500% is attainable.

  13. Hybrid thermionic-photovoltaic converter

    Energy Technology Data Exchange (ETDEWEB)

    Datas, A. [Instituto de Energía Solar, Universidad Politécnica de Madrid, 28040 Madrid (Spain)

    2016-04-04

    A conceptual device for the direct conversion of heat into electricity is presented. This concept hybridizes thermionic (TI) and thermophotovoltaic (TPV) energy conversion in a single thermionic-photovoltaic (TIPV) solid-state device. This device transforms into electricity both the electron and photon fluxes emitted by an incandescent surface. This letter presents an idealized analysis of this device in order to determine its theoretical potential. According to this analysis, the key advantage of this converter, with respect to either TPV or TI, is the higher power density in an extended temperature range. For low temperatures, TIPV performs like TPV due to the negligible electron flux. On the contrary, for high temperatures, TIPV performs like TI due to the great enhancement of the electron flux, which overshadows the photon flux contribution. At the intermediate temperatures, ∼1650 K in the case of this particular study, I show that the power density potential of TIPV converter is twice as great as that of TPV and TI. The greatest impact concerns applications in which the temperature varies in a relatively wide range, for which averaged power density enhancement above 500% is attainable.

  14. Simultaneous leaching of Pt, Pd and Rh from automotive catalytic converters in chloride-containing solutions

    Science.gov (United States)

    Hasani, M.; Khodadadi, A.; Koleini, S. M. J.; Saeedi, A. H.; Meléndez, A. M.

    2017-01-01

    Dissolution of platinum group metals (PGM; herein Pt, Pd and Rh) in different chloride-based leaching systems from spent auto catalysts was performed. Response surface methodology and a five-level-five-factor central composite design were used to evaluate the effects of 1) temperature, 2) liquid-to-solid ratio, 3) stirring speed, 4) acid concentration and 5) particle size on extraction yield of PGM by aqua regia. Analysis of variance was used to determine the optimum conditions and most significant factors affecting the overall metal extraction. In the optimum conditions, leaching of Pt, Pd and Rh was 91.58%, 93.49% and 60.15%, respectively. The effect of different oxidizing agents on the PGM dissolution in chloride medium was studied comparatively in the following leaching systems: a) aqua regia/sulfuric acid mixture, b) hydrogen peroxide in sulfuric acid (piranha solution), c) sodium hypochlorite and d) copper(II). Dissolution of Rh is increased in both aqua regia and hydrogen peroxide/hydrochloric acid solutions by adding sulfuric acid.

  15. Thermal Catalytic Syngas Cleanup for High-Efficiency Waste-to-Energy Converters

    Science.gov (United States)

    2015-12-01

    selection of individual plastic types was based on a proportion of the waste stream and the desire to create a challenging fuel . Polyethylene is one of the...conditions would displace approximately 100 gallons of diesel fuel . In addition to the potential for high energy conversion, this project’s testing has...control and would conceivably only require significant user oversight at start-up and incremental fuel loadings. The operator burden is estimated to

  16. Effectiveness of replacing catalytic converters in LPG-fueled vehicles in Hong Kong

    Directory of Open Access Journals (Sweden)

    X. Lyu

    2016-05-01

    Full Text Available Many taxis and public buses are powered by liquefied petroleum gas (LPG in Hong Kong. With more vehicles using LPG, they have become the major contributor to ambient volatile organic compounds (VOCs in Hong Kong. An intervention program which aimed to reduce the emissions of VOCs and nitrogen oxides (NOx from LPG-fueled vehicles was implemented by the Hong Kong government in September 2013. Long-term real-time measurements indicated that the program was remarkably effective in reducing LPG-related VOCs, NOx and nitric oxide (NO in the atmosphere. Receptor modeling results further revealed that propane, propene, i-butane, n-butane and NO in LPG-fueled vehicle exhaust emissions decreased by 40.8 ± 0.1, 45.7 ± 0.2, 35.7 ± 0.1, 47.8 ± 0.1 and 88.6 ± 0.7 %, respectively, during the implementation of the program. In contrast, despite the reduction of VOCs and NOx, O3 following the program increased by 0.40 ± 0.03 ppbv (∼  5.6 %. The LPG-fueled vehicle exhaust was generally destructive to OH and HO2. However, the destruction effect weakened for OH and it even turned to positive contribution to HO2 during the program. These changes led to the increases of OH, HO2 and HO2 ∕ OH ratio, which might explain the positive O3 increment. Analysis of O3–VOCs–NOx sensitivity in ambient air indicated VOC-limited regimes in the O3 formation before and during the program. Moreover, a maximum reduction percentage of NOx (i.e., 69 % and the lowest reduction ratio of VOCs ∕ NOx (i.e., 1.1 in LPG-fueled vehicle exhaust were determined to give a zero O3 increment. The findings are of great help to future formulation and implementation of control strategies on vehicle emissions in Hong Kong, and could be extended to other regions in China and around the world.

  17. Analysis of Platinum Content in Used Auto Catalytic Converter Carriers and the Possibility of its Recovery

    Directory of Open Access Journals (Sweden)

    Saternus M.

    2014-06-01

    Full Text Available Obecnie każdy wyprodukowany samochód musi być wyposażony w katalizator, w którym metale szlachetne takie jak platyna, pallad czy rod pełnią funkcje katalityczne. Czas życia katalizatorów jest ograniczony, zatem zostają one zastąpione nowymi, a stare stanowią ważne źródło platynowców. Zużyte katalizatory samochodowe przerabiane są hydrometalurgicznie lub pirometalurgicznie. Jednakże pierwszym etapem takiego przerobu powinna być analiza chemiczna. W pracy analizie na zawartość platyny poddano kilka różnych nośników katalitycznych pochodzących z różnych samochodów. Do tego celu posłużył elektronowy mikroskop skaningowy. Przedstawiono strukturę analizowanych nośników katalitycznych, ich analizę chemiczną jak również wykresy EDS (Energy Dispersive Spectrum. Przeprowadzono dyskusję wyników i możliwych metod odzysku platyny.

  18. The human core exosome interacts with differentially localized processive RNases

    DEFF Research Database (Denmark)

    Tomecki, Rafal; Kristiansen, Maiken Søndergaard; Lykke-Andersen, Søren

    2010-01-01

    The eukaryotic RNA exosome is a ribonucleolytic complex involved in RNA processing and turnover. It consists of a nine-subunit catalytically inert core that serves a structural function and participates in substrate recognition. Best defined in Saccharomyces cerevisiae, enzymatic activity comes......, identity and arrangements of its catalytic subunits in different vertebrates remain elusive. Here, we demonstrate the association of two different Dis3p homologs--hDIS3 and hDIS3L--with the human exosome core. Interestingly, these factors display markedly different intracellular localizations: hDIS3...

  19. Environmental Engineering of Pd Nanoparticle Catalysts for Catalytic Hydrogenation of CO2 and Bicarbonate.

    Science.gov (United States)

    Lee, Li-Chen; Xing, Xiaoyu; Zhao, Yan

    2017-10-24

    The extraordinary catalytic properties of enzymes are derived not only from their catalytic groups but also the unique properties of the active site. Tuning the microenvironment of synthetic catalysts is expected to enhance their performance if effective strategies can be developed. Interfacially cross-linked reverse micelles were prepared from three different cross-linkable surfactants. Pd nanoparticles were deposited in the core of the micelle for the catalytic hydrogenation of bicarbonate and CO2. The catalytic performance was found to depend heavily on the nature of the headgroup of the surfactant. Quaternary ammonium-based surfactants through ion exchange could bring bicarbonate to the catalytic center, whereas tertiary amine-based surfactants worked particularly well in CO2 hydrogenation, with turnover numbers an order of magnitude higher than that of commercially available Pd/C. The amines were proposed to bring CO2 to the proximity of the catalysts through reversible formation of carbamate, in the nanospace of the hydrophilic core of the cross-linked reverse micelle. In the bicarbonate reduction, additional improvement of the catalysts was achieved through localized sol-gel synthesis that introduced metal oxide near the catalytic metal.

  20. Catalytic carboxyester hydrolysis by diaminodiphenols

    Indian Academy of Sciences (India)

    Administrator

    Two diaminodiphenols, 1 and 2, have been examined as catalysts for the hydrolysis of 4- nitrophenyl acetate (NA) and 4-nitrophenylphosphate (NP) in aqueous-acetonitrile (25% acetonitrile v/v) media at 35ºC, I = 1·0 mol dm–3. The compound 1 enhances the hydrolysis rate of NA more than 105 times. Its catalytic efficiency ...

  1. Catalytic combustion of gasified biomass for electricity and heat production

    Energy Technology Data Exchange (ETDEWEB)

    Jaeraas, S.; Johansson, Magnus [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Chemical Engineering and Technology

    1996-01-01

    High temperature catalytic combustion of gasified biomass for gas turbine applications has been studied, with emphasis on NH{sub 3} conversion and ignition characteristics of the main fuel components CO, H{sub 2} and CH{sub 4}. Three sets of catalysts have been evaluated: Alumina supported transition metal oxides, Unsupported perovskites, and Complex oxide materials such as hexaaluminate supported perovskites and BaMn-hexaaluminates. The three fuel components CO, H{sub 2} and CH{sub 4} ignited in different order, depending on the catalyst material. To design a multi-monolithic catalytic combustion chamber, it will be important to examine at which temperature and in which order the fuel mixture ignites. The analysis of NH{sub 3} conversion to NO{sub x} and N{sub 2} showed that the alumina supported transition metal oxides gave conversion between 21% and 86% to N{sub 2}, where the best result was for NiO catalyst. However, at higher temperatures it is likely that these catalysts sinter and that NO{sub x} formation increases. Pt catalyst showed high conversion of NH{sub 3} to NO{sub x}, <20% to N{sub 2}. Complex oxides showed showed the most promising result with conversion 20 - 80% to N{sub 2}, depending on inlet temperature and catalyst. For BaMn-hexaaluminate 75 - 78% of NH{sub 3} was converted to N{sub 2} between 600 and 750 deg C. For LaNiO{sub 3}/La-hexaaluminate 90% of the NH{sub 3} was converted between 700 and 750 deg C and no NO formed. In addition, the formation of HCN and N{sub 2}O was analysed for some catalysts. The analyses showed that 5 - 10 ppm of N{sub 2}O and HCN was formed at 850 - 950 deg C. The results indicate that it would be possible to design a segmented catalytic combustion chamber, with a first segment working at a temperature window where all NH{sub 3} is converted to N{sub 2} and only 0 - 20% of the fuel components are converted. 34 refs

  2. Catalytic oxidation of model soot by metal chlorides

    Energy Technology Data Exchange (ETDEWEB)

    Mul, Guido; Kapteijn, Freek; Moulijn, Jacob A. [Delft University of Technology, Industrial Catalysis, Delft (Netherlands)

    1997-05-16

    Several metal chlorides were screened for their catalytic activity in the oxidation of model soot (Printex-U) in `loose contact` by means of TGA/DSC. HgCl{sub 2}, CaCl{sub 2}, BaCl{sub 2}, CoCl{sub 2}, and NiCl{sub 2} show little activity. Hydrated BiCl{sub 3} and FeCl{sub 3} are converted in air into BiOCl and FeOCl, which have a moderate soot oxidation activity. MoCl{sub 5} is converted into the corresponding metal oxide and also shows a moderate `loose contact` activity. PbCl{sub 2}, CuCl{sub 2} and CuCl are very active catalysts; the soot oxidation temperature is lowered by 200-275K. The activity of metal chlorides is thought to be induced by in situ formation of intimate contact between the soot and the metal chloride via `wetting` and/or gas phase transport. A correlation between the melting point and the catalytic activity was found. Furthermore, a catalytic cycle is proposed involving activation of oxygen on the surface of the (oxy)chloride, followed by transfer of activated oxygen to the soot surface. DRIFT analyses showed that this results in the formation of carbon surface oxygen complexes. Decomposition of those complexes yields CO and CO{sub 2}. Practical application of metal chlorides for the removal of soot from diesel exhaust is not recommended, because they suffer from instability or high vapour pressures

  3. Self-organized Ruthenium-Barium Core-Shell Nanoparticles on a Mesoporous Calcium Amide Matrix for Efficient Low-Temperature Ammonia Synthesis.

    Science.gov (United States)

    Kitano, Masaaki; Inoue, Yasunori; Sasase, Masato; Kishida, Kazuhisa; Kobayashi, Yasukazu; Nishiyama, Kohei; Tada, Tomofumi; Kawamura, Shigeki; Yokoyama, Toshiharu; Hara, Michikazu; Hosono, Hideo

    2018-01-22

    A low-temperature ammonia synthesis process is required for on-site synthesis. Here, we report that barium-doped calcium amide (Ba-Ca(NH2)2) significantly enhances the ammonia synthesis activities of Ru and Co by two-orders of magnitude more than that of a conventional Ru catalyst below 300ºC. Furthermore, the present catalysts are superior to that of the wüstite-based Fe catalyst known as a highly active industrial catalyst at low temperatures and pressures. Nanosized Ru-Ba core-shell structures are self-organized on the support during hydrogen pretreatment, and the support material is simultaneously converted into a mesoporous structure with a high surface area (>100 m2 g-1). These unique self-organized nanostructures account for the high catalytic performance in low-temperature ammonia synthesis. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Catalytic ozonation of sulfamethoxazole by composite iron-manganese silicate oxide: cooperation mechanism between adsorption and catalytic reaction.

    Science.gov (United States)

    Gao, Guoying; Kang, Jing; Shen, Jimin; Chen, Zhonglin; Chu, Wei

    2016-11-01

    A systematic investigation of the cooperation mechanism between adsorption and catalytic reaction during the catalytic ozonation of sulfamethoxazole (SMX) by composite iron-manganese silicate oxide (FMSO) was carried out in this work. Results showed that the total organic carbon (TOC) removal increased significantly from 27 % (sole-ozonation) to 79.8 % (FMSO catalytic ozonation). The presence of FMSO in the ozonation process effectively enhanced the ozone utilization efficiency and accelerated the transformation of ozone into hydroxyl radicals. The latter result was verified by the indirect method, using NaHSO 3 as the reductor, and the direct electron spin resonance (ESR) determination technology. The adsorption of SMX on FMSO was minimal (1.8 %). However, ozone rapidly converted SMX into various intermediates, which was exhibited by the much higher adsorption affinity on the surface of FMSO than that of SMX. The accumulation of various intermediates on the FMSO surface also increased their contact probability with the ·OH radicals generated by the ozone decomposition. The continuous interaction of intermediates with ·OH radicals could further promote the benign cycling of the release of adsorption sites and the succeeding adsorption/decomposition of ozone and intermediates on FMSO. This could be another reason for the higher and faster TOC removal rate.

  5. A high efficient integrated planar transformer for primary-parallel isolated boost converters

    DEFF Research Database (Denmark)

    Sen, Gökhan; Ouyang, Ziwei; Thomsen, Ole Cornelius

    2010-01-01

    of transformer integration is further extended to multiple primary power stages using modular geometry of the planar core, further reducing the core loss and allowing a higher power density. To verify the validity of the design approach, a 4-kW prototype converter with two primary power stages is implemented......A simple, easy to manufacture and high efficient integrated planar transformer design approach for primary parallel isolated boost converters is presented. Utilizing the same phase flux flow, transformers are integrated, reducing the total ferrite volume and core loss for the same peak flux density....... Number of turns is minimized for easy manufacturing by cascade placement of planar cores increasing the effective cross-sectional area. AC losses in the windings as well as the leakage inductance of the transformer are kept low by extensive interleaving of the primary and secondary turns. The idea...

  6. Catalytic Conversion of Renewable Resources into Bulk and Fine Chemicals.

    Science.gov (United States)

    de Vries, Johannes G

    2016-12-01

    Several strategies can be chosen to convert renewable resources into chemicals. In this account, I exemplify the route that starts with so-called platform chemicals; these are relatively simple chemicals that can be produced in high yield, directly from renewable resources, either via fermentation or via chemical routes. They can be converted into the existing bulk chemicals in a very efficient manner using multistep catalytic conversions. Two examples are given of the conversion of sugars into nylon intermediates. 5-Hydroxymethylfurfural (HMF) can be prepared in good yield from fructose. Two hydrogenation steps convert HMF into 1,6-hexanediol. Oppenauer oxidation converts this product into caprolactone, which in the past, has been converted into caprolactam in a large-scale industrial process by reaction with ammonia. An even more interesting platform chemical is levulinic acid (LA), which can be obtained directly from lignocellulose in good yield by treatment with dilute sulfuric acid at 200°C. Hydrogenation converts LA into gamma-valerolactone, which is ring-opened and esterified in a gas-phase process to a mixture of isomeric methyl pentenoates in excellent selectivity. In a remarkable selective palladium-catalysed isomerising methoxycarbonylation, this mixture is converted in to dimethyl adipate, which is finally hydrolysed to adipic acid. Overall selectivities of both processes are extremely high. The conversion of lignin into chemicals is a much more complicated task in view of the complex nature of lignin. It was discovered that breakage of the most prevalent β-O-4 bond in lignin occurs not only via the well-documented C3 pathway, but also via a C2 pathway, leading to the formation of highly reactive phenylacetaldehydes. These compounds went largely unnoticed as they immediately recondense on lignin. We have now found that it is possible to prevent this by converting these aldehydes in a tandem reaction, as they are formed. For this purpose, we have used

  7. Converting pest insects into food

    DEFF Research Database (Denmark)

    Offenberg, Hans Joachim; Wiwatwittaya, Decha

    2010-01-01

    Canopy dwelling weaver ants (Oecophylla spp.) are used to control a variety of pests in a number of tropical tree crops. What is less familiar is the existence of commercial markets where these ants and their brood are sold for (i) human consumption, (ii) pet food or (iii) traditional medicine...... on management, 32-115 kg ant brood (mainly new queens) was harvested per ha per year without detrimental effect on colony survival and worker ant densities. This suggest that ant biocontrol and ant harvest can be sustainable integrated in plantations and double benefits derived. As ant production is fuelled...... by pest insects, problematic pests are converted into food and additional earnings. To assess the profitability of providing additional food for the ants, O. smaragdina food conversion efficiency (ECI) was estimated in the laboratory. This estimate suggests the feeding of weaver ants in ant farms...

  8. High-Performance Data Converters

    DEFF Research Database (Denmark)

    Steensgaard-Madsen, Jesper

    in a standard CMOS technology, they can be designed to yield 100 dB performance at 10 times oversampling. The proposed scaled-element mismatch-shaping D/A converters are well suited for use as the feedback stage in oversampled delta-sigma quantizers. It is, however, not easy to make full use of their potential...... this problem. This way, the delta-sigma quantizer's feedback signal is obtained by a multiple-stage quantization, where the loop quantizer (low-resolution and minimum-delay) implements only the last-stage quantization. Hence, high-speed, high-resolutiondelta-sigma quantization is feasible without using complex...... circuitry. An improved version of the MASH topology is also proposed. A delta-sigma quantizer is used to quantize the input signal into an oversampled digital representation of low-to-moderate resolution. The delta-sigma quantizer'struncation error is estimated either directly, or as the first...

  9. Reliability of Wave Energy Converters

    DEFF Research Database (Denmark)

    Ambühl, Simon

    There are many different working principles for wave energy converters (WECs) which are used to produce electricity from waves. In order for WECs to become successful and more competitive to other renewable electricity sources, the consideration of the structural reliability of WECs is essential...... WEPTOS. Calibration of safety factors are performed for welded structures at theWavestar device including different control systems for harvesting energy from waves. In addition, a case study of different O&M strategies for WECs is discussed, and an example of reliability-based structural optimization....... Structural reliability considerations and optimizations impact operation and maintenance (O&M) costs as well as the initial investment costs. Furthermore, there is a control system for WEC applications which defines the harvested energy but also the loads onto the structure. Therefore, extreme loads but also...

  10. Reliability of Wave Energy Converters

    DEFF Research Database (Denmark)

    Ambühl, Simon

    There are many different working principles for wave energy converters (WECs) which are used to produce electricity from waves. In order for WECs tobecome successful and more competitive to other renewable electricity sources,the consideration of the structural reliability of WECs is essential...... for welded structures at the Wavestar device includingdifferent control systems for harvesting energy from waves. In addition, a casestudy of different O&M strategies for WECs is discussed, and an example ofreliability-based structural optimization of the Wavestar foundation ispresented. The work performed.......Structural reliability considerations and optimizations impact operation andmaintenance (O&M) costs as well as the initial investment costs.Furthermore, there is a control system for WEC applications which defines theharvested energy but also the loads onto the structure. Therefore, extremeloads but also fatigue loads...

  11. The SSG Wave Energy Converter

    DEFF Research Database (Denmark)

    Vicinanza, Diego; Margheritini, Lucia; Kofoed, Jens Peter

    2012-01-01

    The Sea-wave Slot-cone Generator concept (SSG) is a Wave Energy Converter based on the wave overtopping principle utilizing several reservoirs placed on top of each other, in which the energy of the incoming wave will be stored as potential energy. The water captured in the reservoirs will then run...... through turbines for electricity production. The system utilizes a wide spectrum of different wave conditions by means of multiple reservoirs, located at different levels above the still water level. Thereby, it obtains a high overall efficiency and it can be suitable for shoreline and breakwater...... at the Svaaheia site (Norway), Port of Hanstholm (Denmark) and Port of Garibaldi (Oregon, USA). In the last-mentioned two projects, the Sea-wave Slot-cone Generator technology is integrated into outer harbor breakwater and jetty reconstruction projects. Comprehensive studies have been performed in the last years...

  12. Error Analysis of High Frequency Core Loss Measurement for Low-Permeability Low-Loss Magnetic Cores

    DEFF Research Database (Denmark)

    Niroumand, Farideh Javidi; Nymand, Morten

    2016-01-01

    in magnetic cores is B-H loop measurement where two windings are placed on the core under test. However, this method is highly vulnerable to phase shift error, especially for low-permeability, low-loss cores. Due to soft saturation and very low core loss, low-permeability low-loss magnetic cores are favorable...... in many of the high-efficiency high power-density power converters. Magnetic powder cores, among the low-permeability low-loss cores, are very attractive since they possess lower magnetic losses in compared to gapped ferrites. This paper presents an analytical study of the phase shift error in the core....... The analysis has been validated by experimental measurements for relatively low-loss magnetic cores with different permeability values....

  13. In situ catalytic hydrogenation of model compounds and biomass-derived phenolic compounds for bio-oil upgrading

    Science.gov (United States)

    Junfeng Feng; Zhongzhi Yang; Chung-yun Hse; Qiuli Su; Kui Wang; Jianchun Jiang; Junming Xu

    2017-01-01

    The renewable phenolic compounds produced by directional liquefaction of biomass are a mixture of complete fragments decomposed from native lignin. These compounds are unstable and difficult to use directly as biofuel. Here, we report an efficient in situ catalytic hydrogenation method that can convert phenolic compounds into saturated cyclohexanes. The process has...

  14. Facile synthesis of catalytically active CeO2–Gd2O3 solid solutions ...

    Indian Academy of Sciences (India)

    exhaust gas treatment systems in diesel engines. As a consequence, various emission–reduction technologies have been developed and among them, particle traps combined with oxidation catalysts to convert soot par- ticles into gaseous products is one of the most effi- cient. Catalytic performance of soot oxidation gener-.

  15. Integrated Laser and Electron Microscopy Correlates Structure of Fluid Catalytic Cracking Particles to Brønsted Acidity

    NARCIS (Netherlands)

    Karreman, M.A.|info:eu-repo/dai/nl/315886528; Buurmans, I.L.C.|info:eu-repo/dai/nl/31406592X; Geus, J|info:eu-repo/dai/nl/412538024; Agronskaia, A.V.|info:eu-repo/dai/nl/183239830; Ruiz Martinez, J.|info:eu-repo/dai/nl/341386405; Gerritsen, H.C.|info:eu-repo/dai/nl/071548777; Weckhuysen, B.M.|info:eu-repo/dai/nl/285484397

    2012-01-01

    Fluid catalytic cracking (FCC) is the main industrial process used worldwide to convert crude oil fractions into fuels and important base chemicals, such as light olefins.[1] This is achieved by using micron-sized spherical catalyst particles of complex composition. Zeolitic material, usually

  16. Simultaneous fast pyrolysis and catalytic upgrading of lignin to obtain a marine diesel fuel

    DEFF Research Database (Denmark)

    Zhou, Guofeng

    The topic of this Ph.D. project is to convert lignin, a by-product from a 2nd generation bio-ethanol plant, into a marine diesel fuel by fast pyrolysis followed with catalytic upgrading of the pyrolysis vapor. Lignin, a major component of lignocellulosic biomass, is underutilized in the 2nd...... generation bio-ethanol plants. Shipping industry on the other hand is looking for clean alternative fuels in order to meet stricter fuel quality and emission standards. To convert lignin into a renewable marine diesel fuel will both accelerate the development of modern bio-refinery and transfer the marine...

  17. Ice Core Dating Software for Interactive Dating of Ice Cores

    Science.gov (United States)

    Kurbatov, A. V.; Mayewski, P. A.; Abdul Jawad, B. S.

    2005-12-01

    Scientists involved in ice core dating are well familiar with the problem of identification and recording the depth of annual signals using stable isotopes, glaciochemistry, ECM (electrical conductivity), DEP (dielectric properties) and particle counter data. Traditionally all parameters used for ice core dating were plotted as a function of depth, printed and after years were marked on the paper, converted to depth vs. age time scale. To expedite this tedious and manual process we developed interactive computer software, Ice core Dating (ICD) program. ICD is written in Java programming language, and uses GPL and GPL site licensed graphic libraries. The same 3.5 Mb in size pre-compiled single jar file, that includes all libraries and application code, was successfully tested on WinOS, Mac OSX, Linux, and Solaris operating systems running Java VM version 1.4. We have followed the modular design philosophy in our source code so potential integration with other software modules, data bases and server side distributed computer environments can be easily implemented. We expect to continue development of new suites of tools for easy integration of ice core data with other available time proxies. ICD is thoroughly documented and comes with a technical reference and cookbook that explains the purpose of the software and its many features, and provides examples to help new users quickly become familiar with the operation and philosophy of the software. ICD is available as a free download from the Climate Change Institute web site ( under the terms of GNU GPL public license.

  18. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    Science.gov (United States)

    Huffman, Gerald P.

    2012-11-13

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  19. Three-phase AC-AC power converters based on matrix converter topology matrix-reactance frequency converters concept

    CERN Document Server

    Szczesniak, Pawel

    2013-01-01

    AC voltage frequency changes is one of the most important functions of solid state power converters. The most desirable features in frequency converters are the ability to generate load voltages with arbitrary amplitude and frequency, sinusoidal currents and voltages waveforms; the possibility of providing unity power factor for any load; and, finally, a simple and compact power circuit. Over the past decades, a number of different frequency converter topologies have appeared in the literature, but only the converters with either a voltage or current DC link are commonly used in industrial app

  20. Catalytic Fast Pyrolysis: A Review

    Directory of Open Access Journals (Sweden)

    Theodore Dickerson

    2013-01-01

    Full Text Available Catalytic pyrolysis is a promising thermochemical conversion route for lignocellulosic biomass that produces chemicals and fuels compatible with current, petrochemical infrastructure. Catalytic modifications to pyrolysis bio-oils are geared towards the elimination and substitution of oxygen and oxygen-containing functionalities in addition to increasing the hydrogen to carbon ratio of the final products. Recent progress has focused on both hydrodeoxygenation and hydrogenation of bio-oil using a variety of metal catalysts and the production of aromatics from bio-oil using cracking zeolites. Research is currently focused on developing multi-functional catalysts used in situ that benefit from the advantages of both hydrodeoxygenation and zeolite cracking. Development of robust, highly selective catalysts will help achieve the goal of producing drop-in fuels and petrochemical commodities from wood and other lignocellulosic biomass streams. The current paper will examine these developments by means of a review of existing literature.

  1. Catalytic combustion of residual fuels

    Science.gov (United States)

    Bulzan, D. L.; Tacina, R. R.

    1981-01-01

    A noble metal catalytic reactor was tested using two grades of petroleum derived residual fuels at specified inlet air temperatures, pressures, and reference velocities. Combustion efficiencies greater than 99.5 percent were obtained. Steady state operation of the catalytic reactor required inlet air temperatures of at least 800 K. At lower inlet air temperatures, upstream burning in the premixing zone occurred which was probably caused by fuel deposition and accumulation on the premixing zone walls. Increasing the inlet air temperature prevented this occurrence. Both residual fuels contained about 0.5 percent nitrogen by weight. NO sub x emissions ranged from 50 to 110 ppm by volume at 15 percent excess O2. Conversion of fuel-bound nitrogen to NO sub x ranged from 25 to 50 percent.

  2. Catalytic electrochemistry of xanthine dehydrogenase.

    Science.gov (United States)

    Kalimuthu, Palraj; Leimkühler, Silke; Bernhardt, Paul V

    2012-09-27

    We report the mediated electrocatalytic voltammetry of the molybdoenzyme xanthine dehydrogenase (XDH) from Rhodobacter capsulatus at a thiol-modified Au electrode. The 2-electron acceptor N-methylphenazinium methanesulfonate (phenazine methosulfate, PMS) is an effective artificial electron transfer partner for XDH instead of its native electron acceptor NAD(+). XDH catalyzes the oxidative hydroxylation of hypoxanthine to xanthine and xanthine to uric acid. Cyclic voltammetry was used to generate the active (oxidized) form of the mediator. Simulation of the catalytic voltammetry across a broad range of substrate and PMS concentrations at different sweep rates was achieved with the program DigiSim to yield a set of consistent rate and equilibrium constants that describe the catalytic system. This provides the first example of the mediated electrochemistry of a xanthine dehydrogenase (or oxidase) that is uncomplicated by interference from product oxidation. A remarkable two-step, sequential oxidation of hypoxanthine to uric acid via xanthine by XDH is observed.

  3. Multilevel converters for 10 MW Wind Turbines

    DEFF Research Database (Denmark)

    Ma, Ke; Blaabjerg, Frede

    2011-01-01

    Several promising multi-level converter configurations for 10 MW Wind Turbines both with direct drive and one-stage gear box drive using Permanent Magnet Synchronous Generator (PMSG) are proposed, designed and compared. Reliability is a crucial indicator for large scale wind power converters......, therefore the evaluations are mainly focused on the power device thermal performances, which are closely related to the life time and cost of the converter. Simulation results of different converter candidates regarding the loss and junction temperature are presented and analyzed. It is concluded...... that the three-level and five-level H-bridge converter topologies both have potential to achieve improved thermal performances compared to the three-level Neutral-Point-Clamped converter topology in the wind power application....

  4. Study of catalytic upgrading of biomass tars using Indonesian iron ore

    Science.gov (United States)

    Wicakso, Doni Rahmat; Sutijan, Rochmadi, Budiman, Arief

    2017-03-01

    Catalytic decomposition is a promising way for chemical upgrading process of low quality oil such as biomass tars. In this experiment, catalytic decomposition of biomass tars was performed over Indonesian low grade iron ore catalyst. This process is carried out in a fixed bedreactor which is equipped with preheater to convert the tars into vapor form. The reaction was studied at the temperature range of 500 - 700°C. The kinetic study of catalytic decomposition of biomass tars is represented using first order reaction. The results show that value of constant of chemical reaction is in range 0.2514 - 0.9642 cm3.gr-1.min-1 with value of the frequency factor (A) and the activation energy (E) are 48.98 min-1 and 5724.94 cal.mol-1, respectively.

  5. The Impact of Enzyme Orientation and Electrode Topology on the Catalytic Activity of Adsorbed Redox Enzymes

    Science.gov (United States)

    McMillan, Duncan G. G.; Marritt, Sophie J.; Kemp, Gemma L.; Gordon-Brown, Piers; Butt, Julea N.; Jeuken, Lars J. C.

    2014-01-01

    It is well established that the structural details of electrodes and their interaction with adsorbed enzyme influences the interfacial electron transfer rate. However, for nanostructured electrodes, it is likely that the structure also impacts on substrate flux near the adsorbed enzymes and thus catalytic activity. Furthermore, for enzymes converting macro-molecular substrates it is possible that the enzyme orientation determines the nature of interactions between the adsorbed enzyme and substrate and therefore catalytic rates. In essence the electrode may impede substrate access to the active site of the enzyme. We have tested these possibilities through studies of the catalytic performance of two enzymes adsorbed on topologically distinct electrode materials. Escherichia coli NrfA, a nitrite reductase, was adsorbed on mesoporous, nanocrystalline SnO2 electrodes. CymA from Shewanella oneidensis MR-1 reduces menaquinone-7 within 200 nm sized liposomes and this reaction was studied with the enzyme adsorbed on SAM modified ultra-flat gold electrodes. PMID:24634538

  6. Gadolinium sheet converter for neutron radiography

    Energy Technology Data Exchange (ETDEWEB)

    Lima, C.T.S. [Laboratorio de Neutrongrafia em Tempo Real (LNRTR/PEN/COPPE), Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21941-972 Rio de Janeiro, RJ (Brazil); Crispim, V.R. [Laboratorio de Neutrongrafia em Tempo Real (LNRTR/PEN/COPPE), Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21941-972 Rio de Janeiro, RJ (Brazil); PEN/COPPE-DNC/Escola Politecnica CT, Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21941-972 Rio de Janeiro, RJ (Brazil)], E-mail: verginia@con.ufrj.br; Santos, W.M.S. [Laboratorio de Colisao Atomica e Molecular (LACAM/IF), Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68528, 21941-972 Rio de Janeiro, RJ (Brazil)

    2007-12-15

    This work describes a methodology developed for the confection of gadolinium sheet converter for neutron radiography using the gadolinium chloride (GdCl{sub 3}) as material converter. Though manufactured at a relatively low cost, they are as good as the sheet converter on the market. Here, we present neutron radiography of the penetrameter, the edge spread function, the modulation transfer function and characteristic curves for each set sheet-AA400 Kodak film.

  7. Ocean floor mounting of wave energy converters

    Science.gov (United States)

    Siegel, Stefan G

    2015-01-20

    A system for mounting a set of wave energy converters in the ocean includes a pole attached to a floor of an ocean and a slider mounted on the pole in a manner that permits the slider to move vertically along the pole and rotate about the pole. The wave energy converters can then be mounted on the slider to allow adjustment of the depth and orientation of the wave energy converters.

  8. Commutation Processes in Multiresonant ZVS Bridge Converter

    Directory of Open Access Journals (Sweden)

    Miroslaw Luft

    2008-01-01

    Full Text Available The analysis of the multiresonant ZVS DC/DC bridge converter is presented. The control system of the converter is basedon the method of frequency control at the constant time of transistor turn-off with a phase shift. The operation of the circuit is givenand the operating range of the converter is defined where ZVS switching operation is assured. Control characteristics are given andthe converter’s efficiency is defined. The circuit’s operation is analysed on the basis of results of the converter simulation tests using Simplorer programme.

  9. Conducted Emission Evaluation for Direct Matrix Converters

    Science.gov (United States)

    Nothofer, A.; Tarisciotti, L.; Greedy, S.; Empringham, L.; De Lillo, L.; Degano, M.

    2016-05-01

    Matrix converters have been recently proposed as an alternative solution to the standard back-to-back converter in aerospace applications. However, Electromagnetic Interference (EMI), in particular, conducted emissions represent a critical aspect for this converter family. Direct Matrix Converter (DMC) are usually modelled only at the normal operating frequency, but for the research presented in this paper, the model is modified in order to include a detailed high frequency description, which is of interest for conducted emission studies.This paper analyzes the performance of DMC, when different control and modulation techniques are used. Experimental results are shown to validate the simulation models.

  10. Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.

    Science.gov (United States)

    Mao, Bin; Fañanás-Mastral, Martín; Feringa, Ben L

    2017-08-09

    γ-Butenolides, γ-butyrolactones, and derivatives, especially in enantiomerically pure form, constitute the structural core of numerous natural products which display an impressive range of biological activities which are important for the development of novel physiological and therapeutic agents. Furthermore, optically active γ-butenolides and γ-butyrolactones serve also as a prominent class of chiral building blocks for the synthesis of diverse biological active compounds and complex molecules. Taking into account the varying biological activity profiles and wide-ranging structural diversity of the optically active γ-butenolide or γ-butyrolactone structure, the development of asymmetric synthetic strategies for assembling such challenging scaffolds has attracted major attention from synthetic chemists in the past decade. This review offers an overview of the different enantioselective synthesis of γ-butenolides and γ-butyrolactones which employ catalytic amounts of metal complexes or organocatalysts, with emphasis focused on the mechanistic issues that account for the observed stereocontrol of the representative reactions, as well as practical applications and synthetic potentials.

  11. Analysis and Comparison of Magnetic Structures in a Tapped Boost Converter for LED Applications

    DEFF Research Database (Denmark)

    Mira Albert, Maria del Carmen; Knott, Arnold; Andersen, Michael A. E.

    2014-01-01

    This paper presents an an alysis and comparison of magnetics structures in a tapped boost converter for LED applications. The magnetic structure is a coupled inductor which is analyzed in a conventional wire-wound core as well as in a planar structure for different interleaving winding arrangements...

  12. Catalysis of iron core formation in Pyrococcus furiosus ferritin

    NARCIS (Netherlands)

    Ebrahimi, K.H.; Hagedoorn, P.L.; Jongejan, J.A.; Hagen, W.R.

    2009-01-01

    The hollow sphere-shaped 24-meric ferritin can store large amounts of iron as a ferrihydrite-like mineral core. In all subunits of homomeric ferritins and in catalytically active subunits of heteromeric ferritins a diiron binding site is found that is commonly addressed as the ferroxidase center

  13. Core-shell fuel cell electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Adzic, Radoslav; Bliznakov, Stoyan; Vukmirovic, Miomir

    2017-07-25

    Embodiments of the disclosure relate to electrocatalysts. The electrocatalyst may include at least one gas-diffusion layer having a first side and a second side, and particle cores adhered to at least one of the first and second sides of the at least one gas-diffusion layer. The particle cores includes surfaces adhered to the at least one of the first and second sides of the at least one gas-diffusion layer and surfaces not in contact with the at least one gas-diffusion layer. Furthermore, a thin layer of catalytically atoms may be adhered to the surfaces of the particle cores not in contact with the at least one gas-diffusion layer.

  14. Core-shell fuel cell electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Adzic, Radoslav; Bliznakov, Stoyan; Vukmirovic, Miomir

    2017-12-26

    Embodiments of the disclosure relate to membrane electrode assemblies. The membrane electrode assembly may include at least one gas-diffusion layer having a first side and a second side, and particle cores adhered to at least one of the first and second sides of the at least one gas-diffusion layer. The particle cores includes surfaces adhered to the at least one of the first and second sides of the at least one gas-diffusion layer and surfaces not in contact with the at least one gas-diffusion layer. Furthermore, a thin layer of catalytically atoms may be adhered to the surfaces of the particle cores not in contact with the at least one gas-diffusion layer.

  15. Modeling and Simulation of Matrix Converter

    DEFF Research Database (Denmark)

    Liu, Fu-rong; Klumpner, Christian; Blaabjerg, Frede

    2005-01-01

    This paper discusses the modeling and simulation of matrix converter. Two models of matrix converter are presented: one is based on indirect space vector modulation and the other is based on power balance equation. The basis of these two models is• given and the process on modeling is introduced...

  16. Reliability of Power Electronic Converter Systems

    DEFF Research Database (Denmark)

    The main aims of power electronic converter systems (PECS) are to control, convert, and condition electrical power flow from one form to another through the use of solid-state electronics. This book outlines current research into the scientific modeling, experimentation, and remedial measures for...

  17. Time-Interleaved Analog to Digital Converters

    NARCIS (Netherlands)

    Louwsma, S.M.; van Tuijl, Adrianus Johannes Maria; Nauta, Bram

    2010-01-01

    This book describes the research carried out by our PhD student Simon Louwsma at the University of Twente, The Netherlands in the field of high-speed Analogto- Digital (AD) converters. AD converters are crucial circuits for modern systems where information is stored or processed in digital form. Due

  18. Synchronous Control of Modular Multilevel Converters

    DEFF Research Database (Denmark)

    Oleschuk, Valentin; Blaabjerg, Frede; Bose, Bimal K.

    2002-01-01

    for each module and the composed voltage at the output of the converter. Multilevel output voltage of the converter has quarter-wave symmetry during the whole range including the zone of overmodulation. Both continuous and discontinuous versions of synchronous PWM, based on vector approach...

  19. High Precision Current Measurement for Power Converters

    CERN Document Server

    Cerqueira Bastos, M

    2015-01-01

    The accurate measurement of power converter currents is essential to controlling and delivering stable and repeatable currents to magnets in particle accelerators. This paper reviews the most commonly used devices for the measurement of power converter currents and discusses test and calibration methods.

  20. RF digital-to-analog converter

    Science.gov (United States)

    Conway, P.H.; Yu, D.U.L.

    1995-02-28

    A digital-to-analog converter is disclosed for producing an RF output signal proportional to a digital input word of N bits from an RF reference input, N being an integer greater or equal to 2. The converter comprises a plurality of power splitters, power combiners and a plurality of mixers or RF switches connected in a predetermined configuration. 18 figs.

  1. Modelling and Control of Grid converter

    DEFF Research Database (Denmark)

    Teodorescu, Remus; Blaabjerg, Frede; Iov, Florin

    The present report describes the work done in the Phase 1a during the research project "Modelling and Control of Grid Converter". The developed models for the plant and different control strategies for the grid converter are presented in detail. Simulation results under different operating...

  2. Modelling and Control of Grid converter

    DEFF Research Database (Denmark)

    Iov, Florin; Teodorescu, Remus; Blaabjerg, Frede

    The present report describes the work done in the Phase 1b during the research project "Modelling and Control of Grid Converter". The models used in simulations are presented in detail. Two control strategies for the grid converter are considered for investigations, namely the Adaptive Band...

  3. Present trends in HVDC converter station design

    Energy Technology Data Exchange (ETDEWEB)

    Carlsson, Lennart; Asplund, Gunnar; Bjorklund, Hans; Flisberg, Gunnar [ABB Power Systems AB, Ludvika (Sweden)

    1994-12-31

    HVDC converter station technology has developed rapidly to satisfy increasing requirements during past 10 - 15 years, but there has not been any dramatic changes since thyristor valves were introduced in the mid 70s. This paper describes some recent and expected future developments, that will substantiality change and simplify future converter stations. (author) 4 refs., 7 figs.

  4. Step-Up DC-DC converters

    DEFF Research Database (Denmark)

    Forouzesh, Mojtaba; Siwakoti, Yam P.; Gorji, Saman A.

    2017-01-01

    on the general law and framework of the development of next-generation step-up dc-dc converters, this paper aims to comprehensively review and classify various step-up dc-dc converters based on their characteristics and voltage-boosting techniques. In addition, the advantages and disadvantages of these voltage...

  5. Modelling, analyses and design of switching converters

    Science.gov (United States)

    Cuk, S. M.; Middlebrook, R. D.

    1978-01-01

    A state-space averaging method for modelling switching dc-to-dc converters for both continuous and discontinuous conduction mode is developed. In each case the starting point is the unified state-space representation, and the end result is a complete linear circuit model, for each conduction mode, which correctly represents all essential features, namely, the input, output, and transfer properties (static dc as well as dynamic ac small-signal). While the method is generally applicable to any switching converter, it is extensively illustrated for the three common power stages (buck, boost, and buck-boost). The results for these converters are then easily tabulated owing to the fixed equivalent circuit topology of their canonical circuit model. The insights that emerge from the general state-space modelling approach lead to the design of new converter topologies through the study of generic properties of the cascade connection of basic buck and boost converters.

  6. Periodic Control of Power Electronic Converters

    DEFF Research Database (Denmark)

    Zhou, Keliang; Danwei, Wang; Yang, Yongheng

    Advanced power electronic converters convert, control and condition electricity. Power converters require control strategies for periodic signal compensation to assure good power quality and stable power system operation. This comprehensive text presents the most recent internal model principle...... based periodic control technology, which offers the perfect periodic control solution for power electronic conversion. It also provides complete analysis and synthesis methods for periodic control systems, and plenty of practical examples to demonstrate the validity of proposed periodic control...... technology for power converters. It proposes a unified framework for housing periodic control schemes for power converters, and provides a general proportional-integral-derivative control solution to periodic signal compensation in extensive engineering applications. Periodic Control of Power Electronic...

  7. A review of Indirect Matrix Converter Topologies

    Directory of Open Access Journals (Sweden)

    Salem Rahmani

    2015-08-01

    Full Text Available Abstract—Matrix Converter (MC is a modern direct AC/AC electrical power converter without dc-link capacitor. MC is operated in four quadrant, assuring a control of the output voltage, amplitude and frequency. The matrix converter has recently attracted significant attention among researchers and it has become increasing attractive for applications of wind energy conversion, military power supplies, induction motor drives, etc. Recently, different MC topologies have been proposed and developed which have their own advantages and disadvantages. Matrix converter can be classified as direct and indirect structures. The direct one has been elaborated in previous work. In this paper the indirect MCs are reviewed. Different characteristics of the indirect MC topologies are mentioned to show the strengths and weaknesses of such converter topologies.

  8. Switched Mode Four-Quadrant Converters

    CERN Document Server

    Thurel, Y

    2015-01-01

    This paper was originally presented at CAS-2004, and was slightly modified for CAS-2014. It presents a review of the key parameters that impact the design choices for a true four-quadrant power converter, in the range 1-10 kW, mainly based on switching mode converter topology. This paper will first describe the state-of-the-art for this power converter family, giving the drawbacks and advantages of different possible solutions. It will also present practical results obtained from the CERN-designed converter. It will finally give some important tips regarding critical phases like test one, when conducting a project dealing with this type of power converter.

  9. single-phase dc phase dc-ac boost converter ac boost converter

    African Journals Online (AJOL)

    User

    This paper describes a new power conversion circuit dc-dc boost converter. It boost converter. It boost converter. It comprises an H comprises an H. Change of load .... A full-wave rectified signal is used to produce an AC reference voltage v* o. The outer voltage loop generates the reference current command i* f. A common.

  10. Monodisperse Ag/Pd core/shell nanoparticles assembled on reduced graphene oxide as highly efficient catalysts for the transfer hydrogenation of nitroarenes.

    Science.gov (United States)

    Metin, Önder; Can, Hasan; Şendil, Kıvılcım; Gültekin, Mehmet Serdar

    2017-07-15

    Addressed herein is a facile seed-mediated synthesis of Ag/Pd core/shell nanoparticles (NPs) and their assembly on reduced graphene oxide (rGO) to catalyze the transfer hydrogenation of nitroarenes to anilines using ammonia borane (AB) as a hydrogen donor under ambient conditions. Monodisperse Ag/Pd core/shell NPs with controllable Pd shell-thickness were synthesized by the means of thermal decomposition of palladium(II) bromide over as-prepared Ag NPs in the mixture of oleylamine and oleic acid at 220°C. As-synthesized Ag/Pd core/shell NPs were characterized by TEM, HR-TEM, XRD, XPS, UV-Vis spectroscopy and ICP-MS and then they were assembled on reduced graphene oxide (rGO). Next, rGO@Ag/Pd catalysts were tested in the transfer hydrogenation of nitroarenes in which ammonia borane (AB) was used as a hydrogen donor at room temperature. It was demonstrated that the thickness of the Pd shell has a significant effect on the catalytic activity of rGO@Ag/Pd catalysts and the 1.75nm Pd shell provided the highest performance in the transfer hydrogenation reactions. The rGO@Ag/Pd catalyzed transfer hydrogenation reactions were tested over a variety of nitroarenes (total 16 examples) and they were all converted to the corresponding aniline derivatives with high yields in 5-15min under ambient conditions. Copyright © 2017 Elsevier Inc. All rights reserved.

  11. Dynamic Responsive Systems for Catalytic Function.

    Science.gov (United States)

    Vlatković, Matea; Collins, Beatrice S L; Feringa, Ben L

    2016-11-21

    Responsive systems have recently gained much interest in the scientific community in attempts to mimic dynamic functions in biological systems. One of the fascinating potential applications of responsive systems lies in catalysis. Inspired by nature, novel responsive catalytic systems have been built that show analogy with allosteric regulation of enzymes. The design of responsive catalytic systems allows control of catalytic activity and selectivity. In this Review, advances in the field over the last four decades are discussed and a comparison is made amongst the dynamic responsive systems based on the principles underlying their catalytic mechanisms. The catalyst systems are sorted according to the triggers used to achieve control of the catalytic activity and the distinct catalytic reactions illustrated. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Kinetics of heterogeneous catalytic reactions

    CERN Document Server

    Boudart, Michel

    2014-01-01

    This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These paperback editions preserve the original texts of these important books while presenting them in durable paperback editions. The goal of the Princeton Legacy Library is to vastly increase acc

  13. Catalytic Decoupling of Quantum Information.

    Science.gov (United States)

    Majenz, Christian; Berta, Mario; Dupuis, Frédéric; Renner, Renato; Christandl, Matthias

    2017-02-24

    The decoupling technique is a fundamental tool in quantum information theory with applications ranging from thermodynamics to many-body physics and black hole radiation whereby a quantum system is decoupled from another one by discarding an appropriately chosen part of it. Here, we introduce catalytic decoupling, i.e., decoupling with the help of an independent system. Thereby, we remove a restriction on the standard decoupling notion and present a tight characterization in terms of the max-mutual information. The novel notion unifies various tasks and leads to a resource theory of decoupling.

  14. Studies of coupled chemical and catalytic coal conversion methods

    Energy Technology Data Exchange (ETDEWEB)

    Stock, L.M.; Chatterjee, K.; Cheng, C.; Ettinger, M.; Flores, F.; Jiralerspong, S.; Miyake, M.; Muntean, J.

    1991-12-01

    The objective of this research was to convert coal into a soluble substance under mild conditions. The strategy involved two steps, first to breakdown the macromolecular network of coal, and second to add hydrogen catalytically. We investigated different basic reagents that could, in priciple, break down coal`s structure and alkylation strategies that might enhance its solubility. We examined O- and C-alkylation, the importance of the strength of the base, the character of the added alkyl groups and other reaction parameters. This work provided new information concerning the way in which hydrogen bonding, polarization interactions between aromatic structures and covalent bonding could be disrupted and solubility enhanced. The objective of our research was to explore new organochromium chemistry that might be feasible for the hydrogenation of coal under mild conditions.

  15. Studies of coupled chemical and catalytic coal conversion methods

    Energy Technology Data Exchange (ETDEWEB)

    Stock, L.M.; Chatterjee, K.; Cheng, C.; Ettinger, M.; Flores, F.; Jiralerspong, S.; Miyake, M.; Muntean, J.

    1991-12-01

    The objective of this research was to convert coal into a soluble substance under mild conditions. The strategy involved two steps, first to breakdown the macromolecular network of coal, and second to add hydrogen catalytically. We investigated different basic reagents that could, in priciple, break down coal's structure and alkylation strategies that might enhance its solubility. We examined O- and C-alkylation, the importance of the strength of the base, the character of the added alkyl groups and other reaction parameters. This work provided new information concerning the way in which hydrogen bonding, polarization interactions between aromatic structures and covalent bonding could be disrupted and solubility enhanced. The objective of our research was to explore new organochromium chemistry that might be feasible for the hydrogenation of coal under mild conditions.

  16. Studies of coupled chemical and catalytic coal conversion methods

    Energy Technology Data Exchange (ETDEWEB)

    Stock, L.M.

    1990-01-01

    This report concerns our research on base-catalyzed coal solubilization and a new approach for hydrogen addition. The work on base-catalyzed, chemical solubilization is continuing. this report is focused on the hydrogenation research. Specifically it deals with the use of arene chromium carbonyl complexes as reagents for the addition of dideuterium to coal molecules. In one phase of the work, he has established that the aromatic hydrocarbons in a representative coal liquid can be converted in very good yield to arene chromium carbonyl compounds. In a second phase of the work directly related to our objective of improved methods for catalytic hydrogenation, he has established that the aromatic constituents of the same coal liquid add dideuterium in the presence of added napththalene chromium carbonyl.

  17. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  18. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  19. Catalytic conversion of methane: Carbon dioxide reforming and oxidative coupling

    KAUST Repository

    Takanabe, Kazuhiro

    2012-01-01

    Natural gas conversion remains one of the essential technologies for current energy needs. This review focuses on the mechanistic aspects of the development of efficient and durable catalysts for two reactions, carbon dioxide reforming and the oxidative coupling of methane. These two reactions have tremendous technological significance for practical application in industry. An understanding of the fundamental aspects and reaction mechanisms of the catalytic reactions reviewed in this study would support the design of industrial catalysts. CO 2 reforming of methane utilizes CO 2, which is often stored in large quantities, to convert as a reactant. Strategies to eliminate carbon deposition, which is the major problem associated with this reaction, are discussed. The oxidative coupling of methane directly produces ethylene in one reactor through a slightly exothermic reaction, potentially minimizing the capital cost of the natural gas conversion process. The focus of discussion in this review will be on the attainable yield of C 2 products by rigorous kinetic analyses.

  20. Computational Introduction of Catalytic Activity into Proteins.

    Science.gov (United States)

    Bertolani, Steve J; Carlin, Dylan Alexander; Siegel, Justin B

    2016-01-01

    Recently, there have been several successful cases of introducing catalytic activity into proteins. One method that has been used successfully to achieve this is the theozyme placement and enzyme design algorithms implemented in Rosetta Molecular Modeling Suite. Here, we illustrate how to use this software to recapitulate the placement of catalytic residues and ligand into a protein using a theozyme, protein scaffold, and catalytic constraints as input.

  1. Fuel rich and fuel lean catalytic combustion of the stabilized confined turbulent gaseous diffusion flames over noble metal disc burners

    Directory of Open Access Journals (Sweden)

    Amal S. Zakhary

    2014-03-01

    Full Text Available Catalytic combustion of stabilized confined turbulent gaseous diffusion flames using Pt/Al2O3 and Pd/Al2O3 disc burners situated in the combustion domain under both fuel-rich and fuel-lean conditions was experimentally studied. Commercial LPG fuel having an average composition of: 23% propane, 76% butane, and 1% pentane was used. The thermal structure of these catalytic flames developed over Pt/Al2O3 and Pd/Al2O3 burners were examined via measuring the mean temperature distribution in the radial direction at different axial locations along the flames. Under-fuel-rich condition the flames operated over Pt catalytic disc attained high temperature values in order to express the progress of combustion and were found to achieve higher activity as compared to the flames developed over Pd catalytic disc. These two types of catalytic flames demonstrated an increase in the reaction rate with the downstream axial distance and hence, an increase in the flame temperatures was associated with partial oxidation towards CO due to the lack of oxygen. However, under fuel-lean conditions the catalytic flame over Pd catalyst recorded comparatively higher temperatures within the flame core in the near region of the main reaction zone than over Pt disc burner. These two catalytic flames over Pt and Pd disc burners showed complete oxidation to CO2 since the catalytic surface is covered by more rich oxygen under the fuel-lean condition.

  2. Nanostructured Catalytic Reactors for Air Purification Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase I project proposes the development of lightweight compact nanostructured catalytic reactors for air purification from toxic gaseous organic...

  3. Nanostructured Catalytic Reactors for Air Purification Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase II project proposes the development of lightweight compact nanostructured catalytic reactors for air purification from toxic gaseous organic...

  4. Catalytic enantioselective Reformatsky reaction with ketones

    NARCIS (Netherlands)

    Fernandez-Ibanez, M. Angeles; Macia, Beatriz; Minnaard, Adriaan J.; Feringa, Ben L.

    2008-01-01

    Chiral tertiary alcohols were obtained with good yields and enantioselectivities via a catalytic Reformatsky reaction with ketones, including the challenging diaryl ketones, using chiral BINOL derivatives.

  5. Animal MRI Core

    Data.gov (United States)

    Federal Laboratory Consortium — The Animal Magnetic Resonance Imaging (MRI) Core develops and optimizes MRI methods for cardiovascular imaging of mice and rats. The Core provides imaging expertise,...

  6. Catalytic systems used for polymerization, biomass conversion, and enhancing diffusion

    Science.gov (United States)

    Pong, Frances

    revealed that these angstrom sized catalysts nearly double the speed of diffusion of passive molecular tracers in their immediate surroundings. This result is particularly intriguing because in this size regime, the viscosity of the surroundings is expected to completely overcome the inertial forces of these catalysts. This study has prompted further diffusion-NMR studies of molecular catalysts and enzymes as molecular motors. Catalytic systems play a crucial role in the conversion of renewable biomasses into energy and useful materials. This field of research has become increasingly important and lucrative as fossil fuel sources continue to decline/destabilize in the face of increased worldwide demand for more resources. In this work (iii), the efficacy of a hydrogen-pressurized, biphasic catalytic system to convert linear sugar polyols to iodoalkanes was examined. These iodoalkanes can easily be converted to 1-alkenes which can then be used for the synthesis of low density polyethylene. The results indicated that the system products were relatively pure and that the catalytic layer had a degree of recyclability, hinting that such a system may be viable for industrial use.

  7. Recent progress on synthesis of ceramics core/shell nanostructures

    Directory of Open Access Journals (Sweden)

    Vladimir V. Srdić

    2013-06-01

    Full Text Available Thin surface layers on fine particles were found to substantially change their functionalities and properties, such as chemical reactivity, thermal stability, catalytic activity, dispersibility, or optical, magnetic and electronic properties. Because of that, the core/shell nanostructures have opened up research opportunities in almost all areas of science and engineering, including medicine, catalysis, biotechnology, chemistry, optics, electronics, energy storage, etc. Immense efforts have been implied to produce and investigate different core/shell systems, and thereby, various synthesis techniques have been developed. In this review, we report adetailed overview of different synthesis techniques used for preparation of various ceramics core/shell nanostructures with tunable size and tailored structure.

  8. Catalytic reforming feed characterisation technique

    Energy Technology Data Exchange (ETDEWEB)

    Larraz Mora, R.; Arvelo Alvarez, R. [Univ. of La Laguna, Chemical Engineering Dept., La Laguna (Spain)

    2002-09-01

    The catalytic reforming of naphtha is one of the major refinery processes, designed to increase the octane number of naphtha or to produce aromatics. The naphtha used as catalytic reformer feedstock usually contains a mixture of paraffins, naphthenes, and aromatics in the carbon number range C{sub 6} to C{sub 10}. The detailed chemical composition of the feed is necessary to predict the aromatics and hydrogen production as well as the operation severity. The analysis of feed naphtha is usually reported in terms of its ASTM distillation curve and API or specific gravity. Since reforming reactions are described in terms of lumped chemical species (paraffins, naphthenes and aromatics), a feed characterisation technique should be useful in order to predict reforming operating conditions and detect feed quality changes. Unfortunately online analyzer applications as cromatography or recently introduced naphtha NMR [1] are scarce in most of refineries. This work proposes an algorithmic characterisation method focusing on its main steps description. The method could help on the subjects previously described, finally a calculation example is shown. (orig.)

  9. Electromagnetic Compatibility of Matrix Converter System

    Directory of Open Access Journals (Sweden)

    S. Fligl

    2006-12-01

    Full Text Available The presented paper deals with matrix converters pulse width modulation strategies design with emphasis on the electromagnetic compatibility. Matrix converters provide an all-silicon solution to the problem of converting AC power from one frequency to another, offering almost all the features required of an ideal static frequency changer. They possess many advantages compared to the conventional voltage or current source inverters. A matrix converter does not require energy storage components as a bulky capacitor or an inductance in the DC-link, and enables the bi-directional power flow between the power supply and load. The most of the contemporary modulation strategies are able to provide practically sinusoidal waveforms of the input and output currents with negligible low order harmonics, and to control the input displacement factor. The perspective of matrix converters regarding EMC in comparison with other types of converters is brightly evident because it is no need to use any equipment for power factor correction and current and voltage harmonics reduction. Such converter with proper control is properly compatible both with the supply mains and with the supplied load. A special digital control system was developed for the realized experimental test bed which makes it possible to achieve greater throughput of the digital control system and its variability.

  10. Underwater noise from a wave energy converter

    DEFF Research Database (Denmark)

    Tougaard, Jakob

    A recent addition to the anthropogenic sources of underwater noise is offshore wave energy converters. Underwater noise was recorded from the Wavestar wave energy converter located at Hastholm, Denmark (57°7.73´N, 8°37.23´E). The Wavestar is a full-scale test and demonstration converter...... in full operation and start and stop of the converter. Median broad band (10 Hz – 20 kHz) sound pressure level (Leq) was 123 dB re. 1 Pa, irrespective of status of the wave energy converter (stopped, running or starting/stopping). The most pronounced peak in the third-octave spectrum was in the 160 Hz...... significant noise above ambient could be detected above the 250 Hz band. The absolute increase in noise above ambient was very small. L50 third-octave levels in the four bands with the converter running were thus only 1-2 dB above ambient L50 levels. The noise recorded 25 m from the wave energy converter...

  11. Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels.

    Science.gov (United States)

    Zhou, Chun-Hui; Xia, Xi; Lin, Chun-Xiang; Tong, Dong-Shen; Beltramini, Jorge

    2011-11-01

    Lignocellulosic biomass is the most abundant and bio-renewable resource with great potential for sustainable production of chemicals and fuels. This critical review provides insights into the state-of the-art accomplishments in the chemocatalytic technologies to generate fuels and value-added chemicals from lignocellulosic biomass, with an emphasis on its major component, cellulose. Catalytic hydrolysis, solvolysis, liquefaction, pyrolysis, gasification, hydrogenolysis and hydrogenation are the major processes presently studied. Regarding catalytic hydrolysis, the acid catalysts cover inorganic or organic acids and various solid acids such as sulfonated carbon, zeolites, heteropolyacids and oxides. Liquefaction and fast pyrolysis of cellulose are primarily conducted over catalysts with proper acidity/basicity. Gasification is typically conducted over supported noble metal catalysts. Reaction conditions, solvents and catalysts are the prime factors that affect the yield and composition of the target products. Most of processes yield a complex mixture, leading to problematic upgrading and separation. An emerging technique is to integrate hydrolysis, liquefaction or pyrolysis with hydrogenation over multifunctional solid catalysts to convert lignocellulosic biomass to value-added fine chemicals and bio-hydrocarbon fuels. And the promising catalysts might be supported transition metal catalysts and zeolite-related materials. There still exist technological barriers that need to be overcome (229 references). This journal is © The Royal Society of Chemistry 2011

  12. Selective harmonic control for power converters

    DEFF Research Database (Denmark)

    Zhou, Keliang; Yang, Yongheng; Blaabjerg, Frede

    2014-01-01

    This paper proposes an Internal Model Principle (IMP) based Selective Harmonic Controller (SHC) for power converters. The proposed SHC offers an optimal control solution for power converters to mitigate power harmonics. It makes a good trade-off among cost, complexity and performance. It has high...... accuracy and fast transient response, and it is cost-effective, easy for real-time implementation, and compatible for design rules-of-thumb. An application on a three-phase PWM converter has confirmed the effectiveness of the proposed control scheme in terms of harmonic mitigation....

  13. Reliability of Power Electronic Converter Systems

    DEFF Research Database (Denmark)

    for advancing the reliability, availability, system robustness, and maintainability of PECS at different levels of complexity. Drawing on the experience of an international team of experts, this book explores the reliability of PECS covering topics including an introduction to reliability engineering in power......-tolerant adjustable speed drive systems; mission profile oriented reliability design in wind turbine and photovoltaic systems; reliability of power conversion systems in photovoltaic applications; power supplies for computers; and high-power converters. Reliability of Power Electronic Converter Systems is essential...... reading for researchers, professionals and students working with power electronics and their applications, particularly those specializing in the development and application of power electronic converters and systems....

  14. A Discrete Modeling Approach for Buck Converter

    Science.gov (United States)

    Zhaoxia, Leng; Qingfeng, Liu; Jinkun, Sun; Huamin, Wang

    In this paper, a discrete modeling approach for Buck converters based on continuous condition mode (CCM) and discontinuous condition mode (DCM) was presented. The unified coefficient matrixes of discrete model were described by building a mathematical function and the calculation methods of the parameters in coefficient matrixes were given. The working states of Buck converter on various work conditions were described adopting one discrete equation. The validity of the proposed modeling approach was proved by contrasting the output of discrete model with the operation result of Buck converter system in Simulink.

  15. High-power converters and AC drives

    CERN Document Server

    Wu, Bin

    2017-01-01

    This new edition reflects the recent technological advancements in the MV drive industry, such as advanced multilevel converters and drive configurations. It includes three new chapters, Control of Synchronous Motor Drives, Transformerless MV Drives, and Matrix Converter Fed Drives. In addition, there are extensively revised chapters on Multilevel Voltage Source Inverters and Voltage Source Inverter-Fed Drives. This book includes a systematic analysis on a variety of high-power multilevel converters, illustrates important concepts with simulations and experiments, introduces various megawatt drives produced by world leading drive manufacturers, and addresses practical problems and their mitigations methods.

  16. Pseudolog Digital-to-Analog Converter

    Science.gov (United States)

    Gooder, S. T.

    1986-01-01

    Sensitivity decreases by 10 at beginning of each input decade. Method conceived to convert binary-coded data to suitable linear form for stripchart recording. Strip-chart recordings obtained from typical pressure readings in a vacuum system during pumpdown. In reading curve, BCD digital vacuum-gage output processed by analog-to-digital converter in such way that only reading digits (but not range) appear in output. In range and reading, range also converted to analog and placed as most significant digit.

  17. Programmable Analog-To-Digital Converter

    Science.gov (United States)

    Kist, Edward H., Jr.

    1993-01-01

    High-speed analog-to-digital converter with programmable voltage steps that can be changed during operation. Allows concentration of converter resolution over specific portion of waveform. Particularly useful in digitizing wind-shear radar and lidar return signals, in digital oscilloscopes, and other applications in which desirable to increase digital resolution over specific area of waveform while accepting lower resolution over rest of waveform. Effective increase in dynamic range achieved without increase in number of analog-to-digital converter bits. Enabling faster analog-to-digital conversion.

  18. Heatsink Design of High Power Converter

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chan Ki [Chungang University (Korea)

    1999-04-01

    Various ways of designing heat sink are available for commercial high power converters and among them, the method of air cooling is the most popular and practical method than any other ones. In this paper, a practical method of cooling high power converter, which includes a method of reducing noise and vibration caused by the fan and a method of estimating the gap and contact resistances existing between the thyristor and heat sink, is presented. Finally, the heat transfer analysis and implementation methods of heat sink for high power converter is presented. (author). 14 refs., 11 figs., 3 tabs.

  19. Power Electronics Converters for Wind Turbine Systems

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Liserre, Marco; Ma, Ke

    2012-01-01

    The steady growth of installed wind power together with the upscaling of the single wind turbine power capability has pushed the research and development of power converters toward full-scale power conversion, lowered cost pr kW, increased power density, and also the need for higher reliability......, in the latter case with attention to series connection and parallel connection either electrical or magnetic ones (multiphase/windings machines/transformers). It is concluded that as the power level increases in wind turbines, medium-voltage power converters will be a dominant power converter configuration...

  20. Data preparation for CORE system in a MEBES environment

    Science.gov (United States)

    Lin, Ming-Huei

    1994-11-01

    Early in 1993 a CORE-2564 was installed in Taiwan Mask Corporation (TMC). This was in addition to the two existing MEBES-III systems. We have developed a data preparation system which we call `PRE-CORE' to integrate the CORE system into our existing MEBES-based environment. This PRE-CORE system consists of a high speed workstation and CATS software, supplied by Transcription Enterprises Limited. The system links CORE-2564 and the original data processing computer through the Ethernet network. The data files are converted by the PRE-CORE system into a simpler format for CORE to handle. The time spent in data preparation in the CORE system is significantly reduced, and therefore more time is available for plate-writing. Furthermore, due to this simpler data format, CORE can write masks in precise address units faster than was previously possible, regardless of whether or not the patterns are scaled. This helps produce high quality reticles while at the same time enhancing turn around time. However, in the first stage the TMC lithographic process bias remains the same for both MEBES and CORE plates. In this paper, the PRE-CORE data treatment methodology will be described. The benefits of using PRE-CORE will be compared to results achieved without the pre-processing of PRE-CORE.

  1. multilevel buck converter for automotive electrical load

    African Journals Online (AJOL)

    user

    MULTILEVEL BUCK CONVERTER FOR AUTOMOTIVE ELECTRICAL LOAD. E. T. Yabefa1,* and D. Ebregbe2. 1ELECTRICAL DEPARTMENT, BAYELSA STATE COLLEGE OF ARTS & SCIENCE (BYCAS) YENAGOA, BAYELSA STATE NIGERIA. 2ELECTRICAL ENGINEERING DEPARTMENT, NIGER DELTA UNIVERSITY, ...

  2. Reliability of power electronic converter systems

    CERN Document Server

    Chung, Henry Shu-hung; Blaabjerg, Frede; Pecht, Michael

    2016-01-01

    This book outlines current research into the scientific modeling, experimentation, and remedial measures for advancing the reliability, availability, system robustness, and maintainability of Power Electronic Converter Systems (PECS) at different levels of complexity.

  3. State estimation for wave energy converters

    Energy Technology Data Exchange (ETDEWEB)

    Bacelli, Giorgio; Coe, Ryan Geoffrey

    2017-04-01

    This report gives a brief discussion and examples on the topic of state estimation for wave energy converters (WECs). These methods are intended for use to enable real-time closed loop control of WECs.

  4. Load balancing multimodule switching power converters

    Science.gov (United States)

    Mclyman, W. T.; Wester, G. W.

    1979-01-01

    Regulating system individually adjusts duty cycles of modules so that all share load equally, thus, protects individual modules and their components from overload and increases reliability and life expectancy. Converters are alternative to high-power, single unit systems.

  5. A three-port direct current converter

    DEFF Research Database (Denmark)

    2016-01-01

    The three-port direct current converter comprising: at least one input direct current source; at least one storage battery; a primary side circuit; a secondary side circuit; a first single magnetic component shared by the primary side circuit and the secondary side circuit, wherein the primary side...... circuit comprises a connection between the at least one input direct current source and the at least one storage battery, the primary side circuit configured for operating as a buck converter; a second magnetic component serially coupled to the first single magnetic component, wherein the first and second...... magnetic components are configured to perform a voltage step-up, wherein the secondary side circuit comprises a connection between the at least one storage battery and at least one load, the secondary side configured for operating as a tapped boost converter; wherein the three-port direct current converter...

  6. Third order digital-to-analog converter

    Science.gov (United States)

    Dotson, W. P.

    1972-01-01

    System, consisting of sample and hold digital-to-analog converter, clock circuit, sample delay circuit, initial condition circuit and interpolator circuit, improves accuracy of reconstructed analog signal without increasing sample rates.

  7. (PFC) converters feeding brushless DC motor drive

    African Journals Online (AJOL)

    DR OKE

    1Department of Electrical Engineering, Indian Institute of Technology Delhi, INDIA ... configurations of PFC converters feeding BLDC motor drive are presented as low ..... In future, it is expected for a continuing research in the quest of energy ...

  8. Input-output rearrangement of isolated converters

    DEFF Research Database (Denmark)

    Madsen, Mickey Pierre; Kovacevic, Milovan; Mønster, Jakob Døllner

    2015-01-01

    This paper presents a new way of rearranging the input and output of isolated converters. The new arrangement posses several advantages, as increased voltage range, higher power handling capabilities, reduced voltage stress and improved efficiency, for applications where galvanic isolation...

  9. Catalytic gasification of dry and wet biomass

    NARCIS (Netherlands)

    van Rossum, G.; Potic, B.; Kersten, Sascha R.A.; van Swaaij, Willibrordus Petrus Maria

    2009-01-01

    Catalytic gasification of dry biomass and of wet biomass streams in hot compressed water are reviewed and discussed as potential technologies for the production of synthesis gas, hydrogen- and methane-rich gas. Next to literature data also new experimental results from our laboratory on catalytic

  10. Understanding catalytic biomass conversion through data mining

    NARCIS (Netherlands)

    Ras, E.J.; McKay, B.; Rothenberg, G.

    2010-01-01

    Catalytic conversion of biomass is a key challenge that we chemists face in the twenty-first century. Worldwide, research is conducted into obtaining bulk chemicals, polymers and fuels. Our project centres on glucose valorisation via furfural derivatives using catalytic hydrogenation. We present

  11. Heterogeneous catalytic degradation of polyacrylamide solution | Hu ...

    African Journals Online (AJOL)

    Modified with trace metal elements, the catalytic activity of Fe2O3/Al2O3 could be changed greatly. Among various trace metal elements, Fe2O3/Al2O3 catalysts modified with Co and Cu showed great increase on catalytic activity. International Journal of Engineering, Science and Technology, Vol. 2, No. 7, 2010, pp. 110- ...

  12. Wide Input Range Power Converters Using a Variable Turns Ratio Transformer

    DEFF Research Database (Denmark)

    Ouyang, Ziwei; Andersen, Michael A. E.

    2016-01-01

    of diagonal secondary windings, in order to make the transformer turns ratio adjustable by controlling the phase between the two current excitations subjected to the two primary windings. Full-bridge boost dc-dc converter is employed with the proposed transformer to demonstrate the feasibility of the variable......A new integrated transformer with variable turns ratio is proposed to enable dc-dc converters operating over a wide input voltage range. The integrated transformer employs a new geometry of magnetic core with “four legs”, two primary windings with orthogonal arrangement, and “8” shape connection...

  13. Optimized Integrated Harmonic Filter Inductor for Dual-Converter-Fed Open-End Transformer Topology

    DEFF Research Database (Denmark)

    Gohil, Ghanshyamsinh Vijaysinh; Bede, Lorand; Teodorescu, Remus

    2017-01-01

    Many high power converter systems are often connected to the medium voltage network using a step-up transformer. In such systems, the converter-side windings of the transformer can be configured as an open-end and multi-level voltage waveforms can be achieved by feeding these open-end windings from...... in this paper, where the flux in the common part of the magnetic core is completely canceled out. As a result, the size of the magnetic component can be significantly reduced. A multi-objective design optimization is presented, where the energy loss and the volume are optimized. The optimization process takes...

  14. Fast simulation techniques for switching converters

    Science.gov (United States)

    King, Roger J.

    1987-01-01

    Techniques for simulating a switching converter are examined. The state equations for the equivalent circuits, which represent the switching converter, are presented and explained. The uses of the Newton-Raphson iteration, low ripple approximation, half-cycle symmetry, and discrete time equations to compute the interval durations are described. An example is presented in which these methods are illustrated by applying them to a parallel-loaded resonant inverter with three equivalent circuits for its continuous mode of operation.

  15. Solid-state power converter repeatability analysis

    CERN Document Server

    Dal Gobbo, Anthony; Aguglia, Davide

    2015-01-01

    This paper presents a method for evaluating power converter repeatability. The focus is on solid-state switch mode power converter for which the most problematic non-repeatability sources are the jitter of the drivers and of the switches leading to output voltage pulses bad repeatability. Both driver and switch turn-on and turn-off delay dispersion have been measured. These measurements confirm that the delay is Gaussian distributed and that the repeatability prediction method is valid.

  16. Switching power converters medium and high power

    CERN Document Server

    Neacsu, Dorin O

    2013-01-01

    An examination of all of the multidisciplinary aspects of medium- and high-power converter systems, including basic power electronics, digital control and hardware, sensors, analog preprocessing of signals, protection devices and fault management, and pulse-width-modulation (PWM) algorithms, Switching Power Converters: Medium and High Power, Second Edition discusses the actual use of industrial technology and its related subassemblies and components, covering facets of implementation otherwise overlooked by theoretical textbooks. The updated Second Edition contains many new figures, as well as

  17. Utilization of Nonlinear Converters for Audio Amplification

    OpenAIRE

    Iversen, Niels; Birch, Thomas; Knott, Arnold

    2012-01-01

    Class D ampliers ts the automotive demands quite well. The traditional buck-based amplier has reduced both the cost and size of ampliers. However the buck topology is not without its limitations. The maximum peak AC output voltage produced by the power stage is only equal the supply voltage. The introduction ofnon-linear converters for audio amplication defeats this limitation. A Cuk converter, designed to deliver an AC peak output voltage twice the supply voltage, is presented in this paper....

  18. ANALOG-TO-DIGITAL DATA CONVERTER

    Science.gov (United States)

    Rodgers, G.W.; Althouse, J.E.; Anderson, D.P.; Bussey, G.R.; Minnear, L.H.

    1960-09-01

    Electrical apparatus is described, particularly useful in telemetry work, for converting analog signals into electrical pulses and recording them. An electronic editor commands the taking of signal readings at a frequency which varies according to linearity of the analog signal being converted. Readings of information signals are recorded, along with time base readings and serial numbering, if desired, on magnetic tape and the latter may be used to operate a computer or the like. Magnetic tape data may be transferred to punched cards.

  19. Mitigation of EMI in a flyback converter

    OpenAIRE

    2013-01-01

    M.Ing. (Electrical & Electronic Engineering Science) This study investigates the mitigation of conducted electromagnetic interference (EMI) in a flyback DC-DC converter. Without the use of filters, the maximum mitigation of EMI possible without significantly decreasing converter operating efficiency is investigated. The following parameters are found to influence EMI: · Switching speed: Decreasing switching speed (increasing rise and fall times of the MOSFET) effectively reduces both commo...

  20. TOTAL HARMONIC DISTORTION ANALYSIS OF MATRIX CONVERTER

    OpenAIRE

    K. Kandan; Senthilkumar,K.; Dhivya, K.

    2016-01-01

    This paper deals with the validation and design analysis of Matrix converter for variable frequency using mathematical equations. The analysis was done using Venturini modulation algorithm. The PI controller is used for Matrix converter to reduce Total Harmonic Distortion (THD) in the output current. The comparative study is done for open loop and closed loop PI compensation in MATLAB-Simulink. Furthermore, the output waveforms are produced with significant reduction in the Total Harmonic Dis...

  1. Core-shell Au-Pd nanoparticles as cathode catalysts for microbial fuel cell applications

    OpenAIRE

    Gaixiu Yang; Dong Chen; Pengmei Lv; Xiaoying Kong,; Yongming Sun; Zhongming Wang; Zhenhong Yuan; Hui Liu; Jun Yang

    2016-01-01

    Bimetallic nanoparticles with core-shell structures usually display enhanced catalytic properties due to the lattice strain created between the core and shell regions. In this study, we demonstrate the application of bimetallic Au-Pd nanoparticles with an Au core and a thin Pd shell as cathode catalysts in microbial fuel cells, which represent a promising technology for wastewater treatment, while directly generating electrical energy. In specific, in comparison with the hollow structured Pt ...

  2. Electrochemical promotion of catalytic reactions

    Science.gov (United States)

    Imbihl, R.

    2010-05-01

    The electrochemical promotion of heterogeneously catalyzed reactions (EPOC) became feasible through the use of porous metal electrodes interfaced to a solid electrolyte. With the O 2- conducting yttrium stabilized zirconia (YSZ), the Na + conducting β″-Al 2O 3 (β-alumina), and several other types of solid electrolytes the EPOC effect has been demonstrated for about 100 reaction systems in studies conducted mainly in the mbar range. Surface science investigations showed that the physical basis for the EPOC effect lies in the electrochemically induced spillover of oxygen and alkali metal, respectively, onto the surface of the metal electrodes. For the catalytic promotion effect general concepts and mechanistic schemes were proposed but these concepts and schemes are largely speculative. Applying surface analytical tools to EPOC systems the proposed mechanistic schemes can be verified or invalidated. This report summarizes the progress which has been achieved in the mechanistic understanding of the EPOC effect.

  3. Selective catalytic oxidation of ammonia

    Energy Technology Data Exchange (ETDEWEB)

    Leppaelahti, J.; Koljonen, T. [VTT Energy, Espoo (Finland)

    1996-12-31

    In the combustion of fossil fuels, the principal source of nitrogen oxides is nitrogen bound in the fuel structure. In gasification, a large part of fuel nitrogen forms NH{sub 3}, which may form nitrogen oxides during gas combustion. If NH{sub 3} and other nitrogen species could be removed from hot gas, the NO emission could be considerably reduced. However, relatively little attention has been paid to finding new means of removing nitrogen compounds from the hot gasification gas. The possibility of selectively oxidizing NH{sub 3} to N{sub 2} in the hot gasification has been studied at VTT Energy. The largest NH{sub 3} reductions have been achieved by catalytic oxidation on aluminium oxides. (author) (4 refs.)

  4. APPARATUS FOR CATALYTICALLY COMBINING GASES

    Science.gov (United States)

    Busey, H.M.

    1958-08-12

    A convection type recombiner is described for catalytically recombining hydrogen and oxygen which have been radiolytically decomposed in an aqueous homogeneous nuclear reactor. The device is so designed that the energy of recombination is used to circulate the gas mixture over the catalyst. The device consists of a vertical cylinder having baffles at its lower enda above these coarse screens having platinum and alumina pellets cemented thereon, and an annular passage for the return of recombined, condensed water to the reactor moderator system. This devicea having no moving parts, provides a simple and efficient means of removing the danger of accumulated hot radioactive, explosive gases, and restoring them to the moderator system for reuse.

  5. Fluctuations in catalytic surface reactions

    CERN Document Server

    Imbihl, R

    2003-01-01

    The internal reaction-induced fluctuations which occur in catalytic CO oxidation on a Pt field emitter tip have been studied using field electron microscopy (FEM) as a spatially resolving method. The structurally heterogeneous Pt tip consists of facets of different orientations with nanoscale dimensions. The FEM resolution of roughly 2 nm corresponds to a few hundred reacting adsorbed particles whose variations in the density are imaged as brightness fluctuations. In the bistable range of the reaction one finds fluctuation-induced transitions between the two stable branches of the reaction kinetics. The fluctuations exhibit a behaviour similar to that of an equilibrium phase transition, i.e. the amplitude diverges upon approaching the bifurcation point terminating the bistable range of the reaction. Simulations with a hybrid Monte Carlo/mean-field model reproduce the experimental observations. Fluctuations on different facets are typically uncorrelated but within a single facet a high degree of spatial cohere...

  6. LHC Power Converters: A Precision Game

    CERN Multimedia

    2001-01-01

    The LHC test-bed, String 2, is close to commissioning and one important element to get a first chance to prove what it can do is the power converter system. In String 2 there are 16 converters, in the full LHC there will be almost 1800. This article takes a look at what is so special about the power converters for the LHC. The 13 000 Amps power converters with the watercooled cables going to the String 2 feedboxes. The LHC's superconducting magnets will be the pinnacle of high technology. But to work, they'll need the help of high-precision power converters to supply them with extremely stable DC current. Perfection will be the name of the game, with an accuracy of just 1-2 parts per million (ppm) required. LEP, for the sake of comparison, could live with 10-20 ppm. The LHC's power converters will be very different from those of LEP or the SPS since the new accelerator's magnets are mostly superconducting. That means that they require much higher currents at a lower voltage since superconductors have no re...

  7. Adaptive electrothermal protection of power converters

    Directory of Open Access Journals (Sweden)

    Baraniuk G. A.

    2017-06-01

    Full Text Available Thermal management for power converters during normal operation and transient modes when electrical components are warmed up is an actual problem. This can be particularly important for converters with intermittent duty operation, e.g. power supplies for resistance welding. According to some research, nearly 60% of failures are temperature-induced, and for every 10°C temperature rise in operating environment the failure rate nearly doubles. In this paper, thermal motion of state equations eigenvalue is analysed. It is shown, that in semiconductor converters with an output smoothing filter it is appropriate to use thermal protection devices based on thermal normalisation of the converter filter and, while for cases when short circuits are possible it is appropriate to use a soft start system with thermal adaptation for soft start time factor. Based on these results, two systems of thermal protections operating for semiconductor power converters are introduced. Simulation of combined electromagnetic and thermal processes in buck converter operating with both thermal management systems in overlapping environments MATLAB/Simulink and PLECS showed the possibility to significantly reduce thermal shock on semiconductor components. Using the system of filter parameters normalisation decreases the temperature of the crystal from 210°C to 85°C, using the adaptive soft start system decreases the temperature from 180°C to 80°C. The simulation results are confirmed by tests on real devices.

  8. Method of fabricating a catalytic structure

    Science.gov (United States)

    Rollins, Harry W [Idaho Falls, ID; Petkovic, Lucia M [Idaho Falls, ID; Ginosar, Daniel M [Idaho Falls, ID

    2009-09-22

    A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

  9. Converting lignin to aromatics: step by step

    NARCIS (Netherlands)

    Strassberger, Z.I.

    2014-01-01

    Lignin, the glue that holds trees together, is the most abundant natural resource of aromatics. In that respect, it is a far more advanced resource than crude oil. This is because lignin already contains the aromatic functional groups. Thus, catalytic conversion of lignin to high-value aromatics is

  10. Directly converting CO2 into a gasoline fuel

    Science.gov (United States)

    Wei, Jian; Ge, Qingjie; Yao, Ruwei; Wen, Zhiyong; Fang, Chuanyan; Guo, Lisheng; Xu, Hengyong; Sun, Jian

    2017-05-01

    The direct production of liquid fuels from CO2 hydrogenation has attracted enormous interest for its significant roles in mitigating CO2 emissions and reducing dependence on petrochemicals. Here we report a highly efficient, stable and multifunctional Na-Fe3O4/HZSM-5 catalyst, which can directly convert CO2 to gasoline-range (C5-C11) hydrocarbons with selectivity up to 78% of all hydrocarbons while only 4% methane at a CO2 conversion of 22% under industrial relevant conditions. It is achieved by a multifunctional catalyst providing three types of active sites (Fe3O4, Fe5C2 and acid sites), which cooperatively catalyse a tandem reaction. More significantly, the appropriate proximity of three types of active sites plays a crucial role in the successive and synergetic catalytic conversion of CO2 to gasoline. The multifunctional catalyst, exhibiting a remarkable stability for 1,000 h on stream, definitely has the potential to be a promising industrial catalyst for CO2 utilization to liquid fuels.

  11. Consumable core for manufacture of composite articles and related method

    Science.gov (United States)

    Taxacher, Glenn Curtis; de Diego, Peter; Gray, Paul Edward; Monaghan, Philip Harold

    2017-09-05

    Systems, methods and devices adapted to ease manufacture of composite articles (e.g., ceramic composite articles), particularly composite articles which include a hollow feature are disclosed. In one embodiment, a system includes: a consumable core formed to be disposed within an inner portion of a composite precursor, the consumable core adapted to convert into an infiltrant during a manufacturing process and infiltrate the composite precursor.

  12. k -core covers and the core

    NARCIS (Netherlands)

    Sanchez-Rodriguez, E.; Borm, P.; Estevez Fernandez, M.A.; Fiestras-Janeiro, M.G.; Mosquera, M.A.

    2015-01-01

    This paper extends the notion of individual minimal rights for a transferable utility game (TU-game) to coalitional minimal rights using minimal balanced families of a specific type, thus defining a corresponding minimal rights game. It is shown that the core of a TU-game coincides with the core of

  13. k-core covers and the core

    NARCIS (Netherlands)

    Sanchez-Rodriguez, E.; Borm, Peter; Estevez-Fernandez, A.; Fiestras-Janeiro, G.; Mosquera, M.A.

    This paper extends the notion of individual minimal rights for a transferable utility game (TU-game) to coalitional minimal rights using minimal balanced families of a specific type, thus defining a corresponding minimal rights game. It is shown that the core of a TU-game coincides with the core of

  14. Performance of new generation TWC catalytic systems working under different conditions in order to reduce the emission of a global warming gas: N{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Mac-Beath, I.; Castillo, S.; Camposeco, R.; Moran-Pineda, M. [Instituto Mexicano del Petroleo, Mexico, D.F. (Mexico). Programa de Ingenieria Molecular

    2010-07-01

    In this work, three-way catalytic systems (TWC-K, TWC-M and TWC-P) were prepared and tested experimentally in order to analyze N{sub 2}O emissions. Various types and quantities of precious metals (Pt-Pd-Rh), and different mixed oxides (CexBayLazMgwO{sub 2}-Al{sub 2}O{sub 3}) to prepare the supports were used. The catalytic tests were carried out by using common exhaust gases from a gasoline engine under different oxidizing conditions. The TWC catalytic compositions were based on catalytic converters used in retrofitting programs in the Metropolitan Area in Mexico City. Fresh and aged TWC catalytic samples were tested; in both conditions, the catalytic compositions were characterized by BET, TEM-EDS and XRD in order to analyze the efficiency of the catalytic behavior. Due to the fact that the 4{sup th} TWC generation (Pd-Only TWC) has Pd as main active metal, the tested TWC catalytic samples were synthesized by having Pd in a higher proportion with regard to Pt and Rh used as complements with some differences in support composition. (orig.)

  15. Isolated and soft-switched power converter

    Science.gov (United States)

    Peng, Fang Zheng; Adams, Donald Joe

    2002-01-01

    An isolated and soft-switched power converter is used for DC/DC and DC/DC/AC power conversion. The power converter includes two resonant tank circuits coupled back-to-back through an isolation transformer. Each resonant tank circuit includes a pair of resonant capacitors connected in series as a resonant leg, a pair of tank capacitors connected in series as a tank leg, and a pair of switching devices with anti-parallel clamping diodes coupled in series as resonant switches and clamping devices for the resonant leg. The power converter is well suited for DC/DC and DC/DC/AC power conversion applications in which high-voltage isolation, DC to DC voltage boost, bidirectional power flow, and a minimal number of conventional switching components are important design objectives. For example, the power converter is especially well suited to electric vehicle applications and load-side electric generation and storage systems, and other applications in which these objectives are important. The power converter may be used for many different applications, including electric vehicles, hybrid combustion/electric vehicles, fuel-cell powered vehicles with low-voltage starting, remote power sources utilizing low-voltage DC power sources, such as photovoltaics and others, electric power backup systems, and load-side electric storage and generation systems.

  16. Understanding delta-sigma data converters

    CERN Document Server

    Pavan, Shanti; Temes, Gabor C

    2017-01-01

    This new edition introduces novel analysis and design techniques for delta-sigma (ΔΣ) converters in physical and conceptual terms, and includes new chapters that explore developments in the field over the last decade. This book explains the principles and operation of delta-sigma analog-to-digital converters (ADCs) in physical and conceptual terms in accordance with the most recent developments in the field. The interest of ΔΣ converter designers has shifted significantly over the past decade, due to many new applications for data converters at the far ends of the frequency spectrum. Continuous-time delta-sigma A/D converters with GHz clocks, of both lowpass and bandpass types, are required for wireless applications. At the other extreme, multiplexed ADCs with very narrow (sometimes 10 Hz wide) signal bandwidths, but very high accuracy are needed in the interfaces of biomedical and environmental sensors. To reflect the changing eeds of designers, the second edition includes significant new material on bo...

  17. A resonant dc-dc power converter assembly

    DEFF Research Database (Denmark)

    2015-01-01

    The present invention relates to a resonant DC-DC power converter assembly comprising a first resonant DC-DC power converter and a second resonant DC-DC power converter having identical circuit topologies. A first inductor of the first resonant DC-DC power converter and a second inductor of the s......The present invention relates to a resonant DC-DC power converter assembly comprising a first resonant DC-DC power converter and a second resonant DC-DC power converter having identical circuit topologies. A first inductor of the first resonant DC-DC power converter and a second inductor...

  18. Catalytic processing of high-sulfur fuels for distributed hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Muradov, Nazim; Ramasamy, Karthik; Huang, Cunping; T-Raissi, Ali [Central Florida Univ., FL (United States)

    2010-07-01

    In this work, the development of a new on-demand hydrogen production technology is reported. In this process, a liquid hydrocarbon fuel (e.g., high-S diesel) is first catalytically pre-reformed to shorter chain gaseous hydrocarbons (predominantly, C{sub 1}-C{sub 3}) before being directed to the steam reformer, where it is converted to syngas and then to high-purity hydrogen. In the pre-reformer, most sulfurous species present in the fuel are catalytically converted to H{sub 2}S. In the desulfurization unit, H{sub 2}S is scrubbed and converted to H{sub 2} and elemental sulfur. Desulfurization of the pre-reformate gas is carried out in a special regenerative redox system, which includes Fe(II)/Fe(III)-containing aqueous phase scrubber coupled with an electrolyzer. The integrated pre-reformer/scrubber/electrolyzer unit operated successfully on high-S diesel fuel for more than 100 hours meeting the required desulfurization target of >95 % sulfur removal. (orig.)

  19. An optimized analog to digital converter for WLAN analog front end

    Science.gov (United States)

    Mao, Ye; Yumei, Zhou; Bin, Wu; Jianhua, Jiang

    2012-04-01

    A 10 bit 80 MSPS analog to digital converter optimized for WLAN analog front end is presented. In contrast to conventional 1.5 bit pipeline architecture, four optimized multi-bit multiply digital to analog converter stages are implemented. An on-chip low-noise reference buffer is proposed for SoC integration purposes, and a wide-bandwidth wide swing sample and hold amplifier is also presented for achieving a good dynamic range. The converter was fabricated in 0.18 μm 1P6M CMOS technology, and the core area occupies approximately 0.85 mm2. Measured results show that with an 11 MHz input signal, it provides a 9.4 bit effective number of bits and a 72 dBc spurious frequency dynamic range when sampled at 80 MHz.

  20. Discrete Displacement Hydraulic Power Take-Off System for the Wavestar Wave Energy Converter

    DEFF Research Database (Denmark)

    Hansen, Rico Hjerm; Kramer, Morten; Vidal, Enrique

    2013-01-01

    The Wavestar Wave Energy Converter (WEC) is a multiple absorber concept, consisting of 20 hemisphere shaped floats attached to a single platform. The heart of the Wavestar WEC is the Power Take-Off (PTO) system, converting the wave induced motion of the floats into a steady power output to the grid...... is converted into electricity at a steady pace by hydraulic motors and generators. The storage, thereby, decouples the complicated process of wave power absorption from power generation. The core for enabling this PTO technology is implementing a near loss-free force control of the energy absorbing cylinders....... In the present work, a PTO based on a novel discrete displacement fluid power technology is explored for the Wavestar WEC. Absorption of power from the floats is performed by hydraulic cylinders, supplying power to a common fixed pressure system with accumulators for energy smoothing. The stored pressure energy...

  1. TRANC – a novel fast-response converter to measure total reactive atmospheric nitrogen

    Directory of Open Access Journals (Sweden)

    V. Wolff

    2012-05-01

    Full Text Available The input and loss of plant available nitrogen (reactive nitrogen: Nr from/to the atmosphere can be an important factor for the productivity of ecosystems and thus for its carbon and greenhouse gas exchange. We present a novel converter for reactive nitrogen (TRANC: Total Reactive Atmospheric Nitrogen Converter, which offers the opportunity to quantify the sum of all airborne reactive nitrogen compounds (∑Nr in high time resolution. The basic concept of the TRANC is the full conversion of all Nr to nitrogen monoxide (NO within two reaction steps. Initially, reduced Nr compounds are being oxidised, and oxidised Nr compounds are thermally converted to lower oxidation states. Particulate Nr is being sublimated and oxidised or reduced afterwards. In a second step, remaining higher nitrogen oxides or those generated in the first step are catalytically converted to NO with carbon monoxide used as reduction gas. The converter is combined with a fast response chemiluminescence detector (CLD for NO analysis and its performance was tested for the most relevant gaseous and particulate Nr species under both laboratory and field conditions. Recovery rates during laboratory tests for NH3 and NO2 were found to be 95 and 99%, respectively, and 97% when the two gases were combined. In-field longterm stability over an 11-month period was approved by a value of 91% for NO2. Effective conversion was also found for ammonium and nitrate containing particles. The recovery rate of total ambient Nr was tested against the sum of individual measurements of NH3, HNO3, HONO, NH4+, NO3−, and NOx using a combination of different well-established devices. The results show that the TRANC-CLD system precisely captures fluctuations in ∑Nr concentrations and also matches the sum of all individual Nr compounds measured by the different single techniques. The TRANC features a specific design with very short distance between the sample air inlet and the place where the thermal

  2. New Geometry Integrated Inductors in Two-channel Interleaved Bidirectional Converter

    DEFF Research Database (Denmark)

    Ouyang, Ziwei; Thomsen, Ole Cornelius; Andersen, Michael A. E.

    2010-01-01

    inductors. The air gaps are constructed by separating the I-cores using copper foil windings with well-defined thickness. In this work, inverse connection and direct connection for the two integrated inductors have been analyzed. For the inverse connection, a unique saturation behavior in the middle I......-core has been shown. The integrated inductors with new geometry make it possible to build low-profile, low-cost, flexibility DC/DC converters, and it can be extensively designed for low-voltage and high-current required by modern digital applications. Experiment results obtained from a 48V-12V 30A two......-phase interleaved buck converter, demonstrates the difference in the inverse connection and the direct connection. Both efficiencies are above 91% from half to full output current....

  3. Converters for Distributed Power Generation Systems

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Yang, Yongheng

    2015-01-01

    Power electronics technology has become the enabling technology for the integration of distributed power generation systems (DPGS) such as offshore wind turbine power systems and commercial photovoltaic power plants. Depending on the applications, a vast array of DPGS-based power converter...... presents an overview of the power converters for the DPGS, mainly based on wind turbine systems and photovoltaic systems, covering a wide range of applications. Moreover, the modulation schemes and interfacing power filters for the power converters are also exemplified. Finally, the general control...... topologies has been developed and more are coming into the market in order to achieve an efficient and reliable power conversion from the renewables. In addition, stringent demands from both the distribution system operators and the consumers have been imposed on the renewable-based DPGS. This article...

  4. Data Converter for Multistandard Mobile Phones

    DEFF Research Database (Denmark)

    Yurttas, Aziz; Bruun, Erik; Jensen, Rasmus Glarborg

    2004-01-01

    This paper describes an analog to digital converter (ADC) for mobile communication systems using a direct down conversion architecture. The ADC can be programmed to meet the requirements of different communication standards, including GSM (Global System for Mobile communication) and WCDMA (Wideband...... Code Division Multiple Access). The ADC is realized with a pipeline ADC architecture for WCDMA and a Sigma-Delta architecture for GSM. In order to have an optimized area and power consumption, the basic building blocks (opamps) of the converters are shared between the two converter architectures....... The entire ADC consumes about 5.5 mW and occupies an active area of about 0.36 mm(2). A test circuit has been developed and fabricated and measurements show that both the required programmability and the required performance can be obtained using the proposed configurations....

  5. Self-oscillating resonant power converter

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to resonant power converters and inverters comprising a self-oscillating feedback loop coupled from a switch output to a control input of a switching network comprising one or more semiconductor switches. The self-oscillating feedback loop sets a switching frequency...... of the power converter and comprises a first intrinsic switch capacitance coupled between a switch output and a control input of the switching network and a first inductor. The first inductor is coupled in-between a first bias voltage source and the control input of the switching network and has...... a substantially fixed inductance. The first bias voltage source is configured to generate an adjustable bias voltage applied to the first inductor. The output voltage of the power converter is controlled in a flexible and rapid manner by controlling the adjustable bias voltage....

  6. Metamaterial polarization converter analysis: limits of performance

    DEFF Research Database (Denmark)

    Markovich, Dmitry L.; Andryieuski, Andrei; Zalkovskij, Maksim

    2013-01-01

    In this paper, we analyze the theoretical limits of a metamaterial-based converter with orthogonal linear eigenpolarizations that allow linear-to-elliptical polarization transformation with any desired ellipticity and ellipse orientation. We employ the transmission line approach providing a needed...... level of the design generalization. Our analysis reveals that the maximal conversion efficiency for transmission through a single metamaterial layer is 50 %, while the realistic reflection configuration can give the conversion efficiency up to 90 %. We show that a double layer transmission converter...... and a single layer with a ground plane can have 100 % polarization conversion efficiency. We tested our conclusions numerically reaching the designated limits of efficiency using a simple metamaterial design. Our general analysis provides useful guidelines for the metamaterial polarization converter design...

  7. Reliability of Power Electronic Converter Systems

    DEFF Research Database (Denmark)

    for advancing the reliability, availability, system robustness, and maintainability of PECS at different levels of complexity. Drawing on the experience of an international team of experts, this book explores the reliability of PECS covering topics including an introduction to reliability engineering in power...... electronic converter systems; anomaly detection and remaining-life prediction for power electronics; reliability of DC-link capacitors in power electronic converters; reliability of power electronics packaging; modeling for life-time prediction of power semiconductor modules; minimization of DC......-link capacitance in power electronic converter systems; wind turbine systems; smart control strategies for improved reliability of power electronics system; lifetime modelling; power module lifetime test and state monitoring; tools for performance and reliability analysis of power electronics systems; fault...

  8. High Efficiency Reversible Fuel Cell Power Converter

    DEFF Research Database (Denmark)

    Pittini, Riccardo

    The large scale integration of renewable energy sources requires suitable energy storage systems to balance energy production and demand in the electrical grid. Bidirectional fuel cells are an attractive technology for energy storage systems due to the high energy density of fuel. Compared...... to traditional unidirectional fuel cell, bidirectional fuel cells have increased operating voltage and current ranges. These characteristics increase the stresses on dc-dc and dc-ac converters in the electrical system, which require proper design and advanced optimization. This work is part of the PhD project...... entitled "High Efficiency Reversible Fuel Cell Power Converter" and it presents the design of a high efficiency dc-dc converter developed and optimized for bidirectional fuel cell applications. First, a brief overview of fuel cell and energy storage technologies is presented. Different system topologies...

  9. Reliability of Power Electronic Converter Systems

    DEFF Research Database (Denmark)

    -link capacitance in power electronic converter systems; wind turbine systems; smart control strategies for improved reliability of power electronics system; lifetime modelling; power module lifetime test and state monitoring; tools for performance and reliability analysis of power electronics systems; fault......The main aims of power electronic converter systems (PECS) are to control, convert, and condition electrical power flow from one form to another through the use of solid-state electronics. This book outlines current research into the scientific modeling, experimentation, and remedial measures...... for advancing the reliability, availability, system robustness, and maintainability of PECS at different levels of complexity. Drawing on the experience of an international team of experts, this book explores the reliability of PECS covering topics including an introduction to reliability engineering in power...

  10. Parametric pendulum based wave energy converter

    Science.gov (United States)

    Yurchenko, Daniil; Alevras, Panagiotis

    2018-01-01

    The paper investigates the dynamics of a novel wave energy converter based on the parametrically excited pendulum. The herein developed concept of the parametric pendulum allows reducing the influence of the gravity force thereby significantly improving the device performance at a regular sea state, which could not be achieved in the earlier proposed original point-absorber design. The suggested design of a wave energy converter achieves a dominant rotational motion without any additional mechanisms, like a gearbox, or any active control involvement. Presented numerical results of deterministic and stochastic modeling clearly reflect the advantage of the proposed design. A set of experimental results confirms the numerical findings and validates the new design of a parametric pendulum based wave energy converter. Power harvesting potential of the novel device is also presented.

  11. Reliability of Power Electronic Converter Systems

    DEFF Research Database (Denmark)

    The main aims of power electronic converter systems (PECS) are to control, convert, and condition electrical power flow from one form to another through the use of solid-state electronics. This book outlines current research into the scientific modeling, experimentation, and remedial measures...... for advancing the reliability, availability, system robustness, and maintainability of PECS at different levels of complexity. Drawing on the experience of an international team of experts, this book explores the reliability of PECS covering topics including an introduction to reliability engineering in power......-link capacitance in power electronic converter systems; wind turbine systems; smart control strategies for improved reliability of power electronics system; lifetime modelling; power module lifetime test and state monitoring; tools for performance and reliability analysis of power electronics systems; fault...

  12. Magnetically recyclable reduced graphene oxide nanosheets/magnetite-palladium aerogel with superior catalytic activity and reusability.

    Science.gov (United States)

    Feng, Yan; Zhang, Hui; Xin, Baifu; Wu, Jie

    2017-11-15

    A two-step method was employed to synthesize reduced graphene oxide nanosheets/magnetite-palladium (rGSs/Fe3O4-Pd) aerogel, with excellent catalytic activity and recyclability. Firstly, graphene oxide nanosheet (GS) hydrogels were formed by the self-assembly of GSs during the hydrothermal process. Meanwhile, hematite (α-Fe2O3) and Pd nanoparticles (NPs) were synthesized and anchored onto the surface of the hydrogel. During heat-treatment, GSs were reduced to rGSs, while nonmagnetic α-Fe2O3NPs were converted to magnetic Fe3O4 NPs. The as-obtained rGSs/Fe3O4-Pd aerogel displayed a three-dimensional interconnected hierarchical porous architecture, which was rich in mesopores and macropores. Such a structure was suitable for catalysis, since it not only improved the mass diffusion and transport, but also readily exposed the catalytic Pd NPs to the reactants. The typical reduction of 4-nitrophenol was chosen as a model reaction to evaluate the catalytic performance of the aerogel. As anticipated, both the reaction rate constant and turn over frequency of the aerogel were much higher than those of the commercial Pd/C catalyst. Moreover, due to incorporation of Fe3O4 NPs, the rGSs/Fe3O4-Pd aerogel could be magnetically separated from the reaction solution and reused, without obvious loss of catalytic activity. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. Biogasoline Production from Palm Oil Via Catalytic Hydrocracking over Gamma-Alumina Catalyst

    Directory of Open Access Journals (Sweden)

    Anondho Wijanarko

    2010-10-01

    Full Text Available Bio gasoline conversion from palm oil is an alternative energy resources method which can be substituted fossil fuel base energy utilization. Previous research resulted that palm oil can be converted into hydrocarbon by catalytic cracking reaction with γ-alumina catalyst. In this research, catalytic cracking reaction of palm oil by γ-alumina catalyst is done in  a stirrer batch reactor with the oil/catalyst weight ratio variation of 100:1, 75:1, and 50:1; at suhue variation of 260 to 340oC and reaction time variation of 1 to 2 hour. Post cracking reaction, bio gasoline yield could be obtained after 2 steps batch distillation. Physical property test result such as density and viscosity of this cracking reaction product and commercial gasoline tended a closed similarity. According to result of the cracking product's density, viscosity and FTIR, it  can conclude that optimum yield of the palm oil catalytic cracking reaction could be occurred when oil/catalyst weight  ratio 100:1 at 340 oC in 1.5 hour and base on this bio gasoline's FTIR, GC and GC-MS identification results, its  hydrocarbons content was resembled to the commercial  gasoline. This palm oil catalytic cracking reaction shown 11.8% (v/v in yield and 28.0% (v/v in conversion concern to feed palm oil base and produced a 61.0 octane number's biogasoline.

  14. Catalytic properties of Caucasian zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Kostandyan, M.N.; Babayan, S.G.; Musaev, M.R.; Mirzoeva, K.G.

    1985-09-01

    Great deposits of natural zeolites have been discovered in the Caucasus which can be used in various fields of the economy. One promising direction of using them may be the field of petrochemistry. The results of research on the conversion of 1-hexanol in natural zeolites in the Caucasus have been reported previously. This work was carried out in order to obtain comparative data on the catalytic activity of zeolites from the following deposits: Novyy Kokhb in Armenia, Ay-Dag in Azerbaijan, and Khekordzula in Georgia. This established that without any preliminary chemical treatment these zeolites are good catalysts for the dehydration of primary hexyl alcohol and the isomerization of the l-hexene obtained into 2-hexene. The activity of all three catalysts is almost identical. Continuing the research in this direction, the conversion of cyclohexanol in the same natural zeolites has been studied. The conditions for carrying out the experiments and methodology of obtaining the reaction products are presented. The data obtained show that the degree of dehydration of cyclohexanol at low temperatures (250-350/sup 0/C) is significantly greater than the degree of dehydration of 1-hexanol. The dehydration is accompanied by skeletal isomerization into 1- and 3-methylcyclopentenes (a total of 3%). At high temperatures (400-450/sup 0/), along with an increased degree of isomerization of cyclohexene into methocyclopentenes, the formation of methylcyclopentane is observed as a result of the redistribution of hydrogen and coke on the catalysts. 1 reference.

  15. Impedance coordinative control for cascaded converter in bidirectional application

    DEFF Research Database (Denmark)

    Tian, Yanjun; Loh, Poh Chiang; Deng, Fujin

    2016-01-01

    A two-stage cascaded converter is formed by connecting two sub-converters in series. Output impedance of one sub-converter will therefore interact with input impedance of the other sub-converter. Such interaction may affect the system dynamics and stability, especially when one sub-converter is c......A two-stage cascaded converter is formed by connecting two sub-converters in series. Output impedance of one sub-converter will therefore interact with input impedance of the other sub-converter. Such interaction may affect the system dynamics and stability, especially when one sub......-converter is constant-power-controlled, and hence has different impedance characteristics when its power reverses. To lessen such constant-power effects, a control scheme that can coordinate impedance behaviors of the two sub-converters is proposed. The idea is to reshape the lowfrequency negative impedance...

  16. Hydrodynamic Performance of a Wave Energy Converter

    Science.gov (United States)

    Yang, Yingchen

    2010-11-01

    To harvest energy from ocean waves, a new wave energy converter (WEC) was proposed and tested in a wave tank. The WEC freely floats on the water surface and rides waves. It utilizes its wave-driven angular oscillation to convert the mechanical energy of waves into electricity. To gain the maximum possible angular oscillation of the WEC under specified wave conditions, both floatation of the WEC and wave interaction with the WEC play critical roles in a joint fashion. During the experiments, the submersion condition of the WEC and wave condition were varied. The results were analyzed in terms of the oscillation amplitude, stability, auto-orientation capability, and wave frequency dependency.

  17. The Angiotensin-Converting-Enzyme-Induced Angioedema.

    Science.gov (United States)

    Bas, Murat

    2017-02-01

    The bradykinin B2 receptor antagonist icatibant is effective in angiotensin-converting enzyme inhibitor-induced angioedema. The drug is not approved officially for this indication and has to be administered in an emergency situation off-label. Corticosteroids or antihistamines do not seem to work in this condition. The effectiveness of C1-esterase-inhibitor in angiotensin-converting enzyme-induced angioedema must be verified in a double-blind study. Copyright © 2016 Elsevier Inc. All rights reserved.

  18. Generalized modular multilevel converter and modulation

    DEFF Research Database (Denmark)

    Liu, Hui; Loh, Poh Chiang; Blaabjerg, Frede

    2014-01-01

    Modular multilevel converter (MMC) has gained popularity recently with its modulation, capacitor voltage balancing and circulating current issues widely discussed. Contributing to this effort, a study is presented here to show how the MMC topology can be derived from the viewpoint of two series...... converters regulating a power grid. The generalized topology derived and notated as GMMC can then be altered to create various types of MMC, including the traditional topology that is presently well-known. This effort has not been previously discussed, and may smoothen the understanding of MMC operation...

  19. Soft switched DC-DC converter

    Science.gov (United States)

    Subramanian, K.; Kavitha, K. V. N.; Saravanan, K.

    2017-11-01

    A soft switched single switch isolated dc-dc conveys proposed in this paper. This converter works on the principle of zero current switching (zcs) and zero voltage switching (zvs). The circuit comprises lossless snubber with low rating. The switch works on zcs during turn on and zvs during turnoff. The diodes are based on zcs turn on and turnoff conditions. This paper presents the concept of soft switching and its applications to dc-dc converter. The losses due to soft switching and hard switching are compared.

  20. Combination solar photovoltaic heat engine energy converter

    Science.gov (United States)

    Chubb, Donald L.

    1987-01-01

    A combination solar photovoltaic heat engine converter is proposed. Such a system is suitable for either terrestrial or space power applications. The combination system has a higher efficiency than either the photovoltaic array or the heat engine alone can attain. Advantages in concentrator and radiator area and receiver mass of the photovoltaic heat engine system over a heat-engine-only system are estimated. A mass and area comparison between the proposed space station organic Rankine power system and a combination PV-heat engine system is made. The critical problem for the proposed converter is the necessity for high temperature photovoltaic array operation. Estimates of the required photovoltaic temperature are presented.

  1. A quadratic analog-to-digital converter

    Science.gov (United States)

    Harrison, D. C.; Staples, M. H.

    1980-01-01

    An analog-to-digital converter with a square root transfer function has been developed for use with a pair of CCD imaging detectors in the White Light Coronagraph/X-ray XUV Telescope experiment to be flown as part of the Internal Solar Polar Mission. It is shown that in background-noise-limited instrumentation systems a quadratic analog-to-digital converter will allow a maximum dynamic range with a fixed number of data bits. Low power dissipation, moderately fast conversion time, and reliability are achieved in the proposed design using standard components and avoiding nonlinear elements.

  2. Electrodes For Alkali-Metal Thermoelectric Converters

    Science.gov (United States)

    Williams, Roger M.; Wheeler, Bob L.; Jeffries-Nakamura, Barbara; Lamb, James L.; Bankston, C. Perry; Cole, Terry

    1989-01-01

    Combination of thin, porous electrode and overlying collector grid reduces internal resistance of alkali-metal thermoelectric converter cell. Low resistance of new electrode and grid boosts power density nearly to 1 W/cm2 of electrode area at typical operating temperatures of 1,000 to 1,300 K. Conductive grid encircles electrode film on alumina tube. Bus wire runs along tube to collect electrical current from grid. Such converters used to transform solar, nuclear, and waste heat into electric power.

  3. Converting ODM Metadata to FHIR Questionnaire Resources.

    Science.gov (United States)

    Doods, Justin; Neuhaus, Philipp; Dugas, Martin

    2016-01-01

    Interoperability between systems and data sharing between domains is becoming more and more important. The portal medical-data-models.org offers more than 5.300 UMLS annotated forms in CDISC ODM format in order to support interoperability, but several additional export formats are available. CDISC's ODM and HL7's framework FHIR Questionnaire resource were analyzed, a mapping between elements created and a converter implemented. The developed converter was integrated into the portal with FHIR Questionnaire XML or JSON download options. New FHIR applications can now use this large library of forms.

  4. IGBT Based DC/DC Converter

    Directory of Open Access Journals (Sweden)

    M. Akherraz

    1997-12-01

    Full Text Available This paper presents an in-depth analytical and experimental investigation of an indirect DC-DC converter. The DC-AC conversion is a full bridge based on IGBT power modules, and the AC-DC conversion is done via a high  frequency AC link and a first diode bridge. The AC link, which consists of snubbing capacitors and a variable air-gap transformer, is analytically designed to fulfill Zero Voltage commutation requirement. The proposed converter is simulated using PSPICE and a prototype is designed built and tested in the laboratory. PSPICE simulation and experimental results are presented and compared.

  5. Efficient modelling of a modular multilevel converter

    DEFF Research Database (Denmark)

    El-Khatib, Walid Ziad; Holbøll, Joachim; Rasmussen, Tonny Wederberg

    2013-01-01

    Looking at the near future, we see that offshore wind penetration into the electrical grid will continue increasing rapidly. Until very recently, the trend has been to place the offshore wind farms close to shore within the reach for transmission using HVAC cables but for larger distances HVDC...... are calculated for the converter. Time-domain simulations on a MMC HVDC test system are performed in the PSCAD/EMTDC software environment based on the new model. The results demonstrate that the modeled MMC-HVDC system with or without converter transformer is able to operate under specific fault conditions....

  6. Catalytic Upgrading of Thermochemical Intermediates to Hydrocarbons: Conversion of Lignocellulosic Feedstocks to Aromatic Fuels and High Value Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Cortright, Randy [Virent, Inc., Madison, WI (United States); Rozmiarek, Bob [Virent, Inc., Madison, WI (United States); Van Straten, Matt [Virent, Inc., Madison, WI (United States)

    2017-11-28

    The principal objective of this project was to develop a fully integrated catalytic process that efficiently converts lignocellulosic feedstocks (e.g. bagasse, corn stover, and loblolly pine) into aromatic-rich fuels and chemicals. Virent led this effort with key feedstock support from Iowa State University. Within this project, Virent leveraged knowledge of catalytic processing of sugars and biomass to investigate two liquefaction technologies (Reductive Catalytic Liquefaction (USA Patent No. 9,212,320, 2015) and Solvolysis (USA Patent No. 9,157,030, 2015) (USA Patent No. 9,157,031, 2015)) that take advantage of proprietary catalysts at temperatures less than 300°C in the presence of unique solvent molecules generated in-situ within the liquefaction processes.

  7. High Frequency AC Inductor Analysis and Design for Dual Active Bridge (DAB) Converters

    DEFF Research Database (Denmark)

    Zhang, Zhe; Andersen, Michael A. E.

    2016-01-01

    The dual active bridge (DAB) converter is an isolated bidirectional dc-dc topology which is the most critical part for the power conversion systems such as solid-state transformers (SST). This paper focuses on analysis and design of high frequency ac inductors which are the power interfacing...... the core loss and the winding loss are almost equal is selected as the optimal one. The experimental results are presented to verify the validity of the analysis and design....

  8. A thermogravimetric analysis (TGA) method to determine the catalytic conversion of cellulose from carbon-supported hydrogenolysis process

    Energy Technology Data Exchange (ETDEWEB)

    Leal, Glauco F. [Brazilian Synchrotron Light Laboratory (LNLS), Brazilian Center for Research in Energy and Materials (CNPEM), C.P. 6192, 13083-970 Campinas, SP (Brazil); Institute of Chemistry of São Carlos (IQSC), University of São Paulo (USP), C.P. 780, CEP 13560-970 São Carlos, SP (Brazil); Ramos, Luiz A. [Institute of Chemistry of São Carlos (IQSC), University of São Paulo (USP), C.P. 780, CEP 13560-970 São Carlos, SP (Brazil); Barrett, Dean H. [Brazilian Synchrotron Light Laboratory (LNLS), Brazilian Center for Research in Energy and Materials (CNPEM), C.P. 6192, 13083-970 Campinas, SP (Brazil); Curvelo, Antonio Aprígio S. [Institute of Chemistry of São Carlos (IQSC), University of São Paulo (USP), C.P. 780, CEP 13560-970 São Carlos, SP (Brazil); Brazilian Bioethanol Science and Technology Laboratory (CTBE), Brazilian Center for Research in Energy and Materials (CNPEM), C.P. 6179, 13083-970 Campinas, SP (Brazil); Rodella, Cristiane B., E-mail: cristiane.rodella@lnls.br [Brazilian Synchrotron Light Laboratory (LNLS), Brazilian Center for Research in Energy and Materials (CNPEM), C.P. 6192, 13083-970 Campinas, SP (Brazil)

    2015-09-20

    Graphical abstract: - Highlights: • A new method to determine the catalytic conversion of cellulose using TGA has been developed. • TGA is able to differentiate between carbon from cellulose and carbon from the catalyst. • Building an analytical curve from TGA results enables the accurate determination of cellulose conversion. - Abstract: The ability to determine the quantity of solid reactant that has been transformed after a catalytic reaction is fundamental in accurately defining the conversion of the catalyst. This quantity is also central when investigating the recyclability of a solid catalyst as well as process control in an industrial catalytic application. However, when using carbon-supported catalysts for the conversion of cellulose this value is difficult to obtain using only a gravimetric method. The difficulty lies in weighing errors caused by loss of the solid mixture (catalyst and non-converted cellulose) after the reaction and/or moisture adsorption by the substrate. These errors are then propagated into the conversion calculation giving erroneous results. Thus, a quantitative method using thermogravimetric analysis (TGA) has been developed to determine the quantity of cellulose after a catalytic reaction by using a tungsten carbide catalyst supported on activated carbon. Stepped separation of TGA curves was used for quantitative analysis where three thermal events were identified: moisture loss, cellulose decomposition and CO/CO{sub 2} formation. An analytical curve was derived and applied to quantify the residual cellulose after catalytic reactions which were performed at various temperatures and reaction times. The catalytic conversion was calculated and compared to the standard gravimetric method. Results showed that catalytic cellulose conversion can be determined using TGA and exhibits lower uncertainty (±2%) when compared to gravimetric determination (±5%). Therefore, it is a simple and relatively inexpensive method to determine

  9. Catalytic oxidation for treatment of ECLSS and PMMS waste streams. [Process Material Management Systems

    Science.gov (United States)

    Akse, James R.; Thompson, John; Scott, Bryan; Jolly, Clifford; Carter, Donald L.

    1992-01-01

    Catalytic oxidation was added to the baseline multifiltration technology for use on the Space Station Freedom in order to convert low-molecular weight organic waste components such as alcohols, aldehydes, ketones, amides, and thiocarbamides to CO2 at low temperature (121 C), thereby reducing the total organic carbon (TOC) to below 500 ppb. The rate of reaction for the catalytic oxidation of aqueous organics to CO2 and water depends primarily upon the catalyst, temperature, and concentration of reactants. This paper describes a kinetic study conducted to determine the impact of each of these parameters upon the reaction rate. The results indicate that a classic kinetic model, the Langmuir-Hinshelwood rate equation for heterogeneous catalysis, can accurately represent the functional dependencies of this rate.

  10. Low-temperature catalytic gasification of food processing wastes. 1995 topical report

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, D.C.; Hart, T.R.

    1996-08-01

    The catalytic gasification system described in this report has undergone continuing development and refining work at Pacific Northwest National Laboratory (PNNL) for over 16 years. The original experiments, performed for the Gas Research Institute, were aimed at developing kinetics information for steam gasification of biomass in the presence of catalysts. From the fundamental research evolved the concept of a pressurized, catalytic gasification system for converting wet biomass feedstocks to fuel gas. Extensive batch reactor testing and limited continuous stirred-tank reactor tests provided useful design information for evaluating the preliminary economics of the process. This report is a follow-on to previous interim reports which reviewed the results of the studies conducted with batch and continuous-feed reactor systems from 1989 to 1994, including much work with food processing wastes. The discussion here provides details of experiments on food processing waste feedstock materials, exclusively, that were conducted in batch and continuous- flow reactors.

  11. Entropy production of a steady-growth cell with catalytic reactions

    Science.gov (United States)

    Himeoka, Yusuke; Kaneko, Kunihiko

    2014-10-01

    Cells generally convert external nutrient resources to support metabolism and growth. Understanding the thermodynamic efficiency of this conversion is essential to determine the general characteristics of cellular growth. Using a simple protocell model with catalytic reaction dynamics to synthesize the necessary enzyme and membrane components from nutrients, the entropy production per unit-cell-volume growth is calculated analytically and numerically based on the rate equation for chemical kinetics and linear nonequilibrium thermodynamics. The minimal entropy production per unit-cell growth is found to be achieved at a nonzero nutrient uptake rate rather than at a quasistatic limit as in the standard Carnot engine. This difference appears because the equilibration mediated by the enzyme exists only within cells that grow through enzyme and membrane synthesis. Optimal nutrient uptake is also confirmed by protocell models with many chemical components synthesized through a catalytic reaction network. The possible relevance of the identified optimal uptake to optimal yield for cellular growth is also discussed.

  12. Production of algae-based biodiesel using the continuous catalytic Mcgyan process.

    Science.gov (United States)

    Krohn, Brian J; McNeff, Clayton V; Yan, Bingwen; Nowlan, Daniel

    2011-01-01

    This study demonstrates the production of algal biodiesel from Dunaliella tertiolecta, Nannochloropsis oculata, wild freshwater microalgae, and macroalgae lipids using a highly efficient continuous catalytic process. The heterogeneous catalytic process uses supercritical methanol and porous titania microspheres in a fixed bed reactor to catalyze the simultaneous transesterification and esterification of triacylglycerides and free fatty acids, respectively, to fatty acid methyl esters (biodiesel). Triacylglycerides and free fatty acids were converted to alkyl esters with up to 85% efficiency as measured by 300 MHz (1)H NMR spectroscopy. The lipid composition of the different algae was studied gravimetrically and by gas chromatography. The analysis showed that even though total lipids comprised upwards of 19% of algal dry weight the saponifiable lipids, and resulting biodiesel, comprised only 1% of dry weight. Thus highlighting the need to determine the triacylglyceride and free fatty acid content when considering microalgae for biodiesel production. Copyright © 2010 Elsevier Ltd. All rights reserved.

  13. Production of hydrogen for fuel cells by catalytic partial oxidation of ethanol over structured Ru catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Liguras, D.K.; Goundani, K.; Verykios, X.E. [University of Patras (Greece). Dept. of Chemical Engineering

    2004-03-01

    A series of Ru catalysts supported on cordierite monoliths, ceramic foams and {gamma}-Al{sub 2}O{sub 3} pellets were prepared and tested for the production of hydrogen by catalytic partial oxidation of ethanol. The catalyst supported on a cordierite monolith exhibited excellent catalytic performance for a wide variety of process conditions and excellent long-term stability with low coke formation. The effect of the steam to ethanol molar ratio on conversion and selectivities was relatively small. A more pronounced effect was observed for the oxygen to ethanol ratio. Overall, catalysts on all three supports were able to completely convert ethanol with high selectivities towards the desired products. The Ru supported on a ceramic foam catalyst provided comparatively better performance, probably due to the smaller pore sizes and higher tortuosity of this support. (author)

  14. Sub-nanometer dimensions control of core/shell nanoparticles prepared by atomic layer deposition.

    Science.gov (United States)

    Weber, M J; Verheijen, M A; Bol, A A; Kessels, W M M

    2015-03-06

    Bimetallic core/shell nanoparticles (NPs) are the subject of intense research due to their unique electronic, optical and catalytic properties. Accurate and independent control over the dimensions of both core and shell would allow for unprecedented catalytic performance. Here, we demonstrate that both core and shell dimensions of Pd/Pt core/shell nanoparticles (NPs) supported on Al2O3 substrates can be controlled at the sub-nanometer level by using a novel strategy based on atomic layer deposition (ALD). From the results it is derived that the main conditions for accurate dimension control of these core/shell NPs are: (i) a difference in surface energy between the deposited core metal and the substrate to obtain island growth; (ii) a process yielding linear growth of the NP cores with ALD cycles to obtain monodispersed NPs with a narrow size distribution; (iii) a selective ALD process for the shell metal yielding a linearly increasing thickness to obtain controllable shell growth exclusively on the cores. For Pd/Pt core/shell NPs it is found that a minimum core diameter of 1 nm exists above which the NP cores are able to catalytically dissociate the precursor molecules for shell growth. In addition, initial studies on the stability of these core/shell NPs have been carried out, and it has been demonstrated that core/shell NPs can be deposited by ALD on high aspect ratio substrates such as nanowire arrays. These achievements show therefore that ALD has significant potential for the preparation of tuneable heterogeneous catalyst systems.

  15. Introduction of Residue Fluid Catalytic Cracking Process

    National Research Council Canada - National Science Library

    SAKAKURA, Kei

    2014-01-01

    .... Fluid catalytic cracking (FCC) is one of the most important conversion processes in a petroleum refinery, it also occupies very significant position in the refinery due to its economic benefits...

  16. Catalytic models developed through social work

    DEFF Research Database (Denmark)

    Jensen, Mogens

    2015-01-01

    The article develops the concept of catalytic processes in relation to social work with adolescents in an attempt to both reach a more nuanced understanding of social work and at the same time to develop the concept of catalytic processes in psychology. The social work is pedagogical treatment...... of adolescents placed in out-of-home care and is characterised using three situated cases as empirical data. Afterwards the concept of catalytic processes is briefly presented and then applied in an analysis of pedagogical treatment in the three cases. The result is a different conceptualisation of the social...... work with new possibilities of development of the work, but also suggestions for development of the concept of catalytic processes....

  17. Catalytic iron and acute kidney injury.

    Science.gov (United States)

    Leaf, David E; Swinkels, Dorine W

    2016-11-01

    Acute kidney injury (AKI) is a common and often devastating condition among hospitalized patients and is associated with markedly increased hospital length of stay, mortality, and cost. The pathogenesis of AKI is complex, but animal models support an important role for catalytic iron in causing AKI. Catalytic iron, also known as labile iron, is a transitional pool of non-transferrin-bound iron that is readily available to participate in redox cycling. Initial findings related to catalytic iron and animal models of kidney injury have only recently been extended to human AKI. In this review, we discuss the role of catalytic iron in human AKI, focusing on recent translational studies in humans, assay considerations, and potential therapeutic targets for future interventional studies. Copyright © 2016 the American Physiological Society.

  18. Multi-core Microprocessors

    Indian Academy of Sciences (India)

    programming and computer fundamentals. His current research interests are parallel computing and history of computing. Multi-core microprocessor is an interconnected set of inde- pendent processors called cores integrated on a single sili- con chip. These processing cores communicate and cooperate with one another ...

  19. Core Competence and Education.

    Science.gov (United States)

    Holmes, Gary; Hooper, Nick

    2000-01-01

    Outlines the concept of core competence and applies it to postcompulsory education in the United Kingdom. Adopts an educational perspective that suggests accreditation as the core competence of universities. This economic approach suggests that the market trend toward lifetime learning might best be met by institutions developing a core competence…

  20. Catalytic ammonia oxidation to nitrogen (i) oxide

    OpenAIRE

    MASALITINA NATALIYA YUREVNA; SAVENKOV ANATOLIY SERGEEVICH

    2015-01-01

    The process of synthesis of nitrous oxide by low-temperature catalytical oxidation of NH has been investigated for organic synthesis. The investigation has been carried out by the stage separation approach with NH oxidation occurring in several reaction zones, which characterized by different catalytic conditions. The selectivity for N2O was 92-92,5% at the ammonia conversion of 98-99.5% in the optimal temperature range

  1. MOBILE COMPLEX FOR CATALYTIC THERMAL WASTE TREATMENT

    Directory of Open Access Journals (Sweden)

    Vedi V.E.

    2012-12-01

    Full Text Available The design and purpose of the basic units of the mobile waste processing complex “MPK” are described. Experimental data of catalytic purification of exhaust gases are presented. Experimental data on catalytic clearing of final gases of a designed mobile incinerator plant are shown. It is defined, that concentrating of parasitic bridging in waste gases of the complex are considerably smaller, rather than allowed by normative documents.

  2. Catalytic hydrogenation of carbon monoxide

    Energy Technology Data Exchange (ETDEWEB)

    Wayland, B.B.

    1992-12-01

    This project is focused on developing strategies to accomplish the reduction and hydrogenation of carbon monoxide to produce organic oxygenates at mild conditions. Our approaches to this issue are based on the recognition that rhodium macrocycles have unusually favorable thermodynamic values for producing a series of intermediate implicated in the catalytic hydrogenation of CO. Observations of metalloformyl complexes produced by reactions of H{sub 2} and CO, and reductive coupling of CO to form metallo {alpha}-diketone species have suggested a multiplicity of routes to organic oxygenates that utilize these species as intermediates. Thermodynamic and kinetic-mechanistic studies are used in constructing energy profiles for a variety of potential pathways, and these schemes are used in guiding the design of new metallospecies to improve the thermodynamic and kinetic factors for individual steps in the overall process. Variation of the electronic and steric effects associated with the ligand arrays along with the influences of the reaction medium provide the chemical tools for tuning these factors. Emerging knowledge of the factors that contribute to M-H, M-C and M-O bond enthalpies is directing the search for ligand arrays that will expand the range of metal species that have favorable thermodynamic parameters to produce the primary intermediates for CO hydrogenation. Studies of rhodium complexes are being extended to non-macrocyclic ligand complexes that emulate the favorable thermodynamic features associated with rhodium macrocycles, but that also manifest improved reaction kinetics. Multifunctional catalyst systems designed to couple the ability of rhodium complexes to produce formyl and diketone intermediates with a second catalyst that hydrogenates these imtermediates are promising approaches to accomplish CO hydrogenation at mild conditions.

  3. Efficient, lightweight dc/dc switching converter

    Science.gov (United States)

    Cuk, S.; Middlebrook, R. D.

    1981-01-01

    Converters have input properties of boost power stage and output properties of buck power stage, yet they perform general conversion function with high efficiency. Other features include non-pulsating input/output currents, use of capacitive energy transfer, low output voltage ripple, reduced EMI, and small size.

  4. Power electronics converters for wind turbine systems

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Liserre, Marco; Ma, Ke

    2011-01-01

    The steady growth of installed wind power which reached 200 GW capacity in 2010, together with the up-scaling of the single wind turbine power capability - 7 MW’s has been announced by manufacturers - has pushed the research and development of power converters towards full scale power conversion,...

  5. STIFF: Converting Scientific FITS Images to TIFF

    Science.gov (United States)

    Bertin, Emmanuel

    2011-10-01

    STIFF is a program that converts scientific FITS1 images to the more popular TIFF2 format for illustration purposes. Most FITS readers and converters do not do a proper job at converting FITS image data to 8 bits. 8-bit images stored in JPEG, PNG or TIFF files have the intensities implicitely stored in a non-linear way. Most current FITS image viewers and converters provide the user an incorrect translation of the FITS image content by simply rescaling linearly input pixel values. A first consequence is that the people working on astronomical images usually have to apply narrow intensity cuts or square-root or logarithmic intensity transformations to actually see something on their deep-sky images. A less obvious consequence is that colors obtained by combining images processed this way are not consistent across such a large range of surface brightnesses. Though with other software the user is generally afforded a choice of nonlinear transformations to apply in order to make the faint stuff stand out more clearly in the images, with the limited selection of choices provides, colors will not be accurately rendered, and some manual tweaking will be necessary. The purpose of STIFF is to produce beautiful pictures in an automatic and consistent way.

  6. Assay for Angiotensin-Converting Enzyme.

    Science.gov (United States)

    Russo, Salvatore F.

    1983-01-01

    Describes a three-hour experiment designed to introduce students to chemistry of the angiotensis-converting enzyme, illustrate design of a quenched fluorescence substrate, and examine considerations necessary in designing a clinical assay. Includes background information on the biochemistry of hypertension, reagents/materials needed, procedures…

  7. Online Scheduling in Distributed Message Converter Systems

    NARCIS (Netherlands)

    Risse, Thomas; Wombacher, Andreas; Surridge, Mike; Taylor, Steve; Aberer, Karl

    The optimal distribution of jobs among hosts in distributed environments is an important factor to achieve high performance. The optimal strategy depends on the application. In this paper we present a new online scheduling strategy for distributed EDI converter system. The strategy is based on the

  8. Angiotensin Converting Enzyme Insertion/Deletion Gene ...

    African Journals Online (AJOL)

    Erah

    Pharmacotherapy Group,. Faculty of Pharmacy, University of Benin,. Benin City, 300001 Nigeria. All rights reserved. Available online at http://www.tjpr.org. Research Article. Angiotensin Converting Enzyme Insertion/Deletion. Gene Polymorphism: An Observational Study among. Diabetic Hypertensive Subjects in Malaysia.

  9. Multilevel converters for large electric drives

    Energy Technology Data Exchange (ETDEWEB)

    Tolbert, L.M.; Peng, F.Z.

    1997-11-01

    Traditional two-level high frequency pulse width modulation (PWM) inverters for motor drives have several problems associated with their high frequency switching which produces common-mode voltage and high voltage change (dV/dt) rates to the motor windings. Multilevel inverters solve these problems because their devices can switch at a much lower frequency. Two different multilevel topologies are identified for use as a converter for electric drives, a cascade inverter with separate dc sources and a back-to-back diode clamped converter. The cascade inverter is a natural fit for large automotive all electric drives because of the high VA ratings possible and because it uses several levels of dc voltage sources which would be available from batteries or fuel cells. The back to back diode damped converter is ideal where a source of ac voltage is available such as a hybrid electric vehicle. Simulation and experimental results show the superiority of these two converters over PWM based drives.

  10. Development of the Wave Energy Converter

    DEFF Research Database (Denmark)

    Kofoed, Jens Peter; Frigaard, Peter; Sørensen, Hans Christian

    2000-01-01

    The development of the wave energy converter Wave Dragon (WD) is presented. The WD is based on the overtopping principle. Initially a description of the WD is given. Then the development over time in terms of the various research and development projects working with the concept is described...

  11. Aquabuoy Wave Energy Converter

    DEFF Research Database (Denmark)

    Vicinanza, Diego; Margheritini, Lucia; Frigaard, Peter

    The work reported here is part of the contract agreement between the Finavera Renewables Ocean Energy Ltd. and the Department of Civil Engineering Hydraulics and Coastal Engineering Laboratory to instrument a model in scale 1:10 to prototype of the AquaBuOY (AB) wave energy converter and to analyse...

  12. Layout Optimisation of Wave Energy Converter Arrays

    DEFF Research Database (Denmark)

    Ruiz, Pau Mercadé; Nava, Vincenzo; Topper, Mathew B. R.

    2017-01-01

    This paper proposes an optimisation strategy for the layout design of wave energy converter (WEC) arrays. Optimal layouts are sought so as to maximise the absorbed power given a minimum q-factor, the minimum distance between WECs, and an area of deployment. To guarantee an efficient optimisation...

  13. multilevel buck converter for automotive electrical load

    African Journals Online (AJOL)

    ... from internal combustion engine (ICE). The mass production of the hybrid electric (HE) and the electric vehicle (EV) is still awaited due to subsystem inefficiencies. Increasing the efficiencies of the power converters within subsystems of these HEVs and EVs will increase the performance of the new transportation vehicles.

  14. Gourami lenses convert tryptophan into 3-hydroxykynurenine.

    Science.gov (United States)

    Truscott, R J; Wood, A M

    1994-01-01

    Although free tryptophan was found in the lens of both the kissing gourami (Helostoma temmincki) and the 3-spot gourami (Trichogaster trichopterus), only the lens of the latter species contained 3-hydroxykynurenine. Radiolabel experiments carried out on 3-spot gourami lenses in culture demonstrated that, as in humans, lenticular tryptophan is converted to 3-hydroxykynurenine probably via the intermediate kynurenine.

  15. Mathematical modeling of the flash converting process

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, H.Y.; Perez-Tello, M.; Riihilahti, K.M. [Utah Univ., Salt Lake City, UT (United States)

    1996-12-31

    An axisymmetric mathematical model for the Kennecott-Outokumpu flash converting process for converting solid copper matte to copper is presented. The model is an adaptation of the comprehensive mathematical model formerly developed at the University of Utah for the flash smelting of copper concentrates. The model incorporates the transport of momentum, heat, mass, and reaction kinetics between gas and particles in a particle-laden turbulent gas jet. The standard k-{epsilon} model is used to describe gas-phase turbulence in an Eulerian framework. The particle-phase is treated from a Lagrangian viewpoint which is coupled to the gas-phase via the source terms in the Eulerian gas-phase governing equations. Matte particles were represented as Cu{sub 2}S yFeS, and assumed to undergo homogeneous oxidation to Cu{sub 2}O, Fe{sub 3}O{sub 4}, and SO{sub 2}. A reaction kinetics mechanism involving both external mass transfer of oxygen gas to the particle surface and diffusion of oxygen through the porous oxide layer is proposed to estimate the particle oxidation rate Predictions of the mathematical model were compared with the experimental data collected in a bench-scale flash converting facility. Good agreement between the model predictions and the measurements was obtained. The model was used to study the effect of different gas-injection configurations on the overall fluid dynamics in a commercial size flash converting shaft. (author)

  16. Angiotensin Converting Enzyme Insertion/Deletion Gene ...

    African Journals Online (AJOL)

    Purpose: This study investigated the influence of angiotensin-1 converting enzyme (ACE) insertiondeletion (ID) gene polymorphism on the treatment responses of type 2 diabetic subjects at varying stages of nephropathy to ACE inhibitors (ACEI) with regard to blood pressure (MAP) and renal response (GFR). Methods: The ...

  17. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Catalytic Conversion of Sugars to Hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Tao, L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Scarlata, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Tan, E. C. D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Ross, J. [Harris Group Inc., New York, NY (United States); Lukas, J. [Harris Group Inc., New York, NY (United States); Sexton, D. [Harris Group Inc., New York, NY (United States)

    2015-03-01

    This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to die die diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.

  18. Core stability exercise principles.

    Science.gov (United States)

    Akuthota, Venu; Ferreiro, Andrea; Moore, Tamara; Fredericson, Michael

    2008-02-01

    Core stability is essential for proper load balance within the spine, pelvis, and kinetic chain. The so-called core is the group of trunk muscles that surround the spine and abdominal viscera. Abdominal, gluteal, hip girdle, paraspinal, and other muscles work in concert to provide spinal stability. Core stability and its motor control have been shown to be imperative for initiation of functional limb movements, as needed in athletics. Sports medicine practitioners use core strengthening techniques to improve performance and prevent injury. Core strengthening, often called lumbar stabilization, also has been used as a therapeutic exercise treatment regimen for low back pain conditions. This article summarizes the anatomy of the core, the progression of core strengthening, the available evidence for its theoretical construct, and its efficacy in musculoskeletal conditions.

  19. On the study of catalytic membrane reactor for water detritiation: Membrane characterization

    OpenAIRE

    Mascarade, Jérémy; Liger, Karine; Troulay, Michèle; Joulia, Xavier; Meyer, Xuân-Mi; Perrais, Christophe; Tosti, Silvano

    2013-01-01

    Tritium waste recycling is a real economic and ecological issue. Generally under the non-valuable Q2Oform (Q = H, D or T), waste can be converted into fuel Q2for a fusion machine (e.g. JET, ITER) by isotopeexchange reaction Q2O + H2= H2O + Q2. Such a reaction is carried out over Ni-based catalyst bed packed ina thin wall hydrogen permselective membrane tube. This catalytic membrane reactor can achieve higherconversion ratios than conventional fixed bed reactors by selective removal of reactio...

  20. Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

    Science.gov (United States)

    Narula, Chaitanya K.; Davison, Brian H.

    2015-11-13

    A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100°C and up to 550°C, wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.

  1. Catalytic enantioselective protonation of nitronates utilizing an organocatalyst chiral only at sulfur.

    Science.gov (United States)

    Kimmel, Kyle L; Weaver, Jimmie D; Lee, Melissa; Ellman, Jonathan A

    2012-06-06

    The highly enantioselective protonation of nitronates formed upon the addition of α-substituted Meldrum's acids to terminally unsubstituted nitroalkenes is described. This work represents the first enantioselective catalytic addition of any type of nucleophile to this class of nitroalkenes. Moreover, for the successful implementation of this method, a new type of N-sulfinyl urea catalyst with chirality residing only at the sulfinyl group was developed, thereby enabling the incorporation of a diverse range of achiral diamine motifs. Finally, the Meldrum's acid addition products were readily converted to pharmaceutically relevant 3,5-disubstituted pyrrolidinones in high yield.

  2. Tunable catalytic properties of bi-functional mixed oxides in ethanol conversion to high value compounds

    Energy Technology Data Exchange (ETDEWEB)

    Ramasamy, Karthikeyan K.; Gray, Michel J.; Job, Heather M.; Smith, Colin D.; Wang, Yong

    2016-04-10

    tA highly versatile ethanol conversion process to selectively generate high value compounds is pre-sented here. By changing the reaction temperature, ethanol can be selectively converted to >C2alcohols/oxygenates or phenolic compounds over hydrotalcite derived bi-functional MgO–Al2O3cata-lyst via complex cascade mechanism. Reaction temperature plays a role in whether aldol condensationor the acetone formation is the path taken in changing the product composition. This article containsthe catalytic activity comparison between the mono-functional and physical mixture counterpart to thehydrotalcite derived mixed oxides and the detailed discussion on the reaction mechanisms.

  3. ACIDITY OF MODIFIED MORDENITES SYNTHESIZED FROM RICE HUSK SILICA AND CATALYTIC TRANSFORMATION OF METHYLBUTYNOL

    Directory of Open Access Journals (Sweden)

    Sittichai Kulawong

    2015-02-01

    Full Text Available Mordenite (MOR was synthesized using rice husk silica and modified by base (B, acid (A or acid-base (AB and converted to H-form. The modification did not destroy the MOR structure but increased surface area and generated mesopores. Lewis acidity of the parent and modified MOR samples investigated by aluminum NMR and NH3-TPD showed a decrease in the following order: HMOR > BMOR > ABMOR > AMOR. For the catalytic transformation of methylbutynol, ABMOR provided the highest conversion and selectivity of products from acid sites.

  4. HANARO core channel flow-rate measurement

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Heon Il; Chae, Hee Tae; Im, Don Soon; Kim, Seon Duk [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1996-06-01

    HANARO core consists of 23 hexagonal flow tubes and 16 cylindrical flow tubes. To get the core flow distribution, we used 6 flow-rate measuring dummy fuel assemblies (instrumented dummy fuel assemblies). The differential pressures were measured and converted to flow-rates using the predetermined relationship between AP and flow-rate for each instrumented dummy fuel assemblies. The flow-rate for the cylindrical flow channels shows +-7% relative errors and that for the hexagonal flow channels shows +-3.5% relative errors. Generally the flow-rates of outer core channels show smaller values compared to those of inner core. The channels near to the core inlet pipe and outlet pipes also show somewhat lower flow-rates. For the lower flow channels, the thermal margin was checked by considering complete linear power histories. From the experimental results, the gap flow-rate was estimated to be 49.4 kg/s (cf. design flow of 50 kg/s). 15 tabs., 9 figs., 10 refs. (Author) .new.

  5. Development of full MOX core in ABWR

    Energy Technology Data Exchange (ETDEWEB)

    Aoyama, Motoo; Bessho, Yasunori; Izutsu, Sadayuki; Uchikawa, Sadao [Hitachi Ltd., Tokyo (Japan)

    1995-10-01

    In the long term plan on the research, development and utilization of nuclear power, the plan of processing the plutonium extracted by reprocessing spent fuel into MOX fuel and utilizing it for light water reactors was shown. According to this plan, it is considered appropriate that the utilization of MOX fuel will be started in the latter half of 1990s in small number of BWRs and PWRs, and it will be expanded flexibly along the plan to about 10 plants by around 2000. The project of verifying a small number of MOX fuel assemblies has been carried out in Japan, and the experience of the design and operation of MOX fuel has been accumulated independently. In addition to this experience, reflecting the knowledge resulted from utilizing MOX fuel for the advanced thermal reactor, Hitachi Ltd. has exerted efforts positively for the research and development toward the full scale use of MOX fuel for BWRs. The core of advanced BWR has the excellent characteristics suitable to the use of Mox fuel, in which plutonium can absorb neutrons more easily than uranium. In ABWRs, the volume ratio of water to fuel was increased. As to the full MOX core of ABWRs, equilibrium core characteristics, the characteristics of initial charge and converted cores, and core management are described. (K.I.).

  6. Methods for Converter Sludge Dehydration Intensification

    Science.gov (United States)

    Vakhromeev, M. I.; Moreva, Y. A.; Starkova, L. G.

    2017-11-01

    The article considers the intensification methods for converter sludge dehydration exemplified by the sludges of the Oxygen Converter Workshop (OCW) of the Open Joint-Stock Company “Magnitogorsk Iron and Steel Works” (MMK, OJSC), one of the largest metallurgical companies in the Southern Urals. Converter sludges can contain up to 45-70% of ferrum [21] which is interesting in terms of their use as an addition to a sinter-feed mixture. Sludge intensifies the sintering process. It positively influences pelletizing and fusion mixture melting dynamics at sintering. Over the period of the converter sludge dehydration complex operation at the OCW, MMK, OJSC, it was revealed that processing results in obtaining of high humidity sludge. It causes sludge freezing during the winter period, thus, its transportation involves extra costs for sludge warming up. To resolve the above-mentioned problem, the following works were performed in 2016: - experimental studies of how the application of the low-molecular anionic flocculate “SEURVEY” FL-3 influences sludge humidity reduction. - experimental studies of how the filtering press process operation parameters influence sludge humidity reduction. The new flocculate application didn't lower the dehydrated sludge humidity (the objective was the humidity of not more than 15%). Basing upon the conducted research results, we can make a conclusion that putting into operation the sewage water reactant treatment technology with the use of “SEURVEY”, FL-3 (H-10) is not recommended. The research of the influence the filtering press process parameters have on the dehydration process intensification demonstrated that reaching of the obtained residue humidity value lower than 15% is possible under the reduction of the filtering press chamber depths to 30 mm and with the application of additional operation “Residue drying” with compressed air. This way of the sludge dehydration problem resolving at filtering presses of the

  7. Bidirectional converter interface for a battery energy storage test bench

    DEFF Research Database (Denmark)

    Trintis, Ionut; Thomas, Stephan; Blank, Tobias

    2011-01-01

    This paper presents the bidirectional converter interface for a 6 kV battery energy storage test bench. The power electronic interface consists a two stage converter topology having a low voltage dc-ac grid connected converter and a new dual active bridge dc-dc converter with high transformation...... ratio. The dc-dc converter controls the battery charge/discharge current while the grid converter controls the common dc-link voltage and the grid current. The applied control structures and the hardware implementation of both converters are presented, together with their interaction. Experimental...

  8. Design, Fabrication, and Testing of an External-Fuel [UO2] Full-Length Thermionic Converter

    Energy Technology Data Exchange (ETDEWEB)

    Schock, Alfred; Raab, B; Giorgio, F.

    1971-09-01

    The development of a double-ended full-core-length external-fuel converter, a prototypical fuel module for a 200- to 300-ekw thermionic reactor, is described. The converter design is based on a revolver-shaped tungsten emitter body, with six peripheral fuel chambers loaded with enriched UO2 pellets. The columbium collector is water-cooled through a sub-atmospheric adjustable-pressure helium gap. The converter employs graded metal-ceramic seals, and its double-ended construction is made possible by bellows to compensate for differential axial expansion. Fission gases are vented from the fuel chambers and collected in an accumulator designed for continuous monitoring of the pressure buildup. Component fabrication, assembly sequence, and joining methods are described; also the test procedures, and the converter load control. All tests are performed in vacuum. During inpile testing, the fuel is triply contained, with thermal insulation between the secondary and tertiary containers. Before insertion inpile, the fully fueled converter is qualification-tested by rf-induction heating using a specially developed high vacuum rf-feedthrough.

  9. A High-Efficiency, Low-Cost Solution for On-Board Power Converters

    Directory of Open Access Journals (Sweden)

    V. Boscaino

    2012-01-01

    Full Text Available Wide-input, low-voltage, and high-current applications are addressed. A single-ended isolated topology which improves the power efficiency, reduces both switching and conduction losses, and heavily lowers the system cost is presented. During each switching cycle, the transformer core reset is provided. The traditional tradeoff between the maximum allowable duty-cycle and the reset voltage is avoided and the off-voltage of active switches is clamped to the input voltage. Therefore, the system cost is heavily reduced and the converter is well suited for wide-input applications. Zero-voltage switching is achieved for active switches, and the power efficiency is greatly improved. In the output mesh, an inductor is included making the converter suitable for high-current, low-voltage applications. Since the active clamp forward converter is the closest competitor of the proposed converter, a comparison is provided as well. In this paper, the steady-state and small-signal analysis of the proposed converter is presented. Design examples are provided for further applications. Simulation and experimental results are shown to validate the great advantages brought by the proposed topology.

  10. A novel synthetic test system for thyristor level in the converter valve of HVDC power transmission

    Directory of Open Access Journals (Sweden)

    Liu Longchen

    2016-01-01

    Full Text Available The converter valve is the core equipment in the HVDC power transmission system, a+-nd its performance has a direct effect on the reliability, stability and efficiency of the whole power system. As the basic unit of HVDC converter valve, the thyristor level needs to be test routinely in order to grasp the state of the converter valve equipment. Therefore, it is urgent to develop a novel synthetic test system for the thyristor level with thyristor control unit (TCU. However, currently there is no specific test scheme for the thyristor level of HVDC converter valve. In this paper, the synthetic test principle, content and methods for the thyristor level with TCU are presented based on the analysis of the thyristor reverse recovery characteristic and the IEC technology standard. And a transient high-voltage pulse is applied to the thyristor level during its reverse recovery period in order to test the characteristics of thyristor level. Then, the synthetic test system for the thyristor level is applied to the converter valve test of ±800 kV HVDC power transmission project, and the practical test result verifies the reasonability and validity of the proposed synthetic test system.

  11. High-frequency matrix converter with square wave input

    Science.gov (United States)

    Carr, Joseph Alexander; Balda, Juan Carlos

    2015-03-31

    A device for producing an alternating current output voltage from a high-frequency, square-wave input voltage comprising, high-frequency, square-wave input a matrix converter and a control system. The matrix converter comprises a plurality of electrical switches. The high-frequency input and the matrix converter are electrically connected to each other. The control system is connected to each switch of the matrix converter. The control system is electrically connected to the input of the matrix converter. The control system is configured to operate each electrical switch of the matrix converter converting a high-frequency, square-wave input voltage across the first input port of the matrix converter and the second input port of the matrix converter to an alternating current output voltage at the output of the matrix converter.

  12. HYDRATE CORE DRILLING TESTS

    Energy Technology Data Exchange (ETDEWEB)

    John H. Cohen; Thomas E. Williams; Ali G. Kadaster; Bill V. Liddell

    2002-11-01

    The ''Methane Hydrate Production from Alaskan Permafrost'' project is a three-year endeavor being conducted by Maurer Technology Inc. (MTI), Noble, and Anadarko Petroleum, in partnership with the U.S. DOE National Energy Technology Laboratory (NETL). The project's goal is to build on previous and ongoing R&D in the area of onshore hydrate deposition. The project team plans to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope includes drilling and coring one well on Anadarko leases in FY 2003 during the winter drilling season. A specially built on-site core analysis laboratory will be used to determine some of the physical characteristics of the hydrates and surrounding rock. Prior to going to the field, the project team designed and conducted a controlled series of coring tests for simulating coring of hydrate formations. A variety of equipment and procedures were tested and modified to develop a practical solution for this special application. This Topical Report summarizes these coring tests. A special facility was designed and installed at MTI's Drilling Research Center (DRC) in Houston and used to conduct coring tests. Equipment and procedures were tested by cutting cores from frozen mixtures of sand and water supported by casing and designed to simulate hydrate formations. Tests were conducted with chilled drilling fluids. Tests showed that frozen core can be washed out and reduced in size by the action of the drilling fluid. Washing of the core by the drilling fluid caused a reduction in core diameter, making core recovery very difficult (if not impossible). One successful solution was to drill the last 6 inches of core dry (without fluid circulation). These tests demonstrated that it will be difficult to capture core when drilling in permafrost or hydrates without implementing certain safeguards. Among the coring tests was a simulated hydrate

  13. Adsorbent catalytic nanoparticles and methods of using the same

    Energy Technology Data Exchange (ETDEWEB)

    Slowing, Igor Ivan; Kandel, Kapil

    2017-01-31

    The present invention provides an adsorbent catalytic nanoparticle including a mesoporous silica nanoparticle having at least one adsorbent functional group bound thereto. The adsorbent catalytic nanoparticle also includes at least one catalytic material. In various embodiments, the present invention provides methods of using and making the adsorbent catalytic nanoparticles. In some examples, the adsorbent catalytic nanoparticles can be used to selectively remove fatty acids from feedstocks for biodiesel, and to hydrotreat the separated fatty acids.

  14. Dual Converter Fed Open-End Transformer Topology with Parallel Converters and Integrated Magnetics

    DEFF Research Database (Denmark)

    Gohil, Ghanshyamsinh Vijaysinh; Bede, Lorand; Teodorescu, Remus

    2016-01-01

    A converter system for high power applications, connected to a medium-voltage network using a stepup transformer, is presented in this paper. The converterside winding of the transformer is configured as an openend and both the ends of the windings are fed from two different converter groups. Each...... that flows between the parallel interleaved VSCs. An integrated inductor is proposed which suppresses the circulating current in both the converter groups. In addition, the functionality of the line filter inductor is also integrated. Flux in various parts of the integrated inductor is analyzed and a design...

  15. Three-level neutral-point-clamped matrix converter topology

    OpenAIRE

    Lee, Meng Yeong

    2009-01-01

    Matrix converter is a direct AC-AC converter topology that is able to directly convert energy from an AC source to an AC load without the need of a bulky and limited lifetime energy storage element. Due to the significant advantages offered by matrix converter, such as adjustable power factor, capability of regeneration and high quality sinusoidal input/output waveforms, matrix converter has been one of the AC – AC topologies that receive extensive research attention for being an alternative ...

  16. Renewable chemical commodity feedstocks from integrated catalytic processing of pyrolysis oils.

    Science.gov (United States)

    Vispute, Tushar P; Zhang, Huiyan; Sanna, Aimaro; Xiao, Rui; Huber, George W

    2010-11-26

    Fast pyrolysis of lignocellulosic biomass produces a renewable liquid fuel called pyrolysis oil that is the cheapest liquid fuel produced from biomass today. Here we show that pyrolysis oils can be converted into industrial commodity chemical feedstocks using an integrated catalytic approach that combines hydroprocessing with zeolite catalysis. The hydroprocessing increases the intrinsic hydrogen content of the pyrolysis oil, producing polyols and alcohols. The zeolite catalyst then converts these hydrogenated products into light olefins and aromatic hydrocarbons in a yield as much as three times higher than that produced with the pure pyrolysis oil. The yield of aromatic hydrocarbons and light olefins from the biomass conversion over zeolite is proportional to the intrinsic amount of hydrogen added to the biomass feedstock during hydroprocessing. The total product yield can be adjusted depending on market values of the chemical feedstocks and the relative prices of the hydrogen and biomass.

  17. Dimethyl carbonate as potential reactant in non-catalytic biodiesel production by supercritical method.

    Science.gov (United States)

    Ilham, Zul; Saka, Shiro

    2009-03-01

    In this study, the non-catalytic supercritical method has been studied in utilizing dimethyl carbonate. It was demonstrated that, the supercritical dimethyl carbonate process without any catalysts applied, converted triglycerides to fatty acid methyl esters with glycerol carbonate and citramalic acid as by-products, while free fatty acids were converted to fatty acid methyl esters with glyoxal. After 12 min of reaction at 350 degrees C/20 MPa, rapeseed oil treated with supercritical dimethyl carbonate reached 94% (w/w) yield of fatty acid methyl ester. The by-products from this process which are glycerol carbonate and citramalic acid are much higher in value than glycerol produced by the conventional process. In addition, the yield of the fatty acid methyl esters as biodiesel was almost at par with supercritical methanol method. Therefore, supercritical dimethyl carbonate process can be a good candidate as an alternative biodiesel production process.

  18. Imbalance between pulmonary angiotensin-converting enzyme and angiotensin-converting enzyme 2 activity in acute respiratory distress syndrome

    NARCIS (Netherlands)

    Wosten-van Asperen, Roelie M.; Bos, Albert; Bem, Reinout A.; Dierdorp, Barbara S.; Dekker, Tamara; van Goor, Harry; Kamilic, Jelena; van der Loos, Chris M.; van den Berg, Elske; Bruijn, Martijn; van Woensel, Job B.; Lutter, Rene

    2013-01-01

    Objective: Angiotensin-converting enzyme and its effector peptide angiotensin II have been implicated in the pathogenesis of acute respiratory distress syndrome. Recently, angiotensin-converting enzyme 2 was identified as the counter-regulatory enzyme of angiotensin-converting enzyme that converts

  19. Mesoporous SnO2-coated metal nanoparticles with enhanced catalytic efficiency.

    Science.gov (United States)

    Zhou, Na; Polavarapu, Lakshminarayana; Wang, Qing; Xu, Qing-Hua

    2015-03-04

    Aggregation of plasmonic nanoparticles under harsh conditions has been one of the major obstacles to their potential applications. Here we present the preparation of uniform mesoporous SnO2 shell coated Au nanospheres, Au nanorods and Au/Ag core-shell nanorods and their applications in molecular sensing and catalysis. In these nanostructures, the mesoporous SnO2 shell stabilizes the metal nanoparticle and allows the metal core to be exposed to the surrounding environment for various applications at the same time. These nanostructures display high refractive index sensitivity, which makes them promising materials for LSPR based molecular sensing. Applications of these materials as catalysts for reduction of 4-nitrophenol by NaBH4 have also been demonstrated. Both uncoated and SnO2-coated anisotropic Au and Au/Ag nanorods were found to display significantly better catalytic efficiency compared to the corresponding spherical Au nanoparticles. Catalytic activities of different metal nanoparticles were significantly enhanced by 4-6 times upon coating with the mesoporous SnO2 shell. The enhanced catalytic activity of metal nanoparticles upon SnO2 coating was attributed to charge-redistribution between noble metal and SnO2 that disperses the electrons to a large area and prolonged electron lifetime in SnO2-coated metal nanoparticles. The charge transfer mechanism of enhanced catalytic efficiency for SnO2-coated metal nanoparticles has been further demonstrated by photochemical reduction of silver ions on the outer surface of these NPs. These metal/semiconductor core-shell nanomaterials are potentially useful for various applications such as molecular sensing and catalysis.

  20. Bifunctional Molecular Photoswitches Based on Overcrowded Alkenes for Dynamic Control of Catalytic Activity in Michael Addition Reactions.

    Science.gov (United States)

    Pizzolato, Stefano F; Collins, Beatrice S L; van Leeuwen, Thomas; Feringa, Ben L

    2017-05-02

    The emerging field of artificial photoswitchable catalysis has recently shown striking examples of functional light-responsive systems allowing for dynamic control of activity and selectivity in organocatalysis and metal-catalysed transformations. While our group has already disclosed systems featuring first generation molecular motors as the switchable central core, a design based on second generation molecular motors is lacking. Here, the syntheses of two bifunctionalised molecular switches based on a photoresponsive tetrasubstituted alkene core are reported. They feature a thiourea substituent as hydrogen-donor moiety in the upper half and a basic dimethylamine group in the lower half. This combination of functional groups offers the possibility for application of these molecules in photoswitchable catalytic processes. The light-responsive central cores were synthesized by a Barton-Kellogg coupling of the prefunctionalized upper and lower halves. Derivatization using Buchwald-Hartwig amination and subsequent introduction of the thiourea substituent afforded the target compounds. Control of catalytic activity in the Michael addition reaction between (E)-3-bromo-β-nitrostyrene and 2,4-pentanedione is achieved upon irradiation of stable-(E) and stable-(Z) isomers of the bifunctional catalyst 1. Both isomers display a decrease in catalytic activity upon irradiation to the metastable state, providing systems with the potential to be applied as ON/OFF catalytic photoswitches. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Analog-digital converters for industrial applications including an introduction to digital-analog converters

    CERN Document Server

    Ohnhäuser, Frank

    2015-01-01

    This book offers students and those new to the topic of analog-to-digital converters (ADCs) a broad introduction, before going into details of the state-of-the-art design techniques for SAR and DS converters, including the latest research topics, which are valuable for IC design engineers as well as users of ADCs in applications. The book then addresses important topics, such as correct connectivity of ADCs in an application, the verification, characterization and testing of ADCs that ensure high-quality end products. Analog-to-digital converters are the central element in any data processing system and regulation loops such as modems or electrical motor drives. They significantly affect the performance and resolution of a system or end product. System development engineers need to be familiar with the performance parameters of the converters and understand the advantages and disadvantages of the various architectures. Integrated circuit development engineers have to overcome the problem of achieving high per...

  2. Multi-output DC-DC converters based on diode-clamped converters configuration

    DEFF Research Database (Denmark)

    Nami, A.; Zare, F.; Ghosh, A.

    2010-01-01

    for a diode-clamed inverter in the grid connection systems, where boosting low rectified output-voltage and series DC link capacitors is required. To verify the proposed topology, steady-state and dynamic analyses of a MOB converter are examined. A simple control strategy has been proposed to demonstrate......This study presents a new DC DC multi-output boost (MOB) converter which can share its total output between different series of output voltages for low- and high-power applications. This configuration can be utilised instead of several single output power supplies. This is a compatible topology...... the performance of the proposed topology for a double-output boost converter. The topology and its control strategy can easily be extended to offer multiple outputs. Simulation and experimental results are presented to show the validity of the control strategy for the proposed converter....

  3. Investigating the effects of alkali metal Na addition on catalytic activity of HZSM-5 for methyl mercaptan elimination

    Science.gov (United States)

    Yu, Jie; He, Dedong; Chen, Dingkai; Liu, Jiangping; Lu, Jichang; Liu, Feng; Liu, Pan; Zhao, Yutong; Xu, Zhizhi; Luo, Yongming

    2017-10-01

    Na-modified HZSM-5 catalysts with different Na loading amounts were prepared by incipient-wetness impregnation method and their catalytic activities for methyl mercaptan catalytic elimination were analyzed. XRD, N2 adsorption-desorption, NH3-TPD, CO2-TPD and FT-IR measurements were carried out to investigate the effects of modification of alkali metal Na on the physicochemical properties of the HZSM-5 zeolite catalyst. Research results illustrated that the introduction of alkali metal Na can improve catalytic activity for CH3SH catalytic elimination. CH3SH can be almost completely converted over 3%-Na/HZSM-5 at 450 °C compared to pure HZSM-5 at 600 °C based on our experimental results and the results from previous research. The improved catalytic activity could be attributed to the regulated acid-base properties of the HZSM-5 catalysts by doping with alkali metal Na. High alkali concentration treatment, however, may destroy the framework structure of the catalyst sample, thus causing the poor stability performance of the obtained catalyst.

  4. Yolk-shell Fe(0)@SiO2 nanoparticles as nanoreactors for fenton-like catalytic reaction.

    Science.gov (United States)

    Liu, Chao; Li, Jiansheng; Qi, Junwen; Wang, Jing; Luo, Rui; Shen, Jinyou; Sun, Xiuyun; Han, Weiqing; Wang, Lianjun

    2014-08-13

    Yolk-shell nanoparticles (YSNs) with active metal cores have shown promising applications in nanoreactors with excellent catalytic performance. In this work, Fe(0)@SiO2 YSNs were synthesized by a sequential "two-solvents" impregnation-reduction approach. Specifically, FeSO4 aqueous solution was introduced into the preformed hollow mesoporous silica spheres (HMSS), dispersed in n-hexane, via a "two-solvent" impregnation way. Subsequently, aqueous solution of sodium borohydride (NaBH4) was introduced into the cavity of HMSS by the same way, leading to the formation of Fe core inside the HMSS through the reaction between Fe(2+) and NaBH4. The resulting Fe(0)@SiO2 YSNs possess distinctive structures, including active cores, accessible mesoporous channels, protective shells, and hollow cavities. To present the catalytic performance of YSNs nanoreactors, Fenton-like catalytic oxidation of phenol was chosen as the model catalysis reaction. In addition to the Fe(0)@SiO2 YSNs, two other materials were also applied to the catalytic system for comparison, including Fe@SiO2 composites with iron nanoparticles sticking on the outer shells of HMSS (Fe@SiO2-DI) and bare iron nanoparticles without HMSS (bare Fe(0)), respectively. The catalytic results show that Fe(0)@SiO2 YSNs exhibit higher catalytic rate toward phenol removal at 2-fold and 4-fold as compared to that of Fe@SiO2-DI and bare Fe(0), indicating the outstanding catalytic property of YSNs nanoreactors. To further clarify the relationship between catalytic properties and structural characteristics, the adsorption experiments of the three samples were also performed in the absence of H2O2. Other than catalytic results, Fe(0)@SiO2 YSNs show slightly higher adsorption efficiency than the other two samples, indicating the accessibility of nanoreactors. This result demonstrates that the removal of phenol in the oxidation system of Fe(0)@SiO2 YSNs may have contributed to the structure-enhanced effect of YSNs as nanoreactors.

  5. A Variational Inequality from Pricing Convertible Bond

    Directory of Open Access Journals (Sweden)

    Yan Huiwen

    2011-01-01

    Full Text Available The model of pricing American-style convertible bond is formulated as a zero-sum Dynkin game, which can be transformed into a parabolic variational inequality (PVI. The fundamental variable in this model is the stock price of the firm which issued the bond, and the differential operator in PVI is linear. The optimal call and conversion strategies correspond to the free boundaries of PVI. Some properties of the free boundaries are studied in this paper. We show that the bondholder should convert the bond if and only if the price of the stock is equal to a fixed value, and the firm should call the bond back if and only if the price is equal to a strictly decreasing function of time. Moreover, we prove that the free boundaries are smooth and bounded. Eventually we give some numerical results.

  6. Boost Converter with Active Snubber Network

    Directory of Open Access Journals (Sweden)

    HIMMELSTOSS, F. A.

    2017-02-01

    Full Text Available A new concept for reducing the losses in a boost converter is described. With the help of an auxiliary switch and a resonant circuit, zero-voltage switching at turn-off and zero-current switching during turn-on are achieved. The modes of the circuit are shown in detail. The energy recovery of the turn-off is analyzed and the recovered energy is calculated; an optimized switching concept therefore is described. The influence of the parasitic capacity of the switch is discussed. Dimensioning hints for the converter and the design of the recuperation circuit are given. A bread-boarded design shows the functional efficiency of the concept.

  7. Terahertz broadband polarization converter based on metamaterials

    Science.gov (United States)

    Li, Yonghua; Zhao, Guozhong

    2018-01-01

    Based on the metamaterial composed of symmetrical split resonant ring, a broadband reflective terahertz polarization converter is proposed. The numerical simulation shows that it can rotate the polarization direction of linear polarized wave 90° in the range of 0.7-1.8THz and the polarization conversion ratio is over 90%. The reflection coefficient of the two electric field components in the diagonal direction is the same and the phase difference is 180° ,which leads to the cross-polarization rotation.In order to further study the physical mechanism of high polarization conversion, we analyze the surface current distribution of the resonant ring. The polarization converter has potential applications in terahertz wave plate and metamaterial antenna design.

  8. Component technology for Stirling power converters

    Energy Technology Data Exchange (ETDEWEB)

    Thieme, L.G.

    1994-09-01

    NASA Lewis Research Center has organized a component technology program as part of the efforts to develop Stirling converter technology for space power applications. The Stirling space power program is part of the NASA High Capacity Power Project of the Civil Space Technology Initiative (CSTI). NASA Lewis is also providing technical management for a DOE/Sandia program to develop Stirling converters for solar terrestrial power producing electricity for the utility grid. The primary contractors for the space power and solar terrestrial programs develop component technologies directly related to their program goals. This Lewis component technology effort, while coordinated with the main programs, aims at longer term issues, advanced technologies, and independent assessments. This paper will present an overview of work on linear alternators, engine/alternator/load interactions and controls, heat exchangers, materials, life and reliability, and bearings.

  9. MOCCASIN: converting MATLAB ODE models to SBML.

    Science.gov (United States)

    Gómez, Harold F; Hucka, Michael; Keating, Sarah M; Nudelman, German; Iber, Dagmar; Sealfon, Stuart C

    2016-06-15

    MATLAB is popular in biological research for creating and simulating models that use ordinary differential equations (ODEs). However, sharing or using these models outside of MATLAB is often problematic. A community standard such as Systems Biology Markup Language (SBML) can serve as a neutral exchange format, but translating models from MATLAB to SBML can be challenging-especially for legacy models not written with translation in mind. We developed MOCCASIN (Model ODE Converter for Creating Automated SBML INteroperability) to help. MOCCASIN can convert ODE-based MATLAB models of biochemical reaction networks into the SBML format. MOCCASIN is available under the terms of the LGPL 2.1 license (http://www.gnu.org/licenses/lgpl-2.1.html). Source code, binaries and test cases can be freely obtained from https://github.com/sbmlteam/moccasin : mhucka@caltech.edu More information is available at https://github.com/sbmlteam/moccasin. © The Author 2016. Published by Oxford University Press.

  10. Converter topologies for common mode voltage reduction

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Fernando

    2017-11-21

    An inverter includes a three-winding transformer, a DC-AC inverter electrically coupled to the first winding of the transformer, a cycloconverter electrically coupled to the second winding of the transformer, and an active filter electrically coupled to the third winding of the transformer. The DC-AC inverter is adapted to convert the input DC waveform to an AC waveform delivered to the transformer at the first winding. The cycloconverter is adapted to convert an AC waveform received at the second winding of the transformer to the output AC waveform having a grid frequency of the AC grid. The active filter is adapted to sink and source power with one or more energy storage devices based on a mismatch in power between the DC source and the AC grid. At least two of the DC-AC inverter, the cycloconverter, or the active filter are electrically coupled via a common reference electrical interconnect.

  11. MAGIC: Model and Graphic Information Converter

    Science.gov (United States)

    Herbert, W. C.

    2009-01-01

    MAGIC is a software tool capable of converting highly detailed 3D models from an open, standard format, VRML 2.0/97, into the proprietary DTS file format used by the Torque Game Engine from GarageGames. MAGIC is used to convert 3D simulations from authoritative sources into the data needed to run the simulations in NASA's Distributed Observer Network. The Distributed Observer Network (DON) is a simulation presentation tool built by NASA to facilitate the simulation sharing requirements of the Data Presentation and Visualization effort within the Constellation Program. DON is built on top of the Torque Game Engine (TGE) and has chosen TGE's Dynamix Three Space (DTS) file format to represent 3D objects within simulations.

  12. Analog current mode analog/digital converter

    Science.gov (United States)

    Hadidi, Khayrollah (Inventor)

    1996-01-01

    An improved subranging or comparator circuit is provided for an analog-to-digital converter. As a subranging circuit, the circuit produces a residual signal representing the difference between an analog input signal and an analog of a digital representation. This is achieved by subdividing the digital representation into two or more parts and subtracting from the analog input signal analogs of each of the individual digital portions. In another aspect of the present invention, the subranging circuit comprises two sets of differential input pairs in which the transconductance of one differential input pair is scaled relative to the transconductance of the other differential input pair. As a consequence, the same resistor string may be used for two different digital-to-analog converters of the subranging circuit.

  13. Component technology for Stirling power converters

    Science.gov (United States)

    Thieme, Lanny G.

    1991-01-01

    NASA Lewis Research Center has organized a component technology program as part of the efforts to develop Stirling converter technology for space power applications. The Stirling Space Power Program is part of the NASA High Capacity Power Project of the Civil Space Technology Initiative (CSTI). NASA Lewis is also providing technical management for the DOE/Sandia program to develop Stirling converters for solar terrestrial power producing electricity for the utility grid. The primary contractors for the space power and solar terrestrial programs develop component technologies directly related to their goals. This Lewis component technology effort, while coordinated with the main programs, aims at longer term issues, advanced technologies, and independent assessments. An overview of work on linear alternators, engine/alternator/load interactions and controls, heat exchangers, materials, life and reliability, and bearings is presented.

  14. Strained quantum well photovoltaic energy converter

    Science.gov (United States)

    Freundlich, Alexandre (Inventor); Renaud, Philippe (Inventor); Vilela, Mauro Francisco (Inventor); Bensaoula, Abdelhak (Inventor)

    1998-01-01

    An indium phosphide photovoltaic cell is provided where one or more quantum wells are introduced between the conventional p-conductivity and n-conductivity indium phosphide layer. The approach allows the cell to convert the light over a wider range of wavelengths than a conventional single junction cell and in particular convert efficiently transparency losses of the indium phosphide conventional cell. The approach hence may be used to increase the cell current output. A method of fabrication of photovoltaic devices is provided where ternary InAsP and InGaAs alloys are used as well material in the quantum well region and results in an increase of the cell current output.

  15. Performance Evaluation of Wave Energy Converters

    DEFF Research Database (Denmark)

    Pecher, Arthur

    . Guidelines for the development of wave energy converters recommend the use of different prototypes, having different sizes, which have to perform tank tests or sea trials. Thisimplicates the need of different testing environment, which shifts from being controllable to uncontrollable with the development...... stages, and results thereby in a need for specific testobjectives and procedures for each development stage. This PhD thesis has looked into the different development stages and more specifically in the performance assessment of wave energy converters based on tank testing and sea trials. The objective......Ocean waves provide a sustainable, power-dense, predictable and widely available source of energy that could provide about 10 % of worlds energy needs. While research into waveenergy has been undertaken for decades, a significant increase in related activities has been seen in the recent years...

  16. Performance Evaluation of Wave Energy Converters

    DEFF Research Database (Denmark)

    Pecher, Arthur

    . Guidelines for the development of wave energy converters recommend the use of different prototypes, having different sizes, which have to perform tank tests or sea trials. This implicates the need of different testing environment, which shifts from being controllable to uncontrollable with the development...... stages, and results thereby in a need for specific test objectives and procedures for each development stage. This PhD thesis has looked into the different development stages and more specifically in the performance assessment of wave energy converters based on tank testing and sea trials. The objective......Ocean waves provide a sustainable, power-dense, predictable and widely available source of energy that could provide about 10 % of worlds energy needs. While research into wave energy has been undertaken for decades, a significant increase in related activities has been seen in the recent years...

  17. MOX fuel arrangement for nuclear core

    Energy Technology Data Exchange (ETDEWEB)

    Kantrowitz, Mark L. (Portland, CT); Rosenstein, Richard G. (Windsor, CT)

    1998-01-01

    In order to use up a stockpile of weapons-grade plutonium, the plutonium is converted into a mixed oxide (MOX) fuel form wherein it can be disposed in a plurality of different fuel assembly types. Depending on the equilibrium cycle that is required, a predetermined number of one or more of the fuel assembly types are selected and arranged in the core of the reactor in accordance with a selected loading schedule. Each of the fuel assemblies is designed to produce different combustion characteristics whereby the appropriate selection and disposition in the core enables the resulting equilibrium cycle to closely resemble that which is produced using urania fuel. The arrangement of the MOX rods and burnable absorber rods within each of the fuel assemblies, in combination with a selective control of the amount of plutonium which is contained in each of the MOX rods, is used to tailor the combustion characteristics of the assembly.

  18. Mox fuel arrangement for nuclear core

    Energy Technology Data Exchange (ETDEWEB)

    Kantrowitz, Mark L. (Portland, CT); Rosenstein, Richard G. (Windsor, CT)

    2001-05-15

    In order to use up a stockpile of weapons-grade plutonium, the plutonium is converted into a mixed oxide (MOX) fuel form wherein it can be disposed in a plurality of different fuel assembly types. Depending on the equilibrium cycle that is required, a predetermined number of one or more of the fuel assembly types are selected and arranged in the core of the reactor in accordance with a selected loading schedule. Each of the fuel assemblies is designed to produce different combustion characteristics whereby the appropriate selection and disposition in the core enables the resulting equilibrium cycle to closely resemble that which is produced using urania fuel. The arrangement of the MOX rods and burnable absorber rods within each of the fuel assemblies, in combination with a selective control of the amount of plutonium which is contained in each of the MOX rods, is used to tailor the combustion. characteristics of the assembly.

  19. MOX fuel arrangement for nuclear core

    Energy Technology Data Exchange (ETDEWEB)

    Kantrowitz, Mark L. (Portland, CT); Rosenstein, Richard G. (Windsor, CT)

    2001-07-17

    In order to use up a stockpile of weapons-grade plutonium, the plutonium is converted into a mixed oxide (MOX) fuel form wherein it can be disposed in a plurality of different fuel assembly types. Depending on the equilibrium cycle that is required, a predetermined number of one or more of the fuel assembly types are selected and arranged in the core of the reactor in accordance with a selected loading schedule. Each of the fuel assemblies is designed to produce different combustion characteristics whereby the appropriate selection and disposition in the core enables the resulting equilibrium cycle to closely resemble that which is produced using urania fuel. The arrangement of the MOX rods and burnable absorber rods within each of the fuel assemblies, in combination with a selective control of the amount of plutonium which is contained in each of the MOX rods, is used to tailor the combustion characteristics of the assembly.

  20. MOX fuel arrangement for nuclear core

    Energy Technology Data Exchange (ETDEWEB)

    Kantrowitz, M.L.; Rosenstein, R.G.

    1998-10-13

    In order to use up a stockpile of weapons-grade plutonium, the plutonium is converted into a mixed oxide (MOX) fuel form wherein it can be disposed in a plurality of different fuel assembly types. Depending on the equilibrium cycle that is required, a predetermined number of one or more of the fuel assembly types are selected and arranged in the core of the reactor in accordance with a selected loading schedule. Each of the fuel assemblies is designed to produce different combustion characteristics whereby the appropriate selection and disposition in the core enables the resulting equilibrium cycle to closely resemble that which is produced using urania fuel. The arrangement of the MOX rods and burnable absorber rods within each of the fuel assemblies, in combination with a selective control of the amount of plutonium which is contained in each of the MOX rods, is used to tailor the combustion characteristics of the assembly. 38 figs.